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Sample records for ultra supercritical boilers

  1. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Ultra-Supercritical Pressure CFB Boiler ... Although CFB boilers as large as 300 MWe are now in operation, they are drum type, ...

  2. Materials development for ultra-supercritical boilers

    SciTech Connect (OSTI)

    2005-09-30

    Progress is reported on a US Department of Energy project to develop high temperature, corrosion resistant alloys for use in ultra-supercritical steam cycles. The aim is to achieve boiler operation at 1,400{sup o}F/5,000 psi steam conditions with 47% net cycle efficiency. Most ferritic steel tested such as T92 and Save 12 showed severe corrosion. Nickel-based alloys, especially IN 740 and CCA 617, showed greatest resistance to oxidation with no evidence of exfoliation. Laboratory and in-plant tests have begun. 2 figs.

  3. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study

    SciTech Connect (OSTI)

    Zhen Fan; Steve Goidich; Archie Robertson; Song Wu

    2006-06-30

    Electric utility interest in supercritical pressure steam cycles has revived in the United States after waning in the 1980s. Since supercritical cycles yield higher plant efficiencies than subcritical plants along with a proportional reduction in traditional stack gas pollutants and CO{sub 2} release rates, the interest is to pursue even more advanced steam conditions. The advantages of supercritical (SC) and ultra supercritical (USC) pressure steam conditions have been demonstrated in the high gas temperature, high heat flux environment of large pulverized coal-fired (PC) boilers. Interest in circulating fluidized bed (CFB) combustion, as an alternative to PC combustion, has been steadily increasing. Although CFB boilers as large as 300 MWe are now in operation, they are drum type, subcritical pressure units. With their sizes being much smaller than and their combustion temperatures much lower than those of PC boilers (300 MWe versus 1,000 MWe and 1600 F versus 3500 F), a conceptual design study was conducted herein to investigate the technical feasibility and economics of USC CFB boilers. The conceptual study was conducted at 400 MWe and 800 MWe nominal plant sizes with high sulfur Illinois No. 6 coal used as the fuel. The USC CFB plants had higher heating value efficiencies of 40.6 and 41.3 percent respectively and their CFB boilers, which reflect conventional design practices, can be built without the need for an R&D effort. Assuming construction at a generic Ohio River Valley site with union labor, total plant costs in January 2006 dollars were estimated to be $1,551/kW and $1,244/kW with costs of electricity of $52.21/MWhr and $44.08/MWhr, respectively. Based on the above, this study has shown that large USC CFB boilers are feasible and that they can operate with performance and costs that are competitive with comparable USC PC boilers.

  4. Evaluation of a 1000 MW Commercial Ultra Super-Critical Coal Boiler |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility prediction of instantaneous O2 mass fraction in a hypothetical commercial scale 1000 MW, Ultra Super-Critical (USC) coal boiler Large eddy simulation prediction of instantaneous O2 mass fraction in a hypothetical commercial scale 1000 MW, Ultra Super-Critical (USC) coal boiler. Simulation results may suggest new design features that can have an impact on the operation of current and next-generation USC boilers. Carbon Capture Multi-Disciplinary

  5. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect (OSTI)

    David W. Gandy; John P. Shingledecker

    2011-04-11

    Forced outages and boiler unavailability in conventional coal-fired fossil power plants is most often caused by fireside corrosion of boiler waterwalls. Industry-wide, the rate of wall thickness corrosion wastage of fireside waterwalls in fossil-fired boilers has been of concern for many years. It is significant that the introduction of nitrogen oxide (NOx) emission controls with staged burners systems has increased reported waterwall wastage rates to as much as 120 mils (3 mm) per year. Moreover, the reducing environment produced by the low-NOx combustion process is the primary cause of accelerated corrosion rates of waterwall tubes made of carbon and low alloy steels. Improved coatings, such as the MCrAl nanocoatings evaluated here (where M is Fe, Ni, and Co), are needed to reduce/eliminate waterwall damage in subcritical, supercritical, and ultra-supercritical (USC) boilers. The first two tasks of this six-task project-jointly sponsored by EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)-have focused on computational modeling of an advanced MCrAl nanocoating system and evaluation of two nanocrystalline (iron and nickel base) coatings, which will significantly improve the corrosion and erosion performance of tubing used in USC boilers. The computational model results showed that about 40 wt.% is required in Fe based nanocrystalline coatings for long-term durability, leading to a coating composition of Fe-25Cr-40Ni-10 wt.% Al. In addition, the long term thermal exposure test results further showed accelerated inward diffusion of Al from the nanocrystalline coatings into the substrate. In order to enhance the durability of these coatings, it is necessary to develop a diffusion barrier interlayer coating such TiN and/or AlN. The third task 'Process Advanced MCrAl Nanocoating Systems' of the six-task project jointly sponsored by the Electric Power Research Institute, EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)- has focused on processing of

  6. Computation Modeling and Assessment of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect (OSTI)

    J. Shingledecker; D. Gandy; N. Cheruvu; R. Wei; K. Chan

    2011-06-21

    Forced outages and boiler unavailability of coal-fired fossil plants is most often caused by fire-side corrosion of boiler waterwalls and tubing. Reliable coatings are required for Ultrasupercritical (USC) application to mitigate corrosion since these boilers will operate at a much higher temperatures and pressures than in supercritical (565 C {at} 24 MPa) boilers. Computational modeling efforts have been undertaken to design and assess potential Fe-Cr-Ni-Al systems to produce stable nanocrystalline coatings that form a protective, continuous scale of either Al{sub 2}O{sub 3} or Cr{sub 2}O{sub 3}. The computational modeling results identified a new series of Fe-25Cr-40Ni with or without 10 wt.% Al nanocrystalline coatings that maintain long-term stability by forming a diffusion barrier layer at the coating/substrate interface. The computational modeling predictions of microstructure, formation of continuous Al{sub 2}O{sub 3} scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. Advanced coatings, such as MCrAl (where M is Fe, Ni, or Co) nanocrystalline coatings, have been processed using different magnetron sputtering deposition techniques. Several coating trials were performed and among the processing methods evaluated, the DC pulsed magnetron sputtering technique produced the best quality coating with a minimum number of shallow defects and the results of multiple deposition trials showed that the process is repeatable. scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. The cyclic oxidation test results revealed that the nanocrystalline coatings offer better oxidation resistance, in terms of weight loss, localized oxidation, and formation of mixed oxides in the Al{sub 2}O{sub 3} scale, than widely used MCrAlY coatings. However, the ultra-fine grain structure in these coatings, consistent with the computational model predictions, resulted in accelerated Al

  7. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect (OSTI)

    Gandy, David W.; Shingledecker, John P.

    2011-05-11

    Coal-fired power plants are a significant part of the nation's power generating capacity, currently accounting for more than 55% of the country's total electricity production. Extending the reliable lifetimes of fossil fired boiler components and reducing the maintenance costs are essential for economic operation of power plants. Corrosion and erosion are leading causes of superheater and reheater boiler tube failures leading to unscheduled costly outages. Several types of coatings and weld overlays have been used to extend the service life of boiler tubes; however, the protection afforded by such materials was limited approximately one to eight years. Power companies are more recently focused in achieving greater plant efficiency by increasing steam temperature and pressure into the advanced-ultrasupercritical (A-USC) condition with steam temperatures approaching 760°C (1400°F) and operating pressures in excess of 35MPa (5075 psig). Unfortunately, laboratory and field testing suggests that the resultant fireside environment when operating under A-USC conditions can potentially cause significant corrosion to conventional and advanced boiler materials1-2. In order to improve reliability and availability of fossil fired A-USC boilers, it is essential to develop advanced nanostructured coatings that provide excellent corrosion and erosion resistance without adversely affecting the other properties such as toughness and thermal fatigue strength of the component material.

  8. Safe Use Limits for Advanced Ferritic Steels in Ultra-Supercritical Power Boilers.

    SciTech Connect (OSTI)

    Swindeman, RW

    2003-11-03

    In 2000, a Cooperative Research and Development Agreement (CRADA) was undertaken between the Oak Ridge National Laboratory (ORNL) and the Babcock & Wilcox Company to examine the databases for advanced ferritic steels and determine the safe limits for operation in supercritical steam power boilers. The materials of interest included the vanadium-modified 9-12% Cr steels with 1-2% Mo or W. The first task involved a review of pertinent information and the down-selection of a steel of special interest. The long-time database for 9Cr-1Mo-V steel was found to be most satisfactory for the examinations, and this steel was taken to be representative of the group. The second task involved the collection of aged and service exposed samples for metallurgical and mechanical testing. Here, aged samples to 75,000 hours, laboratory-tested samples to 83,000 hours, and service-exposed sample with up to 143,000 hours exposure were collected. The third task involved mechanical testing of exposed samples. Creep-rupture testing to long times was undertaken. Variable stress and temperature testing was included. Results were compared against the prediction of damage models. These models seemed to be adequate for life prediction. The fourth task involved the metallurgical examination of exposed specimens. Changes in microstructure were compared against published information on the evolution of microstructures in 9Cr-Mo-V steels and the results were found to be consistent with expectations. The fifth task involved a survey of steam and fireside corrosion. Data from the service-exposed tubing was examined, and a literature survey was undertaken as part of an activity in support of ultra-supercritical steam boiler technology. The corrosion study indicated some concerns about long-time fireside corrosion and suggested temperature limits were needed for corrosive coal ash conditions.

  9. Steam Oxidation and Chromia Evaporation in Ultra-Supercritical Steam Boilers and Turbines

    SciTech Connect (OSTI)

    Gordon H. Holcomb

    2009-01-01

    U.S. Department of Energy’s goals include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 °C and 340 atm, so-called ultra-supercritical (USC) conditions. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism. A methodology to calculate Cr evaporation rates from chromia scales was developed and combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles and to predict the time until breakaway oxidation. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. Alloy additions such as Ti may allow for a reduction in evaporation rate with time, mitigating the deleterious effects of chromia evaporation.

  10. Ultra Supercritical Steamside Oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

    2005-01-01

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  11. Conceptual Design of Supercritical O2-Based PC Boiler (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Conceptual Design of Supercritical O2-Based PC Boiler Citation Details In-Document Search Title: Conceptual Design of Supercritical O2-Based PC Boiler No abstract ...

  12. Conceptual Design of Supercritical O2-Based PC Boiler (Technical...

    Office of Scientific and Technical Information (OSTI)

    Conceptual Design of Supercritical O2-Based PC Boiler Citation Details In-Document Search Title: Conceptual Design of Supercritical O2-Based PC Boiler You are accessing a ...

  13. Super Boiler: First Generation, Ultra-High Efficiency Firetube Boiler

    SciTech Connect (OSTI)

    2006-06-01

    This factsheet describes a research project whose goal is to develop and demonstrate a first-generation ultra-high-efficiency, ultra-low emissions, compact gas-fired package boiler (Super Boiler), and formulate a long-range RD&D plan for advanced boiler technology out to the year 2020.

  14. ULTRA-SUPERCRITICAL STEAM CORROSION

    SciTech Connect (OSTI)

    Holcomb, G.R.; Alman, D.E.; Bullard, S.B.; Covino, B.S., Jr.; Cramer, S.D.; Ziomek-Moroz, M.

    2003-04-22

    Efficiency increases in fossil energy boilers and steam turbines are being achieved by increasing the temperature and pressure at the turbine inlets well beyond the critical point of water. To allow these increases, advanced materials are needed that are able to withstand the higher temperatures and pressures in terms of strength, creep, and oxidation resistance. As part of a larger collaborative effort, the Albany Research Center (ARC) is examining the steam-side oxidation behavior for ultrasupercritical (USC) steam turbine applications. Initial tests are being done on six alloys identified as candidates for USC steam boiler applications: ferritic alloy SAVE12, austenitic alloy Super 304H, the high Cr-high Ni alloy HR6W, and the nickel-base superalloys Inconel 617, Haynes 230, and Inconel 740. Each of these alloys has very high strength for its alloy type. Three types of experiments are planned: cyclic oxidation in air plus steam at atmospheric pressure, thermogravimetric ana lysis (TGA) in steam at atmospheric pressure, and exposure tests in supercritical steam up to 650 C (1202 F) and 34.5 MPa (5000 psi). The atmospheric pressure tests, combined with supercritical exposures at 13.8, 20.7, 24.6, and 34.5 MPa (2000, 3000, 4000, and 5000 psi) should allow the determination of the effect of pressure on the oxidation process.

  15. Ultra supercritical turbines--steam oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Ziomek-Moroz, Margaret; Alman, David E.

    2004-01-01

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy?s Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538?C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620?C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which would require steam temperatures of up to 760?C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  16. Model-free adaptive control of supercritical circulating fluidized-bed boilers

    DOE Patents [OSTI]

    Cheng, George Shu-Xing; Mulkey, Steven L

    2014-12-16

    A novel 3-Input-3-Output (3.times.3) Fuel-Air Ratio Model-Free Adaptive (MFA) controller is introduced, which can effectively control key process variables including Bed Temperature, Excess O2, and Furnace Negative Pressure of combustion processes of advanced boilers. A novel 7-input-7-output (7.times.7) MFA control system is also described for controlling a combined 3-Input-3-Output (3.times.3) process of Boiler-Turbine-Generator (BTG) units and a 5.times.5 CFB combustion process of advanced boilers. Those boilers include Circulating Fluidized-Bed (CFB) Boilers and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  17. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study...

    Office of Scientific and Technical Information (OSTI)

    Assuming construction at a generic Ohio River Valley site with union labor, total plant costs in January 2006 dollars were estimated to be 1,551kW and 1,244kW with costs of ...

  18. Economic Analysis for Conceptual Design of Supercritical O2-Based PC Boiler

    SciTech Connect (OSTI)

    Andrew Seltzer; Archie Robertson

    2006-09-01

    This report determines the capital and operating costs of two different oxygen-based, pulverized coal-fired (PC) power plants and compares their economics to that of a comparable, air-based PC plant. Rather than combust their coal with air, the oxygen-based plants use oxygen to facilitate capture/removal of the plant CO{sub 2} for transport by pipeline to a sequestering site. To provide a consistent comparison of technologies, all three plants analyzed herein operate with the same coal (Illinois No 6), the same site conditions, and the same supercritical pressure steam turbine (459 MWe). In the first oxygen-based plant, the pulverized coal-fired boiler operates with oxygen supplied by a conventional, cryogenic air separation unit, whereas, in the second oxygen-based plant, the oxygen is supplied by an oxygen ion transport membrane. In both oxygen-based plants a portion of the boiler exhaust gas, which is primarily CO{sub 2}, is recirculated back to the boiler to control the combustion temperature, and the balance of the flue gas undergoes drying and compression to pipeline pressure; for consistency, both plants operate with similar combustion temperatures and utilize the same CO{sub 2} processing technologies. The capital and operating costs of the pulverized coal-fired boilers required by the three different plants were estimated by Foster Wheeler and the balance of plant costs were budget priced using published data together with vendor supplied quotations. The cost of electricity produced by each of the plants was determined and oxygen-based plant CO{sub 2} mitigation costs were calculated and compared to each other as well as to values published for some alternative CO{sub 2} capture technologies.

  19. Cast Alloys for Advanced Ultra Supercritical Steam Turbines

    SciTech Connect (OSTI)

    G. R. Holcomb, P. Wang, P. D. Jablonski, and J. A. Hawk,

    2010-05-01

    The proposed steam inlet temperature in the Advanced Ultra Supercritical (A-USC) steam turbine is high enough (760 °C) that traditional turbine casing and valve body materials such as ferritic/martensitic steels will not suffice due to temperature limitations of this class of materials. Cast versions of several traditionally wrought Ni-based superalloys were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantial: 2-5,000 kg each half and on the order of 100 cm thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equivalent microstructures. A multi-step homogenization heat treatment was developed to better deploy the alloy constituents. The most successful of these cast alloys in terms of creep strength (Haynes 263, Haynes 282, and Nimonic 105) were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (at 760 and 800 °C).

  20. Superalloys for ultra supercritical steam turbines--oxidation behavior

    SciTech Connect (OSTI)

    Holcomb, G.R.

    2008-09-01

    Goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 °C and 340 atm, so called ultra-supercritical (USC) steam conditions. One of the important materials performance considerations is steam-side oxidation resistance. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism under USC conditions. A methodology to calculate Cr evaporation rates from chromia scales with cylindrical geometries was developed that allows for the effects of CrO2(OH)2 saturation within the gas phase. This approach was combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles as a function of exposure time and to predict the time until the alloy surface concentration of Cr reaches zero. This time is a rough prediction of the time until breakaway oxidation. A hypothetical superheater tube, steam pipe, and high pressure turbine steam path was examined. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. The predicted time until breakaway oxidation increases dramatically with decreases in temperature and total pressure. Possible mitigation techniques were discussed, including those used in solid oxide fuel cell metallic interconnects (lowering the activity of Cr in the oxide scale by adding Mn to the alloy), and thermal barrier coating use on high pressure turbine blades for both erosion and chromia evaporation protection.

  1. Experimental investigation on heat transfer and frictional characteristics of vertical upward rifled tube in supercritical CFB boiler

    SciTech Connect (OSTI)

    Yang, Dong; Pan, Jie; Zhu, Xiaojing; Bi, Qincheng; Chen, Tingkuan; Zhou, Chenn Q.

    2011-02-15

    Water wall design is a key issue for supercritical Circulating Fluidized Bed (CFB) boiler. On account of the good heat transfer performance, rifled tube is applied in the water wall design of a 600 MW supercritical CFB boiler in China. In order to investigate the heat transfer and frictional characteristics of the rifled tube with vertical upward flow, an in-depth experiment was conducted in the range of pressure from 12 to 30 MPa, mass flux from 230 to 1200 kg/(m{sup 2} s), and inner wall heat flux from 130 to 720 kW/m{sup 2}. The wall temperature distribution and pressure drop in the rifled tube were obtained in the experiment. The normal, enhanced and deteriorated heat transfer characteristics were also captured. In this paper, the effects of pressure, inner wall heat flux and mass flux on heat transfer characteristics are analyzed, the heat transfer mechanism and the frictional resistance performance are discussed, and the corresponding empirical correlations are presented. The experimental results show that the rifled tube can effectively prevent the occurrence of departure from nucleate boiling (DNB) and keep the tube wall temperature in a permissible range under the operating condition of supercritical CFB boiler. (author)

  2. Cast Alloys for Advanced Ultra Supercritical Steam Turbines

    SciTech Connect (OSTI)

    G. R. Holcomb, P. D. Jablonski, and P. Wang

    2010-10-01

    Develop advanced coal-based power systems capable of 45–50 % efficiency at <$1,000/kW (in 2002 dollars). Develop technologies for capture and sequestration of CO2 that result in: • <10% increase in the cost of electricity in an IGCC-based plant • <35% increase in the cost of electricity for pulverized coal boilers Demonstrate coal-based energy plants that offer near-zero emissions (including CO2) with multiproduct production

  3. Modeling Creep-Fatigue-Environment Interactions in Steam Turbine Rotor Materials for Advanced Ultra-supercritical Coal Power Plants

    SciTech Connect (OSTI)

    Shen, Chen

    2014-04-01

    The goal of this project is to model creep-fatigue-environment interactions in steam turbine rotor materials for advanced ultra-supercritical (A-USC) coal power Alloy 282 plants, to develop and demonstrate computational algorithms for alloy property predictions, and to determine and model key mechanisms that contribute to the damages caused by creep-fatigue-environment interactions.

  4. Economic Analysis for Conceptual Design of Supercritical O2-Based...

    Office of Scientific and Technical Information (OSTI)

    Economic Analysis for Conceptual Design of Supercritical O2-Based PC Boiler Citation Details In-Document Search Title: Economic Analysis for Conceptual Design of Supercritical ...

  5. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and

  6. US program on materials technology for ultra-supercritical coal power plants

    SciTech Connect (OSTI)

    Viswanathan, R.; Henry, J.F.; Tanzosh, J.; Stanko, G.; Shingledecker, J.; Vitalis, B.; Purgert, R.

    2005-06-01

    The study reported on here is aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers that are capable of operating with steam at temperatures of 760{sup o}C (1400{sup o}F) and pressures of 35 MPa (5000 psi). The economic viability of such a plant has been explored. Candidate alloys applicable to various ranges of temperatures have been identified. Stress rupture tests have been completed on the base metal and on welds to a number of alloys. Steamside oxidation tests in an autoclave at 650{sup o}C (1200{sup o}F) and 800{sup o}C (1475 {sup o}F) have been completed. Fireside corrosion tests have been conducted under conditions simulating those of waterwalls and superheater/reheater tubes. The weldability and fabricability of the alloys have been investigated. The capabilities of various overlay coatings and diffusion coatings have been examined. This article provides a status report on the progress achieved to date on this project.

  7. Evaluation of the Materials Technology Required for a 760?C Power Steam Boiler

    SciTech Connect (OSTI)

    Shingledecker, John P; Wright, Ian G

    2006-01-01

    The U.S. Ultra-supercritical (USC) Steam Boiler Consortium, funded by the U.S. Department of Energy and the Ohio Coal Development Office, has been working to develop the necessary materials technology to construct a steam power boiler with maximum steam conditions of 760 C and 35MPa. One large component of this work is to evaluate the properties of the materials chosen for such a boiler. While long-term creep strength of base metal is initially used to set temperatures, stresses, and simple design rules, it is clear that base metal creep strength is not always the material property of most importance when selecting an alloy. The fabrication issues (typically weldability), the properties of materials after fabrication, the corrosion resistance of the material, and material cost all need to be considered in addition to baseline mechanical properties. Work is ongoing at Oak Ridge National Laboratory to evaluate the material technologies being developed by the USC Steam Boiler Consortium and perform additional advanced research activities in areas where new materials developments and better fundamental understanding are needed to ensure the long-term success of a 760 C power steam boiler.

  8. Engineering development of advanced coal-fired low emission boiler systems

    SciTech Connect (OSTI)

    Not Available

    1993-10-01

    Riley Stoker Corporation is leading an R&D program for the expedited development of a new generation of pulverized coal-fired boiler systems. The overall objective is to develop relatively near term technologies to produce Low-Emission coal-fired Boiler Systems (LEBS) ready for full scale commercial generating plants by the end of the decade. The specific goal is to develop a LEBS incorporating an advanced slagging system for improved ash management in addition to meeting the emission and performance goals. This Concept Selection Report documents an evaluation of subsystems and LEBS concepts. Priority was given to the evaluation of the boiler system, steam cycle, and advanced slagging combustor. Some findings are as follows: An ultra supercritical steam cycle is required to meet project efficiency goals. The cost of electricity (COE) for this cycle, at today`s fuel prices, and without externality costs, is slightly higher than a conventional subcritical cycle. The supercritical cycle includes a substantial contingency. Reduction of contingency, escalation of fuel cost, or inclusion of externalities all lead to a lower COE for the supercritical cycle compared to the subcritical cycle. The advanced cycle is selected for inclusion in the LEBS. The advanced slagging combustor (TVC), should it meet the projected performance goals, yields a lower COE than either a dry firing system or a more conventional slagger fitted with post combustion NO{sub x} controls. Verification and development of the advanced slagger performance is the primary focus of this project. A commercial slagging configuration know as U-firing is selected for parallel development and as a platform for adaptation to the TVC.

  9. Super Boiler 2nd Generation Technology for Watertube Boilers

    SciTech Connect (OSTI)

    Mr. David Cygan; Dr. Joseph Rabovitser

    2012-03-31

    This report describes Phase I of a proposed two phase project to develop and demonstrate an advanced industrial watertube boiler system with the capability of reaching 94% (HHV) fuel-to-steam efficiency and emissions below 2 ppmv NOx, 2 ppmv CO, and 1 ppmv VOC on natural gas fuel. The boiler design would have the capability to produce >1500 F, >1500 psig superheated steam, burn multiple fuels, and will be 50% smaller/lighter than currently available watertube boilers of similar capacity. This project is built upon the successful Super Boiler project at GTI. In that project that employed a unique two-staged intercooled combustion system and an innovative heat recovery system to reduce NOx to below 5 ppmv and demonstrated fuel-to-steam efficiency of 94% (HHV). This project was carried out under the leadership of GTI with project partners Cleaver-Brooks, Inc., Nebraska Boiler, a Division of Cleaver-Brooks, and Media and Process Technology Inc., and project advisors Georgia Institute of Technology, Alstom Power Inc., Pacific Northwest National Laboratory and Oak Ridge National Laboratory. Phase I of efforts focused on developing 2nd generation boiler concepts and performance modeling; incorporating multi-fuel (natural gas and oil) capabilities; assessing heat recovery, heat transfer and steam superheating approaches; and developing the overall conceptual engineering boiler design. Based on our analysis, the 2nd generation Industrial Watertube Boiler when developed and commercialized, could potentially save 265 trillion Btu and $1.6 billion in fuel costs across U.S. industry through increased efficiency. Its ultra-clean combustion could eliminate 57,000 tons of NOx, 460,000 tons of CO, and 8.8 million tons of CO2 annually from the atmosphere. Reduction in boiler size will bring cost-effective package boilers into a size range previously dominated by more expensive field-erected boilers, benefiting manufacturers and end users through lower capital costs.

  10. PARTICULATE CHARACTERIZATION AND ULTRA LOW-NOx BURNER FOR THE CONTROL OF NO{sub x} AND PM{sub 2.5} FOR COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Ralph Bailey; Hamid Sarv; Jim Warchol; Debi Yurchison

    2001-09-30

    In response to the serious challenge facing coal-fired electric utilities with regards to curbing their NO{sub x} and fine particulate emissions, Babcock and Wilcox and McDermott Technology, Inc. conducted a project entitled, ''Particulate Characterization and Ultra Low-NO{sub x} Burner for the Control of NO{sub x} and PM{sub 2.5} for Coal Fired Boilers.'' The project included pilot-scale demonstration and characterization of technologies for removal of NO{sub x} and primary PM{sub 2.5} emissions. Burner development and PM{sub 2.5} characterization efforts were based on utilizing innovative concepts in combination with sound scientific and fundamental engineering principles and a state-of-the-art test facility. Approximately 1540 metric tonnes (1700 tons) of high-volatile Ohio bituminous coal were fired. Particulate sampling for PM{sub 2.5} emissions characterization was conducted in conjunction with burner testing. Based on modeling recommendations, a prototype ultra low-NO{sub x} burner was fabricated and tested at 100 million Btu/hr in the Babcock and Wilcox Clean Environment Development Facility. Firing the unstaged burner with a high-volatile bituminous Pittsburgh 8 coal at 100 million Btu/hr and 17% excess air achieved a NO{sub x} goal of 0.20 lb NO{sub 2}/million Btu with a fly ash loss on ignition (LOI) of 3.19% and burner pressure drop of 4.7 in H{sub 2}O for staged combustion. With the burner stoichiometry set at 0.88 and the overall combustion stoichiometry at 1.17, average NO{sub x} and LOI values were 0.14 lb NO{sub 2}/million Btu and 4.64% respectively. The burner was also tested with a high-volatile Mahoning 7 coal. Based on the results of this work, commercial demonstration is being pursued. Size classified fly ash samples representative of commercial low-NO{sub x} and ultra low-NO{sub x} combustion of Pittsburgh 8 coal were collected at the inlet and outlet of an ESP. The mass of size classified fly ash at the ESP outlet was sufficient to evaluate

  11. Advanced, Low/Zero Emission Boiler Design and Operation

    SciTech Connect (OSTI)

    Babcock Illinois State Geological; Worley Parsons; Parsons Infrastructure /Technology Group

    2007-06-30

    In partnership with the U.S. Department of Energy's National Energy Technology Laboratory, B&W and Air Liquide are developing and optimizing the oxy-combustion process for retrofitting existing boilers as well as new plants. The main objectives of the project is to: (1) demonstrate the feasibility of the oxy-combustion technology with flue gas recycle in a 5-million Btu/hr coal-fired pilot boiler, (2) measure its performances in terms of emissions and boiler efficiency while selecting the right oxygen injection and flue gas recycle strategies, and (3) perform technical and economic feasibility studies for application of the technology in demonstration and commercial scale boilers. This document summarizes the work performed during the period of performance of the project (Oct 2002 to June 2007). Detailed technical results are reported in corresponding topical reports that are attached as an appendix to this report. Task 1 (Site Preparation) has been completed in 2003. The experimental pilot-scale O{sub 2}/CO{sub 2} combustion tests of Task 2 (experimental test performance) has been completed in Q2 2004. Process simulation and cost assessment of Task 3 (Techno-Economic Study) has been completed in Q1 2005. The topical report on Task 3 has been finalized and submitted to DOE in Q3 2005. The calculations of Task 4 (Retrofit Recommendation and Preliminary Design of a New Generation Boiler) has been completed in 2004. In Task 6 (engineering study on retrofit applications), the engineering study on 25MW{sub e} unit has been completed in Q2, 2008 along with the corresponding cost assessment. In Task 7 (evaluation of new oxy-fuel power plants concepts), based on the design basis document prepared in 2005, the design and cost estimate of the Air Separation Units, the boiler islands and the CO{sub 2} compression and trains have been completed, for both super and ultra-supercritical case study. Final report of Task-7 is published by DOE in Oct 2007.

  12. Ultra-High Efficiency Industrial Steam Generation R&D Opportunities

    SciTech Connect (OSTI)

    none,

    2005-01-01

    The workshop report outlines the R&D priorities for the next generation of ultra-high efficiency boilers.

  13. Super Boiler Update

    SciTech Connect (OSTI)

    2007-10-01

    This presentation from the 2007 American Boiler Manufacturers Association Manufacturers Conference provides an update of the First Generation Super Boiler.

  14. Choosing the right boiler air fans at Weston 4

    SciTech Connect (OSTI)

    Spring, N.

    2009-04-15

    When it came to choosing the three 'big' boiler air fans - forced draft, induced draft and primary air, the decision revolved around efficiency. The decision making process for fan selection for the Western 4 supercritical coal-fired plant is described in this article. 3 photos.

  15. Fossil-Fired Boilers

    Energy Science and Technology Software Center (OSTI)

    1993-09-23

    Boiler Performance Model (BPM 3.0S) is a set of computer programs developed to analyze the performance of fossil-fired utility boilers. The programs can model a wide variety of boiler designs, and can model coal, oil, or natural gas firing. The programs are intended for use by engineers performing analyses of alternative fuels, alternative operating modes, or boiler modifications.

  16. Boiler and cooling water basics

    SciTech Connect (OSTI)

    Ketrick, B.T.

    1995-06-01

    Boiler Water Treatment products and programs are used in boiler systems to prevent the formation of water side deposits and corrosion. Water side deposits will cause a loss of boiler efficiency, as well as, damage to the boiler internals. Corrosion can cause a loss of boiler metal integrity. Both conditions can lead to a reduced operating life for the boiler and costly annual repairs.

  17. What is Supercritical CO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is Supercritical CO 2 ? Supercritical CO 2 is a fluid state of carbon dioxide where it is held above its critical pressure and critical temperature, which causes the gas to go beyond liquid or gas into a phase where it acts as both simultaneously. Many fluids can achieve supercritical states, and supercritical steam has been used in power generation for decades. Supercritical CO 2 has many unique properties that allow it to dissolve materials like a liquid but also flow like a gas. The Sandia

  18. CHP Integrated with Burners for Packaged Boilers - Fact Sheet, April 2014 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy CHP Integrated with Burners for Packaged Boilers - Fact Sheet, April 2014 CHP Integrated with Burners for Packaged Boilers - Fact Sheet, April 2014 CMCE, Inc., in collaboration with Altex Technologies Corporation, developed the Boiler Burner Energy System Technology (BBEST), a CHP assembly of a gas-fired simple-cycle 100 kilowatt (kW) microturbine and a new ultra-low NOx gas-fired burner, to increase acceptance of small CHP systems.

  19. Second Generation Super Boiler Technology for Watertube Boilers

    SciTech Connect (OSTI)

    2007-07-01

    This factsheet describes a research project to develop a high-pressure watertube boiler system that incorporates and improves upon the capabilities of the firetube Super Boiler system.

  20. Minimize Boiler Blowdown

    Broader source: Energy.gov [DOE]

    This tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  1. Minimize Boiler Blowdown

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  2. Supercritical fluid extraction

    DOE Patents [OSTI]

    Wai, Chien M.; Laintz, Kenneth

    1994-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated or lipophilic crown ether or fluorinated dithiocarbamate. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  3. Promising Technology: Condensing Gas Boilers

    Broader source: Energy.gov [DOE]

    Condensing boilers achieve higher efficiencies than conventional boilers by capturing the latent heat from water vapor contained in the flue gases.

  4. Boiler MACT | Department of Energy

    Office of Environmental Management (EM)

    Boiler MACT Boiler MACT DOE currently provides technical assistance on combined heat and power (CHP) technologies to commercial and industrial facilities through its seven ...

  5. A Comparison of Creep-Rupture Tested Cast Alloys HR282, IN740 and 263 for Possible Application in Advanced Ultrasupercritical Steam Turbine and Boiler

    SciTech Connect (OSTI)

    Jablonski, P D; Evens, N; Yamamoto, Y; Maziasz, P

    2011-02-27

    Cast forms of traditionally wrought Ni-base precipitation-strengthened superalloys are being considered for service in the ultra-supercritical conditions (760°C, 35MPa) of next-generation steam boilers and turbines. After casting and homogenization, these alloys were given heat-treatments typical for each in the wrought condition to develop the gamma-prime phase. Specimens machined from castings were creep-rupture tested in air at 800°C. In their wrought forms, alloy 282 is expected to precipitate M23C6 within grain boundaries, alloy 740 is expected to precipitate several grain boundary phases including M23C6, G Phase, and η phase, and alloy 263 has M23C6 and MC within its grain boundaries. This presentation will correlate the observed creep-life of these cast alloys with the microstructures developed during creep-rupture tests, with an emphasis on the phase identification and chemistry of precipitated grain boundary phases. The suitability of these cast forms of traditionally wrought alloys for turbine and boiler components will also be discussed.

  6. Combined Heat and Power Integrated with Burners for Packaged Boilers

    SciTech Connect (OSTI)

    2010-10-01

    This factsheet describes a project that will seamlessly integrate a gas-fired simple-cycle 100 kWe microturbine with a new ultra-low NOx gas-fired burner to develop a CHP assembly called the Boiler Burner Energy System Technology.

  7. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year

  8. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to

  9. Biomass Boiler for Food Processing Applications | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Boiler for Food Processing Applications Biomass Boiler for Food Processing Applications Biomass Boiler Uses a Combination of Wood Waste and Tire-Derived Fuel In 2011, the ...

  10. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-10-27

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2005.

  11. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-04-27

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  12. Boiler Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-01-31

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2005.

  13. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2004-10-30

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April to June 30, 2004.

  14. Improve Your Boiler's Combustion Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE)

    This tip sheet outlines how to improve boiler combustion efficiency as part of an optimized steam system.

  15. Recover Heat from Boiler Blowdown, Energy Tips: STEAM, Steam...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 Recover Heat from Boiler Blowdown Heat can be recovered from boiler blowdown by using a heat exchanger to preheat boiler makeup water. Any boiler with continuous blowdown ...

  16. materials | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials for Advanced Steam Cycles Materials for Ultra-Supercritical Coal-Fired Power Plant Boilers R. Viswanathan, EPRI Presentation Coal Ash Corrosion Resistant Materials ...

  17. Minimize Boiler Short Cycling Losses

    Office of Energy Efficiency and Renewable Energy (EERE)

    This tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  18. Return Condensate to the Boiler

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on returning condensate to boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  19. Improve Your Boiler's Combustion Efficiency

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on boiler combustion efficiency provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  20. Supercritical CO2 Tech Team

    Broader source: Energy.gov [DOE]

    Supercritical CO2 is a highly technical team focused on different heat source applications of the sCO2 Brayton Cycle.

  1. Supercritical fluid reverse micelle systems

    DOE Patents [OSTI]

    Fulton, John L.; Smith, Richard D.

    1992-01-01

    of 1 ) United States Patent 5,158,704 Fulton ,   et al. October 27, 1992 Supercritical fluid reverse micelle systems

  2. Supercritical Carbon Dioxide / Reservoir Rock Chemical Interactions...

    Open Energy Info (EERE)

    Supercritical Carbon Dioxide Reservoir Rock Chemical Interactions Jump to: navigation, search Geothermal Lab Call Projects for Supercritical Carbon Dioxide Reservoir Rock...

  3. Preparation, Injection and Combustion of Supercritical Fluids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation ...

  4. Boiler Maximum Achievable Control Technology (MACT) Technical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Boiler Maximum Achievable Control Technology (MACT) Technical Assistance - Fact Sheet, April 2015 Boiler Maximum Achievable Control Technology (MACT) Technical Assistance - Fact ...

  5. Boiler Combustion Control and Monitoring System | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... What Were the Benefits? boilercombustionchart.jpg The boiler combustion control and monitoring system was installed on a 25 MMBtuhr steam boiler located at the Watervliet ...

  6. Small boiler uses waste coal

    SciTech Connect (OSTI)

    Virr, M.J.

    2009-07-15

    Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

  7. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers This fact sheet describes a supercritical carbon ...

  8. Temperature Evolution and Oxide Growth in Waterwall Tubes of Supercritical Units

    SciTech Connect (OSTI)

    Sabau, Adrian S; Wright, Ian G; Zhang, Wei; Pint, Bruce A; Unocic, Kinga A

    2010-01-01

    In order to understand the failures in some waterwall tubes of supercritical steam boilers, an analysis is required to estimate the temperature of the waterwall tubes and the oxide growth in these tubes. A review on the thermophysical properties of oxide grown in waterwall tubes was conducted. Specimens of waterwall tubes associated with thermal fatigue cracking were obtained and microstructural analyses, using metallographic and electron-optical techniques such as SEM and electron-probe microanalysis, were performed. A computer model is being developed to estimate the maximum temperature in waterwall tubes by considering several phenomena that take place in supercritical units. The comprehensive model includes the following boiler operation features and phenomena: oxide growth, distribution of the heat flux on the waterwall tube as a function of height distance, variation of steam flow rate due to load variation, variation of heat flux due to load variation, and variation of the heat transfer coefficient with steam conditions and furnace heat flux. The model will handle the transition subcritical-to-supercritical and will account for the heat transfer deterioration phenomena in tubes. The tube regions with deteriorated heat transfer regimes will be identified. The temperatures of steam, metal, and oxide will be obtained as a function of the height distance in the boiler. The mixing effects of the steam from different waterwall tubes and subsequent fluid dynamics effects on the heat transfer will be considered. The new model will enable the prediction of the maximum metal temperature for realistic boiler operation schedule, which include transitions from full-to-low loads. Based on the estimated data for the steam temperature, metal temperature, and oxide thickness, regions of the waterwall tubes that are exposed to the most severe conditions will be identified.

  9. Utilizing Supplemental Ultra-Low-NO

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supplemental Ultra-Low-NO x Burner Technology to Meet Emissions Standards and Improve System Efficiency This project developed a Flexible Combined Heat and Power (FlexCHP) system that incorporates new burner technology into a 65-kilowatt (kW) microturbine and 100-horsepower (HP) heat recovery boiler. Introduction A combined heat and power (CHP) system can be a fnancially attractive energy option for many industrial and commercial facilities. This is particularly the case in areas of the country

  10. Minimize Boiler Short Cycling Losses | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Minimize Boiler Short Cycling Losses Minimize Boiler Short Cycling Losses This tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial...

  11. Minimize Boiler Short Cycling Losses, Energy Tips: STEAM, Steam...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 Minimize Boiler Short Cycling Losses Boiler "short cycling" occurs when an oversized boiler quickly satisfes process or space heating demands, and then shuts down until heat is ...

  12. Best Management Practice #8: Steam Boiler Systems | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8: Steam Boiler Systems Best Management Practice 8: Steam Boiler Systems Steam boilers are commonly used in large heating systems, institutional kitchens, or in facilities where ...

  13. Purchasing Energy-Efficient Residential Gas Boilers | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas Boilers Purchasing Energy-Efficient Residential Gas Boilers The Federal Energy Management Program (FEMP) provides acquisition guidance for residential gas boilers, a product ...

  14. Minimize Boiler Short Cycling Losses

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  15. Recover Heat from Boiler Blowdown

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on recovering heat from boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  16. Boiler-turbine life extension

    SciTech Connect (OSTI)

    Natzkov, S.; Nikolov, M.

    1995-12-01

    The design life of the main power equipment-boilers and turbines is about 105 working hours. The possibilities for life extension are after normatively regulated control tests. The diagnostics and methodology for Boilers and Turbines Elements Remaining Life Assessment using up to date computer programs, destructive and nondestructive control of metal of key elements of units equipment, metal creep and low cycle fatigue calculations. As well as data for most common damages and some technical decisions for elements life extension are presented.

  17. Supercritical CO2-Brayton Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supercritical CO2-Brayton Cycle - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs

  18. Furnaces and Boilers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Home Heating Systems » Furnaces and Boilers Furnaces and Boilers Upgrading to a high efficiency furnace or boiler is an effective way to save money on home heating. Upgrading to a high efficiency furnace or boiler is an effective way to save money on home heating. Most U.S. homes are heated with either furnaces or boilers. Furnaces heat air and distribute the heated air through the house using ducts. Boilers heat water, and provide either hot water or steam for heating. Steam is distributed via

  19. Gas-Fired Boilers and Furnaces | Department of Energy

    Energy Savers [EERE]

    A vent damper prevents chimney losses by closing off a boiler's vent when the boiler isn't firing. Steam boilers benefit from vent dampers more than hot water boilers, and bigger ...

  20. Boiler using combustible fluid

    DOE Patents [OSTI]

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  1. NOx Control for Utility Boiler OTR Compliance

    SciTech Connect (OSTI)

    Hamid Farzan

    2003-12-31

    Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), the Babcock and Wilcox Company (B and W), and Fuel Tech teamed together to investigate an integrated solution for NO{sub x} control. The system is comprised of B and W's DRB-4Z{trademark} ultra low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NOxOUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. Development of the low-NO{sub x} burner technology has been a focus in B and W's combustion program. The DRB-4Z{trademark} burner is B and W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by controlled mixing of the fuel and air. Based on data from several 500 to 600 MWe boilers firing PRB coal, NOx emissions levels of 0.15 to 0.20 lb/ 106 Btu have been achieved from the DRB-4Z{trademark} burners in combination with overfire air ports. Although NOx emissions from the DRB-4Z{trademark} burner are nearing the Ozone Transport Rule (OTR) level of 0.15 lb NO{sub x}/106 Btu, the utility boiler owners can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them. Large-scale testing is planned in B and W's 100-million Btu/hr Clean Environment Development Facility (CEDF) that simulates the conditions of large coal-fired utility boilers. The objective of the project is to achieve a NO{sub x} level below 0.15 lb/106 Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B and W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign}. During this period B and W prepared and submitted the project management plan and hazardous substance plan to DOE. The negotiation of a subcontract for Fuel Tech has been started.

  2. Ultra Violet Waterworks (UVW)

    Office of Scientific and Technical Information (OSTI)

    Ultra Violet Waterworks Water Disinfecting Device Saves Lives Resources with Additional Information Ultra Violet Waterworks (UVW) device Ultra Violet Waterworks (UVW) is a...

  3. Next Generation Engineered Materials for Ultra Supercritical Steam Turbines

    SciTech Connect (OSTI)

    Douglas Arrell

    2006-05-31

    To reduce the effect of global warming on our climate, the levels of CO{sub 2} emissions should be reduced. One way to do this is to increase the efficiency of electricity production from fossil fuels. This will in turn reduce the amount of CO{sub 2} emissions for a given power output. Using US practice for efficiency calculations, then a move from a typical US plant running at 37% efficiency to a 760 C /38.5 MPa (1400 F/5580 psi) plant running at 48% efficiency would reduce CO2 emissions by 170kg/MW.hr or 25%. This report presents a literature review and roadmap for the materials development required to produce a 760 C (1400 F) / 38.5MPa (5580 psi) steam turbine without use of cooling steam to reduce the material temperature. The report reviews the materials solutions available for operation in components exposed to temperatures in the range of 600 to 760 C, i.e. above the current range of operating conditions for today's turbines. A roadmap of the timescale and approximate cost for carrying out the required development is also included. The nano-structured austenitic alloy CF8C+ was investigated during the program, and the mechanical behavior of this alloy is presented and discussed as an illustration of the potential benefits available from nano-control of the material structure.

  4. Sootblowing optimization for improved boiler performance

    DOE Patents [OSTI]

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J

    2013-07-30

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  5. Sootblowing optimization for improved boiler performance

    DOE Patents [OSTI]

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J.

    2012-12-25

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  6. CHP Integrated with Burners for Packaged Boilers

    SciTech Connect (OSTI)

    Castaldini, Carlo; Darby, Eric

    2013-09-30

    The objective of this project was to engineer, design, fabricate, and field demonstrate a Boiler Burner Energy System Technology (BBEST) that integrates a low-cost, clean burning, gas-fired simple-cycle (unrecuperated) 100 kWe (net) microturbine (SCMT) with a new ultra low-NOx gas-fired burner (ULNB) into one compact Combined Heat and Power (CHP) product that can be retrofit on new and existing industrial and commercial boilers in place of conventional burners. The Scope of Work for this project was segmented into two principal phases: (Phase I) Hardware development, assembly and pre-test and (Phase II) Field installation and demonstration testing. Phase I was divided into five technical tasks (Task 2 to 6). These tasks covered the engineering, design, fabrication, testing and optimization of each key component of the CHP system principally, ULNB, SCMT, assembly BBEST CHP package, and integrated controls. Phase I work culminated with the laboratory testing of the completed BBEST assembly prior to shipment for field installation and demonstration. Phase II consisted of two remaining technical tasks (Task 7 and 8), which focused on the installation, startup, and field verification tests at a pre-selected industrial plant to document performance and attainment of all project objectives. Technical direction and administration was under the management of CMCE, Inc. Altex Technologies Corporation lead the design, assembly and testing of the system. Field demonstration was supported by Leva Energy, the commercialization firm founded by executives at CMCE and Altex. Leva Energy has applied for patent protection on the BBEST process under the trade name of Power Burner and holds the license for the burner currently used in the product. The commercial term Power Burner is used throughout this report to refer to the BBEST technology proposed for this project. The project was co-funded by the California Energy Commission and the Southern California Gas Company (SCG), a

  7. Covered Product Category: Commercial Boilers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance and Federal efficiency requirements for commercial boilers, which is a FEMP-designated product category. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

  8. DB Riley-low emission boiler system (LEBS): Superior power for the 21st century

    SciTech Connect (OSTI)

    Beittel, R.; Ruth, L.A.

    1997-12-31

    In conjunction with the US Department of Energy, DB Riley, Inc., is developing a highly advanced coal-fired power-generation plant called the Low Emission Boiler Systems (LEBS). By the year 2000, LEBS will provide the US electric power industry with a reliable, efficient, cost-effective, environmentally superior alternative to current technologies. LEBS incorporates significant advances in coal combustion, supercritical steam boiler design, environmental control, and materials development. The system will include a state-of-the-art steam cycle operating at supercritical steam conditions; a slagging combustor that produces vitrified ash by-products; low nitrogen oxide (NOx) burners; a new, dry, regenerable flue gas cleanup system (copper oxide process) for simultaneously capturing sulfur dioxide (SO{sub 2}) and nitrogen oxides (NOx); a pulse-jet fabric filter for particulate capture; and a low-temperature heat-recovery system. The copper oxide flue gas cleanup system, which has been under development at DOE`s Pittsburgh field center, removes over 98% of SO{sub 2} and 95% of NOx from flue gas. A new moving-bed design provides efficient sorbent utilization that lowers the cleanup process cost. The captured SO{sub 2} can be converted to valuable by-products such as sulfuric acid and/or element sulfur, and the process generates no waste.

  9. Boiler - tuning basics, part 1

    SciTech Connect (OSTI)

    Leopold, T.

    2009-03-15

    Tuning power plant controls takes nerves of steel and an intimate knowledge of plant systems gained only by experience. Tuning controls also requires equal parts art and science, which probably is why there are so few tuning experts in the power industry. In part 1 of a two-part series, the author explores a mix of the theoretical and practical aspects of tuning boiler control. 5 figs.

  10. Fluidized bed boiler feed system

    DOE Patents [OSTI]

    Jones, Brian C.

    1981-01-01

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  11. Unmanned boiler operation a reality in Europe

    SciTech Connect (OSTI)

    Ilg, E.

    1996-08-01

    With the rise in liquid level technology in Europe comes new standards for boiler operation. SMART technology for level probes and auxiliary equipment, means many European countries allow a boiler to operate completely unmanned (without operators) for up to 72 hours at a time. It is not just a level control system, but a total boiler control scheme. This incorporates level control, continuous TDS monitoring with blowdown, automatic timed bottom blowdown, feed water control, contamination detection systems for monitoring of incoming feed water, monitoring of exhaust stack temperatures, over pressure alarms and timed automatic blowdown of level pots. One of the main reasons for the development of the SMART equipment and the new boiler codes was to increase reliability of boiler operation. Surveys in Germany and England showed that almost 90 percent of boiler failures was due to operator error, this has almost been eliminated through the use of new equipment based on the new codes.

  12. Metallurgical failures in fossil fired boilers

    SciTech Connect (OSTI)

    French, D.N.

    1993-01-01

    This book provides a comprehensive catalog of the types of metallurgical failures common to boilers. The author uses actual case histories of boiler shutdowns, and documents the full range of causes of boiler tube failure. A blueprint is provided for cutting maintenance costs and upgrading the efficiency and reliability of any power plant operation. Individual chapters are processed separately for inclusion in the appropriate data bases.

  13. Nano Particles - Supercritical Fluid Process - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search Nano Particles ... Applications and Industries Nano particles, supercritical fluid, photovoltaic devices, ...

  14. Project Profile: Lifetime Model Development for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    model for materials in supercritical carbon dioxide (sCO2) conditions similar to concentrated solar power (CSP) applications. ... heat transfer fluid or the power cycle working fluid. ...

  15. Supercritical plants to come online in 2009

    SciTech Connect (OSTI)

    Spring, N.

    2009-07-15

    A trio of coal-fired power plants using supercritical technology set to enter service this year. These are: We Energies is Elm Road Generating Station in Wisconsin, a two-unit, 1,230 MW supercritical plant that will burn bituminous coal; a 750 MW supercritical coal-fired power plant at the Comanche Generating Station in Pueblo, Colo., the third unit at the site; and Luminant's Oak Grove plant in Texas which will consist of two supercritical, lignite-fueled power generation units. When complete, the plant will deliver about 1,6000 MW. Some details are given on each of these projects. 2 photos.

  16. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine NREL logo -- This project is inactive -- The ...

  17. EGS rock reactions with Supercritical CO2 saturated with water...

    Office of Scientific and Technical Information (OSTI)

    Conference: EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2 Citation Details In-Document Search Title: EGS rock reactions ...

  18. Ganglion dynamics of Supercritical CO2 in heterogeneous media...

    Office of Scientific and Technical Information (OSTI)

    Ganglion dynamics of Supercritical CO2 in heterogeneous media. Citation Details In-Document Search Title: Ganglion dynamics of Supercritical CO2 in heterogeneous media. Abstract ...

  19. Project Profile: Physics-Based Reliability Models for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Physics-Based Reliability Models for Supercritical-CO2 Turbomachinery Components Project Profile: Physics-Based Reliability Models for Supercritical-CO2 Turbomachinery Components ...

  20. Evaluation of Biodiesel Fuels from Supercritical Fluid Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced ...

  1. Volatility of Gasoline and Diesel Fuel Blends for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced ...

  2. Supercritical/Solid Catalyst (SSC)

    SciTech Connect (OSTI)

    2010-01-01

    INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

  3. Supercritical/Solid Catalyst (SSC)

    ScienceCinema (OSTI)

    None

    2013-05-28

    INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

  4. Recuperative supercritical carbon dioxide cycle

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

    2014-11-18

    A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

  5. Minimize Boiler Blowdown - Steam Tip Sheet #9

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  6. Upgrade Boilers with Energy-Efficient Burners

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP steam tip sheet on upgrading boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  7. Stress-Assisted Corrosion in Boiler Tubes

    SciTech Connect (OSTI)

    Preet M Singh; Steven J Pawel

    2006-05-27

    A number of industrial boilers, including in the pulp and paper industry, needed to replace their lower furnace tubes or decommission many recovery boilers due to stress-assisted corrosion (SAC) on the waterside of boiler tubes. More than half of the power and recovery boilers that have been inspected reveal SAC damage, which portends significant energy and economic impacts. The goal of this project was to clarify the mechanism of stress-assisted corrosion (SAC) of boiler tubes for the purpose of determining key parameters in its mitigation and control. To accomplish this in-situ strain measurements on boiler tubes were made. Boiler water environment was simulated in the laboratory and effects of water chemistry on SAC initiation and growth were evaluated in terms of industrial operations. Results from this project have shown that the dissolved oxygen is single most important factor in SAC initiation on carbon steel samples. Control of dissolved oxygen can be used to mitigate SAC in industrial boilers. Results have also shown that sharp corrosion fatigue and bulbous SAC cracks have similar mechanism but the morphology is different due to availability of oxygen during boiler shutdown conditions. Results are described in the final technical report.

  8. Oil-Fired Boilers and Furnaces | Department of Energy

    Office of Environmental Management (EM)

    Oil-Fired Boilers and Furnaces Oil-Fired Boilers and Furnaces Diagram of an oil boiler. New tanks are generally double-wall or have a spill container built underneath to reduce the ...

  9. Oil-Fired Boilers and Furnaces | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oil-Fired Boilers and Furnaces Oil-Fired Boilers and Furnaces May 16, 2013 - 3:15pm Addthis Diagram of an oil boiler. New tanks are generally double-wall or have a spill container...

  10. Upgrade Boilers with Energy-Efficient Burners | Department of...

    Energy Savers [EERE]

    STEAM TIP SHEET 24 Upgrade Boilers with Energy-Efficient Burners (January 2012) (416.98 ... Improve Your Boiler's Combustion Efficiency Minimize Boiler Short Cycling Losses J.R. ...

  11. Return Condensate to the Boiler | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Return Condensate to the Boiler Return Condensate to the Boiler This tip sheet on returning condensate to boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET #8 Return Condensate to the Boiler (January 2012) (433.53 KB) More Documents & Publications Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Minimize Boiler Blowdown Consider Installing High-Pressure Boilers with Backpressure

  12. Boiler efficiency calculation for multiple fuel burning boilers

    SciTech Connect (OSTI)

    Khodabakhsh, F.; Munukutla, S.; Clary, A.T.

    1996-12-31

    A rigorous method based on the output/loss approach is developed for calculating the coal flow rate for multiple fuel burning boilers. It is assumed that the ultimate analyses of all the fuels are known. In addition, it is assumed that the flow rates of all the fuels with the exception of coal are known. The calculations are performed iteratively, with the first iteration taking into consideration coal as the only fuel. The results converge to the correct answer after a few number of iterations, typically four or five.

  13. Paducah Package Steam Boilers to Provide Efficiency, Environmental Benefits

    Broader source: Energy.gov [DOE]

    PADUCAH, Ky. – Five modern, modular steam boilers have replaced three larger coal-fired boilers that comprised the steam plant at EM’s Paducah Site.

  14. Clean Firetube Boiler Waterside Heat Transfer Surfaces, Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7 Clean Firetube Boiler Waterside Heat Transfer Surfaces The prevention of scale formation in fretube boilers can result in substantial energy savings. Scale deposits occur when ...

  15. Improve Your Boiler's Combustion Efficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improve Your Boiler's Combustion Efficiency This tip sheet outlines how to improve boiler combustion efficiency as part of an optimized steam system. STEAM TIP SHEET 4 Improve...

  16. Improve Your Boiler's Combustion Efficiency, Energy Tips: STEAM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improve Your Boiler's Combustion Efficiency Combustion Efficiency Operating your boiler with an optimum amount of excess air will minimize heat loss up the stack and improve ...

  17. Boiler Upgrades and Decentralizing Steam Systems Save Water and...

    Energy Savers [EERE]

    Boiler Upgrades and Decentralizing Steam Systems Save Water and Energy at Naval Air Station Oceana Boiler Upgrades and Decentralizing Steam Systems Save Water and Energy at Naval ...

  18. Recovery of Water from Boiler Flue Gas Using Condensing Heat...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers Citation Details In-Document Search Title: Recovery of Water from Boiler Flue Gas Using ...

  19. Paducah Package Steam Boilers to Provide Efficiency, Environmental...

    Broader source: Energy.gov (indexed) [DOE]

    PADUCAH, Ky. - Five modern, modular steam boilers have replaced three larger coal-fired boilers that comprised the steam plant at EM's Paducah Site. Moving to the more ...

  20. Winning the fight against boiler tube failure

    SciTech Connect (OSTI)

    Cohen, J.; Dooley, B.

    1986-12-01

    Eliminating boiler tube failures could be worth $5 billion a year to the electric power industry. The causes and cures for the great majority of these ubiquitous failures are now known, with implications for change ranging from senior management to the maintenance crew. Methods for preventing boiler tube failure are discussed.

  1. The solvated electron in supercritical water

    SciTech Connect (OSTI)

    Bartels, D. M.; Takahashi, K.; Cline, J.; Jonah, C. D.

    2000-03-09

    In order to investigate the feasibility for high-efficiency supercritical-water-cooled nuclear reactors, a study of radiation chemistry in supercritical water has been undertaken. Preliminary results in measurement of the optical absorption of the hydrated electron are reported, and compared with recent anion cluster data.

  2. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  3. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, C.L.; Foote, J.P.

    1995-07-04

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

  4. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, Charles L.; Foote, John P.

    1995-01-01

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

  5. Wood fuel in fluidized bed boilers

    SciTech Connect (OSTI)

    Virr, M.J.

    1982-01-01

    Development of fluidized bed fire-tube and water-tube boilers for the burning of wood, gas, and refuse-derived fuel will be reviewed. Experience gained in already installed plants will be outlined. Research experiments results on the use of various forms of wood and other biomass fuels, such as wood chips, pellets, peach pits, nut shells and kernels and refuse-derived fuels, will be described for small and medium sized fire-tube boilers, and for larger water-tube boilers for co-generation. (Refs. 4).

  6. Geothermal energy production with supercritical fluids

    DOE Patents [OSTI]

    Brown, Donald W.

    2003-12-30

    There has been invented a method for producing geothermal energy using supercritical fluids for creation of the underground reservoir, production of the geothermal energy, and for heat transport. Underground reservoirs are created by pumping a supercritical fluid such as carbon dioxide into a formation to fracture the rock. Once the reservoir is formed, the same supercritical fluid is allowed to heat up and expand, then is pumped out of the reservoir to transfer the heat to a surface power generating plant or other application.

  7. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2015-06-09

    A system and method for reactively refining hydrocarbons, such as heavy oils with API gravities of less than 20 degrees and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure, using a selected fluid at supercritical conditions. A reaction portion of the system and method delivers lightweight, volatile hydrocarbons to an associated contacting unit which operates in mixed subcritical/supercritical or supercritical modes. Using thermal diffusion, multiphase contact, or a momentum generating pressure gradient, the contacting unit separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques.

  8. Boiler scale prevention employing an organic chelant

    DOE Patents [OSTI]

    Wallace, Steven L.; Griffin, Jr., Freddie; Tvedt, Jr., Thorwald J.

    1984-01-01

    An improved method of treating boiler water which employs an oxygen scavenging compound and a compound to control pH together with a chelating agent, wherein the chelating agent is hydroxyethylethylenediaminetriacetic acid.

  9. Furnace and Boiler Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Boilers consist of a vessel or tank where heat produced from the combustion of such fuels as natural gas, fuel oil, or coal is used to generate hot water or steam. Many buildings ...

  10. Furnace and Boiler Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2:50pm Addthis Furnaces heat air and distribute the heated air through a building using ducts; boilers heat water, providing either hot water or steam for heating. Furnaces...

  11. Clean Boiler Waterside Heat Transfer Surfaces

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  12. Supercritical fluid reverse micelle separation

    DOE Patents [OSTI]

    Fulton, John L.; Smith, Richard D.

    1993-01-01

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W.sub.o that determines the maximum size of the reverse micelles. The maximum ratio W.sub.o of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions.

  13. Supercritical fluid reverse micelle separation

    DOE Patents [OSTI]

    Fulton, J.L.; Smith, R.D.

    1993-11-30

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W[sub o] that determines the maximum size of the reverse micelles. The maximum ratio W[sub o] of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions. 27 figures.

  14. 10-MW Supercritical-CO2 Turbine

    Broader source: Energy.gov [DOE]

    This fact sheet describes a 10-megawatt supercritical carbon dioxide turbine project, awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The research team, led by NREL, intends to showcase the turbomachinery for a new cycle—the supercritical carbon dioxide (s-CO2) Brayton cycle. The cycle is being optimized and tested at conditions representing dry cooling in desert environments, thereby accurately simulating real-world concentrating solar power system operating conditions.

  15. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2003-10-31

    The objective of this project is to develop an improved ultra- lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report discusses testing that was performed for analyzing the alkali-silica reactivity of ULHS in cement slurries.

  16. CX-005589: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Computational Modeling and Assessment of Nanocoatings for Ultra Supercritical BoilersCX(s) Applied: B3.6Date: 04/11/2011Location(s): Golden, ColoradoOffice(s): Fossil Energy, National Energy Technology Laboratory

  17. CX-005592: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Computational Modeling and Assessment of Nanocoatings for Ultra Supercritical BoilersCX(s) Applied: A1, A9Date: 04/11/2011Location(s): Charlotte, North CarolinaOffice(s): Fossil Energy, National Energy Technology Laboratory

  18. CX-005591: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Computational Modeling and Assessment of Nanocoatings for Ultra Supercritical BoilersCX(s) Applied: A9, B3.6Date: 04/11/2011Location(s): Livingston, New JerseyOffice(s): Fossil Energy, National Energy Technology Laboratory

  19. CX-005590: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Computational Modeling and Assessment of Nanocoatings for Ultra Supercritical BoilersCX(s) Applied: B3.6Date: 04/11/2011Location(s): San Antonio, TexasOffice(s): Fossil Energy, National Energy Technology Laboratory

  20. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2001-07-18

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). Work reported herein addresses Task 1: Assess Ultra-Lightweight Cementing Issues, Task 2: Review Russian Ultra-Lightweight Cement Literature, Task 3: Test Ultra-Lightweight Cements, and Task 8: Develop Field ULHS Cement Blending and Mixing Techniques. Results reported this quarter include: preliminary findings from a literature review focusing on problems associated with ultra-lightweight cements; summary of pertinent information from Russian ultra-lightweight cement literature review; laboratory tests comparing ULHS slurries to foamed slurries and sodium silicate slurries for two different applications; and initial laboratory studies with ULHS in preparation for a field job.

  1. Boiler MACT Technical Assistance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-03-01

    Fact sheet describing the changes to Environmental Protection Act process standards. The DOE will offer technical assistance to ensure that major sources burning coal and oil have information on cost-effective, clean energy strategies for compliance, and to promote cleaner, more efficient boiler burning to cut harmful pollution and reduce operational costs. The U.S. Environmental Protection Agency (EPA) is expected to finalize the reconsideration process for its Clean Air Act pollution standards National Emissions Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers and Process Heaters (known as Boiler Maximum Achievable Control Technology (MACT)), in Spring 2012. This rule applies to large and small boilers in a wide range of industrial facilities and institutions. The U.S. Department of Energy (DOE) will offer technical assistance to ensure that major sources burning coal or oil have information on cost-effective clean energy strategies for compliance, including combined heat and power, and to promote cleaner, more efficient boilers to cut harmful pollution and reduce operational costs.

  2. Boiler house modernization through shared savings program

    SciTech Connect (OSTI)

    Breault, R.W.

    1995-12-31

    Throughout Poland as well as the rest of Eastern Europe, communities and industries rely on small heat only boilers to provide district and process heat. Together these two sectors produce about 85,000 MW from boilers in the 2 to 35 MW size range. The bulk of these units were installed prior to 1992 and must be completely overhauled to meet the emission regulations which will be coming into effect on January 1, 1998. Since the only practical fuel is coal in most cases, these boilers must be either retrofit with emission control technology or be replaced entirely. The question that arises is how to accomplish this given the current tight control of capital in Poland and other East European countries. A solution that we have for this problem is shared savings. These boilers are typically operating with a quiet low efficiency as compared to western standards and with excessive manual labor. Installing modernization equipment to improve the efficiency and to automate the process provides savings. ECOGY provides the funds for the modernization to improve the efficiency, add automation and install emission control equipment. The savings that are generated during the operation of the modernized boiler system are split between the client company and ECOGY for a number of years and then the system is turned over in entirety to the client. Depending on the operating capacity, the shared savings agreement will usually span 6 to 10 years.

  3. Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection | Department of Energy Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be used in diesel engines having efficient fuel systems and combustion chamber designs that decrease fuel consumption and mitigate emissions. p-02_anitescu.pdf (339.45 KB) More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of

  4. Advanced Supercritical Carbon Dioxide Brayton Cycle Development

    SciTech Connect (OSTI)

    Anderson, Mark; Sienicki, James; Moisseytsev, Anton; Nellis, Gregory; Klein, Sanford

    2015-10-21

    Fluids operating in the supercritical state have promising characteristics for future high efficiency power cycles. In order to develop power cycles using supercritical fluids, it is necessary to understand the flow characteristics of fluids under both supercritical and two-phase conditions. In this study, a Computational Fluid Dynamic (CFD) methodology was developed for supercritical fluids flowing through complex geometries. A real fluid property module was implemented to provide properties for different supercritical fluids. However, in each simulation case, there is only one species of fluid. As a result, the fluid property module provides properties for either supercritical CO2 (S-CO2) or supercritical water (SCW). The Homogeneous Equilibrium Model (HEM) was employed to model the two-phase flow. HEM assumes two phases have same velocity, pressure, and temperature, making it only applicable for the dilute dispersed two-phase flow situation. Three example geometries, including orifices, labyrinth seals, and valves, were used to validate this methodology with experimental data. For the first geometry, S-CO2 and SCW flowing through orifices were simulated and compared with experimental data. The maximum difference between the mass flow rate predictions and experimental measurements is less than 5%. This is a significant improvement as previous works can only guarantee 10% error. In this research, several efforts were made to help this improvement. First, an accurate real fluid module was used to provide properties. Second, the upstream condition was determined by pressure and density, which determines supercritical states more precise than using pressure and temperature. For the second geometry, the flow through labyrinth seals was studied. After a successful validation, parametric studies were performed to study geometric effects on the leakage rate. Based on these parametric studies, an optimum design strategy for the see

  5. Minimize Boiler Blowdown, Energy Tips: STEAM, Steam Tip Sheet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    may lead to carryover of boiler water into the steam, or the formation of deposits. ... 108,696 - 106,383 2,313 lbhr Enthalpy of Boiler Water 338.5 Btulb; for ...

  6. Energy Cost Savings Calculator for Commercial Boilers: Closed...

    Office of Environmental Management (EM)

    Water Steam What fuel is used? Gas Oil How many boilers will you purchase? unit(s) Performance Factors Existing What is the capacity of the existing boiler? MBtuhr* What is the ...

  7. Project Profile: Direct Supercritical Carbon Dioxide Receiver Development |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Direct Supercritical Carbon Dioxide Receiver Development Project Profile: Direct Supercritical Carbon Dioxide Receiver Development National Renewable Energy Laboratory logo -- This project is inactive -- The National Renewable Energy Laboratory (NREL), under the National Laboratory R&D competitive funding opportunity, is working to develop, characterize, and experimentally demonstrate a novel high-temperature receiver technology using supercritical carbon dioxide

  8. Consider Installing High-Pressure Boilers with Backpressure

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Turbine-Generators | Department of Energy High-Pressure Boilers with Backpressure Turbine-Generators Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators This tip sheet outlines the benefits of high-pressure boilers with backpressure turbine-generators as part of optimized steam systems. STEAM TIP SHEET #22 Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators (January 2012) (513.44 KB) More Documents & Publications Replace

  9. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, Pascal M.

    1982-01-01

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carry-over through the turbine causes corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  10. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, P.M.

    1979-12-27

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carryover through the turbine causing corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  11. Slag monitoring for utility boilers: Final report

    SciTech Connect (OSTI)

    Anson, D.; Barrett, R.E.; Litt, R.D.; Paisley, M.A.

    1988-04-01

    This report provides a detailed description of commercially available slag monitoring techniques and some developing concepts for slag monitoring. Slag monitoring is currently being evaluated by several organizations as a means of controlling and optimizing sootblowers. The potential benefits from slag monitoring can represent significant savings in utility operating costs. Six types of heat flux meters are described as they are presently being used in utility boilers. These direct monitoring techniques determine local conditions within the furnace. Each application is described with current results and future plans. Boiler heat balance models provide an indirect technique for monitoring the general cleanliness/fouling of major boiler sections. Each model is described with current results at a representative installation. Several developing concepts of slag monitoring are described and evaluated. Four promising concepts, acoustic attenuation, a simplified heat balance model, sonic pyrometry, and ultrasonic pulse reflection, are recommended for further development and evaluation. 16 refs., 34 figs., 4 tabs.

  12. Feasibility Study of Supercritical Light Water Cooled Reactors for Electric Power Production, Progress Report for Work Through September 2003, 2nd Annual/8th Quarterly Report

    SciTech Connect (OSTI)

    Philip E. MacDonald

    2003-09-01

    The supercritical water-cooled reactor (SCWR) is one of the six reactor technologies selected for research and development under the Generation-IV program. SCWRs are promising advanced nuclear systems because of their high thermal efficiency (i.e., about 45% vs. about 33% efficiency for current Light Water Reactors, LWRs) and considerable plant simplification. SCWRs are basically LWRs operating at higher pressure and temperatures with a direct once-through cycle. Operation above the critical pressure eliminates coolant boiling, so the coolant remains single-phase throughout the system. Thus the need for recirculation and jet pumps, a pressurizer, steam generators, steam separators and dryers is eliminated. The main mission of the SCWR is generation of low-cost electricity. It is built upon two proven technologies, LWRs, which are the most commonly deployed power generating reactors in the world, and supercritical fossil-fired boilers, a large number of which is also in use around the world.

  13. TA-2 Water Boiler Reactor Decommissioning Project

    SciTech Connect (OSTI)

    Durbin, M.E.; Montoya, G.M.

    1991-06-01

    This final report addresses the Phase 2 decommissioning of the Water Boiler Reactor, biological shield, other components within the biological shield, and piping pits in the floor of the reactor building. External structures and underground piping associated with the gaseous effluent (stack) line from Technical Area 2 (TA-2) Water Boiler Reactor were removed in 1985--1986 as Phase 1 of reactor decommissioning. The cost of Phase 2 was approximately $623K. The decommissioning operation produced 173 m{sup 3} of low-level solid radioactive waste and 35 m{sup 3} of mixed waste. 15 refs., 25 figs., 3 tabs.

  14. Waste combustion in boilers and industrial furnaces

    SciTech Connect (OSTI)

    1997-12-31

    This set of conference papers deals with the combustion of hazardous wastes in boilers and industrial furnaces. The majority of the papers pertain specifically to cement industry kiln incinerators and focus on environmental issues. In particular, stack emission requirements currently enforced or under consideration by the U.S. EPA are emphasized. The papers were drawn from seven areas: (1) proposed Maximum Achievable Control Technology rule, (2) trial burn planning and experience, (3) management and beneficial use of materials, (4) inorganic emissions and continuous emission monitoring, (5) organic emissions, (6) boiler and industrial furnace operations, and (7) risk assessment and communication.

  15. Ultra Violet Waterworks (UVW)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ultra Violet Waterworks Water Disinfecting Device Saves Lives Resources with Additional Information Ultra Violet Waterworks (UVW) device Ultra Violet Waterworks (UVW) is a small-scale, energy-efficient, and low-maintenance mechanism that uses ultraviolet light to cheaply disinfect water. It is a uniquely effective device that operates using the equivalent of a 60-Watt light bulb at a cost of as low as 4 cents/ton of water treated, treating 15 liters/minute, and providing enough drinking water

  16. Super Boiler: Packed Media/Transport Membrane Boiler Development and Demonstration

    SciTech Connect (OSTI)

    Liss, William E; Cygan, David F

    2013-04-17

    Gas Technology Institute (GTI) and Cleaver-Brooks developed a new gas-fired steam generation system the Super Boiler for increased energy efficiency, reduced equipment size, and reduced emissions. The system consists of a firetube boiler with a unique staged furnace design, a two-stage burner system with engineered internal recirculation and inter-stage cooling integral to the boiler, unique convective pass design with extended internal surfaces for enhanced heat transfer, and a novel integrated heat recovery system to extract maximum energy from the flue gas. With these combined innovations, the Super Boiler technical goals were set at 94% HHV fuel efficiency, operation on natural gas with <5 ppmv NOx (referenced to 3%O2), and 50% smaller than conventional boilers of similar steam output. To demonstrate these technical goals, the project culminated in the industrial demonstration of this new high-efficiency technology on a 300 HP boiler at Clement Pappas, a juice bottler located in Ontario, California. The Super Boiler combustion system is based on two stage combustion which combines air staging, internal flue gas recirculation, inter-stage cooling, and unique fuel-air mixing technology to achieve low emissions rather than external flue gas recirculation which is most commonly used today. The two-stage combustion provides lower emissions because of the integrated design of the boiler and combustion system which permit precise control of peak flame temperatures in both primary and secondary stages of combustion. To reduce equipment size, the Super Boiler's dual furnace design increases radiant heat transfer to the furnace walls, allowing shorter overall furnace length, and also employs convective tubes with extended surfaces that increase heat transfer by up to 18-fold compared to conventional bare tubes. In this way, a two-pass boiler can achieve the same efficiency as a traditional three or four-pass firetube boiler design. The Super Boiler is consequently up to

  17. Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Fox, Robert V.; Kong, Peter C.

    2000-01-01

    This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

  18. Evaluation of coal-derived liquids as boiler fuels. Volume 2: boiler test results. Final report

    SciTech Connect (OSTI)

    Not Available

    1985-09-01

    A combustion demonstration using six coal-derived liquid (CDL) fuels was conducted on a utility boiler located at the Plant Sweatt Electric Generating Station of Mississippi Power Company in Meridian, Mississippi. The test program was conducted in two phases. The first phase included the combustion tests of the two conventional fuels (natural gas and No. 6 fuel oil) and three coal-derived liquid fuels (Solvent Refined Coal-II full range distillate, H-Coal heavy distillate and H-Coal blended distillate). The second phase involved the evaluation of three additional CDL fuels (H-Coal light distillate, Exxon Donor Solvent full range distillate and Solvent Refined Coal-II middle distillate). The test boiler was a front wall-fired Babcock and Wilcox unit with a rated steam flow of 425,000 lb/h and a generating capacity of 40 MW. Boiler performance and emissions were evaluated with baseline and CDL fuels at 15, 25, 40 MW loads and at various excess air levels. Low NO/sub x/ (staged) combustion techniques were also implemented. Boiler performance monitoring included measurements for fuel steam and flue gas flow, pressure, temperature, and heat absorption, resulting in a calculated combustion efficiency, boiler efficiency, and heat rate. Emissions measurements included oxygen, carbon dioxide, carbon monoxide, oxides of nitrogen, sulfur dioxide, sulfur trioxide, acid dewpoint, particulate mass, size distribution and morphology, chlorides, and opacity. The test program demonstrated the general suitability of CDL fuels for use in existing oil-fired utility boilers. No significant boiler tube surface modifications will be required. The CDL fuels could be handled similarly to No. 2 oil with appropriate safety procedures and materials compatibility considerations. Volume 2 of a five-volume report contains the detailed boiler test results. 96 figs., 26 tabs.

  19. Purchasing Energy-Efficient Commercial Boilers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance and Federal efficiency requirements for commercial boilers, which is a FEMP-designated product category. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

  20. Best Management Practice #8: Steam Boiler Systems

    Office of Energy Efficiency and Renewable Energy (EERE)

    Boilers and steam generators are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size, the amount of steam used, and the amount of condensate returned.

  1. The next generation of oxy-fuel boiler systems

    SciTech Connect (OSTI)

    Ochs, Thomas L.; Gross, Alex; Patrick, Brian; Oryshchyn, Danylo B.; Summers, Cathy A.; Turner, Paul C.

    2005-01-01

    Research in the area of oxy-fuel combustion which is being pioneered by Jupiter Oxygen Corporation combined with boiler research conducted by the USDOE/Albany Research Center has been applied to designing the next generation of oxy-fuel combustion systems. The new systems will enhance control of boiler systems during turn-down and improve response time while improving boiler efficiency. These next generation boiler systems produce a combustion product that has been shown to be well suited for integrated pollutant removal. These systems have the promise of reducing boiler foot-print and boiler construction costs. The modularity of the system opens the possibility of using this design for replacement of boilers for retrofit on existing systems.

  2. Chemical deposition methods using supercritical fluid solutions

    DOE Patents [OSTI]

    Sievers, Robert E.; Hansen, Brian N.

    1990-01-01

    A method for depositing a film of a desired material on a substrate comprises dissolving at least one reagent in a supercritical fluid comprising at least one solvent. Either the reagent is capable of reacting with or is a precursor of a compound capable of reacting with the solvent to form the desired product, or at least one additional reagent is included in the supercritical solution and is capable of reacting with or is a precursor of a compound capable of reacting with the first reagent or with a compound derived from the first reagent to form the desired material. The supercritical solution is expanded to produce a vapor or aerosol and a chemical reaction is induced in the vapor or aerosol so that a film of the desired material resulting from the chemical reaction is deposited on the substrate surface. In an alternate embodiment, the supercritical solution containing at least one reagent is expanded to produce a vapor or aerosol which is then mixed with a gas containing at least one additional reagent. A chemical reaction is induced in the resulting mixture so that a film of the desired material is deposited.

  3. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2004-01-30

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report discusses testing that was performed for analyzing the alkali-silica reactivity of ULHS in cement slurries.

  4. Guide to Low-Emission Boiler and Combustion Equipment Selection

    SciTech Connect (OSTI)

    Oland, CB

    2002-05-06

    Boiler owners and operators who need additional generating capacity face a number of legal, political, environmental, economic, and technical challenges. Their key to success requires selection of an adequately sized low-emission boiler and combustion equipment that can be operated in compliance with emission standards established by state and federal regulatory agencies. Recognizing that many issues are involved in making informed selection decisions, the U.S. Department of Energy (DOE), Office of Industrial Technologies (OIT) sponsored efforts at the Oak Ridge National Laboratory (ORNL) to develop a guide for use in choosing low-emission boilers and combustion equipment. To ensure that the guide covers a broad range of technical and regulatory issues of particular interest to the commercial boiler industry, the guide was developed in cooperation with the American Boiler Manufacturers Association (ABMA), the Council of Industrial Boiler Owners (CIBO), and the U.S. Environmental Protection Agency (EPA). The guide presents topics pertaining to industrial, commercial, and institutional (ICI) boilers. Background information about various types of commercially available boilers is provided along with discussions about the fuels that they burn and the emissions that they produce. Also included are discussions about emissions standards and compliance issues, technical details related to emissions control techniques, and other important selection considerations. Although information in the guide is primarily applicable to new ICI boilers, it may also apply to existing boiler installations.

  5. Coal-fired boiler for petroleum refinery

    SciTech Connect (OSTI)

    Ketterman, W.R.; Heinzmann, D.A.

    1982-01-01

    There has been a significant amount of interest in conversion from oil/gas fired boilers to coal-fired equipment since the Arab oil embargo of 1973. The CRA Incorporated Coffeyville Refinery decided in 1977 to proceed with the installation of a 86.183 Kg/h coal fired boiler to generate process steam at 650 psig (4,482 k Pa) 596/sup 0/F (313/sup 0/C). A significant portion of this steam is passed through steam turbines to obtain mechanical power. Building and operating a coal-fired steam plant is a ''Different Kettle of Fish'' from building and operating an oil/gas-fired steam plant. The intention of this paper is to deal with some of the ''Why's and Wherefores'' of the conversion to coal-fired equipment.

  6. Particulate emission abatement for Krakow boiler houses

    SciTech Connect (OSTI)

    Wysk, R.

    1995-12-31

    Among the many strategies for improving air quality in Krakow, one possible method is to adapt new and improved emission control technology. This project focuses on such a strategy. In order to reduce dust emissions from coal-fueled boilers, a new device called a Core Separator has been introduced in several boiler house applications. This advanced technology has been successfully demonstrated in Poland and several commercial units are now in operation. Particulate emissions from the Core Separator are typically 3 to 5 times lower than those from the best cyclone collectors. It can easily meet the new standard for dust emissions which will be in effect in Poland after 1997. The Core Separator is a completely inertial collector and is based on a unique recirculation method. It can effectively remove dust particles below 10 microns in diameter, the so-called PM-10 emissions. Its performance approaches that of fabric filters, but without the attendant cost and maintenance. It is well-suited to the industrial size boilers located in Krakow. Core Separators are now being marketed and sold by EcoInstal, one of the leading environmental firms in Poland, through a cooperative agreement with LSR Technologies.

  7. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock

  8. Supercritical CO2 Power Cycles: Design Considerations for Concentrating

    Office of Scientific and Technical Information (OSTI)

    Solar Power (Conference) | SciTech Connect Supercritical CO2 Power Cycles: Design Considerations for Concentrating Solar Power Citation Details In-Document Search Title: Supercritical CO2 Power Cycles: Design Considerations for Concentrating Solar Power A comparison of three supercritical CO2 Brayton cycles: the simple cycle, recompression cycle and partial-cooling cycle indicates the partial-cooling cycle is favored for use in concentrating solar power (CSP) systems. Although it displays

  9. U.S., Saudi Arabia Announce International Collaboration on Supercritical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Tech Development | Department of Energy , Saudi Arabia Announce International Collaboration on Supercritical CO2 Tech Development U.S., Saudi Arabia Announce International Collaboration on Supercritical CO2 Tech Development June 3, 2016 - 1:00pm Addthis The U. S. and the Kingdom of Saudi Arabia have announced the intention to establish an international consortium to promote the research, development, and demonstration (RD&D) of supercritical carbon dioxide (sCO2) power cycles. The

  10. Solid Catalyzed Isoparaffin Alkylation at Supercritical Fluid and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Near-Supercritical Fluid Conditions - Energy Innovation Portal Startup America Startup America Find More Like This Return to Search Solid Catalyzed Isoparaffin Alkylation at Supercritical Fluid and Near-Supercritical Fluid Conditions Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL has developed a solid catalyst process for the alkylation reaction of isoparaffins with olefins over solid catalysts. The process includes contacting a mixture of an

  11. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine NREL logo -- This project is inactive -- The National Renewable Energy Laboratory (NREL) and its partners, under the 2012 SunShot Concentrating Solar Power (CSP) R&D funding opportunity announcement (FOA), aim to demonstrate a multi-megawatt power cycle using supercritical carbon dioxide (s-CO2) as the working fluid. The use of carbon

  12. Project Profile: High-Efficiency Receivers for Supercritical Carbon Dioxide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cycles | Department of Energy Receivers for Supercritical Carbon Dioxide Cycles Project Profile: High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles Brayton logo --This project is inactive -- Brayton Energy, under the 2012 SunShot Concentrating Solar Power (CSP) R&D FOA, is building and testing a new solar receiver that uses supercritical carbon dioxide (s-CO2) as the heat-transfer fluid. The research team is designing the receiver to withstand higher operating temperatures

  13. Project Profile: Supercritical Carbon Dioxide Turbo-Expander and Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exchangers | Department of Energy Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Project Profile: Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers SWRI Logo The Southwest Research Institute (SWRI) and its partners, under the 2012 Concentrating Solar Power (CSP) SunShot R&D funding opportunity announcement (FOA), are developing a supercritical carbon dioxide (s-CO2) power cycle that combines high efficiencies and low costs for modular CSP applications.

  14. DOE Selects Project to Help Advance More Efficient Supercritical Carbon

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dioxide-Based Power Cycles | Department of Energy Project to Help Advance More Efficient Supercritical Carbon Dioxide-Based Power Cycles DOE Selects Project to Help Advance More Efficient Supercritical Carbon Dioxide-Based Power Cycles August 3, 2015 - 10:25am Addthis The U.S. Department of Energy's National Energy Technology Laboratory (NETL) has selected Thar Energy, LLC to develop new recuperator technologies leading to more cost-effective and efficient supercritical carbon dioxide

  15. Field Test of Boiler Primary Loop Temperature Controller

    SciTech Connect (OSTI)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and, in some cases, return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential.

  16. Supercritical separation process for complex organic mixtures

    DOE Patents [OSTI]

    Chum, Helena L.; Filardo, Giuseppe

    1990-01-01

    A process is disclosed for separating low molecular weight components from complex aqueous organic mixtures. The process includes preparing a separation solution of supercritical carbon dioxide with an effective amount of an entrainer to modify the solvation power of the supercritical carbon dioxide and extract preselected low molecular weight components. The separation solution is maintained at a temperature of at least about 70.degree. C. and a pressure of at least about 1,500 psi. The separation solution is then contacted with the organic mixtures while maintaining the temperature and pressure as above until the mixtures and solution reach equilibrium to extract the preselected low molecular weight components from the organic mixtures. Finally, the entrainer/extracted components portion of the equilibrium mixture is isolated from the separation solution.

  17. Supercritical separation process for complex organic mixtures

    DOE Patents [OSTI]

    Chum, H.L.; Filardo, G.

    1990-10-23

    A process is disclosed for separating low molecular weight components from complex aqueous organic mixtures. The process includes preparing a separation solution of supercritical carbon dioxide with an effective amount of an entrainer to modify the solvation power of the supercritical carbon dioxide and extract preselected low molecular weight components. The separation solution is maintained at a temperature of at least about 70 C and a pressure of at least about 1,500 psi. The separation solution is then contacted with the organic mixtures while maintaining the temperature and pressure as above until the mixtures and solution reach equilibrium to extract the preselected low molecular weight components from the organic mixtures. Finally, the entrainer/extracted components portion of the equilibrium mixture is isolated from the separation solution. 1 fig.

  18. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  19. SUPERCRITICAL STEAM CYCLE FOR NUCLEAR POWER PLANT

    SciTech Connect (OSTI)

    Tsiklauri, Georgi V.; Talbert, Robert J.; Schmitt, Bruce E.; Filippov, Gennady A.; Bogojavlensky, Roald G.; Grishanin, Evgeny I.

    2005-07-01

    Revolutionary improvement of the nuclear plant safety and economy with light water reactors can be reached with the application of micro-fuel elements (MFE) directly cooled by a supercritical pressure light-water coolant-moderator. There are considerable advantages of the MFE as compared with the traditional fuel rods, such as: Using supercritical and superheated steam considerably increases the thermal efficiency of the Rankine cycle up to 44-45%. Strong negative coolant and void reactivity coefficients with a very short thermal delay time allow the reactor to shutdown quickly in the event of a reactivity or power excursion. Core melting and the creation of corium during severe accidents are impossible. The heat transfer surface area is larger by several orders of magnitude due to the small spherical dimensions of the MFE. The larger heat exchange surface significantly simplifies residual heat removal by natural convection and radiation from the core to a subsequent passive system of heat removal.

  20. Using supercritical carbon dioxide as a fracturing fluid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compare different working models of hydraulic fracturing for shale gas and oil production. ... and drawbacks of using supercritical CO2 as a working fluid for shale gas production. ...

  1. DOE Selects Project to Help Advance More Efficient Supercritical...

    Office of Environmental Management (EM)

    higher thermal efficiencies when compared to state of the art steam-based power cycles. ... Developing Components for Advanced Turbine and Supercritical CO2-Based Power Cycles ...

  2. U.S., Saudi Arabia Announce International Collaboration on Supercritic...

    Office of Environmental Management (EM)

    costs and overall reduction in electricity cost compared to steam-based power cycles. ... Developing Components for Advanced Turbine and Supercritical CO2-Based Power Cycles

  3. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Brayton Energy's supercritical carbon dioxide (s-CO 2 ) solar receiver has the potential to significantly improve reliability, increase efficiency, and reduce costs of CSP systems. ...

  4. Startup Design Features for Supercritical Power Conversion Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Startup Design Features for Supercritical Power ... DescriptionThe new design features and procedures will improve the already advanced ...

  5. Test Plan for Heat Cycle Research Program, Phase I Supercritical...

    Office of Scientific and Technical Information (OSTI)

    Test Plan for Heat Cycle Research Program, Phase I Supercritical Cycle Tests Citation Details In-Document Search Title: Test Plan for Heat Cycle Research Program, Phase I ...

  6. Candidate Materials Evaluation for Supercritical Water-Cooled Reactor

    SciTech Connect (OSTI)

    T. R. Allen and G. S. Was

    2008-12-12

    Final technical report on the corrosion, stress corrosion cracking, and radiation response of candidate materials for the supercritical water-cooled reactor concept.

  7. Project Profile: Supercritical Carbon Dioxide Turbo-Expander...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Project Profile: ... Concentrating Solar Power (CSP) SunShot R&D funding opportunity announcement (FOA), are ...

  8. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    cycle offers higher cycle efficiency when compared with supercritical or superheated steam cycles at temperatures relevant for concentrating solar power (CSP) applications....

  9. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon...

    Open Energy Info (EERE)

    Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title...

  10. 10 MW Supercritical CO2 Turbine Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 MW Supercritical CO2 Turbine Project 10 MW Supercritical CO2 Turbine Project This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. csp_review_meeting_042313_turchi.pdf (1.86 MB) More Documents & Publications 10-Megawatt Supercritical Carbon Dioxide Turbine - FY13 Q2 10-MW Supercritical-CO2 Turbine Degradation Mechanisms and Development of Protective Coatings for TES and HTF Containment Materials

  11. Purchasing Energy-Efficient Commercial Boilers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Boilers Purchasing Energy-Efficient Commercial Boilers The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial boilers, a product category covered by FEMP-designated efficiency requirements. Federal laws and requirements mandate that agencies purchase ENERGY STAR-qualified or FEMP-designated products in all product categories covered by these programs and in any acquisition actions that are not specifically exempted by law. FEMP's acquisition guidance and

  12. Coiled tubing drilling with supercritical carbon dioxide

    DOE Patents [OSTI]

    Kolle , Jack J.

    2002-01-01

    A method for increasing the efficiency of drilling operations by using a drilling fluid material that exists as supercritical fluid or a dense gas at temperature and pressure conditions existing at a drill site. The material can be used to reduce mechanical drilling forces, to remove cuttings, or to jet erode a substrate. In one embodiment, carbon dioxide (CO.sub.2) is used as the material for drilling within wells in the earth, where the normal temperature and pressure conditions cause CO.sub.2 to exist as a supercritical fluid. Supercritical carbon dioxide (SC--CO.sub.2) is preferably used with coiled tube (CT) drilling equipment. The very low viscosity SC--CO.sub.2 provides efficient cooling of the drill head, and efficient cuttings removal. Further, the diffusivity of SC--CO.sub.2 within the pores of petroleum formations is significantly higher than that of water, making jet erosion using SC--CO.sub.2 much more effective than water jet erosion. SC--CO.sub.2 jets can be used to assist mechanical drilling, for erosion drilling, or for scale removal. A choke manifold at the well head or mud cap drilling equipment can be used to control the pressure within the borehole, to ensure that the temperature and pressure conditions necessary for CO.sub.2 to exist as either a supercritical fluid or a dense gas occur at the drill site. Spent CO.sub.2 can be vented to the atmosphere, collected for reuse, or directed into the formation to aid in the recovery of petroleum.

  13. Consider Installing High-Pressure Boilers with BackpressureTurbine...

    Broader source: Energy.gov (indexed) [DOE]

    with backpressure turbine-generators as part of optimized steam systems. STEAM TIP SHEET 22 Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators (January ...

  14. Recover Heat from Boiler Blowdown | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Recover Heat from Boiler Blowdown (January 2012) More Documents & Publications Install an Automatic Blowdown-Control System Flash High-Pressure Condensate to Regenerate ...

  15. Oxy-Combustion Boiler Material Development (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to ... Test coupons of boiler tube materials were coated with deposits representative of those ...

  16. EECBG Success Story: New Boilers, Big Savings for Minnesota County

    Broader source: Energy.gov [DOE]

    Officials at Sherburne County's Government Center in Minnesota had a problem: the complex's original boilers, installed in 1972, were in desperate need of replacing. Learn more.

  17. Biomass Boiler and Furnace Emissions and Safety Regulations in...

    Open Energy Info (EERE)

    in the Northeast States Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Biomass Boiler and Furnace Emissions and Safety Regulations in the Northeast States Agency...

  18. Gas-Fired Boilers and Furnaces | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    natural gas meter. Gas boilers and furnaces can be fueled by either natural gas or propane with simple modifications accounting for the different characteristics of the fuels....

  19. Clean Boiler Waterside Heat Transfer Surfaces | Department of...

    Energy Savers [EERE]

    STEAM TIP SHEET 7 Clean Boiler Waterside Heat Transfer Surfaces (April 2012) (395.4 KB) More Documents & Publications Consider Installing Turbulators on Two- and Three-Pass ...

  20. Building America Case Study: Advanced Boiler Load Monitoring...

    Energy Savers [EERE]

    Boiler Load Monitoring Controllers Chicago, Illinois PROJECT INFORMATION Project Name: ... Most of Chicago's older multifamily housing stock is heated by centrally metered steam or ...

  1. Recover Heat from Boiler Blowdown | Department of Energy

    Energy Savers [EERE]

    STEAM TIP SHEET 10 Recover Heat from Boiler Blowdown (January 2012) (372.21 KB) More Documents & Publications Install an Automatic Blowdown-Control System Consider Installing a ...

  2. Field Test of Boiler Primary Loop Temperature Controller

    SciTech Connect (OSTI)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and in some cases return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential. PARR installed and monitored the performance of one type of ALM controller, the M2G from Greffen Systems, at multifamily sites in the city of Chicago and its suburb Cary, IL, both with existing OTR control. Results show that energy savings depend on the degree to which boilers are over-sized for their load, represented by cycling rates. Also savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, over-sized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less over-sized boilers at another site showed muted savings.

  3. Return Condensate to the Boiler - Steam Tip Sheet #8

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on returning condensate to boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  4. Property:Building/SPPurchasedEngyPerAreaKwhM2Oil-FiredBoiler...

    Open Energy Info (EERE)

    Oil-FiredBoiler Jump to: navigation, search This is a property of type String. Oil-fired boiler Pages using the property "BuildingSPPurchasedEngyPerAreaKwhM2Oil-FiredBoiler"...

  5. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2003-01-31

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report discusses testing that was performed for analyzing the alkali-silica reactivity of ULHS in cement slurries. DOE joined the Materials Management Service (MMS)-sponsored joint industry project ''Long-Term Integrity of Deepwater Cement under Stress/Compaction Conditions.'' Results of the project contained in two progress reports are also presented in this report.

  6. Advanced Thermal Storage for Central Receivers with Supercritical Coolants

    SciTech Connect (OSTI)

    Kelly, Bruce D.

    2010-06-15

    The principal objective of the study is to determine if supercritical heat transport fluids in a central receiver power plant, in combination with ceramic thermocline storage systems, offer a reduction in levelized energy cost over a baseline nitrate salt concept. The baseline concept uses a nitrate salt receiver, two-tank (hot and cold) nitrate salt thermal storage, and a subcritical Rankine cycle. A total of 6 plant designs were analyzed, as follows: Plant Designation Receiver Fluid Thermal Storage Rankine Cycle Subcritical nitrate salt Nitrate salt Two tank nitrate salt Subcritical Supercritical nitrate salt Nitrate salt Two tank nitrate salt Supercritical Low temperature H2O Supercritical H2O Two tank nitrate salt Supercritical High temperature H2O Supercritical H2O Packed bed thermocline Supercritical Low temperature CO2 Supercritical CO2 Two tank nitrate salt Supercritical High temperature CO2 Supercritical CO2 Packed bed thermocline Supercritical Several conclusions have been drawn from the results of the study, as follows: 1) The use of supercritical H2O as the heat transport fluid in a packed bed thermocline is likely not a practical approach. The specific heat of the fluid is a strong function of the temperatures at values near 400 °C, and the temperature profile in the bed during a charging cycle is markedly different than the profile during a discharging cycle. 2) The use of supercritical CO2 as the heat transport fluid in a packed bed thermocline is judged to be technically feasible. Nonetheless, the high operating pressures for the supercritical fluid require the use of pressure vessels to contain the storage inventory. The unit cost of the two-tank nitrate salt system is approximately $24/kWht, while the unit cost of the high pressure thermocline system is nominally 10 times as high. 3) For the supercritical fluids, the outer crown temperatures of the receiver tubes are in the range of 700 to 800 °C. At temperatures of 700 °C and above

  7. Ultra High Temperature | Open Energy Information

    Open Energy Info (EERE)

    Ultra High Temperature Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Sanyal Temperature Classification: Ultra High Temperature Dictionary.png Ultra High...

  8. Green wood chip gasification due under boiler

    SciTech Connect (OSTI)

    Not Available

    1981-12-14

    It is reported that Applied Engineering Co. has begun installing the first greenwood chip gasification system to be used in conjunction with fossil fuels at Florida Power Corp's Suwannee generating station near Lake City, Florida. The unit's design capacity is about 37 MMBTU/hour and will provide as much as 25% of the fuel requirements of a large utility type natural gas boiler under normal load conditions. The system is expected to back out as much as 1 million gal/year of fuel oil at a savings of approximately $850,000/year.

  9. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2001-01-15

    The objective of this project is to develop an improved ultra-lightweigh cement using ultralight hollow glass spheres (ULHS). Work reported herein addresses Task 1: Assess Ultra-Lightweight Cementing Problems, Task 2: Review Russian Ultra-Lightweight Cement Literature, and Task 3: Test Ultra-Lightweight Cements. Results reported this quarter include a review and summary surface pipe and intermediate casing cementing conditions historically encountered in the US and establishment of average design conditions for ULHS cements. Russian literature concerning development and use of ultra-lightweight cements employing either nitrogen or ULHS was reviewed, and a summary is presented. Quality control testing of materials used to formulate ULHS cements in the laboratory was conducted to establish baseline material performance standards. A testing protocol was developed employing standard procedures as well as procedures tailored to evaluate ULHS. This protocol is presented and discussed. finally, results of initial testing of ULHS cements is presented along with analysis to establish cement performance design criteria to be used during the remainder of the project.

  10. Utilizing Supplemental Ultra-Low-NO

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... ULN burner technology into a Capstone C65 (65 kW) microturbine and a 100 HP heat recovery boiler by Johnston Boiler Company. Barriers The project seeks to overcome the following ...

  11. Supercritical Water Oxidation Data Acquisition Testing

    SciTech Connect (OSTI)

    K. M. Garcia

    1996-08-01

    Supercritical Water Oxidation (SCWO) is a high pressure oxidation process that blends air, water, and organic waste material in an oxidizer in which where the temperature and pressure in the oxidizer are maintained above the critical point of water. Supercritical water mixed with hydrocarbons, which would be insoluble at subcritical conditions, forms a homogeneous phase which possesses properties associated with both a gas and a liquid. Hydrocarbons in contact with oxygen and SCW are readily oxidized. These properties of SCW make it an attractive means for the destruction of waste streams containing organic materials. SCWO technology holds great promise for treating mixed wastes in an environmentally safe and efficient manner. In the spring of 1994 the U.S. Department of Energy (DOE) initiated a Supercritical Water Oxidation Data Acquisition Testing (SCWODAT) program. The SCWODAT program provided further information and operational data on the effectiveness of treating both simulated mixed waste and typical Navy hazardous waste using the SCWO technology. The program concentrated on the acquisition of data through pilot plant testing. The Phase I DOE testing used a simulated waste stream that contained a complex machine cutting oil and metals, that acted as surrogates for radionuclides. The Phase II Navy testing included pilot testing using hazardous waste materials to demonstrate the effectiveness of the SCWO technology. The SCWODAT program demonstrated that the SCWO process oxidized the simulated waste stream containing complex machine cutting oil, selected by DOE as representative of one of the most difficult of the organic waste streams for which SCWO had been applied. The simulated waste stream with surrogate metals in solution was oxidized, with a high destruction efficiency, on the order of 99.97%, in both the neutralized and unneutralized modes of operation.

  12. Supercritical fluids: Reactions, materials and applications

    SciTech Connect (OSTI)

    Tumas, W.; Jacobson, G.B.; Josephsohn, N.S.; Brown, G.H.

    1999-04-09

    A number of important processes utilizing supercritical fluids have been either implemented or are emerging for extractions, separations and a wide range of cleaning applications. Supercritical fluids can be reasonable solvents yet share many of the advantages of gases including miscibility with other gases (i.e. hydrogen and oxygen), low viscosities and high diffusivities. Carbon dioxide has the further advantages of being nontoxic, nonflammable, inexpensive and currently unregulated. The use of compressed gases, either as liquids or supercritical fluids, as reaction media offers the opportunity to replace conventional hazardous solvents and also to optimize and potentially control the effect of solvent on chemical and material processing. The last several years has seen a significant growth in advances in chemical synthesis, catalytic transformations and materials synthesis and processing. The authors report on results from an exploratory program at Los Alamos National Laboratory aimed at investigating the use of dense phase fluids, particularly carbon dioxide, as reaction media for homogeneous, heterogeneous and phase-separable catalytic reactions in an effort to develop new, environmentally-friendly methods for chemical synthesis and processing. This approach offers the possibility of opening up substantially different chemical pathways, increasing selectivity at higher reaction rates, facilitating downstream separations and mitigating the need for hazardous solvents. Developing and understanding chemical and catalytic transformations in carbon dioxide could lead to greener chemistry at three levels: (1) Solvent replacement; (2) Better chemistry (e.g. higher reactivity, selectivity, less energy consumption); and (3) New chemistry (e.g. novel separations, use of COP{sub 2} as a C-1 source).

  13. Gas reburn retrofit on an industrial cyclone boiler

    SciTech Connect (OSTI)

    Farzan, H.; Latham, C.E.; Maringo, G.J.

    1996-01-01

    Eastman Kodak Company`s cyclone boiler (Unit No. 43), located in Rochester, New York, is being retrofitted with the gas reburning technology developed by Babcock & Wilcox (B & W) to reduce NO{sub x} emissions in order to comply with the Title I, ozone nonattainment, of the Clean Air Act Amendments (CAAA) of 1990. The required NO{sub x} reduction from baseline levels necessary to meet the presumptive limit set in New York`s regulation is about 47%. Eastman Kodak and the Gas Research Institute (GRI) are cosponsoring this project. B & W is the prime contractor and contract negotiations with Chevron as the gas supplier are presently being finalized. Equipment installation for the gas reburn system is scheduled for a September 1995 outage. No. 43 Boiler`s maximum continuous rating (MCR) is 550,000 pounds per hour of steam flow or approximately equivalent to 60 MW{sub e}. Because of the compact boiler design, there is insufficient gas residence time to use pulverized coal or oil as the reburn fuel, thus making it a prime candidate for gas reburn. Kodak currently has four cyclone boilers. Based on successful completion of this gas reburn project, modifying the other three cyclone boilers with gas reburn technology is anticipated. The paper will describe B & W`s gas reburn data from a cyclone-equipped pilot facility (B & W`s Small Boiler Simulator), gas reburn design information specific to Eastman Kodak No. 43 Boiler, and numerical modeling experiences based on the pilot-scale Small Boiler Simulator (SBS) results along with those from a full-scale commercial boiler.

  14. Establishing an energy efficiency recommendation for commercial boilers

    SciTech Connect (OSTI)

    Ware, Michelle J.

    2000-08-01

    To assist the federal government in meeting its energy reduction goals, President Clinton's Executive Order 12902 established the Procurement Challenge, which directed all federal agencies to purchase equipment within the top 25th percentile of efficiency. Under the direction of DOE's Federal Energy Management Program (FEMP), the Procurement Challenge's goal is to create efficiency recommendations for all energy-using products that could substantially impact the government's energy reduction goals, like commercial boilers. A typical 5,000,000 Btuh boiler, with a thermal efficiency of 83.2%, can have lifetime energy cost savings of $40,000 when compared to a boiler with a thermal efficiency of 78%. For the federal market, which makes up 2% of the boiler market, this means lifetime energy cost savings of over $25,600,000. To establish efficiency recommendations, FEMP uses standardized performance ratings for products sold in the marketplace. Currently, the boiler industry uses combustion efficiency and, sometimes, thermal efficiency performance measures when specifying a commercial boiler. For many years, the industry has used these efficiency measures interchangeably, causing confusion about boiler performance measurements, and making it difficult for FEMP to establish the top 25th percentile of efficiency. This paper will illustrate the method used to establish FEMP's recommendation for boilers. The method involved defining a correlation between thermal and combustion efficiency among boiler classifications; using the correlation to model a data set of all the boiler types available in the market; and identifying how the correlation affected the top 25th percentile analysis. The paper also will discuss the applicability of this method for evaluating other equipment for which there are limited data on performance ratings.

  15. Supercritical water oxidation of ammonium picrate

    SciTech Connect (OSTI)

    LaJeunesse, C.A.; Mills, B.E.; Brown, B.G.

    1994-11-01

    This study demonstrates the feasibility of using supercritical water oxidation to destroy ammonium picrate. Analyses of reactor effluent composition at various temperatures, residence times, and oxidant concentrations were used to design an improved reactor configuration for achieving destruction with minimum corrosion. The engineering evaluation reactor, a room-sized laboratory scale reactor, was reconfigured to incorporate this design change. Destruction of ammonium picrate with minimized corrosion was demonstrated on this reconfigured reactor. Factors that must be considered in scaling up to pilot plant size are discussed.

  16. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2002-07-30

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report includes results from laboratory testing of ULHS systems along with other lightweight cement systems, including foamed and sodium silicate slurries. During this project quarter, a comparison study of the three cement systems examined the effect that cement drillout has on the three cement systems. Testing to determine the effect of pressure cycling on the shear bond properties of the cement systems was also conducted. This report discusses testing that was performed to analyze the alkali-silica reactivity of ULHS in cement slurries.

  17. Optimized, Competitive Supercritical-CO2 Cycle GFR for Gen IV Service

    SciTech Connect (OSTI)

    M.J. Driscoll; P. Hejzlar; G. Apostolakis

    2008-09-08

    An overall plant design was developed for a gas-cooled fast reactor employing a direct supercritical Brayton power conversion system. The most important findings were that (1) the concept could be capital-cost competitive, but startup fuel cycle costs are penalized by the low core power density, specified in large part to satisfy the goal of significatn post-accident passive natural convection cooling; (2) active decay heat removal is preferable as the first line of defense, with passive performance in a backup role; (3) an innovative tube-in-duct fuel assembly, vented to the primpary coolant, appears to be practicable; and (4) use of the S-Co2 GFR to support hydrogen production is a synergistic application, since sufficient energy can be recuperated from the product H2 and 02 to allow the electrolysis cell to run 250 C hotter than the reactor coolant, and the water boilers can be used for reactor decay heat removal. Increasing core poer density is identified as the top priority for future work on GFRs of this type.

  18. Energy Conservation Program: Energy Conservation Standards for Residential Boilers, Notice of Proposed Rulemaking

    Office of Energy Efficiency and Renewable Energy (EERE)

    Energy Conservation Program: Energy Conservation Standards for Residential Boilers, Notice of Proposed Rulemaking

  19. Energy Conservation Program for Consumer Products: Test Procedures for Furnaces and Boilers, Comment Period Extension

    Broader source: Energy.gov [DOE]

    Energy Conservation Program for Consumer Products: Test Procedures for Furnaces and Boilers, Comment Period Extension

  20. Boiler Maximum Achievable Control Technology (MACT) Technical Assistance- Fact Sheet, April 2015

    Broader source: Energy.gov [DOE]

    Fact sheet about the Boiler Maximum Achievable Control Technology (MACT) Technical Assistance Program

  1. 2015-12-29 Consumer Furnaces and Boilers Test Procedures Final Rule

    Broader source: Energy.gov [DOE]

    Energy Conservation Program for Consumer Products: Test Procedures for Consumer Furnaces and Boilers

  2. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2001-10-23

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). Work reported herein addresses tasks performed in the fourth quarter as well as the other three quarters of the past year. The subjects that were covered in previous reports and that are also discussed in this report include: Analysis of field laboratory data of active cement applications from three oil-well service companies; Preliminary findings from a literature review focusing on problems associated with ultra-lightweight cements; Summary of pertinent information from Russian ultra-lightweight cement literature review; and Comparison of compressive strengths of ULHS systems using ultrasonic and crush methods Results reported from the fourth quarter include laboratory testing of ULHS systems along with other lightweight cement systems--foamed and sodium silicate slurries. These comparison studies were completed for two different densities (10.0 and 11.5 lb/gal) and three different field application scenarios. Additional testing included the mechanical properties of ULHS systems and other lightweight systems. Studies were also performed to examine the effect that circulation by centrifugal pump during mixing has on breakage of ULHS.

  3. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles This fact sheet describes a project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by Brayton Energy, aims to develop and demonstrate a low-cost, high-efficiency solar receiver that is compatible with s-CO2 cycles and modern thermal storage subsystems. Supercritical CO2 Brayton-cycle

  4. Project Profile: Lifetime Model Development for Supercritical CO2 CSP

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems (SuNLaMP) | Department of Energy Project Profile: Lifetime Model Development for Supercritical CO2 CSP Systems (SuNLaMP) Project Profile: Lifetime Model Development for Supercritical CO2 CSP Systems (SuNLaMP) Funding Program: SuNLaMP SunShot Subprogram: CSP Location: Oak Ridge National Laboratory, Oak Ridge, TN SunShot Award Amount: $2,175,000 This project seeks to develop a predictive lifetime model for materials in supercritical carbon dioxide (sCO2) conditions similar to

  5. Code System for Supercritical Water Cooled Reactor LOCA Analysis.

    Energy Science and Technology Software Center (OSTI)

    1999-10-13

    Version 00 The new SCRELA code was developed to analyze the LOCA of the supercritical water cooled reactor. Since the currently available LWR codes for LOCA analysis could not analyze the significant differences in reactor characteristics between the supercritical-water cooled reactor and the current LWR, the first objective of this code development was to analyze the uniqueness of this reactor. The behavior of the supercritical water in the blowdown phase and the reflood phase ismore » modeled.« less

  6. Rapid ignition of fluidized bed boiler

    DOE Patents [OSTI]

    Osborn, Liman D.

    1976-12-14

    A fluidized bed boiler is started up by directing into the static bed of inert and carbonaceous granules a downwardly angled burner so that the hot gases cause spouting. Air is introduced into the bed at a rate insufficient to fluidize the entire bed. Three regions are now formed in the bed, a region of lowest gas resistance, a fluidized region and a static region with a mobile region at the interface of the fluidized and static regions. Particles are transferred by the spouting action to form a conical heap with the carbonaceous granules concentrated at the top. The hot burner gases ignite the carbonaceous matter on the top of the bed which becomes distributed in the bed by the spouting action and bed movement. Thereafter the rate of air introduction is increased to fluidize the entire bed, the spouter/burner is shut off, and the entire fluidized bed is ignited.

  7. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    aim to demonstrate a multi-megawatt power cycle using supercritical carbon dioxide (s-CO2) as the working fluid. The use of carbon dioxide instead of steam allows higher...

  8. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2012. progressreportsunshotbraytonfy12q4.pdf More Documents & Publications High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1...

  9. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1 High-Efficiency Receivers for...

  10. Development of Materials for Supercritical-Water-Cooled Reactor

    Broader source: Energy.gov [DOE]

    Supercritical-Water-Cooled Reactor (SCWR) was selected as one of the promising candidates in Generation IV reactors for its prominent advantages; those are the high thermal efficiency, the system...

  11. Supercritical fluid carbon dioxide cleaning of plutonium parts

    SciTech Connect (OSTI)

    Hale, S.J.

    1991-12-31

    Supercritical fluid carbon dioxide is under investigation in this work for use as a cleaning solvent for the final cleaning of plutonium parts. These parts must be free of organic residue to avoid corrosion in the stockpile. Initial studies on stainless steel and full-scale mock-up parts indicate that the oils of interest are easily and adequately cleaned from the metal surfaces with supercritical fluid carbon dioxide. Results from compatibility studies show that undesirable oxidation or other surface reactions are not occurring during exposure of plutonium to the supercritical fluid. Cleaning studies indicate that the oils of interest are removed from the plutonium surface under relatively mild conditions. These studies indicate that supercritical fluid carbon dioxide is a very promising cleaning medium for this application.

  12. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus; Yanagihara, Naohisa; Dyke, James T.; Vemulapalli, Krishna

    1991-09-03

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  13. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. ... Supercritical CO2 Brayton-cycle engines have the potential to increase conversion efficiency to more ...

  14. Oil-Fired Boilers and Furnaces | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Diagram of an oil boiler. New tanks are generally double-wall or have a spill container built underneath to reduce the chances of an oil spill. Typically, the tank drip pan shown...

  15. New Boilers, Big Savings for Minnesota County | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    However, hopes for a new set of boilers were revived in April after the county received a ... Local contractor El-Jay Plumbing & Heating of St. Cloud, Minn., will install the new ...

  16. Recover Heat from Boiler Blowdown - Steam Tip Sheet #10

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on recovering heat from boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  17. Minimize Boiler Short Cycling Losses - Steam Tip Sheet #16

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  18. Building America Case Study: Boiler Control Replacement for Hydronical...

    Energy Savers [EERE]

    ... Similar case studies of the effectiveness of these control features in steam- heated buildings would be valuable. Description A state-of-the-art boiler control system includes a ...

  19. Minimize Boiler Short Cycling Losses - Steam Tip Sheet #16

    SciTech Connect (OSTI)

    2006-01-01

    This revised AMO tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  20. Improved Heat Recovery in Biomass-Fired Boilers

    SciTech Connect (OSTI)

    2009-11-01

    This factsheet describes a research project whose goal is to reduce corrosion and improve the life span of boiler superheater tubes operating at temperatures above the melting point of ash deposits.

  1. Gas-Fired Boilers and Furnaces | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    A residential natural gas meter. A residential natural gas meter. What does this mean for me? Your gas boiler or furnace may be oversized, particularly if you've upgraded the...

  2. Advanced Combustion

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2013-03-11

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  3. Containment system for supercritical water oxidation reactor

    DOE Patents [OSTI]

    Chastagner, P.

    1994-07-05

    A system is described for containment of a supercritical water oxidation reactor in the event of a rupture of the reactor. The system includes a containment for housing the reaction vessel and a communicating chamber for holding a volume of coolant, such as water. The coolant is recirculated and sprayed to entrain and cool any reactants that might have escaped from the reaction vessel. Baffles at the entrance to the chamber prevent the sprayed coolant from contacting the reaction vessel. An impact-absorbing layer is positioned between the vessel and the containment to at least partially absorb momentum of any fragments propelled by the rupturing vessel. Remote, quick-disconnecting fittings exterior to the containment, in cooperation with shut-off valves, enable the vessel to be isolated and the system safely taken off-line. Normally-closed orifices throughout the containment and chamber enable decontamination of interior surfaces when necessary. 2 figures.

  4. Viscosity correlations for binary supercritical fluids

    SciTech Connect (OSTI)

    Tilly, K.D.; Foster, N.R.; Macnaughton, S.J.; Tomasko, D.L. . School of Chemical Engineering and Industrial Chemistry)

    1994-03-01

    The viscosities and densities of supercritical mixtures of methanol, ethanol, n-propanol, isopropanol, n-pentane, n-hexane, n-heptane, and acetone in carbon dioxide, at concentrations between 1 and 5 mol %, were determined using a falling weight viscometer at pressures up to 240 bar and at temperatures between 313 and 328 K. The effects of pressure, temperature, cosolvent concentration, and the physical properties of the cosolvents on the mixture viscosity and density were examined. The viscosities and the densities of the mixtures were found to increase with the size, polarity, and concentration of the cosolvent molecule. The mixture viscosity was correlated with several empirical dense gas viscosity correlations. The best correlation was the Ely and Hanley technique modified with a density-dependent noncorrespondence factor. The Peng-Robinson equation of state was used to correlate the mixture densities.

  5. Containment system for supercritical water oxidation reactor

    DOE Patents [OSTI]

    Chastagner, Philippe

    1994-01-01

    A system for containment of a supercritical water oxidation reactor in the event of a rupture of the reactor. The system includes a containment for housing the reaction vessel and a communicating chamber for holding a volume of coolant, such as water. The coolant is recirculated and sprayed to entrain and cool any reactants that might have escaped from the reaction vessel. Baffles at the entrance to the chamber prevent the sprayed coolant from contacting the reaction vessel. An impact-absorbing layer is positioned between the vessel and the containment to at least partially absorb momentum of any fragments propelled by the rupturing vessel. Remote, quick-disconnecting fittings exterior to the containment, in cooperation with shut-off valves, enable the vessel to be isolated and the system safely taken off-line. Normally-closed orifices throughout the containment and chamber enable decontamination of interior surfaces when necessary.

  6. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2002-01-23

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report includes results from laboratory testing of ULHS systems along with other lightweight cement systems: foamed and sodium silicate slurries. Comparison studies of the three cement systems examined several properties: tensile strength, Young's modulus, water permeability, and shear bond. Testing was also done to determine the effect that temperature cycling has on the shear bond properties of the cement systems. In addition, analysis was carried out to examine alkali silica reactivity of slurries containing ULHS. Data is also presented from a study investigating the effects of mixing and pump circulation on breakage of ULHS. Information is also presented about the field application of ULHS in cementing a 7-in. intermediate casing in south Texas.

  7. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2002-10-31

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report includes results from laboratory testing of ULHS systems along with other lightweight cement systems, including foamed and sodium silicate slurries. During this project quarter, a comparison study of the three cement systems examined the effect that cement drillout has on the three cement systems. Testing to determine the effect of pressure cycling on the shear bond properties of the cement systems was also conducted. This report discusses testing that will be performed for analyzing the alkali-silica reactivity of ULHS in cement slurries, as well as the results of Field Tests 1 and 2.

  8. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2002-04-29

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report includes results from laboratory testing of ULHS systems along with other lightweight cement systems, including foamed and sodium silicate slurries. During this project quarter, comparison studies of the three cement systems examined several properties: tensile strength, Young's modulus, and shear bond. Testing to determine the effect of temperature cycling on the shear bond properties of the cement systems was also conducted. In addition, the stress-strain behavior of the cement types was studied. This report discusses a software program that is being developed to help design ULHS cements and foamed cements.

  9. Transonic Combustion ’ - Injection Strategy Development for Supercritical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gasoline Injection-Ignition in a Light Duty Engine | Department of Energy Transonic Combustion ’ - Injection Strategy Development for Supercritical Gasoline Injection-Ignition in a Light Duty Engine Transonic Combustion ’ - Injection Strategy Development for Supercritical Gasoline Injection-Ignition in a Light Duty Engine Novel fuel injection equipment enables knock-free ignition with low noise and smoke in compression-ignition engines and low-particulates in spark-ignition engines.

  10. Using supercritical carbon dioxide as a fracturing fluid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using supercritical carbon dioxide as a fracturing fluid Using supercritical carbon dioxide as a fracturing fluid The Laboratory team used a combination of experiments and modeling for the investigation. June 25, 2015 Simulation of a selection of the particle trajectories toward the well. Simulation of a selection of the particle trajectories toward the well. Communications Office (505) 667-7000 The Laboratory research is part of an ongoing project to make the necessary measurements and develop