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Sample records for ultra supercritical boilers

  1. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Ultra-Supercritical Pressure CFB Boiler ... Although CFB boilers as large as 300 MWe are now in operation, they are drum type, ...

  2. Materials development for ultra-supercritical boilers

    SciTech Connect (OSTI)

    2005-09-30

    Progress is reported on a US Department of Energy project to develop high temperature, corrosion resistant alloys for use in ultra-supercritical steam cycles. The aim is to achieve boiler operation at 1,400{sup o}F/5,000 psi steam conditions with 47% net cycle efficiency. Most ferritic steel tested such as T92 and Save 12 showed severe corrosion. Nickel-based alloys, especially IN 740 and CCA 617, showed greatest resistance to oxidation with no evidence of exfoliation. Laboratory and in-plant tests have begun. 2 figs.

  3. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study

    SciTech Connect (OSTI)

    Zhen Fan; Steve Goidich; Archie Robertson; Song Wu

    2006-06-30

    Electric utility interest in supercritical pressure steam cycles has revived in the United States after waning in the 1980s. Since supercritical cycles yield higher plant efficiencies than subcritical plants along with a proportional reduction in traditional stack gas pollutants and CO{sub 2} release rates, the interest is to pursue even more advanced steam conditions. The advantages of supercritical (SC) and ultra supercritical (USC) pressure steam conditions have been demonstrated in the high gas temperature, high heat flux environment of large pulverized coal-fired (PC) boilers. Interest in circulating fluidized bed (CFB) combustion, as an alternative to PC combustion, has been steadily increasing. Although CFB boilers as large as 300 MWe are now in operation, they are drum type, subcritical pressure units. With their sizes being much smaller than and their combustion temperatures much lower than those of PC boilers (300 MWe versus 1,000 MWe and 1600 F versus 3500 F), a conceptual design study was conducted herein to investigate the technical feasibility and economics of USC CFB boilers. The conceptual study was conducted at 400 MWe and 800 MWe nominal plant sizes with high sulfur Illinois No. 6 coal used as the fuel. The USC CFB plants had higher heating value efficiencies of 40.6 and 41.3 percent respectively and their CFB boilers, which reflect conventional design practices, can be built without the need for an R&D effort. Assuming construction at a generic Ohio River Valley site with union labor, total plant costs in January 2006 dollars were estimated to be $1,551/kW and $1,244/kW with costs of electricity of $52.21/MWhr and $44.08/MWhr, respectively. Based on the above, this study has shown that large USC CFB boilers are feasible and that they can operate with performance and costs that are competitive with comparable USC PC boilers.

  4. Evaluation of a 1000 MW Commercial Ultra Super-Critical Coal Boiler |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility prediction of instantaneous O2 mass fraction in a hypothetical commercial scale 1000 MW, Ultra Super-Critical (USC) coal boiler Large eddy simulation prediction of instantaneous O2 mass fraction in a hypothetical commercial scale 1000 MW, Ultra Super-Critical (USC) coal boiler. Simulation results may suggest new design features that can have an impact on the operation of current and next-generation USC boilers. Carbon Capture Multi-Disciplinary

  5. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect (OSTI)

    David W. Gandy; John P. Shingledecker

    2011-04-11

    Forced outages and boiler unavailability in conventional coal-fired fossil power plants is most often caused by fireside corrosion of boiler waterwalls. Industry-wide, the rate of wall thickness corrosion wastage of fireside waterwalls in fossil-fired boilers has been of concern for many years. It is significant that the introduction of nitrogen oxide (NOx) emission controls with staged burners systems has increased reported waterwall wastage rates to as much as 120 mils (3 mm) per year. Moreover, the reducing environment produced by the low-NOx combustion process is the primary cause of accelerated corrosion rates of waterwall tubes made of carbon and low alloy steels. Improved coatings, such as the MCrAl nanocoatings evaluated here (where M is Fe, Ni, and Co), are needed to reduce/eliminate waterwall damage in subcritical, supercritical, and ultra-supercritical (USC) boilers. The first two tasks of this six-task project-jointly sponsored by EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)-have focused on computational modeling of an advanced MCrAl nanocoating system and evaluation of two nanocrystalline (iron and nickel base) coatings, which will significantly improve the corrosion and erosion performance of tubing used in USC boilers. The computational model results showed that about 40 wt.% is required in Fe based nanocrystalline coatings for long-term durability, leading to a coating composition of Fe-25Cr-40Ni-10 wt.% Al. In addition, the long term thermal exposure test results further showed accelerated inward diffusion of Al from the nanocrystalline coatings into the substrate. In order to enhance the durability of these coatings, it is necessary to develop a diffusion barrier interlayer coating such TiN and/or AlN. The third task 'Process Advanced MCrAl Nanocoating Systems' of the six-task project jointly sponsored by the Electric Power Research Institute, EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)- has focused on processing of

  6. Computation Modeling and Assessment of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect (OSTI)

    J. Shingledecker; D. Gandy; N. Cheruvu; R. Wei; K. Chan

    2011-06-21

    Forced outages and boiler unavailability of coal-fired fossil plants is most often caused by fire-side corrosion of boiler waterwalls and tubing. Reliable coatings are required for Ultrasupercritical (USC) application to mitigate corrosion since these boilers will operate at a much higher temperatures and pressures than in supercritical (565 C {at} 24 MPa) boilers. Computational modeling efforts have been undertaken to design and assess potential Fe-Cr-Ni-Al systems to produce stable nanocrystalline coatings that form a protective, continuous scale of either Al{sub 2}O{sub 3} or Cr{sub 2}O{sub 3}. The computational modeling results identified a new series of Fe-25Cr-40Ni with or without 10 wt.% Al nanocrystalline coatings that maintain long-term stability by forming a diffusion barrier layer at the coating/substrate interface. The computational modeling predictions of microstructure, formation of continuous Al{sub 2}O{sub 3} scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. Advanced coatings, such as MCrAl (where M is Fe, Ni, or Co) nanocrystalline coatings, have been processed using different magnetron sputtering deposition techniques. Several coating trials were performed and among the processing methods evaluated, the DC pulsed magnetron sputtering technique produced the best quality coating with a minimum number of shallow defects and the results of multiple deposition trials showed that the process is repeatable. scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. The cyclic oxidation test results revealed that the nanocrystalline coatings offer better oxidation resistance, in terms of weight loss, localized oxidation, and formation of mixed oxides in the Al{sub 2}O{sub 3} scale, than widely used MCrAlY coatings. However, the ultra-fine grain structure in these coatings, consistent with the computational model predictions, resulted in accelerated Al

  7. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect (OSTI)

    Gandy, David W.; Shingledecker, John P.

    2011-05-11

    Coal-fired power plants are a significant part of the nation's power generating capacity, currently accounting for more than 55% of the country's total electricity production. Extending the reliable lifetimes of fossil fired boiler components and reducing the maintenance costs are essential for economic operation of power plants. Corrosion and erosion are leading causes of superheater and reheater boiler tube failures leading to unscheduled costly outages. Several types of coatings and weld overlays have been used to extend the service life of boiler tubes; however, the protection afforded by such materials was limited approximately one to eight years. Power companies are more recently focused in achieving greater plant efficiency by increasing steam temperature and pressure into the advanced-ultrasupercritical (A-USC) condition with steam temperatures approaching 760°C (1400°F) and operating pressures in excess of 35MPa (5075 psig). Unfortunately, laboratory and field testing suggests that the resultant fireside environment when operating under A-USC conditions can potentially cause significant corrosion to conventional and advanced boiler materials1-2. In order to improve reliability and availability of fossil fired A-USC boilers, it is essential to develop advanced nanostructured coatings that provide excellent corrosion and erosion resistance without adversely affecting the other properties such as toughness and thermal fatigue strength of the component material.

  8. Safe Use Limits for Advanced Ferritic Steels in Ultra-Supercritical Power Boilers.

    SciTech Connect (OSTI)

    Swindeman, RW

    2003-11-03

    In 2000, a Cooperative Research and Development Agreement (CRADA) was undertaken between the Oak Ridge National Laboratory (ORNL) and the Babcock & Wilcox Company to examine the databases for advanced ferritic steels and determine the safe limits for operation in supercritical steam power boilers. The materials of interest included the vanadium-modified 9-12% Cr steels with 1-2% Mo or W. The first task involved a review of pertinent information and the down-selection of a steel of special interest. The long-time database for 9Cr-1Mo-V steel was found to be most satisfactory for the examinations, and this steel was taken to be representative of the group. The second task involved the collection of aged and service exposed samples for metallurgical and mechanical testing. Here, aged samples to 75,000 hours, laboratory-tested samples to 83,000 hours, and service-exposed sample with up to 143,000 hours exposure were collected. The third task involved mechanical testing of exposed samples. Creep-rupture testing to long times was undertaken. Variable stress and temperature testing was included. Results were compared against the prediction of damage models. These models seemed to be adequate for life prediction. The fourth task involved the metallurgical examination of exposed specimens. Changes in microstructure were compared against published information on the evolution of microstructures in 9Cr-Mo-V steels and the results were found to be consistent with expectations. The fifth task involved a survey of steam and fireside corrosion. Data from the service-exposed tubing was examined, and a literature survey was undertaken as part of an activity in support of ultra-supercritical steam boiler technology. The corrosion study indicated some concerns about long-time fireside corrosion and suggested temperature limits were needed for corrosive coal ash conditions.

  9. Steam Oxidation and Chromia Evaporation in Ultra-Supercritical Steam Boilers and Turbines

    SciTech Connect (OSTI)

    Gordon H. Holcomb

    2009-01-01

    U.S. Department of Energy’s goals include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 °C and 340 atm, so-called ultra-supercritical (USC) conditions. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism. A methodology to calculate Cr evaporation rates from chromia scales was developed and combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles and to predict the time until breakaway oxidation. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. Alloy additions such as Ti may allow for a reduction in evaporation rate with time, mitigating the deleterious effects of chromia evaporation.

  10. Ultra Supercritical Steamside Oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

    2005-01-01

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  11. Conceptual Design of Supercritical O2-Based PC Boiler (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Conceptual Design of Supercritical O2-Based PC Boiler Citation Details In-Document Search Title: Conceptual Design of Supercritical O2-Based PC Boiler No abstract ...

  12. Conceptual Design of Supercritical O2-Based PC Boiler (Technical...

    Office of Scientific and Technical Information (OSTI)

    Conceptual Design of Supercritical O2-Based PC Boiler Citation Details In-Document Search Title: Conceptual Design of Supercritical O2-Based PC Boiler You are accessing a ...

  13. Super Boiler: First Generation, Ultra-High Efficiency Firetube Boiler

    SciTech Connect (OSTI)

    2006-06-01

    This factsheet describes a research project whose goal is to develop and demonstrate a first-generation ultra-high-efficiency, ultra-low emissions, compact gas-fired package boiler (Super Boiler), and formulate a long-range RD&D plan for advanced boiler technology out to the year 2020.

  14. ULTRA-SUPERCRITICAL STEAM CORROSION

    SciTech Connect (OSTI)

    Holcomb, G.R.; Alman, D.E.; Bullard, S.B.; Covino, B.S., Jr.; Cramer, S.D.; Ziomek-Moroz, M.

    2003-04-22

    Efficiency increases in fossil energy boilers and steam turbines are being achieved by increasing the temperature and pressure at the turbine inlets well beyond the critical point of water. To allow these increases, advanced materials are needed that are able to withstand the higher temperatures and pressures in terms of strength, creep, and oxidation resistance. As part of a larger collaborative effort, the Albany Research Center (ARC) is examining the steam-side oxidation behavior for ultrasupercritical (USC) steam turbine applications. Initial tests are being done on six alloys identified as candidates for USC steam boiler applications: ferritic alloy SAVE12, austenitic alloy Super 304H, the high Cr-high Ni alloy HR6W, and the nickel-base superalloys Inconel 617, Haynes 230, and Inconel 740. Each of these alloys has very high strength for its alloy type. Three types of experiments are planned: cyclic oxidation in air plus steam at atmospheric pressure, thermogravimetric ana lysis (TGA) in steam at atmospheric pressure, and exposure tests in supercritical steam up to 650 C (1202 F) and 34.5 MPa (5000 psi). The atmospheric pressure tests, combined with supercritical exposures at 13.8, 20.7, 24.6, and 34.5 MPa (2000, 3000, 4000, and 5000 psi) should allow the determination of the effect of pressure on the oxidation process.

  15. Ultra supercritical turbines--steam oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Ziomek-Moroz, Margaret; Alman, David E.

    2004-01-01

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy?s Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538?C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620?C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which would require steam temperatures of up to 760?C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  16. Model-free adaptive control of supercritical circulating fluidized-bed boilers

    DOE Patents [OSTI]

    Cheng, George Shu-Xing; Mulkey, Steven L

    2014-12-16

    A novel 3-Input-3-Output (3.times.3) Fuel-Air Ratio Model-Free Adaptive (MFA) controller is introduced, which can effectively control key process variables including Bed Temperature, Excess O2, and Furnace Negative Pressure of combustion processes of advanced boilers. A novel 7-input-7-output (7.times.7) MFA control system is also described for controlling a combined 3-Input-3-Output (3.times.3) process of Boiler-Turbine-Generator (BTG) units and a 5.times.5 CFB combustion process of advanced boilers. Those boilers include Circulating Fluidized-Bed (CFB) Boilers and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  17. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study...

    Office of Scientific and Technical Information (OSTI)

    Assuming construction at a generic Ohio River Valley site with union labor, total plant costs in January 2006 dollars were estimated to be 1,551kW and 1,244kW with costs of ...

  18. Economic Analysis for Conceptual Design of Supercritical O2-Based PC Boiler

    SciTech Connect (OSTI)

    Andrew Seltzer; Archie Robertson

    2006-09-01

    This report determines the capital and operating costs of two different oxygen-based, pulverized coal-fired (PC) power plants and compares their economics to that of a comparable, air-based PC plant. Rather than combust their coal with air, the oxygen-based plants use oxygen to facilitate capture/removal of the plant CO{sub 2} for transport by pipeline to a sequestering site. To provide a consistent comparison of technologies, all three plants analyzed herein operate with the same coal (Illinois No 6), the same site conditions, and the same supercritical pressure steam turbine (459 MWe). In the first oxygen-based plant, the pulverized coal-fired boiler operates with oxygen supplied by a conventional, cryogenic air separation unit, whereas, in the second oxygen-based plant, the oxygen is supplied by an oxygen ion transport membrane. In both oxygen-based plants a portion of the boiler exhaust gas, which is primarily CO{sub 2}, is recirculated back to the boiler to control the combustion temperature, and the balance of the flue gas undergoes drying and compression to pipeline pressure; for consistency, both plants operate with similar combustion temperatures and utilize the same CO{sub 2} processing technologies. The capital and operating costs of the pulverized coal-fired boilers required by the three different plants were estimated by Foster Wheeler and the balance of plant costs were budget priced using published data together with vendor supplied quotations. The cost of electricity produced by each of the plants was determined and oxygen-based plant CO{sub 2} mitigation costs were calculated and compared to each other as well as to values published for some alternative CO{sub 2} capture technologies.

  19. Cast Alloys for Advanced Ultra Supercritical Steam Turbines

    SciTech Connect (OSTI)

    G. R. Holcomb, P. Wang, P. D. Jablonski, and J. A. Hawk,

    2010-05-01

    The proposed steam inlet temperature in the Advanced Ultra Supercritical (A-USC) steam turbine is high enough (760 °C) that traditional turbine casing and valve body materials such as ferritic/martensitic steels will not suffice due to temperature limitations of this class of materials. Cast versions of several traditionally wrought Ni-based superalloys were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantial: 2-5,000 kg each half and on the order of 100 cm thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equivalent microstructures. A multi-step homogenization heat treatment was developed to better deploy the alloy constituents. The most successful of these cast alloys in terms of creep strength (Haynes 263, Haynes 282, and Nimonic 105) were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (at 760 and 800 °C).

  20. Superalloys for ultra supercritical steam turbines--oxidation behavior

    SciTech Connect (OSTI)

    Holcomb, G.R.

    2008-09-01

    Goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 °C and 340 atm, so called ultra-supercritical (USC) steam conditions. One of the important materials performance considerations is steam-side oxidation resistance. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism under USC conditions. A methodology to calculate Cr evaporation rates from chromia scales with cylindrical geometries was developed that allows for the effects of CrO2(OH)2 saturation within the gas phase. This approach was combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles as a function of exposure time and to predict the time until the alloy surface concentration of Cr reaches zero. This time is a rough prediction of the time until breakaway oxidation. A hypothetical superheater tube, steam pipe, and high pressure turbine steam path was examined. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. The predicted time until breakaway oxidation increases dramatically with decreases in temperature and total pressure. Possible mitigation techniques were discussed, including those used in solid oxide fuel cell metallic interconnects (lowering the activity of Cr in the oxide scale by adding Mn to the alloy), and thermal barrier coating use on high pressure turbine blades for both erosion and chromia evaporation protection.

  1. Experimental investigation on heat transfer and frictional characteristics of vertical upward rifled tube in supercritical CFB boiler

    SciTech Connect (OSTI)

    Yang, Dong; Pan, Jie; Zhu, Xiaojing; Bi, Qincheng; Chen, Tingkuan; Zhou, Chenn Q.

    2011-02-15

    Water wall design is a key issue for supercritical Circulating Fluidized Bed (CFB) boiler. On account of the good heat transfer performance, rifled tube is applied in the water wall design of a 600 MW supercritical CFB boiler in China. In order to investigate the heat transfer and frictional characteristics of the rifled tube with vertical upward flow, an in-depth experiment was conducted in the range of pressure from 12 to 30 MPa, mass flux from 230 to 1200 kg/(m{sup 2} s), and inner wall heat flux from 130 to 720 kW/m{sup 2}. The wall temperature distribution and pressure drop in the rifled tube were obtained in the experiment. The normal, enhanced and deteriorated heat transfer characteristics were also captured. In this paper, the effects of pressure, inner wall heat flux and mass flux on heat transfer characteristics are analyzed, the heat transfer mechanism and the frictional resistance performance are discussed, and the corresponding empirical correlations are presented. The experimental results show that the rifled tube can effectively prevent the occurrence of departure from nucleate boiling (DNB) and keep the tube wall temperature in a permissible range under the operating condition of supercritical CFB boiler. (author)

  2. Cast Alloys for Advanced Ultra Supercritical Steam Turbines

    SciTech Connect (OSTI)

    G. R. Holcomb, P. D. Jablonski, and P. Wang

    2010-10-01

    Develop advanced coal-based power systems capable of 45–50 % efficiency at <$1,000/kW (in 2002 dollars). Develop technologies for capture and sequestration of CO2 that result in: • <10% increase in the cost of electricity in an IGCC-based plant • <35% increase in the cost of electricity for pulverized coal boilers Demonstrate coal-based energy plants that offer near-zero emissions (including CO2) with multiproduct production

  3. Modeling Creep-Fatigue-Environment Interactions in Steam Turbine Rotor Materials for Advanced Ultra-supercritical Coal Power Plants

    SciTech Connect (OSTI)

    Shen, Chen

    2014-04-01

    The goal of this project is to model creep-fatigue-environment interactions in steam turbine rotor materials for advanced ultra-supercritical (A-USC) coal power Alloy 282 plants, to develop and demonstrate computational algorithms for alloy property predictions, and to determine and model key mechanisms that contribute to the damages caused by creep-fatigue-environment interactions.

  4. Economic Analysis for Conceptual Design of Supercritical O2-Based...

    Office of Scientific and Technical Information (OSTI)

    Economic Analysis for Conceptual Design of Supercritical O2-Based PC Boiler Citation Details In-Document Search Title: Economic Analysis for Conceptual Design of Supercritical ...

  5. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and

  6. US program on materials technology for ultra-supercritical coal power plants

    SciTech Connect (OSTI)

    Viswanathan, R.; Henry, J.F.; Tanzosh, J.; Stanko, G.; Shingledecker, J.; Vitalis, B.; Purgert, R.

    2005-06-01

    The study reported on here is aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers that are capable of operating with steam at temperatures of 760{sup o}C (1400{sup o}F) and pressures of 35 MPa (5000 psi). The economic viability of such a plant has been explored. Candidate alloys applicable to various ranges of temperatures have been identified. Stress rupture tests have been completed on the base metal and on welds to a number of alloys. Steamside oxidation tests in an autoclave at 650{sup o}C (1200{sup o}F) and 800{sup o}C (1475 {sup o}F) have been completed. Fireside corrosion tests have been conducted under conditions simulating those of waterwalls and superheater/reheater tubes. The weldability and fabricability of the alloys have been investigated. The capabilities of various overlay coatings and diffusion coatings have been examined. This article provides a status report on the progress achieved to date on this project.

  7. Evaluation of the Materials Technology Required for a 760?C Power Steam Boiler

    SciTech Connect (OSTI)

    Shingledecker, John P; Wright, Ian G

    2006-01-01

    The U.S. Ultra-supercritical (USC) Steam Boiler Consortium, funded by the U.S. Department of Energy and the Ohio Coal Development Office, has been working to develop the necessary materials technology to construct a steam power boiler with maximum steam conditions of 760 C and 35MPa. One large component of this work is to evaluate the properties of the materials chosen for such a boiler. While long-term creep strength of base metal is initially used to set temperatures, stresses, and simple design rules, it is clear that base metal creep strength is not always the material property of most importance when selecting an alloy. The fabrication issues (typically weldability), the properties of materials after fabrication, the corrosion resistance of the material, and material cost all need to be considered in addition to baseline mechanical properties. Work is ongoing at Oak Ridge National Laboratory to evaluate the material technologies being developed by the USC Steam Boiler Consortium and perform additional advanced research activities in areas where new materials developments and better fundamental understanding are needed to ensure the long-term success of a 760 C power steam boiler.

  8. Engineering development of advanced coal-fired low emission boiler systems

    SciTech Connect (OSTI)

    Not Available

    1993-10-01

    Riley Stoker Corporation is leading an R&D program for the expedited development of a new generation of pulverized coal-fired boiler systems. The overall objective is to develop relatively near term technologies to produce Low-Emission coal-fired Boiler Systems (LEBS) ready for full scale commercial generating plants by the end of the decade. The specific goal is to develop a LEBS incorporating an advanced slagging system for improved ash management in addition to meeting the emission and performance goals. This Concept Selection Report documents an evaluation of subsystems and LEBS concepts. Priority was given to the evaluation of the boiler system, steam cycle, and advanced slagging combustor. Some findings are as follows: An ultra supercritical steam cycle is required to meet project efficiency goals. The cost of electricity (COE) for this cycle, at today`s fuel prices, and without externality costs, is slightly higher than a conventional subcritical cycle. The supercritical cycle includes a substantial contingency. Reduction of contingency, escalation of fuel cost, or inclusion of externalities all lead to a lower COE for the supercritical cycle compared to the subcritical cycle. The advanced cycle is selected for inclusion in the LEBS. The advanced slagging combustor (TVC), should it meet the projected performance goals, yields a lower COE than either a dry firing system or a more conventional slagger fitted with post combustion NO{sub x} controls. Verification and development of the advanced slagger performance is the primary focus of this project. A commercial slagging configuration know as U-firing is selected for parallel development and as a platform for adaptation to the TVC.

  9. Super Boiler 2nd Generation Technology for Watertube Boilers

    SciTech Connect (OSTI)

    Mr. David Cygan; Dr. Joseph Rabovitser

    2012-03-31

    This report describes Phase I of a proposed two phase project to develop and demonstrate an advanced industrial watertube boiler system with the capability of reaching 94% (HHV) fuel-to-steam efficiency and emissions below 2 ppmv NOx, 2 ppmv CO, and 1 ppmv VOC on natural gas fuel. The boiler design would have the capability to produce >1500 F, >1500 psig superheated steam, burn multiple fuels, and will be 50% smaller/lighter than currently available watertube boilers of similar capacity. This project is built upon the successful Super Boiler project at GTI. In that project that employed a unique two-staged intercooled combustion system and an innovative heat recovery system to reduce NOx to below 5 ppmv and demonstrated fuel-to-steam efficiency of 94% (HHV). This project was carried out under the leadership of GTI with project partners Cleaver-Brooks, Inc., Nebraska Boiler, a Division of Cleaver-Brooks, and Media and Process Technology Inc., and project advisors Georgia Institute of Technology, Alstom Power Inc., Pacific Northwest National Laboratory and Oak Ridge National Laboratory. Phase I of efforts focused on developing 2nd generation boiler concepts and performance modeling; incorporating multi-fuel (natural gas and oil) capabilities; assessing heat recovery, heat transfer and steam superheating approaches; and developing the overall conceptual engineering boiler design. Based on our analysis, the 2nd generation Industrial Watertube Boiler when developed and commercialized, could potentially save 265 trillion Btu and $1.6 billion in fuel costs across U.S. industry through increased efficiency. Its ultra-clean combustion could eliminate 57,000 tons of NOx, 460,000 tons of CO, and 8.8 million tons of CO2 annually from the atmosphere. Reduction in boiler size will bring cost-effective package boilers into a size range previously dominated by more expensive field-erected boilers, benefiting manufacturers and end users through lower capital costs.

  10. PARTICULATE CHARACTERIZATION AND ULTRA LOW-NOx BURNER FOR THE CONTROL OF NO{sub x} AND PM{sub 2.5} FOR COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Ralph Bailey; Hamid Sarv; Jim Warchol; Debi Yurchison

    2001-09-30

    In response to the serious challenge facing coal-fired electric utilities with regards to curbing their NO{sub x} and fine particulate emissions, Babcock and Wilcox and McDermott Technology, Inc. conducted a project entitled, ''Particulate Characterization and Ultra Low-NO{sub x} Burner for the Control of NO{sub x} and PM{sub 2.5} for Coal Fired Boilers.'' The project included pilot-scale demonstration and characterization of technologies for removal of NO{sub x} and primary PM{sub 2.5} emissions. Burner development and PM{sub 2.5} characterization efforts were based on utilizing innovative concepts in combination with sound scientific and fundamental engineering principles and a state-of-the-art test facility. Approximately 1540 metric tonnes (1700 tons) of high-volatile Ohio bituminous coal were fired. Particulate sampling for PM{sub 2.5} emissions characterization was conducted in conjunction with burner testing. Based on modeling recommendations, a prototype ultra low-NO{sub x} burner was fabricated and tested at 100 million Btu/hr in the Babcock and Wilcox Clean Environment Development Facility. Firing the unstaged burner with a high-volatile bituminous Pittsburgh 8 coal at 100 million Btu/hr and 17% excess air achieved a NO{sub x} goal of 0.20 lb NO{sub 2}/million Btu with a fly ash loss on ignition (LOI) of 3.19% and burner pressure drop of 4.7 in H{sub 2}O for staged combustion. With the burner stoichiometry set at 0.88 and the overall combustion stoichiometry at 1.17, average NO{sub x} and LOI values were 0.14 lb NO{sub 2}/million Btu and 4.64% respectively. The burner was also tested with a high-volatile Mahoning 7 coal. Based on the results of this work, commercial demonstration is being pursued. Size classified fly ash samples representative of commercial low-NO{sub x} and ultra low-NO{sub x} combustion of Pittsburgh 8 coal were collected at the inlet and outlet of an ESP. The mass of size classified fly ash at the ESP outlet was sufficient to evaluate

  11. Advanced, Low/Zero Emission Boiler Design and Operation

    SciTech Connect (OSTI)

    Babcock Illinois State Geological; Worley Parsons; Parsons Infrastructure /Technology Group

    2007-06-30

    In partnership with the U.S. Department of Energy's National Energy Technology Laboratory, B&W and Air Liquide are developing and optimizing the oxy-combustion process for retrofitting existing boilers as well as new plants. The main objectives of the project is to: (1) demonstrate the feasibility of the oxy-combustion technology with flue gas recycle in a 5-million Btu/hr coal-fired pilot boiler, (2) measure its performances in terms of emissions and boiler efficiency while selecting the right oxygen injection and flue gas recycle strategies, and (3) perform technical and economic feasibility studies for application of the technology in demonstration and commercial scale boilers. This document summarizes the work performed during the period of performance of the project (Oct 2002 to June 2007). Detailed technical results are reported in corresponding topical reports that are attached as an appendix to this report. Task 1 (Site Preparation) has been completed in 2003. The experimental pilot-scale O{sub 2}/CO{sub 2} combustion tests of Task 2 (experimental test performance) has been completed in Q2 2004. Process simulation and cost assessment of Task 3 (Techno-Economic Study) has been completed in Q1 2005. The topical report on Task 3 has been finalized and submitted to DOE in Q3 2005. The calculations of Task 4 (Retrofit Recommendation and Preliminary Design of a New Generation Boiler) has been completed in 2004. In Task 6 (engineering study on retrofit applications), the engineering study on 25MW{sub e} unit has been completed in Q2, 2008 along with the corresponding cost assessment. In Task 7 (evaluation of new oxy-fuel power plants concepts), based on the design basis document prepared in 2005, the design and cost estimate of the Air Separation Units, the boiler islands and the CO{sub 2} compression and trains have been completed, for both super and ultra-supercritical case study. Final report of Task-7 is published by DOE in Oct 2007.

  12. Ultra-High Efficiency Industrial Steam Generation R&D Opportunities

    SciTech Connect (OSTI)

    none,

    2005-01-01

    The workshop report outlines the R&D priorities for the next generation of ultra-high efficiency boilers.

  13. Super Boiler Update

    SciTech Connect (OSTI)

    2007-10-01

    This presentation from the 2007 American Boiler Manufacturers Association Manufacturers Conference provides an update of the First Generation Super Boiler.

  14. Choosing the right boiler air fans at Weston 4

    SciTech Connect (OSTI)

    Spring, N.

    2009-04-15

    When it came to choosing the three 'big' boiler air fans - forced draft, induced draft and primary air, the decision revolved around efficiency. The decision making process for fan selection for the Western 4 supercritical coal-fired plant is described in this article. 3 photos.

  15. Fossil-Fired Boilers

    Energy Science and Technology Software Center (OSTI)

    1993-09-23

    Boiler Performance Model (BPM 3.0S) is a set of computer programs developed to analyze the performance of fossil-fired utility boilers. The programs can model a wide variety of boiler designs, and can model coal, oil, or natural gas firing. The programs are intended for use by engineers performing analyses of alternative fuels, alternative operating modes, or boiler modifications.

  16. Boiler and cooling water basics

    SciTech Connect (OSTI)

    Ketrick, B.T.

    1995-06-01

    Boiler Water Treatment products and programs are used in boiler systems to prevent the formation of water side deposits and corrosion. Water side deposits will cause a loss of boiler efficiency, as well as, damage to the boiler internals. Corrosion can cause a loss of boiler metal integrity. Both conditions can lead to a reduced operating life for the boiler and costly annual repairs.

  17. What is Supercritical CO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is Supercritical CO 2 ? Supercritical CO 2 is a fluid state of carbon dioxide where it is held above its critical pressure and critical temperature, which causes the gas to go beyond liquid or gas into a phase where it acts as both simultaneously. Many fluids can achieve supercritical states, and supercritical steam has been used in power generation for decades. Supercritical CO 2 has many unique properties that allow it to dissolve materials like a liquid but also flow like a gas. The Sandia

  18. CHP Integrated with Burners for Packaged Boilers - Fact Sheet, April 2014 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy CHP Integrated with Burners for Packaged Boilers - Fact Sheet, April 2014 CHP Integrated with Burners for Packaged Boilers - Fact Sheet, April 2014 CMCE, Inc., in collaboration with Altex Technologies Corporation, developed the Boiler Burner Energy System Technology (BBEST), a CHP assembly of a gas-fired simple-cycle 100 kilowatt (kW) microturbine and a new ultra-low NOx gas-fired burner, to increase acceptance of small CHP systems.

  19. Second Generation Super Boiler Technology for Watertube Boilers

    SciTech Connect (OSTI)

    2007-07-01

    This factsheet describes a research project to develop a high-pressure watertube boiler system that incorporates and improves upon the capabilities of the firetube Super Boiler system.

  20. Minimize Boiler Blowdown

    Broader source: Energy.gov [DOE]

    This tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  1. Minimize Boiler Blowdown

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  2. Supercritical fluid extraction

    DOE Patents [OSTI]

    Wai, Chien M.; Laintz, Kenneth

    1994-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated or lipophilic crown ether or fluorinated dithiocarbamate. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  3. Promising Technology: Condensing Gas Boilers

    Broader source: Energy.gov [DOE]

    Condensing boilers achieve higher efficiencies than conventional boilers by capturing the latent heat from water vapor contained in the flue gases.

  4. Boiler MACT | Department of Energy

    Office of Environmental Management (EM)

    Boiler MACT Boiler MACT DOE currently provides technical assistance on combined heat and power (CHP) technologies to commercial and industrial facilities through its seven ...

  5. A Comparison of Creep-Rupture Tested Cast Alloys HR282, IN740 and 263 for Possible Application in Advanced Ultrasupercritical Steam Turbine and Boiler

    SciTech Connect (OSTI)

    Jablonski, P D; Evens, N; Yamamoto, Y; Maziasz, P

    2011-02-27

    Cast forms of traditionally wrought Ni-base precipitation-strengthened superalloys are being considered for service in the ultra-supercritical conditions (760°C, 35MPa) of next-generation steam boilers and turbines. After casting and homogenization, these alloys were given heat-treatments typical for each in the wrought condition to develop the gamma-prime phase. Specimens machined from castings were creep-rupture tested in air at 800°C. In their wrought forms, alloy 282 is expected to precipitate M23C6 within grain boundaries, alloy 740 is expected to precipitate several grain boundary phases including M23C6, G Phase, and η phase, and alloy 263 has M23C6 and MC within its grain boundaries. This presentation will correlate the observed creep-life of these cast alloys with the microstructures developed during creep-rupture tests, with an emphasis on the phase identification and chemistry of precipitated grain boundary phases. The suitability of these cast forms of traditionally wrought alloys for turbine and boiler components will also be discussed.

  6. Combined Heat and Power Integrated with Burners for Packaged Boilers

    SciTech Connect (OSTI)

    2010-10-01

    This factsheet describes a project that will seamlessly integrate a gas-fired simple-cycle 100 kWe microturbine with a new ultra-low NOx gas-fired burner to develop a CHP assembly called the Boiler Burner Energy System Technology.

  7. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year

  8. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to

  9. Biomass Boiler for Food Processing Applications | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Boiler for Food Processing Applications Biomass Boiler for Food Processing Applications Biomass Boiler Uses a Combination of Wood Waste and Tire-Derived Fuel In 2011, the ...

  10. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-10-27

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2005.

  11. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-04-27

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  12. Boiler Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-01-31

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2005.

  13. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2004-10-30

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April to June 30, 2004.

  14. Improve Your Boiler's Combustion Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE)

    This tip sheet outlines how to improve boiler combustion efficiency as part of an optimized steam system.

  15. Recover Heat from Boiler Blowdown, Energy Tips: STEAM, Steam...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 Recover Heat from Boiler Blowdown Heat can be recovered from boiler blowdown by using a heat exchanger to preheat boiler makeup water. Any boiler with continuous blowdown ...

  16. materials | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials for Advanced Steam Cycles Materials for Ultra-Supercritical Coal-Fired Power Plant Boilers R. Viswanathan, EPRI Presentation Coal Ash Corrosion Resistant Materials ...

  17. Minimize Boiler Short Cycling Losses

    Office of Energy Efficiency and Renewable Energy (EERE)

    This tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  18. Return Condensate to the Boiler

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on returning condensate to boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  19. Improve Your Boiler's Combustion Efficiency

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on boiler combustion efficiency provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  20. Supercritical Carbon Dioxide / Reservoir Rock Chemical Interactions...

    Open Energy Info (EERE)

    Supercritical Carbon Dioxide Reservoir Rock Chemical Interactions Jump to: navigation, search Geothermal Lab Call Projects for Supercritical Carbon Dioxide Reservoir Rock...

  1. Preparation, Injection and Combustion of Supercritical Fluids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation ...

  2. Supercritical CO2 Tech Team

    Broader source: Energy.gov [DOE]

    Supercritical CO2 is a highly technical team focused on different heat source applications of the sCO2 Brayton Cycle.

  3. Supercritical fluid reverse micelle systems

    DOE Patents [OSTI]

    Fulton, John L.; Smith, Richard D.

    1992-01-01

    of 1 ) United States Patent 5,158,704 Fulton ,   et al. October 27, 1992 Supercritical fluid reverse micelle systems

  4. Boiler Maximum Achievable Control Technology (MACT) Technical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Boiler Maximum Achievable Control Technology (MACT) Technical Assistance - Fact Sheet, April 2015 Boiler Maximum Achievable Control Technology (MACT) Technical Assistance - Fact ...

  5. Boiler Combustion Control and Monitoring System | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... What Were the Benefits? boilercombustionchart.jpg The boiler combustion control and monitoring system was installed on a 25 MMBtuhr steam boiler located at the Watervliet ...

  6. Small boiler uses waste coal

    SciTech Connect (OSTI)

    Virr, M.J.

    2009-07-15

    Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

  7. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers This fact sheet describes a supercritical carbon ...

  8. Temperature Evolution and Oxide Growth in Waterwall Tubes of Supercritical Units

    SciTech Connect (OSTI)

    Sabau, Adrian S; Wright, Ian G; Zhang, Wei; Pint, Bruce A; Unocic, Kinga A

    2010-01-01

    In order to understand the failures in some waterwall tubes of supercritical steam boilers, an analysis is required to estimate the temperature of the waterwall tubes and the oxide growth in these tubes. A review on the thermophysical properties of oxide grown in waterwall tubes was conducted. Specimens of waterwall tubes associated with thermal fatigue cracking were obtained and microstructural analyses, using metallographic and electron-optical techniques such as SEM and electron-probe microanalysis, were performed. A computer model is being developed to estimate the maximum temperature in waterwall tubes by considering several phenomena that take place in supercritical units. The comprehensive model includes the following boiler operation features and phenomena: oxide growth, distribution of the heat flux on the waterwall tube as a function of height distance, variation of steam flow rate due to load variation, variation of heat flux due to load variation, and variation of the heat transfer coefficient with steam conditions and furnace heat flux. The model will handle the transition subcritical-to-supercritical and will account for the heat transfer deterioration phenomena in tubes. The tube regions with deteriorated heat transfer regimes will be identified. The temperatures of steam, metal, and oxide will be obtained as a function of the height distance in the boiler. The mixing effects of the steam from different waterwall tubes and subsequent fluid dynamics effects on the heat transfer will be considered. The new model will enable the prediction of the maximum metal temperature for realistic boiler operation schedule, which include transitions from full-to-low loads. Based on the estimated data for the steam temperature, metal temperature, and oxide thickness, regions of the waterwall tubes that are exposed to the most severe conditions will be identified.

  9. Utilizing Supplemental Ultra-Low-NO

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supplemental Ultra-Low-NO x Burner Technology to Meet Emissions Standards and Improve System Efficiency This project developed a Flexible Combined Heat and Power (FlexCHP) system that incorporates new burner technology into a 65-kilowatt (kW) microturbine and 100-horsepower (HP) heat recovery boiler. Introduction A combined heat and power (CHP) system can be a fnancially attractive energy option for many industrial and commercial facilities. This is particularly the case in areas of the country

  10. Minimize Boiler Short Cycling Losses, Energy Tips: STEAM, Steam...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 Minimize Boiler Short Cycling Losses Boiler "short cycling" occurs when an oversized boiler quickly satisfes process or space heating demands, and then shuts down until heat is ...

  11. Minimize Boiler Short Cycling Losses | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Minimize Boiler Short Cycling Losses Minimize Boiler Short Cycling Losses This tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial...

  12. Best Management Practice #8: Steam Boiler Systems | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8: Steam Boiler Systems Best Management Practice 8: Steam Boiler Systems Steam boilers are commonly used in large heating systems, institutional kitchens, or in facilities where ...

  13. Purchasing Energy-Efficient Residential Gas Boilers | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas Boilers Purchasing Energy-Efficient Residential Gas Boilers The Federal Energy Management Program (FEMP) provides acquisition guidance for residential gas boilers, a product ...

  14. Minimize Boiler Short Cycling Losses

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  15. Recover Heat from Boiler Blowdown

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on recovering heat from boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  16. Boiler-turbine life extension

    SciTech Connect (OSTI)

    Natzkov, S.; Nikolov, M.

    1995-12-01

    The design life of the main power equipment-boilers and turbines is about 105 working hours. The possibilities for life extension are after normatively regulated control tests. The diagnostics and methodology for Boilers and Turbines Elements Remaining Life Assessment using up to date computer programs, destructive and nondestructive control of metal of key elements of units equipment, metal creep and low cycle fatigue calculations. As well as data for most common damages and some technical decisions for elements life extension are presented.

  17. Supercritical CO2-Brayton Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supercritical CO2-Brayton Cycle - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs

  18. Furnaces and Boilers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Home Heating Systems » Furnaces and Boilers Furnaces and Boilers Upgrading to a high efficiency furnace or boiler is an effective way to save money on home heating. Upgrading to a high efficiency furnace or boiler is an effective way to save money on home heating. Most U.S. homes are heated with either furnaces or boilers. Furnaces heat air and distribute the heated air through the house using ducts. Boilers heat water, and provide either hot water or steam for heating. Steam is distributed via

  19. Gas-Fired Boilers and Furnaces | Department of Energy

    Energy Savers [EERE]

    A vent damper prevents chimney losses by closing off a boiler's vent when the boiler isn't firing. Steam boilers benefit from vent dampers more than hot water boilers, and bigger ...

  20. Boiler using combustible fluid

    DOE Patents [OSTI]

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  1. NOx Control for Utility Boiler OTR Compliance

    SciTech Connect (OSTI)

    Hamid Farzan

    2003-12-31

    Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), the Babcock and Wilcox Company (B and W), and Fuel Tech teamed together to investigate an integrated solution for NO{sub x} control. The system is comprised of B and W's DRB-4Z{trademark} ultra low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NOxOUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. Development of the low-NO{sub x} burner technology has been a focus in B and W's combustion program. The DRB-4Z{trademark} burner is B and W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by controlled mixing of the fuel and air. Based on data from several 500 to 600 MWe boilers firing PRB coal, NOx emissions levels of 0.15 to 0.20 lb/ 106 Btu have been achieved from the DRB-4Z{trademark} burners in combination with overfire air ports. Although NOx emissions from the DRB-4Z{trademark} burner are nearing the Ozone Transport Rule (OTR) level of 0.15 lb NO{sub x}/106 Btu, the utility boiler owners can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them. Large-scale testing is planned in B and W's 100-million Btu/hr Clean Environment Development Facility (CEDF) that simulates the conditions of large coal-fired utility boilers. The objective of the project is to achieve a NO{sub x} level below 0.15 lb/106 Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B and W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign}. During this period B and W prepared and submitted the project management plan and hazardous substance plan to DOE. The negotiation of a subcontract for Fuel Tech has been started.

  2. Ultra Violet Waterworks (UVW)

    Office of Scientific and Technical Information (OSTI)

    Ultra Violet Waterworks Water Disinfecting Device Saves Lives Resources with Additional Information Ultra Violet Waterworks (UVW) device Ultra Violet Waterworks (UVW) is a...

  3. Next Generation Engineered Materials for Ultra Supercritical Steam Turbines

    SciTech Connect (OSTI)

    Douglas Arrell

    2006-05-31

    To reduce the effect of global warming on our climate, the levels of CO{sub 2} emissions should be reduced. One way to do this is to increase the efficiency of electricity production from fossil fuels. This will in turn reduce the amount of CO{sub 2} emissions for a given power output. Using US practice for efficiency calculations, then a move from a typical US plant running at 37% efficiency to a 760 C /38.5 MPa (1400 F/5580 psi) plant running at 48% efficiency would reduce CO2 emissions by 170kg/MW.hr or 25%. This report presents a literature review and roadmap for the materials development required to produce a 760 C (1400 F) / 38.5MPa (5580 psi) steam turbine without use of cooling steam to reduce the material temperature. The report reviews the materials solutions available for operation in components exposed to temperatures in the range of 600 to 760 C, i.e. above the current range of operating conditions for today's turbines. A roadmap of the timescale and approximate cost for carrying out the required development is also included. The nano-structured austenitic alloy CF8C+ was investigated during the program, and the mechanical behavior of this alloy is presented and discussed as an illustration of the potential benefits available from nano-control of the material structure.

  4. Sootblowing optimization for improved boiler performance

    DOE Patents [OSTI]

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J

    2013-07-30

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  5. Sootblowing optimization for improved boiler performance

    DOE Patents [OSTI]

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J.

    2012-12-25

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  6. CHP Integrated with Burners for Packaged Boilers

    SciTech Connect (OSTI)

    Castaldini, Carlo; Darby, Eric

    2013-09-30

    The objective of this project was to engineer, design, fabricate, and field demonstrate a Boiler Burner Energy System Technology (BBEST) that integrates a low-cost, clean burning, gas-fired simple-cycle (unrecuperated) 100 kWe (net) microturbine (SCMT) with a new ultra low-NOx gas-fired burner (ULNB) into one compact Combined Heat and Power (CHP) product that can be retrofit on new and existing industrial and commercial boilers in place of conventional burners. The Scope of Work for this project was segmented into two principal phases: (Phase I) Hardware development, assembly and pre-test and (Phase II) Field installation and demonstration testing. Phase I was divided into five technical tasks (Task 2 to 6). These tasks covered the engineering, design, fabrication, testing and optimization of each key component of the CHP system principally, ULNB, SCMT, assembly BBEST CHP package, and integrated controls. Phase I work culminated with the laboratory testing of the completed BBEST assembly prior to shipment for field installation and demonstration. Phase II consisted of two remaining technical tasks (Task 7 and 8), which focused on the installation, startup, and field verification tests at a pre-selected industrial plant to document performance and attainment of all project objectives. Technical direction and administration was under the management of CMCE, Inc. Altex Technologies Corporation lead the design, assembly and testing of the system. Field demonstration was supported by Leva Energy, the commercialization firm founded by executives at CMCE and Altex. Leva Energy has applied for patent protection on the BBEST process under the trade name of Power Burner and holds the license for the burner currently used in the product. The commercial term Power Burner is used throughout this report to refer to the BBEST technology proposed for this project. The project was co-funded by the California Energy Commission and the Southern California Gas Company (SCG), a

  7. Covered Product Category: Commercial Boilers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance and Federal efficiency requirements for commercial boilers, which is a FEMP-designated product category. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

  8. DB Riley-low emission boiler system (LEBS): Superior power for the 21st century

    SciTech Connect (OSTI)

    Beittel, R.; Ruth, L.A.

    1997-12-31

    In conjunction with the US Department of Energy, DB Riley, Inc., is developing a highly advanced coal-fired power-generation plant called the Low Emission Boiler Systems (LEBS). By the year 2000, LEBS will provide the US electric power industry with a reliable, efficient, cost-effective, environmentally superior alternative to current technologies. LEBS incorporates significant advances in coal combustion, supercritical steam boiler design, environmental control, and materials development. The system will include a state-of-the-art steam cycle operating at supercritical steam conditions; a slagging combustor that produces vitrified ash by-products; low nitrogen oxide (NOx) burners; a new, dry, regenerable flue gas cleanup system (copper oxide process) for simultaneously capturing sulfur dioxide (SO{sub 2}) and nitrogen oxides (NOx); a pulse-jet fabric filter for particulate capture; and a low-temperature heat-recovery system. The copper oxide flue gas cleanup system, which has been under development at DOE`s Pittsburgh field center, removes over 98% of SO{sub 2} and 95% of NOx from flue gas. A new moving-bed design provides efficient sorbent utilization that lowers the cleanup process cost. The captured SO{sub 2} can be converted to valuable by-products such as sulfuric acid and/or element sulfur, and the process generates no waste.

  9. Boiler - tuning basics, part 1

    SciTech Connect (OSTI)

    Leopold, T.

    2009-03-15

    Tuning power plant controls takes nerves of steel and an intimate knowledge of plant systems gained only by experience. Tuning controls also requires equal parts art and science, which probably is why there are so few tuning experts in the power industry. In part 1 of a two-part series, the author explores a mix of the theoretical and practical aspects of tuning boiler control. 5 figs.

  10. Fluidized bed boiler feed system

    DOE Patents [OSTI]

    Jones, Brian C.

    1981-01-01

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  11. Unmanned boiler operation a reality in Europe

    SciTech Connect (OSTI)

    Ilg, E.

    1996-08-01

    With the rise in liquid level technology in Europe comes new standards for boiler operation. SMART technology for level probes and auxiliary equipment, means many European countries allow a boiler to operate completely unmanned (without operators) for up to 72 hours at a time. It is not just a level control system, but a total boiler control scheme. This incorporates level control, continuous TDS monitoring with blowdown, automatic timed bottom blowdown, feed water control, contamination detection systems for monitoring of incoming feed water, monitoring of exhaust stack temperatures, over pressure alarms and timed automatic blowdown of level pots. One of the main reasons for the development of the SMART equipment and the new boiler codes was to increase reliability of boiler operation. Surveys in Germany and England showed that almost 90 percent of boiler failures was due to operator error, this has almost been eliminated through the use of new equipment based on the new codes.

  12. Metallurgical failures in fossil fired boilers

    SciTech Connect (OSTI)

    French, D.N.

    1993-01-01

    This book provides a comprehensive catalog of the types of metallurgical failures common to boilers. The author uses actual case histories of boiler shutdowns, and documents the full range of causes of boiler tube failure. A blueprint is provided for cutting maintenance costs and upgrading the efficiency and reliability of any power plant operation. Individual chapters are processed separately for inclusion in the appropriate data bases.

  13. Ganglion dynamics of Supercritical CO2 in heterogeneous media...

    Office of Scientific and Technical Information (OSTI)

    Ganglion dynamics of Supercritical CO2 in heterogeneous media. Citation Details In-Document Search Title: Ganglion dynamics of Supercritical CO2 in heterogeneous media. Abstract ...

  14. Project Profile: Physics-Based Reliability Models for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Physics-Based Reliability Models for Supercritical-CO2 Turbomachinery Components Project Profile: Physics-Based Reliability Models for Supercritical-CO2 Turbomachinery Components ...

  15. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine NREL logo -- This project is inactive -- The ...

  16. EGS rock reactions with Supercritical CO2 saturated with water...

    Office of Scientific and Technical Information (OSTI)

    Conference: EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2 Citation Details In-Document Search Title: EGS rock reactions ...

  17. Evaluation of Biodiesel Fuels from Supercritical Fluid Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced ...

  18. Volatility of Gasoline and Diesel Fuel Blends for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced ...

  19. Nano Particles - Supercritical Fluid Process - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search Nano Particles ... Applications and Industries Nano particles, supercritical fluid, photovoltaic devices, ...

  20. Project Profile: Lifetime Model Development for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    model for materials in supercritical carbon dioxide (sCO2) conditions similar to concentrated solar power (CSP) applications. ... heat transfer fluid or the power cycle working fluid. ...

  1. Supercritical plants to come online in 2009

    SciTech Connect (OSTI)

    Spring, N.

    2009-07-15

    A trio of coal-fired power plants using supercritical technology set to enter service this year. These are: We Energies is Elm Road Generating Station in Wisconsin, a two-unit, 1,230 MW supercritical plant that will burn bituminous coal; a 750 MW supercritical coal-fired power plant at the Comanche Generating Station in Pueblo, Colo., the third unit at the site; and Luminant's Oak Grove plant in Texas which will consist of two supercritical, lignite-fueled power generation units. When complete, the plant will deliver about 1,6000 MW. Some details are given on each of these projects. 2 photos.

  2. Minimize Boiler Blowdown - Steam Tip Sheet #9

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  3. Upgrade Boilers with Energy-Efficient Burners

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP steam tip sheet on upgrading boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  4. Stress-Assisted Corrosion in Boiler Tubes

    SciTech Connect (OSTI)

    Preet M Singh; Steven J Pawel

    2006-05-27

    A number of industrial boilers, including in the pulp and paper industry, needed to replace their lower furnace tubes or decommission many recovery boilers due to stress-assisted corrosion (SAC) on the waterside of boiler tubes. More than half of the power and recovery boilers that have been inspected reveal SAC damage, which portends significant energy and economic impacts. The goal of this project was to clarify the mechanism of stress-assisted corrosion (SAC) of boiler tubes for the purpose of determining key parameters in its mitigation and control. To accomplish this in-situ strain measurements on boiler tubes were made. Boiler water environment was simulated in the laboratory and effects of water chemistry on SAC initiation and growth were evaluated in terms of industrial operations. Results from this project have shown that the dissolved oxygen is single most important factor in SAC initiation on carbon steel samples. Control of dissolved oxygen can be used to mitigate SAC in industrial boilers. Results have also shown that sharp corrosion fatigue and bulbous SAC cracks have similar mechanism but the morphology is different due to availability of oxygen during boiler shutdown conditions. Results are described in the final technical report.

  5. Supercritical/Solid Catalyst (SSC)

    ScienceCinema (OSTI)

    None

    2013-05-28

    INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

  6. Recuperative supercritical carbon dioxide cycle

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

    2014-11-18

    A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

  7. Supercritical/Solid Catalyst (SSC)

    SciTech Connect (OSTI)

    2010-01-01

    INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

  8. Oil-Fired Boilers and Furnaces | Department of Energy

    Office of Environmental Management (EM)

    Oil-Fired Boilers and Furnaces Oil-Fired Boilers and Furnaces Diagram of an oil boiler. New tanks are generally double-wall or have a spill container built underneath to reduce the ...

  9. Oil-Fired Boilers and Furnaces | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oil-Fired Boilers and Furnaces Oil-Fired Boilers and Furnaces May 16, 2013 - 3:15pm Addthis Diagram of an oil boiler. New tanks are generally double-wall or have a spill container...

  10. Upgrade Boilers with Energy-Efficient Burners | Department of...

    Energy Savers [EERE]

    STEAM TIP SHEET 24 Upgrade Boilers with Energy-Efficient Burners (January 2012) (416.98 ... Improve Your Boiler's Combustion Efficiency Minimize Boiler Short Cycling Losses J.R. ...

  11. Return Condensate to the Boiler | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Return Condensate to the Boiler Return Condensate to the Boiler This tip sheet on returning condensate to boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET #8 Return Condensate to the Boiler (January 2012) (433.53 KB) More Documents & Publications Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Minimize Boiler Blowdown Consider Installing High-Pressure Boilers with Backpressure

  12. Boiler efficiency calculation for multiple fuel burning boilers

    SciTech Connect (OSTI)

    Khodabakhsh, F.; Munukutla, S.; Clary, A.T.

    1996-12-31

    A rigorous method based on the output/loss approach is developed for calculating the coal flow rate for multiple fuel burning boilers. It is assumed that the ultimate analyses of all the fuels are known. In addition, it is assumed that the flow rates of all the fuels with the exception of coal are known. The calculations are performed iteratively, with the first iteration taking into consideration coal as the only fuel. The results converge to the correct answer after a few number of iterations, typically four or five.

  13. Improve Your Boiler's Combustion Efficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improve Your Boiler's Combustion Efficiency This tip sheet outlines how to improve boiler combustion efficiency as part of an optimized steam system. STEAM TIP SHEET 4 Improve...

  14. Improve Your Boiler's Combustion Efficiency, Energy Tips: STEAM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improve Your Boiler's Combustion Efficiency Combustion Efficiency Operating your boiler with an optimum amount of excess air will minimize heat loss up the stack and improve ...

  15. Paducah Package Steam Boilers to Provide Efficiency, Environmental Benefits

    Broader source: Energy.gov [DOE]

    PADUCAH, Ky. – Five modern, modular steam boilers have replaced three larger coal-fired boilers that comprised the steam plant at EM’s Paducah Site.

  16. Clean Firetube Boiler Waterside Heat Transfer Surfaces, Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7 Clean Firetube Boiler Waterside Heat Transfer Surfaces The prevention of scale formation in fretube boilers can result in substantial energy savings. Scale deposits occur when ...

  17. Recovery of Water from Boiler Flue Gas Using Condensing Heat...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers Citation Details In-Document Search Title: Recovery of Water from Boiler Flue Gas Using ...

  18. Boiler Upgrades and Decentralizing Steam Systems Save Water and...

    Energy Savers [EERE]

    Boiler Upgrades and Decentralizing Steam Systems Save Water and Energy at Naval Air Station Oceana Boiler Upgrades and Decentralizing Steam Systems Save Water and Energy at Naval ...

  19. Paducah Package Steam Boilers to Provide Efficiency, Environmental...

    Broader source: Energy.gov (indexed) [DOE]

    PADUCAH, Ky. - Five modern, modular steam boilers have replaced three larger coal-fired boilers that comprised the steam plant at EM's Paducah Site. Moving to the more ...

  20. The solvated electron in supercritical water

    SciTech Connect (OSTI)

    Bartels, D. M.; Takahashi, K.; Cline, J.; Jonah, C. D.

    2000-03-09

    In order to investigate the feasibility for high-efficiency supercritical-water-cooled nuclear reactors, a study of radiation chemistry in supercritical water has been undertaken. Preliminary results in measurement of the optical absorption of the hydrated electron are reported, and compared with recent anion cluster data.

  1. Winning the fight against boiler tube failure

    SciTech Connect (OSTI)

    Cohen, J.; Dooley, B.

    1986-12-01

    Eliminating boiler tube failures could be worth $5 billion a year to the electric power industry. The causes and cures for the great majority of these ubiquitous failures are now known, with implications for change ranging from senior management to the maintenance crew. Methods for preventing boiler tube failure are discussed.

  2. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  3. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, C.L.; Foote, J.P.

    1995-07-04

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

  4. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, Charles L.; Foote, John P.

    1995-01-01

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

  5. Wood fuel in fluidized bed boilers

    SciTech Connect (OSTI)

    Virr, M.J.

    1982-01-01

    Development of fluidized bed fire-tube and water-tube boilers for the burning of wood, gas, and refuse-derived fuel will be reviewed. Experience gained in already installed plants will be outlined. Research experiments results on the use of various forms of wood and other biomass fuels, such as wood chips, pellets, peach pits, nut shells and kernels and refuse-derived fuels, will be described for small and medium sized fire-tube boilers, and for larger water-tube boilers for co-generation. (Refs. 4).

  6. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2015-06-09

    A system and method for reactively refining hydrocarbons, such as heavy oils with API gravities of less than 20 degrees and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure, using a selected fluid at supercritical conditions. A reaction portion of the system and method delivers lightweight, volatile hydrocarbons to an associated contacting unit which operates in mixed subcritical/supercritical or supercritical modes. Using thermal diffusion, multiphase contact, or a momentum generating pressure gradient, the contacting unit separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques.

  7. Geothermal energy production with supercritical fluids

    DOE Patents [OSTI]

    Brown, Donald W.

    2003-12-30

    There has been invented a method for producing geothermal energy using supercritical fluids for creation of the underground reservoir, production of the geothermal energy, and for heat transport. Underground reservoirs are created by pumping a supercritical fluid such as carbon dioxide into a formation to fracture the rock. Once the reservoir is formed, the same supercritical fluid is allowed to heat up and expand, then is pumped out of the reservoir to transfer the heat to a surface power generating plant or other application.

  8. Furnace and Boiler Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2:50pm Addthis Furnaces heat air and distribute the heated air through a building using ducts; boilers heat water, providing either hot water or steam for heating. Furnaces...

  9. Boiler scale prevention employing an organic chelant

    DOE Patents [OSTI]

    Wallace, Steven L.; Griffin, Jr., Freddie; Tvedt, Jr., Thorwald J.

    1984-01-01

    An improved method of treating boiler water which employs an oxygen scavenging compound and a compound to control pH together with a chelating agent, wherein the chelating agent is hydroxyethylethylenediaminetriacetic acid.

  10. Furnace and Boiler Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Boilers consist of a vessel or tank where heat produced from the combustion of such fuels as natural gas, fuel oil, or coal is used to generate hot water or steam. Many buildings ...

  11. Clean Boiler Waterside Heat Transfer Surfaces

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  12. Supercritical fluid reverse micelle separation

    DOE Patents [OSTI]

    Fulton, John L.; Smith, Richard D.

    1993-01-01

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W.sub.o that determines the maximum size of the reverse micelles. The maximum ratio W.sub.o of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions.

  13. Supercritical fluid reverse micelle separation

    DOE Patents [OSTI]

    Fulton, J.L.; Smith, R.D.

    1993-11-30

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W[sub o] that determines the maximum size of the reverse micelles. The maximum ratio W[sub o] of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions. 27 figures.

  14. 10-MW Supercritical-CO2 Turbine

    Broader source: Energy.gov [DOE]

    This fact sheet describes a 10-megawatt supercritical carbon dioxide turbine project, awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The research team, led by NREL, intends to showcase the turbomachinery for a new cycle—the supercritical carbon dioxide (s-CO2) Brayton cycle. The cycle is being optimized and tested at conditions representing dry cooling in desert environments, thereby accurately simulating real-world concentrating solar power system operating conditions.

  15. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2003-10-31

    The objective of this project is to develop an improved ultra- lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report discusses testing that was performed for analyzing the alkali-silica reactivity of ULHS in cement slurries.

  16. CX-005589: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Computational Modeling and Assessment of Nanocoatings for Ultra Supercritical BoilersCX(s) Applied: B3.6Date: 04/11/2011Location(s): Golden, ColoradoOffice(s): Fossil Energy, National Energy Technology Laboratory

  17. CX-005592: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Computational Modeling and Assessment of Nanocoatings for Ultra Supercritical BoilersCX(s) Applied: A1, A9Date: 04/11/2011Location(s): Charlotte, North CarolinaOffice(s): Fossil Energy, National Energy Technology Laboratory

  18. CX-005591: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Computational Modeling and Assessment of Nanocoatings for Ultra Supercritical BoilersCX(s) Applied: A9, B3.6Date: 04/11/2011Location(s): Livingston, New JerseyOffice(s): Fossil Energy, National Energy Technology Laboratory

  19. CX-005590: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Computational Modeling and Assessment of Nanocoatings for Ultra Supercritical BoilersCX(s) Applied: B3.6Date: 04/11/2011Location(s): San Antonio, TexasOffice(s): Fossil Energy, National Energy Technology Laboratory

  20. Boiler MACT Technical Assistance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-03-01

    Fact sheet describing the changes to Environmental Protection Act process standards. The DOE will offer technical assistance to ensure that major sources burning coal and oil have information on cost-effective, clean energy strategies for compliance, and to promote cleaner, more efficient boiler burning to cut harmful pollution and reduce operational costs. The U.S. Environmental Protection Agency (EPA) is expected to finalize the reconsideration process for its Clean Air Act pollution standards National Emissions Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers and Process Heaters (known as Boiler Maximum Achievable Control Technology (MACT)), in Spring 2012. This rule applies to large and small boilers in a wide range of industrial facilities and institutions. The U.S. Department of Energy (DOE) will offer technical assistance to ensure that major sources burning coal or oil have information on cost-effective clean energy strategies for compliance, including combined heat and power, and to promote cleaner, more efficient boilers to cut harmful pollution and reduce operational costs.

  1. Boiler house modernization through shared savings program

    SciTech Connect (OSTI)

    Breault, R.W.

    1995-12-31

    Throughout Poland as well as the rest of Eastern Europe, communities and industries rely on small heat only boilers to provide district and process heat. Together these two sectors produce about 85,000 MW from boilers in the 2 to 35 MW size range. The bulk of these units were installed prior to 1992 and must be completely overhauled to meet the emission regulations which will be coming into effect on January 1, 1998. Since the only practical fuel is coal in most cases, these boilers must be either retrofit with emission control technology or be replaced entirely. The question that arises is how to accomplish this given the current tight control of capital in Poland and other East European countries. A solution that we have for this problem is shared savings. These boilers are typically operating with a quiet low efficiency as compared to western standards and with excessive manual labor. Installing modernization equipment to improve the efficiency and to automate the process provides savings. ECOGY provides the funds for the modernization to improve the efficiency, add automation and install emission control equipment. The savings that are generated during the operation of the modernized boiler system are split between the client company and ECOGY for a number of years and then the system is turned over in entirety to the client. Depending on the operating capacity, the shared savings agreement will usually span 6 to 10 years.

  2. Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection | Department of Energy Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be used in diesel engines having efficient fuel systems and combustion chamber designs that decrease fuel consumption and mitigate emissions. p-02_anitescu.pdf (339.45 KB) More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of

  3. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2001-07-18

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). Work reported herein addresses Task 1: Assess Ultra-Lightweight Cementing Issues, Task 2: Review Russian Ultra-Lightweight Cement Literature, Task 3: Test Ultra-Lightweight Cements, and Task 8: Develop Field ULHS Cement Blending and Mixing Techniques. Results reported this quarter include: preliminary findings from a literature review focusing on problems associated with ultra-lightweight cements; summary of pertinent information from Russian ultra-lightweight cement literature review; laboratory tests comparing ULHS slurries to foamed slurries and sodium silicate slurries for two different applications; and initial laboratory studies with ULHS in preparation for a field job.

  4. Advanced Supercritical Carbon Dioxide Brayton Cycle Development

    SciTech Connect (OSTI)

    Anderson, Mark; Sienicki, James; Moisseytsev, Anton; Nellis, Gregory; Klein, Sanford

    2015-10-21

    Fluids operating in the supercritical state have promising characteristics for future high efficiency power cycles. In order to develop power cycles using supercritical fluids, it is necessary to understand the flow characteristics of fluids under both supercritical and two-phase conditions. In this study, a Computational Fluid Dynamic (CFD) methodology was developed for supercritical fluids flowing through complex geometries. A real fluid property module was implemented to provide properties for different supercritical fluids. However, in each simulation case, there is only one species of fluid. As a result, the fluid property module provides properties for either supercritical CO2 (S-CO2) or supercritical water (SCW). The Homogeneous Equilibrium Model (HEM) was employed to model the two-phase flow. HEM assumes two phases have same velocity, pressure, and temperature, making it only applicable for the dilute dispersed two-phase flow situation. Three example geometries, including orifices, labyrinth seals, and valves, were used to validate this methodology with experimental data. For the first geometry, S-CO2 and SCW flowing through orifices were simulated and compared with experimental data. The maximum difference between the mass flow rate predictions and experimental measurements is less than 5%. This is a significant improvement as previous works can only guarantee 10% error. In this research, several efforts were made to help this improvement. First, an accurate real fluid module was used to provide properties. Second, the upstream condition was determined by pressure and density, which determines supercritical states more precise than using pressure and temperature. For the second geometry, the flow through labyrinth seals was studied. After a successful validation, parametric studies were performed to study geometric effects on the leakage rate. Based on these parametric studies, an optimum design strategy for the see

  5. Energy Cost Savings Calculator for Commercial Boilers: Closed...

    Office of Environmental Management (EM)

    Water Steam What fuel is used? Gas Oil How many boilers will you purchase? unit(s) Performance Factors Existing What is the capacity of the existing boiler? MBtuhr* What is the ...

  6. Minimize Boiler Blowdown, Energy Tips: STEAM, Steam Tip Sheet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    may lead to carryover of boiler water into the steam, or the formation of deposits. ... 108,696 - 106,383 2,313 lbhr Enthalpy of Boiler Water 338.5 Btulb; for ...

  7. Project Profile: Direct Supercritical Carbon Dioxide Receiver Development |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Direct Supercritical Carbon Dioxide Receiver Development Project Profile: Direct Supercritical Carbon Dioxide Receiver Development National Renewable Energy Laboratory logo -- This project is inactive -- The National Renewable Energy Laboratory (NREL), under the National Laboratory R&D competitive funding opportunity, is working to develop, characterize, and experimentally demonstrate a novel high-temperature receiver technology using supercritical carbon dioxide

  8. Consider Installing High-Pressure Boilers with Backpressure

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Turbine-Generators | Department of Energy High-Pressure Boilers with Backpressure Turbine-Generators Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators This tip sheet outlines the benefits of high-pressure boilers with backpressure turbine-generators as part of optimized steam systems. STEAM TIP SHEET #22 Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators (January 2012) (513.44 KB) More Documents & Publications Replace

  9. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, Pascal M.

    1982-01-01

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carry-over through the turbine causes corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  10. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, P.M.

    1979-12-27

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carryover through the turbine causing corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  11. Slag monitoring for utility boilers: Final report

    SciTech Connect (OSTI)

    Anson, D.; Barrett, R.E.; Litt, R.D.; Paisley, M.A.

    1988-04-01

    This report provides a detailed description of commercially available slag monitoring techniques and some developing concepts for slag monitoring. Slag monitoring is currently being evaluated by several organizations as a means of controlling and optimizing sootblowers. The potential benefits from slag monitoring can represent significant savings in utility operating costs. Six types of heat flux meters are described as they are presently being used in utility boilers. These direct monitoring techniques determine local conditions within the furnace. Each application is described with current results and future plans. Boiler heat balance models provide an indirect technique for monitoring the general cleanliness/fouling of major boiler sections. Each model is described with current results at a representative installation. Several developing concepts of slag monitoring are described and evaluated. Four promising concepts, acoustic attenuation, a simplified heat balance model, sonic pyrometry, and ultrasonic pulse reflection, are recommended for further development and evaluation. 16 refs., 34 figs., 4 tabs.

  12. Feasibility Study of Supercritical Light Water Cooled Reactors for Electric Power Production, Progress Report for Work Through September 2003, 2nd Annual/8th Quarterly Report

    SciTech Connect (OSTI)

    Philip E. MacDonald

    2003-09-01

    The supercritical water-cooled reactor (SCWR) is one of the six reactor technologies selected for research and development under the Generation-IV program. SCWRs are promising advanced nuclear systems because of their high thermal efficiency (i.e., about 45% vs. about 33% efficiency for current Light Water Reactors, LWRs) and considerable plant simplification. SCWRs are basically LWRs operating at higher pressure and temperatures with a direct once-through cycle. Operation above the critical pressure eliminates coolant boiling, so the coolant remains single-phase throughout the system. Thus the need for recirculation and jet pumps, a pressurizer, steam generators, steam separators and dryers is eliminated. The main mission of the SCWR is generation of low-cost electricity. It is built upon two proven technologies, LWRs, which are the most commonly deployed power generating reactors in the world, and supercritical fossil-fired boilers, a large number of which is also in use around the world.

  13. Waste combustion in boilers and industrial furnaces

    SciTech Connect (OSTI)

    1997-12-31

    This set of conference papers deals with the combustion of hazardous wastes in boilers and industrial furnaces. The majority of the papers pertain specifically to cement industry kiln incinerators and focus on environmental issues. In particular, stack emission requirements currently enforced or under consideration by the U.S. EPA are emphasized. The papers were drawn from seven areas: (1) proposed Maximum Achievable Control Technology rule, (2) trial burn planning and experience, (3) management and beneficial use of materials, (4) inorganic emissions and continuous emission monitoring, (5) organic emissions, (6) boiler and industrial furnace operations, and (7) risk assessment and communication.

  14. TA-2 Water Boiler Reactor Decommissioning Project

    SciTech Connect (OSTI)

    Durbin, M.E.; Montoya, G.M.

    1991-06-01

    This final report addresses the Phase 2 decommissioning of the Water Boiler Reactor, biological shield, other components within the biological shield, and piping pits in the floor of the reactor building. External structures and underground piping associated with the gaseous effluent (stack) line from Technical Area 2 (TA-2) Water Boiler Reactor were removed in 1985--1986 as Phase 1 of reactor decommissioning. The cost of Phase 2 was approximately $623K. The decommissioning operation produced 173 m{sup 3} of low-level solid radioactive waste and 35 m{sup 3} of mixed waste. 15 refs., 25 figs., 3 tabs.

  15. Super Boiler: Packed Media/Transport Membrane Boiler Development and Demonstration

    SciTech Connect (OSTI)

    Liss, William E; Cygan, David F

    2013-04-17

    Gas Technology Institute (GTI) and Cleaver-Brooks developed a new gas-fired steam generation system the Super Boiler for increased energy efficiency, reduced equipment size, and reduced emissions. The system consists of a firetube boiler with a unique staged furnace design, a two-stage burner system with engineered internal recirculation and inter-stage cooling integral to the boiler, unique convective pass design with extended internal surfaces for enhanced heat transfer, and a novel integrated heat recovery system to extract maximum energy from the flue gas. With these combined innovations, the Super Boiler technical goals were set at 94% HHV fuel efficiency, operation on natural gas with <5 ppmv NOx (referenced to 3%O2), and 50% smaller than conventional boilers of similar steam output. To demonstrate these technical goals, the project culminated in the industrial demonstration of this new high-efficiency technology on a 300 HP boiler at Clement Pappas, a juice bottler located in Ontario, California. The Super Boiler combustion system is based on two stage combustion which combines air staging, internal flue gas recirculation, inter-stage cooling, and unique fuel-air mixing technology to achieve low emissions rather than external flue gas recirculation which is most commonly used today. The two-stage combustion provides lower emissions because of the integrated design of the boiler and combustion system which permit precise control of peak flame temperatures in both primary and secondary stages of combustion. To reduce equipment size, the Super Boiler's dual furnace design increases radiant heat transfer to the furnace walls, allowing shorter overall furnace length, and also employs convective tubes with extended surfaces that increase heat transfer by up to 18-fold compared to conventional bare tubes. In this way, a two-pass boiler can achieve the same efficiency as a traditional three or four-pass firetube boiler design. The Super Boiler is consequently up to

  16. Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Fox, Robert V.; Kong, Peter C.

    2000-01-01

    This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

  17. Ultra Violet Waterworks (UVW)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ultra Violet Waterworks Water Disinfecting Device Saves Lives Resources with Additional Information Ultra Violet Waterworks (UVW) device Ultra Violet Waterworks (UVW) is a small-scale, energy-efficient, and low-maintenance mechanism that uses ultraviolet light to cheaply disinfect water. It is a uniquely effective device that operates using the equivalent of a 60-Watt light bulb at a cost of as low as 4 cents/ton of water treated, treating 15 liters/minute, and providing enough drinking water

  18. Evaluation of coal-derived liquids as boiler fuels. Volume 2: boiler test results. Final report

    SciTech Connect (OSTI)

    Not Available

    1985-09-01

    A combustion demonstration using six coal-derived liquid (CDL) fuels was conducted on a utility boiler located at the Plant Sweatt Electric Generating Station of Mississippi Power Company in Meridian, Mississippi. The test program was conducted in two phases. The first phase included the combustion tests of the two conventional fuels (natural gas and No. 6 fuel oil) and three coal-derived liquid fuels (Solvent Refined Coal-II full range distillate, H-Coal heavy distillate and H-Coal blended distillate). The second phase involved the evaluation of three additional CDL fuels (H-Coal light distillate, Exxon Donor Solvent full range distillate and Solvent Refined Coal-II middle distillate). The test boiler was a front wall-fired Babcock and Wilcox unit with a rated steam flow of 425,000 lb/h and a generating capacity of 40 MW. Boiler performance and emissions were evaluated with baseline and CDL fuels at 15, 25, 40 MW loads and at various excess air levels. Low NO/sub x/ (staged) combustion techniques were also implemented. Boiler performance monitoring included measurements for fuel steam and flue gas flow, pressure, temperature, and heat absorption, resulting in a calculated combustion efficiency, boiler efficiency, and heat rate. Emissions measurements included oxygen, carbon dioxide, carbon monoxide, oxides of nitrogen, sulfur dioxide, sulfur trioxide, acid dewpoint, particulate mass, size distribution and morphology, chlorides, and opacity. The test program demonstrated the general suitability of CDL fuels for use in existing oil-fired utility boilers. No significant boiler tube surface modifications will be required. The CDL fuels could be handled similarly to No. 2 oil with appropriate safety procedures and materials compatibility considerations. Volume 2 of a five-volume report contains the detailed boiler test results. 96 figs., 26 tabs.

  19. Purchasing Energy-Efficient Commercial Boilers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance and Federal efficiency requirements for commercial boilers, which is a FEMP-designated product category. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

  20. Best Management Practice #8: Steam Boiler Systems

    Office of Energy Efficiency and Renewable Energy (EERE)

    Boilers and steam generators are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size, the amount of steam used, and the amount of condensate returned.

  1. The next generation of oxy-fuel boiler systems

    SciTech Connect (OSTI)

    Ochs, Thomas L.; Gross, Alex; Patrick, Brian; Oryshchyn, Danylo B.; Summers, Cathy A.; Turner, Paul C.

    2005-01-01

    Research in the area of oxy-fuel combustion which is being pioneered by Jupiter Oxygen Corporation combined with boiler research conducted by the USDOE/Albany Research Center has been applied to designing the next generation of oxy-fuel combustion systems. The new systems will enhance control of boiler systems during turn-down and improve response time while improving boiler efficiency. These next generation boiler systems produce a combustion product that has been shown to be well suited for integrated pollutant removal. These systems have the promise of reducing boiler foot-print and boiler construction costs. The modularity of the system opens the possibility of using this design for replacement of boilers for retrofit on existing systems.

  2. Chemical deposition methods using supercritical fluid solutions

    DOE Patents [OSTI]

    Sievers, Robert E.; Hansen, Brian N.

    1990-01-01

    A method for depositing a film of a desired material on a substrate comprises dissolving at least one reagent in a supercritical fluid comprising at least one solvent. Either the reagent is capable of reacting with or is a precursor of a compound capable of reacting with the solvent to form the desired product, or at least one additional reagent is included in the supercritical solution and is capable of reacting with or is a precursor of a compound capable of reacting with the first reagent or with a compound derived from the first reagent to form the desired material. The supercritical solution is expanded to produce a vapor or aerosol and a chemical reaction is induced in the vapor or aerosol so that a film of the desired material resulting from the chemical reaction is deposited on the substrate surface. In an alternate embodiment, the supercritical solution containing at least one reagent is expanded to produce a vapor or aerosol which is then mixed with a gas containing at least one additional reagent. A chemical reaction is induced in the resulting mixture so that a film of the desired material is deposited.

  3. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2004-01-30

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report discusses testing that was performed for analyzing the alkali-silica reactivity of ULHS in cement slurries.

  4. Guide to Low-Emission Boiler and Combustion Equipment Selection

    SciTech Connect (OSTI)

    Oland, CB

    2002-05-06

    Boiler owners and operators who need additional generating capacity face a number of legal, political, environmental, economic, and technical challenges. Their key to success requires selection of an adequately sized low-emission boiler and combustion equipment that can be operated in compliance with emission standards established by state and federal regulatory agencies. Recognizing that many issues are involved in making informed selection decisions, the U.S. Department of Energy (DOE), Office of Industrial Technologies (OIT) sponsored efforts at the Oak Ridge National Laboratory (ORNL) to develop a guide for use in choosing low-emission boilers and combustion equipment. To ensure that the guide covers a broad range of technical and regulatory issues of particular interest to the commercial boiler industry, the guide was developed in cooperation with the American Boiler Manufacturers Association (ABMA), the Council of Industrial Boiler Owners (CIBO), and the U.S. Environmental Protection Agency (EPA). The guide presents topics pertaining to industrial, commercial, and institutional (ICI) boilers. Background information about various types of commercially available boilers is provided along with discussions about the fuels that they burn and the emissions that they produce. Also included are discussions about emissions standards and compliance issues, technical details related to emissions control techniques, and other important selection considerations. Although information in the guide is primarily applicable to new ICI boilers, it may also apply to existing boiler installations.

  5. Coal-fired boiler for petroleum refinery

    SciTech Connect (OSTI)

    Ketterman, W.R.; Heinzmann, D.A.

    1982-01-01

    There has been a significant amount of interest in conversion from oil/gas fired boilers to coal-fired equipment since the Arab oil embargo of 1973. The CRA Incorporated Coffeyville Refinery decided in 1977 to proceed with the installation of a 86.183 Kg/h coal fired boiler to generate process steam at 650 psig (4,482 k Pa) 596/sup 0/F (313/sup 0/C). A significant portion of this steam is passed through steam turbines to obtain mechanical power. Building and operating a coal-fired steam plant is a ''Different Kettle of Fish'' from building and operating an oil/gas-fired steam plant. The intention of this paper is to deal with some of the ''Why's and Wherefores'' of the conversion to coal-fired equipment.

  6. U.S., Saudi Arabia Announce International Collaboration on Supercritical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Tech Development | Department of Energy , Saudi Arabia Announce International Collaboration on Supercritical CO2 Tech Development U.S., Saudi Arabia Announce International Collaboration on Supercritical CO2 Tech Development June 3, 2016 - 1:00pm Addthis The U. S. and the Kingdom of Saudi Arabia have announced the intention to establish an international consortium to promote the research, development, and demonstration (RD&D) of supercritical carbon dioxide (sCO2) power cycles. The

  7. Supercritical CO2 Power Cycles: Design Considerations for Concentrating

    Office of Scientific and Technical Information (OSTI)

    Solar Power (Conference) | SciTech Connect Supercritical CO2 Power Cycles: Design Considerations for Concentrating Solar Power Citation Details In-Document Search Title: Supercritical CO2 Power Cycles: Design Considerations for Concentrating Solar Power A comparison of three supercritical CO2 Brayton cycles: the simple cycle, recompression cycle and partial-cooling cycle indicates the partial-cooling cycle is favored for use in concentrating solar power (CSP) systems. Although it displays

  8. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine NREL logo -- This project is inactive -- The National Renewable Energy Laboratory (NREL) and its partners, under the 2012 SunShot Concentrating Solar Power (CSP) R&D funding opportunity announcement (FOA), aim to demonstrate a multi-megawatt power cycle using supercritical carbon dioxide (s-CO2) as the working fluid. The use of carbon

  9. Project Profile: High-Efficiency Receivers for Supercritical Carbon Dioxide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cycles | Department of Energy Receivers for Supercritical Carbon Dioxide Cycles Project Profile: High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles Brayton logo --This project is inactive -- Brayton Energy, under the 2012 SunShot Concentrating Solar Power (CSP) R&D FOA, is building and testing a new solar receiver that uses supercritical carbon dioxide (s-CO2) as the heat-transfer fluid. The research team is designing the receiver to withstand higher operating temperatures

  10. Project Profile: Supercritical Carbon Dioxide Turbo-Expander and Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exchangers | Department of Energy Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Project Profile: Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers SWRI Logo The Southwest Research Institute (SWRI) and its partners, under the 2012 Concentrating Solar Power (CSP) SunShot R&D funding opportunity announcement (FOA), are developing a supercritical carbon dioxide (s-CO2) power cycle that combines high efficiencies and low costs for modular CSP applications.

  11. DOE Selects Project to Help Advance More Efficient Supercritical Carbon

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dioxide-Based Power Cycles | Department of Energy Project to Help Advance More Efficient Supercritical Carbon Dioxide-Based Power Cycles DOE Selects Project to Help Advance More Efficient Supercritical Carbon Dioxide-Based Power Cycles August 3, 2015 - 10:25am Addthis The U.S. Department of Energy's National Energy Technology Laboratory (NETL) has selected Thar Energy, LLC to develop new recuperator technologies leading to more cost-effective and efficient supercritical carbon dioxide

  12. Solid Catalyzed Isoparaffin Alkylation at Supercritical Fluid and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Near-Supercritical Fluid Conditions - Energy Innovation Portal Startup America Startup America Find More Like This Return to Search Solid Catalyzed Isoparaffin Alkylation at Supercritical Fluid and Near-Supercritical Fluid Conditions Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL has developed a solid catalyst process for the alkylation reaction of isoparaffins with olefins over solid catalysts. The process includes contacting a mixture of an

  13. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock

  14. Particulate emission abatement for Krakow boiler houses

    SciTech Connect (OSTI)

    Wysk, R.

    1995-12-31

    Among the many strategies for improving air quality in Krakow, one possible method is to adapt new and improved emission control technology. This project focuses on such a strategy. In order to reduce dust emissions from coal-fueled boilers, a new device called a Core Separator has been introduced in several boiler house applications. This advanced technology has been successfully demonstrated in Poland and several commercial units are now in operation. Particulate emissions from the Core Separator are typically 3 to 5 times lower than those from the best cyclone collectors. It can easily meet the new standard for dust emissions which will be in effect in Poland after 1997. The Core Separator is a completely inertial collector and is based on a unique recirculation method. It can effectively remove dust particles below 10 microns in diameter, the so-called PM-10 emissions. Its performance approaches that of fabric filters, but without the attendant cost and maintenance. It is well-suited to the industrial size boilers located in Krakow. Core Separators are now being marketed and sold by EcoInstal, one of the leading environmental firms in Poland, through a cooperative agreement with LSR Technologies.

  15. Field Test of Boiler Primary Loop Temperature Controller

    SciTech Connect (OSTI)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and, in some cases, return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential.

  16. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  17. Supercritical separation process for complex organic mixtures

    DOE Patents [OSTI]

    Chum, Helena L.; Filardo, Giuseppe

    1990-01-01

    A process is disclosed for separating low molecular weight components from complex aqueous organic mixtures. The process includes preparing a separation solution of supercritical carbon dioxide with an effective amount of an entrainer to modify the solvation power of the supercritical carbon dioxide and extract preselected low molecular weight components. The separation solution is maintained at a temperature of at least about 70.degree. C. and a pressure of at least about 1,500 psi. The separation solution is then contacted with the organic mixtures while maintaining the temperature and pressure as above until the mixtures and solution reach equilibrium to extract the preselected low molecular weight components from the organic mixtures. Finally, the entrainer/extracted components portion of the equilibrium mixture is isolated from the separation solution.

  18. Supercritical separation process for complex organic mixtures

    DOE Patents [OSTI]

    Chum, H.L.; Filardo, G.

    1990-10-23

    A process is disclosed for separating low molecular weight components from complex aqueous organic mixtures. The process includes preparing a separation solution of supercritical carbon dioxide with an effective amount of an entrainer to modify the solvation power of the supercritical carbon dioxide and extract preselected low molecular weight components. The separation solution is maintained at a temperature of at least about 70 C and a pressure of at least about 1,500 psi. The separation solution is then contacted with the organic mixtures while maintaining the temperature and pressure as above until the mixtures and solution reach equilibrium to extract the preselected low molecular weight components from the organic mixtures. Finally, the entrainer/extracted components portion of the equilibrium mixture is isolated from the separation solution. 1 fig.

  19. SUPERCRITICAL STEAM CYCLE FOR NUCLEAR POWER PLANT

    SciTech Connect (OSTI)

    Tsiklauri, Georgi V.; Talbert, Robert J.; Schmitt, Bruce E.; Filippov, Gennady A.; Bogojavlensky, Roald G.; Grishanin, Evgeny I.

    2005-07-01

    Revolutionary improvement of the nuclear plant safety and economy with light water reactors can be reached with the application of micro-fuel elements (MFE) directly cooled by a supercritical pressure light-water coolant-moderator. There are considerable advantages of the MFE as compared with the traditional fuel rods, such as: Using supercritical and superheated steam considerably increases the thermal efficiency of the Rankine cycle up to 44-45%. Strong negative coolant and void reactivity coefficients with a very short thermal delay time allow the reactor to shutdown quickly in the event of a reactivity or power excursion. Core melting and the creation of corium during severe accidents are impossible. The heat transfer surface area is larger by several orders of magnitude due to the small spherical dimensions of the MFE. The larger heat exchange surface significantly simplifies residual heat removal by natural convection and radiation from the core to a subsequent passive system of heat removal.

  20. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Brayton Energy's supercritical carbon dioxide (s-CO 2 ) solar receiver has the potential to significantly improve reliability, increase efficiency, and reduce costs of CSP systems. ...

  1. Startup Design Features for Supercritical Power Conversion Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Startup Design Features for Supercritical Power ... DescriptionThe new design features and procedures will improve the already advanced ...

  2. Test Plan for Heat Cycle Research Program, Phase I Supercritical...

    Office of Scientific and Technical Information (OSTI)

    Test Plan for Heat Cycle Research Program, Phase I Supercritical Cycle Tests Citation Details In-Document Search Title: Test Plan for Heat Cycle Research Program, Phase I ...

  3. Candidate Materials Evaluation for Supercritical Water-Cooled Reactor

    SciTech Connect (OSTI)

    T. R. Allen and G. S. Was

    2008-12-12

    Final technical report on the corrosion, stress corrosion cracking, and radiation response of candidate materials for the supercritical water-cooled reactor concept.

  4. Using supercritical carbon dioxide as a fracturing fluid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compare different working models of hydraulic fracturing for shale gas and oil production. ... and drawbacks of using supercritical CO2 as a working fluid for shale gas production. ...

  5. DOE Selects Project to Help Advance More Efficient Supercritical...

    Office of Environmental Management (EM)

    higher thermal efficiencies when compared to state of the art steam-based power cycles. ... Developing Components for Advanced Turbine and Supercritical CO2-Based Power Cycles ...

  6. U.S., Saudi Arabia Announce International Collaboration on Supercritic...

    Office of Environmental Management (EM)

    costs and overall reduction in electricity cost compared to steam-based power cycles. ... Developing Components for Advanced Turbine and Supercritical CO2-Based Power Cycles

  7. 10 MW Supercritical CO2 Turbine Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 MW Supercritical CO2 Turbine Project 10 MW Supercritical CO2 Turbine Project This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. csp_review_meeting_042313_turchi.pdf (1.86 MB) More Documents & Publications 10-Megawatt Supercritical Carbon Dioxide Turbine - FY13 Q2 10-MW Supercritical-CO2 Turbine Degradation Mechanisms and Development of Protective Coatings for TES and HTF Containment Materials

  8. Project Profile: Supercritical Carbon Dioxide Turbo-Expander...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Project Profile: ... Concentrating Solar Power (CSP) SunShot R&D funding opportunity announcement (FOA), are ...

  9. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon...

    Open Energy Info (EERE)

    Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title...

  10. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    cycle offers higher cycle efficiency when compared with supercritical or superheated steam cycles at temperatures relevant for concentrating solar power (CSP) applications....

  11. Purchasing Energy-Efficient Commercial Boilers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Boilers Purchasing Energy-Efficient Commercial Boilers The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial boilers, a product category covered by FEMP-designated efficiency requirements. Federal laws and requirements mandate that agencies purchase ENERGY STAR-qualified or FEMP-designated products in all product categories covered by these programs and in any acquisition actions that are not specifically exempted by law. FEMP's acquisition guidance and

  12. Coiled tubing drilling with supercritical carbon dioxide

    DOE Patents [OSTI]

    Kolle , Jack J.

    2002-01-01

    A method for increasing the efficiency of drilling operations by using a drilling fluid material that exists as supercritical fluid or a dense gas at temperature and pressure conditions existing at a drill site. The material can be used to reduce mechanical drilling forces, to remove cuttings, or to jet erode a substrate. In one embodiment, carbon dioxide (CO.sub.2) is used as the material for drilling within wells in the earth, where the normal temperature and pressure conditions cause CO.sub.2 to exist as a supercritical fluid. Supercritical carbon dioxide (SC--CO.sub.2) is preferably used with coiled tube (CT) drilling equipment. The very low viscosity SC--CO.sub.2 provides efficient cooling of the drill head, and efficient cuttings removal. Further, the diffusivity of SC--CO.sub.2 within the pores of petroleum formations is significantly higher than that of water, making jet erosion using SC--CO.sub.2 much more effective than water jet erosion. SC--CO.sub.2 jets can be used to assist mechanical drilling, for erosion drilling, or for scale removal. A choke manifold at the well head or mud cap drilling equipment can be used to control the pressure within the borehole, to ensure that the temperature and pressure conditions necessary for CO.sub.2 to exist as either a supercritical fluid or a dense gas occur at the drill site. Spent CO.sub.2 can be vented to the atmosphere, collected for reuse, or directed into the formation to aid in the recovery of petroleum.

  13. Oxy-Combustion Boiler Material Development (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to ... Test coupons of boiler tube materials were coated with deposits representative of those ...

  14. EECBG Success Story: New Boilers, Big Savings for Minnesota County

    Broader source: Energy.gov [DOE]

    Officials at Sherburne County's Government Center in Minnesota had a problem: the complex's original boilers, installed in 1972, were in desperate need of replacing. Learn more.

  15. Biomass Boiler and Furnace Emissions and Safety Regulations in...

    Open Energy Info (EERE)

    in the Northeast States Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Biomass Boiler and Furnace Emissions and Safety Regulations in the Northeast States Agency...

  16. Gas-Fired Boilers and Furnaces | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    natural gas meter. Gas boilers and furnaces can be fueled by either natural gas or propane with simple modifications accounting for the different characteristics of the fuels....

  17. Consider Installing High-Pressure Boilers with BackpressureTurbine...

    Broader source: Energy.gov (indexed) [DOE]

    with backpressure turbine-generators as part of optimized steam systems. STEAM TIP SHEET 22 Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators (January ...

  18. Recover Heat from Boiler Blowdown | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Recover Heat from Boiler Blowdown (January 2012) More Documents & Publications Install an Automatic Blowdown-Control System Flash High-Pressure Condensate to Regenerate ...

  19. Clean Boiler Waterside Heat Transfer Surfaces | Department of...

    Energy Savers [EERE]

    STEAM TIP SHEET 7 Clean Boiler Waterside Heat Transfer Surfaces (April 2012) (395.4 KB) More Documents & Publications Consider Installing Turbulators on Two- and Three-Pass ...

  20. Building America Case Study: Advanced Boiler Load Monitoring...

    Energy Savers [EERE]

    Boiler Load Monitoring Controllers Chicago, Illinois PROJECT INFORMATION Project Name: ... Most of Chicago's older multifamily housing stock is heated by centrally metered steam or ...

  1. Recover Heat from Boiler Blowdown | Department of Energy

    Energy Savers [EERE]

    STEAM TIP SHEET 10 Recover Heat from Boiler Blowdown (January 2012) (372.21 KB) More Documents & Publications Install an Automatic Blowdown-Control System Consider Installing a ...

  2. Field Test of Boiler Primary Loop Temperature Controller

    SciTech Connect (OSTI)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and in some cases return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential. PARR installed and monitored the performance of one type of ALM controller, the M2G from Greffen Systems, at multifamily sites in the city of Chicago and its suburb Cary, IL, both with existing OTR control. Results show that energy savings depend on the degree to which boilers are over-sized for their load, represented by cycling rates. Also savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, over-sized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less over-sized boilers at another site showed muted savings.

  3. Return Condensate to the Boiler - Steam Tip Sheet #8

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on returning condensate to boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  4. Property:Building/SPPurchasedEngyPerAreaKwhM2Oil-FiredBoiler...

    Open Energy Info (EERE)

    Oil-FiredBoiler Jump to: navigation, search This is a property of type String. Oil-fired boiler Pages using the property "BuildingSPPurchasedEngyPerAreaKwhM2Oil-FiredBoiler"...

  5. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2003-01-31

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report discusses testing that was performed for analyzing the alkali-silica reactivity of ULHS in cement slurries. DOE joined the Materials Management Service (MMS)-sponsored joint industry project ''Long-Term Integrity of Deepwater Cement under Stress/Compaction Conditions.'' Results of the project contained in two progress reports are also presented in this report.

  6. Advanced Thermal Storage for Central Receivers with Supercritical Coolants

    SciTech Connect (OSTI)

    Kelly, Bruce D.

    2010-06-15

    The principal objective of the study is to determine if supercritical heat transport fluids in a central receiver power plant, in combination with ceramic thermocline storage systems, offer a reduction in levelized energy cost over a baseline nitrate salt concept. The baseline concept uses a nitrate salt receiver, two-tank (hot and cold) nitrate salt thermal storage, and a subcritical Rankine cycle. A total of 6 plant designs were analyzed, as follows: Plant Designation Receiver Fluid Thermal Storage Rankine Cycle Subcritical nitrate salt Nitrate salt Two tank nitrate salt Subcritical Supercritical nitrate salt Nitrate salt Two tank nitrate salt Supercritical Low temperature H2O Supercritical H2O Two tank nitrate salt Supercritical High temperature H2O Supercritical H2O Packed bed thermocline Supercritical Low temperature CO2 Supercritical CO2 Two tank nitrate salt Supercritical High temperature CO2 Supercritical CO2 Packed bed thermocline Supercritical Several conclusions have been drawn from the results of the study, as follows: 1) The use of supercritical H2O as the heat transport fluid in a packed bed thermocline is likely not a practical approach. The specific heat of the fluid is a strong function of the temperatures at values near 400 °C, and the temperature profile in the bed during a charging cycle is markedly different than the profile during a discharging cycle. 2) The use of supercritical CO2 as the heat transport fluid in a packed bed thermocline is judged to be technically feasible. Nonetheless, the high operating pressures for the supercritical fluid require the use of pressure vessels to contain the storage inventory. The unit cost of the two-tank nitrate salt system is approximately $24/kWht, while the unit cost of the high pressure thermocline system is nominally 10 times as high. 3) For the supercritical fluids, the outer crown temperatures of the receiver tubes are in the range of 700 to 800 °C. At temperatures of 700 °C and above

  7. Ultra High Temperature | Open Energy Information

    Open Energy Info (EERE)

    Ultra High Temperature Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Sanyal Temperature Classification: Ultra High Temperature Dictionary.png Ultra High...

  8. Green wood chip gasification due under boiler

    SciTech Connect (OSTI)

    Not Available

    1981-12-14

    It is reported that Applied Engineering Co. has begun installing the first greenwood chip gasification system to be used in conjunction with fossil fuels at Florida Power Corp's Suwannee generating station near Lake City, Florida. The unit's design capacity is about 37 MMBTU/hour and will provide as much as 25% of the fuel requirements of a large utility type natural gas boiler under normal load conditions. The system is expected to back out as much as 1 million gal/year of fuel oil at a savings of approximately $850,000/year.

  9. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2001-01-15

    The objective of this project is to develop an improved ultra-lightweigh cement using ultralight hollow glass spheres (ULHS). Work reported herein addresses Task 1: Assess Ultra-Lightweight Cementing Problems, Task 2: Review Russian Ultra-Lightweight Cement Literature, and Task 3: Test Ultra-Lightweight Cements. Results reported this quarter include a review and summary surface pipe and intermediate casing cementing conditions historically encountered in the US and establishment of average design conditions for ULHS cements. Russian literature concerning development and use of ultra-lightweight cements employing either nitrogen or ULHS was reviewed, and a summary is presented. Quality control testing of materials used to formulate ULHS cements in the laboratory was conducted to establish baseline material performance standards. A testing protocol was developed employing standard procedures as well as procedures tailored to evaluate ULHS. This protocol is presented and discussed. finally, results of initial testing of ULHS cements is presented along with analysis to establish cement performance design criteria to be used during the remainder of the project.

  10. Utilizing Supplemental Ultra-Low-NO

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... ULN burner technology into a Capstone C65 (65 kW) microturbine and a 100 HP heat recovery boiler by Johnston Boiler Company. Barriers The project seeks to overcome the following ...

  11. Supercritical Water Oxidation Data Acquisition Testing

    SciTech Connect (OSTI)

    K. M. Garcia

    1996-08-01

    Supercritical Water Oxidation (SCWO) is a high pressure oxidation process that blends air, water, and organic waste material in an oxidizer in which where the temperature and pressure in the oxidizer are maintained above the critical point of water. Supercritical water mixed with hydrocarbons, which would be insoluble at subcritical conditions, forms a homogeneous phase which possesses properties associated with both a gas and a liquid. Hydrocarbons in contact with oxygen and SCW are readily oxidized. These properties of SCW make it an attractive means for the destruction of waste streams containing organic materials. SCWO technology holds great promise for treating mixed wastes in an environmentally safe and efficient manner. In the spring of 1994 the U.S. Department of Energy (DOE) initiated a Supercritical Water Oxidation Data Acquisition Testing (SCWODAT) program. The SCWODAT program provided further information and operational data on the effectiveness of treating both simulated mixed waste and typical Navy hazardous waste using the SCWO technology. The program concentrated on the acquisition of data through pilot plant testing. The Phase I DOE testing used a simulated waste stream that contained a complex machine cutting oil and metals, that acted as surrogates for radionuclides. The Phase II Navy testing included pilot testing using hazardous waste materials to demonstrate the effectiveness of the SCWO technology. The SCWODAT program demonstrated that the SCWO process oxidized the simulated waste stream containing complex machine cutting oil, selected by DOE as representative of one of the most difficult of the organic waste streams for which SCWO had been applied. The simulated waste stream with surrogate metals in solution was oxidized, with a high destruction efficiency, on the order of 99.97%, in both the neutralized and unneutralized modes of operation.

  12. Supercritical fluids: Reactions, materials and applications

    SciTech Connect (OSTI)

    Tumas, W.; Jacobson, G.B.; Josephsohn, N.S.; Brown, G.H.

    1999-04-09

    A number of important processes utilizing supercritical fluids have been either implemented or are emerging for extractions, separations and a wide range of cleaning applications. Supercritical fluids can be reasonable solvents yet share many of the advantages of gases including miscibility with other gases (i.e. hydrogen and oxygen), low viscosities and high diffusivities. Carbon dioxide has the further advantages of being nontoxic, nonflammable, inexpensive and currently unregulated. The use of compressed gases, either as liquids or supercritical fluids, as reaction media offers the opportunity to replace conventional hazardous solvents and also to optimize and potentially control the effect of solvent on chemical and material processing. The last several years has seen a significant growth in advances in chemical synthesis, catalytic transformations and materials synthesis and processing. The authors report on results from an exploratory program at Los Alamos National Laboratory aimed at investigating the use of dense phase fluids, particularly carbon dioxide, as reaction media for homogeneous, heterogeneous and phase-separable catalytic reactions in an effort to develop new, environmentally-friendly methods for chemical synthesis and processing. This approach offers the possibility of opening up substantially different chemical pathways, increasing selectivity at higher reaction rates, facilitating downstream separations and mitigating the need for hazardous solvents. Developing and understanding chemical and catalytic transformations in carbon dioxide could lead to greener chemistry at three levels: (1) Solvent replacement; (2) Better chemistry (e.g. higher reactivity, selectivity, less energy consumption); and (3) New chemistry (e.g. novel separations, use of COP{sub 2} as a C-1 source).

  13. Establishing an energy efficiency recommendation for commercial boilers

    SciTech Connect (OSTI)

    Ware, Michelle J.

    2000-08-01

    To assist the federal government in meeting its energy reduction goals, President Clinton's Executive Order 12902 established the Procurement Challenge, which directed all federal agencies to purchase equipment within the top 25th percentile of efficiency. Under the direction of DOE's Federal Energy Management Program (FEMP), the Procurement Challenge's goal is to create efficiency recommendations for all energy-using products that could substantially impact the government's energy reduction goals, like commercial boilers. A typical 5,000,000 Btuh boiler, with a thermal efficiency of 83.2%, can have lifetime energy cost savings of $40,000 when compared to a boiler with a thermal efficiency of 78%. For the federal market, which makes up 2% of the boiler market, this means lifetime energy cost savings of over $25,600,000. To establish efficiency recommendations, FEMP uses standardized performance ratings for products sold in the marketplace. Currently, the boiler industry uses combustion efficiency and, sometimes, thermal efficiency performance measures when specifying a commercial boiler. For many years, the industry has used these efficiency measures interchangeably, causing confusion about boiler performance measurements, and making it difficult for FEMP to establish the top 25th percentile of efficiency. This paper will illustrate the method used to establish FEMP's recommendation for boilers. The method involved defining a correlation between thermal and combustion efficiency among boiler classifications; using the correlation to model a data set of all the boiler types available in the market; and identifying how the correlation affected the top 25th percentile analysis. The paper also will discuss the applicability of this method for evaluating other equipment for which there are limited data on performance ratings.

  14. Gas reburn retrofit on an industrial cyclone boiler

    SciTech Connect (OSTI)

    Farzan, H.; Latham, C.E.; Maringo, G.J.

    1996-01-01

    Eastman Kodak Company`s cyclone boiler (Unit No. 43), located in Rochester, New York, is being retrofitted with the gas reburning technology developed by Babcock & Wilcox (B & W) to reduce NO{sub x} emissions in order to comply with the Title I, ozone nonattainment, of the Clean Air Act Amendments (CAAA) of 1990. The required NO{sub x} reduction from baseline levels necessary to meet the presumptive limit set in New York`s regulation is about 47%. Eastman Kodak and the Gas Research Institute (GRI) are cosponsoring this project. B & W is the prime contractor and contract negotiations with Chevron as the gas supplier are presently being finalized. Equipment installation for the gas reburn system is scheduled for a September 1995 outage. No. 43 Boiler`s maximum continuous rating (MCR) is 550,000 pounds per hour of steam flow or approximately equivalent to 60 MW{sub e}. Because of the compact boiler design, there is insufficient gas residence time to use pulverized coal or oil as the reburn fuel, thus making it a prime candidate for gas reburn. Kodak currently has four cyclone boilers. Based on successful completion of this gas reburn project, modifying the other three cyclone boilers with gas reburn technology is anticipated. The paper will describe B & W`s gas reburn data from a cyclone-equipped pilot facility (B & W`s Small Boiler Simulator), gas reburn design information specific to Eastman Kodak No. 43 Boiler, and numerical modeling experiences based on the pilot-scale Small Boiler Simulator (SBS) results along with those from a full-scale commercial boiler.

  15. Supercritical water oxidation of ammonium picrate

    SciTech Connect (OSTI)

    LaJeunesse, C.A.; Mills, B.E.; Brown, B.G.

    1994-11-01

    This study demonstrates the feasibility of using supercritical water oxidation to destroy ammonium picrate. Analyses of reactor effluent composition at various temperatures, residence times, and oxidant concentrations were used to design an improved reactor configuration for achieving destruction with minimum corrosion. The engineering evaluation reactor, a room-sized laboratory scale reactor, was reconfigured to incorporate this design change. Destruction of ammonium picrate with minimized corrosion was demonstrated on this reconfigured reactor. Factors that must be considered in scaling up to pilot plant size are discussed.

  16. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2002-07-30

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report includes results from laboratory testing of ULHS systems along with other lightweight cement systems, including foamed and sodium silicate slurries. During this project quarter, a comparison study of the three cement systems examined the effect that cement drillout has on the three cement systems. Testing to determine the effect of pressure cycling on the shear bond properties of the cement systems was also conducted. This report discusses testing that was performed to analyze the alkali-silica reactivity of ULHS in cement slurries.

  17. Optimized, Competitive Supercritical-CO2 Cycle GFR for Gen IV Service

    SciTech Connect (OSTI)

    M.J. Driscoll; P. Hejzlar; G. Apostolakis

    2008-09-08

    An overall plant design was developed for a gas-cooled fast reactor employing a direct supercritical Brayton power conversion system. The most important findings were that (1) the concept could be capital-cost competitive, but startup fuel cycle costs are penalized by the low core power density, specified in large part to satisfy the goal of significatn post-accident passive natural convection cooling; (2) active decay heat removal is preferable as the first line of defense, with passive performance in a backup role; (3) an innovative tube-in-duct fuel assembly, vented to the primpary coolant, appears to be practicable; and (4) use of the S-Co2 GFR to support hydrogen production is a synergistic application, since sufficient energy can be recuperated from the product H2 and 02 to allow the electrolysis cell to run 250 C hotter than the reactor coolant, and the water boilers can be used for reactor decay heat removal. Increasing core poer density is identified as the top priority for future work on GFRs of this type.

  18. Energy Conservation Program for Consumer Products: Test Procedures for Furnaces and Boilers, Comment Period Extension

    Broader source: Energy.gov [DOE]

    Energy Conservation Program for Consumer Products: Test Procedures for Furnaces and Boilers, Comment Period Extension

  19. Energy Conservation Program: Energy Conservation Standards for Residential Boilers, Notice of Proposed Rulemaking

    Office of Energy Efficiency and Renewable Energy (EERE)

    Energy Conservation Program: Energy Conservation Standards for Residential Boilers, Notice of Proposed Rulemaking

  20. Boiler Maximum Achievable Control Technology (MACT) Technical Assistance- Fact Sheet, April 2015

    Broader source: Energy.gov [DOE]

    Fact sheet about the Boiler Maximum Achievable Control Technology (MACT) Technical Assistance Program

  1. 2015-12-29 Consumer Furnaces and Boilers Test Procedures Final Rule

    Broader source: Energy.gov [DOE]

    Energy Conservation Program for Consumer Products: Test Procedures for Consumer Furnaces and Boilers

  2. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2001-10-23

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). Work reported herein addresses tasks performed in the fourth quarter as well as the other three quarters of the past year. The subjects that were covered in previous reports and that are also discussed in this report include: Analysis of field laboratory data of active cement applications from three oil-well service companies; Preliminary findings from a literature review focusing on problems associated with ultra-lightweight cements; Summary of pertinent information from Russian ultra-lightweight cement literature review; and Comparison of compressive strengths of ULHS systems using ultrasonic and crush methods Results reported from the fourth quarter include laboratory testing of ULHS systems along with other lightweight cement systems--foamed and sodium silicate slurries. These comparison studies were completed for two different densities (10.0 and 11.5 lb/gal) and three different field application scenarios. Additional testing included the mechanical properties of ULHS systems and other lightweight systems. Studies were also performed to examine the effect that circulation by centrifugal pump during mixing has on breakage of ULHS.

  3. Project Profile: Lifetime Model Development for Supercritical CO2 CSP

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems (SuNLaMP) | Department of Energy Project Profile: Lifetime Model Development for Supercritical CO2 CSP Systems (SuNLaMP) Project Profile: Lifetime Model Development for Supercritical CO2 CSP Systems (SuNLaMP) Funding Program: SuNLaMP SunShot Subprogram: CSP Location: Oak Ridge National Laboratory, Oak Ridge, TN SunShot Award Amount: $2,175,000 This project seeks to develop a predictive lifetime model for materials in supercritical carbon dioxide (sCO2) conditions similar to

  4. Code System for Supercritical Water Cooled Reactor LOCA Analysis.

    Energy Science and Technology Software Center (OSTI)

    1999-10-13

    Version 00 The new SCRELA code was developed to analyze the LOCA of the supercritical water cooled reactor. Since the currently available LWR codes for LOCA analysis could not analyze the significant differences in reactor characteristics between the supercritical-water cooled reactor and the current LWR, the first objective of this code development was to analyze the uniqueness of this reactor. The behavior of the supercritical water in the blowdown phase and the reflood phase ismore » modeled.« less

  5. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles This fact sheet describes a project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by Brayton Energy, aims to develop and demonstrate a low-cost, high-efficiency solar receiver that is compatible with s-CO2 cycles and modern thermal storage subsystems. Supercritical CO2 Brayton-cycle

  6. Rapid ignition of fluidized bed boiler

    DOE Patents [OSTI]

    Osborn, Liman D.

    1976-12-14

    A fluidized bed boiler is started up by directing into the static bed of inert and carbonaceous granules a downwardly angled burner so that the hot gases cause spouting. Air is introduced into the bed at a rate insufficient to fluidize the entire bed. Three regions are now formed in the bed, a region of lowest gas resistance, a fluidized region and a static region with a mobile region at the interface of the fluidized and static regions. Particles are transferred by the spouting action to form a conical heap with the carbonaceous granules concentrated at the top. The hot burner gases ignite the carbonaceous matter on the top of the bed which becomes distributed in the bed by the spouting action and bed movement. Thereafter the rate of air introduction is increased to fluidize the entire bed, the spouter/burner is shut off, and the entire fluidized bed is ignited.

  7. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2012. progressreportsunshotbraytonfy12q4.pdf More Documents & Publications High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1...

  8. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1 High-Efficiency Receivers for...

  9. Development of Materials for Supercritical-Water-Cooled Reactor

    Broader source: Energy.gov [DOE]

    Supercritical-Water-Cooled Reactor (SCWR) was selected as one of the promising candidates in Generation IV reactors for its prominent advantages; those are the high thermal efficiency, the system...

  10. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    aim to demonstrate a multi-megawatt power cycle using supercritical carbon dioxide (s-CO2) as the working fluid. The use of carbon dioxide instead of steam allows higher...

  11. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. ... Supercritical CO2 Brayton-cycle engines have the potential to increase conversion efficiency to more ...

  12. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus; Yanagihara, Naohisa; Dyke, James T.; Vemulapalli, Krishna

    1991-09-03

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  13. Supercritical fluid carbon dioxide cleaning of plutonium parts

    SciTech Connect (OSTI)

    Hale, S.J.

    1991-12-31

    Supercritical fluid carbon dioxide is under investigation in this work for use as a cleaning solvent for the final cleaning of plutonium parts. These parts must be free of organic residue to avoid corrosion in the stockpile. Initial studies on stainless steel and full-scale mock-up parts indicate that the oils of interest are easily and adequately cleaned from the metal surfaces with supercritical fluid carbon dioxide. Results from compatibility studies show that undesirable oxidation or other surface reactions are not occurring during exposure of plutonium to the supercritical fluid. Cleaning studies indicate that the oils of interest are removed from the plutonium surface under relatively mild conditions. These studies indicate that supercritical fluid carbon dioxide is a very promising cleaning medium for this application.

  14. Advanced Combustion

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2013-03-11

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  15. Oil-Fired Boilers and Furnaces | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Diagram of an oil boiler. New tanks are generally double-wall or have a spill container built underneath to reduce the chances of an oil spill. Typically, the tank drip pan shown...

  16. Gas-Fired Boilers and Furnaces | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    A residential natural gas meter. A residential natural gas meter. What does this mean for me? Your gas boiler or furnace may be oversized, particularly if you've upgraded the...

  17. New Boilers, Big Savings for Minnesota County | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    However, hopes for a new set of boilers were revived in April after the county received a ... Local contractor El-Jay Plumbing & Heating of St. Cloud, Minn., will install the new ...

  18. Recover Heat from Boiler Blowdown - Steam Tip Sheet #10

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on recovering heat from boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  19. Minimize Boiler Short Cycling Losses - Steam Tip Sheet #16

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  20. Building America Case Study: Boiler Control Replacement for Hydronical...

    Energy Savers [EERE]

    ... Similar case studies of the effectiveness of these control features in steam- heated buildings would be valuable. Description A state-of-the-art boiler control system includes a ...

  1. Minimize Boiler Short Cycling Losses - Steam Tip Sheet #16

    SciTech Connect (OSTI)

    2006-01-01

    This revised AMO tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  2. Improved Heat Recovery in Biomass-Fired Boilers

    SciTech Connect (OSTI)

    2009-11-01

    This factsheet describes a research project whose goal is to reduce corrosion and improve the life span of boiler superheater tubes operating at temperatures above the melting point of ash deposits.

  3. Containment system for supercritical water oxidation reactor

    DOE Patents [OSTI]

    Chastagner, P.

    1994-07-05

    A system is described for containment of a supercritical water oxidation reactor in the event of a rupture of the reactor. The system includes a containment for housing the reaction vessel and a communicating chamber for holding a volume of coolant, such as water. The coolant is recirculated and sprayed to entrain and cool any reactants that might have escaped from the reaction vessel. Baffles at the entrance to the chamber prevent the sprayed coolant from contacting the reaction vessel. An impact-absorbing layer is positioned between the vessel and the containment to at least partially absorb momentum of any fragments propelled by the rupturing vessel. Remote, quick-disconnecting fittings exterior to the containment, in cooperation with shut-off valves, enable the vessel to be isolated and the system safely taken off-line. Normally-closed orifices throughout the containment and chamber enable decontamination of interior surfaces when necessary. 2 figures.

  4. Viscosity correlations for binary supercritical fluids

    SciTech Connect (OSTI)

    Tilly, K.D.; Foster, N.R.; Macnaughton, S.J.; Tomasko, D.L. . School of Chemical Engineering and Industrial Chemistry)

    1994-03-01

    The viscosities and densities of supercritical mixtures of methanol, ethanol, n-propanol, isopropanol, n-pentane, n-hexane, n-heptane, and acetone in carbon dioxide, at concentrations between 1 and 5 mol %, were determined using a falling weight viscometer at pressures up to 240 bar and at temperatures between 313 and 328 K. The effects of pressure, temperature, cosolvent concentration, and the physical properties of the cosolvents on the mixture viscosity and density were examined. The viscosities and the densities of the mixtures were found to increase with the size, polarity, and concentration of the cosolvent molecule. The mixture viscosity was correlated with several empirical dense gas viscosity correlations. The best correlation was the Ely and Hanley technique modified with a density-dependent noncorrespondence factor. The Peng-Robinson equation of state was used to correlate the mixture densities.

  5. Containment system for supercritical water oxidation reactor

    DOE Patents [OSTI]

    Chastagner, Philippe

    1994-01-01

    A system for containment of a supercritical water oxidation reactor in the event of a rupture of the reactor. The system includes a containment for housing the reaction vessel and a communicating chamber for holding a volume of coolant, such as water. The coolant is recirculated and sprayed to entrain and cool any reactants that might have escaped from the reaction vessel. Baffles at the entrance to the chamber prevent the sprayed coolant from contacting the reaction vessel. An impact-absorbing layer is positioned between the vessel and the containment to at least partially absorb momentum of any fragments propelled by the rupturing vessel. Remote, quick-disconnecting fittings exterior to the containment, in cooperation with shut-off valves, enable the vessel to be isolated and the system safely taken off-line. Normally-closed orifices throughout the containment and chamber enable decontamination of interior surfaces when necessary.

  6. Fischer-Tropsch synthesis in supercritical fluids. Final report

    SciTech Connect (OSTI)

    Akgerman, A.; Bukur, D.B.

    1998-12-31

    The objective of this study was to investigate Fischer-Tropsch Synthesis (FTS) in the supercritical phase employing a commercial precipitated iron catalysts. As the supercritical fluid the authors used propane and n-hexane. The catalyst had a nominal composition of 100 Fe/5 Cu/4.2 K/25 SiO{sub 2} on mass basis and was used in a fixed bed reactor under both normal (conventional) and supercritical conditions. Experimental data were obtained at different temperatures (235 C, 250 C, and 260 C) and synthesis gas feed compositions (H{sub 2}/CO molar feed ratio of 0.67, 1.0 and 2.0) in both modes of operation under steady state conditions. The authors compared the performance of the precipitated iron catalyst in the supercritical phase, with the data obtained in gas phase (fixed bed reactor) and slurry phase (STS reactor). Comparisons were made in terms of bulk catalyst activity and various aspects of product selectivity (e.g. lumped hydrocarbon distribution and olefin content as a function of carbon number). In order to gain better understanding of the role of intraparticle mass transfer during FTS under conventional or supercritical conditions, the authors have measured diffusivities of representative hydrocarbon products in supercritical fluids, as well as their effective diffusion rates into the pores of catalyst at the reaction conditions. They constructed a Taylor dispersion apparatus to measure diffusion coefficients of hydrocarbon products of FTS in sub and supercritical ethane, propane, and hexane. In addition, they developed a tracer response technique to measure the effective diffusivities in the catalyst pores at the same conditions. Based on these results they have developed an equation for prediction of diffusion in supercritical fluids, which is based on the rough hard sphere theory.

  7. Using supercritical carbon dioxide as a fracturing fluid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using supercritical carbon dioxide as a fracturing fluid Using supercritical carbon dioxide as a fracturing fluid The Laboratory team used a combination of experiments and modeling for the investigation. June 25, 2015 Simulation of a selection of the particle trajectories toward the well. Simulation of a selection of the particle trajectories toward the well. Communications Office (505) 667-7000 The Laboratory research is part of an ongoing project to make the necessary measurements and develop

  8. Sandia's Supercritical Carbon-Dioxide/Brayton-Cycle Laboratory Signs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Important MOU with Industry Partners Supercritical Carbon-Dioxide/Brayton-Cycle Laboratory Signs Important MOU with Industry Partners - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power

  9. Process for treating effluent from a supercritical water oxidation reactor

    DOE Patents [OSTI]

    Barnes, C.M.; Shapiro, C.

    1997-11-25

    A method for treating a gaseous effluent from a supercritical water oxidation reactor containing entrained solids is provided comprising the steps of expanding the gas/solids effluent from a first to a second lower pressure at a temperature at which no liquid condenses; separating the solids from the gas effluent; neutralizing the effluent to remove any acid gases; condensing the effluent; and retaining the purified effluent to the supercritical water oxidation reactor. 6 figs.

  10. Transonic Combustion ’ - Injection Strategy Development for Supercritical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gasoline Injection-Ignition in a Light Duty Engine | Department of Energy Transonic Combustion ’ - Injection Strategy Development for Supercritical Gasoline Injection-Ignition in a Light Duty Engine Transonic Combustion ’ - Injection Strategy Development for Supercritical Gasoline Injection-Ignition in a Light Duty Engine Novel fuel injection equipment enables knock-free ignition with low noise and smoke in compression-ignition engines and low-particulates in spark-ignition engines.

  11. Process for treating effluent from a supercritical water oxidation reactor

    DOE Patents [OSTI]

    Barnes, Charles M.; Shapiro, Carolyn

    1997-01-01

    A method for treating a gaseous effluent from a supercritical water oxidation reactor containing entrained solids is provided comprising the steps of expanding the gas/solids effluent from a first to a second lower pressure at a temperature at which no liquid condenses; separating the solids from the gas effluent; neutralizing the effluent to remove any acid gases; condensing the effluent; and retaining the purified effluent to the supercritical water oxidation reactor.

  12. Biomass Boiler to Heat Oregon School | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Boiler to Heat Oregon School Biomass Boiler to Heat Oregon School April 26, 2011 - 5:29pm Addthis Oregon Governor Kulongoski maneuvers a backhoe to break ground at the Vernonia school site. | Department of Energy Image | Photo by Joel Danforth, Contractor | Public Domain | Oregon Governor Kulongoski maneuvers a backhoe to break ground at the Vernonia school site. | Department of Energy Image | Photo by Joel Danforth, Contractor | Public Domain | Joel Danforth Project Officer, Golden

  13. Energy Cost Savings Calculator for Commercial Boilers: Closed Loop, Space

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heating Applications Only | Department of Energy Commercial Boilers: Closed Loop, Space Heating Applications Only Energy Cost Savings Calculator for Commercial Boilers: Closed Loop, Space Heating Applications Only This cost calculator is a screening tool that estimates a product's lifetime energy cost savings at various efficiency levels. Learn more about the base model and other assumptions. Project Type Is this a new installation or a replacement? New Replacement What is the deliverable

  14. Brief introduction of GEF efficient industrial boiler project in China

    SciTech Connect (OSTI)

    Meijian, T.

    1996-12-31

    The present situation of installed industrial boilers, their efficiency and environmental impact are assessed. And the factors contribute to the low efficiency and serious pollution are summarized. Based on WB-assisted GEF project, {open_quotes}Efficient Industrial Boiler Project{close_quotes} aimed at CO{sub 2} mitigation in China, a series of effective measures to bring the GHG emission under control are addressed, in technology, system performance, and operation management aspects.

  15. Guide to Low-Emission Boiler and Combustion Equipment Selection

    Office of Energy Efficiency and Renewable Energy (EERE)

    The guide presents topics pertaining to industrial, commercial, and institutional (ICI) boilers. Background information about various types of commercially available boilers is provided along with discussion about the fuels that they burn and the emissions that they produce. Also included are discussions about emissions standards and compliance issues, technical details related to emissions control techniques, and other important selection considerations. It is part of a suite of publications offered by the Department of Energy to improve steam system performance.

  16. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2002-01-23

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report includes results from laboratory testing of ULHS systems along with other lightweight cement systems: foamed and sodium silicate slurries. Comparison studies of the three cement systems examined several properties: tensile strength, Young's modulus, water permeability, and shear bond. Testing was also done to determine the effect that temperature cycling has on the shear bond properties of the cement systems. In addition, analysis was carried out to examine alkali silica reactivity of slurries containing ULHS. Data is also presented from a study investigating the effects of mixing and pump circulation on breakage of ULHS. Information is also presented about the field application of ULHS in cementing a 7-in. intermediate casing in south Texas.

  17. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2002-10-31

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report includes results from laboratory testing of ULHS systems along with other lightweight cement systems, including foamed and sodium silicate slurries. During this project quarter, a comparison study of the three cement systems examined the effect that cement drillout has on the three cement systems. Testing to determine the effect of pressure cycling on the shear bond properties of the cement systems was also conducted. This report discusses testing that will be performed for analyzing the alkali-silica reactivity of ULHS in cement slurries, as well as the results of Field Tests 1 and 2.

  18. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2002-04-29

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report includes results from laboratory testing of ULHS systems along with other lightweight cement systems, including foamed and sodium silicate slurries. During this project quarter, comparison studies of the three cement systems examined several properties: tensile strength, Young's modulus, and shear bond. Testing to determine the effect of temperature cycling on the shear bond properties of the cement systems was also conducted. In addition, the stress-strain behavior of the cement types was studied. This report discusses a software program that is being developed to help design ULHS cements and foamed cements.

  19. Ultra high resolution tomography

    SciTech Connect (OSTI)

    Haddad, W.S.

    1994-11-15

    Recent work and results on ultra high resolution three dimensional imaging with soft x-rays will be presented. This work is aimed at determining microscopic three dimensional structure of biological and material specimens. Three dimensional reconstructed images of a microscopic test object will be presented; the reconstruction has a resolution on the order of 1000 A in all three dimensions. Preliminary work with biological samples will also be shown, and the experimental and numerical methods used will be discussed.

  20. Cofiring Wood and Coal to Stoker Boilers in Pittsburgh

    SciTech Connect (OSTI)

    Cobb, J.T., Jr.; Elder, W.W.

    1997-07-01

    The prime objective of the University of Pittsburgh's overall wood/coal cofiring program is the successful introduction of commercial cofiring of urban wood wastes into the stoker boilers of western Pennsylvania. Central to this objective is the demonstration test at the Pittsburgh Brewing Company. In this test the project team is working to show that two commercially-available clean wood wastes - tub-ground pallet waste and chipped clearance wood - can be included in the fuel fed daily to an industrial stoker boiler. Irrespective of its economic outcome, the technical success of the demonstration at the brewery will allow the local air quality regulation agency to permit a parametric test at the Bellefield Boiler Plant. The objective of this test is to obtain comprehensive data on all key parameters of this operational boiler while firing wood with coal. The data would then be used for thorough generic technical and economic analyses. The technical analysis would be added to the open literature for the general planning and operational guidance for boiler owners and operators. The economic analysis would gage the potential for providing this stoker fuel commercially in an urban setting and for purchasing it regularly for combustion in an urban stoker boiler.

  1. Automated Boiler Combustion Controls for Emission Reduction and Efficiency Improvement

    SciTech Connect (OSTI)

    None, None

    1998-12-02

    In the late 1980s, then President Bush visited Krakow, Poland. The terrible air quality theremotivated him to initiate a USAID-funded program, managed by DOE, entitled "Krakow Clean Fossil Fuels and Energy Efficiency Program." The primary objective of this program was to encourage the formation of commercial ventures between U.S. and Polish firms to provide equipment and/or services to reduce pollution from low-emission sources in Krakow, Poland. This program led to the award of a number of cooperative agreements, including one to Control Techtronics International. The technical objective of CTI's cooperative agreement is to apply combustion controls to existing boiler plants in Krakow and transfer knowledge and technology through a joint U.S. and Polish commercial venture. CTI installed automatic combustion controls on five coal boilers for the district heating system in Krakow. Three of these were for domestic hot-water boilers, and two were for steam for industrial boilers. The following results have occurred due to the addition of CTI's combustion controls on these five existing boilers: ! 25% energy savings ! 85% reduction in particulate emissions The joint venture company CTI-Polska was then established. Eleven additional technical and costing proposals were initiated to upgrade other coal boilers in Krakow. To date, no co-financing has been made available on the Polish side. CTI-Polska continues in operation, serving customers in Russia and Ukraine. Should the market in Poland materialize, the joint venture company is established there to provide equipment and service.

  2. Oregon Hospital Heats Up with a Biomass Boiler | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hospital Heats Up with a Biomass Boiler Oregon Hospital Heats Up with a Biomass Boiler December 27, 2012 - 4:30pm Addthis Using money from the Recovery Act, Blue Mountain Hospital replaced one of its 1950s crude oil boilers with a wood-pellet boiler -- saving the hospital about $100,000 a year in heating costs. | Photo courtesy of the Oregon Department of Energy. Using money from the Recovery Act, Blue Mountain Hospital replaced one of its 1950s crude oil boilers with a wood-pellet boiler --

  3. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  4. Postcombustion and its influences in 135 MWe CFB boilers

    SciTech Connect (OSTI)

    Shaohua Li; Hairui Yang; Hai Zhang; Qing Liu; Junfu Lu; Guangxi Yue

    2009-09-15

    In the cyclone of a circulating fluidized bed (CFB) boiler, a noticeable increment of flue gas temperature, caused by combustion of combustible gas and unburnt carbon content, is often found. Such phenomenon is defined as post combustion, and it could introduce overheating of reheated and superheated steam and extra heat loss of exhaust flue gas. In this paper, mathematical modeling and field measurements on post combustion in 135MWe commercial CFB boilers were conducted. A novel one-dimensional combustion model taking post combustion into account was developed. With this model, the overall combustion performance, including size distribution of various ashes, temperature profile, and carbon content profiles along the furnace height, heat release fraction in the cyclone and furnace were predicted. Field measurements were conducted by sampling gas and solid at different positions in the boiler under different loads. The measured data and corresponding model-calculated results were compared. Both prediction and field measurements showed post combustion introduced a temperature increment of flue gas in the cyclone of the 135MWe CFB boiler in the range of 20-50{sup o}C when a low-volatile bituminous coal was fired. Although it had little influence on ash size distribution, post combustion had a remarkable influence on the carbon content profile and temperature profile in the furnace. Moreover, it introduced about 4-7% heat release in the cyclone over the total heat release in the boiler. This fraction slightly increased with total air flow rate and boiler load. Model calculations were also conducted on other two 135MWe CFB boilers burning lignite and anthracite coal, respectively. The results confirmed that post combustion was sensitive to coal type and became more severe as the volatile content of the coal decreased. 15 refs., 11 figs., 4 tabs.

  5. 10 MW Supercritical CO2 Turbine Test

    SciTech Connect (OSTI)

    Turchi, Craig

    2014-01-29

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700°C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650ºC in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late

  6. Ultra-wideband receiver

    DOE Patents [OSTI]

    McEwan, T.E.

    1996-06-04

    An ultra-wideband (UWB) receiver utilizes a strobed input line with a sampler connected to an amplifier. In a differential configuration, {+-}UWB inputs are connected to separate antennas or to two halves of a dipole antenna. The two input lines include samplers which are commonly strobed by a gating pulse with a very low duty cycle. In a single ended configuration, only a single strobed input line and sampler is utilized. The samplers integrate, or average, up to 10,000 pulses to achieve high sensitivity and good rejection of uncorrelated signals. 21 figs.

  7. Ultra-wideband receiver

    DOE Patents [OSTI]

    McEwan, Thomas E.

    1994-01-01

    An ultra-wideband (UWB) receiver utilizes a strobed input line with a sampler connected to an amplifier. In a differential configuration, .+-.UWB inputs are connected to separate antennas or to two halves of a dipole antenna. The two input lines include samplers which are commonly strobed by a gating pulse with a very low duty cycle. In a single ended configuration, only a single strobed input line and sampler is utilized. The samplers integrate, or average, up to 10,000 pulses to achieve high sensitivity and good rejection of uncorrelated signals.

  8. Ultra-wideband receiver

    DOE Patents [OSTI]

    McEwan, T.E.

    1994-09-06

    An ultra-wideband (UWB) receiver utilizes a strobed input line with a sampler connected to an amplifier. In a differential configuration, [+-] UWB inputs are connected to separate antennas or to two halves of a dipole antenna. The two input lines include samplers which are commonly strobed by a gating pulse with a very low duty cycle. In a single ended configuration, only a single strobed input line and sampler is utilized. The samplers integrate, or average, up to 10,000 pulses to achieve high sensitivity and good rejection of uncorrelated signals. 16 figs.

  9. Ultra-wideband receiver

    DOE Patents [OSTI]

    McEwan, Thomas E.

    1996-01-01

    An ultra-wideband (UWB) receiver utilizes a strobed input line with a sampler connected to an amplifier. In a differential configuration, .+-.UWB inputs are connected to separate antennas or to two halves of a dipole antenna. The two input lines include samplers which are commonly strobed by a gating pulse with a very low duty cycle. In a single ended configuration, only a single strobed input line and sampler is utilized. The samplers integrate, or average, up to 10,000 pulses to achieve high sensitivity and good rejection of uncorrelated signals.

  10. Exfoliation Propensity of Oxide Scale in Heat Exchangers Used for Supercritical CO2 Power Cycles

    SciTech Connect (OSTI)

    Sabau, Adrian S; Shingledecker, John P.; Kung, Steve; Wright, Ian G.; Nash, Jim

    2016-01-01

    Supercritical CO2 (sCO2) Brayton cycle systems offer the possibility of improved efficiency in future fossil energy power generation plants operating at temperatures of 650 C and above. As there are few data on the oxidation/corrosion behavior of structural alloys in sCO2 at these temperatures, modeling to predict the propensity for oxide exfoliation is not well developed, thus hindering materials selection for these novel cycles. The ultimate goal of this effort is to provide needed data on scale exfoliation behavior in sCO2 for confident alloy selection. To date, a model developed by ORNL and EPRI for the exfoliation of oxide scales formed on boiler tubes in high-temperature, high-pressure steam has proven useful for managing exfoliation in conventional steam plants. A major input provided by the model is the ability to predict the likelihood of scale failure and loss based on understanding of the evolution of the oxide morphologies and the conditions that result in susceptibility to exfoliation. This paper describes initial steps taken to extend the existing model for exfoliation of steam-side oxide scales to sCO2 conditions. The main differences between high-temperature, high-pressure steam and sCO2 that impact the model involve (i) significant geometrical differences in the heat exchangers, ranging from standard pressurized tubes seen typically in steam-producing boilers to designs for sCO2 that employ variously-curved thin walls to create shaped flow paths for extended heat transfer area and small channel cross-sections to promote thermal convection and support pressure loads; (ii) changed operating characteristics with sCO2 due to the differences in physical and thermal properties compared to steam; and (iii) possible modification of the scale morphologies, hence properties that influence exfoliation behavior, due to reaction with carbon species from sCO2. The numerical simulations conducted were based on an assumed sCO2 operating schedule and several

  11. Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method

    Broader source: Energy.gov [DOE]

    Supercritical transesterification processing permits efficient fuel system and combustion chamber designs to optimize fuel utilization in diesel engines.,

  12. 10 MW Supercritical CO2 Turbine Test (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    10 MW Supercritical CO2 Turbine Test Citation Details In-Document Search Title: 10 MW Supercritical CO2 Turbine Test The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved

  13. New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement

    SciTech Connect (OSTI)

    Qu, Ming; Abdelaziz, Omar; Yin, Hongxi

    2014-11-01

    Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150 200 C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50 60 C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural gas boilers for applications with process fluid return temperatures higher than or close to the dew point of the water vapor in the flue gas.

  14. Oil ash corrosion; A review of utility boiler experience

    SciTech Connect (OSTI)

    Paul, L.D. ); Seeley, R.R. )

    1991-02-01

    In this paper a review of experience with oil ash corrosion is presented along with current design practices used to avoid excessive tube wastage. Factors influencing oil ash corrosion include fuel chemistry, boiler operation, and boiler design. These factors are interdependent and determine the corrosion behavior in utility boilers. Oil ash corrosion occurs when vanadium-containing ash deposits on boiler tube surfaces become molten. These molten ash deposits dissolve protective oxides and scales causing accelerated tube wastage. Vanadium is the major fuel constituent responsible for oil ash corrosion. Vanadium reacts with sodium, sulfur, and chlorine during combustion to produce lower melting temperature ash compositions, which accelerate tube wastage. Limiting tube metal temperatures will prevent ash deposits from becoming molten, thereby avoiding the onset of oil ash corrosion. Tube metal temperatures are limited by the use of a parallel stream flow and by limiting steam outlet temperatures. Operating a boiler with low excess air has helped avoid oil ash corrosion by altering the corrosive combustion products. Air mixing and distribution are essential to the success of this palliative action. High chromium alloys and coatings form more stable protective scaled on tubing surfaces, which result in lower oil ash corrosion rates. However, there is not material totally resistant to oil ash corrosion.

  15. Plasma-supported coal combustion in boiler furnace

    SciTech Connect (OSTI)

    Askarova, A.S.; Karpenko, E.I.; Lavrishcheva, Y.I.; Messerle, V.E.; Ustimenko, A.B.

    2007-12-15

    Plasma activation promotes more effective and environmentally friendly low-rank coal combustion. This paper presents Plasma Fuel Systems that increase the burning efficiency of coal. The systems were tested for fuel oil-free start-up of coal-fired boilers and stabilization of a pulverized-coal flame in power-generating boilers equipped with different types of burners, and burning all types of power-generating coal. Also, numerical modeling results of a plasma thermochemical preparation of pulverized coal for ignition and combustion in the furnace of a utility boiler are discussed in this paper. Two kinetic mathematical models were used in the investigation of the processes of air/fuel mixture plasma activation: ignition and combustion. A I-D kinetic code PLASMA-COAL calculates the concentrations of species, temperatures, and velocities of the treated coal/air mixture in a burner incorporating a plasma source. The I-D simulation results are initial data for the 3-D-modeling of power boiler furnaces by the code FLOREAN. A comprehensive image of plasma-activated coal combustion processes in a furnace of a pulverized-coal-fired boiler was obtained. The advantages of the plasma technology are clearly demonstrated.

  16. Slag monitoring system for combustion chambers of steam boilers

    SciTech Connect (OSTI)

    Taler, J.; Taler, D.

    2009-07-01

    The computer-based boiler performance system presented in this article has been developed to provide a direct and quantitative assessment of furnace and convective surface cleanliness. Temperature, pressure, and flow measurements and gas analysis data are used to perform heat transfer analysis in the boiler furnace and evaporator. Power boiler efficiency is calculated using an indirect method. The on-line calculation of the exit flue gas temperature in a combustion chamber allows for an on-line heat flow rate determination, which is transferred to the boiler evaporator. Based on the energy balance for the boiler evaporator, the superheated steam mass flow rate is calculated taking into the account water flow rate in attemperators. Comparing the calculated and the measured superheated steam mass flow rate, the effectiveness of the combustion chamber water walls is determined in an on-line mode. Soot-blower sequencing can be optimized based on actual cleaning requirements rather than on fixed time cycles contributing to lowering of the medium usage in soot blowers and increasing of the water-wall lifetime.

  17. Extraction of metals using supercritical fluid and chelate forming ligand

    DOE Patents [OSTI]

    Wai, C.M.; Laintz, K.E.

    1998-03-24

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent is described. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated {beta}-diketone. In especially preferred embodiments the extraction solvent is supercritical carbon dioxide, and the chelating agent comprises a fluorinated {beta}-diketone and a trialkyl phosphate, or a fluorinated {beta}-diketone and a trialkylphosphine oxide. Although a trialkyl phosphate can extract lanthanides and actinides from acidic solutions, a binary mixture comprising a fluorinated {beta}-diketone and a trialkyl phosphate or a trialkylphosphine oxide tends to enhance the extraction efficiencies for actinides and lanthanides. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The method is particularly useful for extracting actinides and lanthanides from acidic solutions. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

  18. Extraction of metals using supercritical fluid and chelate forming legand

    DOE Patents [OSTI]

    Wai, Chien M.; Laintz, Kenneth E.

    1998-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent is described. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated .beta.-diketone. In especially preferred embodiments the extraction solvent is supercritical carbon dioxide, and the chelating agent comprises a fluorinated .beta.-diketone and a trialkyl phosphate, or a fluorinated .beta.-diketone and a trialkylphosphine oxide. Although a trialkyl phosphate can extract lanthanides and actinides from acidic solutions, a binary mixture comprising a fluorinated .beta.-diketone and a trialkyl phosphate or a trialkylphosphine oxide tends to enhance the extraction efficiencies for actinides and lanthanides. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The method is particularly useful for extracting actinides and lanthanides from acidic solutions. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  19. Experimental study of elliptical jet from sub to supercritical conditions

    SciTech Connect (OSTI)

    Muthukumaran, C. K.; Vaidyanathan, Aravind

    2014-04-15

    The jet mixing at supercritical conditions involves fluid dynamics as well as thermodynamic phenomena. All the jet mixing studies at critical conditions to the present date have focused only on axisymmetric jets. When the liquid jet is injected into supercritical environment, the thermodynamic transition could be well understood by considering one of the important fluid properties such as surface tension since it decides the existence of distinct boundary between the liquid and gaseous phase. It is well known that an elliptical liquid jet undergoes axis-switching phenomena under atmospheric conditions due to the presence of surface tension. The experimental investigations were carried out with low speed elliptical jet under supercritical condition. Investigation of the binary component system with fluoroketone jet and N{sub 2} gas as environment shows that the surface tension force dominates for a large downstream distance, indicating delayed thermodynamic transition. The increase in pressure to critical state at supercritical temperature is found to expedite the thermodynamic transition. The ligament like structures has been observed rather than droplets for supercritical pressures. However, for the single component system with fluoroketone jet and fluoroketone environment shows that the jet disintegrates into droplets as it is subjected to the chamber conditions even for the subcritical pressures and no axis switching phenomenon is observed. For a single component system, as the pressure is increased to critical state, the liquid jet exhibits gas-gas like mixing behavior and that too without exhibiting axis-switching behavior.

  20. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2003-06-16

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report discusses testing that was performed for analyzing the alkali-silica reactivity of ULHS in cement slurries. Laboratory testing during the tenth quarter focused on evaluation of the alkali-silica reaction of eight different cement compositions, four of which contain ULHS. The original laboratory procedure for measuring set cement expansion resulted in test specimen erosion that was unacceptable. A different expansion procedure is being evaluated. This report provides a progress summary of ASR testing. The testing program initiated in November produced questionable initial results so the procedure was modified slightly and the testing was reinitiated. The results obtained with the modified procedure showed improvement over data obtained with the original procedure, but questionable data were obtained from several of the compositions. Additional modification of test procedures for compositions containing TXI Lightweight cement are being implemented and testing is ongoing.

  1. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2003-07-31

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). This report discusses testing that was performed for analyzing the alkali-silica reactivity of ULHS in cement slurries. Laboratory testing during the eleventh quarter focused on evaluation of the alkali-silica reaction of eight different cement compositions, four of which contain ULHS. This report provides a progress summary of ASR testing. The original laboratory procedure for measuring set cement expansion resulted in unacceptable erosion of the test specimens. In subsequent tests, a different expansion procedure was implemented and an alternate curing method for cements formulated with TXI Lightweight cement was employed to prevent sample failure caused by thermal shock. The results obtained with the modified procedure showed improvement over data obtained with the original procedure, but data for some compositions were still questionable. Additional modification of test procedures for compositions containing TXI Lightweight cement were implemented and testing is ongoing.

  2. Task 2 Materials for Advanced Boiler and Oxy-combustion Systems...

    Office of Scientific and Technical Information (OSTI)

    Task 2 Materials for Advanced Boiler and Oxy-combustion Systems (NETL-US) Citation Details In-Document Search Title: Task 2 Materials for Advanced Boiler and Oxy-combustion Systems ...

  3. Detection and Control of Deposition on Pendant Tubes in Kraft Chemical Recovery Boilers

    Broader source: Energy.gov [DOE]

    The kraft chemical recovery boilers used for pulp processing are large and expensive and can be the limiting factor for mill capacity. Improvements in boiler efficiency with better control of...

  4. Property:Building/SPPurchasedEngyForPeriodMwhYrOil-FiredBoiler...

    Open Energy Info (EERE)

    eriodMwhYrOil-FiredBoiler Jump to: navigation, search This is a property of type String. Oil-fired boiler Pages using the property "BuildingSPPurchasedEngyForPeriodMwhYrOil-FiredB...

  5. Property:Building/SPPurchasedEngyNrmlYrMwhYrOil-FiredBoiler ...

    Open Energy Info (EERE)

    rmlYrMwhYrOil-FiredBoiler Jump to: navigation, search This is a property of type String. Oil-fired boiler Pages using the property "BuildingSPPurchasedEngyNrmlYrMwhYrOil-FiredBoil...

  6. Characterization of the U.S. Industrial/Commercial Boiler Population -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Final Report, May 2005 | Department of Energy U.S. Industrial/Commercial Boiler Population - Final Report, May 2005 Characterization of the U.S. Industrial/Commercial Boiler Population - Final Report, May 2005 The U.S. industrial and commercial sectors consume large quantities of energy. Much of this energy is used in boilers to generate steam and hot water. This 2005 report characterizes the boilers in the industrial and commercial sector in terms of number of units, aggregate capacity,

  7. Study of oil combustion in the TGMP-314 boiler with hearth burners

    SciTech Connect (OSTI)

    Usman, Yu.M.; Shtal'man, S.G.; Enyakin, Yu.P.; Abryutin, A.A.; Levin, M.M.; Taran, O.E.; Chuprov, V.V.; Antonov, A.Yu.

    1983-01-01

    Studies of the TGMP-314 boiler with hearth configured burners included the gas mixture in the boiler, the degree of fuel combustion at various heights in the boiler, hydrogen sulfide content in the near-wall zones of the boiler, and temperature distribution fields. Experimental data showed that the hearth burners, in conjunction with steam-mechanical atomizing burners, operate with the least possible excess air over a wide range of load changes. The operation and performance of the hearth burners are discussed.

  8. Consider Installing Turbulators on Two- and Three-Pass Firetube Boilers

    Office of Energy Efficiency and Renewable Energy (EERE)

    This tip sheet outlines the benefits of turbulators on firetube boilers as part of optimized steam systems.

  9. ITP Energy Intensive Processes: Improved Heat Recovery in Biomass-Fired Boilers

    Office of Energy Efficiency and Renewable Energy (EERE)

    Factsheet describing the project goal to reduce corrosion and improve the life span of boiler superheater tubes

  10. Guide to Combined Heat and Power Systems for Boiler Owners and Operators, July 2004

    Office of Energy Efficiency and Renewable Energy (EERE)

    This guide presents useful information for evaluating the viability of cogeneration for new or existing ICI boiler installations.

  11. ITP Energy Intensive Processes: Improved Heat Recovery in Biomass-Fired Boilers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    INDUSTRIAL TECHNOLOGIES PROGRAM Improved Heat Recovery in Biomass-Fired Boilers Reducing Superheater Corrosion to Enable Maximum Energy Effi ciency This project will develop materials and coatings to reduce corrosion and improve the life span of boiler superheater tubes exposed to high-temperature biomass exhaust. This improvement in boiler ef ciency will reduce fuel consumption, fuel cost, and CO 2 emissions. Introduction Industrial boilers are commonly used to make process steam, provide

  12. Modeling of a coal-fired natural circulation boiler

    SciTech Connect (OSTI)

    Bhambare, K.S.; Mitra, S.K.; Gaitonde, U.N.

    2007-06-15

    Modeling of a natural circulation boiler for a coal-fired thermal power station is presented here. The boiler system is divided into seven subcomponents, and for each section, models based on conservation of mass, momentum, and energy are formulated. The pressure drop at various sections and the heat transfer coefficients are computed using empirical correlations. Solutions are obtained by using SIMULINK. The model is validated by comparing its steady state and dynamic responses with the actual plant data. Open loop responses of the model to the step changes in the operating parameters, such as pressure, temperature, steam flow, feed water flow, are also analyzed. The present model can be used for the development and design of effective boiler control systems.

  13. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Bob Hurt; Eric Eddings

    2001-01-31

    This is the second Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The focus of our efforts during the last three months have been on: (1) Completion of a long term field test for Rich Reagent Injection (RRI) at the Conectiv BL England Station Unit No.1, a 130 MW Cyclone fired boiler; (2) Extending our Computational Fluid Dynamics (CFD) based NOx model to accommodate the chemistry for RRI in PC fired boilers; (3) Design improvements and calibration tests of the corrosion probe; and (4) Investigations on ammonia adsorption mechanisms and removal processes for Fly Ash.

  14. COAL-FIRED UTILITY BOILERS: SOLVING ASH DEPOSITION PROBLEMS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Steven A. Benson; Jay R. Gunderson

    2001-04-01

    The accumulation of slagging and fouling ash deposits in utility boilers has been a source of aggravation for coal-fired boiler operators for over a century. Many new developments in analytical, modeling, and combustion testing methods in the past 20 years have made it possible to identify root causes of ash deposition. A concise and comprehensive guidelines document has been assembled for solving ash deposition as related to coal-fired utility boilers. While this report accurately captures the current state of knowledge in ash deposition, note that substantial research and development is under way to more completely understand and mitigate slagging and fouling. Thus, while comprehensive, this document carries the title ''interim,'' with the idea that future work will provide additional insight. Primary target audiences include utility operators and engineers who face plant inefficiencies and significant operational and maintenance costs that are associated with ash deposition problems. Pulverized and cyclone-fired coal boilers are addressed specifically, although many of the diagnostics and solutions apply to other boiler types. Logic diagrams, ash deposit types, and boiler symptoms of ash deposition are used to aid the user in identifying an ash deposition problem, diagnosing and verifying root causes, determining remedial measures to alleviate or eliminate the problem, and then monitoring the situation to verify that the problem has been solved. In addition to a step-by-step method for identifying and remediating ash deposition problems, this guideline document (Appendix A) provides descriptions of analytical techniques for diagnostic testing and gives extensive fundamental and practical literature references and addresses of organizations that can provide help in alleviating ash deposition problems.

  15. Destruction of energetic materials by supercritical water oxidation

    SciTech Connect (OSTI)

    Beulow, S.J.; Dyer, R.B.; Harradine, D.M.; Robinson, J.M.; Oldenborg, R.C.; Funk, K.A.; McInroy, R.E.; Sanchez, J.A.; Spontarelli, T.

    1993-10-01

    Supercritical water oxidation is a relatively low-temperature process that can give high destruction efficiencies for a variety of hazardous chemical wastes. Results are presented examining the destruction of high explosives and propellants in supercritical water and the use of low temperature, low pressure hydrolysis as a pretreatment process. Reactions of cyclotrimethylene trinitramine (RDX), cyclotetramethylene tetranitramine (HMX), nitroguanidine (NQ), pentaerythritol tetranitrate (PETN), and 2,4,6-trinitrotoluene (TNT) are examined in a flow reactor operated at temperatures between 400{degrees}C and 650{degrees}C. Explosives are introduced into the reactor at concentrations below the solubility limits. For each of the compounds, over 99.9% is destroyed in less than 30 seconds at temperatures above 600{degrees}C. The reactions produce primarily N{sub 2}, N{sub 2}O,CO{sub 2}, and some nitrate and nitrite ions. The distribution of reaction products depends on reactor pressure, temperature, and oxidizer concentration. Kinetics studies of the reactions of nitrate and nitrite ions with various reducing reagents in supercritical water show that they can be rapidly and completely destroyed at temperatures above 525{degrees}C. The use of slurries and hydrolysis to introduce high concentrations of explosives into a supercritical water reactor is examined. For some compounds the rate of reaction depends on particle size. The hydrolysis of explosives at low temperatures (<100{degrees}C) and low pressures (<1 atm) under basic conditions produces water soluble, non-explosive products which are easily destroyed by supercritical water oxidation. Large pieces of explosives (13 cm diameter) have been successfully hydrolyzed. The rate, extent, and products of the hydrolysis depend on the type and concentration of base. Results from the base hydrolysis of triple base propellant M31A1E1 and the subsequent supercritical water oxidation of the hydrolysis products are presented.

  16. Side stream separator for boiler particulate emission control

    SciTech Connect (OSTI)

    Skiven, D.A.; Sortor, C.J.; Tessier, R.J.

    1982-02-09

    A device is disclosed for controlling the particulate emission from coal-fired boilers. A cyclone type primary separator between the boiler and the stack and a bag filter is coupled in side stream relation to the cyclone separator such as to shunt and departiculatize up to about 20% of the gas stream entering the cyclone. The shunted gas is drawn from below the tube sheet of the cyclone separator, filtered through the bags and returned to the stack. Means are provided to control the temperature of the shunted gas within defined limits corresponding to the acid dew point of the gas and the thermal degradation temperature of the filter media.

  17. Step-wise supercritical extraction of carbonaceous residua

    DOE Patents [OSTI]

    Warzinski, Robert P.

    1987-01-01

    A method of fractionating a mixture containing high boiling carbonaceous material and normally solid mineral matter includes processing with a plurality of different supercritical solvents. The mixture is treated with a first solvent of high critical temperature and solvent capacity to extract a large fraction as solute. The solute is released as liquid from solvent and successively treated with other supercritical solvents of different critical values to extract fractions of differing properties. Fractionation can be supplemented by solute reflux over a temperature gradient, pressure let down in steps and extractions at varying temperature and pressure values.

  18. High Thermal Efficiency and Low Emissions with Supercritical Gasoline

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection-Ignition in a Light Duty Engine | Department of Energy High Thermal Efficiency and Low Emissions with Supercritical Gasoline Injection-Ignition in a Light Duty Engine High Thermal Efficiency and Low Emissions with Supercritical Gasoline Injection-Ignition in a Light Duty Engine A novel fuel injector has been developed and tested that addresses the technical challenges of LTC, HCCI, gasoline PPC, and RCCI by reducing complexity and cost. p-16_zoldak.pdf (698.09 KB) More Documents

  19. Asphaltene reaction via supercritical fluid extraction

    SciTech Connect (OSTI)

    Deo, M.D.; Hanson, F.V.

    1993-01-01

    Supercritical fluid extraction (SFE) of bitumen was carried out in a continuous extractor using propane as the solvent at several temperatures and pressures. The asphaltene contents of the residual fractions in the extractor were compared to the asphaltene content of the original bitumen. Asphaltenes were defined as pentane insolubles in this study. It was found that the absolute asphaltene content of the residual fractions exceeded the asphaltene content of the original bitumen. Even when the asphaltene content was prorated by the weight percent of the residual material, it was found to be higher than the original asphaltene content. The data established that the types of compounds separating as asphaltenes changed as the nature of the mixture was altered by SFE. The data also indicated that it may be inappropriate to perform asphaltene material balances to assess the amount of precipitate. The original asphaltene content of a bitumen that is undergoing compositional changes in a sequence of operations may not be an accurate measure of the precipitating tendency of the bitumen in production and processing operations. The asphaltene content of the residual material varied depending on the extraction conditions and was as much as 3--5 times the original asphaltene content. The asphaltene content of the residual material was a maximum at the most efficient extraction condition which was in the vicinity of the critical temperature of propane. The H/C atomic ratio of the residual fractions was lower compared to the original bitumen, indicating that the ratio of polar to nonpolar compounds may also be important from precipitation considerations. Saturate and aromatic compounds were preferentially extracted and the ratio of asphaltenes to resins increased in the residual fractions relative to the original bitumen.

  20. Asphaltene reaction via supercritical fluid extraction

    SciTech Connect (OSTI)

    Deo, M.D.; Hanson, F.V.

    1993-03-01

    Supercritical fluid extraction (SFE) of bitumen was carried out in a continuous extractor using propane as the solvent at several temperatures and pressures. The asphaltene contents of the residual fractions in the extractor were compared to the asphaltene content of the original bitumen. Asphaltenes were defined as pentane insolubles in this study. It was found that the absolute asphaltene content of the residual fractions exceeded the asphaltene content of the original bitumen. Even when the asphaltene content was prorated by the weight percent of the residual material, it was found to be higher than the original asphaltene content. The data established that the types of compounds separating as asphaltenes changed as the nature of the mixture was altered by SFE. The data also indicated that it may be inappropriate to perform asphaltene material balances to assess the amount of precipitate. The original asphaltene content of a bitumen that is undergoing compositional changes in a sequence of operations may not be an accurate measure of the precipitating tendency of the bitumen in production and processing operations. The asphaltene content of the residual material varied depending on the extraction conditions and was as much as 3--5 times the original asphaltene content. The asphaltene content of the residual material was a maximum at the most efficient extraction condition which was in the vicinity of the critical temperature of propane. The H/C atomic ratio of the residual fractions was lower compared to the original bitumen, indicating that the ratio of polar to nonpolar compounds may also be important from precipitation considerations. Saturate and aromatic compounds were preferentially extracted and the ratio of asphaltenes to resins increased in the residual fractions relative to the original bitumen.

  1. NOx Control for Utility Boiler OTR Compliance

    SciTech Connect (OSTI)

    Hamid Farzan; Jennifer L. Sivy

    2005-07-30

    Babcock & Wilcox Power Generation Group (B&W) and Fuel Tech, Inc. (Fuel Tech) teamed to evaluate an integrated solution for NO{sub x} control comprised of B&W's DRB-4Z{reg_sign} low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NO{sub x}OUT{reg_sign}, a selective non-catalytic reduction (SNCR) technology, capable of meeting a target emission limit of 0.15 lb NO{sub x}/10{sup 6} Btu. In a previous project sponsored by the U.S. Department of Energy (DOE), promising results were obtained with this technology from large-scale testing in B&W's 100-million Btu/hr Clean Environment Development Facility (CEDF) which simulates the conditions of large coal-fired utility boilers. Under the most challenging boiler temperatures at full load conditions, NO{sub x} emissions of 0.19 lb/10{sup 6} Btu were achieved firing Powder River Basin coal while controlling ammonia slip to less than 5 ppm. At a 40 million Btu/hr firing rate, NO{sub x} emissions were as low as 0.09 lb/10{sup 6} Btu. Improved performance with this system was proposed for this new program with injection at full load via a convective pass multiple nozzle lance (MNL) in front of the superheater tubes or in the convective tube bank. Convective pass lances represent the current state-of-the-art in SNCR and needed to be evaluated in order to assess the full potential of the combined technologies. The objective of the program was to achieve a NO{sub x} level below 0.15 lb/10{sup 6} Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B&W's DRB-4Z{reg_sign} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign} System. Commercial installations of B&W's low-NO{sub x} burner, in combination with overfire air ports using PRB coal, have demonstrated a NO{sub x} level of 0.15 to 0.2 lb/10{sup 6} Btu under staged combustion conditions. The proposed goal of the combustion system (no SNCR) for this project is a NO

  2. ISSUANCE 2015-05-12: Energy Conservation Program for Consumer Products: Energy Conservation Standards for Residential Boilers

    Broader source: Energy.gov [DOE]

    Energy Conservation Program for Consumer Products: Energy Conservation Standards for Residential Boilers Comment Period Extension.

  3. ISSUANCE 2016-04-08: Energy Conservation Program: Energy Conservation Standards for Commercial Packaged Boilers, Comment Extension

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Commercial Packaged Boilers, Comment Extension

  4. ISSUANCE 2016-04-26: Energy Conservation Program: Energy Conservation Standards for Commercial Packaged Boilers, Comment Extension

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Commercial Packaged Boilers, Comment Extension

  5. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Bob Hurt; Eric Eddings

    2001-07-27

    This is the third Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. A Rich Reagent Injection (RRI) design has been developed for a cyclone fired utility boiler in which a field test of RRI will be performed later this year. Initial evaluations of RRI for PC fired boilers have been performed. Calibration tests have been developed for a corrosion probe to monitor waterwall wastage. Preliminary tests have been performed for a soot model within a boiler simulation program. Shakedown tests have been completed for test equipment and procedures that will be used to measure soot generation in a pilot scale test furnace. In addition, an initial set of controlled experiments for ammonia adsorption onto fly ash in the presence of sulfur have been performed that indicates the sulfur does enhance ammonia uptake.

  6. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert; Pickard, Paul S.; Parma, Jr., Edward J.; Vernon, Milton E.; Gelbard, Fred; Lenard, Roger X.

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  7. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide

    DOE Patents [OSTI]

    Rathke, Jerome W. (Lockport, IL); Klingler, Robert J. (Westmount, IL)

    1993-01-01

    A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

  8. Method for nucleic acid isolation using supercritical fluids

    DOE Patents [OSTI]

    Nivens, David E.; Applegate, Bruce M.

    1999-01-01

    A method for detecting the presence of a microorganism in an environmental sample involves contacting the sample with a supercritical fluid to isolate nucleic acid from the microorganism, then detecting the presence of a particular sequence within the isolated nucleic acid. The nucleic acid may optionally be subjected to further purification.

  9. Method for nucleic acid isolation using supercritical fluids

    DOE Patents [OSTI]

    Nivens, D.E.; Applegate, B.M.

    1999-07-13

    A method is disclosed for detecting the presence of a microorganism in an environmental sample involves contacting the sample with a supercritical fluid to isolate nucleic acid from the microorganism, then detecting the presence of a particular sequence within the isolated nucleic acid. The nucleic acid may optionally be subjected to further purification. 4 figs.

  10. Field-portable supercritical CO.sub.2 extractor

    DOE Patents [OSTI]

    Wright, Bob W.; Zemanian, Thomas S.; Robins, William H.; Woodcock, Leslie J.

    1997-01-01

    The present invention is an apparatus for extracting organic compounds from solid materials. A generator vessel has a removable closure for receiving a solid or liquid solvent which is heated with a resistive heating element to a gaseous or supercritical phase. The removable closure is unencumbered because the side wall is penetrated with an outlet for the gaseous or supercritical solvent. The generator vessel further has a pressure transducer that provides an electronic signal related to pressure of the gaseous or supercritical solvent. The apparatus of the present invention further includes at least one extraction cell having a top and a bottom and a wall extending therebetween, wherein the bottom is sealably penetrated by an inlet for gaseous or supercritical solvent received through a manifold connected to the outlet, the top having an easy-open removable closure cap, and the wall having an outlet port. Finally, a permeable sample cartridge is included for holding the solid materials and to provide radial-flow of the extraction fluid, which is placed within the extraction cell.

  11. Field-portable supercritical CO{sub 2} extractor

    DOE Patents [OSTI]

    Wright, B.W.; Zemanian, T.S.; Robins, W.H.; Woodcock, L.J.

    1997-06-10

    The present invention is an apparatus for extracting organic compounds from solid materials. A generator vessel has a removable closure for receiving a solid or liquid solvent which is heated with a resistive heating element to a gaseous or supercritical phase. The removable closure is unencumbered because the side wall is penetrated with an outlet for the gaseous or supercritical solvent. The generator vessel further has a pressure transducer that provides an electronic signal related to pressure of the gaseous or supercritical solvent. The apparatus of the present invention further includes at least one extraction cell having a top and a bottom and a wall extending there between, wherein the bottom is sealably penetrated by an inlet for gaseous or supercritical solvent received through a manifold connected to the outlet, the top having an easy-open removable closure cap, and the wall having an outlet port. Finally, a permeable sample cartridge is included for holding the solid materials and to provide radial-flow of the extraction fluid, which is placed within the extraction cell. 10 figs.

  12. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.

    1993-03-30

    A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

  13. Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications

    SciTech Connect (OSTI)

    Levasseur, Armand

    2014-01-01

    This Topical Report outlines guidelines and key considerations for design and operation of pulverized coal-fired boilers for oxy-combustion. The scope addressed includes only the boiler island, not the entire oxy-fired CO{sub 2} capture plant. These guidelines are primarily developed for tangential-fired boilers and focus on designs capable of dual air and oxy-fired operation. The guidelines and considerations discussed are applicable to both new units and existing boiler retrofits. These guidelines are largely based on the findings from the extensive 15 MW{sub th} pilot testing and design efforts conducted under this project. A summary level description is provided for each major aspect of boiler design impacted by oxy-combustion, and key considerations are discussed for broader application to different utility and industrial designs. Guidelines address the boiler system arrangement, firing system, boiler thermal design, ducting, materials, control system, and other key systems.

  14. Effects of fluid dynamics on cleaning efficacy of supercritical fluids

    SciTech Connect (OSTI)

    Phelps, M.R.; Willcox, W.A.; Silva, L.J.; Butner, R.S.

    1993-03-01

    Pacific Northwest Laboratory (PNL) and Boeing Aerospace Company are developing a process to clean metal parts using a supercritical solvent. This work is part of an effort to address issues inhibiting the rapid commercialization of Supercritical Fluid Parts Cleaning (SFPC). PNL assembled a SFPC test stand to observe the relationship between the fluid dynamics of the system and the mass transfer of a contaminant from the surface of a contaminated metal coupon into the bulk fluid. The bench-scale test stand consists of a ``Berty`` autoclave modified for these tests and supporting hardware to achieve supercritical fluids parts cleaning. Three separate sets of tests were conducted using supercritical carbon dioxide. For the first two tests, a single stainless steel coupon was cleaned with organic solvents to remove surface residue, doped with a single contaminant, and then cleaned in the SFPC test stand. Contaminants studied were Dow Corning 200 fluid (dimethylpolysiloxane) and Castle/Sybron X-448 High-temperature Oil (a polybutane/mineral oil mixture). A set of 5-minute cleaning runs was conducted for each dopant at various autoclave impeller speeds. Test results from the first two sets of experiments indicate that precision cleaning for difficult-to-remove contaminants can be dramatically improved by introducing and increasing turbulence within the system. Metal coupons that had been previously doped with aircraft oil were used in a third set of tests. The coupons were placed in the SFPC test stand and subjected to different temperatures, pressures, and run times at a constant impeller speed. The cleanliness of each part was measured by Optically Stimulated Electron Emission. The third set of tests show that levels of cleanliness attained with supercritical carbon dioxide compare favorably with solvent and aqueous cleaning levels.

  15. Effects of fluid dynamics on cleaning efficacy of supercritical fluids

    SciTech Connect (OSTI)

    Phelps, M.R.; Willcox, W.A.; Silva, L.J.; Butner, R.S.

    1993-03-01

    Pacific Northwest Laboratory (PNL) and Boeing Aerospace Company are developing a process to clean metal parts using a supercritical solvent. This work is part of an effort to address issues inhibiting the rapid commercialization of Supercritical Fluid Parts Cleaning (SFPC). PNL assembled a SFPC test stand to observe the relationship between the fluid dynamics of the system and the mass transfer of a contaminant from the surface of a contaminated metal coupon into the bulk fluid. The bench-scale test stand consists of a Berty'' autoclave modified for these tests and supporting hardware to achieve supercritical fluids parts cleaning. Three separate sets of tests were conducted using supercritical carbon dioxide. For the first two tests, a single stainless steel coupon was cleaned with organic solvents to remove surface residue, doped with a single contaminant, and then cleaned in the SFPC test stand. Contaminants studied were Dow Corning 200 fluid (dimethylpolysiloxane) and Castle/Sybron X-448 High-temperature Oil (a polybutane/mineral oil mixture). A set of 5-minute cleaning runs was conducted for each dopant at various autoclave impeller speeds. Test results from the first two sets of experiments indicate that precision cleaning for difficult-to-remove contaminants can be dramatically improved by introducing and increasing turbulence within the system. Metal coupons that had been previously doped with aircraft oil were used in a third set of tests. The coupons were placed in the SFPC test stand and subjected to different temperatures, pressures, and run times at a constant impeller speed. The cleanliness of each part was measured by Optically Stimulated Electron Emission. The third set of tests show that levels of cleanliness attained with supercritical carbon dioxide compare favorably with solvent and aqueous cleaning levels.

  16. Iron aluminide weld overlay coatings for boiler tube protection in coal-fired low NOx boilers

    SciTech Connect (OSTI)

    Banovic, S.W.; DuPont, J.N.; Marder, A.R.

    1997-12-01

    Iron aluminide weld overlay coatings are currently being considered for enhanced sulfidation resistance in coal-fired low NO{sub x} boilers. The use of these materials is currently limited due to hydrogen cracking susceptibility, which generally increases with an increase in aluminum concentration of the deposit. The overall objective of this program is to attain an optimum aluminum content with good weldability and improved sulfidation resistance with respect to conventional materials presently in use. Research has been initiated using Gas Tungsten Arc Welding (GTAW) in order to achieve this end. Under different sets of GTAW parameters (wire feed speed, current), both single and multiple pass overlays were produced. Characterization of all weldments was conducted using light optical microscopy, scanning electron microscopy, and electron probe microanalysis. Resultant deposits exhibited a wide range of aluminum contents (5--43 wt%). It was found that the GTAW overlays with aluminum contents above {approximately}10 wt% resulted in cracked coatings. Preliminary corrosion experiments of 5 to 10 wt% Al cast alloys in relatively simple H{sub 2}/H{sub 2}S gas mixtures exhibited corrosion rates lower than 304 stainless steel.

  17. Supercritical Water Reactor Cycle for Medium Power Applications

    SciTech Connect (OSTI)

    BD Middleton; J Buongiorno

    2007-04-25

    Scoping studies for a power conversion system based on a direct-cycle supercritical water reactor have been conducted. The electric power range of interest is 5-30 MWe with a design point of 20 MWe. The overall design objective is to develop a system that has minimized physical size and performs satisfactorily over a broad range of operating conditions. The design constraints are as follows: Net cycle thermal efficiency {ge}20%; Steam turbine outlet quality {ge}90%; and Pumping power {le}2500 kW (at nominal conditions). Three basic cycle configurations were analyzed. Listed in order of increased plant complexity, they are: (1) Simple supercritical Rankine cycle; (2) All-supercritical Brayton cycle; and (3) Supercritical Rankine cycle with feedwater preheating. The sensitivity of these three configurations to various parameters, such as reactor exit temperature, reactor pressure, condenser pressure, etc., was assessed. The Thermoflex software package was used for this task. The results are as follows: (a) The simple supercritical Rankine cycle offers the greatest hardware simplification, but its high reactor temperature rise and reactor outlet temperature may pose serious problems from the viewpoint of thermal stresses, stability and materials in the core. (b) The all-supercritical Brayton cycle is not a contender, due to its poor thermal efficiency. (c) The supercritical Rankine cycle with feedwater preheating affords acceptable thermal efficiency with lower reactor temperature rise and outlet temperature. (d) The use of a moisture separator improves the performance of the supercritical Rankine cycle with feedwater preheating and allows for a further reduction of the reactor outlet temperature, thus it was selected for the next step. Preliminary engineering design of the supercritical Rankine cycle with feedwater preheating and moisture separation was performed. All major components including the turbine, feedwater heater, feedwater pump, condenser, condenser pump

  18. Update of operating experience of B and W IR-CFB coal-fired boilers

    SciTech Connect (OSTI)

    Belin, F.; Kavidass, S.; Maryamchik, M.; Walker, D.J.; Mandal, A.K.; Price, C.E.

    1999-07-01

    This paper updates the operating experience of two Babcock and Wilcox (B and W) coal-fired, internal recirculation circulating fluidized-bed (IR-CFB) boilers. The first boiler is located at Southern Illinois University (SIU) in Carbondale, Illinois, USA, and is designed for 35 MW{sub th} output for cogeneration application, utilizing high sulfur, low ash Illinois coal. The second boiler is located at Kanoria Chemicals and Industries in Renukoot, India, and is designed for 81 MW{sub th} output for captive power requirement, firing high ash, low sulfur coal. This boiler was supplied by Thermax B and W Ltd., a joint venture company of B and W and Thermax of India. The choice of CFB technology was based on its fuel flexibility, cost effectiveness and environmental benefits for solid fuels. Based on the broad experience in designing utility and industrial boilers for operation worldwide, B and W has developed a cost effective and compact atmospheric pressure IR-CFB boiler. The B and W IR-CFB boiler design is distinctive in its use of U-beam particle separators. Worldwide, B and W offers IF-CFB boilers up to 175 MW{sub th}, both reheat and non-reheat, and is pursuing units up to 350 MW{sub th}. This paper reviews the general description of each IR-CFB boiler, design and performance aspects, as well as overall operating experiences. The boiler availabilities including maintenance aspects and emissions data will be presented.

  19. Study of Supercritical Carbon Dioxide Power Cycle for Low Grade Heat Conversion

    SciTech Connect (OSTI)

    Vidhi, Rachana; Goswami, Yogi D.; Chen, Huijuan; Stefanakos, Elias; Kuravi, Sarada; Sabau, Adrian S

    2011-01-01

    Research on supercritical carbon dioxide power cycles has been mainly focused on high temperature applications, such as Brayton cycle in a nuclear power plant. This paper conducts a comprehensive study on the feasibility of a CO2-based supercritical power cycle for low-grade heat conversion. Energy and exergy analyses of the cycle were conducted to discuss the obstacles as well as the potentials of using supercritical carbon dioxide as the working fluid for supercritical Rankine cycle, Carbon dioxide has desirable qualities such as low critical temperature, stability, little environmental impact and low cost. However, the low critical temperature might be a disadvantage for the condensation process. Comparison between a carbon dioxide-based supercritical Rankine cycle and an organic fluid-based supercritical Rankine cycle showed that the former needs higher pressure to achieve the same efficiency and a heat recovery system is necessary to desuperheat the turbine exhaust and pre-heat the pressure charged liquid.

  20. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior; Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2005-03-31

    This is the nineteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Refurbished corrosion probes were installed at Plant Gavin and operated for approximately 1,300 hours. This quarterly report includes further results from the BYU catalyst characterization lab and the in-situ lab, and includes the first results from a model suitable for comprehensive simulation codes for describing catalyst performance. The SCR slipstream reactor at Plant Gadsden operated for approximately 100 hours during the quarter because of ash blockage in the inlet probe.

  1. Condensing economizers for small coal-fired boilers and furnaces

    SciTech Connect (OSTI)

    Butcher, T.A.; Litzke, W.

    1994-01-01

    Condensing economizers increase the thermal efficiency of boilers by recovering sensible and latent heat from exhaust gas. These economizers are currently being used commercially for this purpose in a wide range of applications. Performance is dependent upon application-specific factors affecting the utility of recovered heat. With the addition of a condensing economizer boiler efficiency improvements up to 10% are possible. Condensing economizers can also capture flue gas particulates. In this work, the potential use of condensing economizers for both efficiency improvement and control of particulate emissions from small, coal water slurry-fired boilers was evaluated. Analysis was done to predict heat transfer and particulate capture by mechanisms including: inertial impaction, interception, diffusion, thermophoretic forces, and condensation growth. Shell-and-tube geometries were considered with flue gas on the outside of Teflon-covered tubes. Experimental studies were done with both air- and water-cooled economizers refit to a small boiler. Two experimental arrangements were used including oil-firing with injection of flyash upstream of the economizer and direct coal water slurry firing. Firing rates ranged from 27 to 82 kW (92,000 to 280,000 Btu/hr). Inertial impaction was found to be the most important particulate capture mechanism and removal efficiencies to 95% were achieved. With the addition of water sprays directly on the first row of tubes, removal efficiencies increased to 98%. Use of these sprays adversely affects heat recovery. Primary benefits of the sprays are seen to be the addition of small impaction sites and future design improvements are suggested in which such small impactors are permanently added to the highest velocity regions of the economizer. Predicted effects of these added impactors on particulate removal and pressure drop are presented.

  2. Trash-fired boiler cuts plant's gas use 30%

    SciTech Connect (OSTI)

    Watson, F

    1983-06-27

    A Minneapolis bottling plant will burn trash in a 450-horsepower boiler/incinerator to reduce natural gas consumption 30% and eliminate the costs of hauling and disposing of trash. Combined with a CA1500 heat-recovery system installed in 1982, the project will have a two-year payback. The system is clean enough that even old tires can be burned and still meet air pollution regulations. (DCK)

  3. Method and apparatus for waste destruction using supercritical water oxidation

    DOE Patents [OSTI]

    Haroldsen, Brent Lowell; Wu, Benjamin Chiau-pin

    2000-01-01

    The invention relates to an improved apparatus and method for initiating and sustaining an oxidation reaction. A hazardous waste, is introduced into a reaction zone within a pressurized containment vessel. An oxidizer, preferably hydrogen peroxide, is mixed with a carrier fluid, preferably water, and the mixture is heated until the fluid achieves supercritical conditions of temperature and pressure. The heating means comprise cartridge heaters placed in closed-end tubes extending into the center region of the pressure vessel along the reactor longitudinal axis. A cooling jacket surrounds the pressure vessel to remove excess heat at the walls. Heating and cooling the fluid mixture in this manner creates a limited reaction zone near the center of the pressure vessel by establishing a steady state density gradient in the fluid mixture which gradually forces the fluid to circulate internally. This circulation allows the fluid mixture to oscillate between supercritical and subcritical states as it is heated and cooled.

  4. Operation and analysis of a supercritical CO2 Brayton cycle.

    SciTech Connect (OSTI)

    Wright, Steven Alan; Radel, Ross F.; Vernon, Milton E.; Pickard, Paul S.; Rochau, Gary Eugene

    2010-09-01

    Sandia National Laboratories is investigating advanced Brayton cycles using supercritical working fluids for use with solar, nuclear or fossil heat sources. The focus of this work has been on the supercritical CO{sub 2} cycle (S-CO2) which has the potential for high efficiency in the temperature range of interest for these heat sources, and is also very compact, with the potential for lower capital costs. The first step in the development of these advanced cycles was the construction of a small scale Brayton cycle loop, funded by the Laboratory Directed Research & Development program, to study the key issue of compression near the critical point of CO{sub 2}. This document outlines the design of the small scale loop, describes the major components, presents models of system performance, including losses, leakage, windage, compressor performance, and flow map predictions, and finally describes the experimental results that have been generated.

  5. Pulse radiolysis studies in supercritical CO{sub 2}

    SciTech Connect (OSTI)

    Jonah, C. D.; Dimitrijevic, N. M.; Bartels, D. M.; Takahashi, K.

    2000-03-09

    The pulse radiolysis technique has been applied to study reactions of ions in supercritical solutions. Evidence for the formation of C{sub 2}O{sub 4}{sup +} has been found in supercritical CO{sub 2}. The rate of the electron transfer reaction from dimethyl aniline to the C{sub 2}O{sub 4}{sup +} was measured over the density range of 0.17--0.7 g/cm{sup 3}. The reaction rate was measured to be close to diffusion-controlled at the lowest density; at higher densities, the rate was considerably below the apparent diffusion-controlled rate. Similar behavior was found for the reaction of the anion (presumably C{sub 2}O{sub 4}{sup {minus}}) with benzoquinone. The reaction of O{sub 2} with C{sub 2}O{sub 4}{sup +} was considerably slower than the expected diffusion-controlled rate.

  6. Mercury control challenge for industrial boiler MACT affected facilities

    SciTech Connect (OSTI)

    2009-09-15

    An industrial coal-fired boiler facility conducted a test program to evaluate the effectiveness of sorbent injection on mercury removal ahead of a fabric filter with an inlet flue gas temperature of 375{sup o}F. The results of the sorbent injection testing are essentially inconclusive relative to providing the facility with enough data upon which to base the design and implementation of permanent sorbent injection system(s). The mercury removal performance of the sorbents was significantly less than expected. The data suggests that 50 percent mercury removal across a baghouse with flue gas temperatures at or above 375{sup o}F and containing moderate levels of SO{sub 3} may be very difficult to achieve with activated carbon sorbent injection alone. The challenge many coal-fired industrial facilities may face is the implementation of additional measures beyond sorbent injection to achieve high levels of mercury removal that will likely be required by the upcoming new Industrial Boiler MACT rule. To counter the negative effects of high flue gas temperature on mercury removal with sorbents, it may be necessary to retrofit additional boiler heat transfer surface or spray cooling of the flue gas upstream of the baghouse. Furthermore, to counter the negative effect of moderate or high SO{sub 3} levels in the flue gas on mercury removal, it may be necessary to also inject sorbents, such as trona or hydrated lime, to reduce the SO{sub 3} concentrations in the flue gas. 2 refs., 1 tab.

  7. Synchrotron X-ray Studies of Super-critical Carbon Dioxide /...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Synchrotron X-ray Studies of Super-critical Carbon Dioxide Reservoir Rock Interfaces Project obectives: Utilize synchrotron X-ray measurements, to monitor all aspects of atomic ...

  8. Ultrasound enhanced process for extracting metal species in supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M.; Enokida, Youichi

    2006-10-31

    Improved methods for the extraction or dissolution of metals, metalloids or their oxides, especially lanthanides, actinides, uranium or their oxides, into supercritical solvents containing an extractant are disclosed. The disclosed embodiments specifically include enhancing the extraction or dissolution efficiency with ultrasound. The present methods allow the direct, efficient dissolution of UO2 or other uranium oxides without generating any waste stream or by-products.

  9. Conversion of hazardous materials using supercritical water oxidation

    DOE Patents [OSTI]

    Rofer, Cheryl K.; Buelow, Steven J.; Dyer, Richard B.; Wander, Joseph D.

    1992-01-01

    A process for destruction of hazardous materials in a medium of supercritical water without the addition of an oxidant material. The harzardous material is converted to simple compounds which are relatively benign or easily treatable to yield materials which can be discharged into the environment. Treatment agents may be added to the reactants in order to bind certain materials, such as chlorine, in the form of salts or to otherwise facilitate the destruction reactions.

  10. Supercritical carbon dioxide cycle control analysis.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. J.

    2011-04-11

    This report documents work carried out during FY 2008 on further investigation of control strategies for supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle energy converters. The main focus of the present work has been on investigation of the S-CO{sub 2} cycle control and behavior under conditions not covered by previous work. An important scenario which has not been previously calculated involves cycle operation for a Sodium-Cooled Fast Reactor (SFR) following a reactor scram event and the transition to the primary coolant natural circulation and decay heat removal. The Argonne National Laboratory (ANL) Plant Dynamics Code has been applied to investigate the dynamic behavior of the 96 MWe (250 MWt) Advanced Burner Test Reactor (ABTR) S-CO{sub 2} Brayton cycle following scram. The timescale for the primary sodium flowrate to coast down and the transition to natural circulation to occur was calculated with the SAS4A/SASSYS-1 computer code and found to be about 400 seconds. It is assumed that after this time, decay heat is removed by the normal ABTR shutdown heat removal system incorporating a dedicated shutdown heat removal S-CO{sub 2} pump and cooler. The ANL Plant Dynamics Code configured for the Small Secure Transportable Autonomous Reactor (SSTAR) Lead-Cooled Fast Reactor (LFR) was utilized to model the S-CO{sub 2} Brayton cycle with a decaying liquid metal coolant flow to the Pb-to-CO{sub 2} heat exchangers and temperatures reflecting the decaying core power and heat removal by the cycle. The results obtained in this manner are approximate but indicative of the cycle transient performance. The ANL Plant Dynamics Code calculations show that the S-CO{sub 2} cycle can operate for about 400 seconds following the reactor scram driven by the thermal energy stored in the reactor structures and coolant such that heat removal from the reactor exceeds the decay heat generation. Based on the results, requirements for the shutdown heat removal system may be defined

  11. Evaluation of Iron Aluminide Weld Overlays for Erosion-Corrosion Resistant Boiler Tube Coatings in Low NOx Boilers

    SciTech Connect (OSTI)

    Regina, J.R.

    2000-05-16

    Iron aluminide weld overlays containing ternary additions and thermal spray coatings are being investigated for corrosion protection of boiler tubes in Low NOx burners. The primary objective of the research is to identify overlay and thermal spray compositions that provide corrosion protection of waterwall boiler tubes. In the current phase of work, preliminary corrosion tests were conducted on a binary Fe-Al alloy in multiple complex gases to determine which gases will be used for testing of the ternary alloys. Preliminary solid-state corrosion tests were also conducted to simulate slag-metal interactions seen in Low NOx furnaces. Two powder compositions were chosen for testing of the ternary alloys. A matrix of alloys to be tested in both gaseous and solid-state corrosion experiments was produced based on corrosion literature.

  12. Supercritical Fluid Extraction of Plutonium and Americium from Soil

    SciTech Connect (OSTI)

    Fox, R.V.; Mincher, B.J.

    2002-05-23

    Supercritical fluid extraction (SFE) of plutonium and americium from soil was successfully demonstrated using supercritical fluid carbon dioxide solvent augmented with organophosphorus and beta-diketone complexants. Spiked Idaho soils were chemically and radiologically characterized, then extracted with supercritical fluid carbon dioxide at 2,900 psi and 65 C containing varying concentrations of tributyl phosphate (TBP) and thenoyltrifluoroacetone (TTA). A single 45 minute SFE with 2.7 mol% TBP and 3.2 mol% TTA provided as much as 88% {+-} 6.0 extraction of americium and 69% {+-} 5.0 extraction of plutonium. Use of 5.3 mol% TBP with 6.8 mol% of the more acidic beta-diketone hexafluoroacetylacetone (HFA) provided 95% {+-} 3.0 extraction of americium and 83% {+-} 5.0 extraction of plutonium in a single 45 minute SFE at 3,750 psi and 95 C. Sequential chemical extraction techniques were used to chemically characterize soil partitioning of plutonium and americium in pre-SFE soil samples. Sequential chemical extraction techniques demonstrated that spiked plutonium resides primarily (76.6%) in the sesquioxide fraction with minor amounts being absorbed by the oxidizable fraction (10.6%) and residual fractions (12.8%). Post-SFE soils subjected to sequential chemical extraction characterization demonstrated that 97% of the oxidizable, 78% of the sesquioxide and 80% of the residual plutonium could be removed using SFE. These preliminary results show that SFE may be an effective solvent extraction technique for removal of actinide contaminants from soil.

  13. Fluid dynamic effects on precision cleaning with supercritical fluids

    SciTech Connect (OSTI)

    Phelps, M.R.; Hogan, M.O.; Silva, L.J.

    1994-06-01

    Pacific Northwest Laboratory staff have assembled a small supercritical fluids parts cleaning test stand to characterize how system dynamics affect the efficacy of precision cleaning with supercritical carbon dioxide. A soiled stainless steel coupon, loaded into a ``Berty`` autoclave, was used to investigate how changes in system turbulence and solvent temperature influenced the removal of test dopants. A pulsed laser beam through a fiber optic was used to investigate real-time contaminant removal. Test data show that cleaning efficiency is a function of system agitation, solvent density, and temperature. These data also show that high levels of cleaning efficiency can generally be achieved with high levels of system agitation at relatively low solvent densities and temperatures. Agitation levels, temperatures, and densities needed for optimal cleaning are largely contaminant dependent. Using proper system conditions, the levels of cleanliness achieved with supercritical carbon dioxide compare favorably with conventional precision cleaning methods. Additional research is currently being conducted to generalize the relationship between cleaning performance and parameters such as contaminant solubilities, mass transfer rates, and solvent agitation. These correlations can be used to optimize cleaning performance, system design, and time and energy consumption for particular parts cleaning applications.

  14. Boiler Upgrades and Decentralizing Steam Systems Save Water and Energy at

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Naval Air Station Oceana | Department of Energy Boiler Upgrades and Decentralizing Steam Systems Save Water and Energy at Naval Air Station Oceana Boiler Upgrades and Decentralizing Steam Systems Save Water and Energy at Naval Air Station Oceana January 7, 2015 - 4:52pm Addthis Boiler Upgrades and Decentralizing Steam Systems Save Water and Energy at Naval Air Station Oceana Addthis Related Articles Building Science Corporation worked with Transformations, Inc., on a subdivision of

  15. Development and Demonstration of a Biomass Boiler for Food Processing Applications

    SciTech Connect (OSTI)

    2009-02-01

    Burns & McDonnell Engineering Company, in collaboration with Frito-Lay, Inc., Oak Ridge National Laboratory, CPL Systems, Inc., Alpha Boilers, and Kansas State University will demonstrate use of a biomass boiler in the food processing industry. The 60,000 lb/hr innovative biomass boiler system utilizing a combination of wood waste and tire-derived fuel (TDF) waste will offset all natural gas consumption at Frito-Lay's Topeka, Kansas, processing facility.

  16. 2015-02-13 Issuance: Test Procedure for Furnaces and Boilers; Notice of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proposed Rulemaking | Department of Energy 3 Issuance: Test Procedure for Furnaces and Boilers; Notice of Proposed Rulemaking 2015-02-13 Issuance: Test Procedure for Furnaces and Boilers; Notice of Proposed Rulemaking This document is a pre-publication Federal Register notice of proposed rulemaking regarding test procedures for furnaces and boilers, as issued by the Deputy Assistant Secretary for Energy Efficiency on February 13, 2015. Though it is not intended or expected, should any

  17. 2016-03-11 Commercial Packaged Boilers_NOPR | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3-11 Commercial Packaged Boilers_NOPR 2016-03-11 Commercial Packaged Boilers_NOPR Commercial Packaged Boilers NOPR (1.82 MB) More Documents & Publications ISSUANCE 2015-06-30: Energy Conservation Program: Energy Conservation Standards for Packaged Terminal Air Conditioners and Packaged Terminal Heat Pumps, Final Rule ISSUANCE 2014-12-23: Energy Conservation Program for Certain Industrial Equipment: Energy Conservation Standards and Test Procedures for Commercial Heating, Air-Conditioning,

  18. Guide to Combined Heat and Power Systems for Boiler Owners and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a CHP project and focuses on technical subjects associated with the integration of cogeneration technology into new and existing ICI boiler installations. chpboilersguide.pdf ...

  19. 2015-02-13 Issuance: Test Procedure for Furnaces and Boilers...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications 2015-12-29 Consumer Furnaces and Boilers Test Procedures Final Rule ISSUANCE 2014-12-23: Energy Conservation Program for Consumer Products: Test ...

  20. Biomass Boiler Market is Projected to Reach USD 8,907.0 Million...

    Open Energy Info (EERE)

    Naval SpA, Hurst Boiler & Welding Co, Inc., Jernforsen Energi System AB, Justsen Energiteknik AS, Kohlbach Group, LAMBION Energy Solutions GmbH, Leroux & Lotz Technologies,...

  1. Consider Installing Turbulators on Two- and Three-Pass Firetube Boilers

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on installing turbulators on firetube boilers provides how-to advice for improving the system using low-cost, proven practices and technologies.

  2. Upgrade Boilers with Energy-Efficient Burners - Steam Tip Sheet #24

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO steam tip sheet on upgrading boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  3. Characterization of the U.S. Industrial/Commercial Boiler Population...

    Broader source: Energy.gov (indexed) [DOE]

    Much of this energy is used in boilers to generate steam and hot water. This 2005 report ... characterizationindustrialcommericalboilerpopulation.pdf (878.7 KB) More Documents ...

  4. Consider Installing Turbulators on Two- and Three-Pass Firetube Boilers - Steam Tip Sheet #25

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO tip sheet on installing turbulators on firetube boilers provides how-to advice for improving the system using low-cost, proven practices and technologies.

  5. Consider Installing Turbulators on Two- and Three-Pass Firetube Boilers - Steam Tip Sheet #25

    SciTech Connect (OSTI)

    2006-01-01

    This revised AMO tip sheet on installing turbulators on firetube boilers provides how-to advice for improving the system using low-cost, proven practices and technologies.

  6. Building America Case Study: Advanced Boiler Load Monitoring Controllers, Chicago, Illinois (Fact Sheet)

    SciTech Connect (OSTI)

    PARR

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and in some cases return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential. PARR installed and monitored the performance of one type of ALM controller, the M2G from Greffen Systems, at multifamily sites in the city of Chicago and its suburb Cary, IL, both with existing OTR control. Results show that energy savings depend on the degree to which boilers are over-sized for their load, represented by cycling rates. Also savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, over-sized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less over-sized boilers at another site showed muted savings.

  7. Clean Firetube Boiler Waterside Heat Transfer Surfaces, Energy Tips: STEAM, Steam Tip Sheet #7 (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-04-01

    A steam energy tip sheet for the Advanced Manufacturing Office (AMO). The prevention of scale formation in firetube boilers can result in substantial energy savings. Scale deposits occur when calcium, magnesium, and silica, commonly found in most water supplies, react to form a continuous layer of material on the waterside of the boiler heat exchange tubes. Scale creates a problem because it typically possesses a thermal conductivity, an order of magnitude less than the corresponding value for bare steel. Even thin layers of scale serve as an effective insulator and retard heat transfer. The result is overheating of boiler tube metal, tube failures, and loss of energy efficiency. Fuel consumption may increase by up to 5% in firetube boilers because of scale. The boilers steam production may be reduced if the firing rate cannot be increased to compensate for the decrease in combustion efficiency. Energy losses as a function of scale thickness and composition are given. Any scale in a boiler is undesirable. The best way to deal with scale is not to let it form in the first place. Prevent scale formation by: (1) Pretreating of boiler makeup water (using water softeners, demineralizers, and reverse osmosis to remove scale-forming minerals); (2) Injecting chemicals into the boiler feedwater; and (3) Adopting proper boiler blowdown practices.

  8. Financial Incentives Available for Facilities Affected by the US EPA Boiler MACT Proposed Rule, December 2012

    Broader source: Energy.gov [DOE]

    Overview of incentives for which larger boilers and then CHP systems qualify; Federal incentive programs are discussed and state, utility and local‐level programs.

  9. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30

    This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected

  10. Superheater Corrosion In Biomass Boilers: Today's Science and Technology

    SciTech Connect (OSTI)

    Sharp, William

    2011-12-01

    This report broadens a previous review of published literature on corrosion of recovery boiler superheater tube materials to consider the performance of candidate materials at temperatures near the deposit melting temperature in advanced boilers firing coal, wood-based fuels, and waste materials as well as in gas turbine environments. Discussions of corrosion mechanisms focus on the reactions in fly ash deposits and combustion gases that can give corrosive materials access to the surface of a superheater tube. Setting the steam temperature of a biomass boiler is a compromise between wasting fuel energy, risking pluggage that will shut the unit down, and creating conditions that will cause rapid corrosion on the superheater tubes and replacement expenses. The most important corrosive species in biomass superheater corrosion are chlorine compounds and the most corrosion resistant alloys are typically FeCrNi alloys containing 20-28% Cr. Although most of these materials contain many other additional additions, there is no coherent theory of the alloying required to resist the combination of high temperature salt deposits and flue gases that are found in biomass boiler superheaters that may cause degradation of superheater tubes. After depletion of chromium by chromate formation or chromic acid volatilization exceeds a critical amount, the protective scale gives way to a thick layer of Fe{sub 2}O{sub 3} over an unprotective (FeCrNi){sub 3}O{sub 4} spinel. This oxide is not protective and can be penetrated by chlorine species that cause further acceleration of the corrosion rate by a mechanism called active oxidation. Active oxidation, cited as the cause of most biomass superheater corrosion under chloride ash deposits, does not occur in the absence of these alkali salts when the chloride is present as HCl gas. Although a deposit is more corrosive at temperatures where it is molten than at temperatures where it is frozen, increasing superheater tube temperatures through

  11. Energy Department Announces New Investments in Supercritical Transformational Electric Power (STEP) Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy’s Supercritical Transformational Electric Power (STEP) program is awarding a total of $3.9 million to three competitively-selected teams to develop conceptual plans to support the design, cost and schedule for a 10 MWe (megawatts electrical) Supercritical Carbon Dioxide (sCO2) Brayton Cycle test facility.

  12. Experimental study of elliptical jet from supercritical to subcritical conditions using planar laser induced fluorescence

    SciTech Connect (OSTI)

    Muthukumaran, C. K.; Vaidyanathan, Aravind

    2015-03-15

    The study of fluid jet dynamics at supercritical conditions involves strong coupling between fluid dynamic and thermodynamic phenomena. Beyond the critical point, the liquid-vapor coexistence ceases to exist, and the fluid exists as a single phase known as supercritical fluid with its properties that are entirely different from liquids and gases. At the critical point, the liquids do not possess surface tension and latent heat of evaporation. Around the critical point, the fluid undergoes large changes in density and possesses thermodynamic anomaly like enhancement in thermal conductivity and specific heat. In the present work, the transition of the supercritical and near-critical elliptical jet into subcritical as well as supercritical environment is investigated experimentally with nitrogen and helium as the surrounding environment. Under atmospheric condition, a liquid jet injected from the elliptical orifice exhibits axis switching phenomena. As the injection temperature increases, the axis switching length also increases. Beyond the critical temperature, the axis switching is not observed. The investigation also revealed that pressure plays a major role in determining the thermodynamic transition of the elliptical jet only for the case of supercritical jet injected into subcritical chamber conditions. At larger pressures, the supercritical jet undergoes disintegration and formation of droplets in the subcritical environment is observed. However, for supercritical jet injection into supercritical environment, the gas-gas like mixing behavior is observed.

  13. Thermal stability of acidic sulfates in kraft recovery boilers

    SciTech Connect (OSTI)

    Tran, H. ); Poon, W.; Barham, D. . Dept. of Chemical Engineering and Applied Chemistry)

    1994-05-01

    Acidic sulfates, such as NaHSO[sub 4] and Na[sub 2]S[sub 2]O[sub 7], are suspected in sticky deposit formation and tube corrosion in the generating bank and economizer regions of kraft recovery boilers. Their stability was examined in air, moist conditions, and in the presence of Na[sub 2]CO[sub 3] at various temperatures. The results showed that, in air, NaHSO[sub 4] melts and decomposes to solid Na[sub 2]S[sub 2]O[sub 7] and water vapor at about 180 C. Na[sub 2]S[sub 2]O[sub 7] is relatively stable up to its melting point of 380 C. Molten Na[sub 2]S[sub 2]O[sub 7] partially decomposes to solid Na[sub 2]SO[sub 4], which reacts with the remaining Na[sub 2]S[sub 2]O[sub 7] to form a newly identified compound, 3Na[sub 2]S[sub 2]O[sub 7][center dot]2Na[sub 2]SO[sub 4]; this compound melts at 570 C. Solid Na[sub 2]S[sub 2]O[sub 7] and its complex compounds react rapidly with H[sub 2]O vapor at 300 C to re-form liquid NaHSO[sub 4], which can be corrosive for the generating bank tubes during boiler operation. These acidic sulfates can coexist with Na[sub 2]CO[sub 3] below their respective melting points. They are hygroscopic, absorbing water from moist air to form sulfuric acid, which may cause tube wastage during boiler outages.

  14. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

    2003-12-31

    This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

  15. Ash formation, deposition, corrosion, and erosion in conventional boilers

    SciTech Connect (OSTI)

    Benson, S.A.; Jones, M.L.

    1995-12-01

    The inorganic components (ash-forming species) associated with coals significantly affect boiler design, efficiency of operation, and lifetimes of boiler parts. During combustion in conventional pulverized fuel boilers, the inorganic components are transformed into inorganic gases, liquids, and solids. This partitioning depends upon the association of the inorganic components in the coal and combustion conditions. The inorganic components are associated as mineral grains and as organically associated elements, and these associations of inorganic components in the fuel directly influence their fate upon combustion. Combustion conditions, such as temperature and atmosphere, influence the volatility and the interaction of inorganic components during combustion and gas cooling, which influences the state and size composition distribution of the particulate and condensed ash species. The intermediate species are transported with the bulk gas flow through the combustion systems, during which time the gases and entrained ash are cooled. Deposition, corrosion, and erosion occur when the ash intermediate species are transported to the heat-transfer surface, react with the surface, accumulate, sinter, and develop strength. Research over the past decade has significantly advanced understanding of ash formation, deposition, corrosion, and erosion mechanisms. Many of the advances in understanding and predicting ash-related issues can be attributed to advanced analytical methods to determine the inorganic composition of fuels and the resulting ash materials. These new analytical techniques have been the key to elucidation of the mechanisms of ash formation and deposition. This information has been used to develop algorithms and computer models to predict the effects of ash on combustion system performance.

  16. Concept selection for advanced low-emission coal fired boiler

    SciTech Connect (OSTI)

    Gorrell, R.L.; Rodgers, L.W.; Farthing, G.A.

    1993-12-31

    The Babcock & Wilcox Company (B&W), under contract to the US Department of Energy (DOE) with subcontract to Physical Sciences, Inc. (PSIT), the Massachusetts Institute of Technology (MIT) and United Engineers and Constructors (UE&C) has begun development of an advanced low-emission boiler system (LEBS). The initial phase of this multi-phase program required a thorough review and assessment of potential advanced technologies and techniques for control of combustion and flue gas emissions. Results of this assessment are presented in this paper.

  17. Standby cooling system for a fluidized bed boiler

    DOE Patents [OSTI]

    Crispin, Larry G.; Weitzel, Paul S.

    1990-01-01

    A system for protecting components including the heat exchangers of a fluidized bed boiler against thermal mismatch. The system includes an injection tank containing an emergency supply of heated and pressurized feedwater. A heater is associated with the injection tank to maintain the temperature of the feedwater in the tank at or about the same temperature as that of the feedwater in the heat exchangers. A pressurized gas is supplied to the injection tank to cause feedwater to flow from the injection tank to the heat exchangers during thermal mismatch.

  18. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

    2002-04-30

    This is the seventh Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. A series of field tests for RRI at the Ameren Sioux Unit No.1 have demonstrated that RRI can provide up to 30% NOx reduction over the use of over fire air in large scale (480MW) cyclone fired utility boilers. The field tests and modeling results are in good agreement. Final data analysis has been completed for tests performed at Eastlake Power Station of a real-time waterwall corrosion monitoring system. The tests demonstrated that corrosion could be measured accurately in real-time in normal boiler operations, and an assessment of waterwall wastage could be made without impacting boiler availability. Detailed measurements of soot volume fraction have been performed for a coal burner in a pilot scale test furnace. The measured values are in good agreement with the expected trends for soot generation and destruction. Catalysts from four commercial manufacturers have been ordered and one of the samples was received this quarter. Several in situ analyses of vanadium-based SCR catalyst systems were completed at BYU. Results to date indicate that the system produces results that represent improvements compared to literature examples of similar experiments. Construction of the catalyst characterization system (CCS) reactor is nearly complete, with a few remaining details discussed in this report. A literature review originally commissioned from other parties is being updated and will be made available under separate cover as part of this investigation. Fabrication of the multi-catalyst slipstream

  19. METHANE DE-NOX FOR UTILITY PC BOILERS

    SciTech Connect (OSTI)

    Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

    2001-10-30

    The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NO{sub x} emissions to 0.15 lb/million Btu or less without post-combustion flue gas cleaning. Work during the quarter included completion of the equipment fabrication and installation efforts for the 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Final selection of the first two test coals and preliminary selection of the final two test coals were also completed.

  20. METHANE DE-NOX FOR UTILITY PC BOILERS

    SciTech Connect (OSTI)

    Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

    2002-01-31

    The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NO{sub x} emissions to 0.15 lb/million Btu or less without post-combustion flue gas cleaning. Work during the quarter included completion of the equipment fabrication and installation efforts for the 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Selection and procurement of the first two test coals and preliminary selection of the final two test coals were completed. Shakedown and commissioning activities were finished and PC Preheat pilot scale tests commenced with PRB coal.

  1. Compliance testing of hot-water and steam boilers, Shaw Afb, South Carolina. Final report

    SciTech Connect (OSTI)

    Garrison, J.A.

    1989-02-01

    At the request of HQ TAC/DEEV, personnel of the USAFOEHL Air Quality Function conducted source testing of eighteen small hot water and steam boilers to determine stack-gas moisture content and velocity. The data obtained during the survey was necessary for boiler operating application.

  2. Effects of installing economizers in boilers used in space heating applications

    SciTech Connect (OSTI)

    Gonzalez, M.A.; Medina, M.A.; Schruben, D.L.

    1999-07-01

    This paper discusses how the performance of a boiler can be improved by adding an economizer to preheat the boiler's feedwater. An energy analysis was applied to a boiler and then to both a boiler and an economizer (water pre-heater) to evaluate the benefits of heat recovery. Exergy rates calculated for both the boiler and the economizer determined that the temperature of the stack gases had primary effects on the performance of a boiler. The results from this study showed that 57% of the heat rejected at the boiler's stack could be recovered by installing an economizer to preheat the feedwater. As a result, the average cost savings that would be realized for a 36,400 kg/h (80,000 lbm/h) boiler averages US$8 per hour. The cost savings to steam production averaged US$0.20 per 455 kg (1,000 lbm) of steam and the ration between the cost savings to stack temperature averaged $0.02 per C (1.8 F). For this case, the fuel and the cost savings realized from using an economizer were averaged at 3.8% and 3.7%, respectively. These results translated to total cost savings, for an eight-day period considered, of US$940.

  3. Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications. Task 4 - Testing in Alstom's 15 MWth Boiler Simulation Facility

    SciTech Connect (OSTI)

    Levasseur, Armand

    2014-04-30

    Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs; Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF); Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools; Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems; Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost; and, Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project is scheduled for completion by April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a matrix of

  4. Supercritical Fluid Extraction of Plutonium and Americium from Soil

    SciTech Connect (OSTI)

    Fox, Robert Vincent; Mincher, Bruce Jay

    2002-08-01

    Supercritical fluid extraction (SFE) of plutonium and americium from soil was successfully demonstrated using supercritical fluid carbon dioxide solvent augmented with organophosphorus and beta-diketone complexants. Spiked Idaho soils were chemically and radiologically characterized, then extracted with supercritical fluid carbon dioxide at 2,900 psi and 65°C containing varying concentrations of tributyl phosphate (TBP) and thenoyltrifluoroacetone (TTA). A single 45 minute SFE with 2.7 mol% TBP and 3.2 mol% TTA provided as much as 88% ± 6.0 extraction of americium and 69% ± 5.0 extraction of plutonium. Use of 5.3 mol% TBP with 6.8 mol% of the more acidic beta-diketone hexafluoroacetylacetone (HFA) provided 95% ± 3.0 extraction of americium and 83% ± 5.0 extraction of plutonium in a single 45 minute SFE at 3,750 psi and 95°C. Sequential chemical extraction techniques were used to chemically characterize soil partitioning of plutonium and americium in pre-SFE soil samples. Sequential chemical extraction techniques demonstrated that spiked plutonium resides primarily (76.6%) in the sesquioxide fraction with minor amounts being absorbed by the oxidizable fraction (10.6%) and residual fractions (12.8%). Post-SFE soils subjected to sequential chemical extraction characterization demonstrated that 97% of the oxidizable, 78% of the sesquioxide and 80% of the residual plutonium could be removed using SFE. These preliminary results show that SFE may be an effective solvent extraction technique for removal of actinide contaminants from soil.

  5. Chemical Functionalization of Nanostructured Materials Using Supercritical Reaction Media

    SciTech Connect (OSTI)

    Zemanian, Thomas S.; Fryxell, Glen E.; Liu, Jun; Mattigod, Shas V.; Shin, Yongsoon; Franz, James A.; Ustyugov, Oleksiy A.; Nie, Zimin

    2001-12-15

    There exists a need for durable and thin functional coatings to utilize the afforded surface area of highly porous ceramic materials. Deposition of silane-based Self Assembled Monolayers (SAMs) has thus far been limited to maximum coverages of 4-5 molecules/nm2 and long processing times (up to 2 weeks), due to the restricted internal geometry of the substrates. Results are presented for SAMs deposited on high surface area silica from supercritical fluids (SCFs). The SAMs so produced display unprecedented coverages, high monolayer integrity, and extremely low surface defect density. Moreover, the depositions and subsequent removal of reaction byproducts are complete in a matter of minutes rather than days. Nuclear Magnetic Resonance (NMR) spectra of the surface modified silica are presented, demonstrating the SAM integrity and evolution over time. Sorption of aqueous metal ions is demonstrated, and results are given demonstrating the broad pH stability of the deposited SAMs. A chemical explanation for the enhanced deposition is posited, and the kinetics of mass transport into and out of the nanostructured spaces are discussed.Related experiments using zeolite substrates show deposition of thiol-terminated silanes to internal surfaces of 6? microporous material. After oxidation of the thiol functional group size selective chemistry was demonstrated using the produced catalyst, proving the efficacy of the supercritical reaction medium for installing functional coatings inside pores of similar diameters to the chain length of the deposited molecule[]. Comparisons are made between the response of the different substrates to the supercritical fluid-based processing, and remarks on the utility of SCF based processing of nanostructured materials are presented.

  6. Sensing system for detection and control of deposition on pendant tubes in recovery and power boilers

    DOE Patents [OSTI]

    Kychakoff, George; Afromowitz, Martin A; Hugle, Richard E

    2005-06-21

    A system for detection and control of deposition on pendant tubes in recovery and power boilers includes one or more deposit monitoring sensors operating in infrared regions and about 4 or 8.7 microns and directly producing images of the interior of the boiler. An image pre-processing circuit (95) in which a 2-D image formed by the video data input is captured, and includes a low pass filter for performing noise filtering of said video input. An image segmentation module (105) for separating the image of the recovery boiler interior into background, pendant tubes, and deposition. An image-understanding unit (115) matches derived regions to a 3-D model of said boiler. It derives a 3-D structure the deposition on pendant tubes in the boiler and provides the information about deposits to the plant distributed control system (130) for more efficient operation of the plant pendant tube cleaning and operating systems.

  7. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers

    Broader source: Energy.gov [DOE]

    This fact sheet describes a supercritical carbon dioxide turbo-expander and heat exchangers project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by the Southwest Research Institute, is working to develop a megawatt-scale s-CO2 hot-gas turbo-expander optimized for the highly transient solar power plant profile. The team is also working to optimize novel printed circuit heat exchangers for s-CO2 applications to drastically reduce their manufacturing costs.

  8. Hydroetching of high surface area ceramics using moist supercritical fluids

    DOE Patents [OSTI]

    Fryxell, Glen; Zemanian, Thomas S.

    2004-11-02

    Aerogels having a high density of hydroxyl groups and a more uniform pore size with fewer bottlenecks are described. The aerogel is exposed to a mixture of a supercritical fluid and water, whereupon the aerogel forms a high density of hydroxyl groups. The process also relaxes the aerogel into a more open uniform internal structure, in a process referred to as hydroetching. The hydroetching process removes bottlenecks from the aerogels, and forms the hydrogels into more standard pore sizes while preserving their high surface area.

  9. Research, Development and Demonstration of Bio-Mass Boiler for Food Industry

    SciTech Connect (OSTI)

    Fisher, Steve; Knapp, David

    2012-07-01

    Frito-Lay is working to reduce carbon emissions from their manufacturing plants. As part of this effort, they invested in a biomass-fired boiler at the Topeka, Kansas, plant. Frito-Lay partnered with Burns & McDonnell Engineering, Inc. and CPL Systems, Inc., to design and construct a steam producing boiler using carbon neutral fuels such as wood wastes (e.g. tree bark), shipping pallets, and used rubber vehicle tires. The U.S. Department of Energy (DOE) joined with Frito-Lay, Burns & McDonnell, and CPL to analyze the reductions in carbon dioxide (CO2) emissions that result from use of biomass-fired boilers in the food manufacturing environment. DOE support provided for the data collection and analysis, and reporting necessary to evaluate boiler efficiencies and reductions in CO2 emissions. The Frito-Lay biomass-fired boiler has resulted in significant reductions in CO2 emissions from the Topeka production facility. The use of natural gas has been reduced by 400 to 420 million standard cubic feet per year with corresponding reductions of 24,000 to 25,000 tons of CO2. The boiler does require auxiliary functions, however, that are unnecessary for a gas-fired boiler. These include heavy motors and fans for moving fuel and firing the boiler, trucks and equipment for delivering the fuel and moving at the boiler plant, and chippers for preparing the fuel prior to delivery. Each of these operations requires the combustion of fossil fuels or electricity and has associated CO2 emissions. Even after accounting for each of these auxiliary processes, however, the biomass-fired boiler results in net emission reductions of 22,500 to 23,500 tons of CO2 per year.

  10. Gasoline Ultra Fuel Efficient Vehicle Program Update | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra Fuel Efficient Vehicle Program Update Gasoline Ultra Fuel Efficient Vehicle Program Update Discusses hardware and system development activities to achieve in-vehicle fuel economy and emissions performance improvements compared to a production baseline vehicle. deer12_confer.pdf (1.38 MB) More Documents & Publications Gasoline Ultra Fuel Efficient Vehicle Gasoline Ultra Fuel Efficient Vehicle Gasoline Ultra Fuel Efficient Vehicle

  11. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2003-06-30

    This is the twelfth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, a new effort was begun on the development of a corrosion management system for minimizing the impacts of low NOx combustion systems on waterwalls; a kickoff meeting was held at the host site, AEP's Gavin Plant, and work commenced on fabrication of the probes. FTIR experiments for SCR catalyst sulfation were finished at BYU and indicated no vanadium/vanadyl sulfate formation at reactor conditions. Improvements on the mass-spectrometer system at BYU have been made and work on the steady state reactor system shakedown neared completion. The slipstream reactor continued to operate at AEP's Rockport plant; at the end of the quarter, the catalysts had been exposed to flue gas for about 1000 hours. Some operational problems were addressed that enable the reactor to run without excessive downtime by the end of the quarter.

  12. Circulating fluidized-bed boiler makes inroads for waste recycling

    SciTech Connect (OSTI)

    1995-09-01

    Circulating fluidized-bed (CFB) boilers have ben used for years in Scandinavia to burn refuse-derived fuel (RDF). Now, Foster Wheeler Power Systems, Inc., (Clinton, N.J.) is bringing the technology to the US. Touted as the world`s largest waste-to-energy plant to use CFB technology, the Robbins (III.) Resource Recovery Facility will have the capacity to process 1,600 tons/d of municipal solid waste (MSW) when it begins operation in early 1997. The facility will have two materials-separation and RDF-processing trains, each with dual trommel screens, magnetic and eddy current separators, and shredders. About 25% of the incoming MSW will be sorted and removed for recycling, while 75% of it will be turned into fuel, with a heat value of roughly 6,170 btu/lb. Once burned in the twin CFB boilers the resulting steam will be routed through a single turbine generator to produce 50,000 mW of electric power.

  13. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior; Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-12-31

    This is the eighteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Safety equipment for ammonia for the SCR slipstream reactor at Plant Gadsden was installed. The slipstream reactor was started and operated for about 1400 hours during the last performance period. Laboratory analysis of exposed catalyst and investigations of the sulfation of fresh catalyst continued at BYU. Thicker end-caps for the ECN probes were designed and fabricated to prevent the warpage and failure that occurred at Gavin with the previous design. A refurbished ECN probe was successfully tested at the University of Utah combustion laboratory. Improvements were implemented to the software that controls the flow of cooling air to the ECN probes.

  14. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-09-30

    This is the seventeenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. The SCR slipstream reactor was assembled and installed at Plant Gadsden this quarter. Safety equipment for ammonia had not been installed at the end of the quarter, but will be installed at the beginning of next quarter. The reactor will be started up next quarter. Four ECN corrosion probes were reinstalled at Gavin and collected corrosion data for approximately one month. Two additional probes were installed and removed after about 30 hours for future profilometry analysis. Preliminary analysis of the ECN probes, the KEMA coupons and the CFD modeling results all agree with the ultrasonic tube test measurements gathered by AEP personnel.

  15. Two Novel Ultra-Incompressible Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Two Novel Ultra-Incompressible Materials Print Some current challenges in aerospace engineering and fissionfusion applications require materials that are mechanically and...

  16. Coupled modeling of a directly heated tubular solar receiver for supercritical carbon dioxide Brayton cycle: Structural and creep-fatigue evaluation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ortega, Jesus; Khivsara, Sagar; Christian, Joshua; Ho, Clifford; Dutta, Pradip

    2016-06-06

    A supercritical carbon dioxide (sCO2) Brayton cycle is an emerging high energy-density cycle undergoing extensive research due to the appealing thermo-physical properties of sCO2 and single phase operation. Development of a solar receiver capable of delivering sCO2 at 20 MPa and 700 °C is required for implementation of the high efficiency (~50%) solar powered sCO2 Brayton cycle. In this work, extensive candidate materials are review along with tube size optimization using the ASME Boiler and Pressure Vessel Code. Moreover, temperature and pressure distribution obtained from the thermal-fluid modeling (presented in a complementary publication) are used to evaluate the thermal andmore » mechanical stresses along with detailed creep-fatigue analysis of the tubes. For resulting body stresses were used to approximate the lifetime performance of the receiver tubes. A cyclic loading analysis is performed by coupling the Strain-Life approach and the Larson-Miller creep model. The structural integrity of the receiver was examined and it was found that the stresses can be withstood by specific tubes, determined by a parametric geometric analysis. The creep-fatigue analysis display the damage accumulation due to cycling and the permanent deformation on the tubes showed that the tubes can operate for the full lifetime of the receiver.« less

  17. Operation and performance of the Supercritical Fluids Reactor (SFR)

    SciTech Connect (OSTI)

    Hanush, R.G.; Rice, S.F.; Hunter, T.B.; Aiken, J.D.

    1995-11-01

    The Supercritical Fluids Reactor (SFR) at Sandia National Laboratories, CA has been developed to examine and solve engineering, process, and fundamental chemistry issues regarding the development of supercritical water oxidation (SCWO). This report details the experimental apparatus, procedures, analytical methods used in these experiments, and performance characteristics of the reactor. The apparatus consists of pressurization, feed, preheat, reactor, cool down, and separation subsystems with ancillary control and data acquisition hardware and software. Its operating range is from 375 - 650{degrees} at 3250 - 6300 psi with resident times from 0.09 to 250 seconds. Procedures required for experimental operations are described. They include maintenance procedures conducted between experiments, optical alignment for acquisition of spectroscopic data, setup of the experiment, reactor start up, experimental operations, and shutdown of apparatus. Analytical methods used are Total Organic Carbon analysis, Gas Chromatography, ion probes, pH probes, turbidity measurements and in situ Raman spectroscopy. Experiments conducted that verify the accuracy of measurement and sampling methods are described.

  18. Transpiring wall supercritical water oxidation reactor salt deposition studies

    SciTech Connect (OSTI)

    Haroldsen, B.L.; Mills, B.E.; Ariizumi, D.Y.; Brown, B.G.

    1996-09-01

    Sandia National Laboratories has teamed with Foster Wheeler Development Corp. and GenCorp, Aerojet to develop and evaluate a new supercritical water oxidation reactor design using a transpiring wall liner. In the design, pure water is injected through small pores in the liner wall to form a protective boundary layer that inhibits salt deposition and corrosion, effects that interfere with system performance. The concept was tested at Sandia on a laboratory-scale transpiring wall reactor that is a 1/4 scale model of a prototype plant being designed for the Army to destroy colored smoke and dye at Pine Bluff Arsenal in Arkansas. During the tests, a single-phase pressurized solution of sodium sulfate (Na{sub 2}SO{sub 4}) was heated to supercritical conditions, causing the salt to precipitate out as a fine solid. On-line diagnostics and post-test observation allowed us to characterize reactor performance at different flow and temperature conditions. Tests with and without the protective boundary layer demonstrated that wall transpiration provides significant protection against salt deposition. Confirmation tests were run with one of the dyes that will be processed in the Pine Bluff facility. The experimental techniques, results, and conclusions are discussed.

  19. Anaerobic fermentation of woody biomass pretreated with supercritical ammonia

    SciTech Connect (OSTI)

    Weimer, P.J.; Chou, Y.C.T.

    1986-10-01

    The degradability of ground hardwood by thermophilic anaerobic bacteria (Clostridium thermocellum with or without Thermoanaerobacter strain B6A) was greatly enhanced by pretreatment of the substrate with supercritical ammonia. Relative to C. thermocellum monocultures, cocultures of C. thermocellum and Thermoanaerobacter strain B6A degraded 1.5-fold more pretreated soft maple but produced 2- 5-fold more fermentation end products because Thermoanaerobacter sp. removed reducing sugars produced by C. thermocellum during the fermentation. Dry weight losses were not totally accounted for in end products, due to formation of partially degraded material (<0.4 ..mu..m diameter wood particles) during the fermentation. One pretreated hardwood, Southern red oak, was fermented poorly because it released soluble inhibitors at the 60/sup 0/C incubation temperature. Considerable (6- to 11-fold) increases in substrate degradability were also noted for supercritical ammonia-pretreated wood materials fermented in an in vitro rumen digestibility assay. Degradation of pretreated softwoods by either thermophilic or mesophilic fermentation was not measurable under the conditions tested.

  20. ISSUANCE 2016-02-22: Energy Conservation Program for Certain Commercial and Industrial Equipment: Test Procedures for Commercial Packaged Boilers, Notice of Proposed Rulemaking

    Office of Energy Efficiency and Renewable Energy (EERE)

    Energy Conservation Program for Certain Commercial and Industrial Equipment: Test Procedures for Commercial Packaged Boilers

  1. ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND RECOMMENDATIONS 2014 ULTRA-DEEPWATER ADVISORY COMMITTEE COMMITTEE FINDINGS AND RECOMMENDATIONS i Table of Contents Research and Development Program Committee ............................................ 1 Sunset Committee .................................................................................................. 5 Advisory Committee Members ........................................................................... 7 ULTRA-DEEPWATER

  2. Overview and status of first 25 MW(e) IR-CFB boiler in India

    SciTech Connect (OSTI)

    Kavidass, S.; Bakshi, V.K.; Diwakar, K.K.

    1997-12-31

    The Babcock and Wilcox (B and W) internal recirculation CFB (IR-CFB) boiler is unique in design. Worldwide, B and W offers IR-CFB boilers up to 150 MW(e) both reheat and non-reheat, and is pursuing units up to 300 MW(e). This paper discusses an overview and status of the construction, commissioning, initial start-up operation and milestones of the ongoing 25 MW(e) IR-CFB boiler project at Kanoria Chemicals and Industries Ltd., Renukoot, India. This IR-CFB boiler is designed, supplied and installed by Thermax Babcock and Wilcox Ltd. (TBW), a joint venture company of the B and W and Thermax in India. The boiler parameters are, steam flow of 29.2 kg/s (23,420 lbs/hr), 6.4 MPa (925 psig), and 485 C (905 F) with feedwater temperature of 180 C (356 F). The boiler will utilize high-ash content (> 45%), subbituminous coal with a heating value of 3,500 KCal/kg (6,300 Btu/lb). This paper also discusses the various aspects of the boiler design, performance, auxiliary equipment, advantages and initial start-up operating performance.

  3. Techno-economic analysis of wood biomass boilers for the greenhouse industry

    SciTech Connect (OSTI)

    Chau, J.; Sowlati, T.; Sokhansanj, Shahabaddine; Bi, X.T.; Preto, F.; Melin, Staffan

    2009-01-01

    The objective of this study is to perform a techno-economic analysis on a typical wood pellet and wood residue boiler for generation of heat to an average-sized greenhouse in British Columbia. The variables analyzed included greenhouse size and structure, boiler efficiency, fuel types, and source of carbon dioxide (CO2) for crop fertilization. The net present value (NPV) show that installing a wood pellet or a wood residue boiler to provide 40% of the annual heat demand is more economical than using a natural gas boiler to provide all the heat at a discount rate of 10%. For an assumed lifespan of 25 years, a wood pellet boiler system could generate NPV of C$259,311 without electrostatic precipitator (ESP) and C$74,695 with ESP, respectively. While, installing a wood residue boiler with or without an ESP could provide NPV of C$919,922 or C$1,104,538, respectively. Using a wood biomass boiler could also eliminate over 3000 tonne CO2 equivalents of greenhouse gases annually. Wood biomass combustion generates more particulate matters than natural gas combustion. However, an advanced emission control system could significantly reduce particulate matters emission from wood biomass combustion which would bring the particulate emission to a relatively similar level as for natural gas.

  4. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Pisupati, S.V.; Poe, R.L.; Morrison, J.L.; Xie, J.; Walsh, P.M.; Wincek, R.T.; Clark, D.A.; Scaroni, A.W.

    1993-04-21

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the capability of effectively firing SCCWS in an industrial boiler designed for heavy fuel oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with 3.0 wt.% ash and 0.9 wt.% sulfur) can effectively be burned in a heavy fuel oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) program expansion (additional 1,000 hours of testing). The boiler testing wig determine if the SCCWS combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion limits, and fuel transport, storage, and handling characteristics can be accommodated in an oil-designed boiler system. In addition, the proof-of-concept demonstration will generate data to determine how the properties of SCCWS and its parent coal affect boiler performance. Economic factors associated with retrofitting boilers will be identified

  5. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Pisupati, S.V.; Poe, R.L.; Morrison, J.L.; Xie, J.; Walsh, P.M.; Shamanna, S.; Schobert, H.H.; Scaroni, A.W.

    1992-10-13

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the capability of effectively firing SCCWS in an industrial boiler designed for oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with 3.0 wt.% ash and 0.9 wt.% sulfur) can effectively be burned in an oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) program expansion (additional 1,000 hours of testing). The boiler testing will determine if the SCCWS combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion limits, and fuel transport, storage, and handling characteristics can be accommodated in an oil-designed boiler system. In addition, the proof-of-concept demonstration will generate data to determine how the properties of SCCWS and its parent coal affect boiler performance. Economic factors associated with retrofitting and operating boilers will be identified to assess the viability of future oil-to-coal retrofits.

  6. Impact of cycle chemistry on fossil-fueled high pressure boilers - BHEL approach and experience

    SciTech Connect (OSTI)

    Somu, M.; Gourishankar, S.

    1995-01-01

    Cycle chemistry in high pressure boilers plays an important role as far as availability and reliability of the boilers are concerned. Up keep of proper cycle chemistry is a stupendous task and care must be taken, right from design stage to commissioning and operation of the boilers. It calls for selection of proper design, method of manufacture of critical components and practicing proper procedures during commissioning and regular operation of boilers. Control of cycle chemistry is important from the view point of proper quality of steam and prevention of corrosion. The corrosion is like a double edged knife which reduces the boiler availability on one side and steam quality on the other. The steam quality dictates the efficiency of the turbine. Apart from the internal and external Water Treatment practices, selection of proper deaerator, sizing of drum, steam loading, selection of appropriate drum internals etc. help achieve the desired cycle chemistry. The impact of such cycle chemistry, selection of equipment, Water Treatment practice and operational practices are presented in this paper, in the back drop of BHEL`s design, fabrication and operational guidelines and experience on high pressure boilers. The critical components in the pre-boiler circuit as well as in the main circuit are assessed from the point of view of appropriate water chemistry parameters.

  7. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Schobert, H.H.

    1990-09-28

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program with the objective of demonstrating the capability of effectively firing SCCWS in industrial boilers designed for oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with less than 3.0% ash and 0.9% sulfur) can effectively be burned in oil-designed industrial boilers without adverse impact on boiler rating, maintainability, reliability and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of three phases: (1) design, permitting, and test planning, (2) construction and start up, and (3) demonstration and evaluation. The boiler testing will determine if the SCCWS combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion limits, and fuel transport, storage, and handling characteristics can be accommodated in an oil-designed boiler system. In addition, the proof-of-concept demonstration will generate data to determine how the properties of SCCWS and its parent coal affect boiler performance. Economic factors associated with retrofitting and operating boilers will be identified to assess the viability of future oil-to-coal retrofits. Progress is reported. 7 refs., 7 figs., 1 tab.

  8. Ultra high vacuum seal arrangement

    DOE Patents [OSTI]

    Flaherty, Robert

    1981-01-01

    Arrangement for demountably sealing two concentric metallic tubes in an ultra high vacuum system which facilitates remote actuation. A tubular seal includes integral spaced lips which circumferentially engage the metallic tubes. The lips plastically deform the metallic tubes by mechanical forces resulting from a martensite to austenite transformation of the tubular seal upon application of a predetermined temperature. The sealing force is released upon application of another temperature which causes a transformation from the stronger austenite to the weaker martensite. Use of a dual acting sealing ring and driving ring circumferentially contacting the sealing ring is particularly applicable to sealing larger diameter concentric metallic members.

  9. Ultra-short pulse generator

    DOE Patents [OSTI]

    McEwan, T.E.

    1993-12-28

    An inexpensive pulse generating circuit is disclosed that generates ultra-short, 200 picosecond, and high voltage 100 kW, pulses suitable for wideband radar and other wideband applications. The circuit implements a nonlinear transmission line with series inductors and variable capacitors coupled to ground made from reverse biased diodes to sharpen and increase the amplitude of a high-voltage power MOSFET driver input pulse until it causes non-destructive transit time breakdown in a final avalanche shock wave diode, which increases and sharpens the pulse even more. 5 figures.

  10. Microgap ultra-violet detector

    DOE Patents [OSTI]

    Wuest, Craig R.; Bionta, Richard M.

    1994-01-01

    A microgap ultra-violet detector of photons with wavelengths less than 400 run (4000 Angstroms) which comprises an anode and a cathode separated by a gas-filled gap and having an electric field placed across the gap. Either the anode or the cathode is semi-transparent to UV light. Upon a UV photon striking the cathode an electron is expelled and accelerated across the gap by the electric field causing interactions with other electrons to create an electron avalanche which contacts the anode. The electron avalanche is detected and converted to an output pulse.

  11. Microgap ultra-violet detector

    DOE Patents [OSTI]

    Wuest, C.R.; Bionta, R.M.

    1994-09-20

    A microgap ultra-violet detector of photons with wavelengths less than 400 run (4,000 Angstroms) which comprises an anode and a cathode separated by a gas-filled gap and having an electric field placed across the gap is disclosed. Either the anode or the cathode is semi-transparent to UV light. Upon a UV photon striking the cathode an electron is expelled and accelerated across the gap by the electric field causing interactions with other electrons to create an electron avalanche which contacts the anode. The electron avalanche is detected and converted to an output pulse. 2 figs.

  12. Ultra-short pulse generator

    DOE Patents [OSTI]

    McEwan, Thomas E. (Livermore, CA)

    1993-01-01

    An inexpensive pulse generating circuit is disclosed that generates ultra-short, 200 picosecond, and high voltage 100 kW, pulses suitable for wideband radar and other wideband applications. The circuit implements a nonlinear transmission line with series inductors and variable capacitors coupled to ground made from reverse biased diodes to sharpen and increase the amplitude of a high-voltage power MOSFET driver input pulse until it causes non-destructive transit time breakdown in a final avalanche shockwave diode, which increases and sharpens the pulse even more.

  13. Composite tube cracking in kraft recovery boilers: A state-of-the-art review

    SciTech Connect (OSTI)

    Singbeil, D.L.; Prescott, R.; Keiser, J.R.; Swindeman, R.W.

    1997-07-01

    Beginning in the mid-1960s, increasing energy costs in Finland and Sweden made energy recovery more critical to the cost-effective operation of a kraft pulp mill. Boiler designers responded to this need by raising the steam operating pressure, but almost immediately the wall tubes in these new boilers began to corrode rapidly. Test panels installed in the walls of the most severely corroding boiler identified austenitic stainless steel as sufficiently resistant to the new corrosive conditions, and discussions with Sandvik AB, a Swedish tube manufacturer, led to the suggestion that coextruded tubes be used for water wall service in kraft recovery boilers. Replacement of carbon steel by coextruded tubes has solved most of the corrosion problems experienced by carbon steel wall tubes, however, these tubes have not been problem-free. Beginning in early 1995, a multidisciplinary research program funded by the US Department of Energy was established to investigate the cause of cracking in coextruded tubes and to develop improved materials for use in water walls and floors of kraft recovery boilers. One portion of that program, a state-of-the-art review of public- and private-domain documents related to coextruded tube cracking in kraft recovery boilers is reported here. Sources of information that were consulted for this review include the following: tube manufacturers, boiler manufacturers, public-domain literature, companies operating kraft recovery boilers, consultants and failure analysis laboratories, and failure analyses conducted specifically for this project. Much of the information contained in this report involves cracking problems experienced in recovery boiler floors and those aspects of spout and air-port-opening cracking not readily attributable to thermal fatigue. 61 refs.

  14. Ultra Low Density Amorphous Shape Memory polymer Foams. (Conference...

    Office of Scientific and Technical Information (OSTI)

    Ultra Low Density Amorphous Shape Memory polymer Foams. Citation Details In-Document Search Title: Ultra Low Density Amorphous Shape Memory polymer Foams. You are accessing a ...

  15. Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum...

    Office of Environmental Management (EM)

    Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources Program Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources Program The ...

  16. Ultra-Deepwater Advisory Committee Members | Department of Energy

    Energy Savers [EERE]

    Ultra-Deepwater Advisory Committee Members 2013-2014 Ultra-Deepwater Advisory Committee Members Dr. George A. Cooper* Professor University of California, Berkeley Dr. Quenton R. ...

  17. Ultra Efficient Combined Heat, Hydrogen, and Power System - Fact...

    Energy Savers [EERE]

    Ultra Efficient Combined Heat, Hydrogen, and Power System - Fact Sheet, 2015 Ultra Efficient Combined Heat, Hydrogen, and Power System - Fact Sheet, 2015 FuelCell Energy, Inc., in ...

  18. Ultra Clean and Efficient Natural Gas Reciprocating Engine for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra Clean and Efficient Natural Gas Reciprocating Engine for CHP - Presentation by Dresser Waukesha, June 2011 Ultra Clean and Efficient Natural Gas Reciprocating Engine for CHP ...

  19. Development of a Low Cost Ultra Specular Advanced Polymer Film...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Cost Ultra Specular Advanced Polymer Film Solar Reflector Development of a Low Cost Ultra Specular Advanced Polymer Film Solar Reflector This presentation was delivered at the ...

  20. Ultra-High Resolution Electron Microscopy for Catalyst Characterizatio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    pm029allard2010p.pdf More Documents & Publications Ultra-High Resolution Electron Microscopy for Catalyst Characterization Ultra-high Resolution Electron Microscopy for Catalyst...

  1. Ultra-cold neutron fundamental physics experiments at LANSCE...

    Office of Scientific and Technical Information (OSTI)

    Ultra-cold neutron fundamental physics experiments at LANSCE Citation Details In-Document Search Title: Ultra-cold neutron fundamental physics experiments at LANSCE Authors: Saunders, ...

  2. Boiler heat transfer modeling using CEMS data with application to fouling analysis

    SciTech Connect (OSTI)

    Zibas, S.J.; Idem, S.A.

    1996-12-31

    A mathematical boiler heat transfer simulation for coal-fired plants is described. Required model input includes boiler geometry, fuel composition, and limited CEMS data that are typically available. Radiation heat transfer in the furnace is calculated using curve-fits to the Hottel charts. The model employs empirical heat transfer coefficient correlations to evaluate convection heat transfer to various boiler component surfaces. Fouling/slagging can be accounted for by including fouling resistance in the calculation of the overall heat transfer coefficient of each component. Model performance predictions are compared to cases available in the literature. Results from parametric studies are presented.

  3. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Morrison, J.L.; Xie, Jiangyang; Walsh, P.M.; Schobert, H.H.; Scaroni, A.W.

    1991-10-01

    Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program with the objective of determining the capability of effectively firing SCCWS in an industrial boiler designed for oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with less that 3.0% ash and 0.9% sulfur) can effectively be burned in an oil-designed industrial boiler without adverse impact on boiler rating maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels.

  4. Recovery Act: Oxy-Combustion Techology Development for Industrial-Scale Boiler Applications

    SciTech Connect (OSTI)

    Levasseur, Armand

    2014-04-30

    Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: • Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs. • Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF). • Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools. • Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems. • Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost. • Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project completion date was April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a

  5. Task 2: Materials for Advanced Boiler and Oxy-combustion Systems

    SciTech Connect (OSTI)

    Holcolm, Gordon R.; McGhee, Barry

    2009-05-01

    The PowerPoint presentation provides an overview of the tasks for the project: Characterize advanced boiler (oxy-fuel combustion, biomass co-fired) gas compositions and ash deposits; Generate critical data on the effects of environmental conditions; develop a unified test method with a view to future standardization; Generate critical data for coating systems for use in advanced boiler systems; Generate critical data for flue gas recycle piping materials for oxy-fuel systems; and, Compile materials performance data from laboratory and pilot plant exposures of candidate alloys for use in advanced boiler systems.

  6. Ultra Low Sulfur Home Heating Oil Demonstration Project

    SciTech Connect (OSTI)

    Batey, John E.; McDonald, Roger

    2015-09-30

    This Ultra Low Sulfur (ULS) Home Heating Oil Demonstration Project was funded by the New York State Energy Research and Development Authority (NYSERDA) and has successfully quantified the environmental and economic benefits of switching to ULS (15 PPM sulfur) heating oil. It advances a prior field study of Low Sulfur (500 ppm sulfur) heating oil funded by NYSERDA and laboratory research conducted by Brookhaven National Laboratory (BNL) and Canadian researchers. The sulfur oxide and particulate matter (PM) emissions are greatly reduced as are boiler cleaning costs through extending cleaning intervals. Both the sulfur oxide and PM emission rates are directly related to the fuel oil sulfur content. The sulfur oxide and PM emission rates approach near-zero levels by switching heating equipment to ULS fuel oil, and these emissions become comparable to heating equipment fired by natural gas. This demonstration project included an in-depth review and analysis of service records for both the ULS and control groups to determine any difference in the service needs for the two groups. The detailed service records for both groups were collected and analyzed and the results were entered into two spreadsheets that enabled a quantitative side-by-side comparison of equipment service for the entire duration of the ULS test project. The service frequency for the ULS and control group were very similar and did indicate increased service frequency for the ULS group. In fact, the service frequency with the ULS group was slightly less (7.5 percent) than the control group. The only exception was that three burner fuel pump required replacement for the ULS group and none were required for the control group.

  7. Effect of chlorine on furnace wall corrosion in utility boilers

    SciTech Connect (OSTI)

    Kung, S.C.; Daniel, P.L.; Seeley, R.R.

    1996-08-01

    The corrosion resistance of several commercial alloys was investigated in laboratory retort tests under a reducing/sulfidizing mixed gas at 700 and 900 F (371 and 482 C) for 1,000 hours. The test conditions were designed to simulate the corrosion of furnace walls in the combustion zone of utility boilers burning sulfur/chlorine-bearing coal substoichiometrically. Corrosion rates of these alloys were determined and compared to those obtained from a previous study in which the same alloys were evaluated under chlorine-free substoichiometric combustion environments. Results of the two studies reveal that the presence of chlorine in the reducing/sulfidizing mixed gas has a negligible effect on the corrosion behavior of these alloys in this gas at 700 F (371 C), whereas a beneficial effect was observed at 900 F (482 C). The beneficial effect implies that the presence of HCl may impede the sulfidation attack by H{sub 2}S under certain substoichiometric combustion environments.

  8. Novel Surface Modification Method for Ultrasupercritical Coal-Fired Boilers

    SciTech Connect (OSTI)

    Xiao, T. Danny

    2013-05-22

    US Department of Energy seeks an innovative coating technology for energy production to reduce the emission of SOx, NOx, and CO2 toxic gaseous species. To realize this need, Inframat Corporation (â??IMCâ?) proposed an SPS thermal spray coating technique to produce ultrafine/nanocoatings that can be deposited onto the surfaces of high temperature boiler tubes, so that higher temperatures of boiler operation becomes possible, leading to significantly reduced emission of toxic gaseous species. It should be noted that the original PI was Dr. Xinqing Ma, who after 1.5 year conducting this project left Inframat in December, 2008. Thus, the PI was transferred to Dr. Danny Xiao, who originally co-authored the proposal with Dr. Ma, in order to carry the project into a completion. Phase II Objectives: The proposed technology has the following attributes, including: (1). Dispersion of a nanoparticle or alloyed particle in a solvent to form a uniform slurry feedstock; (2). Feeding of the slurry feedstock into a thermal spray flame, followed by deposition of the slurry feedstock onto substrates to form tenacious nanocoatings; (3). High coating performance: including high bonding strength, and high temperature service life in the temperature range of 760oC/1400oF. Following the above premises, our past Phase I project has demonstrated the feasibility in small scale coatings on boiler substrates. The objective of this Phase II project was to focus on scale-up the already demonstrated Phase I work for the fabrication of SPS coatings that can satisfy DOEâ??s emission reduction goals for energy production operations. Specifically, they are: (1). Solving engineering problems to scale-up the SPS-HVOF delivery system to a prototype production sub-delivery system; (2). Produce ultrafine/nanocoatings using the scale-up prototype system; (3). Demonstrate the coated components using the scale-up device having superior properties. Proposed Phase II Tasks: In the original Phase II

  9. Design and development for a low emission boiler system

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    The Department of Energy initiated the Combustion 2000 program to develop the next generation of coal-fired power plants. Sargent & Lundy (S&L) is working on the Low Emission Boiler System (LEBS) portion of the program led by Riley Stoker Corporation, with support from Textron Defense Systems, Tecogen, and Reaction Engineering International. Together these organizations form {open_quotes}the Riley Team.{close_quotes} There are four phases of the LEBS development program. Currently, we are working in Phase I, which involves the design of a 400 MWe unit. Phase II through IV will involve pilot scale component testing and a Proof-of-Concept facility ({approximately}40MWe) design, construction, and operation. This document comprises the Design and Development Report for the LEBS. The report describes the design basis, design uncertainties and development plan for each of the major LEBS subsystems.

  10. Coal-fired boiler costs for industrial applications

    SciTech Connect (OSTI)

    Kurzius, S.C.; Barnes, R.W.

    1982-04-01

    Several of the current sources of information provide data on coal-fired steam boiler costs. As published, these data give widely varying and possibly inconsistent conclusions. This study was undertaken to determine the extent to which the differences in the various sets of published data bases could be resolved and, if possible, to arrive at more reliable cost correlations to be used in Oak Ridge Energy Demand Models. Our principal finding is that it is indeed possible to restate the costs within each data base on a more consistent basis. When this is done, reasonable engineering correlations of all the cost data versus steam plant capacity can be made over the 10,000 to 5000,000 lb/hr range.

  11. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Temi Linjewile; Connie Senior; Hong-Shig Shim; Bob Hurt; Eric Eddings; Larry Baxter

    2003-01-30

    This is the tenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, progress was made on the computational simulation of a full-scale boiler with the purpose of understanding the potential impacts of burner operating conditions on soot and NO{sub x} generation. Sulfation tests on both the titania support and vanadia/titania catalysts were completed using BYU's in situ spectroscopy reactor this quarter. These experiments focus on the extent to which vanadia and titania sulfate in an SO{sub 2}-laden, moist environment. Construction of the CCS reactor system is essentially complete and the control hardware and software are largely in place. A large batch of vanadia/titania catalyst in powder form has been prepared for use in poisoning tests. During this quarter, minor modifications were made to the multi-catalyst slipstream reactor and to the control system. The slipstream reactor was installed at AEP's Rockport plant at the end of November 2002. In this report, we describe the reactor system, particularly the control system, which was created by REI specifically for the reactor, as well as the installation at Rockport.

  12. The reapplication of energetic materials as boiler fuels

    SciTech Connect (OSTI)

    Buckley, S.G.; Sclippa, G.C.; Ross, J.R.

    1997-02-01

    Decommissioning of weapons stockpiles, off-specification production, and upgrading of weapons systems results in a large amount of energetic materials (EM) such as rocket propellant and primary explosives that need to be recycled or disposed of each year. Presently, large quantities of EM are disposed of in a process known as open-burn/open-detonation (OB/OD), which not only wastes their energy content, but may release large quantities of hazardous material into the environment. Here the authors investigate the combustion properties of several types of EM to determine the feasibility of reapplication of these materials as boiler fuels, a process that could salvage the energy content of the EM as well as mitigate any potential adverse environmental impact. Reapplication requires pretreatment of the fuels to make them safe to handle and to feed. Double-base nitrocellulose and nitroglycerin, trinitrotoluene (TNT), nitroguanidine, and a rocket propellant binder primarily composed of polybutidiene impregnated with aluminum flakes have been burned in a 100-kW downfired flow reactor. Most of these fuels have high levels of fuel-bound nitrogen, much of it bound in the form of nitrate groups, resulting in high NO{sub x} emissions during combustion. The authors have measured fuel-bound nitrate conversion efficiencies to NO{sub x} of up to 80%, suggesting that the nitrate groups do not follow the typical path of fuel nitrogen through HCN leading to NO{sub x}, but rather form NO{sub x} directly. They show that staged combustion is effective in reducing NO{sub x} concentrations in the postcombustion gases by nearly a factor of 3. In the rocket binder, measured aluminum particle temperatures in excess of 1700{degrees}C create high levels of thermal NO{sub x}, and also generate concern that molten aluminum particles could potentially damage boiler equipment. Judicious selection of the firing method is thus required for aluminum-containing materials.

  13. Ultra-Deepwater Production Systems

    SciTech Connect (OSTI)

    Ken L. Smith; Marc E. Leveque

    2005-05-31

    The report herein is a summary of the work performed on three projects to demonstrate hydrocarbon drilling and production methods applicable to deep and ultra deepwater field developments in the Gulf of Mexico and other like applications around the world. This work advances technology that could lead to more economic development and exploitation of reserves in ultra-deep water or remote areas. The first project is Subsea Processing. Its scope includes a review of the ''state of the art'' in subsea components to enable primary production process functions such as first stage liquids and gas separation, flow boosting, chemical treatment, flow metering, etc. These components are then combined to allow for the elimination of costly surface production facilities at the well site. A number of studies were then performed on proposed field development projects to validate the economic potential of this technology. The second project involved the design and testing of a light weight production riser made of composite material. The proposed design was to meet an actual Gulf of Mexico deepwater development project. The various engineering and testing work is reviewed, including test results. The third project described in this report encompasses the development and testing of a close tolerance liner drilling system, a new technology aimed at reducing deepwater drilling costs. The design and prototype testing in a test well are described in detail.

  14. High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle High-Efficiency Low-Cost ... This presentation was delivered at the SunShot Concentrating Solar Power ...

  15. Fischer-Tropsch synthesis in supercritical reaction media

    SciTech Connect (OSTI)

    Subramaniam, B.; Bochniak, D.; Snavely, K.

    1993-04-01

    The reactor configuration has been modified to handle tows both in the upflow and downflow directions. For comparison to bubble column operation, an upflow mode of operation will be used. For comparison to trickle-bed operation, a downflow mode will be employed. Thus, this modification allows the most flexibility for studying the effects of liquid and supercritical reaction media on the Fischer-Tropsch synthesis reaction and permits comparisons of our experimental results with previous work. A stainless steel reactor tube was ordered. This unit along with three other pieces of tubing (greater than 1/4in. i. d.) are to be sent to Alon Processing Co. for alonizing (passivating) the internal surface. This process had been employed by Huff and Satterfield (1983) to ensure that the stainless steel surfaces are catalytically inert at high temperatures (> 200[degree]C).

  16. Optimization and Comparison of Direct and Indirect Supercritical Carbon Dioxide Power Plant Cycles for Nuclear Applications

    SciTech Connect (OSTI)

    Edwin A. Harvego; Michael G. McKellar

    2011-11-01

    There have been a number of studies involving the use of gases operating in the supercritical mode for power production and process heat applications. Supercritical carbon dioxide (CO2) is particularly attractive because it is capable of achieving relatively high power conversion cycle efficiencies in the temperature range between 550 C and 750 C. Therefore, it has the potential for use with any type of high-temperature nuclear reactor concept, assuming reactor core outlet temperatures of at least 550 C. The particular power cycle investigated in this paper is a supercritical CO2 Recompression Brayton Cycle. The CO2 Recompression Brayton Cycle can be used as either a direct or indirect power conversion cycle, depending on the reactor type and reactor outlet temperature. The advantage of this cycle when compared to the helium Brayton cycle is the lower required operating temperature; 550 C versus 850 C. However, the supercritical CO2 Recompression Brayton Cycle requires an operating pressure in the range of 20 MPa, which is considerably higher than the required helium Brayton cycle operating pressure of 8 MPa. This paper presents results of analyses performed using the UniSim process analyses software to evaluate the performance of both a direct and indirect supercritical CO2 Brayton Recompression cycle for different reactor outlet temperatures. The direct supercritical CO2 cycle transferred heat directly from a 600 MWt reactor to the supercritical CO2 working fluid supplied to the turbine generator at approximately 20 MPa. The indirect supercritical CO2 cycle assumed a helium-cooled Very High Temperature Reactor (VHTR), operating at a primary system pressure of approximately 7.0 MPa, delivered heat through an intermediate heat exchanger to the secondary indirect supercritical CO2 Brayton Recompression cycle, again operating at a pressure of about 20 MPa. For both the direct and indirect cycles, sensitivity calculations were performed for reactor outlet temperature

  17. Characterization of heavy oil by capillary supercritical fluid chromatography

    SciTech Connect (OSTI)

    Fuhr, B.J.; Holloway, L.R.; Reichert, C.

    1988-06-01

    The characterization of heavy oils and bitumen produced by thermal recovery methods may aid in bringing about the following benefits: improved recovery methods, promotion of upgrading in the reservoir, improved emulsion treatment and optimized use of diluent for transportation. Because of the high proportion of nonvolatile compounds in heavy oils, gas chromatography (GC) is not particularly useful for characterization purposes. High performance liquid chromatography, while capable of analyzing a larger proportion of the nonvolatiles, possesses considerably less resolution than GC. By utilizing mobile phases in their supercritical region it is possible to study compounds that cannot be vaporized for GC analysis, yet still attain the resolution approaching that of GC. Another advantage of supercritical fluid chromatography (SFC) with the commonly used mobile phase CO/sub 2/, is the ability to employ the flame ionization detector (FID) which provides a uniform response over a wide range of compound types. SFC methods used on packed columns are excellent for low resolution separations into hydrocarbon group types and can produce data in about 5 to 15 min. A number of workers have described the use of packed silica columns for the separation and quantitation of saturate and aromatic component types in gasolines and middle distillate fuels, and of saturates, aromatics and polars in high boiling residues. In these studies the mobile phase was CO/sub 2/ and the detector was the FID. Campbell and Lee reported a semi-preparative SFC method using a packed, amino-modified silica column for the separation of aromatics according to the number of rings in a coal tar and a solved refined coal heavy distillate.

  18. Test Plan for Heat Cycle Research Program, Phase I Supercritical Cycle

    Office of Scientific and Technical Information (OSTI)

    Tests (Technical Report) | SciTech Connect Test Plan for Heat Cycle Research Program, Phase I Supercritical Cycle Tests Citation Details In-Document Search Title: Test Plan for Heat Cycle Research Program, Phase I Supercritical Cycle Tests The 60 kW Heat Cycle Research Facility (HCRF) provides a means of examining different concepts and components associated with the generation of electrical power from a geothermal resource using a binary power cycle. In this power cycle the heat or energy

  19. Project Profile: Physics-Based Reliability Models for Supercritical-CO2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Turbomachinery Components | Department of Energy Physics-Based Reliability Models for Supercritical-CO2 Turbomachinery Components Project Profile: Physics-Based Reliability Models for Supercritical-CO2 Turbomachinery Components Abengoa logo GE, under the Physics of Reliability: Evaluating Design Insights for Component Technologies in Solar (PREDICTS) Program will be leveraging internally developed models to predict the reliability of hybrid gas bearing (HGB) and dry gas seal (DGS) components

  20. Synchrotron X-ray Studies of Super-critical Carbon Dioxide / Reservoir Rock

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Interfaces | Department of Energy Synchrotron X-ray Studies of Super-critical Carbon Dioxide / Reservoir Rock Interfaces Synchrotron X-ray Studies of Super-critical Carbon Dioxide / Reservoir Rock Interfaces Project obectives: Utilize synchrotron X-ray measurements, to monitor all aspects of atomic to nanoscale structural changes resulting from chemical interactions of scCO2-H2O binary fluids with rocks under environments directly relevant to EGS. chemistry_you_synchrotron_studies.pdf (1.84

  1. Chapter 4: Advancing Clean Electric Power Technologies | Supercritical Carbon Dioxide Brayton Cycle Technology Assessment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Capture and Storage Fast-spectrum Reactors Geothermal Power High Temperature Reactors Hybrid Nuclear-Renewable Energy Systems Hydropower Light Water Reactors Marine and Hydrokinetic Power Nuclear Fuel Cycles Solar Power Stationary Fuel Cells Supercritical Carbon Dioxide Brayton Cycle Wind Power ENERGY U.S. DEPARTMENT OF Clean Power Quadrennial Technology Review 2015 1 Quadrennial Technology Review 2015 Supercritical Carbon Dioxide Brayton Cycle Chapter 4: Technology Assessments Introduction The

  2. EECBG Success Story: San Francisco Turns Up The Heat In Push To Eliminate Old Boilers

    Broader source: Energy.gov [DOE]

    San Francisco’s extensive stock of multifamily properties is getting some critical assistance in replacing old and inefficient boilers with new, high-efficiency heating systems using Energy Efficiency and Conservation Block Grant (EECBG) funds. Learn more.

  3. San Francisco Turns Up The Heat In Push To Eliminate Old Boilers

    Broader source: Energy.gov [DOE]

    San Francisco’s extensive stock of multifamily properties is getting some critical assistance in replacing old and inefficient boilers with new, high-efficiency heating systems using Energy Efficiency and Conservation Block Grant (EECBG) funds.

  4. Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on installing high-pressure boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  5. Residential Bulk-Fed Wood-Pellet Central Boilers and Furnace Rebate Program

    Broader source: Energy.gov [DOE]

    The New Hampshire Public Utilities Commission (PUC) offers rebates of 30% of the installed cost of qualifying new residential bulk-fed, wood-pellet central heating boilers or furnaces. The maximum...

  6. Gas turbines for coal-fired turbocharged PFBC boiler power plants

    SciTech Connect (OSTI)

    Wenglarz, R.; Drenker, S.

    1984-11-01

    A coal-fired turbocharged boiler using fluidized bed combustion at high pressure would be more compact than a pulverized coal fired boiler. The smaller boiler size could permit the utility industry to adopt efficient modular construction methods now widely used in other industries. A commercial turbocharger of the capacity needed to run a 250 MW /SUB e/ power plant does not exist; commercial gas turbines of the correct capacity exist, but they are not matched to this cycle's gas temperature of less than 538/sup 0/C (1000/sup 0/F). In order to avoid impeding the development of the technology, it will probably be desirable to use existing machines to the maximum extent possible. This paper explores the advantages and disadvantages of applying either standard gas turbines or modified standard gas turbines to the turbocharged boiler.

  7. The first pilot compact CFB boiler with water cooled separator in China

    SciTech Connect (OSTI)

    Yue Guangxi; Li Yan; Lu Xiaoma; Zhang Yanguo; Liu Qing; Lu Junfu; Zhao Xiaoxing

    1997-12-31

    The square cyclone was experimentally investigated in Tsinghua University. The flow field in the cyclone was measured and numerically simulated. The investigation prove that the corner of square cyclone created turbulence to decrease the collection efficiency. The acceleration of solid particles at the inlet of the square cyclone was also a factor for good efficiency. The collection efficiency has been improved by a carefully designed curved inlet of the cyclone which received the patent in China. The patented water cooled cyclone was used in a design of improved 75 T/h CFB boiler. The demonstration of the boiler started test operation in April 1996 at Jianjiang Cement Co. in Sichuan Province. The first operation will be used for adjusting the boiler. Further tests will be done to confirm the performance of the boiler.

  8. 2014-01-31 Issuance: Energy Conservation Standards for Residential Boilers; Notice of Data Availability

    Office of Energy Efficiency and Renewable Energy (EERE)

    This document is a pre-publication Federal Register notice of data availability regarding energy conservation standards for residential boilers, as issued by the Deputy Assistant Secretary for Energy Efficiency on January 31, 2014.

  9. Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators - Steam Tip Sheet #22

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO tip sheet on installing high-pressure boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  10. Clean Boiler Water-side Heat Transfer Surfaces - Steam Tip Sheet #7

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  11. Guide to Combined Heat and Power Systems for Boiler Owners and...

    Broader source: Energy.gov (indexed) [DOE]

    It is part of a suite of publications offered by the Department of Energy to improve steam system performance. Guide to Combined Heat and Power Systems for Boiler Owners and ...

  12. CHP Integrated with Packaged Boilers- Presentation by CMCE, Inc., June 2011

    Broader source: Energy.gov [DOE]

    Presentation on CHP Integrated with Packaged Boilers, given by Carlo Castaldini of CMCE, Inc., at the U.S. DOE Industrial Distributed Energy Portfolio Review Meeting in Washington, D.C. on June 1-2, 2011.

  13. 2014-02-07 Issuance: Test Procedure for Commercial Packaged Boilers; Request for Information

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register request for information regarding test procedures for commercial packaged boilers, as issued by the Deputy Assistant Secretary for Energy Efficiency on February 7, 2014.

  14. Hybrid neural net and rule based system for boiler monitoring and diagnosis

    SciTech Connect (OSTI)

    Kraft, T.; Okagaki, K.; Ishii, R.; Surko, P. ); Brandon, A.; DeWeese, A.; Peterson, S.; Bjordal, R. )

    1991-01-01

    A fully recurrent neural net is coupled with a rule-based expert system in this operator adviser system. The neural net has been trained to recognize normal high-efficiency operating behavior of the power plant boiler, and the rule-based expert system diagnoses problems and suggests maintenance and/or operator actions when the boiler strays outside the envelope of normal operating conditions. The fully recurrent neural net provides an accurate model of a boiler even when the load demand is changing rapidly and the boiler operating conditions varying over a wide range. The hybrid system has been quicker and easier to generate than a strictly rule-based one, and has been designed to be more easily portable to other units This paper describes the ongoing development work for monitoring SDGE and E's South Bay Plant, Unit. 1.

  15. Coal-fired boiler houses in Cracow present state and possibilities to improve their efficiency

    SciTech Connect (OSTI)

    Cyklis, P.; Butcher, T.A.

    1995-12-31

    A significant amount of heat energy both for heating and process purposes is generated in Cracow, Poland in small-and medium size local boiler houses. The operating procedure of these boiler houses is most often economically and ecologically ineffective because of the bad condition of boilers and lack of funds to install automation, control and measurement equipment. Within the Polish-American Program of Elimination of Low Emission Sources financed by the US Department of Energy, the ENERGOEKSPERT Co., Ltd. investigated chosen boiler houses in Cracow, commissioned by the Cracow Development Office. The results of these investigations were subject of engineering analysis carried out at the Institute of Industrial Equipment and Power Engineering, Technical University, Cracow. The analysis proved that the low-cost improvement of economic efficiency and reduction of air pollutant emission is feasible for combustion of coal fuels.

  16. Measure Guideline. Condensing Boilers - Control Strategies for Optimizing Performance and Comfort in Residential Applications

    SciTech Connect (OSTI)

    Arena, L.

    2013-05-01

    This guide is intended for designers and installers of hydronic heating systems interested in maximizing the overall system efficiency of condensing boilers when coupled with baseboard convectors. It is applicable to new and retrofit projects.

  17. Evaluation of Exxon donor solvent full-range distillate as a utility boiler fuel. Final report

    SciTech Connect (OSTI)

    Reese, J.; Folsom, B.; Jones, F.

    1984-03-01

    The use of Exxon Donor Solvent (EDS) as a utility boiler fuel was evaluated at Southern California Edison Company's Highgrove Unit 4, a Combustion Engineering 44.5 net Mw wall-fired boiler. The EDS evaluated was a full range solvent oil produced at the Exxon Coal-Liquefaction Pilot Plant in Baytown, Texas. This evaluation involved modifying the boiler equipment and operating procedures for EDS, and then firing 4500 barrels of EDS in the boiler. The resulting boiler performance and emissions with EDS were compared to those with a blended low-sulfur petroleum distillate similar to No. 4 fuel oil and with natural gas. The boiler was operated over a range of load and excess air conditions during the tests. The potential for NO/sub x/ reduction with a burner out of service (BOOS) was also evaluated. Boiler performance, including excess air requirements, maximum load, thermal efficiency and heat rate efficiency was similar to that with oil. The NO/sub x/ emissions with EDS were about 12 percent higher than with oil. NO/sub x/ reduction with BOOS was about 20 percent with both oil and EDS. EDS use did not result in an increase in particulate emissions. Submicron particulate, however, was increased with EDS. Required equipment modifications at Highgrove primarily involved material compatibility with EDS, fuel system capacity, and the burner nozzles. The use of EDS required the implementation of health and safety procedures due to the adverse health effects that could result from prolonged exposure to the fuel. The results of the evaluation demostrated that EDS can be used in a utility boiler designed for oil with only minor modifications.

  18. NO{sub x} control using natural gas reburn on an industrial cyclone boiler

    SciTech Connect (OSTI)

    Farzan, H.; Maringo, G.J.; Beard, C.T.; Weed, G.E.; Pratapas, J.

    1997-07-01

    Eastman Kodak Company`s cyclone boiler (Unit No. 43), located in Rochester, New York, has been retrofitted with the gas reburn. technology developed by the Babcock & Wilcox (B&W) Company to reduce NO{sub x} emissions in order to comply with the New York State regulations adopted in conformance with the Title I of the Clean Air Act Amendments (CAAA) of 1990. At the peak load, the ozone nonattainment required NO{sub x} reduction from baseline levels necessary to meet the presumptive limit for cyclone boilers in this regulation is 56%. Eastman Kodak Company and the Gas Research Institute (GRI) are co-sponsoring this project. Chevron has supplied the natural gas. Equipment installation for the gas reburn system was performed in a September 1995 outage. Boiler No. 43`s maximum continuous rating (MCR) is 550,000 pounds per hour of steam flow (or approximately equivalent to 60 MW{sub e}). Because of the compact boiler design, there is insufficient furnace residence time to use coal or oil as the reburn fuel, thus making it a prime candidate for gas reburn. Kodak currently has four cyclone boilers. Contingent upon successful completion of this gas reburn project, modification of Kodak`s other cyclone boilers to include reburn technology will be considered. The paper will describe B&W`s gas reburn data from a cyclone-equipped pilot facility (B&W`s Small Boiler Simulator), gas reburn system design, manufacturing, and installation information specific to Kodak`s Unit No. 43. In addition, the paper will discuss numerical modeling and the full-scale commercial boiler test results.

  19. NO{sub x} control using natural gas reburn on an industrial cyclone boiler

    SciTech Connect (OSTI)

    Farzan, H.; Maringo, G.J.; Beard, C.T.; Weed, G.E.; Pratapas, J.

    1996-12-31

    Eastman Kodak Company`s cyclone boiler (Unit No. 43), located in Rochester, New York, has been retrofitted with the gas reburn technology developed by the Babcock and Wilcox (B and W) Company to reduce NO{sub x} emissions in order to comply with the New York State regulations adopted in conformance with the Title I of the Clean Air Act Amendments (CAAA) of 1990. At the peak load, the ozone nonattainment required NO{sub x} reduction from baseline levels necessary to meet the presumptive limit for cyclone boilers in this regulation is 56%. Eastman Kodak Company and the Gas Research Institute (GRI) are co-sponsoring this project. Chevron has supplied the natural gas. Equipment installation for the gas reburn system was performed in a September 1995 outage. Boiler No. 43`s maximum continuous rating (MCR) is 550,000 pounds per hour of steam flow (or approximately equivalent to 60 MW{sub e}). Because of the compact boiler design, there is insufficient furnace residence time to use coal or oil as the reburn fuel, thus making it a prime candidate for gas reburn. Kodak currently has four cyclone boilers. Contingent upon successful completion of this gas reburn project, modification of Kodak`s other cyclone boilers to include reburn technology will be consideredd. The paper will describe B and W`s gas reburn data from a cyclone-equipped pilot facility (B and W`s Small Boiler Simulator), gas reburn system design, manufacturing, and installation information specific to Kodak`s Unit No. 43. In addition, the paper will discuss numerical modeling and the full-scale commercial boiler test results.

  20. Low NO sub x /SO sub x Burner retrofit for utility cyclone boilers

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The objective of this project is to demonstrate the LNS Burner as retrofitted to the host cyclone boiler for effective low-cost control of NO{sub x} and SO{sub x} emissions while firing a bituminous coal. The LNS Burner employs a simple, innovative combustion process to burn pulverized coal at high temperatures and provides effective, low-cost control of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions. The coal ash contains sulfur and is removed in the form of molten slag and flyash. Cyclone-fired boiler units are typically older units firing high-sulfur bituminous coals at very high temperatures which results in very high NO{sub x} and SO{sub x} emissions. The addition of conventional emission control equipment, such as wet scrubbers, to these older cyclone units in order to meet current and future environmental regulations is generally not economic. Further, the units are generally not compatible with low sulfur coal switching for S0{sub 2} control or selective catalytic reduction technologies for NO{sub x} control. Because the LNS Burner operates at the same very high temperatures as a typical cyclone boiler and produces a similar slag product, it may offer a viable retrofit option for cyclone boiler emission control. This was confirmed by the Cyclone Boiler Retrofit Feasibility Study carried out by TransAlta and an Operating Committee formed of cyclone boiler owners in 1989. An existing utility cyclone boiler, was then selected for the evaluation of the cost and performance study. It was concluded that the LNS Burner retrofit would be a cost-effective option for control of cyclone boiler emissions. A full-scale demonstration of the LNS Burner retrofit was selected in October 1988 as part of the DOE's Clean Coal Technology Program Round II.

  1. Low NO sub x /SO sub x Burner retrofit for utility cyclone boilers

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    Cyclone furnaces operate with high excess air and at high temperature. The heat release during combustion is very high and as a result the boiler volume is much smaller than would be found in a conventional pc-fired system. The Marion Unit 1 boiler, at the level of the cyclone entry, has a small cross-section; about 5-feet in depth and about 20-feet in width. A boiler schematic showing the LNS Burner and relative location of the superheater region and overfire air ports is shown in Figure 1. The LNS Burner's combustion process is fundamentally different from that of the cyclone, and the combustion products are also different. The LNS Burner products enter the boiler as hot, fuel-rich gases. Additional overfire air must be added to complete this combustion step with care taken to avoid the formation of thermal NO{sub x}. If done correctly, S0{sub 2} is controlled and significant NO{sub x} reductions are achieved. Because of the small boiler volume, flow modelling was found to be necessary to insure that adequate mixing of LNS Burner combustion products with air can be accomplished to achieve NO{sub x} emissions goals. Design requirements for the air injection system for the Marion boiler were developed using FLUENT, a commercially available computational fluid dynamics (CFD) code. A series of runs were made to obtain a design for final air injection that met the process design goals as closely as possible.

  2. Measure Guideline: Condensing Boilers - Control Strategies for Optimizing Performance and Comfort in Residential Applications

    SciTech Connect (OSTI)

    Arena, L.

    2013-05-01

    The combination of a gas-fired condensing boiler with baseboard convectors and an indirect water heater has become a common option for high-efficiency residential space heating in cold climates. While there are many condensing boilers available on the market with rated efficiencies in the low to mid 90% efficient range, it is imperative to understand that if the control systems are not properly configured, these heaters will perform no better than their non-condensing counterparts. Based on previous research efforts, it is apparent that these types of systems are typically not designed and installed to achieve maximum efficiency (Arena 2010). It was found that there is a significant lack of information for contractors on how to configure the control systems to optimize overall efficiency. For example, there is little advice on selecting the best settings for the boiler reset curve or how to measure and set flow rates in the system to ensure that the return temperatures are low enough to promote condensing. It has also been observed that recovery from setback can be extremely slow and, at times, not achieved. Recovery can be affected by the outdoor reset control, the differential setting on the boiler and over-sizing of the boiler itself. This guide is intended for designers and installers of hydronic heating systems interested in maximizing the overall system efficiency of condensing boilers when coupled with baseboard convectors. It is applicable to new and retrofit applications.

  3. Nitrogen oxides emission control options for coal-fired electric utility boilers

    SciTech Connect (OSTI)

    Ravi K. Srivastava; Robert E. Hall; Sikander Khan; Kevin Culligan; Bruce W. Lani

    2005-09-01

    Recent regulations have required reductions in emissions of nitrogen oxides (NOx) from electric utility boilers. To comply with these regulatory requirements, it is increasingly important to implement state-of-the-art NOx control technologies on coal-fired utility boilers. This paper reviews NOx control options for these boilers. It discusses the established commercial primary and secondary control technologies and examines what is being done to use them more effectively. Furthermore, the paper discusses recent developments in NOx controls. The popular primary control technologies in use in the United States are low-NOx burners and overfire air. Data reflect that average NOx reductions for specific primary controls have ranged from 35% to 63% from 1995 emissions levels. The secondary NOx control technologies applied on U.S. coal-fired utility boilers include reburning, selective noncatalytic reduction (SNCR), and selective catalytic reduction (SCR). Thirty-six U.S. coal-fired utility boilers have installed SNCR, and reported NOx reductions achieved at these applications ranged from 15% to 66%. Recently, SCR has been installed at 150 U.S. coal-fired utility boilers. Data on the performance of 20 SCR systems operating in the United States with low-NOx emissions reflect that in 2003, these units achieved NOx emission rates between 0.04 and 0.07 lb/106 Btu. 106 refs., 6 figs., 6 tabs.

  4. Development of the first demonstration CFB boiler for gas and steam cogeneration

    SciTech Connect (OSTI)

    Fang, M; Luo, Z.; Li, X.; Wang, Q.; Shi, Z.; Ni, M.; Cen, K.

    1997-12-31

    To solve the shortage of gas and steam supply in the small towns of the country, a new gas steam cogeneration system has been developed. On the basis of the fundamental research on the system, a demonstration gas steam cogeneration system has been designed. As the phase 1 of the project, a 75t/h demonstration CFB boiler for gas steam cogeneration has been erected and operated at Yangzhong Thermal Power Plant of China. This paper introduces the first 75t/h demonstration CFB boiler for gas steam cogeneration. Due to the need of gas steam cogeneration process, the boiler has the features of high temperature cyclone separation, high solid recycle ratio, staged combustion and an external heat exchanger adjusting bed temperature and heat load. The operation results show that the boiler has wide fuel adaptability and the heating value of the coal changes from 14MJ/Kg to 25MJ/Kg. The heat load changes from 85t/h to 28t/h while steam parameter is maintained at the normal conditions. The combustion efficiency of the boiler attain 98%. The boiler design and operation experiences may be a guide to the design and operation of larger CFB units in the future.

  5. Technology Solutions Case Study: Advanced Boiler Load Monitoring Controls, Chicago, Illinois

    SciTech Connect (OSTI)

    2014-09-01

    Most of Chicago’s older multifamily housing stock is heated by centrally metered steam or hydronic systems. The cost of heat is typically absorbed into the owner’s operating cost and is then passed to tenants. Central boilers typically have long service lifetimes; the incentive for retrofit system efficiency upgrades is greater than equipment replacement for the efficiency-minded owner. System improvements as the “low-hanging fruit” are familiar, from improved pipe insulation to aftermarket controls such as outdoor temperature reset (OTR) or lead/lag controllers for sites with multiple boilers. Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. In this project, the Building America team Partnership for Advanced Residential Retrofit (PARR) installed and monitored an ALM aftermarket controller, the M2G from Greffen Systems, at two Chicago area multifamily buildings with existing OTR control. Results show that energy savings depend on the degree to which boilers are oversized for their load, represented by cycling rates. Also, savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, oversized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less oversized boilers at another site showed muted savings.

  6. Final Report: Guided Acoustic Wave Monitoring of Corrosion in Recovery Boiler Tubing

    SciTech Connect (OSTI)

    Chinn, D J; Quarry, M J; Rose, J L

    2005-03-31

    Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This Department of Energy, Office of Industrial Technologies project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the cold side or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications. This technique appears very promising for recovery boiler tube application, potentially expediting annual inspection of tube integrity.

  7. Curbing Air Pollution and Greenhouse Gas Emissions from Industrial Boilers in China

    SciTech Connect (OSTI)

    Shen, Bo; Price, Lynn K; Lu, Hongyou; Liu, Xu; Tsen, Katherine; Xiangyang, Wei; Yunpeng, Zhang; Jian, Guan; Rui, Hou; Junfeng, Zhang; Yuqun, Zhuo; Shumao, Xia; Yafeng, Han; Manzhi, Liu

    2015-10-28

    China’s industrial boiler systems consume 700 million tons of coal annually, accounting for 18% of the nation’s total coal consumption. Together these boiler systems are one of the major sources of China’s greenhouse gas (GHG) emissions, producing approximately 1.3 gigatons (Gt) of carbon dioxide (CO2) annually. These boiler systems are also responsible for 33% and 27% of total soot and sulfur dioxide (SO2) emissions in China, respectively, making a substantial contribution to China’s local environmental degradation. The Chinese government - at both the national and local level - is taking actions to mitigate the significant greenhouse gas (GHG) emissions and air pollution related to the country’s extensive use of coal-fired industrial boilers. The United States and China are pursuing a collaborative effort under the U.S.-China Climate Change Working Group to conduct a comprehensive assessment of China’s coal-fired industrial boilers and to develop an implementation roadmap that will improve industrial boiler efficiency and maximize fuel-switching opportunities. Two Chinese cities – Ningbo and Xi’an – have been selected for the assessment. These cities represent coastal areas with access to liquefied natural gas (LNG) imports and inland regions with access to interprovincial natural gas pipelines, respectively.

  8. Ultra-wideband directional sampler

    DOE Patents [OSTI]

    McEwan, T.E.

    1996-05-14

    The Ultra-Wideband (UWB) Directional Sampler is a four port device that combines the function of a directional coupler with a high speed sampler. Two of the four ports operate at a high sub-nanosecond speed, in ``real time``, and the other two ports operate at a slow millisecond-speed, in ``equivalent time``. A signal flowing inbound to either of the high speed ports is sampled and coupled, in equivalent time, to the adjacent equivalent time port while being isolated from the opposite equivalent time port. A primary application is for a time domain reflectometry (TDR) situation where the reflected pulse returns while the outbound pulse is still being transmitted, such as when the reflecting discontinuity is very close to the TDR apparatus. 3 figs.

  9. Ultra-wideband directional sampler

    DOE Patents [OSTI]

    McEwan, Thomas E.

    1996-01-01

    The Ultra-Wideband (UWB) Directional Sampler is a four port device that combines the function of a directional coupler with a high speed sampler. Two of the four ports operate at a high sub-nanosecond speed, in "real time", and the other two ports operate at a slow millisecond-speed, in "equivalent time". A signal flowing inbound to either of the high speed ports is sampled and coupled, in equivalent time, to the adjacent equivalent time port while being isolated from the opposite equivalent time port. A primary application is for a time domain reflectometry (TDR) situation where the reflected pulse returns while the outbound pulse is still being transmitted, such as when the reflecting discontinuity is very close to the TDR apparatus.

  10. Development of Modeling Capabilities for the Analysis of Supercritical Water-Cooled Reactor Thermal-Hydraulics and Dynamics

    SciTech Connect (OSTI)

    Dr. Michael Z. Podowski

    2009-04-16

    Develop an experimental and theoretical data base for heat transfer in tubes and channels cooled by water and CO2 at supercritical pressures.

  11. Design features of first of its kind AFBC high pressure boiler for Kutch lignite fuel in Gujarat, India

    SciTech Connect (OSTI)

    Mokashi, A.; Diwakar, K.W.

    1998-07-01

    Gujarat Heavy Chemicals Ltd. (GHCL) of Gujarat State in India is one of the largest manufacturers of Soda Ash with modern technology from Akzo of the Netherlands. GHCL with earlier experience in firing lignite on a travagrate boiler and with a converted fluidized bed boiler has very clearly identified the problem area for review, and with that rich experience awarded a contract to Thermax Babcock and Wilcox Ltd. (TBW), Pune, India. Accordingly, a boiler has been designed to suit Kutch Lignite and coal with AFBC technology. This paper discusses the complete design of the boiler, effects of Kutch Lignite, its composition, thermal efficiency on coal as well as lignite, various performance parameters and guarantees, sizing arrangements of pressure parts, feeding arrangement and specially designed fluidizing bed combustor, various instrumentation and control loops. This paper discusses all the above features of this high-pressure boiler which can be an ideal boiler for the Kutch lignite fuel.

  12. ULTRA BARRIER TOPSHEET (UBT) FOR FLEXIBLE PHOTOVOLTAICS

    SciTech Connect (OSTI)

    DeScioli, Derek

    2013-06-01

    This slide-show presents 3M photovoltaic-related products, particularly flexible components. Emphasis is on the 3M Ultra Barrier Solar Films. Topics covered include reliability and qualification testing and flexible photovoltaic encapsulation costs.

  13. ULTRA BARRIER TOPSHEET (UBT) FOR FLEXIBLE PHOTOVOLTAICS

    SciTech Connect (OSTI)

    Alan, Nachtigal; Berniard, Tracie; Murray, Bill; Roehrig, Mark; Schubert, Charlene; Spagnola, Joseph; Weigel, Mark

    2013-01-01

    This poster describes the 3M Ultra-Barrier Solar Film and its application; production scale-up and data; reliability and qualification testing; and improvements in the next generation.

  14. Use of supercritical fluid solution expansion processes for drug delivery, particle synthesis, and thin film deposition

    SciTech Connect (OSTI)

    Hybertson, B.M.

    1992-01-01

    Properties of the gases and aerosols resulting from the expansion of supercritical fluid solutions were studied. Film deposition, particle formation, and drug delivery processes using supercritical fluids were developed. Thin films of palladium, copper, aluminum, silver, and silicon dioxide were deposited by a method called supercritical fluid transport-chemical deposition (SFT-CD). In each case, a precursor compound was dissolved in a supercritical fluid and the solution was allowed to expand through a restrictor nozzle into a reaction chamber at subcritical pressure, resulting in the formation of aerosol particles of the precursor. A chemical reaction was induced to occur at the surface of a substrate, resulting in deposition of a thin film. Micron-sized particles of aluminum fluoride and copper oxide were synthesized by a method called supercritical fluid transport-chemical formation of particles (SFT-CFP). The process was similar to that in SFT-CD, but the chemical reactions were induced to occur in the gas phase instead of at a substrate surface, resulting in the formation of fine particles. A new method of pulmonary drug delivery called supercritical fluid drug delivery (SFDD) was conceived and demonstrated. In SFDD a drug compound is dissolved in a supercritical fluid, and the solution is allowed to expand through a restrictor nozzle. The resultant aerosol is directly inhaled by a human or animal subject and the fine drug particles are deposited in the lungs. Menthol, vanillin, camphor, cholesterol, Sudan III, and Oil Blue N were used as model drug compounds for SFDD. Delivery of [alpha]-tocopherol to rat lung tissue was demonstrated, with observed increases of 80-290% above background levels.

  15. Incorporating supercritical steam turbines into molten-salt power tower plants : feasibility and performance.

    SciTech Connect (OSTI)

    Pacheco, James Edward; Wolf, Thorsten; Muley, Nishant

    2013-03-01

    Sandia National Laboratories and Siemens Energy, Inc., examined 14 different subcritical and supercritical steam cycles to determine if it is feasible to configure a molten-salt supercritical steam plant that has a capacity in the range of 150 to 200 MWe. The effects of main steam pressure and temperature, final feedwater temperature, and hot salt and cold salt return temperatures were determined on gross and half-net efficiencies. The main steam pressures ranged from 120 bar-a (subcritical) to 260 bar-a (supercritical). Hot salt temperatures of 566 and 600%C2%B0C were evaluated, which resulted in main steam temperatures of 553 and 580%C2%B0C, respectively. Also, the effects of final feedwater temperature (between 260 and 320%C2%B0C) were evaluated, which impacted the cold salt return temperature. The annual energy production and levelized cost of energy (LCOE) were calculated using the System Advisory Model on 165 MWe subcritical plants (baseline and advanced) and the most promising supercritical plants. It was concluded that the supercritical steam plants produced more annual energy than the baseline subcritical steam plant for the same-size heliostat field, receiver, and thermal storage system. Two supercritical steam plants had the highest annual performance and had nearly the same LCOE. Both operated at 230 bar-a main steam pressure. One was designed for a hot salt temperature of 600%C2%B0C and the other 565%C2%B0C. The LCOEs for these plants were about 10% lower than the baseline subcritical plant operating at 120 bar-a main steam pressure and a hot salt temperature of 565%C2%B0C. Based on the results of this study, it appears economically and technically feasible to incorporate supercritical steam turbines in molten-salt power tower plants.

  16. ultra_deepwater | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Policy Act of 2005 The Energy Policy Act of 2005 charges NETL with review and oversight of "a program of research, development, demonstration, and commercial application of technologies for ultra-deepwater and unconventional natural gas and other petroleum resource exploration and production to maximize the value of U.S. resources by increasing supply from these resources." The Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources Program is the

  17. Two Novel Ultra-Incompressible Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Two Novel Ultra-Incompressible Materials Two Novel Ultra-Incompressible Materials Print Wednesday, 29 June 2011 00:00 Some current challenges in aerospace engineering and fission/fusion applications require materials that are mechanically and chemically stable at extreme conditions. One such class of materials is ultrahigh-temperature ceramics, which are often binary transition-metal carbides, borides, or nitrides. It is therefore of great interest to understand how to synthesize new compounds

  18. Low Cost Polymer heat Exchangers for Condensing Boilers

    SciTech Connect (OSTI)

    Butcher, Thomas; Trojanowski, Rebecca; Wei, George; Worek, Michael

    2015-09-30

    Work in this project sought to develop a suitable design for a low cost, corrosion resistant heat exchanger as part of a high efficiency condensing boiler. Based upon the design parameters and cost analysis several geometries and material options were explored. The project also quantified and demonstrated the durability of the selected polymer/filler composite under expected operating conditions. The core material idea included a polymer matrix with fillers for thermal conductivity improvement. While the work focused on conventional heating oil, this concept could also be applicable to natural gas, low sulfur heating oil, and biodiesel- although these are considered to be less challenging environments. An extruded polymer composite heat exchanger was designed, built, and tested during this project, demonstrating technical feasibility of this corrosion-resistant material approach. In such flue gas-to-air heat exchangers, the controlling resistance to heat transfer is in the gas-side convective layer and not in the tube material. For this reason, the lower thermal conductivity polymer composite heat exchanger can achieve overall heat transfer performance comparable to a metal heat exchanger. However, with the polymer composite, the surface temperature on the gas side will be higher, leading to a lower water vapor condensation rate.

  19. Conceptual Design of Oxygen-Based PC Boiler

    SciTech Connect (OSTI)

    Andrew Seltzer; Zhen Fan

    2005-09-01

    Coal is presently the world's primary fuel for generating electrical power and, being more abundant and less expensive than oil or natural gas, is expected to continue its dominance into the future. Coal, however, is more carbon intensive than natural gas and oil and consequently coal-fired power plants are large point source emitters of carbon dioxide (CO{sub 2}). Since CO{sub 2} is a greenhouse gas, which may have an adverse impact on the world's climate/weather patterns, studies have been conducted to determine the feasibility and economic impact of capturing power plant CO{sub 2} emissions for pipeline transport to a sequestration/storage site. The stack gas that exhausts from a modern coal-fired power plant typically contains about 15% CO{sub 2} on a dry volume basis. Although there are numerous processes available for removing CO{sub 2} from gas streams, gas scrubbing with amine solvent is best suited for this application because of the large gas volumes and low CO{sub 2} concentrations involved. Unfortunately the energy required to regenerate the solvent for continued use as a capturing agent is large and imposes a severe energy penalty on the plant. In addition this ''back end'' or post combustion cleanup requires the addition of large vessels, which, in retrofit applications, are difficult to accommodate. As an alternative to post combustion scrubbing, Foster Wheeler (FW) has proposed that the combustion process be accomplished with oxygen rather than air. With all air nitrogen eliminated, a CO{sub 2}-water vapor rich flue gas will be generated. After condensation of the water vapor, a portion of the flue gas will be recirculated back to the boiler to control the combustion temperature and the balance of the CO{sub 2} will be processed for pipeline transport. This proposed oxygen-carbon dioxide (O{sub 2}/CO{sub 2}) combustion process eliminates the need for CO{sub 2} removal/separation and reduces the cost of supplying a CO{sub 2} rich stream for

  20. Life assessment of superheater/reheater tubes in fossil boilers

    SciTech Connect (OSTI)

    Viswanathan, R.; Gehl, S.; Paterson, S.R.; Grunloh, H.

    1995-08-01

    Creep rupture failure of superheater(SH)/-reheater(RH) tubes is a major cause of forced outages of power boilers. A methodology developed recently by EPRI researchers has helped utilities make more informed run/replace decisions for tubes by judiciously combining calculational, nondestructive and destructive evaluations. In this methodology, the tubes/tube assemblies at risk are identified by ultrasonically measuring the thickest steamside oxide scale and thinnest wall thickness in the tubes. The remaining life of each tube/tube assemblies is predicted using a computer code known as TUBELIFE, thus achieving a further level of focus on the tubes/assemblies in the highest risk category. Sacrificial tube samples are then removed from the select locations and subjected to laboratory metallurgical evaluation and isostress rupture testing to refine the remaining life estimates. Research has further refined this methodology by validating the ultrasonic technique for scale measurement, identifying the appropriate stress formula and oxide growth laws and evaluating the limitations of creep damage summation rules and isostress rupture test procedures. This paper provides an overview of the research in the field, and establish a road map for assessing the remaining life of SH/RH tubes.

  1. Life assessment of superheater/reheater tubes in fossil boilers

    SciTech Connect (OSTI)

    Viswanathan, R.; Gehl, S. ); Paterson, S.R. ); Grunloh, H. )

    1994-02-01

    Creep rupture failure of superheater (SH)/reheater (RH) tubes is a major cause of forced outages of power boilers. A methodology developed recently by EPRI and its contractors has helped utilities make more informed run/replace decisions for tubes by judiciously combining calculational, nondestructive, and destructive evaluations. In this methodology, the tubes/tube assemblies at risk are identified by ultrasonically measuring the thickest steamside oxide scale and thinnest wall thickness in the tubes. The remaining life of each tube/tube assembly is predicted using a computer code known as TUBELIFE, thus achieving a further level of focus on the tubes/assemblies in the highest risk'' category. Sacrificial tube samples are then removed from the select locations and subjected to laboratory metallurgical evaluation and isostress rupture testing to refine the remaining life estimates. Research has further refined this methodology by validating the ultrasonic technique for scale measurement, identifying the appropriate stress formula and oxide growths laws and evaluating the limitations of creep damage summation rules and isostress rupture test procedures. This paper provides an overview of the research in the field, and establishes a road map for assessing the remaining life of SH/RH tubes.

  2. Materials, Turbomachinery and Heat Exchangers for Supercritical CO2 Systems

    SciTech Connect (OSTI)

    Anderson, Mark; Nellis, Greg; Corradini, Michael

    2012-10-19

    The objective of this project is to produce the necessary data to evaluate the performance of the supercritical carbon dioxide cycle. The activities include a study of materials compatibility of various alloys at high temperatures, the heat transfer and pressure drop in compact heat exchanger units, and turbomachinery issues, primarily leakage rates through dynamic seals. This experimental work will serve as a test bed for model development and design calculations, and will help define further tests necessary to develop high-efficiency power conversion cycles for use on a variety of reactor designs, including the sodium fast reactor (SFR) and very high-temperature gas reactor (VHTR). The research will be broken into three separate tasks. The first task deals with the analysis of materials related to the high-temperature S-CO{sub 2} Brayton cycle. The most taxing materials issues with regard to the cycle are associated with the high temperatures in the reactor side heat exchanger and in the high-temperature turbine. The system could experience pressures as high as 20MPa and temperatures as high as 650°C. The second task deals with optimization of the heat exchangers required by the S-CO{sub 2} cycle; the S-CO{sub 2} flow passages in these heat exchangers are required whether the cycle is coupled with a VHTR or an SFR. At least three heat exchangers will be required: the pre-cooler before compression, the recuperator, and the heat exchanger that interfaces with the reactor coolant. Each of these heat exchangers is unique and must be optimized separately. The most challenging heat exchanger is likely the pre-cooler, as there is only about a 40°C temperature change but it operates close to the CO{sub 2} critical point, therefore inducing substantial changes in properties. The proposed research will focus on this most challenging component. The third task examines seal leakage through various dynamic seal designs under the conditions expected in the S-CO{sub 2} cycle

  3. Effect of bed pressure drop on performance of a CFB boiler

    SciTech Connect (OSTI)

    Hairui Yang; Hai Zhang; Shi Yang; Guangxi Yue; Jun Su; Zhiping Fu

    2009-05-15

    The effect of bed pressure drop and bed inventory on the performances of a circulating fluidized bed (CFB) boiler was studied. By using the state specification design theory, the fluidization state of the gas-solids flow in the furnace of conventional CFB boilers was reconstructed to operate at a much lower bed pressure drop by reducing bed inventory and control bed quality. Through theoretical analysis, it was suggested that there would exist a theoretical optimal value of bed pressure drop, around which the boiler operation can achieve the maximal combustion efficiency and with significant reduction of the wear of the heating surface and fan energy consumption. The analysis was validated by field tests carried out in a 75 t/h CFB boiler. At full boiler load, when bed pressure drop was reduced from 7.3 to 3.2 kPa, the height of the dense zone in the lower furnace decreased, but the solid suspension density profile in the upper furnace and solid flow rate were barely influenced. Consequently, the average heat transfer coefficient in the furnace was kept nearly the same and the furnace temperature increment was less than 17{sup o}C. It was also found that the carbon content in the fly ash decreased first with decreasing bed pressure drop and then increased with further increasing bed pressure drop. The turning point with minimal carbon content was referred to as the point with optimal bed pressure drop. For this boiler, at the optimum point the bed pressure was around 5.7 kPa with the overall excess air ratio of 1.06. When the boiler was operated around this optimal point, not only the combustion efficiency was improved, but also fan energy consumption and wear of heating surface were reduced. 23 refs., 6 figs., 4 tabs.

  4. Sensing system for detection and control of deposition on pendant tubes in recovery and power boilers

    DOE Patents [OSTI]

    Kychakoff, George; Afromowitz, Martin A.; Hogle, Richard E.

    2008-10-14

    A system for detection and control of deposition on pendant tubes in recovery and power boilers includes one or more deposit monitoring sensors operating in infrared regions of about 4 or 8.7 microns and directly producing images of the interior of the boiler, or producing feeding signals to a data processing system for information to enable a distributed control system by which the boilers are operated to operate said boilers more efficiently. The data processing system includes an image pre-processing circuit in which a 2-D image formed by the video data input is captured, and includes a low pass filter for performing noise filtering of said video input. It also includes an image compensation system for array compensation to correct for pixel variation and dead cells, etc., and for correcting geometric distortion. An image segmentation module receives a cleaned image from the image pre-processing circuit for separating the image of the recovery boiler interior into background, pendant tubes, and deposition. It also accomplishes thresholding/clustering on gray scale/texture and makes morphological transforms to smooth regions, and identifies regions by connected components. An image-understanding unit receives a segmented image sent from the image segmentation module and matches derived regions to a 3-D model of said boiler. It derives a 3-D structure the deposition on pendant tubes in the boiler and provides the information about deposits to the plant distributed control system for more efficient operation of the plant pendant tube cleaning and operating systems.

  5. Ultra-precision positioning assembly

    DOE Patents [OSTI]

    Montesanti, Richard C.; Locke, Stanley F.; Thompson, Samuel L.

    2002-01-01

    An apparatus and method is disclosed for ultra-precision positioning. A slide base provides a foundational support. A slide plate moves with respect to the slide base along a first geometric axis. Either a ball-screw or a piezoelectric actuator working separate or in conjunction displaces the slide plate with respect to the slide base along the first geometric axis. A linking device directs a primary force vector into a center-line of the ball-screw. The linking device consists of a first link which directs a first portion of the primary force vector to an apex point, located along the center-line of the ball-screw, and a second link for directing a second portion of the primary force vector to the apex point. A set of rails, oriented substantially parallel to the center-line of the ball-screw, direct movement of the slide plate with respect to the slide base along the first geometric axis and are positioned such that the apex point falls within a geometric plane formed by the rails. The slide base, the slide plate, the ball-screw, and the linking device together form a slide assembly. Multiple slide assemblies can be distributed about a platform. In such a configuration, the platform may be raised and lowered, or tipped and tilted by jointly or independently displacing the slide plates.

  6. Ultra-wideband impedance sensor

    DOE Patents [OSTI]

    McEwan, Thomas E.

    1999-01-01

    The ultra-wideband impedance sensor (UWBZ sensor, or Z-sensor) is implemented in differential and single-ended configurations. The differential UWBZ sensor employs a sub-nanosecond impulse to determine the balance of an impedance bridge. The bridge is configured as a differential sample-and-hold circuit that has a reference impedance side and an unknown impedance side. The unknown impedance side includes a short transmission line whose impedance is a function of the near proximity of objects. The single-ended UWBZ sensor eliminates the reference side of the bridge and is formed of a sample and hold circuit having a transmission line whose impedance is a function of the near proximity of objects. The sensing range of the transmission line is bounded by the two-way travel time of the impulse, thereby eliminating spurious Doppler modes from large distant objects that would occur in a microwave CW impedance bridge. Thus, the UWBZ sensor is a range-gated proximity sensor. The Z-sensor senses the near proximity of various materials such as metal, plastic, wood, petroleum products, and living tissue. It is much like a capacitance sensor, yet it is impervious to moisture. One broad application area is the general replacement of magnetic sensors, particularly where nonferrous materials need to be sensed. Another broad application area is sensing full/empty levels in tanks, vats and silos, e.g., a full/empty switch in water or petroleum tanks.

  7. Ultra-wideband impedance sensor

    DOE Patents [OSTI]

    McEwan, T.E.

    1999-03-16

    The ultra-wideband impedance sensor (UWBZ sensor, or Z-sensor) is implemented in differential and single-ended configurations. The differential UWBZ sensor employs a sub-nanosecond impulse to determine the balance of an impedance bridge. The bridge is configured as a differential sample-and-hold circuit that has a reference impedance side and an unknown impedance side. The unknown impedance side includes a short transmission line whose impedance is a function of the near proximity of objects. The single-ended UWBZ sensor eliminates the reference side of the bridge and is formed of a sample and hold circuit having a transmission line whose impedance is a function of the near proximity of objects. The sensing range of the transmission line is bounded by the two-way travel time of the impulse, thereby eliminating spurious Doppler modes from large distant objects that would occur in a microwave CW impedance bridge. Thus, the UWBZ sensor is a range-gated proximity sensor. The Z-sensor senses the near proximity of various materials such as metal, plastic, wood, petroleum products, and living tissue. It is much like a capacitance sensor, yet it is impervious to moisture. One broad application area is the general replacement of magnetic sensors, particularly where nonferrous materials need to be sensed. Another broad application area is sensing full/empty levels in tanks, vats and silos, e.g., a full/empty switch in water or petroleum tanks. 2 figs.

  8. Supercritical Solubility of Binders Used in Explosive Formulations

    SciTech Connect (OSTI)

    David A. Bell

    2002-09-14

    The dissolution of polymers in supercritical carbon dioxide was measured using in-situ ultraviolet absorbance. This research was carried out to provide data to support the development of a new process to produce plastic-bonded explosive molding powder. Estane 5703, the polymer used to bind PBX 9501, was insoluble at the tested conditions. The dissolution of Kraton FG 1901 was tested at 27 to 100{degrees}C and 29 to 65 MPa. Only a small fraction of this polymer dissolved, and the quantity that dissolved increased with the polymer sample size. The tested polymer was polydisperse, and it is thought that the lowest molecular weight fraction of the polymer preferentially dissolved. Based on this observation, dissolution of the polymer prior to molding powder synthesis is recommended to obtain a uniform molding powder product. The dissolution of nearly monodisperse samples of polyethylacrylate were tested at 27 to 90{degrees}C and 10 to 65 MPa. The resulting solutions were very dilute, on the order of 100 mg/liter, and the solutions did not reach saturation during the 90 hour test period. The slow approach to saturation indicates that mass transfer rates may significantly affect process performance.

  9. Dynamics of excimer formation and decay in supercritical krypton

    SciTech Connect (OSTI)

    Holroyd, Richard A.; Cook, Andrew R.; Preses, Jack M.

    2009-12-14

    New infrared absorbing species are identified in the pulse radiolysis of supercritical Kr at high pressures. The species are believed to be excimers. Their formation and decay rates have been time resolved using the Laser Electron Accelerator Facility. An initial species, formed in less than 1 ns, absorbs at several wavelengths between 790 and 1300 nm; The decay of this species is initially fast, followed by a slower component; the decay rate increases with pressure. As this initial species decays a second excimer is formed absorbing at 830, 890, and 990 nm. The growth and decay rates of this excimer are also pressure dependent. A third excimer, absorbing between 1000 and 1200 nm grows at a rate similar to that of the decay of the second species. The decay rate of the third species is also pressure dependent; the lifetime increases from 9.4 ns at 109 bar to 49 ns at 15 bar. A kinetic mechanism is proposed that satisfactorily reproduces the experimental results. The first species is identified as a higher energy gerade triplet state excimer and the second as the singlet gerade state.

  10. Mixing coefficients for subchannel analyses with supercritical water

    SciTech Connect (OSTI)

    Vogt, Bastian; Laurien, Eckart; Class, Andreas G.; Schulenberg, Thomas

    2007-07-01

    This paper is related to pressure drop and mixing correlations which are used in subchannel codes. The commercial CFD code STAR-CD has been applied for central subchannels of a supercritical water reactor fuel assembly design. First, pressure drop coefficients for cross flow have been evaluated for this geometry using steady state calculations. Different from established correlations for cross flow in rod bundles, the effects of strong axial flow in the bundle have been taken into account for the presented geometry, flow conditions and fluid properties. In the second part of the paper the unsteady RANS CFD-method is applied and assessed with respect to the prediction of flow pulsation phenomena and turbulent mixing. The results are compared with experimental correlations for the turbulent mixing coefficient and the flow pulsation frequency. It is found that the applied unsteady RANS method is able to predict the flow pulsation frequency but over-predicts the turbulent mixing by a factor of around 3.5. (authors)

  11. Supercritical Fluid Extraction and Separation of Uranium from Other Actinides

    SciTech Connect (OSTI)

    Donna L. Quach; Bruce J. Mincher; Chien M. Wai

    2014-06-01

    This paper investigates the feasibility of separating uranium from other actinides by using supercritical fluid carbon dioxide (sc-CO2) as a solvent modified with tri-n-butylphosphate (TBP) for the development of an extraction and counter current stripping technique, which would be a more efficient and environmentally benign technology for used nuclear fuel reprocessing compared to traditional solvent extraction. Several actinides (U(VI), Np(VI), Pu(IV), and Am(III)) were extracted in sc-CO2 modified with TBP over a range of nitric acid concentrations and then the actinides were exposed to reducing and complexing agents to suppress their extractability. According to this study, the separation of uranium from plutonium in sc-CO2 modified with TBP was successful at nitric acid concentrations of less than 3 M in the presence of acetohydroxamic acid or oxalic acid, and the separation of uranium from neptunium was successful at nitric acid concentrations of less than 1 M in the presence of acetohydroxamic acid, oxalic acid, or sodium nitrite.

  12. Supercritical fluid molecular spray film deposition and powder formation

    DOE Patents [OSTI]

    Smith, Richard D.

    1986-01-01

    Solid films are deposited, or fine powders formed, by dissolving a solid material into a supercritical fluid solution at an elevated pressure and then rapidly expanding the solution through a short orifice into a region of relatively low pressure. This produces a molecular spray which is directed against a substrate to deposit a solid thin film thereon, or discharged into a collection chamber to collect a fine powder. Upon expansion and supersonic interaction with background gases in the low pressure region, any clusters of solvent are broken up and the solvent is vaporized and pumped away. Solute concentration in the solution is varied primarily by varying solution pressure to determine, together with flow rate, the rate of deposition and to control in part whether a film or powder is produced and the granularity of each. Solvent clustering and solute nucleation are controlled by manipulating the rate of expansion of the solution and the pressure of the lower pressure region. Solution and low pressure region temperatures are also controlled.

  13. Supercritical fluid molecular spray thin films and fine powders

    DOE Patents [OSTI]

    Smith, Richard D.

    1988-01-01

    Solid films are deposited, or fine powders formed, by dissolving a solid material into a supercritical fluid solution at an elevated pressure and then rapidly expanding the solution through a short orifice into a region of relatively low pressure. This produces a molecular spray which is directed against a substrate to deposit a solid thin film thereon, or discharged into a collection chamber to collect a fine powder. The solvent is vaporized and pumped away. Solution pressure is varied to determine, together with flow rate, the rate of deposition and to control in part whether a film or powder is produced and the granularity of each. Solution temperature is varied in relation to formation of a two-phase system during expansion to control porosity of the film or powder. A wide variety of film textures and powder shapes are produced of both organic and inorganic compounds. Films are produced with regular textural feature dimensions of 1.0-2.0 .mu.m down to a range of 0.01 to 0.1 .mu.m. Powders are formed in very narrow size distributions, with average sizes in the range of 0.02 to 5 .mu.m.

  14. Ultra Deep Wave Equation Imaging and Illumination

    SciTech Connect (OSTI)

    Alexander M. Popovici; Sergey Fomel; Paul Sava; Sean Crawley; Yining Li; Cristian Lupascu

    2006-09-30

    In this project we developed and tested a novel technology, designed to enhance seismic resolution and imaging of ultra-deep complex geologic structures by using state-of-the-art wave-equation depth migration and wave-equation velocity model building technology for deeper data penetration and recovery, steeper dip and ultra-deep structure imaging, accurate velocity estimation for imaging and pore pressure prediction and accurate illumination and amplitude processing for extending the AVO prediction window. Ultra-deep wave-equation imaging provides greater resolution and accuracy under complex geologic structures where energy multipathing occurs, than what can be accomplished today with standard imaging technology. The objective of the research effort was to examine the feasibility of imaging ultra-deep structures onshore and offshore, by using (1) wave-equation migration, (2) angle-gathers velocity model building, and (3) wave-equation illumination and amplitude compensation. The effort consisted of answering critical technical questions that determine the feasibility of the proposed methodology, testing the theory on synthetic data, and finally applying the technology for imaging ultra-deep real data. Some of the questions answered by this research addressed: (1) the handling of true amplitudes in the downward continuation and imaging algorithm and the preservation of the amplitude with offset or amplitude with angle information required for AVO studies, (2) the effect of several imaging conditions on amplitudes, (3) non-elastic attenuation and approaches for recovering the amplitude and frequency, (4) the effect of aperture and illumination on imaging steep dips and on discriminating the velocities in the ultra-deep structures. All these effects were incorporated in the final imaging step of a real data set acquired specifically to address ultra-deep imaging issues, with large offsets (12,500 m) and long recording time (20 s).

  15. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Suuberg; Eric Eddings; Larry Baxter

    2002-01-31

    This is the sixth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. Preliminary results from laboratory and field tests of a corrosion probe to predict waterwall wastage indicate good agreement between the electrochemical noise corrosion rates predicted by the probe and corrosion rates measured by a surface profilometer. Four commercial manufacturers agreed to provide catalyst samples to the program. BYU has prepared two V/Ti oxide catalysts (custom, powder form) containing commercially relevant concentrations of V oxide and one containing a W oxide promoter. Two pieces of experimental apparatus being built at BYU to carry out laboratory-scale investigations of SCR catalyst deactivation are nearly completed. A decision was made to carry out the testing at full-scale power plants using a slipstream of gas instead of at the University of Utah pilot-scale coal combustor as originally planned. Design of the multi-catalyst slipstream reactor was completed during this quarter. One utility has expressed interest in hosting a long-term test at one of their plants that co-fire wood with coal. Tests to study ammonia adsorption onto fly ash have clearly established that the only routes that can play a role in binding significant amounts of ammonia to the ash surface, under practical ammonia slip conditions, are those that must involve co-adsorbates.

  16. Use of a polishing scrubber with a fluid bed boiler

    SciTech Connect (OSTI)

    Toher, J.G.

    1996-12-31

    Once viewed as {open_quotes}competitive{close_quotes} technologies, the circulating dry scrubber (CDS){reg_sign} and circulating fluid bed (CFB) boiler are being used together to achieve enhanced performance with lower overall costs. The need to understand the synergy between these two technologies is driven by deregulation of the power industry and the 1990 Clean Air Act Amendments. Deregulation of power production in the US has spurred the growth of Independent Power Producers (IPP) who are responding to Industry`s demand for lower cost fuels, and close attention to annual operating costs. Utilities have to provide {open_quotes}open{close_quotes} access to their transmission lines allowing various IPP`s to connect with the end user. Industrial users can now choose from one of several sources of electricity with prices per kilowatt hour that are much lower than what they are currently being charged. The race is on to reduce power production costs and fuel can be the key in many cases. IPP`s and industry are banding together in very logical ways that can benefit both. Industry`s byproducts with heating value can be sold {open_quotes}over the fence{close_quotes} to an IPP who provides the industry with low cost steam and or electricity in return. However, many alternative lower cost fuels also have a higher emissions potential for criteria pollutants such a SO{sub 2}, NO{sub X}, particulate, or other emissions such as VOC`s and mercury which are more recently receiving attention. Cost effective management of these environmental issues must be an integral part of the project planning process. Three such cases are examined that involve the use of CFB`s with the CDS{reg_sign} as a polishing scrubber for SO{sub 2}. The first two cases involve repowering of existing facilities with petroleum coke as the fuel. The last case involves a new facility powered with low sulfur coal.

  17. Novel Supercritical Carbon Dioxide Power Cycle Utilizing Pressured Oxy-combustion in Conjunction with Cryogenic Compression

    SciTech Connect (OSTI)

    Brun, Klaus; McClung, Aaron; Davis, John

    2014-03-31

    The team of Southwest Research Institute® (SwRI) and Thar Energy LLC (Thar) applied technology engineering and economic analysis to evaluate two advanced oxy-combustion power cycles, the Cryogenic Pressurized Oxy-combustion Cycle (CPOC), and the Supercritical Oxy-combustion Cycle. This assessment evaluated the performance and economic cost of the two proposed cycles with carbon capture, and included a technology gap analysis of the proposed technologies to determine the technology readiness level of the cycle and the cycle components. The results of the engineering and economic analysis and the technology gap analysis were used to identify the next steps along the technology development roadmap for the selected cycle. The project objectives, as outlined in the FOA, were 90% CO{sub 2} removal at no more than a 35% increase in cost of electricity (COE) as compared to a Supercritical Pulverized Coal Plant without CO{sub 2} capture. The supercritical oxy-combustion power cycle with 99% carbon capture achieves a COE of $121/MWe. This revised COE represents a 21% reduction in cost as compared to supercritical steam with 90% carbon capture ($137/MWe). However, this represents a 49% increase in the COE over supercritical steam without carbon capture ($80.95/MWe), exceeding the 35% target. The supercritical oxy-combustion cycle with 99% carbon capture achieved a 37.9% HHV plant efficiency (39.3% LHV plant efficiency), when coupling a supercritical oxy-combustion thermal loop to an indirect supercritical CO{sub 2} (sCO{sub 2}) power block. In this configuration, the power block achieved 48% thermal efficiency for turbine inlet conditions of 650°C and 290 atm. Power block efficiencies near 60% are feasible with higher turbine inlet temperatures, however a design tradeoff to limit firing temperature to 650°C was made in order to use austenitic stainless steels for the high temperature pressure vessels and piping and to minimize the need for advanced turbomachinery features

  18. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Lin, Yuehe

    1998-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent is described. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  19. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Lin, Y.

    1998-06-23

    A method is described for extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

  20. Method and apparatus for dissociating metals from metal compounds extracted into supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M.; Hunt, Fred H.; Smart, Neil G.; Lin, Yuehe

    2000-01-01

    A method for dissociating metal-ligand complexes in a supercritical fluid by treating the metal-ligand complex with heat and/or reducing or oxidizing agents is described. Once the metal-ligand complex is dissociated, the resulting metal and/or metal oxide form fine particles of substantially uniform size. In preferred embodiments, the solvent is supercritical carbon dioxide and the ligand is a .beta.-diketone such as hexafluoroacetylacetone or dibutyldiacetate. In other preferred embodiments, the metals in the metal-ligand complex are copper, silver, gold, tungsten, titanium, tantalum, tin, or mixtures thereof. In preferred embodiments, the reducing agent is hydrogen. The method provides an efficient process for dissociating metal-ligand complexes and produces easily-collected metal particles free from hydrocarbon solvent impurities. The ligand and the supercritical fluid can be regenerated to provide an economic, efficient process.

  1. Method for separating metal chelates from other materials based on solubilities in supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Phelps, Cindy

    2001-01-01

    A method for separating a desired metal or metalloi from impurities using a supercritical extraction process based on solubility differences between the components, as well as the ability to vary the solvent power of the supercritical fluid, is described. The use of adduct-forming agents, such as phosphorous-containing ligands, to separate metal or metalloid chelates in such processes is further disclosed. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones; phosphine oxides, such as trialkylphosphine oxides, triarylphosphine oxides and alkylarylphosphine oxides; phosphinic acids; carboxylic acids; phosphates, such as trialkylphosphates, triarylphosphates and alkylarylphosphates; crown ethers; dithiocarbamates; phosphine sulfides; phosphorothioic acids; thiophosphinic acids; halogenated analogs of these chelating agents; and mixtures of these chelating agents. In especially preferred embodiments, at least one of the chelating agents is fluorinated.

  2. ISSUANCE: 2014-11-13 Energy Conservation Standards for Commercial Packaged Boilers: Public Meeting and Availability of the Preliminary Technical Support Document

    Broader source: Energy.gov [DOE]

    Energy Conservation Standards for Commercial Packaged Boilers: Public Meeting and Availability of the Preliminary Technical Support Document

  3. Summary of EPA Final Rules for Air Toxic Standards for Industrial, Commercial, and Institutional (ICI) Boilers and Process Heaters, February 2013

    Office of Energy Efficiency and Renewable Energy (EERE)

    Article overviewing key requirements for the reconsideration area and major source boiler MACT rules and estimated compliance cost impacts

  4. Composite coatings for elevated temperature erosion-corrosion protection in fossil-fueled boilers

    SciTech Connect (OSTI)

    Verstak, A.; Wang, B.; Baranovski, V.; Beliaev, A.

    1998-12-31

    Fluidized bed combustors components suffer severe erosion, frequently accomplished by corrosive gases attack at elevated temperatures. The tubes damage rate depends on the boiler design bed constituents and combustion parameters, however an accelerated metal wastage is usually found in the same specific areas of different boilers. New HVOF sprayed coatings are developed for the tube erosion-corrosion protection, based on Cr{sub 2}C{sub 2}/Ni-Cr, Cr-Ti-C/Ni-Cr-Mo, and Al{sub 2}O{sub 3}/NiAl composite materials. The combustion arc Fe-Cr-C coatings were found as an economical solution for relatively low erosion rate zones. The coatings properties and behavior under simulated elevated temperature erosion conditions and in the operating boilers are discussed.

  5. Maximum Achievable Control Technology for New Industrial Boilers (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01

    As part of Clean Air Act 90 (CAAA90, the EPA on February 26, 2004, issued a final rulethe National Emission Standards for Hazardous Air Pollutants (NESHAP) to reduce emissions of hazardous air pollutants (HAPs) from industrial, commercial, and institutional boilers and process heaters. The rule requires industrial boilers and process heaters to meet limits on HAP emissions to comply with a Maximum Achievable Control Technology (MACT) floor level of control that is the minimum level such sources must meet to comply with the rule. The major HAPs to be reduced are hydrochloric acid, hydrofluoric acid, arsenic, beryllium, cadmium, and nickel. The EPA predicts that the boiler MACT rule will reduce those HAP emissions from existing sources by about 59,000 tons per year in 2005.

  6. Presentation of a prototype absorption boiler. The features and possible developments of the system

    SciTech Connect (OSTI)

    Meyer, M.

    1982-01-01

    Tests on an absorption-type space-heating boiler confirmed that the absorption principle holds promise as a means of recovering the heat energy in the water vapor of the combustion products at a temperature much higher than allowed in current condensation-boiler designs. The system is basically a conventional boiler with an added lithium-bromide absorption circuit. Because the absorbent separates the water from the rest of the stack gases, the condensate is less acidic - and thus not as corrosive - as that produced in other condensing systems. However, because the complex structure of the recuperator poses significant maintenance problems, the absorption heating system would probably be most practical in large multifamily or industrial space-heating applications.

  7. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Poe, R.L.; Morrison, J.L.; Xie, Jianyang; Walsh, P.M.; Schobert, H.H.; Scaroni, A.W.

    1992-05-29

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the capability of effectively firing SCCWS in an industrial boiler designed for oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with less than 3.0 wt.% ash and 0.9 wt.% sulfur) can effectively be burned in an oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels.

  8. Implications of the Clean Air Act acid rain title on industrial boilers

    SciTech Connect (OSTI)

    Maibodi, M. )

    1991-11-01

    This paper discusses the impacts of the 1990 Clean Air Act Amendments related to acid rain controls, as they apply to industrial boilers. Emphasis is placed on explaining the Title IV provisions of the Amendments that permit nonutility sources to participate in the SO{sub 2} allowance system. The allowance system, as it pertains to industrial boiler operators, is described, and the opportunities for operators to trade and/or sell SO{sub 2} emission credits is discussed. The paper also reviews flue gas desulfurization system technologies available for industrial boiler operators who may choose to participate in the system. Furnace sorbent injection, advanced silicate process, lime spray drying, dry sorbent injection, and limestone scrubbing are described, including statements of their SO{sub 2} removing capability, commercial status, and costs. Capital costs, levelized costs and cost-effectiveness are presented for these technologies.

  9. Engineering development of advanced coal-fired low-emissions boiler systems. Quarterly report, April 1--June 30, 1997

    SciTech Connect (OSTI)

    1997-12-31

    This progress report is on the project by Babcock and Wilcox Company to develop an advanced coal-fired low-emissions boiler system. The topics of the report include project management, the NO{sub x} subsystem, the SO{sub 2}/particulate/air toxics/solid by-product subsystem, boiler subsystem, balance of plant subsystem, and controls and sensors subsystems.

  10. Scaling considerations for a multi-megawatt class supercritical CO2 brayton cycle and commercialization.

    SciTech Connect (OSTI)

    Fleming, Darryn D.; Holschuh, Thomas Vernon,; Conboy, Thomas M.; Pasch, James Jay; Wright, Steven Alan; Rochau, Gary Eugene; Fuller, Robert Lynn

    2013-11-01

    Small-scale supercritical CO2 demonstration loops are successful at identifying the important technical issues that one must face in order to scale up to larger power levels. The Sandia National Laboratories supercritical CO2 Brayton cycle test loops are identifying technical needs to scale the technology to commercial power levels such as 10 MWe. The small size of the Sandia 1 MWth loop has demonstration of the split flow loop efficiency and effectiveness of the Printed Circuit Heat Exchangers (PCHXs) leading to the design of a fully recuperated, split flow, supercritical CO2 Brayton cycle demonstration system. However, there were many problems that were encountered, such as high rotational speeds in the units. Additionally, the turbomachinery in the test loops need to identify issues concerning the bearings, seals, thermal boundaries, and motor controller problems in order to be proved a reliable power source in the 300 kWe range. Although these issues were anticipated in smaller demonstration units, commercially scaled hardware would eliminate these problems caused by high rotational speeds at small scale. The economic viability and development of the future scalable 10 MWe solely depends on the interest of DOE and private industry. The Intellectual Property collected by Sandia proves that the ~10 MWe supercritical CO2 power conversion loop to be very beneficial when coupled to a 20 MWth heat source (either solar, geothermal, fossil, or nuclear). This paper will identify a commercialization plan, as well as, a roadmap from the simple 1 MWth supercritical CO2 development loop to a power producing 10 MWe supercritical CO2 Brayton loop.

  11. Black liquor combustion validated recovery boiler modeling, five-year report

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1996-08-01

    The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

  12. Summary on the depressurization from supercritical pressure conditions

    SciTech Connect (OSTI)

    Anderson, M.; Chen, Y.; Ammirable, L.; Yamada, K.

    2012-07-01

    When a fluid discharges from a high pressure and temperature system, a 'choking' or critical condition occurs, and the flow rate becomes independent of the downstream pressure. During a postulated loss of coolant accident (LOCA) of a water reactor the break flow will be subject to this condition. An accurate estimation of the critical flow rate is important for the evaluation of the reactor safety, because this flow rate controls the loss of coolant inventory and energy from the system, and thus has a significant effect on the accident consequences[1]. In the design of safety systems for a super critical water reactor (SCWR), postulated LOCA transients are particularly important due to the lower coolant inventory compared to a typical PWR for the same power output. This lower coolant inventory would result in a faster transient response of the SCWR, and hence accurate prediction of the critical discharge is mandatory. Under potential two-phase conditions critical flow is dominated by the vapor content or quality of the vapor, which is closely related with the onset of vaporization and the interfacial interaction between phases [2]. This presents a major challenge for the estimation of the flow rate due to the lack of the knowledge of those processes, especially under the conditions of interest for the SCWR. According to the limited data of supercritical fluids, the critical flows at conditions above the pseudo-critical point seem to be fairly stable and consistent with the subcritical homogeneous equilibrium model (HEM) model predictions, while having a lower flow rate than those in the two-phase region. Thus the major difficulty in the prediction of the depressurization flow rates remains in the region where two phases co-exist at the top of the vapor dome. In this region, the flow rate is strongly affected by the nozzle geometry and tends to be unstable. Various models for this region have been developed with different assumptions, e.g. the HEM and Moody model [3

  13. Performance improvement options for the supercritical carbon dioxide brayton cycle.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. J.; Nuclear Engineering Division

    2008-07-17

    The supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle is under development at Argonne National Laboratory as an advanced power conversion technology for Sodium-Cooled Fast Reactors (SFRs) as well as other Generation IV advanced reactors as an alternative to the traditional Rankine steam cycle. For SFRs, the S-CO{sub 2} Brayton cycle eliminates the need to consider sodium-water reactions in the licensing and safety evaluation, reduces the capital cost of the SFR plant, and increases the SFR plant efficiency. Even though the S-CO{sub 2} cycle has been under development for some time and optimal sets of operating parameters have been determined, those earlier development and optimization studies have largely been directed at applications to other systems such as gas-cooled reactors which have higher operating temperatures than SFRs. In addition, little analysis has been carried out to investigate cycle configurations deviating from the selected 'recompression' S-CO{sub 2} cycle configuration. In this work, several possible ways to improve S-CO{sub 2} cycle performance for SFR applications have been identified and analyzed. One set of options incorporates optimization approaches investigated previously, such as variations in the maximum and minimum cycle pressure and minimum cycle temperature, as well as a tradeoff between the component sizes and the cycle performance. In addition, the present investigation also covers options which have received little or no attention in the previous studies. Specific options include a 'multiple-recompression' cycle configuration, intercooling and reheating, as well as liquid-phase CO{sub 2} compression (pumping) either by CO{sub 2} condensation or by a direct transition from the supercritical to the liquid phase. Some of the options considered did not improve the cycle efficiency as could be anticipated beforehand. Those options include: a double recompression cycle, intercooling between the compressor stages, and reheating

  14. Selective Extraction of Uranium from Liquid or Supercritical Carbon Dioxide

    SciTech Connect (OSTI)

    Farawila, Anne F.; O'Hara, Matthew J.; Wai, Chien M.; Taylor, Harry Z.; Liao, Yu-Jung

    2012-07-31

    Current liquid-liquid extraction processes used in recycling irradiated nuclear fuel rely on (1) strong nitric acid to dissolve uranium oxide fuel, and (2) the use of aliphatic hydrocarbons as a diluent in formulating the solvent used to extract uranium. The nitric acid dissolution process is not selective. It dissolves virtually the entire fuel meat which complicates the uranium extraction process. In addition, a solvent washing process is used to remove TBP degradation products, which adds complexity to the recycling plant and increases the overall plant footprint and cost. A liquid or supercritical carbon dioxide (l/sc -CO2) system was designed to mitigate these problems. Indeed, TBP nitric acid complexes are highly soluble in l/sc -CO2 and are capable of extracting uranium directly from UO2, UO3 and U3O8 powders. This eliminates the need for total acid dissolution of the irradiated fuel. Furthermore, since CO2 is easily recycled by evaporation at room temperature and pressure, it eliminates the complex solvent washing process. In this report, we demonstrate: (1) A reprocessing scheme starting with the selective extraction of uranium from solid uranium oxides into a TBP-HNO3 loaded Sc-CO2 phase, (2) Back extraction of uranium into an aqueous phase, and (3) Conversion of recovered purified uranium into uranium oxide. The purified uranium product from step 3 can be disposed of as low level waste, or mixed with enriched uranium for use in a reactor for another fuel cycle. After an introduction on the concept and properties of supercritical fluids, we first report the characterization of the different oxides used for this project. Our extraction system and our online monitoring capability using UV-Vis absorbance spectroscopy directly in sc-CO2 is then presented. Next, the uranium extraction efficiencies and kinetics is demonstrated for different oxides and under different physical and chemical conditions: l/sc -CO2 pressure and temperature, TBP/HNO3 complex used

  15. Investigations of supercritical CO2 Rankine cycles for geothermal power plants

    SciTech Connect (OSTI)

    Sabau, Adrian S; Yin, Hebi; Qualls, A L; McFarlane, Joanna

    2011-01-01

    Supercritical CO2 Rankine cycles are investigated for geothermal power plants. The system of equations that describe the thermodynamic cycle is solved using a Newton-Rhapson method. This approach allows a high computational efficiency of the model when thermophysical properties of the working fluid depend strongly on the temperature and pressure. Numerical simulation results are presented for different cycle configurations in order to assess the influences of heat source temperature, waste heat rejection temperatures and internal heat exchanger design on cycle efficiency. The results show that thermodynamic cycle efficiencies above 10% can be attained with the supercritical brayton cycle while lower efficiencies can be attained with the transcritical CO2 Rankine cycle.

  16. Supercritical Water Nuclear Steam Supply System: Innovations In Materials, Neutronics & Thermal-Hydraulics

    SciTech Connect (OSTI)

    Mark Anderson; M.L. Corradini; K. Sridharan; P. WIlson; D. Cho; T.K. Kim; S. Lomperski

    2004-09-02

    In the 1990's supercritical light-water reactors were considered in conceptual designs. A nuclear reactor cooled by supercritical waster would have a much higher thermal efficiency with a once-through direct power cycle, and could be based on standardized water reactor components (light water or heavy water). The theoretical efficiency could be improved by more than 33% over that of other water reactors and could be simplified with higher reliability; e.g., a boiling water reactor without steam separators or dryers.

  17. High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recompression Cycle | Department of Energy Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. csp_review_meeting_042313_sullivan.pdf (1.45 MB) More Documents & Publications High-Efficiency Low-Cost Solar Receiver for Use in a

  18. Brown coal conversion under the action of supercritical water

    SciTech Connect (OSTI)

    A.A. Vostrikov; O.N. Fedyaeva; S.A. Psarov; D.Y. Dubov; M.Ya. Sokol

    2007-10-15

    A test bench was developed and the conversion of the organic matter of coal (OMC) in supercritical water (SCW) was studied under conditions of a continuous supply of a water-coal suspension to a vertical flow reactor at 390-760{sup o}C and a pressure of 30 MPa. From 44 to 63% OMC was released as liquid and gaseous products from coal particles (from the water-coal supension) during the time of fall to the reactor. This stage was referred to as the dynamic conversion of coal. The particles passed through the stage of the dynamic conversion of coal did not agglomerate in the reactor in the subsequent process of batch conversion in a coal layer at T = 550-760{sup o}C. The volatile products of the overall process of the dynamic and batch conversion of coal included saturated hydrocarbons (CH{sub 4} and C{sub 2}H{sub 6}), aromatic hydrocarbons (C{sub 6}H{sub 6}, C{sub 7}H{sub 8}, and C{sub 8}H{sub 10}), synthesis gas (H{sub 2} and CO), and CO{sub 2}. At T < 600{sup o}C, CO{sub 2} and CO were the degradation products of oxygen-containing OMC fragments, whereas they also resulted from the decomposition of water molecules at higher temperatures in accordance with the reaction c + H{sub 2}O = CO + H{sub 2}. The mechanisms were considered, and the parameters responsible for the dynamic conversion of coal were calculated.

  19. Corrosion of boiler tube alloys in refuse firing: Shredded vs bulk refuse

    SciTech Connect (OSTI)

    Krause, H.H. ); Daniel, P.L.; Blue, J.D. )

    1994-08-01

    Results of corrosion probe exposures at two mass burning incinerators were compared with those conducted in a unit burning refuse-derived fuel. Tests were conducted with carbon steel, low-alloy steels, stainless steels, and high nickel-chromium alloys. Corrosion rates at similar metal and gas temperatures were essentially the same for both types of fuel. Boiler tube performance in the waterwalls of other incinerators confirmed these results. Boiler design and operating conditions appear to be more important factors in tube wastage than the extent of refuse processing.

  20. Air toxics evaluation of ABB Combustion Engineering Low-Emission Boiler Systems

    SciTech Connect (OSTI)

    Wesnor, J.D.

    1993-10-26

    The specific goals of the program are to identify air toxic compounds that might be emmitted from the new boiler with its various Air Pollution Control device for APCD alternatives in levels of regulatory concern. For the compounds thought to be of concern, potential air toxic control methodologies will be suggested and a Test Protocol will be written to be used in the Proof of Concept and full scale tests. The following task was defined: Define Replations and Standards; Identify Air Toxic Pollutants of Interest to Interest to Utility Boilers; Assesment of Air Toxic By-Products; State of the Art Assessment of Toxic By-Product Control Technologies; and Test Protocol Definition.