Sample records for ultra supercritical boilers

  1. Materials development for ultra-supercritical boilers

    SciTech Connect (OSTI)

    NONE

    2005-09-30T23:59:59.000Z

    Progress is reported on a US Department of Energy project to develop high temperature, corrosion resistant alloys for use in ultra-supercritical steam cycles. The aim is to achieve boiler operation at 1,400{sup o}F/5,000 psi steam conditions with 47% net cycle efficiency. Most ferritic steel tested such as T92 and Save 12 showed severe corrosion. Nickel-based alloys, especially IN 740 and CCA 617, showed greatest resistance to oxidation with no evidence of exfoliation. Laboratory and in-plant tests have begun. 2 figs.

  2. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study

    SciTech Connect (OSTI)

    Zhen Fan; Steve Goidich; Archie Robertson; Song Wu

    2006-06-30T23:59:59.000Z

    Electric utility interest in supercritical pressure steam cycles has revived in the United States after waning in the 1980s. Since supercritical cycles yield higher plant efficiencies than subcritical plants along with a proportional reduction in traditional stack gas pollutants and CO{sub 2} release rates, the interest is to pursue even more advanced steam conditions. The advantages of supercritical (SC) and ultra supercritical (USC) pressure steam conditions have been demonstrated in the high gas temperature, high heat flux environment of large pulverized coal-fired (PC) boilers. Interest in circulating fluidized bed (CFB) combustion, as an alternative to PC combustion, has been steadily increasing. Although CFB boilers as large as 300 MWe are now in operation, they are drum type, subcritical pressure units. With their sizes being much smaller than and their combustion temperatures much lower than those of PC boilers (300 MWe versus 1,000 MWe and 1600 F versus 3500 F), a conceptual design study was conducted herein to investigate the technical feasibility and economics of USC CFB boilers. The conceptual study was conducted at 400 MWe and 800 MWe nominal plant sizes with high sulfur Illinois No. 6 coal used as the fuel. The USC CFB plants had higher heating value efficiencies of 40.6 and 41.3 percent respectively and their CFB boilers, which reflect conventional design practices, can be built without the need for an R&D effort. Assuming construction at a generic Ohio River Valley site with union labor, total plant costs in January 2006 dollars were estimated to be $1,551/kW and $1,244/kW with costs of electricity of $52.21/MWhr and $44.08/MWhr, respectively. Based on the above, this study has shown that large USC CFB boilers are feasible and that they can operate with performance and costs that are competitive with comparable USC PC boilers.

  3. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect (OSTI)

    David W. Gandy; John P. Shingledecker

    2011-04-11T23:59:59.000Z

    Forced outages and boiler unavailability in conventional coal-fired fossil power plants is most often caused by fireside corrosion of boiler waterwalls. Industry-wide, the rate of wall thickness corrosion wastage of fireside waterwalls in fossil-fired boilers has been of concern for many years. It is significant that the introduction of nitrogen oxide (NOx) emission controls with staged burners systems has increased reported waterwall wastage rates to as much as 120 mils (3 mm) per year. Moreover, the reducing environment produced by the low-NOx combustion process is the primary cause of accelerated corrosion rates of waterwall tubes made of carbon and low alloy steels. Improved coatings, such as the MCrAl nanocoatings evaluated here (where M is Fe, Ni, and Co), are needed to reduce/eliminate waterwall damage in subcritical, supercritical, and ultra-supercritical (USC) boilers. The first two tasks of this six-task project-jointly sponsored by EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)-have focused on computational modeling of an advanced MCrAl nanocoating system and evaluation of two nanocrystalline (iron and nickel base) coatings, which will significantly improve the corrosion and erosion performance of tubing used in USC boilers. The computational model results showed that about 40 wt.% is required in Fe based nanocrystalline coatings for long-term durability, leading to a coating composition of Fe-25Cr-40Ni-10 wt.% Al. In addition, the long term thermal exposure test results further showed accelerated inward diffusion of Al from the nanocrystalline coatings into the substrate. In order to enhance the durability of these coatings, it is necessary to develop a diffusion barrier interlayer coating such TiN and/or AlN. The third task 'Process Advanced MCrAl Nanocoating Systems' of the six-task project jointly sponsored by the Electric Power Research Institute, EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)- has focused on processing of advanced nanocrystalline coating systems and development of diffusion barrier interlayer coatings. Among the diffusion interlayer coatings evaluated, the TiN interlayer coating was found to be the optimum one. This report describes the research conducted under the Task 3 workscope.

  4. Computation Modeling and Assessment of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect (OSTI)

    J. Shingledecker; D. Gandy; N. Cheruvu; R. Wei; K. Chan

    2011-06-21T23:59:59.000Z

    Forced outages and boiler unavailability of coal-fired fossil plants is most often caused by fire-side corrosion of boiler waterwalls and tubing. Reliable coatings are required for Ultrasupercritical (USC) application to mitigate corrosion since these boilers will operate at a much higher temperatures and pressures than in supercritical (565 C {at} 24 MPa) boilers. Computational modeling efforts have been undertaken to design and assess potential Fe-Cr-Ni-Al systems to produce stable nanocrystalline coatings that form a protective, continuous scale of either Al{sub 2}O{sub 3} or Cr{sub 2}O{sub 3}. The computational modeling results identified a new series of Fe-25Cr-40Ni with or without 10 wt.% Al nanocrystalline coatings that maintain long-term stability by forming a diffusion barrier layer at the coating/substrate interface. The computational modeling predictions of microstructure, formation of continuous Al{sub 2}O{sub 3} scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. Advanced coatings, such as MCrAl (where M is Fe, Ni, or Co) nanocrystalline coatings, have been processed using different magnetron sputtering deposition techniques. Several coating trials were performed and among the processing methods evaluated, the DC pulsed magnetron sputtering technique produced the best quality coating with a minimum number of shallow defects and the results of multiple deposition trials showed that the process is repeatable. scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. The cyclic oxidation test results revealed that the nanocrystalline coatings offer better oxidation resistance, in terms of weight loss, localized oxidation, and formation of mixed oxides in the Al{sub 2}O{sub 3} scale, than widely used MCrAlY coatings. However, the ultra-fine grain structure in these coatings, consistent with the computational model predictions, resulted in accelerated Al diffusion from the coating into the substrate. An effective diffusion barrier interlayer coating was developed to prevent inward Al diffusion. The fire-side corrosion test results showed that the nanocrystalline coatings with a minimum number of defects have a great potential in providing corrosion protection. The coating tested in the most aggressive environment showed no evidence of coating spallation and/or corrosion attack after 1050 hours exposure. In contrast, evidence of coating spallation in isolated areas and corrosion attack of the base metal in the spalled areas were observed after 500 hours. These contrasting results after 500 and 1050 hours exposure suggest that the premature coating spallation in isolated areas may be related to the variation of defects in the coating between the samples. It is suspected that the cauliflower-type defects in the coating were presumably responsible for coating spallation in isolated areas. Thus, a defect free good quality coating is the key for the long-term durability of nanocrystalline coatings in corrosive environments. Thus, additional process optimization work is required to produce defect-free coatings prior to development of a coating application method for production parts.

  5. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect (OSTI)

    David W. Gandy; John P. Shingledecker

    2011-05-11T23:59:59.000Z

    Coal-fired power plants are a significant part of the nation���¢��������s power generating capacity, currently accounting for more than 55% of the country���¢��������s total electricity production. Extending the reliable lifetimes of fossil fired boiler components and reducing the maintenance costs are essential for economic operation of power plants. Corrosion and erosion are leading causes of superheater and reheater boiler tube failures leading to unscheduled costly outages. Several types of coatings and weld overlays have been used to extend the service life of boiler tubes; however, the protection afforded by such materials was limited approximately one to eight years. Power companies are more recently focused in achieving greater plant efficiency by increasing steam temperature and pressure into the advanced-ultrasupercritical (A-USC) condition with steam temperatures approaching 760�������°C (1400�������°F) and operating pressures in excess of 35MPa (5075 psig). Unfortunately, laboratory and field testing suggests that the resultant fireside environment when operating under A-USC conditions can potentially cause significant corrosion to conventional and advanced boiler materials1-2. In order to improve reliability and availability of fossil fired A-USC boilers, it is essential to develop advanced nanostructured coatings that provide excellent corrosion and erosion resistance without adversely affecting the other properties such as toughness and thermal fatigue strength of the component material.

  6. Steam Oxidation and Chromia Evaporation in Ultra-Supercritical Steam Boilers and Turbines

    SciTech Connect (OSTI)

    Gordon H. Holcomb

    2009-01-01T23:59:59.000Z

    U.S. Department of Energy’s goals include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 °C and 340 atm, so-called ultra-supercritical (USC) conditions. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism. A methodology to calculate Cr evaporation rates from chromia scales was developed and combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles and to predict the time until breakaway oxidation. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. Alloy additions such as Ti may allow for a reduction in evaporation rate with time, mitigating the deleterious effects of chromia evaporation.

  7. Ultra Supercritical Steamside Oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

    2005-01-01T23:59:59.000Z

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  8. ULTRA-SUPERCRITICAL STEAM CORROSION

    SciTech Connect (OSTI)

    Holcomb, G.R.; Alman, D.E.; Bullard, S.B.; Covino, B.S., Jr.; Cramer, S.D.; Ziomek-Moroz, M.

    2003-04-22T23:59:59.000Z

    Efficiency increases in fossil energy boilers and steam turbines are being achieved by increasing the temperature and pressure at the turbine inlets well beyond the critical point of water. To allow these increases, advanced materials are needed that are able to withstand the higher temperatures and pressures in terms of strength, creep, and oxidation resistance. As part of a larger collaborative effort, the Albany Research Center (ARC) is examining the steam-side oxidation behavior for ultrasupercritical (USC) steam turbine applications. Initial tests are being done on six alloys identified as candidates for USC steam boiler applications: ferritic alloy SAVE12, austenitic alloy Super 304H, the high Cr-high Ni alloy HR6W, and the nickel-base superalloys Inconel 617, Haynes 230, and Inconel 740. Each of these alloys has very high strength for its alloy type. Three types of experiments are planned: cyclic oxidation in air plus steam at atmospheric pressure, thermogravimetric ana lysis (TGA) in steam at atmospheric pressure, and exposure tests in supercritical steam up to 650 C (1202 F) and 34.5 MPa (5000 psi). The atmospheric pressure tests, combined with supercritical exposures at 13.8, 20.7, 24.6, and 34.5 MPa (2000, 3000, 4000, and 5000 psi) should allow the determination of the effect of pressure on the oxidation process.

  9. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward

    2007-01-01T23:59:59.000Z

    allow ultra-supercritical boilers to achieve still higherthat supercritical-coal boilers, at least in the 1970s, didGW/year) by type of boiler. Source: [25]. Net Efficiency (

  10. Ultra supercritical turbines--steam oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Ziomek-Moroz, Margaret; Alman, David E.

    2004-01-01T23:59:59.000Z

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy?s Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538?C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620?C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which would require steam temperatures of up to 760?C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  11. Model-free adaptive control of supercritical circulating fluidized-bed boilers

    DOE Patents [OSTI]

    Cheng, George Shu-Xing; Mulkey, Steven L

    2014-12-16T23:59:59.000Z

    A novel 3-Input-3-Output (3.times.3) Fuel-Air Ratio Model-Free Adaptive (MFA) controller is introduced, which can effectively control key process variables including Bed Temperature, Excess O2, and Furnace Negative Pressure of combustion processes of advanced boilers. A novel 7-input-7-output (7.times.7) MFA control system is also described for controlling a combined 3-Input-3-Output (3.times.3) process of Boiler-Turbine-Generator (BTG) units and a 5.times.5 CFB combustion process of advanced boilers. Those boilers include Circulating Fluidized-Bed (CFB) Boilers and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  12. Economic Analysis for Conceptual Design of Supercritical O2-Based PC Boiler

    SciTech Connect (OSTI)

    Andrew Seltzer; Archie Robertson

    2006-09-01T23:59:59.000Z

    This report determines the capital and operating costs of two different oxygen-based, pulverized coal-fired (PC) power plants and compares their economics to that of a comparable, air-based PC plant. Rather than combust their coal with air, the oxygen-based plants use oxygen to facilitate capture/removal of the plant CO{sub 2} for transport by pipeline to a sequestering site. To provide a consistent comparison of technologies, all three plants analyzed herein operate with the same coal (Illinois No 6), the same site conditions, and the same supercritical pressure steam turbine (459 MWe). In the first oxygen-based plant, the pulverized coal-fired boiler operates with oxygen supplied by a conventional, cryogenic air separation unit, whereas, in the second oxygen-based plant, the oxygen is supplied by an oxygen ion transport membrane. In both oxygen-based plants a portion of the boiler exhaust gas, which is primarily CO{sub 2}, is recirculated back to the boiler to control the combustion temperature, and the balance of the flue gas undergoes drying and compression to pipeline pressure; for consistency, both plants operate with similar combustion temperatures and utilize the same CO{sub 2} processing technologies. The capital and operating costs of the pulverized coal-fired boilers required by the three different plants were estimated by Foster Wheeler and the balance of plant costs were budget priced using published data together with vendor supplied quotations. The cost of electricity produced by each of the plants was determined and oxygen-based plant CO{sub 2} mitigation costs were calculated and compared to each other as well as to values published for some alternative CO{sub 2} capture technologies.

  13. Cast Alloys for Advanced Ultra Supercritical Steam Turbines

    SciTech Connect (OSTI)

    G. R. Holcomb, P. Wang, P. D. Jablonski, and J. A. Hawk,

    2010-05-01T23:59:59.000Z

    The proposed steam inlet temperature in the Advanced Ultra Supercritical (A-USC) steam turbine is high enough (760 °C) that traditional turbine casing and valve body materials such as ferritic/martensitic steels will not suffice due to temperature limitations of this class of materials. Cast versions of several traditionally wrought Ni-based superalloys were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantial: 2-5,000 kg each half and on the order of 100 cm thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equivalent microstructures. A multi-step homogenization heat treatment was developed to better deploy the alloy constituents. The most successful of these cast alloys in terms of creep strength (Haynes 263, Haynes 282, and Nimonic 105) were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (at 760 and 800 °C).

  14. Experimental investigation on heat transfer and frictional characteristics of vertical upward rifled tube in supercritical CFB boiler

    SciTech Connect (OSTI)

    Yang, Dong; Pan, Jie; Zhu, Xiaojing; Bi, Qincheng; Chen, Tingkuan [State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an 710049 (China); Zhou, Chenn Q. [Department of Mechanical Engineering, Purdue University Calumet, Hammond, IN 46323 (United States)

    2011-02-15T23:59:59.000Z

    Water wall design is a key issue for supercritical Circulating Fluidized Bed (CFB) boiler. On account of the good heat transfer performance, rifled tube is applied in the water wall design of a 600 MW supercritical CFB boiler in China. In order to investigate the heat transfer and frictional characteristics of the rifled tube with vertical upward flow, an in-depth experiment was conducted in the range of pressure from 12 to 30 MPa, mass flux from 230 to 1200 kg/(m{sup 2} s), and inner wall heat flux from 130 to 720 kW/m{sup 2}. The wall temperature distribution and pressure drop in the rifled tube were obtained in the experiment. The normal, enhanced and deteriorated heat transfer characteristics were also captured. In this paper, the effects of pressure, inner wall heat flux and mass flux on heat transfer characteristics are analyzed, the heat transfer mechanism and the frictional resistance performance are discussed, and the corresponding empirical correlations are presented. The experimental results show that the rifled tube can effectively prevent the occurrence of departure from nucleate boiling (DNB) and keep the tube wall temperature in a permissible range under the operating condition of supercritical CFB boiler. (author)

  15. Superalloys for ultra supercritical steam turbines--oxidation behavior

    SciTech Connect (OSTI)

    Holcomb, G.R.

    2008-09-01T23:59:59.000Z

    Goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 °C and 340 atm, so called ultra-supercritical (USC) steam conditions. One of the important materials performance considerations is steam-side oxidation resistance. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism under USC conditions. A methodology to calculate Cr evaporation rates from chromia scales with cylindrical geometries was developed that allows for the effects of CrO2(OH)2 saturation within the gas phase. This approach was combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles as a function of exposure time and to predict the time until the alloy surface concentration of Cr reaches zero. This time is a rough prediction of the time until breakaway oxidation. A hypothetical superheater tube, steam pipe, and high pressure turbine steam path was examined. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. The predicted time until breakaway oxidation increases dramatically with decreases in temperature and total pressure. Possible mitigation techniques were discussed, including those used in solid oxide fuel cell metallic interconnects (lowering the activity of Cr in the oxide scale by adding Mn to the alloy), and thermal barrier coating use on high pressure turbine blades for both erosion and chromia evaporation protection.

  16. Boiler materials for ultra-supercritical coal power plants - steamside oxidation

    SciTech Connect (OSTI)

    Viswanathan, R.; Sarver, J.; Tanzosh, J.M. [Electric Power Research Institute, Palo Alto, CA (United States)

    2006-06-15T23:59:59.000Z

    The corrosion behavior of tubing materials carrying steam at high temperature is of great concern to fossil power plant operators. This is due to the fact that the oxide films formed on the steam side can lead to major failures and consequently to reduced plant availability. The wall loss of the pressure boundary caused by oxidation can increase the hoop stresses and cause premature creep failures; second, the increased insulation of the tubes due to the low thermal conductivity of the oxide film can lead to increased metal temperature, thereby exacerbating the fireside corrosion as well as creep problems. The third concern is that thicker oxides may spall more easily when the plant is cooled down. On restart, the spalled material may lodge somewhere in the system with the potential for causing tube blockages, or it may be swept out with the working fluid and enter the steam turbine causing erosion damage to the turbine nozzles and blades. Failures of tubing and turbine components by these mechanisms have been widely reported in the United States. In view of the importance of the steamside oxidation, a major study of the phenomenon is being carried out as part of a major national program sponsored by the U.S. Department of Energy and the Ohio Coal Development Office. As a prelude to the experimental work, a literature survey was performed to document the state of the art. Results of the review are reported here.

  17. SciTech Connect: Ultra-Supercritical Pressure CFB Boiler Conceptual Design

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2) CawithMicrofluidic MembranelessPropertiesStudy

  18. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30T23:59:59.000Z

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and related combustion performance. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive Powder River Basin coal (PRB) to a moderately reactive Midwestern bituminous coal (HVB) to a less reactive medium volatile Eastern bituminous coal (MVB). Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis.

  19. Modeling Creep-Fatigue-Environment Interactions in Steam Turbine Rotor Materials for Advanced Ultra-supercritical Coal Power Plants

    SciTech Connect (OSTI)

    Shen, Chen

    2014-01-20T23:59:59.000Z

    The goal of this project is to model creep-fatigue-environment interactions in steam turbine rotor materials for advanced ultra-supercritical (A-USC) coal power Alloy 282 plants, to develop and demonstrate computational algorithms for alloy property predictions, and to determine and model key mechanisms that contribute to the damages caused by creep-fatigue-environment interactions. The nickel based Alloy 282 is selected for this project because it is one of the leading candidate materials for the high temperature/pressure section of an A-USC steam turbine. The methods developed in the project are expected to be applicable to other metal alloys in similar steam/oxidation environments. The major developments are: ? failure mechanism and microstructural characterization ? atomistic and first principles modeling of crack tip oxygen embrittlement ? modeling of gamma prime microstructures and mesoscale microstructure-defect interactions ? microstructure and damage-based creep prediction ? multi-scale crack growth modeling considering oxidation, viscoplasticity and fatigue The technology developed in this project is expected to enable more accurate prediction of long service life of advanced alloys for A-USC power plants, and provide faster and more effective materials design, development, and implementation than current state-of-the-art computational and experimental methods. This document is a final technical report for the project, covering efforts conducted from January 2011 to January 2014.

  20. Super Boiler 2nd Generation Technology for Watertube Boilers

    SciTech Connect (OSTI)

    Mr. David Cygan; Dr. Joseph Rabovitser

    2012-03-31T23:59:59.000Z

    This report describes Phase I of a proposed two phase project to develop and demonstrate an advanced industrial watertube boiler system with the capability of reaching 94% (HHV) fuel-to-steam efficiency and emissions below 2 ppmv NOx, 2 ppmv CO, and 1 ppmv VOC on natural gas fuel. The boiler design would have the capability to produce >1500 F, >1500 psig superheated steam, burn multiple fuels, and will be 50% smaller/lighter than currently available watertube boilers of similar capacity. This project is built upon the successful Super Boiler project at GTI. In that project that employed a unique two-staged intercooled combustion system and an innovative heat recovery system to reduce NOx to below 5 ppmv and demonstrated fuel-to-steam efficiency of 94% (HHV). This project was carried out under the leadership of GTI with project partners Cleaver-Brooks, Inc., Nebraska Boiler, a Division of Cleaver-Brooks, and Media and Process Technology Inc., and project advisors Georgia Institute of Technology, Alstom Power Inc., Pacific Northwest National Laboratory and Oak Ridge National Laboratory. Phase I of efforts focused on developing 2nd generation boiler concepts and performance modeling; incorporating multi-fuel (natural gas and oil) capabilities; assessing heat recovery, heat transfer and steam superheating approaches; and developing the overall conceptual engineering boiler design. Based on our analysis, the 2nd generation Industrial Watertube Boiler when developed and commercialized, could potentially save 265 trillion Btu and $1.6 billion in fuel costs across U.S. industry through increased efficiency. Its ultra-clean combustion could eliminate 57,000 tons of NOx, 460,000 tons of CO, and 8.8 million tons of CO2 annually from the atmosphere. Reduction in boiler size will bring cost-effective package boilers into a size range previously dominated by more expensive field-erected boilers, benefiting manufacturers and end users through lower capital costs.

  1. Advanced, Low/Zero Emission Boiler Design and Operation

    SciTech Connect (OSTI)

    Babcock/Wilcox; Illinois State Geological; Worley Parsons; Parsons Infrastructure/Technology Group

    2007-06-30T23:59:59.000Z

    In partnership with the U.S. Department of Energy's National Energy Technology Laboratory, B&W and Air Liquide are developing and optimizing the oxy-combustion process for retrofitting existing boilers as well as new plants. The main objectives of the project is to: (1) demonstrate the feasibility of the oxy-combustion technology with flue gas recycle in a 5-million Btu/hr coal-fired pilot boiler, (2) measure its performances in terms of emissions and boiler efficiency while selecting the right oxygen injection and flue gas recycle strategies, and (3) perform technical and economic feasibility studies for application of the technology in demonstration and commercial scale boilers. This document summarizes the work performed during the period of performance of the project (Oct 2002 to June 2007). Detailed technical results are reported in corresponding topical reports that are attached as an appendix to this report. Task 1 (Site Preparation) has been completed in 2003. The experimental pilot-scale O{sub 2}/CO{sub 2} combustion tests of Task 2 (experimental test performance) has been completed in Q2 2004. Process simulation and cost assessment of Task 3 (Techno-Economic Study) has been completed in Q1 2005. The topical report on Task 3 has been finalized and submitted to DOE in Q3 2005. The calculations of Task 4 (Retrofit Recommendation and Preliminary Design of a New Generation Boiler) has been completed in 2004. In Task 6 (engineering study on retrofit applications), the engineering study on 25MW{sub e} unit has been completed in Q2, 2008 along with the corresponding cost assessment. In Task 7 (evaluation of new oxy-fuel power plants concepts), based on the design basis document prepared in 2005, the design and cost estimate of the Air Separation Units, the boiler islands and the CO{sub 2} compression and trains have been completed, for both super and ultra-supercritical case study. Final report of Task-7 is published by DOE in Oct 2007.

  2. PARTICULATE CHARACTERIZATION AND ULTRA LOW-NOx BURNER FOR THE CONTROL OF NO{sub x} AND PM{sub 2.5} FOR COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Ralph Bailey; Hamid Sarv; Jim Warchol; Debi Yurchison

    2001-09-30T23:59:59.000Z

    In response to the serious challenge facing coal-fired electric utilities with regards to curbing their NO{sub x} and fine particulate emissions, Babcock and Wilcox and McDermott Technology, Inc. conducted a project entitled, ''Particulate Characterization and Ultra Low-NO{sub x} Burner for the Control of NO{sub x} and PM{sub 2.5} for Coal Fired Boilers.'' The project included pilot-scale demonstration and characterization of technologies for removal of NO{sub x} and primary PM{sub 2.5} emissions. Burner development and PM{sub 2.5} characterization efforts were based on utilizing innovative concepts in combination with sound scientific and fundamental engineering principles and a state-of-the-art test facility. Approximately 1540 metric tonnes (1700 tons) of high-volatile Ohio bituminous coal were fired. Particulate sampling for PM{sub 2.5} emissions characterization was conducted in conjunction with burner testing. Based on modeling recommendations, a prototype ultra low-NO{sub x} burner was fabricated and tested at 100 million Btu/hr in the Babcock and Wilcox Clean Environment Development Facility. Firing the unstaged burner with a high-volatile bituminous Pittsburgh 8 coal at 100 million Btu/hr and 17% excess air achieved a NO{sub x} goal of 0.20 lb NO{sub 2}/million Btu with a fly ash loss on ignition (LOI) of 3.19% and burner pressure drop of 4.7 in H{sub 2}O for staged combustion. With the burner stoichiometry set at 0.88 and the overall combustion stoichiometry at 1.17, average NO{sub x} and LOI values were 0.14 lb NO{sub 2}/million Btu and 4.64% respectively. The burner was also tested with a high-volatile Mahoning 7 coal. Based on the results of this work, commercial demonstration is being pursued. Size classified fly ash samples representative of commercial low-NO{sub x} and ultra low-NO{sub x} combustion of Pittsburgh 8 coal were collected at the inlet and outlet of an ESP. The mass of size classified fly ash at the ESP outlet was sufficient to evaluate the particle size distribution, but was of insufficient size to permit reliable chemical analysis. The size classified fly ash from the inlet of the ESP was used for detailed chemical analyses. Chemical analyses of the fly ash samples from the ESP outlet using a high volume sampler were performed for comparison to the size classified results at the inlet. For all test conditions the particulate removal efficiency of the ESP exceeded 99.3% and emissions were less than the NSPS limits of {approx}48 mg/dscm. With constant combustion conditions, the removal efficiency of the ESP increased as the ESP voltage and Specific Collection Area (SCA) increased. The associated decrease in particle emissions occurred in size fractions both larger and smaller than 2.5 microns. For constant ESP voltage and SCA, the removal efficiency for the ultra low-NO{sub x} combustion ash (99.4-99.6%) was only slightly less than for the low-NO{sub x} combustion ash (99.7%). The decrease in removal efficiency was accompanied by a decrease in ESP current. The emission of PM{sub 2.5} from the ESP did not change significantly as a result of the change in combustion conditions. Most of the increase in emissions was in the size fraction greater than 2.5 microns, indicating particle re-entrainment. These results may be specific to the coal tested in this program. In general, the concentration of inorganic elements and trace species in the fly ash at the ESP inlet was dependent on the particle size fraction. The smallest particles tended to have higher concentrations of inorganic elements/trace species than larger particles. The concentration of most elements by particle size range was independent of combustion condition and the concentration of soluble ions in the fly ash showed little change with combustion condition when evaluated on a carbon free basis.

  3. Choosing the right boiler air fans at Weston 4

    SciTech Connect (OSTI)

    Spring, N.

    2009-04-15T23:59:59.000Z

    When it came to choosing the three 'big' boiler air fans - forced draft, induced draft and primary air, the decision revolved around efficiency. The decision making process for fan selection for the Western 4 supercritical coal-fired plant is described in this article. 3 photos.

  4. Recovery Boiler Corrosion Chemistry

    E-Print Network [OSTI]

    Das, Suman

    11/13/2014 1 Recovery Boiler Corrosion Chemistry Sandy Sharp and Honghi Tran Symposium on Corrosion of a recovery boiler each cause their own forms of corrosion and cracking Understanding the origin of the corrosive conditions enables us to operate a boiler so as to minimize corrosion and cracking select

  5. NETL F 451.1-1/1 Categorical Exclusion (CX) Designation Form

    Broader source: Energy.gov (indexed) [DOE]

    for Ultra Supercritical Boilers This project will develop advanced nanostructured corrosion resistant coatings for high temperature boiler tubes by using science-based...

  6. Recovery Boiler Modeling

    E-Print Network [OSTI]

    Abdullah, Z.; Salcudean, M.; Nowak, P.

    , east, e, west, w, bot tom, b, and top, t, neighbors. The neighboring cou pling coefficients (an, a., .. , etc) express the magnitudes of the convection and diffusion which occur across the control volume boundaries. The variable b p represents... represents a model of one half of the recovery boiler. The boiler has three air levels. The North, South and East boundaries of the computational domain represent the water walls of the boiler. The West boundary represents a symmetry plane. It should...

  7. Minimize Boiler Blowdown

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  8. A Comparison of Creep-Rupture Tested Cast Alloys HR282, IN740 and 263 for Possible Application in Advanced Ultrasupercritical Steam Turbine and Boiler

    SciTech Connect (OSTI)

    Jablonski, P D; Evens, N; Yamamoto, Y; Maziasz, P

    2011-02-27T23:59:59.000Z

    Cast forms of traditionally wrought Ni-base precipitation-strengthened superalloys are being considered for service in the ultra-supercritical conditions (760°C, 35MPa) of next-generation steam boilers and turbines. After casting and homogenization, these alloys were given heat-treatments typical for each in the wrought condition to develop the gamma-prime phase. Specimens machined from castings were creep-rupture tested in air at 800°C. In their wrought forms, alloy 282 is expected to precipitate M23C6 within grain boundaries, alloy 740 is expected to precipitate several grain boundary phases including M23C6, G Phase, and ? phase, and alloy 263 has M23C6 and MC within its grain boundaries. This presentation will correlate the observed creep-life of these cast alloys with the microstructures developed during creep-rupture tests, with an emphasis on the phase identification and chemistry of precipitated grain boundary phases. The suitability of these cast forms of traditionally wrought alloys for turbine and boiler components will also be discussed.

  9. Supercritical fluid extraction

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Laintz, Kenneth (Pullman, WA)

    1994-01-01T23:59:59.000Z

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated or lipophilic crown ether or fluorinated dithiocarbamate. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  10. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31T23:59:59.000Z

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year) data. The test program details and data are presented herein.

  11. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31T23:59:59.000Z

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year) data. The test program details and data are presented herein.

  12. Boiler Corrosion and Monitoring

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    G. R. Holcomb; B. F. McGhee; A. T. Fry; N. J. Simms; K. Davis; Shim, H S; S. J. Bullard

    2013-11-19T23:59:59.000Z

    Results of a collaborative effort to investigate and develop solutions for key material issues affecting the performance of large-scale coal-fired boilers operating at advanced conditions is presented. Advanced conditions include advanced steam temperatures, oxyfuel firing, and co-firing biomass materials. A series of laboratory experimental results are presented on fireside corrosion in environments representing air-, and oxy-fired conditions, and with coal and/or biomass as the fuel. The effects of fluctuating reducing atmospheres and heat flux effects were examined. A variety of boiler corrosion probes and sensors were developed and tested. The probes measured corrosion by section loss and the sensors by electrochemical techniques including electrochemical noise. The probes were tested in coal and waste-to-energy boilers. Correlations between section loss probes and electrochemical noise sensors allow for real-time corrosion rate measurements to be made that allow for changes in boiler operations to be tracked in terms of corrosion effects.

  13. Boiler Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-01-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2005.

  14. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-04-27T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  15. Boiler Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; J. Sarver; M. Borden; K. Coleman; J. Blough; S. Goodstine; R.W. Swindeman; W. Mohn; I. Perrin

    2003-04-21T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  16. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-08-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April 1 to June 30, 2005.

  17. Boiler Materials For Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-09-30T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2006.

  18. Boiler Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-07-17T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April 1 to June 30, 2006.

  19. Boiler Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-04-20T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of January 1 to March 31, 2006.

  20. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-10-27T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2005.

  1. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2004-04-23T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2003.

  2. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    K. Coleman; R. Viswanathan; J. Shingledecker; J. Sarver; G. Stanko; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2004-01-23T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2003.

  3. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-01-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  4. Improve Your Boiler's Combustion Efficiency

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on boiler combustion efficiency provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  5. Return Condensate to the Boiler

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on returning condensate to boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  6. RENEWABLES RESEARCH Boiler Burner Energy System Technology

    E-Print Network [OSTI]

    RENEWABLES RESEARCH Boiler Burner Energy System Technology (BBEST) for Firetube Boilers PIER Renewables Research September 2010 The Issue Researchers at Altex Technologies Corporation in Sunnyvale, industrial combined heat and power (CHP) boiler burner energy system technology ("BBEST"). Their research

  7. CX-012283: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    similar to those in USC (ultra supercritical) steam boilers and turbines to determine corrosion mechanisms of alloys. CX-012283.pdf More Documents & Publications CX-006278:...

  8. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: Energy.gov (indexed) [DOE]

    similar to those in USC (ultra supercritical) steam boilers and turbines to determine corrosion mechanisms of alloys. Gordon R Holcomb Digitally signed by Gordon R Holcomb DN:...

  9. Small boiler uses waste coal

    SciTech Connect (OSTI)

    Virr, M.J. [Spinheat Ltd. (United States)

    2009-07-15T23:59:59.000Z

    Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

  10. Boiler Maximum Achievable Control Technology (MACT) Technical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Industrial, Commercial, and Institutional (ICI) Boilers and Process Heaters, February 2013 Guide to Combined Heat and Power Systems for Boiler Owners and Operators, July 2004...

  11. Specifying Waste Heat Boilers

    E-Print Network [OSTI]

    Ganapathy, V.

    of incinerator.whether fixed bed.rotary kiln or fluid bed.Sla9ging constituents present in the gas can result in bridging of tubes by molten salts if tube spacing is not wide,particularly at the boiler inlet.Ash hoppers ,soot blowers and cleaning lanes... take various configurations as seen in Fig 1 to ~.Consultants and engineers who specify and evaluate HRSGs should be aware that several factors influence the final configuration of HRSGs.Some of these factors are discussed below. SYSTEM...

  12. Boilers | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartmentAUDIT REPORTOpenWendeGuo Feng Bio JumpVenturesCoral CapitalBoilers Jump to:

  13. Investigation of Mineral Transformations in Wet Supercritical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy. Investigation of Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy. Abstract: The...

  14. Recover Heat from Boiler Blowdown

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on recovering heat from boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  15. Volatility of Gasoline and Diesel Fuel Blends for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be...

  16. Supercritical Fluid Extraction

    E-Print Network [OSTI]

    Johnston, K. P.; Flarsheim, W. M.

    1984-01-01T23:59:59.000Z

    .5 ,~---------------~, .~ I \\ I \\ (lJ o I \\ I , "0 I \\ I S '\\ l 0.1 L-__'--__L-__'--__L-_....:'.............L.:z:----L__..J o 1.0 _2.0 3.0 Reduced Density Fi g. 1. Pressure-versus-density isotherms for pure carbon dioxide (T = 304K, P c = 7.38 MPa, 3 c p = 0..., wood [28, 29~, and oil shal e [4J although these processes are far from commercialization. The Standard Oil Co. of Indiana used supercritical water with a density above 0.2 g/cc to recovery the bitumen from tar sand, while Williams used...

  17. NOx Control for Utility Boiler OTR Compliance

    SciTech Connect (OSTI)

    Hamid Farzan

    2003-12-31T23:59:59.000Z

    Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), the Babcock and Wilcox Company (B and W), and Fuel Tech teamed together to investigate an integrated solution for NO{sub x} control. The system is comprised of B and W's DRB-4Z{trademark} ultra low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NOxOUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. Development of the low-NO{sub x} burner technology has been a focus in B and W's combustion program. The DRB-4Z{trademark} burner is B and W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by controlled mixing of the fuel and air. Based on data from several 500 to 600 MWe boilers firing PRB coal, NOx emissions levels of 0.15 to 0.20 lb/ 106 Btu have been achieved from the DRB-4Z{trademark} burners in combination with overfire air ports. Although NOx emissions from the DRB-4Z{trademark} burner are nearing the Ozone Transport Rule (OTR) level of 0.15 lb NO{sub x}/106 Btu, the utility boiler owners can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them. Large-scale testing is planned in B and W's 100-million Btu/hr Clean Environment Development Facility (CEDF) that simulates the conditions of large coal-fired utility boilers. The objective of the project is to achieve a NO{sub x} level below 0.15 lb/106 Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B and W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign}. During this period B and W prepared and submitted the project management plan and hazardous substance plan to DOE. The negotiation of a subcontract for Fuel Tech has been started.

  18. Steam Conservation and Boiler Plant Efficiency Advancements

    E-Print Network [OSTI]

    Fiorino, D. P.

    This paper examines several cost-effective steam conservation and boiler plant efficiency advancements that were implemented during a recently completed central steam boiler plant replacement project at a very large semiconductor manufacturing...

  19. Sootblowing optimization for improved boiler performance

    DOE Patents [OSTI]

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J.

    2012-12-25T23:59:59.000Z

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  20. Sootblowing optimization for improved boiler performance

    DOE Patents [OSTI]

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J

    2013-07-30T23:59:59.000Z

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  1. CHP Integrated with Burners for Packaged Boilers

    SciTech Connect (OSTI)

    Castaldini, Carlo; Darby, Eric

    2013-09-30T23:59:59.000Z

    The objective of this project was to engineer, design, fabricate, and field demonstrate a Boiler Burner Energy System Technology (BBEST) that integrates a low-cost, clean burning, gas-fired simple-cycle (unrecuperated) 100 kWe (net) microturbine (SCMT) with a new ultra low-NOx gas-fired burner (ULNB) into one compact Combined Heat and Power (CHP) product that can be retrofit on new and existing industrial and commercial boilers in place of conventional burners. The Scope of Work for this project was segmented into two principal phases: (Phase I) Hardware development, assembly and pre-test and (Phase II) Field installation and demonstration testing. Phase I was divided into five technical tasks (Task 2 to 6). These tasks covered the engineering, design, fabrication, testing and optimization of each key component of the CHP system principally, ULNB, SCMT, assembly BBEST CHP package, and integrated controls. Phase I work culminated with the laboratory testing of the completed BBEST assembly prior to shipment for field installation and demonstration. Phase II consisted of two remaining technical tasks (Task 7 and 8), which focused on the installation, startup, and field verification tests at a pre-selected industrial plant to document performance and attainment of all project objectives. Technical direction and administration was under the management of CMCE, Inc. Altex Technologies Corporation lead the design, assembly and testing of the system. Field demonstration was supported by Leva Energy, the commercialization firm founded by executives at CMCE and Altex. Leva Energy has applied for patent protection on the BBEST process under the trade name of Power Burner and holds the license for the burner currently used in the product. The commercial term Power Burner is used throughout this report to refer to the BBEST technology proposed for this project. The project was co-funded by the California Energy Commission and the Southern California Gas Company (SCG), a division of Sempra Energy. These match funds were provided via concurrent contracts and investments available via CMCE, Altex, and Leva Energy The project attained all its objectives and is considered a success. CMCE secured the support of GI&E from Italy to supply 100 kW Turbec T-100 microturbines for the project. One was purchased by the project’s subcontractor, Altex, and a second spare was purchased by CMCE under this project. The microturbines were then modified to convert from their original recuperated design to a simple cycle configuration. Replacement low-NOx silo combustors were designed and bench tested in order to achieve compliance with the California Air Resources Board (CARB) 2007 emission limits for NOx and CO when in CHP operation. The converted microturbine was then mated with a low NOx burner provided by Altex via an integration section that allowed flow control and heat recovery to minimize combustion blower requirements; manage burner turndown; and recover waste heat. A new fully integrated control system was designed and developed that allowed one-touch system operation in all three available modes of operation: (1) CHP with both microturbine and burner firing for boiler heat input greater than 2 MMBtu/hr; (2) burner head only (BHO) when the microturbine is under service; and (3) microturbine only when boiler heat input requirements fall below 2 MMBtu/hr. This capability resulted in a burner turndown performance of nearly 10/1, a key advantage for this technology over conventional low NOx burners. Key components were then assembled into a cabinet with additional support systems for generator cooling and fuel supply. System checkout and performance tests were performed in the laboratory. The assembled system and its support equipment were then shipped and installed at a host facility where final performance tests were conducted following efforts to secure fabrication, air, and operating permits. The installed power burner is now in commercial operation and has achieved all the performance goals.

  2. Covered Product Category: Commercial Boilers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance and Federal efficiency requirements for commercial boilers, which is a FEMP-designated product category. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

  3. Underdeposit corrosion in boiler applications

    SciTech Connect (OSTI)

    Seels, F.H.

    1987-05-01T23:59:59.000Z

    Corrosion in industrial boilers is often associated with localized deposits. The most severe corrosion damage is often beneath the deposit. Waterside deposits can result in tube metal temperatures above the safe working limit for low-carbon steel. The variable of elevated metal temperature influences interactions between the deposit and corrosion processes under the deposit. Four case histories are discussed.

  4. Implementation of Boiler Best Practices

    E-Print Network [OSTI]

    Blake, N. R.

    . It also makes it easier to assign a value to the projects that are indicated by the questionnaire. The ten sections examine feedwater system performance and capability, with target limits for mixed-bed, two-bed, and softened water operation, boiler...

  5. Factors affecting stress assisted corrosion cracking of carbon steel under industrial boiler conditions.

    E-Print Network [OSTI]

    Yang, Dong

    2008-01-01T23:59:59.000Z

    ??Failure of carbon steel boiler tubes from waterside has been reported in the utility boilers and industrial boilers for a long time. In industrial boilers,… (more)

  6. Kraft recovery boiler physical and chemical processes

    SciTech Connect (OSTI)

    Adams, T.N.; Frederick, W.J. (Adams (Terry N.), Tacoma, WA (USA); Oregon State Univ., Corvallis, OR (USA). Dept. of Chemical Engineering)

    1988-01-01T23:59:59.000Z

    The focus of this book is on the recent research into the physical and chemical processes occurring in and around a black liquor recovery boiler. Almost all of the detailed technical information in this book has previously appeared in the open literature. The purpose here is not to present research for the first time, but to present it in a context of the other processes occurring in recovery boilers. Topics covered include: general characteristics of recovery boilers; black liquor thermal and transport properties; black liquor droplet formation and combustion; recovery boiler char bed processes; flow and mixing in Kraft recovery boilers; entrainment and carryover in recovery furnaces; fume formation and dust chemistry; deposits and boiler plugging; and recovery boiler thermal performance. 257 refs., 102 figs., 38 tabs.

  7. Alternate Materials for Recovery Boiler Superheater Tubes

    SciTech Connect (OSTI)

    Keiser, James R [ORNL; Kish, Joseph [McMaster University; Singbeil, Douglas [FPInnovations

    2009-01-01T23:59:59.000Z

    The ever escalating demands for increased efficiency of all types of boilers would most sensibly be realized by an increase in the steam parameters of temperature and pressure. However, materials and corrosion limitations in the steam generating components, particularly the superheater tubes, present major obstacles to boiler designers in achieving systems that can operate under the more severe conditions. This paper will address the issues associated with superheater tube selection for many types of boilers; particularly chemical recovery boilers, but also addressing the similarities in issues for biomass and coal fired boilers. It will also review our recent study of materials for recovery boiler superheaters. Additional, more extensive studies, both laboratory and field, are needed to gain a better understanding of the variables that affect superheater tube corrosion and to better determine the best means to control this corrosion to ultimately permit operation of recovery boilers at higher temperatures and pressures.

  8. Predictive modelling of boiler fouling

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    In this reporting period, efforts were initiated to supplement the comprehensive flow field description obtained from the RNG-Spectral Element Simulations by incorporating, in a general framework, appropriate modules to model particle and condensable species transport to the surface. Specifically, a brief survey of the literature revealed the following possible mechanisms for transporting different ash constituents from the host gas to boiler tubes as deserving prominence in building the overall comprehensive model: (1) Flame-volatilized species, chiefly sulfates, are deposited on cooled boiler tubes via the mechanism of classical vapor diffusion. This mechanism is more efficient than the particulate ash deposition, and as a result there is usually an enrichment of condensable salts, chiefly sulfates, in boiler deposits; (2) Particle diffusion (Brownian motion) may account for deposition of some fine particles below 0. 1 mm in diameter in comparison with the mechanism of vapor diffusion and particle depositions, however, the amount of material transported to the tubes via this route is probably small. (3) Eddy diffusion, thermophoretic and electrophoretic deposition mechanisms are likely to have a marked influence in transporting 0.1 to 5[mu]m particles from the host gas to cooled boiler tubes; (4) Inertial impaction is the dominant mechanism in transporting particles above 5[mu]m in diameter to water and steam tubes in pulverized coal fired boiler, where the typical flue gas velocity is between 10 to 25 m/s. Particles above 10[mu]m usually have kinetic energies in excess of what can be dissipated at impact (in the absence of molten sulfate or viscous slag deposit), resulting in their entrainment in the host gas.

  9. Supercritical Fluid Attachment of Palladium Nanoparticles on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Attachment of Palladium Nanoparticles on Aligned Carbon Nanotubes. Supercritical Fluid Attachment of Palladium Nanoparticles on Aligned Carbon Nanotubes. Abstract: Nanocomposite...

  10. Project Profile: Direct Supercritical Carbon Dioxide Receiver...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Dioxide Receiver Development Project Profile: Direct Supercritical Carbon Dioxide Receiver Development National Renewable Energy Laboratory logo The National...

  11. Fluidized bed boiler feed system

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1981-01-01T23:59:59.000Z

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  12. Boiler - tuning basics, part 1

    SciTech Connect (OSTI)

    Leopold, T. [ABB Inc. (United States)

    2009-03-15T23:59:59.000Z

    Tuning power plant controls takes nerves of steel and an intimate knowledge of plant systems gained only by experience. Tuning controls also requires equal parts art and science, which probably is why there are so few tuning experts in the power industry. In part 1 of a two-part series, the author explores a mix of the theoretical and practical aspects of tuning boiler control. 5 figs.

  13. Determining boiler-water makeup

    SciTech Connect (OSTI)

    Beecher, J.; Herman, K. [Ashland Chemical Co., Boonton, NJ (United States). Drew Industrial Div.

    1995-10-01T23:59:59.000Z

    In boiler operations, it is desirable to determine blowdown--and, thus, the feedwater`s concentration cycles--because it enables operators to calculate the theoretical concentrations of iron, copper or dispersant in the system. These calculations are important for maintaining boiler cleanliness. In practice, however, it isn`t always feasible to determine blowdown. For example, if the steam, feedwater and blowdown flows are not measured in a system, or if the measurements are not accurate, the blowdown and feedwater concentration cycles cannot be accurately determined. Also, if demineralized makeup water with very-low silica concentrations is mixed with essentially silica-free condensate, the ratio of silica in the boiler water to the silica in the feedwater may not yield accurate values for the concentration cycle. This method for calculating concentration cycles is accurate to within 5%, when the accuracy of the parameters measured are within the following limits: steam flow (2%); phosphate, residual (5%); micro calcium (50%); micro iron (25%); and phosphate, feed (10%).

  14. Quantifying Energy Savings by Improving Boiler Operation

    E-Print Network [OSTI]

    Carpenter, K.; Kissock, J. K.

    2005-01-01T23:59:59.000Z

    Dayton, OH ABSTRACT On/off operation and excess combustion air reduce boiler energy efficiency. This paper presents methods to quantify energy savings from switching to modulation control mode and reducing excess air in natural gas fired boilers... the accuracy of the methods. INTRODUCTION In our experience, common opportunities for improving boiler efficiency include switching from on/off to modulation control and reducing excess air. The decision about whether to pursue these opportunities...

  15. Stress-Assisted Corrosion in Boiler Tubes

    SciTech Connect (OSTI)

    Preet M Singh; Steven J Pawel

    2006-05-27T23:59:59.000Z

    A number of industrial boilers, including in the pulp and paper industry, needed to replace their lower furnace tubes or decommission many recovery boilers due to stress-assisted corrosion (SAC) on the waterside of boiler tubes. More than half of the power and recovery boilers that have been inspected reveal SAC damage, which portends significant energy and economic impacts. The goal of this project was to clarify the mechanism of stress-assisted corrosion (SAC) of boiler tubes for the purpose of determining key parameters in its mitigation and control. To accomplish this in-situ strain measurements on boiler tubes were made. Boiler water environment was simulated in the laboratory and effects of water chemistry on SAC initiation and growth were evaluated in terms of industrial operations. Results from this project have shown that the dissolved oxygen is single most important factor in SAC initiation on carbon steel samples. Control of dissolved oxygen can be used to mitigate SAC in industrial boilers. Results have also shown that sharp corrosion fatigue and bulbous SAC cracks have similar mechanism but the morphology is different due to availability of oxygen during boiler shutdown conditions. Results are described in the final technical report.

  16. Upgrade Boilers with Energy-Efficient Burners

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP steam tip sheet on upgrading boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  17. Next Generation Engineered Materials for Ultra Supercritical Steam Turbines

    SciTech Connect (OSTI)

    Douglas Arrell

    2006-05-31T23:59:59.000Z

    To reduce the effect of global warming on our climate, the levels of CO{sub 2} emissions should be reduced. One way to do this is to increase the efficiency of electricity production from fossil fuels. This will in turn reduce the amount of CO{sub 2} emissions for a given power output. Using US practice for efficiency calculations, then a move from a typical US plant running at 37% efficiency to a 760 C /38.5 MPa (1400 F/5580 psi) plant running at 48% efficiency would reduce CO2 emissions by 170kg/MW.hr or 25%. This report presents a literature review and roadmap for the materials development required to produce a 760 C (1400 F) / 38.5MPa (5580 psi) steam turbine without use of cooling steam to reduce the material temperature. The report reviews the materials solutions available for operation in components exposed to temperatures in the range of 600 to 760 C, i.e. above the current range of operating conditions for today's turbines. A roadmap of the timescale and approximate cost for carrying out the required development is also included. The nano-structured austenitic alloy CF8C+ was investigated during the program, and the mechanical behavior of this alloy is presented and discussed as an illustration of the potential benefits available from nano-control of the material structure.

  18. Best Practices: The Engineering Approach For Industrial Boilers

    E-Print Network [OSTI]

    Blake, N. R.

    , as well as plant profitability. Boiler Best Practices represent The Engineering Approach for Boilers-a way to examine mechanical, operational and chemical aspects of the systems (pretreatment through condensate) to ensure reliable boiler operations...

  19. Boiler System Efficiency Improves with Effective Water Treatment

    E-Print Network [OSTI]

    Bloom, D.

    Water treatment is an important aspect of boiler operation which can affect efficiency or result in damage if neglected. Without effective water treatment, scale can form on boiler tubes, reducing heat transfer, and causing a loss of boiler...

  20. Biomass Boiler and Furnace Emissions and Safety Regulations in...

    Open Energy Info (EERE)

    Biomass Boiler and Furnace Emissions and Safety Regulations in the Northeast States Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Biomass Boiler and Furnace Emissions...

  1. Consider Installing High-Pressure Boilers with BackpressureTurbine...

    Broader source: Energy.gov (indexed) [DOE]

    High-Pressure Boilers with Backpressure Turbine-Generators Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators This tip sheet outlines the benefits of...

  2. A Methodology for Optimizing Boiler Operating Strategy

    E-Print Network [OSTI]

    Jones, K. C.

    1983-01-01T23:59:59.000Z

    Among the many ways by which an energy manager can conserve energy is the establishment of a strategy for operation of fired boilers. In particular, he can effect total fuel consumption by his decision on how much on-line boiler surplus is required...

  3. PtRu/Carbon Nanotube Nanocomposite Synthesized in Supercritical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesized in Supercritical Fluid: A Novel Electrocatalyst for Direct Methanol Fuel Cell. PtRuCarbon Nanotube Nanocomposite Synthesized in Supercritical Fluid: A Novel...

  4. Reaction of Water-Saturated Supercritical CO2 with Forsterite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water-Saturated Supercritical CO2 with Forsterite: Evidence for Magnesite Formation at Low Temperatures. Reaction of Water-Saturated Supercritical CO2 with Forsterite: Evidence for...

  5. Evaluation of Biodiesel Fuels from Supercritical Fluid Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced...

  6. Advanced combustion system for industrial boilers. Phase 2, Quarterly technical progress report, October--December 1990

    SciTech Connect (OSTI)

    Wagoner, C.L.; Foote, J.P.; Millard, W.P.; Attig, R.C.; Schulz, R.J.

    1990-12-31T23:59:59.000Z

    This During this quarter, work continued on development/improvement of the low-NO{sub x} coal combustor for the boiler system. Reburning tests were conducted in the external, water-cooled test duct with a length of 15 feet using ultra fine coal with propane to reduce the NO{sub x} levels to as low as 0.295 lb-NO{sub x}/MBtu. Work also continued on design/construction of the new coal-feed system that will be used for the 100-hour demonstration test with the on-line refillable coal hopper operating in air at atmospheric pressure. Coal will be loaded into the hopper from bulk bags. Initial testing of the UTSI boiler control and automation system was successful. Normally-pulverized coal with approximately 70% passing a number 200 sieve was burned in the external test duct. Initial flame-visualization tests were successful, and the burner was able to handle coal without being micronized to the ultra fine level. Refractory was poured for a new combustor second-stage assembly. Subsequently, the combustor was installed inside the 200 hp fire-tube boiler.

  7. Recuperative supercritical carbon dioxide cycle

    DOE Patents [OSTI]

    Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

    2014-11-18T23:59:59.000Z

    A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

  8. Supercritical/Solid Catalyst (SSC)

    SciTech Connect (OSTI)

    None

    2010-01-01T23:59:59.000Z

    INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

  9. Supercritical/Solid Catalyst (SSC)

    ScienceCinema (OSTI)

    None

    2013-05-28T23:59:59.000Z

    INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

  10. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, C.L.; Foote, J.P.

    1995-07-04T23:59:59.000Z

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

  11. A new blowdown compensation scheme for boiler leak detection

    E-Print Network [OSTI]

    Marquez, Horacio J.

    considers the blowdown effect in industrial boiler operation. This adds to the efficiency of recent advancesA new blowdown compensation scheme for boiler leak detection A. M. Pertew ,1 X. Sun ,1 R. Kent in identification-based leak detection techniques of boiler steam- water systems. Keywords: Industrial Boilers, Tube

  12. Using HYTECH to Synthesize Control Parameters for a Steam Boiler? ??

    E-Print Network [OSTI]

    Henzinger, Thomas A.

    Using HYTECH to Synthesize Control Parameters for a Steam Boiler? ?? Thomas A. Henzinger1 Howard model a steam-boiler control system using hybrid au- tomata. We provide two abstracted linear models that guarantee the safety of the boiler. 1 Introduction A description of an industrial steam boiler has been

  13. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, Charles L. (Tullahoma, TN); Foote, John P. (Tullahoma, TN)

    1995-01-01T23:59:59.000Z

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

  14. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01T23:59:59.000Z

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  15. Parametric study of a firetube boiler performance

    SciTech Connect (OSTI)

    Park, H. [Marquette Univ., Milwaukee, WI (United States). Dept. of Mechanical and Industrial Engineering; Valentino, M.W. [Cleaver-Brooks, Milwaukee, WI (United States)

    1995-12-31T23:59:59.000Z

    Critical areas in the design of commercial and industrial firetube boilers are burner and furnace configuration, as is the resultant heat transfer from the furnace wall to the water under the various conditions. Furthermore, performance of industrial and commercial boilers is mainly dependent upon their material and geometrical dimensions. In order to investigate boiler performance globally, a relatively simple model which can be processed in a personal computer (PC) is proposed. In this paper, the effects of thermo-physical parameters on the energy and exergy performance of a firetube boiler are studied by using a simple model for the combustion product gas behavior through the boiler passes. For each steady-state condition, the boiler performance is investigated by parametrically changing the degree of inception of nucleate boiling, the tube wall emissivity, the saturation steam pressure, and the fraction of flue gas recirculation (FGR, utilized for NO{sub x} emissions reduction). Results for a set of parameters such as those considered in this work may be used in future firetube boiler design to improve performance and reduce manufacturing costs.

  16. Low Temperature Heat Recovery for Boiler Systems

    E-Print Network [OSTI]

    Shook, J. R.; Luttenberger, D. B.

    be economically heated to within 50 0 F of the entering flue gas temperature. Other less common, but practical, uses for energy include driving a low-temperature electric turbine cycle or an absorption chilling cycle. An improvement in boiler efficiency of 3...% to 8% can normally be realized by cooling boiler flue gasses down to llO o F_200 0 F. This recovers a large quantity of the available sensible heat in most boiler flue gas streams. Efficiency can be improv ed by up to 10% if flue gas is cooled down...

  17. Resource recovery waste heat boiler upgrade

    SciTech Connect (OSTI)

    Kuten, P.; McClanahan, D.E. [Fluor Daniel, Inc., Houston, TX (United States); Gehring, P.R.; Toto, M.L. [SRRI, Springfield, MA (United States); Davis, J.J. [Deltak, Minon, MN (United States)

    1996-09-01T23:59:59.000Z

    The waste heat boilers installed in a 360 TPD waste to energy plant were identified as the bottle neck for an effort to increase plant capacity. These boilers were successfully modified to accommodate the increase of plant capacity to 408 TPD, improve steam cycle performance and reduce boiler tube failures. The project demonstrated how engineering and operation can work together to identify problems and develop solutions that satisfy engineering, operation, and financial objectives. Plant checking and testing, design review and specification development, installation and operation results are presented.

  18. Boiler scale prevention employing an organic chelant

    DOE Patents [OSTI]

    Wallace, Steven L. (Lake Jackson, TX); Griffin, Jr., Freddie (Missouri City, TX); Tvedt, Jr., Thorwald J. (Angleton, TX)

    1984-01-01T23:59:59.000Z

    An improved method of treating boiler water which employs an oxygen scavenging compound and a compound to control pH together with a chelating agent, wherein the chelating agent is hydroxyethylethylenediaminetriacetic acid.

  19. Commonwealth Small Pellet Boiler Grant Program

    Broader source: Energy.gov [DOE]

    The Massachusetts Clean Energy Center (MassCEC) and the Department of Energy Resources (DOER) are offering the Commonwealth Small Pellet Boiler Pilot Grant Program to provide grants to residents...

  20. Condensing Heat Exchangers Optimize Steam Boilers

    E-Print Network [OSTI]

    Sullivan, B.; Sullivan, P. A.

    1983-01-01T23:59:59.000Z

    for Industrial Boilers" R. E. Thompson - R. J. Goldstick KVB, Inc., 18806 Skypark Blvd., Irvine, California 92714, pg. 12-4. (3) "Condensing Heat Exchangers Using Tenon R Covered Tubes", Ronald Hessen, Condensing Heat Exchanger Corp., Latham, New York...

  1. Practical Procedures for Auditing Industrial Boiler Plants

    E-Print Network [OSTI]

    O'Neil, J. P.

    1980-01-01T23:59:59.000Z

    Industrial boiler plants are an area of opportunity in virtually every industry to save energy and reduce costs by using relatively simple, inexpensive auditing procedures. An energy audit consists of inspection, measurement, analysis...

  2. Energy Conservation for Boiler Water Systems

    E-Print Network [OSTI]

    Beardsley, M. L.

    1981-01-01T23:59:59.000Z

    . This paper reviews methods to conserve energy in industrial boiler water systems. Both mechanical and chemical approaches for energy conservation are discussed. The important aspects of efficient combustion are covered as well as other mechanical factors...

  3. Clean Boiler Waterside Heat Transfer Surfaces

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  4. Geothermal energy production with supercritical fluids

    DOE Patents [OSTI]

    Brown, Donald W.

    2003-12-30T23:59:59.000Z

    There has been invented a method for producing geothermal energy using supercritical fluids for creation of the underground reservoir, production of the geothermal energy, and for heat transport. Underground reservoirs are created by pumping a supercritical fluid such as carbon dioxide into a formation to fracture the rock. Once the reservoir is formed, the same supercritical fluid is allowed to heat up and expand, then is pumped out of the reservoir to transfer the heat to a surface power generating plant or other application.

  5. Boiler MACT Technical Assistance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-03-01T23:59:59.000Z

    Fact sheet describing the changes to Environmental Protection Act process standards. The DOE will offer technical assistance to ensure that major sources burning coal and oil have information on cost-effective, clean energy strategies for compliance, and to promote cleaner, more efficient boiler burning to cut harmful pollution and reduce operational costs. The U.S. Environmental Protection Agency (EPA) is expected to finalize the reconsideration process for its Clean Air Act pollution standards National Emissions Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers and Process Heaters (known as Boiler Maximum Achievable Control Technology (MACT)), in Spring 2012. This rule applies to large and small boilers in a wide range of industrial facilities and institutions. The U.S. Department of Energy (DOE) will offer technical assistance to ensure that major sources burning coal or oil have information on cost-effective clean energy strategies for compliance, including combined heat and power, and to promote cleaner, more efficient boilers to cut harmful pollution and reduce operational costs.

  6. Supercritical Water desulfurization of crude oil

    E-Print Network [OSTI]

    Kida, Yuko

    2014-01-01T23:59:59.000Z

    Supercritical Water (SCW) desulfurization was investigated for both model sulfur compounds and Arab Heavy crude. In part 1, the reactions of alkyl sulfides in SCW were studied. During hexyl sulfide decomposition in SCW, ...

  7. Analysis of a supercritical hydrogen liquefaction cycle

    E-Print Network [OSTI]

    Staats, Wayne Lawrence

    2008-01-01T23:59:59.000Z

    In this work, a supercritical hydrogen liquefaction cycle is proposed and analyzed numerically. If hydrogen is to be used as an energy carrier, the efficiency of liquefaction will become increasingly important. By examining ...

  8. Stability analysis of supercritical water cooled reactors

    E-Print Network [OSTI]

    Zhao, Jiyun, Ph. D. Massachusetts Institute of Technology

    2005-01-01T23:59:59.000Z

    The Supercritical Water-Cooled Reactor (SCWR) is a concept for an advanced reactor that will operate at high pressure (25MPa) and high temperature (500°C average core exit). The high coolant temperature as it leaves the ...

  9. On blowup in supercritical wave equations

    E-Print Network [OSTI]

    Roland Donninger; Birgit Schörkhuber

    2014-11-28T23:59:59.000Z

    We study the blowup behaviour for the focusing energy-supercritical semilinear wave equation in 3 space dimensions without symmetry assumptions on the data. We prove the stability of the ODE blowup profile.

  10. Simulation of Combustion and Thermal Flow in an Industrial Boiler

    E-Print Network [OSTI]

    Saripalli, R.; Wang, T.; Day, B.

    2005-01-01T23:59:59.000Z

    Industrial boilers that produce steam or electric power represent a crucial facility for overall plant operations. To make the boiler more efficient, less emission (cleaner) and less prone to tube rupture problems, it is important to understand...

  11. Modern Boiler Control and Why Digital Systems are Better

    E-Print Network [OSTI]

    Hughart, C. L.

    1983-01-01T23:59:59.000Z

    Steam generation in petrochemical plants and refineries is in a state of change. Expensive fuels have resulted in greater use of waste heat recovery boilers and other energy conservation measures. As a result, many conventional boilers have been...

  12. 10-MW Supercritical-CO2 Turbine

    Broader source: Energy.gov [DOE]

    This fact sheet describes a 10-megawatt supercritical carbon dioxide turbine project, awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The research team, led by NREL, intends to showcase the turbomachinery for a new cycle—the supercritical carbon dioxide (s-CO2) Brayton cycle. The cycle is being optimized and tested at conditions representing dry cooling in desert environments, thereby accurately simulating real-world concentrating solar power system operating conditions.

  13. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, Pascal M. (Richmond, CA)

    1982-01-01T23:59:59.000Z

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carry-over through the turbine causes corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  14. FAQs Manhattanville Campus Central Energy Plant Boiler Stacks

    E-Print Network [OSTI]

    Kim, Philip

    FAQs Manhattanville Campus Central Energy Plant Boiler Stacks Installation Frequently Asked Questions What is happening? Columbia University is installing two (2) boiler stacks on top of the Jerome L, a below-grade facility which will consist four (4) 45,000 lbs/hr steam boilers and related equipment

  15. Waterside Stress Assisted Corrosion (SAC) of Boiler Tubes

    E-Print Network [OSTI]

    Das, Suman

    Waterside Stress Assisted Corrosion (SAC) of Boiler Tubes School of Materials Science Boiler Areas Susceptible to SAC · Generally SAC initiates near weld joints on cold side of tubes · SAC cracks are difficult to detect inaccessibility · Failures Detected at Various Locations in Boilers

  16. 1 | P a g e Boiler Gold Rush

    E-Print Network [OSTI]

    Ginzel, Matthew

    1 | P a g e Boiler Gold Rush VISION STATEMENT The vision of BGR is twofold: first, help all new by participating in the premiere orientation program in the nation, Boiler Gold Rush. Second, enhance upper leaders for the betterment of the university. PROGRAM GOALS Boiler Gold Rush will provide the following

  17. Nanotube Boiler 1 Abstract--Controlled copper evaporation at attogram

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Nanotube Boiler 1 Abstract-- Controlled copper evaporation at attogram level from individual carbon nanotube (CNT) vessels, which we call nanotube boilers, is investigated experimentally, and ionization in these CNT boilers, which can serve as sources for mass transport and deposition in nanofluidic

  18. Project Recap Humanitarian Engineering Biodiesel Boiler System for Steam Generator

    E-Print Network [OSTI]

    Demirel, Melik C.

    Project Recap Humanitarian Engineering ­ Biodiesel Boiler System for Steam Generator Currently 70 biodiesel boiler system to drive a steam engine generator. This system is to provide electricity the customer needs, a boiler fueled by biodiesel and outputting to a steam engine was decided upon. The system

  19. Density-Enthalpy Phase Diagram 0D Boiler Simulation

    E-Print Network [OSTI]

    Vuik, Kees

    Diagram 0D Boiler Simulation Finite Element Method Further Research Mass and Heat balances V d dt = i - eDensity-Enthalpy Phase Diagram 0D Boiler Simulation Finite Element Method Further Research Finite Transitions #12;Density-Enthalpy Phase Diagram 0D Boiler Simulation Finite Element Method Further Research

  20. Using HYTECH to Synthesize Control Parameters for a Steam Boiler ?;??

    E-Print Network [OSTI]

    Henzinger, Thomas A.

    Using HYTECH to Synthesize Control Parameters for a Steam Boiler ?;?? Thomas A. Henzinger 1 Howard model a steam­boiler control system using hybrid au­ tomata. We provide two abstracted linear models constraints that guarantee the safety of the boiler. 1 Introduction A description of an industrial steam

  1. Steam boiler control speci cation problem: A TLA solution

    E-Print Network [OSTI]

    Steam boiler control speci cation problem: A TLA solution Frank Le ke and Stephan Merz Institut fur of the state of the steam boiler, detect failures, and model message transmission. We give a more detailed between the physi- cal state of the steam boiler and the model maintained by the controller and discuss

  2. An Object-Oriented Algebraic Steam-Boiler Control Specification

    E-Print Network [OSTI]

    Ă?lveczky, Peter Csaba

    An Object-Oriented Algebraic Steam-Boiler Control Specification.In this paper an object-oriented algebraic solution of the steam-boiler specification problem is presented computations cannot happen. 1 Introduction The steam-boiler control specification problem has been

  3. An Object-Oriented Algebraic Steam-Boiler Control Specification

    E-Print Network [OSTI]

    Ă?lveczky, Peter Csaba

    An Object-Oriented Algebraic Steam-Boiler Control Specification Peter Csaba ()lveczky, Poland Abstract. In this paper an object-oriented algebraic solution of the steam-boiler specification Introduction The steam-boiler control specification problem has been proposed as a challenge for different

  4. Streams of Steam The Steam Boiler Specification Case Study

    E-Print Network [OSTI]

    Streams of Steam ­ The Steam Boiler Specification Case Study Manfred Broy, Franz Regensburger-tuned con- cepts of FOCUS by its application of the requirements specification of a steam boiler, see [Abr96-studies. In this context, applying FOCUS to the steam boiler case study ([Abr96]) led us to a couple of questions re- #12

  5. Steam boiler control specification problem: A TLA solution

    E-Print Network [OSTI]

    Merz, Stephan

    Steam boiler control specification problem: A TLA solution Frank Le�ke and Stephan Merz Institut f of the state of the steam boiler, detect failures, and model message transmission. We give a more detailed between the physi­ cal state of the steam boiler and the model maintained by the controller and discuss

  6. TA-2 Water Boiler Reactor Decommissioning Project

    SciTech Connect (OSTI)

    Durbin, M.E. (ed.); Montoya, G.M.

    1991-06-01T23:59:59.000Z

    This final report addresses the Phase 2 decommissioning of the Water Boiler Reactor, biological shield, other components within the biological shield, and piping pits in the floor of the reactor building. External structures and underground piping associated with the gaseous effluent (stack) line from Technical Area 2 (TA-2) Water Boiler Reactor were removed in 1985--1986 as Phase 1 of reactor decommissioning. The cost of Phase 2 was approximately $623K. The decommissioning operation produced 173 m{sup 3} of low-level solid radioactive waste and 35 m{sup 3} of mixed waste. 15 refs., 25 figs., 3 tabs.

  7. Circulating Fluidized Bed Combustion Boiler Project

    E-Print Network [OSTI]

    Farbstein, S. B.; Moreland, T.

    1984-01-01T23:59:59.000Z

    or turndown so we delayed consideration of installation of a FBC boil r. CIRCULATING FBC In early 1980 we became aware of the work by the Ahlstrom Company of Helsinki, Finland in the development of the circulating FBC boiler design. The PYROFLOW... layer is a lightweight insulating refractory. In 1979, Ahlstrom started up a 45,000 pound per hour PYROFLOW unIt at Pihlava, Finland. In 1981, 200,000 pound per hour boiler was started up 1 Kauttua, Finland as le b se load steam supply for paper...

  8. Super Boiler: Packed Media/Transport Membrane Boiler Development and Demonstration

    SciTech Connect (OSTI)

    Liss, William E; Cygan, David F

    2013-04-17T23:59:59.000Z

    Gas Technology Institute (GTI) and Cleaver-Brooks developed a new gas-fired steam generation system���¢��������the Super Boiler���¢��������for increased energy efficiency, reduced equipment size, and reduced emissions. The system consists of a firetube boiler with a unique staged furnace design, a two-stage burner system with engineered internal recirculation and inter-stage cooling integral to the boiler, unique convective pass design with extended internal surfaces for enhanced heat transfer, and a novel integrated heat recovery system to extract maximum energy from the flue gas. With these combined innovations, the Super Boiler technical goals were set at 94% HHV fuel efficiency, operation on natural gas with <5 ppmv NOx (referenced to 3%O2), and 50% smaller than conventional boilers of similar steam output. To demonstrate these technical goals, the project culminated in the industrial demonstration of this new high-efficiency technology on a 300 HP boiler at Clement Pappas, a juice bottler located in Ontario, California. The Super Boiler combustion system is based on two stage combustion which combines air staging, internal flue gas recirculation, inter-stage cooling, and unique fuel-air mixing technology to achieve low emissions rather than external flue gas recirculation which is most commonly used today. The two-stage combustion provides lower emissions because of the integrated design of the boiler and combustion system which permit precise control of peak flame temperatures in both primary and secondary stages of combustion. To reduce equipment size, the Super Boiler's dual furnace design increases radiant heat transfer to the furnace walls, allowing shorter overall furnace length, and also employs convective tubes with extended surfaces that increase heat transfer by up to 18-fold compared to conventional bare tubes. In this way, a two-pass boiler can achieve the same efficiency as a traditional three or four-pass firetube boiler design. The Super Boiler is consequently up to 50% smaller in footprint, has a smaller diameter, and is up to 50% lower in weight, resulting in very compact design with reduced material cost and labor costs, while requiring less boiler room floor space. For enhanced energy efficiency, the heat recovery system uses a transport membrane condenser (TMC), a humidifying air heater (HAH), and a split-stage economizer to extract maximum energy from the flue gas. The TMC is a new innovation that pulls a major portion of water vapor produced by the combustion process from the flue gases along with its sensible and latent heat. This results in nearly 100% transfer of heat to the boiler feed water. The HAH improves the effectiveness of the TMC, particularly in steam systems that do not have a large amount of cold makeup water. In addition, the HAH humidifies the combustion air to reduce NOx formation. The split-stage economizer preheats boiler feed water in the same way as a conventional economizer, but extracts more heat by working in tandem with the TMC and HAH to reduce flue gas temperature. These components are designed to work synergistically to achieve energy efficiencies of 92-94% which is 10-15% higher than today���¢��������s typical firetube boilers.

  9. Evaluation of coal-derived liquids as boiler fuels. Volume 2: boiler test results. Final report

    SciTech Connect (OSTI)

    Not Available

    1985-09-01T23:59:59.000Z

    A combustion demonstration using six coal-derived liquid (CDL) fuels was conducted on a utility boiler located at the Plant Sweatt Electric Generating Station of Mississippi Power Company in Meridian, Mississippi. The test program was conducted in two phases. The first phase included the combustion tests of the two conventional fuels (natural gas and No. 6 fuel oil) and three coal-derived liquid fuels (Solvent Refined Coal-II full range distillate, H-Coal heavy distillate and H-Coal blended distillate). The second phase involved the evaluation of three additional CDL fuels (H-Coal light distillate, Exxon Donor Solvent full range distillate and Solvent Refined Coal-II middle distillate). The test boiler was a front wall-fired Babcock and Wilcox unit with a rated steam flow of 425,000 lb/h and a generating capacity of 40 MW. Boiler performance and emissions were evaluated with baseline and CDL fuels at 15, 25, 40 MW loads and at various excess air levels. Low NO/sub x/ (staged) combustion techniques were also implemented. Boiler performance monitoring included measurements for fuel steam and flue gas flow, pressure, temperature, and heat absorption, resulting in a calculated combustion efficiency, boiler efficiency, and heat rate. Emissions measurements included oxygen, carbon dioxide, carbon monoxide, oxides of nitrogen, sulfur dioxide, sulfur trioxide, acid dewpoint, particulate mass, size distribution and morphology, chlorides, and opacity. The test program demonstrated the general suitability of CDL fuels for use in existing oil-fired utility boilers. No significant boiler tube surface modifications will be required. The CDL fuels could be handled similarly to No. 2 oil with appropriate safety procedures and materials compatibility considerations. Volume 2 of a five-volume report contains the detailed boiler test results. 96 figs., 26 tabs.

  10. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1 High-Efficiency Receivers for Supercritical...

  11. Best Management Practice #8: Steam Boiler Systems

    Broader source: Energy.gov [DOE]

    Boilers and steam generators are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size, the amount of steam used, and the amount of condensate returned.

  12. Digital radiographic systems detect boiler tube cracks

    SciTech Connect (OSTI)

    Walker, S. [EPRI, Charlotte, NC (United States)

    2008-06-15T23:59:59.000Z

    Boiler water wall leaks have been a major cause of steam plant forced outages. But conventional nondestructive evaluation techniques have a poor track record of detecting corrosion fatigue cracking on the inside surface of the cold side of waterwall tubing. EPRI is performing field trials of a prototype direct-digital radiographic system that promises to be a game changer. 8 figs.

  13. Mitsubishi FGD plants for lignite fired boilers

    SciTech Connect (OSTI)

    Kotake, Shinichiro; Okazoe, Kiyoshi; Iwashita, Koichiro; Yajima, Satoru

    1998-07-01T23:59:59.000Z

    In order to respond to the increasing electric energy demand for sustaining economic growth, construction of coal-fired thermal power plants worldwide is indispensable. As a countermeasure for environmental pollution which otherwise may reach a serious proportion from the operation of these plants, construction of flue gas desulfurization (FGD) plants is being promoted. Among these power stations where lignite fuel is burnt, the FGD plants concerned have to be designed to cope with high gas volume and SO{sub x} concentration as well as violent fluctuations in their values caused by such features of lignite as high sulfur content, low calorific volume, and unstable properties. Mitsubishi Heavy Industries (MHI) has received construction awards for a total of seven (7) FGD plants for lignite-fired boilers in succession starting from that for CEZ as, Czech Republic followed by those for EGAT, Thailand in 1993. All these plants are presently operating satisfactorily since successful completion of their performance tests in 1996. Further, a construction award of three (3) more FGD plants for lignite-fired boilers was received from ENDESA (Spain) in 1995 which are now being outfitted and scheduled to start commercial operation in 1998. In this paper, the authors discuss the outline design of FGD plants for lignite-fired boilers based on experience of FGD plants constructed since 1970 for heavy oil--as well as black coal-fired boilers, together with items confirmed from the operation and design guideline hereafter.

  14. The next generation of oxy-fuel boiler systems

    SciTech Connect (OSTI)

    Ochs, Thomas L.; Gross, Alex (Jupiter Oxygen Corp.); Patrick, Brian (Jupiter Oxygen Corp.); Oryshchyn, Danylo B.; Summers, Cathy A.; Turner, Paul C.

    2005-01-01T23:59:59.000Z

    Research in the area of oxy-fuel combustion which is being pioneered by Jupiter Oxygen Corporation combined with boiler research conducted by the USDOE/Albany Research Center has been applied to designing the next generation of oxy-fuel combustion systems. The new systems will enhance control of boiler systems during turn-down and improve response time while improving boiler efficiency. These next generation boiler systems produce a combustion product that has been shown to be well suited for integrated pollutant removal. These systems have the promise of reducing boiler foot-print and boiler construction costs. The modularity of the system opens the possibility of using this design for replacement of boilers for retrofit on existing systems.

  15. Feasibility Study of Supercritical Light Water Cooled Reactors for Electric Power Production, Progress Report for Work Through September 2003, 2nd Annual/8th Quarterly Report

    SciTech Connect (OSTI)

    Philip E. MacDonald

    2003-09-01T23:59:59.000Z

    The supercritical water-cooled reactor (SCWR) is one of the six reactor technologies selected for research and development under the Generation-IV program. SCWRs are promising advanced nuclear systems because of their high thermal efficiency (i.e., about 45% vs. about 33% efficiency for current Light Water Reactors, LWRs) and considerable plant simplification. SCWRs are basically LWRs operating at higher pressure and temperatures with a direct once-through cycle. Operation above the critical pressure eliminates coolant boiling, so the coolant remains single-phase throughout the system. Thus the need for recirculation and jet pumps, a pressurizer, steam generators, steam separators and dryers is eliminated. The main mission of the SCWR is generation of low-cost electricity. It is built upon two proven technologies, LWRs, which are the most commonly deployed power generating reactors in the world, and supercritical fossil-fired boilers, a large number of which is also in use around the world.

  16. Supercritical fluid thermodynamics for coal processing

    SciTech Connect (OSTI)

    van Swol, F. (Illinois Univ., Urbana, IL (United States). Dept. of Chemical Engineering); Eckert, C.A. (Georgia Inst. of Tech., Atlanta, GA (United States). School of Chemical Engineering)

    1988-09-15T23:59:59.000Z

    The main objective of this research is to develop an equation of state that can be used to predict solubilities and tailor supercritical fluid solvents for the extraction and processing of coal. To meet this objective we have implemented a two-sided. approach. First, we expanded the database of model coal compound solubilities in higher temperature fluids, polar fluids, and fluid mixtures systems. Second, the unique solute/solute, solute/cosolvent and solute/solvent intermolecular interactions in supercritical fluid solutions were investigated using spectroscopic techniques. These results increased our understanding of the molecular phenomena that affect solubility in supercritical fluids and were significant in the development of an equation of state that accurately reflects the true molecular makeup of the solution. (VC)

  17. Recovery Boiler Superheater Ash Corrosion Field Study

    SciTech Connect (OSTI)

    Keiser, James R [ORNL] [ORNL; Kish, Joseph [McMaster University] [McMaster University; Singbeil, Douglas [FPInnovations] [FPInnovations

    2010-01-01T23:59:59.000Z

    With the trend towards increasing the energy efficiency of black liquor recovery boilers operated in North America, there is a need to utilize superheater tubes with increased corrosion resistance that will permit operation at higher temperatures and pressures. In an effort to identify alloys with improved corrosion resistance under more harsh operating conditions, a field exposure was conducted that involved the insertion of an air-cooled probe, containing six candidate alloys, into the superheater section of an operating recovery boiler. A metallographic examination, complete with corrosion scale characterization using EMPA, was conducted after a 1,000 hour exposure period. Based on the results, a ranking of alloys based on corrosion performance was obtained.

  18. Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Fox, Robert V. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2000-01-01T23:59:59.000Z

    This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

  19. World Class Boilers and Steam Distribution System

    E-Print Network [OSTI]

    Portell, V. P.

    WORLD CLASS BOILERS AND STEAM DISTRIBUTION SYSTEM Vernon P. Portell, Ph.D. Manager Armstrong Service, Inc. ABSTRACT categorizing, measuring, and comparing subjects which are of interest to us is the way we identify the "World class" is a... of information can also be obtained through an independent firm that provides third-party assessment of steam systems. One of these third parties, Armstrong Energy Certification, Inc., has used data gleaned from decades of industrial experience...

  20. Reducing NOx in Fired Heaters and Boilers

    E-Print Network [OSTI]

    Garg, A.

    -6, 2000 Reducing NOx in Fired Heaters Air Pollution Control and Boilers Keeping the environment clean Presented by Ashutosh Garg Furnace Improvements Low cost solutions for fired heaters Trace compounds ? Nitric oxides ? Carbon monoxide ? Sulfur... it is essential to estimate accurately baseline NOx emissions. ? This will establish each units current compliance status. ? Emissions ? Current excess air level ? Carbon monoxide ? Combustibles ? NOx corrected to 3% 02 314 ESL-IE-00-04-46 Proceedings...

  1. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-10-20T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  2. Operating experience of Pyroflow boilers in a 250 MWe unit

    SciTech Connect (OSTI)

    Chelian, P.K.; Hyvarinen, K. [Pyropower Corp., San Diego, CA (United States)

    1995-12-31T23:59:59.000Z

    The Cedar Bay Cogeneration project is a 250 MWe unit owned and operated by US Generating Company. This plant has one turbine rated at 250 MWe net which is supplied by three Pyroflow CFB boilers that operate in parallel while supplying a paper mill with steam on an uninterruptible basis. Compared to similar size CFB boilers the Cedar Bay boilers have certain unique features. First, these are reheat boilers which must continue to supply process steam even when the steam turbine is down. Second, the SO{sub 2} control operates at a very low Ca/S molar ratio by optimizing the process conditions and flyash reinjection. Third, the NO{sub x} reduction process utilizes aqueous ammonia injection. This paper presents the operating data at full load in terms of boiler efficiency, and the ability to limit gaseous emissions with minimum limestone and ammonia usage. Unique features relating to the multiple boiler installation are also discussed.

  3. Boiler MACT 35000FT: Maximum Achievable Control Technology

    E-Print Network [OSTI]

    Robinson, J.

    2013-01-01T23:59:59.000Z

    fossil fuel is coal, petroleum coke, tire derived fuel, etc. ESL-IE-13-05-29 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 Classification-Boiler Subcategory Boiler Classification Pulverized... Heaters Affected ? Large affected units burning coal, oil, biomass, natural gas, other solid, liquid, gaseous non-waste materials ? Boilers or Process Heaters Not Affected ? Electric Utility Generating Unit (EGU) ?Waste Heat, hot water heaters...

  4. Build, Own, Operate and Maintain (BOOM) Boiler Systems

    E-Print Network [OSTI]

    Henry, T.

    Build, Own, Operate and Maintain (BOOM) Boiler Systems Tom Henry, Annstrong Service, Inc. Overview: The article addresses the growing trend in outsourcing boiler equipment, installation, operation, maintenance and ownership by large.... In most cases, thennal, electric and air energy systems are not considered "core" assets resulting in the need to find "other" solutions to providing the needed energy. ? Reduced staffing has resulted in fewer experienced and knowledgeable boiler...

  5. Supercritical Fluid Extraction- Process Simulation and Design

    E-Print Network [OSTI]

    Martin, C. L.; Seibert, A. F.

    SIMULATION P-1 SFE FEED PUMP SUPERCRITICAL FLUID EXTRACTOR (SFE) 2 T-1 10 7 .r D-2 SFE BOnoMS FLASH 9 222 The extract is decanted and fed to the fractionator to recover solvent carbon dioxide overhead and waterlIPA/carbon dioxide out...

  6. Chemical deposition methods using supercritical fluid solutions

    DOE Patents [OSTI]

    Sievers, Robert E. (Boulder, CO); Hansen, Brian N. (Boulder, CO)

    1990-01-01T23:59:59.000Z

    A method for depositing a film of a desired material on a substrate comprises dissolving at least one reagent in a supercritical fluid comprising at least one solvent. Either the reagent is capable of reacting with or is a precursor of a compound capable of reacting with the solvent to form the desired product, or at least one additional reagent is included in the supercritical solution and is capable of reacting with or is a precursor of a compound capable of reacting with the first reagent or with a compound derived from the first reagent to form the desired material. The supercritical solution is expanded to produce a vapor or aerosol and a chemical reaction is induced in the vapor or aerosol so that a film of the desired material resulting from the chemical reaction is deposited on the substrate surface. In an alternate embodiment, the supercritical solution containing at least one reagent is expanded to produce a vapor or aerosol which is then mixed with a gas containing at least one additional reagent. A chemical reaction is induced in the resulting mixture so that a film of the desired material is deposited.

  7. Modeling of a Drum Boiler Using MATLAB/Simulink.

    E-Print Network [OSTI]

    Anderson, Scott B.

    2008-01-01T23:59:59.000Z

    ?? A dynamic simulator was developed for a natural circulation drum type boiler through a joint Youngstown State University/The Babcock and Wilcox Company cooperative agreement.… (more)

  8. Application of Boiler Op for combustion optimization at PEPCO

    SciTech Connect (OSTI)

    Maines, P.; Williams, S. [Potomac Electric Power Co., Upper Marlsboro, MD (United States); Levy, E. [Lehigh Univ., Bethlehem, PA (United States). Energy Research Center

    1997-09-01T23:59:59.000Z

    Title IV requires the reduction of NOx at all stations within the PEPCO system. To assist PEPCO plant personnel in achieving low heat rates while meeting NOx targets, Lehigh University`s Energy Research Center and PEPCO developed a new combustion optimization software package called Boiler Op. The Boiler Op code contains an expert system, neural networks and an optimization algorithm. The expert system guides the plant engineer through a series of parametric boiler tests, required for the development of a comprehensive boiler database. The data are then analyzed by the neural networks and optimization algorithm to provide results on the boiler control settings which result in the best possible heat rate at a target NOx level or produce minimum NOx. Boiler Op has been used at both Potomac River and Morgantown Stations to help PEPCO engineers optimize combustion. With the use of Boiler Op, Morgantown Station operates under low NOx restrictions and continues to achieve record heat rate values, similar to pre-retrofit conditions. Potomac River Station achieves the regulatory NOx limit through the use of Boiler Op recommended control settings and without NOx burners. Importantly, any software like Boiler Op cannot be used alone. Its application must be in concert with human intelligence to ensure unit safety, reliability and accurate data collection.

  9. FEMP Technology Brief: Boiler Combustion Control and Monitoring System

    Broader source: Energy.gov [DOE]

    There are more than 45,000 industrial and commercial boilers larger than 10 MMBtu/hr in the United States with a total fuel input capacity of 2.7 million MMBtu/hr. Efficiency of existing boilers can be improved in three ways; replacement with new boilers, replacement of the burner, or installation of a combustion control system. While installation of a new boiler or replacement of the burner can lead to the greatest efficiency gains, the higher costs associated with these measures typically leads to longer payback periods than combustion control systems.

  10. Field Test of Boiler Primary Loop Temperature Controller

    SciTech Connect (OSTI)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01T23:59:59.000Z

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and in some cases return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential. PARR installed and monitored the performance of one type of ALM controller, the M2G from Greffen Systems, at multifamily sites in the city of Chicago and its suburb Cary, IL, both with existing OTR control. Results show that energy savings depend on the degree to which boilers are over-sized for their load, represented by cycling rates. Also savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, over-sized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less over-sized boilers at another site showed muted savings.

  11. Robust Output Feedback Stabilization of Nonlinear Interconnected Systems with Application to an Industrial Utility Boiler

    E-Print Network [OSTI]

    Marquez, Horacio J.

    to an Industrial Utility Boiler Adarsha Swarnakar, Horacio Jose Marquez and Tongwen Chen Abstract-- This paper boiler (Utility boiler), where the nonlinear model describes the complicated dynamics of the drum

  12. Life-cycle cost analysis of energy efficiency design options for residential furnaces and boilers

    E-Print Network [OSTI]

    Lutz, James; Lekov, Alex; Whitehead, Camilla Dunham; Chan, Peter; Meyers, Steve; McMahon, James

    2004-01-01T23:59:59.000Z

    9 Hot-Water Oil Boiler LCC Analysis-Efficiency Levels and10 Hot-Water Gas Boiler LCC Analysis-Efficiency Levels andfurnace and boiler energy-efficiency standards. Determining

  13. Characterization of the U.S. Industrial/Commercial Boiler Population...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Characterization of the U.S. IndustrialCommercial Boiler Population - Final Report, May 2005 Characterization of the U.S. IndustrialCommercial Boiler Population - Final Report,...

  14. Guide to Combined Heat and Power Systems for Boiler Owners and...

    Broader source: Energy.gov (indexed) [DOE]

    Combined Heat and Power Systems for Boiler Owners and Operators Guide to Combined Heat and Power Systems for Boiler Owners and Operators This guide presents useful information for...

  15. Boiler Efficiency vs. Steam Quality- The Challenge of Creating Quality Steam Using Existing Boiler Efficiencies

    E-Print Network [OSTI]

    Hahn, G.

    A boiler works under pressure and it is not possible to see what is happening inside of it. The terms "wet steam" and "carry over" are every day idioms in the steam industry, yet very few people have ever seen these phenomena and the actual water...

  16. Modification of boiler operating conditions for mercury emissions reductions in coal-fired utility boilers

    E-Print Network [OSTI]

    Li, Ying

    matter and char, and cold-end air pollution control devices. There is also evidence that boiler is equipped with hot and cold precipitators and a tubular air preheater. A strategy for mercury control designated hazardous air pollutants by the US Environmental Protection Agency (EPA), mercury (Hg) has

  17. List of Boilers Incentives | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpInc Place:KeystoneSolar (Texas) JumpEventBoilers Incentives Jump to:

  18. Introduction to the Boiler MACT Energy Assessment Process

    E-Print Network [OSTI]

    Theising, T. R.

    2014-01-01T23:59:59.000Z

    served from affected boiler(s) that are under BASF’s control. • Review of architectural/engineering plans, facility O&M procedures/logs, and fuel usage • Review of facility’s energy management practice and provide recommendations for improvement where...

  19. Boiler Gold Rush Prof. Johnny Brown (MATH 700)

    E-Print Network [OSTI]

    Brown, Johnny E.

    Boiler Gold Rush Prof. Johnny Brown (MATH 700) jeb@math.purdue.edu #12;#12;#12;David McCullough, Jr help Always be prepared #12;Boiler Gold Rush Prof. Johnny Brown (MATH 700) jeb@math.purdue.edu #12;

  20. Stack Gas Heat Recovery from 100 to 1200 HP Boilers

    E-Print Network [OSTI]

    Judson, T. H.

    1980-01-01T23:59:59.000Z

    in reduced production and caused personnel layoffs. U.S. Government reports indicate that roughly 20% of all fuel is consumed in boilers. A savings in boiler fuel consumption can have a positive impact on energy conservation, and become an important component...

  1. How to Evaluate Low Excess Air Controls for Packaged Boilers

    E-Print Network [OSTI]

    Londerville, S. B.; Kerler, W. J.

    1984-01-01T23:59:59.000Z

    characteristics within your boiler so that a reliable estimate of the efficiency gain from LEA firing can be determined. Recall that heat transfer takes place in three main areas of the boiler-the radiant section, convection bank, and heat recovery equipment...

  2. E-Print Network 3.0 - advanced supercritical light Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    liquid-like densities of supercritical fluids. Even... demonstrated using propane at subcritical and supercritical temperatures between 35 C and 97 C ... Source: Stanford...

  3. IECM OverviewIECM Overview Edward S. Rubin

    E-Print Network [OSTI]

    Resource use EnvironmentalEnvironmental EmissionsEmissions -- Air, water, landAir, water, land Plant & Process · Mechanical treatment Boiler/Turbine Types · Subcritical · Supercritical · Ultra-supercritical Furnace Firing Process Condensate Treatment Auxiliary Equipment Cooling Water System · Once-through · Wet cooling tower

  4. A Flexural Mode Tuning Technique for Membraned Boiler Tubing

    SciTech Connect (OSTI)

    Quarry, M J; Chinn, D J; Rose, J L

    2005-03-21T23:59:59.000Z

    Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the cold side or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications.

  5. Candidate Materials Evaluation for Supercritical Water-Cooled Reactor

    SciTech Connect (OSTI)

    T. R. Allen and G. S. Was

    2008-12-12T23:59:59.000Z

    Final technical report on the corrosion, stress corrosion cracking, and radiation response of candidate materials for the supercritical water-cooled reactor concept.

  6. High Density Thermal Energy Storage with Supercritical Fluids...

    Broader source: Energy.gov (indexed) [DOE]

    concept using supercritical fluids - Enhanced penetration of solar thermal for baseload power - Waste heat capture * Presents feasibility looking at thermodynamics of...

  7. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon...

    Broader source: Energy.gov (indexed) [DOE]

    chemistrybutchercarbonationmechanism.pdf More Documents & Publications Synchrotron X-ray Studies of Super-critical Carbon Dioxide Reservoir Rock Interfaces Innovative...

  8. Platinum/Carbon Nanotube Nanocomposite Synthesized in Supercritical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PlatinumCarbon Nanotube Nanocomposite Synthesized in Supercritical Fluid as Electrocatalysts for Low-Temperature Fuel Cells. PlatinumCarbon Nanotube Nanocomposite Synthesized in...

  9. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25T23:59:59.000Z

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  10. Supercriticality to subcriticality in dynamo transitions

    SciTech Connect (OSTI)

    Verma, Mahendra K. [Department of Physics, Indian Institute of Technology, Kanpur 208016 (India)] [Department of Physics, Indian Institute of Technology, Kanpur 208016 (India); Yadav, Rakesh K. [Max-Planck-Institut für Sonnensystemforschung, Max Planck Strasse 2, 37191 Katlenburg-Lindau (Germany)] [Max-Planck-Institut für Sonnensystemforschung, Max Planck Strasse 2, 37191 Katlenburg-Lindau (Germany)

    2013-07-15T23:59:59.000Z

    Evidence from numerical simulations suggests that the nature of dynamo transition changes from supercritical to subcritical as the magnetic Prandtl number is decreased. To explore this interesting crossover, we first use direct numerical simulations to investigate the hysteresis zone of a subcritical Taylor-Green dynamo. We establish that a well defined boundary exists in this hysteresis region which separates dynamo states from the purely hydrodynamic solution. We then propose simple dynamo models which show similar crossover from supercritical to subcritical dynamo transition as a function of the magnetic Prandtl number. Our models show that the change in the nature of dynamo transition is connected to the stabilizing or de-stabilizing influence of governing non-linearities.

  11. Establishing an energy efficiency recommendation for commercial boilers

    SciTech Connect (OSTI)

    Ware, Michelle J.

    2000-08-01T23:59:59.000Z

    To assist the federal government in meeting its energy reduction goals, President Clinton's Executive Order 12902 established the Procurement Challenge, which directed all federal agencies to purchase equipment within the top 25th percentile of efficiency. Under the direction of DOE's Federal Energy Management Program (FEMP), the Procurement Challenge's goal is to create efficiency recommendations for all energy-using products that could substantially impact the government's energy reduction goals, like commercial boilers. A typical 5,000,000 Btuh boiler, with a thermal efficiency of 83.2%, can have lifetime energy cost savings of $40,000 when compared to a boiler with a thermal efficiency of 78%. For the federal market, which makes up 2% of the boiler market, this means lifetime energy cost savings of over $25,600,000. To establish efficiency recommendations, FEMP uses standardized performance ratings for products sold in the marketplace. Currently, the boiler industry uses combustion efficiency and, sometimes, thermal efficiency performance measures when specifying a commercial boiler. For many years, the industry has used these efficiency measures interchangeably, causing confusion about boiler performance measurements, and making it difficult for FEMP to establish the top 25th percentile of efficiency. This paper will illustrate the method used to establish FEMP's recommendation for boilers. The method involved defining a correlation between thermal and combustion efficiency among boiler classifications; using the correlation to model a data set of all the boiler types available in the market; and identifying how the correlation affected the top 25th percentile analysis. The paper also will discuss the applicability of this method for evaluating other equipment for which there are limited data on performance ratings.

  12. Coiled tubing drilling with supercritical carbon dioxide

    DOE Patents [OSTI]

    Kolle , Jack J. (Seattle, WA)

    2002-01-01T23:59:59.000Z

    A method for increasing the efficiency of drilling operations by using a drilling fluid material that exists as supercritical fluid or a dense gas at temperature and pressure conditions existing at a drill site. The material can be used to reduce mechanical drilling forces, to remove cuttings, or to jet erode a substrate. In one embodiment, carbon dioxide (CO.sub.2) is used as the material for drilling within wells in the earth, where the normal temperature and pressure conditions cause CO.sub.2 to exist as a supercritical fluid. Supercritical carbon dioxide (SC--CO.sub.2) is preferably used with coiled tube (CT) drilling equipment. The very low viscosity SC--CO.sub.2 provides efficient cooling of the drill head, and efficient cuttings removal. Further, the diffusivity of SC--CO.sub.2 within the pores of petroleum formations is significantly higher than that of water, making jet erosion using SC--CO.sub.2 much more effective than water jet erosion. SC--CO.sub.2 jets can be used to assist mechanical drilling, for erosion drilling, or for scale removal. A choke manifold at the well head or mud cap drilling equipment can be used to control the pressure within the borehole, to ensure that the temperature and pressure conditions necessary for CO.sub.2 to exist as either a supercritical fluid or a dense gas occur at the drill site. Spent CO.sub.2 can be vented to the atmosphere, collected for reuse, or directed into the formation to aid in the recovery of petroleum.

  13. Sulphidation resistance of composite boiler tube materials

    SciTech Connect (OSTI)

    Kish, Joseph [McMaster University; Eng, Philip [FPInnovations; Singbeil, Douglas [FPInnovations; Keiser, James R [ORNL

    2008-01-01T23:59:59.000Z

    A lab-based testing program was undertaken to generate data to better define the sulphidation resistance of composite tubes installed in the lower-furnace section of black liquor recovery boilers. All composite tube cladding alloys tested were observed to have an acceptable corrosion rate at normal operating temperatures (up to 400 C) in the synthetic lower-furnace gaseous environment tested (1% H{sub 2}S-99% N{sub 2}). This acceptable corrosion resistance is due to the expected formation of a relatively protective chromium-rich inner sulphide scale. An increase in temperature up to 560 C was found to significantly increase the corrosion rate. Of the various alloys tested, Alloy HR11N exhibited the lowest corrosion rate at each of the three temperatures tested. Moreover, the corrosion rate was found not to be strongly dependent on the fabrication route (weld overlay versus co-extruded). To minimize corrosion, operating conditions that promote prolonged exposure to elevated temperatures in the lower-furnace section of black liquor recovery boilers should be avoided, regardless of the type of composite tube installed.

  14. Advanced Thermal Storage for Central Receivers with Supercritical Coolants

    SciTech Connect (OSTI)

    Kelly, Bruce D.

    2010-06-15T23:59:59.000Z

    The principal objective of the study is to determine if supercritical heat transport fluids in a central receiver power plant, in combination with ceramic thermocline storage systems, offer a reduction in levelized energy cost over a baseline nitrate salt concept. The baseline concept uses a nitrate salt receiver, two-tank (hot and cold) nitrate salt thermal storage, and a subcritical Rankine cycle. A total of 6 plant designs were analyzed, as follows: Plant Designation Receiver Fluid Thermal Storage Rankine Cycle Subcritical nitrate salt Nitrate salt Two tank nitrate salt Subcritical Supercritical nitrate salt Nitrate salt Two tank nitrate salt Supercritical Low temperature H2O Supercritical H2O Two tank nitrate salt Supercritical High temperature H2O Supercritical H2O Packed bed thermocline Supercritical Low temperature CO2 Supercritical CO2 Two tank nitrate salt Supercritical High temperature CO2 Supercritical CO2 Packed bed thermocline Supercritical Several conclusions have been drawn from the results of the study, as follows: 1) The use of supercritical H2O as the heat transport fluid in a packed bed thermocline is likely not a practical approach. The specific heat of the fluid is a strong function of the temperatures at values near 400 °C, and the temperature profile in the bed during a charging cycle is markedly different than the profile during a discharging cycle. 2) The use of supercritical CO2 as the heat transport fluid in a packed bed thermocline is judged to be technically feasible. Nonetheless, the high operating pressures for the supercritical fluid require the use of pressure vessels to contain the storage inventory. The unit cost of the two-tank nitrate salt system is approximately $24/kWht, while the unit cost of the high pressure thermocline system is nominally 10 times as high. 3) For the supercritical fluids, the outer crown temperatures of the receiver tubes are in the range of 700 to 800 °C. At temperatures of 700 °C and above, intermetallic compounds can precipitate between, and within, the grains of nickel alloys. The precipitation leads to an increase in tensile strength, and a decrease in ductility. Whether the proposed tube materials can provide the required low cycle fatigue life for the supercritical H2O and CO2 receivers is an open question. 4) A ranking of the plants, in descending order of technical and economic feasibility, is as follows: i) Supercritical nitrate salt and baseline nitrate salt: equal ratings ii) Low temperature supercritical H2O iii) Low temperature supercritical CO2 iv) High temperature supercritical CO2 v) High temperature supercritical H2O 5) The two-tank nitrate salt thermal storage systems are strongly preferred over the thermocline systems using supercritical heat transport fluids.

  15. Energy Conservation Program: Energy Conservation Standards for Residential Boilers, Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Residential Boilers, Notice of Proposed Rulemaking

  16. Decentralized robust PI controller design for an industrial boiler Batool Labibi a,*, Horacio Jose Marquez b

    E-Print Network [OSTI]

    Marquez, Horacio J.

    Decentralized robust PI controller design for an industrial boiler Batool Labibi a,*, Horacio Jose in revised form 23 April 2008 Accepted 23 April 2008 Keywords: Industrial utility boiler Internal model boiler, a control oriented nonlinear model for the boiler is identified. The nonlinearity of the system

  17. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan

    2002-04-15T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), and up to 5500 psi with emphasis upon 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally-acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national perspective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  18. Boiler Upgrades and Decentralizing Steam Systems Save Water and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    replacing its central plant with a combination of distributed boilers and ground source heat pumps. The results saved more than 1 million MBtu in energy and 19,574 Kgal of water...

  19. Application of Multivariable Control to Oil and Coal Fired Boilers

    E-Print Network [OSTI]

    Swanson, K.

    1981-01-01T23:59:59.000Z

    Increased visibility provided by advanced measurement and control techniques has shown that control of oil and coal fired boilers is a complex problem involving simultaneous determination of flue gas carbon monoxide, hydrocarbon, opacity...

  20. Application of Oxygen Trim Control to Small Packaged Boilers

    E-Print Network [OSTI]

    Nelson, R. L.

    1984-01-01T23:59:59.000Z

    control. New mechanical interfaces capable of modifying the relationship between the air and fuel linkage on existing boilers without expensive jackshaft modification or installation difficulties has significantly reduce the installed cost. A field...

  1. A Boiler Plant Energy Efficiency and Load Balancing Survey

    E-Print Network [OSTI]

    Nutter, D. W.; Murphy, D. R.

    Daily energy use data was used to perform an energy efficiency survey of a medium-sized university boiler plant. The physical plant operates centralized mechanical plants to provide both chilled water and steam for building conditioning. Steam...

  2. Heat Recovery Consideration for Process Heaters and Boilers

    E-Print Network [OSTI]

    Kumar, A.

    1984-01-01T23:59:59.000Z

    The largest single area for industrial energy conservation is in the improvement of combustion efficiencies for heaters and boilers. A number of methods can be employed to recover heat. The most common are by use of recuperative air preheaters...

  3. Heat Recovery Consideration for Process Heaters and Boilers

    E-Print Network [OSTI]

    Kumar, A.

    1983-01-01T23:59:59.000Z

    The largest single area for industrial energy conservation is in the improvement of combustion efficiencies for heaters and boilers. A number of methods can be employed to recover heat. The most common are by use of recuperative air preheaters...

  4. Cost-Effective Industrial Boiler Plant Efficiency Advancements

    E-Print Network [OSTI]

    Fiorino, D. P.

    Natural gas and electricity are expensive to the extent that annual fuel and power costs can approach the initial cost of an industrial boiler plant. Within this context, this paper examines several cost-effective efficiency advancements that were...

  5. Improving Boiler Efficiency Modeling Based on Ambient Air Temperature

    E-Print Network [OSTI]

    Zhou, J.; Deng, S.; Claridge, D. E.; Haberl, J. S.; Turner, W. D.

    Optimum economic operation in a large power plant can cut operating costs substantially. Individual plant equipment should be operated under conditions that are most favorable for maximizing its efficiency. It is widely accepted that boiler load...

  6. Dissimilar-metal weld failures in boiler tubing

    SciTech Connect (OSTI)

    Klueh, R.L.

    1984-02-01T23:59:59.000Z

    Both ferritic heat-resisting steels and austenitic stainless steels are used for fossil-fired boilers for central power stations. The use of these two different types of materials within the system leads to the need for a dissimilar-metal weld transition joint. Increased cyclic operation of boilers has led to a rash of failures in welds between dissimilar metals; studies have identified the causes, and improved nondestructive testing techniques permit early identification of problem areas.

  7. Climate Wise Boiler and Steam Efficiency Wise Rules

    E-Print Network [OSTI]

    Milmoe, P. H.; Winkelman, S. R.

    (and excess oxygen, 02), boiler tube cleaning, and re-calibration of boiler controls. ? A good tune-up with preclSlon testing equipment can detect and correct excess air losses, smoking, unbumed fuel losses, sooting, and high stack temperatures... control 7. Utilize characterizable fuel valve 8. Convert to atomizing burners Stack Losses and Waste Heat Recovery 9. Reduce net stack temperature by 40 of 10. Utilize stack dampers II. Direct contact condensation heat recovery 12. Pre...

  8. Optimized, Competitive Supercritical-CO2 Cycle GFR for Gen IV Service

    SciTech Connect (OSTI)

    M.J. Driscoll; P. Hejzlar; G. Apostolakis

    2008-09-08T23:59:59.000Z

    An overall plant design was developed for a gas-cooled fast reactor employing a direct supercritical Brayton power conversion system. The most important findings were that (1) the concept could be capital-cost competitive, but startup fuel cycle costs are penalized by the low core power density, specified in large part to satisfy the goal of significatn post-accident passive natural convection cooling; (2) active decay heat removal is preferable as the first line of defense, with passive performance in a backup role; (3) an innovative tube-in-duct fuel assembly, vented to the primpary coolant, appears to be practicable; and (4) use of the S-Co2 GFR to support hydrogen production is a synergistic application, since sufficient energy can be recuperated from the product H2 and 02 to allow the electrolysis cell to run 250 C hotter than the reactor coolant, and the water boilers can be used for reactor decay heat removal. Increasing core poer density is identified as the top priority for future work on GFRs of this type.

  9. Notice of construction for proposed backup package boiler

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    The Hanford Site steam plant consists of coal-fired boilers located at the 200 East and the 200 West Areas. These boilers have provided steam to heat and cool facilities in the 200 Areas since the early 1940`s. As part of Project L-017, ``Steam System Rehabilitation, Phase II``, the 200 West Area coal-fired boilers will be permanently shut down. The shut down will only occur after a proposed package backup boiler (50,000 pounds per hour (lb/hr) steam, firing No. 2 oil) is installed at the 200 West Area. The proposed backup boiler will provide back-up services when the 200 East Area steam line, which provides steam to the 200 West Area, is down for maintenance or, when the demand for steam exceeds the supply available from the 200 East Plant. This application is a request for approval to construct and operate the package backup boiler. This request is being made pursuant to Washington Administration Code (WAC) Chapter 173-400, ``General Regulations for Air Pollution Sources``, and Chapter 173-460, ``Controls for New Sources of Toxic Air Pollutants``.

  10. Guided wave acoustic monitoring of corrosion in recovery boiler tubing

    SciTech Connect (OSTI)

    Quarry, M J; Chinn, D J

    2004-02-19T23:59:59.000Z

    Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This Department of Energy, Office of Industrial Technologies project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the coldside or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications. This technique appears very promising for recovery boiler tube application, potentially expediting annual inspection of tube integrity.

  11. Low Carbon Footprint and Ultra Low NOx Boilers through Efficiency Gain

    E-Print Network [OSTI]

    Benz, R,; Staedter, M.

    2008-01-01T23:59:59.000Z

    control software. A UV or IR flame scanner is wired in series and closes the control circuit if and only if a flame is detected to prevent fuel from entering the combustion chamber without being burned. Other interlocks include: ? Purge Interlock... in environmental policy as well as vulnerability to fluctuating fuel prices require industrial and utility steam generation to find feasible, reliable and cost-effective solutions. Rather than focusing on alternative fuel types and drastic changes in plant...

  12. Advanced Combustion

    SciTech Connect (OSTI)

    Holcomb, Gordon R. [NETL

    2013-03-11T23:59:59.000Z

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  13. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30T23:59:59.000Z

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  14. Predictive modelling of boiler fouling. Final report.

    SciTech Connect (OSTI)

    Chatwani, A

    1990-12-31T23:59:59.000Z

    A spectral element method embodying Large Eddy Simulation based on Re- Normalization Group theory for simulating Sub Grid Scale viscosity was chosen for this work. This method is embodied in a computer code called NEKTON. NEKTON solves the unsteady, 2D or 3D,incompressible Navier Stokes equations by a spectral element method. The code was later extended to include the variable density and multiple reactive species effects at low Mach numbers, and to compute transport of large particles governed by inertia. Transport of small particles is computed by treating them as trace species. Code computations were performed for a number of test conditions typical of flow past a deep tube bank in a boiler. Results indicate qualitatively correct behavior. Predictions of deposition rates and deposit shape evolution also show correct qualitative behavior. These simulations are the first attempts to compute flow field results at realistic flow Reynolds numbers of the order of 10{sup 4}. Code validation was not done; comparison with experiment also could not be made as many phenomenological model parameters, e.g., sticking or erosion probabilities and their dependence on experimental conditions were not known. The predictions however demonstrate the capability to predict fouling from first principles. Further work is needed: use of large or massively parallel machine; code validation; parametric studies, etc.

  15. Postcombustion and its influences in 135 MWe CFB boilers

    SciTech Connect (OSTI)

    Shaohua Li; Hairui Yang; Hai Zhang; Qing Liu; Junfu Lu; Guangxi Yue [Tsinghua University, Beijing (China). Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering

    2009-09-15T23:59:59.000Z

    In the cyclone of a circulating fluidized bed (CFB) boiler, a noticeable increment of flue gas temperature, caused by combustion of combustible gas and unburnt carbon content, is often found. Such phenomenon is defined as post combustion, and it could introduce overheating of reheated and superheated steam and extra heat loss of exhaust flue gas. In this paper, mathematical modeling and field measurements on post combustion in 135MWe commercial CFB boilers were conducted. A novel one-dimensional combustion model taking post combustion into account was developed. With this model, the overall combustion performance, including size distribution of various ashes, temperature profile, and carbon content profiles along the furnace height, heat release fraction in the cyclone and furnace were predicted. Field measurements were conducted by sampling gas and solid at different positions in the boiler under different loads. The measured data and corresponding model-calculated results were compared. Both prediction and field measurements showed post combustion introduced a temperature increment of flue gas in the cyclone of the 135MWe CFB boiler in the range of 20-50{sup o}C when a low-volatile bituminous coal was fired. Although it had little influence on ash size distribution, post combustion had a remarkable influence on the carbon content profile and temperature profile in the furnace. Moreover, it introduced about 4-7% heat release in the cyclone over the total heat release in the boiler. This fraction slightly increased with total air flow rate and boiler load. Model calculations were also conducted on other two 135MWe CFB boilers burning lignite and anthracite coal, respectively. The results confirmed that post combustion was sensitive to coal type and became more severe as the volatile content of the coal decreased. 15 refs., 11 figs., 4 tabs.

  16. Corrosion Behavior of Candidate Alloys for Supercritical Water Reactors

    SciTech Connect (OSTI)

    Sridharan, K.; Zillmer, A.; Licht, J.R.; Allen, T.R.; Anderson, M.H.; Tan, L. [Department of Engineering Physics, University of Wisconsin, 1500 Engineering Drive, Madison, WI (United States)

    2004-07-01T23:59:59.000Z

    The corrosion and stress corrosion cracking behavior of metallic cladding and other core internal structures is critical to the success of the Generation IV Supercritical Water-cooled Reactors (SCWR). The eventual materials selected will be chosen based on the combined corrosion, stress-corrosion, mechanical performance, and radiation stability properties. Among the materials being considered are austenitic stainless steels, ferritic/martensitic steels, and nickel-base alloys. This paper reports initial studies on the corrosion performance of the candidate alloys 316 austenitic stainless steel, Inconel 718, and Zircaloy-2, all exposed to supercritical water at 300-500 deg. C in a corrosion loop at the University of Wisconsin. Long-term corrosion performance of AISI 347, also a candidate austenitic steel, has also been examined by sectioning samples from a component that was exposed for a period of about 30 years in supercritical water at the Genoa 3 Supercritical Water fossil power plant located in Genoa, Wisconsin. (authors)

  17. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus (Tucson, AZ); Yanagihara, Naohisa (Zacopan, MX); Dyke, James T. (Santa Fe, NM); Vemulapalli, Krishna (Tuscon, AZ)

    1991-09-03T23:59:59.000Z

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  18. An investigation of real gas effects in supercritical CO? compressors

    E-Print Network [OSTI]

    Baltadjiev, Nikola D. (Nikola Dimitrov)

    2012-01-01T23:59:59.000Z

    This thesis presents a comprehensive assessment of real gas effects on the performance and matching of centrifugal compressors operating with CO2 at supercritical conditions. The analytical framework combines first principles ...

  19. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...

    Broader source: Energy.gov (indexed) [DOE]

    that is compatible with s-CO2 cycles and modern thermal storage subsystems. Supercritical CO2 Brayton-cycle engines have the potential to increase conversion efficiency to...

  20. Characterization of Oxide Layers Formed During Corrosion in Supercritical Water

    E-Print Network [OSTI]

    Motta, Arthur T.

    .edu ABSTRACT The Supercritical Water Reactor is one of the Generation IV nuclear power plant designs envisioned of the Generation IV nuclear power plant designs envisioned for its high thermal efficiency and plant simplification

  1. Reactor physics design of supercritical CO?-cooled fast reactors

    E-Print Network [OSTI]

    Pope, Michael A. (Michael Alexander)

    2004-01-01T23:59:59.000Z

    Gas-Cooled Fast Reactors (GFRs) are among the GEN-IV designs proposed for future deployment. Driven by anticipated plant cost reduction, the use of supercritical CO? (S-CO?) as a Brayton cycle working fluid in a direct ...

  2. Autothermal oxidation of dilute aqueous wastes under supercritical conditions

    SciTech Connect (OSTI)

    Kodra, D.; Balakotaiah, V. (Univ. of Houston, TX (United States). Dept. of Chemical Engineering)

    1994-03-01T23:59:59.000Z

    Analysis of the autothermal wet oxidation of dilute aqueous wastes reveals some important differences between the subcritical and supercritical operation of this process. The energy requirements are considerably higher for supercritical operation and are comparable to those for incineration. The calculations show that the efficiency of the heat exchanger in the near-critical region decreases significantly and using a regenerative heat exchanger for supercritical operation requires excessive heat-transfer area even for wastewaters with heating values around 1,000 kJ/kg. Better results are obtained at higher pressures. This study demonstrates that autothermal operation of the supercritical wet oxidation process for dilute wastewaters is feasible only with the addition of auxiliary fuel.

  3. Control strategies for supercritical carbon dioxide power conversion systems

    E-Print Network [OSTI]

    Carstens, Nathan, 1978-

    2007-01-01T23:59:59.000Z

    The supercritical carbon dioxide (S-C02) recompression cycle is a promising advanced power conversion cycle which couples well to numerous advanced nuclear reactor designs. This thesis investigates the dynamic simulation ...

  4. Development of Materials for Supercritical-Water-Cooled Reactor

    Broader source: Energy.gov [DOE]

    Supercritical-Water-Cooled Reactor (SCWR) was selected as one of the promising candidates in Generation IV reactors for its prominent advantages; those are the high thermal efficiency, the system...

  5. New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement

    SciTech Connect (OSTI)

    Qu, Ming [Purdue University, West Lafayette, IN; Abdelaziz, Omar [ORNL; Yin, Hongxi [Southeast University, Nanjing, China

    2014-01-01T23:59:59.000Z

    Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150 200 C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50 60 C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural gas boilers for applications with process fluid return temperatures higher than or close to the dew point of the water vapor in the flue gas.

  6. Process for treating effluent from a supercritical water oxidation reactor

    DOE Patents [OSTI]

    Barnes, C.M.; Shapiro, C.

    1997-11-25T23:59:59.000Z

    A method for treating a gaseous effluent from a supercritical water oxidation reactor containing entrained solids is provided comprising the steps of expanding the gas/solids effluent from a first to a second lower pressure at a temperature at which no liquid condenses; separating the solids from the gas effluent; neutralizing the effluent to remove any acid gases; condensing the effluent; and retaining the purified effluent to the supercritical water oxidation reactor. 6 figs.

  7. Upgraded recovery boiler meets low air emissions standards

    SciTech Connect (OSTI)

    La Fond, J.F.; Jansen, J.H. (Jansen Combustion and Boiler Technologies, Inc., Woodinville, WA (United States)); Eide, P. (Boise Cascade Corp., International Falls, MN (United States))

    1994-12-01T23:59:59.000Z

    In the fall of 1990, the Boise Cascade mill in International Falls, MN, carried out a millwide modernization project. One critical element of the project was the upgrade of their recovery boiler. As a result of the recovery boiler upgrade, the mill was required to obtain a prevention of significant deterioration (PSD) air permit. A best available control technology (BACT) assessment was performed as a requirement of the PSD regulations. Ultimately, a number of more stringent air pollution emission limits were established for the boiler, and a continuous emissions monitoring system (CEMS) was purchased and installed to report daily results to the Minnesota Pollution Control Agency. This paper describes efforts to achieve increased firing capacity in the mill's recovery boiler while meeting more severe air emissions regulations. The authors will show that each of the emissions limits, including CO, SO[sub 2], NO[sub x], TRS, and opacity, are met by the upgraded boiler, while achieving an increase in firing capacity over pre-upgrade levels of up to 40%.

  8. Plasma-supported coal combustion in boiler furnace

    SciTech Connect (OSTI)

    Askarova, A.S.; Karpenko, E.I.; Lavrishcheva, Y.I.; Messerle, V.E.; Ustimenko, A.B. [Kazakh National University, Alma Ata (Kazakhstan). Dept. of Physics

    2007-12-15T23:59:59.000Z

    Plasma activation promotes more effective and environmentally friendly low-rank coal combustion. This paper presents Plasma Fuel Systems that increase the burning efficiency of coal. The systems were tested for fuel oil-free start-up of coal-fired boilers and stabilization of a pulverized-coal flame in power-generating boilers equipped with different types of burners, and burning all types of power-generating coal. Also, numerical modeling results of a plasma thermochemical preparation of pulverized coal for ignition and combustion in the furnace of a utility boiler are discussed in this paper. Two kinetic mathematical models were used in the investigation of the processes of air/fuel mixture plasma activation: ignition and combustion. A I-D kinetic code PLASMA-COAL calculates the concentrations of species, temperatures, and velocities of the treated coal/air mixture in a burner incorporating a plasma source. The I-D simulation results are initial data for the 3-D-modeling of power boiler furnaces by the code FLOREAN. A comprehensive image of plasma-activated coal combustion processes in a furnace of a pulverized-coal-fired boiler was obtained. The advantages of the plasma technology are clearly demonstrated.

  9. Slag monitoring system for combustion chambers of steam boilers

    SciTech Connect (OSTI)

    Taler, J.; Taler, D. [Cracow University of Technology, Krakow (Poland)

    2009-07-01T23:59:59.000Z

    The computer-based boiler performance system presented in this article has been developed to provide a direct and quantitative assessment of furnace and convective surface cleanliness. Temperature, pressure, and flow measurements and gas analysis data are used to perform heat transfer analysis in the boiler furnace and evaporator. Power boiler efficiency is calculated using an indirect method. The on-line calculation of the exit flue gas temperature in a combustion chamber allows for an on-line heat flow rate determination, which is transferred to the boiler evaporator. Based on the energy balance for the boiler evaporator, the superheated steam mass flow rate is calculated taking into the account water flow rate in attemperators. Comparing the calculated and the measured superheated steam mass flow rate, the effectiveness of the combustion chamber water walls is determined in an on-line mode. Soot-blower sequencing can be optimized based on actual cleaning requirements rather than on fixed time cycles contributing to lowering of the medium usage in soot blowers and increasing of the water-wall lifetime.

  10. Containment system for supercritical water oxidation reactor

    DOE Patents [OSTI]

    Chastagner, P.

    1994-07-05T23:59:59.000Z

    A system is described for containment of a supercritical water oxidation reactor in the event of a rupture of the reactor. The system includes a containment for housing the reaction vessel and a communicating chamber for holding a volume of coolant, such as water. The coolant is recirculated and sprayed to entrain and cool any reactants that might have escaped from the reaction vessel. Baffles at the entrance to the chamber prevent the sprayed coolant from contacting the reaction vessel. An impact-absorbing layer is positioned between the vessel and the containment to at least partially absorb momentum of any fragments propelled by the rupturing vessel. Remote, quick-disconnecting fittings exterior to the containment, in cooperation with shut-off valves, enable the vessel to be isolated and the system safely taken off-line. Normally-closed orifices throughout the containment and chamber enable decontamination of interior surfaces when necessary. 2 figures.

  11. Cyclone Boiler Reburn NOx Control Improvements via Cyclone Design Improvements and Advanced Air Staging

    E-Print Network [OSTI]

    Morabito, B.; Nee, B.; Goff, V.; Maringo, G.

    2008-01-01T23:59:59.000Z

    Eastman Kodak owns three Babcock & Wilcox coal fired cyclone boilers and one Combustion Engineering pulverized coal boiler located at Kodak Park in Rochester, New York. Duke Energy Generation Services (DEGS) operates and maintains the steam...

  12. Damage Modeling and Life Extending Control of a Boiler-Turbine System1

    E-Print Network [OSTI]

    Marquez, Horacio J.

    Damage Modeling and Life Extending Control of a Boiler-Turbine System1 Donglin Li Tongwen Chen2 hierarchical LEC structure and apply it to a typ- ical boiler system. There are two damage models

  13. From Basic Control to Optimized Systems-Applying Digital Control Systems to Steam Boilers

    E-Print Network [OSTI]

    Hockenbury, W. D.

    1982-01-01T23:59:59.000Z

    This presentation examines the application of Distributed Digital Controls in order to review the application of this recent control technology towards Steam Boilers in a step-by-step manner. The main purpose of a steam generating boiler...

  14. 2015-02-13 Issuance: Test Procedure for Furnaces and Boilers...

    Energy Savers [EERE]

    2015-02-13 Issuance: Test Procedure for Furnaces and Boilers; Notice of Proposed Rulemaking 2015-02-13 Issuance: Test Procedure for Furnaces and Boilers; Notice of Proposed...

  15. Guide to Combined Heat and Power Systems for Boiler Owners and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guide to Combined Heat and Power Systems for Boiler Owners and Operators, July 2004 Guide to Combined Heat and Power Systems for Boiler Owners and Operators, July 2004 Many owners...

  16. Ultra High Energy Behaviour

    E-Print Network [OSTI]

    Burra G. Sidharth

    2011-03-18T23:59:59.000Z

    We reexamine the behaviour of particles at Ultra Highe energies in the context of the fact that the LHC has already touched an energy of $7 TeV$ and is likely to attain $14 TeV$ by 2013/2014.Consequences like a possible new shortlived interaction within the Compton scale are discussed.

  17. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2001-10-23T23:59:59.000Z

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). Work reported herein addresses tasks performed in the fourth quarter as well as the other three quarters of the past year. The subjects that were covered in previous reports and that are also discussed in this report include: Analysis of field laboratory data of active cement applications from three oil-well service companies; Preliminary findings from a literature review focusing on problems associated with ultra-lightweight cements; Summary of pertinent information from Russian ultra-lightweight cement literature review; and Comparison of compressive strengths of ULHS systems using ultrasonic and crush methods Results reported from the fourth quarter include laboratory testing of ULHS systems along with other lightweight cement systems--foamed and sodium silicate slurries. These comparison studies were completed for two different densities (10.0 and 11.5 lb/gal) and three different field application scenarios. Additional testing included the mechanical properties of ULHS systems and other lightweight systems. Studies were also performed to examine the effect that circulation by centrifugal pump during mixing has on breakage of ULHS.

  18. Modeling of a coal-fired natural circulation boiler

    SciTech Connect (OSTI)

    Bhambare, K.S.; Mitra, S.K.; Gaitonde, U.N. [Indian Institute of Technology, Bombay (India). Dept. of Mechanical Engineering

    2007-06-15T23:59:59.000Z

    Modeling of a natural circulation boiler for a coal-fired thermal power station is presented here. The boiler system is divided into seven subcomponents, and for each section, models based on conservation of mass, momentum, and energy are formulated. The pressure drop at various sections and the heat transfer coefficients are computed using empirical correlations. Solutions are obtained by using SIMULINK. The model is validated by comparing its steady state and dynamic responses with the actual plant data. Open loop responses of the model to the step changes in the operating parameters, such as pressure, temperature, steam flow, feed water flow, are also analyzed. The present model can be used for the development and design of effective boiler control systems.

  19. COAL-FIRED UTILITY BOILERS: SOLVING ASH DEPOSITION PROBLEMS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Steven A. Benson; Jay R. Gunderson

    2001-04-01T23:59:59.000Z

    The accumulation of slagging and fouling ash deposits in utility boilers has been a source of aggravation for coal-fired boiler operators for over a century. Many new developments in analytical, modeling, and combustion testing methods in the past 20 years have made it possible to identify root causes of ash deposition. A concise and comprehensive guidelines document has been assembled for solving ash deposition as related to coal-fired utility boilers. While this report accurately captures the current state of knowledge in ash deposition, note that substantial research and development is under way to more completely understand and mitigate slagging and fouling. Thus, while comprehensive, this document carries the title ''interim,'' with the idea that future work will provide additional insight. Primary target audiences include utility operators and engineers who face plant inefficiencies and significant operational and maintenance costs that are associated with ash deposition problems. Pulverized and cyclone-fired coal boilers are addressed specifically, although many of the diagnostics and solutions apply to other boiler types. Logic diagrams, ash deposit types, and boiler symptoms of ash deposition are used to aid the user in identifying an ash deposition problem, diagnosing and verifying root causes, determining remedial measures to alleviate or eliminate the problem, and then monitoring the situation to verify that the problem has been solved. In addition to a step-by-step method for identifying and remediating ash deposition problems, this guideline document (Appendix A) provides descriptions of analytical techniques for diagnostic testing and gives extensive fundamental and practical literature references and addresses of organizations that can provide help in alleviating ash deposition problems.

  20. Boiler Kids Camp Parent Manual Division of Recreational Sports Mission Statement

    E-Print Network [OSTI]

    Ginzel, Matthew

    Boiler Kids Camp Parent Manual Division of Recreational Sports Mission Statement The Division which fosters an appreciation for a healthy lifestyle and promotes lifelong learning. Boiler Kids Camp Mission Statement Boiler Kids Camp is an interactive, summer day camp designed for children ranging

  1. Decentralized robust control of a class of nonlinear systems and application to a boiler system

    E-Print Network [OSTI]

    Marquez, Horacio J.

    Decentralized robust control of a class of nonlinear systems and application to a boiler system Keywords: Asymptotic disturbance rejection Boiler systems Decentralized robust control Descriptor systems problem, a decentralized controller for the system can be calculated. In order to control a utility boiler

  2. DETECTION OF EVENTS CAUSING PLUGGAGE OF A COAL-FIRED BOILER: A DATA MINING

    E-Print Network [OSTI]

    Kusiak, Andrew

    DETECTION OF EVENTS CAUSING PLUGGAGE OF A COAL-FIRED BOILER: A DATA MINING APPROACH ANDREW KUSIAK to analyze events leading to plug- gage of a boiler. The proposed approach involves statistics, data. The proposed approach has been tested on a 750 MW commercial coal-fired boiler affected with an ash fouling

  3. Development and Application of Gas Sensing Technologies to Enable Boiler Balancing

    E-Print Network [OSTI]

    Dutta, Prabir K.

    01/2004 Development and Application of Gas Sensing Technologies to Enable Boiler Balancing to monitor total NOx (0-1000 ppm), CO (0-1000 ppm) and O2 (1-15%) within the convective pass of the boiler of such sensor systems will dramatically alter how boilers are operated, since much of the emissions creation

  4. Full-Scale Boiler Measurements Demonstrating Striated Flows during Biomass Co-Firing

    E-Print Network [OSTI]

    ACERC-2008 Full-Scale Boiler Measurements Demonstrating Striated Flows during Biomass Co based measurements methods #12;Objective Minor impact of biomass cofiring with coal on boiler operation) · Experimentally demonstrate the existence of stratified flows in boilers Indication: SO2, ash composition, straw

  5. Optimal control of a multi-energy district boiler: a case study

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Optimal control of a multi-energy district boiler: a case study J. Eynard S. Grieu M. Polit of a multi-energy district boiler (La Rochelle, France) which supplies domestic hot water and heats optimizing the use of both the tank and the wood boiler. As a result, fossil energy consumption and CO2

  6. MODELLING OF A NONLINEAR MULTIVARIABLE BOILER PLANT USING HAMMERSTEIN MODEL, A NONPARAMETRIC APPROACH

    E-Print Network [OSTI]

    Al-Duwaish, Hussain N.

    MODELLING OF A NONLINEAR MULTIVARIABLE BOILER PLANT USING HAMMERSTEIN MODEL, A NONPARAMETRIC mathematically and prac- tically tractable. Boilers are industrial units, which are used for gener- ating steam of fuel. Boiler operation is a complex operation in which hot water must be delivered to a turbine

  7. Re ning Abstract Machine Speci cations of the Steam Boiler Control to Well Documented

    E-Print Network [OSTI]

    Börger, Egon

    Re ning Abstract Machine Speci cations of the Steam Boiler Control to Well Documented Executable the steam boiler control speci cation problem to il- lustrate how the evolving algebra approach to the speci, in June 1995, to control the Karlsruhe steam boiler simulator satisfactorily. The abstract machines

  8. Corrections to "Proving Safety Properties of the Steam Boiler Controller" Correction Sheet

    E-Print Network [OSTI]

    Lynch, Nancy

    Corrections to "Proving Safety Properties of the Steam Boiler Controller" 1 Correction Sheet After our paper "Proving Safety Properties of the Steam Boiler Controller" went already to print, Myla address http://theory.lcs.mit.edu/tds/boiler.html. Following are the corrections to these errors and some

  9. An Algebraic Speci cation of the Steam-Boiler Control System

    E-Print Network [OSTI]

    Bidoit, Michel

    An Algebraic Speci#12;cation of the Steam-Boiler Control System Michel Bidoit 1 , Claude Chevenier describe how to derive an algebraic speci#12;cation of the Steam-Boiler Control System starting from to specify the detection of the steam-boiler fail- ures. Finally we discuss validation and veri#12;cation

  10. welcome to university residences Boiler Gold Rush Check-In...........................Saturday, August 13 and

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    welcome to university residences #12;Boiler Gold Rush Check-In...........................Saturday, August 13 and Sunday, August 14, 2011 Boiler Gold Rush residence hall systems in the United States. weLcomE! 1 #12;Boiler GoLD Rush ParticiPants Your regular

  11. Analysis and control of a nonlinear boiler-turbine unit Wen Tan a,*,1

    E-Print Network [OSTI]

    Marquez, Horacio J.

    Analysis and control of a nonlinear boiler-turbine unit Wen Tan a,*,1 , Horacio J. Marquez b, and the concept is applied to a boiler-turbine unit to analyze its dynamics. It is shown that the unit shows. Keywords: Boiler-turbine unit; Nonlinearity measure; Gap metric; Anti-windup bumpless transfer techniques

  12. Wood Pellets for UBC Boilers Replacing Natural Gas Based on LCA

    E-Print Network [OSTI]

    Wood Pellets for UBC Boilers Replacing Natural Gas Based on LCA Submitted to Dr. Bi By Bernard Chan Pellets for UBC Boilers Replacing Natural Gas" By Bernard Chan, Brian Chan, and Christopher Young Abstract This report studies the feasibility of replacing natural gas with wood pellets for UBC boilers. A gasification

  13. Gain-scheduled `1 -optimal control for boiler-turbine dynamics

    E-Print Network [OSTI]

    Shamma, Jeff S.

    , into the mechanical energy acting on the turbine and generator. The steam generated in the boiler system servesGain-scheduled `1 -optimal control for boiler-turbine dynamics with actuator saturation Pang; accepted 2 June 2003 Abstract This paper presents a gain-scheduled approach for boiler-turbine controller

  14. Proving Safety Properties of the Steam Boiler Controller G. Leeb, N. Lynch Page 1 of 20

    E-Print Network [OSTI]

    Lynch, Nancy

    Proving Safety Properties of the Steam Boiler Controller G. Leeb, N. Lynch Page 1 of 20 Proving Safety Properties of the Steam Boiler Controller Formal Methods for Industrial Applications: A Case Study system consisting of a continuous steam boiler and a discrete controller. Our model uses the Lynch

  15. Revisiting the Steam-Boiler Case Study with LUTESS : Modeling for Automatic Test Generation

    E-Print Network [OSTI]

    Boyer, Edmond

    Revisiting the Steam-Boiler Case Study with LUTESS : Modeling for Automatic Test Generation. In this paper, we apply this modeling principle to a well known case study, the steam boiler problem which has model and to assess the difficulty of such a process in a realistic case study. The steam boiler case

  16. Assertional Specification and Verification using PVS of the Steam Boiler Control System

    E-Print Network [OSTI]

    Hooman, Jozef

    Assertional Specification and Verification using PVS of the Steam Boiler Control System Jan Vitt 1 of the steam boiler control system has been derived using a formal method based on assumption/commitment pairs Introduction The steam boiler control system, as described in chapter AS of this book, has been designed

  17. Proving Safety Properties of the Steam Boiler Controller G. Leeb, N. Lynch Page 1 of 37

    E-Print Network [OSTI]

    Lynch, Nancy

    Proving Safety Properties of the Steam Boiler Controller G. Leeb, N. Lynch Page 1 of 37 Proving Safety Properties of the Steam Boiler Controller Formal Methods for Industrial Applications: A Case Study system consisting of a continuous steam boiler and a discrete controller. Our model uses the Lynch

  18. Wood-Coal Fired "Small" Boiler Case Study

    E-Print Network [OSTI]

    Pincelli, R. D.

    1980-01-01T23:59:59.000Z

    extremely attrac t:i.ve to today's capital investment market. 7. Several states, including North Carolina, have enacted 15% State Tax Credits to further the use of wood fuel boilers. Specific examples of the utilization of wood as a boiler fuel include... on the fact that Galaxy would be purchasing all of its waste wood fuel, as well as supplemental coal if needed. Efficiency guarantees of 80% on wood waste with less than 10% moisture content were given, as well as 78.5% on coal. These efficiencies were...

  19. Forsterite [Mg2SiO4)] Carbonation in Wet Supercritical CO2: An...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forsterite Mg2SiO4) Carbonation in Wet Supercritical CO2: An in situ High Pressure X-Ray Diffraction Study. Forsterite Mg2SiO4) Carbonation in Wet Supercritical CO2: An in situ...

  20. Numerical simulations of supercritical water-hydrocarbon mixing in a 3-D cylindrical tee mixer

    E-Print Network [OSTI]

    Raghavan, Ashwin, S.M. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Supercritical water upgrading and desulfurization (SCWUDS) is a new concept in the oil refining industry wherein, crude oil is mixed with supercritical water in a reactor leading to chemical breakdown of the sulfur containing ...

  1. High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical...

    Office of Environmental Management (EM)

    High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1 High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2...

  2. Oxidation behavior of ferriticmartensitic and ODS steels in supercritical water Jeremy Bischoff

    E-Print Network [OSTI]

    Motta, Arthur T.

    in the Generation IV Supercritical Water Reactor. One of the main in-service degradation mech- anisms The Supercritical Water Reactor is one of the six Generation IV nuclear power plant designs and was envisioned

  3. NOx Control for Utility Boiler OTR Compliance

    SciTech Connect (OSTI)

    Hamid Farzan; Jennifer L. Sivy

    2005-07-30T23:59:59.000Z

    Babcock & Wilcox Power Generation Group (B&W) and Fuel Tech, Inc. (Fuel Tech) teamed to evaluate an integrated solution for NO{sub x} control comprised of B&W's DRB-4Z{reg_sign} low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NO{sub x}OUT{reg_sign}, a selective non-catalytic reduction (SNCR) technology, capable of meeting a target emission limit of 0.15 lb NO{sub x}/10{sup 6} Btu. In a previous project sponsored by the U.S. Department of Energy (DOE), promising results were obtained with this technology from large-scale testing in B&W's 100-million Btu/hr Clean Environment Development Facility (CEDF) which simulates the conditions of large coal-fired utility boilers. Under the most challenging boiler temperatures at full load conditions, NO{sub x} emissions of 0.19 lb/10{sup 6} Btu were achieved firing Powder River Basin coal while controlling ammonia slip to less than 5 ppm. At a 40 million Btu/hr firing rate, NO{sub x} emissions were as low as 0.09 lb/10{sup 6} Btu. Improved performance with this system was proposed for this new program with injection at full load via a convective pass multiple nozzle lance (MNL) in front of the superheater tubes or in the convective tube bank. Convective pass lances represent the current state-of-the-art in SNCR and needed to be evaluated in order to assess the full potential of the combined technologies. The objective of the program was to achieve a NO{sub x} level below 0.15 lb/10{sup 6} Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B&W's DRB-4Z{reg_sign} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign} System. Commercial installations of B&W's low-NO{sub x} burner, in combination with overfire air ports using PRB coal, have demonstrated a NO{sub x} level of 0.15 to 0.2 lb/10{sup 6} Btu under staged combustion conditions. The proposed goal of the combustion system (no SNCR) for this project is a NO{sub x} level at 0.15 lb/10{sup 6} Btu. The NO{sub x} reduction goal for SNCR is 25% from the low-NO{sub x} combustion emission levels. Therefore, overall NO{sub x} emissions would approach a level of 0.11 lb/10{sup 6} Btu in commercial installation. The goals of the program were met. At 100% load, using the MNL for very low baseline NO{sub x} (0.094 to 0.162 lb/10{sup 6} Btu depending on burner stoichiometry), an approximately 25% NO{sub x} reduction was achieved (0.071 to 0.124 lb/10{sup 6} Btu) while maintaining NH{sub 3} slip less than 6.4 ppm. At 60% load, using MNL or only wall-injectors for very low baseline NO{sub x} levels, more than 30% NO{sub x} reduction was achieved. Although site specific economic evaluation is required for each unit, our economic evaluation of DRB-4Z{reg_sign} burner and SNCR for a 500 MW{sub e} plant firing PRB shows that the least cost strategy is low-NO{sub x} burner and OFA at a cost of $210 to $525 per ton of NO{sub x} removed. Installation of SNCR allows the utilities to sell more NO{sub x} credit and it becomes economical when NO{sub x} credit cost is more than $5,275 per ton of NO{sub x}.

  4. Supercritical CO2Brayton Cycle Control Strategy for Autonomous Liquid Metal-Cooled Reactors

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J.J.

    2004-10-06T23:59:59.000Z

    This presentation discusses a supercritical carbon dioxide brayton cycle control strategy for autonomous liquid metal-cooled reactors.

  5. Low NOx burner retrofits and enhancements for a 518 MW oil and gas fired boiler

    SciTech Connect (OSTI)

    King, J.J. [Jacksonville Electric Authority, FL (United States); Allen, J.W.; Beal, P.R. [International Combustion Ltd., Derby (United Kingdom). Rolls-Royce Industrial Power Group

    1995-12-31T23:59:59.000Z

    Low NOx oil/gas burners originally supplied to Jacksonville Electric Authority, Northside No. 3 .500 MW unit, were based on a duplex air register design with lobed spray oil atomizers providing additional fuel staging. Although the burners could meet the targeted NOx levels of 0.3 and 0.2 lbs/10{sup 6} BTU on oil and gas respectively. There was insufficient margin on these NOx levels to enable continuous low NOx operation to be achieved. Further burner development was undertaken based on improved aerodynamic control within the burner design to give an approximate 25% improvement in NOx emission reduction thus providing an adequate operating margin. This `RoBTAS` (Round Burner with Tilted Air Supply) burner design based on techniques developed successfully for front wall coal firing applications achieved the required NOx reductions in full scale firing demonstrations on both heavy fuel oil and natural gas firing. The paper describes the development work and the subsequent application of the `RoBTAS` burners to the Northside No. 3 boiler. The burner will also be test fired on Orimulsion fuel and thus the comparison between heavy fuel oil firing and Orimulsion firing under ultra low NOx conditions will be made.

  6. 10 MW Supercritical CO2 Turbine Test

    SciTech Connect (OSTI)

    Turchi, Craig

    2014-01-29T23:59:59.000Z

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700°C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650şC in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late in Phase 1 an opportunity arose to collaborate with another turbine-development team to construct a shared s-CO2 test facility. The synergy of the combined effort would result in greater facility capabilities than either separate project could produce and would allow for testing of both turbine designs within the combined budgets of the two projects. The project team requested a no-cost extension to Phase 1 to modify the subsequent work based on this collaborative approach. DOE authorized a brief extension, but ultimately opted not to pursue the collaborative facility and terminated the project.

  7. Corrosion of Zirconium-based Fuel Cladding Alloys in Supercritical Water. Y.H. Jeong1

    E-Print Network [OSTI]

    Motta, Arthur T.

    Corrosion of Zirconium-based Fuel Cladding Alloys in Supercritical Water. Y.H. Jeong1 , J.Y. Park1, University Park, PA 16802, USA. Keywords: Zirconium alloys, corrosion, supercritical water Abstract Corrosion to evaluate the potential use of Zr alloy cladding in the supercritical water reactor (SCWR). Corrosion tests

  8. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

    2010-01-12T23:59:59.000Z

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  9. Best Management Practice #8: Boiler and Steam Systems

    Broader source: Energy.gov [DOE]

    Boilers and steam generators are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size, the amount of steam used, and the amount of condensate returned.

  10. Extraction of metals using supercritical fluid and chelate forming legand

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Laintz, Kenneth E. (Los Alamos, NM)

    1998-01-01T23:59:59.000Z

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent is described. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated .beta.-diketone. In especially preferred embodiments the extraction solvent is supercritical carbon dioxide, and the chelating agent comprises a fluorinated .beta.-diketone and a trialkyl phosphate, or a fluorinated .beta.-diketone and a trialkylphosphine oxide. Although a trialkyl phosphate can extract lanthanides and actinides from acidic solutions, a binary mixture comprising a fluorinated .beta.-diketone and a trialkyl phosphate or a trialkylphosphine oxide tends to enhance the extraction efficiencies for actinides and lanthanides. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The method is particularly useful for extracting actinides and lanthanides from acidic solutions. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  11. Extraction of metals using supercritical fluid and chelate forming ligand

    DOE Patents [OSTI]

    Wai, C.M.; Laintz, K.E.

    1998-03-24T23:59:59.000Z

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent is described. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated {beta}-diketone. In especially preferred embodiments the extraction solvent is supercritical carbon dioxide, and the chelating agent comprises a fluorinated {beta}-diketone and a trialkyl phosphate, or a fluorinated {beta}-diketone and a trialkylphosphine oxide. Although a trialkyl phosphate can extract lanthanides and actinides from acidic solutions, a binary mixture comprising a fluorinated {beta}-diketone and a trialkyl phosphate or a trialkylphosphine oxide tends to enhance the extraction efficiencies for actinides and lanthanides. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The method is particularly useful for extracting actinides and lanthanides from acidic solutions. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

  12. Experimental study of elliptical jet from sub to supercritical conditions

    SciTech Connect (OSTI)

    Muthukumaran, C. K.; Vaidyanathan, Aravind, E-mail: aravind7@iist.ac.in [Department of Aerospace Engineering, Indian Institute of Space Science and Technology, Trivandrum, Kerala 695547 (India)] [Department of Aerospace Engineering, Indian Institute of Space Science and Technology, Trivandrum, Kerala 695547 (India)

    2014-04-15T23:59:59.000Z

    The jet mixing at supercritical conditions involves fluid dynamics as well as thermodynamic phenomena. All the jet mixing studies at critical conditions to the present date have focused only on axisymmetric jets. When the liquid jet is injected into supercritical environment, the thermodynamic transition could be well understood by considering one of the important fluid properties such as surface tension since it decides the existence of distinct boundary between the liquid and gaseous phase. It is well known that an elliptical liquid jet undergoes axis-switching phenomena under atmospheric conditions due to the presence of surface tension. The experimental investigations were carried out with low speed elliptical jet under supercritical condition. Investigation of the binary component system with fluoroketone jet and N{sub 2} gas as environment shows that the surface tension force dominates for a large downstream distance, indicating delayed thermodynamic transition. The increase in pressure to critical state at supercritical temperature is found to expedite the thermodynamic transition. The ligament like structures has been observed rather than droplets for supercritical pressures. However, for the single component system with fluoroketone jet and fluoroketone environment shows that the jet disintegrates into droplets as it is subjected to the chamber conditions even for the subcritical pressures and no axis switching phenomenon is observed. For a single component system, as the pressure is increased to critical state, the liquid jet exhibits gas-gas like mixing behavior and that too without exhibiting axis-switching behavior.

  13. Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications

    SciTech Connect (OSTI)

    Levasseur, Armand

    2014-01-01T23:59:59.000Z

    This Topical Report outlines guidelines and key considerations for design and operation of pulverized coal-fired boilers for oxy-combustion. The scope addressed includes only the boiler island, not the entire oxy-fired CO{sub 2} capture plant. These guidelines are primarily developed for tangential-fired boilers and focus on designs capable of dual air and oxy-fired operation. The guidelines and considerations discussed are applicable to both new units and existing boiler retrofits. These guidelines are largely based on the findings from the extensive 15 MW{sub th} pilot testing and design efforts conducted under this project. A summary level description is provided for each major aspect of boiler design impacted by oxy-combustion, and key considerations are discussed for broader application to different utility and industrial designs. Guidelines address the boiler system arrangement, firing system, boiler thermal design, ducting, materials, control system, and other key systems.

  14. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

    2001-10-10T23:59:59.000Z

    This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

  15. ADVANCED, LOW/ZERO EMISSION BOILER DESIGN AND OPERATION

    SciTech Connect (OSTI)

    Ovidiu Marin; Fabienne Chatel-Pelage

    2003-04-01T23:59:59.000Z

    This document reviews the work performed during the quarter January-March 2003. The main objectives of the project are: To demonstrate the feasibility of the full-oxy combustion with flue gas recirculation on Babcock & Wilcox's 1.5MW pilot boiler, To measure its performances in terms of emissions and boiler efficiency while selecting the right oxygen injection strategies, To perform an economical feasibility study, comparing this solution with alternate technologies, and To design a new generation, full oxy-fired boiler. The main objective of this quarter was to initiate the project, primarily the experimental tasks. The contractor and its subcontractors have defined a working plan, and the first tasks have been started. Task 1 (Site Preparation) is now in progress, defining the modifications to be implemented to the boiler and oxygen delivery system. The changes are required in order to overcome some current limitations of the existing system. As part of a previous project carried out in 2002, several changes have already been made on the pilot boiler, including the enrichment of the secondary and tertiary air with oxygen or the replacement of these streams with oxygen-enriched recycled flue gas. A notable modification for the current project involves the replacement of the primary air with oxygen-enriched flue gas. Consequently, the current oxygen supply and flue gas recycle system is being modified to meet this new requirement. Task 2 (Combustion and Emissions Performance Optimization) has been initiated with a preliminary selection of four series of tests to be performed. So far, the project schedule is on-track: site preparation (Task 1) should be completed by August 1st, 2003 and the tests (Task 2) are planned for September-October 2003. The Techno-Economic Study (Task 3) will be initiated in the following quarter.

  16. Gasoline Ultra Fuel Efficient Vehicle

    Broader source: Energy.gov (indexed) [DOE]

    Principal Investigator 13MY11 2011 DOE Vehicle Technologies Review Gasoline Ultra Fuel Efficient Vehicle ACE064 "This presentation does not contain any proprietary,...

  17. Superheater Corrosion In Biomass Boilers: Today's Science and Technology

    SciTech Connect (OSTI)

    Sharp, William (Sandy) [SharpConsultant

    2011-12-01T23:59:59.000Z

    This report broadens a previous review of published literature on corrosion of recovery boiler superheater tube materials to consider the performance of candidate materials at temperatures near the deposit melting temperature in advanced boilers firing coal, wood-based fuels, and waste materials as well as in gas turbine environments. Discussions of corrosion mechanisms focus on the reactions in fly ash deposits and combustion gases that can give corrosive materials access to the surface of a superheater tube. Setting the steam temperature of a biomass boiler is a compromise between wasting fuel energy, risking pluggage that will shut the unit down, and creating conditions that will cause rapid corrosion on the superheater tubes and replacement expenses. The most important corrosive species in biomass superheater corrosion are chlorine compounds and the most corrosion resistant alloys are typically FeCrNi alloys containing 20-28% Cr. Although most of these materials contain many other additional additions, there is no coherent theory of the alloying required to resist the combination of high temperature salt deposits and flue gases that are found in biomass boiler superheaters that may cause degradation of superheater tubes. After depletion of chromium by chromate formation or chromic acid volatilization exceeds a critical amount, the protective scale gives way to a thick layer of Fe{sub 2}O{sub 3} over an unprotective (FeCrNi){sub 3}O{sub 4} spinel. This oxide is not protective and can be penetrated by chlorine species that cause further acceleration of the corrosion rate by a mechanism called active oxidation. Active oxidation, cited as the cause of most biomass superheater corrosion under chloride ash deposits, does not occur in the absence of these alkali salts when the chloride is present as HCl gas. Although a deposit is more corrosive at temperatures where it is molten than at temperatures where it is frozen, increasing superheater tube temperatures through the measured first melting point of fly ash deposits does not necessarily produce a step increase in corrosion rate. Corrosion rate typically accelerates at temperatures below the first melting temperature and mixed deposits may have a broad melting temperature range. Although the environment at a superheater tube surface is initially that of the ash deposits, this chemistry typically changes as the deposits mature. The corrosion rate is controlled by the environment and temperature at the tube surface, which can only be measured indirectly. Some results are counter-intuitive. Two boiler manufacturers and a consortium have developed models to predict fouling and corrosion in biomass boilers in order to specify tube materials for particular operating conditions. It would be very useful to compare the predictions of these models regarding corrosion rates and recommended alloys in the boiler environments where field tests will be performed in the current program. Manufacturers of biomass boilers have concluded that it is more cost-effective to restrict steam temperatures, to co-fire biofuels with high sulfur fuels and/or to use fuel additives rather than try to increase fuel efficiency by operating with superheater tube temperatures above melting temperature of fly ash deposits. Similar strategies have been developed for coal fired and waste-fired boilers. Additives are primarily used to replace alkali metal chloride deposits with higher melting temperature and less corrosive alkali metal sulfate or alkali aluminum silicate deposits. Design modifications that have been shown to control superheater corrosion include adding a radiant pass (empty chamber) between the furnace and the superheater, installing cool tubes immediately upstream of the superheater to trap high chloride deposits, designing superheater banks for quick replacement, using an external superheater that burns a less corrosive biomass fuel, moving circulating fluidized bed (CFB) superheaters from the convective pass into the hot recirculated fluidizing medium and adding an insulating layer to superh

  18. Evaluation of Packed Columns in Supercritical Extraction Processes

    E-Print Network [OSTI]

    Rathkamp, P. J.; Fair, J. R.; Humphrey, J. L.

    used was 1/4 inch Raschig rings with a surface area of 220 ft 2 /ft 3 . The supercritical systems studied were carbon dioxide/ethanol/water and carbon dioxide/isopropanol/water at 102 atmos pheres and 35 0 C and 102 atmospheres and 40 0 C... to the differences in performance of the two systems. Carbon dioxide is one of the most commonly used supercritical solvents because it is non-toxic and non-flammable. Carbon dioxide is inexpensive rela tive to other solvents and has a conveniently low critical...

  19. Ultra Violet Waterworks (UVW)

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite JC-118794 PREPRINT A Comparison of97l5Ultra Violet

  20. Steam driven centrifugal pump for low cost boiler feed service

    SciTech Connect (OSTI)

    Not Available

    1982-11-01T23:59:59.000Z

    This article describes a steam driven centrifugal pump for boiler feed-water and other high pressure water applications, which was awarded Top Honors in the special pumps category of the 1982 Chemical processing Vaaler competition, because the simple design with turbine, pump and controls combined in an integral unit provides high operating efficiency and reliable performance with minimal maintenance. Single source responsibility for all components when the pump may have to be serviced is another advantage. These features meet the requirements for boiler feed pumps that are critical to maintaining a consistent steam supply in a process plant where downtime can be extremely expensive. The annual cost to operate the pump for 8000 hours is about $100,000, if electricity costs 5 cents/kwh. These pumps can be run for about $30,000 on steam, if natural gas costs $4.00/mcf. Cost savings are $70,000 annually.

  1. Thermal Behavior of Floor Tubes in a Kraft Recovery Boiler

    SciTech Connect (OSTI)

    Barker, R.E.; Choudhury, K.A.; Gorog, J.P.; Hall, L.M.; Keiser, J.R.; Sarma, G.B.

    1999-09-12T23:59:59.000Z

    The temperatures of floor tubes in a slope-floored black liquor recovery boiler were measured using an array of thermocouples located on the tube crowns. It was found that sudden, short duration temperature increases occurred with a frequency that increased with distance from the spout wall. To determine if the temperature pulses were associated with material falling from the convective section of the boiler, the pattern of sootblower operation was recorded and compared with the pattern of temperature pulses. During the period from September, 1998, through February, 1999, it was found that more than 2/3 of the temperature pulses occurred during the time when one of the fast eight sootblowers, which are directed at the back of the screen tubes and the leading edge of the first superheater bank, was operating.

  2. Heat Recovery Considerations for Process Heaters and Boilers

    E-Print Network [OSTI]

    Kumar, A.

    ) Chemicals (223) 0.81xlO 15 81xl0 6 3) Pulp & Paper (8) 1.30xlO 15 2.2xI0 6 4) ~leta1s (32) O.07xlO 15 6.4x10 6 O.28xl0 15 308 291xl0 6 2.46xlO 15 Sec =Specific energy consumption * Calculated as %reduction in SEC - value 10TOR "OUSI.. SEi...Heat Recovery Considerations for Process Heaters and Boilers Ash Kumar, Pennzoil Company, Shreveport, Louisiana The largest single area for industrial energy conservation is in the improvement of combustion efficiencies for heaters and boilers...

  3. Boiler tube failures in municipal waste-to-energy plants

    SciTech Connect (OSTI)

    Krause, H.H.; Wright, I.G. [Battelle, Columbus, OH (United States)

    1996-01-01T23:59:59.000Z

    Waste-to-energy plants experienced increased boiler tube failures when the design changed from waste-heat boilers to radiant furnace waterwalls using superheat. Fireside attack by chlorine and sulfur compounds in refuse combustion products caused many forced outages in early European plants operating at high steam temperatures and pressures. Despite conservative steam conditions in the first US plants, failures occurred. As steam temperatures increased, corrosion problems multiplied. The problems have been alleviated by covering the waterwalls with either refractory or weld overlays of nickel-based alloys and using high nickel-chromium alloys for superheater tubes. Changes in furnace design to provide uniform combustion and avoid reducing conditions in the waterwall zone and to lower the gas temperature in the superheater also have helped minimize corrosion.

  4. Wood/coal cofiring in industrial stoker boilers

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.; Elder, W.W.; Freeman, M.C.

    1999-07-01T23:59:59.000Z

    Realizing that a significant reduction in the global emissions of fossil carbon dioxide may require the installation of a wide variety of control technologies, options for large and small boilers are receiving attention. With over 1,500 coal-fired stoker boilers in the US, biomass co-firing is of interest, which would also open markets for waste wood which is presently landfilled at significant costs ranging from $20--200/ton. While much cofiring occurs inside the fence, where industrial firms burn wastes in their site boilers, other opportunities exist. Emphasis has been placed on stoker boilers in the northeastern US, where abundant supplies of urban wood waste are generally known to exist. Broken pallets form a significant fraction of this waste. In 1997, the cofiring of a volumetric mixture of 30% ground broken pallet material and 70% coal was demonstrated successfully at the traveling-grate stoker boilerplant of the Pittsburgh Brewing Company. Fourteen test periods, with various wood/coal mixtures blended on site, and two extended test periods, using wood/coal mixtures blended at the coal terminal and transported by truck to the brewery, were conducted. The 30% wood/70% coal fuel was conveyed through the feed system without difficulty, and combusted properly on the grate while meeting opacity requirements with low SO{sub 2} and NO{sub x} emissions. Efforts are underway to commercialize a wood/coal blend at the brewery, to identify specific urban wood supplies in the Pittsburgh region and to conduct a demonstration at a spreader stoker.

  5. Single-loop controllers bring boilers in line

    SciTech Connect (OSTI)

    Harrelson, D.; Piechota, B.

    1995-08-01T23:59:59.000Z

    The boiler process seems simple. Some type of fuel is burned in the presence of air, forming heat and combustion gases. The heat is then absorbed by the boiler drum and transferred to the water inside. The heated water changes to steam and is exhausted, which spins an electrical turbine that produces electricity, and exhausts lower pressure steam for condensing in the process. Although this process seems simple, anything could go wrong at any time. The flame could go out, the fuel could run low, or the drum could get dirty. Let`s take a look at how to avoid these problems. The first step is to take accurate measurements. Typically, these measurements include flow, pressure, conductivity, temperature, stack analysis, and a level or two. Ambient conditions can affect performance of each measuring device, so be sure to consider the hot, drafty conditions of boiler houses when selecting/installing devices. The second step is to bring the measurement signals back to the control room. Use two-wire, loop-powered devices to transmit all signals except the stack analysis signals. Two-wire, loop-powered technology increases reliability, lowers installation costs, and eliminates ground loops. Signal conditioning takes place at the microcontroller input points. Signal conditioning is done to provide a linear, overall loop response to the controller. It also simplified measurement. Examining four types of input signal characterization will help explain the signal conditioning process. The first signal is a zero-based pressure signal with a linear characteristic. The second is a temperature measurement made by a thermocouple whose output is nonlinear. Next is a flow measurement made with a conventional d/p cell and orifice plate. It needs a square root characterization. Last is a combustion air flow measurement from the pressure drop across part of the boiler or preheater. This flow measurement is quite tricky because of a large deviation from the simple square root relationship.

  6. Condensing economizers for small coal-fired boilers and furnaces

    SciTech Connect (OSTI)

    Butcher, T.A.; Litzke, W.

    1994-01-01T23:59:59.000Z

    Condensing economizers increase the thermal efficiency of boilers by recovering sensible and latent heat from exhaust gas. These economizers are currently being used commercially for this purpose in a wide range of applications. Performance is dependent upon application-specific factors affecting the utility of recovered heat. With the addition of a condensing economizer boiler efficiency improvements up to 10% are possible. Condensing economizers can also capture flue gas particulates. In this work, the potential use of condensing economizers for both efficiency improvement and control of particulate emissions from small, coal water slurry-fired boilers was evaluated. Analysis was done to predict heat transfer and particulate capture by mechanisms including: inertial impaction, interception, diffusion, thermophoretic forces, and condensation growth. Shell-and-tube geometries were considered with flue gas on the outside of Teflon-covered tubes. Experimental studies were done with both air- and water-cooled economizers refit to a small boiler. Two experimental arrangements were used including oil-firing with injection of flyash upstream of the economizer and direct coal water slurry firing. Firing rates ranged from 27 to 82 kW (92,000 to 280,000 Btu/hr). Inertial impaction was found to be the most important particulate capture mechanism and removal efficiencies to 95% were achieved. With the addition of water sprays directly on the first row of tubes, removal efficiencies increased to 98%. Use of these sprays adversely affects heat recovery. Primary benefits of the sprays are seen to be the addition of small impaction sites and future design improvements are suggested in which such small impactors are permanently added to the highest velocity regions of the economizer. Predicted effects of these added impactors on particulate removal and pressure drop are presented.

  7. Waste heat boiler optimization by entropy minimization principle

    SciTech Connect (OSTI)

    Reddy, B.V.; Murali, J.; Satheesh, V.S. [Vellore Engineering Coll. (India). Mechanical Engineering Dept.; Nag, P.K. [Indian Inst. of Tech., Kharagpur (India). Mechanical Engineering Dept.

    1996-12-31T23:59:59.000Z

    A second law analysis has been undertaken for a waste heat boiler having an economizer, evaporator and superheater. Following the principle of minimization of entropy generation, a general equation for entropy generation number is derived, which incorporates all the operating variables. By differentiating the entropy generation number equation with respect to the operating parameters, various optimization parameters can be obtained. Few illustrations have been made to see the effect of various parameters on entropy generation number.

  8. Covered Product Category: Commercial Boilers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top FiveDepartmentfor EngineeringDepartment ofBoilers Covered Product Category:

  9. Corrosion of various engineering alloys in supercritical carbon dioxide

    E-Print Network [OSTI]

    Gibbs, Jonathan Paul

    2010-01-01T23:59:59.000Z

    The corrosion resistance of ten engineering alloys were tested in a supercritical carbon dioxide (S-CO 2) environment for up to 3000 hours at 610°C and 20MPa. The purpose of this work was to evaluate each alloy as a potential ...

  10. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide

    Broader source: Energy.gov [DOE]

    Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250şC, and to develop chemical modeling of CO2-reservior rock interactions.

  11. Method for nucleic acid isolation using supercritical fluids

    DOE Patents [OSTI]

    Nivens, David E. (11912 Kingsgate Rd., Knoxville, TN 37911); Applegate, Bruce M. (3700 Sutherland Ave. #Q2, Knoxville, TN 37911)

    1999-01-01T23:59:59.000Z

    A method for detecting the presence of a microorganism in an environmental sample involves contacting the sample with a supercritical fluid to isolate nucleic acid from the microorganism, then detecting the presence of a particular sequence within the isolated nucleic acid. The nucleic acid may optionally be subjected to further purification.

  12. CRYOGENIC FLUID JETS AND MIXING LAYERS IN TRANSCRITICAL AND SUPERCRITICAL

    E-Print Network [OSTI]

    Yang, Vigor

    for high-pressure combustion devices (such as liquid-propellant rockets and gas-turbine and diesel engines the strongest influ- ence on the underlying processes. Keywords: supercritical combustion, liquid propellant in this field was motivated by the development of advanced cryogenic- propellant rocket engines in the past

  13. Field-portable supercritical CO.sub.2 extractor

    DOE Patents [OSTI]

    Wright, Bob W. (Richland, WA); Zemanian, Thomas S. (Richland, WA); Robins, William H. (Richland, WA); Woodcock, Leslie J. (Benton City, WA)

    1997-01-01T23:59:59.000Z

    The present invention is an apparatus for extracting organic compounds from solid materials. A generator vessel has a removable closure for receiving a solid or liquid solvent which is heated with a resistive heating element to a gaseous or supercritical phase. The removable closure is unencumbered because the side wall is penetrated with an outlet for the gaseous or supercritical solvent. The generator vessel further has a pressure transducer that provides an electronic signal related to pressure of the gaseous or supercritical solvent. The apparatus of the present invention further includes at least one extraction cell having a top and a bottom and a wall extending therebetween, wherein the bottom is sealably penetrated by an inlet for gaseous or supercritical solvent received through a manifold connected to the outlet, the top having an easy-open removable closure cap, and the wall having an outlet port. Finally, a permeable sample cartridge is included for holding the solid materials and to provide radial-flow of the extraction fluid, which is placed within the extraction cell.

  14. Field-portable supercritical CO{sub 2} extractor

    DOE Patents [OSTI]

    Wright, B.W.; Zemanian, T.S.; Robins, W.H.; Woodcock, L.J.

    1997-06-10T23:59:59.000Z

    The present invention is an apparatus for extracting organic compounds from solid materials. A generator vessel has a removable closure for receiving a solid or liquid solvent which is heated with a resistive heating element to a gaseous or supercritical phase. The removable closure is unencumbered because the side wall is penetrated with an outlet for the gaseous or supercritical solvent. The generator vessel further has a pressure transducer that provides an electronic signal related to pressure of the gaseous or supercritical solvent. The apparatus of the present invention further includes at least one extraction cell having a top and a bottom and a wall extending there between, wherein the bottom is sealably penetrated by an inlet for gaseous or supercritical solvent received through a manifold connected to the outlet, the top having an easy-open removable closure cap, and the wall having an outlet port. Finally, a permeable sample cartridge is included for holding the solid materials and to provide radial-flow of the extraction fluid, which is placed within the extraction cell. 10 figs.

  15. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.

    1993-03-30T23:59:59.000Z

    A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

  16. Mercury control challenge for industrial boiler MACT affected facilities

    SciTech Connect (OSTI)

    NONE

    2009-09-15T23:59:59.000Z

    An industrial coal-fired boiler facility conducted a test program to evaluate the effectiveness of sorbent injection on mercury removal ahead of a fabric filter with an inlet flue gas temperature of 375{sup o}F. The results of the sorbent injection testing are essentially inconclusive relative to providing the facility with enough data upon which to base the design and implementation of permanent sorbent injection system(s). The mercury removal performance of the sorbents was significantly less than expected. The data suggests that 50 percent mercury removal across a baghouse with flue gas temperatures at or above 375{sup o}F and containing moderate levels of SO{sub 3} may be very difficult to achieve with activated carbon sorbent injection alone. The challenge many coal-fired industrial facilities may face is the implementation of additional measures beyond sorbent injection to achieve high levels of mercury removal that will likely be required by the upcoming new Industrial Boiler MACT rule. To counter the negative effects of high flue gas temperature on mercury removal with sorbents, it may be necessary to retrofit additional boiler heat transfer surface or spray cooling of the flue gas upstream of the baghouse. Furthermore, to counter the negative effect of moderate or high SO{sub 3} levels in the flue gas on mercury removal, it may be necessary to also inject sorbents, such as trona or hydrated lime, to reduce the SO{sub 3} concentrations in the flue gas. 2 refs., 1 tab.

  17. The environmental impact of orimulsion combustion in large utility boilers

    SciTech Connect (OSTI)

    Allen, J.W.; Beal, P.R. [International Combustion Ltd., Derby (United Kingdom)

    1997-07-01T23:59:59.000Z

    There is considerable worldwide interest in the practical use of Orimulsion as a replacement fuel in both oil and coal fired utility boilers. Practical experience of such applications has been gained in Canada, UK, Japan, Europe and USA. Fundamental work has demonstrated the different combustion characteristics of Orimulsion which has been termed the {open_quotes}fourth{close_quotes} fossil fuel to the fossil fuels normally used for power generation and how, in certain circumstances, these can be used to advantage in the application of Orimulsion in utility boiler combustion systems. Orimulsion is an emulsify ed fuel prepared from naturally occurring bitumen deposits located in the Orinoco Basin in Venezuela and comprises approximately 70% bitumen and 30% water. Compared to the heavier fuel oils the sulphur content of Orimulsion is medium to high, the ash content is high with high levels of Vanadium and Nickel. The ash content is enhanced by the addition of Magnesium compounds, to the commercial fuel, to mitigate against the potential in boiler corrosion effects arising form the Va, Na and S content in the fuel.

  18. Design of an expert system to aid in the selection of a wood fired boiler system.

    E-Print Network [OSTI]

    Morris, Melissa L.

    2008-01-01T23:59:59.000Z

    ??Currently most industrial and institutional facilities rely on fossil fuels to power their boiler systems. As the quantity of these non-renewable resources is depleted, and… (more)

  19. A methodology for in-situ calibration of steam boiler instrumentation.

    E-Print Network [OSTI]

    Wei, Guanghua

    2012-01-01T23:59:59.000Z

    ??This thesis presents a broadly useful diagnostic methodology to engineers and plant managers for finding the in-situ operating characteristics of power plant boilers when metered… (more)

  20. Second law analysis of a natural gas-fired steam boiler and cogeneration plant.

    E-Print Network [OSTI]

    Conklin, Eric D

    2010-01-01T23:59:59.000Z

    ??A second law thermodynamic analysis of a natural gas-fired steam boiler and cogeneration plant at Rice University was conducted. The analysis included many components of… (more)

  1. Planning and setup for the implementation of coal and wood co-fired boilers.

    E-Print Network [OSTI]

    Gump, Christopher D.

    2007-01-01T23:59:59.000Z

    ??Coal and wood co-fired boiler technology has been significantly advancing in the past years, but many of their capabilities remain unknown to much of the… (more)

  2. Distribution of bed material in a Horizontal Circulating Fluidised Bed boiler.

    E-Print Network [OSTI]

    Ekvall, Thomas

    2011-01-01T23:59:59.000Z

    ??A conventional circulating fluidised bed (CFB) boiler has a limitation due to the height of the furnace, when implemented in smaller industrial facilities. The design… (more)

  3. Continuous Measurement of Carbon Monoxide Improves Combustion Efficiency of CO Boilers

    E-Print Network [OSTI]

    Gilmour, W. A.; Pregler, D. N.; Branham, R. L.; Prichard, J. J.

    1981-01-01T23:59:59.000Z

    The paper describes the application of in-situ flue gas CO measurement in the operation of CO Boilers and details the steps needed to optimize combustion efficiency....

  4. E-Print Network 3.0 - advanced coal-fired boilers Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CHLORINE LINK IN COMMERCIAL SCALE SYSTEM FLUE GASES? Summary: that Battelle measured dioxins in coal fired utility boiler stack emissions in the United States and by ETSU... in...

  5. Building America Case Study: Advanced Boiler Load Monitoring Controllers, Chicago, Illinois (Fact Sheet)

    SciTech Connect (OSTI)

    PARR

    2014-09-01T23:59:59.000Z

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and in some cases return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential. PARR installed and monitored the performance of one type of ALM controller, the M2G from Greffen Systems, at multifamily sites in the city of Chicago and its suburb Cary, IL, both with existing OTR control. Results show that energy savings depend on the degree to which boilers are over-sized for their load, represented by cycling rates. Also savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, over-sized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less over-sized boilers at another site showed muted savings.

  6. Consider Installing Turbulators on Two- and Three-Pass Firetube Boilers

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on installing turbulators on firetube boilers provides how-to advice for improving the system using low-cost, proven practices and technologies.

  7. Demonstration of coal reburning for cyclone boiler NO{sub x} control. Appendix, Book 1

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    Based on the industry need for a pilot-scale cyclone boiler simulator, Babcock Wilcox (B&W) designed, fabricated, and installed such a facility at its Alliance Research Center (ARC) in 1985. The project involved conversion of an existing pulverized coal-fired facility to be cyclone-firing capable. Additionally, convective section tube banks were installed in the upper furnace in order to simulate a typical boiler convection pass. The small boiler simulator (SBS) is designed to simulate most fireside aspects of full-size utility boilers such as combustion and flue gas emissions characteristics, fireside deposition, etc. Prior to the design of the pilot-scale cyclone boiler simulator, the various cyclone boiler types were reviewed in order to identify the inherent cyclone boiler design characteristics which are applicable to the majority of these boilers. The cyclone boiler characteristics that were reviewed include NO{sub x} emissions, furnace exit gas temperature (FEGT) carbon loss, and total furnace residence time. Previous pilot-scale cyclone-fired furnace experience identified the following concerns: (1) Operability of a small cyclone furnace (e.g., continuous slag tapping capability). (2) The optimum cyclone(s) configuration for the pilot-scale unit. (3) Compatibility of NO{sub x} levels, carbon burnout, cyclone ash carryover to the convection pass, cyclone temperature, furnace residence time, and FEGT.

  8. Clean Firetube Boiler Waterside Heat Transfer Surfaces, Energy Tips: STEAM, Steam Tip Sheet #7 (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-04-01T23:59:59.000Z

    A steam energy tip sheet for the Advanced Manufacturing Office (AMO). The prevention of scale formation in firetube boilers can result in substantial energy savings. Scale deposits occur when calcium, magnesium, and silica, commonly found in most water supplies, react to form a continuous layer of material on the waterside of the boiler heat exchange tubes. Scale creates a problem because it typically possesses a thermal conductivity, an order of magnitude less than the corresponding value for bare steel. Even thin layers of scale serve as an effective insulator and retard heat transfer. The result is overheating of boiler tube metal, tube failures, and loss of energy efficiency. Fuel consumption may increase by up to 5% in firetube boilers because of scale. The boilers steam production may be reduced if the firing rate cannot be increased to compensate for the decrease in combustion efficiency. Energy losses as a function of scale thickness and composition are given. Any scale in a boiler is undesirable. The best way to deal with scale is not to let it form in the first place. Prevent scale formation by: (1) Pretreating of boiler makeup water (using water softeners, demineralizers, and reverse osmosis to remove scale-forming minerals); (2) Injecting chemicals into the boiler feedwater; and (3) Adopting proper boiler blowdown practices.

  9. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30T23:59:59.000Z

    This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

  10. Supercritical Water Reactor Cycle for Medium Power Applications

    SciTech Connect (OSTI)

    BD Middleton; J Buongiorno

    2007-04-25T23:59:59.000Z

    Scoping studies for a power conversion system based on a direct-cycle supercritical water reactor have been conducted. The electric power range of interest is 5-30 MWe with a design point of 20 MWe. The overall design objective is to develop a system that has minimized physical size and performs satisfactorily over a broad range of operating conditions. The design constraints are as follows: Net cycle thermal efficiency {ge}20%; Steam turbine outlet quality {ge}90%; and Pumping power {le}2500 kW (at nominal conditions). Three basic cycle configurations were analyzed. Listed in order of increased plant complexity, they are: (1) Simple supercritical Rankine cycle; (2) All-supercritical Brayton cycle; and (3) Supercritical Rankine cycle with feedwater preheating. The sensitivity of these three configurations to various parameters, such as reactor exit temperature, reactor pressure, condenser pressure, etc., was assessed. The Thermoflex software package was used for this task. The results are as follows: (a) The simple supercritical Rankine cycle offers the greatest hardware simplification, but its high reactor temperature rise and reactor outlet temperature may pose serious problems from the viewpoint of thermal stresses, stability and materials in the core. (b) The all-supercritical Brayton cycle is not a contender, due to its poor thermal efficiency. (c) The supercritical Rankine cycle with feedwater preheating affords acceptable thermal efficiency with lower reactor temperature rise and outlet temperature. (d) The use of a moisture separator improves the performance of the supercritical Rankine cycle with feedwater preheating and allows for a further reduction of the reactor outlet temperature, thus it was selected for the next step. Preliminary engineering design of the supercritical Rankine cycle with feedwater preheating and moisture separation was performed. All major components including the turbine, feedwater heater, feedwater pump, condenser, condenser pump and pipes were modeled with realistic assumptions using the PEACE module of Thermoflex. A three-dimensional layout of the plant was also generated with the SolidEdge software. The results of the engineering design are as follows: (i) The cycle achieves a net thermal efficiency of 24.13% with 350/460 C reactor inlet/outlet temperatures, {approx}250 bar reactor pressure and 0.75 bar condenser pressure. The steam quality at the turbine outlet is 90% and the total electric consumption of the pumps is about 2500 kWe at nominal conditions. (ii) The overall size of the plant is attractively compact and can be further reduced if a printed-circuit-heat-exchanger (vs shell-and-tube) design is used for the feedwater heater, which is currently the largest component by far. Finally, an analysis of the plant performance at off-nominal conditions has revealed good robustness of the design in handling large changes of thermal power and seawater temperature.

  11. Selective chelation and extraction of lanthanides and actinides with supercritical fluids

    SciTech Connect (OSTI)

    Brauer, R.D.; Carleson, T.E.; Harrington, J.D.; Jean, F.; Jiang, H.; Lin, Y.; Wai, C.M.

    1994-01-01T23:59:59.000Z

    This report is made up of three independent papers: (1) Supercritical Fluid Extraction of Thorium and Uranium with Fluorinated Beta-Diketones and Tributyl Phosphate, (2) Supercritical Fluid Extraction of Lanthanides with Beta-Diketones and Mixed Ligands, and (3) A Group Contribution Method for Predicting the Solubility of Solid Organic Compounds in Supercritical Carbon Dioxide. Experimental data are presented demonstrating the successful extraction of thorium and uranium using fluorinated beta-diketones to form stable complexes that are extracted with supercritical carbon dioxide. The conditions for extracting the lanthanide ions from liquid and solid materials using supercritical carbon dioxide are presented. In addition, the Peng-Robison equation of state and thermodynamic equilibrium are used to predict the solubilities of organic solids in supercritical carbon dioxide from the sublimation pressure, critical properties, and a centric factor of the solid of interest.

  12. SRC burn test in 700-hp oil-designed boiler. Annex Volume B. DOE-Pittsburgh Energy Technology Center report. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1983-09-01T23:59:59.000Z

    Solvent Refined Coal (SRC) combustion tests were conducted at the U.S. Department of Energy's Pittsburgh Energy Technology Center. Combustion and flue-gas treatment of three different physical forms of SRC, as well as a No. 6 fuel oil, were evaluated. The three SRC fuels were (1) pulverized SRC Fuel; (2) SRC Residual Fuel Oil; and (3) SRC/Water Slurry. The SRC Residual Fuel Oil was a solution of SRC Fuel dissolved in heated process solvent. Approximately 500 tons of pulverized SRC Fuel and 30,000 gallons of SRC Residual Fuel Oil were combusted in a 700 hp (30 x 130 x 10/sup 6/ Btu/hr fuel input) oil-designed watertube package boiler. Sixty four-hour ASME combustion tests with three different SRC fuels were successfully concluded. The principal parameters evaluated were excess air levels and combustion air preheat temperature levels. Extensive data were collected on flue-gas levels of O/sub 2/, CO/sub 2/, CO, unburned hydrocarbons, SO/sub x/, NO/sub x/, uncontrolled particulates, uncontrolled opacity and carbon content of the flue-gas particulates. Boiler and combustion efficiencies were measured. The particulates were characterized via mass loadings, impactors, in-situ resistivity measurements, ultra-fine sampling, optical large particle sampling, five-stage cyclone sampling and chemical analysis of various cut sizes. A three-field pilot electrostatic precipitator (ESP) containing over 1000 square feet of plate collection area, a reverse air fabric filter pilot dust collector and a commercial pulse-jet fabric filter dust collector were operated at high collection efficiency. The results will be valuable in making recommendations for future tests and will provide a basis for conversion of industrial oil-fired boilers to SRC fuels. 11 references, 20 figures, 29 tables.

  13. A New Scheme on Robust Observer Based Control Design for Nonlinear Interconnected Systems with Application to an Industrial Utility Boiler

    E-Print Network [OSTI]

    Marquez, Horacio J.

    with Application to an Industrial Utility Boiler Adarsha Swarnakar, Horacio Jose Marquez and Tongwen Chen Abstract. The controller design is evaluated on a natural circulation drum boiler, where the nonlinear model describes

  14. New 90,000 PPH Coal Fired Boiler Plant at Liggett & Myers Tobacco Company, Durham North Carolina

    E-Print Network [OSTI]

    Kaskey, G. T.

    1984-01-01T23:59:59.000Z

    Liggett & Myers Tobacco Company in Durham, North Carolina is installing a future cogeneration, coal fired boiler system designed and built by Energy Systems (ESI) of Chattanooga, Tennessee. The complete boiler plant is comprised of a 90,000 pph Dorr...

  15. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

    2003-12-31T23:59:59.000Z

    This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

  16. Method and apparatus for waste destruction using supercritical water oxidation

    DOE Patents [OSTI]

    Haroldsen, Brent Lowell (1251 Sprague St., Manteca, CA 95336); Wu, Benjamin Chiau-pin (2270 Goldenrod La., San Ramon, CA 94583)

    2000-01-01T23:59:59.000Z

    The invention relates to an improved apparatus and method for initiating and sustaining an oxidation reaction. A hazardous waste, is introduced into a reaction zone within a pressurized containment vessel. An oxidizer, preferably hydrogen peroxide, is mixed with a carrier fluid, preferably water, and the mixture is heated until the fluid achieves supercritical conditions of temperature and pressure. The heating means comprise cartridge heaters placed in closed-end tubes extending into the center region of the pressure vessel along the reactor longitudinal axis. A cooling jacket surrounds the pressure vessel to remove excess heat at the walls. Heating and cooling the fluid mixture in this manner creates a limited reaction zone near the center of the pressure vessel by establishing a steady state density gradient in the fluid mixture which gradually forces the fluid to circulate internally. This circulation allows the fluid mixture to oscillate between supercritical and subcritical states as it is heated and cooled.

  17. Why the Accuracy of Analytical Instrumentation Affects Boiler Combustion Efficiency

    E-Print Network [OSTI]

    McFadden, R. W.

    1984-01-01T23:59:59.000Z

    carbon monoxide level. A testing firm can provide this instrumentation or it can be purchased. The size and type of combustor to be tested will usually dictate the buy or contract decision. Small to medium boilers will usually be the ones involved... fan's damper linkage, that is adjusted by the operator on a shift-by-shift basis, to a dedicated microcomputer that looks at the load, oxygen, carbon monoxide/ carbon dioxide and even the flue gas opacity. The selection of the type of trim...

  18. Effects of copper deposition on boiler waterside surfaces

    SciTech Connect (OSTI)

    Wangerin, M.C.; Rondum, K.D. [Ashland Chemical Co., Boonton, NJ (United States)

    1995-12-01T23:59:59.000Z

    The relative importance of metal oxide corrosion products in waterside deposits, as opposed to traditional scale-forming constituents, is discussed, and the sources of copper and copper oxide boiler deposits are reviewed. Also reviewed are explanations of some of the problems associated with the presence of deposits and especially, copper-containing deposits. These include those due to a reduction in heat transfer and tube metal overheating, as well as various corrosion mechanisms. Case histories, which illustrate certain deleterious mechanisms due to the presence of such deposition, are also presented.

  19. Why Do Kraft Recovery Boiler Composite Floor Tubes Crack?

    SciTech Connect (OSTI)

    Keiser, J.R.

    2001-10-22T23:59:59.000Z

    Cracks were first reported in 1992 in co-extruded 304L stainless steel/SA210 Gd Al carbon steel floor tubes of North American black liquor recovery boilers. Since then, a considerable amount of information has been collected on the tube environment, crack characteristics, the stress state of the tubes, and the crack initiation and propagation mechanisms. These studies have identified both operating procedures that apparently can greatly lessen the likelihood of crack formation in the stainless steel layer and alternate materials that appear to be much more resistant to cracking than is 304L stainless.

  20. Synergistic air port corrosion in kraft recovery boilers

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2001-08-01T23:59:59.000Z

    Localized hot corrosion can occur on the cold-side of air-ports in Kraft recovery boilers. Depending on the basicity of the molten salt, either acidic or basic fluxing takes place, with a solubility minima at the transition between the two reactions. For stainless steel, if the basicity of the fused salt is between the iron and chromium oxide solubility minima, then a synergistic effect can occur that leads to rapid corrosion. The products of one reaction are the reactants of the other, which eliminates the need for rate-controlling diffusion. This effect can explain why stainless steel is attacked more readily than carbon steel.

  1. ADVANCED, LOW/ZERO EMISSION BOILER DESIGN AND OPERATION

    SciTech Connect (OSTI)

    Fabienne Chatel-Pelage

    2004-01-01T23:59:59.000Z

    This document reviews the work performed during the quarter October-December 2003. Task 1 (Site Preparation) had been completed in the previous reporting period. In this reporting period, one week of combustion parameters optimization has been performed in Task 2 (experimental test performance) of the project. Under full-oxy conditions (100% air replacement with O{sub 2}-enriched flue gas) in 1.5MW{sub th} coal-fired boiler, the following parameters have been varied and their impact on combustion characteristics measured: the recirculated flue gas flow rate has been varied from 80% to 95% of total flue gas flow, and the total oxygen flow rate into the primary air zone of the boiler has been set to levels ranging from 15% to 25% of the total oxygen consumption in the overall combustion. In current reporting period, significant progress has also been made in Task 3 (Techno-Economic Study) of the project: mass and energy balance calculations and cost assessment have been completed on plant capacity of 533MW{sub e} gross output while applying the methodology described in previous reporting periods. Air-fired PC Boiler and proposed Oxygen-fired PC Boiler have been assessed, both for retrofit application and new unit. The current work schedule is to review in more details the experimental data collected so far as well as the economics results obtained on the 533MWe cases, and to develop a work scope for the remainder of the project. Approximately one week of pilot testing is expected during the first quarter of 2004, including mercury emission measurement and heat transfer characterization. The project was on hold from mid-November through December 2003 due to non-availability of funds. Out of the {approx}$785k allocated DOE funds in this project, $497k have been spent to date ($480 reported so far), mainly in site preparation, test performance and economics assessment. In addition to DOE allocated funds, to date approximately $330k has been cost-shared by the participants, bringing the total project cost up to $827k ($810k reported so far) as on December 31st, 2003.

  2. Heat Recovery Considerations for Process Heaters and Boilers

    E-Print Network [OSTI]

    Kumar, A.

    and boilere. A number of methods can be I~loyed to recover heat. The moat COI8)D are by use of recuperative air preheat.'la, regenerative air preheate'la and economizers. Relative advantages and applicability of the three IDIthoda are discuased... be designed for any steam pres~ur~, including sup~rc.riti('al, "1. A wic1er range ur- dcs-ign::. LS . J. Hore eificient that a iire-tub~ unit. 4. They do not l~nd th~m5elves to cOul in~) o:;!lo:;!-? vated...

  3. Biomass Boiler to Heat Oregon School | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy UsageAUDITVehiclesTankless orA BRIEFApril 2015CommerceDepartment ofBioenergyBoiler to

  4. Building America Technology Solutions for New and Existing Homes: Boiler

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EEREDepartmentFebruary 4,BrentFeedbackPerformance of aBoilerControl

  5. Standby cooling system for a fluidized bed boiler

    DOE Patents [OSTI]

    Crispin, Larry G. (Akron, OH); Weitzel, Paul S. (Canal Fulton, OH)

    1990-01-01T23:59:59.000Z

    A system for protecting components including the heat exchangers of a fluidized bed boiler against thermal mismatch. The system includes an injection tank containing an emergency supply of heated and pressurized feedwater. A heater is associated with the injection tank to maintain the temperature of the feedwater in the tank at or about the same temperature as that of the feedwater in the heat exchangers. A pressurized gas is supplied to the injection tank to cause feedwater to flow from the injection tank to the heat exchangers during thermal mismatch.

  6. New Boilers, Big Savings for Minnesota County | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F S i DOETowardExecutiveRate principlesPierpont StudentsBoilers, Big

  7. Value of electrical heat boilers and heat pumps for wind power integration

    E-Print Network [OSTI]

    Value of electrical heat boilers and heat pumps for wind power integration Peter Meibom Juha of using electrical heat boilers and heat pumps as wind power integration measures relieving the link between the heat and power production in combined heat and power plants. Each of these measures has

  8. Analysis of Heating Systems and Scale of Natural Gas-Condensing Water Boilers in Northern Zones

    E-Print Network [OSTI]

    Wu, Y.; Wang, S.; Pan, S.; Shi, Y.

    2006-01-01T23:59:59.000Z

    In this paper, various heating systems and scale of the natural gas-condensing water boiler in northern zones are discussed, based on a technical-economic analysis of the heating systems of natural gas condensing water boilers in northern zones...

  9. Energy Conservation Through Use of Boiler Economizers (Economic and Practical Considerations)

    E-Print Network [OSTI]

    Roethe, L. A.

    1982-01-01T23:59:59.000Z

    One of the most productive means of obtaining conservation of energy lies in the improvement of the fuel-to-steam efficiency of high pressure steam generating boilers. Boilers operating at steam pressures of 100 psig and above are viable prospects...

  10. Conversion of hazardous materials using supercritical water oxidation

    DOE Patents [OSTI]

    Rofer, Cheryl K. (Los Alamos, NM); Buelow, Steven J. (Los Alamos, NM); Dyer, Richard B. (Los Alamos, NM); Wander, Joseph D. (Parker, FL)

    1992-01-01T23:59:59.000Z

    A process for destruction of hazardous materials in a medium of supercritical water without the addition of an oxidant material. The harzardous material is converted to simple compounds which are relatively benign or easily treatable to yield materials which can be discharged into the environment. Treatment agents may be added to the reactants in order to bind certain materials, such as chlorine, in the form of salts or to otherwise facilitate the destruction reactions.

  11. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGHBrayton Energy's supercritical carbon

  12. Supercritical Fluid Extraction of Plutonium and Americium from Soil

    SciTech Connect (OSTI)

    Fox, R.V.; Mincher, B.J.

    2002-05-23T23:59:59.000Z

    Supercritical fluid extraction (SFE) of plutonium and americium from soil was successfully demonstrated using supercritical fluid carbon dioxide solvent augmented with organophosphorus and beta-diketone complexants. Spiked Idaho soils were chemically and radiologically characterized, then extracted with supercritical fluid carbon dioxide at 2,900 psi and 65 C containing varying concentrations of tributyl phosphate (TBP) and thenoyltrifluoroacetone (TTA). A single 45 minute SFE with 2.7 mol% TBP and 3.2 mol% TTA provided as much as 88% {+-} 6.0 extraction of americium and 69% {+-} 5.0 extraction of plutonium. Use of 5.3 mol% TBP with 6.8 mol% of the more acidic beta-diketone hexafluoroacetylacetone (HFA) provided 95% {+-} 3.0 extraction of americium and 83% {+-} 5.0 extraction of plutonium in a single 45 minute SFE at 3,750 psi and 95 C. Sequential chemical extraction techniques were used to chemically characterize soil partitioning of plutonium and americium in pre-SFE soil samples. Sequential chemical extraction techniques demonstrated that spiked plutonium resides primarily (76.6%) in the sesquioxide fraction with minor amounts being absorbed by the oxidizable fraction (10.6%) and residual fractions (12.8%). Post-SFE soils subjected to sequential chemical extraction characterization demonstrated that 97% of the oxidizable, 78% of the sesquioxide and 80% of the residual plutonium could be removed using SFE. These preliminary results show that SFE may be an effective solvent extraction technique for removal of actinide contaminants from soil.

  13. Supercritical Fluid Extraction of Plutonium and Americium from Soil

    SciTech Connect (OSTI)

    Fox, Robert Vincent; Mincher, Bruce Jay

    2002-08-01T23:59:59.000Z

    Supercritical fluid extraction (SFE) of plutonium and americium from soil was successfully demonstrated using supercritical fluid carbon dioxide solvent augmented with organophosphorus and beta-diketone complexants. Spiked Idaho soils were chemically and radiologically characterized, then extracted with supercritical fluid carbon dioxide at 2,900 psi and 65°C containing varying concentrations of tributyl phosphate (TBP) and thenoyltrifluoroacetone (TTA). A single 45 minute SFE with 2.7 mol% TBP and 3.2 mol% TTA provided as much as 88% ± 6.0 extraction of americium and 69% ± 5.0 extraction of plutonium. Use of 5.3 mol% TBP with 6.8 mol% of the more acidic beta-diketone hexafluoroacetylacetone (HFA) provided 95% ± 3.0 extraction of americium and 83% ± 5.0 extraction of plutonium in a single 45 minute SFE at 3,750 psi and 95°C. Sequential chemical extraction techniques were used to chemically characterize soil partitioning of plutonium and americium in pre-SFE soil samples. Sequential chemical extraction techniques demonstrated that spiked plutonium resides primarily (76.6%) in the sesquioxide fraction with minor amounts being absorbed by the oxidizable fraction (10.6%) and residual fractions (12.8%). Post-SFE soils subjected to sequential chemical extraction characterization demonstrated that 97% of the oxidizable, 78% of the sesquioxide and 80% of the residual plutonium could be removed using SFE. These preliminary results show that SFE may be an effective solvent extraction technique for removal of actinide contaminants from soil.

  14. Integrated supercritical water gasification combined cycle (IGCC) systems for improved performance and reduced operating costs in existing plants

    SciTech Connect (OSTI)

    Tolman, R.; Parkinson, W.J.

    1999-07-01T23:59:59.000Z

    A revolutionary hydrothermal heat recovery steam generator (HRSG) is being developed to produce clean fuels for gas turbines from slurries and emulsions of opportunity fuels. Water can be above 80% by weight and solids below 20%, including coal fines, coal water fuels, biomass, composted municipal refuse, sewage sludge and bitumen/Orimulsion. The patented HRSG tubes use a commercial method of particle scrubbing to improve heat transfer and prevent corrosion and deposition on heat transfer surfaces. A continuous-flow pilot plant is planned to test the HRSG over a wide range of operating conditions, including the supercritical conditions of water, above 221 bar (3,205 psia) and 374 C (705 F). Bench scale data shows, that supercritical water gasification below 580 C (1,076 F) and low residence time without catalysts or an oxidizer can produce a char product that can contain carbon up to the amount of fixed carbon in the proximate analysis of the solids in the feed. This char can be burned with coal in an existing combustion system to provide the heat required for gasification. The new HRSG tubes can be retrofitted into existing power plant boilers for repowering of existing plants for improved performance and reduced costs. A special condensing turbine allows final low-temperature cleaning and maintains quality and combustibility of the fuel vapor for modern gas turbine in the new Vapor Transmission Cycle (VTC). Increased power output and efficiency can be provided for existing plants, while reducing fuel costs. A preliminary computer-based process simulation model has been prepared that includes material and energy balances that simulate commercial-scale operations of the VTC on sewage sludge and coal. Results predict over 40% HHV thermal efficiency to electric power from sewage sludge at more than 83% water by weight. The system appears to become autothermal (no supplemental fuel required) at about 35% fixed carbon in the feed. Thus, bituminous and lignite coal slurries could be gasified at less than 25% coal and more than 75% water. Preliminary life cycle cost analyses indicate that disposal fees for sewage sludge improve operating economics over fuel that must be purchased, the cost and schedule advantages of natural gas-fired combined cycle systems are preserved. Sensitivity analyses show that increasing capital costs by 50% can be offset by an increase in sewage sludge disposal fees of $10/metric ton.

  15. Studies, Transport and Treatment Concept for Boilers from Berkeley NPP, England - 13599

    SciTech Connect (OSTI)

    Wirendal, Bo [Studsvik Nuclear AB (Sweden)] [Studsvik Nuclear AB (Sweden); Saul, David; Robinson, Joe; Davidson, Gavin [Studsvik UK Ltd (United Kingdom)] [Studsvik UK Ltd (United Kingdom)

    2013-07-01T23:59:59.000Z

    In November 2011 Studsvik was awarded a contract to transport five decommissioned boilers from the Berkeley Nuclear Licensed Site in the UK to the Studsvik Nuclear Site in Sweden for metal treatment and recycling. A key objective of the project was to remove the boilers from the site by 31 March 2012 and this was successfully achieved with all boilers off site by 22 March and delivered to Studsvik on 6 April. Four boilers have been processed and the fifth is planned for completion by end of December 2012.The project had many challenges including a very tight timescale and has been successfully delivered to cost and ahead of the baseline programme. This paper describes the project and the experience gained from treatment of the first four boilers. It is the first UK project to send large components overseas for recycling and provides new insight into the processing of Magnox gas-circuit components. (authors)

  16. New source performance standards for industrial boilers. Volume 2. Review of industry operating practices

    SciTech Connect (OSTI)

    Bryan, R.J.; Weisenberg, I.J.; Wilson, K.

    1980-09-01T23:59:59.000Z

    The applicability is evaluated of several possible versions of a revised New Source Performance Standards (NSPS) for industrial boilers to boilers that are operated according to typical industry practices. A survey of operating practices is presented, and it is concluded that an NSPS that includes too high a percent removal requirement for SO/sub 2/ (90%) might be excessively costly and cause operating problems for the industrial operator. More field evaluations of low excess air and low Btu gasification are required to validate these techniques for pollution control under industrial boiler operating conditions. The cost of two small boilers with no SO/sub 2/ controls was less than one large boiler of twice the capacity with SO/sub 2/ controls. The annual cost of operating and maintaining the control system accounted for the difference.

  17. Modular approach for modelling a multi-energy district boiler Julien Eynard, Stphane Grieu1 and Monique Polit

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Modular approach for modelling a multi-energy district boiler Julien Eynard, Stéphane Grieu1 with the modelling of a district boiler (city of La Rochelle, west coast of France), as part of the OptiEnR research project. This "multi- energy" boiler supplies domestic hot water and heats residential and public

  18. Error Recovery for a Boiler System with OTS PID Controller Tom Anderson, Mei Feng, Steve Riddle, Alexander Romanovsky

    E-Print Network [OSTI]

    Newcastle upon Tyne, University of

    Error Recovery for a Boiler System with OTS PID Controller Tom Anderson, Mei Feng, Steve Riddle-The-Shelf) item. The case study used a Simulink model of a steam boiler system together with an OTS PID in practice, employing software models of the PID controller and the steam boiler system rather than

  19. Error Recovery for a Boiler System with OTS PID Controller Tom Anderson, Mei Feng, Steve Riddle, Alexander Romanovsky

    E-Print Network [OSTI]

    Newcastle upon Tyne, University of

    1 Error Recovery for a Boiler System with OTS PID Controller Tom Anderson, Mei Feng, Steve Riddle employing an OTS (Off-The-Shelf) item. The case study used a Simulink model of a steam boiler system, employing software models of the PID controller and the steam boiler system rather than conducting

  20. Efficient model-based leak detection in boiler steam-water systems Xi Sun, Tongwen Chen *, Horacio J. Marquez

    E-Print Network [OSTI]

    Marquez, Horacio J.

    Efficient model-based leak detection in boiler steam-water systems Xi Sun, Tongwen Chen *, Horacio detection in boiler steam-water systems. The algorithm has been tested using real industrial data from Syncrude Canada, and has proven to be effective in detection of boiler tube or steam leaks; proper

  1. Supercritical carbon dioxide cycle control analysis.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. J. (Nuclear Engineering Division)

    2011-04-11T23:59:59.000Z

    This report documents work carried out during FY 2008 on further investigation of control strategies for supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle energy converters. The main focus of the present work has been on investigation of the S-CO{sub 2} cycle control and behavior under conditions not covered by previous work. An important scenario which has not been previously calculated involves cycle operation for a Sodium-Cooled Fast Reactor (SFR) following a reactor scram event and the transition to the primary coolant natural circulation and decay heat removal. The Argonne National Laboratory (ANL) Plant Dynamics Code has been applied to investigate the dynamic behavior of the 96 MWe (250 MWt) Advanced Burner Test Reactor (ABTR) S-CO{sub 2} Brayton cycle following scram. The timescale for the primary sodium flowrate to coast down and the transition to natural circulation to occur was calculated with the SAS4A/SASSYS-1 computer code and found to be about 400 seconds. It is assumed that after this time, decay heat is removed by the normal ABTR shutdown heat removal system incorporating a dedicated shutdown heat removal S-CO{sub 2} pump and cooler. The ANL Plant Dynamics Code configured for the Small Secure Transportable Autonomous Reactor (SSTAR) Lead-Cooled Fast Reactor (LFR) was utilized to model the S-CO{sub 2} Brayton cycle with a decaying liquid metal coolant flow to the Pb-to-CO{sub 2} heat exchangers and temperatures reflecting the decaying core power and heat removal by the cycle. The results obtained in this manner are approximate but indicative of the cycle transient performance. The ANL Plant Dynamics Code calculations show that the S-CO{sub 2} cycle can operate for about 400 seconds following the reactor scram driven by the thermal energy stored in the reactor structures and coolant such that heat removal from the reactor exceeds the decay heat generation. Based on the results, requirements for the shutdown heat removal system may be defined. In particular, the peak heat removal capacity of the shutdown heat removal loop may be specified to be 1.1 % of the nominal reactor power. An investigation of the oscillating cycle behavior calculated by the ANL Plant Dynamics Code under specific conditions has been carried out. It has been found that the calculation of unstable operation of the cycle during power reduction to 0 % may be attributed to the modeling of main compressor operation. The most probable reason for such instabilities is the limit of applicability of the currently used one-dimensional compressor performance subroutines which are based on empirical loss coefficients. A development of more detailed compressor design and performance models is required and is recommended for future work in order to better investigate and possibly eliminate the calculated instabilities. Also, as part of such model development, more reliable surge criteria should be developed for compressor operation close to the critical point. It is expected that more detailed compressor models will be developed as a part of validation of the Plant Dynamics Code through model comparison with the experiment data generated in the small S-CO{sub 2} loops being constructed at Barber-Nichols Inc. and Sandia National Laboratories (SNL). Although such a comparison activity had been planned to be initiated in FY 2008, data from the SNL compression loop currently in operation at Barber Nichols Inc. has not yet become available by the due date of this report. To enable the transient S-CO{sub 2} cycle investigations to be carried out, the ANL Plant Dynamics Code for the S-CO{sub 2} Brayton cycle was further developed and improved. The improvements include further optimization and tuning of the control mechanisms as well as an adaptation of the code for reactor systems other than the Lead-Cooled Fast Reactor (LFR). Since the focus of the ANL work on S-CO{sub 2} cycle development for the majority of the current year has been on the applicability of the cycle to SFRs, work has started on modification of the ANL Plant Dynamics Code to allow

  2. Research, Development and Demonstration of Bio-Mass Boiler for Food Industry

    SciTech Connect (OSTI)

    Fisher, Steve; Knapp, David

    2012-03-31T23:59:59.000Z

    Frito-Lay is working to reduce carbon emissions from their manufacturing plants. As part of this effort, they invested in a â??biomass-firedâ?ť boiler at the Topeka, Kansas, plant. Frito-Lay partnered with Burns & McDonnell Engineering, Inc. and CPL Systems, Inc., to design and construct a steam producing boiler using â??carbon neutralâ?ť fuels such as wood wastes (e.g. tree bark), shipping pallets, and used rubber vehicle tires. The U.S. Department of Energy (DOE) joined with Frito-Lay, Burns & McDonnell, and CPL to analyze the reductions in carbon dioxide (CO{sub 2}) emissions that result from use of biomass-fired boilers in the food manufacturing environment. DOE support provided for the data collection and analysis, and reporting necessary to evaluate boiler efficiencies and reductions in CO{sub 2} emissions. The Frito-Lay biomass-fired boiler has resulted in significant reductions in CO{sub 2} emissions from the Topeka production facility. The use of natural gas has been reduced by 400 to 420 million standard cubic feet per year with corresponding reductions of 24,000 to 25,000 tons of CO{sub 2}. The boiler does require auxiliary â??functions,â?ť however, that are unnecessary for a gas-fired boiler. These include heavy motors and fans for moving fuel and firing the boiler, trucks and equipment for delivering the fuel and moving at the boiler plant, and chippers for preparing the fuel prior to delivery. Each of these operations requires the combustion of fossil fuels or electricity and has associated CO{sub 2} emissions. Even after accounting for each of these auxiliary processes, however, the biomass-fired boiler results in net emission reductions of 22,500 to 23,500 tons of CO{sub 2} per year.

  3. Pattern of Thermal Fluctuations in a Recovery Boiler Floor

    SciTech Connect (OSTI)

    Abdullah, Z.; Gorog, J.P.; Keiser, J.R.; Meyers, L.E.; Swindeman, R.W.

    1999-04-25T23:59:59.000Z

    The floor of a black liquor recovey boiler at a mill in central Canada has experienced cracking and delamination of the composite tubing near the spout wall and deformation of the floor panels that is most severe in the vicinity of the spout wall. One possible explanation for the observed damage is impacts of salt cake falling from the convective section onto the floor. In order to determine if such impacts do occur, strain gauges and thermocouples were installed on the boiler floor in areas where cracking and deformation were most frequent. The data obtained from these instruments indicate that brief, sudden temperature fluctuations do occur, and changes in the strain experienced by the affected tube occur simultaneously. These fluctuations appear to occur less often along the spout wall and more frequently with increasing distance from the wall. The frequency of these temperature fluctuations is insufficient for thermal fatigue to be the sole cause of the cracking observed on the tubes, but the data are consistent with what might be expected from pieces of falling salt cake.

  4. Pattern of thermal fluctuations in a recovery boiler floor

    SciTech Connect (OSTI)

    Keiser, J.R.; Meyers, L.E.; Swindeman, R.W.; Gorog, J.P.; Abdullah, Z.

    1999-07-01T23:59:59.000Z

    The floor of a black liquor recovery boiler at a mill in central Canada has experienced cracking and delamination of the composite tubing near the spout wall and deformation of the floor panels that is most severe in the vicinity of the spout wail. One possible explanation for the observed damage is impacts of salt cake falling from the convective section onto the floor. In order to determine if such impacts do occur, strain gauges and thermocouples were installed on the boiler floor in areas where cracking and deformation were most frequent. The data obtained from these instruments indicate that brief, sudden temperature fluctuations do occur, and changes in the strain experienced by-the affected tube occur simultaneously. These fluctuations appear to occur less often along the spout wall and more frequently with increasing distance from the wall. The frequency of these temperature fluctuations is insufficient for thermal fatigue to be the sole cause of the cracking observed on the tubes, but the data are consistent with what might be expected from pieces of falling salt cake.

  5. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Martin Denison; Connie Senior; Hong-Shig Shim; Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker

    2005-06-30T23:59:59.000Z

    This is the twentieth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NO{sub x} control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. At the beginning of this quarter, the corrosion probes were removed from Gavin Station. Data analysis and preparation of the final report continued this quarter. This quarterly report includes further results from the BYU catalyst characterization lab and the in-situ FTIR lab, and includes the first results from tests run on samples cut from the commercial plate catalysts. The SCR slipstream reactor at Plant Gadsden was removed from the plant, where the total exposure time on flue gas was 350 hours. A computational framework for SCR deactivation was added to the SCR model.

  6. Coal reburning for cyclone boiler NO sub x control demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    Babcock Wilcox engineering studies followed by pilot-scale testing has developed/confirmed the potential of utilizing gas, oil or coal reburning as a viable NO{sub x} reduction technology. To date, two US sponsored programs promote natural gas/oil as a reburning fuel because it was believed that gas/oil will provide significantly higher combustion efficiency than using coal at the reburn zone. Although B W has shown that gas/oil reburning will play a role in reducing NO{sub x} emissions from cyclone boilers, B W coal reburning research has also shown that coal as a reburning fuel performs nearly as well as gas/oil without deleterious effects on combustion efficiency. This means that boilers using reburning for NO, control can maintain 100% coal usage instead of switching to 20% gas/oil for reburning. As a result of the B W performed coal reburning research, the technology has advanced to the point which it is now ready for demonstration on a commercial scale.

  7. Circulating fluidized-bed boiler makes inroads for waste recycling

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    Circulating fluidized-bed (CFB) boilers have ben used for years in Scandinavia to burn refuse-derived fuel (RDF). Now, Foster Wheeler Power Systems, Inc., (Clinton, N.J.) is bringing the technology to the US. Touted as the world`s largest waste-to-energy plant to use CFB technology, the Robbins (III.) Resource Recovery Facility will have the capacity to process 1,600 tons/d of municipal solid waste (MSW) when it begins operation in early 1997. The facility will have two materials-separation and RDF-processing trains, each with dual trommel screens, magnetic and eddy current separators, and shredders. About 25% of the incoming MSW will be sorted and removed for recycling, while 75% of it will be turned into fuel, with a heat value of roughly 6,170 btu/lb. Once burned in the twin CFB boilers the resulting steam will be routed through a single turbine generator to produce 50,000 mW of electric power.

  8. Corrosion of ferriticmartensitic steels in steam and supercritical water Jeremy Bischoff a,b

    E-Print Network [OSTI]

    Motta, Arthur T.

    Corrosion of ferritic­martensitic steels in steam and supercritical water Jeremy Bischoff a: Available online xxxx a b s t r a c t Corrosion tests were performed in steam and supercritical water at 500 °C for two ferritic­martensitic alloys: HCM12A and NF616. The corrosion kinetics for the two alloys

  9. Convective heat transfer characteristics of China RP-3 aviation kerosene at supercritical pressure

    E-Print Network [OSTI]

    Guo, Zhixiong "James"

    Convective heat transfer characteristics of China RP-3 aviation kerosene at supercritical pressure Keywords: Supercritical pressure Aviation kerosene Convective heat transfer Numerical study a b s t r a c convective in kerosene pipe flow is complicated. Here the convective heat transfer characteristics of China

  10. Transmission electron microscopy of oxide development on 9Cr ODS steel in supercritical water

    E-Print Network [OSTI]

    Motta, Arthur T.

    Transmission electron microscopy of oxide development on 9Cr ODS steel in supercritical water A strengthened ferritic steel alloys during exposure to 600 °C supercritical water for 2- and 4-weeks were cladding include austenitic stainless steels, solid solution and precipitation-hardened alloys, ferritic

  11. Self-assembly of surfactants in a supercritical solvent from lattice Monte Carlo simulations

    E-Print Network [OSTI]

    Lisal, Martin

    Self-assembly of surfactants in a supercritical solvent from lattice Monte Carlo simulations Martin self-assembly of surfactants in a supercritical solvent by large-scale Monte Carlo simulations. CarbonCO2.3 Surfactant molecules used in scCO2 have two mutually incompatible components: a CO2-philic tail

  12. Celerity and Amplification of Supercritical Surface Waves Pierre Y. Julien1

    E-Print Network [OSTI]

    Julien, Pierre Y.

    . 2003 . Simplified wave models present advantages over the dynamic wave model due to lower computationalCelerity and Amplification of Supercritical Surface Waves Pierre Y. Julien1 ; Noah Friesen2 ; Jennifer G. Duan3 ; and Richard Eykholt4 Abstract: The amplification of supercritical waves in steep

  13. Compliance testing of Grissom AFB, Central Heating Plant coal-fired boilers 3, 4 and 5, Grissom AFB, Indiana. Final report, 3-13 Dec 90

    SciTech Connect (OSTI)

    Vaughn, R.W.

    1991-03-01T23:59:59.000Z

    Source compliance testing (particulates and visible emissions) of boiler 3, 4 and 5 in the Grissom AFB Central Heating Plant was accomplished 3-13 Dec 90. The boilers were all tested through the bypass stack. Visible emissions from the three boilers met applicable opacity regulations. However, particulate emissions from the three boilers were above their applicable emission standards.

  14. Solubilities of p-quinone and 9,10-anthraquinone in supercritical carbon dioxide

    SciTech Connect (OSTI)

    Coutsikos, P.; Magoulas, K.; Tassios, D. [National Technical Univ. of Athens (Greece)] [National Technical Univ. of Athens (Greece)

    1997-05-01T23:59:59.000Z

    Equilibrium solubilities of p-quinone (1,4-benzoquinone) and 9,10-anthraquinone at 35 C and 45 C in supercritical carbon dioxide over a pressure range of about (85--300) bar have been measured using a supercritical fluid extractor coupled with a high-pressure liquid chromatography apparatus. The solubility results, along with those reported in the literature for 1,4-naphthoquinone, are correlated with a modified Peng-Robinson equation of state. The ability of a supercritical fluid to separate a multicomponent mixture is unique, since it utilizes the salient features of both distillation and liquid extraction. The solubility of a solute in a supercritical fluid is the most important thermophysical property that has to be determined and modeled for an efficient design of any extraction based on supercritical solvents.

  15. Techno-economic analysis of wood biomass boilers for the greenhouse industry

    SciTech Connect (OSTI)

    Chau, J. [University of British Columbia, Vancouver; Sowlati, T. [University of British Columbia, Vancouver; Sokhansanj, Shahabaddine [ORNL; Bi, X.T. [University of British Columbia, Vancouver; Preto, F. [Natural Resources Canada; Melin, Staffan [University of British Columbia, Vancouver

    2009-01-01T23:59:59.000Z

    The objective of this study is to perform a techno-economic analysis on a typical wood pellet and wood residue boiler for generation of heat to an average-sized greenhouse in British Columbia. The variables analyzed included greenhouse size and structure, boiler efficiency, fuel types, and source of carbon dioxide (CO2) for crop fertilization. The net present value (NPV) show that installing a wood pellet or a wood residue boiler to provide 40% of the annual heat demand is more economical than using a natural gas boiler to provide all the heat at a discount rate of 10%. For an assumed lifespan of 25 years, a wood pellet boiler system could generate NPV of C$259,311 without electrostatic precipitator (ESP) and C$74,695 with ESP, respectively. While, installing a wood residue boiler with or without an ESP could provide NPV of C$919,922 or C$1,104,538, respectively. Using a wood biomass boiler could also eliminate over 3000 tonne CO2 equivalents of greenhouse gases annually. Wood biomass combustion generates more particulate matters than natural gas combustion. However, an advanced emission control system could significantly reduce particulate matters emission from wood biomass combustion which would bring the particulate emission to a relatively similar level as for natural gas.

  16. Final technical report. In-situ FT-IR monitoring of a black liquor recovery boiler

    SciTech Connect (OSTI)

    James Markham; Joseph Cosgrove; David Marran; Jorge Neira; Chad Nelson; Peter Solomon

    1999-05-31T23:59:59.000Z

    This project developed and tested advanced Fourier transform infrared (FT-IR) instruments for process monitoring of black liquor recovery boilers. The state-of-the-art FT-IR instruments successfully operated in the harsh environment of a black liquor recovery boiler and provided a wealth of real-time process information. Concentrations of multiple gas species were simultaneously monitored in-situ across the combustion flow of the boiler and extractively at the stack. Sensitivity to changes of particulate fume and carryover levels in the process flow were also demonstrated. Boiler set-up and operation is a complex balance of conditions that influence the chemical and physical processes in the combustion flow. Operating parameters include black liquor flow rate, liquor temperature, nozzle pressure, primary air, secondary air, tertiary air, boiler excess oxygen and others. The in-process information provided by the FT-IR monitors can be used as a boiler control tool since species indicative of combustion efficiency (carbon monoxide, methane) and pollutant emissions (sulfur dioxide, hydrochloric acid and fume) were monitored in real-time and observed to fluctuate as operating conditions were varied. A high priority need of the U.S. industrial boiler market is improved measurement and control technology. The sensor technology demonstrated in this project is applicable to the need of industry.

  17. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Pisupati, S.V.; Poe, R.L.; Morrison, J.L.; Xie, J.; Walsh, P.M.; Wincek, R.T.; Clark, D.A.; Scaroni, A.W.

    1993-04-21T23:59:59.000Z

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the capability of effectively firing SCCWS in an industrial boiler designed for heavy fuel oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with 3.0 wt.% ash and 0.9 wt.% sulfur) can effectively be burned in a heavy fuel oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) program expansion (additional 1,000 hours of testing). The boiler testing wig determine if the SCCWS combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion limits, and fuel transport, storage, and handling characteristics can be accommodated in an oil-designed boiler system. In addition, the proof-of-concept demonstration will generate data to determine how the properties of SCCWS and its parent coal affect boiler performance. Economic factors associated with retrofitting boilers will be identified

  18. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Schobert, H.H.

    1990-09-28T23:59:59.000Z

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program with the objective of demonstrating the capability of effectively firing SCCWS in industrial boilers designed for oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with less than 3.0% ash and 0.9% sulfur) can effectively be burned in oil-designed industrial boilers without adverse impact on boiler rating, maintainability, reliability and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of three phases: (1) design, permitting, and test planning, (2) construction and start up, and (3) demonstration and evaluation. The boiler testing will determine if the SCCWS combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion limits, and fuel transport, storage, and handling characteristics can be accommodated in an oil-designed boiler system. In addition, the proof-of-concept demonstration will generate data to determine how the properties of SCCWS and its parent coal affect boiler performance. Economic factors associated with retrofitting and operating boilers will be identified to assess the viability of future oil-to-coal retrofits. Progress is reported. 7 refs., 7 figs., 1 tab.

  19. Composite tube cracking in kraft recovery boilers: A state-of-the-art review

    SciTech Connect (OSTI)

    Singbeil, D.L.; Prescott, R. [Pulp and Paper Research Inst. of Canada, Vancouver, British Columbia (Canada); Keiser, J.R.; Swindeman, R.W. [Oak Ridge National Lab., TN (United States)

    1997-07-01T23:59:59.000Z

    Beginning in the mid-1960s, increasing energy costs in Finland and Sweden made energy recovery more critical to the cost-effective operation of a kraft pulp mill. Boiler designers responded to this need by raising the steam operating pressure, but almost immediately the wall tubes in these new boilers began to corrode rapidly. Test panels installed in the walls of the most severely corroding boiler identified austenitic stainless steel as sufficiently resistant to the new corrosive conditions, and discussions with Sandvik AB, a Swedish tube manufacturer, led to the suggestion that coextruded tubes be used for water wall service in kraft recovery boilers. Replacement of carbon steel by coextruded tubes has solved most of the corrosion problems experienced by carbon steel wall tubes, however, these tubes have not been problem-free. Beginning in early 1995, a multidisciplinary research program funded by the US Department of Energy was established to investigate the cause of cracking in coextruded tubes and to develop improved materials for use in water walls and floors of kraft recovery boilers. One portion of that program, a state-of-the-art review of public- and private-domain documents related to coextruded tube cracking in kraft recovery boilers is reported here. Sources of information that were consulted for this review include the following: tube manufacturers, boiler manufacturers, public-domain literature, companies operating kraft recovery boilers, consultants and failure analysis laboratories, and failure analyses conducted specifically for this project. Much of the information contained in this report involves cracking problems experienced in recovery boiler floors and those aspects of spout and air-port-opening cracking not readily attributable to thermal fatigue. 61 refs.

  20. User's manual for the INDCEPT code for estimating industrial steam boiler plant capital investment costs

    SciTech Connect (OSTI)

    Bowers, H I; Fuller, L C; Hudson, II, C R

    1982-09-01T23:59:59.000Z

    The INDCEPT computer code package was developed to provide conceptual capital investment cost estimates for single- and multiple-unit industrial steam boiler plants. Cost estimates can be made as a function of boiler type, size, location, and date of initial operation. The output includes a detailed breakdown of the estimate into direct and indirect costs. Boiler plant cost models are provided to reflect various types and sources of coal and alternate means of sulfur and particulate removal. Cost models are also included for low-Btu and medium-Btu gas produced in coal gasification plants.

  1. Upgrade of Multiple Boiler/Turbine Plant to Microprocessor Control- A Case History

    E-Print Network [OSTI]

    Schenk, J. R.; Sommer, A. C.

    'lis is done by first calculating the sum of the losses efficiency 0 line and using that and auxiliaries costs to determine the cost I curve function for each boiler. The incremental co~ts for each are CjPared 231 I 1 I ESL-IE-85-05-44 Proceedings from... into equipment maintenance. Boiler efficiency degradation can be monitored and actions taken before an unexpected outage occurs. A -loose- boiler really didn't matter before, now the maintenance staff is able to keep the system operat.ing at peak...

  2. Recovery Act: Oxy-Combustion Techology Development for Industrial-Scale Boiler Applications

    SciTech Connect (OSTI)

    Levasseur, Armand

    2014-04-30T23:59:59.000Z

    Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: • Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs. • Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF). • Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools. • Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems. • Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost. • Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project completion date was April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a matrix of fuels, oxyprocess variables and boiler design parameters. Significant improvement of CFD modeling tools and validation against 15 MWth experimental data has been completed. Oxy-boiler demonstration and large reference designs have been developed, supported with the information and knowledge gained from the 15 MWth testing. The results from the 15 MWth testing in the BSF and complimentary bench-scale testing are addressed in this volume (Volume II) of the final report. The results of the modeling efforts (Volume III) and the oxy boiler design efforts (Volume IV) are reported in separate volumes.

  3. TA-2 water boiler reactor decommissioning (Phase 1)

    SciTech Connect (OSTI)

    Elder, J.C.; Knoell, C.L.

    1986-12-01T23:59:59.000Z

    Removal of external structures and underground piping associated with the gaseous effluent (stack) line from the TA-2 Water Boiler Reactor was performed as Phase I of reactor decommissioning. Six concrete structures were dismantled and 435 ft of contaminated underground piping was removed. Extensive soil contamination by /sup 137/Cs was encountered around structure TA-2-48 and in a suspected leach field near the stream flowing through Los Alamos Canyon. Efforts to remove all contaminated soil were hampered by infiltrating ground water and heavy rains. Methods, cleanup guidelines, and ALARA decisions used to successfully restore the area are described. The cost of the project was approximately $320K; 970 m/sup 3/ of low-level solid radioactive waste resulted from the cleanup operations.

  4. Design and development for a low emission boiler system

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    The Department of Energy initiated the Combustion 2000 program to develop the next generation of coal-fired power plants. Sargent & Lundy (S&L) is working on the Low Emission Boiler System (LEBS) portion of the program led by Riley Stoker Corporation, with support from Textron Defense Systems, Tecogen, and Reaction Engineering International. Together these organizations form {open_quotes}the Riley Team.{close_quotes} There are four phases of the LEBS development program. Currently, we are working in Phase I, which involves the design of a 400 MWe unit. Phase II through IV will involve pilot scale component testing and a Proof-of-Concept facility ({approximately}40MWe) design, construction, and operation. This document comprises the Design and Development Report for the LEBS. The report describes the design basis, design uncertainties and development plan for each of the major LEBS subsystems.

  5. Chemical Functionalization of Nanostructured Materials Using Supercritical Reaction Media

    SciTech Connect (OSTI)

    Zemanian, Thomas S.; Fryxell, Glen E.; Liu, Jun; Mattigod, Shas V.; Shin, Yongsoon; Franz, James A.; Ustyugov, Oleksiy A.; Nie, Zimin

    2001-12-15T23:59:59.000Z

    There exists a need for durable and thin functional coatings to utilize the afforded surface area of highly porous ceramic materials. Deposition of silane-based Self Assembled Monolayers (SAMs) has thus far been limited to maximum coverages of 4-5 molecules/nm2 and long processing times (up to 2 weeks), due to the restricted internal geometry of the substrates. Results are presented for SAMs deposited on high surface area silica from supercritical fluids (SCFs). The SAMs so produced display unprecedented coverages, high monolayer integrity, and extremely low surface defect density. Moreover, the depositions and subsequent removal of reaction byproducts are complete in a matter of minutes rather than days. Nuclear Magnetic Resonance (NMR) spectra of the surface modified silica are presented, demonstrating the SAM integrity and evolution over time. Sorption of aqueous metal ions is demonstrated, and results are given demonstrating the broad pH stability of the deposited SAMs. A chemical explanation for the enhanced deposition is posited, and the kinetics of mass transport into and out of the nanostructured spaces are discussed.Related experiments using zeolite substrates show deposition of thiol-terminated silanes to internal surfaces of 6? microporous material. After oxidation of the thiol functional group size selective chemistry was demonstrated using the produced catalyst, proving the efficacy of the supercritical reaction medium for installing functional coatings inside pores of similar diameters to the chain length of the deposited molecule[]. Comparisons are made between the response of the different substrates to the supercritical fluid-based processing, and remarks on the utility of SCF based processing of nanostructured materials are presented.

  6. Reactions of inorganic nitrogen species in supercritical water

    SciTech Connect (OSTI)

    Dell`Orco, P.C. [Texas Univ., Austin, TX (United States)] [Texas Univ., Austin, TX (United States)

    1994-12-31T23:59:59.000Z

    Redox reactions of nitrate salts with NH3 and methanol were studied in near-critical and supercritical water at 350 to 530 C and constant pressure of 302 bar. Sodium nitrate decomposition reactions were investigated at similar conditions. Reactions were conducted in isothermal tubular reactor under plug flow. For kinetic modeling, nitrate and nitrite reactants were lumped into an NO{sub x}{sup -} reactant; kinetic expressions were developed for MNO{sub 3}/NH{sub 4}X and sodium nitrate decomposition reactions. The proposed elementary reaction mechanism for MNO{sub 3}/NH{sub 4}X reaction indicated that NO{sub 2} was the primary oxidizing species and that N{sub 2}/N{sub 2}O selectivities could be determined by the form of MNO{sub 3} used. This suggest a nitrogen control strategy for use in SCWO (supercritical water oxidation) processes; nitrate or NH3 could be used to remove the other, at reaction conditions far less severe than required by other methods. Reactions of nitrate with methanol indicated that nitrate was a better oxidant than oxygen in supercritical water. Nitrogen reaction products included NH3 and nitrite, while inorganic carbon was the major carbon reaction product. Analysis of excess experiments indicated that the reaction at 475 C was first order in methanol concentration and second order in NO{sub x}{sup -} concentration. In order to determine phase regimes for these reactions, solubility of sodium nitrate was determined for some 1:1 nitrate electrolytes. Solubilities were measured at 450 to 525 C, from 248 to 302 bar. A semi-empirical solvation model was shown to adequately describe the experimental sodium nitrate solubilities. Solubilities of Li, Na, and K nitrates revealed with cations with smaller ionic radii had greater solubilities with nitrate.

  7. ADVANCED, LOW/ZERO EMISSION BOILER DESIGN AND OPERATION

    SciTech Connect (OSTI)

    Ovidiu Marin; Fabienne Chatel-Pelage

    2003-07-01T23:59:59.000Z

    This document reviews the work performed during the quarter April-June 2003. The main focus of this quarter has been the site preparation (task 1) for the test campaign scheduled in September/October 2003. Task 3 (Techno-economical assessment) has also been initiated while selecting the methodology to be used in the economics analysis and specifying the plants to be compared: In Task 1 (Site Preparation), the process definition and design activities have been completed, the equipment and instruments required have been identified, and the fabrication and installation activities have been initiated, to implement the required modifications on the pilot boiler. As of today, the schedule calls for completion of construction by late-July. System check-down is scheduled for the first two weeks of August. In Task 2 (Combustion and Emissions Performance Optimization), four weeks of testing are planned, two weeks starting second half of August and two weeks starting at the end of September. In Task 3 (Techno-Economic Study), the plants to be evaluated have been specified, including baseline cases (air fired PC boilers with or without CO{sub 2} capture), O{sub 2}-fired cases (with or without flue gas recirculation) and IGCC cases. Power plants ranging from 50 to 500MW have been selected and the methodology to be used has been described, both for performance evaluation and cost assessment. The first calculations will be performed soon and the first trends will be reported in the next quarter. As part of Task 5 (Project Management & Reporting), the subcontract between Babcock&Wilcox and American Air Liquide has been finalized. The subcontract between ISGS and American Air Liquide is in the final stages of completion.

  8. The reapplication of energetic materials as boiler fuels

    SciTech Connect (OSTI)

    Buckley, S.G.; Sclippa, G.C.; Ross, J.R. [and others

    1997-02-01T23:59:59.000Z

    Decommissioning of weapons stockpiles, off-specification production, and upgrading of weapons systems results in a large amount of energetic materials (EM) such as rocket propellant and primary explosives that need to be recycled or disposed of each year. Presently, large quantities of EM are disposed of in a process known as open-burn/open-detonation (OB/OD), which not only wastes their energy content, but may release large quantities of hazardous material into the environment. Here the authors investigate the combustion properties of several types of EM to determine the feasibility of reapplication of these materials as boiler fuels, a process that could salvage the energy content of the EM as well as mitigate any potential adverse environmental impact. Reapplication requires pretreatment of the fuels to make them safe to handle and to feed. Double-base nitrocellulose and nitroglycerin, trinitrotoluene (TNT), nitroguanidine, and a rocket propellant binder primarily composed of polybutidiene impregnated with aluminum flakes have been burned in a 100-kW downfired flow reactor. Most of these fuels have high levels of fuel-bound nitrogen, much of it bound in the form of nitrate groups, resulting in high NO{sub x} emissions during combustion. The authors have measured fuel-bound nitrate conversion efficiencies to NO{sub x} of up to 80%, suggesting that the nitrate groups do not follow the typical path of fuel nitrogen through HCN leading to NO{sub x}, but rather form NO{sub x} directly. They show that staged combustion is effective in reducing NO{sub x} concentrations in the postcombustion gases by nearly a factor of 3. In the rocket binder, measured aluminum particle temperatures in excess of 1700{degrees}C create high levels of thermal NO{sub x}, and also generate concern that molten aluminum particles could potentially damage boiler equipment. Judicious selection of the firing method is thus required for aluminum-containing materials.

  9. ADVANCED, LOW/ZERO EMISSION BOILER DESIGN AND OPERATION

    SciTech Connect (OSTI)

    Fabienne Chatel-Pelage

    2003-10-01T23:59:59.000Z

    This document reviews the work performed during the quarter July--September 2003. Significant progress has been made in Task 1 (Site Preparation), Task 2 (Test performance) and Task 3 (Techno-Economic Study) of the project: the site preparation has been completed, two weeks of tests have been performed and the power generating units to be compared from an economical standpoint have been selected and accurately described. In the experimental part of this effort (task1), the partners in this project demonstrated the feasibility of 100% air replacement with O{sub 2}-enriched flue gas on 1.5MW coal-fired boiler. The air infiltration have been reduced to approximately 5% of the stoichiometry, enabling to reach around 70% of CO{sub 2} in the flue gases. Higher air in-leakage reduction is expected using alternative boiler operating procedure in order to achieve higher CO{sub 2} concentration in flue gas for further sequestration or reuse. The NO{sub x} emissions have been shown considerably lower in O{sub 2}-fired conditions than in air-baseline, the reduction rate averaging 70%. An additional week of tests is scheduled mid October 2003 for combustion parameter optimization, and some more days of operation will be dedicated to mercury emission measurement and heat transfer characterization. Out of the $485k already allocated in this project, $300k has been spent and reported to date, mainly in site preparation ({approx}$215k) and test performance ({approx}$85k). In addition to DOE allocated funds, to date approximately $240k has been cost-shared by the participants, bringing the total project cost up to $540k as on September 30, 2003.

  10. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-06-30T23:59:59.000Z

    This is the sixteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. During an unplanned outage, damage occurred to the electrochemical noise corrosion probes installed at the AEP Gavin plant; testing is expected to resume in August. The KEMCOP corrosion coupons were not affected by the unplanned outage; the coupons were removed and sent for analysis. BYU conducted a series of tests before the ISSR lab was relocated. Ammonia adsorption experiments provided clear evidence of the types of acidic sites present on catalyst surfaces. Data collected this quarter indicate that surface sulfation decreases Lewis acid site concentrations for all catalysts thus far studied, confirming that catalytic activity under commercial coal-based SCR conditions occurs primarily on Br{o}nsted acid sites and would be susceptible to basic impurities such as alkali and alkaline earth oxides, chlorides, and sulfates. SCR activity tests based on MS analysis showed that increasing sulfation generally increases NO reduction activity for both 0% and 1% vanadia catalysts. During this quarter, the slipstream reactor at Rockport operated for 720 hours on flue gas. Catalyst exposure time reached 4500 hours since installation. The reactor is out of service at the Rockport plant and plans are being made to move it to the Gadsden Plant. At Gadsden, modifications have begun in preparation for installation of the slipstream reactor next quarter.

  11. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Temi Linjewile; Connie Senior; Hong-Shig Shim; Bob Hurt; Eric Eddings; Larry Baxter

    2003-01-30T23:59:59.000Z

    This is the tenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, progress was made on the computational simulation of a full-scale boiler with the purpose of understanding the potential impacts of burner operating conditions on soot and NO{sub x} generation. Sulfation tests on both the titania support and vanadia/titania catalysts were completed using BYU's in situ spectroscopy reactor this quarter. These experiments focus on the extent to which vanadia and titania sulfate in an SO{sub 2}-laden, moist environment. Construction of the CCS reactor system is essentially complete and the control hardware and software are largely in place. A large batch of vanadia/titania catalyst in powder form has been prepared for use in poisoning tests. During this quarter, minor modifications were made to the multi-catalyst slipstream reactor and to the control system. The slipstream reactor was installed at AEP's Rockport plant at the end of November 2002. In this report, we describe the reactor system, particularly the control system, which was created by REI specifically for the reactor, as well as the installation at Rockport.

  12. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers

    Broader source: Energy.gov [DOE]

    This fact sheet describes a supercritical carbon dioxide turbo-expander and heat exchangers project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by the Southwest Research Institute, is working to develop a megawatt-scale s-CO2 hot-gas turbo-expander optimized for the highly transient solar power plant profile. The team is also working to optimize novel printed circuit heat exchangers for s-CO2 applications to drastically reduce their manufacturing costs.

  13. Supercritical Helium Cooling of the LHC Beam Screens

    E-Print Network [OSTI]

    Hatchadourian, E; Tavian, L

    1998-01-01T23:59:59.000Z

    The cold mass of the LHC superconducting magnets, operating in pressurised superfluid helium at 1.9 K, must be shielded from the dynamic heat loads induced by the circulating particle beams, by means of beam screens maintained at higher temperature. The beam screens are cooled between 5 and 20 K by forced flow of weakly supercritical helium, a solution which avoids two-phase flow in the long, narr ow cooling channels, but still presents a potential risk of thermohydraulic instabilities. This problem has been studied by theoretical modelling and experiments performed on a full-scale dedicated te st loop.

  14. Project Profile: Direct Supercritical Carbon Dioxide Receiver Development |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d FNEPA/309DepartmentDepartment of Energy Direct Supercritical

  15. Supercritical water oxidation test bed effluent treatment study

    SciTech Connect (OSTI)

    Barnes, C.M.

    1994-04-01T23:59:59.000Z

    This report presents effluent treatment options for a 50 h Supercritical Water Test Unit. Effluent compositions are calculated for eight simulated waste streams, using different assumed cases. Variations in effluent composition with different reactor designs and operating schemes are discussed. Requirements for final effluent compositions are briefly reviewed. A comparison is made of two general schemes. The first is one in which the effluent is cooled and effluent treatment is primarily done in the liquid phase. In the second scheme, most treatment is performed with the effluent in the gas phase. Several unit operations are also discussed, including neutralization, mercury removal, and evaporation.

  16. Hydroetching of high surface area ceramics using moist supercritical fluids

    DOE Patents [OSTI]

    Fryxell, Glen; Zemanian, Thomas S.

    2004-11-02T23:59:59.000Z

    Aerogels having a high density of hydroxyl groups and a more uniform pore size with fewer bottlenecks are described. The aerogel is exposed to a mixture of a supercritical fluid and water, whereupon the aerogel forms a high density of hydroxyl groups. The process also relaxes the aerogel into a more open uniform internal structure, in a process referred to as hydroetching. The hydroetching process removes bottlenecks from the aerogels, and forms the hydrogels into more standard pore sizes while preserving their high surface area.

  17. Residential Bulk-Fed Wood-Pellet Central Boilers and Furnace Rebate Program

    Broader source: Energy.gov [DOE]

    The New Hampshire Public Utilities Commission (PUC) is offering rebates of 30% of the installed cost of qualifying new residential bulk-fed, wood-pellet central heating boilers or furnaces. The...

  18. Benefits of Industrial Boiler Control and Economic Load Allocation at AMOCO Chemicals, Decatur, Alabama

    E-Print Network [OSTI]

    Winter, J.

    The objective of this paper is to provide an overview of the economic benefits realized by Amoco's Decatur plant from the utilization of Honeywell's Industrial Boiler Control solution and Turbo Economic Load Allocation packages on an integrated four...

  19. 2014-02-07 Issuance: Test Procedure for Commercial Packaged Boilers; Request for Information

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register request for information regarding test procedures for commercial packaged boilers, as issued by the Deputy Assistant Secretary for Energy Efficiency on February 7, 2014.

  20. Recovery Boiler Modeling: An Improved Char Burning Model Including Sulfate Reduction and Carbon Removal

    E-Print Network [OSTI]

    Grace, T. M.; Wag, K. J.; Horton, R. R.; Frederick, W. J.

    gasification, reactions between oxygen and combustibles in the boundary layer, and integration of sulfate reduction and sulfide reoxidation into the char burning process. Simulations using the model show that for typical recovery boiler conditions, char burning...

  1. 2014-01-31 Issuance: Energy Conservation Standards for Residential Boilers; Notice of Data Availability

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register notice of data availability regarding energy conservation standards for residential boilers, as issued by the Deputy Assistant Secretary for Energy Efficiency on January 31, 2014.

  2. A methodology for in-situ calibration of steam boiler instrumentation

    E-Print Network [OSTI]

    Wei, Guanghua

    1997-01-01T23:59:59.000Z

    This thesis presents a broadly useful diagnostic methodology to engineers and plant managers for finding the in-situ operating characteristics of power plant boilers when metered data is either missing or obviously erroneous. The methodology is able...

  3. Task 2: Materials for Advanced Boiler and Oxy-combustion Systems

    SciTech Connect (OSTI)

    G. R. Holcomb and B. McGhee

    2009-05-01T23:59:59.000Z

    Characterize advanced boiler (oxy-fuel combustion, biomass cofired) gas compositions and ash deposits Generate critical data on the effects of environmental conditions; develop a unified test method with a view to future standardisation

  4. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.

    2007-01-01T23:59:59.000Z

    change; Steam plant; Steam turbine; Electricity 1.housed ?ve 10,000 kW steam turbines and typically requiredAdvances in boiler and steam turbine technology, materials

  5. Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on installing high-pressure boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  6. Novel Supercritical Carbon Dioxide Power Cycle Utilizing Pressured Oxy-combustion in Conjunction with Cryogenic Compression

    SciTech Connect (OSTI)

    Brun, Klaus; McClung, Aaron; Davis, John

    2014-03-31T23:59:59.000Z

    The team of Southwest Research Institute® (SwRI) and Thar Energy LLC (Thar) applied technology engineering and economic analysis to evaluate two advanced oxy-combustion power cycles, the Cryogenic Pressurized Oxy-combustion Cycle (CPOC), and the Supercritical Oxy-combustion Cycle. This assessment evaluated the performance and economic cost of the two proposed cycles with carbon capture, and included a technology gap analysis of the proposed technologies to determine the technology readiness level of the cycle and the cycle components. The results of the engineering and economic analysis and the technology gap analysis were used to identify the next steps along the technology development roadmap for the selected cycle. The project objectives, as outlined in the FOA, were 90% CO{sub 2} removal at no more than a 35% increase in cost of electricity (COE) as compared to a Supercritical Pulverized Coal Plant without CO{sub 2} capture. The supercritical oxy-combustion power cycle with 99% carbon capture achieves a COE of $121/MWe. This revised COE represents a 21% reduction in cost as compared to supercritical steam with 90% carbon capture ($137/MWe). However, this represents a 49% increase in the COE over supercritical steam without carbon capture ($80.95/MWe), exceeding the 35% target. The supercritical oxy-combustion cycle with 99% carbon capture achieved a 37.9% HHV plant efficiency (39.3% LHV plant efficiency), when coupling a supercritical oxy-combustion thermal loop to an indirect supercritical CO{sub 2} (sCO{sub 2}) power block. In this configuration, the power block achieved 48% thermal efficiency for turbine inlet conditions of 650°C and 290 atm. Power block efficiencies near 60% are feasible with higher turbine inlet temperatures, however a design tradeoff to limit firing temperature to 650°C was made in order to use austenitic stainless steels for the high temperature pressure vessels and piping and to minimize the need for advanced turbomachinery features such as blade cooling. The overall technical readiness of the supercritical oxy-combustion cycle is TRL 2, Technology Concept, due to the maturity level of the supercritical oxy-combustor for solid fuels, and several critical supporting components, as identified in the Technical Gap Analysis. The supercritical oxycombustor for solid fuels operating at pressures near 100 atm is a unique component of the supercritical oxy-combustion cycle. In addition to the low TRL supercritical oxy-combustor, secondary systems were identified that would require adaptation for use with the supercritical oxycombustion cycle. These secondary systems include the high pressure pulverized coal feed, high temperature cyclone, removal of post-combustion particulates from the high pressure cyclone underflow stream, and micro-channel heat exchangers tolerant of particulate loading. Bench scale testing was utilized to measure coal combustion properties at elevated pressures in a CO{sub 2} environment. This testing included coal slurry preparation, visualization of coal injection into a high pressure fluid, and modification of existing test equipment to facilitate the combustion properties testing. Additional bench scale testing evaluated the effectiveness of a rotary atomizer for injecting a coal-water slurry into a fluid with similar densities, as opposed to the typical application where the high density fluid is injected into a low density fluid. The swirl type supercritical oxy-combustor was developed from initial concept to an advanced design stage through numerical simulation using FLUENT and Chemkin to model the flow through the combustor and provide initial assessment of the coal combustion reactions in the flow path. This effort enabled the initial combustor mechanical layout, initial pressure vessel design, and the conceptual layout of a pilot scale test loop. A pilot scale demonstration of the supercritical oxy-combustion cycle is proposed as the next step in the technology development. This demonstration would advance the supercritical oxy-combustion cycle and the supercritical

  7. Transpiring wall supercritical water oxidation reactor salt deposition studies

    SciTech Connect (OSTI)

    Haroldsen, B.L.; Mills, B.E.; Ariizumi, D.Y.; Brown, B.G. [and others

    1996-09-01T23:59:59.000Z

    Sandia National Laboratories has teamed with Foster Wheeler Development Corp. and GenCorp, Aerojet to develop and evaluate a new supercritical water oxidation reactor design using a transpiring wall liner. In the design, pure water is injected through small pores in the liner wall to form a protective boundary layer that inhibits salt deposition and corrosion, effects that interfere with system performance. The concept was tested at Sandia on a laboratory-scale transpiring wall reactor that is a 1/4 scale model of a prototype plant being designed for the Army to destroy colored smoke and dye at Pine Bluff Arsenal in Arkansas. During the tests, a single-phase pressurized solution of sodium sulfate (Na{sub 2}SO{sub 4}) was heated to supercritical conditions, causing the salt to precipitate out as a fine solid. On-line diagnostics and post-test observation allowed us to characterize reactor performance at different flow and temperature conditions. Tests with and without the protective boundary layer demonstrated that wall transpiration provides significant protection against salt deposition. Confirmation tests were run with one of the dyes that will be processed in the Pine Bluff facility. The experimental techniques, results, and conclusions are discussed.

  8. Use of (high temperature) ammoniated citric acid for boiler chemical cleaning

    SciTech Connect (OSTI)

    Smith, C.W. [Georgia Power Co., Atlanta, GA (United States)

    1995-01-01T23:59:59.000Z

    Georgia Power`s primary boiler cleaning solvent in the past has been hydrochloric acid. Citric acid has recently been used on two boilers in an effort to move to a safer and more environmentally acceptable cleaning solvent. As with any change, there is a learning curve and the (new) cleaning process has to be proven with regard to process consistency and cleaning effectiveness. This paper describes our experiences with citric acid along with comparisons of past hydrochloric acid cleanings.

  9. Combustion control in boilers. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-11-01T23:59:59.000Z

    The bibliography contains citations concerning utility and industrial boiler combustion control systems and methods. Topics include methods to meet emission standards, energy savings, and safety. The use of microcomputers, mathematical models, algorithms, artificial intelligence, and fuzzy logic is considered. Citations on boilers and furnaces fueled by coal, oil, gas, refuse, and multiple fuels are included. (Contains a minimum of 128 citations and includes a subject term index and title list.)

  10. Post-remedial action report for the Water Boiler Reactor Site

    SciTech Connect (OSTI)

    Montoya, G.M.

    1991-05-01T23:59:59.000Z

    The TA-2 Water Boiler Reactor Decommissioning Project decontaminated and decommissioned the Water Boiler Reactor, TA-2-1-122, at Los Alamos National Laboratory in Los Alamos, New Mexico, to provide reusable space at the TA-2 site and to eliminate the hazard of accidental intrusion into a contaminated structure. This report documents the radiological condition of the site after the decommissioning and decontamination between June 1989 and April 1990. 7 refs., 3 figs., 5 tabs.

  11. Low NO sub x /SO sub x Burner retrofit for utility cyclone boilers

    SciTech Connect (OSTI)

    Not Available

    1990-01-01T23:59:59.000Z

    The objective of this project is to demonstrate the LNS Burner as retrofitted to the host cyclone boiler for effective low-cost control of NO{sub x} and SO{sub x} emissions while firing a bituminous coal. The LNS Burner employs a simple, innovative combustion process to burn pulverized coal at high temperatures and provides effective, low-cost control of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions. The coal ash contains sulfur and is removed in the form of molten slag and flyash. Cyclone-fired boiler units are typically older units firing high-sulfur bituminous coals at very high temperatures which results in very high NO{sub x} and SO{sub x} emissions. The addition of conventional emission control equipment, such as wet scrubbers, to these older cyclone units in order to meet current and future environmental regulations is generally not economic. Further, the units are generally not compatible with low sulfur coal switching for S0{sub 2} control or selective catalytic reduction technologies for NO{sub x} control. Because the LNS Burner operates at the same very high temperatures as a typical cyclone boiler and produces a similar slag product, it may offer a viable retrofit option for cyclone boiler emission control. This was confirmed by the Cyclone Boiler Retrofit Feasibility Study carried out by TransAlta and an Operating Committee formed of cyclone boiler owners in 1989. An existing utility cyclone boiler, was then selected for the evaluation of the cost and performance study. It was concluded that the LNS Burner retrofit would be a cost-effective option for control of cyclone boiler emissions. A full-scale demonstration of the LNS Burner retrofit was selected in October 1988 as part of the DOE's Clean Coal Technology Program Round II.

  12. Modeling energy consumption of residential furnaces and boilers in U.S. homes

    SciTech Connect (OSTI)

    Lutz, James; Dunham-Whitehead, Camilla; Lekov, Alex; McMahon, James

    2004-02-01T23:59:59.000Z

    In 2001, DOE initiated a rulemaking process to consider whether to amend the existing energy efficiency standards for furnaces and boilers. A key factor in DOE's consideration of new standards is their cost-effectiveness to consumers. Determining cost-effectiveness requires an appropriate comparison of the additional first cost of energy efficiency design options with the savings in operating costs. This report describes calculation of equipment energy consumption (fuel and electricity) based on estimated conditions in a sample of homes that are representative of expected furnace and boiler installations. To represent actual houses with furnaces and boilers in the United States, we used a set of houses from the Residential Energy Consumption Survey of 1997 conducted by the Energy Information Administration. Our calculation methodology estimates the energy consumption of alternative (more-efficient) furnaces, if they were to be used in each house in place of the existing equipment. We developed the method of calculation described in this report for non-weatherized gas furnaces. We generalized the energy consumption calculation for this product class to the other furnace product classes. Fuel consumption calculations for boilers are similar to those for the other furnace product classes. The electricity calculations for boilers are simpler than for furnaces, because boilers do not provide thermal distribution for space cooling as furnaces often do.

  13. Final Report: Guided Acoustic Wave Monitoring of Corrosion in Recovery Boiler Tubing

    SciTech Connect (OSTI)

    Chinn, D J; Quarry, M J; Rose, J L

    2005-03-31T23:59:59.000Z

    Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This Department of Energy, Office of Industrial Technologies project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the cold side or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications. This technique appears very promising for recovery boiler tube application, potentially expediting annual inspection of tube integrity.

  14. Low NO sub x /SO sub x Burner retrofit for utility cyclone boilers

    SciTech Connect (OSTI)

    Not Available

    1990-01-01T23:59:59.000Z

    Cyclone furnaces operate with high excess air and at high temperature. The heat release during combustion is very high and as a result the boiler volume is much smaller than would be found in a conventional pc-fired system. The Marion Unit 1 boiler, at the level of the cyclone entry, has a small cross-section; about 5-feet in depth and about 20-feet in width. A boiler schematic showing the LNS Burner and relative location of the superheater region and overfire air ports is shown in Figure 1. The LNS Burner's combustion process is fundamentally different from that of the cyclone, and the combustion products are also different. The LNS Burner products enter the boiler as hot, fuel-rich gases. Additional overfire air must be added to complete this combustion step with care taken to avoid the formation of thermal NO{sub x}. If done correctly, S0{sub 2} is controlled and significant NO{sub x} reductions are achieved. Because of the small boiler volume, flow modelling was found to be necessary to insure that adequate mixing of LNS Burner combustion products with air can be accomplished to achieve NO{sub x} emissions goals. Design requirements for the air injection system for the Marion boiler were developed using FLUENT, a commercially available computational fluid dynamics (CFD) code. A series of runs were made to obtain a design for final air injection that met the process design goals as closely as possible.

  15. Measure Guideline: Condensing Boilers - Control Strategies for Optimizing Performance and Comfort in Residential Applications

    SciTech Connect (OSTI)

    Arena, L.

    2013-05-01T23:59:59.000Z

    The combination of a gas-fired condensing boiler with baseboard convectors and an indirect water heater has become a common option for high-efficiency residential space heating in cold climates. While there are many condensing boilers available on the market with rated efficiencies in the low to mid 90% efficient range, it is imperative to understand that if the control systems are not properly configured, these heaters will perform no better than their non-condensing counterparts. Based on previous research efforts, it is apparent that these types of systems are typically not designed and installed to achieve maximum efficiency (Arena 2010). It was found that there is a significant lack of information for contractors on how to configure the control systems to optimize overall efficiency. For example, there is little advice on selecting the best settings for the boiler reset curve or how to measure and set flow rates in the system to ensure that the return temperatures are low enough to promote condensing. It has also been observed that recovery from setback can be extremely slow and, at times, not achieved. Recovery can be affected by the outdoor reset control, the differential setting on the boiler and over-sizing of the boiler itself. This guide is intended for designers and installers of hydronic heating systems interested in maximizing the overall system efficiency of condensing boilers when coupled with baseboard convectors. It is applicable to new and retrofit applications.

  16. Advanced, Low/Zero Emission Boiler Design and Operation

    SciTech Connect (OSTI)

    Fabienne Chatel-Pelage; Rajani Varagani

    2004-06-30T23:59:59.000Z

    This document reviews the work performed during the quarter April-June 2004. Task 1 (Site Preparation) had been completed 2003, along with three weeks of oxycombustion tests in Task 2 (experimental test performance) of the project. In current reporting period, the experimental testing has been completed: one additional week of tests has been performed to finalize the optimization of the combustion characteristics in O{sub 2}/CO{sub 2} environment ; two more days of testing were dedicated to mercury sampling in air-fired or O{sub 2}-fired conditions, and to characterization of heat transfer in O{sub 2} conditions vs. to air-blown conditions. Task 3 (Techno-Economic Study) has also been completed in current quarter: 250MWe, 500MWe and 1000MWe oxygen-fired PC unit have been simulated and quoted, and their performance and cost have been compared to same-capacity air-fired pulverized coal (PC) unit and IGCC. New and retrofit cases have been evaluated. The comparison has been completed in terms of capital cost, operating cost, cost of electricity and cost of CO{sub 2} avoided. The scope of task 4 (Conceptual Boiler Design) had been modified as per DOE request in previous quarter. Engineering calculations are currently in progress. Next steps include detail review of the experimental data collected during the entire testing campaign, finalization of detailed report on economic task, and reporting of the preliminary results in the boiler design task. Two papers summarizing the project main achievements have been presented at Clearwater coal conference in April 2004 (overall project results), and at the CO{sub 2} sequestration conference in May 2004 (emphasis on economics). Out of the {approx}$785k allocated DOE funds in this project, $545k have been spent to date, mainly in site preparation, test performance and economics assessment. In addition to DOE allocated funds, to date approximately $400k have been cost-shared by the participants, bringing the total project cost up to $945k as on June 30, 2004.

  17. Mathematical Modeling and Experimental Study of Biomass Combustion in a Thermal 108 MW Grate-Fired Boiler

    E-Print Network [OSTI]

    Rosendahl, Lasse

    -Fired Boiler Chungen Yin,*, Lasse Rosendahl, Søren K. Kær, Sønnik Clausen, Søren L. Hvid,§ and Torben Hille, Denmark ReceiVed NoVember 16, 2007. ReVised Manuscript ReceiVed January 4, 2008 Grate boilers are widely) model for an industrial biomass-fired grate boiler, which can be used for diagnosis and optimization

  18. Conceptual Design of Oxygen-Based PC Boiler

    SciTech Connect (OSTI)

    Andrew Seltzer; Zhen Fan

    2005-09-01T23:59:59.000Z

    Coal is presently the world's primary fuel for generating electrical power and, being more abundant and less expensive than oil or natural gas, is expected to continue its dominance into the future. Coal, however, is more carbon intensive than natural gas and oil and consequently coal-fired power plants are large point source emitters of carbon dioxide (CO{sub 2}). Since CO{sub 2} is a greenhouse gas, which may have an adverse impact on the world's climate/weather patterns, studies have been conducted to determine the feasibility and economic impact of capturing power plant CO{sub 2} emissions for pipeline transport to a sequestration/storage site. The stack gas that exhausts from a modern coal-fired power plant typically contains about 15% CO{sub 2} on a dry volume basis. Although there are numerous processes available for removing CO{sub 2} from gas streams, gas scrubbing with amine solvent is best suited for this application because of the large gas volumes and low CO{sub 2} concentrations involved. Unfortunately the energy required to regenerate the solvent for continued use as a capturing agent is large and imposes a severe energy penalty on the plant. In addition this ''back end'' or post combustion cleanup requires the addition of large vessels, which, in retrofit applications, are difficult to accommodate. As an alternative to post combustion scrubbing, Foster Wheeler (FW) has proposed that the combustion process be accomplished with oxygen rather than air. With all air nitrogen eliminated, a CO{sub 2}-water vapor rich flue gas will be generated. After condensation of the water vapor, a portion of the flue gas will be recirculated back to the boiler to control the combustion temperature and the balance of the CO{sub 2} will be processed for pipeline transport. This proposed oxygen-carbon dioxide (O{sub 2}/CO{sub 2}) combustion process eliminates the need for CO{sub 2} removal/separation and reduces the cost of supplying a CO{sub 2} rich stream for sequestration. FW has developed a conceptual design of an O{sub 2} fired boiler to determine overall plant performance and economics. Five subtasks were conducted: (1) a literature review, (2) a system design and analysis, (3) a low NOx burner design and analysis, (4) a furnace and heat recovery area design analysis, and (5) an economic analysis. The objective of the literature search is to locate any data/information relevant to the Oxygen-Based PC Boiler conceptual design. The objective of the system design and analysis task is to optimize the PC boiler plant by maximizing system efficiency within practical considerations. Simulations of the oxygen-fired plant with CO{sub 2} sequestration were conducted using Aspen Plus and were compared to a reference air-fired 460 MW plant. Flue gas recycle is used in the O{sub 2}-fired PC to control the flame temperature. Parametric runs were made to determine the effect of flame temperature on system efficiency and required waterwall material and thickness. The degree of improvement on system efficiency of various modifications including hot gas recycle, purge gas recycle, flue gas feedwater recuperation, and recycle purge gas expansion were investigated. The selected O{sub 2}-fired design case has a system efficiency of 30.6% compared to the air-fired system efficiency of 36.7%. The design O{sub 2}-fired case requires T91 waterwall material and has a waterwall surface area of only 65% of the air-fired reference case. The objective of the low NOx burner design and analysis task is to optimize the burner design to ensure stable ignition, to provide safe operation, and to minimize pollutant formation. The burners were designed and analyzed using the Fluent CFD computer program. Four burner designs were developed: (1) with no OFG and 65% flue gas recycle, (2) with 20% OFG and 65% flue gas recycle, (3) with no OFG and 56% flue gas recycle and (4) with 20% OFG and 56% flue gas recycle. A 3-D Fluent simulation was made of a single wall-fired burner and horizontal portion of the furnace from the wall to the center. Without primary gas sw

  19. Scale-up of commercial PCFB boiler plant technology

    SciTech Connect (OSTI)

    Lamar, T.W.

    1993-10-01T23:59:59.000Z

    The DMEC-1 Demonstration Project will provide an 80 MWe commercial-scale demonstration of the Pressurized Circulating Fluidized Bed (PCFB) technology. Following confirmation of the PCFB design in the 80 MWe scale, the technology with be scaled to even larger commercial units. It is anticipated that the market for commercial scale PCFB plants will exist most predominantly in the utility and independent power producer (IPP) sectors. These customers will require the best possible plant efficiency and the lowest achievable emissions at competitive cost. This paper will describe the PCFB technology and the expected performance of a nominal 400 MWe PCFB power plant Illinois No. 6 coal was used as a representative fuel for the analysis. The description of the plant performance will be followed by a discussion of the scale-up of the major PCFB components such as the PCFB boiler, the pressure vessel, the ceramic filter, the coal/sorbent handling steam, the gas turbine, the heat recovery unit and the steam turbine, demonstrating the reasonableness of scale-up from demonstration plant to a nominal 400 MWe unit.

  20. Hot Corrosion at Air-Ports in Kraft Recovery Boilers

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Russell, James H.

    2003-01-01T23:59:59.000Z

    Hot corrosion can occur on the cold-side of airports in Kraft recovery boilers. The primary corrosion mechanism involves the migration of sodium hydroxide and potassium hydroxide vapors through leaks in the furnace wall at the airports and their subsequent condensation. It has been reported that stainless steel is attacked much faster than carbon steel in composite tubes, and that carbon steel tubing, when used with a low-chromium refractory, does not exhibit this type of corrosion. For hot corrosion fluxing of metal oxides, either acidic or basic fluxing takes place, with a solubility minimum at the basicity of transition between the two reactions. For stainless steel, if the basicity of the fused salt is between the iron and chromium oxide solubility minima, then a synergistic effect can occur that leads to rapid corrosion. The products of one reaction are the reactants of the other, which eliminates the need for rate-controlling diffusion. This effect can explain why stainless steel is attacked more readily than carbon steel.

  1. An Exploration of the Effect of Temperature on Different Alloys in a Supercritical Carbon Dioxide Environment

    E-Print Network [OSTI]

    Dunlevy, Michael William

    2009-01-01T23:59:59.000Z

    In the constant effort to increase efficiency, safety margins, and lower cost, a new breed of nuclear reactors, Generation IV, is being developed in which supercritical carbon dioxide (SCO?) is a prime coolant candidate. ...

  2. Synthesis of controlled release drug device with supercritical CO2 and co-solvent

    E-Print Network [OSTI]

    Bush, Joshua R.

    2007-04-25T23:59:59.000Z

    of these solvents are toxic themselves. Therefore, steps must be taken to either remove residual solvent from the final device or limit their use during synthesis. Ideally, it is desirable to remove the organic solvents from the process entirely. Supercritical...

  3. Theoretical and experimental analysis of supercritical carbon dioxide cooling / Paul Marius Harris.

    E-Print Network [OSTI]

    Harris, Paul Marius

    2014-01-01T23:59:59.000Z

    ??With on-going developments in the field of trans-critical carbon dioxide (R-744) vapour compression cycles, a need to effectively describe the heat transfer of supercritical carbon… (more)

  4. Power conversion system design for supercritical carbon dioxide cooled indirect cycle nuclear reactors

    E-Print Network [OSTI]

    Gibbs, Jonathan Paul

    2008-01-01T23:59:59.000Z

    The supercritical carbon dioxide (S-CO?) cycle is a promising advanced power conversion cycle which couples nicely to many Generation IV nuclear reactors. This work investigates the power conversion system design and ...

  5. Experimental assessment of the internal flow behavior of supercritical carbon dioxide

    E-Print Network [OSTI]

    Yang, David, S.M. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    This thesis presents an experimental assessment of the internal flow behavior of supercritical carbon dioxide. The investigation focused mainly on assessing condensation onset during rapid expansion of CO? into the two-phase ...

  6. High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical...

    Broader source: Energy.gov (indexed) [DOE]

    Low-Cost Solar Receiver for Use in a Supercritical CO 2 Recompression Cycle Brayton Energy, LLC Award Number: DE-EE0005799 | November 30, 2012 | Sullivan * Numerical Modeling is...

  7. Novel Approaches to Conserve Energy in Textile Processing Through The Use Of Supercritical Fluids

    E-Print Network [OSTI]

    Brown, M.; Sikorski, M.

    alternative to wet-processing is the use of supercritical fluids, such as carbon dioxide, as the carrier. This option would eliminate water discharge and convective drying and could achieve improved energy efficiency. A description of textile processing using...

  8. Dynamic response of the supercritical C0? Brayton recompression cycle to various system transients

    E-Print Network [OSTI]

    Trinh, Tri Q. (Tri Quang)

    2009-01-01T23:59:59.000Z

    The supercritical carbon dioxide (SC0?) power conversion system has been suggested for use with many of the Generation IV nuclear reactors. The SC0? cycle is highly attractive because of its low operating temperatures and ...

  9. The deterioration in heat transfer to fluids at supercritical pressure and high heat fluxes

    E-Print Network [OSTI]

    Shiralkar, B. S.

    1968-01-01T23:59:59.000Z

    At slightly supercritical pressure and in the neighborhood of the pseudo-critical temperature (defined as the temperature corresponding to the peak in specific heat at the operating pressure), the heat transfer coefficient ...

  10. Tools for supercritical carbon dioxide cycle analysis and the cycle's applicability to sodium fast reactors

    E-Print Network [OSTI]

    Ludington, Alexander R. (Alexander Rockwell)

    2009-01-01T23:59:59.000Z

    The Sodium-Cooled Fast Reactor (SFR) and the Supercritical Carbon Dioxide (S-C0?) Recompression cycle are two technologies that have the potential to impact the power generation landscape of the future. In order for their ...

  11. Co-oxidation in supercritical water : methylphosphonic acid-ethanol and ammonia-ethanol model systems

    E-Print Network [OSTI]

    Ploeger, Jason M

    2006-01-01T23:59:59.000Z

    Supercritical water (SCW) is an effective solvent for the destruction of organic compounds by oxidation. Because both organics and oxygen have high solubility in water above its critical point (To = 374 °C (647 K), Pc = ...

  12. An investigation of corrosion mechanisms of constructional alloys in supercritical water oxidation (SCWO) systems

    E-Print Network [OSTI]

    Kim, Hojong, 1974-

    2004-01-01T23:59:59.000Z

    Supercritical water oxidation (SCWO) is a technology that can effectively destroy aqueous organic waste above the critical point of pure water. These waste feed streams are very aggressive and pose material performance ...

  13. Oxidation kinetics of methylphosphonic acid in supercritical water : experimental measurements and model development

    E-Print Network [OSTI]

    Sullivan, Patricia A. (Patricia Ann), 1978-

    2004-01-01T23:59:59.000Z

    (cont.) at well-defined operating conditions and to develop. both microscopic and macroscopic models, ranging from regressed global models to an elementary reaction mechanism, to quantify MPA oxidation kinetics in supercritical ...

  14. Synchrotron X-ray Studies of Super-critical Carbon Dioxide /...

    Broader source: Energy.gov (indexed) [DOE]

    Program eere.energy.gov RelevanceImpact of Research Supercritical CO 2 Water Binary Fluids Geothermal region T. Tassaing et al., proc. 14th Int'l Conf. on properties of Water...

  15. Nano-scale magnetic film formation by decompression of supercritical CO?/ferric acetylacetonate solutions

    E-Print Network [OSTI]

    De Dea, Silvia

    2008-01-01T23:59:59.000Z

    GROWTH OF NANO-SCALE MAGNETIC FILMS USING CO 2 RESS EX-113 GROWTH OF NANO-SCALE MAGNETIC FILMS USING A SUPERCRIT-of EDX analysis on nano-scale ?lms. . . . . . . . . . . 109

  16. Experimental and simulation studies of sequestration of supercritical carbon dioxide in depleted gas reservoirs

    E-Print Network [OSTI]

    Seo, Jeong Gyu

    2004-09-30T23:59:59.000Z

    he feasibility of sequestering supercritical CO2 in depleted gas reservoirs. The experimental runs involved the following steps. First, the 1 ft long by 1 in. diameter carbonate core is inserted into a viton Hassler sleeve and placed inside...

  17. Metal Carbonation of Forsterite in Supercritical CO2 and H2O...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and reaction extent relevant to geologic carbon sequestration (GCS) using a model silicate mineral forsterite (Mg2SiO4)+supercriticalCO2 with and without H2O. Run conditions...

  18. Supercritical fluid thermodynamics for coal processing: Quarterly progress report, September 15, 1988--December 31, 1988

    SciTech Connect (OSTI)

    Eckert, C.A.

    1988-01-01T23:59:59.000Z

    Because of their unusual solvating and mass transfer properties, supercritical fluids show potential for a variety of coal processing applications. To establish a database of coal model compound equilibria, this quarter we have measured the solubility of 5,6-dimethyl-benzimidazole and anthraquinone in supercritical butane. In addition, we have used fluorescence spectroscopy to study the nature of the intermolecular interactions in the systems of pyrene and naphthalene in supercritical CO/sub 2/, C/sub 2/H/sub 4/, and CF/sub 3/H. The spectroscopy measurements are being used to guide the development of an equation of state that can be used to predict the solubility behavior so systems can be designed for the processing of coal with supercritical fluids. 4 figs.

  19. PHYSICAL REVIEW E 88, 042152 (2013) Unstable supercritical discontinuous percolation transitions

    E-Print Network [OSTI]

    D'Souza, Raissa

    , such as displaying a "Devil's staircase" of discrete jumps in the supercritical regime. Here we investigate whether where the order parameter exhibits a staircase, the largest discontinuity generically does not coincide

  20. Development and application of a steady state code for supercritical carbon dioxide cycles

    E-Print Network [OSTI]

    Legault, David M. (David Michael)

    2006-01-01T23:59:59.000Z

    The supercritical CO2 power conversion system is of interest for advanced nuclear reactor applications because the same efficiencies are obtained as for the most developed of the closed gas-turbine cycles (helium-Brayton), ...

  1. An analysis of ilmenite particles used as bed material for combustion of biomass in a CFB boiler.

    E-Print Network [OSTI]

    Corcoran, Angelica

    2013-01-01T23:59:59.000Z

    ??Combustion of biomass in a fluidized bed boiler with silica sand as bed material is related to problems such as agglomeration of bed material and… (more)

  2. Utredning av primärluftförvärmning till tvĺ avfallseldade pannor; Investigation of primary air preheating for two waste incineration boilers.

    E-Print Network [OSTI]

    Björkman, Mattias

    2008-01-01T23:59:59.000Z

    ?? The purpose of this degree-project was to investigate the possibilities for primary air preheating into the two smallest waste incineration boilers of Halmstad Energy… (more)

  3. Cold End Inserts for Process Gas Waste Heat Boilers Air Products, operates hydrogen production plants, which utilize large waste heat boilers (WHB)

    E-Print Network [OSTI]

    Demirel, Melik C.

    Cold End Inserts for Process Gas Waste Heat Boilers Overview Air Products, operates hydrogen walls. Air Products tasked our team to design an insert to place in the tubes of the WHB to increase flow velocity, thereby reducing fouling of the WHB. Objectives Air Products wishes that our team

  4. Optimization and Comparison of Direct and Indirect Supercritical Carbon Dioxide Power Plant Cycles for Nuclear Applications

    SciTech Connect (OSTI)

    Edwin A. Harvego; Michael G. McKellar

    2011-11-01T23:59:59.000Z

    There have been a number of studies involving the use of gases operating in the supercritical mode for power production and process heat applications. Supercritical carbon dioxide (CO2) is particularly attractive because it is capable of achieving relatively high power conversion cycle efficiencies in the temperature range between 550 C and 750 C. Therefore, it has the potential for use with any type of high-temperature nuclear reactor concept, assuming reactor core outlet temperatures of at least 550 C. The particular power cycle investigated in this paper is a supercritical CO2 Recompression Brayton Cycle. The CO2 Recompression Brayton Cycle can be used as either a direct or indirect power conversion cycle, depending on the reactor type and reactor outlet temperature. The advantage of this cycle when compared to the helium Brayton cycle is the lower required operating temperature; 550 C versus 850 C. However, the supercritical CO2 Recompression Brayton Cycle requires an operating pressure in the range of 20 MPa, which is considerably higher than the required helium Brayton cycle operating pressure of 8 MPa. This paper presents results of analyses performed using the UniSim process analyses software to evaluate the performance of both a direct and indirect supercritical CO2 Brayton Recompression cycle for different reactor outlet temperatures. The direct supercritical CO2 cycle transferred heat directly from a 600 MWt reactor to the supercritical CO2 working fluid supplied to the turbine generator at approximately 20 MPa. The indirect supercritical CO2 cycle assumed a helium-cooled Very High Temperature Reactor (VHTR), operating at a primary system pressure of approximately 7.0 MPa, delivered heat through an intermediate heat exchanger to the secondary indirect supercritical CO2 Brayton Recompression cycle, again operating at a pressure of about 20 MPa. For both the direct and indirect cycles, sensitivity calculations were performed for reactor outlet temperature between 550 C and 850 C. The UniSim models used realistic component parameters and operating conditions to model the complete reactor and power conversion systems. CO2 properties were evaluated, and the operating ranges of the cycles were adjusted to take advantage of the rapidly changing properties of CO2 near the critical point. The results of the analyses showed that, for the direct supercritical CO2 power cycle, thermal efficiencies in the range of 40 to 50% can be achieved. For the indirect supercritical CO2 power cycle, thermal efficiencies were approximately 10% lower than those obtained for the direct cycle over the same reactor outlet temperature range.

  5. Demonstration of sorbent injection technology on a tangentially coal-fired utility boiler (Yorktown Limb Demonstration)

    SciTech Connect (OSTI)

    Clark, J.P.; Koucky, R.W.; Gogineni, M.R. [Combustion Engineering, Inc., Windsor, CT (United States)] [and others

    1995-06-01T23:59:59.000Z

    Limestone Injection Multistage Burner (LIMB) technology has been successfully demonstrated on a tangentially fired coal-burning utility boiler, Virginia Power`s 180 MWe Yorktown Unit No. 2. This document summarizes the activities conducted, and results achieved, under this EPA-sponsored demonstration program. LIMB combines furnace injection of a calcium-based sorbent for moderate reductions of sulfur dioxide with a low nitrogen oxide firing system for NO{sub x} emissions reduction. The process is attractive for retrofit of existing coal-burning utility boilers, since the capital equipment requirements and overall sulfur reduction costs per ton of SO{sub 2} removed are less than for most other options, such as wet flue gas desulfurization. Five sorbents were tested: commercial hydrated lime, with and without calcium lignosulfonate treatment, each from two suppliers, and finely pulverized limestone. The effects of LIMB operation on boiler, electrostatic precipitator (ESP), and ash handling system performance are also discussed. The most significant impact on boiler performance was the deposition rate of LIMB solids plus flyash on boiler convective surfaces during continuous operation, resulting in poorer boiler heat transfer performance and higher temperatures leaving the boiler. Continuous operation of the sootblowing system minimized this effect. The results of two ESP performance tests which were conducted during continuous LIMB operation are discussed and compared to results from similar testing conducted without LIMB operation. Ash conditioning and disposal during LIMB operation at Yorktown was significantly affected by the unreacted lime in the ash. These problems, as well as suggested precautions to avoid them, are discussed. Recommendations for LIMB commercialization, and an evaluation of the economics of the technology in comparison to a conventional flue gas desulfurization system, are discussed.

  6. Sensing system for detection and control of deposition on pendant tubes in recovery and power boilers

    DOE Patents [OSTI]

    Kychakoff, George (Maple Valley, WA); Afromowitz, Martin A. (Mercer Island, WA); Hogle, Richard E. (Olympia, WA)

    2008-10-14T23:59:59.000Z

    A system for detection and control of deposition on pendant tubes in recovery and power boilers includes one or more deposit monitoring sensors operating in infrared regions of about 4 or 8.7 microns and directly producing images of the interior of the boiler, or producing feeding signals to a data processing system for information to enable a distributed control system by which the boilers are operated to operate said boilers more efficiently. The data processing system includes an image pre-processing circuit in which a 2-D image formed by the video data input is captured, and includes a low pass filter for performing noise filtering of said video input. It also includes an image compensation system for array compensation to correct for pixel variation and dead cells, etc., and for correcting geometric distortion. An image segmentation module receives a cleaned image from the image pre-processing circuit for separating the image of the recovery boiler interior into background, pendant tubes, and deposition. It also accomplishes thresholding/clustering on gray scale/texture and makes morphological transforms to smooth regions, and identifies regions by connected components. An image-understanding unit receives a segmented image sent from the image segmentation module and matches derived regions to a 3-D model of said boiler. It derives a 3-D structure the deposition on pendant tubes in the boiler and provides the information about deposits to the plant distributed control system for more efficient operation of the plant pendant tube cleaning and operating systems.

  7. Effect of bed pressure drop on performance of a CFB boiler

    SciTech Connect (OSTI)

    Hairui Yang; Hai Zhang; Shi Yang; Guangxi Yue; Jun Su; Zhiping Fu [Tsinghua University, Beijing (China). Department of Thermal Engineering

    2009-05-15T23:59:59.000Z

    The effect of bed pressure drop and bed inventory on the performances of a circulating fluidized bed (CFB) boiler was studied. By using the state specification design theory, the fluidization state of the gas-solids flow in the furnace of conventional CFB boilers was reconstructed to operate at a much lower bed pressure drop by reducing bed inventory and control bed quality. Through theoretical analysis, it was suggested that there would exist a theoretical optimal value of bed pressure drop, around which the boiler operation can achieve the maximal combustion efficiency and with significant reduction of the wear of the heating surface and fan energy consumption. The analysis was validated by field tests carried out in a 75 t/h CFB boiler. At full boiler load, when bed pressure drop was reduced from 7.3 to 3.2 kPa, the height of the dense zone in the lower furnace decreased, but the solid suspension density profile in the upper furnace and solid flow rate were barely influenced. Consequently, the average heat transfer coefficient in the furnace was kept nearly the same and the furnace temperature increment was less than 17{sup o}C. It was also found that the carbon content in the fly ash decreased first with decreasing bed pressure drop and then increased with further increasing bed pressure drop. The turning point with minimal carbon content was referred to as the point with optimal bed pressure drop. For this boiler, at the optimum point the bed pressure was around 5.7 kPa with the overall excess air ratio of 1.06. When the boiler was operated around this optimal point, not only the combustion efficiency was improved, but also fan energy consumption and wear of heating surface were reduced. 23 refs., 6 figs., 4 tabs.

  8. Limiting diffusion coefficients of heavy molecular weight organic contaminants in supercritical carbon dioxide

    E-Print Network [OSTI]

    Orejuela, Mauricio

    1994-01-01T23:59:59.000Z

    LIMITING DIFFUSION COEFFICIENTS OF HEAVY MOLECULAR WEIGHT ORGANIC CONTAMINANTS IN SUPERCRITICAL CARBON DIOXIDE A Thesis by MAURICIO OREJUELA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August 1994 Major Subject: Chemical Engineering LIMITING DIFFUSION COEFFICIENTS OF HEAVY MOLECULAR WEIGHT ORGANIC CONTAMINANTS IN SUPERCRITICAL CARBON DIOXIDE A Thesis by MAURICIO OREJUELA Submitted...

  9. Supercritical CO2 extraction of organic compounds from soil-water slurries

    E-Print Network [OSTI]

    Carter, Brian Dean

    2012-06-07T23:59:59.000Z

    SUPERCRITICAL COi EXTRACTION OF ORGANIC COMPOUNDS FROM SOIL-WATER SLURRIES A Thesis by BRIAN DEAN CARTER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1993 Major Subject: Chemical Engineering SUPERCRITICAL COz FXTRACTION OF ORGANIC COMPOUNDS FROM SOIL-WATER SLURRIES A Thesis by BRIAN DEAN CARTER Submitted to Texas A&M University in partial fulfillment of the requirements...

  10. Optically Thick Outflows of Supercritical Accretion Discs: Radiative Diffusion Approach

    E-Print Network [OSTI]

    P. Abolmasov; S. Karpov; Taro Kotani

    2008-09-04T23:59:59.000Z

    Highly supercritical accretion discs are probable sources of dense optically thick axisymmetric winds. We introduce a new approach based on diffusion approximation radiative transfer in a funnel geometry and obtain an analytical solution for the energy density distribution inside the wind assuming that all the mass, momentum and energy are injected well inside the spherization radius. This allows to derive the spectrum of emergent emission for various inclination angles. We show that self-irradiation effects play an important role altering the temperature of the outcoming radiation by about 20% and the apparent X-ray luminosity by a factor of 2-3. The model has been successfully applied to two ULXs. The basic properties of the high ionization HII-regions found around some ULXs are also easily reproduced in our assumptions.

  11. Supercritical Coulomb center and excitonic instability in graphene

    E-Print Network [OSTI]

    O. V. Gamayun; E. V. Gorbar; V. P. Gusynin

    2009-10-31T23:59:59.000Z

    It is well known that there are resonant states with complex energy for the supercritical Coulomb impurity in graphene. We show that opening of a quasiparticle gap decreases the imaginary part of energy, |ImE|, of these states and stabilizes the system. For gapless quasiparticles with strong Coulomb interaction in graphene, we solve the Bethe-Salpeter equation for the electron - hole bound state and show that it has a tachyonic solution for strong enough coupling \\alpha=e^2/\\kappa\\hbar v_F leading to instability of the system. In the random-phase approximation, the critical coupling is estimated to be \\alpha_c =1.62 and is an analogue of the critical charge in the Coulomb center problem. We argue that the excitonic instability should be resolved through the formation of an excitonic condensate and gap generation in the quasiparticle spectrum.

  12. Removal of pollutants from solid matrices using supercritical fluids

    SciTech Connect (OSTI)

    Tomasko, D.L. [Ohio State Univ., Columbus, OH (United States); Macnaughton, S.J.; Foster, N.R. [Univ. of South Wales, Kensington (Australia)] [and others

    1995-04-01T23:59:59.000Z

    Several supercritical fluid extraction (SCFE) processes have been proposed for removing toxic and intractable organic compounds from a range of contaminated solids. These include soil remediation and the regeneration of absorbents used to treat wastewater streams such as granular activated carbon (GAC). As a separation technique for environmental control, SCFR has several distinct advantages over conventional liquid extraction methods and incineration. Most notably, the contaminant is removed from the solvent in a concentrated form via a change in pressure or temperature and can be completely separated upon expansion to atmospheric pressure. The viability of SCFE hinges on process conditions such as solvent-feed ratio and solvent recycle ratio. The necessity of recycling solvent complicates the contaminant separation step since a complete reduction to atmospheric pressure would create large recompression costs. Because of this, the pressure and temperature dependence of contaminant solubility must be understood so that operating conditions for the separation step can be defined. Fortunately, this is the most developed aspect of SCF technology. However, the mass transfer limitations to removing contaminants from solids change with solvent flow rate. This paper discusses the use of SCFE for environmental control and presents results for the removal of DDT and 2-chlorophenol from GAC. 2-chlorophenol is almost completely removed with pure CO{sub 2} at 40{degrees}C and 101 bar while only 55% of the DDT is removed at 40{degrees}C and 200 bar. These differences in regeneration efficiency cannot be understood solely in terms of solubility but point to a need for detailed studies of adsorption equilibrium and mass transfer resistances in supercritical fluid systems.

  13. ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND

    Energy Savers [EERE]

    ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND RECOMMENDATIONS 2014 ULTRA-DEEPWATER ADVISORY COMMITTEE COMMITTEE FINDINGS AND RECOMMENDATIONS i Table of Contents Research and...

  14. Development of a Low Cost Ultra Specular Advanced Polymer Film...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of a Low Cost Ultra Specular Advanced Polymer Film Solar Reflector Development of a Low Cost Ultra Specular Advanced Polymer Film Solar Reflector This presentation was...

  15. Ultra Efficient Combined Heat, Hydrogen, and Power System - Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra Efficient Combined Heat, Hydrogen, and Power System - Fact Sheet, 2011 Ultra Efficient Combined Heat, Hydrogen, and Power System - Fact Sheet, 2011 FuelCell Energy, Inc., in...

  16. Ultra Efficient Combined Heat, Hydrogen, and Power System - Presentati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra Efficient Combined Heat, Hydrogen, and Power System - Presentation by FuelCell Energy, June 2011 Ultra Efficient Combined Heat, Hydrogen, and Power System - Presentation by...

  17. Novel Ultra-Low-Energy Consumption Ultrasonic Clothes Dryer ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra-Low-Energy Consumption Ultrasonic Clothes Dryer Novel Ultra-Low-Energy Consumption Ultrasonic Clothes Dryer Preliminary measured drying time of fabric sample using ultrasonic...

  18. Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum...

    Energy Savers [EERE]

    Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources Program Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources Program The...

  19. Ultra Clean and Efficient Natural Gas Reciprocating Engine for...

    Broader source: Energy.gov (indexed) [DOE]

    Ultra Clean and Efficient Natural Gas Reciprocating Engine for CHP - Presentation by Dresser Waukesha, June 2011 Ultra Clean and Efficient Natural Gas Reciprocating Engine for CHP...

  20. Ultra Efficient Combined Heat, Hydrogen, and Power System - Fact...

    Energy Savers [EERE]

    Ultra Efficient Combined Heat, Hydrogen, and Power System - Fact Sheet, 2015 Ultra Efficient Combined Heat, Hydrogen, and Power System - Fact Sheet, 2015 FuelCell Energy, Inc., in...

  1. Mechanical Design of Steel Tubing for Use in Black Liquor Recovery Boilers

    SciTech Connect (OSTI)

    Taljat, B.; Zacharaia, T.; Wang, X.; Kesier, J.; Swindeman, R.; Hubbard, C.

    1999-05-26T23:59:59.000Z

    Finite element models were developed for thermal-mechanical analysis of black liquor recovery boiler floor tubes. Residual stresses in boiler floors due to various manufacturing processes were analyzed. The modeling results were verified by X-ray and neutron diffraction measurements at room temperature on as-manufactured tubes as well as tubes after service. The established finite element models were then used to evaluate stress conditions during boiler operation. Using these finite element models, a parametric response surface study was performed to investigate the influence of material properties of the clad layer on stresses in the floor tubes during various boiler operating conditions, which yielded a generalized solution of stresses in the composite tube floors. The results of the study are useful for identifying the mechanisms of cracking experienced by recovery boilers. Based on the results of the response surface study, a recommendation was made for more suitable materials in terms of the analyzed mechanical properties. Alternative materials and manufacturing processes are being considered to improve the resistance to cracking and the in-service life of composite tubes. To avoid numerous FE stress-strain analyses of composite tubes made of different material combinations, a response surface study was performed that considered two essential mechanical properties of the clad material - coefficient of thermal expansion and yield stress - as independent variables. The response surface study provided a generalized solution of stresses in the floor in terms of the two selected parameters.

  2. Materials for the pulp and paper industry. Section 1: Development of materials for black liquor recovery boilers

    SciTech Connect (OSTI)

    Keiser, J.R.; Hubbard, C.R.; Payzant, E.A. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01T23:59:59.000Z

    Black liquor recovery boilers are essential components of kraft pulp and paper mills because they are a critical element of the system used to recover the pulping chemicals required in the kraft pulping process. In addition, the steam produced in these boilers is used to generate a significant portion of the electrical power used in the mill. Recovery boilers require the largest capital investment of any individual component of a paper mill, and these boilers are a major source of material problems in a mill. The walls and floors of these boilers are constructed of tube panels that circulate high pressure water. Molten salts (smelt) accumulate on the floor of recovery boilers, and leakage of water into the boiler can result in a violent explosion when the leaked water instantly vaporizes upon contacting the molten smelt. Because corrosion of the conventionally-used carbon steel tubing was found to be excessive in the lower section of recovery boilers, use of stainless steel/carbon steel co-extruded tubing was adopted for boiler walls to lessen corrosion and reduce the likelihood of smelt/water explosions. Eventually, this co-extruded or composite (as it is known in the industry) tubing was selected for use as a portion or all of the floor of recovery boilers, particularly those operating at pressures > 6.2 MPa (900 psi), because of the corrosion problems encountered in carbon steel floor tubes. Since neither the cause of the cracking nor an effective solution has been identified, this program was established to develop a thorough understanding of the degradation that occurs in the composite tubing used for walls and floors. This is being accomplished through a program that includes collection and review of technical reports, examination of unexposed and cracked tubes from boiler floors, computer modeling to predict residual stresses under operating conditions, and operation of laboratory tests to study corrosion, stress corrosion cracking, and thermal fatigue.

  3. Ultra-short pulse generator

    DOE Patents [OSTI]

    McEwan, T.E.

    1993-12-28T23:59:59.000Z

    An inexpensive pulse generating circuit is disclosed that generates ultra-short, 200 picosecond, and high voltage 100 kW, pulses suitable for wideband radar and other wideband applications. The circuit implements a nonlinear transmission line with series inductors and variable capacitors coupled to ground made from reverse biased diodes to sharpen and increase the amplitude of a high-voltage power MOSFET driver input pulse until it causes non-destructive transit time breakdown in a final avalanche shock wave diode, which increases and sharpens the pulse even more. 5 figures.

  4. Microgap ultra-violet detector

    DOE Patents [OSTI]

    Wuest, C.R.; Bionta, R.M.

    1994-09-20T23:59:59.000Z

    A microgap ultra-violet detector of photons with wavelengths less than 400 run (4,000 Angstroms) which comprises an anode and a cathode separated by a gas-filled gap and having an electric field placed across the gap is disclosed. Either the anode or the cathode is semi-transparent to UV light. Upon a UV photon striking the cathode an electron is expelled and accelerated across the gap by the electric field causing interactions with other electrons to create an electron avalanche which contacts the anode. The electron avalanche is detected and converted to an output pulse. 2 figs.

  5. Microgap ultra-violet detector

    DOE Patents [OSTI]

    Wuest, Craig R. (Danville, CA); Bionta, Richard M. (Livermore, CA)

    1994-01-01T23:59:59.000Z

    A microgap ultra-violet detector of photons with wavelengths less than 400 run (4000 Angstroms) which comprises an anode and a cathode separated by a gas-filled gap and having an electric field placed across the gap. Either the anode or the cathode is semi-transparent to UV light. Upon a UV photon striking the cathode an electron is expelled and accelerated across the gap by the electric field causing interactions with other electrons to create an electron avalanche which contacts the anode. The electron avalanche is detected and converted to an output pulse.

  6. ULTRA-DEEPWATER ADVISORY COMMITTEE

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartment of EnergyofProject is on Track |Weatherized|Energy-WaterUDAC2ULTRA-DEEPWATER

  7. NICKEL SPECIES EMISSION INVENTORY FOR OIL-FIRED BOILERS

    SciTech Connect (OSTI)

    Kevin C. Galbreath; Richard L. Schulz; Donald L. Toman; Carolyn M. Nyberg

    2004-01-01T23:59:59.000Z

    Representative duplicate fly ash samples were obtained from the stacks of 400-MW and 385-MW utility boilers (Unit A and Unit B, respectively) using a modified U.S. Environmental Protection Agency (EPA) Method 17 sampling train assembly as they burned .0.9 and 0.3 wt% S residual oils, respectively, during routine power plant operations. Residual oil fly ash (ROFA) samples were analyzed for nickel (Ni) concentrations and speciation using inductively coupled plasma-atomic emission spectroscopy, x-ray absorption fine structure (XAFS) spectroscopy, x-ray diffraction (XRD), and a water-soluble Ni extraction method. ROFA water extraction residues were also analyzed for Ni speciation using XAFS and XRD. Total Ni concentrations in the ROFAs were similar, ranging from 1.3 to 1.5 wt%; however, stack gas Ni concentrations in the Unit A were {approx}990 {micro}g/Nm{sup 3} compared to {approx}620 {micro}g/Nm{sup 3} for Unit B because of the greater residual oil feed rates employed at Unit A to attain higher load (i.e., MW) conditions with a lower heating value oil. Ni speciation analysis results indicate that ROFAs from Unit A contain about 3 wt% NiSO{sub 4} {center_dot} xH{sub 2}O (where x is assumed to be 6 for calculation purposes) and a Ni-containing spinel compound, similar in composition to (Mg,Ni)(Al,Fe){sub 2}O{sub 4}. ROFAs from Unit B contain on average 2.0 wt% NiSO{sub 4} {center_dot} 6H{sub 2}O and 1.1 wt% NiO. XAFS and XRD analyses did not detect any nickel sulfide compounds, including nickel subsulfide (Ni{sub 3}S{sub 2}) (XAFS detection limit is 5% of the total Ni concentration). In addition, XAFS measurements indicated that inorganic sulfate and organic thiophene species account for >97% of the total sulfur in the ROFAs. The presence of NiSO{sub 4} {center_dot} xH{sub 2}O and nickel oxide compound mixtures and lack of carcinogenic Ni{sub 3}S{sub 2} or nickel sulfide compounds (e.g., NiS, NiS{sub 2}) in ROFAs stack-sampled from 400- and 385-MW boilers are contrary to EPA's Ni inhalation cancer risk assessment (''Study of Hazardous Air Pollutant Emissions from Electric Utility Steam Generating Units--Final Report to Congress'', February 1998), where it is assumed that the Ni compound mixture emitted from oil-fired utilities is 50% as carcinogenic as Ni{sub 3}S{sub 2}. Apparently, this assumption greatly overestimates the Ni inhalation cancer risk from oil-fired utilities.

  8. Gas mixing in the wall layer of a CFB boiler

    SciTech Connect (OSTI)

    Sterneus, J.; Johnsson, F. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Energy Conversion

    1997-12-31T23:59:59.000Z

    Tracer-gas measurements were carried out in the transport zone of a 12 MW CFB boiler with special emphasis on the wall-layer flow. Helium (He) was used as tracer gas and a mass spectrometer was used to determine the He-concentrations. The primary gas velocity, U{sub 0}, was 1.2, 2.6 and 4.3 m/s (no secondary air) and the bed material was silica sand with an average particle diameter of 0.32 mm. Tracer gas was injected at different distances from one of the furnace walls and sampled above and below the injection level. In the wall layer, tracer-gas concentrations were detected above (C{sub above}) as well as below (C{sub below}) the injection height for all operating conditions, i.e., the gas flows both up and down from the injection point. The data show that the net flow of tracer gas in the wall layer depends on the operating conditions, and the concentration ratio of the down- and up-flowing gas, {psi} = C{sub below}/C{sub above}, decreases with increased gas velocity ({psi} > 1 for U{sub 0} = 1.2 m/s, {psi} {approx} 1 for U{sub 0} = 2.6 m/s and {psi} < 1 for U{sub 0} = 4.3 m/s). There exists a gas exchange between the core region and the wall-layer. A plug flow model applied to the core region gives a radial dispersion coefficient, D{sub r}, in the range of 0.015--0.025 m{sup 2}/s which is higher than the D{sub r} values reported in literature which are below 0.01 m{sup 2}/x. However, the latter values were obtained in tall and narrow risers.

  9. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Suuberg; Eric Eddings; Larry Baxter

    2002-01-31T23:59:59.000Z

    This is the sixth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. Preliminary results from laboratory and field tests of a corrosion probe to predict waterwall wastage indicate good agreement between the electrochemical noise corrosion rates predicted by the probe and corrosion rates measured by a surface profilometer. Four commercial manufacturers agreed to provide catalyst samples to the program. BYU has prepared two V/Ti oxide catalysts (custom, powder form) containing commercially relevant concentrations of V oxide and one containing a W oxide promoter. Two pieces of experimental apparatus being built at BYU to carry out laboratory-scale investigations of SCR catalyst deactivation are nearly completed. A decision was made to carry out the testing at full-scale power plants using a slipstream of gas instead of at the University of Utah pilot-scale coal combustor as originally planned. Design of the multi-catalyst slipstream reactor was completed during this quarter. One utility has expressed interest in hosting a long-term test at one of their plants that co-fire wood with coal. Tests to study ammonia adsorption onto fly ash have clearly established that the only routes that can play a role in binding significant amounts of ammonia to the ash surface, under practical ammonia slip conditions, are those that must involve co-adsorbates.

  10. Optimal life-extending control of a boiler system D. Li, H.J. Marquez, T. Chen and R.K. Gooden

    E-Print Network [OSTI]

    Marquez, Horacio J.

    Optimal life-extending control of a boiler system D. Li, H.J. Marquez, T. Chen and R.K. Gooden hierarchical LEC structure and apply it to a typical boiler system. There are two damage models

  11. Ultra-Deepwater Production Systems

    SciTech Connect (OSTI)

    Ken L. Smith; Marc E. Leveque

    2005-05-31T23:59:59.000Z

    The report herein is a summary of the work performed on three projects to demonstrate hydrocarbon drilling and production methods applicable to deep and ultra deepwater field developments in the Gulf of Mexico and other like applications around the world. This work advances technology that could lead to more economic development and exploitation of reserves in ultra-deep water or remote areas. The first project is Subsea Processing. Its scope includes a review of the ''state of the art'' in subsea components to enable primary production process functions such as first stage liquids and gas separation, flow boosting, chemical treatment, flow metering, etc. These components are then combined to allow for the elimination of costly surface production facilities at the well site. A number of studies were then performed on proposed field development projects to validate the economic potential of this technology. The second project involved the design and testing of a light weight production riser made of composite material. The proposed design was to meet an actual Gulf of Mexico deepwater development project. The various engineering and testing work is reviewed, including test results. The third project described in this report encompasses the development and testing of a close tolerance liner drilling system, a new technology aimed at reducing deepwater drilling costs. The design and prototype testing in a test well are described in detail.

  12. Technical and economic analysis: Gas cofiring in industrial boilers. Final report, November 1995-September 1996

    SciTech Connect (OSTI)

    Potter, F.J.

    1996-09-01T23:59:59.000Z

    This report presents an analysis of the technical and marketing issues associated with the deployment of natural gas cofiring technology in stoker boilers. As part of the work effort, a composite database of stoker boilers was developed using state and federal emission inventories over the years 1985 - 1995. Information sources included the most recent AIRS Facility Subsystem database, the Ozone Transport Region 1990 database, the 1990 Ohio Permit database and the 1985 NAPAP database--all are electronic databases of facilities with air emission permits. The initial data set included almost 3,000 stokers at about 1,500 locations. Stoker facilities were contacted to verify the operating status, capacity, fuel capability, efficiency and other stoker-specific data. The report presents the current stoker boiler distribution by SIC, industrial groups, primary solid fuel (coal, wood, waste, refuse), operating status, and state. Maps are included.

  13. Maximum Achievable Control Technology for New Industrial Boilers (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01T23:59:59.000Z

    As part of Clean Air Act 90 (CAAA90, the EPA on February 26, 2004, issued a final rulethe National Emission Standards for Hazardous Air Pollutants (NESHAP) to reduce emissions of hazardous air pollutants (HAPs) from industrial, commercial, and institutional boilers and process heaters. The rule requires industrial boilers and process heaters to meet limits on HAP emissions to comply with a Maximum Achievable Control Technology (MACT) floor level of control that is the minimum level such sources must meet to comply with the rule. The major HAPs to be reduced are hydrochloric acid, hydrofluoric acid, arsenic, beryllium, cadmium, and nickel. The EPA predicts that the boiler MACT rule will reduce those HAP emissions from existing sources by about 59,000 tons per year in 2005.

  14. ISSUANCE: 2014-11-13 Energy Conservation Standards for Commercial Packaged Boilers: Public Meeting and Availability of the Preliminary Technical Support Document

    Broader source: Energy.gov [DOE]

    Energy Conservation Standards for Commercial Packaged Boilers: Public Meeting and Availability of the Preliminary Technical Support Document

  15. Detection and control of deposition on pendant tubes of Kraft chemical recovery boilers. Quarterly report for the period July-September 1999

    SciTech Connect (OSTI)

    Kychakoff, George

    1999-10-01T23:59:59.000Z

    Activities during this period continued to focus on obtaining a clear image of deposits inside an operating recovery boiler.

  16. IEEE TRANSACTIONS ON INDUSTRIAL INFORMATICS, VOL. 3, NO. 1, FEBRUARY 2007 73 Constraint-Based Control of Boiler Efficiency

    E-Print Network [OSTI]

    Kusiak, Andrew

    -Based Control of Boiler Efficiency: A Data-Mining Approach Zhe Song and Andrew Kusiak, Member, IEEE Abstract--In this paper, a data-mining approach is used to de- velop a model for optimizing the efficiency of an electric-utility boiler subject to operating constraints. Selection of process vari- ables to optimize combustion

  17. Speci cation and Veri cation of a Steam-Boiler with Signal-Coq Micka l Kerb uf1

    E-Print Network [OSTI]

    Boyer, Edmond

    Speci cation and Veri cation of a Steam-Boiler with Signal-Coq Micka l Kerb uf1 , David Nowak2 assistant, Coq, for the speci cation and the veri cation of co-inductive properties of the well-known steam cation tools. Keywords: synchronous programming, theorem proving, the steam- boiler problem. 1

  18. Incorporating supercritical steam turbines into molten-salt power tower plants : feasibility and performance.

    SciTech Connect (OSTI)

    Pacheco, James Edward; Wolf, Thorsten [Siemens Energy, Inc., Orlando, FL; Muley, Nishant [Siemens Energy, Inc., Orlando, FL

    2013-03-01T23:59:59.000Z

    Sandia National Laboratories and Siemens Energy, Inc., examined 14 different subcritical and supercritical steam cycles to determine if it is feasible to configure a molten-salt supercritical steam plant that has a capacity in the range of 150 to 200 MWe. The effects of main steam pressure and temperature, final feedwater temperature, and hot salt and cold salt return temperatures were determined on gross and half-net efficiencies. The main steam pressures ranged from 120 bar-a (subcritical) to 260 bar-a (supercritical). Hot salt temperatures of 566 and 600%C2%B0C were evaluated, which resulted in main steam temperatures of 553 and 580%C2%B0C, respectively. Also, the effects of final feedwater temperature (between 260 and 320%C2%B0C) were evaluated, which impacted the cold salt return temperature. The annual energy production and levelized cost of energy (LCOE) were calculated using the System Advisory Model on 165 MWe subcritical plants (baseline and advanced) and the most promising supercritical plants. It was concluded that the supercritical steam plants produced more annual energy than the baseline subcritical steam plant for the same-size heliostat field, receiver, and thermal storage system. Two supercritical steam plants had the highest annual performance and had nearly the same LCOE. Both operated at 230 bar-a main steam pressure. One was designed for a hot salt temperature of 600%C2%B0C and the other 565%C2%B0C. The LCOEs for these plants were about 10% lower than the baseline subcritical plant operating at 120 bar-a main steam pressure and a hot salt temperature of 565%C2%B0C. Based on the results of this study, it appears economically and technically feasible to incorporate supercritical steam turbines in molten-salt power tower plants.

  19. Evaluation of coal-derived liquids as boiler fuels. Volume 1. Comprehensive report. Final report

    SciTech Connect (OSTI)

    Not Available

    1985-09-01T23:59:59.000Z

    A combustion demonstration using six coal-derived liquid (CDL) fuels was conducted on a utility boiler located at the Plant Sweatt Electric Generating Station of Mississippi Power Company in Meridian, Mississippi. The test program was conducted in two phases which are distinguished by the level of the test effort. The first phase included the combustion tests of the two conventional fuels used at the station (natural gas and No. 6 fuel oil) and three coal-derived liquid fuels (Solvent Refined Coal-II full range distillate, H-Coal heavy distillate and H-Coal blended distillate). Boiler performance monitoring included measurements for fuel steam and flue gas flow, pressure, temperature, and heat absorption, resulting in a calculated combustion efficiency, boiler efficiency, and heat rate. Emissions measurements included oxygen, carbon dioxide, carbon monoxide, oxides of nitrogen, sulfur dioxide, sulfur trioxide, acid dewpoint, particulate mass, size distribution and morphology, chlorides, and opacity. In general, no adverse boiler performance effects were encountered with the combustion of the CDL fuels. The test program demonstrated the general suitability of CDL fuels for use in existing oil-fired utility boilers. No significant boiler tube surface modifications will be required. With the exception of NO/sub x/ emissions, the CDL fuels will be expected to have lower levels of stack emissions compared to a conventional No. 6 fuel oil. NO/sub x/ emissions will be controllable to EPA standards with the application of conventional combustion modification techniques. Volume 1, of a five-volume report, contains a comprehensive report of the entire test program. 43 figs., 19 tabs.

  20. Black liquor combustion validated recovery boiler modeling, five-year report

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1996-08-01T23:59:59.000Z

    The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

  1. To connect to Boiler Television, you will need to provide a coaxial cable to connect your television set to the cable wall outlet. In connecting the coaxial

    E-Print Network [OSTI]

    Ginzel, Matthew

    To connect to Boiler Television, you will need to provide a coaxial cable to connect your? By providing this initial information, you help Boiler Television staff assess and resolve this issue as soon for use with any University Residences work request -- not just for the Boiler Television system. Set

  2. IEEE TRANSACTIONS ON CONTROL SYSTEMS TECHNOLOGY, VOL. 10, NO. 5, SEPTEMBER 2002 735 Multivariable Robust Controller Design for a Boiler System

    E-Print Network [OSTI]

    Marquez, Horacio J.

    Robust Controller Design for a Boiler System Wen Tan, Horacio J. Marquez, and Tongwen Chen Abstract--In an industrial boiler system, multiloop (decen- tralized) proportional-integral (PI) control is used because and performance of the overall system. In particular, under normal boiler operating conditions, we de- sign

  3. 202 IEEE TRANS.4CTIONS Oh'AUTOMATIC CONTROL, VOL. AC-18,NO. 3, J U K E 1973 Design and Analysis of Boiler-Turbine-Generator

    E-Print Network [OSTI]

    Kwatny, Harry G.

    of Boiler-Turbine-Generator Controls Using Optimal Linear Regulator Theory JOHN P. McDOKALD AND HARRY G of a nonlinear mathematical model of a drum-type, twin furnace, reheat boiler-turbine-generator (RBTG) system- tiveoperatingandcontrolstrategies for boiler-t.urbine- generator systems to meet different, system operating ob- jectives. Among

  4. Conversion of a black liquor recovery boiler to wood firing: A case history

    SciTech Connect (OSTI)

    Eleniewski, M.A. [Detroit Stoker Company, Monroe, MI (United States)

    1994-12-31T23:59:59.000Z

    In 1983 a large integrated pulp and paper mill in southeastern United States retired an older chemical recovery boiler when it was replaced by a newer and larger unit as part of a mill expansion. At that time the mill was generating steam and power using wood waste, natural gas and black liquor, a common fuel mix for pulp mills. The retirement of the recovery boiler presented an opportunity for the mill and corporate engineering to evaluate various mixes of fuels for the mill.

  5. Laser-induced breakdown spectroscopy at high temperatures in industrial boilers and furnaces.

    SciTech Connect (OSTI)

    Walsh, Peter M. (University of Alabama at Birmingham and Southern Research Institute, Birmingham, AL); Shaddix, Christopher R.; Sickafoose, Shane M.; Blevins, Linda Gail

    2003-02-01T23:59:59.000Z

    Laser-induced breakdown spectroscopy (LIBS) was applied (1) near the superheater of an electric power generation boiler burning biomass, coat, or both, (2) at the exit of a glass-melting furnace burning natural gas and oxygen, and (3) near the nose arches of two paper mill recovery boilers burning black liquor. Difficulties associated with the high temperatures and high particle loadings in these environments were surmounted by use of novel LIBS probes. Echelle and linear spectrometers coupled to intensified CCD cameras were used individually and sometimes simultaneously. Elements detected include Na, K, Ca, Mg, C, B, Si, Mn, Al, Fe, Rb, Cl, and Ti.

  6. Materials, Turbomachinery and Heat Exchangers for Supercritical CO2 Systems

    SciTech Connect (OSTI)

    Mark Anderson; Greg Nellis; Michael Corradini

    2012-10-19T23:59:59.000Z

    The objective of this project is to produce the necessary data to evaluate the performance of the supercritical carbon dioxide cycle. The activities include a study of materials compatibility of various alloys at high temperatures, the heat transfer and pressure drop in compact heat exchanger units, and turbomachinery issues, primarily leakage rates through dynamic seals. This experimental work will serve as a test bed for model development and design calculations, and will help define further tests necessary to develop high-efficiency power conversion cycles for use on a variety of reactor designs, including the sodium fast reactor (SFR) and very high-temperature gas reactor (VHTR). The research will be broken into three separate tasks. The first task deals with the analysis of materials related to the high-temperature S-CO{sub 2} Brayton cycle. The most taxing materials issues with regard to the cycle are associated with the high temperatures in the reactor side heat exchanger and in the high-temperature turbine. The system could experience pressures as high as 20MPa and temperatures as high as 650°C. The second task deals with optimization of the heat exchangers required by the S-CO{sub 2} cycle; the S-CO{sub 2} flow passages in these heat exchangers are required whether the cycle is coupled with a VHTR or an SFR. At least three heat exchangers will be required: the pre-cooler before compression, the recuperator, and the heat exchanger that interfaces with the reactor coolant. Each of these heat exchangers is unique and must be optimized separately. The most challenging heat exchanger is likely the pre-cooler, as there is only about a 40°C temperature change but it operates close to the CO{sub 2} critical point, therefore inducing substantial changes in properties. The proposed research will focus on this most challenging component. The third task examines seal leakage through various dynamic seal designs under the conditions expected in the S-CO{sub 2} cycle, including supercritical, choked, and two-phase flow conditions.

  7. CO{sub 2}-based supercritical fluids as environmentally-friendly processing solvents

    SciTech Connect (OSTI)

    Rubin, J.B.; Davenhall, L.B.; Taylor, C.M.V.; Pierce, T. [Los Alamos National Lab., NM (United States). Physical Organic Chemistry Group; Tiefert, K. [Hewlett-Packard Co., Inc., Santa Clara, CA (United States)

    1999-03-01T23:59:59.000Z

    The production of integrated circuits involves a number of discrete steps that utilize hazardous or regulated solvents. Environmental, safety and health considerations associated with these chemicals have prompted a search for alternative, more environmentally benign, solvent systems. An emerging technology for conventional solvent replacement is the use of supercritical fluids based on carbon dioxide (CO{sub 2}). Supercritical CO{sub 2} (SCCO{sub 2}) is an excellent choice for IC manufacturing processes since it is non-toxic, non-flammable, inexpensive, and is compatible with all substrate and metallizations systems. Also, conditions of temperature and pressure needed to achieve the supercritical state are easily achievable with existing process equipment. The authors first describe the general properties of supercritical fluids, with particular emphasis on their application as alternative solvents. Next, they review some of the work which has been published involving the use of supercritical fluids, and particularly CO{sub 2}, as they may be applied to the various steps of IC manufacture, including wafer cleaning, thin film deposition, etching, photoresist stripping, and waste treatment. Next, they describe the research work conducted at Los Alamos, on behalf of Hewlett-Packard, on the use of SCCO{sub 2} in a specific step of the IC manufacturing process: the stripping of hard-baked photoresist.

  8. Ultra-wideband directional sampler

    DOE Patents [OSTI]

    McEwan, Thomas E. (Livermore, CA)

    1996-01-01T23:59:59.000Z

    The Ultra-Wideband (UWB) Directional Sampler is a four port device that combines the function of a directional coupler with a high speed sampler. Two of the four ports operate at a high sub-nanosecond speed, in "real time", and the other two ports operate at a slow millisecond-speed, in "equivalent time". A signal flowing inbound to either of the high speed ports is sampled and coupled, in equivalent time, to the adjacent equivalent time port while being isolated from the opposite equivalent time port. A primary application is for a time domain reflectometry (TDR) situation where the reflected pulse returns while the outbound pulse is still being transmitted, such as when the reflecting discontinuity is very close to the TDR apparatus.

  9. Ultra-wideband directional sampler

    DOE Patents [OSTI]

    McEwan, T.E.

    1996-05-14T23:59:59.000Z

    The Ultra-Wideband (UWB) Directional Sampler is a four port device that combines the function of a directional coupler with a high speed sampler. Two of the four ports operate at a high sub-nanosecond speed, in ``real time``, and the other two ports operate at a slow millisecond-speed, in ``equivalent time``. A signal flowing inbound to either of the high speed ports is sampled and coupled, in equivalent time, to the adjacent equivalent time port while being isolated from the opposite equivalent time port. A primary application is for a time domain reflectometry (TDR) situation where the reflected pulse returns while the outbound pulse is still being transmitted, such as when the reflecting discontinuity is very close to the TDR apparatus. 3 figs.

  10. Supercritical Fluid Extraction and Separation of Uranium from Other Actinides

    SciTech Connect (OSTI)

    Donna L. Quach; Bruce J. Mincher; Chien M. Wai

    2014-06-01T23:59:59.000Z

    This paper investigates the feasibility of separating uranium from other actinides by using supercritical fluid carbon dioxide (sc-CO2) as a solvent modified with tri-n-butylphosphate (TBP) for the development of an extraction and counter current stripping technique, which would be a more efficient and environmentally benign technology for used nuclear fuel reprocessing compared to traditional solvent extraction. Several actinides (U(VI), Np(VI), Pu(IV), and Am(III)) were extracted in sc-CO2 modified with TBP over a range of nitric acid concentrations and then the actinides were exposed to reducing and complexing agents to suppress their extractability. According to this study, the separation of uranium from plutonium in sc-CO2 modified with TBP was successful at nitric acid concentrations of less than 3 M in the presence of acetohydroxamic acid or oxalic acid, and the separation of uranium from neptunium was successful at nitric acid concentrations of less than 1 M in the presence of acetohydroxamic acid, oxalic acid, or sodium nitrite.

  11. Topping PCFB combustion plant with supercritical steam pressure

    SciTech Connect (OSTI)

    Robertson, A. [Foster Wheeler Development Corp., Livingston, NJ (United States); White, J. [Parsons Power Group Inc., Reading, PA (United States)

    1997-11-01T23:59:59.000Z

    Research is being conducted to develop a new type of coal fired plant for electric power generation. This new type of plant, called a second generation or topping pressurized circulating fluidized bed combustion (topping PCFB) plant, offers the promise of efficiencies greater than 46 percent (HHV), with both emissions and a cost of electricity that are significantly lower than conventional pulverized coal fired plants with scrubbers. The topping PCFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized bed combustor (PCFB), and the combustion of carbonizer fuel gas in a topping combustor to achieve gas turbine inlet temperatures of 2,300 F and higher. After completing pilot plant tests of a carbonizer, a PCFB, and a gas turbine topping combustor, all being developed for this new plant, the authors calculated a higher heating value efficiency of 46.2 percent for the plant. In that analysis, the plant operated with a conventional 2,400 psig steam cycle with 1,000 F superheat and reheat steam and a 2.5 inch mercury condenser back pressure. This paper identifies the efficiency gains that this plant will achieve by using supercritical pressure steam conditions.

  12. Compliance testing of Grissom AFB Central Heating Plant coal-fired boilers 3, 4, and 5, Grissom AFB, Indiana. Final report, 29 January-15 February 1989

    SciTech Connect (OSTI)

    Garrison, J.A.

    1989-06-01T23:59:59.000Z

    At the request of HQ, SAC/SGPB source compliance testing (particulate and visible emissions) of boilers 3, 4, and 5 in the Grissom AFB Central Heating Plant was accomplished 29 Jan-15 Feb 89. The survey was conducted to determine compliance with regards to Indiana Administrative Code, Title 325 - Air Pollution Control Board, Article 5, Opacity Regulations, and Article 6, Particulate Regulations. Boiler 3 was tested through scrubber B, Boiler 4 through scrubber A, and Boiler 5 through scrubber B and the bypass stack. Results indicate that each boiler met applicable visible and particulate emission standards.

  13. National Emission Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers; Guidance for Calculating Emission Credits Resulting from Implementation of Energy Conservation Measures

    SciTech Connect (OSTI)

    Cox, Daryl [ORNL; Papar, Riyaz [Hudson Technologies; Wright, Dr. Anthony [ALW Consulting

    2012-07-01T23:59:59.000Z

    The purpose of this document is to provide guidance for developing a consistent approach to documenting efficiency credits generated from energy conservation measures in the Implementation Plan for boilers covered by the Boiler MACT rule (i.e., subpart DDDDD of CFR part 63). This document divides Boiler System conservation opportunities into four functional areas: 1) the boiler itself, 2) the condensate recovery system, 3) the distribution system, and 4) the end uses of the steam. This document provides technical information for documenting emissions credits proposed in the Implementation Plan for functional areas 2) though 4). This document does not include efficiency improvements related to the Boiler tune-ups.

  14. National Emission Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers; Guidance for Calculating Efficiency Credits Resulting from Implementation of Energy Conservation Measures

    SciTech Connect (OSTI)

    Cox, Daryl [ORNL; Papar, Riyaz [Hudson Technologies; Wright, Dr. Anthony [ALW Consulting

    2013-02-01T23:59:59.000Z

    The purpose of this document is to provide guidance for developing a consistent approach to documenting efficiency credits generated from energy conservation measures in the Implementation Plan for boilers covered by the Boiler MACT rule (i.e., subpart DDDDD of CFR part 63). This document divides Boiler System conservation opportunities into four functional areas: 1) the boiler itself, 2) the condensate recovery system, 3) the distribution system, and 4) the end uses of the steam. This document provides technical information for documenting emissions credits proposed in the Implementation Plan for functional areas 2) though 4). This document does not include efficiency improvements related to the Boiler tune-ups.

  15. The effects of sliding pressure operation on utility boiler tube integrity

    SciTech Connect (OSTI)

    Dewitt-Dick, D.B.; Wangerin, M.C. [Ashland Chemical Co., Boonton, NJ (United States). Ashland Chemical Co.

    1996-08-01T23:59:59.000Z

    Sliding pressure operation is employed by utilities to optimize efficiency during periods of reduced load demand. However, this mode of operation can lead to a deterioration in boiler tube integrity. The various mechanisms involved and their effects on tube integrity are discussed. Case histories are also provided, which illustrate these phenomena.

  16. Building America Case Study: Boiler Control Replacement for Hydronically Heated Multifamily Buildings, Cambridge, Massachusetts (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-11-01T23:59:59.000Z

    The ARIES Collaborative, a U.S. Department of Energy Building America research team, partnered with NeighborWorks America affiliate Homeowners' Rehab Inc. (HRI) of Cambridge, Massachusetts, to study improvements to the central hydronic heating system in one of the nonprofit's housing developments. The heating controls in the three-building, 42-unit Columbia Cambridge Alliance for Spanish Tenants housing development were upgraded. Fuel use in the development was excessive compared to similar properties. A poorly insulated thermal envelope contributed to high energy bills, but adding wall insulation was not cost-effective or practical. The more cost-effective option was improving heating system efficiency. Efficient operation of the heating system faced several obstacles, including inflexible boiler controls and failed thermostatic radiator valves. Boiler controls were replaced with systems that offer temperature setbacks and one that controls heat based on apartment temperature in addition to outdoor temperature. Utility bill analysis shows that post-retrofit weather-normalized heating energy use was reduced by 10%-31% (average of 19%). Indoor temperature cutoff reduced boiler runtime (and therefore heating fuel consumption) by 28% in the one building in which it was implemented. Nearly all savings were obtained during night which had a lower indoor temperature cut off (68 degrees F) than day (73 degrees F). This implies that the outdoor reset curve was appropriately adjusted for this building for daytime operation. Nighttime setback of heating system supply water temperature had no discernable impact on boiler runtime or gas bills.

  17. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 4 (Appendix IV)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 4 contains the following appendix sections: Radiative heat transfer properties for black liquor combustion -- Facilities and techniques and Spectral absorbance and emittance data; and Radiate heat transfer determination of the optical constants of ash samples from kraft recovery boilers -- Calculation procedure; Computation program; Density determination; Particle diameter determination; Optical constant data; and Uncertainty analysis.

  18. Method of prevention of deposits in the pipes of waste heat boilers

    SciTech Connect (OSTI)

    Gettert, H.; Kaempfer, K.

    1983-12-13T23:59:59.000Z

    A process is disclosed for preventing deposits in the pipes of waste heat boilers employed for cooling gases in the partial autothermal oxidation of fossil fuels to prepare hydrogen or synthesis gases, wherein the pipes are flushed, at the operating temperature, with hydrogen-containing gases which contain little or no H/sub 2/S.

  19. Fuel Cost Savings Through Computer Control of a Boiler Complex - - Two Case Histories

    E-Print Network [OSTI]

    Worthley, C. M.

    1979-01-01T23:59:59.000Z

    large pulp and paper mill complex in which multiple power boilers and turbine generators are controlled so as to meet the total energy demand of the mill at minimum cost. Also discussed are results from a second installation involving control of a...

  20. Influence of combustion parameters on NOx production in an industrial boiler

    E-Print Network [OSTI]

    Aldajani, Mansour A.

    Influence of combustion parameters on NOx production in an industrial boiler M.A. Habib a,*, M; accepted 14 April 2007 Available online 24 June 2007 Abstract NOx formation during the combustion process occurs mainly through the oxidation of nitrogen in the combustion air (thermal NOx) and through oxidation

  1. Particulate emission abatement for Krakow boiler houses. Quarterly technical report, October 1, 1996--December 31, 1996

    SciTech Connect (OSTI)

    Wysk, S.R.

    1997-01-01T23:59:59.000Z

    This project involves the implementation of a new particulate control technology called a ``Core Separator`` for low emission sources (LES) in Krakow. With several hundred boiler sites in the city burning low grade coal, existing pollution control equipment consists primarily of low efficiency cyclones. Such equipment cannot meet the emission standards of most industrial nations. More importantly, these conditions have been the cause of low ambient air quality in Krakow from suspended particles. The Core Separator can be retrofitted onto these boiler houses to substantially reduce particulate emissions, particularly those consisting of the fraction classified as PM10. In this project, Core Separator technology will be demonstrated for boiler house applications in the Krakow region. Phase I entailed business planning and infrastructure studies to determine the market for this equipment. In the second phase, the technology is to be demonstrated in several boilers of different capacity and firing various grades of coal. Later, a joint venture company was to be established with capability of manufacturing and supplying this equipment in Krakow and throughout Poland.

  2. Development of Cost Effective Oxy-Combustion Retrofitting for Coal-Fired Boilers

    SciTech Connect (OSTI)

    Hamid Farzan

    2010-12-31T23:59:59.000Z

    The overall objective of this project is to further develop the oxy-combustion technology for commercial retrofit in existing wall-fired and Cyclone boilers by 2012. To meet this goal, a research project was conducted that included pilot-scale testing and a full-scale engineering and economic analysis.

  3. Predictive control and thermal energy storage for optimizing a multi-energy district boiler

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and used when demand is high, instead of engaging the gas-fuel oil boiler. Keywords: multi-energy district believe that by 2015 the supply of oil and natural gas will be unable to keep up with demand [1 of La Rochelle (France) adding to the plant a controlled thermal storage tank. This plant supplies

  4. Hydronic Heating Retrofits for Low-Rise Multifamily Buildings: Boiler Control Replacement and Monitoring

    SciTech Connect (OSTI)

    Dentz, J.; Henderson, H.; Varshney, K.

    2014-09-01T23:59:59.000Z

    The ARIES Collaborative, a U.S. Department of Energy Building America research team, partnered with NeighborWorks America affiliate Homeowners' Rehab Inc. (HRI) of Cambridge, Massachusetts, to study improvements to the central hydronic heating system in one of the nonprofit's housing developments. The heating controls in the three-building, 42-unit Columbia Cambridge Alliance for Spanish Tenants housing development were upgraded. Fuel use in the development was excessive compared to similar properties. A poorly insulated thermal envelope contributed to high energy bills, but adding wall insulation was not cost-effective or practical. The more cost-effective option was improving heating system efficiency. Efficient operation of the heating system faced several obstacles, including inflexible boiler controls and failed thermostatic radiator valves. Boiler controls were replaced with systems that offer temperature setbacks and one that controls heat based on apartment temperature in addition to outdoor temperature. Utility bill analysis shows that post-retrofit weather-normalized heating energy use was reduced by 10%-31% (average of 19%). Indoor temperature cutoff reduced boiler runtime (and therefore heating fuel consumption) by 28% in the one building in which it was implemented. Nearly all savings were obtained during night which had a lower indoor temperature cut off (68 degrees F) than day (73 degrees F). This implies that the outdoor reset curve was appropriately adjusted for this building for daytime operation. Nighttime setback of heating system supply water temperature had no discernable impact on boiler runtime or gas bills.

  5. Model of penetration of coal boilers and cogeneration in the paper industry

    SciTech Connect (OSTI)

    Reister, D.B.

    1982-01-01T23:59:59.000Z

    A model has been developed to forecast the penetration of coal boilers and cogeneration of electricity in the paper industry. Given the demand for energy services (process steam and electricity) by the paper industry, the Penetration Model forecasts the demand for purchased fuel and electricity. The model splits the demand for energy service between energy carriers (coal, fuel oil/natural gas, bark, and spent liquor) on the basis of the installed capacity of 16 types of boilers (combinations of four types of energy carriers and four types of throttle conditions). Investment in new boilers is allocated by an empirical distribution function among the 16 types of boilers on the basis of life cycle cost. In the short run (5 years), the Penetration Model has a small price response. The model has a large price response in the long run (30 years). For constant fuel prices, the model forecasts a 19-percent share for coal and a 65-percent share for residual oil in the year 2000. If the real price of oil and gas doubles by the year 2000, the model forecasts a 68-percent share for coal and a 26-percent share for residual oil.

  6. Extraction of Uranium from Aqueous Solutions Using Ionic Liquid and Supercritical Carbon Dioxide in Conjunction

    SciTech Connect (OSTI)

    Wang, Joanna S.; Sheaff, Chrystal N.; Yoon, Byunghoon; Addleman, Raymond S.; Wai, Chien M.

    2009-01-01T23:59:59.000Z

    Uranyl ions (UO2)2+ in aqueous nitric acid solutions can be extracted into supercritical CO2 (sc-CO2) via an imidazolium-based ionic liquid using tri-n-butylphosphate (TBP) as a complexing agent. The transfer of uranium from the ionic liquid to the supercritical fluid phase was monitored by UV/Vis spectroscopy using a high-pressure fiberoptic cell. The form of the uranyl complex extracted into the supercritical CO2 phase was found to be UO2(NO3)2(TBP)2. The extraction results were confirmed by UV/Vis spectroscopy and by neutron activation analysis. This technique could potentially be used to extract other actinides for applications in the field of nuclear waste management.

  7. Supercritical Fluid Immersion Deposition: A New Process for Selective Deposition of Metal Films on Silicon Substrates

    SciTech Connect (OSTI)

    Ye, Xiangrong; Wai, Chien M.; Lin, Yuehe; Young, James S.; Engelhard, Mark H.

    2005-01-01T23:59:59.000Z

    Supercritical CO2 is used as a new solvent for immersion deposition, a galvanic displacement process traditionally carried out in aqueous HF solutions containing metal ions, to selectively develop metal films on featured or non-featured silicon substrates. Components of supercritical fluid immersion deposition (SFID) solutions for fabricating Cu and Pd films on silicon substrates are described along with the corresponding experimental setup and procedure. Only silicon substrates exposed and reactive to SFID solutions can be coated. The highly pressurized and gas-like supercritical CO2, combined with the galvanic displacement property of immersion deposition, enables the SFID technique to selectively deposit metal films in small features. SFID may also provide a new method to fabricate palladium silicide in small features or to metallize porous silicon.

  8. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Lin, Yuehe (Moscow, ID)

    1998-01-01T23:59:59.000Z

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent is described. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  9. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Lin, Y.

    1998-06-23T23:59:59.000Z

    A method is described for extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

  10. Method for separating metal chelates from other materials based on solubilities in supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Workington, GB); Phelps, Cindy (Moscow, ID)

    2001-01-01T23:59:59.000Z

    A method for separating a desired metal or metalloi from impurities using a supercritical extraction process based on solubility differences between the components, as well as the ability to vary the solvent power of the supercritical fluid, is described. The use of adduct-forming agents, such as phosphorous-containing ligands, to separate metal or metalloid chelates in such processes is further disclosed. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones; phosphine oxides, such as trialkylphosphine oxides, triarylphosphine oxides and alkylarylphosphine oxides; phosphinic acids; carboxylic acids; phosphates, such as trialkylphosphates, triarylphosphates and alkylarylphosphates; crown ethers; dithiocarbamates; phosphine sulfides; phosphorothioic acids; thiophosphinic acids; halogenated analogs of these chelating agents; and mixtures of these chelating agents. In especially preferred embodiments, at least one of the chelating agents is fluorinated.

  11. Method and apparatus for dissociating metals from metal compounds extracted into supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Hunt, Fred H. (Moscow, ID); Smart, Neil G. (Workington, GB); Lin, Yuehe (Richland, WA)

    2000-01-01T23:59:59.000Z

    A method for dissociating metal-ligand complexes in a supercritical fluid by treating the metal-ligand complex with heat and/or reducing or oxidizing agents is described. Once the metal-ligand complex is dissociated, the resulting metal and/or metal oxide form fine particles of substantially uniform size. In preferred embodiments, the solvent is supercritical carbon dioxide and the ligand is a .beta.-diketone such as hexafluoroacetylacetone or dibutyldiacetate. In other preferred embodiments, the metals in the metal-ligand complex are copper, silver, gold, tungsten, titanium, tantalum, tin, or mixtures thereof. In preferred embodiments, the reducing agent is hydrogen. The method provides an efficient process for dissociating metal-ligand complexes and produces easily-collected metal particles free from hydrocarbon solvent impurities. The ligand and the supercritical fluid can be regenerated to provide an economic, efficient process.

  12. Supercritical fluid thermodynamics for coal processing. Final report, September 15, 1988--September 14, 1991

    SciTech Connect (OSTI)

    van Swol, F. [Illinois Univ., Urbana, IL (United States). Dept. of Chemical Engineering; Eckert, C.A. [Georgia Inst. of Tech., Atlanta, GA (United States). School of Chemical Engineering

    1988-09-15T23:59:59.000Z

    The main objective of this research is to develop an equation of state that can be used to predict solubilities and tailor supercritical fluid solvents for the extraction and processing of coal. To meet this objective we have implemented a two-sided. approach. First, we expanded the database of model coal compound solubilities in higher temperature fluids, polar fluids, and fluid mixtures systems. Second, the unique solute/solute, solute/cosolvent and solute/solvent intermolecular interactions in supercritical fluid solutions were investigated using spectroscopic techniques. These results increased our understanding of the molecular phenomena that affect solubility in supercritical fluids and were significant in the development of an equation of state that accurately reflects the true molecular makeup of the solution. (VC)

  13. ULTRA BARRIER TOPSHEET (UBT) FOR FLEXIBLE PHOTOVOLTAICS

    SciTech Connect (OSTI)

    DeScioli, Derek

    2013-06-01T23:59:59.000Z

    This slide-show presents 3M photovoltaic-related products, particularly flexible components. Emphasis is on the 3M Ultra Barrier Solar Films. Topics covered include reliability and qualification testing and flexible photovoltaic encapsulation costs.

  14. Ultra wide-bandwidth micro energy harvester

    E-Print Network [OSTI]

    Hajati, Arman

    2011-01-01T23:59:59.000Z

    An ultra wide-bandwidth resonating thin film PZT MEMS energy harvester has been designed, modeled, fabricated and tested. It harvests energy from parasitic ambient vibration at a wide range of amplitude and frequency via ...

  15. Ultra-wide bandwidth piezoelectric energy harvesting

    E-Print Network [OSTI]

    Hajati, Arman

    Here, we present an ultra wide-bandwidth energy harvester by exploiting the nonlinear stiffness of a doubly clamped microelectromechanical systems (MEMSs) resonator. The stretching strain in a doubly clamped beam shows a ...

  16. ULTRA BARRIER TOPSHEET (UBT) FOR FLEXIBLE PHOTOVOLTAICS

    SciTech Connect (OSTI)

    Alan, Nachtigal; Berniard, Tracie; Murray, Bill; Roehrig, Mark; Schubert, Charlene; Spagnola, Joseph; Weigel, Mark

    2013-01-01T23:59:59.000Z

    This poster describes the 3M Ultra-Barrier Solar Film and its application; production scale-up and data; reliability and qualification testing; and improvements in the next generation.

  17. EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2

    SciTech Connect (OSTI)

    Earl D. Mattson; Travis L. McLing; William Smith; Carl Palmer

    2013-02-01T23:59:59.000Z

    EGS using CO2 as a working fluid will likely involve hydro-shearing low-permeability hot rock reservoirs with a water solution. After that process, the fractures will be flushed with CO2 that is maintained under supercritical conditions (> 70 bars). Much of the injected water in the main fracture will be flushed out with the initial CO2 injection; however side fractures, micro fractures, and the lower portion of the fracture will contain connate water that will interact with the rock and the injected CO2. Dissolution/precipitation reactions in the resulting scCO2/brine/rock systems have the potential to significantly alter reservoir permeability, so it is important to understand where these precipitates form and how are they related to the evolving ‘free’ connate water in the system. To examine dissolution / precipitation behavior in such systems over time, we have conducted non-stirred batch experiments in the laboratory with pure minerals, sandstone, and basalt coupons with brine solution spiked with MnCl2 and scCO2. The coupons are exposed to liquid water saturated with scCO2 and extend above the water surface allowing the upper portion of the coupons to be exposed to scCO2 saturated with water. The coupons were subsequently analyzed using SEM to determine the location of reactions in both in and out of the liquid water. Results of these will be summarized with regard to significance for EGS with CO2 as a working fluid.

  18. Scaling considerations for a multi-megawatt class supercritical CO2 brayton cycle and commercialization.

    SciTech Connect (OSTI)

    Fleming, Darryn D.; Holschuh, Thomas Vernon,; Conboy, Thomas M.; Pasch, James Jay; Wright, Steven Alan; Rochau, Gary Eugene; Fuller, Robert Lynn [Barber-Nichols, Inc., Arvada, CO

    2013-11-01T23:59:59.000Z

    Small-scale supercritical CO2 demonstration loops are successful at identifying the important technical issues that one must face in order to scale up to larger power levels. The Sandia National Laboratories supercritical CO2 Brayton cycle test loops are identifying technical needs to scale the technology to commercial power levels such as 10 MWe. The small size of the Sandia 1 MWth loop has demonstration of the split flow loop efficiency and effectiveness of the Printed Circuit Heat Exchangers (PCHXs) leading to the design of a fully recuperated, split flow, supercritical CO2 Brayton cycle demonstration system. However, there were many problems that were encountered, such as high rotational speeds in the units. Additionally, the turbomachinery in the test loops need to identify issues concerning the bearings, seals, thermal boundaries, and motor controller problems in order to be proved a reliable power source in the 300 kWe range. Although these issues were anticipated in smaller demonstration units, commercially scaled hardware would eliminate these problems caused by high rotational speeds at small scale. The economic viability and development of the future scalable 10 MWe solely depends on the interest of DOE and private industry. The Intellectual Property collected by Sandia proves that the ~10 MWe supercritical CO2 power conversion loop to be very beneficial when coupled to a 20 MWth heat source (either solar, geothermal, fossil, or nuclear). This paper will identify a commercialization plan, as well as, a roadmap from the simple 1 MWth supercritical CO2 development loop to a power producing 10 MWe supercritical CO2 Brayton loop.

  19. Predictive modelling of boiler fouling. Quarterly technical progress report, January 1, 1992--March 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-01T23:59:59.000Z

    In this reporting period, efforts were initiated to supplement the comprehensive flow field description obtained from the RNG-Spectral Element Simulations by incorporating, in a general framework, appropriate modules to model particle and condensable species transport to the surface. Specifically, a brief survey of the literature revealed the following possible mechanisms for transporting different ash constituents from the host gas to boiler tubes as deserving prominence in building the overall comprehensive model: (1) Flame-volatilized species, chiefly sulfates, are deposited on cooled boiler tubes via the mechanism of classical vapor diffusion. This mechanism is more efficient than the particulate ash deposition, and as a result there is usually an enrichment of condensable salts, chiefly sulfates, in boiler deposits; (2) Particle diffusion (Brownian motion) may account for deposition of some fine particles below 0. 1 mm in diameter in comparison with the mechanism of vapor diffusion and particle depositions, however, the amount of material transported to the tubes via this route is probably small. (3) Eddy diffusion, thermophoretic and electrophoretic deposition mechanisms are likely to have a marked influence in transporting 0.1 to 5{mu}m particles from the host gas to cooled boiler tubes; (4) Inertial impaction is the dominant mechanism in transporting particles above 5{mu}m in diameter to water and steam tubes in pulverized coal fired boiler, where the typical flue gas velocity is between 10 to 25 m/s. Particles above 10{mu}m usually have kinetic energies in excess of what can be dissipated at impact (in the absence of molten sulfate or viscous slag deposit), resulting in their entrainment in the host gas.

  20. A strange weak value in spontaneous pair productions via a supercritical step potential

    E-Print Network [OSTI]

    Kazuhiro Yokota; Nobuyuki Imoto

    2012-08-24T23:59:59.000Z

    We consider a case where a weak value is introduced as a physical quantity rather than an average of weak measurements. The case we treat is a time evolution of a particle by 1+1 dimensional Dirac equation. Particularly in a spontaneous pair production via a supercritical step potential, a quantitative explanation can be given by a weak value for the group velocity of the particle. We also show the condition for the pair production (supercriticality) corresponds to the condition when the weak value takes a strange value (superluminal velocity).

  1. General features of direct-cycle, supercritical-pressure, light-water-cooled reactors

    SciTech Connect (OSTI)

    Oka, Y.; Koshizuka, S. [Univ. of Tokyo (Japan). Nuclear Engineering Research Lab.

    1996-07-01T23:59:59.000Z

    The concept of direct-cycle, supercritical-pressure, light-water-cooled reactors is developed. Breeding is possible in the tight lattice core. The power output can be maximized in the fast converter reactor. The gross thermal efficiency of the high temperature reactor adopting Inconel as fuel cladding is expected to be 44.8%. The plant system is similar to the supercritical-fossil-fired power plant which adopts once-through type coolant circulation system. The volume and height of the containment are approximately half of the BWR. The basic safety principles follows those of LWRs. The reactor will solve the economic problems of LWR and LMFBR.

  2. Performance improvement options for the supercritical carbon dioxide brayton cycle.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. J.; Nuclear Engineering Division

    2008-07-17T23:59:59.000Z

    The supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle is under development at Argonne National Laboratory as an advanced power conversion technology for Sodium-Cooled Fast Reactors (SFRs) as well as other Generation IV advanced reactors as an alternative to the traditional Rankine steam cycle. For SFRs, the S-CO{sub 2} Brayton cycle eliminates the need to consider sodium-water reactions in the licensing and safety evaluation, reduces the capital cost of the SFR plant, and increases the SFR plant efficiency. Even though the S-CO{sub 2} cycle has been under development for some time and optimal sets of operating parameters have been determined, those earlier development and optimization studies have largely been directed at applications to other systems such as gas-cooled reactors which have higher operating temperatures than SFRs. In addition, little analysis has been carried out to investigate cycle configurations deviating from the selected 'recompression' S-CO{sub 2} cycle configuration. In this work, several possible ways to improve S-CO{sub 2} cycle performance for SFR applications have been identified and analyzed. One set of options incorporates optimization approaches investigated previously, such as variations in the maximum and minimum cycle pressure and minimum cycle temperature, as well as a tradeoff between the component sizes and the cycle performance. In addition, the present investigation also covers options which have received little or no attention in the previous studies. Specific options include a 'multiple-recompression' cycle configuration, intercooling and reheating, as well as liquid-phase CO{sub 2} compression (pumping) either by CO{sub 2} condensation or by a direct transition from the supercritical to the liquid phase. Some of the options considered did not improve the cycle efficiency as could be anticipated beforehand. Those options include: a double recompression cycle, intercooling between the compressor stages, and reheating between the turbine stages. Analyses carried out as part of the current investigation confirm the possibilities of improving the cycle efficiency that have been identified in previous investigations. The options in this group include: increasing the heat exchanger and turbomachinery sizes, raising of the cycle high end pressure (although the improvement potential of this option is very limited), and optimization of the low end temperature and/or pressure to operate as close to the (pseudo) critical point as possible. Analyses carried out for the present investigation show that significant cycle performance improvement can sometimes be realized if the cycle operates below the critical temperature at its low end. Such operation, however, requires the availability of a heat sink with a temperature lower than 30 C for which applicability of this configuration is dependent upon the climate conditions where the plant is constructed (i.e., potential performance improvements are site specific). Overall, it is shown that the S-CO{sub 2} Brayton cycle efficiency can potentially be increased to 45 %, if a low temperature heat sink is available and incorporation of larger components (e.g.., heat exchangers or turbomachinery) having greater component efficiencies does not significantly increase the overall plant cost.

  3. Selective Extraction of Uranium from Liquid or Supercritical Carbon Dioxide

    SciTech Connect (OSTI)

    Farawila, Anne F.; O'Hara, Matthew J.; Wai, Chien M.; Taylor, Harry Z.; Liao, Yu-Jung

    2012-07-31T23:59:59.000Z

    Current liquid-liquid extraction processes used in recycling irradiated nuclear fuel rely on (1) strong nitric acid to dissolve uranium oxide fuel, and (2) the use of aliphatic hydrocarbons as a diluent in formulating the solvent used to extract uranium. The nitric acid dissolution process is not selective. It dissolves virtually the entire fuel meat which complicates the uranium extraction process. In addition, a solvent washing process is used to remove TBP degradation products, which adds complexity to the recycling plant and increases the overall plant footprint and cost. A liquid or supercritical carbon dioxide (l/sc -CO2) system was designed to mitigate these problems. Indeed, TBP nitric acid complexes are highly soluble in l/sc -CO2 and are capable of extracting uranium directly from UO2, UO3 and U3O8 powders. This eliminates the need for total acid dissolution of the irradiated fuel. Furthermore, since CO2 is easily recycled by evaporation at room temperature and pressure, it eliminates the complex solvent washing process. In this report, we demonstrate: (1) A reprocessing scheme starting with the selective extraction of uranium from solid uranium oxides into a TBP-HNO3 loaded Sc-CO2 phase, (2) Back extraction of uranium into an aqueous phase, and (3) Conversion of recovered purified uranium into uranium oxide. The purified uranium product from step 3 can be disposed of as low level waste, or mixed with enriched uranium for use in a reactor for another fuel cycle. After an introduction on the concept and properties of supercritical fluids, we first report the characterization of the different oxides used for this project. Our extraction system and our online monitoring capability using UV-Vis absorbance spectroscopy directly in sc-CO2 is then presented. Next, the uranium extraction efficiencies and kinetics is demonstrated for different oxides and under different physical and chemical conditions: l/sc -CO2 pressure and temperature, TBP/HNO3 complex used, reductant or complexant used for selectivity, and ionic liquids used as supportive media. To complete the extraction and recovery cycle, we then demonstrate uranium back extraction from the TBP loaded sc-CO2 phase into an aqueous phase and the characterization of the uranium complex formed at the end of this process. Another aspect of this project was to limit proliferation risks by either co-extracting uranium and plutonium, or by leaving plutonium behind by selectively extracting uranium. We report that the former is easily achieved, since plutonium is in the tetravalent or hexavalent oxidation state in the oxidizing environment created by the TBP-nitric acid complex, and is therefore co-extracted. The latter is more challenging, as a reductant or complexant to plutonium has to be used to selectively extract uranium. After undertaking experiments on different reducing or complexing systems (e.g., AcetoHydroxamic Acid (AHA), Fe(II), ascorbic acid), oxalic acid was chosen as it can complex tetravalent actinides (Pu, Np, Th) in the aqueous phase while allowing the extraction of hexavalent uranium in the sc-CO2 phase. Finally, we show results using an alternative media to commonly used aqueous phases: ionic liquids. We show the dissolution of uranium in ionic liquids and its extraction using sc-CO2 with and without the presence of AHA. The possible separation of trivalent actinides from uranium is also demonstrated in ionic liquids using neodymium as a surrogate and diglycolamides as the extractant.

  4. Summary on the depressurization from supercritical pressure conditions

    SciTech Connect (OSTI)

    Anderson, M. [Univ. of Wisconsin Madison, 1500 Engineering Dr., Madison, WI 53706 (United States); Chen, Y. [Dept. of Reactor Engineering, Research and Design, Reactor Thermal-Hydraulic Lab., China Inst. of Atomic Energy, P.O.Box 275 59, 102413 Beijing (China); Ammirable, L. [JRC/Inst. for Energy and Transport (Netherlands); Novog, D. [Dept. of Engineering Physics, McMaster Univ., 1280 Main Street, ON (Canada); Yamada, K. [International Atomic Energy Agency, Vienna International Centre, P.O. Box 100, 1400 Vienna (Austria)

    2012-07-01T23:59:59.000Z

    When a fluid discharges from a high pressure and temperature system, a 'choking' or critical condition occurs, and the flow rate becomes independent of the downstream pressure. During a postulated loss of coolant accident (LOCA) of a water reactor the break flow will be subject to this condition. An accurate estimation of the critical flow rate is important for the evaluation of the reactor safety, because this flow rate controls the loss of coolant inventory and energy from the system, and thus has a significant effect on the accident consequences[1]. In the design of safety systems for a super critical water reactor (SCWR), postulated LOCA transients are particularly important due to the lower coolant inventory compared to a typical PWR for the same power output. This lower coolant inventory would result in a faster transient response of the SCWR, and hence accurate prediction of the critical discharge is mandatory. Under potential two-phase conditions critical flow is dominated by the vapor content or quality of the vapor, which is closely related with the onset of vaporization and the interfacial interaction between phases [2]. This presents a major challenge for the estimation of the flow rate due to the lack of the knowledge of those processes, especially under the conditions of interest for the SCWR. According to the limited data of supercritical fluids, the critical flows at conditions above the pseudo-critical point seem to be fairly stable and consistent with the subcritical homogeneous equilibrium model (HEM) model predictions, while having a lower flow rate than those in the two-phase region. Thus the major difficulty in the prediction of the depressurization flow rates remains in the region where two phases co-exist at the top of the vapor dome. In this region, the flow rate is strongly affected by the nozzle geometry and tends to be unstable. Various models for this region have been developed with different assumptions, e.g. the HEM and Moody model [3], and the Henry-Fauske non-equilibrium model [4], and are currently used in subcritical pressure reactor safety design[5]. It appears that some of these models could be reasonably extended to above the thermodynamic pseudo-critical point. The more stable and lower discharge flow rates observed in conditions above the pseudo-critical point suggests that even though SCWR's have a smaller coolant inventory, the safety implications of a LOCA and the subsequent depressurization may not be as severe as expected, this however needs to be confirmed by a rigorous evaluation of the particular event and further evaluation of the critical flow rate. This paper will summarize activities on critical flow models, experimental data and numerical modeling during blowdown from supercritical pressure conditions under the International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on 'Heat Transfer Behaviour and Thermo-hydraulics Code testing for SCWRs'. (authors)

  5. Design requirements for the supercritical water oxidation test bed

    SciTech Connect (OSTI)

    Svoboda, J.M.; Valentich, D.J.

    1994-05-01T23:59:59.000Z

    This report describes the design requirements for the supercritical water oxidation (SCWO) test bed that will be located at the Idaho National Engineering Laboratory (INEL). The test bed will process a maximum of 50 gph of waste plus the required volume of cooling water. The test bed will evaluate the performance of a number of SCWO reactor designs. The goal of the project is to select a reactor that can be scaled up for use in a full-size waste treatment facility to process US Department of Energy mixed wastes. EG&G Idaho, Inc. will design and construct the SCWO test bed at the Water Reactor Research Test Facility (WRRTF), located in the northern region of the INEL. Private industry partners will develop and provide SCWO reactors to interface with the test bed. A number of reactor designs will be tested, including a transpiring wall, tube, and vessel-type reactor. The initial SCWO reactor evaluated will be a transpiring wall design. This design requirements report identifies parameters needed to proceed with preliminary and final design work for the SCWO test bed. A flow sheet and Process and Instrumentation Diagrams define the overall process and conditions of service and delineate equipment, piping, and instrumentation sizes and configuration Codes and standards that govern the safe engineering and design of systems and guidance that locates and interfaces test bed hardware are provided. Detailed technical requirements are addressed for design of piping, valves, instrumentation and control, vessels, tanks, pumps, electrical systems, and structural steel. The approach for conducting the preliminary and final designs and environmental and quality issues influencing the design are provided.

  6. Corrosion in Supercritical carbon Dioxide: Materials, Environmental Purity, Surface Treatments, and Flow Issues

    SciTech Connect (OSTI)

    Sridharan, Kumar; Anderson, Mark

    2013-12-10T23:59:59.000Z

    The supercritical CO{sub 2} Brayton cycle is gaining importance for power conversion in the Generation IV fast reactor system because of its high conversion efficiencies. When used in conjunction with a sodium fast reactor, the supercritical CO{sub 2} cycle offers additional safety advantages by eliminating potential sodium-water interactions that may occur in a steam cycle. In power conversion systems for Generation IV fast reactors, supercritical CO{sub 2} temperatures could be in the range of 30°C to 650°C, depending on the specific component in the system. Materials corrosion primarily at high temperatures will be an important issue. Therefore, the corrosion performance limits for materials at various temperatures must be established. The proposed research will have four objectives centered on addressing corrosion issues in a high-temperature supercritical CO{sub 2} environment: Task 1: Evaluation of corrosion performance of candidate alloys in high-purity supercritical CO{sub 2}: The following alloys will be tested: Ferritic-martensitic Steels NF616 and HCM12A, austenitic alloys Incoloy 800H and 347 stainless steel, and two advanced concept alloys, AFA (alumina forming austenitic) steel and MA754. Supercritical CO{sub 2} testing will be performed at 450°C, 550°C, and 650°C at a pressure of 20 MPa, in a test facility that is already in place at the proposing university. High purity CO{sub 2} (99.9998%) will be used for these tests. Task 2: Investigation of the effects of CO, H{sub 2}O, and O{sub 2} impurities in supercritical CO{sub 2} on corrosion: Impurities that will inevitably present in the CO{sub 2} will play a critical role in dictating the extent of corrosion and corrosion mechanisms. These effects must be understood to identify the level of CO{sub 2} chemistry control needed to maintain sufficient levels of purity to manage corrosion. The individual effects of important impurities CO, H{sub 2}O, and O{sub 2} will be investigated by adding them separately to high purity CO{sub 2}. Task 3: Evaluation of surface treatments on the corrosion performance of alloys in supercritical CO{sub 2}: Surface treatments can be very beneficial in improving corrosion resistance. Shot peening and yttrium and aluminum surface treatments will be investigated. Shot peening refines the surface grain sizes and promotes protective Cr-oxide layer formation. Both yttrium and aluminum form highly stable oxide layers (Y{sub 2}O{sub 3} and Al{sub 2}O{sub 3}), which can get incorporated in the growing Fe-oxide layer to form an impervious complex oxide to enhance corrosion resistance. Task 4: Study of flow-assisted corrosion of select alloys in supercritical CO{sub 2} under a selected set of test conditions: To study the effects of flow-assisted corrosion, tests will be conducted in a supercritical CO{sub 2} flow loop. An existing facility used for supercritical water flow studies at the proposing university will be modified for use in this task. The system is capable of flow velocities up to 10 m/s and can operate at temperatures and pressures of up to 650°C and 20 MPa, respectively. All above tasks will be performed in conjunction with detailed materials characterization and analysis using scanning electron microscopy/energy dispersive spectroscopy (SEM-EDS), x-ray diffraction (XRD), Auger electron spectroscopy (AES) techniques, and weight change measurements. Inlet and outlet gas compositions will be monitored using gas chromatography-mass spectrometry (GCMS).

  7. Ultra-precision positioning assembly

    DOE Patents [OSTI]

    Montesanti, Richard C. (San Francisco, CA); Locke, Stanley F. (Livermore, CA); Thompson, Samuel L. (Pleasanton, CA)

    2002-01-01T23:59:59.000Z

    An apparatus and method is disclosed for ultra-precision positioning. A slide base provides a foundational support. A slide plate moves with respect to the slide base along a first geometric axis. Either a ball-screw or a piezoelectric actuator working separate or in conjunction displaces the slide plate with respect to the slide base along the first geometric axis. A linking device directs a primary force vector into a center-line of the ball-screw. The linking device consists of a first link which directs a first portion of the primary force vector to an apex point, located along the center-line of the ball-screw, and a second link for directing a second portion of the primary force vector to the apex point. A set of rails, oriented substantially parallel to the center-line of the ball-screw, direct movement of the slide plate with respect to the slide base along the first geometric axis and are positioned such that the apex point falls within a geometric plane formed by the rails. The slide base, the slide plate, the ball-screw, and the linking device together form a slide assembly. Multiple slide assemblies can be distributed about a platform. In such a configuration, the platform may be raised and lowered, or tipped and tilted by jointly or independently displacing the slide plates.

  8. Ultra-wideband impedance sensor

    DOE Patents [OSTI]

    McEwan, Thomas E. (Livermore, CA)

    1999-01-01T23:59:59.000Z

    The ultra-wideband impedance sensor (UWBZ sensor, or Z-sensor) is implemented in differential and single-ended configurations. The differential UWBZ sensor employs a sub-nanosecond impulse to determine the balance of an impedance bridge. The bridge is configured as a differential sample-and-hold circuit that has a reference impedance side and an unknown impedance side. The unknown impedance side includes a short transmission line whose impedance is a function of the near proximity of objects. The single-ended UWBZ sensor eliminates the reference side of the bridge and is formed of a sample and hold circuit having a transmission line whose impedance is a function of the near proximity of objects. The sensing range of the transmission line is bounded by the two-way travel time of the impulse, thereby eliminating spurious Doppler modes from large distant objects that would occur in a microwave CW impedance bridge. Thus, the UWBZ sensor is a range-gated proximity sensor. The Z-sensor senses the near proximity of various materials such as metal, plastic, wood, petroleum products, and living tissue. It is much like a capacitance sensor, yet it is impervious to moisture. One broad application area is the general replacement of magnetic sensors, particularly where nonferrous materials need to be sensed. Another broad application area is sensing full/empty levels in tanks, vats and silos, e.g., a full/empty switch in water or petroleum tanks.

  9. Ultra-wideband impedance sensor

    DOE Patents [OSTI]

    McEwan, T.E.

    1999-03-16T23:59:59.000Z

    The ultra-wideband impedance sensor (UWBZ sensor, or Z-sensor) is implemented in differential and single-ended configurations. The differential UWBZ sensor employs a sub-nanosecond impulse to determine the balance of an impedance bridge. The bridge is configured as a differential sample-and-hold circuit that has a reference impedance side and an unknown impedance side. The unknown impedance side includes a short transmission line whose impedance is a function of the near proximity of objects. The single-ended UWBZ sensor eliminates the reference side of the bridge and is formed of a sample and hold circuit having a transmission line whose impedance is a function of the near proximity of objects. The sensing range of the transmission line is bounded by the two-way travel time of the impulse, thereby eliminating spurious Doppler modes from large distant objects that would occur in a microwave CW impedance bridge. Thus, the UWBZ sensor is a range-gated proximity sensor. The Z-sensor senses the near proximity of various materials such as metal, plastic, wood, petroleum products, and living tissue. It is much like a capacitance sensor, yet it is impervious to moisture. One broad application area is the general replacement of magnetic sensors, particularly where nonferrous materials need to be sensed. Another broad application area is sensing full/empty levels in tanks, vats and silos, e.g., a full/empty switch in water or petroleum tanks. 2 figs.

  10. Development of Computational Capabilities to Predict the Corrosion Wastage of Boiler Tubes in Advanced Combustion Systems

    SciTech Connect (OSTI)

    Kung, Steven; Rapp, Robert

    2014-08-31T23:59:59.000Z

    A comprehensive corrosion research project consisting of pilot-scale combustion testing and long-term laboratory corrosion study has been successfully performed. A pilot-scale combustion facility available at Brigham Young University was selected and modified to enable burning of pulverized coals under the operating conditions typical for advanced coal-fired utility boilers. Eight United States (U.S.) coals were selected for this investigation, with the test conditions for all coals set to have the same heat input to the combustor. In addition, the air/fuel stoichiometric ratio was controlled so that staged combustion was established, with the stoichiometric ratio maintained at 0.85 in the burner zone and 1.15 in the burnout zone. The burner zone represented the lower furnace of utility boilers, while the burnout zone mimicked the upper furnace areas adjacent to the superheaters and reheaters. From this staged combustion, approximately 3% excess oxygen was attained in the combustion gas at the furnace outlet. During each of the pilot-scale combustion tests, extensive online measurements of the flue gas compositions were performed. In addition, deposit samples were collected at the same location for chemical analyses. Such extensive gas and deposit analyses enabled detailed characterization of the actual combustion environments existing at the lower furnace walls under reducing conditions and those adjacent to the superheaters and reheaters under oxidizing conditions in advanced U.S. coal-fired utility boilers. The gas and deposit compositions were then carefully simulated in a series of 1000-hour laboratory corrosion tests, in which the corrosion performances of different commercial candidate alloys and weld overlays were evaluated at various temperatures for advanced boiler systems. Results of this laboratory study led to significant improvement in understanding of the corrosion mechanisms operating on the furnace walls as well as superheaters and reheaters in coal-fired boilers resulting from the coexistence of sulfur and chlorine in the fuel. A new corrosion mechanism, i.e., “Active Sulfidation Corrosion Mechanism,” has been proposed to account for the accelerated corrosion wastage observed on the furnace walls of utility boilers burning coals containing sulfur and chlorine. In addition, a second corrosion mechanism, i.e., “Active Sulfide-to-Oxide Corrosion Mechanism,” has been identified to account for the rapid corrosion attack on superheaters and reheaters. Both of the newly discovered corrosion mechanisms involve the formation of iron chloride (FeCl2) vapor from iron sulfide (FeS) and HCl, followed by the decomposition of FeCl2 via self-sustaining cycling reactions. For higher alloys containing sufficient chromium, the attack on superheaters and reheaters is dominated by Hot Corrosion in the presence of a fused salt. Furthermore, two stages of the hot corrosion mechanism have been identified and characterized in detail. The initiation of hot corrosion attack induced by molten sulfate leads to Stage 1 “acidic” fluxing and re-precipitation of the protective scale formed initially on the deposit-covered alloy surfaces. Once the protective scale is penetrated, Stage 2 Hot Corrosion is initiated, which is dominated by “basic” fluxing and re-precipitation of the scale in the fused salt. Based on the extensive corrosion information generated from this project, corrosion modeling was performed using non-linear regression analysis. As a result of the modeling efforts, two predictive equations have been formulated, one for furnace walls and the other for superheaters and reheaters. These first-of-the-kind equations can be used to estimate the corrosion rates of boiler tubes based on coal chemistry, alloy compositions, and boiler operating conditions for advanced boiler systems.

  11. Alkali deposits found in biomass boilers: The behavior of inorganic material in biomass-fired power boilers -- Field and laboratory experiences. Volume 2

    SciTech Connect (OSTI)

    Baxter, L.L. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Miles, T.R.; Miles, T.R. Jr. [Miles (Thomas R.), Portland, OR (United States); Jenkins, B.M. [California Univ., Davis, CA (United States); Dayton, D.C.; Milne, T.A. [National Renewable Energy Lab., Golden, CO (United States); Bryers, R.W. [Foster Wheeler Development Corp., Livingston, NJ (United States); Oden, L.L. [Bureau of Mines, Albany, OR (United States). Albany Research Center

    1996-03-01T23:59:59.000Z

    This report documents the major findings of the Alkali Deposits Investigation, a collaborative effort to understand the causes of unmanageable ash deposits in biomass-fired electric power boilers. Volume 1 of this report provide an overview of the project, with selected highlights. This volume provides more detail and discussion of the data and implications. This document includes six sections. The first, the introduction, provides the motivation, context, and focus for the investigation. The remaining sections discuss fuel properties, bench-scale combustion tests, a framework for considering ash deposition processes, pilot-scale tests of biomass fuels, and field tests in commercially operating biomass power generation stations. Detailed chemical analyses of eleven biomass fuels representing a broad cross-section of commercially available fuels reveal their properties that relate to ash deposition tendencies. The fuels fall into three broad categories: (1) straws and grasses (herbaceous materials); (2) pits, shells, hulls and other agricultural byproducts of a generally ligneous nature; and (3) woods and waste fuels of commercial interest. This report presents a systematic and reasonably detailed analysis of fuel property, operating condition, and boiler design issues that dictate ash deposit formation and property development. The span of investigations from bench-top experiments to commercial operation and observations including both practical illustrations and theoretical background provide a self-consistent and reasonably robust basis to understand the qualitative nature of ash deposit formation in biomass boilers. While there remain many quantitative details to be pursued, this project encapsulates essentially all of the conceptual aspects of the issue. It provides a basis for understanding and potentially resolving the technical and environmental issues associated with ash deposition during biomass combustion. 81 refs., 124 figs., 76 tabs.

  12. Advanced Computational Thermal Studies and their Assessment for Supercritical-Pressure Reactors (SCRs)

    SciTech Connect (OSTI)

    D. M. McEligot; J. Y. Yoo; J. S. Lee; S. T. Ro; E. Lurien; S. O. Park; R. H. Pletcher; B. L. Smith; P. Vukoslavcevic; J. M. Wallace

    2009-04-01T23:59:59.000Z

    The goal of this laboratory / university collaboration of coupled computational and experimental studies is the improvement of predictive methods for supercritical-pressure reactors. The general objective is to develop supporting knowledge needed of advanced computational techniques for the technology development of the concepts and their safety systems.

  13. Numerical and experimental validation of transient modelling for Scramjet active cooling with supercritical

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Numerical and experimental validation of transient modelling for Scramjet active cooling of the engine. In order to simulate the behaviour of a complete actively cooled scramjet, a one for supercritical fuel under pyrolysis. This model is called RESPIRE (French acronym for Scramjet Cooling

  14. SUPERCRITICAL WATER PARTIAL OXIDATION G.T. Hong and M.H. Spritzer

    E-Print Network [OSTI]

    Oxidation (SWPO), a gasification process involving oxidative reactions in a supercritical water environment the gasification medium, resulting in less char formation and improved hydrogen yield. Another major advantage water content of the medium is effective for gasification of hydrogen-poor materials such as coal

  15. Transition metal catalyzed polymerization of butadiene in supercritical CO{sub 2}

    SciTech Connect (OSTI)

    Borkowsky, S. [Los Alamos National Lab., NM (United States)]|[Stanford Univ., CA (United States); Tumas, W. [Los Alamos National Lab., NM (United States); Waymouth, R.M. [Stanford Univ., CA (United States)

    1998-08-01T23:59:59.000Z

    A class of Ni(II) catalysts has been shown to stereoselectively catalyze the 1,4-polymerization of butadiene. The authors have been investigating the use of supercritical CO{sub 2} as an environmentally benign replacement solvent for conventional hydrocarbon and halocarbon solvents for a variety of chemical transformations. Above 31 C, CO{sub 2} enters a supercritical phase, where its physical properties are both liquid-like and gas-like. Importantly, the solvent properties such as dielectric constant for supercritical fluids can be varied by changing the pressure of the fluid. In this report, the authors present results of an investigation of the polymerization of 1,3-butadiene using [({pi}-allyl) Ni(CF{sub 3}CO{sub 2})]{sub 2} in supercritical CO{sub 2}. They conducted 1,3-butadiene polymerizations in CO{sub 2} to determine whether or not they could systematically and predictably adjust the regiochemistry/stereochemistry of the polybutadiene product by varying the solution properties at different pressures. They also mention experiments with CO catalysts that are known to give 1,2-syndiotactic polybutadiene, and with a Pd catalyst system that is known to copolymerize olefin with CO to give perfectly alternating copolymers.

  16. Numerical simulations of the thermal impact of supercritical CO2 injection on chemical

    E-Print Network [OSTI]

    Boyer, Edmond

    Numerical simulations of the thermal impact of supercritical CO2 injection on chemical reactivity, investigates thermal effects during CO2 injection into a deep carbonate formation. Different thermal processes in carbonate aquifers, and the influence of anthropic thermal processes (e.g., injection temperature

  17. Fabrication of activated carbon fibers/carbon aerogels composites by gelation and supercritical drying

    E-Print Network [OSTI]

    Liu, Jie

    Fabrication of activated carbon fibers/carbon aerogels composites by gelation and supercritical August 2003) Activated carbon fiber/carbon aerogel (ACF/CA) composites were fabricated by gelling. The ACFs can reinforce the related carbon aerogels when they originally have low mass density and are weak

  18. Modelling of a solar-powered supercritical water biomass gasifier Laurance A Watson1

    E-Print Network [OSTI]

    is incorporated that recovers the waste heat proceeding biomass gasification. Under the ideal assumptions applied exercise to design a solar supercritical water gasification (SCWG) reactor. A formative reactor concept the waste heat (steam) of a downstream Fischer- Tropsch process. An intermediate heat exchange unit

  19. Large scale characterisation of the concentAtion field of supercritical jets of hydrogen and methane

    E-Print Network [OSTI]

    Boyer, Edmond

    and methane E. Ruffin, Y. Mouilleau. J. Chaineaux INERIS - Institut National de l'Environnement Industriel et at INERIS' sought to characterise the clouds formed by supercritical jets of methane and hydrogen out were: the gas used (methane or hydrogen), the vent orifice diameter (25. 50, 75. 100 or 150 mm

  20. Subcritical and supercritical Klein-Gordon-Maxwell equations without Ambrosetti-Rabinowitz condition

    E-Print Network [OSTI]

    Cunha, Patricia L

    2012-01-01T23:59:59.000Z

    In this article we present some results on the existence of positive and ground state solutions for the nonlinear Klein-Gordon-Maxwell equations. We introduce a general nonlinearity with subcritical and supercritical growth which does not require the usual Ambrosetti-Rabinowitz condition. The proof is based on variational methods and perturbation arguments.