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Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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1

Identification of a new pseudo-binary hydroxide during calendar corrosion of (La, Mg)2Ni7-type hydrogen storage alloys for Nickel-Metal Hydride batteries  

E-Print Network (OSTI)

hydrogen storage alloys for Nickel-Metal Hydride batteries J. Monnier 1 , H. Chen 1 , S. Joiret2,3 , J present higher hydrogen storage capacity and higher discharge capacity, eg. 356mAh/g for LaCaMgNi9 [4 in the huge market of hybrid electric vehicles (HEV) and Emergency Light Units (ELU). Hydrogen

Boyer, Edmond

2

Steps to Commercialization: Nickel Metal Hydride Batteries | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Steps to Commercialization: Nickel Metal Hydride Batteries Steps to Commercialization: Nickel Metal Hydride Batteries Steps to Commercialization: Nickel Metal Hydride Batteries October 17, 2011 - 10:42am Addthis Steps to Commercialization: Nickel Metal Hydride Batteries Matthew Loveless Matthew Loveless Data Integration Specialist, Office of Public Affairs How does it work? Through licensing and collaborative work, Energy Department-sponsored research can yield great economic benefits and help bring important new products to market. The Energy Department funds cutting-edge research on a broad range of topics ranging from advanced battery construction to the modeling of industrial processes and supercomputer simulation of supernovae. But this research is not only about furthering our understanding of the world around

3

Hydridable material for the negative electrode in a nickel-metal hydride storage battery  

SciTech Connect

A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##

Knosp, Bernard (Neuilly-sur-Seine, FR); Bouet, Jacques (Paris, FR); Jordy, Christian (Dourdan, FR); Mimoun, Michel (Neuilly-sur-Marne, FR); Gicquel, Daniel (Lanorville, FR)

1997-01-01T23:59:59.000Z

4

Sulfur resistance of Group VIII transition metal promoted nickel catalysts for synthesis gas methanation  

E-Print Network (OSTI)

SULFUR RESISTANCE OF GROUP VIII TRANSITION METAL PROMOTED NICKEL CATALYSTS FOR SYNTHESIS GAS METHANATION A Thesis by KELLEE HALL HAMLIN Submitted to the Graduate College of Texas AgrM University in partial fulfillment of the requirement...: Aydin Akger n (Chairman of Co 'ttee) Ahme M. Gadalla (Member) Michael . Rosynek (Member) aries D. Holland . ( ead of Department) May 1986 ABSTRACT Sulfur Resistance of Group VIII Transition Metal Promoted Nickel Catalysts For Synthesis Gas...

Hamlin, Kellee Hall

2012-06-07T23:59:59.000Z

5

Method for inhibiting alkali metal corrosion of nickel-containing alloys  

DOE Patents (OSTI)

Structural components of nickel-containing alloys within molten alkali metal systems are protected against corrosion during the course of service by dissolving therein sufficient aluminum, silicon, or manganese to cause the formation and maintenance of a corrosion-resistant intermetallic reaction layer created by the interaction of the molten metal, selected metal, and alloy.

DeVan, Jackson H. (Oak Ridge, TN); Selle, James E. (Westminster, CO)

1983-01-01T23:59:59.000Z

6

Oxidative Dissolution of Nickel Metal in Hydrogenated Hydrothermal Solutions  

SciTech Connect

A platinum-lined, flowing autoclave facility is used to investigate the solubility behavior of metallic nickel in hydrogenated ammonia and sodium hydroxide solutions between 175 and 315 C. The solubility measurements were interpreted by means of an oxidative dissolution reaction followed by a sequence of Ni(II) ion hydrolysis reactions: Ni(s) + 2H+(aq) = Ni2+(aq) + H2(g) and Ni{sup 2+}(aq) + nH{sub 2}O = Ni(OH){sub n}{sup 2-n}(aq) + nH{sup +}(aq) where n = 1 and 2. Gibbs energies associated with these reaction equilibria were determined from a least-squares analysis of the data. The extracted thermochemical properties ({Delta}fG{sup 0}, {Delta}fH{sup 0} and S{sup 0}) for Ni2{sup +}(aq), Ni(OH){sup +}(aq) and Ni(OH){sub 2}(aq) were found to be consistent with those determined in a previous solubility study of NiO/Ni(OH){sub 2} conducted in our laboratory. The thermodynamic basis of the Ni/NiO phase boundary in aqueous solutions is examined to show that Ni(s) is stable relative to NiO(s) in solutions saturated at 25 C with 1 atm H{sub 2} for temperatures below 309 C.

Ziemniak SE, Guilmette PA, Turcotte RA, Tunison HM

2007-03-27T23:59:59.000Z

7

Electron Density Distributions Calculated for the Nickel Sulfides Millerite, Vaesite, and Heazlewoodite and Nickel Metal: A Case for the Importance of Ni-Ni Bond Paths for  

E-Print Network (OSTI)

Electron Density Distributions Calculated for the Nickel Sulfides Millerite, Vaesite, and Heazlewoodite and Nickel Metal: A Case for the Importance of Ni-Ni Bond Paths for Electron Transport G. V. Gibbs point properties (the electron density (F) and the Hessian of F at the bond critical points (bcp

Downs, Robert T.

8

Electrodepositionof Metal Alloyand Mixed Oxide Films Usinga Single-PrecursorTetranuclearCopper-NickelComplex  

E-Print Network (OSTI)

Compositionally uniform mixed metals, metal oxides, and alloys are used extensively as corrosion protective and catalysts. I-~For example, nickel-containing oxides and alloys are used for oxidative protection of very. Although Cu-Ni alloy deposition has been stud- ied for many years, none of the previous approaches has led

Kounaves, Samuel P.

9

Analytical assessment of the thermal behavior of nickel-metal hydride batteries  

E-Print Network (OSTI)

Analytical assessment of the thermal behavior of nickel-metal hydride batteries Peyman Taheri in batteries with orthotropic thermal conductivities, where the heat generation is due to irreversible of the battery thermal behavior with modest numerical effort. The accuracy of the proposed model is tested

Bahrami, Majid

10

Paste Type Nickel Electrode Containing Compound And At Least One Other Element  

DOE Patents (OSTI)

The present invention provides a paste type nickel electrode for a storage cell having an alkaline electrolyte, the electrode comprising a current collector and a paste containing a nickel-based hydroxide and an oxidized compound of cobalt syncrystallized with at least one other element, wherein said hydroxide forms a first powder and wherein said compound forms a second powder distinct from said first powder, said powders being mixed mechanically within said paste.

Bernard, Patrick (Massy, FR); Bertrand, Fran.cedilla.oise (Ris Orangis, FR); Simonneau, Olivier (Dourdan, FR)

1999-11-30T23:59:59.000Z

11

Nickel-Metal-Hydride Batterie--High Energy Storage for Electric Vehicles  

NLE Websites -- All DOE Office Websites (Extended Search)

Freedomcar & Vehicle Technologies Program Freedomcar & Vehicle Technologies Program Nickel-Metal-Hydride Batteries - High Energy Storage for Electric Vehicles Background The key to making electric vehicles (EVs) practical is the development of batteries that can provide performance comparable with that of con ventional vehicles at a similar cost. Most EV batteries have limited energy storage capabili ties, permitting only relatively short driving distances before the batteries must be recharged. In 1991, under a coopera tive agreement with The U.S. Department of Energy (DOE), the United States Advanced Battery Consortium (USABC) initiated development of nickel- metal-hydride (NiMH) battery technology and established it as a prime mid-term candidate for use in EVs. DOE funding has been instru

12

Structural Basis of the Metal Specificity for Nickel Regulatory Protein NikR  

SciTech Connect

In the presence of excess nickel, Escherichia coli NikR regulates cellular nickel uptake by suppressing the transcription of the nik operon, which encodes the nickel uptake transporter, NikABCDE. Previously published in vitro studies have shown that NikR is capable of binding a range of divalent transition metal ions in addition to Ni{sup 2+}, including Co{sup 2+}, Cu{sup 2+}, Zn{sup 2+}, and Cd{sup 2+}. To understand how the high-affinity nickel binding site of NikR is able to accommodate these other metal ions, and to improve our understanding of NikR's mechanism of binding to DNA, we have determined structures of the metal-binding domain (MBD) of NikR in the apo form and in complex with Cu{sup 2+} and Zn{sup 2+} ions and compared them with the previously published structures with Ni{sup 2+}. We observe that Cu{sup 2+} ions bind in a manner very similar to that of Ni{sup 2+}, with a square planar geometry but with longer bond lengths. Crystals grown in the presence of Zn{sup 2+} reveal a protein structure similar to that of apo MBD with a disordered {alpha}3 helix, but with two electron density peaks near the Ni{sup 2+} binding site corresponding to two Zn{sup 2+} ions. These structural findings along with biochemical data on NikR support a hypothesis that ordering of the {alpha}3 helix is important for repressor activation.

Phillips, C.M.; Schreiter, E.R.; Guo, Y.; Wang, S.C.; Zamble, D.B.; Drennan, C.L.

2009-05-21T23:59:59.000Z

13

Hyperaccumulator Alyssum murale Relies on a Different Metal Storage Mechanism for Cobalt than for Nickel  

SciTech Connect

The nickel (Ni) hyperaccumulator Alyssum murale has been developed as a commercial crop for phytoremediation/phytomining Ni from metal-enriched soils. Here, metal co-tolerance, accumulation and localization were investigated for A. murale exposed to metal co-contaminants. A. murale was irrigated with Ni-enriched nutrient solutions containing basal or elevated concentrations of cobalt (Co) or zinc (Zn). Metal localization and elemental associations were investigated in situ with synchrotron X-ray microfluorescence (SXRF) and computed-microtomography (CMT). A. murale hyperaccumulated Ni and Co (> 1000 {micro}g g{sup -1} dry weight) from mixed-metal systems. Zinc was not hyperaccumulated. Elevated Co or Zn concentrations did not alter Ni accumulation or localization. SXRF images showed uniform Ni distribution in leaves and preferential localization of Co near leaf tips/margins. CMT images revealed that leaf epidermal tissue was enriched with Ni but devoid of Co, that Co was localized in the apoplasm of leaf ground tissue and that Co was sequestered on leaf surfaces near the tips/margins. Cobalt-rich mineral precipitate(s) form on leaves of Co-treated A. murale. Specialized biochemical processes linked with Ni (hyper)tolerance in A. murale do not confer (hyper)tolerance to Co. A. murale relies on a different metal storage mechanism for Co (exocellular sequestration) than for Ni (vacuolar sequestration).

Tappero, R.; Peltier, E; Grafe, M; Heidel, K; Ginder-Vogel, M; Livi, K; Rivers, M; Marcus, M; Chaney, R; Sparks, D

2007-01-01T23:59:59.000Z

14

Mixing effect of metal oxides on negative electrode reactions in the nickel-hydride battery  

SciTech Connect

Negative electrodes for use in nickel-hydride batteries were prepared from MmNi[sub 3.6]Mn[sub 0.4]Al[sub 0.3]Co[sub 0.7] (Mm = misch metal with the composition of 24.87% La, 52.56% Ce, 5.57% Pr, 16.86% Nd, and 0.14% Sm) alloy being mixed with RuO[sub 2] or Co[sub 3]O[sub 4] powder. Then the hydrogen evolution reactions at the electrodes were investigated by measuring the potential decay immediately after the interruption of an applied cathodic current. The reactions were found to proceed by the Volmer-Tafel mechanism. The total overvoltage ([eta]) was divided into two components ([eta][sub 1] and [eta][sub 2]) corresponding to the Tafel and Volmer reactions. The exchange current densities of the elementary reactions, i[sub 0V] and i[sub 0T], were then evaluated by extrapolating the Tafel lines for [eta][sub 1] and [eta][sub 2]. The Volmer reaction is much more accelerated by surface modification with RuO[sub 2] or Co[sub 3]O[sub 4] powder than the Tafel reaction, which results in the enrichment of adsorbed hydrogen, leading to higher charging efficiency.

Iwakura, Chiaki; Matsuoka, Masao; Kohno, Tatsuoki (Univ. of Osaka Prefecture (Japan). Dept. of Applied Chemistry)

1994-09-01T23:59:59.000Z

15

Reinforced nickel and nickel-platinum catalysts for performing the thermally coupled reactions of methane steam reforming and hydrogen oxidation  

Science Journals Connector (OSTI)

The formation of composite nickel and nickel-platinum catalysts reinforced with steel gauze was studied. The catalysts were prepared by sintering powdered nickel metal and a supported nickel catalyst (GIAP-3 or N...

M. M. Danilova; Z. A. Sabirova; N. A. Kuzin; V. A. Kirillov…

16

Zero-field Spin Depolarization of Low-Energy Muons in Ferromagnetic Nickel and Silver Metal  

Science Journals Connector (OSTI)

We present zero-field muon-spin depolarization measurements in nickel and silver performed using low-energy muon-spin relaxation technique.Ni or Ag are usually used in this depth-resolved technique as a backing material to enable background subtraction when studying small crystals or materials with weak magnetism. The depolarization rate of the asymmetry in silver and that of the slow relaxing part of the asymmetry in nickel are small(? 0.05 ?s?1), and weakly temperature and energy-dependent.

H. Saadaoui; Z. Salman; T. Prokscha; A. Suter; B.M. Wojek; E. Morenzoni

2012-01-01T23:59:59.000Z

17

Nickel-Cathoded Perovskite Solar Cells  

Science Journals Connector (OSTI)

Nickel-Cathoded Perovskite Solar Cells ... Current lead halide perovskite solar cells use high work function (?) precious metals, such as gold (? = 5.1 eV), as the back cathode to maximize the attainable photovoltage. ... We report herein a set of perovskite-type solar cells that use nickel (? = 5.04 eV), an earth-abundant element and non-precious metal, as back cathode and achieve the same open-circuit voltage as gold and an efficiency of 10.4%. ...

Qinglong Jiang; Xia Sheng; Bing Shi; Xinjian Feng; Tao Xu

2014-10-22T23:59:59.000Z

18

Influence of additives on the thermal behavior of nickel/metal hydride battery  

Science Journals Connector (OSTI)

This study discusses the thermal behavior of the 6.5 Ah cylinder Ni/MH hydride battery with 0.5 wt% ytterbium oxide (...2O3...) in nickel electrode and 1.0 wt% super absorbent polymer (SAP) in hydrogen-storage al...

Kai Yang; Jin Jing An; Shi Chen

2010-12-01T23:59:59.000Z

19

Effects on the positive electrode of the corrosion of AB{sub 5} alloys in nickel-metal-hydride batteries  

SciTech Connect

Effects of corrosion of MmNi{sub 4.3{minus}x}Mn{sub 0.3}Al{sub 0.4}Co{sub x} alloys (where Mm = Ce 50%, La 30%, Nd 15%, Pr 5%) are evaluated in nickel-metal-hydride (Ni-MH) cells. Particularly, it is shown how Al released by the corroded alloys pollutes the positive electrode, which endures a loss of charging efficiency, due to the formation of a hydrotalcite-like phase stabilized with Al. Furthermore, since Al is eluted from the hydride electrode and is completely trapped in the positive active material, the titration of this element in the positive electrode is a powerful technique for quantification of the corrosion of AB{sub 5} alloys in Ni-MH cells.

Bernard, P. [SAFT, Marcoussis (France). Research Dept.

1998-02-01T23:59:59.000Z

20

Perfluorodiethoxymethane on nickel and nickel oxide surfaces  

SciTech Connect

The interaction of perfluorodiethoxymethane with a nickel single crystal, Ni(100); a nickel crystal with chemisorbed oxygen, Ni(100)-c(2x2)O; and a nickel crystal with nickel oxide crystallites, NiO(100) is investigated in an ultra high vacuum environment using thermal desorption spectroscopy and high resolution electron energy loss spectroscopy. Nickel, a component of hard disk drives and stainless steel, is used to represent metal surfaces in these {open_quotes}real{close_quotes} systems. Perfluorodiethoxymethane is used in this study as a model compound of industrial perfluoropolyether lubricants. These lubricants are known for their exceptional stability, except in the presence of metals. Perfluorodiethoxymethane contains the acetal group (-OCF{sub 2}O-), believed to be particularly vulnerable to attack in the presence of Lewis acids. Since the surfaces studied show increasing Lewis acidity at the nickel atom sites, one might expect to see increasing decomposition of perfluorodiethoxymethane due to acidic attack of the acetal group. No decomposition of perfluorodiethoxymethane is observed on the clean Ni(100) surface, while more research is needed to determine whether a small decomposition pathway is observed on the oxygenated surfaces, or whether sample impurities are interfering with results. The strength of the bonding of perfluorodiethoxymethane to the surface is found to increase as the nickel atoms sites become more acidic in moving from Ni(100) to Ni (100)-c(2x2)O to NiO (100).

Jacobson, J.

1994-03-03T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia  

SciTech Connect

Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?°C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?°C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

2014-03-15T23:59:59.000Z

22

Benchmark Analysis of Subcritical Noise Measurements on a Nickel-Reflected Plutonium Metal Sphere  

SciTech Connect

Subcritical experiments using californium source-driven noise analysis (CSDNA) and Feynman variance-to-mean methods were performed with an alpha-phase plutonium sphere reflected by nickel shells, up to a maximum thickness of 7.62 cm. Both methods provide means of determining the subcritical multiplication of a system containing nuclear material. A benchmark analysis of the experiments was performed for inclusion in the 2010 edition of the International Handbook of Evaluated Criticality Safety Benchmark Experiments. Benchmark models have been developed that represent these subcritical experiments. An analysis of the computed eigenvalues and the uncertainty in the experiment and methods was performed. The eigenvalues computed using the CSDNA method were very close to those calculated using MCNP5; however, computed eigenvalues are used in the analysis of the CSDNA method. Independent calculations using KENO-VI provided similar eigenvalues to those determined using the CSDNA method and MCNP5. A slight trend with increasing nickel-reflector thickness was seen when comparing MCNP5 and KENO-VI results. For the 1.27-cm-thick configuration the MCNP eigenvalue was approximately 300 pcm greater. The calculated KENO eigenvalue was about 300 pcm greater for the 7.62-cm-thick configuration. The calculated results were approximately the same for a 5-cm-thick shell. The eigenvalues determined using the Feynman method are up to approximately 2.5% lower than those determined using either the CSDNA method or the Monte Carlo codes. The uncertainty in the results from either method was not large enough to account for the bias between the two experimental methods. An ongoing investigation is being performed to assess what potential uncertainties and/or biases exist that have yet to be properly accounted for. The dominant uncertainty in the CSDNA analysis was the uncertainty in selecting a neutron cross-section library for performing the analysis of the data. The uncertainty in the Feynman method was equally shared between the uncertainties in fitting the data to the Feynman equations and the neutron multiplicity of 239Pu. Material and geometry uncertainties in the benchmark experiment were generally much smaller than uncertainties in the analysis methods.

John D. Bess; Jesson Hutchinson

2009-09-01T23:59:59.000Z

23

Electrochromic nickel oxide simultaneously doped with lithium and a metal dopant  

DOE Patents (OSTI)

An electrochromic device comprising a counter electrode layer comprised of lithium metal oxide which provides a high transmission in the fully intercalated state and which is capable of long-term stability, is disclosed. Methods of making an electrochromic device comprising such a counter electrode are also disclosed.

Gillaspie, Dane T; Weir, Douglas G

2014-04-01T23:59:59.000Z

24

Inert anode containing oxides of nickel iron and cobalt useful for the electrolytic production of metals  

DOE Patents (OSTI)

An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and CoO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and CoO: 0.15 to 0.99 NiO; 0.0001 to 0.85 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.45 CoO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA)

2002-01-01T23:59:59.000Z

25

Inert anode containing oxides of nickel, iron and zinc useful for the electrolytic production of metals  

DOE Patents (OSTI)

An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and ZnO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and ZnO: 0.2 to 0.99 NiO; 0.0001 to 0.8 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.3 ZnO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

Ray, Siba P. (Murrysville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA); Liu, Xinghua (Monroeville, PA)

2002-01-01T23:59:59.000Z

26

Nickel recovery aids battery development  

Science Journals Connector (OSTI)

GM is developing the zinc/nickel-oxide battery for the small commuter-type electric car that the company expects to produce in a few years. ...

1981-11-02T23:59:59.000Z

27

SPECTROSCOPIC METALLICITY DETERMINATIONS FOR W UMa-TYPE BINARY STARS  

SciTech Connect

This study is the first attempt to determine the metallicities of W UMa-type binary stars using spectroscopy. We analyzed about 4500 spectra collected at the David Dunlap Observatory. To circumvent problems caused by the extreme spectral line broadening and blending and by the relatively low quality of the data, all spectra were subject to the same broadening function (BF) processing to determine the combined line strength in the spectral window centered on the Mg I triplet between 5080 A and 5285 A. All individual integrated BFs were subsequently orbital-phase averaged to derive a single line-strength indicator for each star. The star sample was limited to 90 W UMa-type (EW) binaries with the strict phase-constancy of colors and without spectral contamination by spectroscopic companions. The best defined results were obtained for an F-type sub-sample (0.32 < (B - V){sub 0} < 0.62) of 52 binaries for which integrated BF strengths could be interpolated in the model atmosphere predictions. The logarithmic relative metallicities, [M/H], for the F-type sub-sample indicate metal abundances roughly similar to the solar metallicity, but with a large scatter which is partly due to combined random and systematic errors. Because of the occurrence of a systematic color trend resulting from inherent limitations in our approach, we were forced to set the absolute scale of metallicities to correspond to that derived from the m{sub 1} index of the Stroemgren uvby photometry for 24 binaries of the F-type sub-sample. The trend-adjusted metallicities [M/H]{sub 1} are distributed within -0.65 < [M/H]{sub 1} < +0.50, with the spread reflecting genuine metallicity differences between stars. One half of the F-sub-sample binaries have [M/H]{sub 1} within -0.37 < [M/H]{sub 1} < +0.10, a median of -0.04 and a mean of -0.10, with a tail toward low metallicities, and a possible bias against very high metallicities. A parallel study of kinematic data, utilizing the most reliable and recently obtained proper motion and radial velocity data for 78 binaries of the full sample, shows that the F-type sub-sample binaries (44 stars with both velocities and metallicity determinations) have similar kinematic properties to solar-neighborhood, thin-disk dwarfs with space velocity component dispersions: {sigma}U = 33 km s{sup -1}, {sigma}V = 23 km s{sup -1} and {sigma}W = 14 km s{sup -1}. FU Dra with a large spatial velocity, V{sub tot} = 197 km s{sup -1} and [M/H]{sub 1} = -0.6 {+-} 0.2, appears to be the only thick-disk object in the F-type sub-sample. The kinematic data indicate that the F-type EW binaries are typical, thin-disk population stars with ages about 3-5.5 Gyr. The F-type binaries that appear to be older than the rest tend to have systematically smaller mass ratios than most of the EW binaries of the same period.

Rucinski, Slavek M. [Department of Astronomy and Astrophysics, University of Toronto, 50 St. George Street, Toronto, Ontario M5S 3H4 (Canada); Pribulla, Theodor; Budaj, Jan, E-mail: rucinski@astro.utoronto.ca, E-mail: pribulla@ta3.sk, E-mail: budaj@ta3.sk [Astronomical Institute, Slovak Academy of Sciences, 059 60 Tatranska Lomnica (Slovakia)

2013-09-15T23:59:59.000Z

28

Ductility and chemical reactions at the interface between nickel and magnesium oxide single crystals.  

E-Print Network (OSTI)

??An investigation was conducted on the interaction between nickel metal and single crystals of magnesium oxide. The nickel was cleaned with purified hydrogen gas at… (more)

Hasselman, Didericus Petrus Hermannus

2011-01-01T23:59:59.000Z

29

E-Print Network 3.0 - alb2-type transition-metal diborides Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

alb2-type transition-metal diborides Search Powered by Explorit Topic List Advanced Search Sample search results for: alb2-type transition-metal diborides Page: << < 1 2 3 4 5 > >>...

30

Formation of Nickel Silicide from Direct-Liquid-Injection Chemical-Vapor-Deposited Nickel Nitride Films  

E-Print Network (OSTI)

. Published April 28, 2010. Metal silicides such as TiSi2 and CoSi2 have been commonly used as the contactsFormation of Nickel Silicide from Direct-Liquid-Injection Chemical-Vapor-Deposited Nickel Nitride as the intermediate for subsequent conversion into nickel silicide NiSi , which is a key material for source, drain

31

Quantum dissipative dynamics of adsorbates near metal surfaces: A surrogate Hamiltonian theory applied to hydrogen on nickel  

E-Print Network (OSTI)

Quantum dissipative dynamics of adsorbates near metal surfaces: A surrogate Hamiltonian theory; accepted 18 February 1997 Dissipative dynamics of an adsorbate near a metal surface is formulated of molecules adsorbed on metal surfaces are complicated due to the simultaneous encounter with dis- sipative

Baer, Roi

32

Metal-sulfur type cell having improved positive electrode  

DOE Patents (OSTI)

An novel metal-sulfur type cell operable at a temperature of 200.degree. C. or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S).sub.y).sub.n wherein y=1 to 6; n=2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprisises one of more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associtated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

Dejonghe, Lutgard C. (Berkeley, CA); Visco, Steven J. (Berkeley, CA); Mailhe, Catherine C. (Berkeley, CA); Armand, Michel B. (St. Martin D'Uriage, FR)

1989-01-01T23:59:59.000Z

33

Transition from metallic to tunneling-type conductance in metal-metal and normal-metal–superconductor point contacts  

Science Journals Connector (OSTI)

We have investigated the microshort–to–tunneling crossover in normal-normal (N-N) and normal-metal–superconductor (N-S) point-contact junctions at 4.2 K as the junction conductance (G0) is varied. The microshort (or ‘‘metallic’’) point contact with the dynamic conductance G (V) having a negative derivative with respect to bias V (i.e., ?G/?V0 when G0?3–5 mS. We show that this is the region where the contact radius ? is a few times kF-1 (kF is the Fermi wave vector) and the crossover in the sign of ?G/?V occurs due to electron confinement in a length scale comparable to kF-1. The effect of confinement is to make the electrons crossing the constriction evanescent in nature as the junction size is reduced progressively and the energy for lateral confinement becomes comparable to EF. We argue that in this extreme ballistic regime, the classical Sharvin approach breaks down as quantum effects due to electron confinement takes over. This happens much before ‘‘single-atom’’ contact is reached which signals the onset of vacuum tunneling. As a further test of the electron confinement effects in point contacts, we investigated clean N-S microshorts showing near-ideal Andreev reflection. We find that in N-S junctions, the Andreev reflection (which is a manifestation of superconductivity) gradually vanishes when the contact radius ??0.1? (? is the coherence length) and the energy cost of electron confinement is larger than the superconducting energy gap ?.

H. Srikanth and A. K. Raychaudhuri

1992-12-01T23:59:59.000Z

34

Materials Reliability Program Low-Temperature Cracking of Nickel-Based Alloys and Weld Metals (MRP-108)  

SciTech Connect

OAK-B135 A rising load test in low-temperature (50-100 degree C) pH 10 water containing a high concentration of dissolved hydrogen (150 cc/kg) has demonstrated that Alloy 690 as well as weld metals 82 and 52 exhibit a marked loss of ductility. A similar loss of ductility has been shown to occur in widely used weld metal 182 under replica test conditions and simulated PWR primary water containing 100 cc/kg of hydrogen. The objective of this report was to confirm the Bettis test results for weld metal 82 and determine whether weld metal 182 is susceptible to the same reductions in toughness. This report documents the first industry effort to reckon with the low temperature crack propagation (LTCP) issue.

B. Young

2004-02-01T23:59:59.000Z

35

Formation of Nickel Silicide from Direct-liquid-injection Chemical-vapor-deposited Nickel Nitride Films  

SciTech Connect

Smooth, continuous, and highly conformal nickel nitride (NiN{sub x}) films were deposited by direct liquid injection (DLI)-chemical vapor deposition (CVD) using a solution of bis(N,N{prime}-di-tert-butylacetamidinato)nickel(II) in tetrahydronaphthalene as the nickel (Ni) source and ammonia (NH{sub 3}) as the coreactant gas. The DLI-CVD NiNx films grown on HF-last (100) silicon and on highly doped polysilicon substrates served as the intermediate for subsequent conversion into nickel silicide (NiSi), which is a key material for source, drain, and gate contacts in microelectronic devices. Rapid thermal annealing in the forming gas of DLI-CVD NiNx films formed continuous NiSi films at temperatures above 400 C. The resistivity of the NiSi films was 15{mu}{Omega} cm, close to the value for bulk crystals. The NiSi films have remarkably smooth and sharp interfaces with underlying Si substrates, thereby producing contacts for transistors with a higher drive current and a lower junction leakage. Resistivity and synchrotron X-ray diffraction in real-time during annealing of NiNx films showed the formation of a NiSi film at about 440 C, which is morphologically stable up to about 650 C. These NiSi films could find applications in future nanoscale complementary metal oxide semiconductor devices or three-dimensional metal-oxide-semiconductor devices such as Fin-type field effect transistors for the 22 nm technology node and beyond.

Li, Z.; Gordon, R; Li, H; Shenai, D; Lavoie, C

2010-01-01T23:59:59.000Z

36

Microstructural, mechanical and weldability assessments of the dissimilar welds between ??- and ??-strengthened nickel-base superalloys  

SciTech Connect

Dissimilar welding of ??- and ??-strengthened nickel-base superalloys has been investigated to identify the relationship between the microstructure of the welds and the resultant mechanical and weldability characteristics. ??-Strengthened nickel-base Alloy 500 and ??-strengthened nickel-base Alloy 718 were used for dissimilar welding. Gas tungsten arc welding operations were utilized for performing the autogenous dissimilar welding. Alloy 500 and Alloy 718 base metals showed various types of phases, carbides, intermetallics and eutectics in their microstructure. The results for Alloy 500 weld metal showed severe segregation of titanium to the interdendritic regions. The Alloy 718 weld metal compositional analysis confirmed the substantial role of Nb in the formation of low-melting eutectic-type morphologies which can reduce the weldability. The microstructure of dissimilar weld metal with dilution level of 65% wt.% displayed semi-developed dendritic structure. The less segregation and less formation of low-melting eutectic structures caused to less susceptibility of the dissimilar weld metal to the solidification cracking. This result was confirmed by analytic modeling achievements. Dissolution of ??-Ni{sub 3}Nb precipitations took place in the Alloy 718 heat-affected zone leading to sharp decline of the microhardness in this region. Remelted and resolidified regions were observed in the partially-melted zone of Alloy 500 and Alloy 718. Nevertheless, no solidification and liquation cracking happened in the dissimilar welds. Finally, this was concluded that dissimilar welding of ??- and ??-strengthened nickel-base superalloys can successfully be performed. - Highlights: • Dissimilar welding of ??- and ??-strengthened nickel-base superalloys is studied. • Microstructural, mechanical and weldability aspects of the welds are assessed. • Microstructure of welds, bases and heat-affected zones is characterized in detail. • The type, morphology and distribution of the phases are thoroughly investigated. • Dissimilar welding is successfully performed without occurrence of any hot cracks.

Naffakh Moosavy, Homam, E-mail: homam_naffakh@iust.ac.ir [School of Metallurgy and Materials Engineering, Iran University of Science and Technology (IUST), Tehran 16846-13114 (Iran, Islamic Republic of); Aboutalebi, Mohammad-Reza; Seyedein, Seyed Hossein [School of Metallurgy and Materials Engineering, Iran University of Science and Technology (IUST), Tehran 16846-13114 (Iran, Islamic Republic of); Mapelli, Carlo [Dipartimento di Meccanica, Politecnico di Milano, Via La Massa 34, Milan 20156 (Italy)

2013-08-15T23:59:59.000Z

37

Thermal behavior of nickel–metal hydride battery during charging at a wide range of ambient temperatures  

Science Journals Connector (OSTI)

The thermal behavior of D-type Ni–MH battery during charging was investigated at a wide ... this work. The temperature measurement of the battery was conducted by using a thermal infrared imager put in a high–low...

Kai Zheng Fang; Dao Bin Mu; Shi Chen…

2011-07-01T23:59:59.000Z

38

Electroless nickel recycling via electrodialysis  

SciTech Connect

Electroless nickel is widely used in the metal finishing industry as a coating. It plates evenly on a variety of surfaces and replicates or enhances the surface finish. It has high hardness and good corrosion resistance and machinability. However, its bath life is limited and it has a tendency to spontaneously plate out on the tank and associated equipment. These problems add to the cost per unit component plated. Also, expensive waste treatment is required before users can dispose of the spent solution. Electroless nickel`s limited bath life is inherent in its chemical make-up. Using hypophosphite as the reducing agent for the nickel ion generates by-products of nickel metal and orthophosphite. When the level of orthophosphite in the solution reaches a high concentration, the reaction slows and finally stops. The bath must be disposed of, and its treatment and replacement costs are high. Metal salts have a tendency to plate out because of the dissolved solids present, and this also makes it necessary to discard the bath. Lawrence Livermore National Laboratory (LLNL) has conducted a study of an electrodialysis process that can reduce both chemical purchases and disposal costs. Electrodialysis employs a membrane, deionized water, and an electromotive potential to separate the orthophosphite and other dissolved solids from the nickel ions. With the aid of the electromotive potential, the dissolved solids migrate across the membrane from the process solution into the water in the recycling unit`s holding cell. This migration lowers the total dissolved solids (TDS) in the process solution and improves plating performance. The dialysis process makes it possible to reuse the bath many times without disposal.

Steffani, C.; Meltzer, M.

1995-04-01T23:59:59.000Z

39

Switchable Mirrors Based on Nickel-Magnesium Films  

NLE Websites -- All DOE Office Websites (Extended Search)

Switchable Mirrors Based on Nickel-Magnesium Films Switchable Mirrors Based on Nickel-Magnesium Films Title Switchable Mirrors Based on Nickel-Magnesium Films Publication Type Journal Article LBNL Report Number LBNL-47180 Year of Publication 2001 Authors Richardson, Thomas J., Jonathan L. Slack, Robert D. Armitage, Robert Kostecki, Baker Farangis, and Michael D. Rubin Journal Applied Physics Letters Volume 78 Pagination 3047 Call Number LBNL-47180 Abstract An electrochromic mirror electrode based on reversible uptake of hydrogen in nickel magnesium alloy films is reported. Thin, magnesium-rich Ni-Mg films prepared on glass substrates by cosputtering from Ni and Mg targets are mirror-like in appearance and have low visible transmittance. Upon exposure to hydrogen gas or on cathodic polarization in alkaline electrolyte, the films take up hydrogen and become transparent. When hydrogen is removed, the mirror properties are recovered. The transition is believed to result from reversible formation of Mg2NiH4 and MgH2. A thin overlayer of palladium was found to enhance the kinetics of hydrogen insertion and extraction, and to protect the metal surface against oxidation.

40

Synthesis and structure of complex metal oxides produced by interaction of iron and nickel acetylacetonates with hydrolysis products of titanium and zirconium alcoholates  

Science Journals Connector (OSTI)

The interaction of nickel and iron acetylacetonates with hydrolysis products of titanium and zirconium alcoholates and their mixture has been studied. It was shown that chemical synthesis of organometallic gel...

M. V. Tsodikov; O. V. Bukhtenko…

1991-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

p-Type semiconducting nickel oxide as an efficiency-enhancing anodal interfacial layer in bulk heterojunction solar cells  

DOE Patents (OSTI)

The present invention, in one aspect, relates to a solar cell. In one embodiment, the solar cell includes an anode, a p-type semiconductor layer formed on the anode, and an active organic layer formed on the p-type semiconductor layer, where the active organic layer has an electron-donating organic material and an electron-accepting organic material.

Irwin, Michael D; Buchholz, Donald B; Marks, Tobin J; Chang, Robert P. H.

2014-11-25T23:59:59.000Z

42

DOE - Office of Legacy Management -- International Nickel Co - Bayonne  

Office of Legacy Management (LM)

Nickel Co - Bayonne Nickel Co - Bayonne Laboratories - NJ 17 FUSRAP Considered Sites Site: International Nickel Co., Bayonne Laboratories (NJ.17 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Bayonne , New Jersey NJ.17-1 Evaluation Year: 1994 NJ.17-1 Site Operations: Conducted research on the nickel plating of uranium metal. NJ.17-2 Site Disposition: Eliminated - Potential for contamination considered remote due to limited scope of the operations Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium NJ.17-2 Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to International Nickel Co., Bayonne Laboratories

43

High temperature low-cycle fatigue of friction welded joints - type 304-304 stainless steel and alloy 718-718 nickel base superalloy  

SciTech Connect

This paper assesses the high-temperature low-cycle fatigue of the Type 304 stainless steel and Alloy 718 superalloy friction-welded joints. Strain controlled low-cycle fatigue tests for 304-304 and 718-718 friction-welded specimens were carried out at 923 K in air to obtain the fatigue strength of the joints. These materials were selected as the cyclic hardening and softening materials, respectively. The 304-304 welded specimens showed inferior fatigue strength in comparison with the base metal while the 718-718 specimens exhibited fatigue strength equivalent to that of the base metal. The difference in the fatigue strength between the two materials is discussed from the viewpoint of the cyclic deformation behavior and strain reduction at weld interface.

Wakai, T. (Power Reactor and Nuclear Fuel Development Corp., Ibaraki (Japan). Oarai Engineering Center); Sakane, M.; Ohnami, M. (Ritsumeikan Univ., Kyoto (Japan). Dept. of Mechanical Engineering); Okita, K. (Hyogo Prefectural Inst. of Industrial Research, Miki (Japan). Technical Center for Machinery and Metals); Fukuchi, Y. (Hyogo Prefectural Inst. of Industrial Research, Kobe (Japan))

1993-01-01T23:59:59.000Z

44

Metal-insulator-semiconductor structures on p-type GaAs with low interface state density  

E-Print Network (OSTI)

Metal-insulator-semiconductor structures on p-type GaAs with low interface state density Zhi Chen properties of in situ deposited Si3N4 /Si/p-GaAs metal-insulator-semiconductor structures have been offered by a low gate leakage technology in GaAs, such as metal insulator structures, func- tional Ga

Chen, Zhi

45

Transition-Metal Hydrides  

NLE Websites -- All DOE Office Websites (Extended Search)

Transition-Metal Hydride Electrochromics Transition-Metal Hydride Electrochromics A new type of electrochromic hydride material has interesting and unusual properties. Thin Ni-Mg films, for example, are mirror-like in appearance and have very low visible transmittance. On exposure to hydrogen gas or on reduction in alkaline electrolyte, the films become transparent. The transition is believed to result from formation of nickel magnesium hydride, Mg2NiH4. Switchable mirrors based on rare earth hydrides were discovered in 1996 at Vrije University in the Netherlands, Rare earth-magnesium alloy films were subsequently found to be superior to the pure lanthanides in maximum transparency and mirror-state reflectivity by Philips Laboratories. The newer transition-metal types which use less expensive and less reactive materials were discovered at LBNL. This has now become a very active area of study with a network of researchers.

46

Dissimilar-weld failure analysis and development. Comparative behavior of similar and dissimilar welds. Final report. [Welds of 2-1/4Cr-1Mo to 2-1/4Cr-1Mo using 2-1/4Cr-1Mo filler material; and austenitic to ferritic steel welds made by fusion welding alloy-800H to 2-1/4Cr-1Mo using nickel base filler metal ERNiCr-3  

SciTech Connect

The 593/sup 0/C (1100/sup 0/F) stress rupture behavior of similar metal welds (SMWs) and dissimilar metal welds (DMWs) was investigated under cyclic load and cyclic temperature conditions to provide insight into the question, ''Why do DMWs fail sooner than SMWs in the fossil fuel boilers.'' The weld joints of interest were an all ferritic steel SMW made by fusion welding 2-1/4Cr-1Mo to 2-1/4Cr-1Mo using 2-1/4Cr-1Mo filler metal and an austenitic to ferritic steel DMW made by fusion welding Alloy-800H to 2-1/4Cr-1Mo using a nickel base filler metal ERNiCr-3. The stress rupture behavior obtained on cross weld specimens was similar for both types of welds with only a 20% reduction in rupture life for the DMW. For rupture times less than 1500 hours, failures occurred in the 2-1/4Cr-1Mo base metal whereas, for rupture times greater than 1500 hours, failures occurred in the 2-1/4Cr-1Mo heat affected zone (HAZ). The HAZ failures exhibited a more brittle appearance than the base metal failures for both types of welds and it appears that the life of both joints was limited by the stress rupture properties of the HAZ. These results support the hypothesis that increased residual stresses due to abrupt changes in hardness (strength) of metals involved are the major contributors to the reduction in life of DMWs as compared to SMWs. 10 refs., 15 figs., 7 tabs.

Busboom, H.; Ring, P.J.

1986-07-01T23:59:59.000Z

47

Dimensionality-induced insulator-metal crossover in layered nickelates La{sub n+1}Ni{sub n}O{sub 2n+2} (n = 2, 3, and ?)  

SciTech Connect

Low-valence layered nickelates are a structural analog to the superconducting cuprates and possess interesting properties. In this work, we have systematically studied the electronic structure of La{sub n+1}Ni{sub n}O{sub 2n+2} using first-principles calculations. Our results reveal that the Ni-3d 3z{sup 2} ? r{sup 2} orbital state is active and evolves from discrete molecular levels to a continuous solid band and its filling varies as the dimensionality (or n) increases. The two-dimensional (2D) La{sub 3}Ni{sub 2}O{sub 6} and La{sub 4}Ni{sub 3}O{sub 8} are thus found to have a molecular insulating state. In contrast, the 3D LaNiO{sub 2} is metallic and its 3z{sup 2} ? r{sup 2} band surprisingly becomes 3D due to the Ni-La hybridization, and the La-5d xy orbital also forms a 2D metallic band. Therefore, La{sub n+1}Ni{sub n}O{sub 2n+2} is a dimensionality-controlled insulator-metal crossover system.

Liu, Ting; Jia, Ting; Zhang, Xiaoli [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China)] [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Wu, Hua, E-mail: wuh@fudan.edu.cn [Laboratory for Computational Physical Sciences (MOE), State Key Laboratory of Surface Physics, and Department of physics, Fudan University, Shanghai 200433 (China)] [Laboratory for Computational Physical Sciences (MOE), State Key Laboratory of Surface Physics, and Department of physics, Fudan University, Shanghai 200433 (China); Zeng, Zhi, E-mail: zzeng@theory.issp.ac.cn [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China) [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Hefei National Laboratory for Physical Sciences at Microscale, Department of Physics, University of Science and Technology of China, Hefei 230026 (China); Lin, H. Q. [Beijing Computational Science Research Center, Beijing 100084 (China)] [Beijing Computational Science Research Center, Beijing 100084 (China); Li, X. G. [Hefei National Laboratory for Physical Sciences at Microscale, Department of Physics, University of Science and Technology of China, Hefei 230026 (China)] [Hefei National Laboratory for Physical Sciences at Microscale, Department of Physics, University of Science and Technology of China, Hefei 230026 (China)

2014-04-15T23:59:59.000Z

48

Bellows-Type Accumulators for Liquid Metal Loops of Space Reactor Power Systems  

SciTech Connect

In many space nuclear power systems, the primary and/or secondary loops use liquid metal working fluids, and require accumulators to accommodate the change in the liquid metal volume and maintain sufficient subcooling to avoid boiling. This paper developed redundant and light-weight bellows-type accumulators with and without a mechanical spring, and compared the operating condition and mass of the accumulators for different types of liquid metal working fluids and operating temperatures: potassium, NaK-78, sodium and lithium loops of a total capacity of 50 liters and nominal operating temperatures of 840 K, 860 K, 950 K and 1340 K, respectively. The effects of using a mechanical spring and different structural materials on the design, operation and mass of the accumulators are also investigated. The structure materials considered include SS-316, Hastelloy-X, C-103 and Mo-14Re. The accumulator without a mechanical spring weighs 23 kg and 40 kg for a coolant subcooling of 50 K and 100 K, respectively, following a loss of the fill gas. The addition of a mechanical spring comes with a mass penalty, in favor of higher redundancy and maintaining a higher liquid metal subcooling.

Tournier, Jean-Michel; El-Genk, Mohamed S. [Institute for Space and Nuclear Power Studies, University of New Mexico, Albuquerque, NM 87131 (United States); Chemical and Nuclear Engineering Department, University of New Mexico, Albuquerque, NM 87131 (United States)

2006-01-20T23:59:59.000Z

49

Nickel assisted healing of defective graphene S. Karoui,1  

E-Print Network (OSTI)

nickel or transition-metal-carbide surfaces can pro- duce thin graphitic layers.5 However, for the most of graphene grown from a metallic substrate is investigated using tight-binding Monte Carlo simulations and 1000 C, using metallic substrates (such as Co, Ni, Ir, Ru) that catalyze the decomposition

Boyer, Edmond

50

Structural and electrochemical properties of nanostructured nickel silicides by reduction and silicification of high-surface-area nickel oxide  

SciTech Connect

Graphical abstract: Nanostructured nickel silicides have been synthesized by reduction and silification of high-surface-area nickel oxide, and exhibited remarkably like-noble metal property, lower electric resistivity, and ferromagnetism at room temperature. Highlights: Black-Right-Pointing-Pointer NiSi{sub x} have been prepared by reduction and silification of high-surface-area NiO. Black-Right-Pointing-Pointer The structure of nickel silicides changed with increasing reaction temperature. Black-Right-Pointing-Pointer Si doping into nickel changed the magnetic properties of metallic nickel. Black-Right-Pointing-Pointer NiSi{sub x} have remarkably lower electric resistivity and like-noble metal property. -- Abstract: Nanostructured nickel silicides have been prepared by reduction and silicification of high-surface-area nickel oxide (145 m{sup 2} g{sup -1}) produced via precipitation. The prepared materials were characterized by nitrogen adsorption, X-ray diffraction, thermal analysis, FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, magnetic and electrochemical measurements. The nickel silicide formation involves the following sequence: NiO (cubic) {yields} Ni (cubic) {yields} Ni{sub 2}Si (orthorhombic) {yields} NiSi (orthorhombic) {yields} NiSi{sub 2} (cubic), with particles growing from 13.7 to 21.3 nm. The nickel silicides are ferromagnetic at room temperature, and their saturation magnetization values change drastically with the increase of Si content. Nickel silicides have remarkably low electrical resistivity and noble metal-like properties because of a constriction of the Ni d band and an increase of the electronic density of states. The results suggest that such silicides are promising candidates as inexpensive yet functional materials for applications in electrochemistry as well as catalysis.

Chen, Xiao [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Zhang, Bingsen [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany)] [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany); Li, Chuang; Shao, Zhengfeng [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Su, Dangsheng [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany)] [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany); Williams, Christopher T. [Department of Chemical Engineering, Swearingen Engineering Center, University of South Carolina (United States)] [Department of Chemical Engineering, Swearingen Engineering Center, University of South Carolina (United States); Liang, Changhai, E-mail: changhai@dlut.edu.cn [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)

2012-03-15T23:59:59.000Z

51

Monolithic Nickel (II) Oxide Aerogels Using an Organic Epoxide: The Importance of the Counter Ion  

SciTech Connect

The synthesis and characterization of nickel (II) oxide aerogel materials prepared using the epoxide addition method is described. The addition of the organic epoxide propylene oxide to an ethanolic solution of NiCl{sub 2} 6H{sub 2}O resulted in the formation of an opaque light green monolithic gel and subsequent drying with supercritical CO{sub 2} gave a monolithic aerogel material of the same color. This material has been characterized using powder X-ray diffraction, electron microscopy, elemental analysis, and nitrogen adsorption/desorption analysis. The results indicate that the nickel (II) oxide aerogel has very low bulk density (98 kg/m{sup 3} ({approx}98 %porous)), high surface area (413 m{sup 2}/g), and has a particulate-type aerogel microstructure made up of very fine spherical particles with an open porous network. By comparison, a precipitate of Ni{sub 3}(NO{sub 3}){sub 2}(OH){sub 4} is obtained when the same preparation is attempted with the common Ni(NO{sub 3}){sub 2} 6H{sub 2}O salt as the precursor. The implications of the difference of reactivity of the two different precursors are discussed in the context of the mechanism of gel formation via the epoxide addition method. The synthesis of nickel (II) oxide aerogel, using the epoxide addition method, is especially unique in our experience. It is our first example of the successful preparation of a metal oxide aerogel using a metal divalent metal ion and may have implications for the application of this method to the preparation of aerogels or nanoparticles of other divalent metal oxides. To our knowledge this is the first report of a monolithic pure nickel (II) oxide aerogel materials.

Gash, A E; Satcher, J H; Simpson, R L

2004-01-13T23:59:59.000Z

52

A STUDY OF FUNDAMENTAL REACTION PATHWAYS FOR TRANSITION METAL ALKYL COMPLEXES. I. THE REACTION OF A NICKEL METHYL COMPLEX WITH ALKYNES. II. THE MECHANISM OF ALDEHYDE FORMATION IN THE REACTION OF A MOLYBDENUM HYDRIDE WITH MOLYBDENUM ALKYLS  

SciTech Connect

I. This study reports the rapid reaction under mild conditions of internal or terminal alkynes with methyl (acetyl~ acetonato) (triphenylphosphine) nickel (1) in either aromatic or ether solvents. In all cases vinylnickel products 2 are formed by insertion of the alkyne into the nickel=methyl bond. These complexes may be converted into a variety of organic products (e.g. alkenes, esters, vinyl halides) by treatment with appropriate reagents. Unsymmetrical alkynes give selectively the one regioisomer with the sterically largest substituent next to the nickel atom. In order to investigate the stereochemistry of the initial insertion, a x-ray diffraction study of the reaction of 1 with diphenylacetylene was carried out. This showed that the vinylnickel complex formed by overall trans insertion was the product of the reaction. Furthermore, subsequent slow isomerization of this complex, to a mixture of it and the corresponding cis isomer, demonstrated that this trans addition product is the kinetic product of the reaction. In studies with other alkynes, the product of trans addition was not always exclusively (or even predominantly) formed, but the ratio of the stereoisomers formed kinetically was substantially different from the thermodynamic ratio. Isotope labeling, added phosphine, and other experiments have allowed us to conclude that the mechanism of this reaction does involve initial cis addition. However, a coordinatively unsaturated vinylnickel complex is initially formed which can undergo rapid, phosphine-catalyzed cis-trans isomerization in competition with its conversion to the isolable phosphine-substituted kinetic reaction products. II. The reaction of CpMo(CO){sub 3}H (1a) with CpMo(CO){sub 3}R (2, R= CH{sub 3}, C{sub 2}H{sub 5}) at 50{degrees} C in THF gives the aldehyde RCHO and the dimers [CpMo(CO){sub 3}]{sub 2} (3a) and [CpMo(CO){sub 2}]{sub 2} (4a). Labeling one of the reactants with a methylcyclopentadienyl ligand it was possible to show that the mixed dimers MeCpMo(CO){sub 3}-(CO){sub 3}MoCp (3b) and MeCpMo(CO){sub 2}{triple_bond}(CO){sub 2}MoCp (4b) are the predominant kinetic products of the reaction. Additionally labeling the carbonyl ligands of 1a with {sup 13}CO led to the conclusion that all three of the carbonyl ligands in 1a end up in the tetracarbonyl dimers 4a if the reaction is carried out under a continuous purge of argon Trapping studies failed to find any evidence for the intermediacy of either [CpMo(CO){sub 3}]{sup -} or [CpMo(CO){sub 3}]{sup +} in this reaction. A mechanism is proposed that involves the initial migration of the alkyl ligand in 2 to CO forming an unsaturated acyl complex which reacts with 1a to give a binuclear complex containing a three center-two electron Mo-H-Mo bond. This complex then selectively looses a carbonyl from the acyl molybdenum, migrates the hydride to that same metal, and forms a metal-metal bond. This binuclear complex with the hydride and acyl ligands on one metal reductively eliminates aldehyde, and migrates a carbonyl ligand, to give 4a directly. The other product 3a is formed by addition of two molecules of free CO to 4a.

Huggins, John Mitchell

1980-06-01T23:59:59.000Z

53

A comparative evaluation of low-cycle fatigue behavior of type 316LN base metal, 316 weld metal, and 316LN/316 weld joint  

SciTech Connect

A comparative evaluation of the low-cycle fatigue (LCF) behavior of type 316LN base metal, carried out at 773 and 873 K. Total strain-controlled LCF tests were conducted at a constant strain rate of 3 {times} 10{sup {minus}3} s{sup {minus}1} with strain amplitudes in the range {+-}0.20 to {+-}1.0 pct. Weld pads with single V and double V configuration were prepared by the shielded metal-arc welding (SMAW) process using 316 electrodes for weld-metal and weld-joint specimens. Optical microscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) of the untested and tested samples were carried out to elucidate the deformation and the fracture behavior. The cyclic stress response of the base metal shows a very rapid hardening to a maximum stress followed by a saturated stress response. Weld metal undergoes a relatively short initial hardening followed by a gradual softening regime. Weld joints exhibit an initial hardening and a subsequent softening regime at all strain amplitudes, except at low strain amplitudes where a saturation regime is noticed. The initial hardening observed in base metal has been attributed to interaction between dislocations and solute atoms/complexes and cyclic saturation to saturation in the number density of slip bands. The 18-8 group of austenitic stainless steels, such as AISI type 316, 304, and their modified grades, finds applications as structural material for various components of the liquid-metal-cooled fast breeder reactor (LMFBR).

Valsan, M.; Sundararaman, D.; Sankara Rao, K.B.; Mannan, S.L. [Indira Gandhi Centre for Atomic Research, Tamil Nadu (India)

1995-05-01T23:59:59.000Z

54

Recovery of nickel and water from nickel electroplating wastewater by electrodialysis  

Science Journals Connector (OSTI)

Abstract Galvanic processes are one of the main activities contributing to metal discharges into the environment. The wastewater generated contains a high load of salts and metals that should be treated. In this work, the electrodialysis (ED) treatment was studied in order to concentrate and extract nickel (Ni) and its salts of effluents from the bright nickel electroplating process, aiming at water and concentrated solution recovery for reuse, and saving industrial and environmental resources. A laboratory-scale ED system was applied in the treatment of a synthetic effluent based on industrial bath composition. Properties of recovered water and nickel-concentrated solution have also been analyzed to verify their quality: Both solutions were used in the nickel-plating process in order to analyze their effects on the properties of electroplated pieces. It was found that ED treatment generates a very low conductivity solution, enabling its reuse as rinsewater, and a concentrated solution, which can be fed to the bath to recover volumes lost by evaporation and drag out during the nickel-electroplating process. The reuse does not cause any harm to the quality of plated pieces with regard to the visual aspects and corrosion resistance.

T. Benvenuti; R.S. Krapf; M.A.S. Rodrigues; A.M. Bernardes; J. Zoppas-Ferreira

2014-01-01T23:59:59.000Z

55

The metal abundance of circumnuclear star forming regions in early type spirals. Spectrophotometric observations  

E-Print Network (OSTI)

We have obtained long-slit observations in the optical and near infrared of 12 circumnuclear HII regions (CNSFR) in the early type spiral galaxies NGC 2903, NGC 3351 and NGC 3504 with the aim of deriving their chemical abundances. Only for one of the regions, the [SIII] $\\lambda$ 6312 \\AA was detected providing, together with the nebular [SIII] lines at $\\lambda\\lambda$ 9069, 9532 \\AA, a value of the electron temperature of T$_e$([SIII])= 8400$^{+ 4650}_{-1250}$K. A semi-empirical method for the derivation of abundances in the high metallicity regime is presented. We obtain abundances which are comparable to those found in high metallicity disc HII regions from direct measurements of electron temperatures and consistent with solar values within the errors. The region with the highest oxygen abundance is R3+R4 in NGC 3504, 12+log(O/H) = 8.85, about 1.5 solar if the solar oxygen abundance is set at the value derived by Asplund et al. (2005), 12+log(O/H)$_{\\odot}$ = 8.66$\\pm$0.05. Region R7 in NGC 3351 has the lowest oxygen abundance of the sample, about 0.6 times solar. In all the observed CNSFR the O/H abundance is dominated by the O$^+$/H$^+$ contribution, as is also the case for high metallicity disc HII regions. For our observed regions, however, also the S$^+$/S$^{2+}$ ratio is larger than one, contrary to what is found in high metallicity disc HII regions for which, in general, the sulphur abundances are dominated by S$^{2+}$/H$^+$...

Angeles I. Diaz; Elena Terlevich; Marcelo Castellanos; Guillermo F. Hagele

2007-09-08T23:59:59.000Z

56

Kinetic model of catalytic oxidation of carbon monoxide on nickel  

SciTech Connect

A mechanism is proposed for describing the previous disclosed multiplicity of equilibrium states in the oxidation of carbon monoxide on metallic nickel. In contrast to the known mechanism for oxidation of CO on platinum metals it includes a nonlinear stage of carbon monoxide adsorption and a linear stage of oxygen adsorption. A kinetic model has been obtained and stage velocity constants have been found, providing a basis for obtaining a quantitative agreement between the calculated and experimental relations between the reaction velocity and the reagent concentrations. Opinions are stated in relation to the causes for evolution of the CO oxidation reaction from platinum metals to nickel.

Pyatnitskii, Yu.I.; Ostapyuk, V.A.

1986-07-01T23:59:59.000Z

57

Metallic glass composition  

DOE Patents (OSTI)

A metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon carbon and phosphorous to which is added an amount of a ductility enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, Donald M. (Knoxville, TN); Koch, Carl C. (Raleigh, NC)

1986-01-01T23:59:59.000Z

58

ADSORPTIVE DESULFURIZATION OF LIQUID TRANSPORTATION FUELS VIA NICKEL-BASED ADSORBENTS FOR FUEL CELL APPLICATONS.  

E-Print Network (OSTI)

??The objectives of this work are to compare the adsorptive desulfurization capacity of several different types of nickel-based adsorbents and to identify ways for further… (more)

Clemons, Jennifer

2009-01-01T23:59:59.000Z

59

Steam reforming of carbo-metallic oils  

SciTech Connect

A process is disclosed for economically converting carbo-metallic oils to liquid fuel products by bringing a converter feed containing 650/sup 0/ F. + material characterized by a carbon residue on pyrolysis of at least about 1 and by containing at least about 4 ppm of nickel equivalents of heavy metals, including nickel, into contact with a particulate cracking catalyst in a progressive flow type reactor having an elongated conversion zone. The suspension of catalyst and feed in the reactor has a vapor residence time in the range of about 0.5 to about 10 seconds, a temperature of about 900/sup 0/ F. to about 1400/sup 0/ F. and a pressure of about 10 to about 50 pounds per square inch absolute for causing a conversion per pass in the range of about 50 to about 90 percent while depositing nickel on the catalyst and coke on the catalyst in amounts in the range of about 0.3 to about 3 percent by weight. The coke-laden catalyst is separated from the resulting stream of hydrocarbons and regenerated by combustion of the coke with oxygen, the regenerated catalyst being characterized by deposited nickel in at least a partially oxidized state and a level of carbon on catalyst of about 0.25 percent by weight or less. The regenerated catalyst is contacted with a reducing gas under reducing conditions sufficient to reduce at least a portion of the oxidized nickel deposits to a reduced state and the regenerated catalyst with reduced nickel deposits is recycled to the conversion zone for contact with fresh feed. Water is also introduced into the reactor conversion zone and the amount of water and the amount of reduced nickel on the recycled catalyst are sufficient to provide a steam reforming reaction so that hydrogen deficient components of the feed are converted to products having higher hydrogen to carbon ratios and the amount of feed converted to coke is reduced. The amount of deposited nickel on catalyst is preferably in the range from about 2,000 to about 20,000 ppm.

Myers, G.D.; Hettinger, W.P. Jr.; Kovach, S.M.; Zandona, O.J.

1984-02-21T23:59:59.000Z

60

Influences on the oceanic biogeochemical cycling of the hybrid-type metals, cobalt, iron, and manganese  

E-Print Network (OSTI)

Trace metal cycling is one of many processes that influence ocean ecosystem dynamics. Cobalt, iron, and manganese are redox active trace metal micro-nutrients with oceanic distributions that are influenced by both biological ...

Noble, Abigail Emery

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

E-Print Network 3.0 - active filler metal Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

. The dissolution of the base metal in the liquid filler metal could eventually shift the eutectic point, however... -temperature brazing with nickel-based filler ... Source:...

62

Thermoelectric material including a multiple transition metal-doped type I clathrate crystal structure  

DOE Patents (OSTI)

A thermoelectric material includes a multiple transition metal-doped type I clathrate crystal structure having the formula A.sub.8TM.sub.y.sub.1.sup.1TM.sub.y.sub.2.sup.2 . . . TM.sub.y.sub.n.sup.nM.sub.zX.sub.46-y.sub.1.sub.-y.sub.2.sub.- . . . -y.sub.n.sub.-z. In the formula, A is selected from the group consisting of barium, strontium, and europium; X is selected from the group consisting of silicon, germanium, and tin; M is selected from the group consisting of aluminum, gallium, and indium; TM.sup.1, TM.sup.2, and TM.sup.n are independently selected from the group consisting of 3d, 4d, and 5d transition metals; and y.sub.1, y.sub.2, y.sub.n and Z are actual compositions of TM.sup.1, TM.sup.2, TM.sup.n, and M, respectively. The actual compositions are based upon nominal compositions derived from the following equation: z=8q.sub.A-|.DELTA.q.sub.1|y.sub.1-|.DELTA.q.sub.2|y.sub.2- . . . -|.DELTA.q.sub.n|y.sub.n, wherein q.sub.A is a charge state of A, and wherein .DELTA.q.sub.1, .DELTA.q.sub.2, .DELTA.q.sub.n are, respectively, the nominal charge state of the first, second, and n-th TM.

Yang, Jihui (Lakeshore, CA); Shi, Xun (Troy, MI); Bai, Shengqiang (Shanghai, CN); Zhang, Wenqing (Shanghai, CN); Chen, Lidong (Shanghai, CN); Yang, Jiong (Shanghai, CN)

2012-01-17T23:59:59.000Z

63

A comprehensive review on the hydro metallurgical process for the production of nickel and copper powders by hydrogen reduction  

SciTech Connect

Production of nickel and copper powders from leach solutions and other aqueous streams by hydrogen reduction under pressure has been reviewed in the present paper. By optimising the optimum process condition, powders or composite materials of required specification could be produced from different types of acidic and alkaline solutions by coating nickel or copper powders on the secondary materials such as graphite, tungsten carbide and aluminium. The paper also highlights the kinetics of reduction and the use of various inorganic and organic additives to improve the quality of the powder on bench and commercial scale. Effect of various experimental factors such as pH of the solution, concentration of metals, particle size and nature of additives, operating condition of autoclave, etc. on the rate of reduction and quality of powder are also discussed.

Agrawal, A. [Non Ferrous Process Group, National Metallurgical Laboratory, Jamshedpur 831007 (India)]. E-mail: archana@nmlindia.com; Kumar, V. [Non Ferrous Process Group, National Metallurgical Laboratory, Jamshedpur 831007 (India); Pandey, B.D. [Non Ferrous Process Group, National Metallurgical Laboratory, Jamshedpur 831007 (India); Sahu, K.K. [Non Ferrous Process Group, National Metallurgical Laboratory, Jamshedpur 831007 (India)

2006-04-13T23:59:59.000Z

64

The Behaviour of Base Metals in Arc-Type Magmatic-Hydrothermal Systems Insights from Merapi Volcano,  

E-Print Network (OSTI)

zone stratovolcanoes provide important windows on the magmatic-hydrothermal processes at playThe Behaviour of Base Metals in Arc-Type Magmatic- Hydrothermal Systems Ā­ Insights from Merapi systems include a shallow magmatic reservoir (the porphyry stock), an overlying hydrothermal cell, its

Barnes, Sarah-Jane

65

Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /  

E-Print Network (OSTI)

active material for Li-ion battery, Fe2OF4. ElectrochemistryIron Fluoride, in a Li Ion Battery: A Solid-State NMR, X-raymaterials for Li-ion battery……………………………133 8.2. P2 type

Lee, Dae Hoe

2013-01-01T23:59:59.000Z

66

Mechanisms of Nickel Sorption on Pyrophyllite: Macroscopic and Microscopic Approaches  

E-Print Network (OSTI)

Mechanisms of Nickel Sorption on Pyrophyllite: Macroscopic and Microscopic Approaches Andre M of the sorption mechanisms of heavy metals on soil mineral surfaces is therefore of fundamental importance. This study examined Ni(Il) sorption mechanisms on pyrophyllite. The removal of Ni from solution was studied

Sparks, Donald L.

67

Nickel-cobalt alloy nanosheets obtained from reductive hydrothermal-treatment of nickel-cobalt hydroxide carbonate  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer An anionic layered material, nickel-cobalt hydroxide carbonate was synthesized. Black-Right-Pointing-Pointer Reductive hydrothermal-treatment of the layered precursor produced an alloy. Black-Right-Pointing-Pointer The alloy is a bimetallic nanostructured nickel-cobalt and a soft magnet material. -- Abstract: Nickel-cobalt hydroxide carbonate, a layered material was synthesized by the co-precipitation method using urea as precipitant agent. This anionic layered material with hexagonal structure is constructed from nickel and cobalt ions within the layers and carbonate anions between the layers. Nickel-cobalt alloy with pure cubic phase was obtained by a reductive hydrothermal-treatment of the layered precursor. Powder X-ray diffraction pattern and Fourier transform infrared spectroscopy confirmed the formation of the initial layered material and its metallic alloy product. That is, the nickel-cobalt alloy has really produced via a wet chemical route for the first time. Magnetic measurement revealed that the alloy sample is a soft magnet material.

Ghotbi, Mohammad Yeganeh, E-mail: yeganehghotbi@gmail.com [Nanomaterials and Nanotechnology Program, Ceramic Engineering Department, Faculty of Engineering, Malayer University, Malayer (Iran, Islamic Republic of); Jolagah, Ali; Afrasiabi, Hasan-ali [Nanomaterials and Nanotechnology Program, Ceramic Engineering Department, Faculty of Engineering, Malayer University, Malayer (Iran, Islamic Republic of)] [Nanomaterials and Nanotechnology Program, Ceramic Engineering Department, Faculty of Engineering, Malayer University, Malayer (Iran, Islamic Republic of)

2012-03-15T23:59:59.000Z

68

Hysteresis During Cycling of Nickel Hydroxide Active Material  

NLE Websites -- All DOE Office Websites (Extended Search)

Hysteresis During Cycling of Nickel Hydroxide Active Material Hysteresis During Cycling of Nickel Hydroxide Active Material Title Hysteresis During Cycling of Nickel Hydroxide Active Material Publication Type Journal Article Year of Publication 2001 Authors Srinivasan, Venkat, John W. Weidner, and John S. Newman Journal Electrochemical Society Volume 148 Start Page A969 Issue 9 Pagination A969-A980 Date Published 04/2001 Abstract The nickel hydroxide electrode is known to exhibit a stable hysteresis loop, with the potential on charge being higher than that on discharge at every state-of-charge ~SOC!.What we show here is that this loop created during a complete charge and discharge ~i.e., boundary curves! is not sufficient to define the state of the system. Rather, internal paths within the boundary curves ~i.e., scanning

69

Morphology and utilization of smooth hydrogen-evolving Raney nickel cathode coatings and porous sintered-nickel cathodes  

SciTech Connect

The utilization of the inner surfaces of hydrogen-evolving, porous, sintered-nickel electrodes and Raney nickel-coated electrodes was investigated and compared by steady-state voltammetry, impedance spectroscopy, coulometric determination of catalyst surface, and scanning electron microscopy. Porous, sintered-nickel electrodes are shown to be utilized only to approximately 10%. On the time average, roughly 90% of the inner surface of these electrodes is gas-blanketed. Nanoporous, smooth Raney nickel coatings are divided by micron-scale cracks. The essential part of the catalytically active electrode surface of Raney nickel coatings is represented by the walls of nanopores whose diameter is around 2 nm. Tafel slopes of less than {minus}120 mV/dec, namely, {minus}50 to {minus}70 mV/dec, are measured at 50 {micro}m thick smooth Raney nickel coatings. These low Tafel slopes are explained by an increasing degree of nanopore utilization with increasing current density rising from less than 0.6 to {approximately}10% if the overpotential rises from {minus}30 to {minus}120 mV. The effect can be modeled for nanopores and is at variance with known micropore behavior under concentration polarization known for increased Tafel slopes. From pore modeling it follows also that in another type of Raney nickel coatings, the so-called composite coating composed of micrometer particles of Raney nickel, different from smooth Raney nickel coatings, the utilization of that part of particles which is contacted by the electrolyte is almost 100%. Since, as in sintered electrodes, only 10% of the particle surface are expected not to be gas-blanketed, the total utilization of composite coated nanoporous catalysts amounts to {approximately} 10%, independent of overpotential and current density.

Rausch, S.; Wendt, H. [TH Darmstadt (Germany). Inst. fuer Chemische Technologie

1996-09-01T23:59:59.000Z

70

Magnetism of nickel  

Science Journals Connector (OSTI)

A previously developed theory of the magnetism of iron, based upon notion of a randomized exchange field, has now been applied to calculate the properties of nickel. We obtained a Curie temperature of 1200 K, about twice the observed value. The magnetization curve, the paramagnetic susceptibility (a Curie-Weiss law), and the distribution of spin lengths are also calculated. Both similarities and differences from the results of the iron calculations are noted.

J. Hubbard

1981-06-01T23:59:59.000Z

71

Biomonitoring on Carcinogenic Metals and Oxidative DNA Damage in a Cross-Sectional Study  

Science Journals Connector (OSTI)

...result of human activities such as mining, smelting, fossil fuel combustion, and industrial application of metals. The highest...production of stainless steel, high-nickel alloys, Ni-Cd batteries, and electronic components. A major fraction of nickel absorbed...

Hiltrud Merzenich; Andrea Hartwig; Wolfgang Ahrens; Detmar Beyersmann; Regina Schlepegrell; Martin Scholze; Jürgen Timm; and Karl-Heinz Jöckel

2001-05-01T23:59:59.000Z

72

Nanoparticle assembly via the dewetting of patterned thin metal lines: Understanding the instability mechanisms  

E-Print Network (OSTI)

Nanoparticle assembly via the dewetting of patterned thin metal lines: Understanding correlated nanoparticles from lithographically patterned pseudo-one-dimensional nickel lines. The evolution of the nickel line instabilities and nanoparticle formation with a correlated size and spacing was observed

Kondic, Lou

73

Material Flow Analysis of Scarce Metals: Sources, Functions, End-Uses and Aspects for Future Supply  

Science Journals Connector (OSTI)

First, it surveys the main sources of geologically scarce (byproduct) metals currently considered critical by one or other of several recent studies. ... One example is the use of phosphors based on scarce metals in LEDs now competing with older types of light for many applications such as automobile headlights and streetlights as well as interior lighting. ... (9) MFA has been used to study the industrial metabolism of major base metals (iron and steel, aluminum, copper, zinc, lead, and nickel) to quantify waste residuals generated by processing. ...

Laura Talens Peiró; Gara Villalba Méndez; Robert U. Ayres

2013-02-13T23:59:59.000Z

74

Reaction Condition Effects on Nickel Sorption Mechanisms in IlliteWater Suspensions E. J. Elzinga* and D. L. Sparks  

E-Print Network (OSTI)

Reaction Condition Effects on Nickel Sorption Mechanisms in IlliteĀ­Water Suspensions E. J. Elzinga by ions other than K, presumably leadingNickel sorption in illite suspensions was studied as a function the Ni sorption complexes formed. The formation of The different sites available for metal uptake

Sparks, Donald L.

75

Support and crystallite effects in CO hydrogenation on nickel  

SciTech Connect

The adsorption and reaction of carbon monoxide and hydrogen were studied on seven alumina-supported catalysts containing 0.5-23% nickel, four silica-supported catalysts containing 2.7-15% nickel, and 2.8 and 15% nickel on titanium oxide. On the silica and alumina-supported catalysts, hydrogen adsorption, per cent reduction of metal, carbon monoxide/hydrogen adsorption ratio, and methane yield increased with increasing metal dispersion, the methane turnover number decreased with increasing metal dispersion, and the carbon monoxide turnover number was not affected by dispersion. Hydrogen adsorption was suppressed by the titanium dioxide support. The suppression of hydrogen adsorption and the activity for carbon monoxide hydrogenation decreased as a function of support in the order TiO/sub 2/ > Al/sub 2/O/sub 3/ > SiO/sub 2/ and apparently depended on the strength of the electronic interaction of support and metal. The selectivity shifted to higher hydrocarbons as the metal dispersion increased and as the carbon monoxide/hydrogen adsorption ratio increased. Effects of preparation method are also reported.

Bartholomew, C.H.; Pannell, R.B.; Butler, J.L.

1980-10-01T23:59:59.000Z

76

CO2/oxalate Cathodes as Safe and Efficient Alternatives in High Energy Density Metal-Air Type Rechargeable Batteries  

E-Print Network (OSTI)

We present theoretical analysis on why and how rechargeable metal-air type batteries can be made significantly safer and more practical by utilizing CO2/oxalate conversions instead of O2/peroxide or O2/hydroxide ones, in the positive electrode. Metal-air batteries, such as the Li-air one, may have very large energy densities, comparable to that of gasoline, theoretically allowing for long range all-electric vehicles. There are, however, still significant challenges, especially related to the safety of their underlying chemistries, the robustness of their recharging and the need of supplying high purity O2 from air to the battery. We point out that the CO2/oxalate reversible electrochemical conversion is a viable alternative of the O2-based ones, allowing for similarly high energy density and almost identical voltage, while being much safer through the elimination of aggressive oxidant peroxides and the use of thermally stable, non-oxidative and environmentally benign oxalates instead.

Nemeth, Karoly

2013-01-01T23:59:59.000Z

77

Distribution Patterns of Metals Contamination in Sediments Based on Type Regional Development on the Intertidal Coastal Zones of the Persian Gulf, Iran  

Science Journals Connector (OSTI)

This study was performed to determine the variation of metals concentrations (Pb, Cd, Zn, and Cu) in surface sediments based on type region development from ten sites on the intertidal coastal zone of the Persian

Ali Kazemi; Alireza Riyahi Bakhtiari…

2012-01-01T23:59:59.000Z

78

Radiochemical Separation and Quantification of Tritium in Metallic Radwastes Generated from CANDU Type NPP - 13279  

SciTech Connect

As a destructive quantification method of {sup 3}H in low and intermediate level radwastes, bomb oxidation, sample oxidation, and wet oxidation methods have been introduced. These methods have some merits and demerits in the radiochemical separation of {sup 3}H radionuclides. That is, since the bomb oxidation and sample oxidation methods are techniques using heating at high temperature, the separation methods of the radionuclides are relatively simple. However, since {sup 3}H radionuclide has a property of being diffused deeply into the inside of metals, {sup 3}H which is distributed on the surface of the metals can only be extracted if the methods are applied. As an another separation method, the wet oxidation method makes {sup 3}H oxidized with an acidic solution, and extracted completely to an oxidized HTO compound. However, incomplete oxidized {sup 3}H compounds, which are produced by reactions of acidic solutions and metallic radwastes, can be released into the air. Thus, in this study, a wet oxidation method to extract and quantify the {sup 3}H radionuclide from metallic radwastes was established. In particular, a complete extraction method and complete oxidation method of incomplete chemical compounds of {sup 3}H using a Pt catalyst were studied. The radioactivity of {sup 3}H in metallic radwastes is extracted and measured using a wet oxidation method and liquid scintillation counter. Considering the surface dose rate of the sample, the appropriate size of the sample was determined and weighed, and a mixture of oxidants was added to a 200 ml round flask with 3 tubes. The flask was quickly connected to the distilling apparatus. 20 mL of 16 wt% H{sub 2}SO{sub 4} was given into the 200-ml round flask through a dropping funnel while under stirring and refluxing. After dropping, the temperature of the mixture was raised to 96 deg. C and the sample was leached and oxidized by refluxing for 3 hours. At that time, the incomplete oxidized {sup 3}H compounds were completely oxidized using the Pt catalysts and produced a stable HTO compound. After that, about a 20 ml solution was distilled in the separation apparatus, and the distillate was mixed with an ultimagold LLT as a cocktail solution. The solution in the vial was left standing for at least 24 hours. The radioactivity of {sup 3}H was counted directly using a liquid scintillation analyzer (Packard, 2500 TR/AB, Alpha and Beta Liquid Scintillation Analyzer). (authors)

Ahn, H.J.; Choi, K.C.; Choi, K.S.; Park, T.H.; Park, Y.J.; Song, K. [Korea Atomic Energy Research Institute, P.O. Box 105, Yuseong, Daejeon, 305-330 (Korea, Republic of)] [Korea Atomic Energy Research Institute, P.O. Box 105, Yuseong, Daejeon, 305-330 (Korea, Republic of)

2013-07-01T23:59:59.000Z

79

Synthesis of Graphene Layers from Metal-Carbon Melts: Nucleation and Growth Kinetics  

E-Print Network (OSTI)

both stable graphite and metal stable carbide formation. ForCarbide Eutectic in Nickel-Carbon Alloys The Physics of Metals andcarbide transition As it was explained in section 1.2 in some of metal-

Amini, Shaahin

2012-01-01T23:59:59.000Z

80

Nickel catalysts based on porous nickel for methane steam reforming  

Science Journals Connector (OSTI)

The influence of synthesis conditions on the phase composition and texture of porous nickel supports as plates with a magnesium oxide underlayer were investigated by X-ray diffraction, low-temperature nitrogen...

Z. A. Sabirova; M. M. Danilova; V. I. Zaikovskii; N. A. Kuzin…

2008-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Biosorption of Lead and Nickel by Biomass of Marine Algae  

E-Print Network (OSTI)

Biosorption of Lead and Nickel by Biomass of Marine Algae Z.R. Holan and B. Volesky" Department 22, 1993 Screening tests of different marine algae biomass types revealed a high passive biosorptive uptake of lead up to 270 mg Pb/g of biomass in some brown marine algae. Members of the order Fucales

Volesky, Bohumil

82

Mass transfer and kinetic phenomena at the nickel hydroxide electrode  

SciTech Connect

Thin-film (10 to 40 nm thickness) nickel hydroxide intercalation electrodes were constructed using an electroprecipitation technique. Cyclic voltammetry, potentiostatic step, and galvanostatic discharge experiments were performed and interpreted in terms of a macroscopic model treating the simultaneous mass transfer, kinetic, and thermodynamic phenomena occurring within the cell. The side reaction, oxygen evolution, exhibited irreversible Tafel behavior, with a proton concentration-dependent exchange current density of 4.5 {times} 10{sup {minus}9} [(c{sub 0} {minus} c)/c{sub 0}] A/cm{sup 2} on pure nickel hydroxide films, and a constant exchange current density of 4.5 {times} 10{sup {minus}9} A/cm{sup 2} on cobalt hydroxide-containing nickel hydroxide films. The apparent anodic transfer coefficient for the oxygen reaction is 0.49 on pure nickel hydroxide films and 0.42 on cobalt hydroxide-containing nickel hydroxide films. The apparent anodic transfer coefficient for the oxygen reaction is 0.49 on pure nickel hydroxide films and 0.42 on cobalt hydroxide-containing nickel hydroxide films. The intercalation reaction is described with a Butler-Volmer-type expression with a large, proton concentration-dependent exchange current density of 9.5 {times} 10{sup {minus}2} [c(c{sub 0} {minus} c)]{sup 1/2} A/cm{sup 2}, and anodic and cathodic apparent transfer coefficients of 0.5 for both electrode types. Here c and c{sub 0} have units of mol/cm{sup 3}. The proton diffusion coefficient in pure nickel hydroxide was found to depend on the proton concentration, with values ranging from 1.2 {times} 10{sup {minus}13} to 1.9 {times} 10{sup {minus}12} cm{sup 2}/s, with a concentration-averaged value of 3.417 {times} 10{sup {minus}13} cm{sup 2}/s. In cobalt hydroxide-containing nickel hydroxide, the values ranged from 2 {times} 10{sup {minus}13} to 1.9 {times} 10{sup {minus}12} cm{sup 2}/s, with a concentration-averaged value of 8.402 {times} 10{sup {minus}13} cm{sup 2}/s.

Ta, K.P.; Newman, J. [Lawrence Berkeley National Lab., CA (United States). Environmental Energy Technologies Div.]|[Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering

1998-11-01T23:59:59.000Z

83

Boronization of nickel and nickel clad materials for potential use in polymer electrolyte membrane fuel cells  

SciTech Connect

A new low-cost, nickel clad bipolar plate concept is currently being developed for use in polymer electrolyte membrane fuel cells. Reported in this paper are the details of a powder-pack boronization process that would be used to establish a passivation layer on the electrolyte exposed surfaces of the bipolar plate in the final stage of manufacture. Results from energy dispersive X-ray analysis, X-ray diffraction, and scanning electron microscopy indicate that under moderate boronization conditions a homogeneous Ni3B layer grows on the exposed surfaces of the nickel clad material, the thickness of which depends on the time and temperature of boronization according to a Wagner-type scale growth relationship. At higher temperatures and longer reaction times, a Ni2B overlayer forms on top of the Ni3B during boronization.

Weil, K. Scott; Kim, Jin Yong Y.; Xia, Gordon; Coleman, J. E.; Yang, Z Gary

2006-12-20T23:59:59.000Z

84

Magnetism in metal-organic capsules  

SciTech Connect

Nickel and cobalt seamed metal-organic capsules have been isolated and studied using structural, magnetic and computational approaches. Antiferromagnetic exchange in the Ni capsule results from coordination environments enforced by the capsule framework.

Atwood, Jerry L.; Brechin, Euan K; Dalgarno, Scott J.; Inglis, Ross; Jones, Leigh F.; Mossine, Andrew; Paterson, Martin J.; Power, Nicholas P.; Teat, Simon J.

2010-01-07T23:59:59.000Z

85

Improved thermoelectric performance in polycrystalline p -type Bi 2 Te 3 via an alkali metal salt hydrothermal nanocoating treatment approach  

Science Journals Connector (OSTI)

We report herein a proof-of-principle study of grain boundary engineering in the polycrystalline p -type Bi 2 Te 3 system. Utilizing the recently developed hydrothermal nanocoating treatment technique we fabricated an alkali-metal(s)-containing surface layer on the p -Bi 2 Te 3 bulk grain which in turn became part of the grain boundary upon hot pressing densification. Compared to the untreated bulk reference the dimensionless figure of merit Z T has been improved by ? 30 % in the Na-treated sample chiefly due to the reduced thermal conductivity and ? 38 % in the Rb-treated sample mainly owing to the improved power factor. The grain boundary phase provides a new avenue by which one can potentially decouple the otherwise inter-related electrical resistivity Seebeck coefficient and thermal conductivity within one thermoelectric material.

Xiaohua Ji; Jian He; Zhe Su; Nick Gothard; Terry M. Tritt

2008-01-01T23:59:59.000Z

86

Laser fusing of HVOF thermal sprayed alloy 625 on nickel-aluminum bronze  

SciTech Connect

A preliminary study has been conducted to determine the feasibility of laser fusing alloy 625 onto nickel-aluminum-bronze base metal. Laser fusing was performed by melting a pre-coated surface of alloy 625 that had been applied by the high velocity oxyfuel (HVOF) thermal spray process. The laser fusing was successful in producing a metallurigical bond between alloy 625 and the substrate. Minor modification to the heat-affected zone of the base metal was observed by microhardness measurements, and defect-free interfaces were produced between alloy 625 and nickel-aluminum-bronze by the process. The laser is a high energy density source that can be used for precise thermal processing of materials including surface modification. Laser fusing is the full or partial melting of a coating material that has been previously applied in some fashion to the substrate. Thermal spray coating of nickel-aluminum-bronze material with alloy 625 was conducted at the David Taylor Research Center. Nickel-aluminum-bronze specimens 2 x 3-in. by 1/2-in. thick were coated with alloy 25 utilizing the HVOF equipment. Coating thicknesses of approximately 0.014-in. (0.3 mm) were produced for subsequent laser fusing experiments. A preliminary study has been conducted to determine the feasibility of laser fusing a HVOF thermal sprayed alloy 625 coating onto nickel-aluminum-bronze base metal. Conclusions of this investigation were as follows: (1) Laser fusing was successful in producing a metallurgical bond between HVOF thermal sprayed alloy 625 and the nickel-aluminum-bronze. (2) Only minor microstructural modification to the heat-affected zone of the base metal ws observed by microhardness measurements. (3) Defect-free interfaces were produced between thermal sprayed alloy 625 and nickel-aluminum-bronze by laser fusing.

Brenna, R.T.; Pugh, J.L.; Denney, P.E. [and others

1994-12-31T23:59:59.000Z

87

A plant growth-promoting bacterium that decreases nickel toxicity in seedlings  

SciTech Connect

A plant growth-promoting bacterium, Kluyvera ascorbata SUD165, that contained high levels of heavy metals was isolated from soil collected near Sudbury, Ontario, Canada. The bacterium was resistant to the toxic effects of Ni{sup 2+}, Pb{sup 2+}, Zn{sup 2+}, and CrO{sub 4}{sup {minus}}, produced a siderophore(s), and displayed 1-aminocyclopropane-1-carboxylic acid deaminase activity. Canola seeds inoculated with this bacterium and then grown under gnotobiotic conditions in the presence of high concentrations of nickel chloride were partially protected against nickel toxicity. In addition, protection by the bacterium against nickel toxicity was evident in pot experiments with canola and tomato seeds. The presence of K. ascorbata SUD165 had no measurable influence on the amount of nickel accumulated per milligram (dry weight) of either roots or shoots of canola plants. Therefore, the bacterial plant growth-promoting effect in the presence of nickel was probably not attributable to the reduction of nickel uptake by seedlings. Rather, it may reflect the ability of the bacterium to lower the level of stress ethylene induced by the nickel.

Burd, G.I.; Dixon, D.G.; Glick, B.R. [Univ. of Waterloo, Ontario (Canada). Dept. of Biology

1998-10-01T23:59:59.000Z

88

Electron screening in nickel  

SciTech Connect

In order to further investigate electron screening phenomenon we studied proton induced nuclear reactions over an energy range from 1.35 to 3.08 MeV for different environments: Ni metal and NiO insulator. The measurements were based on observation of the {gamma}-ray yields of {sup 59,61,63,64,65}Cu and {sup 58,60,62}Ni. Also, we have studied the decay of {sup 61}Cu produced in the reaction {sup 60}Ni(p,{gamma}), in order to find a possible decay rate perturbation by atomic electrons and found a small difference in half-life for metallic compared to oxide environment, respectively. The present results clearly show that the metallic environment affects the fusion reactions at low energy and that it might also affect the decay rate.

Gajevic, Jelena; Lipoglavsek, Matej; Petrovic, Toni; Pelicon, Primoz [Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia); Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia) and Cosylab d.d, Teslova ulica 30, Ljubljana (Slovenia); Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia)

2012-11-20T23:59:59.000Z

89

Metal Dusting of Heat-Resistant Alloys  

E-Print Network (OSTI)

Metal dusting leads to disintegration of such alloys as iron and nickel-based into a “dust” of particulate metal, metal carbide, carbon, and/or oxide. It occurs in strongly carburising environments at 400-900°C. Literature survey has shown...

Al-Meshari, Abdulaziz I

90

Electron screening in nickel  

SciTech Connect

In order to investigate the interplay between nuclei and their surroundings we studied proton induced nuclear reactions over an energy range from 1.35 to 3.08 MeV for different environments: Ni metal and NiO insulator. The measurements were based on observation of the {gamma}-ray yields of {sup 59,61,63,64,65}Cu and {sup 58,60,62}Ni. The presented results clearly show that the metallic environment affects the fusion reactions at low energies.

Gajevic, Jelena; Lipoglavsek, Matej; Petrovic, Toni; Pelicon, Primoz [Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia); Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia) and Cosylab d.d, Teslova ulica 30, Ljubljana (Slovenia); Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia)

2012-10-20T23:59:59.000Z

91

Elemental composition of nickel silicide layers using thermal and fast neutrons  

SciTech Connect

Metal silicides are important contact materials used in the manufacture of semiconductor devices. The presence of impurities has been observed to alter or control the formation of the silicide during fabrication and to influence critically the thermal and electrical performance characteristics of the metal-semiconductor interface. The purpose of this investigation has been to use neutron activation analysis (NAAA), relying on both thermal and fast neutrons, to determine relative concentrations of nickel and impurity elements in nickel silicide/silicon systems. 5 refs., 2 figs., 1 tab.

McGuire, S.C.; Wong, K.; Silcox, J. (Cornell Univ., Ithaca, NY (United States))

1992-01-01T23:59:59.000Z

92

Method Of Bonding A Metal Connection To An Electrode Including A Core Having A Fiber Or Foam Type Structure For An Electrochemical Cell, An  

SciTech Connect

A method of bonding a metal connection to an electrode including a core having a fiber or foam-type structure for an electrochemical cell, in which method at least one metal strip is pressed against one edge of the core and is welded thereto under compression, wherein, at least in line with the region in which said strip is welded to the core, which is referred to as the "main core", a retaining core of a type analogous to that of the main core is disposed prior to the welding.

Loustau, Marie-Therese (Bordeaux, FR); Verhoog, Roelof (Bordeaux, FR); Precigout, Claude (Lormont, FR)

1996-09-24T23:59:59.000Z

93

Nickel crystallite thermometry during methanation  

SciTech Connect

A magnetic method to measure the average temperature of superparamagnetic nickel crystallites has been applied during CO methanation. The method takes advantage of the temperature dependence of the low field magnetization of such catalysts; however, the adsorption of carbon monoxide and the formation of surface carbon species complicate the interpretation of results. Calibrations to account for temperature change and the adsorption of reactants are described. The calibration for the effects of CO is based on the assumption that the interaction of CO with nickel is the same for methanation and disproportionation. Interphase heat transfer calculations based on the thermometric data compare favorably with previous results from ethane hyrogenolysis, and give no indication of microscopic temperature differences between the nickel crystallites and support.

Ludlow, D.K.; Cale, T.S.

1986-01-01T23:59:59.000Z

94

Metal-ceramic joint assembly  

DOE Patents (OSTI)

A metal-ceramic joint assembly in which a brazing alloy is situated between metallic and ceramic members. The metallic member is either an aluminum-containing stainless steel, a high chromium-content ferritic stainless steel or an iron nickel alloy with a corrosion protection coating. The brazing alloy, in turn, is either an Au-based or Ni-based alloy with a brazing temperature in the range of 9500 to 1200.degree. C.

Li, Jian (New Milford, CT)

2002-01-01T23:59:59.000Z

95

Studies on nickel nanoparticle attachment on surface modified carbon nanotubes by wet chemical method  

Science Journals Connector (OSTI)

Wet chemical method is a relatively simple technique, which has been used for attaching nickel nanoparticles homogeneously on multi-walled carbon nanotubes (MWCNT). The MWCNT was synthesised by catalytic chemical vapour deposition (CCVD) method. The surface of MWCNT was modified by treating with boiling conc. nitric acid. Carbon nanotubes dispersed in nickel nitrate solution were heat treated with particular heating rate of 8°C/min from room temperature to 100°C under argon atmosphere and soaked at this temperature for 1 h before heating to 500°C at 4C/min. The resultant product is found to be nanostructured nickel oxide attached to MWCNT. Subsequent reduction of the metal oxide in hydrogen atmosphere yielded nickel nanoparticles anchored to the surface of nanotubes. Chemical impregnation resulted in homogeneously dispersed nickel particles on the surface of oxidised MWCNT whereas in the case of unoxidised MWCNT uneven dispersion of nickel particle was observed. Results obtained on the characterisation of the products from XRD, SEM, TEM and EDX are presented. This simple method could allow large-scale production of functionalised MWCNT, which can be used as catalyst supports with high stability.

Jyoti Prakash; Ramani Venugopalan; D. Sathiyamoorthy

2010-01-01T23:59:59.000Z

96

Iron aluminides and nickel aluminides as materials for chemical air separation  

DOE Patents (OSTI)

The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.

Kang, Doohee (Macungie, PA)

1991-01-01T23:59:59.000Z

97

Iron aluminides and nickel aluminides as materials for chemical air separation  

DOE Patents (OSTI)

The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.

Kang, D.

1991-01-29T23:59:59.000Z

98

INFLUENCE OF TEMPERATURE ON NICKEL SORPTION ON CLAY MINERAL AND OXIDE SURFACES. K. G. Scheckel1  

E-Print Network (OSTI)

INFLUENCE OF TEMPERATURE ON NICKEL SORPTION ON CLAY MINERAL AND OXIDE SURFACES. K. G. Scheckel1. Introduction: Many kinetic studies have shown that sorption of metals on natural materials results in the for- tions ranged from 59 to 67 kJ mol-1 [2] while pesticide sorption on humic acid had an Ea value of 6.7 k

Sparks, Donald L.

99

Organic Thin Film Magnet of Nickel-Tetracyanoethylene  

SciTech Connect

Hybrid organic-inorganic materials consisting of a transition metal and an organic compound, TCNE form a unique class of organic magnets denoted by M(TCNE){sub x}(where M = transition metals, and TCNE = tetracyanoethylene). The organic thin film magnet of nickel-tetracyanoethylene, Ni(TCNE){sub x} is deposited on sputtered clean gold substrate using the physical vapor deposition (PVD) technique under ultra high vacuum (UHV) conditions at room temperature. X-ray photoelectron spectroscopy (XPS) has been used to investigate chemical and electronic properties of Ni(TCNE){sub x} film. XPS derived film thickness and stoichiometry are found to be 6 nm and 1:2 ratio between Ni and TCNE resulting Ni(TCNE){sub 2} film, respectively. In addition, XPS results do not show any signature of the presence of pure metallic Ni or Ni-clustering in the Ni(TCNE){sub x} film.

Bhatt, Pramod; Yusuf, S. M. [Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)

2011-07-15T23:59:59.000Z

100

Icosahedral structure in hydrogenated cobalt and nickel clusters  

SciTech Connect

Reactions with ammonia and with water are used to probe the geometrical structures of cobalt and nickel clusters that are saturated with hydrogen. Ammonia saturation experiments allow the determination of the number of primary NH{sub 3} binding sites on cluster surfaces, and this number shows a repeated minimization to values of 12 for many cluster sizes in the 50- to 200-atom size region. These sizes correspond to closed shells and subshells of icosahedra, suggesting that the ammoniated clusters have metal frameworks with icosahedral structure. The equilibrium reaction of the hydrogenated clusters with a single water molecule shows a pattern of local maxima in the cluster--water binding energy, with the maxima in most cases coming at clusters having one metal atom more than those showing minima in ammonia binding. This correlation suggests that nonammoniated clusters likewise have icosahedral structure, and is consistent with the nature of the metal--water interaction. Some of the larger clusters do not show clear evidence for icosahedral structure at room temperature, although they begin to do so at elevated temperature. Annealing experiments suggest that many of these clusters are icosahedral in their most stable configuration at room temperature, although the 147-atom nickel cluster is not. In general, hydrogenation enhances the icosahedral features in the ammonia and water binding patterns compared to those seen for bare clusters, and extends the cluster size region over which icosahedral structure is evident.

Klots, T.D.; Winter, B.J.; Parks, E.K.; Riley, S.J. (Chemistry Division, Argonne National Laboratory, Argonne, Illinois (USA))

1991-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

SAFT 4{1/2} inch nickel hydrogen battery cells  

SciTech Connect

SAFT Advanced Batteries has now produced over 400 high capacity 4{1/2} inch Nickel Hydrogen Battery Cells for flight programs. The 4.5 inch diameter, rabbit-ear cell design is designed to provide the anticipated energy required at the lowest practical weight. SAFT has incorporated into the design of the dry-powder nickel electrode, truly hermetic ceramic to metal seals, qualified terminal feedthroughs, high reliability mechanical design, composite pure platinum negative electrode, and zircar separator, plus more than 25 years experience in aerospace nickel cell technology, resulting in a 4{1/2} inch configuration with the 3{1/2} inch cell design carryover heritage. General performance requirements for GEO missions that SAFT cells meet are 15 years in orbit lifetime, 80% DOD, low mass to energy ratios, and flexible capacity by modifying number of electrodes in the stack. This design is qualified for geostationary orbits based on SAFT`s 3{1/2} inch qualification heritage, design verification, and cycling performed by customer Space Systems/LORAL in support of the INTELSAT VIIA and N-STAR flight programs.

Duquesne, D.; Lacout, B.; Sennet, A. [SAFT Advanced Batteries, Poitiers (France)

1995-12-31T23:59:59.000Z

102

Scha's Parallel Lines Bernhard Nickel  

E-Print Network (OSTI)

Scha's Parallel Lines Bernhard Nickel May 10, 2010 1 Introduction Scha (1981) has a famous example) The single lines run parallel to the double lines. 3 Code for Figure 1 \\begin{figure} \\centering \\setlength{\\unitlength}{.5in} \\begin{picture}(6,4) % first square \\put(0,4){\\line(1,0){4}}% \\put(0,1){\\line(1,0){4}}% \\put(0

Nickel, Bernhard

103

Unanticipated potential cancer risk near metal recycling facilities  

SciTech Connect

Metal recycling is an important growing industry. Prior to this study, area sources consisting of metal recycling facilities fell in a category of limited regulatory scrutiny because of assumed low levels of annual emissions. Initiating with community complaints of nuisance from smoke, dust and odor, the Houston Department of Health and Human Services (HDHHS) began a monitoring program outside metal recycler facilities and found metal particulates in outdoor ambient air at levels which could pose a carcinogenic human health risk. In a study of five similar metal recycler facilities which used a torch cutting process, air downwind and outside the facility was sampled for eight hours between 6 and 10 times each over 18 months using a mobile laboratory. Ten background locations were also sampled. Iron, manganese, copper, chromium, nickel, lead, cobalt, cadmium and mercury were detected downwind of the metal recyclers at frequencies ranging from 100% of the time for iron to 2% of the time for mercury. Of these metals, chromium, nickel, lead, cobalt, cadmium and mercury were not detected in any sample in the background. Two pairs of samples were analyzed for total chromium and hexavalent chromium to establish a ratio of the fraction of hexavalent chromium in total chromium. This fraction was used to estimate hexavalent chromium at all locations. The carcinogenic risk posed to a residential receptor from metal particulate matter concentrations in the ambient air attributed to the metal recyclers was estimated from each of the five facilities in an effort to rank the importance of this source and inform the need for further investigation. The total risk from these area sources ranged from an increased cancer risk of 1 in 1,000,000 to 6 in 10,000 using the 95th upper confidence limit of the mean of the carcinogenic metal particulate matter concentration, assuming the point of the exposure is the sample location for a residential receptor after accounting for wind direction and the number of shifts that could operate a year. Further study is warranted to better understand the metal air pollution levels in the community and if necessary, to evaluate the feasibility of emission controls and identify operational improvements and best management practices for this industry. This research adds two new aspects to the literature: identification of types and magnitude of metal particulate matter air pollutants associated with a previously unrecognized area source, metal recyclers and their potential risk to health. -- Highlights: • Air monitoring study in response to community complaints found metal contamination. • Metal recyclers found to potentially pose cancer from metal particulates • Chromium, nickel, cobalt and cadmium samples were detected in five metal recyclers. • These metals were not detected in background air samples. • Estimated increased cancer risk ranges from 1 in 1,000,000 to 8 in 10,000.

Raun, Loren, E-mail: raun@rice.edu [Department of Statistics, MS 138, Rice University, P.O. Box 1892, Houston, TX 77251-1892 (United States)] [Department of Statistics, MS 138, Rice University, P.O. Box 1892, Houston, TX 77251-1892 (United States); Pepple, Karl, E-mail: pepple.karl@epa.gov [State and Local Programs Group, Air Quality Policy Division, Office of Air Quality Planning and Standards, Policy, Analysis, and Communications Staff, Mail Drop C404-03, U.S. EPA, Research Triangle Park, NC 27711 (United States)] [State and Local Programs Group, Air Quality Policy Division, Office of Air Quality Planning and Standards, Policy, Analysis, and Communications Staff, Mail Drop C404-03, U.S. EPA, Research Triangle Park, NC 27711 (United States); Hoyt, Daniel, E-mail: hoyt.daniel@epa.gov [Air Surveillance Section, US EPA, Region 6, 6EN-AS, 1445 Ross Avenue, Dallas, TX 75202-2733 (United States)] [Air Surveillance Section, US EPA, Region 6, 6EN-AS, 1445 Ross Avenue, Dallas, TX 75202-2733 (United States); Richner, Donald, E-mail: Donald.Richner@houstontx.gov [Houston Department of Health and Human Services, Bureau of Pollution Control and Prevention, 7411 Park Place Blvd., Houston, TX 77087 (United States)] [Houston Department of Health and Human Services, Bureau of Pollution Control and Prevention, 7411 Park Place Blvd., Houston, TX 77087 (United States); Blanco, Arturo, E-mail: arturo.blanco@houstontx.gov [Pollution Control and Prevention, Environmental Health Division, Houston Department of Health and Human Services, 7411 Park Place Blvd., Houston, TX 77087 (United States)] [Pollution Control and Prevention, Environmental Health Division, Houston Department of Health and Human Services, 7411 Park Place Blvd., Houston, TX 77087 (United States); Li, Jiao, E-mail: jiao.li@rice.edu [Wiess School of Natural Science, Rice University, 6100 Main St., Houston, TX 77005 (United States)] [Wiess School of Natural Science, Rice University, 6100 Main St., Houston, TX 77005 (United States)

2013-07-15T23:59:59.000Z

104

Electrochemical, Structural and Surface Characterization of Nickel...  

NLE Websites -- All DOE Office Websites (Extended Search)

The interaction of antimony with the nickel-zirconia solid oxide fuel cell (SOFC) anode has been investigated. Tests with both anode-supported and electrolyte-supported...

105

Conflicting Roles Of Nickel In Controlling Cathode Performance...  

NLE Websites -- All DOE Office Websites (Extended Search)

Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries. Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries....

106

Biosensors Based on Carbon Nanotubes/Nickel Hexacyanoferrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

Biosensors Based on Carbon NanotubesNickel HexacyanoferrateGlucose Oxidase Nanocomposites. Biosensors Based on Carbon NanotubesNickel HexacyanoferrateGlucose Oxidase...

107

Moving Protons with Pendant Amines: Proton Mobility in a Nickel...  

NLE Websites -- All DOE Office Websites (Extended Search)

Moving Protons with Pendant Amines: Proton Mobility in a Nickel Catalyst for Oxidation of Hydrogen. Moving Protons with Pendant Amines: Proton Mobility in a Nickel Catalyst for...

108

Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine...  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A Predictive Model through Computations. Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A...

109

Metallic glass composition. [That does not embrittle upon annealing  

DOE Patents (OSTI)

This patent pertains to a metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon, carbon and phosphorous to which is added an amount of a ductility-enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, D.M.; Koch, C.C.

1984-09-14T23:59:59.000Z

110

Subcritical Noise Measurements with a Nickel-Reflected Plutonium Sphere  

SciTech Connect

Subcritical measurements were conducted with an a-phase plutonium sphere reflected by nickel hemishells using the 252Cf Source-Driven Noise Analysis (CSDNA) method to provide criticality safety benchmark data. Measured configurations included a bare plutonium sphere as well as the plutonium sphere reflected by the following nickel thicknesses: 1.27, 2.54, 3.81, 5.08, and 7.62 cm. A certain ratio of spectral quantities was measured for each configuration which varies linearly with the keff of the system. In addition, two types of Monte Carlo calculations were employed: a modified version of MCNP to calculate the ratio of spectral quantities and a KCODE calculation. From the measured and computed quantities the multiplication of each configuration can be approximated. A comprehensive uncertainty analysis was then performed that includes uncertainties in the geometry and materials present in the system in addition to the uncertainties in the method and nuclear data.

Jesson D. Hutchinson; John D. Bess

2009-11-01T23:59:59.000Z

111

Electrodialysis Treatment of Nickel Wastewater  

Science Journals Connector (OSTI)

The galvanic processes are one of the main activities contributing to metal discharges into the environment. A large volume of wastewater is generated that contains a high load of salts and metals and it must be ...

Tatiane Benvenuti; Marco Antōnio Siqueira Rodrigues…

2014-01-01T23:59:59.000Z

112

Braze material for joining ceramic to metal and ceramic to ceramic surfaces and joined ceramic to metal and ceramic to ceramic article  

DOE Patents (OSTI)

An improved active metal braze filler material is provided in which the coefficient of thermal expansion of the braze filler is more closely matched with that of the ceramic and metal, or two ceramics, to provide ceramic to metal, or ceramic to ceramic, sealed joints and articles which can withstand both high temperatures and repeated thermal cycling without failing. The braze filler material comprises a mixture of a material, preferably in the form of a powder, selected from the group consisting of molybdenum, tungsten, silicon carbide and mixtures thereof, and an active metal filler material selected from the group consisting of alloys or mixtures of nickel and titanium, alloys or mixtures of nickel and zirconium, alloys or mixtures of nickel, titanium, and copper, alloys or mixtures of nickel, titanium, and zirconium, alloys or mixtures of niobium and nickel, alloys or mixtures of niobium and zirconium, alloys or mixtures of niobium and titanium, alloys or mixtures of niobium, titanium, and nickel, alloys or mixtures of niobium, zirconium, and nickel, and alloys or mixtures of niobium, titanium, zirconium, and nickel. The powder component is selected such that its coefficient of thermal expansion will effect the overall coefficient of thermal expansion of the braze material so that it more closely matches the coefficients of thermal expansion of the ceramic and metal parts to be joined. 3 figures.

Hunt, T.K.; Novak, R.F.

1991-05-07T23:59:59.000Z

113

Braze material for joining ceramic to metal and ceramic to ceramic surfaces and joined ceramic to metal and ceramic to ceramic article  

DOE Patents (OSTI)

An improved active metal braze filler material is provided in which the coefficient of thermal expansion of the braze filler is more closely matched with that of the ceramic and metal, or two ceramics, to provide ceramic to metal, or ceramic to ceramic, sealed joints and articles which can withstand both high temperatures and repeated thermal cycling without failing. The braze filler material comprises a mixture of a material, preferably in the form of a powder, selected from the group consisting of molybdenum, tungsten, silicon carbide and mixtures thereof, and an active metal filler material selected from the group consisting of alloys or mixtures of nickel and titanium, alloys or mixtures of nickel and zirconium, alloys or mixtures of nickel, titanium, and copper, alloys or mixtures of nickel, titanium, and zirconium, alloys or mixtures of niobium and nickel, alloys or mixtures of niobium and zirconium, alloys or mixtures of niobium and titanium, alloys or mixtures of niobium, titanium, and nickel, alloys or mixtures of niobium, zirconium, and nickel, and alloys or mixtures of niobium, titanium, zirconium, and nickel. The powder component is selected such that its coefficient of thermal expansion will effect the overall coefficient of thermal expansion of the braze material so that it more closely matches the coefficients of thermal expansion of the ceramic and metal parts to be joined.

Hunt, Thomas K. (Ann Arbor, MI); Novak, Robert F. (Farmington Hills, MI)

1991-01-01T23:59:59.000Z

114

The Fate of Heavy Metals in Highway Stormwater Runoff: The Characterization of a Bioretention Basin in the Midwest  

E-Print Network (OSTI)

The usual wear of automobiles and road surfaces deposits numerous environmental pollutants on roadways and parking lots, including heavy metals such as copper, zinc, lead, nickel and cadmium. During rainfall and snow events, these metals are washed...

Lacy, Sarah

2009-01-01T23:59:59.000Z

115

NICKEL/YTTRIA-STABILISED ZIRCONIA CERMET ANODES  

E-Print Network (OSTI)

NICKEL/YTTRIA-STABILISED ZIRCONIA CERMET ANODES FOR SOLID OXIDE FUEL CELLS SĆøren Primdahl #12;ii Primdahl, SĆøren Nickel/yttria-stabilised zirconia cermet anodes for solid oxide fuel cells Thesis FOR SOLID OXIDE FUEL CELLS PROEFSCHRIFT ter verkrijging van de graad van doctor aan de Universiteit Twente

116

Parasitic corrosion-resistant anode for use in metal/air or metal/O/sub 2/ cells  

DOE Patents (OSTI)

A consumable metal anode is described which is used in refuelable electrochemical cells and wherein at least a peripheral edge portion of the anode is protected against a corrosive alkaline environment of the cell by the application of a thin metal coating, the coating being formed of metals such as nickel, silver, and gold.

Joy, R.W.; Smith, D.F.

1982-09-20T23:59:59.000Z

117

Hard metal composition  

DOE Patents (OSTI)

A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

Sheinberg, H.

1983-07-26T23:59:59.000Z

118

Hard metal composition  

DOE Patents (OSTI)

A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

Sheinberg, Haskell (Los Alamos, NM)

1986-01-01T23:59:59.000Z

119

The structure of nickel clusters  

SciTech Connect

The reactions of nickel clusters with ammonia and with water are used to probe cluster geometrical structure. Ammonia uptake experiments allow the determination of the number of preferred binding sites on cluster surfaces. This number shows pronounced minima in the 50- to 116- atom size range for many of the cluster sizes that appear as magic numbers in mass spectra of rare gas clusters. Since these magic numbers arise from closings of shells and subshells of the Mackay icosahedra, the correlation suggests that ammoniated nickel clusters in this size region also have icosahedral structure. Similar structure is found for ammoniated clusters smaller than {similar to}30 atoms, but is not seen for room temperature clusters in the vicinity of the third shell closing at 147 atoms. Icosahedral features do appear for the larger clusters at elevated temperatures. For many clusters above 50 atoms, prolonged exposure to ammonia causes a conversion from the icosahedral structure to some other structure that binds more ammonia molecules, and often the two structures are seen together. The equilibrium reaction of a single water molecule with the bare clusters probes the strength of the cluster--water bond. Enhanced water adsorption is often seen for clusters one atom larger than those showing minima in ammonia uptake, suggesting that these bare clusters likewise have icosahedral structure. The reasons for minima in ammonia uptake and maxima in water binding are discussed.

Parks, E.K.; Winter, B.J.; Klots, T.D.; Riley, S.J. (Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439 (US))

1991-02-01T23:59:59.000Z

120

Magnetism in iron and nickel  

Science Journals Connector (OSTI)

The fluctuating local band theory of itinerant electron ferromagnetism in nickel and iron is investigated with the use of first-principles numerical calculations. In this theory the excitations predominantly responsible for the phase transition are fluctuations in the direction of local magnetization. The free energy in the presence of a fluctuation is evaluated numerically in the approximation that this direction changes in time and space slowly enough to justify the use of the static approximation and second-order perturbation theory. The energies and wave functions used to incorporate the band and wavevector dependence of the relevant interaction matrix elements were obtained by Slater-Koster fits to earlier ab initio self-consistent energy bands. Results for nickel and iron are obtained in terms of an effective classical Heisenberg exchange. This is compared with other theoretical calculations and available experimental data. From the numerical results, it is concluded that both quantum effects (the time dependence of the exchange field) and local-field effects are important to account for the transition temperature TC.

C. S. Wang; R. E. Prange; V. Korenman

1982-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

The effect of iron dilution on strength of nickel/steel and Monel/steel welds  

SciTech Connect

The weld strength, as a function of iron content, for nickel/steel and Monel/steel welds was determined. Samples were prepared using a Gas Metal Arc (GMAW) automatic process to weld steel plate together with nickel or Monel to produce a range of iron contents typical of weld compositions. Tensile specimens of each iron content were tested to obtain strength and ductility measurements for that weld composition. Data indicate that at iron contents of less than 20% iron in a nickel/steel weld, the weld fails at the weld interface, due to a lack of fusion. Between 20% and 35% iron, the highest iron dilution that could be achieved in a nickel weld, the welds were stronger than the steel base metal. This indicates that a minimum amount of iron dilution (20%) is necessary for good fusion and optimum strength. On the other hand for Monel/steel welds, test results showed that the welds had good strength and integrity between 10% and 27% iron in the weld. Above 35% iron, the welds have less strength and are more brittle. The 35% iron content also corresponds to the iron dilution in Monel welds that has been shown to produce an increase in corrosion rate. This indicates that the iron dilution in Monel welds should be kept below 35% iron to maximize both the strength and corrosion resistance. 2 refs., 6 figs., 3 tabs.

Fout, S.L.; Wamsley, S.D.

1983-03-28T23:59:59.000Z

122

Kinetics of methanation on nickel catalysts  

SciTech Connect

Extensive steady-state and transient measurements of the disproportionation of carbon monoxide, the hydrogenation of deposited carbon, and methanation of carbon monoxide were performed over 2 and 10% nickel on silica support. The results indicated that the methanation of carbon monoxide involves competitively adsorbed species; that the reaction is nearly zero order in carbon monoxide at 0.1-0.5 atm CO and 1 atm H/sub 2/, but negative at higher CO partial pressures and that it becomes less negative with increasing temperature or increasing hydrogen pressure; and that the reaction order with respect to hydrogen changes from 0.5 to 1.0 with increasing CO pressure and decreasing H/sub 2/ pressure. A reaction mechanism is proposed which consists of the molecular adsorption of CO, the dissociative adsorption of H/sub 2/, dissociation of the surface CO species, and reaction of two adsorbed hydrogen atoms with the oxygen; and a multistep hydrogenation and desorption process for the adsorbed carbon. The dissociation and reaction of adsorbed CO is probably the rate-limiting step. The kinetic behavior is best represented with the assumption of a heterogeneous catalyst surface, containing three types of sites of widely varying activity.

Ho, S.V.; Harriott, P.

1980-08-01T23:59:59.000Z

123

DIVISION S-2--SOIL CHEMISTRY Dissolution Kinetics of Nickel Surface Precipitates on Clay Mineral and Oxide Surfaces  

E-Print Network (OSTI)

sorption under ambient environmental conditions. in brucite-like octahedral sheets with anions in the inter, brucite-like metal hydroxide precipi-percentage of total Ni sorption, decreased from 96 to 30% and 23 at pH 4 and 6. Nickel de-brucite-like hydroxide layers, (ii) Si-for-NO3 exchange in the interlay

Sparks, Donald L.

124

Radioactive Nickel-63 - ORNL Neutron Sciences  

NLE Websites -- All DOE Office Websites (Extended Search)

Making Radioactive Nickel-63 Making Radioactive Nickel-63 ORNL-Supplied Nickel-63 Enables High-Sensitivity Explosives, Chemical Weapons, and Narcotics Detectors at Airports Explosives and narcotics detector. Detectors based on ion mobility spectrometry using ORNL 63Ni can now satisfy enhanced Homeland Security requirements at airports and other sensitive locations. When Transportation Security Administration (TSA) inspectors swipe a cloth over your luggage and then place it in an analyzer to check for explosives residue, they are using a device containing 63Ni, a radioactive isotope of nickel, made at ORNL. ORNL is the exclusive producer for 63Ni in North America and perhaps worldwide. "Our only competition would probably be Russia. They have high-flux research reactors and may well be supplying the material also,"

125

Elastic moduli of nickel and iron aluminides  

E-Print Network (OSTI)

ELASTIC MODULI OF NICKEL AND IRON ALUMINIDES A Thesis by SREEDHAR MAN JIGANI Submitted to the Oifice of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1993... Major Subject: Mechanical Engineering ELASTIC MODULI OF NICKEL AND IRON ALUMINIDES A Thesis by SREEDHAR MAN JIGANI Submitted to Texas AkM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved...

Manjigani, Sreedhar

2012-06-07T23:59:59.000Z

126

Ligand effects on the X-ray absorption of a nickel porphyrin complex: a simulation study  

E-Print Network (OSTI)

.elsevier.com/locate/chemphys #12;where W l PP stands for the atomic absorption spectrum for the lth site: W l PP Ā¼ 1 2 1 X2 x R ZLigand effects on the X-ray absorption of a nickel porphyrin complex: a simulation study Luke Abstract We present a simulation of the X-ray absorption near-edge spectrum (XANES) of the metal porphyrin

Mukamel, Shaul

127

Die wasserstoffspeicherkapazität des Raney-Nickels  

Science Journals Connector (OSTI)

Zusammenfassung Die elektrochemisch be- und entladbare Wasserstoffkapazität des Raney-Nickels hängt auch bei konstanter Oxydbedeckung und unverändertem Al-Gehalt stark von der Vorbehandlung ab. BET-Messungen ergeben, daß der Wasserstoffgehalt proportional zur BET-Oberfläche des Katalysators ist. Das Raney-Nickel speichert ca 0,00072 Ah/m2 bzw. 1 H-Atom pro Ni-Oberflächenatom. Die elektrochemisch reversible Speicherung von Wasserstoff mit Raney-Nickel kann deshalb als Adsorption des Wasserstoffs an der Oberfläche des Katalysators während der Beladung und als Oxydation der Wasserstoff-Bedeckung während der Entladung betrachtet werden. The electrochemically chargeable and dischargeable hydrogen capacity of the Raney-nickel catalyst was investigated at constant state of oxidation and constant aluminium concentration as a function of pretreatment. The present extensive BET measurements indicate that the amount of hydrogen sorbate is exactly proportional to the BET surface within the limit of measuring and calculating accuracy; quantitatively the relation is 0,00072 Ah/m2, corresponding to 1 H-atom per 1 Ni-atom of the inner surface. Thus the reversible part of the hydrogen sorption capacity of Raney nickel may be explained by sorption of hydrogen at the nickel BET surface, and subsequent anodic oxidation of this hydrogen coating layer under discharge.

H.H. Ewe

1972-01-01T23:59:59.000Z

128

Manual HVOF thermal spray repair of nickel aluminum bronze castings  

SciTech Connect

Manual high velocity oxyfuel (HVOF) thermal spray repairs were accomplished on a large nickel aluminum bronze propeller castings. The repairs were done on three different configurations of surface defects of up to 100 square inches and as deep as 90 mils. Nickel aluminum bronze alloy powder, sieve sized for the HVOF process, was sprayed. High quality, high coating density, repairs were achieved even on porous areas of the castings. Prior to performance of the repairs, a procedure was qualified in accordance with MIL-STD-1687 and a mock-up simulating the repair was produced. After HVOF spraying of the mock-up, the sprayed surface was sanded, milled, and drilled to determine how finishing of the actual castings would be done. After successful procedure qualification, the HVOF equipment was moved to the job site, metal masking was devised for the spray areas and grit blasting and manual HVOF spraying was done. Results of HVOF coating chemical analyses, bend tests, coating tensile bond strength tests, coating microscopic examinations, and mock-up evaluations are reported along with the spray procedures and techniques used in the repairs.

Brenna, R.T.; McCaw, R.L.; Pugh, J.L.

1994-12-31T23:59:59.000Z

129

Weldability and microstructure development in nickel-base superalloys  

SciTech Connect

The integrity of nickel-base superalloy single-crystal welds depends on the weld cracking tendency, weld metal dendrite selection process, stray crystal formation, and macro- and microstructure development. These phenomena have been investigated in commercial nickel-base superalloy single crystal welds. During electron beam and laser beam welding, transverse and longitudinal weld cracking occurred. However, the weld cracking tendency was reduced with preheating. Most of the dendritic growth pattern development in these welds can be explained by a geometric model. However, the welds also contained misoriented stray crystals, which were frequently associated with weld cracks. The formation of stray crystals was related to thermal and constitutional supercooling effects. Fine-scale elemental partitioning between {gamma} and {gamma}{prime} phase was measured with atom-probe field-ion microscopy. Marked differences in partitioning characteristics in two welds were observed and are related to differences in cooling rates. In this paper, the modeling tools available to describe the above are reviewed.

David, S.A.; Babu, S.S.; Vitek, J.M.

1997-11-01T23:59:59.000Z

130

Effect of modifier Pd metal on hydrocracking of polyaromatic compounds over Ni-loaded Y-type zeolite and its application as hydrodesulfurization catalysts  

SciTech Connect

Coal tar obtained from coal carbonization is a treasure of polyaromatic hydrocarbons, where more than 400 kinds of aromatic compounds are found to be contained. The development of new catalysts being able to convert these aromatics into mono or diaromatic compounds is one of objectives for utilization of polyaromatics. Hydrocracking of polyaromatic compounds is believed to proceed via formation of terminal-naphthenic ring of starting aromatic compounds, followed by cleavage of the naphthenic ring to produce alkylated aromatic compounds which has less numbers of ring than starting aromatics. Accordingly, hydrogenation of aromatic rings and cracking of resulting naphthenic rings are key steps of hydrocracking reaction, so that dual functional catalysts such as metal-supported acid catalysts are considered to be one of the best catalysts. Zeolite has controlled pore structures and strong acidity enough to crack naphthenic rings, being characteristics in exchanging metal species with ease. We have been studying the hydrocracking of polyaromatic compounds over Ni-loaded zeolite catalysts (ZSM-5, mordenite, and Y-type) and found the fact that pore size of zeolite exerts an interesting effect on product distribution. We also conducted computer-simulation for diffusion phenomena of the polyaromatic hydrocarbons in the pore of these zeolites and found that diffusion ability of the substrate affects strongly the product distributions Recently we found that modifying of Ni-loaded Y-type zeolite by Pd-loading enhanced hydrocracking ability of the catalyst. In this report, we would like to refer to the results of both hydrocracking reaction of pyrene and hydrodesulfurization of dibenzothiophene using Pd-modified Ni-loaded Y-type zeolite.

Wada, Takema; Murata, Satoru; Nomura, Masakatsu [Osaka Univ. (Japan)

1995-12-31T23:59:59.000Z

131

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Title X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Publication Type Journal Article LBNL Report Number LBNL-50574 Year of Publication 2002 Authors Richardson, Thomas J., Baker Farangis, Jonathan L. Slack, Ponnusamy Nachimuthu, Rupert C. C. Perera, Nobumichi Tamura, and Michael D. Rubin Journal Journal of Alloys and Compounds Volume 356-357 Start Page 204 Pagination 204-207 Date Published 08/2003 Keywords A. hydrogen storage materials, NEXAFS, thin film s; C. EXAFS, x-ray diffraction Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption spectroscopy. Mg K-edge and Ni, Co, and Ti L-edge spectra reflect both reversible and irreversible changes in the metal environments. A significant shift in the nickel L absorption edge shows it to be an active participant in hydride formation. The effect on cobalt and titanium is much less dramatic, suggesting that these metals act primarily as catalysts for formation of magnesium hydride.

132

Development of a metal hydride electrode waste treatment process  

SciTech Connect

Manufacturing residues of metal hydride electrodes for nickel - metal hydride batteries were chemically processed to recover the metal part and heat treated for the organic part. Chemical recovery yielded Ni-Co alloy after electrolysis of the solution and hydroxides of other metal, mainly rare earths. The organic part, pyrolyzed at 700 C, led to separation between carbon and fluorinated matter. Infrared coupling at the output of the pyrolysis furnace was used to identify the pyrolysis gases.

Bianco, J.C.; Martin, D.; Ansart, F.; Castillo, S.

1999-12-01T23:59:59.000Z

133

Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1987-01-01T23:59:59.000Z

134

Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids (shale oil, SRC, etc.) by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20/sup 0/ to 100/sup 0/C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, R.H.

1985-05-17T23:59:59.000Z

135

Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20 to 100 C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, R.H.

1987-04-21T23:59:59.000Z

136

Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1986-01-01T23:59:59.000Z

137

Inspection of Nickel Alloy Welds: Results from Five Year International Program  

SciTech Connect

The U.S. Nuclear Regulatory Commission established and coordinated the international Program for the Inspection of Nickel alloy Components (PINC). The goal of PINC was to evaluate the capabilities of various nondestructive examination (NDE) techniques to detect and characterize primary water stress corrosion cracking (PWSCC) in dissimilar metal welds. Round-robin results showed that a combination of conventional and phased-array ultrasound provide the highest performance for flaw detection and depth sizing in dissimilar metal piping welds. The effective detection of flaws in bottom-mounted instrumentation penetrations by eddy current and ultrasound shows that it may be possible to reliably inspect these components in the field.

Prokofiev, Iouri; Cumblidge, Stephen E.; Doctor, Steven R.

2011-06-23T23:59:59.000Z

138

Production of hard metal-like wear protection coatings by CO2 laser cladding  

Science Journals Connector (OSTI)

Protective coatings with hard metal-like wear properties could be obtained by laser beam surfacing of powder mixtures consisting of coarse-grained tungsten carbide and a nickel or cobalt hard alloy. The micros...

A. Techel; A. Luft; A. Müller; S. Nowotny

1995-12-01T23:59:59.000Z

139

Steam-methane reforming at low temperature on nickel-based catalysts  

Science Journals Connector (OSTI)

Abstract In this work, we report the activity results obtained in steam-methane reforming (SMR) at 500 and 600 °C using four nickel-based catalysts: (a) Ni/?-Al2O3 and Ni/SiO2, prepared by incipient wetness impregnation method and (b) Ni–Zn–Al and Ni–Mg–Al, prepared by coprecipitation method. In all of the samples, the nickel load ranged between 7% and 9%. The catalytic activity in SMR at steady state followed the pattern: Ni–Mg–Al ? Ni–Zn–Al > Ni/?-Al2O3 > Ni/SiO2. According to characterization results, the interaction between Ni2+ species and support in precursor oxides was stronger in Ni–Mg–Al and Ni–Zn–Al than in Ni/?-Al2O3 and Ni/SiO2. After activation in H2 flow, large metal nickel particles with low or none interaction with the support were obtained in the case of Ni/?-Al2O3 and Ni/SiO2. On the contrary, small metal particles, between 3 and 6 nm, in high interaction with support were obtained in Ni–Zn–Al and Ni–Mg–Al catalysts. The metal phase formed in Ni–Mg–Al and Ni–Zn–Al was the most active and resistant to sintering under reaction conditions at T ? 600 °C. It was also found that carbon nanofibers were formed on Ni/?-Al2O3, Ni/SiO2 and Ni–Mg–Al catalysts during SMR at 600 °C. The amount and diameter of nanofibers formed on Ni–Mg–Al were lower than on catalysts prepared by impregnation method, which is in agreement with the relative sizes of metal nickel particles in each case. Amazingly, no filamentary carbon was detected on the used Ni–Zn–Al sample: only amorphous coke in low amounts was formed. This was attributed to the proper interaction of small metal nickel particles with the non-stoichiometric zinc aluminate-like phase formed after thermal treatments of catalyst precursor.

Marķa A. Nieva; Marķa M. Villaverde; Antonio Monzón; Teresita F. Garetto; Alberto J. Marchi

2014-01-01T23:59:59.000Z

140

Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel...  

NLE Websites -- All DOE Office Websites (Extended Search)

Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas. Reversible Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen...

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Carcinogenicity of Nickel Subsulfide for Respiratory Tract Mucosa  

Science Journals Connector (OSTI)

...Biology Division, Oak Ridge National Laboratory, P. O. Box Y, Oak Ridge, Tenn. 37830...cancers in nickel workers. Carcinogenicity...cancers in nickel workers. | Journal Article...Biology Division, Oak Ridge National Laboratory...

Tsutomu Yarita and Paul Nettesheim

1978-10-01T23:59:59.000Z

142

Advanced technologies for decontamination and conversion of scrap metal  

SciTech Connect

In October 1993, Manufacturing Sciences Corporation was awarded DOE contract DE-AC21-93MC30170 to develop and test recycling of radioactive scrap metal (RSM) to high value and intermediate and final product forms. This work was conducted to help solve the problems associated with decontamination and reuse of the diffusion plant barrier nickel and other radioactively contaminated scrap metals present in the diffusion plants. Options available for disposition of the nickel include decontamination and subsequent release or recycled product manufacture for restricted end use. Both of these options are evaluated during the course of this research effort. work during phase I of this project successfully demonstrated the ability to make stainless steel from barrier nickel feed. This paved the way for restricted end use products made from stainless steel. Also, after repeated trials and studies, the inducto-slag nickel decontamination process was eliminated as a suitable alternative. Electro-refining appeared to be a promising technology for decontamination of the diffusion plant barrier material. Goals for phase II included conducting experiments to facilitate the development of an electro-refining process to separate technetium from nickel. In parallel with those activities, phase II efforts were to include the development of the necessary processes to make useful products from radioactive scrap metal. Nickel from the diffusion plants as well as stainless steel and carbon steel could be used as feed material for these products.

MacNair, V.; Muth, T.; Shasteen, K.; Liby, A.; Hradil, G.; Mishra, B.

1996-12-31T23:59:59.000Z

143

Breakthrough Research on Platinum-Nickel Alloys  

NLE Websites -- All DOE Office Websites (Extended Search)

Breakthrough Research on Platinum-Nickel Alloys Print Breakthrough Research on Platinum-Nickel Alloys Print Two out of three of the kinetic barriers to the practical use of polymer electrolyte membrane (PEM) hydrogen fuel cells in automobiles have been breached: the impractically high amount of extra energy needed for the oxidation reduction reaction (ORR) on the catalyst and the loss of catalytic surface areas available for ORR. Using a combination of probes and calculations, a group of scientists has demonstrated that the Pt3Ni(111) alloy is ten times more active for ORR than the corresponding Pt(111) surface and ninety times more active than the current state-of-the-art Pt/C catalysts used in existing PEM fuel cells. This new variation of the platinum-nickel alloy is the most active oxygen-reducing catalyst ever reported.

144

Breakthrough Research on Platinum-Nickel Alloys  

NLE Websites -- All DOE Office Websites (Extended Search)

Breakthrough Research on Breakthrough Research on Platinum-Nickel Alloys Breakthrough Research on Platinum-Nickel Alloys Print Wednesday, 28 February 2007 00:00 Two out of three of the kinetic barriers to the practical use of polymer electrolyte membrane (PEM) hydrogen fuel cells in automobiles have been breached: the impractically high amount of extra energy needed for the oxidation reduction reaction (ORR) on the catalyst and the loss of catalytic surface areas available for ORR. Using a combination of probes and calculations, a group of scientists has demonstrated that the Pt3Ni(111) alloy is ten times more active for ORR than the corresponding Pt(111) surface and ninety times more active than the current state-of-the-art Pt/C catalysts used in existing PEM fuel cells. This new variation of the platinum-nickel alloy is the most active oxygen-reducing catalyst ever reported.

145

Technical report series: Concentrations of PCBs, DDTr, and selected metals in biota from Guntersville Reservoir  

SciTech Connect

The purpose was to determine if there was potential for human health risks from consumption of reservoir fish or if selected toxic substances might be impacting reservoir biota. Fillets from catfish (channel and blue) and largemouth bass were analyzed for the first purpose and whole gizzard shad, catfish livers, and turtle livers and fat were analyzed for the second. Results indicate largemouth bass should be safe for consumption based on low levels of tested contaminants. However, three of sixteen catfish samples contained PCB levels above the Food and Drug Administration (FDA) tolerance of 2.0 ..mu..g/g, and seven others contained levels sufficiently close to that value to warrant concern. DDT and its metabolites and selected metals were low in catfish except for chromium, nickel, and mercury in selected cases. Analyses on all sample types (those referenced above plus catfish livers and turtle fat and livers) indicated levels of metals were generally low and probably not individually impacting reservoir biota.

Dycus, D.L.; Lowery, D.R.

1986-10-01T23:59:59.000Z

146

Status of the International Cooperative Program for Inspection of Nickel Alloy Components - PINC  

SciTech Connect

Primary water stress corrosion cracking (PWSCC) has occurred world-wide in nuclear power plants and is seen as a serious issue. Crack samples show very tight and very complex cracks in the nickel-base weld metal and forgings that are difficult to detect, size, and characterize. Pacific Northwest National Laboratory (PNNL) is conducting a research program on non-destructive evaluation (NDE) reliability in detecting and characterizing PWSCC. This program is part of an international cooperative research project called the Program for the Inspection of Nickel-Alloy Components (PINC), led by the U.S. Nuclear Regulatory Commission (NRC), which has been set up to leverage efforts in several countries to address this significant and common problem. This work has the general goal of developing an understanding of the morphology of PWSCC and assessing the NDE responses from it.

Schuster, George J.; Cumblidge, Stephen E.; Doctor, Steven R.; Moyer, Carol E.

2008-01-01T23:59:59.000Z

147

Structural Basis of Low-Affinity Nickel Binding to the Nickel-Responsive Transcription Factor NikR from Escherichia coli  

E-Print Network (OSTI)

Escherichia coli NikR regulates cellular nickel uptake by binding to the nik operon in the presence of nickel and blocking transcription of genes encoding the nickel uptake transporter. NikR has two binding affinities for ...

Phillips, Christine M.

148

Water treatment process and system for metals removal using Saccharomyces cerevisiae  

DOE Patents (OSTI)

A process and a system for removal of metals from ground water or from soil by bioreducing or bioaccumulating the metals using metal tolerant microorganisms Saccharomyces cerevisiae. Saccharomyces cerevisiae is tolerant to the metals, able to bioreduce the metals to the less toxic state and to accumulate them. The process and the system is useful for removal or substantial reduction of levels of chromium, molybdenum, cobalt, zinc, nickel, calcium, strontium, mercury and copper in water.

Krauter, Paula A. W. (Livermore, CA); Krauter, Gordon W. (Livermore, CA)

2002-01-01T23:59:59.000Z

149

Effect of a fluorinated nickel surface on the decomposition of perfluorodiethoxymethane  

SciTech Connect

Perfluoropolyethers (PFPEs) are a commercial class of lubricants widely used in computer and aerospace industries. This is a study of the degradation of a perfluorinated ether in the presence of a metal fluoride. Perfluorodiethoxymethane (PFDEM) is a PFPE analog. Temperature programmed desorption shows no contribution of PFDEM toward nickel fluoride on an NiF{sub 2} surface obtained by CF{sub 3}I adsorption. Higher coverages of nickel fluoride do not show any evidence of NiF{sub 2} contribution from PFDEM. The results do not agree with the idea that a fluorinated surface might induce decomposition of PFPEs, leading to addition fluoride formation on the surface. The metal fluoride bond strength is not a legitimate concern for decomposition of PFE lubricants. Impurity in PFPEs might be the cause of initial surface fluoridation leading to breakdown of PFPEs which could cause additional metal fluoride formation. It is clear that the reaction of PFPEs with metals does not involve a direct formation of a simple M-F bond; results do not show any C-F bond cleavage of the fluorinated ether and do not support a proposed autocatalytic mechanism.

Sreevidya, S.

1995-11-09T23:59:59.000Z

150

Low temperature iron- and nickel-catalyzed reactions leading to coalbed gas formation  

SciTech Connect

Hydrocarbon hydrogenolysis and CO{sub 2} hydrogenation in the presence of Fe/SiO{sub 2} and Ni/SiO{sub 2} catalysts were evaluated as potential mechanisms contributing to natural gas formation in coalbeds. The hydrocarbons used as reactants in hydrogenolysis included butane, octane, 1-octene, and 1-dodecene. The reactions carried out in a laboratory batch reactor produced gas that contained methane concentrations greater than 90%, which resembles the composition of natural gas. Reaction temperatures were selected to resemble natural coalbed conditions. Evidence is presented to show that iron and nickel minerals, which can be present in coals at levels of 2,000 and 10 ppm, respectively, can become active under geologic conditions. The oxides (Fe{sub 2}O{sub 3} and NiO) used as precursors of the active catalysts (Fe and Ni metals) were reduced at 200 C under a hydrogen atmosphere. Moessbauer spectroscopy showed that ca. 6% of the iron oxide was converted to the metal; in the case of nickel, oxygen titration showed that the extent of reduction to the metal was ca. 29%. The resultant fractions of the active metals in coals are adequate to catalyze generation of appreciable amounts of methane over geologic time.

Medina, J.C.; Butala, S.J.; Bartholomew, C.H.; Lee, M.L.

2000-02-01T23:59:59.000Z

151

On the solar nickel and oxygen abundances  

E-Print Network (OSTI)

Determinations of the solar oxygen content relying on the neutral forbidden transition at 630 nm depend upon the nickel abundance, due to a Ni I blend. Here we rederive the solar nickel abundance, using the same ab initio 3D hydrodynamic model of the solar photosphere employed in the recent revision of the abundances of C, N, O and other elements. Using 17 weak, unblended lines of Ni I together with the most accurate atomic and observational data available we find log epsilon_Ni = 6.17 +/- 0.02 (statistical) +/- 0.05 (systematic), a downwards shift of 0.06 to 0.08 dex relative to previous 1D-based abundances. We investigate the implications of the new nickel abundance for studies of the solar oxygen abundance based on the [O I] 630 nm line in the quiet Sun. Furthermore, we demonstrate that the oxygen abundance implied by the recent sunspot spectropolarimetric study of Centeno & Socas-Navarro needs to be revised downwards from log epsilon_O = 8.86 +/- 0.07 to 8.71 +/- 0.10. This revision is based on the new nickel abundance, application of the best available gf-value for the 630 nm forbidden oxygen line, and a more transparent treatment of CO formation. Determinations of the solar oxygen content relying on forbidden lines now appear to converge around log epsilon_O = 8.7.

Pat Scott; Martin Asplund; Nicolas Grevesse; A. Jacques Sauval

2008-11-05T23:59:59.000Z

152

173. NICKEL SORPTION KINETICS ON THE CLAY FRACTION OF A SOIL. D.R. Roberts and D.L. Sparks, Department of Plant and Soil Sciences, University of Delaware, Newark,  

E-Print Network (OSTI)

173. NICKEL SORPTION KINETICS ON THE CLAY FRACTION OF A SOIL. D.R. Roberts and D.L. Sparks the fate of heavy metal contaminants in the soil environment. Past studies of heavy metal sorption kinetics. This study exannines Ni(II) sorption and desorption kinetics on the clay fraction (

Sparks, Donald L.

153

Metal-Air Batteries  

SciTech Connect

Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

2011-08-01T23:59:59.000Z

154

Notes on the photo-induced characteristics of transition metal-doped and undoped titanium dioxide thin films  

E-Print Network (OSTI)

Ā­gel method using titanium n-butoxide, acetylacetone, and transition metal acetylacetonates as precursors dioxide with transition met- als such as iron [28], cobalt [29], nickel [30], manganese [31], chro- mium

Cirkva, Vladimir

155

Chapter 4 - Recycling Rare Metals  

Science Journals Connector (OSTI)

Abstract The industrial system now utilizes many more elements, especially rare metals, than was the case even a half century ago. Most are not mined for themselves but are obtained as by-products or “hitchhikers” of the more familiar industrial metals, such as iron, aluminum, copper, nickel, and zinc. This imposes a limit on the production of by-product metals. But in some cases, demand may increase much faster than new supply. This suggests a need for recycling. But the uses of these metals are often in products, such as cell phones, that are mass-produced but where the amount in each individual product is very small. Some uses are also inherently dissipative. This makes recycling very difficult in principle. It constitutes a serious challenge for the future economy. Prices will rise.

Robert U. Ayres; Gara Villalba Méndez; Laura Talens Peiró

2014-01-01T23:59:59.000Z

156

Hydrogen production by steam reforming of simulated liquefied natural gas (LNG) over mesoporous nickel–M–alumina (M = Ni, Ce, La, Y, Cs, Fe, Co, and Mg) aerogel catalysts  

Science Journals Connector (OSTI)

Mesoporous nickel–M–alumina aerogel catalysts (denoted as NiMAE) with different second metal (M = Ni, Ce, La, Y, Cs, Fe, Co, and Mg) were prepared by a single-step sol–gel method and a subsequent CO2 supercritical drying method. The effect of second metal of mesoporous nickel–M–alumina aerogel catalysts on their physicochemical properties and catalytic activity for steam reforming of simulated liquefied natural gas (LNG) was investigated. Textural and chemical properties of NiMAE catalysts were strongly influenced by the identity of second metal. Nickel species were highly dispersed on the surface of NiMAE catalysts through the formation of nickel aluminate phase. In the steam reforming of LNG, both LNG conversion and hydrogen yield decreased in the order of NiLaAE > NiCeAE > NiYAE > NiCsAE > NiNiAE > NiFeAE > NiCoAE > NiMgAE. Average nickel diameter of NiMAE catalysts was well correlated with LNG conversion and hydrogen yield over the catalysts. Among the catalysts tested, NiLaAE catalyst exhibited the best catalytic performance due to its smallest average nickel diameter. Furthermore, NiLaAE catalyst exhibited a strong capability of facilitating heat and mass transfer of reactant and product during the steam reforming of LNG. Water–gas shift reaction governed the steam reforming reaction over NiLaAE catalyst under the steam-rich reaction condition (steam/carbon > 2).

Jeong Gil Seo; Min Hye Youn; Yongju Bang; In Kyu Song

2011-01-01T23:59:59.000Z

157

Effects of metallic nanoparticle doped flux on the interfacial intermetallic compounds between lead-free solder ball and copper substrate  

Science Journals Connector (OSTI)

Abstract Lead free solders currently in use are prone to develop thick interfacial intermetallic compound layers with rough morphology which are detrimental to the long term solder joint reliability. A novel method has been developed to control the morphology and growth of intermetallic compound layers between lead-free Sn–3.0Ag–0.5Cu solder ball and copper substrate by doping a water soluble flux with metallic nanoparticles. Four types of metallic nanoparticles (nickel, cobalt, molybdenum and titanium) were used to investigate their effects on the wetting behavior and interfacial microstructural evaluations after reflow. Nanoparticles were dispersed manually with a water soluble flux and the resulting nanoparticle doped flux was placed on copper substrate. Lead-free Sn–3.0Ag–0.5Cu solder balls of diameter 0.45 mm were placed on top of the flux and were reflowed at a peak temperature of 240 °C for 45 s. Angle of contact, wetting area and interfacial microstructure were studied by optical microscopy, field emission scanning electron microscopy and energy-dispersive X-ray spectroscopy. It was observed that the angle of contact increased and wetting area decreased with the addition of cobalt, molybdenum and titanium nanoparticles to flux. On the other hand, wettability improved with the addition of nickel nanoparticles. Cross-sectional micrographs revealed that both nickel and cobalt nanoparticle doping transformed the morphology of Cu6Sn5 from a typical scallop type to a planer one and reduced the intermetallic compound thickness under optimum condition. These effects were suggested to be related to in-situ interfacial alloying at the interface during reflow. The minimum amount of nanoparticles required to produce the planer morphology was found to be 0.1 wt.% for both nickel and cobalt. Molybdenum and titanium nanoparticles neither appear to undergo alloying during reflow nor have any influence at the solder/substrate interfacial reaction. Thus, doping of flux with appropriate metallic nanoparticles can be successfully used to control the morphology and growth of intermetallic compound layers at the solder/substrate interface which is expected to lead to better reliability of electronic devices.

G.K. Sujan; A.S.M.A. Haseeb; A.B.M. Afifi

2014-01-01T23:59:59.000Z

158

Advanced technologies for decontamination and conversion of scrap metals  

SciTech Connect

Recycle of radioactive scrap metals (RSM) from decommissioning of DOE uranium enrichment and nuclear weapons manufacturing facilities is mandatory to recapture the value of these metals and avoid the high cost of disposal by burial. The scrap metals conversion project detailed below focuses on the contaminated nickel associated with the gaseous diffusion plants. Stainless steel can be produced in MSC`s vacuum induction melting process (VIM) to the S30400 specification using nickel as an alloy constituent. Further the case alloy can be rolled in MSC`s rolling mill to the mechanical property specification for S30400 demonstrating the capability to manufacture the contaminated nickel into valuable end products at a facility licensed to handle radioactive materials. Bulk removal of Technetium from scrap nickel is theoretically possible in a reasonable length of time with the high calcium fluoride flux, however the need for the high temperature creates a practical problem due to flux volatility. Bulk decontamination is possible and perhaps more desirable if nickel is alloyed with copper to lower the melting point of the alloy allowing the use of the high calcium fluoride flux. Slag decontamination processes have been suggested which have been proven technically viable at the Colorado School of Mines.

Muth, T.R. [Manufacturing Sciences Corp., Oak Ridge, TN (United States); Moore, J.; Olson, D.; Mishra, B. [Colorado School of Mines, Golden, CO (United States)

1994-12-31T23:59:59.000Z

159

High weldability nickel-base superalloy  

DOE Patents (OSTI)

This is a nickel-base superalloy with excellent weldability and high strength. Its composition consists essentially of, by weight percent, 10-20 iron, 57-63 nickel, 7-18 chromium, 4-6 molybdenum, 1-2 niobium, 0.2-0.8 silicon, 0.01-0.05 zirconium, 1.0-2.5 titanium, 1.0-2.5 aluminum, 0.02-0.06 carbon, and 0.002-0.015 boron. The weldability and strength of this alloy give it a variety of applications. The long-time structural stability of this alloy together with its low swelling under nuclear radiation conditions, make it especially suitable for use as a duct material and controlling element cladding for sodium-cooled nuclear reactors.

Gibson, Robert C. (Ringwood, NJ); Korenko, Michael K. (Richland, WA)

1980-01-01T23:59:59.000Z

160

DOE Seeks Industry Input on Nickel Disposition Strategy | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Seeks Industry Input on Nickel Disposition Strategy DOE Seeks Industry Input on Nickel Disposition Strategy DOE Seeks Industry Input on Nickel Disposition Strategy March 23, 2012 - 12:00pm Addthis WASHINGTON, D.C. - The Energy Department's prime contractor, Fluor-B&W Portsmouth (FBP), managing the Portsmouth Gaseous Diffusion Plant (GDP), issued a request for Expressions of Interest (EOI) seeking industry input to support the development of an acquisition strategy for potential disposition of DOE nickel. The EOI requests technical, financial, and product market information to review the feasibility of technologies capable of decontaminating the nickel to a level indistinguishable from what is commercially available, such that it could be safely recycled and reused. The EOI scope is for 6,400 tons of nickel to be recovered from the uranium enrichment process

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

DOE Seeks Industry Input on Nickel Disposition Strategy | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Industry Input on Nickel Disposition Strategy Industry Input on Nickel Disposition Strategy DOE Seeks Industry Input on Nickel Disposition Strategy March 23, 2012 - 12:00pm Addthis WASHINGTON, D.C. - The Energy Department's prime contractor, Fluor-B&W Portsmouth (FBP), managing the Portsmouth Gaseous Diffusion Plant (GDP), issued a request for Expressions of Interest (EOI) seeking industry input to support the development of an acquisition strategy for potential disposition of DOE nickel. The EOI requests technical, financial, and product market information to review the feasibility of technologies capable of decontaminating the nickel to a level indistinguishable from what is commercially available, such that it could be safely recycled and reused. The EOI scope is for 6,400 tons of nickel to be recovered from the uranium enrichment process

162

Electrohydrodynamic atomization (EHDA) assisted wet chemical synthesis of nickel nanoparticles  

SciTech Connect

Highlights: ? Electrohydrodynamic atomization (EHDA) assisted chemical synthesis of nickel nanoparticles is reported. ? Substituting water with non-aqueous media prevents the formation of nickel hydroxide. ? Size of particles decreased from 10 to 20 nm down to 2–4 nm by using multi-jet mode. ? Synthesized nanoparticles have diffraction patterns similar to amorphous materials. -- Abstract: In this study nickel nanoparticles were prepared via chemical reduction of nickel acetate using sodium borohydride using electrohydrodynamic atomization (EHDA) technique. This technique was used to spray a finely dispersed aerosol of nickel precursor solution into the reductive bath. Obtained particles were characterized by means of X-ray diffraction (XRD), UV–Visible spectroscopy, and transmission electron microscopy (TEM). Results confirmed the formation of nickel nanoparticles and showed that applying EHDA technique to chemical reduction method results in producing smaller particles with narrower size distribution in comparison with conventional reductive precipitation method.

Barzegar Vishlaghi, M. [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of)] [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of); Farzalipour Tabriz, M., E-mail: meisam.fa@gmail.com [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of); Mohammad Moradi, O. [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of)] [Department of Mechanical Engineering, University of Tabriz, Tabriz (Iran, Islamic Republic of)

2012-07-15T23:59:59.000Z

163

Competitive adsorption effects in the electrodeposition of iron-nickel alloys  

SciTech Connect

Two-step reaction mechanisms involving adsorbed monovalent intermediate ions for the electrodeposition of iron and nickel as single metals can be combined to form a predictive model for the codeposition of iron-nickel alloys. Inhibition of the more noble nickel in the presence of iron is caused by preferential surface coverage of the adsorbed iron intermediate resulting from a difference between the two elements in Tafel constant for the electrosorption step. The role of hydrolyzed cations and surface pH is investigated and methods for evaluating the influence of pH are explored. The analysis shows that changes in surface pH with potential are not necessary for iron-rich (anomalous) deposits, but that variations in pH from one electrolyte to another may influence deposit composition. The tendency toward iron-rich deposits with increasing overpotential exists in all systems, however, and can be prevented only by decreasing the iron concentration of the bath. An extension of the analysis to account for transport limitations in baths with low iron concentration is developed and calculations with the model are presented to illustrate the effects of current density and electrolyte convection under conditions similar to those investigated experimentally in the literature.

Matlosz, M. (Ecole Polytechnique Federale de Lausanne, (Switzerland). Dept. des materiaux)

1993-08-01T23:59:59.000Z

164

Non-Magnetic Films of Nickel  

Science Journals Connector (OSTI)

Properties of sputtered nickel films.—(1) Magnetic. These films, prepared by sputtering in hydrogen on to a cooled surface, with a 1000 volt d.c. generator, are initially non-magnetic, showing neither magneto-optic rotation nor tractive effects in a magnetic field. After heating to 300° or 400°C, however, they become strongly magentic and exhibit both these effects. Films much thicker than 120m?, or those sputtered with an induction coil, are likely to be magnetic from the start. (2) Crystal structure. X-ray spectrograms by the powder method show for the heat-treated (magnetic) film the face-centered cubic lattice as for ordinary nickel, but prove that the original non-magnetic film is amorphous. These facts suggest that ferro-magnetism in nickel, at any rate, is not a property of the individual atom as customarily supposed, but of the crystalline aggregate. A number of possible objections to this point of view are taken up and discussed. (3) Electric. The gain in magnetic properties on heat-treatment is accompanied by a decrease of resistance to a fraction (a fifth in one case) of its initial value. The original film also gives only about 1 percent of the Hall effect that it does after heat-treatment. (4) Color. Some films, particularly those deposited on a surface at liquid-air temperatures, display remarkable colors. On examination of the reflected light with a spectroscope, only a narrow spectral region is seen to be absent. If the nickel films are thin, covering with an optically dense liquid completely destroys the colors.

L. R. Ingersoll and S. S. De Vinney

1925-07-01T23:59:59.000Z

165

Structural Evaluation and Solution Integrity of Alkali Metal Salt Complexes of the Manganese 12-Metallacrown-4 (12-MC-4) Structural Type  

E-Print Network (OSTI)

of crystalline salts (LiCl2)[12-MCMn(III)N(shi)-4]- ([(LiCl2),1]-), (Li(trifluoro- acetate))[12-MCMn(III)N(shi)-4:1 metal:metallacrown adducts with lithium and 2:1 metal:metallacrown complexes with sodium and potassium

Gibney, Brian R.

166

Hydrogen storage characteristics of nanograined free-standing magnesium–nickel films  

E-Print Network (OSTI)

of nanograined free-standing magnesium–nickel ?lms MatthewAbstract Free-standing magnesium–nickel (Mg–Ni) ?lms withfree- standing magnesium–nickel ?lms. Magnesium hydride (MgH

2009-01-01T23:59:59.000Z

167

Direct Reduction of Waste through Refining of DOE Metal Assets - 13632  

SciTech Connect

CVMR{sup R} presents a technology for refining nickel from the enrichment barrier materials of the DOE that is proven through 100 years of use by the metals industry. CVMR{sup R} applies modern controls, instrumentation for process and monitoring of the system, and innovative production methods to produce a wide spectrum of products that generate new technology applications and improvements to our society and economy. CVMR{sup R} will receive barrier materials as a secure operation and size reduce the metal to a shred that is fed to a carbonylation reactor where nickel is reacted with carbon monoxide and generate nickel carbonyl. The carbonyl will be filtered and decomposed with heat to form a variety of products that include high value nano powders, coated substrates, net shapes and pure nickel. The residue from the reactor will retain radionuclides from enrichment activities. The carbon monoxide will only react and extract nickel under the operating conditions to leave volumetric contamination in the unreacted residue. A demonstration plant was designed and built by CVMR{sup R} and operated by BWXT, to demonstrate the systems capabilities to DOE in 2006. A pilot plant operation precedes the detailed design of the nickel refinery and provides essential data for design, safe work practices, waste characterizations and system kinetics and confirms the project feasibility. CVMR{sup R} produces nickel products that are cleaner than the nickel in U.S. commerce and used by industry today. The CVMR{sup R} process and systems for nickel refining is well suited for DOE materials and will provide value through environmental stewardship, recovery of high value assets, and support of the DOE environmental remediation programs as the refined nickel generates additional long term benefits to local communities. (authors)

Hargett, Michael C.; Terekhov, Dimitri; Khozan, Kamran M. [Chemical Vapour Metal Refining - CVMR (United States)] [Chemical Vapour Metal Refining - CVMR (United States)

2013-07-01T23:59:59.000Z

168

E-Print Network 3.0 - acid nickel ii Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Use of Magnetic and Electrically Conductive Fillers in a Polymer Matrix for Electromagnetic Interference Shielding Summary: of nickel powder were used, namely nickel powder I and...

169

E-Print Network 3.0 - aluminium nickel arsenic Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

and electrothermal Summary: , copper, nickel and palladium nitrates on the arsenic atomic absorption signal magnitude were examined... stabilisation of platform); C, nickel...

170

Effect of titania surface species on the chemisorption of CO and H/sub 2/ on polycrystalline nickel  

SciTech Connect

A submonolayer amount of titanium was deposited and subsequently oxidized in situ on a clean polycrystalline nickel foil in ultrahigh vacuum. Temperature-programmed desorption revealed the activation energy for CO desorption was reduced significantly by the presence of titania surface species. The titania-containing Ni surface showed three binding states for dissociative hydrogen adsorption. Adsorption into the strongest of these three states was an activated process. These results suggest the apparent suppression of CO and H/sub 2/ adsorption typically observed at 300 K for titania-supported group 8 metals may be due to the existence of titania species on the surfaces of the metal particles.

Raupp, G.B.; Dumesic, J.A.

1984-02-16T23:59:59.000Z

171

Edge effects caused by enhancement of DD/DT fusion reactions in metals at low energy of projectile particles in an ITER-type fusion reactor  

Science Journals Connector (OSTI)

Experimental data on enhancement of the yield of DD/DT reactions in metal targets at low energies of projectile deuterons (E d...< 5 keV) were analyzed. A semiempirical expression was obtained to ...

A. G. Lipson; A. S. Roussetski; B. F. Lyakhov; E. I. Saunin…

2008-07-01T23:59:59.000Z

172

Adsorption of carbonyl sulfide on nickel and tungsten films  

SciTech Connect

The interaction of carbonyl sulfide with evaporated nickel and tungsten films has been investigated in the temperature range 195-450 K using gas pressures ranging from 1 to 13 N m/sup -2/. Rapid but mainly associative chemisorption of COS occurred on both metals at 195 K. Further adsorption of COS on W at temperatures 293-450 K was extremely slow and accompanied by more CO desorption than COS adsorbed. Sulfidation of Ni film by COS occurred at temperatures greater than or equal to 293 K with the liberation of carbon monoxide. The rate of adsorption increased with temperature but was independent of COS pressure. The activation energy (E/sub x/) increased with extent (X) of sulfidation to a limiting value of 97 kJ mol/sup -1/. A linear relationship was obtained from the plot of E/sub x/ against 1/X, suggesting the applicability of Cabrera-Mott theory to the sulfidation of Ni film by COS. 20 references, 2 figures, 1 table.

Saleh, J.M.; Nasser, F.A.K.

1985-07-18T23:59:59.000Z

173

Disproportionation of carbon monoxide on supported nickel catalysts  

SciTech Connect

The disproportionation of carbon monoxide was investigated mainly on a 5.5% Ni/Al/sub 2/O/sub 3/ catalyst by infrared spectroscopy and temperature-programmed desorption. The reaction was found to be of first order with respect to the surface concentration of CO below 200/sup 0/C, while at 450/sup 0/C the reaction proceeded as a second order reaction for the pressure of CO. Results obtained with predeposited carbon indicated that the disproportionation reaction requires an ensemble of several nickel atoms. In agreement with this result, the disproportionation did not take place readily on a 1.1% Ni/Al/sub 2/O/sub 3/ catalyst on which a high dispersion of the metal was indicated by both infrared spectroscopy and the chemisorption of hydrogen. In the temperature-programmed desorption (TPD) carbon monoxide desorbed in a single peak before 300/sup 0/C. Some of the carbon monoxide, however, underwent disproportionation during TPD and a carbon dioxide peak appeared at about 220/sup 0/C. Furthermore, carbon thus deposited on the surface was oxidized to carbon monoxide by oxygen supplied from the catalysts and gave a second peak of CO in TPD at temperatures higher than 300/sup 0/C. Possible sources of the oxygen were discussed.

Galuszka, J.; Chang, J.R.; Amenomiya, Y.

1981-03-01T23:59:59.000Z

174

Removal of heavy metals from samples of residual sludge  

Science Journals Connector (OSTI)

Nitric acid leaching processes were evaluated for removal of heavy metals from samples of residual sludge from an industrial and municipal wastewater plant. The study showed that an acid:water ratio of 1:1 and a nitric acid concentration of 2 mol 1?1 gave efficient removal of 86.7%, 100% and 100% of copper, nickel and arsenic.

Jose Abrego

1996-01-01T23:59:59.000Z

175

Dehydrogenation of tetrahydrothiophene on nickel-zeolite catalysts  

Science Journals Connector (OSTI)

Application of Y zeolites for the preparation of nickel-containing catalysts makes it possible to increase the yield of thiophene up to 55–65% at a selectivity of 70–73% (450–500°C). The activity of nickel-zeo...

L. V. Manujlova; T. S. Sukhareva

1989-01-01T23:59:59.000Z

176

Stabilization of Electrocatalytic Metal Nanoparticles at Metal...  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

177

High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions  

SciTech Connect

The importance of the oxide: Ce{sub 0.8}Ni{sub 0.2}O{sub 2-y} is an excellent catalyst for ethanol steam reforming. Metal-oxide interactions perturb the electronic properties of the small particles of metallic nickel present in the catalyst under the reaction conditions and thus suppress any methanation activity. The nickel embedded in ceria induces the formation of O vacancies, which facilitate cleavage of the OH bonds in ethanol and water.

G Zhou; L Barrio; S Agnoli; S Senanayake; J Evans; A Kubacka; M Estrella; J Hanson; A Martinez-Arias; et al.

2011-12-31T23:59:59.000Z

178

PHYTOEXTRACTION OF HEAVY METALS  

E-Print Network (OSTI)

) Type of phytoremediation Cost effective form of environmental remediation (Glass 1999) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al -using hyperaccumulator plant biomass to produce a bio-ore for commercial use -Li et al. look at using Ni

Blouin-Demers, Gabriel

179

Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur  

SciTech Connect

Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 ŗC to ~750 ŗC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

Ziomek-Moroz, M.; Hawk, Jeffrey A.

2005-01-01T23:59:59.000Z

180

Nickel and iron EXAFS of carbon monoxide dehydrogenase from Clostridium thermoaceticum strain DSM  

Science Journals Connector (OSTI)

Nickel and iron EXAFS of carbon monoxide dehydrogenase from Clostridium thermoaceticum strain DSM ...

Neil R. Bastian; Gabriele. Diekert; Eric C. Niederhoffer; Boon Keng. Teo; Christopher T. Walsh; William H. Orme-Johnson

1988-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Heavy reflector experiments in the IPEN/MB-01 reactor: Stainless steel, carbon steel and nickel  

SciTech Connect

New experiments devoted to the measurements of physical parameters of a light water core surrounded by a heavy reflector were performed in the IPEN/MB-01 research reactor facility. These experiments comprise three sets of heavy reflector (SS-304, Carbon Steel, and Nickel) in a form of laminates around 3 mm thick. Each set was introduced individually in the west face of the core of the IPEN/MB-01 reactor. The aim here is to provide high quality experimental data for the interpretation and validation of the SS-304 heavy reflector calculation methods. The experiments of Carbon Steel, which is composed mainly of iron, and Nickel were performed to provide a consistent and an interpretative check for the SS-304 reflector experiment. The experimental results comprise critical control bank positions, temperatures and reactivities as a function of the number of the plates. Particularly to the case of Nickel, the experimental data are unique of its kind. The theoretical analysis was performed by MCNP-5 with the nuclear data library ENDF/B-VII.0. It was shown that this nuclear data library has a very good performance up to thirteen plates and overestimates the reactivity for higher number of plates independently of the type of the reflector.

Santos, Adimir dos; Andrade e Silva, Graciete Simoes de; Jerez, Rogerio; Liambos Mura, Luis Felipe; Fuga, Rinaldo [Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP Av. Prof. Lineu Prestes 2242 - CEP 05508-000 Sao Paulo, SP (Brazil)

2013-05-06T23:59:59.000Z

182

Extensive Interstitial Solid Solutions of Metals in Metals  

Science Journals Connector (OSTI)

A new type of metallic solid solution has been prepared in which <~12.5 at.% of comparatively small metal atoms (Cu) fill interstitial sites in a host metal composed of larger atoms (Y). At higher solute concentrations, both interstitial and substitutional sites are occupied. These solid solutions are metastable; they were formed by ultrarapid quenching from the liquid.

B. C. Giessen; R. Ray; S. H. Hahn

1971-03-01T23:59:59.000Z

183

Serum nickel concentrations in hemodialysis patients with environmental exposure  

SciTech Connect

Nickel was analyzed by electrothermal atomic absorption spectrophotometry in serum specimens from 22 healthy hospital workers and 30 patients with end-stage renal disease treated by extracorporeal hemodialysis, who resided in Sudbury, Ontario, Canada, a city with extensive nickel mines and smelters. Samples of tap water from Sudbury contained 109 +/- 46 micrograms Ni per L (P less than 0.01 vs 0.4 +/- 0.2 micrograms Ni per L in corresponding water samples from Hartford, Connecticut). Serum nickel concentrations averaged 0.6 +/- 0.3 micrograms Ni per L in Sudbury hospital workers (P less than 0.05 vs 0.2 +/- 0.2 micrograms Ni per L in corresponding serums from 43 healthy hospital workers in Hartford). In serums collected post-treatment from Sudbury hemodialysis patients, nickel concentrations averaged 8.5 +/- 2.8 micrograms Ni per L, (i.e., 14-times the corresponding mean in Sudbury hospital workers, P less than 0.01), but were not significantly higher than the nickel concentrations in serums from 42 Hartford hemodialysis patients (7.2 +/- 2.2 micrograms Ni per L). This study confirms the presence of hypernickelemia in hemodialysis patients, but does not suggest that hemodialysis patients have significantly increased risk of nickel toxicity in Sudbury, compared to Hartford, despite the high nickel concentrations in Sudbury tap water. This favorable outcome attests to the efficient deionization of water used to prepare hemodialysis solutions in Sudbury.

Hopfer, S.M.; Fay, W.P.; Sunderman, F.W. Jr.

1989-05-01T23:59:59.000Z

184

Parameters affecting the fate of metals in various soils  

E-Print Network (OSTI)

At Different Mixed Spike Concentrations 200 150 a Cadmium p Copper Lead Q Nickel 0 Zinc L. O LI 1 00 O O O 50 10 Mixed Spike Concentration 100 FIGURE 12. Per Cent Of Metal Accounted For In Bastrop Soil At Different Mixed Spike Concentrations..., copper, lead, nickel, and zinc along with four soils native to Texas . The following questions The citations on the following pages follow the style of the Jo 1 fthE loentt~Eai i Diplo, A icS sty of Civil Engineers. directed the course of the study...

Covar, Andrew Prescott

1975-01-01T23:59:59.000Z

185

Copper and Nickel Partitioning with Nanoscale Goethite.  

E-Print Network (OSTI)

??Goethite is an ideal sorbent for investigations of metal partitioning with iron oxyhydroxides because it is the most abundant iron oxyhydroxide in sediments (Langmuir, 1997;… (more)

Danner, Kelsey Marie

2013-01-01T23:59:59.000Z

186

Metal Aminoboranes  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal Aminoboranes Metal Aminoboranes Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. June 25, 2013 Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Available for thumbnail of Feynman Center (505) 665-9090 Email Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit. U.S. Patent No.: 7,713,506 (DOE S-112,798)

187

Desorption of carbon monoxide from nickel using mercaptans  

SciTech Connect

An IR spectroscopic study on the displacement of carbon monoxide with 1-propyl, 2-propyl-, 1-butyl-, 2-butyl-, and tert.-butyl mercaptan from nickel foil and silica-supported nickel showed that at low carbon monoxide coverage on supported nickel, mercaptan adsorption initially converted bridged to linear carbon monoxide surface species. At higher mercaptan pressures, carbon monoxide desorbed into the gas phase. A small amount of carbon monoxide remained on the surface when the poisoned sample was evacuated, and additional carbon monoxide adsorbed when 5 mm Hg of carbon monoxide was added to the evacuated sample.

Neff, L.D.; Sturdivant, A.E.; Wallace, J.L.

1980-06-01T23:59:59.000Z

188

Electrode Plate For An Eletrlchemical Cell And Having A Metal Foam Type Support, And A Method Of Obtaining Such An Electrode  

DOE Patents (OSTI)

The electrode plate includes an active portion that is pasted with active material, and a plate head that is made up of three layers of compressed metal foam comprising: a non-pasted portion of height G of the support of the electrode plate; and two strips of non-pasted metal foam of height R on either side of the non-pasted portion of height G of the support and also extending for an overlap height h.sub.2 over the pasted portion of the support. The plate head includes a zone of reduced thickness including a portion that is maximally compressed, and a transitional portion between said maximally compressed portion and the remainder of the electrode which is of thickness e.sub.2. A portion of said plate head forms a connection tab. The method of obtaining the electrode consists in simultaneously rolling all three layers of metal foam in the plate head, and then in cutting matter away from the plates so as to obtain respective connection tabs.

Verhoog, Roelof (Bordeaux, FR); Precigout, Claude (Bordeaux, FR); Stewart, Donald (Bordeaux, FR)

1996-05-21T23:59:59.000Z

189

Microsoft PowerPoint - Nickell.ppt  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Spring 2009 Technical Workshop Spring 2009 Technical Workshop U.S. DOE 2009 Congestion Study Bradley M Nickell, PE Renewable Integration and Planning Director Transmission Expansion Planning Policy Committee 2008 Study Results Today's Discussion ā—¸ TEPPC Study Scenarios ā—¸ 2008 Study Results ā—¸ 2009 Study Requests ā—¸ Related WECC Activities 2017 Renewable Energy Scenarios ā—¸ 15% Renewables Case - PC4A ā—¸ 15% Renewables plus 20% Energy Efficiency - PC4B ā—¸ 15% Renewables plus 20% Energy Efficiency plus a $20 per ton CO2 adder - PC4C-3 3 2017 - Base Case ā—¸ Loads - Member supplied 2017 Forecast ā—¸ Transmission System - WECC base case 2016-2017 ā—¸ Generation - All existing, plus LRS Category 1 and Category 2 generation. Sufficient RPS resources were added to meet minimum RPS requirements for 2017, which equates

190

Type B Accident Investigation Board Report, May 8, 2004, Exothermic Metal Reactor Event During Sodium Transfer Activities, East Tennessee Technology Park, Oak Ridge, Tennessee  

Energy.gov (U.S. Department of Energy (DOE))

This report is an independent product of the Type B Accident Investigation Board (Board) appointed by Gerald Boyd, Manager, Oak Ridge Operations Office, U.S. Department of Energy. The Board was appointed to perform a Type B investigation of the accident and prepare an investigation report in accordance with DOE O 225.1A, Accident Investigations.

191

Draft Genome Sequences for Two Metal-Reducing Pelosinus fermentans Strains Isolated from a Cr(VI) Contaminated Site and for Type Strain R7  

SciTech Connect

Pelosinus fermentans 16S rRNA gene sequences have been reported from diverse geographical sites since the recent isolation of the type strain. We present the genome sequence of the P. fermentans type strain R7 (DSM 17108) and genome sequences for two new strains with different abilities to reduce iron, chromate, and uranium.

Brown, Steven D [ORNL; Podar, Mircea [ORNL; Klingeman, Dawn Marie [ORNL; Johnson, Courtney M [ORNL; Yang, Zamin Koo [ORNL; Utturkar, Sagar M [ORNL; Land, Miriam L [ORNL; Mosher, Jennifer J [ORNL; Hurt, Jr., Richard Ashley [ORNL; Phelps, Tommy Joe [ORNL; Palumbo, Anthony Vito [ORNL; Arkin, Adam [Lawrence Berkeley National Laboratory (LBNL); Hazen, Terry C [ORNL; Elias, Dwayne A [ORNL

2012-01-01T23:59:59.000Z

192

Quantifying the effect of metal-rich precipitates on minority carrier diffusion length in multicrystalline silicon using synchrotron-based  

E-Print Network (OSTI)

Quantifying the effect of metal-rich precipitates on minority carrier diffusion length diffusion length of individual transition metal species in multicrystalline silicon. SR-XBIC, -XRF, and -XAS correlation between local concentrations of copper and nickel silicide precipitates and a decrease of minority

193

EA-1599: Disposition of Radioactively Contaminated Nickel Located at the  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

99: Disposition of Radioactively Contaminated Nickel Located 99: Disposition of Radioactively Contaminated Nickel Located at the East Tennessee Technology Park, Oak Ridge, Tennessee, and the Paducah Gaseous Diffusion Plant, Paducah, Kentucky, for Controlled Radiological Applications EA-1599: Disposition of Radioactively Contaminated Nickel Located at the East Tennessee Technology Park, Oak Ridge, Tennessee, and the Paducah Gaseous Diffusion Plant, Paducah, Kentucky, for Controlled Radiological Applications Summary This EA was being prepared to evaluate potential environmental impacts of a proposal to dispose of nickel scrap that is volumetrically contaminated with radioactive materials and that DOE recovered from equipment it had used in uranium enrichment. This EA is on hold. Public Comment Opportunities No public comment opportunities at this time.

194

The nickel pipes of Vlakfontein and vicinity, western Transvaal  

Science Journals Connector (OSTI)

...feet of pneumaticand diamond drilling) on Vlaldontein and vicinity...the centrallylocatedVredefort dome within the Witwatersrand Basin...NICKEL PIPES' OF VLAKFONTEIN TAtum 4. Microscopicand Microprobe...ft. The orebody,proved by drilling,haddimensionsof about200...

C. F. Vermaak

195

Momentum Distribution of Electrons in Chromium, Iron, and Nickel  

Science Journals Connector (OSTI)

The Compton profiles of the electron momentum distribution in chromium, iron, and nickel are calculated using the wave functions obtained from self-consistent linear-combination-of-atomic-orbitals energy-band calculations. The results are compared with experiment.

J. Rath, C. S. Wang, R. A. Tawil, and J. Callaway

1973-12-01T23:59:59.000Z

196

Laser ignition of a heterogeneous nickel-aluminum system  

Science Journals Connector (OSTI)

The ignition of a heterogeneous nickel—aluminum system by laser radiation is investigated experimentally. The ignition characteristics are investigated as a function of ... the samples. It is established that the...

Yu. S. Naiborodenko; V. M. Filatov

197

Sound speed and thermophysical properties of liquid iron and nickel  

Science Journals Connector (OSTI)

An electrical-pulse-heating technique has been used to heat iron and nickel to high temperatures to measure thermophysical properties in the liquid state. A dynamic technique was used because static techniques, which are capable of greater precision, fail at a relatively low temperature. Measurements have been made, and results are shown for enthalpy, temperature, density, electrical resistivity, and sound speed up to 3950 K in iron and 4250 K in nickel.

R. S. Hixson; M. A. Winkler; M. L. Hodgdon

1990-10-01T23:59:59.000Z

198

Anthropogenic Nickel Cycle: Insights into Use, Trade, and Recycling  

Science Journals Connector (OSTI)

There are two reasons: their construction technologies use nickel more than elsewhere, and nickel containing goods used in construction are much less traded than any others, particularly machinery. ... Environmental Science and Technology (2004), 38 (4), 1242-1252 CODEN: ESTHAG; ISSN:0013-936X. ... While material flow analysis (MFA) has been widely used to characterize stocks and flows along technological life cycle within a specific geographical area, trade ... ...

Barbara K. Reck; Daniel B. Müller; Katherine Rostkowski; T. E. Graedel

2008-03-25T23:59:59.000Z

199

Type B Accident Investigation on the June 27, 2002, Exothermic Metal Reaction Event During Converter Disassembly in Building K-33 at the East Tennessee Technology Park  

Energy.gov (U.S. Department of Energy (DOE))

This report is an independent product of the Type B Accident Investigation Board (Board) appointed by Michael Holland, Acting Manager, Oak Ridge Operations Office, U.S. Department of Energy.

200

Nickel coated aluminum battery cell tabs  

DOE Patents (OSTI)

A battery cell tab is described. The battery cell tab is anodized on one end and has a metal coating on the other end. Battery cells and methods of making battery cell tabs are also described.

Bucchi, Robert S.; Casoli, Daniel J.; Campbell, Kathleen M.; Nicotina, Joseph

2014-07-29T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Nickel-hydrogen voltage-efficiency model  

SciTech Connect

A model for providing voltage vs. current relationships and coulombic efficiency has been developed applicable to Nickel-Hydrogen (NiH{sub 2}) batteries. The performance relationships can be used directly in dynamic electrical energy storage system models or customized by predicting the particular case of voltage as a function of applied current. The algorithm utilizes electrochemical models for competing cell reactions: a single Butler-Volmer equation for the main NiH{sub 2} reaction, and a Tafel relationship for oxygen generation. For the main NiH{sub 2} reaction, the dependence on state-of-charge is introduced via a Nerstian term containing concentrations of active materials present. Oxygen recombination and self-discharge are modeled as first order reactions. Model parameters are determined by a modified Marquardt algorithm to provide a best-fit of both voltage and pressure data to the physical model. The data fit is from electrical characterization tests which may include capacity measurements or repeated electrical cycling at specified depths-of-discharge or with particular regimens. It has been found that test performance data covering a wide domain of the independent variables (temperature, current, and state-of-charge) will produce a well-behaved model.

Hafen, D.P.; Armantrout, J.D. [Lockheed Martin Missiles and Space, Sunnyvale, CA (United States)

1996-12-31T23:59:59.000Z

202

THE COORDINATION CHEMISTRY OF METAL SURFACES  

SciTech Connect

In coordinately unsaturated molecular metal complexes, carbon-hydrogen bonds of the peripheral ligands may, if the stereochemistry allows, closely approach a metal center so as to develop a three-center two-electron bond between the carbon, the hydrogen, and the metal atoms, C-H-M. In some instances, the interaction .is followed by a scission of the C-H bond whereby the metal is effectively oxidized and discrete M-H and M-C {sigma} bonds are forrned. This class of metal-hydrogen-carbon interactions and reactions is shown to be a common phenomenon in metal surface chemistry. Ultra high vacuum studies of nickel and platinum with simple organic molecules like olefins, and arenes are described. These surface chemistry studies were done as a function of surface crystallography and surface composition. The discussion is largely limited to the chemistry of methyl isocyanide, acetonitrile, benzene and toluene. Molecular orbital calculations are presented that support the experimental identification of the importance of C-H-M metal bonding for metal surfaces.

Muetterties, Earl L.

1980-10-01T23:59:59.000Z

203

Method of making metal matrix composites reinforced with ceramic particulates  

DOE Patents (OSTI)

Composite materials and methods for making such materials are disclosed in which dispersed ceramic particles are at chemical equilibrium with a base metal matrix, thereby permitting such materials to be remelted and subsequently cast or otherwise processed to form net weight parts and other finished (or semi-finished) articles while maintaining the microstructure and mechanical properties (e.g. wear resistance or hardness) of the original composite. The composite materials of the present invention are composed of ceramic particles in a base metal matrix. The ceramics are preferably carbides of titanium, zirconium, tungsten, molybdenum or other refractory metals. The base metal can be iron, nickel, cobalt, chromium or other high temperature metal and alloys thereof. For ferrous matrices, alloys suitable for use as the base metal include cast iron, carbon steels, stainless steels and iron-based superalloys.

Cornie, James A. (North Chelmsford, MA); Kattamis, Theodoulos (Watertown, MA); Chambers, Brent V. (Cambridge, MA); Bond, Bruce E. (Bedford, MA); Varela, Raul H. (Canton, MA)

1989-01-01T23:59:59.000Z

204

Method of making metal matrix composites reinforced with ceramic particulates  

DOE Patents (OSTI)

Composite materials and methods for making such materials are disclosed in which dispersed ceramic particles are at chemical equilibrium with a base metal matrix, thereby permitting such materials to be remelted and subsequently cast or otherwise processed to form net weight parts and other finished (or semi-finished) articles while maintaining the microstructure and mechanical properties (e.g. wear resistance or hardness) of the original composite. The composite materials of the present invention are composed of ceramic particles in a base metal matrix. The ceramics are preferably carbides of titanium, zirconium, tungsten, molybdenum or other refractory metals. The base metal can be iron, nickel, cobalt, chromium or other high temperature metal and alloys thereof. For ferrous matrices, alloys suitable for use as the base metal include cast iron, carbon steels, stainless steels and iron-based superalloys. 2 figs.

Cornie, J.A.; Kattamis, T.; Chambers, B.V.; Bond, B.E.; Varela, R.H.

1989-08-01T23:59:59.000Z

205

Metal inks  

DOE Patents (OSTI)

Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

2014-02-04T23:59:59.000Z

206

Electrodeposition and characterization of nanostructured black nickel selective absorber coatings for solar–thermal energy conversion  

Science Journals Connector (OSTI)

Selective coatings consisting of a bright nickel interlayer and black nickel overlayer for solar-to-thermal energy conversion have been electrodeposited onto stainless steel...2, NiOOH, Ni2O3..., NiO, water and m...

F. I. Lizama-Tzec; J. D. Macķas…

2014-08-01T23:59:59.000Z

207

Electrochemical continuous decomposition of chloroform and other volatile chlorinated hydrocarbons in water using a column type metal impregnated carbon fiber electrode  

SciTech Connect

Trihalomethane and other chlorinated hydrocarbons are known to be toxic to human health. However, removal of these compounds from water is not easy. The authors attempted continuous electrochemical decomposition of chloroform that is the main compound of trihalomethanes and some toxic chlorinated hydrocarbons in water using a metal-impregnated CFE, concentration of chloroform in 0.5 M K{sub 2}SO{sub 4} (the supporting electrolyte) solution was decreased from 0.23m mol/L to below the limit of detection of their analysis system (1 ppm) at a flow rate of 1 mL/min. The main product of electrolysis was methane. This high efficiency, determined by the chemical yield, hardly changed at a flow rate of 20 mL/min at a Ag-impregnated CFE. At a flow rate of 1 mL/min, chloroform was degraded with a decomposition efficiency of almost 100% even in the solution without the supporting electrolyte, whereas at a higher flow rate, the efficiency for the decomposition of chloroform decreased with a decrease in the concentration of the supporting electrolyte. Tetrachloroethylene, 1,1,1-trichloroethane, and 1,1,2-trichloroethane were also decomposed at a Ag-impregnated CFE with an efficiency of almost 100%.

Sonoyama, Noriyuki; Sakata, Tadayoshi

1999-10-01T23:59:59.000Z

208

Characterization of segregation in nickel and titanium aluminides  

SciTech Connect

Atom probe field ion microscopy has been used to characterize the distributions of microalloying additions in the microstructure of a variety of nickel and titanium aluminides. In Ni{sub 3}Al, boron additions were found to segregate to dislocations, low angle boundaries, stacking faults, antiphase boundaries, and grain boundaries. The boron and aluminum levels at grain boundaries were found to vary both from boundary to boundary and also along an individual boundary segment. In some cases, a boron-enriched film up to {approximately}3 nm thick was observed. In aluminum-enriched Ni{sub 3}Al, ultrafine clusters containing up to approximately 10 boron atoms were detected in the matrix. In contrast, the majority of the boron additions in NiAl was determined to be in the form of ultrafine MB{sub 2}-type precipitates. These precipitates offset the benefits of the boron segregation to the high angle grain boundaries. In molybdenum-doped NiAl, atom probe analyses indicated extremely low solubilities of the molybdenum and other trace impurities in the matrix and significant enrichments of molybdenum, nitrogen and silicon, boron, and iron at the grain boundaries. In boron-doped two phase {alpha}{sub 2} + {gamma} TiAl containing chromium, niobium, and tungsten, the boron level was found to be significantly depleted from the bulk level in both the {alpha}{sub 2} and {gamma} phases and a variety of coarse borides including TiB, TiB{sub 2} and a finer chromium-enriched (Ti, Cr){sub 2}B precipitate was observed. The tungsten and chromium were determined to partition preferentially to the {alpha}{sub 2} phase and also to segregated to the {alpha}{sub 2}-{gamma} and {gamma}-{gamma} interfaces. These results indicate that a significant proportion of the microalloying elements are consumed by the boride precipitates.

Miller, M.K.; Larson, D.J.; Russell, K.F. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

1997-03-01T23:59:59.000Z

209

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

210

A novel "Kabuto-like" nickel catalyst forms bioactive frameworks from low-cost phenol derivatives  

E-Print Network (OSTI)

1 A novel "Kabuto-like" nickel catalyst forms bioactive developed a new nickel catalyst with a "Kabuto-like" structure that was found to catalyze the cross nickel catalyst to catalyze the cross-coupling reaction between carbonyl compounds and phenol derivatives

Takahashi, Ryo

211

Silicone metalization  

DOE Patents (OSTI)

A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

2006-12-05T23:59:59.000Z

212

Hydroconversion of heavy crude oils using soluble metallic compounds in the presence of hydrogen or methane  

SciTech Connect

The hydroconversion of heavy crude oil was studied under thermal and catalytic conditions using soluble organo-metallic compounds of Mo, Fe, Cr, V, Ni, and Co as a catalyst precursors. All catalysts are effective for the hydroconversion, however, molybdenum and nickel compounds are preferred.

Morales, A.; Salazar, A.; Ovalles, C.; Filgueiras, E. [INTEVEP, Caracas (Venezuela)

1996-12-31T23:59:59.000Z

213

Experimental Study of In Situ Combustion with Tetralin and Metallic Catalysts  

E-Print Network (OSTI)

or metallic catalysts; the second run used heavy oil premixed with 3 wt% tetralin and 500ppm nickel catalyst; and the third run was with heavy oil premixed with 3 wt% tetralin and 500ppm iron catalyst. For the three runs, the cell production pressure was kept...

Palmer-Ikuku, Emuobonuvie

2010-01-16T23:59:59.000Z

214

DETERMINATION OF IN-VITRO LUNG SOLUBILITY AND INTAKE-TO-DOSE CONVERSION FACTOR FOR TRITIATED LANTHANUM NICKEL ALUMINUM ALLOY  

SciTech Connect

A sample of tritiated lanthanum nickel aluminum alloy (LaNi4.25Al0.75 or LANA.75) similar to that used at the Savannah River Site Tritium Facilities was analyzed to estimate the particle size distribution of this metal tritide powder and the rate, at which this material dissolves in the human respiratory tract after it is inhaled. This information is used to calculate the committed effective dose received by a worker after inhaling the material. These doses, which were calculated using the same methodology given in the DOE Tritium Handbook, are presented as inhalation intake-to-dose conversion factors (DCF). The DCF for this metal tritide is less than the DCF for tritiated water and radiation worker bioassay programs designed for tritiated water are adequate to monitor for intakes of this material.

Farfan, E.; Labone, T.; Staack, G.; Cheng, Y.; Zhou, Y.; Varallo, T.

2011-11-11T23:59:59.000Z

215

Nonequilibrium electron tunneling in metal-insulator-metal junctions  

Science Journals Connector (OSTI)

The small structure in the conductance curve near zero bias of metal-insulator-metal tunnel junctions has been studied extensively. These experiments are analyzed in detail in a nonequilibrium model. It is shown that this type of zero-bias anomaly can be accounted for entirely by an electron bottleneck arising from the blocking of tunneling states due to nonzero electron relaxation times.

J. G. Adler; H. J. Kreuzer; J. Straus

1975-04-15T23:59:59.000Z

216

Formation of amorphous metal alloys by chemical vapor deposition  

DOE Patents (OSTI)

Amorphous alloys are deposited by a process of thermal dissociation of mixtures of organometallic compounds and metalloid hydrides,e.g., transition metal carbonyl, such as nickel carbonyl and diborane. Various sizes and shapes of deposits can be achieved, including near-net-shape free standing articles, multilayer deposits, and the like. Manipulation or absence of a magnetic field affects the nature and the structure of the deposit. 1 fig.

Mullendore, A.W.

1988-03-18T23:59:59.000Z

217

Superalloy Surface Treatment for Improved Metal Performance  

NLE Websites -- All DOE Office Websites (Extended Search)

Superalloy Surface Treatment Superalloy Surface Treatment for Improved Metal Performance Opportunity Research is active on the patent pending technology, titled "Method to Improve Superalloy Resistance by Surface Treatment." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory (NETL). Overview To produce power more efficiently and cleanly, the next generation of power and aero turbines along with other essential components will have to operate at extreme temperatures and pressures. Currently advanced single crystal nickel-based superalloys are used in such extreme environments. Even though these components are coated with a bond

218

C:\Eco-SSLs\Contaminant Specific Documents\Nickel\March 2007\Eco-SSL for Nickel.wpd  

NLE Websites -- All DOE Office Websites (Extended Search)

Nickel Nickel Interim Final OSWER Directive 9285.7-76 U.S. Environmental Protection Agency Office of Solid Waste and Emergency Response 1200 Pennsylvania Avenue, N.W. Washington, DC 20460 March 2007 This page intentionally left blank i TABLE OF CONTENTS 1.0 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2.0 SUMMARY OF ECO-SSLs FOR NICKEL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 3.0 ECO-SSL FOR TERRESTRIAL PLANTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 4.0 ECO-SSL FOR SOIL INVERTEBRATES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 5.0 ECO-SSL FOR AVIAN WILDLIFE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 5.1 Avian TRV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 5.2 Estimation of Dose and Calculation of the Eco-SSL . . . . . . . . . . . . . . . . . . . . . . . 10 6.0 ECO-SSL FOR MAMMALIAN WILDLIFE .

219

GASAR porous metals process control  

SciTech Connect

GASAR porous metals are produced by melting under a partial pressure of hydrogen and then casting into a mold that ensures directional solidification. Hydrogen is driven out of solution and usually grows as quasi-cylindrical pores normal to the solidification front. Experiments with pure nickel have been carried out under processing conditions of varying H{sub 2} partial pressure, total pressure (H{sub 2} + Ar), and superheat. An analysis that considers heterogeneous bubble nucleation was developed that identifies processing conditions in which hydrogen bubbles are stable in the liquid before solidification. It is hypothesized that these conditions lead to low porosity because these bubbles float out of the melt and escape the advancing solidification front. Experimental data are shown to support this hypothesis.

Apprill, J.M.; Poirier, D.R. [Univ. of Arizona, Tucson, AZ (United States); Maguire, M.C. [Sandia National Labs., Albuquerque, NM (United States); Gutsch, T.C. [California State Univ., Chico, CA (United States)

1998-12-31T23:59:59.000Z

220

National Low-Level Waste Management Program Radionuclide Report Series. Volume 10, Nickel-63  

SciTech Connect

This report outlines the basic radiological, chemical, and physical characteristics of nickel-63 ({sup 63}Ni) and examines how these characteristics affect the behavior of {sup 63}Ni in various environmental media, such as soils, groundwater, plants, animals, the atmosphere, and the human body. Discussions also include methods of {sup 63}Ni production, waste types, and waste forms that contain {sup 63}Ni. The primary source of {sup 63}Ni in the environment has been low-level radioactive waste material generated as a result of neutron activation of stable {sup 62}Ni that is present in the structural components of nuclear reactor vessels. {sup 63}Ni enters the environment from the dismantling activities associated with nuclear reactor decommissioning. However, small amounts of {sup 63}Ni have been detected in the environment following the testing of thermonuclear weapons in the South Pacific. Concentrations as high as 2.7 Bq{sup a} per gram of sample (or equivalently 0.0022 parts per billion) were observed on Bikini Atoll (May 1954). {sup 63}Ni was not created as a fission product species (e.g., from {sup 235}U or {sup 239}Pu fissions), but instead was produced as a result of neutron capture in {sup 63}Ni, a common nickel isotope present in the stainless steel components of nuclear weapons (e.g., stainless-304 contains {approximately}9% total Ni or {approximately}0.3% {sup 63}Ni).

Carboneau, M.L.; Adams, J.P.

1995-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Process for the hydrotreatment of heavy hydrocarbons in the presence of reduced metals  

SciTech Connect

A heavy hydrocarbon charge containing sulfur, asphaltenes and/or resins is hydrotreated in the liquid phase at 250/sup 0/-500/sup 0/ C. under a pressure of 20-350 bars in the presence of a catalyst previously obtained by reacting an organic compound of a transition metal with an organic aluminum compound, in a hydrocarbon free of asphaltene and resin. The transition metal organic compound is advantageously an iron, nickel, cobalt, molybdenum, tungsten or vanadium acetylacetonate or carboxylate.

Dinh, C.T.; Desvard, A.; Jacquin, Y.; Martino, G.

1984-03-06T23:59:59.000Z

222

Pile on the metal  

Science Journals Connector (OSTI)

Discovering superconductivity above room temperature is a dream for modern science and technology. Now, theorists propose that for certain types of superconductors, contact with a metal layer could greatly increase the transition temperatures of these materials—in some cases by as much as an order of magnitude.

Dung-Hai Lee

2008-09-15T23:59:59.000Z

223

Preliminary Compatibility Assessment of Metallic Dispenser Materials for Service in Ethanol Fuel Blends  

SciTech Connect

The compatibility of selected metals representative of those commonly used in dispensing systems was evaluated in an aggressive E20 formulation (CE20a) and in synthetic gasoline (Reference Fuel C) in identical testing to facilitate comparison of results. The testing was performed at modestly elevated temperature (nominally 60 C) and with constant fluid flow in an effort to accelerate potential interactions in the screening test. Based on weight change, the general corrosion of all individual coupons exposed in the vapor phase above Reference Fuel C and CE20a as well as all coupons immersed in Reference Fuel C was essentially nil (<0.3 {micro}m/y), with no evidence of localized corrosion such as pitting/crevice corrosion or selective leaching at any location. Modest discoloration was observed on the copper-based alloys (cartridge brass and phosphor bronze), but the associated corrosion films were quite thin and apparently protective. For coupons immersed in CE20a, four different materials exhibited net weight loss over the entire course of the experiment: cartridge brass, phosphor bronze, galvanized steel, and terne-plated steel. None of these exhibited substantial incompatibility with the test fluid, with the largest general corrosion rate calculated from coupon weight loss to be approximately 4 {micro}m/y for the cartridge brass specimens. Selective leaching of zinc (from brass) and tin (from bronze) was observed, as well as the presence of sulfide surface films rich in these elements, suggesting the importance of the role of sulfuric acid in the CE20a formulation. Analysis of weight loss data for the slightly corroded metals indicated that the corrosivity of the test environment decreased with exposure time for brass and bronze and increased for galvanized and terne-plated steel. Other materials immersed in CE20a - type 1020 mild steel, type 1100 aluminum, type 201 nickel, and type 304 stainless steel - each appeared essentially immune to corrosion at the test conditions.

Pawel, Steven J [ORNL; Kass, Michael D [ORNL; Janke, Christopher James [ORNL

2009-11-01T23:59:59.000Z

224

Synthesis and vibrational spectroscopic characterisation of nickel containing aurichalcite  

Science Journals Connector (OSTI)

Raman spectroscopy complimented with supplementary infrared spectroscopy has been used to characterise a synthetic nickel substituted aurichalcite a zinc/nickel hydroxy carbonate, (Zn2+, Cu2+, Ni2+)5(CO3)2(OH)6. XRD patterns show high orientation and indicate the presence of some minor impurities. The diffraction patterns for the Ni-aurichalcite are well correlated with the standard reference patterns. EDAX analyses indicate variations in chemical composition of Zn/Ni ratios of ?20:1. The symmetry of the carbonate anion in aurichalcite is Cs and is composition dependent. This symmetry reduction results in multiple bands in both the symmetric stretching and bending regions. The intense band for the Ni-aurichalcite at 1070 cm?1 is assigned to the ?1(CO3)2? symmetric stretching mode. Three Raman bands assigned to the ?3(CO3)2? antisymmetric stretching modes are observed for Ni-aurichalcite at 1372, 1480 and 1543 cm?1. Multiple Raman bands are observed in the regions from 800 to 850 cm?1 and 720 to 750 cm?1, and are attributed to ?2 and ?4 bending modes confirming the reduction of the carbonate anion symmetry in the aurichalcite structure. This research proves that nickel containing aurichalcites can be synthesised in the laboratory thus mimicing the natural nickel containing aurichalcites.

Ray L. Frost; Ashley Locke; B. Jagannadha Reddy; Matt C. Hales

2008-01-01T23:59:59.000Z

225

Hydrogenation of Magnesium Nickel Boride for Reversible Hydrogen Storage  

Science Journals Connector (OSTI)

Hydrogenation of Magnesium Nickel Boride for Reversible Hydrogen Storage ... Use of hydrogen for transportation applications requires materials that not only store hydrogen at high density but that can operate reversibly at temperatures and pressures below approximately 100 °C and 10 bar, respectively. ... This composition is based on assuming the following complete hydrogenation reaction:which stores 2.6 wt % hydrogen. ...

Wen Li; John J. Vajo; Robert W. Cumberland; Ping Liu; Son-Jong Hwang; Chul Kim; Robert C. Bowman, Jr.

2009-11-06T23:59:59.000Z

226

Nickel Sorption Mechanisms in a Mixed Pyrophyllite-Montmorillonite System  

E-Print Network (OSTI)

Nickel Sorption Mechanisms in a Mixed Pyrophyllite-Montmorillonite System E. J. Elzinga Surface the mechanism responsible for the initial stage of Ni sorption, and surface precipitation being the slower structure (EXAFS) data on sorption studies on Ni/clay systems revealed that the Ni sorption behavior

Sparks, Donald L.

227

Molten salt extraction process for the recovery of valued transition metals from land-based and deep-sea minerals  

DOE Patents (OSTI)

A process for extracting transition metals and particularly cobalt and manganese together with iron, copper and nickel from low grade ores (including ocean-floor nodules) by converting the metal oxides or other compositions to chlorides in a molten salt, and subsequently using a combination of selective distillation at temperatures below about 500.degree. C., electrolysis at a voltage not more negative than about -1.5 volt versus Ag/AgCl, and precipitation to separate the desired manganese and cobalt salts from other metals and provide cobalt and manganese in metallic forms or compositions from which these metals may be more easily recovered.

Maroni, Victor A. (Naperville, IL); von Winbush, Samuel (Huntington, NY)

1988-01-01T23:59:59.000Z

228

Nickel-Specific Response in the Transcriptional Regulator, 'Escherichia Coli'NikR  

SciTech Connect

Studies of the transcriptional repression of the Ni-specific permease encoded by the Pnik operon by Escherichia coli NikR using a LacZ reporter assay establish that the NikR response is specific to nickel in vivo. Toward understanding this metal ion-specific response, X-ray absorption spectroscopy (XAS) analysis of various M-NikR complexes (M = Co(II), Ni(II), Cu(II), Cu(I), and Zn(II)) was used to show that each high-affinity binding site metal adopts a unique structure, with Ni(II) and Cu(II) being the only two metal ions to feature planar four-coordinate complexes. The results are consistent with an allosteric mechanism whereby the geometry and ligand selection of the metal present in the high-affinity site induce a unique conformation in NikR that subsequently influences DNA binding. The influence of the high-affinity metal on protein structure was examined using hydrogen/deuterium (H/D) exchange detected by liquid chromatography-electrospray ionization mass spectrometry (LC-ESI-MS). Each NikR complex gives rise to differing amounts of H/D exchange; Zn(II)- and Co(II)-NikR are most like apo-NikR, while the exchange time course is substantially different for Ni(II) and to a lesser extent for Cu(II). In addition to the high-affinity metal binding site, E. coli NikR has a low-affinity metal-binding site that affects DNA binding affinity. We have characterized this low-affinity site using XAS in heterobimetallic complexes of NikR. When Cu(II) occupies the high-affinity site and Ni(II) occupies the low-affinity site, the Ni K-edge XAS spectra show that the Ni site is composed of six N/O-donors. A similar low-affinity site structure is found for the NikR complex when Co(II) occupies the low-affinity site and Ni(II) occupies the high-affinity site, except that one of the Co(II) ligands is a chloride derived from the buffer.

Leitch, S.; Bradley, M.J.; Rowe, J.L.; Chivers, P.T.; Maroney, M.J.; /Massachusetts U., Amherst /Washington U., St. Louis

2007-07-10T23:59:59.000Z

229

Nickel-Specific Response in the Transcriptional Regulator, Escherichia coli NikR  

SciTech Connect

Studies of the transcriptional repression of the Ni-specific permease encoded by the P{sub nik} operon by Escherichia coli NikR using a LacZ reporter assay establish that the NikR response is specific to nickel in vivo. Toward understanding this metal ion-specific response, X-ray absorption spectroscopy (XAS) analysis of various M-NikR complexes (M = Co(II), Ni(II), Cu(II), Cu(I), and Zn(II)) was used to show that each high-affinity binding site metal adopts a unique structure, with Ni(II) and Cu(II) being the only two metal ions to feature planar four-coordinate complexes. The results are consistent with an allosteric mechanism whereby the geometry and ligand selection of the metal present in the high-affinity site induce a unique conformation in NikR that subsequently influences DNA binding. The influence of the high-affinity metal on protein structure was examined using hydrogen/deuterium (H/D) exchange detected by liquid chromatography-electrospray ionization mass spectrometry (LC-ESI-MS). Each NikR complex gives rise to differing amounts of H/D exchange; Zn(II)- and Co(II)-NikR are most like apo-NikR, while the exchange time course is substantially different for Ni(II) and to a lesser extent for Cu(II). In addition to the high-affinity metal binding site, E. coli NikR has a low-affinity metal-binding site that affects DNA binding affinity. We have characterized this low-affinity site using XAS in heterobimetallic complexes of NikR. When Cu(II) occupies the high-affinity site and Ni(II) occupies the low-affinity site, the Ni K-edge XAS spectra show that the Ni site is composed of six N/O-donors. A similar low-affinity site structure is found for the NikR complex when Co(II) occupies the low-affinity site and Ni(II) occupies the high-affinity site, except that one of the Co(II) ligands is a chloride derived from the buffer.

Leitch,S.; Bradley, M.; Rowe, J.; Chivers, P.; Maroney, M.

2007-01-01T23:59:59.000Z

230

Effects of Additive Elements on the Phase Formation and Morphological Stability of Nickel Monosilicide Films  

SciTech Connect

Alloying elements can substantially affect the formation and morphological stability of nickel monosilicide. A comprehensive study of phase formation was performed on 24 Ni alloys with varying concentrations of alloying elements. Silicide films have been used for more than 15 years to contact the source, drain and gate of state-of-the-art complementary-metal-oxide-semiconductor (CMOS) devices. In the past, the addition of alloying elements was shown to improve the transformation from the high resistivity C49 to the low resistivity C54-TiSi{sub 2} phase and to allow for the control of surface and interface roughness of CoSi{sub 2} films as well as produce significant improvements with respect to agglomeration of the films. Using simultaneous time-resolved X-ray diffraction (XRD), resistance and light scattering measurements, we follow the formation of the silicide phases in real time during rapid thermal annealing. Additions to the Ni-Si system lead to modifications in the phase formation sequence at low temperatures (metal-rich phases), to variations in the formation temperatures of NiSi and NiSi{sub 2}, and to changes in the agglomeration behavior of the films formed. Of the 24 elements studied, additions of Mo, Re, Ta and W are amongst the most efficient to retard agglomeration while elements such as Pd, Pt and Rh are most efficient to retard the formation of NiSi{sub 2}.

Lavoie,C.; Detavernier, C.; Cabral, Jr. , C.; d'Heurle, F.; Kellock, A.; Jordan-Sweet, J.; Harper, J.

2006-01-01T23:59:59.000Z

231

Pollution prevention and waste minimization in metal finishing  

SciTech Connect

This study was done to identify pollution prevention and waste minimization opportunities in the general plating department and the printed circuit board processing department. Recommendations for certain recycle and recovery technologies were mad in order to reduce usage of acids and the volume of heavy metal sludge that is formed at the industrial Wastewater Pretreatment Facility (IWPF). Some of these technologies discussed were acid purification, electrowinning, and ion exchange. Specific technologies are prescribed for specific processes. Those plating processes where the metals can be recovered are copper, nickel, gold, cadmium, tin, lead, and rhodium.

Stimetz, C.J.

1994-12-01T23:59:59.000Z

232

CHARACTERIZATION OF THE STRUCTURE AND REACTIVITY OF A NICKEL(II)-TRIPEPTIDE MIMIC OF NICKEL SUPEROXIDE DISMUTASE  

E-Print Network (OSTI)

. However, prior to this work, the structure and chemical reactivity of the nickel-peptide complex were undefined. The work presented herein involves structural and reactivity investigations of the MAP-tag bound with NiII in the dianionic complex [Ni-NCC]2...

Glass, Amanda M.

2012-08-31T23:59:59.000Z

233

Catalysis Without Precious Metals  

SciTech Connect

Written for chemists in industry and academia, this ready reference and handbook summarizes recent progress in the development of new catalysts that do not require precious metals. The research thus presented points the way to how new catalysts may ultimately supplant the use of precious metals in some types of reactions, while highlighting the remaining challenges. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

Bullock, R. Morris

2010-11-01T23:59:59.000Z

234

Metal oxide films on metal  

DOE Patents (OSTI)

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

235

Draft Genome Sequence for Microbacterium laevaniformans Strain OR221, a Bacterium Tolerant to Metals, Nitrate, and Low pH  

SciTech Connect

Microbacterium laevaniformans strain OR221 was isolated from subsurface sediments obtained from the Field Research Center (FRC) in Oak Ridge, TN. It was characterized as a bacterium tolerant to heavy metals such as uranium, nickel, cobalt, cadmium, as well as nitrate and low pH. We present its draft genome sequence.

Brown, Steven D [ORNL; Palumbo, Anthony Vito [ORNL; Panikov, Nikolai [ORNL; Ariyawansa, Thilini [Northeastern University; Klingeman, Dawn Marie [ORNL; Johnson, Courtney M [ORNL; Land, Miriam L [ORNL; Utturkar, Sagar M [ORNL; Epstein, Slava [Northeastern University

2012-01-01T23:59:59.000Z

236

Deciphering the structure of nano-nickel composites  

SciTech Connect

A model has been developed to predict piezoresistivity in Silicone/Nickel Nanostrand composites. This model combines the theory of quantum mechanical tunneling with percolation theory to obtain macroscopic composite resistivity as a function of strain from quantum mechanical principles and statistical characterization of constituent morphology. It has been shown that a model incorporating quantum mechanical tunneling and percolation theory can be used to predict piezoresistivity in Silicone/Nickel Nanostrand composites. The predictions of this model qualitatively demonstrate the large drop in resistivity with strain that these composites exhibit. The quantitative accuracy of the model was shown to be usually within one order of magnitude. Further work must be done to obtain an empirical distribution of inter-nanostrand gap distances, the tunneling barrier height ({lambda}), and the fraction of conductive junctions as a function of strain for these composites.

Johnson, Oliver K [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

237

Sulfur poisoning of H/sub 2/ and CO adsorption on supported nickel  

SciTech Connect

New and previously published adsorption data for hydrogen and carbon monoxide on various fresh and presulfided nickel/alumina catalysts showed that at 298/sup 0/K, the fractional hydrogen uptake decreased linearly with sulfur coverage; that irreversible adsorption of carbon monoxide was higher on sulfided than on fresh catalysts at 190/sup 0/, 273/sup 0/, and 300/sup 0/K, probably as a result of nickel tetracarbonyl formation; and that substantial amounts of nickel tetracarbonyl were formed in the gas phase in the presence of sulfided catalysts, which caused significant loss of nickel. The formation of the nickel tetracarbonyl probably proceeded via stable subcarbonyl species. At carbon monoxide pressures of < 1 mm Hg, no carbon monoxide absorbed at room temperature, but at methanation temperature (473/sup 0/-673/sup 0/K), dissociative adsorption did take place. Chemisorption of carbon monoxide therefore, cannot be used to measure nickel dispersion on used catalysts.

Bartholomew, C.H.; Pannell, R.B.

1980-01-01T23:59:59.000Z

238

PLUTONIUM METALLIC FUELS FOR FAST REACTORS  

SciTech Connect

Early interest in metallic plutonium fuels for fast reactors led to much research on plutonium alloy systems including binary solid solutions with the addition of aluminum, gallium, or zirconium and low-melting eutectic alloys with iron and nickel or cobalt. There was also interest in ternaries of these elements with plutonium and cerium. The solid solution and eutectic alloys have most unusual properties, including negative thermal expansion in some solid-solution alloys and the highest viscosity known for liquid metals in the Pu-Fe system. Although metallic fuels have many potential advantages over ceramic fuels, the early attempts were unsuccessful because these fuels suffered from high swelling rates during burn up and high smearing densities. The liquid metal fuels experienced excessive corrosion. Subsequent work on higher-melting U-PuZr metallic fuels was much more promising. In light of the recent rebirth of interest in fast reactors, we review some of the key properties of the early fuels and discuss the challenges presented by the ternary alloys.

STAN, MARIUS [Los Alamos National Laboratory; HECKER, SIEGFRIED S. [Los Alamos National Laboratory

2007-02-07T23:59:59.000Z

239

High-temperature fabricable nickel-iron aluminides  

DOE Patents (OSTI)

Nickel-iron aluminides are described that are based on Ni.sub.3 Al, and have significant iron content, to which additions of hafnium, boron, carbon and cerium are made resulting in Ni.sub.3 Al base alloys that can be fabricated at higher temperatures than similar alloys previously developed. Further addition of molybdenum improves oxidation and cracking resistance. These alloys possess the advantages of ductility, hot fabricability, strength, and oxidation resistance.

Liu, Chain T. (Oak Ridge, TN)

1988-02-02T23:59:59.000Z

240

Electrochemical behavior of reactively sputtered iron-doped nickel oxide  

SciTech Connect

Iron-doped nickel oxide films were deposited by reactive sputtering from elemental and alloy targets in a 20% oxygen/argon atmosphere and were characterized for use as oxygen evolution catalysts. The incorporation of iron reduced the overpotential required for oxygen evolution by as much as 300 mV at a current density of 100 mA/cm{sup 2} compared to undoped nickel oxide deposited under similar conditions. Tafel slopes were reduced from 95 mV/dec in undoped NiO{sub x} films to less than 40 mV/dec for films containing 1.6 to 5.6 mole percent (m/o) iron, indicating a change in the rate-limiting step from the primary discharge of OH{sup {minus}} ions to the recombination of oxygen radicals. Resistivity, structural, and compositional measurements indicate that high oxygen content is necessary to gain the full benefit of the iron dopant. Initial tests in KOH indicate excellent long-term stability. A film deposited from the FeNi alloy target, which exhibited low oxygen overpotentials and a Tafel slope of 35 mV/dec, had not degraded appreciably following more than 7,000 h of operation at an anodic current density of 20 mA/cm{sup 2}. Taken together, the low oxygen evolution reaction overpotentials, the excellent stability in KOH, and the relative insensitivity to iron content indicative that reactively sputtered iron-doped nickel oxide is promising as an oxygen catalyst.

Miller, E.L.; Rocheleau, R.E. [Univ. of Hawaii, Honolulu, HI (United States)

1997-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Metal Toxicity  

Science Journals Connector (OSTI)

Problems posed to plants by metal toxicity in the soils of the world are basically of two kinds. The first kind are of natural origin. These arise either as a consequence of the nature of the parent material f...

T. McNeilly

1994-01-01T23:59:59.000Z

242

Dendritic metal nanostructures  

DOE Patents (OSTI)

Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

2010-08-31T23:59:59.000Z

243

Ultralight Metallic Microlattices  

Science Journals Connector (OSTI)

...a 100-nm-thick uniform conformal coating can be achieved, resulting in a cellular...Ultralight multiwalled carbon nanotube aerogel . ACS Nano 4 , 7293 ( 2010...self-propagating photopolymer waveguide prototyping, coating the template by electroless nickel plating...

T. A. Schaedler; A. J. Jacobsen; A. Torrents; A. E. Sorensen; J. Lian; J. R. Greer; L. Valdevit; W. B. Carter

2011-11-18T23:59:59.000Z

244

The effect of parent metal properties on the performance of Lattice Block Material{trademark}  

SciTech Connect

Lattice Block Material{trademark}, or LBM{trademark} is a unique lightweight structure consisting of repeated cells with an internal node connected to, in the most common configuration, 14 ligaments. In its metallic version, this product is available in a variety of castable metals including aluminum alloys, copper alloys, nickel alloys and steels. The relationship between LBM structural performance (strength and stiffness) and parent metal properties is investigated using compression tests in three primary orientations and 3-pt. bend tests. Analytical assessment of the LBM via finite element analysis shows reasonable agreement with experimental findings and provides predictions for LBM capabilities with different materials, unit cell sizes and ligament geometries.

Renauld, M.L.; Giamei, A.F.; Thompson, M.S. [United Technologies Research Center, East Hartford, CT (United States). Materials and Structures Technology Dept.; Priluck, J. [JAMCORP, Wilmington, MA (United States)

1998-12-31T23:59:59.000Z

245

Doping Graphene with Metal Contacts  

Science Journals Connector (OSTI)

Making devices with graphene necessarily involves making contacts with metals. We use density functional theory to study how graphene is doped by adsorption on metal substrates and find that weak bonding on Al, Ag, Cu, Au, and Pt, while preserving its unique electronic structure, can still shift the Fermi level with respect to the conical point by ?0.5??eV. At equilibrium separations, the crossover from p-type to n-type doping occurs for a metal work function of ?5.4??eV, a value much larger than the graphene work function of 4.5 eV. The numerical results for the Fermi level shift in graphene are described very well by a simple analytical model which characterizes the metal solely in terms of its work function, greatly extending their applicability.

G. Giovannetti; P. A. Khomyakov; G. Brocks; V. M. Karpan; J. van den Brink; P. J. Kelly

2008-07-10T23:59:59.000Z

246

Slow positron annihilation spectroscopy and electron microscopy of electron beam evaporated cobalt and nickel silicides  

SciTech Connect

Metal silicide thin films on single-crystal silicon substrates are the subject of much research, due to their applications as electrical contacts and interconnects, diffusion barriers, low resistance gates, and field-assisted positron moderators, among others. Defects within the silicide layer and/or at the silicide/silicon interface are detrimental to device performance, since they can act as traps for charge carriers, as well as positrons. Pinholes penetrating the film are another detriment particularly for cobalt silicide films, since they allow electrons to permeate the film, rather than travel ballistically, in addition to greatly increasing surface area for recombination events. A series of epitaxial cobalt and nickel silicide thin films, deposited via electron-beam evaporation and annealed at various temperatures, have been grown on single-crystal silicon (111) substrates, in an effort to establish a relationship between deposition and processing parameters and film quality. The films have been analyzed by transmission and scanning electron microscopy, sputter depth profile Auger, and slow positron annihilation spectroscopy. The latter has been shown to both correlate and complement the traditional electron microscopy results.

Frost, R.L.; DeWald, A.B. (Georgia Institute of Technology, Atlanta, Georgia 30332 (USA)); Zaluzec, M.; Rigsbee, J.M. (University of Illinois, Urbana, Illinois 61801 (USA)); Nielsen, B.; Lynn, K.G. (Brookhaven National Laboratory, Upton, New York 11973 (USA))

1990-07-01T23:59:59.000Z

247

Competing, Coverage-Dependent Decomposition Pathways for C2Hy Species on Nickel (111) Jonathan E. Mueller,  

E-Print Network (OSTI)

reasons. Nickel is the primary catalyst in the steam reforming process for converting methane and water in which it typically selects for methane production.4 More recently, nickel has also been used extensively

Goddard III, William A.

248

Theory of bonding of transition metals to nontransition metals  

Science Journals Connector (OSTI)

We present a theory of the chemical bond in compounds consisting of both transition metals and nontransition metals. Chemical trends in the bonding properties are established by directly comparing the total energies of a large number of such compounds with the total energies of their constituents. These chemical trends are analyzed in terms of the s-, p-, and d-like state densities of the compounds and the constituents. Rather different types of bonding are shown to result when the atomic s and p levels of the nontransition metal lie above, below, and near the energy of the transition-metal d level. The heat of compound formation is shown to result from a competition between two simple physical effects: (1) the weakening of the transition-metal bonds by the lattice dilatation required for the accommodation of the nontransition metal, and (2) the increased bonding which results from the occupation of the bonding members of the hybrid states formed from the interaction between the transition-metal d states and the s-p states on the nontransition metal. Our theoretical values for the heats of formation of these compounds are generally similar to those given by Miedema's empirical formula. Distinctive aspects of the variation of the heat of formation with the number of valence electrons reveal, however, that the microscopic picture on which the empirical formula is based is quite different from that given by our self-consistent energy-band theory.

C. D. Gelatt; Jr.; A. R. Williams; V. L. Moruzzi

1983-02-15T23:59:59.000Z

249

Polymer quenched prealloyed metal powder  

DOE Patents (OSTI)

A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3 % Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

Hajaligol, Mohammad R. (Midlothian, VA); Fleischhauer, Grier (Midlothian, VA); German, Randall M. (State College, PA)

2001-01-01T23:59:59.000Z

250

Determining the Heavy Metal Pollution in Mascara (Algeria) by Using Casuarina equisetifolia  

E-Print Network (OSTI)

Abstract. In this study, Casuarina equisetifolia needles were evaluated as the possible biomonitors of heavy metal air pollution in Mascara (Algeria). The needles were sampled from seven locations with different degrees of metal pollution (near roads) and from a control site. The concentrations of lead, zinc, copper and nickel were measured by using a flame atomic absorption spectrophotometer. The maximal values of these four metals were found in the samples collected near the roads and the minimal values were found in the control site. Furthermore, sites with high traffic density and frequency of cars stoppage showed high heavy metal concentrations. However, the comparison of concentrations of all metals showed that the zinc one had the highest concentration of all. The cluster analysis divided the selected sampling sites in three distinct clusters. With regard to the results of this study, Casuarina equisetifolia can be successfully applied in biomonitoring of air pollution. Key words: Casuarina equisetifolia, Mascara, biomonitors, pollution, heavy metals.

Lakhdari Aissa; Benabdeli Kéloufi

251

Supported nickel catalysts for low temperature methane steam reforming: comparison between metal additives and support modification  

Science Journals Connector (OSTI)

The effect of Ag (1 wt%) and Au (1 wt%) on the catalytic properties of Ni/Al2O3 (7 wt% Ni) for methane steam reforming (MSR) was studied in parallel with...2 (6 wt%) and La2O3 (6 wt%) addition. The addition of 1 ...

Monica Dan; Maria Mihet; Alexandru R. Biris…

2012-02-01T23:59:59.000Z

252

Improving nickel metal hydride batteries through research in negative electrode corrosion control and novel electrode materials  

E-Print Network (OSTI)

electrode materials. In order to fully understand the processes involved in the corrosion study, tests were carried at Brookhaven National Laboratory using X-ray Absorption Near Edge Spectroscopy. These tests showed that Zn prevented the corrosion of Ni-a...

Alexander, Michael Scott

1997-01-01T23:59:59.000Z

253

Thermal analysis of nickel/metal (Ni/MH) hydride battery during charge cycle  

Science Journals Connector (OSTI)

A three-dimensional mathematical model containing temporal and spatial coordinates is presented for analyzing the thermal behavior and obtaining the internal temperature profile of cylindrical Ni/MH battery. This model is performed to investigate the ... Keywords: Ni/MH battery, charge, heat transfer coefficient, thermal analysis

Nabi Jahantigh; Ebrahim Afsharia

2008-02-01T23:59:59.000Z

254

Thermal behavior of nickel/metal hydride battery during charging and discharging  

Science Journals Connector (OSTI)

This work discusses thermal behavior of Ni/MH battery with experimental methods. The present work not ... new way to get more exactly parameters and thermal model, but also concentrates on thermal behavior in dis...

K. Yang; D. H. Li; S. Chen; F. Wu

2009-02-01T23:59:59.000Z

255

Thermal behavior analysis of nickel/metal hydride battery during overcharging  

Science Journals Connector (OSTI)

To analyze the thermal behavior of the cylinder Ni/MH battery during overcharging, a two-dimensional thermal model is provided in this work. More ... reliable data is provided to create the precise thermal model....

Kai Yang; JinJing An; Shi Chen

2010-05-01T23:59:59.000Z

256

Blood Types  

E-Print Network (OSTI)

Broadcast Transcript: According to the Japanese, you can tell a lot about a person by their blood type: Type A is the farmer, calm and responsible; Type B is the hunter, independent and creative; Type AB is humanistic, ...

Hacker, Randi; Tsutsui, William

2007-03-14T23:59:59.000Z

257

Influence of dimensionality on deep tunneling rates: A study based on the hydrogen-nickel system  

E-Print Network (OSTI)

, such as hydrogen embrittlement, catalysis, and fuel storage.1 Moreover, tunneling draws fundamental interest sinceInfluence of dimensionality on deep tunneling rates: A study based on the hydrogen-nickel system hydrogen into a surface site of a nickel crystal is used to investigate deep tunneling phenomena. A method

Zeiri, Yehuda

258

Adsorption and Desorption of Hydrocarbons on a Supported Nickel Cracking Catalyst  

Science Journals Connector (OSTI)

...Hydrocarbons on a Supported Nickel Cracking Catalyst A. K. Galwey A study has been made...a high area supported nickel cracking catalyst. Measurements have been made of (i...adsorbed, after standard preparation of the catalyst, when a known volume of each hydrocarbon...

1963-01-01T23:59:59.000Z

259

Z. B. He et al., Nickel catalyst shape Etchant-induced shaping of nanoparticle  

E-Print Network (OSTI)

Z. B. He et al., Nickel catalyst shape - 1 - Etchant-induced shaping of nanoparticle catalysts al., Nickel catalyst shape - 2 - Abstract Carbon nanofibres (CNFs) obtained by plasma show in this paper that the shape of Ni nanoparticle catalysts, and in turn the CNF properties, can

Boyer, Edmond

260

Reaktionshemmender Einfluß von Schwefel auf die Aufkohlung von Nickel in Methan-Wasserstoff-Gemischen  

Science Journals Connector (OSTI)

The carburization of nickel in CH4-H2 and CH4-H2S-H2 gas mixtures was studied in a flow apparatus at 1060–1280 K applying the resistance-relaxation technique. The reaction of nickel with CH4 is found to be therma...

R. Kikowatz; G. Hörz

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM  

E-Print Network (OSTI)

In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel

Dunin-Borkowski, Rafal E.

262

Journal of Magnetism and Magnetic Materials 225 (2001) 337345 Irreversible magnetization in nickel nanoparticles  

E-Print Network (OSTI)

in this magnetic nanoparticle system. # 2001 Elsevier Science B.V. All rights reserved. PACS: 75.10.Nr; 75.50.KjJournal of Magnetism and Magnetic Materials 225 (2001) 337Ā­345 Irreversible magnetization in nickel in revised form 20 October 2000 Abstract We report magnetic studies on nickel nanoparticle films of average

Zuo, Fulin

263

Nickel Sorption Mechanisms in a PyrophylliteMontmorillonite Mixture Evert J. Elzinga1  

E-Print Network (OSTI)

Nickel Sorption Mechanisms in a PyrophylliteĀ­Montmorillonite Mixture Evert J. Elzinga1 and Donald L-mail: elzinga@udel.edu Received October 6, 1998; accepted February 17, 1999 Nickel sorption on pyrophyllite in the overall Ni uptake in the clay mixture, and that neither sorption mechanism truly out-competed the other

Sparks, Donald L.

264

Superoxide dismutase activity and novel reactions with hydrogen peroxide of histidine-containing nickel(II)-oligopeptide complexes and nickel(II)-induced structural changes in synthetic DNA  

Science Journals Connector (OSTI)

At physiologic pH values, histidine-containing nickel(II) oligopeptides reduced the flux of superoxide anion (O2) generated in the hypoxanthine/xanthine oxidase system. The postulated involvement of the Ni(III)/N...

E. Nieboer; R. T. Tom; F. E. Rossetto

265

Composite metal membrane  

DOE Patents (OSTI)

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, Nathaniel M. (Espanola, NM); Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM); Birdsell, Stephan A. (Los Alamos, NM)

1998-01-01T23:59:59.000Z

266

Composite metal membrane  

DOE Patents (OSTI)

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

1998-04-14T23:59:59.000Z

267

Torsion Testing of Diffusion Bonded LIGA Formed Nickel  

SciTech Connect

A test technique has been devised which is suitable for the testing of the bond strength of batch diffusion bonded LIGA or DXRL defined structures. The method uses a torsion tester constructed with the aid of LIGA fabrication and distributed torsion specimens which also make use of the high aspect ratio nature of DXRL based processing. Measurements reveal achieved bond strengths of 130MPa between electroplated nickel with a bond temperature of 450 C at 7 ksi pressure which is a sufficiently low temperature to avoid mechanical strength degradation.

Buchheit, T.E.; Christenson, T.R.; Schmale, D.T.

1999-01-27T23:59:59.000Z

268

Advanced nickel base alloys for high strength, corrosion applications  

DOE Patents (OSTI)

Improved nickel-base alloys of enhanced strength and corrosion resistance, produced by atomization of an alloy melt under an inert gas atmosphere and of composition 0--20Fe, 10--30Cr, 2--12Mo, 6 max. Nb, 0.05--3 V, 0.08 max. Mn, 0.5 max. Si, less than 0.01 each of Al and Ti, less than 0.05 each of P and S, 0.01--0.08C, less than 0.2N, 0.1 max. 0, bal. Ni. 3 figs.

Flinn, J.E.

1998-11-03T23:59:59.000Z

269

Plasma-assisted catalytic ionization using porous nickel plate  

SciTech Connect

Hydrogen atomic pair ions, i.e., H{sup +} and H{sup -} ions, are produced by plasma-assisted catalytic ionization using a porous nickel plate. Positive ions in a hydrogen plasma generated by dc arc discharge are irradiated to the porous plate, and pair ions are produced from the back of the irradiation plane. It becomes clear that the production quantity of pair ions mainly depends on the irradiation current of positive ions and the irradiation energy affects the production efficiency of H{sup -} ions.

Oohara, W.; Maeda, T.; Higuchi, T. [Department of Electronic Device Engineering, Yamaguchi University, Ube 755-8611 (Japan)

2011-09-15T23:59:59.000Z

270

DOE Seeking Input on Alternative Uses of Nickel Inventory | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Seeking Input on Alternative Uses of Nickel Inventory Seeking Input on Alternative Uses of Nickel Inventory DOE Seeking Input on Alternative Uses of Nickel Inventory March 9, 2007 - 10:28am Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) is seeking input from industry representatives on the safe disposition of approximately 15,300 tons of nickel scrap recovered from uranium enrichment process equipment at the Department's Oak Ridge, TN, and Paducah, KY, facilities. The Expression of Interest (EOI), released today, will assist in DOE's evaluation of restricted uses of its nickel material for controlled radiological applications. These restricted uses could include use in commercial nuclear power plants, DOE nuclear facilities, or by the U.S. Navy. The Department will solicit input through May 8, 2007.

271

DOE Seeking Input on Alternative Uses of Nickel Inventory | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Seeking Input on Alternative Uses of Nickel Inventory DOE Seeking Input on Alternative Uses of Nickel Inventory DOE Seeking Input on Alternative Uses of Nickel Inventory March 9, 2007 - 10:28am Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) is seeking input from industry representatives on the safe disposition of approximately 15,300 tons of nickel scrap recovered from uranium enrichment process equipment at the Department's Oak Ridge, TN, and Paducah, KY, facilities. The Expression of Interest (EOI), released today, will assist in DOE's evaluation of restricted uses of its nickel material for controlled radiological applications. These restricted uses could include use in commercial nuclear power plants, DOE nuclear facilities, or by the U.S. Navy. The Department will solicit input through May 8, 2007.

272

The synthesis, characterization and reactivity of high oxidation state nickel fluorides  

SciTech Connect

The research described in this thesis has mainly addressed the challenge of the synthesis of thermodynamically unstable nickel fluorides, which cannot be made by traditional thermal methods. A low-temperature approach towards the synthesis of such transition metal fluorides exploits the greater thermodynamic stability of high oxidation states in anions and involves the use of anhydrous hydrogen fluoride (aHF) as a solvent. The general method consists of combining an aHF soluble starting material (e.g., K{sub 2}NiF{sub 6}) with a Lewis fluoroacid (e.g., BF{sub 3}), which precipitates a neutral polymeric solid state fluoride: 2 K{sup +} + NiF{sub 6}{sup 2{minus}} + BF{sub 3} {r_arrow} NiF{sub 4} + 2 BF{sub 4}{sup {minus}} + 2 K{sup +}. At room temperature, this reaction yields a different structural phase, with composition K{sub x}NiF{sub 3} (x {approx} 0.18). This material has a pseudo-hexagonal tungsten bronze structure (H{sub 0}-K{sub x}NiF{sub 3}), and is an ionic conductor, probably due to K{sup +} ions hosted in the lattice channels. R-NiF{sub 3} is capable of fluorinating a wide range of inorganic and organic substrates. These reactions have probably shed light on the mechanism of the Simons Electrochemical Fluorination (ECF) Process, an important industrial method of fluorinating organic compounds. It has long been speculated that NiF{sub 3} plays a role in the ECF process, which uses nickel electrodes in aHF solvent. K{sub 2}NiF{sub 6} also fluorinates organic compounds in aHF, but interestingly, yields different fluorinated products. The reduction of R-NiF{sub 3} and K{sub 2}NiF{sub 6} during fluorination reactions yields NiF{sub 2}. A method has been developed to regenerate NiF{sub 6}{sup 2{minus}} from NiF{sub 2}.

Chacon, L.C. [Univ. of Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley National Lab., CA (United States). Chemical Sciences Div.

1997-12-01T23:59:59.000Z

273

Carbon migration in 5Cr-0.5Mo/21Cr-12Ni dissimilar metal welds  

SciTech Connect

The carbon migration between a ferritic steel and an austenitic steel was studied in submerged arc-welded 5Cr-0.5Mo/21Cr-12Ni dissimilar metal welds (DMWs) after aging at 500 C for various times and after long-term service in technical practice. The distribution of carbon, chromium, nickel, and iron in the areas around the weld interface was determined by electron probe microanalysis, and the microstructural aspect in the carbon-depleted/enriched zone was characterized by optical microscopy and transmission electron microscopy (TEM). Furthermore, the precipitation sequences and composition characteristics of the carbides were identified by diffraction pattern microanalysis and energy-dispersive X-ray (EDX) microanalysis. It was found (1) that there exists a coherent relationship between intracrystalline M{sub 23}C{sub 6} and the austenitic matrix; (2) that the composition of M{sub 23}C{sub 6} in the carbon-enriched zone is independent of the duration of aging and service; (3) that the maximum carbon concentration is determined by the carbide type, the composition characteristic of precipitated carbides, and the concentration of carbide-forming Cr adjacent to the weld interface in the carbon-enriched zone; and (4) that the carbon migration in the 5Cr-0.5Mo/21Cr-12Ni DMWs can be described by a diffusion model.

Huang, M.L.; Wang, L. [Dalian Univ. of Technology (China). Dept. of Materials Engineering

1998-12-01T23:59:59.000Z

274

DIRECT DECOMPOSITION OF METHANE TO HYDROGEN ON METAL LOADED ZEOLITE CATALYST  

SciTech Connect

The manufacture of hydrogen from natural gas is essential for the production of ultra clean transportation fuels. Not only is hydrogen necessary to upgrade low quality crude oils to high-quality, low sulfur ultra clean transportation fuels, hydrogen could eventually replace gasoline and diesel as the ultra clean transportation fuel of the future. Currently, refinery hydrogen is produced through the steam reforming of natural gas. Although efficient, the process is responsible for a significant portion of refinery CO2 emissions. This project is examining the direct catalytic decomposition of methane as an alternative to steam reforming. The energy required to produce one mole of hydrogen is slightly lower and the process does not require water-gas-shift or pressure-swing adsorption units. The decomposition process does not produce CO2 emissions and the product is not contaminated with CO -- a poison for PEM fuel cells. In this work we examined the direct catalytic decomposition of methane over a metal modified zeolite catalyst and the recovery of catalyst activity by calcination. A favorable production of hydrogen was obtained, when compared with previously reported nickel-zeolite supported catalysts. Reaction temperature had a strong influence on catalyst activity and on the type of carbon deposits. The catalyst utilized at 873 and 973 K could be regenerated without any significant loss of activity, however the catalyst utilized at 1073 K showed some loss of activity after regeneration.

Lucia M. Petkovic; Daniel M. Ginosar; Kyle C. Burch; Harry W. Rollins

2005-08-01T23:59:59.000Z

275

Kinetics of the steam reforming of methane with iron, nickel, and iron-nickel alloys as catalysts  

SciTech Connect

The steam reforming of methane on iron or nickel, CH/sub 4/ + H/sub 2/O ..-->.. CO + 3H/sub 2/, can be regarded as a sequence of two reactions with adsorbed carbon as an intermediate species: CH/sub 4/ ..-->.. C(ads) + 2H/sub 2/, C(ads) + H/sub 2/O ..-->.. CO + H/sub 2/. As the first reaction is rate limiting, the following rate law can be applied to methane reforming catalysed by iron: v = k/sub 2//sup Fe/ a/sub 0//sup -n/ p/sub CH/sub 4///P/sub H/sub 2///sup 1/2/, 0.6 less than or equal to n less than or equal to 1.0. The oxygen activity a/sub 0/ on the catalyst surface is virtually determined by the ratio P/sub H/sub 2/O//P/sub H/sub 2// in the gas atmosphere. The above rate equation was confirmed by measurements in a flow apparatus for the temperature range 700 to 900/sup 0/C. In agreement with the reaction model the steady-state carbon activity on the iron surface and the steady-state carbon concentration in the iron catalyst are very low. With nickel as catalyst the reaction rate is much higher and independent of the oxygen activity on the catalyst surface. The rate equation reads: v = k/sub 2//sup Ni/ P/sub CH/sub 4//. Different partial reaction steps of the methane decomposition are rate determining on iron and nickel.

Muenster, P.; Grabke, H.J.

1981-12-01T23:59:59.000Z

276

Nickel electroplating of steam generator tubes (kiss sleeving process)  

SciTech Connect

This process, the nickel electroplating of steam generator tubes, has been jointly developed under a Belgatom (Laborelec) and Framatome agreement with shared experience gained by both companies, industrial applications being under the responsibility of Framatome. Application of the coating in zones where residual stresses or cracks are present prevents contact between the primary water and the tube, which stops the stress corrosion process. In the Doel 2 plant, 91 tubes have been plated since 1985, and different sets of parameters have been used for comparison purposes. Among these tubes, 9 have been preventively plugged because of defective plating, 9 have been pulled out for laboratory examinations, 2 just after plating and 7 after 1 or 2 yr of service. There are 73 plated tubes still in service. From the tests that were performed, it was possible to select an optimized set of parameters guaranteeing the following properties: bridging of existing cracks and good behavior of the coating in relevant zones, good adhesion to the Inconel tube, high ductility, low residual stresses, thermal shock resistance, corrosion resistance, erosion resistance, and low cobalt content. The licensability of this process is being completed. It is based first on the leak-before-break concept to determine the characteristics of the nickel plating, thickness in particular, and second on the inspectability of ultrasonic testing methods.

Michaut, B.

1988-01-01T23:59:59.000Z

277

Method of preparing silicon carbide particles dispersed in an electrolytic bath for composite electroplating of metals  

DOE Patents (OSTI)

A method for preparing silicon carbide particles dispersed in an electrolytic bath for composite electroplating of metals includes the steps of washing the silicon carbide particles with an organic solvent; washing the silicon carbide particles with an inorganic acid; grinding the silicon carbide particles; and heating the silicon carbide particles in a nickel-containing solution at a boiling temperature for a predetermined period of time.

Peng, Yu-Min (Hsinchu, TW); Wang, Jih-Wen (Hsinchu, TW); Liue, Chun-Ying (Tau-Yung, TW); Yeh, Shinn-Horng (Kaohsiung, TW)

1994-01-01T23:59:59.000Z

278

Processing capabilties for the elimination of contaminated metal scrapyards at DOE/ORO-managed sites. [Metal smelting facility  

SciTech Connect

Capabilities exist for reducing all the contaminated nickel, aluminum, and copper scrap to ingot form by smelting. Processing these metals at existing facilities could be completed in about 5 or 6 years. However, these metals represent only about 20% of the total metal inventories currently on hand at the DOE/ORO-managed sites. No provisions have been made for the ferrous scrap. Most of the ferrous scrap is unclassified and does not require secured storage. Also, the potential resale value of the ferrous scrap at about $100 per ton is very low in comparison. Consequently, this scrap has been allowed to accumulate. With several modifications and equipment additions, the induction melter at PGDP could begin processing ferrous scrap after its commitment to nickel and aluminum. The PGDP smelter is a retrofit installation, and annual throughput capabilities are limited. Processing of the existing ferrous scrap inventories would not be completed until the FY 1995-2000 time frame. An alternative proposal has been the installation of induction melters at the other two enrichment facilities. Conceptual design of a generic metal smelting facility is under way. The design study includes capital and operating costs for scrap preparation through ingot storage at an annual throughput of 10,000 tons per year. Facility design includes an induction melter with the capability of melting both ferrous and nonferrous metals. After three years of operation with scrapyard feed, the smelter would have excess capacity to support on-site decontamination and decomissioning projects or upgrading programs. The metal smelting facility has been proposed for FY 1984 line item funding with start-up operations in FY 1986.

Mack, J.E.; Williams, L.C.

1982-01-01T23:59:59.000Z

279

NICKEL SPECIES EMISSION INVENTORY FOR OIL-FIRED BOILERS  

SciTech Connect

Representative duplicate fly ash samples were obtained from the stacks of 400-MW and 385-MW utility boilers (Unit A and Unit B, respectively) using a modified U.S. Environmental Protection Agency (EPA) Method 17 sampling train assembly as they burned .0.9 and 0.3 wt% S residual oils, respectively, during routine power plant operations. Residual oil fly ash (ROFA) samples were analyzed for nickel (Ni) concentrations and speciation using inductively coupled plasma-atomic emission spectroscopy, x-ray absorption fine structure (XAFS) spectroscopy, x-ray diffraction (XRD), and a water-soluble Ni extraction method. ROFA water extraction residues were also analyzed for Ni speciation using XAFS and XRD. Total Ni concentrations in the ROFAs were similar, ranging from 1.3 to 1.5 wt%; however, stack gas Ni concentrations in the Unit A were {approx}990 {micro}g/Nm{sup 3} compared to {approx}620 {micro}g/Nm{sup 3} for Unit B because of the greater residual oil feed rates employed at Unit A to attain higher load (i.e., MW) conditions with a lower heating value oil. Ni speciation analysis results indicate that ROFAs from Unit A contain about 3 wt% NiSO{sub 4} {center_dot} xH{sub 2}O (where x is assumed to be 6 for calculation purposes) and a Ni-containing spinel compound, similar in composition to (Mg,Ni)(Al,Fe){sub 2}O{sub 4}. ROFAs from Unit B contain on average 2.0 wt% NiSO{sub 4} {center_dot} 6H{sub 2}O and 1.1 wt% NiO. XAFS and XRD analyses did not detect any nickel sulfide compounds, including nickel subsulfide (Ni{sub 3}S{sub 2}) (XAFS detection limit is 5% of the total Ni concentration). In addition, XAFS measurements indicated that inorganic sulfate and organic thiophene species account for >97% of the total sulfur in the ROFAs. The presence of NiSO{sub 4} {center_dot} xH{sub 2}O and nickel oxide compound mixtures and lack of carcinogenic Ni{sub 3}S{sub 2} or nickel sulfide compounds (e.g., NiS, NiS{sub 2}) in ROFAs stack-sampled from 400- and 385-MW boilers are contrary to EPA's Ni inhalation cancer risk assessment (''Study of Hazardous Air Pollutant Emissions from Electric Utility Steam Generating Units--Final Report to Congress'', February 1998), where it is assumed that the Ni compound mixture emitted from oil-fired utilities is 50% as carcinogenic as Ni{sub 3}S{sub 2}. Apparently, this assumption greatly overestimates the Ni inhalation cancer risk from oil-fired utilities.

Kevin C. Galbreath; Richard L. Schulz; Donald L. Toman; Carolyn M. Nyberg

2004-01-01T23:59:59.000Z

280

The Dundonald deposit; an example of volcanic-type nickel-sulfide mineralization  

Science Journals Connector (OSTI)

...197I): Archeannickel sulphide depositsin Canada: their classification, geologicalsetting and genesiswith somesugggs-iions as to exploration./n Symposium on Ar-cheanRocks(J.E. Glover, ed.), Geol,Soc,Aust. Spec,Publ. g, 2AL'226...

J. E. Muir; C. D. A. Comba

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

The effects of soil type and chemical treatment on nickel speciation in refinery enriched soils  

E-Print Network (OSTI)

: A multi-technique investigation David H. McNear Jr. a,*, Rufus L. Chaney b , Donald L. Sparks c of 29 km2 of land with Ni concentrations exceeding the Canadian Ministry of the Environment's remedial as a remediation strategy for this area. In this paper we use multiple techniques to directly assess the role soil

282

Metal-based reactive nanomaterials  

Science Journals Connector (OSTI)

Recent developments in materials processing and characterization resulted in the discovery of a new type of reactive materials containing nanoscaled metal components. The well-known high oxidation energies of metallic fuels can now be released very rapidly because of the very high reactive interface areas in such metal-based reactive nanomaterials. Consequently, these materials are currently being examined for an entire range of applications in energetic formulations inappropriate for conventional, micron-sized metal fuels having relatively low reaction rates. New application areas, such as reactive structural materials, are also being explored. Research remains active in manufacturing and characterization of metal-based reactive nanomaterials including elemental metal nanopowders and various nanocomposite material systems. Because of the nanometer scale of the individual particles, or phase domains, and because of the very high enthalpy of reaction between components of the nanocomposite materials, the final phase compositions, morphology, and thermodynamic properties of the reactive nanocomposite materials may be different from those of their micron-scaled counterparts. Ignition mechanisms in such materials can be governed by heterogeneous reactions that are insignificant for materials with less developed reactive interface areas. New combustion regimes are being observed that are affected by very short ignition delays combined with very high metal combustion temperatures. Current progress in this rapidly growing research area is reviewed and some potential directions for the future research are discussed.

Edward L. Dreizin

2009-01-01T23:59:59.000Z

283

Method of Determining the Extent to which a Nickel Structure has been Attached by a Fluorine-Containing Gas  

DOE Patents (OSTI)

The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

Brusie, James P.

2004-07-13T23:59:59.000Z

284

Development of nickel silicide for integrated circuit technology.  

E-Print Network (OSTI)

?? Continuous advancements in devices, materials and processes have resulted in integrated circuits with smaller device dimensions, higher functionality and higher speed. The complementary metal… (more)

Do, Phu H.

2006-01-01T23:59:59.000Z

285

3-D Metals | Open Energy Information  

Open Energy Info (EERE)

Metals Metals Jump to: navigation, search Name 3-D Metals Facility 3-D Metals Sector Wind energy Facility Type Small Scale Wind Facility Status In Service Location Valley City OH Coordinates 41.2481362Ā°, -81.88305616Ā° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.2481362,"lon":-81.88305616,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

286

CO hydrogenation and adsorption studies on supported nickel SMSI catalysts. Technical report no. 42, 1 January-31 December 1985  

SciTech Connect

The uptake of CO by Ni/TiO2 and Ni/Ti/sub 2/O/sub 3/ was investigated at 25 and 125 C following low-temperature (LT = 250 C) and high-temperature (HT = 450 C) reduction. Infrared spectroscopy was used to identify the onset of nickel carbonyl (Ni(CO)/sub 4/) formation under various conditions of temperature and pressure. The CO uptake data were modeled using the Langmuir equation for isothermal adsorption. Monolayer coverages and equilibrium constants for CO adsorption were obtained from the uptake data. Carbon monoxide monolayer coverages were not affected by the reduction temperature of either Ni/TiO/sub 2/ or Ni/Ti/sub 2/O/sub 3/. Methanation activity at 275C was approximately a factor of 2 greater for the Ni/TiO/sub 2/ (LT) than the NiTiO/sub 2/ (HT) catalyst. This correlated well with the relative strength of the CO-metal surface bond, which also decreased by a factor of approximately 2. These findings suggest that the enhanced methanation rate observed on TiO/sub 2/ supported catalysts is not due to the presence or absence of a strong metal-support interaction condition of the TiO/sub 2/ but to other properties of TiO/sub 2/ as compared to other supports.

Fang, S.M.; White, J.M.; Campione, T.J.; Ekerdt, J.G.

1985-01-01T23:59:59.000Z

287

Microstructural characteristics of the built up layer of a precipitation hardened nickel based superalloy by electrospark deposition  

Science Journals Connector (OSTI)

Abstract Buildup of precipitation hardened nickel base superalloys by electro spark deposition due to the low heat input of the process has many attractions. Characterization of the microstructure of the ESD built up layer of IN738LC over an as-cast base metal is accomplished in this work. The grain structure and solidification texture of the coating are investigated by orientation imaging microscopy (OIM), optical and scanning electron microscopy. It is shown that the deposited layer is formed mainly through epitaxial nucleation and growth on the base metal structure while discontinuities acting as nucleation sites produce fine grains with independent orientations. It is shown that such independent grains can have a significant role in improving the integrity of the ESD built up layer, since they can act as crack arrest sites and make the coating more resistant to the propagation of liquation and solidification fissures. Moreover, it is found that nanosized ?? precipitates exist in the coating indicating the high tendency of ?? for precipitation even in the extremely high cooling rates involved in the ESD process. Hardness measurements indicated a higher hardness for the built up layer which is attributable to the finer microstructure of the coating.

M. Ebrahimnia; F. Malek Ghaini; Y.J. Xie; H. Shahverdi

2014-01-01T23:59:59.000Z

288

The magnetic properties of the iron-rich, iron-nickel-zinc alloys  

E-Print Network (OSTI)

this density. The samples were again sealed in steel jackets with a 12 small amount of zinc to maintain the vapor pressure high enough to al- low the impregnated zinc to remain in the samples. The jacketed speci- 0 mens were heated to 1000 C for two hours.... This curve indicated that the coercive force is strongly affected by the zinc content of the al- loy. Fig, 12 is a plot of hardness against nickel content. The 10 w/o Zn al'loys gave the greatest hardness with low nickel content. As the nickel content...

Gupton, Paul Stephen

1961-01-01T23:59:59.000Z

289

Sulfur poisoning of H/sub 2/ and CO adsorption on supported nickel  

SciTech Connect

Effects of H/sub 2/S on adsorption of H/sub 2/ and CO on unsupported nickel are: H/sub 2/ adsorption at 298/sup 0/K and CO adsorption at 190/sup 0/K were lowered by presulfiding; and irreversible CO adsorption at 298/sup 0/K was decreased, whereas reversible adsorption was increased after presulfiding, the stoichiometry in the latter case suggesting the formation of Ni(CO)/sub 4/. Recent studies indicate a similar, but even more complex behavior in the case of supported nickel. These effects of sulfur poisoning on H/sub 2/ and CO adsorption on supported nickel are described and discussed.

Bartholomew, C.H.; Pannell, R.B.

1980-03-01T23:59:59.000Z

290

Fuel electrode containing pre-sintered nickel/zirconia for a solid oxide fuel cell  

DOE Patents (OSTI)

A fuel cell structure (2) is provided, having a pre-sintered nickel-zirconia fuel electrode (6) and an air electrode (4), with a ceramic electrolyte (5) disposed between the electrodes, where the pre-sintered fuel electrode (6) contains particles selected from the group consisting of nickel oxide, cobalt and cerium dioxide particles and mixtures thereof, and titanium dioxide particles, within a matrix of yttria-stabilized zirconia and spaced-apart filamentary nickel strings having a chain structure, and where the fuel electrode can be sintered to provide an active solid oxide fuel cell.

Ruka, Roswell J. (Pittsburgh, PA); Vora, Shailesh D. (Monroeville, PA)

2001-01-01T23:59:59.000Z

291

Nickel Ferrite Aerogels with Monodisperse Nanoscale Building Blocks—The Importance of Processing Temperature and Atmosphere  

Science Journals Connector (OSTI)

Nickel Ferrite Aerogels with Monodisperse Nanoscale Building Blocks—The Importance of Processing Temperature and Atmosphere ... Using two-step (air/argon) thermal processing, sol?gel-derived nickel?iron oxide aerogels are transformed into monodisperse, networked nanocrystalline magnetic oxides of NiFe2O4 with particle diameters that can be ripened with increasing temperature under argon to 4.6, 6.4, and 8.8 nm. ... nickel ferrites; magnetic nanomaterials; nanoarchitectures; aerogels; sol?gel chemistry; single magnetic domains; thermal processing ...

Katherine A. Pettigrew; Jeffrey W. Long; Everett E. Carpenter; Colin C. Baker; Justin C. Lytle; Christopher N. Chervin; Michael S. Logan; Rhonda M. Stroud; Debra R. Rolison

2008-04-22T23:59:59.000Z

292

Mechanochemical processing for metals and metal alloys  

DOE Patents (OSTI)

A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Prisbrey, Keith (Moscow, ID)

2001-01-01T23:59:59.000Z

293

Micrographic detection of plastic deformation in nickel base alloys  

DOE Patents (OSTI)

A method for detecting low levels of plastic deformation in metal articles comprising electrolytically etching a flow free surface of the metal article with nital at a current density of less than about 0.1 amp/cm.sup.2 and microscopically examining the etched surface to determine the presence of alternating striations. The presence of striations indicates plastic deformation in the article.

Steeves, Arthur F. (Schenectady, NY); Bibb, Albert E. (Clifton Park, NY)

1984-01-01T23:59:59.000Z

294

Complexes of niobium and tantalum containing metal-metal bonds  

SciTech Connect

A new entry into the area of low valent niobium and tantalum complexes containing metal-metal bonds is described. M/sub 2/X/sub 6/ (..mu..-THT)(THF)/sub 2/ complexes, where M = Nb or Ta, X = Cl or Br and THT - tetrahydrothiophene, are conveniently synthesized via the reaction of M/sub 2/M/sub 6/(THT)/sub 3/ with THF (THF = tetrahydrofuran). Unlike M/sub 2/X/sub 6/(THT)/sub 3/, M/sub 2/X/sub 6/(..mu..-THT)(THF)/sub 2/ can be easily reduced by sodium amalgam. In THF and in the presence of THT, complexes of the type M/sub 2/X/sub 6/(..mu..-THT)/sub 3//sup 2 -/ form. Salts of these compounds can also be synthesized directly from the metal pentahalides in a two step, one pot reaction in which M/sub 2/X/sub 6/(THT)/sub 3/ is an intermediate. The M/sub 2/X/sub 6/(..mu..-THT)/sub 3//sup 2 -/ complexes have a face-sharing bioctahedral structure with metal-metal triple bonds, the first reported for niobium or tantalum. These compounds are relatively inert, but (Nb/sub 2/Cl/sub 6/(..mu..-THT)/sub 3//sup 2 -/ does reach with pyridine and with a solution of acetic acid/acetic anhydride. These reactions and those of some of the sodium salts are described. In general, trinuclear complexes of niobium and tantalum are rare, and this type of discrete trinuclear complex, which contains one capping, three bridging and nine terminal ligands, has been seen only once before for the group 5 metals, although many examples of similar group 6 metal complexes are known. Full details of the synthesis and characterization of these complexes are described and an interpretation of their electronic structures is given.

Diebold, M.P.

1987-01-01T23:59:59.000Z

295

Carbon and carbon monoxide hydrogenation on nickel: support effects  

SciTech Connect

Hydrogenation of carbon, deposited on nickel catalysts by CO disproportionation, was investigated by temperature-programmed surface reaction (TPSR) for four oxide supports, alumina (Al/sub 2/O/sub 3/), silica (SiO/sub 2/), titanium oxide (TiO/sub 2/), and SiO/sub 2/.Al/sub 2/O/sub 3/. The rate of carbon monoxide hydrogenation was measured by temperature-programmed reaction (TPR) for comparison. The rate of carbon hydrogenation to methane was found to be independent of the support and an average activation energy of 42 kJ/mol was estimated. In contrast, the rate of carbon monoxide hydrogenation was very sensitive to the catalyst support. Nickel (Ni) supported on TiO/sub 2/ exhibited the highest specific activity, and two distinct sites for methanation were observed on Ni/TiO/sub 2/ and Ni/Al/sub 2/O/sub 3/. The lowest specific activities were observed for Ni/SiO/sub 2/ and Ni/SiO/sub 2/.Al/sub 2/O/sub 3/. For all catalysts, carbon hydrogenation occurred at a lower temperature than carbon monoxide hydrogenation. For both TPR and TPSR, small amounts of ethane were formed and at a lower temperature than methane. The amount of less-active, ..beta..-carbon observed in TPSR experiments was very small on all catalysts. These results indicate that at high coverages, carbon hydrogenation does not depend on the support, and thus it is not rate-determining for CO hydrogenation in excess hydrogen. The support is also shown to change the specific rate of carbon monoxide methanation; activity differences seen in steady-state experiments are not just due to differences in site densities. 5 figures, 5 tables.

Ozdogan, S.Z.; Gochis, P.D.; Falconer, J.L.

1983-10-01T23:59:59.000Z

296

Studies of mechanisms and kinetics of methane and ethane steam reforming on nickel catalysts  

SciTech Connect

Methane and ethane adsorption/desorption and reaction on steam-reforming catalysts, Ni(INCO), Ni/ZrO{sub 2}, and Ni/CaAl{sub 2}O{sub 4}, were studied by temperature-programmed desorption (TPD), temperature-programmed surface reaction (TPSR), and thermogravimetric (TGA) techniques. The data show that only a fraction of the methane adsorbed (determined by TPSR with H{sub 2}) on nickel catalysts is desorbed during TPD experiments. The results of TPD indicate supports and promoters affect the adsorption of methane and ethane, and transformation of adsorbed carbon species. Several carbon types formed during methane and ethane adsorptions including {alpha}, {beta}, {gamma}, vermicular (v), and graphitic (c) carbon can be identified by TPSR. These data indicate that the distribution of these carbon forms is also strongly a function of adsorption temperature and catalyst. The results show that there are significant quantities of CH{sub 4}, CO, and CO{sub 2} desorbed during TPSR reaction of H{sub 2}O with preadsorbed CH{sub 4}, CD{sub 4} and C{sub 2}H{sub 6}. The agreement between previously reported steady-state and the unsteady-state steam reforming reforming rates of this study indicates that the steam-reforming kinetic data can be quantitatively measured by TPSR experiments.

Hsieh, H.Y.

1988-01-01T23:59:59.000Z

297

Oxygen addition to sulfur of metal thiolates  

E-Print Network (OSTI)

, and characterized. Molecular oxygen or hydrogen peroxide reacted with (N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane-nickel(II), (BME-DACO)2Ni3 +2, to produce a trimetallic, (N,N'-bismercaptoethyl-1,5-diazacyclooctane-nickel(II))-nickelate, (BME-DACO)2Ni3 2...

Soma, Takako

2012-06-07T23:59:59.000Z

298

Rovibronically selected and resolved two-color laser photoionization and photoelectron study of nickel carbide cation  

SciTech Connect

We have performed a two-color laser photoionization and photoelectron study of nickel carbide (NiC) and its cation (NiC{sup +}). By preparing NiC in a single rovibronic level of an intermediate vibronic state via visible laser excitation prior to ultraviolet laser photoionization, we have measured the photoionization efficiency spectrum of NiC near its ionization threshold, covering the formation of NiC{sup +}(X {sup 2}{Sigma}{sup +};v{sup +}=0-3). We have also obtained well-resolved rotational transitions for the v{sup +}=0 and 1 vibrational bands of the NiC{sup +}(X {sup 2}{Sigma}{sup +}) ground state. The assignment of rotational transitions observed between the neutral NiC intermediate state and the NiC{sup +} ion ground state has allowed the direct determination of a highly precise value for the ionization energy of NiC, IE(NiC)=67 525.1{+-}0.5 cm{sup -1} (8.372 05{+-}0.000 06 eV). This experiment also provides reliable values for the vibrational spacing [{Delta}G(1/2)=859.5{+-}0.5 cm{sup -1}], rotational constants (B{sub e}{sup +}=0.6395{+-}0.0018 cm{sup -1} and {alpha}{sub e}{sup +}=0.0097{+-}0.0009 cm{sup -1}), and equilibrium bond distance (r{sub e}{sup +}=1.628 A) for the NiC{sup +}(X {sup 2}{Sigma}{sup +}) ground state. The experimental results presented here are valuable for benchmarking the development of more reliable ab initio quantum computation procedures for energetic and spectroscopic calculations of transition metal-containing molecules.

Chang, Yih Chung [Department of Chemistry, University of California, Davis, Davis, California 95616 (United States); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 106, Taiwan (China); Shi Xiaoyu; Ng, C. Y. [Department of Chemistry, University of California, Davis, Davis, California 95616 (United States); Lau, Kai-Chung [Department of Biology and Chemistry, City University of Hong Kong, Kowloon (Hong Kong); Yin Qingzhu [Department of Geology, University of California, Davis, Davis, California 95616 (United States); Liou, H. T. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 106, Taiwan (China)

2010-08-07T23:59:59.000Z

299

Nickel (II)-induced cytotoxicity and apoptosis in human proximal tubule cells through a ROS- and mitochondria-mediated pathway  

SciTech Connect

Nickel compounds are known to be toxic and carcinogenic in kidney and lung. In this present study, we investigated the roles of reactive oxygen species (ROS) and mitochondria in nickel (II) acetate-induced cytotoxicity and apoptosis in the HK-2 human renal cell line. The results showed that the cytotoxic effects of nickel (II) involved significant cell death and DNA damage. Nickel (II) increased the generation of ROS and induced a noticeable reduction of mitochondrial membrane potential (MMP). Analysis of the sub-G1 phase showed a significant increase in apoptosis in HK-2 cells after nickel (II) treatment. Pretreatment with N-acetylcysteine (NAC) not only inhibited nickel (II)-induced cell death and DNA damage, but also significantly prevented nickel (II)-induced loss of MMP and apoptosis. Cell apoptosis triggered by nickel (II) was characterized by the reduced protein expression of Bcl-2 and Bcl-xL and the induced the protein expression of Bad, Bcl-Xs, Bax, cytochrome c and caspases 9, 3 and 6. The regulation of the expression of Bcl-2-family proteins, the release of cytochrome c and the activation of caspases 9, 3 and 6 were inhibited in the presence of NAC. These results suggest that nickel (II) induces cytotoxicity and apoptosis in HK-2 cells via ROS generation and that the mitochondria-mediated apoptotic signaling pathway may be involved in the positive regulation of nickel (II)-induced renal cytotoxicity.

Wang, Yi-Fen; Shyu, Huey-Wen [Department of Medical Laboratory Sciences and Biotechnology, Fooyin University, Kaohsiung, Taiwan (China)] [Department of Medical Laboratory Sciences and Biotechnology, Fooyin University, Kaohsiung, Taiwan (China); Chang, Yi-Chuang [Department of Nursing, Fooyin University, Kaohsiung, Taiwan (China)] [Department of Nursing, Fooyin University, Kaohsiung, Taiwan (China); Tseng, Wei-Chang [Department of Medical Laboratory Sciences and Biotechnology, Fooyin University, Kaohsiung, Taiwan (China)] [Department of Medical Laboratory Sciences and Biotechnology, Fooyin University, Kaohsiung, Taiwan (China); Huang, Yeou-Lih [Department of Medical Laboratory Science and Biotechnology, Kaohsiung Medical University, Kaohsiung, Taiwan (China)] [Department of Medical Laboratory Science and Biotechnology, Kaohsiung Medical University, Kaohsiung, Taiwan (China); Lin, Kuan-Hua; Chou, Miao-Chen; Liu, Heng-Ling [Department of Medical Laboratory Sciences and Biotechnology, Fooyin University, Kaohsiung, Taiwan (China)] [Department of Medical Laboratory Sciences and Biotechnology, Fooyin University, Kaohsiung, Taiwan (China); Chen, Chang-Yu, E-mail: mt037@mail.fy.edu.tw [Department of Medical Laboratory Sciences and Biotechnology, Fooyin University, Kaohsiung, Taiwan (China)] [Department of Medical Laboratory Sciences and Biotechnology, Fooyin University, Kaohsiung, Taiwan (China)

2012-03-01T23:59:59.000Z

300

Reinforced nickel catalysts for steam reforming of methane to synthesis gas  

Science Journals Connector (OSTI)

XRD, mercury porosimetry, low-temperature nitrogen adsorption and electron microscopy were used to study peculiarities of the formation of reinforced composite nickel catalysts. The catalysts were prepared by sin...

Zaliya A. Sabirova; Marianna M. Danilova…

2009-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Steam Reforming of Methane Over Nickel: Development of a Multi-Step Surface Reaction Mechanism  

Science Journals Connector (OSTI)

A detailed multi-step reaction mechanism is developed for modeling steam reforming of methane over nickel-based catalysts. The mechanism also ... tested by simulating experimental investigations of SR of methane ...

L. Maier; B. Schädel; K. Herrera Delgado; S. Tischer; O. Deutschmann

2011-09-01T23:59:59.000Z

302

Fabrication and tribological properties of superhydrophobic nickel films with positive and negative biomimetic microtextures  

Science Journals Connector (OSTI)

Nickel (Ni) films with positive and negative textured surfaces of lotus and rice leaf patterns were fabricated through an inexpensive and effective method. The as-prepared Ni films were superhydrophobic and ex...

Ying Wang; Jing Yang; Xiaobao Guo; Qiang Zhang; Jingyu Wang; Jianning Ding…

2014-09-01T23:59:59.000Z

303

Dispersion and Characterization of Nickel Nanostrands in Thermoset and Thermoplastic Polymers  

E-Print Network (OSTI)

Nickel Nanostrands (NiNS) are nano-particles that are highly branched and have a high aspect ratio. These particles show promise as excellent additives to composites when electrical conductivity is desired. Unfortunately, there is very little...

Whalen, Casey Allen

2012-02-14T23:59:59.000Z

304

Partage du nickel entre serpentine et brucite au cours de la serpentinisation du péridot  

Science Journals Connector (OSTI)

When nickeliferous peridot is submitted to a serpentinisation reaction with formation of brucite, the peridotic nickel is partitioned between the two minerals (serpentine and brucite) with a distribution coeffici...

Alain Perruchot

305

Nickel-catalyzed preparation of acrylamides from alpha olefins and isocyanates ; Synthetic studies toward ripostatin A  

E-Print Network (OSTI)

Chapter I. In the presence of the N-heterocyclic carbene ligand IPr, the nickel(0)-catalyzed coupling reaction of a-olefins and branched aliphatic isocyanates provides c,-unsaturated amides arising from preferential C-C ...

Schleicher, Kristin D. (Kristin Diann)

2010-01-01T23:59:59.000Z

306

Magnetism in Transition Metals  

Science Journals Connector (OSTI)

An attempt is made to distinguish "band-type magnetization" from "alignment-type magnetization" on the basis of whether the local moments associated with the Wannier functions on the atom sites are "induced" or "permanent." In general, the local moment is partially induced and partially permanent, and a criterion is suggested: A local moment is defined to be of the permanent variety if in the presence of magnetic forces (supposed characteristic of the crystal in a given circumstance) tending to produce a moment in one sense (z^, say) of a direction, it can maintain itself (perhaps altered in magnitude, however) in the opposite sense (-z^), as well as in z^. The internal mechanisms tending to produce permanent moments are simplified to just the Hcorr of Anderson, and the external inducing mechanism are the Heisenberg interaction and a magnetic field, Hspin, say. If Hcorr dominates Hspin, then it is shown that a local moment can maintain itself to the polarizing tendencies (whence an alignment type of magnetization calculation is appropriate), but if Hspin dominates Hcorr, then the local moment has only one sense possible in this environment (and a band type of calculation is appropriate). It is suggested that this distinction is relevant to transition metals.

M. Bailyn

1965-09-13T23:59:59.000Z

307

Metallic Power Inc | Open Energy Information  

Open Energy Info (EERE)

Metallic Power Inc Metallic Power Inc Jump to: navigation, search Name Metallic Power Inc Place Carlsbad, California Zip CA 92009- Product Metallic Power, which closed down in September 2004, was focused on remote and distributed power solutions based on zinc-air fuel cell technology. Coordinates 31.60396Ā°, -100.641609Ā° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":31.60396,"lon":-100.641609,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

308

Type Fusion  

Science Journals Connector (OSTI)

Fusion is an indispensable tool in the arsenal ... Less well-known, but equally valuable is type fusion, which states conditions for fusing an application ... algebra. We provide a novel proof of type fusion base...

Ralf Hinze

2011-01-01T23:59:59.000Z

309

Electronic Structure of Noble-Metal-Noble-Metal Alloys  

Science Journals Connector (OSTI)

We describe optical studies of dilute noble-metal-noble-metal alloys. A differential technique compared the reflectance of the alloy with the reflectance of the pure metal and measured a quantity proportional to just the difference in reflectance. The method was particularly sensitive to small changes in reflectances and could be used to study very dilute alloys-the alloys here were between 110- and 3-at.% impurity concentration. The measurements indicated that the noble alloys are of two types. In copper-gold and silver-gold alloys the electron energy bands shift smoothly as the concentration varies. The rates and directions of shifts are determined not only by differences in the host and impurity potentials, but also by the changes in lattice constant, and we emphasize the importance of the latter. In contrast, in copper-silver alloys separate host and impurity d bands are formed.

David Beaglehole and Erich Erlbach

1972-08-15T23:59:59.000Z

310

Type B Accident Investigation Board Report, May 8, 2004, Exothermic...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Report, May 8, 2004, Exothermic Metal Reactor Event During Sodium Transfer Activities, East Tennessee Technology Park, Oak Ridge, Tennessee Type B Accident Investigation Board...

311

Three D Metals Wind Turbine | Open Energy Information  

Open Energy Info (EERE)

Three D Metals Wind Turbine Three D Metals Wind Turbine Jump to: navigation, search Name Three D Metals Wind Turbine Facility Three D Metals Wind Turbine Sector Wind energy Facility Type Small Scale Wind Facility Status In Service Owner Three D Metals Energy Purchaser Three D Metals Location Valley City OH Coordinates 41.248155Ā°, -81.883079Ā° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.248155,"lon":-81.883079,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

312

Metal-phosphate binders  

DOE Patents (OSTI)

A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

2009-05-12T23:59:59.000Z

313

3D Imaging of Nickel Oxidation States using Full Field X-ray Absorption Near Edge Structure Nanotomography  

SciTech Connect

Reduction-oxidation (redox) cycling of the nickel electrocatalyst phase in the solid oxide fuel cell (SOFC) anode can lead to performance degradation and cell failure. A greater understanding of nickel redox mechanisms at the microstructural level is vital to future SOFC development. Transmission x-ray microscopy (TXM) provides several key techniques for exploring oxidation states within SOFC electrode microstructure. Specifically, x-ray nanotomography and x-ray absorption near edge structure (XANES) spectroscopy have been applied to study samples of varying nickel (Ni) and nickel oxide (NiO) compositions. The imaged samples are treated as mock SOFC anodes containing distinct regions of the materials in question. XANES spectra presented for the individual materials provide a basis for the further processing and analysis of mixed samples. Images of composite samples obtained are segmented, and the distinct nickel and nickel oxide phases are uniquely identified using full field XANES spectroscopy. Applications to SOFC analysis are discussed.

Nelson, George; Harris, William; Izzo, John; Grew, Kyle N. (Connecticut); (USARL)

2012-01-20T23:59:59.000Z

314

Metal Hydrides - Science Needs  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Storage Grand Challenge Pre-Solicitation Meeting, June 19, 2003 1 Metal Hydrides - Science Needs TRADITIONAL METALLIC HYDRIDES: 1.5 to 2 wt.% H. Well studied. COMPLEX...

315

Probing metal solidification nondestructively  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting and...

316

Probing metal solidification nondestructively  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting...

317

Neutron imaging of alkali metal heat pipes  

SciTech Connect

High-temperature heat pipes are two-phase, capillary driven heat transfer devices capable of passively providing high thermal fluxes. Such a device using a liquid-metal coolant can be used as a solution for successful thermal management on hypersonic flight vehicles. Imaging of the liquid-metal coolant inside will provide valuable information in characterizing the detailed heat and mass transport. Neutron imaging possesses an inherent advantage from the fact that neutrons penetrate the heat pipe metal walls with very little attenuation, but are significantly attenuated by the liquid metal contained inside. Using the BT-2 beam line at the National Institute of Standards and Technology (NIST) in Gaithersburg, Maryland, preliminary efforts have been conducted on a nickel-sodium heat pipe. The contrast between the attenuated beam and the background is calculated to be approximately 3%. This low contrast requires sacrifice in spatial or temporal resolution so efforts have since been concentrated on lithium (Li) which has a substantially larger neutron attenuation cross section. Using the CG-1D beam line at the High Flux Isotope Reactor (HFIR) of Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee, the first neutron images of high-temperature molybdenum (Mo)-Li heat pipes have been achieved. The relatively high neutron cross section of Li allows for the visualization of the Li working fluid inside the heat pipes. The evaporator region of a gravity assisted cylindrical heat pipe prototype 25 cm long was imaged from start-up to steady state operation up to approximately 900 C. In each corner of the square bore inside, the capillary action raises the Li meniscus above the bulk Li pool in the evaporator region. As the operational temperature changes, the meniscus shapes and the bulk meniscus height also changes. Furthermore, a three-dimensional tomographic image is also reconstructed from the total of 128 projection images taken 1.4o apart in which the Li had already cooled and solidified.

Kihm, Ken [University of Tennessee, Knoxville (UTK); Kirchoff, Eric [University of Tennessee, Knoxville (UTK); Golden, Matt [University of Tennessee, Knoxville (UTK); Rosenfeld, J. [Thermacore Inc.; Rawal, S. [Lockheed Martin Space Systems Company; Pratt, D. [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Bilheux, Hassina Z [ORNL; Walker, Lakeisha MH [ORNL; Voisin, Sophie [ORNL; Hussey, Dan [NIST Center for Neutron Research (NCRN), Gaithersburg, MD

2013-01-01T23:59:59.000Z

318

Effects of residues from municipal solid waste landfill on corn yield and heavy metal content  

SciTech Connect

The effects of residues from municipal solid waste landfill, Khon Kaen Municipality, Thailand, on corn (Zea mays L.) yield and heavy metal content were studied. Field experiments with randomized complete block design with five treatments (0, 20, 40, 60 and 80% v/v of residues and soil) and four replications were carried out. Corn yield and heavy metal contents in corn grain were analyzed. Corn yield increased by 50, 72, 85 and 71% at 20, 40, 60 and 80% treatments as compared to the control, respectively. All heavy metals content, except cadmium, nickel and zinc, in corn grain were not significantly different from the control. Arsenic, cadmium and zinc in corn grain were strongly positively correlated with concentrations in soil. The heavy metal content in corn grain was within regulated limits for human consumption.

Prabpai, S. [Suphan Buri Campus Establishment Project, Kasetsart University, 50 U Floor, Administrative Building, Paholyothin Road, Jatujak, Bangkok 10900 (Thailand)], E-mail: s.prabpai@hotmail.com; Charerntanyarak, L. [Department of Epidemiology, Faculty of Public Health, Khon Kaen University, Khon Kaen 40002 (Thailand)], E-mail: lertchai@kku.ac.th; Siri, B. [Department of Agronomy, Faculty of Agriculture, Khon Kaen University, Khon Kaen 40002 (Thailand)], E-mail: boonmee@kku.ac.th; Moore, M.R. [The University of Queensland, The National Research Center for Environmental Toxicology, 39 Kessels Road, Coopers Plans, Brisbane, Queensland 4108 (Australia)], E-mail: m.moore@uq.edu.au; Noller, Barry N. [The University of Queensland, Centre for Mined Land Rehabilitation, Brisbane, Queensland 4072 (Australia)], E-mail: b.noller@uq.edu.au

2009-08-15T23:59:59.000Z

319

INVESTIGATION IN HARDSURFACING A NICKEL-COPPER ALLOY (MONEL400).  

SciTech Connect

Brookhaven National Laboratory (BNL) investigated the causes of weldability problems and materials failures encountered with the application of Monel (Ni-Cu) 400 as a base material and Stellite 6 (Co-Cr) as the hard-surfacing material when using the oxyacetylene welding process. This work was performed under a cooperative research and development agreement (CRADA) with the Target Rock Division of the Curtiss-Wright Flow Control Corporation. BNL evaluated two heats of Monel 400 material. One of the heats had performed well during manufacturing, producing an acceptable number of ''good'' parts. The second heat had produced some good parts but also exhibited a peculiar type of hardsurfacing/base metal collapse during the welding process. A review of the chemistry on the two heats of material indicated that they both met the chemical requirements for Monel400. During examination of the failed component, linear indications (cracks) were evident on the valve body, both on the circumferential area (top of valve body) and below the hard surfaced weld deposit. independent measurements also indicated that the two heats met the specification requirement for the material. The heat affected zone (HAZ) also contained linear discontinuities. The valve body was welded using the oxyacetylene welding process, a qualified and skilled welder, and had been given a pre-heat of between 1400-1600 F (760-871 C), which is the Target Rock qualified procedure requirement. Both original suppliers performed mechanical testing on their material that indicated the two heats also met the mechanical property requirements of the specification. The BNL investigation into the cause of the differences between these heats of material utilized the following techniques: (1) Heat Treatment of both heats of material; (2) Hardness testing; (3) Optical microscopy; (4) Scanning electron microscope (SEM)/Fractography; and (5) Energy dispersive spectroscopy (EDS). The report concludes that the cause of the failure of the valve body during welding is not obvious, however, it does not appear to be a welding issue. The observed inter-granular fractures indicate a grain boundary problem. Further research is recommended.

CZAJKOWSKI,C.; BUTTERS,M.

2001-12-01T23:59:59.000Z

320

Trace metals in gills of fish from the Arabian Gulf  

SciTech Connect

Complexation of metals by coordinate linkages with appropriate organic molecules in biological tissues is an important process involved in metal accumulation by aquatic organisms. Fish respiratory systems differ from all other systems because damage to gills has immediate impacts on the rest of the fish's body. Veer et al. observed significant correlation between gill-metal concentration and whole-body weight. More nickel is accumulated in gill tissue of the catfish (Clarias batrachus) than in the liver or intestine. More cadmium is accumulated in gill tissue of the fish Heteropneustes fossilis (Bloch) and Channa punctatus (Bloch) than in the liver or kidney. When exposed to lethal and sublethal concentrations of copper, gills of the freshwater fish Labeo rohita (Hamilton) showed the highest degree of copper accumulation. Petroleum and petrochemical industry wastes contribute significantly to metal enrichment of the Arabian Gulf marine environment. Because accumulation of metal ions is significant in gills, levels of Cd, Cr, Cu, Ni and Pb were investigated in gills of fish from potentially impacted areas along the western side of the Arabian Gulf after the 1991 oil-spill. 15 refs., 3 figs., 1 tab.

Al-Yakoob, S.; Bahloul, M. (Kuwait Institute for Scientific Research, Safat (Kuwait)); Bou-Olayan, A.H.

1994-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

322

Study of electrodeposited nickel-molybdenum, nickel-tungsten, cobalt-molybdenum, and cobalt-tungsten as hydrogen electrodes in alkaline water electrolysis  

SciTech Connect

Electrodeposited nickel-molybdenum, nickel-tungsten, cobalt-molybdenum, and cobalt-tungsten were characterized for the hydrogen evolution reaction (HER) in the electrolysis of 30 w/o KOH alkaline water at 25 C. The rate-determining step (rds) of the HER was suggested based on the Tafel slope of polarization and the capacitance of electrode-solution interface determined by ac impedance measurement. The HER on the nickel- and cobalt-based codeposits was enhanced significantly compared with that o the electrolytic nickel and cobalt with comparable deposit loadings. The decrease in the HER overpotential was more pronounced on the molybdenum-containing codeposits, particularly on cobalt-molybdenum which also showed a high stability. The enhancement of the HER was attributed to both the synergetic composition and the increased active surface of the codeposits. The real electrocatalytic activity of te electrodes and the effect of their and the increased active surface of the codeposits. The real electrocatalytic activity of the electrodes and the effect of their surface increase were distinguished quantitatively. The linear relations between HER overpotential and surface roughness factor of the electrodes on a Y-log(X) plot were obtained experimentally and interpreted based on the Tafel law.

Fan, C.; Piron, D.L.; Sleb, A.; Paradis, P. (Ecole Polytechnique de Montreal, Quebec (Canada). Dept. de Metallurgie et de Genie des Materiaux)

1994-02-01T23:59:59.000Z

323

Hydrogen-induced cracking along the fusion boundary of dissimilar metal welds  

SciTech Connect

Presented here are the results from a series of experiments in which dissimilar metals welds were made using the gas tungsten arc welding process with pure argon or argon-6% hydrogen shielding gas. The objective was to determine if cracking near the fusion boundary of dissimilar metal welds could be caused by hydrogen absorbed during welding and to characterize the microstructures in which cracking occurred. Welds consisted of ER308 and ER309LSi austenitic stainless steel and ERNiCr-3-nickel-based filler metals deposited on A36 steel base metal. Cracking was observed in welds made with all three filler metals. A ferrofluid color metallography technique revealed that cracking was confined to regions in the weld metal containing martensite. Microhardness indentations indicated that martensitic regions in which cracking occurred had hardness values from 400 to 550 HV. Cracks did not extend into bulk weld metal with hardness less than 350 HV. Martensite formed near the fusion boundary in all three filler metals due to regions of locally increased base metal dilution.

Rowe, M.D.; Nelson, T.W.; Lippold, J.C. [Ohio State Univ., Columbus, OH (United States)

1999-02-01T23:59:59.000Z

324

Platinum-Coated Nickel Nanowires as Oxygen-Reducing Electrocatalysts  

SciTech Connect

Platinum (Pt)-coated nickel (Ni) nanowires (PtNiNWs) are synthesized by the partial spontaneous galvanic displacement of NiNWs, with a diameter of 150 250 nm and a length of 100 200 m. PtNiNWs are electrochemically characterized for oxygen reduction (ORR) in rotating disk electrode half-cells with an acidic electrolyte and compared to carbon-supported Pt (Pt/HSC) and a polycrystalline Pt electrode. Like other extended surface catalysts, the nanowire morphology yields significant gains in ORR specific activity compared to Pt/HSC. Unlike other extended surface approaches, the resultant materials have yielded exceptionally high surface areas, greater than 90 m2 gPt 1. These studies have found that reducing the level of Pt displacement increases Pt surface area and ORR mass activity. PtNiNWs produce a peak mass activity of 917 mA mgPt 1, 3.0 times greater than Pt/HSC and 2.1 times greater than the U.S. Department of Energy target for proton-exchange membrane fuel cell activity.

Alia, Shaun M [National Renewable Energy Laboratory (NREL); Larsen, Brian A [National Renewable Energy Laboratory (NREL); Pylypenko, Svitlana [ORNL; Cullen, David A [ORNL; Diercks, David R [Colorado School of Mines, Golden; Neyerlin, Kenneth C [National Renewable Energy Laboratory (NREL); Kocha, Shyam S [National Renewable Energy Laboratory (NREL); Pivovar, Bryan [Los Alamos National Laboratory (LANL)

2014-01-01T23:59:59.000Z

325

Geochemical, metagenomic and metaproteomic insights into trace metal utilization by methane-oxidizing microbial consortia in sulfidic marine sediments  

SciTech Connect

Microbes have obligate requirements for trace metals in metalloenzymes that catalyze important biogeochemical reactions. In anoxic methane- and sulfide-rich environments, microbes may have unique adaptations for metal acquisition and utilization due to decreased bioavailability as a result of metal sulfide precipitation. However, micronutrient cycling is largely unexplored in cold ( 10 C) and sulfidic (>1 mM H2S) deep-sea methane seep ecosystems. We investigated trace metal geochemistry and microbial metal utilization in methane seeps offshore Oregon and California, USA, and report dissolved concentrations of nickel (0.5-270 nM), cobalt (0.5-6 nM), molybdenum (10-5,600 nM) and tungsten (0.3-8 nM) in Hydrate Ridge sediment porewaters. Despite low levels of cobalt and tungsten, metagenomic and metaproteomic data suggest that microbial consortia catalyzing anaerobic oxidation of methane utilize both scarce micronutrients in addition to nickel and molybdenum. Genetic machinery for cobalt-containing vitamin B12 biosynthesis was present in both anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB). Proteins affiliated with the tungsten-containing form of formylmethanofuran dehydrogenase were expressed in ANME from two seep ecosystems, the first evidence for expression of a tungstoenzyme in psychrotolerant microorganisms. Finally, our data suggest that chemical speciation of metals in highly sulfidic porewaters may exert a stronger influence on microbial bioavailability than total concentration

Glass, DR. Jennifer [California Institute of Technology, Pasadena; Yu, DR. Hang [California Institute of Technology, Pasadena; Steele, Joshua [California Institute of Technology, Pasadena; Dawson, Katherine [California Institute of Technology, Pasadena; Sun, S [University of California, San Diego; Chourey, Karuna [ORNL; Hettich, Robert {Bob} L [ORNL; Orphan, V [California Institute of Technology, Pasadena

2014-01-01T23:59:59.000Z

326

Heavy metal biosensor  

DOE Patents (OSTI)

Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

2014-04-15T23:59:59.000Z

327

Atomic and electronic structure of simple metal/graphene and complex metal/graphene/metal interfaces  

Science Journals Connector (OSTI)

Structural, electronic, and magnetic properties of simple interfaces (graphene on top of a metallic substrate) and complex interfaces (a single metallic adlayer on a simple graphene/metal system, either on top or between the graphene and metallic substrate) have been studied using density functional theory. Two types of simple interface with strong (Ni/graphene) and weak (Cu/graphene) bonding were considered. In addition to binding energies and interface distances, which are used to quantify the strength of graphene-substrate interactions, the bonding in simple and complex interfaces was analyzed using charge density distributions and bond orders. Substantial enhancement of the metallic substrate/graphene binding was observed in complex interfaces, consisting of a Ni monolayer on top of a simple {Ni or Cu}/graphene interface. The increase of substrate-graphene bonding in such complex interfaces is accompanied by weakening of in-plane C-C bonds in graphene, as quantified by the bond orders. A weak ferrimagnetism in graphene, i.e., unequal magnetic moments ?0.04?B and +0.06?B on the C atoms, is induced by a ferromagnetic Ni substrate. The strength of graphene-substrate interactions is also reflected in simulated scanning tunneling microscopy images.

Lyudmyla Adamska; You Lin; Andrew J. Ross; Matthias Batzill; Ivan I. Oleynik

2012-05-22T23:59:59.000Z

328

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

329

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

330

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

331

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

332

In-situ repairs of pipelines using metal arc welding under oil (MAW-UO) aided by eddy current crack detection  

Science Journals Connector (OSTI)

Metal arc welding under oil (MAW-UO) is a new process developed to make in-situ internal repairs of in-service oil industry pipelines tanks and vessels without the need to evacuate the service from the containing fluid. High nickel alloy welding wires were used to produce a tough relatively soft austenitic weld metal; with reduced weld metal hardness porosity residual strain and cracking susceptibility. Eddy current sensors were able to detect cracks under oil which then can be repaired in-situ using MAW-UO. The in-situ under oil crack detection and arc weld repair process will be described.

2012-01-01T23:59:59.000Z

333

Crystalline silicon growth in nickel/a-silicon bilayer  

SciTech Connect

The effect of substrate temperature on amorphous Silicon crystallization, mediated by metal impurity is reported. Bilayers of Ni(200nm)/Si(400nm) are deposited on fused silica substrate by electron beam evaporator at 200 and 500 Degree-Sign C. Raman mapping shows that, 2 to 5 micron size crystalline silicon clusters are distributed over the entire surface of the sample. X-ray diffraction and X-ray absorption spectroscopy studies demonstrate silicon crystallizes over the metal silicide seeds and grow with the annealing temperature.

Mohiddon, Md Ahamad; Naidu, K. Lakshun [School of Physics, University of Hyderabad, Hyderabad-500046 (India) and Department of Physics, University of Trento, 38123 POVO (Trento) (Italy); Dalba, G. [Department of Physics, University of Trento, 38123 POVO (Trento) (Italy); Rocca, F. [IFN-CNR, Institute for Photonics and Nanotechnologies, Unit FBK-Photonics of Trento, 38123, Trento (Italy); Krishna, M. Ghanashyam [School of Physics, University of Hyderabad, Hyderabad-500046 (India)

2013-02-05T23:59:59.000Z

334

Nickel-base superalloys for ultra-supercritical coal-fired power plants: Fireside corrosion. Laboratory studies and power plant exposures  

Science Journals Connector (OSTI)

The aim of the study was to determine the fireside corrosion performance of certain nickel-base superalloys dedicated for construction of superheater and reheater sections of a boiler operating at advanced ultra-supercritical conditions. For this purpose, three nickel-base alloys varying in chromium content from 20% to 25% (Alloys 263, 617 and 740) were selected for laboratory tests up to 1000 h. Additionally, the chosen materials were exposed using a temperature-controlled corrosion probe in a 500 kWth pulverized fuel test rig, one lignite-fired and two hard-coal-fired power plants. The specimens’ temperatures were in the range 640–760 °C. The fireside corrosion was studied having in focus the synergy effect of combustion gas atmosphere, real fly ash deposits and alloy composition. Corrosion behavior of each alloy was determined using dimensional metrology and the obtained results were compared with data available from the literature. The values measured on the samples exposed in power plants fit well with the numbers generated from the laboratory tests performed at 24, 350 and 1000 h. Moreover the values are in good agreement with results found in the literature and similar alloy ranking based on corrosion resistance is confirmed by the literature. Clear sulphur-induced corrosion was noticed after 1000 h exposures in the laboratory furnaces at only one of the examined alloys, which is characterized by the highest molybdenum and lowest titanium content. Both of these elements are believed to play a significant role in the corrosion behavior of the examined alloys. In some metal rings exposed in power plants sulphur induced corrosion is witnessed. In contrast to iron-base austenitic steels no straight connection is observed between increasing chromium content and improved corrosion resistance in the nickel-base austenites. Intergranular oxidation with participation of alumina repeats and occasionally leads almost to a grain release. In laboratory conditions fly ash appears to partially inhibit the corrosive influence of the gas atmosphere, since it behaves to a certain extent as a protective barrier for the metal surface while acting as a “sulphur sink”.

Gosia Stein-Brzozowska; Diana M. Flórez; Jörg Maier; Günter Scheffknecht

2013-01-01T23:59:59.000Z

335

Stability of nickel-coated sand as gravel-pack material for thermal wells  

SciTech Connect

Laboratory flow tests have been carried out to study the stability of various nickel-coated sands under aqueous steam temperature and pH conditions that may exist in thermal recovery operations. Other gravel-pack materials tested include Ottawa sand, sintered bauxite, cement clinker, zirconium oxide, and nickel pellets. A comparison was made between the performances of these materials after exposure to identical thermal and hydrolytic conditions. Test results indicate that nickel-coated sands are highly resistant to dissolution at temperatures as high as 300/sup 0/C (570/sup 0/F) and to solution pH's from 4.75 to 11. Weight losses measured after a 72-hour period were less than 1%. In contrast, weight losses from sintered bauxite, zirconium oxide, and Ottawa sand dissolution tests were 30 to 70 times higher under the same conditions. Cement clinker losses were in the intermediate range under alkaline conditions. API standard crushing and acid-solubility tests for proppants also were performed on nickel-coated sands. These results were favorable in that they exceeded the recommended standards. This study of nickel-coated sand stability and mechanical strength has demonstrated its high potential for application as either a gravel-pack material or proppant in thermal recovery operations.

Sacuta, A.; Nguyen, D.M.; Kissel, G.A. (Alberta Research Council (CA))

1988-11-01T23:59:59.000Z

336

Nickel hydrogen battery cell testing data base: an industry and government survey  

SciTech Connect

Both government and industry were surveyed to determine the level of testing of nickel hydrogen (NiH/sub 2/) battery cells and to evaluate the demonstrable capabilities of the couple. Only flight-type cells undergoing ground test were incorporated in the data base; no boilerplate cells or flight batteries were included. Both USAF-design and COMSAT-design cells, as well as a few cells produced by SAFT, were listed. The USAF design is in test in both high and low-earth-orbit simulations, whereas the COMSAT design, intended specifically for high-orbit applications, is being tested predominantly in high orbits. The data from over 400 cells show that the reliability and capability of both designs for high-orbit applications are reasonably established out to ten years in geosynchronous orbit, and to approximately 3000 cycles in other high-orbit applications. However, the data base is weak and incomplete for applications of the USAF cell in low earth orbit. This results from the harsh testing environment to which these cells have been subjected, as well as from various minor design questions that were not resolved when these cells began testing. It must also be pointed out that most of the testing data base is constructed from cells that were developmental in design or manufacture (all cells purchased for a test are used, even if their performance is questionable), as contrasted to a flight program where it can be assumed that many of the failures listed would have been rejected prior either to life test or their use in a flight battery.

Badcock, C.C.; Milden, M.J.

1985-12-31T23:59:59.000Z

337

A Modular, Energy-Based Approach to the Development of Nickel Containing Molecular Electrocatalysts for Hydrogen Production and Oxidation  

SciTech Connect

This review discusses the development of molecular electrocatalysts for H2 production and oxidation based on nickel. A modular approach is used in which the structure of the catalyst is divided into first second and outer coordination spheres. The first coordination sphere consists of the ligands bound directly to the metal center, and this coordination sphere can be used to control such factors as the presence or absence of vacant coordination sites, redox potentials, hydride acceptor abilities and other important thermodynamic parameters. The second coordination sphere is defined as functional groups such as pendant acids or bases that can interact with bound substrates such as H2 molecules and hydride ligands, but that do not form strong bonds with the metal center. These functional groups can play diverse roles such as assisting the heterolytic cleavage of H2, controlling intra- and intermolecular proton transfer reactions, and provide a physical pathway for coupling proton and electron transfer reactions. By controlling both the hydride donor/acceptor ability of the catalysts using the first coordination sphere and the proton acceptor/donor abilities of the functional groups in the second coordination sphere, catalysts can be designed that are biased toward H2 production, H2 oxidation, or that are bidirectional (catalyzing both H2 oxidation and production). The outer coordination sphere is defined as that portion of the catalytic system that are not in the first and second coordination spheres. This coordination sphere can assist in the delivery of protons and electrons to and from the catalytically active site, thereby adding another important avenue for controlling catalytic activity. Many features of these simple catalytic systems are good models for enzymes and they provide the opportunity to probe certain aspects of catalysis that may be difficult in enzymes themselves, but that can provide insights into enzyme function and reactivity.

Shaw, Wendy J.; Helm, Monte L.; DuBois, Daniel L.

2013-08-01T23:59:59.000Z

338

Nickel(II) and copper(II) complexes with pyridine-containing macrocycles bearing an aminopropyl pendant arm: synthesis,  

E-Print Network (OSTI)

Nickel(II) and copper(II) complexes with pyridine-containing macrocycles bearing an aminopropyl that were used for the preparation of the copper(II) complexes. The structures of three nickel(II) complexes and two copper(II) complexes were determined by X-ray crystallography. Protonation of the pendant arm (p

Nazarenko, Alexander

339

High-temperature Hydrogen Permeation in Nickel Alloys  

SciTech Connect

In gas cooled Very High Temperature Reactor concepts, tritium is produced as a tertiary fission product and by activation of graphite core contaminants, such as lithium; of the helium isotope, He-3, that is naturally present in the He gas coolant; and the boron in the B4C burnable poison. Because of its high mobility at the reactor outlet temperatures, tritium poses a risk of permeating through the walls of the intermediate heat exchanger (IHX) or steam generator (SG) systems, potentially contaminating the environment and in particular the hydrogen product when the reactor heat is utilized in connection with a hydrogen generation plant. An experiment to measure tritium permeation in structural materials at temperatures up to 1000 C has been constructed at the Idaho National Laboratory Safety and Tritium Applied Research (STAR) facility within the Next Generation Nuclear Plant program. The design is based on two counter flowing helium loops to represent heat exchanger conditions and was optimized to allow control of the materials surface condition and the investigation of the effects of thermal fatigue. In the ongoing campaign three nickel alloys are being considered because of their high-temperature creep properties, alloy 617, 800H and 230. This paper introduces the general issues related to tritium in the on-going assessment of gas cooled VHTR systems fission product transport and outlines the planned research activities in this area; outlines the features and capabilities of the experimental facility being operated at INL; presents and discusses the initial results of hydrogen permeability measurements in two of the selected alloys and compares them with the available database from previous studies.

P. Calderoni; M. Ebner; R. Pawelko

2010-10-01T23:59:59.000Z

340

Melanin Types  

NLE Websites -- All DOE Office Websites (Extended Search)

Melanin Types Melanin Types Name: Irfan Location: N/A Country: N/A Date: N/A Question: What are different types of melanins? And what are the functions of these types? Replies: Hi Irfan! Melanin is a dark compound or better a photoprotective pigment. Its major role in the skin is to absorb the ultraviolet (UV) light that comes from the sun so the skin is not damaged. Sun exposure usually produces a tan at the skin that represents an increase of melanin pigment in the skin. Melanin is important also in other areas of the body, as the eye and the brain., but it is not completely understood what the melanin pigment does in these areas. Melanin forms a special cell called melanocyte. This cell is found in the skin, in the hair follicle, and in the iris and retina of the eye.

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Method for improving x-ray diffraction determinations of residual stress in nickel-base alloys  

DOE Patents (OSTI)

A process for improving the technique of measuring residual stress by x-ray diffraction in pieces of nickel-base alloys is discussed. Part of a predetermined area of the surface of a nickel-base alloy is covered with a dispersion. This exposes the covered and uncovered portions of the surface of the alloy to x-rays by way of an x-ray diffractometry apparatus, making x-ray diffraction determinations of the exposed surface, and measuring the residual stress in the alloy based on these determinations. The dispersion is opaque to x-rays and serves a dual purpose, since it masks off unsatisfactory signals such that only a small portion of the surface is measured, and it supplies an internal standard by providing diffractogram peaks comparable to the peaks of the nickel alloy so that the alloy peaks can be very accurately located regardless of any sources of error external to the sample. 2 figs.

Berman, R.M.; Cohen, I.

1988-04-26T23:59:59.000Z

342

Recycling nickel electroplating rinse waters by low temperature evaporation and reverse osmosis  

SciTech Connect

Low temperature evaporation and reverse osmosis systems were each evaluated (on a pilot scale) on their respective ability to process rinse water collected from a nickel electroplating operation. Each system offered advantages under specific operating conditions. The low temperature evaporation system was best suited to processing solutions with relatively high (greater than 4,000 to 5,000 mg/L) nickel concentrations. The reverse osmosis system was best adapted to conditions where the feed solution had a relatively low (less than4,000 to 5,000 mg/L) nickel concentration. In electroplating operations where relatively dilute rinse water solutions must be concentrated to levels acceptable for replacement in the plating bath, a combination of the two technologies might provide the best process alternative.

Lindsey, T.C.; Randall, P.M.

1993-08-01T23:59:59.000Z

343

Epitaxial growth of nickel on Si(100) by dc magnetron sputtering  

SciTech Connect

The influence of the substrate temperature on the growth of highly textured Ni(111) and epitaxial Ni(200) with the relationships Ni[100] parallel Si[110] and Ni(001) parallel Si(001) on hydrogen terminated Si(100) wafer substrates by means of direct current magnetron sputtering is reported. In order to minimize crystal defect formation and to achieve a high quality epitaxial growth of Ni on Si, a two step deposition process was developed whereby different deposition conditions were used for an initial nickel seed layer and the remaining nickel film. The in-plane and out-of-plane structural properties of the films were investigated using x-ray scattering techniques, whereas magneto-optical Kerr effect and neutron reflectometry were used to confirm the magnetic nature of the epitaxially deposited nickel films.

Kreuzpaintner, W.; Stoermer, M.; Lott, D.; Solina, D.; Schreyer, A. [GKSS Forschungszentrum GmbH, Max-Planck-Strasse 1, 21502 Geesthacht (Germany)

2008-12-01T23:59:59.000Z

344

Money where it comes from and how we use it MA.02.01.06.07: Identifies pennies, nickels, dimes, and quarters, and their values.  

E-Print Network (OSTI)

Money Ā­ where it comes from and how we use it MA.02.01.06.07: Identifies pennies, nickels, dimes properties. Pre-survey: How is money made? Where is money made? What is the name of each coin? What in value section on chart - use money magnets to discuss how many pennies make a nickel, nickels make

345

Sheffield Metals International | Open Energy Information  

Open Energy Info (EERE)

Metals International Metals International Jump to: navigation, search Name Sheffield Metals International Address 5467 Evergreen Parkway Place Sheffield Village, Ohio Zip 44054 Sector Buildings, Efficiency, Solar Product Agriculture; Consulting; Manufacturing; Retail product sales and distribution;Trainining and education Phone number 800-283-5262 Website http://www.sheffieldmetals.com Coordinates 41.452914Ā°, -82.072009Ā° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.452914,"lon":-82.072009,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

346

Daiyang Metal Co Ltd | Open Energy Information  

Open Energy Info (EERE)

Daiyang Metal Co Ltd Daiyang Metal Co Ltd Jump to: navigation, search Name Daiyang Metal Co Ltd Place Seoul, Seoul, Korea (Republic) Zip 137-040 Sector Solar Product Stainless steel manufacturing and CIGS solar cell maker. Coordinates 37.557121Ā°, 126.977379Ā° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":37.557121,"lon":126.977379,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

347

Northern States Metals Company | Open Energy Information  

Open Energy Info (EERE)

Metals Company Metals Company Jump to: navigation, search Name Northern States Metals Company Address 3207 Innovation Place Place Youngstown, Ohio Zip 44509 Sector Solar Product Manufacturing Phone number 330-799-1855 Website http://extrusions.com Coordinates 41.123592Ā°, -80.704685Ā° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.123592,"lon":-80.704685,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

348

In situ catalytic conversion of tar using rice husk char/ash supported nickel–iron catalysts for biomass pyrolytic gasification combined with the mixing-simulation in fluidized-bed gasifier  

Science Journals Connector (OSTI)

Abstract A catalytic gasification technology has been proposed for tar in situ conversion using the rice husk char (RHC) or rice husk ash (RHA) supported nickel–iron catalysts. Biomass tar could be converted effectively by co-pyrolysis with the RHC/RHA supported nickel–iron catalysts at 800 °C, simplifying the follow-up tar removal process. Under the optimized conditions, the tar conversion efficiency could reach about 92.3% by the RHC Ni–Fe, which exhibited more advantages of easy preparation and energy-saving. In addition, the tar conversion efficiency could reach about 93% by the RHA Ni. Significantly, partial metal oxides (e.g., NiO, Fe2O3) in the carbon matrix of RHC could be in-situ carbothermally reduced into the metallic state (e.g., Ni0) by reducing gases (e.g., CO) or carbon atom, thereby enhancing the catalytic performance of tar conversion. Furthermore, mixing with other solid particles such as sand and RHA Ni, can also improve biomass (e.g., RH) fluidization behavior by optimizing the operation parameters (e.g., particle size, mass fraction) in the mode of fluidized bed gasifier (FBG). After the solid–solid mixing simulation, the RH mass fraction of 0.5 and the particle diameter of 0.5 mm can be employed in the binary mixture of RH and RHA.

Yafei Shen; Peitao Zhao; Qinfu Shao; Fumitake Takahashi; Kunio Yoshikawa

2014-01-01T23:59:59.000Z

349

Method of attaching ceramics to gas-turbine metal components  

SciTech Connect

When attaching ceramics to metal gas-turbine parts, an interlayer of lowmodulus fiber metal is recommended as a buffer layer to compensate for the different coefficients of thermal expansion. This elastic interlayer, made of matted and sintered metallic fibers, is actually a woven mat with 90% of the volume taken up by porosity. Nickel alloys, Hastelloy-X, Inconel-600, FeCrAlSi, and FeCrAlY can be used for the interlayer. However, the last two alloys provide optimum oxidation and high-temperature-corrosion resistance. The interlayers are attached to the component metal by normal brazing, while the ceramic is attached by plasma spraying. The bond between the ceramic and the interlayer is formed by the penetration and condensation of the sprayed powder in the interlayer pores. This joining method can be most efficiently used in high-pressure-turbine seals; combustion-chamber facings; facings of slag hoppers and boosted steamboiler combustion chambers; coal gasification equipment, including valves, cyclones, transport main pipelines and exhaust valves; cylinder heads; and diesel engine pistons.

Legchilin, P.F.

1985-01-01T23:59:59.000Z

350

THE EFFECT OF SMECTITE ON THE CORROSION OF IRON METAL. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

THE EFFECT OF SMECTITE ON THE CORROSION OF IRON METAL. THE EFFECT OF SMECTITE ON THE CORROSION OF IRON METAL. Abstract: The combination of zero-valent iron and a clay-type...

351

High-Affinity Binding and Direct Electron Transfer to Solid Metals...  

NLE Websites -- All DOE Office Websites (Extended Search)

Binding and Direct Electron Transfer to Solid Metals by the Shewanella oneidensis MR-1 Outer Membrane c-type High-Affinity Binding and Direct Electron Transfer to Solid Metals...

352

Exploring the mechanisms critical to the operation of metal face seals through modeling and experiments  

E-Print Network (OSTI)

This thesis aims to explore operation mechanisms of a special type of mechanical face seals: the flexible metal-to-metal face seal (FMMFS). Unique features of the FMMFS include much more flexibility in the circumferential ...

Wang, Yong, Ph. D. Massachusetts Institute of Technology, Dept. of Aeronautics and Astronautics

2008-01-01T23:59:59.000Z

353

A Computational Approach to Homogenizing Nickel-Based Single Crystal Alloys  

NLE Websites -- All DOE Office Websites (Extended Search)

Computational Approach to Homogenizing Nickel-Based Computational Approach to Homogenizing Nickel-Based Single Crystal Alloys Contact NETL Technology Transfer Group techtransfer@netl.doe.gov May 2013 Significance * Provides significantly diminished processing costs, including reduced energy consumption and throughput times, and increased availability of capital equipment such as furnaces, due to shorter heat treatments * Generates superior Ni-based superalloys with improved performance in downstream applications * Provides extreme flexibility, allowing for modification to meet the differing constraints of individual production facilities and the level of homogenization desired

354

Graphene-Passivated Nickel as an Oxidation-Resistant Electrode for Spintronics  

E-Print Network (OSTI)

1 Published as: ACS Nano 6, 10930 (2012) DOI: 10.1021/nn304424x Graphene-Passivated Nickel as an Oxidation-Resistant Electrode for Spintronics Bruno Dlubak1, Marie-Blandine Martin2, Robert S. Weatherup1, Heejun Yang2, Cyrile Deranlot2... 4-6, 14195 Berlin, Germany We report on graphene-passivated ferromagnetic electrodes (GPFE) for spin devices. GPFE are shown to act as spin-polarized oxidation-resistant electrodes. The direct coating of nickel with few layer graphene through a...

Dlubak, Bruno; Martin, Marie-Blandine; Weatherup, Robert S.; Yang, Heejun; Deranlot, Cyrile; Blume, Raoul; Schloegl, Robert; Fert, Albert; Anane, Abdelmadjid; Hofmann, Stephan; Seneor, Pierre; Robertson, John

2012-11-12T23:59:59.000Z

355

Synthesis Of Fluorescent Metal Nanoclusters  

NLE Websites -- All DOE Office Websites (Extended Search)

Synthesis Of Fluorescent Metal Nanoclusters Synthesis Of Fluorescent Metal Nanoclusters Fluorescent metal nanoclusters were prepared. Available for thumbnail of Feynman Center...

356

Method of Applying a Cerium Diffusion Coating to a Metallic Alloy  

NLE Websites -- All DOE Office Websites (Extended Search)

Applying a Cerium Diffusion Applying a Cerium Diffusion Coating to a Metallic Alloy Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,553,517 entitled "Method of Applying a Cerium Diffusion Coating to a Metallic Alloy." This invention is applicable to advanced, next-generation power plant components; solid oxide fuels cells; heaters and heat exchangers; or any other application where oxidation-resistant metals are needed. Disclosed in this patent is NETL's robust, inexpensive process for increasing the oxidation resistance of nickel-based superalloys, as well as ferritic and austenitic stainless steels. The process involves applying a cerium oxide (CeO

357

DOE - Office of Legacy Management -- Metals Disintegrating Co Inc - NJ 0-03  

Office of Legacy Management (LM)

Disintegrating Co Inc - NJ Disintegrating Co Inc - NJ 0-03 FUSRAP Considered Sites Site: METALS DISINTEGRATING CO., INC. (NJ.0-03 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 271 Grove Avenue , Verona or Elizabeth , New Jersey NJ.0-03-1 NJ.0-03-2 NJ.0-03-3 Evaluation Year: 1987 NJ.0-03-3 Site Operations: Provided nickel to Linde. NJ.0-03-3 NJ.0-03-4 Site Disposition: Eliminated - No radioactive materials were handled at this site. NJ.0-03-3 Radioactive Materials Handled: None Indicated Primary Radioactive Materials Handled: None Indicated Radiological Survey(s): None Indicated Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to METALS DISINTEGRATING CO., INC. NJ.0-03-1 - Letter; Goman to Metals Disintegrating Company, Inc.

358

Nickel Solubility and Precipitation in Soils: A Thermodynamic Study  

SciTech Connect

The formation of mixed-metal-Al layered double hydroxide (LDH) phases similar to hydrotalcite has been identified as a significant mechanism for immobilization of trace metals in some environmental systems. These precipitate phases become increasingly stable as they age, and their formation may therefore be an important pathway for sequestration of toxic metals in contaminated soils. However, the lack of thermodynamic data for LDH phases makes it difficult to model their behavior in natural systems. In this work, enthalpies of formation for Ni LDH phases with nitrate and sulfate interlayers were determined and compared to recently published data on carbonate interlayer LDHs. Differences in the identity of the anion interlayer resulted in substantial changes in the enthalpies of formation of the LDH phases, in the order of increasing enthalpy carbonate

Peltier,E.; Allada, R.; Navrotsky, A.; Sparks, D.

2006-01-01T23:59:59.000Z

359

Metal phthalocyanine catalysts  

DOE Patents (OSTI)

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

1994-01-01T23:59:59.000Z

360

MECS 2006- Fabricated Metals  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Fabricated Metals (NAICS 332) Sector with Total Energy Input, October 2012 (MECS 2006)

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Notice Type: Presolicitation  

E-Print Network (OSTI)

NAICS Code: 332 -- Fabricated Metal Product Manufacturing/332322 -- Sheet Metal Work Manufacturing Storage Container. (Microsoft IE required). Additional specifications and opening and closing dates

362

Deposition of Contiguous Metal Adlayer on Transition Metal Nanostructu...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Abstract Primary Lab Date Application 20100099012 Application 20100099012 Electrocatalyst Synthesized by Depositing a Contiguous Metal Adlayer on Transition Metal...

363

Pulmonary toxicity after exposure to military-relevant heavy metal tungsten alloy particles  

SciTech Connect

Significant controversy over the environmental and public health impact of depleted uranium use in the Gulf War and the war in the Balkans has prompted the investigation and use of other materials including heavy metal tungsten alloys (HMTAs) as nontoxic alternatives. Interest in the health effects of HMTAs has peaked since the recent discovery that rats intramuscularly implanted with pellets containing 91.1% tungsten/6% nickel/2.9% cobalt rapidly developed aggressive metastatic tumors at the implantation site. Very little is known, however, regarding the cellular and molecular mechanisms associated with the effects of inhalation exposure to HMTAs despite the recognized risk of this route of exposure to military personnel. In the current study military-relevant metal powder mixtures consisting of 92% tungsten/5% nickel/3% cobalt (WNiCo) and 92% tungsten/5% nickel/3% iron (WNiFe), pure metals, or vehicle (saline) were instilled intratracheally in rats. Pulmonary toxicity was assessed by cytologic analysis, lactate dehydrogenase activity, albumin content, and inflammatory cytokine levels in bronchoalveolar lavage fluid 24 h after instillation. The expression of 84 stress and toxicity-related genes was profiled in lung tissue and bronchoalveolar lavage cells using real-time quantitative PCR arrays, and in vitro assays were performed to measure the oxidative burst response and phagocytosis by lung macrophages. Results from this study determined that exposure to WNiCo and WNiFe induces pulmonary inflammation and altered expression of genes associated with oxidative and metabolic stress and toxicity. Inhalation exposure to both HMTAs likely causes lung injury by inducing macrophage activation, neutrophilia, and the generation of toxic oxygen radicals. -- Highlights: ? Intratracheal instillation of W–Ni–Co and W–Ni–Fe induces lung inflammation in rats. ? W–Ni–Co and W–Ni–Fe alter expression of oxidative stress and toxicity genes. ? W–Ni–Co induces a greater oxidative burst response than W–Ni–Fe in lung macrophages.

Roedel, Erik Q., E-mail: Erik.Roedel@amedd.army.mil [Department of General Surgery, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Cafasso, Danielle E., E-mail: Danielle.Cafasso@amedd.army.mil [Department of General Surgery, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Lee, Karen W.M., E-mail: Karen.W.Lee@amedd.army.mil [Department of Clinical Investigation, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Pierce, Lisa M., E-mail: Lisa.Pierce@amedd.army.mil [Department of Clinical Investigation, Tripler Army Medical Center, Honolulu, HI 96859 (United States)

2012-02-15T23:59:59.000Z

364

Nonrandom Chromosomal Alterations in Nickel-transformed Chinese Hamster Embryo Cells  

Science Journals Connector (OSTI)

...from the agar (Table 1). Four of 12 nickel-treated female...of the X chromosome (Xq). Four of 7 male lines transformed...indicated by arrows. !1Cl lift li IN iss u ... 'I 8 10 X...translocation, and the break point on chromosome 5 was at the same...

Kathleen Conway and Max Costa

1989-11-01T23:59:59.000Z

365

Studies in Bioinorganic Chemistry: Synthesis and Reactivity of Nickel and Vanadyl NxSy Complexes  

E-Print Network (OSTI)

As inspired by the coordination environment of nickel in NikR and NiSOD, imidazole ligands were incorporated into N2SNiII square planar complexes in order to investigate the electronic and structural features of NiII species containing both...

Jenkins, Roxanne Michelle

2011-08-08T23:59:59.000Z

366

Influence of steps on the interaction between adsorbed hydrogen atoms and a nickel surface  

E-Print Network (OSTI)

practical phenomena such as hydrogen stor- age, corrosion, and embrittlement. One of the goals of surfaceInfluence of steps on the interaction between adsorbed hydrogen atoms and a nickel surface Aubrey T-dimensional phase behavior of adsorbed hydrogen on a Ni surface using helium atom scattering. Specifically

Sibener, Steven

367

Nickel catalyst faceting in plasma-enhanced direct current chemical vapor deposition of carbon nanofibers  

E-Print Network (OSTI)

1 Nickel catalyst faceting in plasma-enhanced direct current chemical vapor deposition of carbon vapor deposition with Ni catalysts on the top of nanofibers. Transmission electron microscopy was used to study the morphology and crystallography of Ni catalysts, which are essential for the nucleation

Paris-Sud XI, UniversitƩ de

368

Nickel Phase Wettability and YSZ Redox Fracture Percolation in Solid Oxide Fuel Cell Anodes  

E-Print Network (OSTI)

Nickel Phase Wettability and YSZ Redox Fracture Percolation in Solid Oxide Fuel Cell Anodes Alex and Aerospace Engineering Background Solid oxide fuel cells lose mechanical stability and functionality when oxidize (redox reaction) instead of the hydrogen fuel [2]. This conversion to NiO exerts a volumetric

Petta, Jason

369

Design of a creep resistant nickel base superalloy for power plant applications  

E-Print Network (OSTI)

-component system based on the assessment of binary, ternary, and quaternary experimental data. It puts several and used as tools to design a new `made to measure' nickel base superalloy for power plant applications with steam temperatures as high as 750Ā°C. This alloy has been designed on the basis of its estimated

Cambridge, University of

370

HYDROGEN STORAGE IN NICKEL DOPED MCM-41 Ezgi Dndar Tekkaya1  

E-Print Network (OSTI)

HYDROGEN STORAGE IN NICKEL DOPED MCM-41 Ezgi DĆ¼ndar Tekkaya1 and Yuda YĆ¼rĆ¼m1 1 Faculty of hydrogen results with increasing demand to hydrogen production and storage. Recent studies show that materials having high surface area, large pore size and high affinity to hydrogen have high hydrogen storage

Yanikoglu, Berrin

371

Comparing calculated and measured grain boundary energies in nickel Gregory S. Rohrer a  

E-Print Network (OSTI)

Comparing calculated and measured grain boundary energies in nickel Gregory S. Rohrer a , Elizabeth measured and computed grain boundary energies. While the overall correlation between experimental Laboratories (SNL) [23] have utilized new, high-throughput methods to measure energy for large ensembles

Rohrer, Gregory S.

372

Decorating multi-walled carbon nanotubes with nickel nanoparticles for selective hydrogenation of citral  

SciTech Connect

The nanocomposites of multi-walled carbon nanotubes (MWNTs) decorated with nickel nanoparticles were conveniently prepared by a chemical reduction of nickel salt in the present of poly(acrylic acid) grafted MWNTs (PAA-g-MWNTs). Due to the strong interaction between Ni{sup 2+} and -COOH, PAA-g-MWNTs became an excellent supporting material for Ni nanoparticles. The morphology and distribution of Ni nanoparticles on the surface of MWNTs were greatly influenced by the reduction temperatures, the experimental results also showed that the distribution of Ni nanoparticles was greatly improved while the MWNTs were modified by poly(acrylic acid) (PAA). The hydrogenation activity and selectivity of MWNTs decorated with Ni nanoparticles (Ni-MWNTs) for alpha, beta-unsaturated aldehyde (citral) were also studied, and the experimental results showed that the citronellal, an important raw material for flavoring and perfumery industries, is the favorable product with a percentage as high as 86.9%, which is 7 times higher than that of catalyst by Ni-supported active carbon (Ni-AC). - Abstract: Nickel nanoparticles decorated multi-walled carbon nanotubes (Ni-MWNTs) nanocomposites were conveniently prepared by a chemical reduction of nickel salt in the present of poly(acrylic acid) grafted MWNTs (PAA-g-MWNTs). These nanocomposites possessed excellent catalytic activity and selectivity for hydrogenation of citral.

Tang Yuechao; Yang Dong [Key Laboratory of Molecular Engineering of Polymers (Ministry of Education), Department of Macromolecular Science and Advanced Materials Laboratory, Fudan University, Shanghai 200433 (China); Qin Feng [Department of Chemistry, Fudan University, Shanghai 200433 (China); Hu Jianhua [Key Laboratory of Molecular Engineering of Polymers (Ministry of Education), Department of Macromolecular Science and Advanced Materials Laboratory, Fudan University, Shanghai 200433 (China); Wang Changchun, E-mail: ccwang@fudan.edu.c [Key Laboratory of Molecular Engineering of Polymers (Ministry of Education), Department of Macromolecular Science and Advanced Materials Laboratory, Fudan University, Shanghai 200433 (China); Xu Hualong [Department of Chemistry, Fudan University, Shanghai 200433 (China)

2009-08-15T23:59:59.000Z

373

Corrosion of nickel and Monel welds of steel in chlorine trifluoride  

SciTech Connect

Failures in the weld areas of nickel-plated steel pipe carrying chlorine trifluoride, ClF/sub 3/, prompted this investigation to determine the effect of weld composition on corrosion by ClF/sub 3/. Monel/steel and nickel/steel alloys of composition to simulate weld overlays were tested to determine their corrosion rates in ClF/sub 3/ at 200/degree/F and 300/degree/F. For both nickel/steel and Monel/steel, the corrosion rate was higher at the higher temperature. For nickel/steel alloys at compositions up to 50% iron, which would cover a range considered normal for welding, the corrosion rate would be within acceptable limits. For Monel/steel alloys, compositions up to 35% iron have an acceptable corrosion rate. Above this, the corrosion would be greater than a tolerable amount. It should pose no problem to keep the heat input to the weld low enough to produce a Monel weld with an iron content below 35%. 2 refs., 5 figs., 2 tabs.

Fout, S.L.

1988-07-25T23:59:59.000Z

374

High-temperature corrosion of metallic alloys in an oxidizing atmosphere containing NaCl  

SciTech Connect

A particular heat-exchanger application involved metallic alloys exposed to flue gases of an aluminum remelt furnace. Because the flue gases might contain NaCl and other halides, the corrosion behavior of the alloys was to be investigated. Planned direct exposure of candidate alloys to the flue gases, however, was not conducted because of premature termination of the project. Complementary laboratory testing was conducted on seven commercially available alloys and two nickel aluminides. These materials were exposed to an oxidizing atmosphere containing 0.06 wt % NaCl for 1100 h at 1000/degree/C. Most of the alloy exhibited grain-boundary attack, which resulted in complete oxidation of enveloped grains. The alloys Incoloy MA-956, Incoloy 800, Inconel 625, Inconel 601, Hastelloy X, Haynes 188, and nickel aluminide IC-50 were substantially more corroded than Alloy 214 and nickel aluminide IC-221. The latter two alloys, therefore, would probably be superior to the others in application involving flue gases containing NaCl. Strength fabricability, and weldability, which are briefly discussed, would also affect selection of materials. 8 refs., 12 figs., 5 tabs.

Federer, J.I.

1989-02-01T23:59:59.000Z

375

Metal Speciation in Landfill Leachates with a Focus on the Influence of Organic Matter  

SciTech Connect

This study characterizes the heavy-metal content in leachates collected from eight landfills in France. In order to identify heavy metal occurrence in the different size fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest that most of the metals are concentrated in the <30 kDa fraction, while lead, copper and cadmium show an association with larger particles. Initial speciation calculations, without considering metal association with organic matter, suggest that leachate concentrations in lead, copper, nickel and zinc are super-saturated with respect to sulphur phases. Speciation calculations that account for metal complexation with organic matter, considered as fulvic acids based on C1(s) NEXAFS spectroscopy, show that this mechanism is not sufficient to explain such deviation from equilibrium conditions. It is therefore hypothesized that the deviation results also from the influence of biological activity on the kinetics of mineral phase precipitation and dissolution, thus providing a dynamic system. The results of chemical analyses of sampled fluids are compared with speciation calculations and some implications for the assessment of metal mobility and natural attenuation in a context of landfill risk assessment are discussed.

F Claret; C Tournassat; C Crouzet; E Gaucher; T Schäfer; G Braibant; D Guyonnet

2011-12-31T23:59:59.000Z

376

Metal speciation in landfill leachates with a focus on the influence of organic matter  

SciTech Connect

Highlights: > This study characterises the heavy-metal content in leachates collected from eight landfills in France. > Most of the metals are concentrated in the <30 kDa fraction, while Pb, Cu and Cd are associated with larger particles. > Metal complexation with OM is not sufficient to explain apparent supersaturation of metals with sulphide minerals. - Abstract: This study characterises the heavy-metal content in leachates collected from eight landfills in France. In order to identify heavy metal occurrence in the different size fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest that most of the metals are concentrated in the <30 kDa fraction, while lead, copper and cadmium show an association with larger particles. Initial speciation calculations, without considering metal association with organic matter, suggest that leachate concentrations in lead, copper, nickel and zinc are super-saturated with respect to sulphur phases. Speciation calculations that account for metal complexation with organic matter, considered as fulvic acids based on C1(s) NEXAFS spectroscopy, show that this mechanism is not sufficient to explain such deviation from equilibrium conditions. It is therefore hypothesized that the deviation results also from the influence of biological activity on the kinetics of mineral phase precipitation and dissolution, thus providing a dynamic system. The results of chemical analyses of sampled fluids are compared with speciation calculations and some implications for the assessment of metal mobility and natural attenuation in a context of landfill risk assessment are discussed.

Claret, Francis, E-mail: f.claret@brgm.fr [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France); Tournassat, Christophe; Crouzet, Catherine; Gaucher, Eric C. [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France); Schaefer, Thorsten [Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, 76021 Karlsruhe (Germany); Freie Universitaet Berlin, Institute of Geological Sciences, Department of Earth Sciences, Hydrogeology Group, D-12249 Berlin (Germany); Braibant, Gilles; Guyonnet, Dominique [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France)

2011-09-15T23:59:59.000Z

377

Science at the interface : grain boundaries in nanocrystalline metals.  

SciTech Connect

Interfaces are a critical determinant of the full range of materials properties, especially at the nanoscale. Computational and experimental methods developed a comprehensive understanding of nanograin evolution based on a fundamental understanding of internal interfaces in nanocrystalline nickel. It has recently been shown that nanocrystals with a bi-modal grain-size distribution possess a unique combination of high-strength, ductility and wear-resistance. We performed a combined experimental and theoretical investigation of the structure and motion of internal interfaces in nanograined metal and the resulting grain evolution. The properties of grain boundaries are computed for an unprecedented range of boundaries. The presence of roughening transitions in grain boundaries is explored and related to dramatic changes in boundary mobility. Experimental observations show that abnormal grain growth in nanograined materials is unlike conventional scale material in both the level of defects and the formation of unfavored phases. Molecular dynamics simulations address the origins of some of these phenomena.

Rodriguez, Mark Andrew; Follstaedt, David Martin; Knapp, James Arthur; Brewer, Luke N.; Holm, Elizabeth Ann; Foiles, Stephen Martin; Hattar, Khalid M.; Clark, Blythe B.; Olmsted, David L.; Medlin, Douglas L.

2009-09-01T23:59:59.000Z

378

Experimental studies of the chemistry of metal clusters  

SciTech Connect

The procedures for studying chemical reactions of metal clusters in a continuous-flow reactor are described, and examples of such studies are given. Experiments to be discussed include kinetics and thermodynamics measurements, and determination of the composition of clusters saturated with various adsorbate reagents. Specific systems to be covered include the reaction of iron clusters with ammonia and with hydrogen, the reaction of nickel clusters with hydrogen and with ammonia, and the reaction of platinum clusters with ethylene. The last two reactions are characterized by complex, multi-step processes that lead to adsorbate decomposition and hydrogen desorption from the clusters. Methods for probing these processes will be discussed. 26 refs., 8 figs.

Parks, E.K.; Riley, S.J.

1988-01-01T23:59:59.000Z

379

Strengthening of metallic alloys with nanometer-size oxide dispersions  

DOE Patents (OSTI)

Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains.

Flinn, John E. (Idaho Falls, ID); Kelly, Thomas F. (Madison, WI)

1999-01-01T23:59:59.000Z

380

Strengthening of metallic alloys with nanometer-size oxide dispersions  

DOE Patents (OSTI)

Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains. 20 figs.

Flinn, J.E.; Kelly, T.F.

1999-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Nickel Catalysts Supported on Barium Hexaaluminate for Enhanced CO Methanation  

Science Journals Connector (OSTI)

(4, 5) Since Sabatier and Senderens discovered that some metals such as Ni, Ru, Rh, Pt, Fe, and Co could be used in the methanation reaction in 1902,(6) many methanation catalysts have been developed. ... In short, although Ni/Al2O3 catalysts have been extensively explored, their thermal stability and resistance to carbon deposition still need to be improved. ... Meanwhile, the catalyst coatings on the walls of micro-channel reactor showed high activity and stability, having the excellent catalytic performance for methanation reaction in micro-channel reactors and the reliability in long-term use as well. ...

Jiajian Gao; Chunmiao Jia; Jing Li; Fangna Gu; Guangwen Xu; Ziyi Zhong; Fabing Su

2012-07-16T23:59:59.000Z

382

The erosion-corrosion of copper-based and nickel-based alloys in warm polluted Arabian Gulf seawater  

SciTech Connect

This paper presents the results of an investigation of the erosion-corrosion behavior of copper-nickel alloys (90:10 Cu/Ni and 7030 Cu/Ni), nickel-copper alloy UNS N04400 and nickel-based alloys (UNS N06022, N06030 and UNS S32550) used as heat exchanger tubes, in warm flowing Arabian Gulf seawater containing up to 5 ppm of sulphide ions. Visual and optical examinations of the internal surfaces of the tubes were carried out to compare the susceptibilities to erosion-corrosion attack of the different alloys, taking into consideration the nature of the product films formed.

Carew, J.A. [Kuwait Inst. for Scientific Research, Safat (Kuwait); Islam, M. [Cortest Columbus Technologies Inc., Columbus, OH (United States)

1994-12-31T23:59:59.000Z

383

ccsd00001984, Selective production of metallic carbon nanotubes  

E-Print Network (OSTI)

ccsdĀ­00001984, version 1 Ā­ 18 Oct 2004 Selective production of metallic carbon nanotubes Yasushi- type nanotubes (metallic character) evaluated using the previous Huckel-Poisson method can be applied at the tip of a nanotube in a realistic system. Setting the cross-section of a nanotube and the external #12

384

Extraction process for removing metallic impurities from alkalide metals  

DOE Patents (OSTI)

A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

Royer, L.T.

1987-03-20T23:59:59.000Z

385

Radio-frequency-excited carbon dioxide metal waveguide laser  

Science Journals Connector (OSTI)

A new type of waveguide laser is described in which a single-surface concave metal waveguide also doubles as the grounded electrode in a radio-frequency-excited gaseous discharge. The...

Grossman, Jonathan G; Casperson, Lee W; Stafsudd, Oscar M

1983-01-01T23:59:59.000Z

386

Sumitomo Metal Industries Ltd Sumitomo Metals | Open Energy Information  

Open Energy Info (EERE)

Sumitomo Metal Industries Ltd Sumitomo Metals Sumitomo Metal Industries Ltd Sumitomo Metals Jump to: navigation, search Name Sumitomo Metal Industries Ltd (Sumitomo Metals) Place Osaka-shi, Osaka, Japan Zip 540-0041 Sector Solar Product Engaged in the steel, engineering, and electronics businesses; works on fuel cell component technology and manufactures silicon wafers for the solar sector. References Sumitomo Metal Industries Ltd (Sumitomo Metals)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Sumitomo Metal Industries Ltd (Sumitomo Metals) is a company located in Osaka-shi, Osaka, Japan . References ā†‘ "Sumitomo Metal Industries Ltd (Sumitomo Metals)" Retrieved from "http://en.openei.org/w/index.php?title=Sumitomo_Metal_Industries_Ltd_Sumitomo_Metals&oldid=351744"

387

Type: Renewal  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1 INCITE Awards 1 INCITE Awards Type: Renewal Title: -Ab Initio Dynamical Simulations for the Prediction of Bulk Propertiesā€– Principal Investigator: Theresa Windus, Iowa State University Co-Investigators: Brett Bode, Iowa State University Graham Fletcher, Argonne National Laboratory Mark Gordon, Iowa State University Monica Lamm, Iowa State University Michael Schmidt, Iowa State University Scientific Discipline: Chemistry: Physical INCITE Allocation: 10,000,000 processor hours Site: Argonne National Laboratory Machine (Allocation): IBM Blue Gene/P (10,000,000 processor hours) Research Summary: This project uses high-quality electronic structure theory, statistical mechanical methods, and

388

The role of crystallography and nanostructures on metallic friction.  

SciTech Connect

In ductile metals, sliding contact is often accompanied by severe plastic deformation localized to a small volume of material adjacent to the wear surface. During the initial run-in period, hardness, grain structure and crystallographic texture of the surfaces that come into sliding contact undergo significant changes, culminating in the evolution of subsurface layers with their own characteristic features. Here, a brief overview of our ongoing research on the fundamental phenomena governing the friction-induced recrystallization in single crystal metals, and how these recrystallized structures with nanometer-size grains would in turn influence metallic friction will be presented. We have employed a novel combination of experimental tools (FIB, EBSD and TEM) and an analysis of the critical resolved shear stress (RSS) on the twelve slip systems of the FCC lattice to understand the evolution of these friction-induced structures in single crystal nickel. The later part of the talk deals with the mechanisms of friction in nanocrystalline Ni films. Analyses of friction-induced subsurfaces seem to confirm that the formation of stable ultrafine nanocrystalline layers with 2-10 nm grains changes the deformation mechanism from the traditional dislocation mediated one to that is predominantly controlled by grain boundaries, resulting in significant reductions in the coefficient friction.

Michael, Joseph Richard; Prasad, Somuri V.; Battaile, Corbett Chandler; Majumdar, Bhaskar Sinha (New Mexico Institute of Mining & Technology, Socorro, NM); Kotula, Paul Gabriel

2010-06-01T23:59:59.000Z

389

Metallic glass alloys of Zr, Ti, Cu and Ni  

DOE Patents (OSTI)

At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM.sub.1-x Ti.sub.x).sub.a Cu.sub.b (Ni.sub.1-y Co.sub.y).sub.c wherein x is from 0.1 to 0.3, y.cndot.c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b.

Lin, Xianghong (Pasadena, CA); Peker, Atakan (Pasadena, CA); Johnson, William L. (Pasadena, CA)

1997-01-01T23:59:59.000Z

390

Bacteria Types  

NLE Websites -- All DOE Office Websites (Extended Search)

Bacteria Types Bacteria Types Name: Evelyn Location: N/A Country: N/A Date: N/A Question: What is the significance of S. marcescens,M.luteus, S.epidermidis, and E. Coli? Which of these are gram-positive and gram-negative, and where can these be found? Also, what problems can they cause? When we culture these bacteria, we used four methods: plates, broth, slants, and pour plates. The media was made of TSB, TSA, NAP, and NAD. What is significant about these culturing methods? Replies: I could give you the answer to that question but it is more informative, and fun, to find out yourself. Start with the NCBI library online (http://www.ncbi.nlm.nih.gov/) and do a query with the species name, and 'virulence' if you want to know what they're doing to us. Have a look at the taxonomy devision to see how they are related. To find out if they're gram-pos or neg you should do a gram stain if you can. Otherwise you'll find that information in any bacteriology determination guide. Your question about the media is not specific enough so I can't answer it.

391

Untersuchung des wasserstoffaustausches an Raney-Nickel mit hilfe einer magnet-elektrode  

Science Journals Connector (OSTI)

Zusammenfassung Es wird eine elektrochemische Zelle beschrieben, in der pulverförmiger Raney-Nickelkatalysator durch magnetische Kräfte in Kontakt mit einer Stromabnehmerelektrode gebracht wird. Der Kontakt kann ununterbrochen oder auch periodisch hergestellt werden. Damit ist eine bequeme Methode gegeben, die Ladungsübertragung an der Elektrode zu steuern. Der Aluminium- und Wasserstoffgehalt des Raney-Katalysators wurde in Abhängigkeit von der Vorbehandlung bestimmt. Frisch hergestellter Katalysator enthält mit 0,2 his 0,3 H pro 1 Ni wesentlich weniger Wasserstoff, als heute noch oft angenommen wird. Reversibel lässt sich der Wasserstoff nur bis zu einer Überspannung von etwa +150 mV austauschen. Bei höheren Überspannungen beginnt mit der Oxydation des Nickels die Inaktivierung des Katalysators. Die von anderen Autoren beschriebenen unterschiedlichen Bindungszustände des Wasserstoffs sind zum Teil als unterschiedliche Oxydationszustände des Nickels zu verstehen. Die Wasserstoff-Konzentration in Abhängigkeit von der Spannung, die Wasserstoffaufnahmegeschwindigkeit und die potentiostatischen Entladeströme vermitteln einen Überblick über die optimale anodische Belastbarkeit von wasserstoffhaltigem Raney-Nickel in Abhängigkeit von den experimentellen Bedingungen. Der Anfangsstrom bei 120 mV Überspannung an Raney-Nickel der Korngrösse 42 bis 50?m und einer Elektrodenbelegung von 20 mg Katalysator pro 1 cm2 Elektrodenfläche beträgt bei 25°C 38 A/g. Bei einer Kontaktzeit von 1s sinkt der mittlere Strom auf die Hälfte dieses Wertes ab. Ausser den Untersuchungen zur Wasserstoff-Elektrode werden orientierende Versuche zur Reduktion von Sauerstoff und zur Oxydation von Alkohol an magnetischen Stromabnehmerelektroden beschrieben. A cell assembly is described in which finely grained Raney nickel catalyst is brought into contact with an indifferent electrode by magnetic force. The contact can be made continuous or intermittent. This offers a convenient means for the control of the charge transfer at the electrode. The aluminium and hydrogen content of the Raney nickel catalyst has been determined as a function of pre-treatment. Freshly prepared catalyst contains 0·2–0·3 H per 1 Ni, considerably less than prevailing opinion would suggest. The hydrogen exchange proceeds reversibly only up to an overpotential of ca +150 mV. At higher overpotentials oxidation of nickel occurs, followed by inactivation of the catalyst. The formerly described different kinds of hydrogen bound at the surface may partly be explained by different oxidation states of nickel. The hydrogen concentration as function of polarization, the rate of hydrogen uptake and the current of potentiostatic discharge must be known if the process is to be optimized. The initial current at an overpotential of 120 mV with Raney nickel of 42–50 ?m grain size and an electrode coverage with 20 mg catalyst for 1 cm2 is 38 A/g at 25°C. During a contact time of 1 s the average current decreases to one half of the initial current. In addition to the investigations of the hydrogen electrode, preliminary experiments of oxygen reduction and alcohol oxidation at magnet electrodes are described.

F.V. Sturm; G. Richter

1965-01-01T23:59:59.000Z

392

Surface attack on metals in the presence of liquid metals. Final report  

SciTech Connect

A study was undertaken to evaluate liquid metals as electrical collectors in contact with solid metal alloys. Surface attack of the liquid metal on the solid metal is expected to be a major challenge to the development of a credible system. Low-melting-temperature metals and alloys of the fusible type are to be utilized for a collector that will operate in the 200-500 F range, with emphasis towards the lower end. Solid metals have been selected for experimental work based on their electrical properties and minimal potential reaction with the candidate liquid-metal alloys. Material properties of both liquid and solid metals were reviewed to identify initial material combinations for evaluation. Thorough literature searches were conducted to obtain as much pertinent physical-property and metallurgical data as possible, prior to actual experimental work. Process and material modelling was adopted to select candidate materials for both solids and liquids. Consideration of practical requirements for the eventual collectors is an integral part of the study. Work effort has concentrated on apparatus construction, evaluation and a program of testing to obtain screening data on materials selected and the chosen test method. Results have identified limitations of the test unit design and maximum current loads under test conditions with experimental current collectors. Candidate electrode materials have been exposed in low-melting fusible alloys for direct-dissolution data.

Beal, R.E.

1986-04-10T23:59:59.000Z

393

Photoactivated metal removal  

SciTech Connect

The authors propose the use of photochromic dyes as light activated switches to bind and release metal ions. This process, which can be driven by solar energy, can be used in environmental and industrial processes to remove metals from organic and aqueous solutions. Because the metals can be released from the ligands when irradiated with visible light, regeneration of the ligands and concentration of the metals may be easier than with conventional ion exchange resins. Thus, the process has the potential to be less expensive than currently used metal extraction techniques. In this paper, the authors report on their studies of the metal binding of spirogyran dyes and the hydrolytic stability of these dyes. They have prepared a number of spirogyrans and measured their binding constants for calcium and magnesium. They discuss the relationship of the structure of the dyes to their binding strengths. These studies are necessary towards determining the viability of this technique.

Nimlos, M.R.; Filley, J.; Ibrahim, M.A.; Watt, A.S.; Blake, D.M.

1999-07-01T23:59:59.000Z

394

Computational Investigation of the Thermochemistry and Kinetics of Steam Methane Reforming Over a Multi-Faceted Nickel Catalyst  

Science Journals Connector (OSTI)

A microkinetic model of steam methane reforming over a multi-faceted nickel surface using ... on the Ni(100) surface. The primary reforming pathway is predicted to be through C* ... reactions are predicted to be ...

D. Wayne Blaylock; Yi-An Zhu; William H. Green

2011-09-01T23:59:59.000Z

395

Nickel-catalyzed reductive coupling reactions : application to the total syntheses of pumiliotoxins 209F and 251D  

E-Print Network (OSTI)

Catalytic Asymmetric Reductive Coupling of 1,3-Enynes and Aromatic Aldehydes Nickel-catalyzed reductive coupling reactions of 1,3-enynes and aromatic aldehydes efficiently afford conjugated dienols in excellent regioselectivity ...

Woodin, Katrina Sue

2007-01-01T23:59:59.000Z

396

Effect of Specific Energy Input on Microstructure and Mechanical Properties of Nickel-Base Intermetallic Alloy Deposited by Laser Cladding  

Science Journals Connector (OSTI)

This article describes the microstructural features and mechanical properties of nickel-base intermetallic alloy laser-clad layers on stainless steel-316 L ... , with specific attention on the effect of laser-spe...

Reena Awasthi; Santosh Kumar; Kamlesh Chandra…

2012-12-01T23:59:59.000Z

397

CH4 reforming with CO2 for syngas production over nickel catalysts supported on mesoporous nanostructured ?-Al2O3  

Science Journals Connector (OSTI)

Nanostructured ?-Al2O3 with high surface area and mesoporous structure was synthesized by sol-gel method and employed as catalyst support for nickel catalysts in methane reforming with carbon dioxide. The prepare...

Nasrollah Majidian; Narges Habibi; Mehran Rezaei

2014-07-01T23:59:59.000Z

398

The mechanism of hydrogen evolution reaction on a modified Raney nickel composite-coated electrode by AC impedance  

SciTech Connect

The hydrogen evolution reaction (HER) on a modified Raney nickel electrode, consisting of Ni-Al-Cu-Cr alloy, was investigated with ac impedance measurements and by dc polarization current behavior in 5.36 M KOH solution at 70 C. Comparative measurements also were carried out on commercial Raney nickel (Ni-Al). The rate constants of the forward and backward reactions of Volmer, Heyrovsky, and Tafel steps were estimated by a nonlinear fitting method. The modified Raney nickel composite-coated electrode provides a lower overpotential for the HER than the commercial Raney nickel-coated electrode. The main pathway for the HER is Volmer-Tafel with Volmer as the rate determining step.

Okido, M.; Depo, J.K.; Capuano, G.A. (Univ. du Quebec a Montreal (Canada))

1993-01-01T23:59:59.000Z

399

TSNo s02-nachtegaal193236-O Kinetics and Mechanisms of Nickel Sorption to a Goethite-Coated Kaolinite  

E-Print Network (OSTI)

TSNo s02-nachtegaal193236-O Title Kinetics and Mechanisms of Nickel Sorption to a Goethite- Coated with goethite. Kaolinite was coated with increasing amounts of goethite and characterized via SEM, XRD, and XPS

Sparks, Donald L.

400

Nickel-and Ruthenium-Doped Lanthanum Chromite Anodes: Effects of Nanoscale Metal Precipitation on Solid Oxide  

E-Print Network (OSTI)

on Solid Oxide Fuel Cell Performance W. Kobsiriphat,* B. D. Madsen, Y. Wang, M. Shah, L. D. Marks, and S. A characterization and electrochemical measurements in solid oxide fuel cells SOFCs . Transmission electron. Nanometer-scale electrode structures in solid oxide fuel cells SOFCs have the potential to yield improved

Marks, Laurence D.

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Do trace metals (chromium, copper, and nickel) influence toxicity of diesel fuel for free-living marine nematodes?  

Science Journals Connector (OSTI)

The objective of this study was to test the hypotheses that (1) free-living marine nematodes respond in a differential way to diesel fuel if it is combined with three trace ... (2) the magnitude of toxicity of di...

Amor Hedfi; Fehmi Boufahja; Manel Ben Ali…

2013-06-01T23:59:59.000Z

402

Metal atomization spray nozzle  

DOE Patents (OSTI)

A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

Huxford, T.J.

1993-11-16T23:59:59.000Z

403

Facility Type!  

Office of Legacy Management (LM)

ITY: ITY: --&L~ ----------- srct-r~ -----------~------~------- if yee, date contacted ------------- cl Facility Type! i I 0 Theoretical Studies Cl Sample 84 Analysis ] Production 1 Diepasal/Storage 'YPE OF CONTRACT .--------------- 1 Prime J Subcontract&- 1 Purchase Order rl i '1 ! Other information (i.e., ---------~---~--~-------- :ontrait/Pirchaee Order # , I C -qXlJ- --~-------~~-------~~~~~~ I I ~~~---~~~~~~~T~~~ FONTRACTING PERIODi IWNERSHIP: ,I 1 AECIMED AECMED GOVT GOUT &NTtiAC+OR GUN-I OWNED ----- LEEE!? M!s LE!Ps2 -LdJG?- ---L .ANDS ILJILDINGS X2UIPilENT IRE OR RAW HA-I-L :INAL PRODUCT IASTE Z. RESIDUE I I kility l pt I ,-- 7- ,+- &!d,, ' IN&"E~:EW AT SITE -' ---------------- , . Control 0 AEC/tlED managed operations

404

Fabricated Metals (2010 MECS)  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Fabricated Metals Sector (NAICS 332) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014

405

EMSL - trace metals  

NLE Websites -- All DOE Office Websites (Extended Search)

trace-metals en Microbial Reductive Transformation of Phyllosilicate Fe(III) and U(VI) in Fluvial Subsurface Sediments. http:www.emsl.pnl.govemslwebpublications...

406

Heavy metals in the eastern oyster, Crassostrea virginica, of the Mississippi Sound  

SciTech Connect

Levels of metals in oysters in the Sound are of profound interest not only because they document those geographic areas where metal pollution levels may be problematic but because they may disclose possible problems to consumers of oysters. At the present time objective federal standards for heavy metals in oysters and other seafood are restricted to mercury. The closure of Mississippi oyster reefs has been predicated upon bacteriological standards with little if any attention paid to heavy metals. A study of fourteen metals in oysters of the Sound was began in 1988 with objectives differing from that of the Status and Trends Program (STP) in three ways. STP levels are reported on dry weight basis of composites from three sites. In the present study, oysters were analyzed and reported on wet weight basis. Additionally analyses were made of individual specimens to indicate expected specimen to specimen variations and were conducted on oysters from the three STP and two other important oyster reef sites. In the future three or more additional sites will be added to this continuing survey effort. Metals chosen for this study were lead (Pb), cadmium (Cd), iron (Fe), copper (Cu), cobalt (Co), manganese (Mn), zinc (Zn), silver (Ag), nickel (Ni), mercury (Hg), aluminum (Al), chromium (Cr), molybdenum (Mo), and vanadium (V).

Lytle, T.F.; Lytle, J.S. (Gulf Coast Research Lab., Ocean Springs, MS (USA))

1990-01-01T23:59:59.000Z

407

Influence of Cobalt Nanoparticles’ Incorporation on the Magnetic Properties of the Nickel Nanofibers: Cobalt-Doped Nickel Nanofibers Prepared by Electrospinning  

Science Journals Connector (OSTI)

Nickel(II) acetate tetrahydrate (Ni(AOc), 98%) and poly(vinyl alcohol) (PVA, molecular weight (MW) = 65?000 g/mol) were obtained from Showa Co., Japan and Aldrich Co., USA, respectively. ... In this study, three mixtures have been individually electrospun; Ni(AOc)/PVA, Co nanoparticles/PVA, and Co nanoparticles/Ni(AOc)/PVA. A PVA aqueous solution (10 wt %) was utilized in all mixtures. ... Briefly, Ni(AOc)/PVA sol?gel was prepared by mixing of aqueous Ni(AOc) solution (20 wt %) and the prepared PVA solution in a weight ratio of 1:3. ...

Nasser A. M. Barakat; Bongsoo Kim; Chuan Yi; Younghun Jo; Myung-Hwa Jung; Kong Hee Chu; Hak Yong Kim

2009-10-19T23:59:59.000Z

408

Structural Basis for Metal Binding Specificity: the N-terminal Cadmium Binding Domain of the  

E-Print Network (OSTI)

In bacteria, P1-type ATPases are responsible for resistance to di- and monovalent toxic heavy metals by taking years and no common mechanism for resistance toward toxic heavy metals such as Cd(II), Zn(II), HgStructural Basis for Metal Binding Specificity: the N-terminal Cadmium Binding Domain of the P1

Scott, Robert A.

409

Metal precipitation at grain boundaries in silicon: Dependence on grain boundary character and dislocation decoration  

E-Print Network (OSTI)

are combined to determine the dependence of metal silicide precipitate formation on grain boundary character and microstructure in multicrystalline silicon mc-Si . Metal silicide precipitate decoration is observed to increase the local metal silicide precipitate concentrations at various types of grain boundaries, identifying clear

410

Mixed Metal Films with Switchable Optical Properties  

NLE Websites -- All DOE Office Websites (Extended Search)

Mixed Metal Films with Switchable Optical Properties Mixed Metal Films with Switchable Optical Properties Title Mixed Metal Films with Switchable Optical Properties Publication Type Journal Article LBNL Report Number LBNL-49043 Year of Publication 2001 Authors Richardson, Thomas J., Jonathan L. Slack, Baker Farangis, and Michael D. Rubin Journal Applied Physics Letters Volume 80 Pagination 1349-1351 Call Number LBNL-49043 Abstract Thin, Pd-capped metallic films containing magnesium and first row transition metals (Mn, Fe, Co) switch reversibly from their initial reflecting state to visually transparent states when exposed to gaseous hydrogen or following reduction cathodic polarization in an alkaline electrolyte. Reversion to the reflecting state is achieved by exposure to air or by anodic polarization. The films were prepared by co-sputtering from one magnesium target and one manganese, iron, or cobalt target. Both the dynamic optical switching range and the speed of the transition depend on the magnesium-transition metal ratio. Infrared spectra of films in the transparent, hydrided (deuterided) states support the presence of the intermetallic hydride phases Mg3MnH7, Mg2FeH6, and Mg2CoH5.

411

Silicon metal-semiconductor-metal photodetector  

DOE Patents (OSTI)

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1997-01-01T23:59:59.000Z

412

Silicon metal-semiconductor-metal photodetector  

DOE Patents (OSTI)

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1995-01-01T23:59:59.000Z

413

Symmetry reduction of metal phthalocyanines on metals  

Science Journals Connector (OSTI)

The temperature-dependent adsorption behavior of fourfold symmetric metal phthalocyanines (MPcs) on metals with commensurate and incommensurate symmetries was investigated by scanning tunneling microscopy. On the fourfold symmetric Cu(100) surface, planar and fourfold molecular structures in two equivalent orientations were found for MPcs when prepared at room temperature. In addition, two metastable orientations were identified when prepared at low temperature, which can be depopulated upon annealing. MPcs adsorbed on the sixfold symmetric Cu(111) surface showed a disturbed molecular appearance. The symmetry of molecular structures changed from fourfold to twofold, which is discussed in terms of molecule-substrate interaction.

Shih-Hsin Chang; Stefan Kuck; Jens Brede; Leonid Lichtenstein; Germar Hoffmann; Roland Wiesendanger

2008-12-29T23:59:59.000Z

414

X-ray resonant exchange scattering of rare-earth nickel borocarbides  

SciTech Connect

The purpose of this thesis is to investigate the systematics of the microscopic magnetic order within a series of isostructural compounds and, at the same, to develop the relatively young experimental method of x-ray resonant exchange scattering (XRES). In this thesis, the author presents XRES studies of several rare-earth nickel borocarbides, RNi{sub 2}B{sub 2}C. He shows that XRES, similar to the neutron techniques, allows the determination of the orientation of the magnetic moment by measuring the Q-dependence of the scattered intensity of magnetic Bragg reflections. As samples in this study, he chose the recently discovered family of rare-earth nickel borocarbides, RNi{sub 2}B{sub 2}C, which display a wide variety of magnetic structures. Furthermore, in several of these materials, long range magnetic order coexists with superconductivity over some temperature range.

Detlefs, C.

1997-10-08T23:59:59.000Z

415

Effect of Sintering Temperature on Dielectric Properties of Iron Deficient Nickel-Ferrite  

SciTech Connect

Nickel Ferrite among all the magneto ceramic materials have been studied very much due to its large number of applications. But there is a large scope of modification of its properties. Thus people still working on it for improvisation of its properties via compositional and structural modifications. Present paper reporting the preparation and characterization of iron deficient Nickel ferrite for different sintering temperature. Ferrite samples having the general formula NiFe1.98O{sub 4} were prepared using the standard ceramic method. The phase formation was confirmed by X-ray diffraction technique. The effect of sintering temperature on the electrical properties and resistivity was studied. The data shows that dielectric properties are highly dependent on the sintering temperature.

Rani, Renu [Electroceramics Research Lab, GVM Girls College, Sonepat-131001 (India); School of Physics and Material Science, Thapar University, Patiala-147004 (India); Singh, Sangeeta [Department of Physics, GVM Girls College, Sonepat-131001 (India); Juneja, J. K. [Department of Physics, Hindu College, Sonepat-131001 (India); Prakash, Chandra [Directorate of ER and IPR, DRDO, DRDO Bhawan, New Delhi-110105 (India); Raina, K. K. [School of Physics and Material Science, Thapar University, Patiala-147004 (India)

2011-11-22T23:59:59.000Z

416

Synthesis, characterization, and reactivity of pentamethylcyclopentadienyl complexes of divalent cobalt and nickel  

SciTech Connect

The thesis is divided into the following 4 chapters: synthesis, characterization, and reactivity of trinuclear pentamethylcyclopentadienyl cobalt and nickel clusters with triply-bridging methylidyne groups; chemical and physical properties of pentamethylcyclopentadienyl acetylacetonate complexes of Co(II) and Ni(II); synthesis, characterization, and reactivity of pentamethylcyclopentadienyl halide complexes of Co and Ni; and crystallographic studies of distortions in metallocenes with C{sub 5}-symmetrical cyclopentadienyl rings.

Smith, M.E.

1993-10-01T23:59:59.000Z

417

Coupling the nickel-iodine-sulphur cycle with a nuclear reactor  

Science Journals Connector (OSTI)

Nuclear hydrogen production is a technically feasible and economically viable option for addressing future energy needs. Several projects have been started on the co-generation of hydrogen and electricity from nuclear energy. In this report, the nickel sulphur iodine (NIS) cycle, a thermochemical water splitting cycle originally developed in ENEA for solar hydrogen production, was studied to be coupled with a new generation nuclear reactor for massive hydrogen production.

Pier Paolo Prosini

2013-01-01T23:59:59.000Z

418

Resonantly photo-pumped nickel-like erbium X-ray laser  

DOE Patents (OSTI)

A resonantly photo-pumped X-ray laser (10) that enhances the gain of seve laser lines that also lase because of collisional excitations and recombination processes, is described. The laser comprises an aluminum (12) and erbium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state nickel-like erbium ions (34) are resonantly photo-pumped by line emission from hydrogen-like aluminum ions (32).

Nilsen, Joseph (Livermore, CA)

1990-01-01T23:59:59.000Z

419

Sorption Speciation of Nickel(II) onto Ca-Montmorillonite: Batch, EXAFS Techniques and Modeling  

E-Print Network (OSTI)

1 Sorption Speciation of Nickel(II) onto Ca-Montmorillonite: Batch, EXAFS Techniques and Modeling, 44307 Nantes cedex 03, France The sorption speciation of Ni(II) on Ca-montmorillonite was evaluated(II) sorption as well as the local atomic structure of the adsorbed Ni(II) ions. At 0.001 mol/L Ca(NO3)2 and low

Paris-Sud XI, UniversitƩ de

420

[Bis(diphenylphosphino)alkane](pentane-2,4-dithionato) complexes of nickel(II)  

Science Journals Connector (OSTI)

The structures of three four-coordinate nickel(II) complexes of the form [Ni(sacsac)(L)]PF6 [sacsac is the pentane-2,4-dithione anion; L = Ph2P(CH2)nPPh2, where n = 1, 2 or 3] have been determined. All have a distorted square-planar arrangement about the Ni atom, with angles varying with the length of the hydrocarbon chain.

Boyd, P.D.W.

2000-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

SOPHIE velocimetry of Kepler transit candidates. XV. KOI-614b, KOI-206b, and KOI-680b: a massive warm Jupiter orbiting a G0 metallic dwarf and two highly inflated planets with a distant companion around evolved F-type stars  

E-Print Network (OSTI)

We report the validation and characterization of three new transiting exoplanets using SOPHIE radial velocities: KOI-614b, KOI-206b, and KOI-680b. KOI-614b has a mass of $2.86\\pm0.35~{\\rm M_{Jup}}$ and a radius of $1.13^{+0.26}_{-0.18}~{\\rm R_{Jup}}$, and it orbits a G0, metallic ([Fe/H]=$0.35\\pm0.15$) dwarf in 12.9 days. Its mass and radius are familiar and compatible with standard planetary evolution models, so it is one of the few known transiting planets in this mass range to have an orbital period over ten days. With an equilibrium temperature of $T_{eq}=1000 \\pm 45$ K, this places KOI-614b at the transition between what is usually referred to as "hot" and "warm" Jupiters. KOI-206b has a mass of $2.82\\pm 0.52~{\\rm M_{Jup}}$ and a radius of $1.45\\pm0.16~{\\rm R_{Jup}}$, and it orbits a slightly evolved F7-type star in a 5.3-day orbit. It is a massive inflated hot Jupiter that is particularly challenging for planetary models because it requires unusually large amounts of additional dissipated energy in the ...

Almenara, J M; Bouchy, F; Havel, M; Bruno, G; Hébrard, G; Diaz, R F; Deleuil, M; Barros, S C C; Boisse, I; Bonomo, A; Montagnier, G; Santerne, A

2015-01-01T23:59:59.000Z

422

Metallization of fluid hydrogen  

Science Journals Connector (OSTI)

...P. Tunstall Metallization of fluid hydrogen W. J. Nellis 1 A. A. Louis 2 N...The electrical resistivity of liquid hydrogen has been measured at the high dynamic...which structural changes are paramount. hydrogen|metallization of hydrogen|liquid...

1998-01-01T23:59:59.000Z

423

Electroreflectance in Metals  

Science Journals Connector (OSTI)

Calculations have been made which suggest that the prominent maximum in the electroreflectance spectra of metals observed by Feinleib is not due to modulation of the optical constants of the electrolyte, but to modulation of the optical constants of the metal.

Arnold Prostak and Wilford N. Hansen

1967-08-15T23:59:59.000Z

424

Single crystal Processing and magnetic properties of gadolinium nickel  

SciTech Connect

GdNi is a rare earth intermetallic material that exhibits very interesting magnetic properties. Spontaneous magnetostriction occurs in GdNi at T{sub C}, on the order of 8000ppm strain along the c-axis and only until very recently the mechanism causing this giant magnetostriction was not understood. In order to learn more about the electronic and magnetic structure of GdNi, single crystals are required for anisotropic magnetic property measurements. Single crystal processing is quite challenging for GdNi though since the rare-earth transition-metal composition yields a very reactive intermetallic compound. Many crystal growth methods are pursued in this study including crucible free methods, precipitation growths, and specially developed Bridgman crucibles. A plasma-sprayed Gd{sub 2}O{sub 3} W-backed Bridgman crucible was found to be the best means of GdNi single crystal processing. With a source of high-quality single crystals, many magnetization measurements were collected to reveal the magnetic structure of GdNi. Heat capacity and the magnetocaloric effect are also measured on a single crystal sample. The result is a thorough report on high quality single crystal processing and the magnetic properties of GdNi.

Shreve, Andrew John [Ames Laboratory

2012-11-02T23:59:59.000Z

425

Production of magnesium metal  

SciTech Connect

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

2010-02-23T23:59:59.000Z

426

Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-diene dithiocyanate with nickel (II) acetate  

SciTech Connect

The complexation of nickel acetate with tetraaza involves deprotonation of protonated amine nitrogen to form neutral ligand coordinated to the nickel via the four nitrogen atom. The dication complex is paired with thiocyanate anions. The complex was characterized by elemental analysis, UV-VIS and FTIR spectroscopic method. The crystal structure of nickel complex characterized by X-Ray crystallography and adopts square planar geometry.

Ishak, Nur Iliyani Mohd; Yamin, Bohari M. [Department of Chemistry, Faculty of Science and Technology, UniversitiKebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

2013-11-27T23:59:59.000Z

427

Metal-Nonmetal Transition in Metal-Ammonia Solutions  

Science Journals Connector (OSTI)

A review is given of the properties of metal-ammonia solutions together with a summary of the evidence for the existence of a metal-nonmetal transition.

J. C. THOMPSON

1968-10-01T23:59:59.000Z

428

Removal and recovery of metal ions from process and waste streams using polymer filtration  

SciTech Connect

Polymer Filtration (PF) is an innovative, selective metal removal technology. Chelating, water-soluble polymers are used to selectively bind the desired metal ions and ultrafiltration is used to concentrate the polymer-metal complex producing a permeate with low levels of the targeted metal ion. When applied to the treatment of industrial metal-bearing aqueous process streams, the permeate water can often be reused within the process and the metal ions reclaimed. This technology is applicable to many types of industrial aqueous streams with widely varying chemistries. Application of PF to aqueous streams from nuclear materials processing and electroplating operations will be described.

Jarvinen, G.D.; Smith, B.F.; Robison, T.W.; Kraus, K.M.; Thompson, J.A.

1999-06-13T23:59:59.000Z

429

Fuel assembly transfer basket for pool type nuclear reactor vessels  

DOE Patents (OSTI)

A fuel assembly transfer basket for a pool type, liquid metal cooled nuclear reactor having a side access loading and unloading port for receiving and relinquishing fuel assemblies during transfer.

Fanning, Alan W. (San Jose, CA); Ramsour, Nicholas L. (San Jose, CA)

1991-01-01T23:59:59.000Z

430

Toxic Metal Fumes from Mantle-Type Camp Lanterns  

Science Journals Connector (OSTI)

...ed from two separate sites (Camp Century and a "virgin site"), they...analyzed ice core samples from Camp Century (770 1O'N, 61008'W) and...Date Mercury (in) (ng/liter) Camp Century 56.94 1850 13 10 Site 2 54...

Kyle Griggs

1973-08-31T23:59:59.000Z

431

Ohmic contact metallization on p-type indium phosphide  

E-Print Network (OSTI)

contact resistivities comparable to those of Au-based contacts, determined by the Cox and Strack structure, can be obtained for a pure Pd contact on p-InP (hole concentration -3xlOl' cm-'). The defects can be identified to be related with phosphorus...

Park, Moonho

1993-01-01T23:59:59.000Z

432

WeldingFabr&MetalForm  

NLE Websites -- All DOE Office Websites (Extended Search)

Welding, Welding, Fabrication, and Metal Forming Manufacturing Technologies The department consists of three trades: weld- ing; fabrication and assembly; and precision metal forming. These interrelated groups use similar equipment and rely on each other's skills. One stop will get you the service of three reliable trades. The team manufactures and assembles proto- type hardware and has the in-house capability of producing hardware with sizes ranging from thumbnail to rail-car. Expertise includes aircraft quality sheet metal construction, certified weld- ing, and assembly. The staff has experience managing a variety of activities: design modifi- cation assistance; in-house fabrication; and project management and can work with your engineers to transform sketches and ideas into working prototypes.

433

Liquid metal electric pump  

DOE Patents (OSTI)

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

434

Simple test for dissimilar-metal welds  

SciTech Connect

A simplified accelerated test procedure has been developed for testing dissimilar-metal welds between austenitic stainless steels and low-alloy ferritic steels. The failure of these welded joints in operating steam generators of fossil-fired power plants has become an increasing problem for the utility industry. The proposed test is a three-point loading, bent-beam test that uses sheet specimens taken from a dissimilar-metal weldment. Tests were conducted in a simple test fixture where the specimens are loaded with a set-screw. To determine whether the test produces the same type of failure as those produced in a power plant, tests were conducted on specimens taken from a weld between Type 316 stainless steel and 2 1/4 Cr-1 Mo steel plates using Type 309 stainless steel filler metal. The specimens were loaded in the test fixture at room temperature and then thermally cycled between room temperature and 593/sup 0/C (1099/sup 0/F) by placing the test apparatus in a box furnace (thermal cycling during power plant operation plays a major role in the weld failure during service). The specimens were kept in the furnace for 20 to 70 hours (h), cooled to room temperature, and then the cycle was repeated. Metallographic examination of specimens cycled as few as 64 times with a total of 2300 h at 593/sup 0/C revealed that the specimens contained cracks similar to the cracks observed on dissimilar-metal welds cut from steam tubes after long-time elevated-temperature service racks similar to the cracks observed on dissimilar-metal welds cut from steam tubes after longtime elevated-temperature service in a fossil-fired steam generator. All indications are that this simple accelerated test could be used as a screening procedure to compare the relative behavior of ''improved'' welds in future research and development programs.

Klueh, R.L.; King, J.F.; Griffith, J.L.

1983-06-01T23:59:59.000Z

435

Divalent metal nanoparticles  

E-Print Network (OSTI)

Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a ...

DeVries, Gretchen Anne

2008-01-01T23:59:59.000Z

436

Nitrided Metallic Bipolar Plates  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

to meet 5000 h automotive durability goal at cost < 5kW Year 1 Goals: Single-cell fuel cell test performance for 25 cm 2 stamped and nitrided metallic bipolar plates...

437

Metal stocks and sustainability  

Science Journals Connector (OSTI)

...dissipated through corrosion and wear, and some enters waste repositories...landfills. Dissipation from wear and corrosion is generally small...dispersion of metals from wear and corrosion is an important...transportation (railroad, marine, aircraft, and aerospace equipment...

R. B. Gordon; M. Bertram; T. E. Graedel

2006-01-01T23:59:59.000Z

438

Oligocyclopentadienyl transition metal complexes  

SciTech Connect

Synthesis, characterization, and reactivity studies of oligocyclopentadienyl transition metal complexes, namely those of fulvalene, tercyclopentadienyl, quatercyclopentadienyl, and pentacyclopentadienyl(cyclopentadienyl) are the subject of this account. Thermal-, photo-, and redox chemistries of homo- and heteropolynuclear complexes are described.

de Azevedo, Cristina G.; Vollhardt, K. Peter C.

2002-01-18T23:59:59.000Z

439

Excitons in Metals  

Science Journals Connector (OSTI)

It is shown that exciton states exist in metals, occurring near the interband threshold in optical absorption and substantially altering the shape and strength of the absorption edge. Their relation to the corresponding donor states is discussed.

G. D. Mahan

1967-03-20T23:59:59.000Z

440

Lithium metal reduction of plutonium oxide to produce plutonium metal  

DOE Patents (OSTI)

A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

Coops, Melvin S. (Livermore, CA)

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Molten metal reactors  

DOE Patents (OSTI)

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

2013-11-05T23:59:59.000Z

442

Interfacial characterization of nickel–yttria-stabilized zirconia cermet anode/interconnect joints with Ag–Pd–Ga active filler for use in solid-oxide fuel cells  

Science Journals Connector (OSTI)

Abstract Nickel–yttria-stabilized zirconia cermet anode (Ni–YSZ)/interconnect joints with silver–palladium–gallium (Ag–9Pd–9Ga) active fillers are prepared by vacuum brazing. The joint structure and microstructure are analyzed by X-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS), and by using an electron probe microanalyzer (EPMA). SEM observations of the joint show no cracks near the interface, confirming the compatibility of the Ag–9Pd–9Ga filler with a different anode and interconnect. The XRD pattern of the joint specimens oxidized at 800 °C for 250 h shows Cr2O3 and (Mn,Cr)3O4 surface layers. EPMA analysis of the cell/Ag–9Pd–9Ga/alloys joint at the cross section shows Cr, O, Fe, Zr, Ni, Ag, Pd, Ga, Y, and Mn. Overall, the results indicate that the bonding between metal and cermet is well established and the interface is smooth. By correlating the XRD and EPMA analysis results, we also analyzed the possible stages during joint oxidation. The joint strength was evaluated at 25 and 800 °C under shear and tensile loading conditions, respectively, and the brazed Ag–9Pd–9Ga sealant compared favorably with the commercially available glass-ceramic GC-9 counterpart.

Chih-Long Chao; Chun-Lin Chu; Yiin-Kuen Fuh; Ray-Quen Hsu; Shyong Lee; Yung-Neng Cheng

2014-01-01T23:59:59.000Z

443

Functionalized Silicone Nanospheres: Synthesis, Transition Metal...  

NLE Websites -- All DOE Office Websites (Extended Search)

Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

444

Metal concentrations in selected tissues and main prey species of the annulated sea snake (Hydrophis cyanocinctus) in the Hara Protected Area, northeastern coast of the Persian Gulf, Iran  

Science Journals Connector (OSTI)

This study is the first detailed ecotoxicological study of the annulated sea snake, Hydrophis cyanocinctus. Concentrations of lead, cadmium, nickel and vanadium were evaluated in muscle, liver, kidney, skin and blood of the annulated sea snake (H. cyanocinctus) and in the whole bodies of its main prey species (Periophthalmus waltoni and Boleophthalmus dussumieri) in the Hara Protected Area, the Persian Gulf. The mean concentrations of lead and vanadium were highest in the kidney, which identified the kidney as a target organ for metals in sea snakes as it is in other reptilian groups. Mean concentrations of cadmium and nickel were highest in the liver and skin, respectively. Mean cadmium concentrations were significantly higher in the liver compared to prey species, which indicated that prey items may be a source of cadmium for the annulated sea snake in the study area. Data presented here may be considered as a baseline for further ecotoxicological studies in sea snakes.

Mohsen Rezaie-Atagholipour; Alireza Riyahi-Bakhtiari; Mirmasoud Sajjadi; Chee Kong Yap; Sanaz Ghaffari; Zohreh Ebrahimi-Sirizi; Parviz Ghezellou

2012-01-01T23:59:59.000Z

445

Effect of hydrogen sulfide on chemical looping of coal-derived synthesis gas over bentonite-supported metal---oxide oxygen carriers  

SciTech Connect

The effect of hydrogen sulfide (H2S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxidesssuch as iron oxide, nickel oxide, manganese oxide, and copper oxideswas investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H2S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H2S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H2S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation decreased in the presence of H2S for all four metal oxides.

Tian, H.; Simonyi, T.; Poston, J.; Siriwardane, R.

2009-01-01T23:59:59.000Z

446

Effect of hydrogen sulfide on chemical looping combustion of coal-derived synthesis gas over bentonite-supported metal-oxide oxygen carriers  

SciTech Connect

The effect of hydrogen sulfide (H{sub 2}S) on the chemical looping combustion of coal-derived synthesis gas with bentonite-supported metal oxides - such as iron oxide, nickel oxide, manganese oxide, and copper oxide - was investigated by thermogravimetric analysis, mass spectrometry, and X-ray photoelectron spectroscopy (XPS). During the reaction with synthesis gas containing H{sub 2}S, metal-oxide oxygen carriers were first reduced by carbon monoxide and hydrogen, and then interacted with H{sub 2}S to form metal sulfide, which resulted in a weight gain during the reduction/sulfidation step. The reduced/sulfurized compounds could be regenerated to form sulfur dioxide and oxides during the oxidation reaction with air. The reduction/oxidation capacities of iron oxide and nickel oxide were not affected by the presence of H{sub 2}S, but both manganese oxide and copper oxide showed decreased reduction/oxidation capacities. However, the rates of reduction and oxidation decreased in the presence of H{sub 2}S for all four metal oxides.

Tian, H.J.; Simonyi, T.; Poston, J.; Siriwardane, R. [US DOE, Morgantown, WV (United States). National Energy Technology Laboratory

2009-09-15T23:59:59.000Z

447

C-H vs C-C Bond Activation of Acetonitrile and Benzonitrile via Oxidative Addition: Rhodium vs Nickel and Cp* vs Tp  

E-Print Network (OSTI)

Nickel and Cp* vs Tp (Tp ) Hydrotris(3,5-dimethylpyrazol-1-yl)borate, Cp* ) 5 interaction with the rhodium center. Reactions of acetonitrile and benzonitrile with the fragment [Tp of acetonitrile on nickel(II) using potassium tert- butoxide.6 In contrast, the fragment [Tp

Jones, William D.

448

Composites Part B: Engineering, 2011, 42(4): p. 916-925 Analysis of active cooling through nickel coated carbon fibers in the solidification  

E-Print Network (OSTI)

nickel coated carbon fibers in the solidification processing of aluminum matrix composites Nikhil Gupta1 cooling through reinforcing carbon fibers to obtain better control over the solidification microstructure and Ni represent the aluminum melt, carbon fiber, and nickel coating, respectively. 1 INTRODUCTION

Gupta, Nikhil

449

Hydrogen transport in nickel ,,111... Department of Physical Chemistry and the Fritz Haber Research Center, The Hebrew University, Jerusalem 91904, Israel  

E-Print Network (OSTI)

Hydrogen transport in nickel ,,111... Roi Baer Department of Physical Chemistry and the Fritz Haber Received 13 November 1996; revised manuscript received 21 January 1997 The intricate dynamics of hydrogen of subsurface with surface hydrogen on the nickel host. The analysis is based on the embedded diatomics

Zeiri, Yehuda

450

Sequential-ion-implantation synthesis of ternary metal silicides  

SciTech Connect

By implanting two different metals in sequence into Si(100), we find that new ternary silicides can by synthesized with simple binary silicide structures. The synthesis of CoSi[sub 2]-type (Co,Fe)Si[sub 2], and CoSi-type (Co,Fe)Si and (Fe,Ni)Si is demonstrated. The structure is largely determined by the first implanted metal and the total dose of the two metals, allowing one to design the structure of the ternary silicide. The two implanted species occupy equivalent positions in the same structure and the metal composition may be continuously varied in a given structure. This opens new possibilities for the synthesis of ternary and multinary compounds and alloys.

Tan, Z. (Brookhaven National Laboratory, Upton, New York 11973 (United States)); Namavar, F. (Spire Corporation, Bedford, Massachusetts 01730-2396 (United States)); Heald, S.M. (Brookhaven National Laboratory, Upton, New York 11973 (United States)); Budnick, J.I. (Physics Department and Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269-3046 (United States))

1993-08-09T23:59:59.000Z

451

Liquid metal thermal electric converter  

DOE Patents (OSTI)

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

452

Synthesis, characterization and properties of anti-sintering nickel incorporated MCM-41 methanation catalysts  

Science Journals Connector (OSTI)

Abstract Several nickel incorporated MCM-41 catalysts with a nickel molar content from 1% to 10% were prepared by a hydrothermal synthesis method, and investigated for their catalytic performances for the production of substitute natural gas (SNG) from syngas methanation in a continuous flow fixed-bed reactor. The catalysts were characterized by FTIR, ICP, XRD, H2-TPR, TG–DTA and TEM, and the results showed that the mesoporous structure of MCM-41 still maintained well when the incorporated Ni molar content was up to 10%. The Ni–M catalyst prepared by the hydrothermal synthesis method with a nickel molar content of 10% showed the best catalytic activity with a high CO conversion of almost 100%, and a CH4 yield of 95.7% at 350 °C with 3:1 molar ratio of H2 to CO under 1.0 MPa and 12000 ml/h/g. Compared with the 10%Ni/M catalyst prepared by the impregnation method, the 10%Ni–M catalyst showed a higher resistance to sintering and no decrease in catalytic activity after calcination at 700 °C for 2 h. In the 100 h stability test under atmospheric pressure, the CO conversion rate and the CH4 yield obtained on 10%Ni–M catalyst maintained at about 100% and 82%, respectively, suggesting an excellent catalytic stability of this catalyst. The results of XRD, H2-TPR and TG–DTA showed that there was a strong interaction between the Ni species and the support, which inhibited the catalyst sintering. And the amount of coke formed on the spent 10%Ni–M catalyst in the stability test was 3.0 wt%. The coke formation was relatively easily to remove by calcination because the deposited carbon had a small particle size and uniform dispersion on the catalyst.

Jiaying Zhang; Zhong Xin; Xin Meng; Miao Tao

2013-01-01T23:59:59.000Z

453

Comparison of the structural and chemical composition of two unique micro/nanostructures produced by femtosecond laser interactions on nickel  

SciTech Connect

The structural and chemical composition of two unique microstructures formed on nickel, with nanoscale features, produced using femtosecond laser surface processing (FLSP) techniques is reported in this paper. These two surface morphologies, termed mounds and nanoparticle-covered pyramids, are part of a larger class of self-organized micro/nanostructured surfaces formed using FLSP. Cross-sections of the structures produced using focused ion beam milling techniques were analyzed with a transmission electron microscope. Both morphologies have a solid core with a layer of nanoparticles on the surface. Energy dispersive X-ray spectroscopy by scanning transmission electron microscopy studies reveal that the nanoparticles are a nickel oxide, while the core material is pure nickel.

Zuhlke, Craig A.; Anderson, Troy P.; Alexander, Dennis R. [Department of Electrical Engineering, University of Nebraska-Lincoln, Lincoln, Nebraska 68588 (United States)] [Department of Electrical Engineering, University of Nebraska-Lincoln, Lincoln, Nebraska 68588 (United States)

2013-09-16T23:59:59.000Z

454

Ultra-thin ohmic contacts for p-type nitride light emitting devices  

DOE Patents (OSTI)

A semiconductor based Light Emitting Device (LED) can include a p-type nitride layer and a metal ohmic contact, on the p-type nitride layer. The metal ohmic contact can have an average thickness of less than about 25 .ANG. and a specific contact resistivity less than about 10.sup.-3 ohm-cm.sup.2.

Raffetto, Mark (Raleigh, NC); Bharathan, Jayesh (Cary, NC); Haberern, Kevin (Cary, NC); Bergmann, Michael (Chapel Hill, NC); Emerson, David (Chapel Hill, NC); Ibbetson, James (Santa Barbara, CA); Li, Ting (Ventura, CA)

2012-01-03T23:59:59.000Z

455

The reactivity of cesium nickel ferrocyanide towards nitrate and nitrite salts  

SciTech Connect

Beginning in late 1988, the Pacific Northwest Laboratory (PNL) began an experimental program at the request of Westinghouse Hanford Company (WHC) to investigate the effects of temperature on the oxidation reaction between synthetic nickel cesium ferrocyanide (FeCN) and nitrates and nitrites representative of materials present in some of the Hanford single-shell tanks (SSTs). After completing a preliminary series of experiments in 1988, the program was expanded to include five tasks to evaluate the effect of selected compositional and operational parameters on the reaction and explosion temperatures of FeCN and nitrate and/or nitrite mixtures. 10 refs., 4 figs., 6 tabs.

Burger, L.L.; Scheele, R.D.

1991-09-01T23:59:59.000Z

456

Sulfur adsorption on nickel(100) and its effect on carbon monoxide, nitric oxide, and deuterium chemisorption  

SciTech Connect

The adsorption of CO, NO, and D/sub 2/ was studied on clean and sulfided Ni(100) near 100K using Auger electron spectroscopy, thermal desorption spectroscopy, X-ray and ultraviolet photoelectron spectroscopies, and work function change measurements. The evidence suggests that sulfur's effects are predominantly steric in nature. Weak, short-range (approx.4 angstrom) electrostatic effects are also present, due to charge transfer of about 0.04 of an electron from nickel to sulfur. The blocking effect of S on the adsorption of each gas at various temperatures is discussed.

Hardegree, E.L.

1985-01-01T23:59:59.000Z

457

Magnetic shielding properties of plasma sprayed YBa2Cu3O7-x on nickel substrates  

Science Journals Connector (OSTI)

YBa2Cu3O7-x films were grown by a low pressure plasma spraying technique and atmospheric plasma spray on polycrystalline nickel substrate using yttrium-stabilized zirconia as a buffer layer. After post-annealing in oxygen at high temperature, zero resistance is reached above 77 K. YBa2Cu3O7-x films with thicknesses between 120 and 420 ?m were prepared and their critical currents measured. The a.c. magnetic shielding properties were determined in the high frequency region, 100 kHz to 3 MHz. The relations between the screening properties, the critical currents and the microstructure of the thin films are discussed.

D. Castello; J. Fontcuberta; M. Pont; J.S. Muńoz

1992-01-01T23:59:59.000Z

458

Erosion corrosion of copper- and nickel-based alloys in polluted seawater  

SciTech Connect

Erosion corrosion of heat exchanger tubes in warm, flowing Persian Gulf seawater containing up to 5 ppm of sulfide ions is investigated. Tube samples were made of copper (Cu)-nickel (Ni) alloys (90% Cu-10% Ni and 70% Cu-30% Ni), Ni-Cu alloy (UNS N04400), and Ni-based alloys (UNS N06022, N06030, and S32550). Visual and optical examinations of the internal surfaces of the tubes were conducted to compare the susceptibilities to erosion corrosion attack of the different alloys, taking into consideration the nature of the product films formed.

Carew, J.A. [Kuwait Inst. for Scientific Research, Safat (Kuwait); Islam, M. [Cortest Columbus Technologies Inc., Columbus, OH (United States)

1995-04-01T23:59:59.000Z

459

Dissimilar-metal weld failures in boiler tubing  

SciTech Connect

Both ferritic heat-resisting steels and austenitic stainless steels are used for fossil-fired boilers for central power stations. The use of these two different types of materials within the system leads to the need for a dissimilar-metal weld transition joint. Increased cyclic operation of boilers has led to a rash of failures in welds between dissimilar metals; studies have identified the causes, and improved nondestructive testing techniques permit early identification of problem areas.

Klueh, R.L.

1984-02-01T23:59:59.000Z

460

Notice Type: Presolicitation  

E-Print Network (OSTI)

-- Fabricated Metal Product Manufacturing/332996 -- Fabricated Pipe and Pipe Fitting Manufacturing Synopsis Materials. (Microsoft IE required). Additional specifications and opening and closing dates will appear

Note: This page contains sample records for the topic "type nickel metal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

462

Chemically and compositionally modified solid solution disordered multiphase nickel hydroxide positive electrode for alkaline rechargeable electrochemical cells  

DOE Patents (OSTI)

A high capacity, long cycle life positive electrode for use in an alkaline rechargeable electrochemical cell comprising: a solid solution nickel hydroxide material having a multiphase structure that comprises at least one polycrystalline .gamma.-phase including a polycrystalline .gamma.-phase unit cell comprising spacedly disposed plates with at least one chemical modifier incorporated around the plates, the plates having a range of stable intersheet distances corresponding to a 2.sup.+ oxidation state and a 3.5.sup.+, or greater, oxidation state; and at least one compositional modifier incorporated into the solid solution nickel hydroxide material to promote the multiphase structure.

Ovshinsky, Stanford R. (Bloomfield Hills, MI); Corrigan, Dennis (Troy, MI); Venkatesan, Srini (Southfield, MI); Young, Rosa (Troy, MI); Fierro, Christian (Troy, MI); Fetcenko, Michael A. (Rochester Hills, MI)

1994-01-01T23:59:59.000Z

463

Metal rich stars in omega Cen: preliminary FLAMES GTO results  

E-Print Network (OSTI)

I present preliminary results for a sample of ~700 red giants in omega Cen, observed during the Ital-FLAMES Consortium GTO time in May 2003, for the Bologna Project on omega Cen. Preliminary Fe and Ca abundances confirm previous results: while the metal-poor and intermediate populations show a normal halo alpha-enhancement of [alpha/Fe]=$+0.3, the most metal-rich stars show a significantly lower [alpha/Fe]=+0.1. If the metal-rich stars have evolved within the cluster in a process of self-enrichment, the only way to lower their alpha-enhancement would be SNe type Ia intervention.

Pancino, E

2004-01-01T23:59:59.000Z

464

Metal rich stars in omega Cen: preliminary FLAMES GTO results  

E-Print Network (OSTI)

I present preliminary results for a sample of ~700 red giants in omega Cen, observed during the Ital-FLAMES Consortium GTO time in May 2003, for the Bologna Project on omega Cen. Preliminary Fe and Ca abundances confirm previous results: while the metal-poor and intermediate populations show a normal halo alpha-enhancement of [alpha/Fe]=$+0.3, the most metal-rich stars show a significantly lower [alpha/Fe]=+0.1. If the metal-rich stars have evolved within the cluster in a process of self-enrichment, the only way to lower their alpha-enhancement would be SNe type Ia intervention.

E. Pancino

2004-10-28T23:59:59.000Z

465

Abstract No. pan0505 Sorption of Heavy Metal Contaminants onto Hydrated Ferric Oxides: Mechanistic Modeling using X-ray  

E-Print Network (OSTI)

Abstract No. pan0505 Sorption of Heavy Metal Contaminants onto Hydrated Ferric Oxides: Mechanistic. Hence, to understand the mobility and bioavailability of these metal contaminants, these sorption suggesting that sorption of these metal ions onto ferrihydrite can be described by one average type of site

Sparks, Donald L.

466

Bond-order potential for transition metal carbide cluster for the growth simulation of a single-walled carbon nanotube  

E-Print Network (OSTI)

Bond-order potential for transition metal carbide cluster for the growth simulation of a single for transition metal carbide cluster is developed in the form of the bond-order type potential function-order potential; Carbon nanotube; transition metal carbide cluster *Corresponding Author. Fax: +81-3-5841-8653 E

Maruyama, Shigeo

467

Metal alloy identifier  

DOE Patents (OSTI)

To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

Riley, William D. (Avondale, MD); Brown, Jr., Robert D. (Avondale, MD)

1987-01-01T23:59:59.000Z

468

Helium plasma implantation on metals: Nanostructure formation and visible-light photocatalytic response  

SciTech Connect

It has been found recently that low-energy helium (He) plasma irradiation to tungsten (W) leads to the growth of W nanostructures on the surface. The process to grow the nanostructure is identified as a self-growth process of He bubbles and has a potential to open up a new plasma processing method. Here, we show that the metallic nanostructure formation process by the exposure to He plasma can occur in various metals such as, titanium, nickel, iron, and so on. When the irradiation conditions alter, the metallic cone arrays including nanobubbles inside are formed on the surface. Different from W cases, other processes than growth of fiberform structure, i.e., physical sputtering and the growth of large He bubbles, can be dominant on other metals during irradiation; various surface morphology changes can occur. The nanostructured W, part of which was oxidized, has revealed a significant photocatalytic activity under visible light (wavelength >700 nm) in decolorization of methylene blue without any co-catalyst.

Kajita, Shin; Yoshida, Tomoko [EcoTopia Science Institute, Nagoya University, Nagoya 464-8603 (Japan); Kitaoka, Daiki; Etoh, Reo; Yajima, Miyuki; Ohno, Noriyasu; Yoshida, Hisao [Graduate School of Engineering, Nagoya University, Nagoya 464-8603 (Japan); Yoshida, Naoaki [Research Institute for Applied Mechanics, Kyushu University, Fukuoka 816-8580 (Japan); Terao, Yoshitaka [Samsung Yokohama Research Institute (Japan)

2013-04-07T23:59:59.000Z

469

Investigation of nickel supported catalysts for the upgrading of brown peat derived gasification products  

Science Journals Connector (OSTI)

A gasification test rig was designed in which peat was gasified under nitrogen over a temperature range 25–550°C at 5°C min?1. The gasification unit resulted in 35.5 wt% of the carbon present in the peat being converted to a volatile fraction. The volatile fraction was transferred to a secondary catalytic reforming reactor at 800°C. The thermal effect of the second reactor resulted in an increase in the CO, CO2 and CH4 content of the volatile fraction, a syngas ratio of 0.75 and a higher heating value (HHV) of 26.5 MJ kg?1. Several nickel-supported catalysts were investigated with the intention that they should give an increase in the conversion of the condensable hydrocarbons in the volatile fraction to CO, CO2 and CH4, and a resultant gas stream suitable for use in an integrated gasification combined cycle plant (IGCC) (i.e. syngas ratio 2:1, low methane content and better HHV). Alumina-supported nickel catalysts investigated gave the highest activities and co-precipitated Ni/Al catalysts were most active. A Ni/Al 3:17 catalyst increased the conversion of the hydrocarbons to 91.5%, gave a syngas ratio of 1.81:1, increased the HHV by a factor of 5.3 and completely eliminated methane from the gas stream.

David Sutton; Brian Kelleher; Aidan Doyle; J.R.H Ross

2001-01-01T23:59:59.000Z

470

Adsorption and methanation of carbon dioxide on a nickel/silica catalyst  

SciTech Connect

The adsorption and methanation of carbon dioxide on a nickel/silica catalyst were studied using temperature-programmed desorption and temperature-programmed reaction. Carbon dioxide adsorption on nickel was found to be activated; almost no adsorption occurred at room temperature, but large coverages were obtained between 383 and 473 K. The data indicate CO/sub 2/ dissociates upon adsorption at elevated temperatures to yield carbon monoxide and oxygen atoms. These oxygen atoms react with hydrogen at room temperature, so the methane and water observed during programmed heating in flowing hydrogen are identical for adsorbed CO and adsorbed CO/sub 2/. Single CH/sub 4/ and H/sub 2/O peaks, each with a peak temperature at 473 K, were observed. This peak temperature did not change with initial coverage, indicating methanation is first order in CO surface coverage. The activated adsorption of CO/sub 2/ allowed these coverage variation experiments to be carried out. Thus, following adsorption, CO and CO/sub 2/ methanation proceed by the same mechanism. However, the activated adsorption of CO/sub 2/ may create a higher H/sub 2/:CO surface ratio during steady-state hydrogenation, causing CO/sub 2/ hydrogenation to favor methane over higher hydrocarbons. 5 figures.

Falconer, J.L.; Zagli, A.E.

1980-04-01T23:59:59.000Z

471

Reaction of aromatic compounds and coal-derived liquids with steam over alumina supported nickel catalysts  

SciTech Connect

The objective of this research program has been to explore and define the potential of steam reforming to produce light gases from coal-derived liquids. This was achieved through a study of the reaction of a model aromatic compound and of a coal-derived liquid with steam over an alumina supported nickel catalyst. The reaction of steam with benzene and SRC-II liquids over an alumina supported nickel-catalyst has been investigated in a plug flow reactor. The primary process variables investigated were reactor pressure and temperature, contact time, and steam/carbon ratio. A proposed reaction network was also developed to explain the data obtained in this study. The empirical rate equation for the benzene steam reforming reaction at 973 K, 300 psig, and a steam/carbon ratio of approximately 3 was r/sub C6H6/ = 1.92 x 10 TP/sub C6H6/. The activation energy was 88 KJ/mol, or 21 kcal/mol in the temperature range 748-973 K. A correlation was developed to predict product yields and hydrocarbon conversion over the range of process variables investigated. A second correlation was developed to predict the yields and conversion beyond the range of variables investigated.

Chen, I.E.

1985-01-01T23:59:59.000Z

472

Rolling contact fatigue in high vacuum using ion plated nickel-copper-silver solid lubrication  

SciTech Connect

Ion plated, nickel-copper-silver coated steel ball bearings that were tested in rolling contact fatigue (RCF) experiments in high vacuum are presented in this article. ANSI T5 ball bearings were coated with approximately 10 nm of nickel-copper followed by 100 nm of silver using a dc ion plating process. The balls were then tested for RCF in vacuum in the 10{sup -7} Torr range at 130 Hz rotational speed and at 4.1 GPa Hertzian contact stress. The significance of this work is in the extension of RCF testing to an ultrahigh vacuum (UHV) application using silver as a lubricant instead of oil. The effects of pressure and voltage on the ion plating process were also investigated using scanning electron microscopy and RCF life testing in UHV. Test results with a ball size of 5/16 in. in UHV show that deposition at voltages greater than 2.5 kV shortens the RCF life and introduces a unique failure mode. Voltage and pressure fluctuations during the deposition process result in significant thickness monitor measurement errors as well. A regulator control scheme that minimizes the process pressure overshoot is also simulated.

Danyluk, Mike; Dhingra, Anoop [Mechanical Engineering Department, University of Wisconsin-Milwaukee, Milwaukee, Wisconsin 53211-3029 (United States)

2011-01-15T23:59:59.000Z