Sample records for type nickel metal

  1. Revêtements métalliques : Dépôts électrolytiques de nickel Metallic coatings : Electrodeposited coatings of nickel

    E-Print Network [OSTI]

    International Organization for Standardization. Geneva

    2002-01-01T23:59:59.000Z

    Revêtements métalliques : Dépôts électrolytiques de nickel Metallic coatings : Electrodeposited coatings of nickel

  2. Recycle Batteries CSM recycles a variety of battery types including automotive, sealed lead acid, nickel

    E-Print Network [OSTI]

    , nickel cadmium (Nicad), nickel metal hydride, lithium ion, silver button, mercury, magnesium carbon. Recycling rechargeable batteries Rechargeable batteries are often referred to as nickel cadmium, nickel Battery Per Bag Please sort the batteries by battery type, using a separate receptacle for nickel cadmium

  3. Identification of a new pseudo-binary hydroxide during calendar corrosion of (La, Mg)2Ni7-type hydrogen storage alloys for Nickel-Metal Hydride batteries

    E-Print Network [OSTI]

    Boyer, Edmond

    hydrogen storage alloys for Nickel-Metal Hydride batteries J. Monnier 1 , H. Chen 1 , S. Joiret2,3 , J-MH batteries have been extensively studied during calendar storage and cycling [6-8]. In these alloys To improve the performances of Nickel-Metal Hydride batteries, an important step is the understanding

  4. Method for decontamination of nickel-fluoride-coated nickel containing actinide-metal fluorides

    DOE Patents [OSTI]

    Windt, Norman F. (Paducah, KY); Williams, Joe L. (Paducah, KY)

    1983-01-01T23:59:59.000Z

    The invention is a process for decontaminating particulate nickel contaminated with actinide-metal fluorides. In one aspect, the invention comprises contacting nickel-fluoride-coated nickel with gaseous ammonia at a temperature effecting nickel-catalyzed dissociation thereof and effecting hydrogen-reduction of the nickel fluoride. The resulting nickel is heated to form a melt and a slag and to effect transfer of actinide metals from the melt into the slag. The melt and slag are then separated. In another aspect, nickel containing nickel oxide and actinide metals is contacted with ammonia at a temperature effecting nickel-catalyzed dissociation to effect conversion of the nickel oxide to the metal. The resulting nickel is then melted and separated as described. In another aspect nickel-fluoride-coated nickel containing actinide-metal fluorides is contacted with both steam and ammonia. The resulting nickel then is melted and separated as described. The invention is characterized by higher nickel recovery, efficient use of ammonia, a substantial decrease in slag formation and fuming, and a valuable increase in the service life of the furnace liners used for melting.

  5. Metallic coatings: autocatalytic (electroless) nickel-phosphorus alloy coatings: specification and test methods

    E-Print Network [OSTI]

    International Organization for Standardization. Geneva

    2003-01-01T23:59:59.000Z

    Metallic coatings: autocatalytic (electroless) nickel-phosphorus alloy coatings: specification and test methods

  6. Effect of gold-nickel metallization microstructure on fluxless soldering

    SciTech Connect (OSTI)

    Cinque, R.B.; Morris, J.W. Jr. (Lawrence Berkeley Lab., CA (United States) Univ. of California, Berkeley, CA (United States))

    1994-06-01T23:59:59.000Z

    Gold plating is used in the microelectronics industry to maintain the wettability of metal substrates. The nature of wetting during soldering of gold plated metals is discussed, and the results of experiments on the fluxless wettability and oxidation of gold plated nickel are described. The results suggest that electrodeposition of a thin gold plate (0.14 [mu]m) and the concurrent reduction of nickel oxide produce a gold-nickel system which will wet without flux. Oxidation of nickel was observed to occur via nickel out-diffusion and by direct exposure of the substrate through pinhole plating defects. Auger chemical analysis indicates that pinholes do not produce oxidation of the surrounding substrate area. 20 refs., 10 figs.

  7. Filler metal alloy for welding cast nickel aluminide alloys

    DOE Patents [OSTI]

    Santella, Michael L. (Knoxville, TN); Sikka, Vinod K. (Oak Ridge, TN)

    1998-01-01T23:59:59.000Z

    A filler metal alloy used as a filler for welding east nickel aluminide alloys contains from about 15 to about 17 wt. % chromium, from about 4 to about 5 wt. % aluminum, equal to or less than about 1.5 wt. % molybdenum, from about 1 to about 4.5 wt. % zirconium, equal to or less than about 0.01 wt. % yttrium, equal to or less than about 0.01 wt. % boron and the balance nickel. The filler metal alloy is made by melting and casting techniques such as are melting the components of the filler metal alloy and east in copper chill molds.

  8. Filler metal alloy for welding cast nickel aluminide alloys

    DOE Patents [OSTI]

    Santella, M.L.; Sikka, V.K.

    1998-03-10T23:59:59.000Z

    A filler metal alloy used as a filler for welding cast nickel aluminide alloys contains from about 15 to about 17 wt. % chromium, from about 4 to about 5 wt. % aluminum, equal to or less than about 1.5 wt. % molybdenum, from about 1 to about 4.5 wt. % zirconium, equal to or less than about 0.01 wt. % yttrium, equal to or less than about 0.01 wt. % boron and the balance nickel. The filler metal alloy is made by melting and casting techniques such as are melting the components of the filler metal alloy and cast in copper chill molds. 3 figs.

  9. Inhalation carcinogenicity study with nickel metal powder in Wistar rats

    SciTech Connect (OSTI)

    Oller, Adriana R. [NiPERA, 2605 Meridian Parkway, Suite 200, Durham, NC 27713 (United States)], E-mail: aoller@nipera.org; Kirkpatrick, Daniel T.; Radovsky, Ann [WIL Research Laboratories, LLC, 1407 George Road, Ashland, OH 44805 8946 (United States); Bates, Hudson K. [NiPERA, 2605 Meridian Parkway, Suite 200, Durham, NC 27713 (United States)

    2008-12-01T23:59:59.000Z

    Epidemiological studies of nickel refinery workers have demonstrated an association between increased respiratory cancer risk and exposure to certain nickel compounds (later confirmed in animal studies). However, the lack of an association found in epidemiological analyses for nickel metal remained unconfirmed for lack of robust animal inhalation studies. In the present study, Wistar rats were exposed by whole-body inhalation to 0, 0.1, 0.4, and 1.0 mg Ni/m{sup 3} nickel metal powder (MMAD = 1.8 {mu}m, GSD = 2.4 {mu}m) for 6 h/day, 5 days/week for up to 24 months. A subsequent six-month period without exposures preceded the final euthanasia. High mortality among rats exposed to 1.0 mg Ni/m{sup 3} nickel metal resulted in the earlier termination of exposures in this group. The exposure level of 0.4 mg Ni/m{sup 3} was established as the MTD for the study. Lung alterations associated with nickel metal exposure included alveolar proteinosis, alveolar histiocytosis, chronic inflammation, and bronchiolar-alveolar hyperplasia. No increased incidence of neoplasm of the respiratory tract was observed. Adrenal gland pheochromocytomas (benign and malignant) in males and combined cortical adenomas/carcinomas in females were induced in a dose-dependent manner by the nickel metal exposure. The incidence of pheochromocytomas was statistically increased in the 0.4 mg Ni/m{sup 3} male group. Pheochromocytomas appear to be secondary to the lung toxicity associated with the exposure rather than being related to a direct nickel effect on the adrenal glands. The incidence of cortical tumors among 0.4 mg Ni/m{sup 3} females, although statistically higher compared to the concurrent controls, falls within the historical control range; therefore, in the present study, this tumor is of uncertain relationship to nickel metal exposure. The lack of respiratory tumors in the present animal study is consistent with the findings of the epidemiological studies.

  10. Mathematical modeling of the nickel/metal hydride battery system

    SciTech Connect (OSTI)

    Paxton, B K [Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering

    1995-09-01T23:59:59.000Z

    A group of compounds referred to as metal hydrides, when used as electrode materials, is a less toxic alternative to the cadmium hydroxide electrode found in nickel/cadmium secondary battery systems. For this and other reasons, the nickel/metal hydride battery system is becoming a popular rechargeable battery for electric vehicle and consumer electronics applications. A model of this battery system is presented. Specifically the metal hydride material, LaNi{sub 5}H{sub 6}, is chosen for investigation due to the wealth of information available in the literature on this compound. The model results are compared to experiments found in the literature. Fundamental analyses as well as engineering optimizations are performed from the results of the battery model. In order to examine diffusion limitations in the nickel oxide electrode, a ``pseudo 2-D model`` is developed. This model allows for the theoretical examination of the effects of a diffusion coefficient that is a function of the state of charge of the active material. It is found using present data from the literature that diffusion in the solid phase is usually not an important limitation in the nickel oxide electrode. This finding is contrary to the conclusions reached by other authors. Although diffusion in the nickel oxide active material is treated rigorously with the pseudo 2-D model, a general methodology is presented for determining the best constant diffusion coefficient to use in a standard one-dimensional battery model. The diffusion coefficients determined by this method are shown to be able to partially capture the behavior that results from a diffusion coefficient that varies with the state of charge of the active material.

  11. Nickel Bubble Expansion in Type Ia Supernovae: Adiabatic Solutions

    E-Print Network [OSTI]

    Chih-Yueh Wang

    2008-06-20T23:59:59.000Z

    This paper presents hydrodynamical and radiation-hydrodynamical simulations of the nickel bubble effect in Type Ia supernovae, comparison of results to self-similar solutions, and application to observations of Type Ia supernova remnants, with a particular emphasis on Tycho's SNR.

  12. Hydridable material for the negative electrode in a nickel-metal hydride storage battery

    DOE Patents [OSTI]

    Knosp, Bernard (Neuilly-sur-Seine, FR); Bouet, Jacques (Paris, FR); Jordy, Christian (Dourdan, FR); Mimoun, Michel (Neuilly-sur-Marne, FR); Gicquel, Daniel (Lanorville, FR)

    1997-01-01T23:59:59.000Z

    A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##

  13. Ductile filler metal alloys for welding nickel aluminide alloys

    DOE Patents [OSTI]

    Santella, Michael L. (Knoxville, TN); McNabb, Jeffrey D. (Lenoir City, TN); Sikka, Vinod K. (Oak Ridge, TN)

    2003-04-08T23:59:59.000Z

    Nickel aluminum alloys are welded utilizing a nickel based alloy containing zirconium but substantially free of titanium and niobium which reduces the tendency to crack.

  14. Electron Density Distributions Calculated for the Nickel Sulfides Millerite, Vaesite, and Heazlewoodite and Nickel Metal: A Case for the Importance of Ni-Ni Bond Paths for

    E-Print Network [OSTI]

    Downs, Robert T.

    Electron Density Distributions Calculated for the Nickel Sulfides Millerite, Vaesite, and Heazlewoodite and Nickel Metal: A Case for the Importance of Ni-Ni Bond Paths for Electron Transport G. V. Gibbs's)) have been calculated for the bonded interactions comprising the nickel sulfide minerals millerite, Ni

  15. Method for inhibiting alkali metal corrosion of nickel-containing alloys

    DOE Patents [OSTI]

    DeVan, Jackson H. (Oak Ridge, TN); Selle, James E. (Westminster, CO)

    1983-01-01T23:59:59.000Z

    Structural components of nickel-containing alloys within molten alkali metal systems are protected against corrosion during the course of service by dissolving therein sufficient aluminum, silicon, or manganese to cause the formation and maintenance of a corrosion-resistant intermetallic reaction layer created by the interaction of the molten metal, selected metal, and alloy.

  16. In situ spectroscopic detection of SMSI effect in a Ni/CeO2 system: hydrogen-induced burial and dig out of metallic nickel

    E-Print Network [OSTI]

    Caballero, Alfonso

    2011-01-01T23:59:59.000Z

    and dig out of metallic nickel Alfonso Caballero,* a Juan P.on a CeO 2 thin film. The nickel particles of about 10–15 nm1 shows SEM images of the nickel particles before (top) and

  17. Experimental determination of equilibrium nickel isotope fractionation between metal and silicate from 500 C

    E-Print Network [OSTI]

    Manning, Craig

    Experimental determination of equilibrium nickel isotope fractionation between metal and silicate.04& between equilibrated bulk silicate Earth and chondrites, indicating that Ni isotopes are not likely- lation process involving a well-mixed silicate reservoir. Ã? 2012 Elsevier Ltd. All rights reserved. 1

  18. Sudbury: Nickel Smelting and Refining Nickel Production

    E-Print Network [OSTI]

    Toohey, Darin W.

    Sudbury: Nickel Smelting and Refining Nickel Production o Toyota buys most of its nickel from Sudbury to produce its nickel- metal hydride batteries Used in cars such as the Toyota Prius SO2 Emissions o The smelting of nickel = large amount of SO2 released as byproduct 4 metric tons of SO2 per

  19. Nickel anode electrode

    DOE Patents [OSTI]

    Singh, Prabhakar (Bethel, CT); Benedict, Mark (Monroe, CT)

    1987-01-01T23:59:59.000Z

    A nickel anode electrode fabricated by oxidizing a nickel alloying material to produce a material whose exterior contains nickel oxide and whose interior contains nickel metal throughout which is dispersed the oxide of the alloying material and by reducing and sintering the oxidized material to form a product having a nickel metal exterior and an interior containing nickel metal throughout which is dispersed the oxide of the alloying material.

  20. Paste Type Nickel Electrode Containing Compound And At Least One Other Element

    DOE Patents [OSTI]

    Bernard, Patrick (Massy, FR); Bertrand, Fran.cedilla.oise (Ris Orangis, FR); Simonneau, Olivier (Dourdan, FR)

    1999-11-30T23:59:59.000Z

    The present invention provides a paste type nickel electrode for a storage cell having an alkaline electrolyte, the electrode comprising a current collector and a paste containing a nickel-based hydroxide and an oxidized compound of cobalt syncrystallized with at least one other element, wherein said hydroxide forms a first powder and wherein said compound forms a second powder distinct from said first powder, said powders being mixed mechanically within said paste.

  1. High capacity nickel battery material doped with alkali metal cations

    DOE Patents [OSTI]

    Jackovitz, John F. (Monroeville, PA); Pantier, Earl A. (Penn Hills, PA)

    1982-05-18T23:59:59.000Z

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  2. The effects of soil type and chemical treatment on nickel speciation in refinery enriched soils

    E-Print Network [OSTI]

    The effects of soil type and chemical treatment on nickel speciation in refinery enriched soils Aerial deposition of Ni from a refinery in Port Colborne, Ontario, Canada has resulted in the enrichment in vegetable crops grown in the vicinity of the refinery. Conversely, dolomitic lime- stone additions resulted

  3. Diastereoselective nickel-catalyzed reductive coupling of alkynes and aldehydes and application towards the B-type amphidinolides

    E-Print Network [OSTI]

    Ndubaku, Chudi O

    2006-01-01T23:59:59.000Z

    The application of recently developed stereoselective nickel-catalyzed reductive coupling reactions of alkynes and aldehydes to the synthesis of complex natural product targets was explored. The "B-Type" amphidinolides ...

  4. Preparation of Mesoporous Silica Templated Metal Nanowire Films on Foamed Nickel Substrates

    SciTech Connect (OSTI)

    Campbell, Roger [University of Alabama, Tuscaloosa; Kenik, Edward A [ORNL; Bakker, Martin [University of Alabama, Tuscaloosa; Havrilla, George [Los Alamos National Laboratory (LANL); Montoya, Velma [Los Alamos National Laboratory (LANL); Shamsuzzoha, Mohammed [University of Alabama, Tuscaloosa

    2006-01-01T23:59:59.000Z

    A method has been developed for the formation of high surface area nanowire films on planar and three-dimensional metal electrodes. These nanowire films are formed via electrodeposition into a mesoporous silica film. The mesoporous silica films are formed by a sol-gel process using Pluronic tri-block copolymers to template mesopore formation on both planar and three-dimensional metal electrodes. Surface area increases of up to 120-fold have been observed in electrodes containing a templated film when compared to the same types of electrodes without the templated film.

  5. Schottky barrier height reduction for holes by Fermi level depinning using metal/nickel oxide/silicon contacts

    SciTech Connect (OSTI)

    Islam, Raisul, E-mail: raisul@stanford.edu; Shine, Gautam; Saraswat, Krishna C. [Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States)

    2014-11-03T23:59:59.000Z

    We report the experimental demonstration of Fermi level depinning using nickel oxide (NiO) as the insulator material in metal-insulator-semiconductor (M-I-S) contacts. Using this contact, we show less than 0.1?eV barrier height for holes in platinum/NiO/silicon (Pt/NiO/p-Si) contact. Overall, the pinning factor was improved from 0.08 (metal/Si) to 0.26 (metal/NiO/Si). The experimental results show good agreement with that obtained from theoretical calculation. NiO offers high conduction band offset and low valence band offset with Si. By reducing Schottky barrier height, this contact can be used as a carrier selective contact allowing hole transport but blocking electron transport, which is important for high efficiency in photonic applications such as photovoltaics and optical detectors.

  6. Nickel-Catalyzed Heck-Type Reactions of Benzyl Chlorides and Simple Olefins

    E-Print Network [OSTI]

    Matsubara, Ryosuke

    Nickel-catalyzed intermolecular benzylation and heterobenzylation of unactivated alkenes to provide functionalized allylbenzene derivatives are described. A wide range of both the benzyl chloride and alkene coupling partners ...

  7. Sulfur resistance of Group VIII transition metal promoted nickel catalysts for synthesis gas methanation

    E-Print Network [OSTI]

    Hamlin, Kellee Hall

    1986-01-01T23:59:59.000Z

    their resistance to deactivation by Hxg. The nickel and promoters were adsorbed on the catalyst by a simple precipitation technique. To investigate catalyst activity and deactivation experimentally, a fixed bed tubular reactor was operated at atmospheric... AND PROCEDURE To investigate catalyst activity and deactivation experimentally, a fixed bed tubular reactor wae constructed for the synthesis gss methanation studies. The reactor system and supporting equipment are shown schematically in Figure 1, while...

  8. Relating metal binding to DNA binding in the nickel regulatory protein NikR

    E-Print Network [OSTI]

    Phillips, Christine M. (Christine Marie)

    2010-01-01T23:59:59.000Z

    The concentration of transition metals within the cell must be tightly regulated. If the concentration of a given transition metal is too low the cell may not be able to perform life-sustaining processes, while high levels ...

  9. Contaminated nickel scrap processing

    SciTech Connect (OSTI)

    Compere, A.L.; Griffith, W.L.; Hayden, H.W.; Johnson, J.S. Jr.; Wilson, D.F.

    1994-12-01T23:59:59.000Z

    The DOE will soon choose between treating contaminated nickel scrap as a legacy waste and developing high-volume nickel decontamination processes. In addition to reducing the volume of legacy wastes, a decontamination process could make 200,000 tons of this strategic metal available for domestic use. Contaminants in DOE nickel scrap include {sup 234}Th, {sup 234}Pa, {sup 137}Cs, {sup 239}Pu (trace), {sup 60}Co, U, {sup 99}Tc, and {sup 237}Np (trace). This report reviews several industrial-scale processes -- electrorefining, electrowinning, vapormetallurgy, and leaching -- used for the purification of nickel. Conventional nickel electrolysis processes are particularly attractive because they use side-stream purification of process solutions to improve the purity of nickel metal. Additionally, nickel purification by electrolysis is effective in a variety of electrolyte systems, including sulfate, chloride, and nitrate. Conventional electrorefining processes typically use a mixed electrolyte which includes sulfate, chloride, and borate. The use of an electrorefining or electrowinning system for scrap nickel recovery could be combined effectively with a variety of processes, including cementation, solvent extraction, ion exchange, complex-formation, and surface sorption, developed for uranium and transuranic purification. Selected processes were reviewed and evaluated for use in nickel side-stream purification. 80 refs.

  10. Quantum dissipative dynamics of adsorbates near metal surfaces: A surrogate Hamiltonian theory applied to hydrogen on nickel

    E-Print Network [OSTI]

    Baer, Roi

    applied to hydrogen on nickel Roi Baer and Ronnie Kosloff Department of Physical Chemistry and the Fritz on nickel were studied. In the bulk the line shape is mostly influenced by nonadiabatic effects on nickel. A distinction between lattice modes that enhance the tunneling and ones that suppress

  11. Stabilization of hexagonal close-packed metallic nickel for alumina-supported systems prepared from Ni(II) glycinate

    SciTech Connect (OSTI)

    Rodriguez-Gonzalez, Vicente [Laboratoire de Reactivite de Surface (UMR 7609 CNRS), Universite Pierre et Marie Curie-Paris 6, 4 Place Jussieu, 75252 Paris Cedex 05 (France); Marceau, Eric [Laboratoire de Reactivite de Surface (UMR 7609 CNRS), Universite Pierre et Marie Curie-Paris 6, 4 Place Jussieu, 75252 Paris Cedex 05 (France)], E-mail: eric.marceau@upmc.fr; Beaunier, Patricia [Laboratoire de Reactivite de Surface (UMR 7609 CNRS), Universite Pierre et Marie Curie-Paris 6, 4 Place Jussieu, 75252 Paris Cedex 05 (France); Che, Michel [Laboratoire de Reactivite de Surface (UMR 7609 CNRS), Universite Pierre et Marie Curie-Paris 6, 4 Place Jussieu, 75252 Paris Cedex 05 (France); Institut Universitaire de France (France); Train, Cyrille [Laboratoire de Chimie Inorganique et Materiaux Moleculaires (UMR 7071 CNRS), Universite Pierre et Marie Curie-Paris 6, 4 Place Jussieu, 75252 Paris Cedex 05 (France)

    2007-01-15T23:59:59.000Z

    The decomposition in flowing argon of the neutral complex [Ni{sup II}(glycinate){sub 2}(H{sub 2}O){sub 2}] leads to a mixture of face-centered cubic (fcc) and hexagonal close-packed (hcp) metallic nickel. The latter is the main phase when the Ni(II) complex is supported on alumina. Unlike most hexagonal Ni phases described earlier, and similar to hexagonal Ni{sub 3}C, the unit cell parameters (a=0.2493 and c=0.4084nm) lead to Ni-Ni distances equal to those encountered in fcc Ni. TEM shows that the nanoparticles are protected by graphite layers, whose elimination by heating in hydrogen results in transformation to the fcc phase and crystal growth. Magnetic measurements provide evidence of the coexistence of superparamagnetic and ferromagnetic nanoparticles. This result is in line with the broad size distribution observed by TEM and is interpreted on the basis of the metallic character of hcp Ni particles.

  12. Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia

    SciTech Connect (OSTI)

    Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

    2014-03-15T23:59:59.000Z

    Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?°C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?°C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

  13. Improving nickel metal hydride batteries through research in negative electrode corrosion control and novel electrode materials 

    E-Print Network [OSTI]

    Alexander, Michael Scott

    1997-01-01T23:59:59.000Z

    on the Adsorption of Hydrogen on and Absorption into Metal, Alloys, and Intermetallics, The Electrochemical Society, PV 97-16, p. 277. vn1 TABLE OF CONTENTS ABSTRACT Page DEDICATION. lv ACKNOWLEGEMENTS . TABLE OF CONTENTS vnr LIST OF FIGURES. . LIST... of a new family of the intermetallic alloys containing one transition metal (4, 7, 8-10). The major family of such intermetallic alloys and their hydrides are listed in Table 1. 2 which also shows the gravimetric and volumetric hydrogen density...

  14. Improving nickel metal hydride batteries through research in negative electrode corrosion control and novel electrode materials

    E-Print Network [OSTI]

    Alexander, Michael Scott

    1997-01-01T23:59:59.000Z

    The objective of this work is to improve the negative electrode of the metal hydride electrodes. Three areas were investigated: corrosion inhibition through Zn additives to the electrolyte, the use of AB5 and AB2 alloy mixtures, and novel AB2...

  15. Electrochromic nickel oxide simultaneously doped with lithium and a metal dopant

    DOE Patents [OSTI]

    Gillaspie, Dane T; Weir, Douglas G

    2014-04-01T23:59:59.000Z

    An electrochromic device comprising a counter electrode layer comprised of lithium metal oxide which provides a high transmission in the fully intercalated state and which is capable of long-term stability, is disclosed. Methods of making an electrochromic device comprising such a counter electrode are also disclosed.

  16. X-ray absorption spectroscopy study of the local structure of heavy metal ions incorporated into electrodeposited nickel oxide films

    SciTech Connect (OSTI)

    Balasubramanian, M.; Melendres, C.A. [Argonne National Lab., IL (United States). Chemical Technology Div.] [Argonne National Lab., IL (United States). Chemical Technology Div.; Mansour, A.N. [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.] [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.

    1999-02-01T23:59:59.000Z

    The incorporation of heavy metal ions into simulated corrosion films has been investigated using spectroscopic and electrochemical techniques. The films were formed by electrodeposition of the appropriate oxide (hydroxide) onto a graphite substrate. Synchrotron X-ray absorption spectroscopy (XAS) was used to determine the structure and composition of the host oxide film, as well as the local structure of the impurity ion. Results on the incorporation of Ce and Sr into surface films of Ni(OH){sub 2} and NiOOH are reported. Cathodically deposited Ni(OH){sub 2} was found to be mainly in the alpha form while anodically prepared NiOOH showed the presence of Ni{sup +2} and Ni{sup +4}. Cerium incorporated into Ni(OH){sub 2} exists as mixed Ce{sup +3} and Ce{sup +4} phases; a Ce{sup +4} species was found when Ce was codeposited with NiOOH. The structure of the Ce{sup +4} phase in anodic films appears similar to a Ce(OH){sub 4} standard. However, XAS, X-ray diffraction, and laser Raman measurements indicate that the latter chemical formulation is probably incorrect and that the material is really a disordered form of hydrous cerium oxide. The local structure of this material is similar to CeO{sub 2} but has much higher structural disorder. The significance of this finding on the question of the structure of Ce-based corrosion inhibitors in aluminum oxide films is pointed out. Moreover, the authors found it possible to form pure Ce oxide (hydroxide) films on graphite by both cathodic and anodic electrodeposition; their structures have also been elucidated. Strontium incorporated into nickel oxide films consists of Sr{sup +2} which is coordinated to oxygen atoms and is likely to exist as small domains of coprecipitated material.

  17. Advanced nickel-metal hydride cell development. Final report, September 1993--March 1996

    SciTech Connect (OSTI)

    Lim, Hong S.

    1996-03-01T23:59:59.000Z

    Inert gas atomization using metal hydride alloys for a Ni/MH{sub x}cell was studied. Atomization of the alloys was demonstrated on a small production scale up to batch size of several kg. Relative performance of the atomized and nonatomized alloys was investigated for the electrode material in a Ni/MH{sub x} cell. The study included effects of charge-discharge rates, temperature, and particle size on cell voltage (polarization) and specific capacity. Results show that the specific capacity of the present atomized alloys was apprecialy smaller than that of the nonatomized powder, especially for initial cycles. Full activation of the atomized alloys oftentook several hundreds of cycles. However, no appreciable difference in discharge rate capability was observed with R10 and R12 alloys. Chemical compositions were indistinguishable, although the oxygen contents of the atomized alloys were always higher. Effects of Ni and Cu coating on alloy performance were studied after electroless coating; the coatings noticeably improved the electrode rate capability for all the alloys. The electrode polarization was esecially improved, but not the cycle life. Further studies are needed.

  18. INFLUENCE OF GERMANIUM CONCENTRATION AND HOMOGENEOUS BORON DOPING ON MICROSTRUCTURE, KINETICS, AND SHEET RESISTANCE OF NICKEL

    E-Print Network [OSTI]

    Florida, University of

    , AND SHEET RESISTANCE OF NICKEL GERMANOSILICIDE THIN FILMS By JOHN SAMUEL MOORE A DISSERTATION PRESENTED...................................................................................18 1.3 Nickel as a Silicidation Metal........................................................................25 2.1.2 Nickel-Silicon Binary System........................................................

  19. Measuring nickel masses in Type Ia supernovae using cobalt emission in nebular phase spectra

    E-Print Network [OSTI]

    Childress, Michael J; Seitenzahl, Ivo; Sullivan, Mark; Maguire, Kate; Taubenberger, Stefan; Scalzo, Richard; Ruiter, Ashley; Blagorodnova, Nadejda; Camacho, Yssavo; Castillo, Jayden; Elias-Rosa, Nancy; Fraser, Morgan; Gal-Yam, Avishay; Graham, Melissa; Howell, D Andrew; Inserra, Cosimo; Jha, Saurabh W; Kumar, Sahana; Mazzali, Paolo A; McCully, Curtis; Morales-Garoffolo, Antonia; Pandya, Viraj; Polshaw, Joe; Schmidt, Brian; Smartt, Stephen; Smith, Ken W; Sollerman, Jesper; Spyromilio, Jason; Tucker, Brad; Valenti, Stefano; Walton, Nicholas; Wolf, Christian; Yaron, Ofer; Young, D R; Yuan, Fang; Zhang, Bonnie

    2015-01-01T23:59:59.000Z

    The light curves of Type Ia supernovae (SNe Ia) are powered by the radioactive decay of $^{56}$Ni to $^{56}$Co at early times, and the decay of $^{56}$Co to $^{56}$Fe from ~60 days after explosion. We examine the evolution of the [Co III] 5892 A emission complex during the nebular phase for SNe Ia with multiple nebular spectra and show that the line flux follows the square of the mass of $^{56}$Co as a function of time. This result indicates both efficient local energy deposition from positrons produced in $^{56}$Co decay, and long-term stability of the ionization state of the nebula. We compile 77 nebular spectra of 25 SN Ia from the literature and present 17 new nebular spectra of 7 SNe Ia, including SN2014J. From these we measure the flux in the [Co III] 5892 A line and remove its well-behaved time dependence to infer the initial mass of $^{56}$Ni ($M_{Ni}$) produced in the explosion. We then examine $^{56}$Ni yields for different SN Ia ejected masses ($M_{ej}$ - calculated using the relation between light...

  20. Nickel/ruthenium catalyst and method for aqueous phase reactions

    DOE Patents [OSTI]

    Elliott, Douglas C. (Richland, WA); Sealock, John L. (West Richland, WA)

    1998-01-01T23:59:59.000Z

    A method of hydrogenation using a catalyst in the form of a plurality of porous particles wherein each particle is a support having nickel metal catalytic phase or reduced nickel deposited thereon in a first dispersed phase and an additional ruthenium metal deposited onto the support in a second dispersed phase. The additional ruthenium metal is effective in retarding or reducing agglomeration or sintering of the nickel metal catalytic phase thereby increasing the life time of the catalyst during hydrogenation reactions.

  1. Inhibition of nickel precipitation by organic ligands

    SciTech Connect (OSTI)

    Hu, H.L.; Nikolaidis, N.P.; Grasso, D. [Univ. of Connecticut, Storrs, CT (United States)

    1996-11-01T23:59:59.000Z

    Wastewaters from electroplating are very complex due to the composition of the plating baths. A nickel plating bath typically consists of a nickel source (nickel chloride or nickel sulfate), complexing agents to solubilize nickel ions controlling their concentration in the solution, buffering agents to maintain pH, brighteners to improve brightness of the plated metal, stabilizers (inhibitors) to prevent undesired reactions, accelerators to enhance speed of reactions, wetting agents to reduce surface tension at the metal surface, and reducing agents (only for electroless nickel plating) to supply electrons for reduction of the nickel. Alkaline precipitation is the most common method of recovering nickel from wastewaters. However, organic constituents found in the wastewaters can mask or completely inhibit the precipitation of nickel. The objective of this study was to conduct an equilibrium study to explore the inhibition behavior of various organic ligands on nickel precipitation. This will lay the groundwork for development of technologies efficacious in the treatment of complexed nickel. The organic ligands used in this study are EDTA, triethanolamine (TEA), gluconate, and tartrate.

  2. Nickel aluminide alloys with improved weldability

    DOE Patents [OSTI]

    Santella, M.L.; Goodwin, G.M.

    1995-05-09T23:59:59.000Z

    Weldable nickel aluminide alloys which are essentially free, if not entirely free, of weld hot cracking are provided by employing zirconium concentrations in these alloys of greater than 2.6 wt. % or sufficient to provide a substantial presence of Ni--Zr eutectic phase in the weld so as to prevent weld hot cracking. Weld filler metals formed from these so modified nickel aluminide alloys provide for crack-free welds in previously known nickel aluminide alloys. 5 figs.

  3. Nickel aluminide alloys with improved weldability

    DOE Patents [OSTI]

    Santella, Michael L. (Knoxville, TN); Goodwin, Gene M. (Lenior City, TN)

    1995-05-09T23:59:59.000Z

    Weldable nickel aluminide alloys which are essentially free, if not entirely free, of weld hot cracking are provided by employing zirconium concentrations in these alloys of greater than 2.6 wt. % or sufficient to provide a substantial presence of Ni--Zr eutectic phase in the weld so as to prevent weld hot cracking. Weld filler metals formed from these so modified nickel aluminide alloys provide for crack-free welds in previously known nickel aluminide alloys.

  4. In situ X-ray absorption fine structure studies of foreign metal ions in nickel hydrous oxide electrodes in alkaline electrolytes

    SciTech Connect (OSTI)

    Kim, Sunghyun; Tryk, D.A.; Scherson, D. (Case Western Reserve Univ., Cleveland, OH (United States)); Antonio, M.R. (Argonne National Lab., IL (United States)); Carr, R. (Stanford Synchrotron Radiation Lab., CA (United States))

    1994-10-06T23:59:59.000Z

    Aspects of the structural and electronic properties of hydrous oxide films of composite (9:1) Ni/Co and (9:1) Ni/Fe, prepared by electrodeposition, have been examined in alkaline electrolytes using in situ X-ray absorption fine structure (XAFS). An analysis of the X-ray absorption near the edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) for the Co and Fe K-edges of these composite hydrous oxides revealed that, regardless of the oxidation state of nickel sites in the films, the guest metal ions are present as Co[sup 3+] and Fe[sup 3+] and that the cobalt-oxygen distance d(Co-O) = 1.9 [+-] 0.02 [angstrom] and d(Fe-O) = 1.92 [+-] 0.02 [angstrom]. The latter values are in excellent agreement with d(Me-O) (Me = Co or Fe) in CoOOH and [beta]- and [gamma]-FeOOH, respectively, determined by conventional X-ray diffraction. Two clearly defined Me-Ni first coordination shells could be observed in the Fourier transforms (FT) of the K-edge EXAFS of the guest metal recorded at a potential at which both Ni[sup 2+] and Ni[sup 3+] sites are expected to be present. 28 refs., 10 figs., 3 tabs.

  5. Parameters affecting the fate of metals in various soils

    E-Print Network [OSTI]

    Covar, Andrew Prescott

    1975-01-01T23:59:59.000Z

    Parameters Affecting the Fate of Metals in Various Soils. (December 1975) Andrew Prescott Covar, B. S. , University of Texas at E1 Paso Chairman of Advisory Committee: Dr. Calvin Woods In this study, the fate of cadmium, copper, lead, nickel, and zinc... DETERMINATION OF WATER SOLUBLE, EXCHANGEABLE, ORGANIC BOUND, AND MINERAL ASSOCIATED METALS ? SPLIT I I PAGE 18 19 3 CADMIUM UPTAKE BY SOIL TYPE 4 COPPER UPTAKE BY SOIL TYPE 5 LEAD UPTAKE BY SOIL TYPE 6 NICKEL UPTAKE BY SOIL TYPE 7 ZINC UPTAKE BY SOIL...

  6. Geogenic Nickel Speciation in Serpentine Soils and Its Relationship to Nickel Uptake in Hyperaccumulator Plants. Tuesday, November 3, 2009: 3:00 PM

    E-Print Network [OSTI]

    Sparks, Donald L.

    Geogenic Nickel Speciation in Serpentine Soils and Its Relationship to Nickel Uptake to extract pollutants from soil. Some can accumulate up to 20g/kg nickel in dry shoot biomass. This ability can be utilized to economically remediate contaminated soils. Nickel is a transition metal that occurs

  7. Superior Performance of HIS-SelectTM HF Nickel

    E-Print Network [OSTI]

    Lebendiker, Mario

    Superior Performance of HIS-SelectTM HF Nickel Affinity Gel By John Dapron, Michael Harvey, Heidi by immobilized metal affinity chromatography (IMAC), using nickel as the affinity ligand. Sigma-Aldrich has been expanding its line of specialty HIS-Select nickel chelate affinity media to meet the varied needs

  8. Microstructural, mechanical and weldability assessments of the dissimilar welds between ??- and ??-strengthened nickel-base superalloys

    SciTech Connect (OSTI)

    Naffakh Moosavy, Homam, E-mail: homam_naffakh@iust.ac.ir [School of Metallurgy and Materials Engineering, Iran University of Science and Technology (IUST), Tehran 16846-13114 (Iran, Islamic Republic of); Aboutalebi, Mohammad-Reza; Seyedein, Seyed Hossein [School of Metallurgy and Materials Engineering, Iran University of Science and Technology (IUST), Tehran 16846-13114 (Iran, Islamic Republic of); Mapelli, Carlo [Dipartimento di Meccanica, Politecnico di Milano, Via La Massa 34, Milan 20156 (Italy)

    2013-08-15T23:59:59.000Z

    Dissimilar welding of ??- and ??-strengthened nickel-base superalloys has been investigated to identify the relationship between the microstructure of the welds and the resultant mechanical and weldability characteristics. ??-Strengthened nickel-base Alloy 500 and ??-strengthened nickel-base Alloy 718 were used for dissimilar welding. Gas tungsten arc welding operations were utilized for performing the autogenous dissimilar welding. Alloy 500 and Alloy 718 base metals showed various types of phases, carbides, intermetallics and eutectics in their microstructure. The results for Alloy 500 weld metal showed severe segregation of titanium to the interdendritic regions. The Alloy 718 weld metal compositional analysis confirmed the substantial role of Nb in the formation of low-melting eutectic-type morphologies which can reduce the weldability. The microstructure of dissimilar weld metal with dilution level of 65% wt.% displayed semi-developed dendritic structure. The less segregation and less formation of low-melting eutectic structures caused to less susceptibility of the dissimilar weld metal to the solidification cracking. This result was confirmed by analytic modeling achievements. Dissolution of ??-Ni{sub 3}Nb precipitations took place in the Alloy 718 heat-affected zone leading to sharp decline of the microhardness in this region. Remelted and resolidified regions were observed in the partially-melted zone of Alloy 500 and Alloy 718. Nevertheless, no solidification and liquation cracking happened in the dissimilar welds. Finally, this was concluded that dissimilar welding of ??- and ??-strengthened nickel-base superalloys can successfully be performed. - Highlights: • Dissimilar welding of ??- and ??-strengthened nickel-base superalloys is studied. • Microstructural, mechanical and weldability aspects of the welds are assessed. • Microstructure of welds, bases and heat-affected zones is characterized in detail. • The type, morphology and distribution of the phases are thoroughly investigated. • Dissimilar welding is successfully performed without occurrence of any hot cracks.

  9. Electroless nickel recycling via electrodialysis

    SciTech Connect (OSTI)

    Steffani, C.; Meltzer, M.

    1995-04-01T23:59:59.000Z

    Electroless nickel is widely used in the metal finishing industry as a coating. It plates evenly on a variety of surfaces and replicates or enhances the surface finish. It has high hardness and good corrosion resistance and machinability. However, its bath life is limited and it has a tendency to spontaneously plate out on the tank and associated equipment. These problems add to the cost per unit component plated. Also, expensive waste treatment is required before users can dispose of the spent solution. Electroless nickel`s limited bath life is inherent in its chemical make-up. Using hypophosphite as the reducing agent for the nickel ion generates by-products of nickel metal and orthophosphite. When the level of orthophosphite in the solution reaches a high concentration, the reaction slows and finally stops. The bath must be disposed of, and its treatment and replacement costs are high. Metal salts have a tendency to plate out because of the dissolved solids present, and this also makes it necessary to discard the bath. Lawrence Livermore National Laboratory (LLNL) has conducted a study of an electrodialysis process that can reduce both chemical purchases and disposal costs. Electrodialysis employs a membrane, deionized water, and an electromotive potential to separate the orthophosphite and other dissolved solids from the nickel ions. With the aid of the electromotive potential, the dissolved solids migrate across the membrane from the process solution into the water in the recycling unit`s holding cell. This migration lowers the total dissolved solids (TDS) in the process solution and improves plating performance. The dialysis process makes it possible to reuse the bath many times without disposal.

  10. Antiferromagnetic half-metals, gapless half-metals, and spin gapless semiconductors: The D0{sub 3}-type Heusler alloys

    SciTech Connect (OSTI)

    Gao, G. Y., E-mail: guoying-gao@mail.hust.edu.cn; Yao, Kai-Lun, E-mail: klyao@mail.hust.edu.cn [School of Physics and Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074 (China)] [School of Physics and Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2013-12-02T23:59:59.000Z

    High-spin-polarization materials are desired for the realization of high-performance spintronic devices. We combine recent experimental and theoretical findings to theoretically design several high-spin-polarization materials in binary D0{sub 3}-type Heusler alloys: gapless (zero-gap) half-metallic ferrimagnets of V{sub 3}Si and V{sub 3}Ge, half-metallic antiferromagnets of Mn{sub 3}Al and Mn{sub 3}Ga, half-metallic ferrimagnets of Mn{sub 3}Si and Mn{sub 3}Ge, and a spin gapless semiconductor of Cr{sub 3}Al. The high spin polarization, zero net magnetic moment, zero energy gap, and slight disorder compared to the ternary and quaternary Heusler alloys make these binary materials promising candidates for spintronic applications. All results are obtained by the electronic structure calculations from first-principles.

  11. p-Type semiconducting nickel oxide as an efficiency-enhancing anodal interfacial layer in bulk heterojunction solar cells

    DOE Patents [OSTI]

    Irwin, Michael D; Buchholz, Donald B; Marks, Tobin J; Chang, Robert P. H.

    2014-11-25T23:59:59.000Z

    The present invention, in one aspect, relates to a solar cell. In one embodiment, the solar cell includes an anode, a p-type semiconductor layer formed on the anode, and an active organic layer formed on the p-type semiconductor layer, where the active organic layer has an electron-donating organic material and an electron-accepting organic material.

  12. Determination of Primordial Metallicity and Mixing in the Type IIP Supernova 1993W

    SciTech Connect (OSTI)

    Baron, E.; Nugent, Peter E.; Branch, David; Hauschildt, Peter H.; Turatto, M.; Cappellaro, E.

    2002-12-11T23:59:59.000Z

    We present the results of a large grid of synthetic spectra and compare them to early spectroscopic observations of SN 1993W. This supernova was discovered close to its explosion date and at a recession velocity of 5400 km/s is located in the Hubble flow. We focus here on two early spectra that were obtained approximately 5 and 9 days after explosion. We parameterize the outer supernova envelope as a power-law density profile in homologous expansion. In order to extract information on the value of the parameters a large number of models was required. We show that very early spectra combined with detailed models can provide constraints on the value of the power law index, the ratio of hydrogen to helium in the surface of the progenitor, the progenitor metallicity and the amount of radioactive nickel mixed into the outer envelope of the supernova. The spectral fits reproduce the observed spectra exceedingly well. The spectral results combined with the early photometry predict that the explosion date was 4.7 {+-} 0.7 days before the first spectrum was obtained. The ability to obtain the metallicity from early spectra make SN IIP attractive probes of chemical evolution in the universe and by showing that we have the ability to pin down the parameters of the progenitor and mixing during the supernova explosion, it is likely to make SN IIP useful cosmological distance indicators which are at the same time complementary to SNe Ia.

  13. Effect of the composition of polypyrrole substrate on the electrodeposition of copper and nickel

    SciTech Connect (OSTI)

    Hepel, M.; Chen, Y.M.; Stephenson, R. [State Univ. of New York, Potsdam, NY (United States). Dept. of Chemistry

    1996-02-01T23:59:59.000Z

    Electrodeposition of copper and nickel on a variety of substrates including conductive polymer films with two different compositions has been studied. The enhancement of the copper and nickel electrodeposition rate was observed for composite polypyrrole films with cation-exchange properties in comparison to undoped polypyrrole films with anion-exchange properties. Significant enhancement of the nickel electrodeposition rate on both types of conductive polymer vs. the bare gold electrode was also found. An explanation of these effects is presented. An electrochemical quartz crystal microbalance (EQCM) with 10 MHz AT-cut piezoelectrodes was used in this study. Use of the EQCM technique allowed for simultaneous monitoring of voltamperometric and resonance frequency vs. potential or time characteristics. The thickness of electropolymerized polypyrrole films as well as the amounts of electrodeposited metals were controlled by monitoring the EQCM resonant frequency. The nucleation density has been determined from scanning electron microscope experiments.

  14. Nickel/ruthenium catalyst and method for aqueous phase reactions

    DOE Patents [OSTI]

    Elliott, D.C.; Sealock, J.L.

    1998-09-29T23:59:59.000Z

    A method of hydrogenation is described using a catalyst in the form of a plurality of porous particles wherein each particle is a support having nickel metal catalytic phase or reduced nickel deposited thereon in a first dispersed phase and an additional ruthenium metal deposited onto the support in a second dispersed phase. The additional ruthenium metal is effective in retarding or reducing agglomeration or sintering of the nickel metal catalytic phase thereby increasing the life time of the catalyst during hydrogenation reactions. 2 figs.

  15. THE IMPACT OF METALLICITY ON THE RATE OF TYPE Ia SUPERNOVAE

    SciTech Connect (OSTI)

    Kistler, Matthew D. [California Institute of Technology, Mail Code 350-17, Pasadena, CA 91125 (United States); Stanek, K. Z.; Kochanek, Christopher S.; Thompson, Todd A. [Center for Cosmology and Astro-Particle Physics, Ohio State University, Columbus, OH 43210 (United States); Prieto, Jose L. [Carnegie Observatories, 813 Santa Barbara Street, Pasadena, CA 91101 (United States)

    2013-06-20T23:59:59.000Z

    The metallicity of a star strongly affects both its evolution and the properties of the stellar remnant that results from its demise. It is generally accepted that stars with initial masses below {approx}8 M{sub Sun} leave behind white dwarfs and that some sub-population of these lead to Type Ia supernovae (SNe Ia). However, it is often tacitly assumed that metallicity has no effect on the rate of SNe Ia. We propose that a consequence of the effects of metallicity is to significantly increase the SN Ia rate in lower-metallicity galaxies, in contrast to previous expectations. This is because lower-metallicity stars leave behind higher-mass white dwarfs, which should be easier to bring to explosion. We first model SN Ia rates in relation to galaxy masses and ages alone, finding that the elevation in the rate of SNe Ia in lower-mass galaxies measured by Lick Observatory SN Search is readily explained. However, we then see that models incorporating this effect of metallicity agree just as well. Using the same parameters to estimate the cosmic SN Ia rate, we again find good agreement with data up to z Almost-Equal-To 2. We suggest that this degeneracy warrants more detailed examination of host galaxy metallicities. We discuss additional implications, including for hosts of high-z SNe Ia, the SN Ia delay time distribution, super-Chandrasekhar SNe, and cosmology.

  16. Amorphous metal alloy and composite

    DOE Patents [OSTI]

    Wang, Rong (Richland, WA); Merz, Martin D. (Richland, WA)

    1985-01-01T23:59:59.000Z

    Amorphous metal alloys of the iron-chromium and nickel-chromium type have excellent corrosion resistance and high temperature stability and are suitable for use as a protective coating on less corrosion resistant substrates. The alloys are stabilized in the amorphous state by one or more elements of titanium, zirconium, hafnium, niobium, tantalum, molybdenum, and tungsten. The alloy is preferably prepared by sputter deposition.

  17. Metal-insulator-semiconductor structures on p-type GaAs with low interface state density

    E-Print Network [OSTI]

    Chen, Zhi

    Metal-insulator-semiconductor structures on p-type GaAs with low interface state density Zhi Chen properties of in situ deposited Si3N4 /Si/p-GaAs metal-insulator-semiconductor structures have been offered by a low gate leakage technology in GaAs, such as metal insulator structures, func- tional Ga

  18. METALLICITY DIFFERENCES IN TYPE Ia SUPERNOVA PROGENITORS INFERRED FROM ULTRAVIOLET SPECTRA

    SciTech Connect (OSTI)

    Foley, Ryan J.; Kirshner, Robert P. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

    2013-05-20T23:59:59.000Z

    Two ''twin'' Type Ia supernovae (SNe Ia), SNe 2011by and 2011fe, have extremely similar optical light-curve shapes, colors, and spectra, yet have different ultraviolet (UV) continua as measured in Hubble Space Telescope spectra and measurably different peak luminosities. We attribute the difference in the UV continua to significantly different progenitor metallicities. This is the first robust detection of different metallicities for SN Ia progenitors. Theoretical reasoning suggests that differences in metallicity also lead to differences in luminosity. SNe Ia with higher progenitor metallicities have lower {sup 56}Ni yields and lower luminosities for the same light-curve shape. SNe 2011by and 2011fe have different peak luminosities ({Delta}M{sub V} Almost-Equal-To 0.6 mag), which correspond to different {sup 56}Ni yields: M{sub 11fe}({sup 56}Ni) / M{sub 11by}({sup 56}Ni) = 1.7{sup +0.7}{sub -0.5}. From theoretical models that account for different neutron-to-proton ratios in progenitors, the differences in {sup 56}Ni yields for SNe 2011by and 2011fe imply that their progenitor stars were above and below solar metallicity, respectively. Although we can distinguish progenitor metallicities in a qualitative way from UV data, the quantitative interpretation in terms of abundances is limited by the present state of theoretical models.

  19. Hydrogen production with nickel powder cathode catalysts in microbial electrolysis cells

    E-Print Network [OSTI]

    Hydrogen production with nickel powder cathode catalysts in microbial electrolysis cells Priscilla Available online 24 November 2009 Keywords: MEC Electrohydrogenesis Hydrogen production Cathode Metal Nickel using a nickel powder (0.5­1 mm) and their performance was compared to conventional electrodes

  20. Precipitation of sigma and chi phases in ?-ferrite of Type 316FR weld metals

    SciTech Connect (OSTI)

    Chun, Eun Joon, E-mail: ejchun@mapse.eng.osaka-u.ac.jp [Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita-shi, Osaka 565-0871 (Japan); Baba, Hayato [Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita-shi, Osaka 565-0871 (Japan); Nishimoto, Kazutoshi [Department of the Application of Nuclear Technology, Fukui University of Technology, Gakuen 3-6-1, Fukui-shi, Fukui 910-8505 (Japan); Saida, Kazuyoshi [Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita-shi, Osaka 565-0871 (Japan)

    2013-12-15T23:59:59.000Z

    The decomposition behavior and kinetics of ?-ferrite are examined using aging treatments between 873 and 1073 K for Type 316FR stainless steel weld metals with different solidification modes (316FR AF, 316FR FA). The dominant precipitates are sigma, chi, and secondary austenite nucleated at ?-ferrite/austenite interfaces or in the interior of the ferrite grains. These precipitates consume all the ferrite during isothermal aging in both 316FR AF and FA weld metals. Differences in the precipitation behavior (precipitation initiation time and precipitation speed) between weld metals can be explained by i) the degree of Cr and Mo microsegregation within ?-ferrite or austenite near ferrite and ii) the nucleation sites induced due to the solidification mode (AF or FA), such as the ferrite amount. For both weld materials, a Johnson–Mehl-type equation can express the precipitation behavior of the sigma + chi phases and quantitatively predict the behavior at the service-exposure temperatures of a fast breed reactor. - Highlights: • Precipitation of ? and ? phase in Type 316FR welds (two solidification modes) • Different precipitation behaviors: precipitation initiation time and growth speed • Johnson-Mehl–type equation is the most applicable to the precipitation behaviors • Precipitation behaviors are predicted under service conditions of FBRs.

  1. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2004-04-20T23:59:59.000Z

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  2. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander (Sunnyvale, CA)

    2003-01-01T23:59:59.000Z

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  3. CHARACTERIZATION OF THE STRUCTURE AND REACTIVITY OF A NICKEL(II)-TRIPEPTIDE MIMIC OF NICKEL SUPEROXIDE DISMUTASE

    E-Print Network [OSTI]

    Glass, Amanda M.

    2012-08-31T23:59:59.000Z

    The tripeptide asparagine-cysteine-cysteine (NCC) was found by the J. Laurence lab to bind nickel very tightly. In fact, NCC was serendipitously discovered as a metal-abstraction peptide tag (MAP-tag) because it was stripping nickel from a standard...

  4. Nickel-catalyzed coupling reactions and synthetic studies toward ent-dioxepandehydrothyrsiferol via an epoxide-opening cascade

    E-Print Network [OSTI]

    Ng, Sze-Sze

    2008-01-01T23:59:59.000Z

    Nickel-Catalyzed Coupling Reactions. Nickel-catalyzed allene--aldehyde coupling and alkene--aldehyde coupling represent two methods of preparing allylic alcohols. Most asymmetric transition metal-catalyzed methods of ...

  5. Low-Metallicity Inhibition of Type Ia Supernovae and Galactic and Cosmic Chemical Evolution

    E-Print Network [OSTI]

    Chiaki Kobayashi; Takuji Tsujimoto; Ken'ich Nomoto; Izumi Hachisu; Mariko Kato

    1998-06-25T23:59:59.000Z

    We introduce a metallicity dependence of Type Ia supernova (SN Ia) rate into the Galactic and cosmic chemical evolution models. In our SN Ia progenitor scenario, the accreting white dwarf (WD) blows a strong wind to reach the Chandrasekhar mass limit. If the iron abundance of the progenitors is as low as [Fe/H] 1-2, SNe Ia can be found only in the environments where the timescale of metal enrichment is sufficiently short as in starburst galaxies and ellipticals. The low-metallicity inhibition of SNe Ia can shed new light on the following issues: 1) The limited metallicity range of the SN Ia progenitors would imply that ``evolution effects'' are relatively small for the use of high redshift SNe Ia to determine the cosmological parameters. 2) WDs of halo populations are poor producers of SNe Ia, so that the WD contribution to the halo mass is not constrained from the iron abundance in the halo. 3) The abundance patterns of globular clusters and field stars in the Galactic halo lack of SN Ia signatures in spite of their age difference of several Gyrs, which can be explained by the low-metallicity inhibition of SNe Ia. 4) It could also explain why the SN Ia contamination is not seen in the damped Ly\\alpha systems for over a wide range of redshift.

  6. Structure/Function Relationships in Nickel-Peptide Complexes: Impact of the Primary Coordination Sphere on Square-Planar Nickel Chemistry

    E-Print Network [OSTI]

    Krause, Mary Elizabeth

    2011-05-31T23:59:59.000Z

    -cancer therapeutic, whereas nickel generates a catalytic antioxidant. The advantage of this tag is that it is extremely small, is composed of naturally occurring amino acids, and binds metal with unique geometry. Metal binds irreversibly at physiological p...

  7. Fly ash enhanced metal removal process

    SciTech Connect (OSTI)

    Nonavinakere, S. [Plexus Scientific Corp., Annapolis, MD (United States); Reed, B.E. [West Virginia Univ., Morgantown, WV (United States). Dept. of Civil Engineering

    1995-12-31T23:59:59.000Z

    The primary objective of the study was to evaluate the effectiveness of fly ashes from local thermal power plants in the removal of cadmium, nickel, chromium, lead, and copper from aqueous waste streams. Physical and chemical characteristics of fly ashes were determined, batch isotherm studies were conducted. A practical application of using fly ash in treating spent electroless nickel (EN) plating baths by modified conventional precipitation or solid enhanced metal removal process (SEMR) was investigated. In addition to nickel the EN baths also contains completing agents such as ammonium citrate and succinic acid reducing agents such as phosphate and hypophosphite. SEMR experiments were conducted at different pHs, fly ash type and concentrations, and settling times.

  8. Structural transformation of nickel hydroxide films during anodic oxidation

    SciTech Connect (OSTI)

    Crocker, R.W.; Muller, R.H.

    1992-05-01T23:59:59.000Z

    The transformation of anodically formed nickel hydroxide/oxy-hydroxide electrodes has been investigated. A mechanism is proposed for the anodic oxidation reaction, in which the reaction interface between the reduced and oxidized phases of the electrode evolves in a nodular topography that leads to inefficient utilization of the active electrode material. In the proposed nodular transformation model for the anodic oxidation reaction, nickel hydroxide is oxidized to nickel oxy-hydroxide in the region near the metal substrate. Since the nickel oxy-hydroxide is considerably more conductive than the surrounding nickel hydroxide, as further oxidation occurs, nodular features grow rapidly to the film/electrolyte interface. Upon emerging at the electrolyte interface, the reaction boundary between the nickel hydroxide and oxy-hydroxide phases spreads laterally across the film/electrolyte interface, creating an overlayer of nickel oxy-hydroxide and trapping uncharged regions of nickel hydroxide within the film. The nickel oxy-hydroxide overlayer surface facilitates the oxygen evolution side reaction. Scanning tunneling microscopy of the electrode in its charged state revealed evidence of 80 {endash} 100 Angstrom nickel oxy-hydroxide nodules in the nickel hydroxide film. In situ spectroscopic ellipsometer measurements of films held at various constant potentials agree quantitatively with optical models appropriate to the nodular growth and subsequent overgrowth of the nickel oxy-hydroxide phase. A two-dimensional, numerical finite difference model was developed to simulate the current distribution along the phase boundary between the charged and uncharged material. The model was used to explore the effects of the physical parameters that govern the electrode behavior. The ratio of the conductivities of the nickel hydroxide and oxy-hydroxide phases was found to be the dominant parameter in the system.

  9. MUSIC-TYPE ALGORITHM FOR EDDY-CURRENT NONDESTRUC-TIVE EVALUATION OF SMALL DEFECTS IN METAL PLATES

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    MUSIC-TYPE ALGORITHM FOR EDDY-CURRENT NONDESTRUC- TIVE EVALUATION OF SMALL DEFECTS IN METAL PLATES Eddy-Current nondestructive evaluation of metal plates is of interest in a wide range of applications in the lower frequency band (kHz) for eddy-current testing, to retrieve small void defects inside a conducting

  10. Combination nickel foam expanded nickel screen electrical connection supports for solid oxide fuel cells

    DOE Patents [OSTI]

    Draper, Robert; Prevish, Thomas; Bronson, Angela; George, Raymond A.

    2007-01-02T23:59:59.000Z

    A solid oxide fuel assembly is made, wherein rows (14, 25) of fuel cells (17, 19, 21, 27, 29, 31), each having an outer interconnection (20) and an outer electrode (32), are disposed next to each other with corrugated, electrically conducting expanded metal mesh member (22) between each row of cells, the corrugated mesh (22) having top crown portions and bottom portions, where the top crown portion (40) have a top bonded open cell nickel foam (51) which contacts outer interconnections (20) of the fuel cells, said mesh and nickel foam electrically connecting each row of fuel cells, and where there are no more metal felt connections between any fuel cells.

  11. Fabrication of nickel microbump on aluminum using electroless nickel plating

    SciTech Connect (OSTI)

    Watanabe, H.; Honma, H. [Kanto Gakuin Univ., Yokohama, Kanagawa (Japan). Faculty of Engineering

    1997-02-01T23:59:59.000Z

    Fabrication of nickel microbumps on an aluminum electrode using a nickel displacement and a direct nickel plating process was investigated. Electroless nickel plating reaction with hypophosphite as a reducing agent was not initiated on the aluminum substrate, because aluminum does not have catalytic action on the oxidation of hypophosphite. Accordingly, nickel was initially deposited on the aluminum using nickel displacement plating for the initiation of the electroless plating. Nickel bumps on the aluminum electrode were fabricated by treatment of the nickel displacement plating followed by electroless nickel plating. Nickel microbumps also can be formed on the aluminum electrode without the displacement plating process. Activation of the aluminum surface is an indispensable process to initiate electroless nickel plating. Uniform bumps 20 {micro}m wide and 15 {micro}m high with good configuration were obtained by direct nickel plating after being activated with dimethyl amine borane.

  12. A STUDY OF FUNDAMENTAL REACTION PATHWAYS FOR TRANSITION METAL ALKYL COMPLEXES. I. THE REACTION OF A NICKEL METHYL COMPLEX WITH ALKYNES. II. THE MECHANISM OF ALDEHYDE FORMATION IN THE REACTION OF A MOLYBDENUM HYDRIDE WITH MOLYBDENUM ALKYLS

    SciTech Connect (OSTI)

    Huggins, John Mitchell

    1980-06-01T23:59:59.000Z

    I. This study reports the rapid reaction under mild conditions of internal or terminal alkynes with methyl (acetyl~ acetonato) (triphenylphosphine) nickel (1) in either aromatic or ether solvents. In all cases vinylnickel products 2 are formed by insertion of the alkyne into the nickel=methyl bond. These complexes may be converted into a variety of organic products (e.g. alkenes, esters, vinyl halides) by treatment with appropriate reagents. Unsymmetrical alkynes give selectively the one regioisomer with the sterically largest substituent next to the nickel atom. In order to investigate the stereochemistry of the initial insertion, a x-ray diffraction study of the reaction of 1 with diphenylacetylene was carried out. This showed that the vinylnickel complex formed by overall trans insertion was the product of the reaction. Furthermore, subsequent slow isomerization of this complex, to a mixture of it and the corresponding cis isomer, demonstrated that this trans addition product is the kinetic product of the reaction. In studies with other alkynes, the product of trans addition was not always exclusively (or even predominantly) formed, but the ratio of the stereoisomers formed kinetically was substantially different from the thermodynamic ratio. Isotope labeling, added phosphine, and other experiments have allowed us to conclude that the mechanism of this reaction does involve initial cis addition. However, a coordinatively unsaturated vinylnickel complex is initially formed which can undergo rapid, phosphine-catalyzed cis-trans isomerization in competition with its conversion to the isolable phosphine-substituted kinetic reaction products. II. The reaction of CpMo(CO){sub 3}H (1a) with CpMo(CO){sub 3}R (2, R= CH{sub 3}, C{sub 2}H{sub 5}) at 50{degrees} C in THF gives the aldehyde RCHO and the dimers [CpMo(CO){sub 3}]{sub 2} (3a) and [CpMo(CO){sub 2}]{sub 2} (4a). Labeling one of the reactants with a methylcyclopentadienyl ligand it was possible to show that the mixed dimers MeCpMo(CO){sub 3}-(CO){sub 3}MoCp (3b) and MeCpMo(CO){sub 2}{triple_bond}(CO){sub 2}MoCp (4b) are the predominant kinetic products of the reaction. Additionally labeling the carbonyl ligands of 1a with {sup 13}CO led to the conclusion that all three of the carbonyl ligands in 1a end up in the tetracarbonyl dimers 4a if the reaction is carried out under a continuous purge of argon Trapping studies failed to find any evidence for the intermediacy of either [CpMo(CO){sub 3}]{sup -} or [CpMo(CO){sub 3}]{sup +} in this reaction. A mechanism is proposed that involves the initial migration of the alkyl ligand in 2 to CO forming an unsaturated acyl complex which reacts with 1a to give a binuclear complex containing a three center-two electron Mo-H-Mo bond. This complex then selectively looses a carbonyl from the acyl molybdenum, migrates the hydride to that same metal, and forms a metal-metal bond. This binuclear complex with the hydride and acyl ligands on one metal reductively eliminates aldehyde, and migrates a carbonyl ligand, to give 4a directly. The other product 3a is formed by addition of two molecules of free CO to 4a.

  13. Photoelectron spectroscopy of nickel group dimers: Ni:, PdF, and Ptc Joe Ho,`) Mark L. Polak,b) Kent M. Ervin,C) and W. C. Lineberger

    E-Print Network [OSTI]

    Lineberger, W. Carl

    Photoelectron spectroscopy of nickel group dimers: Ni:, PdF, and Ptc Joe Ho,`) Mark L. Polak are tentatively assigned.Comparison of the nickel group dimers to the coinage metal dimers shedslight on the d orbital contribution to the metal bonding in the nickel group dimers. I. INTRODUCTION Spectroscopicstudy

  14. Electronic Structure of Nickel(II) and Zinc(II) Borohydrides from Spectroscopic Measurements and Computational Modeling

    E-Print Network [OSTI]

    Weston, Ken

    Electronic Structure of Nickel(II) and Zinc(II) Borohydrides from Spectroscopic Measurements materials for solid phase hydrogen storage. In some cases, nickel and other transition metals can play a role in the catalytic decomposition of these solid phase hydrides.6 Nickel exhibits rich and varied

  15. Cleavage of Carbon-Carbon Bonds in Alkyl Cyanides Using Nickel(0)

    E-Print Network [OSTI]

    Jones, William D.

    Cleavage of Carbon-Carbon Bonds in Alkyl Cyanides Using Nickel(0) Juventino J. Garci´a,*, Alma Are of alkyl cyanides afforded nickel(0) compounds of the type [(dippe)Ni(2 -RCN)], where R ) Me, Et, Pr, i Pr cyanides using [(dippe)NiH]2, leading to the formation of an 2- nitrile complex of nickel(0), which

  16. An electrochemical route for making porous nickel oxide electrochemical capacitors

    SciTech Connect (OSTI)

    Srinivasan, V.; Weidner, J.W. [Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemical Engineering

    1997-08-01T23:59:59.000Z

    Porous nickel oxide films were prepared by electrochemically precipitating nickel hydroxide and heating the hydroxide in air at 300 C. The resulting nickel oxide films behave as an electrochemical capacitor with a specific capacitance of 59 F/g electrode material. These nickel oxide films maintain high utilization at high rates of discharge (i.e., high power density) and have excellent cycle life. Porous cobalt oxide films were also synthesized. Although the specific capacitances of these films are approximately one-fifth that of the nickel oxide films, the results demonstrate the versatility of fabricating a wide range of porous metal oxide films using this electrochemical route for use in capacitor applications. Electrochemical capacitors have generated wide interest in recent years for use in high power applications (e.g., in a hybrid electric vehicle, where they are expected to work in conjunction with a conventional battery).

  17. Waste water treatment and metal recovery

    E-Print Network [OSTI]

    Braun, Paul

    Waste water treatment and metal recovery Nickel catalysts for hydrogen production Nickel and single versions of which contained cobalt, chromium, carbon, molybdenum, tungsten, and nickel. In 1911 and 1912% on their stainless steel production. The company paid sizable dividends to its owners until it was dissolved

  18. Respiration of metal (hydr)oxides by Shewanella and Geobacter: a key role for multihaem c-type cytochromes

    SciTech Connect (OSTI)

    Shi, Liang; Squier, Thomas C.; Zachara, John M.; Fredrickson, Jim K.

    2007-07-01T23:59:59.000Z

    Dissimilatory reduction of metal (e.g. Fe, Mn) (hydr)oxides represents a challenge for microorganisms, as their cell envelopes are impermeable to metal (hydr)oxides that are poorly soluble in water. To overcome this physical barrier, the Gram-negative bacteria Shewanella oneidensis MR-1 and Geobactersulfurreducens have developed electron transfer (ET) strategies that require multihaem c-type cytochromes (c-Cyts). In S. oneidensis MR-1, multihaem c-Cyts CymA and MtrA are believed to transfer electrons from the inner membrane quinone/quinol pool through the periplasm to the outer membrane. The type II secretion system of S. oneidensis MR-1 has been implicated in the reduction of metal (hydr)oxides, most likely by translocating decahaem c-Cyts MtrC and OmcA across outer membrane to the surface of bacterial cells where they form a protein complex. The extracellular MtrC and OmcA can directly reduce solid metal (hydr)oxides. Likewise, outer membrane multihaem c-Cyts OmcE and OmcS of G. sulfurreducens are suggested to transfer electrons from outer membrane to type IV pili that are hypothesized to relay the electrons to solid metal (hydr)oxides. Thus, multihaem c-Cyts play critical roles in S. oneidensis MR-1-and G. sulfurreducens-mediated dissimilatory reduction of solid metal (hydr)oxides by facilitating ET across the bacterial cell envelope.

  19. Switchable mirrors based on nickel-magnesium films

    SciTech Connect (OSTI)

    Richardson,Thomas J.; Slack, Jonathan L.; Armitage, Robert D.; Kostecki, Robert; Farangis, Baker; Rubin, Michael D.

    2001-01-16T23:59:59.000Z

    A new type of electrochromic mirror electrode based on reversible uptake of hydrogen in nickel magnesium alloy films is reported. Thin,magnesium-rich Ni-Mg films prepared on glass substrates by cosputtering from Ni and Mg targets are mirror-like in appearance and have low visible transmittance. Upon exposure to hydrogen gas or on reduction in alkaline electrolyte, the films take up hydrogen and become transparent. When hydrogen is removed, the mirror properties are recovered. The transition is believed to result from reversible formation of Mg2NiH4 and MgH2. A thin overlayer of palladium was found to enhance the kinetics of hydrogen insertion and extraction,and to protect the metal surface against oxidation.

  20. On the role of mass-transport in electrodeposition of nickel-iron alloys

    SciTech Connect (OSTI)

    Hessami, S.; Tobias, C.W.

    1990-11-01T23:59:59.000Z

    Despite the extensive use of nickel-iron, the mechanism of codeposition is not well understood. The interactions occurring during codeposition are such that nickel deposition is inhibited in the presence of iron, and the resulting alloy deposit has a much higher iron to nickel ratio than the electrolyte. This type of interactive deposition is an example of what has been termed anomalous codeposition, which is also used in describing electrodeposition of iron group elements (iron, cobalt, and nickel) with each other, or with zinc, tin, lead, and cadmium. In Chapter 2 of this thesis, a critical review of the literature is presented. Various interpretations and proposed mechanisms for the anomalous deposition of the iron-group alloys, particularly nickel-iron, is discussed. The major objectives of this review are to provide unambiguous definitions for various codeposition schemes, including the anomalous deposition itself, reflect on some of the more widely accepted hypothesis describing this phenomenon, and summarize the more recent results of other investigators in the field. To elucidate the electrodeposition mechanism of magnetic alloys, a mathematical model is developed in Chapter 3. The model is applied to a rotating disk electrode system, with well understood hydrodynamics, and incorporates homogeneous reactions of metal-hydroxide complexes. In Chapter 4, the model is further used to investigate the effect of buffering agents which are commonly used in electroplating baths. Our understanding of the mechanism of electrode processes depends on the accurate measurement of these concentrations. The interfacial value of pH is particularly important for electrodeposition of the iron-group alloys. In Chapters 5 and 6, an in-situ nonintrusive technique for surface pH measurement is investigated by theoretical and experimental methods.

  1. Computersimulationen martensitischer Phasenubergange in Eisen-Nickel-und Nickel-Aluminium-Legierungen

    E-Print Network [OSTI]

    Entel, P.

    Computersimulationen martensitischer Phasen¨uberg¨ange in Eisen-Nickel- und Nickel Molekulardynamik-Simulationen der martensitischen Umwandlungen in Eisen-Nickel- und Nickel Anpassung parametrisierter Funktionen an experimentelle Daten von Eisen, Nickel, Aluminium und NiAl gewonnen

  2. Thermoelectric material including a multiple transition metal-doped type I clathrate crystal structure

    DOE Patents [OSTI]

    Yang, Jihui (Lakeshore, CA); Shi, Xun (Troy, MI); Bai, Shengqiang (Shanghai, CN); Zhang, Wenqing (Shanghai, CN); Chen, Lidong (Shanghai, CN); Yang, Jiong (Shanghai, CN)

    2012-01-17T23:59:59.000Z

    A thermoelectric material includes a multiple transition metal-doped type I clathrate crystal structure having the formula A.sub.8TM.sub.y.sub.1.sup.1TM.sub.y.sub.2.sup.2 . . . TM.sub.y.sub.n.sup.nM.sub.zX.sub.46-y.sub.1.sub.-y.sub.2.sub.- . . . -y.sub.n.sub.-z. In the formula, A is selected from the group consisting of barium, strontium, and europium; X is selected from the group consisting of silicon, germanium, and tin; M is selected from the group consisting of aluminum, gallium, and indium; TM.sup.1, TM.sup.2, and TM.sup.n are independently selected from the group consisting of 3d, 4d, and 5d transition metals; and y.sub.1, y.sub.2, y.sub.n and Z are actual compositions of TM.sup.1, TM.sup.2, TM.sup.n, and M, respectively. The actual compositions are based upon nominal compositions derived from the following equation: z=8q.sub.A-|.DELTA.q.sub.1|y.sub.1-|.DELTA.q.sub.2|y.sub.2- . . . -|.DELTA.q.sub.n|y.sub.n, wherein q.sub.A is a charge state of A, and wherein .DELTA.q.sub.1, .DELTA.q.sub.2, .DELTA.q.sub.n are, respectively, the nominal charge state of the first, second, and n-th TM.

  3. Influences on the oceanic biogeochemical cycling of the hybrid-type metals, cobalt, iron, and manganese

    E-Print Network [OSTI]

    Noble, Abigail Emery

    2012-01-01T23:59:59.000Z

    Trace metal cycling is one of many processes that influence ocean ecosystem dynamics. Cobalt, iron, and manganese are redox active trace metal micro-nutrients with oceanic distributions that are influenced by both biological ...

  4. Experimental and Theoretical Examination of C-CN Bond Activation of Benzonitrile Using Zerovalent Nickel

    E-Print Network [OSTI]

    Jones, William D.

    Nickel Tu¨lay A. Ates¸in, Ting Li, Se´bastien Lachaize, Juventino J. García, and William D. JonesVersidad Nacional Auto´noma de Me´xico, Me´xico City, Me´xico D. F. 04510 ReceiVed May 9, 2008 The nickel(0 these transition states, those for the migration of the nickel metal between the carbon-carbon bonds of the phenyl

  5. Influence of Cobalt Nanoparticles' Incorporation on the Magnetic Properties of the Nickel Nanofibers: Cobalt-Doped Nickel Nanofibers Prepared by Electrospinning

    E-Print Network [OSTI]

    Kim, Bongsoo

    , magnetic refrigeration systems, and contrast enhancement in magnetic resonance imaging carriers for drugsInfluence of Cobalt Nanoparticles' Incorporation on the Magnetic Properties of the Nickel, 2009 Among the common ferromagnetic metals, cobalt has distinct magnetic properties, so incorporation

  6. crystal nickel a hree dimension

    E-Print Network [OSTI]

    Braun, Paul

    Zhenting 1 Department 2 Departmen ABSTRACT This pape crystal nickel a hree dimension photonic cryst polystyrene op silicon chips, volume fraction can be controlle nickel structure hen sacrificed volume fraction reports microm crystal structur or alumina she nickel microca microstructure further electrop volume

  7. 888Metal and silicate particles including nanoparticles are present in electronic cigarette cartomizer fluid and aserosol. 

    E-Print Network [OSTI]

    Talbot, Prue

    2013-01-01T23:59:59.000Z

    Metal and Silicate Particles Including Nanoparticles Areiron, nickel, aluminum, and silicate and nanoparticles (,100The presence of metal and silicate particles in cartomizer

  8. Revealing a universal planet-metallicity correlation for planets of different solar-type stars

    SciTech Connect (OSTI)

    Wang, Ji; Fischer, Debra A., E-mail: ji.wang@yale.edu [Department of Astronomy, Yale University, New Haven, CT 06511 (United States)

    2015-01-01T23:59:59.000Z

    The metallicity of exoplanet systems serves as a critical diagnostic of planet formation mechanisms. Previous studies have demonstrated the planet–metallicity correlation for large planets (R{sub P} ? 4 R{sub E}); however, a correlation has not been found for smaller planets. With a sample of 406 Kepler objects of interest whose stellar properties are determined spectroscopically, we reveal a universal planet–metallicity correlation: not only gas-giant planets (3.9 R{sub E} metal-rich stars. The planet occurrence rates of gas-giant planets, gas-dwarf planets, and terrestrial planets are 9.30{sub ?3.04}{sup +5.62}, 2.03{sub ?0.26}{sup +0.29}, and 1.72{sub ?0.17}{sup +0.19} times higher for metal-rich stars than for metal-poor stars, respectively.

  9. Review of metallic surface treatments for corrosion mitigation. Final report

    SciTech Connect (OSTI)

    Hock, V.F.; Rigsbee, J.M.; Boy, J.H.

    1984-09-01T23:59:59.000Z

    Innovative metallic surface treatments for corrosion protection of facility systems and components were reviewed, including plasma spraying, electroless nickel plating, and ion plating. The work is part of the U.S. Army Corps of Engineers effort to find coatings with properties superior to conventional polymeric types. The three methods were judged for adhesion, corrosion and erosion resistance, rust mitigation, and possible use in electromagnetic shielding. A brief description of physics is given for these methods along with case studies documenting their performance. Such metallic treatments may be a cost-effective, long-term corrosion protection alternative to traditional polymeric coatings, depending on component design and purpose.

  10. Structural Basis of Low-Affinity Nickel Binding to the Nickel-Responsive Transcription Factor NikR from Escherichia coli

    SciTech Connect (OSTI)

    Phillips, C.; Schreiter, E; Stultz, C; Drennan, C

    2010-01-01T23:59:59.000Z

    Escherichia coli NikR regulates cellular nickel uptake by binding to the nik operon in the presence of nickel and blocking transcription of genes encoding the nickel uptake transporter. NikR has two binding affinities for the nik operon: a nanomolar dissociation constant with stoichiometric nickel and a picomolar dissociation constant with excess nickel [Bloom, S. L., and Zamble, D. B. (2004) Biochemistry 43, 10029-10038; Chivers, P. T., and Sauer, R. T. (2002) Chem. Biol. 9, 1141-1148]. While it is known that the stoichiometric nickel ions bind at the NikR tetrameric interface [Schreiter, E. R., et al. (2003) Nat. Struct. Biol. 10, 794-799; Schreiter, E. R., et al. (2006) Proc. Natl. Acad. Sci. U.S.A. 103, 13676-13681], the binding sites for excess nickel ions have not been fully described. Here we have determined the crystal structure of NikR in the presence of excess nickel to 2.6 {angstrom} resolution and have obtained nickel anomalous data (1.4845 {angstrom}) in the presence of excess nickel for both NikR alone and NikR cocrystallized with a 30-nucleotide piece of double-stranded DNA containing the nik operon. These anomalous data show that excess nickel ions do not bind to a single location on NikR but instead reveal a total of 22 possible low-affinity nickel sites on the NikR tetramer. These sites, for which there are six different types, are all on the surface of NikR, and most are found in both the NikR alone and NikR-DNA structures. Using a combination of crystallographic data and molecular dynamics simulations, the nickel sites can be described as preferring octahedral geometry, utilizing one to three protein ligands (typically histidine) and at least two water molecules.

  11. Bulk and surface half-metallicity: The case of D0{sub 3}-type Mn{sub 3}Ge

    SciTech Connect (OSTI)

    Liu, Hao; Gao, G. Y., E-mail: guoying-gao@mail.hust.edu.cn; Hu, Lei; Ni, Yun; Zu, Fengxia; Zhu, Sicong; Wang, Shuling; Yao, K. L. [School of Physics and Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2014-01-21T23:59:59.000Z

    Motivated by the experimental realization of D0{sub 22}-type Mn{sub 3}Ge (001) films [Kurt et al. Appl. Phys. Lett. 101, 132410 (2012)] and the structural stability of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge [Zhang et al. J. Phys.: Condens. Matter 25, 206006 (2013)], we use the first-principles calculations based on the full potential linearized augmented plane-wave method to investigate the electronic and magnetic properties of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge and its (001) surface. We show that bulk D0{sub 3}-Mn{sub 3}Ge is a half-metallic ferromagnet with the minority-spin energy gap of 0.52?eV and the magnetic moment of 1.00??{sub B} per formula unit. The bulk half-metallicity is preserved at the pure Mn-terminated (001) surface due to the large exchange split, but the MnGe-terminated (001) surface destroys the bulk half-metallicity. We also reveal that the surface stabilities are comparable between the D0{sub 3}-Mn{sub 3}Ge (001) and the experimental D0{sub 22}-Mn{sub 3}Ge (001), which indicates the feasibility to grow the Mn{sub 3}Ge (001) films with D0{sub 3} phase other than D0{sub 22} one. The surface half-metallicity and stability make D0{sub 3}-Mn{sub 3}Ge a promising candidate for spintronic applications.

  12. Attack polish for nickel-base alloys and stainless steels

    DOE Patents [OSTI]

    Not Available

    1980-05-28T23:59:59.000Z

    A chemical attack polish and polishing procedure for use on metal surfaces such as nickel base alloys and stainless steels is described. The chemical attack polich comprises FeNO/sub 3/, concentrated CH/sub 3/COOH, concentrated H/sub 2/SO/sub 4/ and H/sub 2/O. The polishing procedure includes saturating a polishing cloth with the chemical attack polish and submicron abrasive particles and buffing the metal surface.

  13. Method of polishing nickel-base alloys and stainless steels

    DOE Patents [OSTI]

    Steeves, Arthur F. (Schenectady, NY); Buono, Donald P. (Schenectady, NY)

    1981-01-01T23:59:59.000Z

    A chemical attack polish and polishing procedure for use on metal surfaces such as nickel base alloys and stainless steels. The chemical attack polish comprises Fe(NO.sub.3).sub.3, concentrated CH.sub.3 COOH, concentrated H.sub.2 SO.sub.4 and H.sub.2 O. The polishing procedure includes saturating a polishing cloth with the chemical attack polish and submicron abrasive particles and buffing the metal surface.

  14. Attack polish for nickel-base alloys and stainless steels

    DOE Patents [OSTI]

    Steeves, Arthur F. (Schenectady, NY); Buono, Donald P. (Schenectady, NY)

    1983-01-01T23:59:59.000Z

    A chemical attack polish and polishing procedure for use on metal surfaces such as nickel base alloys and stainless steels. The chemical attack polish comprises Fe(NO.sub.3).sub.3, concentrated CH.sub.3 COOH, concentrated H.sub.2 SO.sub.4 and H.sub.2 O. The polishing procedure includes saturating a polishing cloth with the chemical attack polish and submicron abrasive particles and buffing the metal surface.

  15. CO2/oxalate Cathodes as Safe and Efficient Alternatives in High Energy Density Metal-Air Type Rechargeable Batteries

    E-Print Network [OSTI]

    Nemeth, Karoly

    2013-01-01T23:59:59.000Z

    We present theoretical analysis on why and how rechargeable metal-air type batteries can be made significantly safer and more practical by utilizing CO2/oxalate conversions instead of O2/peroxide or O2/hydroxide ones, in the positive electrode. Metal-air batteries, such as the Li-air one, may have very large energy densities, comparable to that of gasoline, theoretically allowing for long range all-electric vehicles. There are, however, still significant challenges, especially related to the safety of their underlying chemistries, the robustness of their recharging and the need of supplying high purity O2 from air to the battery. We point out that the CO2/oxalate reversible electrochemical conversion is a viable alternative of the O2-based ones, allowing for similarly high energy density and almost identical voltage, while being much safer through the elimination of aggressive oxidant peroxides and the use of thermally stable, non-oxidative and environmentally benign oxalates instead.

  16. PROSPECTING IN LATE-TYPE DWARFS: A CALIBRATION OF INFRARED AND VISIBLE SPECTROSCOPIC METALLICITIES OF LATE K AND M DWARFS SPANNING 1.5 dex

    SciTech Connect (OSTI)

    Mann, Andrew W.; Hilton, Eric J. [Institute for Astronomy, University of Hawai'i, 2680 Woodlawn Dr, Honolulu, HI 96822 (United States); Brewer, John M. [Department of Astronomy, Yale University, New Haven, CT 06511 (United States); Gaidos, Eric [Department of Geology and Geophysics, University of Hawai'i, 1680 East-West Road, Honolulu, HI 96822 (United States); Lepine, Sebastien [Department of Astrophysics, American Museum of Natural History, New York, NY 10024 (United States)

    2013-02-01T23:59:59.000Z

    Knowledge of late K and M dwarf metallicities can be used to guide planet searches and constrain planet formation models. However, the determination of metallicities of late-type stars is difficult because visible wavelength spectra of their cool atmospheres contain many overlapping absorption lines, preventing the measurement of equivalent widths. We present new methods, and improved calibrations of existing methods, to determine metallicities of late K and M dwarfs from moderate resolution (1300 < R < 2000) visible and infrared spectra. We select a sample of 112 wide binary systems that contain a late-type companion to a solar-type primary star. Our sample includes 62 primary stars with previously published metallicities, as well as 50 stars with metallicities determined from our own observations. We use our sample to empirically determine which features in the spectrum of the companion are best correlated with the metallicity of the primary. We find {approx_equal}120 features in K and M dwarf spectra that are useful for predicting metallicity. We derive metallicity calibrations for different wavelength ranges, and show that it is possible to get metallicities reliable to <0.10 dex using either visible, J-, H-, or K-band spectra. We find that the most accurate metallicities derived from visible spectra requires the use of different calibrations for early-type (K5.5-M2) and late-type (M2-M6) dwarfs. Our calibrations are applicable to dwarfs with metallicities of -1.04 < [Fe/H] <+0.56 and spectral types from K7 to M5. Lastly, we use our sample of wide binaries to test and refine existing calibrations to determine M dwarf metallicities. We find that the {zeta} parameter, which measures the ratio of TiO can CaH bands, is correlated with [Fe/H] for super-solar metallicities, and {zeta} does not always correctly identify metal-poor M dwarfs. We also find that existing calibrations in the K and H bands are quite reliable for stars with [Fe/H] >-0.5, but are less useful for more metal-poor stars.

  17. Infiltration of nickel into alumina compact by electrodeposition

    SciTech Connect (OSTI)

    Hirata, Yoshihiro; Kyoda, Hideharu; Iwamoto, Takayuki [Kagoshima Univ. (Japan)

    1995-09-01T23:59:59.000Z

    Ni metal was electrodeposited into pores of an alumina compact in the aqueous solution of nickel nitrate/urea/ethylene glycol/ammonium sulfate. The Ni{sup 2+} ions in pores of the alumina compact deposited in proportion to t{sup 0.45}-t{sup 0.61} of deposition time (t) on Au electrode sputtered on the alumina surface. The deposition rate of Ni was higher for direct current than pulsed current Nickel grew dendritically in the alumina pores.

  18. On the origin of the luminosity - metallicity relation for late-type galaxies: Spirals to irregulars transition

    E-Print Network [OSTI]

    L. S. Pilyugin; F. Ferrini

    2000-01-05T23:59:59.000Z

    We consider the roles of two widely invoked mechanisms for the metallicity-luminosity correlation among late-type galaxies: higher astration level and decreasing efficiency of heavy-element loss with increasing luminosity. We find that both mechanisms contribute about equally to the range in oxygen abundance between low (logL_B = 8) and high (logL_B = 10.5) luminosity galaxies. We also consider the transition from spirals to irregulars, finding that both the oxygen abundance deficiency (indicating the degree of mass exchange between a galaxy and its environment) and the gas fraction vary smoothly along the sequence. Thus we find no "irregular versus spiral dichotomy".

  19. Dispersion enhanced metal/zeolite catalysts

    DOE Patents [OSTI]

    Sachtler, W.M.H.; Tzou, M.S.; Jiang, H.J.

    1987-03-31T23:59:59.000Z

    Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

  20. Hydrodesulfurization Properties of Cobalt–nickel Phosphide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Cobalt–nickel Phosphide Catalysts:Ni-rich Materials are Highly Active. Hydrodesulfurization Properties of Cobalt–nickel Phosphide Catalysts:Ni-rich Materials are...

  1. INVESTIGATING THE POTENTIAL DILUTION OF THE METAL CONTENT OF HOT GAS IN EARLY-TYPE GALAXIES BY ACCRETED COLD GAS

    SciTech Connect (OSTI)

    Su, Yuanyuan; Irwin, Jimmy A., E-mail: ysu@crimson.ua.edu [Department of Physics and Astronomy, University of Alabama, Box 870324, Tuscaloosa, AL 35487 (United States)

    2013-03-20T23:59:59.000Z

    The measured emission-weighted metal abundance of the hot gas in early-type galaxies has been known to be lower than theoretical expectations for 20 years. In addition, both X-ray luminosity and metal abundance vary significantly among galaxies of similar optical luminosities. This suggests some missing factors in the galaxy evolution process, especially the metal enrichment process. With Chandra and XMM-Newton, we studied 32 early-type galaxies (kT {approx}< 1 keV) covering a span of two orders of L{sub X,gas}/L{sub K} to investigate these missing factors. Contrary to previous studies that X-ray faint galaxies show extremely low Fe abundance ({approx}0.1 Z{sub Sun }), nearly all galaxies in our sample show an Fe abundance at least 0.3 Z{sub Sun }, although the measured Fe abundance difference between X-ray faint and X-ray bright galaxies remains remarkable. We investigated whether this dichotomy of hot gas Fe abundances can be related to the dilution of hot gas by mixing with cold gas. With a subset of 24 galaxies in this sample, we find that there is virtually no correlation between hot gas Fe abundances and their atomic gas content, which disproves the scenario that the low metal abundance of X-ray faint galaxies might be a result of the dilution of the remaining hot gas by pristine atomic gas. In contrast, we demonstrate a negative correlation between the measured hot gas Fe abundance and the ratio of molecular gas mass to hot gas mass, although it is unclear what is responsible for this apparent anti-correlation. We discuss several possibilities including that externally originated molecular gas might be able to dilute the hot gas metal content. Alternatively, the measured hot gas Fe abundance may be underestimated due to more complex temperature and abundance structures and even a two-temperature model might be insufficient to reflect the true value of the emission weighted mean Fe abundance.

  2. Contact Resistance of Tri-layer Graphene Side Contacted with Nickel Jason Giuliani,1-3

    E-Print Network [OSTI]

    UG-34 Contact Resistance of Tri-layer Graphene Side Contacted with Nickel Electrodes.S.A. High contact resistance is a key problem in graphene-type device performance. In order to create, the contact properties of graphene devices requires further research. Nickel's high work-function and contact

  3. Mechanical Properties of Controlled Memory and Superelastic Nickel-Titanium Wires Used in the Manufacture

    E-Print Network [OSTI]

    Zheng, Yufeng

    Mechanical Properties of Controlled Memory and Superelastic Nickel-Titanium Wires Used was to investigate the structure and mechanical properties of newly devel- oped controlled memory (CM) nickel-titanium transformation behavior of both types of wires were examined by x-ray energy dispersive spectroscopy

  4. Mechanisms of nickel sorption by a bacteriogenic birnessite

    E-Print Network [OSTI]

    Pena, J.

    2010-01-01T23:59:59.000Z

    P. A. (2001) Processes of nickel and cobalt uptake by achemistry of cobalt and nickel in lithiophorite and asbolaneMechanisms of nickel sorption by a bacteriogenic birnessite

  5. JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 13, NO. 5, OCTOBER 2004 791 Electroplated Metal Microstructures Embedded

    E-Print Network [OSTI]

    of multiwafer, MEMS devices. [1276] Index Terms--Copper, encapsulation, micromachining, nickel alloys, permalloy metallization of electroplated materials in polymer micromolds [9]. Electrodeposition has proven

  6. Magnetism in metal-organic capsules

    SciTech Connect (OSTI)

    Atwood, Jerry L.; Brechin, Euan K; Dalgarno, Scott J.; Inglis, Ross; Jones, Leigh F.; Mossine, Andrew; Paterson, Martin J.; Power, Nicholas P.; Teat, Simon J.

    2010-01-07T23:59:59.000Z

    Nickel and cobalt seamed metal-organic capsules have been isolated and studied using structural, magnetic and computational approaches. Antiferromagnetic exchange in the Ni capsule results from coordination environments enforced by the capsule framework.

  7. Complexation effects in the electrodeposition of nickel-iron alloys

    SciTech Connect (OSTI)

    Huynh, T.; Harris, T. [Univ. of Tulsa, OK (United States)

    1995-12-01T23:59:59.000Z

    The nickel-iron alloy electrodeposition system exhibits a phenomenon known as anomalous codeposition, where the less noble metal (Fe) deposits preferentially to the more noble metal (Ni). One explanation for this behavior is that ferrous hydroxide adsorbs to the surface of the electrode and inhibits the electrodeposition of the nickel. This mechanism is being tested through the use of {open_quotes}selective{close_quotes} complexing agents for Ni{sup 2+}, Fe{sup 2+} and Fe{sup 3+}. The complexation behavior of these ions with acetate, chloroacetate,and aminoacetate ions is being characterized by potentiometric titration and polarographic measurements. The effect of these complexants on the electrodeposition of the alloys is also being studied.

  8. Complexation effects in the electrodeposition of nickel-zinc alloys

    SciTech Connect (OSTI)

    Melville, A.; Harris, T. [Univ. of Tulsa, OK (United States)

    1995-12-01T23:59:59.000Z

    The nickel-zinc alloy electrodeposition system exhibits a phenomenon known as anomalous codeposition, where the less noble metal (Zn) deposits preferentially to the more noble metal (Ni). One explanation for this behavior is that zinc hydroxide adsorbs to the surface of the electrode and inhibits the electrodeposition of the nickel. This mechanism is being tested through the use of {open_quotes}selective{close_quotes} complexing agents for Ni{sup 2+} and Zn{sup 2+}. The complexation behavior of these ions with citrate, aspartate and pyrophosphate ions is being characterized by potentiometric titration and polarographic measurements. The effect of these complexants on the electrodeposition of the alloys is also being studied.

  9. Biosorption of Lead and Nickel by Biomass of Marine Algae

    E-Print Network [OSTI]

    Volesky, Bohumil

    Biosorption of Lead and Nickel by Biomass of Marine Algae Z.R. Holan and B. Volesky" Department 22, 1993 Screening tests of different marine algae biomass types revealed a high passive biosorptive uptake of lead up to 270 mg Pb/g of biomass in some brown marine algae. Members of the order Fucales

  10. Nickel Sequestration in a Kaolinite-Humic Acid Complex

    E-Print Network [OSTI]

    Sparks, Donald L.

    Nickel Sequestration in a Kaolinite-Humic Acid Complex M A A R T E N N A C H T E G A A L * A N D D (with 2 carbon atoms at an average radial distance of 2.85 Å). A Ni-Al LDH precipitate phase was formed and otherfirstrowtransitionmetalsintostablesurfaceprecipitates is an important sequestration pathway for toxic metals in the environment, despite the presence

  11. Non-Sintered Nickel Electrode

    DOE Patents [OSTI]

    Bernard, Patrick (Massy, FR); Dennig, Corinne (Asnieres sur Seine, FR); Cocciantelli, Jean-Michel (Bordeaux, FR); Alcorta, Jose (Bordeaux, FR); Coco, Isabelle (Dax, FR)

    2002-01-01T23:59:59.000Z

    A non-sintered nickel electrode contains a conductive support and a paste comprising an electrochemically active material containing nickel hydroxide and a binder which is a mixture of an elastomer and a crystalline polymer. The proportion of the elastomer is in the range 25% to 60% by weight of the binder and the proportion of the crystalline polymer is in the range 40% to 75% by weight of the binder.

  12. High Dispersion Spectroscopy of Solar-type Superflare Stars. I. Temperature, Surface Gravity, Metallicity, and $v \\sin i$

    E-Print Network [OSTI]

    Notsu, Yuta; Maehara, Hiroyuki; Notsu, Shota; Shibayama, Takuya; Nogami, Daisaku; Shibata, Kazunari

    2014-01-01T23:59:59.000Z

    We conducted high dispersion spectroscopic observations of 50 superflare stars with Subaru/HDS, and measured the stellar parameters of them. These 50 targets were selected from the solar-type (G-type main sequence) superflare stars that we had discovered from the Kepler photometric data. As a result of these spectroscopic observations, we found that more than half (34 stars) of our 50 targets have no evidence of binary system. We then estimated effective temperature ($T_{\\rm{eff}}$), surface gravity ($\\log g$), metallicity ([Fe/H]), and projected rotational velocity ($v\\sin i$) of these 34 superflare stars on the basis of our spectroscopic data. The accuracy of our estimations is higher than that of Kepler Input Catalog (KIC) values, and the differences between our values and KIC values ($(\\Delta T_{\\rm{eff}})_{\\rm{rms}} \\sim 219$K, $(\\Delta \\log g)_{\\rm{rms}} \\sim 0.37$ dex, and $(\\Delta\\rm{[Fe/H]})_{\\rm{rms}} \\sim 0.46$ dex) are comparable to the large uncertainties and systematic differences of KIC values ...

  13. PROBING THE LOW-REDSHIFT STAR FORMATION RATE AS A FUNCTION OF METALLICITY THROUGH THE LOCAL ENVIRONMENTS OF TYPE II SUPERNOVAE

    SciTech Connect (OSTI)

    Stoll, R.; Stanek, K. Z.; Pogge, R. W. [Department of Astronomy, Ohio State University, 140 West 18th Avenue, Columbus, OH 43210-1173 (United States); Prieto, J. L. [Department of Astrophysical Sciences, Princeton University, 4 Ivy Lane, Peyton Hall, Princeton, NJ 08544 (United States)

    2013-08-10T23:59:59.000Z

    Type II supernovae (SNe) can be used as a star formation tracer to probe the metallicity distribution of global low-redshift star formation. We present oxygen and iron abundance distributions of Type II SN progenitor regions that avoid many previous sources of bias. Because iron abundance, rather than oxygen abundance, is of key importance for the late stage evolution of the massive stars that are the progenitors of core-collapse supernovae, and because iron enrichment lags oxygen enrichment, we find a general conversion from oxygen abundance to iron abundance. The distributions we present here are the best yet observational standard of comparison for evaluating how different classes of supernovae depend on progenitor metallicity. We spectroscopically measure the gas-phase oxygen abundance near a representative subsample of the hosts of Type II SNe from the first-year Palomar Transient Factory (PTF) SN search, using a combination of Sloan Digital Sky Survey (SDSS) spectra near the SN location (9 hosts) and new longslit spectroscopy (25 hosts). The median metallicity of these 34 hosts at or near the SN location is 12+log(O/H) = 8.65, with a median error of 0.09. The median host galaxy stellar mass from fits to SDSS photometry is 10{sup 9.9} M{sub Sun }. They do not show a systematic offset in metallicity or mass from a redshift-matched sample of the MPA/JHU value-added catalog. In contrast to previous SN host metallicity studies, this sample is drawn from a single survey. It is also drawn from an areal rather than a targeted survey, so SNe in the lowest-mass galaxies are not systematically excluded. Indeed, the PTF SN search has a slight bias toward following up transients in low mass galaxies. The progenitor region metallicity distribution we find is statistically indistinguishable from the metallicity distribution of Type II SN hosts found by targeted surveys and by samples from multiple surveys with different selection functions. Using the relationship between iron and oxygen abundances found for Milky Way disk, bulge, and halo stars, we translate our distribution of Type II SN environments as a function of oxygen abundance into an estimate of the iron abundance, since iron varies more steeply than oxygen. We find that though this sample spans only 0.65 dex in oxygen abundance, the gap between the iron and oxygen abundance is 50% wider at the low-metallicity end of our sample than at the high-metallicity end.

  14. Structure study on electrochromic films of nickel oxide

    SciTech Connect (OSTI)

    Hu Xingfang; Chen Xiaofeng; Song Xiangyun [Chinese Academy of Sciences, Shanghai (China). Shanghai Inst. of Ceramics

    1993-12-31T23:59:59.000Z

    Using HREM, the relationship between structure and electrochromic properties of rf diode sputtered nickel oxide films with good and poor electrochromic performance has been investigated. The experimental results indicate that all kinds of the films consist of cubic nickel oxide with nano-crystal structure. For the films having good electrochromic properties, the grain size ranges about 5--10 nm. In the films exhibiting poor performance, an amorphous phase of nickel oxide as a continuous phase existing in the film has been observed and the cubic nickel oxide grains appear as isolated islands existing in the amorphous phase. From the structural features of the films, it may be concluded that the grain boundary of nano-polycrystalline structure plays an important role in the electrochromic reaction and the grain boundary would act as channel for the injection and extraction of alkali metal ions and electrons during the coloring and bleaching process. So, it is important to control the structure of films in the deposition process to prepare the film with good electrochromic performance.

  15. Neutron diffraction studies of nickel-containing perovskite oxide catalysts exposed to autothermal reforming environments.

    SciTech Connect (OSTI)

    Mawdsley, J. R.; Vaughey, J. T.; Krause, T. R.; Chemical Sciences and Engineering Division

    2009-10-27T23:59:59.000Z

    Six nickel-containing perovskite oxides (La{sub 1-x}Sr{sub x})M{sub 0.9}Ni{sub 0.1}O{sub 3{+-}{delta}}, where x = 0 or 0.2 and M = Cr, Fe, or Mn were used to catalyze the autothermal reforming of isooctane (C{sub 8}H{sub 18}) into a hydrogen-rich gas during short-term tests at 700 C. To determine the phase stability of the samples in the reducing environment of the reforming reactor, characterization studies of the as-prepared and tested perovskite samples were conducted using powder X-ray diffraction, powder neutron diffraction, transmission electron microscopy, and scanning electron microscopy. We determined that the reducing conditions of the microreactor caused metallic nickel to form in all six compositions. However, the extent of the nickel loss from the perovskite lattices varied: the chromium-containing compositions lost the least nickel, compared to the manganese- and iron-containing compositions, and the strontium-free compositions lost more nickel than their strontium-containing analogs. Five of the six perovskite compositions tested showed no breakdown of the perovskite lattice despite the loss of nickel from the B-sites, producing only the third example of a B-cation-deficient, 3d transition-metal-containing perovskite.

  16. Strained Ge channel p-type metal-oxide-semiconductor field-effect transistors grown on Siâ?â??xGex/Si virtual substrates

    E-Print Network [OSTI]

    Lee, Minjoo L.

    We have fabricated strained Ge channel p-type metal-oxide-semiconductor field-effect transistors (p-MOSFETs) on Siâ??.â??Geâ??.â?? virtual substrates. The poor interface between silicon dioxide (SiOâ??) and the Ge channel ...

  17. Electron screening in nickel

    SciTech Connect (OSTI)

    Gajevic, Jelena; Lipoglavsek, Matej; Petrovic, Toni; Pelicon, Primoz [Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia); Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia) and Cosylab d.d, Teslova ulica 30, Ljubljana (Slovenia); Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia)

    2012-11-20T23:59:59.000Z

    In order to further investigate electron screening phenomenon we studied proton induced nuclear reactions over an energy range from 1.35 to 3.08 MeV for different environments: Ni metal and NiO insulator. The measurements were based on observation of the {gamma}-ray yields of {sup 59,61,63,64,65}Cu and {sup 58,60,62}Ni. Also, we have studied the decay of {sup 61}Cu produced in the reaction {sup 60}Ni(p,{gamma}), in order to find a possible decay rate perturbation by atomic electrons and found a small difference in half-life for metallic compared to oxide environment, respectively. The present results clearly show that the metallic environment affects the fusion reactions at low energy and that it might also affect the decay rate.

  18. Metal-ceramic joint assembly

    DOE Patents [OSTI]

    Li, Jian (New Milford, CT)

    2002-01-01T23:59:59.000Z

    A metal-ceramic joint assembly in which a brazing alloy is situated between metallic and ceramic members. The metallic member is either an aluminum-containing stainless steel, a high chromium-content ferritic stainless steel or an iron nickel alloy with a corrosion protection coating. The brazing alloy, in turn, is either an Au-based or Ni-based alloy with a brazing temperature in the range of 9500 to 1200.degree. C.

  19. Electron screening in nickel

    SciTech Connect (OSTI)

    Gajevic, Jelena; Lipoglavsek, Matej; Petrovic, Toni; Pelicon, Primoz [Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia); Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia) and Cosylab d.d, Teslova ulica 30, Ljubljana (Slovenia); Jozef Stefan Institute, Jamova cesta 39, Ljubljana (Slovenia)

    2012-10-20T23:59:59.000Z

    In order to investigate the interplay between nuclei and their surroundings we studied proton induced nuclear reactions over an energy range from 1.35 to 3.08 MeV for different environments: Ni metal and NiO insulator. The measurements were based on observation of the {gamma}-ray yields of {sup 59,61,63,64,65}Cu and {sup 58,60,62}Ni. The presented results clearly show that the metallic environment affects the fusion reactions at low energies.

  20. W.-L. Huang, Z. Ren, and C. T.-C. Nguyen, "Nickel vibrating micromechanical disk resonator with solid dielectric capacitive-transducer gap," Proceedings, 2006 IEEE Int. Frequency Control Symp., Miami, Florida, June 5-7, 2006, pp. 839-847.

    E-Print Network [OSTI]

    Nguyen, Clark T.-C.

    W.-L. Huang, Z. Ren, and C. T.-C. Nguyen, "Nickel vibrating micromechanical disk resonator, Florida, June 5-7, 2006, pp. 839-847. Nickel Vibrating Micromechanical Disk Resonator With Solid in a low temperature nickel metal material and using a 30-nm nitride dielectric capacitive transducer has

  1. Logistic Tensor Factorization for Multi-Relational Data Maximilian Nickel nickel@dbs.ifi.lmu.de

    E-Print Network [OSTI]

    Tresp, Volker

    Logistic Tensor Factorization for Multi-Relational Data Maximilian Nickel nickel or recommendation data (Nickel et al., 2012; Bordes et al., 2011; Bader et al., 2007; Rendle et al., 2010- able and easier to handle then general non-linear ap- proaches. Rescal (Nickel et al., 2011; 2012

  2. Modeling of a Nickel-Hydrogen Cell Phase Reactions in the Nickel Active Material

    E-Print Network [OSTI]

    Modeling of a Nickel-Hydrogen Cell Phase Reactions in the Nickel Active Material B. Wu and R. E of South Carolina, Columbia, South Carolina 29208, USA A nonisothermal model of a nickel-hydrogen cell has been developed with the consideration of multiple phases in the nickel active material. Important

  3. Platinum-ruthenium-nickel fuel cell electrocatalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2005-07-26T23:59:59.000Z

    A catalyst suitable for use in a fuel cell, especially as an anode catalyst, that contains platinum, ruthenium, and nickel, wherein the nickel is at a concentration that is less than about 10 atomic percent.

  4. Nickel isotopes in stellar matter

    E-Print Network [OSTI]

    Jameel-Un Nabi

    2014-08-19T23:59:59.000Z

    Isotopes of nickel play a key role during the silicon burning phase up to the presupernova phase of massive stars. Electron capture rates on these nickel isotopes are also important during the phase of core contraction. I present here the microscopic calculation of ground and excited states Gamow-Teller (GT) strength distributions for key nickel isotopes. The calculation is performed within the frame-work of pn-QRPA model. A judicious choice of model parameters, specially of the Gamow-Teller strength parameters and the deformation parameter, resulted in a much improved calculation of GT strength functions. The excited state GT distributions are much different from the corresponding ground-state distributions resulting in a failure of the Brink's hypothesis. The electron capture and positron decay rates on nickel isotopes are also calculated within the framework of pn-QRPA model relevant to the presupernova evolution of massive stars. The electron capture rates on odd-A isotopes of nickel are shown to have dominant contributions from parent excited states during as early as silicon burning phases. Comparison is being made with the large scale shell model calculation. During the silicon burning phases of massive stars the electron capture rates on $^{57,59}$Ni are around an order of magnitude bigger than shell model rates and can bear consequences for core-collapse simulators.

  5. Annealing behaviors of vacancy-type defects near interfaces between metal contacts and GaN probed using a monoenergetic positron beam

    SciTech Connect (OSTI)

    Uedono, Akira, E-mail: uedono.akira.gb@u.tsukuba.ac.jp; Yoshihara, Nakaaki [Division of Applied Physics, Faculty of Pure and Applied Science, University of Tsukuba, Tsukuba, Ibaraki 305-8573 (Japan); Fujishima, Tatsuya; Piedra, Daniel; Palacios, Tomás [Microsystems Technology Laboratories, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139-4307 (United States); Ishibashi, Shoji [Nanosystem Research Institute “RICS,” National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki 305-8568 (Japan); Sumiya, Masatomo [Wide Bandgap Material Group, National Institute for Materials Science, Tsukuba 305-0044 (Japan); Laboutin, Oleg; Johnson, Wayne [IQE, 200 John Hancock Road, Taunton, Massachusetts 01581 (United States)

    2014-08-04T23:59:59.000Z

    Vacancy-type defects near interfaces between metal contacts and GaN grown on Si substrates by metal organic chemical vapor deposition have been studied using a monoenergetic positron beam. Measurements of Doppler broadening spectra of the annihilation radiation for Ti-deposited GaN showed that optically active vacancy-type defects were introduced below the Ti/GaN interface after annealing at 800?°C. Charge transition of those defects due to electron capture was observed and was found to correlate with a yellow band in the photoluminescence spectrum. The major defect species was identified as vacancy clusters such as three to five Ga-vacancies coupled with multiple nitrogen-vacancies. The annealing behaviors of vacancy-type defects in Ti-, Ni-, and Pt-deposited GaN were also examined.

  6. NICKEL/YTTRIA-STABILISED ZIRCONIA CERMET ANODES

    E-Print Network [OSTI]

    NICKEL/YTTRIA-STABILISED ZIRCONIA CERMET ANODES FOR SOLID OXIDE FUEL CELLS Søren Primdahl #12;ii Primdahl, Søren Nickel/yttria-stabilised zirconia cermet anodes for solid oxide fuel cells Thesis as Risø-R-1137(EN) ISBN 87-550-2605-2 (internet) #12;iii NICKEL/YTTRIA-STABILISED ZIRCONIA CERMET ANODES

  7. Microcompression of nanocrystalline nickel B. E. Schuster

    E-Print Network [OSTI]

    Wei, Qiuming

    on electrodeposited nanocrystalline nickel a material system where the grain size is much smaller than the specimenMicrocompression of nanocrystalline nickel B. E. Schuster Department of Mechanical Engineering of face-centered-cubic nanocrystalline nickel nano-Ni have been closely examined in recent years

  8. Intercrystalline density on nanocrystalline nickel

    SciTech Connect (OSTI)

    Haasz, T.R.; Aust, K.T. [Univ. of Toronto, Ontario (Canada). Dept. of Metallurgy and Materials Science] [Univ. of Toronto, Ontario (Canada). Dept. of Metallurgy and Materials Science; Palumbo, G. [Ontario Hydro Research Div., Toronto, Ontario (Canada)] [Ontario Hydro Research Div., Toronto, Ontario (Canada); El-Sherik, A.M.; Erb, U. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Materials and Metallurgical Engineering] [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Materials and Metallurgical Engineering

    1995-02-01T23:59:59.000Z

    Most methods currently available for the synthesis of nanostructured materials result in considerable residual porosity. Studies concerned with the novel structures and properties of these materials are thus compromised by the intrinsically high levels of porosity. As recently shown by Kristic et al., porosity can have a significant effect on fundamental materials properties such as Young`s modulus. One of the most promising techniques for the production of fully dense nanocrystalline materials is electrodeposition. In the present work, the residual porosity and density of nanostructured nickel produced by the electrodeposition method is assessed and discussed in light of the intrinsic intercrystalline density of nickel.

  9. Polymers near Metal Surfaces: Selective Adsorption and Global Conformations L. Delle Site,1

    E-Print Network [OSTI]

    Alavi, Ali

    of a polycarbonate melt near a nickel surface as a model system for the interaction of polymers with metal surfaces- level modeling of polymers near metal surfaces. Liquid polycarbonate near a nickel surface is taken.g., production of compact disks). We combine ab initio calculations for the interaction of fragments of bisphenol-A-polycarbonate

  10. Synthesis of Thermal Interface Materials Made of Metal Decorated Carbon Nanotubes and Polymers

    E-Print Network [OSTI]

    Okoth, Marion Odul

    2011-10-21T23:59:59.000Z

    -Methly-2-Pyrrolidone (NMP). The metals used for this experiment were copper (Cu), tin (Sn), and nickel (Ni). The metal nanoparticles were seeded using functionalized MWCNTs as templates. Once seeded, the nanotubes and polymer composites were made...

  11. Systematic Approach to Compare the Inflammatory Response of Liver Cell Culture Systems Exposed to Silver, Copper, and Nickel Nanoparticles 

    E-Print Network [OSTI]

    Banerjee, Nivedita

    2011-10-21T23:59:59.000Z

    hepatotoxicity concerns, the inflammatory response of hepatocytes after exposure to metal colloids was assessed. Four ~30-nm-sized metal colloids, including silver (nano-Ag), copper (nano-Cu) and nickel (nano-Ni) were examined in an effort to understand...

  12. Phase transformations in nickel-rich nickel-titanium alloys : influence of strain-rate, temperature, thermomechanical treatment and nickel composition on the shape memory and superelastic characteristics

    E-Print Network [OSTI]

    Adharapurapu, Raghavendra R.

    2007-01-01T23:59:59.000Z

    Buehler, W.J. and R.C. Wiley, Nickel-base Alloys, in UnitedYork. Standard Terminology for nickel-titanium shape memoryinto martensite in iron-nickel alloys under stress. Z.

  13. Phase transformations in nickel-rich nickel-titanium alloys : influence of strain-rate, temperature, thermomechanical treatment and nickel composition on the shape memory and superelastic characteristics

    E-Print Network [OSTI]

    Adharapurapu, Raghavendra R.

    2007-01-01T23:59:59.000Z

    Terminology for nickel-titanium shape memory alloys. ASTME. Ence, and J.P. Nielsen, Titanium-nickel phase diagram.pseudoelasticity in titanium-nickel alloys. Journal de

  14. Unanticipated potential cancer risk near metal recycling facilities

    SciTech Connect (OSTI)

    Raun, Loren, E-mail: raun@rice.edu [Department of Statistics, MS 138, Rice University, P.O. Box 1892, Houston, TX 77251-1892 (United States)] [Department of Statistics, MS 138, Rice University, P.O. Box 1892, Houston, TX 77251-1892 (United States); Pepple, Karl, E-mail: pepple.karl@epa.gov [State and Local Programs Group, Air Quality Policy Division, Office of Air Quality Planning and Standards, Policy, Analysis, and Communications Staff, Mail Drop C404-03, U.S. EPA, Research Triangle Park, NC 27711 (United States)] [State and Local Programs Group, Air Quality Policy Division, Office of Air Quality Planning and Standards, Policy, Analysis, and Communications Staff, Mail Drop C404-03, U.S. EPA, Research Triangle Park, NC 27711 (United States); Hoyt, Daniel, E-mail: hoyt.daniel@epa.gov [Air Surveillance Section, US EPA, Region 6, 6EN-AS, 1445 Ross Avenue, Dallas, TX 75202-2733 (United States)] [Air Surveillance Section, US EPA, Region 6, 6EN-AS, 1445 Ross Avenue, Dallas, TX 75202-2733 (United States); Richner, Donald, E-mail: Donald.Richner@houstontx.gov [Houston Department of Health and Human Services, Bureau of Pollution Control and Prevention, 7411 Park Place Blvd., Houston, TX 77087 (United States)] [Houston Department of Health and Human Services, Bureau of Pollution Control and Prevention, 7411 Park Place Blvd., Houston, TX 77087 (United States); Blanco, Arturo, E-mail: arturo.blanco@houstontx.gov [Pollution Control and Prevention, Environmental Health Division, Houston Department of Health and Human Services, 7411 Park Place Blvd., Houston, TX 77087 (United States)] [Pollution Control and Prevention, Environmental Health Division, Houston Department of Health and Human Services, 7411 Park Place Blvd., Houston, TX 77087 (United States); Li, Jiao, E-mail: jiao.li@rice.edu [Wiess School of Natural Science, Rice University, 6100 Main St., Houston, TX 77005 (United States)] [Wiess School of Natural Science, Rice University, 6100 Main St., Houston, TX 77005 (United States)

    2013-07-15T23:59:59.000Z

    Metal recycling is an important growing industry. Prior to this study, area sources consisting of metal recycling facilities fell in a category of limited regulatory scrutiny because of assumed low levels of annual emissions. Initiating with community complaints of nuisance from smoke, dust and odor, the Houston Department of Health and Human Services (HDHHS) began a monitoring program outside metal recycler facilities and found metal particulates in outdoor ambient air at levels which could pose a carcinogenic human health risk. In a study of five similar metal recycler facilities which used a torch cutting process, air downwind and outside the facility was sampled for eight hours between 6 and 10 times each over 18 months using a mobile laboratory. Ten background locations were also sampled. Iron, manganese, copper, chromium, nickel, lead, cobalt, cadmium and mercury were detected downwind of the metal recyclers at frequencies ranging from 100% of the time for iron to 2% of the time for mercury. Of these metals, chromium, nickel, lead, cobalt, cadmium and mercury were not detected in any sample in the background. Two pairs of samples were analyzed for total chromium and hexavalent chromium to establish a ratio of the fraction of hexavalent chromium in total chromium. This fraction was used to estimate hexavalent chromium at all locations. The carcinogenic risk posed to a residential receptor from metal particulate matter concentrations in the ambient air attributed to the metal recyclers was estimated from each of the five facilities in an effort to rank the importance of this source and inform the need for further investigation. The total risk from these area sources ranged from an increased cancer risk of 1 in 1,000,000 to 6 in 10,000 using the 95th upper confidence limit of the mean of the carcinogenic metal particulate matter concentration, assuming the point of the exposure is the sample location for a residential receptor after accounting for wind direction and the number of shifts that could operate a year. Further study is warranted to better understand the metal air pollution levels in the community and if necessary, to evaluate the feasibility of emission controls and identify operational improvements and best management practices for this industry. This research adds two new aspects to the literature: identification of types and magnitude of metal particulate matter air pollutants associated with a previously unrecognized area source, metal recyclers and their potential risk to health. -- Highlights: • Air monitoring study in response to community complaints found metal contamination. • Metal recyclers found to potentially pose cancer from metal particulates • Chromium, nickel, cobalt and cadmium samples were detected in five metal recyclers. • These metals were not detected in background air samples. • Estimated increased cancer risk ranges from 1 in 1,000,000 to 8 in 10,000.

  15. INTEGRAL FIELD SPECTROSCOPY OF SUPERNOVA EXPLOSION SITES: CONSTRAINING THE MASS AND METALLICITY OF THE PROGENITORS. II. TYPE II-P AND II-L SUPERNOVAE

    SciTech Connect (OSTI)

    Kuncarayakti, Hanindyo; Maeda, Keiichi [Kavli Institute for the Physics and Mathematics of the Universe (WPI), Todai Institutes for Advanced Study, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8583 (Japan); Doi, Mamoru; Morokuma, Tomoki; Hashiba, Yasuhito [Institute of Astronomy, Graduate School of Science, University of Tokyo, 2-21-1 Osawa, Mitaka, Tokyo 181-0015 (Japan); Aldering, Greg [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Arimoto, Nobuo [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-0015 (Japan); Pereira, Rui [CNRS/IN2P3, Institut de Physique Nucleaire de Lyon, 4 Rue Enrico Fermi, F-69622 Villeurbanne Cedex (France); Usuda, Tomonori, E-mail: hanindyo.kuncarayakti@ipmu.jp [Subaru Telescope, National Astronomical Observatory of Japan, 650 North A'ohoku Place, Hilo, HI 96720 (United States)

    2013-08-01T23:59:59.000Z

    Thirteen explosion sites of Type II-P and II-L supernovae (SNe) in nearby galaxies have been observed using integral field spectroscopy, enabling both spatial and spectral study of the explosion sites. We used the properties of the parent stellar population of the coeval SN progenitor star to derive its metallicity and initial mass. The spectrum of the parent stellar population yields estimates of metallicity via the strong-line method and age via a comparison with simple stellar population models. These metallicity and age parameters are adopted for the progenitor star. Age, or lifetime of the star, was used to derive the initial (zero-age main sequence) mass of the star using comparisons with stellar evolution models. With this technique, we were able to determine the metallicities and initial masses of the SN progenitors in our sample. Our results indicate that some Type II SN progenitors may have been stars with masses comparable to those of SN Ib/c progenitors.

  16. Catalytically active nickel ^110 surfaces in growth of carbon tubular structures

    E-Print Network [OSTI]

    Wang, Zhong L.

    Catalytically active nickel ^110 surfaces in growth of carbon tubular structures M. H. Kuang and Z of Sciences, Beijing 100083, China Received 19 October 1999; accepted for publication 11 January 2000 Recent interest in the growth of aligned carbon nanotube films using transition metal catalysts has led

  17. Iron aluminides and nickel aluminides as materials for chemical air separation

    DOE Patents [OSTI]

    Kang, Doohee (Macungie, PA)

    1991-01-01T23:59:59.000Z

    The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.

  18. Iron aluminides and nickel aluminides as materials for chemical air separation

    DOE Patents [OSTI]

    Kang, D.

    1991-01-29T23:59:59.000Z

    The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.

  19. Metal articles having ultrafine particles dispersed therein

    SciTech Connect (OSTI)

    Alexander, G.B.; Nadkarni, R.A.

    1992-07-28T23:59:59.000Z

    This patent describes a metal article of manufacture. It comprises: a metal selected from the group consisting of copper, silver, gold, lead, tin, nickel, zinc, cobalt, antimony, bismuth, iron, cadmium, chromium, germanium, gallium, selenium, tellurium, mercury, tungsten arsenic, manganese, iridium, indium, ruthenium, rhenium, rhodium, molybdenum, palladium, osmium and platinum; and a plurality of ultrafine particles.

  20. Experiences with polishing electroless nickel

    SciTech Connect (OSTI)

    Brown, N.J.; Taylor, J.S.; Fuchs, B.A.

    1991-04-01T23:59:59.000Z

    During recent years the bureaucracy has become increasingly rigid in demanding a mechanical observance of the minimum bid specified on the simplest terms. Qualifications of the vendor and specifications of the product are increasingly viewed as attempts to thwart the progress of the process toward minimum quality, Any such qualification or specification must be justified as to not only reasonableness but necessity. This provides the purpose of this paper, to record forever the existence of the wild dingleberry and to disclose its habits with respect to laps and the marvelous effects it has on the emotional state of the lappers. Among metal polishers, the term dingleberry refers to a type of nodule or wartlike structure sometimes seen in isolation and occasionally in considerable profusion particularly in chemically plated surfaces. 2 refs.

  1. Growth of Nanoscale Nickel Ferrite on Carbonaceous Matrix- A Novel Method of Turning Harmful Particulates into a Functional Nanocomposite: An XAFS Study

    SciTech Connect (OSTI)

    Pattanaik, S.; Huggins, F; Huffman, G

    2010-01-01T23:59:59.000Z

    Particulate matter (PM) emission from residual oil combustion typically consists of carbonaceous material accompanied by inorganic matter notably transition metal sulfates. Often a minor sulfide form is found in the coarse fraction while an oxide form is more common in the fine and ultrafine fractions. A composite comprising of nanoscale nickel ferrite dispersed on carbonaceous matrix has been obtained following liberation of metal sulfates from the fine PM - a novel method of turning harmful particulates into a functional nanocomposite without the need for elaborate preparation using expensive precursors. The nickel ferrite content in the composite varies with the Fe/Ni ratio in particulate, fuel type, and combustion condition. Such variation may lead to the composite exhibiting diverse physical behaviors. Detailed structure and cation distribution in dispersed ferrite have been studied using Fe and Ni K-edges XAFS spectroscopy. Peaks are identified in the radial structure function with specific atom pair correlations within the spinel ferrite from which the relative occupancy of the cations in the octahedral and tetrahedral sites can be discerned. The results show that Ni(II) has strong preference for the octahedral site, while Fe(III) prefers both sites which is consistent with that of an inverted spinel ferrite.

  2. Silicon and Nickel Enrichment in Planet-Host Stars: Observations and Implications for the Core-Accretion Theory of Planet Formation

    E-Print Network [OSTI]

    Sarah E. Robinson; Gregory Laughlin; Peter Bodenheimer; Debra Fischer

    2006-01-27T23:59:59.000Z

    We present evidence that stars with planets exhibit statistically significant silicon and nickel enrichment over the general metal-rich population. We also present simulations which predict silicon enhancement of planet hosts within the context of the core-accretion hypothesis for giant planet formation. Because silicon and oxygen are both alpha elements, [Si/Fe] traces [O/Fe], so the silicon enhancement in planet hosts predicts that these stars are oxygen-rich as well. We present new numerical simulations of planet formation by core accretion that establish the timescale on which a Jovian planet reaches rapid gas accretion, t_rga, as a function of solid surface density sigma_solid: (t_rga / 1 Myr) = (sigma_solid / 25.0 g cm^{-2})^{-1.44}. This relation enables us to construct Monte Carlo simulations that predict the fraction of star-disk systems that form planets as a function of [Fe/H], [Si/Fe], disk mass, outer disk radius and disk lifetime. Our simulations reproduce both the known planet-metallicity correlation and the planet-silicon correlation reported in this paper. The simulations predict that 16% of Solar-type stars form Jupiter-mass planets, in agreement with 12% predicted from extrapolation of the observed planet frequency-semimajor axis distribution. Although a simple interpretation of core accretion predicts that the planet-silicon correlation should be much stronger than the planet-nickel correlation, we observe the same degree of silicon and nickel enhancement in planet hosts. If this result persists once more planets have been discovered, it might indicate a complexity in the chemistry of planet formation beyond the simple accumulation of solids in the core accretion theory.

  3. Nickel aluminides and nickel-iron aluminides for use in oxidizing environments

    DOE Patents [OSTI]

    Liu, Chain T. (Oak Ridge, TN)

    1988-03-15T23:59:59.000Z

    Nickel aluminides and nickel-iron aluminides treated with hafnium or zirconium, boron and cerium to which have been added chromium to significantly improve high temperature ductility, creep resistance and oxidation properties in oxidizing environments.

  4. Twelve Year Study of Underground Corrosion of Activated Metals

    SciTech Connect (OSTI)

    M. Kay Adler Flitton; Timothy S. Yoder

    2012-03-01T23:59:59.000Z

    The subsurface radioactive disposal facility located at the U.S. Department of Energy’s Idaho site contains neutron-activated metals from non-fuel nuclear-reactor-core components. A long-term corrosion study is being conducted to obtain site-specific corrosion rates to support efforts to more accurately estimate the transfer of activated elements in an arid vadose zone environment. The study uses non-radioactive metal coupons representing the prominent neutron-activated material buried at the disposal location, namely, two types of stainless steels, welded stainless steel, welded nickel-chromium steel alloy, zirconium alloy, beryllium, and aluminum. Additionally, carbon steel (the material used in cask disposal liners and other disposal containers) and duplex stainless steel (high-integrity containers) are also included in the study. This paper briefly describes the test program and presents the corrosion rate results through twelve years of underground exposure.

  5. Evaluation of nickel flash smelting through piloting and simulation

    SciTech Connect (OSTI)

    Varnas, S.R.; Koh, P.T.L. [CSIRO, Clayton, Victoria (Australia). Div. of Minerals; Kemori, N. [Sumitomo Metal Mining Co., Ehime (Japan)

    1998-12-01T23:59:59.000Z

    An extensive study of the nickel flash smelting process has been undertaken. It is aimed at the optimization of the burner design to improve the smelting performance and to increase the throughput of the rebuilt furnace. A design-based mathematical model was developed to simulate the operation of the four burners and the reaction shaft of the flash furnace at Western Mining Corporation Ltd.`s Kalgoorlie Nickel Smelter. A modified single burner version of the model was validated against data obtained from the pilot plant at the Pyrometallurgical Research Centre (PRC) of the Sumitomo Metal Mining Co.`s Toyo Smelter. The approach taken involved experimental measurements of key process parameters in the pilot plant and detailed numerical simulation of the fluid flow, heat transfer, and combustion in the entire burner-shaft complex. Several burner designs have been tested experimentally at the pilot plant and theoretically through computer simulation. The main outcome of the study was the development of an experimentally validated mathematical model of the flash smelter providing a new powerful design tool. The insight gained about the process from the application of this tool led to the design of a more efficient nickel flash smelting process.

  6. Templated synthesis of nickel nanoparticles: Toward heterostructured nanocomposites for efficient hydrogen storage

    SciTech Connect (OSTI)

    Nelson, Nicholas Cole [Ames Laboratory

    2013-05-07T23:59:59.000Z

    The world is currently facing an energy and environmental crisis for which new technologies are needed. Development of cost-competitive materials for catalysis and hydrogen storage on-board motor vehicles is crucial to lead subsequent generations into a more sustainable and energy independent future. This thesis presents work toward the scalable synthesis of bimetallic heterostructures that can enable hydrogen to compete with carbonaceous fuels by meeting the necessary gravimetric and volumetric energy densities and by enhancing hydrogen sorption/desorption kinetics near ambient temperatures and pressures. Utilizing the well-known phenomenon of hydrogen spillover, these bimetallic heterostructures could work by lowering the activation energy for hydrogenation and dehydrogenation of metals. Herein, we report a novel method for the scalable synthesis of silica templated zero-valent nickel particles (Ni?SiO{sub 2}) that hold promise for the synthesis of nickel nanorods for use in bimetallic heterostructures for hydrogen storage. Our synthesis proceeds by chemical reduction of a nickel-hydrazine complex with sodium borohydride followed by calcination under hydrogen gas to yield silica encapsulated nickel particles. Transmission electron microscopy and powder X-ray diffraction were used to characterize the general morphology of the resultant nanocapsules as well as the crystalline phases of the incorporated Ni{sup 0} nanocrystals. The structures display strong magnetic behavior at room temperature and preliminary data suggests nickel particle size can be controlled by varying the amount of nickel precursor used in the synthesis. Calcination under different environments and TEM analysis provides evidence for an atomic migration mechanism of particle formation. Ni?SiO{sub 2} nanocapsules were used as seeds to induce heterogeneous nucleation and subsequent growth within the nanocapsule via electroless nickel plating. Nickel nanoparticle growth occurs under high temperature alkaline conditions, however silica nanocapsule integrity is not maintained due to the incompatibility of silica with the growth conditions. Silica nanocapsule integrity is maintained under low temperature neutral conditions, but nickel particle growth is not observed. Through FTIR and UV/Vis analysis, we show the degree of crosslinking and condensation increases in calcined silica compared to as-synthesized silica. We propose the increased density of the silica nanocapsule hinders mass transfer of the bulky nickel precursor complex from solution and onto the surface of the “catalytic” zero-valent nickel seed within the nanocapsule cavity. Decreasing the density of the silica nanocapsule can be achieved through co-condensation of tetraethylorthosilicate with an alkyl functionalized silane followed by calcination to remove the organic component or by chemical etching in alkaline solution, but will not be addressed in this thesis.

  7. Selective Electroless Nickel Plating of Particle Arrays on Polyelectrolyte Multilayers

    E-Print Network [OSTI]

    Lee, Ilsoon

    Selective Electroless Nickel Plating of Particle Arrays on Polyelectrolyte Multilayers Ilsoon Lee Received June 30, 2003. Revised Manuscript Received September 25, 2003 Selective electroless nickel plating and particles. Selectively nickel-plated surfaces were characterized with optical microscopy, X

  8. Hydrogen dissociation catalyzed by carbon coated nickel nanoparticles: experiment and theory

    E-Print Network [OSTI]

    Yermakov, A Ye; Uimin, M A; Lokteva, E S; Erokhin, A V; Schegoleva, N N

    2012-01-01T23:59:59.000Z

    Based on combination of experimental measurements and first-principles calculations we report a novel carbon-based catalytic material and describe significant acceleration of the hydrogenation of magnesium at room temperature in presence of nickel nanoparticles wrapped in multilayer graphene. Increase of the rate of magnesium hydrogenation in contrast to the mix of graphite and nickel nanoparticles evidences intrinsic catalytic properties of explored nanocomposites. Results of simulations demonstrate that the doping from metal substrate and the presence of Stone-Wales defects turn multilayer graphene from chemically inert to chemically active mode. The role of the size of nanoparticles and temperature are also discussed.

  9. Braze material for joining ceramic to metal and ceramic to ceramic surfaces and joined ceramic to metal and ceramic to ceramic article

    DOE Patents [OSTI]

    Hunt, Thomas K. (Ann Arbor, MI); Novak, Robert F. (Farmington Hills, MI)

    1991-01-01T23:59:59.000Z

    An improved active metal braze filler material is provided in which the coefficient of thermal expansion of the braze filler is more closely matched with that of the ceramic and metal, or two ceramics, to provide ceramic to metal, or ceramic to ceramic, sealed joints and articles which can withstand both high temperatures and repeated thermal cycling without failing. The braze filler material comprises a mixture of a material, preferably in the form of a powder, selected from the group consisting of molybdenum, tungsten, silicon carbide and mixtures thereof, and an active metal filler material selected from the group consisting of alloys or mixtures of nickel and titanium, alloys or mixtures of nickel and zirconium, alloys or mixtures of nickel, titanium, and copper, alloys or mixtures of nickel, titanium, and zirconium, alloys or mixtures of niobium and nickel, alloys or mixtures of niobium and zirconium, alloys or mixtures of niobium and titanium, alloys or mixtures of niobium, titanium, and nickel, alloys or mixtures of niobium, zirconium, and nickel, and alloys or mixtures of niobium, titanium, zirconium, and nickel. The powder component is selected such that its coefficient of thermal expansion will effect the overall coefficient of thermal expansion of the braze material so that it more closely matches the coefficients of thermal expansion of the ceramic and metal parts to be joined.

  10. Electrochemical, Structural and Surface Characterization of Nickel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrochemical, Structural and Surface Characterization of NickelZirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Electrochemical, Structural and Surface...

  11. Electroless (autocatalytic) nickel-cobalt thin films as solar control coatings

    SciTech Connect (OSTI)

    John, S.; Srinivasan, K.N.; Selvam, M. [Central Electrochemical Research Inst., Tamilnadu (India); Anuradha, S.; Rajendran, S. [Alagappa Univ., Tamilnadu (India). Dept. of Physics

    1994-12-31T23:59:59.000Z

    This paper describes the deposition of nickel-cobalt-phosphorus coatings by the electroless deposition technique for use as solar control coatings in architectural glazing of buildings. Electroless deposition is characterized by the autocatalytic deposition of a metal/alloy from an aqueous solution of its ions by interaction with a chemical reducing agent. The reducing agent provides electrons for the metal ions to be neutralized. The reduction is initiated by the catalyzed surface of the substrate and continued by the self catalytic activity of the deposited metal/alloy as long as the substrate is immersed in the electroless bath and operating conditions are maintained. Electroless nickel-cobalt-phosphorus thin films were deposited from a solution containing 15 g/l nickel sulphate, 5 g/l cobalt sulphate, 60 g/l ammonium citrate and 25 g/l sodium hypophosphite operating at 30 C, at a pH of 9.5 for two minutes. Electroless nickel-cobalt-phosphorus coatings are found to satisfy the basic requirements of solar control coatings. Autocatalytic deposition technique offers the possibilities of producing large area coatings with low capital investment, stability and good adhesion to glass substrates.

  12. Parasitic corrosion-resistant anode for use in metal/air or metal/O/sub 2/ cells

    DOE Patents [OSTI]

    Joy, R.W.; Smith, D.F.

    1982-09-20T23:59:59.000Z

    A consumable metal anode is described which is used in refuelable electrochemical cells and wherein at least a peripheral edge portion of the anode is protected against a corrosive alkaline environment of the cell by the application of a thin metal coating, the coating being formed of metals such as nickel, silver, and gold.

  13. X-ray absorption spectroscopic studies of the active sites of nickel- and copper-containing metalloproteins

    SciTech Connect (OSTI)

    Tan, G.O.

    1993-06-01T23:59:59.000Z

    X-ray absorption spectroscopy (XAS) is a useful tool for obtaining structural and chemical information about the active sites of metalloproteins and metalloenzymes. Information may be obtained from both the edge region and the extended X-ray absorption fine structure (EXAFS) or post-edge region of the K-edge X-ray absorption spectrum of a metal center in a compound. The edge contains information about the valence electronic structure of the atom that absorbs the X-rays. It is possible in some systems to infer the redox state of the metal atom in question, as well as the geometry and nature of ligands connected to it, from the features in the edge in a straightforward manner. The EXAFS modulations, being produced by the backscattering of the ejected photoelectron from the atoms surrounding the metal atom, provide, when analyzed, information about the number and type of neighbouring atoms, and the distances at which they occur. In this thesis, analysis of both the edge and EXAFS regions has been used to gain information about the active sites of various metalloproteins. The metalloproteins studied were plastocyanin (Pc), laccase and nickel carbon monoxide dehydrogenase (Ni CODH). Studies of Cu(I)-imidazole compounds, related to the protein hemocyanin, are also reported here.

  14. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, Haskell (Los Alamos, NM)

    1986-01-01T23:59:59.000Z

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  15. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, H.

    1983-07-26T23:59:59.000Z

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  16. Directed Assembly of Transition-Metal-Coordinated Molecular Loops and Squares from Salen-Type Components. Examples

    E-Print Network [OSTI]

    catalytic materials. Recently, we and others have shown that supramolecular compounds incorporating multiple. The incorporation of multiple reactive metal sites into a single, cavity-containing supramolecular structure points attention in the past decade.1 By judicious design of preprogrammed synthons, the desired supramolecular

  17. Synthesis, Properties, and Reactions of Trinuclear Macrocyclic Nickel(II) and Nickel(I) Complexes: Electrocatalytic Reduction of CO2 by Nickel(II) Complex

    E-Print Network [OSTI]

    Paik Suh, Myunghyun

    FULL PAPER Synthesis, Properties, and Reactions of Trinuclear Macrocyclic Nickel(II) and Nickel(I) Complexes: Electrocatalytic Reduction of CO2 by Nickel(II) Complex Eun Young Lee,[a] Daewon Hong,[a] Han Woong Park,[a] and Myunghyun Paik Suh*[a] Keywords: Nickel / Macrocyclic compounds / Carbon dioxide

  18. Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A Predictive Model through Computations. Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A...

  19. Moving Protons with Pendant Amines: Proton Mobility in a Nickel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Moving Protons with Pendant Amines: Proton Mobility in a Nickel Catalyst for Oxidation of Hydrogen. Moving Protons with Pendant Amines: Proton Mobility in a Nickel Catalyst for...

  20. Conflicting Roles Of Nickel In Controlling Cathode Performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries. Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries....

  1. Electrodeposition From Acidic Solutions of Nickel Bis(benzenedithiolat...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From Acidic Solutions of Nickel Bis(benzenedithiolate) Produces a Hydrogen-Evolving Ni-S Film on Glassy Carbon Electrodeposition From Acidic Solutions of Nickel...

  2. Predicting Nickel Precipitate Formation in Contaminated Soils. (3717)

    E-Print Network [OSTI]

    Sparks, Donald L.

    Predicting Nickel Precipitate Formation in Contaminated Soils. (3717) Authors: E. Peltier* - Univ controlling precipitate formation is still needed. In this study, we have combined experimental data on nickel

  3. Conformational Dynamics and Proton Relay Positioning in Nickel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dynamics and Proton Relay Positioning in Nickel Catalysts for Hydrogen Production and Oxidation. Conformational Dynamics and Proton Relay Positioning in Nickel Catalysts for...

  4. Enzyme Design From the Bottom Up: An Active Nickel Electrocatalyst...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enzyme Design From the Bottom Up: An Active Nickel Electrocatalyst with a Structured Peptide Outer Coordination Sphere. Enzyme Design From the Bottom Up: An Active Nickel...

  5. Structural, Spectroscopic, And Theoretical Elucidation of a Redox-Active Pincer-Type Ancillary Applied in Catalysis

    SciTech Connect (OSTI)

    Adhikari, D.; Mossin, S.; Basuli, F.; Huffman, J.C.; Szilagyi, R.K.; Meyer, K.; Mindiola, D.J.

    2009-05-11T23:59:59.000Z

    Pincer-type ligands are believed to be very robust scaffolds that can support multifarious functionalities as well as highly reactive metal motifs applied in organometallic chemistry, especially in the realm of catalysis. In this paper, we describe the redox and, therefore, noninnocent behavior of a PNP (PNP{sup -} = N[2-P(CHMe{sub 2}){sub 2}-4-methylphenyl]{sub 2}) pincer ancillary bound to nickel. A combination of structural, spectroscopic, and theoretical techniques suggests that this type of framework can house an electron hole when coordinated to Ni(II).

  6. Metal-atom fluorescence from the quenching of metastable rare gases by metal carbonyls

    SciTech Connect (OSTI)

    Hollingsworth, W.E.

    1982-11-01T23:59:59.000Z

    A flowing afterglow apparatus was used to study the metal fluorescence resulting from the quenching of metastable rare-gas states by metal carbonyls. The data from the quenching or argon, neon, and helium by iron and nickel carbonyl agreed well with a restricted degree of freedom model indicating a concerted bond-breaking dissociation.

  7. Strength of semiconductors, metals, and ceramics evaluated by a microscopic cleavage model with Morse-type and Lennard-Jones-type interaction

    SciTech Connect (OSTI)

    Hess, Peter [Institute of Physical Chemistry, University of Heidelberg, Im Neuenheimer Feld 253, D-69120 Heidelberg (Germany)

    2014-08-07T23:59:59.000Z

    An improved microscopic cleavage model, based on a Morse-type and Lennard-Jones-type interaction instead of the previously employed half-sine function, is used to determine the maximum cleavage strength for the brittle materials diamond, tungsten, molybdenum, silicon, GaAs, silica, and graphite. The results of both interaction potentials are in much better agreement with the theoretical strength values obtained by ab initio calculations for diamond, tungsten, molybdenum, and silicon than the previous model. Reasonable estimates of the intrinsic strength are presented for GaAs, silica, and graphite, where first principles values are not available.

  8. Electroless plating of graphite with copper and nickel

    SciTech Connect (OSTI)

    Caturla, F.; Molina, F.; Molina-Sabio, M.; Rodriguez-Reinoso, F. [Univ. de Alicante (Spain). Dept. de Quimica Inorganica; Esteban, A. [CIEMAT, Madrid (Spain)

    1995-12-01T23:59:59.000Z

    Decommissioning in the European Union of gas-cooled nuclear reactors using graphite as the moderator will generate a large amount of irradiated graphite as waste. Graphite is a radioactive waste of relatively low activity and consequently the options considered for the management of the waste may include: (i) incineration, (ii) ocean bed disposal, (iii) deep geological disposal, and (iv) shallow land burial. In case the last is the selected mode, an appropriate conditioning procedure is necessary before final disposal, by covering the graphite with a material avoiding or reducing the emission of radionuclides to its surrounding. This work analyses the possibility of conditioning graphite pieces (with a large proportion of pores of different sizes up to 100 {micro}m) with a metal coating of copper or nickel produced by electroless plating, with the aim of completely isolating the graphite from its surrounding. Electroless plating with copper results in a very large proportion of pores filled or covered, but a fraction of the pores remain in the graphite, which decreases with increasing thickness of metal deposit. Furthermore, the copper plating is permeable to liquids and consequently the graphite does not become completely isolated from the surrounding. The percentage of porosity filled or covered by nickel deposits is similar to copper, but they are not permeable to liquids, at least when the thickness is relatively high, and consequently the access of the liquids to the graphite is rather limited. However, when electroless plating with copper is followed by nickel deposition the graphite becomes isolated from the exterior.

  9. Anomalous output characteristic shift for the n-type lateral diffused metal-oxide-semiconductor transistor with floating P-top layer

    SciTech Connect (OSTI)

    Liu, Siyang; Zhang, Chunwei; Sun, Weifeng, E-mail: swffrog@seu.edu.cn [National ASIC System Engineering Research Center, Southeast University, Nanjing 210096 (China); Su, Wei; Wang, Shaorong; Ma, Shulang; Huang, Yu [CSMC Technologies Corporation, Wuxi 214061 (China)

    2014-04-14T23:59:59.000Z

    Anomalous output characteristic shift of the n-type lateral diffused metal-oxide-semiconductor transistor with floating P-top layer is investigated. It shows that the linear drain current has obvious decrease when the output characteristic of fresh device is measured for two consecutive times. The charge pumping experiments demonstrate that the decrease is not from hot-carrier degradation. The reduction of cross section area for the current flowing, which results from the squeezing of the depletion region surrounding the P-top layer, is responsible for the shift. Consequently, the current capability of this special device should be evaluated by the second measured output characteristic.

  10. Simplifying Nickel(0) Catalysis: An Air-stable, COD-free Nickel Precatalyst for the Internally-selective Benzylation of Terminal Alkenes

    E-Print Network [OSTI]

    Jamison, Timothy F.

    The synthesis and characterization of the air-stable nickel(II) complex trans-(PCy[subscript 2]Ph)[subscript 2]Ni(o-tolyl)Cl is described in conjunction with an investigation of its use for the Mizoroki–Heck-type, room ...

  11. Gold-nickel-titanium brazing alloy

    DOE Patents [OSTI]

    Mizuhara, Howard

    1995-01-03T23:59:59.000Z

    A brazing alloy in accordance with this invention has the following composition, by weight: 91 to 99 gold, 0.5 to 7% nickel; 0.10 to 2% titanium. Alternatively, with palladium present, the composition is as follows, by weight: 83 to 96% gold; 3 to 10% palladium; 0.5 to 5% nickel; 0.10 to 2% titanium.

  12. Gold-nickel-titanium brazing alloy

    DOE Patents [OSTI]

    Mizuhara, Howard (Hillsborough, CA)

    1990-07-03T23:59:59.000Z

    A brazing alloy in accordance with this invention has the following composition, by weight: 91 to 99% gold, 0.5 to 7% nickel; 0.10 to 2% titanium. Alternatively, with palladium present, the composition is as follows, by weight: 83 to 96% gold; 3 to 10% palladium; 0.5 to 5% nickel; 0.10 to 2% titanium.

  13. INTEGRAL FIELD SPECTROSCOPY OF SUPERNOVA EXPLOSION SITES: CONSTRAINING THE MASS AND METALLICITY OF THE PROGENITORS. I. TYPE Ib AND Ic SUPERNOVAE

    SciTech Connect (OSTI)

    Kuncarayakti, Hanindyo; Maeda, Keiichi [Kavli Institute for the Physics and Mathematics of the Universe (WPI), Todai Institutes for Advanced Study, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8583 (Japan); Doi, Mamoru; Morokuma, Tomoki; Hashiba, Yasuhito [Institute of Astronomy, Graduate School of Science, The University of Tokyo, 2-21-1 Osawa, Mitaka, Tokyo 181-0015 (Japan); Aldering, Greg [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Arimoto, Nobuo [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-0015 (Japan); Pereira, Rui [CNRS/IN2P3, Institut de Physique Nucleaire de Lyon, 4 Rue Enrico Fermi, F-69622 Villeurbanne Cedex (France); Usuda, Tomonori, E-mail: hanindyo.kuncarayakti@ipmu.jp [Subaru Telescope, National Astronomical Observatory of Japan, 650 North A'ohoku Place, Hilo, HI 96720 (United States)

    2013-08-01T23:59:59.000Z

    Integral field spectroscopy of 11 Type Ib/Ic supernova (SN Ib/Ic) explosion sites in nearby galaxies has been obtained using UH88/SNIFS and Gemini-N/GMOS. The use of integral field spectroscopy enables us to obtain both spatial and spectral information about the explosion site, enabling the identification of the parent stellar population of the SN progenitor star. The spectrum of the parent population provides metallicity determination via strong-line method and age estimation obtained via comparison with simple stellar population models. We adopt this information as the metallicity and age of the SN progenitor, under the assumption that it was coeval with the parent stellar population. The age of the star corresponds to its lifetime, which in turn gives the estimate of its initial mass. With this method we were able to determine both the metallicity and initial (zero-age main sequence) mass of the progenitor stars of SNe Ib and Ic. We found that on average SN Ic explosion sites are more metal-rich and younger than SN Ib sites. The initial mass of the progenitors derived from parent stellar population age suggests that SN Ic has more massive progenitors than SN Ib. In addition, we also found indication that some of our SN progenitors are less massive than {approx}25 M{sub Sun }, indicating that they may have been stars in a close binary system that have lost their outer envelope via binary interactions to produce SNe Ib/Ic, instead of single Wolf-Rayet stars. These findings support the current suggestions that both binary and single progenitor channels are in effect in producing SNe Ib/Ic. This work also demonstrates the power of integral field spectroscopy in investigating SN environments and active star-forming regions.

  14. Statistical Time-Resolved Spectroscopy: A higher fraction of short-period binaries for metal-rich F-type dwarfs in SDSS

    E-Print Network [OSTI]

    Hettinger, T; Strader, J; Bickerton, S J; Beers, T C

    2015-01-01T23:59:59.000Z

    Stellar multiplicity lies at the heart of many problems in modern astrophysics, including the physics of star formation, the observational properties of unresolved stellar populations, and the rates of interacting binaries such as cataclysmic variables, X-ray binaries, and Type Ia supernovae. However, little is known about the stellar multiplicity of field stars in the Milky Way, in particular about the differences in the multiplicity characteristics between metal-rich disk stars and metal-poor halo stars. In this study we perform a statistical analysis of ~15,000 F-type dwarf stars in the Milky Way through time-resolved spectroscopy with the sub-exposures archived in the Sloan Digital Sky Survey. We obtain absolute radial velocity measurements through template cross-correlation of individual sub-exposures with temporal baselines varying from minutes to years. These sparsely sampled radial velocity curves are analyzed using Markov chain Monte Carlo techniques to constrain the very short-period binary fraction...

  15. Search For Iron, Nickel, and Fluorine in PG1159 Stars

    E-Print Network [OSTI]

    E. Reiff; T. Rauch; K. Werner; J. W. Kruk; L. Koesterke

    2008-03-01T23:59:59.000Z

    A possible origin of the iron-deficiency in PG1159 stars could be neutron captures on Fe nuclei. A nickel overabundance would corroborate this idea. Consequently we are looking for nickel lines in PG1159 stars. Prime targets are relatively cool objects, because Ni VI is the dominant ionisation stage and the spectral lines of this ion are accessible with UV observations. We do not find such lines in the coolest PG1159 star observed by FUSE (PG1707+427, Teff = 85,000 K) and conclude that the nickel abundance is not enhanced. Hence, the Fe-deficiency in PG1159 stars remains unexplained. In addition, we present results of a wind analysis of the hybrid-PG1159 star NGC 7094 and the [WC]-PG1159 transition-type object Abell 78 in order to derive F abundances from the F VI 1139.5 Angstrom line. In both cases, we find F overabundances, in agreement with results of photospheric analyses of many PG1159 stars. Surprisingly, we find indications for a very low O abundance in NGC 7094.

  16. Initiation of electroless nickel plating on copper, palladium-activated copper, gold, and platinum

    SciTech Connect (OSTI)

    Flis, J.; Duquette, D.J.

    1984-02-01T23:59:59.000Z

    The catalytic activity of copper, palladium-activated copper, gold, and platinum for electro-oxidation of hypophosphite and electroless nickel plating was investigated in an ammoniacal solution of pH 8.8 at 50/sup 0/C by potential measurements and linear sweep voltammetry from -0.3 to -0.92V vs. SCE. Early stages of nickel plating on copper-palladium substrates were studied by scanning electron microscopy in conjunction with EDAX. It was found that palladium-activated copper and gold were catalytically active in the entire range of potentials examined; copper was active below -0.6 platinum was not active at all. Small amounts of electrolytically deposited nickel considerably increased the electro-oxidation rate of hypophosphite on copper, gold, and palladium. TEM examinations showed that activation of copper in a PdCl/sub 2//HCl solution resulted in the deposition of palladium in the form of separate patches. Electroless nickel deposition on copper substrates with separate palladium spots took place on copper and palladium independently of each other. The deposition on palladium was faster than that on copper. It was concluded that the activation of copper substrates around palladium spots occurred solely through a spontaneous potential shift, induced by electro-oxidation of hypophosphite on the palladium spots. It was suggested that small amounts of one metal synergistically enhanced the catalytic activity of the other metals.

  17. Proton Diffusion in Nickel Hydroxide Prediction of Active Material Utilization

    E-Print Network [OSTI]

    Weidner, John W.

    to improve battery design and operation. Introduction Nickel hydroxide is the active material in rechargeable of protons, we used elec- trochemical impedance spectroscopy to measure D+ in planar nickel hydroxide films nickel batteries (e.g., Ni/Cd, Ni/Zn, and Ni/H2). Nickel batteries are usually positive limited, meaning

  18. Micromachined Nickel Floating Element Shear Stress Sensor Array , J. Gallmanb

    E-Print Network [OSTI]

    White, Robert D.

    Micromachined Nickel Floating Element Shear Stress Sensor Array Z. Zhaoa , J. Gallmanb , R. Whitea (Technic Copper FB) and patterned lithographically. A Nickel structural layer with varied thickness is deposited from a nickel sulfamate plating solution (Technic Nickel Sulfamate SemiBright) and patterned

  19. Conduction properties of metal/organic monolayer/semiconductor heterostructures

    SciTech Connect (OSTI)

    Li, D.; Bishop, A.; Gim, Y.; Shi, X.B.; Fitzsimmons, M.R.; Jia, Q.X. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    1998-11-01T23:59:59.000Z

    We have fabricated and characterized rectifying devices made of metal/organic monolayer/semiconductor heterostructures. The devices consist of an organic barrier layer sandwiched between an aluminum (Al) metal contact and a {ital p}-type Si semiconductor. The barrier materials were chosen from three types of self-assembled monolayers (SAMs) with different electronic properties: (1) wide-band gap poly(diallydimethyl ammonium) chloride (PDDA), (2) narrow-band gap PDDA/NiPc (nickel phthalocyanine tetrasulfonate), and (3) donor type PDDA/PPP (poly {ital p}-quaterphenylene-disulfonic-dicarboxylic acid). From current{endash}voltage (I{endash}V) measurements at room temperature, we have found the turn-on voltage of the devices can be tuned by varying the structure, hence electronic properties, of the organic monolayers, and that there exists a power-law dependence of {ital I} on V, I{proportional_to}V{sup {alpha}}, with the exponent {alpha}=2.2 for PDDA, 2.7 for PDDA/NiPc, and 1.44 for PDDA/PPP as the barrier layer, respectively. Our results imply that the transport properties are controlled by both the electronic properties of the SAMs and those of the metal and semiconductor, as indicated by the power-law dependence of the I{endash}V characteristics. {copyright} {ital 1998 American Institute of Physics.}

  20. A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

    E-Print Network [OSTI]

    Müller, Peter

    A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel ABSTRACT: A series of air-stable nickel complexes of the form L2Ni(aryl) X (L = monodentate phosphine, X of precatalysts suitable for a wide variety of nickel-catalyzed transformations. These complexes are easily

  1. Nickel vacancy behavior in the electrical conductance of nonstoichiometric nickel oxide film

    SciTech Connect (OSTI)

    Kim, Dong Soo; Lee, Hee Chul [Department of Electrical Engineering, Korea Advanced Institute of Science and Technology, 335 Gwahangno, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)

    2012-08-01T23:59:59.000Z

    Nickel vacancy behavior in electrical conductance is systematically investigated using various analysis methods on nickel oxide films deposited at different oxygen partial pressures. The results of Rutherford backscattering, x-ray diffraction, and Auger electron spectroscopy analyses demonstrate that the sputtered nickel oxide films are nickel-deficient. Through the deconvolution of Ni2p and O1s spectra in the x-ray photoelectron spectroscopy data, the number of Ni{sup 3+} ions is found to increase with the O{sub 2} ratio during the deposition. According to the vacancy model, nickel vacancies created from the non-stoichiometry are concluded to produce Ni{sup 3+} ions which lead to an increment of the conductivity of the nickel oxide films due to the increase of the hole concentration.

  2. Nickel porphyrins for memory optical applications

    DOE Patents [OSTI]

    Shelnutt, John A. (Tijeras, NM); Jia, Songling (Albuquerque, NM); Medforth, Craig (Vacaville, CA); Holten, Dewey (St. Louis, MO); Nelson, Nora Y. (Manteca, CA); Smith, Kevin M. (Davis, CA)

    2000-01-01T23:59:59.000Z

    The present invention relates to a nickel-porphyrin derivative in a matrix, the nickel-porphyrin derivative comprising at least two conformational isomers, a lower-energy-state conformer and a higher-energy-state conformer, such that when the higher-energy-state conformer is generated from the lower-energy-state conformer following absorption of a photon of suitable energy, the time to return to the lower-energy-state conformer is greater than 40 nanoseconds at approximately room temperature. The nickel-porphyrin derivative is useful in optical memory applications.

  3. Aspects of electroless nickel plating on molybdenum

    SciTech Connect (OSTI)

    Mikkola, R.D.; Daugherty, C.E.; Harris, G.E.; Neff, W.A.; Owens, W.W.

    1984-07-01T23:59:59.000Z

    A process for depositing an adherent coating of an electroless nickel-phosphorus alloy on molybdenum was developed. The required pretreatment processes included an anodic etch in a chromic acid-nitric acid solution, an anodic etch in a phosphonic acid solution, and an oxide stripping step in a chromic acid-nitric acid solution. Initiation of the electroless nickel plating was accomplished through a series of strikes in the nickel bath. Scale up from laboratory parts to large components involved optimization of parameters such as pretreat time, current density, anode to cathode ratio and strike time.

  4. THE DEVELOPMENT OF NICKEL-FREE AUSTENITIC STAINLESS STEELS FOR AMBIENT AND CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Haddick, Glen T.

    2011-01-01T23:59:59.000Z

    7397 c THE DEVELOPMENT OF NICKEL-FREE AUSTENITIC STAINLESSTHE DEVELOPMENT OF NICKEL-FREE AUSTENITIC STAINLESS STEELS92121. THE DEVELOPMENT OF NICKEL-FREE AUSTENITIC STAINLESS

  5. Increasing the thermoelectric figure of merit of tetrahedrites by Co-doping with nickel and zinc

    E-Print Network [OSTI]

    Lu, X; Morelli, DT; Morelli, DT; Xia, Y; Ozolins, V

    2015-01-01T23:59:59.000Z

    by  Co-­? doping  with  Nickel  and  Zinc   Xu  Lu 1 ,  t 2g   states   of   nickel   indeed   lie   in   the  of   the   dopant  nickel  ions.  While  one  could  

  6. Ni/metal hydride secondary element

    DOE Patents [OSTI]

    Bauerlein, Peter

    2005-04-19T23:59:59.000Z

    A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Ca(OH).sub.2, as well as mixtures of these compounds.

  7. In situ atomic force microscopy imaging of electroprecipitated nickel hydrous oxide films in alkaline electrolytes

    SciTech Connect (OSTI)

    Chen, R.; Mo, Y.; Scherson, D.A. (Case Western Reserve Univ., Cleveland, OH (United States))

    1994-11-01T23:59:59.000Z

    In situ atomic force microscopy images of nickel hydrous oxide films electrodeposited on the basal plane of highly oriented pyrolytic graphite in alkaline electrolytes have shown that a stepwise oxidation leads to irreversible formation of wide crevices throughout the material. Upon subsequent stepwise reduction, the gaps close leaving a hairline type crack which follows the profile of the crevice. These potential induced structural rearrangements have been attributed to stresses induced by differences in the densities of the nickel hydrous oxide in the two oxidation states. 9 refs., 5 figs.

  8. Electrochromic properties of nickel oxide thin films prepared by the sol-gel method

    SciTech Connect (OSTI)

    Miki, Takeshi; Yoshimura, Kazuki; Tai, Yutaka; Tazawa, Masato; Jin, P.; Tanemura, Sakae [National Industrial Research Inst., Nagoya (Japan). Multifunctional Material Science Dept.

    1995-12-31T23:59:59.000Z

    Recently electrochromic (EC) device has been attractive as a smart glazing to control heating, cooling and lighting loads of buildings and housing. Among various electrochromic materials, nickel oxide is one of the typical anode type materials. Here, the electrochromic nickel oxide films were prepared onto transparent conducting film on glass substrate by the sol-gel method using an ethylene glycol solution of nickel nitrate hexahydrate. The films produced by the dip-coating method and calcined at 250, 300 and 350 C. The formed films were characterized by their electrochromic behavior in cyclic voltammetry. The formed films showed electrochromic behavior in 1M KOH aqueous solution as electrolytic solution. The cyclic voltammograms were recorded up to 100 cycles for each film. The anodic peak of the coloration reaction appeared at approximately +400 mV, while the cathodic peak of the bleaching reaction occurred at about +200 mV vs. Ag/AgCl. Both the anodic peak and the cathodic peak increased with an increase of the cyclic numbers in voltammograms, whereas these peaks at 100 cycles decreased with an increase of the calcination temperature of nickel oxide films. The calcination gave great influence on the other electrochromic behaviors of nickel oxide films.

  9. A novel plating process for microencapsulating metal hydrides

    SciTech Connect (OSTI)

    Law, H.H.; Vyas, B.; Zahurak, S.M.; Kammlott, G.W. [AT and T Bell Labs., Murray Hill, NJ (United States)

    1996-08-01T23:59:59.000Z

    One approach to increasing the lifetime of the metal hydride electrode has been the use of conventional electroless plating to produce a coating of copper or nickel on the surface of the metal hydride powders. In this paper, a novel method for microencapsulating the active electrode powders is presented. This new plating technique takes advantage of the reducing power of hydrogen already stored inside the metal hydride to plate a variety of metals onto metal hydride materials. This method greatly simplifies electroless plating for these powders, eliminating the need for stabilizers and additives typically required for conventional electroless plating solutions. Metals that can be electrolessly plated with stored hydrogen have been identified based on thermodynamic considerations. Experimentally, micrometers thick coatings of copper, silver, and nickel have been plated on several metal hydrides.

  10. Comparison of Nonprecious Metal Cathode Materials for Methane Production by Electromethanogenesis

    E-Print Network [OSTI]

    contributed to electromethanogenic gas production. KEYWORDS: Biocathode, Carbon capturing and sequestration generation, we examined several cathode materials: plain graphite blocks, graphite blocks coated with carbon black or carbon black containing metals (platinum, stainless steel or nickel) or insoluble minerals

  11. Crystallographic studies of the metal-responsive transcription factor NikR

    E-Print Network [OSTI]

    Schreiter, Eric R. (Eric Robert)

    2005-01-01T23:59:59.000Z

    Metal ion homeostasis is critical to the survival of all cells, because requirements for these essential nutrients must be balanced with their toxicity when present at elevated concentrations. Regulation of nickel ...

  12. Inspection of Nickel Alloy Welds: Results from Five Year International Program

    SciTech Connect (OSTI)

    Prokofiev, Iouri; Cumblidge, Stephen E.; Doctor, Steven R.

    2011-06-23T23:59:59.000Z

    The U.S. Nuclear Regulatory Commission established and coordinated the international Program for the Inspection of Nickel alloy Components (PINC). The goal of PINC was to evaluate the capabilities of various nondestructive examination (NDE) techniques to detect and characterize primary water stress corrosion cracking (PWSCC) in dissimilar metal welds. Round-robin results showed that a combination of conventional and phased-array ultrasound provide the highest performance for flaw detection and depth sizing in dissimilar metal piping welds. The effective detection of flaws in bottom-mounted instrumentation penetrations by eddy current and ultrasound shows that it may be possible to reliably inspect these components in the field.

  13. Electrodeposition of nickel-iron alloys: Regular codeposition induced by the presence of ethylenediamine

    SciTech Connect (OSTI)

    St. Clair, J.; Harris, T. [Univ. of Tulsa, OK (United States)

    1996-10-01T23:59:59.000Z

    The nickel-iron alloy electrodeposition system typically exhibits a phenomenon known as {open_quotes}anomalous codeposition{close_quotes}, where the less noble metal (Fe) deposits preferentially to the more noble metal (Ni). The addition of ethylenediamine to the bath changes the electrodeposition toward {open_quotes}regular codeposition{close_quotes}, i.e. less Fe and more Ni am found in the deposit. The impact of various electrodeposition parameters, including the concentrations of ferrous ion and ethylenediamine and the pH of the bath, on this change in behavior will be presented.

  14. Study of electroless nickel plating of ceramic particles

    SciTech Connect (OSTI)

    Deuis, R.L.; Subramanian, C.; Strafford, K.N.; Arora, P. [Univ. of South Australia (Australia)] [Univ. of South Australia (Australia); Yellup, J.M. [CSIRO, Woodville North, South Australia (Australia). Div. of Manufacturing Technology] [CSIRO, Woodville North, South Australia (Australia). Div. of Manufacturing Technology

    1995-10-15T23:59:59.000Z

    In the production of aluminum-based metal matrix composites (MMC), the wettability of the reinforcement particulates by the matrix is an important factor. The manufacture of MMC reinforced with alumina particles require the use of specialized fabrication techniques such as rheocasting in order to achieve effective particle incorporation. Several surface treatments have been applied to alumina and other reinforcement particulates in order to modify particle wettability. The aim of this study was to investigate the deposition of Ni-P onto several ceramic particulate surfaces without the use of the conventional sensitization and activation steps. This nickel plating treatment, had the potential to improve the incorporation of alumina particles in aluminum melts, with respect to MMC formation by the plasma transferred arc (PTA) surfacing process.

  15. XAFS Studies of Nickel And Sulfur Speciation in Residual Oil Fly-Ash Particulate Matters (ROFA PM)

    SciTech Connect (OSTI)

    Pattanaik, S.; Huggins, F.E.; Huffman, G.P.; Linak, W.P.; Miller, C.A.

    2007-07-12T23:59:59.000Z

    XAFS spectroscopy has been employed to evaluate the effect of fuel compositions and combustion conditions on the amount, form, and distribution of sulfur and nickel in size-fractionated ROFA PM. Analysis of S K-edge XANES establish that sulfate is abundant in all PM. However, depending upon the combustion conditions, lesser amounts of thiophenic sulfur, metal sulfide, and elemental sulfur may also be observed. Least-squares fitting of Ni K-edge XANES reveals that most of the nickel in PM is present as bioavailable NiSO{sub 4}.nH{sub 2}O. The insoluble Ni mainly exists as a minor species, as nickel ferrite in PM{sub 2.5} (PM < 2.5 {micro}m) and nickel sulfide, NixSy in PM{sub 2.5+} (PM > 2.5 {micro}m). The Ni K-edge XANES results are in agreement with the EXAFS data. Such detailed speciation of Ni and S in PM is needed for determining their mobility, bioavailability, and reactivity, and hence, their role in PM toxicity. This information is also important for understanding the mechanism of PM formation, developing effective remediation measures, and providing criteria for identification of potential emission sources. Transition metals complexing with sulfur is ubiquitous in nature. Therefore, this information on metal sulfur complex can be critical to a large body of environmental literature.

  16. Stabilization of Nickel Metal Catalysts for Aqueous Processing Systems -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  17. Steps to Commercialization: Nickel Metal Hydride Batteries | Department of

    Energy Savers [EERE]

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  18. Steps to Commercialization: Nickel Metal Hydride Batteries | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative JC3 RSS September 9,AwardGradsSites PendingAgreementsSteam Systems Steam

  19. Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer

    DOE Patents [OSTI]

    Fish, R.H.

    1987-04-21T23:59:59.000Z

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20 to 100 C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  20. Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, R.H.

    1985-05-17T23:59:59.000Z

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids (shale oil, SRC, etc.) by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20/sup 0/ to 100/sup 0/C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  1. Formation of Carbon Nanostructures in Cobalt- and Nickel-Doped Carbon Aerogels

    SciTech Connect (OSTI)

    Fu, R; Baumann, T F; Cronin, S; Dresselhaus, G; Dresselhaus, M; Satcher, Jr., J H

    2004-11-09T23:59:59.000Z

    We have prepared carbon aerogels (CAs) doped with cobalt or nickel through sol-gel polymerization of formaldehyde with the potassium salt of 2,4-dihydroxybenzoic acid, followed by ion-exchange with M(NO{sub 3}){sub 2} (where M = Co{sup 2+} or Ni{sup 2+}), supercritical drying with liquid CO{sub 2} and carbonization at temperatures between 400 C and 1050 C under an N{sub 2} atmosphere. The nanostructures of these metal-doped carbon aerogels were characterized by elemental analysis, nitrogen adsorption, high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Metallic nickel and cobalt nanoparticles are generated during the carbonization process at about 400 C and 450 C, respectively, forming nanoparticles that are {approx}4 nm in diameter. The sizes and size dispersion of the metal particles increase with increasing carbonization temperatures for both materials. The carbon frameworks of the Ni- and Co-doped aerogels carbonized below 600 C mainly consist of interconnected carbon particles with a size of 15 to 30 nm. When the samples are pyrolyzed at 1050 C, the growth of graphitic nanoribbons with different curvatures is observed in the Ni and Co-doped carbon aerogel materials. The distance of graphite layers in the nanoribbons is about 0.38 nm. These metal-doped CAs retain the overall open cell structure of metal-free CAs, exhibiting high surface areas and pore diameters in the micro and mesoporic region.

  2. Advanced technologies for decomtamination and conversion of scrap metal

    SciTech Connect (OSTI)

    Valerie MacNair; Steve Sarten; Thomas Muth; Brajendra Mishra

    1999-05-27T23:59:59.000Z

    The Department of Energy (DOE) faces the task of decommissioning much of the vast US weapons complex. One challenge of this effort includes the disposition of large amounts of radioactively contaminated scrap metal (RSM) including but not limited to steel, nickel, copper, and aluminum. The decontamination and recycling of RSM has become a key element in the DOE's strategy for cleanup of contaminated sites and facilities. Recycling helps to offset the cost of decommissioning and saves valuable space in the waste disposal facilities. It also reduces the amount of environmental effects associated with mining new metals. Work on this project is geared toward finding decontamination and/or recycling alternatives for the RSM contained in the decommissioned gaseous diffusion plants including approximately 40,000 tons of nickel. The nickel is contaminated with Technetium-99, and is difficult to remove using traditional decontamination technologies. The project, titled ``Advanced Technologies for Decontamination and Conversion of Scrap Metal'' was proposed as a four phase project. Phase 1 and 2 are complete and Phase 3 will complete May 31, 1999. Stainless steel made from contaminated nickel barrier was successfully produced in Phase 1. An economic evaluation was performed and a market study of potential products from the recycled metal was completed. Inducto-slag refining, after extensive testing, was eliminated as an alternative to remove technetium contamination from nickel. Phase 2 included successful lab scale and pilot scale demonstrations of electrorefining to separate technetium from nickel. This effort included a survey of available technologies to detect technetium in volumetrically contaminated metals. A new process to make sanitary drums from RSM was developed and implemented. Phase 3 included a full scale demonstration of electrorefining, an evaluation of electro-refining alternatives including direct dissolution, melting of nickel into anodes, a laser cutting demonstration, an investigation of commercial markets for RSM, and refinement of methods to quantify isotopic elements.

  3. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01T23:59:59.000Z

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  4. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas. Reversible Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen...

  5. Nickel-Catalyzed Allylic Substitution of Simple Alkenes

    E-Print Network [OSTI]

    Matsubara, Ryosuke

    This report describes a nickel-catalyzed allylic substitution process of simple alkenes whereby an important structural motif, a 1,4-diene, was prepared. The key to success is the use of an appropriate nickel–phosphine ...

  6. Mechanisms of Nickel Sorption on Pyrophyllite: Macroscopic and Microscopic Approaches

    E-Print Network [OSTI]

    Sparks, Donald L.

    Mechanisms of Nickel Sorption on Pyrophyllite: Macroscopic and Microscopic Approaches Andre M adsorption are involved. In the higher pH region (pH >7), nickel sorption becomes slow and does not seem

  7. Preliminary evaluation of electrowinning for nickel scrap processing

    SciTech Connect (OSTI)

    Brown, G.M.; Compere, A.L.; Griffith, W.L.; Hayden, H.W.; Wilson, D.F.

    1996-12-01T23:59:59.000Z

    Purification of the 70,000 to 245,000 tons of diffusion plant nickel scrap permit its use in a variety of DOE and, with establishment of de minimus standards, foreign and domestic industrial applications. Nickel recycle would also substantially decrease DOE legacy wastes. This report presents data on electrolytes and separations which could be used in electrolytic purification of radiologically contaminated nickel scrap from first generation diffusion plants. Potentiometric scans and plating tests indicate that both industrial electrolytes, buffered nickel sulfate-sodium chloride and nickel chloride, provide good current densities. Electrolytes which contain ammonium thiocyanate or ammonium chloride also perform well. Nickel does not plate appreciably from nitrate solutions because the nitrate was preferentially reduced to nitrite. Solvent extractions of cobalt, a common contaminant in commercial nickel, and pertechnate, a radiological contaminant expected in DOE nickel scrap, are also successful.

  8. Water treatment process and system for metals removal using Saccharomyces cerevisiae

    DOE Patents [OSTI]

    Krauter, Paula A. W. (Livermore, CA); Krauter, Gordon W. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    A process and a system for removal of metals from ground water or from soil by bioreducing or bioaccumulating the metals using metal tolerant microorganisms Saccharomyces cerevisiae. Saccharomyces cerevisiae is tolerant to the metals, able to bioreduce the metals to the less toxic state and to accumulate them. The process and the system is useful for removal or substantial reduction of levels of chromium, molybdenum, cobalt, zinc, nickel, calcium, strontium, mercury and copper in water.

  9. Mechanical and metallographic characterization of LIGA fabricated nickel and 80%Ni-20%Fe Permalloy

    SciTech Connect (OSTI)

    Christenson, T.R.; Buchheit, T.E.; Schmale, D.T. [Sandia National Labs., Albuquerque, NM (United States); Bourcier, R.J. [Corning Inc., NY (United States). Photonic Technologies Div.

    1998-04-13T23:59:59.000Z

    A table top servohydraulic load frame equipped with a laser displacement measurement system was constructed for the mechanical characterization of LIGA fabricated electroforms. A drop in tensile specimen geometry which includes a pattern to identify gauge length via laser scanning has proven to provide a convenient means to monitor and characterize mechanical property variations arising during processing. In addition to tensile properties, hardness and metallurgical data were obtained for nickel deposit specimens of current density varying between 20 and 80 mA/cm{sup 2} from a sulfamate based bath. Data from 80/20 nickel-iron deposits is also presented for comparison. As expected, substantial mechanical property differences from bulk metal properties are observed as well as a dependence of material strength on current density which is supported by grain size variation. While elastic modulus values of the nickel electrodeposit are near 160 GPa, yield stress values vary by over 60%. A strong orientation in the metal electrodeposits as well as variations in nucleating and growth morphology present a concern for anisotropic and geometry dependent mechanical properties within and between different LIGA components.

  10. Nickel assisted healing of defective graphene S. Karoui,1

    E-Print Network [OSTI]

    Boyer, Edmond

    Nickel assisted healing of defective graphene S. Karoui,1 H. Amara,1 C. Bichara,2 and F. Ducastelle suggesting that their healing are thermally activated. We show that in presence of a nickel substrate we obtain a perfect graphene layer. The nickel-carbon chemical bonds keep breaking and reforming around

  11. Nickel Complexes DOI: 10.1002/anie.200804435

    E-Print Network [OSTI]

    Hone, James

    Angewandte Chemie Nickel Complexes DOI: 10.1002/anie.200804435 A Stable Tetraalkyl Complex of Nickel(IV)** Matthew Carnes, Daniela Buccella, Judy Y.-C. Chen, Arthur P. Ramirez, Nicholas J. TurroA, Weinheim Angew. Chem. Int. Ed. 2009, 48, 290 ­294 #12;Herein we describe the reaction of nickel(0

  12. Karl L. E. Nickel (1924 2009) Jurgen Garloff

    E-Print Network [OSTI]

    Kearfott, R. Baker

    Karl L. E. Nickel (1924 ­ 2009) J¨urgen Garloff Konstanz, Germany garloff@htwg-konstanz.de DIE Fehler kleiner Epsi- lon Professor Dr. Karl Nickel, one of the founding fathers of interval computa- tions in Germany, died on January 1, 2009, a couple of weeks before his 85th birthday1 . Karl Nickel

  13. Nickel Electroplating for Nanostructure Mold Fabrication * Xiaohui Lin1

    E-Print Network [OSTI]

    Chen, Ray

    Nickel Electroplating for Nanostructure Mold Fabrication * Xiaohui Lin1 , Xinyuan Dou1 , Xiaolong demonstrated a practical process of fabricating nickel molds for nanoimprinting. Dual-side polished glass is chosen as the substrate on which nickel nanostructures are successfully electroplated. Photonic crystal

  14. Caustic stress corrosion cracking of E-Brite and Carpenter 7-MO stainless steels welded to Nickel 200 and Inconel 600

    E-Print Network [OSTI]

    Stockman, Steven Miles

    1982-01-01T23:59:59.000Z

    steel, each welded separatelv to Nickel 200 and Inconel 600, were teated for stress corrosion cracking in caus- tic supplied by Dow Chemical of Freeport, Texas, The V-bend type of specimen was tested in the caustic at room temperature, 60C and 800... ' The oh/ective of the test was to determine whether either of the stainless steels could be used in re- pairing nickel and nickel alloy equipment at the Dow Chemical caustic plant. Both stainless steels passed the initial test- ing and are recommended...

  15. Black nickel selective absorber, optimization of parameters

    SciTech Connect (OSTI)

    Akinoglu, B.; Cercioglu, V.; Ecevit, A.

    1983-12-01T23:59:59.000Z

    Electroplated black nickel selective absorber is one of the most commercially used element of solar energy systems. Electrodeposition parameters such as time of deposition, pH, current density, electrolyte temperature should be optimized to produce the most efficient selective absorber. The topology of the substrate material is very effective on selectivity and it should also be optimized. In this study, by controlling the conditions of electrodeposition black nickel selective absorbers are produced and their reflectivities are measured. The effects of the electrodeposition parameters together with the topology of the substrate, on the selective properties are investigated.

  16. Positive bias temperature instability in p-type metal-oxide-semiconductor devices with HfSiON/SiO{sub 2} gate dielectrics

    SciTech Connect (OSTI)

    Samanta, Piyas, E-mail: piyas@vcfw.org [Department of Physics, Vidyasagar College for Women, 39 Sankar Ghosh Lane, Kolkata 700 006 (India); Huang, Heng-Sheng; Chen, Shuang-Yuan [Institute of Mechatronic Engineering, National Taipei University of Technology, No. 1, Sec. 3, Chung-Hsiao E. Rd., Taipei 106, Taiwan (China); Liu, Chuan-Hsi [Department of Mechatronic Technology, National Taiwan Normal University, No. 162, Sec. 1, He-Ping E. Rd., Taipei 106, Taiwan (China); Cheng, Li-Wei [Central R and D Division, United Microelectronics Corporation, No. 3, Li-Hsin Rd. II, Hsinchu 300, Taiwan (China)

    2014-02-21T23:59:59.000Z

    We present a detailed investigation on positive-bias temperature stress (PBTS) induced degradation of nitrided hafnium silicate (HfSiON)/SiO{sub 2} gate stack in n{sup +}-poly crystalline silicon (polySi) gate p-type metal-oxide-semiconductor (pMOS) devices. The measurement results indicate that gate dielectric degradation is a composite effect of electron trapping in as-fabricated as well as newly generated neutral traps, resulting a significant amount of stress-induced leakage current and generation of surface states at the Si/SiO{sub 2} interface. Although, a significant amount of interface states are created during PBTS, the threshold voltage (V{sub T}) instability of the HfSiON based pMOS devices is primarily caused by electron trapping and detrapping. It is also shown that PBTS creates both acceptor- and donor-like interface traps via different depassivation mechanisms of the Si{sub 3}???SiH bonds at the Si/SiO{sub 2} interface in pMOS devices. However, the number of donor-like interface traps ?N{sub it}{sup D} is significantly greater than that of acceptor-like interface traps ?N{sup A}{sub it}, resulting the PBTS induced net interface traps as donor-like.

  17. Quantitative adhesion data for electroless nickel deposited on various substrates

    SciTech Connect (OSTI)

    Dini, J.W.; Johnson, H.R.

    1982-09-20T23:59:59.000Z

    This paper includes a review of the literature on quantitative adhesion of electroless nickel coatings and then presents recent ring shear quantitative data for the electroless nickel deposited on a variety of substrates. Procedures for obtaining good adhesion between electroless nickel coatings and a variety of aluminum alloys (1100, 2024, 5083, 6061 and 7075), beryllium-copper, 4340 steel, HP 9-4-20 steel, and U-0.75 Ti are outlined. In addition, data are presented on a procedure for activating electroless nickel for subsequent coating with electrodeposited nickel. 6 tables.

  18. Quantitative adhesion data for electroless nickel deposited on various substrates

    SciTech Connect (OSTI)

    Dini, J.W.; Johnson, H.R.

    1983-01-01T23:59:59.000Z

    A review of the literature on quantitative adhesion of electroless nickel coatings is given and recent ring shear quantitative data for the electroless nickel deposited on a variety of substrates are presented. Procedures for obtaining good adhesion between electroless nickel coatings and a variety of aluminum alloys (1100, 2024, 5083, 6061 and 7075), beryllium-copper, 4340 steel and HP 9-4-20 steel are outlined. In addition, data are presented on a procedure for activating electroless nickel for subsequent coating with electrodeposited nickel.

  19. Structural Basis of Low-Affinity Nickel Binding to the Nickel-Responsive Transcription Factor NikR from Escherichia coli

    E-Print Network [OSTI]

    Phillips, Christine M.

    Escherichia coli NikR regulates cellular nickel uptake by binding to the nik operon in the presence of nickel and blocking transcription of genes encoding the nickel uptake transporter. NikR has two binding affinities for ...

  20. Proposed sale of radioactively contaminated nickel ingots located at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) proposes to sell 8,500 radioactively contaminated nickel ingots (9.350 short tons), currently in open storage at the Paducah Gaseous Diffusion Plant (PGDP), to Scientific Ecology Group, Inc. (SEG) for decontamination and resale on the international market. SEG would take ownership of the ingots when they are loaded for transport by truck to its facility in Oak Ridge, Tennessee. SEG would receive approximately 200 short tons per month over approximately 48 months (an average of 180 ingots per month). The nickel decontamination process specified in SEG`s technical proposal is considered the best available technology and has been demonstrated in prototype at SEG. The resultant metal for resale would have contamination levels between 0.3 and 20 becquerel per gram (Bq/g). The health hazards associated with release of the decontaminated nickel are minimal. The activity concentration of the end product would be further reduced when the nickel is combined with other metals to make stainless steel. Low-level radioactive waste from the SEG decontamination process, estimated to be approximately 382 m{sup 3} (12,730 ft), would be shipped to a licensed commercial or DOE disposal facility. If the waste were packaged in 0.23 m{sup 3}-(7.5 ft{sup 3}-) capacity drums, approximately 1,500 to 1,900 drums would be transported over the 48-month contract period. Impacts from the construction of decontamination facilities and the selected site are minimal.

  1. Delayed Nickel Decay in Gamma Ray Bursts

    E-Print Network [OSTI]

    G. C. McLaughlin; R. A. M. J. Wijers

    2002-05-19T23:59:59.000Z

    Recently observed emission lines in the X-ray afterglow of gamma ray bursts suggest that iron group elements are either produced in the gamma ray burst, or are present nearby. If this material is the product of a thermonuclear burn, then such material would be expected to be rich in Nickel-56. If the nickel remains partially ionized, this prevents the electron capture reaction normally associated with the decay of Nickel-56, dramatically increasing the decay timescale. Here we examine the consequences of rapid ejection of a fraction of a solar mass of iron group material from the center of a collapsar/hypernova. The exact rate of decay then depends on the details of the ionization and therefore the ejection process. Future observations of iron, nickel and cobalt lines can be used to diagnose the origin of these elements and to better understand the astrophysical site of gamma ray bursts. In this model, the X-ray lines of these iron-group elements could be detected in suspected hypernovae that did not produce an observable gamma ray burst due to beaming.

  2. Castable nickel aluminide alloys for structural applications

    DOE Patents [OSTI]

    Liu, C.T.

    1992-04-28T23:59:59.000Z

    The specification discloses nickel aluminide alloys which include as a component from about 0.5 to about 4 at. % of one or more of the elements selected from the group consisting of molybdenum or niobium to substantially improve the mechanical properties of the alloys in the cast condition. 4 figs.

  3. Castable nickel aluminide alloys for structural applications

    DOE Patents [OSTI]

    Liu, Chain T. (Oak Ridge, TN)

    1992-01-01T23:59:59.000Z

    The specification discloses nickel aluminide alloys which include as a component from about 0.5 to about 4 at. % of one or more of the elements selected from the group consisting of molybdenum or niobium to substantially improve the mechanical properties of the alloys in the cast condition.

  4. On the solar nickel and oxygen abundances

    E-Print Network [OSTI]

    Pat Scott; Martin Asplund; Nicolas Grevesse; A. Jacques Sauval

    2009-01-27T23:59:59.000Z

    Determinations of the solar oxygen content relying on the neutral forbidden transition at 630 nm depend upon the nickel abundance, due to a Ni I blend. Here we rederive the solar nickel abundance, using the same ab initio 3D hydrodynamic model of the solar photosphere employed in the recent revision of the abundances of C, N, O and other elements. Using 17 weak, unblended lines of Ni I together with the most accurate atomic and observational data available we find log epsilon_Ni = 6.17 +/- 0.02 (statistical) +/- 0.05 (systematic), a downwards shift of 0.06 to 0.08 dex relative to previous 1D-based abundances. We investigate the implications of the new nickel abundance for studies of the solar oxygen abundance based on the [O I] 630 nm line in the quiet Sun. Furthermore, we demonstrate that the oxygen abundance implied by the recent sunspot spectropolarimetric study of Centeno & Socas-Navarro needs to be revised downwards from log epsilon_O = 8.86 +/- 0.07 to 8.71 +/- 0.10. This revision is based on the new nickel abundance, application of the best available gf-value for the 630 nm forbidden oxygen line, and a more transparent treatment of CO formation. Determinations of the solar oxygen content relying on forbidden lines now appear to converge around log epsilon_O = 8.7.

  5. Underground Corrosion of Activated Metals, 6-Year Exposure Analysis

    SciTech Connect (OSTI)

    M. K. Adler Flitton; T. S. Yoder

    2006-03-01T23:59:59.000Z

    The subsurface radioactive disposal site located at the Idaho National Laboratory contains neutronactivated metals from non-fuel nuclear-reactor-core components. A long-term underground corrosion test is being conducted to obtain site-specific corrosion rates to support efforts to more accurately estimate the transfer of activated elements in the surrounding arid vadose zone environment. The test uses nonradioactive metal coupons representing the prominent neutron-activated materials buried at the disposal location, namely, Type 304L stainless steel (UNS S30403), Type 316L stainless steel (S31603), nickel-chromium alloy (UNS NO7718), beryllium, aluminum 6061-T6 (A96061), and a zirconium alloy (UNS R60804). In addition, carbon steel (the material presently used in the cask disposal liners and other disposal containers) and a duplex stainless steel (UNS S32550) are also included in the test. This paper briefly describes the ongoing test and presents the results of corrosion analysis from coupons exposed underground for 1, 3, and 6 years.

  6. Frontispiece: origin of extraordinary stability of square-planar carbon atoms in surface carbides of cobalt and nickel.

    E-Print Network [OSTI]

    Nandula, A; Trinh, QT; Saeys, M; Alexandrova, AN

    2015-01-01T23:59:59.000Z

    Carbides of Cobalt and Nickel** Anjan Nandula, Quang Thangcarbides of cobalt and nickel are exception- ally stable,C binds to cobalt and nickel with a remarkable affinity,

  7. Origin of Extraordinary Stability of Square-Planar Carbon Atoms in Surface Carbides of Cobalt and Nickel.

    E-Print Network [OSTI]

    Nandula, A; Trinh, QT; Saeys, M; Alexandrova, AN

    2015-01-01T23:59:59.000Z

    Carbides of Cobalt and Nickel** Anjan Nandula, Quang Thangcarbides of cobalt and nickel are exception- ally stable,C binds to cobalt and nickel with a remarkable affinity,

  8. Nanostructured metal foams: synthesis and applications

    SciTech Connect (OSTI)

    Luther, Erik P [Los Alamos National Laboratory; Tappan, Bryce [Los Alamos National Laboratory; Mueller, Alex [Los Alamos National Laboratory; Mihaila, Bogdan [Los Alamos National Laboratory; Volz, Heather [Los Alamos National Laboratory; Cardenas, Andreas [Los Alamos National Laboratory; Papin, Pallas [Los Alamos National Laboratory; Veauthier, Jackie [Los Alamos National Laboratory; Stan, Marius [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    Fabrication of monolithic metallic nanoporous materials is difficult using conventional methodology. Here they report a relatively simple method of synthesizing monolithic, ultralow density, nanostructured metal foams utilizing self-propagating combustion synthesis of novel metal complexes containing high nitrogen energetic ligands. Nanostructured metal foams are formed in a post flame-front dynamic assembly with densities as low as 0.011 g/cc and surface areas as high as 270 m{sup 2}/g. They have produced metal foams via this method of titanium, iron, cobalt, nickel, zirconium, copper, palladium, silver, hafnium, platinum and gold. Microstructural features vary as a function of composition and process parameters. Applications for the metal foams are discussed including hydrogen absorption in palladium foams. A model for the sorption kinetics of hydrogen in the foams is presented.

  9. Dissolution of Nickel Oxide in a Smelter Contaminated Soil. (S02-mcnear100330-Oral)

    E-Print Network [OSTI]

    Sparks, Donald L.

    Dissolution of Nickel Oxide in a Smelter Contaminated Soil. (S02-mcnear100330-Oral) Abstract: Aerially dispersed nickel oxide particles from a nickel smelter were studied. SXRF mapping and SEM imaging XAFS and micro-XAFS analysis, indicates that nickel oxide (NiO) and nickel hydroxide (alpha -Ni(OH)2

  10. Magnesium substitutions in rare-earth metal germanides with the Gd5Si4 type. Synthesis, structure determination and magnetic properties of RE5-xMgxGe4 (RE=Gd-Tm, Lu and Y)

    SciTech Connect (OSTI)

    Sarrao, J L [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory; Tobash, P H [UNIV. OF DE; Bobev, S [UNIV. OF DE

    2009-01-01T23:59:59.000Z

    A series of magnesium-substituted rare-earth metal germanides with a general formula RE{sub 5-x}Mg{sub x}Ge{sub 4} (x {approx} 1.0-2.3; RE =Gd-Tm, Lu, Y) have been synthesized by high-temperature reactions and structurally characterized by single-crystal X-ray diffraction. These compounds crystallize with the common Gd{sub 5}Si{sub 4} type in the orthorhombic space group Pnma (No. 62; Z =4; Pearson's code oP36) and do not appear to undergo temperature-induced crystallographic phase transitions down to 120 K. Replacing rare-earth metal atoms with Mg, up to nearly 45 % at., reduces the valence electron count and is clearly expressed in the subtle changes of the Ge-Ge and metal-metal bonding. Magnetization measurements as a function of the temperature and the applied field reveal complex magnetic structures at cryogenic temperatures, and Curie-Weiss paramagnetic behavior at higher temperatures. The observed local moment magnetism is consistent with RE+ ground states in all cases. In the magnetically ordered phases, the magnetization cannot reach saturation in fields up to 50 kOe. The structural trends across the series and the variations of hte magnetic properties as a function of the Mg content are also discussed. KEYWORDS: Rare-earth intermetallics, germanides, crystal structure,Gd{sub 5}Si{sub 4} type.

  11. An experimental study of the solubility and thermodynamic properties of nickel in the system NIO + HCL + H?O 

    E-Print Network [OSTI]

    Lin, Saulwood

    1984-01-01T23:59:59.000Z

    ' were used to calculate the solubility of Ni-olivine. Calculations of fluid compositions in equilibrium with a variety of mineral assemblages indicate that nickel is not highly mobilized by chloride-bearing fluids in comparison with metals such as Fe... Knowledge of the solubilities of minerals and the properties of aqueous species in solutions is essential to understand the formation of hydrothermal ore deposits and amociated rocks. The behavior of aqueous species is reasonably well understood in simple...

  12. Direct Reduction of Waste through Refining of DOE Metal Assets - 13632

    SciTech Connect (OSTI)

    Hargett, Michael C.; Terekhov, Dimitri; Khozan, Kamran M. [Chemical Vapour Metal Refining - CVMR (United States)] [Chemical Vapour Metal Refining - CVMR (United States)

    2013-07-01T23:59:59.000Z

    CVMR{sup R} presents a technology for refining nickel from the enrichment barrier materials of the DOE that is proven through 100 years of use by the metals industry. CVMR{sup R} applies modern controls, instrumentation for process and monitoring of the system, and innovative production methods to produce a wide spectrum of products that generate new technology applications and improvements to our society and economy. CVMR{sup R} will receive barrier materials as a secure operation and size reduce the metal to a shred that is fed to a carbonylation reactor where nickel is reacted with carbon monoxide and generate nickel carbonyl. The carbonyl will be filtered and decomposed with heat to form a variety of products that include high value nano powders, coated substrates, net shapes and pure nickel. The residue from the reactor will retain radionuclides from enrichment activities. The carbon monoxide will only react and extract nickel under the operating conditions to leave volumetric contamination in the unreacted residue. A demonstration plant was designed and built by CVMR{sup R} and operated by BWXT, to demonstrate the systems capabilities to DOE in 2006. A pilot plant operation precedes the detailed design of the nickel refinery and provides essential data for design, safe work practices, waste characterizations and system kinetics and confirms the project feasibility. CVMR{sup R} produces nickel products that are cleaner than the nickel in U.S. commerce and used by industry today. The CVMR{sup R} process and systems for nickel refining is well suited for DOE materials and will provide value through environmental stewardship, recovery of high value assets, and support of the DOE environmental remediation programs as the refined nickel generates additional long term benefits to local communities. (authors)

  13. Competitive adsorption effects in the electrodeposition of iron-nickel alloys

    SciTech Connect (OSTI)

    Matlosz, M. (Ecole Polytechnique Federale de Lausanne, (Switzerland). Dept. des materiaux)

    1993-08-01T23:59:59.000Z

    Two-step reaction mechanisms involving adsorbed monovalent intermediate ions for the electrodeposition of iron and nickel as single metals can be combined to form a predictive model for the codeposition of iron-nickel alloys. Inhibition of the more noble nickel in the presence of iron is caused by preferential surface coverage of the adsorbed iron intermediate resulting from a difference between the two elements in Tafel constant for the electrosorption step. The role of hydrolyzed cations and surface pH is investigated and methods for evaluating the influence of pH are explored. The analysis shows that changes in surface pH with potential are not necessary for iron-rich (anomalous) deposits, but that variations in pH from one electrolyte to another may influence deposit composition. The tendency toward iron-rich deposits with increasing overpotential exists in all systems, however, and can be prevented only by decreasing the iron concentration of the bath. An extension of the analysis to account for transport limitations in baths with low iron concentration is developed and calculations with the model are presented to illustrate the effects of current density and electrolyte convection under conditions similar to those investigated experimentally in the literature.

  14. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1998-01-01T23:59:59.000Z

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  15. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, X.; Johnson, W.L.

    1998-04-07T23:59:59.000Z

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3}K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf){sub a}(Al,Zn){sub b}(Ti,Nb){sub c}(Cu{sub x}Fe{sub y}(Ni,Co){sub z}){sub d} wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d{hor_ellipsis}y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  16. Stabilization of Electrocatalytic Metal Nanoparticles at Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

  17. A new family of metal chalogenide thin film electrodes for photoelectrochemical applications

    SciTech Connect (OSTI)

    Rajeshwar, K.; Tacconi, N.R. de [Univ. of Texas, Arlington, TX (United States)

    1996-10-01T23:59:59.000Z

    A new family of metal/semiconductor electrocomposite photoelectrodes is described for photoelectrochemical (PEC) applications. These electrocomposites are prepared from an aqueous dispersion containing the targeted metal (in ionic form) and the semiconductor particles. Electrodeposition of the metal affords a matrix in which the semiconductor particles are occluded. This approach is illustrated for nickel/TiO{sub 2} and nickel/CdS model candidates. The influence of preparation variables (deposition potential, temperature, pH, semiconductor content) on the PEC behavior is described.

  18. Electrodeposition of amorphous ternary nickel-chromium-phosphorus alloy

    DOE Patents [OSTI]

    Guilinger, Terry R. (Albuquerque, NM)

    1990-01-01T23:59:59.000Z

    Amorphous ternary nickel-chromium-phosphorus alloys are electrodeposited from a bath comprising a nickel salt, a chromium salt, a phosphorus source such as sodium hypophosphite, a complexing agent for the nickel ions, supporting salts to increase conductivity, and a buffering agent. The process is carried out at about room temperature and requires a current density between about 20 to 40 A/dm.sup.2.

  19. Positive Active Material For Alkaline Electrolyte Storage Battert Nickel Electrodes

    DOE Patents [OSTI]

    Bernard, Patrick (Massy, FR); Baudry, Michelle (Le Pontaroux, FR)

    2000-12-05T23:59:59.000Z

    A method of manufacturing a positive active material for nickel electrodes of alkaline storage batteries which consists of particles of hydroxide containing mainly nickel and covered with a layer of a hydroxide phase based on nickel and yttrium is disclosed. The proportion of the hydroxide phase is in the range 0.15% to 3% by weight of yttrium expressed as yttrium hydroxide relative to the total weight of particles.

  20. MECHANISTIC STUDIES OF ARYL-OXYGEN BOND ACTIVATION IN A NICKEL(0) DIPHOSPHINE-ETHER COMPLEX

    E-Print Network [OSTI]

    Winfree, Erik

    with nickel precursors was studied. A series of nickel(0) complexes containing nickel-arene interactions.1).1a,1b Quenching of the lithium species with an electrophilic species leads to the functionalization

  1. Nickel-Catalyzed Amination of Aryl Carbamates and Sulfamates Using an Air-Stable Precatalyst

    E-Print Network [OSTI]

    Hie, Liana

    2012-01-01T23:59:59.000Z

    2008, 130, 13848–13849. Nickel-catalyzed amination of arylgained popularity. 14 Using nickel, researchers have usedOF CALIFORNIA Los Angeles Nickel-Catalyzed Amination of Aryl

  2. Hydrogen storage characteristics of nanograined free-standing magnesium–nickel films

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    free-standing magnesium–nickel ?lms Matthew Rogers · StevenFree-standing magnesium–nickel (Mg–Ni) ?lms with extensivefree- standing magnesium–nickel ?lms. Magnesium hydride (MgH

  3. Nickel-Catalyzed Cross-Coupling of Phenol Derivatives and Total Synthesis of Welwitindolinone Natural Products

    E-Print Network [OSTI]

    Quasdorf, Kyle

    2012-01-01T23:59:59.000Z

    Organic Synthesis, 2010. Nickel-Catalyzed Cross-CouplingsMeeting. 2011, FUEL-99. Nickel-catalyzed cross-couplings ofSymposium. 2011 (poster). Nickel-catalyzed cross-couplings

  4. Cobalt and Nickel-Based Organometallic Chemistry of the [N]Phenylenes

    E-Print Network [OSTI]

    Padilla, Robin

    2010-01-01T23:59:59.000Z

    1984, 30, 1. 89) Gu, Z. Nickel-Catalyzed CycloadditionCobalt and Nickel-Based Organometallic Chemistry of the [N]Spring 2010 Cobalt and Nickel-Based Organometallic Chemistry

  5. Effect of Annealing on Hardness and the Modulus of Elasticity in Bulk Nanocrystalline Nickel

    E-Print Network [OSTI]

    Torrents, Anna; Yang, Heather; Mohamed, Farghalli A.

    2010-01-01T23:59:59.000Z

    in Bulk Nanocrystalline Nickel ANNA TORRENTS, HEATHER YANG,Composition of (ED) nc-Nickel P S Cu Co B Ni balance 622—for monocrys- talline nickel at ambient temperature (S 11 =

  6. THE ORIGIN OF UNUSUAL DISLOCATION STRUCTURES OBSERVED IN ION-THINNED NICKEL OXIDE

    E-Print Network [OSTI]

    Little, J.A.

    2013-01-01T23:59:59.000Z

    OBSERVED IN ION-THINNED NICKEL OXIDE J. A. Little, H.OBSERVED IN ION-THINNED NICKEL OXIDE By J. A. Little t , H.thinned single crystals of nickel oxide were examined and

  7. Electrochimica Acta xxx (2005) xxxxxx Electrochemical and AFM study of nickel nucleation mechanisms on

    E-Print Network [OSTI]

    Pesic, Batric

    2005-01-01T23:59:59.000Z

    electrodeposition was carried out from solutions with higher nickel concentrations. The clusters were also larger investigations. © 2005 Elsevier Ltd. All rights reserved. Keywords: Nickel electrodeposition; Ammonia; Nucleation [13,14] for nickel electrodeposition from acidicchloridesolutionscontaininghighnickelconcentration

  8. nouvelle-caldonie, terre de nickel rce au cours lev du nickel, la Nouvelle-Caldonie a travers la dernire crise

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    nouvelle-calédonie, terre de nickel 50 G râce au cours élevé du nickel, la Nouvelle Nouvelle-Calédonie aux besoins planétaires en nickel Bien qu'en termes de tonnage produit (1 400 000 tonnes en 2008) le nickel se situe en queue de peloton des métaux usuels (fer, aluminium, cuivre, manganèse

  9. Nickel Alloy Primary Water Bulk Surface and SCC Corrosion Film Analytical Characterization and SCC Mechanistic Implications

    SciTech Connect (OSTI)

    Morton, D.; Lewis, N.; Hanson, M.; Rice, S.; Sanders, P.

    2007-04-18T23:59:59.000Z

    Alloy 600 corrosion coupon tests were performed: (1) to quantify the temperature dependency of general corrosion and (2) to characterize the composition and structure of bulk surface corrosion films for comparison with ongoing primary water SCC (PWSCC) crack tip corrosion film analyses. Results suggest that the thermal activation energy of Alloy 600 corrosion is consistent with the thermal activation energy of nickel alloy PWSCC. Analytical investigations of the structure and composition of Alloy 600 bulk surface corrosion oxides revealed a duplex (inner and outer) oxide layer structure. The outer layer is discontinuous and comprised of relatively large (1 to 3 {micro}m) nickel ferrite crystals and smaller ({approx}0.1 {micro}m) chromium containing nickel ferrite crystals. The inner layer consists of a relatively continuous chromite spinel (major phase) and chromia (Cr{sub 2}O{sub 3} minor phase) which formed through non-selective oxidation. Chromia and dealloyed Alloy 600 (highly Ni enriched metal) were only observed at 337 C (640 F) and only along the boundaries of deformation induced fine grains and subcells. Specimens having deformation free surfaces exhibited continuous uniform inner chromite spinel oxide layers. Specimens with machining induced surface deformation produced non-uniform inner layer oxides (chromite spinel, Cr{sub 2}O{sub 3} and unoxidized material). PWSCC crack tip oxides, in contrast, were fine grain (no duplex structure) and consisted of both chromium rich spinels and ''NiO'' structure oxides. Generally, nickel rich oxides were more abundant under more oxidized conditions (reduced coolant hydrogen) and spinel rich crack tip oxides were favored under more reducing conditions (increased coolant hydrogen). Bulk surface corrosion film thickness did not correlate with observed SCC growth rates. These results suggest that corrosion is not the rate controlling step of PWSCC but rather that PWSCC and corrosion have a common rate controlling sub process (e.g., cation diffusion, oxygen ingress).

  10. Biosensors Based on Carbon Nanotubes/Nickel Hexacyanoferrate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    were synthesized, characterized, and evaluated for chemical and bio-sensing properties. Nickel hexacyanoferrate particles were electrodeposited on the porous CNT...

  11. alliages base nickel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    XI, Universit de 5 Machining of nickel based superalloys using coated PCBN tooling. Open Access Theses and Dissertations Summary: ??Following a comprehensive literature...

  12. Polarization-Induced Interfacial Reactions between Nickel and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Polarization-Induced Interfacial Reactions between Nickel and Selenium in NiZirconia SOFC Anodes and Comparison with Sulfur Polarization-Induced Interfacial Reactions between...

  13. High Catalytic Rates for Hydrogen Production Using Nickel Electrocatal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Catalytic Rates for Hydrogen Production Using Nickel Electrocatalysts with Seven-Membered Diphosphine Ligands Containing High Catalytic Rates for Hydrogen Production Using...

  14. Response of nickel surface to pulsed fusion plasma radiations

    SciTech Connect (OSTI)

    Niranjan, Ram, E-mail: niranjan@barc.gov.in; Rout, R. K., E-mail: niranjan@barc.gov.in; Srivastava, R., E-mail: niranjan@barc.gov.in; Gupta, Satish C. [Applied Physics Division, Bhabha Atomic Research Centre, Mumbai-400085 (India); Chakravarthy, Y. [Laser and Plasma Technology Division, Bhabha Atomic Research Centre, Mumbai-400085 (India); Patel, N. N. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai-400085 (India); Alex, P. [Materials Processing Division, Bhabha Atomic Research Centre, Mumbai-400085 (India)

    2014-04-24T23:59:59.000Z

    Nickel based alloys are being projected as suitable materials for some components of the next generation fusion reactor because of compatible thermal, electrical and mechanical properties. Pure nickel material is tested here for possibility of similar application purpose. Nickel samples (> 99.5 % purity) are exposed here to plasma radiations produced due to D-D fusion reaction inside an 11.5 kJ plasma focus device. The changes in the physical properties of the nickel surface at microscopic level which in turn change the mechanical properties are analyzed using scanning electron microscope, optical microscope, glancing incident X-ray diffractometer and Vicker's hardness gauge. The results are reported here.

  15. acidic nickel laterite: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vibrational line shapes of hydrogen and deuterium Baer, Roi 255 J Mater Sci (2006) 41:72327239 7232 Squeeze Infiltration Processing of Nickel Coated Carbon Fiber Reinforced...

  16. acid nickel ii: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vibrational line shapes of hydrogen and deuterium Baer, Roi 367 J Mater Sci (2006) 41:72327239 7232 Squeeze Infiltration Processing of Nickel Coated Carbon Fiber Reinforced...

  17. Soft-x-ray hollow fiber optics with inner metal coating

    SciTech Connect (OSTI)

    Matsuura, Yuji; Oyama, Tadaaki; Miyagi, Mitsunobu

    2005-10-10T23:59:59.000Z

    A glass capillary with an inner metal coating is proposed to be used as soft-x-ray fiber optics in medical applications. Based on the results of theoretical calculations, nickel was chosen as the coating material for x rays radiated from a conventional x-ray tube. A nickel-coated capillary was fabricated by electroless deposition, and focusing and collimating effects were observed from measurements of the transmission efficiency of soft x rays. The transmission of a nickel-coated capillary with an inner diameter of 0.53 mm and a length of 300 mm was 10%, which is approximately double that of an uncoated glass capillary.

  18. JOURNAL DE PHYSIQUE Colfoque Cl, supplkrnent au no 4, Tome 38, Auril 1977, page Cl-333 METAL-OXIDES COMPOSITES FOR BaFe,,Ol PERMANENT MAGNETS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    the possibility of producing composites of Ba ferrite with various metals such as cobalt, nickel, iron, copper of a CO deposit with preferential orientation obtained by chemical reduction and electrodeposition. 2. CO

  19. Part IB Metals Course A: Worked Examples (2022)

    E-Print Network [OSTI]

    Cambridge, University of

    2022-01-01T23:59:59.000Z

    and the surface finish is good. A heat­resistant nickel base alloy cast using the lost wax process in which a wax model is surrounded by ceramic, the wax is then burnt off and the metal cast into the ceramic mould

  20. THE PLANT SOIL INTERFACE: NICKEL BIOAVAILABILITY AND THE MECHANISMS OF PLANT HYPERACCUMULATION

    E-Print Network [OSTI]

    Sparks, Donald L.

    THE PLANT SOIL INTERFACE: NICKEL BIOAVAILABILITY AND THE MECHANISMS OF PLANT HYPERACCUMULATION and Learning Company. #12;ii THE PLANT SOIL INTERFACE: NICKEL BIOAVAILABILITY AND THE MECHANISMS OF PLANT

  1. Brief history of the metal accumulation in the intracluster medium

    E-Print Network [OSTI]

    S. Ettori

    2005-07-09T23:59:59.000Z

    We use models of the rates of Type Ia supernovae (SNe Ia) and core-collapse supernovae, built in such a way that both are consistent with recent observational constraints at zaccumulation in the intra-cluster medium. We show that these SN rates, in unit of SN number per comoving volume and rest-frame year, provide on average a total amount of Iron that is marginally consistent with the value measured in galaxy clusters in the redshift range 0-1, and a relative evolution with redshift that is in agreement with the observational constraints up to z~1.2. Moreover, we verify that the predicted metals to Iron ratios reproduce the measurements obtained in nearby clusters through X-ray analysis, implying that (1) about half of the Iron mass and >75 per cent of the Nickel mass observed locally are produced by SN Ia ejecta, (2) the SN Ia contribution to the metal budget decreases steeply with redshift and by z~1 is already less than half of the local amount and (3) a transition in the abundance ratios relative to the Iron is present between redshifts ~0.5 and 1.4, with core-collapse SN products becoming dominant at higher redshifts.

  2. Metalization of lipid vesicles via electroless plating

    SciTech Connect (OSTI)

    Ferrar, W.T.; O'Brien, D.F.; Warshawsky, A.; Voycheck, C.L.

    1988-01-06T23:59:59.000Z

    The encapsulation of metallic particles and metallic oxides within lipid vesicles has recently been of interest for applications such as catalysis, water splitting, and magnetic control of spin coupling. In this communication the authors introduce the concept and practice of the deposition of metal on vesicles by using electroless plating techniques. Coordination of low valent transition metals to organic functional groups on the surface of the bilayer membrane provides a means of binding metal atoms to vesicles. Chemical reduction produced zero valent atoms which serve as sites for further metal deposition by the chemical reduction techniques of electroless plating. Specifically, this procedure involved the binding of a small amount of tetrachloropalladate to the vesicle bilayer, reduction of the palladium(II) to palladium(0), followed by the deposition of much larger amounts of metal from an electroless plating solution. Electroless plating solutions were used for the deposition of palladium, nickel, cobalt, or copper metal onto the catalytic palladium centers. Since the metallic particles were associated with the vesicles, colloids were formed that were stable in water for much longer periods than the control metal particles formed in water alone. If the vesicles were composed in part of unsaturated lipids, with the olefinic groups on the hydrocarbon chains, the initial evidence suggests the transition metal was directed into the bilayer, rather than staying on the surface.

  3. Adsorption of carbonyl sulfide on nickel and tungsten films

    SciTech Connect (OSTI)

    Saleh, J.M.; Nasser, F.A.K.

    1985-07-18T23:59:59.000Z

    The interaction of carbonyl sulfide with evaporated nickel and tungsten films has been investigated in the temperature range 195-450 K using gas pressures ranging from 1 to 13 N m/sup -2/. Rapid but mainly associative chemisorption of COS occurred on both metals at 195 K. Further adsorption of COS on W at temperatures 293-450 K was extremely slow and accompanied by more CO desorption than COS adsorbed. Sulfidation of Ni film by COS occurred at temperatures greater than or equal to 293 K with the liberation of carbon monoxide. The rate of adsorption increased with temperature but was independent of COS pressure. The activation energy (E/sub x/) increased with extent (X) of sulfidation to a limiting value of 97 kJ mol/sup -1/. A linear relationship was obtained from the plot of E/sub x/ against 1/X, suggesting the applicability of Cabrera-Mott theory to the sulfidation of Ni film by COS. 20 references, 2 figures, 1 table.

  4. High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions

    SciTech Connect (OSTI)

    G Zhou; L Barrio; S Agnoli; S Senanayake; J Evans; A Kubacka; M Estrella; J Hanson; A Martinez-Arias; et al.

    2011-12-31T23:59:59.000Z

    The importance of the oxide: Ce{sub 0.8}Ni{sub 0.2}O{sub 2-y} is an excellent catalyst for ethanol steam reforming. Metal-oxide interactions perturb the electronic properties of the small particles of metallic nickel present in the catalyst under the reaction conditions and thus suppress any methanation activity. The nickel embedded in ceria induces the formation of O vacancies, which facilitate cleavage of the OH bonds in ethanol and water.

  5. Thermoelectric transport properties of polycrystalline titanium diselenide co-intercalated with nickel and titanium using spark plasma sintering

    SciTech Connect (OSTI)

    Holgate, T.C. [Department of Energy Storage and Conversion, Technical University of Denmark, Riso Campus, 4000 Roskilde (Denmark); Zhu, S.; Zhou, M. [Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 (United States); Bangarigadu-Sanasy, S.; Kleinke, H. [Department of Chemistry, University of Waterloo, Waterloo, Ontario, N2L 3G1 (Canada); He, J. [Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 (United States); Tritt, T.M., E-mail: ttritt@clemson.edu [Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 (United States)

    2013-01-15T23:59:59.000Z

    Polycrystalline samples of nickel intercalated (0-5%) TiSe{sub 2} were attempted via solid-state reaction in evacuated quartz tubes followed by densification using a spark plasma sintering process. X-ray diffraction data indicated that mixed NiSe{sub 2} and TiSe{sub 2} phases were present after initial synthesis by solid-state reaction, but a pure TiSe{sub 2} phase was present after the spark plasma sintering. While EPMA data reveals the stoichiometry to be near 1:1.8 (Ti:Se) for all samples, comparisons of the measured bulk densities to the theoretical densities suggest that the off stoichiometry is a result of the co-intercalation of both Ni and Ti rather than Se vacancies. Due to the presence of excess Ti (0.085-0.130 per formula) in the van der Waals gap of all the samples, the sensitive electron-hole balance is offset by the additional Ti-3d electrons, leading to an increase in the thermopower (n-type) over pristine, stoichiometric TiSe{sub 2}. The effects of the co-intercalation of both Ni and Ti in TiSe{sub 2} on the structural, thermal, and electrical properties are discussed herein. - Graphical abstract: Co-intercalation of nickel and excess titanium into the van der Waals gap of TiSe{sub 2} via solid state synthesis followed by spark plasma sintering results in a systematic shift in the ratio of hole and electron carrier concentration, which is close to unity for pristine TiSe{sub 2}. This directly affects the electrical transport properties, and as the structural disorder induced by intercalation suppresses the lattice thermal conductivity, co-intercalation is an effective route to enhance the thermoelectric properties of transition metal diselenides. Highlights: Black-Right-Pointing-Pointer Single phase bulk Ni and Ti co-intercalated TiSe{sub 2} samples prepared by spark plasma sintering. Black-Right-Pointing-Pointer Density and X-ray diffraction suggest that the Ni and excess Ti are ordered in the Van der Waals gap. Black-Right-Pointing-Pointer Co-intercalation of Ni and Ti can be used to control electron-hole ratio and structural disorder.

  6. Ceramic-metal composite article and joining method

    DOE Patents [OSTI]

    Kang, Shinhoo (Wayland, MA); Selverian, John H. (Burlington, MA); Kim, Hans J. (Concord, MA); Dunn, Edmund M. (Lexington, MA); Kim, Kyung S. (Barrington, RI)

    1992-01-01T23:59:59.000Z

    A ceramic-metal article including a ceramic rod, a metal rod, and a braze joining the ceramic and metal rods at a braze area of a coaxial bore in the metal rod. The bore gradually decreases in diameter, having an inward seat area sized for close sliding fit about the ceramic, a larger brazing area near the joint end, and a void area intermediate the braze and seat areas. The ceramic is seated without brazing in the bore seat area. The side wall between the brazing area and the metal outer surface is about 0.030-0.080 inch. The braze includes an inner braze layer, an outer braze layer, and an interlayer about 0.030-0.090 inch thick. A shoulder between the brazing and void areas supports the interlayer during bonding while preventing bonding between the void area and the ceramic member, leaving a void space between the void area and the ceramic member. A venting orifice extends generally radially through the metal member from the outer surface to the void space. The braze layers are palladium, platinum, gold, silver, copper, nickel, indium, chromium, molybdenum, niobium, iron, aluminum, or alloys thereof. Preferred is a gold-palladium-nickel brazing alloy. The interlayer is nickel, molybdenum, copper, tantalum, tungsten, niobium, aluminum, cobalt, iron, or an alloy thereof.

  7. Ceramic-metal composite article and joining method

    DOE Patents [OSTI]

    Kang, S.; Selverian, J.H.; Kim, H.J.; Dunn, E.M.; Kim, K.S.

    1992-04-28T23:59:59.000Z

    A ceramic-metal article including a ceramic rod, a metal rod, and a braze joining the ceramic and metal rods at a braze area of a coaxial bore in the metal rod is described. The bore gradually decreases in diameter, having an inward seat area sized for close sliding fit about the ceramic, a larger brazing area near the joint end, and a void area intermediate the braze and seat areas. The ceramic is seated without brazing in the bore seat area. The side wall between the brazing area and the metal outer surface is about 0.030-0.080 inch. The braze includes an inner braze layer, an outer braze layer, and an interlayer about 0.030-0.090 inch thick. A shoulder between the brazing and void areas supports the interlayer during bonding while preventing bonding between the void area and the ceramic member, leaving a void space between the void area and the ceramic member. A venting orifice extends generally radially through the metal member from the outer surface to the void space. The braze layers are palladium, platinum, gold, silver, copper, nickel, indium, chromium, molybdenum, niobium, iron, aluminum, or alloys thereof. Preferred is a gold-palladium-nickel brazing alloy. The interlayer is nickel, molybdenum, copper, tantalum, tungsten, niobium, aluminum, cobalt, iron, or an alloy thereof. 4 figs.

  8. Strained Sistrained Ge dual-channel heterostructures on relaxed Si0.5Ge0.5 for symmetric mobility p-type and n-type metal-oxide-semiconductor

    E-Print Network [OSTI]

    Strained SiÕstrained Ge dual-channel heterostructures on relaxed Si0.5Ge0.5 for symmetric mobility By growing heterostructures that combine a surface strained Si layer with a buried strained Ge layer on Si0.5Ge0.5 , we have fabricated metal-oxide-semiconductor field-effect transistors with mobility

  9. Toxicity of nickel and nickel electroplating water to the freshwater cladoceran Moina macrocopa

    SciTech Connect (OSTI)

    Wong, C.K.; Wong, P.K.; Tao, H. (Chinese Univ. of Hong Kong, Shatin (Hong Kong))

    1991-09-01T23:59:59.000Z

    The present study investigates the effects of Ni{sup 2+} and other components of nickel electroplating water on the survival and reproductive capacity of the cladoceran Moina macrocopa, a common inhabitant of small ponds and rice paddies in Hong Kong and Southern China.

  10. Production of H2 at Fast Rates Using a Nickel Electrocatalyst in Water/Acetonitrile Solutions

    SciTech Connect (OSTI)

    Hoffert, Wesley A.; Roberts, John A.; Bullock, R. Morris; Helm, Monte L.

    2013-09-14T23:59:59.000Z

    Efficient production of molecular hydrogen for storage of energy from renewable sources is crucial for the development of wind and solar power. Hydrogenase enzymes in nature catalyze H2 production using earth-abundant metals (iron and nickel) using precise delivery of protons to the metal center. Here we report a synthetic nickel complex containing proton relays, [Ni(PPh2NC6H4OH2)2](BF4)2 (PPh2NC6H4OH2 = 1,5-bis(p-hydroxyphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane), that catalyzes the production of H2 in an aqueous environment with turnover frequencies of 750-170,000 s-1 at directly measured overpotentials of 310-470 mV. The remarkable performance of this catalyst in aqueous environments exceeds the requirements necessary for molecular catalytic production of H2 by energy derived from photovoltaic solar cells. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  11. Cobalt and nickel supported on HY zeolite: Synthesis, characterization and catalytic properties

    SciTech Connect (OSTI)

    Garrido Pedrosa, Anne M. [Federal University of Rio Grande do Norte, Department of Chemistry, CP 1692, 59078-970 Natal-RN (Brazil)]. E-mail: annemgp@yahoo.com; Souza, Marcelo J.B. [Federal University of Sergipe, Department of Chemical Engineering, 49100-000 Sao Cristovao-SE (Brazil); Melo, Dulce M.A. [Federal University of Rio Grande do Norte, Department of Chemistry, CP 1692, 59078-970 Natal-RN (Brazil); Araujo, Antonio S. [Federal University of Rio Grande do Norte, Department of Chemistry, CP 1692, 59078-970 Natal-RN (Brazil)

    2006-06-15T23:59:59.000Z

    Bifunctional catalysts consisting of cobalt and nickel supported on HY zeolite were synthesized by solvent excess impregnation and characterized by X-ray diffraction, Fourier-transformed infrared spectroscopy, scanning electron microscopy, atomic absorption spectroscopy, thermogravimetric analysis and nitrogen adsorption. The profiles of metal reduction on zeolite were obtained by temperature-programmed reduction. The catalytic properties of the bifunctional catalysts were verified by n-hexane hydroconversion. X-ray diffraction and microstructural analyses showed the presence of crystalline phases in HY zeolite and in samples after impregnation. A decrease in the micropore surface area was observed by nitrogen adsorption experiments and attributed to a reduction in the accessibility to micropores. The catalysts showed catalytic activity in the hydroconversion of n-hexane with selectivity to branched hydrocarbons. Such catalytic activity was related to the acid and metallic properties of the bifunctional catalysts used.

  12. Computational Benchmarking in Biomimetic Nickel, Copper, and Iron Complexes 

    E-Print Network [OSTI]

    Brothers, Scott Michael

    2012-02-14T23:59:59.000Z

    in the absence of experimental data. In this dissertation, such techniques serve to elucidate the observed reactivity or electronic character of both nickel and copper bound in square planar N?S? ligand fields, and of {Fe(NO)?} units, respectively. Nickel...

  13. Thermal conductivity of electroless nickel-phosphorus alloy plating

    SciTech Connect (OSTI)

    Smith, D.D.

    1982-04-01T23:59:59.000Z

    Properties of specific heat, thermal diffusivity, density, and calculated thermal conductivity have been determined for a modified acid bath electroless nickel-12.7 wt% phosphorus alloy between 298 ad 423 K. Thermal conductivity values are about half those of pure nickel.

  14. Original article Differential nickel tolerance of mung bean

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Differential nickel tolerance of mung bean (Vigna radiata L.) genotypes, Orissa, India (Received 2 August 1997; accepted 2 September 1998) Abstract - Eight cultivars of mung bean cultivars of mung bean were ranked with respect to their tolerance to nickel: Dhauli > PDM-116 > LGG-407 > K

  15. Computational Benchmarking in Biomimetic Nickel, Copper, and Iron Complexes

    E-Print Network [OSTI]

    Brothers, Scott Michael

    2012-02-14T23:59:59.000Z

    in the absence of experimental data. In this dissertation, such techniques serve to elucidate the observed reactivity or electronic character of both nickel and copper bound in square planar N?S? ligand fields, and of {Fe(NO)?} units, respectively. Nickel...

  16. Effects of oxygen reduction on nickel deposition from unbuffered aqueous solutions. 2: Characterization of the electrode interface in electrodeposition

    SciTech Connect (OSTI)

    Cui, C.Q.; Lee, J.Y.; Lin, J.; Tan, K.L. [National Univ. of Singapore (Singapore)

    1995-04-01T23:59:59.000Z

    Contrary to the reactive electrodeposition of cobalt, porous nickel is not easily produced by electrodeposition from neutral aqueous solutions in the presence of dissolved oxygen. X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) examination of the electrode surface detected the presence of a highly stable metal hydroxide layer of the same characteristics as precipitated Ni(OH){sub 2}. The hydroxide layer inhibits the nucleation of nickel nuclei and increases the irreversibility in electrodeposition. For reactive deposition to result in a porous deposit, the hydroxide layer should have only moderate stability so that it can be continuously removed and reinstated by interfacial chemical and electrochemical reactions. The surface Ni(OH){sub 2} formed in neutral solutions lacks the reactivity for such dynamism. Nonetheless, the stability of surface Ni(OH){sub 2} could be lowered by increasing the acidity of the deposition medium. Careful pH control seems to be a requirement for nickel reactive electrodeposition to produce porous metal deposits.

  17. High Variability of the Metal Content of Tree Growth Rings as Measured by Synchrotron Micro X-ray Fluorescence Spectrometry

    SciTech Connect (OSTI)

    Martin,R.; Naftel, S.; Macfie, S.; Jones, K.; Feng, H.; Trembley, C.

    2006-01-01T23:59:59.000Z

    Synchrotron radiation analysis was used to investigate the metal content of tree rings collected from paper birch, Betula papyrifera Marsh, on transects downwind from two metal smelters (nickel and copper). Individual trees reflected changes in ring metal content with time, which may be presumed to represent changes in local metal bioavailability. However, between-tree variations were large and no statistically significant differences in metal content as a function of time were found within or between sites. Although concentrations of both total and exchangeable copper and nickel in the soil increased with proximity to the respective smelter, this pattern was reflected only in the nickel content of rings near the nickel smelter; copper content did not vary with distance from either smelter. The sites did differ with respect to lead, manganese and zinc content of the rings, which may be related to pH. In conclusion, the variability between trees at each site suggests that dendroanalysis is a poor method for evaluating metal exposure at a large (site) scale. Tree ring metal content may be used to evaluate the metal uptake by individual trees but metal mobility in the stem makes it difficult to establish a reliable chronology.

  18. Polarized Neutron Reflectometry of Nickel Corrosion Inhibitors

    E-Print Network [OSTI]

    Wood, Mary. H.; Welbourn, Rebecca J. L.; Zarbakhsh, Ali; Gutfreund, Philipp; Clarke, Stuart M.

    2015-06-07T23:59:59.000Z

    and cosurfactant on the protecting corrosion for nickel. Acta. Phys-Chim. Sin. 2000, 16, 899–905. (22) Vezvaie, M.; Noel, J. J.; Tun, Z.; Shoesmith, D. W. Hydrogen absorption into titanium under cathodic polarisation: an in-situ neutron reflometry and EIS study... , 378 (1), 152–158. (42) Wang, X.; Lee, S. Y.; Miller, K.; Stocker, I.; Clarke, S.; Casford, M.; Gutfreund, P.; Skoda, M. W. A. Cation bridging studied by specular neutron reflection. Langmuir 2013, 29, 5520–5527. (43) Aquino, L. I. A. J. A.; Tunega...

  19. Pulsed electrodeposition of iron-nickel alloys

    SciTech Connect (OSTI)

    Grimmett, D.L.; Schwartz, M.; Nobe, K. (Dept. of Chemical Engineering, Univ. of California, Los Angeles, CA (US))

    1990-11-01T23:59:59.000Z

    This paper reports on the effects of dc, pulse, and pulse reverse current waveforms on deposition of Fe-Ni alloys studied in unagitated solutions and with a rotating cylindrical electrode. A nickel sulfamate/ferrous chloride electrolyte system at pH 2 less than 2 A/dm{sup 2}. Pulse reverse plating led to a decrease in anomalous deposition at low current densities. Rotating cylindrical electrodes indicated significant mass transfer effects at high current densities. During pulse reverse plating an increase in anodic pulse magnitude decreased anomalous deposition; pulse frequency had its greatest effect in reducing anomalous deposition between 100 and 300 Hz.

  20. Method for regeneration of electroless nickel plating solution

    DOE Patents [OSTI]

    Eisenmann, Erhard T. (5423 Vista Sandia, NE., Albuquerque, NM 87111)

    1997-01-01T23:59:59.000Z

    An electroless nickel(EN)/hypophosphite plating bath is provided employing acetic acid/acetate as a buffer and which is, as a result, capable of perpetual regeneration while avoiding the production of hazardous waste. A regeneration process is provided to process the spent EN plating bath solution. A concentrated starter and replenishment solution is provided for ease of operation of the plating bath. The regeneration process employs a chelating ion exchange system to remove nickel cations from spent EN plating solution. Phosphites are then removed from the solution by precipitation. The nickel cations are removed from the ion exchange system by elution with hypophosphorous acid and the nickel concentration of the eluate adjusted by addition of nickel salt. The treated solution and adjusted eluate are combined, stabilizer added, and the volume of resulting solution reduced by evaporation to form the bath starter and replenishing solution.

  1. Method for regeneration of electroless nickel plating solution

    DOE Patents [OSTI]

    Eisenmann, E.T.

    1997-03-11T23:59:59.000Z

    An electroless nickel(EN)/hypophosphite plating bath is provided employing acetic acid/acetate as a buffer and which is, as a result, capable of perpetual regeneration while avoiding the production of hazardous waste. A regeneration process is provided to process the spent EN plating bath solution. A concentrated starter and replenishment solution is provided for ease of operation of the plating bath. The regeneration process employs a chelating ion exchange system to remove nickel cations from spent EN plating solution. Phosphites are then removed from the solution by precipitation. The nickel cations are removed from the ion exchange system by elution with hypophosphorus acid and the nickel concentration of the eluate adjusted by addition of nickel salt. The treated solution and adjusted eluate are combined, stabilizer added, and the volume of resulting solution reduced by evaporation to form the bath starter and replenishing solution. 1 fig.

  2. Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries

    SciTech Connect (OSTI)

    Gu, Meng; Belharouak, Ilias; Genc, Arda; Wang, Zhiguo; Wang, Dapeng; Amine, Khalil; Gao, Fei; Zhou, Guangwen; Thevuthasan, Suntharampillai; Baer, Donald R.; Zhang, Jiguang; Browning, Nigel D.; Liu, Jun; Wang, Chong M.

    2012-09-17T23:59:59.000Z

    A variety of approaches are being made to enhance the performance of lithium ion batteries. Incorporating multi-valence transition metal ions into metal oxide cathodes has been identified as an essential approach to achieve the necessary high voltage and high capacity. However, the fundamental mechanism that limits their power rate and cycling stability remains unclear. The power rate strongly depends on the lithium ion drift speed in the cathode. Crystallographically, these transition metal-based cathodes frequently have a layered structure. In the classic wisdom, it is accepted that lithium ion travels swiftly within the layers moving out/in of the cathode during the charge/discharge. Here, we report the unexpected discovery of a thermodynamically driven, yet kinetically controlled, surface modification in the widely explored lithium nickel manganese oxide cathode material, which may inhibit the battery charge/discharge rate. We found that during cathode synthesis and processing before electrochemical cycling in the cell nickel can preferentially move along the fast diffusion channels and selectively segregate at the surface facets terminated with a mix of anions and cations. This segregation essentially blocks the otherwise fast out/in pathways for lithium ions during the charge/discharge. Therefore, it appears that the transition metal dopant may help to provide high capacity and/or high voltage, but can be located in a “wrong” location that blocks or slows lithium diffusion, limiting battery performance. In this circumstance, limitations in the properties of Li-ion batteries using these cathode materials can be determined more by the materials synthesis issues than by the operation within the battery itself.

  3. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya; Shrestha, Roshan P.

    2010-05-11T23:59:59.000Z

    Metal aminoboranes of the formula M(NH2BH3)n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  4. The Interactions and Exchanges of Metal-bound Sulfur Containing Ligands with Various Transition Metals

    E-Print Network [OSTI]

    Foley, William

    2011-02-22T23:59:59.000Z

    ............................................................... 11 3. M(CO) X ADDUCTS OF ZINC (II) AND CADMIUM (II) BIOMIMETIC COMPLEXES ..................................................................................................... 15 Conclusions for Section 3... ....... 26 Figure 4-1 The zinc-platinum adduct (a) and the metal exchange product (b) ... 29 Figure 4-2 Previously studied reactions of zinc and nickel biomimetic pathways 31 Figure 4-3 The ligand cannibalism of Zn-1?-Ac to form the diacetate...

  5. Heavy reflector experiments in the IPEN/MB-01 reactor: Stainless steel, carbon steel and nickel

    SciTech Connect (OSTI)

    Santos, Adimir dos; Andrade e Silva, Graciete Simoes de; Jerez, Rogerio; Liambos Mura, Luis Felipe; Fuga, Rinaldo [Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP Av. Prof. Lineu Prestes 2242 - CEP 05508-000 Sao Paulo, SP (Brazil)

    2013-05-06T23:59:59.000Z

    New experiments devoted to the measurements of physical parameters of a light water core surrounded by a heavy reflector were performed in the IPEN/MB-01 research reactor facility. These experiments comprise three sets of heavy reflector (SS-304, Carbon Steel, and Nickel) in a form of laminates around 3 mm thick. Each set was introduced individually in the west face of the core of the IPEN/MB-01 reactor. The aim here is to provide high quality experimental data for the interpretation and validation of the SS-304 heavy reflector calculation methods. The experiments of Carbon Steel, which is composed mainly of iron, and Nickel were performed to provide a consistent and an interpretative check for the SS-304 reflector experiment. The experimental results comprise critical control bank positions, temperatures and reactivities as a function of the number of the plates. Particularly to the case of Nickel, the experimental data are unique of its kind. The theoretical analysis was performed by MCNP-5 with the nuclear data library ENDF/B-VII.0. It was shown that this nuclear data library has a very good performance up to thirteen plates and overestimates the reactivity for higher number of plates independently of the type of the reflector.

  6. Nickel-free duplex stainless steels

    SciTech Connect (OSTI)

    Wang, J.; Uggowitzer, P.J.; Magdowski, R.; Speidel, M.O. [ETH-Zentrum, Zurich (Switzerland). Inst. of Metallurgy] [ETH-Zentrum, Zurich (Switzerland). Inst. of Metallurgy

    1998-12-04T23:59:59.000Z

    It is well known that nitrogen-alloying in steel produces a variety of exceptional properties such as high strength, high ductility and, eventually, resistance to stress corrosion cracking. High-nitrogen steels (HNS), therefore, have recently been developed to enhance the strength and corrosion resistance of stainless steels. However, due to a low solubility of nitrogen in a liquid steel under atmospheric pressure, the production of such high-nitrogen alloys needs high-pressure facilities that cause an extra cost. A possible route of developing high-nitrogen alloys under atmospheric pressure is to choose a duplex microstructure, where the amount of austenite and ferrite phase is nearly equal. A much lower nitrogen content is needed to maintain a 50% austenite phase compared with the necessary addition of nitrogen to reach a 100% austenitic microstructure. In addition, duplex stainless steels (DSS) with 40--60% ferrite can significantly improve the SCC-resistance. The objective of this work was to develop a new group of nickel-free, high strength and corrosion resistant DSS. Nickel was completely replaced by nitrogen in order to enhance SCC resistance and reduce the alloying element cost. The microstructure, mechanical properties, corrosion resistance and cost analysis of new alloys are investigated in comparison with some commercial stainless steels.

  7. Encapsulation of Nickel Nanoparticles in Carbon Obtained by the Sonochemical Decomposition of

    E-Print Network [OSTI]

    Prozorov, Ruslan

    Encapsulation of Nickel Nanoparticles in Carbon Obtained by the Sonochemical Decomposition of Ni(C8 A new precursor for the sonochemical preparation of amorphous nickel, Ni(cyclooctadiene)2, yielded relatively large (200 nm) amorphous nanoparticles composed of nickel and carbon atoms. Small nickel particles

  8. The stability of aqueous nickel(II) chloride complexes in hydrothermal solutions: Results of UVVisible

    E-Print Network [OSTI]

    The stability of aqueous nickel(II) chloride complexes in hydrothermal solutions: Results of UV of aqueous nickel chloride complexes is important for understanding and quantitatively evaluating nickel for dissolved nickel in perchlorate, triflic acid and sodium chloride solutions at temperatures up to 250 °C

  9. JOIJKUAL I)E I'HYSIQUE Diffusion study of oxygen implanted in nickel oxide

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    JOIJKUAL I)E I'HYSIQUE Diffusion study of oxygen implanted in nickel oxide M. Meyer, S. Barbezat, C coefficients d'autodiffusion de I'oxygene dans l'oxyde de nickel, mesurkes rkemment, par Cchange isotopique implanted in nickel oxide; the experiments are carried out by annealing between 1 300 and 1 500 OC nickel

  10. Toxicity of Nickel to a Soil-Dwelling Springtail, Folsomia metaria (Collembola: Isotomidae)

    E-Print Network [OSTI]

    Hopkin, Steve

    Toxicity of Nickel to a Soil-Dwelling Springtail, Folsomia ¢metaria (Collembola: Isotomidae) Janeck. to nickel via soil caused signi®cant mortality and reduced growth and reproductive output. Nickel may and important organisms in the soil ecosystem, the eect of nickel has not previously been studied

  11. Distribution of copper, nickel, and cadmium in the surface waters of the North Atlantic and North Pacific Ocean

    SciTech Connect (OSTI)

    Boyle, E.A.; Huested, S.S.; Jones, S.P.

    1981-09-20T23:59:59.000Z

    Concentrations of copper, nickel, and cadmium have been determined for about 250 surface water samples. Nonupwelling open-ocean concentrations of these metals are Cu, 0.5-1.4 nmol/kg: Ni, 1-2 nmol/kg; and Cd, less than 10 pmol/kg. In the equatorial Pacific upwelling zone, concentrations of Ni (3 nmol/kg) and Cd (80 pmol/kg) are higher than in the open ocean, but Cu (0.9 nmol/kg) is not significantly enriched. Metal concentrations are higher in cool, nutrient-rich eastern boundary currents: Cu, 1.5 nmol/kg: Ni, 3.5 nmol/kg and Cd, 30-50 pmol/kg. Copper is distinctly higher in the coastal waters of the Gulf of Panama (3--4 nmol/kg) and also higher in the shelf waters north of the Gulf Stream (2.5 nmol/kg): these copper enrichments may be caused by copper remobilized from mildly reducing shelf sediments and maintained by a coastal nutrient trap. In the open ocean, events of high-Cu water (1.5--3.5 nmol/kg) are seen on scales up to 60 km; presumably, these are due to the advection of coastal water into the ocean interior. The lowest copper concentrations in the North Pacific central gyre (0.5 nmol/kg: (Bruland, 1980) are lower than in the Sargasso Sea (1.3 nmol/kg), while for nickel the lowest concentrations are 2 nmol/kg in both the North Pacific and the North Atlantic. Nickel and cadmium, while generally correlated with the nutrients in surface waters, show distinct regional changes in their element-nutrient correlations. The residual concentrations of trace metals in the surface waters of the ocean can be explained if biological discrimination against trace metals relative to phosphorus increases as productivity decreases.

  12. TRANSITION DE MOTT METAL-INSULATOR TRANSITIONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    TRANSITION DE MOTT METAL-INSULATOR TRANSITIONS IN TRANSITION METAL OXIDES by D. B. McWHAN, A. MENTH oxydes de metaux de transition on observe une transition d'isolant a metal puis de metal a isolant de type Mott lorsque l'on augmentelenombre d'electrons d. Danslesysthe(V1-~Cr~)203une transition de Mott

  13. In vivo corrosion, tumor outcome, and microarray gene expression for two types of muscle-implanted tungsten alloys

    SciTech Connect (OSTI)

    Schuster, B.E. [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, B434 Mulberry Road, Aberdeen Proving Ground, MD 21005-5609 (United States)] [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, B434 Mulberry Road, Aberdeen Proving Ground, MD 21005-5609 (United States); Roszell, L.E. [U.S. Army Institute of Public Health, 5158 Blackhawk Road, Aberdeen Proving Ground, MD 21010?5403 (United States)] [U.S. Army Institute of Public Health, 5158 Blackhawk Road, Aberdeen Proving Ground, MD 21010?5403 (United States); Murr, L.E.; Ramirez, D.A. [Department of Metallurgical and Materials Engineering, University of Texas, El Paso, TX 79968 (United States)] [Department of Metallurgical and Materials Engineering, University of Texas, El Paso, TX 79968 (United States); Demaree, J.D. [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, B434 Mulberry Road, Aberdeen Proving Ground, MD 21005-5609 (United States)] [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, B434 Mulberry Road, Aberdeen Proving Ground, MD 21005-5609 (United States); Klotz, B.R. [Dynamic Science Inc., Aberdeen Proving Ground, MD 21005?5609 (United States)] [Dynamic Science Inc., Aberdeen Proving Ground, MD 21005?5609 (United States); Rosencrance, A.B.; Dennis, W.E. [U.S. Army Center for Environmental Health Research, Department of Chemistry, Ft. Detrick, MD 21702?5010 (United States)] [U.S. Army Center for Environmental Health Research, Department of Chemistry, Ft. Detrick, MD 21702?5010 (United States); Bao, W. [SAS Institute, Inc. SAS Campus Drive, Cary, NC 27513 (United States)] [SAS Institute, Inc. SAS Campus Drive, Cary, NC 27513 (United States); Perkins, E.J. [U.S. Army Engineer Research and Development Center, 3909 Hall Ferry Road, Vicksburg MS 39180 (United States)] [U.S. Army Engineer Research and Development Center, 3909 Hall Ferry Road, Vicksburg MS 39180 (United States); Dillman, J.F. [U.S. Army Medical Research Institute of Chemical Defense, 3100 Ricketts Point Road, Aberdeen Proving Ground, MD 21010?5400 (United States)] [U.S. Army Medical Research Institute of Chemical Defense, 3100 Ricketts Point Road, Aberdeen Proving Ground, MD 21010?5400 (United States); Bannon, D.I., E-mail: desmond.bannon@us.army.mil [U.S. Army Institute of Public Health, 5158 Blackhawk Road, Aberdeen Proving Ground, MD 21010?5403 (United States)

    2012-11-15T23:59:59.000Z

    Tungsten alloys are composed of tungsten microparticles embedded in a solid matrix of transition metals such as nickel, cobalt, or iron. To understand the toxicology of these alloys, male F344 rats were intramuscularly implanted with pellets of tungsten/nickel/cobalt, tungsten/nickel/iron, or pure tungsten, with tantalum pellets as a negative control. Between 6 and 12 months, aggressive rhabdomyosarcomas formed around tungsten/nickel/cobalt pellets, while those of tungsten/nickel/iron or pure tungsten did not cause cancers. Electron microscopy showed a progressive corrosion of the matrix phase of tungsten/nickel/cobalt pellets over 6 months, accompanied by high urinary concentrations of nickel and cobalt. In contrast, non-carcinogenic tungsten/nickel/iron pellets were minimally corroded and urinary metals were low; these pellets having developed a surface oxide layer in vivo that may have restricted the mobilization of carcinogenic nickel. Microarray analysis of tumors revealed large changes in gene expression compared with normal muscle, with biological processes involving the cell cycle significantly up?regulated and those involved with muscle development and differentiation significantly down?regulated. Top KEGG pathways disrupted were adherens junction, p53 signaling, and the cell cycle. Chromosomal enrichment analysis of genes showed a highly significant impact at cytoband 7q22 (chromosome 7) which included mouse double minute (MDM2) and cyclin?dependant kinase (CDK4) as well as other genes associated with human sarcomas. In conclusion, the tumorigenic potential of implanted tungsten alloys is related to mobilization of carcinogenic metals nickel and cobalt from corroding pellets, while gene expression changes in the consequent tumors are similar to radiation induced animal sarcomas as well as sporadic human sarcomas. -- Highlights: ? Tungsten/nickel/cobalt, tungsten/nickel/iron, and pure tungsten were studied. ? Male Fischer rats implanted with pellets in gastrocnemius muscle of each hind leg. ? Aggressive rhabdomyosarcomas developed from tungsten/nickel/cobalt pellets only. ? Microarray gene expression analysis was carried out on selected tumors. ? Pellet degradation, urinary metal concentration, and sarcoma were correlated.

  14. Master of Science project in advanced computational material physics Electrical conductivity of the correlated metal LaNiO3

    E-Print Network [OSTI]

    Hellsing, Bo

    Master of Science project in advanced computational material physics Electrical conductivity of the correlated metal LaNiO3 Lanthanum nickelate, LaNiO3, belongs to the class of materials named strongly correlated metals. Several properties of these materials can not be understood based on standard

  15. Process for forming a nickel foil with controlled and predetermined permeability to hydrogen

    DOE Patents [OSTI]

    Engelhaupt, Darell E. (Kansas City, MO)

    1981-09-22T23:59:59.000Z

    The present invention provides a novel process for forming a nickel foil having a controlled and predetermined hydrogen permeability. This process includes the steps of passing a nickel plating bath through a suitable cation exchange resin to provide a purified nickel plating bath free of copper and gold cations, immersing a nickel anode and a suitable cathode in the purified nickel plating bath containing a selected concentration of an organic sulfonic acid such as a napthalene-trisulfonic acid, electrodepositing a nickel layer having the thickness of a foil onto the cathode, and separating the nickel layer from the cathode to provide a nickel foil. The anode is a readily-corrodible nickel anode. The present invention also provides a novel nickel foil having a greater hydrogen permeability than palladium at room temperature.

  16. Figure and finish characterization of high performance metal mirrors

    SciTech Connect (OSTI)

    Takacs, P.Z. [Brookhaven National Lab., Upton, NY (United States); Church, E.L. [Army Armament Research and Development Command, Dover, NJ (United States)

    1991-10-01T23:59:59.000Z

    Most metal mirrors currently used in synchrotron radiation (SR) beam lines to reflect soft x-rays are made of electroless nickel plate on an aluminum substrate. This material combination has allowed optical designers to incorporate exotic cylindrical aspheres into grazing incidence x-ray beam-handling systems by taking advantage of single-point diamond machining techniques. But the promise of high-quality electroless nickel surfaces has generally exceeded the performance. We will examine the evolution of electroless nickel surfaces through a study of the quality of mirrors delivered for use at the National Synchrotron Light Source over the past seven years. We have developed techniques to assess surface quality based on the measurement of surface roughness and figure errors with optical profiling instruments. It is instructive to see how the quality of the surface is related to the complexity of the machine operations required to produce it.

  17. The distribution of potentially toxic heavy metals in the sediments of San Antonio Bay and the northwest Gulf of Mexico

    E-Print Network [OSTI]

    Trefry, John Harold

    1974-01-01T23:59:59.000Z

    total of 123 sediment samples from 48 locations in the northwest Gulf of Mexico, including San Antonio Bay and the Mississippi River Delta, were acid leached and analyzed for iron, manganese, lead, zinc, cadmium, copper, and nickel by atomic... of the river mouths, also showed slightly higher than expected levels of nickel, lead, and cadmium. The proposition that shell dredging operations in the bay remobilize significant quantities of toxic metals and make them available to the biota of the area...

  18. REPORT FOR COMMERCIAL GRADE NICKEL CHARACTERIZATION AND BENCHMARKING

    SciTech Connect (OSTI)

    None

    2012-12-20T23:59:59.000Z

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, has completed the collection, sample analysis, and review of analytical results to benchmark the concentrations of gross alpha-emitting radionuclides, gross beta-emitting radionuclides, and technetium-99 in commercial grade nickel. This report presents methods, change management, observations, and statistical analysis of materials procured from sellers representing nine countries on four continents. The data suggest there is a low probability of detecting alpha- and beta-emitting radionuclides in commercial nickel. Technetium-99 was not detected in any samples, thus suggesting it is not present in commercial nickel.

  19. Underground Corrosion of Activated Metals in an Arid Vadose Zone Environment

    SciTech Connect (OSTI)

    Adler Flitton, Mariana Kay; Mizia, Ronald Eugene; Bishop, Carolyn Wagoner

    2002-04-01T23:59:59.000Z

    The subsurface radioactive disposal site located at the Idaho National Engineering and Environmental Laboratory contains neutron-activated metals from nonfuel nuclear-reactor- core components. A long-term corrosion test is being conducted to obtain site-specific corrosion rates to support efforts to more accurately estimate the transfer of activated elements in an arid vadose zone environment. The tests use nonradioactive metal coupons representing the prominent neutron-activated material buried at the disposal location, namely, Type 304L stainless steel, Type 315L stainless steel, nickel-chromium alloy (UNS NO7718), beryllium, aluminum 6061-T6, and a zirconium alloy, (UNS R60804). In addition, carbon steel (the material presently used in the cask disposal liners and other disposal containers) and a duplex stainless steel (UNS S32550) (the proposed material for the high- integrity disposal containers) are also included in the test program. This paper briefly describes the test program and presents the early corrosion rate results after 1 year and 3 years of underground exposure.

  20. Underground Corrosion of Activated Metals in an Arid Vadose Zone Environment

    SciTech Connect (OSTI)

    Adler Flitton, M.K; Mizia, R.E.; Bishop, C.W.

    2001-10-24T23:59:59.000Z

    The subsurface radioactive disposal site located at the Idaho National Engineering and Environmental Laboratory contains neutron-activated metals from nonfuel nuclear-reactor- core components. A long-term corrosion test is being conducted to obtain site-specific corrosion rates to support efforts to more accurately estimate the transfer of activated elements in an arid vadose zone environment. The tests use nonradioactive metal coupons representing the prominent neutron-activated material buried at the disposal location, namely, Type 304L stainless steel, Type 315L stainless steel, nickel-chromium alloy (UNS NO7718), beryllium, aluminum 6061-T6, and a zirconium alloy, (UNS R60804). In addition, carbon steel (the material presently used in the cask disposal liners and other disposal containers) and a duplex stainless steel (UNS S32550) (the proposed material for the high- integrity disposal containers) are also included in the test program. This paper briefly describes the test program and presents the early corrosion rate results after 1 year and 3 years of underground exposure.

  1. Identification of c-Type Heme-Containing Peptides Using Non-Activated Immobilized Metal Affinity Cchromatography Resin Enrichment and Higher-Energy Collisional Dissociation

    SciTech Connect (OSTI)

    Zhang, Haizhen; Yang, Feng; Qian, Weijun; Brown, Roslyn N.; Wang, Yuexi; Merkley, Eric D.; Park, Jea H.; Monroe, Matthew E.; Purvine, Samuel O.; Moore, Ronald J.; Shi, Liang; Fredrickson, Jim K.; Pasa-Tolic, Ljiljana; Smith, Richard D.; Lipton, Mary S.

    2011-10-01T23:59:59.000Z

    c-type cytochromes play essential roles in many biological activities of both prokaryotic and eukaryotic cells, including electron transfer, enzyme catalysis and induction of apoptosis. We report a novel enrichment strategy for identifying c-type heme-containing peptides that uses non-activated IMAC resin. The strategy demonstrated at least seven-fold enrichment for heme-containing peptides digested from a cytochrome c protein standard, and quantitative linear performance was also assessed for heme-containing peptide enrichment. Heme-containing peptides extracted from the periplasmic fraction of Shewanella oneidensis MR-1 were further identified using higher-energy collisional dissociation tandem mass spectrometry. The results demonstrated the applicability of this enrichment strategy to identify c-type heme-containing peptides from a highly complex biological sample, and at the same time, confirmed the periplasmic localization of heme-containing proteins during suboxic respiration activities of S. oneidensis MR-1.

  2. Rapid substitution of gold for aluminum metallization on integrated circuits

    SciTech Connect (OSTI)

    Krasopoulos, A.V. [Washington State Univ., Pullman, WA (United States). Dept. of Chemical Engineering; Li, J.; Josowicz, M.; Janata, J. [Pacific Northwest National Lab., Richland, WA (United States)

    1997-03-01T23:59:59.000Z

    A rapid procedure for substitution of gold for aluminum metallization on integrated solid-state circuits, such as solid-state chemical multisensor chips, has been developed. The final product consists of original aluminum overlaid with nickel and gold, both deposited by an electroless process. The final metallization is chemically inert and the resistance of the contacts remains ohmic and unchanged from the original value. The substitution can be performed either at the wafer or at the chip level. After the plasma etching, the metallization process takes only 25 min.

  3. Solidification/stabilization of simulated uranium and nickel contaminated sludges 

    E-Print Network [OSTI]

    Ramabhadran, Sanjay

    1996-01-01T23:59:59.000Z

    Research missions in nuclear energy conducted by the U.S. Department of Energy facilities have generated large volumes of mixed wastes with hazardous and radioactive components. Uranium and nickel are the primary contaminants of concern...

  4. Nickel-catalysed reductive aldol cyclisation: scope and mechanistic insight 

    E-Print Network [OSTI]

    Fordyce, Euan Alexander Fraser

    2009-01-01T23:59:59.000Z

    A highly diastereoselective nickel-catalysed reductive aldol cyclisation is described. Using Ni(acac)2 as a precatalyst and diethylzinc as a stoichiometric reductant, various ?,?-unsaturated carbonyl compounds tethered through an amide or ester...

  5. Atomistic computer simulation analysis of nanocrystalline nickel-tungsten alloys

    E-Print Network [OSTI]

    Engwall, Alison Michelle

    2009-01-01T23:59:59.000Z

    Nanocrystalline nickel-tungsten alloys are harder, stronger, more resistant to degradation, and safer to electrodeposit than chromium. Atomistic computer simulations have previously met with success in replicating the ...

  6. Caustic stress corrosion cracking of E-Brite and Carpenter 7-MO stainless steels welded to Nickel 200 and Inconel 600 

    E-Print Network [OSTI]

    Stockman, Steven Miles

    1982-01-01T23:59:59.000Z

    -Brite and Carpenter 7-MO Stainless Steels Welded to Nickel 200 and Znconel 600~ (December 1982) Steven Miles Stockman, B. S ~ , Texas AgM University Chairman of Advisory Committee: Dr, R. B. Griffin Samples of E-Brite stainless steel and Carpenter 7-MO stainless... steel, each welded separatelv to Nickel 200 and Inconel 600, were teated for stress corrosion cracking in caus- tic supplied by Dow Chemical of Freeport, Texas, The V-bend type of specimen was tested in the caustic at room temperature, 60C and 800...

  7. E.-H. HALL. 2014 On the rotational Coefficient in nickel and cobalt ( Coefficients de rotation du nickel et du cobalt); Philosophical Magazine, 5e srie, t. XII.

    E-Print Network [OSTI]

    Boyer, Edmond

    509 E.-H. HALL. 2014 On the « rotational Coefficient in nickel and cobalt » ( Coefficients de rotation du nickel et du cobalt); Philosophical Magazine, 5e série, t. XII. p. 157; 1881. E.-H. HALL. 2014 pour le fer, le nickel, l'argent, l'or, le cobalt, l'aluminium, le magnésium; l'effet est bien moindre

  8. Performance of electroless nickel coated steel in oil field environments

    SciTech Connect (OSTI)

    Duncan, R.N.

    1983-01-01T23:59:59.000Z

    Details of test programs to establish the corrosion and erosion resistance of electroless nickel coating in saline/CO/sub 2//H/sub 2/S petroleum production environments at temperatures up to 180/sup 0/C (350 F) are presented, together with actual experience with their use. Data on heat treatment and deposit composition effects on electroless nickel corrosion in oil field services are given.

  9. Performance of Electroless Nickel coatings in oil field environments

    SciTech Connect (OSTI)

    Duncan, R.N.

    1982-01-01T23:59:59.000Z

    Recent experience has shown functional Electroless Nickel to have outstanding resistance to corrosion and erosion in petroleum production facilities. Details of test programs to establish the performance of this coating in saline/CO/sub 2//H/sub 2/S environments at temperatures up to 180 C (350 F) are reported, together with actual experience with their use. Data also are presented on the effect of heat treatment and of deposit composition on the corrosion of Electroless Nickel in oil field services.

  10. In-situ scanning probe microscopy of electrodeposited nickel.

    SciTech Connect (OSTI)

    Kelly, James J.; Dibble, Dean C.

    2004-10-01T23:59:59.000Z

    The performance characteristics and material properties such as stress, microstructure, and composition of nickel coatings and electroformed components can be controlled over a wide range by the addition of small amounts of surface-active compounds to the electroplating bath. Saccharin is one compound that is widely utilized for its ability to reduce tensile stress and refine grain size in electrodeposited nickel. While the effects of saccharin on nickel electrodeposition have been studied by many authors in the past, there is still uncertainty over saccharin's mechanisms of incorporation, stress reduction, and grain refinement. In-situ scanning probe microscopy (SPM) is a tool that can be used to directly image the nucleation and growth of thin nickel films at nanometer length scales to help elucidate saccharin's role in the development and evolution of grain structure. In this study, in-situ atomic force microscopy (AFM) and scanning tunneling microscopy (STM) techniques are used to investigate the effects of saccharin on the morphological evolution of thin nickel films. By observing mono-atomic height nickel island growth with and without saccharin present we conclude that saccharin has little effect on the nickel surface mobility during deposition at low overpotentials where the growth occurs in a layer-by-layer mode. Saccharin was imaged on Au(l11) terraces as condensed patches without resolved packing structure. AFM measurements of the roughness evolution of nickel films up to 1200 nm thick on polycrystalline gold indicate that saccharin initially increases the roughness and surface skewness of the deposit that at greater thickness becomes smoother than films deposited without saccharin. Faceting of the deposit morphology decreases as saccharin concentration increases even for the thinnest films that have 3-D growth.

  11. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04T23:59:59.000Z

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  12. Method of making metal matrix composites reinforced with ceramic particulates

    DOE Patents [OSTI]

    Cornie, James A. (North Chelmsford, MA); Kattamis, Theodoulos (Watertown, MA); Chambers, Brent V. (Cambridge, MA); Bond, Bruce E. (Bedford, MA); Varela, Raul H. (Canton, MA)

    1989-01-01T23:59:59.000Z

    Composite materials and methods for making such materials are disclosed in which dispersed ceramic particles are at chemical equilibrium with a base metal matrix, thereby permitting such materials to be remelted and subsequently cast or otherwise processed to form net weight parts and other finished (or semi-finished) articles while maintaining the microstructure and mechanical properties (e.g. wear resistance or hardness) of the original composite. The composite materials of the present invention are composed of ceramic particles in a base metal matrix. The ceramics are preferably carbides of titanium, zirconium, tungsten, molybdenum or other refractory metals. The base metal can be iron, nickel, cobalt, chromium or other high temperature metal and alloys thereof. For ferrous matrices, alloys suitable for use as the base metal include cast iron, carbon steels, stainless steels and iron-based superalloys.

  13. Method of making metal matrix composites reinforced with ceramic particulates

    DOE Patents [OSTI]

    Cornie, J.A.; Kattamis, T.; Chambers, B.V.; Bond, B.E.; Varela, R.H.

    1989-08-01T23:59:59.000Z

    Composite materials and methods for making such materials are disclosed in which dispersed ceramic particles are at chemical equilibrium with a base metal matrix, thereby permitting such materials to be remelted and subsequently cast or otherwise processed to form net weight parts and other finished (or semi-finished) articles while maintaining the microstructure and mechanical properties (e.g. wear resistance or hardness) of the original composite. The composite materials of the present invention are composed of ceramic particles in a base metal matrix. The ceramics are preferably carbides of titanium, zirconium, tungsten, molybdenum or other refractory metals. The base metal can be iron, nickel, cobalt, chromium or other high temperature metal and alloys thereof. For ferrous matrices, alloys suitable for use as the base metal include cast iron, carbon steels, stainless steels and iron-based superalloys. 2 figs.

  14. Nickel coated aluminum battery cell tabs

    DOE Patents [OSTI]

    Bucchi, Robert S.; Casoli, Daniel J.; Campbell, Kathleen M.; Nicotina, Joseph

    2014-07-29T23:59:59.000Z

    A battery cell tab is described. The battery cell tab is anodized on one end and has a metal coating on the other end. Battery cells and methods of making battery cell tabs are also described.

  15. Kinetic method for the determination of iridium in copper and copper-nickel alloys and in industrial solutions

    SciTech Connect (OSTI)

    Danilova, F.I.; Fedotova, I.A.; Ustinova, N.V.

    1986-02-01T23:59:59.000Z

    This article discusses the kinetic determination of iridium in copper and copper-nickel alloys, in ores and ore processing products containing down to 10/sup -8/%, and in waste solutions down to 0.01 mg/liter. The procedure for the kinetic determination of iridium based on the oxidation of mercury(I) and cerium(IV) is described. The applications of the schemes presented allows one to widen significantly the range of products to be analyzed, to determine iridium at a concentration of 10/sup -8/% in the presence of copper and noble metals, and to shorten the time required for the analysis.

  16. Transition metal oxide improves overall efficiency and maintains performance with inexpensive metals.

    E-Print Network [OSTI]

    Transition metal oxide improves overall efficiency and maintains performance with inexpensive that inserting a transition metal oxide (TMO) between the lead sulfide (PbS) quantum dot (QD) layer and the metal-Yu Chen; Octavi E. Semonin; Arthur J. Nozik; Randy J. Ellingson; Matthew C. Beard."n-Type Transition Metal

  17. Small molecule binding to electrophilic trigonal pyramidal platinum, palladium, and nickel

    E-Print Network [OSTI]

    Tsay, Charlene

    2013-01-01T23:59:59.000Z

    Chapter 1 A general introduction to the concepts and background of several types of transition metal complexes that motivate and inform the research described herein. These include a-complexes and molecular adducts of ...

  18. Measurement of the Nickel/Nickel Oxide Transition in Ni-Cr-Fe Alloys and Updated Data and Correlations to Quantify the Effect of Aqueous Hydrogen on Primary Water SCC

    SciTech Connect (OSTI)

    Steven A. Attanasio; David S. Morton

    2003-06-16T23:59:59.000Z

    Alloys 600 and X-750 have been shown to exhibit a maximum in primary water stress corrosion cracking (PWSCC) susceptibility, when testing is conducted over a range of aqueous hydrogen (H{sub 2}) levels. Contact electric resistance (CER) and corrosion coupon testing using nickel specimens has shown that the maximum in SCC susceptibility occurs in proximity to the nickel-nickel oxide (Ni/NiO) phase transition. The measured location of the Ni/NiO transition has been shown to vary with temperature, from 25 scc/kg H{sub 2} at 360 C to 4 scc/kg H{sub 2} at 288 C. New CER measurements show that the Ni/NiO transition is located at 2 scc/kg H{sub 2} at 260 C. An updated correlation of the phase transition is provided. The present work also reports CER testing conducted using an Alloy 600 specimen at 316 C. A large change in resistance occurred between 5 and 10 scc/kg H{sub 2}, similar to the results obtained at 316 C using a nickel specimen. This result adds confidence in applying the Ni/NiO transition measurements to Ni-Cr-Fe alloys. The understanding of the importance of the Ni/NiO transition to PWSCC has been used previously to quantify H{sub 2} effects on SCC growth rate (SCCGR). Specifically, the difference in the electrochemical potential (EcP) of the specimen or component from the Ni/NiO transition (i.e., EcP{sub Ni/NiO}-EcP) has been used as a correlating parameter. In the present work, these SCCGR-H{sub 2} correlations, which were based on SCCGR data obtained at relatively high test temperatures (338 and 360 C), are evaluated via SCCGR tests at a reduced temperature (316 C). The 316 C data are in good agreement with the predictions, implying that the SCCGR-H{sub 2} correlations extrapolate well to reduced temperatures. The SCCGR-H{sub 2} correlations have been revised to reflect the updated Ni/NiO phase transition correlation. New data are presented for EN82H weld metal (also known as Alloy 82) at 338 C. Similar to other nickel alloys, SCC of EN82H is a function of the aqueous H{sub 2} level, with the SCCGR exhibiting a maximum near the Ni/NiO transition. For example, the SCCGR at 8 scc/kg H{sub 2} is {approx} 81 x higher than at 60 scc/kg H{sub 2}. The 8 scc/kg H{sub 2} condition is near the Ni/NiO transition (located at {approx} 14 scc/kg H{sub 2} at 338 C), while 60 scc/kg H{sub 2} is well into the nickel metal regime. A hydrogen-SCCGR correlation is provided for EN82H. The data and understanding obtained from the present work show that SCC can be mitigated by adjusting the aqueous H{sub 2} level. For example, SCCGR is typically minimized at relatively high aqueous H{sub 2} levels, that are well into the nickel metal regime (i.e., far from the Ni/NiO transition).

  19. Studies Pertaining to the Diastereoselective Fischer Indolization and Exploration of Aryl Carbamates in Nickel-Catalyzed Reactions

    E-Print Network [OSTI]

    Mesganaw, Tehetena

    2012-01-01T23:59:59.000Z

    Relevant to Chapter Three: Nickel-Catalyzed Amination ofRelevant to Chapter Four: Nickel-Catalyzed Amination of Aryl2010, 66, 4687–4695. Nickel-Catalyzed Amination of Aryl

  20. Two cases with nickel-induced oral mucosal hyperplasia: A rare clinical form of allergic contact stomatitis?

    E-Print Network [OSTI]

    Özkaya, Esen; Babuna, Goncagül

    2011-01-01T23:59:59.000Z

    O, Sayal A. The role of nickel accumulation and epithelialMA, Khakhria ML, Strange S. Nickel allergy associated with aTwo cases with nickel-induced oral mucosal hyperplasia: A

  1. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09T23:59:59.000Z

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  2. Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols

    SciTech Connect (OSTI)

    Weiss, Charles J.; Wiedner, Eric S.; Roberts, John A.; Appel, Aaron M.

    2015-01-01T23:59:59.000Z

    Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells. The research by CJW, ESW, and AMA was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. The research by JASR was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  3. Molecular characterization of vanadyl and nickel non-porphyrin compounds in heavy crude petroleums and residua

    SciTech Connect (OSTI)

    Reynolds, J.G.; Biggs, W.R.; Fetzer, J.C.; Gallegos, E.J.; Fish, R.H.; Komlenic, J.J.; Wines, B.K.

    1984-01-01T23:59:59.000Z

    The molecular characterization of vanadium and nickel compounds in heavy crude petroleums has been the subject of current research. Arabian Heavy, Maya, Boscan, Cerro Negro, Prudhoe Bay, Wilmington Beta, Kern River, and Morichal crude petroleums have been examined. Fractions from D 2007 separations, porphyrin extractions, and solvent selective extraction with reversed phase column separations of these petroleums have been studied thoroughly by EPR. Important structural aspects are emerging from the presented data: (1) There are non-porphyrin metal complexes in the crude petroleums. (2) They appear to be smaller molecules with MW < 400 which are liberated when the tertiary structure of the large asphaltics is denatured. (3) The first coordination spheres of this class of compounds are possibly 4N, N O 2S, and 4S. 10 references, 3 figures, 1 table.

  4. Leaching of metals from ores. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    The bibliography contains citations of selected patents concerning the extraction of metals from ores by leaching. Topics include leaching of metals from ore heaps, mine tailings, smelter wastes, and sea nodules. Metals covered include gold, uranium, copper, nickel, silver, manganese, and cobalt. Bacterio-electric, biological-acid, and hydrogen peroxide leaching are included. (Contains 50-250 citations and includes a subject term index and title list.)

  5. Thin films of mixed metal compounds

    DOE Patents [OSTI]

    Mickelsen, R.A.; Chen, W.S.

    1985-06-11T23:59:59.000Z

    Disclosed is a thin film heterojunction solar cell, said heterojunction comprising a p-type I-III-IV[sub 2] chalcopyrite substrate and an overlying layer of an n-type ternary mixed metal compound wherein said ternary mixed metal compound is applied to said substrate by introducing the vapor of a first metal compound to a vessel containing said substrate from a first vapor source while simultaneously introducing a vapor of a second metal compound from a second vapor source of said vessel, said first and second metals comprising the metal components of said mixed metal compound; independently controlling the vaporization rate of said first and second vapor sources; reducing the mean free path between vapor particles in said vessel, said gas being present in an amount sufficient to induce homogeneity of said vapor mixture; and depositing said mixed metal compound on said substrate in the form of a uniform composition polycrystalline mixed metal compound. 5 figs.

  6. High Temperature Interactions of Antimony with Nickel

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.

    2012-07-01T23:59:59.000Z

    In this chapter, the surface and bulk interactions of antimony with the Ni-based anodes in solid oxide fuel cells (SOFC) will be discussed. High fuel flexibility is a significant advantage of SOFCs, allowing the direct use of fossil and bio fuels without a hydrogen separation unit. Synthesis gas derived from coal and biomass consists of a mixture of hydrogen, carbon monoxide, carbon dioxide, and steam, but finite amounts of tars and trace impurities such as S, Se, P, As, Sb, Cd, Pb, Cl, etc, are also always present. While synthesis gas is commonly treated with a series of chemical processes and scrubbers to remove the impurities, complete purification is not economical. Antimony is widely distributed in coals. During coal gasification antimony is volatilized, such that contact with the SOFC anodes and other SOFC parts, e.g., interconnect, current collecting wires, fuel gas supplying tubing, is most likely. This chapter addresses the following topics: high temperature Ni - Sb interactions; alteration phase, Ni3Sb, Ni5Sb2, NiSb, formation; thermochemical modeling; impact of Sb on the electrocatalytic activity of Ni toward the fuel oxidation and the presence of other impurities (sulfur, in particular); converted anode structural instability during long-term SOFC operation; comparison with nickel heterogeneous catalysts.

  7. Assessing nickel bioavailability in smelter-contaminated soils Jeffrey L. Everhart a,, David McNear Jr. a

    E-Print Network [OSTI]

    Sparks, Donald L.

    Assessing nickel bioavailability in smelter-contaminated soils Jeffrey L. Everhart a,, David Mc: Nickel uptake; Bioavailability; Alyssum murale; Avena sativa; Hyperaccumulators; Phytoremediation 1

  8. Biodegradation of nickel-citrate and modulation of nickel toxicity by iron

    SciTech Connect (OSTI)

    Francis, A.; Joshi-Tope, G.A.; Dodge, C.J. [Brookhaven National Lab., Upton, NY (United States)] [Brookhaven National Lab., Upton, NY (United States)

    1996-02-01T23:59:59.000Z

    Biodegradation of 1:1 nickel:citric acid by Pseudomonas fluorescens proceeded after a lag (nearly 17h) at the rate of 11{+-}1 {mu}mol h{sup -1}, with only partial mineralization of the complex. The incomplete degradation of the complex was not attributed to changes in its structure, but was due to the toxicity of the Ni released. Addition of 1:1 Ni:citric acid inhibited glucose metabolism by the bacterium. The toxicity of the released Ni was evident only when it attained a threshold concentration of > 0.3 mM in the culture medium. Speciation calculations showed that Ni released after metabolism of the complex was present as Ni{sup 2+} ion and nickel carbonate. Addition of iron as a ferric hydroxide or 1:1 Fe:citric acid to 1:1 Ni:citric acid resulted in the complete metabolism of the Ni-citrate complex, with concurrent removal of the released Ni from solution by coprecipitation with iron. 29 refs., 6 figs., 1 tab.

  9. Corrosion-resistant fuel cladding allow for liquid metal fast breeder reactors

    DOE Patents [OSTI]

    Brehm, Jr., William F. (Richland, WA); Colburn, Richard P. (Pasco, WA)

    1982-01-01T23:59:59.000Z

    An aluminide coating for a fuel cladding tube for LMFBRs (liquid metal fast breeder reactors) such as those using liquid sodium as a heat transfer agent. The coating comprises a mixture of nickel-aluminum intermetallic phases and presents good corrosion resistance to liquid sodium at temperatures up to 700.degree. C. while additionally presenting a barrier to outward diffusion of .sup.54 Mn.

  10. Flexible metal film with micro-and nanopatterns transferred by electrochemical deposition

    E-Print Network [OSTI]

    if the film can bend or even can roll up. Generally, the metal film can be produced by electroless deposition film A nickel film ð25 mm � 30 mm � 2 mm� was chosen as master, which was cleaned by acetone, methanol

  11. ThreeDimensional Metallic Microstructures Fabricated by Soft Lithography and Microelectrodeposition

    E-Print Network [OSTI]

    Whitesides, Sue

    will require new approaches not drawn from existing tech­ nologies. Electroforming (electrodeposition structures by repairing any strain­induced defects with electrodeposition of ad­ ditional metal over bubblememorydevices, 11 thin­ film chip carriers, 2 and components for MEMS (nickel turbine rotor, 5 magnetic

  12. Three-Dimensional Metallic Microstructures Fabricated by Soft Lithography and Microelectrodeposition

    E-Print Network [OSTI]

    Prentiss, Mara

    existing tech- nologies. Electroforming (electrodeposition and electromachin- ing) is a technique with electrodeposition of ad- ditional metal over the damaged areas. Most techniques that are used in conjunction (nickel turbine rotor,5 magnetic microactuator,12 microgears, microvalves and pumps,13 capacitive

  13. Formation of amorphous metal alloys by chemical vapor deposition

    DOE Patents [OSTI]

    Mullendore, A.W.

    1988-03-18T23:59:59.000Z

    Amorphous alloys are deposited by a process of thermal dissociation of mixtures of organometallic compounds and metalloid hydrides,e.g., transition metal carbonyl, such as nickel carbonyl and diborane. Various sizes and shapes of deposits can be achieved, including near-net-shape free standing articles, multilayer deposits, and the like. Manipulation or absence of a magnetic field affects the nature and the structure of the deposit. 1 fig.

  14. Formation of amorphous metal alloys by chemical vapor deposition

    DOE Patents [OSTI]

    Mullendore, Arthur W. (Sandia Park, NM)

    1990-01-01T23:59:59.000Z

    Amorphous alloys are deposited by a process of thermal dissociation of mixtures or organometallic compounds and metalloid hydrides, e.g., transition metal carbonyl such as nickel carbonyl, and diborane. Various sizes and shapes of deposits can be achieved, including near-net-shape free standing articles, multilayer deposits, and the like. Manipulation or absence of a magnetic field affects the nature and the structure of the deposit.

  15. A nonchromate method for refurbishment of worn metallic components

    SciTech Connect (OSTI)

    Dearnaley, G.; Badger, P. [Southwest Research Inst., San Antonio, TX (United States); [Wear-Cote International Inc., Rock Island, IL (United States)

    1995-12-31T23:59:59.000Z

    Hard chrome electrodeposition is a widely used method for building up worn metallic components, but regulations concerning hexavalent chromium effluent are making this process less acceptable. A new method is described in which electroless nickel with phosphorus is used in a closed-loop system in order to build up the worn surface, and an amorphous diamond-like carbon (DLC) coating is bonded to this to provide a low-friction bearing surface. The combination is highly resistant to wear and corrosion.

  16. Surface-Induced Nickel Hydroxide Precipitation in the Presence of Citrate and Salicylate

    E-Print Network [OSTI]

    Sparks, Donald L.

    Surface-Induced Nickel Hydroxide Precipitation in the Presence of Citrate and Salicylate Noriko U-lim- iting step for the formation of Ni­Al LDH is Al dissolu- Nickel contamination of soils is a serious

  17. Nickel and cadmium ions inhibit quorum sensing and biofilm formation without affecting viability in Burkholderia multivorans

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Nickel and cadmium ions inhibit quorum sensing and biofilm formation without affecting viability transcriptase polymerase chain reaction (q-PCR) assays, we show that sub-millimolar concentrations of nickel (Ni

  18. Neuroendocrine effects of acute nickel chloride administration in rats

    SciTech Connect (OSTI)

    Clemons, G.K.; Garcia, J.F.

    1981-01-01T23:59:59.000Z

    An sc injection of nickel chloride (20 and 10 mg/kg) led to a profound and consistent increase of circulating prolactin (PRL) levels after 1 day and lasted for 4 days (p < 0.001) in male rats. Increases in insulin levels occurred 1 and 2 days postinjection. The nickel-induced PRL rise could be abolished by a simultaneous administration of 2-bromo-..cap alpha..-ergocryptine (CB 154). In vitro incubation of pituitaries from rats that received 20 mg/kg of nickel chloride 48 hr prior to sacrifice released more PRL into the culture medium, as well as contained more PRL in the final tissue than did the pituitaries from control animals. The hypothalamic extracts (HE) obtained from hypothalami of nickel-injected rats were tested also in vitro on normal rat pituitaries and the results showed that the HE from such rats released more PRL and therefore had less prolactin-inhibiting factor (PIF) than the HE obtained from control rats. The results show that nickel chloride has effects on the endocrine system that (a) last considerably longer than previously reported, (b) are mediated through the neuroendocrine system, and (c) instead of specifically inhibiting PRL secretion from the pituitary promote high circulating PRL levels lasting from 1 to 4 days.

  19. Research, development, and demonstration of nickel-iron batteries for electric vehicle propulsion. Annual report, 1979

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    The program has progressed to the stage of evaluating full-sized (220 Ah) cells, multicell modules, and 22 kWh batteries. Nickel electrodes that display stable capacities of up to 24 Ah/plate (at C/3 drain rate) at design thickness (2.5 mm) in tests at 200/sup +/ test cycles. Iron electrodes of the composite-type are also delivering 24 Ah/plate (at C/3) at target thickness (1.0 mm). Iron plates are displaying capacity stability for 300/sup +/ test cycles in continuing 3 plate cell tests. Best finished cells are delivering 57 to 63 Wh/kg at C/3, based on cell weights of the finished cells, and in the actual designed cell volume. 6-cell module (6-1) performance has demonstrated 239 Ah, 1735 Wh, 53 WH/kg at the C/3 drain rate. This module is now being evaluated at the National Battery Test Laboratory. The 2 x 4 battery has been constructed, tested, and delivered for engineering test and evaluation. The battery delivered 22.5 kWh, as required (199 Ah discharge at 113 V-bar) at the C/3 drain rate. The battery has performed satisfactorily under dynamometer and constant current drain tests. Some cell problems, related to construction, necessitated changing 3 modules, but the battery is now ready for further testing. Reduction in nickel plate swelling (and concurrent stack electrolyte starvation), to improve cycling, is one area of major effort to reach the final battery objectives. Pasted nickel electrodes are showing promise in initial full-size cell tests and will continue to be evaluated in finished cells, along with other technology advancements. 30 figures, 14 tables.

  20. Regenerate metal-plating baths to cut waste and save

    SciTech Connect (OSTI)

    NONE

    1995-03-01T23:59:59.000Z

    During electrode-based metal plating of equipment components, the formation of an electrical field causes metal deposits to be thicker at edges and seams, and thinner on flat surfaces. And, electrode-based methods consume large amounts of energy. Electroless-nickel (EN) -- or autocatalytic -- plating systems were pioneered in the 1940s to solve these problems. EN plating produces a more uniform coating, irrespective of the complexity of the part, and it consumes less electricity, since to electric current is required during plating. Plating in an EN system results from a chemical reaction between nickel in the bath and the substrate of the equipment component. The downside of electroless plating, however, is the limited life of the nickel bath, and the large volume of metal waste produced by bath disposal. Ionsep Corp. (Wilmington, Del.) has developed an electrodialytic system that continuously reforms the EN plating baths, to give them longer life. Its patented system has been successfully laboratory tested in a 1-ft{sup 2} cell, and the firm recently won a $250,000 grant from the US Dept. of Energy (Washington, D.C.) and Environmental Protection Agency (Washington, D.C.), to design and engineer a commercial-scale version of the system.

  1. Chromium modified nickel-iron aluminide useful in sulfur bearing environments

    DOE Patents [OSTI]

    Cathcart, John V. (Knoxville, TN); Liu, Chain T. (Oak Ridge, TN)

    1989-06-13T23:59:59.000Z

    An improved nickel-iron aluminide containing chromium and molybdenum additions to improve resistance to sulfur attack.

  2. Use of the Niyama Criterion To Predict Shrinkage-Related Leaks in High-Nickel

    E-Print Network [OSTI]

    Beckermann, Christoph

    1 Use of the Niyama Criterion To Predict Shrinkage-Related Leaks in High-Nickel Steel and Nickel by the present authors determined that Nymacro = 1.0 (°C-s)1/2 /mm for nickel-based alloys M30C, M35-1 and CW12MW-shrinkage in high-nickel alloys by determining Nymicro. This is accomplished by performing metallographic analyses

  3. Magnetization of an electroless deposited nickel-phosphorus alloy J. Flchon, S. Karbal, F. Machizaud

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1405 Magnetization of an electroless deposited nickel-phosphorus alloy J. Fléchon, S. Karbal, F) du nickel c.f.c. et l'on observe une brusque augmentation de 03C3*o,o et de Tc. Ces résultats sont en cristallin de nickel pur et de phosphure de nickel Ni3P après un recuit à 773 K. Nous avons confirmé l

  4. 25. Steenbock symposium -- Biosynthesis and function of metal clusters for enzymes: Proceedings

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    This symposium was held June 10--14, 1997 in Madison, Wisconsin. The purpose of this conference was to provide a multidisciplinary forum for exchange of state-of-the-art information on biochemistry of enzymes that have an affinity for metal clusters. Attention is focused on the following: metal clusters involved in energy conservation and remediation; tungsten, molybdenum, and cobalt-containing enzymes; Fe proteins, and Mo-binding proteins; nickel enzymes; and nitrogenase.

  5. Spectroscopic investigation of metal-RNA interactions

    E-Print Network [OSTI]

    Vogt, Matthew John

    2005-02-17T23:59:59.000Z

    Metal-RNA interactions are important to neutralize the negative charge and aid in correctly folding the RNA. Spectroscopically active metal ions, especially Mn2+, have been used to probe the type of interaction the metal has with RNA. In previous...

  6. DETERMINATION OF IN-VITRO LUNG SOLUBILITY AND INTAKE-TO-DOSE CONVERSION FACTOR FOR TRITIATED LANTHANUM NICKEL ALUMINUM ALLOY

    SciTech Connect (OSTI)

    Farfan, E.; Labone, T.; Staack, G.; Cheng, Y.; Zhou, Y.; Varallo, T.

    2011-11-11T23:59:59.000Z

    A sample of tritiated lanthanum nickel aluminum alloy (LaNi4.25Al0.75 or LANA.75) similar to that used at the Savannah River Site Tritium Facilities was analyzed to estimate the particle size distribution of this metal tritide powder and the rate, at which this material dissolves in the human respiratory tract after it is inhaled. This information is used to calculate the committed effective dose received by a worker after inhaling the material. These doses, which were calculated using the same methodology given in the DOE Tritium Handbook, are presented as inhalation intake-to-dose conversion factors (DCF). The DCF for this metal tritide is less than the DCF for tritiated water and radiation worker bioassay programs designed for tritiated water are adequate to monitor for intakes of this material.

  7. Solution processed nickel oxide anodes for organic photovoltaic devices

    SciTech Connect (OSTI)

    Mustafa, Bestoon; Griffin, Jonathan; Alsulami, Abdullah S.; Lidzey, David G.; Buckley, Alastair R., E-mail: alastair.buckley@sheffield.ac.uk [Department of Physics and Astronomy, Hicks Building, Hounsfield Road, University of Sheffield, Sheffield S3 7RH (United Kingdom)

    2014-02-10T23:59:59.000Z

    Nickel oxide thin films have been prepared from a nickel acetylacetonate (Ni(acac)) precursor for use in bulk heterojunction organic photovoltaic devices. The conversion of Ni(acac) to NiO{sub x} has been investigated. Oxygen plasma treatment of the NiO layer after annealing at 400?°C affords solar cell efficiencies of 5.2%. Photoelectron spectroscopy shows that high temperature annealing converts the Ni(acac) to a reduced form of nickel oxide. Additional oxygen plasma treatment further oxidizes the surface layers and deepens the NiO work function from 4.7?eV for the annealed film, to 5.0?eV allowing for efficient hole extraction at the organic interface.

  8. Ductile tungsten-nickel alloy and method for making same

    DOE Patents [OSTI]

    Snyder, Jr., William B. (Knoxville, TN)

    1976-01-01T23:59:59.000Z

    The present invention is directed to a ductile, high-density tungsten-nickel alloy which possesses a tensile strength in the range of 100,000 to 140,000 psi and a tensile elongation of 3.1 to 16.5 percent in 1 inch at 25.degree.C. This alloy is prepared by the steps of liquid phase sintering a mixture of tungsten-0.5 to 10.0 weight percent nickel, heat treating the alloy at a temperature above the ordering temperature of approximately 970.degree.C. to stabilize the matrix phase, and thereafter rapidly quenching the alloy in a suitable liquid to maintain the matrix phase in a metastable, face-centered cubic, solid- solution of tungsten in nickel.

  9. Design of a creep resistant nickel base superalloy for power plant applications

    E-Print Network [OSTI]

    Cambridge, University of

    Design of a creep resistant nickel base superalloy for power plant applications Part 2­Phase and used as tools to design a new `made to measure' nickel base superalloy for power plant applications (wt-%) nickel base superalloy has been proposed, for use in future fossil fuel power plant, to operate

  10. Toxicity of nickel to the earthworm and the applicability of the neutral red retention assay

    E-Print Network [OSTI]

    Hopkin, Steve

    Toxicity of nickel to the earthworm and the applicability of the neutral red retention assay JANECK of nickel on survival, growth, and reproduction of Eisenia veneta were investigated following 4 weeks of exposure to a nickel-chloride spiked loamy sand soil. The ability of a simple earthworm biomarker

  11. Determination of Tin in Nickel-based Alloys by Electrothermal Laser-excited

    E-Print Network [OSTI]

    Michel, Robert G.

    Determination of Tin in Nickel-based Alloys by Electrothermal Laser-excited Atomic Fluorescence. The determination of tin in nickel-based alloys by laser-excited sampling, has been the most frequently employed technique for the determination of tin in nickel-based alloys.3­5 The useatomic fluorescence in a graphite

  12. Mechanisms of Nickel on A. M. SCHEIDEGGER*, D. L. SPARKS, Univ. of Delaware, M. FENDORF,

    E-Print Network [OSTI]

    Sparks, Donald L.

    Mechanisms of Nickel on A. M. SCHEIDEGGER*, D. L. SPARKS, Univ. of Delaware, M. FENDORF, Univ. of Berkeley, and G. M. LAMBLE, Brookhaven National Laboratory. Nickel adsorption on the edge swfaces be divided into two pH regions. In the lower pH region (pH nickel adsorption increased

  13. Reversible Cleavage of Carbon-Carbon Bonds in Benzonitrile Using Nickel(0)

    E-Print Network [OSTI]

    Jones, William D.

    Reversible Cleavage of Carbon-Carbon Bonds in Benzonitrile Using Nickel(0) Juventino J. Garcia 3, 2000 Summary: The nickel(0) fragment [(dippe)Ni] has been found to -coordinate to the CN bond efficient and reversible. The nickel dimer [(dippe)NiH]2 has been reported to be capable of cleaving the C

  14. Combined Experimental and Computational Investigation of the Mechanism of Nickel-Catalyzed

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    Combined Experimental and Computational Investigation of the Mechanism of Nickel-Catalyzed Three University, Detroit, Michigan 48202-3489 Received July 14, 2004 The mechanism of nickel-catalyzed couplings of an enone, alkyne, and organozinc has been studied. Adducts of the substrates with nickel(0) have been

  15. Synthesis of Nickel-Zinc Ferrites in RF Thermal Plasma Reactor J. Szpvlgyi1,2*

    E-Print Network [OSTI]

    Gubicza, Jenõ

    Synthesis of Nickel-Zinc Ferrites in RF Thermal Plasma Reactor J. Szépvölgyi1,2* , I. Mohai1 , L POB 32, Budapest, Hungary Abstract Nickel-zinc ferrites usually exhibit high saturation mag. In this paper results of thermal plasma synthesis of nanosized nickel-zinc ferrites from oxide powders

  16. Reliability of Nano-Structured Nickel Interconnections Replacing FlipChip Solder Assembly without Underfill

    E-Print Network [OSTI]

    Swaminathan, Madhavan

    Reliability of Nano-Structured Nickel Interconnections Replacing FlipChip Solder Assembly without nano-structured nickel as the primary interconnection material. Assembly was accomplished materials such as nanostructured copper and nickel, novel bonding and barrier layers to provide both

  17. Querying the Web with Statistical Machine Volker Tresp, Yi Huang, and Maximilian Nickel

    E-Print Network [OSTI]

    Tresp, Volker

    Querying the Web with Statistical Machine Learning Volker Tresp, Yi Huang, and Maximilian Nickel.Tresp@Siemens.com Yi Huang Siemens AG, Otto-Hahn-Ring 6, 81739 Muenchen, e-mail: YiHuang@Siemens.com Maximilian Nickel Ludwig Maximilian University of Munich, e-mail: nickel@dbs.ifi.lmu.de 1 #12;2 Volker Tresp, Yi Huang

  18. Evolution of microstructure and twin density during thermomechanical processing in a -' nickel-based

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Evolution of microstructure and twin density during thermomechanical processing in a -' nickel evolution has been studied in the nickel-based superalloy PER®72 submitted to hot-torsion, to annealing.06.028 #12;2 1. Introduction / Background Nickel-based superalloys have been specifically designed for high

  19. Oceanic nickel depletion and a methanogen famine before the Great Oxidation Event

    E-Print Network [OSTI]

    Konhauser, Kurt

    LETTERS Oceanic nickel depletion and a methanogen famine before the Great Oxidation Event Kurt O a decline in the molar nickel to iron ratio recorded in banded iron formations about 2.7 Gyr ago, which we attribute to a reduced flux of nickel to the oceans, a consequence of cooling upper-mantle temperatures

  20. INFLUENCE OF TEMPERATURE ON NICKEL SORPTION ON CLAY MINERAL AND OXIDE SURFACES. K. G. Scheckel1

    E-Print Network [OSTI]

    Sparks, Donald L.

    INFLUENCE OF TEMPERATURE ON NICKEL SORPTION ON CLAY MINERAL AND OXIDE SURFACES. K. G. Scheckel1- ues are within the range of mineral formation which sup- ports previous findings of nickel precipitation on these mineral and oxide surfaces. Conclusions: Sorption of nickel on the mineral phases results

  1. DOMAIN PATTERNS AND REVERSALS BY WALL MOVEMENTS OF THIN FILMS OF IRON AND NICKEL IRON

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    310 DOMAIN PATTERNS AND REVERSALS BY WALL MOVEMENTS OF THIN FILMS OF IRON AND NICKEL IRON By C. E directions but in the case of the nickel-iron film the reversal of magnetization in the perpendicular domain reversals in nickel-iron films observed by the Kerr effect, and that of Williams and Sherwood [2

  2. Catalytic Carbon-Carbon Bond Activation and Functionalization by Nickel Complexes

    E-Print Network [OSTI]

    Jones, William D.

    Catalytic Carbon-Carbon Bond Activation and Functionalization by Nickel Complexes Brian L. Edelbach, New York 14627 Received May 24, 1999 The nickel alkyne complexes (dippe)Ni(PhCtCPh), 1, (dippe reported using (C5Me5)Rh- (PMe3)H2 5e and several platinum, palladium, and nickel phosphine complexes.5i

  3. Stress dependence of cross slip energy barrier for face-centered cubic nickel

    E-Print Network [OSTI]

    Cai, Wei

    Stress dependence of cross slip energy barrier for face-centered cubic nickel Keonwook Kang a , Jie-centered cubic (FCC) nickel as a function of multiple stress components is predicted by both continuum line the line tension model is compared against an atomistic model for FCC nickel, a good agreement is found

  4. Nickel-Based Superalloy Welding Practices for Industrial Gas Turbine Applications M.B. Henderson

    E-Print Network [OSTI]

    Cambridge, University of

    1 Nickel-Based Superalloy Welding Practices for Industrial Gas Turbine Applications M.B. Henderson capability materials, such as nickel based superalloys. To satisfy the requirements of the component design alloyed materials and reviews a number of welding processes used in the manufacture and repair of nickel

  5. Mechanistic Insights on the Hydrodesulfurization of Biphenyl-2-thiol with Nickel Compounds

    E-Print Network [OSTI]

    Jones, William D.

    Mechanistic Insights on the Hydrodesulfurization of Biphenyl-2-thiol with Nickel Compounds Jorge@servidor.unam.mx Abstract: The reactivity of the nickel(I) dimer [(dippe)Ni(µ-H)]2 (1) with biphenyl-2-thiol was explored evolves to the terminal nickel-hydride [(dippe)Ni (1 -C-2-biphenyl)(H)] (4) and transient [(dippe)NiS] (5

  6. 2918 J. Am. Chem. SOC.1993, 115, 2918-2919 Structure of Nickel Dichloride

    E-Print Network [OSTI]

    Ashworth, Stephen H.

    2918 J. Am. Chem. SOC.1993, 115, 2918-2919 Structure of Nickel Dichloride Stephen H. Ashworth thisclassof molecules is nickel dichloride, whose geometry has been a matter of debate for some time state of NiClz is most probably 3 2 . Nickel(I1) chloridecan besublimed unchanged, isvolatilebelow 1000

  7. A novel "Kabuto-like" nickel catalyst forms bioactive frameworks from low-cost phenol derivatives

    E-Print Network [OSTI]

    Takahashi, Ryo

    1 A novel "Kabuto-like" nickel catalyst forms bioactive developed a new nickel catalyst with a "Kabuto-like" structure that was found to catalyze the cross nickel catalyst to catalyze the cross-coupling reaction between carbonyl compounds and phenol derivatives

  8. OBSERVATION PAR MICROSCOPIE LECTRONIQUE D'AMAS DE LACUNES DANS LE NICKEL TREMP

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    285 OBSERVATION PAR MICROSCOPIE ÉLECTRONIQUE D'AMAS DE LACUNES DANS LE NICKEL TREMPÉ G. LOZES (1 décembre 1970) Résumé. 2014 Des échantillons de nickel de haute pureté ont été étudiés, après trempe, à la, dans le nickel, une forte tendance à l'agglomération, et qu'en dehors des amas visibles, il se forme d

  9. Z. B. He et al., Nickel catalyst shape Etchant-induced shaping of nanoparticle

    E-Print Network [OSTI]

    Boyer, Edmond

    Z. B. He et al., Nickel catalyst shape - 1 - Etchant-induced shaping of nanoparticle catalysts al., Nickel catalyst shape - 2 - Abstract Carbon nanofibres (CNFs) obtained by plasma-00525194,version1-11Oct2010 #12;Z. B. He et al., Nickel catalyst shape - 3 - 1 Introduction Vertically

  10. arXiv draft On the mechanisms of precipitation of graphene on nickel thin

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    arXiv draft On the mechanisms of precipitation of graphene on nickel thin films L. Baraton1 (a) , Z. In the case of nickel, where carbon has a significant solubility, such a growth process includes at least two, we dissolve calibrated amounts of carbon in nickel films, using carbon ion implantation

  11. Immobilized nickel catalysts for cyclotrimerizations of acetylenes: enhancement of activities, stabilities, and lifetimes

    E-Print Network [OSTI]

    Bluemel, Janet

    Immobilized nickel catalysts for cyclotrimerizations of acetylenes: enhancement of activities to optimize the stability and mini- mize leaching of nickel catalysts for alkyne cyclotrimerization supports. They have, for example, been successfully used to immobilize carbonyl nickel3 or rho- dium2

  12. Transient Influx of Nickel in Root Mitochondria Modulates Organic Acid and Reactive Oxygen Species Production in

    E-Print Network [OSTI]

    Sparks, Donald L.

    Transient Influx of Nickel in Root Mitochondria Modulates Organic Acid and Reactive Oxygen Species Production in Nickel Hyperaccumulator Alyssum murale*S Received for publication,August 1, 2012 that nickel is localized in the mitochondria of Alyssum murale root epidermal cells. Conclusion

  13. Catalytic Carbon-Carbon and Carbon-Silicon Bond Activation and Functionalization by Nickel Complexes

    E-Print Network [OSTI]

    Jones, William D.

    Catalytic Carbon-Carbon and Carbon-Silicon Bond Activation and Functionalization by Nickel of Rochester, Rochester, New York 14627 Received June 11, 1999 The nickel alkyne complexes (dippe)Ni(Me3Si, and nickel phosphine complexes.3 Milstein and co-workers reported the cata- lytic hydrogenolysis

  14. Phase Stability of Nickel Hydroxides and Oxyhydroxides A. Van der Ven,a,z

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Phase Stability of Nickel Hydroxides and Oxyhydroxides A. Van der Ven,a,z D. Morgan,b Y. S. Meng of Technology, Cambridge, Massachusetts 02139, USA We investigate phase stability of several nickel hydroxides manuscript received September 12, 2005. Available electronically December 14, 2005. Nickel hydroxide

  15. Feeding of High-Nickel Alloy Castings KENT D. CARLSON, SHOUZHU OU, and CHRISTOPH BECKERMANN

    E-Print Network [OSTI]

    Beckermann, Christoph

    Feeding of High-Nickel Alloy Castings KENT D. CARLSON, SHOUZHU OU, and CHRISTOPH BECKERMANN Feeding of the nickel-based alloys CZ-100, M-35-1, and CW-12MW, as well as of the austenitic stainless steel CN-7M are shown to provide accurate FDs for the casting trial plates. The FDs of the high-nickel alloys (except CZ

  16. Step-modied phase diagram of chemisorbed oxygen on nickel T.P. Pearl 1

    E-Print Network [OSTI]

    Sibener, Steven

    Step-modi®ed phase diagram of chemisorbed oxygen on nickel T.P. Pearl 1 , S.B. Darling, S of chemisorbed oxygen overlayers on a vicinal nickel surface using low energy electron diraction (LEED), Auger by the presence of regular steps. Ó 2001 Elsevier Science B.V. All rights reserved. Keywords: Oxygen; Nickel

  17. Development and Validation of ReaxFF Reactive Force Field for Hydrocarbon Chemistry Catalyzed by Nickel

    E-Print Network [OSTI]

    Goddard III, William A.

    by Nickel Jonathan E. Mueller, Adri C. T. van Duin, and William A. Goddard III*, Materials and Process reactions catalyzed by nickel surfaces and particles using reactive molecular dynamics on thousands of atoms adsorption, decomposition, reformation and desorption of hydrocarbons as they interact with the nickel

  18. Mathematical Modeling and Experimental Investigations of Isothermal Solidification during Transient Liquid Phase Bonding of Nickel

    E-Print Network [OSTI]

    Medraj, Mamoun

    Liquid Phase Bonding of Nickel Superalloys M. A. Arafin1, a , M. Medraj1, b , D. P. Turner2, c and P Liquid Phase Bonding, Nickel Superalloys. Abstract. Mathematical model, based on Fick's second law with nickel based brazing filler alloy BNi-2. Experimental investigations were carried out in the range

  19. NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Hwang, S.

    2010-01-01T23:59:59.000Z

    3, 1976 LBL-5401 l NICKEL-FREE Fe-12Mn-O. 2Ti ALLOY STEELowned rights. I v LBL-540l NICKEL-FREE Fe-12Mn-0.2Ti ALLOY94720 USA ABSTRACT A nickel-free Fe-12Mn-0.2Ti alloy steel

  20. Influence of dimensionality on deep tunneling rates: A study based on the hydrogen-nickel system

    E-Print Network [OSTI]

    Zeiri, Yehuda

    Influence of dimensionality on deep tunneling rates: A study based on the hydrogen-nickel system hydrogen into a surface site of a nickel crystal is used to investigate deep tunneling phenomena. A method of a hydrogen atom in a nickel fcc crystal is studied. The atom is located in a subsurface interstitial site

  1. Nickel Sorption Mechanisms in a PyrophylliteMontmorillonite Mixture Evert J. Elzinga1

    E-Print Network [OSTI]

    Sparks, Donald L.

    Nickel Sorption Mechanisms in a Pyrophyllite­Montmorillonite Mixture Evert J. Elzinga1 and Donald L-mail: elzinga@udel.edu Received October 6, 1998; accepted February 17, 1999 Nickel sorption on pyrophyllite over the mixture components. Nickel uptake on singly reacted pyrophyllite was slightly higher than

  2. INFLUENCE DES DIMENSIONS DE GRAINS SUR L'ANOMALIE DE LA RSISTIVIT DU NICKEL

    E-Print Network [OSTI]

    Boyer, Edmond

    L-223 INFLUENCE DES DIMENSIONS DE GRAINS SUR L'ANOMALIE DE LA RÉSISTIVITÉ DU NICKEL AUTOUR DU POINT. 2014 Les mesures de résistivité effectuées sur du nickel formé de cristaux très petits (15 Å, 25 Å) ont grain-sized nickel (15 Å, 25 Å). The critical exponent 03BD and the constant 03BE0 are computed. Results

  3. Effects of Catalyst Introduction Methods Using PAMAM Dendrimers on Selective Electroless Nickel Deposition on Polyelectrolyte

    E-Print Network [OSTI]

    Lee, Ilsoon

    Effects of Catalyst Introduction Methods Using PAMAM Dendrimers on Selective Electroless Nickel stamping. After patterning, the sample surfaces were placed in an electroless bath where nickel the effects of catalyst introduction methods using poly(amidoamine) (PAMAM) dendrimers on the nickel

  4. Journal of Magnetism and Magnetic Materials 288 (2005) 196204 Micromagnetic studies of nickel microbars fabricated by

    E-Print Network [OSTI]

    Pesic, Batric

    2005-01-01T23:59:59.000Z

    Abstract Micromagnetic configurations and macromagnetic properties of electrodeposited nickel microbars: 75.50.Cc; 75.75.+a; 81.15.Pq Keywords: Electrodeposited nickel; Magnetic microbar; Magnetic vortex (VSM) studies of nickel microbars with round corners, produced by nanoimprinting and electrodeposition

  5. Numerical analysis of a model for Nickel-Iron alloy electrodeposition on rotating disk

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Numerical analysis of a model for Nickel-Iron alloy electrodeposition on rotating disk electrode N the nickel-iron electrodeposition process, we have developed one-dimensional numerical model. This model ad can predict characteristic features of the nickel-iron sys- tem. this work was supported

  6. An Experimental Study of Microfabricated Nickel Spark Plug Georgia Institute of technology

    E-Print Network [OSTI]

    electrodeposition through polymer molds. The nickel spark plugs are tested at 20 Hz using spark energies of 5 mAn Experimental Study of Microfabricated Nickel Spark Plug Georgia Institute of technology Atlanta presents experimental. results of the erosion and wear characteristics of micromachined nickel spark plugs

  7. Molten salt extraction process for the recovery of valued transition metals from land-based and deep-sea minerals

    DOE Patents [OSTI]

    Maroni, Victor A. (Naperville, IL); von Winbush, Samuel (Huntington, NY)

    1988-01-01T23:59:59.000Z

    A process for extracting transition metals and particularly cobalt and manganese together with iron, copper and nickel from low grade ores (including ocean-floor nodules) by converting the metal oxides or other compositions to chlorides in a molten salt, and subsequently using a combination of selective distillation at temperatures below about 500.degree. C., electrolysis at a voltage not more negative than about -1.5 volt versus Ag/AgCl, and precipitation to separate the desired manganese and cobalt salts from other metals and provide cobalt and manganese in metallic forms or compositions from which these metals may be more easily recovered.

  8. Molten salt extraction process for the recovery of valued transition metals from land-based and deep-sea minerals

    DOE Patents [OSTI]

    Maroni, V.A.; von Winbush, S.

    1987-05-01T23:59:59.000Z

    A process for extracting transition metals and particularly cobalt and manganese together with iron, copper and nickel from low grade ores (including ocean-floor nodules) by converting the metal oxides or other compositions to chlorides in a molten salt, and subsequently using a combination of selective distillation at temperatures below about 500/degree/C, electrolysis at a voltage not more negative that about /minus/1.5 volt versus Ag/AgCl, and precipitation to separate the desired manganese and cobalt salts from other metals and provide cobalt and manganese in metallic forms or compositions from which these metals may be more easily recovered.

  9. Nickel aluminide alloy for high temperature structural use

    DOE Patents [OSTI]

    Liu, Chain T. (Oak Ridge, TN); Sikka, Vinod K. (Clinton, TN)

    1991-01-01T23:59:59.000Z

    The specification discloses nickel aluminide alloys including nickel, aluminum, chromium, zirconium and boron wherein the concentration of zirconium is maintained in the range of from about 0.05 to about 0.35 atomic percent to improve the ductility, strength and fabricability of the alloys at 1200.degree. C. Titanium may be added in an amount equal to about 0.2 to about 0.5 atomic percent to improve the mechanical properties of the alloys and the addition of a small amount of carbon further improves hot fabricability.

  10. Electrodeposition of amorphous ternary nickel-chromium-phosphorus alloy

    SciTech Connect (OSTI)

    Guilinger, T.R.

    1990-01-09T23:59:59.000Z

    This patent describes a method of forming amorphous ternary nickel-phosphorus-chromium alloy deposits by electrodeposition on an electrically conductive substrate. It comprises: subjecting the substrate to an applied current density between about 20 and 40 A/dm{sup 2} at a temperature from the range of about 20{degrees} to 30{degrees} C. in a bath comprising: a chromium salt and a nickel salt in a weight ratio of about 3:1, a phosphorus source of about 0.3 M P concentration; about 0.3 M of a complexing agent; about 0.1 M of a supporting salt; and about 0.1 M of buffer.

  11. Electrodeposition of nickel oxyhydroxide films through polymer masks

    SciTech Connect (OSTI)

    Yang, M.C.; Lin, C.K.; Su, C.L. [National Cheng Kung Univ., Tainan (Taiwan, Province of China). Dept. of Chemical Engineering

    1995-04-01T23:59:59.000Z

    Electrochromic materials have attracted much attention for devices including ``smart windows`` and displays. Nickel oxyhydroxide films were electrodeposited through gelatin masks, whose thicknesses may control the optical transmittances of the deposited electrochromic films. The difference of transmittance, {Delta}T{sub 540}, between bleaching and coloration states at wavelength of 540 nm has a linear relationship with the gelatin mask thickness. {Delta}T{sub 540} increased if nickel oxyhydroxide was prepared in agitated electrolyte. The electrodeposited films, prepared with gelatin masks, may have higher stability. These results showed the feasibility of fabricating an electrochromic device with a controlled image whose contrast and brightness are adjustable with potential or current.

  12. Pollution prevention and waste minimization in metal finishing

    SciTech Connect (OSTI)

    Stimetz, C.J.

    1994-12-01T23:59:59.000Z

    This study was done to identify pollution prevention and waste minimization opportunities in the general plating department and the printed circuit board processing department. Recommendations for certain recycle and recovery technologies were mad in order to reduce usage of acids and the volume of heavy metal sludge that is formed at the industrial Wastewater Pretreatment Facility (IWPF). Some of these technologies discussed were acid purification, electrowinning, and ion exchange. Specific technologies are prescribed for specific processes. Those plating processes where the metals can be recovered are copper, nickel, gold, cadmium, tin, lead, and rhodium.

  13. Research, development, and demonstration of nickel-zinc batteries for electric-vehicle propulsion. Annual report for 1980

    SciTech Connect (OSTI)

    Not Available

    1981-03-01T23:59:59.000Z

    Progress in work at Exide in three main development areas, i.e., battery design and development, nickel cathode study, and electrochemical studies is reported. Battery design and development concentrated on the optimization of design parameters, including electrode spacing, charging methods, electrolyte concentration, the design and fabrication of prototype cells and modules, and testing to verify these parameters. Initial experiments indicated that an interelectrode spacing of 2.5 mm was optimum when normal (D.C.) charging is used. It was during these experiments that a high rate charging technique was developed to deposit a dense active zinc which did not shed during vibration. A 4 cell - 300 Ah experimental module was built and sent to NBTL for testing. Initial testing on this module and a 300 Ah cell are reported. Experiments on electrolyte concentration indicate that higher concentrations of KOH (8M, 9M or 10M) are beneficial to capacity maintenance. Available nickel cathodes were evaluated for possible use in the VIBROCEL. These included pocket, sintered plaque impregnated, nickel plated steel wool impregnated, plastic bonded and CMG (multifoil) electrodes. These electrodes have Coulombic densities ranging from 70 Ah/Kg for pocket plates to 190 Ah/Kg for CMG electrodes. Detailed test data are presented for each type including rate capability, effect of zincate on performance, and capacity maintenance with cycling. Work on zinc deposition emphasized the special charging technique. This is a deposition using special waveforms of charging current, to deposit dense crystalline zinc on the anode substrate.

  14. Crack growth rates of nickel alloy welds in a PWR environment.

    SciTech Connect (OSTI)

    Alexandreanu, B.; Chopra, O. K.; Shack, W. J.; Energy Technology

    2006-05-31T23:59:59.000Z

    In light water reactors (LWRs), vessel internal components made of nickel-base alloys are susceptible to environmentally assisted cracking. A better understanding of the causes and mechanisms of this cracking may permit less conservative estimates of damage accumulation and requirements on inspection intervals. A program is being conducted at Argonne National Laboratory to evaluate the resistance of Ni alloys and their welds to environmentally assisted cracking in simulated LWR coolant environments. This report presents crack growth rate (CGR) results for Alloy 182 shielded-metal-arc weld metal in a simulated pressurized water reactor (PWR) environment at 320 C. Crack growth tests were conducted on 1-T compact tension specimens with different weld orientations from both double-J and deep-groove welds. The results indicate little or no environmental enhancement of fatigue CGRs of Alloy 182 weld metal in the PWR environment. The CGRs of Alloy 182 in the PWR environment are a factor of {approx}5 higher than those of Alloy 600 in air under the same loading conditions. The stress corrosion cracking for the Alloy 182 weld is close to the average behavior of Alloy 600 in the PWR environment. The weld orientation was found to have a profound effect on the magnitude of crack growth: cracking was found to propagate faster along the dendrites than across them. The existing CGR data for Ni-alloy weld metals have been compiled and evaluated to establish the effects of key material, loading, and environmental parameters on CGRs in PWR environments. The results from the present study are compared with the existing CGR data for Ni-alloy welds to determine the relative susceptibility of the specific Ni-alloy weld to environmentally enhanced cracking.

  15. Difference in the Reactivities of H-and Me-Substituted Dinucleating Bis(iminopyridine) Ligands with Nickel(0)

    E-Print Network [OSTI]

    Müller, Peter

    with Nickel(0) Amarnath Bheemaraju, Richard L. Lord, Peter Muller, and Stanislav Groysman*, Department

  16. Research, development, and demonstration of nickel-iron batteries for electric vehicle propulsion. Annual report for 1980

    SciTech Connect (OSTI)

    Not Available

    1981-03-01T23:59:59.000Z

    The FY 1980 program continued to involve full-size, prototype cell, module and battery fabrication and evaluation, aimed at advancing the technical capabilities of the nickel-iron battery, while simultaneously reducing its potential cost in materials and process areas. Improved Electroprecipitation Process (EPP) nickel electrodes of design thickness (2.5 mm) are now being prepared that display stable capacities of 23 to 25 Ah for the C/3 drain rate at 200+ test cycles. Iron electrodes of the composite-type are delivering 24 Ah at the target thickness (1.0 mm). Iron electrodes are displaying capacity stability for > 1000 test cycles in continuing 3 plate cell tests. Finished cells have delivered 57 to 61 Wh/kg at C/3, and have demonstrated cyclic stability to 500+ cycles at 80% depth of discharge profiles at Westinghouse. A 6-cell module that demonstrated 239 Ah, 1735 Wh, 48 Wh/kg at the C/3 drain rate has also been evaluated at the National Battery Test Laboratory, ANL. It operated for 327 test cycles, to a level of 161 Ah at the C/3 rate, before being removed from test. Reduction in nickel electrode swelling (and concurrent stack starvation), to improve cycling, continues to be an area of major effort to reach the final battery cycle life objectives. Pasted nickel electrodes continue to show promise for meeting the life objectives while, simultaneously, providing a low manufacturing cost. Refinements have occurred in the areas of cell hardware, module manifolding and cell interconnections. These improvements have been incorporated into the construction and testing of the cells and modules for this program. Temperature tests at 0/sup 0/C were performed on a 6-cell module and showed a decrease in capacity of only 25% in Ah and .29% in Wh as compared to 25/sup 0/C performance. Additional tests are planned to demonstrate performance at -15/sup 0/C and 40/sup 0/C.

  17. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  18. Dynamics, Brandom-Style Bernhard Nickel Harvard University

    E-Print Network [OSTI]

    Nickel, Bernhard

    Dynamics, Brandom-Style Bernhard Nickel · Harvard University June 26, 2011 Abstract This paper understood as a special version of dynamic semantics, so that these semantics by themselves offer and motivations. Keywords static semantics · dynamic semantics · incompatibility se- mantics · brandom · norms

  19. Introduction Nickel Titanium exhibits shape-memory or

    E-Print Network [OSTI]

    Dalang, Robert C.

    Introduction Nickel Titanium exhibits shape-memory or superelastic effect coupled with good of the implant. Figure 1: (a) Shape-memory effect. (b) Superelastic effect Processing and Characterization of NiTi Shape-Memory Alloys with 3D Interconnected Porosity Antoine Emery Supervisors: Prof. A. Mortensen (EPFL

  20. Enantioselective nickel catalysis : exploiting activated C-H bonds

    E-Print Network [OSTI]

    Bencivenga, Nicholas Ernest

    2012-01-01T23:59:59.000Z

    A method for the nickel-catalyzed cross-coupling between benzoxazole and secondary halides was explored. This method was to make use of the activated C-H bond found in benzoxazole at the 2-position to generate the nucleophilic ...

  1. Lead and nickel alter the cardiorenal actions of endothelin in the rat

    SciTech Connect (OSTI)

    Novak, J.; Banks, R.O. [Univ. of Cincinnati College of Medicine, OH (United States)

    1995-02-01T23:59:59.000Z

    In the current study, we have determined to what extent lead and nickel alter the cardiorenal actions of endothelin in pentobarbital anesthetized female rates. One hour following surgery, 3 x 15-min renal clearances were collected and endothelin (ET)-1 was infused iv at 100 ng/kg/min for 30 min during which time an additional two clearances was collected. Lead (infused as lead acetate throughout the experiment) at 4.8 nmoles/min and 24 nmoles/min significantly attenuated the ET-induced increase in mean arterial pressure (MAP); lead infused at 0.48 nmoles/min had no effect. An ET-induced decrease in the glomerular filtration rate (GFR) in control rats was completely blocked by the higher doses of Pb{sup 2+}. By contrast, Pb{sup 2+} had no effect on angiotensin II or norepinephrine induced increases in MAP. In additional experiments, calcium chloride was infused at 500 nmoles/min for 105 min, then Ca{sup 2+} + Pb{sup 2+} (4.8 nmoles/min) were infused for another 105 min; in these experiments, there was no Pb{sup 2+}-induced inhibition of the MAP response to endothelin: the GFR response to the peptide remained blocked. NiCl{sub 2} reduced the ET-induced increase in MAP only at 24 nmoles/min; at 4.8 and 24 nmoles/min, nickel attentuated the decrease in GFR induced by ET. Finally, Ca{sup 2+} infusion had no effect on the inhibition by Ni{sup 2+} of the GFR response to ET. These data illustrate that (i) lead inhibits the cardiorenal actions of endothelin; (ii) a Ca{sup 2+}-related process is involved the systemic but not the renal component of this inhibition; (iii) since the heavy metal does not affect angiotensin II or nonrepinephrine-induced increases in MAP, the inhibition by lead of the systemic response is relatively specific for endothelin; and (iv) nickel also inhibits the renal response to the peptide but higher doses are required to inhibit the systemic response. 35 refs., 4 figs., 2 tabs.

  2. Anomalous X-Ray emission in GRB060904B: a Nickel line?

    E-Print Network [OSTI]

    R. Margutti; A. Moretti; F. Pasotti; S. Campana; G. Chincarini; S. Covino; C. Guidorzi; P. Romano; G. Tagliaferri

    2007-12-10T23:59:59.000Z

    The detection of an extra component in GRB060904B X-ray spectra in addition to the standard single power-law behaviour has recently been reported in the literature. This component can be fit with different models; in particular the addition of a spectral line provides the best representation.In this paper we investigate the physical properties that the surrounding medium must have in order to produce a spectral feature that can explain the detected emission. We analyse and discuss how and if the detected spectral excess fits in different theoretical models developed to explain the nature of line emission during the afterglow phase of Gamma-Ray Bursts (GRBs). Trasmission and reflection models have been considered. Given the high value (>>1) of the Thomson optical depth, the emission is likely to arise in a reflection scenario. Within reflection models, the external reflection geometry fails to predict the observed luminosity. On the contrary, the detected feature can be explained in a funnel scenario with typical opening angle theta of 5 degrees, Nickel mass of the order of 0.1 M_o and T=10^6 K. For theta=20 degrees, assuming the reprocessing material to be the SN shell, the detected emission implies a Nickel mass of 0.4 M_o at T=10^7 K and a metallicity 10 times the solar value. If the giant X-ray flare that dominates the early XRT light curve is identified with the ionizing source, the SN expansion began 3000 s before the GRB event.

  3. Positive electrode current collector for liquid metal cells

    DOE Patents [OSTI]

    Shimotake, Hiroshi (Hinsdale, IL); Bartholme, Louis G. (Joliet, IL)

    1984-01-01T23:59:59.000Z

    A current collector for the positive electrode of an electrochemical cell with a positive electrode including a sulfide. The cell also has a negative electrode and a molten salt electrolyte including halides of a metal selected from the alkali metals and the alkaline earth metals in contact with both the positive and negative electrodes. The current collector has a base metal of copper, silver, gold, aluminum or alloys thereof with a coating thereon of iron, nickel, chromium or alloys thereof. The current collector when subjected to cell voltage forms a sulfur-containing compound on the surface thereby substantially protecting the current collector from further attack by sulfur ions during cell operation. Both electroless and electrolytic processes may be used to deposit coatings.

  4. Positive-electrode current collector for liquid-metal cells

    DOE Patents [OSTI]

    Shimotake, H.; Bartholme, L.G.

    1982-09-27T23:59:59.000Z

    A current collector for the positive electrode of an electrochemical cell with a positive electrode including a sulfide. The cell also has a negative electrode and a molten salt electrolyte including halides of a metal selected from the alkali metals and the alkaline earth metals in contact with both the positive and negative electrodes. The current collector has a base metal of copper, silver, gold, aluminum or alloys thereof with a coating thereon of iron, nickel, chromium or alloys thereof. The current collector when subjected to cell voltage forms a sulfur-containing compound on the surface thereby substantially protecting the current collector from further attack by sulfur ions during cell operation. Both electroless and electrolytic processes may be used to deposit coatings.

  5. Metals 2000

    SciTech Connect (OSTI)

    Allison, S.W.; Rogers, L.C.; Slaughter, G. [Oak Ridge National Lab., TN (United States); Boensch, F.D. [6025 Oak Hill Lane, Centerville, OH (United States); Claus, R.O.; de Vries, M. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States)

    1993-05-01T23:59:59.000Z

    This strategic planning exercise identified and characterized new and emerging advanced metallic technologies in the context of the drastic changes in global politics and decreasing fiscal resources. In consideration of a hierarchy of technology thrusts stated by various Department of Defense (DOD) spokesmen, and the need to find new and creative ways to acquire and organize programs within an evolving Wright Laboratory, five major candidate programs identified are: C-17 Flap, Transport Fuselage, Mach 5 Aircraft, 4.Fighter Structures, and 5. Missile Structures. These results were formed by extensive discussion with selected major contractors and other experts, and a survey of advanced metallic structure materials. Candidate structural applications with detailed metal structure descriptions bracket a wide variety of uses which warrant consideration for the suggested programs. An analysis on implementing smart skins and structures concepts is given from a metal structures perspective.

  6. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

    2010-08-31T23:59:59.000Z

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  7. PLUTONIUM METALLIC FUELS FOR FAST REACTORS

    SciTech Connect (OSTI)

    STAN, MARIUS [Los Alamos National Laboratory; HECKER, SIEGFRIED S. [Los Alamos National Laboratory

    2007-02-07T23:59:59.000Z

    Early interest in metallic plutonium fuels for fast reactors led to much research on plutonium alloy systems including binary solid solutions with the addition of aluminum, gallium, or zirconium and low-melting eutectic alloys with iron and nickel or cobalt. There was also interest in ternaries of these elements with plutonium and cerium. The solid solution and eutectic alloys have most unusual properties, including negative thermal expansion in some solid-solution alloys and the highest viscosity known for liquid metals in the Pu-Fe system. Although metallic fuels have many potential advantages over ceramic fuels, the early attempts were unsuccessful because these fuels suffered from high swelling rates during burn up and high smearing densities. The liquid metal fuels experienced excessive corrosion. Subsequent work on higher-melting U-PuZr metallic fuels was much more promising. In light of the recent rebirth of interest in fast reactors, we review some of the key properties of the early fuels and discuss the challenges presented by the ternary alloys.

  8. Inversion Procedure for Eddy Current Profiling of the Near-Surface Residual Stress in Shot-Peened Metals

    SciTech Connect (OSTI)

    Yu, F.; Nagy, P.B. [Department of Aerospace Engineering and Engineering Mechanics, University of Cincinnati, Cincinnati, Ohio 45221-0070 (United States)

    2005-04-09T23:59:59.000Z

    Because of their frequency-dependent penetration depth, eddy current measurements are capable of mapping the near-surface depth profile of the electrical conductivity. This technique can be used to nondestructively characterize the subsurface residual stress distribution in certain types of shot-peened metals, e.g., in nickel-base superalloys. For quantitative evaluation of the experimental results, analytical and computational techniques are needed to solve the direct and inverse problems, i.e., to predict the frequency-dependent apparent eddy current conductivity from the depth profile of the frequency-independent intrinsic electrical conductivity of the specimen and vice versa. Simple analytical approximations are presented for both the direct and inverse eddy current problems by exploiting two specific features of the electrical conductivity variation caused by near-surface residual stresses in shot-peened metals. First, compressive residual stresses are limited to a shallow surface region of depth much less than typical probe coil diameters. Second, the change in electrical conductivity due to residual stresses is always very small, typically less than 1%. The proposed approximations are verified by numerical comparison to much more complicated numerical solutions.

  9. Iterative Inversion Method for Eddy Current Evaluation of Near-Surface Residual Stress Profile in Surface-Treated Metals

    SciTech Connect (OSTI)

    Abu-Nabah, Bassam A.; Nagy, Peter B. [Department of Aerospace Engineering and Engineering Mechanics, University of Cincinnati, Cincinnati, Ohio 45221-0070 (United States)

    2007-03-21T23:59:59.000Z

    Because of their frequency-dependent penetration depth, eddy current measurements are capable of mapping the near-surface depth profile of the electric conductivity. This technique can be used to nondestructively characterize the subsurface residual stress distribution in certain types of shot-peened metals, e.g., in nickel-base superalloys. To predict the depth-dependent, but frequency-independent, intrinsic electric conductivity from the frequency-dependent apparent eddy current conductivity (AECC), a highly convergent iterative inversion procedure is presented. The proposed technique exploits three specific features of the subsurface electric conductivity variation caused by near-surface residual stresses in shot-peened metals. First, compressive residual stresses are limited to a shallow surface region of depth much less than typical probe coil diameters. Second, the change in electric conductivity due to residual stresses is always very small, typically less than 1%. Third, the electric conductivity profile is fairly smooth and continuous. The accuracy of the proposed iterative inversion procedure is one order of magnitude better than that of the previously developed simpler method (J. Appl. Phys. 96, 1257 2004)

  10. Non-stoichiometric AB5 alloys for metal hydride electrodes

    DOE Patents [OSTI]

    Reilly, James J. (Bellport, NY); Adzic, Gordana D. (Setauket, NY); Johnson, John R. (Calverton, NY); Vogt, Thomas (Cold Spring Harbor, NY); McBreen, James (Bellport, NY)

    2001-01-01T23:59:59.000Z

    The present invention provides a non-stoichiometric alloy comprising a composition having the formula AB.sub.5+X an atomic ratio wherein A is selected from the group consisting of the rare earth metals, yttrium, mischmetal, or a combination thereof; B is nickel and tin, or nickel and tin and at least a third element selected from the group consisting of the elements in group IVA of the periodic table, aluminum, manganese, iron, cobalt, copper, antimony or a combination thereof; X is greater than 0 and less than or equal to about 2.0; and wherein at least one substituted A site is occupied by at least one of the B elements. An electrode incorporating said alloy and an electrochemical cell incorporating said electrode are also described.

  11. Measurement of the Nickel/Nickel Oxide Phase Transition in High Temperature Hydrogenated Water Using the Contact Electric Resistance (CER) Technique

    SciTech Connect (OSTI)

    S.A. Attanasio; D.S. Morton; M.A. Ando; N.F. Panayotou; C.D. Thompson

    2001-05-08T23:59:59.000Z

    Prior studies of Alloy 600 and Alloy X-750 have shown the existence of a maximum in stress corrosion cracking (SCC) susceptibility in high temperature water (e.g., at 360 C), when testing is conducted over a range of dissolved (i.e., aqueous) hydrogen (H{sub 2}) concentrations. It has also been shown that this maximum in SCC susceptibility tends to occur in proximity to the nickel/nickel oxide (Ni/NiO) phase transition, suggesting that oxide phase stability may affect primary water SCC (PWSCC) resistance. Previous studies have estimated the Ni/NiO transition using thermodynamic calculations based on free energies of formation for NiO and H{sub 2}O. The present study reports experimental measurements of the Ni/NiO transition performed using a contact electric resistance (CER) instrument. The CER is capable of measuring the surface resistance of a metal to determine whether it is oxide-covered or oxide-free at a given condition. The transition aqueous hydrogen (H{sub 2}) concentration corresponding to the Ni/NiO equilibrium was measured at 288, 316, 338 and 360 C using high purity Ni specimens. The results showed an appreciable deviation (i.e., 7 to 58 scc H{sub 2}/kg H{sub 2}O) between the measured Ni/NiO transition and the theoretical Ni/NiO transition previously calculated using free energy data from the Journal of Solution Chemistry. The CER-measured position of the Ni/NiO transition is in good agreement with the maxima in PWSCC susceptibility at 338 and 360 C. The measured Ni/NiO transition provides a reasonable basis for estimating the aqueous H{sub 2} level at which the maximum in SCC susceptibility is likely to be observed at temperatures lower than 338 to 360 C, at which SCC tests are time-consuming to perform. Limited SCC data are presented which are consistent with the observation that SCC susceptibility is maximized near the Ni/NiO transition at 288 C.

  12. Mixed ionic and electronic conducting electrode studies for an alkali metal thermal to electric converter

    E-Print Network [OSTI]

    Guo, Yuyan

    2009-05-15T23:59:59.000Z

    This research focuses on preparation, kinetics, and performance studies of mixed ionic and electronic conducting electrodes (MIEE) applied in an alkali metal thermal to electric converter (AMTEC). Two types of MIEE, metal/sodium titanate and metal...

  13. A Synthetic Nickel Electrocatalyst With a Turnover Frequency Above 100,000 s-1 for H2 Production

    SciTech Connect (OSTI)

    Helm, Monte L.; Stewart, Michael P.; Bullock, R. Morris; Rakowski DuBois, Mary; DuBois, Daniel L.

    2011-08-12T23:59:59.000Z

    Increased worldwide energy demand will require greater use of carbon-neutral sustainable energy sources. The intermittent nature of solar and wind power requires storage of energy, so electrocatalysts that convert electrical energy to chemical bonds in fuels are needed. Platinum is an excellent catalyst, but it is of low abundance and high cost. Hydrogenase enzymes in Nature catalyze the evolution of H2 and use earth-abundant metals such as nickel and iron. We report that a synthetic nickel catalyst, [Ni(7PPh2NPh)2](BF4)2, (7PPh2NPh = 1,3,6-triphenyl-1-aza-3,6-diphosphacycloheptane) catalyzes the production of H2 using [(DMF)H]+OTf as the proton source, with turnover frequencies of 31,000 s-1 in dry acetonitrile and 108,000 s-1 in the presence of H2O (1.2 M), at a potential of -1.13 V (vs. the ferrocenium/ferrocene couple). These turnover frequencies exceed those reported for the [FeFe] hydrogenase enzyme by more than an order of magnitude, and are the fastest reported for any molecular catalyst for H2 production. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

  14. Metal-sensing layer-semiconductor and metal-sensing layer-metal heterostructure gas sensors

    SciTech Connect (OSTI)

    O'Leary, M.; Li, Zheng; Fonash, S.J.

    1987-01-01T23:59:59.000Z

    Extremely sensitive gas sensors can be fabricated using heterostructures of the form metal-sensing layer-semiconductor or metal-sensing layer-metal. These structures are heterostructure diodes which have the barrier controlling transport at least partially located in the sensing layer. In the presence of the gas species to be detected, the electrical properties of the sensing layer evolve, resulting in a modification of the barrier to electric current transport and, hence, resulting in detection due to changes in the current-voltage characteristics of the device. This type of sensor structure is demonstrated using the Pd/Ti-O/sub x/Ti heterostructure hydrogen detector.

  15. Level densities of nickel isotopes: microscopic theory versus experiment

    E-Print Network [OSTI]

    M. Bonett-Matiz; Abhishek Mukherjee; Y. Alhassid

    2013-05-01T23:59:59.000Z

    We apply a spin-projection method to calculate microscopically the level densities of a family of nickel isotopes $^{59-64}$Ni using the shell model Monte Carlo approach in the complete $pfg_{9/2}$ shell. Accurate ground-state energies of the odd-mass nickel isotopes, required for the determination of excitation energies, are determined using the Green's function method recently introduced to circumvent the odd particle-number sign problem. Our results are in excellent agreement with recent measurements based on proton evaporation spectra and with level counting data at low excitation energies. We also compare our results with neutron resonance data, assuming equilibration of parity and a spin-cutoff model for the spin distribution at the neutron binding energy, and find good agreement with the exception of $^{63}$Ni.

  16. Deciphering the structure of nano-nickel composites

    SciTech Connect (OSTI)

    Johnson, Oliver K [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    A model has been developed to predict piezoresistivity in Silicone/Nickel Nanostrand composites. This model combines the theory of quantum mechanical tunneling with percolation theory to obtain macroscopic composite resistivity as a function of strain from quantum mechanical principles and statistical characterization of constituent morphology. It has been shown that a model incorporating quantum mechanical tunneling and percolation theory can be used to predict piezoresistivity in Silicone/Nickel Nanostrand composites. The predictions of this model qualitatively demonstrate the large drop in resistivity with strain that these composites exhibit. The quantitative accuracy of the model was shown to be usually within one order of magnitude. Further work must be done to obtain an empirical distribution of inter-nanostrand gap distances, the tunneling barrier height ({lambda}), and the fraction of conductive junctions as a function of strain for these composites.

  17. Method for heat treating iron-nickel-chromium alloy

    DOE Patents [OSTI]

    Merrick, Howard F. (Suffern, NY); Korenko, Michael K. (Rockville, MD)

    1982-01-01T23:59:59.000Z

    A method for heat treating an age-hardenable iron-nickel-chromium alloy to obtain a bimodal distribution of gamma prime phase within a network of dislocations, the alloy consisting essentially of about 25% to 45% nickel, 10% to 16% chromium, 1.5% to 3% of an element selected from the group consisting of molybdenum and niobium, about 2% titanium, about 3% aluminum, and the remainder substantially all iron. To obtain optimum results, the alloy is heated to a temperature of 1025.degree. C. to 1075.degree. C. for 2-5 minutes, cold-worked about 20% to 60%, aged at a temperature of about 775.degree. C. for 8 hours followed by an air-cool, and then heated to a temperature in the range of 650.degree. C. to 700.degree. C. for 2 hours followed by an air-cool.

  18. Electrodeposition of amorphous ternary nickel-chromium-phosphorus alloy

    SciTech Connect (OSTI)

    Guilinger, T.R.

    1990-01-09T23:59:59.000Z

    This patent describes a method of forming amorphous ternary nickel-phosphorus-chromium alloy deposits by electrodeposition on an electrically conductive substrate. It comprises: subjecting the substrate to an applied current density between about 20 and 40 A/dm{sup 2} at a temperature from the range of about 20{degrees} to 30{degrees}C in a bath. The bath comprising: a chromium salt and a nickel salt in a weight ratio of about 3:1, a phosphorus source at about 0.3 MP concentration; about 0.3 M of a complexing agent; about 0.1 M of a supporting salt; and about 1.0 M of buffer.

  19. Improvement in electrochromic stability of electrodeposited nickel hydroxide thin film

    SciTech Connect (OSTI)

    Natarajan, C.; Matsumoto, H.; Nogami, G. [Kyushu Inst. of Tech., Kitakyushu (Japan). Dept. of Electrical Engineering

    1997-01-01T23:59:59.000Z

    The electrochromic nickel hydroxide thin film was anodically deposited from an aqueous solution. The effect of solution temperature, postheat-treatment temperature, and addition of cadmium on the electrochromic behavior (color/bleach durability cycle, response time, and coloration efficiency of the nickel hydroxide films in NaOH) were investigated. A significant increase in the color/bleach durability cycle from 500 (for the as-deposited film) to more than 5000 cycles (for the heat-treated film) was observed. The addition of cadmium increased the utilization of the active materials. It was found that the coloration efficiency was 40 cm{sup 2}/C and coloration and bleaching response time were 20 to 30 s and 8 to 10 s, respectively. The change in the electrochromic properties with heat-treatment temperature is discussed based on the physical and electrochemical analysis.

  20. Process for the electrodeposition of low stress nickel-manganese alloys

    DOE Patents [OSTI]

    Kelly, James John; Goods, Steven Howard; Yang, Nancy Yuan-Chi; Cadden, Charles Henry

    2005-06-07T23:59:59.000Z

    A process for electrodepositing a low stress nickel-manganese multilayer alloy on an electrically conductive substrate is provided. The process includes the steps of immersing the substrate in an electrodeposition solution containing a nickel salt and a manganese salt and repeatedly passing an electric current through an immersed surface of the substrate. The electric current is alternately pulsed for predetermined durations between a first electrical current that is effective to electrodeposit nickel and a second electrical current that is effective to electrodeposit nickel and manganese. A multilayered alloy having adjacent layers of nickel and a nickel-manganese alloy on the immersed surface of the substrate is thereby produced. The resulting multilayered alloy exhibits low internal stress, high strength and ductility, and high strength retention upon exposure to heat.

  1. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), OctoberMay 18-19,DepartmentEnergyMetalMetal

  2. Polymer quenched prealloyed metal powder

    DOE Patents [OSTI]

    Hajaligol, Mohammad R. (Midlothian, VA); Fleischhauer, Grier (Midlothian, VA); German, Randall M. (State College, PA)

    2001-01-01T23:59:59.000Z

    A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3 % Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

  3. Biographyg p y Julia Nickel was a Research Assistant in SEAri and a Master's student

    E-Print Network [OSTI]

    de Weck, Olivier L.

    Biographyg p y Julia Nickel was a Research Assistant in SEAri and a Master's student at MIT from) to the Architecting and Design of julia.nickel@alum.mit.edu (MATE) to the Architecting and Design of Related Publications T t ti S t e ated ub cat o s Nickel, J., Ross, A.M., and Rhodes, D.H., "Cross-domain Comparison

  4. The Surface Morphology Characterization of Electroless Nickel Immersion Gold Under Bump Metallurgy (UBM) Using SEM

    SciTech Connect (OSTI)

    Arshad, M. K. Md; Isa, M. N. Md; Sohiful, Z. M. A. [School of Microelectronic, Kolej Universiti Kejuruteraan Utara Malaysia (KUKUM), Blok A, Kompleks Pusat Pengajian KUKUM, Jalan Kangar-Arau, 02600 Jejawi, Perlis (Malaysia)

    2007-05-09T23:59:59.000Z

    This paper presents the surface morphology characterization at each process step in electroless nickel immersion gold (ENIG) deposition using Scanning Electron Microscope (SEM). The characterization start at initial bond pad, followed by cleaning, activation, first zincation, zinc removal, second zincation, electroless nickel and lastly immersion gold process. The result shows that the surface morphology of initial bond pad starts to change with deposition of zinc layer and further changes with deposition of nickel and gold layer.

  5. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing...

  6. Synthesis and characterization of catalysts containing nickel for reforming methane with carbon dioxide 

    E-Print Network [OSTI]

    Sommer, Michael Edward

    1988-01-01T23:59:59.000Z

    . The compositions were chosen to yield solid solutions so that nickel would precipitate on the atomic scale upon reduction, to produce a highly active catalyst. To allow the solid state reaction to occur at low temperatures, nickel and magnesium hydroxides were... by Gadalla and Bower (1988) and by this study34 9. Thermal analysis of the coprecipitate of nickel and magnesium hydroxides at 5K/min in air 36 10. Thermal analysis of pure magnesium hydroxide at 5K/min in air . 37 11. Thermal analysis of pure nickel...

  7. COORDINATION CHEMISTRY OF METAL SURFACES AND METAL COMPLEXES

    E-Print Network [OSTI]

    Muetterties, E.L.

    2013-01-01T23:59:59.000Z

    probable orientation of acetonitrile molecules bound to atwo isomeric molecules, acetonitrile and methyl isocyanide,of methyl isocyanide to acetonitrile within these nickel

  8. Lead, Uranium, and Nickel Compound Data from the XAFS Library at the Stanford Synchrotron Radiation Laboratory (SSRL)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The x-ray absorption fine structure spectroscopy (XAFS) library at the Stanford Synchrotron Radiation Laboratory is intended to be a reference library of XAFS spectra for various lead, uranium, and nickel compounds. Compounds are organized by central atom and all spectra are transmission data. Molecular Environmental Science (MES) research at SSRL focuses on the fundamental interfacial, molecular- and nano-scale processes that control contaminant and nutrient cycling in the biosphere with the goal of elucidating global elemental cycles and anthropogenic influences on the environment. Key areas of investigation include the: (a) Structural chemistry of water and dissolved solutes, (b) Structural chemistry and reactivity of complex natural environmental materials with respect to heavy metals and metalloids (biominerals, Fe- and Mn-oxides, biofilms, and organic materials), (c) Reactions at environmental interfaces, including sorption, precipitation and dissolution processes that affect the bioavailability of heavy metals and other contaminants, and (d) Microbial transformations of metals and anions. SSRL-based MES research utilizes synchrotron-based x-ray absorption spectroscopy (XAS), x-ray diffraction (XRD), small-angle x-ray scattering (SAXS), x-ray standing wave (XSW) spectroscopy, and photoemission spectroscopy (PES) because of their unique capabilities to probe structure/composition relationships in complex, non-crystalline, and dilute materials. [copied from http://www-ssrl.slac.stanford.edu/mes/index.html

  9. DIRECT DECOMPOSITION OF METHANE TO HYDROGEN ON METAL LOADED ZEOLITE CATALYST

    SciTech Connect (OSTI)

    Lucia M. Petkovic; Daniel M. Ginosar; Kyle C. Burch; Harry W. Rollins

    2005-08-01T23:59:59.000Z

    The manufacture of hydrogen from natural gas is essential for the production of ultra clean transportation fuels. Not only is hydrogen necessary to upgrade low quality crude oils to high-quality, low sulfur ultra clean transportation fuels, hydrogen could eventually replace gasoline and diesel as the ultra clean transportation fuel of the future. Currently, refinery hydrogen is produced through the steam reforming of natural gas. Although efficient, the process is responsible for a significant portion of refinery CO2 emissions. This project is examining the direct catalytic decomposition of methane as an alternative to steam reforming. The energy required to produce one mole of hydrogen is slightly lower and the process does not require water-gas-shift or pressure-swing adsorption units. The decomposition process does not produce CO2 emissions and the product is not contaminated with CO -- a poison for PEM fuel cells. In this work we examined the direct catalytic decomposition of methane over a metal modified zeolite catalyst and the recovery of catalyst activity by calcination. A favorable production of hydrogen was obtained, when compared with previously reported nickel-zeolite supported catalysts. Reaction temperature had a strong influence on catalyst activity and on the type of carbon deposits. The catalyst utilized at 873 and 973 K could be regenerated without any significant loss of activity, however the catalyst utilized at 1073 K showed some loss of activity after regeneration.

  10. Sulfur resistance of Group VIII transition metal promoted nickel catalysts for synthesis gas methanation 

    E-Print Network [OSTI]

    Hamlin, Kellee Hall

    1986-01-01T23:59:59.000Z

    and support. Finally a special thanks to my parents for their love and support throughout. TABLE OF CONTENTS CHAPTER I INTRODUCTION II LITERATURE REVIEW III APPARATUS AND PROCEDURE . Page Feed System Temperature Control and Heating Tubular Reactor...Os . . 44 CHAPTER I INTRODUCTION Methanation has been used for many years to remove traces of CO and COr from hydrogen rich gases such as those used for ammonia synthesis. Recent interest is primarily in the methanation of CO as the final step...

  11. Method Of Charging Maintenance-Free Nickel Metal Hydride Storage Cells

    DOE Patents [OSTI]

    Berlureau, Thierry (Bordeaux, FR); Liska, Jean-Louis (Bordeaux, FR)

    1999-11-16T23:59:59.000Z

    A method of charging an industrial maintenance-free Ni-MH storage cell, the method comprising in combination a first stage at a constant current I.sub.1 lying in the range I.sub.c /10 to I.sub.c /2, and a second stage at a constant current I.sub.2 lying in the range I.sub.c /50 to I.sub.c /10, the changeover from the first stage to the second stage taking place when the time derivative of the temperature reaches a threshold value which varies as a function of the temperature at the time of the changeover.

  12. Decontamination and Conversion of Nickel Radioactive Scrap Metal. Innovative Technology Summary Report

    SciTech Connect (OSTI)

    NONE

    2001-04-01T23:59:59.000Z

    This document contains information on the above-mentioned technology, including description, applicability, cost, and performance data.

  13. Industrial Technologies Program ORNL-developed cast nickel aluminide rolls

    E-Print Network [OSTI]

    strength and oxidation resistance. · · · · Metal Infusion Surface Treatment (MIST) (2006)--a process for infusing up to 51 elements into metal and alloy surfaces, MIST lengthens the life of metalworking technology and the deployment of industrial wireless technologies. #12;Nanomanufacturing Metal Infusion

  14. Nickel-catalyzed asymmetric cross-couplings of secondary allylic chlorides and planar-chiral compounds in asymmetric synthesis

    E-Print Network [OSTI]

    Son, Sunghee

    2008-01-01T23:59:59.000Z

    In Part I, nickel-catalyzed asymmetric carbon-carbon bond-forming reactions are described. A nickel/Pybox system effectively catalyzes regio- and enantioselective cross-couplings between racemic secondary allylic chlorides ...

  15. Nickel-catalyzed reductive coupling reactions of 1,6-enynes and the total synthesis of (+)-acutiphycin

    E-Print Network [OSTI]

    Moslin, Ryan Thomas McLeod

    2007-01-01T23:59:59.000Z

    Nickel-Catalyzed Reductive Coupling Reactions of Aldehydes and Chiral 1,6-Enynes. A study of nickel-catalyzed reductive coupling reactions of aldehydes and chiral 1,6-enynes has provided evidence for stereospecific ligand ...

  16. Reaction Condition Effects on Nickel Sorption Mechanisms in IlliteWater Suspensions E. J. Elzinga* and D. L. Sparks

    E-Print Network [OSTI]

    Sparks, Donald L.

    Reaction Condition Effects on Nickel Sorption Mechanisms in Illite­Water Suspensions E. J. Elzinga by ions other than K, presumably leadingNickel sorption in illite suspensions was studied as a function

  17. Abstract--While there has been a steady progression of research in robotic and mechatronic systems that utilize nickel

    E-Print Network [OSTI]

    Dollar, Aaron M.

    systems that utilize nickel titanium alloy (Nitinol) as an actuator, the design of the antagonistic] and piezoelectric materials [2], nickel titanium alloys (Nitinol) show the largest achievable strain and greatest

  18. Mathematical model of a NiOOH/metal hydride cell. Final report, September 15, 1993--November 14, 1996

    SciTech Connect (OSTI)

    White, R.E.; Popov, B.N.

    1996-12-31T23:59:59.000Z

    One of the objectives of work on the nickel/metal hydride cell has been to develop a mathematical model of the performance of the cell. This is a summary of work to date and is meant to be a Final Report of the BES project. Mathematical model of the nickel/metal hydride cell depends on the kinetics, thermodynamics, and transport properties of the metal hydride electrode. Consequently, investigations were carried out to determine: (1) the exchange current density and the equilibrium potential as a function of hydrogen content in the electrode; (2) the hydrogen diffusion coefficient in the bulk of the alloy; (3) the hydrogen reaction rate order; (4) the symmetry factor for hydrogen evolution reaction and (5) to determine the reaction mechanisms of the hydrogen charge and discharge processes including overcharge and overdischarge mechanism.

  19. Cosmic metal production and the mean metallicity of the Universe

    E-Print Network [OSTI]

    F. Calura; F. Matteucci

    2004-03-08T23:59:59.000Z

    By means of detailed chemo-photometric models for elliptical, spiral and irregular galaxies, we evaluate the cosmic history of the production of chemical elements as well as the metal mass density of the present-day universe. We then calculate the mean metal abundances for galaxies of different morphological types, along with the average metallicity of galactic matter in the universe (stars, gas and intergalactic medium). For the average metallicity of galaxies in the local universe, we find Z_gal= 0.0175, i.e. close to the solar value. We find the main metal production in spheroids (ellipticals and bulges) to occur at very early times, implying an early peak in the metal production and a subsequent decrease. On the other hand, the metal production in spirals and irregulars is always increasing with time. We perform a self-consistent census of the baryons and metals in the local universe finding that, while the vast majority of the baryons lies outside galaxies in the inter-galactic medium (IGM), 52 % of the metals (with the exception of the Fe-peak elements) is locked up in stars and in the interstellar medium. We estimate indirectly the amount of baryons which resides in the IGM and we derive its mean Fe abundance, finding a value of X_Fe,IGM=0.05 X_Fe,sun. We believe that this estimate is uncertain by a factor of 2, owing to the normalization of the local luminosity function. This means that the Fe abundance of 0.3 solar inferred from X-ray observations of the hot intra-cluster medium (ICM) is higher than the average Fe abundance of the inter-galactic gas in the field.

  20. Design of a creep resistant nickel base superalloy for power plant applications

    E-Print Network [OSTI]

    Cambridge, University of

    Design of a creep resistant nickel base superalloy for power plant applications Part 1 ­ Mechanical and used as tools to design a new `made to measure' nickel base superalloy for power plant applications and Mining. Introduction Future fossil fuel power plants are being conceived to operate with steam

  1. Mathematical modeling of lithium-ion and nickel battery systems Parthasarathy M. Gomadama

    E-Print Network [OSTI]

    Mathematical modeling of lithium-ion and nickel battery systems Parthasarathy M. Gomadama , John W of lithium and nickel battery systems developed at the University of South Carolina is presented. Models of Li/Li-ion batteries are reviewed that simulated the behavior of single electrode particles, single

  2. In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design

  3. Phase Transformation Behavior and Mechanical Properties of Thermomechanically Treated K3XF Nickel-Titanium

    E-Print Network [OSTI]

    Zheng, Yufeng

    Phase Transformation Behavior and Mechanical Properties of Thermomechanically Treated K3XF Nickel-Titanium of thermomechanically treated K3XF (SybronEndo, Orange, CA) nickel-titanium instruments in relation to their phase composition was determined by scan- ning electron microscopy with X-ray energy-dispersive spectrometric

  4. Metallurgical Characterization of Controlled Memory Wire Nickel-Titanium Rotary Instruments

    E-Print Network [OSTI]

    Zheng, Yufeng

    Metallurgical Characterization of Controlled Memory Wire Nickel-Titanium Rotary Instruments Ya Shen Haapasalo, DDS, PhD* Abstract Introduction: To improve the fracture resistance of nickel-titanium (Ni- tron microscopy with x-ray energy-dispersive spectro- metric (EDS) analyses. Results: The DSC analyses

  5. Electrochemical characterization of cobalt-encapsulated nickel as cathodes for MCFC

    E-Print Network [OSTI]

    Popov, Branko N.

    Electrochemical characterization of cobalt-encapsulated nickel as cathodes for MCFC Anand an electroless deposition process. The electrochemical oxidation behavior of the Co-coated electrodes is similar when compared to bare nickel oxide electrodes in the presence of cathode gas. The solubility decreased

  6. Structure-Activity Correlations in a Nickel-Borate Oxygen Evolution D. Kwabena Bediako,

    E-Print Network [OSTI]

    Structure-Activity Correlations in a Nickel-Borate Oxygen Evolution Catalyst D. Kwabena Bediako of the electrodeposited films, is accompanied by structure and oxidation state changes. Coulometric measurements correlated with X-ray absorption near- edge structure spectra of the active catalyst show that the nickel

  7. Progress in the development of lightweight nickel electrode for aerospace applications

    SciTech Connect (OSTI)

    Britton, D.L.

    1992-03-01T23:59:59.000Z

    The NASA Lewis Research Center is currently developing nickel electrodes for nickel-hydrogen (Ni-H2) cells and batteries. These electrodes are lighter in weight and have higher specific energy than the heavy sintered state of the art nickel electrodes. In the present approach, lightweight materials or plaques are used as conductive supports for the nickel hydroxide active material. These plaques (fiber, felt, and nickel plated plastic) are fabricated into nickel electrodes by electrochemically impregnating them with active material. Initial performance tests include capacity measurements at five discharge levels, C/2, 1.0C, 1.37C, 2.0C, and 2.74C. The electrodes that pass the initial tests are life cycle tested at 40 and 80 percent depths of discharge (DOD). Different formulations of nickel fiber materials obtained from several manufacturers are currently being tested as possible candidates for nickel electrodes. Over 7,000 cycles of life cycle testing have been accumulated at 40 percent DOD, using the lightweight fiber electrode in a boiler plate Ni-H2 cell with stable voltage.

  8. Cyclic strain hardening of nanocrystalline nickel B. Moser a,b,*, T. Hanlon a,c

    E-Print Network [OSTI]

    Suresh, Subra

    Cyclic strain hardening of nanocrystalline nickel B. Moser a,b,*, T. Hanlon a,c , K.S. Kumar d , S strain hardening and frequency-dependent fatigue life in electrodeposited nanocrystalline Ni subjected. All rights reserved. Keywords: Nanocrystalline materials; Nickel; Low cycle fatigue; Fracture; Cyclic

  9. Deforming nanocrystalline nickel at ultrahigh strain rates Y. M. Wang,a

    E-Print Network [OSTI]

    Meyers, Marc A.

    Deforming nanocrystalline nickel at ultrahigh strain rates Y. M. Wang,a E. M. Bringa, J. M. Mc of this letter is to investigate these deformation mechanisms using a model material, nanocrystalline nickel Goodfellow Inc.; and 2 we also electrodeposited Ni samples at several other grain sizes, 30­100 nm.11

  10. Metallic coatings for enhancement of thermal contact conductance

    SciTech Connect (OSTI)

    Lambert, M.A.; Fletcher, L.S. (Texas A M Univ., College Station, TX (United States))

    1994-04-01T23:59:59.000Z

    The reliability of standard electronic modules may be improved by decreasing overall module temperature. This may be accomplished by enhancing the thermal contact conductance at the interface between the module frame guide rib and the card rail to which the module is clamped. Some metallic coatings, when applied to the card rail, would deform under load, increasing the contact area and associated conductance. This investigation evaluates the enhancements in thermal conductance afforded by vapor deposited silver and gold coatings. Experimental thermal conductance measurements were made for anodized aluminum 6101-T6 and electroless nickel-plated copper C11000-H03 card materials to the aluminum A356-T61 rail material. Conductance values for the electroless nickel-plated copper junction ranged from 600 to 2800 W/m(exp 2)K and those for the anodized aluminum junction ranged from 25 to 91 W/m(exp 2)K for contact pressures of 0.172-0.862 MPa and mean junction temperatures of 20-100 C. Experimental thermal conductance values of vapor deposited silver- and gold-coated aluminum A356-T61 rail surfaces indicate thermal enhancements of 1.25-2.19 for the electroless nickel-plated copper junctions and 1.79-3.41 for the anodized aluminum junctions. The silver and gold coatings provide significant thermal enhancement; however, these coating-substrate combinations are susceptible to galvanic corrosion under some conditions. 25 refs.

  11. Platinum-barium-type L zeolite

    SciTech Connect (OSTI)

    Buss, W.C.; Hughes, T.R.

    1987-01-06T23:59:59.000Z

    A method is described of reforming hydrocarbons comprising contacting the hydrocarbons with a catalyst comprising: (a) a type L zeolite; (b) at least one Group VIII metal; and (c) an alkaline earth metal selected from the group consisting of barium, strontium and calcium. A method is described of dehydrocyclizing acyclic hydrocarbons comprising contacting the hydrocarbons with a catalyst comprising: (a) a type L zeolite (b) at least one Group VIII metal; and (c) an alkaline earth metal selected from the group consisting of barium, strontium and calcium.

  12. Method of preparing silicon carbide particles dispersed in an electrolytic bath for composite electroplating of metals

    DOE Patents [OSTI]

    Peng, Yu-Min (Hsinchu, TW); Wang, Jih-Wen (Hsinchu, TW); Liue, Chun-Ying (Tau-Yung, TW); Yeh, Shinn-Horng (Kaohsiung, TW)

    1994-01-01T23:59:59.000Z

    A method for preparing silicon carbide particles dispersed in an electrolytic bath for composite electroplating of metals includes the steps of washing the silicon carbide particles with an organic solvent; washing the silicon carbide particles with an inorganic acid; grinding the silicon carbide particles; and heating the silicon carbide particles in a nickel-containing solution at a boiling temperature for a predetermined period of time.

  13. Application of ultrasound in solvent extraction of nickel and gallium

    SciTech Connect (OSTI)

    Pesic, B.

    1996-07-01T23:59:59.000Z

    The effects of ultrasound on the rate of solvent extraction of nickel with Lix 65N and Lix 70, and gallium with Kelex 100 were investigated. These solvent extraction systems are noted by their sluggish nature. Low frequency (20 kHz) ultrasound increased the rates of extraction of nickel by factors of four to seven. The ultrasound had no effect on the final chemical equilibrium. Gallium extraction rates were enhanced with the use of ultrasound by as much as a factor of 15. Again, the ultrasound had no effect on extraction equilibrium. For both nickel and gallium, the enhanced rates were attributed to increased interfacial surface area associated with ultrasonically induced cavitation and microdroplet formation. The stability of the microdroplets permitted intermittent application of ultrasound with corresponding decreases in ultrasonic energy requirements. The lowest energy consumption was observed with short (0.25 to 5 s) bursts of high power (41 to 61 W) ultrasonic inputs. The study also provided insight into the factors that affect the complex extraction of gallium from sodium aluminate solutions. The rate controlling step was found to be the dehydration of the gallate ion, Ga(OH)4, and the first complex formation between gallium and Kelex 100. Sodium was found to enhance the extraction rate up to a point, beyond which increased concentration was detrimental. Increasing aluminum concentration was found to slow extraction rates. Modifiers and diluents were shown to markedly affect extraction rates even without ultrasound. Ketone modifiers, particularly 2-undecanone, when used with Kermac 470B or Escaid 200 diluents enhanced extraction rates of gallium to the point that the use of ultrasound provided no additional benefits. The positive effects of ketone modifiers for the solvent extraction of gallium had not been previously reported.

  14. Synthesis, structural and magnetic characterisation of nanocrystalline nickel ferrite NiFe2O4 obtained by reactive milling

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Synthesis, structural and magnetic characterisation of nanocrystalline nickel ferrite ­ NiFe2O4-Napoca, Romania Abstract Nanocrystalline nickel ferrite (NiFe2O4) has been synthesized from a stoichiometric. The particles size distribution was analyzed using a laser particle size analyser. The nickel ferrite begins

  15. Nickel(II) Complexes with Tetra-and Pentadentate Aminopyridine Ligands: Synthesis, Structure, Electrochemistry, and Reduction to

    E-Print Network [OSTI]

    Nazarenko, Alexander

    Nickel(II) Complexes with Tetra- and Pentadentate Aminopyridine Ligands: Synthesis, Structure, Electrochemistry, and Reduction to Nickel(I) Species Sergey V. Kryatov, B. Sharmila Mohanraj, Vladislav V. Tarasov A series of nickel(II) complexes with polydentate aminopyridine ligands N,N,N-tris-[2-(2-pyridyl

  16. PROPRITS MAGNTIQUES DDUITES DES TUDES DE CONDUCTIBILIT LECTRIQUE ET D'EFFET HALL DES COUCHES MINCES DE NICKEL

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    COUCHES MINCES DE NICKEL Par A. COLOMBANT, G. GOUREAUX et P. HUET, Faculté des Sciences de Caen, France ferromagnétique Tf et paramagnétique Tp de couches minces de nickel en fonction de leur épaisseur. La différence, calculées par la formule de Cabrera, rejoignent pour les fortes épaisseurs celles de Weiss pour le nickel

  17. Amino Alcohols as Ligands for Nickel-Catalyzed Suzuki Reactions of Unactivated Alkyl Halides, Including Secondary Alkyl Chlorides, with

    E-Print Network [OSTI]

    Fu, Gregory C.

    Amino Alcohols as Ligands for Nickel-Catalyzed Suzuki Reactions of Unactivated Alkyl Halides February 27, 2006; E-mail: gcf@mit.edu Early work in the area of palladium- and nickel-catalyzed cross of unactivated secondary alkyl halides is based on nickel/bathophenanthroline.4 This method can be applied

  18. Syntectonic mobility of supergene nickel ores of New Caledonia (Southwest Pacific). Evidence from faulted regolith and garnierite veins.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Syntectonic mobility of supergene nickel ores of New Caledonia (Southwest Pacific). Evidence from. dominique.cluzel@univ-orleans.fr Running title: Syntectonic mobility of supergene nickel ores Abstract Supergene nickel deposits of New Caledonia that have been formed in the Neogene by weathering of obducted

  19. GERMAIN C ET AL: ESTIMATING THE SECTION ELEVATION ANGLE OF CUBES ON A CUBIC MESH. APPLICATION TO NICKEL MICROSTRUCTURE SIZE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    TO NICKEL MICROSTRUCTURE SIZE ESTIMATION. Abbreviated Title ESTIMATING THE SECTION ANGLE OF CUBES ON A CUBIC MESH FOR NICKEL SUPERALLOY CHARACTERISATION. Christian GERMAIN, Rémy BLANC, Marc DONIAS, Olivier are applicable to materials such as nickel base superalloys, the microstructure of which shows cubes arranged

  20. J. Phys. Chem. 1994, 98, 1245-1249 1245 Structural and Catalytic Properties of Model Supported Nickel Catalysts

    E-Print Network [OSTI]

    Goodman, Wayne

    Nickel Catalysts Kent Coulter, Xueping Xu, and D. Wayne Goodman' Department of Chemistry, Texas A" The surface structure and catalytic properties of model silica-supported nickel catalysts have been hydrogenolysis and carbon monoxide methanation. Nickel particles in the range 15-80 %L were vacuum deposited onto

  1. JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 16, NO. 5, OCTOBER 2007 1025 Ultrathick and High-Aspect-Ratio Nickel

    E-Print Network [OSTI]

    Akin, Tayfun

    -Aspect-Ratio Nickel Microgyroscope Using EFAB Multilayer Additive Electroforming Said Emre Alper, Ilker Ender Ocak of a microgyroscope that has a 240-µm-thick multilayer electroformed-nickel structural mass and a lateral aspect ratio, demonstrating reliability of electroformed nickel of EFAB process. In addition, the mechanical quality factor

  2. Properties of liquid nickel: A critical comparison of EAM and MEAM calculations F. J. Cherne and M. I. Baskes

    E-Print Network [OSTI]

    Deymier, Pierre

    Properties of liquid nickel: A critical comparison of EAM and MEAM calculations F. J. Cherne and M 19 December 2001 In this paper, we compare a variety of properties of liquid nickel calculated shows that the short-ranged MEAM potential can give a representative picture of liquid nickel. DOI: 10

  3. THE CRYSTAL STRUCTURE OF NICKEL HYDRIDE By J. W. CABLE, E. O. WOLLAN, and W. C. KOEHLER,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    460. THE CRYSTAL STRUCTURE OF NICKEL HYDRIDE By J. W. CABLE, E. O. WOLLAN, and W. C. KOEHLER, Oak Ridge National Laboratory, Oak Ridge, Tennessee. Résumé. 2014 L'hydrure de nickel est cubique à faces centrées. H occupe les sites octaédriques avec un rapport H/Ni égal à 0,6 ± 0,1. Abstract. 2014 Nickel

  4. The paramagnetic response of nickel at high temperature P. J. Brown (+), H. Capellman (), J. Dportes (*), D. Givord (*), S. M. Johnson (+)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    491 The paramagnetic response of nickel at high temperature P. J. Brown (+), H. Capellman (°), J, révisé le 5 novembre, accepté le 6 novembre 1985) Résumé. 2014 La réponse paramagnétique du nickel a été. 2014 The paramagnetic response of nickel has been measured using polarized neutron scattering

  5. From carbon nanobells to nickel nanotubes S. Ma, V. V. S. S. Srikanth, D. Maik, G. Y. Zhang,a

    E-Print Network [OSTI]

    Zhang, Guangyu

    From carbon nanobells to nickel nanotubes S. Ma, V. V. S. S. Srikanth, D. Maik, G. Y. Zhang,a T nanostructures as the initial templates. Following the strategy, nickel Ni nanotubes are prepared by using carbon deposition technique. Carbon/nickel core/shell structures are then prepared by electroplating the CNBs

  6. Nickel(II) and copper(II) complexes with pyridine-containing macrocycles bearing an aminopropyl pendant arm: synthesis,

    E-Print Network [OSTI]

    Nazarenko, Alexander

    Nickel(II) and copper(II) complexes with pyridine-containing macrocycles bearing an aminopropyl of three five-coordinate nickel(II) complexes with pendant arm-containing macrocycles has been achieved-pyridine and a tripodal tetramine. Demetallation of the nickel(II) macrocycles yielded stable pentadentate ligands

  7. Materials Science and Engineering A 460461 (2007) 392402 High temperature corrosion resistance of candidate nickel-based

    E-Print Network [OSTI]

    DuPont, John N.

    2007-01-01T23:59:59.000Z

    of candidate nickel-based weld overlay alloys in a low NOx environment R.M. Deacon, J.N. DuPont, A.R. Marder overlay a more corrosion resistant alloy on top of existing tubes. Two nickel- based alloys developed: Microsegregation; Nickel-based alloys; Sulfidation 1. Introduction In an effort to reduce boiler emissions

  8. Synthesis and Hydride Transfer Reactions of Cobalt and Nickel Hydride Complexes to BX3 Compounds

    SciTech Connect (OSTI)

    Mock, Michael T.; Potter, Robert G.; O'Hagan, Molly J.; Camaioni, Donald M.; Dougherty, William G.; Kassel, W. S.; DuBois, Daniel L.

    2011-12-05T23:59:59.000Z

    Hydrides of numerous transition metal complexes can be generated by the heterolytic cleavage of H{sub 2} gas such that they offer alternatives to using main group hydrides in the regeneration of ammonia borane, a compound that has been intensely studied for hydrogen storage applications. Previously, we reported that HRh(dmpe){sub 2}, dmpe = 1,2-bis(dimethylphosphinoethane) was capable of reducing a variety of BX{sub 3} compounds having hydride affinity (HA) greater than or equal to HA of BEt{sub 3}. This study examines the reactivity of less expensive cobalt and nickel hydride complexes, (HCo(dmpe){sub 2} and [HNi(dmpe){sub 2}]{sup +}), to form B-H bonds. The hydride donor abilities ({Delta}G{sub H{sup -}}{sup o}) of HCo(dmpe){sub 2} and [HNi(dmpe){sub 2}]{sup +} were positioned on a previously established scale in acetonitrile that is cross-referenced with calculated HAs of BX{sub 3} compounds. The collective data guided our selection of BX{sub 3} compounds to investigate and aided our analysis of factors that determine favorability of hydride transfer. HCo(dmpe){sub 2} was observed to transfer H{sup -} to BX{sub 3} compounds with X = H, OC{sub 6}F{sub 5} and SPh. The reaction with B(SPh){sub 3} is accompanied by formation of (BH{sub 3}){sub 2}-dmpe and (BH{sub 2}SPh){sub 2}-dmpe products that follow from reduction of multiple BSPh bonds and loss of a dmpe ligand from Co. Reactions between HCo(dmpe){sub 2} and B(SPh){sub 3} in the presence of triethylamine result in formation of Et{sub 3}N-BH{sub 2}SPh and Et{sub 3}N-BH{sub 3} with no loss of dmpe ligand. Reactions of the cationic complex [HNi(dmpe){sub 2}]{sup +} with B(SPh){sub 3} under analogous conditions give Et{sub 3}N-BH{sub 2}SPh as the final product along with the nickel-thiolate complex [Ni(dmpe){sub 2}(SPh)]{sup +}. The synthesis and characterization of HCo(dedpe){sub 2} (dedpe = diethyldiphenyl(phosphino)ethane) from H{sub 2} and a base is also discussed; including the formation of an uncommon trans dihydride species, trans-[(H{sub 2})Co(dedpe){sub 2}][BF{sub 4}].

  9. Radiative and Auger decay data for modelling nickel K lines

    E-Print Network [OSTI]

    P. Palmeri; P. Quinet; C. Mendoza; M. A. Bautista; J. Garcia; M. C. Witthoeft; T. R. Kallman

    2008-06-06T23:59:59.000Z

    Radiative and Auger decay data have been calculated for modelling the K lines in ions of the nickel isonuclear sequence, from Ni$^+$ up to Ni$^{27+}$. Level energies, transition wavelengths, radiative transition probabilities, and radiative and Auger widths have been determined using Cowan's Hartree--Fock with Relativistic corrections (HFR) method. Auger widths for the third-row ions (Ni$^+$--Ni$^{10+}$) have been computed using single-configuration average (SCA) compact formulae. Results are compared with data sets computed with the AUTOSTRUCTURE and MCDF atomic structure codes and with available experimental and theoretical values, mainly in highly ionized ions and in the solid state.

  10. Advanced nickel base alloys for high strength, corrosion applications

    DOE Patents [OSTI]

    Flinn, John E. (Idaho Falls, ID)

    1998-01-01T23:59:59.000Z

    Improved nickel-base alloys of enhanced strength and corrosion resistance, produced by atomization of an alloy melt under an inert gas atmosphere and of composition 0-20Fe, 10-30Cr, 2-12Mo, 6 max. Nb, 0.05-3 V, 0.08 max. Mn, 0.5 max. Si, less than 0.01 each of Al and Ti, less than 0.05 each of P and S, 0.01-0.08C, less than 0.2N, 0.1 max. 0, bal. Ni.

  11. Electroless nickel: an important coating for diamond turning applications

    SciTech Connect (OSTI)

    Dini, J.W.

    1980-09-24T23:59:59.000Z

    Diamond turning is the use of a single-point diamond tool on a precision lathe under very precisely controlled machine and environmental conditions to fabricate finished components. With a machine presently available at LLNL a part accuracy between 0.05 and 1.0 ..mu..m (2 and 40 millionths of an inch) is obtainable. Coatings offer significant advantages for diamond turning applications inasmuch as they can be applied to lightweight substrates such as aluminum or beryllium. One of the most used coatings for diamond turning applications is electroless nickel. Purpose of this paper is to document case histories of such applications and suggest areas for future work.

  12. Electrodeposited tungsten-nickel-boron: A replacement for hexavalent chromium

    SciTech Connect (OSTI)

    Steffani, C.; Meltzer, M.

    1995-04-01T23:59:59.000Z

    Chromium, deposited from acidic solutions of its hexavalent ion, has been the rule for wear resistant, corrosion resistant coatings for many years. Although chromium coatings are durable, the plating process generates air emissions, effluent rinse waters, and process solutions that are toxic, suspected carcinogens, and a risk to human health and the environment. Tungsten-nickel-boron (W-Ni-B) alloy deposition is a potential substitute for hexavalent chrome. It has excellent wear, corrosion, and mechanical properties and also may be less of an environmental risk. This study examines the electroplating process and deposit properties of W-Ni-B and compares them with those of hexavalent chrome.

  13. Torsion Testing of Diffusion Bonded LIGA Formed Nickel

    SciTech Connect (OSTI)

    Buchheit, T.E.; Christenson, T.R.; Schmale, D.T.

    1999-01-27T23:59:59.000Z

    A test technique has been devised which is suitable for the testing of the bond strength of batch diffusion bonded LIGA or DXRL defined structures. The method uses a torsion tester constructed with the aid of LIGA fabrication and distributed torsion specimens which also make use of the high aspect ratio nature of DXRL based processing. Measurements reveal achieved bond strengths of 130MPa between electroplated nickel with a bond temperature of 450 C at 7 ksi pressure which is a sufficiently low temperature to avoid mechanical strength degradation.

  14. Advanced nickel base alloys for high strength, corrosion applications

    DOE Patents [OSTI]

    Flinn, J.E.

    1998-11-03T23:59:59.000Z

    Improved nickel-base alloys of enhanced strength and corrosion resistance, produced by atomization of an alloy melt under an inert gas atmosphere and of composition 0--20Fe, 10--30Cr, 2--12Mo, 6 max. Nb, 0.05--3 V, 0.08 max. Mn, 0.5 max. Si, less than 0.01 each of Al and Ti, less than 0.05 each of P and S, 0.01--0.08C, less than 0.2N, 0.1 max. 0, bal. Ni. 3 figs.

  15. Low temperature formation of electrode having electrically conductive metal oxide surface

    DOE Patents [OSTI]

    Anders, Simone (Albany, CA); Anders, Andre (Albany, CA); Brown, Ian G. (Berkeley, CA); McLarnon, Frank R. (Orinda, CA); Kong, Fanping (Berkeley, CA)

    1998-01-01T23:59:59.000Z

    A low temperature process is disclosed for forming metal suboxides on substrates by cathodic arc deposition by either controlling the pressure of the oxygen present in the deposition chamber, or by controlling the density of the metal flux, or by a combination of such adjustments, to thereby control the ratio of oxide to metal in the deposited metal suboxide coating. The density of the metal flux may, in turn, be adjusted by controlling the discharge current of the arc, by adjusting the pulse length (duration of on cycle) of the arc, and by adjusting the frequency of the arc, or any combination of these parameters. In a preferred embodiment, a low temperature process is disclosed for forming an electrically conductive metal suboxide, such as, for example, an electrically conductive suboxide of titanium, on an electrode surface, such as the surface of a nickel oxide electrode, by such cathodic arc deposition and control of the deposition parameters. In the preferred embodiment, the process results in a titanium suboxide-coated nickel oxide electrode exhibiting reduced parasitic evolution of oxygen during charging of a cell made using such an electrode as the positive electrode, as well as exhibiting high oxygen overpotential, resulting in suppression of oxygen evolution at the electrode at full charge of the cell.

  16. Preparation and electrochemical properties of multiwalled carbon nanotubes-nickel oxide porous composite for supercapacitors

    SciTech Connect (OSTI)

    Zheng Yanzhen [College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Zhang Milin [College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)]. E-mail: dhyzyz@yahoo.com.cn; Gao Peng [College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)

    2007-09-04T23:59:59.000Z

    Porous nickel oxide/multiwalled carbon nanotubes (NiO/MWNTs) composite material was synthesized using sodium dodecyl phenyl sulfate as a soft template and urea as hydrolysis-controlling agent. Scanning electron microscopy (SEM) results show that the as-prepared nickel oxide nanoflakes aggregate to form a submicron ball shape with a porous structure, and the MWNTs with entangled and cross-linked morphology are well dispersed in the porous nickel oxide. The composite shows an excellent cycle performance at a high current of 2 A g{sup -1} and keeps a capacitance retention of about 89% over 200 charge/discharge cycles. A specific capacitance approximate to 206 F g{sup -1} has been achieved with NiO/MWNTs (10 wt.%) in 2 M KOH electrolyte. The electrical conductivity and the active sites for redox reaction of nickel oxide are significantly improved due to the connection of nickel nanoflakes by the long entangled MWNTs.

  17. Electrocatalytic hydrogenation using precious metal microparticles in redox-active polymer films

    SciTech Connect (OSTI)

    Coche, L.; Ehui, B.; Limosin, D.; Moutet, J.C. (Univ. Joseph Fourier, Grenoble (France))

    1990-11-09T23:59:59.000Z

    Glassy carbon felt electrodes have been modified by electrodeposition of poly(pyrrole-viologen) films (derived from N,N{prime}-dialkyl-4,4{prime}-bipyridinium salts), followed by electroprecipitation of precious metal (Pt, Pd, Rh, or Ru) microparticles. The resulting electrodes have been proved to be active for the electrocatalytic hydrogenation of conjugated enones (2-cyclohexen-1-one, cryptone, carvone, isophorone), styrene, and benzonitrile in aqueous media (pH 1). Despite low loadings of metal catalysts, high electric and products yields and a long term stability of these cathodes have been observed. The influence of the metal loading and the polymer structure on the catalytic efficiency as well as the selectivity obtained according to the metal catalyst used have been studied. Comparison with results previously reported for other catalytic cathodes like Pt/Pt, Pd/C, or Raney nickel electrodes proves the high efficiency of these metal microparticles within redox polymer film based electrodes.

  18. Trace metal capture by various sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.N.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

    1996-12-31T23:59:59.000Z

    Toxic trace metallic elements such as arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, and selenium are usually contained in coal in various forms and trace amounts. These metals will either stay in the ash or be vaporized during high temperature combustion. Portions of the vaporized metals may eventually be emitted from a combustion system in the form of metal fumes or particulates with diameters less than 1 micron, which are potentially hazardous to the environment. Current practice of controlling trace metal emissions during coal combustion employs conventional air pollution control devices (APCDs), such as electrostatic precipitators and baghouses, to collect fly ash and metal fumes. The control may not always be effective on metal fumes due to their extremely fine sizes. This study is to explore the opportunities for improved control of toxic trace metal emissions from coal-fired combustion systems. Specifically, the technology proposed is to employ suitable sorbents to reduce the amount of metal volatilization and capture volatilized metal vapors during fluidized bed coal combustion. The objective of the study was to investigate experimentally and theoretically the metal capture process.

  19. Method for the preparation of metal colloids in inverse micelles and product preferred by the method

    DOE Patents [OSTI]

    Wilcoxon, Jess P. (Albuquerque, NM)

    1992-01-01T23:59:59.000Z

    A method is provided for preparing catalytic elemental metal colloidal particles (e.g. gold, palladium, silver, rhodium, iridium, nickel, iron, platinum, molybdenum) or colloidal alloy particles (silver/iridium or platinum/gold). A homogeneous inverse micelle solution of a metal salt is first formed in a metal-salt solvent comprised of a surfactant (e.g. a nonionic or cationic surfactant) and an organic solvent. The size and number of inverse micelles is controlled by the proportions of the surfactant and the solvent. Then, the metal salt is reduced (by chemical reduction or by a pulsed or continuous wave UV laser) to colloidal particles of elemental metal. After their formation, the colloidal metal particles can be stabilized by reaction with materials that permanently add surface stabilizing groups to the surface of the colloidal metal particles. The sizes of the colloidal elemental metal particles and their size distribution is determined by the size and number of the inverse micelles. A second salt can be added with further reduction to form the colloidal alloy particles. After the colloidal elemental metal particles are formed, the homogeneous solution distributes to two phases, one phase rich in colloidal elemental metal particles and the other phase rich in surfactant. The colloidal elemental metal particles from one phase can be dried to form a powder useful as a catalyst. Surfactant can be recovered and recycled from the phase rich in surfactant.

  20. Maternal exposure to metals—Concentrations and predictors of exposure

    SciTech Connect (OSTI)

    Callan, A.C., E-mail: a.callan@ecu.edu.au [Centre for Ecosystem Management, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027 (Australia); Hinwood, A.L.; Ramalingam, M.; Boyce, M. [Centre for Ecosystem Management, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027 (Australia)] [Centre for Ecosystem Management, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027 (Australia); Heyworth, J. [School Population Health, The University of Western Australia, 35 Stirling Highway Crawley, WA 6009 (Australia)] [School Population Health, The University of Western Australia, 35 Stirling Highway Crawley, WA 6009 (Australia); McCafferty, P. [ChemCentre, PO Box 1250, Bentley, WA 6983 (Australia)] [ChemCentre, PO Box 1250, Bentley, WA 6983 (Australia); Odland, J.Ø. [Department of Community Medicine, University of Tromsø, N-9037 Tromsø (Norway)] [Department of Community Medicine, University of Tromsø, N-9037 Tromsø (Norway)

    2013-10-15T23:59:59.000Z

    A variety of metals are important for biological function but have also been shown to impact health at elevated concentrations, whereas others have no known biological function. Pregnant women are a vulnerable population and measures to reduce exposure in this group are important. We undertook a study of maternal exposure to the metals, aluminium, arsenic, copper, cobalt, chromium, lithium, manganese, nickel, selenium, tin, uranium and zinc in 173 participants across Western Australia. Each participant provided a whole blood and urine sample, as well as drinking water, residential soil and dust samples and completed a questionnaire. In general the concentrations of metals in all samples were low with the notable exception of uranium (blood U mean 0.07 µg/L, range <0.01–0.25 µg/L; urinary U mean 0.018 µg/g creatinine, range <0.01–0.199 µg/g creatinine). Factors that influenced biological concentrations were consumption of fish which increased urinary arsenic concentrations, hobbies (including mechanics and welding) which increased blood manganese concentrations and iron/folic acid supplement use which was associated with decreased concentrations of aluminium and nickel in urine and manganese in blood. Environmental concentrations of aluminium, copper and lithium were found to influence biological concentrations, but this was not the case for other environmental metals concentrations. Further work is underway to explore the influence of diet on biological metals concentrations in more detail. The high concentrations of uranium require further investigation. -- Highlights: • High concentrations of uranium with respect to international literature. • Environmental concentrations of Al, Cu and Li influenced urinary concentrations. • Exposure to mechanics/welding hobbies increased blood Mn concentrations. • Iron/Folic acid supplements reduced biological concentrations of Al, Ni and Mn.

  1. SURFACE MODIFICATION OF ZIRCALOY-4 SUBSTRATES WITH NICKEL ZIRCONIUM INTERMETALLICS

    SciTech Connect (OSTI)

    Luscher, Walter G.; Gilbert, Edgar R.; Pitman, Stan G.; Love, Edward F.

    2013-02-01T23:59:59.000Z

    Surfaces of Zircaloy-4 (Zr-4) substrates were modified with nickel-zirconium (NiZr) intermetallics to tailor oxidation performance for specialized applications. Surface modification was achieved by electroplating Zr-4 substrates with nickel (Ni) and then performing thermal treatments to fully react the Ni plating with the substrates, which resulted in a coating of NiZr intermetallics on the substrate surfaces. Both plating thickness and thermal treatment were evaluated to determine the effects of these fabrication parameters on oxidation performance and to identify an optimal surface modification process. Isothermal oxidation tests were performed on surface-modified materials at 290°, 330°, and 370°C under a constant partial pressure of oxidant (i.e., 1 kPa D2O in dry Ar at 101 kPa) for 64 days. Test results revealed an enhanced, transient oxidation rate that decreased asymptotically toward the rate of the Zr-4 substrate. Oxidation kinetics were analyzed from isothermal weight gain data, which were correlated with microstructure, hydrogen pickup, strength, and hardness.

  2. Oxide dispersion strengthening of nickel electrodeposits for microsystem applications.

    SciTech Connect (OSTI)

    Janek, Richard P. (Owens Technology Inc., Palo Alto, CA); Kotula, Paul Gabriel; Buchheit, Thomas Edward; Michael, R. P.; Goods, Steven Howard

    2003-11-01T23:59:59.000Z

    Oxide dispersion strengthened nickel (ODS-Ni) electrodeposits were fabricated to net shape in a nickel sulfamate bath using the LIGA process. A 20 g/l charge of 10 nm Al{sub 2}O{sub 3} powder was suspended in the bath during electrodeposition to produce specimens containing an approximately 0.001-0.02 volume fraction dispersion of the alumina particulate. Mechanical properties are compared to baseline specimens fabricated using an identical sulfamate bath chemistry without the Al{sub 2}O{sub 3} powder charge. Results reveal that the as-deposited ODS-Ni exhibited significantly higher yield strength and ultimate tensile strength than the baseline material. This increase in as-deposited strength is attributed to Orowan strengthening. The ODS-Ni also showed improved retention of room temperature strength after annealing over a range of temperatures up to 600 C. Microscopy revealed that this resistance to anneal softening was due to an inhibition of grain growth in the presence of the oxide dispersion. Nanoindentation measurements revealed that the properties of the dispersion strengthened deposit were uniform through its thickness, even in narrow, high aspect ratio structures. At elevated temperatures, the strength of the ODS-Ni was approximately three times greater than that of the baseline material although with a significant reduction in hot ductility.

  3. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  4. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

    1997-01-01T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  5. Vortex dynamics : a window into the properties of type-II superconductors

    E-Print Network [OSTI]

    Taylor, Benjamin Jeremy

    2006-01-01T23:59:59.000Z

    A. Superconductivity . . . . . . . . . .theory of superconductivity B. Type I . . . . . . . . . . .11] P. G. DeGennes, Superconductivity of Metals and Alloys,

  6. FATE OF NICKEL ION IN (II-III) HYDROXYSULPHATE GREEN RUST SYNTHESIZED BY... 813 R. Bras. Ci. Solo, 31:813-818, 2007

    E-Print Network [OSTI]

    Chorover, Jon

    FATE OF NICKEL ION IN (II-III) HYDROXYSULPHATE GREEN RUST SYNTHESIZED BY... 813 R. Bras. Ci. Solo, 31:813-818, 2007 FATE OF NICKEL ION IN (II-III) HYDROXYSULPHATE GREEN RUST SYNTHESIZED the environment by coprecipitation. Index terms: nickel incorporation, nickel adsorption, X-ray diffraction

  7. NICKEL SPECIES EMISSION INVENTORY FOR OIL-FIRED BOILERS

    SciTech Connect (OSTI)

    Kevin C. Galbreath; Richard L. Schulz; Donald L. Toman; Carolyn M. Nyberg

    2004-01-01T23:59:59.000Z

    Representative duplicate fly ash samples were obtained from the stacks of 400-MW and 385-MW utility boilers (Unit A and Unit B, respectively) using a modified U.S. Environmental Protection Agency (EPA) Method 17 sampling train assembly as they burned .0.9 and 0.3 wt% S residual oils, respectively, during routine power plant operations. Residual oil fly ash (ROFA) samples were analyzed for nickel (Ni) concentrations and speciation using inductively coupled plasma-atomic emission spectroscopy, x-ray absorption fine structure (XAFS) spectroscopy, x-ray diffraction (XRD), and a water-soluble Ni extraction method. ROFA water extraction residues were also analyzed for Ni speciation using XAFS and XRD. Total Ni concentrations in the ROFAs were similar, ranging from 1.3 to 1.5 wt%; however, stack gas Ni concentrations in the Unit A were {approx}990 {micro}g/Nm{sup 3} compared to {approx}620 {micro}g/Nm{sup 3} for Unit B because of the greater residual oil feed rates employed at Unit A to attain higher load (i.e., MW) conditions with a lower heating value oil. Ni speciation analysis results indicate that ROFAs from Unit A contain about 3 wt% NiSO{sub 4} {center_dot} xH{sub 2}O (where x is assumed to be 6 for calculation purposes) and a Ni-containing spinel compound, similar in composition to (Mg,Ni)(Al,Fe){sub 2}O{sub 4}. ROFAs from Unit B contain on average 2.0 wt% NiSO{sub 4} {center_dot} 6H{sub 2}O and 1.1 wt% NiO. XAFS and XRD analyses did not detect any nickel sulfide compounds, including nickel subsulfide (Ni{sub 3}S{sub 2}) (XAFS detection limit is 5% of the total Ni concentration). In addition, XAFS measurements indicated that inorganic sulfate and organic thiophene species account for >97% of the total sulfur in the ROFAs. The presence of NiSO{sub 4} {center_dot} xH{sub 2}O and nickel oxide compound mixtures and lack of carcinogenic Ni{sub 3}S{sub 2} or nickel sulfide compounds (e.g., NiS, NiS{sub 2}) in ROFAs stack-sampled from 400- and 385-MW boilers are contrary to EPA's Ni inhalation cancer risk assessment (''Study of Hazardous Air Pollutant Emissions from Electric Utility Steam Generating Units--Final Report to Congress'', February 1998), where it is assumed that the Ni compound mixture emitted from oil-fired utilities is 50% as carcinogenic as Ni{sub 3}S{sub 2}. Apparently, this assumption greatly overestimates the Ni inhalation cancer risk from oil-fired utilities.

  8. Development of materials resistant to metal dusting degradation.

    SciTech Connect (OSTI)

    Natesan, K.; Zeng, Z.

    2006-04-24T23:59:59.000Z

    Metal dusting corrosion has been a serious problem in the petroleum and petrochemical industries, such as reforming and syngas production systems. This form of deterioration has led to worldwide material loss for 50 years. For the past three years, we have studied the mechanism of metal dusting for Fe- and Ni-base alloys. In this report, we present a correlation between the weight loss and depth of pits that form in Ni-base alloys. Nickel-base alloys were also tested at 1 and 14.8 atm (210 psi), in a high carbon activity environment. Higher system pressure was found to accelerate corrosion in most Ni-base alloys. To reduce testing time, a pre-pitting method was developed. Mechanical scratches on the alloy surface led to fast metal dusting corrosion. We have also developed preliminary data on the performance of weldments of several Ni-base alloys in a metal dusting environment. Finally, Alloy 800 tubes and plates used in a reformer plant were examined by scanning electron microscopy, energy dispersive X-ray, and Raman spectroscopy. The oxide scale on the surface of the Alloy 800 primarily consists of Fe{sub 1+x}Cr{sub 2-X}O{sub 4} spinel phase with high Fe content. Carbon can diffuse through this oxide scale. It was discovered that the growth of metal dusting pits could be stopped by means of a slightly oxidized alloy surface. This leads to a new way to solve metal dusting problem.

  9. Water-soluble metal-binding polymers with ultrafiltration: A technology for the removal, concentration, and recovery of metal ions from aqueous streams

    SciTech Connect (OSTI)

    Smith, B.F.; Robison, T.W.; Jarvinen, G.D.

    1997-12-31T23:59:59.000Z

    The use of water-soluble metal-binding polymers coupled with ultrafiltration (UF) is a technology under development to selectively concentrate and recover valuable or regulated metal-ions from dilute process or waste waters. The polymers have a sufficiently large molecular size that they can be separated and concentrated using commercially available UF technology. The polymers can then be reused by changing the solution conditions to release the metal-ions, which are recovered in a concentrated form for recycle or disposal. Pilot-scale demonstrations have been completed for a variety of waste streams containing low concentrations of metal ions including electroplating wastes (zinc and nickel) and nuclear waste streams (plutonium and americium). Many other potential commercial applications exist including remediation of contaminated solids. An overview of both the pilot-scale demonstrated applications and small scale testing of this technology are presented.

  10. In situ x-ray absorption fine structure and optical reflectance studies of electrodeposited nickel hydrous oxide films in alkaline electrolytes.

    SciTech Connect (OSTI)

    Hu, Y.; Bae, I. T.; Mo, Y.; Antonio, M. R.; Scherson, D. A.; Chemistry; Case Western Reserve Univ.

    1997-01-01T23:59:59.000Z

    X-ray absorption fine structure (XAFS) and optical reflectance spectroscopy (RS) have been used to examine in situ electronic and structural aspects of nickel hydrous oxide, a-Ni(OH)2(hyd), electrodes supported on gold in alkaline electrolytes as a function of their state of charge. The extended X-ray absorption fine structure (EXAFS) of a-Ni(OH)2(hyd) electrodes in the uncharged (UC, or discharged) and overcharged (OC, or fully charged) states yielded, in each case, a single set of two distinct nearest-neighbor shells, with distances, d(Ni-O)1 = 2.05 {+-} 0.02 {angstrom} and d(Ni-Ni)1 = 3.11 {+-} 0.02 {angstrom} for UC, and d(Ni-O)1 = 1.87 {+-} 0.02 {angstrom} and d(Ni-Ni)1 = 2.83 {+-} 0.02 {angstrom} for OC. The in situ EXAFS of films allowed to self-discharge following overcharge could be fit with contributions from both sets of shells, suggesting that only two types of nickel sites are sufficient to account for the redox chemistry of this material. These data, in addition to information derived both from quantitative X-ray absorption near-edge structure (XANES) and optical RS in the visible range, indicate that the excess anodic charge, i.e., beyond the one-electron oxidation of Ni2+ sites, observed during the first oxidation of freshly prepared a-Ni(OH)2(hyd) electrodes may not be related to oxidation state changes involving nickel sites in the lattice, and, therefore, do not support the existence of nickel sites with a formal oxidation state higher than three for charged or overcharged electrodes in this media.

  11. aluminium nickel arsenic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  12. New binding materials for metal hydride electrodes which permit good recyclability

    SciTech Connect (OSTI)

    Hara, T.; Yasuda, N. (Japan Synthetic Rubber Co., Ltd., Yokkaichi (Japan). Development Center); Takeuchi, Y. (Japan Synthetic Rubber Co., Ltd., Tokyo (Japan). Electronics Project Dept.); Sakai, T.; Uchiyama, A.; Miyamura, H.; Kuriyama, N.; Ishikawa, H. (Government Industrial Research Inst., Osaka (Japan))

    1993-09-01T23:59:59.000Z

    Thermoplastic elastomers such as styrene-butadiene-styrene block copolymer (SBS) and styrene-ethylene/butylene-styrene block copolymer (SEBS) were used successfully as binding materials for metal hydride (MH) electrodes of a nickel-metal hydride battery. These binding materials have a rubber-like nature and are soluble in organic solvents. It was easy to remove the alloy powder from a used electrode for recycling. The battery performance depended on both the kind and amount of binding materials. The best discharge capacity and rate capability were obtained for MH electrodes containing 2--5 weight percent (w/o) SEBS. The particle size distributions for the alloy were examined successfully.

  13. Method of determining the extent to which a nickel structure has been attached by a fluorine-containing gas

    DOE Patents [OSTI]

    Brusie, James P. (Oak Ridge, TN)

    2004-07-13T23:59:59.000Z

    The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

  14. Method of Determining the Extent to which a Nickel Structure has been Attached by a Fluorine-Containing Gas

    DOE Patents [OSTI]

    Brusie, James P.

    2004-07-13T23:59:59.000Z

    The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

  15. INEL metal recycle radioactive scrap metal survey report

    SciTech Connect (OSTI)

    Funk, D.M.

    1994-09-01T23:59:59.000Z

    DOE requested that inventory and characterization of radioactive scrap metal (RSM) be conducted across the DOE complex. Past studies have estimated the metal available from unsubstantiated sources. In meetings held in FY-1993, with seven DOE sites represented and several DOE-HQ personnel present, INEL personnel discovered that these numbers were not reliable and that large stockpiles did not exist. INEL proposed doing in-field measurements to ascertain the amount of RSM actually available. This information was necessary to determine the economic viability of recycling and to identify feed stock that could be used to produce containers for radioactive waste. This inventory measured the amount of RSM available at the selected DOE sites. Information gathered included radionuclide content and chemical form, general radiation field, alloy type, and mass of metal.

  16. Type B Accident Investigation Board Report, May 8, 2004, Exothermic...

    Energy Savers [EERE]

    Report, May 8, 2004, Exothermic Metal Reactor Event During Sodium Transfer Activities, East Tennessee Technology Park, Oak Ridge, Tennessee Type B Accident Investigation Board...

  17. Interaction of coal-derived synthesis gas impurities with solid oxide fuel cell metallic components

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Edwards, Danny J.; Chou, Y. S.; Cramer, Carolyn N.

    2010-05-28T23:59:59.000Z

    Chromium-containing iron-based alloys Crofer22 APU and SS 441 and nickel-based alloy Inconel600, all commonly used in a solid oxide fuel cell (SOFC) stack as interconnect materials, heat exchanger and gas feeding pipes, were exposed at 700-850oC to a synthetic coal gas containing ?2 ppm phosphine, arsine, sulfur and antimony. Samples were characterized by SEM/EDS and XRD to monitor the secondary phase formation. Exposure of ferritic stainless steels to P led to the formation of surface Cr-Mn-P-O and Fe-P-O compounds and increased temperatures accelerated the rate of interactions. Fewer interactions were observed after exposures to As and Sb. No sulfur containing compounds were found. Nickel-based alloy exhibited much stronger interactions with As and P in comparison with ferritic steels and the arsenic interactions were particularly strong. The difference between the iron- and nickel-based alloys is explained by the different chemistry and morphology of the scales grown on the alloy surfaces in coal gas. While P and As interactions with the metallic parts in the SOFC are likely to mitigate the nickel/zirconia anode poisoning, the other degradation mechanisms should be taken into consideration to avoid potential stack failures. Manganese spinels were found to be effective as phosphorus getters and could be used in coal gas cleanup.

  18. Oxygen addition to sulfur of metal thiolates

    E-Print Network [OSTI]

    Soma, Takako

    1996-01-01T23:59:59.000Z

    , and characterized. Molecular oxygen or hydrogen peroxide reacted with (N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane-nickel(II), (BME-DACO)2Ni3 +2, to produce a trimetallic, (N,N'-bismercaptoethyl-1,5-diazacyclooctane-nickel(II))-nickelate, (BME-DACO)2Ni3 2...

  19. Process for the displacement of cyanide ions from metal-cyanide complexes

    DOE Patents [OSTI]

    Smith, Barbara F. (Los Alamos, NM); Robinson, Thomas W. (Los Alamos, NM)

    1997-01-01T23:59:59.000Z

    The present invention relates to water-soluble polymers and the use of such water-soluble polymers in a process for the displacement of the cyanide ions from the metal ions within metal-cyanide complexes. The process waste streams can include metal-cyanide containing electroplating waste streams, mining leach waste streams, mineral processing waste streams, and related metal-cyanide containing waste streams. The metal ions of interest are metals that give very strong complexes with cyanide, mostly iron, nickel, and copper. The physical separation of the water-soluble polymer-metal complex from the cyanide ions can be accomplished through the use of ultrafiltration. Once the metal-cyanide complex is disrupted, the freed cyanide ions can be recovered for reuse or destroyed using available oxidative processes rendering the cyanide nonhazardous. The metal ions are released from the polymer, using dilute acid, metal ion oxidation state adjustment, or competing chelating agents, and collected and recovered or disposed of by appropriate waste management techniques. The water-soluble polymer can then be recycled. Preferred water-soluble polymers include polyethyleneimine and polyethyleneimine having a catechol or hydroxamate group.

  20. Metal-phosphate binders

    DOE Patents [OSTI]

    Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

    2009-05-12T23:59:59.000Z

    A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.