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1

Vehicle Specifications Battery Type: Li-Ion  

NLE Websites -- All DOE Office Websites (Extended Search)

1 All-Electric Conversion of the USPS Long Life Vehicle (LLV) Vehicle Specifications Battery Type: Li-Ion Pack Locations: Underbody (inboard of frame rails) Nominal System Voltage:...

2

Vehicle Specifications Battery Type: Li-Ion  

NLE Websites -- All DOE Office Websites (Extended Search)

267 V Rated Capacity (C3): 80 Ah Cooling Method: Glycol Water mix heat exchanger Powertrain Motor Type: 3 Phase Permanent Magnet Number of Motors: One Motor Cooling Type: Oil to...

3

Vehicle Specifications Battery Type: Li-Ion  

NLE Websites -- All DOE Office Websites (Extended Search)

Under hood above powertrain Under hood above powertrain Nominal System Voltage: 333 V Rated Capacity (C/3): 40 Ah Cooling Method: Glycol / Water mix Powertrain Motor Type: DC Brushless Number of Motors: One Motor Cooling Type: Glycol / Water mix Drive Wheels: Rear Wheel Drive Transmission: None (gear ratio only in rear axle) Charger Location: Underhood Charger Port: Driver's side, front quarter panel Type: Conductive (J1772 connector) Input Voltage(s): 120 or 240 VAC Chassis Aluminum Body on Steel Frame Rear Suspension: Solid Axle with Leaf Springs Front Suspension: Dual A-arm with Coil Springs Weights Design Curb Weight: 3250 lbs Delivered Curb Weight: 3310 lbs 7 Distribution F/R: 55.2/44.8% GVWR: 4450 lbs Max Payload: 940 lbs + 200 lbs driver 1 Performance Goal Payload: 1000 lbs + 200 lbs driver

4

Degradation Reactions in SONY-Type Li-Ion Batteries  

DOE Green Energy (OSTI)

Thermal instabilities were identified in SONY-type lithium-ion cells and correlated with interactions of cell constituents and reaction products. Three temperature regions of interaction were identified and associated with the state of charge (degree of Li intercalation) of the cell. Anodes were shown to undergo exothermic reactions as low as 100°C involving the solid electrolyte interface (SEI) layer and the LiPF6 salt in the electrolyte (EC: PC: DEC/LiPF6). These reactions could account for the thermal runaway observed in these cells beginning at 100°C. Exothermic reactions were also observed in the 200°C-300°C region between the intercalated lithium anodes, the LiPF6 salt and the PVDF. These reactions were followed by a high- temperature reaction region, 300°C-400°C, also involving the PVDF binder and the intercalated lithium anodes. The solvent was not directly involved in these reactions but served as a moderator and transport medhun. Cathode exotherrnic reactions with the PVDF binder were observed above 200oC and increased with the state of charge (decreasing Li content). This offers an explanation for the observed lower thermal runaway temperatures for charged cells.

Nagasubramanian, G.; Roth, E. Peter

1999-05-04T23:59:59.000Z

5

Li-ion Batteries and Beyond  

Science Conference Proceedings (OSTI)

Mar 12, 2012 ... Energy Nanomaterials: Li-ion Batteries and Beyond Sponsored by: The Minerals, Metals and Materials Society, TMS Materials Processing and ...

6

Nanotechnology in Li-ion Batteries  

DOE Green Energy (OSTI)

This is the second of three talks on nanostructures for li-ion batteries. The talks provide an up-to-date review of the issues and challenges facing Li-ion battery research with special focus on how nanostructures/ nanotechnology are being applied to this field. Novel materials reported as prospective candidates for anode, cathode and electrolyte will be summarized. The expected role of nanostructures in improving the performance of Li-ion batteries and the actual pros and cons of using such structures in this device will be addressed. Electrochemical experiments used to study Li-ion batteries will also be discussed. This includes the introduction to the standard experimental set-up and how experimental data (from charge-discharge experiments, cyclic voltammetry, impedance spectroscopy, etc) are interpreted.

Mukaibo, Hitomi (University of Florida, Martin Research Group)

2010-06-04T23:59:59.000Z

7

Ion Beam Preparation of Li-Ion Battery Electrodes Li-Ion  

Science Conference Proceedings (OSTI)

One key factor to producing such batteries is the electrode architecture. In order to tune the morphologies of Li-ion battery electrodes, a dual beam Focused Ion ...

8

Negative Electrodes for Li-Ion Batteries  

DOE Green Energy (OSTI)

Graphitized carbons have played a key role in the successful commercialization of Li-ion batteries. The physicochemical properties of carbon cover a wide range; therefore identifying the optimum active electrode material can be time consuming. The significant physical properties of negative electrodes for Li-ion batteries are summarized, and the relationship of these properties to their electrochemical performance in nonaqueous electrolytes, are discussed in this paper.

Kinoshita, Kim; Zaghib, Karim

2001-10-01T23:59:59.000Z

9

Investigation of particle isolation in Li-ion battery electrodes...  

NLE Websites -- All DOE Office Websites (Extended Search)

Investigation of particle isolation in Li-ion battery electrodes using 7Li NMR spectroscopy Title Investigation of particle isolation in Li-ion battery electrodes using 7Li NMR...

10

Mesoscale Phase Distribution in Li-ion Battery Electrode Materials...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Science SSRL Phone List People Search Maps Mesoscale Phase Distribution in Li-ion Battery Electrode Materials Friday, May 31, 2013 Li-ion batteries are regarded as key devices...

11

Li ion Motors Corp formerly EV Innovations Inc | Open Energy...  

Open Energy Info (EERE)

Page Edit with form History Facebook icon Twitter icon Li ion Motors Corp formerly EV Innovations Inc Jump to: navigation, search Name Li-ion Motors Corp (formerly EV...

12

Impedance studies on Li-ion cathodes  

DOE Green Energy (OSTI)

This paper describes the author's 2- and 3-electrode impedance results of metal oxide cathodes. These results were extracted from impedance data on 18650 Li-ion cells. The impedance results indicate that the ohmic resistance of the cell is very nearly constant with state-of-charge (SOC) and temperature. For example, the ohmic resistance of 18650 Li-ion cells is around 60 m{Omega} for different SOCS (4.1V to 3.0V) and temperatures from 35 C to {minus}20 C. However, the interfacial impedance shows a modest increase with SOC and a huge increase of between 10 and 100 times with decreasing temperature. For example, in the temperature regime (35 C down to {minus}20 C) the overall cell impedance has increased from nearly 200 m{Omega} to 8,000 m{Omega}. Most of the increase in cell impedance comes from the metal oxide cathode/electrolyte interface.

NAGASUBRAMANIAN, GANESAN

2000-04-17T23:59:59.000Z

13

Metal Oxide-Graphene Nanocomposites for Li-Ion Battery  

Science Conference Proceedings (OSTI)

Presentation Title, Metal Oxide-Graphene Nanocomposites for Li-Ion Battery. Author(s), Donghai Wang, Daiwon Choi, Juan Li, Zhenguo Yang, Zimin Nie, Rong ...

14

A Comparison of Li-Ion Battery Recycling Options  

NLE Websites -- All DOE Office Websites (Extended Search)

1 A Comparison of Li-Ion Battery Recycling Options Linda Gaines and Jennifer Dunn Center for Transportation Research Argonne National Laboratory SAE World Congress April 2012 PAPER...

15

Electrode Materials for Rechargeable Li-ion Batteries: a New ...  

High-energy density Li-ion batteries available in the market today have low power and progressively lose their energy due to voltage fade during ...

16

Ultrathin Surface Coatings for Enhanced Cycleability of Li-Ion ...  

Science Conference Proceedings (OSTI)

Characterization of Battery Cycling by In-Situ Microscopy · Chemical ... as Li-ion Battery Electrodes · In Situ and In Operando Studies of High Capacity Cathodes.

17

Recycling of Li-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 Linda Gaines Center for Transportation Research Argonne National Laboratory Recycling of Li-Ion Batteries Illinois Sustainable Technology Center University of Illinois We don't want to trade one crisis for another!  Battery material shortages are unlikely - We demonstrated that lithium demand can be met - Recycling mitigates potential scarcity  Life-cycle analysis checks for unforeseen impacts  We need to find something to do with the used materials - Safe - Economical 2 We answer these questions to address material supply issues  How many electric-drive vehicles will be sold in the US and world-wide?  What kind of batteries might they use? - How much lithium would each battery use?  How much lithium would be needed each year?

18

Novel Energy Sources -Material Architecture and Charge Transport in Solid State Ionic Materials for Rechargeable Li ion Batteries  

Science Conference Proceedings (OSTI)

Since its introduction in the consumer market at the beginning of 1990s by Sony Corporation ‘Li-ion rechargeable battery’ and ‘LiCoO2 cathode’ is an inseparable couple for highly reliable practical applications. However, a separation is inevitable as Li-ion rechargeable battery industry demand more and more from this well serving cathode. Spinel-type lithium manganate (e.g., LiMn2O4), lithium-based layered oxide materials (e.g., LiNiO2) and lithium-based olivine-type compounds (e.g., LiFePO4) are nowadays being extensively studied for application as alternate cathode materials in Li-ion rechargeable batteries. Primary goal of this project was the advancement of Li-ion rechargeable battery to meet the future demands of the energy sector. Major part of the research emphasized on the investigation of electrodes and solid electrolyte materials for improving the charge transport properties in Li-ion rechargeable batteries. Theoretical computational methods were used to select electrodes and electrolyte material with enhanced structural and physical properties. The effect of nano-particles on enhancing the battery performance was also examined. Satisfactory progress has been made in the bulk form and our efforts on realizing micro-battery based on thin films is close to give dividend and work is progressing well in this direction.

Katiyar, Ram S; Gómez, M; Majumder, S B; Morell, G; Tomar, M S; Smotkin, E; Bhattacharya, P; Ishikawa, Y

2009-01-19T23:59:59.000Z

19

Electrochemical Experiments Used to Study Li-ion Batteries  

DOE Green Energy (OSTI)

This is the third of three talks on nanostructures for Li-ion batteries. The talks provide an up-to-date review of the issues and challenges facing Li-ion battery research with special focus on how nanostructures/nanotechnology are being applied to this field. Novel materials reported as prospective candidates for anode, cathode and electrolyte will be summarized. The expected role of nanostructures in improving the performance of Li-ion batteries and the actual pros and cons of using such structures in this device will be addressed. Electrochemical experiments used to study Li-ion batteries will also be discussed. This includes the introduction to the standard experimental set-up and how experimental data (from charge-discharge experiments, cyclic voltammetry, impedance spectroscopy, etc) are interpreted.

Mukaibo, Hitomi (University of Florida, Martin Research Group)

2010-06-04T23:59:59.000Z

20

Li-Ion Batteries for Transportation Applications II  

Science Conference Proceedings (OSTI)

Oct 27, 2009 ... Energy Storage: Materials, Systems, and Applications: Li-Ion Batteries for ... storage and utilization of renewable energies like solar and wind. Cost ... Rahul Singhal1; Karina Asmar1; Ram Katiyar1; 1University of Puerto Rico

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Transport and Failure in Li-ion Batteries | Stanford Synchrotron...  

NLE Websites -- All DOE Office Websites (Extended Search)

Transport and Failure in Li-ion Batteries Monday, February 13, 2012 - 1:30pm SSRL Conference Room 137-322 Stephen J. Harris, General Motors R&D While battery performance is well...

22

Thermal Stability of Li-Ion Cells  

DOE Green Energy (OSTI)

The thermal stability of Li-ion cells with intercalating carbon anodes and metal oxide cathodes was measured as a function of state of charge and temperature for two advanced cell chemistries. Cells of the 18650 design with Li{sub x}CoO{sub 2} cathodes (commercial SONY cells) and Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2} cathodes were measured for thermal reactivity in the open circuit cell condition. Accelerating rate calorimetry (ARC) was used to measure cell thermal runaway as a function of state of charge (SOC). Microcalorimetry was used to measure the time dependence of heat generating side reactions also as a function of SOC. Components of cells were measured using differential scanning calorimetry (DSC) to study the thermal reactivity of the individual electrodes to determine the temperature regimes and conditions of the major thermal reactions. Thermal decomposition of the SEI layer at the anodes was identified as the initiating source for thermal runaway. The cells with Li{sub x}CoO{sub 2} cathodes showed greater sensitivity to SOC and higher accelerating heating rates than seen for the cells with Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2}cathodes. Lower temperature reactions starting as low as 40 C were also observed that were SOC dependent but not accelerating. These reactions were also measured in the microcalorimeter and observed to decay over time with a power-law dependence and are believed to result in irreversible capacity loss in the cells.

ROTH,EMANUEL P.

1999-09-17T23:59:59.000Z

23

Batteries - Next-generation Li-ion batteries Breakout session  

NLE Websites -- All DOE Office Websites (Extended Search)

Next-generation Li-ion batteries Next-generation Li-ion batteries EV Everywhere Workshop July 26, 2012 Breakout Session #1 - Discussion of Performance Targets and Barriers Comments on the Achievability of the Targets * Overall, everything is achievable, but, clearly, the cost targets are dramatic, particularly for AEV 300. (I have discussed this with Yet-Ming Chiang, who has a good feel for cost reductions, both their importance and interesting approaches.) * AEV 100 achievable with a good silicon/graphite composite anode and LMRNMC (unsure timeline) * AEV 300 would require cycleable Li-metal anode and UHVHC cathode (can't get there with Li-ion intercalation on both electrodes) (unsure timeline) Barriers Interfering with Reaching the Targets * Pack - too high a fraction of inactive materials/inefficient engineering designs.

24

Review on Current State of Li-ion Batteries  

DOE Green Energy (OSTI)

This is an up-to-date review of the issues and challenges facing Li-ion battery research with special focus on how nanostructures/ nanotechnology are being applied to this field. Novel materials reported as prospective candidates for anode, cathode and electrolyte will be summarized. The expected role of nanostructures in improving the performance of Li-ion batteries and the actual pros and cons of using such structures in this device will be addressed. Electrochemical experiments used to study Li-ion batteries will also be discussed. This includes the introduction to the standard experimental set-up and how experimental data (from charge-discharge experiments, cyclic voltammetry, impedance spectroscopy, etc) are interpreted.

Mukaibo, Hitomi (University of Florida, Martin Research Group)

2010-06-04T23:59:59.000Z

25

Finite volume discretization of equations describing nonlinear diffusion in Li-Ion batteries  

Science Conference Proceedings (OSTI)

Numerical modeling of electrochemical process in Li-Ion battery is an emerging topic of great practical interest. In this work we present a Finite Volume discretization of electrochemical diffusive processes occurring during the operation of Li-Ion batteries. ...

P. Popov; Y. Vutov; S. Margenov; O. Iliev

2010-08-01T23:59:59.000Z

26

IMPROVEMENT OF THERMAL STABILITY OF LI-ION BATTERIES BY  

E-Print Network (OSTI)

and Commercial Building End-Use Energy Efficiency · Industrial/Agricultural/Water End-Use Energy EfficiencyIMPROVEMENT OF THERMAL STABILITY OF LI-ION BATTERIES BY POLYMER COATING OF LIMN2O4 Prepared For: California Energy Commission Energy Innovations Small Grant Program Prepared By: Pieter Stroeve, UC Davis

27

Li-Ion and Other Advanced Battery Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

scientist viewing computer screen scientist viewing computer screen Li-Ion and Other Advanced Battery Technologies The research aims to overcome the fundamental chemical and mechanical instabilities that have impeded the development of batteries for vehicles with acceptable range, acceleration, costs, lifetime, and safety. Its aim is to identify and better understand cell performance and lifetime limitations. These batteries have many other applications, in mobile electronic devices, for example. The work addresses synthesis of components into battery cells with determination of failure modes, materials synthesis and evaluation, advanced diagnostics, and improved electrochemical model development. This research involves: Battery development and analysis; Mathematical modeling; Sophisticated diagnostics;

28

Why are there no volume Li-ion battery manufacturers in the ...  

Science Conference Proceedings (OSTI)

... There No Volume Lithium-Ion Battery Manufacturers in ... R&D; US Manufacturing of Li-ion Batteries. ... The Innovation Process for Battery Technologies. ...

2008-07-28T23:59:59.000Z

29

Analysis of Heat Dissipation in Li-Ion Cells & Modules for Modeling of Thermal Runaway (Presentation)  

DOE Green Energy (OSTI)

The objectives of this study are: (1) To develop 3D Li-Ion battery thermal abuse ''reaction'' models for cell and module analysis; (2) To understand the mechanisms and interactions between heat transfer and chemical reactions during thermal runaway for Li-Ion cells and modules; (3) To develop a tool and methodology to support the design of abuse-tolerant Li-Ion battery systems for PHEVs/HEVs; and (4) To help battery developers accelerate delivery of abuse-tolerant Li-Ion battery systems in support of the FreedomCAR's Energy Storage Program.

Kim, G.-H.; Pesaran, A.

2007-05-15T23:59:59.000Z

30

Real Space Mapping of Li-Ion Transport in Amorphous Si Anodes with Nanometer Resolution  

SciTech Connect

The electrical bias driven Li-ion motion in silicon anode materials in thin film battery heterostructures is investigated using electrochemical strain microscopy (ESM), which is a newly developed scanning probe microscopy based characterization method. ESM utilizes the intrinsic link between bias-controlled Li-ion concentration and molar volume of electrode materials, providing the capability for studies on the sub-20 nm scale, and allows the relationship between Li-ion flow and microstructure to be established. The evolution of Li-ion transport during the battery charging is directly observed.

Balke, Nina [ORNL; Jesse, Stephen [ORNL; Kim, Yoongu [Oak Ridge National Laboratory (ORNL); Adamczyk, Leslie A [ORNL; Tselev, Alexander [ORNL; Ivanov, Ilia N [ORNL; Dudney, Nancy J [ORNL; Kalinin, Sergei V [ORNL

2010-01-01T23:59:59.000Z

31

A Historical-Data-Based Method for Health Assessment of Li-Ion Battery.  

E-Print Network (OSTI)

??Nowadays, rechargeable Li-ion batteries have been widely used in laptops, cell phones and hybrid electric vehicles (HEV). The health information of battery is very important.… (more)

Dai, Wanchen

2012-01-01T23:59:59.000Z

32

Flexible, Thin, and Rechargeable Li-ion Battery Based on Semi ...  

Science Conference Proceedings (OSTI)

Symposium, Energy Storage III: Materials, Systems and Applications Symposium. Presentation Title, Flexible, Thin, and Rechargeable Li-ion Battery Based on ...

33

Modeling, Simulation & Implementation of Li-ion Battery Powered Electric and Plug-in Hybrid Vehicles.  

E-Print Network (OSTI)

??The modeling, simulation and hardware implementation of a Li-ion battery powered electric vehicle are presented in this thesis. The results obtained from simulation and experiments… (more)

Mantravadi, Siva Rama Prasanna

2011-01-01T23:59:59.000Z

34

Thermal Abuse Modeling of Li-Ion Cells and Propagation in Modules (Presentation)  

DOE Green Energy (OSTI)

The objectives of this paper are: (1) continue to explore thermal abuse behaviors of Li-ion cells and modules that are affected by local conditions of heat and materials; (2) use the 3D Li-ion battery thermal abuse 'reaction' model developed for cells to explore the impact of the location of internal short, its heating rate, and thermal properties of the cell; (3) continue to understand the mechanisms and interactions between heat transfer and chemical reactions during thermal runaway for Li-ion cells and modules; and (4) explore the use of the developed methodology to support the design of abuse-tolerant Li-ion battery systems.

Kim, G.-H.; Pesaran, A.; Smith, K.

2008-05-01T23:59:59.000Z

35

Comparison of Li-Ion Battery Recycling Processes by Life-Cycle...  

NLE Websites -- All DOE Office Websites (Extended Search)

Center for Transportation Research Argonne National Laboratory Comparison of Li-Ion Battery Recycling Processes by Life-Cycle Analysis Electric Vehicles and the Environment...

36

(V2O5) Films for Li-ion Battery and Supercapacitor Applications  

Science Conference Proceedings (OSTI)

These binder and carbon free films are characterized electrochemically for Li-ion battery applications with impedance, and galvanostatic charge-discharge cyclic ...

37

ESS 2012 Peer Review - Unique Li-ion Batteries for Utility Application...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Unique Li-ion Batteries for Utility Applications Daiwon Choi, Vilayanur V. Viswanathan, Wei Wang, Vincent L. Sprenkle Pacific Northwest National Laboratory 902 Battelle Blvd., P....

38

Fluoro-Carbonate Solvents for Li-Ion Cells  

DOE Green Energy (OSTI)

A number of fluoro-carbonate solvents were evaluated as electrolytes for Li-ion cells. These solvents are fluorine analogs of the conventional electrolyte solvents such as dimethyl carbonate, ethylene carbonate, diethyl carbonate in Li-ion cells. Conductivity of single and mixed fluoro carbonate electrolytes containing 1 M LiPF{sub 6} was measured at different temperatures. These electrolytes did not freeze at -40 C. We are evaluating currently, the irreversible 1st cycle capacity loss in carbon anode in these electrolytes and the capacity loss will be compared to that in the conventional electrolytes. Voltage stability windows of the electrolytes were measured at room temperature and compared with that of the conventional electrolytes. The fluoro-carbon electrolytes appear to be more stable than the conventional electrolytes near Li voltage. Few preliminary electrochemical data of the fluoro-carbonate solvents in full cells are reported in the literature. For example, some of the fluorocarbonate solvents appear to have a wider voltage window than the conventional electrolyte solvents. For example, methyl 2,2,2 trifluoro ethyl carbonate containing 1 M LiPF{sub 6} electrolyte has a decomposition voltage exceeding 6 V vs. Li compared to <5 V for conventional electrolytes. The solvent also appears to be stable in contact with lithium at room temperature.

NAGASUBRAMANIAN,GANESAN

1999-09-17T23:59:59.000Z

39

ESS 2012 Peer Review - Unique Li-ion Batteries for Utility Applications - Daiwon Choi, PNNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Unique Li-ion Batteries for Utility Unique Li-ion Batteries for Utility Applications Daiwon Choi, Vilayanur V. Viswanathan, Wei Wang, Vincent L. Sprenkle Pacific Northwest National Laboratory 902 Battelle Blvd., P. O. Box 999, Richland, WA 99352, USA DOE Energy Storage Program Review, Washington, DC Sept. 26-28, 2012 Acknowledgment: Dr. Imre Gyuk - Energy Storage Program Manager, Office of Electricity Delivery and Energy Reliability  Investigate the Li-ion battery for stationary energy storage unit in ~kWh level.  Fabrication and optimization of LiFePO 4 / Li 4 Ti 5 O 12 18650 cell.  Li-ion battery energy storage with effective thermal management.  Improve rate and cycle life of Li-ion battery.  Screen possible new cathode/anode electrode materials and its combinations

40

Low Temperature Electrical Performance Characteristics of Li-Ion Cells  

DOE Green Energy (OSTI)

Advanced rechargeable lithium-ion batteries are presently being developed and commercialized worldwide for use in consumer electronics, military and space applications. The motivation behind these efforts involves, among other things, a favorable combination of energy and power density. For some of the applications the power sources may need to perform at a reasonable rate at subambient temperatures. Given the nature of the lithium-ion cell chemistry the low temperature performance of the cells may not be very good. At Sandia National Laboratories, we have used different electrochemical techniques such as impedance and charge/discharge at ambient and subambient temperatures to probe the various electrochemical processes that are occurring in Li-ion cells. The purpose of this study is to identify the component that reduces the cell performance at subambient temperatures. We carried out 3-electrode impedance measurements on the cells which allowed us to measure the anode and cathode impedances separately. Our impedance data suggests that while the variation in the electrolyte resistance between room temperature and -20"C is negligible, the cathode electrolyte interracial resistance increases substantially in the same temperature span. We believe that the slow interracial charge transfer kinetics at the cathode electrolyte may be responsible for the increase in cell impedance and poor cell performance.

Nagasubramanian, Ganesan

1999-04-29T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Thermal characterization of Li-ion cells using calorimetric techniques  

DOE Green Energy (OSTI)

The thermal stability of Li-ion cells with intercalating carbon anodes and metal oxide cathodes was measured as a function of state of charge and temperature for two advanced cell chemistries. Cells of the 18650 design with Li{sub x}CoO{sub 2} cathodes (commercial Sony cells) and Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2} cathodes were measured for thermal reactivity. Accelerating rate calorimetry (ARC) was used to measure cell thermal runaway as a function of state of charge (SOC), microcalorimetry was used to measure the time dependence of thermal output, and differential scanning calorimetry (DSC) was used to study the thermal reactivity of the individual components. Thermal decomposition of the anode solid electrolyte interphase (SEI) layer occurred at low temperatures and contributes to the initiation of thermal runaway. Low temperature reactions from 40 C--70 C were observed during the ARC runs that were SOC dependent. These reactions measured in the microcalorimeter decayed over time with power-law dependence and were highly sensitive to SOC and temperature. ARC runs of aged and cycled cells showed complete absence of these low-temperature reactions but showed abrupt exothermic spikes between 105--135 C. These results suggest that during aging the anode SEI layer is decomposing from a metastable state to a stable composition that is breaking down at elevated temperatures.

ROTH,EMANUEL P.

2000-05-31T23:59:59.000Z

42

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation  

NLE Websites -- All DOE Office Websites (Extended Search)

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation and Optimization Speaker(s): Jordi Cabana-Jimenez Date: January 14, 2008 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Venkat Srinivasan The advent of Li-ion batteries has played a central role in the impressive development of portable digital and wireless technology. Such success has triggered further efforts to utilize them as key components in other applications with an even larger impact on society, which include electric vehicles and energy backup for renewable energy sources. However, several challenges need to be met before these expectations can be realized, as Li-ion batteries currently do not meet the power and energy density requirements of these devices. New and better materials for the electrodes

43

Second-Use Li-Ion Batteries to Aid Automotive and Utility Industries (Fact Sheet)  

SciTech Connect

Repurposing Li-ion batteries at the end of useful life in electric drive vehicles could eliminate owners' disposal concerns and offer low-cost energy storage for certain applications.

Not Available

2014-01-01T23:59:59.000Z

44

An ultra-compact and efficient Li-ion battery charger circuit for biomedical applications  

E-Print Network (OSTI)

This paper describes an ultra-compact analog lithium-ion (Li-ion) battery charger for wirelessly powered implantable medical devices. The charger presented here takes advantage of the tanh output current profile of an ...

Do Valle, Bruno Guimaraes

45

Comparative Modeling of Li-Ion Cell and LiFePO4 - Programmaster ...  

Science Conference Proceedings (OSTI)

Presentation Title, Comparative Modeling of Li-Ion Cell and LiFePO4 Cell for Automotive ... The cathode active material of a LiFePO4 cell is assumed to undergo ...

46

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

E-Print Network (OSTI)

R.A. Sutula, F. McLamon, Battery Rsearch Pograms of theof Energy, in Selected Battery Topics. Proceedings of theEthylene Carbonate in Li-Ion Battery Electrolyte Guoying

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-01-01T23:59:59.000Z

47

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries...  

NLE Websites -- All DOE Office Websites (Extended Search)

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation and Optimization Speaker(s): Jordi Cabana-Jimenez Date: January 14, 2008 - 12:00pm Location: 90-3122...

48

Reductive Leaching Behavior of Valuable Metals from Spent Li-Ion ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Commercial trend of cathode material for Li-ion batteries, LiCoO2, ... The Challenge of Allocation in LCA: The Case of Open-Loop Recycling.

49

Technology Assessment of Li-Ion Energy Storage Technology for Stationary Electric Utility Applications  

Science Conference Proceedings (OSTI)

Emerging Lithium-ion (Li-ion) energy storage technology, which is being developed and applied in the transportation sector, could have a profound impact in the electric sector by serving applications for distributed energy storage (DES). An earlier EPRI Report, Technology Review and Assessment of Distributed Energy Resources: Distributed Energy Storage (1012983, February 2006), identified Li-ion batteries as a potential disruptive technology for the electric power sector. EPRI undertook this project to a...

2008-03-13T23:59:59.000Z

50

Silicon Based Anodes for Li-Ion Batteries  

SciTech Connect

Silicon is environmentally benign and ubiquitous. Because of its high specific capacity, it is considered one of the most promising candidates to replace the conventional graphite negative electrode used in today's Li ion batteries. Silicon has a theoretical specific capacity of nearly 4200 mAh/g (Li21Si5), which is 10 times larger than the specific capacity of graphite (LiC6, 372 mAh/g). However, the high capacity of silicon is associated with huge volume changes (more than 300 percent) when alloyed with lithium, which can cause severe cracking and pulverization of the electrode and lead to significant capacity loss. Significant scientific research has been conducted to circumvent the deterioration of silicon based anode materials during cycling. Various strategies, such as reduction of particle size, generation of active/inactive composites, fabrication of silicon based thin films, use of alternative binders, and the synthesis of 1-D silicon nanostructures have been implemented by a number of research groups. Fundamental mechanistic research has also been performed to better understand the electrochemical lithiation and delithiation process during cycling in terms of crystal structure, phase transitions, morphological changes, and reaction kinetics. Although efforts to date have not attained a commercially viable Si anode, further development is expected to produce anodes with three to five times the capacity of graphite. In this chapter, an overview of research on silicon based anodes used for lithium-ion battery applications will be presented. The overview covers electrochemical alloying of the silicon with lithium, mechanisms responsible for capacity fade, and methodologies adapted to overcome capacity degradation observed during cycling. The recent development of silicon nanowires and nanoparticles with significantly improved electrochemical performance will also be discussed relative to the mechanistic understanding. Finally, future directions on the development of silicon based anodes will be considered.

Zhang, Jiguang; Wang, Wei; Xiao, Jie; Xu, Wu; Graff, Gordon L.; Yang, Zhenguo; Choi, Daiwon; Li, Xiaolin; Wang, Deyu; Liu, Jun

2012-06-15T23:59:59.000Z

51

Program on Technology Innovation: Technology Assessment Presentation on Li-Ion Energy Storage Technology for Stationary Electric Uti lity Applications  

Science Conference Proceedings (OSTI)

Emerging Li-ion (Li-ion) energy storage technology, which is being developed and applied in the transportation sector, could have a profound impact to in the electric sector by serving applications for distributed energy storage (DES). An earlier EPRI Report, Technology Review and Assessment of Distributed Energy ResourcesDistributed Energy Storage (1012983), identified Li-ion batteries as a potential disruptive technology for the electric power sector. This project was undertaken to assess the potential...

2008-05-20T23:59:59.000Z

52

NREL's PHEV/EV Li-Ion Battery Secondary-Use Project  

SciTech Connect

Accelerated development and market penetration of plug-in hybrid electric vehicles (PHEVs) and electric vehicles (EVs) is restricted at present by the high cost of lithium-ion (Li-ion) batteries. One way to address this problem is to recover a fraction of the Li-ion battery's cost via reuse in other applications after it is retired from service in the vehicle, when the battery may still have sufficient performance to meet the requirements of other energy storage applications.

Newbauer, J.; Pesaran, A.

2010-06-01T23:59:59.000Z

53

A New Type of Steady and Stable, Laminar, Premixed Flame in Ultra-Lean, Hydrogen-Air Combustion  

E-Print Network (OSTI)

A New Type of Steady and Stable, Laminar, Premixed Flame in Ultra-Lean, Hydrogen-Air Combustion in the development of combustion science. Several aspects of these two-dimensional flame cells are identified for premixed combustion when the other types of idealized flames are inapplicable. 1 #12;Nomenclature fuel

Geddes, Cameron Guy Robinson

54

Investigation of Path Dependence in Commercial Li-ion Cells Chosen for PHEV Duty Cycle Protocols (paper)  

Science Conference Proceedings (OSTI)

Path dependence is emerging as a premier issue of how electrochemical cells age in conditions that are diverse and variable in the time domain. For example, lithium-ion cells in a vehicle configuration will experience a variable combination of usage and rest periods over a range of temperature and state of charge (SOC). This is complicated by the fact that some aging can actually become worse (or better) when a lithium-ion cell is idle for extended periods under calendar-life (calL) aging, as opposed to cycle-life (cycL) conditions where the cell is used within a predictable schedule. The purpose of this study is to bridge the gap between highly idealized and controlled laboratory test conditions and actual field conditions regarding PHEV applications, so that field-type aging mechanisms can be mimicked and quantified in a repeatable laboratory setting. The main parameters are the magnitude and frequency of the thermal cycling, looking at isothermal, mild, and severe scenarios. To date, little is known about Li-ion aging effects caused by thermal cycling superimposed onto electrochemical cycling, and related path dependence. This scenario is representative of what Li-ion batteries will experience in vehicle service, where upon the typical start of a HEV/PHEV, the batteries will be cool or cold, will gradually warm up to normal temperature and operate there for a time, then will cool down after the vehicle is turned off. Such thermal cycling will occur thousands of times during the projected life of a HEV/PHEV battery pack. We propose to quantify the effects of thermal cycling on Li-ion batteries using a representative chemistry that is commercially available. The secondary Li-ion cells used in this study are of the 18650 configuration, have a nominal capacity rating of 1.9 Ah, and consist of a {LiMn2O4 + LiMn(1/3)Ni(1/3)Co(1/3)O2} cathode and a graphite anode. Electrochemical cycling is based on PHEV-relevant cycle-life protocols that are a combination of charge depleting (CD) and charge sustaining (CS) modes discussed in the Battery Test Manual for Plug-in Hybrid Electric Vehicles (INL, March 2008, rev0). A realistic duty cycle will involve both CD and CS modes, the proportion of each defined by the severity of the power demands. We assume that the cells will start each cycling day at 90% SOC, and that they will not be allowed to go below 35% SOC, with operation around 70% SOC being a nominal condition. The 35, 70, and 90% SOC conditions are also being used to define critical aspects of the related reference performance test (RPT) for this investigation. There are three primary components to the RPT, all assessed at room temperature: (A) static and residual capacity (SRC) over a matrix of current, (B) kinetics and pulse performance testing (PPT) over current for SOCs of interest, and (C) EIS for SOCs of interest. The RPT is performed on all cells every 30 day test interval, as well as a pulse-per-day to provide a quick diagnostic snapshot. Where feasible, we utilize various elements of Diagnostic Testing (DT) to characterize performance of the cells and to gain mechanistic-level knowledge regarding both performance features and limitations. We will present the rationale behind the experimental design, early data, and discuss the fundamental tools used to elucidate performance degradation mechanisms.

Kevin L. Gering

2011-04-01T23:59:59.000Z

55

Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion  

SciTech Connect

We used anionic sulfate surfactants to assist the stabilization of graphene in aqueous solutions and facilitate the self-assembly of in-situ grown nanocrystalline TiO2, rutile and anatase, with graphene. These nanostructured TiO2-graphene hybrid materials were used for investigation of Li-ion insertion properties. The hybrid materials showed significantly enhanced Li-ion insertion/extraction in TiO2. The specific capacity was more than doubled at high charge rates, as compared with the pure TiO2 phase. The improved capacity at high charge-discharge rate may be attributed to increased electrode conductivity in presence of a percolated graphene network embedded into the metal oxide electrodes.

Wang, Donghai; Choi, Daiwon; Li, Juan; Yang, Zhenguo; Nie, Zimin; Kou, Rong; Hu, Dehong; Wang, Chong M.; Saraf, Laxmikant V.; Zhang, Jiguang; Aksay, Ilhan A.; Liu, Jun

2009-04-01T23:59:59.000Z

56

NANOSTRUCTURED METAL OXIDES FOR ANODES OF LI-ION RECHARGEABLE BATTERIES  

DOE Green Energy (OSTI)

The aligned nanorods of Co{sub 3}O{sub 4} and nanoporous hollow spheres (NHS) of SnO{sub 2} and Mn{sub 2}O{sub 3} were investigated as the anodes for Li-ion rechargeable batteries. The Co{sub 3}O{sub 4} nanorods demonstrated 1433 mAh/g reversible capacity. The NHS of SnO{sub 2} and Mn{sub 2}O{sub 3} delivered 400 mAh/g and 250 mAh/g capacities respectively in multiple galvonastatic discharge-charge cycles. It was found that high capacity of NHS of metal oxides is sustainable attributed to their unique structure that maintains material integrity during cycling. The nanostructured metal oxides exhibit great potential as the new anode materials for Li-ion rechargeable batteries with high energy density, low cost and inherent safety.

Au, M.

2009-12-04T23:59:59.000Z

57

Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li-Ion Battery Anodes  

SciTech Connect

Hollow core-shell structured porous Si-C nanocomposites with void space up to tens of nanometers are designed to accommodate the volume expansion during lithiation for high-performance Li-ion battery anodes. An initial capacity of {approx}760 mAh/g after formation cycles (based on the entire electrode weight) with {approx}86% capacity retention over 100 cycles is achieved at a current density of 1 A/g. Good rate performance is also demonstrated.

Li, Xiaolin; Meduri, Praveen; Chen, Xilin; Qi, Wen N.; Engelhard, Mark H.; Xu, Wu; Ding, Fei; Xiao, Jie; Wang, Wei; Wang, Chong M.; Zhang, Jiguang; Liu, Jun

2012-06-14T23:59:59.000Z

58

Synthesis, Characterization and Testing of Novel Anode and Cathode Materials for Li-Ion Batteries  

DOE Green Energy (OSTI)

During this program we have synthesized and characterized several novel cathode and anode materials for application in Li-ion batteries. Novel synthesis routes like chemical doping, electroless deposition and sol-gel method have been used and techniques like impedance, cyclic voltammetry and charge-discharge cycling have been used to characterize these materials. Mathematical models have also been developed to fit the experimental result, thus helping in understanding the mechanisms of these materials.

White, Ralph E.; Popov, Branko N.

2002-10-31T23:59:59.000Z

59

Nanostructured ion beam-modified Ge films for high capacity Li ion battery anodes  

SciTech Connect

Nanostructured ion beam-modified Ge electrodes fabricated directly on Ni current collector substrates were found to exhibit excellent specific capacities during electrochemical cycling in half-cell configuration with Li metal for a wide range of cycling rates. Structural characterization revealed that the nanostructured electrodes lose porosity during cycling but maintain excellent electrical contact with the metallic current collector substrate. These results suggest that nanostructured Ge electrodes have great promise for use as high performance Li ion battery anodes.

Rudawski, N. G.; Darby, B. L.; Yates, B. R.; Jones, K. S. [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611-6400 (United States); Elliman, R. G. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, Australian National University, Canberra, Australian Capital Territory 0200 (Australia); Volinsky, A. A. [Department of Mechanical Engineering, University of South Florida, Tampa Florida 33620 (United States)

2012-02-20T23:59:59.000Z

60

A Practical Circuit-based Model for State of Health Estimation of Li-ion Battery Cells in Electric Vehicles.  

E-Print Network (OSTI)

??In this thesis the development of the state of health of Li-ion battery cells under possible real-life operating conditions in electric cars has been characterised.… (more)

Lam, L.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Fofonoff-type, Inertial-Mode Steady States in a Model of the Equatorial Oceans  

Science Conference Proceedings (OSTI)

We examine the steady state response in the equatorial regions of a nonlinear, one-active-layer, reduced-gravity shallow water ocean model with meridional boundaries that is driven by uniform wind forcing. When the wind forcing is westward, the ...

Richard Greatbatch; Toshio Yamagata

1985-10-01T23:59:59.000Z

62

Selected test results from the neosonic polymer Li-ion battery.  

DOE Green Energy (OSTI)

The performance of the Neosonic polymer Li-ion battery was measured using a number of tests including capacity, capacity as a function of temperature, ohmic resistance, spectral impedance, hybrid pulsed power test, utility partial state of charge (PSOC) pulsed cycle test, and an over-charge/voltage abuse test. The goal of this work was to evaluate the performance of the polymer Li-ion battery technology for utility applications requiring frequent charges and discharges, such as voltage support, frequency regulation, wind farm energy smoothing, and solar photovoltaic energy smoothing. Test results have indicated that the Neosonic polymer Li-ion battery technology can provide power levels up to the 10C{sub 1} discharge rate with minimal energy loss compared to the 1 h (1C) discharge rate. Two of the three cells used in the utility PSOC pulsed cycle test completed about 12,000 cycles with only a gradual loss in capacity of 10 and 13%. The third cell experienced a 40% loss in capacity at about 11,000 cycles. The DC ohmic resistance and AC spectral impedance measurements also indicate that there were increases in impedance after cycling, especially for the third cell. Cell No.3 impedance Rs increased significantly along with extensive ballooning of the foil pouch. Finally, at a 1C (10 A) charge rate, the over charge/voltage abuse test with cell confinement similar to a multi cell string resulted in the cell venting hot gases at about 45 C 45 minutes into the test. At 104 minutes into the test the cell voltage spiked to the 12 volt limit and continued out to the end of the test at 151 minutes. In summary, the Neosonic cells performed as expected with good cycle-life and safety.

Ingersoll, David T.; Hund, Thomas D.

2010-07-01T23:59:59.000Z

63

Surface treated natural graphite as anode material for high-power Li-ion battery applications.  

Science Conference Proceedings (OSTI)

High power application of Li-ion battery in hybrid electrical vehicles requires low cost and safe cell materials. Among the various carbon anode materials used in lithium ion batteries, natural graphite shows the most promise with advantages in performance and cost. However, natural graphite is not compatible with propylene carbonate (PC)-based electrolytes, which have a lower melting point and improved safety characteristics. The problem with it is that the molecules of propylene carbonate intercalate with Li+ into graphite, and that frequently leads to the exfoliation of the graphite matrix.

Liu, J.; Vissers, D. R.; Amine, K.; Barsukov, I. V.; Henry, F.; Doniger, J.; Chemical Engineering; Superior Graphite Co.

2006-01-01T23:59:59.000Z

64

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

DOE Green Energy (OSTI)

A study of the anodic oxidation of vinyl ethylene carbonate (VEC) was conducted with post-mortem analysis of reaction products by ATR-FTIR and gel permeation chromatography (GPC). The half-wave potential (E1/2) for oxidation of VEC is ca. 3.6 V producing a resistive film on the electrode surface. GPC analysis of the film on a gold electrode produced by anodization of a commercial Li-ion battery electrolyte containing 2 percent VEC at 4.1 V showed the presence of a high molecular weight polymer. IR analysis indicated polycarbonate with alkyl carbonate rings linked by aliphatic methylene and methyl branches.

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-02-28T23:59:59.000Z

65

Two and Three-Electrode Impedance Studies on 18650 Li-Ion Cells  

DOE Green Energy (OSTI)

Two and three electrode impedance measurements were made on 18650 Li-ion cells at different QB temperatures ranging from 35 C to {minus}40 C. The ohmic resistance of the cell is nearly constant the temperature range studied although the total cell impedance increases by an order of magnitude in the same temperature range. In contrast to what is commonly believed, we show from our three-electrode impedance results that, the increase in cell impedance comes mostly from the cathode and not from the anode. Further, the anode and cathode contribute to both the impedance loops (in the NyQuist plot).

Nagasubramanian, Ganesan

1999-08-11T23:59:59.000Z

66

Predicted Structure, Thermo-Mechanical Properties and Li Ion Transport in LiAlF4 Glass  

Science Conference Proceedings (OSTI)

Materials with the LiAlF{sub 4} composition are of interest as protective electrode coatings in Li ion battery applications due to their high cationic conductivity. Here classical molecular dynamics calculations are used to produce amorphous model structures by simulating a quench from the molten state. These are analysed in terms of their individual pair correlation functions and atomic coordination environments. This indicates that amorphous LiAlF{sub 4} is formed of a network of corner sharing AlF{sub 6} octahedra. Li ions are distributed within this network, primarily associated with non-bridging fluorine atoms. The nature of the octahedral network is further analysed through intra- and interpolyhedral bond angle distributions and the relative populations of bridging and non-bridging fluorine ions are calculated. Network topology is considered through the use of ring statistics, which indicates that, although topologically well connected, LiAlF{sub 4} contains an appreciable number of corner-linked branch-like AlF{sub 6} chains. Thermal expansion values are determined above and below the predicted glass transition temperature of 1340 K. Finally, movement of Li ions within the network is examined with predictions of the mean squared displacements, diffusion coefficients and Li ion activation energy. Different regimes for lithium ion movement are identified, with both diffusive and sessile Li ions observed. For migrating ions, a typical trajectory is illustrated and discussed in terms of a hopping mechanism for Li transport.

Stechert, T. R.; Rushton, M. J. D.; Grimes, R. W.; Dillon, A. C.

2012-08-15T23:59:59.000Z

67

PHEV/EV Li-Ion Battery Second-Use Project (Presentation)  

SciTech Connect

Accelerated development and market penetration of plug-in hybrid electric vehicles (PHEVs) and electric vehicles (Evs) are restricted at present by the high cost of lithium-ion (Li-ion) batteries. One way to address this problem is to recover a fraction of the battery cost via reuse in other applications after the battery is retired from service in the vehicle, if the battery can still meet the performance requirements of other energy storage applications. In several current and emerging applications, the secondary use of PHEV and EV batteries may be beneficial; these applications range from utility peak load reduction to home energy storage appliances. However, neither the full scope of possible opportunities nor the feasibility or profitability of secondary use battery opportunities have been quantified. Therefore, with support from the Energy Storage activity of the U.S. Department of Energy's Vehicle Technologies Program, the National Renewable Energy Laboratory (NREL) is addressing this issue. NREL will bring to bear its expertise and capabilities in energy storage for transportation and in distributed grids, advanced vehicles, utilities, solar energy, wind energy, and grid interfaces as well as its understanding of stakeholder dynamics. This presentation introduces NREL's PHEV/EV Li-ion Battery Secondary-Use project.

Neubauer, J.; Pesaran, A.

2010-04-01T23:59:59.000Z

68

Electrical and Electrochemical Performance Characteristics of Small Commercial Li-Ion Cells  

DOE Green Energy (OSTI)

Advanced rechargeable lithium-ion batteries are presently being developed and commercialized worldwide for use in consumer electronics, military and space applications. At Sandia National Laboratories we have used different electrochemical techniques such as impedance and charge/discharge at ambient and subambient temperatures to probe the various electrochemical processes that are occurring in Li-ion cell. The purpose of this study is to identify the component that reduces the cell performance at subambient temperatures. Our impedance data suggest that while the variation in the electrolyte resistance between room temperature and {minus}20 C is negligible the anode electrolyte interfacial resistance increases by an order of magnitude in the same temperature regime. We believe that the solid electrolyte interface (SEI) layer on the carbon anode may be responsible for the increase in cell impedance. We have also evaluated the cells in hybrid mode with capacitors. High-current operation in the hybrid mode allowed fill usage of the Li-ion cell capacity at 25 C and showed a factor of 5 improvement in delivered capacity at {minus}20 C.

Ingersoll, D.; Nagasubramanian, G.; Roth, E.P.

1998-12-22T23:59:59.000Z

69

Demonstration Initiative for a Grid Support Energy Storage System using Li-ion Technology: Phase I Report  

Science Conference Proceedings (OSTI)

This report documents a research project to scope and implement an initiative to catalyze the early market deployment of a utility-scale electric energy storage system, a project that leverages Lithium-ion (Li-ion) battery technology being globally scaled to serve emerging electric and hybrid electric vehicle markets. The impressive scale of Li-ion battery production and R&D is driving a trend in cost reduction and performance improvements that make this technology attractive for certain grid storage app...

2012-07-31T23:59:59.000Z

70

Design of composite polymer electrolytes for Li ion batteries based on mechanical stability criteria  

Science Conference Proceedings (OSTI)

Mechanical properties and conductivity were computed for several composite polymer electrolyte structures. A multi-phase effective medium approach was used to estimate effective conductivity. The Mori-Tanaka approach was applied for calculating the effective stiffness tensor of the composites. An analysis of effective mechanical properties was performed in order to identify the composite structures, which would be capable of blocking the dendrites forming in Li-ion battery when Li metal is used as anode. The data on conductivity, elastic modulus, and Poisson s ratio can be used to formulate design criteria for solid electrolytes that would exhibit appropriate stiffness and compressibility to suppress lithium dendrite growth while maintaining high effective conductivities.

Kalnaus, Sergiy [ORNL; Sabau, Adrian S [ORNL; Tenhaeff, Wyatt E [ORNL; Daniel, Claus [ORNL; Dudney, Nancy J [ORNL

2012-01-01T23:59:59.000Z

71

Investigation of induced fission of natPb by accelerated 7Li ions  

E-Print Network (OSTI)

The cross-section of the natPb binary fission, induced by 7Li ions at 245 MeV energy, was measured and the fission product cross-sections studied by means of activation analysis in the off-line regimen. The analysis of charge and mass distributions of fission products allows to calculate the fission cross-section. The recoil technique ("thick target- thick catcher"), based on the two step model mathematical formalism, is used for the determination of the kinematical characteristics of reaction products. The data concerning transferred linear momentum provides information on the initial projectile-target interaction, and is compared to measurements of the proton-induced fission.

N. A. Demekhina; G. S. Karapetyan; V. Guimaraes

2013-02-02T23:59:59.000Z

72

A Combustion Chemistry Analysis of Carbonate Solvents in Li-Ion Batteries  

DOE Green Energy (OSTI)

Under abusive conditions Li-ion batteries can rupture, ejecting electrolyte and other flammable gases. In this paper we consider some of the thermochemical properties of these gases that will determine whether they ignite and how energetically they burn. We show that flames of carbonate solvents are fundamentally less energetic than those of conventional hydrocarbons. An example of this difference is given using a recently developed mechanism for dimethyl carbonate (DMC) combustion, where we show that a diffusion flame burning DMC has only half the peak energy release rate of an analogous propane flame. We find a significant variation among the carbonate solvents in the factors that are important to determining flammability, such as combustion enthalpy and vaporization enthalpy. This result suggests that thermochemical and kinetic factors might well be considered when choosing solvent mixtures.

Harris, S J; Timmons, A; Pitz, W J

2008-11-13T23:59:59.000Z

73

Modeling of species and charge transport in Li-Ion batteries based on non-equilibrium thermodynamics  

Science Conference Proceedings (OSTI)

In order to improve the design of Li ion batteries the complex interplay of various physical phenomena in the active particles of the electrodes and in the electrolyte has to be balanced. The separate transport phenomena in the electrolyte and in the ...

Arnulf Latz; Jochen Zausch; Oleg Iliev

2010-08-01T23:59:59.000Z

74

Selected test results from the LiFeBatt iron phosphate Li-ion battery.  

DOE Green Energy (OSTI)

In this paper the performance of the LiFeBatt Li-ion cell was measured using a number of tests including capacity measurements, capacity as a function of temperature, ohmic resistance, spectral impedance, high power partial state of charge (PSOC) pulsed cycling, pulse power measurements, and an over-charge/voltage abuse test. The goal of this work was to evaluate the performance of the iron phosphate Li-ion battery technology for utility applications requiring frequent charges and discharges, such as voltage support, frequency regulation, and wind farm energy smoothing. Test results have indicated that the LiFeBatt battery technology can function up to a 10C{sub 1} discharge rate with minimal energy loss compared to the 1 h discharge rate (1C). The utility PSOC cycle test at up to the 4C{sub 1} pulse rate completed 8,394 PSOC pulsed cycles with a gradual loss in capacity of 10 to 15% depending on how the capacity loss is calculated. The majority of the capacity loss occurred during the initial 2,000 cycles, so it is projected that the LiFeBatt should PSOC cycle well beyond 8,394 cycles with less than 20% capacity loss. The DC ohmic resistance and AC spectral impedance measurements also indicate that there were only very small changes after cycling. Finally, at a 1C charge rate, the over charge/voltage abuse test resulted in the cell venting electrolyte at 110 C after 30 minutes and then open-circuiting at 120 C with no sparks, fire, or voltage across the cell.

Ingersoll, David T.; Hund, Thomas D.

2008-09-01T23:59:59.000Z

75

A New Type of Steady and Stable, Laminar, Premixed Flame in Ultra-Lean, Hydrogen-Air Combustion  

Science Conference Proceedings (OSTI)

Ultra-lean, hydrogen-air mixtures are found to support another kind of laminar flame that is steady and stable beside flat flames and flame balls. Direct numerical simulations are performed of flames that develop into steadily and stably propagating cells. These cells were the original meaning of the word"flamelet'' when they were observed in lean flammability studies conducted early in the development of combustion science. Several aspects of these two-dimensional flame cells are identified and are contrasted with the properties of one-dimensional flame balls and flat flames. Although lean hydrogen-air flames are subject to thermo-diffusive effects, in this case the result is to stabilize the flame rather than to render it unstable. The flame cells may be useful as basic components of engineering models for premixed combustion when the other types of idealized flames are inapplicable.

Grcar, Joseph F; Grcar, Joseph F

2008-06-30T23:59:59.000Z

76

ESS 2012 Peer Review - Organic and Inorganic Solid Electrolytes for Li-ion Batteries - Nader Hagh, NEI Corporation  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Organic and Inorganic Solid Electrolytes for Li-ion Batteries Organic and Inorganic Solid Electrolytes for Li-ion Batteries Background & Objectives * Lithium ion batteries widely used in consumer applications Solvent leakage and flammability of conventional liquid electrolytes * Current solid state electrolytes suffer from low ionic conductivity, inferior rate capability, and interfacial instability * Objective of the program is to develop solid state organic and inorganic electrolyte that has enhanced ionic conductivity * PEO based polymer electrolyte has poor room ionic conductivity due to crystallinity * The current program develops a PEO based hybrid copolymer that disrupts crystallization and at the same time provides mechanical integrity Abstract: The use of a solid polymer electrolyte instead of the conventional liquid or gel electrolyte can drastically improve the safety

77

Understanding Li-ion battery processes at the atomic to nano-scale.  

Science Conference Proceedings (OSTI)

Reducing battery materials to nano-scale dimensions may improve battery performance while maintaining the use of low-cost materials. However, we need better characterization tools with atomic to nano-scale resolution in order to understand degradation mechanisms and the structural and mechanical changes that occur in these new materials during battery cycling. To meet this need, we have developed a micro-electromechanical systems (MEMS)-based platform for performing electrochemical measurements using volatile electrolytes inside a transmission electron microscope (TEM). This platform uses flip-chip assembly with special alignment features and multiple buried electrode configurations. In addition to this platform, we have developed an unsealed platform that permits in situ TEM electrochemistry using ionic liquid electrolytes. As a test of these platform concepts, we have assembled MnO{sub 2} nanowires on to the platform using dielectrophoresis and have examined their electrical and structural changes as a function of lithiation. These results reveal a large irreversible drop in electronic conductance and the creation of a high degree of lattice disorder following lithiation of the nanowires. From these initial results, we conclude that the future full development of in situ TEM characterization tools will enable important mechanistic understanding of Li-ion battery materials.

Zhan, Yongjie (Rice University, Houston, TX); Subramanian, Arunkumar; Hudak, Nicholas; Sullivan, John Patrick; Shaw, Michael J.; Huang, Jian Yu

2010-05-01T23:59:59.000Z

78

Na and Li ion diffusion in modified ASTM C 1260 test by Magnetic Resonance Imaging (MRI)  

SciTech Connect

In the current study, MRI was applied to investigate lithium and sodium ion diffusion in cement paste and mortars containing inert sand and borosilicate glass. Paste and mortars were treated by complying with ASTM C 1260. Lithium and sodium distribution profiles were collected at different ages after different treatments. Results revealed that sodium ions had a greater diffusion rate than lithium ions, suggesting that Na reaches the aggregate particle surface before Li. Results also showed that Na and Li ions had a competitive diffusion process in mortars; soaking in a solution with higher [Li] favored Li diffusion but hindered Na diffusion. In mortars containing glass, a substantial amount of Li was consumed by the formation of ASR products. When [Li] in soaking solution was reduced to 0.37 N, a distinctive Na distribution profile was observed, indicating the free-state Na ions were continuously transformed to solid reaction products by ASR. Hence, in the modified ASTM C 1260 test, [Li] in the storage solution should be controlled at 0.74 N, in order to completely prevent the consumption of Na ions and thus stop ASR.

Feng, X. [Department of Civil Engineering, University of New Brunswick, Fredericton, NB (Canada)], E-mail: XFeng@ctlgroup.com; Balcom, B.J. [MRI Center, Department of Physics, University of New Brunswick, Fredericton, NB (Canada); Thomas, M.D.A.; Bremner, T.W. [Department of Civil Engineering, University of New Brunswick, Fredericton, NB (Canada)

2008-12-15T23:59:59.000Z

79

Electrical Characteristics of 18650 Li-Ion Cells at Low Temperatures  

DOE Green Energy (OSTI)

Low temperature electrical performance characteristics of A and T, Moli, and Panasonic 18650 Li-ion cells are described. Ragone plots of energy and power data of the cells for different temperatures from 25 C to {minus}40 C are compared. Although the electrical performance of these cells at and around room temperature is respectable, at temperatures below 0 C the performance is poor. For example, the delivered power and energy densities of the Panasonic cells at 25 C are {approximately}800 W/l and {approximately}100 Wh/l respectively and those at {minus}40 C are <10 W/l and {approximately}5 Wh/l. In order to identify the source for this poor performance at subambient temperatures, both 2- and 3-electrode impedance studies were made on these cells. The 2-electrode impedance data suggests that the cell ohmic resistance remains nearly constant from 25 C to {minus}20 C but increases modestly at {minus}40 C while the overall cell impedance increases by an order of magnitude over the same temperature range. The 3-electrode impedance data of the A and T cells show that the increase in cell resistance comes mostly from the cathode electrolyte interface and very little either from the anode electrolyte interface or from the ohmic resistance of the cell. This suggests that the poor performance of the cells comes mainly from the high cathode/electrolyte interfacial impedance.

Nagasubramanian, Ganesan

1999-08-05T23:59:59.000Z

80

Electrostatic energy harvester and Li-Ion charger circuit for microscale applications  

E-Print Network (OSTI)

Abstract—Modern portable micro-systems like biomedical implants and ad-hoc wireless transceiver micro-sensors continue to integrate more functions into smaller devices, which result in low energy levels and short operational lives. Researchers and industry alike are consequently considering harvesting energy from the surrounding environment as a means of offsetting this energy deficit. Even with power efficient designs, low duty-cycle operation, smart power-aware network architectures, and batteries with improved energy density, the stored energy in micro-scale systems is simply not sufficient to sustain extended lifetimes. Fortunately, the surrounding environment is a rich source of energy, from solar and thermal to kinetic, but harnessing it without dissipating much power in the process is challenging. In this paper, an electrostatic vibrational energy harvester circuit is proposed and evaluated. It harnesses energy from inherent vibrations in the system (e.g., engine-powered applications) by modulating the parallelplate distance of a variable capacitor and channeling the resulting change in charge into a secondary Li-Ion micro-battery. The varactor, in essence, behaves like a vibration-dependent current source. Simulations show that a 100-to-1 pF variable plate capacitor subjected to vibrations with a period of 15 µs produces an average harvesting current of 40.8 µA, an energy gain of 569 pJ per cycle, and a net average power gain of 38 µW.

Erick O. Torres; Student Member; Gabriel A. Rincón-mora; Senior Member

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
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81

The effects of silicon doping on the performance of PMAN carbon anodes in Li-ion cells  

DOE Green Energy (OSTI)

Carbons derived from polymethylacrylonitrile (PMAN) have been studied for use as intercalation anodes in Li-ion cells. The effect of Si doping upon the electrochemical performance of PMAN carbons was studied using tetravinylsilane (TVS) and tetramethysilane (TMS) as sources of Si during the formation of the PMAN precursors. The carbons were characterized by galvanostatic cycling, cyclic voltammetry, and complex impedance. The presence of 9 to 11 w/o Si in the PMAN lattice greatly increased the irreversible capacity of these materials.

Guidotti, R.A.; Johnson, B.J. [Sandia National Labs., Albuquerque, NM (United States); Even, W. Jr. [Sandia National Labs., Livermore, CA (United States)

1996-05-01T23:59:59.000Z

82

A numerical study of steady-state vortex configurations and vortex pinning in type-II superconductors  

E-Print Network (OSTI)

In part I, a numerical study of the mixed states in a mesoscopic type-II superconducting cylinder is described. Steady-state configurations and transient behavior of the magnetic vortices for various values of the applied magnetic field H are presented. Transitions between different multi-vortex states as H is changed is demonstrated by abrupt changes in vortex configurations and jumps in the B vs H plot. An efficient scheme to determine the equilibrium vortex configuration in a mesoscopic system at any given applied field, not limited to the symmetry of the system, is devised and demonstrated. In part II, a superconducting thin film is subject to a non-uniform magnetic field from a vertical magnetic dipole, consisting of two magnetic monopoles of opposite charges. For a film with constant thickness and with no pins, it has been found that the film carries two pairs of vortex-antivortex in the steady state in the imposed flux range of 2.15 < (Phi)+ < 2.90 (in units of flux quantum) and no vortex at all for (Phi)+ <= 2.15. Transitions from a superconducting state with 3 pairs of vortex-antivortex to one with 2 pairs, where a pair of vortex-antivortex annihilates, have been observed in the pseudo-time sequence. With a perturbation with antidots (holes), vortexantivortex pair has been created for lower magnetic fluxes down to (Phi)+ = 1.3. In the sample of size 16(Xi) x 16(Xi), the attraction force between the vortex and antivortex always dominates over the pinning force, so that they eventually come out of pins, move toward each other, and annihilate each other. The annihilation rate, measured with time taken for the annihilation, is reduced noticeably by the increase of the distance between pins, or the increase in the pin size. A simulation of the magnetic vortex pinning in the sample of size 32(Xi) x 32(Xi) suggests we are likely to achieve pinning of the vortex-antivortex pair with the sample size around this and vortex-antivortex separation of 22(Xi). Using this sample as a template, the maximum density of pinned vortices achievable is calculates to be about 7.6 x 10^14 vortices/m2 for (Xi) =~ 1.6A°.

Kim, Sangbum

2004-12-01T23:59:59.000Z

83

Composit, Nanoparticle-Based Anode material for Li-ion Batteries Applied in Hybrid Electric (HEV's)  

DOE Green Energy (OSTI)

Lithium-ion batteries are promising energy storage devices in hybrid and electric vehicles with high specific energy values ({approx}150 Wh/kg), energy density ({approx}400 Wh/L), and long cycle life (>15 years). However, applications in hybrid and electric vehicles require increased energy density and improved low-temperature (<-10 C) performance. Silicon-based anodes are inexpensive, environmentally benign, and offer excellent theoretical capacity values ({approx}4000 mAh/g), leading to significantly less anode material and thus increasing the overall energy density value for the complete battery (>500 Wh/L). However, tremendous volume changes occur during cycling of pure silicon-based anodes. The expansion and contraction of these silicon particles causes them to fracture and lose electrical contact to the current collector ultimately severely limiting their cycle life. In Phase I of this project Yardney Technical Products, Inc. proposed development of a carbon/nano-silicon composite anode material with improved energy density and silicon's cycleability. In the carbon/nano-Si composite, silicon nanoparticles were embedded in a partially-graphitized carbonaceous matrix. The cycle life of anode material would be extended by decreasing the average particle size of active material (silicon) and by encapsulation of silicon nanoparticles in a ductile carbonaceous matrix. Decreasing the average particle size to a nano-region would also shorten Li-ion diffusion path and thus improve rate capability of the silicon-based anodes. Improved chemical inertness towards PC-based, low-temperature electrolytes was expected as an additional benefit of a thin, partially graphitized coating around the active electrode material.

Dr. Malgorzata Gulbinska

2009-08-24T23:59:59.000Z

84

ALD of Al2O3 for Highly Improved Performance in Li-Ion Batteries  

Science Conference Proceedings (OSTI)

Significant advances in energy density, rate capability and safety will be required for the implementation of Li-ion batteries in next generation electric vehicles. We have demonstrated atomic layer deposition (ALD) as a promising method to enable superior cycling performance for a vast variety of battery electrodes. The electrodes range from already demonstrated commercial technologies (cycled under extreme conditions) to new materials that could eventually lead to batteries with higher energy densities. For example, an Al2O3 ALD coating with a thickness of ~ 8 A was able to stabilize the cycling of unexplored MoO3 nanoparticle anodes with a high volume expansion. The ALD coating enabled stable cycling at C/2 with a capacity of ~ 900 mAh/g. Furthermore, rate capability studies showed the ALD-coated electrode maintained a capacity of 600 mAh/g at 5C. For uncoated electrodes it was only possible to observe stable cycling at C/10. Also, we recently reported that a thin ALD Al2O3 coating with a thickness of ~5 A can enable natural graphite (NG) electrodes to exhibit remarkably durable cycling at 50 degrees C. The ALD-coated NG electrodes displayed a 98% capacity retention after 200 charge-discharge cycles. In contrast, bare NG showed a rapid decay. Additionally, Al2O3 ALD films with a thickness of 2 to 4 A have been shown to allow LiCoO2 to exhibit 89% capacity retention after 120 charge-discharge cycles performed up to 4.5 V vs Li/Li+. Bare LiCoO2 rapidly deteriorated in the first few cycles. The capacity fade is likely caused by oxidative decomposition of the electrolyte at higher potentials or perhaps cobalt dissolution. Interestingly, we have recently fabricated full cells of NG and LiCoO2 where we coated both electrodes, one or the other electrode as well as neither electrode. In creating these full cells, we observed some surprising results that lead us to obtain a greater understanding of the ALD coatings. We have also recently coated a binder free LiNi0.04Mn0.04Co02O2 electrode containing 5 wt% single-walled carbon nanotubes as the conductive additive and demonstrated both high rate capability as well as the ability to cycle the cathode to 5 V vrs. Li/Li+. Finally, we coated a Celgard (TM) separator and enabled stable cycling in a high dielectric electrolyte. These results will be presented in detail.

Dillon, A.; Jung, Y. S.; Ban, C.; Riley, L.; Cavanagh, A.; Yan, Y.; George, S.; Lee, S. H.

2012-01-01T23:59:59.000Z

85

High Rate and High Capacity Li-Ion Electrodes for Vehicular Applications  

Science Conference Proceedings (OSTI)

Significant advances in both energy density and rate capability for Li-ion batteries are necessary for implementation in electric vehicles. We have employed two different methods to improve the rate capability of high capacity electrodes. For example, we previously demonstrated that thin film high volume expansion MoO{sub 3} nanoparticle electrodes ({approx}2 {micro}m thick) have a stable capacity of {approx}630 mAh/g, at C/2 (charge/dicharge in 2 hours). By fabricating thicker conventional electrodes, an improved reversible capacity of {approx}1000 mAh/g is achieved, but the rate capability decreases. To achieve high-rate capability, we applied a thin Al{sub 2}O{sub 3} atomic layer deposition coating to enable the high volume expansion and prevent mechanical degradation. Also, we recently reported that a thin ALD Al{sub 2}O{sub 3} coating can enable natural graphite (NG) electrodes to exhibit remarkably durable cycling at 50 C. Additionally, Al{sub 2}O{sub 3} ALD films with a thickness of 2 to 4 {angstrom} have been shown to allow LiCoO{sub 2} to exhibit 89% capacity retention after 120 charge-discharge cycles performed up to 4.5 V vs. Li/Li{sup +}. Capacity fade at this high voltage is generally caused by oxidative decomposition of the electrolyte or cobalt dissolution. We have recently fabricated full cells of NG and LiCoO{sub 2} and coated both electrodes, one or the other electrode as well as neither electrode. In creating these full cells, we observed some surprising results that lead us to obtain a greater understanding of the ALD coatings. In a different approach we have employed carbon single-wall nanotubes (SWNTs) to synthesize binder-free, high-rate capability electrodes, with 95 wt.% active materials. In one case, Fe{sub 3}O{sub 4} nanorods are employed as the active storage anode material. Recently, we have also employed this method to demonstrate improved conductivity and highly improved rate capability for a LiNi{sub 0.4}Mn{sub 0.4}Co{sub 0.2}O{sub 2} cathode material. Raman spectroscopy was employed to understand how the SWNTs function as a highly flexible conductive additive.

Dillon, A. C.

2012-01-01T23:59:59.000Z

86

Effect of entropy of lithium intercalation in cathodes and anodes on Li-ion battery thermal management  

Science Conference Proceedings (OSTI)

The entropy changes (?S) in various cathode and anode materials, as well as complete Li-ion batteries, were measured using an electrochemical thermodynamic measurement system (ETMS). LiCoO2 has a much larger entropy change than electrodes based on LiNixCoyMnzO2 and LiFePO4, while lithium titanate based anode has lower entropy change compared to graphite anodes. Reversible heat generation rate was found to be a significant portion of the total heat generation rate. The appropriate combinations of cathode and anode were investigated to minimize reversible heat.

Viswanathan, Vilayanur V.; Choi, Daiwon; Wang, Donghai; Xu, Wu; Towne, Silas A.; Williford, Ralph E.; Zhang, Jiguang; Liu, Jun; Yang, Zhenguo

2010-06-01T23:59:59.000Z

87

Oxidation Potentials of Functionalized Sulfone Solvents for High-Voltage Li-Ion Batteries: A Computational Study  

Science Conference Proceedings (OSTI)

New electrolytes with large electrochemical windows are needed to meet the challenge for high-voltage Li-ion batteries. Sulfone as an electrolyte solvent boasts of high oxidation potentials. Here we examine the effect of multiple functionalization on sulfone's oxidation potential. We compute oxidation potentials for a series of sulfone-based molecules functionalized with fluorine, cyano, ester, and carbonate groups by using a quantum chemistry method within a continuum solvation model. We find that multifunctionalization is a key to achieving high oxidation potentials. This can be realized through either a fluorether group on a sulfone molecule or sulfonyl fluoride with a cyano or ester group.

Shao, Nan [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL; Jiang, Deen [ORNL

2012-01-01T23:59:59.000Z

88

Battery-level material cost model facilitates high-power li-ion battery cost reductions.  

SciTech Connect

Under the FreedomCAR Partnership, Argonne National Laboratory (ANL) is working to identify and develop advanced anode, cathode, and electrolyte components that can significantly reduce the cost of the cell chemistry, while simultaneously enhancing the calendar life and inherent safety of high-power Li-Ion batteries. Material cost savings are quantified and tracked via the use of a cell and battery design model that establishes the quantity of each material needed in batteries designed to meet the requirements of hybrid electric vehicles (HEVs). In order to quantify the material costs, relative to the FreedomCAR battery cost goals, ANL uses (1) laboratory cell performance data, (2) its battery design model and (3) battery manufacturing process yields to create battery-level material cost models. Using these models and industry-supplied material cost information, ANL assigns battery-level material costs for different cell chemistries. These costs can then be compared to the battery cost goals to determine the probability of meeting the goals with these cell chemistries. The most recent freedomCAR cost goals for 25-kW and 40-kW power-assist HEV batteries are $500 and $800, respectively, which is $20/kW in both cases. In 2001, ANL developed a high-power cell chemistry that was incorporated into high-power 18650 cells for use in extensive accelerated aging and thermal abuse characterization studies. This cell chemistry serves as a baseline for this material cost study. It incorporates a LiNi0.8Co0.15Al0.05O2 cathode, a synthetic graphite anode, and a LiPF6 in EC:EMC electrolyte. Based on volume production cost estimates for these materials-as well as those for binders/solvents, cathode conductive additives, separator, and current collectors--the total cell winding material cost for a 25-kW power-assist HEV battery is estimated to be $399 (based on a 48- cell battery design, each cell having a capacity of 15.4 Ah). This corresponds to {approx}$16/kW. Our goal is to reduce the cell winding material cost to <$10/kW, in order to allow >$10/kW for the cell and battery manufacturing costs, as well as profit for the industrial manufacturer. The material cost information is obtained directly from the industrial material suppliers, based on supplying the material quantities necessary to support an introductory market of 100,000 HEV batteries/year. Using its battery design model, ANL provides the material suppliers with estimates of the material quantities needed to meet this market, for both 25-kW and 40-kW power-assist HEV batteries. Also, ANL has funded a few volume-production material cost analyses, with industrial material suppliers, to obtain needed cost information. In a related project, ANL evaluates and develops low-cost advanced materials for use in high-power Li-Ion HEV batteries. [This work is the subject of one or more separate papers at this conference.] Cell chemistries are developed from the most promising low-cost materials. The performance characteristics of test cells that employ these cell chemistries are used as input to the cost model. Batteries, employing these cell chemistries, are designed to meet the FreedomCAR power, energy, weight, and volume requirements. The cost model then provides a battery-level material cost and material cost breakdown for each battery design. Two of these advanced cell chemistries show promise for significantly reducing the battery-level material costs (see Table 1), as well as enhancing calendar life and inherent safety. It is projected that these two advanced cell chemistries (A and B) could reduce the battery-level material costs by an estimated 24% and 43%, respectively. An additional cost advantage is realized with advanced chemistry B, due to the high rate capability of the 3-dimensional LiMn{sub 2}O{sub 4} spinel cathode. This means that a greater percentage of the total Ah capacity of the cell is usable and cells with reduced Ah capacity can be used. This allows for a reduction in the quantity of the anode, electrolyte, separator, and current collector materials needed f

Henriksen, G.; Chemical Engineering

2003-01-01T23:59:59.000Z

89

Thermal Stability of LiPF6 Salt and Li-ion Battery ElectrolytesContaining LiPF6  

DOE Green Energy (OSTI)

The thermal stability of the neat LiPF6 salt and of 1 molal solutions of LiPF6 in prototypical Li-ion battery solvents was studied with thermogravimetric analysis (TGA) and on-line FTIR. Pure LiPF6 salt is thermally stable up to 380 K in a dry inert atmosphere, and its decomposition path is a simple dissociation producing LiF as solid and PF5 as gaseous products. In the presence of water (300 ppm) in the carrier gas, its decomposition onset temperature is lowered as a result of direct thermal reaction between LiPF6 and water vapor to form POF3 and HF. No new products were observed in 1 molal solutions of LiPF6 in EC, DMC and EMC by on-line TGA-FTIR analysis. The storage of the same solutions in sealed containers at 358 K for 300 420 hrs. did not produce any significant quantity of new products as well. In particular, noalkylflurophosphates were found in the solutions after storage at elevated temperature. In the absence of either an impurity like alcohol or cathode active material that may (or may not) act as a catalyst, there is no evidence of thermally induced reaction between LiPF6 and the prototypical Li-ion battery solvents EC, PC, DMC or EMC.

Yang, Hui; Zhuang, Guorong V.; Ross Jr., Philip N.

2006-03-08T23:59:59.000Z

90

Li-Ion Batteries from LiFePO4 Cathode and Anatase/Graphene Composite Anode for Stationary Energy Storage  

SciTech Connect

Li-ion batteries based on LiFePO4 cathode and anatase TiO2/graphene anode were investigated for possible stationary energy storage application. Fine-structured LiFePO4 was synthesized by novel molten surfactant approach. Anatase TiO2/graphene nanocomposite was prepared via self assembly method. The full cell that operated at flat 1.6V demonstrated negligible fade after more than 700 cycles. The LiFePO4/TiO2 combination Li-ion battery is inexpensive, environmentally benign, safe and stable. Therefore, it can be practically applied as stationary energy storage for renewable power sources.

Choi, Daiwon; Wang, Donghai; Viswanathan, Vilayanur V.; Bae, In-Tae; Wang, Wei; Nie, Zimin; Zhang, Jiguang; Graff, Gordon L.; Liu, Jun; Yang, Zhenguo; Duong, Tien Q.

2009-11-06T23:59:59.000Z

91

A study of lithium ion intercalation induced fracture of silicon particles used as anode material in Li-ion battery  

Science Conference Proceedings (OSTI)

The fracture of Si particles due to internal stresses formed during the intercalation of lithium ions was described by means of thermal analogy model and brittle fracture damage parameter. The stresses were calculated following the diffusion equation and equations of elasticity with appropriate volumetric expansion term. The damage parameter takes into account triaxiality of the stress state and change in elasticity upon tension and compression, and represents the probability of fracture under given stress state, - an approach suitable for brittle materials. The results were compared with the acoustic emission data from the experiments on electrochemical cycling of Li ion half-cells with silicon electrodes. A good correlation between experiment and prediction was observed.

Daniel, Claus [ORNL; Kalnaus, Sergiy [ORNL; Rhodes, Kevin [University of Tennessee, Knoxville (UTK)

2011-01-01T23:59:59.000Z

92

In situ XRD Studies of Li-ion Cells with Mixed LiMn2O4 and LiCo1/3Ni1/3Mn1/3O2 Composite Cathode  

Science Conference Proceedings (OSTI)

The structural changes of the composite cathode made by mixing spinel LiMn2O4 and layered LiNi1/3Co1/3Mn1/3O2 in 1:1 wt% in both Li-half and Li-ion cells during charge/discharge are studied by in situ XRD. During the first charge up to {approx}5.2 V vs. Li/Li+, the in situ XRD spectra for the composite cathode in the Li-half cell track the structural changes of each component. At the early stage of charge, the lithium extraction takes place in the LiNi1/3Co1/3Mn1/3O2 component only. When the cell voltage reaches at {approx}4.0 V vs. Li/Li+, lithium extraction from the spinel LiMn2O4 component starts and becomes the major contributor for the cell capacity due to the higher rate capability of LiMn2O4. When the voltage passed 4.3 V, the major structural changes are from the LiNi1/3Co1/3Mn1/3O2 component, while the LiMn2O4 component is almost unchanged. In the Li-ion cell using a MCMB anode and a composite cathode cycled between 2.5 V and 4.2 V, the structural changes are dominated by the spinel LiMn2O4 component, with much less changes in the layered LiNi1/3Co1/3Mn1/3O2 component, comparing with the Li-half cell results. These results give us valuable information about the structural changes relating to the contributions of each individual component to the cell capacity at certain charge/discharge state, which are helpful in designing and optimizing the composite cathode using spinel- and layered-type materials for Li-ion battery research.

Nam, K.; Yoon, W; Shin, H; Chung, K; Choi, S; Yang, X

2009-01-01T23:59:59.000Z

93

Second-Use Li-Ion Batteries to Aid Automotive and Utility Industries (Fact Sheet), NREL Highlights in Research & Development, NREL (National Renewable Energy Laboratory)  

NLE Websites -- All DOE Office Websites (Extended Search)

Repurposing lithium-ion batteries at the end of useful life Repurposing lithium-ion batteries at the end of useful life in electric drive vehicles could eliminate owners' disposal concerns and offer low-cost energy storage for certain applications. Increasing the number of plug-in electric drive vehicles (PEVs) is one major strategy for reduc- ing the nation's oil imports and greenhouse gas emissions. However, the high up-front cost and end-of-service disposal concerns of their lithium-ion (Li-ion) batteries could impede the proliferation of such vehicles. Re-using Li-ion batteries after their useful automotive life has been proposed as a way to remedy both matters. In response, the National Renewable Energy Laboratory (NREL) and its partners are conducting research to identify, assess, and verify profitable

94

Li-Ion Battery with LiFePO4 Cathode and Li4Ti5O12 Anode for Stationary Energy Storage  

Science Conference Proceedings (OSTI)

i-ion batteries based on commercially available LiFePO4 cathode and Li4Ti5O12 anode were investigated for potential stationary energy storage applications. The full cell that operated at flat 1.85V demonstrated stable cycling for 200 cycles followed by a rapid fade. A significant improvement in cycling stability was achieved via Ketjen black coating of the cathode. A Li-ion full cell with Ketjen black modified LiFePO4 cathode and an unmodified Li4Ti5O12 anode exhibited negligible fade after more than 1200 cycles with a capacity of ~130mAh/g. The improved stability, along with its cost-effectiveness, environmentally benignity and safety, make the LiFePO4/ Li4Ti5O12 Li-ion battery a promising option of storing renewable energy.

Wang, Wei; Choi, Daiwon; Yang, Zhenguo

2013-01-01T23:59:59.000Z

95

Sn/SnOx Core-Shell Nanospheres: Synthesis, Anode Performance in Li Ion Batteries, and Superconductivity  

Science Conference Proceedings (OSTI)

Sn/SnO{sub x} core?shell nanospheres have been synthesized via a modified polyol process. Their size can be readily controlled by tuning the usage of surface stabilizers and the temperature. Anode performance in Li ion batteries and their superconducting properties is detailed. As anode materials, 45 nm nanospheres outperform both larger and smaller ones. Thus, they exhibit a capacity of about 3443 mAh cm{sup -3} and retain about 88% of after 10 cycles. We propose a model based on the microstructural evolution to explain the size impact on nanosphere performance. Magnetic measurements indicate that the nanospheres become superconducting below the transition temperature T{sub C} = 3.7 K, which is similar to the value obtained in bulk tin. Although T{sub C} does not significantly change with the size of the Sn core, we determined that the critical field H{sub C} of nanospheres can be as much as a factor of 30 larger compared to the bulk value. Alternating current measurements demonstrated that a transition from conventional to filamentary superconducting structure occurs in Sn/SnO{sub x} particles as their size increases. The transition is determined by the relationship between the particle size and the magnetic field penetration depth.

Wang, X.L.; Feygenson, M.; Aronson, M.C.; Han, W.-Q.

2010-09-09T23:59:59.000Z

96

Improved performance of Li-ion cells under pulsed load using double-layer capacitors in a hybrid circuit mode  

DOE Green Energy (OSTI)

Electrical characteristics of hybrid power sources consisting of Li-ion cells and double-layer capacitors were studied at 25 C and {minus}20 C. The cells were initially evaluated for pulse performance and then measured in hybrid modes of operation where they were coupled with the high-power capacitors. Cells manufactured by Panasonic measured at 25 C delivered full capacities of 0.76 Ah for pulses up to 3A and cells from A and T delivered full capacities of 0.73 Ah for pulses up to 4A. Measured cell resistances were 0.15 ohms and 0.12 ohms, respectively. These measurements were repeated at {minus}20 C. Direct coupling of the cells and capacitors (coupled hybrid) using 10F Panasonic capacitors in a 8F series/parallel combination extended the full capacity pulse limits (3.0V threshold) to 5.6A for the Panasonic cells and to 9A for the A and T cells. A similar arrangement using 100F capacitors from Elna in a 60F combination increased the Panasonic cell limit to 10 A. Operation in an uncoupled hybrid mode using uncoupled cell/capacitor discharge allowed fill cell capacity usage at 25 C up to the capacitor discharge limit and showed a factor of 5 improvement in delivered capacity at {minus}20 C.

ROTH,EMANUEL P.; NAGASUBRAMANIAN,GANESAN

2000-02-07T23:59:59.000Z

97

Advanced technology development program for lithium-ion batteries : thermal abuse performance of 18650 Li-ion cells.  

SciTech Connect

Li-ion cells are being developed for high-power applications in hybrid electric vehicles currently being designed for the FreedomCAR (Freedom Cooperative Automotive Research) program. These cells offer superior performance in terms of power and energy density over current cell chemistries. Cells using this chemistry are the basis of battery systems for both gasoline and fuel cell based hybrids. However, the safety of these cells needs to be understood and improved for eventual widespread commercial application in hybrid electric vehicles. The thermal behavior of commercial and prototype cells has been measured under varying conditions of cell composition, age and state-of-charge (SOC). The thermal runaway behavior of full cells has been measured along with the thermal properties of the cell components. We have also measured gas generation and gas composition over the temperature range corresponding to the thermal runaway regime. These studies have allowed characterization of cell thermal abuse tolerance and an understanding of the mechanisms that result in cell thermal runaway.

Crafts, Chris C.; Doughty, Daniel Harvey; McBreen, James. (Bookhaven National Lab, Upton, NY); Roth, Emanuel Peter

2004-03-01T23:59:59.000Z

98

A Computational Investigation of Li(subscript 9)M(subscript 3)(P(subscript 2)O(subscript 7))(subscript 3)(PO(subscript 4))(subscript 2) (M = V, Mo) as Cathodes for Li Ion Batteries  

E-Print Network (OSTI)

Cathodes with high energy density and safety are sought to improve the performance of Li ion batteries for electric vehicle and consumer electronics applications. In this study, we examine the properties of the potential ...

Jain, Anubhav

99

Composit, Nanoparticle-Based Anode material for Li-ion Batteries Applied in Hybrid Electric (HEV's)  

SciTech Connect

Lithium-ion batteries are promising energy storage devices in hybrid and electric vehicles with high specific energy values ({approx}150 Wh/kg), energy density ({approx}400 Wh/L), and long cycle life (>15 years). However, applications in hybrid and electric vehicles require increased energy density and improved low-temperature (<-10 C) performance. Silicon-based anodes are inexpensive, environmentally benign, and offer excellent theoretical capacity values ({approx}4000 mAh/g), leading to significantly less anode material and thus increasing the overall energy density value for the complete battery (>500 Wh/L). However, tremendous volume changes occur during cycling of pure silicon-based anodes. The expansion and contraction of these silicon particles causes them to fracture and lose electrical contact to the current collector ultimately severely limiting their cycle life. In Phase I of this project Yardney Technical Products, Inc. proposed development of a carbon/nano-silicon composite anode material with improved energy density and silicon's cycleability. In the carbon/nano-Si composite, silicon nanoparticles were embedded in a partially-graphitized carbonaceous matrix. The cycle life of anode material would be extended by decreasing the average particle size of active material (silicon) and by encapsulation of silicon nanoparticles in a ductile carbonaceous matrix. Decreasing the average particle size to a nano-region would also shorten Li-ion diffusion path and thus improve rate capability of the silicon-based anodes. Improved chemical inertness towards PC-based, low-temperature electrolytes was expected as an additional benefit of a thin, partially graphitized coating around the active electrode material.

Dr. Malgorzata Gulbinska

2009-08-24T23:59:59.000Z

100

Reinvestigation on the state-of-the-art nonaqueous carbonate electrolytes for 5 V Li-ion battery applications  

SciTech Connect

The charging voltage limits of mixed carbonate solvents for Li-ion batteries have been systematically investigated from 4.9 to 5.3 V in half cells using Cr-doped spinel cathode material LiNi0.45Cr0.05Mn1.5O4. We found that the stability of conventional carbonate electrolytes is strongly related to the stability and properties of the cathode materials at both lithiated and de-lithiated states. It is the first time to report that the conventional electrolytes based on mixtures of ethylene carbonate (EC) and linear carbonate (dimethyl carbonate - DMC, ethyl methyl carbonate - EMC, and diethyl carbonate - DEC) have shown very similar long-term cycling performance when cycled up to 5.2 V on LiNi0.45Cr0.05Mn1.5O4. The discharge capacity increases with the charge cutoff voltage and reaches the highest discharge capacity at 5.2 V. The capacity retention is about 87% after 500 cycles at 1C rate for all three carbonate mixtures when cycled between 3.0 V and 5.2V. The first-cycle efficiency has a maximum value at 5.1 V, with an average from 83% to 85% at C/10 rate. When cycled to 5.3 V, EC-DMC still shows good cycling performance but EC-EMC and EC-DEC show faster capacity fading. EC-DMC and EC-EMC have much better rate capability than EC-DEC. In addition, the first-cycle irreversible capacity loss increases with the cutoff voltage and the 'inactive' conductive carbon has also been found to be partly associated with the low first-cycle Coulombic efficiency at high voltages due to electrolyte decomposition and probably the PF6- anion irreversible intercalation.

Xu, Wu; Chen, Xilin; Ding, Fei; Xiao, Jie; Wang, Deyu; Pan, Anqiang; Zheng, Jianming; Li, Xiaohong S.; Padmaperuma, Asanga B.; Zhang, Jiguang

2012-09-01T23:59:59.000Z

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101

Materials cost evaluation report for high-power Li-ion batteries.  

SciTech Connect

The U.S. Department of Energy (DOE) is the lead federal agency in the partnership between the U.S. automobile industry and the federal government to develop fuel cell electric vehicles (FCEVs) and hybrid electric vehicles (HEVs) as part of the FreedomCAR Partnership. DOE's FreedomCAR and Vehicle Technologies Office sponsors the Advanced Technology Development (ATD) Program--involving 5 of its national laboratories--to assist the industrial developers of high-power lithium-ion batteries to overcome the barriers of cost, calendar life, and abuse tolerance so that this technology can be rendered practical for use in HEV and FCEV applications under the FreedomCAR Partnership. In the area of cost reduction, Argonne National Laboratory (ANL) is working to identify and develop advanced anode, cathode, and electrolyte components that can significantly reduce the cost of the cell chemistry, while simultaneously extending the calendar life and enhancing the inherent safety of this electrochemical system. The material cost savings are quantified and tracked via the use of a cell and battery design model that establishes the quantity of each material needed in the production of batteries that are designed to meet the requirements of a minimum-power-assist HEV battery or a maximum-power-assist HEV battery for the FreedomCAR Partnership. Similar models will be developed for FEV batteries when the requirements for those batteries are finalized. In order to quantify the material costs relative to the FreedomCAR battery cost goals, ANL uses (1) laboratory cell performance data, (2) its battery design model and (3) battery manufacturing process yields to create battery-level material cost models. Using these models and industry-supplied material cost information, ANL assigns battery-level material costs for different cell chemistries. These costs can then be compared with the battery cost goals to determine the probability of meeting the goals with these cell chemistries. As can be seen from the results of this materials cost study, a cell chemistry based on the use of a LiMn{sub 2}O{sub 4} cathode material is lowest-cost and meets our battery-level material cost goal of <$250 for a 25-kW minimum-power-assist HEV battery. A major contributing factor is the high-rate capability of this material, which allows one to design a lower-capacity cell to meet the battery-level power and energy requirements. This reduces the quantities of the other materials needed to produce a 25-kW minimum-power-assist HEV battery. The same is true for the 40-kW maximum-power-assist HEV battery. Additionally, the LiMn{sub 2}O{sub 4} cathode is much more thermally and chemically stable than the LiNi{sub 0.8}Co{sub 0.2}O{sub 2} type cathode, which should enhance inherent safety and extend calendar life (if the LiMn{sub 2}O{sub 4} cathode can be stabilized against dissolution via HF attack). Therefore, we recommend that the FreedomCAR Partnership focus its research and development efforts on developing this type of low-cost high-power lithium-ion cell chemistry. Details supporting this recommendation are provided in the body of this report.

Henriksen, G. L.; Amine, K.; Liu, J.

2003-01-10T23:59:59.000Z

102

Materials cost evaluation report for high-power Li-ion batteries.  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy (DOE) is the lead federal agency in the partnership between the U.S. automobile industry and the federal government to develop fuel cell electric vehicles (FCEVs) and hybrid electric vehicles (HEVs) as part of the FreedomCAR Partnership. DOE's FreedomCAR and Vehicle Technologies Office sponsors the Advanced Technology Development (ATD) Program--involving 5 of its national laboratories--to assist the industrial developers of high-power lithium-ion batteries to overcome the barriers of cost, calendar life, and abuse tolerance so that this technology can be rendered practical for use in HEV and FCEV applications under the FreedomCAR Partnership. In the area of cost reduction, Argonne National Laboratory (ANL) is working to identify and develop advanced anode, cathode, and electrolyte components that can significantly reduce the cost of the cell chemistry, while simultaneously extending the calendar life and enhancing the inherent safety of this electrochemical system. The material cost savings are quantified and tracked via the use of a cell and battery design model that establishes the quantity of each material needed in the production of batteries that are designed to meet the requirements of a minimum-power-assist HEV battery or a maximum-power-assist HEV battery for the FreedomCAR Partnership. Similar models will be developed for FEV batteries when the requirements for those batteries are finalized. In order to quantify the material costs relative to the FreedomCAR battery cost goals, ANL uses (1) laboratory cell performance data, (2) its battery design model and (3) battery manufacturing process yields to create battery-level material cost models. Using these models and industry-supplied material cost information, ANL assigns battery-level material costs for different cell chemistries. These costs can then be compared with the battery cost goals to determine the probability of meeting the goals with these cell chemistries. As can be seen from the results of this materials cost study, a cell chemistry based on the use of a LiMn{sub 2}O{sub 4} cathode material is lowest-cost and meets our battery-level material cost goal of battery. A major contributing factor is the high-rate capability of this material, which allows one to design a lower-capacity cell to meet the battery-level power and energy requirements. This reduces the quantities of the other materials needed to produce a 25-kW minimum-power-assist HEV battery. The same is true for the 40-kW maximum-power-assist HEV battery. Additionally, the LiMn{sub 2}O{sub 4} cathode is much more thermally and chemically stable than the LiNi{sub 0.8}Co{sub 0.2}O{sub 2} type cathode, which should enhance inherent safety and extend calendar life (if the LiMn{sub 2}O{sub 4} cathode can be stabilized against dissolution via HF attack). Therefore, we recommend that the FreedomCAR Partnership focus its research and development efforts on developing this type of low-cost high-power lithium-ion cell chemistry. Details supporting this recommendation are provided in the body of this report.

Henriksen, G. L.; Amine, K.; Liu, J.

2003-01-10T23:59:59.000Z

103

Low-cost flexible packaging for high-power Li-Ion HEV batteries.  

DOE Green Energy (OSTI)

Batteries with various types of chemistries are typically sold in rigid hermetically sealed containers that, at the simplest level, must contain the electrolyte while keeping out the exterior atmosphere. However, such rigid containers can have limitations in packaging situations where the form of the battery is important, such as in hand-held electronics like personal digital assistants (PDAs), laptops, and cell phones. Other limitations exist as well. At least one of the electrode leads must be insulated from the metal can, which necessitates the inclusion of an insulated metal feed-through in the containment hardware. Another limitation may be in hardware and assembly cost, such as exists for the lithium-ion batteries that are being developed for use in electric vehicles (EVs) and hybrid electric vehicles (HEVs). The large size (typically 10-100 Ah) of these batteries usually results in electric beam or laser welding of the metal cap to the metal can. The non-aqueous electrolyte used in these batteries are usually based on flammable solvents and therefore require the incorporation of a safety rupture vent to relieve pressure in the event of overcharging or overheating. Both of these features add cost to the battery. Flexible packaging provides an alternative to the rigid container. A common example of this is the multi-layered laminates used in the food packaging industry, such as for vacuum-sealed coffee bags. However, flexible packaging for batteries does not come without concerns. One of the main concerns is the slow egress of the electrolyte solvent through the face of the inner laminate layer and at the sealant edge. Also, moisture and air could enter from the outside via the same method. These exchanges may be acceptable for brief periods of time, but for the long lifetimes required for batteries in electric/hybrid electric vehicles, batteries in remote locations, and those in satellites, these exchanges are unacceptable. Argonne National Laboratory (ANL), in collaboration with several industrial partners, is working on low-cost flexible packaging as an alternative to the packaging currently being used for lithium-ion batteries [1,2]. This program is funded by the FreedomCAR & Vehicle Technologies Office of the U.S. Department of Energy. (It was originally funded under the Partnership for a New Generation of Vehicles, or PNGV, Program, which had as one of its mandates to develop a power-assist hybrid electric vehicle with triple the fuel economy of a typical sedan.) The goal in this packaging effort is to reduce the cost associated with the packaging of each cell several-fold to less than $1 per cell ({approx} 50 cells are required per battery, 1 battery per vehicle), while maintaining the integrity of the cell contents for a 15-year lifetime. Even though the battery chemistry of main interest is the lithium-ion system, the methodology used to develop the most appropriate laminate structure will be very similar for other battery chemistries.

Jansen, A. N.; Amine, K.; Henriksen, G. L.

2004-06-18T23:59:59.000Z

104

Li-ion Batteries  

Science Conference Proceedings (OSTI)

Mar 12, 2012... are critical for the development of zero-emission electrical vehicles, large scale smart grid, and energy efficient cargo ships and locomotives.

105

Amorphous Hierarchical Porous GeOx as High-Capacity Anodes for LiIon Batteries with Very Long Cycling Life  

SciTech Connect

Many researchers have focused in recent years on resolving the crucial problem of capacity fading in Li ion batteries when carbon anodes are replaced by other group-IV elements (Si, Ge, Sn) with much higher capacities. Some progress was achieved by using different nanostructures (mainly carbon coatings), with which the cycle numbers reached 100-200. However, obtaining longer stability via a simple process remains challenging. Here we demonstrate that a nanostructure of amorphous hierarchical porous GeO{sub x} whose primary particles are {approx}3.7 nm diameter has a very stable capacity of {approx}1250 mA h g{sup -1} for 600 cycles. Furthermore, we show that a full cell coupled with a Li(NiCoMn){sub 1/3}O{sub 2} cathode exhibits high performance.

Wang, X.L.; Han, W.-Q.; Chen, H.; Bai, J.; Tyson, T.A.; Yu, X.-Q.; Wang, X.-J.; Yang, X.-Q.

2011-12-28T23:59:59.000Z

106

Li6La3SnMO12 (M = Sb, Nb, Ta), a Family of Lithium Garnets with High Li-Ion Conductivity  

Science Conference Proceedings (OSTI)

In order to investigate the influence of covalent bonding within the garnet framework on the conductivity of Li+ in the interstitial space, the Li+ conductivities in the family of Sn-based compounds Li6La3 SnMO12 (M = Sb, Nb, Ta) have been obtained and are compared with those of Li6La3ZrMO12. Refinement of the neutron diffraction pattern of Li6La3 SnNbO12shows that the interstitial tetrahedral sites (24d ) are about half-occupied and most of the Li in the interstitial bridging octahedral sites are displaced from the center position (48g ). The Sb-based compound has the largest lattice parameter while the Ta-based compound has the highest Li+-ion conductivity of 0.42 10 4 Scm 1.

Bridges, Craig A [ORNL; Goodenough, J. B. [University of Texas, Austin; Gupta, Dr Asha [University of Texas, Austin; Nakanishi, Masahiro [ORNL; Paranthaman, Mariappan Parans [ORNL; Sokolov, Alexei P [ORNL; Bi, Zhonghe [ORNL; Li, Yutao [University of Texas, Austin; Han, Jiantao [University of Texas, Austin; Dong, Youzhong [South China University of Technology, Guangzhou, PR China; Wang, Long [University of Texas, Austin; Xu, Maowen [University of Texas, Austin

2012-01-01T23:59:59.000Z

107

Steady-State and Transient Thermal Modeling of Oil-Immersed Bushing-type Current Transformers in Power Transformers and Circuit Brea kers  

Science Conference Proceedings (OSTI)

This report documents methods of calculating the thermal rating of bushing-type Current Transformers (CTs). Researchers compared mathematical models to experimental results and evaluated the limits on CT winding temperature experimentally.

2009-02-09T23:59:59.000Z

108

Self-Aligned Cu-Si Core-Shell Nanowire Array as a High-Performance Anode for Li-Ion Batteries  

SciTech Connect

Silicon nanowires (NWs) have been reported as a promising anode that demonstrated high capacity without pulverization during cycling, however, they present some technical issues that remain to be solved. The high aspect ratio of the NWs and their small contact areas with the current collector cause high electrical resistance, which results in inefficient electron transport. The nano-size interface between a NW and the substrate experiences high shear stress during lithiation, causing the wire to separate from the current collector. In addition, most reported methods for producing silicon NWs involve high-temperature processing and require catalysts that later become contaminants. This study developed a new self-aligned Cu-Si core-shell NW array using a low-temperature, catalyst-free process to address the issues described. The silicon shell is amorphous as synthesized and accommodates Li-ions without phase transformation. The copper core functions as a built-in current collector to provide very short (nm) electron transport pathways as well as backbone to improve mechanical strength. Initial electrochemical evaluation has demonstrated good capacity retention and high Coulombic efficiency for this new anode material in a half-cell configuration. No wire fracture or core-shell separation was observed after cycling. However, electrolyte decomposition products largely covered the top surface of the NW array, restricting electrolyte access and causing capacity reduction at high charging rates.

Qu, Jun [ORNL; Li, Huaqing [ORNL; Henry Jr, John James [ORNL; Martha, Surendra K [ORNL; Dudney, Nancy J [ORNL; Lance, Michael J [ORNL; Mahurin, Shannon Mark [ORNL; Besmann, Theodore M [ORNL; Dai, Sheng [ORNL

2012-01-01T23:59:59.000Z

109

First-Principles Study of Novel Conversion Reactions for High-Capacity Li-Ion Battery Anodes in the Li-Mg-B-N-H System  

DOE Green Energy (OSTI)

Anodes for Li-ion batteries are primarily carbon-based due to their low cost and long cycle life. However, improvements to the Li capacity of carbon anodes, LiC{sub 6} in particular, are necessary to obtain a larger energy density. State-of-the-art light-metal hydrides for hydrogen storage applications often contain Li and involve reactions requiring Li transport, and light-metal ionic hydrides are candidates for novel conversion materials. Given a set of known solid-state and gas-phase reactants, we have determined the phase diagram in the Li-Mg-B-N-H system in the grand canonical ensemble, as a function of lithium chemical potential. We present computational results for several new conversion reactions with capacities between 2400 and 4000 mAh g{sup -1} that are thermodynamically favorable and that do not involve gas evolution. We provide experimental evidence for the reaction pathway on delithiation for the compound Li{sub 4}BN{sub 3}H{sub 10}. While the predicted reactions involve multiple steps, the maximum volume increase for these materials on lithium insertion is significantly smaller than that for Si.

Mason, T.H.; Graetz, J.; Liu, X.; Hong, J.; Majzoub, E.H.

2011-07-28T23:59:59.000Z

110

Nanospheres of a New Intermetalic FeSn5 Phase: Synthesis Magnetic Properties and Anode Performance in Li-ion Batteries  

Science Conference Proceedings (OSTI)

We synthesized monodisperse nanospheres of an intermetallic FeSn{sub 5} phase via a nanocrystal-conversion protocol using preformed Sn nanospheres as templates. This tetragonal phase in P4/mcc space group, along with the defect structure Fe{sub 0.74}Sn{sub 5} of our nanospheres, has been resolved by synchrotron X-ray diffraction and Rietveld refinement. Importantly, FeSn{sub 5}, which is not yet established in the Fe-Sn phase diagram, exhibits a quasi-one dimensional crystal structure along the c-axis, thus leading to interesting anisotropic thermal expansion and magnetic properties. Magnetization measurements indicate that nanospheres are superparamagnetic above the blocking temperature T{sub B} = 300 K, which is associated with the higher magnetocrystalline anisotropy constant K = 3.33 kJ m{sup -3}. The combination of the magnetization measurements and first-principles density functional theory calculations reveals the canted antiferromagnetic nature with significant spin fluctuation in lattice a-b plane. The low Fe concentration also leads Fe{sub 0.74}Sn{sub 5} to enhanced capacity as an anode in Li ion batteries.

X Wang; M Feygenson; H Chen; C Lin; W Ku; J Bai; M Aronson; T Tyson; W Han

2011-12-31T23:59:59.000Z

111

A 3D Porous Architecture of Si/graphene Nanocomposite as High-performance Anode Materials for Li-ion Batteries  

SciTech Connect

A 3D porous architecture of Si/graphene nanocomposite has been rationally designed and constructed through a series of controlled chemical processes. In contrast to random mixture of Si nanoparticles and graphene nanosheets, the porous nanoarchitectured composite has superior electrochemical stability because the Si nanoparticles are firmly riveted on the graphene nanosheets through a thin SiO{sub x} layer. The 3D graphene network enhances electrical conductivity, and improves rate performance, demonstrating a superior rate capability over the 2D nanostructure. This 3D porous architecture can deliver a reversible capacity of {approx}900 mA h g{sup -1} with very little fading when the charge rates change from 100 mA g{sup -1} to 1 A g{sup -1}. Furthermore, the 3D nanoarchitechture of Si/graphene can be cycled at extremely high Li{sup +} extraction rates, such as 5 A g{sup -1} and 10 A g{sup -1}, for over than 100 times. Both the highly conductive graphene network and porous architecture are considered to contribute to the remarkable rate capability and cycling stability, thereby pointing to a new synthesis route to improving the electrochemical performances of the Si-based anode materials for advanced Li-ion batteries.

Xin X.; Zhu Y.; Zhou, X.; Wang, F.; Yao, X.; Xu, X.; Liu, Z.

2012-04-28T23:59:59.000Z

112

Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through Control of Site Disorder  

SciTech Connect

High voltage spinel LiNi0.5Mn1.5O4 is a very promising cathode material for lithium ion batteries that can be used to power hybrid electrical vehicles (HEVs). In an effort to maximize the performances of high voltage spinel, it is found that the presence of an appropriate amount of oxygen deficiency and/or Mn3+ is critical to accelerate the transport of Li+ ions within the crystalline structure. Through careful control of the cooling rates after high temperature calcination, LiNi0.5Mn1.5O4 spinels with different disordered phase and/or Mn3+ contents have been synthesized. It is revealed that during slow cooling process (<3oC/min), oxygen deficiency is reduced by the oxygen intake, thus residual Mn3+ amount is also decreased in spinels due to charge neutrality. The relative ratio of ordered/disordered phases in high voltage spinels are systematically investigated and finally correlated with Li+ transport phenomena in the lattice through electrochemical evaluation and in-situ XRD technique. LiNi0.5Mn1.5O4 with an appropriate amount of disordered phase or Mn3+ ions offers high rate capability (96 mAh g-1 at 10 C) and excellent cycling performance with 94.8% capacity retention after 300 cycles. The fundamental findings in this work can be widely used to guide the synthesis of other mixed oxides or spinels as high performance electrode materials for lithium ion batteries.

Zheng, Jianming; Xiao, Jie; Yu, Xiqian; Kovarik, Libor; Gu, Meng; Omenya, Fredrick; Chen, Xilin; Yang, Xiao-Qing; Liu, Jun; Graff, Gordon L.; Whittingham, M. S.; Zhang, Jiguang

2012-10-31T23:59:59.000Z

113

Trimodal steady water waves  

E-Print Network (OSTI)

We construct three-dimensional families of small-amplitude gravity-driven rotational steady water waves on finite depth. The solutions contain counter-currents and multiple crests in each minimal period. Each such wave generically is a combination of three different Fourier modes, giving rise to a rich and complex variety of wave patterns. The bifurcation argument is based on a blow-up technique, taking advantage of three parameters associated with the vorticity distribution, the strength of the background stream, and the period of the wave.

Mats Ehrnström; Erik Wahlén

2013-10-31T23:59:59.000Z

114

Electric Vehicle Supply Equipment (EVSE) Test Report: ClipperCreek  

NLE Websites -- All DOE Office Websites (Extended Search)

(Vrms) 208.89 Supply frequency (Hz) 60.00 Initial ambient temperature (F) 52 Test Vehicle 1,3 Make and model 2011 Chevrolet Volt Battery type Li-ion Steady state charge power...

115

Electric Vehicle Supply Equipment (EVSE) Test Report: Leviton  

NLE Websites -- All DOE Office Websites (Extended Search)

(Vrms) 239.69 Supply frequency (Hz) 59.99 Initial ambient temperature (F) 58 Test Vehicle 1,3 Make and model 2011 Chevrolet Volt Battery type Li-ion Steady state charge power...

116

EVSE Features  

NLE Websites -- All DOE Office Websites (Extended Search)

60.00 Initial ambient temperature (F) 85 Test Vehicle 1 Make and model 2011 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 3 3.16 Maximum charge power (AC...

117

EVSE Features  

NLE Websites -- All DOE Office Websites (Extended Search)

Initial ambient temperature (F) 88 Test Vehicle 1,3 Make and model 2011 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 3.12 Maximum charge power (AC kW)...

118

In-situ raman microscopy of individual LiNi0.8Co0.15Al0.05O2 particles in the Li-ion battery composite cathode  

DOE Green Energy (OSTI)

Kinetic characteristics of Li{sup +} intercalation/deintercalation into/from individual LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} particles in a composite cathode were studied in-situ using Raman microscopy during electrochemical charge-discharge in 1.2 M LiPF{sub 6}, ethylene carbonate (EC): ethyl-methyl carbonate (EMC), 3:7 by volume. Spectroscopic analysis of a cathode that was removed from a tested high-power Li-ion cell, which suffered substantial power and capacity loss, showed that the state of charge (SOC) of oxide particles on the cathode surface was highly non-uniform despite deep discharge of the Li-ion cell at the end of the test. In-situ monitoring of the SOC of selected oxide particles in the composite cathode in a sealed spectro-electrochemical cell revealed that the rate at which particles charge and discharge varied with time and location. The inconsistent kinetic behavior of individual oxide particles was attributed to degradation of the electronically conducting matrix in the composite cathode upon testing. These local micro-phenomena are responsible for the overall impedance rise of the cathode and contribute to the mechanism of lithium-ion cell failure.

Lei, Jinglei; McLarnon, Frank; Kostecki, Robert

2004-10-01T23:59:59.000Z

119

Jump Steady Resort Space Heating Low Temperature Geothermal Facility | Open  

Open Energy Info (EERE)

Jump Steady Resort Space Heating Low Temperature Geothermal Facility Jump Steady Resort Space Heating Low Temperature Geothermal Facility Jump to: navigation, search Name Jump Steady Resort Space Heating Low Temperature Geothermal Facility Facility Jump Steady Resort Sector Geothermal energy Type Space Heating Location Buena Vista, Colorado Coordinates 38.8422178°, -106.1311288° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

120

On the Steadiness of Separating Meandering Currents  

Science Conference Proceedings (OSTI)

The existence of inertial steady currents that separate from a coast and meander afterward is investigated. By integrating the zonal momentum equation over a suitable area, it is shown that retroflecting currents cannot be steady in a reduced ...

Peter Jan van Leeuwen; Will P. M. de Ruijter

2009-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
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121

The Lady and the Li-ion  

Science Conference Proceedings (OSTI)

Laptops desperately need a better Lithium-ion battery. Boston-Power's Christina Lampe-Onnerud says she's got it. Your world increasingly runs on lithium-ion batteries. Chances are good that your phone, laptop, camera, portable music and video players, ...

C. Lampe-Onnerud

2008-03-01T23:59:59.000Z

122

Advanced Solid State Li-Ion Battery  

Research on all-solid-state rechargeable lithium batteries has increased considerably in recent years due to raised concerns relating to safety hazards such as solvent leakage and flammability of liquid electrolytes used for commercial lithium-ion ...

123

Steady state compact toroidal plasma production  

DOE Patents (OSTI)

This invention relates to the confinement of field reversed plasma rings and, more particularly, to the steady state maintainance of field reversed plasma rings produced by coaxial plasma guns.

Turner, W.C.

1983-05-17T23:59:59.000Z

124

Description of alternative steady-state fuel cycles  

SciTech Connect

This study provides a first cut analysis for the FRAD program of a range of reference, steady-state, fresh and spent fuel compositions for the development of alternative fuels refabrication technology. Included are the resource requirements and separative work requirements and the material flows for each fuel cycle evaluated. However, since steady-state represents only a portion of the complete fuel cycle, a more in depth evaluation of each alternative fuel cycle will follow this analysis. Each of the fuel types investigated is composed of either plutonium-uranium (Pu-U), denatured uranium-thorium (DU-Th), plutonium-thorium (Pu-Th), highly enriched uranium-thorium (HEU-Th) or low enriched uranium (LEU). Seven ''closed cycles'' were formed by coupling two or more of the above fuel types. The closed cycle concept assumes that all fissile material recovered from spent fuel is either recycled into fresh fuel, or retired to waste when its net reactivity worth is equal to or less than tails equivalence. Additional fissile material required as makeup is introduced to the system from the enrichment cascade only. Each closed system presented in this study simulates the production of 1000 MWe in steady-state operation. The findings of this preliminary study indicated that, at equilibrium, those closed cycles which employ DU-Th or HEU-Th as the primary fuel are more efficient with respect to resource consumption than those cycles where LEU is used as the primary fuel.

Boegel, A.J.; Merrill, E.T.; Newman, D.F.; Nolan, A.M.

1978-11-01T23:59:59.000Z

125

Molecular stretching in polymer melts undergoing steady elongational flow.  

E-Print Network (OSTI)

Molecular stretching in polymer melts undergoing steady elongational flow. Kell Mortensen Centre DTU, Lyngby, Denmark The molecular stretching of a polymer melt undergoing steady elongational

126

Steady-state inductive spheromak operation  

DOE Patents (OSTI)

The inductively formed spheromak plasma can be maintained in a highly stable and controlled fashion. Steady-state operation is obtained by forming the plasma in the linked mode, then oscillating the poloidal and toroidal fields such that they have different phases. Preferably, the poloidal and magnetic fields are 90.degree. out of phase.

Janos, Alan C. (E. Windsor, NJ); Jardin, Stephen C. (Princeton, NJ); Yamada, Masaaki (Lawrenceville, NJ)

1987-01-01T23:59:59.000Z

127

Steady water waves with multiple critical layers  

E-Print Network (OSTI)

We construct small-amplitude periodic water waves with multiple critical layers. In addition to waves with arbitrarily many critical layers and a single crest in each period, two-dimensional sets of waves with several crests and troughs in each period are found. The setting is that of steady two-dimensional finite-depth gravity water waves with vorticity.

Mats Ehrnström; Joachim Escher; Erik Wahlén

2010-04-29T23:59:59.000Z

128

Steady-state inductive spheromak operation  

DOE Patents (OSTI)

The inductively formed spheromak configuration (S-1) can be maintained in a highly stable and controlled fashion. The method described eliminates the restriction to pulsed spheromak plasmas or the use of electrodes for steady-state operation, and, therefore, is a reactor-relevant formation and sustainment method.

Janos, A.C.; Jardin, S.C.; Yamada, M.

1985-02-20T23:59:59.000Z

129

Manipulating the Steady State of Metabolic Pathways  

Science Conference Proceedings (OSTI)

Metabolic pathways show the complex interactions among enzymes that transform chemical compounds. The state of a metabolic pathway can be expressed as a vector, which denotes the yield of the compounds or the flux in that pathway at a given time. The ... Keywords: Metabolic pathway, steady state, traversal approach, genetic algorithm.

Bin Song; I. Esra Buyuktahtakin; Sanjay Ranka; Tamer Kahveci

2011-05-01T23:59:59.000Z

130

Steady state compact toroidal plasma production  

DOE Patents (OSTI)

Apparatus and method for maintaining steady state compact toroidal plasmas. A compact toroidal plasma is formed by a magnetized coaxial plasma gun and held in close proximity to the gun electrodes by applied magnetic fields or magnetic fields produced by image currents in conducting walls. Voltage supply means maintains a constant potential across the electrodes producing an increasing magnetic helicity which drives the plasma away from a minimum energy state. The plasma globally relaxes to a new minimum energy state, conserving helicity according to Taylor's relaxation hypothesis, and injecting net helicity into the core of the compact toroidal plasma. Controlling the voltage so as to inject net helicity at a predetermined rate based on dissipative processes maintains or increases the compact toroidal plasma in a time averaged steady state mode.

Turner, William C. (Livermore, CA)

1986-01-01T23:59:59.000Z

131

DIVERSITY OF LUMINOUS SUPERNOVAE FROM NON-STEADY MASS LOSS  

Science Conference Proceedings (OSTI)

We show that the diversity in the density slope of the dense wind due to non-steady mass loss can be one way to explain the spectral diversity of Type II luminous supernovae (LSNe). The interaction of SN ejecta and wind surrounding it is considered to be a power source to illuminate LSNe because many LSNe show the wind signature in their spectra (Type IIn LSNe). However, there also exist LSNe without the spectral features caused by the wind (Type IIL LSNe). We show that, even if LSNe are illuminated by the interaction, it is possible that they do not show the narrow spectra from the wind if we take into account the non-steady mass loss of their progenitors. When the shock breakout takes place in a dense wind with the density structure {rho}{proportional_to}r{sup -w}, the ratio of the diffusion timescale in the optically thick region of the wind (t{sub d} ) and the shock propagation timescale of the entire wind after the shock breakout (t{sub s} ) strongly depends on w. For the case w {approx}< 1, both timescales are comparable (t{sub d} /t{sub s} {approx_equal} 1) and t{sub d} /t{sub s} gets smaller as w gets larger. For the case t{sub d} /t{sub s} {approx_equal} 1, the shock goes through the entire wind just after the light-curve (LC) peak, and narrow spectral lines from the wind cannot be observed after the LC peak (Type IIL LSNe). If t{sub d} /t{sub s} is much smaller, the shock wave continues to propagate in the wind after the LC peak, and unshocked wind remains (Type IIn LSNe). This difference can be obtained only through careful treatment of the shock breakout condition in a dense wind. The lack of narrow Lorentzian line profiles in Type IIL LSNe before the LC peak can also be explained by the difference in the density slope. Furthermore, we apply our model to Type IIn LSN 2006gy and Type IIL LSN 2008es and find that our model is consistent with the observations.

Moriya, Takashi J.; Tominaga, Nozomu, E-mail: takashi.moriya@ipmu.jp [Institute for the Physics and Mathematics of the Universe, Todai Institutes for Advanced Study, University of Tokyo, Kashiwanoha 5-1-5, Kashiwa, Chiba 277-8583 (Japan)

2012-03-10T23:59:59.000Z

132

Intense steady state electron beam generator  

DOE Patents (OSTI)

An intense, steady state, low emittance electron beam generator is formed by operating a hollow cathode discharge plasma source at critical levels in combination with an extraction electrode and a target electrode that are operable to extract a beam of fast primary electrons from the plasma source through a negatively biased grid that is critically operated to repel bulk electrons toward the plasma source while allowing the fast primary electrons to move toward the target in the desired beam that can be successfully transported for relatively large distances, such as one or more meters away from the plasma source. 2 figs.

Hershcovitch, A.; Kovarik, V.J.; Prelec, K.

1990-07-17T23:59:59.000Z

133

Progress towards Steady State on NSTX  

SciTech Connect

In order to reduce recirculating power fraction to acceptable levels, the spherical torus concept relies on the simultaneous achievement of high toroidal {beta} and high bootstrap fraction in steady state. In the last year, as a result of plasma control system improvements, the achievable plasma elongation on the National Spherical Torus Experiment (NSTX) has been raised from {kappa} {approx} 2.1 to {kappa} {approx} 2.6--approximately a 25% increase. This increase in elongation has lead to a doubling increase in the toroidal {beta} for long-pulse discharges. The increase in {beta} is associated with an increase in plasma current at nearly fixed poloidal {beta}, which enables higher {beta}{sub t} with nearly constant bootstrap fraction. As a result, for the first time in a spherical torus, a discharge with a plasma current of 1 MA has been sustained for 1 second. Data is presented from NSTX correlating the increase in performance with increased plasma shaping capability. In addition to improved shaping, H-modes induced during the current ramp phase of the plasma discharge have been used to reduce flux consumption during and to delay the onset of MHD instabilities. A modeled integrated scenario, which has 100% non-inductive current drive with very high toroidal {beta}, will also be presented. The NSTX poloidal field coils are currently being modified to produce the plasma shape which is required for this scenario, which requires high triangularity ({delta} {approx} 0.8) at elevated elongation ({kappa} {approx} 2.5). The other main requirement for steady state on NSTX is the ability to drive a fraction of the total plasma current with radio-frequency waves. The results of High Harmonic Fast Wave heating and current drive studies as well as electron Bernstein Wave emission studies will be presented.

D.A. Gates; C. Kessel; J. Menard; G. Taylor; J.R. Wilson; plus 94 co-authors

2005-01-24T23:59:59.000Z

134

Multiple Steady States in Azeotropic and Reactive Distillation  

E-Print Network (OSTI)

Introduction . Motivation Overview on the Contributions MSS in Reactive Distillation Conclusions Outline Multiple Steady States (MSS) Overview on the Contributions . The Starting Point . Consolidation . Industrial Applications . Incorporating Reactions MSS in Reactive Distillation Conclusions Outline Multiple Steady States (MSS) Overview on the Contributions MSS in Reactive Distillation . Prediction Method . MTBE Process Conclusions Outline Multiple Steady States (MSS) Overview on the Contributions MSS in Reactive Distillation Conclusions Distillation Overview . Ideal binary / multicomponent distillation . Homogeneous azeotropic distillation -- Heavy entrainer (extractive distillation) -- Intermediate entrainer -- "Boundary scheme" (ligh

Thomas E. Güttinger

1998-01-01T23:59:59.000Z

135

Steady state deformation of the Coso Range, east central California...  

Open Energy Info (EERE)

Steady state deformation of the Coso Range, east central California, inferred from satellite radar interferometry Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...

136

Final design of OSCAR steady state flowsheeting system. Technical report. [OTEC Steady-state and Control System Analysis Routines  

DOE Green Energy (OSTI)

The engineer using the OSCAR steady state simulation program will be able to link together in an arbitrary configuration the pieces of equipment needed to simulate an OTEC plant. Each one of these pieces of equipment (condenser, mixer, splitter, pump, etc.) is called a unit. Within a unit there are three types of substructures. A group of variables associated with a unit is called a variable pack. A unit can utilize more than one variable pack, and several units can utilize the same variable pack. The variables associated with a stream (flow rate, temperature, and pressure) form a variable pack. These variables are used by the unit producing the stream and by the unit receiving the stream. Another example of a variable pack would be the variables associated with a condenser. This type of variable pack would contain such variables as condenser area, log mean temperature difference, and heat duty. Other variable packs would contain physical properties of the pure components of a stream. A physical property variable pack of a particular component would be available to any unit where the component appeared.

Westerberg, A.W.; Chao, N.H.; Kuru, S.; Locke, M.H.

1978-12-01T23:59:59.000Z

137

NFRC Test Procedure for Measuring the Steady-State  

E-Print Network (OSTI)

NFRC Test Procedure for Measuring the Steady-State Thermal Transmittance of Fenestration Systems Adopted: March 15, 1991 Revised: April 17, 1997 Prepared by: Test Laboratory Task Group U Test Procedure for Measuring the Steady-State Thermal Transmittance of Fenestration Systems Adopted

Massachusetts at Amherst, University of

138

BATTERY STORAGE CONTROL FOR STEADYING RENEWABLE POWER GENERATION  

E-Print Network (OSTI)

BATTERY STORAGE CONTROL FOR STEADYING RENEWABLE POWER GENERATION By Shengyuan (Mike) Chen, Emilie-626-7370 URL: http://www.ima.umn.edu #12;Battery Storage Control for Steadying Renewable Power Generation by storing excess power to a battery during excess generation, and then releasing the energy when power

139

Continuously Stratified Models of the Steady-State Equatorial Ocean  

Science Conference Proceedings (OSTI)

Two linearized, vertically diffusive steady-state models are formulated on an equatorial ?-plane. The purpose is (a) to investigate the vertical boundary-layer structure in a continuously stratified ocean spanning the equator and (b) to test the ...

Michael J. McPhaden

1981-03-01T23:59:59.000Z

140

On the Physics of the Agulhas Current: Steady Retroflection Regimes  

Science Conference Proceedings (OSTI)

From previous model studies, it has become clear that several physical mechanisms may be at work in the retroflection of the Agulhas Current. Here, a systematic study of steady barotropic flows connecting the Indian Ocean and South Atlantic Ocean ...

Henk A. Dijkstra; Wilhelmus P. M. de Ruijter

2001-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Experimental Observations of Internal Vortex Structures in Steady Baroclinic Waves  

Science Conference Proceedings (OSTI)

The basic structures of steady baroclinic waves observed in a differentially heated rotating-fluid annulus are well known to be composed of high and low pressure vortices, upper (eastward) and lower (westward) jet streams meandering through the ...

T. Tajima; T. Nakamura; T. Sakata

1997-06-01T23:59:59.000Z

142

Method and apparatus for adapting steady flow with cyclic thermodynamics  

DOE Patents (OSTI)

Energy transfer apparatus has a resonator for supporting standing acoustic waves at a selected frequency with a steady flow process fluid thermodynamic medium and a solid medium having heat capacity. The fluid medium and the solid medium are disposed within the resonator for thermal contact therebetween and for relative motion therebetween. The relative motion is produced by a first means for producing a steady velocity component and second means for producing an oscillating velocity component at the selected frequency and concomitant wavelength of the standing acoustic wave. The oscillating velocity and associated oscillating pressure component provide energy transfer between the steady flow process fluid and the solid medium as the steady flow process fluid moves through the resonator.

Swift, Gregory W. (Santa Fe, NM); Reid, Robert S. (Los Alamos, NM); Ward, William C. (Santa Fe, NM)

2000-01-01T23:59:59.000Z

143

Steady, Free Circulation in a Stratified Quasi-Geostrophic Ocean  

Science Conference Proceedings (OSTI)

Steady solutions in which quasi-geostrophic potential vorticity is constant along a streamline of the flow are derived for a baroclinic ocean. Friction, transfer by geostrophic eddies, and wind forcing are treated as high-order effects that serve ...

John Marshall; George Nurser

1986-11-01T23:59:59.000Z

144

Steady Coastal Circulation Due to Oceanic Alongshore Pressure Gradients  

Science Conference Proceedings (OSTI)

A depth-averaged barotropic model is used to investigate the steady response of the coastal ocean to alongshore pressure gradients imposed by the deep ocean. Solution indicate that the dimensionless continental margin width ? is the appropriate ...

Jason H. Middleton

1987-05-01T23:59:59.000Z

145

Observations of Steady Longshore Currents in the Surf Zone  

Science Conference Proceedings (OSTI)

Steady surf-zone longshore currents and directional properties of the incident wave field were measured on a beach with nearly straight and parallel depth contours. Selected data were processed into 64 segments, each of 68.2 min. duration, ...

R. T. Guza; E. B. Thornton; N. Christensen Jr.

1986-11-01T23:59:59.000Z

146

Constraints On The Mechanism Of Long-Term, Steady Subsidence...  

Open Energy Info (EERE)

of Geophysical Research 96, 16, 319-16, 333.); Dzurisin et al., 2002 (Dzurisin, D., Poland, M.P., Burgmann, R., 2002. Steady subsidence of Medicine Lake Volcano, Northern...

147

Safety testing of 18650-style Li-Ion cells  

DOE Green Energy (OSTI)

To address lithium-ion cell safety issues in demanding power applications, electrical and thermal abuse tests were performed on 18650 sized cells. Video and electrically monitored abuse tests in air included short circuit, forced overcharge, forced reversal, and controlled overheating (thermal) modes. Controlled overheating tests to 200 C were performed in a sealed chamber under a helium atmosphere and the gases released from the cell during thermal runaway were analyzed at regular intervals using gas chromatography and mass spectrometry. In addition to alkane and alkene solvent breakdown fragments, significant H{sub 2} was detected and evidence that HF was evolved was also found.

CRAFTS,CHRIS C.; BOREK III,THEODORE T.; MOWRY,CURTIS DALE

2000-06-08T23:59:59.000Z

148

Improved Positive Electrode Materials for Li-ion Batteries  

E-Print Network (OSTI)

from conventional petroleum sources, while the dottedline includes non-petroleum sources like ethanol and otherpowered by petroleum-based energy sources, a value that does

Conry, Thomas Edward

2012-01-01T23:59:59.000Z

149

Porous Graphene Nanosheets for Li-ion Battery Anodes  

Science Conference Proceedings (OSTI)

A21: First-Principles Molecular Dynamics Simulation of Chemical ... A3: Investigation on Co-combustion Kinetics of Anthracite Coal and Biomass Char by ... Lithium Redox Process for Thermochemical Water-Splitting as Energy Conversion.

150

Improved Positive Electrode Materials for Li-ion Batteries  

E-Print Network (OSTI)

of US dependence on foreign oil. The United States has morethat US dependence on foreign oil can be decreased by up to

Conry, Thomas Edward

2012-01-01T23:59:59.000Z

151

Polymer electrolytes for a rechargeable li-Ion battery  

SciTech Connect

Lithium-ion polymer electrolyte battery technology is attractive for many consumer and military applications. A Li{sub x}C/Li{sub y}Mn{sub 2}O{sub 4} battery system incorporating a polymer electrolyte separator base on novel Li-imide salts is being developed under sponsorship of US Army Research Laboratory (Fort Monmouth NJ). This paper reports on work currently in progress on synthesis of Li-imide salts, polymer electrolyte films incorporating these salts, and development of electrodes and cells. A number of Li salts have been synthesized and characterized. These salts appear to have good voltaic stability. PVDF polymer gel electrolytes based on these salts have exhibited conductivities in the range 10{sup -4} to 10{sub -3} S/cm.

Argade, S.D.; Saraswat, A.K.; Rao, B.M.L. [Technochem Co., Greensboro, NC (United States); Lee, H.S.; Xiang, C.L.; McBreen, J. [Brookhaven National Lab., Upton, NY (United States)

1996-10-01T23:59:59.000Z

152

Anode Materials for Rechargeable Li-Ion Batteries  

DOE Green Energy (OSTI)

This is the annual progress report for the Grant DE-FG03-00ER15035. This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. Our materials studies on electrode materials divide into electronic studies of the valence at and around Li atoms, and the crystal structures of these materials. We are addressing the basic questions of how these change with Li concentration, and what long-term changes take place during charge/discharge cycling of the materials.

B. Fultz

2001-01-12T23:59:59.000Z

153

Graphenic Material for High Performance Li-Ion Battery Electrodes  

Science Conference Proceedings (OSTI)

3D Nanostructured Bicontinuous Electrodes: Path to Ultra-High Power and Energy ... High Energy Density Lithium Capacitors Using Carbon-Carbon Electrodes.

154

Graphene Based Anodes for Li-ion Batteries  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, 2013 TMS Annual Meeting & Exhibition. Symposium , Nanostructured Materials for Lithium Ion Batteries and for Supercapacitors.

155

Recovery of Metallic Values from Spent Li Ion Secondary Batteries  

Science Conference Proceedings (OSTI)

During the first step, 92% of the cobalt was recovered as CoSO4 by the use of ethanol at a volume ratio of 3 : 1. In the second step, the remaining cobalt was ...

156

Batteries - Next-generation Li-ion batteries Breakout session  

NLE Websites -- All DOE Office Websites (Extended Search)

power, stability) * Lack of new high-energy intercalation materials * Lack of stable high-voltage electrolytes * Lack of cycleable, high-density anode (e.g. metallic lithium)...

157

ELECTROLYTE MIXTURES USEFUL FOR LI-ION BATTERIES - Energy ...  

Solar Photovoltaic; Solar Thermal; Startup America; Vehicles and Fuels; ... The Regents of the University of California (Oakland CA) Application Number: 12/ 274,012:

158

FREE STANDING NANOSTRUCTURED ANODES FOR LI-ION RECHARGEABLE BATTERIES  

DOE Green Energy (OSTI)

The free standing nanorodes of aluminum and cobalt oxides were grown on electrode and tested as the anodes directly in the half-cell. The average diameter and length of the nanorods are 80 nm and 200 nm respectively. The aligned nanorods demonstrated high initial capacity from 1200-1400 mAh/g at rate of 0.5C. The gradually decrease of initial capacity was observed. The preliminary characterization shows that the changes of the crystalline structure and morphology during cycling may be responsible for the capacity decay.

Au, M.

2009-07-20T23:59:59.000Z

159

Probing Li-Ion Battery Electrode Architectures with a  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2009. Symposium, Energy Storage: Materials, Systems, and Applications. Presentation Title ...

160

Novel Electrode Material Offers Alternative for Li-ion Batteries  

Science Conference Proceedings (OSTI)

Jun 10, 2013 ... Further increasing the capacity of lithium-ion batteries could enable laptops to work longer and electric cars to drive farther, among many ...

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

New Model Predicts Dendrite Formation in Li-Ion Batteries  

Science Conference Proceedings (OSTI)

Mar 28, 2013 ... The dendrites are lithium deposits that form on electrode surfaces that can potentially cause an internal short circuit, resulting in battery failure ...

162

Integrating SOC Dependent Material Properties into Li-Ion Battery ...  

Science Conference Proceedings (OSTI)

During battery operation, Li flows into and out of electrode particles, causing microstructural changes and deformation-induced degradation. A variety of models ...

163

Berkeley Lab Researchers Evaluate Tin Nanocrystals for Li-ion...  

NLE Websites -- All DOE Office Websites (Extended Search)

with EETD scientists on cooperative research? Get a job in EETD? Make my home more energy-efficient? Find a source within EETD for a news story I'm writing, shooting, or...

164

Anode Materials for Rechargeable Li-Ion Batteries  

DOE Green Energy (OSTI)

This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. At present, our experimental work involves only materials for Li storage, but we have been writing papers from our previous work on hydrogen-storage materials.

Fultz, B.

2001-01-12T23:59:59.000Z

165

Improved Positive Electrode Materials for Li-ion Batteries  

E-Print Network (OSTI)

could double Chevy Volt battery capacity. ” http://could-double-chevy-volt-battery-capacity/chevy-volt3-4/; “Volt’s Battery Capacity Could Double. ” http://

Conry, Thomas Edward

2012-01-01T23:59:59.000Z

166

Direct Observation of Microstructure Evolution in Li-Ion Battery ...  

Science Conference Proceedings (OSTI)

Catalytic Properties of Ni3Al Foils for Methane Steam Reforming · Characterization of the Crystallographic Textures and Mechanical Anisotropy Factors in Two ...

167

Combustion dynamics in steady compressible flows  

E-Print Network (OSTI)

We study the evolution of a reactive field advected by a one-dimensional compressible velocity field and subject to an ignition-type nonlinearity. In the limit of small molecular diffusivity the problem can be described by a spatially discretized system, and this allows for an efficient numerical simulation. If the initial field profile is supported in a region of size l < lc one has quenching, i.e., flame extinction, where lc is a characteristic length-scale depending on the system parameters (reacting time, molecular diffusivity and velocity field). We derive an expression for lc in terms of these parameters and relate our results to those obtained by other authors for different flow settings.

S. Berti; D. Vergni; A. Vulpiani

2008-07-03T23:59:59.000Z

168

Paducah Site Undergoing Steady Groundwater Cleanup with Variety of Methods  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Site Undergoing Steady Groundwater Cleanup with Variety of Site Undergoing Steady Groundwater Cleanup with Variety of Methods Paducah Site Undergoing Steady Groundwater Cleanup with Variety of Methods June 1, 2012 - 12:00pm Addthis The yellow outline depicts an area southeast of the C-400 Cleaning Building, background, where electrical resistance heating will be used to remove trichloroethene (TCE) down to 60 feet below ground. Electrodes will heat the chemical into a vapor that can be pumped to the surface and treated in the white structure, center. The yellow outline depicts an area southeast of the C-400 Cleaning Building, background, where electrical resistance heating will be used to remove trichloroethene (TCE) down to 60 feet below ground. Electrodes will heat the chemical into a vapor that can be pumped to the surface and

169

Thermalization of Starlight in the Steady-State Cosmology  

E-Print Network (OSTI)

We investigate the fate of starlight in the Steady-State Cosmology. We discover that it is largely unaffected by the presence of ions in intergalactic space as it gets progressively red-shifted from the visible all the way down to the plasma frequency of the intergalactic matter. At that point, after about 450 Gyr - and contrary to previously published claims - the radiation will be thermalized. Under the assumptions adopted by Gold, Bondi, Hoyle, Narlikar, Burbidge and others concerning the creation of matter in the Steady-State Cosmology, and using reasonable estimates for the baryonic mass-density and mass-fraction of 4He, the analysis predicts a universal radiation field matching the CMB, i.e. having a black-body spectrum and temperature of about 2.7 K. The Steady-state Cosmology predicts that this radiation field will appear to originate from the intergalactic plasma.

M. Ibison

2009-10-15T23:59:59.000Z

170

Steady state deformation of the Coso Range, east central California,  

Open Energy Info (EERE)

Steady state deformation of the Coso Range, east central California, Steady state deformation of the Coso Range, east central California, inferred from satellite radar interferometry Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Steady state deformation of the Coso Range, east central California, inferred from satellite radar interferometry Details Activities (2) Areas (1) Regions (0) Abstract: Observations of deformation from 1992 to 1997 in the southern Coso Range using satellite radar interferometry show deformation rates of up to 35 mm yr -1 in an area approximately 10 km by 15 km. The deformation is most likely the result of subsidence in an area around the Coso geothermal field. The deformation signal has a short-wavelength component, related to production in the field, and a long-wavelength component,

171

Advanced quasi-steady state approximation for chemical kinetics  

E-Print Network (OSTI)

Computational feasibility of turbulent reacting flows hinges on the reduction of large chemical kinetics systems to smaller more manageable reaction sets. Recently, several sophisticated reduction techniques have been developed but they continue to be computationally prohibitive for practical three-dimensional unsteady computations. For such applications, the classical quasi-steady state assumption (QSSA), despite serious shortcomings, continues to be popular due to its conceptual clarity and computational simplicity. Starting from invariant manifold description, we develop an advanced quasi-steady state assumption which (i) is independent of the choice of the retained (slow) species; (ii) possesses much improved physical and mathematical characteristics; and (iii) can be specialized for any objective function.

Girimaji, Sharath

2011-01-01T23:59:59.000Z

172

Steady-state and transient wellbore temperatures during drilling  

DOE Green Energy (OSTI)

An extensive literature search was made to locate technical publications and computer programs relating to wellbore temperatures during drilling operations. The search confirmed the need for knowledge of transient and steady state circulating temperatures in the design of geothermal bits. Two approaches were used in calculating borehole temperatures. The steady state solution of Holmes and Swift was programmed and 2100 cases calculated for various borehole configurations. For transient temperature studies, calculations were made for ten borehole configurations. These calculations help emphasize the need for better high temperature bit performance and improved engineering procedures in drilling. The conclusions and recommendations are based on latest available technology for calculating wellbore temperatures.

McDonald, W.J.

1976-05-20T23:59:59.000Z

173

Steady-State Diagnostic Model of the New York Bight  

Science Conference Proceedings (OSTI)

A qualitative evaluation is made of the output from a finite-element, steady-state diagnostic model to observed time-averaged currents. The model uses a vorticity balance equation with linear bottom friction and inputs observations of near-bottom ...

Gregory Han; Donald V. Hansen; Jerry A. Galt

1980-12-01T23:59:59.000Z

174

Steady State Analysis of an induction generator infinite bus system  

E-Print Network (OSTI)

analysis of grid connected wind energy conver- sion systems employing induction generators, one1 Steady State Analysis of an induction generator infinite bus system Rajesh G Kavasseri Department of Electrical and Computer Engineering North Dakota State University, Fargo, ND 58105 - 5285, USA (email: rajesh

Kavasseri, Rajesh

175

On the steady states of weakly reversible chemical reaction networks  

E-Print Network (OSTI)

A natural condition on the structure of the underlying chemical reaction network, namely weak reversibility, is shown to guarantee the existence of an equilibrium (steady state) in each positive stoichiometric compatibility class for the associated mass-action system. Furthermore, an index formula is given for the set of equilibria in a given stoichiometric compatibility class.

Deng, Jian; Feinberg, Martin; Nachman, Adrian

2011-01-01T23:59:59.000Z

176

Steady water waves with multiple critical layers: interior dynamics  

E-Print Network (OSTI)

We study small-amplitude steady water waves with multiple critical layers. Those are rotational two-dimensional gravity-waves propagating over a perfect fluid of finite depth. It is found that arbitrarily many critical layers with cat's-eye vortices are possible, with different structure at different levels within the fluid. The corresponding vorticity depends linearly on the stream function.

Mats Ehrnström; Joachim Escher; Gabriele Villari

2010-04-29T23:59:59.000Z

177

Ranking and selection for steady-state simulation  

Science Conference Proceedings (OSTI)

We present and evaluate two ranking-and-selection procedures for use in steady-state simulation experiments when the goal is to find which among a finite number of alternative systems has the largest or smallest long-run average performance. Both procedures ...

David Goldsman; William S. Marshall; Seong-Hee Kim; Barry L. Nelson

2000-12-01T23:59:59.000Z

178

BURNER DEVELOPMENT AND OPERABILITY ISSUES ASSOCIATED WITH STEADY FLOWING SYNGAS  

E-Print Network (OSTI)

BURNER DEVELOPMENT AND OPERABILITY ISSUES ASSOCIATED WITH STEADY FLOWING SYNGAS FIRED COMBUSTORS-Mu¨nchen, Garching, Germany This article addresses the impact of syngas fuel composition on combustor blowout, flash flashback mechanisms are present in swirling flows, and the key thermophysical properties of a syngas

Lieuwen, Timothy C.

179

Comments on the Quasi-Steady-State Cosmology  

E-Print Network (OSTI)

The Quasi-Steady-State Cosmology as proposed by Hoyle, Burbidge and Narlikar does not fit the observed facts of the Universe. In particular, it predicts that 75-90\\% of the radio sources in the brightest sample that shows steeper than Euclidean source counts should be blueshifted.

Edward L. Wright

1994-10-20T23:59:59.000Z

180

Theory of minimum dissipation of energy for the steady state  

SciTech Connect

The magnetic configuration of an inductively driven steady-state plasma bounded by a surface (or two adjacent surfaces) on which B{center dot}n = 0 is force-free: {del}{times}B = 2{alpha}B, where {alpha} is a constant, in time and in space. {alpha} is the ratio of the Poynting flux to the magnetic helicity flux at the boundary. It is also the ratio of the dissipative rates of the magnetic energy to the magnetic helicity in the plasma. The spatial extent of the configuration is noninfinitesimal. This global constraint is a result of the requirement that, for a steady-state plasma, the rate of change of the vector potential, {partial derivative}A/{partial derivative}t, is constant in time and uniform in space.

Chu, T.K.

1992-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Theory of minimum dissipation of energy for the steady state  

SciTech Connect

The magnetic configuration of an inductively driven steady-state plasma bounded by a surface (or two adjacent surfaces) on which B{center_dot}n = 0 is force-free: {del}{times}B = 2{alpha}B, where {alpha} is a constant, in time and in space. {alpha} is the ratio of the Poynting flux to the magnetic helicity flux at the boundary. It is also the ratio of the dissipative rates of the magnetic energy to the magnetic helicity in the plasma. The spatial extent of the configuration is noninfinitesimal. This global constraint is a result of the requirement that, for a steady-state plasma, the rate of change of the vector potential, {partial_derivative}A/{partial_derivative}t, is constant in time and uniform in space.

Chu, T.K.

1992-02-01T23:59:59.000Z

182

QUASI-STEADY CONFIGURATIONS OF CONDUCTIVE INTRACLUSTER MEDIA  

SciTech Connect

The radial distributions of temperature, density, and gas entropy among cool-core clusters tend to be quite similar, suggesting that they have entered a quasi-steady state. If that state is regulated by a combination of thermal conduction and feedback from a central active galactic nucleus (AGN), then the characteristics of those radial profiles ought to contain information about the spatial distribution of AGN heat input and the relative importance of thermal conduction. This paper addresses those topics by deriving steady-state solutions for clusters in which radiative cooling, electron thermal conduction, and thermal feedback fueled by accretion are all present, with the aim of interpreting the configurations of cool-core clusters in terms of steady-state models. It finds that the core configurations of many cool-core clusters have entropy levels just below those of conductively balanced solutions in which magnetic fields have suppressed electron thermal conduction to {approx}1/3 of the full Spitzer value, suggesting that AGN feedback is triggered when conduction can no longer compensate for radiative cooling. And even when feedback is necessary to heat the central {approx}30 kpc, conduction may still be the most important heating mechanism within a cluster's central {approx}100 kpc.

Voit, G. M., E-mail: voit@pa.msu.edu [Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States)

2011-10-10T23:59:59.000Z

183

Flashback Characteristics of Syngas-Type Fuels Under Steady and Pulsating Conditions  

DOE Green Energy (OSTI)

The objective of this project was to improve understanding and modeling of flashback, a significant issue in low emissions combustors containing high levels of hydrogen. Experimental studies were performed over a range of fuel compositions, flow velocities, reactant temperatures, and combustor pressures to study the factors leading to flashback. In addition, high speed imaging of the flashback phenomenon was obtained. One of the key conclusions of this study was that there existed multiple mechanisms which lead to flashback, each with different underlying parametric dependencies. Specifically, two mechanisms of 'flashback' were noted: rapid flashback into the premixer, presumably through the boundary layer, and movement of the static flame position upstream along the centerbody. The former and latter mechanisms were observed at high and low hydrogen concentrations. In the latter mechanism, flame temperature ratio, not flame speed, appeared to be the key parameter describing flashback tendencies. We suggested that this was due to an alteration of the vortex breakdown location by the adverse pressure gradient upstream of the flame, similar to the mechanism proposed by Sattelmayer and co-workers [1]. As such, a key conclusion here was that classical flashback scalings derived from, e.g., Bunsen flames, were not relevant for some parameter regimes found in swirling flames. In addition, it was found that in certain situations, pure H2 flames could not be stabilized, i.e., the flame would either flashback or blowout at ignition. This result could have significant implications on the development of future high hydrogen turbine systems.

Tim Lieuwen

2007-09-30T23:59:59.000Z

184

Progress in Steady-State Scenario Development in the DIII-D Tokamak (A26981)  

E-Print Network (OSTI)

Proc. Of 6th IAEA Technical Meeting On Steady-State Operation Of Magnetic Fusion Devices6th IAEA Technical Committee Meeting on Steady State Operation of Magnetic Fusion Devices Vienna, AT, 2010999617785

Luce, T.C.

2011-01-19T23:59:59.000Z

185

The Existence and Stability of Steady Circulations in a Conditionally Symmetrically Unstable Basic Flow  

Science Conference Proceedings (OSTI)

By treating the latent heating as an energy source which is implicitly related to the motion field, the existence of steady nonlinear circulations in a flow susceptible to Conditionally Symmetric Instability (CSI) is studied. Steady viscous ...

Qin Xu

1987-10-01T23:59:59.000Z

186

Steady State Microbunching for High Brilliance and High Repetition Rate Storage Ring-Based Light Sources  

SciTech Connect

Electron-based light sources have proven to be effective sources of high brilliance, high frequency radiation. Such sources are typically either linac-Free Electron Laser (FEL) or storage ring types. The linac-FEL type has high brilliance (because the beam is microbunched) but low repetition rate. The storage ring type has high repetition rate (rapid beam circulation) but comparatively low brilliance or coherence. We propose to explore the feasibility of a microbunched beam in a storage ring that promises high repetition rate and high brilliance. The steady-state-micro-bunch (SSMB) beam in storage ring could provide CW sources for THz, EUV, or soft X-rays. Several SSMB mechanisms have been suggested recently, and in this report, we review a number of these SSMB concepts as promising directions for high brilliance, high repetition rate light sources of the future. The trick of SSMB lies in the RF system, together with the associated synchrotron beam dynamics, of the storage ring. Considering various different RF arrangements, there could be considered a number of scenarios of the SSMB. In this report, we arrange these scenarios more or less in order of the envisioned degree of technical challenge to the RF system, and not in the chronological order of their original references. Once the stored beam is steady-state microbunched in a storage ring, it passes through a radiator repeatedly every turn (or few turns). The radiator extracts a small fraction of the beam energy as coherent radiation with a wavelength corresponding to the microbunched period of the beam. In contrast to an FEL, this radiator is not needed to generate the microbunching (as required e.g. by SASE FELs or seeded FELs), so the radiator can be comparatively simple and short.

Chao, Alex; Ratner, Daniel; /SLAC; Jiao, Yi; /Beijing, Inst. High Energy Phys.

2012-09-06T23:59:59.000Z

187

Steady Deflagration of PBX-9501 Within a Copper Cylinder  

SciTech Connect

A copper cylinder cook-off experiment has been designed to cause steady deflagration in PBX-9501 explosive material. The design is documented and preliminary copper expansion results are presented for steady deflagration with a reaction speed of 1092 +/- 24 m/s. The expansion of reaction products from the detonation of an explosive is something that is well understood, and reasonably simulated using documented equations of state (EOS) for many explosives of interest. These EOS were historically measured using a 'standard' copper cylinder test design; this design comprised an annealed, oxygen-free high conductivity (OFHC) copper tube filled with explosive material and detonated from one end. Expansion of the copper wall was measured as a function of time using either a streak camera (for classic testing), or more recently using laser velocimetry techniques. Expansion data were then used to derive the EOS in various preferred forms - which are not discussed here for the sake of brevity. [Catanach, et. al., 1999] When an explosive deflagrates rather than detonating, simulation becomes more difficult. Reaction products are released on a slower time scale, and the reactions are much more affected by the geometry and local temperature within the reaction environment. It is assumed that the standard, documented EOS will no longer apply. In an effort to establish a first order approximation of deflagration product behavior, a cook-off test has been designed to cause steady deflagration in PBX-9501 explosive material, and to record the copper expansion profile as a function of time during this test. The purpose of the current paper is to document the initial test design and report some preliminary results. A proposal for modification of the design is also presented.

Pemberton, Steven J. [Los Alamos National Laboratory; Herrera, Dennis H. [Los Alamos National Laboratory; Herrera, Tommy J. [Los Alamos National Laboratory; Arellano, Jesus C. [Los Alamos National Laboratory; Sandoval, Thomas D. [Los Alamos National Laboratory

2012-06-26T23:59:59.000Z

188

Steady-state and transient wellbore temperatures during drilling  

DOE Green Energy (OSTI)

An extensive literature search was made to locate technical publications and computer programs relating to wellbore temperatures during drilling operations. Publications obtained are listed in the References. Two approaches were used in calculating borehole temperatures: The steady state solution of Holmes and Swift was programmed and 2100 cases calculated for various borehole configurations. For transient temperature studies, Exxon Production Research Co. made calculations for ten borehole configurations under subcontract. These calculations emphasize the need for better high temperature bit performance and improved engineering procedures in drilling.

McDonald, W.J.

1976-05-20T23:59:59.000Z

189

Integration through transients for Brownian particles under steady shear  

E-Print Network (OSTI)

Abstract. Starting from the microscopic Smoluchowski equation for interacting Brownian particles under stationary shearing, exact expressions for shear– dependent steady–state averages, correlation and structure functions, and susceptibilities are obtained, which take the form of generalized Green–Kubo relations. They require integration of transient dynamics. Equations of motion with memory effects for transient density fluctuation functions are derived from the same microscopic starting point. We argue that the derived formal expressions provide useful starting points for approximations in order to describe the stationary non–equilibrium state of steadily sheared dense colloidal dispersions.

M. Fuchs; M. E. Cates

2005-01-01T23:59:59.000Z

190

Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state,  

E-Print Network (OSTI)

Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state), Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state, variably and colloid transport through coarse Hanford sediments under steady state, variably saturated flow'' by Kelly

Flury, Markus

191

Analytical and numerical solution of one- and two-dimensional steady heat transfer in a coldplate  

SciTech Connect

We develop analytical models for steady-state, one- and two-dimensional heat transfer in a single-material, flat-plate coldplate. Discrete heat sources are mounted on one side of the plate and heat transfer to a flowing fluid occurs on the other. The models are validated numerically using finite differences. We propose a simple procedure for estimating maximum coldplate temperature at the location of each heat source which includes thermal interaction among the sources. Results from one model are compared with data obtained for a composite coldplate operated in the laboratory. We demonstrate the utility of the models as diagnostic tools to be used for predicting the existence and extent of void volumes and delaminations in the composite material that can occur with coldplates of this type. Based on our findings, recommendations for effective coldplate design are given.

Jones, G.F.; Bennett, G.A.; Bultman, D.H.

1987-01-01T23:59:59.000Z

192

COMSOL Simulations for Steady State Thermal Hydraulics Analyses of ORNL s High Flux Isotope Reactor  

SciTech Connect

Simulation models for steady state thermal hydraulics analyses of Oak Ridge National Laboratory s High Flux Isotope Reactor (HFIR) have been developed using the COMSOL Multiphysics simulation software. A single fuel plate and coolant channel of each type of HFIR fuel element was modeled in three dimensions; coupling to adjacent plates and channels was accounted for by using periodic boundary conditions. The standard k- turbulence model was used in simulating turbulent flow with conjugate heat transfer. The COMSOL models were developed to be fully parameterized to allow assessing impacts of fuel fabrication tolerances and uncertainties related to low enriched uranium (LEU) fuel design and reactor operating parameters. Heat source input for the simulations was obtained from separate Monte Carlo N Particle calculations for the axially non-contoured LEU fuel designs at the beginning of the reactor cycle. Mesh refinement studies have been performed to calibrate the models against the pressure drop measured across the HFIR core.

Khane, Vaibhav B [ORNL; Jain, Prashant K [ORNL; Freels, James D [ORNL

2012-01-01T23:59:59.000Z

193

Fueling Requirements for Steady State high butane current fraction discharges  

SciTech Connect

The CT injector originally used for injecting CTs into 1T toroidal field discharges in the TdeV tokamak was shipped PPPL from the Affiliated Customs Brokers storage facility in Montreal during November 2002. All components were transported safely, without damage, and are currently in storage at PPPL, waiting for further funding in order to begin advanced fueling experiments on NSTX. The components are currently insured through the University of Washington. Several technical presentations were made to investigate the feasibility of the CT injector installation on NSTX. These technical presentations, attached to this document, were: (1) Motivation for Compact Toroida Injection in NSTX; (2) Assessment of the Engineering Feasibility of Installing CTF-II on NSTX; (3) Assessment of the Cost for CT Installation on NSTX--A Peer Review; and (4) CT Fueling for NSTX FY 04-08 steady-state operation needs.

R.Raman

2003-10-08T23:59:59.000Z

194

A steady state analysis code for prediction of behavior in loop heat pipes.  

E-Print Network (OSTI)

??The purpose of this work is to prepare an analysis raphics. code for the prediction of Loop Heat Pipe (LHP) behavior in steady-state operation. The… (more)

Hamm, Trenton Allen

2012-01-01T23:59:59.000Z

195

Formation of Solar Filaments by Steady and Nonsteady Chromospheric Heating  

E-Print Network (OSTI)

It has been established that cold plasma condensations can form in a magnetic loop subject to localized heating of the footpoints. In this paper, we use grid-adaptive numerical simulations of the radiative hydrodynamic equations to parametrically investigate the filament formation process in a pre-shaped loop with both steady and finite-time chromospheric heating. Compared to previous works, we consider low-lying loops with shallow dips, and use a more realistic description for the radiative losses. We demonstrate for the first time that the onset of thermal instability satisfies the linear instability criterion. The onset time of the condensation is roughly \\sim 2 hr or more after the localized heating at the footpoint is effective, and the growth rate of the thread length varies from 800 km hr-1 to 4000 km hr-1, depending on the amplitude and the decay length scale characterizing this localized chromospheric heating. We show how single or multiple condensation segments may form in the coronal portion. In th...

Xia, C; Keppens, R; van Marle, A J

2011-01-01T23:59:59.000Z

196

NASA Lewis steady-state heat pipe code users manual  

SciTech Connect

The NASA Lewis heat pipe code has been developed to predict the performance of heat pipes in the steady state. The code can be used as a design tool on a personal computer or, with a suitable calling routine, as a subroutine for a mainframe radiator code. A variety of wick structures, including a user input option, can be used. Heat pipes with multiple evaporators, condensers, and adiabatic sections in series and with wick structures that differ among sections can be modeled. Several working fluids can be chosen, including potassium, sodium, and lithium, for which the monomer-dimer equilibrium is considered. The code incorporates a vapor flow algorithm that treats compressibility and axially varying heat input. This code facilitates the determination of heat pipe operating temperatures and heat pipe limits that may be encountered at the specified heat input and environment temperature. Data are input to the computer through a user-interactive input subroutine. Output, such as liquid and vapor pressures and temperatures, is printed at equally spaced axial positions along the pipe as determined by the user.

Tower, L.K. [Sverdrup Technology, Inc., Brook Park, OH (United States). Lewis Research Center Group; Baker, K.W. [National Aeronautics and Space Administration, Cleveland, OH (United States). Lewis Research Center; Marks, T.S. [Oregon State Univ., Corvallis, OR (United States)

1992-06-01T23:59:59.000Z

197

The Path of Carbon in Photosynthesis. XX. The Steady State  

DOE Green Energy (OSTI)

The separation of the phenomenon of photosynthesis in green plants into a photochemical reaction and into the light-dependent reduction of carbon dioxide is discussed, The reduction of carbon dioxide and the fate of the assimilated carbon were investigated with the help of the tracer technique (exposure of the planks to the radioactive C{sup 14}O{sub 2}) and of paper chromatography. A reaction cycle is proposed in which phosphoglyceric acid is the first isolable assimilations product. Analyses of the algal extracts which had assimilated radioactive carbon dioxide in a stationary condition ('steady-state' photosynthesis) for a long time provided further information concerning the proposed cycle and permitted the approximate estimation, for a number of compounds of what fraction of each compound was taking part in the cycle. The earlier supposition that light influences the respiration cycle was confirmed. The possibility of the assistance of {alpha}-lipoic acid, or of a related substance, in this influence and in the photosynthesis cycle, is discussed.

Calvin, M.; Massini, Peter

1952-09-01T23:59:59.000Z

198

OL YMERS  

Science Conference Proceedings (OSTI)

... oxide type Li ion battery electrolytes, are ... as a model polymer electrolyte for lithium-ion batteries. ... the local, mean square atomic displacements (MSD ...

2012-10-02T23:59:59.000Z

199

Estimating the Most Steady Frame of Reference from Doppler Radar Data  

Science Conference Proceedings (OSTI)

A method is described to determine the most steady frame of reference of a weather system from data from one or more Doppler radars at three analysis times. The most steady frame of reference is that frame in which the velocity field displays the ...

Thomas Matejka

2002-07-01T23:59:59.000Z

200

Efficient kinetic schemes for steady and unsteady flow simulations on unstructured meshes  

Science Conference Proceedings (OSTI)

This paper presents efficient second-order kinetic schemes on unstructured meshes for both compressible unsteady and incompressible steady flows. For compressible unsteady flows, a time-dependent gas distribution function with a discontinuous particle ... Keywords: Compressible unsteady flows, Efficient second-order kinetic schemes, Incompressible steady flows, Unstructured meshes

Guoxi Ni; Song Jiang; Kun Xu

2008-03-01T23:59:59.000Z

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201

Improving Steady-State Fit of Dynamics to Data Using Adjoint Equation for Gradient Preconditioning  

Science Conference Proceedings (OSTI)

The steady-state fit of Arakawa and Lamb's shallow-water equation model to time-mean sea surface height (SSH) has been examined, seeking better performance of the steady-state fit without requiring longer time integrations. It is shown that the ...

Jieping Zou; Greg Holloway

1995-01-01T23:59:59.000Z

202

A steady-state L-mode tokamak fusion reactor : large scale and minimum scale  

E-Print Network (OSTI)

We perform extensive analysis on the physics of L-mode tokamak fusion reactors to identify (1) a favorable parameter space for a large scale steady-state reactor and (2) an operating point for a minimum scale steady-state ...

Reed, Mark W. (Mark Wilbert)

2010-01-01T23:59:59.000Z

203

Nitrate and colloid transport through coarse Hanford sediments under steady state, variably saturated flow  

E-Print Network (OSTI)

Nitrate and colloid transport through coarse Hanford sediments under steady state, variably] At the U.S. Department of Energy's Hanford Reservation, colloid-facilitated transport is a potential of colloids through Hanford sediments under steady state, unsaturated flow conditions. We isolated colloids

Flury, Markus

204

Progress Towards High Performance, Steady-state Spherical Torus  

SciTech Connect

Research on the Spherical Torus (or Spherical Tokamak) is being pursued to explore the scientific benefits of modifying the field line structure from that in more moderate aspect-ratio devices, such as the conventional tokamak. The Spherical Tours (ST) experiments are being conducted in various U.S. research facilities including the MA-class National Spherical Torus Experiment (NSTX) at Princeton, and three medium-size ST research facilities: Pegasus at University of Wisconsin, HIT-II at University of Washington, and CDX-U at Princeton. In the context of the fusion energy development path being formulated in the U.S., an ST-based Component Test Facility (CTF) and, ultimately a Demo device, are being discussed. For these, it is essential to develop high-performance, steady-state operational scenarios. The relevant scientific issues are energy confinement, MHD stability at high beta (B), noninductive sustainment, ohmic-solenoid-free start-up, and power and particle handling. In the confinement area, the NSTX experiments have shown that the confinement can be up to 50% better than the ITER-98-pby2 H-mode scaling, consistent with the requirements for an ST-based CTF and Demo. In NSTX, CTF-relevant average toroidal beta values bT of up to 35% with the near unity central betaT have been obtained. NSTX will be exploring advanced regimes where bT up to 40% can be sustained through active stabilization of resistive wall modes. To date, the most successful technique for noninductive sustainment in NSTX is the high beta-poloidal regime, where discharges with a high noninductive fraction ({approx}60% bootstrap current + neutral-beam-injected current drive) were sustained over the resistive skin time. Research on radio-frequency-based heating and current drive utilizing HHFW (High Harmonic Fast Wave) and EBW (Electron Bernstein Wave) is also pursued on NSTX, Pegasus, and CDX-U. For noninductive start-up, the Coaxial Helicity Injection (CHI), developed in HIT/HIT-II, has been adopted on NSTX to test the method up to Ip {approx} 500 kA. In parallel, start-up using radio-frequency current drive and only external poloidal field coils are being developed on NSTX. The area of power and particle handling is expected to be challenging because of the higher power density expected in the ST relative to that in conventional aspect-ratio tokamaks. Due to its promise for power and particle handling, liquid lithium is being studied in CDX-U as a potential plasma-facing surface for a fusion reactor.

M. Ono; M.G. Bell; R.E. Bell; T. Bigelow; M. Bitter; W. Blanchard; J. Boedo; C. Bourdelle; C. Bush; W. Choe; J. Chrzanowski; D.S. Darrow; S.J. Diem; R. Doerner; P.C. Efthimion; J.R. Ferron; R.J. Fonck; E.D. Fredrickson; G.D. Garstka; D.A. Gates; T. Gray; L.R. Grisham; W. Heidbrink; K.W. Hill; D. Hoffman; T.R. Jarboe; D.W. Johnson; R. Kaita; S.M. Kaye; C. Kessel; J.H. Kim; M.W. Kissick; S. Kubota; H.W. Kugel; B.P. LeBlanc; K. Lee; S.G. Lee; B.T. Lewicki; S. Luckhardt; R. Maingi; R. Majeski; J. Manickam; R. Maqueda; T.K. Mau; E. Mazzucato; S.S. Medley; J. Menard; D. Mueller; B.A. Nelson; C. Neumeyer; N. Nishino; C.N. Ostrander; D. Pacella; F. Paoletti; H.K. Park; W. Park; S.F. Paul; Y.-K. M. Peng; C.K. Phillips; R. Pinsker; P.H. Probert; S. Ramakrishnan; R. Raman; M. Redi; A.L. Roquemore; A. Rosenberg; P.M. Ryan; S.A. Sabbagh; M. Schaffer; R.J. Schooff; R. Seraydarian; C.H. Skinner; A.C. Sontag; V. Soukhanovskii; J. Spaleta; T. Stevenson; D. Stutman; D.W. Swain; E. Synakowski; Y. Takase; X. Tang; G. Taylor; J. Timberlake; K.L. Tritz; E.A. Unterberg; A. Von Halle; J. Wilgen; M. Williams; J.R. Wilson; X. Xu; S.J. Zweben; R. Akers; R.E. Barry; P. Beiersdorfer; J.M. Bialek; B. Blagojevic; P.T. Bonoli; M.D. Carter; W. Davis; B. Deng; L. Dudek; J. Egedal; R. Ellis; M. Finkenthal; J. Foley; E. Fredd; A. Glasser; T. Gibney; M. Gilmore; R.J. Goldston; R.E. Hatcher; R.J. Hawryluk; W. Houlberg; R. Harvey; S.C. Jardin; J.C. Hosea; H. Ji; M. Kalish; J. Lowrance; L.L. Lao; F.M. Levinton; N.C. Luhmann; R. Marsala; D. Mastravito; M.M. Menon; O. Mitarai; M. Nagata; G. Oliaro; R. Parsells; T. Peebles; B. Peneflor; D. Piglowski; G.D. Porter; A.K. Ram; M. Rensink; G. Rewoldt; P. Roney; K. Shaing; S. Shiraiwa; P. Sichta; D. Stotler; B.C. Stratton; R. Vero; W.R. Wampler; G.A. Wurden

2003-10-02T23:59:59.000Z

205

Uncertainty analysis of steady state incident heat flux measurements in hydrocarbon fuel fires.  

SciTech Connect

The objective of this report is to develop uncertainty estimates for three heat flux measurement techniques used for the measurement of incident heat flux in a combined radiative and convective environment. This is related to the measurement of heat flux to objects placed inside hydrocarbon fuel (diesel, JP-8 jet fuel) fires, which is very difficult to make accurately (e.g., less than 10%). Three methods will be discussed: a Schmidt-Boelter heat flux gage; a calorimeter and inverse heat conduction method; and a thin plate and energy balance method. Steady state uncertainties were estimated for two types of fires (i.e., calm wind and high winds) at three times (early in the fire, late in the fire, and at an intermediate time). Results showed a large uncertainty for all three methods. Typical uncertainties for a Schmidt-Boelter gage ranged from {+-}23% for high wind fires to {+-}39% for low wind fires. For the calorimeter/inverse method the uncertainties were {+-}25% to {+-}40%. The thin plate/energy balance method the uncertainties ranged from {+-}21% to {+-}42%. The 23-39% uncertainties for the Schmidt-Boelter gage are much larger than the quoted uncertainty for a radiative only environment (i.e ., {+-}3%). This large difference is due to the convective contribution and because the gage sensitivities to radiative and convective environments are not equal. All these values are larger than desired, which suggests the need for improvements in heat flux measurements in fires.

Nakos, James Thomas

2005-12-01T23:59:59.000Z

206

Two-Sample Kalman Filter for Steady-State Data Assimilation  

Science Conference Proceedings (OSTI)

In this paper, a new iterative algorithm for computing a steady-state Kalman gain is proposed. This algorithm utilizes two model forecasts with statistically independent random perturbations to determine the error covariance used to define a ...

Julius H. Sumihar; Martin Verlaan; Arnold W. Heemink

2008-11-01T23:59:59.000Z

207

Constraints on Solutions of Long's Equation for Steady, Two-Dimensional, Hydrostatic Flow over a Ridge  

Science Conference Proceedings (OSTI)

Two-dimensional, stratified shear flow over a ridge is considered. The finite-amplitude disturbances are steady and hydrostatic, and solutions are derived from the Boussinesq from the Long's equation. Two limiting solutions are examined; viz., 1) ...

William Blumen

1989-05-01T23:59:59.000Z

208

On the Structural Characteristics of Steady Finite-Amplitude Mountain Waves over Bell-Shaped Topography  

Science Conference Proceedings (OSTI)

The characteristics of the two-dimensional steady state flow of unbounded stratified Boussinesq fluid over an isolated obstacle of finite height are analyzed for the simplqst case in which the incident flow speed, UO, and Brunt-Vaisala frequency, ...

R. Laprise; W. R. Peltier

1989-02-01T23:59:59.000Z

209

Simple Solutions to Steady-state Cumulus Regimes in the Convective Boundary Layer  

Science Conference Proceedings (OSTI)

A modeling framework is developed which extends the mixed layer model to steady state cumulus convection. The aim is to consider the simplest model which retains the essential behavior of cumulus-capped layers. The presented framework allows for ...

Jerôme Schalkwijk; Harmen J. J. Jonker; A. Pier Siebesma

210

Quasi-Steady Katabatic Winds on Slopes in Wide Valleys: Hydraulic Theory and Observations  

Science Conference Proceedings (OSTI)

Theoretical and field observational studies on mean velocity and temperature fields of quasi-steady nocturnal downslope (katabatic) flows on sloping surfaces are reported for the case of very wide valleys in the presence of weak synoptic winds. ...

M. Princevac; J. C. R. Hunt; H. J. S. Fernando

2008-02-01T23:59:59.000Z

211

Potential multiple steady-states in the long-term carbon cycle  

E-Print Network (OSTI)

Modelers of the long term carbon cycle in Earth history have previously assumed there is only one stable climatic steady state. Here we investigate the possibility of multiple steady states. We find them in Abiotic World, lacking any biotic influence, resulting from possible variations in planetary albedo in different temperature, atmospheric carbon dioxide level regimes, with the same weathering forcing balancing a volcanic source to the atmosphere, ocean pool. In Plant World modeling relevant to the Phanerozoic, we include the additional effects of biotic enhancement of weathering on land, organic carbon burial, oxidation of reduced organic carbon in terrestrial sediments and the variation of biotic productivity with temperature, finding a second stable steady state appearing between twenty and fifty degrees C. The very warm early Triassic climate may be the prime candidate for an upper temperature steady state. Given our results, the anthropogenic driven rise of atmospheric carbon dioxide could potentially...

Tennenbaum, Stephen; Schwartzman, David

2013-01-01T23:59:59.000Z

212

Aspects of Steady-State Operation of the Wendelstein 7-X Stellarator  

Science Conference Proceedings (OSTI)

The objective of Wendelstein 7-X is to demonstrate steady-state operation at -values of up to 5%, at ion temperatures of several keV and plasma densities of up to 2 1020 m 3. The second operational phase foresees a fully steady-state high heat flux (HHF) divertor. Preparations are underway to cope with residual bootstrap currents, either by electron cyclotron current drive or by HHF protection elements. The main steady-state heating system is an electron cyclotron resonance heating facility. Various technical improvements of the gyrotrons have been implemented recently. They enable a reliable operation at the 1MW power level. Some of the technical issues preparing plasma diagnostics for steady-state operation are exemplified. This includes the protection against non-absorbed microwave radiation.

Geiger, J. [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Wolf, R. C. [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Beidler, C. [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Cardella, A [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Chlechowitz, E [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Erckmann, V. [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Gantenbein, G [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Hathiramani, D [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Hirsch, M [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Kasparek, W [Institute for Plasma Research, University of Stuttgart; Kisslinger, J [EURATOM / IPP Garching, Germany; Koenig, R [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Kornejew, P [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Laqua, H P [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Lechte, C [Institute for Plasma Research, University of Stuttgart; Lore, Jeremy D [ORNL; Lumsdaine, Arnold [ORNL; Maassberg, H. [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Marushchenko, N B [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Michel, G [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Otte, M [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Peacock, A. [Max-Planck-Institut fur Plasmaphysik, EURATOM Association, Garching, Germany; Sunn Pedersen, T [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Thumm, M [Karlsruhe Institute for Technology, IHM, EURATOM Association, Karlsruhe, Germany; Turkin, Yu. [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Werner, A. [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany; Zhang, D [Max-Planck-Institute for Plasmaphysik, EURATOM-Association, Greifswald, Germany

2013-01-01T23:59:59.000Z

213

Accelerated Iterative Method for Solving Steady Problems of Linearized Atmospheric Models  

Science Conference Proceedings (OSTI)

A new approach, referred to as the accelerated iterative method (AIM), is developed for obtaining steady atmospheric responses with a zonally varying basic state. The linear dynamical operator is divided into two parts, one associated with the ...

Masahiro Watanabe; Fei-fei Jin; Lin Pan

2006-12-01T23:59:59.000Z

214

The Stability of Steady Fronts and the Adjoint Method: Nonmodal Frontal Waves  

Science Conference Proceedings (OSTI)

The adjoint method for finding optimal or singular modes is employed for studying the finite time stability of steady, tw0-dimensional atmospheric fronts as represented by the uniform potential vorticity semigeostrophic model.

Alain Joly

1995-09-01T23:59:59.000Z

215

The Response of Stratified Shelf and Slope Waters to Steady Offshore Forcing  

Science Conference Proceedings (OSTI)

The effect of steady, deep-ocean forcing on the flow over a continental slope and shelf region is examined using a linear and time-independent numerical model which includes continuous stratification, vertical and horizontal diffusion of momentum ...

Kathryn A. Kelly; David C. Chapman

1988-06-01T23:59:59.000Z

216

Study of Linear Steady Atmospheric Flow above a Finite Surface Heating  

Science Conference Proceedings (OSTI)

The steady-state atmospheric responses to a finite surface heating through thermal eddy diffusion are studied. The effects of the mean wind, the earth's rotation, and the thermal stratification are considered in a linear system. Scale analysis ...

Hsiao-Ming Hsu

1987-01-01T23:59:59.000Z

217

A steady-state L-mode tokamak fusion reactor : large scale and minimum scale.  

E-Print Network (OSTI)

??We perform extensive analysis on the physics of L-mode tokamak fusion reactors to identify (1) a favorable parameter space for a large scale steady-state reactor… (more)

Reed, Mark W. (Mark Wilbert)

2010-01-01T23:59:59.000Z

218

Steady Linear Response to Thermal Forcing of an Anomaly Model with an Asymmetric Climatology  

Science Conference Proceedings (OSTI)

An anomaly model linearized around the observed winter climatology is used to study the steady response of the atmosphere to diabatic heating. The model is an R7, nine vertical levels, primitive equations, fully spectral model, derived from the ...

A. Navarra

1990-01-01T23:59:59.000Z

219

The Path of Carbon in Photosynthesis. XVI. Kinetic Relationships of the Intermediates in Steady State Photosynthesis  

E-Print Network (OSTI)

OF CARBON I N PHOTOSYNTHESIS, X U , KINETIC REIATIORSEIPS OFof steady. state photosynthesis in cUO2 provides informationThe path of carbon i n photosynthesis begins with a small

Benson, A.A.; Kawaguchi, S.; Hayes, P.; Calvin, M.

1952-01-01T23:59:59.000Z

220

Product Form Steady-State Distribution for Stochastic Automata Networks with Domino Synchronizations  

Science Conference Proceedings (OSTI)

We present a new kind of synchronization which allows Continuous Time Stochastic Automata Networks (SAN) to have a product form steady-state distribution. Unlike previous models on SAN with product form solutions, our model allows synchronization between ...

Jean-Michel Fourneau

2008-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

The Steady Linear Response of a Spherical Atmosphere to Thermal and Orographic Forcing  

Science Conference Proceedings (OSTI)

Motivated by some results from barotropic models, a linearized steady-state five-layer baroclinic model is used to study the response of a spherical atmosphere to thermal and orographic forcing. At low levels the significant perturbations are ...

Brian J. Hoskins; David J. Karoly

1981-06-01T23:59:59.000Z

222

Thermohaline Oscillations Induced by Strong Steady Salinity Forcing of Ocean General Circulation Models  

Science Conference Proceedings (OSTI)

A series of numerical experiments is conducted with a three-dimensional ocean general circulation model and a two-dimensional counterpart both designed for efficient integration over diffusive (millennial) time scales. With strong steady salinity ...

Michael Winton; E. S. Sarachik

1993-07-01T23:59:59.000Z

223

Response to a Steady Poleward Outflow. Part II: Oscillations and Eddies  

Science Conference Proceedings (OSTI)

A conceptually simple model is presented for predicting the amplitude and periodicity of eddies generated by a steady poleward outflow in a 1½-layer ?-plane formulation. The prediction model is rooted in linear quasigeostrophic dynamics but is ...

Theodore S. Durland; Michael A. Spall; Joseph Pedlosky

2009-07-01T23:59:59.000Z

224

Steady state kinetic analyses of nitroalkane oxidase mutants  

E-Print Network (OSTI)

Nitroalkane oxidase (NAO) catalyzes the oxidation of neutral nitroalkanes to aldehydes and ketones with oxygen consumption and the production of hydrogen peroxide and nitrite. The enzyme is a flavoprotein from the fungus Fusarium oxysporum. The active site base, Asp402, abstracts one proton from the substrate to give a carbanion which then attacks the flavin adenine dinucleotide (FAD). The three dimensional crystal structure of NAO shows that Arg409 is 3.6 Å from Asp402. When Arg409 is mutated to Lys, the rate constant for proton abstraction decreases 100-fold. The three-dimensional structure of NAO also reveals the existence of a tunnel which extends from the protein exterior and terminates at the FAD N5 atom and the residues Asp402 and Phe401. We mutated amino acids in the tunnel into tryptophan, phenylalanine and leucine. The L99W, S276W and S276A enzymes showed the biggest decreases in both kcat and kcat/Km; these amino acids are closest to the FAD molecule and the active site. Mutation of amino acids farther away from the active site showed very small changes in the kinetic parameters. Ser276 is hydrogen bonded to Asp402 in the wild-type enzyme. When this amino acid is mutated to alanine or tryptophan, k3, the rate constant for proton abstraction, decreases around 35 fold. Asp402, Arg409 and Ser276 constitute a catalytic triad in the active site of nitroalkane oxidase, and both Arg409 and Ser276 are important for positioning Asp402 and catalysis.

Bozinovski, Dragana Milivoj

2008-05-01T23:59:59.000Z

225

Steady and unsteady calibration of multi-hole probes  

E-Print Network (OSTI)

This thesis presents the development of a data crographics. reduction algorithm for multi-hole pressure probes. The algorithm has been developed for the reduction of calibration data from miniature non-nulling multi-hole probes in compressible, subsonic flow gelds. The algorithm is able to reduce data from any 5-or 7-hole probe in a subsonic flow field and generate very accurate predictions of the velocity magnitude and direction, total and static pressure, Mach and Reynolds member and fluid properties like the density and viscosity. The algorithm utilizes a local least-squares modeling technique and has been tested on 4 novel miniature 7-hole probes that have been calibrated at NASA Langley Flow Modeling and Control Branch for the entire subsonic regime. Each of the probes had a conical tip with diameter of 0.065''. Excellent prediction capabilities are demonstrated with maximum errors in angle prediction less than 0.6 degrees and maximum errors in velocity prediction less than 1%, both with 99 percent confidence. The development of Micro Electro Mechanical Systems (MEMS) -based, fast-response, multi-sensor pressure probes of miniature size for velocity and pressure measurement applications in unsteady and turbulent flow gelds is also discussed. A new type of pressure sensor has been developed with silicon-nitride diaphragm and a characteristic size of only 250 gm. These pressure sensors are small enough to be mounted close to the surface of a miniature hemispherical-tip probe, obtaining a probe bandwidth and a theoretical frequency response up to 100 kl-lz. Both computational and experimental approaches are employed to develop calibration techniques suitable for highly unsteady flow environments with strong spatial gradients.

Johansen, Espen S

1998-01-01T23:59:59.000Z

226

Formulation of Non-steady-state Dust Formation Process in Astrophysical Environments  

E-Print Network (OSTI)

The non-steady-state formation of small clusters and the growth of grains accompanied by chemical reactions are formulated under the consideration that the collision of key gas species (key molecule) controls the kinetics of dust formation process. The formula allows us to evaluate the size distribution and condensation efficiency of dust formed in astrophysical environments. We apply the formulation to the formation of C and MgSiO3 grains in the ejecta of supernovae, as an example, to investigate how the non-steady effect influences the formation process, condensation efficiency f_{con}, and average radius a_{ave} of newly formed grains in comparison with the results calculated with the steady-state nucleation rate. We show that the steady-state nucleation rate is a good approximation if the collision timescale of key molecule tau_{coll} is much smaller than the timescale tau_{sat} with which the supersaturation ratio increases; otherwise the effect of the non-steady state becomes remarkable, leading to a lo...

Nozawa, Takaya

2013-01-01T23:59:59.000Z

227

Steam Generator Management Program: Dynamic Analysis of a Steam Generator--Part 1: Method Development, Steady-State Verification, an d Steady-State Validation  

Science Conference Proceedings (OSTI)

This report is the first of a two-part set that details the development and application of a new software model for steam generator dynamic analysis. This report contains the background and development of the steam generator dynamic analysis model and the steady-state verification and validation results. The second report (to be published in early 2013) is expected to contain results from simulations that illustrate the effect of tube support plate clogging levels on the onset of water level instability ...

2012-06-28T23:59:59.000Z

228

Award Types  

NLE Websites -- All DOE Office Websites (Extended Search)

nuclear deterrent; reduce global threats; and solve other emerging national security and energy challenges. Contact Awards Team (505) 667-7824 Email Types of Awards The Awards...

229

A New Type of Steady and Stable, Laminar, Premixed Flame in Ultra-Lean, Hydrogen-Air Combustion  

E-Print Network (OSTI)

Joulin, P. Ronney, Combust. Flame 84 (1991) 411–422. [9] I.R. A. Strehlow, Combust. Flame 49 (1983) 123–140. [11] B.F. A. Williams, Combust. Flame 33 (1978) 33–45. [12] T.

Grcar, Joseph F

2008-01-01T23:59:59.000Z

230

A New Type of Steady and Stable, Laminar, Premixed Flame in Ultra-Lean, Hydrogen-Air Combustion  

E-Print Network (OSTI)

411–422. [9] I. Glassman, Combustion, 3rd Edition, AcademicB. Lewis, G. von Elbe, Combustion, Flames and Explosions ofin Ultra-Lean, Hydrogen-Air Combustion Joseph F. Grcar a a

Grcar, Joseph F

2008-01-01T23:59:59.000Z

231

Constraints On The Mechanism Of Long-Term, Steady Subsidence At Medicine  

Open Energy Info (EERE)

Constraints On The Mechanism Of Long-Term, Steady Subsidence At Medicine Constraints On The Mechanism Of Long-Term, Steady Subsidence At Medicine Lake Volcano, Northern California, From Gps, Leveling, And Insar Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Constraints On The Mechanism Of Long-Term, Steady Subsidence At Medicine Lake Volcano, Northern California, From Gps, Leveling, And Insar Details Activities (2) Areas (1) Regions (0) Abstract: Leveling surveys across Medicine Lake volcano (MLV) have documented subsidence that is centered on the summit caldera and decays symmetrically on the flanks of the edifice. Possible mechanisms for this deformation include fluid withdrawal from a subsurface reservoir, cooling/crystallization of subsurface magma, loading by the volcano and dense intrusions, and crustal thinning due to tectonic extension (Dzurisin

232

History-independence of steady-state in simultaneous two-phase flow through porous media  

E-Print Network (OSTI)

It is well known that the transient behavior during drainage or imbibition in multiphase flow in porous media strongly depends on the history and initial condition of the system. However, when the steady-state regime is reached and both drainage and imbibition take place at the pore level, the influence of the evolution history and initial preparation is an open question. Here, we present an extensive experimental and numerical work investigating the history dependence of simultaneous steady-state two-phase flow through porous media. Our experimental system consists of a Hele-Shaw cell filled with glass beads which we model numerically by a network of disordered pores transporting two immiscible fluids. From the measurements of global pressure evolution, histogram of saturation and cluster-size distributions, we find that when both phases are flowing through the porous medium, the steady state does not depend on the initial preparation of the system or on the way it has been reached.

Erpelding, Marion; Tallakstad, Ken Tore; Hansen, Alex; Flekkøy, Eirik Grude; Måløy, Knut Jørgen

2013-01-01T23:59:59.000Z

233

Steady-state heat transfer in an inverted U-tube steam generator  

SciTech Connect

Experimental results are presented involving U-tube steam generator tube bundle local heat transfer and fluid conditions during steady-state, full-power operations performed at high temperatures and pressures with conditions typical of a pressurized water reactor (15.0 MPa primary pressure, 600 K hot-leg fluid temperatures, 6.2 MPa secondary pressure). The MOD-2C facility represents the state-of-the-art in measurement of tube local heat transfer data and average tube bundle secondary fluid density at several elevations, which allows an estimate of the axial heat transfer and void distributions during steady-state and transient operations. The method of heat transfer data reduction is presented and the heat flux, secondary convective heat transfer coefficient, and void fraction distributions are quantified for steady-state, full-power operations.

Boucher, T.J.

1986-01-01T23:59:59.000Z

234

SUPERENERGY-2: a multiassembly, steady-state computer code for LMFBR core thermal-hydraulic analysis  

SciTech Connect

Core thermal-hydraulic design and performance analyses for Liquid Metal Fast Breeder Reactors (LMFBRs) require repeated detailed multiassembly calculations to determine radial temperature profiles and subchannel outlet temperatures for various core configurations and subassembly structural analyses. At steady-state, detailed core-wide temperature profiles are required for core restraint calculations and subassembly structural analysis. In addition, sodium outlet temperatures are routinely needed for each reactor operating cycle. The SUPERENERGY-2 thermal-hydraulic code was designed specifically to meet these designer needs. It is applicable only to steady-state, forced-convection flow in LMFBR core geometries.

Basehore, K.L.; Todreas, N.E.

1980-08-01T23:59:59.000Z

235

Melanin Types  

NLE Websites -- All DOE Office Websites (Extended Search)

Melanin Types Melanin Types Name: Irfan Location: N/A Country: N/A Date: N/A Question: What are different types of melanins? And what are the functions of these types? Replies: Hi Irfan! Melanin is a dark compound or better a photoprotective pigment. Its major role in the skin is to absorb the ultraviolet (UV) light that comes from the sun so the skin is not damaged. Sun exposure usually produces a tan at the skin that represents an increase of melanin pigment in the skin. Melanin is important also in other areas of the body, as the eye and the brain., but it is not completely understood what the melanin pigment does in these areas. Melanin forms a special cell called melanocyte. This cell is found in the skin, in the hair follicle, and in the iris and retina of the eye.

236

Type systems  

Science Conference Proceedings (OSTI)

The study of type systems has emerged as one of the most active areas of research in programming languages, with applications in software engineering, language design, high-performance compiler implementation, and security. This chapter discusses the ...

Benjamin C. Pierce

2003-01-01T23:59:59.000Z

237

Simple Solutions to Steady-State Cumulus Regimes in the Convective Boundary Layer  

Science Conference Proceedings (OSTI)

A modeling framework is developed that extends the mixed-layer model to steady-state cumulus convection. The aim is to consider the simplest model that retains the essential behavior of cumulus-capped layers. The presented framework allows for the ...

Jerôme Schalkwijk; Harmen J. J. Jonker; A. Pier Siebesma

2013-11-01T23:59:59.000Z

238

Simulated Annealing: A Tool for Data Assimilation into an Almost Steady Model State  

Science Conference Proceedings (OSTI)

A new method is used to calculate a steady-state best fit of a given strongly nonlinear time-dependent model to observed data. The proposed technique has a statistical nature and is known as simulated annealing. It is described in detail and two ...

J. Kruger

1993-04-01T23:59:59.000Z

239

The Role of Integration Time in Determining a Steady State through Data Assimilation  

Science Conference Proceedings (OSTI)

The length of time an ocean model and its adjoint should be integrated in determining a steady state compatible with observed data is investigated. The starting point is based upon a suggestion that only one time step is required. This method ...

Jochem Marotzke

1992-12-01T23:59:59.000Z

240

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

DOE Green Energy (OSTI)

Assess the steady-state flammability level at normal and off-normal ventilation conditions. The hydrogen generation rate was calculated for 177 tanks using the rate equation model. Flammability calculations based on hydrogen, ammonia, and methane were performed for 177 tanks for various scenarios.

HU TA

2009-10-26T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Further Criteria for the Existence of Steady Line-Driven Winds  

E-Print Network (OSTI)

In Paper I, we showed that steady line-driven disk wind solutions can exist by using "simple" models that mimic the disk environment. Here I extend the concepts introduced in Paper I and discuss many details of the analysis of the steady/unsteady nature of 1D line-driven winds. This work confirms the results and conclusions of Paper I, and is thus consistent with the steady nature of the 1D streamline line-driven disk wind models of Murray and collaborators and the 2.5D line-driven disk wind models of Pereyra and collaborators. When including gas pressures effects, as is routinely done in time-dependent numerical models, I find that the spatial dependence of the nozzle function continues to play a key role in determining the steady/unsteady nature of supersonic line-driven wind solutions. I show here that the existence/nonexistence of local wind solutions can be proved through the nozzle function without integrating the equation of motion. This work sets a detailed framework with which we will analyze, in a following paper, more realistic models than the "simple" models of Paper I.

N. A. Pereyra

2004-12-19T23:59:59.000Z

242

Steady State Performance Analysis of a VSC-Based HVDC Converter Stations Using PSCAD/EMTDC  

Science Conference Proceedings (OSTI)

This paper presents a steady state performance analysis carried out to study the behavior of a two VSC-based operating as a single-input single output HVDC link. The digital model of the HVDC link has been implemented and evaluated using PSCAD/EMTDC©. ... Keywords: Voltage source converter, HVDC Stations, pulse width modulation, harmonic spectra

Eduardo Vásquez-Mortera; Edgar L. Moreno-Goytia

2008-09-01T23:59:59.000Z

243

Equatorward Propagation of Inertia–Gravity Waves due to Steady and Intermittent Wave Sources  

Science Conference Proceedings (OSTI)

A simple ray-tracing model for the equatorward propagation of inertia–gravity waves in the lower stratosphere is investigated. The model is based on a zonally symmetric wave source and incorporates radiative wave damping. It is shown that steady ...

Oliver Bühler

2003-06-01T23:59:59.000Z

244

Conjugate Effects on Steady Laminar Natural Convection Heat Transfer in Vertical Eccentric Annuli  

E-Print Network (OSTI)

Local heat flux on outer interface at channel exit i Index for bi-polar grid in the -directionConjugate Effects on Steady Laminar Natural Convection Heat Transfer in Vertical Eccentric Annuli University of Petroleum and Minerals, Dhahran, Saudi Arabia Combined conduction-free convection heat transfer

Jamal, Ahmad

245

On the Steady-State Energy Balance of Short Gravity Wave Systems  

Science Conference Proceedings (OSTI)

Steady-state energy balances of short gravity wave systems generated in a wave tank with and without airflow have been measured and compared with the predictions of perturbation theory. Wind-wave spectra were found to fit a JONSWAP form to a good ...

William J. Plant

1980-09-01T23:59:59.000Z

246

System and method for generating steady state confining current for a toroidal plasma fusion reactor  

SciTech Connect

A system for generating steady state confining current for a toroidal plasma fusion reactor providing steady-state generation of the thermonuclear power. A dense, hot toroidal plasma is initially prepared with a confining magnetic field with toroidal and poloidal components. Continuous wave RF energy is injected into said plasma to establish a spectrum of traveling waves in the plasma, where the traveling waves have momentum components substantially either all parallel, or all anti-parallel to the confining magnetic field. The injected RF energy is phased to couple to said traveling waves with both a phase velocity component and a wave momentum component in the direction of the plasma traveling wave components. The injected RF energy has a predetermined spectrum selected so that said traveling waves couple to plasma electrons having velocities in a predetermined range .DELTA.. The velocities in the range are substantially greater than the thermal electron velocity of the plasma. In addition, the range is sufficiently broad to produce a raised plateau having width .DELTA. in the plasma electron velocity distribution so that the plateau electrons provide steady-state current to generate a poloidal magnetic field component sufficient for confining the plasma. In steady state operation of the fusion reactor, the fusion power density in the plasma exceeds the power dissipated in the plasma.

Fisch, Nathaniel J. (Cambridge, MA)

1981-01-01T23:59:59.000Z

247

System and method for generating steady state confining current for a toroidal plasma fusion reactor  

SciTech Connect

A system for generating steady state confining current for a toroidal plasma fusion reactor providing steady-state generation of the thermonuclear power. A dense, hot toroidal plasma is initially prepared with a confining magnetic field with toroidal and poloidal components. Continuous wave RF energy is injected into said plasma to estalish a spectrum of traveling waves in the plasma, where the traveling waves have momentum components substantially either all parallel, or all anti-parallel to the confining magnetic field. The injected RF energy is phased to couple to said traveling waves with both a phase velocity component and a wave momentum component in the direction of the plasma traveling wave components. The injected RF energy has a predetermined spectrum selected so that said traveling waves couple to plasma electrons having velocities in a predetermined range .DELTA.. The velocities in the range are substantially greater than the thermal electron velocity of the plasma. In addition, the range is sufficiently broad to produce a raised plateau having width .DELTA. in the plasma electron velocity distribution so that the plateau electrons provide steady-state current to generate a poloidal magnetic field component sufficient for confining the plasma. In steady state operation of the fusion reactor, the fusion power density in the plasma exceeds the power dissipated inthe plasma.

Bers, Abraham (Arlington, MA)

1981-01-01T23:59:59.000Z

248

The Hybrid Solid Oxide Fuel Cell (SOFC) and Gas Turbine (GT) Systems Steady State Modeling  

E-Print Network (OSTI)

The Hybrid Solid Oxide Fuel Cell (SOFC) and Gas Turbine (GT) Systems Steady State Modeling Penyarat plants offer high cycle efficiencies. In this work a hybrid solid oxide fuel cell and gas turbine power, Gas turbine, Hybrid, Solid Oxide Fuel Cell hal-00703135,version1-31May2012 Author manuscript

Paris-Sud XI, Université de

249

A Method for Direct Solution of a Steady Linearized Spectral General Circulation Model  

Science Conference Proceedings (OSTI)

A steady linearized version of a general circulation model (GCM) is a potentially useful tool for diagnosis and understanding of the time-mean solutions of the GCM. A method is developed for direct solution of the linearized equations. The method ...

Edwin K. Schneider

1989-10-01T23:59:59.000Z

250

A Nonlinear Steady-State Model of the North Water Polynya, Baffin Bay  

Science Conference Proceedings (OSTI)

A nonlinear, steady-state model of the North Water (NOW), the Arctic's largest polynya, is presented. The model follows in the spirit of the recently developed latent and sensible heat polynya model of Mysak and Huang, but extends it in several ...

M. S. Darby; A. J. Willmott; L. A. Mysak

1994-05-01T23:59:59.000Z

251

ASHRAE Transactions: Research 3 A steady-state simulation model for a water-to-water  

E-Print Network (OSTI)

ASHRAE Transactions: Research 3 ABSTRACT A steady-state simulation model for a water Jeffrey D. Spitler, Ph.D., P.E. Student Member ASHRAE Member ASHRAE Hui Jin is a graduate student-Conditioning Engineers, Inc. (www.ashrae.org). Published in ASHRAE Transactions 2002, Vol 108, P

252

Numerical simulation of steady and unsteady mixed convection from tubes of elliptic cross-section  

Science Conference Proceedings (OSTI)

The problem of two-dimensional laminar mixed convection (forced and free convection) from a tube of elliptic cross-section has been numerically simulated for the cases when the approaching flow is either steady or fluctuating. The elliptic cross-section ... Keywords: elliptic tube, fluctuating flow, heat transfer, mixed convection

H. M. Badr; E. H. Ahmed

2002-09-01T23:59:59.000Z

253

Ultraviolet Spectra of CV Accretion Disks with Non-Steady T(r) Laws  

E-Print Network (OSTI)

An extensive grid of synthetic mid- and far-ultraviolet spectra for accretion disks in cataclysmic variables has been presented by Wade and Hubeny (1998). In those models, the disk was assumed to be in steady-state, that is T_eff(r) is specified completely by the mass M_WD and radius R_WD of the accreting white dwarf star and the mass transfer rate M_dot which is constant throughout the disk. In these models, T_eff(r) is proportional to r^{-3/4} except as modified by a cutoff term near the white dwarf. Actual disks may vary from the steady-state prescription for T_eff(r), however, e.g. owing to outburst cycles in dwarf novae M_dot not constant with radius) or irradiation (in which case T_eff in the outer disk is raised above T_steady). To show how the spectra of such disks might differ from the steady case, we present a study of the ultraviolet (UV) spectra of models in which power-law temperature profiles T_eff(r) is proportional to r^{-gamma} with gamma < 3/4 are specified. Otherwise, the construction of...

Orosz, J A; Orosz, Jerome A.; Wade, Richard A.

2003-01-01T23:59:59.000Z

254

On Steady Salinity Distribution and Circulation in Partially Mixed and Well Mixed Estuaries  

Science Conference Proceedings (OSTI)

Perturbation analysis based on small ? = Ra0.23Fm0.9, where Ra is the Rayleigh number and Fm is the Froude number, is used to study steady-state circulation and salinity distribution in estuaries. The classical Hansen and Rattray's similarity ...

Li-Yauw Oey

1984-03-01T23:59:59.000Z

255

Steady decline of east Asian monsoon winds, 19692000: Evidence from direct ground measurements of wind speed  

E-Print Network (OSTI)

Steady decline of east Asian monsoon winds, 1969­2000: Evidence from direct ground measurements winter monsoon but strengthen the summer monsoon, because of stronger warming over high-latitude land with the east Asian monsoon has significantly weakened in both winter and summer in the recent three decades

Chang, Chih-Pei

256

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

DOE Green Energy (OSTI)

Assess the steady-state flammability level at normal and off-normal ventilation conditions. The hydrogen generation rate was calculated for 177 tanks using the rate equation model. Flammability calculations based on hydrogen, ammonia, and methane were performed for 177 tanks for various scenarios.

HU, T.A.

2005-10-27T23:59:59.000Z

257

On the Rossby Wave Source and the Steady Linear Response to Tropical Forcing  

Science Conference Proceedings (OSTI)

A two-level spectral model with a zonally homogeneous climate is used to study the steady response of a spherical atmosphere to tropical heating. Solutions are obtained by both averaging the time integration of the model and solving for the ...

Jianchun Qin; Walter A. Robinson

1993-06-01T23:59:59.000Z

258

Steady-State Diagnostic Model of Summer Mean Circulation on the Georgia Shelf  

Science Conference Proceedings (OSTI)

The Galt (1975) diagnostic model was used to investigate summer circulation on the Georgia shelf. The steady-state model uses a finite-element method to solve the depth-integrated vorticity equation for sea surface elevation over the model domain ...

Thomas N. Lee; Ernest Daddio; Gregory C. Han

1982-08-01T23:59:59.000Z

259

PROCESS DESIGN AND CONTROL Steady-State Operational Degrees of Freedom with Application to Refrigeration  

E-Print Network (OSTI)

PROCESS DESIGN AND CONTROL Steady-State Operational Degrees of Freedom with Application to Refrigeration Cycles Jørgen Bauck Jensen and Sigurd Skogestad* Department of Chemical Engineering, Norwegian Uni of the circulating refrigerant are also discussed. Two liquified natural gas (LNG) processes of current interest

Skogestad, Sigurd

260

Steady Wind-driven Upwelling in the Presence of a Baroclinic Coastally Trapped Jet  

Science Conference Proceedings (OSTI)

The usual two-layer model for steady wind-driven upwelling along a uniform coastline is extended to incorporate the effects of an upper-layer jet trapped against the coast. The characteristic width of the jet is the internal deformation radius, ...

A. E. Hay; E. D. Kinsella

1986-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

The Three-Dimensional Steady Circulation in a Homogenous Ocean Induced by a Stationary Hurricane  

Science Conference Proceedings (OSTI)

Based on the classical Ekman layer theory, a simple analytical solution of the steady flow induced by a stationary hurricane in a homogenous ocean is discussed. The model consists of flow converging in an inward spiral in the deeper layer and ...

Zhu Min Lu; Rui Xin Huang

2010-07-01T23:59:59.000Z

262

Reply to “Comments on ‘On the Steadiness of Separating Meandering Currents’”  

Science Conference Proceedings (OSTI)

The authors thank Nof et al. for their comments on the authors’ paper “On the steadiness of separating meandering currents.” The authors’ paper was motivated by a series of papers by Nof et al. Under a certain set of conditions (reduced gravity, ...

Peter Jan van Leeuwen; W. P. M. De Ruijter

2012-08-01T23:59:59.000Z

263

Statistical Analysis of Steady State Leakage Currents in Nano-CMOS Devices  

E-Print Network (OSTI)

Statistical Analysis of Steady State Leakage Currents in Nano-CMOS Devices Jawar Singh, Jimson, UK. Department of Computer Science and Engineering, University of North Texas, USA. jawar also propose a statistical model to characterize nano-scale CMOS device characteristics such as dynamic

Mohanty, Saraju P.

264

Steady State Flammable Gas Release Rate Calculation and Lower Flammability Level Evaluation for Hanford Tank Waste  

DOE Green Energy (OSTI)

Assess the steady-state flammability level at normal and off-normal ventilation conditions. Hydrogen generation rate was calculated for 177 tanks using rate equation model. Ammonia liquid/vapor equilibrium model is incorporated into the methodology for ammonia analysis.

HU, T.A.

2001-02-23T23:59:59.000Z

265

Steady State Flammable Gas Release Rate Calculation and Lower Flammability Level Evaluation for Hanford Tank Waste  

DOE Green Energy (OSTI)

This work is to assess the steady-state flammability level at normal and off-normal ventilation conditions in the tank dome space for 177 double-shell and single-shell tanks at Hanford. Hydrogen generation rate was calculated for 177 tanks using rate equation model developed recently.

HU, T.A.

2000-04-27T23:59:59.000Z

266

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

DOE Green Energy (OSTI)

Assess the steady-state flammability level at normal and off-normal ventilation conditions. The hydrogen generation rate was calculated for 177 tanks using the rate equation model. Flammability calculations based on hydrogen, ammonia, and methane were performed for 177 tanks for various scenarios.

HU, T.A.

2004-10-27T23:59:59.000Z

267

The existence theorem for steady Navier--Stokes equations in the axially symmetric case  

E-Print Network (OSTI)

We study the nonhomogeneous boundary value problem for Navier-Stokes equations of steady motion of a viscous incompressible fluid in a three-dimensional bounded multiply connected domain. We prove that this problem has a solution in some axially symmetric cases, in particular, when all components of the boundary intersect the axis of symmetry.

Mikhail Korobkov; Konstantin Pileckas; Remigio Russo

2011-10-28T23:59:59.000Z

268

An implicit steady-state initialization package for the RELAP5 computer code  

Science Conference Proceedings (OSTI)

A direct steady-state initialization (DSSI) method has been developed and implemented in the RELAP5 hydrodynamic analysis program. It provides a means for users to specify a small set of initial conditions which are then propagated through the remainder of the system. The DSSI scheme utilizes the steady-state form of the RELAP5 balance equations for nonequilibrium two-phase flow. It also employs the RELAP5 component models and constitutive model packages for wall-to-phase and interphase momentum and heat exchange. A fully implicit solution of the linearized hydrodynamic equations is implemented. An implicit coupling scheme is used to augment the standard steady-state heat conduction solution for steam generator use. It solves the primary-side tube region energy equations, heat conduction equations, wall heat flux boundary conditions, and overall energy balance equation as a coupled system of equations and improves convergence. The DSSI method for initializing RELAP5 problems to steady-state conditions has been compared with the transient solution scheme using a suite of test problems including; adiabatic single-phase liquid and vapor flow through channels with and without healing and area changes; a heated two-phase test bundle representative of BWR core conditions; and a single-loop PWR model.

Paulsen, M.P.; Peterson, C.E.; Odar, F.

1995-08-01T23:59:59.000Z

269

Steady-State Large-Eddy Simulations to Study the Stratocumulus to Shallow Cumulus Cloud Transition  

Science Conference Proceedings (OSTI)

This study presents a series of steady-state large-eddy simulations (LESs) to study the stratocumulus to shallow cumulus cloud transition. To represent the different stages of what can be interpreted as an Eulerian view of the transition, each ...

D. Chung; G. Matheou; J. Teixeira

2012-11-01T23:59:59.000Z

270

Rayleigh Friction, Newtonian Cooling, and the Linear Response to Steady Tropical Heating  

Science Conference Proceedings (OSTI)

A series of studies are performed to examine the response of the tropical atmosphere to a prescribed steady, large-scale, elevated heat source (i.e., a region of persistent precipitation). Special emphasis is placed on the surface wind response ...

Zhaohua Wu; David S. Battisti; E. S. Sarachik

2000-06-01T23:59:59.000Z

271

Model relaxations for the fuel cost minimization of steady-state gas pipeline networks  

Science Conference Proceedings (OSTI)

Natural gas, driven by pressure, is transported through pipeline network systems. As the gas flows through the network, energy and pressure are lost due to both friction between the gas and the pipes' inner wall, and heat transfer between the gas and ... Keywords: Compressor stations, Lower bounds, Natural gas, Nonconvex objective, Pipelines, Steady state, Transmission networks

Suming Wu; R. Z. Ríos-Mercado; E. A. Boyd; L. R. Scott

2000-01-01T23:59:59.000Z

272

Prediction of Retained Capacity and EODV of Li-ion Batteries in LEO Spacecraft Batteries  

E-Print Network (OSTI)

In resent years ANN is widely reported for modeling in different areas of science including electro chemistry. This includes modeling of different technological batteries such as lead acid battery, Nickel cadmium batteries etc. Lithium ion batteries are advance battery technology which satisfy most of the space mission requirements. Low earth orbit (LEO)space craft batteries undergo large number of charge discharge cycles (about 25000 cycles)compared to other ground level or space applications. This study is indented to develop ANN model for about 25000 cycles, cycled under various temperature, Depth Of Discharge (DOD) settings with constant charge voltage limit to predict the retained capacity and End of Discharge Voltage (EODV). To extract firm conclusion and distinguish the capability of ANN method, the predicted values are compared with experimental result by statistical method and Bland Altman plot.

Ramakrishnan, S; Jeyakumar, A Ebenezer

2010-01-01T23:59:59.000Z

273

Advanced Solid State Li-Ion Battery Vaccine for Prevention and ...  

not carry the safety burdens of liquid electrolytes and are more ... Glass–ceramic Li2S–P2S5 electrolytes prepared by a single step ball billing process and

274

Thermal/Electrical Modeling for Abuse-Tolerant Design of Li-Ion Modules (Presentation)  

DOE Green Energy (OSTI)

To help design safe, high-performing batteries, NREL and NASA created and verified a new multicell math model capturing electrical-thermal interactions of cells with PTC devices during thermal abuse.

Smith, K.; Kim, G.-H.; Pesaran, A.; Darcy, E.

2008-11-01T23:59:59.000Z

275

Sulfone-based electrolytes for high voltage li-ion batteries.  

Science Conference Proceedings (OSTI)

Sulfone-based electrolytes have been investigated as electrolytes for lithium-ion cells using high-voltage positive electrodes, such as LiMn{sub 2}O{sub 4} and LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} spinels, and Li{sub 4}Ti{sub 5}O{sub 12} spinel as negative electrode. In the presence of imide salt (LiTFSI) and ethyl methyl sulfone or tetramethyl sulfone (TMS) electrolytes, the Li{sub 4}Ti{sub 5}O{sub 12}/LiMn{sub 2}O{sub 4} cell exhibited a specific capacity of 80 mAh g{sup -1} with an excellent capacity retention after 100 cycles. In a cell with high-voltage LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} positive electrode and 1 M LiPF{sub 6} in TMS as electrolyte, the capacity reached 110 mAh g{sup -1} at the C/12 rate. When TMS was blended with ethyl methyl carbonate, the Li{sub 4}Ti{sub 5}O{sub 12}/LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} cell delivered an initial capacity of 80 mAh g{sup -1} and cycled fairly well for 1000 cycles under 2C rate. The exceptional electrochemical stability of the sulfone electrolytes and their compatibility with the Li{sub 4}Ti{sub 5}O{sub 12} safer and stable anode were the main reason behind the outstanding electrochemical performance observed with high-potential spinel cathode materials. These electrolytes could be promising alternative electrolytes for high-energy density battery applications such as plug-in hybrid and electric vehicles that require a long cycle life.

Abouimrane, A.; Belharouak, I.; Amine, K. (Chemical Sciences and Engineering Division)

2009-05-01T23:59:59.000Z

276

Thin Film Patterned Sandwich Anode Structures for Li-Ion batteries  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, 2013 TMS Annual Meeting & Exhibition. Symposium , Nanostructured Materials for Lithium Ion Batteries and for Supercapacitors.

277

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network (OSTI)

electric vehicle (PEV), performance requirements are raised especially from the aspects of energy/power density, cycling life and safety

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

278

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network (OSTI)

Coating for Lithium-Ion Battery Cathodes", Chemistry ofas the cathode of the lithium ion battery by Thackeray et

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

279

LI-ION BATTERIESWITH LONGER LIFE, LOWER COST, AND BETTER SAFETY  

E-Print Network (OSTI)

materials that include LiFePO4 for use in, but not limited to, electrode materials for lithium-ion batteries cathode manufacturing processes. Lithium Iron Phosphate Composites for Lithium Batteries (ANL-IN-11 functionality for high power and high energy lithium batteries. The Invention A family of lithium iron composite

Kemner, Ken

280

Screening report on cell materials for high-power Li-Ion HEV batteries.  

DOE Green Energy (OSTI)

The Battery Technology Department at Argonne National Laboratory is a major participant in the U.S. Department of Energy's Advanced Technology Development (ATD) program. This multi-national laboratory program is dedicated to improving lithium-ion batteries for high-power HEV and FCEV applications. As part of the FreedomCAR Partnership, this program is addressing the three key barriers for high-power lithium-ion batteries: calendar life, abuse tolerance, and cost. All three of these barriers can be addressed by the choice of materials used in the cell chemistry. To date, the ATD program has developed two high-power cell chemistries, denoted our Gen 1 and Gen 2 cell chemistries. The selection of materials for use in the Gen 2 cell chemistry was based largely on reducing material cost and extending cell calendar life, relative to our Gen 1 cell chemistry. Table 1 provides a list of the materials used in our Gen 2 cell chemistry and their projected costs, when produced in large-scale quantities. In evaluating advanced materials, we have focused our efforts on materials that are lower cost than those listed in Table 1, while simultaneously offering enhanced chemical, structural, and thermal stability. Therefore, we have focused on natural graphite anode materials (having round-edge particle morphologies), cathode materials that contain more Mn and less Co and Ni (which can be produced via low-cost processes), lower cost electrode binders and/or binders that possess superior bonding properties at lower concentrations, and lower cost salts and solvents (with superior thermal and oxidation/reduction stability) for use in the electrolyte. The purpose of this report is to document the results of screening tests that were performed on a large number of advanced low-cost materials. These materials were screened for their potential to impact positively on the calendar life, safety, and/or cost of high-power lithium-ion cell chemistries, relative to our Gen 2 cell chemistry. As part of this effort, we developed and employed a set of standard test protocols to evaluate all of the materials. After brief descriptions of the screening test methodologies and equipment, relevant data on each material are summarized in the body of this report. We have evaluated five categories of materials, and the report is organized accordingly. Results will be presented on advanced carbons for anodes, improved cathode materials, new salts and solvent systems, alternative binders, and novel separators.

Liu, J.; Kahaian, A.; Belharouak, I.; Kang, S.; Oliver, S.; Henriksen, S.; Amine, K.

2003-04-24T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Electrochimica Acta 51 (2006) 20122022 A generalized cycle life model of rechargeable Li-ion batteries  

E-Print Network (OSTI)

· Gas evolution Cathode Aging Image: Vetter et al., "Ageing mechanisms in lithium-ion batteries," J Battery Robust Design - 13 Cathode Aging Source: Vetter et al., "Ageing mechanisms in lithium-ion., "Ageing mechanisms in lithium- ion batteries," J. Power Sources, 147 (2005) 269-281 ASTR 2010 Oct 6 ­ 8

Popov, Branko N.

282

Battery management system for Li-Ion batteries in hybrid electric vehicles.  

E-Print Network (OSTI)

??The Battery Management System (BMS) is the component responsible for the effcient and safe usage of a Hybrid Electric Vehicle (HEV) battery pack. Its main… (more)

Marangoni, Giacomo

2010-01-01T23:59:59.000Z

283

Li-Ion Nanobattery: Lessons from In-Situ Electron Microscopy  

Science Conference Proceedings (OSTI)

3D Nanostructured Bicontinuous Electrodes: Path to Ultra-High Power and Energy ... High Energy Density Lithium Capacitors Using Carbon-Carbon Electrodes.

284

Computer-Aided Engineering of Batteries for Designing Better Li-Ion Batteries (Presentation)  

DOE Green Energy (OSTI)

This presentation describes the current status of the DOE's Energy Storage R and D program, including modeling and design tools and the Computer-Aided Engineering for Automotive Batteries (CAEBAT) program.

Pesaran, A.; Kim, G. H.; Smith, K.; Lee, K. J.; Santhanagopalan, S.

2012-02-01T23:59:59.000Z

285

Fail-Safe Design for Large Capacity Li-Ion Battery Systems  

candidate for energy storage of electric drive vehicles due to their high power and energy density. The total electric vehicle LIB market shipped 2,400 units in 2008 generating over $28 million in revenue and is predicted to be greater than $10 ...

286

Microsoft PowerPoint - NanoAnode for Li-ion Batteries SRNL-L9100...  

NLE Websites -- All DOE Office Websites (Extended Search)

Anodes for Lithium-Ion Batteries at a glance patent pending increase energy density longer cyclic life replaces graphite anodes simple and lower cost...

287

LIFETIME OF THE METASTABLE 23S1 STATE IN STORED Li+ IONS  

E-Print Network (OSTI)

with an oven consisting of resistive heating elementsoven is lowered over the main chamber, which is resting on a Maronite base, and heatingand heating coil in order to minimize radiation losses to the walls. This oven,

Knight, R.D.

2010-01-01T23:59:59.000Z

288

Source fabrication and lifetime for Li+ ion beams extracted from alumino-silicate sources  

Science Conference Proceedings (OSTI)

A space-charge-limited beam with current densities (J) exceeding 1 mA/cm{sup 2} have been measured from lithium alumino-silicate ion sources at a temperature of #24;~1275#14;{degrees} C. At higher extraction voltages, the source appears to become emission limited with J #21;{>=} 1.5 mA/cm{sup 2}, and J increases weakly with the applied voltage. A 6.35 mm diameter source with an alumino-silicate coating, {<=}#20;0.25 mm thick, has a measured lifetime of ~#24;40 hours at ~#24;1275#14;{degrees} C, when pulsed at 0.05 Hz and with pulse length of #24;~6 ?s each. At this rate, the source lifetime was independent of the actual beam charge extracted due to the loss of neutral atoms at high temperature. The source lifetime increases with the amount of alumino-silicate coated on the emitting surface, and may also be further extended if the temperature is reduced between pulses.

Roy, Prabir K.; Greenway, Wayne G.; Kwan, Joe W

2012-03-05T23:59:59.000Z

289

Source fabrication and lifetime for Li+ ion beams extracted from alumino-silicate sources  

SciTech Connect

A space-charge-limited beam with current densities (J) exceeding 1 mA/cm{sup 2} have been measured from lithium alumino-silicate ion sources at a temperature of #24;~1275#14;{degrees} C. At higher extraction voltages, the source appears to become emission limited with J #21;{>=} 1.5 mA/cm{sup 2}, and J increases weakly with the applied voltage. A 6.35 mm diameter source with an alumino-silicate coating, {<=}#20;0.25 mm thick, has a measured lifetime of ~#24;40 hours at ~#24;1275#14;{degrees} C, when pulsed at 0.05 Hz and with pulse length of #24;~6 μs each. At this rate, the source lifetime was independent of the actual beam charge extracted due to the loss of neutral atoms at high temperature. The source lifetime increases with the amount of alumino-silicate coated on the emitting surface, and may also be further extended if the temperature is reduced between pulses.

Roy, Prabir K.; Greenway, Wayne G.; Kwan, Joe W

2012-03-05T23:59:59.000Z

290

Structural Complexity of Layered-spinel Composite Electrodes for Li-ion Batteries  

DOE Green Energy (OSTI)

The complexity of layered-spinel yLi{sub 2}MnO{sub 3} {center_dot} (1-y)Li{sub 1+x}Mn{sub 2-x}O{sub 4} (Li:Mn = 1.2:1; 0 = x = 0.33; y = 0.45) composites synthesized at different temperatures has been investigated by a combination of x-ray diffraction (XRD), x-ray absorption spectroscopy (XAS), and nuclear magnetic resonance (NMR). While the layered component does not change substantially between samples, an evolution of the spinel component from a high to a low lithium excess phase has been traced with temperature by comparing with data for pure Li{sub 1+x}Mn{sub 2-x}O{sub 4}. The changes that occur to the structure of the spinel component and to the average oxidation state of the manganese ions within the composite structure as lithium is electrochemically removed in a battery have been monitored using these techniques, in some cases in situ. Our 6Li NMR results constitute the first direct observation of lithium removal from Li{sub 2}MnO{sub 3} and the formation of LiMnO{sub 2} upon lithium reinsertion.

Cabana, J.; Yang, X.; Johnson, C.S., Chung, K.-Y.; Yoon, W.-S.; Kang, S.-H.; Thackeray, M.M., Grey, C.P.

2010-08-01T23:59:59.000Z

291

Corrosion of current-collector materials in Li-ion cells  

DOE Green Energy (OSTI)

The primary current-collector materials being used in lithium-ion cells are susceptible to environmental degradation: aluminum to pitting corrosion and copper to environmentally assisted cracking. Pitting occurs at the highly oxidizing potentials associated with the positive-electrode charge condition. However, the pitting mechanism is more complex than that typically observed in aqueous systems in that the pits are filled with a mixed metal/oxide product and exist as mounds or nodules on the surface. Electrochemical impedance was shown to be an effective analytical tool for quantification and verification of visual observations and trends. Two fluorocarbon-based coatings were shown to improve the resistance of Al to localized pitting. Finally, environmental cracking of copper can occur at or near the lithium potential and only if specific metallurgical conditions exist (work hardening and large grain size).

Braithwaite, J.; Nagasubramanian, G.; Gonzales, A.; Lucero, S.; Cieslak, W.

1996-12-01T23:59:59.000Z

292

Degradation of the materials of construction in Li-ion batteries  

DOE Green Energy (OSTI)

The primary current-collector materials being used in lithium-ion cells are susceptible to environmental degradation: aluminum to pitting corrosion and copper to environmentally assisted cracking. Pitting occurs at the highly oxidizing potentials associated with the positive-electrode charge condition. However, the pitting mechanism is more complex than that typically observed in aqueous systems in that the pits are filled with a mixed metal/oxide product and exist as mounds or nodules on the surface. Electrochemical impedance spectroscopy was shown to be an effective analytical tool for quantifying and verifying aluminum corrosion behavior. Two fluorocarbon-based coatings were shown to improve the resistance of Al to pitting attack. Detailed x-ray photoelectron spectroscopy (XPS) surface analyses showed that there was very little difference in the films observed after simple immersion in either PC:DEC or EC:DMC electrolytes versus those following electrical cycling. Li and P are the predominant surface species. Finally, environmental cracking of copper can occur at or near the lithium potential and only if specific metallurgical conditions exist (work-hardening and large grain size).

Braithwaite, J.W.; Gonzales, A.; Lucero, S.J. [and others

1997-03-01T23:59:59.000Z

293

Challenges in Developing High Energy Density Li-ion Batteries with ...  

Science Conference Proceedings (OSTI)

The approaches that have been taken recently include the use of high voltage cathodes coupled with graphite or high capacity Li-alloy anodes. In either ...

294

Redox-active Ionic Liquids in Energy Storage: Application to Li-ion ...  

Science Conference Proceedings (OSTI)

Electric Cell-impedance Spectroscopy at the Biological-inorganic Interface, Shewanella Oneidensis - Gold, for Microbial Fuel Cell Applications · Encapsulating ...

295

Synthesis of LiCoO2 Cathodes for Li–Ion Batteries via Solution ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2011. Symposium, Energy Storage: Materials, Systems and Applications. Presentation Title ...

296

TransForum v8n1 - Li-Ion Battery Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

material, a key element of the material licensed to NanoeXa. Argonne's Lithium-Ion Battery Technology Offers Reliability, Greater Safety Argonnes an internationally...

297

Computer-Aided Engineering of Batteries for Designing Better Li-Ion Batteries (Presentation)  

SciTech Connect

This presentation describes the current status of the DOE's Energy Storage R and D program, including modeling and design tools and the Computer-Aided Engineering for Automotive Batteries (CAEBAT) program.

Pesaran, A.; Kim, G. H.; Smith, K.; Lee, K. J.; Santhanagopalan, S.

2012-02-01T23:59:59.000Z

298

Light-Metal Hydrides as Novel Conversion Mateirals for Li-ion ...  

Science Conference Proceedings (OSTI)

We present the phase diagram as a function of lithium chemical potential and ... 3D Nanostructured Bicontinuous Electrodes: Path to Ultra-High Power and Energy ... The Electrochemical Flow Capacitor for Efficient Grid-Scale Energy Storage.

299

3D Multiwall Carbon Nanotubes (MWCNTs) for Li-Ion Battery Anode  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, 2012 TMS Annual Meeting & Exhibition. Symposium , 2012 Functional and Structural Nanomaterials: Fabrication, Properties, ...

300

D4: In-situ Characterisation of Silicon-based Anodes for Li-ion ...  

Science Conference Proceedings (OSTI)

A8: Microstructural Investigation of Nano-Calcium Phosphates Doped with Fluoride Ions .... D7: Surfactant Structure–property Relationship: Effect of Polypropylene ... E4: The Effect of Monobutyl Ether Ethylene Glycol on the Conductivity and ...

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Maximum power point tracking and optimal Li-ion battery charging control for photovoltaic charging system  

Science Conference Proceedings (OSTI)

Due to the severity of the global energy crisis and environmental pollution, the photovoltaic (PV) system has become one kind of important renewable energy source. Solar energy has the advantages of maximum reserve, inexhaustibleness, and is free from ... Keywords: Genetic algorithms (GA), Photovoltaic (PV), Variable Step Size Incremental Conductance method

Her-Terng Yau; Qin-Cheng Liang; Chin-Tsung Hsieh

2012-09-01T23:59:59.000Z

302

Electrochemical Windows of Sulfone-Based Electrolytes for High-Voltage Li-Ion Batteries  

Science Conference Proceedings (OSTI)

Further development of high-voltage lithium-ion batteries requires electrolytes with electrochemical windows greater than 5 V. Sulfone-based electrolytes are promising for such a purpose. Here we compute the electrochemical windows for experimentally tested sulfone electrolytes by different levels of theory in combination with various solvation models. The MP2 method combined with the polarizable continuum model is shown to be the most accurate method to predict oxidation potentials of sulfone-based electrolytes with mean deviation less than 0.29 V. Mulliken charge analysis shows that the oxidation happens on the sulfone group for ethylmethyl sulfone and tetramethylene sulfone, and on the ether group for ether functionalized sulfones. Large electrochemical windows of sulfone-based electrolytes are mainly contributed by the sulfone group in the molecules which helps lower the HOMO level. This study can help understand the voltage limits imposed by the sulfone-based electrolytes and aid in designing new electrolytes with greater electrochemical windows.

Shao, Nan [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL; Jiang, Deen [ORNL

2011-01-01T23:59:59.000Z

303

Modeling of Nonuniform Degradation in Large-Format Li-ion Batteries (Poster)  

DOE Green Energy (OSTI)

Shows results of an empirical model capturing effects of both storage and cycling and developed the lithium ion nickel cobalt aluminum advanced battery chemistry.

Smith, K.; Kim, G. H.; Pesaran, A.

2009-06-01T23:59:59.000Z

304

Nanostructured 3.9 V Triplite Cathode Materials for Li-Ion Batteries  

Science Conference Proceedings (OSTI)

Microstructural Evolution of SnS Thin Films Grown by Electrodeposition · Morphology Engineering of 1D, 2D and 3D TiO2 Nanostructures and Their Application ...

305

Improved layered mixed transition metal oxides for Li-ion batteries  

E-Print Network (OSTI)

Radiation Lightsource (SSRL). We would like to acknowledgeMèhta for the work done at SSRL. REFERENCES [I] Yabuuchi,

Doeff, Marca M.

2010-01-01T23:59:59.000Z

306

Layer cathode methods of manufacturing and materials for Li-ion rechargeable batteries  

DOE Patents (OSTI)

A positive electrode active material for lithium-ion rechargeable batteries of general formula Li.sub.1+xNi.sub..alpha.Mn.sub..beta.A.sub..gamma.O.sub.2 and further wherein A is Mg, Zn, Al, Co, Ga, B, Zr, or Ti and 0

Kang, Sun-Ho (Naperville, IL); Amine, Khalil (Downers Grove, IL)

2008-01-01T23:59:59.000Z

307

Improved layered mixed transition metal oxides for Li-ion batteries  

E-Print Network (OSTI)

vehicles (EV), plug-in hybrid electric vehicles (PHEVs),or hybrid electric vehicles (HEVs). To reduce materialsapplications (plug-in hybrid electric vehicles (PHEVs) and

Doeff, Marca M.

2010-01-01T23:59:59.000Z

308

Conductive Rigid Skeleton Supported Silicon as High-Performance Li-Ion Battery Anodes  

Science Conference Proceedings (OSTI)

A cost effective and scalable method is developed to prepare a core-shell structured Si/B4C composite with graphite coating with high efficiency, exceptional rate performance and long-term stability. In this material, conductive B4C with high Mohs hardness serves not only as micro-/nano- millers in the ball-milling process to break down micron-sized Si but also as the conductive rigid skeleton to support the in-situ formed sub-10 nm Si particles to alleviate the volume expansion during charge/discharge. The Si/B4C composite is coated with a few graphitic layers to further improve the conductivity and stability of the composite. The Si/B4C/graphite (SBG) composite anode shows excellent cyclability with a specific capacity of ~822 mAh?g-1 (based on the weight of the entire electrode, including binder and conductive carbon) and ~94% capacity retention over 100 cycles at 0.8C rate. This new structure has the potential to provide adequate storage capacity and stability for practical applications, and good opportunity for large scale manufacturing using commercially available materials and technologies.

Chen, Xilin; Li, Xiaolin; Ding, Fei; Xu, Wu; Xiao, Jie; Cao, Yuliang; Meduri, Praveen; Liu, Jun; Graff, Gordon L.; Zhang, Jiguang

2012-08-08T23:59:59.000Z

309

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes  

SciTech Connect

Silicon is regarded as one of the most promising anode materials for next generation lithium-ion batteries. For use in practical applications, a Si electrode must have high capacity, long cycle life, high efficiency, and the fabrication must be industrially scalable. Here, we design and fabricate a yolk-shell structure to meet all these needs. The fabrication is carried out without special equipment and mostly at room temperature. Commercially available Si nanoparticles are completely sealed inside conformal, thin, self-supporting carbon shells, with rationally designed void space in between the particles and the shell. The well-defined void space allows the Si particles to expand freely without breaking the outer carbon shell, therefore stabilizing the solid-electrolyte interphase on the shell surface. High capacity (?2800 mAh/g at C/10), long cycle life (1000 cycles with 74% capacity retention), and high Coulombic efficiency (99.84%) have been realized in this yolk-shell structured Si electrode.

Liu, Nian; Wu, Hui; Mcdowell, Matthew T.; Yao, Yan; Wang, Chong M.; Cui, Yi

2012-05-02T23:59:59.000Z

310

Lipon Coatings for High Voltage and High Temperature Li-Ion ...  

use of high-capacity and high-voltage cathode materials, but charging to voltages approaching 4.5-5V invariably causes rapid loss of capacity with cycling.

311

Experimental design and analysis for accelerated degradation tests with Li-ion cells.  

DOE Green Energy (OSTI)

This document describes a general protocol (involving both experimental and data analytic aspects) that is designed to be a roadmap for rapidly obtaining a useful assessment of the average lifetime (at some specified use conditions) that might be expected from cells of a particular design. The proposed experimental protocol involves a series of accelerated degradation experiments. Through the acquisition of degradation data over time specified by the experimental protocol, an unambiguous assessment of the effects of accelerating factors (e.g., temperature and state of charge) on various measures of the health of a cell (e.g., power fade and capacity fade) will result. In order to assess cell lifetime, it is necessary to develop a model that accurately predicts degradation over a range of the experimental factors. In general, it is difficult to specify an appropriate model form without some preliminary analysis of the data. Nevertheless, assuming that the aging phenomenon relates to a chemical reaction with simple first-order rate kinetics, a data analysis protocol is also provided to construct a useful model that relates performance degradation to the levels of the accelerating factors. This model can then be used to make an accurate assessment of the average cell lifetime. The proposed experimental and data analysis protocols are illustrated with a case study involving the effects of accelerated aging on the power output from Gen-2 cells. For this case study, inadequacies of the simple first-order kinetics model were observed. However, a more complex model allowing for the effects of two concurrent mechanisms provided an accurate representation of the experimental data.

Doughty, Daniel Harvey; Thomas, Edward Victor; Jungst, Rudolph George; Roth, Emanuel Peter

2003-08-01T23:59:59.000Z

312

LIFETIME OF THE METASTABLE 23S1 STATE IN STORED Li+ IONS  

E-Print Network (OSTI)

ramped over a range ~ 5 volts through the particular voltagecm r = 3.0 cm Q = 2TT X 1.0 MHz V U D = 250 - 400 volts =0 - 30 volts = 8 - 1 8 volts u) = 2ir x 1 0 0 K H z AU = 10

Knight, R.D.

2010-01-01T23:59:59.000Z

313

Modeling of Nonuniform Degradation in Large-Format Li-ion Batteries (Presentation)  

DOE Green Energy (OSTI)

Study of impacts of large-format cell design features on battery useful life to improve battery engineering models, including both realistic geometry and physics.

Smith, K.; Kim, G. H.; Pesaran, A.

2009-05-01T23:59:59.000Z

314

Progress on advanced tokamak and steady-state scenario development on DIII-D and NSTX  

Science Conference Proceedings (OSTI)

Advanced tokamak (AT) research seeks to develop steady-state operating scenarios for ITER and other future devices from a demonstrated scientific basis. Normalized target parameters for steady-state operation on ITER are 100% non-inductive current operation with a bootstrap current fraction f(BS) >= 60%, q(95) similar to 4-5 and G = beta H-N(scaling)/q(95)(2) >= 0.3. Progress in realizing such plasmas is considered in terms of the development of plasma control capabilities and scientific understanding, leading to improved AT performance. NSTX has demonstrated active resistive wall mode stabilization with low, ITER-relevant, rotation rates below the critical value required for passive stabilization. On DIII-D, experimental observations and GYRO simulations indicate that ion internal transport barrier (ITB) formation at rational-q surfaces is due to equilibrium zonal flows generating high local E x B shear levels. In addition, stability modelling for DIII-D indicates a path to operation at beta N >= 4 with q(min) >= 2, using broad, hollow current profiles to increase the ideal wall stability limit. Both NSTX and DIII-D have optimized plasma performance and expanded AT operational limits. NSTX now has long-pulse, high performance discharges meeting the normalized targets for an spherical torus-based component test facility. DIII-D has developed sustained discharges combining high beta and ITBs, with performance approaching levels required for AT reactor concepts, e. g. beta(N) = 4, H-89 = 2.5, with f(BS) > 60%. Most importantly, DIII-D has developed ITER steady-state demonstration discharges, simultaneously meeting the targets for steady-state Q >= 5 operation on ITER set out above, substantially increasing confidence in ITER meeting its steady-state performance objective.

Doyle, E. J. [University of California, Los Angeles; Peng, Yueng Kay Martin [ORNL

2006-01-01T23:59:59.000Z

315

Quantitative broadband absorption and scattering spectroscopy in turbid media by combined frequency-domain and steady state methodologies  

DOE Patents (OSTI)

A technique for measuring broadband near-infrared absorption spectra of turbid media that uses a combination of frequency-domain and steady-state reflectance methods. Most of the wavelength coverage is provided by a white-light steady-state measurement, whereas the frequency-domain data are acquired at a few selected wavelengths. Coefficients of absorption and reduced scattering derived from the frequency-domain data are used to calibrate the intensity of the steady-state measurements and to determine the reduced scattering coefficient at all wavelengths in the spectral window of interest. The absorption coefficient spectrum is determined by comparing the steady-state reflectance values with the predictions of diffusion theory, wavelength by wavelength. Absorption spectra of a turbid phantom and of human breast tissue in vivo, derived with the combined frequency-domain and steady-state technique, agree well with expected reference values.

Tromberg, Bruce J. (Irvine, CA); Berger, Andrew J. (Rochester, NY); Cerussi, Albert E. (Lake Forest, CA); Bevilacqua, Frederic (Costa Mesa, CA); Jakubowski, Dorota (Irvine, CA)

2008-09-23T23:59:59.000Z

316

PEBBLE: a two-dimensional steady-state pebble bed reactor thermal hydraulics code  

SciTech Connect

This report documents the local implementation of the PEBBLE code to treat the two-dimensional steady-state pebble bed reactor thermal hydraulics problem. This code is implemented as a module of a computation system used for reactor core history calculations. Given power density data, the geometric description in (RZ), and basic heat removal conditions and thermal properties, the coolant properties, flow conditions, and temperature distributions in the pebble fuel elements are predicted. The calculation is oriented to the continuous fueling, steady state condition with consideration of the effect of the high energy neutron flux exposure and temperature history on the thermal conductivity. The coolant flow conditions are calculated for the same geometry as used in the neutronics calculation, power density and fluence data being used directly, and temperature results are made available for subsequent use.

Vondy, D.R.

1981-09-01T23:59:59.000Z

317

A Conductivity Relationship for Steady-state Unsaturated Flow Processes under Optimal Flow Conditions  

SciTech Connect

Optimality principles have been used for investigating physical processes in different areas. This work attempts to apply an optimal principle (that water flow resistance is minimized on global scale) to steady-state unsaturated flow processes. Based on the calculus of variations, we show that under optimal conditions, hydraulic conductivity for steady-state unsaturated flow is proportional to a power function of the magnitude of water flux. This relationship is consistent with an intuitive expectation that for an optimal water flow system, locations where relatively large water fluxes occur should correspond to relatively small resistance (or large conductance). Similar results were also obtained for hydraulic structures in river basins and tree leaves, as reported in other studies. Consistence of this theoretical result with observed fingering-flow behavior in unsaturated soils and an existing model is also demonstrated.

Liu, H. H.

2010-09-15T23:59:59.000Z

318

Steady State Analysis of Mobile Station State Transition for General Packet Radio Service  

E-Print Network (OSTI)

General Packet Radio Service (GPRS) is a system for efficient data packet radio transmission services which is used in conjunction with the Global System for Mobile Communications (GSM) system. The three mobile station (MS) states idle, ready, and standby are defined for efficient management of radio resources and signaling networks. The MS state transition behavior is modeled and the steady state probability of the MS states is derived using a semi-Markov process approach. The effect of various input parameters on the steady state probability is investigated. These results can be used in analyzing the effect of the input parameters on the tradeoff between location update and paging signaling, and thus, providing guidelines for proper selection of GPRS system parameters.

Yun Won Chung; Dan Keun Sung; A. Hamid Aghvami

2002-01-01T23:59:59.000Z

319

Transient and steady-state dark current mechanisms in amorphous selenium avalanche radiation detectors  

SciTech Connect

A theoretical model for describing bias-dependent transient and steady-state behaviors of dark current in amorphous selenium (a-Se) avalanche detector structures has been developed. The analytical model considers bulk thermal generation current from mid-gap sates, transient carrier depletion, and carrier injection from the electrodes incorporating avalanche multiplication. The proposed physics-based dark current model is compared with the published experimental results on three potential a-Se avalanche detector structures. The steady-state dark current is the minimum for the structures that have effective blocking layers for both holes and electrons. The transient decay time to reach a plateau decreases considerably with increasing electric field.

Kabir, M. Z.; Imam, Safayat-Al [Department of Electrical and Computer Engineering, Concordia University, 1455 Blvd. de Maisonneuve West, Montreal, Quebec H3G 1M8 (Canada)] [Department of Electrical and Computer Engineering, Concordia University, 1455 Blvd. de Maisonneuve West, Montreal, Quebec H3G 1M8 (Canada)

2013-04-15T23:59:59.000Z

320

Steady-state heat transfer in an inverted U-tube steam generator  

Science Conference Proceedings (OSTI)

Experimental results are presented involving U-tube steam generator tube bundle local heat transfer and fluid conditions during stead-state, full-power operations performed at high temperatures and pressures with conditions typical of a pressurized water reactor (15.0 MPa primary pressure, 600 K steam generator inlet plenum fluid temperatures, 6.2 MPa secondary pressure). The Semiscale (MOD-2C facility represents the state-of-the-art in measurement of tube local heat transfer data and average tube bundle secondary fluid density at several elevations, which allows an estimate of the axial heat transfer and void distributions during steady-state and transient operations. The method of heat transfer data reduction is presented and the heat flux, secondary convective heat transfer coefficient, and void fraction distributions are quantified for steady-state, full-power operations.

Boucher, T.J.

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Control of unstable steady states by extended time-delayed feedback  

E-Print Network (OSTI)

Time-delayed feedback methods can be used to control unstable periodic orbits as well as unstable steady states. We present an application of extended time delay autosynchronization introduced by Socolar et al. to an unstable focus. This system represents a generic model of an unstable steady state which can be found for instance in a Hopf bifurcation. In addition to the original controller design, we investigate effects of control loop latency and a bandpass filter on the domain of control. Furthermore, we consider coupling of the control force to the system via a rotational coupling matrix parametrized by a variable phase. We present an analysis of the domain of control and support our results by numerical calculations.

Thomas Dahms; Philipp Hoevel; Eckehard Schoell

2007-08-01T23:59:59.000Z

322

Ultraviolet Spectra of CV Accretion Disks with Non-Steady T(r) Laws  

E-Print Network (OSTI)

An extensive grid of synthetic mid- and far-ultraviolet spectra for accretion disks in cataclysmic variables has been presented by Wade and Hubeny (1998). In those models, the disk was assumed to be in steady-state, that is T_eff(r) is specified completely by the mass M_WD and radius R_WD of the accreting white dwarf star and the mass transfer rate M_dot which is constant throughout the disk. In these models, T_eff(r) is proportional to r^{-3/4} except as modified by a cutoff term near the white dwarf. Actual disks may vary from the steady-state prescription for T_eff(r), however, e.g. owing to outburst cycles in dwarf novae M_dot not constant with radius) or irradiation (in which case T_eff in the outer disk is raised above T_steady). To show how the spectra of such disks might differ from the steady case, we present a study of the ultraviolet (UV) spectra of models in which power-law temperature profiles T_eff(r) is proportional to r^{-gamma} with gamma grid, to allow comparison. We discuss both the UV spectral energy distributions and the appearance of the UV line spectra. We also briefly discuss the eclipse light curves of the non-standard models. Comparison of these models with UV observations of novalike variables suggests that better agreement may be possible with such modified T_eff(r) profiles.

Jerome A. Orosz; Richard A. Wade

2003-05-20T23:59:59.000Z

323

World`s gas-processing expands; Canada, U.S. lead remains steady  

SciTech Connect

Worldwide gas-processing capacity increased in 1997, led by expansions in North America, Latin America, and the Middle East. Canada and the US continued to dominate the rest of the world in capacity, but those countries` combined share of world capacities and production was kept steady in 1997 by expansions elsewhere. The paper discusses prices of natural gas in the US, Canadian plans, North American activity, world activity, and sulfur recovery capacity.

True, W.R.

1998-06-08T23:59:59.000Z

324

EV Sales Skyrocketing. eGallon Holds Steady. | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

EV Sales Skyrocketing. eGallon Holds Steady. EV Sales Skyrocketing. eGallon Holds Steady. EV Sales Skyrocketing. eGallon Holds Steady. July 19, 2013 - 8:45am Addthis eGallon: Compare the costs of driving with electricity What is eGallon? It is the cost of fueling a vehicle with electricity compared to a similar vehicle that runs on gasoline. Did you know? On average, it costs about 3 times less to drive an electric vehicle. Find out how much it costs to fuel an electric vehicle in your state regular gasoline 0 6 4 1 0 3 · 0 2 0 4 8 6 0 8 9 2 3 5 0 electric eGallon 0 4 1 7 2 3 3 · 0 4 2 0 4 6 0 8 5 9 1 5 0 Data and Methodology The eGallon price is calculated using the most recently available state by state residential electricity prices. The state gasoline price above is either the statewide average retail price or a multi-state regional average

325

Quasi-steady model for predicting temperature of aqueous foams circulating in geothermal wellbores  

DOE Green Energy (OSTI)

A quasi-steady model has been developed for predicting the temperature profiles of aqueous foams circulating in geothermal wellbores. The model assumes steady one-dimensional incompressible flow in the wellbore; heat transfer by conduction from the geologic formation to the foam is one-dimensional radially and time-dependent. The vertical temperature distribution in the undisturbed geologic formation is assumed to be composed of two linear segments. For constant values of the convective heat-transfer coefficient, a closed-form analytical solution is obtained. It is demonstrated that the Prandtl number of aqueous foams is large (1000 to 5000); hence, a fully developed temperature profile may not exist for representative drilling applications. Existing convective heat-transfer-coefficient solutions are adapted to aqueous foams. The simplified quasi-steady model is successfully compared with a more-sophisticated finite-difference computer code. Sample temperature-profile calculations are presented for representative values of the primary parameters. For a 5000-ft wellbore with a bottom hole temperature of 375{sup 0}F, the maximum foam temperature can be as high as 300{sup 0}F.

Blackwell, B.F.; Ortega, A.

1983-01-01T23:59:59.000Z

326

Type: Renewal  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1 INCITE Awards 1 INCITE Awards Type: Renewal Title: -Ab Initio Dynamical Simulations for the Prediction of Bulk Properties‖ Principal Investigator: Theresa Windus, Iowa State University Co-Investigators: Brett Bode, Iowa State University Graham Fletcher, Argonne National Laboratory Mark Gordon, Iowa State University Monica Lamm, Iowa State University Michael Schmidt, Iowa State University Scientific Discipline: Chemistry: Physical INCITE Allocation: 10,000,000 processor hours Site: Argonne National Laboratory Machine (Allocation): IBM Blue Gene/P (10,000,000 processor hours) Research Summary: This project uses high-quality electronic structure theory, statistical mechanical methods, and

327

An Experimental and Numerical Investigation of the Steady State Forces in Single Incremental Sheet Forming  

E-Print Network (OSTI)

Incremental sheet forming process is a relatively new method of forming which is increasingly being used in the industry. Complex shapes can be manufactured using this method and the forming operation doesn't require any dies. High strains of over 300 % can also be achieved. Incremental sheet forming method is used to manufacture many different components presently. Prototype examples include car headlights, tubs, train body panels and medical products. The work done in the thesis deals with the prediction of the steady state forces acting on the tool during forming. Prediction of forces generated would help to design the machine against excessive vibrations. It would help the user to protect the tool and the material blank from failure. An efficient design ensures that the tool would not get deflected out of its path while forming, improving the accuracy of the finished part. To study the forces, experiments were conducted by forming pyramid and cone shapes. An experimental arrangement was set up and experimental data was collected using a data acquisition system. The effect that the various process parameters, like the thickness of the sheet, wall angle of the part and tool diameter had on the steady state force were studied. A three dimensional model was developed using commercial finite element software ABAQUS using a new modeling technique to simulate the deformation of the sheet metal blank during incremental sheet forming. The steady state forces generated for any shape, with any set of parameters used, could be predicted using the numerical model. The advantage of having a numerical model is that the forces can be predicted without doing experiments. The model was used to predict the steady state forces developed during forming of pyramid and cone shapes. The results were compared and were seen to be reasonably close to the experimental results. Later, the numerical model was validated by forming arbitrary shapes and comparing the value obtained from simulations to the value of the measured steady state forces. The results obtained from the numerical model were seen to match very well with the experimental forces for the new shapes. The numerical model developed using the new technique was seen to predict forces to a reasonable extent with less computational time as compared to the models currently available.

Nair, Mahesh

2011-08-01T23:59:59.000Z

328

Bacteria Types  

NLE Websites -- All DOE Office Websites (Extended Search)

Bacteria Types Bacteria Types Name: Evelyn Location: N/A Country: N/A Date: N/A Question: What is the significance of S. marcescens,M.luteus, S.epidermidis, and E. Coli? Which of these are gram-positive and gram-negative, and where can these be found? Also, what problems can they cause? When we culture these bacteria, we used four methods: plates, broth, slants, and pour plates. The media was made of TSB, TSA, NAP, and NAD. What is significant about these culturing methods? Replies: I could give you the answer to that question but it is more informative, and fun, to find out yourself. Start with the NCBI library online (http://www.ncbi.nlm.nih.gov/) and do a query with the species name, and 'virulence' if you want to know what they're doing to us. Have a look at the taxonomy devision to see how they are related. To find out if they're gram-pos or neg you should do a gram stain if you can. Otherwise you'll find that information in any bacteriology determination guide. Your question about the media is not specific enough so I can't answer it.

329

Facility Type!  

Office of Legacy Management (LM)

ITY: ITY: --&L~ ----------- srct-r~ -----------~------~------- if yee, date contacted ------------- cl Facility Type! i I 0 Theoretical Studies Cl Sample 84 Analysis ] Production 1 Diepasal/Storage 'YPE OF CONTRACT .--------------- 1 Prime J Subcontract&- 1 Purchase Order rl i '1 ! Other information (i.e., ---------~---~--~-------- :ontrait/Pirchaee Order # , I C -qXlJ- --~-------~~-------~~~~~~ I I ~~~---~~~~~~~T~~~ FONTRACTING PERIODi IWNERSHIP: ,I 1 AECIMED AECMED GOVT GOUT &NTtiAC+OR GUN-I OWNED ----- LEEE!? M!s LE!Ps2 -LdJG?- ---L .ANDS ILJILDINGS X2UIPilENT IRE OR RAW HA-I-L :INAL PRODUCT IASTE Z. RESIDUE I I kility l pt I ,-- 7- ,+- &!d,, ' IN&"E~:EW AT SITE -' ---------------- , . Control 0 AEC/tlED managed operations

330

EVSE Features  

NLE Websites -- All DOE Office Websites (Extended Search)

UL, cUL, CE, CTick listed UL, cUL, CE, CTick listed Approximate size (H x W x D inches) 12 x 12 x 8 Charge level AC Level 2 Input voltage 208VAC to 240 VAC Maximum input current 30 Amp Circuit breaker rating 40 Amp Test Conditions 1 Test date 1/31/2012 Nominal supply voltage (Vrms) 235.68 Supply frequency (Hz) 60.00 Initial ambient temperature (°F) 58 Test Vehicle 1,3 Make and model 2011 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 3.34 Maximum charge power (AC kW) 3.39 EVSE Test Results 1,2,4 EVSE consumption prior to charge (AC W) 5.11 EVSE consumption during steady state charge (AC W) 22.77

331

Effective Hydraulic Parameters in Horizontally and Vertically Heterogeneous Soils for Steady-State Land–Atmosphere Interaction  

Science Conference Proceedings (OSTI)

In this study, the authors investigate effective soil hydraulic parameter averaging schemes for steady-state flow in heterogeneous shallow subsurfaces useful to land–atmosphere interaction modeling. “Effective” soil hydraulic parameters of the ...

Binayak P. Mohanty; Jianting Zhu

2007-08-01T23:59:59.000Z

332

An Intense, Quasi-Steady Thunderstorm over Mountainous Terrain. Part II: Doppler Radar Observations of the Storm Morphological Structure  

Science Conference Proceedings (OSTI)

An analysis of an intense, quasi-steady thunderstorm which developed over mountainous terrain is presented. This storm, extensively analyzed using multiple Doppler radar and surface mesonet data, formed within an environment having strong low-...

Kevin R. Knupp; William R. Cotton

1982-02-01T23:59:59.000Z

333

The Steady-State Barotropic Response of the Gulf of Maine and Adjacent Regions to Surface Wind Stress  

Science Conference Proceedings (OSTI)

The response of the Gulf of Maine region to steady, spatially uniform wind stress is examined using a linearized numerical model, with the influence of the strong tidal currents in the region included in the bottom stress formulation. The ...

Daniel G. Wright; David A. Greenberg; John W. Loder; Peter C. Smith

1986-05-01T23:59:59.000Z

334

Regime Transitions of Steady and Time-Dependent Hadley Circulations: Comparison of Axisymmetric and Eddy-Permitting Simulations  

Science Conference Proceedings (OSTI)

Steady-state and time-dependent Hadley circulations are investigated with an idealized dry GCM, in which thermal forcing is represented as relaxation of temperatures toward a radiative-equilibrium state. The latitude 0 of maximum radiative-...

Simona Bordoni; Tapio Schneider

2010-05-01T23:59:59.000Z

335

Transition dynamics between the multiple steady states in natural ventilation systems : from theories to applications in optimal controls  

E-Print Network (OSTI)

In this study, we investigated the multiple steady state behavior, an important observation in numerical and experimental studies in natural ventilation systems. The-oretical models are developed and their applications in ...

Yuan, Jinchao

2007-01-01T23:59:59.000Z

336

Steady State Flammable Gas Release Rate Calculation & Lower Flammability Level Evaluation for Hanford Tank Waste [SEC 1 & 2  

DOE Green Energy (OSTI)

Assess the steady state level at normal & off-normal ventilation conditions. Hydrogen generation rate calculated for 177 tanks using rate equation model. Flammability calc. based on hydrogen, ammonia, & methane proformed for tanks at various scenarios.

HU, T.A.

2002-06-20T23:59:59.000Z

337

A Model Study of the Stably Stratified Steady-State Atmospheric Boundary Layer over a Slightly Inclined Terrain  

Science Conference Proceedings (OSTI)

A simple, steady-state, numerical model is used to examine the Rossby-number similarity theory of the atmospheric boundary layer over a slightly inclined terrain. The model confirms the similarity predictions. The slope-influenced universal ...

Zbigniew Sorbjan

1984-06-01T23:59:59.000Z

338

An Alternative Form of Andrews' Conservation Law for Quasi-geostrophic Waves on a Steady, Nonuniform Flow  

Science Conference Proceedings (OSTI)

This note reports the derivation of an alternative form of Andrews' conservation law for small-amplitude, quasi-geostrophic, transient eddies on a steady but spatially nonuniform flow.

R. Alan Plumb

1985-02-01T23:59:59.000Z

339

The Steady-State Atmospheric Circulation Response to Climate Change–like Thermal Forcings in a Simple General Circulation Model  

Science Conference Proceedings (OSTI)

The steady-state extratropical atmospheric response to thermal forcing is investigated in a simple atmospheric general circulation model. The thermal forcings qualitatively mimic three key aspects of anthropogenic climate change: warming in the ...

Amy H. Butler; David W. J. Thompson; Ross Heikes

2010-07-01T23:59:59.000Z

340

Steady energy transfer dependence granular temperature on single bouncing granular particle  

E-Print Network (OSTI)

Simulation of a system consisted of free particle bouncing on a vertically vibrated based is performed. Two different states, which are steady and unsteady energy transfer state are found. The vibrating based is hold at constant vibration frequency $f = 0.1$ as the vibration amplitude $A$ varied. Sinusoidal form is used. Granular temperature $T_g$ as function of based velocity and coefficient of restitution is used but shown no role in determining energy transfer state of the system. Peak of free particle trajectory $x_m$ around value 20 seperate region of the two states.

Suparno Satira; Sparisoma Viridi; Freddy P Zen

2011-06-09T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

A theorem for the thermodynamics of chemical reaction networks at steady state  

E-Print Network (OSTI)

In this article the Gordan theorem is applied to the thermodynamics of a chemical reaction network at steady state. From a theoretical viewpoint it states that the exclusion (presence) of closed reactions loops makes possible (impossible) the definition of a thermodynamic potential and vice versa. On the computational side, it reveals that calculating reactions free energy and correcting reaction fluxes from infeasible loops are dual problems whose solutions are alternatively inconsistent. The relevance of this result for applications is discussed with an example in the field of constraints-based modeling of cellular metabolism where it leads to efficient and scalable methods to afford the energy balance analysis.

De Martino, Daniele

2012-01-01T23:59:59.000Z

342

Gas-cooled fast breeder reactor steady-state irradiation testing program  

Science Conference Proceedings (OSTI)

The requirements for the gas-cooled fast breeder reactor irradiation program are specified, and an irradiation program plan which satisfies these requirements is presented. The irradiation program plan consists of three parts and includes a schedule and a preliminary cost estimate: (1) a steady-state irradiation program, (2) irradiations in support of the design basis transient test program, and (3) irradiations in support of the GRIST-2 safety test program. Data from the liquid metal fast breeder reactor program are considered, and available irradiation facilities are examined.

Acharya, R.T.; Campana, R.J.; Langer, S.

1980-08-01T23:59:59.000Z

343

Investigation of component failure rates for pulsed versus steady state tokamak operation  

Science Conference Proceedings (OSTI)

This report presents component failure rate data sources applicable to magnetic fusion systems, and defines multiplicative factors to adjust these data for specific use on magnetic fusion experiment designs. The multipliers address both long pulse and steady state tokamak operation. Thermal fatigue and radiation damage are among the leading reasons for large multiplier values in pulsed operation applications. Field failure rate values for graphite protective tiles are presented, and beryllium tile failure rates in laboratory testing are also given. All of these data can be used for reliability studies, safety analyses, design tradeoff studies, and risk assessments.

Cadwallader, L.C.

1992-07-01T23:59:59.000Z

344

Estimation of steady-state unbalanced system conditions combining conventional power flow and fault analysis software  

Science Conference Proceedings (OSTI)

In real three-phase power systems the voltages and currents are not fully symmetrical. A method has been developed to estimate the effects of slight unbalanced network conditions for steady-state operation. A conventional power flow is followed by a linear incremental calculation using a three-phase model of the network. The unbalanced condition is handled like a multiple unbalanced fault. The process is illustrated for the case of a transformer bank with non-identical single phase units. The results show the effects of different transformer reactances and different voltage ratios, respectively.

Reichelt, D.; Ecknauer, E. [Nordostschweizerische Kraftwerke AG, Baden (Switzerland); Glavitsch, H. [Swiss Federal Inst. of Tech., Zurich (Switzerland)

1996-02-01T23:59:59.000Z

345

Number: 1894 Type: factoid ...  

Science Conference Proceedings (OSTI)

... type> Type: factoid Description: How high is the pitcher's mound? ... 2047 Type: factoid Description: How close is Mercury to ...

2003-08-04T23:59:59.000Z

346

Mosaic neurofibromatosis type 1  

E-Print Network (OSTI)

with neurofibromatosis type 1 (NF1) with microdeletionsM, Huson S. Mosaic (segmental) neurofibromatosis type 1and type 2: no longer neurofibromatosis type 5. Am J Med

Liang, Christine; Schaffer, Julie V

2008-01-01T23:59:59.000Z

347

Kinetic model of electric potentials in localized collisionless plasma structures under steady quasi-gyrotropic conditions  

SciTech Connect

Localized plasma structures, such as thin current sheets, generally are associated with localized magnetic and electric fields. In space plasmas localized electric fields not only play an important role for particle dynamics and acceleration but may also have significant consequences on larger scales, e.g., through magnetic reconnection. Also, it has been suggested that localized electric fields generated in the magnetosphere are directly connected with quasi-steady auroral arcs. In this context, we present a two-dimensional model based on Vlasov theory that provides the electric potential for a large class of given magnetic field profiles. The model uses an expansion for small deviation from gyrotropy and besides quasineutrality it assumes that electrons and ions have the same number of particles with their generalized gyrocenter on any given magnetic field line. Specializing to one dimension, a detailed discussion concentrates on the electric potential shapes (such as 'U' or 'S' shapes) associated with magnetic dips, bumps, and steps. Then, it is investigated how the model responds to quasi-steady evolution of the plasma. Finally, the model proves useful in the interpretation of the electric potentials taken from two existing particle simulations.

Schindler, K. [Ruhr University Bochum, 44780 Bochum (Germany); Birn, J. [Space Science Institute, Boulder, Colorado 80301 (United States); Hesse, M. [Nasa Goddard Space Flight Center, Greenbelt, Maryland 20771 (United States)

2012-08-15T23:59:59.000Z

348

Plasma Shape Optimization for Steady-State Tokamak Development in DIII-D  

Science Conference Proceedings (OSTI)

For a more detailed account of the results summarized here and for references, see C.T. Holcomb et al., Phys. Plasmas 16, 056116 (2009). Advanced tokamak research on DIII-D is focused on developing a high fusion gain, steady-state scenario that would eliminate or greatly reduce the demands on an inductive transformer in future machines. Steady-state operation requires the inductively driven current density (j{sub Ind}) be zero everywhere. Most of the total current I{sub p} is typically from self-driven bootstrap current, with the remainder driven by external noninductive sources, such as neutral beam and radiofrequency current drive. This paper describes an extension of the fully noninductive condition (f{sub NI} {approx} 100%) to {approx}0.7 current relaxation times that was achieved by a combination of more available ECCD and new scientific insights. The insights are an optimization of performance through variation of the plasma shape parameter known as squareness ({zeta}) and an optimization of divertor magnetic balance. These optimizations simultaneously improve stability, confinement, and density control. These are each essential for achieving fully noninductive operation.

Holcomb, C T; Ferron, J R; Luce, T C; Petrie, T W; Politzer, P A; Challis, C; DeBoo, J C; Doyle, E J; Greenfield, C M; Groebner, R J; Groth, M; Hyatt, A M; Jackson, G L; Kessel, C; La Haye, R J; Makowski, M A; McKee, G R; Murakami, M; Osborne, T H; Park, J; Prater, R; Porter, G D; Reimerdes, H; Rhodes, T L; Shafer, M W; Snyder, P B; Turnbull, A D; West, W P

2009-06-17T23:59:59.000Z

349

Selection of Steady-State Process Simulation Software to Optimize Treatment of Radioactive and Hazardous Waste  

SciTech Connect

The process used for selecting a steady-state process simulator under conditions of high uncertainty and limited time is described. Multiple waste forms, treatment ambiguity, and the uniqueness of both the waste chemistries and alternative treatment technologies result in a large set of potential technical requirements that no commercial simulator can totally satisfy. The aim of the selection process was two-fold. First, determine the steady-state simulation software that best, albeit not completely, satisfies the requirements envelope. And second, determine if the best is good enough to justify the cost. Twelve simulators were investigated with varying degrees of scrutiny. The candidate list was narrowed to three final contenders: ASPEN Plus 10.2, PRO/II 5.11, and CHEMCAD 5.1.0. It was concluded from "road tests" that ASPEN Plus appears to satisfy the project's technical requirements the best and is worth acquiring. The final software decisions provide flexibility: they involve annual rather than multi-year licensing, and they include periodic re-assessment.

Nichols, Todd Travis; Barnes, Charles Marshall; Lauerhass, Lance; Taylor, Dean Dalton

2001-06-01T23:59:59.000Z

350

Selection of Steady-State Process Simulation Software to Optimize Treatment of Radioactive and Hazardous Waste  

Science Conference Proceedings (OSTI)

The process used for selecting a steady-state process simulator under conditions of high uncertainty and limited time is described. Multiple waste forms, treatment ambiguity, and the uniqueness of both the waste chemistries and alternative treatment technologies result in a large set of potential technical requirements that no commercial simulator can totally satisfy. The aim of the selection process was two-fold. First, determine the steady-state simulation software that best, albeit not completely, satisfies the requirements envelope. And second, determine if the best is good enough to justify the cost. Twelve simulators were investigated with varying degrees of scrutiny. The candidate list was narrowed to three final contenders: ASPEN Plus 10.2, PRO/II 5.11, and CHEMCAD 5.1.0. It was concluded from ''road tests'' that ASPEN Plus appears to satisfy the project's technical requirements the best and is worth acquiring. The final software decisions provide flexibility: they involve annual rather than multi-year licensing, and they include periodic re-assessment.

Nichols, T. T.; Barnes, C. M.; Lauerhass, L.; Taylor, D. D.

2001-06-01T23:59:59.000Z

351

The Path of Carbon in Photosynthesis. XVI. Kinetic Relationshipsof the Intermediates in Steady State Photosynthesis  

DOE Green Energy (OSTI)

A kinetic study of the accumulation of C{sup 14} in the intermediates of steady state photosynthesis in C{sup 14}O{sub 2} provides information regarding the sequence of reactions involved. The work described applied the radio-chromatographic technique for analysis of the labeled early products. The simultaneous carboxylation reaction resulting in malic acid as well as phosphoglycerate is demonstrated in experiments at high light intensity. A comparison of radioactivities in a number of phosphorylated sugars as a function of time reveals concurrent synthesis of fructose and sedoheptulose phosphates followed by that of ribulose phosphates and later by that of glucose phosphates. The possibility that the cleavage of C{sub 4} compounds to C{sub 2} carbon dioxide acceptors may involve C{sub 7} and C{sub 5} sugars and evidence for this mechanism is presented.

Benson, A.A.; Kawaguchi, S.; Hayes, P.; Calvin, M.

1952-06-05T23:59:59.000Z

352

Steady-state model for estimating gas production from underground coal gasification  

Science Conference Proceedings (OSTI)

A pseudo-one-dimensional channel model has been developed to estimate gas production from underground coal gasification. The model incorporates a zero-dimensional steady-state cavity growth submodel and models mass transfer from the bulk gas to the coal wall using a correlation for natural convection. Simulations with the model reveal that the gas calorific value is sensitive to coal reactivity and the exposed reactive surface area per unit volume in the channel. A comparison of model results with several small-scale field trials conducted at Centralia in the U.S.A. show that the model can make good predictions of the gas production and composition under a range of different operating conditions, including operation with air and steam/oxygen mixtures. Further work is required to determine whether the model formulation is also suitable for simulating large-scale underground coal gasification field trials.

Greg Perkins; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). School of Materials Science and Engineering

2008-11-15T23:59:59.000Z

353

Solute transport under steady and transient conditions in biodegraded municipal solid waste  

E-Print Network (OSTI)

The transport of a conservative tracer (lithium) in a large (3.5 m3) undisturbed municipal solid waste sample has been investigated under steady and fully transient conditions using a simple model. The model comprises a kinematic wave approximation for water movement, presented in a previous paper, and a strict convective solute flux law. The waste medium is conceptualized as a three-domain system consisting of a mobile domain (channels), an immobile fast domain, and an immobile slow domain. The mobile domain constitutes only a minor fraction of the medium, and the access to the major part of medium is constrained by diffusive transport. Thus the system is in a state of physical nonequilibrium. The fast immobile domain is the part of the matrix which surrounds the channels and forms the boundary between the channels and the matrix. Owing to its exposure to mobile water, which enhances the biodegradation process, this domain is assumed to be more porous and loose in its structure and therefore to respond faster to a change in solute concentration in the mobile domain compared to the regions deep inside the matrix. The diffusive mass exchange between the domains is modeled with two first-order mass transfer expressions coupled in series. Under transient conditions the system will also be in a state of hydraulic nonequilibrium. Hydraulic gradients build up between the channel domain and the matrix in response to the water input events. The gradients will govern a reversible flow and convective transport between the domains, here represented as a source/sink term in the governing equation. The model has been used to interpret and compare the results from a steady state experiment and an unsteady state experiment. By solely adjusting the size of the fraction of the immobile fast domain that is active in transferring solute, the model is capable of accurately reproducing the measured outflow breakthrough curves for both the steady and unsteady state experiments. During transient conditions the fraction of the immobile fast domain that is active in transferring solute is found to be about 65% larger than that under steady state conditions. It is therefore concluded that the water input pattern governs the size of the fraction of the immobile fast domain which, in turn, governs the solute residence time in the solid waste. It can be concluded that the contaminant transport process in landfills is likely to be in a state of both physical, hydraulic, and chemical nonequilibrium. The transport process for a conservative solute is here shown to be dominated by convective transport in the channels and a fast diffusive mass exchange with the surrounding matrix. This may imply that the observed leachate quality from landfills mainly reflects the biochemical conditions in these regions. The water input pattern is of great importance for the transport process since it governs the size of the fraction of the immobile fast domain which is active in transferring solute. This may be the reason for leachate quality to be seasonally or water flux dependent, which has been observed in several investigations. The result also has a significant practical implication for efforts to enhance the biodegradation process in landfills by recycling of the leachate.

Bendz, David; Singh, Vijay P.

1999-08-01T23:59:59.000Z

354

Two-Phase Flow in Porous Media: Scaling of Steady-State Effective Permeability  

E-Print Network (OSTI)

A recent experiment has considered the effective permeability of two-phase flow of air and a water-glycerol solution under steady-state conditions in a two-dimensional model porous medium, and found a power law dependence with respect to capillary number. Running simulations on a two-dimensional network model a similar power law is found, for high viscosity contrast as in the experiment and also for viscosity matched fluids. Two states are found, one with stagnant clusters and one without. For the stagnant cluster state, a power law exponent 0.50 is found for viscosity matched fluids and 0.54 for large viscosity contrast. When there are no stagnant clusters the exponent depends on saturation and varies within the range of 0.67 - 0.80.

Morten Grøva

2012-01-23T23:59:59.000Z

355

Progress towards Steady State at Low Aspect Ratio on the National Spherical Torus Experiment (NSTX)  

SciTech Connect

Modifications to the plasma control capabilities and poloidal field coils of the National Spherical Torus Experiment (NSTX) have enabled a significant enhancement in shaping capability which has led to the transient achievement of a record shape factor (S ? q95 (I?? ???)) of ?41 (MA m?1 ??1) simultaneous with a record plasma elongation of ? ? ? ? ? ? 3. This result was obtained using isoflux control and real-time equilibrium reconstruction. Achieving high shape factor together with tolerable divertor loading is an important result for future ST burning plasma experiments as exemplified by studies for future ST reactor concepts, as well as neutron producing devices, which rely on achieving high shape factors in order to achieve steady state operation while maintaining MHD stability. Statistical evidence is presented which demonstrates the expected correlation between increased shaping and improved plasma performance.

D.A. Gates, J. Menard, R. Maingi, S. Kaye, S.A. Sabbagh, S. Diem, J.R.Wilson, M.G. Bell, R.E. Bell, J. Ferron, E.D. Fredrickson, C.E. Kessel, B.P. LeBlanc, F. Levinton, J. Manickam, D. Mueller, R. Raman, T. Stevenson, D. Stutman, G. Taylor, K. Tritz, H. Yu, and the NSTX Research Team

2007-11-08T23:59:59.000Z

356

Variable-delay feedback control of unstable steady states in retarded time-delayed systems  

E-Print Network (OSTI)

We study the stability of unstable steady states in scalar retarded time-delayed systems subjected to a variable-delay feedback control. The important aspect of such a control problem is that time-delayed systems are already infinite-dimensional before the delayed feedback control is turned on. When the frequency of the modulation is large compared to the system's dynamics, the analytic approach consists of relating the stability properties of the resulting variable-delay system with those of an analogous distributed delay system. Otherwise, the stability domains are obtained by a numerical integration of the linearized variable-delay system. The analysis shows that the control domains are significantly larger than those in the usual time-delayed feedback control, and that the complexity of the domain structure depends on the form and the frequency of the delay modulation.

Aleksandar Gjurchinovski; Viktor Urumov

2010-07-06T23:59:59.000Z

357

Steady states and linear stability analysis of precipitation pattern formation at geothermal hot springs  

E-Print Network (OSTI)

A dynamical theory of geophysical precipitation pattern formation is presented and applied to irreversible calcium carbonate (travertine) deposition. Specific systems studied here are the terraces and domes observed at geothermal hot springs, such as those at Yellowstone National Park, and speleothems, particularly stalactites and stalagmites. The theory couples the precipitation front dynamics with shallow water flow, including corrections for turbulent drag and curvature effects. In the absence of capillarity and with a laminar flow profile, the theory predicts a one-parameter family of steady state solutions to the moving boundary problem describing the precipitation front. These shapes match well the measured shapes near the vent at the top of observed travertine domes. Closer to the base of the dome, the solutions deviate from observations, and circular symmetry is broken by a fluting pattern, which we show is associated with capillary forces causing thin film break-up. We relate our model to that recent...

Chan, Pak Yuen

2007-01-01T23:59:59.000Z

358

Experiments on steady state particle control in Tore Supra and DIII-D  

DOE Green Energy (OSTI)

Particle control is playing an increasingly important role in tokamak plasma performance. The present paper discusses particle control of hydrogen/deuterium by wall pumping on graphite or carbonized surfaces, as well as by external exhaust with pumped limiters and pumped divertors. Wall pumping is ultimately a transient effect and by itself not suitable for steady state particle exhaust. Therefore, external exhaust techniques with pumped divertors and limiters are being developed. How wall pumping phenomena interact and correlate with these inherently steady state, external exhaust techniques, is not well known to date. In the present paper, the processes involved in wall pumping and in external pumping are investigated in an attempt to evaluate the effect of external exhaust on wall pumping. Some of the key elements of this analysis are: (1) charge-exchange fluxes to the wall play a crucial role in the core-wall particle dynamics, (2) the recycling fluxes of thermal molecules have a high probability of ionization in the scrape-off layer, (3) thermal particles originating from the wall, which are ionized within the scrape-off layer, can be directly exhausted, thus providing a direct path between wall and exhaust which can be used to control the wall inventory. This way, the wall can be kept in a continuous pumping state in the sense that it continuously absorbs energetic particles and releases thermal molecules which are then removed by the external exhaust mechanism. While most of the ingredients of this analysis have been observed individually before, the present evaluation is an attempt to correlate effects of wall recycling and external exhaust.

Mioduszewski, P.K.; Hogan, J.T.; Owen, L.W. [and others

1994-12-31T23:59:59.000Z

359

Type checking and normalisation.  

E-Print Network (OSTI)

??This thesis is about Martin-Löf's intuitionistic theory of types (type theory). Type theory is at the same time a formal system for mathematical proof and… (more)

Chapman, James Maitland

2009-01-01T23:59:59.000Z

360

Hybrid type checking  

E-Print Network (OSTI)

Phase distinctions in type theory. Manuscript, 1988. [10]Typechecking dependent types and subtypes. In Lecture notesF. Pfenning. Intersection types and computational effects.

Flanagan, C

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Type 2 segmental glomangiomas  

E-Print Network (OSTI)

skin disorders: different types of severitiy reflectevidence for dichotomous types of severitiy. Arch Dermatol9. Happle R, König A. Type 2 segmental manifestation of

Hoekzema, Rick; Zonneveld, Ingrid M; Wal, Allard C van der

2010-01-01T23:59:59.000Z

362

Writing with Complex Type  

E-Print Network (OSTI)

29] Middendorp, J. 2004. Dutch type. 010 Publishers. [30]A. Hyland. 1992. Twentieth-century type. Laurence King. [7]Robertson. 2005. From Movable Type to Moving Type-Evolution

Lewis, Jason; Nadeau, Bruno

2009-01-01T23:59:59.000Z

363

abstract data type  

Science Conference Proceedings (OSTI)

Definition of abstract data type, possibly with links to more information and implementations. NIST. abstract data type. (definition). ...

2013-11-08T23:59:59.000Z

364

Integrated modelling of steady-state scenarios and heating and current drive mixes for ITER  

Science Conference Proceedings (OSTI)

Recent progress on ITER steady-state (SS) scenario modelling by the ITPA-IOS group is reviewed. Code-to-code benchmarks as the IOS group's common activities for the two SS scenarios (weak shear scenario and internal transport barrier scenario) are discussed in terms of transport, kinetic profiles, and heating and current drive (CD) sources using various transport codes. Weak magnetic shear scenarios integrate the plasma core and edge by combining a theory-based transport model (GLF23) with scaled experimental boundary profiles. The edge profiles (at normalized radius rho = 0.8-1.0) are adopted from an edge-localized mode-averaged analysis of a DIII-D ITER demonstration discharge. A fully noninductive SS scenario is achieved with fusion gain Q = 4.3, noninductive fraction f(NI) = 100%, bootstrap current fraction f(BS) = 63% and normalized beta beta(N) = 2.7 at plasma current I(p) = 8MA and toroidal field B(T) = 5.3 T using ITER day-1 heating and CD capability. Substantial uncertainties come from outside the radius of setting the boundary conditions (rho = 0.8). The present simulation assumed that beta(N)(rho) at the top of the pedestal (rho = 0.91) is about 25% above the peeling-ballooning threshold. ITER will have a challenge to achieve the boundary, considering different operating conditions (T(e)/T(i) approximate to 1 and density peaking). Overall, the experimentally scaled edge is an optimistic side of the prediction. A number of SS scenarios with different heating and CD mixes in a wide range of conditions were explored by exploiting the weak-shear steady-state solution procedure with the GLF23 transport model and the scaled experimental edge. The results are also presented in the operation space for DT neutron power versus stationary burn pulse duration with assumed poloidal flux availability at the beginning of stationary burn, indicating that the long pulse operation goal (3000s) at I(p) = 9 MA is possible. Source calculations in these simulations have been revised for electron cyclotron current drive including parallel momentum conservation effects and for neutral beam current drive with finite orbit and magnetic pitch effects.

Murakami, Masanori [ORNL; Park, Jin Myung [ORNL

2011-01-01T23:59:59.000Z

365

Type Ia Supernova: Burning and Detonation in the Distributed Regime  

E-Print Network (OSTI)

A simple, semi-analytic representation is developed for nuclear burning in Type Ia supernovae in the special case where turbulent eddies completely disrupt the flame. The speed and width of the ``distributed'' flame front are derived. For the conditions considered, the burning front can be considered as a turbulent flame brush composed of corrugated sheets of well-mixed flames. These flames are assumed to have a quasi-steady-state structure similar to the laminar flame structure, but controlled by turbulent diffusion. Detonations cannot appear in the system as long as distributed flames are still quasi-steady-state, but this condition is violated when the distributed flame width becomes comparable to the size of largest turbulent eddies. When this happens, a transition to detonation may occur. For current best estimates of the turbulent energy, the most likely density for the transition to detonation is in the range 0.5 - 1.5 x 10^7 g cm^{-3}.

S. E. Woosley

2007-09-26T23:59:59.000Z

366

Quasi-Steady Analysis of a PBL Model with an Eddy-Diffusivity Profile and Nonlocal Fluxes  

Science Conference Proceedings (OSTI)

Analytic solutions to a planetary boundary layer (PBL) model with an eddy-diffusivity profile (i.e., a K profile) and nonlocal fluxes are presented for the quasi-steady regime. The solutions demonstrate how different processes contribute to the ...

Bjorn Stevens

2000-03-01T23:59:59.000Z

367

Detection of Nerve Injury with Diffusion Weighted Wide Band Steady State Free Precession (DW-WBSSFP) in the Lumbar Spine  

E-Print Network (OSTI)

Detection of Nerve Injury with Diffusion Weighted Wide Band Steady State Free Precession (DW Precession (DW-WBSSFP) technique, which may allow both superior anatomical visualization as well as detection repetition time (TR), which is used for acquisition. In DW-WBSSFP, diffusion gradients were placed in TRs

Southern California, University of

368

Airborne Doppler Observations of the Inner-Core Structural Differences between Intensifying and Steady-State Tropical Cyclones  

Science Conference Proceedings (OSTI)

Differences in the inner-core structure of intensifying [IN; intensity increase of at least 20 kt (24 h)?1, where 1 kt = 0.51 m s?1] and steady-state [SS; intensity remaining between ±10 kt (24 h)?1] tropical cyclones (TCs) are examined using ...

Robert Rogers; Paul Reasor; Sylvie Lorsolo

2013-09-01T23:59:59.000Z

369

Steady-State Dynamics of a Density Current in an f-Plane Nonlinear Shallow-Water Model  

Science Conference Proceedings (OSTI)

The authors study the nonlinear dynamics of a density current generated by a diabatic source in a rotating and a nonrotating system, both in the presence and in the absence of frictional losses, using a steady-state hydrostatic shallow-water ...

Giovanni A. Dalu; Marina Baldi

2010-02-01T23:59:59.000Z

370

Statistical mechanical theory for steady-state systems. III. Heat flow in a Lennard-Jones fluid  

E-Print Network (OSTI)

flow is developed based upon the second entropy for dynamical transitions between energy moment a molecular-dynamics trajectory was generated, and various time-dependent properties were accumulatedStatistical mechanical theory for steady-state systems. III. Heat flow in a Lennard-Jones fluid

Attard, Phil

371

The interpretation of speech reception threshold data in normal-hearing and hearing-impaired listeners: Steady-state noise  

Science Conference Proceedings (OSTI)

Speech-in-noise-measurements are important in clinical practice and have been the subject of research for a long time. The results of these measurements are often described in terms of the speech reception threshold(SRT) and SNR loss. Using the basic concepts that underlie several models of speech recognition in steady-state noise

Cas Smits; Joost M. Festen

2011-01-01T23:59:59.000Z

372

Parallel implementation of a steady state thermal and hydraulic analysis of pipe networks in OpenMP  

Science Conference Proceedings (OSTI)

The considerable computation time of a practical application of sequential algorithms for simulating thermal and flow distribution in pipe networks is the motivating factor to study their parallel implementation. The mathematical model formulated and ... Keywords: OpenMP, flow and thermal analysis, parallel implementation, pipe networks, steady state

Mykhaylo Fedorov

2009-09-01T23:59:59.000Z

373

Steady and Periodic Pressure Measurements on a Generic Helicopter Fuselage Model in the Presence of a Rotor  

Science Conference Proceedings (OSTI)

A wind tunnel test of a generic helicopter fuselage model with an independently mounted rotor has been conducted to obtain steady and periodic pressure data on the helicopter body. The model was tested at four advance ratios and three thrust coefficients. ...

Mineck Raymond E.; Gorton Susan Althoff

2000-06-01T23:59:59.000Z

374

A Continental Storm with a Steady, Adiabatic Updraft and High Concentrations of Small Ice Particles: 6 July 1976 Case Study  

Science Conference Proceedings (OSTI)

A storm in southeastern Wyoming was investigated by the NCAR/NOAA sailplane which spiraled up to 5.6 km above cloud base in and above a weak echo region. The updraft associated with the weak echo region was remarkably steady (about 8 m s?1) and ...

Ilga R. Paluch; Daniel W. Breed

1984-03-01T23:59:59.000Z

375

Results of transient and steady state experiments investigating hazards of flow reductions in a K process tube  

SciTech Connect

The purpose of this report is to present the results of transient and steady state heat transfer experiments investigating the degree of protection offered by the Panellit pressure gage system to hazards arising from coolant flow reductions to a K process tube.

Hesson, G.M.; Thorne, W.L.

1958-01-02T23:59:59.000Z

376

EVSE Features Charge Delay Option Power Light Indicator Eight-segment Progress Indicator Auto-restart  

NLE Websites -- All DOE Office Websites (Extended Search)

Charge Delay Option Power Light Indicator Charge Delay Option Power Light Indicator Eight-segment Progress Indicator Auto-restart EVSE Specifications Grid connection Plug and cord NEMA 6-50 Connector type J1772 Test lab certifications UL Listed Approximate size (H x W x D inches) 10 x 13 x 4 Charge level AC Level 2 Input voltage 240 VAC Maximum input current 30 Amp Circuit breaker rating 40 Amp Test Conditions 1 Test date 10/30/2012 Nominal supply voltage (Vrms) 209.04 Supply frequency (Hz) 59.99 Initial ambient temperature (°F) 64 Test Vehicle 1,3 Make and model 2012 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 3.09 Maximum charge power (AC kW) 3.20 EVSE Test Results 1,2,4

377

EVSE Features  

NLE Websites -- All DOE Office Websites (Extended Search)

lights lights UART interface EVSE Specifications Grid connection Plug and cord NEMA 6-30 Connector type J1772 Test lab certifications ETL listed Approximate size (H x W x D inches) 5 x 14 x 4 Charge level AC Level 2 Input voltage 95VAC to 264 VAC Maximum input current 24 Amp Circuit breaker rating 40 Amp Test Conditions 1 Test date 10/25/2011 Nominal supply voltage (Vrms) 239.93 Supply frequency (Hz) 60.00 Initial ambient temperature (°F) 52 Test Vehicle 1,3 Make and model 2011 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 3.33 Maximum charge power (AC kW) 3.38 EVSE Test Results 1,2,4 EVSE consumption prior to charge (AC W) 1.8 EVSE consumption during

378

EVSE Features Low and High Current Settings Integrated Flashlight  

NLE Websites -- All DOE Office Websites (Extended Search)

Low and High Current Settings Integrated Flashlight Low and High Current Settings Integrated Flashlight Auto-restart EVSE Specifications Grid connection Plug and cord NEMA 5-15 Connector type J1772 Test lab certifications ETL Listed Approximate size (H x W x D inches) 16 x 9 x 4 Charge level AC Level 1 Input voltage 120 VAC Maximum input current 12 Amp Circuit breaker rating 20 Amp Test Conditions 1 Test date 9/4/2012 Nominal supply voltage (Vrms) 117.05 Supply frequency (Hz) 59.99 Initial ambient temperature (°F) 58 Test Vehicle 1,3 Make and model 2012 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 1.36 Maximum charge power (AC kW) 1.45 EVSE Test Results 1,2,4 EVSE consumption prior to charge (AC W) 3.6

379

EVSE Features  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Flashlight 25ft of coiled cable Integrated Flashlight 25ft of coiled cable Auto-reset EVSE Specifications Grid connection Hardwired Connector type J1772 Test lab certifications ETL Listed Approximate size (H x W x D inches) 10 x 15 x 5 Charge level AC Level 2 Input voltage 208 / 240 VAC Maximum input current 15 Amp Circuit breaker rating 20 Amp Test Conditions 1 Test date 3/29/2012 Nominal supply voltage (Vrms) 243.11 Supply frequency (Hz) 60.01 Initial ambient temperature (°F) 64 Test Vehicle 1,3 Make and model 2011 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 3.33 Maximum charge power (AC kW) 3.39 EVSE Test Results 1,2,4

380

EVSE Features  

NLE Websites -- All DOE Office Websites (Extended Search)

lights lights EVSE Specifications Grid connection Plug and cord NEMA 14-30 Connector type J1772 Test lab certifications ETL listed Approximate size (H x W x D inches) 10 x 15 x 5 Charge level AC Level 2 Input voltage 208 VAC to 240 VAC Maximum input current 30 Amp Circuit breaker rating 40 Amp Test Conditions 1 Test date 10/24/2011 Nominal supply voltage (Vrms) 240.37 Supply frequency (Hz) 60.00 Initial ambient temperature (°F) 58 Test Vehicle 1,3 Make and model 2011 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 3.33 Maximum charge power (AC kW) 3.37 EVSE Test Results 1,2,4 EVSE consumption prior to charge (AC W) 3.2 EVSE consumption during

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

EVSE Features Power Button for Zero Consumption Auto-restart  

NLE Websites -- All DOE Office Websites (Extended Search)

Button for Zero Consumption Auto-restart Button for Zero Consumption Auto-restart Multi Colored Charge Indicator Led Power Indicator EVSE Specifications Grid connection Plug and cord NEMA 6-50 Connector type J1772 Test lab certifications ETL Listed Approximate size (H x W x D inches) 16 x 24 x 6 Charge level AC Level 2 Input voltage 208-240 VAC Maximum input current 30 Amp Circuit breaker rating 40 Amp Test Conditions 1 Test date 10/29/2012 Nominal supply voltage (Vrms) 208.38 Supply frequency (Hz) 59.99 Initial ambient temperature (°F) 64 Test Vehicle 1,3 Make and model 2012 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 3.07 Maximum charge power (AC kW) 3.32 EVSE Test Results

382

Types of Costs Types of Cost Estimates  

E-Print Network (OSTI)

05-1 · Types of Costs · Types of Cost Estimates · Methods to estimate capital costs MIN E 408) costs apply to those items that are consumed in production process and are roughly proportional to level in cash flow analysis and in the decision to use the equipment for reclamation? Types of Costs #12

Boisvert, Jeff

383

Types of Costs Types of Cost Estimates  

E-Print Network (OSTI)

· Types of Costs · Types of Cost Estimates · Methods to estimate capital costs MIN E 408: Mining the equipment for reclamation? Types of Costs #12;· Marginal Cost: ­ Change in total cost ­ Any production process involves fixed and variable costs. As production increases/expands, fixed costs are unchanged, so

Boisvert, Jeff

384

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

Science Conference Proceedings (OSTI)

This report assesses the steady state flammability level under off normal ventilation conditions in the tank headspace for 28 double-shell tanks (DST) and 149 single shell-tanks (SST) at the Hanford Site. Flammability was calculated using estimated gas release rates, Le Chatelier's rule, and lower flammability limits of fuels in an air mixture. This revision updates the hydrogen generation rate input data for all 177 tanks using waste composition information from the Best Basis Inventory Detail Report (data effective as of August 4,2008). Assuming only barometric breathing, the shortest time to reach 25% of the lower flammability limit is 11 days for DSTs (i.e., tank 241-AZ-10l) and 36 days for SSTs (i.e., tank 241-B-203). Assuming zero ventilation, the shortest time to reach 25% of the lower flammability limit is 10 days for DSTs (i.e., tank 241-AZ-101) and 34 days for SSTs (i.e., tank 241-B-203).

MEACHAM JE

2009-10-26T23:59:59.000Z

385

Steady-State Simulation of Steam Reforming of INEEL Tank Farm Waste  

SciTech Connect

A steady-state model of the Sodium-Bearing Waste steam reforming process at the Idaho National Engineering and Environmental Laboratory has been performed using the commercial ASPEN Plus process simulator. The preliminary process configuration and its representation in ASPEN are described. As assessment of the capability of the model to mechanistically predict product stream compositions was made, and fidelity gaps and opportunities for model enhancement were identified, resulting in the following conclusions: (1) Appreciable benefit is derived from using an activity coefficient model for electrolyte solution thermodynamics rather than assuming ideality (unity assumed for all activity coefficients). The concentrations of fifteen percent of the species present in the primary output stream were changed by more than 50%, relative to Electrolyte NRTL, when ideality was assumed; (2) The current baseline model provides a good start for estimating mass balances and performing integrated process optimization because it contains several key species, uses a mechanistic electrolyte thermodynamic model, and is based on a reasonable process configuration; and (3) Appreciable improvement to model fidelity can be realized by expanding the species list and the list of chemical and phase transformations. A path forward is proposed focusing on the use of an improved electrolyte thermodynamic property method, addition of chemical and phase transformations for key species currently absent from the model, and the combination of RGibbs and Flash blocks to simulate simultaneous phase and chemical equilibria in the off-gas treatment train.

Nichols, T.T.; Taylor, D.D.; Wood, R.A.; Barnes, C.M.

2002-08-15T23:59:59.000Z

386

Steady-State Simulation of Steam Reforming of INEEL Tank Farm Waste  

SciTech Connect

A steady-state model of the Sodium-Bearing Waste steam reforming process at the Idaho National Engineering and Environmental Laboratory has been performed using the commercial ASPEN Plus process simulator. The preliminary process configuration and its representation in ASPEN are described. As assessment of the capability of the model to mechanistically predict product stream compositions was made, and fidelity gaps and opportunities for model enhancement were identified, resulting in the following conclusions: 1) Appreciable benefit is derived from using an activity coefficient model for electrolyte solution thermodynamics rather than assuming ideality (unity assumed for all activity coefficients). The concentrations of fifteen percent of the species present in the primary output stream were changed by more than 50%, relative to Electrolyte NRTL, when ideality was assumed; 2) The current baseline model provides a good start for estimating mass balances and performing integrated process optimization because it contains several key species, uses a mechanistic electrolyte thermodynamic model, and is based on a reasonable process configuration; and 3) Appreciable improvement to model fidelity can be realized by expanding the species list and the list of chemical and phase transformations. A path forward is proposed focusing on the use of an improved electrolyte thermodynamic property method, addition of chemical and phase transformations for key species currently absent from the model, and the combination of RGibbs and Flash blocks to simulate simultaneous phase and chemical equilibria in the off-gas treatment train.

Nichols, Todd Travis; Taylor, Dean Dalton; Wood, Richard Arthur; Barnes, Charles Marshall

2002-08-01T23:59:59.000Z

387

Steady-State Thermal Performance Evaluation of Steel-Framed Wall Assembly with Local Foam Insulation  

DOE Green Energy (OSTI)

During January and May, 2009, two configurations of steel-framed walls constructed with conventional 2 4 steel studs insulated with R-19 ~14cm. (5.5-in. thick) and R-13 ~9cm. (3.5-in. thick) fiberglass insulation batts were tested in the Oak Ridge National Laboratory (ORNL) guarded hot-box using ASTM C1363 test procedure. The first test wall used conventional 2 4 steel studs insulated with 2.5-cm. (1-in.) thick foam profiles, called stud snugglers. These stud snugglers converted the 2 4 wall assembly into a 2 6 assembly allowing application of R-19 fiberglass insulation. The second wall tested for comparison was a conventional 2 4 steel stud wall using R-13 insulation batts. Further, numerical simulations were performed in order to evaluate the steady-state thermal performance of various wood- and steel-framed wall assemblies. The effects of adding the stud-snugglers to the wood and steel studs were also investigated numerically. Different combinations of insulation and framing factor were used in the simulations.

Kosny, Jan [ORNL; Biswas, Kaushik [ORNL; Childs, Phillip W [ORNL

2010-01-01T23:59:59.000Z

388

Cancellation of vorticity in steady-state non-isentropic flows of complex fluids  

E-Print Network (OSTI)

In steady-state non-isentropic flows of perfect fluids there is always thermodynamic generation of vorticity when the difference between the product of the temperature with the gradient of the entropy and the gradient of total enthalpy is different from zero. We note that this property does not hold in general for complex fluids for which the prominent influence of the material substructure on the gross motion may cancel the thermodynamic vorticity. We indicate the explicit condition for this cancellation (topological transition from vortex sheet to shear flow) for general complex fluids described by coarse-grained order parameters and extended forms of Ginzburg-Landau energies. As a prominent sample case we treat first Korteweg's fluid, used commonly as a model of capillary motion or phase transitions characterized by diffused interfaces. Then we discuss general complex fluids. We show also that, when the entropy and the total enthalpy are constant throughout the flow, vorticity may be generated by the inhomogeneous character of the distribution of material substructures, and indicate the explicit condition for such a generation. We discuss also some aspects of unsteady motion and show that in two-dimensional flows of incompressible perfect complex fluids the vorticity is in general not conserved, due to a mechanism of transfer of energy between different levels.

Paolo Maria Mariano

2003-07-11T23:59:59.000Z

389

The Effect of Steady Winds on Radon-222 Entry from soil into houses  

Science Conference Proceedings (OSTI)

Wind affects the radon-222 entry rate from soil into buildings and the resulting indoor concentrations. To investigate this phenomenon, we employ a previously tested three-dimensional numerical model of soil-gas Bow around houses, a commercial computational fluid dynamics code, an established model for determining ventilation rates in the presence of wind, and new wind tunnel results for the ground-surface pressure field caused by wind. These tools and data, applied under steady-state conditions to a prototypical residential building, allow us (1) to determine the complex soil-gas flow patterns that result from the presence of wind-generated ground-surface pressures, (2) to evaluate the effect of these flows on the radon concentration in the soil, and (3) to calculate the effect of wind on the radon entry rate and indoor concentration. For a broad range of soil permeabilities, two wind speeds, and two wind directions, we quantify the"flushing" effect of wind on the radon in the soil surrounding a house, and the consequent sharp decrease in radon entry rates. Experimental measurements of the time-dependent radon concentration in soil gas beneath houses confirm the existence of wind-induced flushing. Comparisons are made to modeling predictions obtained while ignoring the effect of the wind-generated ground-surface pressures. These investigations lead to the conclusion that wind-generated ground-surface pressures play a significant role in determining radon entry rates into residential buildings. [References: 26

Riley, W.J.; Gadgil, A.J.; Bonnefous, Y.C.; Nazaroff, W.W.

1994-10-01T23:59:59.000Z

390

SALT (System Analysis Language Translater): A steady state and dynamic systems code  

DOE Green Energy (OSTI)

SALT (System Analysis Language Translater) is a lumped parameter approach to system analysis which is totally modular. The modules are all precompiled and only the main program, which is generated by SALT, needs to be compiled for each unique system configuration. This is a departure from other lumped parameter codes where all models are written by MACROS and then compiled for each unique configuration, usually after all of the models are lumped together and sorted to eliminate undetermined variables. The SALT code contains a robust and sophisticated steady-sate finder (non-linear equation solver), optimization capability and enhanced GEAR integration scheme which makes use of sparsity and algebraic constraints. The SALT systems code has been used for various technologies. The code was originally developed for open-cycle magnetohydrodynamic (MHD) systems. It was easily extended to liquid metal MHD systems by simply adding the appropriate models and property libraries. Similarly, the model and property libraries were expanded to handle fuel cell systems, flue gas desulfurization systems, combined cycle gasification systems, fluidized bed combustion systems, ocean thermal energy conversion systems, geothermal systems, nuclear systems, and conventional coal-fired power plants. Obviously, the SALT systems code is extremely flexible to be able to handle all of these diverse systems. At present, the dynamic option has only been used for LMFBR nuclear power plants and geothermal power plants. However, it can easily be extended to other systems and can be used for analyzing control problems. 12 refs.

Berry, G.; Geyer, H.

1983-01-01T23:59:59.000Z

391

Steady states and linear stability analysis of precipitation pattern formation at geothermal hot springs  

E-Print Network (OSTI)

A dynamical theory of geophysical precipitation pattern formation is presented and applied to irreversible calcium carbonate (travertine) deposition. Specific systems studied here are the terraces and domes observed at geothermal hot springs, such as those at Yellowstone National Park, and speleothems, particularly stalactites and stalagmites. The theory couples the precipitation front dynamics with shallow water flow, including corrections for turbulent drag and curvature effects. In the absence of capillarity and with a laminar flow profile, the theory predicts a one-parameter family of steady state solutions to the moving boundary problem describing the precipitation front. These shapes match well the measured shapes near the vent at the top of observed travertine domes. Closer to the base of the dome, the solutions deviate from observations, and circular symmetry is broken by a fluting pattern, which we show is associated with capillary forces causing thin film break-up. We relate our model to that recently proposed for stalactite growth, and calculate the linear stability spectrum of both travertine domes and stalactites. Lastly, we apply the theory to the problem of precipitation pattern formation arising from turbulent flow down an inclined plane, and identify a linear instability that underlies scale-invariant travertine terrace formation at geothermal hot springs.

Pak Yuen Chan; Nigel Goldenfeld

2007-06-21T23:59:59.000Z

392

Type systems for dummies  

Science Conference Proceedings (OSTI)

We extend Pure Type Systems with a function turning each term M of type A into a dummy |M| of the same type (|.| is not an identity, in that M ? |M|). Intuitively, a dummy represents an unknown, canonical object of the given type: dummies are opaque ... Keywords: canonical element, proof irrelevance, pure type system

Andrea Asperti; Ferruccio Guidi

2012-01-01T23:59:59.000Z

393

Mitigation of thermoacoustic instability utilizing steady air injection near the flame anchoring zone  

Science Conference Proceedings (OSTI)

The objective of this work is to investigate the effectiveness of steady air injection near the flame anchoring zone in suppressing thermoacoustic instabilities driven by flame-vortex interaction mechanism. We perform a systematic experimental study which involves using two different configurations of air injection in an atmospheric pressure backward-facing step combustor. The first configuration utilizes a row of micro-diameter holes allowing for air injection in the cross-stream direction just upstream of the step. The second configuration utilizes an array of micro-diameter holes located on the face of the step, allowing for air injection in the streamwise direction. The effects of each of these configurations are analyzed to determine which one is more effective in suppressing thermoacoustic instabilities at different operating conditions. The tests are conducted while varying the equivalence ratio and the inlet temperature. The secondary air temperature is always the same as the inlet temperature. We used pure propane or propane/hydrogen mixtures as fuels. Combustion dynamics are explored through simultaneous pressure and heat release-rate measurements, and high-speed video images. When the equivalence ratio of the reactant mixture is high, it causes the flame to flashback towards the inlet channel. When air is injected in the cross-stream direction, the flame anchors slightly upstream of the step, which suppresses the instability. When air is injected in the streamwise direction near the edge of step, thermoacoustic instability could be eliminated at an optimum secondary air flow rate, which depends on the operating conditions. When effective, the streamwise air injection prevents the shedding of an unsteady vortex, thus eliminating the flame-vortex interaction mechanism and resulting in a compact, stable flame to form near the step. (author)

Murat Altay, H.; Hudgins, Duane E.; Speth, Raymond L.; Annaswamy, Anuradha M.; Ghoniem, Ahmed F. [Massachusetts Institute of Technology, Department of Mechanical Engineering, Cambridge, MA 02139 (United States)

2010-04-15T23:59:59.000Z

394

Development of microbial-enzyme-mediated decomposition model parameters through steady-state and dynamic analyses  

Science Conference Proceedings (OSTI)

We developed a Microbial-ENzyme-mediated Decomposition (MEND) model, based on the Michaelis-Menten kinetics, that describes the dynamics of physically defined pools of soil organic matter (SOC). These include particulate, mineral-associated, dissolved organic matter (POC, MOC, and DOC, respectively), microbial biomass, and associated exoenzymes. The ranges and/or distributions of parameters were determined by both analytical steady-state and dynamic analyses with SOC data from the literature. We used an improved multi-objective parameter sensitivity analysis (MOPSA) to identify the most important parameters for the full model: maintenance of microbial biomass, turnover and synthesis of enzymes, and carbon use efficiency (CUE). The model predicted an increase of 2 C (baseline temperature =12 C) caused the pools of POC-Cellulose, MOC, and total SOC to increase with dynamic CUE and decrease with constant CUE, as indicated by the 50% confidence intervals. Regardless of dynamic or constant CUE, the pool sizes of POC, MOC, and total SOC varied from 8% to 8% under +2 C. The scenario analysis using a single parameter set indicates that higher temperature with dynamic CUE might result in greater net increases in both POC-Cellulose and MOC pools. Different dynamics of various SOC pools reflected the catalytic functions of specific enzymes targeting specific substrates and the interactions between microbes, enzymes, and SOC. With the feasible parameter values estimated in this study, models incorporating fundamental principles of microbial-enzyme dynamics can lead to simulation results qualitatively different from traditional models with fast/slow/passive pools.

Wang, Gangsheng [ORNL; Post, Wilfred M [ORNL; Mayes, Melanie [ORNL

2013-01-01T23:59:59.000Z

395

ARM - Measurement - Cloud type  

NLE Websites -- All DOE Office Websites (Extended Search)

type ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud type Cloud type such as...

396

A fission-fusion hybrid reactor in steady-state L-mode tokamak configuration with natural uranium  

Science Conference Proceedings (OSTI)

This work develops a conceptual design for a fusion-fission hybrid reactor operating in steady-state L-mode tokamak configuration with a subcritical natural or depleted uranium pebble bed blanket. A liquid lithium-lead alloy breeds enough tritium to replenish that consumed by the D-T fusion reaction. The fission blanket augments the fusion power such that the fusion core itself need not have a high power gain, thus allowing for fully non-inductive (steady-state) low confinement mode (L-mode) operation at relatively small physical dimensions. A neutron transport Monte Carlo code models the natural uranium fission blanket. Maximizing the fission power gain while breeding sufficient tritium allows for the selection of an optimal set of blanket parameters, which yields a maximum prudent fission power gain of approximately 7. A 0-D tokamak model suffices to analyze approximate tokamak operating conditions. This fission blanket would allow the fusion component of a hybrid reactor with the same dimensions as ITER to operate in steady-state L-mode very comfortably with a fusion power gain of 6.7 and a thermal fusion power of 2.1 GW. Taking this further can determine the approximate minimum scale for a steady-state L-mode tokamak hybrid reactor, which is a major radius of 5.2 m and an aspect ratio of 2.8. This minimum scale device operates barely within the steady-state L-mode realm with a thermal fusion power of 1.7 GW. Basic thermal hydraulic analysis demonstrates that pressurized helium could cool the pebble bed fission blanket with a flow rate below 10 m/s. The Brayton cycle thermal efficiency is 41%. This reactor, dubbed the Steady-state L-mode non-Enriched Uranium Tokamak Hybrid (SLEUTH), with its very fast neutron spectrum, could be superior to pure fission reactors in terms of breeding fissile fuel and transmuting deleterious fission products. It would likely function best as a prolific plutonium breeder, and the plutonium it produces could actually be more proliferation-resistant than that bred by conventional fast reactors. Furthermore, it can maintain constant total hybrid power output as burnup proceeds by varying the neutron source strength.

Reed, Mark; Parker, Ronald R.; Forget, Benoit [Department of Nuclear Science and Engineering, Massachusetts Institute of Technology 77 Massachusetts Avenue, Cambridge, MA 02139 (United States)

2012-06-19T23:59:59.000Z

397

Type-checking injective pure type systems  

Science Conference Proceedings (OSTI)

Injective pure type systems form a large class of pure type systems for which one can compute by purely syntactic means two sorts elmt(?∣M) and sort(?∣M), where ? is a pseudo-context and M is a pseudo-term, ...

Gilles Barthe

1999-11-01T23:59:59.000Z

398

STEADY-STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

SciTech Connect

Assess the steady-state flammability level at normal and off-normal ventilation conditions. The methodology of flammability analysis for Hanford tank waste is developed. The hydrogen generation rate model was applied to calculate the gas generation rate for 177 tanks. Flammability concentrations and the time to reach 25% and 100% of the lower flammability limit, and the minimum ventilation rate to keep from 100 of the LFL are calculated for 177 tanks at various scenarios.

HU TA

2007-10-26T23:59:59.000Z

399

Typing constraint logic programs  

Science Conference Proceedings (OSTI)

We present a prescriptive type system with parametric polymorphism and subtyping for constraint logic programs. The aim of this type system is to detect programming errors statically. It introduces a type discipline for constraint logic programs and ... Keywords: Constraint logic programming, Metaprogramming, Prolog, subtyping, type systems

François Fages; Emmanuel Coquery

2001-11-01T23:59:59.000Z

400

ESS 2012 Peer Review - Tehachapi Wind Energy Storage Project Using Li-Ion Batteries - Christopher Clarke, SCE  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Tehachapi Storage Project (TSP) Tehachapi Storage Project (TSP) American Recovery and Reinvestment Act Funded Project Christopher R. Clarke - Southern California Edison (SCE) christopher.r.clarke@sce.com Examples of Wind Generation in the Tehachapi Wind Resource Area August 2012 June 2012 May 2012 February 2012 April 2012 Progress To Date * Facility construction expected to complete in September 2012 * First Power Conversion System installed September 13, 2012 * A123 to ship initial battery equipment for delivery week of September 24, 2012 Future Major Milestones * September 2012 - Completion of BESS facility * October 2012 - Initial installation * November 2012 - Installation of second Power Conversion Subsystem * Q1 2013 - Install balance of equipment and commissioning * Q2 2013 - Start of 2 year M&V testing and reporting

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A new material, Li2Mn2(MoO4)3 for Li-ion batteries: Synthesis and ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The demand for electrically operated devices has led to a variety of ... Co-Production of Pure Hydrogen and Electricity from Coal Syngas via the ...

402

Multi-Scale Multi-Dimensional Li-Ion Battery Model for Better Design and Management (Presentation)  

DOE Green Energy (OSTI)

The developed model used is to provide a better understanding and help answer engineering questions about improving the design, operational strategy, management, and safety of cells.

Kim, G.-H.; Smith, K.

2008-10-01T23:59:59.000Z

403

Platform Li-Ion Battery Risk Assessment Tool: Cooperative Research and Development Final Report, CRADA Number CRD-10-407  

DOE Green Energy (OSTI)

Creare was awarded a Phase 1 STTR contract from the US Office of Naval Research, with a seven month period of performance from 6/28/2010 to 1/28/2011. The objectives of the STTR were to determine the feasibility of developing a software package for estimating reliability of battery packs, and develop a user interface to allow the designer to assess the overall impact on battery packs and host platforms for cell-level faults. NREL served as sub-tier partner to Creare, providing battery modeling and battery thermal safety expertise.

Smith, K.

2012-01-01T23:59:59.000Z

404

TransForum v8n1 - Argonne/Toda Kogyo Partner on Li-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

and nickel-metal hydride battery markets. The company recently acquired a plant in the Detroit area that will help serve U.S. automobile manufacturers. Todas plant in Ontario,...

405

A combined Li-ion & lead-acid battery system for start-stop application: potential & realization.  

E-Print Network (OSTI)

??The aim of this master thesis is to investigate the possibility of using lithium-ion batteries as a second battery instead of lead-acid batteries for the… (more)

Taha Mahmoud, Heza

2011-01-01T23:59:59.000Z

406

Li4Ti5O12 as an anode material for Li ion batteries in situ XRD and XPS studies.  

E-Print Network (OSTI)

?? This thesis examines parts of the kinetics and performance in Li-battery cells using lithium titanate anodes and lithium manganese oxide cathodes. Lithium titanate (Li4Ti5O12)… (more)

Nordh, Tim

2013-01-01T23:59:59.000Z

407

Improvement of Thermal Stability of Li-Ion Batteries by Polymer Coating of LiMn2O4  

E-Print Network (OSTI)

capacity fading of a lithium-ion battery cycled at elevatedthe lifetime of the lithium-ion battery by arresting the Mna challenge in the lithium-ion battery field to identifying

Stroeve, Pieter; Vidu, Ruxandra

2004-01-01T23:59:59.000Z

408

Improvement of Thermal Stability of Li-Ion Batteries by Polymer Coating of LiMn2O4  

E-Print Network (OSTI)

lithium-ion battery by arresting the Mn + dissolution, thereby increasing the battery stability. Key Words: Lithium Battery, Cathode,

Stroeve, Pieter; Vidu, Ruxandra

2004-01-01T23:59:59.000Z

409

A Quantum Leap Forward for Li-Ion Battery Cathodes GCEP Final Technical Report: August 2007 July 2010  

E-Print Network (OSTI)

, nanoscale coating, nanostructures, interface control 1. INTRODUCTION Lithium-ion batteries are one-Induced Damage and Disorder in LiCoO2 Cathodes for Recharge- able Lithium Batteries, J. Electrochem. Soc. 146 Material for Lithium-Ion Batteries, Chem. Mater. 17, 3695 (2005). 27. J. Cho, Y. J. Kim, and B. Park, Novel

Nur, Amos

410

Development of a Novel Test Method for On-Demand Internal Short Circuit in a Li-Ion Cell (Presentation)  

DOE Green Energy (OSTI)

This presentation describes a cell-level test method that simulates an emergent internal short circuit, produces consistent and reproducible test results, can establish the locations and temperatures/power/SOC conditions where an internal short circuit will result in thermal runaway, and provides relevant data to validate internal short circuit models.

Keyser, M.; Long, D.; Jung, Y. S.; Pesaran, A.; Darcy, E.; McCarthy, B.; Patrick, L.; Kruger, C.

2011-01-01T23:59:59.000Z

411

In-Situ Stress Study of Porous V2O5 Films as Li-ion Battery Electrodes  

Science Conference Proceedings (OSTI)

Carbon-Sulfur Nanocomposite Cathode Materials for Lithium-Sulfur Batteries ... Multinuclear Solid and Liquid State NMR Studies of Battery Materials.

412

In-situ Stress Study of V2O5 Thin Film as Li-ion Battery Electrode  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2013. Symposium, Energy Storage III: Materials, Systems and Applications Symposium.

413

Sources of variability and uncertainty in LCA of single wall carbon nanotubes for Li-ion batteries in electric vehicles  

Science Conference Proceedings (OSTI)

Production alternatives for single-walled carbon nanotubes (SWCNT) such as chemical vapor deposition, laser, arc and flame, vary widely in material and energy yields, catalyst requirements and product characteristics. The overall environmental profile ...

Thomas P. Seager; Ryne P. Raffaelle; Brian J. Landi

2008-05-01T23:59:59.000Z

414

PHEV/EV Li-Ion Battery Second-Use Project, NREL (National Renewable Energy Laboratory) (Poster)  

SciTech Connect

Plug-in hybrid electric vehicles (PHEVs) and full electric vehicles (Evs) have great potential to reduce U.S. dependence on foreign oil and emissions. Battery costs need to be reduced by ~50% to make PHEVs cost competitive with conventional vehicles. One option to reduce initial costs is to reuse the battery in a second application following its retirement from automotive service and offer a cost credit for its residual value.

Newbauer, J.; Pesaran, A.

2010-05-01T23:59:59.000Z

415

Platform Li-Ion Battery Risk Assessment Tool: Cooperative Research and Development Final Report, CRADA Number CRD-01-406  

Science Conference Proceedings (OSTI)

The pressure within a lithium-ion cell changes due to various chemical reactions. When a battery undergoes an unintended short circuit, the pressure changes are drastic - and often lead to uncontrolled failure of the cells. As part of work for others with Oceanit Laboratories Inc. for the NAVY STTR, NREL built Computational Fluid Dynamic (CFD) simulations that can identify potential weak spots in the battery during such events, as well as propose designs to control violent failure of batteries.

Santhanagopalan, S.

2012-07-01T23:59:59.000Z

416

In-situ Transmission Electron Microscopy and Spectroscopy Studies of Interfaces in Li-ion Batteries: Challenges and Opportunities  

SciTech Connect

The critical challenge facing the lithium ion battery development is the basic understanding of the structural evolution during the cyclic operation of the battery and the consequence of the structural evolution on the properties of the battery. Although transmission electron microscopy (TEM) and spectroscopy have been evolved to a stage such that it can be routinely used to probe into both the structural and chemical composition of the materials with a spatial resolution of a single atomic column, a direct in-situ TEM observation of structural evolution of the materials in lithium ion battery during the dynamic operation of the battery has never been reported. This is related to three factors: high vacuum operation of a TEM; electron transparency requirement of the region to be observed, and the difficulties dealing with the liquid electrolyte of lithium ion battery. In this paper, we report the results of exploring the in-situ TEM techniques for observation of the interface in lithium ion battery during the operation of the battery. A miniature battery was fabricated using a nanowire and an ionic liquid electrolyte. The structure and chemical composition of the interface across the anode and the electrolyte was studied using TEM imaging, electron diffraction, and electron energy loss spectroscopy. In addition, we also explored the possibilities of carrying out in-situ TEM studies of lithium ion batteries with a solid state electrolyte.

Wang, Chong M.; Xu, Wu; Liu, Jun; Choi, Daiwon; Arey, Bruce W.; Saraf, Laxmikant V.; Zhang, Jiguang; Yang, Zhenguo; Thevuthasan, Suntharampillai; Baer, Donald R.; Salmon, Norman

2010-08-01T23:59:59.000Z

417

Addressing the Impact of Temperature Extremes on Large Format Li-Ion Batteries for Vehicle Applications (Presentation)  

SciTech Connect

This presentation discusses the effects of temperature on large format lithium-ion batteries in electric drive vehicles.

Pesaran, A.; Santhanagopalan, S.; Kim, G. H.

2013-05-01T23:59:59.000Z

418

Quadruple Adaptive Observer of the Core Temperature in Cylindrical Li-ion Batteries and their Health Monitoring  

E-Print Network (OSTI)

for hybrid electric vehicles (HEV), plug-in hybrid electric vehicles (PHEV) and battery electric vehicles@umich.edu, siegeljb@umich.edu and annastef@umich.edu Y. Li and R. D. Anderson are with the Vehicle and Battery Controls De- partment, Research and Advanced Engineering, Ford Motor Company, Dear- born, MI 48121, USA. E

Stefanopoulou, Anna

419

Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries  

E-Print Network (OSTI)

the past few years due to poten- tial applications in both hybrid electric vehicles (HEV) and full electric of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305 vehicles (EV).1-3 Although lithium ion batteries can provide higher energy density (W h/kg) than other

Cui, Yi

420

AlSb thin films as negative electrodes for Li-ion and Na-ion batteries  

SciTech Connect

The electrochemical reactions between Li and Na with amorphous/nanocrystalline AlSb thin films prepared by magnetron sputtering are reported for the first time. The films are composed of AlSb and Sb nanoparticles embedded into an amorphous matrix with an overall Sb/Al ratio of 1.13. The reaction with Li proceeds with an average reaction potential of 0.65 V, a reversible capacity of 750 mAh g-1, and very fast reaction kinetics. For instance, a storage capacity close to 500 mAh g-1, corresponding to 70% of the maximum capacity, is achieved at 125 C-rate. In addition, there is only a small increase in overpotentials with increasing current: ~0.15 V at 12 C and ~0.7 V at 125 C. In contrast, the reaction with Na results in average reaction potential of 0.5 V and a storage capacity of 500 mAh g-1 obtained at low currents. The capacity retention and reaction kinetics are presently not satisfactory with pronounced capacity losses upon cycling and large overpotentials with increasing current. The capacity retention can be improved by using fluoroethylene carbonate additive in the Na-ion electrolyte, which highlights that the Solid Electrolyte Interphase plays an important role for the electrode cycling stability. The reaction kinetics is relatively poor and an increase in overpotentials of about 0.9 V at 2 C is observed (retained capacity of about 350 mAh g-1 or 66% of the maximum). The study of the reaction mechanism on thick films (3-5 m) by X-ray diffraction reveals that the electrode material remains amorphous at all potentials. The presence of broad humps, located at the positions expected for Li-Al and Li-Sb line compounds, suggests that during the reaction with Li the atomic short range ordering is similar to the expected phases.

Baggetto, Loic [ORNL; Marszewski, Michal [Kent State University; Gorka, Joanna [ORNL; Jaroniec, Mietek [Kent State University; Veith, Gabriel M [ORNL

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

First-principles modeling of thermal stability and morphology control of cathode materials in Li-ion batteries  

E-Print Network (OSTI)

We compute the energy of a large number of oxidation reactions of 3d transition metal oxides using the generalized gradient approximation (GGA) to density functional theory and GGA+ U method. Two substantial contributions ...

Wang, Lei, Ph.D. Massachusetts Institute of Technology

2010-01-01T23:59:59.000Z

422

An investigation of the impedance rise and power fade in high-power, Li-ion cells.  

DOE Green Energy (OSTI)

Two different cell chemistries, Gen 1 and Gen 2, were subjected to accelerated aging experiments. In Gen 1 calendar life experiments, useful cell life was strongly affected by temperature and time. Higher temperature accelerated cell performance degradation. The rates of impedance increase and power fade followed simple laws based on a power of time and Arrhenius kinetics. The data have been modeled using these two concepts, and the calculated data agree well with the experimental values. The Gen 1 calendar life increase and power fade data follow (time){sup 1/2} kinetics. This may be due to solid electrolyte interface (SEI) layer growth. From the cycle life experiments, the impedance increase data follow (time){sup 1/2} kinetics also, there is an apparent change in overall power fade mechanism, from 3% to 6% {Delta}SOC. Here, the power of time changes to a value less than 0.5 indicating that the power fade mechanism is due to factors more complex than just SEI layer growth. The Gen 2 calendar and cycle life experiments show the effect of cell chemistry on kinetics. The calendar life impedance data follow either ''linear'' or (time){sup 1/2} plus linear kinetics, depending on time and temperature.

Bloom, I.; Jones, S. A.; Battaglia, V. S.; Polzin, E. G.; Henriksen, G. L.; Motloch, C. G.; Christophersen, J. P.; Belt, J. R.; Ho, C. D.; Wright, R. B.; Jungst, R. G.; Case, H. L.; Doughty, D. H.

2002-07-18T23:59:59.000Z

423

An investigation of the resistance rise and power fade in high-power Li-ion cells.  

DOE Green Energy (OSTI)

Two different cell chemistries, Gen 1 and Gen 2, were subjected to accelerated aging experiments. In Gen 1 calendar-life experiments, useful cell life was strongly affected by temperature and time. Higher temperatures accelerated the degradation of cell performance. The rates of resistance increase and power fade followed simple laws based on a power of time and Arrhenius kinetics. The data have been modeled using these two concepts, and the calculated data agree well with the experimental values. The Gen 1 calendar-life resistance increase and power fade data follow (time){sup 1/2} kinetics. This may be due to solid electrolyte interface (SEI) layer growth. From the cycle-life experiments, the resistance increase data also follow (time){sup 1/2} kinetics. But there is an apparent change in overall power fade mechanism going from 3% to 6% {Delta}SOC. Here, the power of time changes to a value less than 0.5, indicating that the power fade mechanism is more complex than layer growth. The Gen 2 calendar- and cycle-life experiments show the effect of cell chemistry on kinetics. The calendar-life resistance and power fade follow either linear or linear plus (time){sup 1/2} kinetics, depending on temperature. Temperature dependence for the kinetic law was also found in the cycle-life data. At 25 C, the resistance increase (and power fade) follows linear kinetics, while at 45 C, (time){sup 1/2} kinetics are found.

Bloom, I.; Jones, S. A.; Battaglia, V. S.; Polzin, E. G.; Henriksen, G. L.; Motloch, C. G.; Christophersen, J. P.; Belt, J. R.; Ho, C. D.; Wright, R. B.; Jungst, R. G.; Case, H. L.; Doughty, D. H.

2002-02-20T23:59:59.000Z

424

Regular Object Types  

E-Print Network (OSTI)

Regular expression types have been proposed as a foundation for statically typed processing of XML and similar forms of tree-structured data. To date, however, regular expression types have been explored in special-purpose languages (e.g., XDuce, CDuce, and XQuery) with type systems designed around regular expression types "from the ground up." The goal of the Xtatic language is to bring regular expression types to a broad audience by offering them as a lightweight extension of a popular object-oriented language, C#. We develop...

Vladimir Gapeyev; Benjamin C. Pierce

2003-01-01T23:59:59.000Z

425

Types of Radiation Exposure  

NLE Websites -- All DOE Office Websites (Extended Search)

External Irradiation Contamination Incorporation Biological Effects of Acute, Total Body Irradiation Managing Radiation Emergencies Procedure Demonstration Types of radiation...

426

Concurrent calorimetric and interferometric studies of steady-state natural convection from miniaturized horizontal single plate-fin systems and plate-fin arrays  

E-Print Network (OSTI)

Concurrent calorimetric and interferometric studies have been conducted to investigate the effect that reduction of the base-plate dimensions has on the steady-state performance of the rate of natural convection heat ...

Harahap, Filino

427

Low-Frequency Variability in Shallow-Water Models of the Wind-Driven Ocean Circulation. Part I: Steady-State Solution  

Science Conference Proceedings (OSTI)

Successive bifurcations—from steady states through periodic to aperiodic solutions—are studied in a shallow-water, reduced-gravity, 2½-layer model of the midlatitude ocean circulation subject to time-independent wind stress. The bifurcation ...

Eric Simonnet; Michael Ghil; Kayo Ide; Roger Temam; Shouhong Wang

2003-04-01T23:59:59.000Z

428

The Evaluation of the Heat Loading from Steady, Transient, and Off-Normal Conditions in ARIES Power Plants  

Science Conference Proceedings (OSTI)

The heat loading on plasma facing components (PFCs) provides a critical limitation for design and operation of the first wall, divertor, and other special components. Power plants will have high power entering the scrape-off layer and transporting to the first wall and divertor. Although the design for steady heat loads is understood, the approach for transient and offnormal loading is not. The characterization of heat loads developed for ITER1 can be applied to power plants to better develop the operating space of viable solutions and point to research focus areas.

C.E. Kessel, M.S. Tillack and J. Blanchard

2012-09-07T23:59:59.000Z

429

Tritium distribution in the environment in the vicinity of a chronic atmospheric source-assessment of the steady state hypothesis  

Science Conference Proceedings (OSTI)

The Savannah River Site (SRS) is a major radionuclide production center. Tritium has been released to the atmosphere over the 36 year period of operation. The tritiated water concentration of the atmosphere, rain, vegetation and food have been routinely monitored during this period. Special studies have been made of tritium in soils and in the organic fractions of these same materials. The available data suggest that the average tritium concentration in the components of the terrestrial environment have approached a steady state with the two main sources of tritium, rainfall and atmospheric water vapor.

Murphy, C.E. Jr.; Bauer, L.R.; Zeigler, C.C.

1990-12-31T23:59:59.000Z

430

Tritium distribution in the environment in the vicinity of a chronic atmospheric source-assessment of the steady state hypothesis  

Science Conference Proceedings (OSTI)

The Savannah River Site (SRS) is a major radionuclide production center. Tritium has been released to the atmosphere over the 36 year period of operation. The tritiated water concentration of the atmosphere, rain, vegetation and food have been routinely monitored during this period. Special studies have been made of tritium in soils and in the organic fractions of these same materials. The available data suggest that the average tritium concentration in the components of the terrestrial environment have approached a steady state with the two main sources of tritium, rainfall and atmospheric water vapor.

Murphy, C.E. Jr.; Bauer, L.R.; Zeigler, C.C.

1990-01-01T23:59:59.000Z

431

Type B Drum packages  

Science Conference Proceedings (OSTI)

The Type B Drum package is a container in which a single drum containing Type B quantities of radioactive material will be packaged for shipment. The Type B Drum containers are being developed to fill a void in the packaging and transportation capabilities of the US Department of Energy (DOE), as no double containment packaging for single drums of Type B radioactive material is currently available. Several multiple-drum containers and shielded casks presently exist. However, the size and weight of these containers present multiple operational challenges for single-drum shipments. The Type B Drum containers will offer one unshielded version and, if needed, two shielded versions, and will provide for the option of either single or double containment. The primary users of the Type B Drum container will be any organization with a need to ship single drums of Type B radioactive material. Those users include laboratories, waste retrieval facilities, emergency response teams, and small facilities.

Edwards, W.S.

1995-11-01T23:59:59.000Z

432

Photoluminescence studies of type-II CdSe/CdTe superlattices  

SciTech Connect

CdSe/CdTe type-II superlattices grown on GaSb substrates by molecular beam epitaxy are studied using time-resolved and steady-state photoluminescence (PL) spectroscopy at 10 K. The relatively long carrier lifetime of 188 ns observed in time-resolved PL measurements shows good material quality. The steady-state PL peak position exhibits a blue shift with increasing excess carrier concentration. Self-consistent solutions of the Schroedinger and Poisson equations show that this effect can be explained by band bending as a result of the spatial separation of electrons and holes, which is critical confirmation of a strong type-II band edge alignment between CdSe and CdTe.

Li Jingjing; Johnson, Shane R.; Wang Shumin; Ding Ding; Ning Cunzheng; Zhang Yonghang [Center for Photonics Innovation, Arizona State University, Tempe, Arizona 85287-5706 (United States); School of Electrical, Computer, and Energy Engineering, Arizona State University, Tempe, Arizona 85287-5706 (United States); Yin Leijun [Center for Photonics Innovation, Arizona State University, Tempe, Arizona 85287-5706 (United States); Department of Physics, Arizona State University, Tempe, Arizona 85287-1504 (United States); Skromme, B. J. [School of Electrical, Computer, and Energy Engineering, Arizona State University, Tempe, Arizona 85287-5706 (United States); Liu Xinyu; Furdyna, Jacek K. [Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

2012-08-06T23:59:59.000Z

433

Modeling Tritium Transport in PbLi Breeder Blankets Under Steady State  

SciTech Connect

Tritium behavior in the breeder/coolant plays a crucial role in keeping the tritium loss under an allowable limit and realizing high tritium recovery efficiency. In this paper, progress toward the development of a comprehensive 3D predictive capability is discussed and presented. The sequence of transport processes leading to tritium release includes diffusion and convection through the PbLi, transfer across the liquid/solid interface, diffusion of atomic tritium through the structure, and dissolution-recombination at the solid/gas interface. Numerical simulation of the coupled individual physics phenomena of tritium transport is performed for DCLL/HCLL type breeder blankets under realistic reactor-like conditions in this paper. Tritium concentration and permeation are presented and the MHD effects are evaluated. Preliminary results shows that the MHD velocity profile has the significant effect in preventing tritium permeation due to the higher convection effects near the wall.

H. Zhang; A. Ying; M. Abdou; B. Merrill

2011-08-01T23:59:59.000Z

434

Modeling of absorption heat pumps: solar applications employing chemical storage and steady-state modeling with a comparison to experiments  

SciTech Connect

This work develops simulation models for absorption heat pumps (AHPs) with the goal of enabling a more analytical approach to their study and design. A continuous, liquid absorbent AHP with chemical storage is modeled using mass and energy balances and assuming mass transfer equilibrium. This model is used with the TRNSYS program to simulate the performance of an AHP in a residential solar-driven heating and cooling system. The steady-state and cyclic testing of a prototype gas-fired ammonia-water AHP in an environmental chamber is described; measurements include temperatures, pressures, absorbent concentrations, flow rates and heat flows. The coefficient of performance and heating capacity depend most strongly on ambient temperature; varying the load water temperature and flow rate has lesser effects. The performance of the unit is sensitive to refrigerant charge, with the optimum charge varying with ambient temperature. This AHP shows a significant performance degradation in cyclic operation. A modular, steady-state simulation program for absorption heat pumps in developed and validated with experimental data. The model utilizes an analysis of the refrigerant and absorbent inventory to set the system pressures.

McLinden, M.O.

1984-01-01T23:59:59.000Z

435

Nanosecond Time Resolved and Steady State Infrared Studies of Photoinduced Decomposition of TATB at Ambient and Elevated Pressures  

SciTech Connect

The timescale and/or products of photo-induced decomposition of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) were investigated at ambient pressure and compared with products formed at elevated pressure (i.e. 8 GPa). Ultrafast time-resolved infrared and steady state Fourier transform IR (FTIR) spectroscopies were used to probe TATB and its products after photoexcitation with a 5 ns pulse of 532 nm light. At ambient pressure, transient spectra of TATB indicate that the molecule has significantly decomposed within 60 ns; transient spectra also indicate that formation of CO{sub 2}, an observed decomposition product, is complete within 30-40 s. Proof of principle time resolved experiments at elevated pressures were performed and are discussed briefly. Comparison of steady-state FTIR spectra obtained at ambient and elevated pressure (ca. 8 GPa) indicate that the decomposition products vary with pressure. We find evidence for water as a decomposition product only at elevated pressure.

Glascoe, E A; Zaug, J M; Armstrong, M R; Crowhurst, J C; Grant, C D; Fried, L E

2009-03-05T23:59:59.000Z

436

TYPE OF UPERATICIN  

Office of Legacy Management (LM)

Process i Theoretical Studies Sample & Analysis 0 Production 0 DisposalStorage a Facility Type 0 Manufacturing q University, a Research Organizatiori 0 Government Sponsored...

437

TYPES OF FIELD TESTING  

NLE Websites -- All DOE Office Websites (Extended Search)

TYPES OF FIELD TESTING Convincing proof of energy savings and performance in a specific building and occupant context If direct proof of savings is desired, the only feasible...

438

Discriminative sum types locate the source of type errors  

Science Conference Proceedings (OSTI)

We propose a type system for locating the source of type errors in an applied lambda calculus with ML-style polymorphism. The system is based on discriminative sum types---known from work on soft typing---with annotation subtyping and recursive types. ... Keywords: polymorphism, type errors, type inference

Matthias Neubauer; Peter Thiemann

2003-08-01T23:59:59.000Z

439

A steady state thermal duct model derived by fin-theory approach and applied on an unglazed solar collector  

SciTech Connect

This paper presents the thermal modelling of an unglazed solar collector (USC) flat panel, with the aim of producing a detailed yet swift thermal steady-state model. The model is analytical, one-dimensional (1D) and derived by a fin-theory approach. It represents the thermal performance of an arbitrary duct with applied boundary conditions equal to those of a flat panel collector. The derived model is meant to be used for efficient optimisation and design of USC flat panels (or similar applications), as well as detailed thermal analysis of temperature fields and heat transfer distributions/variations at steady-state conditions; without requiring a large amount of computational power and time. Detailed surface temperatures are necessary features for durability studies of the surface coating, hence the effect of coating degradation on USC and system performance. The model accuracy and proficiency has been benchmarked against a detailed three-dimensional Finite Difference Model (3D FDM) and two simpler 1D analytical models. Results from the benchmarking test show that the fin-theory model has excellent capabilities of calculating energy performances and fluid temperature profiles, as well as detailed material temperature fields and heat transfer distributions/variations (at steady-state conditions), while still being suitable for component analysis in junction to system simulations as the model is analytical. The accuracy of the model is high in comparison to the 3D FDM (the prime benchmark), as long as the fin-theory assumption prevails (no 'or negligible' temperature gradient in the fin perpendicularly to the fin length). Comparison with the other models also shows that when the USC duct material has a high thermal conductivity, the cross-sectional material temperature adopts an isothermal state (for the assessed USC duct geometry), which makes the 1D isothermal model valid. When the USC duct material has a low thermal conductivity, the heat transfer course of events adopts a 1D heat flow that reassembles the conditions of the 1D simple model (for the assessed USC duct geometry); 1D heat flow through the top and bottom fins/sheets as the duct wall reassembles a state of adiabatic condition. (author)

Stojanovic, B.; Hallberg, D.; Akander, J. [Building Materials Technology, KTH Research School, Centre for Built Environment, University of Gaevle, SE-801 76 Gaevle (Sweden)

2010-10-15T23:59:59.000Z

440

An Improved Type Reduction Algorithm for Type-2 Fuzzy Sets.  

E-Print Network (OSTI)

??Type reduction does the work of computing the centroid of a type-2 fuzzy set. The result is a type-1 fuzzy set from which a corresponding… (more)

Su, Yao-Lung

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Screw Type Ac Air Compressor Manufacturers, Screw Type Ac Air ...  

U.S. Energy Information Administration (EIA)

Screw Type Ac Air Compressor, Screw Type Ac Air Compressor Manufacturers & Suppliers Directory - Find here Screw Type Ac Air Compressor Traders, ...

442

Optimization of steady-state and hybrid operations in a tokamak fusion reactor by using divertor scaling models  

SciTech Connect

Steady-state and hybrid-mode operation of a tokamak fusion reactor is investigated by power balance calculations, and operation points are optimized with respect to divertor heat load. The dependence of the divertor heat load on a variety of models is also discussed. Several schemes to reduce the heat load are investigated, and the goal of physics research and development is clarified. Hybrid-mode operation appears to be suitable for technology testing, which requires a long burn time and a high neutron wall load. The divertor heat load can be reduced to the ignition-mode level without impurity seeding if the energy confinement is enhanced by 10%. The relation between the divertor heat load and the controllability of the current profile, that is, the fraction of the beam-driven current, is also discussed. 9 refs., 17 figs., 4 tabs.

Murakami, Yoshiki; Sugihara, Masayoshi (Japan Atomic Energy Research Institute, Naka-machi (Japan))

1993-12-01T23:59:59.000Z

443

Pityriasis rubra pilaris, type IV  

E-Print Network (OSTI)

Pityriasis rubra pilaris, type IV Jennifer Bragg MD,rubra pilaris (PRP), type IV (circumscribed juvenile).Type IV PRP develops in prepubertal children, is typically

Bragg, Jennifer; Witkiewicz, Agnieszka; Orlow, Seth J; Schaffer, Julie V

2005-01-01T23:59:59.000Z

444

Pityriasis rubra pilaris, type 1  

E-Print Network (OSTI)

Pityriasis rubra pilaris, type 1 Alexandria V Booth MD andhemorrhages [ 1 ]. Five types of pityriasis rubra pilarisand prognosis. The five types include the classic adult and

Booth, Alexandria V; Ma, Linglei

2005-01-01T23:59:59.000Z

445

Types of Thermocouples  

Science Conference Proceedings (OSTI)

Table 1   Properties of standard thermocouples...Table 1 Properties of standard thermocouples Type Thermoelements Base composition Melting point, °C Resisivity nΩ · m Recommended

446

Manufacturer: Panasonic Battery Type: ...  

NLE Websites -- All DOE Office Websites (Extended Search)

Battery Specifi cations Manufacturer: Panasonic Battery Type: Nickel Metal Hydride Rated Capacity: 5.5 Ahr Rated Power: Not Available Nominal Pack Voltage: 158.4 VDC Nominal Cell...

447

Type I Tanks  

NLE Websites -- All DOE Office Websites (Extended Search)

I Tanks I Tanks * 12 Type I tanks were built between 1951-53 * 750,000 gallon capacity; 75 feet in diameter by 24 ½ feet high * Partial secondary containment with leak detection * Contain approximately 10 percent of the waste volume * 7 Type I tanks have leaked waste into the tank annulus; the amount of waste stored in these tanks is kept below the known leak sites that have appeared over the decades of

448

Dispersed-flow film boiling in rod-bundle geometry: steady-state heat-transfer data and correlation comparisons. [PWR; BWR  

SciTech Connect

Assessment of six film boiling correlations and one single-phase vapor correlation has been made using data from 22 steady state upflow rod bundle tests (series 3.07.9). Bundle fluid conditions were calculated using energy and mass conservation considerations. Results of the steady state film boiling tests support the conclusions reached in the analysis of prior transient tests 3.03.6AR, 3.06.6B, and 3.08.6C. Comparisons between experimentally determined and correlation-predicted heat transfer coefficients, are presented.

Yoder, G. L.; Morris, D. G.; Mullins, C. B.; Ott, L. J.; Reed, D. A.

1982-03-01T23:59:59.000Z

449

The Napier Type System  

E-Print Network (OSTI)

Persistent programming is concerned with the construction of large and long lived systems of data. In designing and building persistent object systems, we are attempting to regularise the activities that are performed on data by programming languages, operating systems, database management systems and file systems. We have identified the following areas of research which we are investigating in the context of persistent systems. They are: controlling complexity, protection of data, orthogonal persistence, controlled system evolution and concurrent computation. In this paper, we describe the data modelling facilities of the Napier type system. We also demonstrate the flexible and incremental nature of the type checking mechanism that is required for persistent programming. The type system is central to the nature of the Napier language and we will demonstrate how it has been designed to solve problems in the five areas identified above.

R. Morrison; A.L. Brown; R. Carrick; R.C.H. Connor; A. Dearle; M.P. Atkinson

1989-01-01T23:59:59.000Z

450

TYPE OF OPERATION  

Office of Legacy Management (LM)

3!NEEi_S1 3!NEEi_S1 past: -~~~-~~~~~-~~~---------- current: ------------_------------- Owner contacted q yes g no; if ye=, date contacted TYPE OF OPERATION --~~__--~-~~~---- 5 Research & Development 5 Facility Type 0 Production scale testing c1 Pilot Scale 0 Bench Scale Process z Theareti cal Studi es Sample Sr Analysis 0 Production D Disposal/Storage TYPE OF CONTRACT ---------------- 0 Manufacturing 0 University 0 Research Clrganization B Government Cpanaored Faci 1 i ty 0 Other ~~---~~---_--~~-----_ a Prime 13 Subcontract& D PurcSase Order 0 Other information (i.e., cost + fixed fee, unit price, time & material, +z) ----_----------------------- Cantract/Purchaae Order #-d-z=&-/) -2_7~-------------Is_------------ PERIOD: CONTRACTING I%~(?) - 1465

451

EVSE Features  

NLE Websites -- All DOE Office Websites (Extended Search)

UL listed UL listed Approximate size (H x W x D inches) 17 x 14 x 6 Charge level AC Level 2 Input voltage 208VAC to 240 VAC Maximum input current 32 Amp Circuit breaker rating 40 Amp Test Conditions 1 Test date 2/1/2012 Nominal supply voltage (Vrms) 208.89 Supply frequency (Hz) 60.00 Initial ambient temperature (°F) 52 Test Vehicle 1,3 Make and model 2011 Chevrolet Volt Battery type Li-ion Steady state charge power (AC kW) 3.06 Maximum charge power (AC kW) 3.21 EVSE Test Results 1,2,4 EVSE consumption prior to charge (AC W) 3.21 EVSE consumption during steady state charge (AC W) 23.75 EVSE consumption post charge (AC W) 3.26 Efficiency during steady state charge 99.24% NOTE: Charge start and charge end power demand curves are dependent upon the vehicle

452

Types of quantum information  

E-Print Network (OSTI)

Quantum, in contrast to classical, information theory, allows for different incompatible types (or species) of information which cannot be combined with each other. Distinguishing these incompatible types is useful in understanding the role of the two classical bits in teleportation (or one bit in one-bit teleportation), for discussing decoherence in information-theoretic terms, and for giving a proper definition, in quantum terms, of ``classical information.'' Various examples (some updating earlier work) are given of theorems which relate different incompatible kinds of information, and thus have no counterparts in classical information theory.

Robert B. Griffiths

2007-07-25T23:59:59.000Z

453

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE [SEC 1 & 2  

DOE Green Energy (OSTI)

Flammable gases such as hydrogen, ammonia, and methane are observed in the tank dome space of the Hanford Site high-level waste tanks. This report assesses the steady-state flammability level under normal and off-normal ventilation conditions in the tank dome space for 177 double-shell tanks and single-shell tanks at the Hanford Site. The steady-state flammability level was estimated from the gas concentration of the mixture in the dome space using estimated gas release rates, Le Chatelier's rule and lower flammability limits of fuels in an air mixture. A time-dependent equation of gas concentration, which is a function of the gas release and ventilation rates in the dome space, has been developed for both soluble and insoluble gases. With this dynamic model, the time required to reach the specified flammability level at a given ventilation condition can be calculated. In the evaluation, hydrogen generation rates can be calculated for a given tank waste composition and its physical condition (e.g., waste density, waste volume, temperature, etc.) using the empirical rate equation model provided in Empirical Rate Equation Model and Rate Calculations of Hydrogen Generation for Hanford Tank Waste, HNF-3851. The release rate of other insoluble gases and the mass transport properties of the soluble gas can be derived from the observed steady-state gas concentration under normal ventilation conditions. The off-normal ventilation rate is assumed to be natural barometric breathing only. A large body of data is required to do both the hydrogen generation rate calculation and the flammability level evaluation. For tank waste that does not have sample-based data, a statistical-based value from probability distribution regression was used based on data from tanks belonging to a similar waste group. This report (Revision 3) updates the input data of hydrogen generation rates calculation for 177 tanks using the waste composition information in the Best-Basis Inventory Detail Report in the Tank Waste Information Network System, and the waste temperature data in the Surveillance Analysis Computer System (SACS) (dated July 2003). However, the release rate of methane, ammonia, and nitrous oxide is based on the input data (dated October 1999) as stated in Revision 0 of this report. Scenarios for adding waste to existing waste levels (dated July 2003) have been studied to determine the gas generation rates and the effect of smaller dome space on the flammability limits to address the issues of routine water additions and other possible waste transfer operations. In the flammability evaluation with zero ventilation, the sensitivity to waste temperature and to water addition was calculated for double-shell tanks 241-AY-102, 241-AN-102,241-AZ-101,241-AN-107,241-AY-101 and 241-AZ-101. These six have the least margin to flammable conditions among 28 double-shell tanks.

HU, T.A.

2003-09-30T23:59:59.000Z

454

Conditional belief types  

E-Print Network (OSTI)

We study type spaces where a player’s type at a state is a conditional probability on the space. We axiomatize these type spaces using conditional belief operators, and examine three additional axioms of increasing strength. First, introspection, which requires the agent to be unconditionally certain of her beliefs. Second, echo, according to which the unconditional beliefs implied by the condition must be held given the condition. Third, determination, which says that the conditional beliefs are the unconditional beliefs that are conditionally certain. The echo axiom implies that conditioning on an event is the same as conditioning on the event being certain, which formalizes the standard informal interpretation of conditioning in probability theory. The echo axiom also implies that the conditional probability given an event is a prior of the unconditional probability. The game-theoretic application of our model, which we treat in the context of an example, sheds light on a number of basic issues in the analysis of extensive form games. Type spaces are closely related to the sphere models of counterfactual conditionals and to models of hypothetical knowledge, and we discuss these relationships in detail.

Alfredo Di; Tillio Joseph; Y. Halpern; Dov Samet

2013-01-01T23:59:59.000Z

455

Spray type wet scrubber  

SciTech Connect

A spray type wet scrubber includes a plurality of spray nozzles installed in parallel banks across the path of gas stream within the scrubber body, and partition walls held upright in grating fashion to divide the path of gas stream into a plurality of passages, each of which accommodates one of the spray nozzles.

Atsukawa, M.; Tatani, A.

1978-01-10T23:59:59.000Z

456

Types of Multinet System  

Science Conference Proceedings (OSTI)

A limiting factor in research on combining classifiers is a lack of awareness of the full range of available modular structures. One reason for this is that there is as yet little agreement on a means of describing and classifying types of multiple classifier ...

Amanda J. C. Sharkey

2002-06-01T23:59:59.000Z

457

Comment on "Steady-state fluctuations of a genetic feedback loop: an exact solution" [J. Chem. Phys. {\\bf 137}, 035104 (2012).  

E-Print Network (OSTI)

The comment is intended to answer the criticism presented on `Steady-state fluctuations of a genetic feedback loop: an exact solution' [J. Chem. Phys. {\\bf 137}, 035104 (2012).] and provides the missing component for the complete analytic solutions to the author's model.

Guilherme C. P. Innocentini; Alexandre F. Ramos; José Eduardo M. Hornos

2013-02-20T23:59:59.000Z

458

Application of a Polythermal Three-Dimensional Ice Sheet Model to the Greenland Ice Sheet: Response to Steady-State and Transient Climate Scenarios  

Science Conference Proceedings (OSTI)

Steady-state and transient climate-change computations are performed with the author’s three-dimensional polythermal ice sheet model Simulation Code for Polythermal Ice Sheets for the Greenland Ice Sheet. The distinctive feature of this model is ...

Ralf Greve

1997-05-01T23:59:59.000Z

459

A Model for the Influence of Wind and Oceanic Currents on the Size of a Steady-State Latent Heat Coastal Polynya  

Science Conference Proceedings (OSTI)

This paper presents a model for determining the size and shape of a steady-state latent heat coastal polynya in terms of the following free parameters: 1) the frazil ice production rate (F); 2) the wind stress (?); 3) the surface ocean velocity ...

A. J. Willmott; M. A. Morales Maqueda; M. S. Darby

1997-10-01T23:59:59.000Z

460

High-Order Terms in the Asymptotic Expansions of the Steady-State Voltage Potentials in the Presence of Conductivity Inhomogeneities of Small Diameter  

E-Print Network (OSTI)

We derive high-order terms in the asymptotic expansions of the steady-state voltage potentials in the presence of a finite number of diametrically small inhomogeneities with conductivities different from the background conductivity. Our derivation is rigorous, and based on layer potential techniques. The asymptotic expansions in this paper are valid for inhomogeneities with Lipschitz boundaries and those with extreme conductivities.

Habib Ammari; Hyeonbae Kang

2001-12-12T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Method and apparatus for steady-state magnetic measurement of poloidal magnetic field near a tokamak plasma  

DOE Patents (OSTI)

A method and apparatus for the steady-state measurement of poloidal magnetic field near a tokamak plasma, where the tokamak is configured with respect to a cylindrical coordinate system having z, phi (toroidal), and r axes. The method is based on combining the two magnetic field principles of induction and torque. The apparatus includes a rotor assembly having a pair of inductive magnetic field pickup coils which are concentrically mounted, orthogonally oriented in the r and z directions, and coupled to remotely located electronics which include electronic integrators for determining magnetic field changes. The rotor assembly includes an axle oriented in the toroidal direction, with the axle mounted on pivot support brackets which in turn are mounted on a baseplate. First and second springs are located between the baseplate and the rotor assembly restricting rotation of the rotor assembly about its axle, the second spring providing a constant tensile preload in the first spring. A strain gauge is mounted on the first spring, and electronic means to continually monitor strain gauge resistance variations is provided. Electronic means for providing a known current pulse waveform to be periodically injected into each coil to create a time-varying torque on the rotor assembly in the toroidal direction causes mechanical strain variations proportional to the torque in the mounting means and springs so that strain gauge measurement of the variation provides periodic magnetic field measurements independent of the magnetic field measured by the electronic integrators.

Woolley, R.D.

1996-12-31T23:59:59.000Z

462

Method and apparatus for steady-state magnetic measurement of poloidal magnetic field near a tokamak plasma  

DOE Patents (OSTI)

A method and apparatus for the steady-state measurement of poloidal magnetic field near a tokamak plasma, where the tokamak is configured with respect to a cylindrical coordinate system having z, phi (toroidal), and r axes. The method is based on combining the two magnetic field principles of induction and torque. The apparatus includes a rotor assembly having a pair of inductive magnetic field pickup coils which are concentrically mounted, orthogonally oriented in the r and z directions, and coupled to remotely located electronics which include electronic integrators for determining magnetic field changes. The rotor assembly includes an axle oriented in the toroidal direction, with the axle mounted on pivot support brackets which in turn are mounted on a baseplate. First and second springs are located between the baseplate and the rotor assembly restricting rotation of the rotor assembly about its axle, the second spring providing a constant tensile preload in the first spring. A strain gauge is mounted on the first spring, and electronic means to continually monitor strain gauge resistance variations is provided. Electronic means for providing a known current pulse waveform to be periodically injected into each coil to create a time-varying torque on the rotor assembly in the toroidal direction causes mechanical strain variations proportional to the torque in the mounting means and springs so that strain gauge measurement of the variation provides periodic magnetic field measurements independent of the magnetic field measured by the electronic integrators.

Woolley, Robert D. (Hillsborough, NJ)

1998-01-01T23:59:59.000Z

463

The Local Instability of Steady Astrophysical Flows with non Circular Streamlines with Application to Differentially Rotating Disks with Free Eccentricity  

E-Print Network (OSTI)

We carry out a general study of the stability of astrophysical flows that appear steady in a uniformly rotating frame. Such a flow might correspond to a stellar pulsation mode or an accretion disk with a free global distortion giving it finite eccentricity. We consider perturbations arbitrarily localized in the neighbourhood of unperturbed fluid streamlines.When conditions do not vary around them, perturbations take the form of oscillatory inertial or gravity modes. However, when conditions do vary so that a circulating fluid element is subject to periodic variations, parametric instability may occur. For nearly circular streamlines, the dense spectra associated with inertial or gravity modes ensure that resonance conditions can always be satisfied when twice the period of circulation round a streamline falls within. We apply our formalism to a differentially rotating disk for which the streamlines are Keplerian ellipses, with free eccentricity up to 0.7, which do not precess in an inertial frame. We show that for small $e,$ the instability involves parametric excitation of two modes with azimuthal mode number differing by unity in magnitude which have a period of twice the period of variation as viewed from a circulating unperturbed fluid element. Instability persists over a widening range of wave numbers with increasing growth rates for larger eccentricities. The nonlinear outcome is studied in a follow up paper which indicates development of small scale subsonic turbulence.

J. C. B. Papaloizou

2004-12-22T23:59:59.000Z

464

Scripting the type inference process  

Science Conference Proceedings (OSTI)

To improve the quality of type error messages in functional programming languages,we propose four techniques which influence the behaviour of constraint-based type inference processes. These techniques take the form of externally supplied type inference ... Keywords: constraints, directives, domain-specific programming, type errors, type inference

Bastiaan Heeren; Jurriaan Hage; S. Doaitse Swierstra

2003-08-01T23:59:59.000Z

465

Calculation note: project W-320 primary ventilation air flowrequirements for mitigation of steady state flammable gasconcentrations in the headspaces of tanks 241-C-106 and 241-AY-102  

DOE Green Energy (OSTI)

This calculation note analyzes headspace concentrations of hydrogen dependent upon assumed ventilation flow rates provided for tanks 241-C-106 and 241-AY-102. The analyses are based on measured or estimated steady state hydrogen release rates. Tank 241-C-106 is analyzed prior to sluicing; tank 241-AY-102 is analyzed both prior to and after completion of sluicing. Specific analyses, using both best estimated and bounding hydrogen generation rates, include the minimum primary ventilation flow rates required in the tanks to ensure that the steady state hydrogen concentration in the respective tank headspace does not exceed 25% and 100% of the LFL. The headspace hydrogen concentration as a function of time as well as the time required to reach 25% and 100% of LFL upon complete loss of active ventilation, starting from the steady state hydrogen concentration based on a 200 CFM minimum flow rate in tank 241-C-106 and a 100 CFM minimum flow rate in tank241-AY-102. The headspace hydrogen concentration as a function of thee following partial loss of active ventilation (i.e., step changes to l60, l20, 80, and 40 CFM ventilation flow rates) in tank 241-C-106, staffing from a 200 CFM flow rate and the corresponding steady state hydrogen concentration based on the 200 CFM flow rate. The headspace hydrogen concentration as a function of the following partial loss of active ventilation i.e., step changes to 80, 60, 40, and 20 CFM ventilation flow rates) in tank 241-AY-102, starting from a 100 CFM flow rate and the corresponding steady state hydrogen concentration based on the 100 CFM flow rate.

Estey, S.D.

1997-06-04T23:59:59.000Z

466

TYPE OF OPERATION  

Office of Legacy Management (LM)

Owner c:ontacted Owner c:ontacted TYPE OF OPERATION ----------------_ jJ Research & Development 0 Production scale testing Cl Pilot Scale 0 Bench Scale Process i Theoretical Studies Sample & Analysis B Production 0 Disposal/Storage $r Prime 0 Subcontract& 0 Purchase Order 0 Facility Type 0 Manufacturing 0 University 0 Research Organization a Other information (i.e., cost + fixed fern, unit price,' time & mate ~r~~-r~~tf~-_~_-_~-~f-~~J~ d ial, etc)_kl/Jlfits ---- -7---- -- Contract/Purchase Order # w?@7-e?-b $ 6, i;,_~~~~~----------------- - ----- C_O!!IF!KXYE-PEELEg: -lTlL-/L?~J --------------------------- OWNERSHXP: AEWHEC AEC/HED' GOVT GB' JT SiXiRACTOR CONiRkCiGR WEE LEAs_EE a!!!%? IEEE!? --------_ ..---LEASED ._ OWNED LANDS BUILDINGS EQUIPMENT

467

TYPE OF OPERATION  

Office of Legacy Management (LM)

~~__--------_____ ~~__--------_____ q Research & Development q Production scale testing Cl Pilat Scale 0 Bench Scale Process 0 Theoretical Studies a Sample & Analysis c] Production 0 Disposal/Storage TYPE OF CONTRACT ~~__-------_--__ 0 Prime 0 Subcontractor 0 Purchase Order a d//F- a Faci 1 i ty Type a tlanuf acturi ng 0 University q Research Organization 0 Government Sponsored Facility a other --------------__----- Other information (i.e., cost + fixed fee, unit price, time & material, qtr) ------- -1------------------_L______ Contract/Purchase Order # CONTRACTING PE?IOD- 42 --------------L---- --------- ----------------_---______ OWNERSHIP: AEC/MED AEC/tlED OWNED ----- LE_A_sEE GOUT GO' JT CONTRACTOR E!!!!E!z LEASED - ----_ ---_OW_E!L LANDS BUILDINGS

468

TYPE OF OPERATION  

Office of Legacy Management (LM)

OWNEF? (S) OWNEF? (S) Current: ____ LcrcJksLG! _________ Owner contacted n yes WI-IO; if yes, date contacted-- TYPE OF OPERATION ----_-------_---- m Research & Development Cl Pilot Scale Cl Disposal/Storaqe TYPE OF CDNTRACT ---__------__--- q Prime 0 Subcnntractor Cl Purchase Order 0 Other infcrmation (i.e., cnst + fixed fee, unit price, time 84 materi+, e.tc) v-7Y07-&G-W ---------------------------- Contract/Pur&aae Order # 0 -?+7- FJc-(CL --___--------~----_______________ CONTRACTING PEXIOD: fl& ,&I;'"'-?;': (&e-?)_-- ' ------------------ OWNERSHIP: AEC/MED GEC/MED SOVT GOVT CONTRACTOR CCNTRACTOR OWNE3 LEASE3 OWNE3 LEASED OWNE3 ----- ------ ----- ------ -__------- LE.352 LANDS u u q BUILDINGS EQUIPMENT 0 FINAL PRODUCT WASTE G RESIDUE a

469

Solar-type Variables  

E-Print Network (OSTI)

The rich acoustic oscillation spectrum in solar-type variables make these stars particularly interesting for studying fluid-dynamical aspects of the stellar interior. I present a summary of the properties of solar-like oscillations, how they are excited and damped and discuss some of the recent progress in using asteroseismic diagnostic techniques for analysing low-degree acoustic modes. Also the effects of stellar-cycle variations in low-mass main-sequence stars are addressed.

Houdek, Gunter

2009-01-01T23:59:59.000Z

470

Practical pluggable types for Java  

E-Print Network (OSTI)

This paper introduces the Checker Framework, which supports adding pluggable type systems to the Java language in a backward-compatible way. A type system designer defines type qualifiers and their semantics, and a compiler ...

Papi, Matthew M

2008-01-01T23:59:59.000Z

471

Practical pluggable types for Java.  

E-Print Network (OSTI)

??This paper introduces the Checker Framework, which supports adding pluggable type systems to the Java language in a backward-compatible way. A type system designer defines… (more)

Papi, Matthew M

2008-01-01T23:59:59.000Z

472

Type inference for datalog with complex type hierarchies  

Science Conference Proceedings (OSTI)

Type inference for Datalog can be understood as the problem of mapping programs to a sublanguage for which containment is decidable. To wit, given a program in Datalog, a schema describing the types of extensional relations, and a user-supplied set of ... Keywords: datalog, type inference, type system

Max Schäfer; Oege de Moor

2010-01-01T23:59:59.000Z

473

Evaluation of uncertainties due to hydrogeological modeling and groundwater flow analysis: Steady flow, transient flow, and thermal studies  

SciTech Connect

Starting with regional geographic, geologic, surface and subsurface hydrologic, and geophysical data for the Tono area in Gifu, Japan, we develop an effective continuum model to simulate subsurface flow and transport in a 4 km by 6 km by 3 km thick fractured granite rock mass overlain by sedimentary layers. Individual fractures are not modeled explicitly. Rather, continuum permeability and porosity distributions are assigned stochastically, based on well-test data and fracture density measurements. Lithologic layering and one major fault, the Tsukiyoshi Fault, are assigned deterministically. We conduct three different studies: (1) the so-called base case, in which the model simulates the steady-state groundwater flow through the site, and then stream trace analysis is used to calculate travel times to the model boundary from specified release points; (2) simulations of transient flow during long term pump tests (LTPT) using the base-case model; and (3) thermal studies in which coupled heat flow and fluid flow are modeled, to examine the effects of the geothermal gradient on groundwater flow. The base-case study indicates that the choice of open or closed lateral boundaries has a strong influence on the regional groundwater flow patterns produced by the models, but no field data exist that can be used to determine which boundary conditions are more realistic. The LTPT study cannot be used to distinguish between the alternative boundary conditions, because the pumping rate is too small to produce an analyzable pressure response at the model boundaries. In contrast, the thermal study shows that the temperature distributions produced by the open and closed models differ greatly. Comparison with borehole temperature data may be used to eliminate the closed model from further consideration.

Doughty, Christine; Karasaki, Kenzi

2002-12-11T23:59:59.000Z

474

TYPE OF OPERATION  

Office of Legacy Management (LM)

_---------_-- _---------_-- Research & Development 0 Production scale testing Cl Pilat Scale 0 Bench Scale Process 0 Theoretical Studies Cl Sample SC Analysis !J Production 0 Dis.posal/Storage 0 Prime ." 0 Subcontract& 0 Purchase Order 0 Facility Type 0 Manufacturing 0 University 0 Research Org&ization 0 Government Sponsored Facility Cl Other ---------_---__-____- Other information (i.e., cost + fixed fee, unit price, time & material, gtr) Coni+act/Purchase Order # ---------------------_--_________ C!2kEE~_CIL_N_G-EE~LE~: /5J--L-,r4 53 -------------------------------------- OWNERSHIP: AEC/MED AEC/MED GOVT GOVT CONTRACTOR CONTRACTOR !w!!E? ___--- " EWNED LEASED L_EesEE OWNED LEASED ---------_ --_------ LANDS BUILDINGS ' EQUIPMENT

475

Forecast Technical Document Forecast Types  

E-Print Network (OSTI)

Forecast Technical Document Forecast Types A document describing how different forecast types are implemented in the 2011 Production Forecast system. Tom Jenkins Robert Matthews Ewan Mackie Lesley Halsall #12;PF2011 ­ Forecast Types Background Different `types' of forecast are possible for a specified area

476

Type inference for generic Haskell  

E-Print Network (OSTI)

Abstract. The more expressive a type system, the more type information has to be provided in a program. Having to provide a type is sometimes a pain, but lacking expressivity is often even worse. There is a continuous struggle between expressivity and (type-)verbosity. However, even very expressive type systems allow type inference for parts of a program. Generic Haskell is an extension of Haskell that supports defining generic functions. Generic Haskell assumes that the type of a generic function is explicitly specified. This is often no problem, but sometimes it is rather painful to have to specify a type – in particular for generic functions with many dependencies – and sometimes the specified type can be generalized. In this paper, we identify three type inference problems specific to generic functions, and present (partial) solutions to each of them. 1

Alexey Rodriguez; Johan Jeuring; Andres Löh

2005-01-01T23:59:59.000Z

477

TYPE OF OPERATION  

Office of Legacy Management (LM)

______ ______ 0 Research & Development 9 Faciiity Type 0 Production scale testing Cl Pilot Scale 0 Bench Scale Process 0 Theoretical Studies Cl Sample 84 Analysis Production Di aposal /Storage g ;E:"V',;=:;;';"" IJ Research Organization 0 Government Sponeored Facility q Other --------------------- 0 Prime q ,@ Subcontract& Other information (i.e., cost 0 Purchase Order + fixed fee, unit price, time ?8 material, etc) -------mm----+------------- Contract/Purchase Order # CONTRACTING PERIODr c&L&.& rqs-z i i -----~_--~~~_----_ -------------------------------------- OWNERSHIP8 CIEC/tlED CIEC/MED GOUT WNED LE&xU _o!!EED LANDS BUILDINGS EQUIPMENT iii E : ORE OR RAW MATL IJ : E FINCIL PRODUCT [7 WCISTE b RESIDUE q GOUT

478

TYPE OF OPERATION  

Office of Legacy Management (LM)

----------------- ----------------- 0 Research & Development .a Production scale testing 0 Pilat Scale 0 Bench Scale Process 0 Thearetical Studies Cl Sample 84 Analysis 0 Production *i DiaposalKitorage Cl Facility Tybe q Government Sponsored Facility Other R.L- 6:e 14 1 1 ---------- --------- I I I TYPE OF CONTRACT ~-__-----------_ fl Prime *I 0 Subcantractbr Other infuriation (i.e., L.t + fixed fee, kit price, 0 Purchase Order time k mat*iik, gtc) /I -~---------'-t-----------~- ----------II---------------- Contract/Purchase Order # I EP!EBEII!G-PEEI9E: ---------------------------------~---- , OWNERSHiP: : I I j ,' / 1 AEC/tlED AEC/MED GOUT GOUT E!!NE_D LEASEI! !z%!NE_D CONTTACTOR CONTf?qCTOR LEASE?? ---w!En- ---LEL3SEI! i I I I LANDS BUILDINGS EIXIIPMENT

479

Development of hardware simulators for tests of solar cooling/heating subsystems and systems. Phase 1. Residential subsystem hardware simulator and steady state simulation  

DOE Green Energy (OSTI)

The proposed hardware simulator has been successfully built at the Solar Technology Group Laboratory of BNL, and it has been operational since its construction. The hardware simulator has the following unique features: it has been incorporated with a measurement-double-checking system, it is a totally closed-loop system, it employs three separate energy storage tanks, and it has been automated to perform instantaneous data collection and reduction. With the external energy storage, all the external test conditions can be easily set up for any steady state or transient run. The simulator is described in detail with schematics and actual photographs. The steady state testing of Arkla's Solaire 36 absorption chiller has been performed. The test dealt primarily with chiller capacity or coefficient-of-performance (COP) as a function of generator hot water inlet temperature (1) with condenser cooling water inlet temperature as parameter, and (2) with evaporator chilled water outlet temperature as parameter.

Auh, P.C.

1979-09-01T23:59:59.000Z

480

Evaluation of Suspected Steady-State Magnetic Induction by a 345-kV Double-Circuit Transmission Line onto Railroad Track  

Science Conference Proceedings (OSTI)

CenterPoint Energy operates a double circuit 345-kV transmission line north of Houston that parallels the Burlington Northern Santa Fe Railroad (BNSF) for approximately 15 miles. The railroad is experiencing elevated steady-state 60-Hz voltage in the parallel exposure. AC voltages and currents in railroad track can come from many sources. And, railroad systems can withstand reasonable amounts of this electromagnetic interference (EMI) without problems. When problems with EMI on a railroad do appear, it i...

2008-11-12T23:59:59.000Z

Note: This page contains sample records for the topic "type li-ion steady" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


481

Modeling the steady-state ISV (in situ vitrification) process: A 3-D finite element analysis of coupled thermal-electric fields  

Science Conference Proceedings (OSTI)

Steady-state modeling considerations for simulating the in situ vitrification (ISV) process are documented based upon the finite element numerical approach. Recommendations regarding boundary condition specifications and mesh discretization are presented. The effects of several parameters on the ISV process response are calculated and the results discussed. The parameters investigated include: (1) electrode depth, (2) ambient temperature, (3) supplied current, (4) electrical conductivity, (5) electrode separation, and (6) soil/waste characterization. 13 refs., 29 figs., 1 tab.

Langerman, M.A.

1990-09-01T23:59:59.000Z

482

Scoping heat transfer analysis of a completely-blocked Type-Q septifoil  

Science Conference Proceedings (OSTI)

Heat removal mechanisms for a completely-blocked Type-Q (new design) septifoil situated in an otherwise normally operating K-reactor are investigated in this report. The best-estimate maximum septifoil heat generation rate for a 26.2{degrees}C cooling water inlet temperature is 119 to 141 kW depending on the counter-current flow limitation correlation chosen. The corresponding reactor powers are 648 and 768 MW or 27 and 32% of 2400 MW (historical annual averaged full power). These estimates are based on a steady-state scoping analysis and have a large uncertainty.

Flach, G.P.

1991-12-01T23:59:59.000Z

483

PLANETESIMAL FORMATION AT THE BOUNDARY BETWEEN STEADY SUPER/SUB-KEPLERIAN FLOW CREATED BY INHOMOGENEOUS GROWTH OF MAGNETOROTATIONAL INSTABILITY  

Science Conference Proceedings (OSTI)

We have studied formation of planetesimals at a radial pressure bump in a protoplanetary disk created by radially inhomogeneous magnetorotational instability (MRI), through three-dimensional resistive MHD simulations including dust particles. In our previous papers, we showed that the inhomogeneous MRI developing in non-uniform structure of magnetic field or magnetic resistivity can transform the local gas flow in the disk to a quasi-steady state with local rigid rotation that is no longer unstable against the MRI. Since the outer part of the rigid rotation is super-Keplerian flow, a quasi-static pressure bump is created and dust concentration is expected there. In this paper, we perform simulations of the same systems, adding dust particles that suffer gas drag and modulate gas flow via the back-reaction of the gas drag (dust drag). We use {approx}O(10{sup 7}) super-particles, each of which represents {approx}O(10{sup 6})-O(10{sup 7}) dust particles with sizes of centimeter to meter. We have found that the dust drag suppresses turbulent motion to decrease the velocity dispersion of the dust particles while it broadens the dust concentrated regions to limit peaky dust concentration, compared with the simulation without the dust drag. We found that the positive effect for the gravitational instability (GI), reduction in the velocity dispersion, dominates over the negative one, suppression in particle concentration. For meter-size particles with the friction time {tau}{sub f} {approx_equal} 1/{Omega}, where {Omega} is Keplerian frequency, the GI of the dust particles that may lead to planetesimal formation is expected. For such a situation, we further introduced the self-gravity of dust particles to the simulation to demonstrate that several gravitationally bound clumps are actually formed. Through analytical arguments, we found that planetesimal formation from meter-sized dust particles is possible at {approx}5 AU, if dust spatial density is a few times larger than that in the minimum mass solar nebula.

Kato, M. T.; Ida, S. [Department of Earth and Planetary Science, Tokyo Institute of Technology, Ookayama 2-1-12-I2-10, Meguro-ku, Tokyo (Japan); Fujimoto, M., E-mail: ida@geo.titech.ac.jp [Institute of Space and Astronomical Science, Japan Aerospace Exploration Agency, Yoshinodai 3-1-1 Sagamihara, Kanagawa (Japan)

2012-03-01T23:59:59.000Z

484

Sensitivity of transport and stability to the current profile in steady-state scenario plasmas in DIII-D  

SciTech Connect

Recent experiments on DIII-D have provided the first systematic data on the impact of the current profile on the transport and stability properties of high-performance, steady-state scenario plasmas. In a future tokamak, to achieve 100% noninductive conditions and produce net power, the current profile J must be sustained by a large fraction of bootstrap current J{sub BS}, which is nonlinearly coupled with the kinetic profiles. Systematic scans of q{sub min} and q{sub 95} were performed to determine empirically the best alignment of the noninductive currents with J and the variation of the transport properties with q. Transport analysis indicates that {chi}{sub e} and {chi}{sub i} are sensitive to the details of J in a way that makes the pressure profile peaking and J{sub BS} scale nonlinearly with both q and {beta} in the experiment. Drift wave stability analysis yields linear growth rates that do not reproduce experimental trends in {chi} with q{sub min} and q{sub 95}. At high beta, necessary to maximize f{sub BS}, the plasma duration is often limited by n=1 tearing modes, whose stability also depends on the J profile. Broadly deposited electron cyclotron (EC) current at mid-radius was found to supply part of the required noninductive current and to positively affect the tearing stability. The modes appear when J{sub EC} is turned off for stable cases and always appear when the EC deposition is shifted outwards. The variation in the EC scan results is consistent with PEST3 calculations, showing that the tearing stability becomes extremely sensitive to small perturbations of the equilibrium in wall-stabilized plasmas run close to the ideal MHD limit. These modeling results are being used to design new experiments with higher ideal and tearing limits. A new capability for off-axis neutral beam injection system will be used to explore higher q{sub min} scenarios and different current alignments.

Turco, F.; Hanson, J. M. [Columbia University, New York, New York 10027 (United States); Holcomb, C. T. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Ferron, J. R.; Luce, T. C.; Politzer, P. A.; Turnbull, A. D. [General Atomics, P.O. Box 85608, San Diego, California 92186-5608 (United States); Park, J. M. [Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); White, A. E. [Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Brennan, D. P. [University of Tulsa, Tulsa, Oklahoma 74104 (United States); Okabayashi, M. [Princeton Plasma Physics Laboratory, Princeton 08543, New Jersey (United States); In, Y. [Far-Tech, Inc., San Diego, California 92121 (United States)

2012-12-15T23:59:59.000Z

485

NESTLE: Few-group neutron diffusion equation solver utilizing the nodal expansion method for eigenvalue, adjoint, fixed-source steady-state and transient problems  

Science Conference Proceedings (OSTI)

NESTLE is a FORTRAN77 code that solves the few-group neutron diffusion equation utilizing the Nodal Expansion Method (NEM). NESTLE can solve the eigenvalue (criticality); eigenvalue adjoint; external fixed-source steady-state; or external fixed-source. or eigenvalue initiated transient problems. The code name NESTLE originates from the multi-problem solution capability, abbreviating Nodal Eigenvalue, Steady-state, Transient, Le core Evaluator. The eigenvalue problem allows criticality searches to be completed, and the external fixed-source steady-state problem can search to achieve a specified power level. Transient problems model delayed neutrons via precursor groups. Several core properties can be input as time dependent. Two or four energy groups can be utilized, with all energy groups being thermal groups (i.e. upscatter exits) if desired. Core geometries modelled include Cartesian and Hexagonal. Three, two and one dimensional models can be utilized with various symmetries. The non-linear iterative strategy associated with the NEM method is employed. An advantage of the non-linear iterative strategy is that NSTLE can be utilized to solve either the nodal or Finite Difference Method representation of the few-group neutron diffusion equation.

Turinsky, P.J.; Al-Chalabi, R.M.K.; Engrand, P.; Sarsour, H.N.; Faure, F.X.; Guo, W. [North Carolina State Univ., Raleigh, NC (United States)

1994-06-01T23:59:59.000Z

486

A type system for CHR  

E-Print Network (OSTI)

We propose a generic type system for the Constraint Handling Rules (CHR), a rewriting rule language for implementing constraint solvers. CHR being a high-level extension of a host language, such as Prolog or Java, this type system is parameterized by the type system of the host language. We show the consistency of the type system for CHR w.r.t. its operational semantics. We also study the case when the host language is a constraint logic programming language, typed with the prescriptive type system we developed in our previous work. In particular, we show the consistency of the resulting type system w.r.t. the extended execution model CLP+CHR. This system is implemented through an extension of our type checker TCLP for constraint logic languages. We report on experimental results about the type-checking of 12 CHR solvers and programs, including TCLP itself.

Emmanuel Coquery; François Fages

2005-01-01T23:59:59.000Z

487

Pluggable type-checking for custom type qualifiers in Java  

E-Print Network (OSTI)

We have created a framework for adding custom type qualifiers to the Javalanguage in a backward-compatible way. The type system designer definesthe qualifiers and creates a compiler plug-in that enforces theirsemantics. ...

Papi, Matthew M.

2007-09-17T23:59:59.000Z

488

Tornado type wind turbines  

DOE Patents (OSTI)

A tornado type wind turbine has a vertically disposed wind collecting tower with spaced apart inner and outer walls and a central bore. The upper end of the tower is open while the lower end of the structure is in communication with a wind intake chamber. An opening in the wind chamber is positioned over a turbine which is in driving communication with an electrical generator. An opening between the inner and outer walls at the lower end of the tower permits radially flowing air to enter the space between the inner and outer walls while a vertically disposed opening in the wind collecting tower permits tangentially flowing air to enter the central bore. A porous portion of the inner wall permits the radially flowing air to interact with the tangentially flowing air so as to create an intensified vortex flow which exits out of the top opening of the tower so as to create a low pressure core and thus draw air through the opening of the wind intake chamber so as to drive the turbine.

Hsu, Cheng-Ting (Ames, IA)

1984-01-01T23:59:59.000Z

489

A Type Driven Theory of Predication with Complex Types  

Science Conference Proceedings (OSTI)

This paper investigates several models of the complex type • which is needed to analyze copredication. Previous accounts are shown to be inadequate and a new account both of • and copredication is proposed. Keywords: categorial interpretation,, coercion,, complex types,, copredication,, dot(•)types, lambda calculus,

Nicholas Asher

2008-09-01T23:59:59.000Z

490

Generic and maximal Jordan types  

Science Conference Proceedings (OSTI)

Mar 7, 2007 ... •(G,k) we exhibit a “generic Jordan type” of M. In the very special ... specializes to the non-trivial observation that the Jordan type obtained by.

491

Evolutionary Analysis of 11beta-Hydroxysteroid Dehydrogenase-Type 1, -Type 2, -Type 3 and 17beta-Hydroxysteroid Dehydrogenase-Type 2 in Fish  

E-Print Network (OSTI)

metabolized by 11 -hydroxysteroid dehydrogenase-type 1and type 2 andhydroxysteroid dehydrogenase-type 1 and type 2. A. 11 -HSD1

Baker, Michael E

2004-01-01T23:59:59.000Z