National Library of Energy BETA

Sample records for type carbon coefficient

  1. Power coefficient of tornado-type wind turbines

    SciTech Connect (OSTI)

    Rangwalla, A.A.; Hsu, C.T.

    1983-11-01

    In a tornado-type wind turbine the wind collecting tower is equipped with adjustable vanes that can be opened on the windward side and closed on the leeward side. The wind enters the tower tangentially through these open vanes and exits from the top. As a result, a vortex is formed inside the tower. A vertical axis turbine which is located underneath the tower floor admits air vertically and exhausts it into the vortex core. The pressure drop in the vortex core can be high, depending upon the vortex concentration, thus enhancing manyfold the total pressure drop across the turbine. The power coefficient C /SUB p/ of this system depends mainly on how low a pressure can be created in the vortex core. A maximum C /SUB p/ of about 2.5 was obtained by Yen for a spiral shaped tower. This is about 6.25 times the C /SUB p/ of conventional windmills. Analytical studies have been carried out by several investigators to study the C /SUB p/ of this vortex machine. Loth considered the conservation of angular momentum and obtained a C /SUB p/ based on the tower frontal area, which is not impressive.

  2. Molecular dynamics simulation of diffusion coefficients and structural properties of some alkylbenzenes in supercritical carbon dioxide at infinite dilution

    SciTech Connect (OSTI)

    Wang, Jinyang; Zhong, Haimin; Qiu, Wenda; Chen, Liuping; Feng, Huajie

    2014-03-14

    The binary infinite dilute diffusion coefficients, D{sub 12}{sup ?}, of some alkylbenzenes (Ph-C{sub n}, from Ph-H to Ph-C{sub 12}) from 313 K to 333 K at 15 MPa in supercritical carbon dioxide (scCO{sub 2}) have been studied by molecular dynamics (MD) simulation. The MD values agree well with the experimental ones, which indicate MD simulation technique is a powerful way to predict and obtain diffusion coefficients of solutes in supercritical fluids. Besides, the local structures of Ph-C{sub n}/CO{sub 2} fluids are further investigated by calculating radial distribution functions and coordination numbers. It qualitatively convinces that the first solvation shell of Ph-C{sub n} in scCO{sub 2} is significantly influenced by the structure of Ph-C{sub n} solute. Meanwhile, the mean end-to-end distance, the mean radius of gyration and dihedral angle distribution are calculated to gain an insight into the structural properties of Ph-C{sub n} in scCO{sub 2}. The abnormal trends of radial distribution functions and coordination numbers can be reasonably explained in term of molecular flexibility. Moreover, the computed results of dihedral angle clarify that flexibility of long-chain Ph-C{sub n} is the result of internal rotation of C-C single bond (?{sub c-c}) in alkyl chain. It is interesting that compared with n-alkane, because of the existence of benzene ring, the flexibility of alkyl chain in Ph-C{sub n} with same carbon atom number is significantly reduced, as a result, the carbon chain dependence of diffusion behaviors for long-chain n-alkane (n ? 5) and long-chain Ph-C{sub n} (n ? 4) in scCO{sub 2} are different.

  3. A STUDY OF CARBON FEATURES IN TYPE Ia SUPERNOVA SPECTRA (Journal...

    Office of Scientific and Technical Information (OSTI)

    A STUDY OF CARBON FEATURES IN TYPE Ia SUPERNOVA SPECTRA Citation Details In-Document Search Title: A STUDY OF CARBON FEATURES IN TYPE Ia SUPERNOVA SPECTRA One of the major ...

  4. Black Carbon Concentrations and Diesel Vehicle Emission FactorsDerived from Coefficient of Haze Measurements in California:1967-2003

    SciTech Connect (OSTI)

    Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.

    2007-10-01

    We have derived ambient black carbon (BC) concentrations and estimated emission factors for on-road diesel vehicles from archived Coefficient of Haze (COH) data that was routinely collected beginning in 1967 at 11 locations in the San Francisco Bay Area. COH values are a measure of the attenuation of light by particles collected on a white filter, and available data indicate they are proportional to BC concentrations measured using the conventional aethalometer. Monthly averaged BC concentrations are up to five times greater in winter than summer, and, consequently, so is the population's exposure to BC. The seasonal cycle in BC concentrations is similar for all Bay Area sites, most likely due to area-wide decreased pollutant dispersion during wintertime. A strong weekly cycle is also evident, with weekend concentrations significantly lower than weekday concentrations, consistent with decreased diesel traffic volume on weekends. The weekly cycle suggests that, in the Bay Area, diesel vehicle emissions are the dominant source of BC aerosol. Despite the continuous increase in diesel fuel consumption in California, annual Bay Area average BC concentrations decreased by a factor of {approx}3 from the late 1960s to the early 2000s. Based on estimated annual BC concentrations, on-road diesel fuel consumption, and recent measurements of on-road diesel vehicle BC emissions, diesel BC emission factors decreased by an order of magnitude over the study period. Reductions in the BC emission factor reflect improved engine technology, emission controls and changes in diesel fuel composition. A new BC monitoring network is needed to continue tracking ambient BC trends because the network of COH monitors has recently been retired.

  5. Black Carbon Concentrations and Diesel Vehicle Emission Factors Derived from Coefficient of Haze Measurements in California: 1967-2003

    SciTech Connect (OSTI)

    Tast, CynthiaL; Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.; Fairley, David

    2007-11-09

    We have derived ambient black carbon (BC) concentrations and estimated emission factors for on-road diesel vehicles from archived Coefficient of Haze (COH) data that was routinely collected beginning in 1967 at 11 locations in the San Francisco Bay Area. COH values are a measure of the attenuation of light by particles collected on a white filter, and available data indicate they are proportional to BC concentrations measured using the conventional aethalometer. Monthly averaged BC concentrations are up to five times greater in winter than summer, and, consequently, so is the population?s exposure to BC. The seasonal cycle in BC concentrations is similar for all Bay Area sites, most likely due to area-wide decreased pollutant dispersion during wintertime. A strong weekly cycle is also evident, with weekend concentrations significantly lower than weekday concentrations, consistent with decreased diesel traffic volume on weekends. The weekly cycle suggests that, in the Bay Area, diesel vehicle emissions are the dominant source of BC aerosol. Despite the continuous increase in diesel fuel consumption in California, annual Bay Area average BC concentrations decreased by a factor of ~;;3 from the late 1960s to the early 2000s. Based on estimated annual BC concentrations, on-road diesel fuel consumption, and recent measurements of on-road diesel vehicle BC emissions, diesel BC emission factors decreased by an order of magnitude over the study period. Reductions in the BC emission factor reflect improved engine technology, emission controls and changes in diesel fuel composition. A new BC monitoring network is needed to continue tracking ambient BC trends because the network of COH monitors has recently been retired.

  6. Ultra low friction carbon/carbon composites for extreme temperature applications

    DOE Patents [OSTI]

    Erdemir, Ali; Busch, Donald E.; Fenske, George R.; Lee, Sam; Shepherd, Gary; Pruett, Gary J.

    2001-01-01

    A carbon/carbon composite in which a carbon matrix containing a controlled amount of boron or a boron compound is reinforced with carbon fiber exhibits a low coefficient of friction, i.e., on the order of 0.04 to 0.1 at temperatures up to 600.degree. C., which is one of the lowest frictional coefficients for any type of carbonaceous material, including graphite, glassy carbon, diamond, diamond-like carbon and other forms of carbon material. The high degree of slipperiness of the carbon composite renders it particularly adapted for limiting friction and wear at elevated temperatures such as in seals, bearings, shafts, and flexible joints

  7. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    SciTech Connect (OSTI)

    Myint, P. C.; Hao, Y.; Firoozabadi, A.

    2015-03-27

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO2) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data [1]. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi [2], and the CO2 activity coefficient model by Duan and Sun [3]. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO2, pure water, and both CO2-rich and aqueous (H2O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Suns model yields accurate results for the partial molar enthalpy of CO2. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H2O-CO2-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  8. Electronic Durability of Flexible Transparent Films from Type-Specific Single-Wall Carbon Nanotubes

    SciTech Connect (OSTI)

    Harris, J; Iyer, S; Bernhardt, A; Huh, JY; Hudson, S; Fagan, J; Hobbie, E.

    2011-12-11

    The coupling between mechanical flexibility and electronic performance is evaluated for thin films of metallic and semiconducting single-wall carbon nanotubes (SWCNTs) deposited on compliant supports. Percolated networks of type-purified SWCNTs are assembled as thin conducting coatings on elastic polymer substrates, and the sheet resistance is measured as a function of compression and cyclic strain through impedance spectroscopy. The wrinkling topography, microstructure and transparency of the films are independently characterized using optical microscopy, electron microscopy, and optical absorption spectroscopy. Thin films made from metallic SWCNTs show better durability as flexible transparent conductive coatings, which we attribute to a combination of superior mechanical performance and higher interfacial conductivity.

  9. Solar-induced chemical vapor deposition of diamond-type carbon films

    DOE Patents [OSTI]

    Pitts, J. Roland; Tracy, C. Edwin; King, David E.; Stanley, James T.

    1994-01-01

    An improved chemical vapor deposition method for depositing transparent continuous coatings of sp.sup.3 -bonded diamond-type carbon films, comprising: a) providing a volatile hydrocarbon gas/H.sub.2 reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and b) directing a concentrated solar flux of from about 40 to about 60 watts/cm.sup.2 through said reactant mixture to produce substrate temperatures of about 750.degree. C. to about 950.degree. C. to activate deposition of the film on said substrate.

  10. Solar-induced chemical vapor deposition of diamond-type carbon films

    DOE Patents [OSTI]

    Pitts, J.R.; Tracy, C.E.; King, D.E.; Stanley, J.T.

    1994-09-13

    An improved chemical vapor deposition method for depositing transparent continuous coatings of sp[sup 3]-bonded diamond-type carbon films, comprises: (a) providing a volatile hydrocarbon gas/H[sub 2] reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and (b) directing a concentrated solar flux of from about 40 to about 60 watts/cm[sup 2] through said reactant mixture to produce substrate temperatures of about 750 C to about 950 C to activate deposition of the film on said substrate. 11 figs.

  11. A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.

    2013-05-10

    In collaboration with participants of the Coordinating Research Council (CRC) Advanced Vehicle/Fuels/Lubricants (AVFL) Committee, and project AVFL-19, the characteristics of fuels from advanced and renewable sources were compared to commercial diesel fuels. The main objective of this study was to highlight similarities and differences among the fuel types, i.e. ULSD, renewables, and alternative fuels, and among fuels within the different fuel types. This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of 14 diesel fuel samples. The diesel fuel samples come from diverse sources and include four commercial ultra-low sulfur diesel fuels (ULSD), one gas-to-liquid diesel fuel (GTL), six renewable diesel fuels (RD), two shale oil-derived diesel fuels, and one oil sands-derived diesel fuel. Overall, the fuels examined fall into two groups. The two shale oil-derived samples and the oil-sand-derived sample closely resemble the four commercial ultra-low sulfur diesels, with SO1 and SO2 most closely matched with ULSD1, ULSD2, and ULSD4, and OS1 most closely matched with ULSD3. As might be expected, the renewable diesel fuels, with the exception of RD3, do not resemble the ULSD fuels because of their very low aromatic content, but more closely resemble the gas-to-liquid sample (GTL) in this respect. RD3 is significantly different from the other renewable diesel fuels in that the aromatic content more closely resembles the ULSD fuels. Fused-ring aromatics are readily observable in the ULSD, SO, and OS samples, as well as RD3, and are noticeably absent in the remaining RD and GTL fuels. Finally, ULSD3 differs from the other ULSD fuels by having a significantly lower aromatic carbon content and higher cycloparaffinic carbon content. In addition to providing important comparative compositional information regarding the various diesel fuels, this report also provides important information about the capabilities of NMR

  12. Facile synthesis of B-type carbonated nanoapatite with tailored microstructure

    SciTech Connect (OSTI)

    Gualtieri, Magdalena Lassinantti; Romagnoli, Marcello; Hanuskova, Miriam; Fabbri, Elena; Gualtieri, Alessandro F.

    2014-12-15

    Nanolime and a phosphate-based chelating agent were used to synthesize B-type carbonated apatite. Developed Rietveld refinement strategies allowed one to determine process yield, product crystallinity as well as structural (unit cell) and microstructural (size, strain) parameters. The effect of synthesis temperature (20–60 °C) as well as Ca/P ratio (1.5–2.5) and solid content (10–30 wt%) of the starting batch on these properties were investigated. FTIR, TEM and gas adsorption data provided supporting evidence. The process yield was 42–60 wt% and found to be governed by the Ca/P ratio. The purified products had high specific surface area (107–186 m{sup 2}/g) and crystallinity (76–97%). The unit cell parameters, correlated to the degree of structural carbonate, were sensitive to the Ca/P ratio. Instead, temperature governed the microstructural parameters. Less strained and larger crystals were obtained at higher temperatures. Long-term aging up to 6 months at 20 °C compensated for higher crystal growth kinetics at higher temperature. - Graphical abstract: Controlled synthesis of carbonated apatite at moderate temperatures using nanolime and sodiumhexametaphosphate as starting reagent. - Highlights: • Chemical synthesis of nano-sized apatite with tailored microstructure was performed. • Colloidal Ca(OH){sub 2} and a phosphorus-based chelating agents were used as reagents. • The method is simple and reproducible which facilitate industrial process scale-up. • Rietveld refinement strategies for product characterization were developed. • Rietveld analyses provided yield, microstructural and structure information.

  13. Influence of Electronic Type Purity on the Lithiation of Single-Walled Carbon Nanotubes

    SciTech Connect (OSTI)

    Jaber-Ansari, Laila; Iddir, Hakim; Curtiss, Larry A.; Hersam, Mark C.

    2014-03-25

    Single-walled carbon nanotubes (SWCNTs) have emerged as one of the leading additives for high-capacity nanocomposite lithium ion battery electrodes due to their ability to improve electrode conductivity, current collection efficiency, and charge/discharge rate for high power applications. However, since as-grown SWCNTs possess a distribution of physical and electronic structures, it is of high interest to determine which subpopulations of SWCNTs possess the highest lithiation capacity and to develop processing methods that can enhance the lithiation capacity of underperforming SWCNT species. Toward this end, SWCNT electronic type purity is controlled via density gradient ultracentrifugation, enabling a systematic study of the lithiation of SWCNTs as a function of metal versus semiconducting content. Experimentally, vacuum-filtered freestanding films of metallic SWCNTs are found to accommodate lithium with an order of magnitude higher capacity than their semiconducting counterparts, which is consistent with ab initio molecular dynamics and density functional theory calculations in the limit of isolated SWCNTs. In contrast, SWCNT film densification leads to the enhancement of the lithiation capacity of semiconducting SWCNTs to levels comparable to metallic SWCNTs, which is corroborated by theoretical calculations that show increased lithiation of semiconducting SWCNTs in the limit of small SWCNT*SWCNT spacing. Overall, these results will inform ongoing efforts to utilize SWCNTs as conductive additives in nanocomposite lithium ion battery electrodes.

  14. Strong near-infrared carbon in the Type Ia supernova iPTF13ebh

    SciTech Connect (OSTI)

    Hsiao, E. Y.; Burns, C. R.; Contreras, C.; Höflich, P.; Sand, D.; Marion, G. H.; Phillips, M. M.; Stritzinger, M.; González-Gaitán, S.; Mason, R. E.; Folatelli, G.; Parent, E.; Gall, C.; Amanullah, R.; Anupama, G. C.; Arcavi, I.; Banerjee, D. P. K.; Beletsky, Y.; Blanc, G. A.; Bloom, J. S.; Brown, P. J.; Campillay, A.; Cao, Y.; De Cia, A.; Diamond, T.; Freedman, W. L.; Gonzalez, C.; Goobar, A.; Holmbo, S.; Howell, D. A.; Johansson, J.; Kasliwal, M. M.; Kirshner, R. P.; Krisciunas, K.; Kulkarni, S. R.; Maguire, K.; Milne, P. A.; Morrell, N.; Nugent, P. E.; Ofek, E. O.; Osip, D.; Palunas, P.; Perley, D. A.; Persson, S. E.; Piro, A. L.; Rabus, M.; Roth, M.; Schiefelbein, J. M.; Srivastav, S.; Sullivan, M.; Suntzeff, N. B.; Surace, J.; Woźniak, P. R.; Yaron, O.

    2015-05-22

    We present near-infrared (NIR) time-series spectroscopy, as well as complementary ultraviolet (UV), optical, and NIR data, of the Type Ia supernova (SN Ia) iPTF13ebh, which was discovered within two days from the estimated time of explosion. The first NIR spectrum was taken merely 2.3 days after explosion and may be the earliest NIR spectrum yet obtained of a SN Ia. The most striking features in the spectrum are several NIR C I lines, and the C Iλ1.0693 μm line is the strongest ever observed in a SN Ia. Interestingly, no strong optical C II counterparts were found, even though the optical spectroscopic time series began early and is densely cadenced. Except at the very early epochs, within a few days from the time of explosion, we show that the strong NIR C I compared to the weaker optical C II appears to be general in SNe Ia. iPTF13ebh is a fast decliner with Δm15(B) = 1.79 ± 0.01, and its absolute magnitude obeys the linear part of the width-luminosity relation. It is therefore categorized as a “transitional” event, on the fast-declining end of normal SNe Ia as opposed to subluminous/91bg-like objects. iPTF13ebh shows NIR spectroscopic properties that are distinct from both the normal and subluminous/91bg-like classes, bridging the observed characteristics of the two classes. These NIR observations suggest that composition and density of the inner core are similar to that of 91bg-like events, and that it has a deep-reaching carbon burning layer that is not observed in more slowly declining SNe Ia. Furthermore, there is also a substantial difference between the explosion times inferred from the early-time light curve and the velocity evolution of the Si II λ0.6355 μm line, implying a long dark phase of ~4 days.

  15. Strong near-infrared carbon in the Type Ia supernova iPTF13ebh

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hsiao, E. Y.; Burns, C. R.; Contreras, C.; Höflich, P.; Sand, D.; Marion, G. H.; Phillips, M. M.; Stritzinger, M.; González-Gaitán, S.; Mason, R. E.; et al

    2015-05-22

    We present near-infrared (NIR) time-series spectroscopy, as well as complementary ultraviolet (UV), optical, and NIR data, of the Type Ia supernova (SN Ia) iPTF13ebh, which was discovered within two days from the estimated time of explosion. The first NIR spectrum was taken merely 2.3 days after explosion and may be the earliest NIR spectrum yet obtained of a SN Ia. The most striking features in the spectrum are several NIR C I lines, and the C Iλ1.0693 μm line is the strongest ever observed in a SN Ia. Interestingly, no strong optical C II counterparts were found, even though themore » optical spectroscopic time series began early and is densely cadenced. Except at the very early epochs, within a few days from the time of explosion, we show that the strong NIR C I compared to the weaker optical C II appears to be general in SNe Ia. iPTF13ebh is a fast decliner with Δm15(B) = 1.79 ± 0.01, and its absolute magnitude obeys the linear part of the width-luminosity relation. It is therefore categorized as a “transitional” event, on the fast-declining end of normal SNe Ia as opposed to subluminous/91bg-like objects. iPTF13ebh shows NIR spectroscopic properties that are distinct from both the normal and subluminous/91bg-like classes, bridging the observed characteristics of the two classes. These NIR observations suggest that composition and density of the inner core are similar to that of 91bg-like events, and that it has a deep-reaching carbon burning layer that is not observed in more slowly declining SNe Ia. Furthermore, there is also a substantial difference between the explosion times inferred from the early-time light curve and the velocity evolution of the Si II λ0.6355 μm line, implying a long dark phase of ~4 days.« less

  16. Strong near-infrared carbon in the Type Ia supernova iPTF13ebh

    SciTech Connect (OSTI)

    Hsiao, E. Y.; Burns, C. R.; Contreras, C.; Hflich, P.; Sand, D.; Marion, G. H.; Phillips, M. M.; Stritzinger, M.; Gonzlez-Gaitn, S.; Mason, R. E.; Folatelli, G.; Parent, E.; Gall, C.; Amanullah, R.; Anupama, G. C.; Arcavi, I.; Banerjee, D. P. K.; Beletsky, Y.; Blanc, G. A.; Bloom, J. S.; Brown, P. J.; Campillay, A.; Cao, Y.; De Cia, A.; Diamond, T.; Freedman, W. L.; Gonzalez, C.; Goobar, A.; Holmbo, S.; Howell, D. A.; Johansson, J.; Kasliwal, M. M.; Kirshner, R. P.; Krisciunas, K.; Kulkarni, S. R.; Maguire, K.; Milne, P. A.; Morrell, N.; Nugent, P. E.; Ofek, E. O.; Osip, D.; Palunas, P.; Perley, D. A.; Persson, S. E.; Piro, A. L.; Rabus, M.; Roth, M.; Schiefelbein, J. M.; Srivastav, S.; Sullivan, M.; Suntzeff, N. B.; Surace, J.; Wo?niak, P. R.; Yaron, O.

    2015-05-22

    We present near-infrared (NIR) time-series spectroscopy, as well as complementary ultraviolet (UV), optical, and NIR data, of the Type Ia supernova (SN Ia) iPTF13ebh, which was discovered within two days from the estimated time of explosion. The first NIR spectrum was taken merely 2.3 days after explosion and may be the earliest NIR spectrum yet obtained of a SN Ia. The most striking features in the spectrum are several NIR C I lines, and the C I?1.0693 ?m line is the strongest ever observed in a SN Ia. Interestingly, no strong optical C II counterparts were found, even though the optical spectroscopic time series began early and is densely cadenced. Except at the very early epochs, within a few days from the time of explosion, we show that the strong NIR C I compared to the weaker optical C II appears to be general in SNe Ia. iPTF13ebh is a fast decliner with ?m15(B) = 1.79 0.01, and its absolute magnitude obeys the linear part of the width-luminosity relation. It is therefore categorized as a transitional event, on the fast-declining end of normal SNe Ia as opposed to subluminous/91bg-like objects. iPTF13ebh shows NIR spectroscopic properties that are distinct from both the normal and subluminous/91bg-like classes, bridging the observed characteristics of the two classes. These NIR observations suggest that composition and density of the inner core are similar to that of 91bg-like events, and that it has a deep-reaching carbon burning layer that is not observed in more slowly declining SNe Ia. Furthermore, there is also a substantial difference between the explosion times inferred from the early-time light curve and the velocity evolution of the Si II ?0.6355 ?m line, implying a long dark phase of ~4 days.

  17. Carbon-Type Analysis and Comparison of Original and Reblended FACE Diesel Fuels (FACE 2, FACE 4, and FACE 7)

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.; O'Hagan, Molly J.

    2012-10-01

    This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of Fuels for Advanced Combustion Engines (FACE) diesel blends, FD-2B, FD 4B, and FD-7B, and makes comparison of the new blends with the original FACE diesel blends, FD 2A, FD 4A, and FD-7A, respectively. Generally, FD-2A and FD-2B are more similar than the A and B blends of FD-4 and FD-7. The aromatic carbon content is roughly equivalent, although the new FACE blends have decreased monoaromatic content and increased di- and tri-cycloaromatic content, as well as a higher overall aromatic content, than the original FACE blends. The aromatic components of the new FACE blends generally have a higher alkyl substitution with longer alkyl substituents. The naphthenic and paraffinic contents remained relatively consistent. Based on aliphatic methyl and methylene carbon ratios, cetane numbers for FD-2A and -2B, and FD-7A and -7B are predicted to be consistent, while the cetane number for FD-4B is predicted to be higher than FD-4A. Overall, the new FACE fuel blends are fairly consistent with the original FACE fuel blends, but there are observable differences. In addition to providing important comparative compositional information on reformulated FACE diesel blends, this report also provides important information about the capabilities of the team at Pacific Northwest National Laboratory in the use of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  18. Classification of Multiple Types of Organic Carbon Composition in Atmospheric Particles by Scanning Transmission X-Ray Microscopy Analysis

    SciTech Connect (OSTI)

    Kilcoyne, Arthur L; Takahama, S.; Gilardoni, S.; Russell, L.M.; Kilcoyne, A.L.D.

    2007-05-16

    A scanning transmission X-ray microscope at the Lawrence Berkeley National Laboratory is used to measure organic functional group abundance and morphology of atmospheric aerosols. We present a summary of spectra, sizes, and shapes observed in 595 particles that were collected and analyzed between 2000 and 2006. These particles ranged between 0.1 and 12 mm and represent aerosols found in a large range of geographical areas, altitudes, and times. They include samples from seven different field campaigns: PELTI, ACE-ASIA, DYCOMS II, Princeton, MILAGRO (urban), MILAGRO (C-130), and INTEX-B. At least 14 different classes of organic particles show different types of spectroscopic signatures. Different particle types are found within the same region while the same particle types are also found in different geographical domains. Particles chemically resembling black carbon, humic-like aerosols, pine ultisol, and secondary or processed aerosol have been identified from functional group abundance and comparison of spectra with those published in the literature.

  19. Reconstruction of the phase separation ordering type and specific heat in carbon nanotubes

    SciTech Connect (OSTI)

    Ponomarev, Alexander N. E-mail: val110@mail.ru; Egorushkin, Valery E. E-mail: val110@mail.ru; Bobenko, Nadezda G.; Melnikova, Natalia V.

    2014-11-14

    The low-temperature behavior of the specific heat in disordered nanotubes strongly depends on structure changes and was not explained by the phonon contribution. Expression for electronic specific heat was carried out taking into account the multiple elastic scattering of electrons on impurities and structural inhomogeneities of short-range order type, it includes dependence on diameter of nanotube, concentration of impurities, parameters of short-range order (structural heterogeneity) and temperature. Anomalous low-temperature behavior of the specific heat of disordered CNT is shown to have electronic nature and may be associated with the electrons that are involved in restructuring.

  20. PRODUCTION OF THE p-PROCESS NUCLEI IN THE CARBON-DEFLAGRATION MODEL FOR TYPE Ia SUPERNOVAE

    SciTech Connect (OSTI)

    Kusakabe, Motohiko; Iwamoto, Nobuyuki; Nomoto, Ken'ichi E-mail: iwamoto.nobuyuki@jaea.go.jp

    2011-01-01

    We calculate the nucleosynthesis of proton-rich isotopes in the carbon-deflagration model for Type Ia supernovae (SNe Ia). The seed abundances are obtained by calculating the s-process nucleosynthesis that is expected to occur in the repeating helium shell flashes on the carbon-oxygen (CO) white dwarf (WD) during mass accretion from a binary companion. When the deflagration wave passes through the outer layer of the CO WD, p-nuclei are produced by photodisintegration reactions on s-nuclei in a region where the peak temperature ranges from 1.9 to 3.6 x 10{sup 9} K. We confirm the sensitivity of the p-process on the initial distribution of s-nuclei. We show that the initial C/O ratio in the WD does not affect much the yield of p-nuclei. On the other hand, the abundance of {sup 22}Ne left after s-processing has a large influence on the p-process via the {sup 22}Ne({alpha},n) reaction. We find that about 50% of p-nuclides are co-produced when normalized to their solar abundances in all adopted cases of seed distribution. Mo and Ru, which are largely underproduced in Type II supernovae (SNe II), are produced more than in SNe II although they are underproduced with respect to the yield levels of other p-nuclides. The ratios between p-nuclei and iron in the ejecta are larger than the solar ratios by a factor of 1.2. We also compare the yields of oxygen, iron, and p-nuclides in SNe Ia and SNe II and suggest that SNe Ia could make a larger contribution than SNe II to the solar system content of p-nuclei.

  1. Partition coefficients for acetic, propionic, and butyric acids in a crude oil/water system

    SciTech Connect (OSTI)

    Reinsel, M.A.; Borkowski, J.J.; Sears, J.T. . National Science Foundation Engineering Research Center for Biofilm Engineering)

    1994-07-01

    The effects of pH, temperature, and organic acid concentration on the partition coefficients for short-chain organic acids were measured in a crude oil/water system. Acetic, propionic, and butyric acids, as probable substrates for microbial souring of oil reservoirs, were used in conjunction with two types of crude oil. Temperatures of 35--75 C, pH values of 4.0--7.0, and acid concentrations of 10--1,000 mg/L were studied. Initial naturally occurring levels of organic acids in the crude oils were also determined. pH had by far the largest effect on the partition coefficient for all three organic acids for both types oil. At conditions normally seen in an oil reservoir (pH 5--7), the great percentage (85+%) of these acids were dissolved in the aqueous phase. The log of the partition coefficient K increased approximately linearly with the number of carbon atoms in the acid. It was seen that organic acids are readily available carbon sources for sulfate-reducing bacteria (SRB) at normal reservoir conditions, and that crude oil may provide a source of organic acids in a low-pH, water-flooded reservoir.

  2. Storage Resource Unit (SRU) Formula Coefficients

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formula Coefficients Storage Resource Unit (SRU) Formula Coefficients The coefficients in the Storage Resource Unit (SRU) formula were arrived at from the following considerations:...

  3. α -cluster asymptotic normalization coefficients for nuclear...

    Office of Scientific and Technical Information (OSTI)

    -cluster asymptotic normalization coefficients for nuclear astrophysics Citation Details In-Document Search Title: -cluster asymptotic normalization coefficients for nuclear ...

  4. Fuel Temperature Coefficient of Reactivity

    SciTech Connect (OSTI)

    Loewe, W.E.

    2001-07-31

    A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

  5. Transport coefficients of gluonic fluid

    SciTech Connect (OSTI)

    Das, Santosh K.; Alam, Jan-e

    2011-06-01

    The shear ({eta}) and bulk ({zeta}) viscous coefficients have been evaluated for a gluonic fluid. The elastic, gg{yields}gg and the inelastic, number nonconserving, gg{yields}ggg processes have been considered as the dominant perturbative processes in evaluating the viscous coefficients to entropy density (s) ratios. Recently the processes: gg{yields}ggg has been revisited and a correction to the widely used Gunion-Bertsch (GB) formula has been obtained. The {eta} and {zeta} have been evaluated for gluonic fluid with the formula recently derived. At large {alpha}{sub s} the value of {eta}/s approaches its lower bound, {approx}1/4{pi}.

  6. Carbon investment funds

    SciTech Connect (OSTI)

    2007-01-15

    The report is a study of the development of funds to invest in the purchase of carbon credits. It takes a look at the growing market for carbon credits, the rise of carbon investment funds, and the current state of carbon investing. Topics covered in the report include: Overview of climate change, greenhouse gases, and the Kyoto Protocols. Analysis of the alternatives for reducing carbon emissions including nitrous oxide reduction, coal mine methane capture and carbon capture and storage; Discussion of the different types of carbon credits; Discussion of the basics of carbon trading; Evaluation of the current status of carbon investing; and Profiles of 37 major carbon investment funds worldwide.

  7. Conductivities and Seebeck Coefficients of Boron Carbides:'...

    Office of Scientific and Technical Information (OSTI)

    Coefficients of Boron Carbides: ''Softening-Bipolaron'' Hopping Citation Details In-Document Search Title: Conductivities and Seebeck Coefficients of Boron Carbides: ...

  8. Portable vapor diffusion coefficient meter

    DOE Patents [OSTI]

    Ho, Clifford K.

    2007-06-12

    An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.

  9. Three Human Cell Types Respond to Multi-Walled Carbon Nanotubes and Titanium Dioxide Nanobelts with Cell-Specific Transcriptomic and Proteomic Expression Patterns.

    SciTech Connect (OSTI)

    Tilton, Susan C.; Karin, Norman J.; Tolic, Ana; Xie, Yumei; Lai, Xianyin; Hamilton, Raymond F.; Waters, Katrina M.; Holian, Andrij; Witzmann, Frank A.; Orr, Galya

    2014-08-01

    The growing use of engineered nanoparticles (NPs) in commercial and medical applications raises the urgent need for tools that can predict NP toxicity. Global transcriptome and proteome analyses were conducted on three human cell types, exposed to two high aspect ratio NP types, to identify patterns of expression that might indicate high versus low NP toxicity. Three cell types representing the most common routes of human exposure to NPs, including macrophage-like (THP-1), small airway epithelial and intestinal (Caco-2/HT29-MTX) cells, were exposed to TiO2 nanobelts (TiO2-NB; high toxicity) and multi-walled carbon nanotubes (MWCNT; low toxicity) at low (10 g/mL) and high (100 g/mL) concentrations for 1 and 24 h. Unique patterns of gene and protein expressions were identified for each cell type, with no differentially expressed (p < 0.05, 1.5-fold change) genes or proteins overlapping across all three cell types. While unique to each cell type, the early response was primarily independent of NP type, showing similar expression patterns in response to both TiO2-NB and MWCNT. The early response might, therefore, indicate a general response to insult. In contrast, the 24 h response was unique to each NP type. The most significantly (p < 0.05) enriched biological processes in THP-1 cells indicated TiO2-NB regulation of pathways associated with inflammation, apoptosis, cell cycle arrest, DNA replication stress and genomic instability, while MWCNT-regulated pathways indicated increased cell proliferation, DNA repair and anti-apoptosis. These two distinct sets of biological pathways might, therefore, underlie cellular responses to high and low NP toxicity, respectively.

  10. Hydrothermal synthesis of nanocubes of sillenite type compounds for photovoltaic applications and solar energy conversion of carbon dioxide to fuels

    DOE Patents [OSTI]

    Subramanian, Vaidyanathan; Murugesan, Sankaran

    2014-04-29

    The present invention relates to formation of nanocubes of sillenite type compounds, such as bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, via a hydrothermal synthesis process, with the resulting compound(s) having multifunctional properties such as being useful in solar energy conversion, environmental remediation, and/or energy storage, for example. In one embodiment, a hydrothermal method is disclosed that transforms nanoparticles of TiO.sub.2 to bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, optionally loaded with palladium nanoparticles. The method includes reacting titanium dioxide nanotubes with a bismuth salt in an acidic bath at a temperature sufficient and for a time sufficient to form bismuth titanate crystals, which are subsequently annealed to form bismuth titanate nanocubes. After annealing, the bismuth titanate nanocubes may be optionally loaded with nano-sized metal particles, e.g., nanosized palladium particles.

  11. Characterization of solid state nuclear track detectors of the polyallyl-diglycol-carbonate (CR-39/PM-355) type for light charged particle spectroscopy

    SciTech Connect (OSTI)

    Malinowska, A. Jask?a, M.; Korman, A.; Kuk, M.; Szyd?owski, A.

    2014-12-15

    This paper presents a method which uses the characteristics of the etch pits induced in a polyallyl-diglycol-carbonate (PADC) detector of the CR-39/PM-355 type to estimate particle energy. This method is based on the data provided by a semiautomatic system that selects tracks according to two parameters, crater diameters, and mean gray level values. In this paper we used the results of the calibration measurements that were obtained in our laboratory in the period 20002014. Combining the information on the two parameters it is possible to determine unambiguously the incident projectile energy values. The paper presents the results of an attempt to estimate the energy resolution of the method when analyzing the tracks produced in the CR-39/PM-355 detector by energetic ions such as alpha particles, protons, and deuterons. We discuss the energy resolution of the measurement of light charged particle energy which is based on the parameters (crater diameter and mean gray level value) of tracks induced in solid state nuclear track detectors of the PADC type.

  12. Coupling coefficients for tensor product representations of quantum SU(2)

    SciTech Connect (OSTI)

    Groenevelt, Wolter

    2014-10-15

    We study tensor products of infinite dimensional irreducible {sup *}-representations (not corepresentations) of the SU(2) quantum group. We obtain (generalized) eigenvectors of certain self-adjoint elements using spectral analysis of Jacobi operators associated to well-known q-hypergeometric orthogonal polynomials. We also compute coupling coefficients between different eigenvectors corresponding to the same eigenvalue. Since the continuous spectrum has multiplicity two, the corresponding coupling coefficients can be considered as 2 2-matrix-valued orthogonal functions. We compute explicitly the matrix elements of these functions. The coupling coefficients can be considered as q-analogs of Bessel functions. As a results we obtain several q-integral identities involving q-hypergeometric orthogonal polynomials and q-Bessel-type functions.

  13. Code System to Calculate Correlation & Regression Coefficients.

    Energy Science and Technology Software Center (OSTI)

    1999-11-23

    Version 00 PCC/SRC is designed for use in conjunction with sensitivity analyses of complex computer models. PCC/SRC calculates the partial correlation coefficients (PCC) and the standardized regression coefficients (SRC) from the multivariate input to, and output from, a computer model.

  14. Diffusion and transport coefficients in synthetic opals

    SciTech Connect (OSTI)

    Sofo, J. O.; Mahan, G. D.; Department of Physics and Astronomy, The University of Tennessee, Knoxville, Tennessee 37996-1200

    2000-07-15

    Opals are structures composed of close-packed spheres in the size range of nano to micrometers. They are sintered to create small necks at the points of contact. We have solved the diffusion problem in such structures. The relation between the diffusion coefficient and the thermal and electrical conductivity is used to estimate the transport coefficients of opal structures as a function of the neck size and the mean free path of the carriers. The theory presented is also applicable to the diffusion problem in other periodic structures. (c) 2000 The American Physical Society.

  15. Shear viscosity coefficient of liquid lanthanides

    SciTech Connect (OSTI)

    Patel, H. P. Thakor, P. B. Prajapati, A. V.; Sonvane, Y. A.

    2015-05-15

    Present paper deals with the computation of shear viscosity coefficient (η) of liquid lanthanides. The effective pair potential v(r) is calculated through our newly constructed model potential. The Pair distribution function g(r) is calculated from PYHS reference system. To see the influence of local field correction function, Hartree (H), Tailor (T) and Sarkar et al (S) local field correction function are used. Present results are compared with available experimental as well as theoretical data. Lastly, we found that our newly constructed model potential successfully explains the shear viscosity coefficient (η) of liquid lanthanides.

  16. Measurement of the iodine partition coefficient

    SciTech Connect (OSTI)

    Furrer, M.; Cripps, R.C.; Gubler, R.

    1985-08-01

    The hydrolysis of iodine is complicated because it involves a number of species that differ considerably in their individual volatilities. Large uncertainties exist in the thermodynamic data of some of the iodine species, especially at temperatures above 25C. Because of this, an experiment was undertaken to measure the partition coefficient under varying physical and chemical conditions. Measurements of P were made for a temperature range of 21 to 113C under well-defined conditions (liquid molar concentration, pH, and redox potential) for inorganic iodine. The experimental results are interpreted with the aid of an analytical model and published thermodynamic data. A good agreement between calculated and measured values was found. The experimental setup allows the determination of very high partition coefficients up to a value of 2.0 X 10W. This is demonstrated by adding cesium-iodide to the fuel pool water of a boiling water reactor.

  17. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, Mohammad; Yuh, Chao-Yi

    1996-01-01

    A carbonate fuel cell matrix comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles.

  18. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, M.; Yuh, C.Y.

    1996-12-03

    A carbonate fuel cell matrix is described comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles. 8 figs.

  19. Coefficients of thermal expansiion of common encapsulants

    SciTech Connect (OSTI)

    Adolf, D.B.

    1988-07-01

    The coefficient of thermal expansion (CTE) of common electronic encapsulating polymers were measured over the temperature range of /minus/ 50/degree/C to approximately 120/degree/C. CTE's are presented for these systems as continuous functions of temperature in contrast to previous measurements. Comparison between the historical '' property chart'' CTE's and those obtained in this study are made when possible. The procedures used in this study are presented in detail so that, unlike the property chart, users will fully understand the accuracy and limitations of these values. 27 figs., 5 tabs.

  20. Bounds on Transport Coefficients of Porous Media

    SciTech Connect (OSTI)

    Berryman, J G

    2005-03-21

    An analytical formulation of conductivity bounds by Bergman and Milton is used in a different way to obtain rigorous bounds on the real transport coefficients (electrical conductivity, thermal conductivity, and/or fluid permeability) of a fluid-saturated porous medium. These bounds do not depend explicitly on the porosity, but rather on two formation factors--one associated with the pore space and the other with the solid frame. Hashin-Shtrikman bounds for transport in random polycrystals of porous-material laminates will also be discussed.

  1. Mass transfer coefficients developed from the air gasification of wood pellets

    SciTech Connect (OSTI)

    Botts, J.W.

    1998-07-01

    A convertible updraft/downdraft, fixed-bed gasifier was used in the gasification of 3/8-inch diameter wood pellets. The test data was used to develop mass transfer coefficients and describe the gasification process for each gasifier configuration. The results show that the production of the principal combustion gases, i.e., hydrogen (H{sub c}), carbon monozide (CO), and methane (CH{sub 4}), varies directly as to their mass transfer coefficient: H{sub 2}, CO, and CH{sub 4} = k h{sub DA}. Factoring the Reynolds (Re{sub d}) and Schmidt (Sc) numbers with the influence of the noncombustible gases, i.e., nitrogen (N{sub 2}), oxygen (O{sub 2}), and carbon dioxide (CO{sub 2}), is used to define the mass transfer coefficients. The general form describing this joint variation is: H{sub 2}, CO, and CH{sub 4} = kx (the effect of the noncombustible gases) x Re x Sc where Re = Reynolds number and Sc = Schmidt number. The developments of these mass transfer coefficients are shown for updraft and downdraft gasification.

  2. HTO washout model: on the relationship between exchange rate and washout coefficient

    SciTech Connect (OSTI)

    Golubev, A.; Balashov, Y.; Mavrin, S.; Golubeva, V.; Galeriu, D.

    2015-03-15

    Washout coefficient Λ is widely used as a parameter in washout models. These models describes overall HTO washout with rain by a first-order kinetic equation, while washout coefficient Λ depends on the type of rain event and rain intensity and empirical parameters a, b. The washout coefficient is a macroscopic parameter and we have considered in this paper its relationship with a microscopic rate K of HTO isotopic exchange in atmospheric humidity and drops of rainwater. We have shown that the empirical parameters a, b can be represented through the rain event characteristics using the relationships of molecular impact rate, rain intensity and specific rain water content while washout coefficient Λ can be represented through the exchange rate K, rain intensity, raindrop diameter and terminal raindrop velocity.

  3. Fuel temperature reactivity coefficient calculation by Monte Carlo perturbation techniques

    SciTech Connect (OSTI)

    Shim, H. J.; Kim, C. H.

    2013-07-01

    We present an efficient method to estimate the fuel temperature reactivity coefficient (FTC) by the Monte Carlo adjoint-weighted correlated sampling method. In this method, a fuel temperature change is regarded as variations of the microscopic cross sections and the temperature in the free gas model which is adopted to correct the asymptotic double differential scattering kernel. The effectiveness of the new method is examined through the continuous energy MC neutronics calculations for PWR pin cell problems. The isotope-wise and reaction-type-wise contributions to the FTCs are investigated for two free gas models - the constant scattering cross section model and the exact model. It is shown that the proposed method can efficiently predict the reactivity change due to the fuel temperature variation. (authors)

  4. Stirling cycle simulation without differential coefficients

    SciTech Connect (OSTI)

    Organ, A.J.

    1995-12-31

    With a simple transformation, the gas processes in the Stirling machine are described for all time and location in an algebraic equation free of differential coefficients of the unknowns. Local instantaneous heat transfer and friction are represented in function of local instantaneous Reynolds number, N{sub re}. The method avoids problems of numerical discretization, stability, convergence, artificial dispersion and diffusion. The paper presents the algebra of the transformation. Specimen solutions cover the temperature field of the gas circuit (exchangers and regenerator) over a representative cycle. When programmed for workstation the core code occupies some 2 dozen lines, and processing calls for seconds of CPU time. Availability of the solution means that intimate details of the gas processes are susceptible to examination using the most basic of computing facilities.

  5. Low-Carbon Energy: A Roadmap | Open Energy Information

    Open Energy Info (EERE)

    Resource Type: Publications Website: www.worldwatch.orgnode7069summary Cost: Free, Paid Low-Carbon Energy: A Roadmap Screenshot References: Low-Carbon Energy: A...

  6. Fact #562: March 16, 2009 Carbon Reduction of Plug-in Hybrid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Reduction Shares by Technology Type (Percent carbon reduction from internal combustion engines) Technology Type Cars Light Trucks All-Coal Elecricity Generation Typical Grid ...

  7. Carbon Smackdown: Carbon Capture

    SciTech Connect (OSTI)

    Jeffrey Long

    2010-07-12

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  8. Carbon Smackdown: Carbon Capture

    ScienceCinema (OSTI)

    Jeffrey Long

    2010-09-01

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  9. Determining window solar heat gain coefficient

    SciTech Connect (OSTI)

    Harrison, S.J.; Wonderen, S.J. van . Solar Calorimetry Lab.)

    1994-08-01

    The solar heat gain characteristics of fenestration systems impact daytime building energy performance, occupant comfort and utility load demands. A measure of the fraction of available solar energy entering a building interior per unit window area is defined as the solar heat gain coefficient (SHGC). Together with a window's thermal transmittance (U-value), the SHGC is used to compare fenestration products, and it allows for the calculation of energy rating number and annual energy performance. The need to measure and compared advances in window technology has led to the development of experimental and analytical methods for the determination of SHGC performance. Several test facilities currently or previously capable of performing SHGC measurements exist worldwide. Results experimentally determined using these facilities have provided design data for handbook tables, and have been instrumental in the development and validation of predictive analytical methods and computer simulation tools. However, these facilities have operated without a standard test procedure for SHGC performance. Consequently, recent efforts have been focused on developing consensus test procedures for the evaluation of window energy performance.

  10. Carbon Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon capture involves the separation of carbon dioxide (CO2) from coal-based power plant ... are not ready for implementation on coal-based power plants because they have not ...

  11. Scanning measurement of Seebeck coefficient of a heated sample

    DOE Patents [OSTI]

    Snyder, G. Jeffrey; Iwanaga, Shiho

    2016-04-19

    A novel scanning Seebeck coefficient measurement technique is disclosed utilizing a cold scanning thermocouple probe tip on heated bulk and thin film samples. The system measures variations in the Seebeck coefficient within the samples. The apparatus may be used for two dimensional mapping of the Seebeck coefficient on the bulk and thin film samples. This technique can be utilized for detection of defective regions, as well as phase separations in the sub-mm range of various thermoelectric materials.

  12. Carbon Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Fact Sheet Research Team Members Key Contacts Carbon Storage Carbon capture and storage (CCS) is a key component of the U.S. carbon management portfolio. Numerous studies have shown that CCS can account for up to 55 percent of the emissions reductions needed to stabilize and ultimately reduce atmospheric concentrations of CO2. NETL's Carbon Storage Program is readying CCS technologies for widespread commercial deployment by 2020. The program's goals are: By 2015, develop technologies

  13. Scale dependence of sorption coefficients for contaminant transport...

    Office of Scientific and Technical Information (OSTI)

    fractured rock Citation Details In-Document Search Title: Scale dependence of sorption coefficients for contaminant transport in saturated fractured rock You are ...

  14. Scale dependence of sorption coefficients for contaminant transport...

    Office of Scientific and Technical Information (OSTI)

    fractured rock Citation Details In-Document Search Title: Scale dependence of sorption coefficients for contaminant transport in saturated fractured rock No abstract prepared. ...

  15. Temperature coefficients for PV modules and arrays: Measurement...

    Office of Scientific and Technical Information (OSTI)

    The term temperature coefficient has been applied to several different photovoltaic ... Resource Relation: Conference: 26. IEEE photovoltaic specialists conference, Anaheim, CA ...

  16. TEMPERATURE COEFFICIENTS FOR PV MODULES AND ARRAYS: MEASUREMENT...

    Office of Scientific and Technical Information (OSTI)

    ASTM also specifies that temperature coefficients are determined using a standard solar ... fixture, illuminating the cell with a solar simulator, measuring the cell's ...

  17. Diffusion coefficient of three-dimensional Yukawa liquids

    SciTech Connect (OSTI)

    Dzhumagulova, K. N.; Ramazanov, T. S.; Masheeva, R. U.

    2013-11-15

    The purpose of this work is an investigation of the diffusion coefficient of the dust component in complex plasma. The computer simulation of the Yukawa liquids was made on the basis of the Langevin equation, which takes into account the influence of buffer plasma on the dust particles dynamics. The GreenKubo relation was used to calculate the diffusion coefficient. Calculations of the diffusion coefficient for a wide range of the system parameters were performed. Using obtained numerical data, we constructed the interpolation formula for the diffusion coefficient. We also show that the interpolation formula correctly describes experimental data obtained under microgravity conditions.

  18. Isopiestic Determination of the Osmotic and Activity Coefficients...

    Office of Scientific and Technical Information (OSTI)

    model with an ionic-strength dependent third virial coefficient, as well as those of ... Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 58 ...

  19. Predicting Local Transport Coefficients at Solid-Gas Interfaces...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the predictability of the coefficient quantifying this local process, the surface permeability , by means of a two-scale simulation approach. Methane tracer-release from the...

  20. State of the Forest Carbon Markets 2009 | Open Energy Information

    Open Energy Info (EERE)

    analysis Resource Type: Publications Website: moderncms.ecosystemmarketplace.comrepositorymoderncmsdocumentsSFCM State of the Forest Carbon Markets 2009 Screenshot...

  1. CarbonSolve | Open Energy Information

    Open Energy Info (EERE)

    Type: Softwaremodeling tools User Interface: Website Website: www.carbonsolve.com Web Application Link: www.carbonsolve.com Cost: Paid CarbonSolve Screenshot References:...

  2. Forest Carbon Portal | Open Energy Information

    Open Energy Info (EERE)

    Forest Trends Sector: Land Focus Area: Forestry Topics: GHG inventory Resource Type: Lessons learnedbest practices Website: www.forestcarbonportal.com Forest Carbon Portal...

  3. Micro- and macroscale coefficients of friction of cementitious materials

    SciTech Connect (OSTI)

    Lomboy, Gilson; Sundararajan, Sriram; Wang, Kejin

    2013-12-15

    Millions of metric tons of cementitious materials are produced, transported and used in construction each year. The ease or difficulty of handling cementitious materials is greatly influenced by the material friction properties. In the present study, the coefficients of friction of cementitious materials were measured at the microscale and macroscale. The materials tested were commercially-available Portland cement, Class C fly ash, and ground granulated blast furnace slag. At the microscale, the coefficient of friction was determined from the interaction forces between cementitious particles using an Atomic Force Microscope. At the macroscale, the coefficient of friction was determined from stresses on bulk cementitious materials under direct shear. The study indicated that the microscale coefficient of friction ranged from 0.020 to 0.059, and the macroscale coefficient of friction ranged from 0.56 to 0.75. The fly ash studied had the highest microscale coefficient of friction and the lowest macroscale coefficient of friction. -- Highlights: •Microscale (interparticle) coefficient of friction (COF) was determined with AFM. •Macroscale (bulk) COF was measured under direct shear. •Fly ash had the highest microscale COF and the lowest macroscale COF. •Portland cement against GGBFS had the lowest microscale COF. •Portland cement against Portland cement had the highest macroscale COF.

  4. Gas Chromatography Data Classification Based on Complex Coefficients of an Autoregressive Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Weixiang; Morgan, Joshua T.; Davis, Cristina E.

    2008-01-01

    This paper introduces autoregressive (AR) modeling as a novel method to classify outputs from gas chromatography (GC). The inverse Fourier transformation was applied to the original sensor data, and then an AR model was applied to transform data to generate AR model complex coefficients. This series of coefficients effectively contains a compressed version of all of the information in the original GC signal output. We applied this method to chromatograms resulting from proliferating bacteria species grown in culture. Three types of neural networks were used to classify the AR coefficients: backward propagating neural network (BPNN), radial basis function-principal component analysismore » (RBF-PCA) approach, and radial basis function-partial least squares regression (RBF-PLSR) approach. This exploratory study demonstrates the feasibility of using complex root coefficient patterns to distinguish various classes of experimental data, such as those from the different bacteria species. This cognition approach also proved to be robust and potentially useful for freeing us from time alignment of GC signals.« less

  5. Seal assembly for materials with different coefficients of thermal expansion

    DOE Patents [OSTI]

    Minford, Eric

    2009-09-01

    Seal assembly comprising (a) two or more seal elements, each element having having a coefficient of thermal expansion; and (b) a clamping element having a first segment, a second segment, and a connecting segment between and attached to the first and second segments, wherein the two or more seal elements are disposed between the first and second segments of the clamping element. The connecting segment has a central portion extending between the first segment of the clamping element and the second segment of the clamping element, and the connecting segment is made of a material having a coefficient of thermal expansion. The coefficient of thermal expansion of the material of the connecting segment is intermediate the largest and smallest of the coefficients of thermal expansion of the materials of the two or more seal elements.

  6. ORISE: Dose Coefficients for Intakes of Radionuclides via Contaminated

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wounds Dose Coefficients for Intakes of Radionuclides via Contaminated Wounds Dose coefficients for 38 radionuclides based on NCRP Wound Model and ICRP biokinetic models This report is intended to assist health physics and medical staff in more rapidly assessing the potential dosimetric consequences of a contaminated wound. The National Council on Radiation Protection and Measurements Wound Model describing the retention of selected radionuclides at the site of a contaminated wound and their

  7. Higher order matrix differential equations with singular coefficient matrices

    SciTech Connect (OSTI)

    Fragkoulis, V. C.; Kougioumtzoglou, I. A.; Pantelous, A. A.; Pirrotta, A.

    2015-03-10

    In this article, the class of higher order linear matrix differential equations with constant coefficient matrices and stochastic process terms is studied. The coefficient of the highest order is considered to be singular; thus, rendering the response determination of such systems in a straightforward manner a difficult task. In this regard, the notion of the generalized inverse of a singular matrix is used for determining response statistics. Further, an application relevant to engineering dynamics problems is included.

  8. Carbon Fiber

    SciTech Connect (OSTI)

    McGetrick, Lee

    2014-04-17

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  9. Carbon Fiber

    ScienceCinema (OSTI)

    McGetrick, Lee

    2014-07-23

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  10. Carbon Sequestration

    SciTech Connect (OSTI)

    2013-05-06

    Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

  11. Carbon Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capture Fact Sheet Key Contacts Carbon Capture Research & Development Carbon capture and storage from fossil-based power generation is a critical component of realistic strategies for arresting the rise in atmospheric CO2 concentrations, but capturing substantial amounts of CO2 using current technology would result in a prohibitive rise in the cost of producing energy. The National Energy Technology Laboratory Office of Research and Development (NETL-ORD), in collaboration with researchers

  12. Carbon Constraints and the Electric Power Industry

    SciTech Connect (OSTI)

    2007-11-15

    The report is designed to provide a thorough understanding of the type of carbon constraints that are likely to be imposed, when they are likely to take effect, and how they will impact the electric power industry. The main objective of the report is to provide industry participants with the knowledge they need to plan for and react to a future in which carbon emissions are restricted. The main goal of the report is to ensure an understanding of the likely restrictions that will be placed on carbon emissions, the methods available for reducing their carbon emissions, and the impact that carbon reductions will have on the electric power industry. A secondary goal of the report is to provide information on key carbon programs and market participants to enable companies to begin participating in the international carbon marketplace. Topics covered in the report include: overview of what climate change and the Kyoto Protocol are; analysis of the impacts of climate change on the U.S. and domestic efforts to mandate carbon reductions; description of carbon reduction mechanisms and the types of carbon credits that can be created; evaluation of the benefits of carbon trading and the rules for participation under Kyoto; Description of the methods for reducing carbon emissions available to the U.S. electric power industry; analysis of the impact of carbon restrictions on the U.S. electric power industry in terms of both prices and revenues; evaluation of the impact of carbon restrictions on renewable energy; overview of the current state of the global carbon market including descriptions of the three major marketplaces; descriptions of the industry and government programs already underway to reduce carbon emissions in the U.S. electric power industry; and, profiles of the major international carbon exchanges and brokers.

  13. Identification of Bayesian posteriors for coefficients of chaos expansions

    SciTech Connect (OSTI)

    Arnst, M. Ghanem, R.; Soize, C.

    2010-05-01

    This article is concerned with the identification of probabilistic characterizations of random variables and fields from experimental data. The data used for the identification consist of measurements of several realizations of the uncertain quantities that must be characterized. The random variables and fields are approximated by a polynomial chaos expansion, and the coefficients of this expansion are viewed as unknown parameters to be identified. It is shown how the Bayesian paradigm can be applied to formulate and solve the inverse problem. The estimated polynomial chaos coefficients are hereby themselves characterized as random variables whose probability density function is the Bayesian posterior. This allows to quantify the impact of missing experimental information on the accuracy of the identified coefficients, as well as on subsequent predictions. An illustration in stochastic aeroelastic stability analysis is provided to demonstrate the proposed methodology.

  14. Control of Surface Functional Groups on Pertechntate Sorption on Activated Carbon

    SciTech Connect (OSTI)

    Y. Wang; H. Gao; R. Yeredla; H. Xu; M. Abrecht; G.D. Stasio

    2006-07-05

    {sup 99}Tc is highly soluble and poorly adsorbed by natural materials under oxidizing conditions, thus being of particular concern for radioactive waste disposal. Activated carbon can potentially be used as an adsorbent for removing Tc from aqueous solutions. We have tested six commercial activated carbon materials for their capabilities for sorption of pertechnetate (TcO{sub 4}{sup -}). The tested materials can be grouped into two distinct types: Type I materials have high sorption capabilities with the distribution coefficients (K{sub d}) varying from 9.5 x 10{sup 5} to 3.2 x 10{sup 3} mL/g as the pH changes from 4.5 to 9.5, whereas type II materials have relatively low sorption capabilities with K{sub d} remaining more or less constant (1.1 x 10{sup 3} - 1.8 x 10{sup 3} mL/g) over a similar pH range. The difference in sorption behavior between the two types of materials is attributed to the distribution of surface functional groups. The predominant surface groups are identified to be carboxylic and phenolic groups. The carboxylic group can be further divided into three subgroups A, B, and C in the order of increasing acidity. The high sorption capabilities of type I materials are found to be caused by the presence of a large fraction of carboxylic subgroups A and B, while the low sorption capabilities of type II materials are due to the exclusive presence of phenolic and carboxylic subgroup C. Therefore, the performance of activated carbon for removing TcO{sub 4}{sup -} can be improved by enhancing the formation of carboxylic subgroups A and B during material processing.

  15. Lattice-structures and constructs with designed thermal expansion coefficients

    DOE Patents [OSTI]

    Spadaccini, Christopher; Hopkins, Jonathan

    2014-10-28

    A thermal expansion-managed lattice structure having a plurality of unit cells each having flexure bearing-mounted tabs supported on a base and actuated by thermal expansion of an actuator having a thermal expansion coefficient greater than the base and arranged so that the tab is inwardly displaced into a base cavity. The flexure bearing-mounted tabs are connected to other flexure-bearing-mounted tabs of adjacent unit cells so that the adjacent unit cells are spaced from each other to accommodate thermal expansion of individual unit cells while maintaining a desired bulk thermal expansion coefficient of the lattice structure as a whole.

  16. Effective atomic numbers and mass attenuation coefficients of some thermoluminescent dosimetric compounds for total photon interaction

    SciTech Connect (OSTI)

    Shivaramu; Amutha, R.; Ramprasath, V.

    1999-05-01

    Effective atomic numbers for total gamma-ray interaction with some selected thermoluminescent dosimetric compounds such as barium acetate, barium sulfate, calcium carbonate, calcium sulfate, calcium sulfate dihydrate, cadmium sulfate (anhydrous), cadmium sulfate, strontium sulfate, and lithium fluoride have been calculated in the 1-keV to 20-MeV energy region. Experimental mass attenuation coefficients and effective atomic numbers for these compounds at selected photon energies of 26.3, 33.2, 59.54, and 661.6 keV have been obtained from good geometry transmission measurements and compared with theoretical values. The effect of absorption edge on effective atomic numbers and its variation with energy, and nonvalidity of the Bragg`s mixture rule at incident photon energies closer to the absorption edges of constituent elements of compounds are discussed.

  17. SCALE Continuous-Energy Eigenvalue Sensitivity Coefficient Calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Perfetti, Christopher M.; Rearden, Bradley T.; Martin, William R.

    2016-02-25

    Sensitivity coefficients describe the fractional change in a system response that is induced by changes to system parameters and nuclear data. The Tools for Sensitivity and UNcertainty Analysis Methodology Implementation (TSUNAMI) code within the SCALE code system makes use of eigenvalue sensitivity coefficients for an extensive number of criticality safety applications, including quantifying the data-induced uncertainty in the eigenvalue of critical systems, assessing the neutronic similarity between different critical systems, and guiding nuclear data adjustment studies. The need to model geometrically complex systems with improved fidelity and the desire to extend TSUNAMI analysis to advanced applications has motivated the developmentmore » of a methodology for calculating sensitivity coefficients in continuous-energy (CE) Monte Carlo applications. The Contributon-Linked eigenvalue sensitivity/Uncertainty estimation via Tracklength importance CHaracterization (CLUTCH) and Iterated Fission Probability (IFP) eigenvalue sensitivity methods were recently implemented in the CE-KENO framework of the SCALE code system to enable TSUNAMI-3D to perform eigenvalue sensitivity calculations using continuous-energy Monte Carlo methods. This work provides a detailed description of the theory behind the CLUTCH method and describes in detail its implementation. This work explores the improvements in eigenvalue sensitivity coefficient accuracy that can be gained through the use of continuous-energy sensitivity methods and also compares several sensitivity methods in terms of computational efficiency and memory requirements.« less

  18. Carbon supercapacitors

    SciTech Connect (OSTI)

    Delnick, F.M.

    1993-11-01

    Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

  19. Carbon particles

    DOE Patents [OSTI]

    Hunt, Arlon J.

    1984-01-01

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  20. Carbon microtubes

    DOE Patents [OSTI]

    Peng, Huisheng (Shanghai, CN); Zhu, Yuntian Theodore (Cary, NC); Peterson, Dean E. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

    2011-06-14

    A carbon microtube comprising a hollow, substantially tubular structure having a porous wall, wherein the microtube has a diameter of from about 10 .mu.m to about 150 .mu.m, and a density of less than 20 mg/cm.sup.3. Also described is a carbon microtube, having a diameter of at least 10 .mu.m and comprising a hollow, substantially tubular structure having a porous wall, wherein the porous wall comprises a plurality of voids, said voids substantially parallel to the length of the microtube, and defined by an inner surface, an outer surface, and a shared surface separating two adjacent voids.

  1. Letter to the Editor: Appropriate selection of dose coefficients in radiological assessments: C-14 and Cl-36

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harrison, Dr John; Leggett, Richard Wayne

    2016-01-01

    This letter to the editor of Journal of Radiological Protection is in response to a letter to the editor from G. M. Smith and M. C. Thorne of Great Britain concerning the appropriate selection of dose coefficients for ingested carbon-14 and chlorine-36, two of the most important long-lived components of radioactive wastes. Smith and Thorne argue that current biokinetic models of the International Commission on Radiological Protection (ICRP) for carbon and chlorine are overly cautious models from the standpoint of radiation dose estimates for C-14 and Cl-36, and that more realistic models are needed for evaluation of the hazards ofmore » these radionuclides in nuclear wastes. We (Harrison and Leggett) point out that new biokinetic models for these and other elements (developed at ORNL) will soon appear in ICRP Publications. These new models generally are considerably more realistic than current ICRP models. Examples are given for C-14 inhaled as carbon dioxide or ingested in water as bicarbonate, carbonate, or carbon dioxide.« less

  2. Characterization of electrospun lignin based carbon fibers

    SciTech Connect (OSTI)

    Poursorkhabi, Vida; Mohanty, Amar; Misra, Manjusri

    2015-05-22

    The production of lignin fibers has been studied in order to replace the need for petroleum based precursors for carbon fiber production. In addition to its positive environmental effects, it also benefits the economics of the industries which cannot take advantage of carbon fiber properties because of their high price. A large amount of lignin is annually produced as the byproduct of paper and growing cellulosic ethanol industry. Therefore, finding high value applications for this low cost, highly available material is getting more attention. Lignin is a biopolymer making about 15 30 % of the plant cell walls and has a high carbon yield upon carbonization. However, its processing is challenging due to its low molecular weight and also variations based on its origin and the method of separation from cellulose. In this study, alkali solutions of organosolv lignin with less than 1 wt/v% of poly (ethylene oxide) and two types of lignin (hardwood and softwood) were electrospun followed by carbonization. Different heating programs for carbonization were tested. The carbonized fibers had a smooth surface with an average diameter of less than 5?m and the diameter could be controlled by the carbonization process and lignin type. Scanning electron microscopy (SEM) was used to study morphology of the fibers before and after carbonization. Thermal conductivity of a sample with amorphous carbon was 2.31?W/m.K. The electrospun lignin carbon fibers potentially have a large range of application such as in energy storage devices and water or gas purification systems.

  3. Carbon | Open Energy Information

    Open Energy Info (EERE)

    Carbon Jump to: navigation, search TODO: Add description Related Links List of Companies in Carbon Sector Retrieved from "http:en.openei.orgwindex.php?titleCarbon&oldid271960...

  4. Sign problem in Z-coefficient for particle emission angular distributi...

    Office of Scientific and Technical Information (OSTI)

    Sign problem in Z-coefficient for particle emission angular distributions Citation Details In-Document Search Title: Sign problem in Z-coefficient for particle emission angular ...

  5. Sign problem in Z-coefficient for particle emission angular distributi...

    Office of Scientific and Technical Information (OSTI)

    Sign problem in Z-coefficient for particle emission angular distributions Citation Details In-Document Search Title: Sign problem in Z-coefficient for particle emission angular...

  6. Backscattering and absorption coefficients for electrons: Solutions of invariant embedding transport equations using a method of convergence

    SciTech Connect (OSTI)

    Figueroa, C.; Brizuela, H.; Heluani, S. P.

    2014-05-21

    The backscattering coefficient is a magnitude whose measurement is fundamental for the characterization of materials with techniques that make use of particle beams and particularly when performing microanalysis. In this work, we report the results of an analytic method to calculate the backscattering and absorption coefficients of electrons in similar conditions to those of electron probe microanalysis. Starting on a five level states ladder model in 3D, we deduced a set of integro-differential coupled equations of the coefficients with a method know as invariant embedding. By means of a procedure proposed by authors, called method of convergence, two types of approximate solutions for the set of equations, namely complete and simple solutions, can be obtained. Although the simple solutions were initially proposed as auxiliary forms to solve higher rank equations, they turned out to be also useful for the estimation of the aforementioned coefficients. In previous reports, we have presented results obtained with the complete solutions. In this paper, we present results obtained with the simple solutions of the coefficients, which exhibit a good degree of fit with the experimental data. Both the model and the calculation method presented here can be generalized to other techniques that make use of different sorts of particle beams.

  7. Award Types

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Awards Team (505) 667-7824 Email Types of Awards The Awards Office, sponsored by the Technology Transfer Division and the Science and Technology Base Program Office, coordinates...

  8. Scale dependency of the effective matrix diffusion coefficient

    SciTech Connect (OSTI)

    Liu, H.H.; Bodvarsson, G.S.; Zhang, G.

    2003-05-30

    It has been recognized that matrix diffusion is an important process for retarding solute transport in fractured rock. Based on analyses of tracer transport data from a number of field tests, we demonstrate for the first time that the effective matrix-diffusion coefficient may be scale dependent and generally increases with test scale. A preliminary theoretical explanation of this scale dependency is also presented, based on the hypothesis that solute travel paths within a fracture network are fractals.

  9. Theoretical rate coefficients for allyl + HO2 and allyloxy decomposition

    SciTech Connect (OSTI)

    Goldsmith, C. F.; Klippenstein, S. J.; Green, W. H.

    2011-01-01

    The kinetics of the allyl + HO{sub 2} bimolecular reaction, the thermal decomposition of C{sub 3}H{sub 5}OOH, and the unimolecular reactions of C{sub 3}H{sub 5}O are studied theoretically. High-level ab initio calculations of the C{sub 3}H{sub 5}OOH and C{sub 3}H{sub 5}O potential energy surfaces are coupled with RRKM master equation methods to compute the temperature- and pressure-dependence of the rate coefficients. Variable reaction coordinate transition state theory is used to characterize the barrierless transition states for the allyl + HO{sub 2} and C{sub 3}H{sub 5}O + OH reactions. The predicted rate coefficients for allyl + HO{sub 2} ? C{sub 3}H{sub 5}OOH ? products are in good agreement with experimental values. The calculations for allyl + HO{sub 2} ? C{sub 3}H{sub 6} + O{sub 2} underpredict the observed rate. The new rate coefficients suggest that the reaction of allyl + HO{sub 2} will promote chain-branching significantly more than previous models suggest.

  10. Type A Accident Investigation Board Report of the July 28, 1998, Fatality and Multiple Injuries Resulting from Release of Carbon Dioxide at Building 648, Test Reactor Area, Idaho National Engineering and Environmental Laboratory

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report is an independent product of the Type A Accident Investigation Board appointed by Peter N. Brush, Acting Assistant Secretary for Environment, Safety and Health (EH-1).

  11. Modified carbon nanotubes and methods of forming carbon nanotubes

    DOE Patents [OSTI]

    Heintz, Amy M.; Risser, Steven; Elhard, Joel D.; Moore, Bryon P.; Liu, Tao; Vijayendran, Bhima R.

    2016-06-14

    In this invention, processes which can be used to achieve stable doped carbon nanotubes are disclosed. Preferred CNT structures and morphologies for achieving maximum doping effects are also described. Dopant formulations and methods for achieving doping of a broad distribution of tube types are also described.

  12. Statement by Energy Secretary Ernest Moniz on new EPA Carbon...

    Broader source: Energy.gov (indexed) [DOE]

    the range of generation types, promote advanced fossil energy technologies such as carbon capture, utilization, and storage (CCUS), and deploy more clean energy. DOE is also...

  13. Carbon p electron ferromagnetism in silicon carbide (Journal...

    Office of Scientific and Technical Information (OSTI)

    Carbon p electron ferromagnetism in silicon carbide Citation Details ... GrantContract Number: AC02-05CH11231 Type: Accepted Manuscript Journal Name: Scientific Reports ...

  14. International Low-Carbon Energy Technology Platform | Open Energy...

    Open Energy Info (EERE)

    Topics: Low emission development planning, Policiesdeployment programs Resource Type: Lessons learnedbest practices Website: www.iea.orgplatform.asp International Low-Carbon...

  15. Kinetic performance of CO2 absorption into a potassium carbonate...

    Office of Scientific and Technical Information (OSTI)

    Title: Kinetic performance of CO2 absorption into a potassium carbonate solution ... Type: Publisher's Accepted Manuscript Journal Name: Chemical Engineering Journal (Print) ...

  16. Single-ion adsorption and switching in carbon nanotubes (Journal...

    Office of Scientific and Technical Information (OSTI)

    in carbon nanotubes Citation Details In-Document ... Here we report the observation of single gaseous ion ... Type: Accepted Manuscript Journal Name: Nature ...

  17. New Species of Cyanobacteria Forms Intracellular Carbonates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    images at a spatial resolution better than 25 nm. The soft x-ray STXM enabled characterization of the type (i.e., coordination andor reduction-oxidation state) of carbon...

  18. Parameterization of the Extinction Coefficient in Ice and Mixed-Phase Arctic Clouds during the ISDAC Field Campaign

    SciTech Connect (OSTI)

    Korolev, A; Shashkov, A; Barker, H

    2012-03-06

    This report documents the history of attempts to directly measure cloud extinction, the current measurement device known as the Cloud Extinction Probe (CEP), specific problems with direct measurement of extinction coefficient, and the attempts made here to address these problems. Extinction coefficient is one of the fundamental microphysical parameters characterizing bulk properties of clouds. Knowledge of extinction coefficient is of crucial importance for radiative transfer calculations in weather prediction and climate models given that Earth's radiation budget (ERB) is modulated much by clouds. In order for a large-scale model to properly account for ERB and perturbations to it, it must ultimately be able to simulate cloud extinction coefficient well. In turn this requires adequate and simultaneous simulation of profiles of cloud water content and particle habit and size. Similarly, remote inference of cloud properties requires assumptions to be made about cloud phase and associated single-scattering properties, of which extinction coefficient is crucial. Hence, extinction coefficient plays an important role in both application and validation of methods for remote inference of cloud properties from data obtained from both satellite and surface sensors (e.g., Barker et al. 2008). While estimation of extinction coefficient within large-scale models is relatively straightforward for pure water droplets, thanks to Mie theory, mixed-phase and ice clouds still present problems. This is because of the myriad forms and sizes that crystals can achieve, each having their own unique extinction properties. For the foreseeable future, large-scale models will have to be content with diagnostic parametrization of crystal size and type. However, before they are able to provide satisfactory values needed for calculation of radiative transfer, they require the intermediate step of assigning single-scattering properties to particles. The most basic of these is extinction

  19. ARM: 10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  20. ARM: 1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  1. ARM: 10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  2. ARM: 10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  3. ARM: 2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  4. ARM: 1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  5. ARM: 10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Newsom, Rob; Goldsmith, John

    1998-03-01

    10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  6. ARM: 2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2004-10-01

    2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  7. ORISE: Dose Coefficients for Intakes of Radionuclides via Contaminated Wounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dose CoeffiCients for intakes of raDionuCliDes via ContaminateD WounDs R. E. Toohey*, L. Bertelli + , S. L. Sugarman*, A. L. Wiley* and D. M. Christensen* *Radiation Emergency Assistance Center/Training Site, Oak Ridge Institute for Science and Education, Oak Ridge, TN 37031-0117; + Radiation Protection Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545. Ver. 2, Aug 2014 The NCRP Wound Model describing the retention of selected radionuclides at the site of a contaminated

  8. Trigonometric Pade approximants for functions with regularly decreasing Fourier coefficients

    SciTech Connect (OSTI)

    Labych, Yuliya A; Starovoitov, Alexander P [Gomel State University, Gomel (Belarus)

    2009-08-31

    Sufficient conditions describing the regular decrease of the coefficients of a Fourier series f(x)=a{sub 0}/2 + {sigma} a{sub n} cos kx are found which ensure that the trigonometric Pade approximants {pi}{sup t}{sub n,m}(x;f) converge to the function f in the uniform norm at a rate which coincides asymptotically with the highest possible one. The results obtained are applied to problems dealing with finding sharp constants for rational approximations. Bibliography: 31 titles.

  9. Mixing coefficients for subchannel analyses with supercritical water

    SciTech Connect (OSTI)

    Vogt, Bastian; Laurien, Eckart; Class, Andreas G.; Schulenberg, Thomas

    2007-07-01

    This paper is related to pressure drop and mixing correlations which are used in subchannel codes. The commercial CFD code STAR-CD has been applied for central subchannels of a supercritical water reactor fuel assembly design. First, pressure drop coefficients for cross flow have been evaluated for this geometry using steady state calculations. Different from established correlations for cross flow in rod bundles, the effects of strong axial flow in the bundle have been taken into account for the presented geometry, flow conditions and fluid properties. In the second part of the paper the unsteady RANS CFD-method is applied and assessed with respect to the prediction of flow pulsation phenomena and turbulent mixing. The results are compared with experimental correlations for the turbulent mixing coefficient and the flow pulsation frequency. It is found that the applied unsteady RANS method is able to predict the flow pulsation frequency but over-predicts the turbulent mixing by a factor of around 3.5. (authors)

  10. Applications of the second virial coefficient: protein crystallization and solubility

    SciTech Connect (OSTI)

    Wilson, William W.; DeLucas, Lawrence J.

    2014-04-30

    This article highlights some of the ground-based studies emanating from NASAs Microgravity Protein Crystal Growth (PCG) program, and includes a more detailed discussion of the history and the progress made in one of the NASA-funded PCG investigations involving the use of measured second virial coefficients (B values) as a diagnostic indicator of solution conditions conducive to protein crystallization. This article begins by highlighting some of the ground-based studies emanating from NASAs Microgravity Protein Crystal Growth (PCG) program. This is followed by a more detailed discussion of the history of and the progress made in one of the NASA-funded PCG investigations involving the use of measured second virial coefficients (B values) as a diagnostic indicator of solution conditions conducive to protein crystallization. A second application of measured B values involves the determination of solution conditions that improve or maximize the solubility of aqueous and membrane proteins. These two important applications have led to several technological improvements that simplify the experimental expertise required, enable the measurement of membrane proteins and improve the diagnostic capability and measurement throughput.

  11. New measurement of the α asymptotic normalization coefficient...

    Office of Scientific and Technical Information (OSTI)

    that dominates the C 13 ( , n ) O 16 reaction rate at temperatures relevant for the s ... Type: Publisher's Accepted Manuscript Journal Name: Physical Review C Additional Journal ...

  12. THE EFFECT OF UNCERTAINTY IN MODELING COEFFICIENTS USED TO PREDICT...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    likely to vary for systems in different climates, depending on the distribution of temperature and irradiance, as well as for different technology types. As previously reported,...

  13. An unusual carbon-carbon bond cleavage reaction during phosphinothrici...

    Office of Scientific and Technical Information (OSTI)

    An unusual carbon-carbon bond cleavage reaction during phosphinothricin biosynthesis Citation Details In-Document Search Title: An unusual carbon-carbon bond cleavage reaction ...

  14. US Department of Transportation (DOT) Spec 7A Type A evaluation document: Spec 17C 55-gal steel drum with RWMC/SWEPP drum venting system carbon filter assembly

    SciTech Connect (OSTI)

    Edling, D.A.

    1986-09-15

    As part of MRC-Mound's responsibility to coordinate DOE Spec 7A Type A Packaging testing, evaluation, and utilization, this document evaluates per 49CFR 173.415(a) the SWEPP packaging system: DOT Spec 17C steel drums - 30, 55 and 83-gal; High Density Polyethylene (HDPE) liners; and SWEPP DVS Filter Assemblies (two configurations) as a US DOT Spec 7A Type A packaging. A variety of Type A performance testing was done on: DOT Spec 17C 55-gal steel drums; DOT Spec 17C 55-gal steel drums with HDPE liners; and DOT Spec 17C 55-gal steel drums with ''Nucfil'' filters as part of MRC-Mound's Type A Packaging Evaluation Program funded by DOE/HQ, DP-4, Security Evaluations. The subject SWEPP packaging incorporates modifications to the ''Nucfil'' filter and installation assembly previously tested in conjunction with the Spec 17C 55-gal drums. Thus, additional testing was required on the new filter installation in order to evaluate the entire packaging system. This document presents the test data to demonstrate the SWEPP packaging system's performance against the DOT 7A Type A requirements.

  15. Carbon Capture | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Capture Carbon Capture This GIF shows how CO2 emissions vary across the United States. Each bar represents a 50x50 kilometer grid. Bar height is proportional to total CO2 emissions and bar color represents the type of CO2 emissions. Red bars represent proportionately more CO2 emissions from electricity generation (coal, gas and oil). Green bars represent CO2 emissions by other sources (such as ethanol production, iron-steel production and cement manufacture). Yellow/orange bars signify a

  16. Carbon Capital | Open Energy Information

    Open Energy Info (EERE)

    Capital Jump to: navigation, search Name: Carbon Capital Place: United Kingdom Sector: Carbon Product: Manages a carbon fund specialised in forestry projects References: Carbon...

  17. Wedge sampling for computing clustering coefficients and triangle counts on large graphs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Seshadhri, C.; Pinar, Ali; Kolda, Tamara G.

    2014-05-08

    Graphs are used to model interactions in a variety of contexts, and there is a growing need to quickly assess the structure of such graphs. Some of the most useful graph metrics are based on triangles, such as those measuring social cohesion. Despite the importance of these triadic measures, algorithms to compute them can be extremely expensive. We discuss the method of wedge sampling. This versatile technique allows for the fast and accurate approximation of various types of clustering coefficients and triangle counts. Furthermore, these techniques are extensible to counting directed triangles in digraphs. Our methods come with provable andmore » practical time-approximation tradeoffs for all computations. We provide extensive results that show our methods are orders of magnitude faster than the state of the art, while providing nearly the accuracy of full enumeration.« less

  18. Calculation of combined diffusion coefficients in SF{sub 6}-Cu mixtures

    SciTech Connect (OSTI)

    Zhong, Linlin; Wang, Xiaohua Rong, Mingzhe Wu, Yi; Murphy, Anthony B.

    2014-10-15

    Diffusion coefficients play an important role in the description of the transport of metal vapours in gas mixtures. This paper is devoted to the calculation of four combined diffusion coefficients, namely, the combined ordinary diffusion coefficient, combined electric field diffusion coefficient, combined temperature diffusion coefficient, and combined pressure diffusion coefficient in SF{sub 6}-Cu mixtures at temperatures up to 30 000 K. These four coefficients describe diffusion due to composition gradients, applied electric fields, temperature gradients, and pressure gradients, respectively. The influence of copper fluoride and sulfide species on the diffusion coefficients is shown to be negligible. The effect of copper proportion and gas pressures on these diffusion coefficients is investigated. It is shown that increasing the proportion of copper generally increases the magnitude of the four diffusion coefficients, except for copper mole fractions of 90% or more. It is further found that increasing the pressure reduces the magnitude of the coefficients, except for the combined temperature diffusion coefficient, and shifts the maximum of all four coefficients towards higher temperatures. The results presented in this paper can be applied to the simulation of high-voltage circuit breaker arcs.

  19. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B.

    1993-01-01

    A process for making 2D and 3D carbon-carbon composites having a combined high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizible woven cloth are infiltrated with carbon material to form green composites. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnant step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3100.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. C. to 1300.degree. C. at a reduced. pressure.

  20. Type: Renewal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 INCITE Awards Type: Renewal Title: -Ab Initio Dynamical Simulations for the Prediction of Bulk Properties‖ Principal Investigator: Theresa Windus, Iowa State University Co-Investigators: Brett Bode, Iowa State University Graham Fletcher, Argonne National Laboratory Mark Gordon, Iowa State University Monica Lamm, Iowa State University Michael Schmidt, Iowa State University Scientific Discipline: Chemistry: Physical INCITE Allocation: 10,000,000 processor hours Site: Argonne National

  1. Facility Type!

    Office of Legacy Management (LM)

    ITY: --&L~ ----------- srct-r~ -----------~------~------- if yee, date contacted ------------- cl Facility Type! i I 0 Theoretical Studies Cl Sample 84 Analysis ] Production 1 Diepasal/Storage 'YPE OF CONTRACT .--------------- 1 Prime J Subcontract&- 1 Purchase Order rl i '1 ! Other information (i.e., ---------~---~--~-------- :ontrait/Pirchaee Order # , I C -qXlJ- --~-------~~-------~~~~~~ I I ~~~---~~~~~~~T~~~ FONTRACTING PERIODi IWNERSHIP: ,I 1 AECIMED AECMED GOVT GOUT &NTtiAC+OR

  2. Forest Carbon Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    forest carbon cycle Forest Carbon Cycle Terrestrial carbon stocks above- and belowground (in humus and litter layers, woody debris, and mineral soil) are not only sensitive to physical environmental controls (e.g., temperature, precipitation, soil moisture) but also to land use history/management, disturbance, "quality" of carbon input (a reflection of plant carbon allocation and species controls), and the microbial community. The relative importance of these controls on soil carbon

  3. Carbon Capture (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Smit, Berend

    2011-06-08

    Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  4. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  5. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

    1997-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  6. Type here

    Office of Environmental Management (EM)

    Injury at the Savannah River National Laboratory | Department of Energy January 10, 2006, Flash Fire and Injury at the Savannah River National Laboratory Type B Accident Investigation of the January 10, 2006, Flash Fire and Injury at the Savannah River National Laboratory February 1, 2006 On January 10, 2006, at approximately 7:47 a.m., a first-line manager (FLM) at the Savannah River National Laboratory (SRNL) received first- and second-degree burns to his head, face, neck, and left hand

  7. Carbon monoxide sensor and method of use thereof

    DOE Patents [OSTI]

    McDaniel; Anthony H. , Medlin; J. Will , Bastasz; Robert J.

    2007-09-04

    Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

  8. Determination of the Evaporation Coefficient of D2O

    SciTech Connect (OSTI)

    Drisdell, Walter S.; Cappa, Christopher D.; Smith, Jared D.; Saykally, Richard J.; Cohen, Ronald C.

    2008-03-26

    The evaporation rate of D{sub 2}O has been determined by Raman thermometry of a droplet train (12-15 {micro}m diameter) injected into vacuum ({approx}10{sup -5} torr). The cooling rate measured as a function of time in vacuum was fit to a model that accounts for temperature gradients between the surface and the core of the droplets, yielding an evaporation coefficient ({gamma}{sub e}) of 0.57 {+-} 0.06. This is nearly identical to that found for H{sub 2}O (0.62 {+-} 0.09) using the same experimental method and model, and indicates the existence of a kinetic barrier to evaporation. The application of a recently developed transition state theory (TST) model suggests that the kinetic barrier is due to librational and hindered translational motions at the liquid surface, and that the lack of an isotope effect is due to competing energetic and entropic factors. The implications of these results for cloud and aerosol particles in the atmosphere are discussed.

  9. Carbon Nanotube Based Sensors

    SciTech Connect (OSTI)

    Jiang, Mian; Lin, Yuehe

    2006-11-01

    This review article provides a comprehensive review on sensors and biosensors based on functionalized carbon nanotubes.

  10. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J.

    1998-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  11. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J.

    1999-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  12. Carbon nanotube composite materials

    DOE Patents [OSTI]

    O'Bryan, Gregory; Skinner, Jack L; Vance, Andrew; Yang, Elaine Lai; Zifer, Thomas

    2015-03-24

    A material consisting essentially of a vinyl thermoplastic polymer, un-functionalized carbon nanotubes and hydroxylated carbon nanotubes dissolved in a solvent. Un-functionalized carbon nanotube concentrations up to 30 wt % and hydroxylated carbon nanotube concentrations up to 40 wt % can be used with even small concentrations of each (less than 2 wt %) useful in producing enhanced conductivity properties of formed thin films.

  13. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, R.J.

    1998-02-10

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein. 17 figs.

  14. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Fulvio, Pasquale Fernando; Mayes, Richard T.; Wang, Xiqing; Sun, Xiao-Guang; Guo, Bingkun

    2014-09-09

    A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.

  15. The theoretical ultimate magnetoelectric coefficients of magnetoelectric composites by optimization design

    SciTech Connect (OSTI)

    Wang, H.-L.; Liu, B.

    2014-03-21

    This paper investigates what is the largest magnetoelectric (ME) coefficient of ME composites, and how to realize it. From the standpoint of energy conservation, a theoretical analysis is carried out on an imaginary lever structure consisting of a magnetostrictive phase, a piezoelectric phase, and a rigid lever. This structure is a generalization of various composite layouts for optimization on ME effect. The predicted theoretical ultimate ME coefficient plays a similar role as the efficiency of ideal heat engine in thermodynamics, and is used to evaluate the existing typical ME layouts, such as the parallel sandwiched layout and the serial layout. These two typical layouts exhibit ME coefficient much lower than the theoretical largest values, because in the general analysis the stress amplification ratio and the volume ratio can be optimized independently and freely, but in typical layouts they are dependent or fixed. To overcome this shortcoming and achieve the theoretical largest ME coefficient, a new design is presented. In addition, it is found that the most commonly used electric field ME coefficient can be designed to be infinitely large. We doubt the validity of this coefficient as a reasonable ME effect index and consider three more ME coefficients, namely the electric charge ME coefficient, the voltage ME coefficient, and the static electric energy ME coefficient. We note that the theoretical ultimate value of the static electric energy ME coefficient is finite and might be a more proper measure of ME effect.

  16. Shunting arc plasma source for pure carbon ion beam

    SciTech Connect (OSTI)

    Koguchi, H.; Sakakita, H.; Kiyama, S.; Shimada, T.; Sato, Y.; Hirano, Y.

    2012-02-15

    A plasma source is developed using a coaxial shunting arc plasma gun to extract a pure carbon ion beam. The pure carbon ion beam is a new type of deposition system for diamond and other carbon materials. Our plasma device generates pure carbon plasma from solid-state carbon material without using a hydrocarbon gas such as methane gas, and the plasma does not contain any hydrogen. The ion saturation current of the discharge measured by a double probe is about 0.2 mA/mm{sup 2} at the peak of the pulse.

  17. Revisiting Maxwell’s accommodation coefficient: A study of nitrogen flow in a silica microtube across all flow regimes

    SciTech Connect (OSTI)

    Lei, Wenwen McKenzie, David R.

    2014-12-15

    Gas flows have been studied quantitatively for more than a hundred years and have relevance in modern fields such as the control of gas inputs to processes, the measurement of leak rates and the separation of gaseous species. Cha and McCoy have derived a convenient formula for the flow of an ideal gas applicable across a wide range of Knudsen numbers (Kn) that approaches the Navier–Stokes equations at small Kn and the Smoluchowski extension of the Knudsen flow equation at large Kn. Smoluchowski’s result relies on the Maxwell definition of the tangential momentum accommodation coefficient α, recently challenged by Arya et al. We measure the flow rate of nitrogen gas in a smooth walled silica tube across a wide range of Knudsen numbers from 0.0048 to 12.4583. We find that the nitrogen flow obeys the Cha and McCoy equation with a large value of α, unlike carbon nanotubes which show flows consistent with a small value of α. Silica capillaries are therefore not atomically smooth. The flow at small Kn has α=0.91 and at large Kn has α close to one, consistent with the redefinition of accommodation coefficient by Arya et al., which also resolves a problem in the literature where there are many observations of α of less than one at small Kn and many equal to one at large Kn. Silica capillaries are an excellent choice for an accurate flow control system. - Highlights: • First experimental study on flow rate across all flow regimes in a well-defined microtube. • Extend Cha and McCoy theory for molecular flow regime. • Demonstrate the Maxwell accommodation coefficient is different in the slip and molecular flow regimes.

  18. Estimating Uranium Partition Coefficients from Laboratory Adsorption Isotherms

    SciTech Connect (OSTI)

    Hull, L.C.; Grossman, C.; Fjeld, R.A.; Coates, J.T.; Elzerman, A.W.

    2002-05-10

    An estimated 330 metric tons of uranium have been buried in the radioactive waste Subsurface Disposal Area (SDA) at the Idaho National Engineering and Environmental Laboratory (INEEL). An assessment of uranium transport parameters is being performed to decrease the uncertainty in risk and dose predictions derived from computer simulations of uranium fate and transport to the underlying Snake River Plain Aquifer. Uranium adsorption isotherms have been measured in the laboratory and fit with a Freundlich isotherm. The Freundlich n parameter was statistically identical for 14 sediment samples. The Freundlich Kf for seven samples, where material properties have been measured, is correlated to sediment surface area. Based on these empirical observations, a model has been derived for adsorption of uranium on INEEL sedimentary materials using surface complexation theory. The model was then used to predict the range of adsorption conditions to be expected at the SDA. Adsorption in the deep vadose zone is predicted to be stronger than in near-surface sediments because the total dissolved carbonate decreases with depth.

  19. Estimating Uranium Partition Coefficients from Laboratory Adsorption Isotherms

    SciTech Connect (OSTI)

    Hull, Laurence Charles; Grossman, Christopher; Fjeld, R. A.; Coates, C.J.; Elzerman, A.

    2002-08-01

    An estimated 330 metric tons of uranium have been buried in the radioactive waste Subsurface Disposal Area (SDA) at the Idaho National Engineering and Environmental Laboratory (INEEL). An assessment of uranium transport parameters is being performed to decrease the uncertainty in risk and dose predictions derived from computer simulations of uranium fate and transport to the underlying Snake River Plain Aquifer. Uranium adsorption isotherms have been measured in the laboratory and fit with a Freundlich isotherm. The Freundlich n parameter was statistically identical for 14 sediment samples. The Freundlich Kf for seven samples, where material properties have been measured, is correlated to sediment surface area. Based on these empirical observations, a model has been derived for adsorption of uranium on INEEL sedimentary materials using surface complexation theory. The model was then used to predict the range of adsorption conditions to be expected at the SDA. Adsorption in the deep vadose zone is predicted to be stronger than in near-surface sediments because the total dissolved carbonate decreases with depth.

  20. Carbon fuel cells with carbon corrosion suppression

    DOE Patents [OSTI]

    Cooper, John F.

    2012-04-10

    An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

  1. Metallic carbon materials

    DOE Patents [OSTI]

    Cohen, Marvin Lou; Crespi, Vincent Henry; Louie, Steven Gwon Sheng; Zettl, Alexander Karlwalter

    1999-01-01

    Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

  2. Carbon Jungle | Open Energy Information

    Open Energy Info (EERE)

    Jungle Jump to: navigation, search Name: Carbon Jungle Place: El Segundo, California Zip: 90246 Sector: Carbon Product: Carbon Jungle's mission is to decrease CO2 in the atmosphere...

  3. Carbon Connections | Open Energy Information

    Open Energy Info (EERE)

    Connections Jump to: navigation, search Name: Carbon Connections Place: Norfolk, England, United Kingdom Zip: NR4 7TJ Sector: Carbon Product: Carbon Connections links partner...

  4. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile...

  5. Asset Carbon | Open Energy Information

    Open Energy Info (EERE)

    Carbon Jump to: navigation, search Name: Asset Carbon Place: United Kingdom Product: UK-based startup looking to invest in CDMJI projects. References: Asset Carbon1 This article...

  6. Jumpstarting the carbon capture industry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jumpstarting the carbon capture industry: Science on the Hill Jumpstarting the carbon capture industry: Science on the Hill Carbon capture, utilization, and storage can provide a...

  7. Photoconductivity of Activated Carbon Fibers

    DOE R&D Accomplishments [OSTI]

    Kuriyama, K.; Dresselhaus, M. S.

    1990-08-01

    The photoconductivity is measured on a high-surface-area disordered carbon material, namely activated carbon fibers, to investigate their electronic properties. Measurements of decay time, recombination kinetics and temperature dependence of the photoconductivity generally reflect the electronic properties of a material. The material studied in this paper is a highly disordered carbon derived from a phenolic precursor, having a huge specific surface area of 1000--2000m{sup 2}/g. Our preliminary thermopower measurements suggest that this carbon material is a p-type semiconductor with an amorphous-like microstructure. The intrinsic electrical conductivity, on the order of 20S/cm at room temperature, increases with increasing temperature in the range 30--290K. In contrast with the intrinsic conductivity, the photoconductivity in vacuum decreases with increasing temperature. The recombination kinetics changes from a monomolecular process at room temperature to a biomolecular process at low temperatures. The observed decay time of the photoconductivity is {approx equal}0.3sec. The magnitude of the photoconductive signal was reduced by a factor of ten when the sample was exposed to air. The intrinsic carrier density and the activation energy for conduction are estimated to be {approx equal}10{sup 21}/cm{sup 3} and {approx equal}20meV, respectively. The majority of the induced photocarriers and of the intrinsic carriers are trapped, resulting in the long decay time of the photoconductivity and the positive temperature dependence of the conductivity.

  8. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B.

    1991-01-01

    A process for making a carbon-carbon composite having a combination of high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizable woven cloth are covered with petroleum or coal tar pitch and pressed at a temperature a few degrees above the softening point of the pitch to form a green laminated composite. The green composite is restrained in a suitable fixture and heated slowly to carbonize the pitch binder. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnation step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3000.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. to 1300.degree. C. at a reduced pressure for approximately one hundred and fifty (150) hours.

  9. Carbon nanotube nanoelectrode arrays

    DOE Patents [OSTI]

    Ren, Zhifeng; Lin, Yuehe; Yantasee, Wassana; Liu, Guodong; Lu, Fang; Tu, Yi

    2008-11-18

    The present invention relates to microelectode arrays (MEAs), and more particularly to carbon nanotube nanoelectrode arrays (CNT-NEAs) for chemical and biological sensing, and methods of use. A nanoelectrode array includes a carbon nanotube material comprising an array of substantially linear carbon nanotubes each having a proximal end and a distal end, the proximal end of the carbon nanotubes are attached to a catalyst substrate material so as to form the array with a pre-determined site density, wherein the carbon nanotubes are aligned with respect to one another within the array; an electrically insulating layer on the surface of the carbon nanotube material, whereby the distal end of the carbon nanotubes extend beyond the electrically insulating layer; a second adhesive electrically insulating layer on the surface of the electrically insulating layer, whereby the distal end of the carbon nanotubes extend beyond the second adhesive electrically insulating layer; and a metal wire attached to the catalyst substrate material.

  10. Carbon Emissions: Food Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct....

  11. Wear and friction behavior of metal impregnated microporous carbon composites

    SciTech Connect (OSTI)

    Goller, G.; Koty, D.P.; Tewari, S.N.; Singh, M.; Tekin, A.

    1996-11-01

    Metal-matrix composites have been prepared by pressure-infiltration casting of copper-base alloy melts into microporous carbon preforms. The carbon preforms contained varying proportions of amorphous carbon and graphite. Load dependence of the wear and friction behavior of the composite pins has been examined under ambient conditions against cast-iron plates, using a pin-on-plate reciprocating wear tester. The wear resistance of the composite is significantly improved, as compared with the base alloy. Contrary to the normally expected behavior, the addition of graphite to the amorphous carbon does not reduce the friction coefficient, especially at high loads. The wear and friction behavior of the composites is very sensitive to the size and distribution of the microstructural constituents.

  12. ARM - Measurement - Total carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total carbon The total concentration of carbon in all its organic and non-organic forms. Categories Atmospheric Carbon, Aerosols Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including

  13. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F.; Vajo, John J.; Cumberland, Robert W.; Liu, Ping; Salguero, Tina T.

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  14. Carbon Sequestration.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concepts Current Sequestration Methods Novel Concepts * Glacial Storage * Biogenic Methane * Mineralization * Waste Streams Recycling * Calcium Carbonate Hydrates Glacial...

  15. Carbon Bearing Trace Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon bearing trace gases Carbon Bearing Trace Gases A critical scientific and policy oriented question is what are the present day sources and sinks of carbon dioxide (CO2) in the natural environment and how will these sinks evolve under rising CO2 concentrations and expected climate change and ecosystem response. Sources and sinks of carbon dioxide impart their signature on the distribution, concentration, and isotopic composition of CO2. Spatial and temporal trends (variability) provide

  16. Carbon Capture Simulation Initiative

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capture R&D Carbon Capture R&D DOE's Carbon Capture Program, administered by the Office of Fossil Energy and the National Energy Technology Laboratory, is conducting research and development activities on Second Generation and Transformational carbon capture technologies that have the potential to provide step-change reductions in both cost and energy penalty as compared to currently available First Generation technologies. The Carbon Capture Program consists of two core research

  17. Wetland (peat) Carbon Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    wetland peat carbon cycle Wetland (peat) Carbon Cycle Methane (CH4) is an important greenhouse gas, twenty times more potent than CO2, but atmospheric concentrations of CH4 under future climate change are uncertain. This is in part because many climate-sensitive ecosystems release both CH4 and carbon dioxide (CO2) and it is unknown how these systems will partition future releases of carbon to the atmosphere. Ecosystem observations of CH4 emissions lack mechanistic links to the processes that

  18. Big Sky Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    (Acknowledgment to the Big Sky Carbon Sequestration Partnership (BSCSP); see home page at http://www.bigskyco2.org/)

  19. Intro to Carbon Sequestration

    ScienceCinema (OSTI)

    None

    2010-01-08

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  20. Intro to Carbon Sequestration

    SciTech Connect (OSTI)

    2008-03-06

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  1. On the Stochastic Maximum Principle in Optimal Control of Degenerate Diffusions with Lipschitz Coefficients

    SciTech Connect (OSTI)

    Bahlali, Khaled Djehiche, Boualem Mezerdi, Brahim

    2007-12-15

    We establish a stochastic maximum principle in optimal control of a general class of degenerate diffusion processes with global Lipschitz coefficients, generalizing the existing results on stochastic control of diffusion processes. We use distributional derivatives of the coefficients and the Bouleau Hirsh flow property, in order to define the adjoint process on an extension of the initial probability space.

  2. ARM: 10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  3. ARM: 10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2010-12-15

    10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  4. Rock Physics of Geologic Carbon Sequestration/Storage Type of...

    Office of Scientific and Technical Information (OSTI)

    ... 2 into sandstones from the Otway Basin, Geophysics, 78, D293-D306. Mavko, G., Mukerji, T., and Dvorkin, J., 2009, Rock Physics Handbook, 2 nd Edition, Cambridge University Press. ...

  5. Rock Physics of Geologic Carbon Sequestration/Storage Type of...

    Office of Scientific and Technical Information (OSTI)

    ... reduction of water saturation S w with the increasing capillary pressure P c : S w S wi + (1 - S wi )(P t P c ) , (2.1) where S wi is the irreducible water saturation; P t ...

  6. Carbon dioxide sensor

    DOE Patents [OSTI]

    Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

    2011-11-15

    The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

  7. Henry`s law solubilities and Setchenow coefficients for biogenic reduced sulfur species obtained from gas-liquid uptake measurements

    SciTech Connect (OSTI)

    De Bruyn, W.J.; Swartz, E.; Hu, J.H. [Boston College, Chestnut Hill, MA (United States)] [and others] [Boston College, Chestnut Hill, MA (United States); and others

    1995-04-20

    Biogenically produced reduced sulfur compounds, including dimethylsulfide (DMS, CH{sub 3}SCH{sub 3}), hydrogen sulfide (H{sub 2}S), carbon disulfide (CS{sub 2}), methyl mercaptan (CH{sub 3}SH), and carbonyl sulfide (OCS), are a major source of sulfur in the marine atmosphere. This source is estimated to contribute 25-40% of global sulfur emissions. These species and their oxidation products, dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO{sub 2}), and methane sulfonic acid (MSA), dominate the production of aerosol and cloud condensation nuclei (CCN) in the clean marine atmosphere. The multiphase chemical processes for these species must be understood in order to study the evolving role of combustion-produced sulfur oxides over the oceans. Using a newly developed bubble column apparatus, a series of aqueous phase uptake studies have been completed for the reduced sulfur species DMS, H{sub 2}S, CS{sub 2}, CH{sub 3}SH, and OCS. Aqueous phase uptake has been studied as a function of temperature (278-298 K), pH (1-14), H{sub 2}O{sub 2} concentration (0-1 M), NaCl concentration (0-5 M), and (NH{sub 4}){sub 2}SO{sub 4} concentration (0-4 M). The Henry`s law coefficients for CH{sub 3}SH and CS{sub 2} were determined for the first time, as were the Setchenow coefficients for all the species studied. 33 refs., 8 figs., 2 tabs.

  8. Sandwich-type electrode

    DOE Patents [OSTI]

    Lu, Wen-Tong P.; Garcia, Earl R.

    1983-01-01

    Disclosed is an improvement on a method of making an electrode wherein a suspension in a liquid is prepared of a powdered catalyst containing a noble metal, carbon powder and a binder, and the suspension is poured over a carbon substrate dried, compressed and sintered to form a solid catalyst layer bonded to the carbon substrate. The improvement is placing a carbon paper on the catalyst layer prior to compressing. The improved electrode can be used as either a cathode or an anode in a sulfur dioxide depolarized electrolyzer in a process for producing hydrogen from water.

  9. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Wang, Xiqing

    2013-08-20

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  10. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Wang, Xiqing

    2012-02-14

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  11. Ion source sample preparation techniques for carbon-14 AMS measurements

    SciTech Connect (OSTI)

    Balsley, D.R.; Farwell, G.W.; Grootes, P.M.; Schmidt, F.H.

    1987-01-01

    Methods for preparing solid graphite, and other types of carbon samples possessing good geometrical characteristics and producing large beams are described. Amorphous carbon, or graphite powder, is encapsulated in tantalum, compressed to approx.14 kilobars, and heated in vacuum to approx.2500/sup 0/C. The end of the capsule is cut off, exposing a smooth and hard graphite surface which provides excellent emittance in a reflection-type sputter source. The powder is prepared from CO/sub 2/ by the hydrogen-iron powder catalyzation method. Silver-carbon mixtures with good geometrical properties can also be prepared with our press. 6 refs., 4 figs.

  12. Transport coefficients in Lorentz plasmas with the power-law kappa-distribution

    SciTech Connect (OSTI)

    Jiulin, Du

    2013-09-15

    Transport coefficients in Lorentz plasma with the power-law κ-distribution are studied by means of using the transport equation and macroscopic laws of Lorentz plasma without magnetic field. Expressions of electric conductivity, thermoelectric coefficient, and thermal conductivity for the power-law κ-distribution are accurately derived. It is shown that these transport coefficients are significantly modified by the κ-parameter, and in the limit of the parameter κ→∞ they are reduced to the standard forms for a Maxwellian distribution.

  13. Carbon Dioxide Utilization Summit

    Broader source: Energy.gov [DOE]

    The 6th Carbon Dioxide Utilization Summit will be held in Newark, New Jersey, from Feb. 24–26, 2016. The conference will look at the benefits and challenges of carbon dioxide utilization. Advanced Algal Systems Program Manager Alison Goss Eng and Technology Manager Devinn Lambert will be in attendance. Dr. Goss Eng will be chairing a round table on Fuels and Chemicals during the Carbon Dioxide Utilization: From R&D to Commercialization discussion session.

  14. Activated Carbon Injection

    ScienceCinema (OSTI)

    None

    2014-07-22

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  15. Activated Carbon Injection

    SciTech Connect (OSTI)

    2014-07-16

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  16. Reinforced Carbon Nanotubes.

    DOE Patents [OSTI]

    Ren, Zhifen; Wen, Jian Guo; Lao, Jing Y.; Li, Wenzhi

    2005-06-28

    The present invention relates generally to reinforced carbon nanotubes, and more particularly to reinforced carbon nanotubes having a plurality of microparticulate carbide or oxide materials formed substantially on the surface of such reinforced carbon nanotubes composite materials. In particular, the present invention provides reinforced carbon nanotubes (CNTs) having a plurality of boron carbide nanolumps formed substantially on a surface of the reinforced CNTs that provide a reinforcing effect on CNTs, enabling their use as effective reinforcing fillers for matrix materials to give high-strength composites. The present invention also provides methods for producing such carbide reinforced CNTs.

  17. Carbon Capture, Utilization & Storage

    Broader source: Energy.gov [DOE]

    Learn about the Energy Department's work to advance capture and safe, sustainable storage of carbon dioxide emissions in underground geologic formations.

  18. Activated carbon material

    DOE Patents [OSTI]

    Evans, A. Gary

    1978-01-01

    Activated carbon particles for use as iodine trapping material are impregnated with a mixture of selected iodine and potassium compounds to improve the iodine retention properties of the carbon. The I/K ratio is maintained at less than about 1 and the pH is maintained at above about 8.0. The iodine retention of activated carbon previously treated with or coimpregnated with triethylenediamine can also be improved by this technique. Suitable flame retardants can be added to raise the ignition temperature of the carbon to acceptable standards.

  19. Hardy-Littlewood theorem for trigonometric series with {alpha}-monotone coefficients

    SciTech Connect (OSTI)

    Dyachenko, Mikhail I; Nursultanov, Erlan D

    2009-12-31

    The Hardy-Littlewood theorem is established for trigonometric series with {alpha}-monotone coefficients. Inequalities of Hardy-Littlewood kind are proved. Examples of series demonstrating that the results obtained are sharp are constructed. Bibliography: 15 titles.

  20. Boston Carbon Corp | Open Energy Information

    Open Energy Info (EERE)

    Carbon Corp Jump to: navigation, search Name: Boston Carbon Corp Place: Carlisle, Massachusetts Zip: 1741 Sector: Carbon Product: Boston Carbon Corporation helps develop clean...

  1. Edgewood Carbon Holdings LLC | Open Energy Information

    Open Energy Info (EERE)

    Edgewood Carbon Holdings LLC Jump to: navigation, search Name: Edgewood Carbon Holdings LLC Place: Cornwall, Vermont Zip: 57530 Sector: Carbon Product: Edgewood Carbon Holdings LLC...

  2. Eon Masdar Integrated Carbon | Open Energy Information

    Open Energy Info (EERE)

    Eon Masdar Integrated Carbon Jump to: navigation, search Name: Eon Masdar Integrated Carbon Place: Germany Sector: Carbon Product: Germany-based carbon emission projects developer....

  3. Renaissance Carbon Investment Ltd | Open Energy Information

    Open Energy Info (EERE)

    Carbon Investment Ltd Jump to: navigation, search Name: Renaissance Carbon Investment Ltd. Place: Shanghai, China Zip: 200052 Sector: Carbon Product: Renaissance Carbon Investment...

  4. Carbon-Based and Carbon-Supported Heterogeneous Catalysts for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon-Based and Carbon-Supported Heterogeneous Catalysts for the Conversion of Biomass Carbon-based heterogeneous catalysts play a central role in the conversion of biomass to...

  5. Unravelling the low thermal expansion coefficient of cation-substituted YBaCo4O7+δ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Manthiram, Arumugam; Huq, Ashfia; Kan, Wang Hay; Lai, Ke -Yu

    2016-01-12

    With an aim to understand the origin of the low thermal expansion coefficients (TECs), cation substituted YBaCo4O7-type oxides have been investigated by in-situ neutron diffraction, bond valence sum (BVS), thermogravimetric analysis, and dilatometry. The compositions YBaCo4O7+δ, Y0.9ln0.1BaCo3ZnO7+δ, and Y0.9ln0.1BaCo3Zn0.6Fe0.4O7+δ) were synthesized by solid-state reaction at 1200 °C. Here, Rietveld refinement of the joint synchrotron X-ray and neutron diffraction data shows that the Zn and Fe dopants have different preferences to substitute the Co ions in the 6c and 2a sites.

  6. A universal model for nanoporous carbon supercapacitors

    SciTech Connect (OSTI)

    Huang, Jingsong; Sumpter, Bobby G; Meunier, Vincent

    2009-01-01

    Supercapacitors based on nanoporous carbon materials, commonly called electric double-layer capacitors (EDLCs), are emerging as a novel type of energy-storage device with the potential to substitute batteries in applications that require high power densities. Nanoporous carbon supercapacitors are generally viewed as a parallel-plate capacitor since supercapacitors store energy by charge separation in an electric double layer formed at the electrode/electrolyte interface. The EDLC model has been used to characterize the energy storage of supercapacitors for decades. We comment in this chapter on the shortcomings of the EDLC model when applied to nanoporous carbon supercapacitors. In response to the latest experimental breakthrough in nanoporous carbon supercapacitors, we have proposed a heuristic model that takes pore curvature into account as a replacement for the EDLC model. When the pore size is in the mesopore regime (2 50 nm), electrolyte counterions enter mesoporous carbons and approach the pore wall to form an electric double-cylinder capacitor (EDCC); in the micropore regime (< 2 nm), solvated/desolvated counterions line up along the pore axis to form an electric wire-in-cylinder capacitor (EWCC). In the macropore regime (> 50 nm), where pores are large enough so that pore curvature is no longer significant, the EDCC model can be reduced to the EDLC model. With the backing of experimental data and quantum density functional theory calculations, we have shown that the EDCC/EWCC model is universal for carbon supercapacitors with diverse carbon materials and electrolytes. The strengths and limitations of this new model are discussed. The new model allows the supercapacitor properties to be correlated with pore size, specific surface area, Debye length, electrolyte concentration, dielectric constant, and solute ion size, and may lend support to the systematic optimization of the properties of carbon supercapacitors through experiments.

  7. FITTING OF THE DATA FOR DIFFUSION COEFFICIENTS IN UNSATURATED POROUS MEDIA

    SciTech Connect (OSTI)

    B. Bullard

    1999-05-01

    The purpose of this calculation is to evaluate diffusion coefficients in unsaturated porous media for use in the TSPA-VA analyses. Using experimental data, regression techniques were used to curve fit the diffusion coefficient in unsaturated porous media as a function of volumetric water content. This calculation substantiates the model fit used in Total System Performance Assessment-1995 An Evaluation of the Potential Yucca Mountain Repository (TSPA-1995), Section 6.5.4.

  8. Coefficient indicates if rod pump can unload water from gas well

    SciTech Connect (OSTI)

    Hu Yongquan; Wu Zhijun

    1995-09-11

    A sucker rod pump can efficiently dewater gas wells if the separation coefficient is sufficiently high. To determine this separation coefficient, it is not sufficient to only know if the system meets the criteria of rod string stress, horsehead load, and crankshaft torque. This paper reviews water production and gas locking problems at the Sichuan gas field and identifies the methodologies used to optimize the pumping efficiency of the area wells.

  9. Microsoft PowerPoint - User Experience with Module Performance Coefficients.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    borregosolar.com © Borrego Solar Systems, Inc. Private & Confidential Generating Change Since 1980 User Experience with Module Performance Coefficients Bradley Hibberd 2013 Sandia PV Performance Modeling Workshop Santa Clara, CA May 1-2 2013 Published by Sandia National Laboratories with the Permission of the Author www.borregosolar.com © Borrego Solar Systems, Inc. Private & Confidential User Experience with Module Performance Coefficients ‣ Performance Modeling for Projects * For

  10. Recent Advances on Carbon Nanospheres. Synthetic Routes and Applications

    SciTech Connect (OSTI)

    Zhang, Pengfei; Qiao, Zhenan; Dai, Sheng

    2015-04-02

    Carbon-based materials are the most popular material types in both fundamental research and industrial applications, partly because of their well-controlled nano-morphologies. In the past two decades, we have witnessed a number of breakthroughs in carbon research: fullerenes, carbon nanotubes, and more recently graphene. Nowadays, carbon nanospheres are attracting more and more attention worldwide due to their excellent performance in various fields: drug delivery, heterogeneous catalysis, encapsulation of support and electrode materials. Actually, spherical carbon is an old material, whereas controlling carbon spheres in the nanometer range is a recent story. In the past 5 years, it has become possible to precisely control the particle size, surface area, pore size, chemical composition, and dispersity of carbon nanospheres. Toward this end, a number of synthetic strategies are emerging, such as hydrothermal carbonization of biomass-based resources, extended Stöber synthesis, and organic–organic self-assembly via different binding methods. In this feature article, we summarize recent routes for carbon nanospheres and briefly touch on their applications to shed light on the potential of this field. Throughout this article, a special emphasis is placed on the possible modulation of spherical structures at the nanoscale, and we wish to inspire many more designs and applications of carbon nanostructures in the near future.

  11. Recent Advances on Carbon Nanospheres. Synthetic Routes and Applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Pengfei; Qiao, Zhenan; Dai, Sheng

    2015-04-02

    Carbon-based materials are the most popular material types in both fundamental research and industrial applications, partly because of their well-controlled nano-morphologies. In the past two decades, we have witnessed a number of breakthroughs in carbon research: fullerenes, carbon nanotubes, and more recently graphene. Nowadays, carbon nanospheres are attracting more and more attention worldwide due to their excellent performance in various fields: drug delivery, heterogeneous catalysis, encapsulation of support and electrode materials. Actually, spherical carbon is an old material, whereas controlling carbon spheres in the nanometer range is a recent story. In the past 5 years, it has become possible tomore » precisely control the particle size, surface area, pore size, chemical composition, and dispersity of carbon nanospheres. Toward this end, a number of synthetic strategies are emerging, such as hydrothermal carbonization of biomass-based resources, extended Stöber synthesis, and organic–organic self-assembly via different binding methods. In this feature article, we summarize recent routes for carbon nanospheres and briefly touch on their applications to shed light on the potential of this field. Throughout this article, a special emphasis is placed on the possible modulation of spherical structures at the nanoscale, and we wish to inspire many more designs and applications of carbon nanostructures in the near future.« less

  12. Non-local thermodynamic equilibrium effects on isentropic coefficient in argon and helium thermal plasmas

    SciTech Connect (OSTI)

    Sharma, Rohit; Singh, Kuldip

    2014-03-15

    In the present work, two cases of thermal plasma have been considered; the ground state plasma in which all the atoms and ions are assumed to be in the ground state and the excited state plasma in which atoms and ions are distributed over various possible excited states. The variation of Z?, frozen isentropic coefficient and the isentropic coefficient with degree of ionization and non-equilibrium parameter ?(= T{sub e}/T{sub h}) has been investigated for the ground and excited state helium and argon plasmas at pressures 1?atm, 10?atm, and 100?atm in the temperature range from 6000?K to 60?000?K. For a given value of non-equilibrium parameter, the relationship of Z? with degree of ionization does not show any dependence on electronically excited states in helium plasma whereas in case of argon plasma this dependence is not appreciable till degree of ionization approaches 2. The minima of frozen isentropic coefficient shifts toward lower temperature with increase of non-equilibrium parameter for both the helium and argon plasmas. The lowering of non-equilibrium parameter decreases the frozen isentropic coefficient more emphatically in helium plasma at high pressures in comparison to argon plasma. The increase of pressure slightly reduces the ionization range over which isentropic coefficient almost remains constant and it does not affect appreciably the dependence of isentropic coefficient on non-equilibrium parameter.

  13. Electronic properties of linear carbon chains: Resolving the controversy

    SciTech Connect (OSTI)

    Al-Backri, Amaal; Zólyomi, Viktor; Lambert, Colin J.

    2014-03-14

    Literature values for the energy gap of long one-dimensional carbon chains vary from as little as 0.2 eV to more than 4 eV. To resolve this discrepancy, we use the GW many-body approach to calculate the band gap E{sub g} of an infinite carbon chain. We also compute the energy dependence of the attenuation coefficient β governing the decay with chain length of the electrical conductance of long chains and compare this with recent experimental measurements of the single-molecule conductance of end-capped carbon chains. For long chains, we find E{sub g} = 2.16 eV and an upper bound for β of 0.21 Å{sup −1}.

  14. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock

  15. Fly ash carbon passivation

    DOE Patents [OSTI]

    La Count, Robert B; Baltrus, John P; Kern, Douglas G

    2013-05-14

    A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

  16. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, Stephen E.; Moses, William W.

    1991-01-01

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses.

  17. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon...

    Open Energy Info (EERE)

    Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title...

  18. Thermal expansion of multiwall carbon nanotube reinforced nanocrystalline silver matrix composite

    SciTech Connect (OSTI)

    Sharma, Manjula Sharma, Vimal; Pal, Hemant

    2014-04-24

    Multiwall carbon nanotube reinforced silver matrix composite was fabricated by novel molecular level mixing method, which involves nucleation of Ag ions inside carbon nanotube dispersion at the molecular level. As a result the carbon nanotubes get embedded within the powder rather than on the surfaces. Micro structural characterization by X- ray diffraction and scanning electron microscopy reveals that the nanotubes are homogeneously dispersed and anchored within the matrix. The thermal expansion of the composite with the multiwall nanotube content (0, 1.5 vol%) were investigated and it is found that coefficient of thermal expansion decreases with the addition of multiwall nanotube content and reduce to about 63% to that of pure Ag.

  19. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon First Proof of Ferromagnetic Carbon Print Wednesday, 25 July 2007 00:00 Although it has long been suspected that carbon belongs on the short list of...

  20. carbon | OpenEI Community

    Open Energy Info (EERE)

    carbon Home Graham7781's picture Submitted by Graham7781(2017) Super contributor 9 January, 2014 - 13:12 Suburbs offset Low Carbon Footprint of major U.S. Cities carbon cities CO2...

  1. Magnetic properties and transmission electron microscopy studies of Ni nanoparticles encapsulated in carbon nanocages and carbon nanotubes

    SciTech Connect (OSTI)

    He Chunnian; Zhao Naiqin Shi Chunsheng; Li Jiajun; Li Haipeng

    2008-08-04

    Three types of carbon nanomaterials, including bamboo-shaped carbon nanotubes with Ni encapsulated and hollow and Ni catalytic particles filled carbon nanocages, have been prepared by methane catalytic decomposition at a relatively low temperature. Transmission electron microscopy observations showed that fascinating fullerene-like Ni-C (graphitic) core-shell nanostructures predominated. Detailed examination of high-resolution transmission electron microscopy showed that the walls of bamboo-shaped carbon nanotubes with quasi-cone catalytic particles encapsulated consisted of oblique graphene planes with respect to the tube axis. The Ni particles encapsulated in the carbon nanocages were larger than that encapsulated in carbon nanotubes, but the diameters of the cores of hollow carbon nanocages were less than that of Ni particles encapsulated in carbon nanotubes, suggesting that the sizes of catalyst particles played an important role during carbon nanomaterial growth. The magnetic properties of the carbon nanomaterials were measured, which showed relatively large coercive force (H{sub c} = 138.4 O{sub e}) and good ferromagnetism (M{sub r}/M{sub s} = 0.325)

  2. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-06-30

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. During the third quarter, planning efforts are underway for the next Partnership meeting which will showcase the architecture of the GIS framework and initial results for sources and sinks, discuss the methods and analysis underway for assessing geological and terrestrial sequestration potentials. The meeting will conclude with an ASME workshop (see attached agenda). The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement

  3. Effect of altitude on the carbon-isotope composition of forest and grassland soils from Papua New Guinea

    SciTech Connect (OSTI)

    Bird, M.I.; Haberle, S.G.; Chivas, A.R. )

    1994-03-01

    The stable isotope composition of carbon can be used to provide information on the origin of carbon in soil organic matter. This study looks at the effect of decreasing temperature and atmospheric pressure (altitude) on the carbon-isotope composition of soil organic carbon from forests and grasslands in tropical regions. Investigators examine whether a predictable relationship exists between vegetation type, the 13C value of surface soil organic matter, and altitude. The results provide a framework within which to more accurately constrain the carbon-isotope composition of terrestrial carbon ppls and to interpret the observed variations in the isotopic composition of rivere particulate organic carbon. 31 refs., 5 figs., 1 tab.

  4. ARM - Measurement - Black carbon concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of carbon in its very absorbing, elemental, non-organic, non-oxide form (e.g. graphite). Categories Aerosols, Atmospheric Carbon Instruments The above measurement is...

  5. Carbon Capture Research and Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center Lawrence Berkeley National Laboratory Research Institute of Innovative Energy Carbon Capture Research and Development Carbon capture and storage from fossil-based power...

  6. Carbon International | Open Energy Information

    Open Energy Info (EERE)

    International Jump to: navigation, search Name: Carbon International Place: London, United Kingdom Zip: NW1 8LH Sector: Carbon Product: London-based energy and communications...

  7. Carbone Lorraine | Open Energy Information

    Open Energy Info (EERE)

    Carbone Lorraine Jump to: navigation, search Name: Carbone Lorraine Place: France Product: Paris-based company developing industrial applications and systems for the optimal...

  8. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    finally put to rest doubts about the existence of magnetic carbon. Carbon's Magnetic Personality Attracts Attention Most materials exhibit weak forms of magnetism-diamagnetism,...

  9. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sensors, and data processing. Fortunately, additional research has proven that etching carbon with sulfuric acid can also make the carbon magnetic, opening the door for...

  10. Fossil Energy Research Benefits Carbon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    has become a world leader in carbon capture and storage (CCS) science and technology. ... and storing in geologic formations carbon dioxide (CO 2 ) from industrial or power plants. ...

  11. Behavior of the particle transport coefficients near the density limit in MTX

    SciTech Connect (OSTI)

    Marinak, M.M.

    1993-04-01

    The perturbed particle transport coefficients were determined for a range of plasma conditions in the Alcator C tokamak, a component of the Microwave Tokamak Experiment (MTX), from analysis of density perturbations created in gas modulation experiments. Density measurements from a 15 chord far-infrared interferometer were sufficiently detailed to allow radial profiles of the transport coefficients to be resolved. Gas modulation experiments were carried out on plasmas over a range of relatively low currents and a wide variety of line-averaged densities, including values near the Greenwald density limit. With this technique the perturbed diffusion coefficient D and the perturbed convection velocity V can be determined simultaneously. Measured profiles of D rise toward the outside of the plasma column in a manner generally similar to those determined previously for {chi}{sub e,HP} from sawtooth heat pulse propagation. Values of D are typically smaller than those of {chi}{sub e,HP} given for the same line-averaged densities by a factor of 2-5. Diffusion coefficients from a series of discharges at constant current showed little variation with density through most of the saturated ohmic confinement regime. At the Greenwald density limit threshold a dramatic increase occurred in both the perturbed convective and diffusive transport coefficients in the outer region of the plasma. The increases were most pronounced at the outermost range of the radii where coefficients were determined (r/a = 0.8), but were apparent over a region which extended well into the plasma interior. Density profiles maintained a similar shape near the density limit, congruous with the similar behavior of the transport coefficients. No dramatic deterioration was evident in the global energy confinement.

  12. ARM - Measurement - Cloud type

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement : Cloud type Cloud type such as cirrus, stratus, cumulus etc Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  13. Big Sky Carbon Sequestration Partnership

    SciTech Connect (OSTI)

    Susan Capalbo

    2005-12-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I are organized into four areas: (1) Evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; (2) Development of GIS-based reporting framework that links with national networks; (3) Design of an integrated suite of monitoring, measuring, and verification technologies, market-based opportunities for carbon management, and an economic/risk assessment framework; (referred to below as the Advanced Concepts component of the Phase I efforts) and (4) Initiation of a comprehensive education and outreach program. As a result of the Phase I activities, the groundwork is in place to provide an assessment of storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that complements the ongoing DOE research agenda in Carbon Sequestration. The geology of the Big Sky Carbon Sequestration Partnership Region is favorable for the potential sequestration of enormous volume of CO{sub 2}. The United States Geological Survey (USGS 1995) identified 10 geologic provinces and 111 plays in the region. These provinces and plays include both sedimentary rock types characteristic of oil, gas, and coal productions as well as large areas of mafic volcanic rocks. Of the 10 provinces and 111 plays, 1 province and 4 plays are located within Idaho. The remaining 9 provinces and 107 plays are dominated by sedimentary rocks and located in the states of Montana and Wyoming. The potential sequestration capacity of the 9 sedimentary provinces within the region ranges from 25,000 to almost 900,000 million metric tons of CO{sub 2}. Overall every sedimentary formation investigated

  14. Improving carbon fixation pathways

    SciTech Connect (OSTI)

    Ducat, DC; Silver, PA

    2012-08-01

    A recent resurgence in basic and applied research on photosynthesis has been driven in part by recognition that fulfilling future food and energy requirements will necessitate improvements in crop carbon-fixation efficiencies. Photosynthesis in traditional terrestrial crops is being reexamined in light of molecular strategies employed by photosynthetic microbes to enhance the activity of the Calvin cycle. Synthetic biology is well-situated to provide original approaches for compartmentalizing and enhancing photosynthetic reactions in a species independent manner. Furthermore, the elucidation of alternative carbon-fixation routes distinct from the Calvin cycle raises possibilities that novel pathways and organisms can be utilized to fix atmospheric carbon dioxide into useful materials.

  15. Terrestrial Carbon Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cycle Terrestrial Carbon Cycle "Only about half of the CO2 released into the atmosphere by human activities currently resides in the atmosphere, the rest absorbed on land and in the oceans. The period over which the carbon will be sequestered is unclear, and the efficiency of future sinks is unknown." US Carbon Cycle Research Plan "We" desire to be able to predict the future spatial and temporal distribution of sources and sinks of atmospheric CO2 and their interaction

  16. IMPACCT: Carbon Capture Technology

    SciTech Connect (OSTI)

    2012-01-01

    IMPACCT Project: IMPACCT’s 15 projects seek to develop technologies for existing coal-fired power plants that will lower the cost of carbon capture. Short for “Innovative Materials and Processes for Advanced Carbon Capture Technologies,” the IMPACCT Project is geared toward minimizing the cost of removing carbon dioxide (CO2) from coal-fired power plant exhaust by developing materials and processes that have never before been considered for this application. Retrofitting coal-fired power plants to capture the CO2 they produce would enable greenhouse gas reductions without forcing these plants to close, shifting away from the inexpensive and abundant U.S. coal supply.

  17. Electrolyte matrix for molten carbonate fuel cells

    DOE Patents [OSTI]

    Huang, Chao M.; Yuh, Chao-Yi

    1999-01-01

    A matrix for a carbonate electrolyte including a support material and an additive constituent having a relatively low melting temperature and a relatively high coefficient of thermal expansion. The additive constituent is from 3 to 45 weight percent of the matrix and is formed from raw particles whose diameter is in a range of 0.1 .mu.m to 20 .mu.m and whose aspect ratio is in a range of 1 to 50. High energy intensive milling is used to mix the support material and additive constituent during matrix formation. Also disclosed is the use of a further additive constituent comprising an alkaline earth containing material. The further additive is mixed with the support material using high energy intensive milling.

  18. Electrolyte matrix for molten carbonate fuel cells

    DOE Patents [OSTI]

    Huang, C.M.; Yuh, C.Y.

    1999-02-09

    A matrix is described for a carbonate electrolyte including a support material and an additive constituent having a relatively low melting temperature and a relatively high coefficient of thermal expansion. The additive constituent is from 3 to 45 weight percent of the matrix and is formed from raw particles whose diameter is in a range of 0.1 {micro}m to 20 {micro}m and whose aspect ratio is in a range of 1 to 50. High energy intensive milling is used to mix the support material and additive constituent during matrix formation. Also disclosed is the use of a further additive constituent comprising an alkaline earth containing material. The further additive is mixed with the support material using high energy intensive milling. 5 figs.

  19. Preparation and Characterization of Carbon Pellets from Pre-Carbonized Mangrove Leaves

    SciTech Connect (OSTI)

    Deraman, Mohamad; Mohtar, Mazliza; Jumali, Mohd Hafizuddin; Omar, Ramli; Yunus, Rozan Mohamad; Aziz, Astimar Abd; Senin, H. B.

    2007-05-09

    Mangrove leaves (ML) were pre-carbonized at low carbonization temperature, ball milled for 36 hours and followed by sieving to obtain powder (SACG) with particle size less than 53 micron and then pelletized into green pellets (GP). A multi-step heating profile which was previously proven suitable for producing 'crack-free' carbon pellets (CP) from the GP of the SACG from oil palm empty fruit bunch (EFB) was found to be suitable for producing CP from the SACG of the ML. Themogravimetri results on the SACG show that in comparison to the SACG-EFB, the SACG-ML decomposed with a lower rate of weight loss within a wider range of the temperature region and it maximum rate occurs at the slightly higher temperature. X-ray diffraction results found that both types the SACG retain their lignocellulosic structure. The density of CP produced up to the carbonization temperatures of 700 deg. C and 1000 deg. C respectively were found to be in the range from 0.94 to 1.03 gcm-3 and 0.98 to 1.28 gcm-3 for the ML and EFB samples respectively. X-ray diffraction results on the CP found that both type of samples have turbostratic structure, with their interlayer spacing d002 decrease with increasing carbonization temperature; that is from 3.79 Aa to 3.43 Aa for the ML samples and 3.82 Aa to 3.68 Aa for the EFB samples.

  20. ATK - Supersonic Carbon Capture

    ScienceCinema (OSTI)

    Castrogiovanni, Anthony (ACEnT Laboratories, President and CEO); Calayag, Bon (ATK, Program Manager)

    2014-04-11

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  1. Regional Carbon Sequestration Partnerships

    Office of Energy Efficiency and Renewable Energy (EERE)

    DOE has created a network of seven Regional Carbon Sequestration Partnerships (RCSPs) to help develop the technology, infrastructure, and regulations to implement large-scale CO2 storage (also...

  2. ATK - Supersonic Carbon Capture

    SciTech Connect (OSTI)

    Castrogiovanni, Anthony; Calayag, Bon

    2014-03-05

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  3. Activated carbon aerogels

    SciTech Connect (OSTI)

    Hanzawa, Y.; Kaneko, K. [Chiba Univ. (Japan)] [Chiba Univ. (Japan); Pekala, R.W. [Lawrence Livermore National Lab., CA (United States)] [Lawrence Livermore National Lab., CA (United States); Dresselhaus, M.S. [Massachusetts Inst. of Technology, Cambridge, MA (United States)] [Massachusetts Inst. of Technology, Cambridge, MA (United States)

    1996-12-25

    Activated carbon aerogels were obtained from the CO{sub 2} activation of the carbon aerogels. The adsorption isotherms of nitrogen on activated carbon aerogels at 77 K were measured and analyzed by the high-resolution {alpha}{sub s} plot to evaluate their porosities. The {alpha}{sub s} plot showed an upward deviation from linearity below {alpha}{sub s} = 0.5, suggesting that the presence of micropores becomes more predominant with the extent of the activation. Activation increased noticeably the pore volume and the surface area (the maximum value: 2600 m{sup 2}.g{sup -1}) without change of the basic network structure of primary particles. Activated carbon aerogels had a bimodal pore size distribution of uniform micropores and mesopores. 16 refs., 2 figs., 1 tab.

  4. Dynamic measurement of heat loss coefficients through Trombe wall glazing systems

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1981-01-01

    A Trombe wall presents a unique opportunity to measure the heat-loss coefficient through the glazing system because the wall itself can be used as a heat meter. Since the instantaneous heat flux through the outer wall surface can be determined, the heat loss coefficient at night can be calculated by dividing by the wall surface-to-ambient temperature difference. This technique has been used to determine heat-loss coefficients for Los Alamos test rooms during the winter of 1980-1981. Glazing systems studied include single and double glazing both with and without night insulation used in conjunction with a flat black paint, and both single and double glazing used in conjunction with a selective surface.

  5. Mean ionic activity coefficients in aqueous NaCl solutions from molecular dynamics simulations

    SciTech Connect (OSTI)

    Mester, Zoltan; Panagiotopoulos, Athanassios Z.

    2015-01-28

    The mean ionic activity coefficients of aqueous NaCl solutions of varying concentrations at 298.15 K and 1 bar have been obtained from molecular dynamics simulations by gradually turning on the interactions of an ion pair inserted into the solution. Several common non-polarizable water and ion models have been used in the simulations. Gibbs-Duhem equation calculations of the thermodynamic activity of water are used to confirm the thermodynamic consistency of the mean ionic activity coefficients. While the majority of model combinations predict the correct trends in mean ionic activity coefficients, they overestimate their values at high salt concentrations. The solubility predictions also suffer from inaccuracies, with all models underpredicting the experimental values, some by large factors. These results point to the need for further ion and water model development.

  6. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, S.E.; Moses, W.W.

    1991-05-14

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses. 3 figures.

  7. Carbon dioxide removal process

    DOE Patents [OSTI]

    Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

    2003-11-18

    A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

  8. Carbon Fiber Technology Facility

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Fiber Technology Facility Dave Warren, PI Cliff Eberle, Presenter Technology Development Manager Polymer Matrix Composites Oak Ridge National Laboratory May 16, 2012 Project ID # LM003 Status as of March 30, 2012 This presentation does not contain any proprietary, confidential, or otherwise restricted information 2 Managed by UT-Battelle for the U.S. Department of Energy Carbon Fiber Technology Facility (CFTF) ARRA CAPITAL Project Overview * Funds received FY10Q2 * Scheduled finish FY13Q4

  9. Observed drag coefficients in high winds in the near offshore of the South China Sea

    SciTech Connect (OSTI)

    Bi, Xueyan; Liu, Yangan; Gao, Zhiqiu; Liu, Feng; Song, Qingtao; Huang, Jian; Huang, Huijun; Mao, Weikang; Liu, Chunxia

    2015-07-14

    This paper investigates the relationships between friction velocity, 10 m drag coefficient, and 10 m wind speed using data collected at two offshore observation towers (one over the sea and the other on an island) from seven typhoon episodes in the South China Sea from 2008 to 2014. The two towers were placed in areas with different water depths along a shore-normal line. The depth of water at the tower over the sea averages about 15 m, and the depth of water near the island is about 10 m. The observed maximum 10 min average wind speed at a height of 10 m is about 32 m s⁻¹. Momentum fluxes derived from three methods (eddy covariance, inertial dissipation, and flux profile) are compared. The momentum fluxes derived from the flux profile method are larger (smaller) over the sea (on the island) than those from the other two methods. The relationship between the 10 m drag coefficient and the 10 m wind speed is examined by use of the data obtained by the eddy covariance method. The drag coefficient first decreases with increasing 10 m wind speed when the wind speeds are 5–10 m s⁻¹, then increases and reaches a peak value of 0.002 around a wind speed of 18 m s⁻¹. The drag coefficient decreases with increasing 10 m wind speed when 10 m wind speeds are 18–27 m s⁻¹. A comparison of the measurements from the two towers shows that the 10 m drag coefficient from the tower in 10 m water depth is about 40% larger than that from the tower in 15 m water depth when the 10 m wind speed is less than 10 m s⁻¹. Above this, the difference in the 10 m drag coefficients of the two towers disappears.

  10. EMPIRICAL DETERMINATION OF EINSTEIN A-COEFFICIENT RATIOS OF BRIGHT [Fe II] LINES

    SciTech Connect (OSTI)

    Giannini, T.; Antoniucci, S.; Nisini, B.; Lorenzetti, D.; Alcal, J. M.; Bacciotti, F.; Podio, L.; Bonito, R.; Stelzer, B.

    2015-01-01

    The Einstein spontaneous rates (A-coefficients) of Fe{sup +} lines have been computed by several authors with results that differ from each other by up to 40%. Consequently, models for line emissivities suffer from uncertainties that in turn affect the determination of the physical conditions at the base of line excitation. We provide an empirical determination of the A-coefficient ratios of bright [Fe II] lines that would represent both a valid benchmark for theoretical computations and a reference for the physical interpretation of the observed lines. With the ESO-Very Large Telescope X-shooter instrument between 3000 and 24700 , we obtained a spectrum of the bright Herbig-Haro object HH1. We detect around 100 [Fe II] lines, some of which with a signal-to-noise ratios ?100. Among these latter lines, we selected those emitted by the same level, whose dereddened intensity ratios are direct functions of the Einstein A-coefficient ratios. From the same X-shooter spectrum, we got an accurate estimate of the extinction toward HH1 through intensity ratios of atomic species, H I recombination lines and H{sub 2} ro-vibrational transitions. We provide seven reliable A-coefficient ratios between bright [Fe II] lines, which are compared with the literature determinations. In particular, the A-coefficient ratios involving the brightest near-infrared lines (?12570/?16440 and ?13209/?16440) are in better agreement with the predictions by the Quinet et al. relativistic Hartree-Fock model. However, none of the theoretical models predict A-coefficient ratios in agreement with all of our determinations. We also show that literature data of near-infrared intensity ratios better agree with our determinations than with theoretical expectations.

  11. Observed drag coefficients in high winds in the near offshore of the South China Sea

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bi, Xueyan; Liu, Yangan; Gao, Zhiqiu; Liu, Feng; Song, Qingtao; Huang, Jian; Huang, Huijun; Mao, Weikang; Liu, Chunxia

    2015-07-14

    This paper investigates the relationships between friction velocity, 10 m drag coefficient, and 10 m wind speed using data collected at two offshore observation towers (one over the sea and the other on an island) from seven typhoon episodes in the South China Sea from 2008 to 2014. The two towers were placed in areas with different water depths along a shore-normal line. The depth of water at the tower over the sea averages about 15 m, and the depth of water near the island is about 10 m. The observed maximum 10 min average wind speed at a heightmore » of 10 m is about 32 m s⁻¹. Momentum fluxes derived from three methods (eddy covariance, inertial dissipation, and flux profile) are compared. The momentum fluxes derived from the flux profile method are larger (smaller) over the sea (on the island) than those from the other two methods. The relationship between the 10 m drag coefficient and the 10 m wind speed is examined by use of the data obtained by the eddy covariance method. The drag coefficient first decreases with increasing 10 m wind speed when the wind speeds are 5–10 m s⁻¹, then increases and reaches a peak value of 0.002 around a wind speed of 18 m s⁻¹. The drag coefficient decreases with increasing 10 m wind speed when 10 m wind speeds are 18–27 m s⁻¹. A comparison of the measurements from the two towers shows that the 10 m drag coefficient from the tower in 10 m water depth is about 40% larger than that from the tower in 15 m water depth when the 10 m wind speed is less than 10 m s⁻¹. Above this, the difference in the 10 m drag coefficients of the two towers disappears.« less

  12. Observed drag coefficients in high winds in the near offshore of the South China Sea

    SciTech Connect (OSTI)

    Bi, Xueyan; Liu, Yangan; Gao, Zhiqiu; Liu, Feng; Song, Qingtao; Huang, Jian; Huang, Huijun; Mao, Weikang; Liu, Chunxia

    2015-07-14

    This paper investigates the relationships between friction velocity, 10 m drag coefficient, and 10 m wind speed using data collected at two offshore observation towers (one over the sea and the other on an island) from seven typhoon episodes in the South China Sea from 2008 to 2014. The two towers were placed in areas with different water depths along a shore-normal line. The depth of water at the tower over the sea averages about 15 m, and the depth of water near the island is about 10 m. The observed maximum 10 min average wind speed at a height of 10 m is about 32 m s?. Momentum fluxes derived from three methods (eddy covariance, inertial dissipation, and flux profile) are compared. The momentum fluxes derived from the flux profile method are larger (smaller) over the sea (on the island) than those from the other two methods. The relationship between the 10 m drag coefficient and the 10 m wind speed is examined by use of the data obtained by the eddy covariance method. The drag coefficient first decreases with increasing 10 m wind speed when the wind speeds are 510 m s?, then increases and reaches a peak value of 0.002 around a wind speed of 18 m s?. The drag coefficient decreases with increasing 10 m wind speed when 10 m wind speeds are 1827 m s?. A comparison of the measurements from the two towers shows that the 10 m drag coefficient from the tower in 10 m water depth is about 40% larger than that from the tower in 15 m water depth when the 10 m wind speed is less than 10 m s?. Above this, the difference in the 10 m drag coefficients of the two towers disappears.

  13. Biosensors Based on Carbon Nanotubes

    SciTech Connect (OSTI)

    Lin, Yuehe; Yantasee, Wassana; Lu, Fang; Wang, Joseph; Musameh, Mustafa; Tu, Yi; Ren, Zhifeng

    2009-03-24

    This chapter summarizes the recent development of carbon nanotube based electrochemical biosensors work at PNNL.

  14. Biosensors Based on Carbon Nanotubes

    SciTech Connect (OSTI)

    Lin, Yuehe; Yantasee, Wassana; Lu, Fang; Wang, Joseph; Musameh, Mustafa; Tu, Yi; Ren, Zhifeng; J. A. Schwarz, C. Contescu, K. Putyera

    2004-04-01

    This invited review article summarizes recent work on biosensor development based on carbon nanotubes

  15. Method for synthesizing carbon nanotubes

    DOE Patents [OSTI]

    Fan, Hongyou

    2012-09-04

    A method for preparing a precursor solution for synthesis of carbon nanomaterials, where a polar solvent is added to at least one block copolymer and at least one carbohydrate compound, and the precursor solution is processed using a self-assembly process and subsequent heating to form nanoporous carbon films, porous carbon nanotubes, and porous carbon nanoparticles.

  16. Estimation of instantaneous heat transfer coefficients for a direct-injection stratified-charge rotary engine

    SciTech Connect (OSTI)

    Lee, C.M.; Addy, H.E.; Bond, T.H.; Chun, K.S.

    1987-01-01

    The main objective of this report was to derive equations to estimate neat transfer coefficients in both the combustion chamber and coolant passage of a rotary engine. This was accomplished by making detailed temperature and pressure measurements in a direct-injection stratified-charge rotary engine under a range of conditions. For each specific measurement point, the local physical properties of the fluids were calculated. Then an empirical correlation of the coefficients was derived by using a multiple regression program. This correlation expresses the Nusselt number as a function of the Prandtl number and Reynolds number.

  17. Effect of electron collisions on transport coefficients induced by the inverse bremsstrahlung absorption in plasmas

    SciTech Connect (OSTI)

    Bendib, A.; Tahraoui, A.; Bendib, K.; Mohammed El Hadj, K.; Hueller, S.

    2005-03-01

    The transport coefficients of fully ionized plasmas under the influence of a high-frequency electric field are derived solving numerically the electron Fokker-Planck equation using a perturbation method, parametrized as a function of the electron mean-free-path {lambda}{sub ei} compared to the spatial scales L. The isotropic and anisotropic contributions of the inverse bremsstrahlung heating are considered. Electron-electron collision terms are kept in the analysis, which allows us to consider with sufficient accuracy to describe plasmas with arbitrary atomic number Z. Practical numerical fits of the transport coefficients are proposed as functions of Z and the collisionality parameter {lambda}{sub ei}/L.

  18. Metastable Changes to the Temperature Coefficients of Thin-Film Photovoltaic Modules

    SciTech Connect (OSTI)

    Deceglie, M. G.; Silverman, T. J.; Marion, B.; Kurtz, S. R.

    2014-07-01

    Transient changes in the performance of thin-film modules with light exposure are a well-known and widely reported phenomenon. These changes are often the result of reversible metastabilities rather than irreversible changes. Here we consider how these metastable changes affect the temperature dependence of photovoltaic performance. We find that in CIGS modules exhibiting a metastable increase in performance with light exposure, the light exposure also induces an increase in the magnitude of the temperature coefficient. It is important to understand such changes when characterizing temperature coefficients and when analyzing the outdoor performance of newly installed modules.

  19. Diffusion coefficients of Fokker-Planck equation for rotating dust grains in a fusion plasma

    SciTech Connect (OSTI)

    Bakhtiyari-Ramezani, M. Alinejad, N.; Mahmoodi, J.

    2015-11-15

    In the fusion devices, ions, H atoms, and H{sub 2} molecules collide with dust grains and exert stochastic torques which lead to small variations in angular momentum of the grain. By considering adsorption of the colliding particles, thermal desorption of H atoms and normal H{sub 2} molecules, and desorption of the recombined H{sub 2} molecules from the surface of an oblate spheroidal grain, we obtain diffusion coefficients of the Fokker-Planck equation for the distribution function of fluctuating angular momentum. Torque coefficients corresponding to the recombination mechanism show that the nonspherical dust grains may rotate with a suprathermal angular velocity.

  20. Evaluation of Pseudo-Static Coefficients According to Performance-Based Criteria

    SciTech Connect (OSTI)

    Biondi, Giovanni; Maugeri, Michele; Cascone, Ernesto

    2008-07-08

    A rational procedure is presented for the selection of the equivalent seismic coefficient to be introduced in the pseudo-static analysis of geotechnical systems which, at failure, behave as a 1-degree of freedom system. It is shown that although pseudo-static and displacement analyses may be regarded as alternative methods of analysis, the seismic coefficient may be related to earthquake-induced permanent displacements and, then, to the expected level of damage. Following the proposed procedure a pseudo-static analysis in accordance with performance based design can be carried out.

  1. Image analysis measurements of particle coefficient of restitution for coal gasification applications

    SciTech Connect (OSTI)

    Gibson, LaTosha M; Gopalan, Balaji; Pisupati, Sarma V; Shadle, Lawrence J

    2013-10-01

    New robust Lagrangian computational fluid dynamic (CFD) models are powerful tools that can be used to study the behavior of a diverse population of coal particle sizes, densities, and mineral compositions in entrained gasifiers. By using this approach, the responses of the particles impacting the wall were characterized over a range of velocities (1 to 8 m/s) and incident angles (90 to 20°). Within CFD models, the kinematic coefficient of restitution is the boundary condition defining the particle wall behavior. Four surfaces were studied to simulate the physical conditions of different entrained-flow gasification particle–surface collision scenarios: 1) a flat metal plate 2) a low viscosity silicon adhesive, 3) a high viscosity silicon adhesive, and 4) adhered particles on a flat metal plate with Young's modulus of elasticity ranging from 0.9 to 190 GPa. Entrained flow and drop experiments were conducted with granular coke particles, polyethylene beads and polystyrene pellets. The particle normal and tangential coefficients of restitution were measured using high speed imaging and particle tracking. The measured coefficients of restitution were observed to have a strong dependence on the rebound angles for most of the data. Suitable algebraic expressions for the normal and the tangential component of the coefficient of restitution were developed based upon ANOVA analysis. These expressions quantify the effect of normalized Young's modulus, particle equancy, and relative velocity on the coefficient of restitution. The coefficient of restitution did not have a strong dependence on the particle velocity over the range considered as long as the velocity was above the critical velocity. However, strong correlations were found between the degree of equancy of the particles and the mean coefficient of restitution such that the coefficient of restitution decreased for smaller particle equancies. It was concluded that the degree of equancy and the normalized Young

  2. Effect of carbon ion irradiation on Ag diffusion in SiC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Bin; Ko, Hyunseok; Gerczak, Tyler J.; Deng, Jie; Giordani, Andrew J.; Hunter, Jerry L.; Morgan, Dane; Szlufarska, Izabela; Sridharan, Kumar

    2015-11-14

    Transport of Ag fission product through the silicon-carbide (SiC) diffusion barrier layer in TRISO fuel particles is of considerable interest given the application of this fuel type in high temperature gas-cooled reactor (HTGR) and other future reactor concepts. The reactor experiments indicate that radiation may play an important role in release of Ag; however so far the isolated effect of radiation on Ag diffusion has not been investigated in controlled laboratory experiments. In this study, we investigate the diffusion couples of Ag and polycrystalline 3C–SiC, as well as Ag and single crystalline 4H–SiC samples before and after irradiation with C2+more » ions. The diffusion couple samples were exposed to temperatures of 1500 °C, 1535 °C, and 1569 °C, and the ensuing diffusion profiles were analyzed by secondary ion mass spectrometry (SIMS). We found that diffusion coefficients calculated from these measurements indicate that Ag diffusion was greatly enhanced by carbon irradiation due to a combined effect of radiation damage on diffusion and the presence of grain boundaries in polycrystalline SiC samples.« less

  3. Carbon-based tribofilms from lubricating oils | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon-based tribofilms from lubricating oils Title Carbon-based tribofilms from lubricating oils Publication Type Journal Article Year of Publication 2016 Authors Erdemir, A, Ramirez, G, Eryilmaz, O, Narayanan, B, Liao, Y, Kamath, G, Sankaranarayanan, SKRS Journal Nature Volume 536 Start Page 67 Pagination 5 Date Published 08/2016 Keywords mechanical engineering, mechanical properties, structural properties, synthesis and processing Abstract Moving mechanical interfaces are commonly lubricated

  4. 2016 Carbon Storage Project Portfolio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2016 Carbon Storage Project Portfolio Carbon Storage Project Portfolio Cover The 2016 Carbon Storage Project Portfolio provides a comprehensive overview of the NETL Carbon Storage Program's current and recently completed work. The portfolio includes division personnel contact information, technology area introductions, project communication products for projects active on or after 10/1/2016, papers and technical reports, best practices manuals, and access to all archived projects. Carbon Storage

  5. Iron-Doped Carbon Aerogels: Novel Porous Substrates for Direct Growth of Carbon Nanotubes

    SciTech Connect (OSTI)

    Steiner, S A; Baumann, T F; Kong, J; Satcher, J H; Dresselhaus, M S

    2007-02-15

    We present the synthesis and characterization of Fe-doped carbon aerogels (CAs) and demonstrate the ability to grow carbon nanotubes directly on monoliths of these materials to afford novel carbon aerogel-carbon nanotube composites. Preparation of the Fe-doped CAs begins with the sol-gel polymerization of the potassium salt of 2,4-dihydroxybenzoic acid with formaldehyde, affording K{sup +}-doped gels that can then be converted to Fe{sup 2+}- or Fe{sup 3+}-doped gels through an ion exchange process, dried with supercritical CO{sub 2} and subsequently carbonized under an inert atmosphere. Analysis of the Fe-doped CAs by TEM, XRD and XPS revealed that the doped iron species are reduced during carbonization to form metallic iron and iron carbide nanoparticles. The sizes and chemical composition of the reduced Fe species were related to pyrolysis temperature as well as the type of iron salt used in the ion exchange process. Raman spectroscopy and XRD analysis further reveal that, despite the presence of the Fe species, the CA framework is not significantly graphitized during pyrolysis. The Fe-doped CAs were subsequently placed in a thermal CVD reactor and exposed to a mixture of CH{sub 4} (1000 sccm), H{sub 2} (500 sccm), and C{sub 2}H{sub 4} (20 sccm) at temperatures ranging from 600 to 800 C for 10 minutes, resulting in direct growth of carbon nanotubes on the aerogel monoliths. Carbon nanotubes grown by this method appear to be multiwalled ({approx}25 nm in diameter and up to 4 mm long) and grow through a tip-growth mechanism that pushes catalytic iron particles out of the aerogel framework. The highest yield of CNTs were grown on Fe-doped CAs pyrolyzed at 800 C treated at CVD temperatures of 700 C.

  6. Iron-Doped Carbon Aerogels: Novel Porous Substrates for Direct Growth of Carbon Nanotubes

    DOE R&D Accomplishments [OSTI]

    Steiner, S. A.; Baumann, T. F.; Kong, J.; Satcher, J. H.; Dresselhaus, M. S.

    2007-02-20

    We present the synthesis and characterization of Fe-doped carbon aerogels (CAs) and demonstrate the ability to grow carbon nanotubes directly on monoliths of these materials to afford novel carbon aerogel-carbon nanotube composites. Preparation of the Fe-doped CAs begins with the sol-gel polymerization of the potassium salt of 2,4-dihydroxybenzoic acid with formaldehyde, affording K{sup +}-doped gels that can then be converted to Fe{sup 2+}- or Fe{sup 3+}-doped gels through an ion exchange process, dried with supercritical CO{sub 2} and subsequently carbonized under an inert atmosphere. Analysis of the Fe-doped CAs by TEM, XRD and XPS revealed that the doped iron species are reduced during carbonization to form metallic iron and iron carbide nanoparticles. The sizes and chemical composition of the reduced Fe species were related to pyrolysis temperature as well as the type of iron salt used in the ion exchange process. Raman spectroscopy and XRD analysis further reveal that, despite the presence of the Fe species, the CA framework is not significantly graphitized during pyrolysis. The Fe-doped CAs were subsequently placed in a thermal CVD reactor and exposed to a mixture of CH{sub 4} (1000 sccm), H{sub 2} (500 sccm), and C{sub 2}H{sub 4} (20 sccm) at temperatures ranging from 600 to 800 C for 10 minutes, resulting in direct growth of carbon nanotubes on the aerogel monoliths. Carbon nanotubes grown by this method appear to be multiwalled ({approx}25 nm in diameter and up to 4 mm long) and grow through a tip-growth mechanism that pushes catalytic iron particles out of the aerogel framework. The highest yield of CNTs were grown on Fe-doped CAs pyrolyzed at 800 C treated at CVD temperatures of 700 C.

  7. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2005-01-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I fall into four areas: evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; development of GIS-based reporting framework that links with national networks; designing an integrated suite of monitoring, measuring, and verification technologies and assessment frameworks; and initiating a comprehensive education and outreach program. The groundwork is in place to provide an assessment of storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. Efforts are underway to showcase the architecture of the GIS framework and initial results for sources and sinks. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is

  8. WESTCARB Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The West Coast Regional Carbon Sequestration Partnership (known as WESTCARB) was established in Fall 2003. It is one of seven research partnerships co-funded by DOE to characterize regional carbon sequestration opportunities and conduct pilot-scale validation tests. The California Energy Commission manages WESTCARB and is a major co-funder. WESTCARB is characterizing the extent and capacity of geologic formations capable of storing CO2, known as sinks. Results are entered into a geographic information system (GIS) database, along with the location of major CO2-emitting point sources in each of the six WESTCARB states, enabling researchers and the public to gauge the proximity of candidate CO2 storage sites to emission sources and the feasibility of linking them via pipelines. Specifically, the WESTCARB GIS database (also known as the carbon atlas) stores layers of geologic information about potential underground storage sites, such as porosity and nearby fault-lines and aquifers. Researchers use these data, along with interpreted geophysical data and available oil and gas well logs to estimate the region's potential geologic storage capacity. The database also depicts existing pipeline routes and rights-of-way and lands that could be off-limits, which can aid the development of a regional carbon management strategy. The WESTCARB Carbon Atlas, which is accessible to the public, provides a resource for public discourse on practical solutions for regional CO2 management. A key WESTCARB partner, the Utah Automated Geographic Reference Center, has developed data serving procedures to enable the WESTCARB Carbon Atlas to be integrated with those from other regional partnerships, thereby supporting the U.S. Department of Energy's national carbon atlas, NATCARB

  9. Measurement of carbon capture efficiency and stored carbon leakage

    DOE Patents [OSTI]

    Keeling, Ralph F.; Dubey, Manvendra K.

    2013-01-29

    Data representative of a measured carbon dioxide (CO.sub.2) concentration and of a measured oxygen (O.sub.2) concentration at a measurement location can be used to determine whether the measured carbon dioxide concentration at the measurement location is elevated relative to a baseline carbon dioxide concentration due to escape of carbon dioxide from a source associated with a carbon capture and storage process. Optionally, the data can be used to quantify a carbon dioxide concentration increase at the first location that is attributable to escape of carbon dioxide from the source and to calculate a rate of escape of carbon dioxide from the source by executing a model of gas-phase transport using at least the first carbon dioxide concentration increase. Related systems, methods, and articles of manufacture are also described.

  10. ATMOSPHERIC DISPERSION COEFFICIENTS AND RADIOLOGICAL AND TOXICOLOGICAL EXPOSURE METHODOLOGY FOR USE IN TANK FARMS

    SciTech Connect (OSTI)

    GRIGSBY KM

    2011-04-07

    This report presents the atmospheric dispersion coefficients used in Tank Farms safety analysis. The basis equations for calculating radiological and toxicological exposures are also included. In this revision, the time averaging for toxicological consequence evaluations is clarified based on a review of DOE complex guidance and a review of tank farm chemicals.

  11. FIELD-SCALE EFFECTIVE MATRIX DIFFUSION COEFFICIENT FOR FRACTURED ROCK:RESULTS FROM LITERATURE SURVEY

    SciTech Connect (OSTI)

    Q. Zhou; Hui-Hai Liu; F.J. Molz; Y. Zhang; G.S. Bodvarsson

    2005-04-08

    Matrix diffusion is an important mechanism for solute transport in fractured rock. We recently conducted a literature survey on the effective matrix diffusion coefficient, D{sub m}{sup e}, a key parameter for describing matrix diffusion processes at the field scale. Forty field tracer tests at 15 fractured geologic sites were surveyed and selected for the study, based on data availability and quality. Field-scale D{sub m}{sup e} values were calculated, either directly using data reported in the literature or by reanalyzing the corresponding field tracer tests. Surveyed data indicate that the effective-matrix-diffusion-coefficient factor F{sub D} (defined as the ratio of D{sub m}{sup e} to the lab-scale matrix diffusion coefficient [D{sub m}] of the same tracer) is generally larger than one, indicating that the effective matrix diffusion coefficient in the field is comparatively larger than the matrix diffusion coefficient at the rock-core scale. This larger value can be attributed to the many mass-transfer processes at different scales in naturally heterogeneous, fractured rock systems. Furthermore, we observed a moderate trend toward systematic increase in the F{sub D} value with observation scale, indicating that the effective matrix diffusion coefficient is likely to be statistically scale dependent. The F{sub D} value ranges from 1 to 10,000 for observation scales from 5 to 2,000 m. At a given scale, the F{sub D} value varies by two orders of magnitude, reflecting the influence of differing degrees of fractured rock heterogeneity at different sites. In addition, the surveyed data indicate that field-scale longitudinal dispersivity generally increases with observation scale, which is consistent with previous studies. The scale-dependent field-scale matrix diffusion coefficient (and dispersivity) may have significant implications for assessing long-term, large-scale radionuclide and contaminant transport events in fractured rock, both for nuclear waste disposal

  12. Big Sky Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Big Sky Carbon Atlas is an online geoportal designed for you to discover, interpret, and access geospatial data and maps relevant to decision support and education on carbon sequestration in the Big Sky Region. In serving as the public face of the Partnership's spatial Data Libraries, the Atlas provides a gateway to geographic information characterizing CO2 sources, potential geologic sinks, terrestrial carbon fluxes, civil and energy infrastructure, energy use, and related themes. In addition to directly serving the BSCSP and its stakeholders, the Atlas feeds regional data to the NatCarb Portal, contributing to a national perspective on carbon sequestration. Established components of the Atlas include a gallery of thematic maps and an interactive map that allows you to: • Navigate and explore regional characterization data through a user-friendly interface • Print your map views or publish them as PDFs • Identify technical references relevant to specific areas of interest • Calculate straight-line or pipeline-constrained distances from point sources of CO2 to potential geologic sink features • Download regional data layers (feature under development) (Acknowledgment to the Big Sky Carbon Sequestration Partnership (BSCSP); see home page at http://www.bigskyco2.org/)

  13. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott J; Alvizo, Oscar

    2013-10-29

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  14. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  15. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2011-08-16

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  16. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2008-10-21

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  17. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-01-24

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  18. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott; Alvizo, Oscar

    2013-01-15

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  19. Field-Scale Effective Matrix Diffusion Coefficient for FracturedRock: Results From Literature Survey

    SciTech Connect (OSTI)

    Zhou, Quanlin; Liu, Hui Hai; Molz, Fred J.; Zhang, Yingqi; Bodvarsson, Gudmundur S.

    2005-03-28

    Matrix diffusion is an important mechanism for solutetransport in fractured rock. We recently conducted a literature survey onthe effective matrix diffusion coefficient, Dem, a key parameter fordescribing matrix diffusion processes at the field scale. Forty fieldtracer tests at 15 fractured geologic sites were surveyed and selectedfor study, based on data availability and quality. Field-scale Dem valueswere calculated, either directly using data reported in the literature orby reanalyzing the corresponding field tracer tests. Surveyed dataindicate that the effective-matrix-diffusion-coefficient factor FD(defined as the ratio of Dem to the lab-scale matrix diffusioncoefficient [Dem]of the same tracer) is generally larger than one,indicating that the effective matrix diffusion coefficient in the fieldis comparatively larger than the matrix diffusion coefficient at therock-core scale. This larger value could be attributed to the manymass-transfer processes at different scales in naturally heterogeneous,fractured rock systems. Furthermore, we observed a moderate trend towardsystematic increase in the emDFmDDF value with observation scale,indicating that the effective matrix diffusion coefficient is likely tobe statistically scale dependent. The FD value ranges from 1 to 10,000for observation scales from 5 to 2,000 m. At a given scale, the FD valuevaries by two orders of magnitude, reflecting the influence of differingdegrees of fractured rock heterogeneity at different sites. In addition,the surveyed data indicate that field-scale longitudinal dispersivitygenerally increases with observation scale, which is consistent withprevious studies. The scale-dependent field-scale matrix diffusioncoefficient (and dispersivity) may have significant implications forassessing long-term, large-scale radionuclide and contaminant transportevents in fractured rock, both for nuclear waste disposal and contaminantremediation.

  20. Types of Reuse

    Broader source: Energy.gov [DOE]

    The following provides greater detail regarding the types of reuse pursued for LM sites. It should be noted that many actual reuses combine several types of the uses listed below.

  1. Big Sky Carbon Sequestration Partnership

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2005-11-01

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I fall into four areas: evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; development of GIS-based reporting framework that links with national networks; designing an integrated suite of monitoring, measuring, and verification technologies and assessment frameworks; and initiating a comprehensive education and outreach program. The groundwork is in place to provide an assessment of storage capabilities for CO2 utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research agenda in Carbon Sequestration. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other DOE regional partnerships. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the

  2. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-10-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. During the third quarter, planning efforts are underway for the next Partnership meeting which will showcase the architecture of the GIS framework and initial results for sources and sinks, discuss the methods and analysis underway for assessing geological and terrestrial sequestration potentials. The meeting will conclude with an ASME workshop. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification

  3. Types of Radiation Exposure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    External Irradiation Contamination Incorporation Biological Effects of Acute, Total Body Irradiation Managing Radiation Emergencies Procedure Demonstration Types of radiation ...

  4. Implications of Carbon Regulation for Green Power Markets

    SciTech Connect (OSTI)

    Bird, Lori; Holt, Ed; Carroll, Ghita

    2007-04-01

    This paper examines the potential effects that emerging mandatory carbon markets have for voluntary markets for renewable energy, or green power markets. In an era of carbon regulation, green power markets will continue to play an important role because many consumers may be interested in supporting renewable energy development beyond what is supported through mandates or other types of policy support. The paper examines the extent to which GHG benefits motivate consumers to make voluntary renewable energy purchases and summarizes key issues emerging as a result of these overlapping markets, such as the implications of carbon regulation for renewable energy marketing claims, the demand for and price of renewable energy certificates (RECs), and the use of RECs in multiple markets (disaggregation of attributes). It describes carbon regulation programs under development in the Northeast and California, and how these might affect renewable energy markets in these regions, as well as the potential interaction between voluntary renewable energy markets and voluntary carbon markets, such as the Chicago Climate Exchange (CCX). It also briefly summarizes the experience in the European Union, where carbon is already regulated. Finally, the paper presents policy options for policymakers and regulators to consider in designing carbon policies to enable carbon markets and voluntary renewable energy markets to work together.

  5. A Semi-Empirical Two Step Carbon Corrosion Reaction Model in PEM Fuel Cells

    SciTech Connect (OSTI)

    Young, Alan; Colbow, Vesna; Harvey, David; Rogers, Erin; Wessel, Silvia

    2013-01-01

    The cathode CL of a polymer electrolyte membrane fuel cell (PEMFC) was exposed to high potentials, 1.0 to 1.4 V versus a reversible hydrogen electrode (RHE), that are typically encountered during start up/shut down operation. While both platinum dissolution and carbon corrosion occurred, the carbon corrosion effects were isolated and modeled. The presented model separates the carbon corrosion process into two reaction steps; (1) oxidation of the carbon surface to carbon-oxygen groups, and (2) further corrosion of the oxidized surface to carbon dioxide/monoxide. To oxidize and corrode the cathode catalyst carbon support, the CL was subjected to an accelerated stress test cycled the potential from 0.6 VRHE to an upper potential limit (UPL) ranging from 0.9 to 1.4 VRHE at varying dwell times. The reaction rate constants and specific capacitances of carbon and platinum were fitted by evaluating the double layer capacitance (Cdl) trends. Carbon surface oxidation increased the Cdl due to increased specific capacitance for carbon surfaces with carbon-oxygen groups, while the second corrosion reaction decreased the Cdl due to loss of the overall carbon surface area. The first oxidation step differed between carbon types, while both reaction rate constants were found to have a dependency on UPL, temperature, and gas relative humidity.

  6. Letter to the Editor: Appropriate selection of dose coefficients in radiological assessments: C-14 and Cl-36: response to the letter of G Smith and M Thorne (2015 J. Radiol. Prot. 35 737-40)

    SciTech Connect (OSTI)

    Harrison, John D.; Leggett, Richard Wayne

    2016-01-01

    This letter to the editor of Journal of Radiological Protection is in response to a letter to the editor from G. M. Smith and M. C. Thorne of Great Britain concerning the appropriate selection of dose coefficients for ingested carbon-14 and chlorine-36, two of the most important long-lived components of radioactive wastes. Smith and Thorne argue that current biokinetic models of the International Commission on Radiological Protection (ICRP) for carbon and chlorine are overly cautious models from the standpoint of radiation dose estimates for C-14 and Cl-36, and that more realistic models are needed for evaluation of the hazards of these radionuclides in nuclear wastes. We (Harrison and Leggett) point out that new biokinetic models for these and other elements (developed at ORNL) will soon appear in ICRP Publications. These new models generally are considerably more realistic than current ICRP models. Here, examples are given for C-14 inhaled as carbon dioxide or ingested in water as bicarbonate, carbonate, or carbon dioxide.

  7. Letter to the Editor: Appropriate selection of dose coefficients in radiological assessments: C-14 and Cl-36: response to the letter of G Smith and M Thorne (2015 J. Radiol. Prot. 35 737-40)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harrison, John D.; Leggett, Richard Wayne

    2016-01-01

    This letter to the editor of Journal of Radiological Protection is in response to a letter to the editor from G. M. Smith and M. C. Thorne of Great Britain concerning the appropriate selection of dose coefficients for ingested carbon-14 and chlorine-36, two of the most important long-lived components of radioactive wastes. Smith and Thorne argue that current biokinetic models of the International Commission on Radiological Protection (ICRP) for carbon and chlorine are overly cautious models from the standpoint of radiation dose estimates for C-14 and Cl-36, and that more realistic models are needed for evaluation of the hazards ofmore » these radionuclides in nuclear wastes. We (Harrison and Leggett) point out that new biokinetic models for these and other elements (developed at ORNL) will soon appear in ICRP Publications. These new models generally are considerably more realistic than current ICRP models. Here, examples are given for C-14 inhaled as carbon dioxide or ingested in water as bicarbonate, carbonate, or carbon dioxide.« less

  8. Postdoc Appointment Types

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Appointment Types Postdoc Appointment Types Most postdocs will be offered a postdoctoral research associate appointment. Each year, approximately 30 Postdoctoral Fellow appointments, including the Distinguished Fellows, are awarded. Postdoc appointment types offer world of possibilities Meet the current LANL Distinguished Postdocs Research Associates Research Associates pursue research as part of ongoing LANL science and engineering programs. Sponsored postdoctoral candidate packages are

  9. Carbon-particle generator

    DOE Patents [OSTI]

    Hunt, A.J.

    1982-09-29

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  10. HOLLOW CARBON ARC DISCHARGE

    DOE Patents [OSTI]

    Luce, J.S.

    1960-10-11

    A device is described for producing an energetic, direct current, hollow, carbon-arc discharge in an evacuated container and within a strong magnetic field. Such discharges are particularly useful not only in dissociation and ionization of high energy molecular ion beams, but also in acting as a shield or barrier against the instreaming of lowenergy neutral particles into a plasma formed within the hollow discharge when it is used as a dissociating mechanism for forming the plasma. There is maintained a predetermined ratio of gas particles to carbon particles released from the arc electrodes during operation of the discharge. The carbon particles absorb some of the gas particles and are pumped along and by the discharge out of the device, with the result that smaller diffusion pumps are required than would otherwise be necessary to dispose of the excess gas.

  11. Carbon Capture and Storage

    SciTech Connect (OSTI)

    Friedmann, S

    2007-10-03

    Carbon capture and sequestration (CCS) is the long-term isolation of carbon dioxide from the atmosphere through physical, chemical, biological, or engineered processes. This includes a range of approaches including soil carbon sequestration (e.g., through no-till farming), terrestrial biomass sequestration (e.g., through planting forests), direct ocean injection of CO{sub 2} either onto the deep seafloor or into the intermediate depths, injection into deep geological formations, or even direct conversion of CO{sub 2} to carbonate minerals. Some of these approaches are considered geoengineering (see the appropriate chapter herein). All are considered in the 2005 special report by the Intergovernmental Panel on Climate Change (IPCC 2005). Of the range of options available, geological carbon sequestration (GCS) appears to be the most actionable and economic option for major greenhouse gas reduction in the next 10-30 years. The basis for this interest includes several factors: (1) The potential capacities are large based on initial estimates. Formal estimates for global storage potential vary substantially, but are likely to be between 800 and 3300 Gt of C (3000 and 10,000 Gt of CO{sub 2}), with significant capacity located reasonably near large point sources of the CO{sub 2}. (2) GCS can begin operations with demonstrated technology. Carbon dioxide has been separated from large point sources for nearly 100 years, and has been injected underground for over 30 years (below). (3) Testing of GCS at intermediate scale is feasible. In the US, Canada, and many industrial countries, large CO{sub 2} sources like power plants and refineries lie near prospective storage sites. These plants could be retrofit today and injection begun (while bearing in mind scientific uncertainties and unknowns). Indeed, some have, and three projects described here provide a great deal of information on the operational needs and field implementation of CCS. Part of this interest comes from several

  12. The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries

    SciTech Connect (OSTI)

    Bhadra, S; Hertzberg, BJ; Hsieh, AG; Croft, M; Gallaway, JW; Van Tassell, BJ; Chamoun, M; Erdonmez, C; Zhong, Z; Sholklapper, T; Steingart, DA

    2015-01-01

    The coefficient of restitution of alkaline batteries has been shown to increase as a function of depth of discharge. In this work, using non-destructive mechanical testing, the change in coefficient of restitution is compared to in situ energy-dispersive X-ray diffraction data to determine the cause of the macroscopic change in coefficient of restitution. The increase in coefficient of restitution correlates to the formation of a percolation pathway of ZnO within the anode of the cell, and the coefficient of restitution levels off at a value of 0.66 +/- 0.02 at 50% state of charge when the anode has densified into porous ZnO solid. Of note is the sensitivity of coefficient of restitution to the amount of ZnO formation that rivals the sensitivity of in situ energy-dispersive X-ray diffraction.

  13. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus; Yanagihara, Naohisa; Dyke, James T.; Vemulapalli, Krishna

    1991-09-03

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  14. CarbonMicro | Open Energy Information

    Open Energy Info (EERE)

    Place: Irvine, California Zip: CA 92618 Sector: Carbon Product: Carbon Micro Battery Corporation has a unique technology of creating micro and nanoscale carbon...

  15. Carbon Micro Battery LLC | Open Energy Information

    Open Energy Info (EERE)

    Micro Battery LLC Jump to: navigation, search Name: Carbon Micro Battery, LLC Place: California Sector: Carbon Product: Carbon Micro Battery, LLC, technology developer of micro and...

  16. Carbon Solutions Group | Open Energy Information

    Open Energy Info (EERE)

    Solutions Group Jump to: navigation, search Name: Carbon Solutions Group Place: Chicago, Illinois Zip: 60601 Sector: Carbon Product: Carbon Solutions Group collaborates with...

  17. Thermal Management Using Carbon Nanotubes - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Management Using Carbon Nanotubes Oak Ridge National Laboratory Contact ORNL About This Technology Vertically Aligned Carbon Nanotubes Vertically Aligned Carbon Nanotubes...

  18. Participatory Carbon Monitoring: Operational Guidance for National...

    Open Energy Info (EERE)

    Participatory Carbon Monitoring: Operational Guidance for National REDD+ Carbon Accounting Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Participatory Carbon...

  19. Arreon Carbon Ltd | Open Energy Information

    Open Energy Info (EERE)

    Arreon Carbon Ltd Jump to: navigation, search Name: Arreon Carbon Ltd Place: Beijing, Beijing Municipality, China Zip: 100022 Sector: Carbon Product: Beijing-based firm that...

  20. GS Carbon Corporation | Open Energy Information

    Open Energy Info (EERE)

    Carbon Corporation Jump to: navigation, search Name: GS Carbon Corporation Place: New York, New York Zip: 10119 Sector: Carbon Product: The company offsets emissions output with...

  1. Carbon Market Brasil Consulting | Open Energy Information

    Open Energy Info (EERE)

    Market Brasil Consulting Jump to: navigation, search Name: Carbon Market Brasil Consulting Place: Sao Paulo, Brazil Zip: 04120-070 Sector: Carbon Product: Brazil-based carbon...

  2. Universal Carbon Credits Limited | Open Energy Information

    Open Energy Info (EERE)

    Universal Carbon Credits Limited Jump to: navigation, search Name: Universal Carbon Credits Limited Place: London, England, United Kingdom Zip: EC3A6DF Sector: Carbon Product:...

  3. Carbon Trust Enterprises Limited | Open Energy Information

    Open Energy Info (EERE)

    Enterprises Limited Jump to: navigation, search Name: Carbon Trust Enterprises Limited Place: London, United Kingdom Zip: WC2A 2AZ Sector: Carbon Product: Carbon Trust Enterprises...

  4. Equinox Carbon Equities LLC | Open Energy Information

    Open Energy Info (EERE)

    Equinox Carbon Equities LLC Jump to: navigation, search Name: Equinox Carbon Equities, LLC Place: Newport Beach, California Zip: 92660 Sector: Carbon Product: Investment firm...

  5. The Social Carbon Company | Open Energy Information

    Open Energy Info (EERE)

    Social Carbon Company Jump to: navigation, search Name: The Social Carbon Company Place: Brasilia, Distrito Federal (Brasilia), Brazil Zip: CEP 70610-440 Sector: Carbon, Services...

  6. Carbon Credit Capital | Open Energy Information

    Open Energy Info (EERE)

    Capital Jump to: navigation, search Name: Carbon Credit Capital Place: New York, New York Zip: 10012 Sector: Carbon, Services Product: Project Advisory Services and Carbon...

  7. The Global Carbon Bank | Open Energy Information

    Open Energy Info (EERE)

    Global Carbon Bank Jump to: navigation, search Name: The Global Carbon Bank Place: Houston, Texas Zip: 77025 Sector: Carbon, Services Product: Houston-based provider of advisory...

  8. RESTORING SUSTAINABLE FORESTS ON APPALACHIAN MINED LANDS FOR WOOD PRODUCTS, RENEWABLE ENERGY, CARBON SEQUESTRATION, AND OTHER ECOSYSTEM SERVICES

    SciTech Connect (OSTI)

    J. Burger; J. Galbraith; T. Fox; G. Amacher; J. Sullivan; C. Zipper

    2003-12-18

    The overall purpose of this project is to evaluate the biological and economic feasibility of restoring high-quality forests on mined land, and to measure carbon sequestration and wood production benefits that would be achieved from forest restoration procedures. In this quarterly report, we present a preliminary comparison of the carbon sequestration benefits for two forest types used to convert abandoned grasslands for carbon sequestration. Annual mixed hardwood benefits, based on total stand carbon volume present at the end of a given year, range from a minimum of $0/ton of carbon to a maximum of $5.26/ton of carbon (low prices). White pine benefits based on carbon volume range from a minimum of $0/ton of carbon to a maximum of $18.61/ton of carbon (high prices). The higher maximum white pine carbon payment can primarily be attributed to the fact that the shorter rotation means that payments for white pine carbon are being made on far less cumulative carbon tonnage than for that of the long-rotation hardwoods. Therefore, the payment per ton of white pine carbon needs to be higher than that of the hardwoods in order to render the conversion to white pine profitable by the end of a rotation. These carbon payments may seem appealingly low to the incentive provider. However, payments (not discounted) made over a full rotation may add up to approximately $17,493/ha for white pine (30-year rotation), and $18,820/ha for mixed hardwoods (60-year rotation). The literature suggests a range of carbon sequestration costs, from $0/ton of carbon to $120/ton of carbon, although the majority of studies suggest a cost below $50/ ton of carbon, with van Kooten et al. (2000) suggesting a cutoff cost of $20/ton of carbon sequestered. Thus, the ranges of carbon payments estimated for this study fall well within the ranges of carbon sequestration costs estimated in previous studies.

  9. Method for production of carbon nanofiber mat or carbon paper

    SciTech Connect (OSTI)

    Naskar, Amit K.

    2015-08-04

    Method for the preparation of a non-woven mat or paper made of carbon fibers, the method comprising carbonizing a non-woven mat or paper preform (precursor) comprised of a plurality of bonded sulfonated polyolefin fibers to produce said non-woven mat or paper made of carbon fibers. The preforms and resulting non-woven mat or paper made of carbon fiber, as well as articles and devices containing them, and methods for their use, are also described.

  10. Friction of partially embedded vertically aligned carbon nanofibers inside elastomers

    SciTech Connect (OSTI)

    Aksak, Burak; Sitti, Metin; Cassell, Alan; Li, Jun; Meyyappan, Meyya; Callen, Phillip [NanoRobotics Laboratory, Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States); NASA Ames Research Center, Moffett Field, California 94035 (United States); NASA Johnson Space Center, Houston, Texas 77058 (United States)

    2007-08-06

    Vertically aligned carbon nanofibers partially embedded inside polyurethane (eVACNFs) are proposed as a robust high friction fibrillar material with a compliant backing. Carbon nanofibers with 50-150 nm in diameter and 20-30 {mu}m in length are vertically grown on silicon and transferred completely inside an elastomer by vacuum molding. By using time controlled and selective oxygen plasma etching, fibers are partially released up to 5 {mu}m length. Macroscale friction experiments show that eVACNFs exhibit reproducible effective friction coefficients up to 1. Besides high friction, the proposed fabrication method improves fiber-substrate bond strength, and enables uniform height nanofibers with a compliant backing.

  11. Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration

    SciTech Connect (OSTI)

    Teng, H. Henry; Xu, Huifang

    2013-07-17

    We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and dolomite) cannot be formed at ambient conditions from a new perspective by exploring the formation of MgCO{sub 3} and Mg{sub x}Ca{sub (1-x)}CO{sub 3} in non-aqueous solutions. Data collected from our experiments in this funding period suggest that a fundamental barrier, other than cation hydration, exists that prevents Mg{sup 2+} and CO{sub 3}{sup 2-} ions from forming long-range ordered structures. We propose that this barrier mainly stems from the lattice limitation on the spatial configuration of CO{sub 3} groups in magnesite crystals. On the other hand, the measured higher distribution coefficients of Mg between magnesian calcites formed in the absence and presence of water give us a first direct proof to support and quantify the cation hydration effect.

  12. Neutralizing Carbonic Acid in Deep Carbonate Strata below the North Atlantic

    SciTech Connect (OSTI)

    Daniel P. Schrag

    2005-12-01

    Our research is aimed at investigating several technical issues associated with carbon dioxide sequestration in calcium carbonate sediments below the sea floor through laboratory experiments and chemical transport modeling. Our goal is to evaluate the basic feasibility of this approach, including an assessment of optimal depths, sediment types, and other issues related to site selection. Through laboratory and modeling efforts, we are studying the flow of liquid carbon dioxide and carbon dioxide-water mixtures through calcium carbonate sediments to better understand the geomechanical and structural stability of the sediments during and after injection. Our modeling efforts in the first year show that the idea is feasible, but requires more sophisticated analysis of fluid flow at high pressure in deep sea sediments. In addition, we are investigating the kinetics of calcium carbonate dissolution in the presence of CO{sub 2}-water fluids, which is a critical feature of the system as it allows for increased permeability during injection. Our experimental results from the first year of work have shown that the kinetics are likely to be fast enough to create dissolution which will affect permeability. However, additional experiments are needed at high pressures, which will be a focus for years 2 and 3. We are also investigating the possibility of carbon dioxide hydrate formation in the pore fluid, which might complicate the injection procedure by reducing sediment permeability but might also provide an upper seal in the sediment-pore fluid system, preventing release of CO{sub 2} into the deep ocean, particularly if depth and temperature at the injection point rule out immediate hydrate formation. Finally, we are in the beginning stages of an economic analysis to estimate costs of drilling and gas injection, site monitoring as well as the availability of potential disposal sites with particular emphasis on those sites that are within the 200-mile economic zone of the

  13. Particles of spilled oil-absorbing carbon in contact with water

    DOE Patents [OSTI]

    Muradov, Nazim

    2011-03-29

    Hydrogen generator coupled to or integrated with a fuel cell for portable power applications. Hydrogen is produced via thermocatalytic decomposition (cracking, pyrolysis) of hydrocarbon fuels in oxidant-free environment. The apparatus can utilize a variety of hydrocarbon fuels, including natural gas, propane, gasoline, kerosene, diesel fuel, crude oil (including sulfurous fuels). The hydrogen-rich gas produced is free of carbon oxides or other reactive impurities, so it could be directly fed to any type of a fuel cell. The catalysts for hydrogen production in the apparatus are carbon-based or metal-based materials and doped, if necessary, with a sulfur-capturing agent. Additionally disclosed are two novel processes for the production of two types of carbon filaments, and a novel filamentous carbon product. Carbon particles with surface filaments having a hydrophobic property of oil film absorption, compositions of matter containing those particles, and a system for using the carbon particles for cleaning oil spills.

  14. Carbon smackdown: wind warriors

    ScienceCinema (OSTI)

    Glen Dahlbacka of the Accelerator & Fusion Research Division and Ryan Wiser of the Environmental Energy Technologies Division are the speakers.

    2010-09-01

    July 16. 2010 carbon smackdown summer lecture: learn how Berkeley Lab scientists are developing wind turbines to be used in an urban setting, as well as analyzing what it will take to increase the adoption of wind energy in the U.S.

  15. Carbon cloth supported electrode

    DOE Patents [OSTI]

    Lu, Wen-Tong P. (Upper St. Clair, PA); Ammon, Robert L. (Baldwin both of, PA)

    1982-01-01

    A flow-by anode is disclosed made by preparing a liquid suspension of about to about 18% by weight solids, the solids comprising about 3.5 to about 8% of a powdered catalyst of platinum, palladium, palladium oxide, or mixtures thereof; about 60 to about 76% carbon powder (support) having a particle size less than about 20 m.mu.m and about 20 to about 33% of an inert binder having a particle size of less than about 500 m.mu.m. A sufficient amount of the suspension is poured over a carbon cloth to form a layer of solids about 0.01 to about 0.05 cm thick on the carbon cloth when the electrode is completed. A vacuum was applied to the opposite side of the carbon cloth to remove the liquid and the catalyst layer/cloth assembly is dried and compressed at about 10 to about 50 MPa's. The binder is then sintered in an inert atmosphere to complete the electrode. The electrode is used for the oxidation of sulfur dioxide in a sulfur based hybrid cycle for the decomposition of water.

  16. Carbon-Fuelled Future

    SciTech Connect (OSTI)

    Appel, Aaron M.

    2014-09-12

    Whether due to changes in policy or consumption of available fossil fuels, alternative sources of energy will be required, especially given the rising global energy demand. However, one of the main factors limiting the widespread utilization of renewable energy, such as wind, solar, wave or geothermal, is our ability to store energy. Storage of energy from carbon-neutral sources, such as electricity from solar or wind, can be accomplished through many routes. One approach is to store energy in the form of chemical bonds, as fuels. The conversion of low-energy compounds, such as water and carbon dioxide, to higher energy molecules, such as hydrogen or carbon-based fuels, enables the storage of carbon-neutral energy on a very large scale. The author¹s work in this area is supported by the US Department of Energy Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  17. Carbon Footprint Calculator

    Broader source: Energy.gov [DOE]

    This calculator estimates the amount of carbon emissions you and members of your household are responsible for. It does not include emissions associated with your work or getting to work if you commute by public transportation. It was developed by IEEE Spectrum magazine.

  18. Method for passively compensating for temperature coefficient of gain in silicon photomultipliers and similar devices

    SciTech Connect (OSTI)

    McKisson, John E.; Barbosa, Fernando

    2015-09-01

    A method for designing a completely passive bias compensation circuit to stabilize the gain of multiple pixel avalanche photo detector devices. The method includes determining circuitry design and component values to achieve a desired precision of gain stability. The method can be used with any temperature sensitive device with a nominally linear coefficient of voltage dependent parameter that must be stabilized. The circuitry design includes a negative temperature coefficient resistor in thermal contact with the photomultiplier device to provide a varying resistance and a second fixed resistor to form a voltage divider that can be chosen to set the desired slope and intercept for the characteristic with a specific voltage source value. The addition of a third resistor to the divider network provides a solution set for a set of SiPM devices that requires only a single stabilized voltage source value.

  19. Dynamic equilibria and magnetohydrodynamic instabilities in toroidal plasmas with non-uniform transport coefficients

    SciTech Connect (OSTI)

    Futatani, Shimpei; Bos, Wouter J. T.; Morales, Jorge A.

    2015-05-15

    It can be shown that in the presence of a toroidal magnetic field induced by poloidal coils, combined with the electromagnetic field induced by a central solenoid, no static equilibrium is possible within the MHD description, as soon as non-zero resistivity is assumed. The resulting dynamic equilibrium was previously discussed for the case of spatially homogeneous resisitivity. In the present work, it is shown how a spatial inhomogeneity of the viscosity and resisitivity coefficients influences this equilibrium. Parameters in both the stable, tokamak-like regime and unstable, reversed field pinch-like regime are considered. It is shown that, whereas the magnitudes of the velocity and magnetic field fluctuations are strongly modified by the spatial variation of the transport coefficients, the qualitative flow behaviour remains largely unaffected.

  20. Temperature coefficients for GaInP/GaAs/GaInNAsSb solar cells

    SciTech Connect (OSTI)

    Aho, Arto; Isoaho, Riku; Tukiainen, Antti; Polojärvi, Ville; Aho, Timo; Raappana, Marianna; Guina, Mircea

    2015-09-28

    We report the temperature coefficients for MBE-grown GaInP/GaAs/GaInNAsSb multijunction solar cells and the corresponding single junction sub-cells. Temperature-dependent current-voltage measurements were carried out using a solar simulator equipped with a 1000 W Xenon lamp and a three-band AM1.5D simulator. The triple-junction cell exhibited an efficiency of 31% at AM1.5G illumination and an efficiency of 37–39% at 70x real sun concentration. The external quantum efficiency was also measured at different temperatures. The temperature coefficients up to 80°C, for the open circuit voltage, the short circuit current density, and the conversion efficiency were determined to be −7.5 mV/°C, 0.040 mA/cm{sup 2}/°C, and −0.09%/°C, respectively.

  1. On a regularization of a scalar conservation law with discontinuous coefficients

    SciTech Connect (OSTI)

    Shen, Chun

    2014-03-15

    This paper is devoted to a scalar conservation law with a linear flux function involving discontinuous coefficients. It is clear that the delta standing wave should be introduced into the Riemann solution in some nonclassical situation. In order to study the formation of delta standing wave, we consider a regularization of the discontinuous coefficient with the Helmholtz mollifier and then obtain a regularized system which depends on a regularization parameter ε > 0. The regularization mechanism is a nonlinear bending of characteristic curves that prevents their finite-time intersection. It is proved rigorously that the solutions of regularized system converge to the delta standing wave solution in the ε → 0 limit. Compared with the classical method of vanishing viscosity, here it is clear to see how the delta standing wave forms naturally along the characteristics.

  2. Three-body interactions in complex fluids: Virial coefficients from simulation finite-size effects

    SciTech Connect (OSTI)

    Ashton, Douglas J.; Wilding, Nigel B.

    2014-06-28

    A simulation technique is described for quantifying the contribution of three-body interactions to the thermodynamical properties of coarse-grained representations of complex fluids. The method is based on a new approach for determining virial coefficients from the measured volume-dependent asymptote of a certain structural function. By comparing the third virial coefficient B{sub 3} for a complex fluid with that of an approximate coarse-grained model described by a pair potential, three body effects can be quantified. The strategy is applicable to both Molecular Dynamics and Monte Carlo simulation. Its utility is illustrated via measurements of three-body effects in models of star polymers and in highly size-asymmetrical colloid-polymer mixtures.

  3. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure...

  4. Carbon Trust | Open Energy Information

    Open Energy Info (EERE)

    Trust Jump to: navigation, search Name: Carbon Trust Place: London, Greater London, United Kingdom Zip: EC4A 3BF Sector: Carbon Product: London-based independent company funded by...

  5. Sustainable Carbon | Open Energy Information

    Open Energy Info (EERE)

    Carbon Jump to: navigation, search Name: Sustainable Carbon Place: Sao Paulo, Sao Paulo, Brazil Zip: 04 038 032 Product: Sao Paulo-based joint-venture with CantorCO2e Brazil. The...

  6. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to...

  7. Carbon Clear | Open Energy Information

    Open Energy Info (EERE)

    Clear Jump to: navigation, search Name: Carbon Clear Place: United Kingdom Product: UK-based voluntary offset provider. References: Carbon Clear1 This article is a stub. You can...

  8. Overview of Carbon Storage Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    Roughly one third of the United States’ carbon emissions come from power plants and other large point sources, such as industrial facilities. The Carbon Storage Program is focused on ensuring the...

  9. Layered ultra-thin coherent structures used as electrical resistors having low temperature coefficient of resistivity

    DOE Patents [OSTI]

    Werner, Thomas R.; Falco, Charles M.; Schuller, Ivan K.

    1984-01-01

    A thin film resistor having a controlled temperature coefficient of resistance (TCR) ranging from negative to positive degrees kelvin and having relatively high resistivity. The resistor is a multilayer superlattice crystal containing a plurality of alternating, ultra-thin layers of two different metals. TCR is varied by controlling the thickness of the individual layers. The resistor can be readily prepared by methods compatible with thin film circuitry manufacturing techniques.

  10. Investigation of photon attenuation coefficient of some building materials used in Turkey

    SciTech Connect (OSTI)

    Dogan, B.; Altinsoy, N.

    2015-03-30

    In this study, some building materials regularly used in Turkey, such as concrete, gas concrete, pumice and brick have been investigated in terms of mass attenuation coefficient at different gamma-ray energies. Measurements were carried out by gamma spectrometry containing NaI(Tl) detector. Narrow beam gamma-ray transmission geometry was used for the attenuation measurements. The results are in good agreement with the theoretical calculation of XCOM code.

  11. Modeling polychlorinated biphenyl mass transfer after amendment of contaminated sediment with activated carbon

    SciTech Connect (OSTI)

    David Werner; Upal Ghosh; Richard G. Luthy

    2006-07-01

    The sorption kinetics and concentration of polychlorinated biphenyls (PCBs) in historically polluted sediment is modeled to assess a remediation strategy based on in situ PCB sequestration by mixing with activated carbon (AC). The authors extend their evaluation of a model based on intraparticle diffusion by including a biomimetic semipermeable membrane device (SPMD) and a first-order degradation rate for the aqueous phase. The model predictions are compared with the previously reported experimental PCB concentrations in the bulk water phase and in SPMDs. The simulated scenarios comprise a marine and a freshwater sediment, four PCB congeners, two AC grain sizes, four doses of AC, and comparison with laboratory experiments. The modeling approach distinguishes between two different sediment particles types: a light-density fraction representing carbonaceous particles such as charcoal, coal, coke, cenospheres, or wood, and a heavy-density fraction representing the mineral phase with coatings of organic matter. A third particle type in the numerical model is AC. The model qualitatively reproduces the observed shifts in the PCB distribution during repartitioning after AC amendment but overestimates the overall effect of the treatment in reducing aqueous and SPMD concentrations of PCBs by a factor of 2-6. For the AC application in sediment, competitive sorption of the various solutes apparently requires a reduction by a factor of 16 of the literature values for the AC-water partitioning coefficient measured in pure aqueous systems. With this correction, model results and measurements agree within a factor of 3. After AC amendment is homogeneously mixed into the sediment and then left undisturbed, aqueous PCB concentrations tend toward the same reduction after 5 years. 19 refs., 5 figs., 4 tabs.

  12. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS finally put to rest doubts about the existence of magnetic carbon.

  13. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS finally put to rest doubts about the existence of magnetic carbon.

  14. Boron nitride converted carbon fiber

    DOE Patents [OSTI]

    Rousseas, Michael; Mickelson, William; Zettl, Alexander K.

    2016-04-05

    This disclosure provides systems, methods, and apparatus related to boron nitride converted carbon fiber. In one aspect, a method may include the operations of providing boron oxide and carbon fiber, heating the boron oxide to melt the boron oxide and heating the carbon fiber, mixing a nitrogen-containing gas with boron oxide vapor from molten boron oxide, and converting at least a portion of the carbon fiber to boron nitride.

  15. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS finally put to rest doubts about the existence of magnetic carbon.

  16. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon First Proof of Ferromagnetic Carbon Print Wednesday, 25 July 2007 00:00 Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS

  17. Carbon nanotube array based sensor

    DOE Patents [OSTI]

    Lee, Christopher L.; Noy, Aleksandr; Swierkowski, Stephan P.; Fisher, Karl A.; Woods, Bruce W.

    2005-09-20

    A sensor system comprising a first electrode with an array of carbon nanotubes and a second electrode. The first electrode with an array of carbon nanotubes and the second electrode are positioned to produce an air gap between the first electrode with an array of carbon nanotubes and the second electrode. A measuring device is provided for sensing changes in electrical capacitance between the first electrode with an array of carbon nanotubes and the second electrode.

  18. Apparatus for producing carbon-coated nanoparticles and carbon nanospheres

    DOE Patents [OSTI]

    Perry, W. Lee; Weigle, John C.; Phillips, Jonathan

    2015-10-20

    An apparatus for producing carbon-coated nano- or micron-scale particles comprising a container for entraining particles in an aerosol gas, providing an inlet for carbon-containing gas, providing an inlet for plasma gas, a proximate torch for mixing the aerosol gas, the carbon-containing gas, and the plasma gas, bombarding the mixed gases with microwaves, and providing a collection device for gathering the resulting carbon-coated nano- or micron-scale particles. Also disclosed is a method and apparatus for making hollow carbon nano- or micro-scale spheres.

  19. Dispersion toughened silicon carbon ceramics

    DOE Patents [OSTI]

    Wei, G.C.

    1984-01-01

    Fracture resistant silicon carbide ceramics are provided by incorporating therein a particulate dispersoid selected from the group consisting of (a) a mixture of boron, carbon and tungsten, (b) a mixture of boron, carbon and molybdenum, (c) a mixture of boron, carbon and titanium carbide, (d) a mixture of aluminum oxide and zirconium oxide, and (e) boron nitride. 4 figures.

  20. 2e Carbon Access | Open Energy Information

    Open Energy Info (EERE)

    e Carbon Access Jump to: navigation, search Name: 2e Carbon Access Place: New York, New York Zip: 10280 Sector: Carbon Product: 2E Carbon Access is an enterprise focused solely on...

  1. Less Carbon Ltd | Open Energy Information

    Open Energy Info (EERE)

    Less Carbon Ltd Jump to: navigation, search Name: Less Carbon Ltd Place: London, Greater London, United Kingdom Zip: EC3M 4BT Sector: Carbon Product: Less Carbon advises energy...

  2. SGL Carbon AG | Open Energy Information

    Open Energy Info (EERE)

    Carbon AG Jump to: navigation, search Name: SGL Carbon AG Place: Wiesbaden, Hessen, Germany Zip: 65203 Sector: Carbon Product: A Germany-based manufacturer of carbon-based products...

  3. Development of carbon-metal oxide supercapacitors from sol-gel derived carbon-ruthenium xerogels

    SciTech Connect (OSTI)

    Lin, C.; Ritter, J.A.; Popov, B.N.

    1999-09-01

    There has been increasing interest in electrochemical capacitors as energy storage systems because of their high power density and long cycle life, compared to battery devices. According to the mechanism of energy storage, there are two types of electrochemical capacitors. One type is based on double layer (dl) formation due to charge separation, and the other type is based on a faradaic process due to redox reactions. Sol-gel derived high surface area carbon-ruthenium xerogels were prepared from carbonized resorcinol-formaldehyde resins containing an electrochemically active form of ruthenium oxide. The electrochemical capacitance of these materials increased with an increase in the ruthenium content indicating the presence of pseudocapacitance associated with the ruthenium oxide undergoing reversible faradaic redox reactions. A specific capacitance of 256 F/g (single electrode) was obtained from a carbon xerogel containing 14 wt% Ru, which corresponded to more than 50% utilization of the ruthenium. The double layer accounted for 40% of this capacitance. This material was also electrochemically stable, showing no change in a cyclic voltammogram for over 2,000 cycles.

  4. Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons

    DOE Patents [OSTI]

    Muradov, Nazim Z.

    2011-08-23

    A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

  5. Electronic and optical properties of novel carbon allotropes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Zhanyu; Dong, F.; Shen, B.; Zhang, R. J.; Zheng, Y. X.; Chen, L. Y.; Wang, S. Y.; Wang, C. Z.; Ho, K. M.; Fan, Yuan -Jia; et al

    2016-01-22

    The vibrational properties, electronic structures and optical properties of novel carbon allotropes, such as monolayer penta-graphene (PG), double-layer PG and T12-carbon, were studied by first-principles calculations. Results of phonon calculations demonstrate that these exotic carbon allotropes are dynamically stable. The bulk T12 phase is an indirect-gap semiconductor having a quasiparticle (QP) bandgap of ~5.19 eV. When the bulk material transforms to a two-dimensional (2D) phase, the monolayer and double-layer PG become quasi-direct gap semiconductors with smaller QP bandgaps of ~4.48 eV and ~3.67 eV, respectively. Furthermore, the partial charge density analysis indicates that the 2D phases retain part of themore » electronic characteristics of the T12 phase. The linear photon energy-dependent dielectric functions and related optical properties including refractive index, extinction coefficient, absorption spectrum, reflectivity, and energy-loss spectrum were also computed and discussed. Additionally, the chemical stability of monolayer PG and the electronic and optical properties of double-side hydrogenated monolayer PG were also investigated. Furthermore, the results obtained from our calculations are beneficial to practical applications of these exotic carbon allotropes in optoelectronics and electronics.« less

  6. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    SciTech Connect (OSTI)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO?- absorbing liquid solvent contained within solid, CO?-permeable, polymer shells. MECS enhance the rate of CO? absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO? pressures in stripping conditions, relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.

  7. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO₂- absorbing liquid solvent contained within solid, CO₂-permeable, polymer shells. MECS enhance the rate of CO₂ absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO₂ pressures in stripping conditions,more » relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.« less

  8. Establishing MICHCARB, a geological carbon sequestration research...

    Office of Scientific and Technical Information (OSTI)

    Western Michigan University 58 GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil, gas and saline reservoirs Geological carbon...

  9. Understanding Manufacturing Energy and Carbon Footprints, October...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Understanding Manufacturing Energy and Carbon Footprints, October 2012 Understanding Manufacturing Energy and Carbon Footprints, October 2012 understandingenergyfootprints2012.p...

  10. Electrobiocommodities from Carbon Dioxide: Enhancing Microbial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrobiocommodities from Carbon Dioxide: Enhancing Microbial Electrosynthesis with Synthetic Electromicrobiology and System Design Electrobiocommodities from Carbon Dioxide: ...

  11. Thermal conversion of municipal solid waste via hydrothermal carbonization: Comparison of carbonization products to products from current waste management techniques

    SciTech Connect (OSTI)

    Lu Xiaowei; Jordan, Beth; Berge, Nicole D.

    2012-07-15

    Highlights: Black-Right-Pointing-Pointer Hydrothermal carbonization (HTC) is a novel thermal conversion process. Black-Right-Pointing-Pointer HTC converts wastes into value-added resources. Black-Right-Pointing-Pointer Carbonization integrates majority of carbon into solid-phase. Black-Right-Pointing-Pointer Carbonization results in a hydrochar with high energy density. Black-Right-Pointing-Pointer Using hydrochar as an energy source may be beneficial. - Abstract: Hydrothermal carbonization (HTC) is a novel thermal conversion process that may be a viable means for managing solid waste streams while minimizing greenhouse gas production and producing residual material with intrinsic value. HTC is a wet, relatively low temperature (180-350 Degree-Sign C) thermal conversion process that has been shown to convert biomass to a carbonaceous residue referred to as hydrochar. Results from batch experiments indicate HTC of representative waste materials is feasible, and results in the majority of carbon (45-75% of the initially present carbon) remaining within the hydrochar. Gas production during the batch experiments suggests that longer reaction periods may be desirable to maximize the production of energy-favorable products. If using the hydrochar for applications in which the carbon will remain stored, results suggest that the gaseous products from HTC result in fewer g CO{sub 2}-equivalent emissions than the gases associated with landfilling, composting, and incineration. When considering the use of hydrochar as a solid fuel, more energy can be derived from the hydrochar than from the gases resulting from waste degradation during landfilling and anaerobic digestion, and from incineration of food waste. Carbon emissions resulting from the use of the hydrochar as a fuel source are smaller than those associated with incineration, suggesting HTC may serve as an environmentally beneficial alternative to incineration. The type and extent of environmental benefits derived from

  12. Water-soluble carbon nanotube compositions for drug delivery and medicinal applications

    DOE Patents [OSTI]

    Tour, James M.; Lucente-Schultz, Rebecca; Leonard, Ashley; Kosynkin, Dmitry V.; Price, Brandi Katherine; Hudson, Jared L.; Conyers, Jr., Jodie L.; Moore, Valerie C.; Casscells, S. Ward; Myers, Jeffrey N.; Milas, Zvonimir L.; Mason, Kathy A.; Milas, Luka

    2014-07-22

    Compositions comprising a plurality of functionalized carbon nanotubes and at least one type of payload molecule are provided herein. The compositions are soluble in water and PBS in some embodiments. In certain embodiments, the payload molecules are insoluble in water. Methods are described for making the compositions and administering the compositions. An extended release formulation for paclitaxel utilizing functionalized carbon nanotubes is also described.

  13. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the

  14. Carbon Capture and Storage, 2008

    ScienceCinema (OSTI)

    None

    2010-01-08

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  15. ARM - Field Campaign - Aircraft Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsAircraft Carbon ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Aircraft Carbon 2006.07.01 - 2008.09.30 Lead Scientist : Margaret Torn For data sets, see below. Abstract Airborne trace-gas measurements at ARM-SGP provided valuable data for addressing carbon-cycle questions highlighted by the US Climate Change Research Program and the North American Carbon Program. A set of carbon-cycle

  16. Carbon Capture and Storage, 2008

    SciTech Connect (OSTI)

    2009-03-19

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  17. Hydrogen storage and carbon dioxide capture in an iron-based...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal-organic framework (Fe-BTT) discovered via high-throughput methods Previous Next List Kenji Sumida, ...

  18. A Universal Model for Nanoporous Carbon Supercapacitors Applicable to Diverse Pore Regimes, Carbons, and Electrolyte

    SciTech Connect (OSTI)

    Sumpter, Bobby G; Huang, Jingsong; Meunier, Vincent

    2008-01-01

    Supercapacitors, commonly called electric double-layer capacitors (EDLCs), are emerging as a novel type of energy storage device with the potential to substitute batteries in applications requiring high power densities. In response to the latest experimental breakthrough in nanoporous carbon supercapacitors, we propose a heuristic theoretical model that takes pore curvature into account as a replacement for the EDLC model which is based on a traditional parallel-plate capacitor. When the pore size is in the mesopore regime (2-50 nm), counterions enter mesoporous carbons and approach the pore wall to form an electric double-cylinder capacitor (EDCC); in the micropore regime (< 2 nm), solvated/desolvated counterions line up along the pore axis to form an electric wire-in-cylinder capacitor (EWCC). In the macropore regime (> 50 nm) where pores are large enough so that the pore curvature is no longer significant, the EDCC model can be reduced naturally to the EDLC model. We present density functional theory calculations and detailed analyses of available experimental data in various pore regimes, showing the significant effects of pore curvature on the supercapacitor properties of nanoporous carbons. It is shown that the EDCC/EWCC model is universal to carbon supercapacitors with diverse carbon materials including activated carbons, template carbons, and novel carbide-derived carbons, and with diverse electrolytes including organic electrolytes such as tetraethylammonium tetrafluoroborate (TEABF4), tetraethylammonium methyl-sulfonate (TEAMS) in acetonitrile, aqueous H2SO4 and KOH electrolytes, and even ionic liquid electrolyte such as 1-ethyl-3-methylimmidazolium bis(trifluromethane-sulfonyl)imide (EMI-TFSI). The EDCC/EWCC model allows the supercapacitor properties to be correlated with pore size, specific surface area, Debye length, electrolyte concentration and dielectric constant, and solute ion size, and may lend a support for the systematic optimization of the

  19. Electrical discharge machining of type-N(f) microwave connectors

    SciTech Connect (OSTI)

    Haushalter, R.J.

    1996-07-01

    A particular out-of-specification mechanical dimension on Type-N(f) [Type-N(female)] microwave connectors sometimes disqualifies otherwise perfectly acceptable microwave devices from being used in calibration systems. The Miniature Machining Group at Sandia National Laboratories applied a technique called Electrical Discharge Machining (EDM) to quickly and economically machine these devices without disassembly. In so doing, they facilitated the use of existing components without the need to purchase new devices. The technique also improves an uncertainty of calibration known as Mismatch Uncertainty by optimizing the reflection coefficient of the calibration test port. This effects a reduction in overall calibration uncertainties.

  20. Carbonate-tephrogenic sediments of the Daribi Ridge (southwestern Mongolia)

    SciTech Connect (OSTI)

    Kheraskova, T.N.; Il'inskaya, M.N.

    1986-01-01

    The article examines the lithology, genetic types, and facies of the formation of carbonate-tephoregenic beds accumulated during the subsidence and compaction of a volcanic rise. The sediments of autokinetic flows of pyroclastic matter and submarine landslide accumulations are described in detail.

  1. Carbon Dioxide Separation from Flue Gas by Phase Enhanced Absorption

    SciTech Connect (OSTI)

    Tim Fout

    2007-06-30

    liquid mass transfer coefficients for the CO{sub 2}-water-organic layer system. For the CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system, the enhanced factor is not only dependent on the liquid mass transfer coefficients, but also the chemical reaction rates.

  2. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-06-01

    The Big Sky Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts during the second performance period fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for

  3. Transverse piezoelectric coefficient measurement of flexible lead zirconate titanate thin films

    SciTech Connect (OSTI)

    Dufay, T.; Guiffard, B.; Seveno, R.; Thomas, J.-C.

    2015-05-28

    Highly flexible lead zirconate titanate, Pb(Zr,Ti)O{sub 3} (PZT), thin films have been realized by modified sol-gel process. The transverse piezoelectric coefficient d{sub 31} was determined from the tip displacement of bending-mode actuators made of PZT cantilever deposited onto bare or RuO{sub 2} coated aluminium substrate (16 μm thick). The influence of the thickness of ruthenium dioxide RuO{sub 2} and PZT layers was investigated for Pb(Zr{sub 0.57}Ti{sub 0.43})O{sub 3}. The modification of Zr/Ti ratio from 40/60 to 60/40 was done for 3 μm thick PZT thin films onto aluminium (Al) and Al/RuO{sub 2} substrates. A laser vibrometer was used to measure the beam displacement under controlled electric field. The experimental results were fitted in order to find the piezoelectric coefficient. Very large tip deflections of about 1 mm under low voltage (∼8 V) were measured for every cantilevers at the resonance frequency (∼180 Hz). For a given Zr/Ti ratio of 58/42, it was found that the addition of a 40 nm thick RuO{sub 2} interfacial layer between the aluminium substrate and the PZT layer induces a remarkable increase of the d{sub 31} coefficient by a factor of 2.7, thus corresponding to a maximal d{sub 31} value of 33 pC/N. These results make the recently developed PZT/Al thin films very attractive for both low frequency bending mode actuating applications and vibrating energy harvesting.

  4. A time-domain estimation of wall conduction transfer function coefficients

    SciTech Connect (OSTI)

    Davies, M.G.

    1996-11-01

    The wall and roof transfer function coefficients, b{sub n} and d{sub n}, listed in the 1993 ASHRAE Fundamentals Handbook, have up to now been derived using laplace and Z-transform methods. This paper shows that they can be readily evaluated using straightforward time-domain solutions of the Fourier continuity equation. These include the response of a wall to a ramp increase in temperature and its transient response. The values of d{sub n} can be found from the first few terms in the series of wall decay times in the transient solution. The solutions are combined using a form of Fourier analysis. Appropriate layer transmission matrices enable one to find the wall`s overall characteristics readily. The wall response factors {phi}{sub j} can thus be found. The b{sub n} transfer coefficients are related to the {phi}{sub j} and d{sub n} values. The approach is illustrated using the data for wall group 6. Allowing for conversion from I-P to SI units, the present approach gives results that are almost identical to those listed. It shows, however, that the performance of the coefficients is very specific to the wall from which they were derived. The b{sub n} and d{sub n} values listed in the Handbook permit an estimate to be made of the wall response factors, including the time of peak flow and the first decay time. For heavy walls, however, values beyond d{sub 6} may be needed.

  5. Effect of Mixed Working Fluid Composition on Binary Cycle Condenser Heat Transfer Coefficients

    SciTech Connect (OSTI)

    Dan Wendt; Greg Mines

    2011-10-01

    Effect of Mixed Working Fluid Composition on Binary Cycle Condenser Heat Transfer Coefficients Dan Wendt, Greg Mines Idaho National Laboratory The use of mixed working fluids in binary power plants can provide significant increases in plant performance, provided the heat exchangers are designed to take advantage of these fluids non-isothermal phase changes. In the 1980's testing was conducted at DOE's Heat Cycle Research Facility (HCRF) where mixtures of different compositions were vaporized at supercritical pressures and then condensed. This testing had focused on using the data collected to verify that Heat Transfer Research Incorporated (HTRI) codes were suitable for the design of heat exchangers that could be used with mixtures. The HCRF data includes mixture compositions varying from 0% to 40% isopentane and condenser tube orientations of 15{sup o}, 60{sup o}, and 90{sup o} from horizontal. Testing was performed over a range of working fluid and cooling fluid conditions. Though the condenser used in this testing was water cooled, the working fluid condensation occurred on the tube-side of the heat exchanger. This tube-side condensation is analogous to that in an air-cooled condenser. Tube-side condensing heat transfer coefficient information gleaned from the HCRF testing is used in this study to assess the suitability of air-cooled condenser designs for use with mixtures. Results of an air-cooled binary plant process model performed with Aspen Plus indicate that that the optimal mixture composition (producing the maximum net power for the scenario considered) is within the range of compositions for which data exist. The HCRF data is used to assess the impact of composition, tube orientation, and process parameters on the condensing heat transfer coefficients. The sensitivity of the condensing coefficients to these factors is evaluated and the suitability of air-cooled condenser designs with mixtures is assessed. This paper summarizes the evaluation of the HCRF

  6. Method for producing ceramic composition having low friction coefficient at high operating temperatures

    DOE Patents [OSTI]

    Lankford, Jr., James

    1988-01-01

    A method for producing a stable ceramic composition having a surface with a low friction coefficient and high wear resistance at high operating temperatures. A first deposition of a thin film of a metal ion is made upon the surface of the ceramic composition and then a first ion implantation of at least a portion of the metal ion is made into the near surface region of the composition. The implantation mixes the metal ion and the ceramic composition to form a near surface composite. The near surface composite is then oxidized sufficiently at high oxidizing temperatures to form an oxide gradient layer in the surface of the ceramic composition.

  7. On the Reliability of Photovoltaic Short-Circuit Current Temperature Coefficient Measurements

    SciTech Connect (OSTI)

    Osterwald, Carl R.; Campanelli, Mark; Kelly, George J.; Williams, Rafell

    2015-06-14

    The changes in short-circuit current of photovoltaic (PV) cells and modules with temperature are routinely modeled through a single parameter, the temperature coefficient (TC). This parameter is vital for the translation equations used in system sizing, yet in practice is very difficult to measure. In this paper, we discuss these inherent problems and demonstrate how they can introduce unacceptably large errors in PV ratings. A method for quantifying the spectral dependence of TCs is derived, and then used to demonstrate that databases of module parameters commonly contain values that are physically unreasonable. Possible ways to reduce measurement errors are also discussed.

  8. Simultaneous evaluation of acoustic nonlinearity parameter and attenuation coefficients using the finite amplitude method

    SciTech Connect (OSTI)

    Zhang, Shuzeng; Li, Xiongbing; Jeong, Hyunjo Cho, Sungjong

    2015-07-15

    A novel method to determine acoustic parameters involved in measuring the nonlinearity parameter of fluids or solids is proposed. The approach is based on the measurement of fundamental and second harmonic pressures with a calibrated receiver, and on a nonlinear least squares data-fitting to multi-Gaussian beam (MGB) equations which explicitly define the attenuation and diffraction effects in the quasilinear regime. Results obtained in water validate the proposed method. The choice of suitable source pressure is discussed with regard to the quasilinear approximation involved. The attenuation coefficients are also acquired in nonlinear regime and their relations are discussed.

  9. Electrode size and boundary condition independent measurement of the effective piezoelectric coefficient of thin films

    SciTech Connect (OSTI)

    Stewart, M.; Lepadatu, S.; McCartney, L. N.; Cain, M. G.; Wright, L.; Crain, J.; Newns, D. M.; Martyna, G. J.

    2015-02-01

    The determination of the piezoelectric coefficient of thin films using interferometry is hindered by bending contributions. Using finite element analysis (FEA) simulations, we show that the Lefki and Dormans approximations using either single or double-beam measurements cannot be used with finite top electrode sizes. We introduce a novel method for characterising piezoelectric thin films which uses a differential measurement over the discontinuity at the electrode edge as an internal reference, thereby eliminating bending contributions. This step height is shown to be electrode size and boundary condition independent. An analytical expression is derived which gives good agreement with FEA predictions of the step height.

  10. Adsorption of selected pharmaceuticals and an endocrine disrupting compound by granular activated carbon. 1. Adsorption capacity and kinetics

    SciTech Connect (OSTI)

    Yu, Z.; Peldszus, S.; Huck, P.M.

    2009-03-01

    The adsorption of two representative PhACs (naproxen and carbamazepine) and one EDC (nonylphenol) were evaluated on two granular activated carbons (GAC) namely coal-based Calgon Filtrasorb 400 and coconut shell-based PICA CTIF TE. The primary objective was to investigate preloading effects by natural organic matter (NOM) on adsorption capacity and kinetics under conditions and concentrations (i.e., ng/L) relevant for drinking water treatment. Isotherms demonstrated that all compounds were significantly negatively impacted by NOM fouling. Adsorption capacity reduction was most severe for the acidic naproxen, followed by the neutral carbamazepine and then the more hydrophobic nonylphenol. The GAC with the wider pore size distribution had considerably greater NOM loading, resulting in lower adsorption capacity. Different patterns for the change in Freundlich KF and 1/n with time revealed different competitive mechanisms for the different compounds. Mass transport coefficients determined by short fixed-bed (SFB) tests with virgin and preloaded GAC demonstrated that film diffusion primarily controls mass transfer on virgin and preloaded carbon. Naproxen suffered the greatest deteriorative effect on kinetic parameters due to preloading, followed by carbamazepine, and then nonylphenol. A type of surface NOM/biofilm, which appeared to add an additional mass transfer resistance layer and thus reduce film diffusion, was observed. In addition, electrostatic interactions between NOM/biofilm and the investigated compounds are proposed to contribute to the reduction of film diffusion. A companion paper building on this work describes treatability studies in pilot-scale GAC adsorbers and the effectiveness of a selected fixed-bed model. 32 refs., 3 figs., 2 tabs.

  11. Neutralizing Carbonic Acid in Deep Carbonate Strata below the North Atlantic

    SciTech Connect (OSTI)

    Daniel P. Schrag

    2006-07-14

    Our research is aimed at investigating several technical issues associated with carbon dioxide sequestration in calcium carbonate sediments below the sea floor through laboratory experiments and chemical transport modeling. Our goal is to evaluate the basic feasibility of this approach, including an assessment of optimal depths, sediment types, and other issues related to site selection. The results of our modeling efforts were published this past summer in the Proceedings of the National Academy of Sciences. We are expanding on that work through a variety of laboratory and modeling efforts. In the laboratories at Columbia and at Harvard, we are studying the flow of liquid carbon dioxide and carbon dioxide-water mixtures through calcium carbonate sediments to better understand the geomechanical and structural stability of the sediments during and after injection. We are currently preparing the results of these findings for publication. In addition, we are investigating the kinetics of calcium carbonate dissolution in the presence of CO{sub 2}-water fluids, which is a critical feature of the system as it allows for increased permeability during injection. We are also investigating the possibility of carbon dioxide hydrate formation in the pore fluid, which might complicate the injection procedure by reducing sediment permeability but might also provide an upper seal in the sediment-pore fluid system, preventing release of CO{sub 2} into the deep ocean, particularly if depth and temperature at the injection point rule out immediate hydrate formation. This is done by injecting liquid CO{sub 2} into various types of porous media, and then monitoring the changes in permeability. Finally, we are performing an economic analysis to estimate costs of drilling and gas injection, site monitoring as well as the availability of potential disposal sites with particular emphasis on those sites that are within the 200-mile economic zone of the United States. We present some

  12. Carbon Ion Pump for Carbon Dioxide Removal - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Carbon Ion Pump for Carbon Dioxide Removal Lawrence Livermore National Laboratory Contact LLNL About This Technology Technology Marketing Summary The limitation to reducing greenhouse gases in the atmosphere is the expense of stripping carbon dioxide from other combustion gases. Without a cost-effective means of accomplishing this, hydrocarbon resources cannot be used freely. A few power plants currently remove

  13. Method for joining carbon-carbon composites to metals

    DOE Patents [OSTI]

    Lauf, Robert J.; McMillan, April D.; Moorhead, Arthur J.

    1997-01-01

    A method for joining carbon-carbon composites to metals by brazing. Conventional brazing of recently developed carbon-bonded carbon fiber (CBCF) material to a metal substrate is limited by the tendency of the braze alloy to "wick" into the CBCF composite rather than to form a strong bond. The surface of the CBCF composite that is to be bonded is first sealed with a fairly dense carbonaceous layer achieved by any of several methods. The sealed surface is then brazed to the metal substrate by vacuum brazing with a Ti-Cu-Be alloy.

  14. Method for joining carbon-carbon composites to metals

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Moorhead, A.J.

    1997-07-15

    A method for joining carbon-carbon composites to metals by brazing. Conventional brazing of recently developed carbon-bonded carbon fiber (CBCF) material to a metal substrate is limited by the tendency of the braze alloy to ``wick`` into the CBCF composite rather than to form a strong bond. The surface of the CBCF composite that is to be bonded is first sealed with a fairly dense carbonaceous layer achieved by any of several methods. The sealed surface is then brazed to the metal substrate by vacuum brazing with a Ti-Cu-Be alloy. 1 fig.

  15. Geologic Carbon Sequestration and Biosequestration (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    DePaolo, Don [Director, LBNL Earth Sciences Division

    2011-06-08

    Don DePaolo, Director of LBNL's Earth Sciences Division, speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  16. Novel Application of Carbonate Fuel Cell for Capturing Carbon...

    Office of Scientific and Technical Information (OSTI)

    the Combined Electric Power and Carbon-dioxide Separation (CEPACS) system concept. ... testingmore of an ECM-based CO2 separation and purification system. less ...

  17. n-Type diamond and method for producing same

    DOE Patents [OSTI]

    Anderson, Richard J.

    2002-01-01

    A new n-type semiconducting diamond is disclosed, which is doped with n-type dopant atoms. Such diamond is advantageously formed by chemical vapor deposition from a source gas mixture comprising a carbon source compound for the diamond, and a volatile hot wire filament for the n-type impurity species, so that the n-type impurity atoms are doped in the diamond during its formation. A corresponding chemical vapor deposition method of forming the n-type semiconducting diamond is disclosed. The n-type semiconducting diamond of the invention may be usefully employed in the formation of diamond-based transistor devices comprising pn diamond junctions, and in other microelectronic device applications.

  18. JV Task 90 - Activated Carbon Production from North Dakota Lignite

    SciTech Connect (OSTI)

    Steven Benson; Charlene Crocker; Rokan Zaman; Mark Musich; Edwin Olson

    2008-03-31

    was superior to commercial DARCO FGD for mercury capture. The results of the activated carbon market assessment indicate an existing market for water treatment and an emerging application for mercury control. That market will involve both existing and new coal-fired plants. It is expected that 20% of the existing coal-fired plants will implement activated carbon injection by 2015, representing about 200,000 tons of annual demand. The potential annual demand by new plants is even greater. In the mercury control market, two characteristics are going to dominate the customer's buying habit-performance and price. As continued demonstration testing of activated carbon injection at the various coal-fired power plants progresses, the importance of fuel type and plant configuration on the type of activated carbon best suited is being identified.

  19. Use of radial symmetry for the calculation of cylindrical absorption coefficients and optimal capillary loadings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khalifah, Peter

    2015-02-01

    The problem of numerically evaluating absorption correction factors for cylindrical samples has been revisited using a treatment that fully takes advantage of the sample symmetry. It is shown that the path lengths for all points within the sample at all possible diffraction angles can be trivially determined once the angle-dependent distance distribution for a single line of points is calculated. This provides advantages in both computational efficiency and in gaining an intuitive understanding of the effects of absorption on diffraction data. A matrix of absorption coefficients calculated for µR products between 0 and 20 for diffraction angles θD of 0°more » to 90° were used to examine the influence of (1) capillary diameter and of (2) sample density on the overall scattered intensity as a function of diffraction angle, where µ is the linear absorption coefficient for the sample and R is the capillary radius. Based on this analysis, the optimal sample loading for a capillary experiment to maximize diffraction at angles of 0 – 50° is in general expected to be achieved when the maximum radius capillary compatible with the beam is used, and when the sample density is adjusted to be 3/(4µR) of its original density.« less

  20. A rapid compression machine study of the oxidation of propane in the negative temperature coefficient regime

    SciTech Connect (OSTI)

    Gallagher, S.M.; Curran, H.J.; Metcalfe, W.K.; Healy, D.; Simmie, J.M.; Bourque, G.

    2008-04-15

    The oxidation of propane has been studied in the temperature range 680-970 K at compressed gas pressures of 21, 27, and 37 atm and at varying equivalence ratios of 0.5, 1.0, and 2.0. These data are consistent with other experiments presented in the literature for alkane fuels in that, when ignition delay times are plotted as a function of temperature, a characteristic negative coefficient behavior is observed. In addition, these data were simulated using a detailed chemical kinetic model. It was found that qualitatively the model correctly simulated the effect of change in equivalence ratio and pressure, predicting that fuel-rich, high-pressure mixtures ignite fastest, while fuel-lean, low-pressure mixtures ignite slowest. Moreover, reactivity as a function of temperature is well captured, with the model predicting negative temperature coefficient behavior similar to the experiments. Quantitatively the model is faster than experiment for all mixtures at the lowest temperatures (650-750 K) and is also faster than experiment throughout the entire temperature range for fuel-lean mixtures. (author)

  1. Distribution coefficient values describing iodine, neptunium, selenium, technetium, and uranium sorption to Hanford sediments. Supplement 1

    SciTech Connect (OSTI)

    Kaplan, D.I.; Seme, R.J.

    1995-03-01

    Burial of vitrified low-level waste (LLW) in the vadose zone of the Hanford Site is being considered as a long-term disposal option. Regulations dealing with LLW disposal require that performance assessment (PA) analyses be conducted. Preliminary modeling efforts for the Hanford Site LLW PA were conducted to evaluate the potential health risk of a number of radionuclides, including Ac, Am, C, Ce, Cm, Co, Cs, Eu, 1, Nb, Ni, Np, Pa, Pb, Pu, Ra, Ru, Se, Sn, Sr, Tc, Th, U, and Zr (Piepho et al. 1994). The radionuclides, {sup 129}I, {sup 237}Np, {sup 79}Se, {sup 99}Tc, and {sup 234,235,238}U, were identified as posing the greatest potential health hazard. It was also determined that the outcome of these simulations were very sensitive to the parameter describing the extent to which radionuclides sorbed to the subsurface matrix, described as a distribution coefficient (K{sub d}). The distribution coefficient is a ratio of the radionuclide concentration associated with the solid phase to that in the liquid phase. The literature-derived K{sub d} values used in these simulations were conservative, i.e., lowest values within the range of reasonable values used to provide an estimate of the maximum health threat. Thus, these preliminary modeling results reflect a conservative estimate rather than a best estimate of what is likely to occur. The potential problem with providing only a conservative estimate is that it may mislead us into directing resources to resolve nonexisting problems.

  2. Use of radial symmetry for the calculation of cylindrical absorption coefficients and optimal capillary loadings

    SciTech Connect (OSTI)

    Khalifah, Peter

    2015-02-01

    The problem of numerically evaluating absorption correction factors for cylindrical samples has been revisited using a treatment that fully takes advantage of the sample symmetry. It is shown that the path lengths for all points within the sample at all possible diffraction angles can be trivially determined once the angle-dependent distance distribution for a single line of points is calculated. This provides advantages in both computational efficiency and in gaining an intuitive understanding of the effects of absorption on diffraction data. A matrix of absorption coefficients calculated for µR products between 0 and 20 for diffraction angles θD of 0° to 90° were used to examine the influence of (1) capillary diameter and of (2) sample density on the overall scattered intensity as a function of diffraction angle, where µ is the linear absorption coefficient for the sample and R is the capillary radius. Based on this analysis, the optimal sample loading for a capillary experiment to maximize diffraction at angles of 0 – 50° is in general expected to be achieved when the maximum radius capillary compatible with the beam is used, and when the sample density is adjusted to be 3/(4µR) of its original density.

  3. Rate coefficients for reaction of OH with acetone between 202 and 395 K

    SciTech Connect (OSTI)

    Wollenhaupt, M.; Carl, S.A.; Horowitz, A.; Crowley, J.N.

    2000-03-30

    The kinetics of the title reaction were investigated between 202 and 395 K and at 20, 50, and 100 Torr of Ar or N{sub 2} bath gas using pulsed laser photolysis (PLP) generation of OH combined with both resonance fluorescence (RF) and laser-induced fluorescence (LIF) detection. OH was generated either by the sequential 439 nm, two-photon dissociation of NO{sub 2} in the presence of H{sub 2}, or by HONO photolysis at 351 nm. The accuracy of the rate constants obtained was enhanced by optical absorption measurements of acetone concentrations both before and after the photolysis reactor. The temperature dependence is not describe by a simple Arrhenius expression but by k{sub 1} (202--395 K) = 8.8 x 10{sup {minus}12} exp({minus}1,320/T) + 1.7 x 10{sup {minus}14} exp(423/T) cm{sup 3} s{sup {minus}1}, indicating that a simple H atom abstraction may not be the only reaction mechanism. The estimated total error (95% confidence) associated wit the rate coefficient derived from this expression is estimated as 5% and is independent of temperature. The curvature in the Arrhenius plot results in a significantly larger rate coefficient at low temperatures than obtained by extrapolation of the previous measurement and implies greater significance for the reaction with OH as a sink for acetone in the upper troposphere than presently assumed.

  4. Stress-intensity-factor influence coefficients for semielliptical inner-surface flaws in clad pressure vessels

    SciTech Connect (OSTI)

    Keeney, J.A.; Bryson, J.W.

    1995-12-31

    A problem of particular interest in pressure vessel technology is the calculation of accurate stress-intensity factors for semielliptical surface cracks in cylinders. Computing costs for direct solution techniques can be prohibitive when applied to three-dimensional (3-D) geometries with time-varying boundary conditions such as those associated with pressurized thermal shock. An alternative superposition technique requires the calculation of a set of influence coefficients for a given 3-D crack model that can be superimposed to obtain mode-I stress-intensity factors. This paper presents stress-intensity-factor influence coefficients (SIFICs) for axially and circumferentially oriented finite-length semielliptical inner-surface flaws with aspect ratios (total crack length (2c) to crack depth (a)) of 2, 6, and 10 for clad cylinders having an internal radius to wall thickness (t) ratio of 10. SIFICs are computed for flaw depths in the range of 0.01 {le} a/t {le} 0.5 and two cladding thicknesses. The incorporate of this SIFIC data base in fracture mechanics codes will facilitate the generation of fracture mechanics solutions for a wide range of flaw geometries as may be required in structural integrity assessments of pressurized-water and boiling-water reactors.

  5. Assessment of wear coefficients of nuclear zirconium claddings without and with pre-oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qu, Jun; Cooley, Kevin M.; Shaw, Austin H.; Lu, Roger Y.; Blau, Peter J.

    2016-03-16

    In the cores of pressurized water nuclear reactors, water-flow induced vibration is known to cause claddings on the fuel rods to rub against their supporting grids. Such grid-to-rod-fretting (GTRF) may lead to fretting wear-through and the leakage of radioactive species. The surfaces of actual zirconium alloy claddings in a reactor are inevitably oxidized in the high-temperature pressurized water, and some claddings are even pre-oxidized. As a result, the wear process of the surface oxide film is expected to be quite different from the zirconium alloy substrate. In this paper, we attempt to measure the wear coefficients of zirconium claddings withoutmore » and with pre-oxidation rubbing against grid samples using a bench-scale fretting tribometer. Results suggest that the volumetric wear coefficient of the pre-oxidized cladding is 50 to 200 times lower than that of the untreated cladding. In terms of the linear rate of wear depth, the pre-oxidized alloy wears about 15 times more slowly than the untreated cladding. Finally, fitted with the experimentally-determined wear rates, a stage-wise GTRF engineering wear model demonstrates good agreement with in-reactor experience in predicting the trend of cladding lives.« less

  6. Device and method for measuring the coefficient of performance of a heat pump

    DOE Patents [OSTI]

    Brantley, Vanston R.; Miller, Donald R.

    1984-01-01

    A method and instrument is provided which allows quick and accurate measurement of the coefficient of performance of an installed electrically powered heat pump including auxiliary resistance heaters. Temperature sensitive resistors are placed in the return and supply air ducts to measure the temperature increase of the air across the refrigerant and resistive heating elements of the system. The voltages across the resistors which are directly proportional to the respective duct temperatures are applied to the inputs of a differential amplifier so that its output voltage is proportional to the temperature difference across the unit. A voltage-to-frequency converter connected to the output of the differential amplifier converts the voltage signal to a proportional frequency signal. A digital watt meter is used to measure the power to the unit and produces a signal having a frequency proportional to the input power. A digital logic circuit ratios the temperature difference signal and the electric power input signal in a unique manner to produce a single number which is the coefficient of performance of the unit over the test interval. The digital logic and an in-situ calibration procedure enables the instrument to make these measurements in such a way that the ratio of heat flow/power input is obtained without computations. No specialized knowledge of thermodynamics or electronics is required to operate the instrument.

  7. Device and method for measuring the coefficient of performance of a heat pump

    DOE Patents [OSTI]

    Brantley, V.R.; Miller, D.R.

    1982-05-18

    A method and instrument is provided which allows quick and accurate measurement of the coefficient of performance of an installed electrically powered heat pump including auxiliary resistane heaters. Temperature-sensitive resistors are placed in the return and supply air ducts to measure the temperature increase of the air across the refrigerant and resistive-heating elements of the system. The voltages across the resistors which are directly proportional to the respective duct tempertures are applied to the inputs of a differential amplifier so that its output voltage is proportional to the temperature difference across the unit. A voltage-to-frequency converter connected to the output of the differential amplifier converts the voltage signal to a proportional-frequency signal. A digital watt meter is used to measure the power to the unit and produces a signal having a frequency proportional to the input power. A digital logic circuit ratios the temperature difference signal and the electric power input signal in a unique manner to produce a single number which is the coefficient of performance of the unit over the test interval. The digital logic and an in-situ calibration procedure enables the instrument to make these measurements in such a way that the ratio of heat flow/power input is obtained without computations. No specialized knowledge of thermodynamics or electrons is required to operate the instrument.

  8. Electron distribution function and recombination coefficient in ultracold plasma in a magnetic field

    SciTech Connect (OSTI)

    Bobrov, A. A.; Bronin, S. Ya.; Zelener, B. B.; Zelener, B. V.; Manykin, E. A.; Khikhlukha, D. R.

    2013-07-15

    The electron distribution function and diffusion coefficient in energy space have been calculated for the first time for a weakly coupled ultracold plasma in a magnetic field in the range of magnetic fields B = 100-50000 G for various temperatures. The dependence of these characteristics on the magnetic field is analyzed and the distribution function is shown to depend on the electron energy shift in a magnetic field. The position of the 'bottleneck' of the distribution function has been found to be shifted toward negative energies with increasing magnetic field. The electron velocity autocorrelators as a function of the magnetic field have been calculated; their behavior suggests that the frequency of collisions between charged particles decreases significantly with increasing magnetic field. The collisional recombination coefficient {alpha}{sub B} has been calculated in the diffusion approximation for a weakly coupled ultracold plasma in a magnetic field. An increase in magnetic field is shown to lead to a decrease in {alpha}{sub B} and this decrease can be several orders of magnitude.

  9. Reconstruction of time-dependent coefficients: A check of approximation schemes for non-Markovian convolutionless dissipative generators

    SciTech Connect (OSTI)

    Bellomo, Bruno; De Pasquale, Antonella; Gualdi, Giulia; Marzolino, Ugo

    2010-12-15

    We propose a procedure to fully reconstruct the time-dependent coefficients of convolutionless non-Markovian dissipative generators via a finite number of experimental measurements. By combining a tomography-based approach with a proper data sampling, our proposal allows to relate the time-dependent coefficients governing the dissipative evolution of a quantum system to experimentally accessible quantities. The proposed scheme not only provides a way to retrieve the full information about potentially unknown dissipative coefficients, but also, most valuably, can be employed as a reliable consistency test for the approximations involved in the theoretical derivation of a given non-Markovian convolutionless master equation.

  10. Modeling the role of terrestrial ecosystems in the global carbon cycle

    SciTech Connect (OSTI)

    Emanuel, W.R.; Post, W.M.; Shugart, H.H. Jr.

    1980-01-01

    A model for the global biogeochemical cycle of carbon which includes a five-compartment submodel for circulation in terrestrial ecosystems of the world is presented. Although this terrestrial submodel divides carbon into compartments with more functional detail than previous models, the variability in carbon dynamics among ecosystem types and in different climatic zones is not adequately treated. A new model construct which specifically treats this variability by modeling the distribution of ecosystem types as a function of climate on a 0.5/sup 0/ latitude by 0.5/sup 0/ longitude scale of resolution is proposed.

  11. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, Rafael A. (Chicago, IL); Hrdina, Kenneth E. (Glenview, IL); Remick, Robert J. (Bolingbrook, IL)

    1993-01-01

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process for production of the lithium ferrite containing anode by slipcasting.

  12. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, R.A.; Hrdina, K.E.; Remick, R.J.

    1993-04-27

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

  13. Global Carbon Budget 2015

    SciTech Connect (OSTI)

    Le Quéré, C.; Moriarty, R.; Andrew, R. M.; Canadell, J. G.; Sitch, S.; Korsbakken, J. I.; Friedlingstein, P.; Peters, G. P.; Andres, R. J.; Boden, T. A.; Houghton, R. A.; House, J. I.; Keeling, R. F.; Tans, P.; Arneth, A.; Bakker, D. C. E.; Barbero, L.; Bopp, L.; Chang, J.; Chevallier, F.; Chini, L. P.; Ciais, P.; Fader, M.; Gkritzalis, T.; Harris, I.; Hauck, J.; Ilyina, T.; Jain, A. K.; Kato, E.; Kitidis, V.; Klein Goldewijk, K.; Landschützer, P.; Lauvset, S. K.; Lefèvre, N.; Lenton, A.; Lima, I. D.; Metzl, N.; Millero, F.; Munro, D. R.; Murata, A.; Nabel, J. E. M. S.; Nakaoka, S.; Nojiri, Y.; O'Brien, K.; Olsen, A.; Ono, T.; Pérez, F. F.; Pfeil, B.; Pierrot, D.; Poulter, B.; Rehder, G.; Rödenbeck, C.; Saito, S.; Schuster, U.; Schwinger, J.; Séférian, R.; Steinhoff, T.; Stocker, B. D.; Sutton, A. J.; Takahashi, T.; Tilbrook, B.; van der Laan-Luijkx, I. T.; van der Werf, G. R.; van Heuven, S.; Vandemark, D.; Viovy, N.; Wiltshire, A.; Zaehle, S.; Zeng, N.

    2015-12-07

    Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We also discuss changes compared to previous estimates as well as consistency within and among components, alongside methodology and data limitations. CO2 emissions from fossil fuels and industry (EFF) are based on energy statistics and cement production data, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover-change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. Moreover, the mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models forced by observed climate, CO2, and land-cover change (some including nitrogen–carbon interactions). We compare the mean land and ocean fluxes and their variability to estimates from three

  14. Global Carbon Budget 2015

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Le Quéré, C.; Moriarty, R.; Andrew, R. M.; Canadell, J. G.; Sitch, S.; Korsbakken, J. I.; Friedlingstein, P.; Peters, G. P.; Andres, R. J.; Boden, T. A.; et al

    2015-12-07

    Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We also discuss changes compared to previous estimates as well as consistency within and among components, alongside methodology andmore » data limitations. CO2 emissions from fossil fuels and industry (EFF) are based on energy statistics and cement production data, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover-change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. Moreover, the mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models forced by observed climate, CO2, and land-cover change (some including nitrogen–carbon interactions). We compare the mean land and ocean fluxes and their variability to estimates from three atmospheric inverse methods for three broad latitude bands. All uncertainties are reported as ±1σ, reflecting the current capacity to characterise the annual estimates of each

  15. Global carbon budget 2014

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Le Quéré, C.; Moriarty, R.; Andrew, R. M.; Peters, G. P.; Ciais, P.; Friedlingstein, P.; Jones, S. D.; Sitch, S.; Tans, P.; Arneth, A.; et al

    2015-05-08

    Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates, consistency within and among components, alongside methodology and data limitations. CO2 emissionsmore » from fossil fuel combustion and cement production (EFF) are based on energy statistics and cement production data, respectively, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover-change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models forced by observed climate, CO2, and land-cover-change (some including nitrogen–carbon interactions). We compare the mean land and ocean fluxes and their variability to estimates from three atmospheric inverse methods for three broad latitude bands. All uncertainties are reported as ±1σ;, reflecting the current capacity to characterise the annual estimates

  16. Global carbon budget 2014

    SciTech Connect (OSTI)

    Le Quéré, C.; Moriarty, R.; Andrew, R. M.; Peters, G. P.; Ciais, P.; Friedlingstein, P.; Jones, S. D.; Sitch, S.; Tans, P.; Arneth, A.; Boden, T. A.; Bopp, L.; Bozec, Y.; Canadell, J. G.; Chini, L. P.; Chevallier, F.; Cosca, C. E.; Harris, I.; Hoppema, M.; Houghton, R. A.; House, J. I.; Jain, A. K.; Johannessen, T.; Kato, E.; Keeling, R. F.; Kitidis, V.; Klein Goldewijk, K.; Koven, C.; Landa, C. S.; Landschützer, P.; Lenton, A.; Lima, I. D.; Marland, G.; Mathis, J. T.; Metzl, N.; Nojiri, Y.; Olsen, A.; Ono, T.; Peng, S.; Peters, W.; Pfeil, B.; Poulter, B.; Raupach, M. R.; Regnier, P.; Rödenbeck, C.; Saito, S.; Salisbury, J. E.; Schuster, U.; Schwinger, J.; Séférian, R.; Segschneider, J.; Steinhoff, T.; Stocker, B. D.; Sutton, A. J.; Takahashi, T.; Tilbrook, B.; van der Werf, G. R.; Viovy, N.; Wang, Y.-P.; Wanninkhof, R.; Wiltshire, A.; Zeng, N.

    2015-05-08

    Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates, consistency within and among components, alongside methodology and data limitations. CO2 emissions from fossil fuel combustion and cement production (EFF) are based on energy statistics and cement production data, respectively, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover-change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models forced by observed climate, CO2, and land-cover-change (some including nitrogen–carbon interactions). We compare the mean land and ocean fluxes and their variability to estimates from

  17. Deactivation by carbon of iron catalysts for indirect liquefaction

    SciTech Connect (OSTI)

    Bartholomew, C.H.

    1991-01-10

    Although promoted cobalt and iron catalysts for Fischer-Tropsch (FT) synthesis of gasoline feedstock were first developed more than three decades ago, a major technical problem still limiting the commercial use of these catalysts today is carbon deactivation. This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for FT synthesis, the objectives of which are to: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; and model the rates of deactivation of the same catalysts in fixed-bed reactors. To accomplish the above objectives, the project is divided into the following tasks: (1) determine the kinetics of reaction and of carbon deactivation during CO hydrogenation on Fe and Fe/K catalysts coated on monolith bodies. (2) Determine the reactivities and types of carbon deposited during reaction on the same catalysts from temperature-programmed-surface-reaction spectroscopy (TPSR) and transmission electron microscopy (TEM). Determine the types of iron carbides formed at various temperatures and H{sub 2}/CO ratios using x-ray diffraction and Moessbauer spectroscopy. (3) Develop mathematical deactivation models which include heat and mass transport contributions for FT synthesis is packed-bed reactors. Progress to date is described. 48 refs., 3 figs., 1 tab.

  18. ARM - Measurement - Organic Carbon Concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsOrganic Carbon Concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Organic Carbon Concentration The concentration of carbon bound in organic compounds. Categories Aerosols Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available

  19. ARM - Sources of Atmospheric Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sources of Atmospheric Carbon Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Sources of Atmospheric Carbon Atmospheric carbon represented a steady state system, where influx equaled outflow, before the Industrial Revolution. Currently, it is no longer a steady state system because the

  20. Carbon Joins the Magnetic Club

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Release 29 May 2007 Carbon Joins the Magnetic Club summary written by Brad Plummer, SLAC Communication Office The exclusive club of magnetic elements officially has a new member-carbon. Using a proton beam and advanced x-ray techniques, SLAC researchers in collaboration with colleagues from LBNL and the University of Leipzig in Germany have finally put to rest doubts about carbon's ability to be made magnetic. "In the past, some groups thought they had discovered magnetic

  1. Carbon Sequestration Atlas IV Video

    ScienceCinema (OSTI)

    Rodosta, Traci

    2014-06-27

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  2. Carbon Stars | Open Energy Information

    Open Energy Info (EERE)

    Stars Jump to: navigation, search Name: Carbon Stars Place: Netherlands Sector: Services Product: General Financial & Legal Services ( Private family-controlled ) References:...

  3. Carbon-assisted flyer plates

    DOE Patents [OSTI]

    Stahl, David B.; Paisley, Dennis L.

    1994-01-01

    A laser driven flyer plate utilizing an optical fiber connected to a laser. The end of the optical fiber has a layer of carbon and a metal layer deposited onto it. The carbon layer provides the laser induced plasma which is superior to the plasma produced from most metals. The carbon layer plasma is capable of providing a flatter flyer plate, converting more of the laser energy to driving plasma, promoting a higher flyer plate acceleration, and providing a more uniform pulse behind the plate. In another embodiment, the laser is in optical communication with a substrate onto which a layer of carbon and a layer of metal have been deposited.

  4. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  5. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  6. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  7. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  8. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  9. Carbon Sequestration Atlas IV Video

    SciTech Connect (OSTI)

    Rodosta, Traci

    2013-04-19

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  10. Soil metagenomics and carbon cycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Establishing a foundational understanding of the microbial and ecosystem factors that ... understanding of the microbial and ecosystem factors that control carbon partitioning ...

  11. The National Carbon Capture Center

    Office of Scientific and Technical Information (OSTI)

    ... Laboratory OD Outer Diameter OSU Ohio State University PC Pulverized Coal PC4 Post-Combustion Carbon Capture Center PCC Post-Combustion CO 2 Capture PCD Particulate ...

  12. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  13. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  14. Carbonate Deposition | Open Energy Information

    Open Energy Info (EERE)

    Alteration Products Carbonate deposits come in many forms and sometimes develop into spectacular colorful terraces such as these at Mammoth Hot Springs in Yellowstone National...

  15. TESTING GUIDELINES FOR TECHNETIUM-99 ABSORPTION ON ACTIVATED CARBON

    SciTech Connect (OSTI)

    BYRNES ME

    2010-09-08

    CH2M HILL Plateau Remediation Company (CHPRC) is currently evaluating the potential use of activated carbon adsorption for removing technetium-99 from groundwater as a treatment method for the Hanford Site's 200 West Area groundwater pump-and-treat system. The current pump-and-treat system design will include an ion-exchange (IX) system for selective removal of technetium-99 from selected wells prior to subsequent treatment of the water in the central treatment system. The IX resin selected for technetium-99 removal is Purolite A530E. The resin service life is estimated to be approximately 66.85 days at the design technetium-99 loading rate, and the spent resin must be replaced because it cannot be regenerated. The resulting operating costs associated with resin replacement every 66.85 days are estimated at $0.98 million/year. Activated carbon pre-treatment is being evaluated as a potential cost-saving measure to offset the high operating costs associated with frequent IX resin replacement. This document is preceded by the Literature Survey of Technetium-99 Groundwater Pre-Treatment Option Using Granular Activated Carbon (SGW-43928), which identified and evaluated prior research related to technetium-99 adsorption on activated carbon. The survey also evaluated potential operating considerations for this treatment approach for the 200 West Area. The preliminary conclusions of the literature survey are as follows: (1) Activated carbon can be used to selectively remove technetium-99 from contaminated groundwater. (2) Technetium-99 adsorption onto activated carbon is expected to vary significantly based on carbon types and operating conditions. For the treatment approach to be viable at the Hanford Site, activated carbon must be capable of achieving a designated minimum technetium-99 uptake. (3) Certain radionuclides known to be present in 200 West Area groundwater are also likely to adsorb onto activated carbon. (4) Organic solvent contaminants of concern (COCs) will

  16. Carbon dioxide and climate

    SciTech Connect (OSTI)

    Not Available

    1990-10-01

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  17. Code System for Calculating the Radial and Axial Neutron Diffusion Coefficients in One-Group and Multigroup Theory.

    Energy Science and Technology Software Center (OSTI)

    1985-10-10

    MARCOPOLO calculates the radial and axial diffusion coefficients in one-group and multi-group theory for a cylinderized cell (Wigner-Seitz theory) with several concentric zones according to the isotropic shock or linear anisotropic shock hypotheses.

  18. Test particle study of ion transport in drift type turbulence

    SciTech Connect (OSTI)

    Vlad, M.; Spineanu, F.

    2013-12-15

    Ion transport regimes in drift type turbulence are determined in the frame of a realistic model for the turbulence spectrum based on numerical simulations. The model includes the drift of the potential with the effective diamagnetic velocity, turbulence anisotropy, and dominant waves. The effects of the zonal flow modes are also analyzed. A semi-analytical method that is able to describe trajectory stochastic trapping or eddying is used for obtaining the transport coefficients as function of the parameters of the turbulence. Analytical approximations of the transport coefficients are derived from the results. They show the transition from Bohm to gyro-Bohm scaling as plasma size increases in very good agreement with the numerical simulations.

  19. Carbon Nanotube Nanocomposites, Methods of Making Carbon Nanotube

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanocomposites, and Devices Comprising the Nanocomposites - Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Industrial Technologies Industrial Technologies Find More Like This Return to Search Carbon Nanotube Nanocomposites, Methods of Making Carbon Nanotube Nanocomposites, and Devices Comprising the Nanocomposites Battelle Memorial Institute Contact BMI About This Technology Technology Marketing SummaryThis technology describes methods to fabricate supercapacitors using

  20. Quasi-steady carbon plasma source for neutral beam injector

    SciTech Connect (OSTI)

    Koguchi, H. Sakakita, H.; Kiyama, S.; Shimada, T.; Sato, Y.; Hirano, Y.

    2014-02-15

    Carbon plasma is successfully sustained during 1000 s without any carrier gas in the bucket type ionization chamber with cusp magnetic field. Every several seconds, seed plasmas having ∼3 ms duration time are injected into the ionization chamber by a shunting arch plasma gun. The weakly ionized carbon plasma ejected from the shunting arch is also ionized by 2.45 GHz microwave at the electron cyclotron resonance surface and the plasma can be sustained even in the interval of gun discharges. Control of the gun discharge interval allows to keep high pressure and to sustain the plasma for long duration.

  1. Carbon Storage Research and Development | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Capture Carbon Capture This GIF shows how CO2 emissions vary across the United States. Each bar represents a 50x50 kilometer grid. Bar height is proportional to total CO2 emissions and bar color represents the type of CO2 emissions. Red bars represent proportionately more CO2 emissions from electricity generation (coal, gas and oil). Green bars represent CO2 emissions by other sources (such as ethanol production, iron-steel production and cement manufacture). Yellow/orange bars signify a

  2. Plastic Bags Might Kickstart the Carbon Capture Industry | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Plastic Bags Might Kickstart the Carbon Capture Industry Plastic Bags Might Kickstart the Carbon Capture Industry May 6, 2016 - 5:46pm Addthis This GIF shows how CO2 emissions vary across the United States. Each bar represents a 50x50 kilometer grid. Bar height is proportional to total CO2 emissions and bar color represents the type of CO2 emissions. Red bars represent proportionately more CO2 emissions from electricity generation (coal, gas and oil). Green bars represent CO2

  3. Carbon Fiber Technology Facility | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Fiber Technology Facility Carbon Fiber Technology Facility 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting lm003_warren_2012_o.pdf (3.98 MB) More Documents & Publications Carbon Fiber Technology Facility Carbon Fiber Pilot Plant and Research Facilities Vehicle Technologies Office Merit Review 2014: Carbon Fiber Technology Facility

  4. Solar Fuels and Carbon Cycle 2.0 (Carbon Cycle 2.0) (Conference...

    Office of Scientific and Technical Information (OSTI)

    Solar Fuels and Carbon Cycle 2.0 (Carbon Cycle 2.0) Citation Details In-Document Search Title: Solar Fuels and Carbon Cycle 2.0 (Carbon Cycle 2.0) Paul Alivisatos, LBNL Director...

  5. Magnetoresistance, electrical conductivity, and Hall effect of glassy carbon

    SciTech Connect (OSTI)

    Baker, D.F.

    1983-02-01

    These properties of glassy carbon heat treated for three hours between 1200 and 2700/sup 0/C were measured from 3 to 300/sup 0/K in magnetic fields up to 5 tesla. The magnetoresistance was generally negative and saturated with reciprocal temperature, but still increased as a function of magnetic field. The maximum negative magnetoresistance measured was 2.2% for 2700/sup 0/C material. Several models based on the negative magnetoresistance being proportional to the square of the magnetic moment were attempted; the best fit was obtained for the simplest model combining Curie and Pauli paramagnetism for heat treatments above 1600/sup 0/C. Positive magnetoresistance was found only in less than 1600/sup 0/C treated glassy carbon. The electrical conductivity, of the order of 200 (ohm-cm)/sup -1/ at room temperature, can be empirically written as sigma = A + Bexp(-CT/sup -1/4) - DT/sup -1/2. The Hall coefficient was independent of magnetic field, insensitive to temperature, but was a strong function of heat treatment temperature, crossing over from negative to positive at about 1700/sup 0/C and ranging from -0.048 to 0.126 cm/sup 3//coul. The idea of one-dimensional filaments in glassy carbon suggested by the electrical conductivity is compatible with the present consensus view of the microstructure.

  6. Laboratory-scale sodium-carbonate aggregate concrete interactions. [LMFBR

    SciTech Connect (OSTI)

    Westrich, H.R.; Stockman, H.W.; Suo-Anttila, A.

    1983-09-01

    A series of laboratory-scale experiments was made at 600/sup 0/C to identify the important heat-producing chemical reactions between sodium and carbonate aggregate concretes. Reactions between sodium and carbonate aggregate were found to be responsible for the bulk of heat production in sodium-concrete tests. Exothermic reactions were initiated at 580+-30/sup 0/C for limestone and dolostone aggregates as well as for hydrated limestone concrete, and at 540+-10/sup 0/C for dehydrated limestone concrete, but were ill-defined for dolostone concrete. Major reaction products included CaO, MgO, Na/sub 2/CO/sub 3/, Na/sub 2/O, NaOH, and elemental carbon. Sodium hydroxide, which forms when water is released from cement phases, causes slow erosion of the concrete with little heat production. The time-temperature profiles of these experiments have been modeled with a simplified version of the SLAM computer code, which has allowed derivation of chemical reaction rate coefficients.

  7. Core Carbon Group AS CCG | Open Energy Information

    Open Energy Info (EERE)

    Carbon Group AS CCG Jump to: navigation, search Name: Core Carbon Group AS (CCG) Place: Copenhagen, Denmark Zip: DK-1074 Sector: Carbon Product: The Core Carbon Group (formerly...

  8. Record Seebeck coefficient and extremely low thermal conductivity in nanostructured SnSe

    SciTech Connect (OSTI)

    Serrano-Sánchez, F.; Gharsallah, M.; Nemes, N. M.; Mompean, F. J.; Martínez, J. L.; Alonso, J. A.

    2015-02-23

    SnSe has been prepared by arc-melting, as mechanically robust pellets, consisting of highly oriented polycrystals. This material has been characterized by neutron powder diffraction (NPD), scanning electron microscopy, and transport measurements. A microscopic analysis from NPD data demonstrates a quite perfect stoichiometry SnSe{sub 0.98(2)} and a fair amount of anharmonicity of the chemical bonds. The Seebeck coefficient reaches a record maximum value of 668 μV K{sup −1} at 380 K; simultaneously, this highly oriented sample exhibits an extremely low thermal conductivity lower than 0.1 W m{sup −1} K{sup −1} around room temperature, which are two of the main ingredients of good thermoelectric materials. These excellent features exceed the reported values for this semiconducting compound in single crystalline form in the moderate-temperatures region and highlight its possibilities as a potential thermoelectric material.

  9. On-Line Measurement of Lubricant Film Thickness Using Ultrasonic Reflection Coefficients

    SciTech Connect (OSTI)

    Drinkwater, B.W.; Dwyer-Joyce, R.S.; Harper, P.

    2004-02-26

    The ultrasonic reflectivity of a lubricant layer between two solid bodies depends on the ultrasonic frequency, the acoustic properties of the liquid and solid, and the layer thickness. In this paper, ultrasonic reflectivity measurements are used as a method for determining the thickness of lubricating films in bearing systems. An ultrasonic transducer is positioned on the outside of a bearing shell such that the wave is focused on the lubricant film layer. For a particular lubricant film the reflected pulse is processed to give a reflection coefficient spectrum. The lubricant film thickness is then obtained from either the layer stiffness or the resonant frequency. The method has been validated using static fluid wedges and the elastohydrodynamic film formed between a ball sliding on a flat. Film thickness values in the range 50-500 nm were recorded which agreed well with theoretical film formation predictions.

  10. Improved Coefficient Calculator for the California Energy Commission 6 Parameter Photovoltaic Module Model

    SciTech Connect (OSTI)

    Dobos, A. P.

    2012-05-01

    This paper describes an improved algorithm for calculating the six parameters required by the California Energy Commission (CEC) photovoltaic (PV) Calculator module model. Rebate applications in California require results from the CEC PV model, and thus depend on an up-to-date database of module characteristics. Currently, adding new modules to the database requires calculating operational coefficients using a general purpose equation solver - a cumbersome process for the 300+ modules added on average every month. The combination of empirical regressions and heuristic methods presented herein achieve automated convergence for 99.87% of the 5487 modules in the CEC database and greatly enhance the accuracy and efficiency by which new modules can be characterized and approved for use. The added robustness also permits general purpose use of the CEC/6 parameter module model by modelers and system analysts when standard module specifications are known, even if the module does not exist in a preprocessed database.

  11. Electrical conductivity, Seebeck coefficient, and defect structure of Ca-doped YCrO sub 3

    SciTech Connect (OSTI)

    Carini, G.F. II.

    1990-01-01

    High temperature electrical conductivity, Seebeck coefficient, and thermogravimetric measurements were made as a function of oxygen activity to investigate the electrical transport behavior and defect structure of Ca-doped YCrO{sub 3}. Defect models were developed to correlate the electrical conductivity and thermogravimetric data by relating the concentration of charge carriers to the acceptor dopant and oxygen vacancy concentrations. These relations were found to adequately explain the experimental data. Thermodynamic properties were calculated which were consistent with the model. Calculations of the carrier concentrations, the activation energies, and the mobilities were also performed. The analysis of the electrical conductivity, Seebeck and mobility data suggested that the conduction process in Ca-doped YCrO{sub 3} occurs via the small polaron hopping mechanism. Kroger-Vink diagrams showing the regions of stability with respect to oxygen activity and temperature were constructed.

  12. Utilization of sensitivity coefficients to guide the design of a thermal battery

    SciTech Connect (OSTI)

    Blackwell, B.F.; Dowding, K.J.; Cochran, R.J.; Dobranich, D.

    1998-08-01

    Equations are presented to describe the sensitivity of the temperature field in a heat-conducting body to changes in the volumetric heat source and volumetric heat capacity. These sensitivity equations, along with others not presented, are applied to a thermal battery problem to compute the sensitivity of the temperature field to 19 model input parameters. Sensitivity coefficients, along with assumed standard deviation in these parameters, are used to estimate the uncertainty in the temperature prediction. From the 19 parameters investigated, the battery cell heat source and volumetric heat capacity were clearly identified as being the major contributors to the overall uncertainty in the temperature predictions. The operational life of the thermal battery was shown to be very sensitive to uncertainty in these parameters.

  13. Understanding Carbon Sequestration Options in the United States: Capabilities of a Carbon Management Geographic Information System

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Dooley, James J.; Brown, Daryl R.; Mizoguchi, Akiyoshi; Shiozaki, Mai

    2001-04-03

    While one can discuss various sequestration options at a national or global level, the actual carbon management approach is highly site specific. In response to the need for a better understanding of carbon management options, Battelle in collaboration with Mitsubishi Corporation, has developed a state-of-the-art Geographic Information System (GIS) focused on carbon capture and sequestration opportunities in the United States. The GIS system contains information (e.g., fuel type, location, vintage, ownership, rated capacity) on all fossil-fired generation capacity in the Untied States with a rated capacity of at least 100 MW. There are also data on other CO2 sources (i.e., natural domes, gas processing plants, etc.) and associated pipelines currently serving enhanced oil recovery (EOR) projects. Data on current and prospective CO2 EOR projects include location, operator, reservoir and oil characteristics, production, and CO2 source. The system also contains information on priority deep saline aquifers and coal bed methane basins with potential for sequestering CO2. The GIS application not only enables data storage, flexible map making, and visualization capabilities, but also facilitates the spatial analyses required to solve complex linking of CO2 sources with appropriate and cost-effective sinks. A variety of screening criteria (spatial, geophysical, and economic) can be employed to identify sources and sinks most likely amenable to deployment of carbon capture and sequestration systems. The system is easily updateable, allowing it to stay on the leading edge of capture and sequestration technology as well as the ever-changing business landscape. Our paper and presentation will describe the development of this GIS and demonstrate its uses for carbon management analysis.

  14. Instrument for stable high temperature Seebeck coefficient and resistivity measurements under controlled oxygen partial pressure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ihlefeld, Jon F.; Brown-Shaklee, Harlan James; Sharma, Peter Anand

    2015-04-28

    The transport properties of ceramic materials strongly depend on oxygen activity, which is tuned by changing the partial oxygen pressure (pO2) prior to and during measurement. Within, we describe an instrument for highly stable measurements of Seebeck coefficient and electrical resistivity at temperatures up to 1300 K with controlled oxygen partial pressure. An all platinum construction is used to avoid potential materials instabilities that can cause measurement drift. Two independent heaters are employed to establish a small temperature gradient for Seebeck measurements, while keeping the average temperature constant and avoiding errors associated with pO2-induced drifts in thermocouple readings. Oxygen equilibriummore » is monitored using both an O2 sensor and the transient behavior of the resistance as a proxy. A pO2 range of 10-25–100 atm can be established with appropriate gas mixtures. Seebeck measurements were calibrated against a high purity platinum wire, Pt/Pt–Rh thermocouple wire, and a Bi2Te3 Seebeck coefficient Standard Reference Material. To demonstrate the utility of this instrument for oxide materials we present measurements as a function of pO2 on a 1 % Nb-doped SrTiO3 single crystal, and show systematic changes in properties consistent with oxygen vacancy defect chemistry. Thus, an approximately 11% increase in power factor over a pO2 range of 10-19–10-8 atm at 973 K for the donor-doped single crystals is observed.« less

  15. Ceramic materials with low thermal conductivity and low coefficients of thermal expansion

    DOE Patents [OSTI]

    Brown, J.; Hirschfeld, D.; Liu, D.M.; Yang, Y.; Li, T.; Swanson, R.E.; Van Aken, S.; Kim, J.M.

    1992-04-07

    Compositions, having the general formula (Ca[sub x]Mg[sub 1[minus]x])Zr[sub 4](PO[sub 4])[sub 6] where x is between 0.5 and 0.99, are produced by solid state and sol-gel processes. In a preferred embodiment, when x is between 0.5 and 0.8, the MgCZP materials have near-zero coefficients of thermal expansion. The MgCZPs of the present invention also show unusually low thermal conductivities, and are stable at high temperatures. Macrostructures formed from MgCZP are useful in a wide variety of high-temperature applications. In a preferred process, calcium, magnesium, and zirconium nitrate solutions have their pH adjusted to between 7 and 9 either before or after the addition of ammonium dihydrogen phosphate. After dehydration to a gel, and calcination at temperatures in excess of 850 C for approximately 16 hours, single phase crystalline MgCZP powders with particle sizes ranging from approximately 20 nm to 50 nm result. The MgCZP powders are then sintered at temperatures ranging from 1200 C to 1350 C to form solid macrostructures with near-zero bulk coefficients of thermal expansion and low thermal conductivities. Porous macrostructures of the MgCZP powders of the present invention are also formed by combination with a polymeric powder and a binding agent, and sintering at high temperatures. The porosity of the resulting macrostructures can be adjusted by varying the particle size of the polymeric powder used. 7 figs.

  16. Ceramic materials with low thermal conductivity and low coefficients of thermal expansion

    DOE Patents [OSTI]

    Brown, Jesse; Hirschfeld, Deidre; Liu, Dean-Mo; Yang, Yaping; Li, Tingkai; Swanson, Robert E.; Van Aken, Steven; Kim, Jin-Min

    1992-01-01

    Compositions having the general formula (Ca.sub.x Mg.sub.1-x)Zr.sub.4 (PO.sub.4).sub.6 where x is between 0.5 and 0.99 are produced by solid state and sol-gel processes. In a preferred embodiment, when x is between 0.5 and 0.8, the MgCZP materials have near-zero coefficients of thermal expansion. The MgCZPs of the present invention also show unusually low thermal conductivities, and are stable at high temperatures. Macrostructures formed from MgCZP are useful in a wide variety of high-temperature applications. In a preferred process, calcium, magnesium, and zirconium nitrate solutions have their pH adjusted to between 7 and 9 either before or after the addition of ammonium dihydrogen phosphate. After dehydration to a gel, and calcination at temperatures in excess of 850.degree. C. for approximately 16 hours, single phase crystalline MgCZP powders with particle sizes ranging from approximately 20 nm to 50 nm result. The MgCZP powders are then sintered at temperatures ranging from 1200.degree. C. to 1350.degree. C. to form solid macrostructures with near-zero bulk coefficients of thermal expansion and low thermal conductivities. Porous macrostructures of the MgCZP powders of the present invention are also formed by combination with a polymeric powder and a binding agent, and sintering at high temperatures. The porosity of the resulting macrostructures can be adjusted by varying the particle size of the polymeric powder used.

  17. Instrument for stable high temperature Seebeck coefficient and resistivity measurements under controlled oxygen partial pressure

    SciTech Connect (OSTI)

    Ihlefeld, Jon F.; Brown-Shaklee, Harlan James; Sharma, Peter Anand

    2015-04-28

    The transport properties of ceramic materials strongly depend on oxygen activity, which is tuned by changing the partial oxygen pressure (pO2) prior to and during measurement. Within, we describe an instrument for highly stable measurements of Seebeck coefficient and electrical resistivity at temperatures up to 1300 K with controlled oxygen partial pressure. An all platinum construction is used to avoid potential materials instabilities that can cause measurement drift. Two independent heaters are employed to establish a small temperature gradient for Seebeck measurements, while keeping the average temperature constant and avoiding errors associated with pO2-induced drifts in thermocouple readings. Oxygen equilibrium is monitored using both an O2 sensor and the transient behavior of the resistance as a proxy. A pO2 range of 10-25–100 atm can be established with appropriate gas mixtures. Seebeck measurements were calibrated against a high purity platinum wire, Pt/Pt–Rh thermocouple wire, and a Bi2Te3 Seebeck coefficient Standard Reference Material. To demonstrate the utility of this instrument for oxide materials we present measurements as a function of pO2 on a 1 % Nb-doped SrTiO3 single crystal, and show systematic changes in properties consistent with oxygen vacancy defect chemistry. Thus, an approximately 11% increase in power factor over a pO2 range of 10-19–10-8 atm at 973 K for the donor-doped single crystals is observed.

  18. Permafrost soils and carbon cycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ping, C. L.; Jastrow, J. D.; Jorgenson, M. T.; Michaelson, G. J.; Shur, Y. L.

    2015-02-05

    Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environment. These efforts significantly increased estimates of the amount of organic carbon stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enormous organic carbon stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global carbon cycle and the potential vulnerability of the region's soil organic carbon (SOC) stocks to changing climatic conditions. Inmore » this review, we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils, and discuss their effects on soil structures and on organic matter distributions within the soil profile. We then examine the quantity of organic carbon stored in permafrost-region soils, as well as the characteristics, intrinsic decomposability, and potential vulnerability of this organic carbon to permafrost thaw under a warming climate. Overall, frozen conditions and cryopedogenic processes, such as cryoturbation, have slowed decomposition and enhanced the sequestration of organic carbon in permafrost-affected soils over millennial timescales. Due to the low temperatures, the organic matter in permafrost soils is often less humified than in more temperate soils, making some portion of this stored organic carbon relatively vulnerable to mineralization upon thawing of permafrost.« less

  19. Natural materials for carbon capture.

    SciTech Connect (OSTI)

    Myshakin, Evgeniy M.; Romanov, Vyacheslav N.; Cygan, Randall Timothy

    2010-11-01

    Naturally occurring clay minerals provide a distinctive material for carbon capture and carbon dioxide sequestration. Swelling clay minerals, such as the smectite variety, possess an aluminosilicate structure that is controlled by low-charge layers that readily expand to accommodate water molecules and, potentially, carbon dioxide. Recent experimental studies have demonstrated the efficacy of intercalating carbon dioxide in the interlayer of layered clays but little is known about the molecular mechanisms of the process and the extent of carbon capture as a function of clay charge and structure. A series of molecular dynamics simulations and vibrational analyses have been completed to assess the molecular interactions associated with incorporation of CO2 in the interlayer of montmorillonite clay and to help validate the models with experimental observation.

  20. Method for producing carbon nanotubes

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Chen, Chun-Ku

    2006-02-14

    Method for producing carbon nanotubes. Carbon nanotubes were prepared using a low power, atmospheric pressure, microwave-generated plasma torch system. After generating carbon monoxide microwave plasma, a flow of carbon monoxide was directed first through a bed of metal particles/glass beads and then along the outer surface of a ceramic tube located in the plasma. As a flow of argon was introduced into the plasma through the ceramic tube, ropes of entangled carbon nanotubes, attached to the surface of the tube, were produced. Of these, longer ropes formed on the surface portion of the tube located in the center of the plasma. Transmission electron micrographs of individual nanotubes revealed that many were single-walled.

  1. Carbon Trust CECIC JV | Open Energy Information

    Open Energy Info (EERE)

    CECIC JV Jump to: navigation, search Name: Carbon Trust & CECIC JV Place: China Sector: Carbon Product: China-based JV innovator and transferrer of low carbon technology in China....

  2. Mandarin Global Carbon Ltd | Open Energy Information

    Open Energy Info (EERE)

    Mandarin Global Carbon Ltd Jump to: navigation, search Name: Mandarin Global Carbon Ltd Place: Londaon, Greater London, United Kingdom Zip: W1S 1TD Sector: Carbon, Hydro Product:...

  3. First Carbon Fund Ltd | Open Energy Information

    Open Energy Info (EERE)

    Fund Ltd Jump to: navigation, search Name: First Carbon Fund Ltd Place: London, Greater London, United Kingdom Zip: EC1V 9EE Sector: Carbon Product: First Carbon Fund Ltd., acts as...

  4. CarbonFree Technology | Open Energy Information

    Open Energy Info (EERE)

    CarbonFree Technology Jump to: navigation, search Logo: CarbonFree Technology Name: CarbonFree Technology Address: 22 St. Clair Ave. E., Suite 1103 Place: Toronto, Ontario Country:...

  5. SEQUESTERING CARBON DIOXIDE IN COALBEDS

    SciTech Connect (OSTI)

    K.A.M. Gasem; R.L. Robinson, Jr.; J.E. Fitzgerald; Z. Pan; M. Sudibandriyo

    2003-04-30

    The authors' long-term goal is to develop accurate prediction methods for describing the adsorption behavior of gas mixtures on solid adsorbents over complete ranges of temperature, pressure, and adsorbent types. The originally-stated, major objectives of the current project are to: (1) measure the adsorption behavior of pure CO{sub 2}, methane, nitrogen, and their binary and ternary mixtures on several selected coals having different properties at temperatures and pressures applicable to the particular coals being studied, (2) generalize the adsorption results in terms of appropriate properties of the coals to facilitate estimation of adsorption behavior for coals other than those studied experimentally, (3) delineate the sensitivity of the competitive adsorption of CO{sub 2}, methane, and nitrogen to the specific characteristics of the coal on which they are adsorbed; establish the major differences (if any) in the nature of this competitive adsorption on different coals, and (4) test and/or develop theoretically-based mathematical models to represent accurately the adsorption behavior of mixtures of the type for which measurements are made. As this project developed, an important additional objective was added to the above original list. Namely, we were encouraged to interact with industry and/or governmental agencies to utilize our expertise to advance the state of the art in coalbed adsorption science and technology. As a result of this additional objective, we participated with the Department of Energy and industry in the measurement and analysis of adsorption behavior as part of two distinct investigations. These include (a) Advanced Resources International (ARI) DOE Project DE-FC26-00NT40924, ''Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on Wet Tiffany Coal'', and (b) the DOE-NETL Project, ''Round Robin: CO{sub 2} Adsorption on Selected Coals''. These activities, contributing directly to the DOE projects listed above, also

  6. Refined BCF-type boundary conditions for mesoscale surface step dynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Renjie; Ackerman, David M.; Evans, James W.

    2015-06-24

    Deposition on a vicinal surface with alternating rough and smooth steps is described by a solid-on-solid model with anisotropic interactions. Kinetic Monte Carlo (KMC) simulations of the model reveal step pairing in the absence of any additional step attachment barriers. We explore the description of this behavior within an analytic Burton-Cabrera-Frank (BCF)-type step dynamics treatment. Without attachment barriers, conventional kinetic coefficients for the rough and smooth steps are identical, as are the predicted step velocities for a vicinal surface with equal terrace widths. However, we determine refined kinetic coefficients from a two-dimensional discrete deposition-diffusion equation formalism which accounts for stepmore » structure. These coefficients are generally higher for rough steps than for smooth steps, reflecting a higher propensity for capture of diffusing terrace adatoms due to a higher kink density. Such refined coefficients also depend on the local environment of the step and can even become negative (corresponding to net detachment despite an excess adatom density) for a smooth step in close proximity to a rough step. Incorporation of these refined kinetic coefficients into a BCF-type step dynamics treatment recovers quantitatively the mesoscale step-pairing behavior observed in the KMC simulations.« less

  7. Refined BCF-type boundary conditions for mesoscale surface step dynamics

    SciTech Connect (OSTI)

    Zhao, Renjie; Ackerman, David M.; Evans, James W.

    2015-06-24

    Deposition on a vicinal surface with alternating rough and smooth steps is described by a solid-on-solid model with anisotropic interactions. Kinetic Monte Carlo (KMC) simulations of the model reveal step pairing in the absence of any additional step attachment barriers. We explore the description of this behavior within an analytic Burton-Cabrera-Frank (BCF)-type step dynamics treatment. Without attachment barriers, conventional kinetic coefficients for the rough and smooth steps are identical, as are the predicted step velocities for a vicinal surface with equal terrace widths. However, we determine refined kinetic coefficients from a two-dimensional discrete deposition-diffusion equation formalism which accounts for step structure. These coefficients are generally higher for rough steps than for smooth steps, reflecting a higher propensity for capture of diffusing terrace adatoms due to a higher kink density. Such refined coefficients also depend on the local environment of the step and can even become negative (corresponding to net detachment despite an excess adatom density) for a smooth step in close proximity to a rough step. Incorporation of these refined kinetic coefficients into a BCF-type step dynamics treatment recovers quantitatively the mesoscale step-pairing behavior observed in the KMC simulations.

  8. Catalytic Growth of Macroscopic Carbon Nanofibers Bodies with Activated Carbon

    SciTech Connect (OSTI)

    Abdullah, N.; Muhammad, I. S.; Hamid, S. B. Abd.; Rinaldi, A.; Su, D. S.; Schlogl, R.

    2009-06-01

    Carbon-carbon composite of activated carbon and carbon nanofibers have been synthesized by growing Carbon nanofiber (CNF) on Palm shell-based Activated carbon (AC) with Ni catalyst. The composites are in an agglomerated shape due to the entanglement of the defective CNF between the AC particles forming a macroscopic body. The macroscopic size will allow the composite to be used as a stabile catalyst support and liquid adsorbent. The preparation of CNT/AC nanocarbon was initiated by pre-treating the activated carbon with nitric acid, followed by impregnation of 1 wt% loading of nickel (II) nitrate solutions in acetone. The catalyst precursor was calcined and reduced at 300 deg. C for an hour in each step. The catalytic growth of nanocarbon in C{sub 2}H{sub 4}/H{sub 2} was carried out at temperature of 550 deg. C for 2 hrs with different rotating angle in the fluidization system. SEM and N{sub 2} isotherms show the level of agglomeration which is a function of growth density and fluidization of the system. The effect of fluidization by rotating the reactor during growth with different speed give a significant impact on the agglomeration of the final CNF/AC composite and thus the amount of CNFs produced. The macrostructure body produced in this work of CNF/AC composite will have advantages in the adsorbent and catalyst support application, due to the mechanical and chemical properties of the material.

  9. Process for making hollow carbon spheres

    DOE Patents [OSTI]

    Luhrs, Claudia C.; Phillips, Jonathan; Richard, Monique N.; Knapp, Angela Michelle

    2013-04-16

    A hollow carbon sphere having a carbon shell and an inner core is disclosed. The hollow carbon sphere has a total volume that is equal to a volume of the carbon shell plus an inner free volume within the carbon shell. The inner free volume is at least 25% of the total volume. In some instances, a nominal diameter of the hollow carbon sphere is between 10 and 180 nanometers.

  10. Agreement Type Union

    National Nuclear Security Administration (NNSA)

    Type Union Local #/Name Number of Employees Project Labor Agreement International Association of Heat and Frost Insulators and Allied Workers 135 2 International Brothehood of Boilermakers, Iron Ship Builders, Blacksmith Forgers and Helpers 92 0 International Union of Bricklayers & Allied Craftsmen 13 0 Regional Council of Carpenters 1780 & 1977 13 Operative Plasterers and Cement Mason International Association Operative Plasterers and Cement Mason International Association 1

  11. TYPE OF OPERATION

    Office of Legacy Management (LM)

    ----------------- 0 Research & Development .a Production scale testing 0 Pilat Scale 0 Bench Scale Process 0 Thearetical Studies Cl Sample 84 Analysis 0 Production *i DiaposalKitorage Cl Facility Tybe q Government Sponsored Facility Other R.L- 6:e 14 1 1 ---------- --------- I I I TYPE OF CONTRACT ~-__-----------_ fl Prime *I 0 Subcantractbr Other infuriation (i.e., L.t + fixed fee, kit price, 0 Purchase Order time k mat*iik, gtc) /I -~---------'-t-----------~- ----------II----------------

  12. CUFR Tree Carbon Calculator | Open Energy Information

    Open Energy Info (EERE)

    Desktop Application Website: www.fs.fed.usccrctopicsurban-forestsctcc Cost: Free Language: English References: CUFR Tree Carbon Calculator1 Overview "The CUFR Tree Carbon...

  13. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng; Guiochon, Georges A; Liang, Chengdu

    2014-01-14

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  14. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng; Guiohon, Georges A; Liang, Chengdu

    2013-02-05

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  15. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng [Knoxville, TN; Guiochon, Georges A. [Farragut, TN; Liang, Chengdu [Knoxville, TN

    2008-11-11

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  16. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng; Guiochon, Georges A; Liang, Chengdu

    2011-02-22

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  17. Visualizing Individual Carbon Nanotubes with Optical Microscopy...

    Office of Scientific and Technical Information (OSTI)

    Published Article: Visualizing Individual Carbon Nanotubes with Optical Microscopy Title: Visualizing Individual Carbon Nanotubes with Optical Microscopy Authors: Novak, Michael A. ...

  18. Lignin-Derived Advanced Carbon Materials

    SciTech Connect (OSTI)

    Chatterjee, Sabornie; Saito, Tomonori

    2015-11-16

    Lignin is a highly abundant source of renewable carbon that can be considered as a valuable sustainable source of biobased materials. By applying specific pretreatments and manufacturing methods, it has been found that lignin can be converted into a variety of value-added carbon materials. However, the physical and chemical heterogeneities of lignin complicate its use as a feedstock. Herein, we discuss the lignin manufacturing process, the effects of pretreatments and manufacturing methods on the properties of product lignin, and structure–property relationships in various applications of lignin-derived carbon materials, such as carbon fibers, carbon mats, activated carbons, carbon films, and templated carbon.

  19. Timing Carbon Ltd | Open Energy Information

    Open Energy Info (EERE)

    Timing Carbon Ltd Jump to: navigation, search Name: Timing Carbon Ltd Place: Beijing, Beijing Municipality, China Zip: 100022 Product: UK registered, China based CDM and voluntary...

  20. Supercritical Carbon Dioxide / Reservoir Rock Chemical Interactions...

    Open Energy Info (EERE)

    Supercritical Carbon Dioxide Reservoir Rock Chemical Interactions Jump to: navigation, search Geothermal Lab Call Projects for Supercritical Carbon Dioxide Reservoir Rock...

  1. Carbon Trust Investments Ltd | Open Energy Information

    Open Energy Info (EERE)

    Investments Ltd Jump to: navigation, search Name: Carbon Trust Investments Ltd Place: United Kingdom Sector: Carbon Product: UK-based venture capital investment division of The...

  2. Campus Carbon Calculator | Open Energy Information

    Open Energy Info (EERE)

    Campus Carbon Calculator Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Campus Carbon Calculator AgencyCompany Organization: Clean Air-Cool Planet Phase: Create a...

  3. Carbon Capture Corporation | Open Energy Information

    Open Energy Info (EERE)

    Corporation Jump to: navigation, search Name: Carbon Capture Corporation Address: 7825 Fay Avenue Place: La Jolla, California Zip: 92037 Region: Southern CA Area Sector: Carbon...

  4. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

  5. Carbon Sequestration Initiative CSI | Open Energy Information

    Open Energy Info (EERE)

    Sequestration Initiative CSI Jump to: navigation, search Name: Carbon Sequestration Initiative (CSI) Place: Cambridge, Massachusetts Zip: MA 02139-4307 Sector: Carbon Product:...

  6. Carbon Trade Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ltd Jump to: navigation, search Name: Carbon Trade Ltd Place: Scotland, United Kingdom Zip: ML12 6HW Product: Scotland-based landfill gas project developer. References: Carbon...

  7. Intan Carbon Corporation | Open Energy Information

    Open Energy Info (EERE)

    Intan Carbon Corporation Jump to: navigation, search Name: Intan Carbon Corporation Place: Beijing, Beijing Municipality, China Zip: 100031 Sector: Efficiency Product:...

  8. BSMB Carbon Consult | Open Energy Information

    Open Energy Info (EERE)

    BSMB Carbon Consult Jump to: navigation, search Name: BSMB Carbon Consult Place: Brazil Product: Sao Paulo-based in-house resource of Banco Sumitomo Mitsui Brasileiro. References:...

  9. Carbon Bank Ireland | Open Energy Information

    Open Energy Info (EERE)

    Ireland Jump to: navigation, search Name: Carbon Bank Ireland Place: Nevada Zip: 89411 Product: Investment bank focused on CDM projects. References: Carbon Bank Ireland1 This...

  10. Carbon Opportunity Group | Open Energy Information

    Open Energy Info (EERE)

    Opportunity Group Jump to: navigation, search Name: Carbon Opportunity Group Place: Chicago, Illinois Zip: 60606 Sector: Carbon, Services Product: Chicago-based firm that provides...

  11. Forest Carbon Index | Open Energy Information

    Open Energy Info (EERE)

    Forest Carbon Index Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Forest Carbon Index AgencyCompany Organization: Resources for the Future Partner: United Nations...

  12. Low Carbon Research Institute | Open Energy Information

    Open Energy Info (EERE)

    Research Institute Jump to: navigation, search Logo: Low Carbon Research Institute Name: Low Carbon Research Institute Address: King Edward VII Avenue CF10 3NB Place: Cardiff,...

  13. Common Carbon Metric | Open Energy Information

    Open Energy Info (EERE)

    Common Carbon Metric Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Common Carbon Metric AgencyCompany Organization: United Nations Environment Programme, World...

  14. Carbon Limiting Technologies | Open Energy Information

    Open Energy Info (EERE)

    Limiting Technologies Jump to: navigation, search Name: Carbon Limiting Technologies Place: London, Greater London, United Kingdom Zip: N1 8HA Sector: Carbon Product: UK-based...

  15. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Teng, H. Henry PI, The George Washington University PI, The George...

  16. Greenstone Carbon Management Ltd | Open Energy Information

    Open Energy Info (EERE)

    solutions provider to measure, manage and mitigate their carbon emissions and realise business and financial benefits. References: Greenstone Carbon Management Ltd.1 This...

  17. Fabrication and Characterization of Suspended Carbon Nanotube...

    Office of Scientific and Technical Information (OSTI)

    of Suspended Carbon Nanotube Devices in Liquid Citation Details In-Document Search Title: Fabrication and Characterization of Suspended Carbon Nanotube Devices in ...

  18. Planarized Unentangled Carbon Nanotube Arrays. (Conference) ...

    Office of Scientific and Technical Information (OSTI)

    Planarized Unentangled Carbon Nanotube Arrays. Citation Details In-Document Search Title: Planarized Unentangled Carbon Nanotube Arrays. Abstract not provided. Authors: Friedman, ...

  19. Energy-Related Carbon Emissions in Manufacturing

    Reports and Publications (EIA)

    2000-01-01

    Energy-related carbon emissions in manufacturing analysis and issues related to the energy use, energy efficiency, and carbon emission indicators.

  20. SciTech Connect: "carbon sequestration"

    Office of Scientific and Technical Information (OSTI)

    carbon sequestration" Find + Advanced Search Term Search Semantic Search Advanced Search All Fields: "carbon sequestration" Semantic Semantic Term Title: Full Text:...

  1. Development and Commercialization of Alternative Carbon Fiber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Office Merit Review 2015: Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor Fibers Advanced Oxidation & Stabilization of PAN-Based Carbon ...

  2. Energy-Related Carbon Emissions in Manufacturing

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Energy-Related Carbon Emissions Detailed Energy-Related Carbon Emissions All Industry Groups 1994 emissions Selected Industries Petroleum refining Chemicals Iron & Steel...

  3. Princeton Plasma Physics Lab - Carbon-free

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon-free Carbon-free en PPPL physicists simulate innovative method for starting up tokamaks without using a solenoid http:www.pppl.govnewspress-releases201601...

  4. USAID Carbon Calculator | Open Energy Information

    Open Energy Info (EERE)

    Application ComplexityEase of Use: Not Available Website: www.afolucarbon.org Cost: Free Language: English USAID Carbon Calculator Screenshot Logo: USAID Carbon Calculator This...

  5. Vertically Aligned Carbon Nanofiber based Biosensor Platform...

    Office of Scientific and Technical Information (OSTI)

    Vertically Aligned Carbon Nanofiber based Biosensor Platform for Glucose Sensor Citation Details In-Document Search Title: Vertically Aligned Carbon Nanofiber based Biosensor ...

  6. Aerosynthesis: Growths of Vertically Aligned Carbon Nanofibers...

    Office of Scientific and Technical Information (OSTI)

    Aerosynthesis: Growths of Vertically Aligned Carbon Nanofibers with Air DC Plasma Citation Details In-Document Search Title: Aerosynthesis: Growths of Vertically Aligned Carbon ...

  7. Manufacturing Energy and Carbon Footprint References | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing Energy and Carbon Footprint References footprintreferences.pdf (309.04 KB) More Documents & Publications 2010 Manufacturing Energy and Carbon Footprints: References ...

  8. Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one year of ...

  9. New Species of Cyanobacteria Forms Intracellular Carbonates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Species of Cyanobacteria Forms Intracellular Carbonates New Species of Cyanobacteria Forms Intracellular Carbonates Print Wednesday, 30 January 2013 00:00 A new species of ...

  10. Financing Residential Energy Efficiency with Carbon Offsets ...

    Broader source: Energy.gov (indexed) [DOE]

    Financing Residential Energy Efficiency with Carbon Offsets (2.6 MB) More Documents & Publications Financing Residential Energy Efficiency with Carbon Offsets Transcript Questions ...

  11. Financing Residential Energy Efficiency with Carbon Offsets

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Residential Energy Efficiency with Carbon Offsets Steve Erario Energy Programs Associate at Alarm.com March 13, 2013 2 * Steve Erario served as the Carbon Project ...

  12. ARM - Measurement - Carbon dioxide (CO2) flux

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon dioxide, a heavy, colorless greenhouse gas. Categories Atmospheric Carbon, Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  13. China Low Carbon Platform | Open Energy Information

    Open Energy Info (EERE)

    Low Carbon Platform Jump to: navigation, search Name China Low Carbon Platform AgencyCompany Organization Institute of Development Studies, Climate Change and Development Centre,...

  14. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate ...

  15. Porous templated pyrolytic carbons as electrocatalyst components...

    Office of Scientific and Technical Information (OSTI)

    Porous templated pyrolytic carbons as electrocatalyst components. Citation Details In-Document Search Title: Porous templated pyrolytic carbons as electrocatalyst components. ...

  16. Energy.gov Page Types

    Broader source: Energy.gov [DOE]

    Learn about the standard page types available in the Energy.gov Drupal content management system. For information about other available page types, or to request a new kind of page type, contact...

  17. Gas permeability of carbon aerogels

    SciTech Connect (OSTI)

    Kong, F.; LeMay, J.D.; Hulsey, S.S.; Alviso, C.T.; Pekala, R.W. (Chemistry and Materials Science Department, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States))

    1993-12-01

    Carbon aerogels are synthesized via the aqueous polycondensation of resorcinol with formaldehyde, followed by supercritical drying and subsequent pyrolysis at 1050 [degree]C. As a result of their interconnected porosity, ultrafine cell/pore size, and high surface area, carbon aerogels have many potential applications such as supercapacitors, battery electrodes, catalyst supports, and gas filters. The performance of carbon aerogels in the latter two applications depends on the permeability or gas flow conductance in these materials. By measuring the pressure differential across a thin specimen and the nitrogen gas flow rate in the viscous regime, the permeability of carbon aerogels was calculated from equations based upon Darcy's law. Our measurements show that carbon aerogels have permeabilities on the order of 10[sup [minus]12] to 10[sup [minus]10] cm[sup 2] over the density range from 0.05--0.44 g/cm[sup 3]. Like many other aerogel properties, the permeability of carbon aerogels follows a power law relationship with density, reflecting differences in the average mesopore size. Comparing the results from this study with the permeability of silica aerogels reported by other workers, we found that the permeability of aerogels is governed by a simple universal flow equation. This paper discusses the relationship between permeability, pore size, and density in carbon aerogels.

  18. First-principles binary diffusion coefficients for H, H2 and four normal alkanes + N2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jasper, Ahren W.; Kamarchik, Eugene; Miller, James A.; Klippenstein, Stephen J.

    2014-09-30

    Collision integrals related to binary (dilute gas) diffusion are calculated classically for six species colliding with N2. The most detailed calculations make no assumptions regarding the complexity of the potential energy surface, and the resulting classical collision integrals are in excellent agreement with previous semiclassical results for H + N2 and H2 + N2 and with recent experimental results for C n H2n+2 + N2, n = 2–4. The detailed classical results are used to test the accuracy of three simplifying assumptions typically made when calculating collision integrals: (1) approximating the intermolecular potential as isotropic, (2) neglecting the internal structuremore » of the colliders (i.e., neglecting inelasticity), and (3) employing unphysical R–12 repulsive interactions. The effect of anisotropy is found to be negligible for H + N2 and H2 + N2 (in agreement with previous quantum mechanical and semiclassical results for systems involving atomic and diatomic species) but is more significant for larger species at low temperatures. For example, the neglect of anisotropy decreases the diffusion coefficient for butane + N2 by 15% at 300 K. The neglect of inelasticity, in contrast, introduces only very small errors. Approximating the repulsive wall as an unphysical R–12 interaction is a significant source of error at all temperatures for the weakly interacting systems H + N2 and H2 + N2, with errors as large as 40%. For the normal alkanes in N2, which feature stronger interactions, the 12/6 Lennard–Jones approximation is found to be accurate, particularly at temperatures above –700 K where it predicts the full-dimensional result to within 5% (although with somewhat different temperature dependence). Overall, the typical practical approach of assuming isotropic 12/6 Lennard–Jones interactions is confirmed to be suitable for combustion applications except for weakly interacting systems, such as H + N2. For these systems, anisotropy and inelasticity

  19. Carbon films produced from ionic liquid carbon precursors

    DOE Patents [OSTI]

    Dai, Sheng; Luo, Huimin; Lee, Je Seung

    2013-11-05

    The invention is directed to a method for producing a film of porous carbon, the method comprising carbonizing a film of an ionic liquid, wherein the ionic liquid has the general formula (X.sup.+a).sub.x(Y.sup.-b).sub.y, wherein the variables a and b are, independently, non-zero integers, and the subscript variables x and y are, independently, non-zero integers, such that ax=by, and at least one of X.sup.+ and Y.sup.- possesses at least one carbon-nitrogen unsaturated bond. The invention is also directed to a composition comprising a porous carbon film possessing a nitrogen content of at least 10 atom %.

  20. Atmospheric carbon dioxide and the global carbon cycle

    SciTech Connect (OSTI)

    Trabalka, J R

    1985-12-01

    This state-of-the-art volume presents discussions on the global cycle of carbon, the dynamic balance among global atmospheric CO2 sources and sinks. Separate abstracts have been prepared for the individual papers. (ACR)

  1. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C. Joseph; Dispennette, John M.

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg.

  2. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg. 3 figs.

  3. Tailoring Pore Size of Nitrogen-Doped Hollow Carbon Nanospheres for Confi ning Sulfur in LithiumSulfur Batteries

    SciTech Connect (OSTI)

    Zhou, Weidong; Wang, Chong M.; Zhang, Quiglin; Abruna, Hector D.; He, Yang; Wang, Jiangwei; Mao, Scott X.; Xiao, Xingcheng

    2015-08-19

    Three types of nitrogen-doped hollow carbon spheres with different pore sized porous shells are prepared to investigate the performance of sulfur confinement. The reason that why no sulfur is observed in previous research is determined and it is successfully demonstrated that the sulfur/polysulfide will overflow the porous carbon during the lithiation process.

  4. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1999-04-27

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  5. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

    1999-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid partides being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

  6. Method for fabricating composite carbon foam

    DOE Patents [OSTI]

    Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

    2001-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

  7. Diffusional Motion of Redox Centers in Carbonate Electrolytes

    SciTech Connect (OSTI)

    Han, Kee Sung; Rajput, Nav Nidhi; Wei, Xiaoliang; Wang, Wei; Hu, Jian Z.; Persson, Kristin A.; Mueller, Karl T.

    2014-09-14

    Ferrocene (Fc) and N-(ferrocenylmethyl)-N,N-dimethyl-N-ethylammonium bistrifluoromethyl-sulfonimide (Fc1N112-TFSI) were dissolved in carbonate solvents and self diffusion coefficents (D) of solutes and solvents were measured by 1H and 19F pulsed field gradient (PFG) nuclear magnetic resonance (NMR) spectroscopy. The organic solvents were propylene carbonate (PC), ethyl methyl carbonate (EMC) and a ternary mixture that also includes ethylene carbonate (EC). Results from NMR studies over the temperature range of 0-50 C and for various concentrations (0.25 - 1.7 M) of Fc1N112-TFSI are compared to values of D simulated with classical molecular dynamics (MD). The measured self-diffusion coefficients gradually decreased as the Fc1N112-TFSI concentration increased in all solvents. Since the peaks for the two ions (Fc1N212 and TFSI) are separated in one-dimensional NMR spectra, separate diffusion coefficients could be measured and DTFSI is larger than DFc1N112 in all samples measured. The EC, PC and EMC have the same D in the neat solvent mixture and when Fc is dissolved in EC/PC/EMC at a concentration of 0.2 M, probably due to the interactions between common carbonyl structures within EC, PC and EMC. A difference in D (DPC < DEC < DEMC), and both a higher Ea for translational motion and higher effective viscosity for PC in the mixture containing Fc1N112-TFSI reflect the interaction between PC and Fc1N112+, which is a relatively stronger interaction than that between Fc1N112+ and other solvent species. In the EC/PC/EMC solution that is saturated with Fc1N112-TFSI, we find that DPC = DEC = DEMC and Fc1N112+ and all components of the EC/PC/EMC solution have the same Ea for translational motion, while the ratio DEC/PC/EMC/DFc1N112+ is approximately 3. These results reflect the lack of available free volume for independent diffusion in the saturated solution. The Fc1N112+ transference numbers lie around 0.4 and increases slightly as the temperature is increased in the PC and

  8. Diffusional motion of redox centers in carbonate electrolytes

    SciTech Connect (OSTI)

    Han, Kee Sung; Rajput, Nav Nidhi; Persson, Kristin A.; Wei, Xiaoliang; Wang, Wei; Hu, Jian Zhi; Mueller, Karl T.

    2014-09-14

    Ferrocene (Fc) and N-(ferrocenylmethyl)-N,N-dimethyl-N-ethylammonium bistrifluoromethyl-sulfonimide (Fc1N112-TFSI) were dissolved in carbonate solvents and self-diffusion coefficients (D) of solutes and solvents were measured by {sup 1}H and {sup 19}F pulsed field gradient nuclear magnetic resonance (NMR) spectroscopy. The organic solvents were propylene carbonate (PC), ethyl methyl carbonate (EMC), and a ternary mixture that also includes ethylene carbonate (EC). Results from NMR studies over the temperature range of 050 C and for various concentrations (0.251.7 M) of Fc1N112-TFSI are compared to values of D simulated with classical molecular dynamics (MD). The measured self-diffusion coefficients gradually decreased as the Fc1N112-TFSI concentration increased in all solvents. Since TFSI{sup ?} has fluoromethyl groups (CF{sub 3}), D{sub TFSI} could be measured separately and the values found are larger than those for D{sub Fc1N112} in all samples measured. The EC, PC, and EMC have the same D in the neat solvent mixture and when Fc is dissolved in EC/PC/EMC at a concentration of 0.2 M, probably due to the interactions between common carbonyl structures within EC, PC, and EMC. A difference in D (D{sub PC} < D{sub EC} < D{sub EMC}), and both a higher E{sub a} for translational motion and higher effective viscosity for PC in the mixture containing Fc1N112-TFSI reflect the interaction between PC and Fc1N112{sup +}, which is a relatively stronger interaction than that between Fc1N112{sup +} and other solvent species. In the EC/PC/EMC solution that is saturated with Fc1N112-TFSI, we find that D{sub PC} = D{sub EC} = D{sub EMC} and Fc1N112{sup +} and all components of the EC/PC/EMC solution have the same E{sub a} for translational motion, while the ratio D{sub EC/PC/EMC}/D{sub Fc1N112} is approximately 3. These results reflect the lack of available free volume for independent diffusion in the saturated solution. The Fc1N112{sup +} transference numbers lie around 0

  9. Heat transfer and flow resistance of a shell and plate-type evaporator

    SciTech Connect (OSTI)

    Uehara, H.; Stuhltraeger, E.; Miyara, A.; Murakami, H.; Miyazaki, K.

    1997-05-01

    The performance test of a shell-and-plate-type evaporator designed for OTEC plants, geothermal power plants, and heat pump systems is reported. This evaporator contains 30 plates with a unit area of 0.813 m{sup 2}, coated with aluminum powder on the working fluid side. Freon 22 is used as working fluid. Results show an overall heat transfer coefficient of about 5,000 W/(m{sup 2}K) when the heating water velocity is 1M/s. The mean boiling heat transfer coefficient is compared with a precious correlation proposed by Nakaoka and Uehara (1988). The water-side pressure loss is also reported.

  10. Self-lubricating carbon nanotube reinforced nickel matrix composites

    SciTech Connect (OSTI)

    Scharf, T. W.; Neira, A.; Hwang, J. Y.; Banerjee, R.; Tiley, J.

    2009-07-01

    Nickel (Ni)--multiwalled carbon nanotube (CNT) composites have been processed in a monolithic form using the laser-engineered net shape (LENS) processing technique. Auger electron spectroscopy maps determined that the nanotubes were well dispersed and bonded in the nickel matrix and no interfacial chemical reaction products were determined in the as-synthesized composites. Mechanisms of solid lubrication have been investigated by micro-Raman spectroscopy spatial mapping of the worn surfaces to determine the formation of tribochemical products. The Ni-CNT composites exhibit a self-lubricating behavior, forming an in situ, low interfacial shear strength graphitic film during sliding, resulting in a decrease in friction coefficient compared to pure Ni.

  11. Empirical correlations between the arrhenius' parameters of impurities' diffusion coefficients in CdTe crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shcherbak, L.; Kopach, O.; Fochuk, P.; James, R. B.; Bolotnikov, A. E.

    2015-01-21

    Understanding of self- and dopant-diffusion in semiconductor devices is essential to our being able to assure the formation of well-defined doped regions. In this paper, we compare obtained in the literature up to date the Arrhenius’ parameters (D=D0exp(–ΔEa/kT)) of point-defect diffusion coefficients and the I-VII groups impurities in CdTe crystals and films. We found that in the diffusion process there was a linear dependence between the pre-exponential factor, D0, and the activation energy, ΔEa, of different species: This was evident in the self-diffusivity and isovalent impurity Hg diffusivity as well as for the dominant IIIA and IVA groups impurities andmore » Chlorine, except for the fast diffusing elements (e.g., Cu and Ag), chalcogens O, S, and Se, halogens I and Br as well as the transit impurities Mn, Co, Fe. As a result, reasons of the lack of correspondence of the data to compensative dependence are discussed.« less

  12. Empirical correlations between the arrhenius' parameters of impurities' diffusion coefficients in CdTe crystals

    SciTech Connect (OSTI)

    Shcherbak, L.; Kopach, O.; Fochuk, P.; James, R. B.; Bolotnikov, A. E.

    2015-01-21

    Understanding of self- and dopant-diffusion in semiconductor devices is essential to our being able to assure the formation of well-defined doped regions. In this paper, we compare obtained in the literature up to date the Arrhenius’ parameters (D=D0exp(–ΔEa/kT)) of point-defect diffusion coefficients and the I-VII groups impurities in CdTe crystals and films. We found that in the diffusion process there was a linear dependence between the pre-exponential factor, D0, and the activation energy, ΔEa, of different species: This was evident in the self-diffusivity and isovalent impurity Hg diffusivity as well as for the dominant IIIA and IVA groups impurities and Chlorine, except for the fast diffusing elements (e.g., Cu and Ag), chalcogens O, S, and Se, halogens I and Br as well as the transit impurities Mn, Co, Fe. As a result, reasons of the lack of correspondence of the data to compensative dependence are discussed.

  13. Evaluation of solar heat gain coefficient for solar-control glazings and shading devices

    SciTech Connect (OSTI)

    Harrison, S.J.; Wonderen, S.J. van

    1998-10-01

    The determination of solar heat gain coefficient (SHGC) values for complex fenestration systems is required to evaluate building energy performance, to estimate peak electrical loads, and to ensure occupant comfort. In the past, simplified techniques have been used to calculate the values of SHGC for fenestration systems. As glazing systems that incorporate complex geometries become more common, test methods are required to evaluate these products and to aid in the development of new computational tools. Recently, a unique facility and test method for the experimental determination of SHGC values were developed and demonstrated for simple fenestration systems. The study described in this paper further applies this method to a variety of commercially available glazing and shading systems (e.g., heat-absorbing insulated glazing units (IGUs), reflective film and suspended film IGUs), and shading devices (i.e., slat blinds and shades). Testing was conducted in a solar simulator facility using a specially designed window calorimeter. The results of this study demonstrate the feasibility of the solar simulator-based test method for the evaluation of SHGC values for solar-control glazings and shading devices.

  14. Optoelectronic properties of Mg{sub 2}Si semiconducting layers with high absorption coefficients

    SciTech Connect (OSTI)

    Kato, Takashi; Sago, Yuichiro; Fujiwara, Hiroyuki

    2011-09-15

    In an attempt to develop a low-cost material for solar cell devices, polycrystalline magnesium silicide (poly-Mg{sub 2}Si) semiconducting layers have been prepared by applying rf magnetron sputtering using a Mg{sub 2}Si target. The optimum substrate temperature for the poly-Mg{sub 2}Si growth was found to be T{sub s} = 200 deg. C; the film deposition at higher temperatures leads to desorption of Mg atoms from the growing surface, while the amorphous phase formation occurs at room temperature. The poly-Mg{sub 2}Si layer deposited at T{sub s} = 200 deg. C shows the (111) preferential orientation with a uniform grain size of {approx}50 nm. The dielectric function of the poly-Mg{sub 2}Si layer has been determined accurately by spectroscopic ellipsometry. From the analysis, quite high absorption coefficients and an indirect gap of 0.77 eV in the poly-Mg{sub 2}Si layer have been confirmed. The above poly-Mg{sub 2}Si layer shows clear photoconductivity and can be applied as a narrow-gap bottom layer in multi-junction solar cell devices.

  15. Study of the absorption coefficient of alpha particles to lower hybrid waves in tokamak

    SciTech Connect (OSTI)

    Wang, Jianbing Zhang, Xianmei Yu, Limin Zhao, Xiang

    2014-02-12

    Part of the energy of the Lower Hybrid (LH) waves may be absorbed by the ? particles via the so-called perpendicular landau damping mechanism, which depends on various parameters of fusion reactors and the LH waves. In this article, we calculate the absorption coefficient ?{sub ?} of LH waves due to ? particles. Results show that, the ?{sub ?} increases with the parallel refraction index n{sub ?} while deceases with increasing the frequency of LH waves ?{sub LH} over a wide range. Higher background plasma temperature and toroidal magnetic field will increase the absorption, and there is a peak value of ?{sub ?} when n{sub e}?810{sup 19}m{sup ?3} for ITER-like scenario. The thermal corrections to the cold plasma dispersion relation will change the damping rate to a certain extent under some specific conditions. We have also evaluated the fraction of LH power absorbed by the alpha particles, ? ? 0.47% and 4.1% for an LH frequency of 5 GHz and 3.7 GHz respectively for ITER-like scenario. This work gives the effective reference for the choice of parameters of future fusion reactors.

  16. Generalized entering coefficients: A criterion for foam stability against oil in porous media

    SciTech Connect (OSTI)

    Bergeron, V.; Fagan, M.E.; Radke, C.J.

    1993-09-01

    The unique mobility-control properties of foam in porous media make it an attractive choice as an injection fluid for enhanced oil recovery. Unfortunately, in many cases oil has a major destabilizing effect on foam. Therefore, it is important to understand how oil destabilizes foam and what surfactant properties lead to increased stability against oil. To explain the stability of foam in porous media in the presence of oil, we generalize the ideas of spreading and entering behavior using Frumkin-Deryaguin wetting theory. This formulation overcomes the inherent deficiencies in the classical spreading and entering coefficients used to explain foam stability against oil. We find that oil-tolerant foam can be produced by making the oil surface ``water wet``. To test our theoretical ideas, we measure foam-flow resistance through 45--70 {mu}m glass beadpacks, surface and interfacial tensions, and disjoining pressure isotherms for foam and pseudoemulsion films for a variety of surfactant/oil systems. Most notably, we measure pseudoemulsion-film disjoining pressure isotherms for the first time and directly establish that pseudoemulsion film stability controls the stability of the foam in the systems we tested. Moreover, we demonstrate the correspondence between stable pseudoemulsion films, negative entering behavior, and oil-tolerant foams.

  17. Measurement and modeling of infrared nonlinear absorption coefficients and laser-induced damage thresholds in Ge and GaSb

    SciTech Connect (OSTI)

    Wagner, T. J.; Bohn, M. J.; Coutu, R. A. Jr.; Gonzalez, L. P.; Murray, J. M.; Guha, S.; Schepler, K. L.

    2010-10-15

    Using a simultaneous fitting technique to extract nonlinear absorption coefficients from data at two pulse widths, we measure two-photon and free-carrier absorption coefficients for Ge and GaSb at 2.05 and 2.5 {mu}m for the first time, to our knowledge. Results agreed well with published theory. Single-shot damage thresholds were also measured at 2.5 {mu}m and agreed well with modeled thresholds using experimentally determined parameters including nonlinear absorption coefficients and temperature dependent linear absorption. The damage threshold for a single-layer Al{sub 2}O{sub 3} anti-reflective coating on Ge was 55% or 35% lower than the uncoated threshold for picosecond or nanosecond pulses, respectively.

  18. Multilayer X-ray mirrors for the (4.4-5)-nm carbon-window spectral region

    SciTech Connect (OSTI)

    Andreev, S. S.; Barysheva, M. M.; Vainer, Yu. A.; Gaikovich, P. K.; Pariev, D. E. Pestov, A. E.; Salashchenko, N. N.; Chkhalo, N. I.

    2013-05-15

    Cr/C-based multilayer X-ray mirrors intended for the reflection of X-ray radiation in the 'carbon-window' spectral region ({lambda} = 4.4-5 nm) are fabricated and studied. The structures are formed by magnetron sputtering at different deposition parameters. Under normal incidence, record reflection coefficients up to 15% are reached. The structural parameters of the mirrors are investigated by reflectometry at wavelengths of 0.154 and 4.47 nm.

  19. Non-carbon induction furnace

    DOE Patents [OSTI]

    Holcombe, C.E.; Masters, D.R.; Pfeiler, W.A.

    1984-01-06

    The present invention is directed to an induction furnace for melting and casting highly pure metals and alloys such as uranium and uranium alloys in such a manner as to minimize contamination of the melt by carbon derived from the materials and the environment within the furnace. The subject furnace is constructed of non-carbon materials and is housed within a conventional vacuum chamber. The furnace comprises a ceramic oxide crucible for holding the charge of metal or alloys. The heating of the crucible is achieved by a plasma-sprayed tungsten susceptor surrounding the crucible which, in turn, is heated by an rf induction coil separated from the susceptor by a cylinder of inorganic insulation. The furnace of the present invention is capable of being rapidly cycled from ambient temperatures to about 1650/sup 0/C for effectively melting uranium and uranium alloys without the attendant carbon contamination problems previously encountered when using carbon-bearing furnace materials.

  20. Carbon-free induction furnace

    DOE Patents [OSTI]

    Holcombe, Cressie E.; Masters, David R.; Pfeiler, William A.

    1985-01-01

    An induction furnace for melting and casting highly pure metals and alloys such as uranium and uranium alloys in such a manner as to minimize contamination of the melt by carbon derived from the materials and the environment within the furnace. The subject furnace is constructed of carbon free materials and is housed within a conventional vacuum chamber. The furnace comprises a ceramic oxide crucible for holding the charge of metal or alloy. The heating of the crucible is achieved by a plasma-sprayed tungsten susceptor surrounding the crucible which, in turn, is heated by an RF induction coil separated from the susceptor by a cylinder of inorganic insulation. The furnace of the present invention is capable of being rapidly cycled from ambient temperatures to about 1650.degree. C. for effectively melting uranium and uranium alloys without the attendant carbon contamination problems previously encountered when using carbon-bearing furnace materials.