National Library of Energy BETA

Sample records for type carbon coefficient

  1. Thermal Expansion and Diffusion Coefficients of Carbon

    E-Print Network [OSTI]

    Wei, Chenyu

    Thermal Expansion and Diffusion Coefficients of Carbon Nanotube-Polymer Composites Chenyu Wei* NASA of carbon nanotube-polyethylene composites. Additions of carbon nanotubes to a polymer matrix are found for polymer-nanotube interface are used to investigate the thermal expansion and diffusion characteristics

  2. Limiting diffusion coefficients of heavy molecular weight organic contaminants in supercritical carbon dioxide 

    E-Print Network [OSTI]

    Orejuela, Mauricio

    1994-01-01

    Carbon Dioxide. 5. Measured Diffusion Coefficients of Hexachlorobenzene in Supercritical Carbon Dioxide. 6. Measured Diffusion Coefficients of Pentachlorophenol in Supercritical Carbon Dioxide. 7. Carbon Dioxide Parameters as Determined by Empirical..., and for polyatomic solute and solvent molecules, A?was set to 0. 70. Erkey (1989) determined the translational-rotational coupling parameters for binary n-Alkane systems from measured diffusivity data at a wide range of densities. It was shown...

  3. Type Ia Supernova Carbon Footprints

    E-Print Network [OSTI]

    Thomas, R C; Aragon, C; Antilogus, P; Bailey, S; Baltay, C; Bongard, S; Buton, C; Canto, A; Childress, M; Chotard, N; Copin, Y; Fakhouri, H K; Gangler, E; Hsiao, E Y; Kerschhaggl, M; Kowalski, M; Loken, S; Nugent, P; Paech, K; Pain, R; Pecontal, E; Pereira, R; Perlmutter, S; Rabinowitz, D; Rigault, M; Rubin, D; Runge, K; Scalzo, R; Smadja, G; Tao, C; Weaver, B A; Wu, C; Brown, P J; Milne, P A

    2011-01-01

    We present convincing evidence of unburned carbon at photospheric velocities in new observations of 5 Type Ia supernovae (SNe Ia) obtained by the Nearby Supernova Factory. These SNe are identified by examining 346 spectra from 124 SNe obtained before +2.5 d relative to maximum. Detections are based on the presence of relatively strong C II 6580 absorption "notches" in multiple spectra of each SN, aided by automated fitting with the SYNAPPS code. Four of the 5 SNe in question are otherwise spectroscopically unremarkable, with ions and ejection velocities typical of SNe Ia, but spectra of the fifth exhibits high-velocity (v > 20,000 km/s) Si II and Ca II features. On the other hand, the light curve properties are preferentially grouped, strongly suggesting a connection between carbon-positivity and broad band light curve/color behavior: Three of the 5 have relatively narrow light curves but also blue colors, and a fourth may be a dust-reddened member of this family. Accounting for signal-to-noise and phase, we ...

  4. Determination of power-law attenuation coefficient and dispersion spectra in multi-wall carbon nanotube

    E-Print Network [OSTI]

    Gladden, Josh

    Determination of power-law attenuation coefficient and dispersion spectra in multi-wall carbon for a set of multi-wall carbon nanotube MWCNT -nylon composites from pure nylon to 20% MWCNT by weight­Kronig relations, the attenuation and dispersion data were found to be consistent with a power-law attenuation

  5. China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces

    E-Print Network [OSTI]

    Lu, Hongyou

    2013-01-01

    Values by Fuel Fuel Type Raw Coal Cleaned Coal Washed CoalType Carbon Coefficient CO 2 Coefficient (t C/TJ) (t CO 2 /TJ) Coal

  6. Measurement of diffusion coefficients in supercritical carbon dioxide and correlation with the equation of Wilke and Chang

    SciTech Connect (OSTI)

    Sassiat, P.R.; Mourier, P.; Caude, M.H.; Rosset, R.H.

    1987-04-15

    Diffusion coefficients of acetone, benzene, naphthalene, 1,3,5-trimethylbenzene, phenanthrene, pyrene, and chrysene have been measured by a chromatographic broadening technique in an open capillary tube (950 x 0.103 cm) filled with pure supercritical carbon dioxide or, in the case of benzene, with CO/sub 2/-methanol mixtures ranging from 0 to 100% in methanol. In pure supercritical CO/sub 2/, diffusion coefficients decrease when density increases; they increase linearly vs. the reciprocal of the viscosity; a linear relationship exists between the logarithms of the diffusion coefficients and the molar volumes with a slope of 0.6. Finally, in the range 0.6-0.9 g cm/sup -3/, the Wilke and Chang equation for the calculation of diffusion coefficients is valid for supercritical CO/sub 2/. For methanol-CO/sub 2/ mixtures there is no discontinuity of the diffusion coefficient of benzene when the methanol content varies from 0 to 100%. In the usual supercritical chromatographic conditions with a methanol content less than 10%, diffusion coefficients are at least 4 times higher than in pure methanol.

  7. Modeling of Seismic Signatures of Carbonate Rock Types 

    E-Print Network [OSTI]

    Jan, Badr H.

    2011-02-22

    Carbonate reservoirs of different rock types have wide ranges of porosity and permeability, creating zones with different reservoir quality and flow properties. This research addresses how seismic technology can be used to identify different...

  8. Simulation of L-mode Tokamak Discharges and ITER Performance with Energy Transport Coefficients of Bohm and Gyro-Bohm Type

    E-Print Network [OSTI]

    Simulation of L-mode Tokamak Discharges and ITER Performance with Energy Transport Coefficients of Bohm and Gyro-Bohm Type

  9. Molecular dynamics simulation of diffusion coefficients and structural properties of some alkylbenzenes in supercritical carbon dioxide at infinite dilution

    SciTech Connect (OSTI)

    Wang, Jinyang; Zhong, Haimin; Qiu, Wenda; Chen, Liuping; Feng, Huajie

    2014-03-14

    The binary infinite dilute diffusion coefficients, D{sub 12}{sup ?}, of some alkylbenzenes (Ph-C{sub n}, from Ph-H to Ph-C{sub 12}) from 313 K to 333 K at 15 MPa in supercritical carbon dioxide (scCO{sub 2}) have been studied by molecular dynamics (MD) simulation. The MD values agree well with the experimental ones, which indicate MD simulation technique is a powerful way to predict and obtain diffusion coefficients of solutes in supercritical fluids. Besides, the local structures of Ph-C{sub n}/CO{sub 2} fluids are further investigated by calculating radial distribution functions and coordination numbers. It qualitatively convinces that the first solvation shell of Ph-C{sub n} in scCO{sub 2} is significantly influenced by the structure of Ph-C{sub n} solute. Meanwhile, the mean end-to-end distance, the mean radius of gyration and dihedral angle distribution are calculated to gain an insight into the structural properties of Ph-C{sub n} in scCO{sub 2}. The abnormal trends of radial distribution functions and coordination numbers can be reasonably explained in term of molecular flexibility. Moreover, the computed results of dihedral angle clarify that flexibility of long-chain Ph-C{sub n} is the result of internal rotation of C-C single bond (?{sub c-c}) in alkyl chain. It is interesting that compared with n-alkane, because of the existence of benzene ring, the flexibility of alkyl chain in Ph-C{sub n} with same carbon atom number is significantly reduced, as a result, the carbon chain dependence of diffusion behaviors for long-chain n-alkane (n ? 5) and long-chain Ph-C{sub n} (n ? 4) in scCO{sub 2} are different.

  10. Black Carbon Emissions by Rocket Engines Types of rocket engines Emissions

    E-Print Network [OSTI]

    Toohey, Darin W.

    Black Carbon Emissions by Rocket Engines Types of rocket engines Emissions Liquid Hydrogen. Note: Black carbon does not deplete ozone. What happens is the black carbon emissions from the rocket. Other black carbon emissions: The number one contributor to black carbon is burning biomass. Also

  11. Black Carbon Concentrations and Diesel Vehicle Emission Factors Derived from Coefficient of Haze Measurements in California: 1967-2003

    SciTech Connect (OSTI)

    Tast, CynthiaL; Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.; Fairley, David

    2007-11-09

    We have derived ambient black carbon (BC) concentrations and estimated emission factors for on-road diesel vehicles from archived Coefficient of Haze (COH) data that was routinely collected beginning in 1967 at 11 locations in the San Francisco Bay Area. COH values are a measure of the attenuation of light by particles collected on a white filter, and available data indicate they are proportional to BC concentrations measured using the conventional aethalometer. Monthly averaged BC concentrations are up to five times greater in winter than summer, and, consequently, so is the population?s exposure to BC. The seasonal cycle in BC concentrations is similar for all Bay Area sites, most likely due to area-wide decreased pollutant dispersion during wintertime. A strong weekly cycle is also evident, with weekend concentrations significantly lower than weekday concentrations, consistent with decreased diesel traffic volume on weekends. The weekly cycle suggests that, in the Bay Area, diesel vehicle emissions are the dominant source of BC aerosol. Despite the continuous increase in diesel fuel consumption in California, annual Bay Area average BC concentrations decreased by a factor of ~;;3 from the late 1960s to the early 2000s. Based on estimated annual BC concentrations, on-road diesel fuel consumption, and recent measurements of on-road diesel vehicle BC emissions, diesel BC emission factors decreased by an order of magnitude over the study period. Reductions in the BC emission factor reflect improved engine technology, emission controls and changes in diesel fuel composition. A new BC monitoring network is needed to continue tracking ambient BC trends because the network of COH monitors has recently been retired.

  12. Black Carbon Concentrations and Diesel Vehicle Emission FactorsDerived from Coefficient of Haze Measurements in California:1967-2003

    SciTech Connect (OSTI)

    Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.

    2007-10-01

    We have derived ambient black carbon (BC) concentrations and estimated emission factors for on-road diesel vehicles from archived Coefficient of Haze (COH) data that was routinely collected beginning in 1967 at 11 locations in the San Francisco Bay Area. COH values are a measure of the attenuation of light by particles collected on a white filter, and available data indicate they are proportional to BC concentrations measured using the conventional aethalometer. Monthly averaged BC concentrations are up to five times greater in winter than summer, and, consequently, so is the population's exposure to BC. The seasonal cycle in BC concentrations is similar for all Bay Area sites, most likely due to area-wide decreased pollutant dispersion during wintertime. A strong weekly cycle is also evident, with weekend concentrations significantly lower than weekday concentrations, consistent with decreased diesel traffic volume on weekends. The weekly cycle suggests that, in the Bay Area, diesel vehicle emissions are the dominant source of BC aerosol. Despite the continuous increase in diesel fuel consumption in California, annual Bay Area average BC concentrations decreased by a factor of {approx}3 from the late 1960s to the early 2000s. Based on estimated annual BC concentrations, on-road diesel fuel consumption, and recent measurements of on-road diesel vehicle BC emissions, diesel BC emission factors decreased by an order of magnitude over the study period. Reductions in the BC emission factor reflect improved engine technology, emission controls and changes in diesel fuel composition. A new BC monitoring network is needed to continue tracking ambient BC trends because the network of COH monitors has recently been retired.

  13. CARBON DEFLAGRATION IN TYPE Ia SUPERNOVA. I. CENTRALLY IGNITED MODELS

    SciTech Connect (OSTI)

    Ma, H.; Woosley, S. E.; Malone, C. M. [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States); Almgren, A.; Bell, J. [Center for Computational Sciences and Engineering, Lawrence Berkeley National Lab, Berkeley, CA 94720 (United States)

    2013-07-01

    A leading model for Type Ia supernovae (SNe Ia) begins with a white dwarf near the Chandrasekhar mass that ignites a degenerate thermonuclear runaway close to its center and explodes. In a series of papers, we shall explore the consequences of ignition at several locations within such dwarfs. Here we assume central ignition, which has been explored before, but is worth revisiting, if only to validate those previous studies and to further elucidate the relevant physics for future work. A perturbed sphere of hot iron ash with a radius of {approx}100 km is initialized at the middle of the star. The subsequent explosion is followed in several simulations using a thickened flame model in which the flame speed is either fixed-within the range expected from turbulent combustion-or based on the local turbulent intensity. Global results, including the explosion energy and bulk nucleosynthesis (e.g., {sup 56}Ni of 0.48-0.56 M{sub Sun }) turn out to be insensitive to this speed. In all completed runs, the energy released by the nuclear burning is adequate to unbind the star, but not enough to give the energy and brightness of typical SNe Ia. As found previously, the chemical stratification observed in typical events is not reproduced. These models produce a large amount of unburned carbon and oxygen in central low velocity regions, which is inconsistent with spectroscopic observations, and the intermediate mass elements and iron group elements are strongly mixed during the explosion.

  14. Rock Physics-Based Carbonate Reservoir Pore Type Evaluation by Combining Geological, Petrophysical and Seismic Data 

    E-Print Network [OSTI]

    Dou, Qifeng

    2012-07-16

    Pore type variations account for complex velocity-porosity relationship and intensive permeability heterogeneity and consequently low oil and gas recovery in carbonate reservoir. However, it is a challenge for geologist ...

  15. N-Type Thermoelectric Performance of Functionalized Carbon Nanotube-Filled Polymer Composites 

    E-Print Network [OSTI]

    Freeman, Dallas

    2012-07-16

    -TYPE THERMOELECTRIC PERFORMANCE OF FUNCTIONALIZED CARBON NANOTUBE-FILLED POLYMER COMPOSITES A Thesis by DALLAS D. FREEMAN II Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 2012 Major Subject: Mechanical Engineering N-Type Thermoelectric Performance of Functionalized Carbon Nanotube-Filled Polymer Composites Copyright 2012 Dallas D. Freeman II...

  16. Ultra low friction carbon/carbon composites for extreme temperature applications

    DOE Patents [OSTI]

    Erdemir, Ali (Naperville, IL); Busch, Donald E. (Hinsdale, IL); Fenske, George R. (Downers Grove, IL); Lee, Sam (Gardena, CA); Shepherd, Gary (Los Alamitos, CA); Pruett, Gary J. (Cypress, CA)

    2001-01-01

    A carbon/carbon composite in which a carbon matrix containing a controlled amount of boron or a boron compound is reinforced with carbon fiber exhibits a low coefficient of friction, i.e., on the order of 0.04 to 0.1 at temperatures up to 600.degree. C., which is one of the lowest frictional coefficients for any type of carbonaceous material, including graphite, glassy carbon, diamond, diamond-like carbon and other forms of carbon material. The high degree of slipperiness of the carbon composite renders it particularly adapted for limiting friction and wear at elevated temperatures such as in seals, bearings, shafts, and flexible joints

  17. Power series with Taylor coefficients of sum-product type and algebraic differential equations /SP-series and the interplay between their resurgence and differential properties

    E-Print Network [OSTI]

    Sharma, Shweta

    2012-01-01

    The article is based on the differential properties of the inner generators (singularities) that occur while handling SP series (sum product series), power series whose Taylor coefficients can be written as sum-product combinations. It is an elaboration with numerical details and some explicit calculations of the chapter 6 of the joint article with Ecalle on these series. For all polynomial inputs $f$ and all monomial inputs $F$, the inner generators corresponding to them verify ordinary differential equations of linear homogeneous type with polynomial coefficients. Numerical results strongly suggest the non-existence of ODEs for functions $F$ that are rational but not monomial, i.e. not of the form ${(1-ax)}^p$, for $p \\in \\mathbb{Z}$.

  18. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    E-Print Network [OSTI]

    Myint, P C; Firoozabadi, A

    2015-01-01

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO$_2$) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi, and the CO$_2$ activity coefficient model by Duan and Sun. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO$_2$, pure water, and both CO$_2$-rich and aqueous (H$_2$O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spy...

  19. Carbon dioxide reduction to alcohols using perovskite-type electrocatalysts

    SciTech Connect (OSTI)

    Schwartz, M.; Cook, R.L.; Kehoe, V.M.; MacDuff, R.C.; Patel, J.; Sammells, A.F. (Eltron Research, Inc., Boulder, CO (United States))

    1993-03-01

    Electrochemical reduction of CO[sub 2] under ambient conditions to methanol, ethanol, and n-propanol is reported at perovskite-type A[sub 1.8]A[prime][sub 0.2]CuO[sub 4] (A = La, Pr, and Gd; A[prime] = Sr and Th) electrocatalysts when incorporated into gas diffusion electrodes. In the absence of copper at the perovskite B lattice site, no activity was found. This investigation resulted in the identification of electrochemical conditions whereby perovskite-type electrocatalysts could achieve cumulative Faradaic efficiencies for CO[sub 2] reduction to methanol, ethanol, and n-propanol up to [congruent] 40% at current densities of 180 mA/cm[sup 2].

  20. Differential support of lake food webs by three types of terrestrial organic carbon

    E-Print Network [OSTI]

    Cole, Jonathan J.

    from the t-DOC to bacteria pathway. Terrestrial POC significantly subsidized the production of bothLETTER Differential support of lake food webs by three types of terrestrial organic carbon Jonathan whole-lake additions of dissolved inorganic 13 C were made to reveal the pathways of subsidies to lakes

  1. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    E-Print Network [OSTI]

    P. C. Myint; Y. Hao; A. Firoozabadi

    2015-04-20

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO$_2$) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi, and the CO$_2$ activity coefficient model by Duan and Sun. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO$_2$, pure water, and both CO$_2$-rich and aqueous (H$_2$O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Sun's model yields accurate results for the partial molar enthalpy of CO$_2$. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H$_2$O-CO$_2$-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  2. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    SciTech Connect (OSTI)

    Myint, P. C.; Hao, Y.; Firoozabadi, A.

    2015-03-27

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO2) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data [1]. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi [2], and the CO2 activity coefficient model by Duan and Sun [3]. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO2, pure water, and both CO2-rich and aqueous (H2O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Sun’s model yields accurate results for the partial molar enthalpy of CO2. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H2O-CO2-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  3. Identification of pore type and origin in a Lower Cretaceous carbonate reservoir using NMR T2 relaxation times 

    E-Print Network [OSTI]

    Lodola, Domenico Domenico

    2004-09-30

    Determining the distribution of porosity and permeability is one of the main challenges in carbonate petroleum reservoir characterization and requires a thorough understanding of pore type and origin, as well as their ...

  4. Measurement of Drag Torque, Lift Off Speed, and Identification of Frequency Dependent Stiffness and Damping Coefficients of a Shimmed Bump-Type Foil Bearing 

    E-Print Network [OSTI]

    Norsworthy, Joshua D

    2014-11-26

    direct damping coefficients (in particular along the static load direction and at high frequencies) while operating at 50 krpm. The energy dissipated is best characterized with a structural loss factor ?, a function of the bearing elastic (K) properties...

  5. Electronic Durability of Flexible Transparent Films from Type-Specific Single-Wall Carbon Nanotubes

    SciTech Connect (OSTI)

    Harris, J; Iyer, S; Bernhardt, A; Huh, JY; Hudson, S; Fagan, J; Hobbie, E.

    2011-12-11

    The coupling between mechanical flexibility and electronic performance is evaluated for thin films of metallic and semiconducting single-wall carbon nanotubes (SWCNTs) deposited on compliant supports. Percolated networks of type-purified SWCNTs are assembled as thin conducting coatings on elastic polymer substrates, and the sheet resistance is measured as a function of compression and cyclic strain through impedance spectroscopy. The wrinkling topography, microstructure and transparency of the films are independently characterized using optical microscopy, electron microscopy, and optical absorption spectroscopy. Thin films made from metallic SWCNTs show better durability as flexible transparent conductive coatings, which we attribute to a combination of superior mechanical performance and higher interfacial conductivity.

  6. Solar-induced chemical vapor deposition of diamond-type carbon films

    DOE Patents [OSTI]

    Pitts, J. Roland (Lakewood, CO); Tracy, C. Edwin (Golden, CO); King, David E. (Lakewood, CO); Stanley, James T. (Beaverton, OR)

    1994-01-01

    An improved chemical vapor deposition method for depositing transparent continuous coatings of sp.sup.3 -bonded diamond-type carbon films, comprising: a) providing a volatile hydrocarbon gas/H.sub.2 reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and b) directing a concentrated solar flux of from about 40 to about 60 watts/cm.sup.2 through said reactant mixture to produce substrate temperatures of about 750.degree. C. to about 950.degree. C. to activate deposition of the film on said substrate.

  7. Solar-induced chemical vapor deposition of diamond-type carbon films

    DOE Patents [OSTI]

    Pitts, J.R.; Tracy, C.E.; King, D.E.; Stanley, J.T.

    1994-09-13

    An improved chemical vapor deposition method for depositing transparent continuous coatings of sp[sup 3]-bonded diamond-type carbon films, comprises: (a) providing a volatile hydrocarbon gas/H[sub 2] reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and (b) directing a concentrated solar flux of from about 40 to about 60 watts/cm[sup 2] through said reactant mixture to produce substrate temperatures of about 750 C to about 950 C to activate deposition of the film on said substrate. 11 figs.

  8. A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.

    2013-05-10

    In collaboration with participants of the Coordinating Research Council (CRC) Advanced Vehicle/Fuels/Lubricants (AVFL) Committee, and project AVFL-19, the characteristics of fuels from advanced and renewable sources were compared to commercial diesel fuels. The main objective of this study was to highlight similarities and differences among the fuel types, i.e. ULSD, renewables, and alternative fuels, and among fuels within the different fuel types. This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of 14 diesel fuel samples. The diesel fuel samples come from diverse sources and include four commercial ultra-low sulfur diesel fuels (ULSD), one gas-to-liquid diesel fuel (GTL), six renewable diesel fuels (RD), two shale oil-derived diesel fuels, and one oil sands-derived diesel fuel. Overall, the fuels examined fall into two groups. The two shale oil-derived samples and the oil-sand-derived sample closely resemble the four commercial ultra-low sulfur diesels, with SO1 and SO2 most closely matched with ULSD1, ULSD2, and ULSD4, and OS1 most closely matched with ULSD3. As might be expected, the renewable diesel fuels, with the exception of RD3, do not resemble the ULSD fuels because of their very low aromatic content, but more closely resemble the gas-to-liquid sample (GTL) in this respect. RD3 is significantly different from the other renewable diesel fuels in that the aromatic content more closely resembles the ULSD fuels. Fused-ring aromatics are readily observable in the ULSD, SO, and OS samples, as well as RD3, and are noticeably absent in the remaining RD and GTL fuels. Finally, ULSD3 differs from the other ULSD fuels by having a significantly lower aromatic carbon content and higher cycloparaffinic carbon content. In addition to providing important comparative compositional information regarding the various diesel fuels, this report also provides important information about the capabilities of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  9. Differential Support of Lake Food Webs by Three Types of Terrestrial Organic Carbon ELE 00670-2005 Revision

    E-Print Network [OSTI]

    Notre Dame, University of

    of dissolved inorganic 13 C were made to reveal the pathways of subsidies to lakes from terrestrial dissolved pathway. Terrestrial POC significantly subsidized the production of both zooplankton and benthic1 Differential Support of Lake Food Webs by Three Types of Terrestrial Organic Carbon ELE 00670

  10. Influence of Electronic Type Purity on the Lithiation of Single-Walled Carbon Nanotubes

    SciTech Connect (OSTI)

    Jaber-Ansari, Laila; Iddir, Hakim; Curtiss, Larry A.; Hersam, Mark C.

    2014-03-25

    Single-walled carbon nanotubes (SWCNTs) have emerged as one of the leading additives for high-capacity nanocomposite lithium ion battery electrodes due to their ability to improve electrode conductivity, current collection efficiency, and charge/discharge rate for high power applications. However, since as-grown SWCNTs possess a distribution of physical and electronic structures, it is of high interest to determine which subpopulations of SWCNTs possess the highest lithiation capacity and to develop processing methods that can enhance the lithiation capacity of underperforming SWCNT species. Toward this end, SWCNT electronic type purity is controlled via density gradient ultracentrifugation, enabling a systematic study of the lithiation of SWCNTs as a function of metal versus semiconducting content. Experimentally, vacuum-filtered freestanding films of metallic SWCNTs are found to accommodate lithium with an order of magnitude higher capacity than their semiconducting counterparts, which is consistent with ab initio molecular dynamics and density functional theory calculations in the limit of isolated SWCNTs. In contrast, SWCNT film densification leads to the enhancement of the lithiation capacity of semiconducting SWCNTs to levels comparable to metallic SWCNTs, which is corroborated by theoretical calculations that show increased lithiation of semiconducting SWCNTs in the limit of small SWCNT*SWCNT spacing. Overall, these results will inform ongoing efforts to utilize SWCNTs as conductive additives in nanocomposite lithium ion battery electrodes.

  11. Reprocessing the Hipparcos data for evolved giant stars II. Absolute magnitudes for the R-type carbon stars

    E-Print Network [OSTI]

    G. R. Knapp; D. Pourbaix; A. Jorissen

    2001-03-09

    The Hipparcos Intermediate Astrometric Data for carbon stars have been reprocessed using an algorithm which provides an objective criterion for rejecting anomalous data points and constrains the parallax to be positive. New parallax solutions have been derived for 317 cool carbon stars, mostly of types R and N. In this paper we discuss the results for the R stars. The most important result is that the early R stars (i.e., R0 - R3) have absolute magnitudes and V-K colors locating them among red clump giants in the Hertzsprung-Russell diagram. Stars with subtypes R4 - R9 tend to be cooler and have similar luminosity to the N-type carbon stars, as confirmed by their position in the (J-H, H-K) color-color diagram. The sample of early R-type stars selected from the Hipparcos Catalogue appears to be approximately complete to magnitude K_0 ~ 7, translating into a completeness distance of 600 pc if all R stars had M_K= -2 (400 pc if M_K= -1). With about 30 early R-type stars in that volume, they comprise about 0.04% (0.14% for M_K= -1) of the red clump stars in the solar neighborhood. Identification with the red clump locates these stars at the helium core burning stage of stellar evolution, while the N stars are on the asymptotic giant branch, where helium shell burning occurs. The present analysis suggests that for a small fraction of the helium core burning stars (far lower than the fraction of helium shell-burning stars), carbon produced in the interior is mixed to the atmosphere in sufficient quantities to form a carbon star.

  12. Influence of Rock Types on Seismic Monitoring of CO2 Sequestration in Carbonate Reservoirs 

    E-Print Network [OSTI]

    Mammadova, Elnara

    2012-10-19

    Although carbonates hold more than 60 percent of the world's oil reserves, they, nevertheless, exhibit much lower average recovery factor values than terrigenous sandstone reservoirs. Thus, utilization of advanced enhanced oil recovery (EOR...

  13. Carbon isotope chemostratigraphy of the Middle Riphean type section (Avzyan Formation, Southern Urals, Russia)

    E-Print Network [OSTI]

    Kah, Linda

    Urals, Russia): Signal recovery in a fold-and-thrust belt Julie K. Bartley a,, Linda C. Kah b , Julie L The Avzyan Formation of the southern Ural Mountains, Russia, forms part of the Middle Riphean (1300­1000 Ma Mesoproterozoic age. © 2006 Elsevier B.V. All rights reserved. Keywords: Mesoproterozoic; Russia; Urals; Carbonate

  14. Carbon-Type Analysis and Comparison of Original and Reblended FACE Diesel Fuels (FACE 2, FACE 4, and FACE 7)

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.; O'Hagan, Molly J.

    2012-10-01

    This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of Fuels for Advanced Combustion Engines (FACE) diesel blends, FD-2B, FD 4B, and FD-7B, and makes comparison of the new blends with the original FACE diesel blends, FD 2A, FD 4A, and FD-7A, respectively. Generally, FD-2A and FD-2B are more similar than the A and B blends of FD-4 and FD-7. The aromatic carbon content is roughly equivalent, although the new FACE blends have decreased monoaromatic content and increased di- and tri-cycloaromatic content, as well as a higher overall aromatic content, than the original FACE blends. The aromatic components of the new FACE blends generally have a higher alkyl substitution with longer alkyl substituents. The naphthenic and paraffinic contents remained relatively consistent. Based on aliphatic methyl and methylene carbon ratios, cetane numbers for FD-2A and -2B, and FD-7A and -7B are predicted to be consistent, while the cetane number for FD-4B is predicted to be higher than FD-4A. Overall, the new FACE fuel blends are fairly consistent with the original FACE fuel blends, but there are observable differences. In addition to providing important comparative compositional information on reformulated FACE diesel blends, this report also provides important information about the capabilities of the team at Pacific Northwest National Laboratory in the use of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  15. Intergranular corrosion mechanism of ultra-low carbon type 304 stainless steel in a nuclear reprocessing plant

    SciTech Connect (OSTI)

    Ueno, Fumiyoshi; Kato, Chiaki; Motooka, Takafumi; Yamamoto, Masahiro [Japan Atomic Energy Agency Shirakata Shirane 2-4, Tokai-mura, Ibaraki pref., 319-1195 (Japan); Ichikawa, Shiro [Kobelco Research Institute, Inc. 1-5-5, Takatsukadai, Nishi-ku, Kobe city, 651-2271 (Japan)

    2007-07-01

    Corrosion of the components which contains nitric acid solution such as vessels, tanks and pipes is an important problem for a PUREX method nuclear fuel reprocessing plant. In Tokai Reprocessing Plant which was startup in 1977 as the first Japanese plant, several events caused by corrosion have been experienced for about 30 years operation. The second plant in Japan, Rokkasho Reprocessing Plant, will start commercial operation from 2007. For stable operation of Rokkasho plant, maintenance management of components will be important. Therefore, it is necessary to clarify the corrosion mechanism and to reflect the results of the research for a maintenance program of the plant adequately. If high burnup fuel will increase in future nuclear power plants, it will become necessary to reprocess the spent fuel which includes more fission products and transuranium from now. Then the study of corrosion mechanism and life evaluation will become more important problem. Authors were aimed for development of life evaluation method of components and clarification of intergranular corrosion mechanism of ultra-low carbon type 304 stainless steel in a nuclear fuel reprocessing plant. In this report, the results of long-term corrosion test in boiling nitric acid by using ultra-low carbon stainless steel made mock-up test apparatus was described. And then, the relation between corrosion rate change and intergranular corrosion behavior were discussed. (authors)

  16. Bounding the Bogoliubov coefficients

    E-Print Network [OSTI]

    Boonserm, Petarpa

    2008-01-01

    While over the last century or more considerable effort has been put into the problem of finding approximate solutions for wave equations in general, and quantum mechanical problems in particular, it appears that as yet relatively little work seems to have been put into the complementary problem of establishing rigourous bounds on the exact solutions. We have in mind either bounds on parametric amplification and the related quantum phenomenon of particle production (as encoded in the Bogoliubov coefficients), or bounds on transmission and reflection coefficients. Modifying and streamlining an approach developed by one of the present authors [Phys. Rev. A 59 (1999) 427-438], we investigate this question by developing a formal but exact solution for the appropriate second-order linear ODE in terms of a time-ordered exponential of 2x2 matrices, then relating the Bogoliubov coefficients to certain invariants of this matrix. By bounding the matrix in an appropriate manner, we can thereby bound the Bogoliubov coeff...

  17. PRODUCTION OF THE p-PROCESS NUCLEI IN THE CARBON-DEFLAGRATION MODEL FOR TYPE Ia SUPERNOVAE

    SciTech Connect (OSTI)

    Kusakabe, Motohiko; Iwamoto, Nobuyuki; Nomoto, Ken'ichi E-mail: iwamoto.nobuyuki@jaea.go.jp

    2011-01-01

    We calculate the nucleosynthesis of proton-rich isotopes in the carbon-deflagration model for Type Ia supernovae (SNe Ia). The seed abundances are obtained by calculating the s-process nucleosynthesis that is expected to occur in the repeating helium shell flashes on the carbon-oxygen (CO) white dwarf (WD) during mass accretion from a binary companion. When the deflagration wave passes through the outer layer of the CO WD, p-nuclei are produced by photodisintegration reactions on s-nuclei in a region where the peak temperature ranges from 1.9 to 3.6 x 10{sup 9} K. We confirm the sensitivity of the p-process on the initial distribution of s-nuclei. We show that the initial C/O ratio in the WD does not affect much the yield of p-nuclei. On the other hand, the abundance of {sup 22}Ne left after s-processing has a large influence on the p-process via the {sup 22}Ne({alpha},n) reaction. We find that about 50% of p-nuclides are co-produced when normalized to their solar abundances in all adopted cases of seed distribution. Mo and Ru, which are largely underproduced in Type II supernovae (SNe II), are produced more than in SNe II although they are underproduced with respect to the yield levels of other p-nuclides. The ratios between p-nuclei and iron in the ejecta are larger than the solar ratios by a factor of 1.2. We also compare the yields of oxygen, iron, and p-nuclides in SNe Ia and SNe II and suggest that SNe Ia could make a larger contribution than SNe II to the solar system content of p-nuclei.

  18. Reconstruction of the “phase separation – ordering” type and specific heat in carbon nanotubes

    SciTech Connect (OSTI)

    Ponomarev, Alexander N. E-mail: val110@mail.ru; Egorushkin, Valery E. E-mail: val110@mail.ru; Bobenko, Nadezda G.; Melnikova, Natalia V.

    2014-11-14

    The low-temperature behavior of the specific heat in disordered nanotubes strongly depends on structure changes and was not explained by the phonon contribution. Expression for electronic specific heat was carried out taking into account the multiple elastic scattering of electrons on impurities and structural inhomogeneities of short-range order type, it includes dependence on diameter of nanotube, concentration of impurities, parameters of short-range order (structural heterogeneity) and temperature. Anomalous low-temperature behavior of the specific heat of disordered CNT is shown to have electronic nature and may be associated with the electrons that are involved in restructuring.

  19. Carbon abundances of the reference late-type stars from 1D analysis of atomic C I and molecular CH lines

    E-Print Network [OSTI]

    Alexeeva, S A

    2015-01-01

    A comprehensive model atom was constructed for C I using the most up-to-date atomic data. We evaluated non-local thermodynamical equilibrium (NLTE) line formation for neutral carbon in classical 1D models representing atmospheres of late-type stars, where carbon abundance varies from solar value down to [C/H] = $-$3. NLTE leads to stronger C I lines compared with their LTE strength and negative NLTE abundance corrections, $\\Delta_{\\rm NLTE}$. The deviations from LTE are large for the strong lines in the infrared (IR), with $\\Delta_{\\rm NLTE}$ = $-$0.10 dex to $-$0.45 dex depending on stellar parameters, and they are minor for the weak lines in the visible spectral range, with |$\\Delta_{\\rm NLTE}| \\le$ 0.03 dex. The NLTE abundance corrections were found to be dependent of the carbon abundance in the model. As the first application of the treated model atom, carbon NLTE abundances were determined for the Sun and eight late-type stars with well-determined stellar parameters that cover the $-2.56 \\le$ [Fe/H] $\\le...

  20. Carbon investment funds

    SciTech Connect (OSTI)

    2007-01-15

    The report is a study of the development of funds to invest in the purchase of carbon credits. It takes a look at the growing market for carbon credits, the rise of carbon investment funds, and the current state of carbon investing. Topics covered in the report include: Overview of climate change, greenhouse gases, and the Kyoto Protocols. Analysis of the alternatives for reducing carbon emissions including nitrous oxide reduction, coal mine methane capture and carbon capture and storage; Discussion of the different types of carbon credits; Discussion of the basics of carbon trading; Evaluation of the current status of carbon investing; and Profiles of 37 major carbon investment funds worldwide.

  1. PHYSICAL REVIEW B 83, 245420 (2011) Stone-Wales-type transformations in carbon nanostructures driven by electron irradiation

    E-Print Network [OSTI]

    Krasheninnikov, Arkady V.

    2011-01-01

    driven by electron irradiation J. Kotakoski,1,* J. C. Meyer,2, S. Kurasch,2 D. Santos-Cottin,1 U. Kaiser of carbon nanostructures are at odds with the equilibrium thermodynamics of these systems. Here displacements. We further study the mechanisms of irradiation- driven bond rotations and explain why electron

  2. Nearby Supernova Factory Observations of SN 2006D: On Sporadic Carbon Signatures in Early Type Ia Supernova Spectra

    E-Print Network [OSTI]

    2006-01-01

    with low volume-?lling factor. Subject headings: supernovae:general — supernovae: individual (SN 2006D)Introduction Type Ia supernovae (SNe Ia) make valuable

  3. Three Human Cell Types Respond to Multi-Walled Carbon Nanotubes and Titanium Dioxide Nanobelts with Cell-Specific Transcriptomic and Proteomic Expression Patterns.

    SciTech Connect (OSTI)

    Tilton, Susan C.; Karin, Norman J.; Tolic, Ana; Xie, Yumei; Lai, Xianyin; Hamilton, Raymond F.; Waters, Katrina M.; Holian, Andrij; Witzmann, Frank A.; Orr, Galya

    2014-08-01

    The growing use of engineered nanoparticles (NPs) in commercial and medical applications raises the urgent need for tools that can predict NP toxicity. Global transcriptome and proteome analyses were conducted on three human cell types, exposed to two high aspect ratio NP types, to identify patterns of expression that might indicate high versus low NP toxicity. Three cell types representing the most common routes of human exposure to NPs, including macrophage-like (THP-1), small airway epithelial and intestinal (Caco-2/HT29-MTX) cells, were exposed to TiO2 nanobelts (TiO2-NB; high toxicity) and multi-walled carbon nanotubes (MWCNT; low toxicity) at low (10 µg/mL) and high (100 µg/mL) concentrations for 1 and 24 h. Unique patterns of gene and protein expressions were identified for each cell type, with no differentially expressed (p < 0.05, 1.5-fold change) genes or proteins overlapping across all three cell types. While unique to each cell type, the early response was primarily independent of NP type, showing similar expression patterns in response to both TiO2-NB and MWCNT. The early response might, therefore, indicate a general response to insult. In contrast, the 24 h response was unique to each NP type. The most significantly (p < 0.05) enriched biological processes in THP-1 cells indicated TiO2-NB regulation of pathways associated with inflammation, apoptosis, cell cycle arrest, DNA replication stress and genomic instability, while MWCNT-regulated pathways indicated increased cell proliferation, DNA repair and anti-apoptosis. These two distinct sets of biological pathways might, therefore, underlie cellular responses to high and low NP toxicity, respectively.

  4. Quantitative analysis of carbon fluxes for fat biosynthesis in wild-type and IRS-1 knockout brown adipocytes

    E-Print Network [OSTI]

    Yoo, Hyun-Tae, 1973-

    2005-01-01

    Excessive fat synthesis and the subsequent dysregulation of lipid metabolism constitute the major pathological factors of obesity and type 2 diabetes through triggering insulin resistance. Thus, controlling fat synthesis ...

  5. Hydrothermal synthesis of nanocubes of sillenite type compounds for photovoltaic applications and solar energy conversion of carbon dioxide to fuels

    DOE Patents [OSTI]

    Subramanian, Vaidyanathan; Murugesan, Sankaran

    2014-04-29

    The present invention relates to formation of nanocubes of sillenite type compounds, such as bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, via a hydrothermal synthesis process, with the resulting compound(s) having multifunctional properties such as being useful in solar energy conversion, environmental remediation, and/or energy storage, for example. In one embodiment, a hydrothermal method is disclosed that transforms nanoparticles of TiO.sub.2 to bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, optionally loaded with palladium nanoparticles. The method includes reacting titanium dioxide nanotubes with a bismuth salt in an acidic bath at a temperature sufficient and for a time sufficient to form bismuth titanate crystals, which are subsequently annealed to form bismuth titanate nanocubes. After annealing, the bismuth titanate nanocubes may be optionally loaded with nano-sized metal particles, e.g., nanosized palladium particles.

  6. Characterization of solid state nuclear track detectors of the polyallyl-diglycol-carbonate (CR-39/PM-355) type for light charged particle spectroscopy

    SciTech Connect (OSTI)

    Malinowska, A. Jaskó?a, M.; Korman, A.; Kuk, M.; Szyd?owski, A.

    2014-12-15

    This paper presents a method which uses the characteristics of the etch pits induced in a polyallyl-diglycol-carbonate (PADC) detector of the CR-39/PM-355 type to estimate particle energy. This method is based on the data provided by a semiautomatic system that selects tracks according to two parameters, crater diameters, and mean gray level values. In this paper we used the results of the calibration measurements that were obtained in our laboratory in the period 2000–2014. Combining the information on the two parameters it is possible to determine unambiguously the incident projectile energy values. The paper presents the results of an attempt to estimate the energy resolution of the method when analyzing the tracks produced in the CR-39/PM-355 detector by energetic ions such as alpha particles, protons, and deuterons. We discuss the energy resolution of the measurement of light charged particle energy which is based on the parameters (crater diameter and mean gray level value) of tracks induced in solid state nuclear track detectors of the PADC type.

  7. Portable vapor diffusion coefficient meter

    DOE Patents [OSTI]

    Ho, Clifford K. (Albuquerque, NM)

    2007-06-12

    An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.

  8. Transport coefficients of gluonic fluid

    E-Print Network [OSTI]

    Santosh K Das; Jan-e Alam

    2011-06-14

    The shear ($\\eta$) and bulk ($\\zeta$) viscous coefficients have been evaluated for a gluonic fluid. The elastic, $gg \\rightarrow gg$ and the inelastic, number non-conserving, $gg\\rightarrow ggg$ processes have been considered as the dominant perturbative processes in evaluating the viscous co-efficients to entropy density ($s$) ratios. Recently the processes: $gg \\rightarrow ggg$ has been revisited and a correction to the widely used Gunion-Bertsch (GB) formula has been obtained. The $\\eta$ and $\\zeta$ have been evaluated for gluonic fluid with the formula derived recently. The sensitivity of the quantity, $\\eta/s$ on the running coupling constant is also discussed. At $\\alpha_s=0.3$ we get $\\eta/s=0.24$ which is close to the value obtained from the analysis of the elliptic flow at RHIC experiments.

  9. Improved thermoelectric power output from multilayered polyethylenimine doped carbon nanotube based organic composites

    SciTech Connect (OSTI)

    Hewitt, Corey A.; Montgomery, David S.; Barbalace, Ryan L.; Carlson, Rowland D.; Carroll, David L., E-mail: carroldl@wfu.edu [Center for Nanotechnology and Molecular Materials, Wake Forest University, 501 Deacon Blvd., Winston Salem, North Carolina 27105 (United States)

    2014-05-14

    By appropriately selecting the carbon nanotube type and n-type dopant for the conduction layers in a multilayered carbon nanotube composite, the total device thermoelectric power output can be increased significantly. The particular materials chosen in this study were raw single walled carbon nanotubes for the p-type layers and polyethylenimine doped single walled carbon nanotubes for the n-type layers. The combination of these two conduction layers leads to a single thermocouple Seebeck coefficient of 96 ± 4??VK{sup ?1}, which is 6.3 times higher than that previously reported. This improved Seebeck coefficient leads to a total power output of 14.7 nW per thermocouple at the maximum temperature difference of 50?K, which is 44 times the power output per thermocouple for the previously reported results. Ultimately, these thermoelectric power output improvements help to increase the potential use of these lightweight, flexible, and durable organic multilayered carbon nanotube based thermoelectric modules in low powered electronics applications, where waste heat is available.

  10. Characterization of carbon fibers: coefficient of thermal expansion and microstructure 

    E-Print Network [OSTI]

    Kulkarni, Raghav Shrikant

    2006-04-12

    and transverse CTE. The orthotropy in the CTE is tested by rotating the fibers through 45? about their axis. The method is validated by testing standard tungsten filaments of known CTE. Additionally, the microstructure of the fibers is studied in a field... strain vs. temperature for tungsten................................... 40 Figure 3.3 Strain vs. temperature for P55 fiber.................................................... 42 Figure 3.4 Cross sectional images of IM7 fibers failed in bending...

  11. Memory Effects and Transport Coefficients for Non-Newtonian Fluids

    E-Print Network [OSTI]

    T. Kodama; T. Koide

    2008-12-22

    We discuss the roles of viscosity in relativistic fluid dynamics from the point of view of memory effects. Depending on the type of quantity to which the memory effect is applied, different terms appear in higher order corrections. We show that when the memory effect applies on the extensive quantities, the hydrodynamic equations of motion become non-singular. We further discuss the question of memory effect in the derivation of transport coefficients from a microscopic theory. We generalize the application of the Green-Kubo-Nakano (GKN) to calculate transport coefficients in the framework of projection operator formalism, and derive the general formula when the fluid is non-Newtonian.

  12. Coupling coefficients for tensor product representations of quantum SU(2)

    SciTech Connect (OSTI)

    Groenevelt, Wolter

    2014-10-15

    We study tensor products of infinite dimensional irreducible {sup *}-representations (not corepresentations) of the SU(2) quantum group. We obtain (generalized) eigenvectors of certain self-adjoint elements using spectral analysis of Jacobi operators associated to well-known q-hypergeometric orthogonal polynomials. We also compute coupling coefficients between different eigenvectors corresponding to the same eigenvalue. Since the continuous spectrum has multiplicity two, the corresponding coupling coefficients can be considered as 2 × 2-matrix-valued orthogonal functions. We compute explicitly the matrix elements of these functions. The coupling coefficients can be considered as q-analogs of Bessel functions. As a results we obtain several q-integral identities involving q-hypergeometric orthogonal polynomials and q-Bessel-type functions.

  13. Carbon abundances of early B-type stars in the solar vicinity. Non-LTE line-formation for C II/III/IV and self-consistent atmospheric parameters

    E-Print Network [OSTI]

    M. F. Nieva; N. Przybilla

    2007-11-23

    Precise determinations of the chemical composition in early B-type stars consitute fundamental observational constraints on stellar and galactochemical evolution. Carbon is one of the most abundant metals in the Universe but analyses in early-type stars show inconclusive results, like large discrepancies between analyses of different lines in C II, a failure to establish the C II/III ionization balance and the derivation of systematically lower abundances than from other objects. We present a comprehensive and robust C II/III/IV model for non-LTE line-formation calculations based on carefully selected atomic data. The model is calibrated with high-S/N spectra of six apparently slow-rotating early B-type dwarfs and giants, which cover a wide parameter range and are randomly distributed in the solar neighbourhood. A self-consistent quantitative spectrum analysis is performed using an extensive iteration scheme to determine stellar atmospheric parameters and to select the appropriate atomic data used for the derivation of chemical abundances. We establish the carbon ionization balance for all sample stars based on a unique set of input atomic data, achieving consistency for all modelled lines. Highly accurate atmospheric parameters and a homogeneous carbon abundance with reduced systematic errors are derived. This results in a present-day stellar carbon abundance in the solar neighbourhood, which is in good agreement with recent determinations of the solar value and with the gas-phase abundance of the Orion H II region. The homogeneous present-day carbon abundance also conforms with predictions of chemical-evolution models for the Galaxy. The present approach allows us to constrain the effects of systematic errors on fundamental parameters and abundances. (abridged)

  14. Green Goals: Carbon Sequestration Grade Levels: 6 12

    E-Print Network [OSTI]

    Hammack, Richard

    Green Goals: Carbon Sequestration Grade Levels: 6 ­ 12 type of carbon sequestration. All plants sequester carbon; however, the larger Objective: To investigate the role of trees in atmospheric carbon dioxide reduction

  15. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon...

    Open Energy Info (EERE)

    Technologies Project Type Topic 2 Supercritical Carbon Dioxide Reservoir Rock Chemical Interactions Project Description Supercritical CO2 is currently becoming a more...

  16. APPENDIX F Partition Coefficients For Lead

    E-Print Network [OSTI]

    APPENDIX F Partition Coefficients For Lead #12;Appendix F Partition Coefficients For Lead F.1.0 Background The review of lead Kd data reported in the literature for a number of soils led to the following important conclusions regarding the factors which influence lead adsorption on minerals, soils

  17. Coefficient of restitution for viscoelastic disks

    E-Print Network [OSTI]

    Thomas Schwager

    2007-01-08

    The dissipative collision of two identical viscoelastic disks is studied. By using a known law for the elastic part of the interaction force and the viscoelastic damping model an analytical solution for the coefficient of restitution shall be given. The coefficient of restitution depends significantly on the impact velocity. It approaches one for small velocities and decreases for increasing velocities.

  18. APPENDIX D Partition Coefficients For Cesium

    E-Print Network [OSTI]

    APPENDIX D Partition Coefficients For Cesium #12;Appendix D Partition Coefficients For Cesium D of cesium Kd values for the look-up table. These assumptions were based on the findings of the literature reviewed we conducted on the geochemical processes affecting cesium sorption. The assumptions

  19. APPENDIX I Partition Coefficients For Thorium

    E-Print Network [OSTI]

    APPENDIX I Partition Coefficients For Thorium #12;Appendix I Partition Coefficients For Thorium of thorium Kd values for the look-up table. These assumptions were based on the findings of the literature review conducted on the geochemical processes affecting thorium sorption. The assumptions are as follows

  20. APPENDIX G Partition Coefficients For Plutonium

    E-Print Network [OSTI]

    and not adsorption reactions. C Adsorption data show that the presence of ligands influence plutonium adsorption onto soils. Increasing concentrations of ligands decrease plutonium adsorption. C If no complexing ligandsAPPENDIX G Partition Coefficients For Plutonium #12;Appendix G Partition Coefficients

  1. Electromechanical coupling coefficient k31 for arbitrary

    E-Print Network [OSTI]

    Cao, Wenwu

    Electromechanical coupling coefficient k31 eff for arbitrary aspect ratio resonators made of 001 on the derived unified formula, the lateral electromechanical energy conversion efficiency k31 eff 2 decreases,3 The square of the electromechanical coupling coefficient k31 2 is used to characterize energy conversion

  2. APPENDIX J Partition Coefficients For Uranium

    E-Print Network [OSTI]

    APPENDIX J Partition Coefficients For Uranium #12;Appendix J Partition Coefficients For Uranium J.1.0 Background The review of uranium Kd values obtained for a number of soils, crushed rock and their effects on uranium adsorption on soils are discussed below. The solution pH was also used as the basis

  3. Generic transport coefficients of a confined electrolyte solution

    E-Print Network [OSTI]

    Hiroaki Yoshida; Hideyuki Mizuno; Tomoyuki Kinjo; Hitoshi Washizu; Jean-Louis Barrat

    2014-11-16

    Physical parameters characterising electrokinetic transport in a confined electrolyte solution are reconstructed from the generic transport coefficients obtained within the classical non-equilibrium statistical thermodynamic framework. The electro-osmotic flow, the diffusio-osmotic flow, the osmotic current, as well as the pressure-driven Poiseuille-type flow, the electric conduction, and the ion diffusion, are described by this set of transport coefficients. The reconstruction is demonstrated for an aqueous NaCl solution between two parallel charged surfaces with a nanoscale gap, by using the molecular dynamic (MD) simulations. A Green-Kubo approach is employed to evaluate the transport coefficients in the linear-response regime, and the fluxes induced by the pressure, electric, and chemical potential fields are compared with the results of non-equilibrium MD simulations. Using this numerical scheme, the influence of the salt concentration on the transport coefficients is investigated. Anomalous reversal of diffusio-osmotic current, as well as that of electro-osmotic flow, is observed at high surface charge densities and high added-salt concentrations.

  4. Transport coefficients of a unitarized pion gas

    E-Print Network [OSTI]

    Juan M. Torres-Rincon

    2011-11-16

    The latest experimental results in relativistic heavy-ion collisions show that the matter there produced requires transport coefficients because of the important collective properties found. We review the theoretical calculation of these transport coefficients in the hadron side at low temperatures by computing them in a gas composed of low energy pions. The interaction of these pions is taken from an effective chiral theory and further requiring scattering unitarity. The propagation of D and D* mesons in the thermalized pion gas is also studied in order to extract the heavy quark diffusion coefficients in the system.

  5. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, M.; Yuh, C.Y.

    1996-12-03

    A carbonate fuel cell matrix is described comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles. 8 figs.

  6. Creating materials with a desired refraction coefficient

    E-Print Network [OSTI]

    A. G. Ramm

    2009-09-02

    A method is given for creating material with a desired refraction coefficient. The method consists of embedding into a material with known refraction coefficient many small particles of size $a$. The number of particles per unit volume around any point is prescribed, the distance between neighboring particles is $O(a^{\\frac{2-\\kappa}{3}})$ as $a\\to 0$, $0<\\kappa<1$ is a fixed parameter. The total number of the embedded particle is $O(a^{\\kappa-2})$. The physical properties of the particles are described by the boundary impedance $\\zeta_m$ of the $m-th$ particle, $\\zeta_m=O(a^{-\\kappa})$ as $a\\to 0$. The refraction coefficient is the coefficient $n^2(x)$ in the wave equation $[\

  7. Separation of Carbon Dioxide from Nitrogen and Water in Flue Gas Streams 

    E-Print Network [OSTI]

    Mera, Hilda 1989-

    2012-04-12

    coefficients of carbon dioxide, nitrogen, and water in MOFs. The metal-organic frameworks studied are copper trimesate (Cu-BTC), zinc terephthalate (IRMOF1), and MIL-47, which belongs to the Materials of the Institute Lavoisier series. Diffusion coefficients...

  8. Carbon sequestration

    E-Print Network [OSTI]

    Carbon sequestration is the process of capture and long-term storage of atmospheric carbon dioxide (CO 2).[1] Carbon sequestration describes long-term storage of carbon dioxide or other forms of carbon to either mitigate or defer global warming and avoid ...

  9. Transport coefficients in Chiral Perturbation Theory

    E-Print Network [OSTI]

    D. Fernandez-Fraile; A. Gomez Nicola

    2006-10-16

    We present recent results on the calculation of transport coefficients for a pion gas at zero chemical potential in Chiral Perturbation Theory using Linear Response Theory. More precisely, we show the behavior of DC conductivity and shear viscosity at low temperatures. To compute transport coefficients, the standard power counting of ChPT has to be modified. The effects derived from imposing unitarity are also analyzed. As physical applications in Relativistic Heavy Ion Collisions, we show the relation of the DC conductivity to soft-photon production and phenomenological effects related to a nonzero shear viscosity. In addition, our values for the shear viscosity to entropy ratio satisfy the KSS bound.

  10. Diffusion and transport coefficients in synthetic opals

    SciTech Connect (OSTI)

    Sofo, J. O.; Mahan, G. D.; Department of Physics and Astronomy, The University of Tennessee, Knoxville, Tennessee 37996-1200

    2000-07-15

    Opals are structures composed of close-packed spheres in the size range of nano to micrometers. They are sintered to create small necks at the points of contact. We have solved the diffusion problem in such structures. The relation between the diffusion coefficient and the thermal and electrical conductivity is used to estimate the transport coefficients of opal structures as a function of the neck size and the mean free path of the carriers. The theory presented is also applicable to the diffusion problem in other periodic structures. (c) 2000 The American Physical Society.

  11. Aspect ratio dependence of electromechanical coupling coefficient of piezoelectric resonators

    E-Print Network [OSTI]

    Cao, Wenwu

    Aspect ratio dependence of electromechanical coupling coefficient of piezoelectric resonators important parameter characterizing a piezoelectric material is the electromechanical coupling coefficient of Physics. DOI: 10.1063/1.2053366 The electromechanical coupling coefficient of piezoelec- tric materials

  12. Fourier Coefficients Of Some Cusp Forms

    E-Print Network [OSTI]

    N. A. Carella

    2013-10-10

    The possible values of the nth Fourier coefficients a(n) of some cusp forms f(z) of weight k => 12 are studied in this article. In particular, the values of the tau function are investigated in some details, and proved that tau(p) =! 0 for all primes p => p_0.

  13. APPENDIX A Landau Free-Energy Coefficients

    E-Print Network [OSTI]

    Chen, Long-Qing

    APPENDIX A ­ Landau Free-Energy Coefficients Long-Qing Chen Department of Materials Science of ferroelectrics is usually described by the phenomeno- logical Landau­Devonshire theory. Using the free energy for the unpolarized and unstrained crystal as the reference, the free energy of a ferroelectric crys- tal

  14. Carbon Smackdown: Carbon Capture

    SciTech Connect (OSTI)

    Jeffrey Long

    2010-07-12

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  15. Carbon Smackdown: Carbon Capture

    ScienceCinema (OSTI)

    Jeffrey Long

    2010-09-01

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  16. Carbon acceptors and carbon-hydrogen complexes in AlSb M. D. McCluskey*

    E-Print Network [OSTI]

    McCluskey, Matthew

    Carbon acceptors and carbon-hydrogen complexes in AlSb M. D. McCluskey* Department of Physics modes LVM's arising from carbon impurities in n- and p-type AlSb. The first and second harmonics. A peak at 572.9 cm 1 is tentatively identified as the 13 C LVM. Carbon-hydrogen complexes were formed

  17. Transport Coefficients and nPI Methods

    E-Print Network [OSTI]

    M. E. Carrington

    2011-10-06

    Transport coefficients can be obtained from 2-point correlators using the Kubo formulae. It has been shown that the full leading order result for electrical conductivity and (QCD) shear viscosity is contained in the re-summed 2-point function that is obtained from the 3-loop 3PI effective action. The theory produces all leading order contributions without the necessity for power counting, and in this sense it provides a natural framework for the calculation and suggests that one can calculate the next-to-leading contribution to transport coefficients from the 4-loop 4PI effective action. The integral equations have been derived for shear viscosity for a scalar theory with cubic and quartic interactions, with a non-vanishing field expectation value. We review these results, and explain how the calculation could be done at higher orders.

  18. Transport coefficients of a massive pion gas

    E-Print Network [OSTI]

    D. Fernandez-Fraile; A. Gomez Nicola

    2009-12-20

    We review or main results concerning the transport coefficients of a light meson gas, in particular we focus on the case of a massive pion gas. Leading order results according to the chiral power-counting are presented for the DC electrical conductivity, thermal conductivity, shear viscosity, and bulk viscosity. We also comment on the possible correlation between the bulk viscosity and the trace anomaly in QCD, as well as the relation between unitarity and a minimum of the quotient $\\eta/s$ near the phase transition.

  19. Transmission eigenvalues for operators with constant coefficients

    E-Print Network [OSTI]

    Michael Hitrik; Katsiaryna Krupchyk; Petri Ola; Lassi Päivärinta

    2010-04-28

    In this paper we study the interior transmission problem and transmission eigenvalues for multiplicative perturbations of linear partial differential operator of order $\\ge 2$ with constant real coefficients. Under suitable growth conditions on the symbol of the operator and the perturbation, we show the discreteness of the set of transmission eigenvalues and derive sufficient conditions on the existence of transmission eigenvalues. We apply these techniques to the case of the biharmonic operator and the Dirac system. In the hypoelliptic case we present a connection to scattering theory.

  20. Bounds on Transport Coefficients of Porous Media

    SciTech Connect (OSTI)

    Berryman, J G

    2005-03-21

    An analytical formulation of conductivity bounds by Bergman and Milton is used in a different way to obtain rigorous bounds on the real transport coefficients (electrical conductivity, thermal conductivity, and/or fluid permeability) of a fluid-saturated porous medium. These bounds do not depend explicitly on the porosity, but rather on two formation factors--one associated with the pore space and the other with the solid frame. Hashin-Shtrikman bounds for transport in random polycrystals of porous-material laminates will also be discussed.

  1. Shear Viscosity Coefficient from Microscopic Models

    E-Print Network [OSTI]

    Azwinndini Muronga

    2003-12-02

    The transport coefficient of shear viscosity is studied for a hadron matter through microscopic transport model, the Ultra--relativistic Quantum Molecular Dynamics (UrQMD), using the Green--Kubo formulas. Molecular--dynamical simulations are performed for a system of light mesons in a box with periodic boundary conditions. Starting from an initial state composed of $\\pi, \\eta ,\\omega ,\\rho ,\\phi$ with a uniform phase--space distribution, the evolution takes place through elastic collisions, production and annihilation. The system approaches a stationary state of mesons and their resonances, which is characterized by common temperature. After equilibration, thermodynamic quantities such as the energy density, particle density, and pressure are calculated. From such an equilibrated state the shear viscosity coefficient is calculated from the fluctuations of stress tensor around equilibrium using Green--Kubo relations. We do our simulations here at zero net baryon density so that the equilibration times depend on the energy density. We do not include hadron strings as degrees of freedom so as to maintain detailed balance. Hence we do not get the saturation of temperature but this leads to longer equilibration times.

  2. Soil Carbon Accumulation During Temperate Forest Succession

    E-Print Network [OSTI]

    Grogan, Paul

    K7L 3N6, Canada ABSTRACT Carbon sequestration in soils that have previously beendepletedoforganic the soil carbon sequestration potential of such lands by sampling adjacent mature forest and agricultural abandonment is more important than soil type in determining the potential magnitude of carbon sequestration

  3. Electromechanical coupling coefficient of an ultrasonic array element Moojoon Kim

    E-Print Network [OSTI]

    Cao, Wenwu

    Electromechanical coupling coefficient of an ultrasonic array element Moojoon Kim Materials for characterizing piezoelectric materials is the so-called electromechanical coupling coefficient, k, which describes the electromechanical coupling strength. Although this parameter should be an intrinsic material

  4. Limited Dependent Variable Correlated Random Coefficient Panel Data Models 

    E-Print Network [OSTI]

    Liang, Zhongwen

    2012-10-19

    for the average slopes of a linear CRC model with a general nonparametric correlation between regressors and random coefficients. I construct a sqrt(n) consistent estimator for the average slopes via varying coefficient regression. The identification of binary...

  5. Asymptotic normalization coefficients from ab initio calculations

    E-Print Network [OSTI]

    Kenneth M. Nollett; R. B. Wiringa

    2011-04-14

    We present calculations of asymptotic normalization coefficients (ANCs) for one-nucleon removals from nuclear states of mass numbers 3 to 9. Our ANCs were computed from variational Monte Carlo solutions to the many-body Schroedinger equation with the combined Argonne v18 two-nucleon and Urbana IX three-nucleon potentials. Instead of computing explicit overlap integrals, we applied a Green's function method that is insensitive to the difficulties of constructing and Monte Carlo sampling the long-range tails of the variational wave functions. This method also allows computation of the ANC at the physical separation energy, even when it differs from the separation energy for the Hamiltonian. We compare our results, which for most nuclei are the first ab initio calculations of ANCs, with existing experimental and theoretical results and discuss further possible applications of the technique.

  6. Continuously Controlled K-Theory with Variable Coefficients

    E-Print Network [OSTI]

    Continuously Controlled K-Theory with Variable Coefficients Douglas R. Anderson and Hans J modules with bounded control and variable coefficients to construct a homology theory on a certain control at infinity and variable coefficients, it has been less clear whether such a theory would have any

  7. Recursion relations for generalized Fresnel coefficients: Casimir force in a planar cavity

    E-Print Network [OSTI]

    Marin-Slobodan Tomas

    2010-04-06

    We emphasize and demonstrate that, besides using the usual recursion relations involving successive layers, generalized Fresnel coefficients of a multilayer can equivalently be calculated using the recursion relations involving stacks of layers, as introduced some time ago [M. S. Tomas, Phys. Rev. A 51, 2545 (1995)]. Moreover, since the definition of the generalized Fresnel coefficients employed does not imply properties of the stacks, these nonstandard recursion relations can be used to calculate Fresnel coefficients not only for local systems but also for a general multilayer consisting of various types (local, nonlocal, inhomogeneous etc.) of layers. Their utility is illustrated by deriving a few simple algorithms for calculating the reflectivity of a Bragg mirror and extending the formula for the Casimir force in a planar cavity to arbitrary media.

  8. High surface area diamond-like carbon electrodes grown on vertically aligned carbon nanotubes

    E-Print Network [OSTI]

    Bristol, University of

    High surface area diamond-like carbon electrodes grown on vertically aligned carbon nanotubes H packed forests of vertically aligned multiwall carbon nanotubes (VACNTs). The DLC:VACNT composite film and high corrosion resistance [13,14]. Other type of dopants, including nickel and boron, also result

  9. Control of Surface Functional Groups on Pertechntate Sorption on Activated Carbon

    SciTech Connect (OSTI)

    Y. Wang; H. Gao; R. Yeredla; H. Xu; M. Abrecht; G.D. Stasio

    2006-07-05

    {sup 99}Tc is highly soluble and poorly adsorbed by natural materials under oxidizing conditions, thus being of particular concern for radioactive waste disposal. Activated carbon can potentially be used as an adsorbent for removing Tc from aqueous solutions. We have tested six commercial activated carbon materials for their capabilities for sorption of pertechnetate (TcO{sub 4}{sup -}). The tested materials can be grouped into two distinct types: Type I materials have high sorption capabilities with the distribution coefficients (K{sub d}) varying from 9.5 x 10{sup 5} to 3.2 x 10{sup 3} mL/g as the pH changes from 4.5 to 9.5, whereas type II materials have relatively low sorption capabilities with K{sub d} remaining more or less constant (1.1 x 10{sup 3} - 1.8 x 10{sup 3} mL/g) over a similar pH range. The difference in sorption behavior between the two types of materials is attributed to the distribution of surface functional groups. The predominant surface groups are identified to be carboxylic and phenolic groups. The carboxylic group can be further divided into three subgroups A, B, and C in the order of increasing acidity. The high sorption capabilities of type I materials are found to be caused by the presence of a large fraction of carboxylic subgroups A and B, while the low sorption capabilities of type II materials are due to the exclusive presence of phenolic and carboxylic subgroup C. Therefore, the performance of activated carbon for removing TcO{sub 4}{sup -} can be improved by enhancing the formation of carboxylic subgroups A and B during material processing.

  10. Carbon Constraints and the Electric Power Industry

    SciTech Connect (OSTI)

    2007-11-15

    The report is designed to provide a thorough understanding of the type of carbon constraints that are likely to be imposed, when they are likely to take effect, and how they will impact the electric power industry. The main objective of the report is to provide industry participants with the knowledge they need to plan for and react to a future in which carbon emissions are restricted. The main goal of the report is to ensure an understanding of the likely restrictions that will be placed on carbon emissions, the methods available for reducing their carbon emissions, and the impact that carbon reductions will have on the electric power industry. A secondary goal of the report is to provide information on key carbon programs and market participants to enable companies to begin participating in the international carbon marketplace. Topics covered in the report include: overview of what climate change and the Kyoto Protocol are; analysis of the impacts of climate change on the U.S. and domestic efforts to mandate carbon reductions; description of carbon reduction mechanisms and the types of carbon credits that can be created; evaluation of the benefits of carbon trading and the rules for participation under Kyoto; Description of the methods for reducing carbon emissions available to the U.S. electric power industry; analysis of the impact of carbon restrictions on the U.S. electric power industry in terms of both prices and revenues; evaluation of the impact of carbon restrictions on renewable energy; overview of the current state of the global carbon market including descriptions of the three major marketplaces; descriptions of the industry and government programs already underway to reduce carbon emissions in the U.S. electric power industry; and, profiles of the major international carbon exchanges and brokers.

  11. Carbon Markets: A Potential Source of Income for Farmers and Ranchers 

    E-Print Network [OSTI]

    Ribera, Luis; Zenteno, Joaquin; McCarl, Bruce

    2009-03-10

    Agricultural producers may be able to increase their earnings by selling carbon credits to large carbon emitters. This publication explains the origins of the carbon market, the types of projects agriculturists can undertake, and the steps...

  12. Computational Geosciences Improved Semi-Analytical Simulation of Geological Carbon Sequestration

    E-Print Network [OSTI]

    Bau, Domenico A.

    Computational Geosciences Improved Semi-Analytical Simulation of Geological Carbon Sequestration of Geological Carbon Sequestration Article Type: Manuscript Keywords: Semi-Analytical Modeling; Iterative Methods; Geological Carbon Sequestration; Injection Site Assessment Corresponding Author: Brent Cody

  13. A pumping system for measuring coastal diffusion coefficients 

    E-Print Network [OSTI]

    Bolen, Zane Kevin

    1980-01-01

    system was used to measure surface horizontal diffusion coefficients in the vicin- ity of the diffuser. These experiments were also used to develop tech- niques of underway sampling as well as measuring site specific horizon- tal diffusion... coefficients. Measurement of horizontal diffusion coef- ficients used a continuous point source of tracer material to produce a plume that could be profiled using the pumping system connected to a fluorometer. The resultant horizontal diffusion coefficients...

  14. Diffusion coefficient of three-dimensional Yukawa liquids

    SciTech Connect (OSTI)

    Dzhumagulova, K. N.; Ramazanov, T. S.; Masheeva, R. U. [IETP, Al Farabi Kazakh National University, 71, al Farabi ave., Almaty 050040 (Kazakhstan)] [IETP, Al Farabi Kazakh National University, 71, al Farabi ave., Almaty 050040 (Kazakhstan)

    2013-11-15

    The purpose of this work is an investigation of the diffusion coefficient of the dust component in complex plasma. The computer simulation of the Yukawa liquids was made on the basis of the Langevin equation, which takes into account the influence of buffer plasma on the dust particles dynamics. The Green–Kubo relation was used to calculate the diffusion coefficient. Calculations of the diffusion coefficient for a wide range of the system parameters were performed. Using obtained numerical data, we constructed the interpolation formula for the diffusion coefficient. We also show that the interpolation formula correctly describes experimental data obtained under microgravity conditions.

  15. Derivation of the coefficient squared probability law in quantum mechanics

    E-Print Network [OSTI]

    Casey Blood

    2013-06-02

    If one assumes there is probability of perception in quantum mechanics, then unitarity dictates that it must have the coefficient squared form, in agreement with experiment.

  16. Reflection and transmission coefficients of a fracture in transversely ...

    E-Print Network [OSTI]

    2011-11-28

    dependent reflection and transmission coefficients. On the other hand, velocity discontinuities generate an energy loss at the interface. The specific viscosity ...

  17. TEMPERATURE COEFFICIENTS FOR PV MODULES AND ARRAYS: MEASUREMENT...

    Office of Scientific and Technical Information (OSTI)

    0 ABSTRACT The term "temperature coefficient" has been applied to several different photovoltaic performance parameters, including voltage, current, and power. The procedures for...

  18. Rigorous bounds on Transmission, Reflection, and Bogoliubov coefficients

    E-Print Network [OSTI]

    Boonserm, Petarpa

    2009-01-01

    This thesis describes the development of some basic mathematical tools of wide relevance to mathematical physics. Transmission and reflection coefficients are associated with quantum tunneling phenomena, while Bogoliubov coefficients are associated with the mathematically related problem of excitations of a parametric oscillator. While many approximation techniques for these quantities are known, very little is known about rigorous upper and lower bounds. In this thesis four separate problems relating to rigorous bounds on transmission, reflection and Bogoliubov coefficients are considered, divided into four separate themes: 1) Bounding the Bogoliubov coefficients; 2) Bounding the greybody factors for Schwarzschild black holes; 3) Transformation probabilities and the Miller--Good transformation; 4) Analytic bounds on transmission probabilities.

  19. Kernel Carpentry for Online Regression using Randomly Varying Coefficient Model 

    E-Print Network [OSTI]

    Edakunni, Narayanan U.; Schaal, Stefan; Vijayakumar, Sethu

    2006-01-01

    We present a Bayesian formulation of locally weighted learning (LWL) using the novel concept of a randomly varying coefficient model. Based on this

  20. Carbon Fiber

    SciTech Connect (OSTI)

    McGetrick, Lee

    2014-04-17

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  1. Carbon Fiber

    ScienceCinema (OSTI)

    McGetrick, Lee

    2014-07-23

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  2. Carbon Sequestration

    SciTech Connect (OSTI)

    2013-05-06

    Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

  3. A model for the diffuse attenuation coefficient of downwelling irradiance

    E-Print Network [OSTI]

    Lee, Zhongping

    A model for the diffuse attenuation coefficient of downwelling irradiance Zhong-Ping Lee1 Naval] The diffuse attenuation coefficient for downwelling irradiance (Kd) is an important parameter for ocean of downwelling irradiance, J. Geophys. Res., 110, C02016, doi:10.1029/2004JC002275. 1. Introduction [2] Diffuse

  4. Mayer coefficients in two-dimensional Coulomb systems

    SciTech Connect (OSTI)

    Speer E.R.

    1986-03-01

    It is shown that, for neutral systems of particles of arbitrary charges in two dimensions, with hard cores, coefficients of the Mayer series for the pressure exist in the thermodynamic limit below certain thresholds in the temperature. The methods used here apply also to correlation functions and yield bounds on the asymptotic behavior of their Mayer coefficients.

  5. Fast Computation of Local Correlation Coefficients on Graphics Processing Units

    E-Print Network [OSTI]

    Pitsianis, Nikos P.

    Fast Computation of Local Correlation Coefficients on Graphics Processing Units Georgios and architectural means, for fast calcula- tion of local correlation coefficients, which is a basic image the use of multi-dimensional fast Fourier transforms, without losing or sacrificing local and non

  6. Particulate optical scattering coefficients along an Atlantic Meridional Transect

    E-Print Network [OSTI]

    Boss, Emmanuel S.

    Particulate optical scattering coefficients along an Atlantic Meridional Transect G. Dall'Olmo,1, E, USA gdal@pml.ac.uk Abstract: The particulate optical backscattering coefficient (bbp) is a fundamental optical property that allows monitoring of marine suspended particles both in situ and from space

  7. Micro- and macroscale coefficients of friction of cementitious materials

    SciTech Connect (OSTI)

    Lomboy, Gilson; Sundararajan, Sriram; Wang, Kejin

    2013-12-15

    Millions of metric tons of cementitious materials are produced, transported and used in construction each year. The ease or difficulty of handling cementitious materials is greatly influenced by the material friction properties. In the present study, the coefficients of friction of cementitious materials were measured at the microscale and macroscale. The materials tested were commercially-available Portland cement, Class C fly ash, and ground granulated blast furnace slag. At the microscale, the coefficient of friction was determined from the interaction forces between cementitious particles using an Atomic Force Microscope. At the macroscale, the coefficient of friction was determined from stresses on bulk cementitious materials under direct shear. The study indicated that the microscale coefficient of friction ranged from 0.020 to 0.059, and the macroscale coefficient of friction ranged from 0.56 to 0.75. The fly ash studied had the highest microscale coefficient of friction and the lowest macroscale coefficient of friction. -- Highlights: •Microscale (interparticle) coefficient of friction (COF) was determined with AFM. •Macroscale (bulk) COF was measured under direct shear. •Fly ash had the highest microscale COF and the lowest macroscale COF. •Portland cement against GGBFS had the lowest microscale COF. •Portland cement against Portland cement had the highest macroscale COF.

  8. THE COHOMOLOGY OF Gm;2 WITH TWISTED INTEGER COEFFICIENTS

    E-Print Network [OSTI]

    Cadek, Martin

    THE COHOMOLOGY OF Gm;2 WITH TWISTED INTEGER COEFFICIENTS Martin Ÿ Cadek, JiŸ r' i VanŸ zura Abstract. Let H \\Lambda (Gm;2 ; Z t ) be the graded cohomology group of the Grassmann manifold Gm;2 with twisted integer coefficients. Then H \\Lambda (Gm;2 ; Z) \\Phi H \\Lambda (Gm;2 ; Z t ) has a structure

  9. Analysis of alternative methods for estimating carbon stock in young tropical plantations

    E-Print Network [OSTI]

    Bermingham, Eldredge

    .2%, supporting our hypothesis. # 2003 Elsevier Science B.V. All rights reserved. Keywords: Carbon sequestration of these plantations to sequester carbon has received renewed interest, since carbon sequestration projects). A good estimate of carbon sequestration is essential to any project of this type. The rate of carbon

  10. Gas Chromatography Data Classification Based on Complex Coefficients of an Autoregressive Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Weixiang; Morgan, Joshua T.; Davis, Cristina E.

    2008-01-01

    This paper introduces autoregressive (AR) modeling as a novel method to classify outputs from gas chromatography (GC). The inverse Fourier transformation was applied to the original sensor data, and then an AR model was applied to transform data to generate AR model complex coefficients. This series of coefficients effectively contains a compressed version of all of the information in the original GC signal output. We applied this method to chromatograms resulting from proliferating bacteria species grown in culture. Three types of neural networks were used to classify the AR coefficients: backward propagating neural network (BPNN), radial basis function-principal component analysismore »(RBF-PCA) approach, and radial basis function-partial least squares regression (RBF-PLSR) approach. This exploratory study demonstrates the feasibility of using complex root coefficient patterns to distinguish various classes of experimental data, such as those from the different bacteria species. This cognition approach also proved to be robust and potentially useful for freeing us from time alignment of GC signals.« less

  11. Computing Limb Darkening Coefficients from Stellar Atmosphere Models

    E-Print Network [OSTI]

    David Heyrovsky

    2006-10-24

    We explore the sensitivity of limb darkening coefficients computed from stellar atmosphere models to different least-squares fitting methods. We demonstrate that conventional methods are strongly biased to fitting the stellar limb. Our suggested method of fitting by minimizing the radially integrated squared residual yields improved fits with better flux conservation. The differences of the obtained coefficients from commonly used values are observationally significant. We show that the new values are in better agreement with solar limb darkening measurements as well as with coefficients reported from analyses of eclipsing binary light curves.

  12. Carbon particles

    DOE Patents [OSTI]

    Hunt, Arlon J. (Oakland, CA)

    1984-01-01

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  13. Carbon supercapacitors

    SciTech Connect (OSTI)

    Delnick, F.M.

    1993-11-01

    Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

  14. Experimental identification of structural force coefficients in a bump-type foil bearing 

    E-Print Network [OSTI]

    Breedlove, Anthony Wayne

    2009-06-02

    temperature applications. During actual operation with shaft rotation, the bearing structural parameters are coupled to the effects of a hydrodynamic gas film layer, thus determining the overall bearing load performance. A 38.17 mm inner diameter foil bearing...

  15. Estimation of Diffusion Coefficient of Lithium in Carbon Using AC Impedance Technique

    E-Print Network [OSTI]

    ,* Venkat R. Subramanian,** John W. Weidner,** and R. E. White***,z Center for Electrochemical Engineering, Department of Chemical Engineering, University of South Carolina, Columbia, South Carolina 29208, USA useful. It was an extension of the Haran et al. model7 of a metal hydride electrode for alkaline

  16. Power series with sum-product Taylor coefficients and their resurgence algebra

    E-Print Network [OSTI]

    Ecalle, Jean

    2009-01-01

    The present paper is devoted to power series of SP type, i.e. with coefficients that are syntactically sum-product combinations. Apart from their applications to analytic knot theory and the so-called "Volume Conjecture'', SP-series are interesting in their own right, on at least four accounts: (i) they generate quite distinctive resurgence algebras (ii) they are one of those relatively rare instances when the resurgence properties have to be derived directly from the Taylor coefficients (iii) some of them produce singularities that unexpectedly verify finite-order differential equations (iv) all of them are best handled with the help of two remarkable, infinite-order integral-differential transforms, "mir" and "nir".

  17. Transport Coefficients for Holographic Hydrodynamics at Finite Energy Scale

    E-Print Network [OSTI]

    Xian-Hui Ge; Hong-Qiang Leng; Li Qing Fang; Guo-Hong Yang

    2014-08-19

    We investigate the relations between black hole thermodynamics and holographic transport coefficients in this paper. The formulae for DC conductivity and diffusion coefficient are verified for electrically single-charged black holes. We examine the correctness of the proposed expressions by taking charged dilatonic and single-charged STU black holes as two concrete examples, and compute the flows of conductivity and diffusion coefficient by solving the linear order perturbation equations. We then check the consistence by evaluating the Brown-York tensor at a finite radial position. Finally, we find that the retarded Green functions for the shear modes can be expressed easily in terms of black hole thermodynamic quantities and transport coefficients.

  18. Seal assembly for materials with different coefficients of thermal expansion

    DOE Patents [OSTI]

    Minford, Eric (Laurys Station, PA)

    2009-09-01

    Seal assembly comprising (a) two or more seal elements, each element having having a coefficient of thermal expansion; and (b) a clamping element having a first segment, a second segment, and a connecting segment between and attached to the first and second segments, wherein the two or more seal elements are disposed between the first and second segments of the clamping element. The connecting segment has a central portion extending between the first segment of the clamping element and the second segment of the clamping element, and the connecting segment is made of a material having a coefficient of thermal expansion. The coefficient of thermal expansion of the material of the connecting segment is intermediate the largest and smallest of the coefficients of thermal expansion of the materials of the two or more seal elements.

  19. Multilayer electromechanical composites with controlled piezoelectric coefficient distribution

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    Multilayer electromechanical composites with controlled piezoelectric coefficient distribution-2875 ABSTRACT We have fabricated multilayer electromechanical composites with controlled piezoelectric in accordance with their characteristic electromechanical coupling values and modulus of elasticity

  20. Connection between asymptotic normalization coefficients, subthreshold bound states, and resonances 

    E-Print Network [OSTI]

    Mukhamedzhanov, AM; Tribble, Robert E.

    1999-01-01

    We present here useful relations showing the connection between the asymptotic normalization coefficient (ANC) and the fitting parameters in K- and R-matrix theory methods which are often used when analyzing low energy experimental data. It is shown...

  1. KRONECKER COEFFICIENTS FOR SOME NEAR-RECTANGULAR VASU V. TEWARI

    E-Print Network [OSTI]

    Fournier, John J.F.

    KRONECKER COEFFICIENTS FOR SOME NEAR-RECTANGULAR PARTITIONS VASU V. TEWARI Abstract. We give function, Young tableau, near-rectangle, bounded height. 1 #12;2 VASU V. TEWARI computing them

  2. Coefficient quantization effects in block state variable digital filters 

    E-Print Network [OSTI]

    Lee, Kab Joo

    1991-01-01

    COEFFICIENT QUANTIZATION EFFECTS IN BLOCK STATE VARIABLE DIGITAL FILTERS A Thesis by KAB JOO LEE Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1991 Major Subject: Electrical Engineering COEFFICIENT QIJANTIZATIOU EFFECTS IN l3LOCI~ STATE VARIABLE DIGITAL FILTERS A Thesis hs IiAB JOO LEE Approved as to style and content by: WVilliam G. )3liss (Chair of Comnaittee) Norman C...

  3. Type A Accident Investigation Board Report of the July 28, 1998, Fatality and Multiple Injuries Resulting from Release of Carbon Dioxide at Building 648, Test Reactor Area, Idaho National Engineering and Environmental Laboratory

    Broader source: Energy.gov [DOE]

    This report is an independent product of the Type A Accident Investigation Board appointed by Peter N. Brush, Acting Assistant Secretary for Environment, Safety and Health (EH-1).

  4. LIMB-DARKENING COEFFICIENTS FOR ECLIPSING WHITE DWARFS

    SciTech Connect (OSTI)

    Gianninas, A.; Strickland, B. D.; Kilic, Mukremin [Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, 440 W. Brooks St., Norman, OK 73019 (United States)] [Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, 440 W. Brooks St., Norman, OK 73019 (United States); Bergeron, P., E-mail: alexg@nhn.ou.edu, E-mail: benstrickland@ou.edu, E-mail: kilic@ou.edu, E-mail: bergeron@astro.umontreal.ca [Departement de Physique, Universite de Montreal, C.P. 6128, Succ. Centre-Ville, Montreal, Quebec H3C 3J7 (Canada)

    2013-03-20

    We present extensive calculations of linear and nonlinear limb-darkening coefficients as well as complete intensity profiles appropriate for modeling the light-curves of eclipsing white dwarfs. We compute limb-darkening coefficients in the Johnson-Kron-Cousins UBVRI photometric system as well as the Large Synoptic Survey Telescope (LSST) ugrizy system using the most up to date model atmospheres available. In all, we provide the coefficients for seven different limb-darkening laws. We describe the variations of these coefficients as a function of the atmospheric parameters, including the effects of convection at low effective temperatures. Finally, we discuss the importance of having readily available limb-darkening coefficients in the context of present and future photometric surveys like the LSST, Palomar Transient Factory, and the Panoramic Survey Telescope and Rapid Response System (Pan-STARRS). The LSST, for example, may find {approx}10{sup 5} eclipsing white dwarfs. The limb-darkening calculations presented here will be an essential part of the detailed analysis of all of these systems.

  5. Type Ia Supernova Explosion Models

    E-Print Network [OSTI]

    W. Hillebrandt; J. C. Niemeyer

    2000-06-21

    Because calibrated light curves of Type Ia supernovae have become a major tool to determine the local expansion rate of the Universe and also its geometrical structure, considerable attention has been given to models of these events over the past couple of years. There are good reasons to believe that perhaps most Type Ia supernovae are the explosions of white dwarfs that have approached the Chandrasekhar mass, M_ch ~ 1.39 M_sun, and are disrupted by thermonuclear fusion of carbon and oxygen. However, the mechanism whereby such accreting carbon-oxygen white dwarfs explode continues to be uncertain. Recent progress in modeling Type Ia supernovae as well as several of the still open questions are addressed in this review. Although the main emphasis will be on studies of the explosion mechanism itself and on the related physical processes, including the physics of turbulent nuclear combustion in degenerate stars, we also discuss observational constraints.

  6. Raspberry derived mesoporous carbon-tubules and fixed-bed adsorption of pharmaceutical drugs

    E-Print Network [OSTI]

    Ma, Lena

    Raspberry derived mesoporous carbon-tubules and fixed-bed adsorption of pharmaceutical drugs Shashi Department, University of Florida, Gainesville, FL 32611-0290, USA 1. Introduction Pharmaceutical drugs (PD­water partition coefficient Pharmaceutical drugs A B S T R A C T Novel mesoporous carbon-tubules were prepared

  7. Thermoelectric Behavior of Flexible Organic Nanocomposites with Carbon Nanotubes 

    E-Print Network [OSTI]

    Choi, Kyung Who

    2013-12-03

    .3 Results and discussion …………………………………………….27 vi Page 3.4 Conclusions………………………………………………………..34 CHAPTER IV HIGHLY DOPED CARBON NANOTUBES WITH GOLD NANOPARTICLES AND THEIR INFLUENCE ON ELECTRICAL CONDUCTIVITY AND THERMOPOWER ………..36 4... with carbon nanotubes ………...76 7.3 Highly doped carbon nanotubes with gold nanoparticles and their influence on electric conductivity and thermopower……………………………………………………...77 7.4 N-type thermoelectric performance of functionalized carbon nanotube...

  8. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01

    Li, M. Daskin. 2009. Carbon Footprint and the Management ofThe Importance of Carbon Footprint Estimation Boundaries.Carbon accounting and carbon footprint - more than just

  9. Public Review Draft: A Method for Assessing Carbon Stocks, Carbon

    E-Print Network [OSTI]

    Public Review Draft: A Method for Assessing Carbon Stocks, Carbon Sequestration, and Greenhouse, and Zhu, Zhiliang, 2010, Public review draft; A method for assessing carbon stocks, carbon sequestration

  10. Transport coefficients of solid particles immersed in a viscous gas

    E-Print Network [OSTI]

    Vicente Garzó; William D. Fullmer; Christine M. Hrenya; Xiaolong Yin

    2015-11-12

    Transport properties of a suspension of solid particles in a viscous gas are studied. The dissipation in such systems arises from two sources: inelasticity in particle collisions and viscous dissipation due to the effect of the gas phase on the particles. Here, we consider a simplified case in which the mean relative velocity between the gas and solid phases is taken to be zero, such that "thermal drag" is the only remaining gas-solid interaction. Unlike the previous more general treatment of the drag force [Garz\\'o \\emph{et al.}, J. Fluid Mech. \\textbf{712}, 129 (2012)], here we take into account contributions to the (scaled) transport coefficients $\\eta^*$ (shear viscosity), $\\kappa^*$ (thermal conductivity) and $\\mu^*$ (Dufour-like coefficient) coming from the temperature-dependence of the (dimensionless) friction coefficient $\\gamma^*$ characterizing the amplitude of the drag force. At moderate densities, the thermal drag model (which is based on the Enskog kinetic equation) is solved by means of the Chapman-Enskog method and the Navier-Stokes transport coefficients are determined in terms of the coefficient of restitution, the solid volume fraction and the friction coefficient. The results indicate that the effect of the gas phase on $\\eta^*$ and $\\mu^*$ is non-negligible (especially in the case of relatively dilute systems) while the form of $\\kappa^*$ is the same as the one obtained in the dry granular limit. Finally, as an application of these results, a linear stability analysis of the hydrodynamic equations is carried out to analyze the conditions for stability of the homogeneous cooling state. A comparison with direct numerical simulations shows a good agreement for conditions of practical interest.

  11. Lattice-structures and constructs with designed thermal expansion coefficients

    DOE Patents [OSTI]

    Spadaccini, Christopher; Hopkins, Jonathan

    2014-10-28

    A thermal expansion-managed lattice structure having a plurality of unit cells each having flexure bearing-mounted tabs supported on a base and actuated by thermal expansion of an actuator having a thermal expansion coefficient greater than the base and arranged so that the tab is inwardly displaced into a base cavity. The flexure bearing-mounted tabs are connected to other flexure-bearing-mounted tabs of adjacent unit cells so that the adjacent unit cells are spaced from each other to accommodate thermal expansion of individual unit cells while maintaining a desired bulk thermal expansion coefficient of the lattice structure as a whole.

  12. Transport Coefficients for the Hard Sphere Granular Fluid

    E-Print Network [OSTI]

    Aparna Baskaran; James W. Dufty; J. Javier Brey

    2006-12-15

    In the preceding paper, linear response methods have been applied to obtain formally exact expressions for the parameters of Navier-Stokes order hydrodynamics. The analysis there is general, applying to both normal and granular fluids with a wide range of collision rules. Those results are specialized here to the case of smooth, inelastic hard spheres with constant coefficient of normal restitution, for further elaboration. Explicit expressions for the cooling rate, pressure, and the transport coefficients are given and compared with the corresponding expressions for a system of elastic hard spheres. The scope of the results for further analytical explorations and possible numerical evaluation is discussed.

  13. Backscattering and absorption coefficients for electrons: Solutions of invariant embedding transport equations using a method of convergence

    SciTech Connect (OSTI)

    Figueroa, C.; Brizuela, H.; Heluani, S. P.

    2014-05-21

    The backscattering coefficient is a magnitude whose measurement is fundamental for the characterization of materials with techniques that make use of particle beams and particularly when performing microanalysis. In this work, we report the results of an analytic method to calculate the backscattering and absorption coefficients of electrons in similar conditions to those of electron probe microanalysis. Starting on a five level states ladder model in 3D, we deduced a set of integro-differential coupled equations of the coefficients with a method know as invariant embedding. By means of a procedure proposed by authors, called method of convergence, two types of approximate solutions for the set of equations, namely complete and simple solutions, can be obtained. Although the simple solutions were initially proposed as auxiliary forms to solve higher rank equations, they turned out to be also useful for the estimation of the aforementioned coefficients. In previous reports, we have presented results obtained with the complete solutions. In this paper, we present results obtained with the simple solutions of the coefficients, which exhibit a good degree of fit with the experimental data. Both the model and the calculation method presented here can be generalized to other techniques that make use of different sorts of particle beams.

  14. Carbon Fiber Consortium | Partnerships | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Fiber Consortium SHARE Carbon Fiber Consortium Oak Ridge Carbon Fiber Composites Consortium The Oak Ridge Carbon Fiber Composites Consortium was established in 2011 to...

  15. The transport coefficient $\\hat{q}$ in an anisotropic plasma

    E-Print Network [OSTI]

    Yacine Mehtar-Tani

    2009-09-15

    We investigate the jet quenching parameter in the case of a fast moving quark in an anisotropic plasma. In the leading log approximation, strong indications are found that the transport coefficient increases with increasing anisotropy. Implications for the phenomenology at RHIC are discussed.

  16. Electromagnetic fields and transport coefficients in a hot pion gas

    E-Print Network [OSTI]

    A. Gomez Nicola; D. Fernandez-Fraile

    2006-08-24

    We present recent results on finite temperature electromagnetic form factors and the electrical conductivity in a pion gas. The standard Chiral Perturbation Theory power counting needs to be modified for transport coefficients. We pay special attention to unitarity and to possible applications for dilepton and photon production.

  17. Transport coefficients of a mesoscopic fluid dynamics model

    E-Print Network [OSTI]

    N. Kikuchi; C. M. Pooley; J. F. Ryder; J. M. Yeomans

    2003-02-21

    We investigate the properties of stochastic rotation dynamics (Malevanets-Kapral method), a mesoscopic model used for simulating fluctuating hydrodynamics. Analytical results are given for the transport coefficients. We discuss the most efficient way of measuring the transport properties and obtain excellent agreement between the theoretical and numerical calculations.

  18. Predicting Soil-Water Partition Coefficients for Cadmium

    E-Print Network [OSTI]

    Sparks, Donald L.

    Predicting Soil-Water Partition Coefficients for Cadmium S U E N - Z O N E L E E Department, University of Delaware, Newark, Delaware 19716 D O N A L D L . S P A R K S Department of Plant and Soil of Cd(II) on 15 New Jersey soils. The soils were characterized in terms of surface properties

  19. Adaptive Calculation of Variable Coefficients Elliptic Differential Equations via Wavelets

    E-Print Network [OSTI]

    Averbuch, Amir

    Adaptive Calculation of Variable Coefficients Elliptic Differential Equations via Wavelets Amir in numerical solution of differential and integral equations. Classical methods for discretization lead-based multiplication is af- fected by different input parameters for the algorithm. We integrated a sparse

  20. The effective pyroelectric and thermal expansion coefficients of ferroelectric ceramics

    E-Print Network [OSTI]

    Li, Jiangyu

    The effective pyroelectric and thermal expansion coefficients of ferroelectric ceramics JiangYu Li ceramics in terms of their microstructural information. The overall behaviors of ferroelectric ceramics be induced in an originally isotropic, thus non-pyroelectric ceramic composed of randomly oriented

  1. Carbon monoxide sensor and method of use thereof

    DOE Patents [OSTI]

    McDaniel; Anthony H. (Livermore, CA), Medlin; J. Will (Boulder, CO), Bastasz; Robert J. (Livermore, CA)

    2007-09-04

    Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

  2. US Department of Transportation (DOT) Spec 7A Type A evaluation document: Spec 17C 55-gal steel drum with RWMC/SWEPP drum venting system carbon filter assembly

    SciTech Connect (OSTI)

    Edling, D.A.

    1986-09-15

    As part of MRC-Mound's responsibility to coordinate DOE Spec 7A Type A Packaging testing, evaluation, and utilization, this document evaluates per 49CFR 173.415(a) the SWEPP packaging system: DOT Spec 17C steel drums - 30, 55 and 83-gal; High Density Polyethylene (HDPE) liners; and SWEPP DVS Filter Assemblies (two configurations) as a US DOT Spec 7A Type A packaging. A variety of Type A performance testing was done on: DOT Spec 17C 55-gal steel drums; DOT Spec 17C 55-gal steel drums with HDPE liners; and DOT Spec 17C 55-gal steel drums with ''Nucfil'' filters as part of MRC-Mound's Type A Packaging Evaluation Program funded by DOE/HQ, DP-4, Security Evaluations. The subject SWEPP packaging incorporates modifications to the ''Nucfil'' filter and installation assembly previously tested in conjunction with the Spec 17C 55-gal drums. Thus, additional testing was required on the new filter installation in order to evaluate the entire packaging system. This document presents the test data to demonstrate the SWEPP packaging system's performance against the DOT 7A Type A requirements.

  3. Photophysics of carbon nanotubes

    E-Print Network [OSTI]

    Samsonidze, Georgii G

    2007-01-01

    This thesis reviews the recent advances made in optical studies of single-wall carbon nanotubes. Studying the electronic and vibrational properties of carbon nanotubes, we find that carbon nanotubes less than 1 nm in ...

  4. Parameterization of the Extinction Coefficient in Ice and Mixed-Phase Arctic Clouds during the ISDAC Field Campaign

    SciTech Connect (OSTI)

    Korolev, A; Shashkov, A; Barker, H

    2012-03-06

    This report documents the history of attempts to directly measure cloud extinction, the current measurement device known as the Cloud Extinction Probe (CEP), specific problems with direct measurement of extinction coefficient, and the attempts made here to address these problems. Extinction coefficient is one of the fundamental microphysical parameters characterizing bulk properties of clouds. Knowledge of extinction coefficient is of crucial importance for radiative transfer calculations in weather prediction and climate models given that Earth's radiation budget (ERB) is modulated much by clouds. In order for a large-scale model to properly account for ERB and perturbations to it, it must ultimately be able to simulate cloud extinction coefficient well. In turn this requires adequate and simultaneous simulation of profiles of cloud water content and particle habit and size. Similarly, remote inference of cloud properties requires assumptions to be made about cloud phase and associated single-scattering properties, of which extinction coefficient is crucial. Hence, extinction coefficient plays an important role in both application and validation of methods for remote inference of cloud properties from data obtained from both satellite and surface sensors (e.g., Barker et al. 2008). While estimation of extinction coefficient within large-scale models is relatively straightforward for pure water droplets, thanks to Mie theory, mixed-phase and ice clouds still present problems. This is because of the myriad forms and sizes that crystals can achieve, each having their own unique extinction properties. For the foreseeable future, large-scale models will have to be content with diagnostic parametrization of crystal size and type. However, before they are able to provide satisfactory values needed for calculation of radiative transfer, they require the intermediate step of assigning single-scattering properties to particles. The most basic of these is extinction coefficient, yet it is rarely measured directly, and therefore verification of parametrizations is difficult. The obvious solution is to be able to measure microphysical properties and extinction at the same time and for the same volume. This is best done by in situ sampling by instruments mounted on either balloon or aircraft. The latter is the usual route and the one employed here. Yet the problem of actually measuring extinction coefficient directly for arbitrarily complicated particles still remains unsolved.

  5. Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production

    E-Print Network [OSTI]

    Narasayya, Vivek

    #12;Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward

  6. TOC Total organic carbon MBC Microbial biomass carbon

    E-Print Network [OSTI]

    Virginia Tech

    C Carbon TOC Total organic carbon MBC Microbial biomass carbon Active C Pool Indicated by Light, the relationship between carbon dynamics including total organic carbon (TOC) storage, microbial biomass carbon and microbial biomass carbon in subsoil 4 years after rehabilitation · Microbial biomass carbon had a positive

  7. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B. (16716 Martincoit Rd., Poway, CA 92064)

    1993-01-01

    A process for making 2D and 3D carbon-carbon composites having a combined high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizible woven cloth are infiltrated with carbon material to form green composites. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnant step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3100.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. C. to 1300.degree. C. at a reduced. pressure.

  8. Interfacial Studies of Sized Carbon Fiber

    SciTech Connect (OSTI)

    Shahrul, S. N.; Hartini, M. N.; Hilmi, E. A.; Nizam, A. [Nanomaterials Program, Advance Materials Centre (AMREC), SIRIM Berhad, Lot 34, Jalan Hi-Tech Park, 09000, Kulim, Kedah (Malaysia)

    2010-03-11

    This study was performed to investigate the influence of sizing treatment on carbon fiber in respect of interfacial adhesion in composite materials, Epolam registered 2025. Fortafil unsized carbon fiber was used to performed the experiment. The fiber was commercially surface treated and it was a polyacrylonitrile based carbon fiber with 3000 filament per strand. Epicure registered 3370 was used as basic sizing chemical and dissolved in two types of solvent, ethanol and acetone for the comparison purpose. The single pull out test has been used to determine the influence of sizing on carbon fiber. The morphology of carbon fiber was observed by atomic force microscopy (AFM) and scanning electron microscopy (SEM). The apparent interfacial strength IFSS values determined by pull out test for the Epicure registered 3370/ethanol sized carbon fiber pointed to a good interfacial behaviour compared to the Epicure registered 3370/acetone sized carbon fiber. The Epicure registered 3370/ethanol sizing agent was found to be effective in promoting adhesion because of the chemical reactions between the sizing and Epolam registered 2025 during the curing process. From this work, it showed that sized carbon fiber using Epicure registered 3370 with addition of ethanol give higher mechanical properties of carbon fiber in terms of shear strength and also provided a good adhesion between fiber and matrix compared to the sizing chemical that contain acetone as a solvent.

  9. Carbon Capture (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Smit, Berend

    2011-06-08

    Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  10. Blood Types

    E-Print Network [OSTI]

    Hacker, Randi; Tsutsui, William

    2007-03-14

    Sox spent a hundred mil to acquire pitcher Daisuke Matsuzaka; they probably weren't even aware that he is a Type O and that they make the best bankers, politicians and... you guessed it... professional baseball players. #ceas #hacker #japan #tsutsuien...

  11. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1997-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  12. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  13. Temperature dependent transport coefficients in a dynamical holographic QCD model

    E-Print Network [OSTI]

    Danning Li; Song He; Mei Huang

    2014-11-19

    We investigate temperature dependent behavior of various transport coefficients in a dynamical holographical QCD model. We show the nontrivial temperature dependent behavior of the transport coefficients, like bulk viscosity, electric conductivity as well as jet quenching parameter, and it is found that all these quantities reveal information of the phase transition. Furthermore, with introducing higher derivative corrections in 5D gravity, the shear viscosity over entropy density ratio also shows a valley around phase transition, and it is found that the shear viscosity over entropy density ratio times the jet quenching over temperature cubic ratio almost remains as a constant above phase transition, and the value is two times larger than the perturbative result in Phys.Rev.Lett.99.192301(2007).

  14. Transport coefficients of soft sphere fluids at high densities

    E-Print Network [OSTI]

    Yu. D. Fomin; V. V. Brazhkin; V. N. Ryzhov

    2010-03-19

    Molecular dynamics computer simulation has been used to compute the self-diffusion coefficient, and shear viscosity of soft-sphere fluids, in which the particles interact through the soft-sphere or inverse power pair potential. The calculations have been made along the melting line in a wide range of pressures and temperatures. The validity of scaling relations for thermodynamic parameters and kinetic coefficients was checked. It was shown that the Stokes-Einstein relationship is obeyed if the Barker diameter is used as a characteristic length scale. It was also shown that the viscosity is non-monotonic along the isochores as predicted by Ya. Rosenfeld. It was shown that the viscosity is strongly growing along the melting line, however, this increase does not stimulate the glass transition because the relaxation time is decreasing.

  15. Estimation of the effective distribution coefficient from the solubility constant

    SciTech Connect (OSTI)

    Wang, Yug-Yea; Yu, C.

    1994-07-01

    An updated version of RESRAD has been developed by Argonne National Laboratory for the US Department of Energy to derive site-specific soil guidelines for residual radioactive material. In this updated version, many new features have been added to the, RESRAD code. One of the options is that a user can input a solubility constant to limit the leaching of contaminants. The leaching model used in the code requires the input of an empirical distribution coefficient, K{sub d}, which represents the ratio of the solute concentration in soil to that in solution under equilibrium conditions. This paper describes the methodology developed to estimate an effective distribution coefficient, Kd, from the user-input solubility constant and the use of the effective K{sub d} for predicting the leaching of contaminants.

  16. ARM: 10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Newsom, Rob; Goldsmith, John

    1998-03-01

    10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  17. ARM: 1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  18. ARM: 2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2004-10-01

    2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  19. ARM: 10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  20. ARM: 10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  1. ARM: 10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  2. ARM: 2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  3. ARM: 1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  4. Theoretical rate coefficients for allyl + HO2 and allyloxy decomposition

    SciTech Connect (OSTI)

    Goldsmith, C. F.; Klippenstein, S. J.; Green, W. H.

    2011-01-01

    The kinetics of the allyl + HO{sub 2} bimolecular reaction, the thermal decomposition of C{sub 3}H{sub 5}OOH, and the unimolecular reactions of C{sub 3}H{sub 5}O are studied theoretically. High-level ab initio calculations of the C{sub 3}H{sub 5}OOH and C{sub 3}H{sub 5}O potential energy surfaces are coupled with RRKM master equation methods to compute the temperature- and pressure-dependence of the rate coefficients. Variable reaction coordinate transition state theory is used to characterize the barrierless transition states for the allyl + HO{sub 2} and C{sub 3}H{sub 5}O + OH reactions. The predicted rate coefficients for allyl + HO{sub 2} ? C{sub 3}H{sub 5}OOH ? products are in good agreement with experimental values. The calculations for allyl + HO{sub 2} ? C{sub 3}H{sub 6} + O{sub 2} underpredict the observed rate. The new rate coefficients suggest that the reaction of allyl + HO{sub 2} will promote chain-branching significantly more than previous models suggest.

  5. Shunting arc plasma source for pure carbon ion beam

    SciTech Connect (OSTI)

    Koguchi, H.; Sakakita, H.; Kiyama, S.; Shimada, T.; Sato, Y.; Hirano, Y.

    2012-02-15

    A plasma source is developed using a coaxial shunting arc plasma gun to extract a pure carbon ion beam. The pure carbon ion beam is a new type of deposition system for diamond and other carbon materials. Our plasma device generates pure carbon plasma from solid-state carbon material without using a hydrocarbon gas such as methane gas, and the plasma does not contain any hydrogen. The ion saturation current of the discharge measured by a double probe is about 0.2 mA/mm{sup 2} at the peak of the pulse.

  6. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J. (6204 Shadow Mountain Dr., Austin, TX 78731)

    1998-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  7. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J. (6204 Shadow Mountain Dr., Austin, TX 78731)

    1999-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  8. Carbon Nanotube Based Sensors

    SciTech Connect (OSTI)

    Jiang, Mian; Lin, Yuehe

    2006-11-01

    This review article provides a comprehensive review on sensors and biosensors based on functionalized carbon nanotubes.

  9. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, R.J.

    1998-02-10

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein. 17 figs.

  10. Carbon Monoxide Environmental Public

    E-Print Network [OSTI]

    The National Workgroup on Carbon Monoxide Surveillance Formed in April 2005 Membership: EPHT grantees Academic

  11. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Fulvio, Pasquale Fernando; Mayes, Richard T.; Wang, Xiqing; Sun, Xiao-Guang; Guo, Bingkun

    2014-09-09

    A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.

  12. 8. S. Perez, H. Schmiedel, and B. Schramm, "Second iteraction virial coefficients of the noble gas-hydrogen mixtures," Z. Phys. Chem., 123, No. I, 35-38 (1980).

    E-Print Network [OSTI]

    Riabov, Vladimir V.

    1980-01-01

    of volume and pressure effects of mixing in dense gas solutions. Helium-carbon dioxide system," Trudy Mosk. Kuznetsov, and V. F. Bondarenko, "Experimental investigation of the thermodynamic properties of binary gas properties of the components. The error in the coefficients can be as large as 10% for the systems studied

  13. Derived Types What Are Derived Types?

    E-Print Network [OSTI]

    Collett Jr., Jeffrey L.

    Derived Types #12;What Are Derived Types? As usual, a hybrid of two, unrelated concepts C++, Python orientation comes in #12;Simple Derived Types TYPE Wheel INTEGER :: spokes REAL :: diameter, width CHARACTER(LEN=15) :: material END TYPE Wheel That defines a derived type Wheel Using derived types needs a special

  14. Derived Types What Are Derived Types?

    E-Print Network [OSTI]

    Collett Jr., Jeffrey L.

    Derived Types #12;What Are Derived Types? As usual, a hybrid of two, unrelated concepts C object orientation comes in This course will only describe the former. #12;Simple Derived Types TYPE That defines a derived type Wheel Using derived types needs a special syntax TYPE(Wheel) :: w1 #12;More

  15. Type: Renewal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaicsStateof Energy TwoEvent at the Pu Facility,Type IV COPV1

  16. Trigonometric Pade approximants for functions with regularly decreasing Fourier coefficients

    SciTech Connect (OSTI)

    Labych, Yuliya A; Starovoitov, Alexander P [Gomel State University, Gomel (Belarus)

    2009-08-31

    Sufficient conditions describing the regular decrease of the coefficients of a Fourier series f(x)=a{sub 0}/2 + {sigma} a{sub n} cos kx are found which ensure that the trigonometric Pade approximants {pi}{sup t}{sub n,m}(x;f) converge to the function f in the uniform norm at a rate which coincides asymptotically with the highest possible one. The results obtained are applied to problems dealing with finding sharp constants for rational approximations. Bibliography: 31 titles.

  17. Towards flavour diffusion coefficient and electrical conductivity without ultraviolet contamination

    E-Print Network [OSTI]

    Y. Burnier; M. Laine

    2012-02-29

    By subtracting from a recent lattice measurement of the thermal vector-current correlator the known 5-loop vacuum contribution, we demonstrate that the remainder is small and shows no visible short-distance divergence. It can therefore in principle be subjected to model-independent analytic continuation. Testing a particular implementation, we obtain estimates for the flavour-diffusion coefficient (2 pi T D \\gsim 0.8) and electrical conductivity which are significantly smaller than previous results. Although systematic errors remain beyond control at present, some aspects of our approach could be of a wider applicability.

  18. Notes 14. Experimental identification of bearing force coefficients 

    E-Print Network [OSTI]

    San Andres, Luis

    2009-01-01

    . IDENTIFICATION OF BEARING FORCE COEFFICIENTS. ? Dr. Luis San Andr?s (2009) 13 Next, the Instrumental Variable Filter (IVF) method of Fritzen (1985), an extension of a least-squares estimation method, is used to simultaneously curve fit all four transfer... contains the stack of measured flexibility functions (at discrete frequencies ? k=1,2?,n ). Eq. (17) is an over determined set of equations, i.e. there are more equations than unknowns. Hence, its solution by least-squares aims to minimize the Euclidean...

  19. THE EFFECT OF UNCERTAINTY IN MODELING COEFFICIENTS USED TO PREDICT...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    likely to vary for systems in different climates, depending on the distribution of temperature and irradiance, as well as for different technology types. As previously reported,...

  20. Carbon fuel cells with carbon corrosion suppression

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA)

    2012-04-10

    An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

  1. Bond et al., 2012 26 March 2012 Bounding the role of black carbon in the climate system: A scientific assessment

    E-Print Network [OSTI]

    Zender, Charles

    system. Black carbon is a type of carbonaceous material with a unique combination of physical properties, following carbon dioxide. Sources that emit black carbon also emit other short- lived species that maypage 1 Bond et al., 2012 26 March 2012 Bounding the role of black carbon in the climate system

  2. Carbon Nanostructure-Based Sensors

    E-Print Network [OSTI]

    Sarkar, Tapan

    2012-01-01

    Control of Single-Walled Carbon Nanotube Functionalization.M. S. Characterizing carbon nanotube samples with resonancewith a Single-Walled Carbon Nanotube Capacitor. Science

  3. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile...

  4. Transport coefficients, membrane couplings and universality at extremality

    E-Print Network [OSTI]

    Miguel F. Paulos

    2009-11-20

    We present an efficient method for computing the zero frequency limit of transport coefficients in strongly coupled field theories described holographically by higher derivative gravity theories. Hydrodynamic parameters such as shear viscosity and conductivity can be obtained by computing residues of poles of the off-shell lagrangian density. We clarify in which sense these coefficients can be thought of as effective couplings at the horizon, and present analytic, Wald-like formulae for the shear viscosity and conductivity in a large class of general higher derivative lagrangians. We show how to apply our methods to systems at zero temperature but finite chemical potential. Our results imply that such theories satisfy $\\eta/s=1/4\\pi$ universally in the Einstein-Maxwell sector. Likewise, the zero frequency limit of the real part of the conductivity for such systems is shown to be universally zero, and we conjecture that higher derivative corrections in this sector do not modify this result to all orders in perturbation theory.

  5. Applications of the second virial coefficient: protein crystallization and solubility

    SciTech Connect (OSTI)

    Wilson, William W.; DeLucas, Lawrence J.

    2014-04-30

    This article highlights some of the ground-based studies emanating from NASA’s Microgravity Protein Crystal Growth (PCG) program, and includes a more detailed discussion of the history and the progress made in one of the NASA-funded PCG investigations involving the use of measured second virial coefficients (B values) as a diagnostic indicator of solution conditions conducive to protein crystallization. This article begins by highlighting some of the ground-based studies emanating from NASA’s Microgravity Protein Crystal Growth (PCG) program. This is followed by a more detailed discussion of the history of and the progress made in one of the NASA-funded PCG investigations involving the use of measured second virial coefficients (B values) as a diagnostic indicator of solution conditions conducive to protein crystallization. A second application of measured B values involves the determination of solution conditions that improve or maximize the solubility of aqueous and membrane proteins. These two important applications have led to several technological improvements that simplify the experimental expertise required, enable the measurement of membrane proteins and improve the diagnostic capability and measurement throughput.

  6. Angular Fock coefficients. Fixing the errors, and further development

    E-Print Network [OSTI]

    Evgeny Z. Liverts; Nir Barnea

    2015-05-10

    The angular coefficients $\\psi_{k,p}(\\alpha,\\theta)$ of the Fock expansion characterizing the S-state wave function of the two-electron atomic system, are calculated in hyperspherical angular coordinates $\\alpha$ and $\\theta$. To solve the problem the Fock recurrence relations separated into the independent individual equations associated with definite power $j$ of the nucleus charge $Z$, are applied. The "pure" $j$-components of the angular Fock coefficients, orthogonal to of the hyperspherical harmonics $Y_{kl}$, are found for even values of $k$. To this end, the specific coupling equation is proposed and applied. Effective techniques for solving the individual equations with simplest nonseparable and separable right-hand sides are proposed. Some mistakes/misprints made earlier in representations of $\\psi_{2,0}$, were noted and corrected. All $j$-components of $\\psi_{4,1}$ and the majority of components and subcomponents of $\\psi_{3,0}$ are calculated and presented for the first time. All calculations were carried out with the help of the Wolfram \\emph{Mathematica}.

  7. Angular Fock coefficients. Fixing the errors, and further development

    E-Print Network [OSTI]

    Liverts, Evgeny Z

    2015-01-01

    The angular coefficients $\\psi_{k,p}(\\alpha,\\theta)$ of the Fock expansion characterizing the S-state wave function of the two-electron atomic system, are calculated in hyperspherical angular coordinates $\\alpha$ and $\\theta$. To solve the problem the Fock recurrence relations separated into the independent individual equations associated with definite power $j$ of the nucleus charge $Z$, are applied. The "pure" $j$-components of the angular Fock coefficients, orthogonal to of the hyperspherical harmonics $Y_{kl}$, are found for even values of $k$. To this end, the specific coupling equation is proposed and applied. Effective techniques for solving the individual equations with simplest nonseparable and separable right-hand sides are proposed. Some mistakes/misprints made earlier in representations of $\\psi_{2,0}$, were noted and corrected. All $j$-components of $\\psi_{4,1}$ and the majority of components and subcomponents of $\\psi_{3,0}$ are calculated and presented for the first time. All calculations were ...

  8. Metallic carbon materials

    DOE Patents [OSTI]

    Cohen, Marvin Lou (Berkeley, CA); Crespi, Vincent Henry (Darien, IL); Louie, Steven Gwon Sheng (Berkeley, CA); Zettl, Alexander Karlwalter (Kensington, CA)

    1999-01-01

    Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

  9. Wear and friction behavior of metal impregnated microporous carbon composites

    SciTech Connect (OSTI)

    Goller, G.; Koty, D.P.; Tewari, S.N.; Singh, M.; Tekin, A.

    1996-11-01

    Metal-matrix composites have been prepared by pressure-infiltration casting of copper-base alloy melts into microporous carbon preforms. The carbon preforms contained varying proportions of amorphous carbon and graphite. Load dependence of the wear and friction behavior of the composite pins has been examined under ambient conditions against cast-iron plates, using a pin-on-plate reciprocating wear tester. The wear resistance of the composite is significantly improved, as compared with the base alloy. Contrary to the normally expected behavior, the addition of graphite to the amorphous carbon does not reduce the friction coefficient, especially at high loads. The wear and friction behavior of the composites is very sensitive to the size and distribution of the microstructural constituents.

  10. Activated carbon testing for the 200 area effluent treatment facility

    SciTech Connect (OSTI)

    Wagner, R.N.

    1997-01-17

    This report documents pilot and laboratory scale testing of activated carbon for use in the 200 Area Effluent Treatment Facility peroxide decomposer columns. Recommendations are made concerning column operating conditions and hardware design, the optimum type of carbon for use in the plant, and possible further studies.

  11. SHORT COMMUNICATION Oxidation processes on conducting carbon additives

    E-Print Network [OSTI]

    Cui, Yi

    window Á Solid electrolyte interphase 1 Introduction Lithium-ion batteries are now used in a wide range of a more stable solid electrolyte interphase (SEI) [13, 14], becomes a challenge. Although the typical different types of typical carbon additives for lithium-ion batteries and carbonates electrolyte above 5 V

  12. Measurements of Heat Transfer Coefficients to Cylinders in Shallow Bubble Columns

    E-Print Network [OSTI]

    Tow, Emily W.

    High heat transfer coefficients and large interfacial areas make bubble columns ideal for dehumidification. However, the effect of geometry on the heat transfer coefficients outside cooling coils in shallow bubble columns, ...

  13. Characterization of piezoelectric materials with large piezoelectric and electromechanical coupling coefficients

    E-Print Network [OSTI]

    Cao, Wenwu

    Characterization of piezoelectric materials with large piezoelectric and electromechanical coupling characterization because their extraordinarily large piezoelectric coefficients and electromechanical coupling piezoelectric and electromechanical coupling coefficients. Ó 2002 Published by Elsevier Science B.V. PACS: 77

  14. Earth’s carbon cycle: A mathematical perspective

    E-Print Network [OSTI]

    Rothman, Daniel H.

    The carbon cycle represents metabolism at a global scale. When viewed through a mathematical lens, observational data suggest that the cycle exhibits an underlying mathematical structure. This review focuses on two types ...

  15. Modeling Catalyzed Growth of Single-Walled Carbon Nanotubes 

    E-Print Network [OSTI]

    Beetge, Jenni Mignon

    2013-02-27

    of the nanotube. Using SIMCAT, a reactive force field code, simulations are run for pure Ni nanoparticles with two types of carbon containing C2 precursor gas, each having five different support interaction energies, for three nanoparticle sizes. The same...

  16. Carbon nanotube nanoelectrode arrays

    DOE Patents [OSTI]

    Ren, Zhifeng (Newton, MA); Lin, Yuehe (Richland, WA); Yantasee, Wassana (Richland, WA); Liu, Guodong (Fargo, ND); Lu, Fang (Burlingame, CA); Tu, Yi (Camarillo, CA)

    2008-11-18

    The present invention relates to microelectode arrays (MEAs), and more particularly to carbon nanotube nanoelectrode arrays (CNT-NEAs) for chemical and biological sensing, and methods of use. A nanoelectrode array includes a carbon nanotube material comprising an array of substantially linear carbon nanotubes each having a proximal end and a distal end, the proximal end of the carbon nanotubes are attached to a catalyst substrate material so as to form the array with a pre-determined site density, wherein the carbon nanotubes are aligned with respect to one another within the array; an electrically insulating layer on the surface of the carbon nanotube material, whereby the distal end of the carbon nanotubes extend beyond the electrically insulating layer; a second adhesive electrically insulating layer on the surface of the electrically insulating layer, whereby the distal end of the carbon nanotubes extend beyond the second adhesive electrically insulating layer; and a metal wire attached to the catalyst substrate material.

  17. ESM 271 Carbon Footprints and Carbon Accounting Instructor: Sangwon Suh

    E-Print Network [OSTI]

    California at Santa Barbara, University of

    1 ESM 271 Carbon Footprints and Carbon Accounting Instructor: Sangwon Suh Bren hall 3422, suh Week 1: Introduction to carbon footprint and carbon account - Background: carbon awareness, major out a report or a web site about carbon footprint results of a product or of a company. Write a two

  18. Carbonation of Rock Minerals by Supercritical Carbon Dioxide at 250 degrees C.

    SciTech Connect (OSTI)

    Sugama, T.; Ecker, L.; Butcher, T.

    2010-06-01

    Wet powder-samples of five rock minerals, granite, albite, hornblende, diorite, and biotite mica, were exposed in supercritical carbon dioxide (scCO2) for 3 days at 250 C under 17.23 MPa pressure, and then the susceptibility of the various crystalline phases present in these mineral structures to reactions with hot scCO2 was investigated by XRD and FT-IR. The anorthite present in diorite was identified as the most vulnerable phase to carbonation. In contrast, biotite displayed a great resistance, although its phase was transformed hydrothermally to sanidine and quartz. Granite comprised of two phases, anorthoclase-type albite and quartz. The carbonation of former phase led to the formation of amorphous sodium and potassium carbonates coexisting with the clay-like by-products of the carbonation reaction. The reactivity of quartz to scCO2 was minimal, if any. Among these rock minerals, only hornblende formed crystalline carbonation products, such as calcite and magnesite after exposure, reflecting the likelihood of an increase in its volume. Based upon the feldspar ternary diagram, the carbonation rate of various different minerals in the plagioclase feldspar family depended primarily on the amount of anorthite. On the other hand, alkali feldspar minerals involving anorthoclase-type albite and sanidine had a lower reactivity with scCO2, compared with that of plagioclase feldspar minerals.

  19. Big Sky Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    (Acknowledgment to the Big Sky Carbon Sequestration Partnership (BSCSP); see home page at http://www.bigskyco2.org/)

  20. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F. (Los Angeles, CA); Vajo, John J. (West Hills, CA); Cumberland, Robert W. (Malibu, CA); Liu, Ping (Irvine, CA); Salguero, Tina T. (Encino, CA)

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  1. Fourth virial coefficients of asymmetric nonadditive hard-disc mixtures

    E-Print Network [OSTI]

    Franz Saija; Andrés Santos; Santos B. Yuste; Mariano López de Haro

    2012-05-16

    The fourth virial coefficient of asymmetric nonadditive binary mixtures of hard disks is computed with a standard Monte Carlo method. Wide ranges of size ratio ($0.05\\leq q\\leq 0.95$) and nonadditivity ($-0.5\\leq \\Delta\\leq 0.5$) are covered. A comparison is made between the numerical results and those that follow from some theoretical developments. The possible use of these data in the derivation of new equations of state for these mixtures is illustrated by considering a rescaled virial expansion truncated to fourth order. The numerical results obtained using this equation of state are compared with Monte Carlo simulation data in the case of a size ratio $q=0.7$ and two nonadditivities $\\Delta=\\pm 0.2$.

  2. FOURIER COEFFICIENTS OF MODULAR FORMS ON G2 WEE TECK GAN, BENEDICT GROSS AND GORDAN SAVIN

    E-Print Network [OSTI]

    Gan, Wee Teck

    FOURIER COEFFICIENTS OF MODULAR FORMS ON G2 WEE TECK GAN, BENEDICT GROSS AND GORDAN SAVIN Abstract. We develop a theory of Fourier coefficients for modular forms on the split ex- ceptional group G2 on the group SL2(Z) is the wealth of information carried by the Fourier coefficients an(f), for n 0

  3. Functional Coefficient Regression Models for Non-linear Time Series: A Polynomial

    E-Print Network [OSTI]

    Shen, Haipeng

    Functional Coefficient Regression Models for Non-linear Time Series: A Polynomial Spline Approach of functional coefficient regression models for non-linear time series. Consistency and rate of convergence to estimate the coefficient functions. Cai et al. (2000) and Chen & Liu (2001) used the local linear method

  4. On some binomial coefficients related to the evaluation of tan(nx)

    E-Print Network [OSTI]

    Ma, Shi-Mei

    2012-01-01

    The purpose of this paper is to study some binomial coefficients which are related to the evaluation of tan(nx). We mainly present a connection between these binomial coefficients and the coefficients of a family of derivative polynomials for tangent and secant.

  5. A method to estimate the Leslie coefficients of liquid crystals based on MBBA data

    E-Print Network [OSTI]

    Wu, Shin-Tson

    A method to estimate the Leslie coefficients of liquid crystals based on MBBA data HAIYING WANG ) A new effective approach for estimating the Leslie coefficients of liquid crystals based on MBBA data of the Leslie coefficients based on the MBBA data. We used the published temperature-dependent MBBA data to fit

  6. CORRELATING EVAPORATION HEAT TRANSFER COEFFICIENT OF REFRIGERANT R-134a IN A PLATE HEAT EXCHANGER

    E-Print Network [OSTI]

    Kandlikar, Satish

    1 CORRELATING EVAPORATION HEAT TRANSFER COEFFICIENT OF REFRIGERANT R-134a IN A PLATE HEAT EXCHANGER for evaporation heat transfer coefficient of refrigerant R-134a flowing in a plate heat exchanger. Correlation schemes proposed by Yan and Lin (1999b) for modeling the heat transfer coefficient in both a single- phase

  7. Spin-dependent thermoelectric transport coefficients in near perfect quantum wires A. Ramsak,1,2

    E-Print Network [OSTI]

    Ramsak, Anton

    Spin-dependent thermoelectric transport coefficients in near perfect quantum wires T. Rejec,1 A 2002 Thermoelectric transport coefficients are determined for semiconductor quantum wires with weak in thermoelectric coefficients are also found in standard strongly correlated systems: the Anderson model,6

  8. Carbon Footprint Towson University

    E-Print Network [OSTI]

    Fath, Brian D.

    Carbon Footprint Towson University GHG Inventory for Educational Institutes Getting Starting.TM The Carbon Footprint 8 The Constellation Experience A Broad Inventory 1. Scope I-Direct Emissions works.TM The Carbon Footprint 10 The Constellation Experience A Broad Inventory 3. Scope III

  9. Intro to Carbon Sequestration

    ScienceCinema (OSTI)

    None

    2010-01-08

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  10. Intro to Carbon Sequestration

    SciTech Connect (OSTI)

    2008-03-06

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  11. STUDY TYPES What is a "Study Type"?

    E-Print Network [OSTI]

    Dorf, Martin E.

    #12;STUDY TYPES What is a "Study Type"? A Study Type is a defined business process. Study Types work together to streamline workflow, track data & keep users informed. There are 2 Study Types in eCOMS: COMS and IACUC. The COMS Study: The COMS Study is an online form that a Principal Investigator fills

  12. Predicting Local Transport Coefficients at Solid-Gas Interfaces | Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen Generation | Center forPostcombustion Carbon Dioxide

  13. Carbon offsets as a cost containment instrument : a case study of reducing emissions from deforestation and forest degradation

    E-Print Network [OSTI]

    Kim, Jieun, S.M. Massachusetts Institute of Technology

    2010-01-01

    Carbon offset is one type of flexibility mechanism in greenhouse gas emission trading schemes that helps nations meet their emission commitments at lower costs. Carbon offsets take advantage of lower abatement cost ...

  14. Supporting information for Vertically Grown Multi-walled Carbon Nanotube Anode

    E-Print Network [OSTI]

    1 Supporting information for Vertically Grown Multi-walled Carbon Nanotube Anode and Nickel-type highly doped silicon wafer. First, we formed a nickel silicide contact path as a low resistance contact comparing carbon nanotube anode and carbon cloth anode Figure S3. Polarization plot comparing MWCNT

  15. Development of a SCALE Tool for Continuous-Energy Eigenvalue Sensitivity Coefficient Calculations

    SciTech Connect (OSTI)

    Perfetti, Christopher M [ORNL] [ORNL; Rearden, Bradley T [ORNL] [ORNL

    2013-01-01

    Two methods for calculating eigenvalue sensitivity coefficients in continuous-energy Monte Carlo applications were implemented in the KENO code within the SCALE code package. The methods were used to calculate sensitivity coefficients for several criticality safety problems and produced sensitivity coefficients that agreed well with both reference sensitivities and multigroup TSUNAMI-3D sensitivity coefficients. The newly developed CLUTCH method was observed to produce sensitivity coefficients with high figures of merit and low memory requirements, and both continuous-energy sensitivity methods met or exceeded the accuracy of the multigroup TSUNAMI-3D calculations.

  16. Continuous-energy eigenvalue sensitivity coefficient calculations in TSUNAMI-3D

    SciTech Connect (OSTI)

    Perfetti, C. M.; Rearden, B. T. [Oak Ridge National Laboratory, Reactor and Nuclear Systems Division, P.O. Box 2008, Oak Ridge, TN 37831-6170 (United States)

    2013-07-01

    Two methods for calculating eigenvalue sensitivity coefficients in continuous-energy Monte Carlo applications were implemented in the KENO code within the SCALE code package. The methods were used to calculate sensitivity coefficients for several test problems and produced sensitivity coefficients that agreed well with both reference sensitivities and multigroup TSUNAMI-3D sensitivity coefficients. The newly developed CLUTCH method was observed to produce sensitivity coefficients with high figures of merit and a low memory footprint, and both continuous-energy sensitivity methods met or exceeded the accuracy of the multigroup TSUNAMI-3D calculations. (authors)

  17. A sequential method of detecting abrupt changes in the correlation coefficient and its application to Bering Sea climate

    E-Print Network [OSTI]

    Rodionov, Sergei

    2015-01-01

    A new method of regime shift detection in the correlation coefficient is proposed. The method is designed to find multiple change-points with unknown locations in time series. It signals a possible regime shift in real time and allows for its monitoring. The method is tested on randomly generated time series with predefined change-points. It is applied to examine structural changes in the Bering Sea climate. A major shift is found in 1967, which coincides with a transition from a zonal type of atmospheric circulation to a meridional one. The most recent shift has occurred in 2004, but it still needs to be monitored.

  18. Ion source sample preparation techniques for carbon-14 AMS measurements

    SciTech Connect (OSTI)

    Balsley, D.R.; Farwell, G.W.; Grootes, P.M.; Schmidt, F.H.

    1987-01-01

    Methods for preparing solid graphite, and other types of carbon samples possessing good geometrical characteristics and producing large beams are described. Amorphous carbon, or graphite powder, is encapsulated in tantalum, compressed to approx.14 kilobars, and heated in vacuum to approx.2500/sup 0/C. The end of the capsule is cut off, exposing a smooth and hard graphite surface which provides excellent emittance in a reflection-type sputter source. The powder is prepared from CO/sub 2/ by the hydrogen-iron powder catalyzation method. Silver-carbon mixtures with good geometrical properties can also be prepared with our press. 6 refs., 4 figs.

  19. The theoretical ultimate magnetoelectric coefficients of magnetoelectric composites by optimization design

    SciTech Connect (OSTI)

    Wang, H.-L.; Liu, B., E-mail: liubin@tsinghua.edu.cn [AML, CNMM, Department of Engineering Mechanics, Tsinghua University, Beijing 100084 (China)

    2014-03-21

    This paper investigates what is the largest magnetoelectric (ME) coefficient of ME composites, and how to realize it. From the standpoint of energy conservation, a theoretical analysis is carried out on an imaginary lever structure consisting of a magnetostrictive phase, a piezoelectric phase, and a rigid lever. This structure is a generalization of various composite layouts for optimization on ME effect. The predicted theoretical ultimate ME coefficient plays a similar role as the efficiency of ideal heat engine in thermodynamics, and is used to evaluate the existing typical ME layouts, such as the parallel sandwiched layout and the serial layout. These two typical layouts exhibit ME coefficient much lower than the theoretical largest values, because in the general analysis the stress amplification ratio and the volume ratio can be optimized independently and freely, but in typical layouts they are dependent or fixed. To overcome this shortcoming and achieve the theoretical largest ME coefficient, a new design is presented. In addition, it is found that the most commonly used electric field ME coefficient can be designed to be infinitely large. We doubt the validity of this coefficient as a reasonable ME effect index and consider three more ME coefficients, namely the electric charge ME coefficient, the voltage ME coefficient, and the static electric energy ME coefficient. We note that the theoretical ultimate value of the static electric energy ME coefficient is finite and might be a more proper measure of ME effect.

  20. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Philip L. Biedler; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-06-23

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. There are a number of parameters which are important for the production of acceptable cokes, including purity, structure, density, electrical resistivity, thermal conductivity etc. From the standpoint of a manufacturer of graphite electrodes such as GrafTech, one of the most important parameters is coefficient of thermal expansion (CTE). Because GrafTech material is usually fully graphitized (i.e., heat treated at 3100 C), very high purity is automatically achieved. The degree of graphitization controls properties such as CTE, electrical resistivity, thermal conductivity, and density. Thus it is usually possible to correlate these properties using a single parameter. CTE has proven to be a useful index for the quality of coke. Pure graphite actually has a slightly negative coefficient of thermal expansion, whereas more disordered carbon has a positive coefficient.

  1. Carbon dioxide sensor

    DOE Patents [OSTI]

    Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

    2011-11-15

    The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

  2. Organic carbon burial forcing of the carbon cycle from

    E-Print Network [OSTI]

    Derry, Louis A.

    Organic carbon burial forcing of the carbon cycle from Himalayan erosion Christian France . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Weathering and erosion can affect the long-term ocean­atmo- sphere budget of carbon dioxide both through of Neogene Himalayan erosion on the carbon cycle is an increase in the amount of organic carbon

  3. CARBON EMISSIONS AND CARBON FIXING FROM AN ECONOMIC PERSPECTIVE

    E-Print Network [OSTI]

    Bateman, Ian J.

    constraint to these relationships, with the carbon dioxide emissions from fossil fuel consumption pressingCARBON EMISSIONS AND CARBON FIXING FROM AN ECONOMIC PERSPECTIVE by Dennis Anderson CSERGE GEC Working Paper 92-28 #12;CARBON EMISSIONS AND CARBON FIXING FROM AN ECONOMIC PERSPECTIVE by Dennis Anderson

  4. Carbon Code Requirements for voluntary carbon sequestration projects

    E-Print Network [OSTI]

    and individuals wishing to reduce their carbon footprint while also delivering a range of other environmentalWoodland Carbon Code Requirements for voluntary carbon sequestration projects ® Version 1.2 July of group schemes 8 2.6 Monitoring 9 2.7 Carbon statements and reporting 9 2.8 Woodland Carbon Code

  5. Carbon RRLs Carbon RRLs towards Ultra-compact HII Regions

    E-Print Network [OSTI]

    Balser, Dana S.

    Carbon RRLs Carbon RRLs towards Ultra-compact HII Regions Dana S. Balser D. Anish Roshi (Raman (Agnes Scott College) #12;Carbon RRLs Carbon Radio Recombination Lines (RRLs) NGC 2024 (Orion B) IC 1795 (W3) Palmer et al. (1967) #12;Carbon RRLs Photodissociation Regions (PDRs) Hollenbach & Tielens (1997

  6. Carbon Sequestration via Mineral Carbonation: Overview and Assessment

    E-Print Network [OSTI]

    1 Carbon Sequestration via Mineral Carbonation: Overview and Assessment 14 March 2002 Howard Herzog overview and assessment of carbon sequestration by mineral carbonation (referred to as "mineral sequestration R&D. The first is that carbonates have a lower energy state than CO2. Therefore, at least

  7. Project Profile: Carbon Dioxide Shuttling Thermochemical Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Profile: Carbon Dioxide Shuttling Thermochemical Storage Using Strontium Carbonate Project Profile: Carbon Dioxide Shuttling Thermochemical Storage Using Strontium...

  8. Determination of oil/water and octanol/water distribution coefficients from aqueous solutions from four fossil fuels. [MS thesis; in oil-water and octanol-water

    SciTech Connect (OSTI)

    Thomas, B.L.

    1984-07-01

    Liquid fossil fuels, both petroleum and synthetically derived oils, are exceedingly complex mixtures of thousands of components. The effect of many of these energy-related components on the environment is largely unknown. Octanol/water distribution coefficients relate both to toxicity and to the bioaccumulation potential of chemical components. Use of these partition data in conjunction with component concentrations in the oils in environmental models provides important information on the fate of fossil fuel components when released to the environment. Octanol/water distribution data are not available for many energy-related organic compounds, and those data that are available have been determined for individual components in simple, one-component octanol/water equilibrium mixtures. In this study, methods for determining many octanol/water distribution coefficients from aqueous extracts of oil products were developed. Sample aqueous mixtures were made by equilibrating liquid fossil fuels with distilled water. This approach has the advantage of detecting interactions between components of interest and other sample components. Compound types studied included phenols, nitrogen bases, hydrocarbons, sulfur heterocyclic compounds, and carboxylic acids. Octanol/water distribution coefficients that were determined in this study ranged from 9.12 for aniline to 67,600 for 1,2-dimethylnaphthalene. Within a compound type, distribution coefficients increased logarithmically with increasing alkyl substitution and molecular weight. Additionally, oil/water distribution data were determined for oil components. These data are useful in predicting maximum environmental concentrations in water columns. 96 references, 26 figures, and 40 tables.

  9. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Wang, Xiqing (Oak Ridge, TN)

    2012-02-14

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  10. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Wang, Xiqing

    2013-08-20

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  11. Assignment Types UTS LIBRARY

    E-Print Network [OSTI]

    University of Technology, Sydney

    Assignment Types UTS LIBRARY February 2013 Academic Writing Guide Part 2 ­ Assignment Types: This section outlines the basic types of written assignments, providing structural elements and examples. #12;2 II. Assignment Types 1. Essay Writing

  12. A universal model for nanoporous carbon supercapacitors

    SciTech Connect (OSTI)

    Huang, Jingsong; Sumpter, Bobby G; Meunier, Vincent

    2009-01-01

    Supercapacitors based on nanoporous carbon materials, commonly called electric double-layer capacitors (EDLCs), are emerging as a novel type of energy-storage device with the potential to substitute batteries in applications that require high power densities. Nanoporous carbon supercapacitors are generally viewed as a parallel-plate capacitor since supercapacitors store energy by charge separation in an electric double layer formed at the electrode/electrolyte interface. The EDLC model has been used to characterize the energy storage of supercapacitors for decades. We comment in this chapter on the shortcomings of the EDLC model when applied to nanoporous carbon supercapacitors. In response to the latest experimental breakthrough in nanoporous carbon supercapacitors, we have proposed a heuristic model that takes pore curvature into account as a replacement for the EDLC model. When the pore size is in the mesopore regime (2 50 nm), electrolyte counterions enter mesoporous carbons and approach the pore wall to form an electric double-cylinder capacitor (EDCC); in the micropore regime (< 2 nm), solvated/desolvated counterions line up along the pore axis to form an electric wire-in-cylinder capacitor (EWCC). In the macropore regime (> 50 nm), where pores are large enough so that pore curvature is no longer significant, the EDCC model can be reduced to the EDLC model. With the backing of experimental data and quantum density functional theory calculations, we have shown that the EDCC/EWCC model is universal for carbon supercapacitors with diverse carbon materials and electrolytes. The strengths and limitations of this new model are discussed. The new model allows the supercapacitor properties to be correlated with pore size, specific surface area, Debye length, electrolyte concentration, dielectric constant, and solute ion size, and may lend support to the systematic optimization of the properties of carbon supercapacitors through experiments.

  13. Black Carbon Concentrations and Diesel Vehicle Emission Factors Derived from Coefficient of Haze Measurements in California: 1967-2003

    E-Print Network [OSTI]

    Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.

    2008-01-01

    Inventory for Heavy-Duty Diesel Truck Emissions. J. Air &T. A. Cackette (2001), Diesel engines: Environmental impact2003), http://www.arb.ca.gov/diesel/diesel.htm BAAQMD, Bay

  14. Black Carbon Concentrations and Diesel Vehicle Emission Factors Derived from Coefficient of Haze Measurements in California: 1967-2003

    E-Print Network [OSTI]

    Kirchstetter, Thomas W.

    2008-01-01

    85 , 241-248. Harley, RA; Marr, LC; Lehner, JK; Giddings,Environ. , 40 , 4137-4149. Marr, LC; Black, DR; Harley,only 10% less on Sundays [Marr et al. , 2002]. Therefore, we

  15. Black Carbon Concentrations and Diesel Vehicle Emission Factors Derived from Coefficient of Haze Measurements in California: 1967-2003

    E-Print Network [OSTI]

    Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.

    2008-01-01

    85, 241-248. Harley, RA; Marr, LC; Lehner, JK; Giddings,Environ. , 40, 4137-4149. Marr, LC; Black, DR; Harley, RA. (only 10% less on Sundays [Marr et al. , 2002]. Therefore, we

  16. Black Carbon Concentrations and Diesel Vehicle Emission Factors Derived from Coefficient of Haze Measurements in California: 1967-2003

    E-Print Network [OSTI]

    Kirchstetter, Thomas W.

    2008-01-01

    Changes in motor vehicle emissions on diurnal to decadalof a revised motor vehicle emission inventory. J. Geophys.and trends in motor vehicle emissions to monthly urban

  17. Activated Carbon Injection

    ScienceCinema (OSTI)

    None

    2014-07-22

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  18. Activated Carbon Injection

    SciTech Connect (OSTI)

    2014-07-16

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  19. Carbon allocation among tree organs: A review of basic processes and representation

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    allocation coefficients; (ii) models based on growth rules, including functional balance or "goal allocation is a key component in function- al-structural tree models (FSTMs). In the short term, parReview Carbon allocation among tree organs: A review of basic processes and representation

  20. Magnetic properties and transmission electron microscopy studies of Ni nanoparticles encapsulated in carbon nanocages and carbon nanotubes

    SciTech Connect (OSTI)

    He Chunnian; Zhao Naiqin Shi Chunsheng; Li Jiajun; Li Haipeng

    2008-08-04

    Three types of carbon nanomaterials, including bamboo-shaped carbon nanotubes with Ni encapsulated and hollow and Ni catalytic particles filled carbon nanocages, have been prepared by methane catalytic decomposition at a relatively low temperature. Transmission electron microscopy observations showed that fascinating fullerene-like Ni-C (graphitic) core-shell nanostructures predominated. Detailed examination of high-resolution transmission electron microscopy showed that the walls of bamboo-shaped carbon nanotubes with quasi-cone catalytic particles encapsulated consisted of oblique graphene planes with respect to the tube axis. The Ni particles encapsulated in the carbon nanocages were larger than that encapsulated in carbon nanotubes, but the diameters of the cores of hollow carbon nanocages were less than that of Ni particles encapsulated in carbon nanotubes, suggesting that the sizes of catalyst particles played an important role during carbon nanomaterial growth. The magnetic properties of the carbon nanomaterials were measured, which showed relatively large coercive force (H{sub c} = 138.4 O{sub e}) and good ferromagnetism (M{sub r}/M{sub s} = 0.325)

  1. Electronic properties of linear carbon chains: Resolving the controversy

    SciTech Connect (OSTI)

    Al-Backri, Amaal [Physics Department, Lancaster University, LA1 4YB Lancaster (United Kingdom) [Physics Department, Lancaster University, LA1 4YB Lancaster (United Kingdom); College of Science, Baghdad University, Al-Jaderyia Campus, Baghdad (Iraq); Zólyomi, Viktor; Lambert, Colin J. [Physics Department, Lancaster University, LA1 4YB Lancaster (United Kingdom)] [Physics Department, Lancaster University, LA1 4YB Lancaster (United Kingdom)

    2014-03-14

    Literature values for the energy gap of long one-dimensional carbon chains vary from as little as 0.2 eV to more than 4 eV. To resolve this discrepancy, we use the GW many-body approach to calculate the band gap E{sub g} of an infinite carbon chain. We also compute the energy dependence of the attenuation coefficient ? governing the decay with chain length of the electrical conductance of long chains and compare this with recent experimental measurements of the single-molecule conductance of end-capped carbon chains. For long chains, we find E{sub g} = 2.16 eV and an upper bound for ? of 0.21 Å{sup ?1}.

  2. Black carbon refractive index and morphology: a Laboratory study

    E-Print Network [OSTI]

    Oxford, University of

    cake 2.6 Heavy fuel oil 1.5 Figure 2: Global sources by fuel types [7]. A wide range of fuel types radiative properties derived from Mie theory and therefore limited to the assumption of spherical aerosol microphysical aerosol models, such as UKCA. This study derives the refractive indices black carbon (BC) aerosol

  3. Thermal expansion of multiwall carbon nanotube reinforced nanocrystalline silver matrix composite

    SciTech Connect (OSTI)

    Sharma, Manjula Sharma, Vimal; Pal, Hemant

    2014-04-24

    Multiwall carbon nanotube reinforced silver matrix composite was fabricated by novel molecular level mixing method, which involves nucleation of Ag ions inside carbon nanotube dispersion at the molecular level. As a result the carbon nanotubes get embedded within the powder rather than on the surfaces. Micro structural characterization by X- ray diffraction and scanning electron microscopy reveals that the nanotubes are homogeneously dispersed and anchored within the matrix. The thermal expansion of the composite with the multiwall nanotube content (0, 1.5 vol%) were investigated and it is found that coefficient of thermal expansion decreases with the addition of multiwall nanotube content and reduce to about 63% to that of pure Ag.

  4. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01

    Y. Li, M. Daskin. 2009. Carbon Footprint and the ManagementJ. van Houtum. 2011. E?ect of carbon emission regulations onStreamlined Enterprise Carbon Footprinting. Environmental

  5. Transport coefficients of D1-D5-P system and the membrane paradigm

    E-Print Network [OSTI]

    Yuya Sasai

    2012-01-12

    I discuss a correspondence between string theory and the black hole membrane paradigm in the context of the D1-D5-P system. By using the Kubo formula, I calculate transport coefficients of the effective string model induced by two kinds of minimal scalars. Then, I show that these transport coefficients exactly agree with the corresponding membrane transport coefficients of a five-dimensional near-extremal black hole with three charges.

  6. Development of Continuous-Energy Eigenvalue Sensitivity Coefficient Calculation Methods in the Shift Monte Carlo Code

    SciTech Connect (OSTI)

    Perfetti, Christopher M [ORNL] [ORNL; Martin, William R [University of Michigan] [University of Michigan; Rearden, Bradley T [ORNL] [ORNL; Williams, Mark L [ORNL] [ORNL

    2012-01-01

    Three methods for calculating continuous-energy eigenvalue sensitivity coefficients were developed and implemented into the SHIFT Monte Carlo code within the Scale code package. The methods were used for several simple test problems and were evaluated in terms of speed, accuracy, efficiency, and memory requirements. A promising new method for calculating eigenvalue sensitivity coefficients, known as the CLUTCH method, was developed and produced accurate sensitivity coefficients with figures of merit that were several orders of magnitude larger than those from existing methods.

  7. On an improvement of the Hardy-Hilbert type inequality

    E-Print Network [OSTI]

    Guang-Sheng Chen

    2011-05-15

    In this paper, by estimating the weight coefficient effectively, we establish an improvement of a Hardy-Hilbert type inequality proved by B.C. Yang, our main tool is Euler-Maclaurin expansion for the zeta function. As applications, some particular results are considered

  8. Materials with a desired refraction coefficient can be made by embedding small particles

    E-Print Network [OSTI]

    A. G. Ramm

    2007-06-15

    A method is proposed to create materials with a desired refraction coefficient, possibly negative one. The method consists of embedding into a given material small particles. Given $n_0(x)$, the refraction coefficient of the original material in a bounded domain $D \\subset \\R^3$, and a desired refraction coefficient $n(x)$, one calculates the number $N(x)$ of small particles, to be embedded in $D$ around a point $x \\in D$ per unit volume of $D$, in order that the resulting new material has refraction coefficient $n(x)$.

  9. Constraints on the second order transport coefficients of an uncharged fluid

    E-Print Network [OSTI]

    Sayantani Bhattacharyya

    2012-06-29

    In this note we have tried to determine how the existence of a local entropy current with non-negative divergence constrains the second order transport coefficients of an uncharged fluid, following the procedure described in \\cite{Romatschke:2009kr}. Just on symmetry ground the stress tensor of an uncharged fluid can have 15 transport coefficients at second order in derivative expansion. The condition of entropy-increase gives five relations among these 15 coefficients. So finally the relativistic stress tensor of an uncharged fluid can have 10 independent transport coefficients at second order.

  10. THERMODYNAMICS OF ELECTROLYTES. X. ENTHALPY AND THE EFFECT OF TEMPERATURE ON THE ACTIVITY COEFFICIENTS.

    E-Print Network [OSTI]

    Silvester, Leonard F.

    2011-01-01

    09 THERMODYNAMICS OFELECI'ROLYTES. X'rights. r'-" e. ct THERMODYNAMICS OF ELECTROLYTES. X.Coefficient, Electrolyte, Thermodynamics v ~p , I J ! l

  11. Basis and implications of the CAP88 age-specific dose coefficients

    SciTech Connect (OSTI)

    Leggett, Richard Wayne [ORNL; Scofield, Patricia A [ORNL; Eckerman, Keith F [ORNL

    2013-01-01

    Recent versions of CAP88 incorporate age-specific dose coefficients based on biokinetic and dosimetric models applied in Federal Guidance Report 13, Cancer Risk Coefficients for Environmental Exposure to Radionuclides (EPA 1999). With a few exceptions the models are those recommended in a series of reports by the International Commission on Radiological Protection (ICRP) on estimation of doses to the public from environmental radionuclides. This paper describes the basis for the ICRP s age-specific biokinetic and dosimetric models and examines differences with age in the derived dose coefficients and in estimates of dose per unit exposure based on those coefficients.

  12. A Typed Operational Semantics for Type Theory 

    E-Print Network [OSTI]

    Goguen, Healfdene

    Untyped reduction provides a natural operational semantics for type theory. Normalization results say that such a semantics is sound. However, this reduction does not take type information into account and gives no information ...

  13. Carbon Park Environmental Impact Assessment

    E-Print Network [OSTI]

    of offsetting the University's carbon footprint, promoting biodiversity and establishing easily maintained Carbon Park Environmental Impact Assessment A B.E.S.T. Project By, Adam Bond 2011 #12; Bishop's University Carbon Park

  14. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon First Proof of Ferromagnetic Carbon Print Wednesday, 25 July 2007 00:00 Although it has long been suspected that carbon belongs on the short list of...

  15. Carbon Dioxide & Global Warming

    E-Print Network [OSTI]

    Miami, University of

    Carbon Dioxide & Global Warming University of MiaMi rosenstiel sChool of Marine anD atMospheriC s , organic carbon, and other chemicals that contribute to global warming in a variety of studies. DownCienCe 4600 rickenbacker Causeway Miami, florida 33149 http://www.rsmas.miami.edu the Chemistry of Global

  16. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, Stephen E. (Pinole, CA); Moses, William W. (Berkeley, CA)

    1991-01-01

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses.

  17. Fly ash carbon passivation

    DOE Patents [OSTI]

    La Count, Robert B; Baltrus, John P; Kern, Douglas G

    2013-05-14

    A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

  18. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-10-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. During the third quarter, planning efforts are underway for the next Partnership meeting which will showcase the architecture of the GIS framework and initial results for sources and sinks, discuss the methods and analysis underway for assessing geological and terrestrial sequestration potentials. The meeting will conclude with an ASME workshop. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies. Two key deliverables were completed in the second quarter--a literature review/database to assess the soil carbon on rangelands, and the draft protocols, contracting options for soil carbon trading. The protocols developed for soil carbon trading are unique and provide a key component of the mechanisms that might be used to efficiently sequester GHG and reduce CO{sub 2} concentrations. While no key deliverables were due during the third quarter, progress on other deliverables is noted in the PowerPoint presentations and in this report. A series of meetings held during the second and third quarters have laid the foundations for assessing the issues surrounding carbon sequestration in this region, the need for a holistic approach to meeting energy demands and economic development potential, and the implementation of government programs or a market-based setting for soil C credits. These meetings provide a connection to stakeholders in the region and a basis on which to draw for the DOE PEIS hearings. In the fourth quarter, three deliverables have been completed, some in draft form to be revised and updated to include Wyoming. This is due primarily to some delays in funding to LANL and INEEL and the approval of a supplemental proposal to include Wyoming in much of the GIS data sets, analysis, and related materials. The de

  19. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-06-30

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. During the third quarter, planning efforts are underway for the next Partnership meeting which will showcase the architecture of the GIS framework and initial results for sources and sinks, discuss the methods and analysis underway for assessing geological and terrestrial sequestration potentials. The meeting will conclude with an ASME workshop (see attached agenda). The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies. Two key deliverables were completed in the second quarter--a literature review/database to assess the soil carbon on rangelands, and the draft protocols, contracting options for soil carbon trading. The protocols developed for soil carbon trading are unique and provide a key component of the mechanisms that might be used to efficiently sequester GHG and reduce CO2 concentrations. While no key deliverables were due during the third quarter, progress on other deliverables is noted in the PowerPoint presentations and in this report. A series of meetings held during the second and third quarters have laid the foundations for assessing the issues surrounding carbon sequestration in this region, the need for a holistic approach to meeting energy demands and economic development potential, and the implementation of government programs or a market-based setting for soil C credits. These meetings provide a connection to stakeholders in the region and a basis on which to draw for the DOE PEIS hearings. A third Partnership meeting has been planned for August 04 in Idaho Falls; a preliminary agenda is attached.

  20. Big Sky Carbon Sequestration Partnership

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2005-11-01

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I fall into four areas: evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; development of GIS-based reporting framework that links with national networks; designing an integrated suite of monitoring, measuring, and verification technologies and assessment frameworks; and initiating a comprehensive education and outreach program. The groundwork is in place to provide an assessment of storage capabilities for CO2 utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research agenda in Carbon Sequestration. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other DOE regional partnerships. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound MMV is critical for public acceptance of these technologies. Deliverables for the 7th Quarter reporting period include (1) for the geological efforts: Reports on Technology Needs and Action Plan on the Evaluation of Geological Sinks and Pilot Project Deployment (Deliverables 2 and 3), and Report on the Feasibility of Mineralization Trapping in the Snake River Plain Basin (Deliverable 14); (2) for the terrestrial efforts: Report on the Evaluation of Terrestrial Sinks and a Report of the Best Production Practices for Soil C Sequestration (Deliverables 8 and 15). In addition, the 7th Quarter activities for the Partnership included further development of the proposed activities for the deployment and demonstration phase of the carbon sequestration pilots including geological and terrestrial pilots, expansion of the Partnership to encompass regions and institutions that are complimentary to the steps we have identified, building greater collaborations with industry and stakeholders in the region, contributed to outreach efforts that spanned all partnerships, co-authorship on the Carbon Capture and Separation report, and developed a regional basis to address future energy opportunities in the region. The deliverables and activities are discussed in the following sections and appended to this report. The education and outreach efforts have resulted in a comprehensive plan which serves as a guide for implementing the outreach activities under Phase I. The public website has been expanded and integrated with the GIS carbon atlas. We have made presentations to stakeholders and policy makers including two tribal sequestration workshops, and made connections to other federal and state agencies concerned with GHG emissions, climate change, and efficient and environmental

  1. CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA

    E-Print Network [OSTI]

    GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA: REPORT TO THE LEGISLATURE Regional Carbon Sequestration Partnership (WESTCARB) studies that we used, including Cameron Downey

  2. ARM: 10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2010-12-15

    10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  3. ARM: 10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  4. The computation of conical diffraction coefficients in high-frequency acoustic wave scattering

    E-Print Network [OSTI]

    Scheichl, Robert

    The computation of conical diffraction coefficients in high-frequency acoustic wave scattering B DIFFRACTION COEFFICIENTS IN HIGH-FREQUENCY ACOUSTIC WAVE SCATTERING B.D. BONNER, I.G. GRAHAM, AND V.P. SMYSHLYAEV§ Abstract. When a high-frequency acoustic or electromagnetic wave is scattered by a surface

  5. On the Stochastic Maximum Principle in Optimal Control of Degenerate Diffusions with Lipschitz Coefficients

    SciTech Connect (OSTI)

    Bahlali, Khaled Djehiche, Boualem Mezerdi, Brahim

    2007-12-15

    We establish a stochastic maximum principle in optimal control of a general class of degenerate diffusion processes with global Lipschitz coefficients, generalizing the existing results on stochastic control of diffusion processes. We use distributional derivatives of the coefficients and the Bouleau Hirsh flow property, in order to define the adjoint process on an extension of the initial probability space.

  6. Interparticle Potential and Drag Coefficient in Nematic Colloids Jurij Kotar,1

    E-Print Network [OSTI]

    Osterman, Natan

    large bead separations (x > 4 m, at a sphere diameter of 3 m), the force decays proportional to xÿ6 un- distorted measurements of forces as well as effective drag coefficient of an immersed beadInterparticle Potential and Drag Coefficient in Nematic Colloids Jurij Kotar,1 Mojca Vilfan,2 Natan

  7. Third virial coefficient for 4-arm and 6-arm star polymers

    E-Print Network [OSTI]

    Sergio Caracciolo; Bortolo Matteo Mognetti; Andrea Pelissetto

    2008-02-15

    We discuss the computation of the third virial coefficient in polymer systems, focusing on an additional contribution absent in the case of monoatomic fluids. We determine the interpenetration ratio and several quantities that involve the third virial coefficient for star polymers with 4 and 6 arms in the good-solvent regime, in the limit of a large degree of polymerization.

  8. Temperature Dependence of Evaporation Coefficient for Water Measured in Droplets in Nitrogen under Atmospheric Pressure

    E-Print Network [OSTI]

    Atmospheric Pressure D. JAKUBCZYK, M. ZIENTARA, K. KOLWAS, AND M. KOLWAS Institute of Physics, Polish Academy 277 to 289 K was found to be 0.7 0.2. 1. Introduction The processes of evaporation and condensation (condensation) or mass accommodation coefficient C. Likewise the ther- mal conductivity coefficient must

  9. Simultaneous determination of mass and thermal accommodation coefficients from temporal evolution

    E-Print Network [OSTI]

    of Physics of the Polish Academy of Sciences, al.Lotnik´ow 32/46, 02-668 Warsaw, Poland E-mail: jakub: J. Phys. D: Appl. Phys. 1. Introduction The processes of evaporation and condensation coefficient with a so called evaporation (condensation) or mass accommodation coefficient C. Likewise

  10. Electro-optic coefficients of lithium tantalate at near-infrared wavelengths

    E-Print Network [OSTI]

    Gopalan, Venkatraman

    Electro-optic coefficients of lithium tantalate at near-infrared wavelengths Joanna L. Casson April 27, 2004 The unclamped linear electro-optic coefficients r13 and r33 for lithium tantalate. In the unclamped mode the effects of mechanical changes caused by piezoelectric and elasto-optic effects

  11. Aspect Ratio Dependence of Electromechanical Coupling Coefficient k31 of Lateral-Excitation Piezoelectric Vibrator

    E-Print Network [OSTI]

    Cao, Wenwu

    Aspect Ratio Dependence of Electromechanical Coupling Coefficient k31 of Lateral analyszed. As a result, a formula for the electromechanical coupling coefficient k31 was derived-mode piezoelectric vibrator with an arbitrary aspect ratio. [DOI: 10.1143/JJAP.46.4459] KEYWORDS: electromechanical

  12. Formaldehyde around 3.5 and 5.7-mm: Measurement and calculation of broadening coefficients

    E-Print Network [OSTI]

    Gamache, Robert R.

    Formaldehyde around 3.5 and 5.7-mm: Measurement and calculation of broadening coefficients D February 2010 Keywords: Formaldehyde Broadening coefficients Widths H2CO Fourier transform spectroscopy has been generated to complete the whole HITRAN 2008 version of formaldehyde (available

  13. Specular highlights of plastic surfaces and the Fresnel Coefficient Elli Angelopoulou*

    E-Print Network [OSTI]

    Angelopoulou, Elli

    Specular highlights of plastic surfaces and the Fresnel Coefficient Elli Angelopoulou* and Sofya of the Fresnel reflec- tance coefficient and its dependence on wavelength. Our theoretical analysis establishes that the sensitivity of the Fresnel term to the wavelength variations of the refractive index can be at least as large

  14. Flow Boiling Heat Transfer Coefficient In Minichannels Correlation and Trends Satish G. Kandlikar

    E-Print Network [OSTI]

    Kandlikar, Satish

    Flow Boiling Heat Transfer Coefficient In Minichannels ­ Correlation and Trends Satish G. Kandlikar York 14623, USA The flow boiling heat transfer in small diameter passages is being applied in many boiling heat transfer coefficient with the correlations developed for conventional channels. It is found

  15. Scaling of Heat Transfer Coefficients Along Louvered Fins A. C. Lyman1

    E-Print Network [OSTI]

    Thole, Karen A.

    1 Scaling of Heat Transfer Coefficients Along Louvered Fins A. C. Lyman1 , R. A. Stephan2 , and K 23681-2199 #12;2 Abstract Louvered fins provide a method for improving the heat transfer performance for evaluating the spatially-resolved louver heat transfer coefficients using various reference temperatures

  16. Estimating a Volumetric Backscatter Coefficient from Measurements on the Greenland Ice Sheet

    E-Print Network [OSTI]

    Kansas, University of

    Estimating a Volumetric Backscatter Coefficient from Measurements on the Greenland Ice Sheet J (> 25°) the measured backscatter is dominated by volumetric scattering, as opposed to surface and specu the volumetric backscatter coefficient as a function of depth in flrn. Re- sults show trends consistent with both

  17. Persistent local order heterogeneity in the supercritical carbon dioxide

    E-Print Network [OSTI]

    Bolmatov, Dima; Gao, M; Zhernenkov, M

    2014-01-01

    The supercritical state is currently viewed as uniform and homogeneous on the pressure-temperature phase diagram in terms of physical properties. Here, we study structural properties of the supercritical carbon dioxide, and discover the existence of persistent medium-range order correlations which make supercritical carbon dioxide non-uniform and heterogeneous on an intermediate length scale, a result not hitherto anticipated. We report on the carbon dioxide heterogeneity shell structure where, in the first shell, both carbon and oxygen atoms experience gas-like type inter- actions with short range order correlations, while within the second shell oxygen atoms essentially exhibit liquid-like type of interactions with medium range order correlations due to localisation of transverse-like phonon packets. We show that the local order heterogeneity remains in the three phase-like equilibrium within very wide temperature range. Importantly, we highlight a catalytic role of atoms inside the nearest neighbor heterog...

  18. Type Ia Supernovae: Toward the Standard Model?

    E-Print Network [OSTI]

    David Branch

    2000-12-13

    In this short review I suggest that recent developments support the conjecture that Type Ia supernovae (SNe Ia) are the complete disruptions of Chandrasekhar-mass carbon-oxygen white dwarfs in single-degenerate binary systems. The causes of the observational diversity of SNe Ia within the context of this standard model, and the implications of the model for young remnants of SNe Ia, are briefly discussed.

  19. Electrolyte matrix for molten carbonate fuel cells

    DOE Patents [OSTI]

    Huang, C.M.; Yuh, C.Y.

    1999-02-09

    A matrix is described for a carbonate electrolyte including a support material and an additive constituent having a relatively low melting temperature and a relatively high coefficient of thermal expansion. The additive constituent is from 3 to 45 weight percent of the matrix and is formed from raw particles whose diameter is in a range of 0.1 {micro}m to 20 {micro}m and whose aspect ratio is in a range of 1 to 50. High energy intensive milling is used to mix the support material and additive constituent during matrix formation. Also disclosed is the use of a further additive constituent comprising an alkaline earth containing material. The further additive is mixed with the support material using high energy intensive milling. 5 figs.

  20. Electrolyte matrix for molten carbonate fuel cells

    DOE Patents [OSTI]

    Huang, Chao M. (Danbury, CT); Yuh, Chao-Yi (New Milford, CT)

    1999-01-01

    A matrix for a carbonate electrolyte including a support material and an additive constituent having a relatively low melting temperature and a relatively high coefficient of thermal expansion. The additive constituent is from 3 to 45 weight percent of the matrix and is formed from raw particles whose diameter is in a range of 0.1 .mu.m to 20 .mu.m and whose aspect ratio is in a range of 1 to 50. High energy intensive milling is used to mix the support material and additive constituent during matrix formation. Also disclosed is the use of a further additive constituent comprising an alkaline earth containing material. The further additive is mixed with the support material using high energy intensive milling.

  1. Trading Water for Carbon with Biological Carbon Sequestration

    E-Print Network [OSTI]

    Jackson, Robert B.

    Trading Water for Carbon with Biological Carbon Sequestration Robert B. Jackson,1 * Esteban G. Farley,1 David C. le Maitre,5 Bruce A. McCarl,6 Brian C. Murray7 Carbon sequestration strategies plantations feature prominently among tools for carbon sequestration (1­8). Plantations typi- cally combine

  2. Henry`s law solubilities and Setchenow coefficients for biogenic reduced sulfur species obtained from gas-liquid uptake measurements

    SciTech Connect (OSTI)

    De Bruyn, W.J.; Swartz, E.; Hu, J.H. [Boston College, Chestnut Hill, MA (United States)] [and others] [Boston College, Chestnut Hill, MA (United States); and others

    1995-04-20

    Biogenically produced reduced sulfur compounds, including dimethylsulfide (DMS, CH{sub 3}SCH{sub 3}), hydrogen sulfide (H{sub 2}S), carbon disulfide (CS{sub 2}), methyl mercaptan (CH{sub 3}SH), and carbonyl sulfide (OCS), are a major source of sulfur in the marine atmosphere. This source is estimated to contribute 25-40% of global sulfur emissions. These species and their oxidation products, dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO{sub 2}), and methane sulfonic acid (MSA), dominate the production of aerosol and cloud condensation nuclei (CCN) in the clean marine atmosphere. The multiphase chemical processes for these species must be understood in order to study the evolving role of combustion-produced sulfur oxides over the oceans. Using a newly developed bubble column apparatus, a series of aqueous phase uptake studies have been completed for the reduced sulfur species DMS, H{sub 2}S, CS{sub 2}, CH{sub 3}SH, and OCS. Aqueous phase uptake has been studied as a function of temperature (278-298 K), pH (1-14), H{sub 2}O{sub 2} concentration (0-1 M), NaCl concentration (0-5 M), and (NH{sub 4}){sub 2}SO{sub 4} concentration (0-4 M). The Henry`s law coefficients for CH{sub 3}SH and CS{sub 2} were determined for the first time, as were the Setchenow coefficients for all the species studied. 33 refs., 8 figs., 2 tabs.

  3. IMPACCT: Carbon Capture Technology

    SciTech Connect (OSTI)

    2012-01-01

    IMPACCT Project: IMPACCT’s 15 projects seek to develop technologies for existing coal-fired power plants that will lower the cost of carbon capture. Short for “Innovative Materials and Processes for Advanced Carbon Capture Technologies,” the IMPACCT Project is geared toward minimizing the cost of removing carbon dioxide (CO2) from coal-fired power plant exhaust by developing materials and processes that have never before been considered for this application. Retrofitting coal-fired power plants to capture the CO2 they produce would enable greenhouse gas reductions without forcing these plants to close, shifting away from the inexpensive and abundant U.S. coal supply.

  4. Improving carbon fixation pathways

    SciTech Connect (OSTI)

    Ducat, DC; Silver, PA

    2012-08-01

    A recent resurgence in basic and applied research on photosynthesis has been driven in part by recognition that fulfilling future food and energy requirements will necessitate improvements in crop carbon-fixation efficiencies. Photosynthesis in traditional terrestrial crops is being reexamined in light of molecular strategies employed by photosynthetic microbes to enhance the activity of the Calvin cycle. Synthetic biology is well-situated to provide original approaches for compartmentalizing and enhancing photosynthetic reactions in a species independent manner. Furthermore, the elucidation of alternative carbon-fixation routes distinct from the Calvin cycle raises possibilities that novel pathways and organisms can be utilized to fix atmospheric carbon dioxide into useful materials.

  5. Types of Commissioning

    Broader source: Energy.gov [DOE]

    Several commissioning types exist to address the specific needs of equipment and systems across both new and existing buildings. The following commissioning types provide a good overview.

  6. Postdoc Appointment Types

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Appointment Types Postdoc Appointment Types Most postdocs will be offered a postdoctoral research associate appointment. Each year, approximately 30 Postdoctoral Fellow...

  7. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-06-01

    The Big Sky Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts during the second performance period fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies. Two key deliverables were completed this quarter--a literature review/database to assess the soil carbon on rangelands, and the draft protocols, contracting options for soil carbon trading. To date, there has been little research on soil carbon on rangelands, and since rangeland constitutes a major land use in the Big Sky region, this is important in achieving a better understanding of terrestrial sinks. The protocols developed for soil carbon trading are unique and provide a key component of the mechanisms that might be used to efficiently sequester GHG and reduce CO{sub 2} concentrations. Progress on other deliverables is noted in the PowerPoint presentations. A series of meetings held during the second quarter have laid the foundations for assessing the issues surrounding the implementation of a market-based setting for soil C credits. These meetings provide a connection to stakeholders in the region and a basis on which to draw for the DOE PEIS hearings. Finally, the education and outreach efforts have resulted in a comprehensive plan and process which serves as a guide for implementing the outreach activities under Phase I. While we are still working on the public website, we have made many presentations to stakeholders and policy makers, connections to other federal and state agencies concerned with GHG emissions, climate change, and efficient and environmentally-friendly energy production. In addition, we have laid plans for integration of our outreach efforts with the students, especially at the tribal colleges and at the universities involved in our partnership. This includes collaboration with the film and media arts departments at MSU, with outreach effort

  8. Hydrogen in Type Ic Supernovae?

    E-Print Network [OSTI]

    David Branch; David J. Jeffery; Timothy R. Young; E. Baron

    2006-05-09

    By definition, a Type Ic supernova (SN Ic) does not have conspicuous lines of hydrogen or helium in its optical spectrum. SNe Ic usually are modelled in terms of the gravitational collapse of bare carbon-oxygen cores. We consider the possibility that the spectra of ordinary (SN 1994I-like) SNe Ic have been misinterpreted, and that SNe Ic eject hydrogen. An absorption feature usually attributed to a blend of Si II 6355 and C II 6580 may be produced by H-alpha. If SN 1994I-like SNe Ic eject hydrogen, the possibility that hypernova (SN 1998bw-like) SNe Ic, some of which are associated with gamma-ray bursts, also eject hydrogen should be considered. The implications of hydrogen for SN Ic progenitors and explosion models are briefly discussed.

  9. Big Sky Carbon Sequestration Partnership

    SciTech Connect (OSTI)

    Susan Capalbo

    2005-12-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I are organized into four areas: (1) Evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; (2) Development of GIS-based reporting framework that links with national networks; (3) Design of an integrated suite of monitoring, measuring, and verification technologies, market-based opportunities for carbon management, and an economic/risk assessment framework; (referred to below as the Advanced Concepts component of the Phase I efforts) and (4) Initiation of a comprehensive education and outreach program. As a result of the Phase I activities, the groundwork is in place to provide an assessment of storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that complements the ongoing DOE research agenda in Carbon Sequestration. The geology of the Big Sky Carbon Sequestration Partnership Region is favorable for the potential sequestration of enormous volume of CO{sub 2}. The United States Geological Survey (USGS 1995) identified 10 geologic provinces and 111 plays in the region. These provinces and plays include both sedimentary rock types characteristic of oil, gas, and coal productions as well as large areas of mafic volcanic rocks. Of the 10 provinces and 111 plays, 1 province and 4 plays are located within Idaho. The remaining 9 provinces and 107 plays are dominated by sedimentary rocks and located in the states of Montana and Wyoming. The potential sequestration capacity of the 9 sedimentary provinces within the region ranges from 25,000 to almost 900,000 million metric tons of CO{sub 2}. Overall every sedimentary formation investigated has significant potential to sequester large amounts of CO{sub 2}. Simulations conducted to evaluate mineral trapping potential of mafic volcanic rock formations located in the Idaho province suggest that supercritical CO{sub 2} is converted to solid carbonate mineral within a few hundred years and permanently entombs the carbon. Although MMV for this rock type may be challenging, a carefully chosen combination of geophysical and geochemical techniques should allow assessment of the fate of CO{sub 2} in deep basalt hosted aquifers. Terrestrial carbon sequestration relies on land management practices and technologies to remove atmospheric CO{sub 2} where it is stored in trees, plants, and soil. This indirect sequestration can be implemented today and is on the front line of voluntary, market-based approaches to reduce CO{sub 2} emissions. Initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil Carbon (C) on rangelands, and forested, agricultural, and reclaimed lands. Rangelands can store up to an additional 0.05 mt C/ha/yr, while the croplands are on average four times that amount. Estimates of technical potential for soil sequestration within the region in cropland are in the range of 2.0 M mt C/yr over 20 year time horizon. This is equivalent to approximately 7.0 M mt CO{sub 2}e/yr. The forestry sinks are well documented, and the potential in the Big Sky region ranges from 9-15 M mt CO{sub 2} equivalent per year. Value-added benefits include enhanced yields, reduced erosion, and increased wildlife habitat. Thus the terrestrial sinks provide a viable, environmentally beneficial, and relatively low cost sink that is available to sequester C in the current time frame. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological and terrestrial sequestration re

  10. Iron-Doped Carbon Aerogels: Novel Porous Substrates for Direct Growth of Carbon Nanotubes

    SciTech Connect (OSTI)

    Steiner, S A; Baumann, T F; Kong, J; Satcher, J H; Dresselhaus, M S

    2007-02-15

    We present the synthesis and characterization of Fe-doped carbon aerogels (CAs) and demonstrate the ability to grow carbon nanotubes directly on monoliths of these materials to afford novel carbon aerogel-carbon nanotube composites. Preparation of the Fe-doped CAs begins with the sol-gel polymerization of the potassium salt of 2,4-dihydroxybenzoic acid with formaldehyde, affording K{sup +}-doped gels that can then be converted to Fe{sup 2+}- or Fe{sup 3+}-doped gels through an ion exchange process, dried with supercritical CO{sub 2} and subsequently carbonized under an inert atmosphere. Analysis of the Fe-doped CAs by TEM, XRD and XPS revealed that the doped iron species are reduced during carbonization to form metallic iron and iron carbide nanoparticles. The sizes and chemical composition of the reduced Fe species were related to pyrolysis temperature as well as the type of iron salt used in the ion exchange process. Raman spectroscopy and XRD analysis further reveal that, despite the presence of the Fe species, the CA framework is not significantly graphitized during pyrolysis. The Fe-doped CAs were subsequently placed in a thermal CVD reactor and exposed to a mixture of CH{sub 4} (1000 sccm), H{sub 2} (500 sccm), and C{sub 2}H{sub 4} (20 sccm) at temperatures ranging from 600 to 800 C for 10 minutes, resulting in direct growth of carbon nanotubes on the aerogel monoliths. Carbon nanotubes grown by this method appear to be multiwalled ({approx}25 nm in diameter and up to 4 mm long) and grow through a tip-growth mechanism that pushes catalytic iron particles out of the aerogel framework. The highest yield of CNTs were grown on Fe-doped CAs pyrolyzed at 800 C treated at CVD temperatures of 700 C.

  11. Research Report Forests and carbon

    E-Print Network [OSTI]

    , baseline, carbon, climate change mitigation, forestry, quality assurance, sequestration. FCRP013/FCResearch Report Forests and carbon: a review of additionality #12;#12;Forests and carbon: a review. ISBN 978-0-85538-816-4 Valatin, G. (2011). Forests and carbon: a review of additionality. Forestry

  12. Biosensors Based on Carbon Nanotubes

    SciTech Connect (OSTI)

    Lin, Yuehe; Yantasee, Wassana; Lu, Fang; Wang, Joseph; Musameh, Mustafa; Tu, Yi; Ren, Zhifeng

    2009-03-24

    This chapter summarizes the recent development of carbon nanotube based electrochemical biosensors work at PNNL.

  13. Biosensors Based on Carbon Nanotubes

    SciTech Connect (OSTI)

    Lin, Yuehe; Yantasee, Wassana; Lu, Fang; Wang, Joseph; Musameh, Mustafa; Tu, Yi; Ren, Zhifeng; J. A. Schwarz, C. Contescu, K. Putyera

    2004-04-01

    This invited review article summarizes recent work on biosensor development based on carbon nanotubes

  14. Method for synthesizing carbon nanotubes

    DOE Patents [OSTI]

    Fan, Hongyou

    2012-09-04

    A method for preparing a precursor solution for synthesis of carbon nanomaterials, where a polar solvent is added to at least one block copolymer and at least one carbohydrate compound, and the precursor solution is processed using a self-assembly process and subsequent heating to form nanoporous carbon films, porous carbon nanotubes, and porous carbon nanoparticles.

  15. ATK - Supersonic Carbon Capture

    ScienceCinema (OSTI)

    Castrogiovanni, Anthony (ACEnT Laboratories, President and CEO); Calayag, Bon (ATK, Program Manager)

    2014-04-11

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  16. ATK - Supersonic Carbon Capture

    SciTech Connect (OSTI)

    Castrogiovanni, Anthony; Calayag, Bon

    2014-03-05

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  17. CARBON DIOXIDE EMISSION REDUCTION

    E-Print Network [OSTI]

    Delaware, University of

    ........................................................................................ 21 2.3.5 Pulp and paper industry Technologies and Measures in Pulp and Paper IndustryCARBON DIOXIDE EMISSION REDUCTION TECHNOLOGIES AND MEASURES IN US INDUSTRIAL SECTOR FINAL REPORT

  18. Activated carbon aerogels

    SciTech Connect (OSTI)

    Hanzawa, Y.; Kaneko, K. [Chiba Univ. (Japan)] [Chiba Univ. (Japan); Pekala, R.W. [Lawrence Livermore National Lab., CA (United States)] [Lawrence Livermore National Lab., CA (United States); Dresselhaus, M.S. [Massachusetts Inst. of Technology, Cambridge, MA (United States)] [Massachusetts Inst. of Technology, Cambridge, MA (United States)

    1996-12-25

    Activated carbon aerogels were obtained from the CO{sub 2} activation of the carbon aerogels. The adsorption isotherms of nitrogen on activated carbon aerogels at 77 K were measured and analyzed by the high-resolution {alpha}{sub s} plot to evaluate their porosities. The {alpha}{sub s} plot showed an upward deviation from linearity below {alpha}{sub s} = 0.5, suggesting that the presence of micropores becomes more predominant with the extent of the activation. Activation increased noticeably the pore volume and the surface area (the maximum value: 2600 m{sup 2}.g{sup -1}) without change of the basic network structure of primary particles. Activated carbon aerogels had a bimodal pore size distribution of uniform micropores and mesopores. 16 refs., 2 figs., 1 tab.

  19. Regional Carbon Sequestration Partnerships

    Broader source: Energy.gov [DOE]

    DOE has created a network of seven Regional Carbon Sequestration Partnerships (RCSPs) to help develop the technology, infrastructure, and regulations to implement large-scale CO2 storage (also...

  20. Low Carbon Fuel Standards

    E-Print Network [OSTI]

    Sperling, Dan; Yeh, Sonia

    2009-01-01

    S O N I A YE H Low Carbon Fuel Standards The most direct andalternative transportation fuels is to spur innovation withstandard for upstream fuel producers. hen it comes to energy

  1. Black Carbon’s Properties and Role in the Environment: A Comprehensive Review

    E-Print Network [OSTI]

    Shrestha, Gyami

    2010-01-01

    black carbon and carbon dioxide emissions. Energ. Policyreduces predicted carbon dioxide emissions estimation by upincrease rates of carbon dioxide emissions [135,136]. Due to

  2. Black Carbon’s Properties and Role in the Environment: A Comprehensive Review

    E-Print Network [OSTI]

    Shrestha, Gyami

    2010-01-01

    Keywords: soil carbon sequestration; carbon budget;of an energy efficient carbon sequestration mechanism, asin the later section on carbon sequestration. In atmospheric

  3. Carbon dioxide removal process

    DOE Patents [OSTI]

    Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

    2003-11-18

    A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

  4. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, S.E.; Moses, W.W.

    1991-05-14

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses. 3 figures.

  5. Types of Lights Types of Lights

    E-Print Network [OSTI]

    1 Types of Lights Types of Lights q So far we have studied point lights ­ Radiate in all direc7ons q Other lights ­ Direc7onal lights (posi7on-independent) ­ Spotlights #12;2 Direc1onal Lights q Shine in a single, uniform direc7on q All rays

  6. Extraction of the symmetry energy coefficients from the masses differences of isobaric nuclei

    E-Print Network [OSTI]

    Junlong Tian; Haitao Cui; Kuankuan Zheng; Ning Wang

    2014-03-28

    The nuclear symmetry energy coefficients of finite nuclei are extracted by using the differences between the masses of isobaric nuclei. Based on the masses of more than 2400 nuclei with $A=9-270$, we investigate the model dependence in the extraction of symmetry energy coefficient. We find that the extraction of the symmetry energy coefficients is strongly correlated with the forms of the Coulomb energy and the mass dependence of the symmetry energy coefficient adopted. The values of the extracted symmetry energy coefficients increase by about 2 MeV for heavy nuclei when the Coulomb correction term is involved. We obtain the bulk symmetry energy coefficient $S_0=28.26\\pm1.3$ MeV and the surface-to-volume ratio $\\kappa=1.26\\pm 0.25 $ MeV if assuming the mass dependence of symmetry energy coefficient $a_{\\rm sym}(A)=S_0(1-\\kappa/A^{1/3})$, and $S_0=32.80\\pm1.7$ MeV, $\\kappa=2.82\\pm0.57$ MeV when $a_{\\rm sym}(A)=S_0 (1+\\kappa/A^{1/3})^{-1}$ is adopted.

  7. A Semi-Empirical Two Step Carbon Corrosion Reaction Model in PEM Fuel Cells

    SciTech Connect (OSTI)

    Young, Alan; Colbow, Vesna; Harvey, David; Rogers, Erin; Wessel, Silvia

    2013-01-01

    The cathode CL of a polymer electrolyte membrane fuel cell (PEMFC) was exposed to high potentials, 1.0 to 1.4 V versus a reversible hydrogen electrode (RHE), that are typically encountered during start up/shut down operation. While both platinum dissolution and carbon corrosion occurred, the carbon corrosion effects were isolated and modeled. The presented model separates the carbon corrosion process into two reaction steps; (1) oxidation of the carbon surface to carbon-oxygen groups, and (2) further corrosion of the oxidized surface to carbon dioxide/monoxide. To oxidize and corrode the cathode catalyst carbon support, the CL was subjected to an accelerated stress test cycled the potential from 0.6 VRHE to an upper potential limit (UPL) ranging from 0.9 to 1.4 VRHE at varying dwell times. The reaction rate constants and specific capacitances of carbon and platinum were fitted by evaluating the double layer capacitance (Cdl) trends. Carbon surface oxidation increased the Cdl due to increased specific capacitance for carbon surfaces with carbon-oxygen groups, while the second corrosion reaction decreased the Cdl due to loss of the overall carbon surface area. The first oxidation step differed between carbon types, while both reaction rate constants were found to have a dependency on UPL, temperature, and gas relative humidity.

  8. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2005-01-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I fall into four areas: evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; development of GIS-based reporting framework that links with national networks; designing an integrated suite of monitoring, measuring, and verification technologies and assessment frameworks; and initiating a comprehensive education and outreach program. The groundwork is in place to provide an assessment of storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. Efforts are underway to showcase the architecture of the GIS framework and initial results for sources and sinks. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies.

  9. Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3)

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2 monoxide (CO), carbon dioxide (CO2), and molecular oxygen (O2) with varying carbon-to-oxygen ratios from 1 and destruction pathways of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3

  10. Transport coefficients of strongly coupled gauge theories: insights from string theory

    E-Print Network [OSTI]

    Andrei O. Starinets

    2005-11-26

    The transport properties of certain strongly coupled thermal gauge theories can be determined from their effective description in terms of gravity or superstring theory duals. Here we provide a short summary of the results for the shear and bulk viscosity, charge diffusion constant, and the speed of sound in supersymmetric strongly interacting plasmas. We also outline a general algorithm for computing transport coefficients in any gravity dual. The algorithm relates the transport coefficients to the coefficients in the quasinormal spectrum of five-dimensional black holes in asymptotically anti de Sitter space.

  11. Determining Importance Weighting Functions for Contributon Theory Eigenvalue Sensitivity Coefficient Methodologies

    SciTech Connect (OSTI)

    Perfetti, Christopher M [ORNL] [ORNL; Martin, William R [University of Michigan] [University of Michigan; Rearden, Bradley T [ORNL] [ORNL; Williams, Mark L [ORNL] [ORNL

    2012-01-01

    This study introduced three approaches for calculating the importance weighting function for Contributon and CLUTCH eigenvalue sensitivity coefficient calculations, and compared them in terms of accuracy and applicability. The necessary levels of mesh refinement and mesh convergence for obtaining accurate eigenvalue sensitivity coefficients were determined through two parametric studies, and the results of these studies suggest that a sufficiently-accurate mesh for calculating eigenvalue sensitivity coefficients can be obtained for the Contributon and CLUTCH methods with only a small increase in problem runtime.

  12. Implications of Carbon Regulation for Green Power Markets

    SciTech Connect (OSTI)

    Bird, L.; Holt, E.; Carroll, G.

    2007-04-01

    This paper examines the potential effects that emerging mandatory carbon markets have for voluntary markets for renewable energy, or green power markets. In an era of carbon regulation, green power markets will continue to play an important role because many consumers may be interested in supporting renewable energy development beyond what is supported through mandates or other types of policy support. The paper examines the extent to which GHG benefits motivate consumers to make voluntary renewable energy purchases and summarizes key issues emerging as a result of these overlapping markets, such as the implications of carbon regulation for renewable energy marketing claims, the demand for and price of renewable energy certificates (RECs), and the use of RECs in multiple markets (disaggregation of attributes). It describes carbon regulation programs under development in the Northeast and California, and how these might affect renewable energy markets in these regions, as well as the potential interaction between voluntary renewable energy markets and voluntary carbon markets, such as the Chicago Climate Exchange (CCX). It also briefly summarizes the experience in the European Union, where carbon is already regulated. Finally, the paper presents policy options for policymakers and regulators to consider in designing carbon policies to enable carbon markets and voluntary renewable energy markets to work together.

  13. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Thomas Nelson; Brian S. Turk; Paul Box; Weijiong Li; Raghubir P. Gupta

    2005-07-01

    This report describes research conducted between April 1, 2005 and June 30, 2005 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas from coal combustion and synthesis gas from coal gasification. Supported sodium carbonate sorbents removed up to 76% of the carbon dioxide from simulated flue gas in a downflow cocurrent flow reactor system, with an approximate 15 second gas-solid contact time. This reaction proceeds at temperatures as low as 25 C. Lithium silicate sorbents remove carbon dioxide from high temperature simulated flue gas and simulated synthesis gas. Both sorbent types can be thermally regenerated and reused. The lithium silicate sorbent was tested in a thermogravimetric analyzer and in a 1-in quartz reactor at atmospheric pressure; tests were also conducted at elevated pressure in a 2-in diameter high temperature high pressure reactor system. The lithium sorbent reacts rapidly with carbon dioxide in flue gas at 350-500 C to absorb about 10% of the sorbent weight, then continues to react at a lower rate. The sorbent can be essentially completely regenerated at temperatures above 600 C and reused. In atmospheric pressure tests with synthesis gas of 10% initial carbon dioxide content, the sorbent removed over 90% of the carbon dioxide. An economic analysis of a downflow absorption process for removal of carbon dioxide from flue gas with a supported sodium carbonate sorbent suggests that a 90% efficient carbon dioxide capture system installed at a 500 MW{sub e} generating plant would have an incremental capital cost of $35 million ($91/kWe, assuming 20 percent for contingencies) and an operating cost of $0.0046/kWh. Assuming capital costs of $1,000/kW for a 500 MWe plant the capital cost of the down flow absorption process represents a less than 10% increase, thus meeting DOE goals as set forth in its Carbon Sequestration Technology Roadmap and Program Plan.

  14. Measurement of carbon capture efficiency and stored carbon leakage

    SciTech Connect (OSTI)

    Keeling, Ralph F.; Dubey, Manvendra K.

    2013-01-29

    Data representative of a measured carbon dioxide (CO.sub.2) concentration and of a measured oxygen (O.sub.2) concentration at a measurement location can be used to determine whether the measured carbon dioxide concentration at the measurement location is elevated relative to a baseline carbon dioxide concentration due to escape of carbon dioxide from a source associated with a carbon capture and storage process. Optionally, the data can be used to quantify a carbon dioxide concentration increase at the first location that is attributable to escape of carbon dioxide from the source and to calculate a rate of escape of carbon dioxide from the source by executing a model of gas-phase transport using at least the first carbon dioxide concentration increase. Related systems, methods, and articles of manufacture are also described.

  15. RESTORING SUSTAINABLE FORESTS ON APPALACHIAN MINED LANDS FOR WOOD PRODUCTS, RENEWABLE ENERGY, CARBON SEQUESTRATION, AND OTHER ECOSYSTEM SERVICES

    SciTech Connect (OSTI)

    J. Burger; J. Galbraith; T. Fox; G. Amacher; J. Sullivan; C. Zipper

    2003-12-18

    The overall purpose of this project is to evaluate the biological and economic feasibility of restoring high-quality forests on mined land, and to measure carbon sequestration and wood production benefits that would be achieved from forest restoration procedures. In this quarterly report, we present a preliminary comparison of the carbon sequestration benefits for two forest types used to convert abandoned grasslands for carbon sequestration. Annual mixed hardwood benefits, based on total stand carbon volume present at the end of a given year, range from a minimum of $0/ton of carbon to a maximum of $5.26/ton of carbon (low prices). White pine benefits based on carbon volume range from a minimum of $0/ton of carbon to a maximum of $18.61/ton of carbon (high prices). The higher maximum white pine carbon payment can primarily be attributed to the fact that the shorter rotation means that payments for white pine carbon are being made on far less cumulative carbon tonnage than for that of the long-rotation hardwoods. Therefore, the payment per ton of white pine carbon needs to be higher than that of the hardwoods in order to render the conversion to white pine profitable by the end of a rotation. These carbon payments may seem appealingly low to the incentive provider. However, payments (not discounted) made over a full rotation may add up to approximately $17,493/ha for white pine (30-year rotation), and $18,820/ha for mixed hardwoods (60-year rotation). The literature suggests a range of carbon sequestration costs, from $0/ton of carbon to $120/ton of carbon, although the majority of studies suggest a cost below $50/ ton of carbon, with van Kooten et al. (2000) suggesting a cutoff cost of $20/ton of carbon sequestered. Thus, the ranges of carbon payments estimated for this study fall well within the ranges of carbon sequestration costs estimated in previous studies.

  16. WESTCARB Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The West Coast Regional Carbon Sequestration Partnership (known as WESTCARB) was established in Fall 2003. It is one of seven research partnerships co-funded by DOE to characterize regional carbon sequestration opportunities and conduct pilot-scale validation tests. The California Energy Commission manages WESTCARB and is a major co-funder. WESTCARB is characterizing the extent and capacity of geologic formations capable of storing CO2, known as sinks. Results are entered into a geographic information system (GIS) database, along with the location of major CO2-emitting point sources in each of the six WESTCARB states, enabling researchers and the public to gauge the proximity of candidate CO2 storage sites to emission sources and the feasibility of linking them via pipelines. Specifically, the WESTCARB GIS database (also known as the carbon atlas) stores layers of geologic information about potential underground storage sites, such as porosity and nearby fault-lines and aquifers. Researchers use these data, along with interpreted geophysical data and available oil and gas well logs to estimate the region's potential geologic storage capacity. The database also depicts existing pipeline routes and rights-of-way and lands that could be off-limits, which can aid the development of a regional carbon management strategy. The WESTCARB Carbon Atlas, which is accessible to the public, provides a resource for public discourse on practical solutions for regional CO2 management. A key WESTCARB partner, the Utah Automated Geographic Reference Center, has developed data serving procedures to enable the WESTCARB Carbon Atlas to be integrated with those from other regional partnerships, thereby supporting the U.S. Department of Energy's national carbon atlas, NATCARB

  17. Particles of spilled oil-absorbing carbon in contact with water

    DOE Patents [OSTI]

    Muradov, Nazim (Melbourne, FL)

    2011-03-29

    Hydrogen generator coupled to or integrated with a fuel cell for portable power applications. Hydrogen is produced via thermocatalytic decomposition (cracking, pyrolysis) of hydrocarbon fuels in oxidant-free environment. The apparatus can utilize a variety of hydrocarbon fuels, including natural gas, propane, gasoline, kerosene, diesel fuel, crude oil (including sulfurous fuels). The hydrogen-rich gas produced is free of carbon oxides or other reactive impurities, so it could be directly fed to any type of a fuel cell. The catalysts for hydrogen production in the apparatus are carbon-based or metal-based materials and doped, if necessary, with a sulfur-capturing agent. Additionally disclosed are two novel processes for the production of two types of carbon filaments, and a novel filamentous carbon product. Carbon particles with surface filaments having a hydrophobic property of oil film absorption, compositions of matter containing those particles, and a system for using the carbon particles for cleaning oil spills.

  18. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott J; Alvizo, Oscar

    2013-10-29

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  19. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott; Alvizo, Oscar

    2013-01-15

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  20. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2011-08-16

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  1. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  2. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2012-01-24

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  3. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2008-10-21

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  4. Logistic Models with Time-Dependent Coefficients and Some of Their Applications

    E-Print Network [OSTI]

    Raquel M. Lopez; Benjamin R. Morin; Sergei K. Suslov

    2010-08-15

    We discuss explicit solutions of the logistic model with variable parameters. Classical data on the sunflower seeds growth are revisited as a simple application of the logistic model with periodic coefficients. Some applications to related biological systems are briefly reviewed.

  5. Identification of Force Coefficients in Two Squeeze Film Dampers with a Central Groove 

    E-Print Network [OSTI]

    Seshagiri, Sanjeev

    2012-07-16

    . The recorded dynamic pressures in the film lands and central groove do not evidence lubricant vapor or gas cavitation for the tested static eccentricities and amplitudes of motion. The direct damping coefficients for both dampers are independent of excitation...

  6. Mean evaporation and condensation coefficients based on energy dependent condensation probability

    E-Print Network [OSTI]

    Struchtrup, Henning

    Maurice Bond and Henning Struchtrup* Department of Mechanical Engineering, University of Victoria, P. Ward, Phys. Rev. E 59, 419 (1999)]. It is shown that mean condensation and evaporation coefficients

  7. Identification of dynamic force coefficients of a labyrinth and gas damper seal using impact load excitations 

    E-Print Network [OSTI]

    Ransom, David Lawrence

    1997-01-01

    Experiments to identify stiffness and damping force coefficients of a two bladed teeth-on-stator labyrinth seal and a gas damper seal, both of diverging clearance, are presented. Calibrated impact guns excite a housing holding the test seal...

  8. Effects of Charge on Osmotic Reflection Coefficients of Macromolecules in Fibrous Membranes

    E-Print Network [OSTI]

    Bhalla, Gaurav

    A model based on continuum hydrodynamics and electrostatics was developed to predict the combined effects of molecular charge and size on the osmotic reflection coefficient (?[subscript o]) of a macromolecule in a fibrous ...

  9. The Henry's law coefficient of 2-nitrophenol over the temperature range 278–303 K 

    E-Print Network [OSTI]

    Heal, Mathew R

    2001-01-01

    Although 2-nitrophenol has been identified as an important environmental chemical there is scarcity in the literature regarding the temperature dependence of its Henry's law coefficient, H. Here a bubble purge method was ...

  10. Experimental study of rotordynamic coefficients of squeeze film dampers of an aircraft gas turbine engine 

    E-Print Network [OSTI]

    Na, Uhn Joo

    1996-01-01

    The rotordynamic coefficients of squeeze film dampers of an aircraft gas turbine engine were investigated experimentally. Rotordynamic model(XLROTOR) for Gas Generator and Power Turbine were constructed. The XLROTOR response plots with changing...

  11. Identification of force coefficients in flexible rotor-bearing systems - enhancements and further validations 

    E-Print Network [OSTI]

    Balantrapu, Achuta Kishore Rama Krishna

    2005-11-01

    Rotor-bearing system characteristics, such as natural frequencies, mode shapes, stiffness and damping coefficients, are essential to diagnose and correct vibration problems during system operation. Of the above characteristics, accurate...

  12. Frequency [Hz] Transmission Coefficient Amplitude h=0.00001 m h ...

    E-Print Network [OSTI]

    10. 0. 10. 1. 10. 2. 10. 3. 10. 4. 10. 5. 10. 6. 10. ?7. 10. ?6. 10. ?5. 10. ?4. 10. ?3. 10. ?2. 10. ?1. 10. 0. Frequency [Hz]. Transmission Coefficient Amplitude.

  13. On an economic prediction of the finer resolution level wavelet coefficients in electron structure calculations

    E-Print Network [OSTI]

    Szilvia Nagy; János Pipek

    2015-02-28

    In wavelet based electron structure calculations introducing a new, finer resolution level is usually an expensive task, this is why often a two-level approximation is used with very fine starting resolution level. This process results in large matrices to calculate with and a large number of coefficients to be stored. In our previous work we have developed an adaptively refining solution scheme that determines the indices, where refined basis functions are to be included, and later a method for predicting the next, finer resolution coefficients in a very economic way. In the present contribution we would like to determine, whether the method can be applied for predicting not only the first, but also the other, higher resolution level coefficients. Also the energy expectation values of the predicted wave functions are studied, as well as the scaling behaviour of the coefficients in the fine resolution limit.

  14. Quantifying the economic and commercial potential of a high strength, low thermal coefficient super-alloy

    E-Print Network [OSTI]

    Liew, Heng Lee Henry

    2008-01-01

    Inspired by the importance of having a favourable sheathing material for superconducting wires, a high-strength, low thermal coefficient (CTE) super-alloy has been developed. Known as Incoloy 908, this super-alloy's material ...

  15. A comparison of theoretical and experimental rotordynamic coefficients for helically grooved annular gas seals 

    E-Print Network [OSTI]

    Gansle, Anthony Joseph

    1993-01-01

    Experimental results for the rotordynamic coefficients and leakage characteristics of helically grooved annular gas seals are presented. The effects of speed, inlet pressure, pressure ratio, clearance, fluid pre-rotation, and groove angle...

  16. Effect of surfactant on evaporative heat transfer coefficients in vertical film forced convection 

    E-Print Network [OSTI]

    Shah, Basit Husain

    1972-01-01

    to the present design conditions in desalination evaporators. A commercial surfactant, procter and Gamble 'Joy ' (Ammon1um Lauryl Sulphate + Cl2-C)&-diethanoiamine, 3:1) was used in the present study. The evaporative coefficients were observed to increase... encountered in de- salinationn evaporators (36). The evaporative coeffici ents were determined under the above conditions for pure water as well as for solutions containing 15, 30, and 50 ppm of surfactant (Procter and Gamble 'Joy'). The feed to the boi...

  17. Consistency of field-theoretical and kinetic calculations of viscous transport coefficients for a relativistic fluid

    E-Print Network [OSTI]

    Gabriel S. Denicol; Xu-Guang Huang; Tomoi Koide; Dirk H. Rischke

    2010-03-03

    The transport coefficients of causal relativistic dissipative fluid dynamics are calculated both in a field-theoretical and a kinetic approach. We find that the results from the traditional kinetic calculation by Israel and Stewart are modified. The new expressions for the viscous transport coefficients agree with the results obtained in the field-theoretical approach when the contributions from pair creation and annihilation are neglected.

  18. Radiotracer determination of anion diffusion coefficients in the electronically conductive polymer polypyrrole 

    E-Print Network [OSTI]

    Burton, Bruce Lawrence

    1987-01-01

    was used as the reference electrode. Figure 2. A diagram of the working electrode. 1. 6 mm glass tube; 2. stainless steel wire; 3. heat shrinkable teflon tube; 4. 9 mm glass tube; 5. mercury; 6. convex platinum electrode. The reference electrode... diffusion coefficients in polypyrrole. The diffusion coefficient for perchlorate through oxidized polypyr role was measured using the method of tracer diffusion, a special case of self-diffusion. Polypyrrole perchlorate films containing 36C1-labelled...

  19. The discrete spectrum of Jacobi matrix related to recurrence relations with periodic coefficients

    E-Print Network [OSTI]

    V. V. Borzov; E. V. Damaskinsky

    2015-02-27

    In this note we investigate the discrete spectrum of Jacobi matrix corresponding to polynomials defined by recurrence relations with periodic coefficients. As examples we consider a)the case when period $N$ of coefficients of recurrence relations equals three (as a particular case we consider "parametric" Chebyshev polynomials introduced by authors early); b)the elementary $N$-symmetrical Chebyshev polynomials ($N=3,4,5$), that was introduced by authors in the study of the "composite model of generalized oscillator".

  20. Diffusion Coefficients in a Lamellar Lyotropic Phase: Evidence for Defects Connecting the Surfactant Structure

    E-Print Network [OSTI]

    Doru Constantin; Patrick Oswald

    2015-04-09

    We measure diffusion coefficients in the lamellar phase of the nonionic binary system C$_{12}$EO$_6$/H$_2$O using fluorescence recovery after photobleaching. The diffusion coefficient across the lamellae shows an abrupt increase upon approaching the lamellar-isotropic phase transition. We interpret this feature in terms of defects connecting the surfactant structure. An estimation of the defect density and of the variation in defect energy close to the transition is given in terms of a simple model.

  1. On carbon footprints and growing energy use

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2012-01-01

    On carbon footprints and growing energy use Curtis M.reductions in the carbon footprint of a growing organizationhis own organization's carbon footprint and answers this

  2. ASSESSMENT OF HOUSEHOLD CARBON FOOTPRINT REDUCTION POTENTIALS

    E-Print Network [OSTI]

    Masanet, Eric

    2010-01-01

    of  American household carbon footprint. ” Ecological and  limitations) of carbon footprint estimates toward of the art in carbon footprint analyses for California, 

  3. Carbon contamination topography analysis of EUV masks

    E-Print Network [OSTI]

    Fan, Y.-J.

    2010-01-01

    induced carbon contamination of extreme ultraviolet optics,"and A. Izumi. "Carbon contamination of EL'V mask: filmEffect of Carbon Contamination on the Printing Performance

  4. Conductive Carbon Coatings for Electrode Materials

    E-Print Network [OSTI]

    Doeff, Marca M.; Kostecki, Robert; Wilcox, James; Lau, Grace

    2007-01-01

    Raman spectrum of the carbon coating. Deconvoluted peaksConductive Carbon Coatings for Electrode Materials Marca M.for optimizing the carbon coatings on non-conductive battery

  5. Participatory Carbon Monitoring: Operational Guidance for National...

    Open Energy Info (EERE)

    Participatory Carbon Monitoring: Operational Guidance for National REDD+ Carbon Accounting Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Participatory Carbon...

  6. Carbon nanotubes : synthesis, characterization, and applications

    E-Print Network [OSTI]

    Deck, Christian Peter

    2009-01-01

    around Surface-Attached Carbon Nanotubes. Ind. Eng. Chem.the flexural rigidity of carbon nanotube ensembles. AppliedNanotechnology in Carbon Materials. Acta Metallurgica, 1997.

  7. Fourier Theory on the Complex Plane IV: Representability of Real Functions by their Fourier Coefficients

    E-Print Network [OSTI]

    Jorge L. deLyra

    2015-05-04

    The results presented in this paper are refinements of some results presented in a previous paper. Three such refined results are presented. The first one relaxes one of the basic hypotheses assumed in the previous paper, and thus extends the results obtained there to a wider class of real functions. The other two relate to a closer examination of the issue of the representability of real functions by their Fourier coefficients. As was shown in the previous paper, in many cases one can recover the real function from its Fourier coefficients even if the corresponding Fourier series diverges almost everywhere. In such cases we say that the real function is still representable by its Fourier coefficients. Here we establish a very weak condition on the Fourier coefficients that ensures the representability of the function by those coefficients. In addition to this, we show that any real function that is absolutely integrable can be recovered almost everywhere from, and hence is representable by, its Fourier coefficients, regardless of whether or not its Fourier series converges. Interestingly, this also provides proof for a conjecture proposed in the previous paper.

  8. Neutralizing Carbonic Acid in Deep Carbonate Strata below the North Atlantic

    SciTech Connect (OSTI)

    Daniel P. Schrag

    2005-12-01

    Our research is aimed at investigating several technical issues associated with carbon dioxide sequestration in calcium carbonate sediments below the sea floor through laboratory experiments and chemical transport modeling. Our goal is to evaluate the basic feasibility of this approach, including an assessment of optimal depths, sediment types, and other issues related to site selection. Through laboratory and modeling efforts, we are studying the flow of liquid carbon dioxide and carbon dioxide-water mixtures through calcium carbonate sediments to better understand the geomechanical and structural stability of the sediments during and after injection. Our modeling efforts in the first year show that the idea is feasible, but requires more sophisticated analysis of fluid flow at high pressure in deep sea sediments. In addition, we are investigating the kinetics of calcium carbonate dissolution in the presence of CO{sub 2}-water fluids, which is a critical feature of the system as it allows for increased permeability during injection. Our experimental results from the first year of work have shown that the kinetics are likely to be fast enough to create dissolution which will affect permeability. However, additional experiments are needed at high pressures, which will be a focus for years 2 and 3. We are also investigating the possibility of carbon dioxide hydrate formation in the pore fluid, which might complicate the injection procedure by reducing sediment permeability but might also provide an upper seal in the sediment-pore fluid system, preventing release of CO{sub 2} into the deep ocean, particularly if depth and temperature at the injection point rule out immediate hydrate formation. Finally, we are in the beginning stages of an economic analysis to estimate costs of drilling and gas injection, site monitoring as well as the availability of potential disposal sites with particular emphasis on those sites that are within the 200-mile economic zone of the United States.

  9. Oxygen reduction by lithium on model carbon and oxidized carbon structures

    SciTech Connect (OSTI)

    Xu, Ye [ORNL; Shelton Jr, William Allison [ORNL

    2011-01-01

    Li-air batteries have attracted substantial interest for their high theoretical specific energies, but the oxygen reduction reaction by Li (Li-ORR) that occurs at the carbon cathode remains poorly understood. Periodic density functional theory calculations have been performed to examine the Li-ORR on several model carbon structures, including the graphite(0001) basal plane, the (8,0) single-wall nanotube, the armchair-type edge, and a di-vacancy in the basal plane. The inertness of the basal plane limits the reversible potential of O{sub 2} reduction to 1.1 V, and slightly higher to 1.2 V on the curved nanotube. The armchair edge and di-vacancy are highly reactive and significantly oxidized at ambient conditions to various CO{sub x} groups, which are reduced by Li via redox mechanisms at 1.2-1.4 V. These CO{sub x} groups can also catalyze O{sub 2} reduction at up to 2.3 V (an overpotential of 0.4 V vs. the calculated equilibrium potential for bulk Li{sub 2}O{sub 2} formation) by chelating and stabilizing the LiO{sub 2} intermediate. The Li-ORR on graphitic carbon, if via concerted Li{sup +}/e{sup -} transfer and involving carbon, lithium, and oxygen only, is therefore expected to initiate with the smallest overpotential at under-coordinated carbon centers that are oxidized at ambient conditions.

  10. Carbon-particle generator

    DOE Patents [OSTI]

    Hunt, A.J.

    1982-09-29

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  11. The design of a test rig for the identification of dynamic coefficients of a high temperature magnetic bearing 

    E-Print Network [OSTI]

    Rahtika, I Putu Gede Sopan

    1998-01-01

    This thesis is a report on the research and Micrographics. development to design a test rig for the identification of the dynamic coefficients of a radial magnetic bearing. The test rig development is intended for dynamic coefficient observation...

  12. A comparison of rotordynamic-coefficient predictions for annular honeycomb gas seals using different friction-factor models 

    E-Print Network [OSTI]

    D'Sousa, Rohan Joseph

    2000-01-01

    Predictions of rotordynamic-coefficients for annular honeycomb gas seals are compared using different friction-factor models. Analysis shows that the fundamental improvement in predicting the rotordynamic-coefficients ...

  13. Types of Reuse

    Broader source: Energy.gov [DOE]

    The following provides greater detail regarding the types of reuse pursued for LM sites. It should be noted that many actual reuses combine several types of the uses listed below.

  14. Friction of partially embedded vertically aligned carbon nanofibers inside elastomers

    SciTech Connect (OSTI)

    Aksak, Burak; Sitti, Metin; Cassell, Alan; Li, Jun; Meyyappan, Meyya; Callen, Phillip [NanoRobotics Laboratory, Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States); NASA Ames Research Center, Moffett Field, California 94035 (United States); NASA Johnson Space Center, Houston, Texas 77058 (United States)

    2007-08-06

    Vertically aligned carbon nanofibers partially embedded inside polyurethane (eVACNFs) are proposed as a robust high friction fibrillar material with a compliant backing. Carbon nanofibers with 50-150 nm in diameter and 20-30 {mu}m in length are vertically grown on silicon and transferred completely inside an elastomer by vacuum molding. By using time controlled and selective oxygen plasma etching, fibers are partially released up to 5 {mu}m length. Macroscale friction experiments show that eVACNFs exhibit reproducible effective friction coefficients up to 1. Besides high friction, the proposed fabrication method improves fiber-substrate bond strength, and enables uniform height nanofibers with a compliant backing.

  15. Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons

    DOE Patents [OSTI]

    Muradov, Nazim Z. (Melbourne, FL)

    2011-08-23

    A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

  16. What is carbon monoxide? Carbon monoxide (CO) is a poisonous,

    E-Print Network [OSTI]

    Johnson, Eric E.

    other material containing carbon such as gasoline, kerosene, oil, propane, coal, or wood. Forges, blast is the internal combustion engine. How does CO harm you? Carbon monoxide is harmful when breathed because

  17. Persistent local order heterogeneity in the supercritical carbon dioxide

    E-Print Network [OSTI]

    Dima Bolmatov; D. Zav'yalov; M. Gao; M. Zhernenkov

    2014-06-06

    The supercritical state is currently viewed as uniform and homogeneous on the pressure-temperature phase diagram in terms of physical properties. Here, we study structural properties of the supercritical carbon dioxide, and discover the existence of persistent medium-range order correlations which make supercritical carbon dioxide non-uniform and heterogeneous on an intermediate length scale, a result not hitherto anticipated. We report on the carbon dioxide heterogeneity shell structure where, in the first shell, both carbon and oxygen atoms experience gas-like type inter- actions with short range order correlations, while within the second shell oxygen atoms essentially exhibit liquid-like type of interactions with medium range order correlations due to localisation of transverse-like phonon packets. We show that the local order heterogeneity remains in the three phase-like equilibrium within very wide temperature range. Importantly, we highlight a catalytic role of atoms inside the nearest neighbor heterogeneity shell in providing a mechanism for diffusion in the supercritical carbon dioxide on an intermediate length scale. Finally, we discuss important implications for answering the intriguing question whether Venus may have had carbon dioxide oceans and urge for an experimental detection of this persistent local order heterogeneity.

  18. Carbon Capture and Storage

    SciTech Connect (OSTI)

    Friedmann, S

    2007-10-03

    Carbon capture and sequestration (CCS) is the long-term isolation of carbon dioxide from the atmosphere through physical, chemical, biological, or engineered processes. This includes a range of approaches including soil carbon sequestration (e.g., through no-till farming), terrestrial biomass sequestration (e.g., through planting forests), direct ocean injection of CO{sub 2} either onto the deep seafloor or into the intermediate depths, injection into deep geological formations, or even direct conversion of CO{sub 2} to carbonate minerals. Some of these approaches are considered geoengineering (see the appropriate chapter herein). All are considered in the 2005 special report by the Intergovernmental Panel on Climate Change (IPCC 2005). Of the range of options available, geological carbon sequestration (GCS) appears to be the most actionable and economic option for major greenhouse gas reduction in the next 10-30 years. The basis for this interest includes several factors: (1) The potential capacities are large based on initial estimates. Formal estimates for global storage potential vary substantially, but are likely to be between 800 and 3300 Gt of C (3000 and 10,000 Gt of CO{sub 2}), with significant capacity located reasonably near large point sources of the CO{sub 2}. (2) GCS can begin operations with demonstrated technology. Carbon dioxide has been separated from large point sources for nearly 100 years, and has been injected underground for over 30 years (below). (3) Testing of GCS at intermediate scale is feasible. In the US, Canada, and many industrial countries, large CO{sub 2} sources like power plants and refineries lie near prospective storage sites. These plants could be retrofit today and injection begun (while bearing in mind scientific uncertainties and unknowns). Indeed, some have, and three projects described here provide a great deal of information on the operational needs and field implementation of CCS. Part of this interest comes from several key documents written in the last three years that provide information on the status, economics, technology, and impact of CCS. These are cited throughout this text and identified as key references at the end of this manuscript. When coupled with improvements in energy efficiency, renewable energy supplies, and nuclear power, CCS help dramatically reduce current and future emissions (US CCTP 2005, MIT 2007). If CCS is not available as a carbon management option, it will be much more difficult and much more expensive to stabilize atmospheric CO{sub 2} emissions. Recent estimates put the cost of carbon abatement without CCS to be 30-80% higher that if CCS were to be available (Edmonds et al. 2004).

  19. Carbon | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtd Jump to: navigation, search Name: Carbon Trade LtdCarbon Jump

  20. Poloidal Density Variation of Impurities in a Rotating Tokamak Plasma ­ Flux Surface Coordinates and Effect on Transport Coefficients

    E-Print Network [OSTI]

    Poloidal Density Variation of Impurities in a Rotating Tokamak Plasma ­ Flux Surface Coordinates and Effect on Transport Coefficients

  1. Water-soluble carbon nanotube compositions for drug delivery and medicinal applications

    DOE Patents [OSTI]

    Tour, James M.; Lucente-Schultz, Rebecca; Leonard, Ashley; Kosynkin, Dmitry V.; Price, Brandi Katherine; Hudson, Jared L.; Conyers, Jr., Jodie L.; Moore, Valerie C.; Casscells, S. Ward; Myers, Jeffrey N.; Milas, Zvonimir L.; Mason, Kathy A.; Milas, Luka

    2014-07-22

    Compositions comprising a plurality of functionalized carbon nanotubes and at least one type of payload molecule are provided herein. The compositions are soluble in water and PBS in some embodiments. In certain embodiments, the payload molecules are insoluble in water. Methods are described for making the compositions and administering the compositions. An extended release formulation for paclitaxel utilizing functionalized carbon nanotubes is also described.

  2. Simulations of field emission from a semiconducting ,,10,0... carbon nanotube

    E-Print Network [OSTI]

    Mayer, Alexandre

    Simulations of field emission from a semiconducting ,,10,0... carbon nanotube A. Mayera three-dimensional simulations of field emission from an ideal open 10,0 carbon nanotube without work function around 5 eV depending on the type of nanotube. These nanotubes show interesting field-emission

  3. ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION EFFORTS

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION examines biological carbon sequestration using a grassland restoration as a model system. Chapter 1 for biological carbon sequestration. In this analysis, we found that significantly greater soil carbon

  4. Cumulative Carbon and Just Allocation of the Global Carbon Commons

    E-Print Network [OSTI]

    goal for a theory of justice: first to reduce the growth rate of global carbon dioxide emissions such activitiespersist.In thispaper the conceptis usedto addressthe question offair allocation of carbon emissions nations could continue emissions for much longer before exhausting theirfair share of the Carbon Commons

  5. Infrared Thermography applied to measurement of Heat transfer coefficient of water in a pipe heated by Joule effect

    E-Print Network [OSTI]

    Boyer, Edmond

    Infrared Thermography applied to measurement of Heat transfer coefficient of water in a pipe heated. It has been applied to measure heat transfer coefficients of water flowing in a round tube and in a multiport-flat tube. Models were developed to deduce heat transfer coefficient from wall temperature

  6. Development of carbon-metal oxide supercapacitors from sol-gel derived carbon-ruthenium xerogels

    SciTech Connect (OSTI)

    Lin, C.; Ritter, J.A.; Popov, B.N.

    1999-09-01

    There has been increasing interest in electrochemical capacitors as energy storage systems because of their high power density and long cycle life, compared to battery devices. According to the mechanism of energy storage, there are two types of electrochemical capacitors. One type is based on double layer (dl) formation due to charge separation, and the other type is based on a faradaic process due to redox reactions. Sol-gel derived high surface area carbon-ruthenium xerogels were prepared from carbonized resorcinol-formaldehyde resins containing an electrochemically active form of ruthenium oxide. The electrochemical capacitance of these materials increased with an increase in the ruthenium content indicating the presence of pseudocapacitance associated with the ruthenium oxide undergoing reversible faradaic redox reactions. A specific capacitance of 256 F/g (single electrode) was obtained from a carbon xerogel containing 14 wt% Ru, which corresponded to more than 50% utilization of the ruthenium. The double layer accounted for 40% of this capacitance. This material was also electrochemically stable, showing no change in a cyclic voltammogram for over 2,000 cycles.

  7. Future Carbon Regulations and Current Investments in Alternative Coal-Fired Power Plant Designs

    E-Print Network [OSTI]

    Sekar, Ram C.

    This paper assesses the role of uncertainty over future U.S. carbon regulations in shaping the current choice of which type of power plant to build. The pulverized coal technology (PC) still offer the lowest cost power— ...

  8. Surfactant Screening to Alter the Wettability and Aid in Acidizing Carbonate Formations 

    E-Print Network [OSTI]

    Yadhalli Shivaprasad, Arun Kumar

    2013-02-26

    Surfactant flooding in carbonate matrix acidizing treatment has been widely used for changing the wettability of the rock and to achieve low IFT values. Optimizing the type of surfactant and concentration for the specific ...

  9. Sensor applications of carbon nanotubes

    E-Print Network [OSTI]

    Rushfeldt, Scott I

    2005-01-01

    A search of published research on sensing mechanisms of carbon nanotubes was performed to identify applications in which carbon nanotubes might improve on current sensor technologies, in either offering improved performance, ...

  10. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure...

  11. Carbon nanotubes: synthesis and functionalization 

    E-Print Network [OSTI]

    Andrews, Robert

    2007-01-01

    conditions were then used as the basis of several comparative CVD experiments showing that the quality of nanotubes and the yield of carbon depended on the availability of carbon to react. The availability could be controlled by the varying concentration...

  12. Behavior of the particle transport coefficients near the density limit in MTX

    SciTech Connect (OSTI)

    Marinak, M.M.

    1993-04-01

    The perturbed particle transport coefficients were determined for a range of plasma conditions in the Alcator C tokamak, a component of the Microwave Tokamak Experiment (MTX), from analysis of density perturbations created in gas modulation experiments. Density measurements from a 15 chord far-infrared interferometer were sufficiently detailed to allow radial profiles of the transport coefficients to be resolved. Gas modulation experiments were carried out on plasmas over a range of relatively low currents and a wide variety of line-averaged densities, including values near the Greenwald density limit. With this technique the perturbed diffusion coefficient D and the perturbed convection velocity V can be determined simultaneously. Measured profiles of D rise toward the outside of the plasma column in a manner generally similar to those determined previously for {chi}{sub e,HP} from sawtooth heat pulse propagation. Values of D are typically smaller than those of {chi}{sub e,HP} given for the same line-averaged densities by a factor of 2-5. Diffusion coefficients from a series of discharges at constant current showed little variation with density through most of the saturated ohmic confinement regime. At the Greenwald density limit threshold a dramatic increase occurred in both the perturbed convective and diffusive transport coefficients in the outer region of the plasma. The increases were most pronounced at the outermost range of the radii where coefficients were determined (r/a = 0.8), but were apparent over a region which extended well into the plasma interior. Density profiles maintained a similar shape near the density limit, congruous with the similar behavior of the transport coefficients. No dramatic deterioration was evident in the global energy confinement.

  13. The Australian terrestrial carbon budget

    E-Print Network [OSTI]

    2013-01-01

    the Australian National Green- house Gas Inventory (DCCEE,fuel emissions Carbon and green house gas (GHG) accounts are

  14. Carbon cloth supported electrode

    DOE Patents [OSTI]

    Lu, Wen-Tong P. (Upper St. Clair, PA); Ammon, Robert L. (Baldwin both of, PA)

    1982-01-01

    A flow-by anode is disclosed made by preparing a liquid suspension of about to about 18% by weight solids, the solids comprising about 3.5 to about 8% of a powdered catalyst of platinum, palladium, palladium oxide, or mixtures thereof; about 60 to about 76% carbon powder (support) having a particle size less than about 20 m.mu.m and about 20 to about 33% of an inert binder having a particle size of less than about 500 m.mu.m. A sufficient amount of the suspension is poured over a carbon cloth to form a layer of solids about 0.01 to about 0.05 cm thick on the carbon cloth when the electrode is completed. A vacuum was applied to the opposite side of the carbon cloth to remove the liquid and the catalyst layer/cloth assembly is dried and compressed at about 10 to about 50 MPa's. The binder is then sintered in an inert atmosphere to complete the electrode. The electrode is used for the oxidation of sulfur dioxide in a sulfur based hybrid cycle for the decomposition of water.

  15. Carbon Footprint Calculator

    Broader source: Energy.gov [DOE]

    This calculator estimates the amount of carbon emissions you and members of your household are responsible for. It does not include emissions associated with your work or getting to work if you commute by public transportation. It was developed by IEEE Spectrum magazine.

  16. CARBON -14 PHYSICAL DATA

    E-Print Network [OSTI]

    Vallino, Joseph J.

    CARBON - 14 [14C] PHYSICAL DATA · Beta Energy: 156 keV (maximum) 49 keV (average) (100% abundance on wipes. #12;RADIATION MONITORING DOSIMETERS · Not needed (beta energy too low). · 14C Beta Dose Rate: 6) · Effective Half-Life: 40 days (unbound) · Specific Activity: 4460 mCi/gram · Maximum Beta Range in Air: 24

  17. Carbon smackdown: wind warriors

    ScienceCinema (OSTI)

    Glen Dahlbacka of the Accelerator & Fusion Research Division and Ryan Wiser of the Environmental Energy Technologies Division are the speakers.

    2010-09-01

    July 16. 2010 carbon smackdown summer lecture: learn how Berkeley Lab scientists are developing wind turbines to be used in an urban setting, as well as analyzing what it will take to increase the adoption of wind energy in the U.S.

  18. Carbon-Fuelled Future

    SciTech Connect (OSTI)

    Appel, Aaron M.

    2014-09-12

    Whether due to changes in policy or consumption of available fossil fuels, alternative sources of energy will be required, especially given the rising global energy demand. However, one of the main factors limiting the widespread utilization of renewable energy, such as wind, solar, wave or geothermal, is our ability to store energy. Storage of energy from carbon-neutral sources, such as electricity from solar or wind, can be accomplished through many routes. One approach is to store energy in the form of chemical bonds, as fuels. The conversion of low-energy compounds, such as water and carbon dioxide, to higher energy molecules, such as hydrogen or carbon-based fuels, enables the storage of carbon-neutral energy on a very large scale. The author¹s work in this area is supported by the US Department of Energy Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  19. OF CARBON FIBERS TURBINE BLADE

    E-Print Network [OSTI]

    THE USE IN WIND DESIGN: OF CARBON FIBERS TURBINE BLADE A SERI-8BLADE EXAMPLE Cheng Printed March 2000 The Use of Carbon Fibers in Wind Turbine Blade Design: a SERI-8 Blade Example Cheng represent different volumes of carbon fibers in the blade, were also studied for two design options

  20. 4, 21112145, 2007 Enhanced carbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    are generally low in productivity and carbon (C) storage. We report, however, large increases in C sequestration . Carbon sequestration following afforestation was associated with increased N use efficiency as reflected of terrestrial ecosystems that leads to increased carbon (C) sequestration. One of those means is afforestation

  1. 4, 99123, 2007 Amazon carbon

    E-Print Network [OSTI]

    Boyer, Edmond

    , suggested much larger estimates for tropical forest carbon sequestration in the Ama- zon BasinBGD 4, 99­123, 2007 Amazon carbon balanc J. Lloyd et al. Title Page Abstract Introduction Discussions is the access reviewed discussion forum of Biogeosciences An airborne regional carbon balance

  2. 3, 409447, 2006 Modeling carbon

    E-Print Network [OSTI]

    Boyer, Edmond

    not only impaired the soil fertility but also increased the amount of carbon dioxide (CO2) emitted fromBGD 3, 409­447, 2006 Modeling carbon dynamics in farmland of China F. Zhang et al. Title Page impacts of management alternatives on soil carbon storage of farmland in Northwest China F. Zhang1,3 , C

  3. Carbon Nanomaterials: The Ideal Interconnect

    E-Print Network [OSTI]

    Carbon Nanomaterials: The Ideal Interconnect Technology for Next- Generation ICs Hong Li, Chuan Xu-generation ICs. In this research, carbon nanomaterials, with their many attractive properties, are emerging-a`-vis optical and RF interconnects, and we illustrate why carbon nanomaterials constitute the ideal intercon

  4. Dispersion toughened silicon carbon ceramics

    DOE Patents [OSTI]

    Wei, G.C.

    1984-01-01

    Fracture resistant silicon carbide ceramics are provided by incorporating therein a particulate dispersoid selected from the group consisting of (a) a mixture of boron, carbon and tungsten, (b) a mixture of boron, carbon and molybdenum, (c) a mixture of boron, carbon and titanium carbide, (d) a mixture of aluminum oxide and zirconium oxide, and (e) boron nitride. 4 figures.

  5. Apparatus for producing carbon-coated nanoparticles and carbon nanospheres

    DOE Patents [OSTI]

    Perry, W. Lee; Weigle, John C.; Phillips, Jonathan

    2015-10-20

    An apparatus for producing carbon-coated nano- or micron-scale particles comprising a container for entraining particles in an aerosol gas, providing an inlet for carbon-containing gas, providing an inlet for plasma gas, a proximate torch for mixing the aerosol gas, the carbon-containing gas, and the plasma gas, bombarding the mixed gases with microwaves, and providing a collection device for gathering the resulting carbon-coated nano- or micron-scale particles. Also disclosed is a method and apparatus for making hollow carbon nano- or micro-scale spheres.

  6. Distributed Energy Resources for Carbon Emissions Mitigation

    E-Print Network [OSTI]

    Firestone, Ryan; Marnay, Chris

    2008-01-01

    Distributed Energy Resource Technology Characterizations. ”ABORATORY Distributed Energy Resources for Carbon Emissions5128 Distributed Energy Resources for Carbon Emissions

  7. Electrobiocommodities from Carbon Dioxide: Enhancing Microbial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrobiocommodities from Carbon Dioxide: Enhancing Microbial Electrosynthesis with Synthetic Electromicrobiology and System Design Electrobiocommodities from Carbon Dioxide:...

  8. Establishing MICHCARB, a geological carbon sequestration research...

    Office of Scientific and Technical Information (OSTI)

    Western Michigan University 58 GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil, gas and saline reservoirs Geological carbon...

  9. Development and Commercialization of Alternative Carbon Fiber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alternative Carbon Fiber Precursors and Conversion Technologies - Advanced Conversion Development and Commercialization of Alternative Carbon Fiber Precursors and Conversion...

  10. Manufacturing Energy and Carbon Footprint References | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    References Manufacturing Energy and Carbon Footprint References footprintreferences.pdf More Documents & Publications 2010 Manufacturing Energy and Carbon Footprints: References...

  11. TYPES OF NONIMMIGRANT VISAS Type Description

    E-Print Network [OSTI]

    for pleasure and cannot receive any type of payments. C-1*, Aliens in travel status while travelling directly through the C-2*, United States. C-3* D-1 Alien crewman on shore leave or transferring to another vessel is grounds for deportation. E-1 Aliens who conduct trade or inventories between the United States

  12. Flow Coefficient

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article) |Final ReporttheHouseNewFlippingGrossThousandperNumerical

  13. Detiding DART buoy data for real-time extraction of source coefficients for operational tsunami forecasting

    E-Print Network [OSTI]

    Percival, Donald B; Eble, Marie C; Gica, Edison; Huang, Paul Y; Mofjeld, Harold O; Spillane, Michael C; Titov, Vasily V; Tolkova, Elena I

    2014-01-01

    U.S. Tsunami Warning Centers use real-time bottom pressure (BP) data transmitted from a network of buoys deployed in the Pacific and Atlantic Oceans to tune source coefficients of tsunami forecast models. For accurate coefficients and therefore forecasts, tides at the buoys must be accounted for. In this study, five methods for coefficient estimation are compared, each of which accounts for tides differently. The first three subtract off a tidal prediction based on (1) a localized harmonic analysis involving 29 days of data immediately preceding the tsunami event, (2) 68 pre-existing harmonic constituents specific to each buoy, and (3) an empirical orthogonal function fit to the previous 25 hrs of data. Method (4) is a Kalman smoother that uses method (1) as its input. These four methods estimate source coefficients after detiding. Method (5) estimates the coefficients simultaneously with a two-component harmonic model that accounts for the tides. The five methods are evaluated using archived data from eleven...

  14. Fracture Mechanics implications for apparent static friction coefficient in contact problems involving slip-weakening laws

    E-Print Network [OSTI]

    A. Papangelo; M. Ciavarella; J. R. Barber

    2015-06-19

    We consider the effect of differing coefficients of static and dynamic friction coefficients on the behaviour of contacts involving microslip. The classic solutions of Cattaneo and Mindlin are unchanged if the transition in coefficients is abrupt, but if it occurs over some small slip distance, the solution has some mathematical similarities with those governing the normal tractions in adhesive contact problems. In particular, if the transition to dynamic slip occurs over a sufficiently small area, we can identify a `JKR' approximation, where the transition region is condensed to a line. A local singularity in shear traction is then predicted, with a stress-intensity factor that is proportional to the the square root of the local contact pressure and to a certain integral of the friction coefficient-slip distance relation. We can also define an equivalent of the `small-scale yielding' criterion, which enables us to assess when the singular solution provides a good approximation. One consequence of the results is that the static coefficient of friction determined from force measurements in experiments is significantly smaller than the value that holds at the microscale.

  15. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    SciTech Connect (OSTI)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO?- absorbing liquid solvent contained within solid, CO?-permeable, polymer shells. MECS enhance the rate of CO? absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO? pressures in stripping conditions, relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.

  16. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO?- absorbing liquid solvent contained within solid, CO?-permeable, polymer shells. MECS enhance the rate of CO? absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO? pressures in stripping conditions,more »relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.« less

  17. CALCULATING THE CARBON FOOTPRINT SUPPLY CHAIN FOR

    E-Print Network [OSTI]

    Su, Xiao

    CALCULATING THE CARBON FOOTPRINT SUPPLY CHAIN FOR THE SEMICONDUCTOR INDUSTRY By: Yasser Dessouky #12;Carbon Footprint Supply Chain Carbon Trust defines carbon footprint of a supply chain as follows: "The carbon footprint of a product is the carbon dioxide emitted across the supply chain for a single

  18. A Universal Model for Nanoporous Carbon Supercapacitors Applicable to Diverse Pore Regimes, Carbons, and Electrolyte

    SciTech Connect (OSTI)

    Sumpter, Bobby G; Huang, Jingsong; Meunier, Vincent

    2008-01-01

    Supercapacitors, commonly called electric double-layer capacitors (EDLCs), are emerging as a novel type of energy storage device with the potential to substitute batteries in applications requiring high power densities. In response to the latest experimental breakthrough in nanoporous carbon supercapacitors, we propose a heuristic theoretical model that takes pore curvature into account as a replacement for the EDLC model which is based on a traditional parallel-plate capacitor. When the pore size is in the mesopore regime (2-50 nm), counterions enter mesoporous carbons and approach the pore wall to form an electric double-cylinder capacitor (EDCC); in the micropore regime (< 2 nm), solvated/desolvated counterions line up along the pore axis to form an electric wire-in-cylinder capacitor (EWCC). In the macropore regime (> 50 nm) where pores are large enough so that the pore curvature is no longer significant, the EDCC model can be reduced naturally to the EDLC model. We present density functional theory calculations and detailed analyses of available experimental data in various pore regimes, showing the significant effects of pore curvature on the supercapacitor properties of nanoporous carbons. It is shown that the EDCC/EWCC model is universal to carbon supercapacitors with diverse carbon materials including activated carbons, template carbons, and novel carbide-derived carbons, and with diverse electrolytes including organic electrolytes such as tetraethylammonium tetrafluoroborate (TEABF4), tetraethylammonium methyl-sulfonate (TEAMS) in acetonitrile, aqueous H2SO4 and KOH electrolytes, and even ionic liquid electrolyte such as 1-ethyl-3-methylimmidazolium bis(trifluromethane-sulfonyl)imide (EMI-TFSI). The EDCC/EWCC model allows the supercapacitor properties to be correlated with pore size, specific surface area, Debye length, electrolyte concentration and dielectric constant, and solute ion size, and may lend a support for the systematic optimization of the properties of carbon supercapacitors via experiments. On the basis of the insight obtained from the new model, we also discuss the effects of the kinetic solvation/desolvation process, multimodal (versus unimodal) pore size distribution, and exohedral (versus endohedral) capacitors on the electrochemical properties of supercapacitors.

  19. Carbon Capture and Storage, 2008

    SciTech Connect (OSTI)

    2009-03-19

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  20. Carbon Capture and Storage, 2008

    ScienceCinema (OSTI)

    None

    2010-01-08

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  1. Free cooling and high-energy tails of granular gases with variable restitution coefficient

    E-Print Network [OSTI]

    Ricardo J. Alonso; Bertrand Lods

    2010-05-31

    We prove the so-called generalized Haff's law yielding the optimal algebraic cooling rate of the temperature of a granular gas described by the homogeneous Boltzmann equation for inelastic interactions with non constant restitution coefficient. Our analysis is carried through a careful study of the infinite system of moments of the solution to the Boltzmann equation for granular gases and precise Lp estimates in the selfsimilar variables. In the process, we generalize several results on the Boltzmann collision operator obtained recently for homogeneous granular gases with constant restitution coefficient to a broader class of physical restitution coefficients that depend on the collision impact velocity. This generalization leads to the so-called L1-exponential tails theorem. for this model.

  2. Dynamic measurement of heat loss coefficients through Trombe wall glazing systems

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1981-01-01

    A Trombe wall presents a unique opportunity to measure the heat-loss coefficient through the glazing system because the wall itself can be used as a heat meter. Since the instantaneous heat flux through the outer wall surface can be determined, the heat loss coefficient at night can be calculated by dividing by the wall surface-to-ambient temperature difference. This technique has been used to determine heat-loss coefficients for Los Alamos test rooms during the winter of 1980-1981. Glazing systems studied include single and double glazing both with and without night insulation used in conjunction with a flat black paint, and both single and double glazing used in conjunction with a selective surface.

  3. Drag coefficient for the air-sea exchange in hurricane conditions

    E-Print Network [OSTI]

    Golbraikh, E

    2013-01-01

    The physical model is proposed for prediction of the non-monotonic drag coefficient variation with the neutral stability 10-m wind speed, U10. The model is based upon measurements of the foam coverage fraction and characteristic size of foam bubbles with U10, and on the drag coefficient approximation by the linearly weighted averaging over alternating foam-free and foam-covered portions of the ocean surface. The obtained drag coefficient is in fair agreement with that obtained by field measurements of the vertical variation of mean wind speed in Powell et al. (Nature, 2003) which discover reduction of the sea-surface drag with U10 rising to hurricane conditions.

  4. Adsorption of selected pharmaceuticals and an endocrine disrupting compound by granular activated carbon. 1. Adsorption capacity and kinetics

    SciTech Connect (OSTI)

    Yu, Z.; Peldszus, S.; Huck, P.M. [University of Waterloo, Waterloo, ON (Canada). NSERC Chair in Water Treatment

    2009-03-01

    The adsorption of two representative PhACs (naproxen and carbamazepine) and one EDC (nonylphenol) were evaluated on two granular activated carbons (GAC) namely coal-based Calgon Filtrasorb 400 and coconut shell-based PICA CTIF TE. The primary objective was to investigate preloading effects by natural organic matter (NOM) on adsorption capacity and kinetics under conditions and concentrations (i.e., ng/L) relevant for drinking water treatment. Isotherms demonstrated that all compounds were significantly negatively impacted by NOM fouling. Adsorption capacity reduction was most severe for the acidic naproxen, followed by the neutral carbamazepine and then the more hydrophobic nonylphenol. The GAC with the wider pore size distribution had considerably greater NOM loading, resulting in lower adsorption capacity. Different patterns for the change in Freundlich KF and 1/n with time revealed different competitive mechanisms for the different compounds. Mass transport coefficients determined by short fixed-bed (SFB) tests with virgin and preloaded GAC demonstrated that film diffusion primarily controls mass transfer on virgin and preloaded carbon. Naproxen suffered the greatest deteriorative effect on kinetic parameters due to preloading, followed by carbamazepine, and then nonylphenol. A type of surface NOM/biofilm, which appeared to add an additional mass transfer resistance layer and thus reduce film diffusion, was observed. In addition, electrostatic interactions between NOM/biofilm and the investigated compounds are proposed to contribute to the reduction of film diffusion. A companion paper building on this work describes treatability studies in pilot-scale GAC adsorbers and the effectiveness of a selected fixed-bed model. 32 refs., 3 figs., 2 tabs.

  5. Observed drag coefficients in high winds in the near offshore of the South China Sea

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bi, Xueyan; Liu, Yangan; Gao, Zhiqiu; Liu, Feng; Song, Qingtao; Huang, Jian; Huang, Huijun; Mao, Weikang; Liu, Chunxia

    2015-07-14

    This paper investigates the relationships between friction velocity, 10 m drag coefficient, and 10 m wind speed using data collected at two offshore observation towers (one over the sea and the other on an island) from seven typhoon episodes in the South China Sea from 2008 to 2014. The two towers were placed in areas with different water depths along a shore-normal line. The depth of water at the tower over the sea averages about 15 m, and the depth of water near the island is about 10 m. The observed maximum 10 min average wind speed at a heightmore »of 10 m is about 32 m s?¹. Momentum fluxes derived from three methods (eddy covariance, inertial dissipation, and flux profile) are compared. The momentum fluxes derived from the flux profile method are larger (smaller) over the sea (on the island) than those from the other two methods. The relationship between the 10 m drag coefficient and the 10 m wind speed is examined by use of the data obtained by the eddy covariance method. The drag coefficient first decreases with increasing 10 m wind speed when the wind speeds are 5–10 m s?¹, then increases and reaches a peak value of 0.002 around a wind speed of 18 m s?¹. The drag coefficient decreases with increasing 10 m wind speed when 10 m wind speeds are 18–27 m s?¹. A comparison of the measurements from the two towers shows that the 10 m drag coefficient from the tower in 10 m water depth is about 40% larger than that from the tower in 15 m water depth when the 10 m wind speed is less than 10 m s?¹. Above this, the difference in the 10 m drag coefficients of the two towers disappears.« less

  6. EMPIRICAL DETERMINATION OF EINSTEIN A-COEFFICIENT RATIOS OF BRIGHT [Fe II] LINES

    SciTech Connect (OSTI)

    Giannini, T.; Antoniucci, S.; Nisini, B.; Lorenzetti, D.; Alcalá, J. M.; Bacciotti, F.; Podio, L.; Bonito, R.; Stelzer, B.

    2015-01-01

    The Einstein spontaneous rates (A-coefficients) of Fe{sup +} lines have been computed by several authors with results that differ from each other by up to 40%. Consequently, models for line emissivities suffer from uncertainties that in turn affect the determination of the physical conditions at the base of line excitation. We provide an empirical determination of the A-coefficient ratios of bright [Fe II] lines that would represent both a valid benchmark for theoretical computations and a reference for the physical interpretation of the observed lines. With the ESO-Very Large Telescope X-shooter instrument between 3000 Å and 24700 Å, we obtained a spectrum of the bright Herbig-Haro object HH 1. We detect around 100 [Fe II] lines, some of which with a signal-to-noise ratios ?100. Among these latter lines, we selected those emitted by the same level, whose dereddened intensity ratios are direct functions of the Einstein A-coefficient ratios. From the same X-shooter spectrum, we got an accurate estimate of the extinction toward HH 1 through intensity ratios of atomic species, H I  recombination lines and H{sub 2} ro-vibrational transitions. We provide seven reliable A-coefficient ratios between bright [Fe II] lines, which are compared with the literature determinations. In particular, the A-coefficient ratios involving the brightest near-infrared lines (?12570/?16440 and ?13209/?16440) are in better agreement with the predictions by the Quinet et al. relativistic Hartree-Fock model. However, none of the theoretical models predict A-coefficient ratios in agreement with all of our determinations. We also show that literature data of near-infrared intensity ratios better agree with our determinations than with theoretical expectations.

  7. Carbon Dioxide Separation from Flue Gas by Phase Enhanced Absorption

    SciTech Connect (OSTI)

    Tim Fout

    2007-06-30

    A new process, phase enhanced absorption, was invented. The method is carried out in an absorber, where a liquid carrier (aqueous solution), an organic mixture (or organic compound), and a gas mixture containing a gas to be absorbed are introduced from an inlet. Since the organic mixture is immiscible or at least partially immiscible with the liquid carrier, the organic mixture forms a layer or small parcels between the liquid carrier and the gas mixture. The organic mixture in the absorber improves mass transfer efficiency of the system and increases the absorption rate of the gas. The organic mixture serves as a transportation media. The gas is finally accumulated in the liquid carrier as in a conventional gas-liquid absorption system. The presence of the organic layer does not hinder the regeneration of the liquid carrier or recovery of the gas because the organic layer is removed by a settler after the absorption process is completed. In another aspect, the system exhibited increased gas-liquid separation efficiency, thereby reducing the costs of operation and maintenance. Our study focused on the search of the organic layer or transportation layer to enhance the absorption rate of carbon dioxide. The following systems were studied, (1) CO{sub 2}-water system and CO{sub 2}-water-organic layer system; (2) CO{sub 2}-Potassium Carbonate aqueous solution system and CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system. CO{sub 2}-water and CO{sub 2}-Potassium Carbonate systems are the traditional gas-liquid absorption processes. The CO{sub 2}-water-organic layer and CO{sub 2}-Potassium Carbonate-organic layer systems are the novel absorption processes, phase enhanced absorption. As we mentioned early, organic layer is used for the increase of absorption rate, and plays the role of transportation of CO{sub 2}. Our study showed that the absorption rate can be increased by adding the organic layer. However, the enhanced factor is highly depended on the liquid mass transfer coefficients for the CO{sub 2}-water-organic layer system. For the CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system, the enhanced factor is not only dependent on the liquid mass transfer coefficients, but also the chemical reaction rates.

  8. Image analysis measurements of particle coefficient of restitution for coal gasification applications

    SciTech Connect (OSTI)

    Gibson, LaTosha M.; Gopalan, Balaji; Pisupati, Sarma V.; Shadle, Lawrence J.

    2013-10-01

    New robust Lagrangian computational fluid dynamic (CFD) models are powerful tools that can be used to study the behavior of a diverse population of coal particle sizes, densities, and mineral compositions in entrained gasifiers. By using this approach, the responses of the particles impacting the wall were characterized over a range of velocities (1 to 8 m/s) and incident angles (90 to 20°). Within CFD models, the kinematic coefficient of restitution is the boundary condition defining the particle wall behavior. Four surfaces were studied to simulate the physical conditions of different entrained-flow gasification particle–surface collision scenarios: 1) a flat metal plate 2) a low viscosity silicon adhesive, 3) a high viscosity silicon adhesive, and 4) adhered particles on a flat metal plate with Young's modulus of elasticity ranging from 0.9 to 190 GPa. Entrained flow and drop experiments were conducted with granular coke particles, polyethylene beads and polystyrene pellets. The particle normal and tangential coefficients of restitution were measured using high speed imaging and particle tracking. The measured coefficients of restitution were observed to have a strong dependence on the rebound angles for most of the data. Suitable algebraic expressions for the normal and the tangential component of the coefficient of restitution were developed based upon ANOVA analysis. These expressions quantify the effect of normalized Young's modulus, particle equancy, and relative velocity on the coefficient of restitution. The coefficient of restitution did not have a strong dependence on the particle velocity over the range considered as long as the velocity was above the critical velocity. However, strong correlations were found between the degree of equancy of the particles and the mean coefficient of restitution such that the coefficient of restitution decreased for smaller particle equancies. It was concluded that the degree of equancy and the normalized Young's modulus should be considered in applications such as gasification and other cases involving the impact of non-spherical particles and complex surfaces. Sliding was observed when particles impacted on oblique surfaces; however, the resulting effects were within the range of measurement uncertainties.

  9. A closed formula for the barrier transmission coefficient in quaternionic quantum mechanics

    SciTech Connect (OSTI)

    De Leo, Stefano; Leonardi, Vinicius; Pereira, Kenia [Department of Applied Mathematics, State University of Campinas, SP 13083-970, Campinas (Brazil); Ducati, Gisele [CMCC, Federal University of ABC, SP 09210-170, Santo Andre (Brazil)

    2010-11-15

    In this paper, we analyze, by using a matrix approach, the dynamics of a nonrelativistic particle in presence of a quaternionic potential barrier. The matrix method used to solve the quaternionic Schroedinger equation allows us to obtain a closed formula for the transmission coefficient. Up to now, in quaternionic quantum mechanics, almost every discussion on the dynamics of nonrelativistic particle was motivated by or evolved from numerical studies. A closed formula for the transmission coefficient stimulates an analysis of qualitative differences between complex and quaternionic quantum mechanics and by using the stationary phase method, gives the possibility to discuss transmission times.

  10. Metastable Changes to the Temperature Coefficients of Thin-Film Photovoltaic Modules

    SciTech Connect (OSTI)

    Deceglie, M. G.; Silverman, T. J.; Marion, B.; Kurtz, S. R.

    2014-07-01

    Transient changes in the performance of thin-film modules with light exposure are a well-known and widely reported phenomenon. These changes are often the result of reversible metastabilities rather than irreversible changes. Here we consider how these metastable changes affect the temperature dependence of photovoltaic performance. We find that in CIGS modules exhibiting a metastable increase in performance with light exposure, the light exposure also induces an increase in the magnitude of the temperature coefficient. It is important to understand such changes when characterizing temperature coefficients and when analyzing the outdoor performance of newly installed modules.

  11. Estimation of instantaneous heat transfer coefficients for a direct-injection stratified-charge rotary engine

    SciTech Connect (OSTI)

    Lee, C.M.; Addy, H.E.; Bond, T.H.; Chun, K.S.

    1987-01-01

    The main objective of this report was to derive equations to estimate neat transfer coefficients in both the combustion chamber and coolant passage of a rotary engine. This was accomplished by making detailed temperature and pressure measurements in a direct-injection stratified-charge rotary engine under a range of conditions. For each specific measurement point, the local physical properties of the fluids were calculated. Then an empirical correlation of the coefficients was derived by using a multiple regression program. This correlation expresses the Nusselt number as a function of the Prandtl number and Reynolds number.

  12. Carbon K-edge Spectra of Carbonate Minerals

    SciTech Connect (OSTI)

    Brandes, J.; Wirick, S; Jacobsen, C

    2010-01-01

    Carbon K-edge X-ray spectroscopy has been applied to the study of a wide range of organic samples, from polymers and coals to interstellar dust particles. Identification of carbonaceous materials within these samples is accomplished by the pattern of resonances in the 280-320 eV energy region. Carbonate minerals are often encountered in the study of natural samples, and have been identified by a distinctive resonance at 290.3 eV. Here C K-edge and Ca L-edge spectra from a range of carbonate minerals are presented. Although all carbonates exhibit a sharp 290 eV resonance, both the precise position of this resonance and the positions of other resonances vary among minerals. The relative strengths of the different carbonate resonances also vary with crystal orientation to the linearly polarized X-ray beam. Intriguingly, several carbonate minerals also exhibit a strong 288.6 eV resonance, consistent with the position of a carbonyl resonance rather than carbonate. Calcite and aragonite, although indistinguishable spectrally at the C K-edge, exhibited significantly different spectra at the Ca L-edge. The distinctive spectral fingerprints of carbonates provide an identification tool, allowing for the examination of such processes as carbon sequestration in minerals, Mn substitution in marine calcium carbonates (dolomitization) and serpentinization of basalts.

  13. Neutralizing Carbonic Acid in Deep Carbonate Strata below the North Atlantic

    SciTech Connect (OSTI)

    Daniel P. Schrag

    2006-07-14

    Our research is aimed at investigating several technical issues associated with carbon dioxide sequestration in calcium carbonate sediments below the sea floor through laboratory experiments and chemical transport modeling. Our goal is to evaluate the basic feasibility of this approach, including an assessment of optimal depths, sediment types, and other issues related to site selection. The results of our modeling efforts were published this past summer in the Proceedings of the National Academy of Sciences. We are expanding on that work through a variety of laboratory and modeling efforts. In the laboratories at Columbia and at Harvard, we are studying the flow of liquid carbon dioxide and carbon dioxide-water mixtures through calcium carbonate sediments to better understand the geomechanical and structural stability of the sediments during and after injection. We are currently preparing the results of these findings for publication. In addition, we are investigating the kinetics of calcium carbonate dissolution in the presence of CO{sub 2}-water fluids, which is a critical feature of the system as it allows for increased permeability during injection. We are also investigating the possibility of carbon dioxide hydrate formation in the pore fluid, which might complicate the injection procedure by reducing sediment permeability but might also provide an upper seal in the sediment-pore fluid system, preventing release of CO{sub 2} into the deep ocean, particularly if depth and temperature at the injection point rule out immediate hydrate formation. This is done by injecting liquid CO{sub 2} into various types of porous media, and then monitoring the changes in permeability. Finally, we are performing an economic analysis to estimate costs of drilling and gas injection, site monitoring as well as the availability of potential disposal sites with particular emphasis on those sites that are within the 200-mile economic zone of the United States. We present some preliminary results from these analyses. A paper discussing the site selection based on data from the Ocean Drilling Program and Deep Sea Drilling Program is currently in preparation.

  14. Carbon Fiber Technology Facility

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels| Departmentof Energy CaliforniaContentsForumCarbon Fiber

  15. JV Task 90 - Activated Carbon Production from North Dakota Lignite

    SciTech Connect (OSTI)

    Steven Benson; Charlene Crocker; Rokan Zaman; Mark Musich; Edwin Olson

    2008-03-31

    The Energy & Environmental Research Center (EERC) has pursued a research program for producing activated carbon from North Dakota lignite that can be competitive with commercial-grade activated carbon. As part of this effort, small-scale production of activated carbon was produced from Fort Union lignite. A conceptual design of a commercial activated carbon production plant was drawn, and a market assessment was performed to determine likely revenue streams for the produced carbon. Activated carbon was produced from lignite coal in both laboratory-scale fixed-bed reactors and in a small pilot-scale rotary kiln. The EERC was successfully able to upgrade the laboratory-scale activated carbon production system to a pilot-scale rotary kiln system. The activated carbon produced from North Dakota lignite was superior to commercial grade DARCO{reg_sign} FGD and Rheinbraun's HOK activated coke product with respect to iodine number. The iodine number of North Dakota lignite-derived activated carbon was between 600 and 800 mg I{sub 2}/g, whereas the iodine number of DARCO FGD was between 500 and 600 mg I{sub 2}/g, and the iodine number of Rheinbraun's HOK activated coke product was around 275 mg I{sub 2}/g. The EERC performed both bench-scale and pilot-scale mercury capture tests using the activated carbon made under various optimization process conditions. For comparison, the mercury capture capability of commercial DARCO FGD was also tested. The lab-scale apparatus is a thin fixed-bed mercury-screening system, which has been used by the EERC for many mercury capture screen tests. The pilot-scale systems included two combustion units, both equipped with an electrostatic precipitator (ESP). Activated carbons were also tested in a slipstream baghouse at a Texas power plant. The results indicated that the activated carbon produced from North Dakota lignite coal is capable of removing mercury from flue gas. The tests showed that activated carbon with the greatest iodine number was superior to commercial DARCO FGD for mercury capture. The results of the activated carbon market assessment indicate an existing market for water treatment and an emerging application for mercury control. That market will involve both existing and new coal-fired plants. It is expected that 20% of the existing coal-fired plants will implement activated carbon injection by 2015, representing about 200,000 tons of annual demand. The potential annual demand by new plants is even greater. In the mercury control market, two characteristics are going to dominate the customer's buying habit-performance and price. As continued demonstration testing of activated carbon injection at the various coal-fired power plants progresses, the importance of fuel type and plant configuration on the type of activated carbon best suited is being identified.

  16. n-Type diamond and method for producing same

    DOE Patents [OSTI]

    Anderson, Richard J. (Oakland, CA)

    2002-01-01

    A new n-type semiconducting diamond is disclosed, which is doped with n-type dopant atoms. Such diamond is advantageously formed by chemical vapor deposition from a source gas mixture comprising a carbon source compound for the diamond, and a volatile hot wire filament for the n-type impurity species, so that the n-type impurity atoms are doped in the diamond during its formation. A corresponding chemical vapor deposition method of forming the n-type semiconducting diamond is disclosed. The n-type semiconducting diamond of the invention may be usefully employed in the formation of diamond-based transistor devices comprising pn diamond junctions, and in other microelectronic device applications.

  17. Nucleosynthesis in Type Ia Supernovae

    E-Print Network [OSTI]

    K. Nomoto; K. Iwamoto; N. Nakasato; F. -K. Thielemann; F. Brachwitz; T. Tsujimoto; Y. Kubo; N. Kishimoto

    1997-06-03

    Among the major uncertainties involved in the Chandrasekhar mass models for Type Ia supernovae are the companion star of the accreting white dwarf (or the accretion rate that determines the carbon ignition density) and the flame speed after ignition. We present nucleosynthesis results from relatively slow deflagration (1.5 - 3 % of the sound speed) to constrain the rate of accretion from the companion star. Because of electron capture, a significant amount of neutron-rich species such as ^{54}Cr, ^{50}Ti, ^{58}Fe, ^{62}Ni, etc. are synthesized in the central region. To avoid the too large ratios of ^{54}Cr/^{56}Fe and ^{50}Ti/^{56}Fe, the central density of the white dwarf at thermonuclear runaway must be as low as \\ltsim 2 \\e9 \\gmc. Such a low central density can be realized by the accretion as fast as $\\dot M \\gtsim 1 \\times 10^{-7} M_\\odot yr^{-1}$. These rapidly accreting white dwarfs might correspond to the super-soft X-ray sources.

  18. Typed Self-Optimization

    E-Print Network [OSTI]

    Brown, Matt

    2013-01-01

    type T y[O]. The operator IsIs is self-applicative, in thatargument t is any of Is[O] or IsIs, and otherwise behavesproof constant introduced by IsIs proves that the type of t

  19. Deactivation by carbon of iron catalysts for indirect liquefaction

    SciTech Connect (OSTI)

    Bartholomew, C.H.

    1991-01-10

    Although promoted cobalt and iron catalysts for Fischer-Tropsch (FT) synthesis of gasoline feedstock were first developed more than three decades ago, a major technical problem still limiting the commercial use of these catalysts today is carbon deactivation. This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for FT synthesis, the objectives of which are to: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; and model the rates of deactivation of the same catalysts in fixed-bed reactors. To accomplish the above objectives, the project is divided into the following tasks: (1) determine the kinetics of reaction and of carbon deactivation during CO hydrogenation on Fe and Fe/K catalysts coated on monolith bodies. (2) Determine the reactivities and types of carbon deposited during reaction on the same catalysts from temperature-programmed-surface-reaction spectroscopy (TPSR) and transmission electron microscopy (TEM). Determine the types of iron carbides formed at various temperatures and H{sub 2}/CO ratios using x-ray diffraction and Moessbauer spectroscopy. (3) Develop mathematical deactivation models which include heat and mass transport contributions for FT synthesis is packed-bed reactors. Progress to date is described. 48 refs., 3 figs., 1 tab.

  20. Carbon Capital: The Political Ecology of Carbon Forestry and Development in Chiapas, Mexico

    E-Print Network [OSTI]

    Osborne, Tracey Muttoo

    2010-01-01

    B v + B d ) C T = Total carbon B v = biomass contained indevelopment through carbon sequestration: experiences in2000) Rural livelihoods and carbon management, IIED Natural

  1. Varying-Coefficient Functional Linear Yichao Wu , Jianqing Fan and Hans-Georg Muller

    E-Print Network [OSTI]

    Müller, Hans-Georg

    Varying-Coefficient Functional Linear Regression Yichao Wu , Jianqing Fan and Hans-Georg M¨uller NCSU, Princeton University, and UC-Davis Abstract: Functional linear regression analysis aims to model arguments of the regression parameter function. This extension of the functional linear regression model

  2. Linear response time-dependent density functional theory for van der Waals coefficients

    E-Print Network [OSTI]

    Chu, Xi

    Linear response time-dependent density functional theory for van der Waals coefficients X. Chu Received 9 January 2004; accepted 15 June 2004 A linear response time-dependent density functional theory description of the linear response function and of the induced self- consistent field, which adequately

  3. Hydrodynamics and transport coefficients for dilute granular gases Nikolai Brilliantov1,2

    E-Print Network [OSTI]

    of engineering and soil mechanics e.g., Refs. 1,2 a first-principles theory for dense granular media is still observa- tions e.g., Refs. 14­16 nor with basic mechanics of par- ticle collisions 17 . The coefficient

  4. Thermoelectric measurement equipments This instrument is designed for simultaneous measurement of Seebeck coefficient and

    E-Print Network [OSTI]

    Taya, Minoru

    measurement of Seebeck coefficient and electric conductivity for the evaluation of thermoelectric electromotive force. · Employment of an infrared gold image heating furnace that excels in temperature.1 msec/0.3 msec or less Sensor Thermocouple Thermocouple, IR detector Measurement Thermal diffusivity

  5. 1D Regression ... estimates of the linear regression coefficients are relevant to the linear

    E-Print Network [OSTI]

    Olive, David

    Chapter 12 1D Regression ... estimates of the linear regression coefficients are relevant and look for a functional form for g(·). Brillinger (1983, p. 98) Regression is the study. The scalar Y is a random variable and x is a random vector. A special case of regression is multiple linear

  6. 1D Regression ... estimates of the linear regression coefficients are relevant to the linear

    E-Print Network [OSTI]

    Olive, David

    Chapter 15 1D Regression ... estimates of the linear regression coefficients are relevant and look for a functional form for g(·). Brillinger (1983, p. 98) Regression is the study. The scalar Y is a random variable and x is a random vector. A special case of regression is multiple linear

  7. Water diffusion coefficients during copper electropolishing and IAN IVAR SUNI2*

    E-Print Network [OSTI]

    Suni, Ian Ivar

    Water diffusion coefficients during copper electropolishing BING DU1 and IAN IVAR SUNI2* 1, including several with ethanol and other species added as diluents. Diluents allow a wider range of water in the mass transfer limited regime are shown to depend on both the number of water acceptor molecules

  8. ATMOSPHERIC DISPERSION COEFFICIENTS AND RADIOLOGICAL AND TOXICOLOGICAL EXPOSURE METHODOLOGY FOR USE IN TANK FARMS

    SciTech Connect (OSTI)

    GRIGSBY KM

    2011-04-07

    This report presents the atmospheric dispersion coefficients used in Tank Farms safety analysis. The basis equations for calculating radiological and toxicological exposures are also included. In this revision, the time averaging for toxicological consequence evaluations is clarified based on a review of DOE complex guidance and a review of tank farm chemicals.

  9. Assessment of Random-noise Contamination in Digital Images via Testing on Wavelet Coefficients

    E-Print Network [OSTI]

    Maldonado, Diego

    Assessment of Random-noise Contamination in Digital Images via Testing on Wavelet Coefficients for different images contaminated with the same source of random noise. In this article, we propose a new full (WNPSSIM), specifically designed to detect visual similarity between images contaminated with all sorts

  10. An analytic approximation to the Diffusion Coefficient for the periodic Lorentz Gas

    E-Print Network [OSTI]

    C. Angstmann; G. P. Morriss

    2012-02-14

    An approximate stochastic model for the topological dynamics of the periodic triangular Lorentz gas is constructed. The model, together with an extremum principle, is used to find a closed form approximation to the diffusion coefficient as a function of the lattice spacing. This approximation is superior to the popular Machta and Zwanzig result and agrees well with a range of numerical estimates.

  11. Dissociation and excitation coefficients of nitrogen molecules and nitrogen monoxide generation

    SciTech Connect (OSTI)

    Uhm, Han S.; Na, Young H.; Choi, Eun H.; Cho, Guangsup [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)] [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)

    2013-08-15

    The excitation coefficient ?{sub N2} is calculated for the excited metastable level of N{sub 2}(A{sub 3}?{sub u}{sup +}) in nitrogen molecules. In addition, the dissociation coefficient of nitrogen molecules is investigated by making use of the Boltzmann distribution of the electrons in atmospheric plasmas. The excitation and electron-impact dissociation coefficients of nitrogen molecules are analytically expressed in terms of the electron temperature T{sub e} for evaluations of the reactive oxygen and nitrogen species in atmospheric plasmas. As an application example of these coefficients, the nitrogen monoxide generation through a microwave torch is carried out for a development of medical tool. The nitrogen monoxide concentration from a microwave plasma-torch can be easily controlled by the nitrogen flow rate, mole fraction of the oxygen gas, and the microwave power. A simple analytic expression of the nitrogen monoxide concentration is obtained in terms of the oxygen molecular density and gas flow rate. The experimental data agree remarkably well with the theoretical results from the analytical expression. A microwave nitrogen-torch can easily provide an appropriate nitrogen monoxide concentration for the wound healings.

  12. Multitap Microwave Photonic Filter With Negative Coefficients Based on the Inherent

    E-Print Network [OSTI]

    Yao, Jianping

    Multitap Microwave Photonic Filter With Negative Coefficients Based on the Inherent Birefringence, IEEE DOI: 10.1109/JPHOT.2013.2265981 1943-0655/$31.00 Ó2013 IEEE #12;Multitap Microwave Photonic Filter 2 Microwave Photonics Research Laboratory, School of Electrical Engineering and Computer Science

  13. Self-Diffusion Coefficients of Methane or Ethane Mixtures with Hydrocarbons at High Pressure by NMR

    E-Print Network [OSTI]

    Dysthe, Dag Kristian

    Self-Diffusion Coefficients of Methane or Ethane Mixtures with Hydrocarbons at High Pressure by NMR in homogeneous mixtures of methane + hexane, ethane + hexane, methane + octane, ethane + octan, methane + decane, ethane + decane, and methane + hexane + benzene over the whole concentration range, at 303.2 K and 333

  14. Reduction operators and exact solutions of variable coefficient nonlinear wave equations with power nonlinearities

    E-Print Network [OSTI]

    Ding-jiang Huang; Qin-min Yang; Shui-geng Zhou

    2013-12-18

    Reduction operators, i.e. the operators of nonclassical (or conditional) symmetry of a class of variable coefficient nonlinear wave equations with power nonlinearities is investigated within the framework of singular reduction operator. A classification of regular reduction operators is performedwith respect to generalized extended equivalence groups. Exact solutions of some nonlinear wave model which are invariant under certain reduction operators are also constructed.

  15. Dispersion of passive tracers in closed basins: Beyond the diffusion coefficient

    E-Print Network [OSTI]

    Cencini, Massimo

    Dispersion of passive tracers in closed basins: Beyond the diffusion coefficient V. Artale ENEA, 00185 Roma, Italy Received 25 April 1997; accepted 10 July 1997 We investigate the spreading of passive of diffusion and transport of passive tracers in a given velocity field has both theoretical and prac- tical

  16. Diffuse attenuation coefficient of downwelling irradiance: An evaluation of remote sensing methods

    E-Print Network [OSTI]

    Lee, Zhongping

    Diffuse attenuation coefficient of downwelling irradiance: An evaluation of remote sensing methods February 2005. [1] The propagation of downwelling irradiance at wavelength l from surface to a depth (z in situ measurements of the vertical profiles of downwelling irradiance. The comparisons show that the two

  17. Grad's moment method for a granular fluid at moderate densities. Navier-Stokes transport coefficients

    E-Print Network [OSTI]

    Vicente Garzó

    2013-03-18

    The Navier-Stokes transport coefficients of a granular dense fluid of smooth inelastic hard disks or spheres are explicitly determined by solving the inelastic Enskog equation by means of Grad's moment method. The transport coefficients are explicitly determined as functions of the (constant) coefficient of restitution and the solid volume fraction. In addition, the cooling rate is also calculated to first order in the spatial gradients. The calculations are performed for an arbitrary number of dimensions. The results are not limited to small dissipation and are expected to apply at moderate densities. It is found that the expressions of the Navier-Stokes transport coefficients and the cooling rate agree with those previously obtained from the Chapman-Enskog method by using the leading terms in a Sonine polynomial expansion. This shows the equivalence between both methods for granular fluids in the Navier-Stokes approximation. A comparison with previous results derived from Grad's moment method for inelastic disks and spheres is also carried out.

  18. Fluid dynamical equations and transport coefficients of relativistic gases with non-extensive statistics

    E-Print Network [OSTI]

    T. S. Biro; E. Molnar

    2012-01-28

    We derive equations for fluid dynamics from a non-extensive Boltzmann transport equation consistent with Tsallis' non-extensive entropy formula. We evaluate transport coefficients employing the relaxation time approximation and investigate non-extensive effects in leading order dissipative phenomena at relativistic energies, like heat conductivity, shear and bulk viscosity.

  19. Absorbed dose in target cell nuclei and dose conversion coefficient of radon progeny

    E-Print Network [OSTI]

    Yu, Peter K.N.

    Absorbed dose in target cell nuclei and dose conversion coefficient of radon progeny in the human Abstract To calculate the absorbed dose in the human lung due to inhaled radon progeny, ICRP focussed and secretory cells). The absorbed energy for alpha particles emitted by radon progeny in the human respiratory

  20. Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs

    E-Print Network [OSTI]

    George, Steven C.

    Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs PETER CONDORELLI, is produced within the tissue of the airways of the lungs.16 As an intercellular messenger, NO is involved is available regarding the basic gas exchange dynamics of NO in the lungs. Ingested ethanol EtOH is transported

  1. Determination of mass and thermal accommodation coefficients from evolution of evaporating water droplet

    E-Print Network [OSTI]

    droplet M. Zientara, D. Jakubczyk, G. Derkachov, K. Kolwas and M. Kolwas Institute of Physics, Polish of evaporation and condensation are in the very heart of various fields of science. Cloud and aerosol called evaporation (condensation) or mass accommodation coefficient C and thermal conductivity

  2. Multivariate $p$-adic formal congruences and integrality of Taylor coefficients of mirror maps

    E-Print Network [OSTI]

    Christian Krattenthaler; Tanguy Rivoal

    2010-04-12

    We generalise Dwork's theory of $p$-adic formal congruences from the univariate to a multi-variate setting. We apply our results to prove integrality assertions on the Taylor coefficients of (multi-variable) mirror maps. More precisely, with $\\mathbf z=(z_1,z_2,...,z_d)$, we show that the Taylor coefficients of the multi-variable series $q(\\mathbf z)=z_i\\exp(G(\\mathbf z)/F(\\mathbf z))$ are integers, where $F(\\mathbf z)$ and $G(\\mathbf z)+\\log(z_i) F(\\mathbf z)$, $i=1,2,...,d$, are specific solutions of certain GKZ systems. This result implies the integrality of the Taylor coefficients of numerous families of multi-variable mirror maps of Calabi-Yau complete intersections in weighted projective spaces, as well as of many one-variable mirror maps in the "Tables of Calabi-Yau equations" [arXiv:math/0507430] of Almkvist, van Enckevort, van Straten and Zudilin. In particular, our results prove a conjecture of Batyrev and van Straten in [Comm. Math. Phys. 168 (1995), 493-533] on the integrality of the Taylor coefficients of canonical coordinates for a large family of such coordinates in several variables.

  3. Ultrasonic backscatter coefficient quantitative estimates from Chinese hamster ovary cell pellet biophantoms

    E-Print Network [OSTI]

    Illinois at Urbana-Champaign, University of

    Ultrasonic backscatter coefficient quantitative estimates from Chinese hamster ovary cell pellet August 2010; accepted 6 August 2010 A cell pellet biophantom technique is introduced, and applied verification purposes. BSC estimates from CHO cell pellet biophantoms of known number density were performed

  4. Frequency [Hz] Transmission Coefficient Amplitude h=0.001 m h ...

    E-Print Network [OSTI]

    10. 0. 10. 1. 10. 2. 10. 3. 10. 4. 10. 5. 10. 6. 0.1. 0.2. 0.3. 0.4. 0.5. 0.6. 0.7. 0.8. 0.9. 1. Frequency [Hz]. Transmission Coefficient Amplitude. Thin layer. Nakagawa ...

  5. Internal conversion coefficients in (134)Cs, (137)Ba, and (139)La: A precise test of theory 

    E-Print Network [OSTI]

    Nica, N.; Hardy, John C.; Iacob, V. E.; Balonek, C.; Trzhaskovskaya, M. B.

    2008-01-01

    Recently we measured the ratio of K-shell internal conversion coefficients, alpha(K), for the 127.5-keV E3 transition in (134)Cs and the 661.7-keV M4 transition in (137)Ba. We here report a measurement of the 165.9-keV M1 transition in (139)La...

  6. Automatic detection of atrial fibrillation using the coefficient of variation and

    E-Print Network [OSTI]

    Glass, Leon

    f Automatic detection of atrial fibrillation using the coefficient of variation and density, Quebec, Canada \\ Abstract--The paper describes a method for the automatic detection of atria, as P-waves are difficult to determine automatically, and irregular baseline activity of the ECG

  7. Specular Highlight Detection Based on the Fresnel Reflection Coefficient Elli Angelopoulou

    E-Print Network [OSTI]

    Angelopoulou, Elli

    Specular Highlight Detection Based on the Fresnel Reflection Coefficient Elli Angelopoulou a new, physics-based specularity detection method, which de- pends on the Fresnel term of the specular to the Fresnel term at various wave- lengths. We then use mean-shift analysis to segment the im- age based

  8. Relaxation Time Constants and Apparent Diffusion Coefficients of Rat Retina at 7 Tesla

    E-Print Network [OSTI]

    Duong, Timothy Q.

    Relaxation Time Constants and Apparent Diffusion Coefficients of Rat Retina at 7 Tesla Govind Nair* and ADC of the rat eyes were measured at 50 3 50 3 800 lm at 7 Tesla. Profiles of T1, T2, T2* and ADC

  9. Asymptotic symmetries at null infinity and local conformal properties of spin coefficients

    E-Print Network [OSTI]

    Glenn Barnich; Pierre-Henry Lambert

    2013-01-24

    We show that the symmetry algebra of asymptotically flat four dimensional spacetimes at null infinity in the sense of Newman and Unti is isomorphic to the direct sum of the abelian algebra of infinitesimal conformal rescalings with bms4. We then work out the local conformal properties of the relevant Newman-Penrose coefficients, as well as the surface charges and their algebra.

  10. Estimating ProteinLigand Binding Free Energy: Atomic Solvation Parameters for Partition Coefficient and

    E-Print Network [OSTI]

    Luhua, Lai

    Estimating Protein­Ligand Binding Free Energy: Atomic Solvation Parameters for Partition Coefficient and Solvation Free Energy Calculation Jianfeng Pei,1,2 Qi Wang,1,2 Jiaju Zhou,3 and Luhua Lai1 free energy and the correct scoring in docking studies. We have developed a new solvation energy

  11. A NUMERICAL METHOD FOR SOLVING VARIABLE COEFFICIENT ELLIPTIC EQUATION WITH INTERFACES

    E-Print Network [OSTI]

    Ferguson, Thomas S.

    A NUMERICAL METHOD FOR SOLVING VARIABLE COEFFICIENT ELLIPTIC EQUATION WITH INTERFACES SONGMING HOU coeÃ?cient elliptic equation in the presence of interfaces where the variable coeÃ?cients, the source at interface are prescribed. The boundary and the interface are only required to be Lipschitz continuous

  12. Improved granular activated carbon for the stabilization of wastewater PH

    SciTech Connect (OSTI)

    Farmer, R.W.; Dussert, B.W.; Kovacic, S.L. [Calgon Carbon Corp., Pittsburgh, PA (United States)

    1996-12-31

    Laboratory studies have identified the cause of the pH rise, which occurs during water treatment with activated carbon, as an interaction between the naturally occurring anions and protons in the water and the carbon surface. The interaction can be described as an ion exchange type of phenomenon, in which the carbon surface sorbs the anions and corresponding hydronium ions from the water. These studies have shown that the anion sorption and resulting pH increase is independent of the raw material used for the activated carbon production, e.g. bituminous or subbituminous coal, peat, wood or coconut. Also, the pH excursions occur with virgin, reactivated, and acid washed granular carbons. Current pH control technologies focus on adjustment of the wastewater pH prior to discharge or recycle of the initial effluent water until the pH increase abates. However, improved water pH control options have been realized by altering the carbon surface through controlled oxidation rather than the water chemistry or extended preprocessing at the treatment site.

  13. FIELD-SCALE EFFECTIVE MATRIX DIFFUSION COEFFICIENT FOR FRACTURED ROCK:RESULTS FROM LITERATURE SURVEY

    SciTech Connect (OSTI)

    Q. Zhou; Hui-Hai Liu; F.J. Molz; Y. Zhang; G.S. Bodvarsson

    2005-04-08

    Matrix diffusion is an important mechanism for solute transport in fractured rock. We recently conducted a literature survey on the effective matrix diffusion coefficient, D{sub m}{sup e}, a key parameter for describing matrix diffusion processes at the field scale. Forty field tracer tests at 15 fractured geologic sites were surveyed and selected for the study, based on data availability and quality. Field-scale D{sub m}{sup e} values were calculated, either directly using data reported in the literature or by reanalyzing the corresponding field tracer tests. Surveyed data indicate that the effective-matrix-diffusion-coefficient factor F{sub D} (defined as the ratio of D{sub m}{sup e} to the lab-scale matrix diffusion coefficient [D{sub m}] of the same tracer) is generally larger than one, indicating that the effective matrix diffusion coefficient in the field is comparatively larger than the matrix diffusion coefficient at the rock-core scale. This larger value can be attributed to the many mass-transfer processes at different scales in naturally heterogeneous, fractured rock systems. Furthermore, we observed a moderate trend toward systematic increase in the F{sub D} value with observation scale, indicating that the effective matrix diffusion coefficient is likely to be statistically scale dependent. The F{sub D} value ranges from 1 to 10,000 for observation scales from 5 to 2,000 m. At a given scale, the F{sub D} value varies by two orders of magnitude, reflecting the influence of differing degrees of fractured rock heterogeneity at different sites. In addition, the surveyed data indicate that field-scale longitudinal dispersivity generally increases with observation scale, which is consistent with previous studies. The scale-dependent field-scale matrix diffusion coefficient (and dispersivity) may have significant implications for assessing long-term, large-scale radionuclide and contaminant transport events in fractured rock, both for nuclear waste disposal and contaminant remediation.

  14. TESTING GUIDELINES FOR TECHNETIUM-99 ABSORPTION ON ACTIVATED CARBON

    SciTech Connect (OSTI)

    BYRNES ME

    2010-09-08

    CH2M HILL Plateau Remediation Company (CHPRC) is currently evaluating the potential use of activated carbon adsorption for removing technetium-99 from groundwater as a treatment method for the Hanford Site's 200 West Area groundwater pump-and-treat system. The current pump-and-treat system design will include an ion-exchange (IX) system for selective removal of technetium-99 from selected wells prior to subsequent treatment of the water in the central treatment system. The IX resin selected for technetium-99 removal is Purolite A530E. The resin service life is estimated to be approximately 66.85 days at the design technetium-99 loading rate, and the spent resin must be replaced because it cannot be regenerated. The resulting operating costs associated with resin replacement every 66.85 days are estimated at $0.98 million/year. Activated carbon pre-treatment is being evaluated as a potential cost-saving measure to offset the high operating costs associated with frequent IX resin replacement. This document is preceded by the Literature Survey of Technetium-99 Groundwater Pre-Treatment Option Using Granular Activated Carbon (SGW-43928), which identified and evaluated prior research related to technetium-99 adsorption on activated carbon. The survey also evaluated potential operating considerations for this treatment approach for the 200 West Area. The preliminary conclusions of the literature survey are as follows: (1) Activated carbon can be used to selectively remove technetium-99 from contaminated groundwater. (2) Technetium-99 adsorption onto activated carbon is expected to vary significantly based on carbon types and operating conditions. For the treatment approach to be viable at the Hanford Site, activated carbon must be capable of achieving a designated minimum technetium-99 uptake. (3) Certain radionuclides known to be present in 200 West Area groundwater are also likely to adsorb onto activated carbon. (4) Organic solvent contaminants of concern (COCs) will load heavily onto activated carbon and should be removed from groundwater upstream of the activated carbon pre-treatment system. Unless removed upstream, the adsorbed loadings of these organic constituents could exceed the land disposal criteria for carbon.

  15. Method for joining carbon-carbon composites to metals

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Moorhead, A.J.

    1997-07-15

    A method for joining carbon-carbon composites to metals by brazing. Conventional brazing of recently developed carbon-bonded carbon fiber (CBCF) material to a metal substrate is limited by the tendency of the braze alloy to ``wick`` into the CBCF composite rather than to form a strong bond. The surface of the CBCF composite that is to be bonded is first sealed with a fairly dense carbonaceous layer achieved by any of several methods. The sealed surface is then brazed to the metal substrate by vacuum brazing with a Ti-Cu-Be alloy. 1 fig.

  16. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01

    in the life-cycle assessment (LCA) and carbon footprintingto integrate the economics- and LCA-based perspectives onto life-cycle assessment (LCA). The existing literature on

  17. Geologic Carbon Sequestration and Biosequestration (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    DePaolo, Don [Director, LBNL Earth Sciences Division

    2011-06-08

    Don DePaolo, Director of LBNL's Earth Sciences Division, speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  18. Field-Scale Effective Matrix Diffusion Coefficient for FracturedRock: Results From Literature Survey

    SciTech Connect (OSTI)

    Zhou, Quanlin; Liu, Hui Hai; Molz, Fred J.; Zhang, Yingqi; Bodvarsson, Gudmundur S.

    2005-03-28

    Matrix diffusion is an important mechanism for solutetransport in fractured rock. We recently conducted a literature survey onthe effective matrix diffusion coefficient, Dem, a key parameter fordescribing matrix diffusion processes at the field scale. Forty fieldtracer tests at 15 fractured geologic sites were surveyed and selectedfor study, based on data availability and quality. Field-scale Dem valueswere calculated, either directly using data reported in the literature orby reanalyzing the corresponding field tracer tests. Surveyed dataindicate that the effective-matrix-diffusion-coefficient factor FD(defined as the ratio of Dem to the lab-scale matrix diffusioncoefficient [Dem]of the same tracer) is generally larger than one,indicating that the effective matrix diffusion coefficient in the fieldis comparatively larger than the matrix diffusion coefficient at therock-core scale. This larger value could be attributed to the manymass-transfer processes at different scales in naturally heterogeneous,fractured rock systems. Furthermore, we observed a moderate trend towardsystematic increase in the emDFmDDF value with observation scale,indicating that the effective matrix diffusion coefficient is likely tobe statistically scale dependent. The FD value ranges from 1 to 10,000for observation scales from 5 to 2,000 m. At a given scale, the FD valuevaries by two orders of magnitude, reflecting the influence of differingdegrees of fractured rock heterogeneity at different sites. In addition,the surveyed data indicate that field-scale longitudinal dispersivitygenerally increases with observation scale, which is consistent withprevious studies. The scale-dependent field-scale matrix diffusioncoefficient (and dispersivity) may have significant implications forassessing long-term, large-scale radionuclide and contaminant transportevents in fractured rock, both for nuclear waste disposal and contaminantremediation.

  19. Quasi-steady carbon plasma source for neutral beam injector

    SciTech Connect (OSTI)

    Koguchi, H. Sakakita, H.; Kiyama, S.; Shimada, T.; Sato, Y.; Hirano, Y.

    2014-02-15

    Carbon plasma is successfully sustained during 1000 s without any carrier gas in the bucket type ionization chamber with cusp magnetic field. Every several seconds, seed plasmas having ?3 ms duration time are injected into the ionization chamber by a shunting arch plasma gun. The weakly ionized carbon plasma ejected from the shunting arch is also ionized by 2.45 GHz microwave at the electron cyclotron resonance surface and the plasma can be sustained even in the interval of gun discharges. Control of the gun discharge interval allows to keep high pressure and to sustain the plasma for long duration.

  20. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    Area Southeast  Regional  Carbon  Sequestration  PartnershipCoast  Regional  Carbon  Sequestration  Partnership Water  West  Coast  Regional  Carbon  Sequestration  Partnership  (

  1. Risk assessment framework for geologic carbon sequestration sites

    E-Print Network [OSTI]

    Oldenburg, C.

    2010-01-01

    carbon sequestration risk assessment, in Carbon Dioxidecarbon sequestration risk assessment, Energy Procedia,Risk Assessment Framework for Geologic Carbon Sequestration

  2. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    for  Geologic  Carbon  Sequestration. ”   International  of  Energy.  “Carbon  Sequestration  Atlas  of  the  Water  Extracted  from  Carbon  Sequestration  Projects."  

  3. The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries

    SciTech Connect (OSTI)

    Bhadra, S; Hertzberg, BJ; Hsieh, AG; Croft, M; Gallaway, JW; Van Tassell, BJ; Chamoun, M; Erdonmez, C; Zhong, Z; Sholklapper, T; Steingart, DA

    2015-01-01

    The coefficient of restitution of alkaline batteries has been shown to increase as a function of depth of discharge. In this work, using non-destructive mechanical testing, the change in coefficient of restitution is compared to in situ energy-dispersive X-ray diffraction data to determine the cause of the macroscopic change in coefficient of restitution. The increase in coefficient of restitution correlates to the formation of a percolation pathway of ZnO within the anode of the cell, and the coefficient of restitution levels off at a value of 0.66 +/- 0.02 at 50% state of charge when the anode has densified into porous ZnO solid. Of note is the sensitivity of coefficient of restitution to the amount of ZnO formation that rivals the sensitivity of in situ energy-dispersive X-ray diffraction.

  4. Hybrid type checking

    E-Print Network [OSTI]

    Flanagan, C

    2006-01-01

    O’Callahan and J. -D. Choi. Hybrid dynamic data race detec-subtyping is sound, the hybrid compilation algorithmHybrid Type Checking Cormac Flanagan Department of Computer

  5. Fejer-type inequalities

    E-Print Network [OSTI]

    Mitroi, F C

    2011-01-01

    The aim of this paper is to present some new Fejer-type results for convex functions. Improvements of Young's inequality (the arithmetic-geometric mean inequality) and other applications to special means are pointed as well.

  6. Effect of Nanoporosity on the Thermal Conductivity of Amorphous Carbon

    E-Print Network [OSTI]

    Fujii, Amanda

    2014-01-01

    Carbon aerogels . . . . . . . . . . . . . . .carbon thin films [6, 7, 15, 16] and carbon aerogels [10,law relations for carbon aerogels are also included [10,

  7. Carbon Sequestration Advisory Committee (Nebraska)

    Broader source: Energy.gov [DOE]

    Under this statute, the Director of Natural Resources will document and quantify carbon sequestration and greenhouse emissions reductions associated with agricultural practices, management systems,...

  8. Manufacturing Energy and Carbon Footprint

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Export 113 Combustion Emissions (MMT CO 2 e Million Metric Tons Carbon Dioxide Equivalent) Total Emissions Offsite Emissions + Onsite Emissions Energy (TBtu ...

  9. Carbon-assisted flyer plates

    SciTech Connect (OSTI)

    Stahl, David B.; Paisley, Dennis L.

    1994-01-01

    A laser driven flyer plate utilizing an optical fiber connected to a laser. The end of the optical fiber has a layer of carbon and a metal layer deposited onto it. The carbon layer provides the laser induced plasma which is superior to the plasma produced from most metals. The carbon layer plasma is capable of providing a flatter flyer plate, converting more of the laser energy to driving plasma, promoting a higher flyer plate acceleration, and providing a more uniform pulse behind the plate. In another embodiment, the laser is in optical communication with a substrate onto which a layer of carbon and a layer of metal have been deposited.

  10. Soil metagenomics and carbon cycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stands to improve climate modeling Environmental microbiology In 2009, the Department of Energy established the Los Alamos Science Focus Area in Soil Metagenomics & Carbon Cycling...

  11. Carbon Sequestration Atlas IV Video

    ScienceCinema (OSTI)

    Rodosta, Traci

    2014-06-27

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  12. Carbon Sequestration Atlas IV Video

    SciTech Connect (OSTI)

    Rodosta, Traci

    2013-04-19

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  13. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, Rafael A. (Chicago, IL); Hrdina, Kenneth E. (Glenview, IL); Remick, Robert J. (Bolingbrook, IL)

    1993-01-01

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process for production of the lithium ferrite containing anode by slipcasting.

  14. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, R.A.; Hrdina, K.E.; Remick, R.J.

    1993-04-27

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

  15. Global carbon budget 2014

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Le Quéré, C.; Moriarty, R.; Andrew, R. M.; Peters, G. P.; Ciais, P.; Friedlingstein, P.; Jones, S. D.; Sitch, S.; Tans, P.; Arneth, A.; et al

    2015-05-08

    Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates, consistency within and among components, alongside methodology and data limitations. CO2 emissionsmore »from fossil fuel combustion and cement production (EFF) are based on energy statistics and cement production data, respectively, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover-change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models forced by observed climate, CO2, and land-cover-change (some including nitrogen–carbon interactions). We compare the mean land and ocean fluxes and their variability to estimates from three atmospheric inverse methods for three broad latitude bands. All uncertainties are reported as ±1?;, reflecting the current capacity to characterise the annual estimates of each component of the global carbon budget. For the last decade available (2004–2013), EFF was 8.9 ± 0.4 GtC yr?¹,ELUC 0.9 ± 0.5 GtC yr?¹, GATM 4.3 ± 0.1 GtC yr?¹, SOCEAN 2.6 ± 0.5 GtC yr?¹, and SLAND 2.9 ± 0.8 GtC yr?¹. For year 2013 alone, EFF grew to 9.9 ± 0.5 GtC yr?¹, 2.3% above 2012, continuing the growth trend in these emissions, ELUC was 0.9 ± 0.5 GtC yr?¹, GATM was 5.4 ± 0.2 GtC yr?¹, SOCEAN was 2.9 ± 0.5 GtC yr?¹, and SLAND was 2.5 ± 0.9 GtC yr?¹. GATM was high in 2013, reflecting a steady increase in EFF and smaller and opposite changes between SOCEAN and SLAND compared to the past decade (2004–2013). The global atmospheric CO2 concentration reached 395.31 ± 0.10 ppm averaged over 2013. We estimate that EFF will increase by 2.5% (1.3–3.5%) to 10.1 ± 0.6 GtC in 2014 (37.0 ± 2.2 GtCO2 yr?¹), 65% above emissions in 1990, based on projections of world gross domestic product and recent changes in the carbon intensity of the global economy. From this projection of EFF and assumed constant ELUC for 2014, cumulative emissions of CO2 will reach about 545 ± 55 GtC (2000 ± 200 GtCO2) for 1870–2014, about 75% from EFF and 25% from ELUC. This paper documents changes in the methods and data sets used in this new carbon budget compared with previous publications of this living data set (Le Quéré et al., 2013, 2014). All observations presented here can be downloaded from the Carbon Dioxide Information Analysis Center (doi:10.3334/CDIAC/GCP_2014).« less

  16. Carbon Capture FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports from thecarbon capture faqs faq-header-big.jpg CARBON

  17. Carbon Storage Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports from thecarbon captureCarbon Storage AtlasStorage

  18. ARM - Carbon Cycle Balance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments? We would love to hear from you! Send us agovInstrumentswrf-chem Comments? We wouldCampaign JournalCarbon

  19. University of Aberdeen Carbon Management Plan

    E-Print Network [OSTI]

    Levi, Ran

    of Aberdeen is committed to reducing its carbon footprint and to playing its part in limiting the worstUniversity of Aberdeen Carbon Management Plan Higher Education Carbon Management Programme working with Page 1 The University of Aberdeen Carbon Management Programme Carbon Management Plan (CMP

  20. University of Dundee Carbon Management Plan

    E-Print Network [OSTI]

    Davidson, Fordyce A.

    Carbon Management Strategy 2.1 Our low carbon vision 6 2.2 Context and drivers for Carbon Management 6 2 and sources of funding 18 6 Actions to Embed Carbon Management in Your Organisation 19 6.1 Corporate Strategy Appendix A: Carbon Management Matrix - Embedding 23 Appendix B: Energy Prices 24 #12;3 FOREWORD FROM

  1. Carbon Management Plan 1. Executive summary 5

    E-Print Network [OSTI]

    Haase, Markus

    Carbon Management Plan June 2011 #12;2 #12;3 CONTENTS 1. Executive summary 5 2. Introduction 15 3. Background and context 16 4. Carbon management strategy 18 5. Carbon emissions baseline and projections 22 6. Past actions and achievements 30 7. Carbon Management Plan implementation 33 8. Carbon Management Plan

  2. Understanding Carbon Sequestration Options in the United States: Capabilities of a Carbon Management Geographic Information System

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Dooley, James J.; Brown, Daryl R.; Mizoguchi, Akiyoshi; Shiozaki, Mai

    2001-04-03

    While one can discuss various sequestration options at a national or global level, the actual carbon management approach is highly site specific. In response to the need for a better understanding of carbon management options, Battelle in collaboration with Mitsubishi Corporation, has developed a state-of-the-art Geographic Information System (GIS) focused on carbon capture and sequestration opportunities in the United States. The GIS system contains information (e.g., fuel type, location, vintage, ownership, rated capacity) on all fossil-fired generation capacity in the Untied States with a rated capacity of at least 100 MW. There are also data on other CO2 sources (i.e., natural domes, gas processing plants, etc.) and associated pipelines currently serving enhanced oil recovery (EOR) projects. Data on current and prospective CO2 EOR projects include location, operator, reservoir and oil characteristics, production, and CO2 source. The system also contains information on priority deep saline aquifers and coal bed methane basins with potential for sequestering CO2. The GIS application not only enables data storage, flexible map making, and visualization capabilities, but also facilitates the spatial analyses required to solve complex linking of CO2 sources with appropriate and cost-effective sinks. A variety of screening criteria (spatial, geophysical, and economic) can be employed to identify sources and sinks most likely amenable to deployment of carbon capture and sequestration systems. The system is easily updateable, allowing it to stay on the leading edge of capture and sequestration technology as well as the ever-changing business landscape. Our paper and presentation will describe the development of this GIS and demonstrate its uses for carbon management analysis.

  3. Laboratory-scale sodium-carbonate aggregate concrete interactions. [LMFBR

    SciTech Connect (OSTI)

    Westrich, H.R.; Stockman, H.W.; Suo-Anttila, A.

    1983-09-01

    A series of laboratory-scale experiments was made at 600/sup 0/C to identify the important heat-producing chemical reactions between sodium and carbonate aggregate concretes. Reactions between sodium and carbonate aggregate were found to be responsible for the bulk of heat production in sodium-concrete tests. Exothermic reactions were initiated at 580+-30/sup 0/C for limestone and dolostone aggregates as well as for hydrated limestone concrete, and at 540+-10/sup 0/C for dehydrated limestone concrete, but were ill-defined for dolostone concrete. Major reaction products included CaO, MgO, Na/sub 2/CO/sub 3/, Na/sub 2/O, NaOH, and elemental carbon. Sodium hydroxide, which forms when water is released from cement phases, causes slow erosion of the concrete with little heat production. The time-temperature profiles of these experiments have been modeled with a simplified version of the SLAM computer code, which has allowed derivation of chemical reaction rate coefficients.

  4. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide

    Broader source: Energy.gov [DOE]

    Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock interactions.

  5. Carbon Mineralization and Labile Organic Carbon Pools in the Sandy

    E-Print Network [OSTI]

    Grunwald, Sabine

    Carbon Mineralization and Labile Organic Carbon Pools in the Sandy Soils of a North Florida mineralization were best explained by TOC (62%) and hot-water- extractable C (59%), whereas acid-hydrolyzable C mineralization and clay content were directly linearly correlated, indicating a possible stimulatory effect

  6. Carbonation of Clay Minerals Exposed to scCO2/Water at 200 degrees and 250 degrees C

    SciTech Connect (OSTI)

    Sugama, T.; Ecker, L.; Gill, S.; Butcher, T. (BNL); Bour, D. (AltaRock Energy, Inc.)

    2010-11-01

    To clarify the mechanisms of carbonation of clay minerals, such as bentonite, kaolinite, and soft clay, we exposed them to supercritical carbon dioxide (scCO2)/water at temperatures of 200 and 250 C and pressures of 1500 and 2000 psi for 72- and 107-hours. Bentonite, comprising three crystalline phases, montmorillonite (MMT), anorthoclase-type albite, and quartz was susceptible to reactions with ionic carbonic acid yielded by the interactions between scCO2 and water, particularly MMT and anorthoclase-type albite phases. For MMT, the cation-exchangeable ions, such as Na+ and Ca2+, present in its basal interplanar space, were replaced by proton, H+, from ionic carbonic acid; thereafter, the cations leaching from MMT directly reacted with CO32- as a counter ion of H+ to form carbonate compounds. Such in-situ carbonation process in basal space caused the shrinkage and breakage of the spacing structure within MMT. In contrast, the wet carbonation of anorthoclase-type albite, categorized as rock minerals, entailed the formation of three amorphous by-products, such as carbonates, kaolinite-like compounds, and silicon dioxide. Together, these two different carbonations caused the disintegration and corruption of bentonite. Kaolinite clay containing the amorphous carbonates and silicon dioxide was inert to wet carbonation. We noted only a gain in weight due to its water uptake, suggesting that kaolinite-like by-products generated by the wet carbonation of rock minerals might remain unchanged even during extended exposure. Soft clay consisting of two crystalline phases, dolomite and silicon dioxide, also was unaltered by wet carbonation, despite the uptake of water.

  7. Carbon dioxide and climate

    SciTech Connect (OSTI)

    Not Available

    1990-10-01

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  8. Intermediate Temperature Carbon - Carbon Composite Structures. CRADA Final Report

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar [ORNL

    2007-06-01

    The objective of this Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC (the "Contractor") and Synterials, Inc. (the "Participant") was to demonstrate promising processing methods, which can lead to producing Carbon-Carbon Composites (CCC), with tensile and interlaminar properties comparable to those of organic matrix composites and environmental stability at 1200 F for long periods of time. The participant synthesized carbon-carbon composites with two different fiber coatings and three different matrices. Both parties evaluated the tensile and interlaminar properties of these materials and characterized the microstructure of the matrices and interfaces. It was found that fiber coatings of carbon and boron carbide provided the best environmental protection and resulted in composites with high tensile strength.

  9. Clinical output factors for carbon-ion beams passing through polyethylene

    E-Print Network [OSTI]

    Kanematsu, Nobuyuki; Ogata, Risa; Himukai, Takeshi

    2013-01-01

    Purpose: A recent study suggested that polyethylene (PE) range compensators would cause extra carbon-ion attenuation by 0.45%/cm due to limitations in water equivalence. The present study aims to assess its influence on tumor dose in carbon-ion radiotherapy. Methods: Carbon-ion radiation was modeled to be composed of primary carbon ions and secondary particles. For these components, tumor dose fraction and relative biological effectiveness (RBE) were estimated at a reference depth in the middle of spread-out Bragg peak. The PE effect was estimated for clinical carbon-ion beams and was partially tested by experiment. The two-component model was integrated into a treatment-planning system, with which the PE effect on tumor dose was investigated in two clinical cases. Results: The fluence and clinical attenuation coefficients for dose decrease per polyethylene thickness were estimated to be 0.1%-0.3%/cm and 0.2%-0.4%/cm, depending on energy and modulation of clinical carbon-ion beams. In the treatment-planning s...

  10. Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao

    E-Print Network [OSTI]

    Barthelat, Francois

    Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao promising carbon uptake results and is a viable option for carbonation curing. Carbon sequestration increase in Carbon dioxide (CO2) emissions over the past five decades, specific ways to reduce

  11. Field tests of carbon monitoring methods in forestry projects

    SciTech Connect (OSTI)

    NONE

    1999-07-01

    In response to the emerging scientific consensus on the facts of global climate change, the international Joint Implementation (JI) program provided a pilot phase in which utilities and other industries could finance, among other activities, international efforts to sequester carbon dioxide, a major greenhouse gas. To make JI and its successor mechanisms workable, however, cost-effective methods are needed for monitoring progress in the reduction of greenhouse gas emissions. The papers in this volume describe field test experiences with methods for measuring carbon storage by three types of land use: natural forest, plantation forest, and agroforestry. Each test, in a slightly different land-use situation, contributes to the knowledge of carbon-monitoring methods as experienced in the field. The field tests of the agroforestry guidelines in Guatemala and the Philippines, for example, suggested adaptations in terms of plot size and method of delineating the total area for sampling.

  12. Quasiparticle Theory of Transport Coefficients for Hadronic Matter at Finite Temperature and Baryon Density

    E-Print Network [OSTI]

    M. Albright; J. I. Kapusta

    2015-08-11

    We develop a flexible quasiparticle theory of transport coefficients of hot hadronic matter at finite baryon density. We begin with a hadronic quasiparticle model which includes a scalar and a vector mean field. Quasiparticle energies and the mean fields depend on temperature and baryon chemical potential. Starting with the quasiparticle dispersion relation, we derive the Boltzmann equation and use the Chapman-Enskog expansion to derive formulas for the shear and bulk viscosities and thermal conductivity. We obtain both relaxation time approximation formulas and more general integral equations. Throughout the work, we explicitly enforce the Landau-Lifshitz conditions of fit and ensure the theory is thermodynamically self-consistent. The derived formulas should be useful for predicting the transport coefficients of the hadronic phase of matter produced in heavy-ion collisions at the Relativistic Heavy Ion Collider (RHIC) and at other accelerators.

  13. The Osmotic Coefficient of Rod-like Polyelectrolytes: Computer Simulation, Analytical Theory, and Experiment

    E-Print Network [OSTI]

    M. Deserno; C. Holm; J. Blaul; M. Ballauff; M. Rehahn

    2001-05-09

    The osmotic coefficient of solutions of rod-like polyelectrolytes is considered by comparing current theoretical treatments and simulations to recent experimental data. The discussion is restricted to the case of monovalent counterions and dilute, salt-free solutions. The classical Poisson-Boltzmann solution of the cell model correctly predicts a strong decrease in the osmotic coefficient, but upon closer look systematically overestimates its value. The contribution of ion-ion-correlations are quantitatively studied by MD simulations and the recently proposed DHHC theory. However, our comparison with experimental data obtained on synthetic, stiff-chain polyelectrolytes shows that correlation effects can only partly explain the discrepancy. A quantitative understanding thus requires theoretical efforts beyond the restricted primitive model of electrolytes.

  14. Three-body interactions in complex fluids: Virial coefficients from simulation finite-size effects

    SciTech Connect (OSTI)

    Ashton, Douglas J.; Wilding, Nigel B.

    2014-06-28

    A simulation technique is described for quantifying the contribution of three-body interactions to the thermodynamical properties of coarse-grained representations of complex fluids. The method is based on a new approach for determining virial coefficients from the measured volume-dependent asymptote of a certain structural function. By comparing the third virial coefficient B{sub 3} for a complex fluid with that of an approximate coarse-grained model described by a pair potential, three body effects can be quantified. The strategy is applicable to both Molecular Dynamics and Monte Carlo simulation. Its utility is illustrated via measurements of three-body effects in models of star polymers and in highly size-asymmetrical colloid-polymer mixtures.

  15. Equilibrium calculation of transport coefficients for a fluid-particle model

    E-Print Network [OSTI]

    Thomas Ihle; Erkan Tuzel; Daniel M. Kroll

    2005-09-26

    A recently introduced particle-based model for fluid flow, called Stochastic Rotation Dynamics, can be made Galilean invariant by introducing a random shift of the computational grid before collisions. In this paper, it is shown how the Green-Kubo relations derived previously can be resummed to obtain exact expressions for the collisional contributions to the transport coefficients. It is also shown that the collisional contribution to the microscopic stress tensor is not symmetric, and that this leads to an additional viscosity. The resulting identification of the transport coefficients for the hydrodynamic modes is discussed in detail, and it is shown that this does not impose restrictions on the applicability of the model. The collisional contribution to the thermal conductivity, which becomes important for small mean free path and small average particle number per cell, is also derived.

  16. On a regularization of a scalar conservation law with discontinuous coefficients

    SciTech Connect (OSTI)

    Shen, Chun

    2014-03-15

    This paper is devoted to a scalar conservation law with a linear flux function involving discontinuous coefficients. It is clear that the delta standing wave should be introduced into the Riemann solution in some nonclassical situation. In order to study the formation of delta standing wave, we consider a regularization of the discontinuous coefficient with the Helmholtz mollifier and then obtain a regularized system which depends on a regularization parameter ? > 0. The regularization mechanism is a nonlinear bending of characteristic curves that prevents their finite-time intersection. It is proved rigorously that the solutions of regularized system converge to the delta standing wave solution in the ? ? 0 limit. Compared with the classical method of vanishing viscosity, here it is clear to see how the delta standing wave forms naturally along the characteristics.

  17. Soil organic carbon and nutrient content in aggregate-size fractions of a subtropical rice soil under variable tillage

    E-Print Network [OSTI]

    Florida, University of

    Soil organic carbon and nutrient content in aggregate-size fractions of a subtropical rice soil The effects of tillage on soil organic carbon (SOC) and nutrient content of soil aggregates can vary spatially and temporally, and for different soil types and cropping systems. We assessed SOC and nutrient levels within

  18. A synthesis of carbon in international trade

    E-Print Network [OSTI]

    Peters, G. P; Davis, S. J; Andrew, R.

    2012-01-01

    and Peters, G. P. : Carbon Footprint of Nations: A Global,analysis for na- tional carbon footprint accounting, Eco.study of the UK’s carbon footprint, Eco. Syst. Res. , 22,

  19. EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    carbon-intensive fossil fuel, increased by 4.8 percent. 2.8. Carbon dioxide emissions and carbon sequestration from nonfuel uses of energy inputs Nonfuel uses of fossil fuels (for...

  20. Who Pays a Price on Carbon?

    E-Print Network [OSTI]

    Grainger, Corbett A.; Kolstad, Charles D.

    2010-01-01

    on a per-capita basis a carbon price is much more regressiveadverse distributional effects of a carbon emissions policy.Distributional incidence · Carbon tax · Tradable permits Q52