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Sample records for tx mn wi

  1. Alternating magnetic anisotropy of Li2(Li1xTx)N(T=Mn,Fe,Co,andNi)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.moreAs a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.less

  2. Alternating magnetic anisotropy of Li2(Li1–xTx)N (T = Mn, Fe, Co, and Ni)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1–xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane→easy axis→easy plane→easy axis when progressing from T = Mn → Fe → Co → Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.more » As a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.« less

  3. WI Windinvest | Open Energy Information

    Open Energy Info (EERE)

    WI Windinvest Jump to: navigation, search Name: WI Windinvest Place: Westfalen, Germany Zip: 48727 Sector: Wind energy Product: Westfalen based wind project developer Coordinates:...

  4. EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX February 18, 2009 EIS-0412: ...

  5. US WSC TX Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    WSC TX Site Consumption million Btu $0 $500 $1,000 $1,500 $2,000 $2,500 US WSC TX Expenditures dollars ALL ENERGY average per household (excl. transportation) 0 4,000 8,000 12,000 16,000 US WSC TX Site Consumption kilowatthours $0 $500 $1,000 $1,500 $2,000 US WSC TX Expenditures dollars ELECTRICITY ONLY average per household * Texas households consume an average of 77 million Btu per year, about 14% less than the U.S. average. * Average electricity consumption per Texas home is 26% higher than

  6. D&TX

    Office of Legacy Management (LM)

    *. ( ARGONNE RATIONAL 1-Ci3ORATORY . 1 D&TX 7. my 19, 1349 70 t. Z. ROse at L, Em &=i*p~~4 DVur;uM hLl%L ?bvs -Lcs . FReti c. c. Fqpr an2 2. E. sulu+rr fis2 S*crep t & fbQ s-e: of the ?atagel DrFAm%un !! 1 0 * the >rt &Fz=z d t& &men of ScieJce & >&7*-z 4-q 2s'; %rZion 0C the ZLLS~~~ of Science a2 31~52-37 fo2 T&imcyyg c.=A+=< he-< - ,,a uas c:cgetes ALL 12, 1SL9. Z 0 sor;~~,-~-lioi! c.jme s 'm&-go& ~WC& c ",& d*cg&A

  7. US ENC WI Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    120 US ENC WI Site Consumption million Btu $0 $500 $1,000 $1,500 $2,000 $2,500 US ENC WI Expenditures dollars ALL ENERGY average per household (excl. transportation) 0 2,000 4,000 6,000 8,000 10,000 12,000 US ENC WI Site Consumption kilowatthours $0 $300 $600 $900 $1,200 $1,500 US ENC WI Expenditures dollars ELECTRICITY ONLY average per household * Wisconsin households use 103 million Btu of energy per home, 15% more than the U.S. average. * Lower electricity and natural gas rates compared to

  8. CleanTX Foundation | Open Energy Information

    Open Energy Info (EERE)

    is a stub. You can help OpenEI by expanding it. CleanTX Foundation is a policy organization located in Austin, Texas. References About CleanTX Foundation Retrieved from...

  9. EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont,

    Energy Savers [EERE]

    TX | Department of Energy 2: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX February 18, 2009 EIS-0412: Notice of Intent to Prepare an Environmental Impact Statement Construction of the TX Energy, LLC, Industrial Gasification Facility near Beaumont, Texas

  10. Penitas, TX Natural Gas Pipeline Imports From Mexico (Dollars...

    U.S. Energy Information Administration (EIA) Indexed Site

    Penitas, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand Cubic Feet) Penitas, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand Cubic Feet) Decade ...

  11. Alamo, TX Natural Gas Pipeline Imports From Mexico (Dollars per...

    U.S. Energy Information Administration (EIA) Indexed Site

    Alamo, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand Cubic Feet) Alamo, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand Cubic Feet) Decade ...

  12. EDF Industrial Power Services (TX), LLC | Open Energy Information

    Open Energy Info (EERE)

    EDF Industrial Power Services (TX), LLC Jump to: navigation, search Name: EDF Industrial Power Services (TX), LLC Place: Texas Phone Number: 877-432-4530 Website:...

  13. TX-100 manufacturing final project report.

    SciTech Connect (OSTI)

    Ashwill, Thomas D.; Berry, Derek S.

    2007-11-01

    This report details the work completed under the TX-100 blade manufacturing portion of the Carbon-Hybrid Blade Developments: Standard and Twist-Coupled Prototype project. The TX-100 blade is a 9 meter prototype blade designed with bend-twist coupling to augment the mitigation of peak loads during normal turbine operation. This structural coupling was achieved by locating off axis carbon fiber in the outboard portion of the blade skins. The report will present the tooling selection, blade production, blade instrumentation, blade shipping and adapter plate design and fabrication. The baseline blade used for this project was the ERS-100 (Revision D) wind turbine blade. The molds used for the production of the TX-100 were originally built for the production of the CX-100 blade. The same high pressure and low pressure skin molds were used to manufacture the TX-100 skins. In order to compensate for the difference in skin thickness between the CX-100 and the TX-100, however, a new TX-100 shear web plug and mold were required. Both the blade assembly fixture and the root stud insertion fixture used for the CX-100 blades could be utilized for the TX-100 blades. A production run of seven TX-100 prototype blades was undertaken at TPI Composites during the month of October, 2004. Of those seven blades, four were instrumented with strain gauges before final assembly. After production at the TPI Composites facility in Rhode Island, the blades were shipped to various test sites: two blades to the National Wind Technology Center at the National Renewable Energy Laboratory in Boulder, Colorado, two blades to Sandia National Laboratory in Albuquerque, New Mexico and three blades to the United States Department of Agriculture turbine field test facility in Bushland, Texas. An adapter plate was designed to allow the TX-100 blades to be installed on existing Micon 65/13M turbines at the USDA site. The conclusion of this program is the kick-off of the TX-100 blade testing at the three testing facilities.

  14. DOE - Office of Legacy Management -- Milwaukee Airport - WI 04

    Office of Legacy Management (LM)

    Milwaukee Airport - WI 04 FUSRAP Considered Sites Site: MILWAUKEE AIRPORT (WI.04 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate...

  15. ARM - Field Campaign - TX-2002 AIRS Validation Campaign

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsTX-2002 AIRS Validation Campaign Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : TX-2002 AIRS Validation...

  16. RAPID/Roadmap/6-TX-b | Open Energy Information

    Open Energy Info (EERE)

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Construction Storm Water Permit (6-TX-b) The Texas...

  17. RAPID/Roadmap/19-TX-a | Open Energy Information

    Open Energy Info (EERE)

    Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Water Access and Water Rights Overview (19-TX-a) In the late 1960's Texas...

  18. RAPID/Roadmap/14-TX-d | Open Energy Information

    Open Energy Info (EERE)

    Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us 401 Water Quality Certification (14-TX-d) Section 401 of the Clean Water Act (CWA)...

  19. RAPID/Roadmap/11-TX-b | Open Energy Information

    Open Energy Info (EERE)

    Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Human Remains Process (11-TX-b) This flowchart illustrates the procedure a...

  20. RAPID/Roadmap/11-TX-a | Open Energy Information

    Open Energy Info (EERE)

    thumbnail: Page number not in range. Flowchart Narrative 11-TX-a.1 - Have Potential Human Remains Been Discovered? If the developer discovers potential human remains during any...

  1. RAPID/Roadmap/3-TX-i | Open Energy Information

    Open Energy Info (EERE)

    construction plans on the leased asset; Permission for the representatives of TxDOT to enter the area for inspection, maintenance, or reconstruction of highway facilities as...

  2. RAPID/Roadmap/15-TX-a | Open Energy Information

    Open Energy Info (EERE)

    BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Air Quality Permit - Permit to Construct (15-TX-a) This flowchart illustrates the general...

  3. RAPID/Roadmap/11-TX-c | Open Energy Information

    Open Energy Info (EERE)

    11-TX-c.2 - Does the Project Area Contain a Recorded Archaeological Site? However, oil, gas, or other mineral exploration, production, processing, marketing, refining, or...

  4. ,"Alamo, TX Natural Gas Pipeline Imports From Mexico (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Alamo, TX Natural Gas Pipeline Imports From Mexico (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data...

  5. RAPID/Roadmap/6-TX-a | Open Energy Information

    Open Energy Info (EERE)

    must obtain the proper oversizeoverweight permit from the Texas Department of Motor Vehicles (TxDMV). 06TXAExtraLegalVehiclePermittingProcess.pdf Error creating...

  6. Hanford Single Shell Tank Leak Causes and Locations - 241-TX Farm

    SciTech Connect (OSTI)

    Girardot, C. L.; Harlow, D> G.

    2014-07-22

    This document identifies 241-TX Tank Farm (TX Farm) leak causes and locations for the 100 series leaking tanks (241-TX-107 and 241-TX-114) identified in RPP-RPT-50870, Rev. 0, Hanford 241-TX Farm Leak Inventory Assessment Report. This document satisfies the TX Farm portion of the target (T04) in the Hanford Federal Facility Agreement and Consent Order milestone M-045-91F.

  7. Penitas, TX Natural Gas Pipeline Exports to Mexico (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) Penitas, TX Natural Gas Pipeline Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 252 1,324 824 1,017 871 770 ...

  8. Freeport, TX Liquefied Natural Gas Exports to Mexico (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Mexico (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 2,725 - No Data ...

  9. Eagle Pass, TX Natural Gas Pipeline Exports to Mexico (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) Eagle Pass, TX Natural Gas Pipeline Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 159 155 151 135 135 127 118 ...

  10. Galvan Ranch, TX Natural Gas Pipeline Imports From Mexico (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) Galvan Ranch, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 12 40 77 59 55 47 43 41 ...

  11. Laredo, TX Liquefied Natural Gas Exports to Mexico (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) Laredo, TX Liquefied Natural Gas Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 0.512 0.497 2016 2.732 - No ...

  12. Freeport, TX Liquefied Natural Gas Exports to South Korea (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    South Korea (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Exports to South Korea (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 3,157 ...

  13. Price Liquefied Freeport, TX Natural Gas Exports Price to Japan...

    U.S. Energy Information Administration (EIA) Indexed Site

    Japan (Dollars per Thousand Cubic Feet) Price Liquefied Freeport, TX Natural Gas Exports Price to Japan (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  14. TxDOT Access Management Manual | Open Energy Information

    Open Energy Info (EERE)

    Access Management Manual Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: TxDOT Access Management ManualLegal Abstract Manual prepared...

  15. RAPID/Roadmap/12-TX-a | Open Energy Information

    Open Energy Info (EERE)

    Contribute Contact Us State Biological Resource Considerations (12-TX-a) In Texas, no person may capture, trap, take, or kill, or attempt to capture, trap, take, or kill,...

  16. RAPID/Roadmap/19-TX-e | Open Energy Information

    Open Energy Info (EERE)

    will not interfere with other water rights. 19-TX-e Temporary Surface Water Permit.pdf Error creating thumbnail: Page number not in range. Error creating thumbnail: Page number...

  17. RAPID/Roadmap/3-TX-e | Open Energy Information

    Open Energy Info (EERE)

    the leasing process. 03-TX-e - Lease of Texas Parks & Wildlife Department Land (1).pdf Error creating thumbnail: Page number not in range. Error creating thumbnail: Page number...

  18. RAPID/Roadmap/19-TX-b | Open Energy Information

    Open Energy Info (EERE)

    19-TX-b.6 - Does the Developer Own the Overlying Land? In Texas, the right to acquire and pump ground water is tied to the ownership of the land overlying the groundwater aquifer....

  19. Alamo, TX Natural Gas Pipeline Exports to Mexico (Million Cubic...

    Gasoline and Diesel Fuel Update (EIA)

    individual company data. Release Date: 09302015 Next Release Date: 10302015 Referring Pages: U.S. Natural Gas Pipeline Exports by Point of Exit Alamo, TX Natural Gas Exports to...

  20. McAllen, TX Natural Gas Pipeline Imports From Mexico (Dollars...

    U.S. Energy Information Administration (EIA) Indexed Site

    McAllen, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand Cubic Feet) McAllen, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand Cubic Feet) Decade ...

  1. File:03-TX-g - Lease of Relinquishment Act Lands.pdf | Open Energy...

    Open Energy Info (EERE)

    TX-g - Lease of Relinquishment Act Lands.pdf Jump to: navigation, search File File history File usage Metadata File:03-TX-g - Lease of Relinquishment Act Lands.pdf Size of this...

  2. File:03-TX-f - Lease of Land Trade Lands.pdf | Open Energy Information

    Open Energy Info (EERE)

    TX-f - Lease of Land Trade Lands.pdf Jump to: navigation, search File File history File usage Metadata File:03-TX-f - Lease of Land Trade Lands.pdf Size of this preview: 463 599...

  3. Price of San Elizario, TX Natural Gas Pipeline Exports to Mexico...

    Gasoline and Diesel Fuel Update (EIA)

    Price of San Elizario, TX Natural Gas Pipeline Exports to Mexico (Dollars per Thousand Cubic Feet) Price of San Elizario, TX Natural Gas Pipeline Exports to Mexico (Dollars per...

  4. File:03-TX-e - Lease of Texas Parks & Wildlife Department Land...

    Open Energy Info (EERE)

    3-TX-e - Lease of Texas Parks & Wildlife Department Land (1).pdf Jump to: navigation, search File File history File usage Metadata File:03-TX-e - Lease of Texas Parks & Wildlife...

  5. WI Biodiesel Blending Progream Final Report

    SciTech Connect (OSTI)

    Redmond, Maria E; Levy, Megan M

    2013-04-01

    The Wisconsin State Energy Office?¢????s (SEO) primary mission is to implement cost?¢???effective, reliable, balanced, and environmentally?¢???friendly clean energy projects. To support this mission the Wisconsin Biodiesel Blending Program was created to financially support the installation infrastructure necessary to directly sustain biodiesel blending and distribution at petroleum terminal facilities throughout Wisconsin. The SEO secured a federal directed award of $600,000 over 2.25 years. With these funds, the SEO supported the construction of inline biodiesel blending facilities at two petroleum terminals in Wisconsin. The Federal funding provided through the state provided a little less than half of the necessary investment to construct the terminals, with the balance put forth by the partners. Wisconsin is now home to two new biodiesel blending terminals. Fusion Renewables on Jones Island (in the City of Milwaukee) will offer a B100 blend to both bulk and retail customers. CITGO is currently providing a B5 blend to all customers at their Granville, WI terminal north of the City of Milwaukee.

  6. Clint, TX Natural Gas Pipeline Exports to Mexico (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) Clint, TX Natural Gas Pipeline Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 8,088 6,402 7,296 6,783 8,836 ...

  7. Freeport, TX Liquefied Natural Gas Exports (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Exports (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2016 2 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 04/29/2016 Next Release Date: 05/31/2016 Referring Pages: U.S.

  8. Freeport, TX Liquefied Natural Gas Exports (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Exports (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 2,725 2014 2,664 2015 2,805 2,728 2,947 3,145 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 04/29/2016 Next Release Date: 05/31/2016 Referring Pages: U.S.

  9. Freeport, TX Liquefied Natural Gas Exports Price (Dollars per Thousand

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Price (Dollars per Thousand Cubic Feet) Freeport, TX Liquefied Natural Gas Exports Price (Dollars per Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2016 10.00 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 04/29/2016 Next Release Date: 05/31/2016 Referring Pages: U.S. Price of

  10. Rotary mode core sampling approved checklist: 241-TX-113

    SciTech Connect (OSTI)

    Fowler, K.D.

    1998-08-03

    The safety assessment for rotary mode core sampling was developed using certain bounding assumptions, however, those assumptions were not verified for each of the existing or potential flammable gas tanks. Therefore, a Flammable Gas/Rotary Mode Core Sampling Approved Checklist has been completed for tank 241-TX-113 prior to sampling operations. This transmittal documents the dispositions of the checklist items from the safety assessment.

  11. Rotary mode core sampling approved checklist: 241-TX-116

    SciTech Connect (OSTI)

    FOWLER, K.D.

    1999-02-24

    The safety assessment for rotary mode core sampling was developed using certain bounding assumptions, however, those assumptions were not verified for each of the existing or potential flammable gas tanks. Therefore, a Flammable Gas/Rotary Mode Core Sampling Approved Checklist has been completed for tank 241-TX-116 prior to sampling operations. This transmittal documents the dispositions of the checklist items from the safety assessment.

  12. Albany, OR * Fairbanks, AK * Morgantown, WV * Pittsburgh, PA * Sugarland, TX

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sugarland, TX Website: www.netl.doe.gov Customer Service: 1-800-553-7681 Enhanced Oil Recovery Program The mission of the Enhanced Oil Recovery Program is to provide information and technologies that will assure sustainable, reliable, affordable, and environmentally sound supplies of domestic oil resources. The Strategic Center for Natural Gas and Oil (SCNGO) seeks to accomplish this critical mission by advancing environmentally responsible technological solutions that enhance recovery of oil

  13. DOE - Office of Legacy Management -- Trane Co - WI 0-02

    Office of Legacy Management (LM)

    Designated Name: Not Designated Alternate Name: None Location: LaCross , Wisconsin WI.0-02-1 Evaluation Year: 1987 WI.0-02-1 Site Operations: Produced Aluminum cans for fuel rod ...

  14. DOE - Office of Legacy Management -- Allis-Chalmers Co - WI 01

    Office of Legacy Management (LM)

    Year: 1987 WI.01-1 Site Operations: Manufactured electrical equipment - pumps, motors, and switchgears for K-25 and Y-12. WI.01-1 Site Disposition: Eliminated - Scope of...

  15. AmeriFlux US-Wi4 Mature red pine (MRP) (Dataset) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Wi4 Mature red pine (MRP) Citation Details In-Document Search Title: AmeriFlux US-Wi4 Mature red pine (MRP) This is the AmeriFlux version of the carbon flux data for the site ...

  16. DOE Zero Energy Ready Home Case Study: M Street Homes, Houston, TX |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy M Street Homes, Houston, TX DOE Zero Energy Ready Home Case Study: M Street Homes, Houston, TX DOE Zero Energy Ready Home Case Study: M Street Homes, Houston, TX Case study of a DOE Zero Energy Ready home in Houston, TX, that achieves a HERS 45 without PV or HERS 32 with 1.2 kW PV. The three-story, 4,507-ft2 custom home is powered by a unique tri-generation system that supplies all of the home's electricity, heating, and cooling on site. The tri-generator is powered by a

  17. Microsoft Word - TX-100 Final Report - SAND2007-6066.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manager: Tom Ashwill Abstract This report details the work completed under the TX-100 blade manufacturing portion of the Carbon-Hybrid Blade Developments: Standard and...

  18. U.S. Energy Information Administration | Annual Coal Report 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    5. Coal Consumers in the Manufacturing and Coke Sectors, 2014 Company Name Plant Location Top Ten Manufacturers American Crystal Sugar Co MN, ND Archer Daniels Midland IA, IL, MN, NE Carmeuse Lime Stone Inc AL, IN, KY, MI, OH, PA, TN, WI Cemex Inc AL, CA, CO, FL, GA, KY, OH, TN, TX Dakota Gasification Company ND Eastman Chemical Company TN Georgia-Pacific Consumer Products LP AL, GA, OK, VA, WI Holcim (US) Inc AL, CO, MD, MO, MT, OK, SC, TX, UT NewPage Corporation MD, MI, WI U S Steel

  19. TRIBAL ISSUES TOPIC GROUP MEETING SUMMARY Milwaukee, WI July 1998

    Office of Environmental Management (EM)

    Milwaukee, WI July 1998 The Topic Group is developing a process to identify appropriate Topic Group membership, and will be working on a protocol for identifying and inviting individual tribes to participate he group identified five actions: (1) catalogue tribal transportation issues; (2) identify a level of tribal awareness of DOE transportation issues; (3) examine funding and tribal support; (4) develop a process for Tribal Topic Group membership; and (5) review the best channels to

  20. CX-100 and TX-100 blade field tests.

    SciTech Connect (OSTI)

    Holman, Adam (USDA-Agriculture Research Service, Bushland, TX); Jones, Perry L.; Zayas, Jose R.

    2005-12-01

    In support of the DOE Low Wind Speed Turbine (LWST) program two of the three Micon 65/13M wind turbines at the USDA Agricultural Research Service (ARS) center in Bushland, Texas will be used to test two sets of experimental blades, the CX-100 and TX-100. The blade aerodynamic and structural characterization, meteorological inflow and wind turbine structural response will be monitored with an array of 75 instruments: 33 to characterize the blades, 15 to characterize the inflow, and 27 to characterize the time-varying state of the turbine. For both tests, data will be sampled at a rate of 30 Hz using the ATLAS II (Accurate GPS Time-Linked Data Acquisition System) data acquisition system. The system features a time-synchronized continuous data stream and telemetered data from the turbine rotor. This paper documents the instruments and infrastructure that have been developed to monitor these blades, turbines and inflow.

  1. File:USDA-CE-Production-GIFmaps-TX.pdf | Open Energy Information

    Open Energy Info (EERE)

    TX.pdf Jump to: navigation, search File File history File usage Texas Ethanol Plant Locations Size of this preview: 776 600 pixels. Full resolution (1,650 1,275 pixels,...

  2. TxDOT - Right of Way Forms webpage | Open Energy Information

    Open Energy Info (EERE)

    Right of Way Forms webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: TxDOT - Right of Way Forms webpage Abstract This webpage provides the...

  3. Freeport, TX Liquefied Natural Gas Exports to Egypt (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Egypt (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Exports to Egypt (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 2,947 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 04/29/2016 Next Release Date: 05/31/2016 Referring Pages: U.S. Liquefied Natural Gas Exports by Point of Exit Freeport, TX Liquefied Natural Gas Exports to Egypt

  4. Freeport, TX Liquefied Natural Gas Exports to Turkey (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Turkey (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Exports to Turkey (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 3,145 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 04/29/2016 Next Release Date: 05/31/2016 Referring Pages: U.S. Liquefied Natural Gas Exports by Point of Exit Freeport, TX Liquefied Natural Gas Exports to Turkey

  5. Super Wi-Fi is Super for Energy Too | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wi-Fi is Super for Energy Too Super Wi-Fi is Super for Energy Too September 24, 2010 - 11:45am Addthis Super Wi-Fi is Super for Energy Too Nick Sinai U.S. Deputy Chief Technology Officer, White House Office of Science and Technology Policy What does this mean for me? By integrating broadband into the emerging Smart Grid, consumers will have revolutionized communication with their utility -- they will have detailed information on their energy use that will help inform them how they can save on

  6. WiTec at Sandia: Pushing a Great Tool Further. (Conference) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect WiTec at Sandia: Pushing a Great Tool Further. Citation Details In-Document Search Title: WiTec at Sandia: Pushing a Great Tool Further. Abstract not provided. Authors: Beechem Iii, Thomas Edwin Publication Date: 2012-09-01 OSTI Identifier: 1116404 Report Number(s): SAND2012-8071C 480446 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: WiTec Research&Development Meeting held September 24-27, 2012 in Ulm, Germany.; Related Information:

  7. RCRA Assessment Plan for Single-Shell Tank Waste Management Area TX-TY

    SciTech Connect (OSTI)

    Horton, Duane G.

    2007-03-26

    WMA TX-TY contains underground, single-shell tanks that were used to store liquid waste that contained chemicals and radionuclides. Most of the liquid has been removed, and the remaining waste is regulated under the RCRA as modified in 40 CFR Part 265, Subpart F and Washington States Hazardous Waste Management Act . WMA TX-TY was placed in assessment monitoring in 1993 because of elevated specific conductance. A groundwater quality assessment plan was written in 1993 describing the monitoring activities to be used in deciding whether WMA TX-TY had affected groundwater. That plan was updated in 2001 for continued RCRA groundwater quality assessment as required by 40 CFR 265.93 (d)(7). This document further updates the assessment plan for WMA TX-TY by including (1) information obtained from ten new wells installed at the WMA after 1999 and (2) information from routine quarterly groundwater monitoring during the last five years. Also, this plan describes activities for continuing the groundwater assessment at WMA TX TY.

  8. Identified Patent Waiver W(I)2010-005 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Identified Patent Waiver W(I)2010-005 This document waives certain patent rights the Department of Energy (DOE) has to inventions conceived or first actually reduced to practice by ...

  9. Identified Patent Waiver W(I)2010-006 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Identified Patent Waiver W(I)2010-006 This document waives certain patent rights the Department of Energy (DOE) has to inventions conceived or first actually reduced to practice by ...

  10. File:USDA-CE-Production-GIFmaps-WI.pdf | Open Energy Information

    Open Energy Info (EERE)

    WI.pdf Jump to: navigation, search File File history File usage Wisconsin Ethanol Plant Locations Size of this preview: 776 600 pixels. Full resolution (1,650 1,275...

  11. 3200 East Ave. S. * PO Box 817 * La Crosse, WI 54602-0817 ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    00 East Ave. S. * PO Box 817 * La Crosse, WI 54602-0817 * 608-788-4000 * 608-787-1420 fax * www.dairynet.com Dairyland Power Cooperative is an equal opportunity provider and ...

  12. Freeport, TX Exports to India Liquefied Natural Gas (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Exports to India Liquefied Natural Gas (Million Cubic Feet) Freeport, TX Exports to India Liquefied Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 3,120 2,873 2012 3,004 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 04/29/2016 Next Release Date: 05/31/2016 Referring Pages: U.S. Liquefied Natural Gas Exports by Point of Exit Freeport, TX Liquefied Natural Gas

  13. Freeport, TX Liquefied Natural Gas Imports From Peru (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    From Peru (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Imports From Peru (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 3,175 3,338 3,262 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Liquefied Natural Gas Imports by Point of Entry Freeport, TX LNG Imports from Peru

  14. Freeport, TX Liquefied Natural Gas Imports from Norway (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Norway (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Imports from Norway (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 2,709 2,918 2015 5,992 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Liquefied Natural Gas Imports by Point of Entry Freeport, TX LNG Imports from Norway

  15. Freeport, TX Liquefied Natural Gas Imports from Yemen (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Yemen (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Imports from Yemen (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 2,869 3,108 2012 2,979 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Liquefied Natural Gas Imports by Point of Entry Freeport, TX LNG Imports from Yemen

  16. Freeport, TX Natural Gas LNG Imports (Price) From Nigeria (Dollars per

    U.S. Energy Information Administration (EIA) Indexed Site

    Thousand Cubic Feet) Freeport, TX Natural Gas LNG Imports (Price) From Nigeria (Dollars per Thousand Cubic Feet) Freeport, TX Natural Gas LNG Imports (Price) From Nigeria (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- -- 2010's 6.43 -- -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date:

  17. Freeport, TX Natural Gas Liquefied Natural Gas Imports (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    (Million Cubic Feet) Freeport, TX Natural Gas Liquefied Natural Gas Imports (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2014 2,703 2,994 2015 5,992 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Liquefied Natural Gas Imports by Point of Entry Freeport, TX LNG Imports from All Countries

  18. Freeport, TX Natural Gas Liquefied Natural Gas Imports from Egypt (Million

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Egypt (Million Cubic Feet) Freeport, TX Natural Gas Liquefied Natural Gas Imports from Egypt (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 2,969 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Liquefied Natural Gas Imports by Point of Entry Freeport, TX LNG Imports from Egypt

  19. Freeport, TX Natural Gas Liquefied Natural Gas Imports from Other Countries

    U.S. Energy Information Administration (EIA) Indexed Site

    (Million Cubic Feet) Other Countries (Million Cubic Feet) Freeport, TX Natural Gas Liquefied Natural Gas Imports from Other Countries (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2014 2,703 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Liquefied Natural Gas Imports by Point of Entry Freeport, TX LNG Imports from

  20. Golden Pass, TX Natural Gas Liquefied Natural Gas Imports (price) (Dollars

    U.S. Energy Information Administration (EIA) Indexed Site

    per Thousand Cubic Feet) Golden Pass, TX Natural Gas Liquefied Natural Gas Imports (price) (Dollars per Thousand Cubic Feet) Golden Pass, TX Natural Gas Liquefied Natural Gas Imports (price) (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- -- 2010's 7.90 5.36 -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next

  1. CRAD, NNSA- Maintenance (MN)

    Office of Energy Efficiency and Renewable Energy (EERE)

    CRAD for Maintenance (MN). Criteria Review and Approach Documents (CRADs) that can be used to conduct a well-organized and thorough assessment of elements of safety and health programs.

  2. McAllen, TX Natural Gas Pipeline Exports to Mexico (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) McAllen, TX Natural Gas Pipeline Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 4,414 4,236 5,595 6,174 4,938 ...

  3. DOE Zero Energy Ready Home Case Study: M Street Homes, Houston, TX

    Broader source: Energy.gov [DOE]

    Case study of a DOE Zero Energy Ready home in Houston, TX, that achieves a HERS 45 without PV or HERS 32 with 1.2 kW PV. The three-story, 4,507-ft2 custom home is powered by a unique tri-generation...

  4. DOE Zero Energy Ready Home Case Study: Sterling Brook Custom Homes, Double Oak, TX

    Broader source: Energy.gov [DOE]

    Case study of a DOE Zero Energy Ready home in Double Oak, TX, north of Dallas, that scored a HERS 44 without PV. The 3,752-ft2 two-story home served as an energy-efficient model home for the custom...

  5. Identified Patent Waiver W(I)2010-009 | Department of Energy

    Energy Savers [EERE]

    9 Identified Patent Waiver W(I)2010-009 This document waives certain patent rights the Department of Energy (DOE) has to inventions conceived or first actually reduced to practice by SCHWEITZER ENGINEERING LAB INC. under agreement DE-FC26-07NT43311, as the DOE has determined that granting such a waiver best serves the interests of the United States and the general public. PDF icon Identified Patent Waiver W(I)2010-009 More Documents & Publications Hallmark Cryptographic Serial Communication

  6. Microsoft Word - figure_03.doc

    U.S. Energy Information Administration (EIA) Indexed Site

    IN OH TN WV VA KY MD PA NY VT NH MA CT ME RI DE DC NC SC GA FL NJ AL MS LA MO AR TX NM OK CO KS UT AZ WY NE IL IA MN WI ND SD ID MT WA OR NV CA HI AK MI Gulf of Mexico Volume

  7. El Paso, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) El Paso, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 996 NA 2000's NA NA NA - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S.

  8. Penitas, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) Penitas, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 253 40 NA 2000's NA NA NA - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S.

  9. Albany, OR * Anchorage, AK * Morgantown, WV * Pittsburgh, PA * Sugar Land, TX

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Training Center CONTACTS Traci Rodosta Carbon Storage Technology Manager National Energy Technology Laboratory 3610 Collins Ferry Road PO Box 880 Morgantown, WV 26507 304-285-1345 traci.rodosta@netl.doe.gov Andrea Dunn Project Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236 412-386-7594 andrea.dunn@netl.doe.gov Hilary Olson Project Director/Principal Investigator University of Texas at Austin 1 University Station, C0300 Austin, TX

  10. MN Office of Energy Security | Open Energy Information

    Open Energy Info (EERE)

    MN Office of Energy Security Jump to: navigation, search Name: MN Office of Energy Security Place: St. Paul, MN Website: www.mnofficeofenergysecurity.c References: MN Office of...

  11. Alternating magnetic anisotropy of Li 2 ( Li 1 - x T x ) N ( T = Mn , Fe , Co , and Ni )

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-01

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li?(Li1-xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.moreThe calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.less

  12. Texas A&M University College Station, TX 77843-3366

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MS #3366 Texas A&M University College Station, TX 77843-3366 Ph: 979-845-1411 Fax: 979-458-3213 Beam Time Request Form In order to be scheduled you must fill in and return this form by FAX (979-458-3213) or email to Henry Clark (clark@comp.tamu.edu) TO SCHEDULE CYCLOTRON TIME: Please indicate in the appropriate spaces below the number of 8 hour shifts you need, your preferred start date and the beams you intend to use. Since we cannot always schedule your preferred start date, please also

  13. El Paso, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Dollars per Thousand Cubic Feet) El Paso, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.09 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Price of

  14. Freeport, TX Liquefied Natural Gas Exports to Brazil (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    to Brazil (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Exports to Brazil (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 2,581 2012 2,601 2,644 2,897 2014 2,664 2015 2,805 2,728 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 04/29/2016 Next Release Date: 05/31/2016 Referring Pages: U.S.

  15. Freeport, TX Natural Gas Liquefied Natural Gas Imports from Trinidad and

    U.S. Energy Information Administration (EIA) Indexed Site

    Tobago (Million Cubic Feet) Trinidad and Tobago (Million Cubic Feet) Freeport, TX Natural Gas Liquefied Natural Gas Imports from Trinidad and Tobago (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 2,706 2012 2,872 2014 2,994 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Liquefied Natural Gas Imports by Point of

  16. Golden Pass, TX Natural Gas Liquefied Natural Gas Imports from Qatar

    U.S. Energy Information Administration (EIA) Indexed Site

    (Million Cubic Feet) from Qatar (Million Cubic Feet) Golden Pass, TX Natural Gas Liquefied Natural Gas Imports from Qatar (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 3,902 4,896 4,100 18,487 4,900 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S.

  17. Hidalgo, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) Hidalgo, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 13,609 17,243 13,496 41,879 2000's 2,093 7,292 782 0 0 1,342 967 5,259 1,201 284 2010's 62 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S.

  18. Price Liquefied Freeport, TX Natural Gas Exports Price to United Kingdom

    U.S. Energy Information Administration (EIA) Indexed Site

    (Dollars per Thousand Cubic Feet) United Kingdom (Dollars per Thousand Cubic Feet) Price Liquefied Freeport, TX Natural Gas Exports Price to United Kingdom (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- -- 2010's 7.56 -- -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 04/29/2016 Next Release Date: 05/31/2016 Referring

  19. McAllen, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) McAllen, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's NA NA 2000's 1,118 NA 402 0 0 5,322 7,902 26,605 20,115 12,535 2010's 2,520 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S.

  20. Alamo, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) Alamo, TX Natural Gas Pipeline Imports From Mexico (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's NA 12,651 2000's 8,390 2,984 571 0 0 2,656 3,880 22,197 20,653 13,279 2010's 4,685 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S.

  1. Albany, OR * Archorage, AK * Morgantown, WV * Pittsburgh, PA * Sugar Land, TX

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Archorage, AK * Morgantown, WV * Pittsburgh, PA * Sugar Land, TX Website: www.netl.doe.gov Customer Service: 1-800-553-7681 R& D FAC T S Geological & Environmental Sciences CONTACTS OFFICE OF RESEARCH AND DEVELOPMENT Kelly Rose Principal Investigator Research Physical Scientist 541-967-5883 kelly.rose@netl.doe.gov Jennifer Bauer Geospatial Researcher 541-918-4507 jennifer.bauer@contr.netl.doe.gov Cynthia Powell Acting Focus Area Lead 541-967-5803 cynthia.powell@netl.doe.gov RESEARCH

  2. Category:Minneapolis, MN | Open Energy Information

    Open Energy Info (EERE)

    16 total. SVFullServiceRestaurant Minneapolis MN Northern States Power Co (Minnesota) Excel Energy.png SVFullServiceRestauran... 89 KB SVHospital Minneapolis MN Northern States...

  3. Cost-effectiveness analysis of TxDOT LPG fleet conversion. Volume 1. Interim research report

    SciTech Connect (OSTI)

    Euritt, M.A.; Taylor, D.B.; Mahmassani, H.

    1992-10-01

    Increased emphasis on energy efficiency and air quality has resulted in a number of state and federal initiatives examining the use of alternative fuels for motor vehicles. Texas' program for alternate fuels includes liquefied petroleum gas (LPG). Based on an analysis of 30-year life-cycle costs, development of a propane vehicle program for the Texas Department of Transportation (TxDOT) would cost about $24.3 million (in 1991 dollars). These costs include savings from lower-priced LPG and differentials between propane and gasoline/diesel in infrastructure costs for a fueling station, vehicle costs, and operating costs. The 30-year life-cycle costs translate into an average annual vehicle cost increase of $308, or about 2.5 cents more per vehicle mile of travel. Sensitivity analyses are performed on the discount rate, price of propane, maintenance savings, vehicle utilization, diesel vehicles, extended vehicle life, original equipment manufacturer (OEM) vehicles, and operating and infrastructure costs. The best results are obtained when not converting diesel vehicles, converting only large fleets, and extending the period the vehicle is kept in service. Combining these factors yields results that are most cost-effective for TxDOT. This is volume one of two volumes.

  4. Cost-effectiveness analysis of TxDOT LPG fleet conversion. Volume 2. Interim research report

    SciTech Connect (OSTI)

    Euritt, M.A.; Taylor, D.B.; Mahmassani, H.

    1992-11-01

    Increased emphasis on energy efficiency and air quality has resulted in a number of state and federal initiatives examining the use of alternative fuels for motor vehicles. Texas' program for alternate fuels includes liquefied petroleum gas (LPG), commonly called propane. Based on an analysis of 30-year life-cycle costs, development of a propane vehicle program for the Texas Department of Transportation (TxDOT) would cost about $24.3 million (in 1991 dollars). These costs include savings from lower-priced propane and differentials between propane and gasoline/diesel in infrastructure costs, vehicle costs, and operating costs. The 30-year life-cycle costs translate into an average annual vehicle cost increase of $308, or about 2.5 cents more per vehicle mile of travel. Based on the cost-effectiveness analysis and assumptions, there are currently no TxDOT locations that can be converted to propane without additional financial outlays. This is volume two of two volumes.

  5. EIS-0412: Federal Loan Guarantee to Support Construction of the TX Energy LLC, Industrial Gasification Facility near Beaumont, Texas

    Broader source: Energy.gov [DOE]

    The Department of Energy is assessing the potential environmental impacts for its proposed action of issuing a Federal loan guarantee to TX Energy, LLC (TXE). TXE submitted an application to DOE under the Federal loan guarantee program pursuant to the Energy Policy Act of 2005 (EPAct 2005) to support construction of the TXE industrial Gasification Facility near Beaumont, Texas.

  6. RCRA Assessment Plan for Single-Shell Tank Waste Management Area TX-TY at the Hanford Site

    SciTech Connect (OSTI)

    Hodges, Floyd N.; Chou, Charissa J.

    2001-02-23

    A groundwater quality assessment plan was prepared to investigate the rate and extent of aquifer contamination beneath Waste Management Area TX-TY on the Hanford Site in Washington State. This plan is an update of a draft plan issued in February 1999, which guided work performed in fiscal year 2000.

  7. Hidalgo, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Dollars per Thousand Cubic Feet) Hidalgo, TX Natural Gas Pipeline Imports From Mexico (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.26 2.31 2.03 2.09 2000's 5.85 4.61 2.26 -- -- 8.10 5.53 6.23 5.55 4.40 2010's 4.21 -- -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016

  8. Reservoir fracture mapping using microearthquakes: Austin chalk, Giddings field, TX and 76 field, Clinton Co., KY

    SciTech Connect (OSTI)

    Phillips, W.S.; Rutledge, J.T.; Gardner, T.L.; Fairbanks, T.D.; Miller, M.E.; Schuessler, B.K.

    1996-11-01

    Patterns of microearthquakes detected downhole defined fracture orientation and extent in the Austin chalk, Giddings field, TX and the 76 field, Clinton Co., KY. We collected over 480 and 770 microearthquakes during hydraulic stimulation at two sites in the Austin chalk, and over 3200 during primary production in Clinton Co. Data were of high enough quality that 20%, 31% and 53% of the events could be located, respectively. Reflected waves constrained microearthquakes to the stimulated depths at the base of the Austin chalk. In plan view, microearthquakes defined elongate fracture zones extending from the stimulation wells parallel to the regional fracture trend. However, widths of the stimulated zones differed by a factor of five between the two Austin chalk sites, indicating a large difference in the population of ancillary fractures. Post-stimulation production was much higher from the wider zone. At Clinton Co., microearthquakes defined low-angle, reverse-fault fracture zones above and below a producing zone. Associations with depleted production intervals indicated the mapped fractures had been previously drained. Drilling showed that the fractures currently contain brine. The seismic behavior was consistent with poroelastic models that predicted slight increases in compressive stress above and below the drained volume.

  9. Nanoscale elastic changes in 2D Ti3C2Tx (MXene) pseudocapacitive electrodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Come, Jeremy; Xie, Yu; Naguib, Michael; Jesse, Stephen; Kalinin, Sergei V.; Gogotsi, Yury; Kent, Paul R. C.; Balke, Nina

    2016-02-01

    Designing sustainable electrodes for next generation energy storage devices relies on the understanding of their fundamental properties at the nanoscale, including the comprehension of ions insertion into the electrode and their interactions with the active material. One consequence of ion storage is the change in the electrode volume resulting in mechanical strain and stress that can strongly affect the cycle life. Therefore, it is important to understand the changes of dimensions and mechanical properties occurring during electrochemical reactions. While the characterization of mechanical properties via macroscopic measurements is well documented, in-situ characterization of their evolution has never been achieved atmore » the nanoscale. Two dimensional (2D) carbides, known as MXenes, are promising materials for supercapacitors and various kinds of batteries, and understating the coupling between their mechanical and electrochemical properties is therefore necessary. Here we report on in-situ imaging, combined with density functional theory of the elastic changes, of a 2D titanium carbide (Ti3C2Tx) electrode in direction normal to the basal plane during cation intercalation. The results show a strong correlation between the Li+ ions content and the elastic modulus, whereas little effects of K+ ions are observed. Moreover, this strategy enables identifying the preferential intercalation pathways within a single particle.« less

  10. STEAB Meeting Minutes August 2007

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Energy Advisory Board Meeting August 14-16, 2007 Berkeley, CA. A Visit to the Lawrence Berkeley National Laboratory BOARD MEMBERS PRESENT Chris Benson (Chairman) (AR), Patricia Sobrero (Vice-Chair) (VA), Elliot Jacobson (Secretary) (MA), Robert Hoppie (ID), Janet Streff (MN), Duane Hauck (ND), Peter Johnston (AZ), John Davies (KY), William "Dub" Taylor (TX), Alexander Mack (FL), Jim Ploger (KS), Jim Nolan (MT), Susan Brown (WI), Paul Gutierrez (NM), and Steven Vincent (OR).

  11. SURFACE GEOPHYSICAL EXPLORATION OF TX-TY TANK FARMS AT THE HANFORD SITE RESULTS OF BACKGROUND CHARACTERIZATION WITH GROUND PENETRATING RADAR

    SciTech Connect (OSTI)

    MYERS DA; CUBBAGE R; BRAUCHLA R; O'BRIEN G

    2008-07-24

    Ground penetrating radar surveys of the TX and TY tank farms were performed to identify existing infrastructure in the near surface environment. These surveys were designed to provide background information supporting Surface-to-Surface and Well-to-Well resistivity surveys of Waste Management Area TX-TY. The objective of the preliminary investigation was to collect background characterization information with GPR to understand the spatial distribution of metallic objects that could potentially interfere with the results from high resolution resistivity{trademark} surveys. The results of the background characterization confirm the existence of documented infrastructure, as well as highlight locations of possible additional undocumented subsurface metallic objects.

  12. SSL Demonstration: Bridge Lighting, Minneapolis, MN

    SciTech Connect (OSTI)

    2014-10-01

    DOE Solid-State Lighting GATEWAY summary brief for Phase II report on the longer-term performance of LED lighting installed in 2008 on the I-35W Bridge in Minneapolis, MN.

  13. High Mn austenitic stainless steel

    DOE Patents [OSTI]

    Yamamoto, Yukinori [Oak Ridge, TN; Santella, Michael L [Knoxville, TN; Brady, Michael P [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Liu, Chain-tsuan [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  14. Local environment of Mn in Mn delta-doped Si layers

    SciTech Connect (OSTI)

    Xiao, Q.F.; Kahwaji, S.; Monchesky, T.L.; Gordon, R.A.; Crozier, E.D.

    2009-11-09

    Dilute magnetic semiconductors combine both magnetic ordering and semiconducting behaviour, leading to potential spintronic applications. Silicon containing dilute Mn impurities is a potential dilute magnetic semiconductor. We have grown Mn delta-doped films by deposition of 0.7 of a monolayer of Mn on Si(001) by molecular beam epitaxy and capping the film with Si. The magnetic properties are likely sensitive to the distribution of Mn on substitutional or interstitial sites and the formation of metallic precipitates. We have used polarization-dependent XAFS to examine the local structure. We compare to a thicker MnSi film grown on Si(111) and also examine the influence of lead on the manganese environment when used as a surfactant in the growth process.

  15. Structural, magnetic, and superconducting properties of pulsed-laser-deposition-grown La<mn>1.85mn> Sr<mn>0.15mn> CuO<mn>4mn> / La<mn>2mn>/>3mn> Ca<mn>1mn>/>3mn> MnO>3mn> superlattices on (001)-oriented LaSrAlO<mn>4mn> substrates

    SciTech Connect (OSTI)

    Das, S.; Sen, K.; Marozau, I.; Uribe-Laverde, M. A.; Biskup, N.; Varela, M.; Khaydukov, Y.; Soltwedel, O.; Keller, T.; Döbeli, M.; Schneider, C. W.; Bernhard, C.

    2014-03-12

    Epitaxial La<mn>1.85mn> Sr<mn>0.15mn> CuO<mn>4mn> / La<mn>2mn>/>3mn> Ca<mn>1mn>/>3mn> MnO>3mn> (LSCO/LCMO) superlattices (SL) on (001)- oriented LaSrAlO4 substrates have been grown with pulsed laser deposition (PLD) technique. Their structural, magnetic and superconducting properties have been determined with in-situ reflection high energy electron diffraction (RHEED), x-ray diffraction, specular neutron reflectometry, scanning transmission electron microscopy (STEM), electric transport, and magnetization measurements. We find that despite the large mismatch between the in-plane lattice parameters of LSCO (a = 0.3779 nm) and LCMO (a = 0.387 nm) these superlattices can be grown epitaxially and with a high crystalline quality. While the first LSCO layer remains clamped to the LSAO substrate, a sizeable strain relaxation occurs already in the first LCMO layer. The following LSCO and LCMO layers adopt a nearly balanced state in which the tensile and compressive strain effects yield alternating in-plane lattice parameters with an almost constant average value. No major defects are observed in the LSCO layers, while a significant number of vertical antiphase boundaries are found in the LCMO layers. The LSCO layers remain superconducting with a relatively high superconducting onset temperature of Tconset ≈ 36 K. The macroscopic superconducting response is also evident in the magnetization data due to a weak diamagnetic signal below 10 K for H ∥ ab and a sizeable paramagnetic shift for H ∥ c that can be explained in terms of a vortex-pinning-induced flux compression. The LCMO layers maintain a strongly ferromagnetic state with a Curie temperature of TCurie ≈ 190 K and a large low-temperature saturation moment of about 3.5 (1) μB. These results suggest that the LSCO/LCMO superlattices can be used to study the interaction between the antagonistic ferromagnetic and superconducting orders and, in combination with previous studies on YBCO/LCMO superlattices, may allow one to identify the relevant mechanisms.

  16. Properties of (Ga,Mn)As codoped with Li

    SciTech Connect (OSTI)

    Miyakozawa, Shohei; Chen, Lin; Matsukura, Fumihiro; Ohno, Hideo

    2014-06-02

    We grow Li codoped (Ga,Mn)As layers with nominal Mn composition up to 0.15 by molecular beam epitaxy. The layers before and after annealing are characterized by x-ray diffraction, transport, magnetization, and ferromagnetic resonance measurements. The codoping with Li reduces the lattice constant and electrical resistivity of (Ga,Mn)As after annealing. We find that (Ga,Mn)As:Li takes similar Curie temperature to that of (Ga,Mn)As, but with pronounced magnetic moments and in-plane magnetic anisotropy, indicating that the Li codoping has nontrivial effects on the magnetic properties of (Ga,Mn)As.

  17. Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Qiang; Tian, Wei; Peterson, Spencer G.; Dennis, Kevin W.; Vaknin, David

    2015-02-18

    Structure and magnetic properties of high-quality polycrystlline CeMnAsO, a parent compound of the “1111”-type oxypnictides, have been investigated using neutron powder diffraction and magnetization measurements. We find that CeMnAsO undergoes a C-type antiferromagnetic order with Mn2+(S = 5/2) moments pointing along the c axis below a relatively high Néel temperature of TN = 347(1) K. Below TSR = 35 K, two simultaneous transitions occur where the Mn moments reorient from the c axis to the ab plane preserving the C-type magnetic order, and Ce moments undergo long-range AFM ordering with antiparallel moments pointing in the ab plane. Another transition tomore » a noncollinear magnetic structure occurs below 7 K. The ordered moments of Mn and Ce at 2 K are 3.32(4) μB and 0.81(4)μB, respectively. We find that CeMnAsO primarily falls into the category of a local-moment antiferromagnetic insulator in which the nearest-neighbor interaction (J1) is dominant with J2 < J1/2 in the context of J1 – J2 – Jc model. The spin reorientation transition driven by the coupling between Ce and the transition metal seems to be common to Mn, Fe, and Cr ions, but not to Co and Ni ions in the isostructural oxypnictides. As a result, a schematic illustration of magnetic structures in Mn and Ce sublattices in CeMnAsO is presented.« less

  18. Magnetoelectric coupling tuned by competing anisotropies in Mn...

    Office of Scientific and Technical Information (OSTI)

    Magnetoelectric coupling tuned by competing anisotropies in Mn 1 - x Ni x TiO 3 Prev Next Title: Magnetoelectric coupling tuned by competing anisotropies in Mn 1 - x Ni x TiO ...

  19. Magnetostructural phase transformations in Tb 1-x Mn 2 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Magnetostructural phase transformations in Tb 1-x Mn 2 Citation Details In-Document Search Title: Magnetostructural phase transformations in Tb 1-x Mn 2 You are accessing a ...

  20. CaMn2Al10: Itinerant Mn magnetism on the verge of magnetic order

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Steinke, L.; Simonson, J. W.; Yin, W. -G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-24

    We report the discovery of CaMn2Al10, a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83μB/Mn, significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ≈ 9% of Rln2. These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility χ is anisotropic below 20 K, with a maximum ratio of χ[010]/χ[001] ≈ 3.5. A strong power-lawmore » divergence χ(T) ~ T–1.2 below 20 K implies incipient ferromagnetic order, an Arrott plot analysis of the magnetization suggests a vanishing low Curie temperature TC ~ 0. Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.« less

  1. Influence of interstitial Mn on magnetism in room-temperature ferromagnet Mn(1+delta)Sb

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Taylor, Alice E; Berlijn, Tom; Hahn, Steven E; May, Andrew F; Williams, Travis J; Poudel, Lekhanath N; Calder, Stuart A; Fishman, Randy Scott; Stone, Matthew B; Aczel, Adam A; et al

    2015-01-01

    We report elastic and inelastic neutron scattering measurements of the high-TC ferromagnet Mn(1+delta)Sb. Measurements were performed on a large, TC = 434 K, single crystal with interstitial Mn content of delta=0.13. The neutron diffraction results reveal that the interstitial Mn has a magnetic moment, and that it is aligned antiparallel to the main Mn moment. We perform density functional theory calculations including the interstitial Mn, and find the interstitial to be magnetic in agreement with the diffraction data. The inelastic neutron scattering measurements reveal two features in the magnetic dynamics: i) a spin-wave-like dispersion emanating from ferromagnetic Bragg positions (Hmore » K 2n), and ii) a broad, non-dispersive signal centered at forbidden Bragg positions (H K 2n+1). The inelastic spectrum cannot be modeled by simple linear spin-wave theory calculations, and appears to be significantly altered by the presence of the interstitial Mn ions. The results show that the influence of the int« less

  2. Influence of interstitial Mn on magnetism in room-temperature ferromagnet Mn(1+delta)Sb

    SciTech Connect (OSTI)

    Taylor, Alice E; Berlijn, Tom; Hahn, Steven E; May, Andrew F; Williams, Travis J; Poudel, Lekhanath N; Calder, Stuart A; Fishman, Randy Scott; Stone, Matthew B; Aczel, Adam A; Cao, Huibo; Lumsden, Mark D; Christianson, Andrew D

    2015-01-01

    We report elastic and inelastic neutron scattering measurements of the high-TC ferromagnet Mn(1+delta)Sb. Measurements were performed on a large, TC = 434 K, single crystal with interstitial Mn content of delta=0.13. The neutron diffraction results reveal that the interstitial Mn has a magnetic moment, and that it is aligned antiparallel to the main Mn moment. We perform density functional theory calculations including the interstitial Mn, and find the interstitial to be magnetic in agreement with the diffraction data. The inelastic neutron scattering measurements reveal two features in the magnetic dynamics: i) a spin-wave-like dispersion emanating from ferromagnetic Bragg positions (H K 2n), and ii) a broad, non-dispersive signal centered at forbidden Bragg positions (H K 2n+1). The inelastic spectrum cannot be modeled by simple linear spin-wave theory calculations, and appears to be significantly altered by the presence of the interstitial Mn ions. The results show that the influence of the int

  3. Opti-MN Impact House Presentation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opti-MN Impact House Presentation Opti-MN Impact House Presentation Opti-MN was the Grand Winner of the 2015 Race to Zero Student Design Competition. View the presentation for the Opti-MN Impact House below. Read a full list of the winning teams. PDF icon Opti-MN Presentation More Documents & Publications 2015 Race to Zero Competition Grand Winner and Grand Winner Finalist Team Submissions 2016 Race to Zero Competition Winner Team Presentations 2014 Race to Zero Student Design Competition:

  4. Resolving the structure of Ti3C2Tx MXenes through multilevel structural modeling of the atomic pair distribution function

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wesolowski, David J.; Wang, Hsiu -Wen; Page, Katharine L.; Naguib, Michael; Gogotsi, Yury

    2015-12-08

    MXenes are a recently discovered family of two-dimensional (2D) early transition metal carbides and carbonitrides, which have already shown many attractive properties and a great promise in energy storage and many other applications. However, a complex surface chemistry and small coherence length has been an obstacle in some applications of MXenes, also limiting accuracy of predictions of their properties. In this study, we describe and benchmark a novel way of modeling layered materials with real interfaces (diverse surface functional groups and stacking order between the adjacent monolayers) against experimental data. The structures of three kinds of Ti3C2Tx MXenes (T standsmore » for surface terminating species, including O, OH, and F) produced under different synthesis conditions were resolved for the first time using atomic pair distribution function obtained by high-quality neutron total scattering. The true nature of the material can be easily captured with the sensitivity of neutron scattering to the surface species of interest and the detailed third-generation structure model we present. The modeling approach leads to new understanding of MXene structural properties and can replace the currently used idealized models in predictions of a variety of physical, chemical and functional properties of Ti3C2-based MXenes. Furthermore, the developed models can be employed to guide the design of new MXene materials with selected surface termination and controlled contact angle, catalytic, optical, electrochemical and other properties. We suggest that the multi-level structural modeling should form the basis for a generalized methodology on modeling diffraction and pair distribution function data for 2D and layered materials.« less

  5. Unexpected crystal and magnetic structures in MnCu4In and MnCu4Sn (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect SciTech Connect Search Results Journal Article: Unexpected crystal and magnetic structures in MnCu4In and MnCu4Sn Citation Details In-Document Search Title: Unexpected crystal and magnetic structures in MnCu4In and MnCu4Sn We discovered a new compound MnCu4In with its own hexagonal structure type (hP12-P63mc, ternary ordered derivative of the hexagonal MgZn2-type) that becomes ferromagnetic at TC = 540 K. This transition temperature is higher than that found in the

  6. albers.dvi

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Madison, 1150 University Avenue, Madison, WI 53706, USA W. D. DECHERT Department of Economics, University of Houston, Houston TX 77204-5882, USA Received January 13, 1998; Revised ...

  7. Unexpected crystal and magnetic structures in MnCu4In and MnCu4Sn

    SciTech Connect (OSTI)

    Provino, A.; Paudyal, D.; Fornasini, ML; Dhiman, I.; Dhar, SK.; Das, A.; Mudryk, Y.; Manfrinetti, P.; Pecharsky, VK

    2013-01-29

    We discovered a new compound MnCu4In with its own hexagonal structure type (hP12-P63mc, ternary ordered derivative of the hexagonal MgZn2-type) that becomes ferromagnetic at TC = 540 K. This transition temperature is higher than that found in the MnCu2In and MnCu2Sn alloys. In contrast, the homologous compound MnCu4Sn, which crystallizes in the cubic MgCu4Sn-type, orders antiferromagnetically with TN = 110 K. The neutron diffraction studies show ferromagnetic spin orientation in the {1 0 1} plane in MnCu4In with a magnetic moment of 4.5 ?B/Mn at 22 K, and a corresponding value of 4.7 ?B/Mn in the antiferromagnetic MnCu4Sn with propagation vector View the MathML source. The first-principles electronic structure calculations show that the unexpected difference in both magnetic and crystal structures of MnCu4In and MnCu4Sn is due to the difference in the Mn-3d bands and exchange interactions relating to different crystal anisotropy, coordination numbers, and interatomic distances.

  8. Solid Solution Phases in the Olivine-Type LiMnPO4/MnPO4 System

    SciTech Connect (OSTI)

    Chen, Guoying; Richardson, Thomas J.

    2009-04-07

    Nonstoichiometry is reported in the LiMnPO{sub 4}/MnPO{sub 4} system for the first time. As lithium is removed from crystalline LiMnPO{sub 4} by chemical or electrochemical methods, the resulting two phase mixture consists of stoichiometric LiMnPO{sub 4} and a delithiated phase, Li{sub y}MnPO{sub 4}, whose lattice parameters depend upon the global extent of delithiation and on the crystalline domain size of the delithiated phase. This behavior is reproduced during electrochemical insertion of lithium. Again, no evidence for nonstoichiometry was found in the vicinity of LiMnPO{sub 4}. Attempts to create single phase solid solutions by heating mixtures of the two phases failed due to the thermal instability of Li{sub y}MnPO{sub 4}.

  9. HIA 2015 DOE Zero Energy Ready Home Case Study: Carl Franklin Homes, L.C./Green Extreme Homes, CDC, McKinley Project, Garland TX

    Energy Savers [EERE]

    Carl Franklin Homes, L.C./ Green Extreme Homes, CDC McKinley Project Garland, TX DOE ZERO ENERGY READY HOME(tm) The U.S. Department of Energy invites home builders across the country to meet the extraordinary levels of excellence and quality specified in DOE's Zero Energy Ready Home program (formerly known as Challenge Home). Every DOE Zero Energy Ready Home starts with ENERGY STAR Certified Homes Version 3.0 for an energy-efficient home built on a solid foundation of building science research.

  10. ~tx421.ptx

    U.S. Energy Information Administration (EIA) Indexed Site

    ... a day-to- 3 day percentage change in past prices. 4 But what ... similar to our STEO query system where the 20 user could ... The term that I've 20 used in class all the time, I tend to ...

  11. ~tx410.ptx

    U.S. Energy Information Administration (EIA) Indexed Site

    ... right. 13 I'll legally change my name to sucker. 14 ... I lead a group that basically 18 does power system modeling, ... graduate energy modeling class where we 19 actually have ...

  12. Training Session: Euless, TX

    Broader source: Energy.gov [DOE]

    This 3.5-hour training provides builders with a comprehensive review of zero energy-ready home construction including the business case, detailed specifications, and opportunities to be recognized...

  13. Characterization of Vadose Zone Sediments Below the TX Tank Farm: Boreholes C3830, C3831, C3832 and RCRA Borehole 299-W10-27

    SciTech Connect (OSTI)

    Serne, R. Jeffrey; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; Legore, Virginia L.; Orr, Robert D.; Kutnyakov, Igor V.; Baum, Steven R.; Geiszler, Keith N.; Valenta, Michelle M.; Vickerman, Tanya S.

    2008-09-11

    This report was revised in September 2008 to remove acid-extractable sodium data from Tables 4.8, 4.28,4.43, and 4.59. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in April 2004. The overall goal of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities at Hanford. To meet this goal, CH2M HILL Hanford Group, Inc. tasked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediments from within Waste Management Area (WMA) T-TX-TY. This report is the first of two reports written to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from boreholes C3830, C3831, and C3832 in the TX Tank Farm, and from borehole 299-W-10-27 installed northeast of the TY Tank Farm.

  14. Investigations of element spatial correlation in Mn-promoted...

    Office of Scientific and Technical Information (OSTI)

    Investigations of element spatial correlation in Mn-promoted Co-based Fischer-Tropsch synthesis catalysts This content will become publicly available on June 4, 2017 Title: ...

  15. Spin caloritronics in graphene with Mn

    SciTech Connect (OSTI)

    Torres, Alberto Lima, Matheus P. Fazzio, A.; Silva, Antnio J. R. da

    2014-02-17

    We show that graphene with Mn adatoms trapped at single vacancies features spin-dependent Seebeck effect, thus enabling the use of this material for spin caloritronics. A gate potential can be used to tune its thermoelectric properties in a way it presents either a total spin polarized current, flowing in one given direction, or currents for both spins flowing in opposite directions without net charge transport. Moreover, we show that the thermal magnetoresistance can be tuned between ?100% and +100% by varying a gate potential.

  16. Buildings Energy Data Book: 3.9 Educational Facilities

    Buildings Energy Data Book [EERE]

    6 2010 Regional New Construction and Renovations Expenditures for Public K-12 Schools ($Million) Region New Schools Additions Renovation Total Region 1 (CT, MA, ME, NH, RI, VT) Region 2 (NJ, NY, PA) Region 3 (DE, MD, VA, WV) Region 4 (KY, NC, SC, TN) Region 5 (AL, FL, GA, MS) Region 6 (IN, MI, OH) Region 7 (IL, MN, WI) Region 8 (IA, KS, MO, NE) Region 9 (AR, LA, OK, TX) Region 10 (CO, MT, ND, NM, SD, UT, WY) Region 11 (AZ, CA, HI, NV) Region 12 (AK, ID, OR, WA) Total Source(s): School Planning

  17. Print

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    < 5k 0 < 50k < 100k < 250k < 500k < 1M > 1M > 5M > 10M DE MD DC MA RI NJ AZ UT WY ID OR WA CA TX OK KS CO NE SD ND MN WI IL IA MO AR LA MS AL FL GA TN KY IN OH MI ME NH CT VT NY PA WV VA NC SC MT AK HI NV NM Princeton Plasma Physics Laboratory Procured Materials and Services 2015 (> $35M) Small business procurements in US: $14.73M

  18. Annual Energy Outlook 2015 - Appendix F

    Gasoline and Diesel Fuel Update (EIA)

    7 U.S. Energy Information Administration | Annual Energy Outlook 2015 Regional maps Figure F6. Coal supply regions WA ID OR CA NV UT TX OK AR MO LA MS AL GA FL TN SC NC KY VA WV WY CO SD ND MI MN WI IL IN OH MD PA NJ DE CT MA NH VT NY ME RI MT NE IA KS MI AZ NM 500 0 SCALE IN MILES APPALACHIA Northern Appalachia Central Appalachia Southern Appalachia INTERIOR NORTHERN GREAT PLAINS Eastern Interior Western Interior Gulf Lignite Dakota Lignite Western Montana Wyoming, Northern Powder River Basin

  19. Magnetic Moment Enhancement for Mn7 Cluster on Graphene

    SciTech Connect (OSTI)

    Liu, Xiaojie; Wang, Cai-Zhuang; Lin, Hai-Qing; Ho, Kai-Ming

    2014-08-21

    Mn7 cluster on graphene with different structural motifs and magnetic orders are investigated systematically by first-principles calculations. The calculations show that Mn7 on graphene prefers a two-layer motif and exhibits a ferrimagnetic coupling. The magnetic moment of the Mn7 cluster increases from 5.0 ?B at its free-standing state to about 6.0 ?B upon adsorption on graphene. Mn7 cluster also induces about 0.3 ?B of magnetic moment in the graphene layer, leading to an overall enhancement of 1.3 ?B magnetic moment for Mn7 on graphene. Detail electron transfer and bonding analysis have been carried out to investigate the origin of the magnetic enhancement.

  20. Training Session: Madison, WI

    Broader source: Energy.gov [DOE]

    This 3.5-hour training provides builders with a comprehensive review of zero net-energy-ready home construction including the business case, detailed specifications, and opportunities to be...

  1. WI DOCUMENT RELEASE FORM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Basin Outline WY UT ID INDEX MAP 2001 Reserve Summary for Wyoming Thrust Belt Fields Wyoming Thrust Belt Oil & Gas Fields By 2001 BOE

    Gas Reserve Class No 2001 gas reserves 0.1 - 10 MMCF 10.1 - 100 MMCF 100.1 - 1,000 MMCF 1,000.1 - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Basin Outline WY UT ID INDEX MAP 2001 Reserve Summary for

  2. Microsoft Word - figure_14.doc

    U.S. Energy Information Administration (EIA) Indexed Site

    42 Figure 14. Net interstate movements, imports, and exports of natural gas in the United States, 2014 (million cubic feet) Norway Trinidad/ Tobago Yemen Trinidad/ Tobago Interstate Movements Not Shown on Map From Volume To From Volume To CT RI Other TX IN MA RI MA MA CT VA DC MD DC VT MA NH MA WA M T I D O R W Y ND SD C A N V U T CO NE KS A Z NM OK TX MN WI MI IA I L IN OH MO AR M S AL GA T N KY FL SC NC WV MD DE VA PA NJ NY CT RI MA VT NH ME LA HI A K Mexico C a n a d a C a n a d a Canada

  3. Inverse spin Hall effect in Pt/(Ga,Mn)As

    SciTech Connect (OSTI)

    Nakayama, H.; Chen, L.; Chang, H. W.; Ohno, H.; Matsukura, F.

    2015-06-01

    We investigate dc voltages under ferromagnetic resonance in a Pt/(Ga,Mn)As bilayer structure. A part of the observed dc voltage is shown to originate from the inverse spin Hall effect. The sign of the inverse spin Hall voltage is the same as that in Py/Pt bilayer structure, even though the stacking order of ferromagnetic and nonmagnetic layers is opposite to each other. The spin mixing conductance at the Pt/(Ga,Mn)As interface is determined to be of the order of 10{sup 19 }m{sup −2}, which is about ten times greater than that of (Ga,Mn)As/p-GaAs.

  4. CaMn2Al10: Itinerant Mn magnetism on the verge of magnetic order

    SciTech Connect (OSTI)

    Steinke, L.; Simonson, J. W.; Yin, W. -G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-24

    We report the discovery of CaMn2Al10, a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83μB/Mn, significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ≈ 9% of Rln2. These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility χ is anisotropic below 20 K, with a maximum ratio of χ[010][001] ≈ 3.5. A strong power-law divergence χ(T) ~ T–1.2 below 20 K implies incipient ferromagnetic order, an Arrott plot analysis of the magnetization suggests a vanishing low Curie temperature TC ~ 0. Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.

  5. Strong enhancement of s -wave superconductivity near a quantum critical point of Ca<mn>3mn>Ir>4mn>Sn>13mn>

    SciTech Connect (OSTI)

    Biswas, P. K.; Guguchia, Z.; Khasanov, R.; Chinotti, M.; Li, L.; Wang, Kefeng; Petrovic, C.; Morenzoni, E.

    2015-11-11

    We report microscopic studies by muon spin rotation/relaxation as a function of pressure of the Ca<mn>3mn>Ir>4mn>Sn>13mn> and Sr3Ir4Sn13 system displaying superconductivity and a structural phase transition associated with the formation of a charge density wave (CDW). Our findings show a strong enhancement of the superfluid density and a dramatic increase of the pairing strength above a pressure of ≈ 1.6 GPa giving direct evidence of the presence of a quantum critical point separating a superconducting phase coexisting with CDW from a pure superconducting phase. The superconducting order parameter in both phases has the same s-wave symmetry. In spite of the conventional phonon-mediated BCS character of the weakly correlated (Ca1-xSrx)3Ir4Sn13 system the dependence of the effective superfluid density on the critical temperature puts this compound in the “Uemura” plot close to unconventional superconductors. This system exemplifies that conventional BCS superconductors in the presence of competing orders or multi-band structure can also display characteristics of unconventional superconductors.

  6. Functional MnMg{sub k} cation complexes in GaN featured by Raman spectroscopy

    SciTech Connect (OSTI)

    Devillers, T. Bonanni, A.; Leite, D. M. G.; Department of Physics, So Paulo State University, BauruSP ; Dias da Silva, J. H.

    2013-11-18

    The evolution of the optical branch in the Raman spectra of (Ga,Mn)N:Mg epitaxial layers as a function of the Mn and Mg concentrations, reveals the interplay between the two dopants. We demonstrate that the various Mn-Mg-induced vibrational modes can be understood in the picture of functional MnMg{sub k} complexes formed when substitutional Mn cations are bound to k substitutional Mg through nitrogen atoms, the number of ligands k being driven by the ratio between the Mg and the Mn concentrations.

  7. Mn-Fe base and Mn-Cr-Fe base austenitic alloys

    DOE Patents [OSTI]

    Brager, Howard R.; Garner, Francis A.

    1987-01-01

    Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

  8. Synthesis, characterization and electrochemical performance of Al-substituted Li₂MnO₃

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dhital, Chetan; Huq, Ashfia; Paranthaman, Mariappan Parans; Manivannan, Ayyakkannu; Torres-Castro, Loraine; Shojan, Jifi; Julien, Christian M.; Katiyar, Ram S.

    2015-08-08

    Li2MnO3 is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li2MnO3 , Li1.5Al0.17MnO3, Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 were synthesized by a sol–gel Pechini method. All the samples were characterized with x-ray diffraction, Raman, x-ray photoelectron spectroscopy, scanning electron microscopy, Tap density and BET analyzer. X-ray diffraction patterns indicated the presence of monoclinic phase for pristine Li2MnO3and mixed monoclinic/spinel phases (Li2 - xMn1 - yAlx + yO3 + z) for Al-substituted Li2MnO3compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. X-ray photoelectronmore » spectroscopy for Mn 2p orbital reveals a significant decrease in binding energy for Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g-1 for Li2MnO3, 68 mAh g-1 for Li1.5Al0.17MnO3, 58 mAh g-1 for Li1.0Al0.33MnO3 and 74 mAh g-1 for Li0.5Al0.5MnO3 were obtained. As a result, aluminum substitutions increased the formation of spinel phase which is responsible for cycling.« less

  9. Structure and magnetic properties of LnMnSbO ( Ln=La and Ce)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Qiang; Kumar, C. M. N.; Tian, Wei; Dennis, Kevin W.; Goldman, Alan I.; Vaknin, David

    2016-03-11

    Here, a neutron powder diffraction (NPD) study of LnMnSbO (Ln = La or Ce) reveals differences between the magnetic ground state of the two compounds due to the strong Ce-Mn coupling compared to La-Mn. The two compounds adopt the P4/nmm space group down to 2 K, and whereas magnetization measurements do not show obvious anomaly at high temperatures, NPD reveals a C-type antiferromagnetic (AFM) order below TN = 255K for LaMnSbO and 240 K for CeMnSbO. While the magnetic structure of LaMnSbO is preserved to base temperature, a sharp transition at TSR = 4.5K is observed in CeMnSbO due tomore » a spin-reorientation (SR) transition of the Mn2+ magnetic moments from pointing along the c axis to the ab plane. The SR transition in CeMnSbO is accompanied by a simultaneous long-range AFM ordering of the Ce moments, which indicates that the Mn SR transition is driven by the Ce-Mn coupling. The ordered moments are found to be somewhat smaller than those expected for Mn2+ (S = 5/2) in insulators, but large enough to suggest that these compounds belong to the class of local-moment antiferromagnets. The lower TN found in these two compounds compared to the As-based counterparts (TN = 317 for LaMnAsO, TN = 347K for CeMnAsO) indicates that the Mn-Pn (Pn=As or Sb) hybridization that mediates the superexchange Mn-Pn-Mn coupling is weaker for the Sb-based compounds.« less

  10. Resonant spin tunneling in randomly oriented nanospheres of Mn?? acetate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lendinez, S.; Billinge, S. J. L.; Zarzuela, R.; Tejada, J.; Terban, M. W.; Espin, J.; Imaz, I.; Maspoch, D.; Chudnovsky, E. M.

    2015-01-06

    We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for amoresingle crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.less

  11. Climate Action Champions: Minneapolis, MN | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Minneapolis, MN Climate Action Champions: Minneapolis, MN The City of Minneapolis, or the “City of Lakes”, lies on both banks of the Mississippi River in Minnesota. Once the flour milling capital of the world, the larger of the Twin Cities is now a thriving Midwestern economic hub. │ Photo courtesy of Meet Minneapolis. The City of Minneapolis, or the "City of Lakes", lies on both banks of the Mississippi River in Minnesota. Once the flour milling capital of the world,

  12. Coexistence of charge-density wave and ferromagnetism in Ni2MnGa...

    Office of Scientific and Technical Information (OSTI)

    Coexistence of charge-density wave and ferromagnetism in Ni2MnGa Citation Details In-Document Search Title: Coexistence of charge-density wave and ferromagnetism in Ni2MnGa ...

  13. High spin polarization in CoFeMnGe equiatomic quaternary Heusler...

    Office of Scientific and Technical Information (OSTI)

    Title: High spin polarization in CoFeMnGe equiatomic quaternary Heusler alloy We report the structure, magnetic property, and spin polarization of CoFeMnGe equiatomic...

  14. Stress induced anisotropy in CoFeMn soft magnetic nanocomposites...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Stress induced anisotropy in CoFeMn soft magnetic nanocomposites Citation Details In-Document Search Title: Stress induced anisotropy in CoFeMn soft magnetic ...

  15. Pulsed laser deposition of Mn doped CdSe quantum dots for improved solar cell performance

    SciTech Connect (OSTI)

    Dai, Qilin; Wang, Wenyong E-mail: jtang2@uwyo.edu; Tang, Jinke E-mail: jtang2@uwyo.edu; Sabio, Erwin M.

    2014-05-05

    In this work, we demonstrate (1) a facile method to prepare Mn doped CdSe quantum dots (QDs) on Zn{sub 2}SnO{sub 4} photoanodes by pulsed laser deposition and (2) improved device performance of quantum dot sensitized solar cells of the Mn doped QDs (CdSe:Mn) compared to the undoped QDs (CdSe). The band diagram of photoanode Zn{sub 2}SnO{sub 4} and sensitizer CdSe:Mn QD is proposed based on the incident-photon-to-electron conversion efficiency (IPCE) data. Mn-modified band structure leads to absorption at longer wavelengths than the undoped CdSe QDs, which is due to the exchange splitting of the CdSe:Mn conduction band by the Mn dopant. Three-fold increase in the IPCE efficiency has also been observed for the Mn doped samples.

  16. Mixing antiferromagnets to tune NiFe-[IrMn/FeMn] interfacial spin-glasses, grains thermal stability, and related exchange bias properties

    SciTech Connect (OSTI)

    Akmaldinov, K.; Ducruet, C.; Portemont, C.; Joumard, I.; Prejbeanu, I. L.; Dieny, B.; Baltz, V.

    2014-05-07

    Spintronics devices and in particular thermally assisted magnetic random access memories require a wide range of ferromagnetic/antiferromagnetic (F/AF) exchange bias (EB) properties and subsequently of AF materials to fulfil diverse functionality requirements for the reference and storage. For the reference layer, large EB energies and high blocking temperature (T{sub B}) are required. In contrast, for the storage layer, mostly moderate T{sub B} are needed. One of the present issues is to find a storage layer with properties intermediate between those of IrMn and FeMn and in particular: (i) with a T{sub B} larger than FeMn for better stability at rest-T but lower than IrMn to reduce power consumption at write-T and (ii) with improved magnetic interfacial quality, i.e., with reduced interfacial glassy character for lower properties dispersions. To address this issue, the EB properties of F/AF based stacks were studied for various mixed [IrMn/FeMn] AFs. In addition to EB loop shifts, the F/AF magnetic interfacial qualities and the AF grains thermal stability are probed via measurements of the low- and high-temperature contributions to the T{sub B} distributions, respectively. A tuning of the above three parameters is observed when evolving from IrMn to FeMn via [IrMn/FeMn] repetitions.

  17. U.S. Natural Gas Exports to Canada

    Gasoline and Diesel Fuel Update (EIA)

    International Falls, MN Noyes, MN Warroad, MN Babb, MT Havre, MT Port of Del Bonita, MT Port of Morgan, MT Sweetgrass, MT Whitlash, MT Portal, ND Sherwood, ND Pittsburg, NH Champlain, NY Grand Island, NY Massena, NY Niagara Falls, NY Waddington, NY Sumas, WA Highgate Springs, VT North Troy, VT U.S. Pipeline Total from Mexico Ogilby, CA Otay Mesa, CA Alamo, TX El Paso, TX Galvan Ranch, TX Hidalgo, TX McAllen, TX Penitas, TX LNG Imports from Algeria Cove Point, MD Everett, MA Lake Charles, LA LNG

  18. Epitaxial growth of intermetallic MnPt films on oxides and large exchange bias

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zhiqi; Biegalski, Michael D.; Hsu, Shang-Lin; Shang, Shunli; Marker, Cassie; Liu, Jian; Li, Li; Fan, Lisha S.; Meyer, Tricia L.; Wong, Anthony T.; et al

    2015-11-05

    High-quality epitaxial growth of intermetallic MnPt films on oxides is achieved, with potential for multiferroic heterostructure applications. Antisite-stabilized spin-flipping induces ferromagnetism in MnPt films, although it is robustly antiferromagnetic in bulk. Thus, highly ordered antiferromagnetic MnPt films exhibit superiorly large exchange coupling with a ferromagnetic layer.

  19. Cationic disorder and Mn{sup 3+}/Mn{sup 4+} charge ordering in the B? and B? sites of Ca{sub 3}Mn{sub 2}NbO{sub 9} perovskite: a comparison with Ca{sub 3}Mn{sub 2}WO{sub 9}

    SciTech Connect (OSTI)

    Lpez, C.A.; Saleta, M.E.; Pedregosa, J.C.; Snchez, R.D.; Alonso, J.A.; and others

    2014-02-15

    We describe the preparation, crystal structure determination, magnetic and transport properties of two novel Mn-containing perovskites, with a different electronic configuration for Mn atoms located in B site. Ca{sub 3}Mn{sup 3+}{sub 2}WO{sub 9} and Ca{sub 3}Mn{sup 3+/4+}{sub 2}NbO{sub 9} were synthesized by standard ceramic procedures; the crystallographic structure was studied from X-ray powder diffraction (XRPD) and neutron powder diffraction (NPD). Both phases exhibit a monoclinic symmetry (S.G.: P2{sub 1}/n); Ca{sub 3}Mn{sub 2}WO{sub 9} presents a long-range ordering over the B sites, whereas Ca{sub 3}Mn{sub 2}NbO{sub 9} is strongly disordered. By in-situ NPD, the temperature evolution of the structure study presents an interesting evolution in the octahedral size (?MnO?) for Ca{sub 3}Mn{sub 2}NbO{sub 9}, driven by a charge ordering effect between Mn{sup 3+} and Mn{sup 4+} atoms, related to the anomaly observed in the transport measurements at T?160 K. Both materials present a magnetic order below T{sub C}=30 K and 40 K for W and Nb materials, respectively. The magneto-transport measurements display non-negligible magnetoresistance properties in the paramagnetic regime. - Graphical abstract: Comparison between the octahedron size and the magnetic behaviour for Ca{sub 3}Mn{sub 2}NbO{sub 9} in the temperature region where the charge and magnetic order occur. Display Omitted - Highlights: Two novel Mn-containing double perovskites were obtained by solid-state reactions. Both double perovskites are monoclinic (P2{sub 1}/n) determined by XRPD and NPD. Ca{sub 3}Mn{sub 2}WO{sub 9} contains Mn{sup 3+} while Ca{sub 3}Mn{sub 2}NbO{sub 9} includes mixed-valence cations Mn{sup 3+}/Mn{sup 4+}. Ca{sub 3}Mn{sub 2}NbO{sub 9} presents a charge-ordering effect between Mn{sup 3+} and Mn{sup 4+} evidenced by NPD. The magnetic and transport studies evidenced the charge ordering in Ca{sub 3}Mn{sub 2}NbO{sub 9}.

  20. Clarification of enhanced ferromagnetism in Be-codoped InMnP fabricated using Mn/InP:Be bilayers grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Shon, Yoon; Lee, Sejoon; Taek Yoon, Im; Jeon, H. C.; Lee, D. J.; Kang, T. W.; Song, J. D.; Yoon, Chong S.; Kim, D. Y.; Park, C. S.

    2011-11-07

    The p-type InMnP:Be epilayers were prepared by the sequential growth of Mn/InP:Be bilayers using molecular-beam-epitaxy and the subsequent in-situ annealing at 200-300 deg. C. In triple-axis x-ray diffraction patterns, the samples revealed a shoulder peak indicative of intrinsic InMnP. The ferromagnetic transition in InMnP:Be was observed to occur at the elevated temperature of {approx}140 K, and the ferromagnetic spin-domains clearly appeared in magnetic force microscopy images. The improved ferromagnetic properties are attributed to the increased p-d hybridation due to high p-type conductivity of InMnP:Be (p {approx} 10{sup 20 }cm{sup -3}). The results suggest that enhanced ferromagnetism can be effectively obtained from Be-codoped InMnP.

  1. Magnetic properties of α−MnO{sub 2} and Co-doped α−MnO{sub 2} nanowires

    SciTech Connect (OSTI)

    Stella, C. Soundararajan, N. Ramachandran, K.

    2014-04-24

    α−MnO{sub 2} and Co-doped α−MnO{sub 2} nanowires (NWs) were synthesized by hydrothermal method. The structural characterization by XRD revealed the tetragonal structure of α−MnO{sub 2}. The formation of one dimensional (1D) NWs of pure and Co-doped α−MnO{sub 2} was confirmed from SEM. From UV-Vis absorption spectra, it is found that both pure and Co-doped α−MnO{sub 2} NWs showed blue shift compared to bulk, which revealed the quantum confinement in the synthesized samples. The magnetic properties were analyzed by VSM, which suggest that pure and doped α−MnO{sub 2} exhibit ferromagnetic behavior at room temperature (RT)

  2. Role of t{sub 2g} electrons in Mn-Tb coupling of multiferroic TbMnO{sub 3}

    SciTech Connect (OSTI)

    Guo, Y. Y.; Wang, Y. L.; Liu, J.-M.; Wei, T.

    2014-08-14

    We investigate the effect of Cr-doping in polycrystalline TbMn{sub 1?x}Cr{sub x}O{sub 3} (x???6%) ceramics on the magnetism, ferroelectricity, and dielectricity. The Cr substitution gradually suppresses the ferroelectricity induced by the Mn spiral spin ordering, and results in a stronger modulation of polarization by magnetic field with increasing x. However, the transition temperature T{sub Tb} corresponding to onset of Tb magnetic ordering has barely shifted with Cr doping. In other words, although the Cr-doping obviously disrupts the Mn spiral spin ordering, the exchange field J{sub Mn-Tb} acting on the Tb moments from the Mn-spin structure is hardly impacted. Our work demonstrates that the e{sub g} electron of Mn{sup 3+} plays an important role in forming the Mn spiral spin order, but the f-d exchange interaction between the Mn 3d spins and the Tb 4f moments in multiferroic TbMnO{sub 3} almost involves only the t{sub 2g} electrons.

  3. Effect of Mn substitution on the transport properties of co-sputtered Fe{sub 3−x}Mn{sub x}Si epilayers

    SciTech Connect (OSTI)

    Tang, M.; Jin, C.; Bai, H. L.

    2014-11-07

    Motivated by the theoretical calculations that Fe{sub 3−x}Mn{sub x}Si can simultaneously exhibit a high spin polarization with a high Curie temperature to be applied in spintronic devices, and in order to further study the effect of Mn contents on the physical properties of Fe{sub 3−x}Mn{sub x}Si, we have investigated the effect of Mn substitution on the transport properties of epitaxial Fe{sub 3−x}Mn{sub x}Si (0≤x≤1) films systematically. The Fe{sub 3−x}Mn{sub x}Si films were epitaxially grown on MgO(001) plane with 45° rotation. The magnetization for various x shows enhanced irreversibility, implying the antiferromagnetic ordering induced by the substitution of Mn. A metal-semiconductor crossover was observed due to the enhanced disorders of interactions and the local lowering of symmetry induced by the substitution of Mn. The single-domain state in the Fe{sub 3−x}Mn{sub x}Si films leads to twofold symmetric curves of the anisotropic magnetoresistance and planar Hall resistivity.

  4. Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals

    SciTech Connect (OSTI)

    KAPLAN, DANIEL

    2005-09-13

    Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

  5. Effect of Composition and Heat Treatment on MnBi Magnetic Materials

    SciTech Connect (OSTI)

    Cui, Jun; Choi, Jung-Pyung; Polikarpov, Evgueni; Bowden, Mark E.; Xie, Wei; Li, Guosheng; Nie, Zimin; Zarkevich, Nikolai; Kramer, Matthew J.; Johnson, Duane D.

    2014-08-17

    The metallic compound MnBi is a promising rare-earth-free permanent magnet material. Compare to other rare-earth-free candidates, MnBi stands out for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. Several groups have demonstrated that the Hci of MnBi compound in thin film or in powder form can exceed 12 kOe and 26 kOe at 300 K and 523 K, respectively. Such steep increase in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. The reaction between Mn and Bi is peritectic, so Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, the composition of the Mn-Bi alloy with the largest amount of the desired LTP (low temperature phase) MnBi and highest saturation magnetization will be over-stoichiometric and rich in Mn. The amount of additional Mn required to compensate the Mn precipitation depends on solidification rate: the faster the quench speed, the less Mn precipitates. Here we report a systematic study of the effect of composition and heat treatments on the phase contents and magnetic properties of Mn-Bi alloys. In this study, Mn-Bi alloys with 14 compositions were prepared using conventional metallurgical methods such as arc melting and vacuum heat treatment, and the obtained alloys were analyzed for compositions, crystal structures, phase content, and magnetic properties. The results show that the composition with 55 at.% Mn exhibits the highest LTP MnBi content and the highest magnetization. The sample with this composition shows >90 wt.% LTP MnBi content. Its measured saturation magnetization is 68 emu/g with 2.3 T applied field at 300 K; its coercivity is 13 kOe and its energy product is 12 MGOe at 300 K. A bulk magnet fabricated using this powder exhibits an energy product of 8.2 MGOe.

  6. Magnetostructural phase transformations in Tb 1-x Mn 2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zou, Junding; Paudyal, Durga; Liu, Jing; Mudryk, Yaroslav; Pecharsky, Vitalij K.; Gschneidner, Karl A.

    2015-01-16

    Magnetism and phase transformations in non-stoichiometric Tb1-xMn2 (x = 0.056, 0.039) have been studied as functions of temperature and magnetic field using magnetization, heat capacity, and X-ray powder diffraction measurements. Lowering the temperature, the compounds sequentially order ferrimagnetically and antiferromagnetically, and finally, exhibit spin reorientation transitions. Moreover, these structural distortions from room temperature cubic to low temperature rhombohedral structures occur at TN, and are accompanied by large volume changes reaching ~-1.27% and -1.42%, respectively. First principles electronic structure calculations confirm the phase transformation from the ferrimagnetic cubic structure to the antiferromagnetic rhombohedral structure in TbMn2.

  7. ~tx22C0.ptx

    Energy Savers [EERE]

    + + + + + STUDYING THE COMMUNICATIONS REQUIREMENTS OF ELECTRIC UTILITIES TO INFORM FEDERAL SMART GRID POLICIES + + + + + PUBLIC MEETING + + + + + THURSDAY, JUNE 17, 2010 + + + + + The Public Meeting was held in Room 8E069 at the Department of Energy, Forrestal Building, 1000 Independence Avenue, S.W., Washington, D.C., at 10:00 a.m., Scott Blake Harris, Chair, presiding. PRESENT: BECKY BLALOCK SHERMAN J. ELLIOTT LYNNE ELLYN SCOTT BLAKE HARRIS JIM INGRAHAM JIM L. JONES MICHAEL LANMAN KYLE

  8. ~txF74.ptx

    Energy Savers [EERE]

    WEDNESDAY OCTOBER 19, 2011 + + + + + The Electricity Advisory Committee met in the Conference Center of the National Rural Electric Cooperative Association Headquarters, 4301 Wilson Boulevard, Arlington, Virginia, at 2:00 p.m., Richard Cowart, Chair, presiding. MEMBERS PRESENT RICHARD COWART, Regulatory Assistance Project, Chair THE HONORABLE ROBERT CURRY, New York State Public Service Commission JOSE DELGADO, American Transmission Company (Ret.) ROGER DUNCAN, Austin Energy (Ret.) ROBERT

  9. US WSC TX Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Consumption Survey www.eia.govconsumptionresidential Space heating Water heating Air conditioning Appliances, electronics, lighting Household Energy Use in Texas A ...

  10. About ZERH Sessions: Austin, TX

    Broader source: Energy.gov [DOE]

    10:00 a.m. - 12:30 p.m. An Overview: What is it, and how do I participate?This session discusses the critical components that define a truly zero energy ready home (ZERH), how builders are able to...

  11. On the state of Mn impurity implanted in Si

    SciTech Connect (OSTI)

    Orlov, A. F.; Bublik, V. T.; Vdovin, V. I.; Agafonov, Yu. A.; Balagurov, L. A.; Zinenko, V. I.; Kulemanov, I. V.; Shcherbachev, K. D.

    2009-07-15

    The state of manganese impurity in implanted silicon at implantation doses of up to 5 x 10{sup 16} cm{sup -2} has been investigated by X-ray diffraction and transmission electron microscopy. It is established that, after short-term vacuum annealing at 850{sup o}C, most of the implanted manganese impurities are in microinclusions up to 20 nm in size formed by a tetragonal silicide phase of the Mn{sub 15}Si{sub 26} type.

  12. High-pressure structural study of MnF2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stavrou, Elissaios; Yao, Yansun; Goncharov, Alexander F.; Konopkova, Zuzana; Raptis, Constantine

    2015-02-01

    In this study, manganese fluoride (MnF2) with the tetragonal rutile-type structure has been studied using a synchrotron angle-dispersive powder x-ray diffraction and Raman spectroscopy in a diamond anvil cell up to 60 GPa at room temperature combined with first-principles density functional calculations. The experimental data reveal two pressure-induced structural phase transitions with the following sequence: rutile → SrI2 type (3 GPa)→ α–PbCl2 type (13 GPa). Complete structural information, including interatomic distances, has been determined in the case of MnF2 including the exact structure of the debated first high-pressure phase. First-principles density functional calculations confirm this phase transition sequence, and themore » two calculated transition pressures are in excellent agreement with the experiment. Lattice dynamics calculations also reproduce the experimental Raman spectra measured for the ambient and high-pressure phases. The results are discussed in line with the possible practical use of rutile-type fluorides in general and specifically MnF2 as a model compound to reveal the HP structural behavior of rutile-type SiO2 (Stishovite).« less

  13. Manganese valence and coordination structure in Mn,Mg-codoped {gamma}-AlON green phosphor

    SciTech Connect (OSTI)

    Takeda, Takashi; Xie, Rong-Jun; Hirosaki, Naoto; Matsushita, Yoshitaka; Honma, Tetuso

    2012-10-15

    The valence and coordination structure of manganese in a Mn,Mg-codoped {gamma}-AlON spinel-type oxynitride green phosphor were studied by synchrotron X-ray diffraction and absorption fine structure measurements. The absorption edge position of the XANES revealed the bivalency of Mn. Two cation sites are available in the spinel structure for cation doping: a tetrahedral site and an octahedral site. The pre-edge of the XANES and the distance to the nearest neighbor atoms obtained from the EXAFS measurement showed that Mn was situated at the tetrahedral site. Rietveld analysis showed that the vacancy occupied the octahedral site. The preferential occupation of the tetrahedral site by Mn and the roles of N and Mg are discussed in relation to the spinel crystal structure. - Graphical Abstract: Fourier transform of EXAFS of Mn K-edge for Mn,Mg-codoped green phosphor and Mn coordination structure. Highlights: Black-Right-Pointing-Pointer Mn, Mg-codoped {gamma}-AlON green phosphor for white LED. Black-Right-Pointing-Pointer The valence of Mn is divalent. Black-Right-Pointing-Pointer Mn occupies the tetrahedral site in the spinel structure.

  14. Ferromagnetic interactions and martensitic transformation in Fe doped Ni-Mn-In shape memory alloys

    SciTech Connect (OSTI)

    Lobo, D. N.; Priolkar, K. R.; Emura, S.; Nigam, A. K.

    2014-11-14

    The structure, magnetic, and martensitic properties of Fe doped Ni-Mn-In magnetic shape memory alloys have been studied by differential scanning calorimetry, magnetization, resistivity, X-ray diffraction (XRD), and EXAFS. While Ni{sub 2}MnIn{sub 1?x}Fe{sub x} (0???x???0.6) alloys are ferromagnetic and non martensitic, the martensitic transformation temperature in Ni{sub 2}Mn{sub 1.5}In{sub 1?y}Fe{sub y} and Ni{sub 2}Mn{sub 1.6}In{sub 1?y}Fe{sub y} increases for lower Fe concentrations (y???0.05) before decreasing sharply for higher Fe concentrations. XRD analysis reveals presence of cubic and tetragonal structural phases in Ni{sub 2}MnIn{sub 1?x}Fe{sub x} at room temperature with tetragonal phase content increasing with Fe doping. Even though the local structure around Mn and Ni in these Fe doped alloys is similar to martensitic Mn rich Ni-Mn-In alloys, presence of ferromagnetic interactions and structural disorder induced by Fe affect Mn-Ni-Mn antiferromagnetic interactions resulting in suppression of martensitic transformation in these Fe doped alloys.

  15. Effect of composition and heat treatment on MnBi magnetic materials

    SciTech Connect (OSTI)

    Cui, Jun [Pacific Northwest National Laboratory; Choi, Jung-Pyung [Pacific Northwest National Laboratory; Polikarpov, Evgueni [Pacific Northwest National Laboratory; Bowden, Mark E [Pacific Northwest National Laboratory; Xie, Wei [Pacific Northwest National Laboratory; Li, Guosheng [Pacific Northwest National Laboratory; Nie, Zimin [Pacific Northwest National Laboratory; Zarkevich, Nikolai [Ames Laboratory; Kramer, Matthew J [Ames Laboratory; Johnson, Duane [Ames Laboratory

    2014-10-01

    The metallic compound MnBi is a promising rare-earth-free permanent magnet material, unique among all candidates for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. The Hci of MnBi in thin-film or powder form can exceed 12 and 26 kOe at 300 and 523 K, respectively. Such a steep rise in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. However, the reaction between Mn and Bi is peritectic, and hence Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, when the alloy is prepared using conventional induction or arc-melting casting methods, additional Mn is required to compensate the precipitation of Mn. In addition to composition, post-casting annealing plays an important role in obtaining a high content of MnBi low-temperature phase (LTP) because the annealing encourages the Mn precipitates and the unreacted Bi to react, forming the desired LTP phase. Here we report a systematic study of the effect of composition and heat treatments on the phase content and magnetic properties of MnBi alloys. In this study, 14 compositions were prepared using conventional metallurgical methods, and the compositions, crystal structures, phase content and magnetic properties of the resulting alloys were analyzed. The results show that the composition with 55 at.% Mn exhibits both the highest LTP content (93 wt.%) and magnetization (74 emu g?1 with 9 T applied field at 300 K).

  16. Dynamic study of (De)sodiation in alpha-MnO2 nanowires

    SciTech Connect (OSTI)

    Yuan, Yifei; Ma, Lu; He, Kun; Yao, Wentao; Nie, Anmin; Bi, Xuanxuan; Amine, Khalil; Wu, Tianpin; Lu, Jun; Shahbazian-Yassr, Reza

    2016-01-01

    In this report, the electrochemical sodiation and desodiation in single crystalline alpha-MnO2 nanowires are studied dynamically at both single particle level using in situ transmission electron microscopy (TEM) and bulk level using in situ synchrotron X-ray. The TEM results suggest that the first sodiation process starts with tunnel-based Na+ intercalation, experiences the formation of Na0.5MnO2 as a result of tunnel degradation, and ends with the Mn2O3 phase. The inserted Na+ can be partially extracted out of the sodiated products, and the following cycles are dominated by the reversible conversion reaction between Na0.5MnO2 and Mn2O3. The Mn valence evolution inside a cycling coin using alpha-MnO2 nanowire electrode also exhibits partially reversible characteristic, agreeing well with the in situ TEM analysis. The sodiation is compared with lithiation in the same alpha-MnO2 nanowires. Both Na+ and Li+ interact with the tunneled structure via a similar tunnel -driven intercalation mechanism before Mn4+ is reduced to Mn3.5+. For the following deep insertion, the tunnels survive up. to LiMnO2 (Mn3+) during lithiation, while the sodiation proceeds via a different mechanism that involves obvious phase transition and fast tunnel degradation after Mn's valence is below 3.5+. The difference in charge carrier insertion mechanisms can be ascribed to the strong interaction between the tunnel frame and inserted Na+ possessing a larger ionic size than inserted Li+.

  17. Large exchange bias enhancement in (Pt(or Pd)/Co)/IrMn/Co trilayers with ultrathin IrMn thanks to interfacial Cu dusting

    SciTech Connect (OSTI)

    Vinai, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France); Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Moritz, J. [Institut Jean Lamour, UMR 7198 CNRS - Universit de Lorraine, Bd des Aiguillettes, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Bandiera, S. [Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Prejbeanu, I. L.; Dieny, B. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France)

    2014-04-21

    The magnitude of exchange bias (H{sub ex}) at room temperature can be significantly enhanced in IrMn/Co and (Pt(or Pd)/Co)/IrMn/Co structures thanks to the insertion of an ultrathin Cu dusting layer at the IrMn/Co interface. The combination of trilayer structure and interfacial Cu dusting leads to a three-fold increase in H{sub ex} as compared to the conventional IrMn/Co bilayer structure, with an increased blocking temperature (T{sub B}) and a concave curvature of the temperature dependence H{sub ex}(T), ideal for improved Thermally Assisted-Magnetic Random Access Memory storage layer. This exchange bias enhancement is ascribed to a reduction of the spin frustration at the IrMn/Co interface thanks to interfacial Cu addition.

  18. Synthesis, characterization and electrochemical performance of Al-substituted Li₂MnO₃

    SciTech Connect (OSTI)

    Dhital, Chetan; Huq, Ashfia; Paranthaman, Mariappan Parans; Manivannan, Ayyakkannu; Torres-Castro, Loraine; Shojan, Jifi; Julien, Christian M.; Katiyar, Ram S.

    2015-08-08

    Li2MnO3 is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li2MnO3 , Li1.5Al0.17MnO3, Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 were synthesized by a sol–gel Pechini method. All the samples were characterized with x-ray diffraction, Raman, x-ray photoelectron spectroscopy, scanning electron microscopy, Tap density and BET analyzer. X-ray diffraction patterns indicated the presence of monoclinic phase for pristine Li2MnO3and mixed monoclinic/spinel phases (Li2 - xMn1 - yAlx + yO3 + z) for Al-substituted Li2MnO3compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. X-ray photoelectron spectroscopy for Mn 2p orbital reveals a significant decrease in binding energy for Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g-1 for Li2MnO3, 68 mAh g-1 for Li1.5Al0.17MnO3, 58 mAh g-1 for Li1.0Al0.33MnO3 and 74 mAh g-1 for Li0.5Al0.5MnO3 were obtained. As a result, aluminum substitutions increased the formation of spinel phase which is responsible for cycling.

  19. The magnetic origin of multiferroic Y{sub 2}CoMnO{sub 6}

    SciTech Connect (OSTI)

    Jia, Ting; Zeng, Zhi; Li, X. G.; Lin, H. Q.

    2015-05-07

    It has been found experimentally that the ferroelectricity in Y{sub 2}CoMnO{sub 6} is driven by a magnetic ordering of collinear up-up-down-down (↑↑↓↓). Here, the origin of the magnetism and thereby ferroelectricity is studied using first-principles calculations. We first confirm that the experimentally observed ↑↑↓↓ antiferromagnetic structure is the ground state of Y{sub 2}CoMnO{sub 6}. Additionally, both the Co{sup 2+} and Mn{sup 4+} are in the high-spin state. By analyzing the exchange coupling and corresponding pathways, we conclude that the ↑↑↓↓ spin order in Y{sub 2}CoMnO{sub 6} originates from a subtle competition between the ferromagnetic Co-O-Mn super-exchange and antiferromagnetic Co-Mn direct-exchange along c axis.

  20. Enhanced magnetic hysteresis in Ni-Mn-Ga single crystal and its influence

    Office of Scientific and Technical Information (OSTI)

    on magnetic shape memory effect (Journal Article) | SciTech Connect Enhanced magnetic hysteresis in Ni-Mn-Ga single crystal and its influence on magnetic shape memory effect Citation Details In-Document Search Title: Enhanced magnetic hysteresis in Ni-Mn-Ga single crystal and its influence on magnetic shape memory effect Enhanced magnetic hysteresis due to boron doping in combination with magnetic shape memory effect in Ni-Mn-Ga single crystal results in new interesting functionality of

  1. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have notmore » been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3μB/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.« less

  2. Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II

    SciTech Connect (OSTI)

    Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

    2012-08-17

    Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

  3. Cr(OH)₃(s) Oxidation Induced by Surface Catalyzed Mn(II) Oxidation

    SciTech Connect (OSTI)

    Namgung, Seonyi; Kwon, M.; Qafoku, Nikolla; Lee, Gie Hyeon

    2014-09-16

    This study examined the feasibility of Cr(OH)₃(s) oxidation mediated by surface catalyzed Mn(II) oxidation under common groundwater pH conditions as a potential pathway of natural Cr(VI) contaminations. Dissolved Mn(II) (50 μM) was reacted with or without synthesized Cr(OH)₃(s) (1.0 g/L) at pH 7 – 9 under oxic or anoxic conditions. In the absence of Cr(OH)₃(s), homogeneous Mn(II) oxidation by dissolved O₂ was not observed at pH ≤ 8.0 for 50 d. At pH 9.0, by contrast, dissolved Mn(II) was completely removed within 8 d and precipitated as hausmannite. When Cr(OH)₃(s) was present, this solid was oxidized and released substantial amounts of Cr(VI) as dissolved Mn(II) was added into the suspension at pH ≥ 8.0 under oxic conditions. Our results suggest that Cr(OH)₃(s) was readily oxidized by a newly formed Mn oxide as a result of Mn(II) oxidation catalyzed on Cr(OH)₃(s) surface. XANES analysis of the residual solids after the reaction between 1.0 g/L Cr(OH)₃(s) and 204 μM Mn(II) at pH 9.0 for 22 d revealed that the product of surface catalyzed Mn(II) oxidation resembled birnessite. The rate and extent of Cr(OH)₃(s) oxidation was likely controlled by those of surface catalyzed Mn(II) oxidation as the production of Cr(VI) increased with increasing pH and initial Mn(II) concentrations. This study evokes the potential environmental hazard of sparingly soluble Cr(OH)₃(s) that can be a source of Cr(VI) in the presence of dissolved Mn(II).

  4. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    SciTech Connect (OSTI)

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have not been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3μB/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.

  5. Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Accepted Manuscript: Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy This content will become publicly available on August 20, 2016 « Prev Next » Title: Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy Momentum resolved inverse photoemission spectroscopy measurements show that the dispersion of the unoccupied bands of Ni2MnGa is significant in the austenite phase. Furthermore, in the martensite phase, it

  6. Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy Citation Details In-Document Search This content will become publicly available on August 20, 2016 Title: Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy Momentum resolved inverse photoemission spectroscopy measurements show that the dispersion of the unoccupied bands of Ni2MnGa is significant in the austenite phase. Furthermore, in the martensite phase,

  7. CaMn2Sb2: Spin waves on a frustrated antiferromagnetic honeycomb lattice

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect CaMn2Sb2: Spin waves on a frustrated antiferromagnetic honeycomb lattice Citation Details In-Document Search Title: CaMn2Sb2: Spin waves on a frustrated antiferromagnetic honeycomb lattice We present inelastic neutron scattering measurements of the antiferromagnetic insulator CaMn2Sb2:, which consists of corrugated honeycomb layers of Mn. The dispersion of magnetic excitations has been measured along the H and L directions in reciprocal space, with a

  8. Preparation and electrochemical properties of lamellar MnO{sub 2} for supercapacitors

    SciTech Connect (OSTI)

    Yan, Jun; Wei, Tong; Cheng, Jie; Fan, Zhuangjun; Zhang, Milin

    2010-02-15

    Lamellar birnessite-type MnO{sub 2} materials were prepared by changing the pH of the initial reaction system via hydrothermal synthesis. The interlayer spacing of MnO{sub 2} with a layered structure increased gradually when the initial pH value varied from 12.43 to 2.81, while the MnO{sub 2}, composed of {alpha}-MnO{sub 2} and {gamma}-MnO{sub 2}, had a rod-like structure at pH 0.63. Electrochemical studies indicated that the specific capacitance of birnessite-type MnO{sub 2} was much higher than that of rod-like MnO{sub 2} at high discharge current densities due to the lamellar structure with fast intercalation/deintercalation of protons and high utilization of MnO{sub 2}. The initial specific capacitance of MnO{sub 2} prepared at pH 2.81 was 242.1 F g{sup -1} at 2 mA cm{sup -2} in 2 mol L{sup -1} (NH{sub 4}){sub 2}SO{sub 4} aqueous electrolyte. The capacitance increased by about 8.1% of initial capacitance after 200 cycles at a current density of 100 mA cm{sup -2}.

  9. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    Inc","AL, CA, CO, FL, GA, KY, OH, TN, TX" "Dakota Gasification Company","ND" "Eastman Chemical Company","TN" "Georgia-Pacific Consumer Products LP","AL, GA, OK, VA, WI" "Holcim ...

  10. International Falls, MN Natural Gas Pipeline Imports From Canada (Dollars

    U.S. Energy Information Administration (EIA) Indexed Site

    per Thousand Cubic Feet) Dollars per Thousand Cubic Feet) International Falls, MN Natural Gas Pipeline Imports From Canada (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 1.71 2.03 2.00 2.33 2000's 2.77 4.85 3.01 -- -- 11.20 -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S.

  11. International Falls, MN Natural Gas Pipeline Imports From Canada (Million

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Million Cubic Feet) International Falls, MN Natural Gas Pipeline Imports From Canada (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 6,373 6,544 6,103 4,857 2000's 3,022 617 602 0 0 22 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S.

  12. US ENC WI Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Consumption Survey www.eia.govconsumptionresidential Space heating Water heating Air conditioning Appliances, electronics, lighting Household Energy Use in ...

  13. RiverHeath Appleton, WI

    Office of Energy Efficiency and Renewable Energy (EERE)

    The goal of the project is to produce a closed loop neighborhood-wide geothermal exchange system using the river as the source of heat exchange.

  14. Electrochemical performance studies of MnO{sub 2} nanoflowers recovered from spent battery

    SciTech Connect (OSTI)

    Ali, Gomaa A.M.; Tan, Ling Ling; Jose, Rajan; Yusoff, Mashitah M.; Chong, Kwok Feng

    2014-12-15

    Highlights: MnO{sub 2} is recovered from spent zinccarbon batteries as nanoflowers structure. Recovered MnO{sub 2} nanoflowers show high specific capacitance. Recovered MnO{sub 2} nanoflowers show stable electrochemical cycling up to 900 cycles. Recovered MnO{sub 2} nanoflowers show low resistance in EIS data. - Abstract: The electrochemical performance of MnO{sub 2} nanoflowers recovered from spent household zinccarbon battery is studied by cyclic voltammetry, galvanostatic charge/discharge cycling and electrochemical impedance spectroscopy. MnO{sub 2} nanoflowers are recovered from spent zinccarbon battery by combination of solution leaching and electrowinning techniques. In an effort to utilize recovered MnO{sub 2} nanoflowers as energy storage supercapacitor, it is crucial to understand their structure and electrochemical performance. X-ray diffraction analysis confirms the recovery of MnO{sub 2} in birnessite phase, while electron microscopy analysis shows the MnO{sub 2} is recovered as 3D nanostructure with nanoflower morphology. The recovered MnO{sub 2} nanoflowers exhibit high specific capacitance (294 F g{sup ?1} at 10 mV s{sup ?1}; 208.5 F g{sup ?1} at 0.1 A g{sup ?1}) in 1 M Na{sub 2}SO{sub 4} electrolyte, with stable electrochemical cycling. Electrochemical data analysis reveal the great potential of MnO{sub 2} nanoflowers recovered from spent zinccarbon battery in the development of high performance energy storage supercapacitor system.

  15. Lattice Mn3+ Behaviors in Li4Ti5O12/LiNi0.5Mn1.5O4 Full Cells

    SciTech Connect (OSTI)

    Zheng, Jianming; Xiao, Jie; Nie, Zimin; Zhang, Jiguang

    2013-05-28

    High voltage spinels LiNi0.5Mn1.5O4 (LNMO) with different contents of residual Mn3+ ions have been evaluated in full cells using Li4Ti5O12 (LTO) as standard anode. Greatly improved cycling stability has been observed for all spinels in LTO-limited full cell, compared with those in LNMO-limited ones, while the underlying mechanisms are quite different. It has been discovered that the participation of active Mn3+ in the extended cycling and thus its observable contribution to Li+ diffusion kinetics depend on the limiting electrode and the sufficiency of Li+ ions. Potential Mn dissolution has also been discussed to identify the key factors that need to be considered to construct full cells employing high voltage spinel as the cathode.

  16. Room temperature spin-polarizations of Mn-based antiferromagnetic nanoelectrodes

    SciTech Connect (OSTI)

    Yamada, Toyo Kazu; Vazquez de Parga, Amadeo L.

    2014-11-03

    Antiferromagnets produce no stray field, and therefore, a tip electrode made of antiferromagnetic material has been considered to be the most suitable choice to measure such as magnetoresistance (MR) through single isolated magnetic nanoparticles, molecules, and ultrathin films. Spin polarizations (P) of antiferromagnetic 3-nm, 6-nm, and annealed 3-nm Mn films grown on W tips with a bcc(110) apex as well as bulk-NiMn tips were obtained at 300?K by measuring MR in ultrahigh vacuum by means of spin-polarized scanning tunneling microscopy using a layerwise antiferromagnetically stacking bct-Mn(001) film electrode. The Mn-coated tips with coverages of 3 and 6?nm exhibited P values of 1??1% and 3??2%, respectively, which tips likely contain ?- or strained Mn. With a thermal assist, the crystalline quality and the magnetic stability of the film could increase. The annealed tip exhibited P?=?9??2%. The bulk-NiMn tips exhibit spin polarizations of 0 or 6??2% probably depending on the chemical species (Mn or Ni) present at the apex of the tip. Fe-coated W tips were used to estimate the bct-Mn(001) film spin polarization.

  17. Impedance studies of the thin film LiMn2O4/electrolyteinterface

    SciTech Connect (OSTI)

    Striebel, Kathryn A.; Sakai, E.; Cairns, Elton J.

    2001-04-07

    Room-temperature impedance measurements of a thin-film LiMn2O4/LiPF6-EC-DMC interface have been used to identify the spontaneous formation Li2Mn2O4 at the interface at room temperature at voltages of 3.7 and higher. The impedance of the LiMn2O4 films exhibited two time constants: at about 14 kHz and 60 to 200 Hz. The high frequency loop is dependent on film morphology and was attributed to the substrate/oxide interface. The low frequency behavior was dependent on both state-of-charge (SOC) and time at a given SOC. At full charge the impedance in this electrolyte was stable at room temperature over several days. At high lithium contents, film OCV and impedance tended to grow logarithmically with time, with lower rates for lower Mn3+ content in the film. The increased impedance was removed by oxidation of the film to 4.5V vs. Li/Li+. The observations are consistent with a reversible disproportionation of part of the LiMn2O4 into Li2Mn2O4 and a lithium-deficient spinel. With extended constant current cycling part of the Li2Mn2O4 degrades to the Mn2O3 and the process is no longer reversible.

  18. Magnetic and structural properties of Zn doped MnV{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Shahi, Prashant; Shukla, K. K.; Singh, Rahul; Chatterjee, Sandip; Das, A.; Ghosh, A. K.; Nigam, A. K.

    2014-04-24

    The magnetization, Neutron diffraction and X-ray diffraction of Zn doped MnV{sub 2}O{sub 4} as a function of temperature have been measured. It has been observed, with increase of Zn the non-linear orientation of Mn spins with the V spins will decrease which effectively decrease the structural transition temperature more rapidly than Curie Temperature.

  19. Spin correlations and electron transport in MnBi:Au films

    SciTech Connect (OSTI)

    Kharel, P.; Skomski, R.; Sellmyer, D. J.

    2011-04-01

    The structural, magnetic, and electron transport properties of Mn{sub 55-x}Au{sub x}Bi{sub 45} (x = 0, 4.5) thin films prepared by magnetron sputtering have been investigated. The magnetization of the MnBi films decreases and the coercivity increases due to Au doping. The temperature dependence of resistivity between 2 to 300 K shows that the films are metallic but the 4.5% Au-doped film shows a Kondo behavior with resistance minimum at 10.2 K. The magnetoresistance is anisotropic and the positive transverse magnetoresistance is significantly enhanced (16.3% at 70 kOe) by Au doping. We interpret these data in terms of a model in which Au atoms preferentially substitute for Mn atoms on the Mn lattice, and some Mn atoms are displaced to interstitial sites in the NiAs structure. These interstitial Mn atoms are coupled antiferromagnetically to the Mn atoms on the original Mn lattice leading to the large decrease in magnetization, Kondo effect, and the positive magnetoresistance.

  20. Electric-Field Modulation of Curie Temperature in (Ga, Mn)As Field-Effect Transistor Structures with Varying Channel Thickness and Mn Compositions

    SciTech Connect (OSTI)

    Nishitani, Y.; Endo, M.; Chiba, D.; Matsukura, F.; Ohno, H.

    2010-01-04

    We have investigated the change of T{sub C} of ferromagnetic semiconductor (Ga, Mn)As by changing hole concentration p. The field effect transistor structure was utilized to change p. The relation T{sub C}propor top{sup 0.2} is obtained for three samples, despite the difference of their Mn composition and thickness, indicating that the relation holds over 2 decades of p.

  1. K and Mn co-doped BaCd{sub 2}As{sub 2}: A hexagonal structured...

    Office of Scientific and Technical Information (OSTI)

    K and Mn co-doped BaCdsub 2Assub 2: A hexagonal structured bulk diluted magnetic semiconductor with large magnetoresistance Citation Details In-Document Search Title: K and Mn ...

  2. Magnetic properties and photoabsorption of the Mn-doped CeO{sub 2} nanorods

    SciTech Connect (OSTI)

    Xia, Chuanhui; Science College of Chongqing Jiaotong University, Chongqing 400074 ; Hu, Chenguo; Chen, Peng; Wan, Buyong; He, Xiaoshan; Tian, Yongshu; Chongqing Communication College, Chongqing 400035

    2010-07-15

    Mn-doped CeO{sub 2} nanorods have been prepared from CeO{sub 2} particles through a facile composite-hydroxide-mediated (CHM) approach. The analysis from X-ray photoelectron spectroscopy indicates that the manganese doped in CeO{sub 2} exists as Mn{sup 2+}. The magnetic measurement of the Mn-doped CeO{sub 2} nanorods exhibits an enhanced ferromagnetic property at room temperature with a remanence magnetization (Mr) of 1.36 x 10{sup -3} emu/g and coercivity (Hc) of 22 Oe. Comparative UV-visible spectra reveal the shift of the absorption peak of the CeO{sub 2} from ultraviolet region to visible light region after being doped with Mn. The room temperature ferromagnetic properties and light absorption of the Mn-doped CeO{sub 2} nanorods would have potential applications in photocatalysis and building of photovoltaic devices.

  3. Giant atomic displacement at a magnetic phase transition in metastable Mn3O4

    SciTech Connect (OSTI)

    Hirai, Shigeto; Moreira Dos Santos, Antonio F; Shapiro, Max C; Molaison, Jamie J; Pradhan, Neelam; Guthrie, Malcolm; Tulk, Christopher A; Fisher, Ian R; Mao, Wendy

    2013-01-01

    We present x-ray, neutron scattering, and heat capacity data that reveal a coupled first-order magnetic and structural phase transition of the metastable mixed-valence postspinel compound Mn3O4 at 210 K. Powder neutron diffraction measurements reveal a magnetic structure in which Mn3+ spins align antiferromagnetically along the edge-sharing a axis, with a magnetic propagation vector k = [1/2,0,0]. In contrast, the Mn2+ spins, which are geometrically frustrated, do not order until a much lower temperature. Although the Mn2+ spins do not directly participate in the magnetic phase transition at 210 K, structural refinements reveal a large atomic shift at this phase transition, corresponding to a physical motion of approximately 0.25 angstrom, even though the crystal symmetry remains unchanged. This "giant" response is due to the coupled effect of built-in strain in the metastable postspinel structure with the orbital realignment of the Mn3+ ion.

  4. Scanning tunneling microscopy reveals LiMnAs is a room temperature anti-ferromagnetic semiconductor

    SciTech Connect (OSTI)

    Wijnheijmer, A. P.; Koenraad, P. M.; Marti, X.; Holy, V.; Cukr, M.; Novak, V.; Jungwirth, T.

    2012-03-12

    We performed scanning tunneling microscopy and spectroscopy on a LiMnAs(001) thin film epitaxially grown on an InAs(001) substrate by molecular beam epitaxy. While the in situ cleavage exposed only the InAs(110) non-polar planes, the cleavage continued into the LiMnAs thin layer across several facets. We combined both topography and current mappings to confirm that the facets correspond to LiMnAs. By spectroscopy we show that LiMnAs has a band gap. The band gap evidenced in this study, combined with the known Neel temperature well above room temperature, confirms that LiMnAs is a promising candidate for exploring the concepts of high temperature semiconductor spintronics based on antiferromagnets.

  5. Ferromagnetic (Ga,Mn)As nanostructures for spintronic applications

    SciTech Connect (OSTI)

    Wosinski, Tadeusz; Andrearczyk, Tomasz; Figielski, Tadeusz; Makosa, Andrzej; Wrobel, Jerzy; Sadowski, Janusz

    2013-12-04

    Magneto-resistive, cross-like nanostructures have been designed and fabricated by electron-beam lithography patterning and chemical etching from thin epitaxial layers of the ferromagnetic semiconductor (Ga,Mn)As. The nanostructures, composed of two perpendicular nanostripes crossing in the middle of their length, represent four-terminal devices, in which an electric current can be driven through any of the two nanostripes. In these devices, a novel magneto-resistive memory effect, related to a rearrangement of magnetic domain walls in the central part of the device, has been demonstrated. It consists in that the zero-field resistance of a nanostripe depends on the direction of previously applied magnetic field. The nanostructures can thus work as two-state devices providing basic elements of nonvolatile memory cells.

  6. Impedance analysis of MnCoCuO NTC ceramic

    SciTech Connect (OSTI)

    Song, S.G. . E-mail: song-ph0@wpmail.paisley.ac.uk; Ling, Z.; Placido, F.

    2005-07-12

    Impedance spectroscopy is often used to analyse the electrical properties of ceramic materials having high-resistive grain boundaries, such as ZnO and SrTiO{sub 3}. Fewer attempts have been made at using this technique for the analysis of inhomogeneous electronic ceramics consisting of grains with differing composition, such as those occurring in negative temperature coefficient (NTC) thermistors. In this study, we have attempted to adopt ac impedance spectroscopy together with other techniques to analyse an NTC thermistor ceramic material. An Mn, Co and Cu multielements transition metal oxide (MnCoCuO) ceramic was prepared by using homogeneous precipitation employing oxalic acid. This material displayed a typical NTC effect, showing an electrical resistance decrease with temperature when dc electrical measurement was performed. The ac impedance spectroscopy analysis showed that there were two peaks in impedance and conductance versus frequency plot. By using an alternative representation of impedance spectra Z'/f versus Z', three distinct relaxation frequency ranges were identified. They are believed to originate, respectively, from the electrode, phase 1 (rich-Cu phase) and phase 2 (poor-Cu phase) grains existing in this ceramic. SEM observation and EDX analysis clearly showed existence of two distinct phase grains. The resistance values were derived from phases 1 and 2 grains based on ac impedance data. The sum of the resistance values was in good agreement with that from dc measurement in the temperature range of 30-95 deg. C. The material constant, B, for the two phases was also calculated, giving 3100 and 3600 K for phases 1 and 2, respectively.

  7. Word Pro - Untitled1

    U.S. Energy Information Administration (EIA) Indexed Site

    State-Level Energy Consumption Estimates and Estimated Consumption per Capita, 2010 Consumption Consumption per Capita 14 U.S. Energy Information Administration / Annual Energy Review 2011 TX CA FL LA IL OH PA NY GA IN MI NC VA NJ TN WA KY AL MO MN WI SC OK CO IA MD AZ MA MS KS AR OR NE UT CT WV NM NV AK WY ID ND ME MT SD NH HI DE RI DC VT 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 0 2 4 6 8 10

  8. pr_a.indd

    Gasoline and Diesel Fuel Update (EIA)

    FL PADD 4: Rocky Mountain PADD 5: West Coast PADD 2: Midwest PADD 1: East Coast PADD 3: Gulf Coast PADD1A: New England PADD1B: Central Atlantic PADD1C: Lower Atlantic Petroleum Administration for Defense Districts AK HI WA OR CA NV AZ MT WY CO UT ID ND SD NE KS OK MO MN WI MI IL IN OH KY TN IA NM TX AR LA AL MS WV VA NC SC GA FL ME NH VT NY PA NJ MD DE MA CT RI

    9 A P P E N D I X A This appendix contains alphabetical listings of the variables used in the price and expenditure module of the

  9. Annual Energy Outlook 2015 - Appendix F

    Gasoline and Diesel Fuel Update (EIA)

    8 Regional maps Figure F7. Coal demand regions Figure F7. Coal Demand Regions CT,MA,ME,NH,RI,VT OH 1. NE 3. S1 4. S2 5. GF 6. OH 7. EN AL,MS MN,ND,SD IA,NE,MO,KS TX,LA,OK,AR MT,WY,ID CO,UT,NV AZ,NM 9. AM 11. C2 12. WS 13. MT 14. CU 15. ZN WV,MD,DC,DE 2. YP Region Content Region Code NY,PA,NJ VA,NC,SC GA,FL IN,IL,MI,WI Region Content Region Code 14. CU 13. MT 16. PC 15. ZN 12. WS 11. C2 9. AM 5. GF 8. KT 4. S2 7. EN 6. OH 2. YP 1. NE 3. S1 10. C1 KY,TN 8. KT 16. PC AK,HI,WA,OR,CA 10. C1

  10. Ab initio study of Fe{sub 2}MnZ (Al, Si, Ge) Heusler alloy using GGA approximation

    SciTech Connect (OSTI)

    Jain, Vivek Kumar Jain, Vishal Lakshmi, N. Venugopalan, K.

    2014-04-24

    Density functional theory based on FP-LAPW method used to investigate the electronic structure of Fe{sub 2}MnZ, shows that the total spin magnetic moment shows a trend consistent with the Slater–Pauling curve. The Fe and Mn magnetic moment depend on choice of Z element although the magnetic moment of Z element is negative and less than 0.1 μ{sub B}. Spin polarization calculations evidence 100% spin polarization for Fe{sub 2}MnSi. Fe{sub 2}MnAl and Fe{sub 2}MnGe show metallic behavior with 93%, 98% spin polarization.

  11. Quantum Anomalous Hall Effect in Hg_1-yMn_yTe Quantum Wells

    SciTech Connect (OSTI)

    Liu, Chao-Xing; Qi, Xiao-Liang; Dai, Xi; Fang, Zhong; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.

    2010-03-19

    The quantum Hall effect is usually observed when the two-dimensional electron gas is subjected to an external magnetic field, so that their quantum states form Landau levels. In this work we predict that a new phenomenon, the quantum anomalous Hall effect, can be realized in Hg{sub 1-y}Mn{sub y}Te quantum wells, without the external magnetic field and the associated Landau levels. This effect arises purely from the spin polarization of the Mn atoms, and the quantized Hall conductance is predicted for a range of quantum well thickness and the concentration of the Mn atoms. This effect enables dissipationless charge current in spintronics devices.

  12. Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy

    SciTech Connect (OSTI)

    Maniraj, M.; D?Souza, S. W.; Rai, Abhishek; Schlagel, D. L.; Lograsso, T. A.; Chakrabarti, Aparna; Barman, S. R.

    2015-08-20

    Momentum resolved inverse photoemission spectroscopy measurements show that the dispersion of the unoccupied bands of Ni2MnGa is significant in the austenite phase. Furthermore, in the martensite phase, it is markedly reduced, which is possibly related to the structural transition to an incommensurate modulated state in the martensite phase. Finally, based on the first principle calculations of the electronic structure of NiMnGa, we show that the modification of the spectral shape with surface composition is related to change in the hybridization between the Mn 3d and Ni 3d-like states that dominate the unoccupied conduction band.

  13. Pressure-Induced Metallization of the Mott Insulator MnO (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Pressure-Induced Metallization of the Mott Insulator MnO Citation Details In-Document Search Title: Pressure-Induced Metallization of the Mott Insulator MnO High-pressure electrical conductivity experiments have been performed on the Mott insulator MnO to a maximum pressure of 106 GPa. We observe a steady decrease in resistivity to 90 GPa, followed by a large, rapid decrease by a factor of 10{sup 5} between 90 and 106 GPa. Temperature cycling the sample at 87 and 106 GPa

  14. Magnetostructural phase transformations in Tb 1-x Mn 2 (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect SciTech Connect Search Results Journal Article: Magnetostructural phase transformations in Tb 1-x Mn 2 Citation Details In-Document Search Title: Magnetostructural phase transformations in Tb 1-x Mn 2 Magnetism and phase transformations in non-stoichiometric Tb1-xMn2 (x = 0.056, 0.039) have been studied as functions of temperature and magnetic field using magnetization, heat capacity, and X-ray powder diffraction measurements. Lowering the temperature, the compounds

  15. Recent progress of magnetocaloric effect and magnetic refrigerant materials of Mn compounds (invited)

    SciTech Connect (OSTI)

    Wada, H. Takahara, T.; Katagiri, K.; Ohnishi, T.; Soejima, K.; Yamashita, K.

    2015-05-07

    Magnetocaloric and related properties of Ru and Ni substituted (MnFe){sub 2}(PSi) are presented. It is found that Ru and Ni are effective doping elements to reduce the thermal hysteresis of (MnFe){sub 2}(PSi). The origin of the thermal hysteresis is discussed on the basis of a thermodynamic model. It is shown that the elastic energy is responsible for the thermal hysteresis. We also show recent developments of the production process of Mn compounds in an industrial scale.

  16. Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a

    Office of Scientific and Technical Information (OSTI)

    function of electrical resistance (Journal Article) | SciTech Connect Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a function of electrical resistance Citation Details In-Document Search Title: Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a function of electrical resistance Particle sizes of manganese oxide (β-MnO₂) powders were modified by using a mortar and pestle ground method for period of times that varied between 15-60 min. Particle size

  17. Role of Cu-Ion Doping in Cu-α-MnO2 Nanowire Electrocatalysts for the Oxygen Reduction Reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davis, Danae J.; Lambert, Timothy N.; Vigil, Julian A.; Rodriguez, Mark A.; Brumbach, Michael T.; Coker, Eric N.; Limmer, Steven J.

    2014-07-09

    The role of Cu-ion doping in α-MnO2 electrocatalysts for the oxygen reduction reaction in alkaline electrolyte was investigated. Copper doped α-MnO2 nanowires (Cu-α-MnO2) were prepared with varying amounts of Cu2+ using a solvothermal method. The electrocatalytic dataindicates that Cu-α-MnO2 nanowires have higher terminal current densities, enhanced kinetic rate constants, and improved charge transfer resistances that trend with Cu-content, exceeding values attained by α-MnO2 alone. The observed improvement in catalytic behavior correlates with an increase in Mn3+ content for the Cu-α-MnO2 nanowires. The Mn3+/Mn4+ couple is themediator for the rate-limiting redox driven O2-/OH- exchange. It is proposed that O2 adsorbs viaanmore » axial site (the eg orbital on the Mn3+ d4 ion) at the surface, or at edge defects, of the nanowireand that the increase in covalent nature of the nanowire with Cu-ion doping leads to stabilization of O2 adsorbates and faster rates of reduction. This work is applicable to other manganese oxide electrocatalysts and shows for the first time there is a correlation for manganese oxides between electrocatalytic activity for the ORR in alkaline electrolyte and an increase in Mn3+ character of the oxide.« less

  18. Planar Hall effect in Y{sub 3}Fe{sub 5}O{sub 12}/IrMn films

    SciTech Connect (OSTI)

    Zhang, X. Zou, L. K.

    2014-12-29

    The planar Hall effect of IrMn on an yttrium iron garnet (YIG = Y{sub 3}Fe{sub 5}O{sub 12}) was measured in the magnetic field rotating in the film plane. The magnetic field angular dependence of planar Hall resistance (PHR) was observed in YIG/IrMn bilayer at different temperatures, while the Gd{sub 3}Ga{sub 5}O{sub 12}/IrMn film shows constant PHR for different magnetic field angles at both 10 K and 300 K. This provides evidence that IrMn has interfacial spins which can be led by ferrimagnetic layer in YIG/IrMn structure. A hysteresis can be observed in PHR-magnetic field angle loop of YIG/IrMn film at 10 K, indicative of the irreversible switching of IrMn interfacial spins at low temperature.

  19. First-principles study of spin-transfer torque in Co{sub 2}MnSi/Al/Co{sub 2}MnSi spin-valve

    SciTech Connect (OSTI)

    Tang, Ling Yang, Zejin

    2013-11-21

    The spin-transfer torque (STT) in Co{sub 2}MnSi(CMS)/Al/Co{sub 2}MnSi spin-valve system with and without interfacial disorder is studied by a first-principles noncollinear wave-function-matching method. It is shown that in the case of clean interface the angular dependence of STT for CoCo/Al (the asymmetry parameter Λ≈4.5) is more skewed than that for MnSi/Al (Λ≈2.9), which suggests the clean CoCo/Al architecture is much more efficient for the application on radio frequency oscillation. We also find that even with interfacial disorder the spin-valve of half-metallic CMS still has a relatively large parameter Λ compared to that of conventional ferromagnet. In addition, for clean interface the in-plane torkance of MnSi/Al is about twice as large as that of CoCo/Al. However, as long as the degree of interfacial disorder is sufficiently large, the CoCo/Al and MnSi/Al will show approximately the same magnitude of in-plane torkance. Furthermore, our results demonstrate that CMS/Al/CMS system has very high efficiency of STT to switch the magnetic layer of spin-valve.

  20. X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation...

    Office of Scientific and Technical Information (OSTI)

    Ca Cluster in the Water-Oxidation Complex of Photosystem II Citation Details In-Document Search Title: X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation Complex ...

  1. File:USDA-CE-Production-GIFmaps-MN.pdf | Open Energy Information

    Open Energy Info (EERE)

    MN.pdf Jump to: navigation, search File File history File usage Minnesota Ethanol Plant Locations Size of this preview: 776 600 pixels. Full resolution (1,650 1,275...

  2. Magnetocaloric effect of Pr2Fe17-x Mn x alloys (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Title: Magnetocaloric effect of Pr2Fe17-x Mn x alloys Authors: Zhong, Xi-Chun ; Liu, Zhong-Wu ; Zeng, De-Chang ; Gschneidner, Karl A. ; Pecharsky, Vitalij K. Publication Date: ...

  3. Modeling and Characterization of the Magnetocaloric Effect in Ni2MnGa Materials

    SciTech Connect (OSTI)

    Nicholson, Don M; Odbadrakh, Khorgolkhuu; Rios, Orlando; Hodges, Jason P; Ludtka, Gerard Michael; Porter, Wallace D; Sefat, A. S.; Rusanu, Aurelian; Evans III, Boyd Mccutchen

    2012-01-01

    Magnetic shape memory alloys have great promise as magneto-caloric effect refrigerant materials due to their combined magnetic and structural transitions. Computational and experimental research is reported on the Ni2MnGa material system. The magnetic states of this system have been explored using the Wang-Landau statistical approach in conjunction with the Locally Self-consistent Multiple-Scattering (LSMS) method to explore the magnetic states responsible for the magnet-caloric effect in this material. The effects of alloying agents on the transition temperatures of the Ni2MnGa alloy were investigated using differential scanning calorimetry (DSC) and superconducting quantum interference device (SQUID). Neutron scattering experiments were performed to observe the structural and magnetic phase transformations at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL) on alloys of Ni-Mn-Ga and Ni-Mn-Ga-Cu-Fe. Data from the observations are discussed in comparison with the computational studies.

  4. In-situ Electrical Conductivity of LixMnO2 Nanowires as a Function...

    Office of Scientific and Technical Information (OSTI)

    of LixMnO2 Nanowires as a Function of "x" and Size Authors: Le, Mya ; Liu, Yu ; Wang, Hui ; Dutta, Rajen ; Yan, Wenbo ; Hemminger, John C ; Wu, Ruqian ; Penner, Reginald...

  5. Enhanced magnetic hysteresis in Ni-Mn-Ga single crystal and its...

    Office of Scientific and Technical Information (OSTI)

    crystal and its influence on magnetic shape memory effect Citation Details In-Document Search Title: Enhanced magnetic hysteresis in Ni-Mn-Ga single crystal and its influence on ...

  6. Effect of Mn substitution on the transport properties of co-sputtered...

    Office of Scientific and Technical Information (OSTI)

    on the transport properties of co-sputtered Fesub 3-xMnsub xSi epilayers Citation Details In-Document Search Title: Effect of Mn substitution on the transport properties of ...

  7. Spectroscopic properties of (PVA+ZnO):Mn{sup 2+} polymer films

    SciTech Connect (OSTI)

    Rani, Ch.; Raju, D. Siva; Bindu, S. Hima; Krishna, J. Suresh; Raju, Ch. Linga

    2015-05-15

    Electron Paramagnetic Resonance (EPR), optical absorption and infrared spectral studies have been carried out on Mn{sup 2+} ions doped in poly(vinyl alcohol) complexed with zinc oxide polymer films prepared by solution cast technique. The EPR spectra of 1 mol% Mn{sup 2+} ions doped polymer complex (PVA+ZnO) at room temperature exhibit sextet hyperfine structure (hfs), centered at 2.01. The spin-Hamiltonian parameter values indicate that the ground state of Mn{sup 2+} ion in d{sup 5} and the site symmetry around Mn{sup 2+} ions in tetragonally distorted octa hedral site. The optical absorption spectra exhibits two bands centered at 275nm at 437nm. The FTIR spectrum exhibits bands characteristic of stretching and banding vibrations of O-H, C-H and C=C groups.

  8. In operando X-ray studies of the conversion reaction in Mn3O4...

    Office of Scientific and Technical Information (OSTI)

    operando X-ray studies of the conversion reaction in Mn3O4 lithium battery anodes Citation Details In-Document Search Title: In operando X-ray studies of the conversion reaction in ...

  9. Electrochemical Performances of LiMnPO4 Synthesized from Non...

    Office of Scientific and Technical Information (OSTI)

    Li1.1MnPO4 exhibits the most stable cycling ability probably because of the existence of a trace amount of Li3PO4 impurity that functions as a solid-state electrolyte on...

  10. Synthesis and characterization of MnPS{sub 3} for hydrogen sorption

    SciTech Connect (OSTI)

    Ismail, N.; Temerk, Y.M.; El-Meligi, A.A.; Badr, M.A.; Madian, M.

    2010-05-15

    Single phase MnPS{sub 3} powder was prepared by solid state reaction between Mn, S and P carried out at 650 deg. C in evacuated silica tube. The structure, morphology and sorption characteristics of the prepared solid were investigated. The results revealed that the obtained MnPS{sub 3} compound was capable of adsorbing 3.5 wt% hydrogen at -193 deg. C and a pressure of 30 bar. Little amount of hydrogen (0.07 wt%) was adsorbed at room temperature. The hydrogen adsorption/desorption cycles at various temperatures did not result in irreversible chemical structural changes of the MnPS{sub 3} compound, but the microstructure after hydrogen cycling diminished and became finer. - Graphical abstract: Atomic building of MPS{sub 3}

  11. Large magneto-optical Kerr effect in noncollinear antiferromagnets Mn 3 X (

    Office of Scientific and Technical Information (OSTI)

    X = Rh , Ir , Pt ) (Journal Article) | SciTech Connect Large magneto-optical Kerr effect in noncollinear antiferromagnets Mn 3 X ( X = Rh , Ir , Pt ) Citation Details In-Document Search This content will become publicly available on October 25, 2016 Title: Large magneto-optical Kerr effect in noncollinear antiferromagnets Mn 3 X ( X = Rh , Ir , Pt ) Authors: Feng, Wanxiang ; Guo, Guang-Yu ; Zhou, Jian ; Yao, Yugui ; Niu, Qian Publication Date: 2015-10-26 OSTI Identifier: 1224360

  12. Phase stability of the SrMnO[subscript 3] hexagonal perovskite system at

    Office of Scientific and Technical Information (OSTI)

    high pressure and temperature (Journal Article) | SciTech Connect stability of the SrMnO[subscript 3] hexagonal perovskite system at high pressure and temperature Citation Details In-Document Search Title: Phase stability of the SrMnO[subscript 3] hexagonal perovskite system at high pressure and temperature Authors: Nielsen, Morten Bormann ; Ceresoli, Davide ; Parisiades, Paraskevas ; Prakapenka, Vitali B. ; Yu, Tony ; Wang, Yanbin ; Bremholm, Martin [1] ; UC) [2] ; ESRF) [2] ; CNR-INFM) [2]

  13. Understanding the Structural and Electronic Evolution of Li2MnO3 During

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Irradiation Via Electron Microscopy - Joint Center for Energy Storage Research November 17, 2014, Research Highlights Understanding the Structural and Electronic Evolution of Li2MnO3 During Electron Irradiation Via Electron Microscopy In-situ electron beam irradiation induces localized pockets of damage (a) and (b) characterized by the Mn atoms migrating to occupy Li sites, as shown in the annular bright field image of (c). This effect is clearly visible in an intensity line profile

  14. Verification of Anderson superexchange in MnO via magnetic pair

    Office of Scientific and Technical Information (OSTI)

    distribution function analysis and ab initio theory (Journal Article) | SciTech Connect Verification of Anderson superexchange in MnO via magnetic pair distribution function analysis and ab initio theory Citation Details In-Document Search This content will become publicly available on May 11, 2017 Title: Verification of Anderson superexchange in MnO via magnetic pair distribution function analysis and ab initio theory Here, we present a temperature-dependent atomic and magnetic pair

  15. The role of C and Mn at the austenite/pearlite reaction front during non-steady-state pearlite growth in a Fe-C-Mn steel

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aranda, M. M.; Rementeria, R.; Poplawsky, Jonathan D.; Urones-Garrote, E.; Capdevila, Carlos

    2015-04-18

    The role of C and Mn during the growth of pearlite under non-steady state conditions is analyzed by comparing the phase compositions of austenite, ferrite and cementite (γ+α+θ) through the use of transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), and atom probe tomography (APT) measurements across the austenite/pearlite interface. Furthermore, a local Mn enrichment and C depletion at the austenite/pearlite interface has been measured, which causes a change in the driving force with time during divergent pearlite growth.

  16. The structure of the Caenorhabditis elegans manganese superoxide dismutase MnSOD-3-azide complex

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hunter, Gary J.; Trinh, Chi H.; Bonetta, Rosalin; Stewart, Emma E.; Cabelli, Diane E.; Hunter, Therese

    2015-08-27

    C. elegans MnSOD-3 has been implicated in the longevity pathway and its mechanism of catalysis is relevant to the aging process and carcinogenesis. The structures of MnSOD-3 provide unique crystallographic evidence of a dynamic region of the tetrameric interface (residues 41–54). We have determined the structure of the MnSOD-3-azide complex to 1.77-Å resolution. The analysis of this complex shows that the substrate analog, azide, binds end-on to the manganese center as a sixth ligand and that it ligates directly to a third and new solvent molecule also positioned within interacting distance to the His30 and Tyr34 residues of the substratemore » access funnel. This is the first structure of a eukaryotic MnSOD-azide complex that demonstrates the extended, uninterrupted hydrogen-bonded network that forms a proton relay incorporating three outer sphere solvent molecules, the substrate analog, the gateway residues, Gln142, and the solvent ligand. This configuration supports the formation and release of the hydrogen peroxide product in agreement with the 5-6-5 catalytic mechanism for MnSOD. The high product dissociation constant k₄ of MnSOD-3 reflects low product inhibition making this enzyme efficient even at high levels of superoxide.« less

  17. Hydrothermal synthesis of Mn vanadate nanosheets and visible-light photocatalytic performance for the degradation of methyl blue

    SciTech Connect (OSTI)

    Pei, L.Z. Xie, Y.K.; Pei, Y.Q.; Jiang, Y.X.; Yu, H.Y.; Cai, Z.Y.

    2013-07-15

    Graphical abstract: - Highlights: Mn vanadate nanosheets have been synthesized by simple hydrothermal process. The formation of Mn vanadate nanosheets can be controlled by growth conditions. Mn vanadate nanosheets exhibit good photocatalytic activities for methyl blue. - Abstract: Mn vanadate nanosheets have been synthesized via a facile hydrothermal route using ammonium metavanadate and Mn acetate as the raw materials, polyvinyl pyrrolidone (PVP) as the surfactant. X-ray diffraction (XRD) shows that the Mn vanadate nanosheets are composed of monoclinic MnV{sub 2}O{sub 6} phase. Scanning electron microscopy (SEM) observation indicates that the nanosheets have the average thickness of about 50 nm, length of 210 ?m and width of 800 nm to 2 ?m. The growth process of the Mn vanadate nanosheets has also been discussed based on the analysis of the roles of the growth conditions on the formation of the Mn vanadate nanosheets. The nanosheets show good photocatalytic activities for the degradation of methylene blue (MB) under visible light irradiation. About 72.96% MB can be degraded after visible light irradiation for 1 h over 10 mg Mn vanadate nanosheets in 10 mL MB solution with the concentration of 10 mg L{sup ?1}.

  18. Inverse magnetocaloric effect in Mn{sub 2}NiGa and Mn{sub 1.75}Ni{sub 1.25}Ga magnetic shape memory alloys

    SciTech Connect (OSTI)

    Singh, Sanjay Barman, S. R.; Esakki Muthu, S.; Arumugam, S.; Senyshyn, A.; Rajput, P.; Suard, E.

    2014-02-03

    Inverse magnetocaloric effect is demonstrated in Mn{sub 2}NiGa and Mn{sub 1.75}Ni{sub 1.25}Ga magnetic shape memory alloys. The entropy change at the martensite transition is larger in Mn{sub 1.75}Ni{sub 1.25}Ga, and it increases linearly with magnetic field in both the specimens. Existence of inverse magnetocaloric effect is consistent with the observation that magnetization in the martensite phase is smaller than the austenite phase. Although the Mn content is smaller in Mn{sub 1.75}Ni{sub 1.25}Ga, from neutron diffraction, we show that the origin of inverse magnetocaloric effect is the antiferromagnetic interaction between the Mn atoms occupying inequivalent sites.

  19. U.S. Total Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    CA Otay Mesa, CA Alamo, TX Clint, TX Del Rio, TX Eagle Pass, TX El Paso, TX Freeport, TX Hidalgo, TX Laredo, TX McAllen, TX Penitas, TX Rio Bravo, TX Rio Grande, TX Roma, TX Total ...

  20. Synthesis of spherical LiMnPO{sub 4}/C composite microparticles

    SciTech Connect (OSTI)

    Bakenov, Zhumabay; Taniguchi, Izumi

    2011-08-15

    Highlights: {yields} We could prepare LiMnPO{sub 4}/C composites by a novel preparation method. {yields} The LiMnPO{sub 4}/C composites were spherical particles with a mean diameter of 3.65 {mu}m. {yields} The LiMnPO{sub 4}/C composite cathode exhibited 112 mAh g{sup -1} at 0.05 C. {yields} It also showed a good rate capability up to 5 C at room temperature and 55 {sup o}C. -- Abstract: Spherical LiMnPO{sub 4}/C composite microparticles were prepared by a combination of spray pyrolysis and spray drying followed by heat treatment and examined as a cathode material for lithium batteries. The structure, morphology and electrochemical performance of the resulting spherical LiMnPO{sub 4}/C microparticles were characterized by X-ray diffraction, field-emission scanning electron microscopy, transmission electronic microscopy and standard electrochemical techniques. The final sample was identified as a single phase orthorhombic structure of LiMnPO{sub 4} and spherical powders with a geometric mean diameter of 3.65 {mu}m and a geometric standard deviation of 1.34. The electrochemical cells contained the spherical LiMnPO{sub 4}/C microparticles exhibited first discharge capacities of 112 and 130 mAh g{sup -1} at 0.05 C at room temperature and 55 {sup o}C, respectively. These also showed a good rate capability up to 5 C at room temperature and 55 {sup o}C.

  1. Electron scattering mechanisms in Cu-Mn films for interconnect applications

    SciTech Connect (OSTI)

    Misjk, F.; Nagy, K. H.; Radnczi, G.; Lobotka, P.

    2014-08-28

    Electrical properties and corresponding structural features of Cu-Mn alloy films with potential application as barrier and interconnect layers were studied. Cu-Mn films were deposited by DC magnetron sputtering at room temperature on SiO{sub 2} substrates. Electrical resistivity measurements were made as a function of film composition and temperature. The specific resistivity varies linearly with the Mn content showing a maximum of 205???cm at 80 at. % Mn. The temperature coefficient of resistance (TCR) of all alloy films is low, showing non-metallic conductivity for most compositions. Also a minimum TCR has been observed in the 4080 at. % Mn range which was attributed to a magnetic transformation around 200300?K. Electrical resistivity measurements are correlated with the film structure revealed by transmission electron microscopy to clarify the phase regions throughout the composition range. In the 2040 at. % and 7080 at. % Mn ranges, two-phase structures were identified, where Cu- or Mn-rich solid solution grains were surrounded by a thin amorphous covering layer. Based on the revealed phase regions and morphologies electron scattering mechanisms in the system were evaluated by combining the Matthiessen's rule and the Mayadas-Schatzkes theory. Grain boundary reflectivity coefficients (r?=?0.60.8) were calculated from fitting the model to the measurements. The proposed model indicates that, in a binary system, the special arrangement of the two phases results in new scattering mechanisms. The results are of value in optimizing the various parameters needed to produce a suitable barrier layer.

  2. Properties of Ga{sub 1-x}Mn{sub x}As with high x (>0.1)

    SciTech Connect (OSTI)

    Chiba, D.; Yu, K. M.; Walukiewicz, W.; Nishitani, Y.; Matsukura, F.; Ohno, H.

    2008-04-01

    We have investigated the magnetic and the crystalline properties of a set of Ga{sub 1-x}Mn{sub x}As layers with high nominal Mn compositions (x=0.101-0.198). Magnetization measurements and combined channeling Rutherford backscattering (c-RBS) and particle induced x-ray emission (c-PIXE) measurements have been performed to determine the effective Mn composition x{sub eff} and the fraction of Mn atoms at various lattice sites. Here, x{sub eff} determined from magnetization measurements, which increases with increasing x, is consistent with the results determined from c-RBS-PIXE measurements.

  3. Mn-Stabilized Zirconia: From Imitation Diamonds to a New Potential High-T{sub C} Ferromagnetic Spintronics Material

    SciTech Connect (OSTI)

    Ostanin, S.; Ernst, A.; Sandratskii, L. M.; Bruno, P.; Daene, M.; Hergert, W.; Mertig, I.; Hughes, I. D.; Staunton, J. B.; Kudrnovsky, J.

    2007-01-05

    From the basis of ab initio electronic structure calculations which include the effects of thermally excited magnetic fluctuations, we predict Mn-stabilized cubic zirconia to be ferromagnetic above 500 K. We find this material, which is well known both as an imitation diamond and as a catalyst, to be half-metallic with the majority and minority spin Mn impurity states lying in zirconia's wide gap. The Mn concentration can exceed 40%. The high-T{sub C} ferromagnetism is robust to oxygen vacancy defects and to how the Mn impurities are distributed on the Zr fcc sublattice. We propose this ceramic as a promising future spintronics material.

  4. Peculiarly strong room-temperature ferromagnetism from low Mn-doping in ZnO grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Zuo Zheng; Morshed, Muhammad; Liu Jianlin; Beyermann, W. P.; Zheng Jianguo; Xin Yan

    2013-03-15

    Strong room-temperature ferromagnetism is demonstrated in single crystalline Mn-doped ZnO thin films grown by molecular beam epitaxy. Very low Mn doping concentration is investigated, and the measured magnetic moment is much larger than what is expected for an isolated ion based on Hund's rules. The ferromagnetic behavior evolves with Mn concentration. Both magnetic anisotropy and anomalous Hall effect confirm the intrinsic nature of ferromagnetism. While the Mn dopant plays a crucial role, another entity in the system is needed to explain the observed large magnetic moments.

  5. Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ∞} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4−x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1−x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution

    SciTech Connect (OSTI)

    West, J. Palmer; Sulejmanovic, Dino; Becht, Gregory; He, Jian; Hitchcock, Dale; Yan, Yonggao; Hwu, Shiou-Jyh

    2013-10-15

    Crystals of Sr{sub 4−x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x∼0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x∼0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ∞} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4−x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1−x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-Jahn–Teller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4−x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1−x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: • Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. • Solid solution with respect to statistical disorder of Sr{sub 1−x}Ln{sub x} in one of the two Sr sites. • Mn{sup 3+}/Mn{sup 4+} magnetic ions are spatially arranged in a triangular kagomé fashion. • Enhanced ferromagnetic ordering attributed to doping non-Jahn–Teller Mn{sup 4+}.

  6. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect (OSTI)

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-05-15

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles [1-2], among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials [3] and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique [4], including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

  7. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect (OSTI)

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-10-12

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles, among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique, including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

  8. Disorder dependent half-metallicity in Mn{sub 2}CoSi inverse Heusler alloy

    SciTech Connect (OSTI)

    Singh, Mukhtiyar; Saini, Hardev S.; Thakur, Jyoti; Reshak, Ali H.; Kashyap, Manish K.

    2013-12-15

    Heusler alloys based thin-films often exhibit a degree of atomic disorder which leads to the lowering of spin polarization in spintronic devices. We present ab-initio calculations of atomic disorder effects on spin polarization and half-metallicity of Mn{sub 2}CoSi inverse Heusler alloy. The five types of disorder in Mn{sub 2}CoSi have been proposed and investigated in detail. The A2{sub a}-type and B2-type disorders destroy the half-metallicity whereas it sustains for all disorders concentrations in DO{sub 3a}- and A2{sub b}-type disorder and for smallest disorder concentration studied in DO{sub 3b}-type disorder. Lower formation energy/atom for A2{sub b}-type disorder than other four disorders in Mn{sub 2}CoSi advocates the stability of this disorder. The total magnetic moment shows a strong dependence on the disorder and the change in chemical environment. The 100% spin polarization even in the presence of disorders explicitly supports that these disorders shall not hinder the use of Mn{sub 2}CoSi inverse Heusler alloy in device applications. - Graphical abstract: Minority-spin gap (E{sub g↓}) and HM gap (E{sub sf}) as a function of concentrations of various possible disorder in Mn{sub 2}CoSi inverse Heusler alloy. The squares with solid line (black color)/dotted line (blue color)/dashed line (red color) reperesents E{sub g↓} for DO{sub 3a}-/DO{sub 3b}-/A2{sub b}-type disorder in Mn{sub 2}CoSi and the spheres with solid line (black color)/dottedline (blue color)/dashed line (red color) represents E{sub sf} for DO{sub 3a}-/DO{sub 3b}-/A2{sub b}-type disorder in Mn{sub 2}CoSi. - Highlights: • The DO{sub 3}- and A2-type disorders do not affect the half-metallicity in Mn{sub 2}CoSi. • The B2-type disorder solely destroys half-metallicity in Mn{sub 2}CoSi. • The A2-type disorder most probable to occur out of all three types. • The total spin magnetic moment strongly depends on the disorder concentrations.

  9. Novel Solar Energy Conversion Materials by Design of Mn(II) Oxides

    SciTech Connect (OSTI)

    Lany, S.; Peng, H.; Ndione, P.; Zakutayev, A.; Ginley, D. S.

    2013-01-01

    Solar energy conversion materials need to fulfill simultaneously a number of requirements in regard of their band-structure, optical properties, carrier transport, and doping. Despite their desirable chemical properties, e.g., for photo-electrocatalysis, transition-metal oxides usually do not have desirable semiconducting properties. Instead, oxides with open cation d-shells are typically Mott or charge-transfer insulators with notoriously poor transport properties, resulting from large effective electron/hole masses or from carrier self-trapping. Based on the notion that the electronic structure features (p-d interaction) supporting the p-type conductivity in d10 oxides like Cu2O and CuAlO2 occurs in a similar fashion also in the d5 (high-spin) oxides, we recently studied theoretically the band-structure and transport properties of the prototypical binary d5 oxides MnO and Fe2O3 [PRB 85, 201202(R)]. We found that MnO tends to self-trap holes by forming Mn+III, whereas Fe2O3 self-traps electrons by forming Fe+II. However, the self-trapping of holes is suppressed by when Mn is tetrahedrally coordinated, which suggests specific routes to design novel solar conversion materials by considering ternary Mn(II) oxides or oxide alloys. We are presenting theory, synthesis, and initial characterization for these novel energy materials.

  10. Extended magnetic exchange interactions in the high-temperature ferromagnet MnBi

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Christianson, Andrew D.; Hahn, Steven E.; Fishman, Randy Scott; Parker, David S.; McGuire, Michael A.; Sales, Brian C.; Lumsden, Mark D.; Williams, T. J.; Taylor, A. E.

    2016-05-09

    Here, the high-temperature ferromagnet MnBi continues to receive attention as a candidate to replace rare-earth-containing permanent magnets in applications above room temperature. This is due to a high Curie temperature, large magnetic moments, and a coercivity that increases with temperature. The synthesis of MnBi also allows for crystals that are free of interstitial Mn, enabling more direct access to the key interactions underlying the physical properties of binary Mn-based ferromagnets. In this work, we use inelastic neutron scattering to measure the spin waves of MnBi in order to characterize the magnetic exchange at low temperature. Consistent with the spin reorientationmore » that occurs below 140~K, we do not observe a spin gap in this system above our experimental resolution. A Heisenberg model was fit to the spin wave data in order to characterize the long-range nature of the exchange. It was found that interactions up to sixth nearest neighbor are required to fully parameterize the spin waves. Surprisingly, the nearest-neighbor term is antiferromagnetic, and the realization of a ferromagnetic ground state relies on the more numerous ferromagnetic terms beyond nearest neighbor, suggesting that the ferromagnetic ground state arises as a consequence of the long-ranged interactions in the system.« less

  11. High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy

    SciTech Connect (OSTI)

    Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

    2007-08-01

    The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

  12. Electronic structure and the origin of the Dzyaloshinskii-Moriya interaction in MnSi

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Satpathy, S.; Shanavas, K. V.

    2016-05-02

    Here, the metallic helimagnet MnSi has been found to exhibit skyrmionic spin textures when subjected to magnetic fields at low temperatures. The Dzyaloshinskii-Moriya (DM) interaction plays a key role in stabilizing the skyrmion state. With the help of first-principles calculations, crystal field theory and a tight-binding model we study the electronic structure and the origin of the DM interaction in the B20 phase of MnSi. The strength ofmore » $$\\vec{D}$$ parameter is determined by the magnitude of the spin-orbit interaction and the degree of orbital mixing, induced by the symmetry-breaking distortions in the B20 phase. We find that, strong coupling between Mn-$d$ and Si-$p$ states lead to a mixed valence ground state $$|d^{7-x}p^{2+x}\\rangle$$ configuration. The experimental magnetic moment of $$0.4~\\mu_B$$ is consistent with the Coulomb-corrected DFT+$U$ calculations, which redistributes electrons between the majority and minority spin channels. We derive the magnetic interaction parameters $J$ and $$\\vec{D}$$ for Mn-Si-Mn superexchange paths using Moriya's theory assuming the interaction to be mediated by $e_g$ electrons near the Fermi level. Using parameters from our calculations, we get reasonable agreement with the observations.« less

  13. Electronic structural and magnetic properties of Mn{sub 5}Ge{sub 3} clusters

    SciTech Connect (OSTI)

    Yuan, H. K.; Chen, H. Kuang, A. L.; Tian, C. L.; Wang, J. Z.

    2013-11-28

    Theoretical understanding of the stability, ferromagnetism, and spin polarization of Mn{sub 5}Ge{sub 3} clusters has been performed by using the density functional theory with generalized gradient approximation for exchange and correlation. The magnetic moments and magnetic anisotropy energy (MAE) have been calculated for both bulk and clusters, and the enhanced magnetic moment as well as the enlarged MAE have been identified in clusters. The most attractive achievement is that Mn{sub 5}Ge{sub 3} clusters show a fine half-metallic character with large energy scales. The present results may have important implications for potential applications of small Mn{sub 5}Ge{sub 3} clusters as both emerging spintronics and next-generation data-storage technologies.

  14. Elasticity and magnetocaloric effect in MnFe4Si3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Herlitschke, Marcus; Klobes, B.; Sergueev, I.; Hering, Paul; Persson, Joerg; Hermann, Raphael P.

    2016-03-16

    The room temperature magnetocaloric material MnFe4Si3 was investigated with nuclear inelastic scattering (NIS) and resonant ultrasound spectroscopy (RUS) at different temperatures and applied magnetic fields in order to assess the infuence of the magnetic transition and the magnetocaloric effect on the lattice dynamics. The NIS data give access to phonons with energies above 3 meV, whereas RUS probes the elasticity of the material in the MHz frequency range and thus low energy, ~5 neV, phonon modes. A significant infuence of the magnetic transition on the lattice dynamics is observed only in the low energy region. Here, MnFe4Si3 and other compoundsmore » in the Mn5-xFexSi3 series were also investigated with vibrating sample magnetometry, resistivity measurements and Moessbauer spectroscopy in order to study the magnetic transitions and to complement the obtained results on the lattice dynamics.« less

  15. Anomalous magnetic configuration of Mn{sub 2}NiAl ribbon and the role of hybridization in the martensitic transformation of Mn{sub 50}Ni{sub 50−x}Al{sub x} ribbons

    SciTech Connect (OSTI)

    Zhao, R. B.; Zhao, D. W.; Li, G. K.; Ma, L. E-mail: houdenglu@mail.hebtu.edu.cn; Zhen, C. M.; Hou, D. L. E-mail: houdenglu@mail.hebtu.edu.cn; Wang, W. H.; Liu, E. K.; Chen, J. L.; Wu, G. H.

    2014-12-08

    The magnetic configuration of Mn{sub 2}NiAl ribbon has been investigated. In contrast to Ni{sub 2}MnAl, the compound Mn{sub 2}NiAl with considerable disorder does exhibit ferromagnetism and, due to exchange interaction competition, both ferromagnetic and antiferromagnetic moment orientations can coexist between nearest neighbor Mn atoms. This is unexpected in Heusler alloys. Regarding the mechanism of the martensitic transformation in Mn{sub 50}Ni{sub 50−x}Al{sub x}, it is found that increasing the Al content results in an unusual change in the lattice constant, a decrease of the transformation entropy change, and enhancement of the calculated electron localization. These results indicate that the p-d covalent hybridization between Mn (or Ni) and Al atoms gradually increases at the expense of the d-d hybridization between Ni and Mn atoms. This leads to an increased stability of the austenite phase and a decrease of the martensitic transformation temperature. For 11 ≤ x ≤ 14, Mn{sub 50}Ni{sub 50−x}Al{sub x} ferromagnetic shape memory alloys are obtained.

  16. Enhanced performance of branched TiO{sub 2} nanorod based Mn-doped CdS and Mn-doped CdSe quantum dot-sensitized solar cell

    SciTech Connect (OSTI)

    Kim, Soo-Kyoung; Gopi, Chandu V. V. M.; Lee, Jae-Cheol; Kim, Hee-Je

    2015-04-28

    TiO{sub 2} branched nanostructures could be efficient as photoanodes for quantum dot-sensitized solar cells (QDSCs) due to their large surface area for QD deposition. In this study, Mn-doped CdS/Mn-doped CdSe deposited branched TiO{sub 2} nanorods were fabricated to enhance the photovoltaic performance of QDSCs. Mn doping in CdS and CdSe retards the recombination losses of electrons, while branched TiO{sub 2} nanorods facilitate effective electron transport and compensate for the low surface area of the nanorod structure. As a result, the charge-transfer resistance (R{sub CT}), electron lifetime (?{sub e}), and the amount of QD deposition were significantly improved with branched TiO{sub 2} nanorod based Mn-doped CdS/Mn-doped CdSe quantum dot-sensitized solar cell.

  17. Perpendicularly magnetized {tau}-MnAl (001) thin films epitaxied on GaAs

    SciTech Connect (OSTI)

    Nie, S. H.; Zhu, L. J.; Lu, J.; Pan, D.; Wang, H. L.; Yu, X. Z.; Xiao, J. X.; Zhao, J. H.

    2013-04-15

    Perpendicularly magnetized {tau}-MnAl films have been epitaxied on GaAs (001) by molecular-beam epitaxy. Crystalline quality and magnetic properties of the samples were strongly dependent on growth temperature. The highest coercivity of 10.7 kOe, saturation magnetization of 361.4 emu/cm{sup 3}, perpendicular magnetic anisotropy constant of 13.65 Merg/cm{sup 3}, and magnetic energy product of 4.44 MGOe were achieved. These tunable magnetic properties make MnAl films valuable as excellent and cost-effective alternative for not only high density perpendicular magnetic recording storage and spintronics devices but also permanent magnets.

  18. In operando X-ray studies of the conversion reaction in Mn3O4 lithium

    Office of Scientific and Technical Information (OSTI)

    battery anodes (Journal Article) | SciTech Connect operando X-ray studies of the conversion reaction in Mn3O4 lithium battery anodes Citation Details In-Document Search Title: In operando X-ray studies of the conversion reaction in Mn3O4 lithium battery anodes Authors: Lowe, Michael A. ; Gao, Jie ; Abruña, Héctor D. Publication Date: 2013-01-01 OSTI Identifier: 1080663 DOE Contract Number: SC0001086 Resource Type: Journal Article Resource Relation: Journal Name: J. Mater. Chem. A; Journal

  19. Magnetically nanostructured state in a Ni-Mn-Sn shape-memory alloy (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | DOE PAGES Publisher's Accepted Manuscript: Magnetically nanostructured state in a Ni-Mn-Sn shape-memory alloy This content will become publicly available on June 15, 2016 « Prev Next » Title: Magnetically nanostructured state in a Ni-Mn-Sn shape-memory alloy Authors: Yuan, S. ; Kuhns, P. L. ; Reyes, A. P. ; Brooks, J. S. ; Hoch, M. J. R. ; Srivastava, V. ; James, R. D. ; El-Khatib, S. ; Leighton, C. Publication Date: 2015-06-16 OSTI Identifier: 1184888 Grant/Contract Number:

  20. Magnetically nanostructured state in a Ni-Mn-Sn shape-memory alloy (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Magnetically nanostructured state in a Ni-Mn-Sn shape-memory alloy Citation Details In-Document Search This content will become publicly available on June 15, 2016 Title: Magnetically nanostructured state in a Ni-Mn-Sn shape-memory alloy Authors: Yuan, S. ; Kuhns, P. L. ; Reyes, A. P. ; Brooks, J. S. ; Hoch, M. J. R. ; Srivastava, V. ; James, R. D. ; El-Khatib, S. ; Leighton, C. Publication Date: 2015-06-16 OSTI Identifier: 1184888 Grant/Contract Number:

  1. Multiscale twin hierarchy in NiMnGa shape memory alloys with Fe and Cu

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Multiscale twin hierarchy in NiMnGa shape memory alloys with Fe and Cu This content will become publicly available on April 30, 2017 « Prev Next » Title: Multiscale twin hierarchy in NiMnGa shape memory alloys with Fe and Cu Authors: Barabash, Rozaliya I. ; Barabash, Oleg M. ; Popov, Dmitry ; Shen, Guoyin ; Park, Changyong ; Yang, Wenge Publication Date: 2015-04-01 OSTI Identifier: 1250957 Grant/Contract Number: FG02-99ER45775; NA0001974 Type: Publisher's

  2. Fabrication of (Mn,Co)3O4 Surface Coatings onto Alloy Substrates

    SciTech Connect (OSTI)

    Yang, Zhenguo; Xia, Guanguang; Li, Xiaohong S.; Singh, Prabhakar; Stevenson, Jeffry W.

    2007-04-30

    Ferritic stainless steels are promising candidates for IT-SOFC interconnect applications due to their low cost and resistance to oxidation at SOFC operating temperatures. However, several challenges remain, including long term electrical conductivity and surface stability under interconnect exposure conditions and chromia scale evaporation. One means of extending interconnect lifetime and improving performance is to apply a protective coating, such as (Mn,Co)3O4 spinel, to the cathode side of the interconnect. These coatings have proven effective in reducing scale growth kinetics and Cr volatility. This report describes several procedures developed at PNNL for fabricating (Mn,Co)3O4 spinel coatings onto ferritic stainless steels.

  3. Graphene in proximity to magnetic insulating LaMnO{sub 3}

    SciTech Connect (OSTI)

    Cheng, Guanghui; Wei, Laiming, E-mail: laiming@ustc.edu.cn, E-mail: cgzeng@ustc.edu.cn; Cheng, Long; Liang, Haixing; Zhang, Xiaoqiang; Li, Hui [Hefei National Laboratory for Physical Sciences at the Microscale (HFNL) and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Yu, Guolin [Shanghai Institute of Technical Physics, Chinese Academy of Science, Shanghai 200083 (China); Zeng, Changgan, E-mail: laiming@ustc.edu.cn, E-mail: cgzeng@ustc.edu.cn [Hefei National Laboratory for Physical Sciences at the Microscale (HFNL) and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); International Center for Quantum Design of Functional Materials (ICQD), HFNL, University of Science and Technology of China, Hefei, Anhui 230026 (China); Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China)

    2014-09-29

    Proximity to functional substrates may enhance the coupling between the quantum degrees of freedom and thus develop nontrivial quantum effects in graphene. Here, we demonstrate the successful fabrication of graphene in proximity to atomically flat magnetic insulating LaMnO{sub 3} films. The insulating nature of the LaMnO{sub 3} films not only ensures the electronic transport only occur in the graphene layers but also allow them to serve as dielectric layers for gating. Transport measurements reveal anomalous behaviors, including asymmetrical longitudinal magnetoresistivity and nonlinear Hall effect. This work may pave a way toward the realization of intriguing quantum phases in graphene.

  4. DOE Zero Energy Ready Home Case Study: Amaris Custom Homes, St. Paul, MN |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Custom Homes, St. Paul, MN DOE Zero Energy Ready Home Case Study: Amaris Custom Homes, St. Paul, MN In this project, the NorthernSTAR Building America Partnership team worked with Amaris Custom Homes to develop the first Zero Energy Ready Home in Minnesota's cold climate using reasonable, cost-effective, and replicable construction materials and practices. The result is a passive solar, super-efficient 3542-ft2 walkout ranch-style home with all the creature comforts. PDF

  5. Study of structural and electronic properties of Mn{sub 3}O{sub 4}

    SciTech Connect (OSTI)

    Kaur, Ramandeep Maitra, Tulika Nautiyal, Tashi

    2014-04-24

    Using density functional theory calculations we have examined the structural and electronic properties of magnetic spinel Mn{sub 3}O{sub 4}. We have optimized the structure (both volume and c/a ratio) within GGA. Then Coulomb correlations are included in the calculations to study the electronic properties. We observe that both the band gap and magnetic moment increase with the increase in Coulomb correlation due to the increased Jahn-Teller splitting and localization of the single e{sub g} electron of Mn{sup 3+}.

  6. Structural transformations in Mn{sub 2}NiGa due to residual stress

    SciTech Connect (OSTI)

    Singh, Sanjay; Maniraj, M.; D'Souza, S. W.; Barman, S. R.; Ranjan, R.

    2010-02-22

    Powder x-ray diffraction study of Mn{sub 2}NiGa ferromagnetic shape memory alloy shows the existence of a 7M monoclinic modulated structure at room temperature (RT). The structure of Mn{sub 2}NiGa is found to be highly dependent on residual stress. For higher stress, the structure is tetragonal at RT, and for intermediate stress it is 7M monoclinic. However, only when the stress is considerably relaxed, the structure is cubic, as is expected at RT since the martensitic transition temperature is 230 K.

  7. Pressure-Induced Metallization of the Mott Insulator MnO (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Pressure-Induced Metallization of the Mott Insulator MnO Citation Details In-Document Search Title: Pressure-Induced Metallization of the Mott Insulator MnO × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. A paper copy of this

  8. Modeling and Characterization of the Magnetocaloric Effect in Ni2MnGa Materials

    SciTech Connect (OSTI)

    Nicholson, Don M; Odbadrakh, Khorgolkhuu; Shassere, Benjamin; Rios, Orlando; Hodges, Jason P; Ludtka, Gerard Michael; Porter, Wallace D; Safa-Sefat, Athena; Rusanu, Aurelian; Brown, Greg; Evans III, Boyd Mccutchen

    2014-01-01

    Magnetic shape memory alloys have great promise as magneto-caloric effect refrigerant materials due to their combined magnetic and structural transitions. Computational and experimental research is reported on the Ni2MnGa material system. The magnetic states of this system are explored using the Wang-Landau statistical approach in conjunction with the Locally Self-consistent Multiple-Scattering method. The effects of alloying agents on the transition temperatures of the Ni2MnGa alloy are investigated using differential scanning calorimetry and superconducting quantum interference device. Experiments are performed at the Spallation Neutron Source at Oak Ridge National Laboratory to observe the structural and magnetic phase transformations.

  9. Dy-Mn-Si as a representative of family of 'Dy-Transition

    Office of Scientific and Technical Information (OSTI)

    Metal-Si' systems: Its isothermal sections, empirical rProd. Type: FTPules and new rare-earth manganese silicides (Journal Article) | SciTech Connect Dy-Mn-Si as a representative of family of 'Dy-Transition Metal-Si' systems: Its isothermal sections, empirical rProd. Type: FTPules and new rare-earth manganese silicides Citation Details In-Document Search Title: Dy-Mn-Si as a representative of family of 'Dy-Transition Metal-Si' systems: Its isothermal sections, empirical rProd. Type: FTPules

  10. Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Accepted Manuscript: Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films Title: Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films The orbital two-channel Kondo effect displaying exotic non-Fermi liquid behaviour arises in the intricate scenario of two conduction electrons compensating a pseudo-spin-1/2 impurity of two-level system. Despite extensive efforts for several decades, no material system has been clearly

  11. Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films Citation Details In-Document Search Title: Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films The orbital two-channel Kondo effect displaying exotic non-Fermi liquid behaviour arises in the intricate scenario of two conduction electrons compensating a pseudo-spin-1/2 impurity of two-level system. Despite extensive efforts for several decades,

  12. Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films Citation Details In-Document Search Title: Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional

  13. MnO spin-wave dispersion curves from neutron powder diffraction

    SciTech Connect (OSTI)

    Goodwin, Andrew L.; Dove, Martin T.; Tucker, Matthew G.; Keen, David A.

    2007-02-15

    We describe a model-independent approach for the extraction of spin-wave dispersion curves from powder neutron total scattering data. Our approach is based on a statistical analysis of real-space spin configurations to calculate spin-dynamical quantities. The RMCPROFILE implementation of the reverse Monte Carlo refinement process is used to generate a large ensemble of supercell spin configurations from MnO powder diffraction data collected at 100 K. Our analysis of these configurations gives spin-wave dispersion curves for MnO that agree well with those determined independently using neutron triple-axis spectroscopic techniques.

  14. Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a

    Office of Scientific and Technical Information (OSTI)

    function of electrical resistance (Journal Article) | SciTech Connect Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a function of electrical resistance Citation Details In-Document Search Title: Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a function of electrical resistance × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is

  15. X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation Complex

    Office of Scientific and Technical Information (OSTI)

    of Photosystem II (Journal Article) | SciTech Connect X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation Complex of Photosystem II Citation Details In-Document Search Title: X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation Complex of Photosystem II No abstract prepared. Authors: Sauer, K. ; Yano, J. ; Yachandra, V.K. ; /UC, Berkeley /LBL, Berkeley Publication Date: 2007-08-08 OSTI Identifier: 912555 Report Number(s): SLAC-REPRINT-2005-323 TRN: US200801%%922

  16. Enlarged Mn 3s splitting and room-temperature ferromagnetism in epitaxially grown oxygen doped Mn{sub 2}N{sub 0.86} films

    SciTech Connect (OSTI)

    Meng, M.; Wu, S. X. Ren, L. Z.; Zhou, W. Q.; Wang, Y. J.; Wang, G. L.; Li, S. W.

    2014-11-07

    Single-phase and oxygen doped Mn{sub 2}N{sub 0.86} thin films have been grown on MgO (111) by plasma-assisted molecular beam epitaxy. The films grow under tensile strain and, remarkably, they show ferromagnetic-like interactions at low temperature and ferromagnetic ordering agreed well with the Bloch-law T{sup 3/2} at room-temperature. We further demonstrate the enlarged Mn 3s splitting (6.46 eV) and its possible relation to the observed ferromagnetism. Our study not only provide a strategy for further theoretical work on oxygen doped manganese nitrides, but also shed promising light on utilizing its room-temperature FM property to fabricate spintronic devices.

  17. Synthesis of MnO{sub 2}-graphene composites with enhanced supercapacitive performance via pulse electrodeposition under supergravity field

    SciTech Connect (OSTI)

    Liu, Tingting; Shao, Guangjie; Ji, Mingtong; Wang, Guiling

    2014-07-01

    A method of pulse electrodeposition under supergravity field was proposed to synthesize MnO{sub 2}-graphene composites. Supergravity is very efficient for promoting mass transfer and decreasing concentration polarization during the electrodeposition process. The synthesis was conducted on our homemade supergravity equipment. The strength of supergravity field depended on the rotating speed of the ring electrode. 3D flower like MnO{sub 2} spheres composed of nanoflakes were acquired when the rotating speed was 3000 rpm. Graphene nanosheets play as a role of conductive substrates for MnO{sub 2} growing. The composites are evaluated as electrode materials for supercapacitors. Electrochemical results show that the maximum specific capacitance of the MnO{sub 2}-graphene composite is 595.7 F g{sup ?1} at a current density of 0.5 A g{sup ?1}. In addition, the composite exhibits excellent cycle stability with no capacitance attenuation after 1000 cycles. The approach provides new ideas for developing supercapacitor electrode materials with high performance. - Graphical abstract: 3D flower like MnO{sub 2} spheres composed of nanoflakes were acquired at 3000 rpm. - Highlights: MnO{sub 2}-graphene composites were prepared by pulse electrodeposition under supergravity. 3D flower like MnO{sub 2} spheres are anchored on the graphene nanosheets. The MnO{sub 2}-graphene electrode exhibits a specific capacitance of 595.7 F g{sup ?1}.

  18. Observation of Precipitation Evolution in Fe-Ni-Mn-Ti-Al Maraging Steel using Atom Probe Tomography

    SciTech Connect (OSTI)

    Pereloma, E. V.; Stohr, R A; Miller, Michael K; Ringer, S. P.

    2009-01-01

    We describe the full decomposition sequence in an Fe-Ni-Mn-Ti-Al maraging steel during isothermal annealing at 550 C. Following significant pre-precipitation clustering reactions within the supersaturated martensitic solid solution, (Ni,Fe){sub 3}Ti and (Ni,Fe){sub 3}(Al,Mn) precipitates eventually form after isothermal aging for {approx}60 seconds. The morphology of the (Ni,Fe){sub 3}Ti particles changes gradually during aging from predominantly plate-like to rod-like, and, importantly, Mn and Al were observed to segregate to these precipitate/matrix interfaces. The (Ni,Fe){sub 3}(Al,Mn) precipitates occurred at two main locations: uniformly within the matrix and at the periphery of the (Ni,Fe){sub 3}Ti particles. We relate this latter mode of precipitation to the Mn-Al segregation.

  19. Effect of Cu{sup 2+} and Ni{sup 2+} substitution at the Mn site in (La{sub

    Office of Scientific and Technical Information (OSTI)

    0.63}Ca{sub 0.37})MnO{sub 3}: A neutron powder diffraction investigation (Journal Article) | SciTech Connect Effect of Cu{sup 2+} and Ni{sup 2+} substitution at the Mn site in (La{sub 0.63}Ca{sub 0.37})MnO{sub 3}: A neutron powder diffraction investigation Citation Details In-Document Search Title: Effect of Cu{sup 2+} and Ni{sup 2+} substitution at the Mn site in (La{sub 0.63}Ca{sub 0.37})MnO{sub 3}: A neutron powder diffraction investigation The crystal and magnetic structures of the

  20. Growth of single-crystal {alpha}-MnO{sub 2} nanorods on multi-walled carbon nanotubes

    SciTech Connect (OSTI)

    Chen Yong; Liu Chenguang; Liu Chang; Lu Gaoqing; Cheng Huiming

    2007-11-06

    Single-crystal {alpha}-MnO{sub 2} nanorods were grown on multi-walled carbon nanotubes (MWNTs) in H{sub 2}SO{sub 4} aqueous solution. The morphology and microstructure of the composites were examined by transmission electron microscopy, high-resolution transmission electron microscopy (HRTEM), X-ray diffractometry and energy dispersive spectroscopy (EDS). The results show that {alpha}-MnO{sub 2} single-crystal nanorods with a mean diameter of 15 nm were densely grown on the surface of MWNTs. Those MWNTs/MnO{sub 2} composites were used as an electrode material for supercapacitors, and it was found that the supercapacitor performance using MWNTs/MnO{sub 2} composites was improved largely compared to that using pure MWNTs and {alpha}-MnO{sub 2} nanorod mechanically mixed with MWNTs.

  1. Microstructures and Mechanical Properties of Compositionally Complex Co-free FeNiMnCr18 FCC Solid Solution Alloy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Zhenggang; Bei, Hongbin

    2015-01-01

    Recently,a structurally-simplebutcompositionally-complex FeNiCoMnCr highentropyalloywasfoundto haveexcellentmechanicalproperties(e.g.,highstrengthandductility).Tounderstandthepotentialof using highentropyalloysasstructuralmaterialsforadvancednuclearreactorandpowerplants,itis necessary tohaveathoroughunderstandingoftheirstructuralstabilityandmechanicalpropertiesde- gradation underneutronirradiation.ThisrequiresustodevelopasimilarmodelalloywithoutCobe- cause materialwithCowillmakepost-neutron-irradiationtestingdifficult duetotheproductionofthe 60Co radioisotope.Toachievethisgoal,aFCC-structuredsingle-phasealloywithacompositionof FeNiMnCr18 wassuccessfullydeveloped.Thisnear-equiatomicFeNiMnCr18 alloy hasgoodmalleability and itsmicrostructurecanbecontrolledbythermomechanicalprocessing.Byrollingandannealing,the as-cast elongated-grained-microstructureisreplacedbyhomogeneousequiaxedgrains.Themechanical properties (e.g.,strengthandductility)oftheFeNiMnCr18 alloy arecomparabletothoseoftheequiatomic FeNiCoMnCr highentropyalloy.Bothstrengthandductilityincreasewithdecreasingdeformation temperature,withthelargestdifferenceoccurringbetween293and77K.Extensivetwin-bandswhich are bundlesofnumerousindividualtwinsareobservedwhenitistensile-fracturedat77K.Notwin bands aredetectedbyEBSDformaterialsdeformedat293Kandhigher.Theunusualtemperature-de- pendencies ofUTSanduniformelongationcouldbecausedbythedevelopmentofthedensetwin substructure, twin-dislocationinteractionsandtheinteractionsbetweenprimaryandsecondarytwin- ning systemswhichresultinamicrostructurerefinement andhencecauseenhancedstrainhardening and postponednecking.

  2. Bulk and surface half-metallicity: The case of D0{sub 3}-type Mn{sub 3}Ge

    SciTech Connect (OSTI)

    Liu, Hao; Gao, G. Y. Hu, Lei; Ni, Yun; Zu, Fengxia; Zhu, Sicong; Wang, Shuling; Yao, K. L.

    2014-01-21

    Motivated by the experimental realization of D0{sub 22}-type Mn{sub 3}Ge (001) films [Kurt et al. Appl. Phys. Lett. 101, 132410 (2012)] and the structural stability of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge [Zhang et al. J. Phys.: Condens. Matter 25, 206006 (2013)], we use the first-principles calculations based on the full potential linearized augmented plane-wave method to investigate the electronic and magnetic properties of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge and its (001) surface. We show that bulk D0{sub 3}-Mn{sub 3}Ge is a half-metallic ferromagnet with the minority-spin energy gap of 0.52 eV and the magnetic moment of 1.00 μ{sub B} per formula unit. The bulk half-metallicity is preserved at the pure Mn-terminated (001) surface due to the large exchange split, but the MnGe-terminated (001) surface destroys the bulk half-metallicity. We also reveal that the surface stabilities are comparable between the D0{sub 3}-Mn{sub 3}Ge (001) and the experimental D0{sub 22}-Mn{sub 3}Ge (001), which indicates the feasibility to grow the Mn{sub 3}Ge (001) films with D0{sub 3} phase other than D0{sub 22} one. The surface half-metallicity and stability make D0{sub 3}-Mn{sub 3}Ge a promising candidate for spintronic applications.

  3. Redox Dynamics of Mixed Metal (Mn, Cr, and Fe) Ultrafine Particles

    SciTech Connect (OSTI)

    Nico, Peter S.; Kumfer, Benjamin M.; Kennedy, Ian M.; Anastasio, Cort

    2008-08-01

    The impact of particle composition on metal oxidation state, and on changes in oxidation state with simulated atmospheric aging, are investigated experimentally in flame-generated nanoparticles containing Mn, Cr, and Fe. The results demonstrate that the initial fraction of Cr(VI) within the particles decreases with increasing total metal concentration in the flame. In contrast, the initial Mn oxidation state was only partly controlled by metal loading, suggesting the importance of other factors. Two reaction pathways, one reductive and one oxidative, were found to be operating simultaneously during simulated atmospheric aging. The oxidative pathway depended upon the presence of simulated sunlight and O{sub 3}, whereas the reductive pathway occurred in the presence of simulated sunlight alone. The reductive pathway appears to be rapid but transient, allowing the oxidative pathway to dominate with longer aging times, i.e. greater than {approx}8 hours. The presence of Mn within the particles enhanced the importance of the oxidative pathway, leading to more net Cr oxidation during aging implying that Mn can mediate oxidation by removal of electrons from other particulate metals.

  4. Modulation on Ni{sub 2}MnGa(001) surface

    SciTech Connect (OSTI)

    D'Souza, S. W.; Rai, Abhishek; Nayak, J.; Maniraj, M.; Dhaka, R. S.; Barman, S. R.; Schlagel, D. L.; Lograsso, T. A.

    2011-07-15

    We report periodic modulation on (001) surface of Ni2MnGa ferromagnetic shape memory alloy. For the stoichiometric surface, analysis of the low energy electron diffraction (LEED) spot profiles shows that the modulation is incommensurate. The modulation appears at 200 K, concomitant with the first order structural transition to the martensitic phase.

  5. Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications

    SciTech Connect (OSTI)

    Kam, Kinson; Doeff, Marca M.

    2010-12-01

    Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

  6. CaMn2Sb2: Spin waves on a frustrated antiferromagnetic honeycomb lattice

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McNally, D. E.; Simonson, J. W.; Kistner-Morris, J. J.; Smith, G. J.; Hassinger, J. E.; DeBeer-Schmidt, L.; Kolesnikov, A. I.; Zaliznyak, I.; Aronson, M. C.

    2015-05-22

    We present inelastic neutron scattering measurements of the antiferromagnetic insulator CaMn2Sb2:, which consists of corrugated honeycomb layers of Mn. The dispersion of magnetic excitations has been measured along the H and L directions in reciprocal space, with a maximum excitation energy of ≈ 24 meV. These excitations are well described by spin waves in a Heisenberg model, including first and second neighbor exchange interactions, J1 and J2, in the Mn plane and also an exchange interaction between planes. The determined ratio J2/J1 ≈ 1/6 suggests that CaMn2Sb2: is the first example of a compound that lies very close to themore » mean field tricritical point, known for the classical Heisenberg model on the honeycomb lattice, where the N´eel phase and two different spiral phases coexist. The magnitude of the determined exchange interactions reveal a mean field ordering temperature ≈ 4 times larger than the reported N´eel temperature TN = 85 K, suggesting significant frustration arising from proximity to the tricritical point.« less

  7. Short- and long-range magnetic order in LaMnAsO

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McGuire, Michael A.; Garlea, Vasile Ovidiu

    2016-02-02

    The magnetic properties of the layered oxypnictide LaMnAsO have been revisited using neutron scattering and magnetization measurements. The present measurements identify the Néel temperature TN = 360(1) K. Below TN the critical exponent describing the magnetic order parameter is β=0.33–0.35 , consistent with a three-dimensional Heisenberg model. Above this temperature, diffuse magnetic scattering indicative of short-range magnetic order is observed, and this scattering persists up to TSRO = 650(10) K. Morevoer, the magnetic susceptibility shows a weak anomaly at TSRO and no anomaly at TN. Analysis of the diffuse scattering data using a reverse Monte Carlo algorithm indicates that abovemore » TN nearly two-dimensional, short-range magnetic order is present with a correlation length of 9.3(3) Å within the Mn layers at 400 K. The inelastic scattering data reveal a spin gap of 3.5 meV in the long-range ordered state, and strong, low-energy (quasielastic) magnetic excitations emerging in the short-range ordered state. When we compared it with other related compounds correlates the distortion of the Mn coordination tetrahedra to the sign of the magnetic exchange along the layer-stacking direction, and suggests that short-range order above TN is a common feature in the magnetic behavior of layered Mn-based pnictides and oxypnictides.« less

  8. Ordering ferromagnetic In{sub 1?x}Mn{sub x}As quantum dots

    SciTech Connect (OSTI)

    Ferri, Fabio A.; Marega Jr, Euclydes; Kunets, Vasyl P.; Salamo, Gregory J.

    2013-12-04

    In this work, we present a method to order low temperature (LT) self-assembled ferromagnetic In{sub 1?x}Mn{sub x}As quantum dots (QDs) grown by molecular beam epitaxy (MBE). The ordered In{sub 1?x}Mn{sub x}As QDs were grown on top of a non-magnetic In{sub 0.4}Ga{sub 0.6}As/GaAs(100) QDs multi-layered structure. The modulation of the chemical potential, due to the stacking, provides a nucleation center for the LT In{sub 1?x}Mn{sub x}As QDs. For particular conditions, such as surface morphology and growth conditions, the In{sub 1?x}Mn{sub x}As QDs align along lines like chains. For comparison purposes, we also report the study of QDs grown on plain GaAs(100) substrates. Ferromagnetic behavior was observed for all structures at 2 K.

  9. Evaluation of Li2MnSiO4 Cathode | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    11 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es018_belharouak_2011_p.pdf More Documents & Publications Search for High Energy Density Cathode Materials Evaluation of Li2MnSiO4 Cathode Design of Safer High-Energy Density Materials for Lithium-Ion Cells

  10. Evaluation of Li2MnSiO4 Cathode | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    9 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon esp_18_belharouak.pdf More Documents & Publications Search for High Energy Density Cathode Materials Evaluation of Li2MnSiO4 Cathode Vehicle Technologies Office Merit Review 2014: High-Capacity Polyanion Cathodes

  11. Helical antiferromagnetic ordering in Lu1-xScxMnSi

    SciTech Connect (OSTI)

    Goetsch, Ryan J; Anand, V K; Johnston, David C

    2014-08-01

    Polycrystalline samples of Lu1?xScxMnSi (x=0, 0.25, 0.5) are studied using powder x-ray diffraction, heat capacity Cp, magnetization, magnetic susceptibility ?, and electrical resistivity ? measurements versus temperature T and magnetic field H. This system crystallizes in the primitive orthorhombic TiNiSi-type structure (space group Pnma) as previously reported. The ?(T) data indicate metallic behavior. The Cp(T), ?(T), and ?(T) measurements consistently indicate long-range antiferromagnetic (AF) transitions with AF ordering temperatures TN=246, 215, and 188 K for x=0, 0.25, and 0.5, respectively. A second transition is observed at somewhat lower T for each sample from the ?(T) and ?(T) measurements, which we speculate are due to spin reorientation transitions; these second transitions are completely suppressed in H=5.5 T. The Cp data below 10 K for each composition indicate an enhanced Sommerfeld electronic heat capacity coefficient for the series in the range ?=2429 mJ/mol K2. The ?(T) measurements up to 1000 K were fitted by local-moment Curie-Weiss behaviors which indicate a low Mn spin S?1. The ? data below TN are analyzed using the Weiss molecular field theory for a planar noncollinear cycloidal AF structure with a composition-dependent pitch, following the previous neutron diffraction work of Venturini et al. [J. Alloys Compd. 256, 65 (1997)]. Within this model, the fits indicate a turn angle between Mn ordered moments along the cycloid axis of ?100? or ?145?, either of which indicate dominant AF interactions between the Mn spins in the Lu1?xScxMnSi series of compounds.

  12. Structural relationships between new carbide La{sub 14}Sn(MnC{sub 6}){sub 3} and fully ordered La{sub 11}(MnC{sub 6}){sub 3}

    SciTech Connect (OSTI)

    Zaikina, Julia V.; Zhou, Haidong; Latturner, Susan E.

    2010-12-15

    Crystals of the ternary La{sub 11}(MnC{sub 6}){sub 3} and new quaternary carbide La{sub 14}Sn(MnC{sub 6}){sub 3} phases were grown from La/Ni eutectic flux and their structures were determined by means of X-ray single crystal diffraction. La{sub 11}(MnC{sub 6}){sub 3} is a new superstructure variant of La{sub 3.67}MnC{sub 6} (previously reported disordered subcell: P6{sub 3}/m; a{sub 0}=8.806 A; c{sub 0}=5.329 A, Z=2). The superstructure (R3-bar ; a={radical}3a{sub 0}=15.2649(9) A; c=3c{sub 0}=16.013(1) A, Z=6; R{sub 1}=0.022) is realized by complete ordering of the La chains within the columns of face-sharing carbon octahedra, with alternating La-La distances leading to R-centering and enlargement of the unit cell. The structure of the quaternary carbide La{sub 14}Sn(MnC{sub 6}){sub 3} (P6-bar ; a=8.756(1) A; c=10.483(2) A, Z=1; R{sub 1}=0.026) is closely related to that of La{sub 11}(MnC{sub 6}){sub 3} with part of the MnC{sub 6} units replaced by Sn atoms. The structure and precise composition of La{sub 14}Sn(MnC{sub 6}){sub 3} can be derived from that of La{sub 11}(MnC{sub 6}){sub 3} by taking into account the extent of this substitution and variation in lanthanum siting in the chain of carbon octahedra. Band structure calculations indicate both phases are metallic; the La{sub 11}(MnC{sub 6}){sub 3} phase is stabilized by the ordering of La atoms which induces a pseudogap at E{sub F}. -- La{sub 11}(MnC{sub 6}){sub 3} with fully ordered superstructure and a new carbide La{sub 14}Sn(MnC{sub 6}){sub 3} were obtained from La/Ni eutectic flux. Display Omitted

  13. TX, RRC District 1 Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    26 144 436 1,266 1,324 1,427 1996-2014 Lease Condensate (million bbls) 6 28 128 257 158 233 1998-2014 Total Gas (billion cu ft) 743 1,725 3,627 6,524 4,317 7,542 1996-2014 Nonassociated Gas (billion cu ft) 719 1,545 2,960 4,532 2,079 4,721 1996-2014 Associated Gas (billion cu ft) 24 180 667 1,992 2,238 2,821

  14. TX, RRC District 10 Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    9 35 51 70 70 46 1996-2014 Lease Condensate (million bbls) 27 55 54 59 41 68 1998-2014 Total Gas (billion cu ft) 2,325 3,353 2,954 2,906 2,062 2,744 1996-2014 Nonassociated Gas (billion cu ft) 2,162 3,138 2,633 2,579 1,728 2,486 1996-2014 Associated Gas (billion cu ft) 163 215 321 327 334 258

  15. TX, RRC District 5 Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    0 1 29 12 28 1996-2014 Lease Condensate (million bbls) 0 0 0 0 0 0 1998-2014 Total Gas (billion cu ft) 9,039 9,340 8,784 3,255 2,729 3,216 1996-2014 Nonassociated Gas (billion cu ft) 9,039 9,340 8,779 3,237 2,724 3,201 1996-2014 Associated Gas (billion cu ft) 0 0 5 18 5 15

  16. TX, RRC District 6 Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    2 11 16 32 18 40 1996-2014 Lease Condensate (million bbls) 21 34 25 39 27 42 1998-2014 Total Gas (billion cu ft) 5,690 7,090 6,712 4,849 4,273 4,458 1996-2014 Nonassociated Gas (billion cu ft) 5,671 6,977 6,596 4,643 4,087 4,373 1996-2014 Associated Gas (billion cu ft) 19 113 116 206 186 8

  17. TX, RRC District 8 Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    679 790 934 1,144 1,057 1,441 1996-2014 Lease Condensate (million bbls) 6 44 19 29 30 20 1998-2014 Total Gas (billion cu ft) 2,469 2,518 2,891 2,626 2,752 3,333 1996-2014 Nonassociated Gas (billion cu ft) 1,427 1,157 991 335 402 368 1996-2014 Associated Gas (billion cu ft) 1,042 1,361 1,900 2,291 2,350 2,965

  18. TX, RRC District 9 Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    5 21 20 32 20 39 1996-2014 Lease Condensate (million bbls) 8 8 12 8 10 4 1998-2014 Total Gas (billion cu ft) 4,168 4,274 2,974 2,824 2,455 2,133 1996-2014 Nonassociated Gas (billion cu ft) 3,935 4,043 2,724 2,452 2,236 1,763 1996-2014 Associated Gas (billion cu ft) 233 231 250 372 219 370

  19. TX, State Offshore Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    0 0 1 0 0 0 1996-2014 Lease Condensate (million bbls) 2 0 1 0 1 0 1998-2014 Total Gas (billion cu ft) 61 29 29 24 15 10 1996-2014 Nonassociated Gas (billion cu ft) 59 29 25 22 13 10 1996-2014 Associated Gas (billion cu ft) 2 0 4 2 2 0

  20. Roma, TX Natural Gas Exports to Mexico

    Gasoline and Diesel Fuel Update (EIA)

    36,813 65,794 133,769 138,340 154,471 168,049 1999-2015 Pipeline Prices 4.55 4.14 2.86 3.80 4.62 2.79

  1. ~txF7D.ptx

    Energy Savers [EERE]

    THURSDAY OCTOBER 20, 2011 + + + + + The Electricity Advisory Committee met, in the Conference Center of the National Rural Electric Cooperative Association Headquarters, 4301 Wilson Boulevard, Arlington, Virginia, at 8:00 a.m., Richard Cowart, Chair, presiding. MEMBERS PRESENT RICHARD COWART, Regulatory Assistance Project, Chair RICK BOWEN, Alcoa RALPH CAVANAGH, Natural Resources Defense Council THE HONORABLE ROBERT CURRY, New York State Public Service Commission JOSE DELGADO, American

  2. Micro-Grids for Colonias (TX)

    SciTech Connect (OSTI)

    Dean Schneider; Michael Martin; Renee Berry; Charles Moyer

    2012-07-31

    This report describes the results of the final implementation and testing of a hybrid micro-grid system designed for off-grid applications in underserved Colonias along the Texas/Mexico border. The project is a federally funded follow-on to a project funded by the Texas State Energy Conservation Office in 2007 that developed and demonstrated initial prototype hybrid generation systems consisting of a proprietary energy storage technology, high efficiency charging and inverting systems, photovoltaic cells, a wind turbine, and bio-diesel generators. This combination of technologies provided continuous power to dwellings that are not grid connected, with a significant savings in fuel by allowing power generation at highly efficient operating conditions. The objective of this project was to complete development of the prototype systems and to finalize and engineering design; to install and operate the systems in the intended environment, and to evaluate the technical and economic effectiveness of the systems. The objectives of this project were met. This report documents the final design that was achieved and includes the engineering design documents for the system. The system operated as designed, with the system availability limited by maintenance requirements of the diesel gensets. Overall, the system achieved a 96% availability over the operation of the three deployed systems. Capital costs of the systems were dependent upon both the size of the generation system and the scope of the distribution grid, but, in this instance, the systems averaged $0.72/kWh delivered. This cost would decrease significantly as utilization of the system increased. The system with the highest utilization achieved a capitol cost amortized value of $0.34/kWh produced. The average amortized fuel and maintenance cost was $0.48/kWh which was dependent upon the amount of maintenance required by the diesel generator. Economically, the system is difficult to justify as an alternative to grid power. However, the operational costs are reasonable if grid power is unavailable, e.g. in a remote area or in a disaster recovery situation. In fact, avoided fuel costs for the smaller of the systems in use during this project would have a payback of the capital costs of that system in 2.3 years, far short of the effective system life.

  3. Microsoft Word - abstract-lacognata-tx_2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ASTROPHYSICAL ENERGIES Dr. M. La Cognata INFN-Laboratori Nazionali del Sud, Catania, Italy ABSTRACT The 19 F(p,) 16 O reaction is an important fluorine destruction channel in ...

  4. Clint, TX Natural Gas Exports to Mexico

    Gasoline and Diesel Fuel Update (EIA)

    87,449 96,722 101,585 108,573 123,670 126,022 1997-2015 Pipeline Prices 4.61 4.29 3.08 4.05 4.68 2.70 1997

  5. Hidalgo, TX Natural Gas Exports to Mexico

    Gasoline and Diesel Fuel Update (EIA)

    Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 2009 2010 2011 2012 2013 2014 View History Pipeline Volumes 284 62 0 0 0 0 1996-2014 Pipeline Prices 4.40 4.21 -- -- -- -- 1996-2014

  6. Hidalgo, TX Natural Gas Exports to Mexico

    Gasoline and Diesel Fuel Update (EIA)

    0 2,506 9,227 14,862 8,817 1996-2015 Pipeline Prices -- -- 3.47 3.92 4.68 2.28 1996

  7. Penitas, TX Natural Gas Exports to Mexico

    Gasoline and Diesel Fuel Update (EIA)

    Working Gas from Same Month Previous Year (Percent) Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Pacific Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 39.40 137.00 162.70 103.50 62.40 34.80 25.30 14.90 12.90 9.80 8.70 -0.90 2016 0.10 -3.90 - = No Data Reported; -- = Not Applicable; NA = Not

  8. Alamo, TX Natural Gas Exports to Mexico

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    3,678 27,479 48,850 72,039 76,111 78,866 1998-2014 Pipeline Prices 3.95 4.50 4.10 2.86 3.81 4.63 1998...

  9. Structural and magnetic properties of magnetron sputtered Ni-Mn-Sn ferromagnetic shape memory alloy thin films

    SciTech Connect (OSTI)

    Vishnoi, Ritu; Kaur, Davinder

    2010-05-15

    In the present study, structural and magnetic properties of Mn-rich, off-stoichiometric, nanocrystalline Ni-Mn-Sn ferromagnetic shape memory alloy thin films, grown on Si (100) substrates at 550 deg. C by dc magnetron sputtering have been systematically investigated. The crystallization, surface morphology, and structural features were studied using x-ray diffraction, atomic force microscopy, and field emission scanning electron microscopy. The structural transition from austenite to martensite was observed with an increase of Mn content. Austenitic phase with mixed L2{sub 1}/A2+B2 structure has been observed at room temperature in Ni{sub 52.6}Mn{sub 23.7}Sn{sub 23.6} (S{sub 1}) and Ni{sub 51.5}Mn{sub 26.1}Sn{sub 22.2} (S{sub 2}) films, while those with composition of Ni{sub 58.9}Mn{sub 28.0}Sn{sub 13.0} (S{sub 3}) and Ni{sub 58.3}Mn{sub 29.0}Sn{sub 12.6} (S{sub 4}) show martensitic phase with 14M modulated monoclinic structures. Field induced martensite-austenite transformation has been observed in magnetization studies using superconducting quantum interference device magnetometer. Temperature dependent magnetization measurements demonstrate the influence of magnetic field on the structural phase transition temperature. The investigations reveal an increase of martensitic transformation temperature (T{sub M}) with corresponding increase in substitution of Mn. The films exhibit ferromagnetic behavior at low temperatures below Curie temperature (T{sub C}). The decrease in saturation moment with increasing Mn content, indicates the existence of antiferromagnetic correlations within ferromagnetic matrix.

  10. Structural characterization of the FeTiO{sub 3}-MnTiO{sub 3} solid solution

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Structural characterization of the FeTiO{sub 3}-MnTiO{sub 3} solid solution Citation Details In-Document Search Title: Structural characterization of the FeTiO{sub 3}-MnTiO{sub 3} solid solution We have synthesized the (Mn{sub 1-x}Fe{sub x})TiO{sub 3} (0.0{<=}x{<=}1.0) solid solution compounds by high-temperature sintered methods, and characterized their crystal structures by combining X-ray diffraction, Moessbauer spectroscopy and Raman

  11. Post-Growth Annealing of Bridgman-grown CdZnTe and CdMnTe Crystals for

    Office of Scientific and Technical Information (OSTI)

    Room-temperature Nuclear Radiation Detectors (Journal Article) | SciTech Connect Post-Growth Annealing of Bridgman-grown CdZnTe and CdMnTe Crystals for Room-temperature Nuclear Radiation Detectors Citation Details In-Document Search Title: Post-Growth Annealing of Bridgman-grown CdZnTe and CdMnTe Crystals for Room-temperature Nuclear Radiation Detectors Bridgman-grown cadmium zinc telluride (CdZnTe or CZT) and cadmium manganese telluride (CdMnTe or CMT) crystals often have Te inclusions that

  12. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jamer, M. E.; Assaf, B. A.; Sterbinsky, G. E.; Arena, D. A.; Heiman, D.

    2014-12-05

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. Results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value.

  13. Atomic moments in Mn{sub 2}CoAl thin films analyzed by X-ray magnetic circular dichroism

    SciTech Connect (OSTI)

    Jamer, M. E.; Assaf, B. A.; Heiman, D.; Sterbinsky, G. E.; Arena, D. A.

    2014-12-07

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn{sub 2}CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value.

  14. Neutron powder diffraction analysis of (Tm{sub 0.50}Ca{sub 0.50})MnO{sub 3}

    Office of Scientific and Technical Information (OSTI)

    and (Lu{sub 0.50}Ca{sub 0.50})MnO{sub 3} (Journal Article) | SciTech Connect Neutron powder diffraction analysis of (Tm{sub 0.50}Ca{sub 0.50})MnO{sub 3} and (Lu{sub 0.50}Ca{sub 0.50})MnO{sub 3} Citation Details In-Document Search Title: Neutron powder diffraction analysis of (Tm{sub 0.50}Ca{sub 0.50})MnO{sub 3} and (Lu{sub 0.50}Ca{sub 0.50})MnO{sub 3} The crystal and magnetic structures of (Tm{sub 0.50}Ca{sub 0.50})MnO{sub 3} and (Lu{sub 0.50}Ca{sub 0.50})MnO{sub 3} have been investigated

  15. Penetration depth and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} polycrystalline films by ferromagnetic resonance and spin pumping

    SciTech Connect (OSTI)

    Merodio, P.; Ghosh, A.; Lemonias, C.; Gautier, E.; Ebels, U.; Chshiev, M.; Béa, H. E-mail: helene.bea@cea.fr; Baltz, V. E-mail: helene.bea@cea.fr

    2014-01-20

    Spintronics relies on the spin dependent transport properties of ferromagnets (Fs). Although antiferromagnets (AFs) are used for their magnetic properties only, some fundamental F-spintronics phenomena like spin transfer torque, domain wall motion, and tunnel anisotropic magnetoresistance also occur with AFs, thus making AF-spintronics attractive. Here, room temperature critical depths and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} are determined by F-resonance and spin pumping. In particular, we find room temperature critical depths originating from different absorption mechanisms: dephasing for Ir{sub 20}Mn{sub 80} and spin flipping for Fe{sub 50}Mn{sub 50}.

  16. Octonary resistance states in La0.7Sr0.3MnO3/BaTiO3/La0.7Sr0.3MnO3

    Office of Scientific and Technical Information (OSTI)

    multiferroic tunnel junctions (Journal Article) | DOE PAGES Octonary resistance states in La0.7Sr0.3MnO3/BaTiO3/La0.7Sr0.3MnO3 multiferroic tunnel junctions This content will become publicly available on October 6, 2016 « Prev Next » Title: Octonary resistance states in La0.7Sr0.3MnO3/BaTiO3/La0.7Sr0.3MnO3 multiferroic tunnel junctions General drawbacks of current electronic/spintronic devices are high power consumption and low density storage. A multiferroic tunnel junction (MFTJ),

  17. Laser activation of ferromagnetism in hydrogenated Ga{sub 1-x}Mn{sub x}As

    SciTech Connect (OSTI)

    Farshchi, R.; Dubon, O. D.; Hwang, D. J.; Misra, N.; Grigoropoulos, C. P.; Ashby, P. D.

    2008-01-07

    We demonstrate the local depassivation of hydrogenated Ga{sub 1-x}Mn{sub x}As by pulsed-laser annealing. The controlled removal of Mn-H defect complexes, which form upon hydrogenation and render Mn acceptors inactive, is achieved by focused laser irradiation. As a result, regions of electrically and ferromagnetically active Ga{sub 1-x}Mn{sub x}As are formed within a nonactive, otherwise structurally identical film. The hydrogenated films subjected to blanket laser depassivation display a Curie temperature T{sub C} up to 60 K, or 60% of the T{sub C} of the as-grown films. These results demonstrate the direct laser writing of mesoscopic ferromagnetically active regions as a viable route for the realization of planar, nanoscale spintronic systems.

  18. Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a function of electrical resistance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hedden, Morgan; Francis, Nick; Haraldsen, Jason T.; Ahmed, Towfiq; Constantin, Costel

    2015-07-15

    Particle sizes of manganese oxide (β-MnO₂) powders were modified by using a mortar and pestle ground method for period of times that varied between 15–60 min. Particle size versus ground time clearly shows the existence of a size-induced regime transition (i.e., regime I and II). Thermoelectric properties of β-MnO₂ powders as a function of electrical resistance in the range of RP = 10 - 80Ω were measured. Based on the data presented, we propose a model for the β-MnO₂ system in which nanometer-scale MnO₂ crystallites bond together through weak van der Waals forces to form larger conglomerates that span inmore » size from nanometer to micrometer scale.« less

  19. Anti-site disorder and improved functionality of Mn?NiX (X = Al, Ga, In, Sn) inverse Heusler alloys

    SciTech Connect (OSTI)

    Paul, Souvik; Kundu, Ashis; Ghosh, Subhradip; Sanyal, Biplab

    2014-10-07

    Recent first-principles calculations have predicted Mn?NiX (X = Al, Ga, In, Sn) alloys to be magnetic shape memory alloys. Moreover, experiments on Mn?NiGa and Mn?NiSn suggest that the alloys deviate from the perfect inverse Heusler arrangement and that there is chemical disorder at the sublattices with tetrahedral symmetry. In this work, we investigate the effects of such chemical disorder on phase stabilities and magnetic properties using first-principles electronic structure methods. We find that except Mn?NiAl, all other alloys show signatures of martensitic transformations in presence of anti-site disorder at the sublattices with tetrahedral symmetry. This improves the possibilities of realizing martensitic transformations at relatively low fields and the possibilities of obtaining significantly large inverse magneto-caloric effects, in comparison to perfect inverse Heusler arrangement of atoms. We analyze the origin of such improvements in functional properties by investigating electronic structures and magnetic exchange interactions.

  20. Magnetochromic effect in multiferroic R In 1 ₋ x Mn x O 3 ( R = Tb , Dy)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, P.; Holinsworth, B. S.; O'Neal, K. R.; Brinzari, T. V.; Mazumdar, D.; Topping, C. V.; Luo, X.; Cheong, S.-W.; Singleton, J.; McGill, S.; et al

    2015-05-26

    We combined high field magnetization and magneto-optical spectroscopy to investigate spin-charge coupling in Mn-substituted rare-earth indium oxides of chemical formula RIn₁₋xMnxO₃ (R=Tb, Dy). The edge states, on-site Mn³⁺d to d excitations, and rare-earth f-manifold excitations all track the magnetization energy due to dominant Zeeman interactions. The field-induced modifications to the rare-earth excitations are quite large because spin-orbit coupling naturally mixes spin and charge, suggesting that the next logical step in the design strategy should be to bring spin-orbit coupling onto the trigonal bipyramidal chromophore site with a 4 or 5d center.

  1. Structural, elastic, electronic, magnetic and vibrational properties of CuCoMnGa under pressure

    SciTech Connect (OSTI)

    İyigör, Ahmet; Uğur, Şule

    2014-10-06

    First principles calculations for the structural, electronic, elastic and phonon properties of the cubic quaternary heusler alloy CuCoMnGa on pressure have been reported by density functional theory (DFT) within generalized gradient approximation (GGA). The calculated values of the elastic constants were used for estimations of the Debye temperatures, the bulk modulus, the shear modulus, the young modulus E, the poisson's ratio σ and the B/G ratio. The elastic constants satisfy all of the mechanical stability criteria. The electronic structures of the ferromagnetic configuration for CuCoMnGa have a metallic character. The estimated magnetic moment per formula unit is 3.76 μ{sub B}. The phonon dispersion is studied using the supercell approach, and the stable nature at 0.2 GPa pressure is observed.

  2. Low temperature magnetic properties of magnesium substituted YbMnO{sub 3}

    SciTech Connect (OSTI)

    Sattibabu, Bhumireddi Bhatnagar, Anil K. Mohan, Dasari Das, Dibakar Sundararaman, Mahadevan; Siruguri, Vasudeva; Rayaprol, Sudhindra

    2014-04-24

    Structural and magnetic properties of polycrystalline Yb{sub 1−x}Mg{sub x}MnO{sub 3} (x = 0, 0.05 and 0.10) hexagonal compounds prepared by solid state method, have been studied. The structural analyses of the samples were carried out by Rietveld analysis of neutron diffraction data. With increasing Mg content, we find that the lattice parameter a decreases and c increases whereas the overall Mn-O bond length decreases. Magnetization measured as a function of magnetic field at 2.5 K exhibits hysteresis, which is attributed to ferromagnetic like ordering of Yb{sup 3+} sublattice. Temperature dependence of ac magnetic susceptibility, χ{sub ac}(T), shows no signature of spin-glass behavior. χ”(T) exhibits a sudden increase at low temperatures which is due to ordering of Yb{sup 3+} sublattice.

  3. What is the valence of Mn in Ga1-xMnxN?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Berlijn, Tom; Jarrell, Mark; Nelson, Ryky; Ku, Wei; Moreno, Juana

    2015-11-04

    Motivated by the potential high Curie temperature of Ga1-xMnxN, we investigate the controversial Mn valence in this diluted magnetic semiconductor. From a first-principles Wannier-function analysis of the high energy Hilbert space, we find unambiguously the Mn valence to be close to 2+(d5), but in a mixed spin configuration with average magnetic moments of 4µB. By integrating out high-energy degrees of freedom differently, we further demonstrate the feasibility of both effective d4 and d5 descriptions. These two descriptions offer simple pictures for local and extended properties of the system, and highlight the dual nature of its doped hole. Specifically, in themore » effective d5 description, we demonstrate novel physical effects absent in previous studies. Thus, our derivation highlights the richness of low-energy sectors in interacting many-body systems and the generic need for multiple effective descriptions.« less

  4. Magneto-optical spectroscopy of ferromagnetic shape-memory Ni-Mn-Ga alloy

    SciTech Connect (OSTI)

    Veis, M. Beran, L.; Zahradnik, M.; Antos, R.; Straka, L.; Kopecek, J.; Fekete, L.; Heczko, O.

    2014-05-07

    Magneto-optical properties of single crystal of Ni{sub 50.1}Mn{sub 28.4}Ga{sub 21.5} magnetic shape memory alloy in martensite and austenite phase were systematically studied. Crystal orientation was approximately along (100) planes of parent cubic austenite. At room temperature, the sample was in modulated 10M martensite phase and transformed to cubic austenite at 323?K. Spectral dependence of polar magneto-optical Kerr effect was obtained by generalized magneto-optical ellipsometry with rotating analyzer in the photon energy range from 1.2 to 4?eV, and from room temperature to temperature above the Curie point. The Kerr rotation spectra exhibit prominent features typical for complexes containing Mn atoms. Significant spectral changes during transformation to austenite can be explained by different optical properties caused by changes in density of states near the Fermi energy.

  5. Extrinsic anomalous Hall effect in epitaxial Mn{sub 4}N films

    SciTech Connect (OSTI)

    Meng, M.; Wu, S. X. Ren, L. Z.; Zhou, W. Q.; Wang, Y. J.; Wang, G. L.; Li, S. W.

    2015-01-19

    Anomalous Hall effect (AHE) in ferrimagnetic Mn{sub 4}N epitaxial films grown by molecular-beam epitaxy is investigated. The longitudinal conductivity σ{sub xx} is within the superclean regime, indicating Mn{sub 4}N is a highly conducting material. We further demonstrate that the AHE signal in 40-nm-thick films is mainly due to the extrinsic contributions based on the analysis fitted by ρ{sub AH}=a′ρ{sub xx0}+bρ{sub xx}{sup 2} and σ{sub AH}∝σ{sub xx}. Our study not only provide a strategy for further theoretical work on antiperovskite manganese nitrides but also shed promising light on utilizing their extrinsic AHE to fabricate spintronic devices.

  6. Homogeneity testing and quantitative analysis of manganese (Mn) in vitrified Mn-doped glasses by laser-induced breakdown spectroscopy (LIBS)

    SciTech Connect (OSTI)

    Unnikrishnan, V. K.; Nayak, Rajesh; Kartha, V. B.; Santhosh, C. E-mail: unnikrishnan.vk@manipal.edu; Sonavane, M. S.; Yeotikar, R. G.; Shah, M. L.; Gupta, G. P.; Suri, B. M.

    2014-09-15

    Laser-induced breakdown spectroscopy (LIBS), an atomic emission spectroscopy method, has rapidly grown as one of the best elemental analysis techniques over the past two decades. Homogeneity testing and quantitative analysis of manganese (Mn) in manganese-doped glasses have been carried out using an optimized LIBS system employing a nanosecond ultraviolet Nd:YAG laser as the source of excitation. The glass samples have been prepared using conventional vitrification methods. The laser pulse irradiance on the surface of the glass samples placed in air at atmospheric pressure was about 1.710{sup 9} W/cm{sup 2}. The spatially integrated plasma emission was collected and imaged on to the spectrograph slit using an optical-fiber-based collection system. Homogeneity was checked by recording LIBS spectra from different sites on the sample surface and analyzing the elemental emission intensities for concentration determination. Validation of the observed LIBS results was done by comparison with scanning electron microscope- energy dispersive X-ray spectroscopy (SEM-EDX) surface elemental mapping. The analytical performance of the LIBS system has been evaluated through the correlation of the LIBS determined concentrations of Mn with its certified values. The results are found to be in very good agreement with the certified concentrations.

  7. Magnetic fields and fluctuations in weakly Mn doped ZnGeP{sub 2}

    SciTech Connect (OSTI)

    Mengyan, P. W.; Lichti, R. L.; Baker, B. B.; Celebi, Y. G.; Catak, E.; Carroll, B. R.; Zawilski, K. T.; Schunemann, P. G.

    2014-02-21

    We report on our measurements of local and bulk magnetic features in weakly Mn doped ZnGeP{sub 2}. Utilizing muon spin rotation and relaxation measurements, we identify local ferromagnetic order and fluctuations in the local fields as sampled by an implanted muon (?{sup +}). We also report on field induced ferromagnetism occurring above the claimed paramagnetic to ferromagnetic transition temperature (T{sub c} = 312 K)

  8. Thermoelectric study of crossroads material MnTe via sulfur doping

    SciTech Connect (OSTI)

    Xie, Wenjie Populoh, Sascha; Sagarna, Leyre; Trottmann, Matthias; Ga??zka, Krzysztof; Xiao, Xingxing; Liu, Yufei; He, Jian; Weidenkaff, Anke

    2014-03-14

    Here, we report thermoelectric study of crossroads material MnTe via iso-electronic doping S on the Te-site. MnTe{sub 1-x}S{sub x} samples with nominal S content of x?=?0.00, 0.05, and 0.10 were prepared using a melt-quench method followed by pulverization and spark plasma sintering. The X-ray powder diffraction, scanning electron microscopy, and ZAF-corrected compositional analysis confirmed that S uniformly substitutes Te up to slightly over 2%. A higher content of S in the starting materials led to the formation of secondary phases. The thermoelectric properties of MnTe{sub 1-x}S{sub x} samples were characterized by means of Seebeck coefficient, electrical conductivity, and thermal conductivity measurements from 300?K to 773?K. Furthermore, Hall coefficient measurements and a single parabolic band model were used to help gain insights on the effects of S-doping on the scattering mechanism and the carrier effective mass. As expected, S doping not only introduced hole charge carriers but also created short-range defects that effectively scatter heat-carrying phonons at elevated temperatures. On the other hand, we found that S doping degraded the effective mass. As a result, the ZT of MnTe{sub 0.9}S{sub 0.1} was substantially enhanced over the pristine sample near 400?K, while the improvement of ZT became marginal at elevated temperatures. A ZT???0.65 at 773?K was obtained in all three samples.

  9. Inverse Design of Mn-based ternary p-type wide-gap oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    used theory to predict band structure and transport properties for the d 5 transition metal (TM) oxides MnO and Fe 2 O 3 . Significance and Impact This work identified design principles for improving d 5 oxides as a new class of semiconductors with potential applications in energy conversion. Design Principles Demonstrated for Semiconducting d 5 Transition-Metal Oxides with Photovoltaic Applications Potential H. Peng and S. Lany, Phys. Rev. B (Rapid Comm.) 85, 201202(R) (2012). Figure 1:

  10. MN Lup: X-RAYS FROM A WEAKLY ACCRETING T TAURI STAR

    SciTech Connect (OSTI)

    Guenther, H. M.; Wolk, S. J.; Wolter, U.; Robrade, J.

    2013-07-01

    Young T Tauri stars (TTS) are surrounded by an accretion disk, which over time disperses due to photoevaporation, accretion, and possibly planet formation. The accretion shock on the central star produces an UV/optical veiling continuum, line emission, and X-ray signatures. As the accretion rate decreases, the impact on the central star must change. In this article we study MN Lup, a young star where no indications of a disk are seen in IR observations. We present XMM-Newton and VLT/UVES observations, some of them taken simultaneously. The X-ray data show that MN Lup is an active star with L{sub X} /L{sub bol} close to the saturation limit. However, we find high densities (n{sub e} > 3 Multiplication-Sign 10{sup 10} cm{sup -3}) in the X-ray grating spectrum. This can be well fitted using an accretion shock model with an accretion rate of 2 Multiplication-Sign 10{sup -11} M{sub Sun} yr{sup -1}. Despite the simple H{alpha} line profile which has a broad component, but no absorption signatures as typically seen on accreting TTS, we find rotational modulation in Ca II K and in photospheric absorption lines. These line profile modulations do not clearly indicate the presence of a localized hot accretion spot on the star. In the H{alpha} line we see a prominence in absorption about 2R{sub *} above the stellar surface-the first of its kind on a TTS. MN Lup is also the only TTS where accretion is seen, but no dust disk is detected that could fuel it. We suggest that MN Lup presents a unique and short-lived state in the disk evolution. It may have lost its dust disk only recently and is now accreting the remaining gas at a very low rate.

  11. Redox Active Layer-by-Layer Structures containing MnO2 Nanoparticles

    SciTech Connect (OSTI)

    Bazito, Fernanda; O'Brien, Robert; Buttry, Daniel A.

    2005-02-01

    Nanoscale materials provide unique properties that will enable new technologies and enhance older ones. One area of intense activity in which nanoscale materials are being used is in the development of new functional materials for battery applications. This effort promises superior materials with properties that circumvent many of the problems associated with traditional battery materials. Previously we have worked on several approaches for using nanoscale materials for application as cathode materials in rechargeable Li batteries. Our recent work has focused on synthesizing MnO2 nanoparticles and using these in layer-by-layer (LbL) structures to probe the redox properties of the nanoparticles. We show that the aqueous colloidal nanoparticles produced by butanol reduction of tetramethylammonium permanganate can be trapped in thin films using a layer-by-layer deposition approach, and that these films are both redox active and exhibit kinetically facile electrochemical responses. We show cyclic voltammetry of MnO2 colloidal nanoparticles entrapped in a LbL thin film at an ITO electrode surface using poly(diallyldimethylammonium chloride) (PDDA). CV experiments demonstrate that Li+ insertion accompanies Mn(IV) reduction in LiClO4 supporting electrolytes, and that reduction is hindered in supporting electrolytes containing only tetrabutylammonium cations. We also show that electron propagation through multilayer films is facile, suggesting that electrons percolate through the films via electron exchange between nanoparticles.

  12. Magnetization-steps in Y?CoMnO? double perovskite: The role of antisite disorder

    SciTech Connect (OSTI)

    Nair, Harikrishnan S. Xiao, Yinguo; Brckel, Th.; Cherian, Dona; Elizabeth, Suja; Hansen, Thomas; Chatterji, Tapan

    2014-09-28

    Antisite disorder is observed to have significant impact on the magnetic properties of the double perovskite YCoMnO? which has been recently identified as a multiferroic. A paramagnetic-ferromagnetic phase transition occurs in this material at Tc ? 75 K. At 2 K, it displays a strong ferromagnetic hysteresis with a significant coercive field of Hc ? 15 kOe. Sharp steps are observed in the hysteresis curves recorded below 8 K. In the temperature range 2 K ? T ? 5 K, the hysteresis loops are anomalous as the virgin curve lies outside the main loop. The field-cooling conditions as well as the rate of field-sweep are found to influence the steps. Quantitative analysis of the neutron diffraction data shows that at room temperature, Y?CoMnO? consists of 62% of monoclinic P2?/n with nearly 70% antisite disorder and 38% Pnma. The bond valence sums indicate the presence of other valence states for Co and Mn which arise from disorder. We explain the origin of steps by using a model for pinning of magnetization at the antiphase boundaries created by antisite disorder. The steps in magnetization closely resemble the martensitic transformations found in intermetallics and display first-order characteristics as revealed in the Arrott's plots.

  13. Correlating Local Structure with Electrochemical Activity in Li2MnO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nanda, Jagjit; Sacci, Robert L.; Veith, Gabriel M.; Dixit, Hemant M.; Cooper, Valentino R.; Pezeshki, Alan M.; Ruther, Rose E.

    2015-07-31

    Li2MnO3 is of interest as one component of the composite lithium-rich oxides, which are under development for high capacity, high voltage cathodes in lithium ion batteries. Despite such practical importance, the mechanism of electrochemical activity in Li2MnO3 is contested in the literature, as are the effects of long-term electrochemical cycling. Here, Raman spectroscopy and mapping are used to follow the chemical and structural changes that occur in Li2MnO3. Both conventional slurry electrodes and thin films are studied as a function of the state of charge (voltage) and cycle number. Thin films have similar electrochemical properties as electrodes prepared from slurries,more » but allow for spectroscopic investigations on uniform samples without carbon additives. Spectral changes correlate well with electrochemical activity and support a mechanism whereby capacity is lost upon extended cycling due to the formation of new manganese oxide phases. Raman mapping of both thin film and slurry electrodes charged to different voltages reveals significant variation in the local structure. Poor conductivity and slow kinetics associated with a two-phase reaction mechanism contribute to the heterogeneity.« less

  14. MnO{sub 2}@colloid carbon spheres nanocomposites with tunable interior architecture for supercapacitors

    SciTech Connect (OSTI)

    Zhang, Yuxin; Liu, Chuanpu; Wen, Zhongquan

    2014-01-01

    Graphical abstract: - Highlights: MnO{sub 2}@CSs nanocomposites have been successfully synthesized in room temperature. The composites exhibited three structures: coreshell, yolkshell and hollow structure. The yolkshell structure exhibited a high specific capacitance and cycling stability. - Abstract: MnO{sub 2}@colloid carbon spheres nanocomposites with tunable interior architecture have been synthesized by a facile and cost-effective strategy at room temperature. The structure and morphology of as-prepared nanocomposites were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), nitrogen adsorption, focused ion beam scanning electron microscopy (FIB/SEM) and high-resolution transmission electron microscopy (HRTEM). The as-obtained composites exhibited a three-dimensional architecture with coreshell, yolkshell and hollow interior structure. Furthermore, the electrochemical properties of composites were evaluated by cycle voltammetric (CV) and galvanostatic chargedischarge measurements. The yolkshell structure exhibited the optimized pseudocapacitance performance, revealing a specific capacitance (273 F g{sup ?1}) with a good rate and cycling stability, owing to its unique structure and the poor crystallinity of MnO{sub 2} nanofilms. Therefore, this facile synthetic strategy could be useful to design and synthesis of tunable nanostructures with enhanced supercapacitor behavior.

  15. Spin-phonon study of EuMn{sub 2}O{sub 5} nanorods

    SciTech Connect (OSTI)

    Hsu, Ting-Wei; Yang, Chung-Cheun Tong, Yong-Xiang; Shih, Wei-Jhe; Lin, Kuen-Song

    2015-05-07

    EuMn{sub 2}O{sub 5} multiferroic nanorods, with diameters radial (?L{sub C}?) lengths of 25(6) nm 47(15) nm and 51(16) nm 70(26) nm, were fabricated by the hydrothermal method. Ferrimagnetic ordering below 50?K (T*) is observed in the ?L{sub C}??=?70?nm sample, which exhibited ferromagnetic (FM) behavior below T* in a field cooling process. No similar behavior was found in the ?L{sub C}??=?47?nm sample. These observations reveal that only the ?L{sub C}??=?70?nm sample has a meta-FM state, and this sample exhibits the stronger coupling between the Mn ions. Raman spectra of both sets of samples were obtained in 0, 610, 1000, 1600, and 2000?G magnetic fields. The red-shift of the A{sub g} (681?cm{sup ?1}) mode of the both samples increased with the strength of the field above 1000?G, indicating the existence of spin-phonon interaction. The smaller sampled exhibited a larger red-shift, suggesting that the size importantly affects the of EuMn{sub 2}O{sub 5} nanorods.

  16. A XANES and EXAFS Study of Hydration and Ion Pairing in Ambient Aqueous MnBr[subscript 2] Solutions

    SciTech Connect (OSTI)

    Chen, Yongsheng; Fulton, John L.; Partenheimer, Walter

    2008-09-25

    Extended X-ray absorption fine structure (EXAFS) and X-ray absorption near edge structure (XANES) spectroscopies were used to probe the first-shell coordination structure of Mn(II) in aqueous MnBr{sub 2} solutions at ambient conditions from very dilute to the near saturation limit. The Mn K-edge EXAFS spectra for 0.05 and 0.2 m solutions showed that there was no Br(-I) in the first shell, and that the Mn(II) was fully hydrated with six water molecules in an octahedral arrangement. In contrast, for 6 m solution, the coordination number of water was reduced to about 5, and an average of about one bromine atom was present in the first shell as a contact ion pair. The 1s {yields} 4p transition at 6545.5 eV confirmed the observation of Mn-Br contact ion pairs at high concentrations and the 1s {yields} 3d transition at 6539.5 eV showed that the first shell coordination symmetry remained octahedral even in the presence of Mn-Br ion pairs.

  17. Role of the antiferromagnetic pinning layer on spin wave properties in IrMn/NiFe based spin-valves

    SciTech Connect (OSTI)

    Gubbiotti, G. Tacchi, S.; Del Bianco, L.; Bonfiglioli, E.; Giovannini, L.; Spizzo, F.; Zivieri, R.; Tamisari, M.

    2015-05-07

    Brillouin light scattering (BLS) was exploited to study the spin wave properties of spin-valve (SV) type samples basically consisting of two 5 nm-thick NiFe layers (separated by a Cu spacer of 5 nm), differently biased through the interface exchange coupling with an antiferromagnetic IrMn layer. Three samples were investigated: a reference SV sample, without IrMn (reference); one sample with an IrMn underlayer (10 nm thick) coupled to the bottom NiFe film; one sample with IrMn underlayer and overlayer of different thickness (10 nm and 6 nm), coupled to the bottom and top NiFe film, respectively. The exchange coupling with the IrMn, causing the insurgence of the exchange bias effect, allowed the relative orientation of the NiFe magnetization vectors to be controlled by an external magnetic field, as assessed through hysteresis loop measurements by magneto-optic magnetometry. Thus, BLS spectra were acquired by sweeping the magnetic field so as to encompass both the parallel and antiparallel alignment of the NiFe layers. The BLS results, well reproduced by the presented theoretical model, clearly revealed the combined effects on the spin dynamic properties of the dipolar interaction between the two NiFe films and of the interface IrMn/NiFe exchange coupling.

  18. The structure of the Caenorhabditis elegans manganese superoxide dismutase MnSOD-3-azide complex

    SciTech Connect (OSTI)

    Hunter, Gary J.; Trinh, Chi H.; Bonetta, Rosalin; Stewart, Emma E.; Cabelli, Diane E.; Hunter, Therese

    2015-08-27

    C. elegans MnSOD-3 has been implicated in the longevity pathway and its mechanism of catalysis is relevant to the aging process and carcinogenesis. The structures of MnSOD-3 provide unique crystallographic evidence of a dynamic region of the tetrameric interface (residues 41–54). We have determined the structure of the MnSOD-3-azide complex to 1.77-Å resolution. The analysis of this complex shows that the substrate analog, azide, binds end-on to the manganese center as a sixth ligand and that it ligates directly to a third and new solvent molecule also positioned within interacting distance to the His30 and Tyr34 residues of the substrate access funnel. This is the first structure of a eukaryotic MnSOD-azide complex that demonstrates the extended, uninterrupted hydrogen-bonded network that forms a proton relay incorporating three outer sphere solvent molecules, the substrate analog, the gateway residues, Gln142, and the solvent ligand. This configuration supports the formation and release of the hydrogen peroxide product in agreement with the 5-6-5 catalytic mechanism for MnSOD. The high product dissociation constant k₄ of MnSOD-3 reflects low product inhibition making this enzyme efficient even at high levels of superoxide.

  19. Preparation and characterization of nanostructured NiO/MnO{sub 2} composite electrode for electrochemical supercapacitors

    SciTech Connect (OSTI)

    Liu Enhui Li Wen; Li Jian; Meng Xiangyun; Ding Rui; Tan Songting

    2009-05-06

    Nanostructured nickel-manganese oxides composite was prepared by the sol-gel and the chemistry deposition combination new route. The surface morphology and structure of the composite were characterized by scanning electron microscope and X-ray diffraction. The as-synthesized NiO/MnO{sub 2} samples exhibit higher surface area of 130-190 m{sup 2} g{sup -1}. Cyclic voltammetry and galvanostatic charge/discharge measurements were applied to investigate the electrochemical performance of the composite electrodes with different ratios of NiO/MnO{sub 2}. When the mass ratio of MnO{sub 2} and NiO in composite material is 80:20, the specific capacitance value of NiO/MnO{sub 2} calculated from the cyclic voltammetry curves is 453 F g{sup -1}, for pure NiO and MnO{sub 2} are 209, 330 F g{sup -1} in 6 mol L{sup -1} KOH electrolyte and at scan rate of 10 mV s{sup -1}, respectively. The specific capacitance of NiO/MnO{sub 2} electrode is much larger than that of each pristine component. Moreover, the composite electrodes showed high power density and stable electrochemical properties.

  20. U.S. Total Exports

    U.S. Energy Information Administration (EIA) Indexed Site

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  1. Why MnIn{sub 2}O{sub 4} spinel is not a transparent conducting oxide?

    SciTech Connect (OSTI)

    Martinez-Lope, M.J.; Retuerto, M.; Calle, C. de la; Porcher, Florence

    2012-03-15

    The title compound has been synthesized by a citrate technique. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3-bar m, Z=8, with a=9.0008(1) A at 295 K. It exhibits a crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively, with a slight degree of inversion, {lambda}=0.08. MnIn{sub 2}O{sub 4} shows antiferromagnetic interactions below T{sub N} Almost-Equal-To 40 K, due to the statistical distribution of Mn ions over the two available sites. Unlike the related MgIn{sub 2}O{sub 4} and CdIn{sub 2}O{sub 4} spinels, well known as transparent conducting oxides, MnIn{sub 2}O{sub 4} is not transparent and shows a poor conductivity ({sigma}=0.38 S cm{sup -1} at 1123 K): the presence of Mn ions, able to adopt mixed valence states, localizes the charges that, otherwise, would be delocalized in the spinel conduction band. - Graphical Abstract: From NPD data the crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, shows a slight degree of inversion, {lambda}=0.08 and a certain In deficiency. The presence of Mn ions, able to adopt mixed oxidation states, localize the charges that, otherwise, would be delocalized in the spinel conduction band; the presence of localized Mn{sup 2+} and Mn{sup 3+} ions provides the characteristic brown color. Highlights: Black-Right-Pointing-Pointer Accurate structural determination from NPD data: inversion degree (8%), and In deficiency. Black-Right-Pointing-Pointer Bond-valence indicates Mn{sup 2+}-Mn{sup 3+} ions; edge-sharing octahedra contain 90% In{sup 3+}+10% Mn{sup 3+} cations. Black-Right-Pointing-Pointer Conductivity several orders of magnitude lower than those of MgIn{sub 2}O{sub 4} or CdIn{sub 2}O{sub 4}. Black-Right-Pointing-Pointer Variability of Mn oxidation states cancels any electron-doping effect, emptying conduction band of mobile charge carriers. Black-Right-Pointing-Pointer Curie-Weiss behavior confirming the determined charge distribution.

  2. m/sup +/SR studies on pure MnF/sub 2/ and site-diluted (Mn/sub 0. 5/Zn/sub 0. 5/)F/sub 2/

    SciTech Connect (OSTI)

    Uemura, Y.J.; Keitel, R.; Senba, M.; Kiefl, R.F.; Kreitzman, S.R.; Noakes, D.R.; Brewer, J.H.; Harshman, D.R.; Ansaldo, E.J.; Crowe, K.M.

    1986-01-01

    Positive muon spin rotation and relaxation measurements have been carried out on the antiferromagnets, pure MnF/sub 2/ and site-diluted (Mn/sub 0.5/Zn/sub 0.5/)F/sub 2/, above and below the Neel temperature T/sub N/ using single-crystal specimens. Two different muon signals have been found in the pure MnF/sub 2/; with the precession frequency nu/sub A/ = 1.3 GHz for the site A and nu/sub B/ = 152 MHz for the site B measured in zero external magnetic field at T = 5 K. We propose a picture that the signal from the A site represents the ''muonium'' state, and discuss the characteristic features of muonium in magnetic materials. The spin relaxation rate 1/T/sub 1/, measured in zero external field, decreases rapidly with decreasing temperature below T/sub N/. The mechanism of the spin relaxation above T/sub N/ is explained by the exchange fluctuations of the Mn moments, while below T/sub N/ by the Raman scattering of spin waves. At the same normalized temperature T/T/sub N/, 1/T/sub 1/ observed in the diluted (Mn/sub 0.5/Zn/sub 0.5/)F/sub 2/ is significantly larger than that in the pure MnF/sub 2/ below T/sub N/. The difference between the pure and diluted systems is related to the large spectral weight of low-energy magnons in (Mn/sub 0.5/Zn/sub 0.5/)F/sub 2/ found by neutron scattering.

  3. Effect of organic solvents on particle size of Mn{sub 3}O{sub 4} nanoparticles synthesized by a solvothermal method

    SciTech Connect (OSTI)

    Song, Rui; Feng, Shouhua; Wang, Hongjun; Hou, Changmin

    2013-06-15

    In this paper, a modified simple solvothermal method is employed to synthesize Mn{sub 3}O{sub 4} nanocrystals using four different solvents: acetone, ethanol, N,N-dimethylformamide (DMF), and dimethyl sulfoxide (DMSO). Mn{sub 3}O{sub 4} nanoparticles with a tetragonal hausmannite nano-structure are characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), Fourier transform infrared spectroscopy (FTIR), as well as superconducting quantum interference device magnetometer (SQUID). The Mn{sub 3}O{sub 4} particle size is found to have a strong dependency on the solvent used. A reaction scheme is proposed to understand this dependency, suggesting that the solvent coordinating capability has a critical effect on Mn{sub 3}O{sub 4} particle size. The stronger the coordinating capability of the solvent is, the smaller the Mn{sub 3}O{sub 4} particle size is. In addition, magnetic properties of the nano-structured Mn{sub 3}O{sub 4} are also tested and discussed. - Graphical abstract: The comparison of the particle size of Mn{sub 3}O{sub 4} nanoparticles synthesized using different solvents and HRTEM image of Mn{sub 3}O{sub 4} individual nanoparticle revealed its single-crystal nature. - Highlights: • Mn{sub 3}O{sub 4} nanocrystals were synthesized using different solvents by a solvothermal method. • The particle size of Mn{sub 3}O{sub 4} nanocrystal is found to have a strong dependency on the solvent used. • A reaction mechanism is proposed to explain the difference of particle size of Mn{sub 3}O{sub 4} nanocrystals. • Magnetic properties of Mn{sub 3}O{sub 4} nanocrystals with different particle size are tested and compared.

  4. Structure and magnetic properties of Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H-polytype in the Ba-Ce-Mn-O system

    SciTech Connect (OSTI)

    Macias, Mario A.; Mentre, Olivier; Cuello, Gabriel J.; Gauthier, Gilles H.

    2013-02-15

    Based on the peculiar magnetic properties that are observed in pseudo one-dimensional manganites, we decided to synthesize the new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} compound. The preparation was performed by solid state reaction in air at about 1350 Degree-Sign C, for which we found that the compound crystallizes in a hexagonal symmetry with space group P6{sub 3}/mmc (No-194) and cell parameters a=b=5.7861(2) A and c=23.902(1) A. The structural description was correlated with neutron diffraction and bond valence calculations, confirming the presence of Ce{sup 4+} and Mn{sup 4+} segregated in the different crystallographic positions. Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} displays evidence for strong AFM couplings already set at room temperature. The main arrangement of Mn{sup 4+} in magnetically isolated tetramers of face-sharing octahedra is responsible for a metamagnetic-like transition around 50 K. - Graphical abstract: The new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} polytype shows strong AFM couplings in magnetically isolated [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers of face-sharing octahedral, resulting in a metamagnetic-like transition around 50 K. Highlights: Black-Right-Pointing-Pointer Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H polytype, has been prepared in the Ba-Ce-Mn-O system. Black-Right-Pointing-Pointer The compound crystallizes in the P6{sub 3}/mmc space group with (cchhh){sub 2} stacking sequence. Black-Right-Pointing-Pointer [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers are separated by [CeO{sub 6}] octahedra in the structure. Black-Right-Pointing-Pointer Instead of robust AFM ordering, a metamagnetic-like transition is found around 50 K.

  5. Probing The Electrode/Electrolyte Interface in The Lithium Excess Layered Oxide Li1.2Ni0.2Mn0.6O2

    SciTech Connect (OSTI)

    Carroll, Kyler J; Qian, Danna; Fell, Chris; Calvin, Scott; Veith, Gabriel M; Chi, Miaofang; Dudney, Nancy J; Meng, Ying Shirley

    2013-01-01

    A detailed surface investigation of the lithium-excess nickel manganese layered oxide Li1.2Ni0.2Mn0.6O2 structure was carried out using x-ray photoelectron spectroscopy (XPS), total electron yield and transmission x-ray absorption spectroscopy (XAS), and electron energy loss spectroscopy (EELS) during the first two electrochemical cycles. All spectroscopy techniques consistently showed the presence of Mn4+ in the pristine material and a surprising reduction of Mn at the voltage plateau during the first charge. The Mn reduction is accompanied by the oxygen loss revealed by EELS. Upon the first discharge, the Mn at the surface never fully returns back to Mn4+. The electrode/electrolyte interface of this compound consists of the reduced Mn at the crystalline defect-spinel inner layer and an oxidized Mn species simultaneously with the presence of a superoxide species in amorphous outer layer. This proposed model signifies that oxygen vacancy formation and lithium removal result in electrolyte decomposition and superoxide formation, leading to Mn activation/dissolution and surface layer-spinel phase transformation. The results also indicate that the role of oxygen is complex and significant in contributing to the extra capacity of this class of high energy density cathode materials.

  6. Effect of Mn doping on the structural, optical, and magnetic properties of In{sub 2}O{sub 3} films

    SciTech Connect (OSTI)

    Wang, Shiqi; An, Yukai; Duan, Lingshen; Liu, Huarui; Liu, Jiwen; Wu, Zhonghua

    2013-11-15

    (In{sub 1−x}Mn{sub x}){sub 2}O{sub 3} films were grown by radio frequency-magnetron sputtering technique. Effect of Mn doping on the structural, optical, and magnetic properties of films is investigated systematically. The detailed structure analyses suggest that Mn ions substitute for In{sup 3+} sites of the In{sub 2}O{sub 3} lattice in the valence of +2 states, and Mn-related secondary phases or clusters as the source of ferromagnetism is safely ruled out. All films show typical room temperature ferromagnetism. The saturation magnetization M{sub s} increases first, and then decreases, while carrier concentration n{sub c} decreases monotonically with Mn doping, implying that the ferromagnetism is not directly induced by the mediated carriers. The optical bandgap E{sub g} of films decreases monotonically with the increase of Mn concentration, and there exists a linear functional dependence between E{sub g} and n{sub c}{sup 2/3}, which is consistent with Burstein-Moss shift arguments. It can be concluded that the ferromagnetic order in Mn-doped In{sub 2}O{sub 3} films is intrinsic, arising from Mn atoms substitution for the In sites of In{sub 2}O{sub 3} lattice. The oxygen vacancies play a mediation role on the ferromagnetic couplings between the Mn ions.

  7. In situ and ex situ spectroelectrochemical and X-ray absorption studies on rechargeable, chemically-modified and other MnO{sub 2} materials

    SciTech Connect (OSTI)

    Conway, B.E.; Qu, D.; McBreen, J. |

    1992-12-31

    A combined series of in situ and ex situ UV spectroelectrochemical and X-ray absorption studies have been made on MnO{sub 2}, chemically-modified by small amounts of Bi(III), and comparatively on other MnO{sub 2} materials such as a blank (Bi-free) and {gamma}-MnO{sub 2}. These procedures are applied in order to follow the oxidation-states of Bi and of Mn during the course of discharge and recharge of MnO{sub 2} as a battery cathode material, and the extents of rechargeability that can be achieved with such materials. Presence of Bi appears to provide a preferred ``heterogeneous`` discharge/recharge pathway involving a soluble Mn(III) intermediate, over the alternative ``electron-proton`` hopping, solid-state mechanism. From XAS results, it is concluded that presence of Bi, although not affecting the O-coordination, does influence the Mn-Mn coordination, determining the way the MnO{sub 2} coordination octahedra are connected.

  8. Mixed metallic Ba(Co,Mn)X{sub 0.2-x}O{sub 3-{delta}} (X=F, Cl) hexagonal perovskites

    SciTech Connect (OSTI)

    Iorgulescu, Mihaela; Roussel, Pascal; Tancret, Nathalie; Renaut, Nicolas; Tiercelin, Nicolas; Mentre, Olivier

    2013-02-15

    We show here that the incorporation of Mn in Ba-Co-oxohalide, BaCoX{sub 0.2-x}O{sub 3-{delta}}, hexagonal perovskite stabilizes the 6H-form (stacking sequence (chhhch Prime ); c, h=[BaO{sub 3}] and h Prime =[BaOX] layers), with tetramers of face-sharing octahedra) rather than the trimeric 10H-form. On the contrary to previous results on the Fe incorporation in similar system leading to more reduced 10H-compounds, the Mn effect is to increase the mean (Co/Mn) valence better suited to the 6H form. We experienced a poor Mn/Co miscibility during our syntheses leading to great difficulties to isolate mixed Co/Mn single phase materials and/or weak reproducibility. Powder neutron diffraction data shows a mixed Mn/Co octahedral occupancy, while the tetrahedra are filled by Co{sup 3+} cations. Anionic vacancies were refined in the h Prime -[BaO{sub 1-z}X{sub 1-x}] layer and the next c-[BaO{sub 3-z}] layers, while the h-[BaO{sub 3}] layers are not oxygen deficient. Magnetic properties suggest that a part of Mn cations remain paramagnetic until low temperature, while isolated spin clusters (probably driven by AFM Co tetrahedral dimers) behave as low-dimensional AFM systems. Transport measurements reveal a transition from high-temperature metallic to low-temperature semi-conducting states that could occur from defect shallow donor upon the Mn for Co substitution. - Graphical abstract: The incorporation of Mn in Ba-Co-oxohalide, BaCoX{sub 0.2-x}O{sub 3-{delta}}, hexagonal perovskite stabilizes the 6H-form with tetrameric (Co,Mn){sub 4}O{sub 15} face sharing linear chains. This results from a oxidizing Mn effect and particular Mn/Co distribution. Highlights: Black-Right-Pointing-Pointer The incorporation of Mn in BaCoX{sub 0.2-x}O{sub 3-{delta}} (X=F,Cl) hexagonal perovskites stabilizes the 6H-form. Black-Right-Pointing-Pointer It contains tetrameric (Co,Mn){sub 4}O{sub 15} face sharing linear chains. Black-Right-Pointing-Pointer The preference for such chains better than trimeric ones is due to the Manganese oxidizing effect. Black-Right-Pointing-Pointer A particular Mn/Co distribution was evidenced. Black-Right-Pointing-Pointer Transport and magnetic properties drastically change during the Mn incorporation.

  9. Structural and Chemical Evolution of Li- and Mn-rich Layered Cathode Material

    SciTech Connect (OSTI)

    Zheng, Jianming; Xu, Pinghong; Gu, Meng; Xiao, Jie; Browning, Nigel D.; Yan, Pengfei; Wang, Chong M.; Zhang, Jiguang

    2015-02-24

    Lithium (Li)- and manganese-rich (LMR) layered-structure materials are very promising cathodes for high energy density lithium-ion batteries. However, their voltage fading mechanism and its relationships with fundamental structural changes are far from being sufficiently understood. Here we report the detailed phase transformation pathway in the LMR cathode (Li[Li0.2Ni0.2Mn0.6]O2) during cycling for the samples prepared by hydro-thermal assistant method. It is found the transformation pathway of LMR cathode is closely correlated to its initial structure and preparation conditions. The results reveal that LMR cathode prepared by HA approach experiences a phase transformation from the layered structure to a LT-LiCoO2 type defect spinel-like structure (Fd-3m space group) and then to a disordered rock-salt structure (Fm-3m space group). The voltage fade can be well correlated with the Li ion insertion into octahedral sites, rather than tetrahedral sites, in both defect spinel-like structure and disordered rock-salt structure. The reversible Li insertion/removal into/from the disordered rock-salt structure is ascribed to the Li excess environment that can satisfy the Li percolating in the disordered rock-salt structure despite the increased kinetic barrier. Meanwhile, because of the presence of a great amount of oxygen vacancies, a significant decrease of Mn valence is detected in the cycled particle, which is below that anticipated for a potentially damaging Jahn-Teller distortion (+3.5). Clarification of the phase transformation pathway, cation redistribution, oxygen vacancy and Mn valence change undoubtedly provides insights into a profound understanding on the voltage fade, and capacity degradation of LMR cathode. The results also inspire us to further enhance the reversibility of LMR cathode via improving its surface structural stability.

  10. Phase transformation during mechano-synthesis of nanocrystalline/amorphous Fe32Mn6Si alloys

    SciTech Connect (OSTI)

    Amini, Rasool; Shamsipoor, Ali; Ghaffari, Mohammad; Alizadeh, Morteza; Okyay, Ali Kemal

    2013-10-15

    Mechano-synthesis of Fe32Mn6Si alloy by mechanical alloying of the elemental powder mixtures was evaluated by running the ball milling process under an inert argon gas atmosphere. In order to characterize the as-milled powders, powder sampling was performed at predetermined intervals from 0.5 to 192 h. X-ray florescence analyzer, X-ray diffraction, scanning electron microscope, and high resolution transmission electron microscope were utilized to investigate the chemical composition, structural evolution, morphological changes, and microstructure of the as-milled powders, respectively. According to the results, the nanocrystalline FeMnSi alloys were completely synthesized after 48 h of milling. Moreover, the formation of a considerable amount of amorphous phase during the milling process was indicated by quantitative X-ray diffraction analysis as well as high resolution transmission electron microscopy image and its selected area diffraction pattern. It was found that the ?-to-? and subsequently the amorphous-to-crystalline (especially martensite) phase transformation occurred by milling development. - Graphical abstract: Mechano-synthesis of nanocrystalline/amorphous Fe32Mn6Si shape memory alloys in the powder form: amorphous phase formation, ?-to-? phase transformation, mechano-crystallization of the amorphous, and martensite phase formation during the process. Highlights: During MA, the ?-to-? phase transformation and amorphization occurred. Mechano-crystallization of the amorphous phase occurred at sufficient milling time. The formation of high amount of ?-martensite was evidenced at high milling times. The platelet, spherical, and then irregular particle shapes was extended by MA. By MA, the particles size was increased, then reduced, and afterward re-increased.

  11. Generation and control of spin-polarized photocurrents in GaMnAs heterostructures

    SciTech Connect (OSTI)

    Bezerra, Anibal T. Farinas, Paulo F.; Studart, Nelson; Degani, Marcos H.; Maialle, Marcelo Z.

    2014-01-13

    Photocurrents are calculated for a specially designed GaMnAs semiconductor heterostructure. The results reveal regions in the infrared range of the energy spectrum, in which the proposed structure is remarkably spin-selective. For such photon energies, the generated photocurrents are strongly spin-polarized. Application of a relatively small static bias in the growth direction of the structure is predicted to efficiently reverse the spin-polarization for some photon energies. This behavior suggests the possibility of conveniently simple switching mechanisms. The physics underlying the results is studied and understood in terms of the spin-dependent properties emerging from the particular potential profile of the structure.

  12. Magnetocrystalline Anisotropy in UMn2Ge2 and Related Mn-based Actinide Ferromagnets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Parker, David S; Mandrus, D.; Ghimire, N J; Baumbach, Ryan; Singleton, John; Thompson, J.D.; Bauer, Eric D.; Li, Ling; Singh, David J

    2015-01-01

    We present magnetization isotherms in pulsed magnetic fields up to 62 Tesla, supported by first principles calculations, demonstrating a huge uniaxial magnetocrystalline anisotropy energy - approximately 20 MJ/m3 - in UMn2Ge2. This large anisotropy results from the extremely strong spin-orbit coupling affecting the uranium 5 f electrons, which in the calculations exhibit a substantial orbital moment exceeding 2 Bohr magnetons. We also find from theoretical calculations that a number of isostructural Mn-actinide compounds are expected to have similarly large anisotropy.

  13. Half metallic ferromagnetism in alkali metal nitrides MN (M = Rb, Cs): A first principles study

    SciTech Connect (OSTI)

    Murugan, A. Rajeswarapalanichamy, R. Santhosh, M. Sudhapriyanga, G.; Kanagaprabha, S.

    2014-04-24

    The structural, electronic and elastic properties of two alkali metal nitrides (MN: M= Rb, Cs) are investigated by the first principles calculations based on density functional theory using the Vienna ab-initio simulation package. At ambient pressure the two nitrides are stable in ferromagnetic state with CsCl structure. The calculated lattice parameters are in good agreement with the available results. The electronic structure reveals that these materials are half metallic in nature. A pressure-induced structural phase transition from CsCl to ZB phase is observed in RbN and CsN.

  14. Vacancy dynamic in Ni-Mn-Ga ferromagnetic shape memory alloys

    SciTech Connect (OSTI)

    Merida, D.; Snchez-Alarcos, V.; Prez-Landazbal, J. I.; Recarte, V.; Plazaola, F.

    2014-06-09

    Vacancies control any atomic ordering process and consequently most of the order-dependent properties of the martensitic transformation in ferromagnetic shape memory alloys. Positron annihilation spectroscopy demonstrates to be a powerful technique to study vacancies in NiMnGa alloys quenched from different temperatures and subjected to post-quench isothermal annealing treatments. Considering an effective vacancy type the temperature dependence of the vacancy concentration has been evaluated. Samples quenched from 1173?K show a vacancy concentration of 1100??200?ppm. The vacancy migration and formation energies have been estimated to be 0.55??0.05?eV and 0.90??0.07?eV, respectively.

  15. Direct evidence of detwinning in polycrystalline Ni-Mn-Ga ferromagnetic shape memory alloys during deformation.

    SciTech Connect (OSTI)

    Nie, Z. H.; Lin Peng, R.; Johansson, S.; Oliver, E. C.; Ren, Y.; Wang, Y. D.; Liu, Y. D.; Deng, J. N.; Zuo, L.; Brown, D. E.; Northwestern Univ., China; Linkoping Univ.; Rutherford Appleton Lab.; Northern Illinois Univ.

    2008-01-01

    In situ time-of-flight neutron diffraction and high-energy x-ray diffraction techniques were used to reveal the preferred reselection of martensite variants through a detwinning process in polycrystalline Ni-Mn-Ga ferromagnetic shape memory alloys under uniaxial compressive stress. The variant reorientation via detwinning during loading can be explained by considering the influence of external stress on the grain/variant orientation-dependent distortion energy. These direct observations of detwinning provide a good understanding of the deformation mechanisms in shape memory alloys.

  16. Magnetic domain wall manipulation in (Ga,Mn)As nanostructures for spintronic applications

    SciTech Connect (OSTI)

    Wosinski, Tadeusz; Andrearczyk, Tomasz; Figielski, Tadeusz; Olender, Karolina; Wrobel, Jerzy

    2014-02-21

    Ring-shaped nanostructures have been designed and fabricated by electron-beam lithography patterning and chemical etching from thin epitaxial layers of the ferromagnetic semiconductor (Ga,Mn)As. The nanostructures, in a form of planar rings with a slit, were supplied with four electrical terminals and subjected to magneto-transport studies under planar weak magnetic field. Magnetoresistive effects caused by manipulation of magnetic domain walls and magnetization reversal in the nanostructures have been investigated and possible applications of the nanostructures as four-terminal spintronic devices are discussed.

  17. Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet {alpha}-NaMnO{sub 2}

    SciTech Connect (OSTI)

    Giot, Maud; Chapon, Laurent C.; Radaelli, Paolo G.; Androulakis, John; Lappas, Alexandros; Green, Mark A.

    2007-12-14

    The magnetic and crystal structures of the {alpha}-NaMnO{sub 2} have been determined by high-resolution neutron powder diffraction. The system maps out a frustrated triangular spin lattice with anisotropic interactions that displays two-dimensional spin correlations below 200 K. Magnetic frustration is lifted through magneto-elastic coupling, evidenced by strong anisotropic broadening of the diffraction profiles at high temperature and ultimately by a structural phase transition at 45 K. In this low-temperature regime a three-dimensional antiferromagnetic state is observed with a propagation vector k=((1/2),(1/2),0)

  18. Magnetic and transport properties of Mn{sub 2}CoAl oriented films

    SciTech Connect (OSTI)

    Jamer, Michelle E.; Assaf, Badih A.; Devakul, Trithep; Heiman, Don

    2013-09-30

    The structure, magnetic, and transport properties of thin films of the Heusler ferrimagnet Mn{sub 2}CoAl have been investigated for properties related to spin gapless semiconductors. Oriented films were grown by molecular beam epitaxy on GaAs substrates and the structure was found to transform from tetragonal to cubic for increasing annealing temperature. The anomalous Hall resistivity is found to be proportional to the square of the longitudinal resistivity and magnetization expected for a topological Berry curvature origin. A delicate balance of the spin-polarized carrier type when coupled with voltage gate-tuning could significantly impact advanced electronic devices.

  19. Neutron structural characterization, inversion degree and transport properties of NiMn{sub 2}O{sub 4} spinel prepared by the hydroxide route

    SciTech Connect (OSTI)

    Sagua, A.; Lescano, Gabriela M.; Alonso, J.A.; Martínez-Coronado, R.; Fernández-Díaz, M.T.; Morán, E.

    2012-06-15

    Graphical abstract: A pure specimen has been synthesized by the hydroxide route. This spinel, studied by NPD, shows an important inversion degree, λ = 0.80. A bond-valence study shows that the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected 3+ and 2+ values, respectively. The mixed valence Mn{sup 3+}/Mn{sup 4+} accounts for a hopping mechanism between adjacent octahedral sites, leading to a significant conductivity. Highlights: ► A low-temperature hydroxide route allowed preparing almost pure specimens of NiMn{sub 2}O{sub 4}. ► NPD essential to determine inversion degree; contrasting Ni and Mn for neutrons. ► Bond valence establishes valence state of octahedral and tetrahedral Ni and Mn ions. ► Thermal analysis, transport measurements complement characterization of this oxide. ► A structure–properties relationship is established. -- Abstract: The title compound has been synthesized by the hydroxide route. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3{sup ¯}m, Z = 8, with a = 8.3940(2) Å at 295 K. The crystallographic formula is (Ni{sub 0.202(1)}Mn{sub 0.798(1)}){sub 8a}(Ni{sub 0.790(1)}Mn{sub 1.210(1)}){sub 16d}O{sub 4} where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively. There is a significant inversion degree of the spinel structure, λ = 0.80. In fact, the variable parameter for the oxygen position, u = 0.2636(4), is far from that expected (u = 0.25) for normal spinels. From a bond-valence study, it seems that the valence distribution in NiMn{sub 2}O{sub 4} spinel is not as trivial as expected (Ni{sup 2+} and Mn{sup 3+}), but clearly the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected +3 and +2 values, respectively. The mixed valence observed at the octahedral sites provides the charge carriers that, by a hopping mechanism between Mn{sup 3+}/Mn{sup 4+} adjacent sites, leads to a significant conductivity, up to 0.85 S cm{sup −1} at 800 °C in air.

  20. Calculations of structural, elastic, electronic, magnetic and phonon properties of FeNiMnAl by the first principles

    SciTech Connect (OSTI)

    U?ur, ?ule; ?yigr, Ahmet

    2014-10-06

    The electronic, elastic and dynamical properties of the quaternary alloy FeNiMnAl have been investigated using a pseudopotential plane wave method within the generalized gradient approximation (GGA). We determined the lattice parameters and the bulk modulus B. In addition, the elastic properties such as elastic constans (C{sub 11}, C{sub 12} and C{sub 44}), the shear modulus G, the young modulus E, the poisson's ratio ? and the B/G ratio are also given. The FeNiMnAl Heusler alloy exhibit a ferromagnetic half-metallic behavior with the total magnetic moment of 4.02 ?{sub B}. The phonon dispersion of FeNiMnAl has been performed using the density functional theory and the direct method with 222 supercell.

  1. Depth-dependent magnetism in epitaxial MnSb thin films: effects of surface passivation and cleaning

    SciTech Connect (OSTI)

    Aldous J. D.; Sanchez-Hanke C.; Burrows, C.W.; Maskery, I.; Brewer, M.S.; Hase, T.P.A.; Duffy, J.A.; Lees, M. Rs; Decoster, T.; Theis, W.; Quesada, A.; Schmid, A.K.; Bell, G.R.

    2012-03-15

    Depth-dependent magnetism in MnSb(0001) epitaxial films has been studied by combining experimental methods with different surface specificities: polarized neutron reflectivity, x-ray magnetic circular dichroism (XMCD), x-ray resonant magnetic scattering and spin-polarized low energy electron microscopy (SPLEEM). A native oxide {approx}4.5 nm thick covers air-exposed samples which increases the film's coercivity. HCl etching efficiently removes this oxide and in situ surface treatment of etched samples enables surface magnetic contrast to be observed in SPLEEM. A thin Sb capping layer prevents oxidation and preserves ferromagnetism throughout the MnSb film. The interpretation of Mn L{sub 3,2} edge XMCD data is discussed.

  2. Itinerant Antiferromagnetism in FeMnP0.8Si0.2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sales, Brian C.; Susner, Michael A.; Conner, Benjamin S.; Yan, Jiaqiang Q.; May, Andrew F.

    2015-01-01

    Compounds based on the Fe2P structure have continued to attract interest because of the interplay between itinerant and localized magnetism in a noncentrosymmetric crystal structure, and because of the recent developments of these materials for magnetocaloric applications. We report the growth and characterization of millimeter-sized single crystals of FeMnP0.8Si0.2 with the Fe2P structure. Single-crystal x-ray diffraction, magnetization, resistivity, and Hall and heat capacity data are reported. The crystals exhibit itinerant antiferromagnetic order below 158 K with no hint of ferromagnetic behavior in the magnetization curves and with the spins ordered primarily in the ab plane. The room-temperature resistivity is closemore » to the Ioffe-Regel limit for a metal. Single-crystal x-ray diffraction indicates a strong preference for Mn to occupy the larger pyramidal 3g site. The cation site preference in the as-grown crystals and the antiferromagnetism were not changed after high-temperature anneals and a rapid quench to room temperature« less

  3. Electronic phase separation in lanthanum manganites: Evidence from {sup 55}Mn NMR

    SciTech Connect (OSTI)

    Allodi, G.; De Renzi, R.; Guidi, G.; Licci, F.; Pieper, M.W.

    1997-09-01

    {sup 55}Mn NMR experiments were carried out at 1.3{endash}4.2 K on six samples of lanthanum manganites, with a hole doping concentration ranging from the antiferromagnetic-insulator to the ferromagnetic-conductor region of the phase diagram. The dependence of the resonance frequencies on external fields is either as expected for ferromagnets (FM) or for antiferromagnets (AF). No indication of a canted phase could be detected. FM and AF resonances were found to coexist in all samples and are grouped in three broad bands, whose frequencies do not depend in first order on hole concentration. Strong evidence of interaction between AF and FM regions was provided by longitudinal relaxation experiments in several samples. An explanation of this behavior is offered in terms of intrinsic phase separation of the holes into FM microdomains. We determine the {sup 55}Mn hyperfine coupling to be isotropic in all cases, with A=6.2T/{mu}{sub B} for the on-site term in the AF domains. {copyright} {ital 1997} {ital The American Physical Society}

  4. Electronic and Magnetic Properties of Li1.5Mn0.5As Alloys in the Cu2Sb

    Office of Scientific and Technical Information (OSTI)

    Structure (Conference) | SciTech Connect Conference: Electronic and Magnetic Properties of Li1.5Mn0.5As Alloys in the Cu2Sb Structure Citation Details In-Document Search Title: Electronic and Magnetic Properties of Li1.5Mn0.5As Alloys in the Cu2Sb Structure Authors: Fong, C Y ; Damewood, L ; Yang, L H ; Felser, C Publication Date: 2012-12-03 OSTI Identifier: 1072409 Report Number(s): LLNL-PROC-606953 DOE Contract Number: W-7405-ENG-48 Resource Type: Conference Resource Relation: Conference:

  5. Electronic and Magnetic Properties of Li1.5Mn0.5As Alloys in the Cu2Sb

    Office of Scientific and Technical Information (OSTI)

    Structure (Conference) | SciTech Connect Conference: Electronic and Magnetic Properties of Li1.5Mn0.5As Alloys in the Cu2Sb Structure Citation Details In-Document Search Title: Electronic and Magnetic Properties of Li1.5Mn0.5As Alloys in the Cu2Sb Structure × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize

  6. LaL2SrL8Mn207BelowTc : Exchange StricthR ECEI VED

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    088-00-105 58916-00-105 9714E3 co C--q 03/64 - 1 Sign Reversal of the MN-0 bond Compressibility r in LaL2SrL8Mn207BelowTc : Exchange StricthR ECEI VED in the Ferromagnetic State JUL Q 7 1997 O S T I D. N. Argyriout§ J. F. Mitchell, J. B. Goodenough * , 0. Chmaissemt S. Short, and J. D. Jorgensen t Science and Technology Center for Superconductivity and Materials Science Division Argonne National Laboratory Argonne, IL 60439 * Center for Materials Science and Engineering, ECT 9.102 University of

  7. Influence of defects on the structural and magnetic properties of multifunctional La2NiMnO6 thin films

    SciTech Connect (OSTI)

    Guo, HZ; Burgess, J; Ada, E; Street, S; Gupta, A.; Iliev, M N; Kellock, A J; Magen Dominguez, Cesar; Varela del Arco, Maria; Pennycook, Stephen J

    2008-01-01

    Thin films of the double perovskite La2NiMnO6 (LNMO) have been grown on various lattice-matched substrates (SrTiO3, LaAlO3, NdGaO3 and MgO) by pulsed laser deposition under varying oxygen background pressure (25 - 800 mTorr). The out-of-plane lattice constant of the LNMO film initially decreases with increasing pressure, likely caused by a reduction in the defect concentration and improved structural ordering, before leveling off at higher pressures. Scanning transmission electron microscopy results show that the films are epitaxial, and the interface is sharp and coherent. While very few defects are observed by STEM in a film grown at high oxygen pressure (800 mTorr), a film grown at a lower pressure (100 mTorr) shows the formation of defects that extend throughout the thickness except for a very thin layer near the interface. The Raman spectra of the films are dominated by two broad peaks at around 540 cm-1 and 685 cm-1, which are assigned to the antisymmetric stretching (AS) and symmetric stretching (S) modes of MnO6 and NiO6 octahedra, respectively. The Raman peaks of the LNMO thin films grown in 800 mTorr background O2 are blue shifted in comparison to those of LNMO bulk, and the shift increases with decreasing film thickness, indicating the increased influence of strain. The critical thickness for strain relaxation as determined from the Raman spectra is between 40 - 80 nm. The strain is observed to have a negligible influence on the magnetic properties for films grown at high oxygen pressures. However, films grown at low pressures exhibit degraded magnetic properties, which can be attributed to a combination of B-site cation disorder and an increase in the concentration of Mn3+ and Ni3+ Jahn-Teller ions caused by oxygen defects. With increasing oxygen pressure during growth, the paramagnetic-ferromagnetic transition temperature (~280 K) gets sharper and the saturation magnetization at low temperatures is enhanced. Based on electron energy loss spectroscopy studies, the Mn and Ni ions in LNMO thin films are determined to be mixed-valent Mn3+/Mn4 +, and a charge transition disproportionation of the type Mn4+ + Ni2+ _ Mn3+ + Ni3+ likely occurs with increasing oxygen deficiency.

  8. Spectroscopic and magnetic properties of Mn doped GaN epitaxial films grown by plasma assisted molecular beam epitaxy

    SciTech Connect (OSTI)

    Vidyasagar, R.; Lin, Y.-T.; Tu, L.-W.

    2012-12-15

    Graphical abstract: We report here that micro-Raman scattering spectrum for Mn doped GaN thin film has displayed a new peak manifested at 578 cm{sup −1}, by which it is attributed to interior LVM originated by the incorporation of Mn ions in place of Ga sites. Mn doped GaN thin film also showed the typical negative magnetoresistance up to ∼50 K, revealing that the film showed magnetic ordering of spins below 50 K. Display Omitted Highlights: ► GaN and Mn doped GaN single phase wurtzite structures grown by PAMBE. ► The phase purity of the epilayers investigated by HRXRD, HRSEM and EDX. ► The red shift in near band edge emission has been observed using micro-PL. ► A new peak related LVM at 578 cm{sup −1} in micro-Raman scattering measurements confirmed Mn doped into GaN. ► Negative-magnetoresistance investigations have showed that the film has T{sub c} < 50 K. -- Abstract: Spectroscopic and magnetic properties of Mn doped GaN, and GaN epitaxial films have been investigated by employing micro-photoluminescence, micro-Raman, and temperature dependent magneto-resistance measurements. The HR-XRD profiles have shown that the epitaxial films are in hexagonal wurtzite structures. Morphology and composition of the films have been examined by field emission scanning electron microscopy, and energy-dispersive X-ray analysis. Micro-photoluminescence spectrum displayed a dominant near band edge emission at 362 nm, which is assigned to near band edge transition within the hexagonal structure of GaN. Raman scattering profiles showed a new vibrational mode at 578 cm{sup −1}, which is attributed to the vacancy-related local vibrational mode of Mn occupying the Ga site. Temperature dependent negative magnetoresistance measurements provide a direct evidence of magnetic ordering below 50 K for the Mn doped GaN thin film.

  9. Suppression of the thermal hysteresis in magnetocaloric MnAs thin film by highly charged ion bombardment

    SciTech Connect (OSTI)

    Trassinelli, M. Marangolo, M.; Eddrief, M.; Etgens, V. H.; Gafton, V.; Hidki, S.; Lacaze, E.; Lamour, E.; Prigent, C.; Rozet, J.-P.; Steydli, S.; Zheng, Y.; Vernhet, D.

    2014-02-24

    We present the investigation on the modifications of structural and magnetic properties of MnAs thin film epitaxially grown on GaAs induced by slow highly charged ions bombardment under well-controlled conditions. The ion-induced defects facilitate the nucleation of one phase with respect to the other in the first-order magneto-structural MnAs transition, with a consequent suppression of thermal hysteresis without any significant perturbation on the other structural and magnetic properties. In particular, the irradiated film keeps the giant magnetocaloric effect at room temperature opening new perspective on magnetic refrigeration technology for everyday use.

  10. Thermochemical generation of hydrogen and oxygen from water. [NaMnO/sub 2/ and TiO/sub 2/

    DOE Patents [OSTI]

    Robinson, P.R.; Bamberger, C.E.

    1980-02-08

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO/sub 2/) and titanium dioxide (TiO/sub 2/) to form sodium titanate (Na/sub 2/TiO/sub 3/), manganese (II) titanate (MnTiO/sub 3/) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  11. Pantex Regional Middle School Science Bowl | U.S. DOE Office...

    Office of Science (SC) Website

    TX Collingsworth County, TX Crosby County, TX Dallam County, TX Dawson County, TX Deaf Smith County, TX Donley County, TX Floyd County, TX Gaines County, TX Garza County, TX Gray ...

  12. Pantex Regional High School Science Bowl | U.S. DOE Office of...

    Office of Science (SC) Website

    TX Cottle County, TX Crosby County, TX Dallam County, TX Dawson County, TX Deaf Smith County, TX Dickens County, TX Donley County, TX Floyd County, TX Gaines County, TX ...

  13. Electronic and magnetic properties of double perovskite Dy{sub 2}MnCoO{sub 6} by first-principles calculation

    SciTech Connect (OSTI)

    Ganeshraj, C.; Santhosh, P. N.

    2014-05-07

    Using first-principles calculation, we investigate electronic and magnetic properties of Dy{sub 2}MnCoO{sub 6}. A detailed structural optimization has been done and found that the orthorhombic structure with Mn (Co) ions aligning along the longest axis type is the most stable structure. Within the generalized gradient approximation, the spin polarized calculations predict Dy{sub 2}MnCoO{sub 6} to be a half-metallic with ferromagnetic interaction between Mn and Co ions and antiferromagnetic interaction between Dy and Mn/Co ions. We also investigate the effect of Hubbard parameter (U) on the ground state magnetic structure. For all values of Hubbard U parameter the Co ions have nonzero magnetic moment; they do not lie in low-spin state, as in DyCoO{sub 3}.

  14. CdSe/ZnSe quantum dot with a single Mn{sup 2+} ionA new system for a single spin manipulation

    SciTech Connect (OSTI)

    Smole?ski, T.

    2015-03-21

    We present a magneto-optical study of individual self-assembled CdSe/ZnSe quantum dots doped with single Mn{sup 2+} ions. Properties of the studied dots are analyzed analogously to more explored system of Mn-doped CdTe/ZnTe dots. Characteristic sixfold splitting of the neutral exciton emission line as well as its evolution in the magnetic field are described using a spin Hamiltonian model. Dynamics of both exciton recombination and Mn{sup 2+} spin relaxation are extracted from a series of time-resolved experiments. Presence of a single dopant is shown not to affect the average excitonic lifetime measured for a number of nonmagnetic and Mn-doped dots. On the other hand, non-resonant pumping is demonstrated to depolarize the Mn{sup 2+} spin in a quantum dot placed in external magnetic field. This effect is utilized to determine the ion spin relaxation time in the dark.

  15. Electrochemically induced deposition method to prepare {gamma}-MnO{sub 2}/multi-walled carbon nanotube composites as electrode material in supercapacitors

    SciTech Connect (OSTI)

    Fan Zhen

    2008-08-04

    The {gamma}-MnO{sub 2}/multi-walled carbon nanotube ({gamma}-MnO{sub 2}/MWNT) composite has been prepared by electrochemically induced deposition method. The morphology and crystal structure of the composite were investigated by X-ray diffraction and scanning electron microscopy, respectively. The capacitive properties of the {gamma}-MnO{sub 2}/MWNT composite have been investigated by cyclic voltammetry (CV). A specific capacitance (based on {gamma}-MnO{sub 2}) as high as 579 F g{sup -1} is obtained at a scan rate of 10 mV s{sup -1} in 0.1 M Na{sub 2}SO{sub 4} aqueous solution. Additionally, the {gamma}-MnO{sub 2}/MWNT composite electrode shows excellent long-term cycle stability (only 2.4% decrease of the specific capacitance is observed after 500 CV cycles)

  16. Induced Ti magnetization at La0.7Sr0.3MnO3 and BaTiO3 interfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Yaohua; Tornos, J.; te Velthuis, S. G. E.; Freeland, J. W.; Zhou, H.; Steadman, P.; Bencok, P.; Leon, C.; Santamaria, J.

    2016-04-01

    In artificial multiferroics hybrids consisting of ferromagnetic La0.7Sr0.3MnO3 (LSMO) and ferroelectric BaTiO3 epitaxial layers, net Ti moments are found from polarized resonant soft x-ray reflectivity and absorption. Moreover, the Ti dichroic reflectivity follows the Mn signal during the magnetization reversal, indicating exchange coupling between the Ti and Mn ions. But, the Ti dichroic reflectivity shows stronger temperature dependence than the Mn dichroic signal. Besides a reduced ferromagnetic exchange coupling in the interfacial LSMO layer, this may also be attributed to a weak Ti-Mn exchange coupling that is insufficient to overcome the thermal energy at elevated temperatures.

  17. Radiation-induced instability of MnS precipitates and its possible consequences on irradiation-induced stress corrosion cracking of austenitic stainless steels

    SciTech Connect (OSTI)

    Chung, H.M.; Sanecki, J.E.; Garner, F.A.

    1996-12-01

    Irradiation-assisted stress corrosion cracking (IASCC) is a significant materials issue for the light water reactor (LWR) industry and may also pose a problem for fusion power reactors that will use water as coolant. A new metallurgical process is proposed that involves the radiation-induced release into solution of minor impurity elements not usually thought to participate in IASCC. MnS-type precipitates, which contain most of the sulfur in stainless steels, are thought to be unstable under irradiation. First, Mn transmutes strongly to Fe in thermalized neutron spectra. Second, cascade-induced disordering and the inverse Kirkendall effect operating at the incoherent interfaces of MnS precipitates are thought to act as a pump to export Mn from the precipitate into the alloy matrix. Both of these processes will most likely allow sulfur, which is known to exert a deleterious influence on intergranular cracking, to re-enter the matrix. To test this hypothesis, compositions of MnS-type precipitates contained in several unirradiated and irradiated heats of Type 304, 316, and 348 stainless steels (SSs) were analyzed by Auger electron spectroscopy. Evidence is presented that shows a progressive compositional modification of MnS precipitates as exposure to neutrons increases in boiling water reactors. As the fluence increases, the Mn level in MnS decreases, whereas the Fe level increases. The S level also decreases relative to the combined level of Mn and Fe. MnS precipitates were also found to be a reservoir of other deleterious impurities such as F and O which could be also released due to radiation-induced instability of the precipitates.

  18. Synthesis, crystal structure, and vibrational spectroscopic and UV-visible studies of Cs{sub 2}MnP{sub 2}O{sub 7}

    SciTech Connect (OSTI)

    Kaoua, Saida; Krimi, Saida; Pechev, Stanislav; Gravereau, Pierre; Chaminade, Jean-Pierre; Couzi, Michel; El Jazouli, Abdelaziz

    2013-02-15

    A new member of the A{sub 2}MP{sub 2}O{sub 7} diphosphate family, Cs{sub 2}MnP{sub 2}O{sub 7}, has been synthesized and structurally characterized. The crystal structure was determined by single crystal X-Ray diffraction. Cs{sub 2}MnP{sub 2}O{sub 7} crystallizes in the orthorhombic system, space group Pnma ( Music-Sharp-Sign 62), with the unit cell parameters a=16.3398(3), b=5.3872(1), c=9.8872(2) A, Z=4 and V=870.33(3) A{sup 3}. The structure parameters were refined to a final R{sub 1}/wR{sub 2}=0.0194/0.0441 for 1650 observed reflections. The 2D framework of Cs{sub 2}MnP{sub 2}O{sub 7} structure consists of P{sub 2}O{sub 7} and MnO{sub 5} units. The corner-shared MnO{sub 5} and P{sub 2}O{sub 7} units are alternately arranged along the b axis to form [(MnO)P{sub 2}O{sub 7}]{sub {infinity}} chains. These chains are interconnected by an oxygen atom to form sheets parallel to the (b, c) plane. The cesium atoms are located between the sheets in 9- and 10-fold coordinated sites. The infrared and Raman vibrational spectra have been investigated. A factor group analysis leads to the determination of internal modes of (P{sub 2}O{sub 7}) groups. UV-visible spectrum consists of weak bands, between 340 and 700 nm, assigned to the forbidden d-d transitions of Mn{sup 2+} ion, and of a strong band around 250 nm, attributed to the O--Mn charge transfer. - Graphical abstract: Structure of Cs{sub 2}MnP{sub 2}O{sub 7}: The 2D structure of Cs{sub 2}MnP{sub 2}O{sub 7} is built from P{sub 2}O{sub 7} diphosphate groups and MnO{sub 5} square pyramids which share corners and form [(MnO)P{sub 2}O{sub 7}]{sub {infinity}} chains along b axis. These chains are interconnected by an oxygen atom to form wavy (MnP{sub 2}O{sub 7}){sup 2-} sheets parallel to the (b, c) plane. The cesium ions are located between these sheets in the inter-layers space, in zigzag positions. Highlights: Black-Right-Pointing-Pointer A new diphosphate, Cs{sub 2}MnP{sub 2}O{sub 7}, has been synthesized and structurally characterized. Black-Right-Pointing-Pointer The structure consists of a 2D framework built up from (MnP{sub 2}O{sub 7}) sheets. Black-Right-Pointing-Pointer The sheets consist of [(MnO)P{sub 2}O{sub 7}]{sub {infinity}} chains formed by P{sub 2}O{sub 7} units and MnO{sub 5} square pyramids. Black-Right-Pointing-Pointer A factor group analysis leads to the determination of internal modes of (P{sub 2}O{sub 7}) groups. Black-Right-Pointing-Pointer UV-visible spectrum consists bands assigned to d-d transitions of Mn{sup 2+} ion and to O--Mn CT.

  19. Magnetic BiMn-α phase synthesis prediction: First-principles calculation, thermodynamic modeling and nonequilibrium chemical partitioning

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, S. H.; Liu, C.; Yao, Y. X.; Du, Y.; Zhang, L. J.; Wang, C. -Z.; Ho, K. -M.; Kramer, M. J.

    2016-04-29

    BiMn-α is promising permanent magnet. Due to its peritectic formation feature, there is a synthetic challenge to produce single BiMn-α phase. The objective of this study is to assess driving force for crystalline phase pathways under far-from-equilibrium conditions. First-principles calculations with Hubbard U correction are performed to provide a robust description of the thermodynamic behavior. The energetics associated with various degrees of the chemical partitioning are quantified to predict temperature, magnetic field, and time dependence of the phase selection. By assessing the phase transformation under the influence of the chemical partitioning, temperatures, and cooling rate from our calculations, we suggestmore » that it is possible to synthesize the magnetic BiMn-α compound in a congruent manner by rapid solidification. The external magnetic field enhances the stability of the BiMn-α phase. In conclusion, the compositions of the initial compounds from these highly driven liquids can be far from equilibrium.« less

  20. Excess Ni-doping induced enhanced room temperature magneto-functionality in Ni-Mn-Sn based shape memory alloy

    SciTech Connect (OSTI)

    Pramanick, S.; Giri, S.; Majumdar, S.; Chatterjee, S.

    2014-09-15

    Present work reports on the observation of large magnetoresistance (??30% at 80 kOe) and magnetocaloric effect (?12?Jkg{sup ?1}K{sup ?1} for 050 kOe) near room temperature (?290?K) on the Ni-excess ferromagnetic shape memory alloy Ni{sub 2.04}Mn{sub 1.4}Sn{sub 0.56}. The sample can be thought of being derived from the parent Ni{sub 2}Mn{sub 1.4}Sn{sub 0.6} alloy, where excess Ni was doped at the expense of Sn. Such Ni doping enhances the martensitic transition temperature and for the Ni{sub 2.04}Mn{sub 1.4}Sn{sub 0.56} it is found to be optimum (288?K). The doped alloy shows enhanced magneto-functional properties as well as reduced saturation magnetization as compared to the undoped counterpart at low temperature. A probable increment of antiferromagnetic correlation between Mn-atoms on Ni substitution can be accounted for the enhanced magneto-functional properties as well as reduction in saturation moment.

  1. Unusual magnetic hysteresis and the weakened transition behavior induced by Sn substitution in Mn{sub 3}SbN

    SciTech Connect (OSTI)

    Sun, Ying, E-mail: sunying@buaa.edu.cn [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng; Li, Jun; Wang, Xia [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [Materials Processing Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan); Wang, Cong [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); Feng, Hai L.; Sathish, Clastin I.; Yamaura, Kazunari, E-mail: yamaura.kazunari@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Matsushita, Yoshitaka [Analysis Station, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan)

    2014-01-28

    Substitution of Sb with Sn was achieved in ferrimagnetic antiperovskite Mn{sub 3}SbN. The experimental results indicate that with an increase in Sn concentration, the magnetization continuously decreases and the crystal structure of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N changes from tetragonal to cubic phase at around x of 0.8. In the doping series, step-like anomaly in the isothermal magnetization was found and this behavior was highlighted at x?=?0.4. The anomaly could be attributed to the magnetic frustration, resulting from competition between the multiple spin configurations in the antiperovskite lattice. Meantime, H{sub c} of 18 kOe was observed at x?=?0.3, which is probably the highest among those of manganese antiperovskite materials reported so far. With increasing Sn content, the abrupt change of resistivity and the sharp peak of heat capacity in Mn{sub 3}SbN were gradually weakened. The crystal structure refinements indicate the weakened change at the magnetic transition is close related to the change of c/a ratio variation from tetragonal to cubic with Sn content. The results derived from this study indicate that the behavior of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N could potentially enhance its scientific and technical applications, such as spin torque transfer and hard magnets.

  2. Controlled fabrication and tunable photoluminescence properties of Mn{sup 2+} doped grapheneZnO composite

    SciTech Connect (OSTI)

    Luan, Xinglong; Zhang, Yihe Tong, Wangshu; Shang, Jiwu; An, Qi; Huang, Hongwei

    2014-11-15

    Highlights: GrapheneZnO composites were synthesized by a mixed solvothermal method. ZnO quantum dots are distributed uniformly on the graphene sheets. A possible hypothesis is raised for the influence of graphene oxide on the nucleation of ZnO. Mn{sup 2+} doped grapheneZnO composites were fabricated and the emission spectra can be tuned by doping. - Abstract: GrapheneZnO composites (GZnO) with controlled morphology and photoluminescence property were synthesized by a mixed solvothermal method. Mixed solvent were composed by dimethyl sulfoxide and ethylene glycol. Fourier transform infrared spectroscopy, transmission electron microscopy and photoluminescence spectra were used to characterize GZnO. Graphene as a substrate can help the distribution and the dispersity of ZnO, and a possible model of the interaction between graphene oxide and ZnO particles is proposed. At the same time, graphene also reduce the size of ZnO particles to about 5 nm. Furthermore, Mn{sup 2+} ions dopes GZnO successfully by the mixed solvothermal synthesis and the doping of Mn{sup 2+} makes GZnO shift red from 465 nm to 548 nm and 554 nm in the emission spectrum. The changes of the emission spectrum by the adding of Mn{sup 2+} make GZnO have tunable photoluminescence spectrum which is desirable for practical applications.

  3. Magnetic properties of MnSb inclusions formed in GaSb matrix directly during molecular beam epitaxial growth

    SciTech Connect (OSTI)

    Lawniczak-Jablonska, Krystyna; Wolska, Anna; Klepka, Marcin T.; Kret, Slawomir; Kurowska, Boguslawa; Kowalski, Bogdan J.; Twardowski, Andrzej; Wasik, Dariusz; Kwiatkowski, Adam; Sadowski, Janusz

    2011-04-01

    Despite of intensive search for the proper semiconductor base materials for spintronic devices working at room temperature no appropriate material based on ferromagnetic semiconductors has been found so far. We demonstrate that the phase segregated system with MnSb hexagonal inclusions inside the GaSb matrix, formed directly during the molecular beam epitaxial growth reveals the ferromagnetic properties at room temperature and is a good candidate for exploitation in spintronics. Furthermore, the MnSb inclusions with only one crystalline structure were identified in this GaMn:MnSb granular material. The SQUID magnetometry confirmed that this material exhibits ferromagnetic like behavior starting from helium up to room temperature. Moreover, the magnetic anisotropy was found which was present also at room temperature, and it was proved that by choosing a proper substrate it is possible to control the direction of easy axis of inclusions' magnetization moment between in-plane and out-of-plane; the latter is important in view of potential applications in spintronic devices.

  4. SANDIA REPORT;SF 1075-SUR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Table 1: IFT&E Vendor Participants Company Test Campaign C Speed Tyler, MN (CARSR) Raytheon SRC Booz Allen Hamilton Abilene, TX (ASR-11) Terma Aveillant (collaboration with Saab ...

  5. RPT_PERIOD","R_S_NAME","LINE_NUM","PROD_CODE","PROD_NAME","PORT...

    U.S. Energy Information Administration (EIA) Indexed Site

    & ROAD OIL",3501,"MINNEAPOLIS, MN","MINNESOTA",2,260,"CANADA",3,0,0,,,,, 39478,"ALPAC MARKETING SERV ",1,130,"MOTOR GAS, CONVENTIONAL, OTHER",5301,"HOUSTON, TX","TEXAS",3,190,"BELG...

  6. Warroad, MN Natural Gas Pipeline Imports From Canada (Dollars per Thousand

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.14 2.22 1.71 2.06 2000's 3.95 4.52 3.16 5.63 6.15 8.28 7.94 6.75 8.50 4.24 2010's 4.69 4.17 3.06 3.94 5.95 3.32 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Price of Natural Gas Pipeline Imports by Point of Entry Warroad, MN Natural Gas Exports

  7. Warroad, MN Natural Gas Pipeline Imports From Canada (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 685 512 473 412 2000's 4,576 5,318 5,374 4,925 4,793 4,982 3,563 4,813 4,800 4,380 2010's 4,325 4,551 4,610 4,835 3,997 3,968 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Natural Gas Pipeline Imports by Point of Entry Warroad, MN Natural Gas Exports to

  8. The manifestation of spin-phonon coupling in CaMnO{sub 3}

    SciTech Connect (OSTI)

    Goian, V. Kamba, S.; Borodavka, F.; Nuzhnyy, D.; Savinov, M.; Belik, A. A.

    2015-04-28

    Recently predicted presence of spin-phonon coupling in the CaMnO{sub 3} is experimentally confirmed in infrared (IR), Raman and time-domain THz spectra. Most of phonon frequencies seen below 350?cm{sup ?1} exhibit significant shifts on cooling below antiferromagnetic phase transition at T{sub N}???120?K. Moreover, several new modes activate in the IR and Raman spectra on cooling below T{sub N}. Sum of phonon contributions to static permittivity exhibits small but reliable anomaly at T{sub N}. On the other hand, the spin-phonon coupling is not manifested in temperature dependence of radio-frequency permittivity, because intrinsic permittivity is screened by extrinsic contribution from conductivity, which enhances the permittivity to giant values.

  9. High Curie temperature of Ce-Fe-Si compounds with ThMn12 structure

    SciTech Connect (OSTI)

    Zhou, C; Pinkerton, FE; Herbst, JF

    2015-01-15

    We report the discovery of ternary CeFe(12-x)Si(x)compounds possessing the ThMn12 structure. The samples were prepared by melt spinning followed by annealing. In contrast to other known Ce Fe-based binary and ternary compounds, CeFe12-xSix compounds exhibit exceptionally high Curie temperatures whose values increase with added Si substitution. The highest T. = 583 K in CeFe10Si2 rivals that of the well-established Nd2Fe14B compound. We ascribe the T-c behavior to a combination of Si-induced 3d band structure changes and partial Ce3+ stabilization. (C) 2014 Published by Elsevier Ltd.

  10. Magnetic structure and spin excitations in BaMn2Bi2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Calder, Stuart A.; Saparov, Bayrammurad I; Cao, H. B.; Niedziela, Jennifer L.; Lumsden, Mark D.; Sefat, Athena Safa; Christianson, Andrew D.

    2014-02-19

    We present a single crystal neutron scattering study of BaMn2Bi2, a recently synthesized material with the same ThCr2Si2type structure found in several Fe-based unconventional superconducting materials. We show long range magnetic order, in the form of a G-type antiferromagnetic structure, to exist up to 390 K with an indication of a structural transition at 100 K. Utilizing inelastic neutron scattering we observe a spin-gap of 16 meV, with spin-waves extending up to 55 meV. We find these magnetic excitations are well fit to a J1-J2-Jc Heisenberg model and present values for the exchange interactions. The spin wave spectrum appears tomore » be unchanged by the 100 K structural phase transition.« less

  11. NaNi sub 3 Mn sub 2 alloy as a tritium storage material

    SciTech Connect (OSTI)

    Ide, T.; Okuno, K.; Konishi, S.; Sakai, F.; Fukui, H.; Enoeda, M.; Naruse, Y.; Anderson, J.L.; Bartlit, J.R.; Los Alamos National Lab., NM )

    1989-01-01

    An all metal apparatus has been constructed and installed in the main cell of the Tritium System Assembly (TSTA) at Los Alamos National Laboratory, as a separate experiment, to handle about 2600 Ci of tritium for study of metal tritides of potential application for storing tritium in fusion fuel processing. The apparatus is similar to that used for protium/deuterium gas but some modifications were made to assure safe handling of tritium. The pressure-composition isotherms for the LaNi{sub 3}Mn{sub 2}-protium (H), deuterium (D) and tritium (T) system were measured to study isotopic effects in the temperature range of 60 {degree}C to 250 {degree}C, the pressure range below 120 kPa. 2 refs., 10 figs.

  12. Noyes, MN Natural Gas Pipeline Imports From Canada (Dollars per Thousand

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.40 2.46 2.07 2.29 2000's 3.75 4.19 3.09 5.04 5.77 8.01 6.82 6.72 8.48 4.21 2010's 4.49 4.15 2.86 3.87 5.59 2.88 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 4/29/2016 Next Release Date: 5/31/2016 Referring Pages: U.S. Price of Natural Gas Pipeline Imports by Point of Entry Noyes, MN Natural Gas Exports

  13. Strain-induced dimensionality crossover of precursor modulations in Ni{sub 2}MnGa

    SciTech Connect (OSTI)

    Nie, Zhihua E-mail: ydwang@neu.edu.cn; Wang, Yandong E-mail: ydwang@neu.edu.cn; Shang, Shunli; Wang, Yi; Liu, Zi-Kui; Zeng, Qiaoshi; Ren, Yang; Liu, Dongmei; Yang, Wenge

    2015-01-12

    Precursor modulations often occur in functional materials like magnetic shape memory alloys, ferroelectrics, and superconductors. In this letter, we have revealed the underlying mechanism of the precursor modulations in ferromagnetic shape memory alloys Ni{sub 2}MnGa by combining synchrotron-based x-ray diffraction experiments and first-principles phonon calculations. We discovered the precursor modulations along [011] direction can be eliminated with [001] uniaxial loading, while the precursor modulations or premartensite can be totally suppressed by hydrostatic pressure condition. The TA{sub 2} phonon anomaly is sensitive to stress induced lattice strain, and the entire TA{sub 2} branch is stabilized along the directions where precursor modulations are eliminated by external stress. Our discovery bridges precursor modulations and phonon anomalies, and sheds light on the microscopic mechanism of the two-step superelasticity in precursor martensite.

  14. Magnetic-field-induced transformation in FeMnGa alloys

    SciTech Connect (OSTI)

    Zhu, W.; Liu, E. K.; Feng, L.; Tang, X. D.; Chen, J. L.; Wu, G. H.; Liu, H. Y.; Meng, F. B.; Luo, H. Z.

    2009-11-30

    A kind of ferromagnetic shape memory alloy with off-stoichiometric composition of Heusler alloy Fe{sub 2}MnGa has been synthesized. By optimizing composition, the martensitic transformation has been modified to occur at about 163 K accompanying spontaneous magnetization, which enables a magnetic field-induced structural transition from a paramagnetic parent phase to a ferromagnetic martensite with high magnetization of 93.8 emu/g. The material performs a quite large lattice distortion through the transformation, (c-a)/c=33.5%, causing a shape memory strain upto 3.6%. Such large lattice distortions strongly influence the electron structures, and thus some special physical behavior related to the transport and conductive properties is investigated.

  15. The magnetic ordering in high magnetoresistance Mn-doped ZnO thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Venkatesh, S.; Baras, A.; Lee, J. -S.; Roqan, I. S.

    2016-03-24

    Here, we studied the nature of magnetic ordering in Mn-doped ZnO thin films that exhibited ferromagnetism at 300 K and superparamagnetism at 5 K. We directly inter-related the magnetisation and magnetoresistance by invoking the polaronpercolation theory and variable range of hopping conduction below the metal-to-insulator transition. By obtaining a qualitative agreement between these two models, we attribute the ferromagnetism to the s-d exchange-induced spin splitting that was indicated by large positive magnetoresistance (~40 %). Low temperature superparamagnetism was attributed to the localization of carriers and non-interacting polaron clusters. This analysis can assist in understanding the presence or absence of ferromagnetismmore » in doped/un-doped ZnO.« less

  16. High spin polarization in CoFeMnGe equiatomic quaternary Heusler alloy

    SciTech Connect (OSTI)

    Bainsla, Lakhan; Suresh, K. G.; Nigam, A. K.; Manivel Raja, M.; Varaprasad, B. S. D. Ch. S.; Takahashi, Y. K.; Hono, K.

    2014-11-28

    We report the structure, magnetic property, and spin polarization of CoFeMnGe equiatomic quaternary Heusler alloy. The alloy was found to crystallize in the cubic Heusler structure (prototype LiMgPdSn) with considerable amount of DO{sub 3} disorder. Thermal analysis result indicated the Curie temperature is about 750 K without any other phase transformation up to melting temperature. The magnetization value was close to that predicted by the Slater-Pauling curve. Current spin polarization of P = 0.70 ± 0.01 was deduced using point contact andreev reflection measurements. The temperature dependence of electrical resistivity has been fitted in the temperature range of 5–300 K in order to check for the half metallic behavior. Considering the high spin polarization and Curie temperature, this material appears to be promising for spintronic applications.

  17. Structural controlled magnetic anisotropy in Heusler L1{sub 0}-MnGa epitaxial thin films

    SciTech Connect (OSTI)

    Wang Kangkang; Lu Erdong; Smith, Arthur R.; Knepper, Jacob W.; Yang Fengyuan

    2011-04-18

    Ferromagnetic L1{sub 0}-MnGa thin films have been epitaxially grown on GaN, sapphire, and MgO substrates using molecular beam epitaxy. Using diffraction techniques, the epitaxial relationships are determined. It is found that the crystalline orientation of the films differ due to the influence of the substrate. By comparing the magnetic anisotropy to the structural properties, a clear correlation could be established indicating that the in-plane and out-of-plane anisotropy is directly determined by the crystal orientation of the film and could be controlled via selection of the substrates. This result could be helpful in tailoring magnetic anisotropy in thin films for spintronic applications.

  18. Electric field-induced magnetic switching in Mn:ZnO film

    SciTech Connect (OSTI)

    Ren, S. X.; Sun, G. W.; Zhao, J.; Dong, J. Y.; Zhao, X.; Chen, W.; Wei, Y.; Ma, Z. C.

    2014-06-09

    A large magnetic modulation, accompanied by stable bipolar resistive switching (RS) behavior, was observed in a Mn:ZnO film by applying a reversible electric field. A significant enhancement of the ferromagnetism of the film, to about five times larger than that in the initial (as-grown) state (IS), was obtained by switching the film into the low resistance state. X-ray photoelectron spectroscopy demonstrated the existence of abundant oxygen vacancies in the IS of the film. We suggest that this electric field-induced magnetic switching effect originates with the migration and redistribution of oxygen vacancies during RS. Our work indicates that electric switching is an effective and simple method to increase the ferromagnetism of diluted magnetic oxide films. This provides a promising direction for research in spintronic devices.

  19. Evidence of martensitic phase transitions in magnetic Ni-Mn-In thin films

    SciTech Connect (OSTI)

    Sokolov, A.; Zhang, Le; Dubenko, I.; Samanta, T.; Ali, N.; Stadler, S.

    2013-02-18

    Ni{sub 50}Mn{sub 35}In{sub 15} Heusler alloy thin films (with thicknesses of about 10 nm) have been grown on single crystal MgO and SrTiO{sub 3} (STO) (100) substrates using a laser-assisted molecular beam epitaxy method. Films of mixed austenitic and martensitic phases and of pure martensitic phase have been detected for those grown on MgO and STO substrates, respectively. Thermomagnetic curves were measured using a SQUID magnetometer and are consistent with those of off-stoichiometric In-based bulk Heusler alloys, including a martensitic transition at T = 315 K for films grown on MgO. The differences in the properties of the films grown on MgO and STO are discussed.

  20. Highly mobile type II twin boundary in Ni-Mn-Ga five-layered martensite

    SciTech Connect (OSTI)

    Sozinov, A.; Lanska, N.; Soroka, A.; Straka, L.

    2011-09-19

    Twin relationships and stress-induced reorientation were studied in Ni{sub 2}Mn{sub 1.14}Ga{sub 0.86} single crystal with five-layered modulated martensite crystal structure. Very low twinning stress of about 0.1 MPa was found for twin boundaries which deviated a few degrees from the (011) crystallographic plane. However, twin boundaries oriented exactly parallel to the (011) plane exhibited considerably higher level of twinning stress, above 1 MPa. X-ray diffraction experiments and calculations based on approximation of the martensite crystal lattice as a tetragonal lattice with a slight monoclinic distortion identified the two different kinds of twin interfaces as type II and type I twin boundaries.

  1. High temperature dielectric relaxation anomaly of Y? and Mn? doped barium strontium titanate ceramics

    SciTech Connect (OSTI)

    Yan, Shiguang; Mao, Chaoliang E-mail: xldong@mail.sic.ac.cn; Wang, Genshui; Yao, Chunhua; Cao, Fei; Dong, Xianlin E-mail: xldong@mail.sic.ac.cn

    2014-10-14

    Relaxation like dielectric anomaly is observed in Y? and Mn? doped barium strontium titanate ceramics when the temperature is over 450 K. Apart from the conventional dielectric relaxation analysis method with Debye or modified Debye equations, which is hard to give exact temperature dependence of the relaxation process, dielectric response in the form of complex impedance, assisted with Cole-Cole impedance model corrected equivalent circuits, is adopted to solve this problem and chase the polarization mechanism in this paper. Through this method, an excellent description to temperature dependence of the dielectric relaxation anomaly and its dominated factors are achieved. Further analysis reveals that the exponential decay of the Cole distribution parameter n with temperature is confirmed to be induced by the microscopic lattice distortion due to ions doping and the interaction between the defects. At last, a clear sight to polarization mechanism containing both the intrinsic dipolar polarization and extrinsic distributed oxygen vacancies hopping response under different temperature is obtained.

  2. Unraveling the voltage fade mechanism in layer Li-Mn-rich electrode: formation of the tetrahedral cations for spinel conversion

    SciTech Connect (OSTI)

    Mohanty, Debasish; Li, Jianlin; Abraham, Daniel P; Huq, Ashfia; Payzant, E Andrew; Wood III, David L; Daniel, Claus

    2014-01-01

    Discovery of high-voltage layered lithium-and manganese-rich (LMR) composite oxide electrode has dramatically enhanced the energy density of current Li-ion energy storage systems. However, practical usage of these materials is currently not viable because of their inability to maintain a consistent voltage profile (voltage fading) during subsequent charge-discharge cycles. This report rationalizes the cause of this voltage fade by providing the evidence of layer to spinel-like (LSL) structural evolution pathways in the host Li1.2Mn0.55Ni0.15Co0.1O2 LMR composite oxide. By employing neutron powder diffraction, and temperature dependent magnetic susceptibility, we show that LSL structural rearrangement in LMR oxide occurs through a tetrahedral cation intermediate via: i) diffusion of lithium atoms from octahedral to tetrahedral sites of the lithium layer [(LiLioct LiLitet] which is followed by the dispersal of the lithium ions from the adjacent octahedral site of the metal layer to the tetrahedral sites of lithium layer [LiTM oct LiLitet]; and ii) migration of Mn from the octahedral sites of the transition metal layer to the permanent octahedral site of lithium layer via tetrahedral site of lithium layer [MnTMoct MnLitet MnLioct)]. The findings opens the door to the potential routes to mitigate this atomic restructuring in the high-voltage LMR composite oxide cathodes by manipulating the composition/structure for practical use in high-energy-density lithium-ion batteries.

  3. Synthesis and characterization of R{sub 2}MnTiO{sub 7} (R = Y and Er) pyrochlores oxides

    SciTech Connect (OSTI)

    Martnez-Coronado, R.; Alonso, J.A.; Fernndez, M.T.

    2013-09-01

    Graphical abstract: - Abstract: New pyrochlore-like phases of composition R{sub 2}MnTiO{sub 7} (R = Er and Y) have been synthesized by a soft-chemistry procedure involving citrates of the different metal ions followed by thermal treatments at moderate temperatures (850 C for 12 h in air). A characterization by X-ray diffraction and neutron powder diffraction (NPD) has been carried out in order to determine the crystal structure features: these phyrochlores are cubic, space group Fd-3m, defining an intrinsically frustrated three-dimensional system. The Rietveld-refinement from NPD data at room temperature evidences an antisite cation disorder (distribution of Mn between A and B positions) that is accompanied by an increment of the oxygen-vacancy concentration due to the reduction of Mn{sup 4+} at the B position to Mn{sup 2+} at the A position. Thermogravimetric analysis (TGA) was useful to evaluate the stability of these oxides in reducing conditions up to 500 C. Magnetic susceptibility measurements indicate a ferromagnetic behavior, due to the random distribution of Mn{sup 4+} ions in the octahedral sublattice. At lower temperatures there is a polarization of the R{sup +3} magnetic moments, which also participate in the magnetic structure. Aiming to evaluate these materials as possible electrodes for solid oxide fuel cells (SOFC) we determined that the thermal expansion coefficients between 100 and 900 C perfectly match with those of the usual electrolytes; however, these pyrochlore oxides display a semiconductor-like behavior with poor conductivity values, e.g. 6 10{sup ?3} cm{sup ?1} at 850 C for Er, which would prevent its use as MIEC (mixed ionic-electronic conductors) oxides in SOFC devices.

  4. F-1 U.S. Energy Information Administration | Annual Energy Outlook...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Central West North Central East North Central Mountain AK WA MT WY ID NV UT CO AZ NM TX OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT VT ME RI MA NH VA WI MI OH...

  5. F-5 U.S. Energy Information Administration | Annual Energy Outlook...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Figure F4. Oil and Gas Supply Model Regions Atlantic WA MT WY ID NV UT CO AZ NM TX OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT ME RI MA NH VA WI MI OH NE...

  6. The role of the (111) texture on the exchange bias and interlayer coupling effects observed in sputtered NiFe/IrMn/Co trilayers

    SciTech Connect (OSTI)

    Castro, I. L.; Nascimento, V. P.; Passamani, E. C.; Takeuchi, A. Y.; Larica, C.; Tafur, M.; Pelegrini, F.

    2013-05-28

    Magnetic properties of sputtered NiFe/IrMn/Co trilayers grown on different seed layers (Cu or Ta) deposited on Si (100) substrates were investigated by magnetometry and ferromagnetic resonance measurements. Exchange bias effect and magnetic spring behavior have been studied by changing the IrMn thickness. As shown by X-ray diffraction, Ta and Cu seed layers provoke different degrees of (111) fcc-texture that directly affect the exchange bias and indirectly modify the exchange spring coupling behavior. Increasing the IrMn thickness, it was observed that the coupling angle between the Co and NiFe ferromagnetic layers increases for the Cu seed system, but it reduces for the Ta case. The results were explained considering (i) different anisotropies of the Co and IrMn layers induced by the different degree of the (111) texture and (ii) the distinct exchange bias set at the NiFe/IrMn and IrMn/Co interfaces in both systems. The NiFe and Co interlayer coupling angle is strongly correlated with both exchange bias and exchange magnetic spring phenomena. It was also shown that the highest exchange bias field occurs when an unstressed L1{sub 2} IrMn structure is stabilized.

  7. First principles treatment of structural, optical, and thermoelectric properties of Li{sub 7}MnN{sub 4} as electrode for a Li secondary battery

    SciTech Connect (OSTI)

    Khan, Wilayat; Reshak, A.H.

    2015-01-15

    The electronic structure, electronic charge density and linear optical properties of the metallic Li{sub 7}MnN{sub 4} compound, having cubic symmetry, are calculated using the full potential linearized augmented plane wave (FP-LAPW) method. The calculated band structure and density of states using the local density, generalized gradient and EngelVosko approximations, depict the metallic nature of the cubic Li{sub 7}MnN{sub 4} compound. The bands crossing the Fermi level in the calculated band structure are mainly from the Mn-d states with small support of N-p states. In addition, the Mn-d states at the Fermi level enhance the density of states, which is very useful for the electronic transport properties. The valence electronic charge density depicts strong covalent bond between Mn and two N atoms and polar covalent bond between Mn and Li atoms. The frequency dependent linear optical properties like real and imaginary part of the dielectric function, optical conductivity, reflectivity and energy loss function are calculated on the basis of the computed band structure. Both intra-band and inter-band transitions contribute to the calculated optical parameters. Using the BoltzTraP code, the thermoelectric properties like electrical and thermal conductivity, Seebeck coefficient, power coefficient and heat capacity of the Li{sub 7}MnN{sub 4} are also calculated as a function of temperature and studied.

  8. Electrical conductivity anomaly and X-ray photoelectron spectroscopy investigation of YCr{sub 1?x}Mn{sub x}O{sub 3} negative temperature coefficient ceramics

    SciTech Connect (OSTI)

    Zhang, Bo; University of Chinese Academy of Sciences, Beijing 100049 ; Zhao, Qing; Chang, Aimin E-mail: wuy@alfred.edu; Li, Yiyu; Liu, Yin; Wu, Yiquan E-mail: wuy@alfred.edu

    2014-03-10

    Electrical conductivity anomaly of perovskite-type YCr{sub 1?x}Mn{sub x}O{sub 3} negative temperature coefficient (NTC) ceramics produced by spark plasma sintering (SPS) has been investigated by using defect chemistry theory combination with X-ray photoelectron spectroscopy (XPS) analysis. From the results of the ln?-1/T curves and the XPS analysis, it can be considered that YCr{sub 1?x}Mn{sub x}O{sub 3} ceramics exhibit the hopping conductivity. The major carriers in YCrO{sub 3} are holes, which are compensated by the oxygen vacancies produced due to the introduction of Mn ions. The Mn{sup 4+} ion contents increase monotonically in the range of 0.2???x???0.5. The resistivity increases at first and then decreases with increasing Mn contents, which has the same varying tendency with activation energy. The electrical conductivity anomaly appearing in these ceramics may be due to the variation of Cr{sup 4+} and Mn{sup 4+} ions concentration as Mn content changes.

  9. Effect of CoFe insertion in Co{sub 2}MnSi/CoFe/n-GaAs junctions on spin injection properties

    SciTech Connect (OSTI)

    Ebina, Yuya; Akiho, Takafumi; Liu, Hong-xi; Yamamoto, Masafumi; Uemura, Tetsuya

    2014-04-28

    The CoFe thickness (t{sub CoFe}) dependence of spin injection efficiency was investigated for Co{sub 2}MnSi/CoFe/n-GaAs junctions. The ?V{sub NL}/I value, which is a measure of spin injection efficiency, strongly depended on t{sub CoFe}, where ?V{sub NL} is the amplitude of a nonlocal spin-valve signal, and I is an injection current. Importantly, the maximum value of ?V{sub NL}/I for a Co{sub 2}MnSi/CoFe/n-GaAs junction was one order of magnitude higher than that for a CoFe/n-GaAs junction, indicating that a Co{sub 2}MnSi electrode works as a highly polarized spin source. No clear spin signal, on the other hand, was observed for a Co{sub 2}MnSi/n-GaAs junction due to diffusion of Mn atoms into the GaAs channel. Secondary ion mass spectrometry analysis indicated that the CoFe insertion effectively suppressed the diffusion of Mn into GaAs, resulting in improved spin injection properties compared with those for a Co{sub 2}MnSi/n-GaAs junction.

  10. The effect of Ca-substitution in La-site on the magnetic properties of La{sub 2}CoMnO{sub 6}

    SciTech Connect (OSTI)

    Li, Qiu-hang; Li, Na; Hu, Jian-zhong; Han, Qi; Ma, Qing-shan; Ge, Lei; Xiao, Biao; Xu, Ming-xiang

    2014-07-21

    Double perovskite La{sub 2-x}Ca{sub x}CoMnO{sub 6} (x?=?0, 0.1, 0.2, 0.5) ceramics samples were synthesized by the standard solid-state reaction method. The crystal structures have been confirmed to be monoclinic perovskite structure with space group of P2{sub 1}/n at room temperature by the powder x-ray diffraction (Cu-K?). The grains of the samples are relatively dense and distribute in random directions from the scanning electron microscope patterns. Holes are doped into La{sub 2}CoMnO{sub 6} with the substitution of the Ca{sup 2+} ions in La-site, and further lead to the valences of Mn ions and Co ions transforming from Mn{sup 4+} and Co{sup 2+} to Mn{sup 3+} and Co{sup 3+}, respectively. Ferromagnetic coupling of Mn{sup 4+}-O{sup 2}-Co{sup 2+} and antiferromagnetic coupling of Mn{sup 3+}-O{sup 2}-Co{sup 3+} are coexistent in La{sub 2-x}Ca{sub x}CoMnO{sub 6} system, which correspond to two transitions existed in field-cooling magnetization versus temperature curves. Curie temperature of La{sub 2-x}Ca{sub x}CoMnO{sub 6} system decreases with the increasing of Ca-substitution amount. The coexistence of different magnetic phases leads to the exchange bias effect.

  11. Effect of L1{sub 2} ordering in antiferromagnetic Ir-Mn epitaxial layer on exchange bias of FePd films

    SciTech Connect (OSTI)

    Chang, Y. C.; Duh, J. G. E-mail: lin.yg@nsrrc.org.tw; Hsiao, S. N. E-mail: lin.yg@nsrrc.org.tw; Liu, S. H.; Su, S. H.; Chiu, K. F.; Hsieh, W. C.; Chen, S. K.; Lin, Y. G. E-mail: lin.yg@nsrrc.org.tw; Lee, H. Y.; Sung, C. K.

    2015-05-07

    Two series of samples of single-layer IrMn and IrMn/FePd bilayer films, deposited on a single-crystal MgO substrate at different IrMn deposition temperatures (T{sub s} = 300–700 °C), were investigated using magnetron sputtering. L1{sub 2} ordering was revealed for the 30 nm-thick IrMn epitaxial (001) films with T{sub s} ≥ 400 °C, determined by synchrotron radiation x-ray diffractometry (XRD). XRD results also provide evidence of the epitaxial growth of the IrMn films on MgO substrate. Increasing T{sub s} from 400 to 700 °C monotonically increases the ordering parameter of L1{sub 2} phases from 0.17 to 0.81. An in-plane exchange bias field (H{sub eb}) of 22 Oe is obtained in a 10 nm-thick FePd film that is deposited on the disordered IrMn films. As the L1{sub 2} ordering of the IrMn layers increases, the H{sub eb} gradually decreases to 0 Oe, meaning that the exchange bias behavior vanishes. The increased surface roughness, revealed by atomic force microscopy, of the epitaxial IrMn layers with increasing T{sub s} cannot be the main cause of the decrease in H{sub eb} due to the compensated surface spins regardless of the disordered and ordered (001) IrMn layers. The change of antiferromagnetic structure from the A1 to the L1{sub 2} phase was correlated with the evolution of H{sub eb}.

  12. Synthesis of murdochite-type Ni{sub 6}MnO{sub 8} with variable specific surface areas and the application in methane oxidation

    SciTech Connect (OSTI)

    Taguchi, Hideki; Tahara, Shohei; Okumura, Mikoto; Hirota, Ken

    2014-07-01

    To synthesize a murdochite-type Ni{sub 6}MnO{sub 8} with variable specific surface areas, an oxalate precursor was calcined at 350500 C in flowing argon, and the calcined sample was heated to 600 C in air. The lattice constant of the Ni{sub 6}MnO{sub 8} did not depend on the calcination temperature of the precursor, while the specific surface area decreased from 8.4 m{sup 2}/g to 2.6 m{sup 2}/g when increasing the calcination temperature of the precursor. The methane (CH{sub 4}) oxidation data indicated that the temperature corresponding to the 50% conversion (T{sub 50%}) of Ni{sub 6}MnO{sub 8} calcined at 350 C or 400 C was lower than that of all other Ni{sub 6}MnO{sub 8} specimens. However, the intrinsic conversion of Ni{sub 6}MnO{sub 8} calcined at 350 C, which is defined as conversion per specific surface area, was half of that of all other Ni{sub 6}MnO{sub 8} specimens. The degree of crystallinity and catalytic performance of the Ni{sub 6}MnO{sub 8} calcined at 400 C were high. - Graphical abstract: The conversion of CH{sub 4} into CO{sub 2} and H{sub 2}O on Ni{sub 6}MnO{sub 8}, which was heated at 600 C in air after the calcination of the precursor at 350 C, 400 C, 450 C, or 500 C in flowing argon, was measured. Since the specific surface area was strongly affected by the calcination temperature of the precursor, intrinsic conversion (IC) was defined as conversion per the specific surface area. For comparison, the IC value on Ni{sub 6}MnO{sub 8} synthesized by the direct calcination of the precursor at 600 C in air is plotted. - Highlights: The oxalate precursor was calcined at 350500 C in flowing argon. Murdochite-type Ni{sub 6}MnO{sub 8} was obtained by heating the calcined sample in air. The specific surface area of Ni{sub 6}MnO{sub 8} varied with the calcination temperature. The degree of crystallinity and catalysis of Ni{sub 6}MnO{sub 8} calcined at 400 C were high.

  13. Strong room-temperature ferromagnetism of high-quality lightly Mn-doped ZnO grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Zuo Zheng; Zhou Huimei; Olmedo, Mario J.; Kong Jieying; Liu Jianlin; Beyermann, Ward P.; Zheng Jianguo; Xin Yan

    2012-09-01

    Strong room-temperature ferromagnetism is demonstrated in single crystalline Mn-doped ZnO grown by molecular beam epitaxy. With a low Mn concentration of 2 Multiplication-Sign 10{sup 19} cm{sup -3}, Mn-doped ZnO films exhibited room-temperature ferromagnetism with a coercivity field larger than 200 Oe, a large saturation moment of 6 {mu}{sub B}/ion, and a large residue moment that is {approx}70% of the saturation magnetization. Isolated ions with long range carrier mediated spin-spin coupling may be responsible for the intrinsic ferromagnetism.

  14. Magneto-transport in LaTi{sub 1−x}Mn{sub x}O{sub 3}/SrTiO{sub 3} oxide heterostructures

    SciTech Connect (OSTI)

    Kumar, Pramod Dogra, Anjana Budhani, R. C.

    2014-04-24

    We report the growth of ultrathin film of Mn doped LaTiO{sub 3} on TiO{sub 2} terminated SrTiO{sub 3} (001) substrate by pulsed laser deposition (PLD) and their electrical transport characteristics including magnetoresistance (MR). Though the replacement of Mn in LaTiO{sub 3} at the Ti site in dilute limit does not affect the metallic behaviour of films but variation in resistance is observed. Normalised resistance behaviour is explained on the basis of variation in charge carriers and increased interaction between Mn atoms in the system under investigation.

  15. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    SciTech Connect (OSTI)

    Jamer, M.; Sterbinsky, G.; Assaf, B.; Arena, D.; Heiman, D.

    2014-12-05

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

  16. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    SciTech Connect (OSTI)

    Jamer, M. E.; Assaf, B. A.; Sterbinsky, G. E.; Arena, D. A.; Heiman, D.

    2014-12-05

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. Results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value.

  17. Magnetic Transitions in the Spin-5/2 Frustrated Magnet BiMn2PO6 and Strong Lattice Softening in BiMn2PO6 and BiZn2PO6 Below 200 K

    SciTech Connect (OSTI)

    Nath, R; Ranjith, K M; Roy, B; Johnston, D C; Furukawa, Y; Tsirlin, A A

    2014-07-01

    The crystallographic, magnetic, and thermal properties of polycrystalline BiMn2PO6 and its nonmagnetic analog BiZn2PO6 are investigated by x-ray diffraction, magnetization M, magnetic susceptibility ?, heat capacity Cp, and P31 nuclear magnetic resonance (NMR) measurements versus applied magnetic field H and temperature T as well as by density-functional band theory and molecular-field calculations. Both compounds show a strong monotonic lattice softening on cooling, where the Debye temperature decreases by a factor of two from ?D?650 K at T=300 K to ?D?300 K at T=2 K. The ?(T) data for BiMn2PO6 above 150 K follow a Curie-Weiss law with a Curie constant consistent with a Mn+2 spin S=5/2 with g factor g=2 and an antiferromagnetic (AFM) Weiss temperature ?CW??78 K. The ? data indicate long-range AFM ordering below TN?30 K, confirmed by a sharp ?-shaped peak in Cp(T) at 28.8 K. The magnetic entropy at 100 K extracted from the Cp(T) data is consistent with spin S=5/2 for the Mn+2 cations. The band-theory calculations indicate that BiMn2PO6 is an AFM compound with dominant interactions J1/kB?6.7 K and J3/kB?5.6 K along the legs and rungs of a Mn two-leg spin-ladder, respectively. However, sizable and partially frustrating interladder couplings lead to an anisotropic three-dimensional magnetic behavior with long-range AFM ordering at TN?30 K observed in the ?, Cp, and NMR measurements. A second magnetic transition at ?10 K is observed from the ? and NMR measurements but is not evident in the Cp data. The Cp data at low T suggest a significant contribution from AFM spin waves moving in three dimensions and the absence of a spin-wave gap. A detailed analysis of the NMR spectra indicates commensurate magnetic order between 10 and 30 K, while below 10 K additional features appear that may arise from an incommensurate modulation and/or spin canting. The commensurate order is consistent with microscopic density functional calculations that yield a collinear Nel-type AFM spin arrangement both within and between the ladders, despite the presence of multiple weak interactions frustrating this magnetic structure of the Mn spins. Frustration for AFM ordering and the one-dimensional spatial anisotropy of the three-dimensional spin interactions are manifested in the frustration ratio f=|?CW|/TN?2.6, indicating a suppression of TN from 68 K in the absence of these effects to the observed value of about 30 K in BiMn2PO6.

  18. Enhance D. C. resistivity of Ba{sub 0.7}Sr{sub 0.3}TiO{sub 3} ceramic by acceptor (Mn) doping

    SciTech Connect (OSTI)

    Sharma, Hakikat Arya, G. S.; Pramar, Kusum; Negi, N. S.

    2015-05-15

    In the present work, we prepared Ba{sub 0.7}Sr{sub 0.3}TiO{sub 3} and Mn (2 and 3 at % on Ti site) doped Ba{sub 0.7}Sr{sub 0.3}TiO{sub 3} ceramic by sol- gel method. The samples were characterized by X-ray diffraction (XRD). The XRD patterns reveled that Mn ions did not change the perovskite structure of BST (70/30). The dielectric measurements proved that dielectric constant decreased with Mn doping. The dc resistivity was studied by using I-V measurements. The dc resistivity of the BST increased with Mn doping, which suppressed the leakage current.

  19. Properties of molecular beam epitaxy grown Eu{sub x}(transition metal){sub y} films (transition metals: Mn, Cr)

    SciTech Connect (OSTI)

    Balin, K.; Nowak, A.; Gibaud, A.; Szade, J.; Celinski, Z.

    2011-04-01

    The electronic and crystallographic structures, as well as the magnetic properties, of Eu{sub x}(transition metal){sub y} (transition metals: Mn, Cr) thin films grown by molecular beam epitaxy were studied. Relative changes of the Eu/Mn and Eu/Cr ratios derived from the XPS lines, as well as x-ray reflectivity, indicate mixing of the Eu/Mn and Eu/Cr layers. Valency transitions from Eu{sup 2+} to Eu{sup 3+} were observed in both systems for most studied stoichiometries. A transition to a magnetically ordered phase was observed at 15 K, 40 K, and 62 K for selected films in the Eu-Mn system, and at 50 K for the film with a Eu/Cr ratio of 0.5.

  20. Bicolor Mn-doped CuInS{sub 2}/ZnS core/shell nanocrystals for white light-emitting diode with high color rendering index

    SciTech Connect (OSTI)

    Huang, Bo; Dai, Qian; Zhang, Huichao; Liao, Chen; Cui, Yiping; Zhang, Jiayu; Zhuo, Ningze; Jiang, Qingsong; Shi, Fenghua; Wang, Haibo

    2014-09-07

    We synthesized bicolor Mn-doped CuInS{sub 2} (CIS)/ZnS core/shell nanocrystals (NCs), in which Mn{sup 2+} ions and the CIS core were separated with a ZnS layer, and both Mn{sup 2+} ions and CIS cores could emit simultaneously. Transmission electron microscopy and powder X-ray diffraction measurements indicated the epitaxial growth of ZnS shell on the CuInS{sub 2} core, and electron paramagnetic resonance spectrum indicated that Mn{sup 2+} ions were on the lattice points of ZnS shell. By integrating these bicolor NCs with commercial InGaN-based blue-emitting diodes, tricolor white light-emitting diodes with color rendering index of 83 were obtained.

  1. U.S. Natural Gas Exports to Canada

    Gasoline and Diesel Fuel Update (EIA)

    Total To Brazil Freeport, TX Sabine Pass, LA Total to Canada Eastport, ID Calais, ME Detroit, MI Marysville, MI Port Huron, MI Crosby, ND Portal, ND Sault St. Marie, MI St. Clair, MI Noyes, MN Warroad, MN Babb, MT Havre, MT Port of Morgan, MT Sherwood, ND Pittsburg, NH Buffalo, NY Grand Island, NY Massena, NY Niagara Falls, NY Waddington, NY Sumas, WA Sweetgrass, MT Total to Chile Sabine Pass, LA Total to China Kenai, AK Sabine Pass, LA Total to Egypt Freeport, TX Total to India Freeport, TX

  2. U.S. Natural Gas Exports to Mexico

    Gasoline and Diesel Fuel Update (EIA)

    Total To Brazil Freeport, TX Sabine Pass, LA Total to Canada Eastport, ID Calais, ME Detroit, MI Marysville, MI Port Huron, MI Crosby, ND Portal, ND Sault St. Marie, MI St. Clair, MI Noyes, MN Warroad, MN Babb, MT Havre, MT Port of Morgan, MT Sherwood, ND Pittsburg, NH Buffalo, NY Grand Island, NY Massena, NY Niagara Falls, NY Waddington, NY Sumas, WA Sweetgrass, MT Total to Chile Sabine Pass, LA Total to China Kenai, AK Sabine Pass, LA Total to Egypt Freeport, TX Total to India Freeport, TX

  3. Magneto-transport properties of oriented Mn{sub 2}CoAl films sputtered on thermally oxidized Si substrates

    SciTech Connect (OSTI)

    Xu, G. Z.; Du, Y.; Zhang, X. M.; Liu, E. K.; Wang, W. H. Wu, G. H.; Zhang, H. G.

    2014-06-16

    Spin gapless semiconductors are interesting family of materials by embracing both magnetism and semiconducting due to their unique band structure. Its potential application in future spintronics requires realization in thin film form. In this Letter, we report fabrication and transport properties of spin gapless Mn{sub 2}CoAl films prepared on thermally oxidized Si substrates by magnetron sputtering deposition. The films deposited at 673 K are well oriented to (001) direction and display a uniform-crystalline surface. Magnetotransport measurements on the oriented films reveal a semiconducting-like resistivity, small anomalous Hall conductivity, and linear magnetoresistance representative of the transport signatures of spin gapless semiconductors. The magnetic properties of the films have also been investigated and compared to that of bulk Mn{sub 2}CoAl, showing small discrepancy induced by the composition deviation.

  4. Metallic transport and large anomalous Hall effect at room temperature in ferrimagnetic Mn{sub 4}N epitaxial thin film

    SciTech Connect (OSTI)

    Shen, Xi; Shigematsu, Kei; Chikamatsu, Akira Fukumura, Tomoteru; Hirose, Yasushi; Hasegawa, Tetsuya

    2014-08-18

    We report the electrical transport properties of ferrimagnetic Mn{sub 4}N (001) epitaxial thin films grown by pulsed laser deposition on MgO (001) substrates. The Mn{sub 4}N thin films were tetragonally distorted with a ratio of out-of-plane to in-plane lattice constants of 0.987 and showed perpendicular magnetic anisotropy with an effective magnetic anisotropy constant of 0.16?MJ/m{sup 3}, which is comparable with that of a recently reported molecular-beam-epitaxy-grown film. The thin films exhibited metallic transport with a room temperature resistivity of 125??? cm in addition to a large anomalous Hall effect with a Hall angle tangent of 0.023.

  5. The effects of high magnetic field on the morphology and microwave electromagnetic properties of MnO{sub 2} powder

    SciTech Connect (OSTI)

    Jia Zhang [Department of Materials Processing Engineering, School of Materials Science and Engineering, Dalian University of Technology, Linggong Road 2, Ganjingzi District, Dalian 116085, Liaoning Province (China); Duan Yuping, E-mail: duanyp@dlut.edu.c [Department of Materials Processing Engineering, School of Materials Science and Engineering, Dalian University of Technology, Linggong Road 2, Ganjingzi District, Dalian 116085, Liaoning Province (China); Li Shuqing, E-mail: lsq6668@126.co [Beijing Aeronautical Manufacturing Technology Research Institute, 1 Jun Zhuang east Road, Chaoyang District, Beijing 100024 (China); Li Xiaogang, E-mail: lixiaogang99@263.ne [School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing 100083 (China); Liu Shunhua [Department of Materials Processing Engineering, School of Materials Science and Engineering, Dalian University of Technology, Linggong Road 2, Ganjingzi District, Dalian 116085, Liaoning Province (China)

    2010-07-15

    MnO{sub 2} with a sea urchin-like ball chain shape was first synthesized in a high magnetic field via a simple chemical process, and a mechanism for the formation of this grain shape was discussed. The as-synthesized samples were characterized by XRD, SEM, TEM, and vector network analysis. The dielectric constant and the loss tangent clearly decreased under a magnetic field. The magnetic loss tangent and the imaginary part of the magnetic permeability increased substantially. Furthermore, the theoretically calculated values of reflection loss showed that the absorption peaks shifted to a higher frequency with increases in the magnetic field strength. - Graphical abstract: MnO{sub 2} with a sea urchin-like ball chain shape is first synthesized in a high magnetic field via a simple hydrothermal route.

  6. Enhanced magnetic hysteresis in Ni-Mn-Ga single crystal and its influence on magnetic shape memory effect

    SciTech Connect (OSTI)

    Heczko, O. Drahokoupil, J.; Straka, L.

    2015-05-07

    Enhanced magnetic hysteresis due to boron doping in combination with magnetic shape memory effect in Ni-Mn-Ga single crystal results in new interesting functionality of magnetic shape memory (MSM) alloys such as mechanical demagnetization. In Ni{sub 50.0}Mn{sub 28.5}Ga{sub 21.5} single crystal, the boron doping increased magnetic coercivity from few Oe to 270?Oe while not affecting the transformation behavior and 10?M martensite structure. However, the magnetic field needed for MSM effect also increased in doped sample. The magnetic behavior is compared to undoped single crystal of similar composition. The evidence from the X-ray diffraction, magnetic domain structure, magnetization loops, and temperature evolution of the magnetic coercivity points out that the enhanced hysteresis is caused by stress-induced anisotropy.

  7. Extended investigation of intermartensitic transitions in Ni-Mn-Ga magnetic shape memory alloys: A detailed phase diagram determination

    SciTech Connect (OSTI)

    akir, Asli; Aktrk, Seluk; Righi, Lara

    2013-11-14

    Martensitic transitions in shape memory Ni-Mn-Ga Heusler alloys take place between a high temperature austenite and a low temperature martensite phase. However, intermartensitic transformations have also been encountered that occur from one martensite phase to another. To examine intermartensitic transitions in magnetic shape memory alloys in detail, we carried out temperature dependent magnetization, resistivity, and x-ray diffraction measurements to investigate the intermartensitic transition in Ni{sub 50}Mn{sub 50x}Ga{sub x} in the composition range 12?x?25 at. %. Rietveld refined x-ray diffraction results are found to be consistent with magnetization and resistivity data. Depending on composition, we observe that intermartensitic transitions occur in the sequences 7M?L1{sub 0},?5M?7M, and 5M?7M?L1{sub 0} with decreasing temperature. The L1{sub 0} non-modulated structure is most stable at low temperature.

  8. Epitaxial Mn{sub 2.5}Ga thin films with giant perpendicular magnetic anisotropy for spintronic devices

    SciTech Connect (OSTI)

    Wu Feng; Mizukami, Shigemi; Watanabe, Daisuke; Miyazaki, Terunobu; Naganuma, Hiroshi; Oogane, Mikihiko; Ando, Yasuo

    2009-03-23

    We report on epitaxial growth and magnetic properties of Mn{sub 2.5}Ga thin films, which were deposited on Cr/MgO single crystal substrates by magnetron sputtering. X-ray diffraction results revealed the epitaxial relationships as Mn{sub 2.5}Ga(001)[100] parallel Cr(001)[110] parallel MgO(001)[100]. The presence of (002) and (011) superlattice peaks indicates that the films were crystallized into DO{sub 22} ordered structures. The perpendicular magnetic anisotropy (PMA) properties were found to be related to the extent of DO{sub 22} chemical ordering. A giant PMA (K{sub u}{sup eff}=1.2x10{sup 7} erg/cm{sup 3}) and low saturation magnetization (M{sub s}=250 emu/cm{sup 3}) can be obtained for the film with highest chemical ordering parameter (S=0.8)

  9. Conditions for spin-gapless semiconducting behavior in Mn{sub 2}CoAl inverse Heusler compound

    SciTech Connect (OSTI)

    Galanakis, I.; zdo?an, K.; ?a??o?lu, E.; Blgel, S.

    2014-03-07

    Employing ab initio electronic structure calculations, we investigate the conditions for spin-gapless semiconducting (SGS) behavior in the inverse Mn{sub 2}CoAl Heusler compound. We show that tetragonalization of the lattice, which can occur during films growth, keeps the SGS character of the perfect cubic compound. On the contrary, atomic swaps even between sites with different local symmetry destroy the SGS character giving rise to a half-metallic state. Furthermore, the occurrence of Co-surplus leads also to half-metallicity. Thus, we propose that in order to achieve SGS behavior during the growth of Mn{sub 2}CoAl (and similar SGS Heusler compounds) thin films, one should minimize the occurrence of defects, while small deformations of the lattice, due to the lattice mismatch with the substrate, do not play a crucial role.

  10. Temperature-induced martensite in magnetic shape memory Fe{sub 2}MnGa observed by photoemission electron microscopy

    SciTech Connect (OSTI)

    Jenkins, Catherine; Scholl, Andreas; Kainuma, R.; Elmers, Hans-Joachim; Omori, Toshihiro

    2012-01-18

    The magnetic domain structure in single crystals of a Heusler shape memory compound near the composition Fe{sub 2}MnGa was observed during phase transition by photoelectron emission microscopy at Beamline 11.0.1.1 of the Advanced Light Source. The behavior is comparable with recent observations of an adaptive martensite phase in prototype Ni{sub 2}MnGa, although the pinning in the recent work is an epitaxial interface and in this work the e#11;ective pinning plane is a boundary between martensitic variants that transform in a self-accommodating way from the single crystal austenite phase present at high temperatures. Temperature dependent observations of the twinning structure give information as to the coupling behavior between the magnetism and the structural evolution.

  11. Structural, morphological, and magnetic characterization of In{sub 1-x}Mn{sub x}As quantum dots grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Ferri, F. A.; Marega, E. Jr.; Coelho, L. N.; Kunets, V. P.; Salamo, G. J.

    2012-08-01

    In this paper, we present a method to order low temperature (LT) self-assembled ferromagnetic In{sub 1-x}Mn{sub x}As quantum dots (QDs) grown by molecular beam epitaxy (MBE). The ordered In{sub 1-x}Mn{sub x}As QDs were grown on top of a non-magnetic In{sub 0.4}Ga{sub 0.6}As/GaAs(100) QDs multi-layered structure. The modulation of the chemical potential, due to the stacking, provides a nucleation center for the LT In{sub 1-x}Mn{sub x}As QDs. For particular conditions, such as surface morphology and growth conditions, the In{sub 1-x}Mn{sub x}As QDs align along lines like chains. This work also reports the characterization of QDs grown on plain GaAs(100) substrates, as well as of the ordered structures, as function of Mn content and growth temperature. The substitutional Mn incorporation in the InAs lattice and the conditions for obtaining coherent and incoherent structures are discussed from comparison between Raman spectroscopy and x-ray analysis. Ferromagnetic behavior was observed for all structures at 2 K. We found that the magnetic moment axis changes from [110] in In{sub 1-x}Mn{sub x}As over GaAs to [1-10] for the ordered In{sub 1-x}Mn{sub x}As grown over GaAs template.

  12. Magnetism in La₂O₃(Fe₁₋xMnx)₂Se₂ tuned by Fe/Mn ratio

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lei, Hechang; Bozin, Emil S.; Llobet, A.; Ivanovski, V.; Koteski, V.; Belosevic-Cavor, J.; Cekic, B.; Petrovic, C.

    2012-09-17

    We report the evolution of structural and magnetic properties in La₂O₃(Fe₁₋xMnx)₂Se₂. Heat capacity and bulk magnetization indicate an increased ferromagnetic component of the long-range magnetic order and possible increased degree of frustration. Atomic disorder on Fe(Mn) sites suppresses the temperature of the long-range order whereas intermediate alloys show a rich magnetic phase diagram.

  13. Determination of elastic properties of a MnO{sub 2} coating by surface acoustic wave velocity dispersion analysis

    SciTech Connect (OSTI)

    Sermeus, J.; Glorieux, C.; Sinha, R.; Vereecken, P. M.; Vanstreels, K.

    2014-07-14

    MnO{sub 2} is a material of interest in the development of high energy-density batteries, specifically as a coating material for internal 3D structures, thus ensuring rapid energy deployment. Its electrochemical properties have been mapped extensively, but there are, to the best of the authors' knowledge, no records of the elastic properties of thin film MnO{sub 2}. Impulsive stimulated thermal scattering (ISTS), also known as the heterodyne diffraction or transient grating technique, was used to determine the Young's modulus (E) and porosity (?) of a 500?nm thick MnO{sub 2} coating on a Si(001) substrate. ISTS is an all optical method that is able to excite and detect surface acoustic waves (SAWs) on opaque samples. From the measured SAW velocity dispersion, the Young's modulus and porosity were determined to be E?=?25??1?GPa and ?=421%, respectively. These values were confirmed by independent techniques and determined by a most-squares analysis of the carefully fitted SAW velocity dispersion. This study demonstrates the ability of the presented technique to determine the elastic parameters of a thin, porous film on an anisotropic substrate.

  14. Correlating Local Structure with Electrochemical Activity in Li2MnO3

    SciTech Connect (OSTI)

    Nanda, Jagjit; Sacci, Robert L.; Veith, Gabriel M.; Dixit, Hemant M.; Cooper, Valentino R.; Pezeshki, Alan M.; Ruther, Rose E.

    2015-07-31

    Li2MnO3 is of interest as one component of the composite lithium-rich oxides, which are under development for high capacity, high voltage cathodes in lithium ion batteries. Despite such practical importance, the mechanism of electrochemical activity in Li2MnO3 is contested in the literature, as are the effects of long-term electrochemical cycling. Here, Raman spectroscopy and mapping are used to follow the chemical and structural changes that occur in Li2MnO3. Both conventional slurry electrodes and thin films are studied as a function of the state of charge (voltage) and cycle number. Thin films have similar electrochemical properties as electrodes prepared from slurries, but allow for spectroscopic investigations on uniform samples without carbon additives. Spectral changes correlate well with electrochemical activity and support a mechanism whereby capacity is lost upon extended cycling due to the formation of new manganese oxide phases. Raman mapping of both thin film and slurry electrodes charged to different voltages reveals significant variation in the local structure. Poor conductivity and slow kinetics associated with a two-phase reaction mechanism contribute to the heterogeneity.

  15. Magnetoelectric coupling tuned by competing single iron anisotropies in Mn1-xNixTiO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chi, Songxue; Ye, Feng; Zhou, Haidong D.; Choi, E. S.; Hwang, J.; Cao, Huibo; Fernandez-Baca, Jaime A.

    2014-01-01

    A flop of electric polarization from Pc to Pa is observed in MnTiO3 as a spin flop transtion is triggered by a c-axis magnetic field, Hc=7 T. The critical magnetic field for Pa is significantly reduced in Mn1-xNixTiO3 (x=0.33). Neutron diffraction measurements revealed similar magnetic arrangements for the two compositions where the ordered spins couple antiferromagnetically with their nearest intra- and inter-planar neighbors. In the x=0.33 system, the single ion anisotropies of Mn2+ and Ni2+ compete and give rise to an additional spin reorientation transition at TR. A magnetic field, Hc, aligns the spins along c for TRN. The rotationmore » of the collinear spins away from the c-axis for TR alters the magnetic point symmetry and gives rise to new ME susceptibility tensor form. Such linear ME response provides satisfactory explanation for behavior of field-induced electric polarization in both compositions. As the Ni content increases to x=0.5 and 0.68, the ME effect disappears as a new magnetic phase emerges.« less

  16. Observation of the large magnetocaloric effect and suppression of orbital entropy change in Fe-doped MnV{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Huang, Z. H.; Luo, X. E-mail: ypsun@issp.ac.cn; Hu, L.; Tan, S. G.; Liu, Y.; Yuan, B.; Chen, J.; Song, W. H.; Sun, Y. P. E-mail: ypsun@issp.ac.cn

    2014-01-21

    We present the structural and magnetic properties of Mn{sub 1−x}Fe{sub x}V{sub 2}O{sub 4} (x = 0.1, 0.2, and 0.3), and investigate the magnetocaloric effect in those compounds. The ferrimagnetic spin ordering is enhanced with the Fe doping at Mn site of MnV{sub 2}O{sub 4}, while the orbital ordering is suppressed. Large magnetic entropy changes up to 3.8 J/kg K as well as the relative cooling power up to 110 J/kg at the field change of 0-2 T for Mn{sub 1−x}Fe{sub x}V{sub 2}O{sub 4} are calculated from the isothermal magnetization measurements. The large orbital entropy change of MnV{sub 2}O{sub 4} is suppressed by the Fe doping, while the spin entropy contribution arising from the strong spin-orbit coupling remains. Moreover, the doping of Fe broadens the temperature span of the large magnetic entropy change and increases the relative cooling power of MnV{sub 2}O{sub 4} by 2.4 times.

  17. X-ray magnetic spectroscopy of MBE-grown Mn-doped Bi{sub 2}Se{sub 3} thin films

    SciTech Connect (OSTI)

    Collins-McIntyre, L. J.; Watson, M. D.; Zhang, S. L.; Coldea, A. I.; Hesjedal, T.; Baker, A. A.; Harrison, S. E.; Pushp, A.; Kellock, A. J.; Parkin, S. S. P.; Laan, G. van der

    2014-12-15

    We report the growth of Mn-doped Bi{sub 2}Se{sub 3} thin films by molecular beam epitaxy (MBE), investigated by x-ray diffraction (XRD), atomic force microscopy (AFM), SQUID magnetometry and x-ray magnetic circular dichroism (XMCD). Epitaxial films were deposited on c-plane sapphire substrates by co-evaporation. The films exhibit a spiral growth mechanism typical of this material class, as revealed by AFM. The XRD measurements demonstrate a good crystalline structure which is retained upon doping up to ?7.5 atomic-% Mn, determined by Rutherford backscattering spectrometry (RBS), and show no evidence of the formation of parasitic phases. However an increasing interstitial incorporation of Mn is observed with increasing doping concentration. A magnetic moment of 5.1 ?{sub B}/Mn is obtained from bulk-sensitive SQUID measurements, and a much lower moment of 1.6 ?{sub B}/Mn from surface-sensitive XMCD. At ?2.5 K, XMCD at the Mn L{sub 2,3} edge, reveals short-range magnetic order in the films and indicates ferromagnetic order below 1.5 K.

  18. Electrode Materials with the Na0.44MnO2 Structure: Effect ofTitanium Substitution on Physical and Electrochemical Properties

    SciTech Connect (OSTI)

    Doeff, Marca M; Saint, Juliette A.; Doeff, Marca M; Wilcox, James D.

    2008-03-10

    The physical and electrochemical properties of LixMnO2 and LixTi0.11Mn0.89O2 synthesized from precursors made by glycine-nitrate combustion (GNC) and solid-state synthesis methods (SS) are examined in this paper. The highest specific capacities in lithium cells are obtained for SS-LixMnO2 electrodes at low current densities, but GNC-LixTi0.11Mn0.89O2 electrodes show the best high rate performance. These results can be explained by changes in the voltage characteristics and differences in the particle morphologies induced by the Ti-substitution and synthesis method. Ti-substitution also results in a decrease in the electronic conductivity, but greatly improves the thermal properties and imparts dissolution resistance to the electrode. For these reasons, it is preferable to use LixTi0.11MnO0.89O2 in lithium battery configurations rather than LixMnO2. Suggestions for improving the electrochemical performance of the Ti-substituted variant are given based on the results described herein.

  19. Crystallographic, magnetic, and electronic structures of ferromagnetic shape memory alloys Ni{sub 2}XGa (X=Mn,Fe,Co) from first-principles calculations

    SciTech Connect (OSTI)

    Bai, J.; Raulot, J. M.; Zhang, Y. D.; Esling, C.; Zhao, X.; Zuo, L.

    2011-01-01

    The crystallographic, magnetic and electronic structures of the ferromagnetic shape memory alloys Ni{sub 2}XGa (X=Mn, Fe, and Co), are systematically investigated by means of the first-principles calculations within the framework of density functional theory using the VIENNA AB INITIO SOFTWARE PACKAGE. The lattice parameters of both austenitic and martensitic phases in Ni{sub 2}MnGa have been calculated. The formation energies of the cubic phase of Ni{sub 2}XGa are estimated, and show a destabilization tendency if Mn atom is substituted by Fe or Co. From Ni{sub 2}MnGa to Ni{sub 2}CoGa, the down spin total density of states (DOS) at Fermi level is gradually increasing, whereas that of the up spin part remains almost unchanged. This is the main origin of the difference of the magnetic moment in these alloys. The partial DOS is dominated by the Ni and Mn 3d states in the bonding region below E{sub F}. There are two bond types existing in Ni{sub 2}XGa: one is between neighboring Ni atoms in Ni{sub 2}MnGa; the other is between Ni and X atoms in Ni{sub 2}FeGa and Ni{sub 2}CoGa alloys.

  20. Structural investigations on Co{sub 3-x}Mn{sub x}TeO{sub 6}; (0 < x ? 2); High temperature ferromagnetism and enhanced low temperature anti-ferromagnetism

    SciTech Connect (OSTI)

    Singh, Harishchandra; Sinha, A. K. E-mail: hng@rrcat.gov.in; Ghosh, Haranath E-mail: hng@rrcat.gov.in; Singh, M. N.; Rajput, Parasmani; Prajapat, C. L.; Singh, M. R.; Ravikumar, G.

    2014-08-21

    In the quest of materials with high temperature ferromagnetism and low temperature anti-ferromagnetism, we prepare Co{sub 3-x}Mn{sub x}TeO{sub 6}; (0?Mn concentration using Synchrotron X-ray diffraction (SXRD) and X-ray absorption near edge structure measurements in corroboration with magnetism are presented. Phase diagram obtained from Rietveld Refinement on SXRD data as a function of Mn concentration indicates doping disproportionate mixing of both monoclinic (C2/c) and rhombohedral (R 3{sup }) structure for x?Mn-O) bond lengths for x???0.5. Co and Mn K-edge XANES spectra reveal that both Co and Mn are in mixed oxidation state, Co{sup 2+}/Mn{sup 2+} and Co{sup 3+}/Mn{sup 3+}. Relative ratios of Co{sup 3+}/Co{sup 2+} and Mn{sup 3+}/Mn{sup 2+} obtained using Linear combination fit decrease with increasing x (for x???0.5). These structural and spectroscopic evidences are used to provide possible interpretation of the observed paramagnetic to ferromagnetic transition at around 185?K followed by an enhanced antiferromagnetic transition ?45?K for x?=?0.5.

  1. Magnetic Response of Mn(III)F(salen) at Low Temperatures

    SciTech Connect (OSTI)

    Park, J. - H.; Risset, O. N.; Shiddiq, M.; Peprah, M. K.; Knowles, E. S.; Andrus, Matthew; Beedle, C. C.; Ehlers, Georg; Podlesnyak, Andrey A; Cizmar, E.; Nagler, Stephen E; Hill, S.; Talham, Daniel R.; Meisel, Mark W.

    2014-01-01

    The low temperature magnetic response of Mn(III)F(salen), salen = H14C16N2O2, an S = 2 linear-chain system, has been studied. Using a single crystal with the field applied perpendicular to the chain direction, torque magnetometry, down to 20 mK and up to 18 T, revealed a feature at 3.8 T when T 400 mK. ESR ( 200 GHz) studies, using single crystals at 4 K and in 5 T, have not detected any signal. In 10 mT, the temperature dependence of the susceptibility of powder-like samples can be reasonably fit when J/kB = 50 K and g = 2. In addition, these data are unchanged for P 1.0 GPa. Using a randomly-oriented, powder-like, deuterated (12 of 14 H replaced by D) sample of 2.2 g at 270 mK, neutron scattering data, acquired with the Cold Neutron Chopper Spectrometer at the Spallation Neutron Source, show several well defined excitations that may be from the zero-field energy levels of antiferromagnetic S = 2 spins with g = 2, J/kB = 50 K, D/kB = 2.8 K, and E/kB = 0.5 K.

  2. Pressure dependence of the magnetic ground states in MnP

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Matsuda, Masaaki; Ye, Feng; Dissanayake, Sachith E.; Cheng, J. -G.; Chi, Songxue; Ma, Jie; Zhou, H. D.; Yan, Jia -Qiang; Kasamatsu, S.; Sugino, O.; et al

    2016-03-17

    MnP, a superconductor under pressure, exhibits a ferromagnetic order below TC~290 K followed by a helical order with the spins lying in the ab plane and the helical rotation propagating along the c axis below Ts~50 K at ambient pressure. We performed single-crystal neutron diffraction experiments to determine the magnetic ground states under pressure. Both TC and Ts are gradually suppressed with increasing pressure and the helical order disappears at ~1.2 GPa. At intermediate pressures of 1.8 and 2.0 GPa, the ferromagnetic order first develops and changes to a conical or two-phase (ferromagnetic and helical) structure with the propagation alongmore » the b axis below a characteristic temperature. At 3.8 GPa, a helical magnetic order appears below 208 K, which hosts the spins in the ac plane and the propagation along the b axis. The period of this b axis modulation is shorter than that at 1.8 GPa. Here, our results indicate that the magnetic phase in the vicinity of the superconducting phase may have a helical magnetic correlation along the b axis.« less

  3. Stress induced anisotropy in CoFeMn soft magnetic nanocomposites

    SciTech Connect (OSTI)

    Leary, A. M. Keylin, V.; McHenry, M. E.; Ohodnicki, P. R.

    2015-05-07

    The use of processing techniques to create magnetic anisotropy in soft magnetic materials is a well-known method to control permeability and losses. In nanocomposite materials, field annealing below the Curie temperature results in uniaxial anisotropy energies up to ?2?kJ/m{sup 3}. Higher anisotropies up to ?10?kJ/m{sup 3} result after annealing Fe-Si compositions under stress due to residual stress in the amorphous matrix acting on body centered cubic crystals. This work describes near zero magnetostriction Co{sub 80?x?y}Fe{sub x}Mn{sub y}Nb{sub 4}B{sub 14}Si{sub 2} soft magnetic nanocomposites, where x and y?

  4. Phase diagram and magnetocaloric effects in Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15} and (Mn{sub 1?x}Cr{sub x})NiGe{sub 1.05} alloys

    SciTech Connect (OSTI)

    Quetz, Abdiel Muchharla, Baleeswaraiah; Dubenko, Igor; Talapatra, Saikat; Ali, Naushad; Samanta, Tapas; Stadler, Shane

    2014-05-07

    The magnetocaloric and thermomagnetic properties of Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15} and (Mn{sub 1?x}Cr{sub x}) NiGe{sub 1.05} systems for 0???x???0.105 and 0???x???0.1, respectively, have been studied by x-ray diffraction, differential scanning calorimetry, and magnetization measurements. Partial substitution of Cr for Mn in (Mn{sub 1?x}Cr{sub x})NiGe{sub 1.05} results in a first order magnetostructural transition from a hexagonal paramagnetic to an orthorhombic paramagnetic phase near T{sub M}???380?K (for x?=?0.07). Partial substitution of Cr for In in Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15} shifts the magnetostructural transition to a higher temperature (T?=?T{sub M}???450?K) for x?=?0.1. Large magnetic entropy changes of ?S?=??12 (J/(kgK)) and ?S?=??11 (J/(kgK)), both for a magnetic field change of 5?T, were observed in the vicinity of T{sub M} for (Mn{sub 1?x}Cr{sub x})NiGe{sub 1.05} and Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15}, respectively.

  5. untitled

    Gasoline and Diesel Fuel Update (EIA)

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Liquefied Refinery Gases 382 8 390 2,072 157 116 2,345 EthaneEthylene 10...

  6. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Liquefied Refinery Gases 331 -18 313 2,398 -147 -220 2,031 EthaneEthylene...

  7. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Refinery and Blender Net Production of Finished Petroleum Products by PAD and Refining Districts, 2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND,...

  8. Redox Exchange Induced MnO2 Nanoparticle Enrichment in Poly(3,4-ethylenedioxythiophene) Nanowires for Electrochemical Energy Storage

    SciTech Connect (OSTI)

    Liu, R.; Duay, Jonathon; Lee, Sang Bok

    2010-06-30

    MnO2 nanoparticle enriched poly(3,4-ethylenedioxythiophene) (PEDOT) nanowires are fabricated by simply soaking the PEDOT nanowires in potassium permanganate (KMnO4) solution. The structures of these MnO2 nanoparticle enriched PEDOT nanowires are characterized by SEM and TEM, which show that the MnO2 nanoparticles have uniform sizes and are finely dispersed in the PEDOT matrix. The chemical constituents and bonding of these composite nanowires are characterized by energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy, and infrared spectroscopy, which indicate that the formation and dispersion of these MnO2 nanoparticles into the nanoscale pores of the PEDOT nanowires are most likely triggered by the reduction of KMnO4 via the redox exchange of permanganate ions with the functional group on PEDOT. Varying the concentrations of KMnO4 and the reaction time controls the loading amount and size of the MnO2 nanoparticles. Cyclic voltammetry and galvanostatic charge-discharge are used to characterize the electrochemical properties of these MnO2 nanoparticle loaded PEDOT nanowires. Due to their extremely high exposed surface area with nanosizes, the pristine MnO2 nanoparticles in these MnO2 nanoparticle enriched PEDOT nanowires show very high specific capacitance (410 F/g) as the supercapacitor electrode materials as well as high Li+ storage capacity (300 mAh/g) as cathode materials of Li ion battery, which boost the energy storage capacity of PEDOT nanowires to 4 times without causing excessive volume expansion in the polymer. The highly conductive and porous PEDOT matrix facilitates fast charge/discharge of the MnO2 nanoparticles and prevents them from agglomerating. These synergic properties enable the MnO2 nanoparticle enriched PEDOT nanowires to be promising electrode materials for supercapacitors and lithium ion batteries.

  9. Insight into the Atomic Structure of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material in the First Cycle

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Xuejie; Yu, Xiqian; Lin, Mingxiang; Ben, Liubin; Sun, Yang; Wang, Hao; Yang, Zhenzhong; Gu, Lin; Yang, Xiao -Qing; Zhao, Haofei; et al

    2014-12-22

    Application of high-voltage spinel LiNi0.5Mn1.5O4 cathode material is the closest and the most realistic approach to meeting the midterm goal of lithium-ion batteries for electric vehicles (EVs) and plug-in hybrid electric vehicles (HEVs). However, this application has been hampered by long-standing issues, such as capacity degradation and poor first-cycle Coulombic efficiency of LiNi0.5Mn1.5O4 cathode material. Although it is well-known that the structure of LiNi0.5Mn1.5O4 into which Li ions are reversibly intercalated plays a critical role in the above issues, performance degradation related to structural changes, particularly in the first cycle, are not fully understood. Here, we report detailed investigations ofmore » local atomic-level and average structure of LiNi0.5Mn1.5O4 during first cycle (3.5–4.9 V) at room temperature. We observed two types of local atomic-level migration of transition metals (TM) ions in the cathode of a well-prepared LiNi0.5Mn1.5O4//Li half-cell during first charge via an aberration-corrected scanning transmission electron microscopy (STEM). Surface regions (~2 nm) of the cycled LiNi0.5Mn1.5O4 particles show migration of TM ions into tetrahedral Li sites to form a Mn3O4-like structure. However, subsurface regions of the cycled particles exhibit migration of TM ions into empty octahedral sites to form a rocksalt-like structure. The migration of these TM ions are closely related to dissolution of Ni/Mn ions and building-up of charge transfer impedance, which contribute significantly to the capacity degradation and the poor first-cycle Coulombic efficiency of spinel LiNi0.5Mn1.5O4 cathode material. Accordingly, we provide suggestions of effective stabilization of LiNi0.5Mn1.5O4 structure to obtain better electrochemical performance.« less

  10. Combined effects of Bi deficiency and Mn substitution on the structural transformation and functionality of BiFeO{sub 3} films

    SciTech Connect (OSTI)

    Chen, Jingyi; Wang, Yao Deng, Yuan

    2014-11-07

    Mn-doped BiFeO{sub 3} films with Mn contents of 5 and 10 mol. % were prepared via a chemical route. A carefully controlled amount of Bi deficiency was introduced to further tune the lattice structure and the functionality of multiferroic BiFeO{sub 3}. The crystal structure of Bi{sub 1−δ}Fe{sub 1−x}Mn{sub x}O{sub 3} films was investigated by X-ray diffraction and Raman spectra; a rhombohedral-to-orthorhombic phase transition was revealed. The observed double hysteresis loops and two capacitance maxima from polarization vs electric field and capacitance-voltage measurements indicate an antiferroelectric-like behavior. Additionally, the coexistence of ferroelectric (FE) and antiferroelectric (AFE) phases in Bi{sub 1−δ}Fe{sub 1−x}Mn{sub x}O{sub 3} films was revealed from the domain structures obtained by piezoelectric force microscopy. The effects of Mn substitution in conjunction with Bi deficiency on the FE-AFE phase transition and electrical behavior of BiFeO{sub 3} films are discussed in detail. Meanwhile, magnetic and photoluminescence measurements on the films illustrate that Mn substitution gives rise to the net magnetic moment and the defects induced by both Bi deficiency and Mn substitution influence the electronic structure of BiFeO{sub 3} films. This study thus shows a simple and effective way to control the functionalities of BiFeO{sub 3} films.

  11. U.S. Department of Energy

    Gasoline and Diesel Fuel Update (EIA)

    ... TX ROBERTS INDIAN CREEK 1909833001 TX GREGG LONGVIEW 1976560001 TX SMITH CHAPEL HILL ... TX STEPHENS SHACKELFORD 170 4916171012 TX IRION MERTZON 4916171017 TX SMITH TYLER GAS ...

  12. Effect of Mn doping on structural and magnetic susceptibility of C-type rare earth nano oxides Er{sub 2?x}Mn{sub x}O{sub 3}

    SciTech Connect (OSTI)

    Heiba, Zein K.; Taif University, Faculty of Science, Physics Department ; Mohamed, Mohamed Bakr; Fuess, H.

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? Er{sub 2?x}Mn{sub x}O{sub 3} (0.0 ? x ? 0.20) prepared by solgel method. ? The change in lattice parameter is not linear with x due to the change in crystallite size with doping. ? Anomalous concentration dependence is found in magnetic susceptibility. ? The effective magnetic moment ?{sub eff} is found to decrease with composition parameter x. ? Superexchange interactions between Er ions depending on the amount of Mn or Er in different sites. -- Abstract: The manganese doped rare earth oxides Er{sub 2?x}Mn{sub x} O{sub 3} (0.0 ? x ? 0.20) were synthesized by a solgel process and analyzed by X-ray diffraction using Rietveld refinement methods. A single phase solid solution is formed up to x = 0.15 while for x ? 0.2 a manganese oxide phase appears in the diffraction pattern. Preferential cationic distribution between the non-equivalent sites 8b and 24d of space group Ia3{sup } is found for all samples but to a different extent. The octahedral volume and average bond length of Er{sub 1}-O for 8b site decrease while both octahedral volume and bond length of Er{sub 2}-O for 24d site increase. Magnetization measurements were done in the temperature range 5300 K. The effective magnetic moment ?{sub eff} is found to decrease with composition parameter x, except for sample x = 0.05 where the magnetization is enhanced. The Curie-Weiss paramagnetic temperatures indicate antiferromagnetic interaction.

  13. Crystal chemical modeling of the Li ion distribution in Li{sub x}Mn{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Rohrer, C.L.; Rohrer, G.S.

    1996-12-31

    The Monte Carlo bond valence method was used to model the local atomic structure of Li{sub x}Mn{sub 2}O{sub 4} (x = 0.25 and x = 1.0). The results predict that Mn{sup +3} and Mn{sup +4} are randomly distributed at the octahedral positions and that the Mn{sup +3}-O bond distance is 2.02 {Angstrom} while the Mn{sup +4}-O distance is 1.91 {Angstrom}. As the Li content decreases, the cell contracts due to the higher concentration of shorter bonds. Based on maps that show the distribution of crystal chemically equivalent sites, we conclude that the Li ion diffusion paths go through 48f sites, that Li might be more mobile for the case of x = 1.0 than for x = 0.25 (due to the expanded cell volume), and that for x > 1, the 16c position is the most likely Li site.

  14. Preparation of magnetic photocatalyst nanoparticlesTiO{sub 2}/SiO{sub 2}/MnZn ferriteand its photocatalytic activity influenced by silica interlayer

    SciTech Connect (OSTI)

    Laohhasurayotin, Kritapas; Pookboonmee, Sudarat; Viboonratanasri, Duangkamon; Kangwansupamonkon, Wiyong

    2012-06-15

    Highlights: ? TiO{sub 2}/SiO{sub 2}/MnZn ferrite acts as magnetic photocatalyst nanoparticle. ? SiO{sub 2} interlayer is used to prevent electron migration between photocatalyst and magnetic core. ? TiO{sub 2}/MnZn ferrite without SiO{sub 2} interlayer shows poor magnetic and photocatalytic property. -- Abstract: A magnetic photocatalyst, TiO{sub 2}/SiO{sub 2}/MnZn ferrite, was prepared by stepwise synthesis involving the co-precipitation of MnZn ferrite as a magnetic core, followed by a coating of silica as the interlayer, and titania as the top layer. The particle size and distribution of magnetic nanoparticles were found to depend on the addition rate of reagent and dispersing rate of reaction. The X-ray diffractometer and transmission electron microscope were used to examine the crystal structures and the morphologies of the prepared composites. Vibrating sample magnetometer was also used to reveal their superparamagnetic property. The UVVis spectrophotometer was employed to monitor the decomposition of methylene blue in the photocatalytic efficient study. It was found that at least a minimum thickness of the silica interlayer around 20 nm was necessary for the inhibition of electron transference initiated by TiO{sub 2} and MnZn ferrite.

  15. Electronic structures and magnetic stabilities of 2D Mn-doped GaAs nanosheets: The role of long-range exchange interactions and doping strategies

    SciTech Connect (OSTI)

    Lan, Mu; Xiang, Gang Zhang, Xi

    2014-08-28

    We investigate the structural, electronic and magnetic properties of Mn atoms doped two-dimensional (2D) hexagonal GaAs nanosheets (GaAsNSs) using both first-principle calculations and Monte Carlo simulations. The first-principle molecular dynamics is first used to test the structural stability of Mn-doped GaAsNS ((Ga,Mn)AsNS). The analysis of spin-resolved electronic structures and determination of magnetic exchange interactions based on density functional theory (DFT) calculations reveals the existence of long-range exchange interaction in the system. Finally, Metropolis Monte Carlo simulation is employed to estimate Curie temperatures (T{sub C}s) of (Ga,Mn)AsNSs with different doping concentrations by different doping strategies. The results indicate that a T{sub C} up to 82 K can be obtained in regularly-doped (Ga,Mn)AsNSs and doping strategies have prominent impact on T{sub C}s of the systems, which emphasizes the importance of both long-range interactions and doping strategies in reduced dimensional diluted magnetic semiconductors (DMSs)

  16. Influence of Mn concentration on magnetic topological insulator MnxBi2−xTe3 thin-film Hall-effect sensor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ni, Y.; Zhang, Z.; Nlebedim, I. C.; Hadimani, R. L.; Jiles, D. C.

    2015-06-11

    Hall-effect (HE) sensors based on high-quality Mn-doped Bi2Te3 topological insulator (TI) thin films have been systematically studied in this paper. Improvement of Hall sensitivity is found after doping the magnetic element Mn into Bi2Te3. The sensors with low Mn concentrations, MnxBi2-xTe3, x = 0.01 and 0.08 show the linear behavior of Hall resistance with sensitivity about 5 Ω/T. And their Hall sensitivity shows weak dependence on temperature. For sensors with high Mn concentration (x = 0.23), the Hall resistance with respect to magnetic field shows a hysteretic behavior. Moreover, its sensitivity shows almost eight times as high as that ofmore »the HE sensors with low Mn concentration. The highest sensitivity can reach 43 Ω/T at very low magnetic field. This increase of Hall sensitivity is caused by the occurrence of anomalous HE (AHE) after ferromagnetic phase transition. Our work indicates that the magnetic-element-doped TIs with AHE are good candidates for HE sensors.« less

  17. Influence of Mn concentration on magnetic topological insulator MnxBi2−xTe3 thin-film Hall-effect sensor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ni, Y.; Zhang, Z.; Nlebedim, I. C.; Hadimani, R. L.; Jiles, D. C.

    2015-06-11

    Hall-effect (HE) sensors based on high-quality Mn-doped Bi2Te3 topological insulator (TI) thin films have been systematically studied in this paper. Improvement of Hall sensitivity is found after doping the magnetic element Mn into Bi2Te3. The sensors with low Mn concentrations, MnxBi2-xTe3, x = 0.01 and 0.08 show the linear behavior of Hall resistance with sensitivity about 5 Ω/T. And their Hall sensitivity shows weak dependence on temperature. For sensors with high Mn concentration (x = 0.23), the Hall resistance with respect to magnetic field shows a hysteretic behavior. Moreover, its sensitivity shows almost eight times as high as that ofmore » the HE sensors with low Mn concentration. The highest sensitivity can reach 43 Ω/T at very low magnetic field. This increase of Hall sensitivity is caused by the occurrence of anomalous HE (AHE) after ferromagnetic phase transition. Our work indicates that the magnetic-element-doped TIs with AHE are good candidates for HE sensors.« less

  18. Structural phase transition and magnetism in hexagonal SrMnO{sub 3} by magnetization measurements and by electron, x-ray, and neutron diffraction studies

    SciTech Connect (OSTI)

    Daoud-Aladine, A.; Chapon, L. C.; Knight, K. S.; Martin, C.; Hervieu, M.; Brunelli, M.; Radaelli, P. G.

    2007-03-01

    The structural and magnetic properties of the hexagonal four-layer form of SrMnO{sub 3} have been investigated by combining magnetization measurements, electron diffraction, and high-resolution synchrotron x-ray and neutron powder diffraction. Below 350 K, there is subtle structural phase transition from hexagonal symmetry (space group P6{sub 3}/mmc) to orthorhombic symmetry (space group C222{sub 1}) where the hexagonal metric is preserved. The second-order phase transition involves a slight tilting of the corner-sharing Mn{sub 2}O{sub 9} units composed of two face-sharing MnO{sub 6} octahedra and the associated displacement of Sr{sup 2+} cations. The phase transition is described in terms of symmetry-adapted displacement modes of the high symmetry phase. Upon further cooling, long range magnetic order with propagation vector k=(0,0,0) sets in below 300 K. The antiferromagnetic structure, analyzed using representation theory, shows a considerably reduced magnetic moment indicating the crucial role played by direct exchange between Mn centers of the Mn{sub 2}O{sub 9} units.

  19. Effect of Heat-Treatment on the Phases of Ni-Mn-Ga Magnetic Shape Memory Alloys

    SciTech Connect (OSTI)

    Huq, Ashfia; Ari-Gur, Pnina; Kimmel, Giora; Richardson, James W; Sharma, Kapil

    2009-01-01

    The Heusler alloys Ni50Mn25+xGa25-x display magnetic shape memory effect (MSM) with very fast and large reversible strain under magnetic fields. This large strain and the speed of reaction make MSM alloys attractive as smart materials. Our crystallographic investigation of these alloys, focused on non-stoichiometric composition with excess of manganese. Using neutron diffraction, we revealed the necessary processing parameters to achieve and preserve the homogeneous metastable one-phase martensitic structure that is needed for an MSM effect at room temperature.

  20. Energy harvesting using martensite variant reorientation mechanism in a NiMnGa magnetic shape memory alloy

    SciTech Connect (OSTI)

    Karaman, I.; Basaran, B.; Karaca, H. E.; Karsilayan, A. I.; Chumlyakov, Y. I.

    2007-04-23

    Magnetic shape memory alloys demonstrate significant potential for harvesting waste mechanical energy utilizing the Villari effect. In this study, a few milliwatts of power output are achieved taking advantage of martensite variant reorientation mechanism in Ni{sub 51.1}Mn{sub 24}Ga{sub 24.9} single crystals under slowly fluctuating loads (10 Hz) without optimization in the power conversion unit. Effects of applied strain range, bias magnetic field, and loading frequency on the voltage output are revealed. Anticipated power outputs under moderate frequencies are predicted showing that the power outputs higher than 1 W are feasible.

  1. Temperature dependence of spin-orbit torque effective fields in the diluted magnetic semiconductor (Ga,Mn)As

    SciTech Connect (OSTI)

    Howells, B.; Edmonds, K. W.; Campion, R. P.; Gallagher, B. L.

    2014-07-07

    We report on a study of the temperature-dependence of current-induced effective magnetic fields due to spin-orbit interactions in the diluted ferromagnetic semiconductor (Ga,Mn)As. Contributions from the effective fields as well as from the anomalous Nernst effect are evident in the difference between transverse resistance measurements as a function of an external magnetic field for opposite orientations of the applied current. We separately extract these contributions by fitting to a model of coherently rotating magnetization. The component of the effective field with Dresselhaus symmetry is substantially enhanced with increasing temperature, while no significant temperature-dependence is observed for the component with Rashba symmetry.

  2. A study of the phase transition and magnetocaloric effect in multiferroic La{sub 2}MnNiO{sub 6} single crystals

    SciTech Connect (OSTI)

    Balli, M. Jandl, S.; Fournier, P.; Gospodinov, M. M.

    2014-05-07

    Magnetic and magnetocaloric properties of single crystal double perovskite La{sub 2}MnNiO{sub 6} have been investigated in details. Its ordered phase with a high Curie temperature (T{sub C} = 280 K) exhibits a significant refrigerant capacity around room temperature. A model based on the mean field theory approximation has been used in order to quantify the magnetic and magnetocaloric properties in the ordered La{sub 2}MnNiO{sub 6}. The magnetization and entropy changes were satisfactorily simulated as a function of temperature and magnetic field. On the other hand, the presence of cationic disorder in La{sub 2}MnNiO{sub 6} phases allows to shift the Curie point to low temperature without a significant change in the magnetocaloric performance.

  3. Electrochemical performance of polyaniline coated LiMn{sub 2}O{sub 4} cathode active material for lithium ion batteries

    SciTech Connect (OSTI)

    ?ahan, Halil Dokan, Fatma K?l?c Ayd?n, Abdlhamit zdemir, Burcu zdemir, Nazl? Patat, ?aban

    2013-12-16

    LiMn{sub 2}O{sub 4} compound are synthesized by combustion method using glycine as a fuel at temperature (T), 800C which was coated by a polyaniline. The goal of this procedure is to promote better electronic conductivity of the LiMn{sub 2}O{sub 4} particles in order to improve their electrochemical performance for their application as cathodes in secondary lithium ion batteries. The structures of prepared products have been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). To investigate the effect of polyaniline coating galvanostatic charge-discharge cycling (148 mA g{sup ?1}) studies are made in the voltage range of 3.5-4.5 V vs. Li at room temperature. Electrochemical performance of the LiMn{sub 2}O{sub 4} was significantly improved by the polaniline coating.

  4. Self-assembly of compositionally modulated Ga{sub 1−x}Mn{sub x}As multilayers during molecular beam epitaxy

    SciTech Connect (OSTI)

    Gallardo-Hernández, S.; Martinez-Velis, I.; Ramirez-Lopez, M.; Lopez-Lopez, M.; Kudriatsev, Y.; Escobosa-Echavarria, A.; Luiz Morelhao, S.

    2013-11-04

    GaMnAs structures were grown on GaAs(100) substrates by molecular beam epitaxy employing different growth parameters. We studied manganese incorporation employing secondary ion mass spectrometry (SIMS). At a growth temperature of 300 °C, we observed a self-assembled modulation of the manganese concentration. SIMS depth profiles were analyzed employing a depth resolution function taking into account sputtering-induced broadening of the original distribution and segregation. We found a Mn segregation length along the growth direction of ∼4 nm. The presence of GaMnAs multilayers was corroborated by high-resolution x-ray diffraction. Spinodal decomposition is a possible mechanism for the spontaneous formation of the multilayer structure.

  5. Synthesis of Mn-intercalated layered titanate by exfoliation-flocculation approach and its efficient photocatalytic activity under visible-light

    SciTech Connect (OSTI)

    Fu, Jie; Tian, Yanlong; Chang, Binbin; Li, Gengnan; Xi, Fengna; Dong, Xiaoping

    2012-12-15

    A novel Mn-intercalated layered titanate as highly active photocatalyst in visible-light region has been synthesized via a convenient and efficient exfoliation-flocculation approach with divalent Mn ions and monolayer titanate nanosheets. The 0.91 nm interlayer spacing of obtained photocatalyst is in accordance with the sum of the thickness of titanate nanosheet and the diameter of Mn ions. The yellow photocatalyst shows a spectral response in visible-light region and the calculated band gap is 2.59 eV. The photocatalytic performance of this material was evaluated by degradation and mineralization of an aqueous dye methylene blue under visible-light irradiation, and an enhanced photocatalytic activity in comparison with protonated titanate as well as the P25 TiO{sub 2} and N-doped TiO{sub 2} was obtained. Additionally, the layered structure is retained, no dye ions intercalating occurs during the photocatalysis process, and a {approx}90% photocatalytic activity can be remained after reusing 3 cycles. - Graphical abstract: Mn-intercalated layered titanate as a novel and efficient visible-light harvesting photocatalyst was synthesized via a convenient and efficient exfoliation-flocculation approach in a mild condition. Highlights: Black-Right-Pointing-Pointer Mn-intercalated titanate has been prepared by exfoliation-flocculation approach. Black-Right-Pointing-Pointer The as-prepared catalyst shows spectral response in the visible-light region. Black-Right-Pointing-Pointer Heat treatment at certain temperature enables formation of Mn-doped TiO{sub 2}. Black-Right-Pointing-Pointer Dye can be degradated effectively by the catalyst under visible light irradiation.

  6. Nano-twin Mediated Plasticity in Carbon-containing FeNiCoCrMn High Entropy Alloys

    SciTech Connect (OSTI)

    Wu, Zhenggang; Bei, Hongbin; Parish, Chad M

    2015-06-14

    Equiatomic FeNiCoCrMn alloy has been reported to exhibit promising strength and ductility at cryogenic temperature and deformation mediated by nano-twining appeared to be one of the main reasons. We use the FeNiCoCrMn alloy as a base alloy to seek further improvement of its mechanical properties by alloying additional elements, i.e., interstitial carbon. Moreover, the effects of carbon on microstructures, mechanical properties and twinning activities were investigated in two different temperatures (77 and 293 K). With addition of 0.5 at% C, the high entropy alloy still remains entirely single phase face-centered cubic (FCC) crystal structure. We found that these materials can be cold rolled and recrystallized to produce a microstructure with equiaxed grains. Both strain hardening rate and strength are enhanced while high uniform elongations to fracture (~70% at 77 K and ~40% at 293 K) are still maintained. The increased strain hardening and strength could be caused by the promptness of deformation twinning in C-containing high entropy alloys.

  7. Effect of Pt and H{sub 2} on n-butane isomerization over Fe and Mn promoted sulfated zirconia

    SciTech Connect (OSTI)

    Song, Xuemin; Reddy, K.R.; Sayari, A.

    1996-06-01

    The activity of a 0.4 wt% Pt-containing Fe and Mn promoted sulfated zirconia (PtSFMZ) catalyst in n-butane isomerization at 35{degrees}C was compared to that of a Pt-free catalyst (SFMZ). The maximum rate of n-butane conversion observed in helium over PtSFMZ was found to be 2.5 times higher than that over the SFMZ catalyst under the same conditions. It is believed that n-butane isomerization proceeds via a bimolecular mechanism in which the formation of hydrogen-deficient intermediates (carbenium ions and butenes), is necessary and the presence of transition metals such as Pt, Fe, and Mn on sulfated zirconia facilitates the formation/accumulation of these intermediates and increases their stability on the catalyst surface. The presence of H{sub 2} had a strong negative effect on n-butane conversion over PtSFMZ, but had no effect over SFMZ. The negative effect of H{sub 2} on PtSFMZ catalyst in n-butane isomerization reaction was attributed to the decreased concentration of butenes in the presence of hydrogen atoms which are formed by the dissociation of H{sub 2} on Pt. The ability of calcined Pt-containing catalysts to activate hydrogen at 35{degrees}C was demonstrated. Reduced SFMZ with or without Pt was not active at 35{degrees}C regardless of the nature of the carrier gas. 42 refs., 5 figs.

  8. Ferromagnetic response of multiferroic TbMnO{sub 3} films mediated by epitaxial strain and chemical pressure

    SciTech Connect (OSTI)

    Izquierdo, J.; Morn, O.; Astudillo, A.; Bolaos, G.; Arnache, O.

    2014-05-07

    High quality Tb{sub 1?x}Al{sub x}MnO{sub 3} (x?=?0, 0.3) films have been grown under different values of compressive/tensile strain using (001)-oriented SrTiO{sub 3} and MgO substrates. The films were grown by means of rf sputtering at substrate temperature of 800??C. X-ray diffraction analysis shows that films are single phase, preferentially oriented in the (111) and (122) directions for films deposited on SrTiO{sub 3} and MgO substrates, respectively. Although the TbMnO{sub 3} target shows antiferromagnetic order, the films deposited on both substrates show weak ferromagnetic phase at low temperature coexisting with the antiferromagnetic phase. The introduction of Al in the films clearly enhances their ferromagnetic behavior, improving the magnetic performance of this material. Indeed, M(H) measurements at 5?K show a well-defined hysteresis for films grown on both substrates. However, a stronger magnetic signal (larger values of remanence and coercive field) is observed for films deposited on MgO substrates. The chemical pressure generated by Al doping together with the substrate-induced strain seem to modify the subtle competition between magnetic interactions in the system. It is speculated that such modification could lead to a non-collinear magnetic state that may be tuned by strain modifications. This may be performed by varying the thickness of the films and/or considering other substrate materials.

  9. Magnetoresistance effects and spin-valve like behavior of an arrangement of two MnAs nanoclusters

    SciTech Connect (OSTI)

    Fischer, M.; Klar, P. J.; Elm, M. T.; Sakita, S.; Hara, S.

    2015-01-19

    We report on magnetotransport measurements on a MnAs nanocluster arrangement consisting of two elongated single-domain clusters connected by a metal spacer. The arrangement was grown on GaAs(111)B-substrates by selective-area metal organic vapor phase epitaxy. Its structural properties were investigated using scanning-electron microscopy and atomic-force microscopy, while its magnetic domain structure was analyzed by magnetic-force microscopy. The magnetoresistance of the arrangement was investigated at 120 K for two measurement geometries with the magnetic field oriented in the sample plane. For both geometries, discrete jumps of the magnetoresistance of the MnAs nanocluster arrangement were observed. These jumps can be explained by magnetic-field induced switching of the relative orientation of the magnetizations of the two clusters which affects the spin-dependent scattering in the interface region between the clusters. For a magnetic field orientation parallel to the nanoclusters' elongation direction a spin-valve like behavior was observed, showing that ferromagnetic nanoclusters may be suitable building blocks for planar magnetoelectronic devices.

  10. Optical and magneto-optical studies of martensitic transformation in Ni-Mn-Ga magnetic shape memory alloys

    SciTech Connect (OSTI)

    Beran, L.; Cejpek, P.; Kulda, M.; Antos, R.; Holy, V.; Veis, M.; Straka, L.; Heczko, O.

    2015-05-07

    Optical and magneto-optical properties of single crystal of Ni{sub 50.1}Mn{sub 28.4}Ga{sub 21.5} magnetic shape memory alloy during its transformation from martensite to austenite phase were systematically studied. Crystal orientation was approximately along (100) planes of parent cubic austenite. X-ray reciprocal mapping confirmed modulated 10?M martensite phase. Temperature depended measurements of saturation magnetization revealed the martensitic transformation at 335?K during heating. Magneto-optical spectroscopy and spectroscopic ellipsometry were measured in the sample temperature range from 297 to 373?K and photon energy range from 1.2 to 6.5?eV. Magneto-optical spectra of polar Kerr rotation as well as the spectra of ellipsometric parameter ? exhibited significant changes when crossing the transformation temperature. These changes were assigned to different optical properties of Ni-Mn-Ga in martensite and austenite phases due to modification of electronic structure near the Fermi energy during martensitic transformation.

  11. Kondo Effect in 3d-host Ferromagnetic Sm1-xCexMn2Ge2

    SciTech Connect (OSTI)

    Liang,G.; Yao, Q.; Xi, H.; Mochizuki, K.; Markert, J.; Croft, M.

    2006-01-01

    Lattice, Ce L{sub 3}-edge, magnetic susceptibility, and electrical resistivity results on polycrystalline Sm{sub 1-x}Ce{sub x}Mn{sub 2}Ge{sub 2} (0 {<=} x {<=} 1) compound series are presented. The lattice parameters a and c increase almost linearly with the increase of Ce concentration x. The Ce-L{sub 3} X-ray absorption spectra indicate that the Ce in this series is nearly trivalent, and Ce valence decreases slightly with the increase of Ce concentration x. Magnetic susceptibility results indicate that the antiferromagnetic (AF) phase in the re-entrant ferromagnetic compound, SmMn{sub 2}Ge{sub 2}, is completely destroyed by merely 1.1% Ce for Sm substitution. For x > 0.011, only ferromagnetic (FM) phases exist below room temperature. It is found that in these materials Ce Kondo scattering coexists with the 3d-host FM fields and is also effectively weakened by such fields.

  12. Magnetooptical study of CdSe/ZnMnSe semimagnetic quantum-dot ensembles with n-type modulation doping

    SciTech Connect (OSTI)

    Reshina, I. I. Ivanov, S. V.

    2014-12-15

    Magnetic and polarization investigations of the photoluminescence and resonant electron spin-flip Raman scattering in ensembles of self-organized CdSe/ZnMnSe semimagnetic quantum dots with n-type modulation doping are carried out. It is demonstrated that exciton transitions contribute to the photoluminescence band intensity, along with the transitions of trions in the singlet state. In the Hanle-effect measurements, negative circular polarization in zero magnetic field is observed, which is related to the optical orientation of a trion heavy hole. The lifetime and spin-relaxation time of a heavy hole are estimated as ?3 and ?1 ps, respectively. Such short times are assumed to be due to Auger recombination with the excitation of an intrinsic transition in a Mn{sup 2+} ion. Investigations of the photoluminescence-maximum intensity and shift in a longitudinal magnetic field at the ?{sup ?}?{sup +} and ?{sup ?}?{sup ?} polarizations reveal the pronounced spin polarization of electrons. Under resonant excitation conditions, a sharp increase in the photoluminescence-band maximum intensity at ?{sup ?} excitation polarization over the ?{sup +} one is observed. The Raman scattering peak at the electron spin-flip transition is observed upon resonant excitation in a transverse magnetic field in crossed linear polarizations. This peak is shown to be a Brillouin function of a magnetic field.

  13. Itinerant Antiferromagnetism in FeMnP0.8Si0.2

    SciTech Connect (OSTI)

    Sales, Brian C.; Susner, Michael A.; Conner, Benjamin S.; Yan, Jiaqiang Q.; May, Andrew F.

    2015-09-25

    Compounds based on the Fe2P structure have continued to attract interest because of the interplay between itinerant and localized magnetism in a noncentrosymmetric crystal structure, and because of the recent developments of these materials for magnetocaloric applications. We report the growth and characterization of millimeter-sized single crystals of FeMnP0.8Si0.2 with the Fe2P structure. Single-crystal x-ray diffraction, magnetization, resistivity, and Hall and heat capacity data are reported. The crystals exhibit itinerant antiferromagnetic order below 158 K with no hint of ferromagnetic behavior in the magnetization curves and with the spins ordered primarily in the ab plane. The room-temperature resistivity is close to the Ioffe-Regel limit for a metal. Single-crystal x-ray diffraction indicates a strong preference for Mn to occupy the larger pyramidal 3g site. The cation site preference in the as-grown crystals and the antiferromagnetism were not changed after high-temperature anneals and a rapid quench to room temperature

  14. Design of Semiconducting Tetrahedral Mn 1 ₋ x Zn x O Alloys and Their Application to Solar Water Splitting

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Haowei; Ndione, Paul F.; Ginley, David S.; Zakutayev, Andriy; Lany, Stephan

    2015-05-18

    Transition metal oxides play important roles as contact and electrode materials, but their use as active layers in solar energy conversion requires achieving semiconducting properties akin to those of conventional semiconductors like Si or GaAs. In particular, efficient bipolar carrier transport is a challenge in these materials. Based on the prediction that a tetrahedral polymorph of MnO should have such desirable semiconducting properties, and the possibility to overcome thermodynamic solubility limits by nonequilibrium thin-film growth, we exploit both structure-property and composition-structure relationships to design and realize novel wurtzite-structure Mn₁₋xZnxO alloys. At Zn compositions above x ≈ 0.3, thin films ofmore » these alloys assume the tetrahedral wurtzite structure instead of the octahedral rocksalt structure of MnO, thereby enabling semiconductor properties that are unique among transition metal oxides, i.e., a band gap within the visible spectrum, a band-transport mechanism for both electron and hole carriers, electron doping, and a band lineup suitable for solar hydrogen generation. A proof of principle is provided by initial photo-electrocatalytic device measurements, corroborating, in particular, the predicted favorable hole-transport properties of these alloys.« less

  15. Verification of Anderson superexchange in MnO via magnetic pair distribution function analysis and ab initio theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Benjamin A. Frandsen; Brunelli, Michela; Page, Katharine; Uemura, Yasutomo J.; Staunton, Julie B.; Billinge, Simon J. L.

    2016-05-11

    Here, we present a temperature-dependent atomic and magnetic pair distribution function (PDF) analysis of neutron total scattering measurements of antiferromagnetic MnO, an archetypal strongly correlated transition-metal oxide. The known antiferromagnetic ground-state structure fits the low-temperature data closely with refined parameters that agree with conventional techniques, confirming the reliability of the newly developed magnetic PDF method. The measurements performed in the paramagnetic phase reveal significant short-range magnetic correlations on a ~1 nm length scale that differ substantially from the low-temperature long-range spin arrangement. Ab initio calculations using a self-interaction-corrected local spin density approximation of density functional theory predict magnetic interactions dominatedmore » by Anderson superexchange and reproduce the measured short-range magnetic correlations to a high degree of accuracy. Further calculations simulating an additional contribution from a direct exchange interaction show much worse agreement with the data. Furthermore, the Anderson superexchange model for MnO is thus verified by experimentation and confirmed by ab initio theory.« less

  16. Spin and orbital Ti magnetism at LaMnO3/SrTiO3 interfaces

    SciTech Connect (OSTI)

    Garcial-Barriocanal, J; Cezar, J. C.; Bruno, F. Y.; Thakur, P.; Brookes, N. B.; Utfeld, C.; Riviera-Calzada, A.; Giblin, S. R.; Taylor, J. W.; Duffy, J. A.; Dugdale, S. B.; Nakamura, T.; Kodama, K.; Leon, C.; Okamoto, Satoshi; Santamaria, J.

    2010-01-01

    In systems with strong electron-lattice coupling, such as manganites, orbital degeneracy is lifted, what causes a null expectation value of the orbital moment. Magnetic structure is thus determined by spin-spin superexchange. In titanates, however, with much smaller Jahn-Teller distortions, orbital degeneracy might allow non-zero values of the orbital magnetic moment. Accordingly, novel forms of ferromagnetic superexchange interaction unique to t2g electrons systems have been theoretically predicted, although their experimental observation has remained elusive. Here we report a new kind of Ti3+ ferromagnetism at LaMnO3/SrTiO3 epitaxial interfaces. It results from charge transfer to the empty conduction band of the titanate and has spin and orbital contributions evidencing the role played by orbital degeneracy. The possibility of tuning magnetic alignment (ferromagnetic or antiferromagnetic) of Ti and Mn moments by structural parameters is demonstrated. This result will provide important clues for the understanding of the effects of orbital degeneracy in superexchange coupling.

  17. Heat capacity of the site-diluted spin dimer system Ba₃(Mn1-xVx)₂O₈

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

    2011-08-05

    Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba₃(Mn1-xVx)₂O₈. The parent compound Ba₃Mn₂O₈ is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d² Mn⁵⁺ ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d⁰ V⁵⁺ ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0≤x≤0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for amore » phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.« less

  18. Large magnetic entropy change and magnetoresistance in a Ni41Co9Mn40Sn10 magnetic shape memory alloy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, L.; Cong, D. Y.; Ma, L.; Nie, Z. H.; Wang, M. G.; Wang, Z. L.; Suo, H. L.; Ren, Y.; Wang, Y. D.

    2015-07-02

    A polycrystalline Ni41Co9Mn40Sn10 (at. %) magnetic shape memory alloy was prepared by arc melting and characterized mainly by magnetic measurements, in-situ high-energy X-ray diffraction (HEXRD), and mechanical testing. A large magnetoresistance of 53.8% (under 5 T) and a large magnetic entropy change of 31.9 J/(kg K) (under 5 T) were simultaneously achieved. Both of these values are among the highest values reported so far in Ni-Mn-Sn-based Heusler alloys. The large magnetic entropy change, closely related to the structural entropy change, is attributed to the large unit cell volume change across martensitic transformation as revealed by our in-situ HEXRD experiment. Furthermore,more » good compressive properties were also obtained. Lastly, the combination of large magnetoresistance, large magnetic entropy change, and good compressive properties, as well as low cost makes this alloy a promising candidate for multifunctional applications.« less

  19. Nano-twin Mediated Plasticity in Carbon-containing FeNiCoCrMn High Entropy Alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Zhenggang; Bei, Hongbin; Parish, Chad M

    2015-06-14

    Equiatomic FeNiCoCrMn alloy has been reported to exhibit promising strength and ductility at cryogenic temperature and deformation mediated by nano-twining appeared to be one of the main reasons. We use the FeNiCoCrMn alloy as a base alloy to seek further improvement of its mechanical properties by alloying additional elements, i.e., interstitial carbon. Moreover, the effects of carbon on microstructures, mechanical properties and twinning activities were investigated in two different temperatures (77 and 293 K). With addition of 0.5 at% C, the high entropy alloy still remains entirely single phase face-centered cubic (FCC) crystal structure. We found that these materials canmore » be cold rolled and recrystallized to produce a microstructure with equiaxed grains. Both strain hardening rate and strength are enhanced while high uniform elongations to fracture (~70% at 77 K and ~40% at 293 K) are still maintained. The increased strain hardening and strength could be caused by the promptness of deformation twinning in C-containing high entropy alloys.« less

  20. Synthesis and electrochemical performance of high-capacity 0.34Li{sub 2}MnO{sub 3}0.66LiMn{sub 0.63}Ni{sub 0.24}Co{sub 0.13}O{sub 2} cathode materials using a CouetteTaylor reactor

    SciTech Connect (OSTI)

    Choi, Mansoo; Kim, Hyun-Soo; Kim, Jik-Soo; Park, Suk-Joon; Lee, Young Moo; Jin, Bong-Soo

    2014-10-15

    Highlights: The cathode material synthesized by co-precipitation using a CouetteTaylor reactor. The first and second discharge capacities were measured to be 311 and 307 mA h g{sup ?1}. The material has an excellent rate capability. - Abstract: The 0.34Li{sub 2}MnO{sub 3}0.66LiMn{sub 0.63}Ni{sub 0.24}Co{sub 0.13}O{sub 2} cathode material for the Li-ion battery is synthesized by co-precipitation using a CouetteTaylor reactor. Particle size analysis (PSA) and a field emission-scanning electron microscopy (FE-SEM) images show that the obtained precursor and cathode material exhibit a narrow particle size distribution and spherical shape. The structure and composition of the 0.34Li{sub 2}MnO{sub 3}0.66LiMn{sub 0.63}Ni{sub 0.24}Co{sub 0.13}O{sub 2} are confirmed by X-ray diffraction (XRD) and inductively coupled plasma atomic emission spectroscopy (ICP-AES). The first and second discharge capacities of 0.34Li{sub 2}MnO{sub 3}0.66LiMn{sub 0.63}Ni{sub 0.24}Co{sub 0.13}O{sub 2} are measured to be 311 and 307 mA h g{sup ?1}, respectively. The material also has an excellent rate capability (250 and 180 mA h g{sup ?1} at 1 C and 5 C, respectively). In the rate capability test at 60 C, 0.34Li{sub 2}MnO{sub 3}0.66LiMn{sub 0.63}Ni{sub 0.24}Co{sub 0.13}O{sub 2} has a higher capacity of over 210 mA h g{sup ?1} in the range 0.110 C. In the cyclic performance test, the capacity retention at high temperature is over 85% after 50 cycles, which is similar to that at room temperature. The 0.34Li{sub 2}MnO{sub 3}0.66LiMn{sub 0.63}Ni{sub 0.24}Co{sub 0.13}O{sub 2} is therefore a high-capacity material with potential for use as an electrode in Li-ion batteries.

  1. Direct observation of the structural and electronic changes of Li{sub 2}MnO{sub 3} during electron irradiation

    SciTech Connect (OSTI)

    Phillips, Patrick J.; Klie, Robert F. [Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60607 (United States); Iddir, Hakim [Materials Science Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439 (United States); Abraham, Daniel P. [Argonne National Laboratory, Chemical Sciences and Engineering, 9700 S. Cass Avenue, Argonne, Illinois 60439 (United States)

    2014-09-15

    This study focuses on the effects of electron beam induced irradiation to the layered oxide Li{sub 2}MnO{sub 3}. Aberration-corrected scanning transmission electron microscopy and electron energy loss spectroscopy are used to characterize structural and electronic transitions in the material during irradiation, with a focus on changes in Mn valence and O content. This truly in situ irradiation allows for specific particle tracking, dose quantification, and real-time observation, while demonstrating many parallels to the oxide's structure evolution observed during electrochemical cycling. Furthermore, it is demonstrated that typical imaging conditions are not severe enough to induce damage to the pristine oxide.

  2. Magnetic hardening of Ce1+xFe11-yCoyTi with ThMn12 structure by melt

    Office of Scientific and Technical Information (OSTI)

    spinning (Journal Article) | SciTech Connect hardening of Ce1+xFe11-yCoyTi with ThMn12 structure by melt spinning Citation Details In-Document Search Title: Magnetic hardening of Ce1+xFe11-yCoyTi with ThMn12 structure by melt spinning A recent study on the intrinsic magnetic properties of CeFe11-yCoyTi has revealed that substituting one Co for Fe retains the favorable magnetocrystalline anisotropy Ha found in the ternary Fe end member, while enhancing the Curie temperature Tc and saturation

  3. Spintronic properties of Li1.5Mn0.5Z (Z=As, Sb) compounds in the Cu2Sb

    Office of Scientific and Technical Information (OSTI)

    structure (Journal Article) | DOE PAGES Publisher's Accepted Manuscript: Spintronic properties of Li1.5Mn0.5Z (Z=As, Sb) compounds in the Cu2Sb structure This content will become publicly available on January 26, 2017 « Prev Next » Title: Spintronic properties of Li1.5Mn0.5Z (Z=As, Sb) compounds in the Cu2Sb structure Authors: Damewood, L. ; Fong, C. Y. ; Klein, B. M. ; Yang, L. H. ; Felser, C. Publication Date: 2015-03-01 OSTI Identifier: 1249897 Grant/Contract Number: AC52-07NA27344

  4. Spintronic properties of Li1.5Mn0.5Z (Z=As, Sb) compounds in the Cu2Sb

    Office of Scientific and Technical Information (OSTI)

    structure (Journal Article) | SciTech Connect Spintronic properties of Li1.5Mn0.5Z (Z=As, Sb) compounds in the Cu2Sb structure Citation Details In-Document Search This content will become publicly available on January 26, 2017 Title: Spintronic properties of Li1.5Mn0.5Z (Z=As, Sb) compounds in the Cu2Sb structure Authors: Damewood, L. ; Fong, C. Y. ; Klein, B. M. ; Yang, L. H. ; Felser, C. Publication Date: 2015-03-01 OSTI Identifier: 1249897 Grant/Contract Number: AC52-07NA27344 Type:

  5. Direct evidence on magnetic-field-induced phase transition in a NiCoMnIn ferromagnetic shape memory alloy under a stress field.

    SciTech Connect (OSTI)

    Wang, Y. D.; Ren, Y.; Huang, E. W.; Nie, Z. H.; Wang, G.; Liu, Y. D.; Deng, J. N.; Zuo, L.; Choo, H.; Liaw, P .K.; Brown, D. E.; Univ. of Tennessee; Northeastern Univ.; Northern Illinois Univ.

    2007-01-01

    The magnetoelasticity and magnetoplasticity behaviors of a Ni-Co-Mn-In ferromagnetic shape memory alloy (FSMA) induced by the reverse phase transformation interplayed under multiple (temperature, magnetic, and stress) fields were captured directly by high-energy synchrotron x-ray diffraction technique. The experiments showed the direct experimental evidence of that a stress ({approx}50 MPa) applied to this material made a complete recovery of the original orientations of the martensite variants, showing a full shape memory effect. This finding offers the in-depth understanding the fundamental properties and applications of the Ni-Co-Mn-In FSMA with the magnetic-field-induced reverse transformation.

  6. Direct evidence on magnetic-field-induced phase transition in a NiCoMnIn ferromagnetic shape memory alloy under a stress field

    SciTech Connect (OSTI)

    Wang, Y. D.; Ren Yang; Huang, E. W.; Nie, Z. H.; Wang, G.; Liu, Y. D.; Deng, J. N.; Zuo, L.; Choo, H.; Liaw, P. K.; Brown, D. E.

    2007-03-05

    The magnetoelasticity and magnetoplasticity behaviors of a Ni-Co-Mn-In ferromagnetic shape memory alloy (FSMA) induced by the reverse phase transformation interplayed under multiple (temperature, magnetic, and stress) fields were captured directly by high-energy synchrotron x-ray diffraction technique. The experiments showed the direct experimental evidence of that a stress ({approx}50 MPa) applied to this material made a complete recovery of the original orientations of the martensite variants, showing a full shape memory effect. This finding offers the in-depth understanding the fundamental properties and applications of the Ni-Co-Mn-In FSMA with the magnetic-field-induced reverse transformation.

  7. Thermal Variation of Ce Valence in Mixed ValenceKondo Lattice Systems CeT2(Si1-xGex)2 with T= Mn and Ni

    SciTech Connect (OSTI)

    Liang,G.; Croft, M.

    2008-01-01

    The results on the thermal variation of Ce L3-valence in CeT2(Si1-xGex)2 series with 0{le}x{le}1 and T=Mn and Ni are reported. It is observed that for both series, the Ce valence increases with decreasing temperature and has little thermal variation for samples in the nearly trivalent regime. The magnitude of this thermal variation in the T=Mn series is much greater than in the T=Ni series. The results are explained by the degenerate Anderson model and correlated with the specific heat data.

  8. Carbon Dioxide, Hydrographic, and Chemical Data Obtained During the Nine R/V Korr Cruises Comprising the Indian Ocean CO2Survey (WOCE Sections I8SI9S, I9N, I8NI5E, I3, I5WI4, I7N, I1, I10, and I2; December 1, 1994-January 19, 1996)

    SciTech Connect (OSTI)

    Kozyr, A.V.

    2003-09-15

    This document describes the procedures and methods used to measure total carbon dioxide (TCO{sub 2}) and total alkalinity (TALK) at hydrographic stations taken during the R/V Knorr Indian Ocean cruises (Sections I8SI9S, I9N, I8NI5E, I3, I5WI4, I7N, I1, I10, and I2) in 1994-1996. The measurements were conducted as part of the World Ocean Circulation Experiment (WOCE). The expedition began in Fremantle, Australia, on December 1, 1994, and ended in Mombasa, Kenya, on January 22, 1996. During the nine cruises, 12 WOCE sections were occupied. Total carbon dioxide was extracted from water samples and measured using single-operator multiparameter metabolic analyzers (SOMMAs) coupled to coulometers. The overall precision and accuracy of the analyses was {+-} 1.20 {micro}mol/kg. The second carbonate system parameter, TALK, was determined by potentiometric titration. The precision of the measurements determined from 962 analyses of certified reference material was {+-} 4.2 {micro}mol/kg (REFERENCE). This work was supported by grants from the National Science Foundation, the U. S. Department of Energy, and the National Oceanographic and Atmospheric Administration. The R/V Knorr Indian Ocean data set is available as a numeric data package (NDP) from the Carbon Dioxide Information Analysis Center (CDIAC). The NDP consists of 18 oceanographic data files, two FORTRAN 77 data retrieval routine files, a readme file, and this printed documentation, which describes the contents and format of all files as well as the procedures and methods used to obtain the data. Instructions for accessing the data are provided.

  9. Alamo, TX Natural Gas Pipeline Exports to Mexico (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    8,101 6,852 6,008 5,844 5,840 4,837 2015 3,440 3,990 6,547 6,431 7,980 6,896 7,411 5,451 5,292 6,185 4,875 4,771 2016 7,203 5,595 - No Data Reported; -- Not Applicable; NA ...

  10. Clint, TX Natural Gas Pipeline Exports to Mexico (Dollars per...

    U.S. Energy Information Administration (EIA) Indexed Site

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 4.51 4.57 4.11 4.50 4.51 4.73 4.68 4.57 4.21 3.89 3.71 3.63 2012 3.30 2.93 2.62 2.34 2.57 2.82 3.13 3.23 3.07 3.53 3.83 ...

  11. Penitas, TX Natural Gas Pipeline Exports to Mexico (Dollars per...

    U.S. Energy Information Administration (EIA) Indexed Site

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 4.43 4.15 3.95 4.32 4.37 4.58 4.44 4.38 3.88 3.64 3.10

  12. Alamo, TX Natural Gas Pipeline Exports to Mexico (Dollars per...

    U.S. Energy Information Administration (EIA) Indexed Site

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 4.37 4.38 3.92 4.24 4.36 4.46 4.46 4.29 3.88 3.67 3.40 3.31 2012 3.11 2.64 2.28 2.09 2.41 2.48 2.90 3.08 2.80 3.26 3.53 ...

  13. Eagle Pass, TX Natural Gas Pipeline Exports to Mexico (Dollars...

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.52 2.79 2.24 2.35 2000's 3.91 4.45 3.44 5.34 5.95 7.49 6.73 6.72 9.00 4.47 2010's 5.13 4.57 ...

  14. Romas, TX Natural Gas Pipeline Exports (Price) Mexico (Dollars...

    U.S. Energy Information Administration (EIA) Indexed Site

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 4.54 4.33 3.95 4.33 4.42 4.49 4.47 4.44 3.92 3.66 3.24 3.30 2012 2.81 2.64 2.35 2.09 2.46 2.63 2.93 3.05 2.81 3.23 3.49 ...

  15. Alamo, TX Natural Gas Pipeline Exports to Mexico (Dollars per...

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's NA NA 2000's 4.49 4.12 3.35 5.36 5.97 7.17 6.62 7.11 8.40 3.95 2010's 4.50 4.10 2.86 3.81 4.63 ...

  16. Clint, TX Natural Gas Pipeline Exports to Mexico (Dollars per...

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.24 1.99 2.22 2000's 3.95 4.28 3.16 5.50 5.91 8.01 6.42 6.37 7.83 3.78 2010's 4.61 4.29 3.08 ...

  17. Galvan Ranch, TX Natural Gas Pipeline Imports From Mexico (Dollars...

    U.S. Energy Information Administration (EIA) Indexed Site

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 3.27 3.34 2.85 3.28 3.41 3.38 3.44 3.42 2.94 2.82 2.55 2.41 2012 2.17 1.80 1.56 1.27 1.15 1.52 1.86 2.09 1.76 2.09 2.80 ...

  18. Penitas, TX Natural Gas Pipeline Exports to Mexico (Dollars per...

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.05 2.62 2.09 NA 2000's NA NA 3.27 6.53 5.71 -- -- -- 8.41 4.37 2010's 4.94 4.19 -- -- --

  19. Romas, TX Natural Gas Pipeline Exports (Price) Mexico (Dollars...

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's NA 2000's NA NA NA 5.18 5.84 7.29 6.75 6.93 8.58 3.91 2010's 4.55 4.14 2.86 3.80 4.62 2.79

  20. Galvan Ranch, TX Natural Gas Pipeline Imports From Mexico (Dollars...

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- 2.69 2010's 3.52 3.12 1.87 2.66 3.45 1.71