National Library of Energy BETA

Sample records for two-phase nitrogen oxide

  1. ARM - Oxides of Nitrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska OutreachCalendar NSA Related LinksOxides of Nitrogen Outreach Home

  2. Nitrogen oxide delivery systems for biological media

    E-Print Network [OSTI]

    Skinn, Brian Thomas

    2012-01-01

    Elevated levels of nitric oxide (NO) in vivo are associated with a variety of cellular modifications thought to be mutagenic or carcinogenic. These processes are likely mediated by reactive nitrogen species (RNS) such as ...

  3. Nitrogen oxides storage catalysts containing cobalt

    DOE Patents [OSTI]

    Lauterbach, Jochen (Newark, DE); Snively, Christopher M. (Clarks Summit, PA); Vijay, Rohit (Annandale, NJ); Hendershot, Reed (Breinigsville, PA); Feist, Ben (Newark, DE)

    2010-10-12

    Nitrogen oxides (NO.sub.x) storage catalysts comprising cobalt and barium with a lean NO.sub.x storage ratio of 1.3 or greater. The NO.sub.x storage catalysts can be used to reduce NO.sub.x emissions from diesel or gas combustion engines by contacting the catalysts with the exhaust gas from the engines. The NO.sub.x storage catalysts can be one of the active components of a catalytic converter, which is used to treat exhaust gas from such engines.

  4. Nitrogen oxides emission trends in Monthly emission estimates of nitrogen oxides from space provide

    E-Print Network [OSTI]

    Haak, Hein

    Chapter 5 Nitrogen oxides emission trends in East Asia Abstract Monthly emission estimates present first results of a new emission estimation algorithm, specifically designed to use daily satellite observations of column concentrations for fast updates of emission estimates of short-lived atmospheric

  5. Method For Selective Catalytic Reduction Of Nitrogen Oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

    2005-02-15

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  6. Method for selective catalytic reduction of nitrogen oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

    2005-02-15

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  7. Reducing Nitrogen Oxide Emissions: 1996 Compliance with Title IV Limits

    Reports and Publications (EIA)

    1998-01-01

    The purpose of this article is to summarize the existing federal nitrogen oxide (Nox) regulations and the 1996 performance of the 239 Title IV generating units. It also reviews the basics of low-Nox burner technology and presents cost and performance data for retrofits at Title IV units.

  8. Nitrogen oxidizing in modeling of diesel engine operation

    SciTech Connect (OSTI)

    Kulakov, V.; Merker, G.

    1995-12-31

    A computer model of diesel engine operation based on the interconnected calculation of diesel fuel spray and the processes in the combustion chamber is extended for the calculation of Nitrogen oxidizing. A number of chemical reactions with O{sub 2}, O, N{sub 2}, N, NO, OH, H, H{sub 2} are included in the model.

  9. Introduction The reduction of nitrogen oxide emissions is

    E-Print Network [OSTI]

    Sandoghdar, Vahid

    is attained in a post-catalyst homogeneous combustion zone.This process leads to substantial reduction of NOxIntroduction The reduction of nitrogen oxide emissions is of great importance in practical emissions (typically NOx is produced exclusively from the gaseous (homogeneous) reaction path

  10. Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Robust Nitrogen OxideAmmonia Sensors for Vehicle On-board Emissions Control Robust Nitrogen OxideAmmonia Sensors for Vehicle On-board Emissions Control 2012 DOE Hydrogen and Fuel...

  11. Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

    DOE Patents [OSTI]

    Walker, Richard J. (Bethel Park, PA)

    1986-01-01

    A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

  12. Nitrogen oxide abatement by distributed fuel addition

    SciTech Connect (OSTI)

    Wendt, J.O.L.; Mereb, J.B.

    1991-09-20

    Reburning is examined as a means of NO{sub x} destruction in a 17 kW down-fired pulverized coal combustor. In reburning, a secondary fuel is introduced downstream of the primary flame to produce a reducing zone, favorable to NO destruction, and air is introduced further downstream to complete the combustion. Emphasis is on natural gas reburning and a bituminous coal primary flame. A parametric examination of reburning employing a statistical experimental design, is conducted, complemented by detailed experiments. Mechanisms governing the inter-conversion of nitrogenous species in the fuel rich reburn zone is explored. The effect of reburning on N{sub 2}O emissions, the effect of primary flame mode (premixed and diffusion) and the effect of distributing the reburning fuel, are also investigated.

  13. Nitrogen doped zinc oxide thin film

    SciTech Connect (OSTI)

    Li, Sonny X.

    2003-12-15

    To summarize, polycrystalline ZnO thin films were grown by reactive sputtering. Nitrogen was introduced into the films by reactive sputtering in an NO{sub 2} plasma or by N{sup +} implantation. All ZnO films grown show n-type conductivity. In unintentionally doped ZnO films, the n-type conductivities are attributed to Zn{sub i}, a native shallow donor. In NO{sub 2}-grown ZnO films, the n-type conductivity is attributed to (N{sub 2}){sub O}, a shallow double donor. In NO{sub 2}-grown ZnO films, 0.3 atomic % nitrogen was found to exist in the form of N{sub 2}O and N{sub 2}. Upon annealing, N{sub 2}O decomposes into N{sub 2} and O{sub 2}. In furnace-annealed samples N{sub 2} redistributes diffusively and forms gaseous N{sub 2} bubbles in the films. Unintentionally doped ZnO films were grown at different oxygen partial pressures. Zni was found to form even at oxygen-rich condition and led to n-type conductivity. N{sup +} implantation into unintentionally doped ZnO film deteriorates the crystallinity and optical properties and leads to higher electron concentration. The free electrons in the implanted films are attributed to the defects introduced by implantation and formation of (N{sub 2}){sub O} and Zni. Although today there is still no reliable means to produce good quality, stable p-type ZnO material, ZnO remains an attractive material with potential for high performance short wavelength optoelectronic devices. One may argue that gallium nitride was in a similar situation a decade ago. Although we did not obtain any p-type conductivity, we hope our research will provide a valuable reference to the literature.

  14. Biofilter for removal of nitrogen oxides from contaminated gases under aerobic conditions

    DOE Patents [OSTI]

    Apel, William A. (Idaho Falls, ID)

    1998-01-01

    A biofilter for reducing concentrations of gaseous nitrogen oxides in a polluted gas comprises a porous organic filter bed medium disposed in a housing, the filter bed medium including a mixed culture of naturally occurring denitrifying bacteria for converting the nitrogen oxides to nitrogen gas, carbon dioxide, and water. A method of reducing concentrations of nitrogen oxides in polluted gas comprises conducting the polluted gas through the biofilter so that the denitrifying bacteria can degrade the nitrogen oxides. A preferred filter medium is wood compost, however composts of other organic materials are functional. Regulation of pH, moisture content, exogenous carbon sources, and temperature are described.

  15. Biofilter for removal of nitrogen oxides from contaminated gases under aerobic conditions

    DOE Patents [OSTI]

    Apel, W.A.

    1998-08-18

    A biofilter is described for reducing concentrations of gaseous nitrogen oxides in a polluted gas comprises a porous organic filter bed medium disposed in a housing, the filter bed medium including a mixed culture of naturally occurring denitrifying bacteria for converting the nitrogen oxides to nitrogen gas, carbon dioxide, and water. A method is described of reducing concentrations of nitrogen oxides in polluted gas comprises conducting the polluted gas through the biofilter so that the denitrifying bacteria can degrade the nitrogen oxides. A preferred filter medium is wood compost, however composts of other organic materials are functional. Regulation of pH, moisture content, exogenous carbon sources, and temperature are described. 6 figs.

  16. Method for reducing nitrogen oxides in combustion effluents

    DOE Patents [OSTI]

    Zauderer, Bert (Merion Station, PA)

    2000-01-01

    Method for reducing nitrogen oxides (NO.sub.x) in the gas stream from the combustion of fossil fuels is disclosed. In a narrow gas temperature zone, NO.sub.x is converted to nitrogen by reaction with urea or ammonia with negligible remaining ammonia and other reaction pollutants. Specially designed injectors are used to introduce air atomized water droplets containing dissolved urea or ammonia into the gaseous combustion products in a manner that widely disperses the droplets exclusively in the optimum reaction temperature zone. The injector operates in a manner that forms droplet of a size that results in their vaporization exclusively in this optimum NO.sub.x -urea/ammonia reaction temperature zone. Also disclosed is a design of a system to effectively accomplish this injection.

  17. Method for combined removal of mercury and nitrogen oxides from off-gas streams

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

    2006-10-10

    A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

  18. The effects of nitrogen oxides on cytochrome P-450 mediated mixed-function oxidations in mammalian lung 

    E-Print Network [OSTI]

    Tucker, Leo Dean

    1979-01-01

    THE EFFECTS OF NITROGEN OXIDES ON CYTOCHROME P-450 MEDIATED MIXED-FUNCTION OXIDATIONS IN ~IAN IUNG A Thesis by LEO DEAN TUCKER, II Submitted to the Graduate College of Texas AAM University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1979 Major Subject: Biology THE EFFECTS OF NITROGEN OXIDES ON CYTOCHROME P-450 MEDIATED MIXED-FUNCTION OXIDATIONS IN MAMMALIAN LUNG A Thesis by LEO DEAN TUCKER, II Approved as to style and content by...

  19. Technological modifications in the nitrogen oxides tradable permit program

    SciTech Connect (OSTI)

    Linn, J.

    2008-07-01

    Tradable permit programs allow firms greater flexibility in reducing emissions than command-and-control regulations and encourage firms to use low cost abatement options, including small-scale modifications to capital equipment. This paper shows that firms have extensively modified capital equipment in the Nitrogen Oxides Budget Trading Program, which covers power plants in the eastern United States. The empirical strategy uses geographic and temporal features of the program to estimate counterfactual emissions, finding that modifications have reduced emission rates by approximately 10-15 percent. The modifications would not have occurred under command-and-control regulation and have reduced regulatory costs.

  20. Two-phase flow studies

    SciTech Connect (OSTI)

    Hanold, R.J.

    1983-12-01

    The two-phase flow program is directed at understanding the hydrodynamics of two-phase flows. The two-phase flow regime is characterized by a series of flow patterns that are designated as bubble, slug, churn, and annular flow. Churn flow has received very little scientific attention. This lack of attention cannot be justified because calculations predict that the churn flow pattern will exist over a substantial portion of the two-phase flow zone in producing geothermal wells. The University of Houston is experimentally investigating the dynamics of churn flow and is measuring the holdup over the full range of flow space for which churn flow exists. These experiments are being conducted in an air/water vertical two-phase flow loop. Brown University has constructed and is operating a unique two-phase flow research facility specifically designed to address flow problems of relevance to the geothermal industry. An important feature of the facility is that it is dedicated to two-phase flow of a single substance (including evaporation and condensation) as opposed to the case of a two-component two-phase flow. This facility can be operated with horizontal or vertical test sections of constant diameter or with step changes in diameter to simulate a geothermal well profile.

  1. Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia

    DOE Patents [OSTI]

    Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

    1980-01-01

    Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

  2. Catalyst and method for reduction of nitrogen oxides

    DOE Patents [OSTI]

    Ott, Kevin C. (Los Alamos, NM)

    2008-05-27

    A Selective Catalytic Reduction (SCR) catalyst was prepared by slurry coating ZSM-5 zeolite onto a cordierite monolith, then subliming an iron salt onto the zeolite, calcining the monolith, and then dipping the monolith either into an aqueous solution of manganese nitrate and cerium nitrate and then calcining, or by similar treatment with separate solutions of manganese nitrate and cerium nitrate. The supported catalyst containing iron, manganese, and cerium showed 80 percent conversion at 113 degrees Celsius of a feed gas containing nitrogen oxides having 4 parts NO to one part NO.sub.2, about one equivalent ammonia, and excess oxygen; conversion improved to 94 percent at 147 degrees Celsius. N.sub.2O was not detected (detection limit: 0.6 percent N.sub.2O).

  3. Catalyst and method for reduction of nitrogen oxides

    DOE Patents [OSTI]

    Ott, Kevin C. (Los Alamos, NM)

    2008-08-19

    A Selective Catalytic Reduction (SCR) catalyst was prepared by slurry coating ZSM-5 zeolite onto a cordierite monolith, then subliming an iron salt onto the zeolite, calcining the monolith, and then dipping the monolith either into an aqueous solution of manganese nitrate and cerium nitrate and then calcining, or by similar treatment with separate solutions of manganese nitrate and cerium nitrate. The supported catalyst containing iron, manganese, and cerium showed 80 percent conversion at 113 degrees Celsius of a feed gas containing nitrogen oxides having 4 parts NO to one part NO.sub.2, about one equivalent ammonia, and excess oxygen; conversion improved to 94 percent at 147 degrees Celsius. N.sub.2O was not detected (detection limit: 0.6 percent N.sub.2O).

  4. Reduction of Nitrogen Oxide Emissions for lean Burn Engine Technology

    SciTech Connect (OSTI)

    McGill, R.N.

    1998-08-04

    Lean-burn engines offer the potential for significant fuel economy improvements in cars and trucks, perhaps the next great breakthrough in automotive technology that will enable greater savings in imported petroleum. The development of lean-burn engines, however, has been an elusive goal among automakers because of the emissions challenges associated with lead-burn engine technology. Presently, cars operate with sophisticated emissions control systems that require the engine's air-fuel ratio to be carefully controlled around the stoichiometric point (chemically correct mixture). Catalysts in these systems are called "three-way" catalysts because they can reduce hydrocarbon, carbon monoxide, and nitrogen oxide emissions simultaneously, but only because of the tight control of the air-fuel ratio. The purpose of this cooperative effort is to develop advanced catalyst systems, materials, and necessary engine control algorithms for reducing NOX emissions in oxygen-rich automotive exhaust (as with lean-burn engine technology) to meet current and near-future mandated Clean Air Act standards. These developments will represent a breakthrough in both emission control technology and automobile efficiency. The total project is a joint effort among five national laboratories, together with US CAR. The role of Lockheed-Martin Energy Systems in the total project is two fold: characterization of catalyst performance through laboratory evaluations from bench-scale flow reactor tests to engine laboratory tests of full-scale prototype catalysts, and microstructural characterization of catalyst material before and after test stand and/or engine testing.

  5. Nitric OxideTriggered Remodeling of Chloroplast Bioenergetics and Thylakoid Proteins upon Nitrogen

    E-Print Network [OSTI]

    Nitric Oxide­Triggered Remodeling of Chloroplast Bioenergetics and Thylakoid Proteins upon Nitrogen droplets, but the accompanying changes in bioenergetics have been little studied so far. Here, we report

  6. Air Pollution Control Regulations: No.27- Control of Nitrogen Oxide Emissions (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations apply to stationary sources with the potential to emit 50 tons of nitrogen oxides (NOx) per year from all pollutant-emitting equipment or activities. The regulations describe...

  7. Nitrogen oxides emission control through reburning with biomass in coal-fired power plants 

    E-Print Network [OSTI]

    Arumugam, Senthilvasan

    2005-02-17

    Oxides of nitrogen from coal-fired power stations are considered to be major pollutants, and there is increasing concern for regulating air quality and offsetting the emissions generated from the use of energy. Reburning ...

  8. Zevenhoven & Kilpinen NITROGEN 18.1.2004 4-35 4.11 Chemistry of nitrogen oxides at atmospheric fluidized bed

    E-Print Network [OSTI]

    Zevenhoven, Ron

    oxide by air staging, and reduction of nitric oxide with char. In circulating fluidized bed combustion reactions between gas and particles become important, e.g., reduction of nitric oxide with char, which or noncatalytic. For example, the reduction of nitric oxide with char #12;Zevenhoven & Kilpinen NITROGEN 18

  9. Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite

    E-Print Network [OSTI]

    Rochelle, Gary T.

    oxidation in limestone slurry scrubbing. Introduction Limestone (CaCO3) slurry scrubbing and lime (Ca

  10. Process for nitrogen oxides reduction with minimization of the production of other pollutants

    SciTech Connect (OSTI)

    Epperly, W.R.; O'Leary, J.H.; Sullivan, J.C.; Sprague, B.N.

    1990-02-20

    This patent describes a process for reducing the concentration of nitrogen oxides in an effluent while minimizing the production of other pollutants. It comprises: determining the condition of the effluent which exists at a location for introduction of a treatment agent; effecting a treatment regimen which comprises introducing a treatment agent comprising an ammonium salt of an organic acid having a carbon to nitrogen ratio of greater than 1:1 into the effluent to reduce the nitrogen oxides concentration in the effluent under the determined effluent conditions while minimizing the production of other pollutants; monitoring the condition of the effluent until a significant alteration in the condition of the effluent is observed; and adjusting the treatment regimen by varying at least one of the following parameters: dilution and introduction rate of the hydrocarbon treatment agent; composition of the hydrocarbon treatment agent; and relative presence of the components of the hydrocarbon treatment agent.

  11. Does the location of aircraft nitrogen oxide emissions affect their climate impact?

    E-Print Network [OSTI]

    Stevenson, David

    integrations: a base case, then variants with extra aircraft nitrogen oxide (NOx) emissions added to specific NOx emissions. NOx promotes tropospheric ozone (O3) production, but also stimulates methane (CH4 how important the emission location is in influencing the impact of aviation NOx on O3 and CH4. 2

  12. KINETICS, CATALYSIS, AND REACTION ENGINEERING Nonthermal Plasma Reactions of Dilute Nitrogen Oxide Mixtures

    E-Print Network [OSTI]

    Yeung, Man-Chung

    -type rate model, is found to capture the effect of power input, NOx composition, and residence time. An N for the conversion of nitrogen oxides,1,2,4-10 sulfur dioxide,11 and volatile organic car- bons.12 Despite its a mathematical model that captures transport and reac- tion rates. Such a model is needed to develop new

  13. Nitrogen oxide abatement by distributed fuel addition. Final report

    SciTech Connect (OSTI)

    Wendt, J.O.L.; Mereb, J.B.

    1991-09-20

    Reburning is examined as a means of NO{sub x} destruction in a 17 kW down-fired pulverized coal combustor. In reburning, a secondary fuel is introduced downstream of the primary flame to produce a reducing zone, favorable to NO destruction, and air is introduced further downstream to complete the combustion. Emphasis is on natural gas reburning and a bituminous coal primary flame. A parametric examination of reburning employing a statistical experimental design, is conducted, complemented by detailed experiments. Mechanisms governing the inter-conversion of nitrogenous species in the fuel rich reburn zone is explored. The effect of reburning on N{sub 2}O emissions, the effect of primary flame mode (premixed and diffusion) and the effect of distributing the reburning fuel, are also investigated.

  14. Process for nitrogen oxides reduction and minimization of the production of other pollutants

    SciTech Connect (OSTI)

    Epperly, W.R.; O'Leary, J.H.; Sullivan, J.C.

    1988-10-25

    This patent describes a process for reducing the concentration of nitrogen oxides in an effluent from the combustion of a carbonaceous fuel while minimizing the production of other pollutants. The process consists of: a. determining the condition of the effluent which exists at a location for introduction of a treatment agent; b. effecting a treatment regimen which comprises introducing a treatment agent into the effluent to treat the effluent to reduce the nitrogen oxides concentration in the effluent under the determined effluent conditions while minimizing the production of other pollutants; c. monitoring the condition of the effluent until a significant alteration in the condition of the effluent is observed; d. adjusting the treatment regimen by varying at least one of the following parameters: (i) dilution and introduction rate of the treatment agent; (ii) components of the treatment agent; and (iii) relative presence of treatment agent components, to effect an adjusted treatment regimen, wherein the adjusted treatment regimen reduces the nitrogen oxides concentration in the effluent under the altered effluent condition while minimizing the production of other pollutants.

  15. Process for nitrogen oxides reduction with minimization of the production of other pollutants

    SciTech Connect (OSTI)

    Epperly, W.R.; O'Leary, J.H.; Sullivan, J.C.; Sprague, B.N.

    1989-10-31

    This patent describes a process for reducing the concentration of nitrogen oxides in an effluent which is at a temperature below about 1450 {degrees}F while minimizing the production of other pollutants. The process comprising: determining the condition of the effluent which exists at a location for introduction of a treatment agent; effecting a treatment regimen which comprises introducing a treatment agent comprising a hydrocarbon into the effluent to reduce the nitrogen oxides concentration in the effluent under the determined effluent conditions while minimizing the production of other pollutants; monitoring the condition of the effluent until a significant alteration in the condition of the effluent is observed; adjusting the treatment regimen by varying at least one of the following parameters: dilution and introduction rate of the hydrocarbon treatment agent; composition of the hydrocarbon treatment agent; and relative presence of the components of the hydrocarbon treatment agent, to effect an adjusted treatment regimen. Wherein the adjusted treatment regimen operates under conditions effective to reduce the nitrogen oxides concentration in the effluent under the altered effluent conditions.

  16. Evaluation of Corona Reactors of Several Geometries for a Plasma Assisted Nitrogen Oxide Emission Reduction Device

    SciTech Connect (OSTI)

    Herling, Darrell R.; Smith, Monty R.; Hemingway, Mark D.; Goulette, David; Silvis, Thomas W.

    2000-08-09

    Proposed vehicle emissions regulations for the near future have prompted automotive manufactures and component suppliers to focus heavily on developing more efficient exhaust aftertreatment devices to lower emissions from spark and compression ignition engines. One of the primary pollutants from lean-burn engines, especially from diesels, are oxides of nitrogen (NOx). Current three-way catalytic converters will not have adequate performance to meet future emission reduction requirements. Therefore, there is a need for researchers and engineers to develop efficient exhaust aftertreatment devices that will reduce NOx emissions from lean-burn engines. These devices must have very high conversion of NOx gases, be unaffected by exhaust-gas impurity such as sulfur, and have minimal impact on vehicle operations and fuel economy. An effective technology for NOx control that is currently receiving a lot of attention is a non-thermal plasma system. This system is comprised of a two-stage corona generation device (plasma reactor) and reduction catalyst that reduces nitric oxide and nitrogen dioxide emissions to nitrogen.

  17. Nitrogen-doped and simultaneously reduced graphene oxide with superior dispersion as electrocatalysts for oxygen reduction reaction

    SciTech Connect (OSTI)

    Lee, Cheol-Ho; Yun, Jin-Mun; Lee, Sungho; Jo, Seong Mu; Yoo, Sung Jong; Cho, Eun Ae; Khil, Myung-Seob; Joh, Han-Ik

    2014-11-15

    Nitrogen doped graphene oxide (Nr-GO) with properties suitable for electrocatalysts is easily synthesized using phenylhydrazine as a reductant at relatively low temperature. The reducing agent removes various oxygen functional groups bonded to graphene oxide and simultaneously dope the nitrogen atoms bonded with phenyl group all over the basal planes and edge sites of the graphene. The Nr-GO exhibits remarkable electrocatalytic activities for oxygen reduction reaction compared to the commercial carbon black and graphene oxide due to the electronic modification of the graphene structure. In addition, Nr-GO shows excellent dispersibility in various solvent due to the dopant molecules.

  18. Combustion process and nitrogen oxides emission of Shenmu coal added with sodium acetate

    SciTech Connect (OSTI)

    Yang Weijuan; Zhou Junhu; Liu Maosheng; Zhou Zhijun; Liu Jianzhong; Cen Kefa

    2007-09-15

    Shenmu bituminous coal with 4% sodium acetate added was used to investigate the characteristics of combustion and nitrogen oxide (NOx) release in a fixed bed reactor heated by a tube furnace. The composition of the flue gas was analyzed to investigate the effects of sodium acetate on the combustion process and NOx emission. The experiments were carried out in a partial reductive atmosphere and a strong oxidative atmosphere. The O{sub 2} valley value in the partial reductive atmosphere was reduced by the added sodium acetate. Sodium acetate accelerated the combustion and shortened the combustion process. The experimental results showed that the emissions of NO, NO{sub 2}, and N{sub 2}O were affected by the reacting atmosphere and the combustion temperature. In the strong oxidative atmosphere, sodium acetate resulted in a slight NOx reduction. In the partial reductive atmosphere, sodium acetate reduced both the peak value of NO concentration and the total NO emission significantly. An over 30% NOx reduction efficiency was achieved at 900{sup o}C in the partial reductive atmosphere, which decreased with the increase in temperature. Sodium acetate was decomposed into hydrocarbon radicals and sodium hydroxide, which can both reduce NOx emissions due to their special reactions with the nitrogen component. 17 refs., 11 figs., 2 tabs.

  19. Material and system for catalytic reduction of nitrogen oxide in an exhaust stream of a combustion process

    DOE Patents [OSTI]

    Gardner, Timothy J. (Albuquerque, NM); Lott, Stephen E. (Edgewood, NM); Lockwood, Steven J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

    1998-01-01

    A catalytic material of activated hydrous metal oxide doped with platinum, palladium, or a combination of these, and optionally containing an alkali or alkaline earth metal, that is effective for NO.sub.X reduction in an oxidizing exhaust stream from a combustion process is disclosed. A device for reduction of nitrogen oxides in an exhaust stream, particularly an automotive exhaust stream, the device having a substrate coated with the activated noble-metal doped hydrous metal oxide of the invention is also provided.

  20. High-surface-area nitrogen-doped reduced graphene oxide for electric double-layer capacitors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Youn, Hee-Chang; Bak, Seong-Min; Kim, Myeong-Seong; Jaye, Cherno; Fischer, Daniel A.; Lee, Chang-Wook; Yang, Xiao-Qing; Roh, Kwang Chul; Kim, Kwang-Bum

    2015-06-08

    A two-step method consisting of solid-state microwave irradiation and heat treatment under NH? gas was used to prepare nitrogen-doped reduced graphene oxide (N-RGO) with a high specific surface area (1007m²g?¹), high electrical conductivity (1532S m?¹), and low oxygen content (1.5 wt%) for electric double-layer capacitor applications. The specific capacitance of N-RGO was 291 Fg?¹ at a current density of 1 A g?¹, and a capacitance of 261 F g?¹ was retained at 50 A g?¹, indicating a very good rate capability. N-RGO also showed excellent cycling stability, preserving 96% of the initial specific capacitance after 100,000 cycles. Near-edge X-ray absorptionmore »fine-structure spectroscopy evidenced the recover of ?-conjugation in the carbon networks with the removal of oxygenated groups and revealed the chemical bonding of the nitrogen atoms in N-RGO. The good electrochemical performance of N-RGO is attributed to its high surface area, high electrical conductivity, and low oxygen content.« less

  1. High-surface-area nitrogen-doped reduced graphene oxide for electric double-layer capacitors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Youn, Hee-Chang [Yonsei Univ., Seoul (Republic of Korea); Bak, Seong-Min [Brookhaven National Lab. (BNL), Upton, NY (United States); Kim, Myeong-Seong [Yonsei Univ., Seoul (Republic of Korea); Jaye, Cherno [National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Fischer, Daniel A. [National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Lee, Chang-Wook [Yonsei Univ., Seoul (Republic of Korea); Yang, Xiao-Qing [Brookhaven National Lab. (BNL), Upton, NY (United States); Roh, Kwang Chul [Korea Inst. of Ceramic Engineering and Technology, Seoul (Republic of Korea); Kim, Kwang-Bum [Yonsei Univ., Seoul (Republic of Korea)

    2015-06-08

    A two-step method consisting of solid-state microwave irradiation and heat treatment under NH? gas was used to prepare nitrogen-doped reduced graphene oxide (N-RGO) with a high specific surface area (1007m²g?¹), high electrical conductivity (1532S m?¹), and low oxygen content (1.5 wt%) for electric double-layer capacitor applications. The specific capacitance of N-RGO was 291 Fg?¹ at a current density of 1 A g?¹, and a capacitance of 261 F g?¹ was retained at 50 A g?¹, indicating a very good rate capability. N-RGO also showed excellent cycling stability, preserving 96% of the initial specific capacitance after 100,000 cycles. Near-edge X-ray absorption fine-structure spectroscopy evidenced the recover of ?-conjugation in the carbon networks with the removal of oxygenated groups and revealed the chemical bonding of the nitrogen atoms in N-RGO. The good electrochemical performance of N-RGO is attributed to its high surface area, high electrical conductivity, and low oxygen content.

  2. Magnetic properties of two-phase superconductors

    E-Print Network [OSTI]

    E. Di Grezia; S. Esposito; G. Salesi

    2007-09-17

    We have recently proposed a theoretical model for superconductors endowed with two distinct superconducting phases, described by two scalar order parameters which condensate at different critical temperatures. On analyzing the magnetic behavior of such systems, we have found some observable differences with respect to the case of ordinary Ginzburg-Landau superconductors. In particular, at low temperature the London penetration length is strongly reduced and the Ginzburg-Landau parameter k becomes a function of temperature. By contrast, in the temperature region between the two phase transitions k is constant and the system is a type-I or a type-II superconductor depending on the ratio between the critical temperatures.

  3. Limited effect of anthropogenic nitrogen oxides on secondary organic aerosol formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.

    2015-12-08

    Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but it can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR (National Center for Atmospheric Research) Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product volatility basis set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. Small differences are found for themore »no-aging VBS and 2-product schemes; large increases in SOA production and the SOA-to-OA ratio are found for the aging scheme. The predicted organic aerosol amounts capture both the magnitude and distribution of US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of 2 compared to aerosol mass spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different regions and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9–5.6, 6.4–12.0 and 0.9–2.8 % for global, southeast US and Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to a limited shift in chemical regime, to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less

  4. Limited effect of anthropogenic nitrogen oxides on Secondary Organic Aerosol formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.

    2015-08-28

    Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product Volatility Basis Set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. The predicted organic aerosol amounts capture both the magnitude and distribution ofmore »US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of two compared to Aerosol Mass Spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different region and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9 to 5.6, 6.4 to 12.0 and 0.9 to 2.8 % for global, the southeast US and the Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less

  5. Parameters affecting nitrogen oxides in a Coal-Fired Flow Facility system

    SciTech Connect (OSTI)

    Lu, Xiaoliang

    1996-03-01

    The unusually high temperature in the primary combustor of the Coal-Fired Magnetohydrodynamics (MHD) power generation system causes much higher nitrogen oxides (NO{sub x}) to be produced than in a conventional coal fired generation system. In order to lower the NO{sub x} concentration to an acceptable level, it is important to know how parameters of the MM power generation system affect the NO{sub x} concentration. This thesis investigates those effects in the Coal-Fired Flow Facility (CFFF) at the University of Tennessee Space Institute under the contract of US Department Of Energy (DOE). With thermodynamic and kinetic computer codes, the theoretical studies were carried out on the parameters of the CFFF system. The results gathered from the computer codes were analyzed and compared with the experimental data collected during the LMF5J test. The thermodynamic and kinetic codes together modeled the NO.{sub x} behavior with reasonable accuracy while some inconsistencies happened at the secondary combustor inlet.

  6. Nitrogen oxides emission control options for coal-fired electric utility boilers

    SciTech Connect (OSTI)

    Ravi K. Srivastava; Robert E. Hall; Sikander Khan; Kevin Culligan; Bruce W. Lani

    2005-09-01

    Recent regulations have required reductions in emissions of nitrogen oxides (NOx) from electric utility boilers. To comply with these regulatory requirements, it is increasingly important to implement state-of-the-art NOx control technologies on coal-fired utility boilers. This paper reviews NOx control options for these boilers. It discusses the established commercial primary and secondary control technologies and examines what is being done to use them more effectively. Furthermore, the paper discusses recent developments in NOx controls. The popular primary control technologies in use in the United States are low-NOx burners and overfire air. Data reflect that average NOx reductions for specific primary controls have ranged from 35% to 63% from 1995 emissions levels. The secondary NOx control technologies applied on U.S. coal-fired utility boilers include reburning, selective noncatalytic reduction (SNCR), and selective catalytic reduction (SCR). Thirty-six U.S. coal-fired utility boilers have installed SNCR, and reported NOx reductions achieved at these applications ranged from 15% to 66%. Recently, SCR has been installed at 150 U.S. coal-fired utility boilers. Data on the performance of 20 SCR systems operating in the United States with low-NOx emissions reflect that in 2003, these units achieved NOx emission rates between 0.04 and 0.07 lb/106 Btu. 106 refs., 6 figs., 6 tabs.

  7. System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly; Rossin, Joseph A

    2014-04-08

    A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

  8. Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2

    SciTech Connect (OSTI)

    Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

    1993-01-04

    Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH[sub 3] as a reductant. Oxidized Green River oil shale heated at 10[degree]C/min in an Ar/O[sub 2]/NO/NH[sub 3] mixture ([approximately]93%/6%/2000 ppM/4000 ppM) with a gas residence time of [approximately]0.6 sec removed NO between 250 and 500[degree]C, with maximum removal of 70% at [approximately]400[degree]C. Under isothermal conditions with the same gas mixture, the maximum NO removal was [approximately]64%. When CO[sub 2] was added to the gas mixture at [approximately]8%, the NO removal dropped to [approximately]50%. However, increasing the gas residence time to [approximately]1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH[sub 3] as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH[sub 3] as the reductant. Parameters calculated for implementing oxidized oil shale for NO[sub x] remediation on the current HRS retort indicate an abatement device is practical to construct.

  9. Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2

    SciTech Connect (OSTI)

    Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

    1993-01-04

    Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as a reductant. Oxidized Green River oil shale heated at 10{degree}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppM/4000 ppM) with a gas residence time of {approximately}0.6 sec removed NO between 250 and 500{degree}C, with maximum removal of 70% at {approximately}400{degree}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH{sub 3} as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant. Parameters calculated for implementing oxidized oil shale for NO{sub x} remediation on the current HRS retort indicate an abatement device is practical to construct.

  10. Nitrogen-doped cuprous oxide as a p-type hole-transporting layer in thin-film solar cells

    E-Print Network [OSTI]

    Nitrogen-doped cuprous oxide as a p-type hole- transporting layer in thin-film solar cells Yun Seog-transparent tunnel junction to a back-contact. We fabricate Cu2O-based heterojunction thin-film solar cells-factor and power conversion efficiency of the solar cells. Cu2O:N thin-films may also be useful in other

  11. Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions

    E-Print Network [OSTI]

    Craig, Michael T. (Michael Timothy)

    2014-01-01

    Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

  12. Implementing a time- and location-differentiated cap-and-trade program : flexible nitrogen oxide abatement from power plants in the eastern United States

    E-Print Network [OSTI]

    Martin, Katherine C

    2007-01-01

    Studies suggest that timing and location of emissions can change the amount of ozone formed from a given amount of nitrogen oxide (NOx) by a factor of five (Mauzerall et al. 2005). Yet existing NOx cap-and-trade programs ...

  13. A cost-effectiveness analysis of alternative ozone control strategies : flexible nitrogen oxide (NOx) abatement from power plants in the eastern United States

    E-Print Network [OSTI]

    Sun, Lin, S.M. Massachusetts Institute of Technology

    2009-01-01

    Ozone formation is a complex, non-linear process that depends on the atmospheric concentrations of its precursors, nitrogen oxide (NOx) and Volatile Organic Compounds (VOC), as well as on temperature and the available ...

  14. TWO-PHASE FLOW TURBINE FOR COGENERATION, GEOTHERMAL,

    E-Print Network [OSTI]

    TWO-PHASE FLOW TURBINE FOR COGENERATION, GEOTHERMAL, SOLAR AND OTHER APPLICATIONS Prepared For REPORT (FAR) TWO-PHASE FLOW TURBINE FOR COGENERATION, GEOTHERMAL, SOLAR AND OTHER APPLICATIONS EISG://www.energy.ca.gov/research/index.html. #12;Page 1 Two-Phase Flow Turbine For Cogeneration, Geothermal, Solar And Other Applications EISG

  15. Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions

    E-Print Network [OSTI]

    Millstein, Dev

    2009-01-01

    2005). Particulate emissions from construction activities.M. S. , (2000b). In-use emissions from heavy- duty dieseland nitrogen dioxide emissions from gasoline- and diesel-

  16. Autoignition in turbulent two-phase flows

    E-Print Network [OSTI]

    Borghesi, Giulio

    2013-01-08

    . Similar concerns about the limited availability and rising price of conventional fuels have encouraged and motivated research on fuel-efficient engines. Meeting these requirements has proven to be an extraor- dinary challenge, and requires a profound... within the bulk gas, leading to air entrainment. As the cold liquid jet is heated by mixing with the hot oxidizer, a thin sheet of air / fuel vapor mixture is formed around the jet’s periphery. Further entrainment of hot air is responsible for start- ing...

  17. Two-Phase Cooling Technology for Power Electronics with Novel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electronics with Novel Coolants Two-Phase Cooling Technology for Power Electronics with Novel Coolants 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program...

  18. Energy stable schemes and numerical simulations of two phase ...

    E-Print Network [OSTI]

    Title: Energy stable schemes and numerical simulations of two phase complex fluids by the phase-field method Abstact: We present an energetic variational ...

  19. Enthalpy and mass flowrate measurements for two-phase geothermal...

    Open Energy Info (EERE)

    Enthalpy and mass flowrate measurements for two-phase geothermal production by Tracer dilution techniques Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  20. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1997-05-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  1. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1996-01-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  2. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  3. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect (OSTI)

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  4. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, Mitchell R. (Troy, NY); Gal, Eli (Lititz, PA)

    1993-01-01

    A process and system for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous The government of the United States of America has rights in this invention pursuant to Contract No. DE-AC21-88MC 23174 awarded by the U.S. Department of Energy.

  5. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, M.R.; Gal, E.

    1993-04-13

    A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

  6. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    LSCo for Solid Oxide Electrolyzer Anodes”, J. Electrochem.gas sensors. Batteries, electrolyzers, and gas sensors allmake a sensor or an electrolyzer. By reading an open circuit

  7. Impact of preindustrial biomass-burning emissions on the oxidation pathways of tropospheric sulfur and nitrogen

    E-Print Network [OSTI]

    Alexander, Becky

    the onset of the Industrial Revolution due to increases in fossil fuel burning emissions [e.g., Lelieveld et-burning events in North America just prior to the Industrial Revolution significantly impacted the oxidation the Industrial Revolution, particularly when using paleo-oxidant data as a reference for model evaluation. INDEX

  8. Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 1

    SciTech Connect (OSTI)

    Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

    1992-06-10

    Oxidized oil shale from the combustor in the LLNL hot recycle solids oil shale retorting process has been studied as a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as areductant. Combusted Green River oil shale heated at 10{degrees}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppm/4000 ppm) with a gas residence time of {approximately}0.6 sec exhibited NO removal between 250 and 500{degrees}C, with maximum removal of 70% at {approximately}400{degrees}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was found to be {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. These results are not based on optimized process conditions, but indicate oxidized (combusted) oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant.

  9. THE TWO-PHASE FRACTIONAL OBSTACLE PROBLEM 1 ...

    E-Print Network [OSTI]

    2012-12-10

    The problem arises in connection with heat flow with control on the boundary. It can also be seen as a non-local analogue of the, by now well studied, two-phase

  10. A WIMP Detector with Two-Phase Liquid Xenon

    E-Print Network [OSTI]

    David B. Cline

    2000-01-13

    We describe the liquid-xenon dark-matter detector program of the UCLA-Torino team. A two-phase detector, ZEPLIN II, for the Boulby Mine is a good match for the current search for WIMP dark matter.

  11. On-farm Assessment of Nitrogen Fertilizer application to corn on Nitrous Oxide Emissions

    E-Print Network [OSTI]

    2009-01-01

    mitigation of greenhouse gas emissions by agriculture. Nutr.1998. Nitrous oxide emission in three years as affected by2008. Soil-surface gas emissions. p.851-861. In: M.R. Carter

  12. Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides

    SciTech Connect (OSTI)

    Akyurtlu, A.; Akyurtlu, J.F.

    1999-03-31

    Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

  13. Flow reactor experiments on the selective non-catalytic removal of nitrogen oxides 

    E-Print Network [OSTI]

    Gentemann, Alexander M.G.

    2001-01-01

    also found. Selective non-catalytic removal of nitric oxide using a water/urea solution was performed in a temperature range between 800 and 1300 K. Different combinations of simulated exhaust gas were tested, which contained various fractions of O?...

  14. Cylinder-averaged histories of nitrogen oxide in a D.I. diesel with simulated turbocharging

    SciTech Connect (OSTI)

    Donahue, R.J.; Borman, G.L.; Bower, G.R.

    1994-10-20

    An experimental study was conducted using the dumping technique (total cylinder sampling) to produce cylinder mass-averaged nitric oxide histories. Data were taken using a four stroke diesel research engine employing a quiescent chamber, high pressure direct ijection fuel system, and simulated turbocharging. Two fuels were used to determine fuel cetane number effects. Two loads were run, one at an equivalence ratio of 0.5 and the other at a ratio of 0.3. The engine speed was held constant at 1500 rpm. Under the turbocharged and retarded timing conditions of this study, nitric oxide was produced up to the point of about 85% mass burned. Two different models were used to simulate the engine mn conditions: the phenomenological Hiroyasu spray-combustion model, and the three dimensional, U.W.-ERO modified KIVA-lI computational fluid dynamic code. Both of the models predicted the correct nitric oxide trend. Although the modified KIVA-lI combustion model using Zeldovich kinetics correctly predicted the shapes of the nitric oxide histories, it did not predict the exhaust concentrations without arbitrary adjustment based on experimental values.

  15. Effect of additives on the reduction of nitrogen oxides using cyanuric acid 

    E-Print Network [OSTI]

    Standridge, Brad Lee

    1994-01-01

    The addition of cyanuric acid to hot exhaust flows has been shown in the past to selectively remove much of the nitric oxide (NO) emitted from combustion sources. Known as the RapreNOx process, this approach to pollution control does not require a...

  16. Adiabatic two-phase frictional pressure drops in microchannels

    SciTech Connect (OSTI)

    Revellin, Remi; Thome, John R. [EPFL, STI ISE LTCM, ME Gl 464, Station 9, CH-1015 Lausanne (Switzerland)

    2007-07-15

    Two-phase pressure drops were measured over a wide range of experimental test conditions in two sizes of microchannels (sight glass tubes 0.509 and 0.790 mm) for two refrigerants (R-134a and R-245fa). Similar to the classic Moody diagram in single-phase flow, three zones were distinguishable when plotting the variation of the two-phase friction factor versus the two-phase Reynolds number: a laminar regime for Re{sub TP} < 2000, a transition regime for 2000 {<=} Re{sub TP} < 8000 and a turbulent regime for Re{sub TP} {>=} 8000. The laminar zone yields a much sharper gradient than in single-phase flow. The transition regime is not predicted well by any of the prediction methods for two-phase frictional pressure drops available in the literature. This is not unexpected since only a few data are available for this region in the literature and most methods ignore this regime, jumping directly from laminar to turbulent flow at Re{sub TP} = 2000. The turbulent zone is best predicted by the Mueller-Steinhagen and Heck correlation. Also, a new homogeneous two-phase frictional pressure drop has been proposed here with a limited range of application. (author)

  17. Transient well testing in two-phase geothermal reservoirs

    SciTech Connect (OSTI)

    Aydelotte, S.R.

    1980-03-01

    A study of well test analysis techniques in two-phase geothermal reservoirs has been conducted using a three-dimensional, two-phase, wellbore and reservoir simulation model. Well tests from Cerro Prieto and the Hawaiian Geothermal project have been history matched. Using these well tests as a base, the influence of reservoir permeability, porosity, thickness, and heat capacity, along with flow rate and fracturing were studied. Single and two-phase transient well test equations were used to analyze these tests with poor results due to rapidly changing fluid properties and inability to calculate the flowing steam saturation in the reservoir. The injection of cold water into the reservoir does give good data from which formation properties can be calculated.

  18. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

    1998-01-01

    Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

  19. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, D.J.; Bonk, D.L.; Dowdy, T.E.

    1998-01-13

    Polluting NO{sub x} gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO{sub x} gases are removed is directed to introducing NO{sub x}-free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor. 2 figs.

  20. Experimental study on confined two-phase jets

    SciTech Connect (OSTI)

    Levy, Y.; Albagli, D. )

    1991-09-01

    The basic mixing phenomena in confined, coaxial, particle-laden turbulent flows are studied within the scope of ram combustor research activities. Cold-flow experiments in a relatively simple configuration of confined, coaxial two-phase jets provided both qualitative and quantitative insight on the multiphase mixing process. Pressure, tracer gas concentration, and two-phase velocity measurements revealed that unacceptably long ram combustors are needed for complete confined jet mixing. Comparison of the experimental results with a previous numerical simulation displayed a very good agreement, indicating the potential of the experimental facility for validation of computational parametric studies. 38 refs.

  1. Acoustic wave propagation in two-phase heterogeneous porous media

    E-Print Network [OSTI]

    J. I. Osypik; N. I. Pushkina; Ya. M. Zhileikin

    2015-03-19

    The propagation of an acoustic wave through two-phase porous media with spatial variation in porosity is studied. The evolutionary wave equation is derived, and the propagation of an acoustic wave is numerically analyzed in application to marine sediments with various physical parameters.

  2. Implicit LES Simulation of Two phase Turbulent Jet Flow

    E-Print Network [OSTI]

    McDonald, Kirk

    Implicit LES Simulation of Two phase Turbulent Jet Flow Feb. 27th 2014 Yan 1 #12;Studied ProblemsD 2120 297 629,640 2 #12;Results 3JetDiameter Case · VOF 3 Initialization (t = 0 s) Z Z #12;Results 3JetDiameter Case (click to watch the movie) 4 · VOF 0 Jet

  3. INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES

    SciTech Connect (OSTI)

    Ates Akyurtlu; Jale F. Akyurtle

    2001-08-01

    Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}.

  4. Next generation gas turbines will be required to produce low concentrations of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), and soot. In order to design gas turbines which produce lower emissions it is essential

    E-Print Network [OSTI]

    Next generation gas turbines will be required to produce low concentrations of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), and soot. In order to design gas turbines which produce

  5. Flow visualization study of inverted U-bend two-phase flow

    SciTech Connect (OSTI)

    Ishii, M.; Kim, S.B.; Lee, R.

    1986-12-01

    A hot-leg U-bend experiment was performed. The experimental condition simulated the two-phase flow in a B and W primary loop during a small break loss of coolant accident or during some other abnormal transients. The loop design was based on the scaling criteria developed previously and the loop was operated either in a natural circulation mode or in a forced circulation mode using nitrogen gas and water. The two-phase flow regimes at the hot-leg were identified on the basis of visual observation. The phase separation at the top of the inverted U-bend was observed at low gas flow rate. The void fractions were measured using differential pressure transducers and compared with the prediction from the drift-flux model. The natural circulation flow interruption occurred in two different modes, namely, quasi-periodic and semi-permanent modes. This phenomenon is mainly dependent on the difference in the hydrostatic head in the riser and downcomer, and the flow regime at hot-leg. Besides this flow interruption phenomenon, dynamic flow instabilities of considerable amplitudes have been observed.

  6. A real two-phase submarine debris flow and tsunami

    SciTech Connect (OSTI)

    Pudasaini, Shiva P.; Miller, Stephen A. [Department of Geodynamics and Geophysics, Steinmann Institute, University of Bonn Nussallee 8, D-53115, Bonn (Germany)

    2012-09-26

    The general two-phase debris flow model proposed by Pudasaini is employed to study subaerial and submarine debris flows, and the tsunami generated by the debris impact at lakes and oceans. The model, which includes three fundamentally new and dominant physical aspects such as enhanced viscous stress, virtual mass, and generalized drag (in addition to buoyancy), constitutes the most generalized two-phase flow model to date. The advantage of this two-phase debris flow model over classical single-phase, or quasi-two-phase models, is that the initial mass can be divided into several parts by appropriately considering the solid volume fraction. These parts include a dry (landslide or rock slide), a fluid (water or muddy water; e.g., dams, rivers), and a general debris mixture material as needed in real flow simulations. This innovative formulation provides an opportunity, within a single framework, to simultaneously simulate the sliding debris (or landslide), the water lake or ocean, the debris impact at the lake or ocean, the tsunami generation and propagation, the mixing and separation between the solid and fluid phases, and the sediment transport and deposition process in the bathymetric surface. Applications of this model include (a) sediment transport on hill slopes, river streams, hydraulic channels (e.g., hydropower dams and plants); lakes, fjords, coastal lines, and aquatic ecology; and (b) submarine debris impact and the rupture of fiber optic, submarine cables and pipelines along the ocean floor, and damage to offshore drilling platforms. Numerical simulations reveal that the dynamics of debris impact induced tsunamis in mountain lakes or oceans are fundamentally different than the tsunami generated by pure rock avalanches and landslides. The analysis includes the generation, amplification and propagation of super tsunami waves and run-ups along coastlines, debris slide and deposition at the bottom floor, and debris shock waves. It is observed that the submarine debris speed can be faster than the tsunami speed. This information can be useful for early warning strategies in the coastal regions. These findings substantially increase our understanding of complex multi-phase systems and multi-physics and flows, and allows for the proper modeling of landslide and debris induced tsunami, the dynamics of turbidity currents and sediment transport, and the associated applications to hazard mitigation, geomorphology and sedimentology.

  7. Flow patterns in vertical two-phase flow

    SciTech Connect (OSTI)

    McQuillan, K.W.; Whalley, P.B.

    1985-03-01

    This paper is concerned with the flow patterns which occur in upwards gas-liquid two-phase flow in vertical tubes. The basic flow patterns are described and the use of flow patter maps is discussed. The transition between plug flow and churn flow is modelled under the assumption that flooding of the falling liquid film limits the stability of plug flow. The resulting equation is combined with other flow pattern transition equations to produce theoretical flow pattern maps, which are then tested against experimental flow pattern data. Encouraging agreement is obtained.

  8. Two Phase Transitions Make a High-Temperature Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPP UPDATE: April 15, 2014Two Electron HolesTwoTwo Phase

  9. Two Phase Transitions Make a High-Temperature Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPP UPDATE: April 15, 2014Two Electron HolesTwoTwo PhaseTwo

  10. Two Phase Transitions Make a High-Temperature Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPP UPDATE: April 15, 2014Two Electron HolesTwoTwo PhaseTwoTwo

  11. Two Phase Transitions Make a High-Temperature Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPP UPDATE: April 15, 2014Two Electron HolesTwoTwoTwo Phase

  12. Two Phase Transitions Make a High-Temperature Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPP UPDATE: April 15, 2014Two Electron HolesTwoTwoTwo PhaseTwo

  13. Thermal and combined thermal and radiolytic reactions involving nitrous oxide, hydrogen, nitrogen, and ammonia in contact with tank 241-SY-101 simulated waste

    SciTech Connect (OSTI)

    Bryan, S.A.; Pederson, L.R.

    1996-02-01

    Work described in this report was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, the purpose of which is to develop information needed to support Westinghouse Hanford Company (WHC) in their efforts to ensure the safe interim storage of wastes at the Hanford Site. Described in this report are the results of tests to evaluate the rates of thermal and combined thermal and radiolytic reactions involving flammable gases in the presence of Tank 241-SY-101 simulated waste. Flammable gases generated by the radiolysis of water and by the thermal and radiolytic decomposition of organic waste constituents may themselves participate in further reactions. Examples include the decomposition of nitrous oxide to yield nitrogen and oxygen, the reaction of nitrous oxide and hydrogen to produce nitrogen and water, and the reaction of nitrogen and hydrogen to produce ammonia. The composition of the gases trapped in bubbles in the wastes might therefore change continuously as a function of the time that the gas bubbles are retained.

  14. Investigation of single-substance horizontal two-phase flow

    SciTech Connect (OSTI)

    Dickinson, D.A.; Maeder, P.F.

    1984-03-01

    Despite the abundance of work in the field of two-phase flow, it seems as though a consensus has not been reached on some of the fundamental points. Although exceptions exist, adequate physical interpretation of the flow seems to be hindered either by complexity of analysis or, in the opposite extreme, the trend toward limited-range analysis and correlations. The dissertation presents the derivation of basic conservation equations for the phases. The combined equations are used to examine the phenomenon of slip and its practical limitations, the Fanno line for single-substance flow and the effect of slip on choking. Equations for critical mass flux in the presence of slip are derived. The Mach, Reynolds and Froude numbers based on conditions at flashing are introduced as the characteristic parameters, and the importance of compressibility in single-substance two-phase flow is discussed. Experimental measurements of pressure change and void fraction for flow in the highly compressible range (.5 < Ma < 1) are presented. The working fluid is Refrigerant R-114, at room temperature, in a test section of diameter 5 cm and length 8 m. The effect of the Froude and Mach numbers is examined. The experimental facility is operated intermittently with running times of approximately two minutes and is instrumented for rapid measurements using a computer data acquisition and control system. A description of the facility and procedure is provided.

  15. A NEW INTERPHASE FORCE IN TWO-PHASE FLUIDIZED BEDS

    SciTech Connect (OSTI)

    D. ZHANG; W. VANDERHEYDEN

    2001-05-01

    Mesoscale structures such as particle clusters have been observed both in experiments and in numerical simulations of circulating fluidized beds. In a numerical simulation, in order to account for the effects of such mesoscale structures, the computational grids have to be fine enough. The use of such fine grids is impractical in engineering applications due to excessive computational costs. To predict the macroscopic behavior of a fluidized bed with reasonable computation cost, they perform a second average over the averaged equations for two-phase flows. A mesoscale inter-phase exchange force is found to be the correlation of the particle volume fraction and the pressure gradient. This force is related to the mesoscale added mass of the two-phase flow. Typically, added mass for particle scale interactions is negligible in gas-solid flows since the gas density is small compared to density of solid particles. However, for a mesoscale structure, such as a bubble, the surrounding media is the mixture of gas and particles. The surrounding fluid density experienced by the mesoscale structure is the density of the surrounding mixture. Therefore, the added mass of a mesoscale structure, such as bubbles, cannot be neglected. The property of this new force is studied based on the numerical simulation of a fluidized bed using high grid resolution. It is shown that this force is important in the region where the particle volume fraction is high. The effects of the inhomogeneity to the interphase drag are also studied.

  16. Emissions of nitrogen oxides from US urban areas: estimation from Ozone Monitoring Instrument retrievals for 2005-2014

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Z.; Streets, D. G.; de Foy, B.; Lamsal, L. N.; Duncan, B. N.; Xing, J.

    2015-05-28

    Satellite remote sensing of tropospheric nitrogen dioxide (NO2) can provide valuable information for estimating surface nitrogen oxides (NOx) emissions. Using an exponentially-modified Gaussian (EMG) method and taking into account the effect of wind on observed NO2 distributions, we estimate three-year moving-average emissions of summertime NOx from 35 US urban areas directly from NO2 retrievals of the Ozone Monitoring Instrument (OMI) during 2005–2014. Following the conclusions of previous studies that the EMG method provides robust and accurate emission estimates under strong-wind conditions, we derive top-down NOx emissions from each urban area by applying the EMG method to OMI data with windmore »speeds greater than 3–5 m s-1. Meanwhile, we find that OMI NO2 observations under weak-wind conditions (i.e., -1) are qualitatively better correlated with the surface NOx source strength in comparison to all-wind OMI maps; and therefore we use them to calculate the satellite-observed NO2 burdens of urban areas and compare with NOx emission estimates. The EMG results show that OMI-derived NOx emissions are highly correlated (R > 0.93) with weak-wind OMI NO2 burdens as well as bottom-up NOx emission estimates over 35 urban areas, implying a linear response of the OMI observations to surface emissions under weak-wind conditions. The simultaneous, EMG-obtained, effective NO2 lifetimes (~3.5 ± 1.3 h), however, are biased low in comparison to the summertime NO2 chemical lifetimes. In general, isolated urban areas with NOx emission intensities greater than ~ 2 Mg h-1 produce statistically significant weak-wind signals in three-year average OMI data. From 2005 to 2014, we estimate that total OMI-derived NOx emissions over all selected US urban areas decreased by 49%, consistent with reductions of 43, 47, 49, and 44% in the total bottom-up NOx emissions, the sum of weak-wind OMI NO2 columns, the total weak-wind OMI NO2 burdens, and the averaged NO2 concentrations, respectively, reflecting the success of NOx control programs for both mobile sources and power plants. The decrease rates of these NOx-related quantities are found to be faster (i.e., -6.8 to -9.3% yr-1) before 2010 and slower (i.e., -3.4 to -4.9% yr-1) after 2010. For individual urban areas, we calculate the R values of pair-wise trends among the OMI-derived and bottom-up NOx emissions, the weak-wind OMI NO2 burdens, and ground-based NO2 measurements; and high correlations are found for all urban areas (median R = 0.8), particularly large ones (R up to 0.97). The results of the current work indicate that using the EMG method and considering the wind effect, the OMI data allow for the estimation of NOx emissions from urban areas and the direct constraint of emission trends with reasonable accuracy.« less

  17. THE NITROGEN OXIDES CONTROVERSY

    E-Print Network [OSTI]

    Johnston, Harold S.

    2012-01-01

    OZONE-COLUMN REDUCTION FOR STA DA D NOx INPUT BY LIVERMOREof NOx perturbation, one could calculate ozone reductionscalculates a reduction of the ozone column by NOx injections

  18. A Platinum-Enriched gamma+gamma' Two-Phase Bond Coat on Ni-Base Superalloys

    SciTech Connect (OSTI)

    Zhang, Ying [Tennessee Technological University; Pint, Bruce A [ORNL; Haynes, James A [ORNL; Wright, Ian G [ORNL

    2005-01-01

    Pt-enriched {gamma} + {gamma}{prime} two-phase coating was applied to directionally-solidified Ni-based superalloy Ren{acute e} 142 substrates with three different Hf levels (0.02, 0.76, and 1.37 wt.%). The coating was prepared by electroplating a thin layer of Pt on the superalloy followed by a diffusion treatment. The as-deposited coating exhibited a {gamma} + {gamma}{prime} two-phase microstructure with a major composition of Ni-16Al-18Pt-7Cr-9Co (in at.%) along with some incorporation of refractory elements from the substrates. Cyclic oxidation testing at 1100 C in air indicated improved oxidation resistance of the Ren{acute e} 142 alloys with the Pt-enriched {gamma} + {gamma}{prime} coatings. In addition, the oxidation resistance of both uncoated and coated alloys was proportional to the Hf content in the substrate. Compared with the single-phase {beta}-(Ni,Pt)Al coating, slightly higher mass gains and localized spallation were observed on the {gamma} + {gamma}{prime} two-phase coating, which might be due to the segregation of refractory elements and high sulfur levels in these superalloy substrates.

  19. Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations may apply to fossil-fuel fired emission units, and describe nitrogen emission allocations that owners of such units must meet. The regulations also contain provisions for...

  20. Two phase coexistence for the hydrogen-helium mixture

    E-Print Network [OSTI]

    Fantoni, Riccardo

    2015-01-01

    We use our newly constructed quantum Gibbs ensemble Monte Carlo algorithm to perform computer experiments for the two phase coexistence of a hydrogen-helium mixture. Our results are in quantitative agreement with the experimental results of C. M. Sneed, W. B. Streett, R. E. Sonntag, and G. J. Van Wylen. The difference between our results and the experimental ones is in all cases less than 15% relative to the experiment, reducing to less than 5% in the low helium concentration phase. At the gravitational inversion between the vapor and the liquid phase, at low temperatures and high pressures, the quantum effects become relevant. At extremely low temperature and pressure the first component to show superfluidity is the helium in the vapor phase.

  1. Emerging Two-Phase Cooling Technologies for Power Electronic Inverters

    SciTech Connect (OSTI)

    Hsu, J.S.

    2005-08-17

    In order to meet the Department of Energy's (DOE's) FreedomCAR and Vehicle Technologies (FVCT) goals for volume, weight, efficiency, reliability, and cost, the cooling of the power electronic devices, traction motors, and generators is critical. Currently the power electronic devices, traction motors, and generators in a hybrid electric vehicle (HEV) are primarily cooled by water-ethylene glycol (WEG) mixture. The cooling fluid operates as a single-phase coolant as the liquid phase of the WEG does not change to its vapor phase during the cooling process. In these single-phase systems, two cooling loops of WEG produce a low temperature (around 70 C) cooling loop for the power electronics and motor/generator, and higher temperature loop (around 105 C) for the internal combustion engine. There is another coolant option currently available in automobiles. It is possible to use the transmission oil as a coolant. The oil temperature exists at approximately 85 C which can be utilized to cool the power electronic and electrical devices. Because heat flux is proportional to the temperature difference between the device's hot surface and the coolant, a device that can tolerate higher temperatures enables the device to be smaller while dissipating the same amount of heat. Presently, new silicon carbide (SiC) devices and high temperature direct current (dc)-link capacitors, such as Teflon capacitors, are available but at significantly higher costs. Higher junction temperature (175 C) silicon (Si) dies are gradually emerging in the market, which will eventually help to lower hardware costs for cooling. The development of high-temperature devices is not the only way to reduce device size. Two-phase cooling that utilizes the vaporization of the liquid to dissipate heat is expected to be a very effective cooling method. Among two-phase cooling methods, different technologies such as spray, jet impingement, pool boiling and submersion, etc. are being developed. The Oak Ridge National Laboratory (ORNL) is leading the research on a novel floating refrigerant loop that cools high-power electronic devices and the motor/generator with very low cooling energy. The loop can be operated independently or attached to the air conditioning system of the vehicle to share the condenser and other mutually needed components. The ability to achieve low cooling energy in the floating loop is attributable to the liquid refrigerant operating at its hot saturated temperature (around 50 C+). In an air conditioning system, the liquid refrigerant is sub-cooled for producing cool air to the passenger compartment. The ORNL floating loop avoids the sub-cooling of the liquid refrigerant and saves significant cooling energy. It can raise the coefficient of performance (COP) more than 10 fold from that of the existing air-conditioning system, where the COP is the ratio of the cooled power and the input power for dissipating the cooled power. In order to thoroughly investigate emerging two-phase cooling technologies, ORNL subcontracted three university/companies to look into three leading two-phase cooling technologies. ORNL's assessments on these technologies are summarized in Section I. Detailed descriptions of the reports by the three university/companies (subcontractors) are in Section II.

  2. Development and Validation of a Two-phase, Three-dimensional...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Validation of a Two-phase, Three-dimensional Model for PEM Fuel Cells Development and Validation of a Two-phase, Three-dimensional Model for PEM Fuel Cells Presented at the...

  3. Two-phase microfluidics, heat and mass transport in direct methanol fuel cells

    E-Print Network [OSTI]

    CHAPTER 9 Two-phase microfluidics, heat and mass transport in direct methanol fuel cells G. Lu & C, including two-phase microfluidics, heat and mass transport. We explain how the better understanding

  4. Emissions of nitrogen oxides from US urban areas: estimation from Ozone Monitoring Instrument retrievals for 2005-2014

    SciTech Connect (OSTI)

    Lu, Z. [Argonne National Lab. (ANL), Argonne, IL (United States); Streets, D. G. [Argonne National Lab. (ANL), Argonne, IL (United States); de Foy, B. [Saint Louis Univ., St. Louis, MO (United States)] (ORCID:0000000341509922); Lamsal, L. N. [Goddard Earth Sciences Technology and Research, Universities Space Research Association, Columbia, MD (United States); NASA Goddard Space Flight Center, Greenbelt, MD (United States); Duncan, B. N. [NASA Goddard Space Flight Center, Greenbelt, MD (United States); Xing, J. [US Environmental Protection Agency, Research Triangle Park, NC (United States)

    2015-01-01

    Satellite remote sensing of tropospheric nitrogen dioxide (NO2) can provide valuable information for estimating surface nitrogen oxides (NOx) emissions. Using an exponentially-modified Gaussian (EMG) method and taking into account the effect of wind on observed NO2 distributions, we estimate three-year moving-average emissions of summertime NOx from 35 US urban areas directly from NO2 retrievals of the Ozone Monitoring Instrument (OMI) during 2005–2014. Following the conclusions of previous studies that the EMG method provides robust and accurate emission estimates under strong-wind conditions, we derive top-down NOx emissions from each urban area by applying the EMG method to OMI data with wind speeds greater than 3–5 m s-1. Meanwhile, we find that OMI NO2 observations under weak-wind conditions (i.e., < 3 m s-1) are qualitatively better correlated with the surface NOx source strength in comparison to all-wind OMI maps; and therefore we use them to calculate the satellite-observed NO2 burdens of urban areas and compare with NOx emission estimates. The EMG results show that OMI-derived NOx emissions are highly correlated (R > 0.93) with weak-wind OMI NO2 burdens as well as bottom-up NOx emission estimates over 35 urban areas, implying a linear response of the OMI observations to surface emissions under weak-wind conditions. The simultaneous, EMG-obtained, effective NO2 lifetimes (~3.5 ± 1.3 h), however, are biased low in comparison to the summertime NO2 chemical lifetimes. In general, isolated urban areas with NOx emission intensities greater than ~ 2 Mg h-1 produce statistically significant weak-wind signals in three-year average OMI data. From 2005 to 2014, we estimate that total OMI-derived NOx emissions over all selected US urban areas decreased by 49%, consistent with reductions of 43, 47, 49, and 44% in the total bottom-up NOx emissions, the sum of weak-wind OMI NO2 columns, the total weak-wind OMI NO2 burdens, and the averaged NO2 concentrations, respectively, reflecting the success of NOx control programs for both mobile sources and power plants. The decrease rates of these NOx-related quantities are found to be faster (i.e., -6.8 to -9.3% yr-1) before 2010 and slower (i.e., -3.4 to -4.9% yr-1) after 2010. For individual urban areas, we calculate the R values of pair-wise trends among the OMI-derived and bottom-up NOx emissions, the weak-wind OMI NO2 burdens, and ground-based NO2 measurements; and high correlations are found for all urban areas (median R = 0.8), particularly large ones (R up to 0.97). The results of the current work indicate that using the EMG method and considering the wind effect, the OMI data allow for the estimation of NOx emissions from urban areas and the direct constraint of emission trends with reasonable accuracy.

  5. Passive Two-Phase Cooling of Automotive Power Electronics: Preprint

    SciTech Connect (OSTI)

    Moreno, G.; Jeffers, J. R.; Narumanchi, S.; Bennion, K.

    2014-08-01

    Experiments were conducted to evaluate the use of a passive two-phase cooling strategy as a means of cooling automotive power electronics. The proposed cooling approach utilizes an indirect cooling configuration to alleviate some reliability concerns and to allow the use of conventional power modules. An inverter-scale proof-of-concept cooling system was fabricated, and tests were conducted using the refrigerants hydrofluoroolefin HFO-1234yf and hydrofluorocarbon HFC-245fa. Results demonstrated that the system can dissipate at least 3.5 kW of heat with 250 cm3 of HFC-245fa. An advanced evaporator design that incorporates features to improve performance and reduce size was conceived. Simulation results indicate its thermal resistance can be 37% to 48% lower than automotive dual side cooled power modules. Tests were also conducted to measure the thermal performance of two air-cooled condensers--plain and rifled finned tube designs. The results combined with some analysis were then used to estimate the required condenser size per operating conditions and maximum allowable system (i.e., vapor and liquid) temperatures.

  6. Full-field velocity measurements of single and two phase flows using digital pulsed laser velocimetry 

    E-Print Network [OSTI]

    Canaan, Robert Ernst

    1990-01-01

    to reliably measure and quantify both component velocities of two phase systems would directly contribute toward the goal of understanding such fundamental two phase flow characteristics as void fraction and its effects, flow and heat transfer regime...-field non-intrusive analysis of two phase flow regimes which are of great concern in the field of nuclear engineering. Modeling of two phase flow systems presents a particularly challenging problem in which there is much room for continuing improvement...

  7. Aalborg Universitet Two phase interleaved buck converter for driving high power LEDs

    E-Print Network [OSTI]

    Munk-Nielsen, Stig

    Aalborg Universitet Two phase interleaved buck converter for driving high power LEDs Beczkowski. (2011). Two phase interleaved buck converter for driving high power LEDs. In Proceedings of the 14th #12;Two phase interleaved buck converter for driving high power LEDs Szymon Bczkowski, Stig Munk

  8. Catalytic Reduction of Nitrogen Oxides by Methane over Pd(110) S. M. Vesecky, J. Paul, and D. W. Goodman*

    E-Print Network [OSTI]

    Goodman, Wayne

    the reduction of NOx species and the oxidation of CO and volatile organic compounds (VOC's) produced in mobile involves the selective catalytic reduction (SCR) or NOx with NH3 4 Although this process is efficient concern. If too much methane is oxidized to CO2, the efficiency of the NOx reduction process will suffer

  9. STUDIES OF TWO-PHASE PLUMES IN STRATIFIED ENVIRONMENTS

    SciTech Connect (OSTI)

    Scott A. Socolofsky; Brian C. Crounse; E. Eric Adams

    1998-11-18

    Two-phase plumes play an important role in the more practical scenarios for ocean sequestration of CO{sub 2}--i.e. dispersing CO{sub 2} as a buoyant liquid from either a bottom-mounted or ship-towed pipeline. Despite much research on related applications, such as for reservoir destratification using bubble plumes, our understanding of these flows is incomplete, especially concerning the phenomenon of plume peeling in a stratified ambient. To address this deficiency, we have built a laboratory facility in which we can make fundamental measurements of plume behavior. Although we are using air, oil and sediments as our sources of buoyancy (rather than CO{sub 2}), by using models, our results can be directly applied to field scale CO{sub 2} releases to help us design better CO{sub 2} injection systems, as well as plan and interpret the results of our up-coming international field experiment. The experimental facility designed to study two-phase plume behavior similar to that of an ocean CO{sub 2} release includes the following components: 1.22 x 1.22 x 2.44 m tall glass walled tank; Tanks and piping for the two-tank stratification method for producing step- and linearly-stratified ambient conditions; Density profiling system using a conductivity and temperature probe mounted to an automated depth profiler; Lighting systems, including a virtual point source light for shadowgraphs and a 6 W argon-ion laser for laser induced fluorescence (LIF) imaging; Imaging system, including a digital, progressive scanning CCD camera, computerized framegrabber, and image acquisition and analysis software; Buoyancy source diffusers having four different air diffusers, two oil diffusers, and a planned sediment diffuser; Dye injection method using a Mariotte bottle and a collar diffuser; and Systems integration software using the Labview graphical programming language and Windows NT. In comparison with previously reported experiments, this system allows us to extend the parameter range of our experiments to better match CO{sub 2} injection scenario field conditions and to make detailed measurements of the experimental plumes. To date we have run a basic suite of experiments covering a range of injected fluids (air and oil), flow rates (0.004 to 0.083 1/s), bubble/droplet sizes (0.05 to 1.5 cm), bubble slip velocities (5 to 35 cm/s), and ambient stratification types (linear and step). Qualitative observations of plume type (frequency and nature of peeling) from these experiments, as well as other experiments from the literature, have been correlated with dimensionless parameters to help us better characterize plume behavior. At the same time, quantitative data are being compared with a new analytical model which treats the flow as an upward-moving inner plume, coupled with an annular, downward-flowing outer plume which entrains from and intrudes into the ambient seawater. The model also includes CO{sub 2} specific features such as bubble/droplet mass transfer, solute dissolution effects on plume buoyancy, and change in total CO{sub 2} concentration and pH. We are continuing to conduct experiments which will provide additional data for model calibration. In turn, the model will be applied to CO{sub 2} injection to help us better understand field-scale CO{sub 2} releases, including those associated with the up-coming international field experiment.

  10. Unsteady two-phase flow instrumentation and measurement

    SciTech Connect (OSTI)

    Bernier, R.J.N.

    1982-01-01

    The performance of a transverse field electromagnetic flowmeter in a steady two-phase flow was investigated analytically for a disperse and an annular flow regime. In both cases the flowmeter output voltage was found to be proportional to the mean velocity of the liquid phase. Experiments in a steady air-water mixture showed good agreement with the analysis. An impedance void fraction meter was designed and built to conduct measurements of unsteady void fractions. Short electrodes excited by voltages of opposite polarity were used in combination with a highly sensitive signal processor. The steady state calibration indicated that the meter was somewhat sensitive to the void fraction distribution for the bubbly flow regime. However, the transition to a churn turbulent regime greatly affected the meter steady state response. The dynamic capability of the void fraction meter was estimated by comparison of the statistical properties of the voltage fluctuations in a nominally steady bubbly flow with those of a shot-noise process. Also some properties of the disperse phase could be inferred from the statistical analysis. Two void fraction meters were used to measure the propagation speed of kinematic shocks in an air-water bubbly mixture for various void fractions and water flow rates. Measurements of the propagation speed of shocks of decreasing strength provided a good verification of the kinematic wave theory. The shock thicknesses could also be determined leading to the conclusion that an important diffusion mechanism was responsible for arresting the steepening of the wave. Cross-correlations of the fluctuating voltage of two void fraction meters in a steady bubbly flow were determined. The speed measured by this technique was identified as the infinitesimal wave speed of the void fraction and not the velocity of the dispersed phase as postulated by some authors. The cross spectral density revealed that the waves present in these disturbances were non-dispersive.

  11. Response of fine particulate matter to emission changes of oxides of nitrogen and anthropogenic volatile organic compounds in the eastern United States

    SciTech Connect (OSTI)

    Alexandra P. Tsimpidi; Vlassis A. Karydis; Spyros N. Pandis

    2008-11-15

    A three-dimensional chemical transport model (Particulate Matter Comprehensive Air Quality Model with Extensions) is used to investigate changes in fine particle (PM2.5) concentrations in response to 50% emissions changes of oxides of nitrogen (NOx) and anthropogenic volatile organic compounds (VOCs) during July 2001 and January 2002 in the eastern United States. The reduction of NOx emissions by 50% during the summer results in lower average oxidant levels and lowers PM2.5 (8% on average), mainly because of reductions of sulfate (9-11%), nitrate (45-58%), and ammonium (7-11%). The organic particulate matter (PM) slightly decreases in rural areas, whereas it increases in cities by a few percent when NOx is reduced. Reduction of NOx during winter causes an increase of the oxidant levels and a rather complicated response of the PM components, leading to small net changes. Sulfate increases (8-17%), nitrate decreases (18-42%), organic PM slightly increases, and ammonium either increases or decreases a little. The reduction of VOC emissions during the summer causes on average a small increase of the oxidant levels and a marginal increase in PM2.5. This small net change is due to increases in the inorganic components and decreases of the organic ones. Reduction of VOC emissions during winter results in a decrease of the oxidant levels and a 5-10% reduction of PM2.5 because of reductions in nitrate (4-19%), ammonium (4-10%), organic PM (12-14%), and small reductions in sulfate. Although sulfur dioxide (SO{sub 2}) reduction is the single most effective approach for sulfate control, the coupled decrease of SO{sub 2} and NOx emissions in both seasons is more effective in reducing total PM2.5 mass than the SO{sub 2} reduction alone. 34 refs., 7 figs., 1 tab.

  12. Experimental study of liquid-side interphase mass transfer coefficients in two-phase channel flows

    SciTech Connect (OSTI)

    Luo, D.; Ghiaasiaan, S.M. [Georgia Inst. of Tech., Atlanta, GA (United States). G.W. Woodruff School of Mechanical Engineering

    1995-12-31

    The volumetric liquid-side interphase mass transfer coefficients were experimentally measured in a vertical channel with 1.9 cm inner diameter supporting a cocurrent, upward two-phase flow. Deionized water constituted the liquid phase, pure nitrogen represented the gas phase, and oxygen was the transferred species. In each test oxygen concentrations in the liquid at two stations near the two ends of the test section were measured on-line. The channel entrance affects were eliminated by performing hydrodynamically-identical tests with two different test section lengths, and using the shorter test section results for quantification of the entrance effects in the longer test section. Experiments were performed over a range of gas and liquid superficial velocities, covering the slug and churn flow regimes. The obtained data were compared with predictions of several widely-used correlations, with significant disagreements among the correlations, and between the correlations and the data. The presence of test section entrance effects and errors associated with sampling techniques in the previously published data appear to be the primary causes for these disagreements.

  13. Flow pattern, void fraction and pressure drop of two-phase air-water flow in a horizontal circular micro-channel

    SciTech Connect (OSTI)

    Saisorn, Sira [Energy Division, The Joint Graduate School of Energy and Environment (JGSEE), King Mongkut's University of Technology Thonburi, Bangmod, Bangkok 10140 (Thailand); Wongwises, Somchai [Fluid Mechanics, Thermal Engineering and Multiphase Flow Research Laboratory (FUTURE), Department of Mechanical Engineering, King Mongkut's University of Technology Thonburi, Bangmod, Bangkok 10140 (Thailand)

    2008-01-15

    Adiabatic two-phase air-water flow characteristics, including the two-phase flow pattern as well as the void fraction and two-phase frictional pressure drop, in a circular micro-channel are experimentally studied. A fused silica channel, 320 mm long, with an inside diameter of 0.53 mm is used as the test section. The test runs are done at superficial velocity of gas and liquid ranging between 0.37-16 and 0.005-3.04 m/s, respectively. The flow pattern map is developed from the observed flow patterns i.e. slug flow, throat-annular flow, churn flow and annular-rivulet flow. The flow pattern map is compared with those of other researchers obtained from different working fluids. The present single-phase experiments also show that there are no significant differences in the data from the use of air or nitrogen gas, and water or de-ionized water. The void fraction data obtained by image analysis tends to correspond with the homogeneous flow model. The two-phase pressure drops are also used to calculate the frictional multiplier. The multiplier data show a dependence on flow pattern as well as mass flux. A new correlation of two-phase frictional multiplier is also proposed for practical application. (author)

  14. Nitrogen spark denoxer

    DOE Patents [OSTI]

    Ng, Henry K. (Naperville, IL); Novick, Vincent J. (Downers Grove, IL); Sekar, Ramanujam R. (Naperville, IL)

    1997-01-01

    A NO.sub.X control system for an internal combustion engine includes an oxygen enrichment device that produces oxygen and nitrogen enriched air. The nitrogen enriched air contains molecular nitrogen that is provided to a spark plug that is mounted in an exhaust outlet of an internal combustion engine. As the nitrogen enriched air is expelled at the spark gap of the spark plug, the nitrogen enriched air is exposed to a pulsating spark that is generated across the spark gap of the spark plug. The spark gap is elongated so that a sufficient amount of atomic nitrogen is produced and is injected into the exhaust of the internal combustion engine. The injection of the atomic nitrogen into the exhaust of the internal combustion engine causes the oxides of nitrogen to be reduced into nitrogen and oxygen such that the emissions from the engine will have acceptable levels of NO.sub.X. The oxygen enrichment device that produces both the oxygen and nitrogen enriched air can include a selectively permeable membrane.

  15. KC-135 zero-gravity two-phase flow pressure drop experiments and modelling 

    E-Print Network [OSTI]

    Lambert, Anne

    1990-01-01

    mass, size, and pumping power requireinents. Knowledge of flow regime transitions, heat transfer characteristics, and pressure drop correlations is necessary to adequately design and develop two-phase systems. This work is concerned with two-phase... to reduce the overall system mass, size, and pumping power requirements. These advantages are realized because two-phase systems require lower mass flux for the same heat transfer capability. Knowledge of flow regime uansitions, heat transfer...

  16. Development of a Front Tracking Method for Two-Phase Micromixing...

    Office of Scientific and Technical Information (OSTI)

    properties of the two-phase mixture in terms of droplets, filaments, and other structures which emerge as a dispersed phase embedded into a continuous phase. Such a...

  17. High Performance Computing linear algorithms for two-phase flow in porous media

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    High Performance Computing linear algorithms for two-phase flow in porous media Robert Eymard High Performance Computing techniques. This implies to handle the difficult problem of solving

  18. Heterogeneous-phase reactions of nitrogen dioxide with vermiculite-supported magnesium oxide (as applied to the control of jet engine test cell emissions). Doctoral thesis

    SciTech Connect (OSTI)

    Kimm, L.T.

    1995-11-01

    Controlling nitrogen oxides (NOx) from a non-steady-state stationary source like a jet engine test cell (JETC) requires a method that is effective over a wide range of conditions. A heterogeneous, porous, high surface area sorbent material comprised of magnesium oxide powder attached to a vermiculite substrate has been commercially developed for this purpose. Data from extensive laboratory testing of this material in a packed-bed flow system are presented. NO2 removal efficiencies, kinetics, and proposed NO2 removal mechanisms over a range of representative JETC exhaust gas characteristics are described. Exhaust gas variables evaluated included: NO2 concentration, temperature, flow rate (retention time), oxygen content, and moisture content. Availability of water and oxygen were found to be important variables. It is probable that water is necessary for the conversion of MgO to Mg(OH)2, which is a more reactive compound having thermal stability over the range of temperatures evaluated. Gaseous oxygen serves to oxidize NO to NO2, the latter being more readily removed from the gas stream. The presence of oxygen also serves to offset thermal decomposition of NO2 or surface nitrite/nitrate. Effective `lifetime` and regenerability of the exposed sorbent material were also evaluated. NO2 removal efficiencies were found to greatly exceed those for NO, with a maximum value greater than 90 percent. The effective conversion of NO to NO2 is a crucial requirement for removal of the former. The reaction between NO2 and MgO-vermiculite is first-order with respect to NO2.

  19. Innovative Clean Coal Technology (ICCT). Demonstration of Selective Catalytic Reduction (SCR) technology for the control of Nitrogen Oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, third and fourth quarters 1995

    SciTech Connect (OSTI)

    1996-05-01

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese, and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

  20. Two-Phase Cooling Method Using R134a Refrigerant to Cool Power Electronic Devices

    E-Print Network [OSTI]

    Tolbert, Leon M.

    Two-Phase Cooling Method Using R134a Refrigerant to Cool Power Electronic Devices Jeremy B, TN 37932 Abstract This paper presents a two-phase cooling method using R134a refrigerant). The cooling method involves submerging PE devices in an R134a bath, which limits the junction temperature

  1. LATEX TikZposter Simulation of two-phase flow for

    E-Print Network [OSTI]

    Ábrahám, Erika

    LATEX TikZposter Simulation of two-phase flow for direct steam-generating solar thermal power Aachen University Simulation of two-phase flow for direct steam-generating solar thermal power plants University Concentrating solar thermal power plants Concentrating solar thermal power (CSP) plants

  2. On-demand generation of aqueous two-phase microdroplets with reversible phase transitions

    SciTech Connect (OSTI)

    Boreyko, Jonathan B [ORNL; Mruetusatorn, Prachya [ORNL; Retterer, Scott T [ORNL; Collier, Pat [ORNL

    2013-01-01

    Aqueous two-phase systems contained entirely within microdroplets enable a bottom-up approach to mimicking the dynamic microcompartmentation of biomaterial that naturally occurs within the cytoplasm of cells. Here, we demonstrate the on-demand generation of femtolitre aqueous two-phase droplets within a microfluidic oil channel. Gated pressure pulses were used to generate individual, stationary two-phase microdroplets with a well-defined time zero for carrying out controlled and sequential phase transformations over time. Reversible phase transitions between single-phase, two-phase, and core-shell microgel states were obtained via evaporation-induced dehydration and on-demand water rehydration. In contrast to other microfluidic aqueous two-phase droplets, which require continuous flows and high-frequency droplet formation, our system enables the controlled isolation and reversible transformation of a single microdroplet and is expected to be useful for future studies in dynamic microcompartmentation and affinity partitioning.

  3. Clean coal technology: selective catalytic reduction (SCR) technology for the control of nitrogen oxide emissions from coal-fired boilers

    SciTech Connect (OSTI)

    NONE

    2005-05-01

    The report discusses a project carried out under the US Clean Coal Technology (CCT) Demonstration Program which demonstrated selective catalytic reduction (SCR) technology for the control of NOx emissions from high-sulphur coal-fired boilers under typical boilers conditions in the United States. The project was conducted by Southern Company Services, Inc., who served as a co-funder and as the host at Gulf Power Company's Plant Crist. The SCR process consists of injecting ammonia (NH{sub 3}) into boiler flue gas and passing the flue gas through a catalyst bed where the Nox and NH{sub 3} react to form nitrogen and water vapor. The results of the CCTDP project confirmed the applicability of SCR for US coal-fired power plants. In part as a result of the success of this project, a significant number of commercial SCR units have been installed and are operating successfully in the United States. By 2007, the total installed SCR capacity on US coal-fired units will number about 200, representing about 100,000 MWe of electric generating capacity. This report summarizes the status of SCR technology. 21 refs., 3 figs., 2 tabs., 10 photos.

  4. Analytical solution for two-phase flow in a wellbore using the drift-flux model

    SciTech Connect (OSTI)

    Pan, L.; Webb, S.W.; Oldenburg, C.M.

    2011-11-01

    This paper presents analytical solutions for steady-state, compressible two-phase flow through a wellbore under isothermal conditions using the drift flux conceptual model. Although only applicable to highly idealized systems, the analytical solutions are useful for verifying numerical simulation capabilities that can handle much more complicated systems, and can be used in their own right for gaining insight about two-phase flow processes in wells. The analytical solutions are obtained by solving the mixture momentum equation of steady-state, two-phase flow with an assumption that the two phases are immiscible. These analytical solutions describe the steady-state behavior of two-phase flow in the wellbore, including profiles of phase saturation, phase velocities, and pressure gradients, as affected by the total mass flow rate, phase mass fraction, and drift velocity (i.e., the slip between two phases). Close matching between the analytical solutions and numerical solutions for a hypothetical CO{sub 2} leakage problem as well as to field data from a CO{sub 2} production well indicates that the analytical solution is capable of capturing the major features of steady-state two-phase flow through an open wellbore, and that the related assumptions and simplifications are justified for many actual systems. In addition, we demonstrate the utility of the analytical solution to evaluate how the bottomhole pressure in a well in which CO{sub 2} is leaking upward responds to the mass flow rate of CO{sub 2}-water mixture.

  5. Modeling analyses of the effects of changes in nitrogen oxides emissions from the electric power sector on ozone levels in the eastern United States

    SciTech Connect (OSTI)

    Edith Gego; Alice Gilliland; James Godowitch

    2008-04-15

    In this paper, we examine the changes in ambient ozone concentrations simulated by the Community Multiscale Air Quality (CMAQ) model for summer 2002 under three different nitrogen oxides (NOx) emission scenarios. Two emission scenarios represent best estimates of 2002 and 2004 emissions; they allow assessment of the impact of the NOx emissions reductions imposed on the utility sector by the NOx State Implementation Plan (SIP) Call. The third scenario represents a hypothetical rendering of what NOx emissions would have been in 2002 if no emission controls had been imposed on the utility sector. Examination of the modeled median and 95th percentile daily maximum 8-hr average ozone concentrations reveals that median ozone levels estimated for the 2004 emission scenario were less than those modeled for 2002 in the region most affected by the NOx SIP Call. Comparison of the 'no-control' with the '2002' scenario revealed that ozone concentrations would have been much higher in much of the eastern United States if the utility sector had not implemented NOx emission controls; exceptions occurred in the immediate vicinity of major point sources where increased NO titration tends to lower ozone levels. 13 refs., 8 figs., 2 tabs.

  6. Nitrogen sorption

    DOE Patents [OSTI]

    Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

    1993-01-01

    Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

  7. Nitrogen sorption

    DOE Patents [OSTI]

    Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Bend, OR); Miller, Warren K. (Bend, OR)

    1996-01-01

    Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

  8. Nitrogen sorption

    DOE Patents [OSTI]

    Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

    1996-05-14

    Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas. 5 figs.

  9. Nitrogen sorption

    DOE Patents [OSTI]

    Friesen, D.T.; Babcock, W.C.; Edlund, D.J.; Miller, W.K.

    1993-07-06

    Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

  10. Impact of structured heterogeneities on reactive two-phase porous flow

    E-Print Network [OSTI]

    Reeves, Daniel

    Two-phase flow through heterogeneous media leads to scale-free distributions of irregularly shaped pockets of one fluid trapped within the other. Although reactions within these fluids are often modeled at the homogeneous ...

  11. Liquid and gas distributions in a two-phase boiling analogy

    E-Print Network [OSTI]

    Wallis, Graham B.

    1958-01-01

    This report contains a description of the design and operation of an experimental appats for the analysis of two-phase flows similar to thom occuwring in boiler tubes at low pressures. Velocity and denuity profiles of ...

  12. A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene...

    Open Energy Info (EERE)

    A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase Tracer at the Coso Geothermal Field Jump to: navigation, search OpenEI Reference...

  13. A two-phase spherical electric machine for generating rotating uniform magnetic fields

    E-Print Network [OSTI]

    Lawler, Clinton T. (Clinton Thomas)

    2007-01-01

    This thesis describes the design and construction of a novel two-phase spherical electric machine that generates rotating uniform magnetic fields, known as a fluxball machine. Alternative methods for producing uniform ...

  14. Experimental on two sensors combination used in horizontal pipe gas-water two-phase flow

    SciTech Connect (OSTI)

    Wu, Hao; Dong, Feng

    2014-04-11

    Gas-water two phase flow phenomenon widely exists in production and living and the measurement of it is meaningful. A new type of long-waist cone flow sensor has been designed to measure two-phase mass flow rate. Six rings structure of conductance probe is used to measure volume fraction and axial velocity. The calibration of them have been made. Two sensors have been combined in horizontal pipeline experiment to measure two-phase flow mass flow rate. Several model of gas-water two-phase flow has been discussed. The calculation errors of total mass flow rate measurement is less than 5% based on the revised homogeneous flow model.

  15. Two-phase mixed media dielectric with macro dielectric beads for enhancing resistivity and breakdown strength

    SciTech Connect (OSTI)

    Falabella, Steven; Meyer, Glenn A; Tang, Vincent; Guethlein, Gary

    2014-06-10

    A two-phase mixed media insulator having a dielectric fluid filling the interstices between macro-sized dielectric beads packed into a confined volume, so that the packed dielectric beads inhibit electro-hydrodynamically driven current flows of the dielectric liquid and thereby increase the resistivity and breakdown strength of the two-phase insulator over the dielectric liquid alone. In addition, an electrical apparatus incorporates the two-phase mixed media insulator to insulate between electrical components of different electrical potentials. And a method of electrically insulating between electrical components of different electrical potentials fills a confined volume between the electrical components with the two-phase dielectric composite, so that the macro dielectric beads are packed in the confined volume and interstices formed between the macro dielectric beads are filled with the dielectric liquid.

  16. Analytical Solutions for Multicomponent, Two-Phase Flow in Porous Media with Double Contact Discontinuities

    E-Print Network [OSTI]

    Orr, F. M. Jr

    This paper presents the first instance of a double contact discontinuity in analytical solutions for multicomponent, two-phase flow in porous media. We use a three-component system with constant equilibrium ratios and fixed ...

  17. Statistical Analysis of Microgravity Two-Phase Slug Flow via the Drift Flux Model 

    E-Print Network [OSTI]

    Larsen, Benjamin A

    2014-05-01

    of microgravity two-phase flow data difficult. Multiple researchers have postulated the microgravity drift flux model parameters to predict void fraction, however, these methods were initially developed with no consideration given to a microgravity environment...

  18. USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS...

    Open Energy Info (EERE)

    USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE COSO EGS PROJECT Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference...

  19. The transition from the annular to the slug flow regime in two-phase flow

    E-Print Network [OSTI]

    Haberstroh, Robert D.

    1964-01-01

    Experiments were conducted to determine the transition from annular to semiannular flow regimes for two-phase, gas-liquid upflow in vertical tubes. The influencesof liquid flow rate, tube diameter, liquid viscosity, surface ...

  20. Drift-flux analysis of two-phase flow in microgravity 

    E-Print Network [OSTI]

    Braisted, Jonathan David

    2004-01-01

    As NASA programs such as the International Space Station, the Space Shuttle, the Space Nuclear Power Initiative, and other future spacecraft become more demanding, two-phase (gas-liquid) systems for advanced life support and thermal management...

  1. Two-phase flow interfacial drag for once through steam generators 

    E-Print Network [OSTI]

    Rais, Omar Tahar

    1990-01-01

    which determined in subroutine PHAINT. The term FIJ is determined for each junction from different models depending on what flow regimes are calculated for the volumes adjoining the junction. IV. 3 Introduction to Two Phase Flow Patterns When a... transfer rates, and other parameters of 25 interest will behave differently as the flow pattern changes. Various techniques are available for the study of two-phase flow patterns in heated and unheated channels. In a transparent channels at low...

  2. Two-phase stratified flow regime transition analysis for low gravity conditions 

    E-Print Network [OSTI]

    Miller, Kathryn M.

    1990-01-01

    TWO-PHASE STRATIFIED FLOW REGIME TRANSITION ANALYSIS FOR LOW GRAVITY CONDITIONS A Thesis by KATHRYN M. MILLER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE December 1990 Major Subject: Nuclear Engineering TWO-PHASE STRATIFIED FLOW REGIME TRANSITION ANALYSIS FOR LOW GRAVITY CONDITIONS A Thesis KATHRYN M. MILLER Approved as to style and content by: Frederick R. Best (Chair...

  3. A finite element analysis of shrinkage stress fields in two-phase materials 

    E-Print Network [OSTI]

    Hall, Frank

    1980-01-01

    A FINITE ELEMENT ANALYSIS OF SHRINKAGE STRESS FIELDS IN TWO-PHASE MATERIALS A Thesis by FRANK HALL Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1980 Maj or Subj ect: Mechanical Engineering A FINITE ELEMENT ANALYSIS OF SHRINKAGE STRESS FIELDS IN TWO-PHASE MATERIALS A Thesis FRANK HALL Approved as to style and content by: (Chairman of Committee) (Member) (Member) (Member) (H d...

  4. Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen

    E-Print Network [OSTI]

    Dabdub, Donald

    Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides and indoor air. Oxides of nitrogen (NOy) are also globally distributed, because NO formed in combustion processes is oxidized to NO2, HNO3, N2O5 and a variety of other nitrogen oxides during transport. Deposition

  5. Selective Catalytic Reduction of Oxides of Nitrogen with Ethanol/Gasoline Blends over a Silver/Alumina Catalyst on Lean Gasoline Engine

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Pihl, Josh A; Toops, Todd J; Thomas, John F; Parks, II, James E; West, Brian H

    2015-01-01

    Ethanol is a very effective reductant of nitrogen oxides (NOX) over silver/alumina (Ag/Al2O3) catalysts in lean exhaust environment. With the widespread availability of ethanol/gasoline-blended fuel in the USA, lean gasoline engines equipped with an Ag/Al2O3 catalyst have the potential to deliver higher fuel economy than stoichiometric gasoline engines and to increase biofuel utilization while meeting exhaust emissions regulations. In this work a pre-commercial 2 wt% Ag/Al2O3 catalyst was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine for the selective catalytic reduction (SCR) of NOX with ethanol/gasoline blends. The ethanol/gasoline blends were delivered via in-pipe injection upstream of the Ag/Al2O3 catalyst with the engine operating under lean conditions. A number of engine conditions were chosen to provide a range of temperatures and space velocities for the catalyst performance evaluations. High NOX conversions were achieved with ethanol/gasoline blends containing at least 50% ethanol; however, higher C1/N ratio was needed to achieve greater than 90% NOX conversion, which also resulted in significant HC slip. Temperature and HC dosing were important in controlling selectivity to NH3 and N2O. At high temperatures, NH3 and N2O yields increased with increased HC dosing. At low temperatures, NH3 yield was very low, however, N2O levels became significant. The ability to generate NH3 under lean conditions has potential for application of a dual SCR approach (HC SCR + NH3 SCR) to reduce fuel consumption needed for NOX reduction and/or increased NOX conversion, which is discussed in this work.

  6. DYNAMIC MODELING STRATEGY FOR FLOW REGIME TRANSITION IN GAS-LIQUID TWO-PHASE FLOWS

    SciTech Connect (OSTI)

    X. Wang; X. Sun; H. Zhao

    2011-09-01

    In modeling gas-liquid two-phase flows, the concept of flow regime has been used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are often flow regime dependent. Currently, the determination of the flow regimes is primarily based on flow regime maps or transition criteria, which are developed for steady-state, fully-developed flows and widely applied in nuclear reactor system safety analysis codes, such as RELAP5. As two-phase flows are observed to be dynamic in nature (fully-developed two-phase flows generally do not exist in real applications), it is of importance to model the flow regime transition dynamically for more accurate predictions of two-phase flows. The present work aims to develop a dynamic modeling strategy for determining flow regimes in gas-liquid two-phase flows through the introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation and destruction of the interfacial area, such as the fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation; and fluid particle coalescence and condensation, respectively. For the flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shape (which are correlated), namely small bubbles and large bubbles. A preliminary approach to dynamically identifying the flow regimes is provided, in which discriminators are based on the predicted information, such as the void fraction and interfacial area concentration of small bubble and large bubble groups. This method is expected to be applied to computer codes to improve their predictive capabilities of gas-liquid two-phase flows, in particular for the applications in which flow regime transition occurs.

  7. Nox control for high nitric oxide concentration flows through combustion-driven reduction

    DOE Patents [OSTI]

    Yeh, James T. (Bethel Park, PA); Ekmann, James M. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA); Drummond, Charles J. (Churchill, PA)

    1989-01-01

    An improved method for removing nitrogen oxides from concentrated waste gas streams, in which nitrogen oxides are ignited with a carbonaceous material in the presence of substoichiometric quantities of a primary oxidant, such as air. Additionally, reductants may be ignited along with the nitrogen oxides, carbonaceous material and primary oxidant to achieve greater reduction of nitrogen oxides. A scrubber and regeneration system may also be included to generate a concentrated stream of nitrogen oxides from flue gases for reduction using this method.

  8. Three-dimensional reconstruction of bubble distribution in two-phase bubbly flows with the dynamic programming method 

    E-Print Network [OSTI]

    Furukawa, Toru

    2002-01-01

    A three-dimensional bubble reconstruction method is proposed in this thesis to analyze two-phase bubbly flows. Gas/liquid two-phase flows have important roles in the nuclear and chemical industries and other engineering fields...

  9. Coupling of a two phase gas liquid compositional 3D Darcy flow with a 1D compositional free gas

    E-Print Network [OSTI]

    Ribot, Magali

    Coupling of a two phase gas liquid compositional 3D Darcy flow with a 1D compositional free gas. Masson1 , L. Trenty2 , Y. Zhang1 Coupling of a two phase gas liquid compositional 3D Darcy flow #12 analysis K, Brenner1 , R. Masson1 , L. Trenty2 , Y. Zhang1 Coupling of a two phase gas liquid compositional

  10. Two-phase pressure drop across a hydrofoil-based micro pin device using R-123

    SciTech Connect (OSTI)

    Kosar, Ali [Mechatronics Engineering Program, Sabanci University, Orhanli, Tuzla, 34956 Istanbul (Turkey)

    2008-05-15

    The two-phase pressure drop in a hydrofoil-based micro pin fin heat sink has been investigated using R-123 as the working fluid. Two-phase frictional multipliers have been obtained over mass fluxes from 976 to 2349 kg/m{sup 2} s and liquid and gas superficial velocities from 0.38 to 1.89 m/s and from 0.19 to 24 m/s, respectively. It has been found that the two-phase frictional multiplier is strongly dependent on flow pattern. The theoretical prediction using Martinelli parameter based on the laminar fluid and laminar gas flow represented the experimental data fairly well for the spray-annular flow. For the bubbly and wavy-intermittent flow, however, large deviations from the experimental data were recorded. The Martinelli parameter was successfully used to determine the flow patterns, which were bubbly, wavy-intermittent, and spray-annular flow in the current study. (author)

  11. Macro-to-microchannel transition in two-phase flow: Part 1 - Two-phase flow patterns and film thickness measurements

    SciTech Connect (OSTI)

    Ong, C.L.; Thome, J.R. [Ecole Polytechnique Federale de Lausanne, EPFL-STI-IGM-LTCM, Station 9, CH-1015 Lausanne (Switzerland)

    2011-01-15

    The classification of macroscale, mesoscale and microscale channels with respect to two-phase processes is still an open question. The main objective of this study focuses on investigating the macro-to-microscale transition during flow boiling in small scale channels of three different sizes with three different refrigerants over a range of saturation conditions to investigate the effects of channel confinement on two-phase flow patterns and liquid film stratification in a single circular horizontal channel (Part 2 covers the flow boiling heat transfer and critical heat flux). This paper presents the experimental two-phase flow pattern transition data together with a top/bottom liquid film thickness comparison for refrigerants R134a, R236fa and R245fa during flow boiling in small channels of 1.03, 2.20 and 3.04 mm diameter. Based on this work, an improved flow pattern map has been proposed by determining the flow patterns transitions existing under different conditions including the transition to macroscale slug/plug flow at a confinement number of Co {approx} 0.3-0.4. From the top/bottom liquid film thickness comparison results, it was observed that the gravity forces are fully suppressed and overcome by the surface tension and shear forces when the confinement number approaches 1, Co {approx} 1. Thus, as a new approximate rule, the lower threshold of macroscale flow is Co = 0.3-0.4 while the upper threshold of symmetric microscale flow is Co {approx} 1 with a transition (or mesoscale) region in-between. (author)

  12. Film boiling on spheres in single- and two-phase flows.

    SciTech Connect (OSTI)

    Liu, C.; Theofanous, T. G.

    2000-08-29

    Film boiling on spheres in single- and two-phase flows was studied experimentally and theoretically with an emphasis on establishing the film boiling heat transfer closure law, which is useful in the analysis of nuclear reactor core melt accidents. Systematic experimentation of film boiling on spheres in single-phase water flows was carried out to investigate the effects of liquid subcooling (from 0 to 40 C), liquid velocity (from 0 to 2 m/s), sphere superheat (from 200 to 900 C), sphere diameter (from 6 to 19 mm), and sphere material (stainless steel and brass) on film boiling heat transfer. Based on the experimental data a general film boiling heat transfer correlation is developed. Utilizing a two-phase laminar boundary-layer model for the unseparated front film region and a turbulent eddy model for the separated rear region, a theoretical model was developed to predict the film boiling heat transfer in all single-phase regimes. The film boiling from a sphere in two-phase flows was investigated both in upward two-phase flows (with void fraction from 0.2 to 0.65, water velocity from 0.6 to 3.2 m/s, and steam velocity from 3.0 to 9.0 m/s) and in downward two-phase flows (with void fraction from 0.7 to 0.95, water velocity from 1.9 to 6.5 m/s, and steam velocity from 1.1 to 9.0 m/s). The saturated single-phase heat transfer correlation was found to be applicable to the two-phase film boiling data by making use of the actual water velocity (water phase velocity), and an adjustment factor of (1 - {alpha}){sup 1/4} (with a being the void fraction) for downward flow case only. Slight adjustments of the Reynolds number exponents in the correlation provided an even better interpretation of the two-phase data. Preliminary experiments were also conducted to address the influences of multi-sphere structure on the film boiling heat transfer in single- and two-phase flows.

  13. The effect of distributors on two-phase and three-phase flows in vertical columns 

    E-Print Network [OSTI]

    Ouyang, Chie-Jan Paul

    1982-01-01

    ) - U1C (1 - E'g)/6'1 where g is the void fraction. For two-phase flow, the area fractions are related by equation 4. Substituting equation 4 into equation 3, the reduced form f' or the drift flux is obtained, Vd ? U (1- 6 ) ? Ulg The drift flux... appropriate: THE EFFECT OF DISTRIBUTORS ON TWO-PHASE AND THREE-PHASE FLOWS IN VERTICAL COLUMNS A Thesis by CHIE-JAN PAUL OUYANG Approved as to sty1e and content by: Chairm of Committee Member M mber Head of Dep rtment May 1982 ABS TRACT The Effect...

  14. Session 1: Geothermal Pumping Systems and Two-Phase Flow Studies

    SciTech Connect (OSTI)

    Hanold, R.J.

    1983-12-01

    Improvements in electric submersible pumping systems have resulted in a demonstrated downhole running life of one year for low horsepower units operating in 180 C brine. The implementation of a prototype pressurized lubrication system to prevent brine intrusion and loss of lubricating oil from the motor and protector sections has been successfully tested. Second generation pressurized lubrication systems have been designed and fabricated and will be utilized in downhole production pumping tests during FY84. Pumping system lifetime is currently limited by available power cable designs that are degraded by high-temperature brine. A prototype metal-sheathed power cable has been designed and fabricated and is currently undergoing destructive and nondestructive laboratory testing. This cable design has the potential for eliminating brine intrusion into the power delivery system through the use of a hermatically sealed cable from the surface to the downhole motor. The two-phase flow program is directed at understanding the hydrodynamics of two-phase flows. The two-phase flow regime is characterized by a series of flow patterns that are designated as bubble, slug, churn, and annular flow. Churn flow has received very little scientific attention. This lack of attention cannot be justified because calculations predict that the churn flow pattern will exist over a substantial portion of the two-phase flow zone in producing geothermal wells. The University of Houston is experimentally investigating the dynamics of churn flow and is measuring the holdup over the full range of flow space for which churn flow exists. These experiments are being conducted in an air/water vertical two-phase flow loop. Brown University has constructed and is operating a unique two-phase flow research facility specifically designed to address flow problems of relevance to the geothermal industry. An important feature of the facility is that it is dedicated to two-phase flow of a single substance (including evaporation and condensation) as opposed to the case of a two-component two-phase flow. This facility can be operated with horizontal or vertical test sections of constant diameter or with step changes in diameter to simulate a geothermal well profile.

  15. The carbon footprint analysis of wastewater treatment plants and nitrous oxide emissions from full-scale biological nitrogen removal processes in Spain

    E-Print Network [OSTI]

    Xu, Xin, S.M. Massachusetts Institute of Technology

    2013-01-01

    This thesis presents a general model for the carbon footprint analysis of advanced wastewater treatment plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ...

  16. Eddy Covariance Fluxes of Nitrogen Oxides at Harvard Forest NOx deposition is important to both the biosphere and the atmosphere: the form of

    E-Print Network [OSTI]

    Current estimates indicate that fossil fuel combustion and soil microbial emissions are the largest by smaller contributions from biomass burning, lightning, ammonia oxidation, the ocean, and the stratosphere. Oxidation of natural and anthropogenic hydrocarbon emissions produces intermediate products

  17. Stochastic Formulation for Uncertainty Analysis of Two-Phase Flow in

    E-Print Network [OSTI]

    Zhang, Dongxiao

    Stochastic Formulation for Uncertainty Analysis of Two-Phase Flow in Heterogeneous Reservoirs in flow performance predictions due to uncertainty in the reservoir description. We solve moment equations. Accurate modeling of the physics that govern complex multi- phase reservoir flows requires a detailed

  18. Biodegradation of 4-Nitrophenol in a Two-Phase System Operating with

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    Biodegradation of 4-Nitrophenol in a Two-Phase System Operating with Polymers as the Partitioning and pressures, with reduced capital and operating costs. A serious limitation of biotreatment systems, however-phase bioreactor, operating with polymers as a partitioning phase, as an alternative to both single phase

  19. Safety relief valve sizing: comparison of two-phase flow models to empirical data 

    E-Print Network [OSTI]

    Meiller, Paul Robert

    2013-02-22

    in this study: The Two-Phase-Homogenous-Equilibrium Model (TPHEM), proposed by the Center for Chemical Process Safety (CCPS), and the Homogenous-Nonequilibrium Model proposed by Fauske. These models were evaluated against steam/water data (both sub-cooled...

  20. Statistical comparison of two-phase flow, void fraction fluctuations in a microgravity environment 

    E-Print Network [OSTI]

    Chang, Jae Ho

    1997-01-01

    A two-phase flow experiment was flown aboard the NASA KC-135 zero gravity aircraft to test void fraction sensors and collect void fraction data under the unique conditions of microgravity. Void fraction measurements were made by two capacitance void...

  1. Mechanisms of self-excitation of thermoacoustic vibrations in two-phase bubble flows

    SciTech Connect (OSTI)

    Skalozubov, V.I. )

    1991-01-01

    In this paper, the mechanisms of self-excitation of thermoacoustic vibrations in two-phase bubble flows are described. It is shown that a theory of this process must take into consideration the work performed by bubbles traveling in the acoustic wave. The results of the theory herein developed agree with previous experimental data of the author.

  2. Solution for Coal Seam Deaasi ication Wel s =ducing Under Two-Phase Flow Conditkms

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    tested extensively using a wide range of coal properties including desorption charac- teristics, and were. `E 22673 7ype-Curve ., Solution for Coal Seam Deaasi ication Wel s =ducing Under Two-Phase Flow the presenceof water in the coal seam and its co- production with gas. The developed type curves are capable

  3. Velocity and energy relaxation in two-phase Yannick Meyapin a

    E-Print Network [OSTI]

    Gisclon, Marguerite

    in industry and in nature. Typical examples include water waves (especially during the wave breaking), petroleum and gas flow in pipes, nuclear reactors [SFW+ 05], etc. The most important industrial application of two-phase flows is the simulation of a wide spectrum of accident scenarios in Pressurized (or Boiling

  4. Measurement and modeling of liquid film thickness evolution in stratified two-phase microchannel flows

    E-Print Network [OSTI]

    Hidrovo, Carlos H.

    in microchannels. Some liquid imaging work has been performed using gamma densitometry, X-ray tomo- graphy 20 January 2006; accepted 27 July 2006 Available online 27 September 2006 Abstract Polymer: Stratified flow; Microchannel; Fluorescent imaging; Two-phase; Liquid film 1. Introduction The polymer

  5. A Biomechanically Motivated Two-Phase Strategy for Biped Upright Balance Control

    E-Print Network [OSTI]

    A Biomechanically Motivated Two-Phase Strategy for Biped Upright Balance Control Muhammad Abdallah and is robust to local ground surface feature. Biomechanics literature indicates a similar strategy in play maintenance during gait. We take our cue from biomechanics research [10] which points out the very different

  6. On the Riemann Problem for a Hyperbolic Two-Phase D. Zeidana,

    E-Print Network [OSTI]

    a Department of Computing and Mathematics Manchester Metropolitan University, Manchester M1 5GD, UK b is hyperbolic, Godunov-type numerical methods for the model can be employed using locally approximate analytical accuracy as achieved using MUSCL-Hancock and WAF [3, 4] schemes. The numerical results for two-phase shock

  7. Sensorless Current Sharing in Digitally Controlled Two-Phase Buck DC-DC Converters

    E-Print Network [OSTI]

    is discussed. Experimental results are shown for a two-phase synchronous buck converter with 6V input voltage synchronous buck converter shown in Fig.1 has been built to test the proposed sensorless current sharing the digital command d. A sensorless current sharing block generates two command duty cycles d1 and d2 in order

  8. Remediation of PAH contaminated soils: Application of a solidliquid two-phase partitioning bioreactor

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    Remediation of PAH contaminated soils: Application of a solid­liquid two-phase partitioning Available online 21 July 2008 keywords: Solid-phase absorption Biodegradation PAHs Bioremediation Soil scale for the remediation of soil contaminated with a model mixture of polycyclic aromatic hydrocarbons

  9. Level Set Based Simulations of Two-Phase Oil-Water Flows in Pipes

    E-Print Network [OSTI]

    Soatto, Stefano

    the assumption that the densities of the two uids are di#11;erent and that the viscosity of the oil core is veryLevel Set Based Simulations of Two-Phase Oil-Water Flows in Pipes Hyeseon Shim July 31, 2000 Abstract We simulate the axisymmetric pipeline transportation of oil and water numerically under

  10. Study of a numerical scheme for miscible two-phase flow in porous media

    E-Print Network [OSTI]

    Boyer, Edmond

    holds for CO2 storage, gas pro- duction, and other situations. For x and t [0, T], we consider Schleper November 21, 2013 Abstract We study the convergence of a finite volume scheme for a model of miscible two-phase flow in porous media. In this model, one phase can dissolve into the other one

  11. Two-Phase Biomedical Named Entity Recognition Using A Hybrid Method

    E-Print Network [OSTI]

    Two-Phase Biomedical Named Entity Recognition Using A Hybrid Method Seonho Kim1 , Juntae Yoon2, Korea 2 NLP Lab. Daumsoft Inc. Seoul, Korea Abstract. Biomedical named entity recognition (NER) is a difficult problem in biomedical information processing due to the widespread am- biguity of terms out

  12. Averaged dynamics of two-phase media in a vibration field Arthur V. Straubea

    E-Print Network [OSTI]

    Straube, Arthur V.

    to astronomic scales. Vibration is a mechanical oscillatory process with an amplitude that is small compared of the system is much larger than the period of the oscillation. Vibration mechanics has been studied for a longAveraged dynamics of two-phase media in a vibration field Arthur V. Straubea Department of Physics

  13. Enhancement of a Two-Phase Partitioning Bioreactor System by Modication

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    : Application of two-phase partitioning biore- actors (TPPB) to the degradation of phenol and xenobi- otics has/L h±1 ), but a comparison of initial cell concentra- tions and yields revealed an improved phenol-degrading could interfere with xenobiotic degradation, limiting remedia- tion ef®ciency, and hence represents

  14. Polymer Selection for Biphenyl Degradation in a Solid-Liquid Two-Phase Partitioning Bioreactor

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    Polymer Selection for Biphenyl Degradation in a Solid-Liquid Two-Phase Partitioning Bioreactor Lars, Kingston, Ontario, Canada K7L 3N6 The commercially available thermoplastic polymer Hytrel was selected biphenyl. The partitioning of biphenyl between the selected polymers and water was analogous

  15. Electrochemical process for the preparation of nitrogen fertilizers

    DOE Patents [OSTI]

    Aulich, Ted R.; Olson, Edwin S.; Jiang, Junhua

    2013-03-19

    The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be solid.

  16. A gas kinetic scheme for the Baer-Nunziato two-phase flow model

    SciTech Connect (OSTI)

    Pan, Liang, E-mail: panliangjlu@sina.com [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China) [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China); The Graduate School of China Academy of Engineering Physics, Beijing 100088 (China); Zhao, Guiping, E-mail: zhaogp@nsfc.gov.cn [National Natural Science Foundation of China, Beijing 100085 (China)] [National Natural Science Foundation of China, Beijing 100085 (China); Tian, Baolin, E-mail: tian_baolin@iapcm.ac.cn [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China) [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China); Key Laboratory of Computational Physics, Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China); Wang, Shuanghu, E-mail: wang_shuanghu@iapcm.ac.cn [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China) [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China); Key Laboratory of Computational Physics, Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China)

    2012-09-15

    Numerical methods for the Baer-Nunziato (BN) two-phase flow model have attracted much attention in recent years. In this paper, we present a new gas kinetic scheme for the BN two-phase flow model containing non-conservative terms in the framework of finite volume method. In the view of microscopic aspect, a generalized Bhatnagar-Gross-Krook (BGK) model which matches with the BN model is constructed. Based on the integral solution of the generalized BGK model, we construct the distribution functions at the cell interface. Then numerical fluxes can be obtained by taking moments of the distribution functions, and non-conservative terms are explicitly introduced into the construction of numerical fluxes. In this method, not only the complex iterative process of exact solutions is avoided, but also the non-conservative terms included in the equation can be handled well.

  17. Measurement of average density and relative volumes in a dispersed two-phase fluid

    DOE Patents [OSTI]

    Sreepada, Sastry R. (Clifton Park, NY); Rippel, Robert R. (late of Scotia, NY)

    1992-01-01

    An apparatus and a method are disclosed for measuring the average density and relative volumes in an essentially transparent, dispersed two-phase fluid. A laser beam with a diameter no greater than 1% of the diameter of the bubbles, droplets, or particles of the dispersed phase is directed onto a diffraction grating. A single-order component of the diffracted beam is directed through the two-phase fluid and its refraction is measured. Preferably, the refracted beam exiting the fluid is incident upon a optical filter with linearly varing optical density and the intensity of the filtered beam is measured. The invention can be combined with other laser-based measurement systems, e.g., laser doppler anemometry.

  18. Identification of two-phase flow patterns by a single void fraction sensor

    SciTech Connect (OSTI)

    Wang, Y.W.; King, C.H.; Pei, B.S.

    1988-10-01

    A wide range of combinations of gas and liquid flow rates that form various flow patterns are investigated. By analyzing the signal spectra detected by a single sensor using light techniques, the criteria for identifying two-phase flow patterns are proposed. By applying these criteria with only one parameter, the high-frequency contribution fraction (HFCF), the reasonable identifying performance is 76% when churn flow is counted and 88% when churn flow is not counted. When ..cap alpha..-bar is added as an auxiliary to HFCF, the identifying performance can be increased to 83 and 96%, depending on whether churn flow is counted. Both parameters can be acquired by signals from a single void fraction sensor. The criteria are expected to apply to other void fraction measurable systems for identifying two-phase flow patterns.

  19. Heat transfer to air-water two-phase flow in slug/churn region

    SciTech Connect (OSTI)

    Wadekar, V.V. [AEA Technology, Harwell (United Kingdom). Heat Transfer and Fluid Flow Service; Tuzla, K.; Chen, J.C. [Lehigh Univ., Bethlehem, PA (United States). Dept. of Chemical Engineering

    1996-12-31

    Measured heat transfer data for air-water two-phase flow in the slug/churn flow region are reported. The measurements were obtained from a 1.3 m tall, 15.7 mm diameter vertical tube test-section. It is observed that the data exhibit different heat transfer characteristics to those predicted by the standard correlations for the convective component of flow boiling heat transfer. Comparison with the predictions of a slug flow model for evaporation shows a significant overprediction of the data. The reason for the overprediction is attributed to the sensible heating requirement of the gas phase. The slug flow model is therefore suitably modified for non-evaporating two-phase flow. This specially adapted model is found to give reasonably good predictions of the measured data.

  20. Cavitation and two-phase flow characteristics of SRPR (Savannah River Plant Reactor) pump. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-07-01

    The possible head degradation of the SRPR pumps may be attributable to two independent phenomena, one due to the inception of cavitation and the other due to the two-phase flow phenomena. The head degradation due to the appearance of cavitation on the pump blade is hardly likely in the conventional pressurized water reactor (PWR) since the coolant circulating line is highly pressurized so that the cavitation is difficult to occur even at LOCA (loss of coolant accident) conditions. On the other hand, the suction pressure of SRPR pump is order-of-magnitude smaller than that of PWR so that the cavitation phenomena, may prevail, should LOCA occur, depending on the extent of LOCA condition. In this study, therefore, both cavitation phenomena and two-phase flow phenomena were investigated for the SRPR pump by using various analytical tools and the numerical results are presented herein.

  1. Proportional electroluminescence in two-phase argon and its relevance to rare-event experiments

    E-Print Network [OSTI]

    A. Bondar; A. Buzulutskov; A. Dolgov; V. Nosov; L. Shekhtman; E. Shemyakina; A. Sokolov

    2015-09-02

    Proportional electroluminescence (EL) in gaseous Ar has for the first time been systematically studied in the two-phase mode, at 87 K and 1.00 atm. Liquid Ar had a minor (56 ppm) admixture of N2, which allowed to understand, inter alia, the effect of N2 doping on the EL mechanism in rare-event experiments using two-phase Ar detectors. The measurements were performed in a two-phase Cryogenic Avalanche Detector (CRAD) with EL gap located directly above the liquid-gas interface. The EL gap was optically read out in the Vacuum Ultraviolet (VUV), near 128 nm (Ar excimer emission), and in the near Ultraviolet (UV), at 300-450 nm (N2 Second Positive System emission), via cryogenic PMTs and a Geiger-mode APD (GAPD). Proportional electroluminescence was measured to have an amplification parameter of 109+-10 photons per drifting electron per kV overall in the VUV and UV, of which 51+-6% were emitted in the UV. The measured EL threshold, at an electric field of 3.7+-0.2 kV/cm, was in accordance with that predicted by the theory. The latter result is particularly relevant to DarkSide and SCENE dark matter search-related experiments, where the operation electric field was thereby on the verge of appearance of the S2 (ionization-induced) signal. The results obtained pave the way to the development of N2-doped two-phase Ar detectors with enhanced sensitivity to the S2 signal.

  2. Lattice Boltzmann Methods to Address Fundamental Boiling and Two-Phase Problems

    SciTech Connect (OSTI)

    Uddin, Rizwan

    2012-01-01

    This report presents the progress made during the fourth (no cost extension) year of this three-year grant aimed at the development of a consistent Lattice Boltzmann formulation for boiling and two-phase flows. During the first year, a consistent LBM formulation for the simulation of a two-phase water-steam system was developed. Results of initial model validation in a range of thermo-dynamic conditions typical for Boiling Water Reactors (BWRs) were shown. Progress was made on several fronts during the second year. Most important of these included the simulation of the coalescence of two bubbles including the surface tension effects. Work during the third year focused on the development of a new lattice Boltzmann model, called the artificial interface lattice Boltzmann model (AILB model) for the 3 simulation of two-phase dynamics. The model is based on the principle of free energy minimization and invokes the Gibbs-Duhem equation in the formulation of non-ideal forcing function. This was reported in detail in the last progress report. Part of the efforts during the last (no-cost extension) year were focused on developing a parallel capability for the 2D as well as for the 3D codes developed in this project. This will be reported in the final report. Here we report the work carried out on testing the AILB model for conditions including the thermal effects. A simplified thermal LB model, based on the thermal energy distribution approach, was developed. The simplifications are made after neglecting the viscous heat dissipation and the work done by pressure in the original thermal energy distribution model. Details of the model are presented here, followed by a discussion of the boundary conditions, and then results for some two-phase thermal problems.

  3. Conceptual plan: Two-Phase Flow Laboratory Program for the Waste Isolation Pilot Plant

    SciTech Connect (OSTI)

    Howarth, S.M.

    1993-07-01

    The Salado Two-Phase Flow Laboratory Program was established to address concerns regarding two-phase flow properties and to provide WIPP-specific, geologically consistent experimental data to develop more appropriate correlations for Salado rock to replace those currently used in Performance Assessment models. Researchers in Sandia`s Fluid Flow and Transport Department originally identified and emphasized the need for laboratory measurements of Salado threshold pressure and relative permeability. The program expanded to include the measurement of capillary pressure, rock compressibility, porosity, and intrinsic permeability and the assessment of core damage. Sensitivity analyses identified the anhydrite interbed layers as the most likely path for the dissipation of waste-generated gas from waste-storage rooms because of their relatively high permeability. Due to this the program will initially focus on the anhydrite interbed material. The program may expand to include similar rock and flow measurements on other WIPP materials including impure halite, pure halite, and backfill and seal materials. This conceptual plan presents the scope, objectives, and historical documentation of the development of the Salado Two-Phase Flow Program through January 1993. Potential laboratory techniques for assessing core damage and measuring porosity, rock compressibility, capillary and threshold pressure, permeability as a function of stress, and relative permeability are discussed. Details of actual test designs, test procedures, and data analysis are not included in this report, but will be included in the Salado Two-Phase Flow Laboratory Program Test Plan pending the results of experimental and other scoping activities in FY93.

  4. Proportional electroluminescence in two-phase argon and its relevance to rare-event experiments

    E-Print Network [OSTI]

    Bondar, A; Dolgov, A; Nosov, V; Shekhtman, L; Shemyakina, E; Sokolov, A

    2015-01-01

    Proportional electroluminescence (EL) in gaseous Ar has for the first time been systematically studied in the two-phase mode, at 87 K and 1.00 atm. Liquid Ar had a minor (56 ppm) admixture of N2, which allowed to understand, inter alia, the effect of N2 doping on the EL mechanism in rare-event experiments using two-phase Ar detectors. The measurements were performed in a two-phase Cryogenic Avalanche Detector (CRAD) with EL gap located directly above the liquid-gas interface. The EL gap was optically read out in the Vacuum Ultraviolet (VUV), near 128 nm (Ar excimer emission), and in the near Ultraviolet (UV), at 300-450 nm (N2 Second Positive System emission), via cryogenic PMTs and a Geiger-mode APD (GAPD). Proportional electroluminescence was measured to have an amplification parameter of 109+-10 photons per drifting electron per kV overall in the VUV and UV, of which 51+-6% were emitted in the UV. The measured EL threshold, at an electric field of 3.7+-0.2 kV/cm, was in accordance with that predicted by th...

  5. Pressure loss in two-phase flow through a microchannel rod bundle

    SciTech Connect (OSTI)

    Smith, A.C.; Hamm, L.L.; Qureshi, Z.; Steeper, T.J. [Westinghouse Savannah River Co., Aiken, SC (United States). Savannah River Site

    1998-09-01

    The purpose of the microchannel rod bundle two-phase flow test described here was to provide data for benchmarking safety analyses for the accelerator production of tritium (APT). The objective was to obtain pressure loss data for a typical accelerator target rod bundle over a wide range of two-phase flow conditions. The test rod bundle assembly was fabricated for single-phase pressure drop tests conducted at Los Alamos National Laboratory (LANL) and subsequently used for the two-phase flow testing described here. The results for a typical case are given. These results fall generally in the slug flow regime for the horizontal flow results of Fukano and Kariyasaki for a 1.0-mm circular channel. Fukano and Kariyasaki found that surface tension effects were dominant in the 1-mm channel and report no churn regime. The results were also compared with the flow regime maps given by Triplett et al. for flow in discrete microchannels. Triplett employed both circular and trapezoidal channels, the latter to approximate the rod bundle interstitial flow channel shape. It was found that the rod bundle flow fell across the slug-to-churn flow regime transition reported by Triplett. This is consistent with the expectation that cross flow among channels would result in turbulent mixing and would suppress the formation of large discrete bubbles.

  6. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  7. Transport of heat and mass in a two-phase mixture: From a continuous to a discontinuous description

    E-Print Network [OSTI]

    Kjelstrup, Signe

    Transport of heat and mass in a two-phase mixture: From a continuous to a discontinuous description online 14 October 2010 We present a theory that describes the transport properties of the interfacial of the surface for transport between the two phases for a mixture. It is shown that interfacial resistances

  8. Role of Nucleation and Growth in Two-Phase Microstructure Formation

    SciTech Connect (OSTI)

    Jong Ho Shin

    2008-05-01

    During the directional solidification of peritectic alloys, a rich variety of two-phase microstructures develop, and the selection process of a specific microstructure is complicated due to the following two considerations. (1) In contrast to many single phase and eutectic microstructures that grow under steady state conditions, two-phase microstructures in a peritectic system often evolve under non-steady-state conditions that can lead to oscillatory microstructures, and (2) the microstructure is often governed by both the nucleation and the competitive growth of the two phases in which repeated nucleation can occur due to the change in the local conditions during growth. In this research, experimental studies in the Sn-Cd system were designed to isolate the effects of nucleation and competitive growth on the dynamics of complex microstructure formation. Experiments were carried out in capillary samples to obtain diffusive growth conditions so that the results can be analyzed quantitatively. At high thermal gradient and low velocity, oscillatory microstructures were observed in which repeated nucleation of the two phases was observed at the wall-solid-liquid junction. Quantitative measurements of nucleation undercooling were obtained for both the primary and the peritectic phase nucleation, and three different ampoule materials were used to examine the effect of different contact angles at the wall on nucleation undercooling. Nucleation undercooling for each phase was found to be very small, and the experimental undercooling values were orders of magnitude smaller than that predicted by the classical theory of nucleation. A new nucleation mechanism is proposed in which the clusters of atoms at the wall ahead of the interface can become a critical nucleus when the cluster encounters the triple junction. Once the nucleation of a new phase occurs, the microstructure is found to be controlled by the relative growth of the two phases that give rise to different oscillatory microstructures that depend on the imposed velocity and the size of the sample. At low thermal gradient to velocity ratio, a steady-state composite microstructure is observed. Two mechanisms of composite microstructure formation were examined: (1) the formation of the peritectic phase in the intercellular region of the primary phase where the solute rejected by the primary phase is absorbed by the peritectic phase. The peritectic phase forms a small distance behind the growing primary phase front. (2) The second mechanism is the coupled growth of the two phases with a macroscopically planar interface, as in the case of eutectic growth. Detailed studies showed that this composite microstructure, although it appears as a eutectic microstructure, did not grow in the coupled manner at the advancing interface in the Sn-cd system. However, a new observation was made when experiments were carried out in thin ampoule of Ta. The peritectic phase nucleated at the wall-interface triple junction and grew along the wall, while the primary phase continued to grow at the center, giving rise to a steady-state couple growth at some specific velocity. The mechanism of coupled growth in this case was shown to be operative due to the presence of a finite contact angle at the wall, and this was demonstrated by including the contact angle effect at the wall in the rod eutectic growth model. The experimental results were summarized to map out the conditions of thermal gradient and velocity on the regimes of composite and oscillatory microstructure formation. The formation of complex time-dependent microstructures was then discussed in terms of the time-dependent dynamics of planar interface growth.

  9. Development of a Spectroscopic Technique for Continuous Online Monitoring of Oxygen and Site-Specific Nitrogen Isotopic Composition of Atmospheric Nitrous Oxide

    E-Print Network [OSTI]

    Harris, Eliza

    Nitrous oxide is an important greenhouse gas and ozone-depleting-substance. Its sources are diffuse and poorly characterized, complicating efforts to understand anthropogenic impacts and develop mitigation policies. Online, ...

  10. Pressure Profiles in Two-Phase Geothermal Wells: Comparison of Field Data and Model Calculations

    SciTech Connect (OSTI)

    Ambastha, A.K.; Gudmundsson, J.S.

    1986-01-21

    Increased confidence in the predictive power of two-phase correlations is a vital part of wellbore deliverability and deposition studies for geothermal wells. Previously, the Orkiszewski (1967) set of correlations has been recommended by many investigators to analyze geothermal wellbore performance. In this study, we use measured flowing pressure profile data from ten geothermal wells around the world, covering a wide range of flowrate, fluid enthalpy, wellhead pressure and well depth. We compare measured and calculated pressure profiles using the Orkiszewski (1967) correlations.

  11. A degeneration of two-phase solutions of focusing NLS via Riemann-Hilbert problems

    E-Print Network [OSTI]

    Marco Bertola; Pietro Giavedoni

    2014-12-06

    Two-phase solutions of focusing NLS equation are classically constructed out of an appropriate Riemann surface of genus two, and expressed in terms of the corresponding theta-function. We show here that in a certain limiting regime such solutions reduce to some elementary ones called "Solitons on unstable condensate". This degeneration turns out to be conveniently studied by means of basic tools from the theory of Riemann-Hilbert problems. In particular no acquaintance with Riemann surfaces and theta-function is required for such analysis.

  12. Scintillation Pulse Shape Discrimination in a Two-Phase Xenon Time Projection Chamber

    E-Print Network [OSTI]

    J. Kwong; P. Brusov; T. Shutt; C. E. Dahl; A. I. Bolozdynya; A. Bradley

    2009-08-06

    The energy and electric field dependence of pulse shape discrimination in liquid xenon have been measured in a 10 gm two-phase xenon time projection chamber. We have demonstrated the use of the pulse shape and charge-to-light ratio simultaneously to obtain a leakage below that achievable by either discriminant alone. A Monte Carlo is used to show that the dominant fluctuation in the pulse shape quantity is statistical in nature, and project the performance of these techniques in larger detectors. Although the performance is generally weak at low energies relevant to elastic WIMP recoil searches, the pulse shape can be used in probing for higher energy inelastic WIMP recoils.

  13. Numerical modeling of two-phase behavior in the PEFC gas diffusion layer

    SciTech Connect (OSTI)

    Mukherjee, Partha Pa223876 [Los Alamos National Laboratory; Kang, Qinjun [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Borup, Rod L [Los Alamos National Laboratory

    2009-01-01

    A critical performance limitation in the polymer electrolye fuel cell (PEFC) is attributed to the mass transport loss originating from suboptimal liquid water transport and flooding phenomena. Liquid water can block the porous pathways in the fibrous gas diffusion layer (GDL) and the catalyst layer (CL), thus hindering oxygen transport from the flow field to the electrochemically actives sites in the catalyst layer. In this paper, the study of the two phase behavior and the durability implications due to the wetting characteristics in the carbon paper GDL are presented using a pore-scale modeling framework.

  14. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1992-02-03

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project.

  15. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, third quarter 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-03

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project.

  16. Final Report - Advanced Conceptual Models for Unsaturated and Two-Phase Flow in Fractured Rock

    SciTech Connect (OSTI)

    Nicholl, Michael J.

    2006-07-10

    The Department of Energy Environmental Management Program is faced with two major issues involving two-phase flow in fractured rock; specifically, transport of dissolved contaminants in the Vadose Zone, and the fate of Dense Nonaqueous Phase Liquids (DNAPLs) below the water table. Conceptual models currently used to address these problems do not correctly include the influence of the fractures, thus leading to erroneous predictions. Recent work has shown that it is crucial to understand the topology, or ''structure'' of the fluid phases (air/water or water/DNAPL) within the subsurface. It has also been shown that even under steady boundary conditions, the influence of fractures can lead to complex and dynamic phase structure that controls system behavior, with or without the presence of a porous rock matrix. Complicated phase structures within the fracture network can facilitate rapid transport, and lead to a sparsely populated and widespread distribution of concentrated contaminants; these qualities are highly difficult to describe with current conceptual models. The focus of our work is to improve predictive modeling through the development of advanced conceptual models for two-phase flow in fractured rock.

  17. Effects of two-phase flow on the deflagration of porous energetic materials

    SciTech Connect (OSTI)

    Margolis, S.B.; Williams, F.A.

    1994-05-01

    The combustion behavior of energetic materials (e.g., solid propellants) has long been of interest in the fields of propulsion and pyrotechnics. In many such applications, it is becoming increasingly clear that two-phase flow effects play an important role, especially since, during combustion, most homogeneous solid propellants develop thin multi-phase layers at their surfaces in which finite-rate exothermic reactions occur. In addition, there is a growing interest in the behavior of porous energetic solids, since even initially dense materials can develop significant void fractions if, at any time, they are exposed to abnormal thermal environments. The deflagration characteristics of such ``damaged`` materials may then differ significantly from those of the pristine material due, at least in part, to gas flow in the solid/gas preheat region. The presence of gas in the porous solid in turn results in a more pronounced two-phase effect in the multi-phase surface layer, such as in the liquid melt region of nitramine propellants, which thus tend to exhibit extensive bubbling in an exothermic foam layer. The present analysis is largely applicable to this latter class of propellants.

  18. Energy balance in two phase models for temperature fluctuations in HII regions

    E-Print Network [OSTI]

    C. Giammanco; J. E. Beckman

    2006-02-14

    Aims. The main objective of this article is to provide a simple physical framework with permits a quantitative comparison of measurements of the temperature fluctuations in the ionized interstellar medium with possible mechanisms which can produce them. Methods. We assume a generalized two phase ISM and derive expressions relating the mean amplitude of the temperature fluctuations to the temperatures of the phases and to the energy input, in excess of the basic component due to photoionization, required to maintain them. We apply these expressions to a set of limiting cases for the temperature and density differences between the phases. Finally we compare the most plausible case with the most complete data set available: the temperature fluctuations observed in the Orion Nebula. Results. We first list the cases considered and our general inferences: (a) Very hot tenuous substrate and warm moderately dense clouds; discarded as requiring too much excess energy input. (b) Two phases with equal densities but different temperatures, both warm; feasible but not general. (c) Two warm phases at moderately different temperatures and densities; the most probable case. This case is then used to quantify a specific hypothesis, reconnection of turbulent magnetic fields, as the source of the fluctuations observed in the Orion Nebula. Field strengths of a few hundred microG are required, not out of line with the limited observations available. Time variability on scales of months is a testable prediction of the scenario.

  19. Numerical simulations of two-phase Taylor-Couette turbulence using an Euler-Lagrange approach

    E-Print Network [OSTI]

    Spandan, Vamsi; Verzicco, Roberto; Lohse, Detlef

    2015-01-01

    Two-phase turbulent Taylor-Couette (TC) flow is simulated using an Euler-Lagrange approach to study the effects of a secondary phase dispersed into a turbulent carrier phase (here bubbles dispersed into water). The dynamics of the carrier phase is computed using Direct Numerical Simulations (DNS) in an Eulerian framework, while the bubbles are tracked in a Lagrangian manner by modelling the effective drag, lift, added mass and buoyancy force acting on them. Two-way coupling is implemented between the dispersed phase and the carrier phase which allows for momentum exchange among both phases and to study the effect of the dispersed phase on the carrier phase dynamics. The radius ratio of the TC setup is fixed to $\\eta=0.833$, and a maximum inner cylinder Reynolds number of $Re_i=8000$ is reached. We vary the Froude number ($Fr$), which is the ratio of the centripetal to the gravitational acceleration of the dispersed phase and study its effect on the net torque required to drive the TC system. In a two-phase TC...

  20. Two-phase behavior and compression effects in the PEFC gas diffusion medium

    SciTech Connect (OSTI)

    Mukherjee, Partha P [Los Alamos National Laboratory; Kang, Qinjun [Los Alamos National Laboratory; Schulz, Volker P [APL-LANDAU GMBH; Wang, Chao - Yang [PENN STATE UNIV; Becker, Jurgen [NON LANL; Wiegmann, Andreas [NON LANL

    2009-01-01

    A key performance limitation in the polymer electrolyte fuel cell (PEFC), manifested in terms of mass transport loss, originates from liquid water transport and resulting flooding phenomena in the constituent components. A key contributor to the mass transport loss is the cathode gas diffusion layer (GDL) due to the blockage of available pore space by liquid water thus rendering hindered oxygen transport to the active reaction sites in the electrode. The GDL, therefore, plays an important role in the overall water management in the PEFC. The underlying pore-morphology and the wetting characteristics have significant influence on the flooding dynamics in the GDL. Another important factor is the role of cell compression on the GDL microstructural change and hence the underlying two-phase behavior. In this article, we present the development of a pore-scale modeling formalism coupled With realistic microstructural delineation and reduced order compression model to study the structure-wettability influence and the effect of compression on two-phase behavior in the PEFC GDL.

  1. Two-Phase Flow Patterns in a Four by Four Rod Bundle

    SciTech Connect (OSTI)

    Yoshitaka Mizutani; Shigeo Hosokawa; Akio Tomiyama [Kobe University, Kobe (Japan)

    2006-07-01

    Air-water two-phase flow patterns in a four by four square lattice rod bundle consisting of an acrylic channel box of 68 mm in width and transparent rods of 12 mm in diameter were observed by utilizing a high speed video camera, FEP (fluorinated ethylene propylene) tubes for rods, and a fiber-scope inserted in a rod. The FEP possesses the same refractive index as water, and thereby, whole flow patterns in the bundle and local flow patterns in subchannels were successfully visualized with little optical distortion. The ranges of liquid and gas volume fluxes, and , in the present experiments were 0.1 < < 2.0 m/s and 0.04 < < 8.85 m/s, which covered typical two-phase flow patterns appearing in a fuel bundle of a boiling water nuclear reactor. As a result, the following conclusions were obtained: (1) the region of slug flow in the - flow pattern diagram is so narrow that it can be regarded as a boundary between bubbly and churn flows, (2) the boundary between bubbly and churn flows is close to the boundary between bubbly and slug flows of the Mishima and Ishii's flow pattern transition model, and (3) the boundary between churn and annular flows is well predicted by the Mishima and Ishii's model. (authors)

  2. Vertical two-phase flow regimes and pressure gradients: Effect of viscosity

    SciTech Connect (OSTI)

    Da Hlaing, Nan; Sirivat, Anuvat; Siemanond, Kitipat [The Petroleum and Petrochemical College, Chulalongkorn University, Soi Chula 12, Phayathai Road, Pathumwan, Bangkok 10330 (Thailand); Wilkes, James O. [Department of Chemical Engineering, The University of Michigan, Ann Arbor, MI 48109-2136 (United States)

    2007-05-15

    The effect of liquid viscosity on the flow regimes and the corresponding pressure gradients along the vertical two-phase flow was investigated. Experiment was carried out in a vertical transparent tube of 0.019 m in diameter and 3 m in length and the pressure gradients were measured by a U-tube manometer. Water and a 50 vol.% glycerol solution were used as the working fluids whose kinematic viscosities were 0.85 x 10{sup -6} and 4.0 x 10{sup -6} m{sup 2}/s, respectively. In our air-liquid annular two-phase flow, the liquid film of various thicknesses flowed adjacent to the wall and the gas phase flowed at the center of the tube. The superficial air velocity, j{sub air}, was varied between 0.0021 and 58.7 m/s and the superficial liquid velocity, j{sub liquid}, was varied between 0 and 0.1053 m/s. In the bubble, the slug and the slug-churn flow regimes, the pressure gradients decreased with increasing Reynolds number. But in the annular and the mist flow regimes, pressure gradients increased with increasing Reynolds number. Finally, the experimentally measured pressure gradient values were compared and are in good agreement with the theoretical values. (author)

  3. Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides. Semiannual report, Apr 1, 1998--Oct 31, 1998

    SciTech Connect (OSTI)

    Dr. Ates Akyurtlu; Dr. Jale F. Akyurtlu

    1998-10-31

    Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823--900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures. The sorbents consisting of cerium oxide and copper oxide impregnated on alumina have been prepared and characterized. Their sulfation performance has been investigated in a TGA setup, studying mainly the effects of temperature and sorbent composition. The results of the sulfation experiments have been evaluated and presented in this report. A study to model the sulfation selectivity of the two constituents of the sorbents is also underway.

  4. A connectivity-based modeling approach for representing hysteresis in macroscopic two-phase flow properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cihan, Abdullah; Birkholzer, Jens; Trevisan, Luca; Bianchi, Marco; Zhou, Quanlin; Illangasekare, Tissa

    2014-12-31

    During CO2 injection and storage in deep reservoirs, the injected CO2 enters into an initially brine saturated porous medium, and after the injection stops, natural groundwater flow eventually displaces the injected mobile-phase CO2, leaving behind residual non-wetting fluid. Accurate modeling of two-phase flow processes are needed for predicting fate and transport of injected CO2, evaluating environmental risks and designing more effective storage schemes. The entrapped non-wetting fluid saturation is typically a function of the spatially varying maximum saturation at the end of injection. At the pore-scale, distribution of void sizes and connectivity of void space play a major role formore »the macroscopic hysteresis behavior and capillary entrapment of wetting and non-wetting fluids. This paper presents development of an approach based on the connectivity of void space for modeling hysteretic capillary pressure-saturation-relative permeability relationships. The new approach uses void-size distribution and a measure of void space connectivity to compute the hysteretic constitutive functions and to predict entrapped fluid phase saturations. Two functions, the drainage connectivity function and the wetting connectivity function, are introduced to characterize connectivity of fluids in void space during drainage and wetting processes. These functions can be estimated through pore-scale simulations in computer-generated porous media or from traditional experimental measurements of primary drainage and main wetting curves. The hysteresis model for saturation-capillary pressure is tested successfully by comparing the model-predicted residual saturation and scanning curves with actual data sets obtained from column experiments found in the literature. A numerical two-phase model simulator with the new hysteresis functions is tested against laboratory experiments conducted in a quasi-two-dimensional flow cell (91.4cm×5.6cm×61cm), packed with homogeneous and heterogeneous sands. Initial results show that the model can predict spatial and temporal distribution of injected fluid during the experiments reasonably well. However, further analyses are needed for comprehensively testing the ability of the model to predict transient two-phase flow processes and capillary entrapment in geological reservoirs during geological carbon sequestration.« less

  5. A connectivity-based modeling approach for representing hysteresis in macroscopic two-phase flow properties

    SciTech Connect (OSTI)

    Cihan, Abdullah [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Birkholzer, Jens [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Trevisan, Luca [Colorado School of Mines, Golden, CO (United States). Center for Experimental Study of Subsurface Environmental Processes (CESEP); Bianchi, Marco [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Zhou, Quanlin [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Illangasekare, Tissa [Colorado School of Mines, Golden, CO (United States). Center for Experimental Study of Subsurface Environmental Processes (CESEP)

    2014-12-31

    During CO2 injection and storage in deep reservoirs, the injected CO2 enters into an initially brine saturated porous medium, and after the injection stops, natural groundwater flow eventually displaces the injected mobile-phase CO2, leaving behind residual non-wetting fluid. Accurate modeling of two-phase flow processes are needed for predicting fate and transport of injected CO2, evaluating environmental risks and designing more effective storage schemes. The entrapped non-wetting fluid saturation is typically a function of the spatially varying maximum saturation at the end of injection. At the pore-scale, distribution of void sizes and connectivity of void space play a major role for the macroscopic hysteresis behavior and capillary entrapment of wetting and non-wetting fluids. This paper presents development of an approach based on the connectivity of void space for modeling hysteretic capillary pressure-saturation-relative permeability relationships. The new approach uses void-size distribution and a measure of void space connectivity to compute the hysteretic constitutive functions and to predict entrapped fluid phase saturations. Two functions, the drainage connectivity function and the wetting connectivity function, are introduced to characterize connectivity of fluids in void space during drainage and wetting processes. These functions can be estimated through pore-scale simulations in computer-generated porous media or from traditional experimental measurements of primary drainage and main wetting curves. The hysteresis model for saturation-capillary pressure is tested successfully by comparing the model-predicted residual saturation and scanning curves with actual data sets obtained from column experiments found in the literature. A numerical two-phase model simulator with the new hysteresis functions is tested against laboratory experiments conducted in a quasi-two-dimensional flow cell (91.4cm×5.6cm×61cm), packed with homogeneous and heterogeneous sands. Initial results show that the model can predict spatial and temporal distribution of injected fluid during the experiments reasonably well. However, further analyses are needed for comprehensively testing the ability of the model to predict transient two-phase flow processes and capillary entrapment in geological reservoirs during geological carbon sequestration.

  6. Dynamic and spectroscopic characteristics of atmospheric gliding arc in gas-liquid two-phase flow

    SciTech Connect (OSTI)

    Tu, X.; Yu, L.; Yan, J. H.; Cen, K. F.; Cheron, B. G.

    2009-11-15

    In this study, an atmospheric alternating-current gliding arc device in gas-liquid two-phase flow has been developed for the purpose of waste water degradation. The dynamic behavior of the gas-liquid gliding arc is investigated through the oscillations of electrical signals, while the spatial evolution of the arc column is analyzed by high speed photography. Different arc breakdown regimes are reported, and the restrike mode is identified as the typical fluctuation characteristic of the hybrid gliding arc in air-water mixture. Optical emission spectroscopy is employed to investigate the active species generated in the gas-liquid plasma. The axial evolution of the OH (309 nm) intensity is determined, while the rotational and vibrational temperatures of the OH are obtained by a comparison between the experimental and simulated spectra. The significant discrepancy between the rotational and translational temperatures has also been discussed.

  7. Primary pump power as a measure of fluid density during bubbly two-phase flow. [PWR

    SciTech Connect (OSTI)

    McCreery, G.E.; Linebarger, J.H.; Koske, J.E.

    1983-01-01

    A nuclear plant operator requires other information on reactor coolant system inventory besides just pressurizer liquid level, which often disappears or gives ambiguous indications during a loss-of-coolant accident. Erroneous instrument readings during the Three Mile Island and Ginna accidents are examples. Pump power or current is shown in this paper to provide an additional source of inventory information. When the reactor coolant pumps are operating, it allows the operator to make decisions about the advisability of continued pump- and safety-injection operation. The inventory information is provided by a simple method of calculating fluid density for bubbly two-phase flow by relating pump power or current to fluid density. The calculational method is derived and compared with data in this paper. Calculations using the method agree well with the measured experimental data with increasing void fraction, until the flow transitions from bubbly to partially stratified churn flow within the pump.

  8. Vertical two-phase flow regimes and pressure gradients under the influence of SDS surfactant

    SciTech Connect (OSTI)

    Duangprasert, Tanabordee; Sirivat, Anuvat; Siemanond, Kitipat [The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok 10330 (Thailand); Wilkes, James O. [Department of Chemical Engineering, The University of Michigan, Ann Arbor, MI 48109-2136 (United States)

    2008-01-15

    Two-phase gas/liquid flows in vertical pipes have been systematically investigated. Water and SDS surfactant solutions at various concentrations were used as the working fluids. In particular, we focus our work on the influence of surfactant addition on the flow regimes, the corresponding pressure gradients, and the bubble sizes and velocity. Adding the surfactant lowers the air critical Reynolds numbers for the bubble-slug flow and the slug flow transitions. The pressure gradients of SDS solutions are lower than those of pure water especially in the slug flow and the slug-churn flow regimes, implying turbulent drag reduction. At low Re{sub air}, the bubble sizes of the surfactant solution are lower than those of pure water due to the increase in viscosity. With increasing and at high Re{sub air}, the bubble sizes of the SDS solution become greater than those of pure water which is attributed to the effect of surface tension. (author)

  9. Two-Phase Emission Detector for Measuring Coherent Neutrino-Nucleus Scattering

    E-Print Network [OSTI]

    Chris Hagmann; Adam Bernstein

    2004-11-04

    Coherent scattering is a flavor-blind, high-rate, as yet undetected neutrino interaction predicted by the Standard Model. We propose to use a compact (kg-scale), two-phase (liquid-gas) argon ionization detector to measure coherent neutrino scattering off nuclei. In our approach, neutrino-induced nuclear recoils in the liquid produce a weak ionization signal, which is transported into a gas under the influence of an electric field, amplified via electroluminescence, and detected by phototubes or avalanche diodes. This paper describes the features of the detector, and estimates signal and background rates for a reactor neutrino source. Relatively compact detectors of this type, capable of detecting coherent scattering, offer a new approach to flavor-blind detection of man-made and astronomical neutrinos, and may allow development of compact neutrino detectors capable of non-intrusive real-time monitoring of fissile material in reactors.

  10. Operation of a two-phase partitioning bioreactor for the oxidation of anthracene by the enzyme manganese peroxidase

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    Polycyclic aromatic hydrocarbons (PAHs) are ubiqui- tous pollutants released into the environment, generated are often contaminated with PAHs. There is toxicological concern about the presence of PAHs biodegradation of PAHs is mainly restricted by two factors: (i) the low water solubility of the PAHs and (ii

  11. Characterization of Flow Homogeneity Downstream of a Slotted Orifice Plate in a Two-Phase Flow Using Electrical Resistance Tomography 

    E-Print Network [OSTI]

    Annamalai, Gautham

    2015-03-03

    The accurate measurement of two-phase flow parameters has always been a key issue for many industries. Advancements in flow measurement techniques led to the development of multiphase flow meters which can measure it without separating...

  12. A computational study of ultrasonic film thickness measurements in annular two-phase flows under microgravity conditions 

    E-Print Network [OSTI]

    Pautz, Shawn Daniel

    1995-01-01

    An ultrasonic system has previously been proposed to measure interfacial characteristics of annular two-phase flows in reduced acceleration environments. A computational model based on ray tracing is developed to predict ...

  13. Development of an electrical impedance computed tomographic two-phase flows analyzer. Annual technical report for program renewal

    SciTech Connect (OSTI)

    Jones, O.C.

    1993-05-01

    This progress report details the theoretical development, numerical results, experimental design (mechanical), experimental design (electronic), and experimental results for the research program for the development of an electrical impedance computed tomographic two-phase flow analyzer.

  14. The effect of virtual mass on the characteristics and the numerical stability in two-phase flow

    E-Print Network [OSTI]

    No, H. C.

    1981-01-01

    It is known that the typical six equation two-fluid model of the two-phase flow possesses complex characteristics, exhibits unbounded instabilities in the short-wavelength limit and constitutes an ill-posed initial value ...

  15. Zero gravity two-phase flow regime transition modeling compared with data and relap5-3d predictions 

    E-Print Network [OSTI]

    Ghrist, Melissa Renee

    2009-05-15

    This thesis compares air/water two-phase flow regime transition models in zero gravity with data and makes recommendations for zero gravity models to incorporate into the RELAP5-3D thermal hydraulic computer code. Data ...

  16. Identification of two-phase flow patterns in a nuclear reactor by high-frequency contribution fraction

    SciTech Connect (OSTI)

    Wang, Y.W.; Pei, B.S. (National Tsing Hua Univ., Hsinchu (Taiwan). Dept. of Nuclear Engineering); King, C.H.; Lee, S.C. (Institute of Nuclear Energy Research, Lung-Tan (Taiwan))

    1990-02-01

    A method based on noise analysis techniques that can be applied to the identification of two-phase flow patterns in nuclear reactors is proposed. The identifying criterion, the high-frequency contribution fraction (HFCF), offers new potential to the in-core recognition of two-phase flow patterns. By analyzing 76 sets of signals acquired from a research nuclear reactor where two-phase flow patterns are generated in an in-core air/water loop, the typical signal, autocorrelogram, and spectrum of each flow pattern are demonstrated and evaluated. The identification success rate is 87 or 93%, depending on whether churn flow is counted. A method to improve the identification rate is also presented. This study demonstrates that the fluctuation characteristics above 10 Hz are induced by two-phase flow itself and are independent of the driving source; thus, it is adequate to apply the HFCF to the identification of two-phase flow patters. This study shows that it is possible to identify two-phase flow patterns by HFCF values.

  17. Steam-water two-phase flow in large diameter vertical piping at high pressures and temperatures

    SciTech Connect (OSTI)

    Hasanein, H.A.; Kawaji, Masahiro [Univ. of Toronto, Ontario (Canada); Chan, A.M.C. [Ontario Hydro Technologies, Toronto, Ontario (Canada); Yoshioka, Yuzuru [Japan Atomic Power Co., Tokyo (Japan)

    1996-08-01

    No information on steam/water two-phase flow behavior in large diameter pipes (10 inch or larger) at elevated pressures is available in the open literature. However, there are many applications, in the nuclear, chemical and petroleum industries among others where two-phase flows in large diameter pipes at elevated pressures and temperatures are encountered routinely or under accident scenarios. Experimental data on steam-water two-phase flow in a large diameter (20 inch, 50.08 cm I.D.) vertical pipe at elevated pressures and temperatures (2.8 MPa/230 C--6.4 MPa/280 C) have been obtained. Void fraction, two-phase mass flux, phase and velocity distributions as well as pressure drop along the test pipe have been measured using the Ontario Hydro Technologies (OHT) Pump Test Loop. The void fraction distributions were found to be axially symmetric and nearly flat over a wide range of two-phase flow conditions. The two-phase flow regime could be inferred from the dynamic void fluctuations data. For the 280 C tests, the flow was found to be relatively stable with bubbly flow at low average void fractions and churn turbulent or wispy-annular flow at higher void fractions. At 230 C, the flow became rather oscillatory and slugging was suspected at relatively low voids. It has also been found that the average void fractions in the test section can be determined reasonably accurately using the axial pressure drop data.

  18. Innovative Clean Coal Technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, third and fourth quarters 1994

    SciTech Connect (OSTI)

    1995-11-01

    The objective of this project is to demonstrate and evaluate commercially available selective catalytic reduction (SCR) catalysts from U.S., Japanese, and European catalyst suppliers on a high-sulfur U.S. Coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and European gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; performance of a wide variety of SCR catalyst compositions, geometries, and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small- scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The demonstration is being performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW capacity) near Pensacola, Florida. The project is funded by the U.S. Department of Energy (DOE), Southern Company Services, Inc. (SCS on behalf of the entire Southern electric system), the Electric Power Research Institute (EPRI), and Ontario Hydro. SCS is the participant responsible for managing al aspects of this project. 1 ref., 69 figs., 45 tabs.

  19. Determination of volume fractions in two-phase flows from sound speed measurement

    SciTech Connect (OSTI)

    Chaudhuri, Anirban; Sinha, Dipen N.; Osterhoudt, Curtis F.

    2012-08-15

    Accurate measurement of the composition of oil-water emulsions within the process environment is a challenging problem in the oil industry. Ultrasonic techniques are promising because they are non-invasive and can penetrate optically opaque mixtures. This paper presents a method of determining the volume fractions of two immiscible fluids in a homogenized two-phase flow by measuring the speed of sound through the composite fluid along with the instantaneous temperature. Two separate algorithms are developed by representing the composite density as (i) a linear combination of the two densities, and (ii) a non-linear fractional formulation. Both methods lead to a quadratic equation with temperature dependent coefficients, the root of which yields the volume fraction. The densities and sound speeds are calibrated at various temperatures for each fluid component, and the fitted polynomial is used in the final algorithm. We present results when the new algorithm is applied to mixtures of crude oil and process water from two different oil fields, and a comparison of our results with a Coriolis meter; the difference between mean values is less than 1%. Analytical and numerical studies of sensitivity of the calculated volume fraction to temperature changes and calibration errors are also presented.

  20. Microtomography and pore-scale modeling of two-phase Fluid Distribution

    SciTech Connect (OSTI)

    Silin, D.; Tomutsa, L.; Benson, S.; Patzek, T.

    2010-10-19

    Synchrotron-based X-ray microtomography (micro CT) at the Advanced Light Source (ALS) line 8.3.2 at the Lawrence Berkeley National Laboratory produces three-dimensional micron-scale-resolution digital images of the pore space of the reservoir rock along with the spacial distribution of the fluids. Pore-scale visualization of carbon dioxide flooding experiments performed at a reservoir pressure demonstrates that the injected gas fills some pores and pore clusters, and entirely bypasses the others. Using 3D digital images of the pore space as input data, the method of maximal inscribed spheres (MIS) predicts two-phase fluid distribution in capillary equilibrium. Verification against the tomography images shows a good agreement between the computed fluid distribution in the pores and the experimental data. The model-predicted capillary pressure curves and tomography-based porosimetry distributions compared favorably with the mercury injection data. Thus, micro CT in combination with modeling based on the MIS is a viable approach to study the pore-scale mechanisms of CO{sub 2} injection into an aquifer, as well as more general multi-phase flows.

  1. Two-phase unsaturated flow at Yucca Mountain, Nevada - A Report on Current Understanding

    SciTech Connect (OSTI)

    Pruess, K.

    1998-08-01

    The U.S. civilian nuclear waste program is unique in its focus on disposal of high-level wastes in the unsaturated zone (UZ), above the water table. The potential repository site currently under investigation is located in a semi-arid region of the southwestern U.S. at Yucca Mountain, Nevada. The geology of the site consists of layered sequences of faulted, fractured, and bedded tuffs. The groundwater table is approximately 600 m beneath the land surface, while the proposed repository horizon is at a nominal depth of approximately 375 m. In this kind of environment, two-phase flow is not just a localized perturbation to natural conditions, as in the saturated zone, but is the predominant mode of water and gas flow. The purpose of this report is to review the current understanding of gas and water flow, and mass transport, in the unique hydrogeologic environment of Yucca Mountain. Characteristics of the Yucca Mountain site are examined, and concepts and mathematical modeling approaches are described for variably saturated flow in thick unsaturated zones of fractured rock. The paper includes a brief summary of the disposal concept and repository design, as developed by a team of engineering contractors to the U.S. Department of Energy (DOE), with strong participation from the DOE National Laboratories.

  2. The Influence of Morphology on the Charge Transport in Two-Phase Disordered Organic Systems

    E-Print Network [OSTI]

    Cristiano F. Woellner; Leonardo D. Machado; Pedro A. S. Autreto; Jose A. Freire; Douglas S. Galvao

    2015-01-07

    In this work we use a three-dimensional Pauli master equation to investigate the charge carrier mobility of a two-phase system, which can mimic donor-acceptor and amorphous- crystalline bulk heterojunctions. Our approach can be separated into two parts: the morphology generation and the charge transport modeling in the generated blend. The morphology part is based on a Monte Carlo simulation of binary mixtures (donor/acceptor). The second part is carried out by numerically solving the steady-state Pauli master equation. By taking the energetic disorder of each phase, their energy offset and domain morphology into consideration, we show that the carrier mobility can have a significant different behavior when compared to a one-phase system. When the energy offset is non-zero, we show that the mobility electric field dependence switches from negative to positive at a threshold field proportional to the energy offset. Additionally, the influence of morphology, through the domain size and the interfacial roughness parameters, on the transport was also investigated.

  3. Flow Regime Identification of Co-Current Downward Two-Phase Flow With Neural Network Approach

    SciTech Connect (OSTI)

    Hiroshi Goda; Seungjin Kim; Ye Mi; Finch, Joshua P.; Mamoru Ishii [Purdue University, West Lafayette, IN 47907 (United States); Jennifer Uhle [U.S. Nuclear Regulatory Commission, Washington, DC 20555-0001 (United States)

    2002-07-01

    Flow regime identification for an adiabatic vertical co-current downward air-water two-phase flow in the 25.4 mm ID and the 50.8 mm ID round tubes was performed by employing an impedance void meter coupled with the neural network classification approach. This approach minimizes the subjective judgment in determining the flow regimes. The signals obtained by an impedance void meter were applied to train the self-organizing neural network to categorize these impedance signals into a certain number of groups. The characteristic parameters set into the neural network classification included the mean, standard deviation and skewness of impedance signals in the present experiment. The classification categories adopted in the present investigation were four widely accepted flow regimes, viz. bubbly, slug, churn-turbulent, and annular flows. These four flow regimes were recognized based upon the conventional flow visualization approach by a high-speed motion analyzer. The resulting flow regime maps classified by the neural network were compared with the results obtained through the flow visualization method, and consequently the efficiency of the neural network classification for flow regime identification was demonstrated. (authors)

  4. Two-phase flow and pressure drop in flow passages of compact heat exchangers

    SciTech Connect (OSTI)

    Wambsganss, M.W.; Jendrzejczyk, J.A.; France, D.M.

    1992-01-01

    Two-phase flow experiments were performed with air/water mixtures in a small rectangular channel measuring 9.52 {times} 1.59 mm (aspects ratio equal to 6), for applications to compact heat exchangers. Pressure drop and flow pattern definition data were obtained over a large range of mass qualities (0.0002 to 1), and in the case of flow pattern data, a large range of mass fluxes (50 to 2,000 kg/m{sup 2}s). A flow pattern map, based on visual observations and photographs of the flow patterns, is presented and compared with a map developed for a rectangular channel of the same aspect ratio but with dimensions twice those of the test channel, and with a map developed for a circular tube with the same hydraulic diameter of 3 mm. Pressure drop data are presented as a function of both mass quality and Martinelli parameter and are compared with state-of-the-art correlations and a modified Chisholm correlation. 13 refs.

  5. Random excitation forces in tube bundles subjected to two-phase cross-flow

    SciTech Connect (OSTI)

    Taylor, C.E.; Pettigrew, M.J. [AECL Research, Chalk River, Ontario (Canada). Chalk River Labs.; Currie, I.G. [Univ. of Toronto, Ontario (Canada). Dept. of Mechanical Engineering

    1996-08-01

    Data from two experimental programs have been analyzed to determine the characteristics of the random excitation forces associated with two-phase cross-flow in tube bundles. Large-scale air-water flow loops in France and Canada were used to generate the data. Tests were carried out on cantilevered, clamped-pinned, and clamped-clamped tubes in normal-square, parallel-triangular, and normal-triangular configurations. Either strain gages or force transducers were used to measure the vibration response of a centrally located tube as the tue array was subjected to a wide range of void fractions and flow rates. Power spectra were analyzed to determine the effect of parameters such as tube diameter, frequency, flow rate, void fraction, and flow regime on the random excitation forces. Normalized expressions for the excitation force power spectra were found to be flow-regime dependent. In the churn flow regime, flow rate and void fraction had very little effect on the magnitude of the excitation forces. In the bubble-plug flow regime, the excitation forces increased rapidly with flow rate and void fraction.

  6. Two-phase flow and pressure drop in flow passages of compact heat exchangers

    SciTech Connect (OSTI)

    Wambsganss, M.W.; Jendrzejczyk, J.A.; France, D.M.

    1992-02-01

    Two-phase flow experiments were performed with air/water mixtures in a small rectangular channel measuring 9.52 {times} 1.59 mm (aspects ratio equal to 6), for applications to compact heat exchangers. Pressure drop and flow pattern definition data were obtained over a large range of mass qualities (0.0002 to 1), and in the case of flow pattern data, a large range of mass fluxes (50 to 2,000 kg/m{sup 2}s). A flow pattern map, based on visual observations and photographs of the flow patterns, is presented and compared with a map developed for a rectangular channel of the same aspect ratio but with dimensions twice those of the test channel, and with a map developed for a circular tube with the same hydraulic diameter of 3 mm. Pressure drop data are presented as a function of both mass quality and Martinelli parameter and are compared with state-of-the-art correlations and a modified Chisholm correlation. 13 refs.

  7. New chemistry with gold-nitrogen complexes: synthesis and characterization of tetra-, tri-, and dinuclear gold(I) amidinate complexes. Oxidative-addition to the dinuclear gold(I) amidinate 

    E-Print Network [OSTI]

    Abdou, Hanan Elsayed

    2009-06-02

    Nitrogen ligands have been little studied with gold(I) and almost no chemistry has been described using anionic bridging nitrogen ligands. This dissertation concerns the impact of the bridging ligands amidinate, ArNHC(H)NAr, ...

  8. High-frame rate, fast neutron imaging of two-phase flow in a thin rectangular channel

    E-Print Network [OSTI]

    Zboray, R; Dangendorf, V; Stark, M; Tittelmeier, K; Cortesi, M; Adams, R

    2015-01-01

    We have demonstrated the feasibility of performing high-frame-rate, fast neutron radiography of air-water two-phase flows in a thin channel with rectangular cross section. The experiments have been carried out at the accelerator facility of the Physikalisch-Technische Bundesanstalt. A polychromatic, high-intensity fast neutron beam with average energy of 6 MeV was produced by 11.5 MeV deuterons hitting a thick Be target. Image sequences down to 10 millisecond exposure times were obtained using a fast-neutron imaging detector developed in the context of fast-neutron resonance imaging. Different two-phase flow regimes such as bubbly slug and churn flows have been examined. Two phase flow parameters like the volumetric gas fraction, bubble size and bubble velocities have been measured. The first results are promising, improvements for future experiments are also discussed.

  9. Multiparticle imaging technique for two-phase fluid flows using pulsed laser speckle velocimetry

    SciTech Connect (OSTI)

    Hassan, T.A.

    1992-12-01

    The practical use of Pulsed Laser Velocimetry (PLV) requires the use of fast, reliable computer-based methods for tracking numerous particles suspended in a fluid flow. Two methods for performing tracking are presented. One method tracks a particle through multiple sequential images (minimum of four required) by prediction and verification of particle displacement and direction. The other method, requiring only two sequential images uses a dynamic, binary, spatial, cross-correlation technique. The algorithms are tested on computer-generated synthetic data and experimental data which was obtained with traditional PLV methods. This allowed error analysis and testing of the algorithms on real engineering flows. A novel method is proposed which eliminates tedious, undersirable, manual, operator assistance in removing erroneous vectors. This method uses an iterative process involving an interpolated field produced from the most reliable vectors. Methods are developed to allow fast analysis and presentation of sets of PLV image data. Experimental investigation of a two-phase, horizontal, stratified, flow regime was performed to determine the interface drag force, and correspondingly, the drag coefficient. A horizontal, stratified flow test facility using water and air was constructed to allow interface shear measurements with PLV techniques. The experimentally obtained local drag measurements were compared with theoretical results given by conventional interfacial drag theory. Close agreement was shown when local conditions near the interface were similar to space-averaged conditions. However, theory based on macroscopic, space-averaged flow behavior was shown to give incorrect results if the local gas velocity near the interface as unstable, transient, and dissimilar from the average gas velocity through the test facility.

  10. Modeling the viscoplastic micromechanical response of two-phase materials using fast Fourier transforms

    SciTech Connect (OSTI)

    Lebensohn, Ricardo A; Lee, Sukbin; Rollett, Anthony D

    2009-01-01

    A viscoplastic approach using the Fast Fourier Transform (FFT) method for obtaining local mechanical response is utilized to study microstructure-property relationships in composite materials. Specifically, three-dimensional, two-phase digital materials containing isotropically coarsened particles surrounded by a matrix phase, generated through a Kinetic Monte Carlo Potts model for Ostwald ripening, are used as instantiations in order to calculate the stress and strain rate fields under uniaxial tension. The effects of the morphology of the matrix phase, the volume fraction and the contiguity of particles, and the polycrystallinity of matrix phase, on the stress and strain rate fields under uniaxial tension are examined. It is found that the first moments of the stress and strain rate fields have a different dependence on the particle volume fraction and the particle contiguity from their second moments. The average stresses and average strain rates of both phases and of the overall composite have rather simple relationships with the particle volume fraction whereas their standard deviations vary strongly, especially when the particle volume fraction is high, and the contiguity of particles has a noticeable effect on the mechanical response. It is also found that the shape of stress distribution in the BCC hard particle phase evolves as the volume fraction of particles in the composite varies, such that it agrees with the stress field in the BCC polycrystal as the volume of particles approaches unity. Finally, it is observed that the stress and strain rate fields in the microstructures with a polycrystalline matrix are less sensitive to changes in volume fraction and contiguity of particles.

  11. End plate assembly having a two-phase fluid-filled bladder and method for compressing a fuel cell stack

    DOE Patents [OSTI]

    Carlstrom, Jr., Charles M. (Clifton Park, NY)

    2001-01-01

    An end plate assembly is disclosed for use in a fuel cell assembly in which the end plate assembly includes a housing having a cavity, and a bladder receivable in the cavity and engageable with the fuel cell stack. The bladder includes a two-phase fluid having a liquid portion and a vapor portion. Desirably, the two-phase fluid has a vapor pressure between about 100 psi and about 600 psi at a temperature between about 70 degrees C. to about 110 degrees C.

  12. Interphase mass transfer in cocurrent vertical two-phase channel flows with non-Newtonian liquids

    SciTech Connect (OSTI)

    Luo, D.; Ghiaasiaan, S.M. [Georgia Inst. of Tech., Atlanta, GA (United States). G.W. Woodruff School of Mechanical Engineering] [Georgia Inst. of Tech., Atlanta, GA (United States). G.W. Woodruff School of Mechanical Engineering

    1997-01-01

    Flow patterns, gas hold-up, and volumetric liquid-side interphase mass transfer coefficients were experimentally studied using aqueous solutions of Polyacrylamide as the liquid phase, pure nitrogen as the gas phase, and oxygen as the transferred species. The channel entrance effects were eliminated by performing hydrodynamically-identical tests with two different test section lengths, and using the shorter test section results for quantification of entrance effects in the longer test section. Experimental data were obtained over a range of gas and liquid superficial velocities covering the bubbly, slug and churn flow regimes and were compared with data previously obtained with pure water and aqueous sucrose solutions. The effect of the liquid-phase rheological properties on channel hydrodynamic and mass transfer processes were examined.

  13. The Nitrogen-Nitride Anode.

    SciTech Connect (OSTI)

    Delnick, Frank M.

    2014-10-01

    Nitrogen gas N 2 can be reduced to nitride N -3 in molten LiCl-KCl eutectic salt electrolyte. However, the direct oxidation of N -3 back to N 2 is kinetically slow and only occurs at high overvoltage. The overvoltage for N -3 oxidation can be eliminated by coordinating the N -3 with BN to form the dinitridoborate (BN 2 -3 ) anion which forms a 1-D conjugated linear inorganic polymer with -Li-N-B-N- repeating units. This polymer precipitates out of solution as Li 3 BN 2 which becomes a metallic conductor upon delithiation. Li 3 BN 2 is oxidized to Li + + N 2 + BN at about the N 2 /N -3 redox potential with very little overvoltage. In this report we evaluate the N 2 /N -3 redox couple as a battery anode for energy storage.

  14. Flow regime mapping of vertical two-phase downflow in a ribbed annulus

    SciTech Connect (OSTI)

    Kielpinski, A.L.

    1992-01-01

    Two-phase flow regimes have been mapped for vertical, cocurrent downflow in a narrow annulus which is partially segmented by the presence of longitudinal ribs. This geometry and flow condition has application to the analysis of a Large-Break Loss of Coolant Accident (LB-LOCA) in the production K-Reactor at the Savannah River Site (SRS). The ribbed annular geometry, particularly the presence of non-sealing ribs, gives rise to some unique phenomenological features. The flow behavior is influenced by the partial segmentation of the annulus into four quadrants or subchannels. A random element is induced by the natural bowing of the slender tubes; the width of the azimuthal flow path between two subchannels at a given axial location is indeterminate, and can take on any value between zero and the maximum clearance of 7.6 [times] l0[sup [minus]4] m. When the rib gap is zero at a given location, it is at a maximum 180P away at the same axial location. The range of rib gaps is spanned in a single test section, as it would be also in a reactor assembly. As a result of these effects, flow regime maps obtained by other researchers for downflow in annuli are not accurate for defining flow regimes in a ribbed annulus. Flow regime transitions similar to those noted by, e.g., Bamea, were observed; the locations of these transitions were displaced with respect to the transition equations derived by Bamea. Experimental bubble rise velocity measurements were also obtained in the same test section. The bubble rise velocities were much higher than expected from the theory developed for slug bubbles in tubes, unribbed annuli, and rectangular channels. An elliptical-cap bubble rises faster than a slug bubble of the same area. Large, slug-shaped bubbles injected into the test section were observed to reduce in size as they rose, due to interaction with a longitudinal rib. They thereby adopted a shape more like an elliptical-cap bubble, hence rising faster than the original slug bubble.

  15. Flow regime mapping of vertical two-phase downflow in a ribbed annulus

    SciTech Connect (OSTI)

    Kielpinski, A.L.

    1992-12-01

    Two-phase flow regimes have been mapped for vertical, cocurrent downflow in a narrow annulus which is partially segmented by the presence of longitudinal ribs. This geometry and flow condition has application to the analysis of a Large-Break Loss of Coolant Accident (LB-LOCA) in the production K-Reactor at the Savannah River Site (SRS). The ribbed annular geometry, particularly the presence of non-sealing ribs, gives rise to some unique phenomenological features. The flow behavior is influenced by the partial segmentation of the annulus into four quadrants or subchannels. A random element is induced by the natural bowing of the slender tubes; the width of the azimuthal flow path between two subchannels at a given axial location is indeterminate, and can take on any value between zero and the maximum clearance of 7.6 {times} l0{sup {minus}4} m. When the rib gap is zero at a given location, it is at a maximum 180P away at the same axial location. The range of rib gaps is spanned in a single test section, as it would be also in a reactor assembly. As a result of these effects, flow regime maps obtained by other researchers for downflow in annuli are not accurate for defining flow regimes in a ribbed annulus. Flow regime transitions similar to those noted by, e.g., Bamea, were observed; the locations of these transitions were displaced with respect to the transition equations derived by Bamea. Experimental bubble rise velocity measurements were also obtained in the same test section. The bubble rise velocities were much higher than expected from the theory developed for slug bubbles in tubes, unribbed annuli, and rectangular channels. An elliptical-cap bubble rises faster than a slug bubble of the same area. Large, slug-shaped bubbles injected into the test section were observed to reduce in size as they rose, due to interaction with a longitudinal rib. They thereby adopted a shape more like an elliptical-cap bubble, hence rising faster than the original slug bubble.

  16. Experimental and theoretical scaling laws for transverse diffusive broadening in two-phase laminar flows in microchannels

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Experimental and theoretical scaling laws for transverse diffusive broadening in two-phase laminar in pressure-driven laminar flow in microchannels at high Pe´clet numbers. Confocal fluorescent microscopy, such as described in this letter, is required for the rational use of laminar flows for performing spatially

  17. characterization and visualization of two-phase flow properties of gas diffusion layers used in a PEM fuel cell

    E-Print Network [OSTI]

    Gao, Yan

    2011-04-26

    Due to the low-temperature operation of Polymer Electrolyte Membrane fuel cell (PEMFC), liquid water can build up in either flow channels or gas diffusion layers (GDL). Better understanding of the effect of two-phase transport properties on liquid...

  18. THERMAL DESIGN METHODOLOGY FOR LOW FLOW RATE SINGLE-PHASE AND TWO-PHASE MICRO-CHANNEL HEAT SINKS

    E-Print Network [OSTI]

    Qu, Weilin

    THERMAL DESIGN METHODOLOGY FOR LOW FLOW RATE SINGLE-PHASE AND TWO-PHASE MICRO-CHANNEL HEAT SINKS-phase micro- channel heat sinks under a fixed liquid coolant flow rate. The parameters relevant to heat sink-channel dimensions corresponding to the prescribed dissipative heat flux and liquid coolant flow rate. Heat sink

  19. On the Riemann Problem for a Hyperbolic TwoPhase D. Zeidan a,# , E. Toro b and A. Slaouti c

    E-Print Network [OSTI]

    . Slaouti c a Department of Computing and Mathematics Manchester Metropolitan University, Manchester M1 5GD is hyperbolic, Godunov­type numerical methods for the model can be employed using locally approximate analytical accuracy as achieved using MUSCL­Hancock and WAF [3, 4] schemes. The numerical results for two­phase shock

  20. A phase-field method for 3D simulation of two-phase heat transfer , H. Babaee a

    E-Print Network [OSTI]

    Dong, Suchuan "Steven"

    A phase-field method for 3D simulation of two-phase heat transfer X. Zheng a , H. Babaee a , S s t r a c t We formulate new multi-phase convective heat transfer equations by combining the three for convergence in time/space including a conjugate heat transfer problem and also for a realistic tran- sient

  1. Polymer Development for Enhanced Delivery of Phenol in a Solid-Liquid Two-Phase Partitioning Bioreactor

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    Polymer Development for Enhanced Delivery of Phenol in a Solid-Liquid Two-Phase Partitioning liquid TPPBs to the use of pure strains of microbes. Solid polymer beads have recently been introduced to be used with mixed microbial populations. The present work was aimed at identifying a polymer

  2. Fixation of nitrogen in the presence of water vapor

    DOE Patents [OSTI]

    Harteck, Paul (Santa Barbara, CA)

    1984-01-01

    A process for the fixation of nitrogen is disclosed which comprises combining a mixture of nitrogen, oxygen, metal oxide and water vapor, initially heating the combination to initiate a reaction which forms nitrate, but at a temperature and pressure range below the dissociation pressure of the nitrate. With or without the water component, the yield of fixed nitrogen is increased by the use of a Linde Molecular Sieve Catalyst.

  3. On-Road Emission Measurements of Reactive Nitrogen Compounds from

    E-Print Network [OSTI]

    Denver, University of

    - equippedvehiclesarenotbelievedtobesignificant(1).Oxides of nitrogen (NOx) emission rates from light-duty gasoline vehicles have been shown to be rapidly decreasing across the United States, but total NOx emissions are decreasing at a slower rate dueOn-Road Emission Measurements of Reactive Nitrogen Compounds from Three California Cities G A R Y

  4. Schematic structure of nitrogen-doped graphene showing carbon

    E-Print Network [OSTI]

    Gong, Jian Ru

    method for graphene doping, and is compatible with current complementary metal oxide semiconductor (CMOSSchematic structure of nitrogen- doped graphene showing carbon (gray) and nitrogen (blue) NPG Asia Materials research highlight | doi:10.1038/asiamat.2010.204 Published online 13 December 2010 Graphene

  5. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Topical report, LNCFS Levels 1 and 3 test results

    SciTech Connect (OSTI)

    Not Available

    1993-08-17

    This report presents results from the third phase of an Innovative Clean Coal Technology (ICC-1) project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The purpose of this project was to study the NO{sub x} emissions characteristics of ABB Combustion Engineering`s (ABB CE) Low NO{sub x} Concentric Firing System (LNCFS) Levels I, II, and III. These technologies were installed and tested in a stepwise fashion at Gulf Power Company`s Plant Lansing Smith Unit 2. The objective of this report is to provide the results from Phase III. During that phase, Levels I and III of the ABB C-E Services Low NO{sub x} Concentric Firing System were tested. The LNCFS Level III technology includes separated overfire air, close coupled overfire air, clustered coal nozzles, flame attachment coal nozzle tips, and concentric firing. The LNCFS Level I was simulated by closing the separated overfire air nozzles of the LNCFS Level III system. Based upon long-term data, LNCFS Level HI reduced NO{sub x} emissions by 45 percent at full load. LOI levels with LNCFS Level III increased slightly, however, tests showed that LOI levels with LNCFS Level III were highly dependent upon coal fineness. After correcting for leakage air through the separated overfire air system, the simulated LNCFS Level I reduced NO{sub x} emissions by 37 percent. There was no increase in LOI with LNCFS Level I.

  6. Continued development of a semianalytical solution for two-phase fluid and heat flow in a porous medium

    SciTech Connect (OSTI)

    Doughty, C.; Pruess, K. [Lawrence Berkeley Lab., CA (United States)

    1991-06-01

    Over the past few years the authors have developed a semianalytical solution for transient two-phase water, air, and heat flow in a porous medium surrounding a constant-strength linear heat source, using a similarity variable {eta} = r/{radical}t. Although the similarity transformation approach requires a simplified geometry, all the complex physical mechanisms involved in coupled two-phase fluid and heat flow can be taken into account in a rigorous way, so that the solution may be applied to a variety of problems of current interest. The work was motivated by adverse to predict the thermohydrological response to the proposed geologic repository for heat-generating high-level nuclear wastes at Yucca Mountain, Nevada, in a partially saturated, highly fractured volcanic formation. The paper describes thermal and hydrologic conditions near the heat source; new features of the model; vapor pressure lowering; and the effective-continuum representation of a fractured/porous medium.

  7. Electrochemical process for the preparation of nitrogen fertilizers

    DOE Patents [OSTI]

    Aulich, Ted R. (Grand Forks, ND); Olson, Edwin S. (Grand Forks, ND); Jiang, Junhua (Grand Forks, ND)

    2012-04-10

    The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia, at low temperature and pressure, preferably at ambient temperature and pressure, utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen or hydrogen equivalent. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source or a hydrogen equivalent such as carbon monoxide or a mixture of carbon monoxide and hydrogen at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be aqueous, non-aqueous, or solid.

  8. Process for preparing zinc oxide-based sorbents

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar (Cary, NC); Turk, Brian Scott (Durham, NC); Gupta, Raghubir Prasad (Durham, NC)

    2011-06-07

    The disclosure relates to zinc oxide-based sorbents, and processes for preparing and using them. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  9. Nitrogen Deposition: A Component of Global Change Analyses

    SciTech Connect (OSTI)

    Norby, Richard J.

    1997-12-31

    The global cycles of carbon and nitrogen are being perturbed by human activities that increase the transfer from large pools of nonreactive forms of the elements to reactive forms that are essential to the functioning of the terrestrial biosphere. The cycles are closely linked at all scales, and global change analyses must consider carbon and nitrogen cycles together. The increasing amount of nitrogen originating from fossil fuel combustion and deposited to terrestrial ecosystems as nitrogen oxides could increase the capacity of ecosystems to sequester carbon thereby removing some of the excess carbon dioxide from the atmosphere and slowing the development of greenhouse warming. Several global and ecosystem models have calculated the amount of carbon sequestration that can be attributed to nitrogen deposition based on assumptions about the allocation of nitrogen among ecosystem components with different carbon-nitrogen ratios. They support the premise that nitrogen deposition is responsible for a an increasing terrestrial carbon sink since industrialization began, but there are large uncertainties related to the continued capacity of ecosystems to retain exogenous nitrogen. Whether terrestrial ecosystems continue to sequester additional carbon will depend in part on their response to increasing atmospheric carbon dioxide concentrations, which is widely thought to be constrained by limited nitrogen availability. Ecosystem models generally support the conclusion that the responses of ecosystems to increasing concentrations of carbon dioxide will be larger, and the range of possible responses will be wider, in ecosystems with increased nitrogen inputs originating as atmospheric deposition.

  10. Experimental and numerical investigation of shock wave propagation through complex geometry, gas continuous, two-phase media

    SciTech Connect (OSTI)

    Liu, J. Chien-Chih [California Univ., Berkeley, CA (United States)

    1993-10-01

    The work presented here investigates the phenomenon of shock wave propagation in gas continuous, two-phase media. The motivation for this work stems from the need to understand blast venting consequences in the HYLIFE inertial confinement fusion (ICF) reactor. The HYLIFE concept utilizes lasers or heavy ion beams to rapidly heat and compress D-T targets injected into the center of a reactor chamber. A segmented blanket of failing molten lithium or Li{sub 2}BeF{sub 4} (Flibe) jets encircles the reactors central cavity, shielding the reactor structure from radiation damage, absorbing the fusion energy, and breeding more tritium fuel.

  11. 0-g annular flow and 1-g stratified flow single component two-phase condensation modeling and experiments 

    E-Print Network [OSTI]

    Baranek, Pascale

    1993-01-01

    on the behavior of condensing two-phase flow in 0- g. Therefore s. new model was developed for condensing 0-g annular flow, using the universal velocity profile, the Karmsn momentum-heat transfer analogy and Wheeler's correlations for film thickness... the vapor and the condensate layer, he performed a momentum balance on the bulk liquid, and was able to estimate the profile of the bottom condensate layer and to define the area covered by the condensate film. Chaddock postulated that heat transfer...

  12. Two phase partially miscible flow and transport modeling in porous media: application to gas migration in a nuclear waste repository

    E-Print Network [OSTI]

    Bourgeat, Alain; Smaï, Farid

    2008-01-01

    We derive a compositional compressible two-phase, liquid and gas, flow model for numerical simulations of hydrogen migration in deep geological repository for radioactive waste. This model includes capillary effects and the gas high diffusivity. Moreover, it is written in variables (total hydrogen mass density and liquid pressure) chosen in order to be consistent with gas appearance or disappearance. We discuss the well possedness of this model and give some computational evidences of its adequacy to simulate gas generation in a water saturated repository.

  13. Two phase partially miscible flow and transport modeling in porous media: application to gas migration in a nuclear waste repository

    E-Print Network [OSTI]

    Alain Bourgeat; Mladen Jurak; Farid Smaï

    2008-02-29

    We derive a compositional compressible two-phase, liquid and gas, flow model for numerical simulations of hydrogen migration in deep geological repository for radioactive waste. This model includes capillary effects and the gas high diffusivity. Moreover, it is written in variables (total hydrogen mass density and liquid pressure) chosen in order to be consistent with gas appearance or disappearance. We discuss the well possedness of this model and give some computational evidences of its adequacy to simulate gas generation in a water saturated repository.

  14. Experimental and numerical investigation of shock wave propagation through complex geometry, gas continuous, two-phase media

    SciTech Connect (OSTI)

    Chien-Chih Liu, J.

    1993-12-31

    The work presented here investigates the phenomenon of shock wave propagation in gas continuous, two-phase media. The motivation for this work stems from the need to understand blast venting consequences in the HYLIFE inertial confinement fusion (ICF) reactor. The HYLIFE concept utilizes lasers or heavy ion beams to rapidly heat and compress D-T targets injected into the center of a reactor chamber. A segmented blanket of falling molten lithium or Li{sub 2}BeF{sub 4} (Flibe) jets encircles the reactor`s central cavity, shielding the reactor structure from radiation damage, absorbing the fusion energy, and breeding more tritium fuel. X-rays from the fusion microexplosion will ablate a thin layer of blanket material from the surfaces which face toward the fusion site. This generates a highly energetic vapor, which mostly coalesces in the central cavity. The blast expansion from the central cavity generates a shock which propagates through the segmented blanket - a complex geometry, gas-continuous two-phase medium. The impulse that the blast gives to the liquid as it vents past, the gas shock on the chamber wall, and ultimately the liquid impact on the wall are all important quantities to the HYLIFE structural designers.

  15. GEOMETRIC SINGULAR PERTURBATION ANALYSIS OF OXIDATION HEAT PULSES

    E-Print Network [OSTI]

    Schecter, Stephen

    reaction. We show that for small heat loss, this combustion front is actually the lead part of a pulseGEOMETRIC SINGULAR PERTURBATION ANALYSIS OF OXIDATION HEAT PULSES FOR TWO-PHASE FLOW IN POROUS, and oxidation or combustion is induced, a combustion front forms if heat loss to the surrounding rock for

  16. Fluidized-bed copper oxide process

    SciTech Connect (OSTI)

    Shah, P.P.; Takahashi, G.S.; Leshock, D.G.

    1991-10-14

    The fluidized-bed copper oxide process was developed to simultaneously remove sulfur dioxide and nitrogen oxide contaminants from the flue gas of coal-fired utility boilers. This dry and regenerable process uses a copper oxide sorbent in a fluidized-bed reactor. Contaminants are removed without generating waste material. (VC)

  17. Modeling the Oxidative Capacity of the Atmosphere of the South Coast

    E-Print Network [OSTI]

    Dabdub, Donald

    of the complex chemistry involving volatile organic compounds (VOCs) and oxides of nitrogen (NOx ) nitrogen oxide (NO) + nitrogen dioxide (NO2))(1).O3 productionisinitiatedbyreactionsthatgenerate HOx radicals Air Basin of California (SoCAB). P(O3) indicates the rapid nature of O3 formation under peak

  18. Bioengineering nitrogen acquisition in rice

    E-Print Network [OSTI]

    Kronzucker, Herbert J.

    gas prices caused the price of nitrogen fertilizer to nearly double.(7) Increased nitrogen use is also nitrogen application is not an ideal solution, partly from a cost perspective--in 2001, increased natural

  19. Measurement of void fraction at different flow regimes in vertical upward two-phase flow of cryogenic fluid

    SciTech Connect (OSTI)

    Pattanayak, S.Ch.; Das, R.K. [Indian Institute of Technology, Kharagpur (India)

    1995-12-01

    Local void fraction in a vertical cryogenic two-phase flow has been measured with the help of a small capacitance sensor. The time varying capacitance signal of the sensor is used to modulate the pulse width of a multivibrator. The probability distribution function (PDF) of the pulse width data is analysed for identifying the flow regimes, while average pulse width is correlated with the average void fraction. The calibrations of the void fraction sensor are found to be sensitive to the flow regimes. In slug and churn flow regimes the calibrations are also found to be sensitive to fluid flow rates. But no such dependence is observed in bubble and annular flow regimes. The sensitivity towards flow rates could be correlated with the position of PDF peaks of the concerned flow regimes.

  20. Theoretical and empirical study of single-substance, upward two-phase flow in a constant-diameter adiabatic pipe

    SciTech Connect (OSTI)

    Laoulache, R.N.; Maeder, P.F.; DiPippo, R.

    1987-05-01

    A Scheme is developed to describe the upward flow of a two-phase mixture of a single substance in a vertical adiabatic constant area pipe. The scheme is based on dividing the mixture into a homogeneous core surrounded by a liquid film. This core may be a mixture of bubbles in a contiguous liquid phase, or a mixture of droplets in a contiguous vapor phase. Emphasis is placed upon the latter case since the range of experimental measurements of pressure, temperature, and void fraction collected in this study fall in the slug-churn''- annular'' flow regimes. The core is turbulent, whereas the liquid film may be laminar or turbulent. Turbulent stresses are modeled by using Prandtl's mixing-length theory. The working fluid is Dichlorotetrafluoroethane CCIF{sub 2}-CCIF{sub 2} known as refrigerant 114 (R-114); the two-phase mixture is generated from the single phase substance by the process of flashing. In this study, the effect of the Froude and Reynolds numbers on the liquid film characteristics is examined. The compressibility is accounted for through the acceleration pressure gradient of the core and not directly through the Mach number. An expression for an interfacial friction coefficient between the turbulent core and the liquid film is developed; it is similar to Darcy's friction coefficient for a single phase flow in a rough pipe. Finally, an actual steam-water geothermal well is simulated; it is based on actual field data from New Zealand. A similarity theory is used to predict the steam-water mixture pressure and temperature starting with laboratory measurements on the flow of R-114.

  1. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, D. Kwok-Keung; Chang, Shih-Ger

    1987-08-25

    The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

  2. Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

    2011-09-28

    This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

  3. The biogeochemistry of marine nitrous oxide

    E-Print Network [OSTI]

    Frame, Caitlin H

    2011-01-01

    Atmospheric nitrous oxide N?O concentrations have been rising steadily for the past century as a result of human activities. In particular, human perturbation of the nitrogen cycle has increased the N?O production rates ...

  4. Turn-on fluorescent probes for detecting nitric oxide in biology

    E-Print Network [OSTI]

    McQuade, Lindsey Elizabeth, 1981-

    2010-01-01

    Chapter 1. Investigating the Biological Roles of Nitric Oxide and Other Reactive Nitrogen Species Using Fluorescent Probes: This chapter presents an overview of recent progress in the field of reactive nitrogen species ...

  5. Study of fuel-nitrogen reactions in rich, premixed flames

    SciTech Connect (OSTI)

    Roby, R.J.

    1988-01-01

    The formation and removal of nitrogen-containing species involved in fuel-nitrogen reactions have been studied in atmospheric-pressure fuel-rich hydrogen/oxygen/argon flames. The fuel-nitrogen reaction mechanism was investigated by addition of ammonia, nitric oxide, or hydrogen cyanide alone or with various hydrocarbons to a base flame. Profiles of stable nitrogen species and hydroxyl radical were measured in the post-flame gases. Results show that an initial rapid decay of nitric oxide added to a hydrogen/oxygen/argon flame to approximately 60% of its initial value occurs within 1.0 mm of the burner surface (0.5 msec). The primary reaction for removal of nitric oxide was found to be H + NO + M = HNO + M. The reaction of nitric oxide with various hydrocarbons to form hydrogen cyanide was found to be first order in both the initial hydrocarbon concentration and the initial nitric oxide concentration. A kinetic model was developed that only partially predicts the results obtained. Analysis showed that, by varying the heat of formation of imidogen within the limits of its uncertainty, agreement between the calculations and the data could be improved for nitric oxide and nitrogen. However, the amine, nitrous oxide and hydrogen cyanide profiles were found not to be significantly affected. The significant discrepancy between the measured and calculated ammonia profiles is discussed in terms of the model predictions of both the ammonia formation and decay rates. The reaction: NM + H = N + H/sub 2/ is identified as a key rate-controlling step for removal of amine species in these flames. Evidence from the data and theoretical calculations suggests that the rate of this reaction at the current flame conditions may be as much as a factor of ten slower than the previously reported value.

  6. RELAP5 Model of a Two-phase ThermoSyphon Experimental Facility for Fuels and Materials Irradiation

    SciTech Connect (OSTI)

    Carbajo, Juan J; McDuffee, Joel Lee

    2013-01-01

    The High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) does not have a separate materials-irradiation flow loop and requires most materials and all fuel experiments to be placed inside a containment. This is necessary to ensure that internal contaminants such as fission products cannot be released into the primary coolant. As part of the safety basis justification, HFIR also requires that all experiments be able to withstand various accident conditions (e.g., loss of coolant) without generating vapor bubbles on the surface of the experiment in the primary coolant. As with any parallel flow system, HFIR is vulnerable to flow excursion events when vapor is generated in one of those flow paths. The effects of these requirements are to artificially increase experiment temperatures by introducing a barrier between the experimental materials and the HFIR coolant and to reduce experiment heat loads to ensure boiling doesn t occur. A new experimental facility for materials irradiation and testing in the HFIR is currently being developed to overcome these limitations. The new facility is unique in that it will have its own internal cooling flow totally independent of the reactor primary coolant and boiling is permitted. The reactor primary coolant will cool the outside of this facility without contacting the materials inside. The ThermoSyphon Test Loop (TSTL), a full scale prototype of the proposed irradiation facility to be tested outside the reactor, is being designed and fabricated (Ref. 1). The TSTL is a closed system working as a two-phase thermosyphon. A schematic is shown in Fig. 1. The bottom central part is the boiler/evaporator and contains three electric heaters. The vapor generated by the heaters will rise and be condensed in the upper condenser, the condensate will drain down the side walls and be circulated via a downcomer back into the bottom of the boiler. An external flow system provides coolant that simulates the HFIR primary coolant. The two-phase flow code RELAP5-3D (Ref. 2) is the main tool employed in this design. The model has multiple challenges: boiling, condensation and natural convection flows need to be modeled accurately.

  7. Effects of aspect ratios on internal flow patterns of an inclined closed two-phase thermosyphon at normal operating condition

    SciTech Connect (OSTI)

    Terdtoon, P.; Chailungkar, M. [Chiang Mai Univ. (Thailand). Dept. of Mechanical Engineering; Shiraishi, M. [MITI, Tsukuba, Ibaraki (Japan). Mechanical Engineering Lab.

    1998-10-01

    A visual study of internal flow patterns inside an inclined closed two-phase thermosyphon at normal operating conditions for several aspect ratios has been conducted. The article describes the details of the flow patterns varying with inclination angles and aspect ratios. A thermosyphon with a diameter of 11.1 mm was used. R123 was selected as the working fluid, with a vapor temperature of 30 C and a filling ratio of 80%. Observation of the flow phenomena was conducted at selected inclination angles of 90{degree}, 30{degree}, and 5{degree} from the horizontal axis, with aspect ratios of 30, 10, and 5. Flow phenomena were recorded with a standard video camera and a still camera, and the corresponding heat transfer rate was also monitored. It was observed that the basic internal flow patterns could be classified according to the aspect ratios as follows: At an aspect ratio of 10 and higher, the internal flow changed from annular and churn flow at the vertical position to a stratified slug flow in the inclined position, and there was an improvement in heat transfer rates between the vertical and the inclined positions. However, in the case of an aspect ratio less than 10, tilting the thermosyphon from vertical did not result in changing the internal bubbly flow. It was observed that the improvement in heat transfer rates in this case was likely to be higher than in the previous case.

  8. Two-Phase Void Drift Phenomena in a 2 x 3 Rod Bundle: Flow Redistribution Data and Their Analysis

    SciTech Connect (OSTI)

    Sadatomi, Michio; Kawahara, Akimaro; Kuno, Tsukasa; Kano, Keiko [Kumamoto University (Japan)

    2005-10-15

    To improve a void drift model used in a subchannel analysis, new experimental data are obtained for air-water two-phase flows in a vertical 2 x 3 rod channel consisting of six subchannels simulating a square array boiling water reactor fuel rod bundle. The data include the axial redistributions of flow rates of both phases and void fraction in the respective subchannels. By fitting the above data with the Lahey and Moody void settling model, we have determined a void diffusion coefficient in their model. It is found that the void diffusion coefficient for slug, churn, and annular flows could be well correlated in terms of a turbulent Peclet number developed in our previous study. Furthermore, a subchannel analysis code based on a two-fluid model proposed in our previous study is examined against the present data. In the code, the void settling model is incorporated with usual conservation equations of mass and momentum. From the examination, it is found that the subchannel analysis code can predict well the data on subchannel flow and void fraction for the 2 x 3 rod channel if appropriate correlations are adopted to evaluate wall and interfacial friction forces needed in the two-fluid model.

  9. Fractal flow patterns in hydrophobic microfluidic pore networks: experimental modeling of two-phase flow in porous electrodes

    E-Print Network [OSTI]

    Berejnov, Viatcheslav; Sinton, David; Djilali, Ned

    2009-01-01

    Experimental two-phase invasion percolation flow patterns were observed in hydrophobic micro-porous networks designed to model fuel cell specific porous media. In order to mimic the operational conditions encountered in the porous electrodes of polymer electrolyte membrane fuel cells (PEMFCs), micro-porous networks were fabricated with corresponding microchannel size distributions. The inlet channels were invaded homogeneously with flow rates corresponding to fuel cell current densities of 1.0 to 0.1 A/cm2 (Ca 10e-7-10e-8). A variety of fractal breakthrough patterns were observed and analyzed to quantify flooding density and geometrical diversity in terms of the total saturation, St, local saturations, s, and fractal dimension, D. It was found that St increases monotonically during the invasion process until the breakthrough point is reached, and s profiles indicate the dynamic distribution of the liquid phase during the process. Fractal analysis confirmed that the experiments fall within the flow regime of i...

  10. Discontinuous non-equilibrium phase transition in a threshold Schloegl model for autocatalysis: Generic two-phase coexistence and metastability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Chi -Jen; Liu, Da -Jiang; Evans, James W.

    2015-04-28

    Threshold versions of Schloegl’s model on a lattice, which involve autocatalytic creation and spontaneous annihilation of particles, can provide a simple prototype for discontinuous non-equilibrium phase transitions. These models are equivalent to so-called threshold contact processes. A discontinuous transition between populated and vacuum states can occur selecting a threshold of N ? 2 for the minimum number, N, of neighboring particles enabling autocatalytic creation at an empty site. Fundamental open questions remain given the lack of a thermodynamic framework for analysis. For a square lattice with N = 2, we show that phase coexistence occurs not at a unique valuemore »but for a finite range of particle annihilation rate (the natural control parameter). This generic two-phase coexistence also persists when perturbing the model to allow spontaneous particle creation. Such behavior contrasts both the Gibbs phase rule for thermodynamic systems and also previous analysis for this model. We find metastability near the transition corresponding to a non-zero effective line tension, also contrasting previously suggested critical behavior. As a result, mean-field type analysis, extended to treat spatially heterogeneous states, further elucidates model behavior.« less

  11. Removal of nitrogen and sulfur from oil-shale

    SciTech Connect (OSTI)

    Olmstead, W.N.

    1986-01-28

    This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

  12. Zinc-oxide-based sorbents and processes for preparing and using same

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar (Cary, NC); Turk, Brian Scott (Durham, NC); Gupta, Raghubir Prasael (Durham, NC)

    2010-03-23

    Zinc oxide-based sorbents, and processes for preparing and using them are provided. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  13. Zinc oxide-based sorbents and processes for preparing and using same

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar; Turk, Brian Scott; Gupta, Raghubir Prasad

    2005-10-04

    Zinc oxide-based sorbents, and processes for preparing and using them are provided, wherein the sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents contain an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2 O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, containing a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  14. Multiparticle imaging technique for two-phase fluid flows using pulsed laser speckle velocimetry. Final report, September 1988--November 1992

    SciTech Connect (OSTI)

    Hassan, T.A.

    1992-12-01

    The practical use of Pulsed Laser Velocimetry (PLV) requires the use of fast, reliable computer-based methods for tracking numerous particles suspended in a fluid flow. Two methods for performing tracking are presented. One method tracks a particle through multiple sequential images (minimum of four required) by prediction and verification of particle displacement and direction. The other method, requiring only two sequential images uses a dynamic, binary, spatial, cross-correlation technique. The algorithms are tested on computer-generated synthetic data and experimental data which was obtained with traditional PLV methods. This allowed error analysis and testing of the algorithms on real engineering flows. A novel method is proposed which eliminates tedious, undersirable, manual, operator assistance in removing erroneous vectors. This method uses an iterative process involving an interpolated field produced from the most reliable vectors. Methods are developed to allow fast analysis and presentation of sets of PLV image data. Experimental investigation of a two-phase, horizontal, stratified, flow regime was performed to determine the interface drag force, and correspondingly, the drag coefficient. A horizontal, stratified flow test facility using water and air was constructed to allow interface shear measurements with PLV techniques. The experimentally obtained local drag measurements were compared with theoretical results given by conventional interfacial drag theory. Close agreement was shown when local conditions near the interface were similar to space-averaged conditions. However, theory based on macroscopic, space-averaged flow behavior was shown to give incorrect results if the local gas velocity near the interface as unstable, transient, and dissimilar from the average gas velocity through the test facility.

  15. Nitrogen is a deep acceptor in ZnO

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tarun, M. C.; Iqbal, M. Zafar; McCluskey, M. D.

    2011-04-14

    Zinc oxide is a promising material for blue and UV solid-state lighting devices, among other applications. Nitrogen has been regarded as a potential p-type dopant for ZnO. However, recent calculations indicate that nitrogen is a deep acceptor. This paper presents experimental evidence that nitrogen is, in fact, a deep acceptor and therefore cannot produce p-type ZnO. A broad photoluminescence (PL) emission band near 1.7 eV, with an excitation onset of ~2.2 eV, was observed, in agreement with the deep-acceptor model of the nitrogen defect. Thus the deep-acceptor behavior can be explained by the low energy of the ZnO valence bandmore »relative to the vacuum level.« less

  16. A study on the characteristics of upward air-water two-phase flow in a large diameter pipe

    SciTech Connect (OSTI)

    Shen, Xiuzhong; Saito, Yasushi; Mishima, Kaichiro [Research Reactor Institute, Kyoto University, Kumatori-cho, Sennan-gun, Osaka 590-0494 (Japan); Nakamura, Hideo [Nuclear Safety Research Center, Japan Atomic Energy Agency, Tokai-mura, Ibaraki 319-1195 (Japan)

    2006-10-15

    An adiabatic upward co-current air-water two-phase flow in a vertical large diameter pipe (inner diameter, D: 0.2m, ratio of pipe length to diameter, L/D: 60.5) was experimentally investigated under various inlet conditions. Flow regimes were visually observed, carefully analyzed and classified into five, i.e. undisturbed bubbly, agitated bubbly, churn bubbly, churn slug and churn froth. Void fraction, bubble frequency, Sauter mean diameter, interfacial area concentration (IAC) and interfacial direction were measured with four-sensor optical probes. Both the measured void fraction and the measured IAC demonstrated radial core-peak distributions in most of the flow regimes and radial wall peak in the undisturbed bubbly flow only. The bubble frequency also showed a wall-peak radial distribution only when the bubbles were small in diameter and the flow was in the undisturbed bubbly flow. The Sauter mean diameter of bubbles did not change much in the radial direction in undisturbed bubbly, agitated bubbly and churn bubbly flows and showed a core-peak radial distribution in the churn slug flow due to the existence of certain amount of large and deformed bubbles in this flow regime. The measurements of interfacial direction showed that the main and the secondary bubbly flow could be displayed by the main flow peak and the secondary flow peak, respectively, in the probability density function (PDF) of the interfacial directional angle between the interfacial direction and the z-axis, {eta}{sub zi}. The local average {eta}{sub zi }at the bubble front or rear hemisphere ({eta}{sub zi}{sup F} and {eta}{sub zi}{sup R}) reflected the local bubble movement and was in direct connection with the flow regimes. Based on the analysis, the authors classified the flow regimes in the vertical large diameter pipe quantitatively by the cross-sectional area-averaged {eta}{sub zi }at bubbly front hemisphere ({eta}{sub zi}{sup F}-bar). Bubbles in the undisturbed bubbly flow moved in a vertical way with some swerving motions and those in other flow regimes moved along the lateral secondary flow with an averaging net upward velocity. (author)

  17. Investigation of two-phase flow phenomena associated with corrosion in an SF/HLW repository in Opalinus Clay, Switzerland

    SciTech Connect (OSTI)

    Senger, R.; Marschall, P.; Finsterle, S.

    2008-08-04

    Gas generation from corrosion of the waste canisters and gas accumulation in the backfilled emplacement tunnels is a key issue in the assessment of long-term radiological safety of the proposed repository for spent fuel and high-level waste (SF/HLW) sited in the Opalinus Clay formation of Northern Switzerland. Previous modeling studies indicated a significant pressure buildup in the backfilled emplacement tunnels for those sensitivity runs, where corrosion rates were high and the permeability of the Opalinus Clay was very low. As an extension to those studies, a refined process model of the canister corrosion phenomena has been developed, which accounts not only for the gas generation but also for the water consumption associated with the chemical reaction of corrosion of steel under anaerobic conditions. The simulations with the new process model indicate, that with increasing corrosion rates and decreasing host-rock permeability, pressure buildup increased, as expected. However, the simulations taking into account water consumption show that the pressure buildup is reduced compared to the simulation considering only gas generation. The pressure reduction is enhanced for lower permeability of the Opalinus Clay and for higher corrosion rates, which correspond to higher gas generations rates and higher water consumption rates. Moreover, the simulated two-phase flow patterns in the engineered barrier system (EBS) and surrounding Opalinus Clay show important differences at late time of the gas production phase as the generated gas continues to migrate outward into the surrounding host rock. For the case without water consumption, the water flow indicates overall downward flow due to a change in the overall density of the gas-fluid mixture from that based on the initially prescribed hydrostatic pressure gradient. For the case with water consumption, water flow converges toward the waste canister at a rate corresponding to the water consumption rate associated with the corrosion reaction. The water flow toward the canister is maintained even for very low permeabilities of the Opalinus clay, sustaining the anaerobic corrosion of the steel canister.

  18. Liquid water quantification in the cathode side gas channels of a proton exchange membrane fuel cell through two-phase flow

    E-Print Network [OSTI]

    Kandlikar, Satish

    t s Liquid water in the cathode side channels of PEM fuel cell is quantified. Algorithm developed in MATLABÒ electrolyte membrane fuel cell Two-phase flow visualization Gas channels Area coverage ratio Water quantification a b s t r a c t Water management is crucial to the performance of PEM fuel cells. Water

  19. Experimental and Modeling Studies of Two-Phase Flow in Porous Media and Its Effects on the Performance of a PEM Fuel Cell

    E-Print Network [OSTI]

    Wang, Xuhai

    2010-01-01

    An experimental investigation was conducted to study the two-phase flow properties of porous media used in proton exchange membrane (PEM) fuel cells. The liquid and gas phase relative permeability of porous media used in PEM fuel cells was measured...

  20. Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions

    DOE Patents [OSTI]

    Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

    2008-11-25

    A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

  1. 8. Innovative Technologies: Two-Phase Heat Transfer in Water-Based Nanofluids for Nuclear Applications Final Report

    SciTech Connect (OSTI)

    Buongiorno, Jacopo; Hu, Lin-wen

    2009-07-31

    Abstract Nanofluids are colloidal dispersions of nanoparticles in water. Many studies have reported very significant enhancement (up to 200%) of the Critical Heat Flux (CHF) in pool boiling of nanofluids (You et al. 2003, Vassallo et al. 2004, Bang and Chang 2005, Kim et al. 2006, Kim et al. 2007). These observations have generated considerable interest in nanofluids as potential coolants for more compact and efficient thermal management systems. Potential Light Water Reactor applications include the primary coolant, safety systems and severe accident management strategies, as reported in other papers (Buongiorno et al. 2008 and 2009). However, the situation of interest in reactor applications is often flow boiling, for which no nanofluid data have been reported so far. In this project we investigated the potential of nanofluids to enhance CHF in flow boiling. Subcooled flow boiling heat transfer and CHF experiments were performed with low concentrations of alumina, zinc oxide, and diamond nanoparticles in water (? 0.1 % by volume) at atmospheric pressure. It was found that for comparable test conditions the values of the nanofluid and water heat transfer coefficient (HTC) are similar (within ?20%). The HTC increased with mass flux and heat flux for water and nanofluids alike, as expected in flow boiling. The CHF tests were conducted at 0.1 MPa and at three different mass fluxes (1500, 2000, 2500 kg/m2s) under subcooled conditions. The maximum CHF enhancement was 53%, 53% and 38% for alumina, zinc oxide and diamond, respectively, always obtained at the highest mass flux. A post-mortem analysis of the boiling surface reveals that its morphology is altered by deposition of the particles during nanofluids boiling. A confocal-microscopy-based examination of the test section revealed that nanoparticles deposition not only changes the number of micro-cavities on the surface, but also the surface wettability. A simple model was used to estimate the ensuing nucleation site density changes, but no definitive correlation between the nucleation site density and the heat transfer coefficient data could be found. Wettability of the surface was substantially increased for heater coupons boiled in alumina and zinc oxide nanofluids, and such wettability increase seems to correlate reasonably well with the observed marked CHF enhancement for the respective nanofluids. Interpretation of the experimental data was conducted in light of the governing surface parameters (surface area, contact angle, roughness, thermal conductivity) and existing models. It was found that no single parameter could explain the observed HTC or CHF phenomena.

  2. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

    1997-09-23

    A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

  3. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

    1997-01-01

    A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

  4. Thermal NF3 fluorination/oxidation of cobalt, yttrium, zirconium, and selected lanthanide oxides

    SciTech Connect (OSTI)

    Scheele, Randall D.; McNamara, Bruce K.; Casella, Andrew M.; Kozelisky, Anne E.; Neiner, Doinita

    2013-02-01

    This paper presents results of our continuing investigation on the use of nitrogen trifluoride as a fluorination or fluorination/oxidation agent for separating valuable constituents from used nuclear fuels by exploiting the different volatilities of the constituent fission product and actinide fluorides. This article focuses on fission products that do not have volatile fluorides or oxyfluorides at expected operations temperatures. Our thermodynamic calculations show that nitrogen trifluoride has the potential to completely fluorinate fission product oxides to their fluorides. Simultaneous thermogravimetric and differential thermal analyses show that the oxides of cobalt, zirconium, and the lanthanides are fluorinated but do not form volatile fluorides when treated with nitrogen trifluoride at temperatures up to 550°C. Our studies of gadolinium-doped commercial nuclear fuel indicate that nitrogen trifluoride can extract uranium from the non-volatile gadolinium.

  5. Absorption Coefficients of the Methane-Nitrogen Binary Ice System: Implications for Pluto

    E-Print Network [OSTI]

    Protopapa, S; Tegler, S C; Bergonio, J M

    2015-01-01

    The methane-nitrogen phase diagram of Prokhvatilov and Yantsevich (1983) indicates that at temperatures relevant to the surfaces of icy dwarf planets like Pluto, two phases contribute to the methane absorptions: nitrogen saturated with methane $\\bf{\\bar{N_{2}}}$:CH$_{4}$ and methane saturated with nitrogen $\\bf{\\bar{CH_{4}}}$:N$_{2}$. No optical constants are available so far for the latter component limiting construction of a proper model, in compliance with thermodynamic equilibrium considerations. New optical constants for solid solutions of methane diluted in nitrogen (N$_{2}$:CH$_{4}$) and nitrogen diluted in methane (CH$_{4}$:N$_{2}$) are presented at temperatures between 40 and 90 K, in the wavelength range 1.1-2.7 $\\mu$m at different mixing ratios. These optical constants are derived from transmission measurements of crystals grown from the liquid phase in closed cells. A systematic study of the changes of methane and nitrogen solid mixtures spectral behavior with mixing ratio and temperature is prese...

  6. Single-phase and two-phase anaerobic digestion of fruit and vegetable waste: Comparison of start-up, reactor stability and process performance

    SciTech Connect (OSTI)

    Ganesh, Rangaraj; Torrijos, Michel; Sousbie, Philippe; Lugardon, Aurelien; Steyer, Jean Philippe; Delgenes, Jean Philippe

    2014-05-01

    Highlights: • Single-phase and two-phase systems were compared for fruit and vegetable waste digestion. • Single-phase digestion produced a methane yield of 0.45 m{sup 3} CH{sub 4}/kg VS and 83% VS removal. • Substrate solubilization was high in acidification conditions at 7.0 kg VS/m{sup 3} d and pH 5.5–6.2. • Energy yield was lower by 33% for two-phase system compared to the single-phase system. • Simple and straight-forward operation favored single phase process over two-phase process. - Abstract: Single-phase and two-phase digestion of fruit and vegetable waste were studied to compare reactor start-up, reactor stability and performance (methane yield, volatile solids reduction and energy yield). The single-phase reactor (SPR) was a conventional reactor operated at a low loading rate (maximum of 3.5 kg VS/m{sup 3} d), while the two-phase system consisted of an acidification reactor (TPAR) and a methanogenic reactor (TPMR). The TPAR was inoculated with methanogenic sludge similar to the SPR, but was operated with step-wise increase in the loading rate and with total recirculation of reactor solids to convert it into acidification sludge. Before each feeding, part of the sludge from TPAR was centrifuged, the centrifuge liquid (solubilized products) was fed to the TPMR and centrifuged solids were recycled back to the reactor. Single-phase digestion produced a methane yield of 0.45 m{sup 3} CH{sub 4}/kg VS fed and VS removal of 83%. The TPAR shifted to acidification mode at an OLR of 10.0 kg VS/m{sup 3} d and then achieved stable performance at 7.0 kg VS/m{sup 3} d and pH 5.5–6.2, with very high substrate solubilization rate and a methane yield of 0.30 m{sup 3} CH{sub 4}/kg COD fed. The two-phase process was capable of high VS reduction, but material and energy balance showed that the single-phase process was superior in terms of volumetric methane production and energy yield by 33%. The lower energy yield of the two-phase system was due to the loss of energy during hydrolysis in the TPAR and the deficit in methane production in the TPMR attributed to COD loss due to biomass synthesis and adsorption of hard COD onto the flocs. These results including the complicated operational procedure of the two-phase process and the economic factors suggested that the single-phase process could be the preferred system for FVW.

  7. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

    1989-01-01

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  8. Catalysis by Confinement: Enthalpic Stabilization of NO Oxidation Transition States by Micropororous and Mesoporous Siliceous

    E-Print Network [OSTI]

    Iglesia, Enrique

    . INTRODUCTION The homogeneous oxidation of nitric oxide (NO) to nitrogen dioxide (NO2) with O2 as the oxidant transformation in selective catalytic NOx reduction (SCR) by NH3 on metal- exchanged zeolites7-11 and in NOxCatalysis by Confinement: Enthalpic Stabilization of NO Oxidation Transition States

  9. Nitrogen fixation apparatus

    DOE Patents [OSTI]

    Chen, Hao-Lin (Walnut Creek, CA)

    1984-01-01

    A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O.sub.2 /cm promotes the formation of vibrationally excited N.sub.2. Atomic oxygen interacts with vibrationally excited N.sub.2 at a much quicker rate than unexcited N.sub.2, greatly improving the rate at which NO is formed.

  10. ARM - Measurement - Nitrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska Outreach Home Roomparticlecontent ARMgovMeasurementsNitrogen ARM Data

  11. Biomass Production and Nitrogen Recovery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Peer Review WBS 4.2.2.10: Biomass Production and Nitrogen Recovery Date: March 23, 2015 Technology Area Review: Sustainability Principal Investigator: M. Cristina Negri...

  12. Two-phase frictional pressure drop of R-134a and R-410A refrigerant-oil mixtures in straight tubes and U-type wavy tubes

    SciTech Connect (OSTI)

    Chen, Ing Youn; Wu, Yu-Shi; Chang, Yu-Juei; Wang, Chi-Chuan

    2007-02-15

    This study presents single-phase and two-phase pressure drop data for R-134a/oil mixture flowing in a wavy tube with inner diameter of D=5.07mm and curvature ratio 2R/D=5.18 and R-410A/oil mixture flowing in a wavy tube of D=3.25mm and 2R/D=3.91. Both mixtures have oil concentration C=0%, 1%, 3% and 5% for the tests. The ratio of frictional factor between U-bend in wavy tube and straight tube (f{sub C}/f{sub S}) is about 3.5 for Re<2500 and is approximate 2.5 for Re=3500-25,000 for oil and liquid R-134a mixture flowing in the 5.07mm diameter wavy tube. The influence of oil concentration on single-phase friction factor is negligible, provided that the properties are based on the mixture of lubricant and refrigerant. The ratio between two-phase pressure gradients of U-bend and straight tube is about 2.5-3.5. This ratio is increased with oil concentration and vapor quality. The influence of oil is augmented at a higher mass flux for liquid spreading around the periphery at an annular flow pattern. Moreover, the influence of lubricant becomes more evident of a U-bend configuration. This is associated the induced swirled flow motion and an early change of flow pattern from stratified to annular flow pattern. The frictional two-phase multiplier for straight tube can be fairly correlated by using the Chisholm correlation for the data having Martinelli parameter X between 0.05 and 1.0. Fridel correlation also shows a good agreement with a mean deviation of 17.6% to all the straight tube data. For the two-phase pressure drop in U-bend, the revised Geary correlation agrees very well with the R-134a and R-410A oil-refrigerant data with a mean deviation of 16.4%. (author)

  13. Eighth international congress on nitrogen fixation

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This volume contains the proceedings of the Eighth International Congress on Nitrogen Fixation held May 20--26, 1990 in Knoxville, Tennessee. The volume contains abstracts of individual presentations. Sessions were entitled Recent Advances in the Chemistry of Nitrogen Fixation, Plant-microbe Interactions, Limiting Factors of Nitrogen Fixation, Nitrogen Fixation and the Environment, Bacterial Systems, Nitrogen Fixation in Agriculture and Industry, Plant Function, and Nitrogen Fixation and Evolution.

  14. Oxidation of some intermetallic compounds and intermetallic matrix composites

    SciTech Connect (OSTI)

    Jackson, M.R.; Rowe, R.G.; Skelly, D.W. [General Electric Co., Schenectady, NY (United States). Corporate Research and Development Center

    1995-07-01

    Oxidation resistance (1,000--1,400 C) was characterized for intermetallics M{sub 2}Al, M{sub 3}Al, M{sub 2}Cr, and M{sub 5}Si{sub 3} (M = Nb, Nb+Ti), and metal-toughened intermetallic composite systems. Aluminides were poorest in oxidation, and Laves phases were best. Substitution of Ti for Nb was beneficial for each intermetallic. Addition of metal to produce two-phase castings had differing effects on oxidation, depending on the metal and intermetallic. Modulus and expansion were also measured.

  15. Time-resolved fast-neutron radiography of air-water two-phase flows in a rectangular channel by an improved detection system

    E-Print Network [OSTI]

    Zboray, Robert; Mor, Ilan; Bromberger, Benjamin; Tittelmeier, Kai

    2015-01-01

    In a previous work we have demonstrated the feasibility of high-frame-rate, fast-neutron radiography of generic air-water two-phase flows in a 1.5 cm thick, rectangular flow channel. The experiments have been carried out at the high-intensity, white-beam facility of the Physikalisch-Technische Bundesanstalt, Germany, using an multi-frame, time-resolved detector developed for fast neutron resonance radiography. The results were however not fully optimal and therefore we have decided to modify the detector and optimize it for the given application, which is described in the present work. Furthermore, we managed to improve the image post-processing methodology and the noise suppression. Using the tailored detector and the improved post-processing significant increase in the image quality and an order of magnitude lower exposure times, down to 3.33 ms, have been achieved with minimized motion artifacts. Similar to the previous study, different two-phase flow regimes such as bubbly slug and churn flows have been e...

  16. O2 Reduction on Graphite and Nitrogen-Doped Graphite: Experiment and Theory Reyimjan A. Sidik and Alfred B. Anderson*

    E-Print Network [OSTI]

    Popov, Branko N.

    toward NOx reduction.7,8 Others are oxidation catalysts.9 In the case of NOx oxidation and O2 reductionO2 Reduction on Graphite and Nitrogen-Doped Graphite: Experiment and Theory Reyimjan A. Sidik for reduction of approximately 0.5 V (SHE) compared to the onset potential of 0.2 V observed for untreated

  17. COMBUSTION SOURCES OF NITROGEN COMPOUNDS

    E-Print Network [OSTI]

    Brown, Nancy J.

    2011-01-01

    Rasmussen, R.A. (1976). Combustion as a source of nitrousx control for stationary combustion sources. Prog. Energy,CA, March 3-4, 1977 COMBUSTION SOURCES OF NITROGEN COMPOUNDS

  18. Two-phase viscoelastic jetting

    E-Print Network [OSTI]

    Yu, J-D

    2009-01-01

    scale. Ink is stored in a cartridge, and driven through thethe e?ect of ink cartridge, supply channel, vibration plate,the in?uence of ink cartridge, supply channel, vibration

  19. Nitrogen Deposition in the Southern High Plains 

    E-Print Network [OSTI]

    Upadhyay, Jeetendra; Auvermann, Brent W.; Bush, K. Jack; Mukhtar, Saqib

    2008-02-11

    convert nitrogen into other chemical forms. Legume roots sustain rhizobia, the organisms capable of nitrogen fixation, a microbial process for con- verting nitrogen into ammonium (NH 4 ). Reactive nitrogen species (RNS) are nitrogen- bearing compounds... acid gas can dissolve as the ammonium ion (NH 4 +), where it may react with Sources Transport / Transformation Removal Effects Photochemistry Chemical Transformations Cloud Processes Vertical Mixing Prevailing Winds Dry DepositionWet Deposition...

  20. Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect (OSTI)

    Scheele, Randall D.; Casella, Andrew M.

    2010-09-28

    This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

  1. Oxygen minimization effects on nitrogen dioxide generation during oxyacetylene metal cutting 

    E-Print Network [OSTI]

    Clendenen, David Lee

    1981-01-01

    oxides lies in the characteristic remission of initial symptoms, such as cough and chest discomfort, for up to several hours prior to onset of acute, potentially lethal pulmonary edema. The generation rate of nitrogen oxides is dependent on many... tract w1th acute severity ranging from a revers1ble irritant coughing to potentially lethal pulmonary edema. ( The danger involved here lies 1n the sudden onset of pulmonary edema occurring an unpredictable length of time after exposure. Very little...

  2. Abatement of Air Pollution: Control of Nitrogen Oxides Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Program Info State Connecticut Program Type Environmental Regulations Provider Department of Energy and Environmental Protection These regulations may apply to reciprocating...

  3. EFFECT OF NITROGEN OXIDE PRETREATMENTS ON ENZYMATIC HYDROLYSIS OF CELLULOSE

    E-Print Network [OSTI]

    Borrevik, R.K.

    2011-01-01

    57) TO EXTRACTION WATER (6276) _________________________ ~~~focus this study on the extraction using water only, with noe followed by water leaching, then extraction for 11 hOl.lr

  4. Nitrogen oxide removal using diesel fuel and a catalyst

    DOE Patents [OSTI]

    Vogtlin, George E. (Fremont, CA); Goerz, David A. (Brentwood, CA); Hsiao, Mark (San Jose, CA); Merritt, Bernard T. (Livermore, CA); Penetrante, Bernie M. (San Ramon, CA); Reynolds, John G. (San Ramon, CA); Brusasco, Ray (Livermore, CA)

    2000-01-01

    Hydrocarbons, such as diesel fuel, are added to internal combustion engine exhaust to reduce exhaust NO.sub.x in the presence of a amphoteric catalyst support material. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbons.

  5. Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

    2007-01-01

    Selective Catalytic Reduction (SCR) NOx Control; Prepared byNOx Removal Technologies. Volume 1. Selective Catalytic Reduction.

  6. Persistent sensitivity of Asian aerosol to emissions of nitrogen oxides

    E-Print Network [OSTI]

    Kharol, S. K.

    We use a chemical transport model and its adjoint to examine the sensitivity of secondary inorganic aerosol formation to emissions of precursor trace gases from Asia. Sensitivity simulations indicate that secondary inorganic ...

  7. Nitrogen oxides reduction by staged combustion of LCV gas 

    E-Print Network [OSTI]

    Cabrera Sixto, Jose Manuel

    1990-01-01

    ); and the bottom (figure 4). The purpose of this design was to provide flexsMity to modify the CC. Figure 5 shows a sectional view of the cydone combustor designed. The dimensions in this drawing were calculated based on a CGT feeding rate in the gasifier... TABLES OF THE STATISTICAL ANALYSES Primary Equivalence Ratio Overall Equivalence Ratio Delay Time between Stages Inlet Reynolds Number Combustion Temperature F/A Ratio in Gasifier D COMPUTER PROGRAM USED IN THE CAMAC SYSTEM E EXAMPLE . 162 163...

  8. Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

    2007-01-01

    Pollution Control Costs for Coal-Fired Power Stations; IEAControl Options for Coal-Fired Electric Utility Boilers; J.for NO x Control on Coal-Fired Boilers; U.S. Environmen- tal

  9. Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

    2007-01-01

    x Control. Volume 1: Utility Boiler Applications; ElectricCoal-Fired Electric Utility Boilers; J. Air & Waste Manage.for NO x Control on Coal-Fired Boilers; U.S. Environmen- tal

  10. Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

    2007-01-01

    including issues of technology and cost un- certainties, areon NO x Control Technologies and Cost Effectiveness forand other factors on technology cost trends (hence, the

  11. Nitrogen-doped graphene as transparent counter electrode for efficient dye-sensitized solar cells

    SciTech Connect (OSTI)

    Wang, Guiqiang, E-mail: wgqiang123@163.com [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China); Fang, Yanyan; Lin, Yuan [Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)] [Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China); Xing, Wei; Zhuo, Shuping [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? NG sheets are prepared through a hydrothermal reduction of graphite oxide. ? The transparent NG counter electrodes of DSCs are fabricated at room temperature. ? Transparent NG electrode exhibits excellent catalytic activity for the reduction of I{sub 3}{sup ?}. ? The DSC with NG electrode achieves a comparable efficiency to that of the Pt-based cell. ? The efficiency of rear illumination is about 85% that of front illumination. -- Abstract: Nitrogen-doped graphene sheets are prepared through a hydrothermal reduction of graphite oxide in the presence of ammonia and applied to fabricate the transparent counter electrode of dye-sensitized solar cells. The atomic percentage of nitrogen in doped graphene sample is about 2.5%, and the nitrogen bonds display pyridine and pyrrole-like configurations. Cyclic voltammetry studies demonstrate a much higher electrocatalytic activity toward I{sup ?}/I{sub 3}{sup ?} redox reaction for nitrogen-doped graphene, as compared with pristine graphene. The dye-sensitized solar cell with this transparent nitrogen-doped graphene counter electrode shows conversion efficiencies of 6.12% and 5.23% corresponding to front-side and rear-side illumination, respectively. Meanwhile, the cell with a Pt counter electrode shows a conversion efficiency of 6.97% under the same experimental condition. These promising results highlight the potential application of nitrogen-doped graphene in cost-effective, transparent dye-sensitized solar cells.

  12. Palladium-Catalysed CH Activation of Aliphatic Amines! to give Strained Nitrogen Heterocycles !

    E-Print Network [OSTI]

    Jackson, Sophie

    Palladium-Catalysed C­H Activation of Aliphatic Amines! to give Strained Nitrogen Heterocycles. The University of Cambridge, Lensfield Road, Cambridge, CB2 1EW.! Palladium-Catalyzed C­H Activation Modes cyclopalladation complex N H palladium catalyst directed C­H activation oxidant C­Pd functionalization 4-membered

  13. Application of Two Phase (Liquid/Gas) Xenon Gamma-Camera for the Detection of Special Nuclear Material and PET Medical Imaging

    SciTech Connect (OSTI)

    McKinsey, Daniel Nicholas

    2013-08-27

    The McKinsey group at Yale has been awarded a grant from DTRA for the building of a Liquid Xenon Gamma Ray Color Camera (LXe-GRCC), which combines state-of-the-art detection of LXe scintillation light and time projection chamber (TPC) charge readout. The DTRA application requires a movable detector and hence only a single phase (liquid) xenon detector can be considered in this case. We propose to extend the DTRA project to applications that allow a two phase (liquid/gas) xenon TPC. This entails additional (yet minimal) hardware and extension of the research effort funded by DTRA. The two phase detector will have better energy and angular resolution. Such detectors will be useful for PET medical imaging and detection of special nuclear material in stationary applications (e.g. port of entry). The expertise of the UConn group in gas phase TPCs will enhance the capabilities of the Yale group and the synergy between the two groups will be very beneficial for this research project as well as the education and research projects of the two universities. The LXe technology to be used in this project has matured rapidly over the past few years, developed for use in detectors for nuclear physics and astrophysics. This technology may now be applied in a straightforward way to the imaging of gamma rays. According to detailed Monte Carlo simulations recently performed at Yale University, energy resolution of 1% and angular resolution of 3 degrees may be obtained for 1.0 MeV gamma rays, using existing technology. With further research and development, energy resolution of 0.5% and angular resolution of 1.3 degrees will be possible at 1.0 MeV. Because liquid xenon is a high density, high Z material, it is highly efficient for scattering and capturing gamma rays. In addition, this technology scales elegantly to large detector areas, with several square meter apertures possible. The Yale research group is highly experienced in the development and use of noble liquid detectors for astrophysics, most recently in the XENON10 experiment. The existing facilities at Yale are fully adequate for the completion of this project. The facilities of the UConn group at the LNS at Avery Point include a (clean) lab for detector development and this group recently delivered an Optical Readout TPC (O-TPC) for research in Nuclear Astrophysics at the TUNL in Duke University. The machine shop at UConn will be used (free of charge) for producing the extra hardware needed for this project including grids and frames.

  14. Two-phase flow regimes and carry-over in a large-diameter model of a PWR hot leg. Final report

    SciTech Connect (OSTI)

    Hashemi, A.

    1986-04-01

    This report describes a series of tests investigating two-phase flow characterization and carryover in a transparent model of a Babcock and Wilson (B and W) Pressurized Water Reactor (PWR) hot leg geometry. This work was performed, inpart, to support the interpretation of results from the Once-Through Integral System (OTIS) and Multi-loop Integral Test (MIST) facilities. Test conditions were selected to cover a wide range of gas and liquid superficial velocities (0.01 m/s < j/sub g/ < 2 m/s, 0 < j/sub l/ < 0.5 m/s) expected to occur in a prototypical reactor geometry during a small break loss of coolant accident (SBLOCA). Tests at high gas superficial velocities (j/sub g/ > 2 m/s) were also performed for comparison with semi-analytical predictions. Tests were conducted in two different test rigs, one with 10.2-cm (4-inch) diameter pipe, and the other with 30.5-cm (12-inch) diameter pipe. Results include average void fraction, amount of water carryover through the U-bend, transient flow rates and pressure histories, and video movies of the two-phase flow phenomena. Results of the 10.2-cm (4-inch) pipe tests show generally good agreement with the Taitel and Dukler (1) flow regime map for vertical pipes. For the 30.5-cm pipe tests, slug flow was not observed. Instead, as the air flow rate was increased, the flow regime progressed from bubbly to churn-type flow with the presence of large bubbles (approximately 15-cm diameter). The results also indicate that flow regimes and collapsed liquid level are more strongly dependent on air superficial velocity than the water superficial velocity and that the amount of water carryover for a given air flow rate is a strong function of collapsed water level (void fraction). Furthermore, the results show that similar thresholds for breakdown in natural circulation flow exist between the 10.2-cm and 30.5-cm pipe tests for gas and liquid superficial velocities expected in a SBLOCA. 20 refs., 24 figs.

  15. Flow pattern, pressure drop and void fraction of two-phase gas-liquid flow in an inclined narrow annular channel

    SciTech Connect (OSTI)

    Wongwises, Somchai; Pipathattakul, Manop [Fluid Mechanics, Thermal Engineering and Multiphase Flow Research Lab (FUTURE), Department of Mechanical Engineering, King Mongkut's University of Technology Thonburi, Bangmod, Bangkok 10140 (Thailand)

    2006-03-01

    Two-phase flow pattern, pressure drop and void fraction in horizontal and inclined upward air-water two-phase flow in a mini-gap annular channel are experimentally studied. A concentric annular test section at the length of 880mm with an outer diameter of 12.5mm and inner diameter of 8mm is used in the experiments. The flow phenomena, which are plug flow, slug flow, annular flow, annular/slug flow, bubbly/plug flow, bubbly/slug-plug flow, churn flow, dispersed bubbly flow and slug/bubbly flow, are observed and recorded by high-speed camera. A slug flow pattern is found only in the horizontal channel while slug/bubbly flow patterns are observed only in inclined channels. When the inclination angle is increased, the onset of transition from the plug flow region to the slug flow region (for the horizontal channel) and from the plug flow region to slug/bubbly flow region (for inclined channels) shift to a lower value of superficial air velocity. Small shifts are found for the transition line between the dispersed bubbly flow and the bubbly/plug flow, the bubbly/plug flow and the bubbly/slug-plug flow, and the bubbly/plug flow and the plug flow. The rest of the transition lines shift to a higher value of superficial air velocity. Considering the effect of flow pattern on the pressure drop in the horizontal tube at low liquid velocity, the occurrence of slug flow stops the rise of pressure drop for a short while, before rising again after the air velocity has increased. However, the pressure does not rise abruptly in the tubes with {theta}=30{sup o} and 60{sup o} when the slug/bubbly flow occurs. At low gas and liquid velocity, the pressure drop increases, when the inclination angles changes from horizontal to 30{sup o} and 60{sup o}. Void fraction increases with increasing gas velocity and decreases with increasing liquid velocity. After increasing the inclination angle from horizontal to {theta}=30{sup o} and 60{sup o}, the void fraction appears to be similar, with a decreasing trend when the inclination angle increases. (author)

  16. What Happens to Nitrogen in Soils? 

    E-Print Network [OSTI]

    Provin, Tony; Hossner, L. R.

    2001-07-09

    35,000 tons of inert nitrogen gas (N 2 ). Most of the nitrogen found in soil originated as N 2 gas and nearly all the nitrogen in the atmosphere is N 2 gas. This inert nitrogen cannot be used by the plant until it is changed to ammonium (NH 4... + ) or nitrate (NO 3 - ) forms. Three important methods for changing nitrogen gas (N 2 ) to ammonium (NH 4 + ) are: a73 Free-living N 2 -fixing bacteria a73 N 2 -fixing bacteria in nodules on the roots of leguminous plants, and a73 Nitrogen fertilizer production...

  17. Power combination of two phase-locked high power microwave beams from a new coaxial microwave source based on dual beams

    SciTech Connect (OSTI)

    Li, Yangmei; Zhang, Xiaoping Zhang, Jiande; Dang, Fangchao; Yan, Xiaolu

    2014-10-15

    The new coaxial high power microwave source based on dual beams has demonstrated two phase-locked output microwave beams generated by its two sub-sources. In order to achieve a single higher output power, we present a three-port waveguide-based power combiner to combine the two microwave beams. Particle-in-cell simulation results show that when the diode voltage is 675?kV and the guiding magnetic field is 0.8?T, a combined microwave with an average power of about 4.0?GW and a frequency of 9.74 GHz is generated; the corresponding power conversion efficiency is 29%. The combination effect of the combiner is further validated in the diode voltage range from 675?kV to 755?kV as well as in the pulse regime. The simulations indicate that the maximum surface axial electric field strength of the electrodynamic structure is 720?kV/cm, which is relatively low corresponding to an output power of 4.0?GW. The stable combined output suggests the probability of long-pulse operation for the combined source.

  18. Interface dynamics of immiscible two-phase lattice-gas cellular automata: A model with random dynamic scatterers and quenched disorder in two dimensions

    E-Print Network [OSTI]

    Azevedo, R M; Coutinho-Filho, M D

    2015-01-01

    We use a lattice gas cellular automata model in the presence of random dynamic scattering sites and quenched disorder in the two-phase immiscible model with the aim of producing an interface dynamics similar to that observed in Hele-Shaw cells. The dynamics of the interface is studied as one fluid displaces the other in a clean lattice and in a lattice with quenched disorder. For the clean system, if the fluid with a lower viscosity displaces the other, we show that the model exhibits the Saffman-Taylor instability phenomenon, whose features are in very good agreement with those observed in real (viscous) fluids. In the system with quenched disorder, we obtain estimates for the growth and roughening exponents of the interface width in two cases: viscosity-matched fluids and the case of unstable interface. The first case is shown to be in the same universality class of the random deposition model with surface relaxation. Moreover, while the early-time dynamics of the interface behaves similarly, viscous finger...

  19. Influence of the Pipe Diameter on the Structure of the Gas-Liquid Interface in a Vertical Two-Phase Pipe Flow

    SciTech Connect (OSTI)

    Prasser, H.-M.; Beyer, M.; Boettger, A.; Carl, H.; Lucas, D.; Schaffrath, A.; Schuetz, P.; Weiss, F.-P.; Zschau, J. [Forschungszentrum Rossendorf (Germany)

    2005-10-15

    Air-water two-phase flow tests in a large vertical pipe of 194.1-mm inner diameter (i.d.) are reported. Close to the outlet of a 9-m-tall test section, two wire-mesh sensors are installed that deliver instantaneous void fraction distributions over the entire cross section with a resolution of 3 mm and 2500 Hz used for fast-flow visualization. Void fraction profiles, gas velocity profiles, and bubble-size distributions were obtained. A comparison to a small pipe of 52.3-mm i.d. (DN50) revealed significant scaling effects. Here, the increase of the airflow rate leads to a transition from bubbly via slug to churn-turbulent flow. This is accompanied by an appearance of a second peak in the bubble-size distribution. A similar behavior was found in the large pipe; though the large bubbles have a significantly larger diameter at identical superficial velocities, the peak is less high but wider. These bubbles move more freely in the large pipe and show more deformations. The shapes of such large bubbles were characterized in three dimensions. They can be rather complicated and far from ideal Taylor bubbles. Also, the small bubble fraction tends to bigger sizes in the large pipe.

  20. Composite mixed oxide ionic and electronic conductors for hydrogen separation

    DOE Patents [OSTI]

    Gopalan, Srikanth (Westborough, MA); Pal, Uday B. (Dover, MA); Karthikeyan, Annamalai (Quincy, MA); Hengdong, Cui (Allston, MA)

    2009-09-15

    A mixed ionic and electronic conducting membrane includes a two-phase solid state ceramic composite, wherein the first phase comprises an oxygen ion conductor and the second phase comprises an n-type electronically conductive oxide, wherein the electronically conductive oxide is stable at an oxygen partial pressure as low as 10.sup.-20 atm and has an electronic conductivity of at least 1 S/cm. A hydrogen separation system and related methods using the mixed ionic and electronic conducting membrane are described.

  1. Kinetic modeling of nitric oxide removal from exhaust gases by Selective Non-Catalytic Reduction 

    E-Print Network [OSTI]

    Chenanda, Cariappa Mudappa

    1993-01-01

    Selective Non-Catalytic Reduction is one of the most promising techniques for the removal of oxides of nitrogen from combustion exhaust gases. These techniques are based on the injection of certain compounds, such as cyanuric acid and ammonia...

  2. Method of preparing nitrogen containing semiconductor material

    DOE Patents [OSTI]

    Barber, Greg D.; Kurtz, Sarah R.

    2004-09-07

    A method of combining group III elements with group V elements that incorporates at least nitrogen from a nitrogen halide for use in semiconductors and in particular semiconductors in photovoltaic cells.

  3. Mechanistic models of oceanic nitrogen fixation

    E-Print Network [OSTI]

    Monteiro, Fanny

    2009-01-01

    Oceanic nitrogen fixation and biogeochemical interactions between the nitrogen, phosphorus and iron cycles have important implications for the control of primary production and carbon storage in the ocean. The biological ...

  4. BIOGEOCHEMISTRY LETTERS Chronic nitrogen additions suppress decomposition

    E-Print Network [OSTI]

    Templer, Pamela

    BIOGEOCHEMISTRY LETTERS Chronic nitrogen additions suppress decomposition and sequester soil carbon dioxide emis- sions, offsetting a substantial portion of greenhouse gas forcing of the climate system. Although a number of factors are responsible for this terrestrial carbon sink, atmospheric nitrogen

  5. Size-reduction of nanodiamonds via air oxidation

    E-Print Network [OSTI]

    Gaebel, T; Chen, J; Hemmer, P; Rabeau, J R

    2011-01-01

    Here we report the size reduction and effects on nitrogen-vacancy centres in nanodiamonds by air oxidation using a combined atomic force and confocal microscope. The average height reduction of individual crystals as measured by atomic force microscopy was 10.6 nm/h at 600 {\\deg}C air oxidation at atmospheric pressure. The oxidation process modified the surface including removal of non-diamond carbon and organic material which also led to a decrease in background fluorescence. During the course of the nanodiamond size reduction, we observed the annihilation of nitrogen-vacancy centres which provided important insight into the formation of colour centres in small crystals. In these unirradiated samples, the smallest nanodiamond still hosting a stable nitrogen-vacancy centre observed was 8 nm.

  6. Size-reduction of nanodiamonds via air oxidation

    E-Print Network [OSTI]

    T. Gaebel; C. Bradac; J. Chen; P. Hemmer; J. R. Rabeau

    2011-04-27

    Here we report the size reduction and effects on nitrogen-vacancy centres in nanodiamonds by air oxidation using a combined atomic force and confocal microscope. The average height reduction of individual crystals as measured by atomic force microscopy was 10.6 nm/h at 600 {\\deg}C air oxidation at atmospheric pressure. The oxidation process modified the surface including removal of non-diamond carbon and organic material which also led to a decrease in background fluorescence. During the course of the nanodiamond size reduction, we observed the annihilation of nitrogen-vacancy centres which provided important insight into the formation of colour centres in small crystals. In these unirradiated samples, the smallest nanodiamond still hosting a stable nitrogen-vacancy centre observed was 8 nm.

  7. Nitrogen dioxide and respiratory illnesses in infants

    SciTech Connect (OSTI)

    Samet, J.M.; Lambert, W.E.; Skipper, B.J.; Cushing, A.H.; Hunt, W.C.; Young, S.A.; McLaren, L.C.; Schwab, M.; Spengler, J.D. )

    1993-11-01

    Nitrogen dioxide is an oxidant gas that contaminates outdoor air and indoor air in homes with unvented gas appliances. A prospective cohort study was carried out to test the hypothesis that residential exposure to NO2 increases incidence and severity of respiratory illnesses during the first 18 months of life. A cohort of 1,205 healthy infants from homes without smokers was enrolled. The daily occurrence of respiratory symptoms and illnesses was reported by the mothers every 2 wk. Illnesses with wheezing or wet cough were classified as lower respiratory tract. Indoor NO2 concentrations were serially measured with passive samplers place in the subjects' bedrooms. In stratified analyses, illness incidence rates did not consistently increase with exposure to NO2 or stove type. In multivariate analyses that adjusted for potential confounding factors, odds ratios were not significantly elevated for current or lagged NO2 exposures, or stove type. Illness duration, a measure of illness severity, was not associated with NO2 exposure. The findings can be extended to homes with gas stoves in regions of the United States where the outdoor air is not heavily polluted by NO2.

  8. Effect of nitrogen-containing groups on enhanced capacitive behaviors of multi-walled carbon nanotubes

    SciTech Connect (OSTI)

    Kim, Ji-Il; Park, Soo-Jin

    2011-08-15

    In this work, electrochemical properties of surface treated multi-walled carbon nanotubes (MWNTs) are studied in supercapacitors. Nitrogen and oxygen functional groups containing MWNTs are prepared by urea and acidic treatments, respectively. The surface properties of the MWNTs are confirmed by X-ray photoelectron spectroscopy (XPS) and zeta-potential measurements. The textural properties are characterized by N{sub 2} adsorption/desorption isotherm at 77 K using the BET eqaution, BJH method, and HK method. The electrochemical properties of the MWNTs are accumulated by cyclic voltammetry, impedance spectra, and charge-discharge cycling performance in 1 M H{sub 2}SO{sub 4} at room temperature. As a result, the functionalized MWNTs lead to an increase in capacitance as compared with pristine MWNTs. It suggests that the pyridinic and pyridinic-N-oxides nitrogen species have effects on the specific capacitance due to the positive charge, and thus an improved electron transfer at high current loads results, the most important functional groups affecting capacitive behaviors. - Graphical Abstract: The N{sub 1s} spectra of nitrogen functionalized multi-walled carbon nanotubes are measured by X-ray photoelectron spectroscopy. Highlights: > Facile method of increasing elemental composition of nitrogen functional groups on carbon materials. > Increased specific capacitance multi-walled carbon nanotubes (MWNTs) for electrode materials as high as general chemical activation process. > Enhanced capacitive behaviors via introducing pyridinic and pyridinic-N-oxides nitrogen species onto the MWNTs. > Improvement of electron transfer at high current loads.

  9. Fig. 1: (a) Conventional dual-pump degenerate PSA using a straight HNLF: phase regeneration effect varies with polarization alignment between BPSK signal and two phase-locked pumps. (b) Polarization-diversity PSA

    E-Print Network [OSTI]

    Touch, Joe

    Fig. 1: (a) Conventional dual-pump degenerate PSA using a straight HNLF: phase regeneration effect varies with polarization alignment between BPSK signal and two phase-locked pumps. (b) Polarization. Pump 2Signal Pump 1 HNLF Impaired by phase noise I Q Single-polarization BPSK signal Pump1 (Phase

  10. Modelling of two phase flow and application in industries CR/ARH | 20/12/2007 | Robert Bosch GmbH 2007. All rights reserved, also regarding any disposal, exploitation, reproduction, editing,

    E-Print Network [OSTI]

    Helluy, Philippe

    for industrial property rights. Modelling of cavitating flow Control volume liquid Steam and air bubbles Volume1 Modelling of two phase flow and application in industries CR/ARH | 20/12/2007 | © Robert Bosch, distribution, as well as in the event of applications for industrial property rights. Dr. Uwe Iben Robert Bosch

  11. Nitrogen fixation method and apparatus

    DOE Patents [OSTI]

    Chen, Hao-Lin (Walnut Creek, CA)

    1983-01-01

    A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O.sub.2 /cm promotes the formation of vibrationally excited N.sub.2. Atomic oxygen interacts with vibrationally excited N.sub.2 at a much quicker rate than unexcited N.sub.2, greatly improving the rate at which NO is formed.

  12. Nitrogen fixation method and apparatus

    DOE Patents [OSTI]

    Chen, H.L.

    1983-08-16

    A method and apparatus for achieving nitrogen fixation includes a volumetric electric discharge chamber. The volumetric discharge chamber provides an even distribution of an electron beam, and enables the chamber to be maintained at a controlled energy to pressure (E/p) ratio. An E/p ratio of from 5 to 15 kV/atm of O[sub 2]/cm promotes the formation of vibrationally excited N[sub 2]. Atomic oxygen interacts with vibrationally excited N[sub 2] at a much quicker rate than unexcited N[sub 2], greatly improving the rate at which NO is formed. 1 fig.

  13. Nitrogen Removal from Natural Gas

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report: AchievementsTemperatures Year 6 -FINALEnergy,Pacificdouble-betaNitrogen

  14. Investigation on Nitric Oxide and Soot of Biodiesel and Conventional Diesel using a Medium Duty Diesel Engine 

    E-Print Network [OSTI]

    Song, Hoseok

    2012-07-16

    Biodiesel has been suggested as an alternative fuel to the petroleum diesel fuel. It beneficially reduces regulated emission gases, but increases NOx (nitric oxide and nitrogen dioxide) Thus, the increase in NOx is the ...

  15. Sandia Energy - Strategic Petroleum Reserve: Nitrogen Monitoring...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Strategic Petroleum Reserve: Nitrogen Monitoring & Integrity Testing of SW Louisiana Caverns Home Carbon Capture & Storage News News & Events Research & Capabilities Systems...

  16. Oxidation catalyst

    DOE Patents [OSTI]

    Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

    2010-11-09

    The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

  17. Nitrogen-doped mesoporous carbon for energy storage in vanadium redox flow batteries

    SciTech Connect (OSTI)

    Shao, Yuyan; Wang, Xiqing; Engelhard, Mark H.; Wang, Chong M.; Dai, Sheng; Liu, Jun; Yang, Zhenguo; Lin, Yuehe

    2010-03-22

    We demonstrate a novel electrode material?nitrogen-doped mesoporous carbon (NMC)?for vanadium redox flow batteries. Mesoporous carbon (MC) is prepared using a soft-template method and doped with nitrogen by heat-treating MC in NH3. NMC is characterized with X-ray photoelectron spectroscopy and transmission electron microscopy. The redox reaction of VO2+/VO2+ is characterized with cyclic voltammetry and electrochemical impedance spectroscopy. The electrocatalytic kinetics of the redox couple VO2+/VO2+ is significantly enhanced on NMC electrode compared with MC and graphite electrodes. The reversibility of the redox couple VO2+/VO2+ is greatly improved on NMC (0.61 for NMC vs. 0.34 for graphite). Nitrogen doping facilitates the electron transfer on the electrode/electrolyte interface for both oxidation and reduction processes. NMC is a promising electrode material for redox flow batteries.

  18. Foliar nitrogen dynamics and nitrogen resorption of a sandy shrub Salix gordejevii in northern China

    E-Print Network [OSTI]

    Foliar nitrogen dynamics and nitrogen resorption of a sandy shrub Salix gordejevii in northern Key words: Nitrogen, resorption efficiency, resorption proficiency, Salix gordejevii, senescence, soil and senescing leaves and N resorption in Salix gordejevii Chang, a sandy shrub in northern China, were studied

  19. The Ecological Society of America www.frontiersinecology.org Earth's atmosphere consists largely of nitrogen (N) in

    E-Print Network [OSTI]

    Templer, Pamela

    nitrogen oxides (NOx) and ammonia (NH3), to the atmosphere (eg Galloway et al. 2008). Both NOx and NH3 can of North America. Some of this N can stimulate carbon (C) storage in terrestrial ecosystems rates of ammonia emissions and deposition are expected to remain unchanged, projected declines

  20. Isothermal oxidation behavior of ternary Zr-Nb-Y alloys at high temperature

    SciTech Connect (OSTI)

    Prajitno, Djoko Hadi, E-mail: djokohp@batan.go.id [Research Center for Nuclear Materials and Radiometry, Jl. Tamansari 71, Bandung 40132 (Indonesia); Soepriyanto, Syoni; Basuki, Eddy Agus [Metallurgy Engineering, Institute Technology Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia); Wiryolukito, Slameto [Materials Engineering, Institute Technology Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia)

    2014-03-24

    The effect of yttrium content on isothermal oxidation behavior of Zr-2,5%Nb-0,5%Y, Zr-2,5%Nb-1%Y Zr-2,5%Nb-1,5%Y alloy at high temperature has been studied. High temperature oxidation carried out at tube furnace in air at 600,700 and 800°C for 1 hour. Optical microscope is used for microstructure characterization of the alloy. Oxidized and un oxidized specimen was characterized by x-ray diffraction. In this study, kinetic oxidation of Zr-2,5%Nb with different Y content at high temperature has also been studied. Characterization by optical microscope showed that microstructure of Zr-Nb-Y alloys relatively unchanged and showed equiaxed microstructure. X-ray diffraction of the alloys depicted that the oxide scale formed during oxidation of zirconium alloys is monoclinic ZrO2 while unoxidised alloy showed two phase ? and ? phase. SEM-EDS examination shows that depletion of Zr composition took place under the oxide layer. Kinetic rate of oxidation of zirconium alloy showed that increasing oxidation temperature will increase oxidation rate but increasing yttrium content in the alloys will decrease oxidation rate.

  1. Single- and Two-Phase Diversion Cross-Flows Between Triangle Tight Lattice Rod Bundle Subchannels - Data on Flow Resistance and Interfacial Friction Coefficients for the Cross-Flow

    SciTech Connect (OSTI)

    Tatsuya Higuchi; Akimaro Kawahara; Michio Sadatomi; Hiroyuki Kudo [Kumamoto University, 39-1, Kurokami 2-chome, Kumamoto 860-8555 (Japan)

    2006-07-01

    Single- and two-phase diversion cross-flows arising from the pressure difference between tight lattice subchannels are our concern in this study. In order to obtain a correlation of the diversion cross-flow, we conducted adiabatic experiments using a vertical multiple-channel with two subchannels simplifying the triangle tight lattice rod bundle for air-water flows at room temperature and atmospheric pressure. In the experiments, data were obtained on the axial variations in the pressure difference between the subchannels, the ratio of flow rate in one subchannel to the whole channel, the void fraction in each subchannel for slug-churn and annular flows in two-phase flow case. These data were analyzed by use of a lateral momentum equation based on a two-fluid model to determine both the cross-flow resistance coefficient between liquid phase and channel wall and the gas-liquid interfacial friction coefficient. The resulting coefficients have been correlated in a way similar to that developed for square lattice subchannel case by Kano et al. (2002); the cross-flow resistance coefficient data can be well correlated with a ratio of the lateral velocity due to the cross-flow to the axial one irrespective of single- and two-phase flows; the interfacial friction coefficient data were well correlated with a Reynolds number, which is based on the relative velocity between gas and liquid cross-flows as the characteristic velocity. (authors)

  2. Contribution of gas phase oxidation of volatile organic compounds to atmospheric carbon monoxide levels in two areas of the United States

    E-Print Network [OSTI]

    Dabdub, Donald

    - house gas, but also the hydroperoxide radical (HO2). HO2 converts nitric oxide to nitrogen dioxideContribution of gas phase oxidation of volatile organic compounds to atmospheric carbon monoxide. Chen, K. Carmody, S. Vutukuru, and D. Dabdub (2007), Contribution of gas phase oxidation of volatile

  3. Correcting Nitrogen Deficiencies in Cotton with Urea-Based Products 

    E-Print Network [OSTI]

    Livingston, Stephen; Stichler, Charles

    1995-11-22

    Correcting nitrogen deficiency is important for cotton plant growth. This publication explains nitrogen requirements, the problems associated with nitrogen deficiency, and ways to correct deficiencies using urea as a source ...

  4. Method for producing high carrier concentration p-Type transparent conducting oxides

    DOE Patents [OSTI]

    Li, Xiaonan (Evergreen, CO); Yan, Yanfa (Littleton, CO); Coutts, Timothy J. (Golden, CO); Gessert, Timothy A. (Conifer, CO); Dehart, Clay M. (Westminster, CO)

    2009-04-14

    A method for producing transparent p-type conducting oxide films without co-doping plasma enhancement or high temperature comprising: a) introducing a dialkyl metal at ambient temperature and a saturated pressure in a carrier gas into a low pressure deposition chamber, and b) introducing NO alone or with an oxidizer into the chamber under an environment sufficient to produce a metal-rich condition to enable NO decomposition and atomic nitrogen incorporation into the formed transparent metal conducting oxide.

  5. Functional and inflammatory alterations in the lung following exposure of rats to nitrogen mustard

    SciTech Connect (OSTI)

    Sunil, Vasanthi R., E-mail: sunilvr@eohsi.rutgers.edu [Department of Pharmacology and Toxicology, Rutgers University, Piscataway, NJ (United States); Patel, Kinal J., E-mail: kinalv5@gmail.com [Department of Pharmacology and Toxicology, Rutgers University, Piscataway, NJ (United States); Shen, Jianliang, E-mail: jianliangs@gmail.com [Department of Pharmacology and Toxicology, Rutgers University, Piscataway, NJ (United States); Reimer, David, E-mail: reimerd@las.rutgers.edu [Laboratory Animal Services, Rutgers University, Piscataway, NJ (United States); Gow, Andrew J., E-mail: gow@rci.rutgers.edu [Department of Pharmacology and Toxicology, Rutgers University, Piscataway, NJ (United States); Laskin, Jeffrey D., E-mail: jlaskin@eohsi.rutgers.edu [Department of Environmental and Occupational Medicine, University of Medicine and Dentistry of New Jersey, Robert Wood Johnson Medical School, Piscataway, NJ (United States); Laskin, Debra L., E-mail: laskin@eohsi.rutgers.edu [Department of Pharmacology and Toxicology, Rutgers University, Piscataway, NJ (United States)

    2011-01-01

    Nitrogen mustard is a vesicant that causes damage to the respiratory tract. In these studies, we characterized the acute effects of nitrogen mustard on lung structure, inflammatory mediator expression, and pulmonary function, with the goal of identifying mediators potentially involved in toxicity. Treatment of rats (male Wistar, 200-225 g) with nitrogen mustard (mechlorethamine hydrochloride, i.t., 0.25 mg/kg) resulted in marked histological changes in the respiratory tract, including necrotizing bronchiolitis, thickening of alveolar septa, and inflammation which was evident within 24 h. This was associated with increases in bronchoalveolar lavage protein and cells, confirming injury to alveolar epithelial regions of the lung. Nitrogen mustard administration also resulted in increased expression of inducible nitric oxide synthase and cyclooxygenase-2, pro-inflammatory proteins implicated in lung injury, in alveolar macrophages and alveolar and bronchial epithelial cells. Expression of connective tissue growth factor and matrix metalloproteinase-9, mediators regulating extracellular matrix turnover was also increased, suggesting that pathways leading to chronic lung disease are initiated early in the pathogenic process. Following nitrogen mustard exposure, alterations in lung mechanics and function were also observed. These included decreases in baseline static compliance, end-tidal volume and airway resistance, and a pronounced loss of methacholine responsiveness in resistance, tissue damping and elastance. Taken together, these data demonstrate that nitrogen mustard induces rapid structural and inflammatory changes in the lung which are associated with altered lung functioning. Understanding the nature of the injury induced by nitrogen mustard and related analogs may aid in the development of efficacious therapies for treatment of pulmonary injury resulting from exposure to vesicants.

  6. Eighth international congress on nitrogen fixation. Final program

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    This volume contains the proceedings of the Eighth International Congress on Nitrogen Fixation held May 20--26, 1990 in Knoxville, Tennessee. The volume contains abstracts of individual presentations. Sessions were entitled Recent Advances in the Chemistry of Nitrogen Fixation, Plant-microbe Interactions, Limiting Factors of Nitrogen Fixation, Nitrogen Fixation and the Environment, Bacterial Systems, Nitrogen Fixation in Agriculture and Industry, Plant Function, and Nitrogen Fixation and Evolution.

  7. Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys

    DOE Patents [OSTI]

    Natesan, K.; Baxter, D.J.

    1983-07-26

    High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

  8. Oxidation sulfidation resistance of Fe-Cr-Ni alloys

    DOE Patents [OSTI]

    Natesan, Ken (Naperville, IL); Baxter, David J. (Woodridge, IL)

    1984-01-01

    High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1-8 wt. % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500.degree.-1000.degree. C.

  9. Nitrogen Fixation and Dentrification in Sediments of Eutrophic Mediterranean-Type Estuaries: Seasonal Patterns and Responses to Anthropogenic Nitrogen Inputs

    E-Print Network [OSTI]

    Kane, Tonya Lynn

    2012-01-01

    and mechanisms controlling sediment nitrogen fixation in aKane T & Fong P. 2007. Sediment nitrogen fixation in UpperKane T & Fong P. 2007. Sediment nitrogen fixation in Upper

  10. ITP Steel: Hydrogen and Nitrogen Control in Ladle and Casting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen and Nitrogen Control in Ladle and Casting Operations ITP Steel: Hydrogen and Nitrogen Control in Ladle and Casting Operations castingops.pdf More Documents & Publications...

  11. Nitrogen Control in Electric Arc Furnace Steelmaking by Direct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines Injection Nitrogen Control in Electric Arc Furnace Steelmaking by Direct Reduced Iron Fines...

  12. Dissociation and excitation coefficients of nitrogen molecules and nitrogen monoxide generation

    SciTech Connect (OSTI)

    Uhm, Han S.; Na, Young H.; Choi, Eun H.; Cho, Guangsup [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)] [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)

    2013-08-15

    The excitation coefficient ?{sub N2} is calculated for the excited metastable level of N{sub 2}(A{sub 3}?{sub u}{sup +}) in nitrogen molecules. In addition, the dissociation coefficient of nitrogen molecules is investigated by making use of the Boltzmann distribution of the electrons in atmospheric plasmas. The excitation and electron-impact dissociation coefficients of nitrogen molecules are analytically expressed in terms of the electron temperature T{sub e} for evaluations of the reactive oxygen and nitrogen species in atmospheric plasmas. As an application example of these coefficients, the nitrogen monoxide generation through a microwave torch is carried out for a development of medical tool. The nitrogen monoxide concentration from a microwave plasma-torch can be easily controlled by the nitrogen flow rate, mole fraction of the oxygen gas, and the microwave power. A simple analytic expression of the nitrogen monoxide concentration is obtained in terms of the oxygen molecular density and gas flow rate. The experimental data agree remarkably well with the theoretical results from the analytical expression. A microwave nitrogen-torch can easily provide an appropriate nitrogen monoxide concentration for the wound healings.

  13. Effect of ammonia plasma treatment on graphene oxide LB monolayers

    SciTech Connect (OSTI)

    Singh, Gulbagh; Botcha, V. Divakar; Narayanam, Pavan K.; Sutar, D. S.; Talwar, S. S.; Major, S. S.; Srinivasa, R. S.

    2013-02-05

    Graphene oxide monolayer sheets were transferred on Si and SiO{sub 2}/Si substrates by Langmuir-Blodgett technique and were exposed to ammonia plasma at room temperature. The monolayer character of both graphene oxide and plasma treated graphene oxide sheets were ascertained by atomic force microscopy. X-ray photoelectron spectroscopy and Raman spectroscopy revealed that ammonia plasma treatment results in enhancement of graphitic carbon content along with the incorporation of nitrogen. The conductivity of graphene oxide monolayers, which was in the range of 10{sup -6}-10{sup -7} S/cm, increased to 10{sup -2}-10{sup -3} S/cm after the ammonia plasma treatment. These results indicate that the graphene oxide was simultaneously reduced and N-doped during ammonia plasma treatment, without affecting the morphological stability of sheets.

  14. Catalyst Additives to Enhance Mercury Oxidation and Capture

    SciTech Connect (OSTI)

    Thomas K. Gale

    2005-12-31

    Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. Three different SCR catalysts are currently being studied in this project--honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Future work to characterize flue gas simulations typically derived from low and high sulfur bituminous coal are being performed in a stepwise manner, to avoid the constant interruptions in testing that occur when leaks in the system are generated during temperature transitions. Specifically, chlorine concentration vs. mercury oxidation correlations will be developed for each catalyst. The contributions of temperature are also being investigated. SO2 oxidation is also being investigated for each test condition.

  15. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wongchang

    2014-05-13

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  16. Transgenic plants that exhibit enhanced nitrogen assimilation

    DOE Patents [OSTI]

    Coruzzi, Gloria M. (New York, NY); Brears, Timothy (Durham, NC)

    2000-01-01

    The present invention relates to a method for producing plants with improved agronomic and nutritional traits. Such traits include enhanced nitrogen assimilatory and utilization capacities, faster and more vigorous growth, greater vegetative and reproductive yields, and enriched or altered nitrogen content in vegetative and reproductive parts. More particularly, the invention relates to the engineering of plants modified to have altered expression of key enzymes in the nitrogen assimilation and utilization pathways. In one embodiment of the present invention, the desired altered expression is accomplished by engineering the plant for ectopic overexpression of one of more the native or modified nitrogen assimilatory enzymes. The invention also has a number of other embodiments, all of which are disclosed herein.

  17. Transgenic plants that exhibit enhanced nitrogen assimilation

    DOE Patents [OSTI]

    Coruzzi, Gloria M.; Brears, Timothy

    2005-03-08

    The present invention relates to a method for producing plants with improved agronomic and nutritional traits. Such traits include enhanced nitrogen assimilatory and utilization capacities, faster and more vigorous growth, greater vegetative and reproductive yields, and enriched or altered nitrogen content in vegetative and reproductive parts. More particularly, the invention relates to the engineering of plants modified to have altered expression of key enzymes in the nitrogen assimilation and utilization pathways. In one embodiment of the present invention, the desired altered expression is accomplished by engineering the plant for ectopic overexpression of one of more the native or modified nitrogen assimilatory enzymes. The invention also has a number of other embodiments, all of which are disclosed herein.

  18. Transgenic plants that exhibit enhanced nitrogen assimilation

    DOE Patents [OSTI]

    Coruzzi, Gloria M. (New York, NY); Brears, Timothy (Durham, NC)

    1999-01-01

    The present invention relates to a method for producing plants with improved agronomic and nutritional traits. Such traits include enhanced nitrogen assimilatory and utilization capacities, faster and more vigorous growth, greater vegetative and reproductive yields, and enriched or altered nitrogen content in vegetative and reproductive parts. More particularly, the invention relates to the engineering of plants modified to have altered expression of key enzymes in the nitrogen assimilation and utilization pathways. In one embodiment of the present invention, the desired altered expression is accomplished by engineering the plant for ectopic overexpression of one of more the native or modified nitrogen assimilatory enzymes. The invention also has a number of other embodiments, all of which are disclosed herein.

  19. Pressure drop, heat transfer, critical heat flux, and flow stability of two-phase flow boiling of water and ethylene glycol/water mixtures - final report for project "Efficent cooling in engines with nucleate boiling."

    SciTech Connect (OSTI)

    Yu, W.; France, D. M.; Routbort, J. L.

    2011-01-19

    Because of its order-of-magnitude higher heat transfer rates, there is interest in using controllable two-phase nucleate boiling instead of conventional single-phase forced convection in vehicular cooling systems to remove ever increasing heat loads and to eliminate potential hot spots in engines. However, the fundamental understanding of flow boiling mechanisms of a 50/50 ethylene glycol/water mixture under engineering application conditions is still limited. In addition, it is impractical to precisely maintain the volume concentration ratio of the ethylene glycol/water mixture coolant at 50/50. Therefore, any investigation into engine coolant characteristics should include a range of volume concentration ratios around the nominal 50/50 mark. In this study, the forced convective boiling heat transfer of distilled water and ethylene glycol/water mixtures with volume concentration ratios of 40/60, 50/50, and 60/40 in a 2.98-mm-inner-diameter circular tube has been investigated in both the horizontal flow and the vertical flow. The two-phase pressure drop, the forced convective boiling heat transfer coefficient, and the critical heat flux of the test fluids were determined experimentally over a range of the mass flux, the vapor mass quality, and the inlet subcooling through a new boiling data reduction procedure that allowed the analytical calculation of the fluid boiling temperatures along the experimental test section by applying the ideal mixture assumption and the equilibrium assumption along with Raoult's law. Based on the experimental data, predictive methods for the two-phase pressure drop, the forced convective boiling heat transfer coefficient, and the critical heat flux under engine application conditions were developed. The results summarized in this final project report provide the necessary information for designing and implementing nucleate-boiling vehicular cooling systems.

  20. Preparation of nitrogen-doped carbon tubes

    DOE Patents [OSTI]

    Chung, Hoon Taek; Zelenay, Piotr

    2015-12-22

    A method for synthesizing nitrogen-doped carbon tubes involves preparing a solution of cyanamide and a suitable transition metal-containing salt in a solvent, evaporating the solvent to form a solid, and pyrolyzing the solid under an inert atmosphere under conditions suitable for the production of nitrogen-doped carbon tubes from the solid. Pyrolyzing for a shorter period of time followed by rapid cooling resulted in a tubes with a narrower average diameter.

  1. Plant nitrogen regulatory P-PII genes

    DOE Patents [OSTI]

    Coruzzi, Gloria M. (New York, NY); Lam, Hon-Ming (Hong Kong, HK); Hsieh, Ming-Hsiun (Woodside, NY)

    2001-01-01

    The present invention generally relates to plant nitrogen regulatory PII gene (hereinafter P-PII gene), a gene involved in regulating plant nitrogen metabolism. The invention provides P-PII nucleotide sequences, expression constructs comprising said nucleotide sequences, and host cells and plants having said constructs and, optionally expressing the P-PII gene from said constructs. The invention also provides substantially pure P-PII proteins. The P-PII nucleotide sequences and constructs of the

  2. Effects of Nitrogen contamination in liquid Argon

    E-Print Network [OSTI]

    R. Acciarri; M. Antonello; B. Baibussinov; M. Baldo-Ceolin; P. Benetti; F. Calaprice; E. Calligarich; M. Cambiaghi; N. Canci; F. Carbonara; F. Cavanna; S. Centro; A. G. Cocco; F. Di Pompeo; G. Fiorillo; C. Galbiati; V. Gallo; L. Grandi; G. Meng; I. Modena; C. Montanari; O. Palamara; L. Pandola; F. Pietropaolo; G. L. Raselli; M. Roncadelli; M. Rossella; C. Rubbia; E. Segreto; A. M. Szelc; S. Ventura; C. Vignoli

    2008-04-08

    A dedicated test of the effects of Nitrogen contamination in liquid Argon has been performed at the INFN-Gran Sasso Laboratory (LNGS, Italy) within the WArP R&D program. A detector has been designed and assembled for this specific task and connected to a system for the injection of controlled amounts of gaseous Nitrogen into the liquid Argon. Purpose of the test is to detect the reduction of the Ar scintillation light emission as a function of the amount of the Nitrogen contaminant injected in the Argon volume. A wide concentration range, spanning from about 10^-1 ppm up to about 10^3 ppm, has been explored. Measurements have been done with electrons in the energy range of minimum ionizing particles (gamma-conversion from radioactive sources). Source spectra at different Nitrogen contaminations are analyzed, showing sensitive reduction of the scintillation yield at increasing concentrations. The rate constant of the light quenching process induced by Nitrogen in liquid Ar has been found to be k(N2)=0.11 micros^-1 ppm^-1. Direct PMT signals acquisition at high time resolution by fast Waveform recording allowed to extract with high precision the main characteristics of the scintillation light emission in pure and contaminated LAr. In particular, the decreasing behavior in lifetime and relative amplitude of the slow component is found to be appreciable from O(1 ppm) of Nitrogen concentrations.

  3. Nitrogen-doped mesoporous carbon for energy storage in vanadium redox flow batteries

    SciTech Connect (OSTI)

    Dai, Sheng [ORNL; Shao, Yuyan [Pacific Northwest National Laboratory (PNNL); Wang, Xiqing [ORNL; Engelhard, Mark H [Pacific Northwest National Laboratory (PNNL); Wang, Congmin [ORNL; Liu, Jun [Pacific Northwest National Laboratory (PNNL); YANG, ZHENGUO [Pacific Northwest National Laboratory (PNNL); Lin, Yuehe [ORNL

    2010-01-01

    We demonstrate an excellent performance of nitrogen-doped mesoporous carbon (N-MPC) for energy storage in vanadium redox flow batteries. Mesoporous carbon (MPC) is prepared using a soft-template method and doped with nitrogen by heat-treating MPC in NH{sub 3}. N-MPC is characterized with X-ray photoelectron spectroscopy and transmission electron microscopy. The redox reaction of [VO]{sup 2+}/[VO{sub 2}]{sup +} is characterized with cyclic voltammetry and electrochemical impedance spectroscopy. The electrocatalytic kinetics of the redox couple [VO]{sup 2+}/[VO{sub 2}]{sup +} is significantly enhanced on N-MPC electrode compared with MPC and graphite electrodes. The reversibility of the redox couple [VO]{sup 2+}/[VO{sub 2}]{sup +} is greatly improved on N-MPC (0.61 for N-MPC vs. 0.34 for graphite), which is expected to increase the energystorage efficiency of redoxflowbatteries. Nitrogen doping facilitates the electron transfer on electrode/electrolyte interface for both oxidation and reduction processes. N-MPC is a promising material for redoxflowbatteries. This also opens up new and wider applications of nitrogen-doped carbon.

  4. Final Report for DOE grant no. DE-FG02-04ER63883: Can soil genomics predict the impact of precipitation on nitrous oxide flux from soil

    SciTech Connect (OSTI)

    Egbert Schwartz

    2008-12-15

    Nitrous oxide is a potent greenhouse gas that is released by microorganisms in soil. However, the production of nitrous oxide in soil is highly variable and difficult to predict. Future climate change may have large impacts on nitrous oxide release through alteration of precipitation patterns. We analyzed DNA extracted from soil in order to uncover relationships between microbial processes, abundance of particular DNA sequences and net nitrous oxide fluxes from soil. Denitrification, a microbial process in which nitrate is used as an electron acceptor, correlated with nitrous oxide flux from soil. The abundance of ammonia oxidizing archaea correlated positively, but weakly, with nitrous oxide production in soil. The abundance of bacterial genes in soil was negatively correlated with gross nitrogen mineralization rates and nitrous oxide release from soil. We suggest that the most important control over nitrous oxide production in soil is the growth and death of microorganisms. When organisms are growing nitrogen is incorporated into their biomass and nitrous oxide flux is low. In contrast, when microorganisms die, due to predation or infection by viruses, inorganic nitrogen is released into the soil resulting in nitrous oxide release. Higher rates of precipitation increase access to microorganisms by predators or viruses through filling large soil pores with water and therefore can lead to large releases of nitrous oxide from soil. We developed a new technique, stable isotope probing with 18O-water, to study growth and mortality of microorganisms in soil.

  5. Evidence for the formation of nitrogen-rich precious metal nanoparticles

    SciTech Connect (OSTI)

    Veith, Gabriel M [ORNL; Lupini, Andrew R [ORNL; Baggetto, Loic [ORNL; Browning, Jim [ORNL; Keum, Jong Kahk [ORNL; Villa, Alberto [Universita di Milano, Italy; Prati, Laura [Universita di Milano, Italy; Papandrew, Alexander B [ORNL; Goenaga Jimenez, Gabriel A [ORNL; Mullins, David R [ORNL; Bullock, Steven E [ORNL; Dudney, Nancy J [ORNL

    2014-01-01

    We report evidence for the formation of nitrogen-rich precious metal nanoparticles (Pt, Pd) prepared by reactive sputtering of the pure metal in a N2 plasma. The composition of the nanoparticles varies as a function of particle size and growth conditions. For the smallest particles the nitrogen content appears to be as high as 6.7 N atoms for each Pd atom or 5.9 N atoms for each Pt atom whereas bulk films have nominal compositions of Pt7.3N and Pd2.5N. The nanoparticles are metastable in air and moisture, slowly decomposing over several years. This paper describes the synthesis of these materials along with experimental evidence of the composition, oxidation state, and growth modes. The catalytic properties of these N-rich nanoparticles were accessed by rotating disk electrode electrochemical studies, the liquid phase oxidation of benzyl alcohol and gas phase CO oxidation and support the experimental evidence for the materials composition.

  6. Availability of Some Nitrogenous and Phosphatic Materials. 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1922-01-01

    at this Station, some of which are reported in this bulletin. Some of these tests relate to the use of the materials as fertilizer, while others relate to their possible value to plants when occurring as soil minerals. These tests have been made from time... to ascertain the availability of the nitrogen in the wheat which was charred. The experiments were carried out in the usual manner. The charred wheat was ground, and a quantity used containing 0.1 gram of nitrogen to 5000 grams of soil. Acid phosphate...

  7. ONE DIMENSIONAL-TWO PHASE PARTICULATE FLOW

    E-Print Network [OSTI]

    Kleist, D.M.

    2011-01-01

    on Materials for Coal Gasification, MPC Contract No. 875-2",coal turbines and coal gasification plants. The importance

  8. Two-Phase Cooling of Power Electronics

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  9. Two phase exhaust for internal combustion engine

    DOE Patents [OSTI]

    Vuk, Carl T. (Denver, IA)

    2011-11-29

    An internal combustion engine having a reciprocating multi cylinder internal combustion engine with multiple valves. At least a pair of exhaust valves are provided and each supply a separate power extraction device. The first exhaust valves connect to a power turbine used to provide additional power to the engine either mechanically or electrically. The flow path from these exhaust valves is smaller in area and volume than a second flow path which is used to deliver products of combustion to a turbocharger turbine. The timing of the exhaust valve events is controlled to produce a higher grade of energy to the power turbine and enhance the ability to extract power from the combustion process.

  10. The dynamics of two-phase (gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired Solar FuelTechnologyTel: Name: Rm. Tel:Test1 April 2000 Anroad to E

  11. Photo-oxidation catalysts

    DOE Patents [OSTI]

    Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

    2009-07-14

    Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

  12. Stress dependent oxidation of sputtered niobium and effects on superconductivity

    SciTech Connect (OSTI)

    David Henry, M. Wolfley, Steve; Monson, Todd; Clark, Blythe G.; Shaner, Eric; Jarecki, Robert

    2014-02-28

    We report on the suppression of room temperature oxidation of DC sputtered niobium films and the effects upon the superconductive transition temperature, T{sub c}. Niobium was sputter-deposited on silicon dioxide coated 150?mm wafers and permitted to oxidize at room temperature and pressure for up to two years. Resistivity and stress measurements indicate that tensile films greater than 400?MPa resist bulk oxidation with measurements using transmission electron microscope, electron dispersive X-ray spectroscopy, x-ray photoelectric spectroscopy, and secondary ion mass spectrometry confirming this result. Although a surface oxide, Nb{sub 2}O{sub 5}, consumed the top 6–10?nm, we measure less than 1 at. % oxygen and nitrogen in the bulk of the films after the oxidation period. T{sub c} measurements using a SQUID magnetometer indicate that the tensile films maintained a T{sub c} approaching the dirty superconductive limit of 8.4?K after two years of oxidation while maintaining room temperature sheet resistance. This work demonstrates that control over niobium film stress during deposition can prevent bulk oxidation by limiting the vertical grain boundaries ability to oxidize, prolonging the superconductive properties of sputtered niobium when exposed to atmosphere.

  13. Biexciton emission from single isoelectronic traps formed by nitrogen-nitrogen pairs in GaAs

    SciTech Connect (OSTI)

    Takamiya, Kengo; Fukushima, Toshiyuki; Yagi, Shuhei; Hijikata, Yasuto; Yaguchi, Hiroyuki [Graduate School of Science and Engineering, Saitama University, 255 Shimo-Okubo, Sakura-ku , Saitama 338-8570 (Japan); Mochizuki, Toshimitsu; Yoshita, Masahiro; Akiyama, Hidefumi [Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Kuboya, Shigeyuki; Onabe, Kentaro [Department of Advanced Materials Science, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Katayama, Ryuji [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2013-12-04

    We have studied photoluminescence (PL) from individual isoelectronic traps formed by nitrogen-nitrogen (NN) pairs in GaAs. Sharp emission lines due to exciton and biexciton were observed from individual isoelectronic traps in nitrogen atomic-layer doped (ALD) GaAs. The binding energy of biexciton bound to individual isoelectronic traps was approximately 8 meV. Both the exciton and biexciton luminescence lines show completely random polarization and no fine-structure splitting. These results are desirable to the application to the quantum cryptography used in the field of quantum information technology.

  14. Impacts of Atmospheric Anthropogenic Nitrogen on the

    E-Print Network [OSTI]

    Ward, Bess

    discharges from wastewater treatment, atmospheric deposition, and so forth, resulting in increasing), including oxidized and reduced inorganic and organic forms. The availability of Nr limits primary pro

  15. Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition

    SciTech Connect (OSTI)

    Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

    2014-01-15

    The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

  16. Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air 2005 Diesel Engine...

  17. Global reactive nitrogen deposition from lightning NOx A. Shepon,1

    E-Print Network [OSTI]

    Gildor, Hezi

    ., 2002]. The anthropogenic perturbation to the nitrogen cycle (i.e., the increased fossil fuel usage of lightning activity [Price and Rind, 1994; Reeve and Toumi, 1999], creating more available nitrogen compounds

  18. Liquid absorbent solutions for separating nitrogen from natural gas

    DOE Patents [OSTI]

    Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Redmond, OR); Lyon, David K. (Bend, OR); Miller, Warren K. (Bend, OR)

    2000-01-01

    Nitrogen-absorbing and -desorbing compositions, novel ligands and transition metal complexes, and methods of using the same, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

  19. ORIGINAL ARTICLE Carbon and nitrogen fixation and

    E-Print Network [OSTI]

    Capone, Douglas G.

    capable of fixing both dinitrogen (N2) and carbon dioxide (CO2), deriving energy from oxygenicORIGINAL ARTICLE Carbon and nitrogen fixation and metabolite exchange in and between individual and was evenly allocated among vegetative cells, with the exception of the most remote vegetative cells between

  20. groundwater nitrogen source identification and remediation

    E-Print Network [OSTI]

    groundwater nitrogen source identification and remediation The Seymour Aquifer is a shallow aquifer, the Seymour Aquifer has the highest groundwater pollution potential of all the major aqui- fers in Texas drinking water standards. Potential sources of nitrate in groundwater include atmospheric deposi- tion

  1. Phase Discrimination through Oxidant Selection for Iron Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films Home > Research > ANSER Research Highlights > Phase Discrimination through Oxidant Selection for Iron...

  2. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Award In order to produce power more efficiently and cleanly, the next generation of power plant boilers, turbines, solid oxide fuel cells (SOFCs) and other essential equipment...

  3. Identifying Sources of Nitrogen to Hanalei Bay, Kauai, Utilizing the

    E-Print Network [OSTI]

    Paytan, Adina

    Identifying Sources of Nitrogen to Hanalei Bay, Kauai, Utilizing the Nitrogen Isotope Signature, Menlo Park, California 94025, and P.O. Box 681, Kilauea, Hawaii 96754 Sewage effluent, storm runoff of land derived nutrients into Hanalei Bay, Kauai. We determined the nitrogen isotopic signatures (15N

  4. Toward a mechanistic modeling of nitrogen limitation on vegetation dynamics

    SciTech Connect (OSTI)

    Xu, Chonggang [Los Alamos National Laboratory (LANL); Fisher, Rosie [National Center for Atmospheric Research (NCAR); Wullschleger, Stan D [ORNL; Wilson, Cathy [Los Alamos National Laboratory (LANL); Cai, Michael [Los Alamos National Laboratory (LANL); McDowell, Nathan [Los Alamos National Laboratory (LANL)

    2012-01-01

    Nitrogen is a dominant regulator of vegetation dynamics, net primary production, and terrestrial carbon cycles; however, most ecosystem models use a rather simplistic relationship between leaf nitrogen content and photosynthetic capacity. Such an approach does not consider how patterns of nitrogen allocation may change with differences in light intensity, growing-season temperature and CO{sub 2} concentration. To account for this known variability in nitrogen-photosynthesis relationships, we develop a mechanistic nitrogen allocation model based on a trade-off of nitrogen allocated between growth and storage, and an optimization of nitrogen allocated among light capture, electron transport, carboxylation, and respiration. The developed model is able to predict the acclimation of photosynthetic capacity to changes in CO{sub 2} concentration, temperature, and radiation when evaluated against published data of V{sub c,max} (maximum carboxylation rate) and J{sub max} (maximum electron transport rate). A sensitivity analysis of the model for herbaceous plants, deciduous and evergreen trees implies that elevated CO{sub 2} concentrations lead to lower allocation of nitrogen to carboxylation but higher allocation to storage. Higher growing-season temperatures cause lower allocation of nitrogen to carboxylation, due to higher nitrogen requirements for light capture pigments and for storage. Lower levels of radiation have a much stronger effect on allocation of nitrogen to carboxylation for herbaceous plants than for trees, resulting from higher nitrogen requirements for light capture for herbaceous plants. As far as we know, this is the first model of complete nitrogen allocation that simultaneously considers nitrogen allocation to light capture, electron transport, carboxylation, respiration and storage, and the responses of each to altered environmental conditions. We expect this model could potentially improve our confidence in simulations of carbon-nitrogen interactions and the vegetation feedbacks to climate in Earth system models.

  5. Methane oxidation rates by AMS

    E-Print Network [OSTI]

    Pack, M; Heintz, M; ReeburGh, WS; Trumbore, SE; Valentine, DL; Xu, X

    2009-01-01

    second case. Number of cases Methane oxidation rates by AMSIn the marine environment methane (CH 4 ) oxidation consumes

  6. Nitrogen control of chloroplast differentiation. Final report

    SciTech Connect (OSTI)

    Schmidt, G.W.

    1998-05-01

    This project was directed toward understanding at the physiological, biochemical and molecular levels of how photosynthetic organisms adapt to long-term nitrogen-deficiency conditions is quite incomplete even though limitation of this nutrient is the most commonly restricts plant growth and development. For our work on this problem, the unicellular green alga, Chlamydomonas reinhardtii, was grown in continuous cultures in which steady-state levels of nitrogen can be precisely controlled. N-limited cells exhibit the classical symptoms of deficiency of this nutrient, chlorosis and slow growth rates, and respond to nitrogen provision by rapid greening and chloroplast differentiation. We have addressed three aspects of this problem: (1) the regulation of pigment synthesis; (2) control of expression of nuclear genes encoding photosynthetic proteins; (3) changes in metabolic and electron transport pathways that enable sustained CO{sub 2} fixation even though they cannot be readily converted into amino and nucleic acids. For the last, principle components are: (a) enhanced mitochondrial respiratory activity intimately associated with photosynthates, and (b) the occurrence in thylakoids of a supplemental electron transport pathway that facilitates reduction of the plastoquinone pool. Together, these distinguishing features of N-limited cells are likely to enable cell survival, especially under conditions of high irradiance stress.

  7. Plant nitrogen regulatory P-PII polypeptides

    DOE Patents [OSTI]

    Coruzzi, Gloria M.; Lam, Hon-Ming; Hsieh, Ming-Hsiun

    2004-11-23

    The present invention generally relates to plant nitrogen regulatory PII gene (hereinafter P-PII gene), a gene involved in regulating plant nitrogen metabolism. The invention provides P-PII nucleotide sequences, expression constructs comprising said nucleotide sequences, and host cells and plants having said constructs and, optionally expressing the P-PII gene from said constructs. The invention also provides substantially pure P-PII proteins. The P-PII nucleotide sequences and constructs of the invention may be used to engineer organisms to overexpress wild-type or mutant P-PII regulatory protein. Engineered plants that overexpress or underexpress P-PII regulatory protein may have increased nitrogen assimilation capacity. Engineered organisms may be used to produce P-PII proteins which, in turn, can be used for a variety of purposes including in vitro screening of herbicides. P-PII nucleotide sequences have additional uses as probes for isolating additional genomic clones having the promoters of P-PII gene. P-PII promoters are light- and/or sucrose-inducible and may be advantageously used in genetic engineering of plants.

  8. Partial oxidation catalyst

    DOE Patents [OSTI]

    Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

    2000-01-01

    A two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion. The dehydrogenation portion is a group VIII metal and the oxide-ion conducting portion is selected from a ceramic oxide crystallizing in the fluorite or perovskite structure. There is also disclosed a method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

  9. Strengthening of metallic alloys with nanometer-size oxide dispersions

    DOE Patents [OSTI]

    Flinn, J.E.; Kelly, T.F.

    1999-06-01

    Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains. 20 figs.

  10. Strengthening of metallic alloys with nanometer-size oxide dispersions

    DOE Patents [OSTI]

    Flinn, John E. (Idaho Falls, ID); Kelly, Thomas F. (Madison, WI)

    1999-01-01

    Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains.

  11. THE EFFECTS OF INITIAL ABUNDANCES ON NITROGEN IN PROTOPLANETARY DISKS

    SciTech Connect (OSTI)

    Schwarz, Kamber R.; Bergin, Edwin A.

    2014-12-20

    The dominant form of nitrogen provided to most solar system bodies is currently unknown, though available measurements show that the detected nitrogen in solar system rocks and ices is depleted with respect to solar abundances and the interstellar medium. We use a detailed chemical/physical model of the chemical evolution of a protoplanetary disk to explore the evolution and abundance of nitrogen-bearing molecules. Based on this model, we analyze how initial chemical abundances provided as either gas or ice during the early stages of disk formation influence which species become the dominant nitrogen bearers at later stages. We find that a disk with the majority of its initial nitrogen in either atomic or molecular nitrogen is later dominated by atomic and molecular nitrogen as well as NH{sub 3} and HCN ices, where the dominant species varies with disk radius. When nitrogen is initially in gaseous ammonia, it later becomes trapped in ammonia ice except in the outer disk where atomic nitrogen dominates. For a disk with the initial nitrogen in the form of ammonia ice, the nitrogen remains trapped in the ice as NH{sub 3} at later stages. The model in which most of the initial nitrogen is placed in atomic N best matches the ammonia abundances observed in comets. Furthermore, the initial state of nitrogen influences the abundance of N{sub 2}H{sup +}, which has been detected in protoplanetary disks. Strong N{sub 2}H{sup +} emission is found to be indicative of an N{sub 2} abundance greater than n{sub N{sub 2}}/n{sub H{sub 2}}>10{sup ?6} in addition to tracing the CO snow line. Our models also indicate that NO is potentially detectable, with lower N gas abundances leading to higher NO abundances.

  12. Separation of metallic residues from the dissolution of a high-burnup BWR fuel using nitrogen trifluoride

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Buck, Edgar C.; Soderquist, Chuck Z.; Smith, Frances N.; Mausolf, Edward J.; Scheele, Randall D.

    2014-02-10

    Nitrogen trifluoride (NF3) was used to fluorinate the metallic residue from the dissolution of a high burnup, boiling water reactor fuel (?70 MWd/kgU). The metallic residue included the noble metal phase (containing ruthenium, rhodium, palladium, technetium, and molybdenum), and smaller amounts of zirconium, selenium, tellurium, and silver. Exposing the noble metal phase to 10% NF3 in argon between 400 and 550?C, removed molybdenum and technetium near 400?C as their volatile fluorides, and ruthenium near 500?C as its volatile fluoride. The events were thermally and temporally distinct and the conditions specified are a recipe to separate these transition metals from each other and from the noble metal phase nonvolatile residue. Depletion of the volatile fluorides resulted in substantial exothermicity. Thermal excursion behavior was recorded under non-adiabatic, isothermal conditions that typically minimize heat release. Physical characterization of the metallic noble phase and its thermal behavior are consistent with high kinetic velocity reactions encouraged by the nanoparticulate phase or perhaps catalytic influences of the mixed platinum metals with nearly pure phase structure. Post-fluorination, only two phases were present in the residual nonvolatile fraction. These were identified as a nano-crystalline, metallic palladium cubic phase and a hexagonal rhodium trifluoride (RhF3) phase. The two phases were distinct as the sub-µm crystallites of metallic palladium were in contrast to the RhF3 phase, which grew from the parent nano-crystalline noble-metal phase during fluorination, to acicular crystals exceeding 20-µm in length.

  13. ZIRCONIUM OXIDE NANOSTRUCTURES PREPARED BY ANODIC OXIDATION

    SciTech Connect (OSTI)

    Dang, Y. Y.; Bhuiyan, M.S.; Paranthaman, M. P.

    2008-01-01

    Zirconium oxide is an advanced ceramic material highly useful for structural and electrical applications because of its high strength, fracture toughness, chemical and thermal stability, and biocompatibility. If highly-ordered porous zirconium oxide membranes can be successfully formed, this will expand its real-world applications, such as further enhancing solid-oxide fuel cell technology. Recent studies have achieved various morphologies of porous zirconium oxide via anodization, but they have yet to create a porous layer where nanoholes are formed in a highly ordered array. In this study, electrochemical methods were used for zirconium oxide synthesis due to its advantages over other coating techniques, and because the thickness and morphology of the ceramic fi lms can be easily tuned by the electrochemical parameters, such as electrolyte solutions and processing conditions, such as pH, voltage, and duration. The effects of additional steps such as pre-annealing and post-annealing were also examined. Results demonstrate the formation of anodic porous zirconium oxide with diverse morphologies, such as sponge-like layers, porous arrays with nanoholes ranging from 40 to 75 nm, and nanotube layers. X-ray powder diffraction analysis indicates a cubic crystallographic structure in the zirconium oxide. It was noted that increased voltage improved the ability of the membrane to stay adhered to the zirconium substrate, whereas lower voltages caused a propensity for the oxide fi lm to fl ake off. Further studies are needed to defi ne the parameters windows that create these morphologies and to investigate other important characteristics such as ionic conductivity.

  14. Electro Catalytic Oxidation (ECO) Operation

    SciTech Connect (OSTI)

    Morgan Jones

    2011-03-31

    The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

  15. Oxidation Resistant Graphite Studies

    SciTech Connect (OSTI)

    W. Windes; R. Smith

    2014-07-01

    The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

  16. High-temperature-oxidation-induced ordered structure in Inconel 939 superalloy exposed to oxy-combustion environments

    SciTech Connect (OSTI)

    Zhu, Jingxi; Wise, Adam; Nuhfer, Thomas; Holcomb, Gordon R.; Jablonski, Paul D.; Sridhar, Seetharaman; Laughlin, David E.

    2013-04-20

    In the integrated oxy-fuel combustion and turbine power generation system, turbine alloys are exposed to high temperature and an atmosphere comprised of steam, CO2 and O2. While surface and internal oxidation of the alloy takes place, the microstructure in the subsurface region also changes due to oxidation that results in the loss of the strengthening precipitates. In an earlier study of the oxidation of Inconel 939 Ni-based superalloy exposed to oxy-fuel combustion environment for up to 1000 hours, a high-temperature-oxidation-induced phase transformation in the sub-surface region was noticed and a two-phase region formed at the expense of strengthening ?' phase. While one of the two phases was identified as the Ni-matrix (? solid solution, face-center-cubic) phase, the other product phase remained unidentified. In this study, the crystal structure of the unknown phase and its orientation relationship with the parent Ni-matrix phase was investigated through electron diffraction and high-resolution transmission electron microscopy. It was determined that the crystal structure of the unknown phase could be modeled as a ternary derivative of the ordered ?-Ni3Ti phase (D024) structure with lattice parameters of a = 0.5092 nm and c = 0.8336 nm, ? = 90º, ? = 90º and ? = 120º.

  17. PROTOSOLAR AMMONIA AS THE UNIQUE SOURCE OF TITAN's NITROGEN

    SciTech Connect (OSTI)

    Mandt, Kathleen E.; Mousis, Olivier; Gautier, Daniel

    2014-06-20

    The origin of Titan's nitrogen-rich atmosphere is thought to be ammonia ice, but this has not yet been confirmed. Furthermore, it is uncertain whether the building blocks of Titan formed within the Saturnian subnebula or in the colder protosolar nebula (PSN). Recent measurements of the nitrogen isotope ratio in cometary ammonia, combined with evolutionary constraints on the nitrogen isotopes in Titan's atmosphere provide firm evidence that the nitrogen in Titan's atmosphere must have originated as ammonia ice formed in the PSN under conditions similar to that of cometary formation. This result has important implications for the projected D/H ratio in cometary methane, nitrogen isotopic fractionation in the PSN and the source of nitrogen for Earth's atmosphere.

  18. Involvement of peptides in nitrogen fixation 

    E-Print Network [OSTI]

    Ahlgren, Joy Annette

    1983-01-01

    molecular weight. 4 Effect of fixed nitrogen (Ca(NO&)z) on the nodula- tion (the number of nodules per plant), growth of nodules (mg per nodule), nitrogenase activity (acetylene reduction assay), and soyrhizin A con- tent in arginine equivalents. 22... solution and 0. 2 g of picric acid were mixed, the volume reduced to 10 approximately 20 ml by vacuum evaporation, and then centrifuged at 25, 000g for 20 min. Each of these samples was eluted from a column of 10 0 go e AG 248 e 1 . F o Rhitohiom 2~4 tc...

  19. Nitrogen removal from natural gas using two types of membranes

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.; Wijmans, Johannes G.; Da Costa, Andre R.

    2003-10-07

    A process for treating natural gas or other methane-rich gas to remove excess nitrogen. The invention relies on two-stage membrane separation, using methane-selective membranes for the first stage and nitrogen-selective membranes for the second stage. The process enables the nitrogen content of the gas to be substantially reduced, without requiring the membranes to be operated at very low temperatures.

  20. Worldwide organic soil carbon and nitrogen data

    SciTech Connect (OSTI)

    Zinke, P.J.; Stangenberger, A.G.; Post, W.M.; Emanual, W.R.; Olson, J.S.

    1986-09-01

    The objective of the research presented in this package was to identify data that could be used to estimate the size of the soil organic carbon pool under relatively undisturbed soil conditions. A subset of the data can be used to estimate amounts of soil carbon storage at equilibrium with natural soil-forming factors. The magnitude of soil properties so defined is a resulting nonequilibrium values for carbon storage. Variation in these values is due to differences in local and geographic soil-forming factors. Therefore, information is included on location, soil nitrogen content, climate, and vegetation along with carbon density and variation.

  1. Stanford Nitrogen Group | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation ofAlbuquerque|SensitiveApril 2, 2014ApplicationLanceStaffStanford Nitrogen

  2. METAL OXIDE NANOPARTICLES

    SciTech Connect (OSTI)

    FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

    2007-10-01

    This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

  3. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  4. Increasing Price of Nitrogen Nitrogen fertilizer is often the largest contributor to the

    E-Print Network [OSTI]

    events; the distribution of more than 5,700 publications; and access to web-based guidance on deep and associated costs. Since 2007, the importance of deep-soil testing for nitrogen management has been-sampling methods and procedures. Economic and Environmental Impact The economic impact of deep-soil testing

  5. Lesson Title: Nitrogen Cycle Game Date: February 1, 2008 Author: Ryan Lenz Topic: Nitrogen Cycle

    E-Print Network [OSTI]

    !" "Waste" is a relative term--some animals' waste is another's food. !" The sun is the driving force a nitrogen molecule as it is passed around the food chain. This lesson should be preceded or followed. Objectives: Students will understand that: !" Animal waste is recycled by other organisms, often bacteria

  6. Absorption of Foliar-Applied Nitrogen by Cotton

    E-Print Network [OSTI]

    Oosterhuis, Derrick M

    2009-01-01

    on the epicuticular wax composition and ultrastructure ofleaf age, epicuticular wax, and nitrogen-15 absorption. Cropleaf cuticle and epicuticular wax as described by Oosterhuis

  7. Effects of atmospheric inorganic nitrogen deposition on ocean biogeochemistry

    E-Print Network [OSTI]

    Moore, Keith

    nitrogen (ammonia and nitrate) sources include fossil fuel combustion [Hameed and Dignon, 1988], biomass burning, soil emissions and breakdown of urea from domestic animals [Warneck, 1988]. Jickells [2005

  8. Raman spectroscopy in hot compressed hydrogen and nitrogen -...

    Office of Scientific and Technical Information (OSTI)

    Raman spectroscopy in hot compressed hydrogen and nitrogen - implications for the intramolecular potential Citation Details In-Document Search Title: Raman spectroscopy in hot...

  9. COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES

    E-Print Network [OSTI]

    Matthews, Ronald D.

    2013-01-01

    SAE Paper 750173, 1975. L. , Fifteenth Symposium Combustion,The Combustion Institute, International Pittsburgh, on 64.chemistry of products of combustion: nitrogenous The

  10. Carbon and Nitrogen Cycling in Snow-Covered Environments

    E-Print Network [OSTI]

    Grogan, Paul

    snow cover through shading, wind sheltering, and interception. Changes in snow cover associated and nitrogen cycling. Introduction Approximately 60% of the terrestrial earth surface experiences seasonal snow

  11. Modeling nitrogen cycling in forested watersheds of Chesapeake Bay

    SciTech Connect (OSTI)

    Hunsaker, C.T.; Garten, C.T.; Mulholland, P.J.

    1995-03-01

    The Chesapeake Bay Agreement calls for a 40% reduction of controllable phosphorus and nitrogen to the tidal Bay by the year 2000. To accomplish this goal the Chesapeake Bay Program needs accurate estimates of nutrient loadings, including atmospheric deposition, from various land uses. The literature was reviewed on forest nitrogen pools and fluxes, and nitrogen data from research catchments in the Chesapeake Basin were identified. The structure of a nitrogen module for forests is recommended for the Chesapeake Bay Watershed Model along with the possible functional forms for fluxes.

  12. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  13. Nitrogen fixation in peanut nodules during dark periods and detopped conditions with special reference to lipid bodies

    SciTech Connect (OSTI)

    Siddique, A.M.; Bal, A.K. (Memorial Univ. of Newfoundland, St. John's (Canada))

    1991-03-01

    The peanut plant (Arachis hypogaea L.), unlike other known legumes, can sustain nitrogen fixation when prolonged periods of darkness or detopping curtail the supply of photosynthate to the nodule. This ability to withstand photosynthate stress is attributed to the presence of lipid bodies in infected nodule cells. In both dark-treated and detopped plants, the lipid bodies show a gradual decrease in numbers, suggesting their utilization as a source of energy and carbon for nitrogen fixation. Lipolytic activity can be localized in the lipid bodies, and the existence of {beta}-oxidation pathway and glyoxylate cycle is shown by the release of {sup 14}CO{sub 2} from {sup 14}C lineoleoyl coenzyme A by the nodule homogenate.

  14. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

    1988-01-01

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  15. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Nyaiesh, A.R.; Garwin, E.L.

    1986-08-04

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  16. Multi-component Zirconia-Titania Mixed Oxides: Catalytic Materials with Unprecedented Performance in the Selective Catalytic Reduction of NOx

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    in the Selective Catalytic Reduction of NOx with NH3 after harsh hydrothermal ageing. Nathalie MARCOTTE1#, Bernard catalytic reduction. 1. Introduction. The abatement of nitrogen oxides (NOx) and particulate matter (PM% H2O, ~ 1050 K) is a prerequisite for deNOx catalysts of tomorrow in Diesel exhaust gas treatment

  17. Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide

    E-Print Network [OSTI]

    Kim, Sehun

    Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide catalytic systems.12,13 On the other hand, the reduced graphene oxide (rGO) is functionalized graphene Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO

  18. Transformation of the Nitrogen Cycle: Recent Trends, Questions, and

    E-Print Network [OSTI]

    Schweik, Charles M.

    production in some parts of the world is nitrogen-deficient, highlighting inequities in the distribution energy production by coal, natural gas, and petroleum combustion increased from 8543 million tons of oil. Martinelli,7 Sybil P. Seitzinger,8 Mark A. Sutton9 Humans continue to transform the global nitrogen cycle

  19. How extensive are the impacts of nitrogen pollution in Great

    E-Print Network [OSTI]

    How extensive are the impacts of nitrogen pollution in Great Britain's forests? Protecting our forests from pollutant deposition is and has been a topical issue for some time. Nitrogen, as well as being an essential nutrient for trees, is one of the most important of these pollutants. This article

  20. Quantum optics with nitrogen-vacancy centers in diamond

    E-Print Network [OSTI]

    Yiwen Chu; Mikhail D. Lukin

    2015-04-22

    We review the electronic level structure of the nitrogen-vacancy in diamond and some common experimental techniques to study its optical properties at low temperatures. We then summarize several recent experiments and advances in using nitrogen-vacancy centers for quantum optics.

  1. Materials Safety Liquid Nitrogen Safety! ! A Message from Rick Kelly

    E-Print Network [OSTI]

    (special cryo- gen gloves or leather) and safety glasses with side shields. When dispensing liquid nitrogen from a pressurized dewar, or at any time that a splash may occur, a face shield should also be used as possible. Dispensing from Bulk Stor! age Tanks: Anyone who will be handling liquid nitrogen must complete

  2. Nitrogen Fertilization of Irrigated Cotton as Fertilizer Prices Climb

    E-Print Network [OSTI]

    Mukhtar, Saqib

    Nitrogen Fertilization of Irrigated Cotton as Fertilizer Prices Climb As gasoline prices at the pump continue to climb above $ 3.00/gallon, fertilizer prices, especially Nitrogen (N) are doing the same. As of spring 2008, the price of one ton of urea ammonium nitrate was $420, or $0.67 per lb N

  3. Mechanisms of plant species impacts on ecosystem nitrogen cycling

    E-Print Network [OSTI]

    Thomas, David D.

    in nitrification, denitrification and trace nitrogen gas losses. Plant species also impact herbivore behaviourREVIEW Mechanisms of plant species impacts on ecosystem nitrogen cycling J. M. H. Knops,1 * K. L. Bradley1 and D. A. Wedin2 1 School of Biological Sciences, 2 School of Natural Resource Sciences

  4. Microbial immobilization drives nitrogen cycling differences among plant species

    E-Print Network [OSTI]

    Thomas, David D.

    1840 Microbial immobilization drives nitrogen cycling differences among plant species Ramesh cycling. We examined four potential mechanisms of plant species effects on nitrogen (N) cycling. We found no species differences in gross ammonification suggesting there are no changes in the ecosystem N cycling

  5. Breath is a mixture of nitrogen, oxygen, carbon dioxide, water

    E-Print Network [OSTI]

    12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide, as the products of normal metabolism and those that have altered owing to disease, and are transported via

  6. THERMAL DIFFUSION OF HEAT PULSE IN SUBCOOLED LIQUID NITROGEN

    E-Print Network [OSTI]

    Chang, Ho-Myung

    and result in better thermal protection and faster recovery from a heat pulse. KEYWORDS: Heat TransferTHERMAL DIFFUSION OF HEAT PULSE IN SUBCOOLED LIQUID NITROGEN H. M. Chang1 , J. J. Byun1 , J. H ABSTRACT Transient heat transfer caused by a heat pulse in subcooled liquid nitrogen is investigated

  7. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wonchang

    2010-05-18

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2-y-zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  8. Toward Institutional Sustainability: A Nitrogen Footprint for the Marine Biological Maggie Notopoulos

    E-Print Network [OSTI]

    Vallino, Joseph J.

    impact on the environment. Many people have focused on improving their carbon footprint, or releaseToward Institutional Sustainability: A Nitrogen Footprint for the Marine Biological Laboratory is defined as the institution's nitrogen footprint. The Marine Biological Laboratory's nitrogen footprint

  9. Process for separating nitrogen from methane using microchannel process technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

    2007-07-31

    The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

  10. Removal of basic nitrogen compounds from hydrocarbon liquids

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Hoover, David S. (New Tripoli, PA)

    1985-01-01

    A method is provided for reducing the concentration of basic nitrogen compounds in hydrocarbonaceous feedstock fluids used in the refining industry by providing a solid particulate carbonaceous adsorbent/fuel material such as coal having active basic nitrogen complexing sites on the surface thereof and the coal with a hydrocarbonaceous feedstock containing basic nitrogen compounds to facilitate attraction of the basic nitrogen compounds to the complexing sites and the formation of complexes thereof on the surface of the coal. The adsorbent coal material and the complexes formed thereon are from the feedstock fluid to provide a hydrocarbonaceous fluid of reduced basic nitrogen compound concentration. The coal can then be used as fuel for boilers and the like.

  11. Catalyst Additives to Enhance Mercury Oxidation and Capture

    SciTech Connect (OSTI)

    Jared W. Cannon; Thomas K. Gale

    2004-12-31

    Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. Three different SCR catalysts are being studied. These are honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts are manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Test methods and experimental procedures were developed for current and future testing. The methods and procedures equalize factors influencing mercury adsorption and oxidation (surface area, catalyst activity, and pore structure) that normally differ for each catalyst type. Initial testing was performed to determine the time necessary for each catalyst to reach surface-adsorption equilibrium. In addition, the fraction of Hg oxidized by each of the SCR catalyst types is being investigated, for a given amount of catalyst and flow rate of mercury and flue gas. The next major effort will be to examine the kinetics of mercury oxidation across the SCR catalysts with respect to changes in mercury concentration and with respect to HCl concentration. Hg-sorption equilibrium times will also be investigated with respect to ammonia concentration in the simulated flue gas.

  12. Spectroscopic detection of nitrogen concentrations in sagebrush

    SciTech Connect (OSTI)

    J. J. MITCHELL; N. F. GLENN; T.T. SANKEY; D. R. DERRYBERRY; R. C. HRUSKA; M. O. Anderson

    2012-07-01

    The ability to estimate foliar nitrogen (N) in semi-arid landscapes can yield information on nutritional status and improve our limited understanding of controls on canopy photosynthesis. We examined two spectroscopic methods for estimating sagebrush dried leaf and live shrub N content: first derivative reflectance (FDR) and continuum removal. Both methods used partial least squares (PLS) regression to select wavebands most significantly correlated with N concentrations in the samples. Sagebrush dried leaf spectra produced PLS models (R2 = 0.76–0.86) that could predict N concentrations within the dataset more accurately than PLS models generated from live shrub spectra (R2 = 0.41–0.63). Inclusion of wavelengths associated with leaf water in the FDR transformations appeared to improve regression results. Findings are encouraging and warrant further exploration into sagebrush reflectance spectra to characterize N concentrations.

  13. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    combustion with excess oxygen that is typical of gas turbinescombustion processes. 14 Automobile engines, gas turbines,

  14. Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions

    E-Print Network [OSTI]

    Millstein, Dev

    2009-01-01

    E. , (2000). Spectral analysis of air pollutants. Part 1:time series and analyses of air quality model outputs will

  15. Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions

    E-Print Network [OSTI]

    Millstein, Dev

    2009-01-01

    3 Community Multiscale Air Quality (CMAQ) model aerosoland its role in regional air quality. Science, 311, 67-70.aerosol in Fresno, CA. J. Air Waste Manage. Assoc. , 56,

  16. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    and Japan. 8 Volkswagen 2009 TDIl-TDI-Motor von Volkswagen für niedrigste Abgasgrenzwerte –l-TDI-Motor von Volkswagen für niedrigste Abgasgrenzwerte –

  17. Air Quality Responses to Changes in Black Carbon and Nitrogen Oxide Emissions

    E-Print Network [OSTI]

    Millstein, Dev

    2009-01-01

    894-895. Harley, R. A. , Marr, L. C. , Lehner, J. K. , andAssoc. , 50, 1236-1250. Marr, L. C. , and Harley, R. A. , (Environ. , 36, 2327-2335. Marr, L. C. , and Harley, R.

  18. Variability in wildfire emissions of nitrogen oxides as observed from space

    E-Print Network [OSTI]

    Mebust, Anna

    2013-01-01

    using wind at 850 hPa from the NCEP Climate Forecast Systemand wind vectors at 850 hPa from the Climate Forecast Systemwind fields from the National Centers for Environmental Prediction (NCEP) Climate Forecast

  19. Reducing nitrogen oxides emissions from the combustion of LCV gas staged firing 

    E-Print Network [OSTI]

    Finch, Stanley Frank

    1986-01-01

    have to meet per mit division guidelines or produce less than 227 Ng (250 tons) per year of NOx on an N02 basis (TACH, 1985). The primary fuel under consideration, cotton gin trash, is approximately 2$ nitr ogen by weight. The applicable TACB...~ (Zeldovich, 1946): N2 + 0~NO+ N N+ 02~NO+ 0 (2) Obviously, before these reactions can take place 02 must dissociate, which requir es high temperature. Reaction 1 is the rate control 1 ing step because of its large acti va- tion energy. According to Wark...

  20. Reducing Emissions of Sulfur Dioxide, Nitrogen Oxides, and Mercury from Electric Power Plants

    Reports and Publications (EIA)

    2001-01-01

    This analysis responds to a request from Senators Bob Smith, George Voinovich, and Sam Brownback to examine the costs of specific multi-emission reduction strategies.

  1. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    Chou, Steve Dai, Ramesh Koripella, Manny Oliver, Daniel Sadler, PaulChou, Steve Dai, Ramesh Koripella, Manny Oliver, Daniel Sadler, Paul

  2. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    deposited by atomic layer deposition ALD: a structural,Paul C. McIntyre, "Atomic Layer Deposition of Y 2 O 3 /ZrO 2rate-determining step Atomic layer Deposition Ammonium

  3. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    material has refractory properties that make it also useful for kiln furniture and for thermal barrier coatings for gas turbine

  4. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    shrinkage of approximately 45% after sintering. 4.1 Introduction Since the inception of the tape-casting

  5. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    Serge, Electrochemistry of Zirconia Gas Sensors, New York:and A. C. Young, "Gelcast Zirconia-Alumina Composites", 15thand A. C. Young, "Gelcast Zirconia-Alumina Composites", 15th

  6. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    James, "Study of solid electrolyte polarization by a complexThe NO 2 response of solid electrolyte sensors made usingTechnologies using Solid Electrolytes in Measuring Gas

  7. Nanocomposites for nitrogen oxide emissions control in lean-burn engines

    E-Print Network [OSTI]

    Pitukmanorom, Pemakorn, 1976-

    2004-01-01

    (cont.) reducing agent than propane in the SCR of NO. Pt-Rh/CuO/A1?O? nanocomposites capable of adsorbing SO? in oxygen-rich environment as metal sulfates and releasing SO? in reducing atmosphere were synthesized with ...

  8. Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions Control

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  9. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    Low Temperature Electrodes for SOFC’s”, EPRI /GRI / DOE FuelSm 0.5 Sr 0.5 CoO 3 as SOFC cathode", Sol. Stat. Ion. ,Low Temperature Electrodes for SOFC’s”, EPRI /GRI / DOE Fuel

  10. Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 -Rob Roberts About Us Rob Roberts - Former DirectorControl |

  11. Nitrogen Oxides as a Chemistry Trap in Detonating Oxygen-Rich Materials

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech Connect Nanomechanical switch for| SciTechPhaseNewton's Method(Conference)modes

  12. Nitrogen Oxides as a Chemistry Trap in Detonating Oxygen-Rich Materials

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech Connect Nanomechanical switch for| SciTechPhaseNewton's

  13. NEPTUNIUM OXIDE PROCESSING

    SciTech Connect (OSTI)

    Jordan, J; Watkins, R; Hensel, S

    2009-05-27

    The Savannah River Site's HB-Line Facility completed a campaign in which fifty nine cans of neptunium oxide were produced and shipped to the Idaho National Laboratory in the 9975 shipping container. The neptunium campaign was divided into two parts: Part 1 which consisted of oxide made from H-Canyon neptunium solution which did not require any processing prior to conversion into an oxide, and Part 2 which consisted of oxide made from additional H-Canyon neptunium solutions which required processing to purify the solution prior to conversion into an oxide. The neptunium was received as a nitrate solution and converted to oxide through ion-exchange column extraction, precipitation, and calcination. Numerous processing challenges were encountered in order make a final neptunium oxide product that could be shipped in a 9975 shipping container. Among the challenges overcome was the issue of scale: translating lab scale production into full facility production. The balance between processing efficiency and product quality assurance was addressed during this campaign. Lessons learned from these challenges are applicable to other processing projects.

  14. Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas Consumption After Energy Assessment Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas...

  15. Surface-induced charge state conversion of nitrogen-vacancy defects in nanodiamonds

    E-Print Network [OSTI]

    Rondin, L; Slablab, A; Treussart, F; Bergonzo, P; Perruchas, S; Gacoin, T; Chaigneau, M; Chang, H -C; Jacques, V; Roch, J -F

    2010-01-01

    We present a study of the charge state conversion of single nitrogen-vacancy (NV) defects hosted in nanodiamonds whose size ranges from 10 nm to 100 nm. We first show that after irradiation and annealing of the nanodiamond powder, the proportion of negatively-charged NV- defects, with respect to its neutral counterpart NV0, decreases with the size of the nanoparticle. We propose a simple model based on a layer of electron traps located at the nanodiamond surface which is in good agreement with the statistics we recorded. By using thermal oxidation to remove the shell of amorphous carbon around the nanodiamonds, we achieve a significant increase of the proportion of NV- defects in approximately 10-nm nanodiamonds. These results demonstrate the importance of controlling the nanodiamond surface for the development of the numerous applications of NV centers which are made possible by their unique photostability and spin properties.

  16. Surface-induced charge state conversion of nitrogen-vacancy defects in nanodiamonds

    E-Print Network [OSTI]

    L. Rondin; G. Dantelle; A. Slablab; F. Grosshans; F. Treussart; P. Bergonzo; S. Perruchas; T. Gacoin; M. Chaigneau; H. -C. Chang; V. Jacques; J. -F. Roch

    2010-10-19

    We present a study of the charge state conversion of single nitrogen-vacancy (NV) defects hosted in nanodiamonds (NDs). We first show that the proportion of negatively-charged NV$^{-}$ defects, with respect to its neutral counterpart NV$^{0}$, decreases with the size of the ND. We then propose a simple model based on a layer of electron traps located at the ND surface which is in good agreement with the recorded statistics. By using thermal oxidation to remove the shell of amorphous carbon around the NDs, we demonstrate a significant increase of the proportion of NV$^{-}$ defects in 10-nm NDs. These results are invaluable for further understanding, control and use of the unique properties of negatively-charged NV defects in diamond

  17. Undoped and doped poly(tetraphenylbenzidine) as sensitive material for an impedimetric nitrogen dioxide gas dosimeter

    SciTech Connect (OSTI)

    Marr, I.; Moos, R.; Neumann, K.; Thelakkat, M.

    2014-09-29

    This article presents a nitrogen dioxide (NO{sub 2}) detecting gas dosimeter based on poly(tetraphenylbenzidine) poly(TPD) as nitrogen oxide (NO{sub x}) sensitive layer. Gas dosimeters are suitable devices to determine reliably low levels of analytes over a long period of time. During NO{sub x} exposure, the analyte molecules are accumulated irreversibly in the sensing layer of the dosimeter enhancing the conductivity of the hole conducting poly(TPD), which can be measured by impedance spectroscopy. Due to their possibility for low cost production by simple printing techniques and very good physical, photochemical, and electrochemical properties, poly(TPD)s are suitable for application in gas dosimeters operated at room temperature. We studied the effect of doping with a Co(III)-complex in combination with a conducting salt on the dosimeter behavior. Compared to the undoped material, a strong influence of the doping can be observed: the conductivity of the sensing material increases significantly, the noise of the signal decreases and an unwanted recovery of the sensor signal can be prevented, leading to a NO{sub x} detection limit <10?ppm.

  18. Catalyst Additives to Enhance Mercury Oxidation and Capture

    SciTech Connect (OSTI)

    Alex J. Berry; Thomas K. Gale

    2005-09-30

    Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. The testing was performed at Southern Research's Catalyst Test Facility, a bench-scale reactor capable of simulating gas-phase reactions occurring in coal-fired utility pollution-control equipment. Three different SCR catalysts are currently being studied in this project - honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Methods and procedures for experimental testing continue to be developed to produce the highest quality mercury-oxidation data. Most experiments so far have focused on testing the catalysts in a simulated Powder River Basin (PRB) flue-gas environment, which contains lower sulfur and chlorine than produced by other coals. Future work to characterize flue gas simulations typically derived from low and high sulfur bituminous coal will be performed in a stepwise manner, to avoid the constant interruptions in testing that occur when leaks in the system are generated during temperature transitions. Specifically, chlorine concentration vs. mercury oxidation graph will be developed for each catalyst. The contributions of temperature and later sulfur will be investigated after this is complete. Also, last quarter's tests showed a potential linear relationship between SO3 conversion and mercury oxidation. As a result, SO3 samples will be taken more frequently to investigate each catalyst's ability to selectively oxidize mercury.

  19. Oxidative Tritium Decontamination System

    DOE Patents [OSTI]

    Gentile, Charles A. (Plainsboro, NJ), Guttadora, Gregory L. (Highland Park, NJ), Parker, John J. (Medford, NJ)

    2006-02-07

    The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

  20. Controlled CO preferential oxidation

    DOE Patents [OSTI]

    Meltser, M.A.; Hoch, M.M.

    1997-06-10

    Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

  1. METHANE AND NITROGEN ABUNDANCES ON PLUTO AND ERIS

    SciTech Connect (OSTI)

    Tegler, S. C.; Cornelison, D. M.; Abernathy, M. R.; Bovyn, M. J.; Burt, J. A.; Evans, D. E.; Maleszewski, C. K.; Thompson, Z.; Grundy, W. M.; Romanishin, W.; Vilas, F. E-mail: David.Cornelison@nau.ed E-mail: wjr@nhn.ou.ed

    2010-12-10

    We present spectra of Eris from the MMT 6.5 m Telescope and Red Channel Spectrograph (5700-9800 A, 5 A pixel{sup -1}) on Mt. Hopkins, AZ, and of Pluto from the Steward Observatory 2.3 m Telescope and Boller and Chivens Spectrograph (7100-9400 A, 2 A pixel{sup -1}) on Kitt Peak, AZ. In addition, we present laboratory transmission spectra of methane-nitrogen and methane-argon ice mixtures. By anchoring our analysis in methane and nitrogen solubilities in one another as expressed in the phase diagram of Prokhvatilov and Yantsevich, and comparing methane bands in our Eris and Pluto spectra and methane bands in our laboratory spectra of methane and nitrogen ice mixtures, we find Eris' bulk methane and nitrogen abundances are {approx}10% and {approx}90% and Pluto's bulk methane and nitrogen abundances are {approx}3% and {approx}97%. Such abundances for Pluto are consistent with values reported in the literature. It appears that the bulk volatile composition of Eris is similar to the bulk volatile composition of Pluto. Both objects appear to be dominated by nitrogen ice. Our analysis also suggests, unlike previous work reported in the literature, that the methane and nitrogen stoichiometry is constant with depth into the surface of Eris. Finally, we point out that our Eris spectrum is also consistent with a laboratory ice mixture consisting of 40% methane and 60% argon. Although we cannot rule out an argon-rich surface, it seems more likely that nitrogen is the dominant species on Eris because the nitrogen ice 2.15 {mu}m band is seen in spectra of Pluto and Triton.

  2. Nitrogen-doped Graphene and Its Electrochemical Applications

    SciTech Connect (OSTI)

    Shao, Yuyan; Zhang, Sheng; Engelhard, Mark H.; Li, Guosheng; Shao, Guocheng; Wang, Yong; Liu, Jun; Aksay, Ilhan A.; Lin, Yuehe

    2010-06-04

    Nitrogen-doped graphene (N-graphene) is obtained by exposing graphene to nitrogen plasma. N-graphene exhibits much higher electrocatalytic activity toward oxygen reduction and H2O2 reduction than graphene, and much higher durability and selectivity than the widely-used expensive Pt. The excellent electrochemical performance of N-graphene is attributed to nitrogen functional groups and the specific properties of graphene. This indicates that N-graphene is promising for applications in electrochemical energy devices (fuel cells, metal-air batteries) and biosensors.

  3. Selective decoration of nickel and nickel oxide nanocrystals on multiwalled carbon nanotubes

    SciTech Connect (OSTI)

    Martis, P.; Venugopal, B.R.; Delhalle, J.; Mekhalif, Z.

    2011-05-15

    A simple route to selective decoration of nickel and nickel oxide nanocrystals on multiwalled carbon nanotubes (MWCNTs) using nickel acetylacetonate (NAA) was successfully achieved for the first time. The homogeneously decorated nanocrystals on MWCNTs were investigated for their structure and morphology by various techniques, such as powder X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, field emission scanning electron microscopy and thermogravimetric analysis. It was found that the size distributions of the nanocrystals on MWCNTs ranged from 8 to 15 nm and they were well resolved. The precursor, NAA, was effectively employed to impregnate the MWCNTs, which on calcination at suitable temperatures and in the presence of hydrogen and nitrogen atmosphere gave rise to nickel and nickel oxide nanocrystals, respectively. -- Graphical abstract: Nickel and nickel oxide nanocrystals were selectively and homogeneously decorated on multiwalled carbon nanotubes using nickel acetylacetonate, as a precursor in a simple and efficient route. Display Omitted Highlights: {yields} A simple route for decoration of nickel and nickel oxide nanocrystals on MWCNTs. {yields} Nickel acetylacetonate used as nickel source for the first time to impregnate on MWCNTs. {yields} Selective decoration was achieved by calcination in hydrogen and nitrogen atmospheres. {yields} The as-decorated nickel and nickel oxide nanocrystals are in the range of 8-15 nm.

  4. Innershell Photoionization Studies of Neutral Atomic Nitrogen

    E-Print Network [OSTI]

    Stolte, W C; Lindle, D W; Sant'Anna, M M; Savin, D W

    2014-01-01

    Innershell ionization of a $1s$ electron by either photons or electrons is important for X-ray photoionized objects such as active galactic nuclei and electron-ionized sources such as supernova remnants. Modeling and interpreting observations of such objects requires accurate predictions for the charge state distribution (CSD) which results as the $1s$-hole system stabilizes. Due to the complexity of the complete stabilization process, few modern calculations exist and the community currently relies on 40-year-old atomic data. Here, we present a combined experimental and theoretical study for innershell photoionization of neutral atomic nitrogen for photon energies of $403-475$~eV. Results are reported for the total ion yield cross section, for the branching ratios for formation of N$^+$, N$^{2+}$, and N$^{3+}$, and for the average charge state. We find significant differences when comparing to the data currently available to the astrophysics community. For example, while the branching ratio to N$^{2+}$ is so...

  5. The effect of sources of nitrogen on nitrate formation and nitrogen uptake by cotton plants growing on Miller clay loam 

    E-Print Network [OSTI]

    Marcos, Zilmar Ziller

    1958-01-01

    LIB RARV A & M COLLEGE OF TEXAS THE EFFECT OF SOURCES OF NITROGEN ON NITRATE FORMATION AND NITROGEN UPTAKE HX COTTON PIANTS GROWXNG ON MILLER CIAY LOAN A Thesis ZXINAR ZXLLER NARCOS AAS Submitted, to the Graduate School of the Agricultural... ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ o ~ 66 APPEEDIXt ~ ~ ~ ~ ~ ~ ~ 73 Tables l. Treatments Used in the Study. 2 Nitrate Content (ppm) of Miller Clay (0-6 ') on the 10th of July as Affected. by Rate and Source of' Nitrogen, Avexage oi' Two Repli- Nitrate Content (ppm) of Miller...

  6. Optimization of row spacing and nitrogen fertilization for cotton 

    E-Print Network [OSTI]

    Clawson, Ernest Leslie

    2004-09-30

    Ultra-narrow row (UNR) cotton (Gossypium hirsutum L.) is a production system using high plant populations in reduced row spacings. The responses of this production system to nitrogen fertilizer have not been fully investigated. Evaluations...

  7. Nitrogen expander cycles for large capacity liquefaction of natural gas

    SciTech Connect (OSTI)

    Chang, Ho-Myung; Park, Jae Hoon; Gwak, Kyung Hyun; Choe, Kun Hyung

    2014-01-29

    Thermodynamic study is performed on nitrogen expander cycles for large capacity liquefaction of natural gas. In order to substantially increase the capacity, a Brayton refrigeration cycle with nitrogen expander was recently added to the cold end of the reputable propane pre-cooled mixed-refrigerant (C3-MR) process. Similar modifications with a nitrogen expander cycle are extensively investigated on a variety of cycle configurations. The existing and modified cycles are simulated with commercial process software (Aspen HYSYS) based on selected specifications. The results are compared in terms of thermodynamic efficiency, liquefaction capacity, and estimated size of heat exchangers. The combination of C3-MR with partial regeneration and pre-cooling of nitrogen expander cycle is recommended to have a great potential for high efficiency and large capacity.

  8. Substitutional Nitrogen in Nanodiamond and Bucky-Diamond Particles

    SciTech Connect (OSTI)

    Barnard, Amanda S.; Sternberg, Michael G.

    2005-09-15

    The inclusion of dopants (such as nitrogen) in diamond nanoparticles is expected to be important for use in future nanodevices, such as qubits for quantum computing. Although most commercial diamond nanoparticles contain a small fraction of nitrogen, it is still unclear whether it is located within the core or at the surface of the nanoparticle. Presented here are density functional tight binding simulations examining the configuration, potential energy surface, and electronic charge of substitutional nitrogen in nanodiamond and bucky-diamond particles. The results predict that nitrogen is likely to be positioned at the surface of both hydrogenated nanodiamond and (dehydrogenated) bucky-diamond, and that the coordination of the dopants within the particles is dependent upon the surface structure.

  9. The nitrogen cycle and ecohydrology of seasonally dry grasslands

    E-Print Network [OSTI]

    Parolari, Anthony Joseph

    2013-01-01

    This thesis addresses the coupling of hydrologic and biogeochemical processes and, specifically, the organization of ecosystem traits with the water, carbon, and nitrogen cycles. Observations from a factorial irrigation- ...

  10. Amplification of subnanosecond nitrogen laser pulses in UV dyes

    SciTech Connect (OSTI)

    Au, M.; Rayner, D.M.; Malatesta, V.; Hackett, P.A.

    1982-12-01

    The performance of a short pulse netrogen laser system have been improved by replacing the subatmospheric TE nitrogen laser amplifier with a XV xenon chloride excimer pumped dye amplifier. (AIP)

  11. The relationship between iron and nitrogen fixation in Trichodesmium spp.

    E-Print Network [OSTI]

    Chappell, Phoebe Dreux

    2009-01-01

    Trichodesmium spp. are considered the dominant nitrogen (N) fixing cyanobacteria in tropical and subtropical oceans, regimes frequently characterized by low iron (Fe). Limited information exists about what levels of Fe ...

  12. Nitrogen chemistry in an urban bioretention system in Singapore

    E-Print Network [OSTI]

    Ritter, Halle (Halle Caitlan)

    2013-01-01

    An investigation into the nitrogen chemistry of the anoxic layer of an urban constructed wetland in Singapore was conducted. This pilot-scale wetland treats stormwater runoff from the Balam Estate housing development for ...

  13. Effects of the Hemlock Woolly Adelgid on Nitrogen Losses from

    E-Print Network [OSTI]

    Templer, Pamela

    of nitrogen losses via leachate were more than ten times greater, at the Arnold Arboretum compared to Harvard Forest. Nitrate that was lost via leachate at Harvard Forest came predominantly from atmospheric

  14. Determination of carbon, nitrogen, and oxygen in high purity magnesium 

    E-Print Network [OSTI]

    Roche, Neil Gerard

    1981-01-01

    DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Submitted to the Graduate College of Texas A8cM University in partial i'ulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1981 Major Subject: Chemistry DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Approved as to style and content by: E. A. Schweikert (Chairman of Committee) G. J. Bastiaans (Member) L...

  15. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid (Menlo Park, CA)

    1997-01-01

    A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

  16. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, K.

    1997-07-15

    A membrane separation process is described which is combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C{sub +2} hydrocarbons that might otherwise freeze and plug the cryogenic equipment. 10 figs.

  17. Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

    E-Print Network [OSTI]

    Dennis, J A

    1971-01-01

    Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

  18. Nitrogen isotope effects on glutamate decarboxylase from Escherichia coli

    SciTech Connect (OSTI)

    Abell, L.M.; O'Leary, M.H.

    1988-05-03

    The nitrogen isotope effect on the decarboxylation of glutamic acid by glutamate decarboxylase from Escherichia coli has been measured by comparison of the isotopic composition of the amino nitrogen of the product ..gamma..-aminobutyric acid isolated after 10-20% reaction with that of the starting glutamic acid. At pH 4.7, 37 /sup 0/C, the isotope effect is k/sup 14//k/sup 15/ = 0.9855 +/- 0.0006 when compared to unprotonated glutamic acid. Interpretation of this result requires knowledge of the equilibrium nitrogen isotope effect for Schiff base formation. This equilibrium isotope effect is K/sup 14//K/sup 15/ - 0.9824 for the formation of the unprotonated Schiff base between unprotonated valine and salicylaldehyde. Analysis of the nitrogen isotope effect on decarboxylation of glutamic acid and of the previously measured carbon isotope effect on this same reaction shows that decarboxylation and Schiff base formation are jointly rate limiting. The enzyme-bound Schiff base between glutamate and pyridoxal 5'-phosphate partitions approximately 2:1 between decarboxylation and return to the starting state. The nitrogen isotope effect also reveals that the Schiff base nitrogen is protonated in this intermediate.

  19. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    1999-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  20. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  1. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  2. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  3. Nitrate movement in soils and nitrogen uptake efficiency as affected by nitrogen source, time of application, and a nitrification inhibitor 

    E-Print Network [OSTI]

    Banks, Kenneth Phanon

    1976-01-01

    NITRATE MOVEMENT IN SOILS AND NITROGEN UPTAKE EFFICIENCY AS AFFECTED BY NITROGEN SOURCEs TINE OF APPLICATIONs AIJD A NITRIFICATION INHIBITOR A Thesis by KENNETH PHAIJON BANKS Submitted to the Graduate College of Texas A&N University..., Norwood silt loam (Typic Udifluvent) and Houston Black clay (Udic Pellustert) to determine the amount of N03-N leaching from various N fertilizer sources. Nitrate N movement, as affected by time of application, was determined for (NHq)2 Sop, urea...

  4. Composite solid oxide fuel cell anode based on ceria and strontium titanate

    DOE Patents [OSTI]

    Marina, Olga A. (Richland, WA); Pederson, Larry R. (Richland, WA)

    2008-12-23

    An anode and method of making the same wherein the anode consists of two separate phases, one consisting of a doped strontium titanate phase and one consisting of a doped cerium oxide phase. The strontium titanate phase consists of Sr.sub.1-xM.sub.xTiO.sub.3-.delta., where M is either yttrium (Y), scandium (Sc), or lanthanum (La), where "x" may vary typically from about 0.01 to about 0.5, and where .delta. is indicative of some degree of oxygen non-stoichiometry. A small quantity of cerium may also substitute for titanium in the strontium titanate lattice. The cerium oxide consists of N.sub.yCe.sub.1-yO.sub.2-.delta., where N is either niobium (Nb), vanadium (V), antimony (Sb) or tantalum (Ta) and where "y" may vary typically from about 0.001 to about 0.1 and wherein the ratio of Ti in said first phase to the sum of Ce and N in the second phase is between about 0.2 to about 0.75. Small quantities of strontium, yttrium, and/or lanthanum may additionally substitute into the cerium oxide lattice. The combination of these two phases results in better performance than either phase used separately as an anode for solid oxide fuel cell or other electrochemical device.

  5. Tetraalykylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

    1998-01-01

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  6. Tetraalklylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

    1998-10-06

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  7. Lecture Session (LeS): E.1 In-situ chemical oxidation-1 ENA OF HETEROCYCLIC HYDROCARBONS USING HYDROGEN PEROXIDE AND

    E-Print Network [OSTI]

    Cirpka, Olaf Arie

    , In situ Biological Degradation, Heterocyclic Hydrocarbons, PAH, Field Trial, Groundwater Circulation WellsLecture Session (LeS): E.1 In-situ chemical oxidation-1 ENA OF HETEROCYCLIC HYDROCARBONS USING (GCW), Hydrogen Peroxide Introduction Heterocyclic hydrocarbons (NSO-HET) containing nitrogen (N

  8. Detailed modeling and laser-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame

    E-Print Network [OSTI]

    Bell, John B.

    non-premixed methane/air flame John B. Bell, Marcus S. Day, Joseph F. Grcar Computing Sciences-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame Abstract In this paper we study the formation of NO in laminar, nitrogen diluted methane diffusion flames that are seeded

  9. Nanostructured transition metal oxides useful for water oxidation catalysis

    DOE Patents [OSTI]

    Frei, Heinz M; Jiao, Feng

    2013-12-24

    The present invention provides for a composition comprising a nanostructured transition metal oxide capable of oxidizing two H.sub.2O molecules to obtain four protons. In some embodiments of the invention, the composition further comprises a porous matrix wherein the nanocluster of the transition metal oxide is embedded on and/or in the porous matrix.

  10. Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide

    E-Print Network [OSTI]

    Collins, Gary S.

    molybdenum dioxide displays excellent behavior as catalytic material for the oxidative reforming of bothOxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide Jessica Whalen, Oscar Marin Flores, Su candidate as an effective catalyst for biodiesel. Few papers have been published on the topic of catalytic

  11. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D. (Oak Ridge, TN); Bond, Walter D. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1993-01-01

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel.

  12. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-12-14

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  13. Conformations of Organophosphine Oxides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    De Silva, Nuwan; Zahariev, Federico; Hay, Benjamin P.; Gordon, Mark S.; Windus, Theresa L.

    2015-07-29

    The conformations of a series of organophosphine oxides, OP(CH3)2R, where R = methyl, ethyl, isopropyl, tert-butyl, vinyl, and phenyl, are predicted using the MP2/cc-pVTZ level of theory. Comparison of potential energy surfaces for rotation about P–C bonds with crystal structure data reveals a strong correlation between predicted location and energetics of minima and histograms of dihedral angle distributions observed in the solid state. In addition, the most stable conformers are those that minimize the extent of steric repulsion between adjacent rotor substituents, and the torsional barriers tend to increase with the steric bulk of the rotating alkyl group. MM3 forcemore »field parameters were adjusted to fit the MP2 results, providing a fast and accurate model for predicting organophosphine oxides shapes—an essential part of understanding the chemistry of these compounds. The predictive power of the modified MM3 model was tested against MP2/cc-pVTZ conformations for triethylphosphine oxide, OP(CH2CH3)3, and triphenylphosphine oxide, OP(Ph)3.« less

  14. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2012-09-11

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  15. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2014-05-20

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  16. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2013-04-16

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  17. REVIEW OF PLUTONIUM OXIDATION LITERATURE

    SciTech Connect (OSTI)

    Korinko, P.

    2009-11-12

    A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles (<15 {micro}m), moderately sized particles (15 < x < 250 {micro}m) and large particles (> 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

  18. Doped palladium containing oxidation catalysts

    DOE Patents [OSTI]

    Mohajeri, Nahid

    2014-02-18

    A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

  19. Nitrogen Monitoring of West Hackberry 117 Cavern Wells.

    SciTech Connect (OSTI)

    Bettin, Giorgia; Lord, David

    2015-02-01

    U.S. Strategic Petroleum Reserve (SPR) oil storage cavern West Hackberry 117 was tested under extended nitrogen monitoring following a successful mechanical integrity test in order to validate a newly developed hydrostatic column model to be used to differentiate between normal "tight" well behavior and small-leak behavior under nitrogen. High resolution wireline pressure and temperature data were collected during the test period and used in conjunction with the hydrostatic column model to predict the nitrogen/oil interface and the pressure along the entire fluid column from the bradenhead flange nominally at ground surface to bottom of brine pool. Results here and for other SPR caverns have shown that wells under long term nitrogen monitoring do not necessarily pressurize with a relative rate (P N2 /P brine) of 1. The theoretical relative pressure rate depends on the well configuration, pressure and the location of the nitrogen-oil interface and varies from well to well. For the case of WH117 the predicted rates were 0.73 for well A and 0.92 for well B. The measured relative pressurization rate for well B was consistent with the model prediction, while well A rate was found to be between 0.58-0.68. A number of possible reasons for the discrepancy between the model and measured rates of well A are possible. These include modeling inaccuracy, measurement inaccuracy or the possibility of the presence of a very small leak (below the latest calculated minimum detectable leak rate).

  20. Direct visualization of atomically precise nitrogen-doped graphene nanoribbons

    SciTech Connect (OSTI)

    Zhang, Yi; Zhang, Yanfang; Li, Geng; Lu, Jianchen; Du, Shixuan, E-mail: sxdu@iphy.ac.cn, E-mail: feng@mpip-mainz.mpg.de; Gao, Hong-Jun [Institute of Physics and University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190 (China); Lin, Xiao [University of Chinese Academy of Sciences and Institute of Physics, Chinese Academy of Sciences, Beijing 100049 (China); Berger, Reinhard; Feng, Xinliang, E-mail: sxdu@iphy.ac.cn, E-mail: feng@mpip-mainz.mpg.de; Müllen, Klaus [Max Planck Institute for Polymer Research, Ackermannweg 10, D-55128 Mainz (Germany)

    2014-07-14

    We have fabricated atomically precise nitrogen-doped chevron-type graphene nanoribbons by using the on-surface synthesis technique combined with the nitrogen substitution of the precursors. Scanning tunneling microscopy and spectroscopy indicate that the well-defined nanoribbons tend to align with the neighbors side-by-side with a band gap of 1.02?eV, which is in good agreement with the density functional theory calculation result. The influence of the high precursor coverage on the quality of the nanoribbons is also studied. We find that graphene nanoribbons with sufficient aspect ratios can only be fabricated at sub-monolayer precursor coverage. This work provides a way to construct atomically precise nitrogen-doped graphene nanoribbons.