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Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Spectral irradiance model for tungsten halogen lamps in 340-850 nm wavelength range  

SciTech Connect (OSTI)

We have developed a physical model for the spectral irradiance of 1 kW tungsten halogen incandescent lamps for the wavelength range 340-850 nm. The model consists of the Planck's radiation law, published values for the emissivity of tungsten, and a residual spectral correction function taking into account unknown factors of the lamp. The correction function was determined by measuring the spectra of a 1000 W, quartz-halogen, tungsten coiled filament (FEL) lamp at different temperatures. The new model was tested with lamps of types FEL and 1000 W, 120 V quartz halogen (DXW). Comparisons with measurements of two national standards laboratories indicate that the model can account for the spectral irradiance values of lamps with an agreement better than 1% throughout the spectral region studied. We further demonstrate that the spectral irradiance of a lamp can be predicted with an expanded uncertainty of 2.6% if the color temperature and illuminance values for the lamp are known with expanded uncertainties of 20 K and 2%, respectively. In addition, it is suggested that the spectral irradiance may be derived from resistance measurements of the filament with lamp on and off.

Ojanen, Maija; Kaerhae, Petri; Ikonen, Erkki

2010-02-10T23:59:59.000Z

2

Applications of Cu{sub 2}O octahedral particles on ITO glass in photocatalytic degradation of dye pollutants under a halogen tungsten lamp  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Photocatalytic activity of Cu{sub 2}O octahedral microcrystals on ITO glass was studied. • They showed high abilities in degradation of methylene blue in the presence of H{sub 2}O{sub 2}. • H{sub 2}O{sub 2} amount could affect the degradation efficiency. • Such particles could be easily recycled and still kept high activity. • Many dye pollutants and their mixtures could be efficiently degraded. - Abstract: Cu{sub 2}O octahedral microcrystals were prepared on the ITO glass by galvanostatic electrodeposition in CuSO{sub 4} solution with poly(vinylpryrrolidone) as the surfactant. By controlling the electrodeposition time, the microcrystals could be randomly distributed on the ITO glass and separated from each other, resulting in as many as possible (1 1 1) crystalline planes were exposed. Such microcrystals immobilized on ITO glass were employed in photodegradation of dye pollutants in the presence of H{sub 2}O{sub 2} under a 150 W halogen tungsten lamp. The photodegradation of methylene blue was taken as an example to evaluate the photocatalytic activities of the octahedral Cu{sub 2}O microcrystals. Effects of electrodeposition time and H{sub 2}O{sub 2} amount on the degradation efficiency was discussed, giving the optimum conditions and the corresponding degradation mechanism. The catalyst showed high ability in degradation of methylene blue, methyl orange, rhodamine B, eosin B and their mixtures under identical conditions.

Zhai, Wei [School of Chemistry and Environment, South China Normal University, Guangzhou 510006 (China); Sun, Fengqiang, E-mail: fqsun@scnu.edu.cn [School of Chemistry and Environment, South China Normal University, Guangzhou 510006 (China); Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University (China); Exhibition Base of Production, Study and Research on New Polymer Materials and Postgraduate Students’ Innovation Training of Guangdong Higher Education Institutes (China); Chen, Wei; Zhang, Lihe; Min, Zhilin; Li, Weishan [School of Chemistry and Environment, South China Normal University, Guangzhou 510006 (China)

2013-11-15T23:59:59.000Z

3

Student Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest RegionatSearchScheduled System Burst Buffer Archive Home »Spotlight Mekena

4

Energy efficient alternatives to halogen torchieres  

SciTech Connect (OSTI)

A series of novel energy efficient torchiere systems have been developed using compact fluorescent lamps (CFLs). These systems were studied photometrically and compared with the performance of traditional commercially available tungsten halogen sources. Gonio-photometric data and power assessments indicate that significant lighting energy savings can be obtained by utilizing CFL sources instead of standard tungsten halogen sources. This energy savings is jointly due to the higher source efficacy of the CFLs and the surprisingly poor performance of the imported 300 Watt halogen lamps. Experimental data shows that a 50 to 60 Watt CFL will effectively lumen match a variety of 300 Watt tungsten halogen sources with 5 to 10 times the efficacy. CFL torchieres have additional benefits of higher power quality and cooler lamp operating temperature, making them safer fixtures.

Siminovitch, M.; Marr, L.; Mitchell, J.; Page, E.

1997-03-01T23:59:59.000Z

5

Spotlight: Bryant Roybal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spotlight: Bryant Roybal March 1, 2015 Champion chile New Mexico's first green chile stew champion, Bryant Roybal, is proud to add first prize at the First Annual Great Bowls of...

6

Solar Decathlon Technology Spotlight: Structural Insulated Panels...  

Broader source: Energy.gov (indexed) [DOE]

Decathlon Technology Spotlight: Structural Insulated Panels Solar Decathlon Technology Spotlight: Structural Insulated Panels September 20, 2011 - 7:13am Addthis These structural...

7

Scientists in the Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2)ScienceScientists In the Spotlight Scientists in the

8

Spotlight: Bryant Roybal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSiteNeutron Scattering4 By I. Tudosa, H.SpokaneSponsoredSpotlight:

9

Better Buildings: Workforce, Spotlight on Maine: Contractor Sales...  

Energy Savers [EERE]

Workforce, Spotlight on Maine: Contractor Sales Training Boosts Energy Upgrade Conversions Better Buildings: Workforce, Spotlight on Maine: Contractor Sales Training Boosts Energy...

10

Better Buildings: Financing and Incentives: Spotlight on Maine...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

to a Sustainable Level of Incentives More Documents & Publications Spotlight on Maine: Transition to a Sustainable Level of Incentives Better Buildings: Workforce, Spotlight on...

11

White House Spotlights Solar Innovation as Summit Registration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

White House Spotlights Solar Innovation as Summit Registration Continues White House Spotlights Solar Innovation as Summit Registration Continues April 23, 2014 - 10:38am Addthis...

12

Better Buildings: Workforce: Spotlight on Fayette County, Pennsylvania...  

Energy Savers [EERE]

Better Buildings: Workforce: Spotlight on Fayette County, Pennsylvania: Developing the Skills and Tools for Workforce Success Better Buildings: Workforce: Spotlight on Fayette...

13

Better Buildings: Workforce: Spotlight on Portland, Oregon: Making...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Spotlight on Portland, Oregon: Making the Program Work for Contractors Better Buildings: Workforce: Spotlight on Portland, Oregon: Making the Program Work for Contractors...

14

Impending U.S. lighting standards will boost market for halogen-infrared lamps: New product line expanding  

SciTech Connect (OSTI)

Many of the incandescent floodlights and spotlights manufactured today will not meet lighting efficiency standards taking effect in the US in 1995. As these models cease production, demand will grow for higher efficiency units to fill this huge market, which now totals about 100 million lamps per year. One prime contender is a new class of halogen lamps that use a spectrally selective coating to reflect heat back onto the filament, reducing the amount of electricity needed to generate light. GE Lighting`s Halogen-IR line is the only series of such lamps currently available to replace the conventional floodlights and spotlights that will be banned by the new standards. Other manufacturers may adopt the technology, however, and the Japanese producer Ushio already sells in the US a line of smaller halogen lamps with a similar heat-reflective coating. In terms of efficacy and lifetime, Halogen-IR lamps out perform standard incandescents and standard halogens, but fall far short of fluorescent, metal halide, and high-pressure sodium sources. These other lighting systems are more appropriate and cost-effective than incandescents for many ambient lighting applications. For accent lighting and other tasks that are best suited to incandescent lighting, however, the Halogen-IR lamp is often a superior choice.

Sardinsky, R.; Shepard, M.

1993-12-31T23:59:59.000Z

15

Tungsten and tungsten alloy powder metallurgy: Powder production and applications excluding lamps. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations of selected patents concerning the preparation of metallic and ceramic powders of tungsten and tungsten alloys, including applications of these materials. The hydrogen reduction of tungsten compounds together with alloying element compounds produce forms with characteristics of high density, hardness, wear resistance, high melting points, and abrasiveness. Topics include production of cathodes, heaters, filament wires, electrical contacts, acoustic absorbers, high-density sheets and coatings, hard penetrators, and tungsten carbide and metallized ceramics. Tungsten halogen lamps are examined in a separate bibliography.(Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1997-01-01T23:59:59.000Z

16

Tungsten and tungsten alloy powder metallurgy: Powder production and applications excluding lamps. (Latest citations from the US Patent database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations of selected patents concerning the preparation of metallic and ceramic powders of tungsten and tungsten alloys, including applications of these materials. The hydrogen reduction of tungsten compounds together with alloying element compounds produce forms with characteristics of high density, hardness, wear resistance, high melting points, and abrasiveness. Topics include production of cathodes, heaters, filament wires, electrical contacts, acoustic absorbers, high-density sheets and coatings, hard penetrators, and tungsten carbide and metallized ceramics. Tungsten halogen lamps are examined in a separate bibliography. (Contains a minimum of 97 citations and includes a subject term index and title list.)

Not Available

1993-05-01T23:59:59.000Z

17

Tungsten and tungsten alloy powder metallurgy: Powder production and applications excluding lamps. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations of selected patents concerning the preparation of metallic and ceramic powders of tungsten and tungsten alloys, including applications of these materials. The hydrogen reduction of tungsten compounds together with alloying element compounds produce forms with characteristics of high density, hardness, wear resistance, high melting points, and abrasiveness. Topics include production of cathodes, heaters, filament wires, electrical contacts, acoustic absorbers, high-density sheets and coatings, hard penetrators, and tungsten carbide and metallized ceramics. Tungsten halogen lamps are examined in a separate bibliography.(Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1995-12-01T23:59:59.000Z

18

Tungsten and tungsten alloy powder metallurgy: Powder production and applications excluding lamps. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations of selected patents concerning the preparation of metallic and ceramic powders of tungsten and tungsten alloys, including applications of these materials. The hydrogen reduction of tungsten compounds together with alloying element compounds produce forms with characteristics of high density, hardness, wear resistance, high melting points, and abrasiveness. Topics include production of cathodes, heaters, filament wires, electrical contacts, acoustic absorbers, high-density sheets and coatings, hard penetrators, and tungsten carbide and metallized ceramics. Tungsten halogen lamps are examined in a separate bibliography. (Contains a minimum of 115 citations and includes a subject term index and title list.)

NONE

1995-02-01T23:59:59.000Z

19

Halogenated solvent remediation  

DOE Patents [OSTI]

Methods for enhancing bioremediation of ground water contaminated with nonaqueous halogenated solvents are disclosed. An illustrative method includes adding an electron donor for microbe-mediated anaerobic reductive dehalogenation of the halogenated solvents, which electron donor enhances mass transfer of the halogenated solvents from residual source areas into the aqueous phase of the ground water. Illustrative electron donors include C.sub.2-C.sub.4 carboxylic acids and hydroxy acids, salts thereof, esters of C.sub.2-C.sub.4 carboxylic acids and hydroxy acids, and mixtures thereof, of which lactic acid, salts of lactic acid--such as sodium lactate, lactate esters, and mixtures thereof are particularly illustrative. The microbes are either indigenous to the ground water, or such microbes can be added to the ground water in addition to the electron donor.

Sorenson, Jr., Kent S. (Windsor, CO)

2008-11-11T23:59:59.000Z

20

Halogenation of cobalt dicarbollide  

DOE Patents [OSTI]

A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10{prime} positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron. 1 fig.

Hurlburt, P.K.; Abney, K.D.; Kinkead, S.A.

1997-05-20T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

SPOTLIGHT on: Kelly Phillips Engineering Management  

E-Print Network [OSTI]

SPOTLIGHT on: Kelly Phillips Engineering Management Graduate Student Hometown: La Canada, CA-a-lifetime experiences have been a part of my life as a Trojan the past five years." Why she is a vWOW: "Kelly has made

Wang, Hai

22

SPOTLIGHT on: Ellen Messer Biomedical (Mechanical) Engineering  

E-Print Network [OSTI]

SPOTLIGHT on: Ellen Messer Biomedical (Mechanical) Engineering Undergraduate Hometown: Easthampton of Biomedical Engineering, Undergraduate Research Assistant Program at the Brain and Creativity Institute, MA Involvement at USC: USC Marathon Team, Society of Women Engineers, Associated Students

Wang, Hai

23

SPOTLIGHT on: Lindsay Freeman Chemical Engineering (Nanotechnology)  

E-Print Network [OSTI]

SPOTLIGHT on: Lindsay Freeman Chemical Engineering (Nanotechnology) Undergraduate Hometown.D. in chemical engineering with an emphasis in nanotechnology. Lindsay stands out as a very well-balanced student

Wang, Hai

24

Tungsten and tungsten-alloy powder metallurgy: Powder production and applications-excluding lamps. November 1971-July 1989 (Citations from the US Patent data base). Report for November 1971-July 1989  

SciTech Connect (OSTI)

This bibliography contains citations of selected patents concerning the preparation of metallic and ceramic powders of tungsten and tungsten alloys including various applications of these materials. The hydrogen reduction of tungsten compounds together with alloying-element compounds produce forms with characteristics of high density, hardness, wear resistance, high melting points, and abrasiveness. Topics include production of various cathodes, heaters, filament wires, electrical contacts, acoustic absorbers, high-density sheets and coatings, hard penetrators, and tungsten carbide and metallized ceramics. Tungsten halogen lamps are examined in a separate bibliography. (Contains 60 citations fully indexed and including a title list.)

Not Available

1989-10-01T23:59:59.000Z

25

DONOR SPOTLIGHT BUSINESS LINKAGE STROKE TREATMENT  

E-Print Network [OSTI]

DONOR SPOTLIGHT BUSINESS LINKAGE STROKE TREATMENT BRAIN CANCER FUNDRAISER German Australian for more information and to book your table, please contact events@qbi.uq.edu.au now. What is stroke? Stroke occurs when the supply of blood to the brain is disrupted. A stroke caused by a blocked artery

Goodhill, Geoffrey J.

26

griculture is in the spotlight as a  

E-Print Network [OSTI]

, cyclone exhaust, facility or mine. Fugitive emissions -- Air pollutants that escape unplanned, as fromA griculture is in the spotlight as a potential contribu- tor to air pollution. Animal feeding emit air pollutants. Clean Air Act -- The law passed in 1970 (and subsequent amendments) that created

Mukhtar, Saqib

27

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Halogens, dioxins/Halogens, dioxins/furansfurans  

E-Print Network [OSTI]

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Halogens, dioxins/Halogens, dioxins and fuel gases ·· Dioxins/Dioxins/furansfurans formation and controlformation and control ·· Other-halogen compoundsOrgano-halogen compounds 2,3,7,8 tetrachloro dibenzo - p- dioxin PCB furan 2

Zevenhoven, Ron

28

Nuclear Fuels & Materials Spotlight Volume 4  

SciTech Connect (OSTI)

As the nation's nuclear energy laboratory, Idaho National Laboratory brings together talented people and specialized nuclear research capability to accomplish our mission. This edition of the Nuclear Fuels and Materials Division Spotlight provides an overview of some of our recent accomplishments in research and capability development. These accomplishments include: • The first identification of silver and palladium migrating through the SiC layer in TRISO fuel • A description of irradiation assisted stress corrosion testing capabilities that support commercial light water reactor life extension • Results of high-temperature safety testing on coated particle fuels irradiated in the ATR • New methods for testing the integrity of irradiated plate-type reactor fuel • Description of a 'Smart Fuel' concept that wirelessly provides real time information about changes in nuclear fuel properties and operating conditions • Development and testing of ultrasonic transducers and real-time flux sensors for use inside reactor cores, and • An example of a capsule irradiation test. Throughout Spotlight, you'll find examples of productive partnerships with academia, industry, and government agencies that deliver high-impact outcomes. The work conducted at Idaho National Laboratory helps to spur innovation in nuclear energy applications that drive economic growth and energy security. We appreciate your interest in our work here at INL, and hope that you find this issue informative.

I. J. van Rooyen,; T. M. Lillo; Y. Q. WU; P.A. Demkowicz; L. Scott; D.M. Scates; E. L. Reber; J. H. Jackson; J. A. Smith; D.L. Cottle; B.H. Rabin; M.R. Tonks; S.B. Biner; Y. Zhang; R.L. Williamson; S.R. Novascone; B.W. Spencer; J.D. Hales; D.R. Gaston; C.J. Permann; D. Anders; S.L. Hayes; P.C. Millett; D. Andersson; C. Stanek; R. Ali; S.L. Garrett; J.E. Daw; J.L. Rempe; J. Palmer; B. Tittmann; B. Reinhardt; G. Kohse; P. Ramuhali; H.T. Chien; T. Unruh; B.M. Chase; D.W. Nigg; G. Imel; J. T. Harris

2014-04-01T23:59:59.000Z

29

SPOTLIGHT on: Jennifer Dowling Industrial and Systems Engineering  

E-Print Network [OSTI]

SPOTLIGHT on: Jennifer Dowling Industrial and Systems Engineering Hometown: La Mirada, CA Involvement at USC: Society of Women Engineers- Corporate Affairs Committee member, Institute of Industrial Engineers- President, Viterbi Graduate Admissions Office- student staff member, Song Girl 2007 Favorite

Wang, Hai

30

Building America Research Teams: Spotlight on Home Innovation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Home Innovation and PARR Building America Research Teams: Spotlight on Home Innovation and PARR April 9, 2015 - 10:55am Addthis This article continues our series of profiles about...

31

2, 14571486, 2005 Halogens in peat  

E-Print Network [OSTI]

BGD 2, 1457­1486, 2005 Halogens in peat porewater H. Biester et al. Title Page Abstract Discussions is the access reviewed discussion forum of Biogeosciences Halogens in porewater of peat bogs ­ the role of peat decomposition and dissolved organic matter H. Biester 1 , D. Selimovi´c 1 , S. Hemmerich 1

Paris-Sud XI, Université de

32

KISMET tungsten dispersal experiment  

SciTech Connect (OSTI)

Results of the KISMET tungsten dispersal experiment indicate a relatively small degree of wall-rock contamination caused by this underground explosive experiment. Designed as an add-on to the KISMET test, which was performed in the U-1a.02 drift of the LYNER facility at Nevada Test Site on 1 March 1995, this experiment involved recovery and analysis of wall-rock samples affected by the high- explosive test. The chemical, high-explosive blast drove tungsten powder, placed around the test package as a plutonium analog, into the surrounding wall- rock alluvium. Sample analyses by an analytical digital electron microscope (ADEM) show tungsten dispersed in the rock as tiny (<10 {mu}m) particles, agglomerates, and coatings on alluvial clasts. Tungsten concentrations, measured by energy dispersive spectral analysis on the ADEM, indicate penetration depths less than 0.1 m and maximum concentrations of 1.5 wt % in the alluvium.

Wohletz, K.; Kunkle, T.; Hawkins, W.

1996-12-01T23:59:59.000Z

33

Tungsten Cathode Catalyst for PEMFC  

SciTech Connect (OSTI)

Final report for project to evaluate tungsten-based catalyst as a cathode catalyst for PEM cell applications.

Joel B. Christian; Sean P. E. Smith

2006-09-22T23:59:59.000Z

34

Aluminum-tungsten fiber composites with cylindrical geometry and controlled architecture of tungsten reinforcement  

E-Print Network [OSTI]

Measurements in Alumina and Tungsten Fibre-Reinforcedto-Ductile Transition in Tungsten Single Crystals. ” ScienceToughness of Polycrystalline Tungsten Under Mode I and Mixed

Lucchese, Carl Joesph

2010-01-01T23:59:59.000Z

35

E-Print Network 3.0 - active halogen species Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

organo-halogen gases or solvents. The most abundant... Zevenhoven & Kilpinen Halogens, dioxinsfurans 17.6.2001 7-1 Chapter 7 Halogens, dioxinsfurans 7... .1 Introduction The...

36

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS  

SciTech Connect (OSTI)

Western Research Institute (WRI) initiated exploratory work towards the development of new field screening methodology and a test kit to measure halogenated volatile organic compounds (VOCs) in the field. Heated diode and corona discharge sensors are commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. They are both selective to the presence of carbon-halogen bonds. Commercially available heated diode and corona discharge leak detectors were procured and evaluated for halogenated VOC response. The units were modified to provide a digital readout of signal related to VOC concentration. Sensor response was evaluated with carbon tetrachloride and tetrachloroethylene (perchloroethylene, PCE), which represent halogenated VOCs with and without double bonds. The response characteristics were determined for the VOCs directly in headspace in Tedlar bag containers. Quantitation limits in air were estimated. Potential interferences from volatile hydrocarbons, such as toluene and heptane, were evaluated. The effect of humidity was studied also. The performance of the new devices was evaluated in the laboratory by spiking soil samples and monitoring headspace for halogenated VOCs. A draft concept of the steps for a new analytical method was outlined. The results of the first year effort show that both devices show potential utility for future analytical method development work towards the goal of developing a portable test kit for screening halogenated VOCs in the field.

John F. Schabron; Joseph F. Rovani Jr.; Theresa M. Bomstad

2002-06-01T23:59:59.000Z

37

Crystallographic studies on enzymatic halogenation of natural products  

E-Print Network [OSTI]

Halogenated natural products are common and serve roles as hormones, pesticides, antibiotics, and anti-tumor agents. The incorporation of a halogen atom into an organic scaffold can tune the molecule's potency and selectivity, ...

Blasiak, Leah Cameron

2008-01-01T23:59:59.000Z

38

Method and apparatus for low temperature destruction of halogenated hydrocarbons  

DOE Patents [OSTI]

A method and apparatus for decomposing halogenated hydrocarbons are provided. The halogenated hydrocarbon is mixed with solvating agents and maintained in a predetermined atmosphere and at a predetermined temperature. The mixture is contacted with recyclable reactive material for chemically reacting with the recyclable material to create dehalogenated hydrocarbons and halogenated inorganic compounds. A feature of the invention is that the process enables low temperature destruction of halogenated hydrocarbons.

Reagen, William Kevin (Stillwater, MN); Janikowski, Stuart Kevin (Idaho Falls, ID)

1999-01-01T23:59:59.000Z

39

Helium bubble bursting in tungsten  

SciTech Connect (OSTI)

Molecular dynamics simulations have been used to systematically study the pressure evolution and bursting behavior of sub-surface helium bubbles and the resulting tungsten surface morphology. This study specifically investigates how bubble shape and size, temperature, tungsten surface orientation, and ligament thickness above the bubble influence bubble stability and surface evolution. The tungsten surface is roughened by a combination of adatom “islands,” craters, and pinholes. The present study provides insight into the mechanisms and conditions leading to various tungsten topology changes, which we believe are the initial stages of surface evolution leading to the formation of nanoscale fuzz.

Sefta, Faiza [University of California, Berkeley, California 94720 (United States); Juslin, Niklas [University of Tennessee, Knoxville, Tennessee 37996 (United States); Wirth, Brian D., E-mail: bdwirth@utk.edu [University of Tennessee, Oak Ridge National Laboratory, Knoxville, Tennessee 37996 (United States)

2013-12-28T23:59:59.000Z

40

Webinar: Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis—Spotlight on Giner and Proton  

Broader source: Energy.gov [DOE]

Video recording of the webinar, Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis—Spotlight on Giner and Proton, originally presented on May 23, 2011.

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Preparation, Characterization, and Catalytic Properties of Tungsten...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Preparation, Characterization, and Catalytic Properties of Tungsten Trioxide Cyclic Trimers on FeO(111)Pt(111). Preparation, Characterization, and Catalytic Properties of Tungsten...

42

Comproportionation of Cationic and Anionic Tungsten Complexes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comproportionation of Cationic and Anionic Tungsten Complexes Having an N-Heterocyclic Carbene Ligand to Give the Isolable 17 Comproportionation of Cationic and Anionic Tungsten...

43

Zevenhoven & Kilpinen Halogens, dioxins/furans 17.6.2001 7-1 Chapter 7 Halogens,  

E-Print Network [OSTI]

Zevenhoven & Kilpinen Halogens, dioxins/furans 17.6.2001 7-1 Chapter 7 Halogens, dioxins/furans 7 in Figure 7.1. The polychlorinated dibenzo -(p) dioxins and -furans (PCDD/Fs) that are found in PCBs and may, dioxins/furans 17.6.2001 7-2 2,3,7,8 tetrachloro dibenzo - p- dioxin PCB furan 2,3,7,8 tetrachlorodibenzo

Zevenhoven, Ron

44

Retention of Halogens in Waste Glass  

SciTech Connect (OSTI)

In spite of their potential roles as melting rate accelerators and foam breakers, halogens are generally viewed as troublesome components for glass processing. Of five halogens, F, Cl, Br, I, and At, all but At may occur in nuclear waste. A nuclear waste feed may contain up to 10 g of F, 4 g of Cl, and ?100 mg of Br and I per kg of glass. The main concern is halogen volatility, producing hazardous fumes and particulates, and the radioactive iodine 129 isotope of 1.7x10^7-year half life. Because F and Cl are soluble in oxide glasses and tend to precipitate on cooling, they can be retained in the waste glass in the form of dissolved constituents or as dispersed crystalline inclusions. This report compiles known halogen-retention data in both high-level waste (HLW) and low-activity waste (LAW) glasses. Because of its radioactivity, the main focus is on I. Available data on F and Cl were compiled for comparison. Though Br is present in nuclear wastes, it is usually ignored; no data on Br retention were found.

Hrma, Pavel R.

2010-05-01T23:59:59.000Z

45

High strength uranium-tungsten alloys  

DOE Patents [OSTI]

Alloys of uranium and tungsten and a method for making the alloys. The amount of tungsten present in the alloys is from about 4 wt % to about 35 wt %. Tungsten particles are dispersed throughout the uranium and a small amount of tungsten is dissolved in the uranium.

Dunn, Paul S. (Santa Fe, NM); Sheinberg, Haskell (Los Alamos, NM); Hogan, Billy M. (Los Alamos, NM); Lewis, Homer D. (Bayfield, CO); Dickinson, James M. (Los Alamos, NM)

1991-01-01T23:59:59.000Z

46

High strength uranium-tungsten alloy process  

DOE Patents [OSTI]

Alloys of uranium and tungsten and a method for making the alloys. The amount of tungsten present in the alloys is from about 4 wt % to about 35 wt %. Tungsten particles are dispersed throughout the uranium and a small amount of tungsten is dissolved in the uranium.

Dunn, Paul S. (Santa Fe, NM); Sheinberg, Haskell (Los Alamos, NM); Hogan, Billy M. (Los Alamos, NM); Lewis, Homer D. (Bayfield, CO); Dickinson, James M. (Los Alamos, NM)

1990-01-01T23:59:59.000Z

47

Process for removal of hydrogen halides or halogens from incinerator gas  

DOE Patents [OSTI]

A process for reducing the amount of halogens and halogen acids in high temperature combustion gas and through their removal, the formation of halogenated organics at lower temperatures, with the reduction being carried out electrochemically by contacting the combustion gas with the negative electrode of an electrochemical cell and with the halogen and/or halogen acid being recovered at the positive electrode.

Huang, H.S.; Sather, N.F.

1987-08-21T23:59:59.000Z

48

Discovery of the Tungsten Isotopes  

E-Print Network [OSTI]

Thirty-five tungsten isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

A. Fritsch; J. Q. Ginepro; M. Heim; A. Schuh; A. Shore; M. Thoennessen

2009-03-25T23:59:59.000Z

49

Discovery of the tungsten isotopes  

SciTech Connect (OSTI)

Thirty-five tungsten isotopes have been observed so far and the discovery of these isotopes is discussed here. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

Fritsch, A.; Ginepro, J.Q.; Heim, M.; Schuh, A.; Shore, A. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Thoennessen, M. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States)], E-mail: thoennessen@nscl.msu.edu

2010-05-15T23:59:59.000Z

50

Discovery of the Tungsten Isotopes  

E-Print Network [OSTI]

Thirty-five tungsten isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

Fritsch, A; Heim, M; Schuh, A; Shore, A; Thoennessen, M

2009-01-01T23:59:59.000Z

51

Workers' Spotlight Newsletter - Issue 1 | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomen Owned SmallOf TheViolations | DepartmentDeborahTanzimaJuly 30, Workers' Spotlight

52

Process Of Bonding Copper And Tungsten  

DOE Patents [OSTI]

Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by sintering a stack of individual copper and tungsten powder blend layers having progressively higher copper content/tungsten content, by volume, ratio values in successive powder blend layers in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO); Davis, John W. (Ballwin, MO)

2000-07-18T23:59:59.000Z

53

Tungsten diffusion in silicon  

SciTech Connect (OSTI)

Two doses (10{sup 13} and 10{sup 15}?cm{sup ?2}) of tungsten (W) atoms were implanted in different Si(001) wafers in order to study W diffusion in Si. The samples were annealed or oxidized at temperatures between 776 and 960?°C. The diffusion profiles were measured by secondary ion mass spectrometry, and defect formation was studied by transmission electron microscopy and atom probe tomography. W is shown to reduce Si recrystallization after implantation and to exhibit, in the temperature range investigated, a solubility limit close to 0.15%–0.2%, which is higher than the solubility limit of usual metallic impurities in Si. W diffusion exhibits unusual linear diffusion profiles with a maximum concentration always located at the Si surface, slower kinetics than other metals in Si, and promotes vacancy accumulation close to the Si surface, with the formation of hollow cavities in the case of the higher W dose. In addition, Si self-interstitial injection during oxidation is shown to promote W-Si clustering. Taking into account these observations, a diffusion model based on the simultaneous diffusion of interstitial W atoms and W-Si atomic pairs is proposed since usual models used to model diffusion of metallic impurities and dopants in Si cannot reproduce experimental observations.

De Luca, A.; Texier, M.; Burle, N.; Oison, V.; Pichaud, B. [Aix-Marseille Université, IM2NP UMR 7334, Faculté des Sciences et Techniques, Campus de Saint-Jérôme, Avenue Escadrille Normandie Niemen - Case 142, F-13397 Marseille Cedex (France); Portavoce, A., E-mail: alain.portavoce@im2np.fr [CNRS, IM2NP UMR 7334, Faculté des Sciences et Techniques, Campus de Saint-Jérôme, Avenue Escadrille Normandie Niemen - Case 142, F-13397 Marseille Cedex (France); Grosjean, C. [STMicroelectronics, Rousset (France)

2014-01-07T23:59:59.000Z

54

E-Print Network 3.0 - anesthesiques halogenes pendant Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Chemistry 38 HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Halogens, dioxinsHalogens, dioxinsfuransfurans Summary: HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153...

55

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS  

SciTech Connect (OSTI)

Western Research Institute (WRI) is continuing work toward the development of new screening methodology and a test kit to measure halogenated volatile organic compounds (VOCs) in the field. Heated diode and corona discharge sensors are commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. They are both selective to the presence of halogens. In prior work, the devices were tested for response to carbon tetrachloride, heptane, toluene, and water vapors. In the current work, sensor response was evaluated with sixteen halogenated VOCs relative to carbon tetrachloride. The results show that the response of the various chlorinated VOCs is within an order of magnitude of the response to carbon tetrachloride for each of the sensors. Thus, for field screening a single response factor can be used. Both types of leak detectors are being further modified to provide an on-board LCD signal readout, which is related to VOC concentration. The units will be fully portable and will operate with 115-V line or battery power. Signal background, noise level, and response data on the Bacharach heated diode detector and the TIF corona discharge detector show that when the response curves are plotted against the log of concentration, the plot is linear to the upper limit for the particular unit, with some curvature at lower levels. When response is plotted directly against concentration, the response is linear at the low end and is curved at the high end. The dynamic ranges for carbon tetrachloride of the two devices from the lower detection limit (S/N=2) to signal saturation are 4-850 vapor parts per million (vppm) for the corona discharge unit and 0.01-70 vppm for the heated diode unit. Additional circuit modifications are being made to lower the detection limit and increase the dynamic response range of the corona discharge unit. The results indicate that both devices show potential utility for future analytical method development work toward the goal of developing a portable test kit for screening halogenated VOCs in the field.

John F. Schabron; Joseph F. Rovani, Jr.; Theresa M. Bomstad

2003-07-01T23:59:59.000Z

56

Method of synthesizing tungsten nanoparticles  

SciTech Connect (OSTI)

A method to synthesize tungsten nanoparticles has been developed that enables synthesis of nanometer-scale, monodisperse particles that can be stabilized only by tetrahydrofuran. The method can be used at room temperature, is scalable, and the product concentrated by standard means. Since no additives or stabilizing surfactants are required, this method is particularly well suited for producing tungsten nanoparticles for dispersion in polymers. If complete dispersion is achieved due to the size of the nanoparticles, then the optical properties of the polymer can be largely maintained.

Thoma, Steven G; Anderson, Travis M

2013-02-12T23:59:59.000Z

57

Accepted Manuscript Making Tungsten Work  

E-Print Network [OSTI]

Thermonuclear Experimental Reactor Organization, Cadarache, FRANCE 3 Plasma Science and Fusion Center at MIT International Thermonuclear Experimental Reactor Organization, Cadarache, FRANCE 3 Plasma Science and Fusion Thermonuclear Experimental Reactor). Tungsten (W) is the plasma-facing material of choice in several design

Raffray, A. René

58

Process Of Bonding Copper And Tungsten  

DOE Patents [OSTI]

Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by thermal plasma spraying mixtures of copper powder and tungsten powder in a varied blending ratio such that the blending ratio of the copper powder and the tungsten powder that is fed to a plasma torch is intermittently adjusted to provide progressively higher copper content/tungsten content, by volume, ratio values in the interlayer in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO)

1999-11-23T23:59:59.000Z

59

Metal halogen battery construction with improved technique for producing halogen hydrate  

DOE Patents [OSTI]

An improved electrical energy storage system comprising, at least one cell having a positive electrode and a negative electrode separated by aqueous electrolyte, a store means wherein halogen hydrate is formed and stored as part of an aqueous material having a liquid level near the upper part of the store, means for circulating electrolyte through the cell, conduit means for transmitting halogen gas formed in the cell to a hydrate forming apparatus associated with the store, said hydrate forming apparatus including, a pump to which there is introduced quantities of the halogen gas and chilled water, said pump being located in the store and an outlet conduit leading from the pump and being substantially straight and generally vertically disposed and having an exit discharge into the gas space above the liquid level in the store, and wherein said hydrate forming apparatus is highly efficient and very resistant to plugging or jamming. The disclosure also relates to an improved method for producing chlorine hydrate in zinc chlorine batteries.

Fong, Walter L. (Royal Oak, MI); Catherino, Henry A. (Rochester, MI); Kotch, Richard J. (Mt. Clemens, MI)

1983-01-01T23:59:59.000Z

60

TUNGSTEN--1998 80.1 By Kim B. Shedd  

E-Print Network [OSTI]

. Domestic production of ammonium paratungstate decreased, while U.S. net production of primary tungsten products (tungsten carbide powder, tungsten chemicals, and tungsten metal powder) increased. In 1998, U.S. industries consumed more tungsten to make end-use products than in 1997. China continued to be the largest

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

TUNGSTEN--2002 80.1 By Kim B. Shedd  

E-Print Network [OSTI]

production was reported in 2002. U.S. supply of tungsten raw materials comprised imports, tungsten- bearing production, providing a new source of concentrates to two major tungsten consumers. Over the courseTUNGSTEN--2002 80.1 TUNGSTEN By Kim B. Shedd Domestic survey data and tables were prepared

62

Photochemical reductive elimination of halogen from transition metal complexes  

E-Print Network [OSTI]

This thesis is focused on the synthesis and study of transition metal complexes that undergo halogen elimination when irradiated with UV and visible light. This chemistry is relevant for solar energy storage schemes in ...

Cook, Timothy R. (Timothy Raymond), 1982-

2010-01-01T23:59:59.000Z

63

Halogenated naphthyl methoxy piperidines for mapping serotonin transporter sites  

DOE Patents [OSTI]

Halogenated naphthyl methoxy piperidines having a strong affinity for the serotonin transporter are disclosed. Those compounds can be labeled with positron-emitting and/or gamma emitting halogen isotopes by a late step synthesis that maximizes the useable lifeterm of the label. The labeled compounds are useful for localizing serotonin transporter sites by positron emission tomography and/or single photon emission computed tomography.

Goodman, Mark M. (Atlanta, GA); Faraj, Bahjat (Lithonia, GA)

1999-01-01T23:59:59.000Z

64

Halogenated naphthyl methoxy piperidines for mapping serotonin transporter sites  

DOE Patents [OSTI]

Halogenated naphthyl methoxy piperidines having a strong affinity for the serotonin transporter are disclosed. Those compounds can be labeled with positron-emitting and/or gamma emitting halogen isotopes by a late step synthesis that maximizes the useable lifeterm of the label. The labeled compounds are useful for localizing serotonin transporter sites by positron emission tomography and/or single photon emission computed tomography.

Goodman, M.M.; Faraj, B.

1999-07-06T23:59:59.000Z

65

Synthesis of tungsten nano composites  

SciTech Connect (OSTI)

Tungsten-copper composites are currently used as thermal management substrates on a commercial basis. Properties such as high corrosion/erosion resistance, good thermal and electrical conductivity and sufficient mechanical strength and thermal shock resistance make tungsten-copper based composites attractive as electrode materials in automobile sparkplugs. These composites are mostly manufactured through infiltration and mechanical alloying. The products, however, generally lack compositional homogeneity. In this study, chemical approaches were used to synthesize W-Cu and W-Cu-TiB{sub 2} composites. The powders obtained had an average agglomerate size of 1.2 {mu}m and consisted of 50--200 mn sized primary particles. The W and Cu distribution was uniform on at least the submicron level. Consolidation studies on a W-Cu-TiB{sub 2} sample showed no substantial grain growth at 1,350 C under 500 MPa pressure for 2 minutes. The morphology of the grains, however, underwent noticeable changes.

Yu, C.C.; Kumar, R.; Sudarshan, T.S. [Materials Modification, Inc., Fairfax, VA (United States)

1996-06-01T23:59:59.000Z

66

Treatment of halogen-containing waste and other waste materials  

DOE Patents [OSTI]

A process for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes.

Forsberg, Charles W. (Oak Ridge, TN); Beahm, Edward C. (Oak Ridge, TN); Parker, George W. (Concord, TN)

1997-01-01T23:59:59.000Z

67

Treatment of halogen-containing waste and other waste materials  

DOE Patents [OSTI]

A process is described for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes. 3 figs.

Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

1997-03-18T23:59:59.000Z

68

A Well-Defined, Silica-Supported Tungsten Imido Alkylidene Olefin Metathesis Catalyst  

E-Print Network [OSTI]

deactivation. Keywords. Tungsten Imido Alkylidene complex.monosiloxy alkylidene tungsten surface complex syn-2, [(_

2006-01-01T23:59:59.000Z

69

Gamma Spectrum from Neutron Capture on Tungsten Isotopes  

E-Print Network [OSTI]

FROM NEUTRON CAPTURE ON TUNGSTEN ISOTOPES A. M. HURST ?1,2 ,capture on the stable tungsten isotopes is presented, withknown decay schemes of the tungsten isotopes from neutron

Hurst, Aaron

2011-01-01T23:59:59.000Z

70

Factors controlling tungsten concentrations in ground water, Carson Desert, Nevada  

E-Print Network [OSTI]

Factors controlling tungsten concentrations in ground water, Carson Desert, Nevada Ralph L. Seiler sources. Tungsten concentrations in 100 ground water samples from all aquifers used as drinking water indicates that W exhibits Tungsten con- centrations are strongly and positively correlated

71

A comparison of spotlight synthetic aperture radar image formation techniques  

SciTech Connect (OSTI)

Spotlight synthetic aperture radar images can be formed from the complex phase history data using two main techniques: (1) polar-to-cartesian interpolation followed by two-dimensional inverse Fourier transform (2DFFT), and (2) convolution backprojection (CBP). CBP has been widely used to reconstruct medical images in computer aided tomography, and only recently has been applied to form synthetic aperture radar imagery. It is alleged that CBP yields higher quality images because (1) all the Fourier data are used and (2) the polar formatted data is used directly to form a 2D Cartesian image and therefore 2D interpolation is not required. This report compares the quality of images formed by CBP and several modified versions of the 2DFFT method. We show from an image quality point of view that CBP is equivalent to first windowing the phase history data and then interpolating to an exscribed rectangle. From a mathematical perspective, we should expect this conclusion since the same Fourier data are used to form the SAR image. We next address the issue of parallel implementation of each algorithm. We dispute previous claims that CBP is more readily parallelizable than the 2DFFT method. Our conclusions are supported by comparing execution times between massively parallel implementations of both algorithms, showing that both experience similar decreases in computation time, but that CBP takes significantly longer to form an image.

Knittle, C.D.; Doren, N.E.; Jakowatz, C.V.

1996-10-01T23:59:59.000Z

72

Effects of Tungsten Oxide Addition on the Electrochemical Performance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tungsten Oxide Addition on the Electrochemical Performance of Nanoscale Tantalum Oxide-Based Electrocatalysts for Effects of Tungsten Oxide Addition on the Electrochemical...

73

Halogenated 1'-methyl-1,2'-bipyrroles (MBPs) in the Norwestern Atlantic  

E-Print Network [OSTI]

Halogenated 1'-methyl-1,2'-bipyrroles (MBPs) are a distinctive class of marine organic compounds. They are naturally produced, they have a unique carbon structure, they are highly halogenated, and they bioaccumulate in ...

Pangallo, Kristin C

2009-01-01T23:59:59.000Z

74

E-Print Network 3.0 - agents anesthesiques halogenes Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry 17 Incompatible Chemicals -Partial list Chemical Incompatibilities Summary: , carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens Ammonia...

75

Symmetric and asymmetric halogen-containing metallocarboranylporphyrins and uses thereof  

DOE Patents [OSTI]

The present invention is directed to low toxicity boronated compounds and methods for their use in the treatment, visualization, and diagnosis of tumors. More specifically, the present invention is directed to low toxicity halogenated, carborane-containing 5,10,15,20-tetraphenylporphyrin compounds and methods for their use particularly in boron neutron capture therapy (BNCT) and photodynamic therapy (PDT) for the treatment of tumors of the brain, head and neck, and surrounding tissue. The invention is also directed to using these halogenated, carborane-containing tetraphenylporphyrin compounds in methods of tumor imaging and/or diagnosis such as MRI, SPECT, or PET.

Miura, Michiko; Wu, Haitao

2013-05-21T23:59:59.000Z

76

High strength and density tungsten-uranium alloys  

DOE Patents [OSTI]

Alloys of tungsten and uranium and a method for making the alloys. The amount of tungsten present in the alloys is from about 55 vol % to about 85 vol %. A porous preform is made by sintering consolidated tungsten powder. The preform is impregnated with molten uranium such that (1) uranium fills the pores of the preform to form uranium in a tungsten matrix or (2) uranium dissolves portions of the preform to form a continuous uranium phase containing tungsten particles.

Sheinberg, Haskell (Los Alamos, NM)

1993-01-01T23:59:59.000Z

77

Physical properties of erbium implanted tungsten oxide films deposited by reactive dual magnetron sputtering  

E-Print Network [OSTI]

of erbium implanted tungsten oxide films deposited byDual magnetron sputtering; tungsten oxide films; Er ionoptical waveguides [3,5]. Tungsten oxide (WO 3 ) thin films

Mohamed, Sodky H.; Anders, Andre

2006-01-01T23:59:59.000Z

78

FINAL FOCUS ION BEAM INTENSITY FROM TUNGSTEN FOIL CALORIMETER AND SCINTILLATOR IN NDCX-I  

E-Print Network [OSTI]

FOCUS ION BEAM INTENSITY FROM TUNGSTEN FOIL CALORIMETER ANDtemperature rise in the tungsten foil. A cross-calibrationis obtained with a 3µm thick tungsten foil calorimeter and

Lidia, S.M.

2010-01-01T23:59:59.000Z

79

Tungsten wire for incandescent lamps  

SciTech Connect (OSTI)

Tungsten wire for incandescent lamp filaments must operate at high temperatures and for long times. To meet these requirements, the grain morphology of the wire must be controlled to reduce the propensity for grain boundary sliding. The morphology is a function of the distribution of very small pockets of potassium in the wire and the mechanical processing from ingot to wire. The behavior of the filament is directly related to the grain morphology. This paper describes the mechanism by which the potassium is incorporated into and distributed in the ingot. The elongation and spheroidization of the bubbles during hot rolling and swaging is also examined and related to the grain morphology of wire. Some indications of the relationship between grain morphology and filament behavior are also given.

Walter, J.L.; Briant, C.L. (General Electric Corporate Research and Development, Schenectady, NY (USA))

1990-09-01T23:59:59.000Z

80

Method for selective dehalogenation of halogenated polyaromatic compounds  

DOE Patents [OSTI]

A method for dehalogenating halogenated polyaromatic compounds is provided wherein the polyaromatic compounds are mixed with a hydrogen donor solvent and a carbon catalyst in predetermined proportions, the mixture is maintained at a predetermined pressure, and the mixture is heated to a predetermined temperature and for a predetermined time.

Farcasiu, Malvina (Pittsburgh, PA); Petrosius, Steven C. (Library, PA)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Growth of tungsten oxide on carbon nanowalls templates  

SciTech Connect (OSTI)

Highlights: ? Tungsten oxide deposited on carbon nanowalls by hot filament chemical vapor deposition technique. ? This composite has two-dimensional uniform morphology with a crystalline structure of monoclinic tungsten trioxide. ? Surface photoelectric voltage measurements show that this product has photoresponse properties. - Abstract: In the present work we present a simple approach for coupling tungsten oxide with carbon nanowalls. The two-dimensional carbon nanowalls with open boundaries were grown using plasma enhanced hot filament chemical vapor deposition, and the subsequent tungsten oxide growth was performed in the same equipment by direct heating of a tungsten filament. The tungsten oxide coating is found to have uniform morphology with a crystalline structure of monoclinic tungsten trioxide. Surface photoelectric voltage measurements show that this product has photoresponse properties. The method of synthesis described here provides an operable route to the production of two-dimensional tungsten oxide nanocomposites.

Wang, Hua, E-mail: wanghua@dlou.edu.cn [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024 (China); College of Fisheries and Life Science, Dalian Ocean University, Dalian 116023 (China); Su, Yan [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024 (China); Chen, Shuo, E-mail: shuochen@dlut.edu.cn [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024 (China); Quan, Xie [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024 (China)

2013-03-15T23:59:59.000Z

82

High-temperature stress measurement on chemical-vapor-deposited tungsten silicide and tungsten films  

SciTech Connect (OSTI)

Stresses in chemical-vapor-deposited tungsten silicide and tungsten films at high temperatures were measured. Tungsten silicide films were formed from WF/sub 6/ and SiH/sub 4/ or Si/sub 2/H/sub 6/. Tungsten films were formed from WF/sub 6/ and H/sub 2/. The stress in tungsten silicide films is tensile and in the order of 10/sup 9/--10/sup 10/ dynes/cm/sup 2/. For a composition ratio of Si/Wless than or equal to2.6, the stress of a film of more than 1000 A has a maximum at about 500 /sup 0/C. On the other hand, for a composition Si/W>2.9, the stress has no maximum. The maximum of the stress is caused by crystallization of the film. The stress has two components. One component is related to the difference of the thermal expansion coefficients between the film and the Si substrate. Another is related to the film crystallization. It was found that the stress concentrates in the portion of the film nearest the substrate. The stress in tungsten films also reaches a maximum at 550 /sup 0/C, similar to the tungsten silicide films. However, the cause of this behavior is not clear.

Shioya, Y.; Ikegami, K.; Maeda, M.; Yanagida, K.

1987-01-15T23:59:59.000Z

83

Element 74, the Wolfram Versus Tungsten Controversy  

SciTech Connect (OSTI)

Two and a quarter centuries ago, a heavy mineral ore was found which was thought to contain a new chemical element called heavy stone (or tungsten in Swedish). A few years later, the metal was separated from its oxide and the new element (Z=74) was called wolfram. Over the years since that time, both the names wolfram and tungsten were attached to this element in various countries. Sixty years ago, IUPAC chose wolfram as the official name for the element. A few years later, under pressure from the press in the USA, the alternative name tungsten was also allowed by IUPAC. Now the original, official name 'wolfram' has been deleted by IUPAC as one of the two alternate names for the element. The history of this controversy is described here.

Holden,N.E.

2008-08-11T23:59:59.000Z

84

Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li  

E-Print Network [OSTI]

Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li Lithium-halogen exchange reactions are essentially inert. 2 t-BuLi t-BuI + RLi t-BuLi isobutene + isobutane + LiI Lithium-halogen exchange reactions, and lithium iodide. H OEtBr H H OEtLi H1.1 eq n-BuLi Et2O, !80 °C Lau, K. S.; Schlosser, M. J. Org. Chem. 1978

85

TUNGSTEN--2000 81.1 By Kim B. Shedd  

E-Print Network [OSTI]

TUNGSTEN--2000 81.1 TUNGSTEN By Kim B. Shedd Domestic survey data and tables were prepared by Jason T. Collins, statistical assistant, and the world production table was prepared by Glenn J. Wallace, international data coordinator. Tungsten is a whitish-gray metal with many unique properties and a wide variety

86

TUNGSTEN--2001 80.1 By Kim B. Shedd  

E-Print Network [OSTI]

equal to that of 2000. U.S. reported consumption of tungsten to make end-use products decreased slightlyTUNGSTEN--2001 80.1 TUNGSTEN By Kim B. Shedd Domestic survey data and tables were prepared by Heather A. Geissler, statistical assistant, and the world production table was prepared by Glenn J

87

TUNGSTEN--1999 80.1 By Kim B. Shedd  

E-Print Network [OSTI]

TUNGSTEN--1999 80.1 TUNGSTEN By Kim B. Shedd Domestic survey data and tables were prepared by Eric A. Seavey, statistical assistant, and the world production table was prepared by Glenn J. Wallace, international data coordinator. Tungsten has a wide range of industrial uses, the largest of which

88

Gas tungsten arc welder with electrode grinder  

DOE Patents [OSTI]

A welder for automated closure of fuel pins by a gas tungsten arc process in which a rotating length of cladding is positioned adjacent a welding electrode in a sealed enclosure. An independently movable axial grinder is provided in the enclosure for refurbishing the used electrode between welds.

Christiansen, David W. (Kennewick, WA); Brown, William F. (West Richland, WA)

1984-01-01T23:59:59.000Z

89

Joining of Tungsten Armor Using Functional Gradients  

SciTech Connect (OSTI)

The joining of low thermal expansion armor materials such as tungsten to high thermal expansion heat sink materials has been a major problem in plasma facing component (PFC) development. Conventional planar bonding techniques have been unable to withstand the high thermal induced stresses resulting from fabrication and high heat flux testing. During this investigation, innovative functional gradient joints produced using vacuum plasma spray forming techniques have been developed for joining tungsten armor to copper alloy heat sinks. A model was developed to select the optimum gradient architecture. Based on the modeling effort, a 2mm copper rich gradient was selected. Vacuum plasma pray parameters and procedures were then developed to produce the functional gradient joint. Using these techniques, dual cooling channel, medium scale mockups (32mm wide x 400mm length) were produced with vacuum plasma spray formed tungsten armor. The thickness of the tungsten armor was up to 5mm thick. No evidence of debonding at the interface between the heat sink and the vacuum plasma sprayed material was observed.

John Scott O'Dell

2006-12-31T23:59:59.000Z

90

Process for coating tungsten carbide with cobalt metal  

SciTech Connect (OSTI)

A process is described for coating tungsten carbide with cobalt metal, the process comprising: (a) forming an aqueous slurry of tungsten carbide having a particle size of no greater than - 100 mesh, and zinc metal powder; (b) adding ammonia to the slurry with the amount of the ammonia being sufficient so that the slurry is basic after the subsequent addition of cobalt chloride in step c; (c) adding to the resulting ammoniated slurry, a solution of cobalt chloride with agitation, to form a coating of partially reduced cobalt on the tungsten carbide; (d) removing the resulting cobalt coated tungsten carbide from the resulting liquor; and (e) heating the cobalt coated tungsten carbide in a reducing atmosphere to effect the essentially complete reduction of the cobalt and to produce a cobalt metal coating on the tungsten carbide, the coating making up no greater than about 15% of weight of the tungsten carbide.

Ritsko, J.E.; Lee, J.S.

1989-01-31T23:59:59.000Z

91

Preliminary assessment of halogenated alkanes as vapor-phase tracers  

SciTech Connect (OSTI)

New tracers are needed to evaluate the efficiency of injection strategies in vapor-dominated environments. One group of compounds that seems to meet the requirements for vapor-phase tracing are the halogenated alkanes (HCFCs). HCFCs are generally nontoxic, and extrapolation of tabulated thermodynamic data indicate that they will be thermally stable and nonreactive in a geothermal environment. The solubilities and stabilities of these compounds, which form several homologous series, vary according to the substituent ratios of fluorine, chlorine, and hydrogen. Laboratory and field tests that will further define the suitability of HCFCs as vapor-phase tracers are under way.

Adams, Michael C.; Moore, Joseph N.; Hirtz, Paul

1991-01-01T23:59:59.000Z

92

Tungsten Divertor Erosion in all Metal Devices: Lessons from the ITER-Like Wall of JET and the All Tungsten ASDEX Upgrade  

E-Print Network [OSTI]

Tungsten Divertor Erosion in all Metal Devices: Lessons from the ITER-Like Wall of JET and the All Tungsten ASDEX Upgrade

93

Catalytic ionic hydrogenation of ketones using tungsten or molybdenum organometallic species  

DOE Patents [OSTI]

The present invention is a process for the catalytic hydrogenation of ketones and aldehydes to alcohols at low temperatures and pressures using organometallic molybdenum and tungsten complexes. The functional group is selected from groups represented by the formulas R(C.dbd.O)R' and R(C.dbd.O)H, wherein R and R' are selected from hydrogen or any alkyl or aryl group. The active catalyst for the process has the form: [CpM(CO).sub.2 (PR*.sub.3) L].sup.+ A.sup.-, where Cp=.eta..sup.5 -R.sup..tangle-solidup..sub.m C.sub.5 H.sub.5-m and R.sup..tangle-solidup. represents an alkyl group or a halogen (F, Cl, Br, I) or R.sup..tangle-solidup. =OR' (where R'=H, an alkyl group or an aryl group) or R.sup..tangle-solidup. =CO.sub.2 R' (where R'=H, an alkyl group or an aryl group) and m=0 to 5; M represents a molybdenum atom or a tungsten atom; R*.sub.3 represents three hydrocarbon groups selected from a cyclohexyl group (C.sub.6 H.sub.11), a methyl group (CH.sub.3), and a phenyl group (C.sub.6 H.sub.5) and all three R* groups can be the same or different or two of the three groups can be the same; L represents a ligand; and A.sup.- represents an anion. In another embodiment, one, two or three of the R* groups can be an OR*.

Voges, Mark (Leverkusen, DE); Bullock, R. Morris (Wading River, NY)

2000-01-01T23:59:59.000Z

94

Efficient and Regioselective Halogenations of 2-Amino-1,3-thiazoles with Copper Salts  

E-Print Network [OSTI]

Efficient and Regioselective Halogenations of 2-Amino-1,3-thiazoles with Copper Salts Fabrice G. Halogenations proceed easily in the presence of copper(I) or copper(II) chlorides, bromides, or iodides directly in solution or with supported copper halides. 1,3-Thiazole rings appear in many compounds that exhibit

Shen, Jun

95

Controlled nanostructuration of polycrystalline tungsten thin films  

SciTech Connect (OSTI)

Nanostructured tungsten thin films have been obtained by ion beam sputtering technique stopping periodically the growing. The total thickness was maintained constant while nanostructure control was obtained using different stopping periods in order to induce film stratification. The effect of tungsten sublayers' thicknesses on film composition, residual stresses, and crystalline texture evolution has been established. Our study reveals that tungsten crystallizes in both stable {alpha}- and metastable {beta}-phases and that volume proportions evolve with deposited sublayers' thicknesses. {alpha}-W phase shows original fiber texture development with two major preferential crystallographic orientations, namely, {alpha}-W<110> and unexpectedly {alpha}-W<111> texture components. The partial pressure of oxygen and presence of carbon have been identified as critical parameters for the growth of metastable {beta}-W phase. Moreover, the texture development of {alpha}-W phase with two texture components is shown to be the result of a competition between crystallographic planes energy minimization and crystallographic orientation channeling effect maximization. Controlled grain size can be achieved for the {alpha}-W phase structure over 3 nm stratification step. Below, the {beta}-W phase structure becomes predominant.

Girault, B. [Institut P' (UPR 3346 CNRS), Universite de Poitiers, ENSMA, Bd Pierre et Marie Curie, 86962 Futuroscope Cedex (France); Institut de Recherche en Genie Civil et Mecanique (UMR CNRS 6183), LUNAM Universite, Universite de Nantes, Centrale Nantes, CRTT, 37 Bd de l'Universite, BP 406, 44602 Saint-Nazaire Cedex (France); Eyidi, D.; Goudeau, P.; Guerin, P.; Bourhis, E. Le; Renault, P.-O. [Institut P' (UPR 3346 CNRS), Universite de Poitiers, ENSMA, Bd Pierre et Marie Curie, 86962 Futuroscope Cedex (France); Sauvage, T. [CEMHTI/CNRS (UPR 3079 CNRS), Universite d'Orleans, 3A rue de la Ferollerie, 45071 Orleans Cedex 2 (France)

2013-05-07T23:59:59.000Z

96

Tungsten-dependent formaldehyde ferredoxin oxidoreductase: Reaction mechanism from quantum chemical calculations  

E-Print Network [OSTI]

Tungsten-dependent formaldehyde ferredoxin oxidoreductase: Reaction mechanism from quantum chemical theory Enzyme catalysis Formaldehyde ferredoxin oxidoreductase from Pyrococcus furiosus is a tungsten the formaldehyde substrate binds directly to the tungsten ion. WVI =O then performs a nucleophilic attack

Liao, Rongzhen

97

Molybdenum and Tungsten Monoalkoxide Pyrrolide (MAP) Alkylidene Complexes That Contain a 2,6-Dimesitylphenylimido  

E-Print Network [OSTI]

Molybdenum and Tungsten Monoalkoxide Pyrrolide (MAP) Alkylidene Complexes That Contain a 2 ABSTRACT: Molybdenum and tungsten bispyrrolide alkyli- dene complexes that contain a 2 those that contain 2,5-dimethylpyrro- lide are pyridine free. Molybdenum and tungsten MAP 2

Müller, Peter

98

Investigation of coronal plasma dynamics in tungsten and carbon X-pinches  

E-Print Network [OSTI]

Coronal Plasma Dynamics in Tungsten and Carbon X-pinches ACoronal Plasma Dynamics in Tungsten and Carbon X-pinches byformation in 2- and 4-wire tungsten x-pinches using an 80

Madden, Robert Edward

2008-01-01T23:59:59.000Z

99

CRITICAL FIELD FOR SUPERCONDUCTIVITY AND LOW-TEMPERATURE NORMAL-STATE HEAT CAPACITY OF TUNGSTEN  

E-Print Network [OSTI]

NORMAL-STATE HEAT CAPACITY OF TUNGSTEN B. B. Triplett, N. E.State Heat Capacity of Tungsten* B. n. Triplett,t N. E.I. ;\\feasurement Properties of tungsten sa~ples. ~feasured

Triplett, B.B.

2008-01-01T23:59:59.000Z

100

THE As-QUENCHED MICROSTRUCTURE AND TEMPERING BEHAVIOR OF RAPIDLY SOLIDIFIED TUNGSTEN STEELS  

E-Print Network [OSTI]

of six ternary iron-tungsten-carbon alloys and commercialFeWCS-6 (20 and 23wt% tungsten) only the cellular micro-microstructure of the higher tungsten alloys. Selected area

Rayment, J.J.

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

(Data in metric tons of tungsten content unless otherwise noted) Domestic Production and Use: Limited shipments of tungsten concentrates were made from a California mine in  

E-Print Network [OSTI]

178 TUNGSTEN (Data in metric tons of tungsten content unless otherwise noted) Domestic Production and primary products, wrought and unwrought tungsten, and waste and scrap: China, 43%; Germany, 11%; Canada,630 1,450 Events, Trends, and Issues: World tungsten supply was dominated by Chinese production

102

(Data in metric tons of tungsten content unless otherwise noted) Domestic Production and Use: A tungsten mine in California produced concentrates in 2012. Approximately eight  

E-Print Network [OSTI]

176 TUNGSTEN (Data in metric tons of tungsten content unless otherwise noted) Domestic Production and concentrates, intermediate and primary products, wrought and unwrought tungsten, and waste and scrap: China, 45,200 3,630 1,610 Events, Trends, and Issues: World tungsten supply was dominated by Chinese production

103

(Data in metric tons of tungsten content unless otherwise noted) Domestic Production and Use: One mine in California produced tungsten concentrates in 2010. Approximately  

E-Print Network [OSTI]

176 TUNGSTEN (Data in metric tons of tungsten content unless otherwise noted) Domestic Production. Import Sources (2006­09): Tungsten contained in ores and concentrates, intermediate and primary products, Trends, and Issues: World tungsten supply is dominated by Chinese production and exports. China

104

(Data in metric tons of tungsten content unless otherwise noted) Domestic Production and Use: A mine in California produced tungsten concentrates in 2009. Approximately eight  

E-Print Network [OSTI]

176 TUNGSTEN (Data in metric tons of tungsten content unless otherwise noted) Domestic Production. Import Sources (2005-08): Tungsten contained in ores and concentrates, intermediate and primary products, and Issues: World tungsten supply was dominated by Chinese production and exports. China's Government limited

105

(Data in metric tons of tungsten content unless otherwise noted) Domestic Production and Use: A tungsten mine in California produced concentrates in 2013. Approximately eight  

E-Print Network [OSTI]

174 TUNGSTEN (Data in metric tons of tungsten content unless otherwise noted) Domestic Production and concentrates, intermediate and primary products, wrought and unwrought tungsten, and waste and scrap: China, 45,100 2,300 2,240 Events, Trends, and Issues: World tungsten supply was dominated by Chinese production

106

(Data in metric tons of tungsten content unless otherwise noted) Domestic Production and Use: One mine in California produced tungsten concentrates in 2011. Approximately  

E-Print Network [OSTI]

176 TUNGSTEN (Data in metric tons of tungsten content unless otherwise noted) Domestic Production (2007­10): Tungsten contained in ores and concentrates, intermediate and primary products, wrought: World tungsten supply is dominated by Chinese production and exports. China's Government regulates its

107

Tungsten Cluster Migration on Nanoparticles: Minimum Energy Pathway...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pathway and Migration Mechanism. Tungsten Cluster Migration on Nanoparticles: Minimum Energy Pathway and Migration Mechanism. Abstract: Transition state searches have been...

108

A visible light-sensitive tungsten carbide/tungsten trioxde composite photocatalyst  

SciTech Connect (OSTI)

A photocatalyst composed of tungsten carbide (WC) and tungsten oxide (WO{sub 3}) has been prepared by the mechanical mixing of each powder. Its photocatalytic activity was evaluated by the gaseous isopropyl alcohol decomposition process. The photocatalyst showed high visible light photocatalytic activity with a quantum efficiency of 3.2% for 400-530 nm light. The photocatalytic mechanism was explained by means of enhanced oxygen reduction reaction due to WC, which may serve as a multielectron reduction catalyst, as well as the photogeneration of holes in the valence band of WO{sub 3}.

Kim, Young-ho [Research Center for Advanced Science and Technology, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904 (Japan); Irie, Hiroshi [Department of Applied Chemistry, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Hashimoto, Kazuhito [Research Center for Advanced Science and Technology, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904 (Japan); Department of Applied Chemistry, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

2008-05-05T23:59:59.000Z

109

Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands  

E-Print Network [OSTI]

Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding,4 we decided to explore some arylthiolate analogues of terphenoxide molybde- num imido and tungsten

Müller, Peter

110

Tungsten silicide and tungsten polycide anisotropic dry etch process for highly controlled dimensions and profiles  

E-Print Network [OSTI]

dimensions and profiles R. Bashir,a),b) A. E. Kabir,b) F. Hebert,c) and C. Brackenb) National Semiconductors. In many applications a spacer needs to be formed on the polycide sidewall Fig. 1 . Undesirable undercutting can re- sult in nonideal spacer formation for further device fabrica- tion. Tungsten silicide

Bashir, Rashid

111

TungsTen--2004 79. Referencesthatincludeasectionmark()arefoundintheInternet  

E-Print Network [OSTI]

TungsTen--2004 79. Referencesthatincludeasectionmark(§)arefoundintheInternet ReferencesCitedsection. TungsTen ByKimB.shedd Domestic survey data and tables were prepared by Amy C. Tolcin, statistical assistant, and the world production table was prepared by Glenn J. Wallace, international data coordinator

112

Low temperature photoresponse of monolayer tungsten disulphide  

SciTech Connect (OSTI)

High photoresponse can be achieved in monolayers of transition metal dichalcogenides. However, the response times are inconveniently limited by defects. Here, we report low temperature photoresponse of monolayer tungsten disulphide prepared by exfoliation and chemical vapour deposition (CVD) method. The exfoliated device exhibits n-type behaviour; while the CVD device exhibits intrinsic behaviour. In off state, the CVD device has four times larger ratio of photoresponse for laser on/off and photoresponse decay–rise times are 0.1 s (limited by our setup), while the exfoliated device has few seconds. These findings are discussed in terms of charge trapping and localization.

Cao, Bingchen; Shen, Xiaonan; Shang, Jingzhi; Cong, Chunxiao; Yang, Weihuang; Eginligil, Mustafa, E-mail: yuting@ntu.edu.sg, E-mail: meginligil@ntu.edu.sg [Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore, 637371 (Singapore); Yu, Ting, E-mail: yuting@ntu.edu.sg, E-mail: meginligil@ntu.edu.sg [Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore, 637371 (Singapore); Department of Physics, Faculty of Science, National University of Singapore, Singapore, 117542 (Singapore); Graphene Research Centre, National University of Singapore, Singapore, 117546 (Singapore)

2014-11-01T23:59:59.000Z

113

Corrosion and wear resistance of tungsten carbide-cobalt and tungsten carbide-cobalt-chromium thermal spray coatings  

SciTech Connect (OSTI)

Tungsten carbide thermal spray coatings provide wear surfaces to new and overhauled components for various industries. Their wear resistance is obtained by incorporating small tungsten carbide particles into a metal matrix. This presentation will show what parameters influence their corrosion resistance in the ASTM B-117 Salt Spray Corrosion Test,

Quets, J.; Alford, J.R.

1999-07-01T23:59:59.000Z

114

Employee Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and West OtherEmployeeLos Careers

115

Spotlights Archive  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists' Research |RegulationRenewable EnergySouthwest4, 2010 Review of

116

Student Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAbout » Staff125,849|Structures forStudent

117

Student Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAbout » Staff125,849|Structures forStudentMaverick Chea

118

Student Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAbout » Staff125,849|Structures forStudentMaverick

119

Student Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAbout » Staff125,849|Structures forStudentMaverickCzapla

120

Student Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAbout » Staff125,849|Structures

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Tungsten Transport in JET H-mode Plasmas in Hybrid Scenario, Experimental Observations and Modelling  

E-Print Network [OSTI]

Tungsten Transport in JET H-mode Plasmas in Hybrid Scenario, Experimental Observations and Modelling

122

Author's personal copy Tungsten geochemistry and implications for understanding the Earth's interior  

E-Print Network [OSTI]

Author's personal copy Tungsten geochemistry and implications for understanding the Earth Keywords: tungsten uranium basalt core mantle concentration ratio The concentration of tungsten (W of tungsten (W) was sequestered into the core (Jagoutz et al., 1979; Sun, 1982; Newsom and Palme, 1984

Mcdonough, William F.

123

Failure Modes of Vacuum Plasma Spray Tungsten Coating Created on Carbon Fibre Composites under Thermal Loads  

E-Print Network [OSTI]

Failure Modes of Vacuum Plasma Spray Tungsten Coating Created on Carbon Fibre Composites under Thermal Loads

124

TUNGSTEN--2003 79.1 References that include a section mark () are found in the Internet  

E-Print Network [OSTI]

Stockpile (NDS) and increases in stocks held by U.S. industry. No U.S. tungsten mine production was reported reported in 2001. Salient U.S. tungsten statistics and world tungsten concentrate production for 2003TUNGSTEN--2003 79.1 1 References that include a section mark (§) are found in the Internet

125

Preparation and electrocatalytic activity of tungsten carbide and titania nanocomposite  

SciTech Connect (OSTI)

Graphical abstract: The electrocatalytic activity of tungsten carbide and titania nanocomposite is related to the structure, crystal phase and chemical components of the nanocomposite, and is also affected by the property of electrolyte. A synergistic effect exists between tungsten carbide and titania of the composite. Highlights: {yields} Electrocatalytic activity of tungsten carbide and titania nanocomposite with core-shell structure. {yields} Activity is related to the structure, crystal phase and chemical component of the nanocomposite. {yields} The property of electrolyte affects the electrocatalytic activity. {yields} A synergistic effect exists between tungsten carbide and titania of the composite. -- Abstract: Tungsten carbide and titania nanocomposite was prepared by combining a reduced-carbonized approach with a mechanochemical approach. The samples were characterized by X-ray diffraction, transmission electron microscope under scanning mode and X-ray energy dispersion spectrum. The results show that the crystal phases of the samples are composed of anatase, rutile, nonstoichiometry titanium oxide, monotungsten carbide, bitungsten carbide and nonstoichiometry tungsten carbide, and they can be controlled by adjusting the parameters of the reduced-carbonized approach; tungsten carbide particles decorate on the surface of titania support, the diameter of tungsten carbide particle is smaller than 20 nm and that of titania is around 100 nm; the chemical components of the samples are Ti, O, W and C. The electrocatalytic activity of the samples was measured by a cyclic voltammetry with three electrodes. The results indicate that the electrocatalytic activities of the samples are related to their crystal phases and the property of electrolyte in aqueous solution. A synergistic effect between titania and tungsten carbide is reported for the first time.

Hu, Sujuan; Shi, Binbin; Yao, Guoxing [State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032 (China)] [State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032 (China); Li, Guohua, E-mail: nanozjut@zjut.edu.cn [State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032 (China)] [State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032 (China); Ma, Chunan [State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032 (China)] [State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, School of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032 (China)

2011-10-15T23:59:59.000Z

126

Processing and properties of extruded tungsten-hafnium and tungsten-steel composites  

SciTech Connect (OSTI)

The purpose of this study was to evaluate the processing behavior and properties of tungsten-hafnium (W-Hf) and W-steel composites produced by hot extrusion of canned powders. The W-Hf composite was consolidated by extrusion of blended powders with preheat temperatures over the temperature range of 1100 to 1400{degrees}C. All extrusions produced fully dense material which exhibits elongation of the tungsten phase within the hafnium matrix. The flow stress, as characterized by the extrusion constant, decreases with increasing temperature up to 1300{degrees}C and increases substantially at 1400{degrees}C as significant quantities of intermetallic phase are formed during preheating. The room-temperature (RT) hardness and compressive yield stress increase modestly with increased extrusion ratio and are not affected by extrusion temperature in the range 1100 to 1300{degrees}C. The microstructures are essentially fully recrystallized at the 1300{degrees}C preheat temperature and partially recrystallized at lower temperatures. Additionally, a mixture of tungsten and steel powder was consolidated to full density by hot extrusion at a 1000{degrees}C preheat temperature and a reduction ratio of 4.2. Increased reduction of the W-steel composite results in increased RT hardness.

Ohriner, E.K.; Sikka, V.K. [Oak Ridge National Lab., TN (United States); Kapoor, D. [Army Armament Research and Development Engineering Center, Dover, NJ (United States)

1995-02-01T23:59:59.000Z

127

Tungsten-doped thin film materials  

DOE Patents [OSTI]

A dielectric thin film material for high frequency use, including use as a capacitor, and having a low dielectric loss factor is provided, the film comprising a composition of tungsten-doped barium strontium titanate of the general formula (Ba.sub.x Sr.sub.1-x)TiO.sub.3, where X is between about 0.5 and about 1.0. Also provided is a method for making a dielectric thin film of the general formula (Ba.sub.x Sr.sub.1-x)TiO.sub.3 and doped with W, where X is between about 0.5 and about 1.0, a substrate is provided, TiO.sub.2, the W dopant, Ba, and optionally Sr are deposited on the substrate, and the substrate containing TiO.sub.2, the W dopant, Ba, and optionally Sr is heated to form a low loss dielectric thin film.

Xiang, Xiao-Dong; Chang, Hauyee; Gao, Chen; Takeuchi, Ichiro; Schultz, Peter G.

2003-12-09T23:59:59.000Z

128

Rhenium alloying of tungsten heavy alloys  

SciTech Connect (OSTI)

Alloying experiments were performed using rhenium additions to a classic 90 mass % tungsten heavy alloy. The mixed-powder system was liquid phase sintered to full density at 1500 C in 60 min The rhenium-modified alloys exhibited a smaller grain size, higher hardness, higher strength, and lower ductility than the unalloyed system. For an alloy with a composition of 84W-6Re-8Ni-2Fe, the sintered density was 17, 4 Mg/m{sup 3} with a yield strength of 815 MPa, tensile strength of 1180 MPa, and elongation to failure of 13%. This property combination results from the aggregate effects of grain size reduction and solid solution hardening due to rhenium. In the unalloyed system these properties require post-sintering swaging and aging; thus, alloying with rhenium is most attractive for applications where net shaping is desired, such as by powder injection molding.

German, R.M.; Bose, A.; Jerman, G.

1989-01-01T23:59:59.000Z

129

Analysis of Halogen-Mercury Reactions in Flue Gas  

SciTech Connect (OSTI)

Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation was observed at SO{sub 2} concentrations of 400 ppmv and higher. In contrast, SO{sub 2} concentrations as low as 50 ppmv significantly reduced mercury oxidation by bromine, this reduction could be due to both gas and liquid phase interactions between SO{sub 2} and oxidized mercury species. The simultaneous presence of chlorine and bromine in the flue gas resulted in a slight increase in mercury oxidation above that obtained with bromine alone, the extent of the observed increase is proportional to the chlorine concentration. The results of this study can be used to understand the relative importance of gas-phase mercury oxidation by bromine and chlorine in combustion systems. Two temperature profiles were tested: a low quench (210 K/s) and a high quench (440 K/s). For chlorine the effects of quench rate were slight and hard to characterize with confidence. Oxidation with bromine proved sensitive to quench rate with significantly more oxidation at the lower rate. The data generated in this program are the first homogeneous laboratory-scale data on bromine-induced oxidation of mercury in a combustion system. Five Hg-Cl and three Hg-Br mechanisms, some published and others under development, were evaluated and compared to the new data. The Hg-halogen mechanisms were combined with submechanisms from Reaction Engineering International for NO{sub x}, SO{sub x}, and hydrocarbons. The homogeneous kinetics under-predicted the levels of mercury oxidation observed in full-scale systems. This shortcoming can be corrected by including heterogeneous kinetics in the model calculations.

Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

2010-01-01T23:59:59.000Z

130

Process for removing halogenated aliphatic and aromatic compounds from petroleum products  

DOE Patents [OSTI]

A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced.

Googin, John M. (Oak Ridge, TN); Napier, John M. (Oak Ridge, TN); Travaglini, Michael A. (Oliver Springs, TN)

1983-01-01T23:59:59.000Z

131

Process for removing halogenated aliphatic and aromatic compounds from petroleum products  

DOE Patents [OSTI]

A process is described for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 1 fig.

Googin, J.M.; Napier, J.M.; Travaglini, M.A.

1983-09-20T23:59:59.000Z

132

Atomistic computer simulation analysis of nanocrystalline nickel-tungsten alloys  

E-Print Network [OSTI]

Nanocrystalline nickel-tungsten alloys are harder, stronger, more resistant to degradation, and safer to electrodeposit than chromium. Atomistic computer simulations have previously met with success in replicating the ...

Engwall, Alison Michelle

2009-01-01T23:59:59.000Z

133

Alkyne metathesis by molybdenum and tungsten alkylidyne complexes  

E-Print Network [OSTI]

Alkyne metathesis by molybdenum and tungsten alkylidyne complexes is now ~45 years old. Progress in the practical aspects of alkyne metathesis reactions with well-defined complexes, as well as applications, in the last ...

Schrock, Richard Royce

134

Tungsten carbide-cobalt by Three Dimensional Printing  

E-Print Network [OSTI]

Three Dimensional Printing is an additive manufacturing process for rapid prototyping ceramic and metallic parts [Sachs, et al, 1990]. Green (not sintered) tungsten carbide-cobalt parts must have a density greater than 50% ...

Kelley, Andrew, III

1998-01-01T23:59:59.000Z

135

Microstructured tungsten thermophotovoltaic selective emitters c by Natalija (Zorana) Jovanovi?.  

E-Print Network [OSTI]

This research investigates the fabrication, modeling, characterization, and application of tungsten two-dimensional (2D) photonic crystal (PhC) structures as selective emitters and means of achieving higher efficiencies ...

Jovanovic, Natalija Zorana

2008-01-01T23:59:59.000Z

136

Surface Coating of Tungsten Carbide by Electric Exploding of Contact  

SciTech Connect (OSTI)

Electric exploding of a tungsten carbide--cobalt material near-by high-speed steel surface forms on it a hardening coating. The essential structure properties of the formed coatings are determined by parameters of contact exploding electrode at the pulse current amplitude from above 106 A/cm2 and duration less than 10-4 s. The metallographic investigations of coating structures were done by microscope 'Neophot-24'. They have shown that the contact electric exploding caused the transfer of tungsten carbide and cobalt on the surface of high-speed steel. The breakdown of tungsten carbide--cobalt material took place during electrical exploding. The hardening layers of tungsten carbide and pure nanocrystalline tungsten have been formed upon the surface of high-speed steel as a result of electric exploding. Crystalline grains of tungsten have an almost spherical form and their characteristic size less than 400 nanometers. Micro hardness of the coating layers and high-speed steel structures was measured.

Grigoryev, Evgeny G. [General Physics Department, Moscow Engineering Physics Institute, Kashirskoe sh. 31, Moscow, 115409 (Russian Federation)

2011-01-17T23:59:59.000Z

137

Spotlight SAR interferometry for terrain elevation mapping and interferometric change detection  

SciTech Connect (OSTI)

In this report, we employ an approach quite different from any previous work; we show that a new methodology leads to a simpler and clearer understanding of the fundamental principles of SAR interferometry. This methodology also allows implementation of an important collection mode that has not been demonstrated to date. Specifically, we introduce the following six new concepts for the processing of interferometric SAR (INSAR) data: (1) processing using spotlight mode SAR imaging (allowing ultra-high resolution), as opposed to conventional strip-mapping techniques; (2) derivation of the collection geometry constraints required to avoid decorrelation effects in two-pass INSAR; (3) derivation of maximum likelihood estimators for phase difference and the change parameter employed in interferometric change detection (ICD); (4) processing for the two-pass case wherein the platform ground tracks make a large crossing angle; (5) a robust least-squares method for two-dimensional phase unwrapping formulated as a solution to Poisson`s equation, instead of using traditional path-following techniques; and (6) the existence of a simple linear scale factor that relates phase differences between two SAR images to terrain height. We show both theoretical analysis, as well as numerous examples that employ real SAR collections to demonstrate the innovations listed above.

Eichel, P.H.; Ghiglia, D.C.; Jakowatz, C.V. Jr. [and others

1996-02-01T23:59:59.000Z

138

VAPORIZATION OF TUNGSTEN-METAL IN STEAM AT HIGH TEMPERATURES.  

SciTech Connect (OSTI)

The vaporization of tungsten from the APT spallation target dominates the radiological source term for unmitigated target overheating accidents. Chemical reactions of tungsten with steam which persist to tungsten temperatures as low as 800 C result in the formation of a hydrated tungsten-oxide which has a high vapor pressure and is readily convected in a flowing atmosphere. This low-temperature vaporization reaction essentially removes the oxide film that forms on the tungsten-metal surface as soon as it forms, leaving behind a fresh metallic surface for continued oxidation and vaporization. Experiments were conducted to measure the oxidative vaporization rates of tungsten in steam as part of the effort to quantify the MT radiological source term for severe target accidents. Tests were conducted with tungsten rods (1/8 inch diameter, six inches long) heated to temperatures from approximately 700 C to 1350 C in flowing steam which was superheated to 140 C. A total of 19 experiments was conducted. Fifteen tests were conducted by RF induction heating of single tungsten rods held vertical in a quartz glass retort. Four tests were conducted in a vertically-mounted tube furnace for the low temperature range of the test series. The aerosol which was generated and transported downstream from the tungsten rods was collected by passing the discharged steam through a condenser. This procedure insured total collection of the steam along with the aerosol from the vaporization of the rods. The results of these experiments revealed a threshold temperature for tungsten vaporization in steam. For the two tests at the lowest temperatures which were tested, approximately 700 C, the tungsten rods were observed to oxidize without vaporization. The remainder of the tests was conducted over the temperature range of 800 C to 1350 C. In these tests, the rods were found to have lost weight due to vaporization of the tungsten and the missing weight was collected in the downstream condensate system. The aerosol formed a fine white smoke of tungsten-oxide which was visible to the eye as it condensed in the laminar boundary layer of steam which flowed along the surface of the rod. The aerosol continued to flow as a smoke tube downstream of the rod, flowing coaxially along the centerline axis of the quartz glass tube and depositing by impaction along the outside of a bend and at sudden area contractions in the piping. The vaporization rate data from the 17 experiments which exceeded the vaporization threshold temperature are shown in Figure 5 in the form of vaporization rates (g/cm{sup 2} s) vs. inverse temperature (K{sup {minus}1}). Two correlations to the present data are presented and compared to a published correlation by Kilpatrick and Lott. The differences are discussed.

GREENE,G.A.; FINFROCK,C.C.

2000-10-01T23:59:59.000Z

139

GREEN LIVING Replace incandencent and halogen light bulbs with LED and CLFs  

E-Print Network [OSTI]

GREEN LIVING GUIDE ENERGY TRAVEL FOOD sustain yosef WATER Replace incandencent and halogen light for your laundry RESIST THAT SWITCH! Use natural light during the day, and no lights when you are gone USE MORE THAN YOU CAN EAT, reduce your waste stream DRINK FAIR TRADE COFFEE - Check out Conrad

Thaxton, Christopher S.

140

Low-Level Detections of Halogenated Volatile Organic Compounds in Groundwater  

E-Print Network [OSTI]

compounds; Groundwater management; Drinking water. Introduction Approximately one-half of the U and Hitt 2006 , or more complex process-based analyses utilizing groundwater models Eberts et al. 2005Low-Level Detections of Halogenated Volatile Organic Compounds in Groundwater: Use in Vulnerability

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

PHYSICAL REVIEW B 84, 092102 (2011) Melting temperature of tungsten from two ab initio approaches  

E-Print Network [OSTI]

PHYSICAL REVIEW B 84, 092102 (2011) Melting temperature of tungsten from two ab initio approaches L the melting temperature of tungsten by two ab initio approaches. The first approach can be divided into two

Alfè, Dario

2011-01-01T23:59:59.000Z

142

Structure-property Relationships in Pure and Doped Epitaxial Tungsten Trioxide Thin Films  

E-Print Network [OSTI]

Structure-property Relationships in Pure and Doped Epitaxial Tungsten Trioxide Thin Films Principal-property relationships of well- defined epitaxial tungsten trioxide (WO3) films with and without dopants, and thereby

143

Olefin Metathesis Reactions Initiated by d2 Molybdenum or Tungsten Complexes  

E-Print Network [OSTI]

Olefin Metathesis Reactions Initiated by d2 Molybdenum or Tungsten Complexes Richard R. Schrock species, behave as olefin metathesis catalysts. Recently we reported tungsten complexes that contain a Wd

Müller, Peter

144

Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts  

E-Print Network [OSTI]

3,5-Dimethylphenylimido complexes of tungsten can be prepared using procedures analogous to those employed for other tungsten catalysts, as can bispyrrolide species and MonoAryloxide-Pyrrolide (MAP) species. Homocouplings ...

Marinescu, Smaranda C.

145

Compressibility and strength of nanocrystalline tungsten boride under compression to 60GPa  

E-Print Network [OSTI]

interest in transition metal borides (TMs) as potential new avenues for synthesizing hard materials.1­4 Tungsten borides, WBx, which include WB, WB2, and WB4 and are analogous to tungsten carbides, have been

Duffy, Thomas S.

146

Mechanism of vacancy formation induced by hydrogen in tungsten  

SciTech Connect (OSTI)

We report a hydrogen induced vacancy formation mechanism in tungsten based on classical molecular dynamics simulations. We demonstrate the vacancy formation in tungsten due to the presence of hydrogen associated directly with a stable hexagonal self-interstitial cluster as well as a linear crowdion. The stability of different self-interstitial structures has been further studied and it is particularly shown that hydrogen plays a crucial role in determining the configuration of SIAs, in which the hexagonal cluster structure is preferred. Energetic analysis has been carried out to prove that the formation of SIA clusters facilitates the formation of vacancies. Such a mechanism contributes to the understanding of the early stage of the hydrogen blistering in tungsten under a fusion reactor environment.

Liu, Yi-Nan [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing, 100191 (China) [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing, 100191 (China); Association EURATOM-TEKES, University of Helsinki, Helsinki, PO Box 64, 00560 (Finland); Ahlgren, T.; Bukonte, L.; Nordlund, K. [Association EURATOM-TEKES, University of Helsinki, Helsinki, PO Box 64, 00560 (Finland)] [Association EURATOM-TEKES, University of Helsinki, Helsinki, PO Box 64, 00560 (Finland); Shu, Xiaolin; Yu, Yi; Lu, Guang-Hong, E-mail: LGH@buaa.edu.cn [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing, 100191 (China)] [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing, 100191 (China); Li, Xiao-Chun [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui, 230031 (China)] [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui, 230031 (China)

2013-12-15T23:59:59.000Z

147

Ductile tungsten-nickel alloy and method for making same  

DOE Patents [OSTI]

The present invention is directed to a ductile, high-density tungsten-nickel alloy which possesses a tensile strength in the range of 100,000 to 140,000 psi and a tensile elongation of 3.1 to 16.5 percent in 1 inch at 25.degree.C. This alloy is prepared by the steps of liquid phase sintering a mixture of tungsten-0.5 to 10.0 weight percent nickel, heat treating the alloy at a temperature above the ordering temperature of approximately 970.degree.C. to stabilize the matrix phase, and thereafter rapidly quenching the alloy in a suitable liquid to maintain the matrix phase in a metastable, face-centered cubic, solid- solution of tungsten in nickel.

Snyder, Jr., William B. (Knoxville, TN)

1976-01-01T23:59:59.000Z

148

A history of tungsten- and molybdenum-base alloys  

SciTech Connect (OSTI)

The development of tungsten and molybdenum alloys was initiated in the early 1900s in search of a better electric lamp filament with tantalum, tungsten, rhenium, and osmium being the prime candidates. The efforts required for accomplishment of the task led to refining oxides to high purity, reduction of the oxides to metal powders, forming green product forms by extrusion or pressing, and finally sintering by electric furnace and self-heating by direct current almost to the melting point. The technology required for producing lamp filaments led to the development of the powder metallurgy field and early research on high-melting-temperature metals. During the period 1909 through 1959, most of the tungsten-molybdenum, high-melting-temperature element alloys were developed and produced in almost any product form required.

Heestand, R.L.

1993-05-01T23:59:59.000Z

149

A history of tungsten- and molybdenum-base alloys  

SciTech Connect (OSTI)

The development of tungsten and molybdenum alloys was initiated in the early 1900s in search of a better electric lamp filament with tantalum, tungsten, rhenium, and osmium being the prime candidates. The efforts required for accomplishment of the task led to refining oxides to high purity, reduction of the oxides to metal powders, forming green product forms by extrusion or pressing, and finally sintering by electric furnace and self-heating by direct current almost to the melting point. The technology required for producing lamp filaments led to the development of the powder metallurgy field and early research on high-melting-temperature metals. During the period 1909 through 1959, most of the tungsten-molybdenum, high-melting-temperature element alloys were developed and produced in almost any product form required.

Heestand, R.L.

1993-01-01T23:59:59.000Z

150

DOI: 10.1002/adsc.201100200 Preparation of Tungsten-Based Olefin Metathesis Catalysts  

E-Print Network [OSTI]

DOI: 10.1002/adsc.201100200 Preparation of Tungsten-Based Olefin Metathesis Catalysts Supported://dx.doi.org/10.1002/adcs.201100200. Abstract: A new tungsten alkylidene complex, WACHTUNGTRENNUNG catalysts; tungsten Introduction In the last dozen years various "well-defined" Mo/W[1] or Ru[2] olefin

Müller, Peter

151

ORIGINAL PAPER Why is the molybdenum-substituted tungsten-dependent  

E-Print Network [OSTI]

ORIGINAL PAPER Why is the molybdenum-substituted tungsten-dependent formaldehyde ferredoxin oxidoreductase is a tungsten-dependent enzyme that catalyzes the oxidative degradation of formaldehyde to formic acid. The moly- bdenum ion can be incorporated into the active site to displace the tungsten ion

Liao, Rongzhen

152

Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride As the Acid  

E-Print Network [OSTI]

Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Supporting Information ABSTRACT: Routes to new tungsten alkylidene complexes that contain tert and tungsten, especially aryls that are mono- or disubstituted in the ortho position(s).2 However, it has

Müller, Peter

153

Single-Crystal Tungsten Oxide Nanosheets: Photochemical Water Oxidation in the Quantum Confinement Regime  

E-Print Network [OSTI]

Single-Crystal Tungsten Oxide Nanosheets: Photochemical Water Oxidation in the Quantum Confinement, catalysis, WO3, tungsten oxide, nanosheet, nanocrystal, quantum confinement, solar energy conversion INTRODUCTION Tungsten trioxide crystallizes in the ReO3 structure type and is an n-type semiconductor with a 2

Osterloh, Frank

154

Synthesis and Reactions of Tungsten Alkylidene Complexes That Contain the 2,6-Dichlorophenylimido Ligand  

E-Print Network [OSTI]

Synthesis and Reactions of Tungsten Alkylidene Complexes That Contain the 2,6-Dichlorophenylimido Institute of Technology, Cambridge, Massachusetts 02139 ReceiVed October 30, 2006 Tungsten alkylidene alkylidene bisalkoxide complexes of molybdenum or tungsten of the type M(NR)(CHR)(OR)2 are now established

Müller, Peter

155

Imido Alkylidene Bispyrrolyl Complexes of Tungsten Thorsten Kreickmann, Stefan Arndt, Richard R. Schrock,* and Peter Muller  

E-Print Network [OSTI]

Imido Alkylidene Bispyrrolyl Complexes of Tungsten Thorsten Kreickmann, Stefan Arndt, Richard R, Massachusetts 02139 ReceiVed July 16, 2007 We have prepared tungsten bispyrrolyl (Pyr) or bis-2 this type of chemistry to tungsten. In this paper we report W(NR)(CHCMe2R)(pyrrolyl)2 complexes where R is 2

Müller, Peter

156

Radial x-ray diffraction of tungsten tetraboride to 86 GPa under nonhydrostatic compression  

E-Print Network [OSTI]

Radial x-ray diffraction of tungsten tetraboride to 86 GPa under nonhydrostatic compression Lun December 2012; published online 16 January 2013) Investigations of the equation of state of tungsten moduli and hardness exceed- ing or closing that of diamond. Tungsten tetraboride (WB4) is a candidate

Lin, Jung-Fu "Afu"

157

Z-Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes  

E-Print Network [OSTI]

Z-Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes Dmitry V). Early in the development of olefin metathesis catalysts that contain tungsten, it was shown that metathetically more active and reproducible systems were produced when tungsten oxo complexes were deliberately

Müller, Peter

158

Tungsten uptake kinetics and trophic1 transfer into a novel gastropod model2  

E-Print Network [OSTI]

Tungsten uptake kinetics and trophic1 transfer into a novel gastropod model2 James H. Lindsay3 U Previous investigations on the military relevant metal, tungsten (W), have paved the way for further6 in comparison to the rest of the body, which was18 predominantly monomeric species of tungsten. The pathways

Ma, Lena

159

Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand  

E-Print Network [OSTI]

Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand 02467, United States *S Supporting Information ABSTRACT: Tungsten NArR alkylidene complexes have been is the nature of Z. Perhaps the most dramatic variations are those in which M is tungsten and Z is an oxo ligand

Müller, Peter

160

Mechanism of tungsten-dependent acetylene hydratase from quantum chemical calculations  

E-Print Network [OSTI]

Mechanism of tungsten-dependent acetylene hydratase from quantum chemical calculations Rong hydratase is a tungsten-dependent enzyme that cata- lyzes the nonredox hydration of acetylene metalloenzyme cluster approach Tungsten is the heaviest metal in biology and plays prominent roles in carbon

Liao, Rongzhen

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Growth of epitaxial tungsten oxide nanorods M.Gillet*, R. Delamare, E. Gillet  

E-Print Network [OSTI]

the grain boundaries. So the synthesis of monocristalline tungsten oxide as nanowires or nanorods amorphous tungsten oxide nanoparticles. Y.B. Li et al [18] have synthesized WO3 nanobelts and nanorods via1 Growth of epitaxial tungsten oxide nanorods M.Gillet*, R. Delamare, E. Gillet UNIVERSITE D

Paris-Sud XI, Université de

162

Tungsten carbide synthesized by low-temperature combustion as gas diffusion electrode catalyst  

E-Print Network [OSTI]

Tungsten carbide synthesized by low-temperature combustion as gas diffusion electrode catalyst Ping June 2014 Keywords: Low-temperature combustion syn- thesis Tungsten carbide Electrocatalyst Gas diffusion electrode a b s t r a c t Tungsten carbide powder, which is used as the catalyst for a gas

Volinsky, Alex A.

163

FRACTURE AND CREEP IN AN ALL-TUNGSTEN DIVERTOR FOR ARIES James P. Blanchard  

E-Print Network [OSTI]

FRACTURE AND CREEP IN AN ALL-TUNGSTEN DIVERTOR FOR ARIES James P. Blanchard University of Wisconsin proposing an all-tungsten divertor for their tokamak designs. In designing such a component, fracture a series of fracture mechanics-based analyses to demonstrate the feasibility of using an all- tungsten

164

Real-time growth rate metrology for a tungsten chemical vapor deposition process by acoustic sensing  

E-Print Network [OSTI]

to a production-scale tungsten chemical vapor deposition cluster tool for in situ process sensing. Process gasesReal-time growth rate metrology for a tungsten chemical vapor deposition process by acoustic to achieve run-to-run process control of the deposited tungsten film thickness. © 2001 American Vacuum

Rubloff, Gary W.

165

The Corrosion of Tungsten During Irradiation in an 800 MeV Proton Beam  

E-Print Network [OSTI]

such technology is Accelerator Production of Tritium (APT). In APT a tungsten target is bombarded by a high energyThe Corrosion of Tungsten During Irradiation in an 800 MeV Proton Beam R. Scott Lillard, Darryl P of solid neutron spallation targets such as tungsten (W), and target cladding or structural materials

166

Production And Characterization Of Tungsten-Based Positron Moderators  

SciTech Connect (OSTI)

Experiments of interest in Atomic Physics require production of well-defined low-energy positron beams through a moderation process of high-energy positrons, which can be produced by either the use of a radioactive source or by accelerator based pair production process. Tungsten is one of the most commonly used moderator materials because of its reasonable efficiency, high work function and relatively low cost. In this work we present different methods to produce tungsten-based candidate moderators in a variety of shapes. We also present results from characterizing these candidate moderators by ion beam analysis and microscopy techniques.

Lucio, O. G. de; Morales, J. G.; Cruz-Manjarrez, H. [Instituto de Fisica, Universidad Nacional Autonoma de Mexico, Apartado Postal 20-364 01000, Mexico DF (Mexico)

2011-06-01T23:59:59.000Z

167

Effects of sequential tungsten and helium ion implantation on nano-indentation hardness of tungsten  

SciTech Connect (OSTI)

To simulate neutron and helium damage in a fusion reactor first wall sequential self-ion implantation up to 13 dpa followed by helium-ion implantation up to 3000 appm was performed to produce damaged layers of {approx}2 {mu}m depth in pure tungsten. The hardness of these layers was measured using nanoindentation and was studied using transmission electron microscopy. Substantial hardness increases were seen in helium implanted regions, with smaller hardness increases in regions which had already been self-ion implanted, thus, containing pre-existing dislocation loops. This suggests that, for the same helium content, helium trapped in distributed vacancies gives stronger hardening than helium trapped in vacancies condensed into dislocation loops.

Armstrong, D. E. J.; Edmondson, P. D.; Roberts, S. G. [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom)] [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom)

2013-06-24T23:59:59.000Z

168

Tungsten and tungsten alloy powder metallurgy: Powder production and applications excluding lamps. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations of selected patents concerning the preparation of metallic and ceramic powders of tungsten and tungsten alloys, including applications of these materials. The hydrogen reduction of tungsten compounds together with alloying element compounds produce forms with characteristics of high density, hardness, wear resistance, high melting points, and abrasiveness. Topics include production of cathodes, heaters, filament wires, electrical contacts, acoustic absorbers, high-density sheets and coatings, hard penetrators, and tungsten carbide and metallized ceramics. (Contains a minimum of 109 citations and includes a subject term index and title list.)

Not Available

1994-04-01T23:59:59.000Z

169

Retention of Hydrogen Isotopes in Neutron Irradiated Tungsten  

SciTech Connect (OSTI)

To investigate the effects of neutron irradiation on hydrogen isotope retention in tungsten, disk-type specimens of pure tungsten were irradiated in the High Flux Isotope Reactor in Oak Ridge National Laboratory followed by exposure to high flux deuterium (D) plasma in Idaho National Laboratory. The results obtained for low dose n-irradiated specimens (0.025 dpa for tungsten) are reviewed in this paper. Irradiation at coolant temperature of the reactor (around 50 degrees C) resulted in the formation of strong trapping sites for D atoms. The concentrations of D in n-irradiated specimens were ranging from 0.1 to 0.4 mol% after exposure to D plasma at 200 and 500 degrees C and significantly higher than those in non-irradiated specimens because of D-trapping by radiation defects. Deep penetration of D up to a depth of 50-100 µm was observed at 500 degrees C. Release of D in subsequent thermal desorption measurements continued up to 900 degrees C. These results were compared with the behaviour of D in ion-irradiated tungsten, and distinctive features of n-irradiation were discussed.

Yuji Hatano; Masashi Shimada; Yasuhisa Oya; Guoping Cao; Makoto Kobayashi; Masanori Hara; Brad J. Merrill; Kenji Okuno; Mikhail A. Sokolov; Yutai Katoh

2013-03-01T23:59:59.000Z

170

Tungsten-yttria carbide coating for conveying copper  

DOE Patents [OSTI]

A method is provided for providing a carbided-tungsten-yttria coating on the interior surface of a copper vapor laser. The surface serves as a wick for the condensation of liquid copper to return the condensate to the interior of the laser for revolatilization.

Rothman, Albert J. (Livermore, CA)

1993-01-01T23:59:59.000Z

171

Development of Bulk Nanocrystalline Cemented Tungsten Carbide for Industrial Applicaitons  

SciTech Connect (OSTI)

This report contains detailed information of the research program entitled "Development of Bulk Nanocrystalline Cemented Tungsten Carbide Materials for Industrial Applications". The report include the processes that were developed for producing nanosized WC/Co composite powders, and an ultrahigh pressure rapid hot consolidation process for sintering of nanosized powders. The mechanical properties of consolidated materials using the nanosized powders are also reported.

Z. Zak Fang, H. Y. Sohn

2009-03-10T23:59:59.000Z

172

Author's personal copy Tungsten in Hawaiian picrites: A compositional model  

E-Print Network [OSTI]

form 15 April 2009; available online 3 May 2009 Abstract Concentrations of tungsten (W) and uranium (U is three-times as enriched as the Depleted MORB Mantle (DMM; 3.0 ± 2.3 ng/g). The relatively high of the recycling of W-rich oceanic crust and sediment into a depleted mantle source, such as the depleted MORB

Mcdonough, William F.

173

Novel Reactor Design and Metrology Study for Tungsten ALD process  

E-Print Network [OSTI]

species Viscous flow condition Short gas residence time Fast gas switching Reactant + carrier gas Multiple Operation Modes Exposure Purge Small reactor volume Throttle Valve 5 torr 10-5 Torr carrier gas 5 torr 10Novel Reactor Design and Metrology Study for Tungsten ALD process Laurent Henn-Lecordier, Wei Lei

Rubloff, Gary W.

174

Space-Variant Post-Filtering for Wavefront Curvature Correction in Polar-Formatted Spotlight-Mode SAR Imagery  

SciTech Connect (OSTI)

Wavefront curvature defocus effects occur in spotlight-mode SAR imagery when reconstructed via the well-known polar-formatting algorithm (PFA) under certain imaging scenarios. These include imaging at close range, using a very low radar center frequency, utilizing high resolution, and/or imaging very large scenes. Wavefront curvature effects arise from the unrealistic assumption of strictly planar wavefronts illuminating the imaged scene. This dissertation presents a method for the correction of wavefront curvature defocus effects under these scenarios, concentrating on the generalized: squint-mode imaging scenario and its computational aspects. This correction is accomplished through an efficient one-dimensional, image domain filter applied as a post-processing step to PF.4. This post-filter, referred to as SVPF, is precalculated from a theoretical derivation of the wavefront curvature effect and varies as a function of scene location. Prior to SVPF, severe restrictions were placed on the imaged scene size in order to avoid defocus effects under these scenarios when using PFA. The SVPF algorithm eliminates the need for scene size restrictions when wavefront curvature effects are present, correcting for wavefront curvature in broadside as well as squinted collection modes while imposing little additional computational penalty for squinted images. This dissertation covers the theoretical development, implementation and analysis of the generalized, squint-mode SVPF algorithm (of which broadside-mode is a special case) and provides examples of its capabilities and limitations as well as offering guidelines for maximizing its computational efficiency. Tradeoffs between the PFA/SVPF combination and other spotlight-mode SAR image formation techniques are discussed with regard to computational burden, image quality, and imaging geometry constraints. It is demonstrated that other methods fail to exhibit a clear computational advantage over polar-formatting in conjunction with SVPF. This research concludes that PFA in conjunction with SVPF provides a computationally efficient spotlight-mode image formation solution that solves the wavefront curvature problem for most standoff distances and patch sizes, regardless of squint, resolution or radar center frequency. Additional advantages are that SVPF is not iterative and has no dependence on the visual contents of the scene: resulting in a deterministic computational complexity which typically adds only thirty percent to the overall image formation time.

DOREN,NEALL E.

1999-10-01T23:59:59.000Z

175

Method of increments for the halogen molecular crystals: Cl, Br, and I  

SciTech Connect (OSTI)

Method of increments (MI) calculations reveal the n-body correlation contributions to binding in solid chlorine, bromine, and iodine. Secondary binding contributions as well as d-correlation energies are estimated and compared between each solid halogen. We illustrate that binding is entirely determined by two-body correlation effects, which account for >80% of the total correlation energy. One-body, three-body, and exchange contributions are repulsive. Using density-fitting (DF) local coupled-cluster singles, doubles, and perturbative triples for incremental calculations, we obtain excellent agreement with the experimental cohesive energies. MI results from DF local second-order Møller-Plesset perturbation (LMP2) yield considerably over-bound cohesive energies. Comparative calculations with density functional theory and periodic LMP2 method are also shown to be less accurate for the solid halogens.

Steenbergen, Krista G. [Physikalische und Theoretische Chemie, Freie Universität Berlin, Takustr. 3, 14195 Berlin (Germany); MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, P.O. Box 600, Wellington 6012 (New Zealand); Gaston, Nicola [MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, P.O. Box 600, Wellington 6012 (New Zealand); Müller, Carsten; Paulus, Beate [Physikalische und Theoretische Chemie, Freie Universität Berlin, Takustr. 3, 14195 Berlin (Germany)

2014-09-28T23:59:59.000Z

176

The chemistry of halogens on diamond: effects on growth and electron emission  

SciTech Connect (OSTI)

Diamond growth using halogenated precursors was studied in several diamond growth reactors. In a conventionao plasma reactor, diamond growth using the following gas mixtures was studied: CF{sub 4}/H{sub 2}, CH{sub 4}/H{sub 2}, CH{sub 3}F/H{sub 2}, and CH{sub 3}CL/H{sub 2}. Both the diamond growth measurements demonstrated ineffective transport of halogen radicals to the diamond surface during the growth process. In order to transport radical halogen species to the diamond surface during growth, a flow-tube reactor was constructed which minimized gas phase reactions. Also, the flow-tube reactor enabled pulsed gs transport to the diamond surface by fast-acting valves. Molecular beam mass spectroscopy was used to find condition which resulted in atomic hydrogen and/or atomic fluorine transport to the growing diamond surface. Although such conditions were found, they required very low pressures (0.5 Torr and below); these low pressures produce radical fluxes which are too low to sustain a reasonable diamond growth rate. The sequential reactor at Stanford was modified to add a halogen-growth step to the conventinoal atomic hydrogen/atomic carbon diamond growth cycle. Since the atomic fluorine, hydrogen and carbon environments are independent in the sequential reactor, the effect of fluorine on diamond growth could be studied independently of gas phase reactions. Although the diamond growth rate was increased by the use of fluorine, the film quality was seen to deteriorate as well as the substrate surface. Moreover, materials incompatibilities with fluorine significantly limited the use of fluorine in this reactor. A diamond growth model incorporating both gas phase and surface reactions was developed for the halocarbon system concurrent with the film growth efforts. In this report, we review the results of the growth experiments, the modeling, and additional experiments done to understand fluorine with diamond surfaces.

Hsu, W.L.; Pan, L.S.; Brown, L.A. [Sandia National Labs., Livermore, CA (United States)] [and others

1997-02-01T23:59:59.000Z

177

Photofragmentation spectra of halogenated methanes in the VUV photon energy range  

SciTech Connect (OSTI)

In this paper an investigation of the photofragmentation of dihalomethanes CH{sub 2}X{sub 2} (X = F, Cl, Br, I) and chlorinated methanes (CH{sub n}Cl{sub 4?n} with n = 0–3) with VUV helium, neon, and argon discharge lamps is reported and the role played by the different halogen atoms is discussed. Halogenated methanes are a class of molecules used in several fields of chemistry and the study of their physical and chemical proprieties is of fundamental interest. In particular their photodissociation and photoionization are of great importance since the decomposition of these compounds in the atmosphere strongly affects the environment. The results of the present work show that the halogen-loss is the predominant fragmentation channel for these molecules in the VUV photon energy range and confirm their role as reservoir of chlorine, bromine, and iodine atoms in the atmosphere. Moreover, the results highlight the peculiar feature of CH{sub 2}F{sub 2} as a source of both fluorine and hydrogen atoms and the characteristic formation of I{sub 2}{sup +} and CH{sub 2}{sup +} ions from the photofragmentation of the CH{sub 2}I{sub 2} molecule.

Cartoni, Antonella, E-mail: antonella.cartoni@uniroma1.it [Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza Università di Roma, P.le Aldo Moro 5, Roma 00185 (Italy)] [Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza Università di Roma, P.le Aldo Moro 5, Roma 00185 (Italy); Bolognesi, Paola; Fainelli, Ettore; Avaldi, Lorenzo [CNR-IMIP, Area della Ricerca di Roma 1, Monterotondo Scalo (Rm) 00015 (Italy)] [CNR-IMIP, Area della Ricerca di Roma 1, Monterotondo Scalo (Rm) 00015 (Italy)

2014-05-14T23:59:59.000Z

178

Pitfalls of tungsten multileaf collimator in proton beam therapy  

SciTech Connect (OSTI)

Purpose: Particle beam therapy is associated with significant startup and operational cost. Multileaf collimator (MLC) provides an attractive option to improve the efficiency and reduce the treatment cost. A direct transfer of the MLC technology from external beam radiation therapy is intuitively straightforward to proton therapy. However, activation, neutron production, and the associated secondary cancer risk in proton beam should be an important consideration which is evaluated. Methods: Monte Carlo simulation with FLUKA particle transport code was applied in this study for a number of treatment models. The authors have performed a detailed study of the neutron generation, ambient dose equivalent [H*(10)], and activation of a typical tungsten MLC and compared with those obtained from a brass aperture used in a typical proton therapy system. Brass aperture and tungsten MLC were modeled by absorber blocks in this study, representing worst-case scenario of a fully closed collimator. Results: With a tungsten MLC, the secondary neutron dose to the patient is at least 1.5 times higher than that from a brass aperture. The H*(10) from a tungsten MLC at 10 cm downstream is about 22.3 mSv/Gy delivered to water phantom by noncollimated 200 MeV beam of 20 cm diameter compared to 14 mSv/Gy for the brass aperture. For a 30-fraction treatment course, the activity per unit volume in brass aperture reaches 5.3 x 10{sup 4} Bq cm{sup -3} at the end of the last treatment. The activity in brass decreases by a factor of 380 after 24 h, additional 6.2 times after 40 days of cooling, and is reduced to background level after 1 yr. Initial activity in tungsten after 30 days of treating 30 patients per day is about 3.4 times higher than in brass that decreases only by a factor of 2 after 40 days and accumulates to 1.2 x 10{sup 6} Bq cm{sup -3} after a full year of operation. The daily utilization of the MLC leads to buildup of activity with time. The overall activity continues to increase due to {sup 179}Ta with a half-life of 1.82 yr and thus require prolonged storage for activity cooling. The H*(10) near the patient side of the tungsten block is about 100 {mu}Sv/h and is 27 times higher at the upstream side of the block. This would lead to an accumulated dose for therapists in a year that may exceed occupational maximum permissible dose (50 mSv/yr). The value of H*(10) at the upstream surface of the tungsten block is about 220 times higher than that of the brass. Conclusions: MLC is an efficient way for beam shaping and overall cost reduction device in proton therapy. However, based on this study, tungsten seems to be not an optimal material for MLC in proton beam therapy. Usage of tungsten MLC in clinic may create unnecessary risks associated with the secondary neutrons and induced radioactivity for patients and staff depending on the patient load. A careful selection of material for manufacturing of an optimal MLC for proton therapy is thus desired.

Moskvin, Vadim; Cheng, Chee-Wai; Das, Indra J. [Department of Radiation Oncology, Indiana University School of Medicine, Indianapolis, Indiana 46202 (United States) and Indiana University Health Proton Therapy Center (Formerly Midwest Proton Radiotherapy Institute), Bloomington, Indiana 47408 (United States)

2011-12-15T23:59:59.000Z

179

Development of positron annihilation spectroscopy for characterizing neutron irradiated tungsten  

SciTech Connect (OSTI)

Tungsten samples (6 mm diameter, 0.2 mm thick) were irradiated to 0.025 and 0.3 dpa with neutrons in the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory. Samples were then exposed to deuterium plasma in the tritium plasma experiment (TPE) at 100, 200 and 500ºC to a total fluence of 1 x 1026 m-2. Nuclear reaction analysis (NRA) and Doppler broadening positron annihilation spectroscopy (DB-PAS) were performed at various stages to characterize damage and retention. We present the first known results of neutron damaged tungsten characterized by DB-PAS in order to study defect concentration. Two positron sources, 22Na and 68Ge, probe ~58 µm and through the entire 200 µm thick samples, respectively. DB-PAS results reveal clear differences between the various irradiated samples. These results, and the calibration of DB-PAS to NRA data are presented.

C.N. Taylor; M. Shimada; D.W. Akers; M.W. Drigert; B.J. Merrill; Y. Hatano

2013-05-01T23:59:59.000Z

180

Studies on nickel-tungsten oxide thin films  

SciTech Connect (OSTI)

Nickel-Tungsten oxide (95:5) thin films were prepared by rf sputtering at 200W rf power with various substrate temperatures. X-ray diffraction study reveals the amorphous nature of films. The substrate temperature induced decrease in energy band gap with a maximum transmittance of 71%1 was observed. The Micro-Raman study shows broad peaks at 560 cm{sup ?1} and 1100 cm{sup ?1} correspond to Ni-O vibration and the peak at 860 cm{sup ?1} can be assigned to the vibration of W-O-W bond. Photoluminescence spectra show two peaks centered on 420 nm and 485 nm corresponding to the band edge emission and vacancies created due to the addition of tungsten, respectively.

Usha, K. S. [Department of Physics, Alagappa University, Karaikudi - 630 004 (India); Sivakumar, R., E-mail: krsivakumar1979@yahoo.com [Directorate of Distance Education, Alagappa University, Karaikudi - 630 004 (India); Sanjeeviraja, C. [Department of Physics, Alagappa Chettiar College of Engineering and Technology, Karaikudi - 630 004 (India)

2014-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Gas-tungsten arc welding of aluminum alloys  

DOE Patents [OSTI]

A gas-tungsten arc welding method for joining together structures formed of aluminum alloy with these structures disposed contiguously to a heat-damagable substrate of a metal dissimilar to the aluminum alloy. The method of the present invention is practiced by diamond machining the fay surfaces of the aluminum alloy structures to provide a mirror finish thereon having a surface roughness in the order of about one microinch. The fay surfaces are aligned and heated sufficiently by the tungsten electrode to fuse the aluminum alloy contiguous to the fay surfaces to effect the weld joint. The heat input used to provide an oxide-free weld is significantly less than that required if the fay surfaces were prepared by using conventional chemical and mechanical practices.

Frye, Lowell D. (Kingston, TN)

1984-01-01T23:59:59.000Z

182

Gas-tungsten arc welding of aluminum alloys  

DOE Patents [OSTI]

The present invention is directed to a gas-tungsten arc welding method for joining together structures formed of aluminum alloy with these structures disposed contiguously to a heat-damagable substrate of a metal dissimilar to the aluminum alloy. The method of the present invention is practiced by diamond machining the fay surfaces of the aluminum alloy structures to profice a mirror finish thereon having a surface roughness in the order of about one microinch. The fay surface are aligned and heated sufficiently by the tungsten electrode to fuse the aluminum alloy continguous to the fay surfaces to effect the weld joint. The heat input used to provide an oxide-free weld is significantly less than that required if the fay surfaces were prepared by using conventional chemical and mechanical practices.

Frye, L.D.

1982-03-25T23:59:59.000Z

183

Solid-state sintering of tungsten heavy alloys  

SciTech Connect (OSTI)

Solid-state sintering is a technologically important step in the fabrication of tungsten heavy alloys. This work addresses practical variables affecting the sinterability: powder particle size, powder mixing, and sintering temperature and time. Compositions containing 1 to 10 micrometer ({mu}M) tungsten (W) powders can be fully densified at temperatures near the matrix solidus. Blending with an intensifier bar provided good dispersion of elemental powders and good as-sintered mechanical properties under adequate sintering conditions. Additional ball milling increases powder bulk density which primarily benefits mold and die filling. Although fine, 1 {mu}m W powder blends have high sinterability, higher as-sintered ductilities are reached in shorter sintering times with coarser, 5 {mu}m W powder blends; 10{mu}m W powder blends promise the highest as-sintered ductilities due to their coarse microstructural W.

Gurwell, W.E.

1994-10-01T23:59:59.000Z

184

In vivo interactions between tungsten microneedles and peripheral nerves  

E-Print Network [OSTI]

Tungsten microneedles are currently used to insert neural electrodes into living peripheral nerves. However, the biomechanics underlying these procedures is not yet well characterized. For this reason, the aim of this work was to model the interactions between these microneedles and living peripheral nerves. A simple mathematical framework was especially provided to model both compression of the external layer of the nerve (epineurium) and the interactions resulting from penetration of the main shaft of the microneedle inside the living nerves. The instantaneous Young's modulus, compression force, the work needed to pierce the tissue, puncturing pressure, and the dynamic friction coefficient between the tungsten microneedles and living nerves were quantified starting from acute experiments, aiming to reproduce the physical environment of real implantations. Indeed, a better knowledge of the interactions between microneedles and peripheral nerves may be useful to improve the effectiveness of these insertion techniques, and could represent a key factor for designing robot-assisted procedures tailored for peripheral nerve insertion.

Pier Nicola Sergi; Winnie Jensen; Silvestro Micera; Ken Yoshida

2013-08-02T23:59:59.000Z

185

Thermal-treatment effect on the photoluminescence and gas-sensing properties of tungsten oxide nanowires  

SciTech Connect (OSTI)

Single-crystalline non-stoichiometric tungsten oxide nanowires were initially prepared using a simple solvothermal method. High resolution transmission electron microscopy (HRTEM) investigations indicate that the tungsten oxide nanowires exhibit various crystal defects, including stacking faults, dislocations, and vacancies. A possible defect-induced mechanism was proposed to account for the temperature-dependent morphological evolution of the tungsten oxide nanowires under thermal processing. Due to the high specific surface areas and non-stoichiometric crystal structure, the original tungsten oxide nanowires were highly sensitive to ppm level ethanol at room temperature. Thermal treatment under dry air condition was found to deteriorate the selectivity of room-temperature tungsten oxide sensors, and 400 {sup o}C may be considered as the top temperature limit in sensor applications for the solvothermally-prepared nanowires. The photoluminescence (PL) characteristics of tungsten oxide nanowires were also strongly influenced by thermal treatment.

Sun, Shibin [College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, Shandong (China)] [College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, Shandong (China); Chang, Xueting [Institute of Materials Science and Engineering, Ocean University of China, Qingdao 266100, Shandong (China)] [Institute of Materials Science and Engineering, Ocean University of China, Qingdao 266100, Shandong (China); Li, Zhenjiang, E-mail: zjli126@126.com [College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, Shandong (China)] [College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, Shandong (China)

2010-09-15T23:59:59.000Z

186

Tungsten spectroscopy relevant to the diagnostics development of ITER divertor plasmas  

SciTech Connect (OSTI)

The ITER tokamak will have tungsten divertor tiles and, consequently, the divertor plasmas are expected to contain tungsten ions. The spectral emission from these ions can serve to diagnose the divertor for plasma parameters such as tungsten concentrations, densities, ion and electron temperatures, and flow velocities. The ITER divertor plasmas will likely have densities around 10{sup 14-15} cm{sup -3} and temperatures below 150 eV. These conditions are similar to the plasmas at the Sustained Spheromak Physics Experiment (SSPX) in Livermore. To simulate ITER divertor plasmas, a tungsten impurity was introduced into the SSPX spheromak by prefilling it with tungsten hexacarbonyl prior to the usual hydrogen gas injection and initiation of the plasma discharge. The possibility of using the emission from low charge state tungsten ions to diagnose tokamak divertor plasmas has been investigated using a high-resolution extreme ultraviolet spectrometer.

Clementson, J; Beiersdorfer, P; Magee, E W; McLean, H S; Wood, R D

2009-12-01T23:59:59.000Z

187

Photoionization of the valence shells of the neutral tungsten atom  

E-Print Network [OSTI]

Results from large-scale theoretical cross section calculations for the total photoionization of the 4f, 5s, 5p and 6s orbitals of the neutral tungsten atom using the Dirac Coulomb R-matrix approximation (DARC: Dirac-Atomic R-matrix codes) are presented. Comparisons are made with previous theoretical methods and prior experimental measurements. In previous experiments a time-resolved dual laser approach was employed for the photo-absorption of metal vapours and photo-absorption measurements on tungsten in a solid, using synchrotron radiation. The lowest ground state level of neutral tungsten is $\\rm 5p^6 5d^4 6s^2 \\; {^5}D_{\\it J}$, with $\\it J$=0, and requires only a single dipole matrix for photoionization. To make a meaningful comparison with existing experimental measurements, we statistically average the large-scale theoretical PI cross sections from the levels associated with the ground state $\\rm 5p^6 5d^4 6s^2 \\; {^5}D_{\\it J}[{\\it J}=0,1,2,3,4]$ levels and the $\\rm 5d^56s \\; ^7S_3$ excited metastable...

Ballance, Connor P

2015-01-01T23:59:59.000Z

188

Synthesis, Crystal Structure, and Elastic Properties of Novel Tungsten Nitrides  

SciTech Connect (OSTI)

Among transition metal nitrides, tungsten nitrides possess unique and/or superior chemical, mechanical, and thermal properties. Preparation of these nitrides, however, is challenging because the incorporation of nitrogen into tungsten lattice is thermodynamically unfavorable at atmospheric pressure. To date, most materials in the W-N system are in the form of thin films produced by nonequilibrium processes and are often poorly crystallized, which severely limits their use in diverse technological applications. Here we report synthesis of tungsten nitrides through new approaches involving solid-state ion exchange and nitrogen degassing under pressure. We unveil a number of novel nitrides including hexagonal and rhombohedral W{sub 2}N{sub 3}. The final products are phase-pure and well-crystallized in bulk forms. For hexagonal W{sub 2}N{sub 3}, hexagonal WN, and cubic W3N4, they exhibit elastic properties rivaling or even exceeding cubic-BN. All four nitrides are prepared at a moderate pressure of 5 GPa, the lowest among high-pressure synthesis of transition metal nitrides, making it practically feasible for massive and industrial-scale production.

Wang, Shanmin; Yu, Xiaohui; Lin, Zhijun; Zhang, Ruifeng; He, Duanwei; Qin, Jiaqian; Zhu, Jinlong; Han, Jiantao; Wang, Lin; Mao, Ho-kwang; Zhang, Jianzhong; Zhao, Yusheng (UNLV); (Ehime U); (CIW); (Sichuan U.); (LANL)

2012-12-13T23:59:59.000Z

189

Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene  

DOE Patents [OSTI]

A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

Googin, J.M.; Napier, J.M.; Travaglini, M.A.

1982-03-31T23:59:59.000Z

190

Sensitivity of Tropospheric Chemical Composition to Halogen-Radical Chemistry Using a Fully Coupled Size-Resolved Multiphase Chemistry-Global Climate System: Halogen Distributions, Aerosol Composition, and Sensitivity of Climate-Relevant Gases  

SciTech Connect (OSTI)

Observations and model studies suggest a significant but highly non-linear role for halogens, primarily Cl and Br, in multiphase atmospheric processes relevant to tropospheric chemistry and composition, aerosol evolution, radiative transfer, weather, and climate. The sensitivity of global atmospheric chemistry to the production of marine aerosol and the associated activation and cycling of inorganic Cl and Br was tested using a size-resolved multiphase coupled chemistry/global climate model (National Center for Atmospheric Research’s Community Atmosphere Model (CAM); v3.6.33). Simulation results showed strong meridional and vertical gradients in Cl and Br species. The simulation reproduced most available observations with reasonable confidence permitting the formulation of potential mechanisms for several previously unexplained halogen phenomena including the enrichment of Br- in submicron aerosol, and the presence of a BrO maximum in the polar free troposphere. However, simulated total volatile Br mixing ratios were generally high in the troposphere. Br in the stratosphere was lower than observed due to the lack of long-lived organobromine species in the simulation. Comparing simulations using chemical mechanisms with and without reactive Cl and Br species demonstrated a significant temporal and spatial sensitivity of primary atmospheric oxidants (O3, HOx, NOx), CH4, and non-methane hydrocarbons (NMHC’s) to halogen cycling. Simulated O3 and NOx were globally lower (65% and 35%, respectively, less in the planetary boundary layer based on median values) in simulations that included halogens. Globally, little impact was seen in SO2 and non-sea-salt SO42- processing due to halogens. Significant regional differences were evident: The lifetime of nss-SO42- was extended downwind of large sources of SO2. The burden and lifetime of DMS (and its oxidation products) were lower by a factor of 5 in simulations that included halogens, versus those without, leading to a 20% reduction in nss-SO42- in the southern hemisphere planetary boundary layer based on median values.

Long, M.; Keene, W. C.; Easter, Richard C.; Sander, Rolf; Liu, Xiaohong; Kerkweg, A.; Erickson, D.

2014-04-07T23:59:59.000Z

191

Solid-State Halogen Atom Source for Chemical Dynamics and Etching. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSite CulturalDepartment2) 1/8Advanced MaterialsHalogen Atom Source

192

Deoxybenzoin-Based Polyarylates as Halogen-Free Fire-Resistant Kenneth A. Ellzey, T. Ranganathan, Joseph Zilberman, E. Bryan Coughlin,*  

E-Print Network [OSTI]

, processing, and engineering of halogen-free, low heat release, fire-resistant materials present important with high carbon monoxide emis- sion.7,8 Ideal flame-retardant polymers would possess high thermal stabilityDeoxybenzoin-Based Polyarylates as Halogen-Free Fire-Resistant Polymers Kenneth A. Ellzey, T

193

Process for the solvent extraction for the radiolysis and dehalogenation of halogenated organic compounds in soils, sludges, sediments and slurries  

DOE Patents [OSTI]

A process of extracting halogenated organic compounds, and particularly PCBs, from soil, sediment, slurry, sludge and dehalogenating the compounds contacts a contaminated soil sample with an extraction medium of a mixture of an alkane and a water miscible alcohol. The organic compounds dissolve in the extraction medium which is separated from the soil by passing water upwardly through the soil. The extraction medium floats to the surface of the water and is separated. Thereafter, the extraction medium containing the halogenated organic contaminants is subjected to ionizing radiation to radiolytically dehalogenate the compounds.

Mincher, Bruce J.; Curry, Randy Dale; Clevenger, Thomas E.; Golden, Jeffry

2003-05-27T23:59:59.000Z

194

Process for the solvent extraction for the radiolysis and dehalogenation of halogenated organic compounds in soils, sludges, sediments and slurries  

DOE Patents [OSTI]

A process of extracting halogenated organic compounds, and particularly PCBs, from soil, sediment, slurry, sludge and dehalogenating the compounds contacts a contaminated soil sample with an extraction medium of a mixture of an alkane and a water miscible alcohol. The organic compounds dissolve in the extraction medium which is separated from the soil by passing water upwardly through the soil. The extraction medium floats to the surface of the water and is separated. Thereafter, the extraction medium containing the halogenated organic contaminants is subjected to ionizing radiation to radiolytically dehalogenate the compounds.

Golden, Jeffry

2007-02-13T23:59:59.000Z

195

Process for the solvent extraction for the radiolysis and dehalogenation of halogenated organic compounds in soils, sludges, sediments and slurries  

DOE Patents [OSTI]

A process of extracting halogenated organic compounds, and particularly PCBs, from soil, sediment, slurry, sludge and dehalogenating the compounds contacting a contaminated soil sample with an extraction medium of a mixture of an alkane and a water miscible alcohol. The organic compounds dissolve in the extraction medium which is separated from the soil by passing water upwardly through the soil. The extraction medium floats to the surface of the water and is separated. Thereafter, the extraction medium containing the halogenated organic contaminants is subjected to ionizing radiation to radiolytically dehalogenate the compounds.

Mincher, Bruce J. (3705 Creekside Dr., Idaho Falls, ID 83404); Curry, Randy Dale (1104 Merrill Ct., Columbia, MO 65203); Clevenger, Thomas E. (2512 Bluff Blvd., Columbia, MO 65201); Golden, Jeffry (12612 Cedarbrook La., Laurel, MD 20708)

2000-01-01T23:59:59.000Z

196

Systematic studies of the nucleation and growth of ultrananocrystalline diamond films on silicon substrates coated with a tungsten layer  

SciTech Connect (OSTI)

We report on effects of a tungsten layer deposited on silicon surface on the effectiveness for diamond nanoparticles to be seeded for the deposition of ultrananocrystalline diamond (UNCD). Rough tungsten surface and electrostatic forces between nanodiamond seeds and the tungsten surface layer help to improve the adhesion of nanodiamond seeds on the tungsten surface. The seeding density on tungsten coated silicon thus increases. Tungsten carbide is formed by reactions of the tungsten layer with carbon containing plasma species. It provides favorable (001) crystal planes for the nucleation of (111) crystal planes by Microwave Plasma Enhanced Chemical Vapor Deposition (MPECVD) in argon diluted methane plasma and further improves the density of diamond seeds/nuclei. UNCD films grown at different gas pressures on tungsten coated silicon which is pre-seeded by nanodiamond along with heteroepitaxially nucleated diamond nuclei were characterized by Raman scattering, field emission-scanning electron microscopy, and high resolution-transmission electron microscopy.

Chu, Yueh-Chieh; Jiang, Gerald [Institute of Microelectronics, No.1, University Road, Tainan 701, Taiwan (China); Tu, Chia-Hao [Institute of Nanotechnology and Microsystems Engineering, No.1, University Road, Tainan 701, Taiwan (China); Department of Materials Science and Engineering, National Cheng Kung University, No.1, University Road, Tainan 701, Taiwan (China); Chang Chi [Institute of Nanotechnology and Microsystems Engineering, No.1, University Road, Tainan 701, Taiwan (China); Liu, Chuan-pu; Ting, Jyh-Ming [Department of Materials Science and Engineering, National Cheng Kung University, No.1, University Road, Tainan 701, Taiwan (China); Lee, Hsin-Li [Industrial Technology Research Institute - South, Tainan 701, Taiwan (China); Tzeng, Yonhua [Institute of Microelectronics, No.1, University Road, Tainan 701, Taiwan (China); Advanced Optoelectronics Technology Center, No.1, University Road, Tainan 701, Taiwan (China); Auciello, Orlando [Argonne National Laboratory, Materials Science Division, 9700 S. Cass Avenue, Argonne, Illinois 60439 (United States)

2012-06-15T23:59:59.000Z

197

Nmr Study of Thiocarbonyl Derivatives of Fe and Mn were made with solutions of the tungsten and molybdenum species  

E-Print Network [OSTI]

Nmr Study of Thiocarbonyl Derivatives of Fe and Mn were made with solutions of the tungsten.g.. the tungsten ion readily oxidizes in aqueous acid [A. Samotus and B. Kosowicz-Czajkowska, Rocz. Chem., 45, 1623

Bodner, George M.

198

Comparison of QM-Only and QM/MM Models for the Mechanism of Tungsten-Dependent Acetylene Hydratase  

E-Print Network [OSTI]

Comparison of QM-Only and QM/MM Models for the Mechanism of Tungsten-Dependent Acetylene Hydratase study on the formation of vinyl alcohol in the catalytic cycle of tungsten-dependent acetylene hydratase

Liao, Rongzhen

199

Bulk Tungsten in the JET Divertor: Potential Influence of the Exhaustion of Ductility and Grain Growth on the Lifetime  

E-Print Network [OSTI]

Bulk Tungsten in the JET Divertor: Potential Influence of the Exhaustion of Ductility and Grain Growth on the Lifetime

200

The Structure of the Tungsten Coatings Deposited by Combined Magnetron Sputtering and Ion Implantation for Nuclear Fusion Applications  

E-Print Network [OSTI]

The Structure of the Tungsten Coatings Deposited by Combined Magnetron Sputtering and Ion Implantation for Nuclear Fusion Applications

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

3-D Finite Element Electromagnetic and Stress Analyses of the JET LB-SRP Divertor Element (Tungsten Lamella Design)  

E-Print Network [OSTI]

3-D Finite Element Electromagnetic and Stress Analyses of the JET LB-SRP Divertor Element (Tungsten Lamella Design)

202

Theoretical Description of Heavy Impurity Transport and its Application to the Modelling of Tungsten in JET and ASDEX Upgrade  

E-Print Network [OSTI]

Theoretical Description of Heavy Impurity Transport and its Application to the Modelling of Tungsten in JET and ASDEX Upgrade

203

Shower characteristics of particles with momenta from up to 100 GeV in the CALICE Scintillator-Tungsten HCAL  

E-Print Network [OSTI]

Shower characteristics of particles with momenta from up to 100 GeV in the CALICE Scintillator-Tungsten HCAL

Klempt W

2015-01-01T23:59:59.000Z

204

Clamping of Solid Tungsten Components for the Bulk W Divertor Row in JET – Precautionary Design for a Brittle Material  

E-Print Network [OSTI]

Clamping of Solid Tungsten Components for the Bulk W Divertor Row in JET – Precautionary Design for a Brittle Material

205

Soft X-Ray Tomographic Reconstruction of JET ILW Plasmas with Tungsten Impurity and Different Spectral Response of Detectors  

E-Print Network [OSTI]

Soft X-Ray Tomographic Reconstruction of JET ILW Plasmas with Tungsten Impurity and Different Spectral Response of Detectors

206

Power Handling of the Bulk Tungsten Divertor Row at JET: First Measurements and Comparison to the GTM Thermal Model  

E-Print Network [OSTI]

Power Handling of the Bulk Tungsten Divertor Row at JET: First Measurements and Comparison to the GTM Thermal Model

207

Positron-production Experiment In Tungsten Crystal Using 4 And 8-gev Channeling Electrons At The Kekb Injector Linac  

E-Print Network [OSTI]

Positron-production Experiment In Tungsten Crystal Using 4 And 8-gev Channeling Electrons At The Kekb Injector Linac

Suwada, T; Chehab, R; Enomoto, A; Furukawa, K; Kakihara, K; Kamitani, T; Ogawa, Y; Ohsawa, S; Okuno, H; Oogoe, T; Fujita, T; Umemori, K; Yoshida, K; Ababiy, V; Potylitsin, A P; Vnukov, I E; Hamatsu, R; Sasahara, K

2002-01-01T23:59:59.000Z

208

Positron-production Experiment By 8-gev Channeling Electrons In Crystal Tungsten At The Kekb Injector Linac  

E-Print Network [OSTI]

Positron-production Experiment By 8-gev Channeling Electrons In Crystal Tungsten At The Kekb Injector Linac

Suwada, T

2001-01-01T23:59:59.000Z

209

Conductive Polypyrrole/Tungsten Oxide Metacomposites with Negative Permittivity Jiahua Zhu,  

E-Print Network [OSTI]

) nanocomposites reinforced with tungsten oxide (WO3) nanoparticles (NPs) and nanorods (NRs) are fabricatedConductive Polypyrrole/Tungsten Oxide Metacomposites with Negative Permittivity Jiahua Zhu, Suying techniques to form PNCs. Therefore, synthesis techniques have been developed and optimized to incorporate

Guo, John Zhanhu

210

Tungsten as first wall material in the main chamber of ASDEX Upgrade  

E-Print Network [OSTI]

experiments are using carbon as plasma facing material. Due to the codepo- sition of tritium with carbon. The carbon tiles were shaped to reduce edge erosion and coated with 0 6 ¡ 1 5 µm tungsten by Plasma Arc-ray spectral region. The tungsten in- flux was determined using the intensity of a WI line at 400.8 nm. All

211

Nanostructured tungsten carbide catalysts for polymer electrolyte fuel cells X. G. Yanga  

E-Print Network [OSTI]

a possibility of replacing precious metal anode catalysts with transition metal compounds for hydrogen oxidation density of states of tungsten carbides resembles that of noble metal platinum.4,5 FundamentalNanostructured tungsten carbide catalysts for polymer electrolyte fuel cells X. G. Yanga and C. Y

212

Hydrogen interaction with point defects in tungsten K. Heinola, T. Ahlgren, K. Nordlund, and J. Keinonen  

E-Print Network [OSTI]

Hydrogen interaction with point defects in tungsten K. Heinola, T. Ahlgren, K. Nordlund, and J-principles calculations were used in determining the binding and trapping properties of hydrogen to point defects in tungsten. Hydrogen zero-point vibrations were taken into account. It was concluded that the monovacancy can

Nordlund, Kai

213

Review on the EFDA programme on tungsten materials technology and science M. Rieth a,  

E-Print Network [OSTI]

Review on the EFDA programme on tungsten materials technology and science M. Rieth a, , J design studies for helium cooled divertors utilize tungsten materials and alloys, mainly due structural as well as armor materials in combination with the necessary production and fab- rication

Nordlund, Kai

214

G.M. Wright, VLT Highlight, March 28, 2012 Growth of tungsten nano-tendrils in  

E-Print Network [OSTI]

1 G.M. Wright, VLT Highlight, March 28, 2012 Growth of tungsten nano-tendrils in the Alcator C morphology of a tungsten divertor modify into fuzz under Helium bombardment in ITER and reactors?! · Linear fragile nano-tendrils! · Increased unipolar arcing! · Likely higher net erosion and W dust production

215

Dynamics of femtosecond laser produced tungsten nanoparticle plumes S. S. Harilal,1  

E-Print Network [OSTI]

Dynamics of femtosecond laser produced tungsten nanoparticle plumes S. S. Harilal,1 N. Farid,1,2 A tungsten nanoparticle plumes in vacuum. Fast gated images showed distinct two components expansion features.1063/1.4833564] I. INTRODUCTION Nanoparticle production and application research is an area of significant

Harilal, S. S.

216

Heat of combustion of tantalum-tungsten oxide thermite composites  

SciTech Connect (OSTI)

The heat of combustion of two distinctly synthesized stoichiometric tantalum-tungsten oxide energetic composites was investigated by bomb calorimetry. One composite was synthesized using a sol-gel (SG) derived method in which micrometric-scale tantalum is immobilized in a tungsten oxide three-dimensional nanostructured network structure. The second energetic composite was made from the mixing of micrometric-scale tantalum and commercially available (CA) nanometric tungsten oxide powders. The energetic composites were consolidated using the spark plasma sintering (SPS) technique under a 300 MPa pressure and at temperatures of 25, 400, and 500 C. For samples consolidated at 25 C, the density of the CA composite is 61.65 {+-} 1.07% in comparison to 56.41 {+-} 1.19% for the SG derived composite. In contrast, the resulting densities of the SG composite are higher than the CA composite for samples consolidated at 400 and 500 C. The theoretical maximum density for the SG composite consolidated to 400 and 500 C are 81.30 {+-} 0.58% and 84.42 {+-} 0.62%, respectively. The theoretical maximum density of the CA composite consolidated to 400 and 500 C are 74.54 {+-} 0.80% and 77.90 {+-} 0.79%, respectively. X-ray diffraction analyses showed an increase of pre-reaction of the constituents with an increase in the consolidation temperature. The increase in pre-reaction results in lower stored energy content for samples consolidated to 400 and 500 C in comparison to samples consolidated at 25 C. (author)

Cervantes, Octavio G. [Physical and Life Sciences Directorate, Lawrence Livermore National Laboratory (United States); Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616 (United States); Kuntz, Joshua D.; Gash, Alexander E. [Physical and Life Sciences Directorate, Lawrence Livermore National Laboratory (United States); Munir, Zuhair A. [Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616 (United States)

2010-12-15T23:59:59.000Z

217

(Data in metric tons of tungsten content unless otherwise noted) Domestic Production and Use: A mine in California restarted operations and made its first shipment of tungsten  

E-Print Network [OSTI]

in the metalworking, mining, oil- and gas-drilling, and construction industries. The remaining tungsten was consumed inventory inventory for disposal FY 2007 FY 2007 Ferrotungsten 6 136 Metal powder 268 268 136 34 Ores

218

Dynamics of femtosecond laser produced tungsten nanoparticle plumes  

SciTech Connect (OSTI)

We investigated the expansion features of femtosecond laser generated tungsten nanoparticle plumes in vacuum. Fast gated images showed distinct two components expansion features, viz., plasma and nanoparticle plumes, separated by time of appearance. The persistence of plasma and nanoparticle plumes are ?500 ns and ?100 ?s, respectively, and propagating with velocities differed by 25 times. The estimated temperature of the nanoparticles showed a decreasing trend with increasing time and space. Compared to low-Z materials (e.g., Si), ultrafast laser ablation of high-Z materials like W provides significantly higher nanoparticle yield. A comparison between the nanoparticle plumes generated by W and Si is also discussed along with other metals.

Harilal, S. S.; Hassanein, A. [Center for Materials Under Extreme Environment, School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47907 (United States)] [Center for Materials Under Extreme Environment, School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47907 (United States); Farid, N. [Center for Materials Under Extreme Environment, School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47907 (United States) [Center for Materials Under Extreme Environment, School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47907 (United States); School of Physics and Optical Engineering, Dalian University of Technology, Dalian 116024 (China); Kozhevin, V. M. [Ioffe Physics Technical Institute, Russian Academy of Sciences, St. Petersburg 194021 (Russian Federation)] [Ioffe Physics Technical Institute, Russian Academy of Sciences, St. Petersburg 194021 (Russian Federation)

2013-11-28T23:59:59.000Z

219

Electrodeposited tungsten-nickel-boron: A replacement for hexavalent chromium  

SciTech Connect (OSTI)

Chromium, deposited from acidic solutions of its hexavalent ion, has been the rule for wear resistant, corrosion resistant coatings for many years. Although chromium coatings are durable, the plating process generates air emissions, effluent rinse waters, and process solutions that are toxic, suspected carcinogens, and a risk to human health and the environment. Tungsten-nickel-boron (W-Ni-B) alloy deposition is a potential substitute for hexavalent chrome. It has excellent wear, corrosion, and mechanical properties and also may be less of an environmental risk. This study examines the electroplating process and deposit properties of W-Ni-B and compares them with those of hexavalent chrome.

Steffani, C.; Meltzer, M.

1995-04-01T23:59:59.000Z

220

DOE - Office of Legacy Management -- Callite Tungsten Co - NJ 36  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou are here Home »Hill -Elmore - OHCallite Tungsten Co

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

X-ray diffraction study of the static strength of tungsten to 69 GPa Duanwei He* and Thomas S. Duffy  

E-Print Network [OSTI]

X-ray diffraction study of the static strength of tungsten to 69 GPa Duanwei He* and Thomas S of tungsten was determined under static high pressures to 69 GPa using x-ray diffraction techniques strength of tungsten increases with compression, reaching a value of 5.3 GPa at the highest pressure

Duffy, Thomas S.

222

TUNGSTEN AND HAFNIUM DISTRIBUTION IN CALCIUM-ALUMINUM INCLUSIONS (CAIs) FROM ALLENDE AND EFREMOVKA. M. Humayun1  

E-Print Network [OSTI]

TUNGSTEN AND HAFNIUM DISTRIBUTION IN CALCIUM-ALUMINUM INCLUSIONS (CAIs) FROM ALLENDE AND EFREMOVKA with, or even earlier than, metal from CAIs and chondrules [3]. Tungsten isotope compositions represent veins [5]. Tungsten mobility is cause for concern, but is not sufficient evidence against the Kleine et

Grossman, Lawrence

223

By Earle B. Amey Tungsten's unique high-temperature properties are beneficial The Office of the United States Trade Representative  

E-Print Network [OSTI]

of tungsten ore concentrates and products with that of 1994. Demand generally increased in the cemented from products under these tariffs. during 1995. During 1995, prices for tungsten concentrates, which had built from 1985). Major Domestic production data for tungsten were developed by the liquidation of both

224

ENHANCEMENT OF THE POSITRON INTENSITY BY A TUNGSTEN SINGLE-CRYSTAL TARGET AT THE KEKB INJECTOR LINAC  

E-Print Network [OSTI]

by these stimulating results, we proceeded to systematic studies on the positron-production efficiencies with tungstenENHANCEMENT OF THE POSITRON INTENSITY BY A TUNGSTEN SINGLE-CRYSTAL TARGET AT THE KEKB INJECTOR, Russia R. Chehab, IPNL, IN2P3-CNRS, Universite Claude Bernald 1, France Abstract A new tungsten single

Paris-Sud XI, Université de

225

Electronic and structural properties of ultrathin tungsten nanowires and nanotubes by density functional theory calculation  

SciTech Connect (OSTI)

The simulated annealing basin-hopping method incorporating the penalty function was used to predict the lowest-energy structures for ultrathin tungsten nanowires and nanotubes of different sizes. These predicted structures indicate that tungsten one-dimensional structures at this small scale do not possess B.C.C. configuration as in bulk tungsten material. In order to analyze the relationship between multi-shell geometries and electronic transfer, the electronic and structural properties of tungsten wires and tubes including partial density of state and band structures which were determined and analyzed by quantum chemistry calculations. In addition, in order to understand the application feasibility of these nanowires and tubes on nano-devices such as field emitters or chemical catalysts, the electronic stability of these ultrathin tungsten nanowires was also investigated by density functional theory calculations.

Sun, Shih-Jye [Department of Applied Physics, National University of Kaohsiung, Kaohsiung 811, Taiwan (China); Lin, Ken-Huang; Li, Jia-Yun [Department of Mechanical and Electro-Mechanical Engineering, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China); Ju, Shin-Pon, E-mail: jushin-pon@mail.nsysu.edu.tw [Department of Mechanical and Electro-Mechanical Engineering, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China); Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 807, Taiwan (China)

2014-10-07T23:59:59.000Z

226

Atomic data of tungsten for current and future uses in fusion and plasma science  

SciTech Connect (OSTI)

Atomic physics has played an important role throughout the history of experimental plasma physics. For example, accurate knowledge of atomic properties has been crucial for understanding the plasma energy balance and for diagnostic development. With the shift in magnetic fusion research toward high-temperature burning plasmas like those expected to be produced in the ITER tokamak, the atomic physics of tungsten has become important. Tungsten will be a constituent of ITER plasmas because of its use as a plasma-facing material able to withstand high heat loads with lower tritium retention than other possible materials. Already, ITER diagnostics are being developed based on using tungsten radiation. In particular, the ITER Core Imaging X-ray Spectrometer (CIXS), which is designed to measure the core ion temperature and bulk plasma motion, is being based on the x-ray emission of neonlike tungsten ions (W{sup 64+}). In addition, tungsten emission will at ITER be measured by extreme ultraviolet (EUV) and optical spectrometers to determine its concentration in the plasma and to assess power loss and tungsten sputtering rates. On present-day tokamaks tungsten measurements are therefore being performed in preparation of ITER. Tungsten has very complex spectra and most are still unknown. The WOLFRAM project at Livermore aims to produce data for tungsten in various spectral bands: Lshell x-ray emission for CIXS development, soft x-ray and EUV M- and N-shell tungsten emission for understanding the edge radiation from ITER plasmas as well as from contemporary tokamaks, and O-shell emission for developing spectral diagnostics of the ITER divertor.

Clementson, J.; Beiersdorfer, P. [Physics Division, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, CA 94551 (United States); Lennartsson, T. [Lund Observatory, Lund University, P.O. Box 43, SE-221 00 Lund (Sweden)

2013-04-19T23:59:59.000Z

227

Introduction The Fiber-Lite MI-150 is a 150 Watt quartz halogen fiber optic illuminator designed for general microscopy  

E-Print Network [OSTI]

Introduction ® The Fiber-Lite MI-150 is a 150 Watt quartz halogen fiber optic illuminator designed for general microscopy use. When used with specialty fiber optic cables the MI-150 illuminator can also Illuminator from the carton and retain the manual and any additional documents. ! Remove the fiber optic cable

Kleinfeld, David

228

A Glove Box Enclosed Gas-Tungsten Arc Welding System  

SciTech Connect (OSTI)

This report describes an inert atmosphere enclosed gas-tungsten arc welding system which has been assembled in support of the MC2730, MC2730A and MC 3500 Radioisotope Thermoelectric Generator (RTG) Enhanced Surveillance Program. One goal of this program is to fabricate welds with microstructures and impurity levels which are similar to production heat source welds previously produced at Los Alamos National Laboratory and the Mound Facility. These welds will subsequently be used for high temperature creep testing as part of the overall component lifetime assessment. In order to maximize the utility of the welding system, means for local control of the arc atmosphere have been incorporated and a wide range of welding environments can easily be evaluated. The gas-tungsten arc welding system used in the assembly is computer controlled, includes two-axis and rotary motion, and can be operated in either continuous or pulsed modes. The system can therefore be used for detailed research studies of welding impurity effects, development of prototype weld schedules, or to mimic a significant range of production-like welding conditions. Fixturing for fabrication of high temperature creep test samples have been designed and constructed, and weld schedules for grip-tab and test welds have been developed. The microstructure of these welds have been evaluated and are consistent with those used during RTG production.

Reevr, E, M; Robino, C.V.

1999-07-01T23:59:59.000Z

229

Characterization of tungsten films and their hydrogen permeability  

SciTech Connect (OSTI)

Prediction of tritium migration and its retention within fusion reactors is uncertain due to a significant role of the structural disorder that is formed on the surface layer after plasma exposure. Tungsten films deposited by any of the suitable methods are always disordered and contain a high density of hydrogen traps. Experiments on such films with hydrogen isotopes present a suitable complementary method, which improves the picture of the hydrogen interaction with fusion relevant materials. The authors report on the morphology, composition, and structure of tungsten films deposited by the thermionic vacuum arc method on highly permeable Eurofer substrates. Subsequently, hydrogen permeation studies through these films were carried out in a wide pressure range from 20 to 1000 mbars at 400?°C. The final value of the permeation coefficient for four samples after 24?h at 400?°C was between P?=?3.2?×?10{sup ?14}?mol?H{sub 2}/(m?s?Pa{sup 0.5}) and P?=?1.1?×?10{sup ?15}?mol H{sub 2}/(m s Pa{sup 0.5}). From the time evolution of the permeation flux, it was shown that diffusivity was responsible for the difference in the steady fluxes, as solubility was roughly the same. This is confirmed by XRD data taken on these samples.

Nemani?, Vincenc, E-mail: vincenc.nemanic@ijs.si; Kova?, Janez [Jozef Stefan Institute, Jamova cesta 39, 1000 Ljubljana (Slovenia); Lungu, Cristian; Porosnicu, Corneliu [National Institute for Laser, Plasma and Radiation Physics, NILPRP, Magurele, Bucharest 077125 (Romania); Zajec, Bojan [Slovenian National Building and Civil Engineering Institute, Dimi?eva 12, 1000 Ljubljana (Slovenia)

2014-11-01T23:59:59.000Z

230

Chromatic instabilities in cesium-doped tungsten bronze nanoparticles  

SciTech Connect (OSTI)

Nanoparticles of alkali-doped tungsten bronzes are an excellent near-infrared shielding material, but exhibit slight chromatic instabilities typically upon applications of strong ultra-violet light or heating in humid environment, which acts detrimentally to long-life commercial applications. Origin of the chromatic instabilities in cesium-doped tungsten bronze has been investigated, and it has been found that the coloration and bleaching processes comprised electronic exchanges which accelerate or depress the polaron excitation and the localized surface plasmon resonance. Coloration on UV illumination is evidenced by electron diffraction as due to the formation of H{sub x}WO{sub 3}, which is considered to take place in the surface Cs-deficient WO{sub 3} region via the double charge injection mechanism. On the other hand, bleaching on heating in air and in humid environment is shown to accompany the extraction of Cs and electrons from Cs{sub 0.33}WO{sub 3} by X-ray photoelectron spectroscopy and X-ray diffraction analysis and is concluded to be an oxidation of Cs{sub 0.33}WO{sub 3} on the particle surface.

Adachi, Kenji, E-mail: kenji-adachi@ni.smm.co.jp; Ota, Yosuke; Tanaka, Hiroyuki; Okada, Mika; Oshimura, Nobumitsu; Tofuku, Atsushi [Ichikawa Research Laboratories, Sumitomo Metal Mining Co., Ltd., Ichikawa 272-8588 (Japan)

2013-11-21T23:59:59.000Z

231

Facile Synthesis of a Tungsten Alkylidyne Catalyst for Alkyne Zachary J. Tonzetich, Yan Choi Lam, Peter Muller, and Richard R. Schrock*  

E-Print Network [OSTI]

Facile Synthesis of a Tungsten Alkylidyne Catalyst for Alkyne Metathesis Zachary J. Tonzetich, Yan cis double bonds. Tungsten alkylidyne trialkoxide alkyne metathesis catalysts were discovered in 1981 of cleavage of a tungsten-tungsten triple bond upon reaction with an alkyne or nitrile.9 Recent advances

Müller, Peter

232

In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents  

DOE Patents [OSTI]

An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants are described. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating. 21 figs.

Taylor, R.T.; Jackson, K.J.; Duba, A.G.; Chen, C.I.

1998-05-19T23:59:59.000Z

233

In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents  

DOE Patents [OSTI]

An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating.

Taylor, Robert T. (Livermore, CA); Jackson, Kenneth J. (San Leandro, CA); Duba, Alfred G. (Livermore, CA); Chen, Ching-I (Danville, CA)

1998-01-01T23:59:59.000Z

234

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS: THE NEW X-WAND HVOC SCREENING DEVICE  

SciTech Connect (OSTI)

Western Research Institute (WRI) has developed new methodology and a test kit to screen soil or water samples for halogenated volatile organic compounds (HVOCs) in the field. The technology has been designated the X-Wand{trademark} screening tool. The new device uses a heated diode sensor that is commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. This sensor is selective to halogens. It does not respond to volatile aromatic hydrocarbons, such as those in gasoline, and it is not affected by high humidity. In the current work, the heated diode leak detectors were modified further to provide units with rapid response and enhanced sensitivity. The limit of detection for trichloroethylene TCE in air is 0.1 mg/m{sup 3} (S/N = 2). The response to other HVOCS relative to TCE is similar. Variability between sensors and changes in a particular sensor over time can be compensated for by normalizing sensor readings to a maximum sensor reading at 1,000 mg/m{sup 3} TCE. The soil TCE screening method was expanded to include application to water samples. Assuming complete vaporization, the detection limit for TCE in soil is about 1 ug/kg (ppb) for a 25-g sample in an 8-oz jar. The detection limit for TCE in water is about 1 ug/L (ppb) for a 25-mL sample in an 8-oz jar. This is comparable to quantitation limits of EPA GC/MS laboratory methods. A draft ASTM method for screening TCE contaminated soils using a heated diode sensor was successfully submitted for concurrent main committee and subcommittee balloting in ASTM Committee D 34 on Waste Management. The method was approved as ASTM D 7203-05, Standard Test Method for Screening Trichloroethylene (TCE)-Contaminated Soil Using a Heated Diode Sensor.

John F. Schabron; Susan S. Sorini; Joseph F. Rovani Jr

2006-03-01T23:59:59.000Z

235

The effect of phosphorus on the formation of tungsten dioxide: A novel morphology  

SciTech Connect (OSTI)

The industrial production of tungsten is based on the hydrogen reduction of tungsten oxides, ammonium paratungstate (APT) or ammonium tungsten oxide bronze (ATOB). Hydrogen reduction is applied when high purity tungsten is required and when the addition of other elements or compounds (dopants) is desired for modification of the properties of the metal powder. The first stage of the reduction is finished when WO{sub 2} is formed and it seems that the efficient incorporation of the additives starts mainly at this reduction step. The study reported here was undertaken to investigate the effect of phosphorus dope on the morphology of the intermediate tungsten dioxide and analyze its influence on the grain size of the final tungsten metal powder. The authors observed star shaped morphology of WO{sub 2}, a structure which has not been describe in the literature. Contrary to the well-known cauliflower shaped tungsten dioxide, these starlets are not pseudomorphic to the initial ATOB particles; they grow separately and have a great influence on the grain size of the final metal powder.

Hegedus, E.; Neugebauer, J. [Hungarian Academy of Sciences, Budapest (Hungary). Research Inst. for Technical Physics and Materials Science] [Hungarian Academy of Sciences, Budapest (Hungary). Research Inst. for Technical Physics and Materials Science

1999-02-19T23:59:59.000Z

236

Tunable carbon nanotube-tungsten carbide nanoparticles heterostructures by vapor deposition  

SciTech Connect (OSTI)

A simple, versatile route for the synthesis of carbon nanotube (CNT)-tungsten carbide nanoparticles heterostructures was set up via vapor deposition process. For the first time, amorphous CNTs (?-CNTs) were used to immobilized tungsten carbide nanoparticles. By adjusting the synthesis and annealing temperature, ?-CNTs/amorphous tungsten carbide, ?-CNTs/W{sub 2}C, and CNTs/W{sub 2}C/WC heterostructures were prepared. This approach provides an efficient method to attach other metal carbides and other nanoparticles to carbon nanotubes with tunable properties.

Xia, Min; Guo, Hongyan; Ge, Changchun [Institute of Special Ceramics and Powder Metallurgy, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing (China); Institute of Powder Metallurgy and Advanced Ceramics, Southwest Jiaotong University, 111, 1st Section, Northern 2nd Ring Road, Chengdu (China); Yan, Qingzhi, E-mail: qzyan@ustb.edu.cn; Lang, Shaoting [Institute of Special Ceramics and Powder Metallurgy, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing (China)

2014-05-14T23:59:59.000Z

237

Mechanisms of gas precipitation in plasma-exposed tungsten  

SciTech Connect (OSTI)

Precipitation in subsurface bubbles is a key process that governs how hydrogen isotopes migrate through and become trapped within plasma-exposed tungsten. We describe a continuum-scale model of hydrogen diffusion in plasma-exposed materials that includes the effects of precipitation. The model can account for bubble expansion via dislocation loop punching, using an accurate equation of state to determine the internal pressure. This information is used to predict amount of hydrogen trapped by bubbles, as well as the conditions where the bubbles become saturated. In an effort to validate the underlying assumptions, we compare our results with published positron annihilation and thermal desorption spectroscopy data, as well as our own measurements using the tritium plasma experiment (TPE).

R. D. Kolasinski; D. F. Cowgill; D. C. Donovan; M. Shimada

2012-05-01T23:59:59.000Z

238

Pico- and nanosecond laser ablation of mixed tungsten / aluminium films  

E-Print Network [OSTI]

In order to extend the investigation of laser-assisted cleaning of ITER-relevant first mirror materials to the picosecond regime, a commercial laser system delivering 10 picosecond pulses at 355 nm at a frequency of up to 1 MHz has been used to investigate the ablation of mixed aluminium (oxide) / tungsten (oxide) layers deposited on poly- and nanocrystalline molybdenum as well as nanocrystalline rhodium mirrors. Characterization before and after cleaning using scanning electron microscopy (SEM) and spectrophotometry shows heavy dust formation, resulting in a degradation of the reflectivity. Cleaning using a 5 nanosecond pulses at 350 and 532 nm, on the other hand, proved very promising. The structure of the film remnants suggests that in this case buckling was the underlying removal mechanism rather than ablation. Repeated coating and cleaning using nanosecond pulses is demonstrated.

Wisse, M; Steiner, R; Mathys, D; Stumpp, A; Joanny, M; Travere, J M; Meyer, E

2014-01-01T23:59:59.000Z

239

Determination of the electron–phonon coupling constant in tungsten  

SciTech Connect (OSTI)

We used two methods to determine the effective electron-phonon coupling constant (G{sub 0}) in tungsten. Our first principles calculations predict G{sub 0}?=?1.65?×?10{sup 17?}W m{sup ?3} K{sup ?1}. The temporal decay of the femtosecond-resolution optical reflectivity for a (100) surface of bulk W was measured using a pump-probe scheme and analysed using ab initio parameterised two temperature model, which includes both the effects of the electron-phonon coupling and thermal conduction into bulk. This analysis gives G{sub 0}?=?1.4(3)?×?10{sup 17?}W m{sup ?3} K{sup ?1}, in good agreement with the theoretical prediction. The described effective method of calculating and measuring G{sub 0} in bulk materials can be easily extended to other metals.

Daraszewicz, Szymon L.; Duffy, Dorothy M.; Shluger, Alexander L. [Department of Physics and Astronomy, London Centre for Nanotechnology, University College London, Gower Street, WC1E 6BT London (United Kingdom); Giret, Yvelin [Department of Physics and Astronomy, London Centre for Nanotechnology, University College London, Gower Street, WC1E 6BT London (United Kingdom); The Institute of Scientific and Industrial Research (ISIR), Osaka University, Mihogaoka 8-1, Ibaraki, Osaka 567-0047 (Japan); Tanimura, Hiroshi; Tanimura, Katsumi [The Institute of Scientific and Industrial Research (ISIR), Osaka University, Mihogaoka 8-1, Ibaraki, Osaka 567-0047 (Japan)

2014-07-14T23:59:59.000Z

240

Gamma Spectrum from Neutron Capture on Tungsten Isotopes  

SciTech Connect (OSTI)

An evaluation of thermal neutron capture on the stable tungsten isotopes is presented, with preliminary results for the compound systems 183;184;185;187W. The evaluation procedure compares the g-ray cross-section data collected at the Budapest reactor, with Monte Carlo simulations of g-ray emission following the thermal neutron-capture process. The statistical-decay code DICEBOX was used for the Monte Carlo simulations. The evaluation yields new gamma rays in 185W and the confirmation of spins in 187W, raising the number of levels below which the level schemes are considered complete, thus increasing the number of levels that can be used in neutron data libraries.

Hurst, Aaron; Summers, Neil; Sleaford, Brad; Firestone, Richard B; Belgya, T.; Revay, Z.S.

2010-04-29T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Tantalum-Tungsten Oxide Thermite Composite Prepared by Sol-Gel Synthesis and Spark Plasma Sintering  

SciTech Connect (OSTI)

Energetic composite powders consisting of sol-gel derived nanostructured tungsten oxide were produced with various amounts of micrometer-scale tantalum fuel metal. Such energetic composite powders were ignition tested and results show that the powders are not sensitive to friction, spark and/or impact ignition. Initial consolidation experiments, using the High Pressure Spark Plasma Sintering (HPSPS) technique, on the sol-gel derived nanostructured tungsten oxide produced samples with higher relative density than can be achieved with commercially available tungsten oxide. The sol-gel derived nanostructured tungsten oxide with immobilized tantalum fuel metal (Ta - WO{sub 3}) energetic composite was consolidated to a density of 9.17 g.cm{sup -3} or 93% relative density. In addition those parts were consolidated without significant pre-reaction of the constituents, thus the sample retained its stored chemical energy.

Cervantes, O; Kuntz, J; Gash, A; Munir, Z

2009-02-13T23:59:59.000Z

242

Simulation Studies of Hydrogen Ion reflection from Tungsten for the Surface Production of Negative Hydrogen Ions  

SciTech Connect (OSTI)

The production efficiency of negative ions at tungsten surface by particle reflection has been investigated. Angular distributions and energy spectra of reflected hydrogen ions from tungsten surface are calculated with a Monte Carlo simulation code ACAT. The results obtained with ACAT have indicated that angular distributions of reflected hydrogen ions show narrow distributions for low-energy incidence such as 50 eV, and energy spectra of reflected ions show sharp peaks around 90% of incident energy. These narrow angular distributions and sharp peaks are favorable for the efficient extraction of negative ions from an ion source equipped with tungsten surface as negative ionization converter. The retained hydrogen atoms in tungsten lead to the reduction in extraction efficiency due to boarded angular distributions.

Kenmotsu, Takahiro; Wada, Motoi [Doshisha University, Kyotanabe, Kyoto 610-0394 (Japan)

2011-09-26T23:59:59.000Z

243

Recent progress in R&D on tungsten alloys for divertor structural and plasma facing materials  

SciTech Connect (OSTI)

Tungsten materials are candidates for plasma facing components for ITER and DEMO because of their superior thermophysical properties. Knowledge and strategies to improve properties of tungsten-based materials are still under development, as they are not a common structural material such as steel. Consequently, several activities have started in Europe, Japan, USA and China. Research is directed towards manufacturing of new materials based on alloying, microstructure stabilizing and composite formation involving improved processing steps. Beside experimental analyses, work also focuses on computational treatment of open questions, supporting the development of better tungsten materials. Assuming the availability of an ideal material that is ready to use, there remain the questions of inherent safety, the joining of tungsten to steel and the influence of radiation damage. These are topics of increasing interest when the material comes to application.

Wurster, S.; Baluc, N.; Battabyal, M.; Crosby, T.; Du, J.; Garcia-Rosales, C.; Hasegawa, Akira; Hoffmann, A.; Kimura, A.; Kurishita, Hiroaki; Kurtz, Richard J.; Li, H.; Noh, S.; Reiser, J.; Riesch, J.; Rieth, Michael; Setyawan, Wahyu; Walter, M.; You, J. H.; Pippan, R.

2013-03-13T23:59:59.000Z

244

Tungsten bridge for the low energy ignition of explosive and energetic materials  

DOE Patents [OSTI]

A tungsten bridge device for the low energy ignition of explosive and energetic materials is disclosed. The device is fabricated on a silicon-on-sapphire substrate which has an insulating bridge element defined therein using standard integrated circuit fabrication techniques. Then, a thin layer of tungsten is selectively deposited on the silicon bridge layer using chemical vapor deposition techniques. Finally, conductive lands are deposited on each end of the tungsten bridge layer to form the device. It has been found that this device exhibits substantially shorter ignition times than standard metal bridges and foil igniting devices. In addition, substantially less energy is required to cause ignition of the tungsten bridge device of the present invention than is required for common metal bridges and foil devices used for the same purpose.

Benson, David A. (Albuquerque, NM); Bickes, Jr., Robert W. (Albuquerque, NM); Blewer, Robert S. (Albuquerque, NM)

1990-01-01T23:59:59.000Z

245

Tungsten bridge for the low energy ignition of explosive and energetic materials  

DOE Patents [OSTI]

A tungsten bridge device for the low energy ignition of explosive and energetic materials is disclosed. The device is fabricated on a silicon-on-sapphire substrate which has an insulating bridge element defined therein using standard integrated circuit fabrication techniques. Then, a thin layer of tungsten is selectively deposited on the silicon bridge layer using chemical vapor deposition techniques. Finally, conductive lands are deposited on each end of the tungsten bridge layer to form the device. It has been found that this device exhibits substantially shorter ignition times than standard metal bridges and foil igniting devices. In addition, substantially less energy is required to cause ignition of the tungsten bridge device of the present invention than is required for common metal bridges and foil devices used for the same purpose. 2 figs.

Benson, D.A.; Bickes, R.W. Jr.; Blewer, R.S.

1990-12-11T23:59:59.000Z

246

Electropolymerized Polyaniline Stabilized Tungsten Oxide Nanocomposite Films: Electrochromic Behavior and Electrochemical  

E-Print Network [OSTI]

Electropolymerized Polyaniline Stabilized Tungsten Oxide Nanocomposite Films: Electrochromic. The optical properties and electrochemical capacitive behaviors of the composite films for electrochromic (EC electrochromism at both positive and negative potentials arising from PANI and WO3, respectively. A coloration

Guo, John Zhanhu

247

Molecular dynamics simulation of deuterium trapping and bubble formation in tungsten  

E-Print Network [OSTI]

erosion rate [1]. In addition, tungsten is a high Z material, therefore the physical sputtering yield surface [5­7] or liquid lithium [8] has been recently studied, while others investigated the low energy

Harilal, S. S.

248

Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride as the Acid  

E-Print Network [OSTI]

Routes to new tungsten alkylidene complexes that contain tert-butylimido or adamantylimido ligands have been devised that begin with a reaction between WCl[subscript 6] and 4 equivalents of HNR(TMS) to give [W(NR)[subscript ...

Jeong, Hyangsoo

249

Method of producing tungsten-titanium sputter targets and targets produced thereby  

SciTech Connect (OSTI)

A method is described for preparing a tungsten-titanium sputter target having substantially no [beta](Ti,W) phase present and exhibiting improvement in reduction of particulate emission upon sputtering, comprising: (a) providing powders of said tungsten and titanium wherein said titanium powder is present in an amount of about 1-20 wt. % based on the total weight of said tungsten and titanium powders provided; (b) compacting said powders at a pressure of from about 200 to 1,000 MPa; and (c) heating said powders at a temperature from about 600-882 C. A method for preparing a tungsten-titanium sputtering target having substantially no [beta](Ti,W) phase present and exhibiting improvement in reduction of particulate emission upon sputtering.

Wickersham, C.E. Jr.; Mueller, J.J.

1993-08-10T23:59:59.000Z

250

Sintering and joining of low temperature co-fired tungsten and aluminum oxide  

E-Print Network [OSTI]

Conventional methods used to fabricate co-fired tungsten/alumina composites usually rely on high temperature processing (>1500C). As it would be beneficial or even necessary for some applications to produce such composites ...

Boonyongmaneerat, Yuttanant

2006-01-01T23:59:59.000Z

251

Multiphysics Design and Simulation of a Tungsten-Cermet Nuclear Thermal Rocket  

E-Print Network [OSTI]

fuel safety have sparked interest in an NTR core based on tungsten-cermet fuel. This work investigates the capability of modern CFD and neutronics codes to design a cermet NTR, and makes specific recommendations for the configuration of channels...

Appel, Bradley

2012-10-19T23:59:59.000Z

252

E-Print Network 3.0 - alkaline tungsten matrix Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to be easily resolved (P. Piccoli and B. Stuller). WDS map of tungsten in a titanite (CaTiSiO5) grain from... the Cathedral Peak Granodiorite, Yosemite National Park. The...

253

Molybdenum-copper and tungsten-copper alloys and method of making  

DOE Patents [OSTI]

Molybdenum-copper and tungsten-copper alloys are prepared by a consumable electrode method in which the electrode consists of a copper matrix with embedded strips of refractory molybdenum or tungsten. The electrode is progressively melted at its lower end with a superatmospheric inert gas pressure maintained around the liquifying electrode. The inert gas pressure is sufficiently above the vapor pressure of copper at the liquidus temperature of the alloy being formed to suppress boiling of liquid copper.

Schmidt, Frederick A. (Ames, IA); Verhoeven, John D. (Ames, IA); Gibson, Edwin D. (Ames, IA)

1989-05-23T23:59:59.000Z

254

Molybdenum-copper and tungsten-copper alloys and method of making  

DOE Patents [OSTI]

Molybdenum-copper and tungsten-copper alloys are prepared by a consumable electrode method in which the electrode consists of a copper matrix with embedded strips of refractory molybdenum or tungsten. The electrode is progressively melted at its lower end with a superatmospheric inert gas pressure maintained around the liquefying electrode. The inert gas pressure is sufficiently above the vapor pressure of copper at the liquidus temperature of the alloy being formed to suppress boiling of liquid copper. 6 figs.

Schmidt, F.A.; Verhoeven, J.D.; Gibson, E.D.

1989-05-23T23:59:59.000Z

255

Growth study and photocatalytic properties of Co-doped tungsten oxide mesocrystals  

SciTech Connect (OSTI)

Cobalt-doped tungsten oxide mesocrystals with different morphologies have been successfully generated using a solvothermal method with tungsten hexachloride and cobalt chloride salts as precursors. The resulting mesocrystals were characterized by X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, Brunauer-Emmet-Teller analysis of nitrogen sorptometer, and UV-vis diffuse reflectance spectroscopy. The photocatalytic properties of the cobalt-doped tungsten oxide mesocrystals were evaluated on the basis of their ability to degrade methyl orange in an aqueous solution under simulated sunlight irradiation. Results showed that the cobalt doping had obvious effect on the morphologies of the final products, and lenticular and blocky cobalt-doped tungsten oxide mesocrystals could be obtained with 1.0 wt.% and 2.0 wt.% cobalt doping, respectively. The cobalt-doped tungsten oxides exhibited superior photocatalytic activities to that of the undoped tungsten oxide. - Graphical abstract: Schematic illustrations of the growth of the bundled nanowires, lenticular mesocrystals, and blocky mesocrystals. Highlights: Black-Right-Pointing-Pointer Co-doped W{sub 18}O{sub 49} mesocrystals were synthesized using a solvothermal method. Black-Right-Pointing-Pointer The Co doping has obvious effect on the morphology of the final mesocrystals. Black-Right-Pointing-Pointer The Co-doped W{sub 18}O{sub 49} exhibited superior photocatalytic activity to the undoped W{sub 18}O{sub 49}.

Sun, Shibin [College of Logistics Engineering, Shanghai Maritime University, Shanghai 200135 (China) [College of Logistics Engineering, Shanghai Maritime University, Shanghai 200135 (China); College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061 (China); Chang, Xueting, E-mail: xuetingchang@yahoo.cn [College of Logistics Engineering, Shanghai Maritime University, Shanghai 200135 (China)] [College of Logistics Engineering, Shanghai Maritime University, Shanghai 200135 (China); Li, Zhenjiang [College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061 (China)] [College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061 (China)

2012-11-15T23:59:59.000Z

256

Study on the oxidation and reduction of tungsten surface for sub-50 nm patterning process  

SciTech Connect (OSTI)

The oxidation characteristics of tungsten line pattern during the carbon-based mask-layer removal process using oxygen plasmas have been investigated for sub-50 nm patterning processes, in addition to the reduction characteristics of the WO{sub x} layer formed on the tungsten line surface using hydrogen plasmas. The surface oxidation of tungsten lines during the mask layer removal process could be minimized by using low-temperature (300 K) plasma processing for the removal of the carbon-based material. Using this technique, the thickness of WO{sub x} on the tungsten line could be decreased to 25% compared to results from high-temperature processing. The WO{sub x} layer could also be completely removed at a low temperature of 300 K using a hydrogen plasma by supplying bias power to the tungsten substrate to provide a activation energy for the reduction. When this oxidation and reduction technique was applied to actual 40-nm-CD device processing, the complete removal of WO{sub x} formed on the sidewall of tungsten line could be observed.

Kim, Jong Kyu; Nam, Seok Woo; Cho, Sung Il; Jhon, Myung S.; Min, Kyung Suk; Kim, Chan Kyu; Jung, Ho Bum; Yeom, Geun Young [Memory Division Semiconductor Business, Samsung Electronics, San No. 16 Banwol-Ri, Taean-Eup, Hwasung-City, Gyeonggi-Do 449-711, South Korea and Department of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); Memory Division Semiconductor Business, Samsung Electronics, San No. 16 Banwol-Ri, Taean-Eup, Hwasung-City, Gyeonggi-Do 449-711 (Korea, Republic of); Department of Chemical Engineering and Data Storage Systems Center, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States); Department of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746 (Korea, Republic of)

2012-11-15T23:59:59.000Z

257

Synthesis and electrochemical capacitance of long tungsten oxide nanorod arrays grown vertically on substrate  

SciTech Connect (OSTI)

Highlights: ? Growth of long amorphous tungsten oxide nanorods on a substrate. ? Formation of single-crystalline tungsten oxide nanorods by a heat-treatment. ? High electrochemical pseudocapacitance of 2.8 mF cm{sup ?2}. ? Excellent cyclability of psuedocapacitance up to 1000 cycles. -- Abstract: Long tungsten oxide nanorods are vertically grown on Al/W/Ti coated silicon substrates using a two-step anodization process. The first anodization of the Al film forms a mesh-like mask of anodic aluminum oxide, and the second anodization of the W film results in the formation of a buffer layer, a bottom nanorod, and a top nanorod of amorphous tungsten oxide. A pore-widening process prior to the second anodization leads to the enhancement of nanorod length above approximately 500 nm. After a heat-treatment, the tungsten oxide nanorods are crystallized to form a single crystalline structure while the buffer layer forms a polycrystalline structure. The crystalline tungsten oxide nanorods show a cyclic voltammogram retaining the quasi-rectangular shape of an electrochemically reversible faradaic redox reaction, i.e., a typical pseudocapacitive behavior. The maximum electrochemical capacitance per apparent surface area reaches approximately 2.8 mF cm{sup ?2} at the voltage scan rate of 20 mV s{sup ?1}, and the excellent cyclability of charge–discharge process is maintained up to 1000 cycles.

Park, Sun Hwa [Department of Nanomaterials Science and Engineering, University of Science and Technology, Daejeon 305-350 (Korea, Republic of)] [Department of Nanomaterials Science and Engineering, University of Science and Technology, Daejeon 305-350 (Korea, Republic of); Kim, Young Heon; Lee, Tae Geol; Shon, Hyun Kyong [Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of)] [Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of); Park, Hyun Min [Department of Nanomaterials Science and Engineering, University of Science and Technology, Daejeon 305-350 (Korea, Republic of) [Department of Nanomaterials Science and Engineering, University of Science and Technology, Daejeon 305-350 (Korea, Republic of); Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of); Song, Jae Yong, E-mail: jysong@kriss.re.kr [Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of); Department of Nano Science, University of Science and Technology, Daejeon 305-350 (Korea, Republic of)

2012-11-15T23:59:59.000Z

258

Tungsten coating for improved wear resistance and reliability of microelectromechanical devices  

DOE Patents [OSTI]

A process is disclosed whereby a 5-50-nanometer-thick conformal tungsten coating can be formed over exposed semiconductor surfaces (e.g. silicon, germanium or silicon carbide) within a microelectromechanical (MEM) device for improved wear resistance and reliability. The tungsten coating is formed after cleaning the semiconductor surfaces to remove any organic material and oxide film from the surface. A final in situ cleaning step is performed by heating a substrate containing the MEM device to a temperature in the range of 200-600 .degree. C. in the presence of gaseous nitrogen trifluoride (NF.sub.3). The tungsten coating can then be formed by a chemical reaction between the semiconductor surfaces and tungsten hexafluoride (WF.sub.6) at an elevated temperature, preferably about 450.degree. C. The tungsten deposition process is self-limiting and covers all exposed semiconductor surfaces including surfaces in close contact. The present invention can be applied to many different types of MEM devices including microrelays, micromirrors and microengines. Additionally, the tungsten wear-resistant coating of the present invention can be used to enhance the hardness, wear resistance, electrical conductivity, optical reflectivity and chemical inertness of one or more semiconductor surfaces within a MEM device.

Fleming, James G. (Albuquerque, NM); Mani, Seethambal S. (Albuquerque, NM); Sniegowski, Jeffry J. (Edgewood, NM); Blewer, Robert S. (Albuquerque, NM)

2001-01-01T23:59:59.000Z

259

Oxidation and Volatilization from Tungsten Brush High Heat Flux Armor During High Temperature Steam Exposure  

SciTech Connect (OSTI)

Tungsten brush accommodates thermal stresses and high heat flux in fusion reactor components such as plasma facing surfaces or armor. However, inherently higher surface areas are introduced with the brush design. We have tested a specific design of tungsten brush in steam between 500 and 1100°C. Hydrogen generation and tungsten volatilization rates were determined to address fusion safety issues. The brush prepared from 3.2-mm diameter welding rods had a packing density of 85 percent. We found that both hydrogen generation and tungsten volatilization from brush, fixtured to represent a unit within a larger component, were less than projections based upon the total integrated surface area (TSA). Steam access and the escape of hydrogen and volatile oxide from void spaces within the brush are restricted compared to specimens with more direct diffusion pathways to the test environment. Hydrogen generation rates from restrained specimens based on normal surface area (NSA) remain about five times higher than rates based on total surface areas from specimens with direct steam access. Volatilization rates from restrained specimens based upon normal surface area (NSA) were only 50 percent higher than our historic cumulative maximum flux plot (CMFP) for tungsten. This study has shown that hydrogen generation and tungsten volatilization from brush do not scale according to predictions with previously determined rates, but in fact, with higher packing density could approach those from flat surfaces.

Smolik, Galen Richard; Pawelko, Robert James; Anderl, Robert Andrew; Petti, David Andrew

2000-05-01T23:59:59.000Z

260

B(C6F5)3 Activation of Oxo Tungsten Complexes That Are Relevant to Olefin Metathesis  

E-Print Network [OSTI]

B(C6F5)3 Activation of Oxo Tungsten Complexes That Are Relevant to Olefin Metathesis Dmitry V Information ABSTRACT: We have found that coordination of B(C6F5)3 to an oxo ligand in tungsten oxo alkylidene reactions between a relatively well behaved Lewis acid (B(C6F5)3) and a variety of tungsten oxo complexes

Müller, Peter

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Reduced ternary molybdenum and tungsten sulfides and hydroprocessing catalysis therewith  

DOE Patents [OSTI]

New amorphous molybdenum/tungsten sulfides with the general formula M{sup n+}{sub 2x/n}(L{sub 6}S{sub 8})S{sub x}, where L is molybdenum or tungsten and M is a ternary metal, has been developed. Characterization of these amorphous materials by chemical and spectroscopic methods (IR, Raman, PES) shows that the (M{sub 6}S{sub 8}){sup 0} cluster units are present. Vacuum thermolysis of the amorphous Na{sub 2x}(Mo{sub 6}S{sub 8})S{sub x}{hor_ellipsis}yMeOH first produces poorly crystalline NaMo{sub 6}S{sub 8} by disproportionation at 800 C and well-crystallized NaMo{sub 6}S{sub 8} at {>=} 900 C. Ion-exchange of the sodium material in methanol with soluble M{sup 2+} and M{sup 3+} salts (M=Sn, Co, Ni, Pb, La, Ho) produces the M{sup n+}{sub 2x/n}(Mo{sub 6}S{sub 8})S{sub x}{hor_ellipsis}yMeOH compounds. Additionally, the new reduced ternary molybdenum sulfides with the general formula M{sup n+}{sub 2x/n}Mo{sub 6}S{sub 8+x}(MeOH){sub y}[MMOS] (M=Sn, Co, Ni) is an effective hydrodesulfurization (HDS) catalyst both as-prepared and after a variety of pretreatment conditions. Under specified pretreatment conditions with flowing hydrogen gas, the SnMoS type catalyst can be stabilized, and while still amorphous, can be considered as ``Chevrel phase-like`` in that both contain Mo{sub 6}S{sub 8} cluster units. Furthermore, the small cation NiMoS and CoMoS type pretreated catalyst is shown to be very active HDS catalysts with rates that exceeded the model unpromoted and cobalt-promoted MoS{sub 2} catalysts. 9 figs.

Hilsenbeck, S.J.; McCarley, R.E.; Schrader, G.L.; Xie, X.B.

1999-02-16T23:59:59.000Z

262

Reduced ternary molybdenum and tungsten sulfides and hydroprocessing catalysis therewith  

DOE Patents [OSTI]

New amorphous molybdenum/tungsten sulfides with the general formula M.sup.n+.sub.2x/n (L.sub.6 S.sub.8)S.sub.x, where L is molybdenum or tungsten and M is a ternary metal, has been developed. Characterization of these amorphous materials by chemical and spectroscopic methods (IR, Raman, PES) shows that the (M.sub.6 S.sub.8).sup.0 cluster units are present. Vacuum thermolysis of the amorphous Na.sub.2x (Mo.sub.6 S.sub.8)S.sub.x .multidot.yMeOH first produces poorly crystalline NaMo.sub.6 S.sub.8 by disproportionation at 800.degree. C. and well-crystallized NaMo.sub.6 S.sub.8 at .gtoreq. 900.degree. C. Ion-exchange of the sodium material in methanol with soluble M.sup.2+ and M.sup.3+ salts (M=Sn, Co, Ni, Pb, La, Ho) produces the M.sup.n+.sub.2x/n (Mo.sub.6 S.sub.8)S.sub.x .multidot.yMeOH compounds. Additionally, the new reduced ternary molybdenum sulfides with the general formula M.sup.n+.sub.2x/n Mo.sub.6 S.sub.8+x (MeOH).sub.y ›MMOS! (M=Sn, Co, Ni) is an effective hydrodesulfurization (HDS) catalyst both as-prepared and after a variety of pretreatment conditions. Under specified pretreatment conditions with flowing hydrogen gas, the SnMoS type catalyst can be stabilized, and while still amorphous, can be considered as "Chevrel phase-like" in that both contain Mo.sub.6 S.sub.8 cluster units. Furthermore, the small cation NiMoS and CoMoS type pretreated catalyst showed to be very active HDS catalysts with rates that exceeded the model unpromoted and cobalt-promoted MoS.sub.2 catalysts.

Hilsenbeck, Shane J. (Ames, IA); McCarley, Robert E. (Ames, IA); Schrader, Glenn L. (Ames, IA); Xie, Xiaobing (College Station, TX)

1999-02-16T23:59:59.000Z

263

Development of an electron-temperature-dependent interatomic potential for molecular dynamics simulation of tungsten under electronic excitation  

E-Print Network [OSTI]

simulation of tungsten under electronic excitation S. Khakshouri,1,* D. Alfè,1,2 and D. M. Duffy1,3 1

Alfè, Dario

264

Magnetization curves of sintered heavy tungsten alloys for applications in MRI-guided radiotherapy  

SciTech Connect (OSTI)

Purpose: Due to the current interest in MRI-guided radiotherapy, the magnetic properties of the materials commonly used in radiotherapy are becoming increasingly important. In this paper, measurement results for the magnetization (BH) curves of a range of sintered heavy tungsten alloys used in radiation shielding and collimation are presented. Methods: Sintered heavy tungsten alloys typically contain >90?% tungsten and <10?% of a combination of iron, nickel, and copper binders. Samples of eight different grades of sintered heavy tungsten alloys with varying binder content were investigated. Using a superconducting quantum interference detector magnetometer, the induced magnetic momentm was measured for each sample as a function of applied external field H{sub 0} and the BH curve derived. Results: The iron content of the alloys was found to play a dominant role, directly influencing the magnetizationM and thus the nonlinearity of the BH curve. Generally, the saturation magnetization increased with increasing iron content of the alloy. Furthermore, no measurable magnetization was found for all alloys without iron content, despite containing up to 6% of nickel. For two samples from different manufacturers but with identical quoted nominal elemental composition (95% W, 3.5% Ni, 1.5% Fe), a relative difference in the magnetization of 11%–16% was measured. Conclusions: The measured curves show that the magnetic properties of sintered heavy tungsten alloys strongly depend on the iron content, whereas the addition of nickel in the absence of iron led to no measurable effect. Since a difference in the BH curves for two samples with identical quoted nominal composition from different manufacturers was observed, measuring of the BH curve for each individual batch of heavy tungsten alloys is advisable whenever accurate knowledge of the magnetic properties is crucial. The obtained BH curves can be used in FEM simulations to predict the magnetic impact of sintered heavy tungsten alloys.

Kolling, Stefan [Sydney Medical School, University of Sydney, NSW 2006 (Australia)] [Sydney Medical School, University of Sydney, NSW 2006 (Australia); Oborn, Bradley M. [Illawarra Cancer Care Centre (ICCC), Wollongong, NSW 2500, Australia and Centre for Medical Radiation Physics (CMRP), University of Wollongong, Wollongong, NSW 2500 (Australia)] [Illawarra Cancer Care Centre (ICCC), Wollongong, NSW 2500, Australia and Centre for Medical Radiation Physics (CMRP), University of Wollongong, Wollongong, NSW 2500 (Australia); Keall, Paul J., E-mail: paul.keall@sydney.edu.au [Sydney Medical School, University of Sydney, NSW 2006, Australia and Ingham Institute for Applied Medical Research, Liverpool, NSW 2170 (Australia); Horvat, Joseph [Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong, NSW 2500, Australia and School of Physics, University of Wollongong, Wollongong, NSW 2500 (Australia)] [Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong, NSW 2500, Australia and School of Physics, University of Wollongong, Wollongong, NSW 2500 (Australia)

2014-06-15T23:59:59.000Z

265

Adsorption of carbonyl sulfide on nickel and tungsten films  

SciTech Connect (OSTI)

The interaction of carbonyl sulfide with evaporated nickel and tungsten films has been investigated in the temperature range 195-450 K using gas pressures ranging from 1 to 13 N m/sup -2/. Rapid but mainly associative chemisorption of COS occurred on both metals at 195 K. Further adsorption of COS on W at temperatures 293-450 K was extremely slow and accompanied by more CO desorption than COS adsorbed. Sulfidation of Ni film by COS occurred at temperatures greater than or equal to 293 K with the liberation of carbon monoxide. The rate of adsorption increased with temperature but was independent of COS pressure. The activation energy (E/sub x/) increased with extent (X) of sulfidation to a limiting value of 97 kJ mol/sup -1/. A linear relationship was obtained from the plot of E/sub x/ against 1/X, suggesting the applicability of Cabrera-Mott theory to the sulfidation of Ni film by COS. 20 references, 2 figures, 1 table.

Saleh, J.M.; Nasser, F.A.K.

1985-07-18T23:59:59.000Z

266

DISPLACEMENT CASCADE SIMULATION IN TUNGSTEN AT 1025 K  

SciTech Connect (OSTI)

Molecular dynamics simulation was employed to investigate the irradiation damage properties of bulk tungsten at 1025 K (0.25 melting temperature). A comprehensive data set of primary cascade damage was generated up to primary knock-on atom (PKA) energies 100 keV. The dependence of the number of surviving Frenkel pairs (NFP) on the PKA energy (E) exhibits three different characteristic domains presumably related to the different cascade morphologies that form. The low-energy regime < 0.2 keV is characterized by a hit-or-miss type of Frenkel pair (FP) production near the displacement threshold energy of 128 eV. The middle regime 0.3 – 30 keV exhibits a sublinear dependence of log(NFP) vs log(E) associated with compact cascade morphology with a slope of 0.73. Above 30 keV, the cascade morphology consists of complex branches or interconnected damage regions. In this extended morphology, large interstitial clusters form from superposition of interstitials from nearby damage regions. Strong clustering above 30 keV results in a superlinear dependence of log(NFP) vs log(E) with a slope of 1.365. At 100 keV, an interstitial cluster of size 92 and a vacancy cluster of size 114 were observed.

Setyawan, Wahyu; Nandipati, Giridhar; Roche, Kenneth J.; Heinisch, Howard L.; Kurtz, Richard J.; Wirth, Brian D.

2013-09-30T23:59:59.000Z

267

Activation Energy of Tantalum-Tungsten Oxide Thermite Reaction  

SciTech Connect (OSTI)

The activation energy of a high melting temperature sol-gel (SG) derived tantalum-tungsten oxide thermite composite was determined using the Kissinger isoconversion method. The SG derived powder was consolidated using the High Pressure Spark Plasma Sintering (HPSPS) technique to 300 and 400 C to produce pellets with dimensions of 5 mm diameter by 1.5 mm height. A custom built ignition setup was developed to measure ignition temperatures at high heating rates (500-2000 C {center_dot} min{sup -1}). Such heating rates were required in order to ignite the thermite composite. Unlike the 400 C samples, results show that the samples consolidated to 300 C undergo an abrupt change in temperature response prior to ignition. This change in temperature response has been attributed to the crystallization of the amorphous WO{sub 3} in the SG derived Ta-WO{sub 3} thermite composite and not to a pre-ignition reaction between the constituents. Ignition temperatures for the Ta-WO{sub 3} thermite ranged from approximately 465-670 C. The activation energy of the SG derived Ta-WO{sup 3} thermite composite consolidated to 300 and 400 C were determined to be 37.787 {+-} 1.58 kJ {center_dot} mol{sup -1} and 57.381 {+-} 2.26 kJ {center_dot} mol{sup -1}, respectively.

Cervantes, O; Kuntz, J; Gash, A; Munir, Z

2010-02-25T23:59:59.000Z

268

In vivo corrosion, tumor outcome, and microarray gene expression for two types of muscle-implanted tungsten alloys  

SciTech Connect (OSTI)

Tungsten alloys are composed of tungsten microparticles embedded in a solid matrix of transition metals such as nickel, cobalt, or iron. To understand the toxicology of these alloys, male F344 rats were intramuscularly implanted with pellets of tungsten/nickel/cobalt, tungsten/nickel/iron, or pure tungsten, with tantalum pellets as a negative control. Between 6 and 12 months, aggressive rhabdomyosarcomas formed around tungsten/nickel/cobalt pellets, while those of tungsten/nickel/iron or pure tungsten did not cause cancers. Electron microscopy showed a progressive corrosion of the matrix phase of tungsten/nickel/cobalt pellets over 6 months, accompanied by high urinary concentrations of nickel and cobalt. In contrast, non-carcinogenic tungsten/nickel/iron pellets were minimally corroded and urinary metals were low; these pellets having developed a surface oxide layer in vivo that may have restricted the mobilization of carcinogenic nickel. Microarray analysis of tumors revealed large changes in gene expression compared with normal muscle, with biological processes involving the cell cycle significantly up?regulated and those involved with muscle development and differentiation significantly down?regulated. Top KEGG pathways disrupted were adherens junction, p53 signaling, and the cell cycle. Chromosomal enrichment analysis of genes showed a highly significant impact at cytoband 7q22 (chromosome 7) which included mouse double minute (MDM2) and cyclin?dependant kinase (CDK4) as well as other genes associated with human sarcomas. In conclusion, the tumorigenic potential of implanted tungsten alloys is related to mobilization of carcinogenic metals nickel and cobalt from corroding pellets, while gene expression changes in the consequent tumors are similar to radiation induced animal sarcomas as well as sporadic human sarcomas. -- Highlights: ? Tungsten/nickel/cobalt, tungsten/nickel/iron, and pure tungsten were studied. ? Male Fischer rats implanted with pellets in gastrocnemius muscle of each hind leg. ? Aggressive rhabdomyosarcomas developed from tungsten/nickel/cobalt pellets only. ? Microarray gene expression analysis was carried out on selected tumors. ? Pellet degradation, urinary metal concentration, and sarcoma were correlated.

Schuster, B.E. [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, B434 Mulberry Road, Aberdeen Proving Ground, MD 21005-5609 (United States)] [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, B434 Mulberry Road, Aberdeen Proving Ground, MD 21005-5609 (United States); Roszell, L.E. [U.S. Army Institute of Public Health, 5158 Blackhawk Road, Aberdeen Proving Ground, MD 21010?5403 (United States)] [U.S. Army Institute of Public Health, 5158 Blackhawk Road, Aberdeen Proving Ground, MD 21010?5403 (United States); Murr, L.E.; Ramirez, D.A. [Department of Metallurgical and Materials Engineering, University of Texas, El Paso, TX 79968 (United States)] [Department of Metallurgical and Materials Engineering, University of Texas, El Paso, TX 79968 (United States); Demaree, J.D. [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, B434 Mulberry Road, Aberdeen Proving Ground, MD 21005-5609 (United States)] [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, B434 Mulberry Road, Aberdeen Proving Ground, MD 21005-5609 (United States); Klotz, B.R. [Dynamic Science Inc., Aberdeen Proving Ground, MD 21005?5609 (United States)] [Dynamic Science Inc., Aberdeen Proving Ground, MD 21005?5609 (United States); Rosencrance, A.B.; Dennis, W.E. [U.S. Army Center for Environmental Health Research, Department of Chemistry, Ft. Detrick, MD 21702?5010 (United States)] [U.S. Army Center for Environmental Health Research, Department of Chemistry, Ft. Detrick, MD 21702?5010 (United States); Bao, W. [SAS Institute, Inc. SAS Campus Drive, Cary, NC 27513 (United States)] [SAS Institute, Inc. SAS Campus Drive, Cary, NC 27513 (United States); Perkins, E.J. [U.S. Army Engineer Research and Development Center, 3909 Hall Ferry Road, Vicksburg MS 39180 (United States)] [U.S. Army Engineer Research and Development Center, 3909 Hall Ferry Road, Vicksburg MS 39180 (United States); Dillman, J.F. [U.S. Army Medical Research Institute of Chemical Defense, 3100 Ricketts Point Road, Aberdeen Proving Ground, MD 21010?5400 (United States)] [U.S. Army Medical Research Institute of Chemical Defense, 3100 Ricketts Point Road, Aberdeen Proving Ground, MD 21010?5400 (United States); Bannon, D.I., E-mail: desmond.bannon@us.army.mil [U.S. Army Institute of Public Health, 5158 Blackhawk Road, Aberdeen Proving Ground, MD 21010?5403 (United States)

2012-11-15T23:59:59.000Z

269

In vitro profiling of epigenetic modifications underlying heavy metal toxicity of tungsten-alloy and its components  

SciTech Connect (OSTI)

Tungsten-alloy has carcinogenic potential as demonstrated by cancer development in rats with intramuscular implanted tungsten-alloy pellets. This suggests a potential involvement of epigenetic events previously implicated as environmental triggers of cancer. Here, we tested metal induced cytotoxicity and epigenetic modifications including H3 acetylation, H3-Ser10 phosphorylation and H3-K4 trimethylation. We exposed human embryonic kidney (HEK293), human neuroepithelioma (SKNMC), and mouse myoblast (C2C12) cultures for 1-day and hippocampal primary neuronal cultures for 1-week to 50-200 {mu}g/ml of tungsten-alloy (91% tungsten/6% nickel/3% cobalt), tungsten, nickel, and cobalt. We also examined the potential role of intracellular calcium in metal mediated histone modifications by addition of calcium channel blockers/chelators to the metal solutions. Tungsten and its alloy showed cytotoxicity at concentrations > 50 {mu}g/ml, while we found significant toxicity with cobalt and nickel for most tested concentrations. Diverse cell-specific toxic effects were observed, with C2C12 being relatively resistant to tungsten-alloy mediated toxic impact. Tungsten-alloy, but not tungsten, caused almost complete dephosphorylation of H3-Ser10 in C2C12 and hippocampal primary neuronal cultures with H3-hypoacetylation in C2C12. Dramatic H3-Ser10 dephosphorylation was found in all cobalt treated cultures with a decrease in H3 pan-acetylation in C2C12, SKNMC and HEK293. Trimethylation of H3-K4 was not affected. Both tungsten-alloy and cobalt mediated H3-Ser10 dephosphorylation were reversed with BAPTA-AM, highlighting the role of intracellular calcium, confirmed with 2-photon calcium imaging. In summary, our results for the first time reveal epigenetic modifications triggered by tungsten-alloy exposure in C2C12 and hippocampal primary neuronal cultures suggesting the underlying synergistic effects of tungsten, nickel and cobalt mediated by changes in intracellular calcium homeostasis and buffering. - Highlights: > Tungsten-alloy caused H3-Ser10 dephosphorylation in C2C12 and hippocampal primary cultures. > Dramatic H3-Ser10 dephosphorylation was found in all cobalt treated cultures. > C2C12 cultures exposed to tungsten-alloy or cobalt exhibited decrease in H3 pan-acetylation. > Tungsten-alloy and cobalt mediated H3-Ser10 dephosphorylation was reversed with BAPTA-AM. > These epigenetic modifications were mediated by changes in calcium homeostasis and buffering.

Verma, Ranjana, E-mail: Ranjana.Verma.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Xu, Xiufen, E-mail: Xiufen.Xu.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Jaiswal, Manoj K., E-mail: Manoj.Jaiswal.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Olsen, Cara, E-mail: colsen@usuhs.mil [Department of Preventive Medicine and Biometrics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Mears, David, E-mail: dmears@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Caretti, Giuseppina, E-mail: giuseppina.caretti@unimi.it [Department of Biomolecular Sciences and Biotechnology, University of Milan (Italy); Galdzicki, Zygmunt, E-mail: zgaldzicki@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States)

2011-06-15T23:59:59.000Z

270

Effect of interfacial interactions on the thermal conductivity and interfacial thermal conductance in tungsten–graphene layered structure  

SciTech Connect (OSTI)

Graphene film was deposited by microwave plasma assisted deposition on polished oxygen free high conductivity copper foils. Tungsten–graphene layered film was formed by deposition of tungsten film by magnetron sputtering on the graphene covered copper foils. Tungsten film was also deposited directly on copper foil without graphene as the intermediate film. The tungsten–graphene–copper samples were heated at different temperatures up to 900?°C in argon atmosphere to form an interfacial tungsten carbide film. Tungsten film deposited on thicker graphene platelets dispersed on silicon wafer was also heated at 900?°C to identify the formation of tungsten carbide film by reaction of tungsten with graphene platelets. The films were characterized by scanning electron microscopy, Raman spectroscopy, and x-ray diffraction. It was found that tungsten carbide film formed at the interface upon heating only above 650?°C. Transient thermoreflectance signal from the tungsten film surface on the samples was collected and modeled using one-dimensional heat equation. The experimental and modeled results showed that the presence of graphene at the interface reduced the cross-plane effective thermal conductivity and the interfacial thermal conductance of the layer structure. Heating at 650 and 900?°C in argon further reduced the cross-plane thermal conductivity and interface thermal conductance as a result of formation nanocrystalline tungsten carbide at the interface leading to separation and formation of voids. The present results emphasize that interfacial interactions between graphene and carbide forming bcc and hcp elements will reduce the cross-plane effective thermal conductivity in composites.

Jagannadham, K., E-mail: jag-kasichainula@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

2014-09-01T23:59:59.000Z

271

Evolution of sputtered tungsten coatings at high temperature  

SciTech Connect (OSTI)

Sputtered tungsten (W) coatings were investigated as potential high temperature nanophotonic material to replace bulk refractory metal substrates. Of particular interest are materials and coatings for thermophotovoltaic high-temperature energy conversion applications. For such applications, high reflectance of the substrate in the infrared wavelength range is critical in order to reduce losses due to waste heat. Therefore, the reflectance of the sputtered W coatings was characterized and compared at different temperatures. In addition, the microstructural evolution of sputtered W coatings (1 and 5 ?m thick) was investigated as a function of anneal temperature from room temperature to 1000 °C. Using in situ x-ray diffraction analysis, the microstrain in the two samples was quantified, ranging from 0.33% to 0.18% for the 1 ?m sample and 0.26% to 0.20% for the 5 ?m sample, decreasing as the temperature increased. The grain growth could not be as clearly quantified due to the dominating presence of microstrain in both samples but was in the order of 20 to 80 nm for the 1 ?m sample and 50 to 100 nm for the 5 ?m sample, as deposited. Finally, the 5 ?m thick layer was found to be rougher than the 1 ?m thick layer, with a lower reflectance at all wavelengths. However, after annealing the 5 ?m sample at 900 °C for 1 h, its reflectance exceeded that of the 1 ?m sample and approached that of bulk W found in literature. Overall, the results of this study suggest that thick coatings are a promising alternative to bulk substrates as a low cost, easily integrated platform for nanostructured devices for high-temperature applications, if the problem of delamination at high temperature can be overcome.

Stelmakh, Veronika; Rinnerbauer, Veronika; Joannopoulos, John D.; Solja?i?, Marin; Celanovic, Ivan; Senkevich, Jay J. [Institute for Soldier Nanotechnologies, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Institute for Soldier Nanotechnologies, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Tucker, Charles; Ives, Thomas; Shrader, Ronney [Materion Corporation, Buellton, California 93427 (United States)] [Materion Corporation, Buellton, California 93427 (United States)

2013-11-15T23:59:59.000Z

272

Nanoparticles synthesis of tungsten disulfide via AOT-based microemulsions  

SciTech Connect (OSTI)

Graphical abstract: A controlled synthesis of WS2 nanoparticles (most probably inorganic fullerene (IF)) via microemulsion was applied for the first time to prepare WS2 (7–12 nm) by acidification of the water cores of the AOT reverse microemulsion. Highlights: ? An innovative reverse microemulsion technique was developed for WS{sub 2} synthesis. ? WS{sub 2} nanoparticles were obtained with narrow size distribution in range of 7–12 nm. ? Operating cost of microemulsion was lower in contrast to quartz reactor method. ? WS{sub 2} morphology could be controlled to obtain highly active and selective catalysts. ? Lower size of WS{sub 2} in this study overcomes the shortcoming of quartz reactor method. -- Abstract: The tungsten disulfide (WS{sub 2}) nanoparticles (most probably inorganic fullerene (IF)) with a narrow size distribution were synthesized by a reverse micelle technique for the first time. The particle size was controlled by varying water-to-surfactant molar ratio (W{sub 0}), aging time and reagent concentration. The synthesized WS{sub 2} nanoparticles were characterized by zetasizer, UV–visible spectrophotometers and transmission electron microscopy (TEM). The WS{sub 2} nanoparticles with particle diameter size of 7–12 nm were obtained via 24 h aging time. The particle size was controlled by changing the aging time and molar ratio of water/surfactant. Doubling W{sub 0} increased the amount and particle size of WS{sub 2} by 22 and 26%, respectively. The effect of aging time in the range of 6–24 h was investigated and the complete disappearance of yellowish color at 24 h resulted in an optically clear solution, which was the indication of WS{sub 2} formation with 100% conversion of reactant ((NH{sub 4}){sub 2}WS{sub 4}) in the batch reactor.

Ghoreishi, S.M., E-mail: ghoreshi@cc.iut.ac.ir [Department of Chemical Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Meshkat, S.S. [Department of Chemical Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of) [Department of Chemical Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Department of Chemical Engineering, Urmia University of Technology, Urmia 57155-419 (Iran, Islamic Republic of); Ghiaci, M. [Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of)] [Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Dadkhah, A.A. [Department of Chemical Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of)] [Department of Chemical Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of)

2012-06-15T23:59:59.000Z

273

Z .Surface and Coatings Technology 130 2000 164 172 Production of high-density Ni-bonded tungsten carbide  

E-Print Network [OSTI]

carbide coatings using an axially fed DC-plasmatron S. Sharafata,U , A. Kobayashib , S. Chena , N spraying; Nickel; Tungsten carbide 1. Introduction 1.1. General Since the mid-1990s, the market share of cemented Z .carbides has surpassed that of high-speed steels HSS , Z .with tungsten carbide WC having 50

Ghoniem, Nasr M.

274

Gas phase reaction products during tungsten atomic layer deposition using WF6 and Si2H6  

E-Print Network [OSTI]

Gas phase reaction products during tungsten atomic layer deposition using WF6 and Si2H6 R. K; published 23 July 2004 The gas phase reaction products during tungsten W atomic layer deposition ALD using WF6 and Si2H6 were studied using quadrupole mass spectrometry. The gas phase reactions products were

George, Steven M.

275

Above: Power deposition in the superconducting magnets and the tungsten-carbide + water shield inside them, according to a  

E-Print Network [OSTI]

Above: Power deposition in the superconducting magnets and the tungsten-carbide + water shield FOR A MUON COLLIDER (TUP265, PAC11) The concept for a muon-production system for a muon collider (or neutrino Magnet shield WC beads + water Shield must dissipate 2.4 MW Superconducting magnets tungsten-carbide (WC

McDonald, Kirk

276

Employee Spotlight: Ann Schlenker  

SciTech Connect (OSTI)

Ann Schlenker, Director for the Center for Transportation Research, discusses mentoring and working at Argonne.

Ann Schlenker

2013-03-20T23:59:59.000Z

277

Spotlight, June 2012  

E-Print Network [OSTI]

notice. The Biofuels and Climate Change: Farmers’ Land Use Decisions (BACC:FLUD) project has brought together an inter-disciplinary team of researchers from The University of Kansas, Kansas State University, and Emporia State University... policies that promote or restrain certain land uses; and economic factors, such as food crop prices and biofuel crop prices. These data sets will be integrated with data from other sources into a rich, longitudinal database on land use decisions...

2012-06-01T23:59:59.000Z

278

Spotlight, November 2012  

E-Print Network [OSTI]

- and water-use decisions in a changing climate,” highlighting elements of the Biofuels and Climate Change: Farmers' Land Use Decisions (BACC: FLUD) project. Engineering faculty and others across multiple social and natural science disciplines from... both KU and K-State are working on this collaborative project researching farmers’ decisions to grow biofuel crops as feedstocks for renewable energy production and their adaptation to climate change. Dr. Sturm’s focus was on irrigation demands...

2012-11-01T23:59:59.000Z

279

Spotlight, October 2012  

E-Print Network [OSTI]

is June 2014. Transportation: Our Transit system uses hybrid buses along its busiest routes, and we’re piloting a compressed natural gas vehicle to By Eileen Horn, Lawrence/Douglas County Sustainability Coordinator learn more about this alternative...

2012-10-01T23:59:59.000Z

280

Spotlight, March 2013  

E-Print Network [OSTI]

family size" to a choice system that (continued on page 2) By Thelma Simons, Project Coordinator for Information Technology and KU Advocate for Just Food 2 Page 2 KU Center for Sustainability March 2013 Kansas Dialogue Focuses Discussion at a...-4 PM Downtown Lawrence & South Park 4/23 Sustainability Leadership Award & Green Office Recognition Event, 3:30 PM Kansas Union 4/23 The Environment & Energy: The Role of Free Enterprise and the Government, 7:30 PM Dole Institute...

2013-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

DOE Sustainability SPOtlight  

Broader source: Energy.gov [DOE]

Newsletter highlights the recipients of the U.S. Department of Energy (DOE) Sustainability Performance Office (SPO) 2014 Sustainability Awards.

282

Spotlight, August 2012  

E-Print Network [OSTI]

August 2012 Page 1 KU Center for Sustainability Hertz on Demand also helps save the environment while saving its members money, by lessening harmful emissions and reducing congestion. Fewer cars on the road means lower CO2 emissions.... Sustainable practices were evident in other areas as well. Solar panels were put wherever they could fit to make the most of an often evasive sun, as clouds and rain became a normalcy. Touring a local organic winery meshed the initiatives of a...

2012-08-01T23:59:59.000Z

283

Spotlight, May 2013  

E-Print Network [OSTI]

Directories Includes: Does Not Include: Steel (tin) cans ONLY Aluminum Cans Bottles of any kind Sheet or Scrap Metal Any #1-#7 plastic (salad bar take-out, plastic packaging etc) TELEPHONE DIRECTORIES & CATALOGS Includes campus...” commodity crops in industrialized agriculture - corn, cotton, rice, soybeans, and wheat - are subsidized, we need to remember that the fossil fuels used to produce them are also subsidized. Consequently, we are not paying the real cost of food. Unless we...

2013-05-01T23:59:59.000Z

284

Robot learning [TC Spotlight  

E-Print Network [OSTI]

Creating autonomous robots that can learn to act in unpredictable environments has been a long-standing goal of robotics, artificial intelligence, and the cognitive sciences. In contrast, current commercially available ...

Tedrake, Russell Louis

285

Spotlight, April 2012  

E-Print Network [OSTI]

Oread. The board hopes to revive this tradition by working with students on annual planting and tree inventory projects. Students fro m the Enviro nmental Law Society help plant a redb ud tree. Sou rce: KU Scho ol of Law. You can help fund...: Sarah Link Left: Garbage - mostly plastic - accumulates on the Damon Slough Beach in Oakland, CA. Right: Manuel Mansylla from Plastic Pollution Coalition displays the plastic waste he collected in about an hour at the beach. Source: Sarah Link...

2012-04-01T23:59:59.000Z

286

Spotlight, March 2012  

E-Print Network [OSTI]

, Assessment & Rating System, measures and encourages sustainability in all aspects of higher education. This is KU’s first year completing the STARS self ?assessment. “Building Sustainable Traditions, introduced last fall, is framed around the principles of... STARS and is guiding our path towards making sustainability an inherent part of everything we do at KU,” said Chancellor Bernadette Gray?Little. “We are proud of achieving a Bronze rating, but more importantly STARS helps us identify opportunities to build...

2012-03-01T23:59:59.000Z

287

Spotlight, April 2013  

E-Print Network [OSTI]

to turn off all lights and appliances when they leave a room, and plan to conduct an energy audit to analyze the effectiveness of this program. In addition, Sigma Phi Epsilon has taken environmental consideration in every facility upgrade made.... She was a founder and chairperson of the Lawrence Community Environmental School charter, a co-founder of the Lawrence Environmental Education Project, an organizer for the Ecoliteracy Book Club in Lawrence, coordinator for the St. John school...

2013-04-01T23:59:59.000Z

288

Employee Spotlight: Ann Schlenker  

ScienceCinema (OSTI)

Ann Schlenker, Director for the Center for Transportation Research, discusses mentoring and working at Argonne.

Ann Schlenker

2013-06-10T23:59:59.000Z

289

MEISPP Internship Spotlight  

Broader source: Energy.gov (indexed) [DOE]

of academic majors, such as economics, business, international relations, biology, physics, engineering, etc. All internships include paid lodging; roundtrip airfare;...

290

Scientists in the Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2)Science HighlightAlanExchangeOfficeofannual

291

Scientists in the Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2)Science HighlightAlanExchangeOfficeofannualScientists

292

Scientists in the Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2)Science

293

Employee Spotlight: Alessandro Cattaneo  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and West OtherEmployeeLos

294

Employee Spotlight: Bryant Roybal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and West OtherEmployeeLosAli ErdemirBryant

295

Employee Spotlight: Dave Keller  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and West OtherEmployeeLosAli

296

Employee Spotlight: Janice Lovato  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and West OtherEmployeeLosAliJanice Lovato

297

Employee Spotlight: Jonathan Engle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and West OtherEmployeeLosAliJanice

298

Employee Spotlight: Kristen Honig  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and West

299

Employee Spotlight: Michael Torrez  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and WestLydia Finney March 16, 2015

300

Employee Spotlight: Monika Bittman  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and WestLydia Finney March 16, 2015Monika

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Employee Spotlight: Ron Barber  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and WestLydia Finney March 16,

302

Employee Spotlight: Sim Balkey  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and WestLydia Finney March 16,Sim

303

Employee Spotlight: Alessandro Cattaneo  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMI SIGTrendsAbout UsHumanAlessandro

304

Employee Spotlight: Bryant Roybal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMI SIGTrendsAboutAnn

305

Employee Spotlight: Dave Keller  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMI SIGTrendsAboutAnnDave Keller

306

Employee Spotlight: Janice Lovato  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMI SIGTrendsAboutAnnDave

307

Employee Spotlight: Jonathan Engle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMI SIGTrendsAboutAnnDaveJonathan

308

Employee Spotlight: Kristen Honig  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMIKristen Honig June 24, 2014 In

309

Employee Spotlight: Michael Torrez  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMIKristen Honig June 24,

310

Employee Spotlight: Monika Bittman  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMIKristen Honig June 24,Monika

311

Employee Spotlight: Ron Barber  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMIKristen Honig June 24,MonikaRon

312

Scientists in the Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmitted forHighlights Nuclear Physics

313

Video: Employee Spotlight | JCESR  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies | Blandine Jerome Velencia Witherspoon

314

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents [OSTI]

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

1999-01-01T23:59:59.000Z

315

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents [OSTI]

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced. 3 figs.

Kansa, E.J.; Anderson, B.L.; Wijesinghe, A.M.; Viani, B.E.

1999-05-25T23:59:59.000Z

316

Micro-Raman and cathodoluminescence studies of epitaxial laterally overgrown GaN with tungsten masks: A method to map the free-carrier  

E-Print Network [OSTI]

Micro-Raman and cathodoluminescence studies of epitaxial laterally overgrown GaN with tungsten properties of two epitaxial-laterally overgrown GaN structures with tungsten masks in 1100 and 1120 direction by tungsten masks3 to prevent the in-diffusion of silicon and oxygen atoms in the overgrown GaN, which

Nabben, Reinhard

317

A Tungsten(VI) Nitride Having a W2(-N)2 Core Zachary J. Tonzetich, Richard R. Schrock,* Keith M. Wampler, Brad C. Bailey,  

E-Print Network [OSTI]

A Tungsten(VI) Nitride Having a W2(µ-N)2 Core Zachary J. Tonzetich, Richard R. Schrock,* Keith M-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 Received September 27, 2007 The tungsten that the tungsten alkylidyne species W(C-t-Bu)(CH2-t-Bu)(OAr)2 (Ar ) 2,6-diisopropylphenyl) can be prepared readily

Müller, Peter

318

Molecular dynamics simulations of hydrogen bombardment of tungsten carbide surfaces P. Trskelin,1 N. Juslin,1 P. Erhart,2 and K. Nordlund1  

E-Print Network [OSTI]

Molecular dynamics simulations of hydrogen bombardment of tungsten carbide surfaces P. Träskelin,1 and tungsten carbide WC is of interest both due to the use of hydrogen-containing plasmas in thin. INTRODUCTION Tungsten carbide WC exhibits extraordinary hardness and temperature resistance. It has long been

Nordlund, Kai

319

Deuterium Depth Profile in Neutron-Irradiated Tungsten Exposed to Plasma  

SciTech Connect (OSTI)

The effect of radiation damage has been mainly simulated using high-energy ion bombardment. The ions, however, are limited in range to only a few microns into the surface. Hence, some uncertainty remains about the increase of trapping at radiation damage produced by 14 MeV fusion neutrons, which penetrate much farther into the bulk material. With the Japan-US joint research project: Tritium, Irradiations, and Thermofluids for America and Nippon (TITAN), the tungsten samples (99.99 % pure from A.L.M.T., 6mm in diameter, 0.2mm in thickness) were irradiated to high flux neutrons at 50 C and to 0.025 dpa in the High Flux Isotope Reactor (HFIR) at the Oak Ridge National Laboratory (ORNL). Subsequently, the neutron-irradiated tungsten samples were exposed to a high-flux deuterium plasma (ion flux: 1021-1022 m-2s-1, ion fluence: 1025-1026 m-2) in the Tritium Plasma Experiment (TPE) at the Idaho National Laboratory (INL). First results of deuterium retention in neutron-irradiated tungsten exposed in TPE have been reported previously. This paper presents the latest results in our on-going work of deuterium depth profiling in neutron-irradiated tungsten via nuclear reaction analysis. The experimental data is compared with the result from non neutron-irradiated tungsten, and is analyzed with the Tritium Migration Analysis Program (TMAP) to elucidate the hydrogen isotope behavior such as retention and depth distribution in neutron-irradiated and non neutron-irradiated tungsten.

Masashi Shimada; G. Cao; Y. Hatano; T. Oda; Y. Oya; M. Hara; P. Calderoni

2011-05-01T23:59:59.000Z

320

Effect of silver incorporation in phase formation and band gap tuning of tungsten oxide thin films  

SciTech Connect (OSTI)

Silver incorporated tungsten oxide thin films are prepared by RF magnetron sputtering technique. The effect of silver incorporation in micro structure evolution, phase enhancement, band gap tuning and other optical properties are investigated using techniques such as x-ray diffraction, micro-Raman spectroscopy, atomic force microscopy, scanning electron microscopy, energy dispersive x-ray spectroscopy, and UV-Visible spectroscopy. Effect of silver addition in phase formation and band gap tuning of tungsten oxide thin films are investigated. It is found that the texturing and phase formation improves with enhancement in silver content. It is also found that as the silver incorporation enhances the thickness of the films increases at the same time the strain in the film decreases. Even without annealing the desired phase can be achieved by doping with silver. A broad band centered at the wavelength 437 nm is observed in the absorption spectra of tungsten oxide films of higher silver incorporation and this can be attributed to surface plasmon resonance of silver atoms present in the tungsten oxide matrix. The transmittance of the films is decreased with increase in silver content which can be due to increase in film thickness, enhancement of scattering, and absorption of light caused by the increase of grain size, surface roughness and porosity of films and enhanced absorption due to surface plasmon resonance of silver. It is found that silver can act as the seed for the growth of tungsten oxide grains and found that the grain size increases with silver content which in turn decreases the band gap of tungsten oxide from 3.14 eV to 2.70 eV.

Jolly Bose, R.; Kumar, R. Vinod; Sudheer, S. K.; Mahadevan Pillai, V. P. [Department of Optoelectronics, University of Kerala, Kariyavattom, Thiruvananthapuram, Kerala 695581 (India); Reddy, V. R.; Ganesan, V. [UGC - DAE Consortium for Scientific Research, Khandwa Road, Indore 452017, Madhyapradesh (India)

2012-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Comparison of Deuterium Retention for Ion-irradiated and Neutron-irradiated Tungsten  

SciTech Connect (OSTI)

The behavior of D retention for Fe{sup 2+}-irradiated tungsten with a damage of 0.025-3 dpa was compared with that for neutron-irradiated tungsten with 0.025 dpa. The D{sub 2} thermal desorption spectroscopy (TDS) spectra for Fe{sup 2+}-irradiated tungsten consisted of two desorption stages at 450 and 550 K, while that for neutron-irradiated tungsten was composed of three stages and an addition desorption stage was found at 750 K. The desorption rate of the major desorption stage at 550K increased as the displacement damage increased due to Fe{sup 2+} irradiation increasing. In addition, the first desorption stage at 450K was found only for damaged samples. Therefore, the second stage would be based on intrinsic defects or vacancy produced by Fe{sup 2+} irradiation, and the first stage should be the accumulation of D in mono-vacancy and the activation energy would be relatively reduced, where the dislocation loop and vacancy is produced. The third one was found only for neutron irradiation, showing the D trapping by a void or vacancy cluster, and the diffusion effect is also contributed to by the high full-width at half-maximum of the TDS spectrum. Therefore, it can be said that the D{sub 2} TDS spectra for Fe{sup 2+}-irradiated tungsten cannot represent that for the neutron-irradiated one, indicating that the deuterium trapping and desorption mechanism for neutron-irradiated tungsten is different from that for the ion-irradiated one.

Yasuhisa Oya; Masashi Shimada; Makoto Kobayashi; Takuji Oda; Masanori Hara; Hideo Watanabe; Yuji Hatano; Pattrick Calderoni; Kenji Okuno

2011-12-01T23:59:59.000Z

322

Utilization of geothermal energy in the mining and processing of tungsten ore. Quarterly report  

SciTech Connect (OSTI)

The status of the engineering and economic feasibility study of utilizing geothermal energy for the mining and processing of tungsten ore at the Union Carbide-Metals Division Pine Creek tungsten complex near Bishop, Calfironia is reviewed. Results of geophysical data analysis including determination of assumed resource parameters are presented. The energy utilization evaluation identifies potential locations for substituting geothermal energy for fossil fuel energy using current technology. Preliminary analyses for local environmental and institutional barriers to development of a geothermal system are also provided.

Lane, C.K.; Erickson, M.V.; Lowe, G.D.

1980-02-01T23:59:59.000Z

323

Measurements of Nucleon-Induced Fission Cross-Sections of Separated Tungsten Isotopes and Natural Tungsten in the 50-200 MeV Energy Region  

E-Print Network [OSTI]

Neutron- and proton-induced fission cross-sections of separated isotopes of tungsten (182W, 183W, 184W, and 186W) and natural tungsten relative to 209Bi have been measured in the incident nucleon energy region 50-200 MeV using fission chambers based on thin-film breakdown counters (TFBC) at quasi-monoenergetic neutrons from the 7Li(p,n) reaction and at the proton beams of The Svedberg Laboratory (TSL), Uppsala University (Uppsala, Sweden). The preliminary experimental data are presented in comparison with the recent data for nuclei in the lead-bismuth region, as well as with predictions by the CEM03.01 event generator.

V. P. Eismont; N. P. Filatov; A. N. Smirnov; S. M. Soloviev; J. Blomgren; H. Conde; A. V. Prokofiev; S. G. Mashnik

2005-07-07T23:59:59.000Z

324

Theoretic Insight into CO2 Reduction at Active Sites of Molybdenum and Tungsten Enzymes: a {\\pi} Interaction between CO2 and Tungsten Bis-Dithiolene Complexes  

E-Print Network [OSTI]

Active sites of molybdenum and tungsten enzymes, particularly mononuclear tungsten formate dehydrogenase (FDH) have been theoretically investigated towards their interaction with CO2. Obvious {\\pi} interaction has been found between the 2e reduced metallodithiole moiety and the molecular CO2. This weak {\\pi} bonding is predicated both at gas phase, noted as -6.0 kcal/mol and aqueous solvation level, -3.6 kcal/mol. Such interaction is not only limited to CO2, but also to the CO2 reduced product, i.e. formate, in the form of anion- {\\pi} interaction, noted as -6.8 kcal/mol and -4.1 kcal/mol respectively in gas and aqueous solvation model. The Bailar twisted angles from 60o to 0o, governing structure preference of tungsten dithiolene from octahedron to triangle prism in their restricted structures, has been explored to evaluate such {\\pi} in-terrelations with CO2 and formate. An octahedral structure with 3 kcal/mol energy lower is preferred over the triangle prismatic when such interactions are concerned.

Yan, Yong

2014-01-01T23:59:59.000Z

325

Materials Corrosion and Mitigation Strategies for APT: Using Solution Resistivity as an Estimate of Tungsten Corrosion  

E-Print Network [OSTI]

Materials Corrosion and Mitigation Strategies for APT: Using Solution Resistivity as an Estimate of Tungsten Corrosion in Spallation Neutron Target Cooling Loops R. Scott Lillard, Darryl P. Butt Materials Corrosion and Environmental Effects Laboratory MST-6, Metallurgy Los Alamos National Laboratory Los Alamos

326

Interactions of mobile helium clusters with surfaces and grain boundaries of plasma-exposed tungsten  

SciTech Connect (OSTI)

We report results of atomistic computations for the interactions of small mobile helium clusters (He{sub n}) with free surfaces and grain boundaries (GBs) in tungsten toward development of continuum drift-diffusion-reaction models for the dynamics of mobile helium clusters in plasma-exposed tungsten. Molecular-statics (MS) simulations based on reliable many-body interatomic potentials are carried out for He{sub n} (1???n???7) clusters near sinks to obtain the potential energy profiles of the He{sub n} clusters as a function of the clusters' center-of-mass distance from a sink. Sinks investigated include surfaces, GBs, and regions in the vicinity of junctions where GBs intersect free surfaces. Elastic interaction potentials based on elastic inclusion theory provide an excellent description of the MS results for the cluster-sink interactions. The key parameter in the elastic models is the sink segregation strength, which is found to increase with increasing cluster size. Such cluster-sink interactions are responsible for the migration of small helium clusters by drift and for helium segregation on surfaces and grain boundaries in tungsten. Such helium segregation on sinks is observed in large-scale molecular-dynamics simulations of helium aggregation in model polycrystalline tungsten at 933?K upon helium implantation.

Hu, Lin; Maroudas, Dimitrios, E-mail: maroudas@ecs.umass.edu [Department of Chemical Engineering, University of Massachusetts, Amherst, Massachusetts 01003-9303 (United States); Hammond, Karl D.; Wirth, Brian D. [Department of Nuclear Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States)

2014-05-07T23:59:59.000Z

327

The role of helium implantation induced vacancy defect on hardening of tungsten  

SciTech Connect (OSTI)

Vacancy-type defects created by helium implantation in tungsten and their impact on the nano-hardness characteristics were investigated by correlating the results from the positron annihilation spectroscopy and the nano-indentation technique. Helium implantation was performed at room temperature (RT) and at an elevated temperate of 600?°C. Also, the effect of post-annealing of the RT implanted sample was studied. The S parameter characterizing the open volume in the material was found to increase after helium irradiation and is significantly enhanced for the samples thermally treated at 600?°C either by irradiation at high temperature or by post-annealing. Two types of helium-vacancy defects were detected after helium irradiation; small defects with high helium-to-vacancy ratio (low S parameter) for RT irradiation and large defects with low helium-to-vacancy ratio (high S parameter) for thermally treated tungsten. The hardness of the heat treated tungsten coincides with the S parameter, and hence is controlled by the large helium-vacancy defects. The hardness of tungsten irradiated at RT without thermal treatment is dominated by manufacturing related defects such as dislocation loops and impurity clusters and additionally by trapped He atoms from irradiation effects, which enhance hardness. He-stabilized dislocation loops mainly cause the very high hardness values in RT irradiated samples without post-annealing.

Ou, Xin, E-mail: x.ou@hzdr.de [Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstr. 400, 01328 Dresden (Germany); State Key Laboratory of Functional Material for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200250 (China); Anwand, Wolfgang, E-mail: w.anwand@hzdr.de; Kögler, Reinhard, E-mail: r.koegler@hzdr.de [Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstr. 400, 01328 Dresden (Germany); Zhou, Hong-Bo [Department of Physics, Beihang University, Beijing 100191 (China); Richter, Asta, E-mail: asta.richter@th-wildau.de [Technische Hochschule Wildau, Hochschulring1, 15745 Wildau (Germany)

2014-03-28T23:59:59.000Z

328

Difference in formation of hydrogen and helium clusters in tungsten K. O. E. Henriksson,a  

E-Print Network [OSTI]

Difference in formation of hydrogen and helium clusters in tungsten K. O. E. Henriksson,a K online 12 October 2005 The experimentally observed large difference in the depths of hydrogen and helium and He embrittlement of materials. Yet many of the basic properties of such systems are not well

Krasheninnikov, Arkady V.

329

Measurement of Tc suppression in tungsten using magnetic impurities B. A. Younga)  

E-Print Network [OSTI]

AND BACKGROUND Thin films of superconducting materials have been used as phonon sensors for many years. The exact design of pho- non sensors varies according to the intended applications.1 For example, some of superconducting aluminum and tungsten.2 These phonon sensors are called ``W/Al quasi-particle-trap- assisted

California at Berkeley, University of

330

Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D  

E-Print Network [OSTI]

Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D W. Zhou*, T. Z. Long and C. K ductility, and the HAZ was found to be the `weakest link'. Keywords: Magnesium alloy, AZ91D, TIG welding, Hot cracking, Liquation, Fracture Introduction Magnesium alloys have high strength/weight ratio

Zhou, Wei

331

Tungsten black absorber for solar light with wide angular operation range Eden Rephaeli1,a  

E-Print Network [OSTI]

Tungsten black absorber for solar light with wide angular operation range Eden Rephaeli1,a of Physics. DOI: 10.1063/1.2936997 In solar-thermal applications, one aims to convert sun- light to heat that displays near-complete absorptivity throughout the entire solar spectrum over a wide angular range

Fan, Shanhui

332

Utilization of geothermal energy in the mining and processing of tungsten ore. Final report  

SciTech Connect (OSTI)

The engineering, economic, and environmental feasibility of the use of low and moderate temperature geothermal heat in the mining and processing of tungsten ore is explored. The following are covered: general engineering evaluation, design of a geothermal energy system, economics, the geothermal resource, the institutional barriers assessment, environmental factors, an alternate geothermal energy source, and alternates to geothermal development. (MHR)

Erickson, M.V.; Lacy, S.B.; Lowe, G.D.; Nussbaum, A.M.; Walter, K.M.; Willens, C.A.

1981-01-01T23:59:59.000Z

333

SPS Fabrication of Tungsten-Rhenium Alloys in Support of NTR Fuels Development  

SciTech Connect (OSTI)

Abstract. Tungsten metal slugs were fabricated via Spark Plasma Sintering (SPS) of powdered metals at temperatures ranging from 1575 K to 1975 K and hold times of 5 minutes to 30 minutes, using powders with an average diameter of 7.8 ?m. Sintered tungsten specimens were found to have relative densities ranging from 83 % to 94 % of the theoretical density for tungsten. Consolidated specimens were also tested for their Vickers Hardness Number (VHN), which was fitted as a function of relative density; the fully consolidated VHN was extrapolated to be 381.45 kg/mm2. Concurrently, tungsten and rhenium powders with average respective diameters of 0.5 ?m and 13.3 ?m were pre-processed either by High-Energy-Ball-Milling (HEBM) or by homogeneous mixing to yield W-25at.%Re mixtures. The powder batches were sintered at temperatures of 1975 K and 2175 K for hold times ranging from 0 minutes to 60 minutes yielding relative densities ranging from 94% to 97%. The combination of HEBM and sintering showed a significant decrease in the inter-metallic phases compared to that of the homogenous mixing and sintering.

Jonathan A. Webb; Indrajit Charit; Cory Sparks; Darryl P. Butt; Megan Frary; Mark Carroll

2011-02-01T23:59:59.000Z

334

Tungsten nano-tendril growth in the Alcator C-Mod divertor  

E-Print Network [OSTI]

Growth of tungsten nano-tendrils ('fuzz') has been observed for the first time in the divertor region of a high-power density tokamak experiment. After 14 consecutive helium L-mode discharges in Alcator C-Mod, the tip of ...

Baldwin, M.J.

335

Submersion Criticality Safety Analysis of Tungsten-Based Fuel for Nuclear Power and Propulsion Applications  

SciTech Connect (OSTI)

The Center for Space Nuclear Research (CSNR) is developing tungsten-encapsulated fuels for space nuclear applications. Aims to develop NTP fuels that are; Affordable Low impact on production and testing environment Producible on a large scale over suitable time period Higher-performance compared to previous graphite NTP fuel elements Space nuclear reactors remain subcritical before and during launch, and do not go critical until required by its mission. A properly designed reactor will remain subcritical in any launch abort scenario, where the reactor falls back to Earth and becomes submerged in terrestrial material. Submersion increases neutron reflection and thermalizes the neutrons, which typically increases the reactivity of the core. This effect is usually very significant for fast-spectrum reactors. This research provided a submersion criticality safety analysis for a representative tungsten/uranium oxide fueled reactor. Determine the submersion behavior of a reactor fueled by tungsten-based fuel. Considered fuel compositions with varying: Rhenium content (wt% rhenium in tungsten) Fuel loading fractions (UO2 vol%)

A.E. Craft; R. C. O'Brien; S. D. Howe; J. C. King

2014-07-01T23:59:59.000Z

336

Defect production in tungsten: A comparison between field-ion microscopy and molecular-dynamics simulations  

E-Print Network [OSTI]

Defect production in tungsten: A comparison between field-ion microscopy and molecular defect production efficiencies obtained by FIM are a consequence of a surface effect, which greatly enhances defect production compared to that in the crystal interior. Comparison of clustering of vacancies

Nordlund, Kai

337

MODELING SPACE-TIME DEPENDENT HELIUM BUBBLE EVOLUTION IN TUNGSTEN ARMOR UNDER IFE CONDITIONS  

E-Print Network [OSTI]

MODELING SPACE-TIME DEPENDENT HELIUM BUBBLE EVOLUTION IN TUNGSTEN ARMOR UNDER IFE CONDITIONS Qiyang dependent Helium transport in finite geometries, including the simultaneous transient production of defects of Helium bubbles. I. INTRODUCTION Helium production and helium bubble evolution in neutron

Ghoniem, Nasr M.

338

Defect annealing and thermal desorption of deuterium in low dose HFIR neutron-irradiated tungsten  

SciTech Connect (OSTI)

Accurately estimating tritium retention in plasma facing components (PFCs) and minimizing its uncertainty are key safety issues for licensing future fusion power reactors. D-T fusion reactions produce 14.1 MeV neutrons that activate PFCs and create radiation defects throughout the bulk of the material of these components. Recent studies show that tritium migrates and is trapped in bulk (>> 10 µm) tungsten beyond the detection range of nuclear reaction analysis technique [1-2], and thermal desorption spectroscopy (TDS) technique becomes the only established diagnostic that can reveal hydrogen isotope behavior in in bulk (>> 10 µm) tungsten. Radiation damage and its recovery mechanisms in neutron-irradiated tungsten are still poorly understood, and neutron-irradiation data of tungsten is very limited. In this paper, systematic investigations with repeated plasma exposures and thermal desorption are performed to study defect annealing and thermal desorption of deuterium in low dose neutron-irradiated tungsten. Three tungsten samples (99.99 at. % purity from A.L.M.T. Co., Japan) irradiated at High Flux Isotope Reactor at Oak Ridge National Laboratory were exposed to high flux (ion flux of (0.5-1.0)x1022 m-2s-1 and ion fluence of 1x1026 m-2) deuterium plasma at three different temperatures (100, 200, and 500 °C) in Tritium Plasma Experiment at Idaho National Laboratory. Subsequently, thermal desorption spectroscopy (TDS) was performed with a ramp rate of 10 °C/min up to 900 °C, and the samples were annealed at 900 °C for 0.5 hour. These procedures were repeated three (for 100 and 200 °C samples) and four (for 500 °C sample) times to uncover damage recovery mechanisms and its effects on deuterium behavior. The results show that deuterium retention decreases approximately 90, 75, and 66 % for 100, 200, and 500 °C, respectively after each annealing. When subjected to the same TDS recipe, the desorption temperature shifts from 800 °C to 600 °C after 1st annealing for the sample exposed to TPE at 500 °C. Tritium Migration Analysis Program (TMAP) analysis reveals that the detrapping energy decreases from 1.8 eV to 1.4 eV, indicating the changes in trapping mechanisms. This paper also summarizes deuterium behavior studies in HFIR neutron-irradiated tungsten under US-Japan TITAN program.

Masashi Shimada; M. Hara; T. Otsuka; Y. Oya; Y. Hatano

2014-05-01T23:59:59.000Z

339

Influence of process parameters on properties of reactively sputtered tungsten nitride thin films  

SciTech Connect (OSTI)

Tungsten nitride (WN{sub x}) thin films were produced by reactive dc magnetron sputtering of tungsten in an Ar-N{sub 2} gas mixture. The influence of the deposition power on the properties of tungsten nitride has been analyzed and compared with that induced by nitrogen content variation in the sputtering gas. A combined analysis of structural, electrical and optical properties on thin WN{sub x} films obtained at different deposition conditions has been performed. It was found that at an N{sub 2} content of 14% a single phase structure of W{sub 2}N films was formed with the highest crystalline content. This sputtering gas composition was subsequently used for fabricating films at different deposition powers. Optical analysis showed that increasing the deposition power created tungsten nitride films with a more metallic character, which is confirmed with resistivity measurements. At low sputtering powers the resulting films were crystalline whereas, with an increase of power, an amorphous phase was also present. The incorporation of an excess of nitrogen atoms resulted in an expansion of the W{sub 2}N lattice and this effect was more pronounced at low deposition powers. Infrared analysis revealed that in WN{sub x} films deposited at low power, chemisorbed N{sub 2} molecules did not behave as ligands whereas at high deposition power they clearly appeared as ligands around metallic tungsten. In this study, the influence of the most meaningful deposition parameters on the phase transformation reaction path was established and deposition conditions suitable for producing thermally stable and highly crystalline W{sub 2}N films were found.

Addonizio, Maria L.; Castaldo, Anna; Antonaia, Alessandro; Gambale, Emilia; Iemmo, Laura [ENEA, Portici Research Centre, Piazzale E. Fermi 1, I-80055, Portici (Italy)

2012-05-15T23:59:59.000Z

340

Evaporation-assisted high-power impulse magnetron sputtering: The deposition of tungsten oxide as a case study  

SciTech Connect (OSTI)

The deposition rate during the synthesis of tungsten trioxide thin films by reactive high-power impulse magnetron sputtering (HiPIMS) of a tungsten target increases, above the dc threshold, as a result of the appropriate combination of the target voltage, the pulse duration, and the amount of oxygen in the reactive atmosphere. This behavior is likely to be caused by the evaporation of the low melting point tungsten trioxide layer covering the metallic target in such working conditions. The HiPIMS process is therefore assisted by thermal evaporation of the target material.

Hemberg, Axel; Dauchot, Jean-Pierre; Snyders, Rony; Konstantinidis, Stephanos [Materia Nova Research Center-Parc Initialis, 1, Avenue Copernic, B-7000 Mons, Belgium and Chimie des Interactions Plasma-Surface, CIRMAP, Universite de Mons-20, Place du Parc, B-7000 Mons (Belgium); Chimie des Interactions Plasma-Surface, CIRMAP, Universite de Mons-20, Place du Parc, B-7000 Mons (Belgium); Materia Nova Research Center-Parc Initialis, 1, Avenue Copernic, B-7000 Mons (Belgium) and Chimie des Interactions Plasma-Surface, CIRMAP, Universite de Mons-20, Place du Parc, B-7000 Mons (Belgium); Chimie des Interactions Plasma-Surface, CIRMAP, Universite de Mons-20, Place du Parc, B-7000 Mons (Belgium)

2012-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

INVESTIGATION OF THE TOTAL ORGANIC HALOGEN ANALYTICAL METHOD AT THE WASTE SAMPLING CHARACTERIZATION FACILITY (WSCF)  

SciTech Connect (OSTI)

Total organic halogen (TOX) is used as a parameter to screen groundwater samples at the Hanford Site. Trending is done for each groundwater well, and changes in TOX and other screening parameters can lead to costly changes in the monitoring protocol. The Waste Sampling and Characterization Facility (WSCF) analyzes groundwater samples for TOX using the United States Environmental Protection Agency (EPA) SW-846 method 9020B (EPA 1996a). Samples from the Soil and Groundwater Remediation Project (S&GRP) are submitted to the WSCF for analysis without information regarding the source of the sample; each sample is in essence a 'blind' sample to the laboratory. Feedback from the S&GRP indicated that some of the WSCF-generated TOX data from groundwater wells had a number of outlier values based on the historical trends (Anastos 2008a). Additionally, analysts at WSCF observed inconsistent TOX results among field sample replicates. Therefore, the WSCF lab performed an investigation of the TOX analysis to determine the cause of the outlier data points. Two causes were found that contributed to generating out-of-trend TOX data: (1) The presence of inorganic chloride in the groundwater samples: at inorganic chloride concentrations greater than about 10 parts per million (ppm), apparent TOX values increase with increasing chloride concentration. A parallel observation is the increase in apparent breakthrough of TOX from the first to the second activated-carbon adsorption tubes with increasing inorganic chloride concentration. (2) During the sample preparation step, excessive purging of the adsorption tubes with oxygen pressurization gas after sample loading may cause channeling in the activated-carbon bed. This channeling leads to poor removal of inorganic chloride during the subsequent wash step with aqueous potassium nitrate. The presence of this residual inorganic chloride then produces erroneously high TOX values. Changes in sample preparation were studied to more effectively remove inorganic chloride from the activated carbon adsorption tubes. With the TOX sample preparation equipment and TOX analyzers at WSCF, the nitrate wash recommended by EPA SW-846 method 9020B was found to be inadequate to remove inorganic chloride interference. Increasing the nitrate wash concentration from 10 grams per liter (g/L) to 100 g/L potassium nitrate and increasing the nitrate wash volume from 3 milliliters (mL) to 10 mL effectively removed the inorganic chloride up to at least 100 ppm chloride in the sample matrix. Excessive purging of the adsorption tubes during sample preparation was eliminated. These changes in sample preparation have been incorporated in the analytical procedure. The results using the revised sample preparation procedure show better agreement of TOX values both for replicate analyses of single samples and for the analysis of replicate samples acquired from the same groundwater well. Furthermore, less apparent column breakthrough now occurs with the revised procedure. One additional modification made to sample preparation was to discontinue the treatment of groundwater samples with sodium bisulfite. Sodium bisulfite is used to remove inorganic chlorine from the sample; inorganic chlorine is not expected to be a constituent in these groundwater samples. Several other factors were also investigated as possible sources of anomalous TOX results: (1) Instrument instability: examination of the history of results for TOX laboratory control samples and initial calibration verification standards indicate good long-term precision for the method and instrument. Determination of a method detection limit of 2.3 ppb in a deionized water matrix indicates the method and instrumentation have good stability and repeatability. (2) Non-linear instrument response: the instrument is shown to have good linear response from zero to 200 parts per billion (ppb) TOX. This concentration range encompasses the majority of samples received at WSCF for TOX analysis. (3) Improper sample preservation: ion-chromatographic analysis of several samples wit

DOUGLAS JG; MEZNARICH HD, PHD; OLSEN JR; ROSS GA; STAUFFER M

2008-09-30T23:59:59.000Z

342

INVESTIGATION OF THE TOTAL ORGANIC HALOGEN ANALYTICAL METHOD AT THE WASTE SAMPLING AND CHARACTERIZATION FACILITY  

SciTech Connect (OSTI)

Total organic halogen (TOX) is used as a parameter to screen groundwater samples at the Hanford Site. Trending is done for each groundwater well, and changes in TOX and other screening parameters can lead to costly changes in the monitoring protocol. The Waste Sampling and Characterization Facility (WSCF) analyzes groundwater samples for TOX using the United States Environmental Protection Agency (EPA) SW-S46 method 9020B (EPA 1996a). Samples from the Soil and Groundwater Remediation Project (SGRP) are submitted to the WSCF for analysis without information regarding the source of the sample; each sample is in essence a ''blind'' sample to the laboratory. Feedback from the SGRP indicated that some of the WSCF-generated TOX data from groundwater wells had a number of outlier values based on the historical trends (Anastos 200Sa). Additionally, analysts at WSCF observed inconsistent TOX results among field sample replicates. Therefore, the WSCF lab performed an investigation of the TOX analysis to determine the cause of the outlier data points. Two causes were found that contributed to generating out-of-trend TOX data: (1) The presence of inorganic chloride in the groundwater samples: at inorganic chloride concentrations greater than about 10 parts per million (ppm), apparent TOX values increase with increasing chloride concentration. A parallel observation is the increase in apparent breakthrough of TOX from the first to the second activated-carbon adsorption tubes with increasing inorganic chloride concentration. (2) During the sample preparation step, excessive purging of the adsorption tubes with oxygen pressurization gas after sample loading may cause channeling in the activated carbon bed. This channeling leads to poor removal of inorganic chloride during the subsequent wash step with aqueous potassium nitrate. The presence of this residual inorganic chloride then produces erroneously high TOX values. Changes in sample preparation were studied to more effectively remove inorganic chloride from the activated-carbon adsorption tubes. With the TOX sample preparation equipment and TOX analyzers at WSCF, the nitrate wash recommended by EPA SW-846 method 9020B was found to be inadequate to remove inorganic chloride interference. Increasing the nitrate wash concentration from 10 grams per liter (g/L) to 100 giL potassium nitrate and increasing the nitrate wash volume from 3 milliliters (mL) to 10 mL effectively removed the inorganic chloride up to at least 100 ppm chloride in the sample matrix. Excessive purging of the adsorption tubes during sample preparation was eliminated. These changes in sample preparation have been incorporated in the analytical procedure. The results using the revised sample preparation procedure show better agreement of TOX values both for replicate analyses of single samples and for the analysis of replicate samples acquired from the same groundwater well. Furthermore, less apparent adsorption tube breakthrough now occurs with the revised procedure. One additional modification made to sample preparation was to discontinue the treatment of groundwater samples with sodium bisulfite. Sodium bisulfite is used to remove inorganic chlorine from the sample; inorganic chlorine is not expected to be a constituent in these groundwater samples. Several other factors were also investigated as possible sources of anomalous TOX results: (1) Instrument instability: examination of the history of results for TOX laboratory control samples and initial calibration verification standards indicate good long-term precision for the method and instrument. Determination of a method detection limit of 2.3 ppb in a deionized water matrix indicates the method and instrumentation have good stability and repeatability. (2) Non-linear instrument response: the instrument is shown to have good linear response from zero to 200 parts per billion (ppb) TOX. This concentration range encompasses the majority of samples received at WSCF for TOX analysis. Linear response was checked using both non-volatile TOX species (trichlorophenol) an

JG DOUGLAS; HK MEZNARICH, PHD; JR OLSEN; GA ROSS PHD; M STAUFFER

2009-02-13T23:59:59.000Z

343

Impacts of halogen additions on mercury oxidation, in a slipstream selective catalyst reduction (SCR), reactor when burning sub-bituminous coal  

SciTech Connect (OSTI)

This paper presents a comparison of impacts of halogen species on the elemental mercury (Hg(0)) oxidation in a real coal-derived flue gas atmosphere. It is reported there is a higher percentage of Hg(0) in the flue gas when burning sub-bituminous coal (herein Powder River Basin (PRB) coal) and lignite, even with the use of selective catalytic reduction (SCR). The higher Hg(0) concentration in the flue gas makes it difficult to use the wet-FGD process for the mercury emission control in coal-fired utility boilers. Investigation of enhanced Hg(0) oxidation by addition of hydrogen halogens (HF, HCl, HBr, and HI) was conducted in a slipstream reactor with and without SCR catalysts when burning PRB coal. Two commercial SCR catalysts were evaluated. SCR catalyst no. 1 showed higher efficiencies of both NO reduction and Hg(0) oxidation than those of SCR catalyst no. 2. NH{sub 3} addition seemed to inhibit the Hg(0) oxidation, which indicated competitive processes between NH{sub 3} reduction and Hg(0) oxidation on the surface of SCR catalysts. The hydrogen halogens, in the order of impact on Hg(0) oxidation, were HBr, HI, and HCl or HF. Addition of HBr at approximately 3 ppm could achieve 80% Hg(0) oxidation. Addition of HI at approximately 5 ppm could achieve 40% Hg(0) oxidation. In comparison to the empty reactor, 40% Hg(0) oxidation could be achieved when HCl addition was up to 300 ppm. The enhanced Hg(0) oxidation by addition of HBr and HI seemed not to be correlated to the catalytic effects by both evaluated SCR catalysts. The effectiveness of conversion of hydrogen halogens to halogen molecules or interhalogens seemed to be attributed to their impacts on Hg(0) oxidation. 30 refs., 4 figs.

Yan Cao; Zhengyang Gao; Jiashun Zhu; Quanhai Wang; Yaji Huang; Chengchung Chiu; Bruce Parker; Paul Chu; Wei-ping Pan [Western Kentucky University (WKU), Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

2008-01-01T23:59:59.000Z

344

The effect of spin-orbit splitting on the association kinetics of barrierless halogen atom-hydrocarbon radical reactions.  

SciTech Connect (OSTI)

The effect of the geometry dependence of spin-orbit splitting on transition state theory (TST) predictions for radical-radical recombination rate coefficients is examined. The effects are illustrated with direct ab initio variable-reaction-coordinate (VRC)-TST calculations for the reactions of two types of hydrocarbon radicals (R = CH{sub 3} and CH{sub 2}CHCH{sub 2}) with three halogen atoms (X = F, Cl, and Br). These halogen atoms exhibit a range of spin-orbit interaction strengths, while their interactions with the two hydrocarbon radicals exhibit a range of attractiveness. The transition state dividing surfaces for these barrierless reactions occur over a range of R-X fragment separations ({approx}3-7 {angstrom}) where the magnitude of the spin-orbit splitting is strongly geometry dependent. Perturbative models for incorporating the energetic effect of spin-orbit splitting into barrierless kinetics are presented and tested. Simply neglecting the variation in the spin-orbit splitting is demonstrated to contribute an error of less than 15% to the predicted rate coefficients for all but the CH{sub 2}CHCH{sub 2} + Br reaction, where its neglect increases the rate by up to a factor of 2. For the CH{sub 2}CHCH{sub 2} + Br reaction, the effect of spin-orbit splitting is not perturbative and instead qualitatively changes the long-range interaction potential and association dynamics. The present theoretical predictions are compared with available experimental measurements and previous theoretical work. For the CH{sub 3} + F association reaction, the errors associated with limitations in the basis set and in the active space are studied, and a detailed comparison is made between VRC-TST and rigid rotor-harmonic oscillator variational TST.

Jasper, A. W.; Klippenstein, S. J.; Harding, L. B. (Chemical Sciences and Engineering Division); (SNL)

2010-01-01T23:59:59.000Z

345

Detection and Differentiation of Neutral Organic Compounds by [superscript 19]F NMR with a Tungsten Calix[4]arene Imido Complex  

E-Print Network [OSTI]

Fluorinated tungsten calix[4]arene imido complexes were synthesized and used as receptors to detect and differentiate neutral organic compounds. It was found that the binding of specific neutral organic molecules to the ...

Zhao, Yanchuan

346

GENERATION, TRANSPORT AND DEPOSITION OF TUNGSTEN-OXIDE AEROSOLS AT 1000 C IN FLOWING AIR-STEAM MIXTURES.  

SciTech Connect (OSTI)

Experiments were conducted to measure the rates of oxidation and vaporization of pure tungsten rods in flowing air, steam and air-steam mixtures in laminar flow. Also measured were the downstream transport of tungsten-oxide condensation aerosols and their region of deposition, including plateout in the superheated flow tube, rainout in the condenser and ambient discharge which was collected on an array of sub-micron aerosol filters. The nominal conditions of the tests, with the exception of the first two tests, were tungsten temperatures of 1000 C, gas mixture temperatures of 200 C and wall temperatures of 150 C to 200 C. It was observed that the tungsten oxidation rates were greatest in all air and least in all steam, generally decreasing non-linearly with increasing steam mole fraction. The tungsten oxidation rates in all air were more than five times greater than the tungsten oxidation rates in all steam. The tungsten vaporization rate was zero in all air and increased with increasing steam mole fraction. The vaporization rate became maximum at a steam mole fraction of 0.85 and decreased thereafter as the steam mole fraction was increased to unity. The tungsten-oxide was transported downstream as condensation aerosols, initially flowing upwards from the tungsten rod through an 18-inch long, one-inch diameter quartz tube, around a 3.5-inch radius, 90{sup o} bend and laterally through a 24-inch horizontal run. The entire length of the quartz glass flow path was heated by electrical resistance clamshell heaters whose temperatures were individually controlled and measured. The tungsten-oxide plateout in the quartz tube was collected, nearly all of which was deposited at the end of the heated zone near the entrance to the condenser which was cold. The tungsten-oxide which rained out in the condenser as the steam condensed was collected with the condensate and weighed after being dried. The aerosol smoke which escaped the condenser was collected on the sub-micron filter assemblies. There was no aerosol generation for the case of all air, so the plateout, condensate and smoke were all zero. For the case of all steam, there was very little plateout in the superheated regions (several percent) and the rest of the aerosol was collected in the condensate from the condenser. There was no smoke discharge into the filters. For the experiments with intermediate air-steam fractions, there was some aerosol plateout, considerable aerosol in the condensate and aerosol smoke discharged from the condenser with the escaping air.

GREENE,G.A.; FINFROCK,C.C.

2001-10-01T23:59:59.000Z

347

The Time Structure of Hadronic Showers in highly granular Calorimeters with Tungsten and Steel Absorbers  

E-Print Network [OSTI]

The intrinsic time structure of hadronic showers influences the timing capability and the required integration time of hadronic calorimeters in particle physics experiments, and depends on the active medium and on the absorber of the calorimeter. With the CALICE T3B experiment, a setup of 15 small plastic scintillator tiles read out with Silicon Photomultipliers, the time structure of showers is measured on a statistical basis with high spatial and temporal resolution in sampling calorimeters with tungsten and steel absorbers. The results are compared to GEANT4 (version 9.4 patch 03) simulations with different hadronic physics models. These comparisons demonstrate the importance of using high precision treatment of low-energy neutrons for tungsten absorbers, while an overall good agreement between data and simulations for all considered models is observed for steel.

Adloff, C; Chefdeville, M.; Drancourt, C.; Gaglione, R.; Geffroy, N.; Karyotakis, Y.; Koletsou, I.; Prast, J.; Vouters, G.; Repond, J.; Schlereth, J.; Xia, L.; Baldolemar, E.; Li, J.; Park, S.T.; Sosebee, M.; White, A.P.; Yu, J.; Eigen, G.; Thomson, M.A.; Ward, D.R.; Benchekroun, D.; Hoummada, A.; Khoulaki, Y.; Apostolakis, J.; Arfaoui, A.; Benoit, M.; Dannheim, D.; Elsener, K.; Folger, G.; Grefe, C.; Ivantchenko, V.; Killenberg, M.; Klempt, W.; van der Kraaij, E.; Linssen, L.; Lucaci-Timoce, A.-I.; Münnich, A.; Poss, S.; Ribon, A.; Roloff, P.; Sailer, A.; Schlatter, D.; Sicking, E.; Strube, J.; Uzhinskiy, V.; Carloganu, C.; Gay, P.; Manen, S.; Royer, L.; Cornett, U.; David, D.; Ebrahimi, A.; Falley, G.; Feege, N.; Gadow, K.; Göttlicher, P.; Günter, C.; Hartbrich, O.; Hermberg, B.; Karstensen, S.; Krivan, F.; Krüger, K.; Lu, S.; Lutz, B.; Morozov, S.; Morgunov, V.; Neubüser, C.; Reinecke, M.; Sefkow, F.; Smirnov, P.; Terwort, M.; Fagot, A.; Tytgat, M.; Zaganidis, N.; Hostachy, J.-Y.; Morin, L.; Garutti, E.; Laurien, S.; Marchesini, I.; Matysek, M.; Ramilli, M.; Briggl, K.; Eckert, P.; Harion, T.; Schultz-Coulon, H.-Ch.; Shen, W.; Stamen, R.; Chang, S.; Khan, A.; Kim, D.H.; Kong, D.J.; Oh, Y.D.; Bilki, B.; Norbeck, E.; Northacker, D.; Onel, Y.; Wilson, G.W.; Kawagoe, K.; Miyazaki, Y.; Sudo, Y.; Ueno, H.; Yoshioka, T.; Dauncey, P.D.; Cortina Gil, E.; Mannai, S.; Baulieu, G.; Calabria, P.; Caponetto, L.; Combaret, C.; Della Negra, R.; Ete, R.; Grenier, G.; Han, R.; Ianigro, J-C.; Kieffer, R.; Laktineh, I.; Lumb, N.; Mathez, H.; Mirabito, L.; Petrukhin, A.; Steen, A.; Tromeur, W.; Vander Donckt, M.; Zoccarato, Y.; Berenguer Antequera, J.; Calvo Alamillo, E.; Fouz, M.-C.; Puerta-Pelayo, J.; Corriveau, F.; Bobchenko, B.; Chadeeva, M.; Danilov, M.; Epifantsev, A.; Markin, O.; Mizuk, R.; Novikov, E.; Rusinov, V.; Tarkovsky, E.; Kozlov, V.; Soloviev, Y.; Besson, D.; Buzhan, P.; Ilyin, A.; Kantserov, V.; Kaplin, V.; Popova, E.; Tikhomirov, V.; Gabriel, M.; Kiesling, C.; Seidel, K.; Simon, F.; Soldner, C.; Szalay, M.; Tesar, M.; Weuste, L.; Amjad, M.S.; Bonis, J.; Conforti di Lorenzo, S.; Cornebise, P.; Fleury, J.; Frisson, T.; van der Kolk, N.; Richard, F.; Pöschl, R.; Rouene, J.; Anduze, M.; Balagura, V.; Becheva, E.; Boudry, V.; Brient, J-C.; Cornat, R.; Frotin, M.; Gastaldi, F.; Guliyev, E.; Haddad, Y.; Magniette, F.; Ruan, M.; Tran, T.H.; Videau, H.; Callier, S.; Dulucq, F.; Martin-Chassard, G.; de la Taille, Ch.; Raux, L.; Seguin-Moreau, N.; Zacek, J.; Cvach, J.; Gallus, P.; Havranek, M.; Janata, M.; Kvasnicka, J.; Lednicky, D.; Marcisovsky, M.; Polak, I.; Popule, J.; Tomasek, L.; Tomasek, M.; Ruzicka, P.; Sicho, P.; Smolik, J.; Vrba, V.; Zalesak, J.; Belhorma, B.; Ghazlane, H.; Kotera, K.; Ono, H.; Takeshita, T.; Uozumi, S.; Chai, J.S.; Song, H.S.; Lee, S.H.; Götze, M.; Sauer, J.; Weber, S.; Zeitnitz, C.

2014-01-01T23:59:59.000Z

348

Operational Experience and First Results with a Highly Granular Tungsten Analog Hadron Calorimeter  

E-Print Network [OSTI]

Precision physics at future multi-TeV lepton colliders such as CLIC requires excellent jet energy resolution. The detectors need deep calorimeter systems to limit the energy leakage also for very highly energetic particles and jets. At the same time, compact physical dimensions are mandatory to permit the installation of the complete calorimeter system inside high-field solenoidal magnets. This requires very dense absorbers, making tungsten a natural choice for hadron calorimeters at such a future collider. To study the performance of such a calorimeter, a physics prototype with tungsten absorbers and scintillator tiles with SiPM readout as active elements has been constructed and has been tested in particle beams at CERN over a wide energy range from 1 GeV to 300 GeV. We report on the construction and on the operational experience obtained with muon, electron and hadron beams.

Frank Simon; for the CALICE Collaboration

2011-11-22T23:59:59.000Z

349

Tungsten injector for scrape-off layer impurity transport experiments in the Tore Supra tokamak  

SciTech Connect (OSTI)

This paper describes the design and operation of a new tungsten (W) injection system for impurity transport experiments in the Tore Supra tokamak. The system is mounted on a reciprocating manipulator and injects a controlled amount of gaseous tungsten hexacarbonyl, W(CO){sub 6} at arbitrary depth in the scrape-off layer, using an inertially activated valve. Injected W(CO){sub 6} is dissociated in the plasma, forming a radially localized plume of W atoms. The injector does not require an external gas feed and can perform a large number of injections from an on-board reservoir of W(CO){sub 6}. Some examples of W injections in Tore Supra are included, demonstrating successful operation and discussing some technical issues of the injector prototype.

Ko?an, M.; Lunt, T. [Max-Planck-Institut für Plasmaphysik, EURATOM Association Boltzmannstr. 2, D-85748 Garching (Germany)] [Max-Planck-Institut für Plasmaphysik, EURATOM Association Boltzmannstr. 2, D-85748 Garching (Germany); Gunn, J. P.; Meyer, O.; Pascal, J.-Y. [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France)] [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France)

2013-07-15T23:59:59.000Z

350

The Time Structure of Hadronic Showers in highly granular Calorimeters with Tungsten and Steel Absorbers  

E-Print Network [OSTI]

The intrinsic time structure of hadronic showers influences the timing capability and the required integration time of hadronic calorimeters in particle physics experiments, and depends on the active medium and on the absorber of the calorimeter. With the CALICE T3B experiment, a setup of 15 small plastic scintillator tiles read out with Silicon Photomultipliers, the time structure of showers is measured on a statistical basis with high spatial and temporal resolution in sampling calorimeters with tungsten and steel absorbers. The results are compared to GEANT4 (version 9.4 patch 03) simulations with different hadronic physics models. These comparisons demonstrate the importance of using high precision treatment of low-energy neutrons for tungsten absorbers, while an overall good agreement between data and simulations for all considered models is observed for steel.

C. Adloff; J. -J. Blaising; M. Chefdeville; C. Drancourt; R. Gaglione; N. Geffroy; Y. Karyotakis; I. Koletsou; J. Prast; G. Vouters J. Repond; J. Schlereth; L. Xia E. Baldolemar; J. Li; S. T. Park; M. Sosebee; A. P. White; J. Yu; G. Eigen; M. A. Thomson; D. R. Ward; D. Benchekroun; A. Hoummada; Y. Khoulaki J. Apostolakis; S. Arfaoui; M. Benoit; D. Dannheim; K. Elsener; G. Folger; C. Grefe; V. Ivantchenko; M. Killenberg; W. Klempt; E. van der Kraaij; L. Linssen; A. -I. Lucaci-Timoce; A. Münnich; S. Poss; A. Ribon; P. Roloff; A. Sailer; D. Schlatter; E. Sicking; J. Strube; V. Uzhinskiy; C. Carloganu; P. Gay; S. Manen; L. Royer; U. Cornett; D. David; A. Ebrahimi; G. Falley; N. Feege; K. Gadow; P. Göttlicher; C. Günter; O. Hartbrich; B. Hermberg; S. Karstensen; F. Krivan; K. Krüger; S. Lu; B. Lutz; S. Morozov; V. Morgunov; C. Neubüser; M. Reinecke; F. Sefkow; P. Smirnov; M. Terwort; A. Fagot; M. Tytgat; N. Zaganidis; J. -Y. Hostachy; L. Morin; E. Garutti; S. Laurien; I. Marchesini; M. Matysek; M. Ramilli; K. Briggl; P. Eckert; T. Harion; H. -Ch. Schultz-Coulon; W. Shen; R. Stamen; S. Chang; A. Khan; D. H. Kim; D. J. Kong; Y. D. Oh; B. Bilki; E. Norbeck; D. Northacker; Y. Onel; G. W. Wilson; K. Kawagoe; Y. Miyazaki; Y. Sudo; H. Ueno; T. Yoshioka; P. D. Dauncey; E. Cortina Gil; S. Mannai; G. Baulieu; P. Calabria; L. Caponetto; C. Combaret; R. Della Negra; R. Ete; G. Grenier; R. Han; J-C. Ianigro; R. Kieffer; I. Laktineh; N. Lumb; H. Mathez; L. Mirabito; A. Petrukhin; A. Steen; W. Tromeur; M. Vander Donckt; Y. Zoccarato J. Berenguer Antequera; E. Calvo Alamillo; M. -C. Fouz; J. Puerta-Pelayo; F. Corriveau; B. Bobchenko; M. Chadeeva; M. Danilov; A. Epifantsev; O. Markin; R. Mizuk; E. Novikov; V. Rusinov; E. Tarkovsky; V. Kozlov; Y. Soloviev; D. Besson; P. Buzhan; A. Ilyin; V. Kantserov; V. Kaplin; E. Popova; V. Tikhomirov; M. Gabriel; C. Kiesling; K. Seidel; F. Simon; C. Soldner; M. Szalay; M. Tesar; L. Weuste; M. S. Amjad; J. Bonis; S. Conforti di Lorenzo; P. Cornebise; J. Fleury; T. Frisson; N. van der Kolk; F. Richard; R. Pöschl; J. Rouene; M. Anduze; V. Balagura; E. Becheva; V. Boudry; J-C. Brient; R. Cornat; M. Frotin; F. Gastaldi; E. Guliyev; Y. Haddad; F. Magniette; M. Ruan; T. H. Tran; H. Videau; S. Callier; F. Dulucq; G. Martin-Chassard; Ch. de la Taille; L. Raux; N. Seguin-Moreau; J. Zacek; J. Cvach; P. Gallus; M. Havranek; M. Janata; J. Kvasnicka; D. Lednicky; M. Marcisovsky; I. Polak; J. Popule; L. Tomasek; M. Tomasek; P. Ruzicka; P. Sicho; J. Smolik; V. Vrba; J. Zalesak; . Belhorma; H. Ghazlane; K. Kotera; H. Ono; T. Takeshita; S. Uozumi; J. S. Chai; H. S. Song; S. H. Lee; M. Götze; J. Sauer; S. Weber; C. Zeitnitz

2014-07-21T23:59:59.000Z

351

High Strain and Strain-Rate Behaviour of PTFE/Aluminium/Tungsten Mixtures  

E-Print Network [OSTI]

Conventional drop-weight techniques were modified to accommodate low-amplitude force transducer signals from low-strength, cold isostatically pressed 'heavy' composites of polytetrafluoroethylene, aluminum and tungsten. The failure strength, strain and the post-critical behavior of failed samples were measured for samples of different porosity and tungsten grain size. Unusual phenomenon of significantly higher strength (55 MPa) of porous composites (density 5.9 g/cc) with small W particles (less than 1 micron) in comparison with strength (32 MPa) of dense composites (7.1 g/cc) with larger W particles (44 microns) at the same volume content of components was observed. This is attributed to force chains created by a network of small W particles. Interrupted tests at different levels of strain revealed the mechanisms of fracture under dynamic compression.

John Addiss; Jing Cai; Stephen Walley; William Proud; Vitali F. Nesterenko

2007-11-08T23:59:59.000Z

352

Test and characterization of a prototype silicon-tungsten electromagnetic calorimeter  

E-Print Network [OSTI]

New generation high-energy physics experiments demand high precision tracking and accurate measurements of a large number of particles produced in the collisions of lementary particles and heavy-ions. Silicon-tungsten (Si-W) calorimeters provide the most viable technological option to meet the requirements of particle detection in high multiplicity environments. We report a novel Si-W calorimeter design, which is optimized for $\\gamma/\\pi^0$ discrimination up to high momenta. In order to test the feasibility of the calorimeter, a prototype mini-tower was constructed using silicon pad detector arrays and tungsten layers. The performance of the mini-tower was tested using pion and electron beams at the CERN Proton Synchrotron (PS). The experimental results are compared with the results from a detailed GEANT-4 simulation. A linear relationship between the observed energy deposition and simulated response of the mini-tower has been obtained, in line with our expectations.

Sanjib Muhuri; Sourav Mukhopadhyay; Vinay B. Chandratre; Menka Sukhwani; Satyajit Jena; Shuaib Ahmad Khan; Tapan K. Nayak; Jogender Saini; Rama Narayana Singaraju

2014-07-22T23:59:59.000Z

353

Method for determining the hardness of strain hardening articles of tungsten-nickel-iron alloy  

DOE Patents [OSTI]

The present invention is directed to a rapid nondestructive method for determining the extent of strain hardening in an article of tungsten-nickel-iron alloy. The method comprises saturating the article with a magnetic field from a permanent magnet, measuring the magnetic flux emanating from the article, comparing the measurements of the magnetic flux emanating from the article with measured magnetic fluxes from similarly shaped standards of the alloy with known amounts of strain hardening to determine the hardness.

Wallace, Steven A. (Knoxville, TN)

1984-01-01T23:59:59.000Z

354

Electrical conductivities of aluminum, copper, and tungsten observed by an underwater explosion  

SciTech Connect (OSTI)

Conductivities of dense aluminum, copper, and tungsten are evaluated using exploding wire discharges in water. Evolutions of the radius and the electrical resistance of exploding wire are measured together with direct pyrometric estimation of the temperature. The conductivities are evaluated based on the measurements and their density dependence is compared with theoretical predictions at a fixed temperature. The results indicate that regardless of materials, the conductivity has a minimum around 3% of solid density at temperature of 5000 K.

Sasaki, Toru [Department of Electrical Engineering, Nagaoka University of Technology, Kamitomioka 1603-1, Nagaoka, Niigata 940-2188 (Japan); Nakajima, Mitsuo; Kawamura, Tohru; Horioka, Kazuhiko [Department of Energy Sciences, Tokyo Institute of Technology, Nagatsuta 4259, Midori-ku, Yokohama 226-8502 (Japan)

2010-08-15T23:59:59.000Z

355

Control of Gas Tungsten Arc welding pool shape by trace element addition to the weld pool  

DOE Patents [OSTI]

An improved process for Gas Tungsten Arc welding maximizes the depth/width ratio of the weld pool by adding a sufficient amount of a surface active element to insure inward fluid flow, resulting in deep, narrow welds. The process is especially useful to eliminate variable weld penetration and shape in GTA welding of steels and stainless steels, particularly by using a sulfur-doped weld wire in a cold wire feed technique.

Heiple, C.R.; Burgardt, P.

1984-03-13T23:59:59.000Z

356

Pulmonary toxicity after exposure to military-relevant heavy metal tungsten alloy particles  

SciTech Connect (OSTI)

Significant controversy over the environmental and public health impact of depleted uranium use in the Gulf War and the war in the Balkans has prompted the investigation and use of other materials including heavy metal tungsten alloys (HMTAs) as nontoxic alternatives. Interest in the health effects of HMTAs has peaked since the recent discovery that rats intramuscularly implanted with pellets containing 91.1% tungsten/6% nickel/2.9% cobalt rapidly developed aggressive metastatic tumors at the implantation site. Very little is known, however, regarding the cellular and molecular mechanisms associated with the effects of inhalation exposure to HMTAs despite the recognized risk of this route of exposure to military personnel. In the current study military-relevant metal powder mixtures consisting of 92% tungsten/5% nickel/3% cobalt (WNiCo) and 92% tungsten/5% nickel/3% iron (WNiFe), pure metals, or vehicle (saline) were instilled intratracheally in rats. Pulmonary toxicity was assessed by cytologic analysis, lactate dehydrogenase activity, albumin content, and inflammatory cytokine levels in bronchoalveolar lavage fluid 24 h after instillation. The expression of 84 stress and toxicity-related genes was profiled in lung tissue and bronchoalveolar lavage cells using real-time quantitative PCR arrays, and in vitro assays were performed to measure the oxidative burst response and phagocytosis by lung macrophages. Results from this study determined that exposure to WNiCo and WNiFe induces pulmonary inflammation and altered expression of genes associated with oxidative and metabolic stress and toxicity. Inhalation exposure to both HMTAs likely causes lung injury by inducing macrophage activation, neutrophilia, and the generation of toxic oxygen radicals. -- Highlights: ? Intratracheal instillation of W–Ni–Co and W–Ni–Fe induces lung inflammation in rats. ? W–Ni–Co and W–Ni–Fe alter expression of oxidative stress and toxicity genes. ? W–Ni–Co induces a greater oxidative burst response than W–Ni–Fe in lung macrophages.

Roedel, Erik Q., E-mail: Erik.Roedel@amedd.army.mil [Department of General Surgery, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Cafasso, Danielle E., E-mail: Danielle.Cafasso@amedd.army.mil [Department of General Surgery, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Lee, Karen W.M., E-mail: Karen.W.Lee@amedd.army.mil [Department of Clinical Investigation, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Pierce, Lisa M., E-mail: Lisa.Pierce@amedd.army.mil [Department of Clinical Investigation, Tripler Army Medical Center, Honolulu, HI 96859 (United States)

2012-02-15T23:59:59.000Z

357

Fracture and Creep in an All-Tungsten Divertor for ARIES  

E-Print Network [OSTI]

Fracture and Creep in an All- Tungsten Divertor for ARIES Jake Blanchard University of Wisconsin by these designs Fracture Thermal creep #12;The Design #12;Major Input Parameters Parameter Value Units Surface c/a=10 Fracture Results 0 1 2 3 4 5 6 7 8 0 0.2 0.4 0.6 StressIntensity(MPa-m1/2) Crack Depth (mm) c

California at San Diego, University of

358

ACHIEVING THE REQUIRED COOLANT FLOW DISTRIBUTION FOR THE ACCELERATOR PRODUCTION OF TRITIUM (APT) TUNGSTEN NEUTRON SOURCE  

SciTech Connect (OSTI)

The Accelerator Production of Tritium neutron source consists of clad tungsten targets, which are concentric cylinders with a center rod. These targets are arranged in a matrix of tubes, producing a large number of parallel coolant paths. The coolant flow required to meet thermal-hydraulic design criteria varies with location. This paper describes the work performed to ensure an adequate coolant flow for each target for normal operation and residual heat-removal conditions.

D. SIEBE; K. PASAMEHMETOGLU

2000-11-01T23:59:59.000Z

359

Study of electrodeposited nickel-molybdenum, nickel-tungsten, cobalt-molybdenum, and cobalt-tungsten as hydrogen electrodes in alkaline water electrolysis  

SciTech Connect (OSTI)

Electrodeposited nickel-molybdenum, nickel-tungsten, cobalt-molybdenum, and cobalt-tungsten were characterized for the hydrogen evolution reaction (HER) in the electrolysis of 30 w/o KOH alkaline water at 25 C. The rate-determining step (rds) of the HER was suggested based on the Tafel slope of polarization and the capacitance of electrode-solution interface determined by ac impedance measurement. The HER on the nickel- and cobalt-based codeposits was enhanced significantly compared with that o the electrolytic nickel and cobalt with comparable deposit loadings. The decrease in the HER overpotential was more pronounced on the molybdenum-containing codeposits, particularly on cobalt-molybdenum which also showed a high stability. The enhancement of the HER was attributed to both the synergetic composition and the increased active surface of the codeposits. The real electrocatalytic activity of te electrodes and the effect of their and the increased active surface of the codeposits. The real electrocatalytic activity of the electrodes and the effect of their surface increase were distinguished quantitatively. The linear relations between HER overpotential and surface roughness factor of the electrodes on a Y-log(X) plot were obtained experimentally and interpreted based on the Tafel law.

Fan, C.; Piron, D.L.; Sleb, A.; Paradis, P. (Ecole Polytechnique de Montreal, Quebec (Canada). Dept. de Metallurgie et de Genie des Materiaux)

1994-02-01T23:59:59.000Z

360

Growth of tungsten nanoparticles in direct-current argon glow discharges  

SciTech Connect (OSTI)

The growth of nanoparticles from the sputtering of a tungsten cathode in DC argon glow discharges is reported. The study was performed at fixed argon pressure and constant discharge current. The growth by successive agglomerations is evidenced. First, tungsten nanocrystallites agglomerate into primary particles, the most probable size of which being {approx}30 nm. Primary particles of this size are observed for all plasma durations and always remain the most numerous in the discharge. Primary particles quickly agglomerate to form particles with size up to {approx}150 nm. For short plasma duration, log-normal functions describe accurately the dust particle size distributions. On the contrary, for long discharge durations, a second hump appears in the distributions toward large particle sizes. In the meantime, the discharge voltage, electron density, and emission line intensities strongly evolve. Their evolutions can be divided in four separate phases and exhibit unusual distinctive features compared to earlier observations in discharges in which particles were growing. The evolution of the different parameters is explained by a competition between the surface state of the tungsten cathode and the influence of the growing nanoparticles. The differences with sputtering glow discharges and chemically active plasmas suggest that the nanoparticle growth and its influence on discharge parameters is system and material dependent.

Kishor Kumar, K.; Coueedel, L.; Arnas, C. [Laboratoire de Physique des Interactions Ioniques et Moleculaires, CNRS-Aix-Marseille Universite, 13397 Marseille (France)

2013-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Effect of tungsten crystallographic orientation on He-ion-induced surface morphology changes  

SciTech Connect (OSTI)

In order to study the early stages of nanofuzz growth in fusion-plasma-facing tungsten, mirror-polished high-purity tungsten was exposed to 80 eV helium at 1130 C to a fluence of 4 1024 He/m2. The previously smooth surface shows morphology changes, and grains form one of four qualitatively different morphologies: smooth, wavy, pyramidal, or terraced/wide waves. Combining high-resolution scanning electron microscopy (SEM) observations to determine the morphology of each grain with quantitative measurement of the grain's orientation via electron backscatter diffraction (EBSD) in SEM shows that the normal-direction crystallographic orientation of the underlying grain controls the growth morphology. Specifically, near-<001> || normal direction (ND) grains formed pyramids, near-<114> to <112> || ND grains formed wavy and stepped structures, and near-<103> || ND grains remained smooth. Comparisons to control specimens indicate no changes to underlying bulk crystallographic texture, and the effects are attributed to surface energy anisotropy, although, surprisingly, the expected {101} low-energy planes were not the most stable. Future developments to control tungsten texture via thermomechanical processing, ideally obtaining a sharp near- <103> || ND processing texture, may delay the formation of nanofuzz.

Parish, Chad M [ORNL; Hijazi, Hussein Dib [ORNL; Meyer III, Harry M [ORNL; Meyer, Fred W [ORNL

2014-01-01T23:59:59.000Z

362

Measurements of the Time Structure of Hadronic Showers in a Scintillator-Tungsten HCAL  

E-Print Network [OSTI]

For calorimeter applications requiring precise time stamping, the time structure of hadronic showers in the detector is a crucial issue. This applies in particular to detector concepts for CLIC, where a hadronic calorimeter with tungsten absorbers is being considered to achieve a high level of shower containment while satisfying strict space constraints. The high hadronic background from gamma gamma to hadrons processes at 3 TeV in combination with the 2 GHz bunch crossing frequency at CLIC requires good time stamping in the detectors. To provide first measurements of the time structure in a highly granular scintillator-tungsten calorimeter, T3B, a dedicated timing experiment, was installed behind the last layer of the CALICE WHCAL prototype, a 30 layer tungsten scintillator calorimeter. T3B consists of 15 small scintillator cells with embedded silicon photomultipliers, read out with fast digitizers over a time window of 2.4 us, and provides detailed measurements of the time structure of the signal. The offline data reconstruction performs an automatic gain calibration using noise events recorded between physics triggers and allows the determination of the arrival time of each photon at the photon sensor. The T3B setup, its calibration and data reconstruction, as well as first results of the time structure of the calorimeter response for 10 GeV pions recorded at the CERN PS confronted with Geant4 simulations using different physics lists are discussed.

Frank Simon; for the CALICE Collaboration

2011-09-15T23:59:59.000Z

363

Enhanced photoelectrochemical properties of TiO{sub 2} by codoping with tungsten and silver  

SciTech Connect (OSTI)

The Tungsten (W) and Silver (Ag) codoped TiO{sub 2} samples were successfully synthesized by hydrothermal method without any post calcination. To understand the correlation between electronic structure and photocatalytic properties, the synthesized samples were characterized using X-ray diffraction, Brunauer–Emmett–Teller specific surface area, transmission electron microscopy, ultra-violet–visible absorption spectra, and X-ray photoelectron spectroscopy (XPS), and the photocatalytic properties were evaluated under visible light irradiations. Codoping could not induce any changes in the phase and all the synthesized samples displayed pure anatase phase with spherical morphology. Visible light absorptions of the codoped samples were dramatically improved compared to the corresponding mono-doped samples. XPS analysis indicated that the dopant atoms successfully entered the TiO{sub 2} network. Results from the visible light photodegradation experiments showed that tungsten-silver codoped TiO{sub 2} possessed strong ability in photo-degrading methylene blue compared to tungsten doped TiO{sub 2} and silver doped TiO{sub 2}, which was attributed to the smaller particle size, higher specific surface area, enhanced visible light absorption, and improved separation of photogenerated carriers.

Khan, Matiullah, E-mail: matiullahustb@gmail.com [Department of Inorganic Nonmetallic Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Department of Physics, Kohat University of Science and Technology (KUST), Kohat 26000 (Pakistan); Jiang, Peng; Cao, Wenbin, E-mail: wbcao@ustb.edu.cn [Department of Inorganic Nonmetallic Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Li, Jing [State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083 (China)

2014-04-21T23:59:59.000Z

364

A study of tungsten spectra using large helical device and compact electron beam ion trap in NIFS  

SciTech Connect (OSTI)

Tungsten spectra have been observed from Large Helical Device (LHD) and Compact electron Beam Ion Trap (CoBIT) in wavelength ranges of visible to EUV. The EUV spectra with unresolved transition array (UTA), e.g., 6g-4f, 5g-4f, 5f-4d and 5p-4d transitions for W{sup +24-+33}, measured from LHD plasmas are compared with those measured from CoBIT with monoenergetic electron beam ({<=}2keV). The tungsten spectra from LHD are well analyzed based on the knowledge from CoBIT tungsten spectra. The C-R model code has been developed to explain the UTA spectra in details. Radial profiles of EUV spectra from highly ionized tungsten ions have been measured and analyzed by impurity transport simulation code with ADPAK atomic database code to examine the ionization balance determined by ionization and recombination rate coefficients. As the first trial, analysis of the tungsten density in LHD plasmas is attempted from radial profile of Zn-like WXLV (W{sup 44+}) 4p-4s transition at 60.9A based on the emission rate coefficient calculated with HULLAC code. As a result, a total tungsten ion density of 3.5 Multiplication-Sign 10{sup 10}cm{sup -3} at the plasma center is reasonably obtained. In order to observe the spectra from tungsten ions in lower-ionized charge stages, which can give useful information on the tungsten influx in fusion plasmas, the ablation cloud of the impurity pellet is directly measured with visible spectroscopy. A lot of spectra from neutral and singly ionized tungsten are observed and some of them are identified. A magnetic forbidden line from highly ionized tungsten ions has been examined and Cd-like WXXVII (W{sup 26+}) at 3893.7A is identified as the ground-term fine-structure transition of 4f{sup 23}H{sub 5}-{sup 3}H{sub 4}. The possibility of {alpha} particle diagnostic in D-T burning plasmas using the magnetic forbidden line is discussed.

Morita, S.; Goto, M.; Murakami, I. [National Institute for Fusion Science, Toki 509-5292, Gifu (Japan); Department of Fusion Science, Graduate University for Advanced Studies, Toki 509-5292, Gifu (Japan); Dong, C. F.; Kato, D.; Sakaue, H. A.; Oishi, T. [National Institute for Fusion Science, Toki 509-5292, Gifu (Japan); Hasuo, M. [Department of Mechanical Engineering and Science, Graduate School of Engineering, Kyoto University, Kyoto 606-8501 (Japan); Koike, F. [Physics Laboratory, School of Medicine, Kitasato University, Sagamihara 252-0374 (Japan); Nakamura, N. [Institute of Laser Science, University of Electro-Communications, Tokyo 182-8585 (Japan); Sasaki, A. [Quantum Beam Science Directorate, Japan Atomic Energy Research Agency, Kizugawa 619-0215, Kyoto (Japan); Wang, E. H. [Department of Fusion Science, Graduate University for Advanced Studies, Toki 509-5292, Gifu (Japan)

2013-07-11T23:59:59.000Z

365

DIVIMP Tungsten Erosion and Transport Simulations of an ELM Cycle in a JET Type-I ELMy H-mode Plasma  

E-Print Network [OSTI]

DIVIMP Tungsten Erosion and Transport Simulations of an ELM Cycle in a JET Type-I ELMy H-mode Plasma

366

Influence of Atomic Physics on EDGE2D-EIRENE Simulations of JET Divertor Detachment with Carbon and Beryllium/Tungsten Plasma-Facing Components  

E-Print Network [OSTI]

Influence of Atomic Physics on EDGE2D-EIRENE Simulations of JET Divertor Detachment with Carbon and Beryllium/Tungsten Plasma-Facing Components

367

Impact of the Carbon and Tungsten Wall Materials on Deuterium Recycling and Neutral Fuelling in JET using EDGE2D/EIRENE  

E-Print Network [OSTI]

Impact of the Carbon and Tungsten Wall Materials on Deuterium Recycling and Neutral Fuelling in JET using EDGE2D/EIRENE

368

Target Particle and Heat Loads in Low-Triangularity L-mode Plasmas in JET with Carbon and Beryllium/Tungsten Walls  

E-Print Network [OSTI]

Target Particle and Heat Loads in Low-Triangularity L-mode Plasmas in JET with Carbon and Beryllium/Tungsten Walls

369

EFFECTS OF B, C, N, O, P AND S IMPURITIES ON TUNGSTEN ?27[110]{552} AND ?3[110]{112} GRAIN BOUNDARIES  

SciTech Connect (OSTI)

The objective of this research is to support the design of tungsten-based materials with increased fracture resistance using first-principles computational methods.

Setyawan, Wahyu; Kurtz, Richard J.

2013-04-01T23:59:59.000Z

370

Simulation of Tungsten Sputtering with EDGE2D-EIRENE in Low Triangularity L-Mode JET ITER-Like Wall Configuration  

E-Print Network [OSTI]

Simulation of Tungsten Sputtering with EDGE2D-EIRENE in Low Triangularity L-Mode JET ITER-Like Wall Configuration

371

A Bulk Tungsten Tile for JET: Derivation of Power-Handling Performance and Validation of the Thermal Model, in the MARION Facility  

E-Print Network [OSTI]

A Bulk Tungsten Tile for JET: Derivation of Power-Handling Performance and Validation of the Thermal Model, in the MARION Facility

372

Discovery, SAR, and Radiolabeling of Halogenated Benzimidazole Carboxamide Antagonists as Useful Tools for (alpha)4(beta)1 Integrin Expressed on T- and B-cell Lymphomas  

SciTech Connect (OSTI)

The cell surface receptor {alpha}{sub 4}{beta}{sub 1} integrin is an attractive yet poorly understood target for selective diagnosis and treatment of T- and B-cell lymphomas. This report focuses on the rapid microwave preparation of medicinally pertinent benzimidazole heterocycles, structure-activity relationships (SAR) of novel halobenzimidazole carboxamide antagonists 3-6, and preliminary biological evaluation of radioiodinated agents 7, 8, and 18. The I-125 derivative 18 had good tumor uptake (12 {+-} 1% ID/g at 24 h; 4.5 {+-} 1% ID/g at 48 h) and tumor:kidney ratio ({approx}4:1 at 24 h; 2.5:1 at 48 h) in xenograft murine models of B-cell lymphoma. Molecular homology models of {alpha}{sub 4}{beta}{sub 1} integrin have predicted that docked halobenzimidazole carboxamides have the halogen atom in a suitable orientation for halogen-hydrogen bonding. These high affinity ({approx} pM binding) halogenated ligands are attractive tools for medicinal and biological use; the fluoro and iodo derivatives are potential radiodiagnostic ({sup 18}F) or radiotherapeutic ({sup 131}I) agents, whereas the chloro and bromo analogues could provide structural insight into integrin-ligand interactions through photoaffinity cross-linking/mass spectroscopy experiments, as well as co-crystallization X-ray studies.

Carpenter, R D; Natarajan, A; Lau, E Y; Andrei, M; Solano, D M; Lightstone, F C; DeNardo, S J; Lam, K S; Kurth, M J

2010-02-08T23:59:59.000Z

373

Influence of tungsten substitution and oxygen deficiency on the thermoelectric properties of CaMnO{sub 3??}  

SciTech Connect (OSTI)

Polycrystalline tungsten-substituted CaMn{sub 1?x}W{sub x}O{sub 3??} (0.00???x???0.05) powders were synthesized from a polymeric precursor, pressed and sintered to high density. The impact of tungsten substitution on the crystal structure, thermal stability, phase transition, electronic and thermal transport properties is assessed. Tungsten acts as an electron donator and strongly affects high-temperature oxygen stoichiometry. Oxygen vacancies form in the high figure-of-merit (ZT)-region starting from about T?=?1000?K and dominate the carrier concentration and electronic transport far more than the tungsten substitution. The analysis of the transport properties yields that in the investigated regime the band filling is sufficiently high to overcome barriers of polaron transport. Therefore, the Cutler-Mott approach describes the electrical transport more accurately than the Mott approach for small polaron transport. The lattice thermal conductivity near room temperature is strongly suppressed with increasing tungsten concentration due to mass-difference impurity scattering. A ZT of 0.25 was found for x?=?0.04 at 1225?K.

Thiel, Philipp; Eilertsen, James; Populoh, Sascha, E-mail: sascha.populoh@empa.ch; Saucke, Gesine; Shkabko, Andrey; Sagarna, Leyre; Karvonen, Lassi [Laboratory for Solid State Chemistry and Catalysis, Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); Döbeli, Max [Ion Beam Physics, Schafmattstrasse 20, ETH Hönggerberg, Swiss Federal Institute of Technology, CH-8093 Zürich (Switzerland); Weidenkaff, Anke [Laboratory for Solid State Chemistry and Catalysis, Empa, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); Materials Chemistry, Institute for Materials Science, University of Stuttgart, Heisenbergstr. 3, DE-70569 Stuttgart (Germany)

2013-12-28T23:59:59.000Z

374

genBRDF: Synthesizing Novel Analytic BRDFs with Genetic Programming Figure 1: Comparison of BRDFs modeling the tungsten carbide material from the MERL BRDF database. Each scene consists of a sphere  

E-Print Network [OSTI]

of BRDFs modeling the tungsten carbide material from the MERL BRDF database. Each scene consists that remains between state-of-the-art analytic BRDFs and measured data in the case of tungsten carbide

Weimer, Westley

375

Dielectric and photovoltaic phenomena in tungsten-doped Pb,,Mg1/3Nb2/3...1-xTixO3 crystal  

E-Print Network [OSTI]

Dielectric and photovoltaic phenomena in tungsten-doped Pb,,Mg1/3Nb2/3...1-xTixO3 crystal Chi. The tungsten-doped Pb1-xLax ZryTiz 1-x/4O3 ceramics, i.e., PLZT x/y/z , exhibits a large photovoltaic ef- fect

376

A Solid-State NMR Study of Tungsten Methyl Group Dynamics in [W(5-C5Me5)Me4][PF6  

E-Print Network [OSTI]

A Solid-State NMR Study of Tungsten Methyl Group Dynamics in [W(5-C5Me5)Me4][PF6] Douglas C. Maus Spinning (MAS) 13C and static 2H NMR studies of the dynamics of the methyl groups coordinated to tungsten

Griffin, Robert G.

377

Radiation-Damage Study of a Monocrystalline Tungsten Positron Converter X. Artru, R. Kirsch, IPN, Lyon, France; R. Chehab, LAL, Orsay, France;  

E-Print Network [OSTI]

Radiation-Damage Study of a Monocrystalline Tungsten Positron Converter X. Artru, R. Kirsch, IPN tested on a 0.3 mm thick tungsten monocrystal exposed dur- ing 6 months to the 30 Gev incident electron and the corresponding enhancement in pair production [1, 3]. Their use in linear colliders (LC), where high beam

Paris-Sud XI, Université de

378

The Effect of 800 MeV Proton Irradiation on the Mechanical Properties of Tungsten at Room Temperature and at 475 Degrees C  

SciTech Connect (OSTI)

For the accelerator production of tritium (APT), the accelerator driven transmutation facility (ADTF), and the advanced fuel cycle initiative (AFCI), tungsten is being proposed as a target material to produce neutrons. In this study, tungsten rods were irradiated at the 800MeV Los Alamos Neutron Science Center (LANSCE) proton accelerator for six months.

Maloy, S A.; James, M R.; Sommer, Walter F.; Willcutt, Gordon; Lopez, M; Romero, T J.; Toloczko, Mychailo B.

2005-08-01T23:59:59.000Z

379

The self-propagation high-temperature synthesis (SHS) of ultrafine high purity tungsten powder from scheelite  

SciTech Connect (OSTI)

High-purity tungsten was prepared by self-propagating high-temperature synthesis (SHS) process from a mixture of CaO{center_dot}WO{sub 3} and Mg. The complete reduction of CaO{center_dot}WO{sub 3} required a 33{percent} excess of magnesium over the stoichiometric molar ratio Mg/CaO{center_dot}WO{sub 3} of 3:1. The MgO and CaO in the product was leached with an HCl solution. The product tungsten had a purity of 99.980{percent} which was higher than that of the reactants. The high purity results because the non tungsten reactants and products are volatilized by the high temperatures generated during the rapid exothermic SHS reaction and are dissolved during HCl leaching of the product. {copyright} {ital 1996 Materials Research Society.}

Jung, J.C.; Ko, S.G.; Won, C.W.; Cho, S.S.; Chun, B.S. [Engineering Research Center for Rapidly Solidified Materials, Chungnam National University, Daejeon 305-764 (Korea)

1996-07-01T23:59:59.000Z

380

Shock-less interactions of ablation streams in tungsten wire array z-pinches  

SciTech Connect (OSTI)

Shock-less dynamics were observed during the ablation phase in tungsten wire array experiments carried out on the 1.4 MA, 240 ns MAGPIE generator at Imperial College London. This behaviour contrasts with the shock structures which were seen to dominate in previous experiments on aluminium arrays [Swadling et al., Phys. Plasmas 20, 022705 (2013)]. In this paper, we present experimental results and make comparisons both with calculations of the expected mean free paths for collisions between the ablation streams and with previously published Thomson scattering measurements of the plasma parameters in these arrays [Harvey-Thompson et al., Phys. Plasmas 19, 056303 (2012)].

Swadling, G. F.; Lebedev, S. V.; Hall, G. N.; Suzuki-Vidal, F.; Burdiak, G.; Harvey-Thompson, A. J.; Bland, S. N.; De Grouchy, P.; Khoory, E.; Pickworth, L.; Skidmore, J.; Suttle, L. [The Blackett Laboratory, Imperial College, London SW7 2AZ (United Kingdom)] [The Blackett Laboratory, Imperial College, London SW7 2AZ (United Kingdom)

2013-06-15T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Testing Hadronic Interaction Models using a Highly Granular Silicon-Tungsten Calorimeter  

E-Print Network [OSTI]

A detailed study of hadronic interactions is presented using data recorded with the highly granular CALICE silicon-tungsten electromagnetic calorimeter. Approximately 600,000 selected negatively changed pion events at energies between 2 and 10 GeV have been studied. The predictions of several physics models available within the GEANT4 simulation tool kit are compared to this data. Although a reasonable overall description of the data is observed, there are significant quantitative discrepancies in the longitudinal and transverse distributions of reconstructed energy.

Bilki, B; Schlereth, J; Xia, L; Deng, Z; Li, Y; Wang, Y; Yue, Q; Yang, Z; Eigen, G; Mikami, Y; Price, T; Watson, N K; Thomson, M A; Ward, D R; Benchekroun, D; Hoummada, A; Khoulaki, Y; Cârloganu, C; Chang, S; Khan, A; Kim, D H; Kong, D J; Oh, Y D; Blazey, G C; Dyshkant, A; Francis, K; Lima, J G R; Salcido, P; Zutshi, V; Boisvert, V; Green, B; Misiejuk, A; Salvatore, F; Kawagoe, K; Miyazaki, Y; Sudo, Y; Suehara, T; Tomita, T; Ueno, H; Yoshioka, T; Apostolakis, J; Folger, G; Ivantchenko, V; Ribon, A; Uzhinskiy, V; Cauwenbergh, S; Tytgat, M; Zaganidis, N; Hostachy, J -Y; Morin, L; Gadow, K; Göttlicher, P; Günter, C; Krüger, K; Lutz, B; Reinecke, M; Sefkow, F; Feege, N; Garutti, E; Laurien, S; Lu, S; Marchesini, I; Matysek, M; Ramilli, M; Kaplan, A; Norbeck, E; Northacker, D; Onel, Y; Kim, E J; van Doren, B; Wilson, G W; Wing, M; Bobchenko, B; Chadeeva, M; Chistov, R; Danilov, M; Drutskoy, A; Epifantsev, A; Markin, O; Mizuk, R; Novikov, E; Popov, V; Rusinov, V; Tarkovsky, E; Besson, D; Popova, E; Gabriel, M; Kiesling, C; Simon, F; Soldner, C; Szalay, M; Tesar, M; Weuste, L; Amjad, M S; Bonis, J; Callier, S; di Lorenzo, S Conforti; Cornebise, P; Doublet, Ph; Dulucq, F; Faucci-Giannelli, M; Fleury, J; Frisson, T; Kégl, B; van der Kolk, N; Li, H; Martin-Chassard, G; Richard, F; de la Taille, Ch; Pöschl, R; Raux, L; Rouëné, J; Seguin-Moreau, N; Anduze, M; Balagura, V; Becheva, E; Boudry, V; Brient, J-C; Cornat, R; Frotin, M; Gastaldi, F; Magniette, F; Matthieu, A; de Freitas, P Mora; Videau, H; Augustin, J-E; David, J; Ghislain, P; Lacour, D; Lavergne, L; Zacek, J; Cvach, J; Gallus, P; Havranek, M; Janata, M; Kvasnicka, J; Lednicky, D; Marcisovsky, M; Polak, I; Popule, J; Tomasek, L; Tomasek, M; Ruzicka, P; Sicho, P; Smolik, J; Vrba, V; Zalesak, J; Jeans, D; Götze, M

2014-01-01T23:59:59.000Z

382

Study of the interactions of pions in the CALICE silicon-tungsten calorimeter prototype  

E-Print Network [OSTI]

A prototype silicon-tungsten electromagnetic calorimeter for an ILC detector was tested in 2007 at the CERN SPS test beam. Data were collected with electron and hadron beams in the energy range 8 to 80 GeV. The analysis described here focuses on the interactions of pions in the calorimeter. One of the main objectives of the CALICE program is to validate the Monte Carlo tools available for the design of a full-sized detector. The interactions of pions in the Si-W calorimeter are therefore confronted with the predictions of various physical models implemented in the GEANT4 simulation framework.

C. Adloff; Y. Karyotakis; J. Repond; J. Yu; G. Eigen; Y. Mikami; N. K. Watson; J. A. Wilson; T. Goto; G. Mavromanolakis; M. A. Thomson; D. R. Ward; W. Yan; D. Benchekroun; A. Hoummada; Y. Khoulaki; J. Apostolakis; A. Ribon; V. Uzhinskiy; M. Benyamna; C. Cârloganu; F. Fehr; P. Gay; G. C. Blazey; D. Chakraborty; A. Dyshkant; K. Francis; D. Hedin; J. G. Lima; V. Zutshi; J. -Y. Hostachy; K. Krastev; L. Morin; N. D'Ascenzo; U. Cornett; D. David; R. Fabbri; G. Falley; K. Gadow; E. Garutti; P. Göttlicher; T. Jung; S. Karstensen; A. -I. Lucaci-Timoce; B. Lutz; N. Meyer; V. Morgunov; M. Reinecke; F. Sefkow; P. Smirnov; A. Vargas-Trevino; N. Wattimena; O. Wendt; N. Feege; M. Groll; J. Haller; R. -D. Heuer; S. Morozov; S. Richter; J. Samson; A. Kaplan; H. -Ch. Schultz-Coulon; W. Shen; A. Tadday; B. Bilki; E. Norbeck; Y. Onel; E. J. Kim; G. Kim; D-W. Kim; K. Lee; S. C. Lee; K. Kawagoe; Y. Tamura; P. D. Dauncey; A. -M. Magnan; H. Yilmaz; O. Zorba; V. Bartsch; M. Postranecky; M. Warren; M. Wing; M. G. Green; F. Salvatore; M. Bedjidian; R. Kieffer; I. Laktineh; M. -C. Fouz; D. S. Bailey; R. J. Barlow; M. Kelly; R. J. Thompson; M. Danilov; E. Tarkovsky; N. Baranova; D. Karmanov; M. Korolev; M. Merkin; A. Voronin; A. Frey; S. Lu; K. Seidel; F. Simon; C. Soldner; L. Weuste; J. Bonis; B. Bouquet; S. Callier; P. Cornebise; Ph. Doublet; M. Faucci Giannelli; J. Fleury; H. Li; G. Martin-Chassard; F. Richard; Ch. de la Taille; R. Poeschl; L. Raux; N. Seguin-Moreau; F. Wicek; M. Anduze; V. Boudry; J-C. Brient; G. Gaycken; D. Jeans; P. Mora de Freitas; G. Musat; M. Reinhard; A. Rougé; M. Ruan; J-Ch. Vanel; H. Videau; K-H. Park; J. Zacek; J. Cvach; P. Gallus; M. Havranek; M. Janata; M. Marcisovsky; I. Polak; J. Popule; L. Tomasek; M. Tomasek; P. Ruzicka; P. Sicho; J. Smolik; V. Vrba; J. Zalesak; B. Belhorma; M. Belmir; S. W. Nam; I. H. Park; J. Yang; Jong-Seo Chai; Jong-Tae Kim; Geun-Bum Kim; J. Kang; Y. -J. Kwon

2010-04-28T23:59:59.000Z

383

Testing Hadronic Interaction Models using a Highly Granular Silicon-Tungsten Calorimeter  

E-Print Network [OSTI]

A detailed study of hadronic interactions is presented using data recorded with the highly granular CALICE silicon-tungsten electromagnetic calorimeter. Approximately 600,000 selected negatively changed pion events at energies between 2 and 10 GeV have been studied. The predictions of several physics models available within the GEANT4 simulation tool kit are compared to this data. Although a reasonable overall description of the data is observed, there are significant quantitative discrepancies in the longitudinal and transverse distributions of reconstructed energy.

The CALICE Collaboration; B. Bilki; J. Repond; J. Schlereth; L. Xia; Z. Deng; Y. Li; Y. Wang; Q. Yue; Z. Yang; G. Eigen; Y. Mikami; T. Price; N. K. Watson; M. A. Thomson; D. R. Ward; D. Benchekroun; A. Hoummada; Y. Khoulaki; C. Cârloganu; S. Chang; A. Khan; D. H. Kim; D. J. Kong; Y. D. Oh; G. C. Blazey; A. Dyshkant; K. Francis; J. G. R. Lima; P. Salcido; V. Zutshi; V. Boisvert; B. Green; A. Misiejuk; F. Salvatore; K. Kawagoe; Y. Miyazaki; Y. Sudo; T. Suehara; T. Tomita; H. Ueno; T. Yoshioka; J. Apostolakis; G. Folger; G. Folger; V. Ivantchenko; A. Ribon; V. Uzhinskiy; S. Cauwenbergh; M. Tytgat; N. Zaganidis; J. -Y. Hostachy; L. Morin; K. Gadow; P. Göttlicher; C. Günter; K. Krüger; B. Lutz; M. Reinecke; F. Sefkow; N. Feege; E. Garutti; S. Laurien; S. Lu; I. Marchesini; M. Matysek; M. Ramilli; A. Kaplan; E. Norbeck; D. Northacker; Y. Onel; E. J. Kim; B. van Doren; G. W. Wilson; M. Wing; B. Bobchenko; M. Chadeeva; R. Chistov; M. Danilov; A. Drutskoy; A. Epifantsev; O. Markin; R. Mizuk; E. Novikov; V. Popov; V. Rusinov; E. Tarkovsky; D. Besson; E. Popova; M. Gabriel; C. Kiesling; F. Simon; C. Soldner; M. Szalay; M. Tesar; L. Weuste; M. S. Amjad; J. Bonis; S. Callier; S. Conforti di Lorenzo; P. Cornebise; Ph. Doublet; F. Dulucq; M. Faucci-Giannelli; J. Fleury; T. Frisson; B. Kégl; N. van der Kolk; H. Li; G. Martin-Chassard; F. Richard; Ch. de la Taille; R. Pöschl; L. Raux; J. Rouëné; N. Seguin-Moreau; M. Anduze; V. Balagura; E. Becheva; V. Boudry; J-C. Brient; R. Cornat; M. Frotin; F. Gastaldi; F. Magniette; A. Matthieu; P. Mora de Freitas; H. Videau; J-E. Augustin; J. David; P. Ghislain; D. Lacour; L. Lavergne; J. Zacek; J. Cvach; P. Gallus; M. Havranek; M. Janata; J. Kvasnicka; D. Lednicky; M. Marcisovsky; I. Polak; J. Popule; L. Tomasek; M. Tomasek; P. Ruzicka; P. Sicho; J. Smolik; V. Vrba; J. Zalesak; D. Jeans; M. Götze

2014-11-26T23:59:59.000Z

384

Subchannel thermal-hydraulic modeling of an APT tungsten target rod bundle  

SciTech Connect (OSTI)

The planned target for the Accelerator Production of Tritium (APT) neutron source consists of an array of tungsten rod bundles through which D{sub 2}O coolant flows axially. Here, a scoping analysis of flow through an APT target rod bundle was conducted to demonstrate that lateral cross-flows are important, and therefore subchannel modeling is necessary to accurately predict thermal-hydraulic behavior under boiling conditions. A local reactor assembly code, FLOWTRAN, was modified to model axial flow along the rod bundle as flow through three concentric heated annular passages.

Hamm, L.L.; Shadday, M.A. Jr.

1997-09-01T23:59:59.000Z

385

Parametric Studies Of Weld Quality Of Tungsten Inert Gas Arc Welding Of Stainless Steel  

SciTech Connect (OSTI)

Effect of current and gas flow rate on quality of weld in tungsten inter gas arc welding of austenitic stainless steel has been studied in the present work through experiments and analyses. Butt welded joints have been made by using several levels of current and gas flow rate. The quality of the weld has been evaluated in terms of ultimate and breaking strengths of the welded specimens. The observed data have been interpreted, discussed and analyzed by using Grey--Taguchi methodology. Optimum parametric setting has been predicted and validated as well.

Kumar Pal, Pradip; Nandi, Goutam; Ghosh, Nabendu [Mechanical Engineering Department, Jadavpur University, Kolkata-700032 (India)

2011-01-17T23:59:59.000Z

386

Phases and domain structures in tungsten-doped Pb,,Mg1/3Nb2/3...1-xTixO3 ,,x=0.35... crystal  

E-Print Network [OSTI]

Phases and domain structures in tungsten-doped Pb,,Mg1/3Nb2/3...1-xTixO3 ,,x=0.35... crystal F and piezoelectric response, has the great potential of applications in wireless photoactuators. The tungsten ferroelectric physics of tungsten-doped PMNT single crystals is still unclear. In this study, temperature

387

ANALYSIS OF A CLAD TUNGSTEN TARGET AFTER IRRADIATION IN AN 800 MeV PROTON BEAM S.A. Maloy, M.R. James, W.F. Sommer jr.,  

E-Print Network [OSTI]

Production of Tritium (APT) and the Accelerator Driven Transmutation Facility (ADTF), tungsten is beingANALYSIS OF A CLAD TUNGSTEN TARGET AFTER IRRADIATION IN AN 800 MeV PROTON BEAM S.A. Maloy, M of tungsten are degraded from irradiation in a neutron flux but little work had been performed

McDonald, Kirk

388

Tungsten Nanowire Based Hyperbolic Metamaterial Emitters for Near-field Thermophotovoltaic Applications  

E-Print Network [OSTI]

Recently, near-field radiative heat transfer enhancement across nanometer vacuum gaps has been intensively studied between two hyperbolic metamaterials (HMMs) due to unlimited wavevectors and high photonic density of state. In this work, we theoretically analyze the energy conversion performance of a thermophotovoltaic (TPV) cell made of In0.2Ga0.8Sb when paired with a HMM emitter composed of tungsten nanowire arrays embedded in Al2O3 host at nanometer vacuum gaps. Fluctuational electrodynamics integrated with effective medium theory and anisotropic thin-film optics is used to calculate the near-field radiative heat transfer. It is found that the spectral radiative energy is enhanced by the epsilon-near-zero and hyperbolic modes at different polarizations. As a result, the power output from a semi-infinite TPV cell is improved by 1.85 times with the nanowire HMM emitter over that with a plain tungsten emitter at a vacuum gap of 10 nm. Moreover, by using a thin TPV cell with 10 um thickness, the conversion eff...

Chang, Jui-Yung; Wang, Liping

2014-01-01T23:59:59.000Z

389

Dynamics of tungsten hexacarbonyl, dicobalt octacarbonyl, and their fragments adsorbed on silica surfaces  

SciTech Connect (OSTI)

Tungsten and cobalt carbonyls adsorbed on a substrate are typical starting points for the electron beam induced deposition of tungsten or cobalt based metallic nanostructures. We employ first principles molecular dynamics simulations to investigate the dynamics and vibrational spectra of W(CO){sub 6} and W(CO){sub 5} as well as Co{sub 2}(CO){sub 8} and Co(CO){sub 4} precursor molecules on fully and partially hydroxylated silica surfaces. Such surfaces resemble the initial conditions of electron beam induced growth processes. We find that both W(CO){sub 6} and Co{sub 2}(CO){sub 8} are stable at room temperature and mobile on a silica surface saturated with hydroxyl groups (OH), moving up to half an Angström per picosecond. In contrast, chemisorbed W(CO){sub 5} or Co(CO){sub 4} ions at room temperature do not change their binding site. These results contribute to gaining fundamental insight into how the molecules behave in the simulated time window of 20 ps and our determined vibrational spectra of all species provide signatures for experimentally distinguishing the form in which precursors cover a substrate.

Muthukumar, Kaliappan; Valentí, Roser; Jeschke, Harald O. [Institut für Theoretische Physik, Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438 Frankfurt am Main (Germany)] [Institut für Theoretische Physik, Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438 Frankfurt am Main (Germany)

2014-05-14T23:59:59.000Z

390

Precision Luminosity for $Z^{0}$ Lineshape Measurements with a Silicon-Tungsten Calorimeter  

E-Print Network [OSTI]

The measurement of small-angle Bhabha scattering is used to determine the luminosity at the OPAL interaction point for the LEP I data recorded between 1993 and 1995. The measurement is based on the OPAL Silicon-Tungsten Luminometer which is composed of two calorimeters encircling the LEP beam pipe, on opposite sides of the interaction point. The luminometer detects electrons from small-angle Bhabha scattering at angles between 25 and 58mrad. At LEP center-of-mass energies around the Z0, about half of all Bhabha electrons entering the detector fall within a 79nb fiducial acceptance region. The electromagnetic showers generated in the stack of 1 radiation length tungsten absorber plates are sampled by 608 silicon detectors with 38,912 radial pads of 2.5mm width.The fine segmentation of the detector, combined with the precise knowledge of its physical dimensions, allows the trajectories of incoming 45GeV electrons or photons to be determined with a total systematic error of less than 7microns. We have quantified...

Abbiendi, G; Alexander, Gideon; Allison, J; Anderson, K J; Anderson, S; Arcelli, S; Asai, S; Ashby, S F; Axen, D A; Azuelos, Georges; Ball, A H; Barberio, E; Barlow, R J; Batley, J Richard; Baumann, S; Bechtluft, J; Behnke, T; Bell, K W; Bella, G; Bellerive, A; Bentvelsen, Stanislaus Cornelius Maria; Bethke, Siegfried; Betts, S; Biebel, O; Biguzzi, A; Bloodworth, Ian J; Bock, P; Böhme, J; Boeriu, O; Bonacorsi, D; Boutemeur, M; Braibant, S; Bright-Thomas, P G; Brigliadori, L; Brown, R M; Burckhart, Helfried J; Capiluppi, P; Carnegie, R K; Carter, A A; Carter, J R; Chang, C Y; Charlton, D G; Chrisman, D; Ciocca, C; Clarke, P E L; Clay, E; Cohen, I; Conboy, J E; Cooke, O C; Couchman, J; Couyoumtzelis, C; Coxe, R L; Cuffiani, M; Dado, S; Dallavalle, G M; Dallison, S; Darling, C L; Davis, R; De Jong, S; de Roeck, A; Dervan, P J; Desch, Klaus; Dienes, B; Dixit, M S; Donkers, M; Dubbert, J; Duchovni, E; Duckeck, G; Duerdoth, I P; Estabrooks, P G; Etzion, E; Evans, H; Fabbri, Franco Luigi; Fanfani, A; Fanti, M; Faust, A A; Feld, L; Ferrari, P; Fiedler, F; Fierro, M; Fleck, I; Foucher, M; Frey, A; Fürtjes, A; Futyan, D I; Gagnon, P; Gary, J W; Gascon-Shotkin, S M; Gaycken, G; Geich-Gimbel, C; Giacomelli, G; Giacomelli, P; Giacomelli, R; Gibson, W R; Gingrich, D M; Glenzinski, D A; Goldberg, J; Gorn, W; Grandi, C; Graham, K; Gross, E; Grunhaus, Jacob; Gruwé, M; Hajdu, C; Hanson, G G; Hansroul, M; Hapke, M; Harder, K; Harel, A; Hargrove, C K; Harin-Dirac, M; Hart, P; Hauschild, M; Hawkes, C M; Hawkings, R; Hemingway, Richard J; Herten, G; Heuer, R D; Hildreth, M D; Hill, J C; Hillier, S J; Hobson, P R; Höcker, Andreas; Hoffman, K; Homer, R James; Honma, A K; Horváth, D; Hossain, K R; Howard, R; Hüntemeyer, P; Igo-Kemenes, P; Imrie, D C; Ishii, K; Jacob, F R; Jawahery, A; Jeremie, H; Jimack, Martin Paul; Jones, C R; Jovanovic, P; Junk, T R; Kanaya, N; Kanzaki, J I; Karlen, D A; Kartvelishvili, V G; Kawagoe, K; Kawamoto, T; Kayal, P I; Keeler, Richard K; Kellogg, R G; Kennedy, B W; Kim, D H; Kirk, J; Klier, A; Kobayashi, T; Kobel, M; Kokott, T P; Kolrep, M; Komamiya, S; Kowalewski, R V; Kress, T; Krieger, P; Von Krogh, J; Kühl, T; Kyberd, P; Lai, W P; Lafferty, G D; Lahmann, R; Landsman, Hagar Yaël; Lanske, D; Lauber, J; Lawson, I; Layter, J G; Lee, A M; Lellouch, Daniel; Letts, J; Levinson, L; Liebisch, R; Lillich, J; List, B; Littlewood, C; Lloyd, A W; Lloyd, S L; Loebinger, F K; Long, G D; Losty, Michael J; Lü, J; Ludwig, J; Liu, D; Macchiolo, A; MacPherson, A L; Mader, W F; Mannelli, M; Marcellini, S; Marchant, T E; Martin, A J; Martin, J P; Martínez, G; Mashimo, T; Mättig, P; McDonald, W J; McKenna, J A; McKigney, E A; McMahon, T J; McPherson, R A; Meijers, F; Méndez-Lorenzo, P; Menke, S; Merritt, F S; Mes, H; Meyer, I; Michelini, Aldo; Mihara, S; Mikenberg, G; Miller, D J; Mohr, W; Montanari, A; Mori, T; Müller, U; Nagai, K; Nakamura, I; Neal, H A; Nisius, R; O'Neale, S W; Oakham, F G; Odorici, F; Ögren, H O; Okpara, A N; Oreglia, M J; Orito, S; Palmonari, F; Pásztor, G; Pater, J R; Patrick, G N; Patt, J; Pérez-Ochoa, R; Petzold, S; Pfeifenschneider, P; Pilcher, J E; Pinfold, James L; Plane, D E; Poffenberger, P R; Poli, B; Polok, J; Przybycien, M B; Quadt, A; Raith, B A; Rembser, C; Rick, Hartmut; Robertson, S; Robins, S A; Rodning, N L; Roney, J M; Rosati, S; Roscoe, K; Rossi, A M; Rozen, Y; Runge, K; Runólfsson, O; Rust, D R; Sachs, K; Saeki, T; Sahr, O; Sang, W M; Sarkisyan-Grinbaum, E; Sbarra, C; Schaile, A D; Schaile, O; Scharff-Hansen, P; Schieck, J; Schmitt, B; Schmitt, S; Schöning, A; Schröder, M; Schumacher, M; Schwick, C; Scott, W G; Seuster, R; Shears, T G; Shen, B C; Shepherd-Themistocleous, C H; Sherwood, P; Siroli, G P; Skuja, A; Smith, A M; Snow, G A; Sobie, Randall J; Söldner-Rembold, S; Spagnolo, S; Springer, W; Sproston, M; Stahl, A; Stephens, K; Stoll, K; Strom, D; Ströhmer, R; Surrow, B; Talbot, S D; Taras, P; Tarem, S; Tecchio, M; Teuscher, R; Thiergen, M; Thomas, J; Thomson, M A; Torrence, E; Towers, S; Trefzger, T M; Trigger, I; Trócsányi, Z L; Tsur, E; Turner-Watson, M F; Ueda, I; Van Kooten, R; Vannerem, P; Verzocchi, M; Voss, H; Wäckerle, F; Wagner, A; Wagner, D; Waller, D; Ward, C P; Ward, D R; Watkins, P M; Watson, A T; Watson, N K; Wells, P S; Wermes, N; Wetterling, D; White, J S; Wilson, G W; Wilson, J A; Wyatt, T R; Yamashita, S; Zacek, V; Zer-Zion, D

2000-01-01T23:59:59.000Z

391

Preparation of amorphous electrochromic tungsten oxide and molybdenum oxide by plasma enhanced chemical vapor deposition  

SciTech Connect (OSTI)

Preliminary experiments have been performed to probe the feasibility of using plasma enhanced chemical vapor deposition (PE--CVD) to prepare electrochromic thin films of tungsten oxide and molybdenum oxide by plasma reaction of WF/sub 6/, W(CO)/sub 6/, and Mo(CO)/sub 6/ with oxygen. Thin films produced in a 300 W, electrodeless, radio-frequency (rf), capacitive discharge were found to be electrochromic when tested with either liquid or solid electrolytes. Optical spectroscopy was performed on two electrochromic coatings after Li/sup +/ ion insertion from a propylene carbonate liquid electrolyte. Broad absorption peaks at --900 nm for WO/sub 3/ and 600 nm for MoO/sub 3/ were observed. Optical results for PE--CVD MoO/sub 3/ films differ from those reported for evaporated MoO/sub 3/ films which have an absorption peak at --800 nm. The shorter wavelength absorption in the PE--CVD MoO/sub 3/ films offers the potential for fabricating electrochromic devices with higher contrast ratios and less color change. Optical emission spectroscopy, Auger, and x-ray diffraction analyses indicate these thin film deposits to be predominantly amorphous tungsten and molybdenum oxides.

Tracy, C.E.; Benson, D.K.

1986-09-01T23:59:59.000Z

392

A Conceptual Multi-Megawatt System Based on a Tungsten CERMET Reactor  

SciTech Connect (OSTI)

Abstract. A conceptual reactor system to support Multi-Megawatt Nuclear Electric Propulsion is investigated within this paper. The reactor system consists of a helium cooled Tungsten-UN fission core, surrounded by a beryllium neutron reflector and 13 B4C control drums coupled to a high temperature Brayton power conversion system. Excess heat is rejected via carbon reinforced heat pipe radiators and the gamma and neutron flux is attenuated via segmented shielding consisting of lithium hydride and tungsten layers. Turbine inlet temperatures ranging from 1300 K to 1500 K are investigated for their effects on specific powers and net electrical outputs ranging from 1 MW to 100 MW. The reactor system is estimated to have a mass, which ranges from 15 Mt at 1 MWe and a turbine inlet temperature of 1500 K to 1200 Mt at 100 MWe and a turbine temperature of 1300 K. The reactor systems specific mass ranges from 32 kg/kWe at a turbine inlet temperature of 1300 K and a power of 1 MWe to 9.5 kg/kW at a turbine temperature of 1500 K and a power of 100 MWe.

Jonathan A. Webb; Brian Gross

2011-02-01T23:59:59.000Z

393

Comproportionation of Cationic and Anionic Tungsten Complexes Having an N-Heterocyclic Carbene Ligand to Give the Isolable 17-Electron Tungsten Radical, CpW(CO)2(IMes)•  

SciTech Connect (OSTI)

A series consisting of a tungsten anion, radical and cation, supported by the N-heterocyclic carbene IMes (1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) and spanning formal oxidation states W(0), W(I) and W(II), has been synthesized, isolated, and characterized. Reaction of the hydride CpW(CO)2(IMes)H with KH and 18 crown 6 gives the tungsten anion [CpW(CO)2(IMes)]-[K(18 crown 6)]+. The crystal structure of this complex shows that the K+ interacts not only with the oxygen atoms in the crown ether, but also with the carbonyl oxygens. The electrochemical oxidation of [CpW(CO)2(IMes)]- in acetonitrile is fully reversible (E½ = ?1.65 V vs Cp2Fe+•/0) at all scan rates, indicating that CpW(CO)2(IMes)• is a persistent radical. Hydride transfer from CpW(CO)2(IMes)H to Ph3C+PF6 affords [cis-CpW(CO)2(IMes)(MeCN)]+PF6 . Comproportionation of [CpW(CO)2(IMes)]- with [CpW(CO)2(IMes)(MeCN)]+ gives the 17-electron tungsten radical CpW(CO)2(IMes)•. This complex shows paramagnetically shifted resonances in 1H NMR spectra and has been characterized by IR spectroscopy, low-temperature EPR spectroscopy, and X-ray diffraction. CpW(CO)2(IMes)• is very stable with respect to disproportionation and dimerization. NMR studies of degenerate electron transfer between CpW(CO)2(IMes)• and [CpW(CO)2(IMes)]- are reported. DFT calculations were carried out on CpW(CO)2(IMes)H, as well as on related complexes bearing NHC ligands with N,N´ substituents Me [CpW(CO)2(IMe)H] or H [CpW(CO)2(IH)H] to compare to the experimentally studied IMes complexes with mesityl substituents. These calculations reveal W H homolytic bond dissociation energies (BDEs) to decrease with increasing steric bulk of the NHC ligand, from 67 for CpW(CO)2(IH)H to 64 for CpW(CO)2(IMe)H to 63 kcal/mol for CpW(CO)2(IMes)H. The calculated spin density at W for CpW(CO)2(IMes)• is 0.63. The W radicals CpW(CO)2(IMe)• and CpW(CO)2(IH)• are calculated to form weak W W bonds. The weakly bonded complexes [CpW(CO)2(IMe)]2 and [CpW(CO)2(IH)]2, are predicted to have W-W BDEs of 6 and 18 kcal/mol, respectively, and to dissociate readily to the W-centered radicals CpW(CO)2(IMe)• and CpW(CO)2(IH)•. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Roberts, John A.; Franz, James A.; van der Eide, Edwin F.; Walter, Eric D.; Petersen, Jeffrey L.; DuBois, Daniel L.; Bullock, R. Morris

2011-09-21T23:59:59.000Z

394

Line spectrum and ion temperature measurements from tungsten ions at low ionization stages in large helical device based on vacuum ultraviolet spectroscopy in wavelength range of 500–2200 Å  

SciTech Connect (OSTI)

Vacuum ultraviolet spectra of emissions released from tungsten ions at lower ionization stages were measured in the Large Helical Device (LHD) in the wavelength range of 500–2200 Å using a 3 m normal incidence spectrometer. Tungsten ions were distributed in the LHD plasma by injecting a pellet consisting of a small piece of tungsten metal and polyethylene tube. Many lines having different wavelengths from intrinsic impurity ions were observed just after the tungsten pellet injection. Doppler broadening of a tungsten candidate line was successfully measured and the ion temperature was obtained.

Oishi, T., E-mail: oishi@LHD.nifs.ac.jp; Morita, S.; Goto, M. [National Institute for Fusion Science, 322-6, Oroshi-cho, Toki 509-5292 (Japan); Department of Fusion Science, Graduate University for Advanced Studies, 322-6, Oroshi-cho, Toki 509-5292 (Japan); Huang, X. L.; Zhang, H. M. [Department of Fusion Science, Graduate University for Advanced Studies, 322-6, Oroshi-cho, Toki 509-5292 (Japan)

2014-11-15T23:59:59.000Z

395

Growth and field-emission property of tungsten oxide nanotip arrays Jun Zhou, Li Gong, Shao Zhi Deng,a  

E-Print Network [OSTI]

and Engineering, SunYat-Sen (Zhongshan) University, Guangzhou, 510275, China Rusen Yang and Zhong Lin Wangb School in the threshold field.14­16 Tungsten oxide is a very important semiconductor. It has been found to be of great- tion deposition process. The experimental setup consists of a vacuum chamber 300 mm 400 mm , two copper

Wang, Zhong L.

396

Materials Corrosion and Mitigation Strategies for APT: Corrosion of Tungsten in an 800 MeV Proton Beam at the  

E-Print Network [OSTI]

Materials Corrosion and Mitigation Strategies for APT: Corrosion of Tungsten in an 800 MeV Proton Beam at the Weapons Neutron Research Facility R. Scott Lillard, Darryl P. Butt Materials Corrosion corrosion. Energy deposition and thermal hydraulic calculations predict that the surface temperature

397

By Earle B. Amey Tungsten's unique high-temperature in Metal Bulletin (London). ferrotungsten, carbide powder blends, and  

E-Print Network [OSTI]

). ferrotungsten, carbide powder blends, and properties can be utilized advantageously in the As a result properties of its carbide continue to scrap, and sodium tungstate and away from the provide important items increased in all imported tungsten materials. the cemented carbide end-use sectors that A summary

398

Solution Processed Tungsten Oxide Interfacial Layer for Efficient Hole-Injection in Quantum Dot Light-Emitting Diodes  

E-Print Network [OSTI]

2/2014 Solution Processed Tungsten Oxide Interfacial Layer for Efficient Hole-Injection in Quantum Layer for Efficient Hole-Injection in Quantum Dot Light- Emitting Diodes Xuyong Yang, Evren Mutlugun-based devices, the organic interfacial buffer layers have inferior thermal stability. Efforts to replace PEDOT

Demir, Hilmi Volkan

399

Influence of gas composition on wafer temperature in a tungsten chemical vapor deposition reactor: Experimental measurements, model  

E-Print Network [OSTI]

Influence of gas composition on wafer temperature in a tungsten chemical vapor deposition reactor-wafer, lamp-heated chemical vapor deposition system were used to study the wafer temperature response to gas composition. A physically based simulation procedure for the process gas and wafer temperature was developed

Rubloff, Gary W.

400

Tungsten Coating on Low Activation Vanadium Alloy by Plasma Spray Process  

SciTech Connect (OSTI)

Tungsten (W) coating on fusion candidate V-4Cr-4Ti (NIFS-HEAT-2) substrate was demonstrated with plasma spray process for the purpose of applying to protection of the plasma facing surface of a fusion blanket. Increase in plasma input power and temperature of the substrate was effective to reduce porosity of the coating, but resulted in hardening of the substrate and degradation of impact property at 77 K. The hardening seemed to be due to contamination with gaseous impurities and deformation by thermal stress during the coating process. Since all the samples showed good ductility at room temperature, further heating seems to be acceptable for the vanadium substrate. The fracture stress of the W coating was estimated from bending tests as at least 313 MPa, which well exceeds the design stress for the vanadium structure in fusion blanket.

Nagasaka, Takuya [National Institute for Fusion Science (Japan); Muroga, Takeo [National Institute for Fusion Science (Japan); Noda, Nobuaki [National Institute for Fusion Science (Japan); Kawamura, Masashi [Kawasaki Heavy Industries, LTD (Japan); Ise, Hideo [Kawasaki Heavy Industries, LTD (Japan); Kurishita, Hiroaki [Tohoku University (Japan)

2005-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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to obtain the most current and comprehensive results.


401

THE REMOVAL OF CARBON/BEUTERIUM FROM STAINLESS STEEL AND TUNGSTEN BY TRANSFERRED-ARC CLEANING  

SciTech Connect (OSTI)

Tungsten and stainless steel samples have been contaminated with deuterium and carbon to simulate deposited layers in magnetic-confinement fusion devices. Deuterium and carbon were co-deposited onto the sample surfaces using a deuterium plasma seeded with varying amounts of deuterated methane. Deuterium was also implanted into the samples in an accelerator to simulate hydrogen isotope ion implantation conditions in magnetic confinement fusion devices. Cathodic arc, or transferred-arc (TA) cleaning was employed to remove the deposits from the samples. The samples were characterized by ion beam analysis both before and after cleaning to determine deuterium and carbon concentrations present. The deuterium content was greatly reduced by the cleaning thus demonstrating the possibility of using the TA cleaning technique for removing deuterium and/or tritium from components exposed to D-T fuels. Removal of surface layers and significant reduction of subsurface carbon concentrations was also observed.

K. J. HOLLIS; R. G. CASTRO; ET AL

2001-04-01T23:59:59.000Z

402

Rapid additive manufacturing of MR compatible multipinhole collimators with selective laser melting of tungsten powder  

SciTech Connect (OSTI)

Purpose: The construction of complex collimators with a high number of oblique pinholes is very labor intensive, expensive or is sometimes impossible with the current available techniques (drilling, milling or electric discharge machining). All these techniques are subtractive: one starts from solid plates and the material at the position of the pinholes is removed. The authors used a novel technique for collimator construction, called metal additive manufacturing. This process starts with a solid piece of tungsten on which a first layer of tungsten powder is melted. Each subsequent layer is then melted on the previous layer. This melting is done by selective laser melting at the locations where the CAD design file defines solid material. Methods: A complex collimator with 20 loftholes with 500 {mu}m diameter pinhole opening was designed and produced (16 mm thick and 70 Multiplication-Sign 52 mm{sup 2} transverse size). The density was determined, the production accuracy was measured (GOM ATOS II Triple Scan, Nikon AZ100M microscope, Olympus IMT200 microscope). Point source measurements were done by mounting the collimator on a SPECT detector. Because there is increasing interest in dual-modality SPECT-MR imaging, the collimator was also positioned in a 7T MRI scanner (Bruker Pharmascan). A uniform phantom was acquired using T1, T2, and T2* sequences to check for artifacts or distortion of the phantom images due to the collimator presence. Additionally, three tungsten sample pieces (250, 500, and 750 {mu}m thick) were produced. The density, attenuation (140 keV beam), and uniformity (GE eXplore Locus SP micro-CT) of these samples were measured. Results: The density of the collimator was equal to 17.31 {+-} 0.10 g/cm{sup 3} (89.92% of pure tungsten). The production accuracy ranges from -260 to +650 {mu}m. The aperture positions have a mean deviation of 5 {mu}m, the maximum deviation was 174 {mu}m and the minimum deviation was -122 {mu}m. The mean aperture diameter is 464 {+-} 19 {mu}m. The calculated and measured sensitivity and resolution of point sources at different positions in the field-of-view agree well. The measured and expected attenuation of the three sample pieces are in a good agreement. There was no influence of the 7T magnetic field on the collimator (which is paramagnetic) and minimal distortion was noticed on the MR scan of the uniform phantom. Conclusions: Additive manufacturing is a very promising technique for the production of complex multipinhole collimators and may also be used for producing other complex collimators. The cost of this technique is only related to the amount of powder needed and the time it takes to have the collimator built. The timeframe from design to collimator production is significantly reduced.

Deprez, Karel; Vandenberghe, Stefaan; Van Audenhaege, Karen; Van Vaerenbergh, Jonas; Van Holen, Roel [MEDISIP, Department of Electronics and Information Systems, Ghent University-iMinds-IBiTech, De Pintelaan 185, B-9000 Ghent (Belgium); Layerwise NV, Kapeldreef 60, 3001 Leuven (Belgium); MEDISIP, Department of Electronics and Information Systems, Ghent University-iMinds-IBiTech, De Pintelaan 185, B-9000 Ghent (Belgium)

2013-01-15T23:59:59.000Z

403

Failure of semiclassical models to describe resistivity of nanometric, polycrystalline tungsten films  

SciTech Connect (OSTI)

The impact of electron scattering at surfaces and grain boundaries in nanometric polycrystalline tungsten (W) films was studied. A series of polycrystalline W films ranging in thickness from 10 to 310?nm and lateral grain size from 74 to 133?nm were prepared on thermally oxidized Si. The Fuchs-Sondheimer surface-scattering model and Mayadas-Shatzkes grain-boundary scattering model were employed for quantitative analyses. Predictions from the theoretical models were found to deviate systematically from the experimental data. Possible reasons for the failure of the theoretical models to describe the experimental data are explored. Finally, a discussion of the crucial features lacking from existing models is presented, along with possible avenues for improving the models to result in better agreement with experimental data.

Choi, Dooho [Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Korea Railroad Research Institute, 360-1 Woulam, Uiwang, Kyunggi 437-757 (Korea, Republic of); Liu, Xuan [Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Schelling, Patrick K. [Advanced Materials Processing and Analysis Center and Department of Physics, University of Central Florida, 4000 Central Florida Boulevard, Orlando, Florida 32816 (United States); Coffey, Kevin R. [Department of Materials Science and Engineering, University of Central Florida, 4000 Central Florida Boulevard, Orlando, Florida 32816 (United States); Barmak, Katayun [Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Department of Applied Physics and Applied Mathematics, Columbia University, 500 West 120th Street, New York, New York 10027 (United States)

2014-03-14T23:59:59.000Z

404

On vapor shielding of dust grains of iron, molybdenum, and tungsten in fusion plasmas  

SciTech Connect (OSTI)

The shielding effects of ablation cloud around a small dust grain composed of iron, molybdenum, or tungsten in fusion plasmas are considered. These include collisional dissipation of momentum flux of impinging plasma ions, heat transfer by secondary plasma created due to electron impact ionization of the ablated atoms, and radiative plasma power losses in the ablation cloud. The maximum radius, which limits applicability of existing dust-plasma interaction models neglecting the cloud shielding effects, for dust grains of the considered high-Z metals is calculated as function of plasma parameters. The thermal bifurcation triggered by thermionic electron emission from dust grains, observed for some of the considered materials, is analyzed. The results are compared with previous calculations for dust composed of low-Z fusion related materials, i.e., lithium, beryllium, and carbon.

Brown, B. T.; Smirnov, R. D., E-mail: rsmirnov@ucsd.edu; Krasheninnikov, S. I. [Department of Mechanical and Aerospace Engineering, University of California, San Diego, 9500 Gilman Dr., La Jolla, California 92093-0411 (United States)] [Department of Mechanical and Aerospace Engineering, University of California, San Diego, 9500 Gilman Dr., La Jolla, California 92093-0411 (United States)

2014-02-15T23:59:59.000Z

405

R&D for a highly granular silicon tungsten electromagnetic calorimeter  

E-Print Network [OSTI]

This article reports on first experience with the technological prototype of a highly- granular silicon-tungsten electromagnetic calorimeter as envisaged for the detectors at a future lepton collider. In the focus of the analysis is the performance of a highly integrated Application Specific Integrated Circuit designed to meet the requirements in terms of dynamic range, compactness and power consumption. The beam test results show that the circuit will allow a future detector with a signal over noise ratio of at least 10:1. To minimise the power dissipation the ASIC will be operated in a power pulsed mode. So far no conceptual problem was revealed but the studies show the way for further work. The prototype is read out by a DAQ system conceived to meet the needs of a trigger less system with a huge number of readout cells.

Pöschl, R

2015-01-01T23:59:59.000Z

406

Oxygen plasma immersion ion implantation treatment to enhance data retention of tungsten nanocrystal nonvolatile memory  

SciTech Connect (OSTI)

Data retention characteristics of tungsten nanocrystal (W-NC) memory devices using an oxygen plasma immersion ion implantation (PIII) treatment are investigated. With an increase of oxygen PIII bias voltage and treatment time, the capacitance–voltage hysteresis memory window is increased but the data retention characteristics become degraded. High-resolution transmission electron microscopy images show that this poor data retention is a result of plasma damage on the tunneling oxide layer, which can be prevented by lowering the bias voltage to 7?kV. In addition, by using the elevated temperature retention measurement technique, the effective charge trapping level of the WO{sub 3} film surrounding the W-NCs can be extracted. This measurement reveals that a higher oxygen PIII bias voltage and treatment time induces more shallow traps within the WO{sub 3} film, degrading the retention behavior of the W-NC memory.

Wang, Jer-Chyi, E-mail: jcwang@mail.cgu.edu.tw; Chang, Wei-Cheng; Lai, Chao-Sung, E-mail: cslai@mail.cgu.edu.tw [Department of Electronic Engineering, Chang Gung University, Kweishan 333, Taoyuan, Taiwan (China); Chang, Li-Chun [Department of Material Engineering and Center for Thin Film Technologies and Applications, Ming Chi University of Technology, Taishan 24301, New Taipei City, Taiwan (China); Ai, Chi-Fong; Tsai, Wen-Fa [Institute of Nuclear Energy Research, Atomic Energy Council, Longtan 325, Taoyuan, Taiwan (China)

2014-03-15T23:59:59.000Z

407

Fabrication of ultrafine tungsten-based alloy powders by novel soda reduction process  

SciTech Connect (OSTI)

A novel reduction method has been developed to fabricate ultrafine tungsten heavy alloy powders, with ammonium metatungstate (AMT), iron(II) chloride tetrahydrate (FeCl{sub 2}.4H{sub 2}O), nickel(II) chloride hexahydrate (NiCl{sub 2}.6H{sub 2}O) as source materials and sodium tungstate dihydrate (Na{sub 2}WO{sub 4}.2H{sub 2}O) as a reductant. In the preparation of mixtures the amounts of the source components were chosen so as to obtain alloy of 93W-5Ni-2Fe composition (wt.%). The obtained powders were characterized by X-ray diffraction, XPS, field-emission scanning microscope (FESEM), and chemical composition was analyzed by EDX.

Lee, Dong-Won [Powder Technology Research Group, Korea Institute of Materials Science (KIMS), Changwon, Kyungnam, 641-010 (Korea, Republic of)] [Powder Technology Research Group, Korea Institute of Materials Science (KIMS), Changwon, Kyungnam, 641-010 (Korea, Republic of); Turaev, Farkhod, E-mail: farkhod_2002@yahoo.com [Powder Technology Research Group, Korea Institute of Materials Science (KIMS), Changwon, Kyungnam, 641-010 (Korea, Republic of)] [Powder Technology Research Group, Korea Institute of Materials Science (KIMS), Changwon, Kyungnam, 641-010 (Korea, Republic of); Kim, Ju-Hyeong [Powder Technology Research Group, Korea Institute of Materials Science (KIMS), Changwon, Kyungnam, 641-010 (Korea, Republic of)] [Powder Technology Research Group, Korea Institute of Materials Science (KIMS), Changwon, Kyungnam, 641-010 (Korea, Republic of); Yang, Mingchuan [W-base Heavy Alloy Research Group, Institute of Metal Research (IMR), 72 Wenhua-road, Shenyang, 110016 (China)] [W-base Heavy Alloy Research Group, Institute of Metal Research (IMR), 72 Wenhua-road, Shenyang, 110016 (China)

2010-03-15T23:59:59.000Z

408

A study of tungsten nanopowder formation by self-propagating high-temperature synthesis  

SciTech Connect (OSTI)

Molten salt-assisted self-propagating high-temperature synthesis of nanocrystalline W powder was studied experimentally. The technique involves the reduction of WO{sub 3} in the presence of sodium chloride using three different reducing agents: magnesium (Mg), sodium azide (NaN{sub 3}), and sodium borohydride (NaBH{sub 4}). The effects of the mole fraction of sodium chloride on temperature distributions, combustion parameters, phase compositions, and morphology of the final products were determined. The sodium chloride-assisted method reported here has been found to be effective for lowering combustion temperature and producing uniform and spherical W nanopowders of average particle size around 20-200, 100-200, and 20-50 nm. The effect of combustion temperature on tungsten particle size is discussed, and a sketch describing the chemistry of combustion is proposed.

Nersisyan, H.H.; Won, C.W. [Rapidly Solidified Materials Research Center, Chungnam National University, 220 Gung-Dong, Yuseong, Daejeon 305-764 (Korea, Republic of); Lee, J.H. [Korea Atomic Energy Research Institute (KAERI), 150 Duckjin-Dong, Yuseong, Daejeon 305-353 (Korea, Republic of)

2005-08-01T23:59:59.000Z

409

Causal Factors of Weld Porosity in Gas Tungsten Arc Welding of Powder Metallurgy Produced Titanium Alloys  

SciTech Connect (OSTI)

ORNL undertook an investigation using gas tungsten arc (GTA) welding on consolidated powder metallurgy (PM) titanium (Ti) plate, to identify the causal factors behind observed porosity in fusion welding. Tramp element compounds of sodium and magnesium, residual from the metallothermic reduction of titanium chloride used to produce the titanium, were remnant in the starting powder and were identified as gas forming species. PM-titanium made from revert scrap where sodium and magnesium were absent, showed fusion weld porosity, although to a lesser degree. We show that porosity was attributable to hydrogen from adsorbed water on the surface of the powders prior to consolidation. The removal / minimization of both adsorbed water on the surface of titanium powder and the residues from the reduction process prior to consolidation of titanium powders, are critical to achieve equivalent fusion welding success similar to that seen in wrought titanium produced via the Kroll process.

Muth, Thomas R [ORNL; Yamamoto, Yukinori [ORNL; Frederick, David Alan [ORNL; Contescu, Cristian I [ORNL; Chen, Wei [ORNL; Lim, Yong Chae [ORNL; Peter, William H [ORNL; Feng, Zhili [ORNL

2013-01-01T23:59:59.000Z

410

Manufacturing Spotlight: Boosting American Competitiveness  

Office of Energy Efficiency and Renewable Energy (EERE)

Find out how the Energy Department is helping bring new clean energy technologies to the marketplace and make manufacturing processes more energy efficient.

411

Spotlights Archive | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomenthe House Committee on Energy andDepartment ofAnShare yourAofMayOctoberMayApril

412

Los Alamos Lab: MPA: Spotlight  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and Interfaces Sample6,LocalNuclear SecurityOfficeMatter December

413

Spotlights Archive | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists' Research |RegulationRenewable EnergySouthwest4, 2010 Review ofJanuary 13, 2015

414

Spotlights Archive | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

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415

Spotlights Archive | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

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416

Spotlights Archive | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

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417

Spotlights Archive | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

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418

Spotlights Archive | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

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419

Employee Spotlights | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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420

Catalytic ionic hydrogenation of ketones using tungsten or molybdenum catalysts with increased lifetimes  

DOE Patents [OSTI]

The present invention is a process for the catalytic hydrogenation of ketones and aldehydes to alcohols at low temperatures and pressures using organometallic molybdenum and tungsten complexes and the catalyst used in the process. The reactants include a functional group which is selected from groups represented by the formulas R*(C.dbd.O)R' and R*(C.dbd.O)H, wherein R* and R' are selected from hydrogen or any alkyl or aryl group. The process includes reacting the organic compound in the presence of hydrogen and a catalyst to form a reaction mixture. The catalyst is prepared by reacting Ph.sub.3 C.sup.+ A.sup.- with a metal hydride. A.sup.- represents an anion and can be BF.sub.4.sup.-, PF.sub.6.sup.-, CF.sub.3 SO.sub.3.sup.- or Bar'.sub.4.sup.-, wherein Ar'=3,5-bis(trifluoromethyl)phenyl. The metal hydride is represented by the formula: HM(CO).sub.2 [.eta..sup.5 :.eta..sup.1 --C.sub.5 H.sub.4 (XH.sub.2).sub.n PR.sub.2 ] wherein M represents a molybdenum (Mo) atom or a tungsten (W) atom; X is a carbon atom, a silicon atom or a combination of carbon (C) and silicon (Si) atoms; n is any positive integer; R represents two hydrocarbon groups selected from H, an aryl group and an alkyl group, wherein both R groups can be the same or different. The metal hydride is reacted with Ph.sub.3 C.sup.+ A.sup.- either before reacting with the organic compound or in the reaction mixture.

Bullock, R. Morris; Kimmich, Barbara F.; Fagan, Paul J.; Hauptman, Elisabeth

2003-09-02T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Properties of chemical vapor deposited tungsten silicide films using reaction of WF/sub 6/ and Si/sub 2/H/sub 6/  

SciTech Connect (OSTI)

Tungsten silicide films were formed by the chemical vapor deposition method using the reaction WF/sub 6/ and Si/sub 2/H/sub 6/. The deposition rate, resistivity, composition, stress, crystal structure, and content of impurities were studied and compared with tungsten silicide films deposited by reaction of WF/sub 6/ and SiH/sub 4/. The tungsten silicide films made using Si/sub 2/H/sub 6/ have a higher deposition rate and higher Si concentration than those made by using SiH/sub 4/ at the same substrate temperature. For these reasons, the tungsten silicide films made by using Si/sub 2/H/sub 6/ were found to have a resistivity that is a little higher and, after annealing, a stress that is smaller than that made by SiH/sub 4/.

Shioya, Y.; Ikegami, K.; Kobayashi, I.; Maeda, M.

1987-05-01T23:59:59.000Z

422

Simultaneous impact of neutron irradiation and sputtering on the surface structure of self–damaged ITER–grade tungsten  

SciTech Connect (OSTI)

Simultaneous effects of neutron irradiation and long–term sputtering on the surface relief of ITER–grade tungsten were studied. The effects of neutron–induced displacement damage have been simulated by irradiation of tungsten target with W{sup 6+} ions of 20?MeV energy. Ar{sup +} ions with energy 600?eV were used as imitation of charge exchange atoms in ITER. The surface relief was studied after each sputtering act. The singularity in the WJ–IG surface relief was ascertained experimentally at the first time, which determines the law of roughness extension under sputtering. As follows from the experimental data, the neutron irradiation has not to make a decisive additional contribution in the processes developing under impact of charge exchange atoms only.

Belyaeva, A. I., E-mail: aibelyaeva@mail.ru; Savchenko, A. A. [National Technical University “Kharkov Politechnical Institute”, Kharkov, 61002 (Ukraine); Galuza, A. A.; Kolenov, I. V. [Institute of Electrophysics and Radiation Technologies, National Academy of Science of Ukraine, Kharkov, 61024 (Ukraine)

2014-07-15T23:59:59.000Z

423

The effect of tungsten and molybdenum additions on the cavitation corrosion behavior of duplex stainless steel (DSS) in seawater  

SciTech Connect (OSTI)

Cavitation corrosion studies were conducted on two duplex stainless steel (DSS) specimens of which one was containing tungsten and more molybdenum than the other. Experiments were conducted in seawater using an ultrasonically-induced cavitation facilities. The rate of mass-loss, free corrosion potential, and microscopic examinations were compared for the two alloys in the presence and absence of cavitation. There was negligible mass loss for the two alloys under stagnant conditions. However, some differences were observed between the two alloys with respect to mass-loss, corrosion potential and morphology of attacked areas. The alloy containing tungsten and mover molybdenum experienced more loss in weight regardless of their more noble corrosion potential during cavitation. This difference in behavior was explained in terms of the effect of the alloying elements on the microstructure of the alloys and their susceptibility to absorb the impact energy of cavitation.

Al-Hashem, A.; Abdullah, A.; Shalaby, H.M. [Kuwait Inst. for Scientific Research, Safat (Kuwait). Materials Application Dept.

1998-12-31T23:59:59.000Z

424

Electric Discharge Sintering and Joining of Tungsten Carbide--Cobalt Composite with High-Speed Steel Substrate  

SciTech Connect (OSTI)

Simultaneous electro discharge sintering of high strength structure of tungsten carbide-cobalt composite and connection it with high-speed steel substrate is investigated and suitable operating parameters are defined. Tungsten carbide-cobalt and high-speed steel joining was produced by the method of high voltage electrical discharge together with application of mechanical pressure to powder compact. It was found that the density and hardness of composite material reach its maximum values at certain magnitudes of applied pressure and high voltage electrical discharge parameters. We show that there is an upper level for the discharge voltage beyond which the powder of composite material disintegrates like an exploding wire. Due to our results it is possible to determine optimal parameters for simultaneous electro discharge sintering of WC-Co and bonding it with high-speed steel substrate.

Grigoryev, Evgeny G. [General Physics Department, Moscow Engineering Physics Institute, Kashirskoe sh. 31, Moscow, 115409 (Russian Federation)

2011-01-17T23:59:59.000Z

425

The influence of transition metal solutes on dislocation core structure and values of Peierls stress and barrier in tungsten.  

SciTech Connect (OSTI)

Several transition metals were examined to evaluate their potential for improving the ductility of tungsten. We investigate the dislocation core structure, Peierls stress and barrier of $1/2\\langle111\\rangle$ screw dislocations in binary tungsten-transition metal alloys (W$_{1-x}$TM$_{x}$) based on first principles electronic structure calculations. The periodic quadrupole approach was applied to model the structure of $1/2\\langle111\\rangle$ dislocation. The alloying with transition metals was modeled using the virtual crystal approximation. In order to verify the applicability of this approach, the equilibrium lattice parameter and elastic constants were calculated for tungsten alloyed with the set of transition metals. Reasonable agreement was obtained between results using the virtual crystal approximation and those using both a conventional super-cell approach and existing experimental data. Increasing the concentration of a transition metal from the VIIIA group leads to reduction of the $C^\\prime$ elastic constant and increase of elastic anisotropy A=$C_{44}/C^\\prime$. It was demonstrated that alloying W with a group VIIIA transition metal changes the structure of the dislocation core from symmetric to asymmetric, similar to results obtained for W$_{1-x}$Re$_{x}$ alloys in the earlier work of Romaner {\\it et al} (Phys. Rev. Lett. 104, 195503 (2010)). Following the core symmetry change, the values of the Peierls stress and barrier are reduced. This combination of two effects could lead to increased ductility in a tungsten-based alloy\\comments. Our results demonstrate that similar effects could be achieved with any of the transition metals from the VIIIA group.

Samolyuk, German D [ORNL; Stoller, Roger E [ORNL; Osetskiy, Yury N [ORNL

2013-01-01T23:59:59.000Z

426

Relativistic configuration-interaction calculations of the n=3-3 transition energies in highly charged tungsten ions  

SciTech Connect (OSTI)

A large-scale relativistic configuration-interaction calculation of the n=3-3 transition energies for Ne- to Ar-like tungsten is carried out. The calculation is based on the relativistic no-pair Hamiltonian and uses finite B-spline orbitals in a cavity as basis functions. Quantum electrodynamic and mass polarization corrections are also included. Results are compared with other theories and with experiment, and are generally found to be more reliable than previous theoretical predictions.

Chen, M. H.; Cheng, K. T. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

2011-07-15T23:59:59.000Z

427

Effects of powder pretreatment on the microstructure and mechanical properties of tungsten heavy alloys. (Reannouncement with new availability information)  

SciTech Connect (OSTI)

Tungsten heavy alloys exhibit unique properties such as high strength, density, ductility and toughness. Alloying additions of molybdenum to the W-Ni-Fe system have drastically decreased the sintered grain size through the limited solubility of tungsten in the solid solution matrix in the presence of molybdenum. This contributes to additional strengthening but a decrease in the ductility. Recent work has shown that the distribution of molybdenum in the tungsten grains is not uniform after sintering. Homogenous coating of Mo on W is desirable to further decrease solution-reprecipitation during liquid phase sintering. In this work, alloying additions of molybdenum in the W-Ni-Fe system through various methods such as electroless-plating, milling, and mixing of elemental powders are investigated. The effects of these techniques on the final microstructure, densification and mechanical properties are examined using electron microscopy, microprobe analysis, and mechanical testing. The ideal distribution of molybdenum in the microstructure is investigated and the optimum alloying addition technique is singled out. This helps to better understand the processes occurring during liquid phase sintering of these alloys and further improve their mechanical properties.

Bedhadjhamida, A.; German, R.M.

1991-12-31T23:59:59.000Z

428

Deuterium trapping at defects created with neutron and ion irradiations in tungsten  

SciTech Connect (OSTI)

The effects of neutron and ion irradiations on deuterium (D) retention in tungsten (W) were investigated. Specimens of pure W were irradiated with neutrons to 0.3 dpa at around 323 K and then exposed to high-flux D plasma at 473 and 773 K. The concentration of D significantly increased by neutron irradiation and reached 0.8 at% at 473 K and 0.4 at% at 773 K. Annealing tests for the specimens irradiated with 20 MeV W ions showed that the defects which play a dominant role in the trapping at high temperature were stable at least up to 973 K, while the density decreased at temperatures equal to or above 1123 K. These observations of the thermal stability of traps and the activation energy for D detrapping examined in a previous study (˜1.8 eV) indicated that the defects which contribute predominantly to trapping at 773 K were small voids. The higher concentration of trapped D at 473 K was explained by additional contributions of weaker traps. The release of trapped D was clearly enhanced by the exposure to atomic hydrogen at 473 K, though higher temperatures are more effective for using this effect for tritium removal in fusion reactors.

Y. Hatano; M. Shimada; T. Otsuka; Y. Oya; V.Kh. Alimov; M. Hara; J. Shi; M. Kobayashi; T. Oda; G. Cao; K. Okuno; T. Tanaka; K. Sugiyama; J. Roth; B. Tyburska-Püschel; J. Dorner; N. Yoshida; N. Futagami; H. Watanabe; M. Hatakeyama; H. Kurishita; M. Sokolov; Y. Katoh

2013-07-01T23:59:59.000Z

429

Tungsten-incorporation induced red-shift in the bandgap of gallium oxide thin films  

SciTech Connect (OSTI)

Tungsten (W) incorporated Ga{sub 2}O{sub 3} films were produced by co-sputter deposition. W-concentration was varied by the applied sputtering-power. The structure and optical properties of W-incorporated Ga{sub 2}O{sub 3} films were evaluated using X-ray diffraction, scanning electron microscopy, and spectrophotometric measurements. No secondary phase formation was observed in W-incorporated Ga{sub 2}O{sub 3} films. W-induced effects were significant on the structure and optical properties of Ga{sub 2}O{sub 3} films. The bandgap of Ga{sub 2}O{sub 3} films without W-incorporation was {approx}5 eV. Red-shift in the bandgap was noted with increasing W-concentration indicating the electronic structure changes in W-Ga{sub 2}O{sub 3} films. A functional relationship between W-concentration and optical property is discussed.

Rubio, E. J.; Ramana, C. V. [Department of Mechanical Engineering, University of Texas at El Paso, El Paso, Texas 79968 (United States)] [Department of Mechanical Engineering, University of Texas at El Paso, El Paso, Texas 79968 (United States)

2013-05-13T23:59:59.000Z

430

Resistive switching phenomena of tungsten nitride thin films with excellent CMOS compatibility  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • The resistive switching characteristics of WN{sub x} thin films. • Excellent CMOS compatibility WN{sub x} films as a resistive switching material. • Resistive switching mechanism revealed trap-controlled space charge limited conduction. • Good endurance and retention properties over 10{sup 5} cycles, and 10{sup 5} s, respectively - Abstract: We report the resistive switching (RS) characteristics of tungsten nitride (WN{sub x}) thin films with excellent complementary metal-oxide-semiconductor (CMOS) compatibility. A Ti/WN{sub x}/Pt memory cell clearly shows bipolar RS behaviors at a low voltage of approximately ±2.2 V. The dominant conduction mechanisms at low and high resistance states were verified by Ohmic behavior and trap-controlled space-charge-limited conduction, respectively. A conducting filament model by a redox reaction explains the RS behavior in WN{sub x} films. We also demonstrate the memory characteristics during pulse operation, including a high endurance over >10{sup 5} cycles and a long retention time of >10{sup 5} s.

Hong, Seok Man; Kim, Hee-Dong; An, Ho-Myoung; Kim, Tae Geun, E-mail: tgkim1@korea.ac.kr

2013-12-15T23:59:59.000Z

431

Waltzing of a helium pair in tungsten: Migration barrier and trajectory revealed from first-principles  

SciTech Connect (OSTI)

Despite well documented first-principles theoretical determination of the low migration energy (0.06 eV) of a single He in tungsten, fully quantum mechanical calculations on the migration of a He pair still present a challenge due to the complexity of its trajectory. By identifying the six most stable configurations of the He pair in W and decomposing its motion into rotational, translational, and rotational-translational routines, we are able to determine its migration barrier and trajectory. Our density functional theory calculations demonstrate a He pair has three modes of motion: a close or open circular two-dimensional motion in (100) plane with an energy barrier of 0.30 eV, a snaking motion along [001] direction with a barrier of 0.30 eV, and a twisted-ladder motion along [010] direction with the two He swinging in the plane (100) and a barrier of 0.31 eV. The graceful associative movements of a He pair are related to the chemical-bonding-like He-He interaction being much stronger than its migration barrier in W. The excellent agreement with available experimental measurements (0.24–0.32 eV) on He migration makes our first-principles result a solid input to obtain accurate He-W interatomic potentials in molecular dynamics simulations.

Niu, J. G. [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Department of Mechanical Engineering, Hebei University, Baoding 071000 (China); Zhan, Q., E-mail: qzhan@mater.ustb.edu.cn [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Geng, W. T., E-mail: geng@ustb.edu.cn [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Psi Quantum Materials LLC, Laiwu 271100 (China)

2014-06-15T23:59:59.000Z

432

Radiative recombination data for tungsten ions: II. W{sup 47+}–W{sup 71+}  

SciTech Connect (OSTI)

New radiative recombination and photoionization cross sections, radiative recombination rate coefficients, and radiated power loss rate coefficients are presented for 23 tungsten impurity ions in plasmas. We consider ions from W{sup 47+} to W{sup 71+} that are of importance to fusion studies for ITER and for experiments using electron beam ion traps. The calculations are fully relativistic and all significant multipoles of the radiative field are taken into account. The Dirac–Fock method is used to compute the electron wavefunctions. Radiative recombination rates and radiated power loss rates are found using the relativistic Maxwell–Jüttner distribution of the continuum electron velocity. The total radiative recombination cross sections are given in the electron energy range from 1 eV to ?80keV. Partial cross sections for ground and excited states are approximated by an analytical expression involving five fit parameters. Radiative recombination rates and radiated power loss rates are calculated in the temperature range from 10{sup 4}K to 10{sup 9}K. The total radiative recombination rates are approximated by another analytical expression with four fit parameters.

Trzhaskovskaya, M.B., E-mail: Trzhask@MT5605.spb.edu [Petersburg Nuclear Physics Institute, Gatchina 188300 (Russian Federation); Nikulin, V.K. [Ioffe Physical Technical Institute, St. Petersburg 194021 (Russian Federation)

2014-07-15T23:59:59.000Z

433

Thermal-hydraulic criteria for the APT tungsten neutron source design  

SciTech Connect (OSTI)

This report presents the thermal-hydraulic design criteria (THDC) developed for the tungsten neutron source (TNS). The THDC are developed for the normal operations, operational transients, and design-basis accidents. The requirements of the safety analyses are incorporated into the design criteria, consistent with the integrated safety management and the safety-by-design philosophy implemented throughout the APT design process. The phenomenology limiting the thermal-hydraulic design and the confidence level requirements for each limit are discussed. The overall philosophy of the uncertainty analyses and the confidence level requirements also are presented. Different sets of criteria are developed for normal operations, operational transients, anticipated accidents, unlikely accidents, extremely unlikely accidents, and accidents during TNS replacement. In general, the philosophy is to use the strictest criteria for the high-frequency events. The criteria is relaxed as the event frequencies become smaller. The THDC must be considered as a guide for the design philosophy and not as a hard limit. When achievable, design margins greater than those required by the THDC must be used. However, if a specific event sequence cannot meet the THDC, expensive design changes are not necessary if the single event sequence results in sufficient margin to safety criteria and does not challenge the plant availability or investment protection considerations.

Pasamehmetoglu, K.

1998-03-01T23:59:59.000Z

434

Optical Spectroscopy of Tungsten Carbide for Uncertainty Analysis in Electron Electric Dipole Moment Search  

E-Print Network [OSTI]

We perform laser induced fluorescence(LIF) spectroscopy on a pulsed supersonic beam of tungsten carbide(WC) molecules, which has been proposed as a candidate molecular system for a permanent Electric Dipole Moment(EDM) search of the electron in its rovibrational ground state of the X3Delta1 state. In particular, [20.6]Omega=2, v'=4 <- X3Delta1,v"=0 transition at 485nm was used for the detection. The hyperfine structure and the Omega-doublet of the transition are measured, which are essential for estimating the size of the potential systematic uncertainties for electron EDM measurement. For further suppression of the systematic uncertainty, an alternative electron EDM measurement scheme utilizing the g factor crossing point of the Omega-doublet levels is discussed. On the other hand, flux and internal temperature of the molecular beam are characterized, which sets the limit on the statistical uncertainty of the electron EDM experiment. With the given results, the prospect of electron EDM experiment with the...

Lee, J; Skripnikov, L V; Petrov, A N; Titov, A V; Mosyagin, N S; Leanhardt, A E

2012-01-01T23:59:59.000Z

435

FINAL FOCUS ION BEAM INTENSITY FROM TUNGSTEN FOIL CALORIMETER AND SCINTILLATOR IN NDCX-I  

SciTech Connect (OSTI)

Laboratory high energy density experiments using ion beam drivers rely upon the delivery of high-current, high-brightness ion beams with high peak intensity onto targets. Solid-state scintillators are typically used to measure the ion beam spatial profile but they display dose-dependent degradation and aging effects. These effects produce uncertainties and limit the accuracy of measuring peak beam intensities delivered to the target. For beam tuning and characterizing the incident beam intensity, we have developed a cross-calibrating diagnostic suite that extends the upper limit of measurable peak intensity dynamic range. Absolute intensity calibration is obtained with a 3 {micro}m thick tungsten foil calorimeter and streak spectrometer. We present experimental evidence for peak intensity measures in excess of 400 kW/cm{sup 2} using a 0.3 MV, 25 mA, 5-20 {micro}sec K{sup +1} beam. Radiative models and thermal diffusion effects are discussed because they affect temporal and spatial resolution of beam intensity profiles.

Lidia, S.M.; Bieniosek, F.; Henestroza, E.; Ni, P.; Seidl, P.

2010-04-30T23:59:59.000Z

436

A Review of Tungsten Heavy Alloy Utilization in Isotope Transport Containers - 13380  

SciTech Connect (OSTI)

A common requirement for radioisotope transport containers is that they provide both durable and efficient shielding of penetrating gamma radiation. This is the case for transport of both spent nuclear fuel as well as intentionally created radioisotopes for medical or other uses. Tungsten heavy alloy (WHA) provides a unique engineering property set for such shielding - easily surpassing more commonly used lead alloys in both strength and attenuation. This family of alloys contains typically 90-98 wt.% W in combination with transition metals such as Ni and Fe. WHA is manufactured in near net shape blanks by liquid phase sintering of compacted powder shapes to full metallurgical density parts. This powder metallurgy approach is described in its ability to provide excellent material utilization and affords efficient manufacturing of various shapes required for gamma shields or collimators. WHAs offer very high density (approaching 19 g/cc) in combination with relatively high thermal conductivity, low thermal expansion, ambient corrosion resistance, and can be provided with mechanical properties comparable to many medium carbon steels. As such, they can be machined to complex, damage resistant geometries using common metal cutting tools and methods. WHA additionally provides a lower toxicity alternative to Pb- or U-based gamma shielding. Given the specialty nature of WHA, specific metallurgical characteristics are reviewed to assist shielding designers who may otherwise encounter difficulties locating important alloy selection and fabrication details. Contained within this materials and applications overview are guidelines for WHA component design, alloy selection, and practical machining, finishing, and assembly considerations. The microstructure of WHA is that of a metal matrix composite. This factor has specific implications in the design of components for stress service as well as their protection in the presence of electrolytes. WHA is also discussed in the broader context of materials compatibility, as it is rarely used in isolated monolithic shapes. Alloy selection for new applications is often made primarily on the basis of density. An alternative strategy to this selection approach is presented which proposes that mechanical requirements for a given shielding use be the primary selection criterion over density. Standard commercial grades of WHA for radiation shielding are defined by specifications such as AMS-T-21014 and ASTM B777. These specifications define 4 density classes of as-sintered WHA. Compositional options, as well as post-sinter processing of WHA, are discussed for shielding components that must exhibit higher levels of ductility or very low magnetic permeability. In addition to the mechanical advantages over Pb-based shielding, the higher linear attenuation of energetic photons for various grades of WHA (as calculated by the NIST XCOM routine) are presented for selected photon energies of interest to illustrate the shield volume reduction generally possible through the use of tungsten-based shielding. While W provides inefficient attenuation of neutrons in a mixed radiation environment, its secondary role in shielding gamma radiation produced as a result of neutron capture is also described. (authors)

Caldwell, Steven G. [ATI Firth Sterling, Madison, AL (United States)] [ATI Firth Sterling, Madison, AL (United States)

2013-07-01T23:59:59.000Z

437

Thickness measurement of aluminum, titanium, titanium silicide, and tungsten silicide films by x-ray fluorescence  

SciTech Connect (OSTI)

X-ray fluorescence (XRF) has received a great deal of attention in the last few years as a quantitative means of determining both the stoichiometry and thickness of many different kinds of films. Examples include Ag and Cu films on mica substrates, Sn-Pb alloys on steel substrates, Al-Ti multilayers on Cu substrates and oxide films on silicon substrates. In XRF the sample is irradiated with x-rays which in turn cause x-rays to be given off by the sample. These x-rays that are given off by the sample can then be analyzed both for energy and intensity. The energy of the x-rays is characteristic of the elemental makeup of the sample and the intensity of the x-rays is dependent on how much of the particular element is present. The intensity then can be related to the thickness of a film if the stoichiometry of the film can be assumed constant. With the increased interest in silicides and more recently, the self-aligned silicide (salicide) process (8-10) for VLSI applications, in-line process monitoring of silicide film thickness has become important to integrated circuit manufacturing. In this study, the number of x-ray photons given of by Al, Ti, titanium silicide, and tungsten silicide films on silicon-based substrates was quantified so that a film thickness for an unknown sample could then be determined easily. In addition, XRF is a more accurate technique, limited principally by the accuracy technique, limited principally by the accuracy of the reference used and the amount of time the x-ray photons are counted.

Ernst, S.; Lee, C.O.; Lee, J.J. (Motorola, Inc., Advanced Products Research and Development Lab., Austin, TX (US))

1988-08-01T23:59:59.000Z

438

Crystal orientation effects on helium ion depth distributions and adatom formation processes in plasma-facing tungsten  

SciTech Connect (OSTI)

We present atomistic simulations that show the effect of surface orientation on helium depth distributions and surface feature formation as a result of low-energy helium plasma exposure. We find a pronounced effect of surface orientation on the initial depth of implanted helium ions, as well as a difference in reflection and helium retention across different surface orientations. Our results indicate that single helium interstitials are sufficient to induce the formation of adatom/substitutional helium pairs under certain highly corrugated tungsten surfaces, such as (1 1 1)-orientations, leading to the formation of a relatively concentrated layer of immobile helium immediately below the surface. The energies involved for helium-induced adatom formation on (1 1 1) and (2 1 1) surfaces are exoergic for even a single adatom very close to the surface, while (0 0 1) and (0 1 1) surfaces require two or even three helium atoms in a cluster before a substitutional helium cluster and adatom will form with reasonable probability. This phenomenon results in much higher initial helium retention during helium plasma exposure to (1 1 1) and (2 1 1) tungsten surfaces than is observed for (0 0 1) or (0 1 1) surfaces and is much higher than can be attributed to differences in the initial depth distributions alone. The layer thus formed may serve as nucleation sites for further bubble formation and growth or as a source of material embrittlement or fatigue, which may have implications for the formation of tungsten “fuzz” in plasma-facing divertors for magnetic-confinement nuclear fusion reactors and/or the lifetime of such divertors.

Hammond, Karl D. [Department of Nuclear Engineering, University of Tennessee, Knoxville, Tennessee 37996–2300 (United States); Wirth, Brian D., E-mail: bdwirth@utk.edu [Department of Nuclear Engineering, University of Tennessee, Knoxville, Tennessee 37996–2300 (United States); P.O. Box 2008, MS-6003, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831–6003 (United States)

2014-10-14T23:59:59.000Z

439

The elastic and piezoelectric properties of tungsten bronze ferroelectric crystals ,,Sr0.7Ba0.3...2NaNb5O15 and ,,Sr0.3Ba0.7...2NaNb5O15  

E-Print Network [OSTI]

The elastic and piezoelectric properties of tungsten bronze ferroelectric crystals ,,Sr0.7Ba0 and piezoelectric constants of tungsten bronze ferroelectric crystals Sr0.7Ba0.3 2NaNb5O15 SBNN70 and Sr0.3Ba0.7 2Na. INTRODUCTION Ferroelectric crystals with tungsten bronze structure are another attractive family beside

Cao, Wenwu

440

Effects of Tungsten Oxide Addition on the Electrochemical Performance of Nanoscale Tantalum Oxide-Based Electrocatalysts for Proton Exchange Membrane PEM Fuel Cells  

SciTech Connect (OSTI)

In the present study, the properties of a series of non-platinum based nanoscale tantalum oxide/tungsten oxide-carbon composite catalysts was investigated for potential use in catalyzing the oxygen reduction reaction (ORR) on the cathode side of a PEM fuel cell membrane electrode assembly. Electrochemical performance was measured using a half-cell test set up with a rotating disc electrode and compared with a commercial platinum-on-carbon (Pt/C) catalyst. Overall, all of the oxide-based composite catalysts exhibit high ORR on-set potentials, comparable to that of the baseline Pt/C catalyst. The addition of tungsten oxide as a dopant to tantalum oxide greatly improved mass specific current density. Maximum performance was achieved with a catalyst containing 32 mol% of tungsten oxide, which exhibited a mass specific current density ~8% that of the Pt/C catalyst at 0.6 V vs. the normal hydrogen electrode (NHE) and ~35% that of the Pt/C catalyst at 0.2 V vs. NHE. Results from X-ray photoelectron spectroscopy analysis indicated that the tungsten cations in the composite catalysts exist in the +6 oxidation state, while the tantalum displays an average valence of +5, suggesting that the addition of tungsten likely creates an oxygen excess in the tantalum oxide structure that influences its oxygen absorption kinetics. When the 32mol% tungsten doped catalyst loading on the working electrode was increased to five times that of the original loading (which was equivalent to that of the baseline Pt/C catalyst), the area specific current density improved four fold, achieving an area specific current density ~35% that of the Pt/C catalyst at 0.6 V vs. NHE.

Oh, Tak Keun; Kim, Jin Yong; Shin, Yongsoon; Engelhard, Mark H.; Weil, K. Scott

2011-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "tungsten halogen spotlights" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Measurement of Leakage Neutron Spectra for Tungsten with D-T Neutrons and Validation of Evaluated Nuclear Data  

E-Print Network [OSTI]

Integral neutronics experiments have been investigated at Institute of Modern Physics, Chinese Academy of Sciences (IMP, CAS) in order to validate evaluated nuclear data related to the design of Chinese Initiative Accelerator Driven Systems (CIADS). In present paper, the accuracy of evaluated nuclear data for Tungsten has been examined by comparing measured leakage neutron spectra with calculated ones. Leakage neutron spectra from the irradiation of D-T neutrons on Tungsten slab sample were experimentally measured at 60$^{\\circ}$ and 120$^{\\circ}$ by using a time-of-flight method. Theoretical calculations are carried out by Monte Carlo neutron transport code MCNP-4C with evaluated nuclear data of the ADS-2.0, ENDF/B-VII.0, ENDF/B-VII.1, JENDL-4.0 and CENDL-3.1 libraries. From the comparisons, it is found that the calculations with ADS-2.0 and ENDF/B-VII.1 give good agreements with the experiments in the whole energy regions at 60$^{\\circ}$, while a large discrepancy is observed at 120$^{\\circ}$ in the elastic scattering peak, caused by a slight difference in the oscillation pattern of the elastic angular distribution at angles larger than 20$^{\\circ}$. However, the calculated spectra using data from ENDF/B-VII.0, JENDL-4.0 and CENDL-3.1 libraries showed larger discrepancies with the measured ones, especially around 8.5-13.5 MeV. Further studies are presented for these disagreements.

S. Zhanga; Z. Chen; Y. Nie; R. Wada; X. Ruan; R. Han; X. Liu; W. Lin; J. Liu; F. Shi; P. Ren; G. Tian; F. Luo; J. Ren; J. Bao

2014-11-20T23:59:59.000Z

442

Quasicontinuous x-ray laser with {lambda}=10.8 nm in Pd-like tungsten using a nanostructured target  

SciTech Connect (OSTI)

A new-generation x-ray laser project is explained. It is based on the transitions in Pd-like ions in nanoplasmas. The gain coefficient is calculated for the 4d{sub 3/2}{sup 9}5d{sub 3/2}[J=0]-4d{sub 3/2}{sup 9}5p{sub 1/2}[J=1] transition ({lambda}{approx_equal}10.8 nm) in Pd-like tungsten. It is suggested that a cylindrical target made of nanostructured tungsten is pumped in the longitudinal direction by a laser pulse with energy 1-2 keV and duration {approx}500 ps. For this pump pulse the target density and dimensions are calculated, as well as the temporal variations of the optimal plasma parameters for attaining gL {approx} 14. The energy yield in the 10.8-nm line is more than 10{sup 20} eV.

Ivanova, E. P. [Institute of Spectroscopy, Russian Academy of Sciences, 142190 Troitsk, Moscow Region (Russian Federation)

2010-10-15T23:59:59.000Z

443

Preparation of hexagonal WO{sub 3} from hexagonal ammonium tungsten bronze for sensing NH{sub 3}  

SciTech Connect (OSTI)

Hexagonal tungsten oxide (h-WO{sub 3}) was prepared by annealing hexagonal ammonium tungsten bronze, (NH{sub 4}){sub 0.07}(NH{sub 3}){sub 0.04}(H{sub 2}O){sub 0.09}WO{sub 2.95}. The structure, composition and morphology of h-WO{sub 3} were studied by XRD, XPS, Raman, {sup 1}H MAS (magic angle spinning) NMR, scanning electron microscopy (SEM), and BET-N{sub 2} specific surface area measurement, while its thermal stability was investigated by in situ XRD. The h-WO{sub 3} sample was built up by 50-100 nm particles, had an average specific surface area of 8.3 m{sup 2}/g and was thermally stable up to 450 deg. C. Gas sensing tests showed that h-WO{sub 3} was sensitive to various levels (10-50 ppm) of NH{sub 3}, with the shortest response and recovery times (1.3 and 3.8 min, respectively) to 50 ppm NH{sub 3}. To this NH{sub 3} concentration, the sensor had significantly higher sensitivity than h-WO{sub 3} samples prepared by wet chemical methods.

Szilagyi, Imre Miklos [Materials Structure and Modeling Research Group of the Hungarian Academy of Sciences, Budapest University of Technology and Economics, H-1111 Budapest, Szt. Gellert ter 4 (Hungary)], E-mail: imre.szilagyi@mail.bme.hu; Wang Lisheng; Gouma, Pelagia-Irene [Department of Materials Science and Engineering, 314 Old Engineering Building, SUNY, Stony Brook, NY 11794-2275 (United States); Balazsi, Csaba [Ceramics and Nanocomposites Laboratory, Research Institute for Technical Physics and Materials Science, H-1121 Budapest, Konkoly-Thege ut 29-33 (Hungary); Madarasz, Janos; Pokol, Gyoergy [Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, H-1111 Budapest, Szt. Gellert ter 4 (Hungary)

2009-03-05T23:59:59.000Z

444

Microstructure evolution of Al/Mg butt joints welded by gas tungsten arc with Zn filler metal  

SciTech Connect (OSTI)

Based on the idea of alloying welding seam, Gas tungsten arc welding method with pure Zn filler metal was chosen to join Mg alloy and Al alloy. The microstructures, phases, element distribution and fracture morphology of welding seams were examined. The results indicate that there was a transitional zone in the width of 80-100 {mu}m between the Mg alloy substrate and fusion zone. The fusion zone was mainly composed of MgZn{sub 2}, Zn-based solid solution and Al-based solid solution. The welding seam presented distinct morphology in different location owning to the quite high cooling rate of the molten pool. The addition of Zn metal could prevent the formation of Mg-Al intermetallics and form the alloyed welding seam during welding. Therefore, the tensile strengths of joints have been significantly improved compared with those of gas tungsten arc welded joints without Zn metal added. Highlights: Black-Right-Pointing-Pointer Mg alloy AZ31B and Al alloy 6061 are welded successfully. Black-Right-Pointing-Pointer Zinc wire is employed as a filler metal to form the alloyed welding seam. Black-Right-Pointing-Pointer An alloyed welding seam is benefit for improving of the joint tensile strength.

Liu Fei; Zhang Zhaodong; Liu Liming, E-mail: liulm@dlut.edu.cn

2012-07-15T23:59:59.000Z

445

Mechanochemical synthesis of tungsten carbide nano particles by using WO{sub 3}/Zn/C powder mixture  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? Nano particles of WC are synthesized by mechanochemical process. ? Zn was used to reduce WO{sub 3}. ? By removing ZnO from the milling products with an acid leaching, WC will be the final products. ? XRD results showed that the reduction reactions were completed after 36 h. ? TEM and SEM images showed that the morphology of produced powder is nearly spherical like. -- Abstract: In this research we introduce a new, facile, and economical system for fabrication of tungsten carbide (WC) nano particle powder. In this system WO{sub 3}, Zn, and C have been ball-milled for several hours, which led to the synthesis of tungsten carbide nano particles. The synthesized WC can successfully be separated from the ball-milled product by subjecting the product powder to diluted HCl for removing ZnO and obtaining WC. X-ray diffraction (XRD) analysis indicates that the reduction of WO{sub 3} will be completed gradually by increasing milling time up to 36 h. Scanning electron microscope (SEM), and transmission electron microscope (TEM) images show that after 36 h of milling the particle size of the fabricated powder is nano metric (about 20 nm). Results have shown that this system can surmount some main problems occurred in previous similar WC synthesizing systems. For example carbothermic reduction reactions, which lead to the synthesis of W{sub 2}C instead of WC, would not be activated because in this system reactions take place gradually.

Hoseinpur, Arman, E-mail: arman.hoseinpur@stu-mail.um.ac.ir [Department of Materials and Metallurgical Engineering, Ferdowsi University of Mashhad, Mashhad 91775-1111, Islamic Republic of Iran (Iran, Islamic Republic of)] [Department of Materials and Metallurgical Engineering, Ferdowsi University of Mashhad, Mashhad 91775-1111, Islamic Republic of Iran (Iran, Islamic Republic of); Vahdati Khaki, Jalil; Marashi, Maryam Sadat [Department of Materials and Metallurgical Engineering, Ferdowsi University of Mashhad, Mashhad 91775-1111, Islamic Republic of Iran (Iran, Islamic Republic of)] [Department of Materials and Metallurgical Engineering, Ferdowsi University of Mashhad, Mashhad 91775-1111, Islamic Republic of Iran (Iran, Islamic Republic of)

2013-02-15T23:59:59.000Z

446

Fabrication of Tungsten-Rhenium Cladding materials via Spark Plasma Sintering for Ultra High Temperature Reactor Applications  

SciTech Connect (OSTI)

This research will develop an optimized, cost-effective method for producing high-purity tungsten-rhenium alloyed fuel clad forms that are crucial for the development of a very high-temperature nuclear reactor. The study will provide critical insight into the fundamental behavior (processing-microstructure- property correlations) of W-Re alloys made using this new fabrication process comprising high-energy ball milling (HEBM) and spark plasma sintering (SPS). A broader goal is to re-establish the U.S. lead in the research field of refractory alloys, such as W-Re systems, with potential applications in very high-temperature nuclear reactors. An essential long-term goal for nuclear power is to develop the capability of operating nuclear reactors at temperatures in excess of 1,000K. This capability has applications in space exploration and some special terrestrial uses where high temperatures are needed in certain chemical or reforming processes. Refractory alloys have been identified as being capable of withstanding temperatures in excess of 1,000K and are considered critical for the development of ultra hightemperature reactors. Tungsten alloys are known to possess extraordinary properties, such as excellent high-temperature capability, including the ability to resist leakage of fissile materials when used as a fuel clad. However, there are difficulties with the development of refractory alloys: 1) lack of basic experimental data on thermodynamics and mechanical and physical properties, and 2) challenges associated with processing these alloys.

Charit, Indrajit; Butt, Darryl; Frary, Megan; Carroll, Mark

2012-11-05T23:59:59.000Z

447

Protonation Studies of a Tungsten Dinitrogen Complex Supported by a Diphosphine Ligand Containing a Pendant Amine  

SciTech Connect (OSTI)

Treatment of trans-[W(N2)2(dppe)(PEtNMePEt)] (dppe = Ph2PCH2CH2PPh2; PEtNMePEt = Et2PCH2N(Me)CH2PEt2) with three equivalents of tetrafluoroboric acid (HBF4?Et2O) at -78 °C generated the seven-coordinate tungsten hydride trans-[W(N2)2(H)(dppe)(PEtNMePEt)][BF4]. Depending on the temperature of the reaction, protonation of a pendant amine is also observed, affording trans-[W(N2)2(H)(dppe)(PEtNMe(H)PEt)][BF4]2, with formation of the hydrazido complex, [W(NNH2)(dppe)(PEtNMe(H)PEt)][BF4]2, as a minor product. Similar product mixtures were obtained using triflic acid (HOTf). Upon acid addition to the carbonyl analogue, cis-[W(CO)2(dppe)(PEtNMePEt)], the seven-coordinate carbonyl-hydride complex, trans-[W(CO)2(H)(dppe)(PEtN(H)MePEt)][OTf]2 was generated. The mixed diphosphine complex without the pendant amine in the ligand backbone, trans-[W(N2)2(dppe)(depp)] (depp = Et2P(CH2)3PEt2), was synthesized and treated with HBF4?Et2O, selectively generating a hydrazido complex, [W(NNH2)(F)(dppe)(depp)][BF4]. Computational analysis was used to probe proton affinity of three sites of protonation, the metal, pendant amine, and N2 ligand in these complexes. Room temperature reactions with 100 equivalents of HOTf produced NH4+ from reduction of the N2 ligand (electrons come from W). The addition of 100 equivalents HOTf to trans-[W(N2)2(dppe)(PEtNMePEt)] afforded 0.88 ± 0.02 equivalents NH4+, while 0.36 ± 0.02 equivalents of NH4+was formed upon treatment of trans-[W(N2)2(dppe)(depp)], the complex without the pendant amine. This work was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy Office of Science, Office of Basic Energy Sciences. Computational resources were provided by the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory. Pacific Northwest National Laboratory is operated by Battelle for DOE.

Weiss, Charles J.; Egbert, Jonathan D.; Chen, Shentan; Helm, Monte L.; Bullock, R. Morris; Mock, Michael T.

2014-05-12T23:59:59.000Z

448

Crystalline mesoporous tungsten oxide nanoplate monoliths synthesized by directed soft template method for highly sensitive NO{sub 2} gas sensor applications  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? Mesoporous WO{sub 3} nanoplate monoliths were obtained by direct templating synthesis. ? Enable effective accession of the analytic molecules for the sensor applications. ? The WO{sub 3} sensor exhibited a high performance to NO{sub 2} gas at low temperature. -- Abstract: Controllable synthesis of nanostructured metal oxide semiconductors with nanocrystalline size, porous structure, and large specific surface area is one of the key issues for effective gas sensor applications. In this study, crystalline mesoporous tungsten oxide nanoplate-like monoliths with high specific surface areas were obtained through instant direct-templating synthesis for highly sensitive nitrogen dioxide (NO{sub 2}) sensor applications. The copolymer soft template was converted into a solid carbon framework by heat treatment in an inert gas prior to calcinations in air to sustain the mesoporous structure of tungsten oxide. The multidirectional mesoporous structures of tungsten oxide with small crystalline size, large specific surface area, and superior physical characteristics enabled the rapid and effective accession of analytic gas molecules. As a result, the sensor response was enhanced and the response and recovery times were reduced, in which the mesoporous tungsten oxide based gas sensor exhibited a superior response of 21,155% to 5 ppm NO{sub 2}. In addition, the developed sensor exhibited selective detection of low NO{sub 2} concentration in ammonia and ethanol at a low temperature of approximately 150 °C.

Hoa, Nguyen Duc, E-mail: ndhoa@itims.edu.vn [International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology (HUST) (Viet Nam); Duy, Nguyen Van [International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology (HUST) (Viet Nam)] [International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology (HUST) (Viet Nam); Hieu, Nguyen Van, E-mail: hieu@itims.edu.vn [International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology (HUST) (Viet Nam)

2013-02-15T23:59:59.000Z

449

Advance Digital Imaging Process for Tungsten Alloys Liquid-Phase Sintered in Microgravity W. B Goodwin, University of Tennessee, SURF 2009 Fellow  

E-Print Network [OSTI]

Advance Digital Imaging Process for Tungsten Alloys Liquid-Phase Sintered in Microgravity W. B is to develop a digital image processing algorithm to rapidly detect and measure dihedral angles in binary. This geometric parameter greatly affects the liquid-phase sintering (LPS) process which is commonly used

Li, Mo

450

Effect of tungsten addition on the toughness and hardness of Fe{sub 2}B in wear-resistant Fe-B-C cast alloy  

SciTech Connect (OSTI)

The effects of tungsten additions of 0%, 1.12%, 2.04%, and 3.17% (in wt.%) on the morphology, fracture toughness and micro-hardness of Fe{sub 2}B in Fe-B-C cast alloy were investigated. The results indicate that, with the increase of tungsten addition, the morphology and distribution of Fe{sub 2}B have no change and a new W-containing phase, except the (Fe, W){sub 2}B with a certain tungsten solution, does not form, and that the fracture toughness of Fe{sub 2}B increases first and then decreases, while the hardness increases first and then has a little change. Compared with the fracture toughness (3.8 MPa{center_dot}m{sup 1/2}) of Fe{sub 2}B without tungsten addition, the toughness at 2.04 wt.% tungsten can be improved by about above 80% and achieves about 6.9 MPa{center_dot}m{sup 1/2}, and variation characteristics of hardness and toughness of Fe{sub 2}B were also testified by viewing the indentation marks and cracks on the Fe{sub 2}B, respectively. - Highlights: Black-Right-Pointing-Pointer Poor toughness of Fe2B decreases obviously the wear resistance of the alloy. Black-Right-Pointing-Pointer As W content increases, Fe2B's toughness increases first and then decreases. Black-Right-Pointing-Pointer As W content increases, Fe2B's hardness first increases and then has little change. Black-Right-Pointing-Pointer The toughness at 2.04 % W can be improved by above 80% more than that at 0% W.

Huang, Zhifu, E-mail: hzf@mail.xjtu.edu.cn; Xing, Jiandong; Lv, Liangliang

2013-01-15T23:59:59.000Z

451

Light scattering from ,,K0.5Na0.5...0.2,,Sr0.75Ba0.25...0.9Nb2O6 with the tungsten bronze structure: An analogy with relaxor ferroelectrics  

E-Print Network [OSTI]

Light scattering from ,,K0.5Na0.5...0.2,,Sr0.75Ba0.25...0.9Nb2O6 with the tungsten bronze structure a complex single crystal from the tungsten­bronze family, K0.5Na0.5 0.2 Sr0.75Ba0.25 0.9Nb2O6 doped with Cu2 photorefractive material.1 KNSBN originates from the tungsten­bronze family of ferroelectrics. KNSBN has two close

452

Multiscale Modeling of Grain Boundary Segregation and Embrittlement in Tungsten for Mechanistic Design of Alloys for Coal Fired Plants  

SciTech Connect (OSTI)

Based on a recent discovery of premelting-like grain boundary segregation in refractory metals occurring at high temperatures and/or high alloying levels, this project investigated grain boundary segregation and embrittlement in tungsten (W) based alloys. Specifically, new interfacial thermodynamic models have been developed and quantified to predict high-temperature grain boundary segregation in the W-Ni binary alloy and W-Ni-Fe, W-Ni-Ti, W-Ni-Co, W-Ni-Cr, W-Ni-Zr and W-Ni-Nb ternary alloys. The thermodynamic modeling results have been experimentally validated for selected systems. Furthermore, multiscale modeling has been conducted at continuum, atomistic and quantum-mechanical levels to link grain boundary segregation with embrittlement. In summary, this 3-year project has successfully developed a theoretical framework in combination with a multiscale modeling strategy for predicting grain boundary segregation and embrittlement in W based alloys.

Luo, Jian; Tomar, Vikas; Zhou, Naixie; Lee, Hongsuk

2013-06-30T23:59:59.000Z

453

Reactive oxygen species and oxidative DNA damage mediate the cytotoxicity of tungsten-nickel-cobalt alloys in vitro  

SciTech Connect (OSTI)

Tungsten alloys (WA) have been introduced in an attempt to find safer alternatives to depleted uranium and lead munitions. However, it is known that at least one alloy, 91% tungsten-6% nickel-3% cobalt (WNC-91-6-3), causes rhabdomyosarcomas when fragments are implanted in rat muscle. This raises concerns that shrapnel, if not surgically removable, may result in similar tumours in humans. There is therefore a clear need to develop rapid and robust in vitro methods to characterise the toxicity of different WAs in order to identify those that are most likely to be harmful to human health and to guide development of new materials in the future. In the current study we have developed a rapid visual in vitro assay to detect toxicity mediated by individual WA particles in cultured L6-C11 rat muscle cells. Using a variety of techniques (histology, comet assay, caspase-3 activity, oxidation of 2'7'-dichlorofluorescin to measure the production of reactive oxygen species and whole-genome microarrays) we show that, in agreement with the in vivo rat carcinogenicity studies, WNC-91-6-3 was the most toxic of the alloys tested. On dissolution, it produces large amounts of reactive oxygen species, causes significant amounts of DNA damage, inhibits caspase-3, triggers a severe hypoxic response and kills the cells in the immediate vicinity of the alloy particles within 24 h. By combining these in vitro data we offer a mechanistic explanation of the effect of this alloy in vivo and show that in vitro tests are a viable alternative for assessing new alloys in the future.

Harris, R.M.; Williams, T.D.; Hodges, N.J.; Waring, R.H., E-mail: R.H.Waring@bham.ac.uk

2011-01-01T23:59:59.000Z

454

Comparison of secondary neutron dose in proton therapy resulting from the use of a tungsten alloy MLC or a brass collimator system  

SciTech Connect (OSTI)

Purpose: To apply the dual ionization chamber method for mixed radiation fields to an accurate comparison of the secondary neutron dose arising from the use of a tungsten alloy multileaf collimator (MLC) as opposed to a brass collimator system for defining the shape of a therapeutic proton field. Methods: Hydrogenous and nonhydrogenous ionization chambers were constructed with large volumes to enable measurements of absorbed doses below 10{sup -4} Gy in mixed radiation fields using the dual ionization chamber method for mixed-field dosimetry. Neutron dose measurements were made with a nominal 230 MeV proton beam incident on a closed tungsten alloy MLC and a solid brass block. The chambers were cross-calibrated against a {sup 60}Co-calibrated Farmer chamber in water using a 6 MV x-ray beam and Monte Carlo simulations were performed to account for variations in ionization chamber response due to differences in secondary neutron energy spectra. Results: The neutron and combined proton plus {gamma}-ray absorbed doses are shown to be nearly equivalent downstream from either a closed tungsten alloy MLC or a solid brass block. At 10 cm downstream from the distal edge of the collimating material the neutron dose from the closed MLC was (5.3 {+-} 0.4) x 10{sup -5} Gy/Gy. The neutron dose with brass was (6.4 {+-} 0.7) x 10{sup -5} Gy/Gy. Further from the secondary neutron source, at 50 cm, the neutron doses remain close for both the MLC and brass block at (6.9 {+-} 0.6) x 10{sup -6} Gy/Gy and (6.3 {+-} 0.7) x 10{sup -6} Gy/Gy, respectively. Conclusions: The dual ionization chamber method is suitable for measuring secondary neutron doses resulting from proton irradiation. The results of measurements downstream from a closed tungsten alloy MLC and a brass block indicate that, even in an overly pessimistic worst-case scenario, secondary neutron production in a tungsten alloy MLC leads to absorbed doses that are nearly equivalent to those seen from brass collimators. Therefore, the choice of tungsten alloy in constructing the leaves of a proton MLC is appropriate, and does not lead to a substantial increase in the secondary neutron dose to the patient compared to that generated in a brass collimator.

Diffenderfer, Eric S.; Ainsley, Christopher G.; Kirk, Maura L.; McDonough, James E.; Maughan, Richard L. [Department of Radiation Oncology, University of Pennsylvania, Philadelphia, Pennsylvania 19104 (United States)

2011-11-15T23:59:59.000Z

455

Overview of the US-Japan collaborative investigation on hydrogen isotope retention in neutron-irradiated and ion-damaged tungsten  

SciTech Connect (OSTI)

Plasma-facing components (PFCs) will be exposed to 14 MeV neutrons from deuterium-tritium (D-T) fusion reactions, and tungsten, a candidate PFC for the divertor in ITER, is expected to receive a neutron dose of 0.7 displacement per atom (dpa) by the end of operation in ITER. The effect of neutron-irradiation damage has been mainly simulated using high-energy ion bombardment. While this prior database of results is quite valuable for understanding the behavior of hydrogen isotopes in PFCs, it does not encompass the full range of effects that must be considered in a practical fusion environment due to short penetration depth, damage gradient, high damage rate, and high PKA energy spectrum of the ion bombardment. In addition, neutrons change the elemental composition via transmutations, and create a high radiation environment inside PFCs, which influence the behavior of hydrogen isotope in PFCs, suggesting the utilization of fission reactors is necessary for neutron irradiation. Therefore, the effort to correlate among high-energy ions, fission neutrons, and fusion neutrons is crucial for accurately estimating tritium retention under a neutron-irradiation environment. Under the framework of the US-Japan TITAN program, tungsten samples (99.99 at. % purity from A.L.M.T. Co.) were irradiated by neutron in the High Flux Isotope Reactor (HFIR), ORNL, at 50 and 300C to 0.025, 0.3, and 1.2 dpa, and the investigation of deuterium retention in neutron-irradiation was performed in the INL Tritium Plasma Experiment (TPE), the unique high-flux linear plasma facility that can handle tritium, beryllium and activated materials. This paper reports the recent results from the comparison of ion-damaged tungsten via various ion species (2.8 MeV Fe2+, 20 MeV W2+, and 700 keV H-) with that from neutron-irradiated tungsten to identify the similarities and differences among them.

Masashi Shimada; Y. Hatano; Y. Oya; T. Oda; M. Hara; G. Cao; M. Kobayashi; M. Sokolov; H. Watanabe; B. Tyburska; Y. Ueda; P. Calderoni

2011-09-01T23:59:59.000Z

456

Peculiarities of formation of phase composition, porous structure, and catalytic properties of tungsten oxide-based macroporous materials fabricated by sol–gel synthesis  

SciTech Connect (OSTI)

The method of template sol–gel synthesis of tungsten oxide-based macroporous materials using ‘core–shell’ latex particles as colloid templates is described. The chemical composition and structural characteristics of the synthesized macroporous oxide systems have been investigated. The peculiarities of formation of material phase composition and macroporous structure under different template thermal destruction conditions have been revealed. An optimal method of a targeted synthesis of the crystalline tungsten(VI) oxide having a defect-free macroporous structure (average pore size 160 nm) and efficient catalytic properties under organic liquid phase oxidation conditions has been suggested. The prospects of the fabricated material application as catalysts of hydrothermal oxidation of radionuclide organic complexes at radioactive waste decontamination have been demonstrated. - Highlights: • Macroporous tungsten oxides were fabricated via sol–gel process. • The correlation between synthesis conditions and composition was determined. • Influence of synthesis conditions on porous structure has been explained. • The effects of template thermodestruction have been set up. • High potential of such materials for catalysis applications has been shown.

Papynov, Evgeniy Konstantinovich, E-mail: Papynov@mail.ru [Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Prospect 100-let Vladivostoku, 159, Vladivostok 690022 (Russian Federation); Far Eastern Federal University, School of Natural Sciences, Suhanova, 8, Vladivostok 690091 (Russian Federation); Mayorov, Vitaliy Yurevich, E-mail: 024205@inbox.ru [Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Prospect 100-let Vladivostoku, 159, Vladivostok 690022 (Russian Federation); Palamarchuk, Marina Sergeevna, E-mail: 02.06.1984@mail.ru [Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Prospect 100-let Vladivostoku, 159, Vladivostok 690022 (Russian Federation); Avramenko, Valentin Aleksandrovich, E-mail: avramenko1@yandex.ru [Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Prospect 100-let Vladivostoku, 159, Vladivostok 690022 (Russian Federation); Far Eastern Federal University, School of Natural Sciences, Suhanova, 8, Vladivostok 690091 (Russian Federation)

2014-02-15T23:59:59.000Z

457

A Highly Granular Silicon-Tungsten Electromagnetic Calorimeter and Top Quark Production at the International Linear Collider  

E-Print Network [OSTI]

This thesis deals with two aspects of the International Linear Collider (ILC) which is a project of a linear electron-positron collider of up to at least 500 GeV center of mass energy. The first aspect is the development of a silicon-tungsten electromagnetic calorimeter (SiW-ECAL) for one of the detectors of the ILC. The concept of this detector is driven by the ILC beam specifications and by the Particle Flow Algorithm (PFA). This requires highly granular calorimeter and very compact one with integrated electronics. To prove the capability of the SiW- ECAL a technological prototype has been built and tested in test beam at DESY. The results are presented here, and show, after the calibration procedure a signal over noise ratio of 10, even in the power pulsing mode. The second aspect is the study of one of the important physics channels of the ILC, the top anti-top quark pairs production. The main goal of this study is to determine the precision that we can expect at the ILC on the top coupling with the W bos...

Rouëné, J

2014-01-01T23:59:59.000Z

458

Structure and physical properties of EuTa{sub 2}O{sub 6} tungsten bronze polymorph  

SciTech Connect (OSTI)

A tetragonal tungsten bronze (TTB) polymorph of EuTa{sub 2}O{sub 6} was prepared and analyzed. EuTa{sub 2}O{sub 6} crystallizes in the centrosymmetric Pnam space group (with unit cell: a?=?12.3693, b?=?12.4254, and c?=?7.7228?Å) isomorphous with orthorhombic ?-SrTa{sub 2}O{sub 6}. In contrast to early reports, we see no evidence of deviation from paramagnetic Curie-Weiss behavior among the Eu{sup 2+} 4f{sup 7}spins in EuTa{sub 2}O{sub 6} down to 2?K. Dielectric constant shows a broad peak at ca. 50?K with dielectric dispersion resembling diffuse phase transition. The relaxation time, however, follows a simple (non-freezing) thermally activated process with an activation energy of 92?meV and an attempt frequency of f{sub 0}?=?5.79?×?10{sup 12?}Hz. A thermal conductivity of EuTa{sub 2}O{sub 6} shows a low-temperature (T???30?K) “plateau” region reminiscent of a glass-like behaviour in Nb-based TTB compounds. This behaviour can be attributed to the loosely bound Eu{sup 2+} ions occupying large tricapped trigonal prismatic sites in the EuTa{sub 2}O{sub 6} structure.

Kolodiazhnyi, T., E-mail: kolodiazhnyi.taras@nims.go.jp; Sakurai, H.; Vasylkiv, O.; Borodianska, H. [National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Forbes, S.; Mozharivskyj, Y. [Department of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario L8S4M1 (Canada)

2014-08-11T23:59:59.000Z

459

Wire number dependence of the implosion dynamics, stagnation, and radiation output of tungsten wire arrays at Z driver  

SciTech Connect (OSTI)

We report results of the experimental campaign, which studied the initiation, implosion dynamics, and radiation yield of tungsten wire arrays as a function of the wire number. The wire array dimensions and mass were those of interest for the Z-pinch driven Inertial Confinement Fusion (ICF) program. An optimization study of the x-ray emitted peak power, rise time, and full width at half maximum was effectuated by varying the wire number while keeping the total array mass constant and equal to {approx}5.8 mg. The driver utilized was the {approx}20-MA Z accelerator before refurbishment in its usual short pulse mode of 100 ns. We studied single arrays of 20-mm diameter and 1-cm height. The smaller wire number studied was 30 and the largest 600. It appears that 600 is the highest achievable wire number with present day's technology. Radial and axial diagnostics were utilized including crystal monochromatic x-ray backlighter. An optimum wire number of {approx}375 was observed which was very close to the routinely utilized 300 for the ICF program in Sandia.

Mazarakis, Michael G.; Stygar, William A.; Sinars, Daniel B.; Cuneo, Michael E.; Nash, Thomas J.; Chandler, Gordon A.; Keith Matzen, M.; Porter, John L.; Struve, Kenneth W.; McDaniel, Dillon H. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, New Mexico 87185 (United States); Deeney, Christopher E. [National Nuclear Security Administration, Washington, D.C. 20585 (United States); Douglas, Melissa R. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Chittenden, Jerry [Imperial College, London, SW and 2BW (United Kingdom)

2011-11-15T23:59:59.000Z

460

NWPPA spotlights synchrophasors, energy-saving competition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Articles (by tag) Lineman shares life-saving skills with electrical workers in Suriname Thursday, January 08, 2015 Platform for a modern grid: customer engagement Friday,...

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461

Children's School February 2012 Research Spotlight  

E-Print Network [OSTI]

questions about several stories that he or she heard during the fall semester. For example, if your child two dolls, Susan and Ann, playing with a marble. Susan places the marble in her basket. Then, Susan and your child either watch or cover their eyes while Ann moves the marble from the basket to a box sitting

462

High Performance Builder Spotlight: Green Coast Enterprises ...  

Energy Savers [EERE]

- New Orleans, Louisiana Building America Whole-House Solutions for New Homes: Green Coast Enterprises, New Orleans, Louisiana Building America Best Practices Series...

463

Sambamurti Memorial Lecture: Spotlight on the Gluon  

ScienceCinema (OSTI)

Begel uses results from the Fermilab D0 and E706 experiments to explain how the production rate and energy spectrum of photons produced during proton collisions helped to clarify how the energy inside the proton is shared between quarks and gluons.

Michael Begelas

2010-09-01T23:59:59.000Z

464

NWPPA spotlights synchrophasors, energy-saving competition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | NationalJohn F. Geisz,AerialStaff NUG 2012 2014NWChem

465

DOE Sustainability SPOtlight | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power Systems EngineeringDepartmentSmartDepartmentEnergyMeeting -2014and LoanDOE

466

In The Spotlight | National Nuclear Security Administration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for planning experimentalPetroleumornl.govInInInIn

467

Doe Sustainability SPOtlight - 2014 Sustainability Awards  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy CooperationRequirements Matrix U.S.7685 Vol. 76, No. 29 Friday,DocumentSustainability

468

Spotlighting Howard University | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage » SearchEnergyDepartmentScopingOverview * Analyzer I nstrumentProgram Reach

469

Employee Spotlight: Ali Erdemir | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and West OtherEmployeeLosAli Erdemir

470

Employee Spotlight: José Valdez  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and West OtherEmployeeLosAliJaniceJosé

471

Employee Spotlight: Lydia Finney | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and WestLydia Finney March 16, 2015 Tweet

472

Solar Decathlon Technology Spotlight: Structural Insulated Panels |  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment of Energy U.S. DepartmentCommitmentGovernmentSmartDay 7 Construction 1 of

473

Employee Spotlight: Ali Erdemir | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMI SIGTrendsAbout

474

Employee Spotlight: Ann Schlenker | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of theEMI SIGTrendsAboutAnn Schlenker