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Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
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1

Independent Oversight Review, Oak Ridge Transuranic Waste Processing...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transuranic Waste Processing Center, September 2013 Independent Oversight Review, Oak Ridge Transuranic Waste Processing Center, September 2013 September 2013 Review of Management...

2

Process to separate transuranic elements from nuclear waste  

DOE Patents [OSTI]

A process for removing transuranic elements from a waste chloride electrolytic salt containing transuranic elements in addition to rare earth and other fission product elements so the salt waste may be disposed of more easily and the valuable transuranic elements may be recovered for reuse. The salt is contacted with a cadmium-uranium alloy which selectively extracts the transuranic elements from the salt. The waste salt is generated during the reprocessing of nuclear fuel associated with the Integral Fast Reactor (IFR).

Johnson, Terry R. (Wheaton, IL); Ackerman, John P. (Downers Grove, IL); Tomczuk, Zygmunt (Orland Park, IL); Fischer, Donald F. (Glen Ellyn, IL)

1989-01-01T23:59:59.000Z

3

Transuranic Waste Processing Center Oak Ridge Site Specific...  

Broader source: Energy.gov (indexed) [DOE]

Transuranic Waste Processing Update Oak Ridge Site Specific Advisory Board May 14, 2014 Laura Wilkerson, Portfolio Federal Project Director Karen Deacon, Deputy Federal Project...

4

Independent Oversight Review, Oak Ridge Transuranic Waste Processing...  

Broader source: Energy.gov (indexed) [DOE]

Facility - December 2013 Independent Oversight Review, Oak Ridge Transuranic Waste Processing Facility - December 2013 December 2013 Review of the Fire Protection Program and Fire...

5

Process to separate transuranic elements from nuclear waste  

DOE Patents [OSTI]

A process is described for removing transuranic elements from a waste chloride electrolytic salt containing transuranic elements in addition to rare earth and other fission product elements so the salt waste may be disposed of more easily and the valuable transuranic elements may be recovered for reuse. The salt is contacted with a cadmium-uranium alloy which selectively extracts the transuranic elements from the salt. The waste salt is generated during the reprocessing of nuclear fuel associated with the Integral Fast Reactor (IFR). 2 figs.

Johnson, T.R.; Ackerman, J.P.; Tomczuk, Z.; Fischer, D.F.

1989-03-21T23:59:59.000Z

6

Process to separate transuranic elements from nuclear waste  

DOE Patents [OSTI]

A process for removing transuranic elements from a waste chloride electrolytic salt containing transuranic elements in addition to rare earth and other fission product elements so the salt waste may be disposed of more easily and the valuable transuranic elements may be recovered for reuse. The salt is contacted with a cadmium-uranium alloy which selectively extracts the transuranic elements from the salt. The waste salt is generated during the reprocessing of nuclear fuel associated with the Integral Fast Reactor (IFR). 2 figs.

Johnson, T.R.; Ackerman, J.P.; Tomczuk, Z.; Fischer, D.F.

1988-07-12T23:59:59.000Z

7

Voluntary Protection Program Onsite Review, Transuranic Waste...  

Energy Savers [EERE]

Transuranic Waste Processing Center - September 2012 Voluntary Protection Program Onsite Review, Transuranic Waste Processing Center - September 2012 September 2012 Evaluation to...

8

Proposed Changes to EPA's Transuranic Waste Characterization Approval Process  

SciTech Connect (OSTI)

This paper describes the changes to the waste characterization (WC) approval process proposed in August 2002 by the U.S. Environmental Protection Agency (EPA or the Agency or we). EPA regulates the disposal of transuranic (TRU) waste at the Waste Isolation Pilot Plant (WIPP) repository in Carlsbad, New Mexico. EPA regulations require that waste generator/storage sites seek EPA approval of WC processes used to characterize TRU waste destined for disposal at WIPP. The regulations also require that EPA verify, through site inspections, characterization of each waste stream or group of waste streams proposed for disposal at the WIPP. As part of verification, the Agency inspects equipment, procedures, and interviews personnel to determine if the processes used by a site can adequately characterize the waste in order to meet the waste acceptance criteria for WIPP. The paper discusses EPA's mandate, current regulations, inspection experience, and proposed changes. We expect that th e proposed changes will provide equivalent or improved oversight. Also, they would give EPA greater flexibility in scheduling and conducting inspections, and should clarify the regulatory process of inspections for both Department of Energy (DOE) and the public.

Joglekar. R. D.; Feltcorn, E. M.; Ortiz, A. M.

2003-02-25T23:59:59.000Z

9

Description of processes for the immobilization of selected transuranic wastes  

SciTech Connect (OSTI)

Processed sludge and incinerator-ash wastes contaminated with transuranic (TRU) elements may require immobilization to prevent the release of these elements to the environment. As part of the TRU Waste Immobilization Program sponsored by the Department of Energy (DOE), the Pacific Northwest Laboratory is developing applicable waste-form and processing technology that may meet this need. This report defines and describes processes that are capable of immobilizing a selected TRU waste-stream consisting of a blend of three parts process sludge and one part incinerator ash. These selected waste streams are based on the compositions and generation rates of the waste processing and incineration facility at the Rocky Flats Plant. The specific waste forms that could be produced by the described processes include: in-can melted borosilicate-glass monolith; joule-heated melter borosilicate-glass monolith or marble; joule-heated melter aluminosilicate-glass monolith or marble; joule-heated melter basaltic-glass monolith or marble; joule-heated melter glass-ceramic monolith; cast-cement monolith; pressed-cement pellet; and cold-pressed sintered-ceramic pellet.

Timmerman, C.L.

1980-12-01T23:59:59.000Z

10

Voluntary Protection Program Onsite Review, Transuranic Waste Processing Center- March 2008  

Broader source: Energy.gov [DOE]

Evaluation to determine whether EnergX, LLC Transuranic Waste Processing Centeris continuing to perform at a level deserving DOE-VPP Star recognition.

11

Process Simulation as Applied to Transuranic Waste Management  

SciTech Connect (OSTI)

The National Transuranic Waste System Model (the Model) is a computer simulation designed to evaluate the preparation and flow of TRU waste from generator sites throughout the Department of Energy (the Department) complex to the Waste Isolation Pilot Plant (WIPP) facility for disposal. The Model uses process simulation software to predict waste outputs of waste management operations as a function of time over the life of the WIPP. Process simulation modeling is a tool used by many industries, both private and public, to evaluate complex systems. For example a manufacturing plant might use process simulation to determine the possible effects of increasing the rate of production: will there be adequate resources (labor pool, raw goods, transportation capability); can the new production rate be sustained for an indefinite period of time without adding additional infrastructure. Process simulation modeling is also used by various military branches to ensure adequate supplies are delivered in a timely manner. The Department currently uses this technique as the basis for its National TRU Waste Management Plan Rev. 1 (DOE, 1997).

Brown, M.; Downes, S.; Trone, J.

1999-01-01T23:59:59.000Z

12

Transuranic Waste Requirements  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The guide provides criteria for determining if a waste is to be managed in accordance with DOE M 435.1-1, Chapter III, Transuranic Waste Requirements.

1999-07-09T23:59:59.000Z

13

Transuranic (TRU) Waste | Department of Energy  

Office of Environmental Management (EM)

Transuranic (TRU) Waste Transuranic (TRU) Waste Transuranic (TRU) Waste Defined by the WIPP Land Withdrawal Act as "waste containing more than 100 nanocuries of alpha-emitting...

14

Process Description for the Retrieval of Earth Covered Transuranic (TRU) Waste Containers at the Hanford Site  

SciTech Connect (OSTI)

This document describes process and operational options for retrieval of the contact-handled suspect transuranic waste drums currently stored below grade in earth-covered trenches at the Hanford Site. Retrieval processes and options discussed include excavation, container retrieval, venting, non-destructive assay, criticality avoidance, incidental waste handling, site preparation, equipment, and shipping.

DEROSA, D.C.

2000-01-13T23:59:59.000Z

15

Economic comparison of centralizing or decentralizing processing facilities for defense transuranic waste  

SciTech Connect (OSTI)

This study is part of a set of analyses under direction of the Transuranic Waste Management Program designed to provide comprehensive, systematic methodology and support necessary to better understand options for national long-term management of transuranic (TRU) waste. The report summarizes activities to evaluate the economics of possible alternatives in locating facilities to process DOE-managed transuranic waste. The options considered are: (1) Facilities located at all major DOE TRU waste generating sites. (2) Two or three regional facilities. (3) Central processing facility at only one DOE site. The study concludes that processing at only one facility is the lowest cost option, followed, in order of cost, by regional then individual site processing.

Brown, C M

1980-07-01T23:59:59.000Z

16

Process Knowledge Summary Report for Materials and Fuels Complex Contact-Handled Transuranic Debris Waste  

SciTech Connect (OSTI)

This Process Knowledge Summary Report summarizes the information collected to satisfy the transportation and waste acceptance requirements for the transfer of transuranic (TRU) waste between the Materials and Fuels Complex (MFC) and the Advanced Mixed Waste Treatment Project (AMWTP). The information collected includes documentation that addresses the requirements for AMWTP and the applicable portion of their Resource Conservation and Recovery Act permits for receipt and treatment of TRU debris waste in AMWTP. This report has been prepared for contact-handled TRU debris waste generated by the Idaho National Laboratory at MFC. The TRU debris waste will be shipped to AMWTP for purposes of supercompaction. This Process Knowledge Summary Report includes information regarding, but not limited to, the generation process, the physical form, radiological characteristics, and chemical contaminants of the TRU debris waste, prohibited items, and packaging configuration. This report, along with the referenced supporting documents, will create a defensible and auditable record for waste originating from MFC.

R. P. Grant; P. J. Crane; S. Butler; M. A. Henry

2010-02-01T23:59:59.000Z

17

Repackaging of High Fissile TRU Waste at the Transuranic Waste Processing Center - 13240  

SciTech Connect (OSTI)

Twenty-six drums of high fissile transuranic (TRU) waste from Oak Ridge National Laboratory (ORNL) operations were declared waste in the mid-1980's and placed in storage with the legacy TRU waste inventory for future treatment and disposal at the Waste Isolation Pilot Plant (WIPP). Repackaging and treatment of the waste at the TRU Waste Packaging Center (TWPC) will require the installation of additional equipment and capabilities to address the hazards for handling and repackaging the waste compared to typical Contact Handled (CH) TRU waste that is processed at the TWPC, including potential hydrogen accumulation in legacy 6M/2R packaging configurations, potential presence of reactive plutonium hydrides, and significant low energy gamma radiation dose rates. All of the waste is anticipated to be repackaged at the TWPC and certified for disposal at WIPP. The waste is currently packaged in multiple layers of containers which presents additional challenges for repackaging activities due to the potential for the accumulation of hydrogen gas in the container headspace in quantities than could exceed the Lower Flammability Limit (LFL). The outer container for each waste package is a stainless steel 0.21 m{sup 3} (55-gal) drum which contains either a 0.04 m{sup 3} or 0.06 m{sup 3} (10-gal or 15-gal) 6M drum. The inner 2R container in each 6M drum is ?12 cm (5 in) outside diameter x 30-36 cm (12-14 in) long and is considered to be a > 4 liter sealed container relative to TRU waste packaging criteria. Inside the 2R containers are multiple configurations of food pack cans, pipe nipples, and welded capsules. The waste contains significant quantities of high burn-up plutonium oxides and metals with a heavy weight percentage of higher atomic mass isotopes and the subsequent in-growth of significant quantities of americium. Significant low energy gamma radiation is expected to be present due to the americium in-growth. Radiation dose rates on inner containers are estimated to be 1-3 mSv/hr (100-300 mrem/hr) with an unshielded dose rate on the waste itself of over 10 mSv/hr (1 rem/hr). Additional equipment to be installed at the TWPC will include a new perma-con enclosure and a shielded/inert glovebox in the process building to repackage and stabilize the waste. All of the waste will be repackaged into Standard Pipe Overpacks. Most of the waste (21 of the 26 drums) is expected to be repackaged at the food-pack can level (i.e. the food-pack cans will not be opened). Five of the incoming waste containers are expected to be repackaged at the primary waste level. Three of the containers exceed the 200 gram Pu-239 Fissile Gram Equivalent (FGE) limit for the Standard Pipe Overpack. These three containers will be repackaged down to the primary waste level and divided into eight Standard Pipe Overpacks for shipment to WIPP. Two containers must be stabilized to eliminate any reactive plutonium hydrides that may be present. These containers will be opened in the inert, shielded glovebox, and the remaining corroded plutonium metal converted to a stable oxide form by using a 600 deg. C tube furnace with controlled oxygen feed in a helium carrier gas. The stabilized waste will then be packaged into two Standard Pipe Overpacks. Design and build out activities for the additional repackaging capabilities at the TWPC are scheduled to begin in Fiscal Year 2013 with repackaging, stabilization, and certification activities scheduled to begin in Fiscal Year 2014. Following repackaging and stabilization activities, the Standard Pipe Overpacks will be certified for disposal at WIPP utilizing Non-Destructive Examination (NDE) to verify the absence of prohibited items and Non-Destructive Assay (NDA) to verify the isotopic content under the TWPC WIPP certification program implemented by the Central Characterization Project (CCP). (authors)

Oakley, Brian; Heacker, Fred [WAI, TRU Waste Processing Center, 100 WIPP Road Lenoir City, TN 37771 (United States)] [WAI, TRU Waste Processing Center, 100 WIPP Road Lenoir City, TN 37771 (United States); McMillan, Bill [DOE, Oak Ridge Operations, Bldg. 2714, Oak Ridge, TN 37830 (United States)] [DOE, Oak Ridge Operations, Bldg. 2714, Oak Ridge, TN 37830 (United States)

2013-07-01T23:59:59.000Z

18

Solvent extraction and recovery of the transuranic elements from waste solutions using the TRUEX process  

SciTech Connect (OSTI)

High-level liquid waste is produced during the processing of irradiated nuclear fuel by the PUREX process. In some cases the treatment of metallurgical scrap to recover the plutonium values also generates a nitric acid waste solution. Both waste solutions contain sufficient concentrations of transuranic elements (mostly /sup 241/Am) to require handling and disposal as a TRU waste. This paper describes a recently developed solvent extraction/recovery process called TRUEX (transuranium extraction) which is designed to reduce the TRU concentration in nitric waste solutions to <100 nCi/g of disposed form (1,2). (In the USA, non-TRU waste is defined as <100 nCi of TRU/g of disposed form.) The process utilizes PUREX process solvent (TBP in a normal paraffinic hydrocarbon or carbon tetrachloride) modified by a small concentration of octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (abbrev. CMPO). The presence of CMPO enables the modified PUREX process solvent to extract trivalent actinides as well as tetra- and hexavalent actinides. A major feature of the TRUEX process is that is is applicable to waste solutions containing a wide range of nitric acid, salt, and fission product concentrations and at the same time is very compatible with existing liquid-liquid extraction technology as usually practiced in a fuel reprocessing plant. To date the process has been tested on two different types of synthetic waste solutions. The first solution is a typical high-level nitric acid waste and the second a typical waste solution generated in metallurgical scrap processing. Results are discussed. 4 refs., 1 fig., 4 tabs.

Horwitz, E.P.; Schulz, W.W.

1985-01-01T23:59:59.000Z

19

Transuranic Waste Processing Center (TWPC) Legacy Tank RH-TRU Sludge Processing and Compliance Strategy - 13255  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) needs to safely and efficiently treat its 'legacy' transuranic (TRU) waste and mixed low-level waste (LLW) from past research and defense activities at the Oak Ridge National Laboratory (ORNL) so that the waste is prepared for safe and secure disposal. The TWPC operates an Environmental Management (EM) waste processing facility on the Oak Ridge Reservation (ORR). The TWPC is classified as a Hazard Category 2, non-reactor nuclear facility. This facility receives, treats, and packages low-level waste and TRU waste stored at various facilities on the ORR for eventual off-site disposal at various DOE sites and commercial facilities. The Remote Handled TRU Waste Sludge held in the Melton Valley Storage Tanks (MVSTs) was produced as a result of the collection, treatment, and storage of liquid radioactive waste originating from the ORNL radiochemical processing and radioisotope production programs. The MVSTs contain most of the associated waste from the Gunite and Associated Tanks (GAAT) in the ORNL's Tank Farms in Bethel Valley and the sludge (SL) and associated waste from the Old Hydro-fracture Facility tanks and other Federal Facility Agreement (FFA) tanks. The SL Processing Facility Build-outs (SL-PFB) Project is integral to the EM cleanup mission at ORNL and is being accelerated by DOE to meet updated regulatory commitments in the Site Treatment Plan. To meet these commitments a Baseline (BL) Change Proposal (BCP) is being submitted to provide continued spending authority as the project re-initiation extends across fiscal year 2012 (FY2012) into fiscal year 2013. Future waste from the ORNL Building 3019 U-233 Disposition project, in the form of U-233 dissolved in nitric acid and water, down-blended with depleted uranyl nitrate solution is also expected to be transferred to the 7856 MVST Annex Facility (formally the Capacity Increase Project (CIP) Tanks) for co-processing with the SL. The SL-PFB project will construct and install the necessary integrated systems to process the accumulated MVST Facilities SL inventory at the TWPC thus enabling safe and effective disposal of the waste. This BCP does not include work to support current MVST Facility Surveillance and Maintenance programs or the ORNL Building 3019 U-233 Disposition project, since they are not currently part of the TWPC prime contract. The purpose of the environmental compliance strategy is to identify the environmental permits and other required regulatory documents necessary for the construction and operation of the SL- PFB at the TWPC, Oak Ridge, TN. The permits and other regulatory documents identified are necessary to comply with the environmental laws and regulations of DOE Orders, and other requirements documented in the SL-PFB, Safety Design Strategy (SDS), SL-A-AD-002, R0 draft, and the Systems, Function and Requirements Document (SFRD), SL-X-AD-002, R1 draft. This compliance strategy is considered a 'living strategy' and it is anticipated that it will be revised as design progresses and more detail is known. The design basis on which this environmental permitting and compliance strategy is based is the Wastren Advantage, Inc., (WAI), TWPC, SL-PFB (WAI-BL-B.01.06) baseline. (authors)

Rogers, Ben C.; Heacker, Fred K.; Shannon, Christopher [Wastren Advantage, Inc., Transuranic Waste Processing Center, 100 WIPP Road, Lenoir City, Tennessee 37771 (United States)] [Wastren Advantage, Inc., Transuranic Waste Processing Center, 100 WIPP Road, Lenoir City, Tennessee 37771 (United States); and others

2013-07-01T23:59:59.000Z

20

Transuranic waste characterization sampling and analysis plan  

SciTech Connect (OSTI)

Los Alamos National Laboratory (the Laboratory) is located approximately 25 miles northwest of Santa Fe, New Mexico, situated on the Pajarito Plateau. Technical Area 54 (TA-54), one of the Laboratory`s many technical areas, is a radioactive and hazardous waste management and disposal area located within the Laboratory`s boundaries. The purpose of this transuranic waste characterization, sampling, and analysis plan (CSAP) is to provide a methodology for identifying, characterizing, and sampling approximately 25,000 containers of transuranic waste stored at Pads 1, 2, and 4, Dome 48, and the Fiberglass Reinforced Plywood Box Dome at TA-54, Area G, of the Laboratory. Transuranic waste currently stored at Area G was generated primarily from research and development activities, processing and recovery operations, and decontamination and decommissioning projects. This document was created to facilitate compliance with several regulatory requirements and program drivers that are relevant to waste management at the Laboratory, including concerns of the New Mexico Environment Department.

NONE

1994-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Audit Report on "Waste Processing and Recovery Act Acceleration Efforts for Contact-Handled Transuranic Waste at the Hanford Site"  

SciTech Connect (OSTI)

The Department of Energy's Office of Environmental Management's (EM), Richland Operations Office (Richland), is responsible for disposing of the Hanford Site's (Hanford) transuranic (TRU) waste, including nearly 12,000 cubic meters of radioactive contact-handled TRU wastes. Prior to disposing of this waste at the Department's Waste Isolation Pilot Plant (WIPP), Richland must certify that it meets WIPP's waste acceptance criteria. To be certified, the waste must be characterized, screened for prohibited items, treated (if necessary) and placed into a satisfactory disposal container. In a February 2008 amendment to an existing Record of Decision (Decision), the Department announced its plan to ship up to 8,764 cubic meters of contact-handled TRU waste from Hanford and other waste generator sites to the Advanced Mixed Waste Treatment Project (AMWTP) at Idaho's National Laboratory (INL) for processing and certification prior to disposal at WIPP. The Department decided to maximize the use of the AMWTP's automated waste processing capabilities to compact and, thereby, reduce the volume of contact-handled TRU waste. Compaction reduces the number of shipments and permits WIPP to more efficiently use its limited TRU waste disposal capacity. The Decision noted that the use of AMWTP would avoid the time and expense of establishing a processing capability at other sites. In May 2009, EM allocated $229 million of American Recovery and Reinvestment Act of 2009 (Recovery Act) funds to support Hanford's Solid Waste Program, including Hanford's contact-handled TRU waste. Besides providing jobs, these funds were intended to accelerate cleanup in the short term. We initiated this audit to determine whether the Department was effectively using Recovery Act funds to accelerate processing of Hanford's contact-handled TRU waste. Relying on the availability of Recovery Act funds, the Department changed course and approved an alternative plan that could increase costs by about $25 million by processing Hanford TRU-waste on-site rather than at AMWTP. Further, under the newly adopted alternative approach, the Department would fail to achieve the previously anticipated reductions in volume associated with the use of existing AMWTP waste compaction capabilities.

None

2010-05-01T23:59:59.000Z

22

Waste Isolation Pilot Plant, National Transuranic Program Have...  

Office of Environmental Management (EM)

Waste Isolation Pilot Plant, National Transuranic Program Have Banner Year in 2013 Waste Isolation Pilot Plant, National Transuranic Program Have Banner Year in 2013 December 24,...

23

EM Makes Significant Progress on Dispositioning Transuranic Waste...  

Office of Environmental Management (EM)

EM Makes Significant Progress on Dispositioning Transuranic Waste at Idaho Site EM Makes Significant Progress on Dispositioning Transuranic Waste at Idaho Site December 24, 2013 -...

24

Process Knowledge Summary Report for Advanced Test Reactor Complex Contact-Handled Transuranic Waste Drum TRA010029  

SciTech Connect (OSTI)

This Process Knowledge Summary Report summarizes information collected to satisfy the transportation and waste acceptance requirements for the transfer of one drum containing contact-handled transuranic (TRU) actinide standards generated by the Idaho National Laboratory at the Advanced Test Reactor (ATR) Complex to the Advanced Mixed Waste Treatment Project (AMWTP) for storage and subsequent shipment to the Waste Isolation Pilot Plant for final disposal. The drum (i.e., Integrated Waste Tracking System Bar Code Number TRA010029) is currently stored at the Materials and Fuels Complex. The information collected includes documentation that addresses the requirements for AMWTP and applicable sections of their Resource Conservation and Recovery Act permits for receipt and disposal of this TRU waste generated from ATR. This Process Knowledge Summary Report includes information regarding, but not limited to, the generation process, the physical form, radiological characteristics, and chemical contaminants of the TRU waste, prohibited items, and packaging configuration. This report, along with the referenced supporting documents, will create a defensible and auditable record for this TRU waste originating from ATR.

B. R. Adams; R. P. Grant; P. R. Smith; J. L. Weisgerber

2013-09-01T23:59:59.000Z

25

Hanford Site Transuranic (TRU) Waste Certification Plan  

SciTech Connect (OSTI)

The Hanford Site Transuranic Waste Certification Plan establishes the programmatic framework and criteria with in which the Hanford Site ensures that contract-handled TRU wastes can be certified as compliant with the WIPP WAC and TRUPACT-II SARP.

GREAGER, T.M.

1999-12-14T23:59:59.000Z

26

Hanford Site Transuranic (TRU) Waste Certification Plan  

SciTech Connect (OSTI)

The Hanford Site Transuranic Waste Certification Plan establishes the programmatic framework and criteria within which the Hanford Site ensures that contract-handled TRU wastes can be certified as compliant with the WIPP WAC and TRUPACT-II SARP.

GREAGER, T.M.

1999-09-09T23:59:59.000Z

27

Los Alamos Transuranic Waste Size Reduction Facility  

SciTech Connect (OSTI)

The Los Alamos Transuranic (TRU) Waste Size Reduction Facility (SRF) is a production oriented prototype. The facility is operated to remotely cut and repackage TRU contaminated metallic wastes (e.g., glove boxes, ducting and pipes) for eventual disposal at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico. The resulting flat sections are packaged into a tested Department of Transportation Type 7A metal container. To date, the facility has successfully processed stainless steel glove boxes (with and without lead shielding construction) and retention tanks. We have found that used glove boxes generate more cutting fumes than do unused glove boxes or metal plates - possibly due to deeply embedded chemical residues from years of service. Water used as a secondary fluid with the plasma arc cutting system significantly reduces visible fume generation during the cutting of used glove boxes and lead-lined glove boxes. 2 figs., 1 tab.

Harper, J.; Warren, J.

1987-06-01T23:59:59.000Z

28

Transuranic Waste Characterization Quality Assurance Program Plan  

SciTech Connect (OSTI)

This quality assurance plan identifies the data necessary, and techniques designed to attain the required quality, to meet the specific data quality objectives associated with the DOE Waste Isolation Pilot Plant (WIPP). This report specifies sampling, waste testing, and analytical methods for transuranic wastes.

NONE

1995-04-30T23:59:59.000Z

29

Final Hanford Site Transuranic (TRU) Waste Characterization QA Project Plan  

SciTech Connect (OSTI)

The Transuranic Waste Characterization Quality Assurance Program Plan required each US Department of Energy (DOE) site that characterizes transuranic waste to be sent the Waste Isolation Pilot Plan that addresses applicable requirements specified in the QAPP.

GREAGER, T.M.

1999-09-09T23:59:59.000Z

30

ACCELERATION OF LOS ALAMOS NATIONAL LABORATORY TRANSURANIC WASTE DISPOSITION  

SciTech Connect (OSTI)

One of Los Alamos National Laboratory's (LANL's) most significant risks is the site's inventory of transuranic waste retrievably stored above and below-ground in Technical Area (TA) 54 Area G, particularly the dispersible high-activity waste stored above-ground in deteriorating facilities. The high activity waste represents approximately 50% (by activity) of the total 292,000 PE-Ci inventory remaining to be disposed. The transuramic waste inventory includes contact-handled and remote-handled waste packaged in drums, boxes, and oversized containers which are retrievably stored both above and below-ground. Although currently managed as transuranic waste, some of the inventory is low-level waste that can be disposed onsite or at approved offsite facilities. Dispositioning the transuranic waste inventory requires retrieval of the containers from above and below-ground storage, examination and repackaging or remediation as necessary, characterization, certification and loading for shipment to the Waste Isolation Pilot Plant in Carlsbad New Mexico, all in accordance with well-defined requirements and controls. Although operations are established to process and characterize the lower-activity contact-handled transuranic waste containers, LAN L does not currently have the capability to repack high activity contact-handled transuranic waste containers (> 56 PE-Ci) or to process oversized containers with activity levels over 0.52 PE-Ci. Operational issues and compliance requirements have resulted in less than optimal processing capabilities for lower activity contact-handled transuranic waste containers, limiting preparation and reducing dependability of shipments to the Waste Isolation Pilot Plant. Since becoming the Los Alamos National Laboratory contract in June 2006, Los Alamos National Security (LANS) L.L.C. has developed a comprehensive, integrated plan to effectively and efficiently disposition the transuranic waste inventory, working in concert with the Department of Energy Los Alamos Site Office, Carlsbad Field Office and the Department of Energy Headquaeters. Rather than simply processing containers as retrieved, the plan places priority on efficient curie disposition, a direct correlation to reducing risk. Key elements of the approch include balancing inventory and operational risks, tailoring methods to meet requirements, optimizing existing facilities, equipment and staff, and incorporating best practices from other Department of Energy sites. With sufficient funding this will enable LANL to ship the above-ground high activity contact-handled transuranic waste offsite by the end of Fiscal Year (FY) 2007 and to disposition the remaining above- and below-ground contact-handled and remote-handled transuranic waste inventory by December 2010. Nearly 70% of the contact-handled transuranic waste containers, including the high activity waste, require processing and repackaging before characterization and certification for shipment to the Waste Isolation Pilot Plant. LANL is employing a balanced risk approach that accomplishes significant long-term risk reduction by accepting short-term increased facility operations risk under well-developed and justified interim controls. Reviews of facility conditions and additional analyses show that the Waste Characterization, Reduction and Repackaging Facility and the Radioassay and Nondestructive Testing Facility are the most appropriate facilities to safetly remediate, repackage, and ship lower activity and the remaining high activity drums. Updated safety documentation supporting limited Hazard Category 2 operations in these facilities has been developed. Once approved, limited-term operations to process the high activity drums can begin in early 2007, building upon the experience base established performing Hazard Category 3 operations processing lower activity waste in these facilities. LANL is also implementing a series of actions to improve and sustain operations for processing contact-handled transuranic waste inventory. Building 412 Decontamination and Volume Facility and Dom

O'LEARY, GERALD A. [Los Alamos National Laboratory

2007-01-04T23:59:59.000Z

31

Remote-handled transuranic waste study  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP) was developed by the US Department of Energy (DOE) as a research and development facility to demonstrate the safe disposal of transuranic (TRU) radioactive wastes generated from the Nation`s defense activities. The WIPP disposal inventory will include up to 250,000 cubic feet of TRU wastes classified as remote handled (RH). The remaining inventory will include contact-handled (CH) TRU wastes, which characteristically have less specific activity (radioactivity per unit volume) than the RH-TRU wastes. The WIPP Land Withdrawal Act (LWA), Public Law 102-579, requires a study of the effect of RH-TRU waste on long-term performance. This RH-TRU Waste Study has been conducted to satisfy the requirements defined by the LWA and is considered by the DOE to be a prudent exercise in the compliance certification process of the WIPP repository. The objectives of this study include: conducting an evaluation of the impacts of RH-TRU wastes on the performance assessment (PA) of the repository to determine the effects of Rh-TRU waste as a part of the total WIPP disposal inventory; and conducting a comparison of CH-TRU and RH-TRU wastes to assess the differences and similarities for such issues as gas generation, flammability and explosiveness, solubility, and brine and geochemical interactions. This study was conducted using the data, models, computer codes, and information generated in support of long-term compliance programs, including the WIPP PA. The study is limited in scope to post-closure repository performance and includes an analysis of the issues associated with RH-TRU wastes subsequent to emplacement of these wastes at WIPP in consideration of the current baseline design. 41 refs.

NONE

1995-10-01T23:59:59.000Z

32

Combined transuranic-strontium extraction process  

DOE Patents [OSTI]

The transuranic (TRU) elements neptunium, plutonium and americium can be separated together with strontium from nitric acid waste solutions in a single process. An extractant solution of a crown ether and an alkyl(phenyl)-N,N-dialkylcarbanylmethylphosphine oxide in an appropriate diluent will extract the TRU's together with strontium, uranium and technetium. The TRU's and the strontium can then be selectively stripped from the extractant for disposal.

Horwitz, E. Philip (Naperville, IL); Dietz, Mark L. (Evanston, IL)

1992-01-01T23:59:59.000Z

33

Combined transuranic-strontium extraction process  

DOE Patents [OSTI]

The transuranic (TRU) elements neptunium, plutonium and americium can be separated together with strontium from nitric acid waste solutions in a single process. An extractant solution of a crown ether and an alkyl(phenyl)-N,N-dialkylcarbanylmethylphosphine oxide in an appropriate diluent will extract the TRU's together with strontium, uranium and technetium. The TRU's and the strontium can then be selectively stripped from the extractant for disposal. 3 figs.

Horwitz, E.P.; Dietz, M.L.

1992-12-08T23:59:59.000Z

34

Combined transuranic-strontium extraction process  

SciTech Connect (OSTI)

The transuranic (TRU) elements neptunium, plutonium and amercium can be separated together with strontium from nitric acid waste solutions in a single process. An extractant solution of a crown ether and an alkyl(phenyl)-N.N-dialkylcarbanylmethylphosphine oxide in an appropriate diluent will extract the TRU`s to gather with strontium, uranium and technetium. The TRU`s and the strontium can then be selectively stripped from the extractant for disposal.

Horwitz, E.P.; Dietz, M.L.

1991-12-31T23:59:59.000Z

35

Hanford site transuranic waste sampling plan  

SciTech Connect (OSTI)

This sampling plan (SP) describes the selection of containers for sampling of homogeneous solids and soil/gravel and for visual examination of transuranic and mixed transuranic (collectively referred to as TRU) waste generated at the U.S. Department of Energy (DOE) Hanford Site. The activities described in this SP will be conducted under the Hanford Site TRU Waste Certification Program. This SP is designed to meet the requirements of the Transuranic Waste Characterization Quality Assurance Program Plan (CAO-94-1010) (DOE 1996a) (QAPP), site-specific implementation of which is described in the Hanford Site Transuranic Waste Characterization Program Quality Assurance Project Plan (HNF-2599) (Hanford 1998b) (QAPP). The QAPP defines the quality assurance (QA) requirements and protocols for TRU waste characterization activities at the Hanford Site. In addition, the QAPP identifies responsible organizations, describes required program activities, outlines sampling and analysis strategies, and identifies procedures for characterization activities. The QAPP identifies specific requirements for TRU waste sampling plans. Table 1-1 presents these requirements and indicates sections in this SP where these requirements are addressed.

GREAGER, T.M.

1999-05-13T23:59:59.000Z

36

LINAC-based transuranic waste characterization system  

SciTech Connect (OSTI)

Remote-handled transuranic nuclear waste poses a particular challenge for assaying due to the high neutron and gamma ray background that emanates from the non-fissile, but highly radioactive material, contained with the waste. The utilization of a RFQ linac with a neutron flux has shown that, in principle, the differential die-away technique can reliably assay this special class of nuclear waste.

Schultz, F.J.; Womble, P.C. [Oak Ridge National Lab., TN (United States); Vourvopoulos, G. [Western Kentucky Univ., Bowling Green, KY (United States); Roberts, M.L. [Lawrence Livermore National Lab., CA (United States)

1994-12-31T23:59:59.000Z

37

Physical Properties of Hanford Transuranic Waste  

SciTech Connect (OSTI)

The research described herein was undertaken to provide needed physical property descriptions of the Hanford transuranic tank sludges under conditions that might exist during retrieval, treatment, packaging and transportation for disposal. The work addressed the development of a fundamental understanding of the types of systems represented by these sludge suspensions through correlation of the macroscopic rheological properties with particle interactions occurring at the colloidal scale in the various liquid media. The results of the work have advanced existing understanding of the sedimentation and aggregation properties of complex colloidal suspensions. Bench scale models were investigated with respect to their structural, colloidal and rheological properties that should be useful for the development and optimization of techniques to process the wastes at various DOE sites.

Berg, John C.

2010-03-25T23:59:59.000Z

38

Hanford Site Transuranic (TRU) Waste Certification Plan  

SciTech Connect (OSTI)

As a generator of transuranic (TRU) and TRU mixed waste destined for disposal at the Waste Isolation Pilot Plant (WIPP), the Hanford Site must ensure that its TRU waste meets the requirements of US. Department of Energy (DOE) 0 435.1, ''Radioactive Waste Management,'' and the Contact-Handled (CH) Transuranic Waste Acceptance Criteria for the Waste Isolation Pilot Plant (WIPP-WAC). WIPP-WAC requirements are derived from the WIPP Technical Safety Requirements, WIPP Safety Analysis Report, TRUPACT-II SARP, WIPP Land Withdrawal Act, WIPP Hazardous Waste Facility Permit, and Title 40 Code of Federal Regulations (CFR) 191/194 Compliance Certification Decision. The WIPP-WAC establishes the specific physical, chemical, radiological, and packaging criteria for acceptance of defense TRU waste shipments at WIPP. The WPP-WAC also requires that participating DOE TRU waste generator/treatment/storage sites produce site-specific documents, including a certification plan, that describe their program for managing TRU waste and TRU waste shipments before transferring waste to WIPP. Waste characterization activities provide much of the data upon which certification decisions are based. Waste characterization requirements for TRU waste and TRU mixed waste that contains constituents regulated under the Resource Conservation and Recovery Act (RCRA) are established in the WIPP Hazardous Waste Facility Permit Waste Analysis Plan (WAP). The Hanford Site Quality Assurance Project Plan (QAPjP) (HNF-2599) implements the applicable requirements in the WAP and includes the qualitative and quantitative criteria for making hazardous waste determinations. The Hanford Site must also ensure that its TRU waste destined for disposal at WPP meets requirements for transport in the Transuranic Package Transporter-11 (TRUPACT-11). The US. Nuclear Regulatory Commission (NRC) establishes the TRUPACT-11 requirements in the Safety Analysis Report for the TRUPACT-II Shipping Package (TRUPACT-11 SARP). In addition, a TRU waste is eligible for disposal at WIPP only if it has been generated in whole or in part by one or more of the activities listed in Section 10101(3) of the Nuclear Waste Policy Act. DOE sites must determine that each waste stream to be disposed of at WIPP is ''defense'' TRU waste. (See also the definition of ''defense'' TRU waste.). Only CH TRU wastes meeting the requirements of the QAPjP, WIPP-WAP, WPP-WAC, and other requirements documents described above will be accepted for transportation and disposal at WIPP.

GREAGER, T.M.

2000-12-06T23:59:59.000Z

39

Hanford Site Transuranic (TRU) Waste Certification Plan  

SciTech Connect (OSTI)

As a generator of transuranic (TRU) and TRU mixed waste destined for disposal at the Waste Isolation Pilot Plant (WIPP), the Hanford Site must ensure that its TRU waste meets the requirements of US. Department of Energy (DOE) 0 435.1, ''Radioactive Waste Management,'' and the Contact-Handled (CH) Transuranic Waste Acceptance Criteria for the Waste Isolation Pilot Plant (WIPP-WAC). WIPP-WAC requirements are derived from the WIPP Technical Safety Requirements, WIPP Safety Analysis Report, TRUPACT-II SARP, WIPP Land Withdrawal Act, WIPP Hazardous Waste Facility Permit, and Title 40 Code of Federal Regulations (CFR) 191/194 Compliance Certification Decision. The WIPP-WAC establishes the specific physical, chemical, radiological, and packaging criteria for acceptance of defense TRU waste shipments at WIPP. The WPP-WAC also requires that participating DOE TRU waste generator/treatment/storage sites produce site-specific documents, including a certification plan, that describe their program for managing TRU waste and TRU waste shipments before transferring waste to WIPP. Waste characterization activities provide much of the data upon which certification decisions are based. Waste characterization requirements for TRU waste and TRU mixed waste that contains constituents regulated under the Resource Conservation and Recovery Act (RCRA) are established in the WIPP Hazardous Waste Facility Permit Waste Analysis Plan (WAP). The Hanford Site Quality Assurance Project Plan (QAPjP) (HNF-2599) implements the applicable requirements in the WAP and includes the qualitative and quantitative criteria for making hazardous waste determinations. The Hanford Site must also ensure that its TRU waste destined for disposal at WPP meets requirements for transport in the Transuranic Package Transporter-11 (TRUPACT-11). The US. Nuclear Regulatory Commission (NRC) establishes the TRUPACT-11 requirements in the Safety Analysis Report for the TRUPACT-II Shipping Package (TRUPACT-11 SARP). In addition, a TRU waste is eligible for disposal at WIPP only if it has been generated in whole or in part by one or more of the activities listed in Section 10101(3) of the Nuclear Waste Policy Act. DOE sites must determine that each waste stream to be disposed of at WIPP is ''defense'' TRU waste. (See also the definition of ''defense'' TRU waste.). Only CH TRU wastes meeting the requirements of the QAPjP, WIPP-WAP, WPP-WAC, and other requirements documents described above will be accepted for transportation and disposal at WIPP.

GREAGER, T.M.

2000-12-01T23:59:59.000Z

40

Application to ship nonmixed transuranic waste to the Nevada Test Site for interim storage. Waste Cerification Program  

SciTech Connect (OSTI)

This report documents various regulations on radioactive waste processing and discusses how the Waste Isolation Pilot Plant will comply with and meet these requirements. Specific procedures are discussed concerning transuranic, metal scrap, salt block, solid, and glove box wastes.

Not Available

1993-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Hanford site transuranic waste certification plan  

SciTech Connect (OSTI)

As a generator of transuranic (TRU) and TRU mixed waste destined for disposal at the Waste Isolation Pilot Plant (WIPP), the Hanford Site must ensure that its TRU waste meets the requirements of U.S. Department of Energy (DOE) Order 5820.2A, ''Radioactive Waste Management, and the Waste Acceptance Criteria for the Waste Isolation Pilot Plant' (DOE 1996d) (WIPP WAC). The WIPP WAC establishes the specific physical, chemical, radiological, and packaging criteria for acceptance of defense TRU waste shipments at WIPP. The WIPP WAC also requires that participating DOE TRU waste generator/treatment/storage sites produce site-specific documents, including a certification plan, that describe their management of TRU waste and TRU waste shipments before transferring waste to WIPP. The Hanford Site must also ensure that its TRU waste destined for disposal at WIPP meets requirements for transport in the Transuranic Package Transporter41 (TRUPACT-11). The U.S. Nuclear Regulatory Commission (NRC) establishes the TRUPACT-I1 requirements in the ''Safety Analysis Report for the TRUPACT-II Shipping Package'' (NRC 1997) (TRUPACT-I1 SARP).

GREAGER, T.M.

1999-05-12T23:59:59.000Z

42

Final Hanford Site Transuranic (TRU) Waste Characterization QA Project Plan  

SciTech Connect (OSTI)

The Quality Assurance Project Plan (QAPjP) has been prepared for waste characterization activities to be conducted by the Transuranic (TRU) Project at the Hanford Site to meet requirements set forth in the Waste Isolation Pilot Plan (WIPP) Hazardous Waste Facility Permit, 4890139088-TSDF, Attachment B, including Attachments B1 through B6 (WAP) (DOE, 1999a). The QAPjP describes the waste characterization requirements and includes test methods, details of planned waste sampling and analysis, and a description of the waste characterization and verification process. In addition, the QAPjP includes a description of the quality assurance/quality control (QA/QC) requirements for the waste characterization program. Before TRU waste is shipped to the WIPP site by the TRU Project, all applicable requirements of the QAPjP shall be implemented. Additional requirements necessary for transportation to waste disposal at WIPP can be found in the ''Quality Assurance Program Document'' (DOE 1999b) and HNF-2600, ''Hanford Site Transuranic Waste Certification Plan.'' TRU mixed waste contains both TRU radioactive and hazardous components, as defined in the WLPP-WAP. The waste is designated and separately packaged as either contact-handled (CH) or remote-handled (RH), based on the radiological dose rate at the surface of the waste container. RH TRU wastes are not currently shipped to the WIPP facility.

GREAGER, T.M.

2000-12-06T23:59:59.000Z

43

Transuranic contaminated waste form characterization and data base  

SciTech Connect (OSTI)

This volume contains 5 appendices. Title listing are: technologies for recovery of transuranics; nondestructive assay of TRU contaminated wastes; miscellaneous waste characteristics; acceptance criteria for TRU waste; and TRU waste treatment technologies.

Kniazewycz, B.G.; McArthur, W.C.

1980-07-01T23:59:59.000Z

44

In situ vitrification: application analysis for stabilization of transuranic waste  

SciTech Connect (OSTI)

The in situ vitrification process builds upon the electric melter technology previously developed for high-level waste immobilization. In situ vitrification converts buried wastes and contaminated soil to an extremely durable glass and crystalline waste form by melting the materials, in place, using joule heating. Once the waste materials have been solidified, the high integrity waste form should not cause future ground subsidence. Environmental transport of the waste due to water or wind erosion, and plant or animal intrusion, is minimized. Environmental studies are currently being conducted to determine whether additional stabilization is required for certain in-ground transuranic waste sites. An applications analysis has been performed to identify several in situ vitrification process limitations which may exist at transuranic waste sites. Based on the process limit analysis, in situ vitrification is well suited for solidification of most in-ground transuranic wastes. The process is best suited for liquid disposal sites. A site-specific performance analysis, based on safety, health, environmental, and economic assessments, will be required to determine for which sites in situ vitrification is an acceptable disposal technique. Process economics of in situ vitrification compare favorably with other in-situ solidification processes and are an order of magnitude less than the costs for exhumation and disposal in a repository. Leachability of the vitrified product compares closely with that of Pyrex glass and is significantly better than granite, marble, or bottle glass. Total release to the environment from a vitrified waste site is estimated to be less than 10/sup -5/ parts per year. 32 figures, 30 tables.

Oma, K.H.; Farnsworth, R.K.; Rusin, J.M.

1982-09-01T23:59:59.000Z

45

Final Hanford Site Transuranic (TRU) Waste Characterization QA Project Plan  

SciTech Connect (OSTI)

The Transuranic Waste Characterization Quality Assurance Program Plan required each U.S. Department of Energy (DOE) site that characterizes transuranic waste to be sent the Waste Isolation Pilot Plan that addresses applicable requirements specified in the quality assurance project plan (QAPP).

GREAGER, T.M.

1999-12-14T23:59:59.000Z

46

EVALUATION OF ALTERNATIVE STRONIUM AND TRANSURANIC SEPARATION PROCESSES  

SciTech Connect (OSTI)

In order to meet contract requirements on the concentrations of strontium-90 and transuranic isotopes in the immobilized low-activity waste, strontium-90 and transuranics must be removed from the supernate of tanks 241-AN-102 and 241-AN-107. The process currently proposed for this application is an in-tank precipitation process using strontium nitrate and sodium permanganate. Development work on the process has not proceeded since 2005. The purpose of the evaluation is to identify whether any promising alternative processes have been developed since this issue was last examined, evaluate the alternatives and the baseline process, and recommend which process should be carried forward.

SMALLEY CS

2011-04-25T23:59:59.000Z

47

Transuranic waste baseline inventory report. Revision No. 3  

SciTech Connect (OSTI)

The Transuranic Waste Baseline Inventory Report (TWBIR) establishes a methodology for grouping wastes of similar physical and chemical properties from across the U.S. Department of Energy (DOE) transuranic (TRU) waste system into a series of {open_quotes}waste profiles{close_quotes} that can be used as the basis for waste form discussions with regulatory agencies. The purpose of Revisions 0 and 1 of this report was to provide data to be included in the Sandia National Laboratories/New Mexico (SNL/NM) performance assessment (PA) processes for the Waste Isolation Pilot Plant (WIPP). Revision 2 of the document expanded the original purpose and was also intended to support the WIPP Land Withdrawal Act (LWA) requirement for providing the total DOE TRU waste inventory. The document included a chapter and an appendix that discussed the total DOE TRU waste inventory, including nondefense, commercial, polychlorinated biphenyls (PCB)-contaminated, and buried (predominately pre-1970) TRU wastes that are not planned to be disposed of at WIPP.

NONE

1996-06-01T23:59:59.000Z

48

Transuranic Waste Retrieval and Certification - Hanford Site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatusButlerTransportation From modeling andTransuranic Waste

49

Transuranic Waste Transportation Containers - Fact Sheet  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatusButlerTransportation From modeling andTransuranic WasteTypes of

50

Contact-Handled and Remote-Handled Transuranic Waste Packaging  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

Provides specific instructions for packaging and/or repackaging contact-handled transuranic (CH-TRU) and remote-handled transuranic (RH-TRU) waste in a manner consistent with DOE O 435.1, Radioactive Waste Management, DOE M 435.1-1 Chg 1, Radioactive Waste Management Manual, CH-TRU and RH-TRU waste transportation requirements, and Waste Isolation Pilot Plant (WIPP) programmatic requirements. Does not cancel other directives.

2011-08-09T23:59:59.000Z

51

DESTRUCTION TECHNOLOGY DEMONSTRATION FOR ORGANICS IN TRANSURANIC WASTE  

SciTech Connect (OSTI)

General Atomics (GA) has recently completed a Phase I program for the development of a two-step alternative to incineration for the destruction of organics in transuranic wastes at the Savannah River Site. This process is known as thermal desorption-supercritical water oxidation, or TD-SCWO. The GA TD process uses heat to volatilize and transport organics from the waste material for subsequent treatment by SCWO. SCWO oxidizes organics in a steam medium at elevated temperatures and pressures in a manner that achieves excellent destruction efficiencies and compliance with all environmental requirements without the need for complex pollution-abatement equipment. This application of TD-SCWO is focused on a full-scale batch process for 55-gallon drums of mixed transuranic waste at the Savannah River Site. The Phase I reduced-scale test results show that the process operates as intended on surrogate waste matrices chosen to be representative of Savannah River Site transuranic mixed wastes. It provides a high degree of hydrogen removal and full containment of the radionuclide surrogate, with minimal requirements for pre-treatment and post-treatment. Other test objectives were to verify that the process produces no dioxins or furans, and meets all applicable regulatory criteria for retention of toxic metals, particulate, and criteria pollutants, while meeting WIPP/WAC and TRUPACT-II requirements. Thermal desorption of surrogate SRS mixed wastes at 500 psi and 1000 F met all tested requirements for WIPP/WAC and TRUPACT-II. SCWO of the desorbed surrogate organic materials at 500 psi and 1500 F also appears to meet all requirements for a nonincineration alternative, although >99.99% DRE for chlorinated solvents has not yet been demonstrated.

Mike Spritzer

2003-02-01T23:59:59.000Z

52

Repository disposal requirements for commercial transuranic wastes (generated without reprocessing)  

SciTech Connect (OSTI)

This report forms a preliminary planning basis for disposal of commercial transuranic (TRU) wastes in a geologic repository. Because of the unlikely prospects for commercial spent nuclear fuel reprocessing in the near-term, this report focuses on TRU wastes generated in a once-through nuclear fuel cycle. The four main objectives of this study were to: develop estimates of the current inventories, projected generation rates, and characteristics of commercial TRU wastes; develop proposed acceptance requirements for TRU wastes forms and waste canisters that ensure a safe and effective disposal system; develop certification procedures and processing requirements that ensure that TRU wastes delivered to a repository for disposal meet all applicable waste acceptance requirements; and identify alternative conceptual strategies for treatment and certification of commercial TRU first objective was accomplished through a survey of commercial producers of TRU wastes. The TRU waste acceptance and certification requirements that were developed were based on regulatory requirements, information in the literature, and from similar requirements already established for disposal of defense TRU wastes in the Waste Isolation Pilot Plant (WIPP) which were adapted, where necessary, to disposal of commercial TRU wastes. The results of the TRU waste-producer survey indicated that there were a relatively large number of producers of small quantities of TRU wastes.

Daling, P.M.; Ludwick, J.D.; Mellinger, G.B.; McKee, R.W.

1986-06-01T23:59:59.000Z

53

Transuranic waste characterization sampling and analysis methods manual  

SciTech Connect (OSTI)

The Transuranic Waste Characterization Sampling and Analysis Methods Manual (Methods Manual) provides a unified source of information on the sampling and analytical techniques that enable Department of Energy (DOE) facilities to comply with the requirements established in the current revision of the Transuranic Waste Characterization Quality Assurance Program Plan (QAPP) for the Waste Isolation Pilot Plant (WIPP) Transuranic (TRU) Waste Characterization Program (the Program). This Methods Manual includes all of the testing, sampling, and analytical methodologies accepted by DOE for use in implementing the Program requirements specified in the QAPP.

NONE

1995-05-01T23:59:59.000Z

54

DOE Issues Final Request for Proposal for Oak Ridge Transuranic...  

Office of Environmental Management (EM)

Oak Ridge Transuranic Waste Processing Center Services DOE Issues Final Request for Proposal for Oak Ridge Transuranic Waste Processing Center Services October 14, 2014 - 2:16pm...

55

Idaho National Engineering Laboratory code assessment of the Rocky Flats transuranic waste  

SciTech Connect (OSTI)

This report is an assessment of the content codes associated with transuranic waste shipped from the Rocky Flats Plant in Golden, Colorado, to INEL. The primary objective of this document is to characterize and describe the transuranic wastes shipped to INEL from Rocky Flats by item description code (IDC). This information will aid INEL in determining if the waste meets the waste acceptance criteria (WAC) of the Waste Isolation Pilot Plant (WIPP). The waste covered by this content code assessment was shipped from Rocky Flats between 1985 and 1989. These years coincide with the dates for information available in the Rocky Flats Solid Waste Information Management System (SWIMS). The majority of waste shipped during this time was certified to the existing WIPP WAC. This waste is referred to as precertified waste. Reassessment of these precertified waste containers is necessary because of changes in the WIPP WAC. To accomplish this assessment, the analytical and process knowledge available on the various IDCs used at Rocky Flats were evaluated. Rocky Flats sources for this information include employee interviews, SWIMS, Transuranic Waste Certification Program, Transuranic Waste Inspection Procedure, Backlog Waste Baseline Books, WIPP Experimental Waste Characterization Program (headspace analysis), and other related documents, procedures, and programs. Summaries are provided of: (a) certification information, (b) waste description, (c) generation source, (d) recovery method, (e) waste packaging and handling information, (f) container preparation information, (g) assay information, (h) inspection information, (i) analytical data, and (j) RCRA characterization.

NONE

1995-07-01T23:59:59.000Z

56

Dangerous Waste Characteristics of Contact-Handled Transuranic Mixed Wastes from the Hanford Tanks  

SciTech Connect (OSTI)

This report summarizes existing analytical data from samples taken from the Hanford tanks designated as potentially containing transuranic mixed process wastes. Process knowledge of the wastes transferred to these tanks has been reviewed to determine whether the dangerous waste characteristics now assigned to all Hanford underground storage tanks are applicable to these particular wastes. Supplemental technologies are being examined to accelerate the Hanford tank waste cleanup mission and accomplish waste treatment safely and efficiently. To date, 11 Hanford waste tanks have been designated as potentially containing contact-handled (CH) transuranic mixed (TRUM) wastes. The CH-TRUM wastes are found in single-shell tanks B-201 through B-204, T-201 through T-204, T-104, T-110, and T-111. Methods and equipment to solidify and package the CH-TRUM wastes are part of the supplemental technologies being evaluated. The resulting packages and wastes must be acceptable for disposal at the Waste Isolation Pilot Plant (WIPP). The dangerous waste characteristics being considered include ignitability, corrosivity, reactivity, and toxicity arising from the presence of 2,4,5-trichlorophenol at levels above the dangerous waste threshold. The analytical data reviewed include concentrations of sulfur, sulfate, cyanide, 2,4,5-trichlorophenol, total organic carbon, and oxalate; the composition of the tank headspace, pH, and mercury. Differential scanning calorimetry results were used to determine the energetics of the wastes as a function of temperature.

Tingey, Joel M.; Bryan, Garry H.; Deschane, Jaquetta R.

2004-08-31T23:59:59.000Z

57

Economic evaluation of volume reduction for Defense transuranic waste  

SciTech Connect (OSTI)

This study evaluates the economics of volume reduction of retrievably stored and newly generated DOE transuranic waste by comparing the costs of reduction of the waste with the savings possible in transportation and disposal of the waste. The report develops a general approach to the comparison of TRU waste volume reduction costs and cost savings, establishes an initial set of cost data, and develops conclusions to support selecting technologies and facilities for the disposal of DOE transuranic waste. Section I outlines the analysis which considers seven types of volume reduction from incineration and compaction of combustibles to compaction, size reduction, shredding, melting, and decontamination of metals. The study considers the volume reduction of contact-handled newly generated, and retrievably stored DOE transuranic waste. Section II of this report describes the analytical approach, assumptions, and flow of waste material through sites. Section III presents the waste inventories, disposal, and transportation savings with volume reduction and the volume reduction techniques and savings.

Brown, C.M.

1981-07-01T23:59:59.000Z

58

Oak Ridge National Laboratory Transuranic Waste Certification Program  

SciTech Connect (OSTI)

The US Department of Energy (DOE) has requested that all DOE facilities handling defense transuranic (TRU) waste develop and implement a program whereby all TRU waste will be contained, stored, and shipped to the Waste Isolation Pilot Plant (WIPP) in accordance with the requirements set forth in the DOE certification documents WIPP-DOE-069, 114, 120, 137, 157, and 158. The program described in this report describes how Oak Ridge National Laboratory (ORNL) intends to comply with these requirements and the techniques and procedures used to ensure that ORNL TRU wastes are certifiable for shipment to WIPP. This document describes the program for certification of newly generated (NG) contact-handled transuranic (CH-TRU) waste. Previsions have been made for addenda, which will extend the coverage of this document to include certification of stored CH-TRU and NG and stored remote-handled transuranic (RH-TRU) waste, as necessary. 24 refs., 11 figs., 4 tabs.

Smith, J.H.; Bates, L.D.; Box, W.D.; Aaron, W.S.; Setaro, J.A.

1988-08-01T23:59:59.000Z

59

Transuranic contaminated waste form characterization and data base  

SciTech Connect (OSTI)

This report outlines the sources, quantities, characteristics and treatment of transuranic wastes in the United States. This document serves as part of the data base necessary to complete preparation and initiate implementation of transuranic wastes, waste forms, waste container and packaging standards and criteria suitable for inclusion in the present NRC waste management program. No attempt is made to evaluate or analyze the suitability of one technology over another. Indeed, by the nature of this report, there is little critical evaluation or analysis of technologies because such analysis is only appropriate when evaluating a particular application or transuranic waste streams. Due to fiscal restriction, the data base is developed from a myriad of technical sources and does not necessarily contain operating experience and the current status of all technologies. Such an effort was beyond the scope of this report.

McArthur, W.C.; Kniazewycz, B.G.

1980-07-01T23:59:59.000Z

60

Accelerating the disposition of transuranic waste from LANL - 9495  

SciTech Connect (OSTI)

Los Alamos National Laboratory (LANL) was established during World War II with a single mission -- to design and build an atomic bomb. In the 65 years since, nuclear weapons physics, design and engineering have been the Laboratory's primary and sustaining mission. Experimental and process operations -- and associated cleanout and upgrade activities -- have generated a significant inventory of transuranic (TRU) waste that is stored at LANL's Technical Area 54, Material Disposal Area G (MDA G). When the Waste Isolation Pilot Plant (WIPP) opened its doors in 1999, LANL's TRU inventory totaled about 10,200 m{sup 3}, with a plutonium 239-equivalent curie (PE Ci) content of approximately 250,000 curies. By December 2008, a total of about 2,300 m3 (61,000 PE Ci) had been shipped to WIPP from LANL. This has resulted in a net reduction of about 1,000 m{sup 3} of TRU inventory over that time frame. This paper presents progress in dispositioning legacy and newly-generated transuranic waste (TRU) from ongoing missions at the LANL. The plans for, and lessons learned, in dispositioning several hundred high-activity TRU waste drums are reviewed. This waste population was one of the highest risks at LANL. Technical challenges in disposition of the high-activity drums are presented. These provide a preview of challenges to be addressed in dispositioning the remaining 6,800 m{sup 3} of TRU stored above ground and 2,400 m{sup 3} of TRU waste that is 'retrievably' stored below-grade. LANL is using subcontractors for much of this work and has formed a strong partnership with WIPP and its contractor to address this cleanup challenge.

Shepard, Mark D [Los Alamos National Laboratory; Stiger, Susan G [Los Alamos National Laboratory; Blankenhorn, James A [Los Alamos National Laboratory; Rael, George J [Los Alamos National Laboratory; Moody, David C [U.S DOE

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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61

Keeping Track of the National Transuranic Program Complex Defense Transuranic Waste  

SciTech Connect (OSTI)

The long-term performance of the Waste Isolation Pilot Plant (WIPP) disposal system in southeastern New Mexico is assessed periodically using transuranic (TRU) waste physical and radiological properties and other information describing the waste. This TRU waste estimate is based on the best knowledge of the TRU waste across the DOE complex at the time repository performance is assessed. TRU waste inventory was collected from each of the Department of Energy (DOE) sites that generated TRU waste for the Compliance Certification Application (CCA) and subsequently for the Compliance Re-certification Application (CRA) in order to support the assessments that ultimately led to certification and re-certification of the WIPP. In each case, information was collected, stored and maintained in the Transuranic Waste Baseline Inventory Database (TWBID) that was used to generate tables describing the volumetric, physical, and radiological properties of the TRU waste. The tables and other descriptions of the waste were reported in baseline reports for the certification and the re-certification. Information maintained in the TWBID database has now been transferred to a new qualified database that utilizes a more efficient operating configuration. This database known as the Comprehensive Inventory Database (CID) will be the information repository for TRU waste destined to WIPP, and the source for information submitted for annual Transuranic Waste Inventory Update Reports to be used in future repository performance assessments (PAs) and re-certifications. The information that has been collected will support a wider range of data needs including waste management, transportation and strategic planning. (authors)

Crawford, B.; Lott, S.; McInroy, W.; VanSoest, G. [Los Alamos National Laboratory-Carlsbad Operations, Carlsbad, NM (United States); Patterson, R. [U.S. Department of Energy Carlsbad Field Office, Carlsbad, NM (United States)

2007-07-01T23:59:59.000Z

62

Waste Isolation Pilot Plant Transuranic Waste Baseline inventory report. Volume 1. Revision 1  

SciTech Connect (OSTI)

This document provides baseline inventories of transuranic wastes for the WIPP facility. Information on waste forms, forecasting of future inventories, and waste stream originators is also provided. A diskette is provided which contains the inventory database.

NONE

1995-02-01T23:59:59.000Z

63

Technical Evaluations of Proposed Remote-Handled Transuranic Waste Characterization Requirements at WIPP  

SciTech Connect (OSTI)

Characterization, packaging, transport, handling and disposal of remotely handled transuranic (RH TRU) waste at WIPP will be different than similar operations with contact handled transuranic (CH TRU) waste. This paper presents results of technical evaluations associated with the planned disposal of remotely handled transuranic waste at the Waste Isolation Pilot Plant (WIPP).

Anastas, G.; Channell, J. K.

2002-02-26T23:59:59.000Z

64

Documentation of acceptable knowledge for LANL Plutonium Facility transuranic waste streams  

SciTech Connect (OSTI)

Characterization of transuranic waste from the LANL Plutonium Facility for certification and transportation to WIPP includes the use of acceptable knowledge as specified in the WIPP Quality Assurance Program Plan. In accordance with a site-specific procedure, documentation of acceptable knowledge for retrievably stored and currently generated transuranic waste streams is in progress at LANL. A summary overview of the transuranic waste inventory is complete and documented in the Sampling Plan. This document also includes projected waste generation, facility missions, waste generation processes, flow diagrams, times, and material inputs. The second part of acceptable knowledge documentation consists of assembling more detailed acceptable knowledge information into auditable records and is expected to require several years to complete. These records for each waste stream must support final assignment of waste matrix parameters, EPA hazardous waste numbers, and radionuclide characterization. They must also include a determination whether waste streams are defense waste streams for compliance with the WIPP Land Withdrawal Act. The LANL Plutonium Facility`s mission is primarily plutonium processing in basic special nuclear material (SNM) research activities to support national defense and energy programs. It currently has about 100 processes ranging from SNM recovery from residues to development of plutonium 238 heat sources for space applications. Its challenge is to characterize and certify waste streams from such diverse and dynamic operations using acceptable knowledge. This paper reports the progress on the certification of the first of these waste streams to the WIPP WAC.

Montoya, A.J.; Gruetzmacher, K.; Foxx, C.; Rogers, P.S.Z.

1998-07-01T23:59:59.000Z

65

Acceptable knowledge document for INEEL stored transuranic waste -- Rocky Flats Plant waste. Revision 2  

SciTech Connect (OSTI)

This document and supporting documentation provide a consistent, defensible, and auditable record of acceptable knowledge for waste generated at the Rocky Flats Plant which is currently in the accessible storage inventory at the Idaho National Engineering and Environmental Laboratory. The inventory consists of transuranic (TRU) waste generated from 1972 through 1989. Regulations authorize waste generators and treatment, storage, and disposal facilities to use acceptable knowledge in appropriate circumstances to make hazardous waste determinations. Acceptable knowledge includes information relating to plant history, process operations, and waste management, in addition to waste-specific data generated prior to the effective date of the RCRA regulations. This document is organized to provide the reader a comprehensive presentation of the TRU waste inventory ranging from descriptions of the historical plant operations that generated and managed the waste to specific information about the composition of each waste group. Section 2 lists the requirements that dictate and direct TRU waste characterization and authorize the use of the acceptable knowledge approach. In addition to defining the TRU waste inventory, Section 3 summarizes the historical operations, waste management, characterization, and certification activities associated with the inventory. Sections 5.0 through 26.0 describe the waste groups in the inventory including waste generation, waste packaging, and waste characterization. This document includes an expanded discussion for each waste group of potential radionuclide contaminants, in addition to other physical properties and interferences that could potentially impact radioassay systems.

NONE

1998-01-23T23:59:59.000Z

66

A new DOE standard for transuranic waste nuclear safety analysis  

SciTech Connect (OSTI)

The DOE Office of Environmental Management (EM) observed through onsite assessments and a review of site-specific lessons learned that transuranic (TRU) waste operations could benefit from standardization of assumptions and approaches used to analyze hazards and select controls. EM collected and compared safety analysis information from DOE sites, including a comparison of the type of TRU waste accidents evaluated and controls selected, as well as specific Airborne Release Fractions (ARFs), Respirable Fractions (RFs), and Damage Ratios (DRs) assumed in accident analyses. This paper recounts the efforts by the DOE and its contractors to bring consistency to the safety analysis process supporting TRU waste operations through an integrated re-engineering effort. EM embarked on a process to re-engineer and standardize TRU safety analysis activities complex-wide. The effort involved DOE headquarters, field offices, and contractors. Five teams were formed to analyze and develop the necessary technical basis for a DOE Technical Standard. The teams looked at general issues including Safety Basis (SB), drum integrity and inspection criteria, hazard controls and analysis, safety analysis review and approval process, and implementation of hazard controls. (authors)

Triay, I.; Chung, D. [U.S. Department of Energy, Washington, D.C. (United States); Woody, J. [Atlas Consulting, Knoxville, TN (United States); Foppe, T. [Carlsbad Technical Assistance Contractor, Carlsbad, NM (United States); Mewhinney, C. [Sandia National Laboratories, Carlsbad, NM (United States); Jennings, S. [Los Alamos National Laboratories, Carlsbad, NM (United States)

2007-07-01T23:59:59.000Z

67

Waste Isolation Pilot Plant Transuranic Waste Baseline inventory report. Volume 2. Revision 1  

SciTech Connect (OSTI)

This document is the Baseline Inventory Report for the transuranic (alpha-bearing) wastes stored at the Waste Isolation Pilot Plant (WIPP) in New Mexico. Waste stream profiles including origin, applicable EPA codes, typical isotopic composition, typical waste densities, and typical rates of waste generation for each facility are presented for wastes stored at the WIPP.

NONE

1995-02-01T23:59:59.000Z

68

Transuranic (TRU) Waste Phase I Retrieval Plan  

SciTech Connect (OSTI)

Phase I retrieval of post-1970 TRU wastes from burial ground 218-W-4C can be done in a safe, efficient, and cost-effective manner. Initiating TRU retrieval by retrieving uncovered drums from Trenches 1, 20, and 29, will allow retrieval to begin under the current SWBG safety authorization basis. The retrieval of buried drums from Trenches 1, 4, 20, and 29, which will require excavation, will commence once the uncovered drum are retrieved. This phased approach allows safety analysis for drum venting and drum module excavation to be completed and approved before the excavation proceeds. In addition, the lessons learned and the operational experience gained from the retrieval of uncovered drums can be applied to the more complicated retrieval of the buried drums. Precedents that have been set at SRS and LANL to perform retrieval without a trench cover, in the open air, should be followed. Open-air retrieval will result in significant cost savings over the original plans for Phase I retrieval (Project W-113). Based on LANL and SRS experience, open-air retrieval will have no adverse impacts to the environment or to the health and safety of workers or the public. Assaying the waste in the SWBG using a mobile assay system, will result in additional cost savings. It is expected that up to 50% of the suspect-TRU wastes will assay as LLW, allowing those waste to remain disposed of in the SWBG. Further processing, with its associated costs, will only occur to the portion of the waste that is verified to be TRU. Retrieval should be done, to the extent possible, under the current SWBG safety authorization basis as a normal part of SWBG operations. The use of existing personnel and existing procedures should be optimized. By working retrieval campaigns, typically during the slow months, it is easier to coordinate the availability of necessary operations personnel, and it is easier to coordinate the availability of a mobile assay vendor.

MCDONALD, K.M.

1999-08-27T23:59:59.000Z

69

Hanford`s remote-handled transuranic and transuranic mixed waste volume assessment  

SciTech Connect (OSTI)

This study documents the results of an assessment of each Hanford program`s potential RH-TRU(M) waste forecast volumes. Of this 3,470 m{sup 3} of remote-handled transuranic and transuranic mixed (RH-TRU[M]) forecast waste, the Environmental Restoration program is the only program generating waste (360 m{sup 3}) after the closure of the WIPP in FY 2033. Previous forecast assessments have estimated Hanford`s RH-TRU(M) waste volumes to range from 4,000 m{sup 3} to 45,000 m{sup 3}. In FY 1995, the RH-TRU(M) waste forecast was approximately 22,200 m{sup 3} (BIR), which exceeds the WIPP remote-handled capacity. The FY-1996 Solid Waste Integrated Life-Cycle Forecast Volume Summary (WHC-EP-0900) published in February 1996 stated that the baseline RH-TRU(M) waste volume was 13,350 m{sup 3}. The primary reason for the three different estimates results from two programmatic baseline revisions: Tank Waste Remediation Systems (TWRS) and Environmental Restoration (EM-40). The difference in the TWRS programmatic baseline is due to a revised programmatic baseline for the disposition of the long-length equipment currently present in the tanks. The difference in the Environmental Restoration programmatic baseline is due to an assessment based on recent experience that many of the facilities at Hanford will not contain RH-TRU(M) waste during decontamination and decommissioning and that for many other facilities, the RH-TRU(M) waste volumes will not be as great as previously estimated.

Templeton, K.J.; DeForest, T.J.; Hladek, K.L.

1996-03-01T23:59:59.000Z

70

Certification document for newly generated contact-handled transuranic waste  

SciTech Connect (OSTI)

The US Department of Energy has requested that all national laboratories handling defense waste develop and augment a program whereby all newly generated contact-handled transuranic (TRU) waste be contained, stored, and then shipped to the Waste Isolation Pilot Plant (WIPP) in accordance with the requirements set forth in WIPP-DOE-114. The program described in this report delineates how Oak Ridge National Laboratory intends to comply with these requirements and lists the procedures used by each generator to ensure that their TRU wastes are certifiable for shipment to WIPP.

Box, W.D.; Setaro, J.

1984-01-01T23:59:59.000Z

71

Long-range master plan for defense transuranic waste management  

SciTech Connect (OSTI)

The Long Range Master Plan for the Defense Transuranic Waste Program (DTWP), or ''Master Plan,'' details current TRU waste management plans and serves as a framework for the DTWP. Not all final decisions concerning activities presented in the Master Plan have been made (e.g., land withdrawal legislation, the WIPP Compliance and Operational Plan and the TRUPACT Certificate of Compliance). It is the goal of the DTWP to end interim storage and achieve permanent disposal of TRU waste. To accomplish this goal, as much TRU waste as possible will be certified to meet the WIPP Acceptance Criteria (WAC). The certified waste will then be disposed of at WIPP. The small quantity of waste which is not practical to certify will be disposed of via alternative methods that require DOE Headquarters approval and shall comply with the National Environmental Policy Act requirements and EPA/State Regulations. The definition of TRU waste is ''without regard to source or form, waste that is contaminated with alpha-emitting transuranium radionuclides with half-lives greater than 20 years and concentrations greater than 100 nanocuries/gram (nCi/g) at the time of assay. Heads of Field Elements can determine that other alpha contaminated wastes, peculiar to a specific site, must be managed as transuranic waste.''

Not Available

1988-12-01T23:59:59.000Z

72

Nondestructive characterization of low-level transuranic waste  

SciTech Connect (OSTI)

The use of nondestructive evaluation (NDE) methods is proposed for characterization of transuranic (TRU) waste stored at the Radioactive Waste Management Complex. These NDE methods include real-time x-ray radiography, real-time neutron radiography, x-ray and neutron computed tomography, thermal imaging, container weighing, visual examination, and acoustic measurements. An integrated NDE system is proposed for characterization and certification of TRU waste destined for eventual shipment to the Waste Isolation Pilot Plant in New Mexico. Methods for automating both the classification waste and control of a complete nondestructive evaluation/nondestructive assay system are presented. Feasibility testing of the different NDE methods, including real-time x-ray radiography, and development of automated waste classification techniques are covered as part of a five year effort designed to yield a production waste characterization system.

Barna, B.A.; Reinhardt, W.W.

1981-10-01T23:59:59.000Z

73

Transuranic (TRU) Waste Repackaging at the Nevada Test Site  

SciTech Connect (OSTI)

This paper describes the activities required to modify a facility and the process of characterizing, repackaging, and preparing for shipment the Nevada Test Site’s (NTS) legacy transuranic (TRU) waste in 58 oversize boxes (OSB). The waste, generated at other U.S. Department of Energy (DOE) sites and shipped to the NTS between 1974 and 1990, requires size-reduction for off-site shipment and disposal. The waste processing approach was tailored to reduce the volume of TRU waste by employing decontamination and non-destructive assay. As a result, the low-level waste (LLW) generated by this process was packaged, with minimal size reduction, in large sea-land containers for disposal at the NTS Area 5 Radioactive Waste Management Complex (RWMC). The remaining TRU waste was repackaged and sent to the Idaho National Laboratory Consolidation Site for additional characterization in preparation for disposal at the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico. The DOE National Nuclear Security Administration Nevada Site Office and the NTS Management and Operating (M&O) contractor, NSTec, successfully partnered to modify and upgrade an existing facility, the Visual Examination and Repackaging Building (VERB). The VERB modifications, including a new ventilation system and modified containment structure, required an approved Preliminary Documented Safety Analysis prior to project procurement and construction. Upgrade of the VERB from a radiological facility to a Hazard Category 3 Nuclear Facility required new rigor in the design and construction areas and was executed on an aggressive schedule. The facility Documented Safety Analysis required that OSBs be vented prior to introduction into the VERB. Box venting was safely completed after developing and implementing two types of custom venting systems for the heavy gauge box construction. A remotely operated punching process was used on boxes with wall thickness of up to 3.05 mm (0.120 in) to insert aluminum bronze filters and sample ports to prevent sparking during penetration. A remotely operated cold-drilling process with self-drilling, self-tapping titanium coated spark-resistant filters was used for boxes with wall thickness of up to 6.35 mm (0.25 in). The box headspace was sampled for the presence of flammable gases. To further accelerate the project schedule, an innovative treatment process was used. Several of the OSBs were re-assayed and determined to be mixed low-level waste (MLLW) which allowed treatment, followed by disposal in the Mixed Waste Disposal Unit at the NTS Area 5 Radioactive Waste Management Complex (RWMC). The MLLW boxes were certified using real-time radiography and overpacked into custom-built polyethylene-lined macroencapsulation containers. The polyethylene-lined lid was welded to the poly-lined box using automatically controlled resistance heating through embedded wiring in the lid. The work was performed under the existing Documented Safety Analysis since plastic welding is accomplished at low temperature and does not introduce the risks of other macroencapsulation processes, such as welding stainless steel containers. The macroencapsulation process for MLLW not only accelerated the schedule by reducing the number of boxes requiring size reduction, but it also resulted in significantly improved safety with as low as reasonable achievable levels of exposure to workers plus reduced cost by eliminating the need to perform repackaging in the VERB.

E.F. Di Sanza; G. Pyles; J. Ciucci; P. Arnold

2009-03-01T23:59:59.000Z

74

Transuranic waste characterization sampling and analysis methods manual. Revision 1  

SciTech Connect (OSTI)

This Methods Manual provides a unified source of information on the sampling and analytical techniques that enable Department of Energy (DOE) facilities to comply with the requirements established in the current revision of the Transuranic Waste Characterization Quality Assurance Program Plan (QAPP) for the Waste Isolation Pilot Plant (WIPP) Transuranic (TRU) Waste Characterization Program (the Program) and the WIPP Waste Analysis Plan. This Methods Manual includes all of the testing, sampling, and analytical methodologies accepted by DOE for use in implementing the Program requirements specified in the QAPP and the WIPP Waste Analysis Plan. The procedures in this Methods Manual are comprehensive and detailed and are designed to provide the necessary guidance for the preparation of site-specific procedures. With some analytical methods, such as Gas Chromatography/Mass Spectrometry, the Methods Manual procedures may be used directly. With other methods, such as nondestructive characterization, the Methods Manual provides guidance rather than a step-by-step procedure. Sites must meet all of the specified quality control requirements of the applicable procedure. Each DOE site must document the details of the procedures it will use and demonstrate the efficacy of such procedures to the Manager, National TRU Program Waste Characterization, during Waste Characterization and Certification audits.

Suermann, J.F.

1996-04-01T23:59:59.000Z

75

Identification of potential transuranic waste tanks at the Hanford Site  

SciTech Connect (OSTI)

The purpose of this document is to identify potential transuranic (TRU) material among the Hanford Site tank wastes for possible disposal at the Waste Isolation Pilot Plant (WIPP) as an alternative to disposal in the high-level waste (HLW) repository. Identification of such material is the initial task in a trade study suggested in WHC-EP-0786, Tank Waste Remediation System Decisions and Risk Assessment (Johnson 1994). The scope of this document is limited to the identification of those tanks that might be segregated from the HLW for disposal as TRU, and the bases for that selection. It is assumed that the tank waste will be washed to remove soluble inert material for disposal as low-level waste (LLW), and the washed residual solids will be vitrified for disposal. The actual recommendation of a disposal strategy for these materials will require a detailed cost/benefit analysis and is beyond the scope of this document.

Colburn, R.P.

1995-05-05T23:59:59.000Z

76

Transuranic (Tru) waste volume reduction operations at a plutonium facility  

SciTech Connect (OSTI)

Programmatic operations at the Los Alamos National Laboratory Plutonium Facility (TA 55) involve working with various amounts of plutonium and other highly toxic, alpha-emitting materials. The spread of radiological contamination on surfaces, airborne contamination, and excursions of contaminants into the operator's breathing zone are prevented through use of a variety of gloveboxes (the glovebox, coupled with an adequate negative pressure gradient, provides primary confinement). Size-reduction operations on glovebox equipment are a common activity when a process has been discontinued and the room is being modified to support a new customer. The Actin ide Processing Group at TA-55 uses one-meter-long glass columns to process plutonium. Disposal of used columns is a challenge, since they must be size-reduced to get them out of the glovebox. The task is a high-risk operation because the glass shards that are generated can puncture the bag-out bags, leather protectors, glovebox gloves, and the worker's skin when completing the task. One of the Lessons Learned from these operations is that Laboratory management should critically evaluate each hazard and provide more effective measures to prevent personnel injury. A bag made of puncture-resistant material was one of these enhanced controls. We have investigated the effectiveness of these bags and have found that they safely and effectively permit glass objects to be reduced to small pieces with a plastic or rubber mallet; the waste can then be easily poured into a container for removal from the glove box as non-compactable transuranic (TRU) waste. This size-reduction operation reduces solid TRU waste generation by almost 2% times. Replacing one-time-use bag-out bags with multiple-use glass crushing bags also contributes to reducing generated waste. In addition, significant costs from contamination, cleanup, and preparation of incident documentation are avoided. This effort contributes to the Los Alamos National Laboratory Continuous Improvement Program by improving the efficiency, cost-effectiveness, and formality of glovebox operations. In this report, the technical issues, associated with implementing this process improvement are addressed, the results discussed, effectiveness of Lessons Learned evaluated, and waste savings presented.

Cournoyer, Michael E [Los Alamos National Laboratory; Nixon, Archie E [Los Alamos National Laboratory; Dodge, Robert L [Los Alamos National Laboratory; Fife, Keith W [Los Alamos National Laboratory; Sandoval, Arnold M [Los Alamos National Laboratory; Garcia, Vincent E [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

77

W-026, transuranic waste restricted waste management (TRU RWM) glovebox operational test report  

SciTech Connect (OSTI)

The TRU Waste/Restricted Waste Management (LLW/PWNP) Glovebox 401 is designed to accept and process waste from the Transuranic Process Glovebox 302. Waste is transferred to the glovebox via the Drath and Schraeder Bagless Transfer Port (DO-07401) on a transfer stand. The stand is removed with a hoist and the operator inspects the waste (with the aid of the Sampling and Treatment Director) to determine a course of action for each item. The waste is separated into compliant and non compliant. One Trip Port DO-07402A is designated as ``Compliant``and One Trip Port DO-07402B is designated as ``Non Compliant``. As the processing (inspection, bar coding, sampling and treatment) of the transferred items takes place, residue is placed in the appropriate One Trip port. The status of the waste items is tracked by the Data Management System (DMS) via the Plant Control System (PCS) barcode interface. As an item is moved for sampling or storage or it`s state altered by treatment, the Operator will track an items location using a portable barcode reader and entry any required data on the DMS console. The Operational Test Procedure (OTP) will perform evolutions (described here) using the Plant Operating Procedures (POP) in order to verify that they are sufficient and accurate for controlled glovebox operation.

Leist, K.J.

1998-02-18T23:59:59.000Z

78

Hanford Site Hazardous waste determination report for transuranic debris waste streams NPFPDL1A, NPFPDL1B, NPFPDL1C and NPFPDL1D  

SciTech Connect (OSTI)

This Hazardous Waste Determination Report is intended to satisfy the terms of a Memorandum of Agreement (Agreement signed on June 16, 1999) between the U.S. Department of Energy and the New Mexico Environment Department. The Agreement pertains to the exchange of information before a final decision is made on the Waste Isolation Pilot Plant application for a permit under the ''New Mexico Hazardous Waste Act''. The Agreement will terminate upon the effective date of a final ''New Mexico Hazardous Waste Act'' permit for the Waste Isolation Pilot Plant. In keeping with the principles and terms of the Agreement, this report describes the waste stream data and information compilation process, and the physical and chemical analyses that the U.S. Department of Energy has performed on selected containers of transuranic debris waste to confirm that the waste is nonhazardous (non-mixed). This also summarizes the testing and analytical results that support the conclusion that the selected transuranic debris waste is not hazardous and thus, not subject to regulation under the ''Resource Conservation and Recovery Act'' or the ''New Mexico Hazardous Waste Act''. This report will be submitted to the New Mexico Environment Department no later than 45 days before the first shipment of waste from the Hanford Site to the Waste Isolation Pilot Plant, unless the parties mutually agree in writing to a shorter time. The 52 containers of transuranic debris waste addressed in this report were generated, packaged, and placed into storage between 1995 and 1997. Based on reviews of administrative documents, operating procedures, waste records, generator certifications, and personnel interviews, this transuranic debris waste was determined to be nonhazardous. This determination is supported by the data derived from nondestructive examination, confirmatory visual examination, and the results of container headspace gas sampling and analysis. Therefore, it is concluded that this transuranic debris waste, which consists of 52 containers from waste streams NPFPDLIA, NPFPDLIB, NPFPDLIC, and NPFPDLID, is not hazardous waste, and no hazardous waste numbers specified in Title 40 Code of Federal Regulations, Part 261, have been assigned. Accordingly, the 52 containers of transuranic debris waste addressed in this report meet the requirements for transuranic waste as defined by the Department of Energy Waste Acceptance Criteria for the Waste Isolation Pilot Plant. The 52 containers are acceptable for disposal at the Waste Isolation Pilot Plant as nonhazardous transuranic waste.

WINTERHALDER, J.A.

1999-09-29T23:59:59.000Z

79

Transuranic (TRU) Waste Phase I Retrieval Plan  

SciTech Connect (OSTI)

From 1970 to 1987, TRU and suspect TRU wastes at Hanford were placed in the SWBG. At the time of placement in the SWBG these wastes were not regulated under existing Resource Conservation and Recovery Act (RCRA) regulations, since they were generated and disposed of prior to the effective date of RCRA at the Hanford Site (1987). From the standpoint of DOE Order 5820.2A1, the TRU wastes are considered retrievably stored, and current plans are to retrieve these wastes for shipment to WIPP for disposal. This plan provides a strategy for the Phase I retrieval that meets the intent of TPA milestone M-91 and Project W-113, and incorporates the lessons learned during TRU retrieval campaigns at Hanford, LANL, and SRS. As in the original Project W-113 plans, the current plan calls for examination of approximately 10,000 suspect-TRU drums located in the 218-W-4C burial ground followed by the retrieval of those drums verified to contain TRU waste. Unlike the older plan, however, this plan proposes an open-air retrieval scenario similar to those used for TRU drum retrieval at LANL and SRS. Phase I retrieval consists of the activities associated with the assessment of approximately 10,000 55-gallon drums of suspect TRU-waste in burial ground 218-W-4C and the retrieval of those drums verified to contain TRU waste. Four of the trenches in 218-W-4C (Trenches 1, 4, 20, and 29) are prime candidates for Phase I retrieval because they contain large numbers of suspect TRU drums, stacked from 2 to 5 drums high, on an asphalt pad. In fact, three of the trenches (Trenches 1 , 20, and 29) contain waste that has not been covered with soil, and about 1500 drums can be retrieved without excavation. The other three trenches in 218-W-4C (Trenches 7, 19, and 24) are not candidates for Phase I retrieval because they contain significant numbers of boxes. Drums will be retrieved from the four candidate trenches, checked for structural integrity, overpacked, if necessary, and assayed at the burial ground. A mobile assay system will be used to determine if the drum is LLW (Le., contains <100 nCi/g). LLW will remain disposed of in the 218-W-4C Burial Ground. TRU waste will be retrieved and staged in the burial ground until it can be shipped to the CWC. The TRU drums will be stored at the CWC until they can be moved to WRAP. The WRAP facility will prepare the waste for shipment to WIPP for final disposal. For planning purposes, approximately 50% of the 10,000 drums have been estimated to contain LLW.

MCDONALD, K.M.

2000-09-28T23:59:59.000Z

80

Recovery Act Funding Leads to Record Year for Transuranic Waste Shipments  

Broader source: Energy.gov [DOE]

With the help of American Recovery and Reinvestment Act funding, the Waste Isolation Pilot Plant (WIPP) received the most transuranic waste shipments in a single year since waste operations began...

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Transuranic Waste Tabletop | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomen Owned SmallOf The 2012 Greenbuy3 Archive Transportation Fact ofATEnergyWaste

82

Safer Transportation and Disposal of Remote Handled Transuranic Waste - 12033  

SciTech Connect (OSTI)

Since disposal of remote handled (RH) transuranic (TRU) waste at the Waste Isolation Pilot Plant (WIPP) began in 2007, the Department of Energy (DOE) has had difficulty meeting the plans and schedule for disposing this waste. PECOS Management Services, Inc. (PECOS) assessed the feasibility of proposed alternate RH-TRU mixed waste containerisation concepts that would enhance the transportation rate of RH-TRU waste to WIPP and increase the utilization of available WIPP space capacity for RH-TRU waste disposal by either replacing or augmenting current and proposed disposal methods. In addition engineering and operational analyses were conducted that addressed concerns regarding criticality, heat release, and worker exposure to radiation. The results of the analyses showed that the concept, development, and use of a concrete pipe based design for an RH-TRU waste shipping and disposal container could be potentially advantageous for disposing a substantial quantity of RHTRU waste at WIPP in the same manner as contact-handled RH waste. Additionally, this new disposal method would eliminate the hazard associated with repackaging this waste in other containers without the requirement for NRC approval for a new shipping container. (authors)

Rojas, Vicente; Timm, Christopher M.; Fox, Jerry V. [PECOS Management Services, Inc., Albuquerque, NM (United States)

2012-07-01T23:59:59.000Z

83

Project plans for transuranic waste at small quantity sites in the Department of Energy comples-10522  

SciTech Connect (OSTI)

Los Alamos National Laboratory, Carlsbad Office (LANL-CO), has been tasked to write Project Plans for all of the Small Quantity Sites (SQS) with defense related Transuranic (TRU) waste in the Department of Energy (DOE) complex. Transuranic Work-Off Plans were precursors to the Project Plans. LANL-CO prepared a Work-Off Plan for each small quantity site. The Work-Off Plan that identified issues, drivers, schedules, and inventory. Eight sites have been chosen to deinventory their legacy TRU waste; Bettis Atomic Power Laboratory, General Electric-Vallecitos Nuclear Center, Lawrence Berkeley National Laboratory, Lawrence Livermore National Laboratory-Area 300, Nevada Test Site, Nuclear Radiation Development, Sandia National Laboratory, and the Separations Process Research Unit. Each plan was written for contact and/or remote handled waste if present at the site. These project plans will assist the small quantity sites to ship legacy TRU waste offsite and de-inventory the site of legacy TRU waste. The DOE is working very diligently to reduce the nuclear foot print in the United States. Each of the eight SQSs will be de-inventoried of legacy TRU waste during a campaign that ends September 2011. The small quantity sites have a fraction of the waste that large quantity sites possess. During this campaign, the small quantity sites will package all of the legacy TRU waste and ship to Idaho or directly to the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. The sites will then be removed from the Transuranic Waste Inventory if they are de-inventoried of all waste. Each Project Plan includes the respective site inventory report, schedules, resources, drivers and any issues. These project plans have been written by the difficult waste team and will be approved by each site. Team members have been assigned to each site to write site specific project plans. Once the project plans have been written, the difficult team members will visit the sites to ensure nothing has been overlooked and to verify the inventory. After each site has approved their project plan, the site will begin writing procedures and packaging/repackaging their waste. In some cases the sites have already begun the process. The waste will be shipped after all of the waste has been characterized and approved.

Mctaggart, Jerri Lynne [Los Alamos National Laboratory; Lott, Sheila [Los Alamos National Laboratory; Gadbury, Casey [DOE

2009-01-01T23:59:59.000Z

84

Los Alamos National Laboratory transuranic waste quality assurance project plan. Revision 1  

SciTech Connect (OSTI)

This Transuranic (TRU) Waste Quality Assurance Project Plan (QAPjP) serves as the quality management plan for the characterization of transuranic waste in preparation for certification and transportation. The Transuranic Waste Characterization/Certification Program (TWCP) consists of personnel who sample and analyze waste, validate and report data; and provide project management, quality assurance, audit and assessment, and records management support, all in accordance with established requirements for disposal of TRU waste at the Waste Isolation Pilot Plant (WIPP) facility. This QAPjP addresses how the TWCP meets the quality requirements of the Carlsbad Area Office (CAO) Quality Assurance Program Description (QAPD) and the technical requirements of the Transuranic Waste Characterization Quality Assurance Program Plan (QAPP). The TWCP characterizes and certifies retrievably stored and newly generated TRU waste using the waste selection, testing, sampling, and analytical techniques and data quality objectives (DQOs) described in the QAPP, the Los Alamos National Laboratory Transuranic Waste Certification Plan (Certification Plan), and the CST Waste Management Facilities Waste Acceptance Criteria and Certification [Los Alamos National Laboratory (LANL) Waste Acceptance Criteria (WAC)]. At the present, the TWCP does not address remote-handled (RH) waste.

NONE

1997-04-14T23:59:59.000Z

85

INTERNATIONAL UNION OF OPERATING ENGINEERS NATIONAL HAZMAT PROGRAM - HANDSS-55 TRANSURANIC WASTE REPACKAGING MODULE  

SciTech Connect (OSTI)

The Transuranic waste generated at the Savannah River Site from nuclear weapons research, development, and production is currently estimated to be over 10,000 cubic meters. Over half of this amount is stored in 55-gallon drums. The waste in drums is primarily job control waste and equipment generated as the result of routine maintenance performed on the plutonium processing operations. Over the years that the drums have been accumulating, the regulatory definitions of materials approved for disposal have changed. Consequently, many of the drums now contain items that are not approved for disposal at DOE Waste Isolation Pilot Plant (WIPP). The HANDSS-55 technology is being developed to allow remote sorting of the items in these drums and then repackaging of the compliant items for disposal at WIPP.

Unknown

2001-08-31T23:59:59.000Z

86

EM Makes Significant Progress on Dispositioning Transuranic Waste at Idaho Site  

Broader source: Energy.gov [DOE]

IDAHO FALLS, Idaho – EM and contractor CH2M-WG, IDAHO, LLC (CWI) made significant progress in 2013 dispositioning transuranic (TRU) waste and helping ship it out of Idaho.

87

CHALLENGES WITH RETRIEVING TRANSURANIC WASTE FROM THE HANFORD BURIAL GROUNDS  

SciTech Connect (OSTI)

The U.S. DOE's Hanford Reservation produced plutonium and other nuclear materials for the nation's defense starting in World War II. The defense mission generated wastes that were either retrievably stored (i.e. retrievably stored waste) and/or disposed of in burial grounds. Challenges have emerged from retrieving suspect TRU waste including adequacy of records, radiological concerns, container integrity, industrial hygiene and safety issues, the lack of processing/treatment facilities, and the integration of regulatory requirements. All retrievably stored waste is managed as mixed waste and assumed to be TRU waste, unless documented otherwise. Mixed waste is defined as radioactive waste that contains hazardous constituents. The Atomic Energy Act governs waste with radionuclides, and the Resource Conservation and Recovery Act (RCRA) governs waste with hazardous constituents. Waste may also be governed by the Toxic Substances Control Act (TSCA), and a portion may be managed under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). In 1970, TRU waste was required to be placed in 20-year retrievable storage and segregated from other Waste. Prior to that date, segregation did not occur. Because of the changing definition of TRU over the years, and the limitations of early assay equipment, all retrievably stored waste in the burial grounds is managed as suspect TRU. Experience has shown that some of this waste will be characterized as low-level (non-TRU) waste after assay. The majority of the retrieved waste is not amenable to sampling due to waste type and/or radiological issues. Key to waste retrieval and disposition are characterization, historical investigation and research, knowledge of past handling and packaging, as well as a broad understanding and application of the regulations.

SWAN, R.J.; LAKES, M.E.

2007-08-06T23:59:59.000Z

88

Radiological, physical, and chemical characterization of transuranic wastes stored at the Idaho National Engineering Laboratory  

SciTech Connect (OSTI)

This document provides radiological, physical and chemical characterization data for transuranic radioactive wastes and transuranic radioactive and hazardous (i.e., mixed) wastes stored at the Idaho National Engineering Laboratory and considered for treatment under the Private Sector Participation Initiative Program (PSPI). Waste characterization data are provided in the form of INEL Waste Profile Sheets. These documents provide, for each content code, information on waste identification, waste description, waste storage configuration, physical/chemical waste composition, radionuclide and associated alpha activity waste characterization data, and hazardous constituents present in the waste. Information is provided for 139 waste streams which represent an estimated total volume of 39,380{sup 3} corresponding to a total mass of approximately 19,000,000 kg. In addition, considerable information concerning alpha, beta, gamma, and neutron source term data specific to Rocky Flats Plant generated waste forms stored at the INEL are provided to assist in facility design specification.

Apel, M.L.; Becker, G.K.; Ragan, Z.K.; Frasure, J.; Raivo, B.D.; Gale, L.G.; Pace, D.P.

1994-03-01T23:59:59.000Z

89

Waste immobilization process development at the Savannah River Plant  

SciTech Connect (OSTI)

Processes to immobilize various wasteforms, including waste salt solution, transuranic waste, and low-level incinerator ash, are being developed. Wasteform characteristics, process and equipment details, and results from field/pilot tests and mathematical modeling studies are discussed.

Charlesworth, D L

1986-01-01T23:59:59.000Z

90

Management activities for retrieved and newly generated transuranic waste, Savannah River Plant  

SciTech Connect (OSTI)

The purpose of this Environmental Assessment (EA) is to assess the potential environmental impacts of the retrieval and processing of retrieved and newly generated transuranic (TRU) radioactive waste at the Savannah River Plant (SRP), including the transportation of the processes TRU waste to the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico. A new TRU Waste Facility (TWF) will be constructed at SRP to retrieve and process the SRP TRU waste in interim storage to meet WIPP criteria. This EA has been prepared in compliance with the National Environmental Policy Act (NEPA) of 1969, as amended, and the requirements of the Council of Environmental Quality Regulations for implementing NEPA (40 CFR Parts 1500--1508). The National Environmental Policy Act (NEPA) requires the assessment of environmental consequences of all major federal actions that may affect the quality of the human environment. This document describes the environmental impact of constructing and operating the TWF facility for processing and shipment of the TRU waste to WIPP and considers alternatives to the proposed action. 40 refs., 12 figs., 12 tabs.

Not Available

1988-08-01T23:59:59.000Z

91

PROJECT STRATEGY FOR THE REMEDIATION AND DISPOSITION OF LEGACY TRANSURANIC WASTE AT THE SAVANNAH RIVER SITE, South Carolina, USA  

SciTech Connect (OSTI)

This paper discusses the Savannah River Site Accelerated Transuranic (TRU) Waste Project that was initiated in April of 2009 to accelerate the disposition of remaining legacy transuranic waste at the site. An overview of the project execution strategy that was implemented is discussed along with the lessons learned, challenges and improvements to date associated with waste characterization, facility modifications, startup planning, and remediation activities. The legacy waste was generated from approximately 1970 through 1990 and originated both on site as well as at multiple US Department of Energy sites. Approximately two thirds of the waste was previously dispositioned from 2006 to 2008, with the remaining one third being the more hazardous waste due to its activity (curie content) and the plutonium isotope Pu-238 quantities in the waste. The project strategy is a phased approach beginning with the lower activity waste in existing facilities while upgrades are made to support remediation of the higher activity waste. Five waste remediation process lines will be used to support the full remediation efforts which involve receipt of the legacy waste container, removal of prohibited items, venting of containers, and resizing of contents to fit into current approved waste shipping containers. Modifications have been minimized to the extent possible to meet the accelerated goals and involve limited upgrades to address life safety requirements, radiological containment needs, and handling equipment for the larger waste containers. Upgrades are also in progress for implementation of the TRUPACT III for the shipment of Standard Large Boxes to the Waste Isolation Pilot Plant, the US TRU waste repository. The use of this larger shipping container is necessary for approximately 20% of the waste by volume due to limited size reduction capability. To date, approximately 25% of the waste has been dispositioned, and several improvements have been made to the overall processing plan as well as facility processing rates. These lessons learned, challenges, and improvements will be discussed to aid other sites in their efforts to conduct similar activities.

Rodriguez, M.

2010-12-17T23:59:59.000Z

92

DOE assay methods used for characterization of contact-handled transuranic waste  

SciTech Connect (OSTI)

US Department of Energy methods used for characterization of contact-handled transuranic (CH-TRU) waste prior to shipment to the Waste Isolation Pilot Plant (WIPP) are described and listed by contractor site. The methods described are part of the certification process. All CH-TRU waste must be assayed for determination of fissile material content and decay heat values prior to shipment and prior to storage on-site. Both nondestructive assay (NDA) and destructive assay methods are discussed, and new NDA developments such as passive-action neutron (PAN) crate counter improvements and neutron imaging are detailed. Specifically addressed are assay method physics; applicability to CH-TRU wastes; calibration standards and implementation; operator training requirements and practices; assay procedures; assay precision, bias, and limit of detection; and assay limitation. While PAN is a new technique and does not yet have established American Society for Testing and Materials. American National Standards Institute, or Nuclear Regulatory Commission guidelines or methods describing proper calibration procedures, equipment setup, etc., comparisons of PAN data with the more established assay methods (e.g., segmented gamma scanning) have demonstrated its reliability and accuracy. Assay methods employed by DOE have been shown to reliable and accurate in determining fissile, radionuclide, alpha-curie content, and decay heat values of CH-TRU wastes. These parameters are therefore used to characterize packaged waste for use in certification programs such as that used in shipment of CH-TRU waste to the WIPP. 36 refs., 10 figs., 7 tabs.

Schultz, F.J. (Oak Ridge National Lab., TN (United States)); Caldwell, J.T. (Pajarito Scientific Corp., Los Alamos, NM (United States))

1991-08-01T23:59:59.000Z

93

EA-1962: Analysis for Below Grade Suspect Transuranic (TRU) Waste at Technical Area (TA)-54  

Broader source: Energy.gov [DOE]

DOE is preparing an EA to evaluate the legacy suspect transuranic (TRU) waste at Area G for the purposes of reclassification of waste type and determination of a final disposal path. Per DOE Order 435.1, Change 1, Radioactive Waste Management, and its associated guide, legacy waste at Los Alamos National Laboratory that contained TRU waste was stored and managed as TRU waste. The waste was given an interim classification for the purposes of applying the most restrictive standard until the waste could be adequately characterized and a final determination on the disposition classification was made.

94

Establishment of a facility for intrusive characterization of transuranic waste at the Nevada Test Site  

SciTech Connect (OSTI)

This paper describes design and construction, project management, and testing results associated with the Waste Examination Facility (WEF) recently constructed at the Nevada Test Site (NTS). The WEF and associated systems were designed, procured, and constructed on an extremely tight budget and within a fast track schedule. Part 1 of this paper focuses on design and construction activities, Part 2 discusses project management of WEF design and construction activities, and Part 3 describes the results of the transuranic (TRU) waste examination pilot project conducted at the WEF. In Part 1, the waste examination process is described within the context of Waste Isolation Pilot Plant (WIPP) characterization requirements. Design criteria are described from operational and radiological protection considerations. The WEF engineered systems are described. These systems include isolation barriers using a glove box and secondary containment structure, high efficiency particulate air (HEPA) filtration and ventilation systems, differential pressure monitoring systems, and fire protection systems. In Part 2, the project management techniques used for ensuring that stringent cost/schedule requirements were met are described. The critical attributes of these management systems are described with an emphasis on team work. In Part 3, the results of a pilot project directed at performing intrusive characterization (i.e., examination) of TRU waste at the WEF are described. Project activities included cold and hot operations. Cold operations included operator training, facility systems walk down, and operational procedures validation. Hot operations included working with plutonium contaminated TRU waste and consisted of waste container breaching, waste examination, waste segregation, data collection, and waste repackaging.

Foster, B.D.; Musick, R.G.; Pedalino, J.P.; Cowley, J.L. [Bechtel Nevada Corp., Las Vegas, NV (United States); Karney, C.C. [Dept. of Energy, Las Vegas, NV (United States); Kremer, J.L.

1998-01-01T23:59:59.000Z

95

The role of acceptable knowledge in transuranic waste disposal operations - 11117  

SciTech Connect (OSTI)

The Acceptable Knowledge (AK) process plays a key role in the delineation of waste streams destined for the Waste Isolation Pilot Plant (WIPP). General Electric's Vallecitos Nuclear Center (GEVNC) provides for an ideal case study of the application of AK in a multiple steward environment. In this review we will elucidate the pivotal role Acceptable Knowledge played in segregating Department of Energy (DOE) responsibilities from a commercial facility. The Acceptable Knowledge process is a necessary component of waste characterization that determines whether or not a waste stream may be considered for disposal at the WIPP site. This process may be thought of as an effort to gain a thorough understanding of the waste origin, chemical content, and physical form gleaned by the collection of documentation that concerns generator/storage site history, mission, and operations; in addition to waste stream specific information which includes the waste generation process, the waste matrix, the quantity of waste concerned, and the radiological and chemical make up of the waste. The collection and dissemination of relevant documentation is the fundamental requirement for the AK process to work. Acceptable Knowledge is the predominant process of characterization and, therefore, a crucial part of WIPP's transuranic waste characterization program. This characterization process, when conducted to the standards set forth in WIPP's operating permit, requires confirmation/verification by physical techniques such as Non-Destructive Examination (NDE), Visual Examination (VE), and Non-Destructive Assay (NDA). These physical characterization techniques may vary in their appropriateness for a given waste stream; however, nothing will allow the substitution or exclusion of AK. Beyond the normal scope of operations, AK may be considered, when appropriate, a surrogate for the physical characterization techniques in a procedure that appeals to concepts such As Low As Reasonably Achievable (ALARA) and budgetary savings. This substitution is referred to as an Acceptable Knowledge Sufficiency Determination. With a Sufficiency Determination Request, AK may supplant the need for one or all of the physical analysis methods. This powerful procedure may be used on a scale as small as a single container to that of a vast waste stream. Only under the most stringent requirements will an AK Sufficiency Determination be approved by the regulators and, to date, only six such Sufficiency Determinations have been approved. Although Acceptable Knowledge is legislated into the operational procedures of the WIPP facility there is more to it than compliance. AK is not merely one of a long list of requirements in the characterization and verification of transuranic (TRU) waste destined for the WIPP. Acceptable Knowledge goes beyond the regulatory threshold by offering a way to reduce risk, cost, time, and uncertainty on its own laurels. Therefore, AK alone can be argued superior to any other waste characterization technique.

Chancellor, Christopher John [Los Alamos National Laboratory; Nelson, Roger [DOE-CARLSBAD

2010-11-08T23:59:59.000Z

96

Total Measurement Uncertainty (TMU) for Nondestructive Assay of Transuranic (TRU) Waste at the WRAP Facility  

SciTech Connect (OSTI)

The Waste Receiving and Processing (WRAP) facility, located on the Hanford Site in southeast Washington, is a key link in the certification of Hanford's transuranic (TRU) waste for shipment to the Waste Isolation Pilot Plant (WIPP). Waste characterization is one of the vital functions performed at WRAP, and nondestructive assay (NDA) measurements of TRU waste containers is one of two required methods used for waste characterization (Reference 1). Various programs exist to ensure the validity of waste characterization data; all of these cite the need for clearly defined knowledge of uncertainty, associated with any measurements taken. All measurements have an inherent uncertainty associated with them. The combined effect of all uncertainties associated with a measurement is referred to as the Total Measurement Uncertainty (TMU). The NDA measurement uncertainties can be numerous and complex. In addition to system-induced measurement uncertainty, other factors contribute to the TMU, each associated with a particular measurement. The NDA measurements at WRAP are based on processes (radioactive decay and induced fission) which are statistical in nature. As a result, the proper statistical summation of the various uncertainty components is essential. This report examines the contributing factors to NDA measurement uncertainty at WRAP. The significance of each factor on the TMU is analyzed, and a final method is given for determining the TMU for NDA measurements at WRAP. As more data becomes available, and WRAP gains in operational experience, this report will be reviewed semi-annually and updated as necessary. This report also includes the data flow paths for the analytical process in the radiometric determinations.

WILLS, C.E.

2000-02-24T23:59:59.000Z

97

Update on intrusive characterization of mixed contact-handled transuranic waste at Argonne-West  

SciTech Connect (OSTI)

Argonne National Laboratory and Lockheed Martin Idaho Technologies Company have jointly participated in the Department of Energy`s (DOE) Waste Isolation Pilot Plant (WIPP) Transuranic Waste Characterization Program since 1990. Intrusive examinations have been conducted in the Waste Characterization Area, located at Argonne-West in Idaho Falls, Idaho, on over 200 drums of mixed contact-handled transuranic waste. This is double the number of drums characterized since the last update at the 1995 Waste Management Conference. These examinations have provided waste characterization information that supports performance assessment of WIPP and that supports Lockheed`s compliance with the Resource Conservation and Recovery Act. Operating philosophies and corresponding regulatory permits have been broadened to provide greater flexibility and capability for waste characterization, such as the provision for minor treatments like absorption, neutralization, stabilization, and amalgamation. This paper provides an update on Argonne`s intrusive characterization permits, procedures, results, and lessons learned. Other DOE sites that must deal with mixed contact-handled transuranic waste have initiated detailed planning for characterization of their own waste. The information presented herein could aid these other storage and generator sites in further development of their characterization efforts.

Dwight, C.C.; Jensen, B.A.; Bryngelson, C.D.; Duncan, D.S.

1997-02-03T23:59:59.000Z

98

Robust Solution to Difficult Hydrogen Issues When Shipping Transuranic Waste to the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP) has been open, receiving, and disposing of transuranic (TRU) waste since March 26, 1999. The majority of the waste has a path forward for shipment to and disposal at the WIPP, but there are about two percent (2%) or approximately 3,020 cubic meters (m{sup 3}) of the volume of TRU waste (high wattage TRU waste) that is not shippable because of gas generation limits set by the U.S. Nuclear Regulatory Commission (NRC). This waste includes plutonium-238 waste, solidified organic waste, and other high plutonium-239 wastes. Flammable gases are potentially generated during transport of TRU waste by the radiolysis of hydrogenous materials and therefore, the concentration at the end of the shipping period must be predicted. Two options are currently available to TRU waste sites for solving this problem: (1) gas generation testing on each drum, and (2) waste form modification by repackaging and/or treatment. Repackaging some of the high wattage waste may require up to 20:1 drum increase to meet the gas generation limits of less than five percent (5%) hydrogen in the inner most layer of confinement (the layer closest to the waste). (This is the limit set by the NRC.) These options increase waste handling and transportation risks and there are high costs and potential worker exposure associated with repackaging this high-wattage TRU waste. The U.S. Department of Energy (DOE)'s Carlsbad Field Office (CBFO) is pursuing a twofold approach to develop a shipping path for these wastes. They are: regulatory change and technology development. For the regulatory change, a more detailed knowledge of the high wattage waste (e.g., void volumes, gas generation potential of specific chemical constituents) may allow refinement of the current assumptions in the gas generation model for Safety Analysis Reports for Packaging for Contact-Handled (CH) TRU waste. For technology development, one of the options being pursued is the use of a robust container, the ARROW-PAK{trademark} System. (1) The ARROW-PAK{trademark} is a macroencapsulation treatment technology, developed by Boh Environmental, LLC, New Orleans, Louisiana. This technology has been designed to withstand any unexpected hydrogen deflagration (i.e. no consequence) and other benefits such as criticality control.

Countiss, S. S.; Basabilvazo, G. T.; Moody, D. C. III; Lott, S. A.; Pickerell, M.; Baca, T.; CH2M Hill; Tujague, S.; Svetlik, H.; Hannah, T.

2003-02-27T23:59:59.000Z

99

An assessment of the flammability and explosion potential of transuranic waste  

SciTech Connect (OSTI)

The explosion potential of transuranic (TRU) waste, destined for the Waste Isolation Pilot (WIPP), was recently examined in EEG-45. That investigation focused on the volatile organic compounds (VOCs) in the waste, particularly acetone, and concluded that an explosion due to the VOCs was unlikely. Recent evidence raises serious concerns about drums containing mixed radioactive hazardous waste bound for the WIPP. Static electricity generated by the plastic bags represents a potential ignition source for other fuels, such as methane gas or hydrogen gas, during transportation and during the test phase. The potential danger of explosion due to hydrogen gas or methane gas generation has not yet been resolved. This report investigates that potential hazard and examines documented ignitions, fires, explosions and incidents of overpressurization of containers at generating and storage sites planning to send transuranic waste to the WIPP for disposal. 68 refs., 6 figs.

Silva, M.

1991-06-01T23:59:59.000Z

100

The effect of vibration on alpha radiolysis of transuranic (TRU) waste  

SciTech Connect (OSTI)

This paper reports on previously unpublished scoping work related to the potential for vibration to redistribute radionuclides on transuranic (TRU) waste. If this were to happen, the amount of gases generated, including hydrogen, could be increased above the undisturbed levels. This could be an important consideration for transport of TRU wastes either at DOE sites or from them to a future repository, e.g., the Waste Isolation Pilot Plant (WIPP). These preliminary data on drums of real waste seem to suggest that radionuclide redistribution does not occur. However improvements in the experimental methodology are suggested to enhance safety of future experiments on real wastes as well as to provide more rigorous data.

Zerwekh, A.; Kosiewicz, S. (Los Alamos National Lab., NM (United States)); Warren, J. (NFT, Inc., Lakewood, CO (United States))

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

The effect of vibration on alpha radiolysis of transuranic (TRU) waste  

SciTech Connect (OSTI)

This paper reports on previously unpublished scoping work related to the potential for vibration to redistribute radionuclides on transuranic (TRU) waste. If this were to happen, the amount of gases generated, including hydrogen, could be increased above the undisturbed levels. This could be an important consideration for transport of TRU wastes either at DOE sites or from them to a future repository, e.g., the Waste Isolation Pilot Plant (WIPP). These preliminary data on drums of real waste seem to suggest that radionuclide redistribution does not occur. However improvements in the experimental methodology are suggested to enhance safety of future experiments on real wastes as well as to provide more rigorous data.

Zerwekh, A.; Kosiewicz, S. [Los Alamos National Lab., NM (United States); Warren, J. [NFT, Inc., Lakewood, CO (United States)

1993-02-01T23:59:59.000Z

102

Oak Ridge National Laboratory contact-handled Transuranic Waste Certification Program plan  

SciTech Connect (OSTI)

The Oak Ridge National Laboratory (ORNL) is required by Department of Energy (DOE) Order 5820.2A to package its transuranic (TRU) waste to comply with waste acceptance criteria (WAC) for the Waste Isolation Pilot Plant (WIPP). TRU wastes are defined in DOE Order 5820.A as those radioactive wastes that are contaminated with alpha-emitting transuranium radionuclides having half-lives greater than 20 years and concentrations greater than 100 nCi/g at the time of the assay. In addition, ORNL handles U{sup 233}, Cm{sup 244}, and Cf{sup 252} as TRU waste radionuclides. The ORNL Transuranic Waste Certification Program was established to ensure that all TRU waste at ORNL is packaged to meet the required transportation and storage criteria for shipping to and storage at the WIPP. The objective of this document is to describe the methods that will be used at ORNL to package contact handled-transuranic (CH-TRU) waste to meet the criteria set forth in the WIPP certification requirements documents. This document addresses newly generated (NG) CH-TRU waste. Stored CH-TRU will be repackaged. This document is organized to provide a brief overview of waste generation operations at ORNL, along with details on data management for CH-TRU waste. The methods used to implement this plan are discussed briefly along with the responsibilities and authorities of applicable organizations. Techniques used for waste data collection, records control, and data archiving are defined. Procedures for the procurement and handling of waste containers are also described along with related quality control methods. 11 refs., 3 figs.

Smith, J.H.; Smith, M.A.

1990-08-01T23:59:59.000Z

103

Contact-Handled Transuranic Waste Acceptance Criteria for the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

The purpose of this document is to summarize the waste acceptance criteria applicable to the transportation, storage, and disposal of contact-handled transuranic (CH-TRU) waste at the Waste Isolation Pilot Plant (WIPP). These criteria serve as the U.S. Department of Energy's (DOE) primary directive for ensuring that CH-TRU waste is managed and disposed of in a manner that protects human health and safety and the environment.The authorization basis of WIPP for the disposal of CH-TRU waste includes the U.S.Department of Energy National Security and Military Applications of Nuclear EnergyAuthorization Act of 1980 (reference 1) and the WIPP Land Withdrawal Act (LWA;reference 2). Included in this document are the requirements and associated criteriaimposed by these acts and the Resource Conservation and Recovery Act (RCRA,reference 3), as amended, on the CH-TRU waste destined for disposal at WIPP.|The DOE TRU waste sites must certify CH-TRU waste payload containers to thecontact-handled waste acceptance criteria (CH-WAC) identified in this document. Asshown in figure 1.0, the flow-down of applicable requirements to the CH-WAC istraceable to several higher-tier documents, including the WIPP operational safetyrequirements derived from the WIPP CH Documented Safety Analysis (CH-DSA;reference 4), the transportation requirements for CH-TRU wastes derived from theTransuranic Package Transporter-Model II (TRUPACT-II) and HalfPACT Certificates ofCompliance (references 5 and 5a), the WIPP LWA (reference 2), the WIPP HazardousWaste Facility Permit (reference 6), and the U.S. Environmental Protection Agency(EPA) Compliance Certification Decision and approval for PCB disposal (references 7,34, 35, 36, and 37). The solid arrows shown in figure 1.0 represent the flow-down of allapplicable payload container-based requirements. The two dotted arrows shown infigure 1.0 represent the flow-down of summary level requirements only; i.e., the sitesmust reference the regulatory source documents from the U.S. Nuclear RegulatoryCommission (NRC) and the New Mexico Environment Department (NMED) for acomprehensive and detailed listing of the requirements.This CH-WAC does not address the subject of waste characterization relating to adetermination of whether the waste is hazardous; rather, the sites are referred to theWaste Analysis Plan (WAP) contained in the WIPP Hazardous Waste Facility Permit fordetails of the sampling and analysis protocols to be used in determining compliance withthe required physical and chemical properties of the waste. Requirements andassociated criteria pertaining to a determination of the radiological properties of thewaste, however, are addressed in appendix A of this document. The collectiveinformation obtained from waste characterization records and acceptable knowledge(AK) serves as the basis for sites to certify that their CH-TRU waste satisfies the WIPPwaste acceptance criteria listed herein.

Washington TRU Solutions LLC

2005-12-29T23:59:59.000Z

104

Unresolved issues for the disposal of remote-handled transuranic waste in the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

The purpose of the Waste Isolation Pilot Plant (WIPP) is to dispose of 176,000 cubic meters of transuranic (TRU) waste generated by the defense activities of the US Government. The envisioned inventory contains approximately 6 million cubic feet of contact-handled transuranic (CH TRU) waste and 250,000 cubic feet of remote handled transuranic (RH TRU) waste. CH TRU emits less than 0.2 rem/hr at the container surface. Of the 250,000 cubic feet of RH TRU waste, 5% by volume can emit up to 1,000 rem/hr at the container surface. The remainder of RH TRU waste must emit less than 100 rem/hr. These are major unresolved problems with the intended disposal of RH TRU waste in the WIPP. (1) The WIPP design requires the canisters of RH TRU waste to be emplaced in the walls (ribs) of each repository room. Each room will then be filled with drums of CH TRU waste. However, the RH TRU waste will not be available for shipment and disposal until after several rooms have already been filled with drums of CH TRU waste. RH TRU disposal capacity will be loss for each room that is first filled with CH TRU waste. (2) Complete RH TRU waste characterization data will not be available for performance assessment because the facilities needed for waste handling, waste treatment, waste packaging, and waste characterization do not yet exist. (3) The DOE does not have a transportation cask for RH TRU waste certified by the US Nuclear Regulatory Commission (NRC). These issues are discussed along with possible solutions and consequences from these solutions. 46 refs.

Silva, M.K.; Neill, R.H.

1994-09-01T23:59:59.000Z

105

Savannah River Site Achieves Transuranic Waste Disposition Goal...  

Office of Environmental Management (EM)

liquid waste contractor, Savannah River Remediation (SRR): Closed two more underground tanks containing radioactive waste, helping reduce a significant environmental risk to South...

106

Nondestructive assay and nondestructive examination of remote-handled transuranic waste at the ORNL waste handling and packaging plant  

SciTech Connect (OSTI)

The purpose of this investigation is to examine the use of an electron linear accelerator (LINAC) in the performance of nondestructive assay (NDA) and nondestructive examination (NDE) measurements of remote-handled transuranic wastes. The system will be used to perform waste characterization and certification activities at the Oak Ridge National Laboratory's proposed Waste Handling and Packaging Plant. The NDA and NDE technologies which were developed for contact-handled wastes are inadequate to perform such measurements on high gamma and neutron dose-rate wastes. A single LINAC will provide the interrogating fluxes required for both NDA and NDE measurements of the wastes. 11 refs., 6 figs.

Schultz, F.J.; Caldwell, J.T. (Oak Ridge National Lab., TN (USA); Pajarito Scientific Corp. (USA))

1989-01-01T23:59:59.000Z

107

A Title 40 Code of Federal Regulations Part 191 Evaluation of Buried Transuranic Waste at the Nevada Test Site  

SciTech Connect (OSTI)

In 1986, 21 m{sup 3} of transuranic (TRU) waste was inadvertently buried in a shallow land burial trench at the Area 5 Radioactive Waste Management Site on the Nevada Test Site (NTS). The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office is considered five options for management of the buried TRU waste. One option is to leave the waste in-place if the disposal can meet the requirements of Title 40 Code of Federal Regulations (CFR) Part 191, 'Environmental Radiation Protection Standard for Management and Disposal of Spent Nuclear Fuel, High-Level, and Transuranic Radioactive Wastes'. This paper describes analyses that assess the likelihood that TRU waste in shallow land burial can meet the 40 CFR 191 standards for a geologic repository. The simulated probability of the cumulative release exceeding 1 and 10 times the 40 CFR 191.13 containment requirements is estimated to be 0.009 and less than 0.0001, respectively. The cumulative release is most sensitive to the number of groundwater withdrawal wells drilled through the disposal trench. The mean total effective dose equivalent for a member of the public is estimated to reach a maximum of 0.014 milliSievert (mSv) at 10,000 years, or approximately 10 percent of the 0.15 mSv 40 CFR 191.15 individual protection requirement. The dose is predominantly from inhalation of short-lived Rn-222 progeny in air produced by low-level waste disposed in the same trench. The transuranic radionuclide released in greatest amounts, Pu-239, contributes only 0.4 percent of the dose. The member of public dose is most sensitive to the U-234 inventory and the radon emanation coefficient. Reasonable assurance of compliance with the Subpart C groundwater protection standard is provided by site characterization data and hydrologic processes modeling which support a conclusion of no groundwater pathway within 10,000 years. Limited quantities of transuranic waste in a shallow land burial trench at the NTS can meet the requirements of 40 CFR 191.

G. J. Shott, V. Yucel, L. Desotell

2008-04-01T23:59:59.000Z

108

Waste Generator Instructions: Key to Successful Implementation of the US DOE's 435.1 for Transuranic Waste Packaging Instructions (LA-UR-12-24155) - 13218  

SciTech Connect (OSTI)

In times of continuing fiscal constraints, a management and operation tool that is straightforward to implement, works as advertised, and virtually ensures compliant waste packaging should be carefully considered and employed wherever practicable. In the near future, the Department of Energy (DOE) will issue the first major update to DOE Order 435.1, Radioactive Waste Management. This update will contain a requirement for sites that do not have a Waste Isolation Pilot Plant (WIPP) waste certification program to use two newly developed technical standards: Contact-Handled Defense Transuranic Waste Packaging Instructions and Remote-Handled Defense Transuranic Waste Packaging Instructions. The technical standards are being developed from the DOE O 435.1 Notice, Contact-Handled and Remote-Handled Transuranic Waste Packaging, approved August 2011. The packaging instructions will provide detailed information and instruction for packaging almost every conceivable type of transuranic (TRU) waste for disposal at WIPP. While providing specificity, the packaging instructions leave to each site's own discretion the actual mechanics of how those Instructions will be functionally implemented at the floor level. While the Technical Standards are designed to provide precise information for compliant packaging, the density of the information in the packaging instructions necessitates a type of Rosetta Stone that translates the requirements into concise, clear, easy to use and operationally practical recipes that are waste stream and facility specific for use by both first line management and hands-on operations personnel. The Waste Generator Instructions provide the operator with step-by-step instructions that will integrate the sites' various operational requirements (e.g., health and safety limits, radiological limits or dose limits) and result in a WIPP certifiable waste and package that can be transported to and emplaced at WIPP. These little known but widely productive Waste Generator Instructions (WGIs) have been used occasionally in the past at large sites for treatment and packaging of TRU waste. The WGIs have resulted in highly efficient waste treatment, packaging and certification for disposal of TRU waste at WIPP. For example, a single WGI at LANL, combined with an increase in gram loading, resulted in a mind boggling 6,400% increase in waste loading for {sup 238}Pu heat source waste. In fact, the WGI combined with a new Contact Handled (CH) TRU Waste Content (TRUCON) Code provided a massive increase in shippable wattage per Transuranic Package Transporter-II (TRUPACT-II) over the previously used and more restrictive TRUCON Code that have been used previously for the heat source waste. In fact, the use of the WGI process at LANL's TA-55 facility reduced non-compliant drums for WIPP certification and disposal from a 13% failure rate down to a 0.5% failure rate and is expected to further reduce the failure rate to zero drums per year. The inherent value of the WGI is that it can be implemented in a site's current procedure issuance process and it provides documented proof of what actions were taken for each waste stream packaged. The WGI protocol provides a key floor-level operational component to achieve goal alignment between actual site operations, the WIPP TRU waste packaging instructions, and DOE O 435.1. (authors)

French, David M. [LANL EES-12, Carlsbad, NM, Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States)] [LANL EES-12, Carlsbad, NM, Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States); Hayes, Timothy A. [LANL EES-12, Carlsbad, NM, Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States)] [LANL EES-12, Carlsbad, NM, Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States); Pope, Howard L. [Aspen Resources Ltd., Inc., P.O. Box 3038, Boulder, CO 80307 (United States)] [Aspen Resources Ltd., Inc., P.O. Box 3038, Boulder, CO 80307 (United States); Enriquez, Alejandro E. [LANL NCO-4, Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States)] [LANL NCO-4, Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States); Carson, Peter H. [LANL NPI-7, Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States)] [LANL NPI-7, Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States)

2013-07-01T23:59:59.000Z

109

Consideration of nuclear criticality when disposing of transuranic waste at the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

Based on general arguments presented in this report, nuclear criticality was eliminated from performance assessment calculations for the Waste Isolation Pilot Plant (WIPP), a repository for waste contaminated with transuranic (TRU) radioisotopes, located in southeastern New Mexico. At the WIPP, the probability of criticality within the repository is low because mechanisms to concentrate the fissile radioisotopes dispersed throughout the waste are absent. In addition, following an inadvertent human intrusion into the repository (an event that must be considered because of safety regulations), the probability of nuclear criticality away from the repository is low because (1) the amount of fissile mass transported over 10,000 yr is predicted to be small, (2) often there are insufficient spaces in the advective pore space (e.g., macroscopic fractures) to provide sufficient thickness for precipitation of fissile material, and (3) there is no credible mechanism to counteract the natural tendency of the material to disperse during transport and instead concentrate fissile material in a small enough volume for it to form a critical concentration. Furthermore, before a criticality would have the potential to affect human health after closure of the repository--assuming that a criticality could occur--it would have to either (1) degrade the ability of the disposal system to contain nuclear waste or (2) produce significantly more radioisotopes than originally present. Neither of these situations can occur at the WIPP; thus, the consequences of a criticality are also low.

RECHARD,ROBERT P.; SANCHEZ,LAWRENCE C.; STOCKMAN,CHRISTINE T.; TRELLUE,HOLLY R.

2000-04-01T23:59:59.000Z

110

The Second Opening of the Waste Isolation Pilot Plant? Review of Salient Characteristics and Unique Operational Considerations for Remote Handled Transuranic Waste  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) intends to dispose of remote handled (RH) transuranic (TRU) waste at the Waste Isolation Pilot Plant (WIPP) beginning in 2005. (1) Four principle regulatory agencies are involved in the process of approving the RH TRU waste activities. The DOE is responsible for operational activities. The U. S. Nuclear Regulatory Commission (NRC) approves the design and use of shipping containers. The U.S. Environmental Protection Agency (EPA) is responsible for assuring safe and environmentally effective long-term disposal of the radioactive component of the waste and operational environmental monitoring. The New Mexico Environment Department (NMED) is responsible for the handling and the disposal of the non-radioactive hazardous component of the waste. The Environmental Evaluation Group (EEG) is responsible for performing independent technical oversight of all WIPP activities, and will comment on documents and practices for the various regulated RH TRU waste activities. The DOE has already obtained the necessary approvals from the NRC, and has submitted a Class 3 Modification request to the NMED. On December 16, 2002 the DOE Carlsbad Field Office (CBFO) provided the EPA with a notice of proposed change, in accordance with 40 CFR 194.4 (b) (3), to receive and dispose of remote handled transuranic waste. (2) WIPP procedures for the management of RH TRU waste at the site are being developed. While there are no issues with current NRC Certificates of Compliance for the RH TRU waste shipping containers, it is likely that there will be some controversy over other aspects of the currently planned RH TRU waste program. These issues may include: (1) the published RH TRU waste inventory, (2) the characterization of the radionuclide portion of the waste, for which one planned method is to use dose-to-Curie conversions, and (3) the plans to use bounding estimates for the hazardous portion of the WIPP waste, rather than measuring VOCs on a container-by-container basis or by representative sampling as is done for contact handled transuranic (CH TRU) waste. This paper discusses the currently planned process and the possible issues related to the DOE's efforts to dispose RH TRU waste at the WIPP.

Anastas, G.; Walker, B.A.

2003-02-24T23:59:59.000Z

111

W-026, transuranic waste (TRU) glovebox acceptance test report  

SciTech Connect (OSTI)

On July 18, 1997, the Transuranic (TRU) glovebox was tested using glovebox acceptance test procedure 13021A-86. The primary focus of the glovebox acceptance test was to examine control system interlocks, display menus, alarms, and operator messages. Limited mechanical testing involving the drum ports, hoists, drum lifter, compacted drum lifter, drum tipper, transfer car, conveyors, sorting table, lidder/delidder device and the TRU empty drum compactor were also conducted. As of February 25, 1998, 10 of the 102 test exceptions that affect the TRU glovebox remain open. These items will be tracked and closed via the WRAP Master Test Exception Database. As part of Test Exception resolution/closure the responsible individual closing the Test Exception performs a retest of the affected item(s) to ensure the identified deficiency is corrected, and, or to test items not previously available to support testing. Test exceptions are provided as appendices to this report.

Leist, K.J.

1998-03-11T23:59:59.000Z

112

Thermal processing systems for TRU mixed waste  

SciTech Connect (OSTI)

This paper presents preliminary ex situ thermal processing system concepts and related processing considerations for remediation of transuranic (TRU)-contaminated wastes (TRUW) buried at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Anticipated waste stream components and problems are considered. Thermal processing conditions required to obtain a high-integrity, low-leachability glass/ceramic final waste form are considered. Five practical thermal process system designs are compared. Thermal processing of mixed waste and soils with essentially no presorting and using incineration followed by high temperature melting is recommended. Applied research and development necessary for demonstration is also recommended.

Eddy, T.L.; Raivo, B.D.; Anderson, G.L.

1992-01-01T23:59:59.000Z

113

Thermal processing systems for TRU mixed waste  

SciTech Connect (OSTI)

This paper presents preliminary ex situ thermal processing system concepts and related processing considerations for remediation of transuranic (TRU)-contaminated wastes (TRUW) buried at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Anticipated waste stream components and problems are considered. Thermal processing conditions required to obtain a high-integrity, low-leachability glass/ceramic final waste form are considered. Five practical thermal process system designs are compared. Thermal processing of mixed waste and soils with essentially no presorting and using incineration followed by high temperature melting is recommended. Applied research and development necessary for demonstration is also recommended.

Eddy, T.L.; Raivo, B.D.; Anderson, G.L.

1992-08-01T23:59:59.000Z

114

Transuranic contaminated waste container characterization and data base. Revision I  

SciTech Connect (OSTI)

The Nuclear Regulatory Commission (NRC) is developing regulations governing the management, handling and disposal of transuranium (TRU) radioisotope contaminated wastes as part of the NRC's overall waste management program. In the development of such regulations, numerous subtasks have been identified which require completion before meaningful regulations can be proposed, their impact evaluated and the regulations implemented. This report was prepared to assist in the development of the technical data base necessary to support rule-making actions dealing with TRU-contaminated wastes. An earlier report presented the waste sources, characteristics and inventory of both Department of Energy (DOE) generated and commercially generated TRU waste. In this report a wide variety of waste sources as well as a large TRU inventory were identified. The purpose of this report is to identify the different packaging systems used and proposed for TRU waste and to document their characteristics. This document then serves as part of the data base necessary to complete preparation and initiate implementation of TRU waste container and packaging standards and criteria suitable for inclusion in the present TRU waste management program. It is the purpose of this report to serve as a working document which will be used as appropriate in the TRU Waste Management Program. This report, and those following, will be compatible not only in format, but also in reference material and direction.

Kniazewycz, B.G.

1980-05-01T23:59:59.000Z

115

MANAGING THE RETRIEVAL RISK OF BURIED TRANSURANIC (TRU) WASTE WITH UNIQUE CHARACTERISTICS  

SciTech Connect (OSTI)

United States-Department of Energy (DOE) sites that store transuranic (TRU) waste are almost certain to encounter waste packages with characteristics that are so unique as to warrant special precautions for retrieval. At the Hanford Site, a subgroup of stored TRU waste (12 drums) had special considerations due to the radioactive source content of plutonium oxide (PuO{sub 2}), and the potential for high heat generation, pressurization, criticality, and high radiation. These characteristics bear on the approach to safely retrieve, overpack, vent, store, and transport the waste package. Because of the potential risk to personnel, contingency planning for unexpected conditions played an effective role in work planning and in preparing workers for the field inspection activity. As a result, the integrity inspections successfully confirmed waste package configuration and waste confinement without experiencing any perturbations due to unanticipated packaging conditions. This paper discusses the engineering and field approach to managing the risk of retrieving TRU waste with unique characteristics.

WOJTASEK, R.D.; GADD, R.R.; GREENWELL, R.D.

2006-01-19T23:59:59.000Z

116

MANAGEING THE RETRIEVAL RISK OF BURIED TRANSURANIC (TRU) WASTE WITH UNIQUE CHARACTERISTICS  

SciTech Connect (OSTI)

United States-Department of Energy (DOE) sites that store transuranic (TRU) waste are almost certain to encounter waste packages with characteristics that are so unique as to warrant special precautions for retrieval. At the Hanford Site, a subgroup of stored TRU waste (12 drums) had special considerations due to the radioactive source content of plutonium oxide (PuO{sub 2}), and the potential for high heat generation, pressurization, criticality, and high radiation. These characteristics bear on the approach to safely retrieve, overpack, vent, store, and transport the waste package. Because of the potential risk to personnel, contingency planning for unexpected conditions played an effective roll in work planning and in preparing workers for the field inspection activity. As a result, the integrity inspections successfully confirmed waste package configuration and waste confinement without experiencing any perturbations due to unanticipated packaging conditions. This paper discusses the engineering and field approach to managing the risk of retrieving TRU waste with unique characteristics.

WOJTASEK, R.D.; GREENWELL, R.D.

2005-11-17T23:59:59.000Z

117

Fiscal year 1986 program plan for the Defense Transuranic Waste Program (DTWP)  

SciTech Connect (OSTI)

The Defense TRU Waste Program (DTWP) is the focal point for the Department of Energy is national planning, integration, and technical development for TRU waste management. The scope of this program extends from the point of TRU waste generation through delivery to a permanent repository. The TRU program maintains a close interface with repository development to ensure program compatibility and coordination. The defense TRU program does not directly address commercial activities that generate TRU waste. Instead, it is concerned with providing alternatives to manage existing and future defense TRU wastes. The FY 86 Program Plan is consistent with the Defense TRU Waste Program goals and objectives stated in the Defense Transuranic Waste Program Strategy Document, January 1984. The roles of participants, the responsibilities and authorities for Research Development (R D), the organizational interfaces and communication channels for R D and the establishment of procedures for planning, reporting, and budgeting of all R D activities meet requirements tated in the Technical Management Plan for the Transuranic Waste Management Program. The Program Plan is revised as needed. Detailed budget planning (i.e., programmatic funding and capital equipment) is presented for FY 86; outyear budget projections are presented for future years.

Not Available

1985-11-01T23:59:59.000Z

118

Characteristics of transuranic waste at Department of Energy sites  

SciTech Connect (OSTI)

This document reports data and information on TRU waste from all DOE generating and storage sites. The geographical location of the sites is shown graphically. There are four major sections in this document. The first three cover the TRU waste groups known as Newly Generated, Stored, and Buried Wastes. Subsections are included under Newly Generated and Stored on contact-handled and remote-handled waste. These classifications of waste are defined, and the current or expected totals of each are given. Figure 1.3 shows the total amount of Buried and Stored TRU waste. Preparation of this document began in 1981, and most of the data are as of December 31, 1980. In a few cases data were reported to December 31, 1981, and these have been noted. The projections in the Newly Generated section were made, for the most part, at the end of 1981.

Jensen, R.T.; Wilkinson, F.J. III

1983-05-01T23:59:59.000Z

119

A little here, a little there, a fairly big problem everywhere: Small quantity site transuranic waste disposition alternatives  

SciTech Connect (OSTI)

Small quantities of transuranic (TRU) waste represent a significant challenge to the waste disposition and facility closure plans of several sites in the Department of Energy (DOE) complex. This paper presents the results of a series of evaluations, using a systems engineering approach, to identify the preferred alternative for dispositioning TRU waste from small quantity sites (SQSs). The TRU waste disposition alternatives evaluation used semi-quantitative data provided by the SQSs, potential receiving sites, and the Waste Isolation Pilot Plant (WIPP) to select and recommend candidate sites for waste receipt, interim storage, processing, and preparation for final disposition of contact-handled (CH) and remote-handled (RH) TRU waste. The evaluations of only four of these SQSs resulted in potential savings to the taxpayer of $33 million to $81 million, depending on whether mobile systems could be used to characterize, package, and certify the waste or whether each site would be required to perform this work. Small quantity shipping sites included in the evaluation included the Battelle Columbus Laboratory (BCL), University of Missouri Research Reactor (MURR), Energy Technology Engineering Center (ETEC), and Mound Laboratory. Candidate receiving sites included the Idaho National Engineering and Environmental Laboratory (INEEL), the Savannah River Site (SRS), Los Alamos National Laboratory (LANL), Oak Ridge (OR), and Hanford. At least 14 additional DOE sites having TRU waste may be able to save significant money if cost savings are similar to the four evaluated thus far.

D. Luke; D. Parker; J. Moss; T. Monk (INEEL); L. Fritz (DOE-ID); B. Daugherty (SRS); K. Hladek (WM Federal Services Hanford); S. Kosiewicx (LANL)

2000-02-27T23:59:59.000Z

120

A Little Here, A Little There, A Fairly Big Problem Everywhere: Small Quantity Site Transuranic Waste Disposition Alternatives  

SciTech Connect (OSTI)

Small quantities of transuranic (TRU) waste represent a significant challenge to the waste disposition and facility closure plans of several sites in the Department of Energy (DOE) complex. This paper presents the results of a series of evaluations, using a systems engineering approach, to identify the preferred alternative for dispositioning TRU waste from small quantity sites (SQSs). The TRU waste disposition alternatives evaluation used semi-quantitative data provided by the SQSs, potential receiving sites, and the Waste Isolation Pilot Plant (WIPP) to select and recommend candidate sites for waste receipt, interim storage, processing, and preparation for final disposition of contact-handled (CH) and remote-handled (RH) TRU waste. The evaluations of only four of these SQSs resulted in potential savings to the taxpayer of $33 million to $81 million, depending on whether mobile systems could be used to characterize, package, and certify the waste or whether each site would be required to perform this work. Small quantity shipping sites included in the evaluation included the Battelle Columbus Laboratory (BCL), University of Missouri Research Reactor (MURR), Energy Technology Engineering Center (ETEC), and Mound. Candidate receiving sites included the Idaho National Engineering and Environmental Laboratory (INEEL), the Savannah River Site (SRS), Los Alamos National Laboratory (LANL), Oak Ridge (OR), and Hanford. At least 14 additional DOE sites having TRU waste may be able to save significant money if cost savings are similar to the four evaluated thus far.

Luke, Dale Elden; Parker, Douglas Wayne; Moss, J.; Monk, Thomas Hugh; Fritz, Lori Lee; Daugherty, B.; Hladek, K.; Kosiewicx, S.

2000-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Quality assurance (QA) plan for the transportation and receipt of transuranic (TRU) waste  

SciTech Connect (OSTI)

The Department of Energy (DOE) Albuquerque Operations (AL) Office of Projects and Energy Programs has been assigned the responsibility for administration of the disposal of Contact-Handled (CH) Transuranic (TRU) contaminated material (waste) from generator/storage sites of the United States defense programs that are operated by the DOE. This responsibility encompasses all activities associated with the certification of TRU waste and the transportation, receipt and disposal of that waste at the Waste Isolation Pilot Plant (WIPP). The WIPP is located near Carlsbad, New Mexico and is being developed under the management of the DOE WIPP Project Office (WPO). The DOE/WPO is a branch of the DOE/AL and has been delegated overall responsibility for all aspects of the WIPP program. This report describes the quality assurance plan for the TRU waste transportation and receipt of waste.

Not Available

1990-02-01T23:59:59.000Z

122

Assessment of alternatives for management of ORNL retrievable transuranic waste. Nuclear Waste Program: transuranic waste (Activity No. AR 05 15 15 0; ONL-WT04)  

SciTech Connect (OSTI)

Since 1970, solid waste with TRU or U-233 contamination in excess of 10 ..mu..Ci per kilogram of waste has been stored in a retrievable fashion at ORNL, such as in ss drums, concrete casks, and ss-lined wells. This report describes the results of a study performed to identify and evaluate alternatives for management of this waste and of the additional waste projected to be stored through 1995. The study was limited to consideration of the following basic strategies: Strategy 1: Leave waste in place as is; Strategy 2: Improve waste confinement; and Strategy 3: Retrieve waste and process for shipment to a Federal repository. Seven alternatives were identified and evaluated, one each for Strategies 1 and 2 and five for Strategy 3. Each alternative was evaluated from the standpoint of technical feasibility, cost, radiological risk and impact, regulatory factors and nonradiological environmental impact.

Not Available

1980-10-01T23:59:59.000Z

123

An Alternative to Performing Remote-Handled Transuranic Waste Container Headspace Gas Sampling and Analysis  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP) is operating under a Resource Conservation and Recovery Act (RCRA) Hazardous Waste Facility Permit (HWFP) for contact-handled (CH) transuranic (TRU) waste. The HWFP contains limitations on allowable emissions from waste disposed in the underground. This environmental performance standard imposed on the WIPP consists of limiting volatile organic compound (VOC) emissions from emplaced waste to ensure protection of human health and the environment. The standard is currently met by tracking individual waste container headspace gas concentrations, which are determined by headspace gas sampling and analysis of CH TRU waste containers. The WIPP is seeking a HWFP modification to allow the disposal of remote-handled (RH) TRU waste. Because RH TRU waste is limited to approximately 5% of the waste volume and is emplaced in the disposal room walls, it is possible to bound the potential RH TRU waste contribution to VOC emissions using conservative upper bounds. These conservative upper bounds were developed as an alternative to RH TRU waste canister headspace gas sampling and analysis. The methodology used to perform the calculations used to evaluate VOC emissions from emplaced RH TRU waste canisters applied the same equations as those used to evaluate VOC emissions in the original HWFP application.

Spangler, L. R.; Djordjevic, S. M.; Kehrman, R. F.; Most, W. A.

2002-02-26T23:59:59.000Z

124

Transuranic Waste Program Framework Agreement - December Deliverable July 2012  

SciTech Connect (OSTI)

Framework agreement deliverables are: (1) 'DOE/NNSA commits to complete removal of all non-cemented above-ground EM Legacy TRU and newly generated TRU currently-stored at Area G as of October 1, 2011, by no later than June 30, 2014. This inventory of above-ground TRU is defined as 3706 cubic meters of material.' (2) 'DOE commits to the complete removal of all newly generated TRU received in Area G during FY 2012 and 2013 by no later than December 31, 2014.' (3) 'Based on projected funding profiles, DOE/NNSA will develop by December 31, 2012, a schedule, including pacing milestones, for disposition of the below-ground TRU requiring retrieval at Area G.' Objectives are to: (1) restore the 'Core Team' to develop the December, 2012 deliverable; (2) obtain agreement on the strategy for below ground water disposition; and (3) establish timeline for completion of the deliverable. Below Grade Waste Strategy is to: (1) Perform an evaluation on below grade waste currently considered retrievable TRU; (2) Only commit to retrieve waste that must be retrieved; (3) Develop the Deliverable including Pacing Milestones based on planned commitments; (4) Align all Regulatory Documents for Consistency; and (5) answer these 3 primary questions, is the waste TRU; is the waste retrievable, can retrieval cause more harm than benefit?

Jones, Patricia [Los Alamos National Laboratory

2012-07-19T23:59:59.000Z

125

Long-Term Performance of Transuranic Waste Inadvertently Disposed in a Shallow Land Burial Trench at the Nevada Test Site  

SciTech Connect (OSTI)

In 1986, 21 m3 of transuranic (TRU) waste was inadvertently disposed in a shallow land burial trench at the Area 5 Radioactive Waste Management Site on the Nevada Test Site. U.S. Department of Energy (DOE) TRU waste must be disposed in accordance with Title 40, Code of Federal Regulations (CFR), Part 191, Environmental Radiation Protection Standard for Management and Disposal of Spent Nuclear Fuel, High-Level, and Transuranic Radioactive Wastes. The Waste Isolation Pilot Plant is the only facility meeting these requirements. The National Research Council, however, has found that exhumation of buried TRU waste for disposal in a deep geologic repository may not be warranted when the effort, exposures, and expense of retrieval are not commensurate with the risk reduction achieved. The long-term risks of leaving the TRU waste in-place are evaluated in two probabilistic performance assessments. A composite analysis, assessing the dose from all disposed waste and interacting sources of residual contamination, estimates an annual total effective dose equivalent (TEDE) of 0.01 mSv, or 3 percent of the dose constraint. A 40 CFR 191 performance assessment also indicates there is reasonable assurance of meeting all requirements. The 40 CFR 191.15 annual mean TEDE for a member of the public is estimated to reach a maximum of 0.055 mSv at 10,000 years, or approximately 37 percent of the 0.15 mSv individual protection requirement. In both assessments greater than 99 percent of the dose is from co-disposed low-level waste. The simulated probability of the 40 CFR 191.13 cumulative release exceeding 1 and 10 times the release limit is estimated to be 0.0093 and less than 0.0001, respectively. Site characterization data and hydrologic process modeling support a conclusion of no groundwater pathway within 10,000 years. Monte Carlo uncertainty analysis indicates that there is reasonable assurance of meeting all regulatory requirements. Sensitivity analysis indicates that the results are insensitive to TRU waste-related parameters. Limited quantities of TRU waste in a shallow land burial trench can meet DOE performance objectives for disposal of TRU waste and contribute negligibly to disposal site risk. Leaving limited quantities of buried TRU waste in-place may be preferred over retrieval for disposal in a deep geologic repository.

Gregory J. Shott; Vefa Yucel

2009-07-16T23:59:59.000Z

126

Shielded Payload Containers Will Enhance the Safety and Efficiency of the DOE's Remote Handled Transuranic Waste Disposal Operations  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP) disposal operation currently employs two different disposal methods: one for Contact Handled (CH) waste and another for Remote Handled (RH) waste. CH waste is emplaced in a variety of payload container configurations on the floor of each disposal room. In contrast, RH waste is packaged into a single type of canister and emplaced in pre-drilled holes in the walls of disposal rooms. Emplacement of the RH waste in the walls must proceed in advance of CH waste emplacement. This poses a significant logistical constraint on waste handling operations by requiring significant coordination between waste characterization and preparations for shipping among the various generators. To improve operational efficiency, the Department of Energy (DOE) is proposing a new waste emplacement process for certain RH waste streams that can be safely managed in shielded containers. RH waste with relatively low gamma-emitting activity would be packaged in lead-lined containers, shipped to WIPP in existing certified transportation packages for CH waste, and emplaced in WIPP among the stacks of CH waste containers on the floor of a disposal room. RH waste with high gamma-emitting activity would continue to be emplaced in the boreholes along the walls. The new RH container appears essentially the same as a nominal 208-liter drum, but is built with about 2.5 cm of lead, sandwiched between thick steel sheet. The top and bottom are made of very thick plate steel, for strengthening the package to meet transportation requirements, and provide similar gamma attenuation. This robust configuration provides an overpack for waste that otherwise would be remotely handled. Up to a 3:1 reduction in number of shipments is projected if RH waste were transported in the proposed shielded containers. This paper describes the container design and testing, as well as the regulatory approach used to meet the requirements that apply to WIPP and its associated transportation system. This paper describes the RH transuranic waste inventory that may be candidates for packaging and emplacement in shielded containers. DOE does not propose to use shielded containers to increase the amount of RH waste allowed at WIPP. DOE's approach to gain approval for the transportation of shielded containers and to secure regulatory approval for use of shielded containers from WIPP regulators is discussed. Finally, the paper describes how DOE proposes to count the waste packaged into shielded containers against the RH waste inventory and how this will comply with the volume and radioactivity limitations imposed in the many and sometimes overlapping regulations that apply to WIPP. (authors)

Nelson, R.A. [U. S. Department of Energy, Carlsbad, New Mexico (United States); White, D.S. [Washington Group International, Carlsbad, New Mexico (United States)

2008-07-01T23:59:59.000Z

127

Electrochemical/Pyrometallurgical Waste Stream Processing and Waste Form Fabrication  

SciTech Connect (OSTI)

This report summarizes treatment and waste form options being evaluated for waste streams resulting from the electrochemical/pyrometallurgical (pyro ) processing of used oxide nuclear fuel. The technologies that are described are South Korean (Republic of Korea – ROK) and United States of America (US) ‘centric’ in the approach to treating pyroprocessing wastes and are based on the decade long collaborations between US and ROK researchers. Some of the general and advanced technologies described in this report will be demonstrated during the Integrated Recycle Test (IRT) to be conducted as a part of the Joint Fuel Cycle Study (JFCS) collaboration between US Department of Energy (DOE) and ROK national laboratories. The JFCS means to specifically address and evaluated the technological, economic, and safe guard issues associated with the treatment of used nuclear fuel by pyroprocessing. The IRT will involve the processing of commercial, used oxide fuel to recover uranium and transuranics. The recovered transuranics will then be fabricated into metallic fuel and irradiated to transmutate, or burn the transuranic elements to shorter lived radionuclides. In addition, the various process streams will be evaluated and tested for fission product removal, electrolytic salt recycle, minimization of actinide loss to waste streams and waste form fabrication and characterization. This report specifically addresses the production and testing of those waste forms to demonstrate their compatibility with treatment options and suitability for disposal.

Steven Frank; Hwan Seo Park; Yung Zun Cho; William Ebert; Brian Riley

2014-12-01T23:59:59.000Z

128

Magnetically assisted chemical separation (MACS) process: Preparation and optimization of particles for removal of transuranic elements  

SciTech Connect (OSTI)

The Magnetically Assisted Chemical Separation (MACS) process combines the selectivity afforded by solvent extractants with magnetic separation by using specially coated magnetic particles to provide a more efficient chemical separation of transuranic (TRU) elements, other radionuclides, and heavy metals from waste streams. Development of the MACS process uses chemical and physical techniques to elucidate the properties of particle coatings and the extent of radiolytic and chemical damage to the particles, and to optimize the stages of loading, extraction, and particle regeneration. This report describes the development of a separation process for TRU elements from various high-level waste streams. Polymer-coated ferromagnetic particles with an adsorbed layer of octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) diluted with tributyl phosphate (TBP) were evaluated for use in the separation and recovery of americium and plutonium from nuclear waste solutions. Due to their chemical nature, these extractants selectively complex americium and plutonium contaminants onto the particles, which can then be recovered from the solution by using a magnet. The partition coefficients were larger than those expected based on liquid[liquid extractions, and the extraction proceeded with rapid kinetics. Extractants were stripped from the particles with alcohols and 400-fold volume reductions were achieved. Particles were more sensitive to acid hydrolysis than to radiolysis. Overall, the optimization of a suitable NMCS particle for TRU separation was achieved under simulant conditions, and a MACS unit is currently being designed for an in-lab demonstration.

Nunez, L.; Kaminski, M.; Bradley, C.; Buchholz, B.A.; Aase, S.B.; Tuazon, H.E.; Vandegrift, G.F. [Argonne National Lab., IL (United States); Landsberger, S. [Univ. of Illinois, Urbana, IL (United States)

1995-05-01T23:59:59.000Z

129

IMPROVEMENTS IN CONTAINER MANAGEMENT OF TRANSURANIC (TRU) AND LOW LEVEL RADIOACTIVE WASTE STORED AT THE CENTRAL WASTE COMPLEX (CWC) AT HANFORD  

SciTech Connect (OSTI)

The Central Waste Complex (CWC) is the interim storage facility for Resource Conservation & Recovery Act (RCRA) mixed waste, transuranic waste, transuranic mixed waste, low-level and low-level mixed radioactive waste at the Department of Energy's (DOE'S) Hanford Site. The majority of the waste stored at the facility is retrieved from the low-level burial grounds in the 200 West Area at the Site, with minor quantities of newly generated waste from on-site and off-site waste generators. The CWC comprises 18 storage buildings that house 13,000 containers. Each waste container within the facility is scanned into its location by building, module, tier and position and the information is stored in a site-wide database. As waste is retrieved from the burial grounds, a preliminary non-destructive assay is performed to determine if the waste is transuranic (TRU) or low-level waste (LLW) and subsequently shipped to the CWC. In general, the TRU and LLW waste containers are stored in separate locations within the CWC, but the final disposition of each waste container is not known upon receipt. The final disposition of each waste container is determined by the appropriate program as process knowledge is applied and characterization data becomes available. Waste containers are stored within the CWC based on their physical chemical and radiological hazards. Further segregation within each building is done by container size (55-gallon, 85-gallon, Standard Waste Box) and waste stream. Due to this waste storage scheme, assembling waste containers for shipment out of the CWC has been time consuming and labor intensive. Qualitatively, the ratio of containers moved to containers in the outgoing shipment has been excessively high, which correlates to additional worker exposure, shipment delays, and operational inefficiencies. These inefficiencies impacted the LLW Program's ability to meet commitments established by the Tri-Party Agreement, an agreement between the State of Washington, the Department of Energy, and the Environmental Protection Agency. These commitments require waste containers to be shipped off site for disposal and/or treatment within a certain time frame. Because the program was struggling to meet production demands, the Production and Planning group was tasked with developing a method to assist the LLW Program in fulfilling its requirements. Using existing databases for container management, a single electronic spreadsheet was created to visually map every waste container within the CWC. The file displays the exact location (e.g., building, module, tier, position) of each container in a format that replicates the actual layout in the facility. In addition, each container was placed into a queue defined by the LLW and TRU waste management programs. The queues were developed based on characterization requirements, treatment type and location, and potential final disposition. This visual aid allows the user to select containers from similar queues and view their location within the facility. The user selects containers in a centralized location, rather than random locations, to expedite shipments out of the facility. This increases efficiency for generating the shipments, as well as decreasing worker exposure and container handling time when gathering containers for shipment by reducing movements of waste container. As the containers are collected for shipment, the remaining containers are segregated by queue, which further reduces future container movements.

UYTIOCO EM

2007-11-14T23:59:59.000Z

130

DOE Seeks Trucking Services for Transuranic Waste Shipments | Department of  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power Systems EngineeringDepartmentSmartDepartmentEnergy Waste Tracking Contract DOE

131

Transuranic and Low-Level Boxed Waste Form Nondestructive Assay Technology Overview and Assessment  

SciTech Connect (OSTI)

The Mixed Waste Focus Area (MWFA) identified the need to perform an assessment of the functionality and performance of existing nondestructive assay (NDA) techniques relative to the low-level and transuranic waste inventory packaged in large-volume box-type containers. The primary objectives of this assessment were to: (1) determine the capability of existing boxed waste form NDA technology to comply with applicable waste radiological characterization requirements, (2) determine deficiencies associated with existing boxed waste assay technology implementation strategies, and (3) recommend a path forward for future technology development activities, if required. Based on this assessment, it is recommended that a boxed waste NDA development and demonstration project that expands the existing boxed waste NDA capability to accommodate the indicated deficiency set be implemented. To ensure that technology will be commercially available in a timely fashion, it is recommended this development and demonstration project be directed to the private sector. It is further recommended that the box NDA technology be of an innovative design incorporating sufficient NDA modalities, e.g., passive neutron, gamma, etc., to address the majority of the boxed waste inventory. The overall design should be modular such that subsets of the overall NDA system can be combined in optimal configurations tailored to differing waste types.

G. Becker; M. Connolly; M. McIlwain

1999-02-01T23:59:59.000Z

132

MANAGEMENT OF TRANSURANIC (TRU) WASTE RETRIEVAL PROJECT RISKS SUCCESSES IN THE STARTUP OF THE HANFORD 200 AREA TRU WASTE RETRIEVAL PROJECT  

SciTech Connect (OSTI)

A risk identification and mitigation method applied to the Transuranic (TRU) Waste Retrieval Project performed at the Hanford 200 Area burial grounds is described. Retrieval operations are analyzed using process flow diagramming. and the anticipated project contingencies are included in the Authorization Basis and operational plans. Examples of uncertainties assessed include degraded container integrity, bulged drums, unknown containers, and releases to the environment. Identification and mitigation of project risks contributed to the safe retrieval of over 1700 cubic meters of waste without significant work stoppage and below the targeted cost per cubic meter retrieved. This paper will be of interest to managers, project engineers, regulators, and others who are responsible for successful performance of waste retrieval and other projects with high safety and performance risks.

GREENWLL, R.D.

2005-01-20T23:59:59.000Z

133

Environmental assessment for transuranic waste work-off plan, Los Alamos National Laboratory. Rough draft: Final report  

SciTech Connect (OSTI)

The Los Alamos National Laboratory (LANL) generates transuranic (TRU) waste in a variety of programs related to national defense. TRU waste is a specific class of radioactive waste requiring permanent isolation. Most defense-related TRU waste will be permanently disposed of in the Waste Isolation Pilot Plant (WIPP). WIPP is a deep geologic repository located in southeastern New Mexico and is now in the testing phase of development. All waste received by Wipp must conform with established Waste Acceptance Criteria (WAC). The purpose of the proposed action is to retrieve stored TRU waste and prepare the waste for shipment to and disposal WIPP. Stored TRU waste LANL is represented by four waste forms. The facilities necessary for work-off activities are tailored to the treatment and preparation of these four waste forms. Preparation activities for newly generated TRU waste are also covered by this action.

Not Available

1990-10-26T23:59:59.000Z

134

TRU (transuranic) waste certification compliance requirements for acceptance of newly generated contact-handled wastes to be shipped to the Waste Isolation Pilot Plant: Revision 2  

SciTech Connect (OSTI)

Compliance requirements are presented for certifying that unclassified, newly generated (NG), contact-handled (CH) transuranic (TRU) solid wastes from defense programs meet the Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria (WAC). Where appropriate, transportation and interim storage requirements are incorporated; however, interim storage sites may have additional requirements consistent with these requirements. All applicable Department of Energy (DOE) orders must continue to be met. The compliance requirements for stored or buried waste are not addressed in this document. The compliance requirements are divided into four sections, primarily determined by the general feature that the requirements address. These sections are General Requirements, Waste Container Requirements, Waste Form Requirements, and Waste Package Requirements. The waste package is the combination of waste container and waste. 10 refs., 1 fig.

Not Available

1989-01-01T23:59:59.000Z

135

TRU (transuranic) waste certification compliance requirements for acceptance of contact-handled wastes retrieved from storage to be shipped to the Waste Isolation Pilot Plant: Revision 2  

SciTech Connect (OSTI)

Compliance requirements are presented for certifying that unclassified, contact-handled (CH) transuranic (TRU) solid defense wastes retrieved from storage at DOE sites meet the Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria (WAC). All applicable Department of Energy (DOE) orders must continue to be met. The compliance requirements for acceptance of newly generated CH waste to be shipped to the WIPP are addressed in another document. The compliance requirements are divided into four sections, primarily determined by the general feature that the requirements address. These sections are General Requirements, Waste Container Requirements, Waste Form Requirements, and Waste Package Requirements. The waste package is the combination of waste container and waste. 10 refs., 1 fig.

Not Available

1989-01-01T23:59:59.000Z

136

Shipping Remote Handled Transuranic Waste to the Waste Isolation Pilot Plant - An Operational Experience  

SciTech Connect (OSTI)

On January 18, 2007, the first ever shipment of Remote Handled Transuranic (RH TRU) waste left the gate at the Idaho National Laboratory (INL), headed toward the Waste Isolation Pilot Plant (WIPP) for disposal, thus concluding one of the most stressful, yet rewarding, periods the authors have ever experienced. The race began in earnest on October 16, 2006, with signature of the New Mexico Environment Department Secretary's Final Order, ruling that the '..draft permit as changed is hereby approved in its entirety.' This established the effective date of the approved permit as November 16, 2006. The permit modification was a consolidation of several Class 3 modification requests, one of which included incorporation of RH TRU requirements and another of which incorporated the requirements of Section 311 of Public Law 108-137. The obvious goal was to complete the first shipment by November 17. While many had anticipated its approval, the time had finally come to actually implement, and time seemed to be the main item lacking. At that point, even the most aggressive schedule that could be seriously documented showed a first ship date in March 2007. Even though planning for this eventuality had started in May 2005 with the arrival of the current Idaho Cleanup Project (ICP) contractor (and even before that), there were many facility and system modifications to complete, startup authorizations to fulfill, and many regulatory audits and approvals to obtain before the first drum could be loaded. Through the dedicated efforts of the ICP workers, the partnership with Department of Energy (DOE) - Idaho, the coordinated integration with the Central Characterization Project (CCP), the flexibility and understanding of the regulatory community, and the added encouragement of DOE - Carlsbad Field Office and at Headquarters, the first RH TRU canister was loaded on December 22, 2006. Following final regulatory approval on January 17, 2007, the historic event finally occurred the following day. While some of the success of this endeavor can be attributed to the sheer will and determination of the individuals involved, the fact that it was established and managed as a separate sub-project under the ICP, accounts for a majority of the success. Utilizing a structured project management approach, including development of, and management to, a performance baseline, allowed for timely decision making and the flexibility to adapt to changing conditions as the various aspects of the project matured. This paper provides some insight into how this was achieved, in a relatively short time, and provides an overview of the experience of start-up of a new retrieval, characterization, loading, and transportation operation in the midst of an aggressive cleanup project. Additionally, as one might expect, everything within the project did not go as planned, which provides a great opportunity to discuss some lessons learned. Finally, the first shipment was just the beginning. There are 224 additional shipments scheduled. In keeping with the theme of WM 2008, Phoenix Rising: Moving Forward in Waste Management, this paper will address the future opportunities and challenges of RH TRU waste management at the INL. (authors)

Anderson, S.; Bradford, J.; Clements, T.; Crisp, D.; Sherick, M. [CH2M-WG Idaho, Idaho Falls, ID (United States); D'Amico, E. [Washington TRU Solutions, Denver, CO (United States); Lattin, W. [United States Department of Energy, Idaho Operations Office, Idaho Falls, ID (United States); Watson, K. [United States Department of Energy, Carlsbad Field Office, Carlsbad, NM (United States)

2008-07-01T23:59:59.000Z

137

A brief analysis and description of transuranic wastes in the Subsurface Disposal Area of the radioactive waste management complex at INEL  

SciTech Connect (OSTI)

This document presents a brief summary of the wastes and waste types disposed of in the transuranic contaminated portions of the Subsurface Disposal Area of the radioactive waste management complex at Idaho National Engineering Laboratory from 1954 through 1970. Wastes included in this summary are organics, inorganics, metals, radionuclides, and atypical wastes. In addition to summarizing amounts of wastes disposed and describing the wastes, the document also provides information on disposal pit and trench dimensions and contaminated soil volumes. The report also points out discrepancies that exist in available documentation regarding waste and soil volumes and make recommendations for future efforts at waste characterization. 19 refs., 3 figs., 17 tabs.

Arrenholz, D.A.; Knight, J.L.

1991-08-01T23:59:59.000Z

138

Key regulatory drivers affecting shipments of mixed transuranic waste from Los Alamos National Laboratory to the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

A number of key regulatory drivers affect the nature, scope, and timing of Los Alamos National Laboratory`s (LANL`s) plans for mixed transuranic (MTRU) waste shipments to the Waste Isolation Pilot Plant (WIPP), which are planned to commence as soon as possible following WIPP`s currently anticipated November, 1997 opening date. This paper provides an overview of some of the key drivers at LANL, particularly emphasizing those associated with the hazardous waste component of LANL`s MTRU waste (MTRU, like any mixed waste, contains both a radioactive and a hazardous waste component). The key drivers discussed here derive from the federal Resource Conservation and Recovery Act (RCRA) and its amendments, including the Federal Facility Compliance Act (FFCAU), and from the New Mexico Hazardous Waste Act (NMHWA). These statutory provisions are enforced through three major mechanisms: facility RCRA permits; the New Mexico Hazardous Waste Management Regulations, set forth in the New Mexico Administrative Code, Title 20, Chapter 4, Part 1: and compliance orders issued to enforce these requirements. General requirements in all three categories will apply to MTRU waste management and characterization activities at both WIPP and LANL. In addition, LANL is subject to facility-specific requirements in its RCRA hazardous waste facility permit, permit conditions as currently proposed in RCRA Part B permit applications presently being reviewed by the New Mexico Environment Department (NNED), and facility-specific compliance orders related to MTRU waste management. Likewise, permitting and compliance-related requirements specific to WIPP indirectly affect LANL`s characterization, packaging, record-keeping, and transportation requirements for MTRU waste. LANL must comply with this evolving set of regulatory requirements to begin shipments of MTRU waste to WIPP in a timely fashion.

Schumann, P.B.; Bacigalupa, G.A.; Kosiewicz, S.T.; Sinkule, B.J. [and others

1997-02-01T23:59:59.000Z

139

Apparatus and method for quantitative assay of generic transuranic wastes from nuclear reactors  

DOE Patents [OSTI]

A combination of passive and active neutron measurements which yields quantitative information about the isotopic composition of transuranic wastes from nuclear power or weapons material manufacture reactors is described. From the measurement of prompt and delayed neutron emission and the incidence of two coincidentally emitted neutrons from induced fission of fissile material in the sample, one can quantify /sup 233/U, /sup 235/U and /sup 239/Pu isotopes in waste samples. Passive coincidence counting, including neutron multiplicity measurement and determination of the overall passive neutron flux additionally enables the separate quantitative evaluation of spontaneous fission isotopes such as /sup 240/Pu, /sup 244/Cm and /sup 252/Cf, and the spontaneous alpha particle emitter /sup 241/Am. These seven isotopes are the most important constituents of wastes from nuclear power reactors and once the mass of each isotope present is determined by the apparatus and method of the instant invention, the overall alpha particle activity can be determined to better than 1 nCi/g from known radioactivity data. Therefore, in addition to the quantitative analysis of the waste sample useful for later reclamation purposes, the alpha particle activity can be determined to decide whether permanent low-level burial is appropriate for the waste sample.

Caldwell, J.T.; Kunz, W.E.; Atencio, J.D.

1982-03-31T23:59:59.000Z

140

Apparatus and method for quantitative assay of generic transuranic wastes from nuclear reactors  

DOE Patents [OSTI]

A combination of passive and active neutron measurements which yields quantitative information about the isotopic composition of transuranic wastes from nuclear power or weapons material manufacture reactors is described. From the measurement of prompt and delayed neutron emission and the incidence of two coincidentally emitted neutrons from induced fission of fissile material in the sample, one can quantify .sup.233 U, .sup.235 U and .sup.239 Pu isotopes in waste samples. Passive coincidence counting, including neutron multiplicity measurement and determination of the overall passive neutron flux additionally enables the separate quantitative evaluation of spontaneous fission isotopes such as .sup.240 Pu, .sup.244 Cm and .sup.252 Cf, and the spontaneous alpha particle emitter .sup.241 Am. These seven isotopes are the most important constituents of wastes from nuclear power reactors and once the mass of each isotope present is determined by the apparatus and method of the instant invention, the overall alpha particle activity can be determined to better than 1 nCi/g from known radioactivity data. Therefore, in addition to the quantitative analysis of the waste sample useful for later reclamation purposes, the alpha particle activity can be determined to decide whether "permanent" low-level burial is appropriate for the waste sample.

Caldwell, John T. (Los Alamos, NM); Kunz, Walter E. (Santa Fe, NM); Atencio, James D. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

WIPP TRANSURANIC WASTE How has the WIPP TRU Waste Inventory Changed  

E-Print Network [OSTI]

of tank waste from the Hanford site that is currently managed as high-level waste. None of this waste has that these Hanford tank wastes will be treated and will eventually be able to meet the WIPP waste acceptance criteria on the Hanford Tank Waste and K-Basin Sludges that were included in the waste inventory for recertifica- tion

142

Mobile/Modular Deployment Project-Enhancing Efficiencies within the National Transuranic Waste Program.  

SciTech Connect (OSTI)

In 1999, the National Transuranic (TRU) Waste Program (NTP) achieved two significant milestones. First, the Waste Isolation Plant (WIPP) opened in March for the permanent disposal of TRU waste generated by, and temporarily stored at, various sites supporting the nation's defense programs. Second, the Hazardous Waste Facility Permit, issued by the New Mexico Environment Department, for WIPP became effective in November. While the opening of WIPP brought to closure a number of scientific, engineering, regulatory, and political challenges, achieving this major milestone led to a new set of challenges-how to achieve the Department of Energy's (DOE's) NTP end-state vision: All TRU waste from DOE sites scheduled for closure is removed All legacy TRU waste from DOE sites with an ongoing nuclear mission is disposed 0 All newly generated TRU waste is disposed as it is generated The goal is to operate the national TRU waste program safely, cost effectively, in compliance with applicable regulations and agreements, and at full capacity in a fully integrated mode. The existing schedule for TRU waste disposition would achieve the NTP vision in 2034 at an estimated life-cycle cost of $16B. The DOE's Carlsbad Field Office (CBFO) seeks to achieve this vision early-by at least 10 years- while saving the nation an estimated $48 to $6B. CBFO's approach is to optimize, or to make as functional as possible, TRU waste disposition. That is, to remove barriers that impede waste disposition, and increase the rate and cost efficiency of waste disposal at WIPP, while maintaining safety. The Mobile/Modular Deployment Project (MMDP) is the principal vehicle for implementing DOE's new commercial model of using best business practices of national authorization basis, standardization, and economies of scale to accelerate the completion of WIPP's mission. The MMDP is one of the cornerstones of the National TRU Waste System Optimization Project (1). The objective of the MMDP is to increase TRU waste shipment and disposal rates from currently certified sites as well as to provide a means to remove TRU waste from sites that have no characterization capability.

Triay, I. R. (Ines R.); Basabilvazo, G. B. (George B.); Countiss, S. (Sue); Moody, D. C. (David C.); Behrens, R. G. (Robert G.); Lott, S. A. (Sheila A.)

2002-01-01T23:59:59.000Z

143

Waste Isolation Pilot Plant Transuranic Waste Baseline inventory report. Volume 3. Revision 1  

SciTech Connect (OSTI)

This report consists of information related to the waste forms at the WIPP facility from the waste originators. Data for retrievably stored, projected and total wastes are given.

NONE

1995-02-01T23:59:59.000Z

144

Waste processing air cleaning  

SciTech Connect (OSTI)

Waste processing and preparing waste to support waste processing relies heavily on ventilation. Ventilation is used at the Hanford Site on the waste storage tanks to provide confinement, cooling, and removal of flammable gases.

Kriskovich, J.R.

1998-07-27T23:59:59.000Z

145

Automation of ORIGEN2 calculations for the transuranic waste baseline inventory database using a pre-processor and a post-processor  

SciTech Connect (OSTI)

The purpose of the work described in this report was to automate ORIGEN2 calculations for the Waste Isolation Pilot Plant (WIPP) Transuranic Waste Baseline Inventory Database (WTWBID); this was done by developing a pre-processor to generate ORIGEN2 input files from WWBID inventory files and a post-processor to remove excess information from the ORIGEN2 output files. The calculations performed with ORIGEN2 estimate the radioactive decay and buildup of various radionuclides in the waste streams identified in the WTWBID. The resulting radionuclide inventories are needed for performance assessment calculations for the WIPP site. The work resulted in the development of PreORG, which requires interaction with the user to generate ORIGEN2 input files on a site-by-site basis, and PostORG, which processes ORIGEN2 output into more manageable files. Both programs are written in the FORTRAN 77 computer language. After running PreORG, the user will run ORIGEN2 to generate the desired data; upon completion of ORIGEN2 calculations, the user can run PostORG to process the output to make it more manageable. All the programs run on a 386 PC or higher with a math co-processor or a computer platform running under VMS operating system. The pre- and post-processors for ORIGEN2 were generated for use with Rev. 1 data of the WTWBID and can also be used with Rev. 2 and 3 data of the TWBID (Transuranic Waste Baseline Inventory Database).

Liscum-Powell, J. [Sandia National Labs., Albuquerque, NM (United States). Nuclear Safety and Systems Analysis

1997-06-01T23:59:59.000Z

146

Environmental impact statement for initiation of transuranic waste disposal at the waste isolation pilot plant  

SciTech Connect (OSTI)

WIPP`s long-standing mission is to demonstrate the safe disposal of TRU waste from US defense activities. In 1980, to comply with NEPA, US DOE completed its first environmental impact statement (EIS) which compared impacts of alternatives for TRU waste disposal. Based on this 1980 analysis, DOE decided to construct WIPP in 1981. In a 1990 decision based on examination of alternatives in a 1990 Supplemental EIS, DOE decided to continue WIPP development by proceeding with a testing program to examine WIPP`s suitability as a TRU waste repository. Now, as DOE`s Carlsbad Area Office (CAO) attempts to complete its regulatory obligations to begin WIPP disposal operations, CAO is developing WIPP`s second supplemental EIS (SEIS-II). To complete the SEIS-II, CAO will have to meet a number of challenges. This paper explores both the past and present EISs prepared to evaluate the suitability of WIPP. The challenges in completing an objective comparison of alternatives, while also finalizing other critical-path compliance documents, controlling costs, and keeping stakeholders involved during the decision-making process are addressed.

Johnson, H.E. [U.S. Dept. of Energy, Carlsbad, NM (United States) Carlsbad Area Office; Whatley, M.E. [Westinghouse Electric Corp., Carlsbad, NM (United States). Waste Isolation Div.

1996-08-01T23:59:59.000Z

147

Salt Waste Processing Initiatives  

Office of Environmental Management (EM)

1 Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives...

148

Development of the remote-handled transuranic waste radioassay data quality objectives. An evaluation of RH-TRU waste inventories, characteristics, radioassay methods and capabilities  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant will accept remote-handled transuranic waste as early as October of 2001. Several tasks must be accomplished to meet this schedule, one of which is the development of Data Quality Objectives (DQOs) and corresponding Quality Assurance Objectives (QAOs) for the assay of radioisotopes in RH-TRU waste. Oak Ridge National Laboratory (ORNL) was assigned the task of providing to the DOE QAO, information necessary to aide in the development of DQOs for the radioassay of RH-TRU waste. Consistent with the DQO process, information needed and presented in this report includes: identification of RH-TRU generator site radionuclide data that may have potential significance to the performance of the WIPP repository or transportation requirements; evaluation of existing methods to measure the identified isotopic and quantitative radionuclide data; evaluation of existing data as a function of site waste streams using documented site information on fuel burnup, radioisotope processing and reprocessing, special research and development activities, measurement collection efforts, and acceptable knowledge; and the current status of technologies and capabilities at site facilities for the identification and assay of radionuclides in RH-TRU waste streams. This report is intended to provide guidance in developing the RH-TRU waste radioassay DQOs, first by establishing a baseline from which to work, second, by identifying needs to fill in the gaps between what is known and achievable today and that which will be required before DQOs can be formulated, and third, by recommending measures that should be taken to assure that the DQOs in fact balance risk and cost with an achievable degree of certainty.

Meeks, A.M.; Chapman, J.A.

1997-09-01T23:59:59.000Z

149

Preservation of artifacts in salt mines as a natural analog for the storage of transuranic wastes at the WIPP repository  

SciTech Connect (OSTI)

Use of nature`s laboratory for scientific analysis of complex systems is a largely untapped resource for understanding long-term disposal of hazardous materials. The Waste Isolation Pilot Plant (WIPP) in the US is a facility designed and approved for storage of transuranic waste in a salt medium. Isolation from the biosphere must be ensured for 10,000 years. Natural analogs provide a means to interpret the evolution of the underground disposal setting. Investigations of ancient sites where manmade materials have experienced mechanical and chemical processes over millennia provide scientific information unattainable by conventional laboratory methods. This paper presents examples of these pertinent natural analogs, provides examples of features relating to the WIPP application, and identifies potential avenues of future investigations. This paper cites examples of analogical information pertaining to the Hallstatt salt mine in Austria and Wieliczka salt mine in Poland. This paper intends to develop an appreciation for the applicability of natural analogs to the science and engineering of a long-term disposal facility in geomedia.

Martell, M.A.; Hansen, F.; Weiner, R.

1998-10-01T23:59:59.000Z

150

Remote-handled transuranic system assessment appendices. Volume 2  

SciTech Connect (OSTI)

Volume 2 of this report contains six appendices to the report: Inventory and generation of remote-handled transuranic waste; Remote-handled transuranic waste site storage; Characterization of remote-handled transuranic waste; RH-TRU waste treatment alternatives system analysis; Packaging and transportation study; and Remote-handled transuranic waste disposal alternatives.

NONE

1995-11-01T23:59:59.000Z

151

Transuranic (TRU) Waste Processing Center - Cask Processing Enclosure |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2Topo II:LIGHT-DUTYTransportation SafeguardsEHSS

152

Review of the WIPP draft application to show compliance with EPA transuranic waste disposal standards  

SciTech Connect (OSTI)

The purpose of the New Mexico Environmental Evaluation Group (EEG) is to conduct an independent technical evaluation of the Waste Isolation Pilot Plant (WIPP) Project to ensure the protection of the public health and safety and the environment. The WIPP Project, located in southeastern New Mexico, is being constructed as a repository for the disposal of transuranic (TRU) radioactive wastes generated by the national defense programs. The EEG was established in 1978 with funds provided by the U.S. Department of Energy (DOE) to the State of New Mexico. Public Law 100-456, the National Defense Authorization Act, Fiscal Year 1989, Section 1433, assigned EEG to the New Mexico Institute of Mining and Technology and continued the original contract DE-AC04-79AL10752 through DOE contract DE-AC04-89AL58309. The National Defense Authorization Act for Fiscal Year 1994, Public Law 103-160, continues the authorization. EEG performs independent technical analyses of the suitability of the proposed site; the design of the repository, its planned operation, and its long-term integrity; suitability and safety of the transportation systems; suitability of the Waste Acceptance Criteria and the generator sites` compliance with them; and related subjects. These analyses include assessments of reports issued by the DOE and its contractors, other federal agencies and organizations, as they relate to the potential health, safety and environmental impacts from WIPP. Another important function of EEG is the independent environmental monitoring of background radioactivity in air, water, and soil, both on-site and off-site.

Neill, R.H.; Chaturvedi, L.; Clemo, T.M. [and others

1996-03-01T23:59:59.000Z

153

EVALUATION OF RISKS AND WASTE CHARACTERIZATION REQUIREMENTS FOR THE TRANSURANIC WASTE EMPLACED IN WIPP DURING 1999  

SciTech Connect (OSTI)

Specifically this report: 1. Compares requirements of the WAP that are pertinent from a technical viewpoint with the WIPP pre-Permit waste characterization program, 2. Presents the results of a risk analysis of the currently emplaced wastes. Expected and bounding risks from routine operations and possible accidents are evaluated; and 3. Provides conclusions and recommendations.

Channell, J.K.; Walker, B.A.

2000-05-01T23:59:59.000Z

154

Application of Fully Ceramic Microencapsulated Fuel for Transuranic Waste Recycling in PWRs  

SciTech Connect (OSTI)

Presented is an investigation of the utilization of Tristructural-Isotropic (TRISO) particle-based fuel designs for the recycling of transuranic (TRU) wastes in typical Westinghouse four-loop pressurized water reactors (PWRs). Though numerous studies have evaluated the recycling of TRU in light water reactors (LWRs), this work differentiates itself by employing TRU-loaded TRISO particles embedded within a SiC matrix and formed into pellets that can be loaded into standard 17 x 17 fuel element cladding. This approach provides the capability of TRU recycling and, by virtue of the TRISO particle design, will allow for greater burnup (i.e., removal of the need for UO2 mixing) and improved fuel reliability. In this study, a variety of assembly layouts and core loading patterns were analyzed to demonstrate the feasibility of TRU-loaded TRISO fuel. The assembly and core design herein reported are a work in progress, so they still require some fine-tuning to further flatten power peaks; however, the progress achieved thus far strongly supports the conclusion that with further rod/assembly/core loading and placement optimization, TRU-loaded TRISO fuel and core designs that are capable of balancing TRU production and destruction can be designed within the standard constraints for thermal and reactivity performance in PWRs.

Gentry, Cole A [ORNL; Maldonado, G Ivan [ORNL; Terrani, Kurt A [ORNL; Gehin, Jess C [ORNL; Godfrey, Andrew T [ORNL

2012-01-01T23:59:59.000Z

155

Analyzing Losses: Transuranics into Waste and Fission Products into Recycled Fuel  

SciTech Connect (OSTI)

All mass streams from separations and fuel fabrication are products that must meet criteria. Those headed for disposal must meet waste acceptance criteria (WAC) for the eventual disposal sites corresponding to their waste classification. Those headed for reuse must meet fuel or target impurity limits. A “loss” is any material that ends up where it is undesired. The various types of losses are linked in the sense that as the loss of transuranic (TRU) material into waste is reduced, often the loss or carryover of waste into TRU or uranium is increased. We have analyzed four separation options and two fuel fabrication options in a generic fuel cycle. The separation options are aqueous uranium extraction plus (UREX+1), electrochemical, Atomics International reduction oxidation separation (AIROX), and melt refining. UREX+1 and electrochemical are traditional, full separation techniques. AIROX and melt refining are taken as examples of limited separations, also known as minimum fuel treatment. The fuels are oxide and metal. To define a generic fuel cycle, a fuel recycling loop is fed from used light water reactor (LWR) uranium oxide fuel (UOX) at 51 MWth-day/kg-iHM burnup. The recycling loop uses a fast reactor with TRU conversion ratio (CR) of 0.50. Excess recovered uranium is put into storage. Only waste, not used fuel, is disposed – unless the impurities accumulate to a level so that it is impossible to make new fuel for the fast reactor. Impurities accumulate as dictated by separation removal and fission product generation. Our model approximates adjustment to fast reactor fuel stream blending of TRU and U products from incoming LWR UOX and recycling FR fuel to compensate for impurity accumulation by adjusting TRU:U ratios. Our mass flow model ignores postulated fuel impurity limits; we compare the calculated impurity values with those limits to identify elements of concern. AIROX and melt refining cannot be used to separate used LWR UOX-51 because they cannot separate U from TRU, it is then impossible to make X% TRU for fast reactors with UOX-51 used fuel with 1.3% TRU. AIROX and melt refining can serve in the recycle loop for about 3 recycles, at which point the accumulated impurities displace fertile uranium and the fuel can no longer be as critical as the original fast reactor fuel recipe. UREX+1 and electrochemical can serve in either capacity; key impurities appear to be lanthanides and several transition metals.

Steven J. Piet; Nick R. Soelberg; Samuel E. Bays; Robert E. Cherry; Layne F. Pincock; Eric L. Shaber; Melissa C. Teague; Gregory M. Teske; Kurt G. Vedros; Candido Pereira; Denia Djokic

2010-11-01T23:59:59.000Z

156

Idaho Nuclear Technology and Engineering Center Low-Activity Waste Process Technology Program FY-2000 Status Report  

SciTech Connect (OSTI)

The Low-Activity Waste Process Technology Program anticipated that grouting will be used for disposal of low-level and transuranic wastes generated at the Idaho Nuclear Technology Engineering Center (INTEC). During fiscal year 2000, grout formulations were studied for transuranic waste derived from INTEC liquid sodium-bearing waste and for projected newly generated low-level liquid waste. Additional studies were completed using silica gel and other absorbents to solidify sodium-bearing wastes. A feasibility study and conceptual design were completed for the construction of a grout pilot plant for simulated wastes and demonstration facility for actual wastes.

Herbst, Alan Keith; Mc Cray, John Alan; Kirkham, Robert John; Pao, Jenn Hai; Argyle, Mark Don; Lauerhass, Lance; Bendixsen, Carl Lee; Hinckley, Steve Harold

2000-11-01T23:59:59.000Z

157

Idaho Nuclear Technology and Engineering Center Low-Activity Waste Process Technology Program FY-2000 Status Report  

SciTech Connect (OSTI)

The Low-Activity Waste Process Technology Program anticipated that grouting will be used for disposal of low-level and transuranic wastes generated at the Idaho Nuclear Technology Engineering Center (INTEC). During fiscal year 2000, grout formulations were studied for transuranic waste derived from INTEC liquid sodium-bearing waste and for projected newly generated low-level liquid waste. Additional studies were completed using silica gel and other absorbents to solidify sodium-bearing wastes. A feasibility study and conceptual design were completed for the construction of a grout pilot plant for simulated wastes and demonstration facility for actual wastes.

Herbst, A.K.; McCray, J.A.; Kirkham, R.J.; Pao, J.; Argyle, M.D.; Lauerhass, L.; Bendixsen, C.L.; Hinckley, S.H.

2000-10-31T23:59:59.000Z

158

HANFORD SITE RIVER PROTECTION PROJECT (RPP) TRANSURANIC (TRU) TANK WASTE IDENTIFICATION & PLANNING FOR REVRIEVAL TREATMENT & EVENTUAL DISPOSAL AT WIPP  

SciTech Connect (OSTI)

The CH2M HILL Manford Group, Inc. (CHG) conducts business to achieve the goals of the Office of River Protection (ORP) at Hanford. As an employee owned company, CHG employees have a strong motivation to develop innovative solutions to enhance project and company performance while ensuring protection of human health and the environment. CHG is responsible to manage and perform work required to safely store, enhance readiness for waste feed delivery, and prepare for treated waste receipts for the approximately 53 million gallons of legacy mixed radioactive waste currently at the Hanford Site tank farms. Safety and environmental awareness is integrated into all activities and work is accomplished in a manner that achieves high levels of quality while protecting the environment and the safety and health of workers and the public. This paper focuses on the innovative strategy to identify, retrieve, treat, and dispose of Hanford Transuranic (TRU) tank waste at the Waste Isolation Pilot Plant (WIPP).

KRISTOFZSKI, J.G.; TEDESCHI, R.; JOHNSON, M.E.; JENNINGS, M

2006-01-18T23:59:59.000Z

159

Assessment of degradation concerns for spent fuel, high-level wastes, and transuranic wastes in monitored retrievalbe storage  

SciTech Connect (OSTI)

It has been concluded that there are no significant degradation mechanisms that could prevent the design, construction, and safe operation of monitored retrievable storage (MRS) facilities. However, there are some long-term degradation mechanisms that could affect the ability to maintain or readily retrieve spent fuel (SF), high-level wastes (HLW), and transuranic wastes (TRUW) several decades after emplacement. Although catastrophic failures are not anticipated, long-term degradation mechanisms have been identified that could, under certain conditions, cause failure of the SF cladding and/or failure of TRUW storage containers. Stress rupture limits for Zircaloy-clad SF in MRS range from 300 to 440/sup 0/C, based on limited data. Additional tests on irradiated Zircaloy (3- to 5-year duration) are needed to narrow this uncertainty. Cladding defect sizes could increase in air as a result of fuel density decreases due to oxidation. Oxidation tests (3- to 5-year duration) on SF are also needed to verify oxidation rates in air and to determine temperatures below which monitoring of an inert cover gas would not be required. Few, if any, changes in the physical state of HLW glass or canisters or their performance would occur under projected MRS conditions. The major uncertainty for HLW is in the heat transfer through cracked glass and glass devitrification above 500/sup 0/C. Additional study of TRUW is required. Some fraction of present TRUW containers would probably fail within the first 100 years of MRS, and some TRUW would be highly degraded upon retrieval, even in unfailed containers. One possible solution is the design of a 100-year container. 93 references, 28 figures, 17 tables.

Guenther, R.J.; Gilbert, E.R.; Slate, S.C.; Partain, W.L.; Divine, J.R.; Kreid, D.K.

1984-01-01T23:59:59.000Z

160

Apparatus and method for quantitative assay of samples of transuranic waste contained in barrels in the presence of matrix material  

DOE Patents [OSTI]

Apparatus and method for performing corrections for matrix material effects on the neutron measurements generated from analysis of transuranic waste drums using the differential-dieaway technique. By measuring the absorption index and the moderator index for a particular drum, correction factors can be determined for the effects of matrix materials on the ''observed'' quantity of fissile and fertile material present therein in order to determine the actual assays thereof. A barrel flux monitor is introduced into the measurement chamber to accomplish these measurements as a new contribution to the differential-dieaway technology. 9 figs.

Caldwell, J.T.; Herrera, G.C.; Hastings, R.D.; Shunk, E.R.; Kunz, W.E.

1987-08-28T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

High-level and transuranic radioactive wastes: Background information document for amendments to 40 CFR part 191  

SciTech Connect (OSTI)

The report provides the necessary background information technical analyses, and justifications in support of the proposed amendments to 40 CFR Part 191. The scope of the report encompasses the conceptual framework for assessing radiation exposures and associated health risks. In general terms, this assessment examines the radioactive source term characterization, analysis of the movement of radionuclides from the repository through the appropriate environmental exposure pathways and doses received by members of the general public. The report used transuranic waste for individual dose and ground-water protection analysis.

Not Available

1993-11-01T23:59:59.000Z

162

Transuranic Waste Burning Potential of Thorium Fuel in a Fast Reactor - 12423  

SciTech Connect (OSTI)

Westinghouse Electric Company (referred to as 'Westinghouse' in the rest of this paper) is proposing a 'back-to-front' approach to overcome the stalemate on nuclear waste management in the US. In this approach, requirements to further the societal acceptance of nuclear waste are such that the ultimate health hazard resulting from the waste package is 'as low as reasonably achievable'. Societal acceptability of nuclear waste can be enhanced by reducing the long-term radiotoxicity of the waste, which is currently driven primarily by the protracted radiotoxicity of the transuranic (TRU) isotopes. Therefore, a transition to a more benign radioactive waste can be accomplished by a fuel cycle capable of consuming the stockpile of TRU 'legacy' waste contained in the LWR Used Nuclear Fuel (UNF) while generating waste which is significantly less radio-toxic than that produced by the current open U-based fuel cycle (once through and variations thereof). Investigation of a fast reactor (FR) operating on a thorium-based fuel cycle, as opposed to the traditional uranium-based is performed. Due to a combination between its neutronic properties and its low position in the actinide chain, thorium not only burns the legacy TRU waste, but it does so with a minimal production of 'new' TRUs. The effectiveness of a thorium-based fast reactor to burn legacy TRU and its flexibility to incorporate various fuels and recycle schemes according to the evolving needs of the transmutation scenario have been investigated. Specifically, the potential for a high TRU burning rate, high U-233 generation rate if so desired and low concurrent production of TRU have been used as metrics for the examined cycles. Core physics simulations of a fast reactor core running on thorium-based fuels and burning an external TRU feed supply have been carried out over multiple cycles of irradiation, separation and reprocessing. The TRU burning capability as well as the core isotopic content have been characterized. Results will be presented showing the potential for thorium to reach a high TRU transmutation rate over a wide variety of fuel types (oxide, metal, nitride and carbide) and transmutation schemes (recycle or partition of in-bred U-233). In addition, a sustainable scheme has been devised to burn the TRU accumulated in the core inventory once the legacy TRU supply has been exhausted, thereby achieving long-term virtually TRU-free. A comprehensive 'back-to-front' approach to the fuel cycle has recently been proposed by Westinghouse which emphasizes achieving 'acceptable', low-radiotoxicity, high-level waste, with the intent not only to satisfy all technical constraints but also to improve public acceptance of nuclear energy. Following this approach, the thorium fuel cycle, due to its low radiotoxicity and high potential for TRU transmutation has been selected as a promising solution. Additional studies not shown here have shown significant reduction of decay heat. The TRU burning potential of the Th-based fuel cycle has been illustrated with a variety of fuel types, using the Toshiba ARR to perform the analysis, including scenarios with continued LWR operation of either uranium fueled or thorium fueled LWRs. These scenarios will afford overall reduction in actinide radiotoxicity, however when the TRU supply is exhausted, a continued U- 235 LWR operation must be assumed to provide TRU makeup feed. This scenario will never reach the characteristically low TRU content of a closed thorium fuel cycle with its associated potential benefits on waste radiotoxicity, as exemplified by the transition scenario studied. At present, the cases studied indicate ThC as a potential fuel for maximizing TRU burning, while ThN with nitrogen enriched to 95% N-15 shows the highest breeding potential. As a result, a transition scenario with ThN was developed to show that a sustainable, closed Th-cycle can be achieved starting from burning the legacy TRU stock and completing the transmutation of the residual TRU remaining in the core inventory after the legacy TRU external supply has been

Wenner, Michael; Franceschini, Fausto; Ferroni, Paolo [Westinghouse Electric Company LLC,Cranberry Township, PA, 16066 (United States); Sartori, Alberto; Ricotti, Marco [Politecnico di Milano, Milan (Italy)

2012-07-01T23:59:59.000Z

163

Total Measurement Uncertainty (TMU) for Nondestructive Assay of Transuranic (TRU) Waste at the WRAP Facility  

SciTech Connect (OSTI)

At the WRAP facility, there are two identical imaging passive/active neutron (IPAN) assay systems and two identical gamma energy assay (GEA) systems. Currently, only the GEA systems are used to characterize waste, therefore, only the GEA systems are addressed in this document. This document contains the limiting factors relating to the waste drum analysis for shipments destined for WIPP. The TMU document provides the uncertainty basis in the NDA analysis of waste containers at the WRAP facility. The defined limitations for the current analysis scheme are as follows: (1) The WRAP waste stream debris is from the Hanford Plutonium Finishing Plant's process lines, primarily combustible materials. (2) Plutonium analysis range is from the minimum detectable concentration (MDC), Reference 6, to 200 grams (g). (3) The GEA system calibration density ranges from 0.013 g/cc to 1.6 g/cc. (4) PDP Plutonium drum densities were evaluated from 0.065 g/cc to 0.305 g/cc. (5) PDP Plutonium source weights ranged from 0.030 g to 318 g, in both empty and combustibles matrix drums. (6) The GEA system design density correction mass absorption coefficient table (MAC) is Lucite, a material representative of combustible waste. (7) Drums with material not fitting the debris waste criteria are targeted for additional calculations, reviews, and potential re-analysis using a calibration suited for the waste type.

CANTALOUB, M.G.

2000-10-20T23:59:59.000Z

164

Total Measurement Uncertainty (TMU) for Nondestructive Assay of Transuranic (TRU) Waste at the WRAP Facility  

SciTech Connect (OSTI)

At the WRAP facility, there are two identical imaging passive/active neutron (IPAN) assay systems and two identical gamma energy assay (GEA) systems. Currently, only the GEA systems are used to characterize waste, therefore, only the GEA systems are addressed in this document. This document contains the limiting factors relating to the waste drum analysis for shipments destined for WIPP. The TMU document provides the uncertainty basis in the NDA analysis of waste containers at the WRAP facility. The defined limitations for the current analysis scheme are as follows: The WRAP waste stream debris is from the Hanford Plutonium Finishing Plant's process lines, primarily combustible materials. Plutonium analysis range is from the minimum detectable concentration (MDC), Reference 6, to 160 grams (8). The GEA system calibration density ranges from 0.013 g/cc to 1.6 g/cc. PDP Plutonium drum densities were evaluated from 0.065 g/cc to 0.305 gkc. PDP Plutonium source weights ranged from 0.030 g to 3 18 g, in both empty and combustibles matrix drums. The GEA system design density correction macroscopic absorption cross section table (MAC) is Lucite, a material representative of combustible waste. Drums with material not fitting the debris waste criteria are targeted for additional calculations, reviews, and potential re-analysis using a calibration suited for the waste type.

CANTALOUB, M.G.

2000-05-22T23:59:59.000Z

165

Solid Waste Processing Center Primary Opening Cells Systems, Equipment and Tools  

SciTech Connect (OSTI)

This document addresses the remote systems and design integration aspects of the development of the Solid Waste Processing Center (SWPC), a facility to remotely open, sort, size reduce, and repackage mixed low-level waste (MLLW) and transuranic (TRU)/TRU mixed waste that is either contact-handled (CH) waste in large containers or remote-handled (RH) waste in various-sized packages.

Bailey, Sharon A.; Baker, Carl P.; Mullen, O Dennis; Valdez, Patrick LJ

2006-04-17T23:59:59.000Z

166

Transuranic radionuclides in the environment surrounding radioactive waste diposal sites, a bibliography  

SciTech Connect (OSTI)

The purpose of this project was to compile a bibliography of references containing environmental transuranic radionuclide data. Our intent was to identify those parameters affecting transuranic radionuclide transport that may be generic and those that may be dependent on chemical form and/or environmental conditions (i.e. site specific). An understanding of the unique characteristics and similarities between source terms and environmental conditions relative to transuranic radionuclide transport and cycling will provide the ability to assess and predict the long term impact on man and the environment. An additional goal of our literature review, was to extract the ranges of environmental transuranic radionuclide data from the identified references for inclusion in a data base. Related to source term, these ranges of data can be used to calculate the dose to man from the radionuclides, and to perform uncertainty analyses on these dose assessments. In an attempt to gather relevant information about the transuranic radionuclides in a variety of environments, we conducted an extensive literature search. In our literature search we identified over 5700 potential written sources of information for review. In addition, we have identified many references which were not found through the literature searches, but which were known to contain useful data. A total of approximately 2600 documents were determined to contain information which would be useful for an in depth study of radionuclides in different environments. The journal articles, books, reports and other documents were reviewed to obtain the source term of the radionuclides studied. Most references containing laboratory study data were not included in our databases. Although these may contain valuable data, we were trying to compile references with information on the behavior of the transuranics in the specific environment being studied.

Stoker, A.C.; Noshkin, V.E.; Wong, K.M.; Brunk, J.L.; Conrado, C.L.; Jones, H.E.; Kehl, S.; Stuart, M.L.; Wasley, L.M.; Bradsher, R.V. [and others

1994-08-01T23:59:59.000Z

167

Municipal waste processing apparatus  

DOE Patents [OSTI]

This invention relates to apparatus for processing municipal waste, and more particularly to vibrating mesh screen conveyor systems for removing grit, glass, and other noncombustible materials from dry municipal waste. Municipal waste must be properly processed and disposed of so that it does not create health risks to the community. Generally, municipal waste, which may be collected in garbage trucks, dumpsters, or the like, is deposited in processing areas such as landfills. Land and environmental controls imposed on landfill operators by governmental bodies have increased in recent years, however, making landfill disposal of solid waste materials more expensive. 6 figs.

Mayberry, J.L.

1988-04-13T23:59:59.000Z

168

Conversion of transuranic waste to low level waste by decontamination: a technical and economic evaluation  

SciTech Connect (OSTI)

A study was conducted to evaluate the technical and economic feasibility of using in-situ decontamination techniques to convert glove boxes and other large TRU-contaminated components directly into LLW. The results of the technical evaluation indicate that in-situ decontamination of these types of components to non-TRU levels is technically feasible. Applicable decontamination techniques include electropolishing, hand scrubbing, chemical washes/sprays, strippable coatings and Freon spray-cleaning. The removal of contamination from crevices and other holdup areas remains a problem, but may be solved through further advances in decontamination technology. Also, the increase in the allowable maximum TRU level from 10 nCi/g to 100 nCi/g as defined in DOE Order 5820.2 reduces the removal requirement and facilitates measurement of the remaining quantities. The major emphasis of the study was on a cost/benefit evaluation that included a review and update of previous analyses and evaluations of TRU-waste volume reduction and conversion options. The results of the economic evaluation show, for the assumptions used, that there is a definite cost incentive to size reduce large components, and that decontamination of sectioned material has become cost competitive with the size reduction options. In-situ decontamination appears to be the lowest cost option when based on routine-type operations conducted by well-trained and properly equipped personnel. 16 references, 1 figure, 7 tables.

Allen, R.P.; Hazelton, R.F.

1984-12-01T23:59:59.000Z

169

Process development for remote-handled mixed-waste treatment  

SciTech Connect (OSTI)

The Oak Ridge National Laboratory (ORNL) is developing a treatment process for remote-handled (RH) liquid transuranic mixed waste governed by the concept of minimizing the volume of waste requiring disposal. This task is to be accomplished by decontaminating the bulk components so the process effluent can be disposed with less risk and expense. Practical processes have been demonstrated on the laboratory scale for removing cesium 137 and strontium 90 isotopes from the waste, generating a concentrated waste volume, and rendering the bulk of the waste nearly radiation free for downstream processing. The process is projected to give decontamination factors of 10{sup 4} for cesium and 10{sup 3} for strontium. Because of the extent of decontamination, downstream processing will be contact handled. The transuranic, radioactive fraction of the mixed waste stream will be solidified using a thin-film evaporator and/or microwave solidification system. Resultant solidified waste will be disposed at the Waste Isolation Pilot Plant (WIPP). 8 refs., 2 figs., 3 tabs.

Berry, J.B.; Campbell, D.O.; Lee, D.D.; White, T.L.

1990-01-01T23:59:59.000Z

170

Solidification Tests Conducted on Transuranic Mixed Oil Waste (TRUM) at the Rocky Flats Environmental Technology Site (RFETS)  

SciTech Connect (OSTI)

Rocky Flats Environmental Technology Site (RFETS) near Golden, Colorado is the first major nuclear weapons site within the DOE complex that has been declared a full closure site. RFETS has been given the challenge of closing the site by 2006. Key to meeting this challenge is the removal of all waste from the site followed by site restoration. Crucial to meeting this challenge is Kaiser-Hill's (RFETS Operating Contractor) ability to dispose of significant quantities of ''orphan'' wastes. Orphan wastes are those with no current disposition for treatment or disposal. Once such waste stream, generically referred to as Transuranic oils, poses a significant threat to meeting the closure schedule. Historically, this waste stream, which consist of a variety of oil contaminated with a range of organic solvents were treated by simply mixing with Environstone. This treatment method rendered a solidified waste form, but unfortunately not a TRUPACT-II transportable waste. So for the last ten years, RFETS has been accumulating these TRU oils while searching for a non-controversial treatment option.

Brunkow, W. G.; Campbell, D.; Geimer, R.; Gilbreath, C.; Rivera, M.

2002-02-25T23:59:59.000Z

171

Using Downhole Probes to Locate and Characterize Buried Transuranic and Mixed Low Level Waste  

SciTech Connect (OSTI)

Borehole logging probes were developed and tested to locate and quantify transuranic elements in subsurface disposal areas and in contaminated sites at USDOE Weapons Complex sites. A new method of measuring very high levels of chlroine in the subsurface was developed using pulsed neutron technology from oilfield applications. The probes were demonstrated at the Hanford site in wells containing plutonium and other contaminants.

Steinman, Donald K; Bramblett, Richard L; Hertzog, Russel C

2012-06-25T23:59:59.000Z

172

CHARACTERIZATION THROUGH DATA QUALITY OBJECTIVES AND CERTIFICATION OF REMOTE-HANDLED TRANSURANIC WASTE GENERATOR/STORAGE SITES FOR SHIPMENT TO THE WIPP  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP) is operating to receive and dispose of contact-handled (CH) transuranic (TRU) waste. The Department of Energy (DOE) Carlsbad Field Office (CBFO) is seeking approval from the Environmental Protection Agency (EPA) and the New Mexico Environment Department (NMED) of the remote-handled (RH) TRU characterization plan to allow disposal of RH TRU waste in the WIPP repository. In addition, the DOE-CBFO has received approval from the Nuclear Regulatory Commission (NRC) to use two shipping casks for transporting RH TRU waste. Each regulatory agency (i.e., EPA, NMED, and NRC) has different requirements that will have to be met through the use of information collected by characterizing the RH TRU waste. Therefore, the DOE-CBFO has developed a proposed characterization program for obtaining the RH TRU waste information necessary to demonstrate that the waste meets the applicable regulatory requirements. This process involved the development of a comprehensive set of Data Quality Objectives (DQOs) comprising the various regulatory requirements. The DOE-CBFO has identified seven DQOs for use in the RH TRU waste characterization program. These DQOs are defense waste determination, TRU waste determination, RH TRU determination, activity determination, RCRA physical and chemical properties, prohibited item determination, and EPA physical and chemical properties. The selection of the DQOs were based on technical, legal and regulatory drivers that assure the health and safety of the workers, the public, to protect the environment, and to comply with the requirements of the regulatory agencies. The DOE-CBFO also has the responsibility for the certification of generator/storage sites to ship RH TRU mixed waste to the WIPP for disposal. Currently, thirteen sites across the DOE complex are generators of RH TRU waste or store the waste at their location for other generators. Generator/storage site certification involves review and approval of site-specific programmatic documents that demonstrate compliance with the WIPP waste characterization and transportation requirements. Additionally, procedures must be developed to implement programmatic requirements and adequacy of those procedures determined. Finally, on-site audits evaluate the technical and administrative implementation and effectiveness of the operating procedures.

Spangler, L.R.; Most, Wm.A.; Kehrman, R.F.; Gist, C.S.

2003-02-27T23:59:59.000Z

173

Independent Oversight Review, Oak Ridge Transuranic Waste Processing  

Broader source: Energy.gov (indexed) [DOE]

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174

Independent Oversight Review, Oak Ridge Transuranic Waste Processing  

Broader source: Energy.gov (indexed) [DOE]

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175

WAI Assumes Responsibility for DOE'S Transuranic Waste Processing Center  

Broader source: Energy.gov (indexed) [DOE]

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176

Voluntary Protection Program Onsite Review, Transuranic Waste Processing  

Office of Environmental Management (EM)

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177

Transuranic Waste Processing Center Contract Awarded to Wastren Advantage,  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of EnergyThe EnergyDepartment7 thFuel27, 2008,Inc. | Department of

178

DOE's Transuranic Waste Processing Center Surpasses 3 Million Safe Work  

Broader source: Energy.gov (indexed) [DOE]

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179

Transuranic (TRU) Waste Processing Center - Overview | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2Topo II:LIGHT-DUTYTransportation SafeguardsEHSSOverview

180

Comparative assessment of TRU waste forms and processes. Volume I. Waste form and process evaluations  

SciTech Connect (OSTI)

This study provides an assesses seven waste forms and eight processes for immobilizing transuranic (TRU) wastes. The waste forms considered are cast cement, cold-pressed cement, FUETAP (formed under elevated temperature and pressure) cement, borosilicate glass, aluminosilicate glass, basalt glass-ceramic, and cold-pressed and sintered silicate ceramic. The waste-immobilization processes considered are in-can glass melting, joule-heated glass melting, glass marble forming, cement casting, cement cold-pressing, FUETAP cement processing, ceramic cold-pressing and sintering, basalt glass-ceramic processing. Properties considered included gas generation, chemical durability, mechanical strength, thermal stability, and radiation stability. The ceramic products demonstrated the best properties, except for plutonium release during leaching. The glass and ceramic products had similar properties. The cement products generally had poorer properties than the other forms, except for plutonium release during leaching. Calculations of the Pu release indicated that the waste forms met the proposed NRC release rate limit of 1 part in 10/sup 5/ per year in most test conditions. The cast-cement process had the lowest processing cost, followed closely by the cold-pressed and FUETAP cement processes. Joule-heated glass melting had the lower cost of the glass processes. In-can melting in a high-quality canister had the highest cost, and cold-pressed and sintered ceramic the second highest. Labor and canister costs for in-can melting were identified. The major contributor to costs of disposing of TRU wastes in a defense waste repository is waste processing costs. Repository costs could become the dominant cost for disposing of TRU wastes in a commercial repository. It is recommended that cast and FUETAP cement and borosilicate glass waste-form systems be considered. 13 figures, 16 tables.

Ross, W.A.; Lokken, R.O.; May, R.P.; Roberts, F.P.; Timmerman, C.L.; Treat, R.L.; Westsik, J.H. Jr.

1982-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Application of Robotics and X-ray Radiography to the Examination of Large Contact Handled Transuranic (TRU) Waste Containers  

SciTech Connect (OSTI)

The US Department of Energy, Savannah River Site is storing a large number of transuranic (TRU) waste containers that are to be shipped to the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. Radiographic examination of waste containers is required prior to shipment. This paper will discuss the TRU waste container positioning system and safety system provided by PaR Systems, Inc., Shoreview, MN, to the inspection system prime contractor, Hytec, Inc., Los Alamos, NM. Most containers will be over-packed in large metal shipping containers (TRUPACT-III). The largest containers are 2.8 m x 1.9 m x 1.9 m and weigh 5600 kg. In addition, smaller containers and drums are inspected. The containers are manipulated to view the contents from various directions. The motions of the container, X-ray source and X-ray detectors are coordinated to obtain a constant viewing area relative to the item of interest in the container. (authors)

Pe, A.S. [PaR Systems, Inc., PaR Systems Inc., Shoreview, MN (United States)

2007-07-01T23:59:59.000Z

182

The Hybrid Treatment Process for mixed radioactive and hazardous waste treatment  

SciTech Connect (OSTI)

This paper describes a new process for treating mixed hazardous and radioactive waste, commonly called mixed waste. The process is called the Hybrid Treatment Process (HTP), so named because it is built on the 20 years of experience with vitrification of wastes in melters, and the 12 years of experience with treatment of wastes by the in situ vitrification (ISV) process. It also uses techniques from several additional technologies. Mixed wastes are being generated by both the US Department of Energy (DOE) and by commercial sources. The wastes are those that contain both a hazardous waste regulated under the US Environmental Protection Agency's (EPA) Resource, Conservation, and Recovery Act (RCRA) regulations and a radioactive waste with source, special nuclear, or byproduct materials. The dual regulation of the wastes increases the complexity of the treatment, handling, and storage of the waste. The DOE is the largest holder and generator of mixed waste. Its mixed wastes are classified as either high-level, transuranic (TRU), or low-level waste (LLW). High-level mixed wastes will be treated in vitrification plants. Transuranic wastes may be disposed of without treatment by obtaining a no-migration variance from the EPA. Lowlevel wastes, however, will require treatment, but treatment systems with sufficient capacity are not yet available to DOE. Various facilities are being proposed for the treatment of low-level waste. The concept described in this paper represents one option for establishing that treatment capacity.

Ross, W.A.; Kindle, C.H.

1992-06-01T23:59:59.000Z

183

The Hybrid Treatment Process for mixed radioactive and hazardous waste treatment  

SciTech Connect (OSTI)

This paper describes a new process for treating mixed hazardous and radioactive waste, commonly called mixed waste. The process is called the Hybrid Treatment Process (HTP), so named because it is built on the 20 years of experience with vitrification of wastes in melters, and the 12 years of experience with treatment of wastes by the in situ vitrification (ISV) process. It also uses techniques from several additional technologies. Mixed wastes are being generated by both the US Department of Energy (DOE) and by commercial sources. The wastes are those that contain both a hazardous waste regulated under the US Environmental Protection Agency`s (EPA) Resource, Conservation, and Recovery Act (RCRA) regulations and a radioactive waste with source, special nuclear, or byproduct materials. The dual regulation of the wastes increases the complexity of the treatment, handling, and storage of the waste. The DOE is the largest holder and generator of mixed waste. Its mixed wastes are classified as either high-level, transuranic (TRU), or low-level waste (LLW). High-level mixed wastes will be treated in vitrification plants. Transuranic wastes may be disposed of without treatment by obtaining a no-migration variance from the EPA. Lowlevel wastes, however, will require treatment, but treatment systems with sufficient capacity are not yet available to DOE. Various facilities are being proposed for the treatment of low-level waste. The concept described in this paper represents one option for establishing that treatment capacity.

Ross, W.A.; Kindle, C.H.

1992-06-01T23:59:59.000Z

184

Complications Associated with Long-Term Disposition of Newly-Generated Transuranic Waste: A National Laboratory Perspective  

SciTech Connect (OSTI)

The Idaho National Laboratory (INL) is a multipurpose national laboratory delivering specialized science and engineering solutions for the U.S. Department of Energy (DOE). Sponsorship of INL was formally transferred to the DOE Office of Nuclear Energy, Science and Technology (NE) by Secretary Spencer Abraham in July 2002. The move to NE, and designation as the DOE lead nuclear energy laboratory for reactor technology, supports the nation’s expanding nuclear energy initiatives, placing INL at the center of work to develop advanced Generation IV nuclear energy systems; nuclear energy/hydrogen coproduction technology; advanced nuclear energy fuel cycle technologies; and providing national security answers to national infrastructure needs. As a result of the Laboratory’s NE mission, INL generates both contact-handled and remote-handled transuranic (TRU) waste from ongoing operations. Generation rates are relatively small and fluctuate based on specific programs and project activities being conducted; however, the Laboratory will continue to generate TRU waste well into the future in association with the NE mission. Currently, plans and capabilities are being established to transfer INL’s contact-handled TRU waste to the Advanced Mixed Waste Treatment Plant (AMWTP) for certification and disposal to the Waste Isolation Pilot Plant (WIPP). Remote-handled TRU waste is currently placed in storage at the Materials and Fuels Complex (MFC). In an effort to minimize future liabilities associated with the INL NE mission, INL is evaluating and assessing options for the management and disposition of all its TRU waste on a real-time basis at time of generation. This paper summarizes near-term activities to minimize future re handling of INL’s TRU waste, as well as, potential complications associated with the long-term disposition of newly-generated TRU waste. Potential complications impacting the disposition of INL newly-generated TRU waste include, but are not limited to: 1) required remote-handled TRU packaging configuration(s) vs. current facility capabilities, 2) long-term NE mission activities, 3) WIPP certification requirements, and 4) budget considerations.

B.J. Orchard; L.A. Harvego; T.L. Carlson; R.P. Grant

2009-03-01T23:59:59.000Z

185

Building 251 Radioactive Waste Characterization by Process Knowledge  

SciTech Connect (OSTI)

Building 251 is the Lawrence Livermore National Laboratory Heavy Elements Facility. Operations that involved heavy elements with uncontained radioisotopes including transuranic elements took place inside of glove boxes and fume hoods. These operations included process and solution chemistry, dissolutions, titrations, centrifuging, etc., and isotope separation. Operations with radioactive material which presently take place outside of glove boxes include storage, assaying, packing and unpacking and inventory verification. Wastes generated inside glove boxes will generally be considered TRU or Greater Than Class C (GTCC). Wastes generated in the RMA, outside glove boxes, is presumed to be low level waste. This process knowledge quantification method may be applied to waste generated anywhere within or around B251. The method is suitable only for quantification of waste which measures below the MDA of the Blue Alpha meter (i.e. only material which measures as Non-Detect with the blue alpha is to be characterized by this method).

Dominick, J L

2002-05-29T23:59:59.000Z

186

Thermal processing system concepts and considerations for RWMC buried waste  

SciTech Connect (OSTI)

This report presents a preliminary determination of ex situ thermal processing system concepts and related processing considerations for application to remediation of transuranic (TRU)-contaminated buried wastes (TRUW) at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Beginning with top-level thermal treatment concepts and requirements identified in a previous Preliminary Systems Design Study (SDS), a more detailed consideration of the waste materials thermal processing problem is provided. Anticipated waste stream elements and problem characteristics are identified and considered. Final waste form performance criteria, requirements, and options are examined within the context of providing a high-integrity, low-leachability glass/ceramic, final waste form material. Thermal processing conditions required and capability of key systems components (equipment) to provide these material process conditions are considered. Information from closely related companion study reports on melter technology development needs assessment and INEL Iron-Enriched Basalt (IEB) research are considered. Five potentially practicable thermal process system design configuration concepts are defined and compared. A scenario for thermal processing of a mixed waste and soils stream with essentially no complex presorting and using a series process of incineration and high temperature melting is recommended. Recommendations for applied research and development necessary to further detail and demonstrate the final waste form, required thermal processes, and melter process equipment are provided.

Eddy, T.L.; Kong, P.C.; Raivo, B.D.; Anderson, G.L.

1992-02-01T23:59:59.000Z

187

Potential microbial impact on transuranic wastes under conditions expected in the Waste Isolation Pilot Plant (WIPP). Annual report, October 1, 1978-September 30, 1979  

SciTech Connect (OSTI)

Previous results were confirmed showing elevated frequencies of radiation-resistant bacteria in microorganisms isolated from shallow transuranic (TRU) burial soil that exhibits nanocurie levels of beta and gamma radioactivity. Research to determine whether plutonium could be methylated by the microbially produced methyl donor, methylcobalamine, was terminated when literature and consulting radiochemists confirmed that other alkylated transuranic elements are extremely short-lived in the presence of oxygen. Emphasis was placed on investigation of the dissolution of plutonium dioxide by complex formation between plutonium and a polyhydroxamate chelate similar to that produced by microorganisms. New chromatographic and spectrophotometric evidence supports previous results showing enhanced dissolution of alpha radioactivity when /sup 239/Pu dioxide was mixed with the chelate Desferol. Microbial degradation studies of citrate, ethylenediamine tetraacetate (EDTA), and nitrilo triacetate (NTA) chelates of europium are in progress. Current results are summarized. All of the chelates were found to degrade. The average half-life for citrate, NTA, and EDTA was 3.2, 8.0, and 28 years, respectively. Microbial CO/sub 2/ generation is also in progress in 72 tests on several waste matrices under potential WIPP isolation conditions. The mean rate of gas generation was 5.97 ..mu..g CO/sub 2//g waste/day. Increasing temperature increased rates of microbial gas generation across treatments of brine, varying water content, nutrient additions, and anaerobic conditions. No microbial growth was detected in experiments to enumerate and identify the microorganisms in rocksalt cores from the proposed WIPP site. This report contains the year's research results and recommendations derived for the design of safe storage of TRU wastes under geologic repository conditions.

Barnhart, B.J.; Campbell, E.W.; Martinez, E.; Caldwell, D.E.; Hallett, R.

1980-07-01T23:59:59.000Z

188

Sorting and Characterizing Oversized Boxes of Transuranic Waste at the Nevada Test Site  

ScienceCinema (OSTI)

Characterization activities conducted inside the Visual Examination and Repackaging Building at the Area 5 Radioactive Waste Management Complex on the Nevada Test Site.

None

2014-10-28T23:59:59.000Z

189

Pre-title I safety evaluation for the retrieval operations of transuranic waste drums in the Solid Waste Disposal Facility. Revision 2  

SciTech Connect (OSTI)

Phase I of the Transuranic (TRU) Waste Facility Line Item Project includes the retrieval and safe storage of the pad drums that are stored on TRU pads 2-6 in the Solid Waste Disposal Facility (SWDF). Drums containing TRU waste were placed on these pads as early as 1974. The pads, once filled, were mounded with soil. The retrieval activities will include the excavation of the soil, retrieval of the pad drums, placing the drums in overpacks (if necessary) and venting and purging the retrieved drums. Once the drums have been vented and purged, they will be transported to other pads within the SWDF or in a designated area until they are eventually treated as necessary for ultimate shipment to the Waste Isolation Pilot Plant in Carlsbad, New Mexico. This safety evaluation provides a bounding assessment of the radiological risk involved with the drum retrieval activities to the maximally exposed offsite individual and the co-located worker. The results of the analysis indicate that the risk to the maximally exposed offsite individual and the co-located worker using maximum frequencies and maximum consequences are within the acceptance criteria defined in WSRC Procedural Manual 9Q. The purpose of this evaluation is to demonstrate the incremental risk from the SWDF due to the retrieval activities for use as design input only. As design information becomes available, this evaluation can be revised to satisfy the safety analysis requirements of DOE Orders 4700 and 5480.23.

Rabin, M.S.

1992-08-01T23:59:59.000Z

190

Special Analysis of Transuranic Waste in Trench T04C at the Area 5 Radioactive Waste Management Site, Nevada Test Site, Nye County, Nevada, Revision 1  

SciTech Connect (OSTI)

This Special Analysis (SA) was prepared to assess the potential impact of inadvertent disposal of a limited quantity of transuranic (TRU) waste in classified Trench 4 (T04C) within the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada Test Site (NTS). The Area 5 RWMS is a low-level radioactive waste disposal site in northern Frenchman Flat on the Nevada Test Site (NTS). The Area 5 RWMS is regulated by the U.S. Department of Energy (DOE) under DOE Order 435.1 and DOE Manual (DOE M) 435.1-1. The primary objective of the SA is to evaluate if inadvertent disposal of limited quantities of TRU waste in a shallow land burial trench at the Area 5 RWMS is in compliance with the existing, approved Disposal Authorization Statement (DAS) issued under DOE M 435.1-1. In addition, supplemental analyses are performed to determine if there is reasonable assurance that the requirements of Title 40, Code of Federal Regulations (CFR), Part 191, Environmental Radiation Protection Standards for Management and Disposal of Spent Nuclear Fuel, High-Level, and Transuranic Radioactive Wastes, can be met. The 40 CFR 191 analyses provide supplemental information regarding the risk to human health and the environment of leaving the TRU waste in T04C. In 1989, waste management personnel reviewing classified materials records discovered that classified materials buried in trench T04C at the Area 5 RWMS contained TRU waste. Subsequent investigations determined that a total of 102 55-gallon drums of TRU waste from Rocky Flats were buried in trench T04C in 1986. The disposal was inadvertent because unclassified records accompanying the shipment indicated that the waste was low-level. The exact location of the TRU waste in T04C was not recorded and is currently unknown. Under DOE M 435.1-1, Chapter IV, Section P.5, low-level waste disposal facilities must obtain a DAS. The DAS specifies conditions that must be met to operate within the radioactive waste management basis, consisting of a performance assessment (PA), composite analysis (CA), closure plan, monitoring plan, waste acceptance criteria, and a PA/CA maintenance plan. The DOE issued a DAS for the Area 5 RWMS in 2000. The Area 5 RWMS DAS was, in part, based on review of a CA as required under DOE M 435.1-1, Chapter IV, Section P.(3). A CA is a radiological assessment required for DOE waste disposed before 26 September 1988 and includes the radiological dose from all sources of radioactive material interacting with all radioactive waste disposed at the Area 5 RWMS. The approved Area 5 RWMS CA, which includes the inventory of TRU waste in T04C, indicates that the Area 5 RWMS waste inventory and all interacting sources of radioactive material can meet the 0.3 mSv dose constraint. The composite analysis maximum annual dose for a future resident at the Area 5 RWMS was estimated to be 0.01 mSv at 1,000 years. Therefore, the inadvertent disposal of TRU in T04C is protective of the public and the environment, and compliant with all the applicable requirements in DOE M 435.1-1 and the DAS. The U.S. Environmental Protection Agency promulgated 40 CFR 191 to establish standards for the planned disposal of spent nuclear fuel, high level, and transuranic wastes in geologic repositories. Although not required, the National Nuclear Security Administration Nevada Site Office requested a supplemental analysis to evaluate the likelihood that the inadvertent disposal of TRU waste in T04C meets the requirements of 40 CFR 191. The SA evaluates the likelihood of meeting the 40 CFR 191 containment requirements (CRs), assurance requirements, individual protection requirements (IPRs), and groundwater protection standards. The results of the SA indicate that there is a reasonable expectation of meeting all the requirements of 40 CFR 191. The conclusion of the SA is that the Area 5 RWMS with the TRU waste buried in T04C is in compliance with all requirements in DOE M 435.1-1 and the DAS. Compliance with the DAS is demonstrated by the results of the Area 5 RWMS CA. Supplemental analyses in the SA indicate there is a

Greg Shott, Vefa Yucel, Lloyd Desotell

2008-05-01T23:59:59.000Z

191

A Close in Place Option for Buried Transuranic Waste at the Nevada...  

National Nuclear Security Administration (NNSA)

1994). 11. J.D. ISTOK, D.O. BLOUT, L. BARKER, K.R. JOHNEJACK, and D.P. HAMMERMEISTER, Spatial Variability in Alluvium Properties at a Low-Level Nuclear Waste Site, Soil Sci....

192

Functions and requirements document for interim store solidified high-level and transuranic waste  

SciTech Connect (OSTI)

The functions, requirements, interfaces, and architectures contained within the Functions and Requirements (F{ampersand}R) Document are based on the information currently contained within the TWRS Functions and Requirements database. The database also documents the set of technically defensible functions and requirements associated with the solidified waste interim storage mission.The F{ampersand}R Document provides a snapshot in time of the technical baseline for the project. The F{ampersand}R document is the product of functional analysis, requirements allocation and architectural structure definition. The technical baseline described in this document is traceable to the TWRS function 4.2.4.1, Interim Store Solidified Waste, and its related requirements, architecture, and interfaces.

Smith-Fewell, M.A., Westinghouse Hanford

1996-05-17T23:59:59.000Z

193

Foreign programs for the storage of spent nuclear power plant fuels, high-level waste canisters and transuranic wastes  

SciTech Connect (OSTI)

The various national programs for developing and applying technology for the interim storage of spent fuel, high-level radioactive waste, and TRU wastes are summarized. Primary emphasis of the report is on dry storage techniques for uranium dioxide fuels, but data are also provided concerning pool storage.

Harmon, K.M.; Johnson, A.B. Jr.

1984-04-01T23:59:59.000Z

194

Hanford Waste Vitrification Plant full-scale feed preparation testing with water and process simulant slurries  

SciTech Connect (OSTI)

The Hanford Waste Vitrification Plant was intended to convert selected, pretreated defense high-level waste and transuranic waste from the Hanford Site into a borosilicate glass. A full-scale testing program was conducted with nonradioactive waste simulants to develop information for process and equipment design of the feed-preparation system. The equipment systems tested included the Slurry Receipt and Adjustment Tank, Slurry Mix Evaporator, and Melter-Feed Tank. The areas of data generation included heat transfer (boiling, heating, and cooling), slurry mixing, slurry pumping and transport, slurry sampling, and process chemistry. 13 refs., 129 figs., 68 tabs.

Gaskill, J.R.; Larson, D.E.; Abrigo, G.P. [and others] [and others

1996-03-01T23:59:59.000Z

195

Use of the TRUEX process for the pretreatment of neutralized cladding removal waste (NCRW) sludge -- Results of FY 1990 studies  

SciTech Connect (OSTI)

The goal of this process is to separate the transuranic elements from the bulk components so that the bulk components can be disposed of as low-level waste with only a small transuranic-containing fraction requiring geologic disposal. The pretreatment process examined here is the one indicated to be most promising in the initial studies. It involves dissolving the unwashed sludge in nitric acid and then using the TRUEX solvent extraction process to remove the transuranic elements from the bulk components of the waste. The areas identified in this work that need additional information are gradual precipitate formation as dissolved sludge solutions age, and formation of solid material when the dissolved sludge solution is contacted with the solvent used in the TRUEX process. 5 refs., 71 figs., 10 tabs.

Swanson, J.L.

1991-09-01T23:59:59.000Z

196

DOE Selects Two Small Businesses to Truck Transuranic Waste to New Mexico  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy UsageAUDITVehiclesTankless orAChiefAppropriation FYG 242.1-1of1.9MOhioDepartmentWaste

197

Radioactive waste processing apparatus  

DOE Patents [OSTI]

Apparatus for use in processing radioactive waste materials for shipment and storage in solid form in a container is disclosed. The container includes a top, and an opening in the top which is smaller than the outer circumference of the container. The apparatus includes an enclosure into which the container is placed, solution feed apparatus for adding a solution containing radioactive waste materials into the container through the container opening, and at least one rotatable blade for blending the solution with a fixing agent such as cement or the like as the solution is added into the container. The blade is constructed so that it can pass through the opening in the top of the container. The rotational axis of the blade is displaced from the center of the blade so that after the blade passes through the opening, the blade and container can be adjusted so that one edge of the blade is adjacent the cylindrical wall of the container, to insure thorough mixing. When the blade is inside the container, a substantially sealed chamber is formed to contain vapors created by the chemical action of the waste solution and fixant, and vapors emanating through the opening in the container.

Nelson, Robert E. (Lombard, IL); Ziegler, Anton A. (Darien, IL); Serino, David F. (Maplewood, MN); Basnar, Paul J. (Western Springs, IL)

1987-01-01T23:59:59.000Z

198

Hydrothermal Processing of Wet Wastes  

Broader source: Energy.gov [DOE]

Breakout Session 3A—Conversion Technologies III: Energy from Our Waste—Will we Be Rich in Fuel or Knee Deep in Trash by 2025? Hydrothermal Processing of Wet Wastes James R. Oyler, President, Genifuel Corporation

199

Process for preparing liquid wastes  

DOE Patents [OSTI]

A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

1997-01-01T23:59:59.000Z

200

Idaho Nuclear Technology and Engineering Center Low-Activity Waste Process Technology Program FY-99 Status Report  

SciTech Connect (OSTI)

The Low-Activity Waste Process Technology Program at the Idaho Nuclear Technology and Engineering Center (INTEC) anticipates that large volumes of low-level/low-activity wastes will need to be grouted prior to near-surface disposal. During fiscal year 1999, grout formulations were studied for transuranic waste derived from INTEC liquid sodium-bearing waste and for projected newly generated low-level liquid waste. Additional studies were completed on radionuclide leaching, microbial degradation, waste neutralization, and a small mockup for grouting the INTEC underground storage tank residual heels.

A. K. Herbst; J. A. McCray; R. J. Kirkham; J. Pao; S. H. Hinckley

1999-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Idaho Nuclear Technology and Engineering Center Low-Activity Waste Process Technology Program FY-99 Status Report  

SciTech Connect (OSTI)

The Low-Activity Waste Process Technology Program at the Idaho Nuclear Technology and Engineering Center (INTEC) anticipates that large volumes of low-level/low-activity wastes will need to be grouted prior to near-surface disposal. During fiscal year 1999, grout formulations were studied for transuranic waste derived from INTEC liquid sodium-bearing waste and for projected newly generated low-level liquid waste. Additional studies were completed on radionuclide leaching, microbial degradation, waste neutralization, and a small mockup for grouting the INTEC underground storage tank residual heels.

Herbst, Alan Keith; Mc Cray, John Alan; Kirkham, Robert John; Pao, Jenn Hai; Hinckley, Steve Harold

1999-10-01T23:59:59.000Z

202

Facility Utilization and Risk Analysis for Remediation of Legacy Transuranic Waste at the Savannah River Site - 13572  

SciTech Connect (OSTI)

Savannah River Nuclear Solutions (SRNS) completed the Accelerated TRU Project for remediating legacy waste at the Savannah River Site with significant cost and schedule efficiencies due to early identification of resources and utilization of risk matrices. Initial project planning included identification of existing facilities that could be modified to meet the technical requirements needed for repackaging and remediating the waste. The project schedule was then optimized by utilization of risk matrices that identified alternate strategies and parallel processing paths which drove the overall success of the project. Early completion of the Accelerated TRU Project allowed SRNS to pursue stretch goals associated with remediating very difficult TRU waste such as concrete casks from the hot cells in the Savannah River National Laboratory. Project planning for stretch goals also utilized existing facilities and the risk matrices. The Accelerated TRU project and stretch goals were funded under the American Recovery and Reinvestment Act (ARRA). (authors)

Gilles, Michael L.; Gilmour, John C. [Savannah River Nuclear Solutions, LLC (United States)] [Savannah River Nuclear Solutions, LLC (United States)

2013-07-01T23:59:59.000Z

203

Los Alamos National Laboratory opens new waste repackaging facility  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to increase its capability to process nuclear waste for permanent disposal. March 7, 2013 A view of the new box line facility where transuranic waste will be repackaged at Los...

204

Method for processing aqueous wastes  

DOE Patents [OSTI]

A method is presented for treating waste water such as that from an industrial processing facility comprising the separation of the waste water into a dilute waste stream and a concentrated waste stream. The concentrated waste stream is treated chemically to enhance precipitation and then allowed to separate into a sludge and a supernate. The supernate is skimmed or filtered from the sludge and blended with the dilute waste stream to form a second dilute waste stream. The sludge remaining is mixed with cementitious material, rinsed to dissolve soluble components, then pressed to remove excess water and dissolved solids before being allowed to cure. The dilute waste stream is also chemically treated to decompose carbonate complexes and metal ions and then mixed with cationic polymer to cause the precipitated solids to flocculate. Filtration of the flocculant removes sufficient solids to allow the waste water to be discharged to the surface of a stream. The filtered material is added to the sludge of the concentrated waste stream. The method is also applicable to the treatment and removal of soluble uranium from aqueous streams, such that the treated stream may be used as a potable water supply. 4 figures.

Pickett, J.B.; Martin, H.L.; Langton, C.A.; Harley, W.W.

1993-12-28T23:59:59.000Z

205

Method for processing aqueous wastes  

DOE Patents [OSTI]

A method for treating waste water such as that from an industrial processing facility comprising the separation of the waste water into a dilute waste stream and a concentrated waste stream. The concentrated waste stream is treated chemically to enhance precipitation and then allowed to separate into a sludge and a supernate. The supernate is skimmed or filtered from the sludge and blended with the dilute waste stream to form a second dilute waste stream. The sludge remaining is mixed with cementitious material, rinsed to dissolve soluble components, then pressed to remove excess water and dissolved solids before being allowed to cure. The dilute waste stream is also chemically treated to decompose carbonate complexes and metal ions and then mixed with cationic polymer to cause the precipitated solids to flocculate. Filtration of the flocculant removes sufficient solids to allow the waste water to be discharged to the surface of a stream. The filtered material is added to the sludge of the concentrated waste stream. The method is also applicable to the treatment and removal of soluble uranium from aqueous streams, such that the treated stream may be used as a potable water supply.

Pickett, John B. (3922 Wood Valley Dr., Aiken, SC 29803); Martin, Hollis L. (Rt. 1, Box 188KB, McCormick, SC 29835); Langton, Christine A. (455 Sumter St. SE., Aiken, SC 29801); Harley, Willie W. (110 Fairchild St., Batesburg, SC 29006)

1993-01-01T23:59:59.000Z

206

Independent Oversight Assessment, Salt Waste Processing Facility...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Salt Waste Processing Facility Project - January 2013 January 2013 Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project The U.S. Department...

207

An evaluation of neutralization for processing sodium-bearing liquid waste  

SciTech Connect (OSTI)

This report addresses an alternative concept for potentially managing the sodium-bearing liquid waste generated at the Idaho Chemical Processing Plant from the current method of calcining a blend of sodium waste and high-level liquid waste. The concept is based on removing the radioactive components from sodium-bearing waste by neutralization and grouting the resulting low-level waste for on-site near-surface disposal. Solidifying the sodium waste as a remote-handled transuranic waste is not considered to be practical because of excessive costs and inability to dispose of the waste in a timely fashion. Although neutralization can remove most radioactive components to provide feed for a solidified low-level waste, and can reduce liquid inventories four to nine years more rapidly than the current practice of blending sodium-bearing liquid waste with first-cycle raffinite, the alternative will require major new facilities and will generate large volumes of low-level waste. Additional facility and operating costs are estimated to be at least $500 million above the current practice of blending and calcining. On-site, low-level waste disposal may be technically difficult and conflict which national and state policies. Therefore, it is recommended that the current practice of calcining a blend of sodium-bearing liquid waste and high-level liquid waste be continued to minimize overall cost and process complexities. 17 refs., 4 figs., 16 tabs.

Chipman, N.A.; Engelgau, G.O.; Berreth, J.R.

1989-01-01T23:59:59.000Z

208

Supplemental information related to risk assessment for the off-site transportation of transuranic waste for the U.S. Department of Energy waste management programmatic environmental impact statement  

SciTech Connect (OSTI)

This report presents supplemental information to support the human health risk assessment conducted for the transportation of transuranic waste (TRUW) in support of the US Department of Energy Waste Management Programmatic Environmental Impact Statement (WM PEIS). Detailed descriptions of the transportation health risk assessment method and results of the assessment are presented in Appendix E of the WM PEIS and are not repeated in this report. This report presents additional information that is not presented in Appendix E but is necessary to conduct the transportation risk assessment for Waste Management (WM) contact- and remote-handed (CH and RH) TRUW. Included are definitions of the TRUW alternatives considered in the WM PEIS, data related to the inventory and to the physical and radiological characteristics of CH and RH TRUW, and detailed results of the assessment for each WM TRUW case considered.

Monette, F.A.; Biwer, B.M.; LePoire, D.J.; Chen, S.Y. [Argonne National Lab., IL (United States). Environmental Assessment Div.

1996-12-01T23:59:59.000Z

209

Salt Waste Processing Initiatives  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September2-SCORECARD-01-24-13 Page 1 of 1 DepartmentSalt Waste1

210

Use of the TRUEX process for the pretreatment of neutralized cladding removal waste (NCRW) sludge: Results of a design basis experiment  

SciTech Connect (OSTI)

This report presents the results of an experiment designed to demonstrate the feasibility of a sludge dissolution/solvent extraction process to separate transuranic elements from the bulk components of Hanford neutralized cladding removal waste (NCRW) sludge. Such a separation would allow the bulk of the waste to be disposed of as low-level waste, which is much less costly than geologic disposal as would be required for the waste in its current form. The results indicate that the proposed process is well suited to meet the desired objectives. A composite sample of NCRW sludge taken from Tank 103-AW in 1986 was dissolved in nitric acid at room temperature. Dissolution of bulk components and all radionuclides was {ge}95% complete; thus, {le}5% of the bulk components will require geologic disposal. The TRUEX (TRansUranium EXtraction) solvent extraction process gave very good separation of the transuranic from the bulk components of the waste.

Swanson, J L

1991-07-01T23:59:59.000Z

211

THE SUCCESSFUL UTILIZATION OF COMMERCIAL TREATMENT CAPABILITIES TO DISPOSITION HANFORD NO-PATH-FORWARD SUSPECT TRANSURANIC WASTES  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) Richland Operations Office (RL) has adopted the 2015 Vision for Cleanup of the Hanford Site. The CH2M HILL Plateau Remediation Company's (CHPRC) Waste and Fuels Management Project (W&FMP) and their partners support this mission by providing centralized waste management services for the Hanford Site waste generating organizations. At the time of the CHPRC contract award (August 2008) slightly more than 9,000 cubic meters (m{sup 3}) of legacy waste was defined as ''no-path-forward waste.'' A significant portion of this waste (7,650 m{sup 3}) comprised wastes with up to 50 grams of special nuclear materials (SNM) in oversized packages recovered during retrieval operations and large glove boxes removed from Hanford's Plutonium Finishing Plant (PFP). Through a collaborative effort between the DOE, CHPRC, and Perma-Fix Environmental Services, Inc. (PESI), pathways for these problematic wastes were developed and are currently being implemented.

BLACKFORD LT; CATLOW RL; WEST LD; COLLINS MS; ROMINE LD; MOAK DJ

2012-01-30T23:59:59.000Z

212

Transuranic waste inventory, characteristics, generation, and facility assessment for treatment, storage, and disposal alternatives considered in the U.S. Department of Energy Waste Management Programmatic Environmental Impact Statement  

SciTech Connect (OSTI)

Transuranic waste (TRUW) loads and potential contaminant releases at and en route to treatment, storage, and disposal sites in the US Department of Energy (DOE) complex are important considerations in DOE`s Waste Management Programmatic Environmental Impact Statement (WM PEIS). Waste loads are determined in part by the level of treatment the waste has undergone and the complex-wide configuration of origination, treatment, storage, and disposal sites selected for TRUW management. Other elements that impact waste loads are treatment volumes, waste characteristics, and the unit operation parameters of the treatment technologies. Treatment levels and site configurations have been combined into six TRUW management alternatives for study in the WM PEIS. This supplemental report to the WM PEIS gives the projected waste loads and contaminant release profiles for DOE treatment sites under each of the six TRUW management alternatives. It gives TRUW characteristics and inventories for current DOE generation and storage sites, describes the treatment technologies for three proposed levels of TRUW treatment, and presents the representative unit operation parameters of the treatment technologies. The data presented are primary inputs to developing the costs, health risks, and socioeconomic and environmental impacts of treating, packaging, and shipping TRUW for disposal.

Hong, K.; Kotek, T.; Folga, S.; Koebnick, B.; Wang, Y.; Kaicher, C.

1996-12-01T23:59:59.000Z

213

Waste Receiving and Processing (WRAP) Facility Final Safety Analysis Report (FSAR)  

SciTech Connect (OSTI)

The Waste Receiving and Processing Facility (WRAP), 2336W Building, on the Hanford Site is designed to receive, confirm, repackage, certify, treat, store, and ship contact-handled transuranic and low-level radioactive waste from past and present U.S. Department of Energy activities. The WRAP facility is comprised of three buildings: 2336W, the main processing facility (also referred to generically as WRAP); 2740W, an administrative support building; and 2620W, a maintenance support building. The support buildings are subject to the normal hazards associated with industrial buildings (no radiological materials are handled) and are not part of this analysis except as they are impacted by operations in the processing building, 2336W. WRAP is designed to provide safer, more efficient methods of handling the waste than currently exist on the Hanford Site and contributes to the achievement of as low as reasonably achievable goals for Hanford Site waste management.

TOMASZEWSKI, T.A.

2000-04-25T23:59:59.000Z

214

Los Alamos Waste Management Cost Estimation Model; Final report: Documentation of waste management process, development of Cost Estimation Model, and model reference manual  

SciTech Connect (OSTI)

This final report completes the Los Alamos Waste Management Cost Estimation Project, and includes the documentation of the waste management processes at Los Alamos National Laboratory (LANL) for hazardous, mixed, low-level radioactive solid and transuranic waste, development of the cost estimation model and a user reference manual. The ultimate goal of this effort was to develop an estimate of the life cycle costs for the aforementioned waste types. The Cost Estimation Model is a tool that can be used to calculate the costs of waste management at LANL for the aforementioned waste types, under several different scenarios. Each waste category at LANL is managed in a separate fashion, according to Department of Energy requirements and state and federal regulations. The cost of the waste management process for each waste category has not previously been well documented. In particular, the costs associated with the handling, treatment and storage of the waste have not been well understood. It is anticipated that greater knowledge of these costs will encourage waste generators at the Laboratory to apply waste minimization techniques to current operations. Expected benefits of waste minimization are a reduction in waste volume, decrease in liability and lower waste management costs.

Matysiak, L.M.; Burns, M.L.

1994-03-01T23:59:59.000Z

215

Challenges using a {sup 252}Cf shuffler instrument in a plant environment to measure mixtures of uranium and plutonium transuranic waste  

SciTech Connect (OSTI)

An active-passive {sup 252}Cf shuffler instrument, installed and certified several years ago at Los Alamos National Laboratory's plutonium facility, has now been calibrated for different matrices to measure Waste Isolation Pilot Plant (WIPP)-destined transuranic (TRU) waste. Little or no data currently exist for these types of measurements in plant environments where sudden large changes in the neutron background radiation can significantly distort the results. Measurements and analyses of twenty-two 55-gallon drums, consisting of mixtures of varying quantities of uranium and plutonium in mostly noncombustible matrices, have been recently completed at the plutonium facility. The calibration and measurement techniques, including the method used to separate out the plutonium component, will be presented and discussed. Calculations used to adjust for differences in uranium enrichment from that of the calibration standards will be shown. Methods used to determine various sources of both random and systematic error will be indicated. Particular attention will be directed to those problems identified as arising from the plant environment. The results of studies to quantify the aforementioned distortion effects in the data will be presented. Various solution scenarios will be outlined, along with those adopted here.

Hurd, J.R.

1999-08-29T23:59:59.000Z

216

Consolidation process for producing ceramic waste forms  

DOE Patents [OSTI]

A process for the consolidation and containment of solid or semisolid hazardous waste, which process comprises closing an end of a circular hollow cylinder, filling the cylinder with the hazardous waste, and then cold working the cylinder to reduce its diameter while simultaneously compacting the waste. The open end of the cylinder can be sealed prior to or after the cold working process. The preferred method of cold working is to draw the sealed cylinder containing the hazardous waste through a plurality of dies to simultaneously reduce the diameter of the tube while compacting the waste. This process provides a quick continuous process for consolidating hazardous waste, including radioactive waste.

Hash, Harry C. (Joliet, IL); Hash, Mark C. (Shorewood, IL)

2000-01-01T23:59:59.000Z

217

Concentration of remote-handled, transuranic, sodium nitrate-based sludge using agitated thin-film evaporators  

SciTech Connect (OSTI)

The Waste Handling and Packaging Plant (WHPP) is being designed at Oak Ridge National Laboratory (ORNL) to prepared transuranic waste for final disposal. Once operational, this facility will process, package, and certify remote-handled transuranic waste for ultimate shipment and disposal at the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. One of the wastes that will be handled at WHIPP is the transuranic sludge currently stored at ORNL in eight 50,000-gal underground tanks. The use of an Agitated Thin-Film Evaporator (ATFE) for concentration of this waste is being investigated. Tests have shown that the ATFE can be used to produce a thick slurry, a powder, or a fused salt. A computer model developed at the Savannah River Plant (SRP) to simulate the operation of ATFE's on their waste is being modified for use on the ORNL transuranic sludge. This paper summarizes the results of the test with the ATFEs to date, discusses the changes in the SRP model necessary to use this model with the ORNL waste, and compares the results of the model with the actual data taken from the operation of ATFEs at vendors' test facilities. 8 refs., 1 fig., 3 tabs.

Walker, J.F. Jr.; Youngblood, E.L.; Berry, J.B. (Oak Ridge National Lab., TN (USA)); Pen, Ben-Li (Institute of Nuclear Energy Research, Lung-Tan (Taiwan))

1991-01-01T23:59:59.000Z

218

A New Concept: Use of Negotiations in the Hazardous Waste Facility Permitting Process in New Mexico  

SciTech Connect (OSTI)

This paper describes a unique negotiation process leading to authorization of the U.S. Department of Energy (DOE) to manage and dispose remote-handled (RH) transuranic (TRU) mixed wastes at the Waste Isolation Pilot Plant (WIPP). The negotiation process involved multiple entities and individuals brought together under authority of the New Mexico Environment Department (NMED) to discuss and resolve technical and facility operational issues flowing from an NMED-issued hazardous waste facility Draft Permit. The novel negotiation process resulted in numerous substantive changes to the Draft Permit, which were ultimately memorialised in a 'Draft Permit as Changed'. This paper discusses various aspects of the negotiation process, including events leading to the negotiations, regulatory basis for the negotiations, negotiation participants, and benefits of the process. (authors)

Johnson, G.J. [Washington TRU Solutions, LLC, Waste Isolation Pilot Plant, New Mexico (United States); Rose, W.M. [U.S. Department of Energy, Carlsbad Field Office, Waste Isolation Pilot Plant, New Mexico (United States); Domenici, P.V.; Hollingsworth, L. [Domenici Law Firm PC, Albuquerque, New Mexico (United States)

2007-07-01T23:59:59.000Z

219

Type B Accident Investigation of the April 8, 2003, Electrical Arc Blast at the Foster Wheeler Environmental Corporation TRU Waste Processing Facility, Oak Ridge, Tennessee  

Broader source: Energy.gov [DOE]

At approximately 0330 hours on April 8, 2003, a phase-to-phase arc blast occurred in the boiler electrical control panel at the Foster Wheeler Environmental Corporation (FWENC) Transuranic (TRU) Waste Processing Facility. The boiler was providing steam for the evaporator and was reportedly operating at about 10% of its capacity.

220

Bubblers Speed Nuclear Waste Processing at SRS  

SciTech Connect (OSTI)

At the Department of Energy's Savannah River Site, American Recovery and Reinvestment Act funding has supported installation of bubbler technology and related enhancements in the Defense Waste Processing Facility (DWPF). The improvements will accelerate the processing of radioactive waste into a safe, stable form for storage and permit expedited closure of underground waste tanks holding 37 million gallons of liquid nuclear waste.

None

2010-11-14T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Bubblers Speed Nuclear Waste Processing at SRS  

ScienceCinema (OSTI)

At the Department of Energy's Savannah River Site, American Recovery and Reinvestment Act funding has supported installation of bubbler technology and related enhancements in the Defense Waste Processing Facility (DWPF). The improvements will accelerate the processing of radioactive waste into a safe, stable form for storage and permit expedited closure of underground waste tanks holding 37 million gallons of liquid nuclear waste.

None

2014-08-06T23:59:59.000Z

222

An Investigation of the Use of Fully Ceramic Microencapsulated Fuel for Transuranic Waste Recycling in Pressurized Water Reactors  

SciTech Connect (OSTI)

An investigation of the utilization of TRistructural- ISOtropic (TRISO)-coated fuel particles for the burning of plutonium/neptunium (Pu/Np) isotopes in typical Westinghouse four-loop pressurized water reactors is presented. Though numerous studies have evaluated the burning of transuranic isotopes in light water reactors (LWRs), this work differentiates itself by employing Pu/Np-loaded TRISO particles embedded within a silicon carbide (SiC) matrix and formed into pellets, constituting the fully ceramic microencapsulated (FCM) fuel concept that can be loaded into standard LWR fuel element cladding. This approach provides the capability of Pu/Np burning and, by virtue of the multibarrier TRISO particle design and SiC matrix properties, will allow for greater burnup of Pu/Np material, plus improved fuel reliability and thermal performance. In this study, a variety of heterogeneous assembly layouts, which utilize a mix of FCM rods and typical UO2 rods, and core loading patterns were analyzed to demonstrate the neutronic feasibility of Pu/Np-loaded TRISO fuel. The assembly and core designs herein reported are not fully optimized and require fine-tuning to flatten power peaks; however, the progress achieved thus far strongly supports the conclusion that with further rod/assembly/core loading and placement optimization, Pu/Np-loaded TRISO fuel and core designs that are capable of balancing Pu/Np production and destruction can be designed within the standard constraints for thermal and reactivity performance in pressurized water reactors.

Gentry, Cole A [ORNL] [ORNL; Godfrey, Andrew T [ORNL] [ORNL; Terrani, Kurt A [ORNL] [ORNL; Gehin, Jess C [ORNL] [ORNL; Powers, Jeffrey J [ORNL] [ORNL; Maldonado, G Ivan [ORNL] [ORNL

2014-01-01T23:59:59.000Z

223

Waste minimization in semiconductor processing  

SciTech Connect (OSTI)

The US semiconductor industry uses 5--7 thousand pounds of arsine annually. Fifty to eighty percent of the arsine used becomes a waste product, which requires abatement. Traditional methods of abatement are reviewed with an emphasis on dry chemical scrubbing. A variety of dry chemical scrubbing materials were evaluated for arsine capacity, using activated carbon as the baseline for comparison. Of the available technologies, dry chemical scrubbing is the most effective means of minimizing arsenic containing waste generated from semiconductor effluents. A copper oxide based media has been identified which has high capacity, high efficiency and treats the spectrum of gases used in MOCVD processes. Reclaim and recovery of spent scrubber media has the potential to drastically reduce arsenic waste from semiconductor manufacturing.

Hardwick, S.J.; Mailloux, J.C. [Novapure Corp., Danbury, CT (United States)

1994-12-31T23:59:59.000Z

224

EIS-0113: Disposal of Hanford Defense High-Level, Transuranic and Tank Waste, Hanford Site, Richland, Washington  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy developed this EIS to examine the potential environmental impacts of final disposal options for legacy and future radioactive defense wastes stored at the Hanford Site.

225

Remote-Handled Transuranic Content Codes  

SciTech Connect (OSTI)

The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document representsthe development of a uniform content code system for RH-TRU waste to be transported in the 72-Bcask. It will be used to convert existing waste form numbers, content codes, and site-specificidentification codes into a system that is uniform across the U.S. Department of Energy (DOE) sites.The existing waste codes at the sites can be grouped under uniform content codes without any lossof waste characterization information. The RH-TRUCON document provides an all-encompassing|description for each content code and compiles this information for all DOE sites. Compliance withwaste generation, processing, and certification procedures at the sites (outlined in this document foreach content code) ensures that prohibited waste forms are not present in the waste. The contentcode gives an overall description of the RH-TRU waste material in terms of processes and|packaging, as well as the generation location. This helps to provide cradle-to-grave traceability ofthe waste material so that the various actions required to assess its qualification as payload for the72-B cask can be performed. The content codes also impose restrictions and requirements on themanner in which a payload can be assembled.The RH-TRU Waste Authorized Methods for Payload Control (RH-TRAMPAC), Appendix 1.3.7of the 72-B Cask Safety Analysis Report (SAR), describes the current governing procedures|applicable for the qualification of waste as payload for the 72-B cask. The logic for this|classification is presented in the 72-B Cask SAR. Together, these documents (RH-TRUCON,|RH-TRAMPAC, and relevant sections of the 72-B Cask SAR) present the foundation and|justification for classifying RH-TRU waste into content codes. Only content codes described in thisdocument can be considered for transport in the 72-B cask. Revisions to this document will be madeas additional waste qualifies for transport. |Each content code uniquely identifies the generated waste and provides a system for tracking theprocess and packaging history. Each content code begins with a two-letter site abbreviation thatindicates the shipper of the RH-TRU waste. The site-specific letter designations for each of the|DOE sites are provided in Table 1. Not all of the sites listed in Table 1 have generated/stored RH-|TRU waste.

Washington TRU Solutions

2001-08-01T23:59:59.000Z

226

COMPLETION OF THE TRANSURANIC GREATER CONFINEMENT DISPOSAL BOREHOLE PERFORMANCE ASSESSMENT FOR THE NEVADA TEST SITE  

SciTech Connect (OSTI)

Classified transuranic material that cannot be shipped to the Waste Isolation Pilot Plant in New Mexico is stored in Greater Confinement Disposal boreholes in the Area 5 Radioactive Waste Management Site on the Nevada Test Site. A performance assessment was completed for the transuranic inventory in the boreholes and submitted to the Transuranic Waste Disposal Federal Review Group. The performance assessment was prepared by Sandia National Laboratories on behalf of the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office using an iterative methodology that assessed radiological releases from the intermediate depth disposal configuration against the regulatory requirements of the 1985 version of 40 CFR 191 of the U.S. Environmental Protection Agency. The transuranic materials are stored at 21 to 37 m depth (70 to 120 ft) in large diameter boreholes constructed in the unsaturated alluvial deposits of Frenchman Flat. Hydrologic processes that affect long- term isolation of the radionuclides are dominated by extremely slow upward rates of liquid/vapor advection and diffusion; there is no downward pathway under current climatic conditions and there is no recharge to groundwater under future ''glacial'' climatic conditions. A Federal Review Team appointed by the Transuranic Waste Disposal Federal Review Group reviewed the Greater Confinement Disposal performance assessment and found that the site met the majority of the regulatory criteria of the 1985 and portions of the 1993 versions of 40 CFR 191. A number of technical and procedural issues required development of supplemental information that was incorporated into a final revision of the performance assessment. These issues include inclusion of radiological releases into the complementary cumulative distribution function for the containment requirements associated with drill cuttings from inadvertent human intrusion, verification of mathematical models used in the performance assessment, inclusion of dose calculations from collocated low-level waste in the boreholes for the individual protection requirements, further assessments of engineered barriers and conditions associated with the assurance requirements, and expansion of documentation provided for assessing the groundwater protection requirements. The Transuranic Waste Disposal Federal Review Group approved the performance assessment for Greater Confinement Disposal boreholes in 2001 and did not approve the Application of the Assurance Requirements. Remaining issues concerned with engineered barriers and the multiple aspects of the Assurance Requirements will be resolved at the time of closure of the Area 5 Radioactive Waste Management Site. This is the first completion and acceptance of a performance assessment for transuranic materials under the U.S. Department of Energy self-regulation. The Greater Confinement Disposal boreholes are only the second waste disposal configuration to meet the safety regulatory requirements of 40 CFR 191.

Colarusso, Angela; Crowe, Bruce; Cochran, John R.

2003-02-27T23:59:59.000Z

227

Management of Salt Waste from Electrochemical Processing of Used Nuclear Fuel  

SciTech Connect (OSTI)

Electrochemical processing of used nuclear fuel involves operation of one or more cells containing molten salt electrolyte. Processing of the fuel results in contamination of the salt via accumulation of fission products and transuranic (TRU) actinides. Upon reaching contamination limits, the salt must be removed and either disposed or treated to remove the contaminants and recycled back to the process. During development of the Experimental Breeder Reactor-II spent fuel treatment process, waste salt from the electrorefiner was to be stabilized in a ceramic waste form and disposed of in a high-level waste repository. With the cancellation of the Yucca Mountain high-level waste repository, other options are now being considered. One approach that involves direct disposal of the salt in a geologic salt formation has been evaluated. While waste forms such as the ceramic provide near-term resistance to corrosion, they may not be necessary to ensure adequate performance of the repository. To improve the feasibility of direct disposal, recycling a substantial fraction of the useful salt back to the process equipment could minimize the volume of the waste. Experiments have been run in which a cold finger is used for this purpose to crystallize LiCl from LiCl/CsCl. If it is found to be unsuitable for transportation, the salt waste could also be immobilized in zeolite without conversion to the ceramic waste form.

Michael F. Simpson; Michael N. Patterson; Joon Lee; Yifeng Wang; Joshua Versey; Ammon Williams; Supathorn Phongikaroon; James Allensworth; Man-Sung Yim

2013-10-01T23:59:59.000Z

228

Management of salt waste from electrochemical processing of used nuclear fuel  

SciTech Connect (OSTI)

Electrochemical processing of used nuclear fuel involves operation of one or more cells containing molten salt electrolyte. Processing of the fuel results in contamination of the salt via accumulation of fission products and transuranic (TRU) actinides. Upon reaching contamination limits, the salt must be removed and either disposed or treated to remove the contaminants and recycled back to the process. During development of the Experimental Breeder Reactor-II spent fuel treatment process, waste salt from the electro-refiner was to be stabilized in a ceramic waste form and disposed of in a high-level waste repository. With the cancellation of the Yucca Mountain high-level waste repository, other options are now being considered. One approach that involves direct disposal of the salt in a geologic salt formation has been evaluated. While waste forms such as the ceramic provide near-term resistance to corrosion, they may not be necessary to ensure adequate performance of the repository. To improve the feasibility of direct disposal, recycling a substantial fraction of the useful salt back to the process equipment could minimize the volume of the waste. Experiments have been run in which a cold finger is used for this purpose to crystallize LiCl from LiCl/CsCl. If it is found to be unsuitable for transportation, the salt waste could also be immobilized in zeolite without conversion to the ceramic waste form. (authors)

Simpson, M.F.; Patterson, M.N. [Idaho National Laboratory, P.O. Box 1625, Idaho Falls, Idaho 83415 (United States); Lee, J.; Wang, Y. [Sandia National Laboratory, Albuquerque, NM (United States); Versey, J.; Phongikaroon, S. [University of Idaho, Idaho Falls, ID (United States)

2013-07-01T23:59:59.000Z

229

The WIPP Hazardous Waste Facility Permit Improvements--2007 Update  

SciTech Connect (OSTI)

The most significant changes to the Waste Isolation Pilot Plant Hazardous Waste Facility Permit to date were completed during the past year with the implementation of significant revisions to the Waste Analysis Plan and the authorization to dispose of remote-handled transuranic waste. The modified Permit removes the requirement for reporting headspace gas sampling and analysis results for every container of transuranic mixed waste and provides for the use of radiography and visual examination to confirm a statistically representative subpopulation of the waste stream in each waste shipment as well as other changes that streamline the analytical data management process. Implementation began on November 17, 2006. (authors)

Kehrman, R.; Most, W. [Washington Regulatory and Environmental Services, Carlsbad, NM (United States)

2007-07-01T23:59:59.000Z

230

Tank Waste and Waste Processing | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

breakthrough immobilization technologies. Currently projects are focusing on: In-tank sludge washing at Hanford Enhanced waste processing at Idaho, Hanford, and Savannah River...

231

A Cask Processing Enclosure for the TRU Waste Processing Center - 13408  

SciTech Connect (OSTI)

This paper will discuss the key elements considered in the design, construction, and use of an enclosure system built for the TRU Waste Processing Center (TWPC). The TWPC system is used for the repackaging and volume reduction of items contaminated with radioactive material, hazardous waste and mixed waste. The modular structural steel frame and stainless steel skin was designed for rapid field erection by the use of interchangeable self-framing panel sections to allow assembly of a sectioned containment building and for ease of field mobility. The structure was installed on a concrete floor inside of an outer containment building. The major sections included an Outer Cask Airlock, Inner Cask Airlock, Cask Process Area, and Personnel Airlocks. Casks in overpacks containing transuranic waste are brought in via an inter-site transporter. The overpack lid is removed and the cask/overpack is transferred into the Outer Cask Airlock. A contamination cover is installed on the overpack body and the Outer Cask Airlock is closed. The cask/overpack is transferred into the Inner Cask Airlock on a cask bogie and the Inner Cask Airlock is closed. The cask lid is removed and the cask is transferred into the Cask Process Area where it is placed on a cask tilting station. Once the Cask Processing Area is closed, the cask tilt station is activated and wastes are removed, size reduced, then sorted and re-packaged into drums and standard waste boxes through bag ports. The modular system was designed and built as a 'Fast Track' project at IP Systems in Broomfield Colorado and then installed and is currently in use at the DOE TWPC located near Oak Ridge, Tennessee. (authors)

Newman, John T.; Mendez, Nicholas [IP Systems, Inc., 2685 Industrial Lane, Broomfield, Colorado 80020 (United States)] [IP Systems, Inc., 2685 Industrial Lane, Broomfield, Colorado 80020 (United States)

2013-07-01T23:59:59.000Z

232

Zone Freezing Study for Pyrochemical Process Waste Minimization  

SciTech Connect (OSTI)

Pyroprocessing technology is a non-aqueous separation process for treatment of used nuclear fuel. At the heart of pyroprocessing lies the electrorefiner, which electrochemically dissolves uranium from the used fuel at the anode and deposits it onto a cathode. During this operation, sodium, transuranics, and fission product chlorides accumulate in the electrolyte salt (LiCl-KCl). These contaminates change the characteristics of the salt overtime and as a result, large volumes of contaminated salt are being removed, reprocessed and stored as radioactive waste. To reduce the storage volumes and improve recycling process for cost minimization, a salt purification method called zone freezing has been proposed at Korea Atomic Energy Research Institute (KAERI). Zone freezing is melt crystallization process similar to the vertical Bridgeman method. In this process, the eutectic salt is slowly cooled axially from top to bottom. As solidification occurs, the fission products are rejected from the solid interface and forced into the liquid phase. The resulting product is a grown crystal with the bulk of the fission products near the bottom of the salt ingot, where they can be easily be sectioned and removed. Despite successful feasibility report from KAERI on this process, there were many unexplored parameters to help understanding and improving its operational routines. Thus, this becomes the main motivation of this proposed study. The majority of this work has been focused on the CsCl-LiCl-KCl ternary salt. CeCl3-LiCl-KCl was also investigated to check whether or not this process is feasible for the trivalent species—surrogate for rare-earths and transuranics. For the main part of the work, several parameters were varied, they are: (1) the retort advancement rate—1.8, 3.2, and 5.0 mm/hr, (2) the crucible lid configurations—lid versus no-lid, (3) the amount or size of mixture—50 and 400 g, (4) the composition of CsCl in the salt—1, 3, and 5 wt%, and (5) the temperature differences between the high and low furnace zones—200 and 300 ?C. During each experiment, the temperatures at selected locations around the crucible were measured and recorded to provide temperature profiles. Following each experiment, samples were collected and elemental analysis was done to determine the composition of iii the salt. Several models—non-mixed, well-mixed, Favier, and hybrid—were explored to describe the zone freezing process. For CsCl-LiCl-KCl system, experimental results indicate that through this process up to 90% of the used salt can be recycled, effectively reducing waste volume by a factor of ten. The optimal configuration was found to be a 5.0 mm/hr rate with a lid configuration and a ?T of 200°C. The larger 400 g mixtures had recycle percentages similar to the 50 g mixtures; however, the throughput per time was greater for the 400 g case. As a result, the 400 g case is recommended. For the CeCl3-LiCl-KCl system, the result implies that it is possible to use this process to separate the rare-earth and transuranics chlorides. Different models were applied to only CsCl ternary system. The best fit model was the hybrid model as a result of a solute transport transition from non- mixed to well-mixed throughout the growing process.

Ammon Williams

2012-05-01T23:59:59.000Z

233

Process for remediation of plastic waste  

DOE Patents [OSTI]

A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of about 700.degree. C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically carbon nanotubes having a partially filled core (encapsulated) adjacent to one end of the nanotube. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.

Pol, Vilas G; Thiyagarajan, Pappannan

2013-11-12T23:59:59.000Z

234

Process for remediation of plastic waste  

DOE Patents [OSTI]

A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of 700.degree. C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically egg-shaped and spherical-shaped solid carbons. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.

Pol, Vilas G. (Westmont, IL); Thiyagarajan, Pappannan (Germantown, MD)

2012-04-10T23:59:59.000Z

235

Evaluation of the WIPP Project`s compliance with the EPA radiation protection standards for disposal of transuranic waste  

SciTech Connect (OSTI)

The US Environmental Protection Agency`s (EPA) proposed rule to certify that the Waste Isolation Pilot Plant (WIPP) meets compliance with the long-term radiation protection standards for geologic repositories (40CFR191 Subparts B and C), is one of the most significant milestones to date for the WIPP project in particular, and for the nuclear waste issue in general. The Environmental Evaluation Group (EEG) has provided an independent technical oversight for the WIPP project since 1978, and is responsible for many improvements in the location, design, and testing of various aspects of the project, including participation in the development of the EPA standards since the early 1980s. The EEG reviewed the development of documentation for assessing the WIPP`s compliance by the Sandia National Laboratories following the 1985 promulgation by EPA, and provided many written and verbal comments on various aspects of this effort, culminating in the overall review of the 1992 performance assessment. For the US Department of Energy`s (DOE) compliance certification application (CCA), the EEG provided detailed comments on the draft CCA in March, 1996, and additional comments through unpublished letters in 1997 (included as Appendices 8.1 and 8.2 in this report). Since the October 30, 1997, publication of the EPA`s proposed rule to certify WIPP, the EEG gave presentations on important issues to the EPA on December 10, 1997, and sent a December 31, 1997 letter with attachments to clarify those issues (Appendix 8.3). The EEG has raised a number of questions that may have an impact on compliance. In spite of the best efforts by the EEG, the EPA reaction to reviews and suggestions has been slow and apparently driven by legal considerations. This report discusses in detail the questions that have been raised about containment requirements. Also discussed are assurance requirements, groundwater protection, individual protection, and an evaluation of EPA`s responses to EEG`s comments.

Neill, R.H.; Chaturvedi, L.; Rucker, D.F.; Silva, M.K.; Walker, B.A.; Channell, J.K.; Clemo, T.M. [Environmental Evaluation Group, Albuquerque, NM (United States)] [Environmental Evaluation Group, Albuquerque, NM (United States); [Environmental Evaluation Group, Carlsbad, NM (United States)

1998-03-01T23:59:59.000Z

236

Transuranic Waste Processing Center Oak Ridge Site Specific Advisory Board May 14, 2014  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomen Owned SmallOf The 2012 Greenbuy3 Archive Transportation Fact ofATEnergy

237

A Robust Power Remote Manipulator for Use in Waste Sorting, Processing, and Packaging - 12158  

SciTech Connect (OSTI)

Disposition of radioactive waste is one of the Department of Energy's (DOE's) highest priorities. A critical component of the waste disposition strategy is shipment of Transuranic (TRU) waste from DOE's Oak Ridge Reservation to the Waste Isolation Plant Project (WIPP) in Carlsbad, New Mexico. This is the mission of the DOE TRU Waste Processing Center (TWPC). The remote-handled TRU waste at the Oak Ridge Reservation is currently in a mixed waste form that must be repackaged in to meet WIPP Waste Acceptance Criteria (WAC). Because this remote-handled legacy waste is very diverse, sorting, size reducing, and packaging will require equipment flexibility and strength that is not possible with standard master-slave manipulators. To perform the wide range of tasks necessary with such diverse, highly contaminated material, TWPC worked with S.A. Technology (SAT) to modify SAT's Power Remote Manipulator (PRM) technology to provide the processing center with an added degree of dexterity and high load handling capability inside its shielded cells. TWPC and SAT incorporated innovative technologies into the PRM design to better suit the operations required at TWPC, and to increase the overall capability of the PRM system. Improving on an already proven PRM system will ensure that TWPC gains the capabilities necessary to efficiently complete its TRU waste disposition mission. The collaborative effort between TWPC and S.A. Technology has yielded an extremely capable and robust solution to perform the wide range of tasks necessary to repackage TRU waste containers at TWPC. Incorporating innovative technologies into a proven manipulator system, these PRMs are expected to be an important addition to the capabilities available to shielded cell operators. The PRMs provide operators with the ability to reach anywhere in the cell, lift heavy objects, perform size reduction associated with the disposition of noncompliant waste. Factory acceptance testing of the TWPC Powered Remote Manipulators has completed at SAT's Colorado facility, and on-site training at TWPC is scheduled to start in early 2012. (authors)

Cole, Matt; Martin, Scott [S.A. Technology, Loveland, Colorado 80537, Transuranic Waste Processing Center, Lenoir City, TN 37771 (United States)

2012-07-01T23:59:59.000Z

238

Estimation and characterization of decontamination and decommissioning solid waste expected from the Plutonium Finishing Plant  

SciTech Connect (OSTI)

Purpose of the study was to estimate the amounts of equipment and other materials that are candidates for removal and subsequent processing in a solid waste facility when the Hanford Plutonium Finishing Plant is decontaminated and decommissioned. (Building structure and soil are not covered.) Results indicate that {approximately}5,500 m{sup 3} of solid waste is expected to result from the decontamination and decommissioning of the Pu Finishing Plant. The breakdown of the volumes and percentages of waste by category is 1% dangerous solid waste, 71% low-level waste, 21% transuranic waste, 7% transuranic mixed waste.

Millar, J.S.; Pottmeyer, J.A.; Stratton, T.J. [and others

1995-01-01T23:59:59.000Z

239

Crystalline Ceramic Waste Forms: Comparison Of Reference Process For Ceramic Waste Form Fabrication  

SciTech Connect (OSTI)

The research conducted in this work package is aimed at taking advantage of the long term thermodynamic stability of crystalline ceramics to create more durable waste forms (as compared to high level waste glass) in order to reduce the reliance on engineered and natural barrier systems. Durable ceramic waste forms that incorporate a wide range of radionuclides have the potential to broaden the available disposal options and to lower the storage and disposal costs associated with advanced fuel cycles. Assemblages of several titanate phases have been successfully demonstrated to incorporate radioactive waste elements, and the multiphase nature of these materials allows them to accommodate variation in the waste composition. Recent work has shown that they can be produced from a melting and crystallization process. The objective of this report is to explore the phase formation and microstructural differences between lab scale melt processing in varying gas environments with alternative densification processes such as Hot Pressing (HP) and Spark Plasma Sintering (SPS). The waste stream used as the basis for the development and testing is a simulant derived from a combination of the projected Cs/Sr separated stream, the Trivalent Actinide - Lanthanide Separation by Phosphorous reagent Extraction from Aqueous Komplexes (TALSPEAK) waste stream consisting of lanthanide fission products, the transition metal fission product waste stream resulting from the transuranic extraction (TRUEX) process, and a high molybdenum concentration with relatively low noble metal concentrations. Melt processing as well as solid state sintering routes SPS and HP demonstrated the formation of the targeted phases; however differences in microstructure and elemental partitioning were observed. In SPS and HP samples, hollandite, pervoskite/pyrochlore, zirconolite, metallic alloy and TiO{sub 2} and Al{sub 2}O{sub 3} were observed distributed in a network of fine grains with small residual pores. The titanate phases that incorporate M{sup +3} rare earth elements were observed to be distinct phases (ex. Nd{sub 2}Ti{sub 2}O{sub 7}) with less degree of substitution as compared to the more homogeneous melt processed samples where a high degree of substitution and variation of composition within grains was observed. Liquid phase sintering was enhanced in reducing gas environments and resulted in large (10-200 microns) irregular shaped grains along with large voids associated with the melt process; SPS and HP samples exhibited finer grain size with smaller voids. Metallic alloys were observed in the bulk of the sample for SPS and HP samples, but were found at the bottom of the crucible in melt processed trials. These results indicate that for a first melter trial, the targeted phases can be formed in air by utilizing Ti/TiO{sub 2} additives which aid phase formation and improve the electrical conductivity. Ultimately, a melter run in reducing gas environments would be beneficial to study differences in phase formation and elemental partitioning.

Brinkman, K. S. [Savannah River National Laboratory; Marra, J. C. [Savannah River National Laboratory; Amoroso, J. [Savannah River National Laboratory; Tang, M. [Los Alamos National Laboratory

2013-08-22T23:59:59.000Z

240

Performance Assessment for Transuranic Waste  

National Nuclear Security Administration (NNSA)

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241

Establishment of a Cost-Effective and Robust Planning Basis for the Processing of M-91 Waste at the Hanford Site  

SciTech Connect (OSTI)

This report identifies and evaluates viable alternatives for the accelerated processing of Hanford Site transuranic (TRU) and mixed low-level wastes (MLLW) that cannot be processed using existing site capabilities. Accelerated processing of these waste streams will lead to earlier reduction of risk and considerable life-cycle cost savings. The processing need is to handle both oversized MLLW and TRU containers as well as containers with surface contact dose rates greater than 200 mrem/hr. This capability is known as the ''M-91'' processing capability required by the Tri-Party Agreement milestone M-91--01. The new, phased approach proposed in this evaluation would use a combination of existing and planned processing capabilities to treat and more easily manage contact-handled waste streams first and would provide for earlier processing of these wastes.

Johnson, Wayne L.; Parker, Brian M.

2004-07-30T23:59:59.000Z

242

Management of Transuranic Contaminated Material  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

To establish guidelines for the generation, treatment, packaging, storage, transportation, and disposal of transuranic (TRU) contaminated material.

1982-09-30T23:59:59.000Z

243

Transuranic Contamination in Sediment and Groundwater at the U.S. DOE Hanford Site  

SciTech Connect (OSTI)

A review of transuranic radionuclide contamination in sediments and groundwater at the DOE’s Hanford Site was conducted. The review focused primarily on plutonium-239/240 and americium-241; however, other transuranic nuclides were discussed as well, including neptunium-237, plutonium-238, and plutonium-241. The scope of the review included liquid process wastes intentionally disposed to constructed waste disposal facilities such as trenches and cribs, burial grounds, and unplanned releases to the ground surface. The review did not include liquid wastes disposed to tanks or solid wastes disposed to burial grounds. It is estimated that over 11,800 Ci of plutonium-239, 28,700 Ci of americium-241, and 55 Ci of neptunium-237 have been disposed as liquid waste to the near surface environment at the Hanford Site. Despite the very large quantities of transuranic contaminants disposed to the vadose zone at Hanford, only minuscule amounts have entered the groundwater. Currently, no wells onsite exceed the DOE derived concentration guide for plutonium-239/240 (30 pCi/L) or any other transuranic contaminant in filtered samples. The DOE derived concentration guide was exceeded by a small fraction in unfiltered samples from one well (299-E28-23) in recent years (35.4 and 40.4 pCi/L in FY 2006). The primary reason that disposal of these large quantities of transuranic radionuclides directly to the vadose zone at the Hanford Site has not resulted in widespread groundwater contamination is that under the typical oxidizing and neutral to slightly alkaline pH conditions of the Hanford vadose zone, transuranic radionuclides (plutonium and americium in particular) have a very low solubility and high affinity for surface adsorption to mineral surfaces common within the Hanford vadose zone. Other important factors are the fact that the vadose zone is typically very thick (hundreds of feet) and the net infiltration rate is very low due to the desert climate. In some cases where transuranic radionuclides have been co-disposed with acidic liquid waste, transport through the vadose zone for considerable distances has occurred. For example, at the 216-Z-9 Crib, plutonium-239 and americium-241 have moved to depths in excess of 36 m (118 ft) bgs. Acidic conditions increase the solubility of these contaminants and reduce adsorption to mineral surfaces. Subsequent neutralization of the acidity by naturally occurring calcite in the vadose zone (particularly in the Cold Creek unit) appears to have effectively stopped further migration. The vast majority of transuranic contaminants disposed to the vadose zone on the Hanford Site (10,200 Ci [86%] of plutonium-239; 27,900 Ci [97%] of americium-241; and 41.8 Ci [78%] of neptunium-237) were disposed in sites within the PFP Closure Zone. This closure zone is located within the 200 West Area (see Figures 1.1 and 3.1). Other closure zones with notably high quantities of transuranic contaminant disposal include the T Farm Zone with 408 Ci (3.5%) plutonium-239, the PUREX Zone with 330 Ci (2.8%) plutonium-239, 200-W Ponds Zone with 324 Ci (2.8%) plutonium-239, B Farm Zone with 183 Ci (1.6%) plutonium-239, and the REDOX Zone with 164 Ci (1.4%) plutonium 239. Characterization studies for most of the sites reviewed in the document are generally limited. The most prevalent characterization methods used were geophysical logging methods. Characterization of a number of sites included laboratory analysis of borehole sediment samples specifically for radionuclides and other contaminants, and geologic and hydrologic properties. In some instances, more detailed research level studies were conducted. Results of these studies were summarized in the document.

Cantrell, Kirk J.

2009-08-20T23:59:59.000Z

244

Use of the Waste-Incidental-to-Reprocessing Citation Process at the West Valley Demonstration Project - 12250  

SciTech Connect (OSTI)

The West Valley Demonstration Project recently achieved a breakthrough in management of radioactive waste from reprocessing of spent nuclear fuel by taking advantage of lessons learned at other Department of Energy (DOE) sites in implementation of the waste-incidental-to-reprocessing citation process of DOE Manual 435.1-1, Radioactive Waste Management. This breakthrough involved a revision to the site procedure on waste-incidental to reprocessing. This procedure revision served as the basis for a determination by the DOE West Valley field office using the citation process that three secondary waste streams consisting of equipment that had once been contaminated by association with HLW are not HLW following decontamination and may be disposed of as low-level waste (LLW) or transuranic waste. These waste streams, which comprised much of the approximately 380 cubic meters of West Valley waste contaminated by association with HLW, included several vessels and certain tank farm equipment. By making use of lessons learned in use of the citation process by other DOE sites and information developed to support use of the citation process at the Hanford site and the Savannah River Site, the team developed a technical basis for showing that use of the citation process of DOE Manual 435.1-1 for the three new waste stream was appropriate and technically justified. The Waste Management Working Group of the EFCOG assisted in transferring lessons learned by drawing on experience from around the DOE complex. This process shared knowledge about effective implementation of the citation process in a manner that proved to be beneficial to the West Valley Demonstration Project and resulted in a technical basis document that could be used to determine that the three new waste streams were not HLW. (authors)

Sullivan, Dan; Suttora, Linda [U.S. Department of Energy (United States); Goldston, Sonny [EnergySolutions - USA (United States); Petras, Robert [Savannah River Remediation (United States); Rowell, Laurene [URS Corporation (United States); McNeil, Jim [Consultant - USA (United States)

2012-07-01T23:59:59.000Z

245

Materials selection for process equipment in the Hanford waste vitrification plant  

SciTech Connect (OSTI)

The Hanford Waste Vitrification Plant (HWVP) is being designed to vitrify defense liquid high-level wastes and transuranic wastes stored at Hanford. The HWVP Functional Design Criteria (FDC) requires that materials used for fabrication of remote process equipment and piping in the facility be compatible with the expected waste stream compositions and process conditions. To satisfy FDC requirements, corrosion-resistant materials have been evaluated under simulated HWVP-specific conditions and recommendations have been made for HWVP applications. The materials recommendations provide to the project architect/engineer the best available corrosion rate information for the materials under the expected HWVP process conditions. Existing data and sound engineering judgement must be used and a solid technical basis must be developed to define an approach to selecting suitable construction materials for the HWVP. This report contains the strategy, approach, criteria, and technical basis developed for selecting materials of construction. Based on materials testing specific to HWVP and on related outside testing, this report recommends for constructing specific process equipment and identifies future testing needs to complete verification of the performance of the selected materials. 30 refs., 7 figs., 11 tabs.

Elmore, M R; Jensen, G A

1991-07-01T23:59:59.000Z

246

Acceptable Knowledge Summary Report for Waste Stream: SR-T001-221F-HET/Drums  

SciTech Connect (OSTI)

Since beginning operations in 1954, the Savannah River Site FB-Line produced Weapons Grade Plutonium for the United States National Defense Program. The facility mission was mainly to process dilute plutonium solution received from the 221-F Canyon into highly purified plutonium metal. As a result of various activities (maintenance, repair, clean up, etc.) in support of the mission, the facility generated a transuranic heterogeneous debris waste stream. Prior to January 25, 1990, the waste stream was considered suspect mixed transuranic waste (based on potential for inclusion of F-Listed solvent rags/wipes) and is not included in this characterization. Beginning January 25, 1990, Savannah River Site began segregation of rags and wipes containing F-Listed solvents thus creating a mixed transuranic waste stream and a non-mixed transuranic waste stream. This characterization addresses the non-mixed transuranic waste stream packaged in 55-gallon drums after January 25, 1990.Characterization of the waste stream was achieved using knowledge of process operations, facility safety basis documentation, facility specific waste management procedures and storage / disposal records. The report is fully responsive to the requirements of Section 4.0 "Acceptable Knowledge" from the WIPP Transuranic Waste Characterization Quality Assurance Plan, CAO-94-1010, and provides a sound, (and auditable) characterization that satisfies the WIPP criteria for Acceptable Knowledge.

Lunsford, G.F.

1998-10-26T23:59:59.000Z

247

Voluntary Protection Program Onsite Review, Salt Waste Processing...  

Broader source: Energy.gov (indexed) [DOE]

Salt Waste Processing Facility Construction Project - February 2013 Voluntary Protection Program Onsite Review, Salt Waste Processing Facility Construction Project - February 2013...

248

Examples of Process Modifications that Reduce Waste  

E-Print Network [OSTI]

The ideal approach to reducing or eliminating waste products is to avoid making them in the first place. This article will examine numerous process modifications that have accomplished that goal. We'll look at changes to raw materials, reactors...

Nelson, K. E.

249

Resource Conservation and Recovery Act, Part B Permit Application [for the Waste Isolation Pilot Plant (WIPP)]. Volume 2, Chapter C, Appendix C1--Chapter C, Appendix C3 (beginning), Revision 3  

SciTech Connect (OSTI)

This volume contains appendices for the following: Rocky Flats Plant and Idaho National Engineering Laboratory waste process information; TRUPACT-II content codes (TRUCON); TRUPACT-II chemical list; chemical compatibility analysis for Rocky Flats Plant waste forms; chemical compatibility analysis for waste forms across all sites; TRU mixed waste characterization database; hazardous constituents of Rocky Flats Transuranic waste; summary of waste components in TRU waste sampling program at INEL; TRU waste sampling program; and waste analysis data.

Not Available

1993-03-01T23:59:59.000Z

250

Process for treating alkaline wastes for vitrification  

DOE Patents [OSTI]

According to its major aspects and broadly stated, the present invention is a process for treating alkaline waste materials, including high level radioactive wastes, for vitrification. The process involves adjusting the pH of the wastes with nitric acid, adding formic acid (or a process stream containing formic acid) to reduce mercury compounds to elemental mercury and MnO{sub 2} to the Mn(II) ion, and mixing with class formers to produce a melter feed. The process minimizes production of hydrogen due to noble metal-catalyzed formic acid decomposition during, treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product. An important feature of the present invention is the use of different acidifying and reducing, agents to treat the wastes. The nitric acid acidifies the wastes to improve yield stress and supplies acid for various reactions; then the formic acid reduces mercury compounds to elemental mercury and MnO{sub 2}) to the Mn(II) ion. When the pH of the waste is lower, reduction of mercury compounds and MnO{sub 2}) is faster and less formic acid is needed, and the production of hydrogen caused by catalytically-active noble metals is decreased.

Hsu, Chia-lin W.

1994-01-01T23:59:59.000Z

251

Exploratory study of complexant concentrate waste processing  

SciTech Connect (OSTI)

The purpose of this exploratory study, conducted by Pacific Northwest Laboratory for Westinghouse Hanford Company, was to determine the effect of applying advanced chemical separations technologies to the processing and disposal of high-level wastes (HLW) stored in underground tanks. The major goals of this study were to determine (1) if the wastes can be partitioned into a small volume of HLW plus a large volume of low-level waste (LLW), and (2) if the activity in the LLW can be lowered enough to meet NRC Class LLW criteria. This report presents the results obtained in a brief scouting study of various processes for separating radionuclides from Hanford complexant concentrate (CC) waste.

Lumetta, G.J.; Bray, L.A.; Kurath, D.E.; Morrey, J.R.; Swanson, J.L.; Wester, D.W.

1993-02-01T23:59:59.000Z

252

Final Environmental Impact Statement for Treating Transuranic (TRU)/Alpha Low-level Waste at the Oak Ridge National Laboratory Oak Ridge, Tennessee  

SciTech Connect (OSTI)

The DOE proposes to construct, operate, and decontaminate/decommission a TRU Waste Treatment Facility in Oak Ridge, Tennessee. The four waste types that would be treated at the proposed facility would be remote-handled TRU mixed waste sludge, liquid low-level waste associated with the sludge, contact-handled TRU/alpha low-level waste solids, and remote-handled TRU/alpha low-level waste solids. The mixed waste sludge and some of the solid waste contain metals regulated under the Resource Conservation and Recovery Act and may be classified as mixed waste. This document analyzes the potential environmental impacts associated with five alternatives--No Action, the Low-Temperature Drying Alternative (Preferred Alternative), the Vitrification Alternative, the Cementation Alternative, and the Treatment and Waste Storage at Oak Ridge National Laboratory (ORNL) Alternative.

N /A

2000-06-30T23:59:59.000Z

253

E-Print Network 3.0 - active nuclear wastes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

disposal site for transuranic (TRU) radio- active waste created during... , americium, curium, and neptunium are created during the produc- tion of nuclear weapons. Transuranic...

254

1987 Oak Ridge model conference: Proceedings: Volume I, Part 3, Waste Management  

SciTech Connect (OSTI)

A conference sponsored by the United States Department of Energy (DOE), was held on waste management. Topics of discussion were transuranic waste management, chemical and physical treatment technologies, waste minimization, land disposal technology and characterization and analysis. Individual projects are processed separately for the data bases. (CBS)

Not Available

1987-01-01T23:59:59.000Z

255

Waste Heat Management Options for Improving Industrial Process...  

Broader source: Energy.gov (indexed) [DOE]

of waste heat streams, and options for recovery including Combined Heat and Power. Waste Heat Management Options for Improving Industrial Process Heating Systems...

256

Waste Minimization Study on Pyrochemical Reprocessing Processes  

SciTech Connect (OSTI)

Ideally a new pyro-process should not generate more waste, and should be at least as safe and cost effective as the hydrometallurgical processes currently implemented at industrial scale. This paper describes the thought process, the methodology and some results obtained by process integration studies to devise potential pyro-processes and to assess their capability of achieving this challenging objective. As example the assessment of a process based on salt/metal reductive extraction, designed for the reprocessing of Generation IV carbide spent fuels, is developed. Salt/metal reductive extraction uses the capability of some metals, aluminum in this case, to selectively reduce actinide fluorides previously dissolved in a fluoride salt bath. The reduced actinides enter the metal phase from which they are subsequently recovered; the fission products remain in the salt phase. In fact, the process is not so simple, as it requires upstream and downstream subsidiary steps. All these process steps generate secondary waste flows representing sources of actinide leakage and/or FP discharge. In aqueous processes the main solvent (nitric acid solution) has a low boiling point and evaporate easily or can be removed by distillation, thereby leaving limited flow containing the dissolved substance behind to be incorporated in a confinement matrix. From the point of view of waste generation, one main handicap of molten salt processes, is that the saline phase (fluoride in our case) used as solvent is of same nature than the solutes (radionuclides fluorides) and has a quite high boiling point. So it is not so easy, than it is with aqueous solutions, to separate solvent and solutes in order to confine only radioactive material and limit the final waste flows. Starting from the initial block diagram devised two years ago, the paper shows how process integration studies were able to propose process fittings which lead to a reduction of the waste variety and flows leading at an 'ideal' new block diagram allowing internal solvent recycling, and self eliminating reactants. This new flowsheet minimizes the quantity of inactive inlet flows that would have inevitably to be incorporated in a final waste form. The study identifies all knowledge gaps to be filled and suggest some possible R and D issues to confirm or infirm the feasibility of the proposed process fittings. (authors)

Boussier, H.; Conocar, O.; Lacquement, J. [CEA/DEN Valrho Marcoule/DRCP/SCPS/Pyrochemical Processes Laboratory, BP 17171 30207 Bagnols-sur-Ceze (France)

2006-07-01T23:59:59.000Z

257

Waste minimization by process modification  

SciTech Connect (OSTI)

A simulation of the Sohio process for the production of acrylonitrile from the catalytic ammoxidation of propylene has been performed, using published kinetic and thermodynamic data to illustrate the concepts of pollution prevention by process modification. The study has determined the reaction parameters which will minimize the production of by-products while maintaining the conversion of propylene above 80%. The reaction parameters studied were reactor type (plug flow reactor [PFR], continuous stirred tank reactor [CSTR], and fluidized bed reactor [FBC]), reaction temperature, residence time, and entering feed temperature. The minimum by-products were produced in an FBR operating at 450 C at a residence time of 7 seconds for a conversion of 81%.

Hopper, J.R.; Yaws, C.L.; Ho, T.C.; Vichailak, M. (Lamar Univ., Beaumont, TX (United States))

1993-01-01T23:59:59.000Z

258

Transuranic radionuclides from resuspension in the environment, a bibliography  

SciTech Connect (OSTI)

The purpose of this project was to compile a bibliography of references containing environmental transuranic radionuclide data. Our intent was to identify those parameters affecting transuranic radionuclide transport that may be generic and those that may be dependent on chemical form and/or environmental conditions. An understanding of the unique characteristics and similarities between source terms and environmental conditions relative to transuranic radionuclide transport and cycling will provide the ability to assess and predict the long term impact on man and the environment. An additional goal of our literature review, was to extract the ranges of environmental transuranic radionuclide data from the identified references for inclusion in a data base. Related to source term, these ranges of data can be used to calculate the dose to man from the radionuclides, and to perform uncertainty analyses on these dose assessments. On the basis of our reviews, we have arbitrarily outlined five general source terms. These are fallout, fuel cycle waste, accidents, disposal sites and resuspension. Resuspension of the transuranic radionuclides is an unique source term, in that the radionuclides can originate from any of the other source terms. If these transuranic radionuclides become resuspended into the air, they then become important as a source of inhaled radionuclides. This bibliography is a compilation of the references containing studies of plutonium and americium in the environment as a result of resuspension.

Stoker, A.C.; Shinn, J.H.; Noshkin, V.E. [and others

1994-04-01T23:59:59.000Z

259

Transuranic radionuclides dispersed into the aquatic environment, a bibliography  

SciTech Connect (OSTI)

The purpose of this project was to compile a bibliography of references containing environmental transuranic radionuclide data. Our intent was to identify those parameters affecting transuranic radionuclide transport that may be generic and those that may be dependent on chemical form and/or environmental conditions (i.e., site specific) in terrestrial, aquatic and atmospheric environments An understanding of the unique characteristics and similarities between source terms and environmental conditions relative to transuranic radionuclide transport and cycling will provide the ability to assess and predict the long term impact on man and the environment. An additional goal of our literature review, was to extract the ranges of environmental transuranic radionuclide data from the identified references for inclusion in a data base. Related to source term, these ranges of data can be used to calculate the dose to man from the radionuclides, and to perform uncertainty analyses on these dose assessments. On the basis of our reviews, we have arbitrarily outlined five general source terms. These are fallout, fuel cycle waste, accidents, disposal sites and resuspension. Resuspension of the transuranic radionuclides is a unique source term, in that the radionuclides can originate from any of the other source terms. If these transuranic radionuclides become resuspended into the air, they then become important as a source of inhaled radionuclides.

Noshkin, V.E.; Stoker, A.C.; Wong, Kai M. [and others

1994-04-01T23:59:59.000Z

260

Apply process integration to waste minimization  

SciTech Connect (OSTI)

This article presents a systematic method for identifying process modifications to minimize waste generation. It is based on the hierarchical decision procedure, which provides a framework for identifying process improvement options and evaluating heat and mass integration opportunities. The article deals specifically with an adaptation of the hierarchical decision approach for use in pollution abatement applications. The article also illustrates the use of the technique by applying it to the fluid catalytic cracking unit at Amoco Oil Co.'s Yorktown, VA, refinery.

Rossiter, A.P.; Spriggs, H.D. (Linnhoff March, Inc., Leesburg, VA (United States)); Klee, H. Jr. (Amoco Corp., Chicago, IL (United States))

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Process for treating alkaline wastes for vitrification  

DOE Patents [OSTI]

A process is described for treating alkaline wastes for vitrification. The process involves acidifying the wastes with an oxidizing agent such as nitric acid, then adding formic acid as a reducing agent, and then mixing with glass formers to produce a melter feed. The nitric acid contributes nitrates that act as an oxidant to balance the redox of the melter feed, prevent reduction of certain species to produce conducting metals, and lower the pH of the wastes to a suitable level for melter operation. The formic acid reduces mercury compounds to elemental mercury for removal by steam stripping, and MnO{sub 2} to the Mn(II) ion to prevent foaming of the glass melt. The optimum amounts of nitric acid and formic acid are determined in relation to the composition of the wastes, including the concentrations of mercury (II) and MnO{sub 2}, noble metal compounds, nitrates, formates and so forth. The process minimizes the amount of hydrogen generated during treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product. 4 figs.

Hsu, C.L.W.

1995-07-25T23:59:59.000Z

262

Process for treating alkaline wastes for vitrification  

DOE Patents [OSTI]

A process for treating alkaline wastes for vitrification. The process involves acidifying the wastes with an oxidizing agent such as nitric acid, then adding formic acid as a reducing agent, and then mixing with glass formers to produce a melter feed. The nitric acid contributes nitrates that act as an oxidant to balance the redox of the melter feed, prevent reduction of certain species to produce conducting metals, and lower the pH of the wastes to a suitable level for melter operation. The formic acid reduces mercury compounds to elemental mercury for removal by steam stripping, and MnO.sub.2 to the Mn(II) ion to prevent foaming of the glass melt. The optimum amounts of nitric acid and formic acid are determined in relation to the composition of the wastes, including the concentrations of mercury (II) and MnO.sub.2, noble metal compounds, nitrates, formates and so forth. The process minimizes the amount of hydrogen generated during treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product.

Hsu, Chia-lin W. (Augusta, GA)

1995-01-01T23:59:59.000Z

263

Waste minimization at a plutonium processing facility  

SciTech Connect (OSTI)

As part of Los Alamos National Laboratory`s (LANL) mission to reduce the nuclear danger throughout the world, the plutonium processing facility at LANL maintains expertise and skills in nuclear weapons technologies as well as leadership in all peaceful applications of plutonium technologies, including fuel fabrication for terrestrial and space reactors and heat sources and thermoelectric generators for space missions. Another near-term challenge resulted from two safety assessments performed by the Defense Nuclear Facilities Safety Board and the U.S. Department of Energy during the past two years. These assessments have necessitated the processing and stabilization of plutonium contained in tons of residues so that they can be stored safely for an indefinite period. This report describes waste streams and approaches to waste reduction of plutonium management.

Pillay, K.K.S. [Los Alamos National Laboratory, NM (United States)

1995-12-31T23:59:59.000Z

264

An approach for sampling solid heterogeneous waste at the Hanford Site waste receiving and processing and solid waste projects  

SciTech Connect (OSTI)

This paper addresses the problem of obtaining meaningful data from samples of solid heterogeneous waste while maintaining sample rates as low as practical. The Waste Receiving and Processing Facility, Module 1, at the Hanford Site in south-central Washington State will process mostly heterogeneous solid wastes. The presence of hazardous materials is documented for some packages and unknown for others. Waste characterization is needed to segregate the waste, meet waste acceptance and shipping requirements, and meet facility permitting requirements. Sampling and analysis are expensive, and no amount of sampling will produce absolute certainty of waste contents. A sampling strategy is proposed that provides acceptable confidence with achievable sampling rates.

Sexton, R.A.

1993-03-01T23:59:59.000Z

265

Supplement Analysis for Site-Wide Environmental Impact Statement for Continued Operation of Los Alamos National Laboratory -- Modification of Management Methods for Transuranic Waste Characterization at Los Alamos National Laboratory  

SciTech Connect (OSTI)

This Supplement Analysis (SA) has been prepared to determine if the Site-Wide Environmental Impact Statement for Continued Operations of Los Alamos National Laboratory (SWEIS) (DOE/EIS-0238) adequately addresses the environmental effects of a waste management proposal for installing and operating modular units for the characterization of transuranic (TRU) waste1 at the Los Alamos National Laboratory (LANL) Technical Area (TA)-54, Area G, or if the SWEIS needs to be supplemented. Council on Environmental Quality regulations at Title 40, Section 1502.9 (c) of the Code of Federal Regulations (40 CFR 1502.9[c]) require federal agencies to prepare a supplement to an EIS when an agency makes substantial changes in the proposed action that are relevant to environmental concerns or there are circumstances or information relevant to concerns and bearing on the proposed action or its impacts. This SA is prepared in accordance with Section 10 CFR 1021.314(c) of the Department of Energy's (DOE's) regulations for NEPA implementation stating that ''When it is unclear whether or not an EIS supplement is required, DOE shall prepare a Supplement Analysis.'' This SA specifically compares key impact assessment parameters of the waste management program evaluated in the SWEIS with those of a proposal that would change the approach of a portion of this management program. It also provides an explanation of any differences between the proposed action and activities described in the previous SWEIS analysis. DOE proposes to expedite the shipment of legacy TRU waste to the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. The Cerro Grande Fire in 2000 and events of September 11, 2001, have focused attention on the potential risk to the public and the credible security hazard posed by the amount of plutonium stored above ground at LANL and the increased necessity to safeguard our nation's nuclear waste. The safest place for defense-generated TRU waste has been determined to be DOE's permitted repository for TRU waste 2100 feet underground at WIPP. The proposed accelerated plan to dispose of TRU waste at WIPP would result in the complete disposition of LANL legacy TRU waste by 2010; this accelerated disposition would be 20 years ahead of schedule, at a savings of $500 million in life-cycle costs and result in 3,000 fewer shipments to WIPP. However, the current individual small facilities at LANL lack the buildings, equipment, and trained personnel to conduct efficient characterization activities on an increased scale. Installing new modular structures and equipment close to the drum storage location at TA-54 in housings designed for a large inventory and high throughput would support DOE's expedited shipment program by increasing the repackaging rate, and it would also decrease on-site transportation vulnerabilities.

N /A

2002-08-13T23:59:59.000Z

266

Double Shell Tank (DST) Process Waste Sampling Subsystem Specification  

SciTech Connect (OSTI)

This specification establishes the performance requirements and provides references to the requisite codes and standards to be applied to the Double-Shell Tank (DST) Process Waste Sampling Subsystem which supports the first phase of Waste Feed Delivery.

RASMUSSEN, J.H.

2000-05-03T23:59:59.000Z

267

Nondestructive radioassay for waste management: an assessment  

SciTech Connect (OSTI)

Nondestructive Assay (NDA) for Transuranic Waste Management is used to mean determining the amount of transuranic (TRU) isotopes in crates, drums, boxes, cans, or other containers without having to open the container. It also means determining the amount of TRU in soil, bore holes, and other environmental testing areas without having to go through extensive laboratory wet chemistry analyses. it refers to radioassay techniques used to check for contamination on objects after decontamination and to determine amounts of TRU in waste processing streams without taking samples to a laboratory. Gednerally, NDA instrumentation in this context refers to all use of radioassay which does not involve taking samples and using wet chemistry techniques. NDA instruments have been used for waste assay at some sites for over 10 years and other sites are just beginning to consider assay of wastes. The instrumentation used at several sites is discussed in this report. Almost all these instruments in use today were developed for special nuclear materials safeguards purposes and assay TRU waste down to the 500 nCi/g range. The need for instruments to assay alpha particle emitters at 10 nCi/g or less has risen from the wish to distinguish between Low Level Waste (LLW) and TRU Waste at the defined interface of 10 nCi/g. Wastes have historically been handled as TRU wastes if they were just suspected to be transuranically contaminated but their exact status was unknown. Economic and political considerations make this practice undesirable since it is easier and less costly to handle LLW. This prompted waste generators to want better instrumentation and led the Transuranic Waste Management Program to develop and test instrumentation capable of assaying many types of waste at the 10 nCi/g level. These instruments are discussed.

Lehmkuhl, G.D.

1981-06-01T23:59:59.000Z

268

Buried waste integrated demonstration technology integration process  

SciTech Connect (OSTI)

A Technology integration Process was developed for the Idaho National Energy Laboratories (INEL) Buried Waste Integrated Demonstration (BWID) Program to facilitate the transfer of technology and knowledge from industry, universities, and other Federal agencies into the BWID; to successfully transfer demonstrated technology and knowledge from the BWID to industry, universities, and other Federal agencies; and to share demonstrated technologies and knowledge between Integrated Demonstrations and other Department of Energy (DOE) spread throughout the DOE Complex. This document also details specific methods and tools for integrating and transferring technologies into or out of the BWID program. The document provides background on the BWID program and technology development needs, demonstrates the direction of technology transfer, illustrates current processes for this transfer, and lists points of contact for prospective participants in the BWID technology transfer efforts. The Technology Integration Process was prepared to ensure compliance with the requirements of DOE's Office of Technology Development (OTD).

Ferguson, J.S.; Ferguson, J.E.

1992-04-01T23:59:59.000Z

269

Buried waste integrated demonstration technology integration process  

SciTech Connect (OSTI)

A Technology integration Process was developed for the Idaho National Energy Laboratories (INEL) Buried Waste Integrated Demonstration (BWID) Program to facilitate the transfer of technology and knowledge from industry, universities, and other Federal agencies into the BWID; to successfully transfer demonstrated technology and knowledge from the BWID to industry, universities, and other Federal agencies; and to share demonstrated technologies and knowledge between Integrated Demonstrations and other Department of Energy (DOE) spread throughout the DOE Complex. This document also details specific methods and tools for integrating and transferring technologies into or out of the BWID program. The document provides background on the BWID program and technology development needs, demonstrates the direction of technology transfer, illustrates current processes for this transfer, and lists points of contact for prospective participants in the BWID technology transfer efforts. The Technology Integration Process was prepared to ensure compliance with the requirements of DOE`s Office of Technology Development (OTD).

Ferguson, J.S.; Ferguson, J.E.

1992-04-01T23:59:59.000Z

270

GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS  

SciTech Connect (OSTI)

Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require ultimate disposal when it is put to use. Each task three waste was evaluated for utilization potential based on its physical properties, bulk chemical composition, and mineral composition. Only one of the thirteen materials studied might be suitable for use as a pozzolanic concrete additive. However, many wastes appeared to be suitable for other high-volume uses such as blasting grit, fine aggregate for asphalt concrete, road deicer, structural fill material, soil stabilization additives, waste stabilization additives, landfill cover material, and pavement base course construction.

Edwin S. Olson; Charles J. Moretti

1999-11-01T23:59:59.000Z

271

Remote-handled transuranic system assessment. Volume 1  

SciTech Connect (OSTI)

This document identifies the necessary actions for addressing current questions concerning the safe and efficient disposal of remote-handled transuranic wastes that have been generated through Department of Energy activities. In addition, this document presents summaries of existing information and analyses regarding the potential alternatives for disposing of remote-handled (RH) transuranic (TRU) waste at the Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP). A further discussion of DOE`s approach for addressing RH-TRU issues is contained in the document, Waste Isolation Pilot Plant Remote-Handled Transuranic Waste Disposal Strategy, DOE/WIPP-95-1090 (DOE, 1995a). Of this stored and projected inventory, approximately 30% can be characterized with current technology and subsequently certified to meet the waste acceptance criteria for disposal at WIPP; characterization of the remaining 70% will require the use of alternative techniques. At most of the generator sites, characterization equipment and facilities need to be procured in order for the sites to certify waste for shipment either to WIPP or to an interim site. If surface dose rates are too high, the use of non-invasive techniques such as non-destructive examination (NDE) and non-destructive assay (NDA) may be precluded. Characterization methods using NDA can be effectively used on RH-TRU wastes with surface dose rates of less than 1.0 rem/hr (neutron); NDE methods are effective on waste with surface dose rates of less than 10 rem/hr (gamma). The ability to use current NDE technology on waste with surface dose rates above 10 rem/hr will need to be demonstrated. Alternate characterization techniques, such as examination within a hot cell, could be used for the remaining waste; however, such techniques are labor intensive and would require additional effort to gather assay data. Improvements in characterization capabilities are being pursued through future technology development initiatives.

NONE

1995-11-01T23:59:59.000Z

272

Remote-Handled Transuranic Content Codes  

SciTech Connect (OSTI)

The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code.

Washington TRU Solutions

2006-12-01T23:59:59.000Z

273

Processing constraints on high-level nuclear waste glasses for Hanford Waste Vitrification Plant  

SciTech Connect (OSTI)

The work presented in this paper is a part of a major technology program supported by the US Department of Energy (DOE) in preparation for the planned operation of the Hanford Waste Vitrification Plant (HWVP). Because composition of Hanford waste varies greatly, processability is a major concern for successful vitrification. This paper briefly surveys general aspects of waste glass processability and then discusses their ramifications for specific examples of Hanford waste streams.

Hrma, P. [Pacific Northwest Lab., Richland, WA (United States)

1993-12-31T23:59:59.000Z

274

Studien-und Prfungsordnung der Universitt Stuttgart fr den auslandsorientierten Studiengang Air Quality Control, Solid Waste and Waste Water Process Engineering  

E-Print Network [OSTI]

Air Quality Control, Solid Waste and Waste Water Process Engineering (WASTE) mit Abschluss Master Quality Control, Solid Waste and Waste Water Process Engineering" (WASTE) beschlossen. Der Rektor hat Control, Solid Waste and Waste Water Process Engineering" (WASTE) überblickt werden, die Fähigkeit

Reyle, Uwe

275

An introduction to the mechanics of performance assessment using examples of calculations done for the Waste Isolation Pilot Plant between 1990 and 1992. Revision  

SciTech Connect (OSTI)

This document provides an overview of the processes used to access the performance of the Waste Isolation Pilot Plant (WIPP). The quantitative metrics used in the performance-assessment (PA) process are those put forward in the Environmental Protection Agency`s Environmental Standards for the Management and Disposal of Spent Nuclear Fuel, HIgh-LEvel and transuranic radioactive Wastes (40 CFR 191).

Rechard, R.P.

1996-06-01T23:59:59.000Z

276

EIS-0082: Defense Waste Processing Facility, Savannah River Plant  

Broader source: Energy.gov [DOE]

The Office of Defense Waste and Byproducts Management developed this EIS to provide environmental input into both the selection of an appropriate strategy for the permanent disposal of the high-level radioactive waste currently stored at the Savannah River Plant (SRP) and the subsequent decision to construct and operate a Defense Waste Processing Facility at the SRP site.

277

Geologic processes in the RWMC area, Idaho National Engineering Laboratory: Implications for long term stability and soil erosion at the radioactive waste management complex  

SciTech Connect (OSTI)

The Radioactive Waste Management Complex (RWMC) is the disposal and storage facility for low-level radioactive waste at the Idaho National Engineering Laboratory (INEL). Transuranic waste and mixed wastes were also disposed at the RWMC until 1970. It is located in the southwestern part of the INEL about 80 km west of Idaho Falls, Idaho. The INEL occupies a portion of the Eastern Snake River Plain (ESRP), a low-relief, basalt, and sediment-floored basin within the northern Rocky Mountains and northeastern Basin and Range Province. It is a cool and semiarid, sagebrush steppe desert characterized by irregular, rolling terrain. The RWMC began disposal of INEL-generated wastes in 1952, and since 1954, wastes have been accepted from other Federal facilities. Much of the waste is buried in shallow trenches, pits, and soil vaults. Until about 1970, trenches and pits were excavated to the basalt surface, leaving no sediments between the waste and the top of the basalt. Since 1970, a layer of sediment (about 1 m) has been left between the waste and the basalt. The United States Department of Energy (DOE) has developed regulations specific to radioactive-waste disposal, including environmental standards and performance objectives. The regulation applicable to all DOE facilities is DOE Order 5820.2A (Radioactive Waste Management). An important consideration for the performance assessment of the RWMC is the long-term geomorphic stability of the site. Several investigators have identified geologic processes and events that could disrupt a radioactive waste disposal facility. Examples of these {open_quotes}geomorphic hazards{close_quotes} include changes in stream discharge, sediment load, and base level, which may result from climate change, tectonic processes, or magmatic processes. In the performance assessment, these hazards are incorporated into scenarios that may affect the future performance of the RWMC.

Hackett, W.R.; Tullis, J.A.; Smith, R.P. [and others

1995-09-01T23:59:59.000Z

278

Flibe blanket concept for transmuting transuranic elements and long lived fission products.  

SciTech Connect (OSTI)

A Molten salt (Flibe) fusion blanket concept has been developed to solve the disposition problems of the spent nuclear fuel and the transuranic elements. This blanket concept can achieve the top rated solution, the complete elimination of the transuranic elements and the long-lived fission products. Small driven fusion devices with low neutron wall loading and low neutron fluence can perform this function. A 344-MW integrated fusion power from D-T plasmas for thirty years with an availability factor of 0.75 can dispose of 70,000 tons of the US inventory of spent nuclear fuel generated up to the year 2015. In addition, the utilization of this blanket concept eliminates the need for a geological repository site, which is a major advantage. This application provides an excellent opportunity to develop and to enhance the public acceptance of the fusion energy for the future. The energy from the transmutation process is utilized to produce revenue. Flibe, lithium-lead eutectic, and liquid lead are possible candidates. The liquid blankets have several features, which are suited for W application. It can operate at constant thermal power without interruption for refueling by adjusting the concentration of the transuranic elements and lithium-6. These liquids operate at low-pressure, which reduces the primary stresses in the structure material. Development and fabrication costs of solid transuranic materials are eliminated. Burnup limit of the transuranic elements due to radiation effects is eliminated. Heat is generated within the liquid, which simplifies the heat removal process without producing thermal stresses. These blanket concepts have large negative temperature coefficient with respect to the blanket reactivity, which enhances the safety performance. These liquids are chemically and thermally stable under irradiation conditions, which minimize the radioactive waste volume. The operational record of the Molten Salt Breeder Reactor with Flibe was very successful, which established the technical bases for this application. This paper provides the technical analyses and the performance of the Flibe blanket concept as an example of this class of blankets.

Gohar, Y.

2000-11-15T23:59:59.000Z

279

Characterization of industrial process waste heat and input heat streams  

SciTech Connect (OSTI)

The nature and extent of industrial waste heat associated with the manufacturing sector of the US economy are identified. Industry energy information is reviewed and the energy content in waste heat streams emanating from 108 energy-intensive industrial processes is estimated. Generic types of process equipment are identified and the energy content in gaseous, liquid, and steam waste streams emanating from this equipment is evaluated. Matchups between the energy content of waste heat streams and candidate uses are identified. The resultant matrix identifies 256 source/sink (waste heat/candidate input heat) temperature combinations. (MHR)

Wilfert, G.L.; Huber, H.B.; Dodge, R.E.; Garrett-Price, B.A.; Fassbender, L.L.; Griffin, E.A.; Brown, D.R.; Moore, N.L.

1984-05-01T23:59:59.000Z

280

Oak Ridge Operations Office (ORO) & Wastren Advantage, Inc. (WAI) Partnering Agreement For The Transuranic Waste Processing Program  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced ScorecardReactor TechnologyOFFICE: I Oak Ridge, Tennessee 37831Mr.

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Waste receiving and processing facility module 1 auditable safetyanalysis  

SciTech Connect (OSTI)

The Waste Receiving and Processing Facility Module 1 Auditable Safety Analysis analyzes postulated accidents and determines controls to prevent the accidents or mitigate the consequences.

Bottenus, R.J.

1997-02-01T23:59:59.000Z

282

Process for treating fission waste. [Patent application  

DOE Patents [OSTI]

A method is described for the treatment of fission waste. A glass forming agent, a metal oxide, and a reducing agent are mixed with the fission waste and the mixture is heated. After melting, the mixture separates into a glass phase and a metal phase. The glass phase may be used to safely store the fission waste, while the metal phase contains noble metals recovered from the fission waste.

Rohrmann, C.A.; Wick, O.J.

1981-11-17T23:59:59.000Z

283

Newly Generated Liquid Waste Processing Alternatives Study, Volume 1  

SciTech Connect (OSTI)

This report identifies and evaluates three options for treating newly generated liquid waste at the Idaho Nuclear Technology and Engineering Center of the Idaho National Engineering and Environmental Laboratory. The three options are: (a) treat the waste using processing facilities designed for treating sodium-bearing waste, (b) treat the waste using subcontractor-supplied mobile systems, or (c) treat the waste using a special facility designed and constructed for that purpose. In studying these options, engineers concluded that the best approach is to store the newly generated liquid waste until a sodium-bearing waste treatment facility is available and then to co-process the stored inventory of the newly generated waste with the sodium-bearing waste. After the sodium-bearing waste facility completes its mission, two paths are available. The newly generated liquid waste could be treated using the subcontractor-supplied system or the sodium-bearing waste facility or a portion of it. The final decision depends on the design of the sodium-bearing waste treatment facility, which will be completed in coming years.

Landman, William Henry; Bates, Steven Odum; Bonnema, Bruce Edward; Palmer, Stanley Leland; Podgorney, Anna Kristine; Walsh, Stephanie

2002-09-01T23:59:59.000Z

284

Hydrothermal processing of Hanford tank wastes: Process modeling and control  

SciTech Connect (OSTI)

In the Los Alamos National Laboratory (LANL) hydrothermal process, waste streams are first pressurized and heated as they pass through a continuous flow tubular reactor vessel. The waste is maintained at reaction temperature of 300--550 C where organic destruction and sludge reformation occur. This report documents LANL activities in process modeling and control undertaken in FY94 to support hydrothermal process development. Key issues discussed include non-ideal flow patterns (e.g. axial dispersion) and their effect on reactor performance, the use and interpretation of inert tracer experiments, and the use of computational fluid mechanics to evaluate novel hydrothermal reactor designs. In addition, the effects of axial dispersion (and simplifications to rate expressions) on the estimated kinetic parameters are explored by non-linear regression to experimental data. Safety-related calculations are reported which estimate the explosion limits of effluent gases and the fate of hydrogen as it passes through the reactor. Development and numerical solution of a generalized one-dimensional mathematical model is also summarized. The difficulties encountered in using commercially available software to correlate the behavior of high temperature, high pressure aqueous electrolyte mixtures are summarized. Finally, details of the control system and experiments conducted to empirically determine the system response are reported.

Currier, R.P. [comp.

1994-10-01T23:59:59.000Z

285

Thermocatalytic conversion of food processing wastes: Topical report, FY 1988  

SciTech Connect (OSTI)

The efficient utilization of waste produced during food processing operations is a topic of growing importance to the industry. While incineration is an attractive option for wastes with relatively low ash and moisture contents (i.e., under about 50 wt % moisture), it is not suitable for wastes with high moisture contents. Cheese whey, brewer's spent grain, and fruit pomace are examples of food processing wastes that are generally too wet to burn efficiently and cleanly. Pacific Northwest Laboratory (PNL) is developing a thermocatalytic conversion process that can convert high-moisture wastes (up to 98 wt % moisture) to a medium-Btu fuel gas consisting primarily of methane and carbon dioxide. At the same time, the COD of these waste streams is reduced by 90% to 99%, Organic wastes are converted by thermocatalytic treatment at 350/degree/C to 400/degree/C and 3000 to 4000 psig. The process offers a relatively simple solution to waste treatment while providing net energy production from wastes containing as little as 2 wt % organic solids (this is equivalent to a COD of approximately 25,000 mg/L). This report describes continuous reactor system (CRS) experiments that have been conducted with food processing wastes. The purpose of the CRS experiments was to provide kinetic and catalyst lifetime data, which could not be obtained with the batch reactor tests. These data are needed for commercial scaleup of the process.

Baker, E.G.; Butner, R.S.; Sealock, L.J. Jr.; Elliott, D.C.; Neuenschwander, G.G.

1989-01-01T23:59:59.000Z

286

Waste Analysis Plan for the Waste Receiving and Processing (WRAP) Facility  

SciTech Connect (OSTI)

The purpose of this waste analysis plan (WAP) is to document the waste acceptance process, sampling methodologies, analytical techniques, and overall processes that are undertaken for dangerous, mixed, and radioactive waste accepted for confirmation, nondestructive examination (NDE) and nondestructive assay (NDA), repackaging, certification, and/or storage at the Waste Receiving and Processing Facility (WRAP). Mixed and/or radioactive waste is treated at WRAP. WRAP is located in the 200 West Area of the Hanford Facility, Richland, Washington. Because dangerous waste does not include source, special nuclear, and by-product material components of mixed waste, radionuclides are not within the scope of this documentation. The information on radionuclides is provided only for general knowledge.

TRINER, G.C.

1999-11-01T23:59:59.000Z

287

The TRUSPEAK Concept: Combining CMPO and HDEHP for Separating Trivalent Lanthanides from the Transuranic Elements  

SciTech Connect (OSTI)

Combining octyl(phenyl)-N,N-diisobutyl-carbamoylmethyl-phosphine oxide (CMPO) and bis-(2-ethylhexyl) phosphoric acid (HDEHP) into a single process solvent for separating transuranic elements from liquid high-level waste is explored. Co-extraction of americium and the lanthanide elements from nitric acid solution is possible with a solvent mixture consisting of 0.1-M CMPO plus 1-M HDEHP in n-dodecane. Switching the aqueous-phase chemistry to a citrate-buffered solution of diethylene triamine pentaacetic acid (DTPA) allows for selective stripping of americium, separating it from the lanthanide elements. Potential strategies for managing molybdenum and zirconium (both of which co-extract with americium and the lanthanides) have been developed. The work presented here demonstrates the feasibility of combining CMPO and HDEHP into a single extraction solvent for recovering americium from high-level waste and its separation from the lanthanides.

Lumetta, Gregg J.; Gelis, Artem V.; Braley, Jenifer C.; Carter, Jennifer C.; Pittman, Jonathan W.; Warner, Marvin G.; Vandegrift, George F.

2013-04-08T23:59:59.000Z

288

Sodium Bearing Waste Processing Alternatives Analysis  

SciTech Connect (OSTI)

A multidisciplinary team gathered to develop a BBWI recommendation to DOE-ID on the processing alternatives for the sodium bearing waste in the INTEC Tank Farm. Numerous alternatives were analyzed using a rigorous, systematic approach. The data gathered were evaluated through internal and external peer reviews for consistency and validity. Three alternatives were identified to be top performers: Risk-based Calcination, MACT to WIPP Calcination and Cesium Ion Exchange. A dual-path through early Conceptual design is recommended for MACT to WIPP Calcination and Cesium Ion Exchange since Risk-based Calcination does not require design. If calcination alternatives are not considered based on giving Type of Processing criteria significantly greater weight, the CsIX/TRUEX alternative follows CsIX in ranking. However, since CsIX/TRUEX shares common uncertainties with CsIX, reasonable backups, which follow in ranking, are the TRUEX and UNEX alternatives. Key uncertainties must be evaluated by the decision-makers to choose one final alternative. Those key uncertainties and a path forward for the technology roadmapping of these alternatives is provided.

Murphy, James Anthony; Palmer, Brent J; Perry, Keith Joseph

2003-12-01T23:59:59.000Z

289

Tank waste remediation system phase I high-level waste feed processability assessment report  

SciTech Connect (OSTI)

This report evaluates the effects of feed composition on the Phase I high-level waste immobilization process and interim storage facility requirements for the high-level waste glass.Several different Phase I staging (retrieval, blending, and pretreatment) scenarios were used to generate example feed compositions for glass formulations, testing, and glass sensitivity analysis. Glass models and data form laboratory glass studies were used to estimate achievable waste loading and corresponding glass volumes for various Phase I feeds. Key issues related to feed process ability, feed composition, uncertainty, and immobilization process technology are identified for future consideration in other tank waste disposal program activities.

Lambert, S.L.; Stegen, G.E., Westinghouse Hanford

1996-08-01T23:59:59.000Z

290

Liquid membrane system for the removal and concentration of transuranic elements  

SciTech Connect (OSTI)

The goal of this program is to develop an efficient, reliable, and radiation-resistant modified liquid membrane system (MLMS) for the selective removal and concentration of transuranic elements (TRUs) and strontium-90 from dissolved Hanford sludge wastes. The efforts are divided into three categories: (1) demonstration and optimization of the MLMS for the TRUEX and SREX processes using simulant waste solution; (2) development of a radiation-resistant microporous divider and membrane module for testing with actual waste solutions; and (3) demonstration of the MLMS for the TRUEX and SREX processes using actual Hanford waste. Successful completion of these development efforts will yield a compact, versatile, and reliable MLMS for implementation with the TRUEX and SREX processes. The MLMS is simple, stable, more efficient, and easier to control and operate than conventional solvent-extraction processes, such as those employing centrifugal contactors. In addition, the MLMS process offers operational cost savings over the conventional technology, by exhibiting at least a 10% reduction in the consumption of extractant chemicals.

Timmins, M.R.; Wysk, S.R.; Smolensky, L.A.; Jiang, D.; Lumetta, G.J.

1996-12-31T23:59:59.000Z

291

Chapter 38 Hazardous Waste Permitting Process (Kentucky)  

Broader source: Energy.gov [DOE]

This administrative regulation establishes the general provisions for storage, treatment, recycling, or disposal of hazardous waste. It provides information about permits and specific requirements...

292

Progress of the High Level Waste Program at the Defense Waste Processing Facility - 13178  

SciTech Connect (OSTI)

The Defense Waste Processing Facility at the Savannah River Site treats and immobilizes High Level Waste into a durable borosilicate glass for safe, permanent storage. The High Level Waste program significantly reduces environmental risks associated with the storage of radioactive waste from legacy efforts to separate fissionable nuclear material from irradiated targets and fuels. In an effort to support the disposition of radioactive waste and accelerate tank closure at the Savannah River Site, the Defense Waste Processing Facility recently implemented facility and flowsheet modifications to improve production by 25%. These improvements, while low in cost, translated to record facility production in fiscal years 2011 and 2012. In addition, significant progress has been accomplished on longer term projects aimed at simplifying and expanding the flexibility of the existing flowsheet in order to accommodate future processing needs and goals. (authors)

Bricker, Jonathan M.; Fellinger, Terri L.; Staub, Aaron V.; Ray, Jeff W.; Iaukea, John F. [Savannah River Remediation, Aiken, South Carolina, 29808 (United States)] [Savannah River Remediation, Aiken, South Carolina, 29808 (United States)

2013-07-01T23:59:59.000Z

293

Technical evaluation of proposed Ukrainian Central Radioactive Waste Processing Facility  

SciTech Connect (OSTI)

This technical report is a comprehensive evaluation of the proposal by the Ukrainian State Committee on Nuclear Power Utilization to create a central facility for radioactive waste (not spent fuel) processing. The central facility is intended to process liquid and solid radioactive wastes generated from all of the Ukrainian nuclear power plants and the waste generated as a result of Chernobyl 1, 2 and 3 decommissioning efforts. In addition, this report provides general information on the quantity and total activity of radioactive waste in the 30-km Zone and the Sarcophagus from the Chernobyl accident. Processing options are described that may ultimately be used in the long-term disposal of selected 30-km Zone and Sarcophagus wastes. A detailed report on the issues concerning the construction of a Ukrainian Central Radioactive Waste Processing Facility (CRWPF) from the Ukrainian Scientific Research and Design institute for Industrial Technology was obtained and incorporated into this report. This report outlines various processing options, their associated costs and construction schedules, which can be applied to solving the operating and decommissioning radioactive waste management problems in Ukraine. The costs and schedules are best estimates based upon the most current US industry practice and vendor information. This report focuses primarily on the handling and processing of what is defined in the US as low-level radioactive wastes.

Gates, R.; Glukhov, A.; Markowski, F.

1996-06-01T23:59:59.000Z

294

Process for removing sulfate anions from waste water  

DOE Patents [OSTI]

A liquid emulsion membrane process for removing sulfate anions from waste water is disclosed. The liquid emulsion membrane process includes the steps of: (a) providing a liquid emulsion formed from an aqueous strip solution and an organic phase that contains an extractant capable of removing sulfate anions from waste water; (b) dispersing the liquid emulsion in globule form into a quantity of waste water containing sulfate anions to allow the organic phase in each globule of the emulsion to extract and absorb sulfate anions from the waste water and (c) separating the emulsion including its organic phase and absorbed sulfate anions from the waste water to provide waste water containing substantially no sulfate anions.

Nilsen, David N. (Lebanon, OR); Galvan, Gloria J. (Albany, OR); Hundley, Gary L. (Corvallis, OR); Wright, John B. (Albany, OR)

1997-01-01T23:59:59.000Z

295

Solid Waste Management Plan. Revision 4  

SciTech Connect (OSTI)

The waste types discussed in this Solid Waste Management Plan are Municipal Solid Waste, Hazardous Waste, Low-Level Mixed Waste, Low-Level Radioactive Waste, and Transuranic Waste. The plan describes for each type of solid waste, the existing waste management facilities, the issues, and the assumptions used to develop the current management plan.

NONE

1995-04-26T23:59:59.000Z

296

Double Shell Tank (DST) Process Waste Sampling Subsystem Definition Report  

SciTech Connect (OSTI)

This report defines the Double-Shell Tank (DST) Process Waste Sampling Subsystem (PWSS). This subsystem definition report fully describes and identifies the system boundaries of the PWSS. This definition provides a basis for developing functional, performance, and test requirements (i.e., subsystem specification), as necessary, for the PWSS. The resultant PWSS specification will include the sampling requirements to support the transfer of waste from the DSTs to the Privatization Contractor during Phase 1 of Waste Feed Delivery.

RASMUSSEN, J.H.

2000-04-25T23:59:59.000Z

297

Tank Waste and Waste Processing | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystallineForeign ObjectOUR8, 2013 FINAL MEETING SUMMARY7,Tank Waste and

298

Molten salt extraction of transuranic and reactive fission products from used uranium oxide fuel  

DOE Patents [OSTI]

Used uranium oxide fuel is detoxified by extracting transuranic and reactive fission products into molten salt. By contacting declad and crushed used uranium oxide fuel with a molten halide salt containing a minor fraction of the respective uranium trihalide, transuranic and reactive fission products partition from the fuel to the molten salt phase, while uranium oxide and non-reactive, or noble metal, fission products remain in an insoluble solid phase. The salt is then separated from the fuel via draining and distillation. By this method, the bulk of the decay heat, fission poisoning capacity, and radiotoxicity are removed from the used fuel. The remaining radioactivity from the noble metal fission products in the detoxified fuel is primarily limited to soft beta emitters. The extracted transuranic and reactive fission products are amenable to existing technologies for group uranium/transuranic product recovery and fission product immobilization in engineered waste forms.

Herrmann, Steven Douglas

2014-05-27T23:59:59.000Z

299

Savannah River Site Waste Isolation Pilot Plant Disposal Program - Acceptable Knowledge Summary Report for Waste Stream: SR-T001-221-HET  

SciTech Connect (OSTI)

This document, along with referenced supporting documents provides a defensible and auditable record of acceptable knowledge for one of the waste streams from the FB-Line. This heterogeneous debris transuranic waste stream was generated after January 25, 1990 and before March 20, 1997. The waste was packaged in 55-gallon drums, then shipped to the transuranic waste storage facility in ''E'' area of the Savannah River Site. This acceptable knowledge report includes information relating to the facility's history, configuration, equipment, process operations and waste management practices. Information contained in this report was obtained from numerous sources including: facility safety basis documentation, historical document archives, generator and storage facility waste records and documents, and interviews with cognizant personnel.

Lunsford, G.F.

2001-01-24T23:59:59.000Z

300

Hanford's Simulated Low Activity Waste Cast Stone Processing  

SciTech Connect (OSTI)

Cast Stone is undergoing evaluation as the supplemental treatment technology for Hanford’s (Washington) high activity waste (HAW) and low activity waste (LAW). This report will only cover the LAW Cast Stone. The programs used for this simulated Cast Stone were gradient density change, compressive strength, and salt waste form phase identification. Gradient density changes show a favorable outcome by showing uniformity even though it was hypothesized differently. Compressive strength exceeded the minimum strength required by Hanford and greater compressive strength increase seen between the uses of different salt solution The salt waste form phase is still an ongoing process as this time and could not be concluded.

Kim, Young

2013-08-20T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Co-processing of agricultural and biomass waste with coal  

SciTech Connect (OSTI)

A major thrust of our research program is the use of waste materials as co-liquefaction agents for the first-stage conversion of coal to liquid fuels. By fulfilling one or more of the roles of an expensive solvent in the direct coal liquefaction (DCL) process, the waste material is disposed off ex-landfill, and may improve the overall economics of DCL. Work in our group has concentrated on co-liquefaction with waste rubber tires, some results from which are presented elsewhere in these Preprints. In this paper, we report on preliminary results with agricultural and biomass-type waste as co-liquefaction agents.

Stiller, A.H.; Dadyburjor, D.B.; Wann, Ji-Perng [West Virginia Univ., Morgantown, WV (United States)] [and others

1995-12-31T23:59:59.000Z

302

Retrieval process development and enhancements waste simulant compositions and defensibility  

SciTech Connect (OSTI)

The purpose of this report is to document the physical waste simulant development efforts of the EM-50 Tanks Focus Area at the Hanford Site. Waste simulants are used in the testing and development of waste treatment and handling processes because performing such tests using actual tank waste is hazardous and prohibitively expensive. This document addresses the simulant development work that supports the testing of waste retrieval processes using simulants that mimic certain key physical properties of the tank waste. Development and testing of chemical simulants are described elsewhere. This work was funded through the EM-50 Tanks Focus Area as part of the Retrieval Process Development and Enhancements (RPD&E) Project at the Pacific Northwest National Laboratory (PNNL). The mission of RPD&E is to understand retrieval processes, including emerging and existing processes, gather performance data on those processes, and relate the data to specific tank problems to provide end users with the requisite technical bases to make retrieval and closure decisions. Physical simulants are prepared using relatively nonhazardous and inexpensive materials rather than the chemicals known to be in tank waste. Consequently, only some of the waste properties are matched by the simulant. Deciding which properties need to be matched and which do not requires a detailed knowledge of the physics of the process to be tested using the simulant. Developing this knowledge requires reviews of available literature, consultation with experts, and parametric tests. Once the relevant properties are identified, waste characterization data are reviewed to establish the target ranges for each property. Simulants are then developed that possess the desired ranges of properties.

Powell, M.R.; Golcar, G.R.; Geeting, J.G.H.

1997-09-01T23:59:59.000Z

303

Transuranic Waste Screener - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2Topo II:LIGHT-DUTYTransportation

304

Transuranic (TRU) Waste | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up from theDepartment of EnergyThe SunMelissa HowellTechnologies »Transportation

305

Transuranic Waste Transportation Working Group Agenda  

Office of Environmental Management (EM)

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306

Annual Transuranic Waste Inventory Report - 2013  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone by E-mail ShareRedAndreas ETechnicalForTotalSRSAnnual

307

Design and performance of a fluidized-bed incinerator for TRU combustible wastes  

SciTech Connect (OSTI)

Problems encountered in the incineration of glovebox generated waste at Rocky Flats Plant (RFP) led to the development of a fluidized-bed incineration (FBI) system for transuranic (TRU) combustible wastes. Laboratory and pilot-scale testing of the process preceded the installation of an 82-kg/h production demonstration incinerator at RFP. The FBI process is discussed, and the design of the demonstration incinerator is described. Operating experience and process performance for both the pilot and demonstration units are presented.

Meile, L.J.; Meyer, F.G.

1982-01-01T23:59:59.000Z

308

E-Print Network 3.0 - agriculture process waste Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Agricultural and food processing plants can turn waste into power can turn... . Wastewater treatment plants (WWTPs), waste streams from food and beverage processing plants,...

309

Technical resource document for assured thermal processing of wastes  

SciTech Connect (OSTI)

This document is a concise compendium of resource material covering assured thermal processing of wastes (ATPW), an area in which Sandia aims to develop a large program. The ATPW program at Sandia is examining a wide variety of waste streams and thermal processes. Waste streams under consideration include municipal, chemical, medical, and mixed wastes. Thermal processes under consideration range from various incineration technologies to non-incineration processes such as supercritical water oxidation or molten metal technologies. Each of the chapters describes the element covered, discusses issues associated with its further development and/or utilization, presents Sandia capabilities that address these issues, and indicates important connections to other ATPW elements. The division of the field into elements was driven by the team`s desire to emphasize areas where Sandia`s capabilities can lead to major advances and is therefore somewhat unconventional. The report will be valuable to Sandians involved in further ATPW program development.

Farrow, R.L.; Fisk, G.A.; Hartwig, C.M.; Hurt, R.H.; Ringland, J.T.; Swansiger, W.A.

1994-06-01T23:59:59.000Z

310

Centralized processing of contact-handled TRU waste feasibility analysis  

SciTech Connect (OSTI)

This report presents work for the feasibility study of central processing of contact-handled TRU waste. Discussion of scenarios, transportation options, summary of cost estimates, and institutional issues are a few of the subjects discussed. (JDL)

Not Available

1986-12-01T23:59:59.000Z

311

Feed specification for the double-shell tank/single shell tank waste blend for high-level waste vitrification process and melter testing  

SciTech Connect (OSTI)

The High-Level Waste (HLW) Vitrification Program is developing technology for the Department of Energy to immobilize high-level and transuranic waste as glass for permanent disposal. In support of the program, Pacific Northwest Laboratory (PNL) is conducting laboratory-scale melter feed preparation studies and HLW melter testing which require a simulated HLW feed. The simulant HLW feed represents a blend of the waste from 177 single shell and double shell tanks. The waste blend composition is based on normalized track radionuclide components (TRAC), historical tank data, and assumptions on the pretreatment of the waste. The HLW simulant feed specification for the waste blend composition provides direction for the preparation of laboratory-scale and large-scale HLW blend simulant to be used in melter feed preparation studies and melter testing.

Tracey, E.M.; Merz, M.D.; Patello, G.K.; Wiemers, K.D.

1996-02-01T23:59:59.000Z

312

Waste heat driven absorption refrigeration process and system  

DOE Patents [OSTI]

Absorption cycle refrigeration processes and systems are provided which are driven by the sensible waste heat available from industrial processes and other sources. Systems are disclosed which provide a chilled water output which can be used for comfort conditioning or the like which utilize heat from sensible waste heat sources at temperatures of less than 170.degree. F. Countercurrent flow equipment is also provided to increase the efficiency of the systems and increase the utilization of available heat.

Wilkinson, William H. (Columbus, OH)

1982-01-01T23:59:59.000Z

313

Accelerator Production of Tritium project process waste assessment  

SciTech Connect (OSTI)

DOE has made a commitment to compliance with all applicable environmental regulatory requirements. In this respect, it is important to consider and design all tritium supply alternatives so that they can comply with these requirements. The management of waste is an integral part of this activity and it is therefore necessary to estimate the quantities and specific wastes that will be generated by all tritium supply alternatives. A thorough assessment of waste streams includes waste characterization, quantification, and the identification of treatment and disposal options. The waste assessment for APT has been covered in two reports. The first report was a process waste assessment (PWA) that identified and quantified waste streams associated with both target designs and fulfilled the requirements of APT Work Breakdown Structure (WBS) Item 5.5.2.1. This second report is an expanded version of the first that includes all of the data of the first report, plus an assessment of treatment and disposal options for each waste stream identified in the initial report. The latter information was initially planned to be issued as a separate Waste Treatment and Disposal Options Assessment Report (WBS Item 5.5.2.2).

Carson, S.D.; Peterson, P.K.

1995-09-01T23:59:59.000Z

314

EIS-0305: Treating Transuranic (TRU)/Alpha Low-Level at the Oak Ridge National Laboratory, Oak Ridge, Tennessee  

Broader source: Energy.gov [DOE]

Treating Transuranic (TRU)/Alpha Low-Level Waste at the Oak Ridge National Laboratory, Oak Ridge, Tennessee)This EIS evaluates DOE's proposal to construct, operate, and decontaminate/decommission a Transuranic (TRU) Waste Treatment Facility in Oak Ridge, Tennessee. The four waste types that would be treated at the proposed facility would be remote-handled TRU mixed waste sludge, liquid low-level waste associated with the sludge, contact-handled TRU/alpha low-level waste solids, and remote-handled TRU/alpha low-level waste solids. The mixed waste sludge and some of the solid waste contain metals regulated under the Resource Conservation and Recovery Act and may be classified as mixed waste.

315

Characterization of past and present waste streams from the 325 Radiochemistry Building  

SciTech Connect (OSTI)

The purpose of this report is to characterize, as far as possible, the solid waste generated by the 325 Radiochemistry Building since its construction in 1953. Solid waste as defined in this document is any containerized or self-contained material that has been declared waste. This characterization is of particular interest in the planning of transuranic (TRU) waste retrieval operations including the Waste Receiving and Processing (WRAP) Facility. Westinghouse Hanford Company (Westinghouse Hanford) and Battelle Pacific Northwest Laboratory (PNL) activities at Building 325 have generated approximately 4.4% and 2.4%, respectively, of the total volume of TRU waste currently stored at the Hanford Site.

Pottmeyer, J.A.; Weyns-Rollosson, M.I.; Dicenso, K.D.; DeLorenzo, D.S. [Los Alamos Technical Associates, Kennewick, WA (United States); Duncan, D.R. [Westinghouse Hanford Co., Richland, WA (United States)

1993-12-01T23:59:59.000Z

316

Acceptable Knowledge Summary Report for Waste Stream: SR-T001-221F-HET/Drums  

SciTech Connect (OSTI)

Since beginning operations in 1954, the Department of Energy's Savannah River Site FB-Line conducted atomic energy defense activities consistent with the listing in Section 10101(3) of the Nuclear Waste Policy Act of 1982. The facility mission was to process and convert dilute plutonium solution into highly purified weapons grade plutonium metal. As a result of various activities conducted in support of the mission (e.g., operation, maintenance, repair, clean up, and facility modifications), the facility generated transuranic waste. This document, along with referenced supporting documents, provides a defensible and auditable record of acceptable knowledge for one of the waste streams from the FB-Line. The waste was packaged in 55-gallon drums, then shipped to the transuranic waste storage facility in ''E'' area of the Savannah River Site. This acceptable knowledge report includes information relating to the facility's history, configuration,equipment, process operations, and waste management practices.

Lunsford, G.F.

1999-08-23T23:59:59.000Z

317

Electromagnetic mixed waste processing system for asbestos decontamination  

SciTech Connect (OSTI)

DOE sites contain a broad spectrum of asbestos materials (cloth, pipe lagging, sprayed insulation and other substances) which are contaminated with a combination of hazardous and radioactive wastes due to its use during the development of the US nuclear weapons complex. These wastes consist of cutting oils, lubricants, solvents, PCBs, heavy metals and radioactive contaminants. The radioactive contaminants are the activation, decay, and fission products of DOE operations. To allow disposal, the asbestos must be converted chemically, followed by removing and separating the hazardous and radioactive materials to prevent the formation of mixed wastes and to allow for both sanitary disposal and effective decontamination. Currently, no technology exists that can meet these sanitary and other objectives. An attempt was made to apply techniques that have already proved successful in the mining, oil, and metals processing industries to the development of a multi-stage process to remove and separate hazardous chemical radioactive materials from asbestos. This process uses three methods: ABCOV chemicals which converts the asbestos to a sanitary waste; dielectric heating to volatilize the organic materials; and electrochemical processing for the removal of heavy metals, RCRA wastes and radionuclides. This process will result in the destruction of over 99% of the asbestos; limit radioactive metal contamination to 0.2 Bq alpha per gram and 1 Bq beta and gamma per gram; reduce hazardous organics to levels compatible with current EPA policy for RCRA delisting; and achieve TCLP limits for all solidified waste.

Kasevich, R.S.; Nocito, T.; Vaux, W.G.; Snyder, T.

1994-12-31T23:59:59.000Z

318

Waste Treatment Technology Process Development Plan For Hanford Waste Treatment Plant Low Activity Waste Recycle  

SciTech Connect (OSTI)

The purpose of this Process Development Plan is to summarize the objectives and plans for the technology development activities for an alternative path for disposition of the recycle stream that will be generated in the Hanford Waste Treatment Plant Low Activity Waste (LAW) vitrification facility (LAW Recycle). This plan covers the first phase of the development activities. The baseline plan for disposition of this stream is to recycle it to the WTP Pretreatment Facility, where it will be concentrated by evaporation and returned to the LAW vitrification facility. Because this stream contains components that are volatile at melter temperatures and are also problematic for the glass waste form, they accumulate in the Recycle stream, exacerbating their impact on the number of LAW glass containers. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and reducing the halides in the Recycle is a key component of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, this stream does not have a proven disposition path, and resolving this gap becomes vitally important. This task seeks to examine the impact of potential future disposition of this stream in the Hanford tank farms, and to develop a process that will remove radionuclides from this stream and allow its diversion to another disposition path, greatly decreasing the LAW vitrification mission duration and quantity of glass waste. The origin of this LAW Recycle stream will be from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover or precipitates of scrubbed components (e.g. carbonates). The soluble components are mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet, and will not be available until the WTP begins operation, causing uncertainty in its composition, particularly the radionuclide content. This plan will provide an estimate of the likely composition and the basis for it, assess likely treatment technologies, identify potential disposition paths, establish target treatment limits, and recommend the testing needed to show feasibility. Two primary disposition options are proposed for investigation, one is concentration for storage in the tank farms, and the other is treatment prior to disposition in the Effluent Treatment Facility. One of the radionuclides that is volatile and expected to be in high concentration in this LAW Recycle stream is Technetium-99 ({sup 99}Tc), a long-lived radionuclide with a half-life of 210,000 years. Technetium will not be removed from the aqueous waste in the Hanford Waste Treatment and Immobilization Plant (WTP), and will primarily end up immobilized in the LAW glass, which will be disposed in the Integrated Disposal Facility (IDF). Because {sup 99}Tc has a very long half-life and is highly mobile, it is the largest dose contributor to the Performance Assessment (PA) of the IDF. Other radionuclides that are also expected to be in appreciable concentration in the LAW Recycle are {sup 129}I, {sup 90}Sr, {sup 137}Cs, and {sup 241}Am. The concentrations of these radionuclides in this stream will be much lower than in the LAW, but they will still be higher than limits for some of the other disposition pathways currently available. Although the baseline process will recycle this stream to the Pretreatment Facility, if the LAW facility begins operation first, this stream will not have a disposition path internal to WTP. One potential solution is to return the stream to the tank farms where it can be evaporated in the 242-A evaporator, or perhaps deploy an auxiliary evaporator to concentrate it prior to return to the tank farms. In either case, testing is needed to evaluat

McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.

2013-08-29T23:59:59.000Z

319

The disposal of orphan wastes using the greater confinement disposal concept  

SciTech Connect (OSTI)

In the United States, radioactive wastes are conventionally classified as high-level wastes, transuranic wastes, or low-level wastes. Each of these types of wastes, by law, has a ``home`` for their final disposal; i.e., high-level wastes are destined for disposal at the proposed repository at Yucca Mountain, transuranic waste for the proposed Waste Isolation Pilot Plant, and low-level waste for shallow-land disposal sites. However, there are some radioactive wastes within the United States Department of Energy (DOE) complex that do not meet the criteria established for disposal of either high-level waste, transuranic waste, or low-level waste. The former are called ``special-case`` or ``orphan`` wastes. This paper describes an ongoing project sponsored by the DOE`s Nevada Operations Office for the disposal of orphan wastes at the Radioactive Waste Management Site at Area 5 of the Nevada Test Site using the greater confinement disposal (GCD) concept. The objectives of the GCD project are to evaluate the safety of the site for disposal of orphan wastes by assessing compliance with pertinent regulations through performance assessment, and to examine the feasibility of this disposal concept as a cost-effective, safe alternative for management of orphan wastes within the DOE complex. Decisions on the use of GCD or other alternate disposal concepts for orphan wastes can be expected to be addressed in a Programmatic Environmental Impact Statement being prepared by DOE. The ultimate decision to use GCD will require a Record of Decision through the National Environmental Policy Act (NEPA) process. 20 refs., 3 figs., 2 tabs.

Bonano, E.J.; Chu, M.S.Y.; Price, L.L.; Conrad, S.H. [Sandia National Labs., Albuquerque, NM (USA); Dickman, P.T. [Department of Energy, Las Vegas, NV (USA). Nevada Operations Office

1991-02-01T23:59:59.000Z

320

Combining CMPO and HEH[EHP] for Separating Trivalent Lanthanides from the Transuranic Elements  

SciTech Connect (OSTI)

Combining octyl(phenyl)-N,N-diisobutyl-carbamoylmethylphosphine oxide (CMPO) and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) into a single process solvent for separating transuranic elements from liquid high-level waste is explored. The lanthanides and americium can be co-extracted from HNO3 into 0.2 mol/L CMPO + 1.0 mol/L HEH[EHP] in n-dodecane. The extraction is relatively insensitive to the HNO3 concentration within 0.1 to 5 mol/L HNO3. Americium can be selectively stripped from the CMPO/HEH[EHP] solvent into a citrate-buffered N-(2-hydroxyethyl)ethylenediaminetriacetic acid solution . Separation factors >14 can be achieved in the range pH 2.5 to 3.7, and the separation factors are relatively insensitive to pH, a major advantage of this solvent formulation.

Braley, Jenifer C.; Lumetta, Gregg J.; Carter, Jennifer C.

2013-09-05T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

IMPACT OF THE SMALL COLUMN ION EXCHANGE PROCESS ON THE DEFENSE WASTE PROCESSING FACILITY - 12112  

SciTech Connect (OSTI)

The Savannah River Site (SRS) is investigating the deployment of a parallel technology to the Salt Waste Processing Facility (SWPF, presently under construction) to accelerate high activity salt waste processing. The proposed technology combines large waste tank strikes of monosodium titanate (MST) to sorb strontium and actinides with two ion exchange columns packed with crystalline silicotitanate (CST) resin to sorb cesium. The new process was designated Small Column Ion Exchange (SCIX), since the ion exchange columns were sized to fit within a waste storage tank riser. Loaded resins are to be combined with high activity sludge waste and fed to the Defense Waste Processing Facility (DWPF) for incorporation into the current glass waste form. Decontaminated salt solution produced by SCIX will be fed to the SRS Saltstone Facility for on-site immobilization as a grout waste form. Determining the potential impact of SCIX resins on DWPF processing was the basis for this study. Accelerated salt waste treatment is projected to produce a significant savings in the overall life cycle cost of waste treatment at SRS.

Koopman, D.; Lambert, D.; Fox, K.; Stone, M.

2011-11-07T23:59:59.000Z

322

RECENT PROCESS AND EQUIPMENT IMPROVEMENTS TO INCREASE HIGH LEVEL WASTE THROUGHPUT AT THE DEFENSE WASTE PROCESSING FACILITY  

SciTech Connect (OSTI)

The Savannah River Site's (SRS) Defense Waste Processing Facility (DWPF) began stabilizing high level waste (HLW) in a glass matrix in 1996. Over the past few years, there have been several process and equipment improvements at the DWPF to increase the rate at which the high level waste can be stabilized. These improvements have either directly increased waste processing rates or have desensitized the process to upsets, thereby minimizing downtime and increasing production. Improvements due to optimization of waste throughput with increased HLW loading of the glass resulted in a 6% waste throughput increase based upon operational efficiencies. Improvements in canister production include the pour spout heated bellows liner (5%), glass surge (siphon) protection software (2%), melter feed pump software logic change to prevent spurious interlocks of the feed pump with subsequent dilution of feed stock (2%) and optimization of the steam atomized scrubber (SAS) operation to minimize downtime (3%) for a total increase in canister production of 12%. A number of process recovery efforts have allowed continued operation. These include the off gas system pluggage and restoration, slurry mix evaporator (SME) tank repair and replacement, remote cleaning of melter top head center nozzle, remote melter internal inspection, SAS pump J-Tube recovery, inadvertent pour scenario resolutions, dome heater transformer bus bar cooling water leak repair and new Infra-red camera for determination of glass height in the canister are discussed.

Odriscoll, R; Allan Barnes, A; Jim Coleman, J; Timothy Glover, T; Robert Hopkins, R; Dan Iverson, D; Jeff Leita, J

2008-01-15T23:59:59.000Z

323

Materials evaluation programs at the Defense Waste Processing Facility  

SciTech Connect (OSTI)

The Savannah River Site (SRS) has been operating a nuclear fuel cycle since the 1950s to produce nuclear materials in support of the national defense effort. About 83 million gallons of high-level waste produced since operations began has been consolidated by evaporation into 33 million gallons at the waste tank farm. The Department of Energy authorized the construction of the Defense Waste Processing Facility (DWPF), the function of which is to immobilize the waste as a durable borosilicate glass contained in stainless steel canisters prior to the placement of the canisters in a federal repository. The DWPF is now mechanically complete and is undergoing commissioning and run-in activities. A brief description of the DWPF process is provided.

Gee, J.T.; Iverson, D.C.; Bickford, D.F.

1992-01-01T23:59:59.000Z

324

Materials evaluation programs at the Defense Waste Processing Facility  

SciTech Connect (OSTI)

The Savannah River Site (SRS) has been operating a nuclear fuel cycle since the 1950s to produce nuclear materials in support of the national defense effort. About 83 million gallons of high-level waste produced since operations began has been consolidated by evaporation into 33 million gallons at the waste tank farm. The Department of Energy authorized the construction of the Defense Waste Processing Facility (DWPF), the function of which is to immobilize the waste as a durable borosilicate glass contained in stainless steel canisters prior to the placement of the canisters in a federal repository. The DWPF is now mechanically complete and is undergoing commissioning and run-in activities. A brief description of the DWPF process is provided.

Gee, J.T.; Iverson, D.C.; Bickford, D.F.

1992-12-31T23:59:59.000Z

325

DQO Summary Report for 324 and 327 Building Hot Cells D4 Project Waste Characterization  

SciTech Connect (OSTI)

This data quality objective (DQO) summary report provides the results of the DQO process conducted for waste characterization activities for the 324 and 327 Building hot cells decommission, deactivate, decontaminate, and demolish activities. This DQO summary report addresses the systems and processes related to the hot cells, air locks, vaults, tanks, piping, basins, air plenums, air ducts, filters, an adjacent elements that have high dose rates, high contamination levels, and/or suspect transuranic waste, which will require nonstandard D4 techniques.

T.A. Lee

2006-02-06T23:59:59.000Z

326

Proceedings of waste stream minimization and utilization innovative concepts: An experimental technology exchange. Volume 2, Industrial liquid waste processing, industrial gaseous waste processing  

SciTech Connect (OSTI)

This two-volume proceedings summarize the results of fifteen innovations that were funded through the US Department of Energy`s Innovative Concept Program. The fifteen innovations were presented at the sixth Innovative Concepts Fair, held in Austin, Texas, on April 22--23, 1993. The concepts in this year`s fair address innovations that can substantially reduce or use waste streams. Each paper describes the need for the proposed concept, the concept being proposed, and the concept`s economics and market potential, key experimental results, and future development needs. The papers are divided into two volumes: Volume 1 addresses innovations for industrial solid waste processing and municipal waste reduction/recycling, and Volume 2 addresses industrial liquid waste processing and industrial gaseous waste processing. Individual reports are indexed separately.

Lee, V.E. [ed.; Watts, R.L.

1993-04-01T23:59:59.000Z

327

Waste Receiving and Processing Facility - Hanford Site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption byAbout Printable VersionProtective ActionsWaste

328

DOE/EIS-0200-SA-01: Supplement Analysis and Determination for the Proposed Characterization for Disposal of Contact-Handled Transuranic Waste at the Waste Isolation Pilot Plant (WIPP) (12/00)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to UserProduct: CrudeOffice of ScientificSolarStartupCH-TRU waste may

329

TECHNOLOGY SUMMARY ADVANCING TANK WASTE RETRIEVAL AND PROCESSING  

SciTech Connect (OSTI)

This technology overview provides a high-level summary of technologies being investigated and developed by Washington River Protection Solutions (WRPS) to advance Hanford Site tank waste retrieval and processing. Technology solutions are outlined, along with processes and priorities for selecting and developing them.

SAMS TL; MENDOZA RE

2010-08-11T23:59:59.000Z

330

TECHNOLOGY SUMMARY ADVANCING TANK WASTE RETREIVAL AND PROCESSING  

SciTech Connect (OSTI)

This technology overview provides a high-level summary of technologies being investigated and developed by Washington River Protection Solutions (WRPS) to advance Hanford Site tank waste retrieval and processing. Technology solutions are outlined, along with processes and priorities for selecting and developing them.

SAMS TL

2010-07-07T23:59:59.000Z

331

Crystallization process to reduce NORM-containing waste  

SciTech Connect (OSTI)

This paper describes a process of Naturally Occurring Radioactive Material (NORM) waste reduction for scales, sludges, and soils. The process involves dissolution and fractional crystallization steps that concentrate the radioactive material into a small mass of barite. The concentration of radium in the product, barite, can be increased or decreased. The NORM-containing barite product is suitable for slurry injection into sandstone formations.

Hayden, C.G. [Inst. of Gas Technology, Chicago, IL (United States); Kraemer, T.F.

1995-11-01T23:59:59.000Z

332

Alpha low-level stored waste systems design study  

SciTech Connect (OSTI)

The Stored Waste System Design Study (SWSDS), commissioned by the Waste Technology Development Department at the Idaho National Engineering Laboratory (INEL), examines relative life-cycle costs associated with three system concepts for processing the alpha low-level waste (alpha-LLW) stored at the Radioactive Waste Management Complex`s Transuranic Storage Area at the INEL. The three system concepts are incineration/melting; thermal treatment/solidification; and sort, treat, and repackage. The SWSDS identifies system functional and operational requirements and assesses implementability; effectiveness; cost; and demonstration, testing, and evaluation (DT&E) requirements for each of the three concepts.

Feizollahi, F.; Teheranian, B. [Morrison Knudson Corp., San Francisco, CA (United States). Environmental Services Div.; Quapp, W.J. [EG and G Idaho, Inc., Idaho Falls, ID (United States)

1992-08-01T23:59:59.000Z

333

Alpha low-level stored waste systems design study  

SciTech Connect (OSTI)

The Stored Waste System Design Study (SWSDS), commissioned by the Waste Technology Development Department at the Idaho National Engineering Laboratory (INEL), examines relative life-cycle costs associated with three system concepts for processing the alpha low-level waste (alpha-LLW) stored at the Radioactive Waste Management Complex's Transuranic Storage Area at the INEL. The three system concepts are incineration/melting; thermal treatment/solidification; and sort, treat, and repackage. The SWSDS identifies system functional and operational requirements and assesses implementability; effectiveness; cost; and demonstration, testing, and evaluation (DT E) requirements for each of the three concepts.

Feizollahi, F.; Teheranian, B. (Morrison Knudson Corp., San Francisco, CA (United States). Environmental Services Div.); Quapp, W.J. (EG and G Idaho, Inc., Idaho Falls, ID (United States))

1992-08-01T23:59:59.000Z

334

Tank waste remediation system high-level waste feed processability assessment report  

SciTech Connect (OSTI)

This study evaluates the effect of feed composition on the performance of the high-level vitrification process. It is assumed in this study that the tank wastes are retrieved and blended by tank farms, producing 12 different blends from the single-shell tank farms, two blends of double-shell tank waste, and a separately defined all-tank blend. This blending scenario was chosen only for evaluating the impact of composition on the volume of high- level waste glass produced. Special glass compositions were formulated for each waste blend based on glass property models and the properties of similar glasses. These glasses were formulated to meet the applicable viscosity, electrical conductivity, and liquidus temperature constraints for the identified candidate melters. Candidate melters in this study include the low-temperature stirred melter, which operates at 1050{degrees}C; the reference Hanford Waste Vitrification Plant liquid-fed ceramic melter, which operates at 1150{degrees}C; and the high-temperature, joule-heated melter and the cold-crucible melter, which operate over a temperature range of 1150{degrees}C to 1400{degrees}C. In the most conservative case, it is estimated that 61,000 MT of glass will be produced if the Site`s high-level wastes are retrieved by tank farms and processed in the reference joule-heated melter. If an all-tank blend was processed under the same conditions, the reference melter would produce 21,250 MT of glass. If cross-tank blending were used, it is anticipated that $2.0 billion could be saved in repository disposal costs (based on an average disposal cost of $217,000 per canister) by blending the S, SX, B, and T Tank Farm wastes with other wastes prior to vitrification. General blending among all the tank farms is expected to produce great potential benefit.

Lambert, S.L. [Westinghouse Hanford Co., Richland, WA (United States); Kim, D.S. [Pacific Northwest Lab., Richland, WA (United States)

1994-12-01T23:59:59.000Z

335

Hanford Tank Waste Information Enclosure 1 Hanford Tank Waste Information  

E-Print Network [OSTI]

Hanford Tank Waste Information Enclosure 1 1 Hanford Tank Waste Information 1.0 Summary This information demonstrates the wastes in the twelve Hanford Site tanks meet the definition of transuranic (TRU. The wastes in these twelve (12) tanks are not high-level waste (HLW), and contain more than 100 nanocuries

336

Polyethylene encapsulatin of nitrate salt wastes: Waste form stability, process scale-up, and economics  

SciTech Connect (OSTI)

A polyethylene encapsulation system for treatment of low-level radioactive, hazardous, and mixed wastes has been developed at Brookhaven National Laboratory. Polyethylene has several advantages compared with conventional solidification/stabilization materials such as hydraulic cements. Waste can be encapsulated with greater efficiency and with better waste form performance than is possible with hydraulic cement. The properties of polyethylene relevant to its long-term durability in storage and disposal environments are reviewed. Response to specific potential failure mechanisms including biodegradation, radiation, chemical attack, flammability, environmental stress cracking, and photodegradation are examined. These data are supported by results from extensive waste form performance testing including compressive yield strength, water immersion, thermal cycling, leachability of radioactive and hazardous species, irradiation, biodegradation, and flammability. The bench-scale process has been successfully tested for application with a number of specific problem'' waste streams. Quality assurance and performance testing of the resulting waste form confirmed scale-up feasibility. Use of this system at Rocky Flats Plant can result in over 70% fewer drums processed and shipped for disposal, compared with optimal cement formulations. Based on the current Rocky Flats production of nitrate salt per year, polyethylene encapsulation can yield an estimated annual savings between $1.5 million and $2.7 million, compared with conventional hydraulic cement systems. 72 refs., 23 figs., 16 tabs.

Kalb, P.D.; Heiser, J.H. III; Colombo, P.

1991-07-01T23:59:59.000Z

337

Characterization of the BVEST waste tanks located at ORNL  

SciTech Connect (OSTI)

During the fall of 1996 there was a major effort to sample and analyze the Active Liquid Low-Level Waste (LLLW) tanks at ORNL which include the Melton Valley Storage Tanks (MVST) and the Bethel Valley Evaporator Service Tanks (BVEST). The characterization data summarized in this report was needed to address waste processing options, address concerns dealing with the performance assessment (PA) data for the Waste Isolation Pilot Plant (WIPP), evaluate the waste characteristics with respect to the waste acceptance criteria (WAC) for WIPP and Nevada Test Site (NTS), address criticality concerns, and meet DOT requirements for transporting the waste. This report discusses the analytical characterization data for the supernatant and sludge in the BVEST waste tanks W-21, W-22, and W-23. The isotopic data presented in this report supports the position that fissile isotopes of uranium and plutonium were denatured as required by the administrative controls stated in the ORNL LLLW waste acceptance criteria (WAC). In general, the BVEST sludge was found to be hazardous based on RCRA characteristics and the transuranic alpha activity was well above the 100 nCi/g limit for TRU waste. The characteristics of the BVEST sludge relative to the WIPP WAC limits for fissile gram equivalent, plutonium equivalent activity, and thermal power from decay heat were estimated from the data in this report and found to be far below the upper boundary for any of the remote-handled transuranic waste (RH-TRU) requirements for disposal of the waste in WIPP.

Keller, J.M.; Giaquinto, J.M.; Meeks, A.M.

1997-01-01T23:59:59.000Z

338

Sorbent Testing for the Solidification of Organic Process Waste streams from the Radiochemical Engineering Development Center at Oak Ridge National Laboratory  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) has tasked MSE Technology Applications, Inc. (MSE) with evaluating various sorbents to solidify the radioactive liquid organic waste from the Radiochemical Engineering Development Center (REDC) at Oak Ridge National Laboratory (ORNL). REDC recovers and purifies heavy elements (berkelium, californium, einsteinium, and fermium) from irradiated targets for research and industrial applications. Both aqueous and organic waste streams are discharged from REDC. Organic waste is generated from the plutonium/uranium extraction (PUREX), Cleanex, and Pubex processes.1 The PUREX waste derives from an organic-aqueous isotope separation process for plutonium and uranium fission products, the Cleanex waste derives from the removal of fission products and other impurities from the americium/curium product, and the Pubex waste is derived from the separation process of plutonium from dissolved targets. An aqueous waste stream is also produced from these separation processes. MSE has been tasked to test a grouting formula for the aqueous waste stream that includes specially formulated radioactive shielding materials developed by Science and Technology Applications, LLC. This paper will focus on the sorbent testing work. Based on work performed at Savannah River Site (SRS) (Refs. 1, 2), ORNL tested and evaluated three sorbents capable of solidifying the PUREX, Pubex, and Cleanex waste streams and a composite of the three organic waste streams: Imbiber Beads{sup R} IMB230301 (Imbiber Beads), Nochar A610 Petro Bond, and Petroset II Granular{sup TM} (Petroset II-G). Surrogates of the PUREX, Pubex, Cleanex, and a composite organic waste were used for the bench-scale testing. Recommendations resulting from the ORNL testing included follow-on testing by MSE for two of the three sorbents: Nochar Petro Bond and Petroset II-G. MSE recommended that another clay sorbent, Organoclay BM-QT-199, be added to the test sequence. The sorbent/surrogate combinations were tested at bench scale, 19-liter (L) [5-gallon (gal)] bucket scale, and 208-L (55-gal) drum scale. The testing performed by MSE will help ORNL select the right solidification materials and wasteform generation methods for the design of a new treatment facility. The results could also be used to help demonstrate that ORNL could meet the waste acceptance criteria for the ultimate disposal site for the waste-forms. The organics will be solidified as transuranic waste for disposal at the Waste Isolation Pilot Plant, and the aqueous waste stream will be grouted and disposed of at the Nevada Test Site as low-level waste if real waste testing indicates similar results to the surrogate testing. The objective of this work was to identify a sorbent capable of solidifying PUREX, Pubex, and Cleanex organic wastes individually and a composite of the three organic waste streams. The sorbent and surrogate combinations must also be compatible with processing equipment and maintain stability under a variety of conditions that could occur during storage/shipment of the solidified wastes. (authors)

Bickford, J.; Foote, M. [MSE Technology Applications, Inc., Montana (United States); Taylor, P. [Oak Ridge National Laboratory, Oak Ridge, Tennessee (United States)

2008-07-01T23:59:59.000Z

339

Idaho Waste Vitrification Facilities Project Vitrified Waste Interim Storage Facility  

SciTech Connect (OSTI)

This feasibility study report presents a draft design of the Vitrified Waste Interim Storage Facility (VWISF), which is one of three subprojects of the Idaho Waste Vitrification Facilities (IWVF) project. The primary goal of the IWVF project is to design and construct a treatment process system that will vitrify the sodium-bearing waste (SBW) to a final waste form. The project will consist of three subprojects that include the Waste Collection Tanks Facility, the Waste Vitrification Facility (WVF), and the VWISF. The Waste Collection Tanks Facility will provide for waste collection, feed mixing, and surge storage for SBW and newly generated liquid waste from ongoing operations at the Idaho Nuclear Technology and Engineering Center. The WVF will contain the vitrification process that will mix the waste with glass-forming chemicals or frit and turn the waste into glass. The VWISF will provide a shielded storage facility for the glass until the waste can be disposed at either the Waste Isolation Pilot Plant as mixed transuranic waste or at the future national geological repository as high-level waste glass, pending the outcome of a Waste Incidental to Reprocessing determination, which is currently in progress. A secondary goal is to provide a facility that can be easily modified later to accommodate storage of the vitrified high-level waste calcine. The objective of this study was to determine the feasibility of the VWISF, which would be constructed in compliance with applicable federal, state, and local laws. This project supports the Department of Energy’s Environmental Management missions of safely storing and treating radioactive wastes as well as meeting Federal Facility Compliance commitments made to the State of Idaho.

Bonnema, Bruce Edward

2001-09-01T23:59:59.000Z

340

Documentation of acceptable knowledge for Los Alamos National Laboratory Plutonium Facility TRU waste stream  

SciTech Connect (OSTI)

Characterization of transuranic waste from the LANL Plutonium Facility for certification and transportation to WIPP includes the use of acceptable knowledge as specified in the WIPP Quality Assurance Program Plan. In accordance with a site specific procedure, documentation of acceptable knowledge for retrievably stored and currently generated transuranic waste streams is in progress at LANL. A summary overview of the TRU waste inventory is complete and documented in the Sampling Plan. This document also includes projected waste generation, facility missions, waste generation processes, flow diagrams, times, and material inputs. The second part of acceptable knowledge documentation consists of assembling more detailed acceptable knowledge information into auditable records and is expected to require several years to complete. These records for each waste stream must support final assignment of waste matrix parameters, EPA hazardous waste numbers, and radionuclide characterization. They must also include a determination whether waste streams are defense waste streams for compliance with the WIPP Land Withdrawal Act. The LANL Plutonium Facility`s mission is primarily plutonium processing in basic special nuclear material (SNM) research activities to support national defense and energy programs. It currently has about 100 processes ranging from SNM recovery from residues to development of plutonium 238 heat sources for space applications. Its challenge is to characterize and certify waste streams from such diverse and dynamic operations using acceptable knowledge. This paper reports the progress on the certification of the first of these waste streams to the WIPP WAC.

Montoya, A.J.; Gruetzmacher, K.M.; Foxx, C.L.; Rogers, P.Z.

1998-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Field study of disposed solid wastes from advanced coal processes  

SciTech Connect (OSTI)

Radian Corporation and the North Dakota Energy and Environmental Research Center (EERC) are funded to develop information to be used by private industry and government agencies for managing solid wastes produced by advanced coal combustion processes. This information will be developed by conducting several field studies on disposed wastes from these processes. Data will be collected to characterize these wastes and their interactions with the environments in which they are disposed. Three sites were selected for the field studies: Colorado Ute's fluidized bed combustion (FBC) unit in Nucla, Colorado; Ohio Edison's limestone injection multistage burner (LIMB) retrofit in Lorain, Ohio; and Freeman United's mine site in central Illinois with wastes supplied by the nearby Midwest Grain FBC unit. During the past year, field monitoring and sampling of the four landfill test cases constructed in 1989 and 1991 has continued. Option 1 of the contract was approved last year to add financing for the fifth test case at the Freeman United site. The construction of the Test Case 5 cells is scheduled to begin in November, 1992. Work during this past year has focused on obtaining data on the physical and chemical properties of the landfilled wastes, and on developing a conceptual framework for interpreting this information. Results to date indicate that hydration reactions within the landfilled wastes have had a major impact on the physical and chemical properties of the materials but these reactions largely ceased after the first year, and physical properties have changed little since then. Conditions in Colorado remained dry and no porewater samples were collected. In Ohio, hydration reactions and increases in the moisture content of the waste tied up much of the water initially infiltrating the test cells.

Not Available

1992-01-01T23:59:59.000Z

342

Hanford contact-handled transuranic drum retrieval project planning document  

SciTech Connect (OSTI)

The Hanford Site is one of several US Department of Energy (DOE) sites throughout the US that has generated and stored transuranic (TRU) wastes. The wastes were primarily placed in 55-gallon drums, stacked in trenches, and covered with soil. In 1970, the Nuclear Regulatory Commission ordered that TRU wastes be segregated from other radioactive wastes and placed in retrievable storage until such time that the waste could be sent to a geologic repository and permanently disposed. Retrievable storage also defined container storage life by specifying that a container must be retrievable as a contamination-free container for 20 years. Hanford stored approximately 37,400 TRU containers in 20-year retrievable storage from 1970 to 1988. The Hanford TRU wastes placed in 20-year retrievable storage are considered disposed under existing Resource Conservation and Recovery Act (RCRA) regulations since they were placed in storage prior to September 1988. The majority of containers were 55-gallon drums, but 20-year retrievable storage includes several TRU wastes covered with soil in different storage methods.

DEMITER, J.A.

1998-11-17T23:59:59.000Z

343

International Best Practices for Pre-Processing and Co-Processing Municipal Solid Waste and Sewage Sludge in the Cement Industry  

E-Print Network [OSTI]

Co-processing Municipal Solid Waste and Sewage Sludge in theno date. “Integrated Solid Waste Management. ” Presentationincineration of Municipal Solid Waste in Cement Industry. :

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

344

Waste Energy Analysis Recovery for a Typical Food Processing Plant  

E-Print Network [OSTI]

An energy analysis made for the Joan of Arc Food Processing Plant in St. Francisville, Louisiana indicated that a significant quantity of waste heat energy was being released to the atmosphere in the forms of low quality steam and hot flue gases...

Miller, P. H.; Mann, L., Jr.

1980-01-01T23:59:59.000Z

345

Waste Heat Recovery from Refrigeration in a Meat Processing Facility  

E-Print Network [OSTI]

A case study is reviewed on a heat recovery system installed in a meat processing facility to preheat water for the plant hot water supply. The system utilizes waste superheat from the facility's 1,350-ton ammonia refrigeration system. The heat...

Murphy, W. T.; Woods, B. E.; Gerdes, J. E.

1980-01-01T23:59:59.000Z

346

Efficient separations & processing crosscutting program  

SciTech Connect (OSTI)

The Efficient Separations and Processing Crosscutting Program (ESP) was created in 1991 to identify, develop, and perfect chemical and physical separations technologies and chemical processes which treat wastes and address environmental problems throughout the DOE complex. The ESP funds several multiyear tasks that address high-priority waste remediation problems involving high-level, low-level, transuranic, hazardous, and mixed (radioactive and hazardous) wastes. The ESP supports applied research and development (R & D) leading to the demonstration or use of these separations technologies by other organizations within the Department of Energy (DOE), Office of Environmental Management.

NONE

1996-08-01T23:59:59.000Z

347

Office of Environmental Management Taps Small Business for Waste...  

Broader source: Energy.gov (indexed) [DOE]

task of securing and isolating defense-generated Transuranic waste. Celeritex LLC is a joint venture, temporarily bringing together Project Services Group, LLC, and DeNuke...

348

The Nevada Test Site Legacy TRU Waste - The WIPP Central Characterization Project  

SciTech Connect (OSTI)

This paper discusses the Central Characterization Project (CCP) designed by the Waste Isolation Pilot Plant (WIPP) to aid sites, especially those sites with small quantities of transuranic (TRU) waste streams, in disposing of legacy waste at their facility. Because of the high cost of contracting vendors with the characterization capabilities necessary to meet the WIPP Waste Acceptance Criteria, utilizing the CCP is meant to simplify the process for small quantity sites. The paper will describe the process of mobilization of the vendors through CCP, the current production milestones that have been met, and the on-site lessons learned.

Norton, J. F.; Lahoud, R. G.; Foster, B. D.; VanMeighem, J.

2003-02-25T23:59:59.000Z

349

Study on a regeneration process of LiCl-KCl eutectic based waste salt generated from the pyrochemical process  

SciTech Connect (OSTI)

A regeneration process of LiCl-KCl eutectic waste salt generated from the pyrochemical process of spent nuclear fuel has been studied. This regeneration process is composed of a chemical conversion process and a vacuum distillation process. Through the regeneration process, a high efficiency of renewable salt recovery can be obtained from the waste salt and rare earth nuclides in the waste salt can be separated as oxide or phosphate forms. Thus, the regeneration process can contribute greatly to a reduction of the waste volume and a creation of durable final waste forms. (authors)

Eun, H.C.; Cho, Y.Z.; Choi, J.H.; Kim, J.H.; Lee, T.K.; Park, H.S.; Kim, I.T.; Park, G.I. [Nuclear Fuel Cycle Waste Treatment Research Division, Korea Atomic Energy Research Institute, 989-111 Daedeok-Daero, Yuseong-Gu, Daejeon 3054-353 (Korea, Republic of)

2013-07-01T23:59:59.000Z

350

Removing nuclear waste, one shipment at a time  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Removing nuclear waste, one shipment at a time Removing nuclear waste, one shipment at a time The Lab's 1,000th shipment of transuranic waste recently left Los Alamos, on its way...

351

Mercury Reduction and Removal from High Level Waste at the Defense Waste Processing Facility - 12511  

SciTech Connect (OSTI)

The Defense Waste Processing Facility processes legacy nuclear waste generated at the Savannah River Site during production of enriched uranium and plutonium required by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. One of the constituents in the nuclear waste is mercury, which is present because it served as a catalyst in the dissolution of uranium-aluminum alloy fuel rods. At high temperatures mercury is corrosive to off-gas equipment, this poses a major challenge to the overall vitrification process in separating mercury from the waste stream prior to feeding the high temperature melter. Mercury is currently removed during the chemical process via formic acid reduction followed by steam stripping, which allows elemental mercury to be evaporated with the water vapor generated during boiling. The vapors are then condensed and sent to a hold tank where mercury coalesces and is recovered in the tank's sump via gravity settling. Next, mercury is transferred from the tank sump to a purification cell where it is washed with water and nitric acid and removed from the facility. Throughout the chemical processing cell, compounds of mercury exist in the sludge, condensate, and off-gas; all of which present unique challenges. Mercury removal from sludge waste being fed to the DWPF melter is required to avoid exhausting it to the environment or any negative impacts to the Melter Off-Gas system. The mercury concentration must be reduced to a level of 0.8 wt% or less before being introduced to the melter. Even though this is being successfully accomplished, the material balances accounting for incoming and collected mercury are not equal. In addition, mercury has not been effectively purified and collected in the Mercury Purification Cell (MPC) since 2008. A significant cleaning campaign aims to bring the MPC back up to facility housekeeping standards. Two significant investigations are being undertaken to restore mercury collection. The SMECT mercury pump has been removed from the tank and will be functionally tested. Also, research is being conducted by the Savannah River National Laboratory to determine the effects of antifoam addition on the behavior of mercury. These path forward items will help us better understand what is occurring in the mercury collection system and ultimately lead to an improved DWPF production rate and mercury recovery rate. (authors)

Behrouzi, Aria [Savannah River Remediation, LLC (United States); Zamecnik, Jack [Savannah River National Laboratory, Aiken, South Carolina, 29808 (United States)

2012-07-01T23:59:59.000Z

352

Process for recovery of palladium from nuclear fuel reprocessing wastes  

DOE Patents [OSTI]

Palladium is selectively removed from spent nuclear fuel reprocessing waste by adding sugar to a strong nitric acid solution of the waste to partially denitrate the solution and cause formation of an insoluble palladium compound. The process includes the steps of: (a) adjusting the nitric acid content of the starting solution to about 10 M; (b) adding 50% sucrose solution in an amount sufficient to effect the precipitation of the palladium compound; (c) heating the solution at reflux temperature until precipitation is complete; and (d) centrifuging the solution to separate the precipitated palladium compound from the supernatant liquid.

Campbell, D.O.; Buxton, S.R.

1980-06-16T23:59:59.000Z

353

Waste Processing Annual Technology Development Report 2007  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy Cooperation | Department of EnergyDepartmentEnergyU.S. DOE EnvironmentalProcessing

354

Processing of solid mixed waste containing radioactive and hazardous materials  

DOE Patents [OSTI]

Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.

Gotovchikov, Vitaly T. (Moscow, RU); Ivanov, Alexander V. (Moscow, RU); Filippov, Eugene A. (Moscow, RU)

1998-05-12T23:59:59.000Z

355

Processing of solid mixed waste containing radioactive and hazardous materials  

DOE Patents [OSTI]

Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.

Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.

1998-05-12T23:59:59.000Z

356

Process for the recovery of curium-244 from nuclear waste  

SciTech Connect (OSTI)

A process has been designed for the recovery of curium from purex waste. Curium and americium are separated from the lanthanides by a TALSPEAK extraction process using differential extraction. Equations were derived for the estimation of the economically optimum conditions for the extraction using laboratory batch extraction data. The preparation of feed for the extraction involves the removal of nitric acid from the Purex waste by vaporization under reduced pressure, the leaching of soluble nitrates from the resulting cake, and the oxalate precipitation of a pure lanthanide-actinide fraction. Final separation of the curium from americium is done by ion-exchange. The steps of the process, except ion-exchange, were tested on a laboratory scale and workable conditions were determined.

Posey, J.C.

1980-10-01T23:59:59.000Z

357

Basic TRUEX process for Rocky Flats Plant  

SciTech Connect (OSTI)

The Generic TRUEX Model was used to develop a TRUEX process flowsheet for recovering the transuranics (Pu, Am) from a nitrate waste stream at Rocky Flats Plant. The process was designed so that it is relatively insensitive to changes in process feed concentrations and flow rates. Related issues are considered, including solvent losses, feed analysis requirements, safety, and interaction with an evaporator system for nitric acid recycle.

Leonard, R.A.; Chamberlain, D.B.; Dow, J.A.; Farley, S.E.; Nunez, L.; Regalbuto, M.C.; Vandegrift, G.F.

1994-08-01T23:59:59.000Z

358

Process modeling of hydrogen production from municipal solid waste  

SciTech Connect (OSTI)

The ASPEN PLUS commercial simulation software has been used to develop a process model for a conceptual process to convert municipal solid waste (MSW) to hydrogen. The process consists of hydrothermal treatment of the MSW in water to create a slurry suitable as feedstock for an oxygen blown Texaco gasifier. A method of reducing the complicated MSW feed material to a manageable set of components is outlined along with a framework for modeling the stoichiometric changes associated with the hydrothermal treatment process. Model results indicate that 0.672 kmol/s of hydrogen can be produced from the processing of 30 kg/s (2600 tonne/day) of raw MSW. A number of variations on the basic processing parameters are explored and indicate that there is a clear incentive to reduce the inert fraction in the processed slurry feed and that cofeeding a low value heavy oil may be economically attractive.

Thorsness, C.B.

1995-01-01T23:59:59.000Z

359

An Effective Waste Management Process for Segregation and Disposal of Legacy Mixed Waste at Sandia National Laboratories/New Mexico  

SciTech Connect (OSTI)

Sandia National Laboratories/New Mexico (SNL/NM) is a research and development facility that generates many highly diverse, low-volume mixed waste streams. Under the Federal Facility Compliance Act, SNL/NM must treat its mixed waste in storage to meet the Land Disposal Restrictions treatment standards. Since 1989, approximately 70 cubic meters (2500 cubic feet) of heterogeneous, poorly characterized and inventoried mixed waste was placed in storage that could not be treated as specified in the SNL/NM Site Treatment Plan. A process was created to sort the legacy waste into sixteen well- defined, properly characterized, and precisely inventoried mixed waste streams (Treatability Groups) and two low-level waste streams ready for treatment or disposal. From June 1995 through September 1996, the entire volume of this stored mixed waste was sorted and inventoried through this process. This process was planned to meet the technical requirements of the sorting operation and to identify and address the hazards this operation presented. The operations were routinely adapted to safely and efficiently handle a variety of waste matrices, hazards, and radiological conditions. This flexibility was accomplished through administrative and physical controls integrated into the sorting operations. Many Department of Energy facilities are currently facing the prospect of sorting, characterizing, and treating a large inventory of mixed waste. The process described in this paper is a proven method for preparing a diverse, heterogeneous mixed waste volume into segregated, characterized, inventoried, and documented waste streams ready for treatment or disposal.

Hallman, Anne K. [Sandia National Labs., Albuquerque, NM (United States); Meyer, Dann [IT Corporation, Albuquerque, NM (United States); Rellergert, Carla A. [Roy F. Weston, Inc., Albuquerque, NM (United States); Schriner, Joseph A. [Automated Solutions of Albuquerque, Albuquerque, NM (United States)

1998-06-01T23:59:59.000Z

360

Defense Waste Processing Facility (DWPF), Modular CSSX Unit (CSSX), and Waste Transfer Line System of Salt Processing Program (U)  

SciTech Connect (OSTI)

All of the waste streams from ARP, MCU, and SWPF processes will be sent to DWPF for vitrification. The impact these new waste streams will have on DWPF's ability to meet its canister production goal and its ability to support the Salt Processing Program (ARP, MCU, and SWPF) throughput needed to be evaluated. DWPF Engineering and Operations requested OBU Systems Engineering to evaluate DWPF operations and determine how the process could be optimized. The ultimate goal will be to evaluate all of the Liquid Radioactive Waste (LRW) System by developing process modules to cover all facilities/projects which are relevant to the LRW Program and to link the modules together to: (1) study the interfaces issues, (2) identify bottlenecks, and (3) determine the most cost effective way to eliminate them. The results from the evaluation can be used to assist DWPF in identifying improvement opportunities, to assist CBU in LRW strategic planning/tank space management, and to determine the project completion date for the Salt Processing Program.

CHANG, ROBERT

2006-02-02T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

THE USE OF POLYMERS IN RADIOACTIVE WASTE PROCESSING SYSTEMS  

SciTech Connect (OSTI)

The Savannah River Site (SRS), one of the largest U.S. Department of Energy (DOE) sites, has operated since the early 1950s. The early mission of the site was to produce critical nuclear materials for national defense. Many facilities have been constructed at the SRS over the years to process, stabilize and/or store radioactive waste and related materials. The primary materials of construction used in such facilities are inorganic (metals, concrete), but polymeric materials are inevitably used in various applications. The effects of aging, radiation, chemicals, heat and other environmental variables must therefore be understood to maximize service life of polymeric components. In particular, the potential for dose rate effects and synergistic effects on polymeric materials in multivariable environments can complicate compatibility reviews and life predictions. The selection and performance of polymeric materials in radioactive waste processing systems at the SRS are discussed.

Skidmore, E.; Fondeur, F.

2013-04-15T23:59:59.000Z

362

Characterization of the MVST waste tanks located at ORNL  

SciTech Connect (OSTI)

During the fall of 1996 there was a major effort to sample and analyze the Active Liquid Low-Level Waste (LLLW) tanks at ORNL which include the Melton Valley Storage Tanks (MVST) and the Bethel Valley Evaporator Service Tanks (BVEST). The characterization data summarized in this report was needed to address waste processing options, address concerns of the performance assessment (PA) data for the Waste Isolation Pilot Plant (WIPP), evaluate the characteristics with respect to the waste acceptance criteria (WAC) for WIPP and Nevada Test Site (NTS), address criticality concerns, and meet DOT requirements for transporting the waste. This report only discusses the analytical characterization data for the MVST waste tanks. The isotopic data presented in this report support the position that fissile isotopes of uranium and plutonium were ``denatured`` as required by administrative controls. In general, MVST sludge was found to be both hazardous by RCRA characteristics and the transuranic alpha activity was well about the limit for TRU waste. The characteristics of the MVST sludge relative to the WIPP WAC limits for fissile gram equivalent, plutonium equivalent activity, and thermal power from decay heat, were estimated from the data in this report and found to be far below the upper boundary for any of the remote-handled transuranic waste requirements for disposal of the waste in WIPP.

Keller, J.M.; Giaquinto, J.M.; Meeks, A.M.

1996-12-01T23:59:59.000Z

363

An effective waste management process for segregation and disposal of legacy mixed waste at Sandia National Laboratories/New Mexico  

SciTech Connect (OSTI)

Sandia National Laboratories/New Mexico (SNL/NM) is a research and development facility that generates many highly diverse, low-volume mixed waste streams. Under the Federal Facility Compliance Act, SNL/NM must treat its mixed waste in storage to meet the Land Disposal Restrictions treatment standards. Since 1989, approximately 70 cubic meters (2,500 cubic feet) of heterogeneous, poorly characterized and inventoried mixed waste was placed in storage that could not be treated as specified in the SNL/NM Site Treatment Plan. A process was created to sort the legacy waste into sixteen well-defined, properly characterized, and accurately inventoried mixed waste streams (Treatability Groups) and two low-level waste streams ready for treatment or disposal. From June 1995 through September 1996, the entire volume of this stored mixed waste was sorted and inventoried. This process was planned to meet the technical requirements of the sorting operation and to identify and address the hazards this operation presented. The operations were routinely adapted to safely and efficiently handle a variety of waste matrices, hazards, and radiological conditions. This flexibility was accomplished through administrative and physical controls integrated into the sorting operations. Many Department of Energy facilities are currently facing the prospect of sorting, characterizing, and treating a large inventory of mixed waste. The process described in this report is a proven method for preparing a diverse, heterogeneous mixed waste volume into segregated, characterized, inventoried, and documented waste streams ready for treatment or disposal.

Hallman, A.K. [Sandia National Labs., Albuquerque, NM (United States); Meyer, D. [IT Corp., Albuquerque, NM (United States); Rellergert, C.A. [Roy F. Weston, Inc., Albuquerque, NM (United States); Schriner, J.A. [Automated Solutions of Albuquerque, Inc., NM (United States)

1998-04-01T23:59:59.000Z

364

DOCKET NO: A-93-02 (CERTIFICATION RULEMAKING) 40 CFR 191 COMPLIANCE DETERMINATION FOR THE WASTE ISOLATION  

E-Print Network [OSTI]

/4/96 DOE Rpt, DOE/CAO-95-1121: Transuranic Waste Baseline Inventory Report (Revision 2) 12/95 II-A-21 6/1/96 DOE Study -- DOE/CAO-95-3102, Radioactive Waste Processing And Volume Reduction Technology Study 10" a Report Relevant to Actinide Solubility Studies at the WIPP Site 6/12/95 II-A-19 4/30/96 DOE Report, DOE/CAO

365

D11 WASTE DISPOSAL FACILITIES FOR TRANSURANIC WASTE  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana. DOCUMENTS AVAILABLEReport 2009Site |Documents D.O.E. RACE TO ZERO

366

Transuranic Waste Acceptance Criteria for the Waste Isolation Pilot Plant |  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNGInternationalTechnologyDepartmentStorage Interface TransportationDepartment

367

Multi-discipline Waste Acceptance Process at the Nevada National Security Site - 13573  

SciTech Connect (OSTI)

The Nevada National Security Site low-level radioactive waste disposal facility acceptance process requires multiple disciplines to ensure the protection of workers, the public, and the environment. These disciplines, which include waste acceptance, nuclear criticality, safety, permitting, operations, and performance assessment, combine into the overall waste acceptance process to assess low-level radioactive waste streams for disposal at the Area 5 Radioactive Waste Management Site. Four waste streams recently highlighted the integration of these disciplines: the Oak Ridge Radioisotope Thermoelectric Generators and Consolidated Edison Uranium Solidification Project material, West Valley Melter, and classified waste. (authors)

Carilli, Jhon T. [US Department Of Energy, Nevada Site Office, P. O. Box 98518, Las Vegas, Nevada 89193-8518 (United States)] [US Department Of Energy, Nevada Site Office, P. O. Box 98518, Las Vegas, Nevada 89193-8518 (United States); Krenzien, Susan K. [Navarro-Intera, LLC, P. O. Box 98952, Las Vegas, Nevada 89193-8952 (United States)] [Navarro-Intera, LLC, P. O. Box 98952, Las Vegas, Nevada 89193-8952 (United States)

2013-07-01T23:59:59.000Z

368

Guidelines for developing certification programs for newly generated TRU waste  

SciTech Connect (OSTI)

These guidelines were prepared with direction from the US Department of Energy (DOE) Transuranic (TRU) Waste Management Program in support of the DOE effort to certify that newly generated TRU wastes meet the Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria. The guidelines provide instructions for generic Certification Program preparation for TRU-waste generators preparing site-specific Certification Programs in response to WIPP requirements. The guidelines address all major aspects of a Certification Program that are necessary to satisfy the WIPP Waste Acceptance Criteria and their associated Compliance Requirements and Certification Quality Assurance Requirements. The details of the major element of a Certification Program, namely, the Certification Plan, are described. The Certification Plan relies on supporting data and control documentation to provide a traceable, auditable account of certification activities. Examples of specific parts of the Certification Plan illustrate the recommended degree of detail. Also, a brief description of generic waste processes related to certification activities is included.

Whitty, W.J.; Ostenak, C.A.; Pillay, K.K.S.; Geoffrion, R.R.

1983-05-01T23:59:59.000Z

369

Sodium-Bearing Waste Treatment Alternatives Implementation Study  

SciTech Connect (OSTI)

The purpose of this document is to discuss issues related to the implementation of each of the five down-selected INEEL/INTEC radioactive liquid waste (sodium-bearing waste - SBW) treatment alternatives and summarize information in three main areas of concern: process/technical, environmental permitting, and schedule. Major implementation options for each treatment alternative are also identified and briefly discussed. This report may touch upon, but purposely does not address in detail, issues that are programmatic in nature. Examples of these include how the SBW will be classified with respect to the Nuclear Waste Policy Act (NWPA), status of Waste Isolation Pilot Plant (WIPP) permits and waste storage availability, available funding for implementation, stakeholder issues, and State of Idaho Settlement Agreement milestones. It is assumed in this report that the SBW would be classified as a transuranic (TRU) waste suitable for disposal at WIPP, located in New Mexico, after appropriate treatment to meet transportation requirements and waste acceptance criteria (WAC).

Charles M. Barnes; James B. Bosley; Clifford W. Olsen

2004-07-01T23:59:59.000Z

370

Radioactive Waste Management Manual  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

This Manual further describes the requirements and establishes specific responsibilities for implementing DOE O 435.1, Radioactive Waste Management, for the management of DOE high-level waste, transuranic waste, low-level waste, and the radioactive component of mixed waste. Change 1 dated 6/19/01 removes the requirement that Headquarters is to be notified and the Office of Environment, Safety and Health consulted for exemptions for use of non-DOE treatment facilities. Certified 1-9-07.

1999-07-09T23:59:59.000Z

371

Waste Form Development for the Solidification of PDCF/MOX Liquid Waste Streams  

SciTech Connect (OSTI)

At the Savannah River Site, part of the Department of Energy's nuclear materials complex located in South Carolina, cementation has been selected as the solidification method for high-alpha and low-activity waste streams generated in the planned plutonium disposition facilities. A Waste Solidification Building (WSB) that will be used to treat and solidify three radioactive liquid waste streams generated by the Pit Disassembly and Conversion Facility) and the Mixed Oxide Fuel Fabrication Facility is in the preliminary design stage. The WSB is expected to treat a transuranic (TRU) waste stream composed primarily of americium and two low-level waste (LLW) streams. The acidic wastes will be concentrated in the WSB evaporator and neutralized in a cement head tank prior to solidification. A series of TRU mixes were prepared to produce waste forms exhibiting a range of processing and cured properties. The LLW mixes were prepared using the premix from the preferred TRU waste form. All of the waste forms tested passed the Toxicity Characteristic Leaching Procedure. After processing in the WSB, current plans are to dispose of the solidified TRU waste at the Waste Isolation Pilot Plant in New Mexico and the solidified LLW waste at an approved low-level waste disposal facility.

COZZI, ALEX

2004-02-18T23:59:59.000Z

372

Evaluation of prospective hazardous waste treatment technologies for use in processing low-level mixed wastes at Rocky Flats  

SciTech Connect (OSTI)

Several technologies for destroying or decontaminating hazardous wastes were evaluated (during early 1988) as potential processes for treating low-level mixed wastes destined for destruction in the Fluidized Bed Incinerator. The processes that showed promise were retained for further consideration and placed into one (or more) of three categories based on projected availability: short, intermediate, and long-term. Three potential short-term options were identified for managing low-level mixed wastes generated or stored at the Rocky Flats Plant (operated by Rockwell International in 1988). These options are: (1) Continue storing at Rocky Flats, (2) Ship to Nevada Test Site for landfill disposal, or (3) Ship to the Idaho National Engineering Laboratory for incineration in the Waste Experimental Reduction Facility. The third option is preferable because the wastes will be destroyed. Idaho National Engineering Laboratory has received interim status for processing solid and liquid low-level mixed wastes. However, low-level mixed wastes will continue to be stored at Rocky Flats until the Department of Energy approval is received to ship to the Nevada Test Site or Idaho National Engineering Laboratory. Potential intermediate and long-term processes were identified; however, these processes should be combined into complete waste treatment systems'' that may serve as alternatives to the Fluidized Bed Incinerator. Waste treatment systems will be the subject of later work. 59 refs., 2 figs.

McGlochlin, S.C.; Harder, R.V.; Jensen, R.T.; Pettis, S.A.; Roggenthen, D.K.

1990-09-18T23:59:59.000Z

373

1993 Solid Waste Reference Forecast Summary  

SciTech Connect (OSTI)

This report, which updates WHC-EP-0567, 1992 Solid Waste Reference Forecast Summary, (WHC 1992) forecasts the volumes of solid wastes to be generated or received at the US Department of Energy Hanford Site during the 30-year period from FY 1993 through FY 2022. The data used in this document were collected from Westinghouse Hanford Company forecasts as well as from surveys of waste generators at other US Department of Energy sites who are now shipping or plan to ship solid wastes to the Hanford Site for disposal. These wastes include low-level and low-level mixed waste, transuranic and transuranic mixed waste, and nonradioactive hazardous waste.

Valero, O.J.; Blackburn, C.L. [Westinghouse Hanford Co., Richland, WA (United States); Kaae, P.S.; Armacost, L.L.; Garrett, S.M.K. [Pacific Northwest Lab., Richland, WA (United States)

1993-08-01T23:59:59.000Z

374

Development of Polymeric Waste Forms for the Encapsulation of Toxic Wastes Using an Emulsion-Encapsulation Based Process  

SciTech Connect (OSTI)

Developed technologies in vitrification, cement, and polymeric materials manufactured using flammable organic solvents have been used to encapsulate solid wastes, including low-level radioactive materials, but are impractical for high salt-content waste streams (Maio, 1998). In this work, we investigate an emulsification process for producing an aqueous-based polymeric waste form as a preliminary step towards fabricating hybrid organic/inorganic polyceram matrices. The material developed incorporates epoxy resin and polystyrene-butadiene (PSB) latex to produce a waste form that is non-flammable, light weight, of relatively low cost, and that can be loaded to a relatively high weight content of waste materials. Sodium nitrate was used as a model for the salt waste. Small-scale samples were manufactured and analyzed using leach tests designed to measure the diffusion coefficient and leachability index for the fastest diffusing species in the waste form, the salt ions. The microstructure and composition of the samples were probed using SEM/EDS techniques. The results show that some portion of the salt migrates towards the exterior surfaces of the waste forms during the curing process. A portion of the salt in the interior of the sample is contained in polymer corpuscles or sacs. These sacs are embedded in a polymer matrix phase that contains fine, well-dispersed salt crystals. The diffusion behavior observed in sections of the waste forms indicates that samples prepared using this emulsion process meet or exceed the leachability criteria suggested for low level radioactivity waste forms.

Evans, R.; Quach, A.; Birnie, D. P.; Saez, A. E.; Ela, W. P.; Zeliniski, B. J. J.; Xia, G.; Smith, H.

2003-01-01T23:59:59.000Z

375

Waste-heat recovery in batch processes using heat storage  

SciTech Connect (OSTI)

The waste-heat recovery in batch processes has been studied using the pinch-point method. The aim of the work has been to investigate theoretical and practical approaches to the design of heat-exchanger networks, including heat storage, for waste-heat recovery in batch processes. The study is limited to the incorporation of energy-storage systems based on fixed-temperature variable-mass stores. The background for preferring this to the alternatives (variable-temperature fixed-mass and constant-mass constant-temperature (latent-heat) stores) is given. It is shown that the maximum energy-saving targets as calculated by the pinch-point method (time average model, TAM) can be achieved by locating energy stores at either end of each process stream. This theoretically large number of heat-storage tanks (twice the number of process streams) can be reduced to just a few tanks. A simple procedure for determining a number of heat-storage tanks sufficient to achieve the maximum energy-saving targets as calculated by the pinch-point method is described. This procedure relies on combinatorial considerations, and could therefore be labeled the combinatorial method for incorporation of heat storage in heat-exchanger networks. Qualitative arguments justifying the procedure are presented. For simple systems, waste-heat recovery systems with only three heat-storage temperatures (a hot storage, a cold storage, and a heat store at the pinch temperature) often can achieve the maximum energy-saving targets. Through case studies, six of which are presented, it is found that a theoretically large number of heat-storage tanks (twice the number of process streams) can be reduced to just a few tanks. The description of these six cases is intended to be sufficiently detailed to serve as benchmark cases for development of alternative methods.

Stoltze, S.; Mikkelsen, J.; Lorentzen, B.; Petersen, P.M.; Qvale, B. [Technical Univ. of Denmark, Lyngby (Denmark). Lab. for Energetics

1995-06-01T23:59:59.000Z

376

Catalytic extraction processing of contaminated scrap metal  

SciTech Connect (OSTI)

Molten Metal Technology was awarded a contract to demonstrate the applicability of the Catalytic Extraction Process, a proprietary process that could be applied to US DOE`s inventory of low level mixed waste. This paper is a description of that technology, and included within this document are discussions of: (1) Program objectives, (2) Overall technology review, (3) Organic feed conversion to synthetic gas, (4) Metal, halogen, and transuranic recovery, (5) Demonstrations, (6) Design of the prototype facility, and (7) Results.

Griffin, T.P.; Johnston, J.E.; Payea, B.M.; Zeitoon, B.M.

1995-12-01T23:59:59.000Z

377

Reevaluation Of Vitrified High-Level Waste Form Criteria For Potential Cost Savings At The Defense Waste Processing Facility  

SciTech Connect (OSTI)

At the Savannah River Site (SRS) the Defense Waste Processing Facility (DWPF) has been immobilizing SRS's radioactive high level waste (HLW) sludge into a durable borosilicate glass since 1996. Currently the DWPF has poured over 3,500 canisters, all of which are compliant with the U. S. Department of Energy's (DOE) Waste Acceptance Product Specifications for Vitrified High-Level Waste Forms (WAPS) and therefore ready to be shipped to a federal geologic repository for permanent disposal. Due to DOE petitioning to withdraw the Yucca Mountain License Application (LA) from the Nuclear Regulatory Commission (NRC) in 2010 and thus no clear disposal path for SRS canistered waste forms, there are opportunities for cost savings with future canister production at DWPF and other DOE producer sites by reevaluating high-level waste form requirements and compliance strategies and reducing/eliminating those that will not negatively impact the quality of the canistered waste form.

Ray, J. W.; Marra, S. L.; Herman, C. C.

2013-01-09T23:59:59.000Z

378

Reevaluation of Vitrified High-Level Waste Form Criteria for Potential Cost Savings at the Defense Waste Processing Facility - 13598  

SciTech Connect (OSTI)

At the Savannah River Site (SRS) the Defense Waste Processing Facility (DWPF) has been immobilizing SRS's radioactive high level waste (HLW) sludge into a durable borosilicate glass since 1996. Currently the DWPF has poured over 3,500 canisters, all of which are compliant with the U. S. Department of Energy's (DOE) Waste Acceptance Product Specifications for Vitrified High-Level Waste Forms (WAPS) and therefore ready to be shipped to a federal geologic repository for permanent disposal. Due to DOE petitioning to withdraw the Yucca Mountain License Application (LA) from the Nuclear Regulatory Commission (NRC) in 2010 and thus no clear disposal path for SRS canistered waste forms, there are opportunities for cost savings with future canister production at DWPF and other DOE producer sites by reevaluating high-level waste form requirements and compliance strategies and reducing/eliminating those that will not negatively impact the quality of the canistered waste form. (authors)

Ray, J.W. [Savannah River Remediation (United States)] [Savannah River Remediation (United States); Marra, S.L.; Herman, C.C. [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)

2013-07-01T23:59:59.000Z

379

Overview of Fiscal Year 2002 Research and Development for Savannah River Site's Salt Waste Processing Facility  

SciTech Connect (OSTI)

The Department of Energy's (DOE) Savannah River Site (SRS) high-level waste program is responsible for storage, treatment, and immobilization of high-level waste for disposal. The Salt Processing Program (SPP) is the salt (soluble) waste treatment portion of the SRS high-level waste effort. The overall SPP encompasses the selection, design, construction and operation of treatment technologies to prepare the salt waste feed material for the site's grout facility (Saltstone) and vitrification facility (Defense Waste Processing Facility). Major constituents that must be removed from the salt waste and sent as feed to Defense Waste Processing Facility include actinides, strontium, cesium, and entrained sludge. In fiscal year 2002 (FY02), research and development (R&D) on the actinide and strontium removal and Caustic-Side Solvent Extraction (CSSX) processes transitioned from technology development for baseline process selection to providing input for conceptual design of the Salt Waste Processing Facility. The SPP R&D focused on advancing the technical maturity, risk reduction, engineering development, and design support for DOE's engineering, procurement, and construction (EPC) contractors for the Salt Waste Processing Facility. Thus, R&D in FY02 addressed the areas of actual waste performance, process chemistry, engineering tests of equipment, and chemical and physical properties relevant to safety. All of the testing, studies, and reports were summarized and provided to the DOE to support the Salt Waste Processing Facility, which began conceptual design in September 2002.

H. D. Harmon, R. Leugemors, PNNL; S. Fink, M. Thompson, D. Walker, WSRC; P. Suggs, W. D. Clark, Jr

2003-02-26T23:59:59.000Z

380

Device Assembly Facility (DAF) Glovebox Radioactive Waste Characterization  

SciTech Connect (OSTI)

The Device Assembly Facility (DAF) at the Nevada Test Site (NTS) provides programmatic support to the Joint Actinide Shock Physics Experimental Research (JASPER) Facility in the form of target assembly. The target assembly activities are performed in a glovebox at DAF and include Special Nuclear Material (SNM). Currently, only activities with transuranic SNM are anticipated. Preliminary discussions with facility personnel indicate that primarily two distributions of SNM will be used: Weapons Grade Plutonium (WG-Pu), and Pu-238 enhanced WG-Pu. Nominal radionuclide distributions for the two material types are included in attachment 1. Wastes generated inside glove boxes is expected to be Transuranic (TRU) Waste which will eventually be disposed of at the Waste Isolation Pilot Plant (WIPP). Wastes generated in the Radioactive Material Area (RMA), outside of the glove box is presumed to be low level waste (LLW) which is destined for disposal at the NTS. The process knowledge quantification methods identified herein may be applied to waste generated anywhere within or around the DAF and possibly JASPER as long as the fundamental waste stream boundaries are adhered to as outlined below. The method is suitable for quantification of waste which can be directly surveyed with the Blue Alpha meter or swiped. An additional quantification methodology which requires the use of a high resolution gamma spectroscopy unit is also included and relies on the predetermined radionuclide distribution and utilizes scaling to measured nuclides for quantification.

Dominick, J L

2001-12-18T23:59:59.000Z

Note: This page contains sample records for the topic "transuranic waste processing" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Process for treating waste water having low concentrations of metallic contaminants  

DOE Patents [OSTI]

A process for treating waste water having a low level of metallic contaminants by reducing the toxicity level of metallic contaminants to an acceptable level and subsequently discharging the treated waste water into the environment without removing the treated contaminants.

Looney, Brian B; Millings, Margaret R; Nichols, Ralph L; Payne, William L

2014-12-16T23:59:59.000Z

382

WRAP Module 1 sampling strategy and waste characterization alternatives study  

SciTech Connect (OSTI)

The Waste Receiving and Processing Module 1 Facility is designed to examine, process, certify, and ship drums and boxes of solid wastes that have a surface dose equivalent of less than 200 mrem/h. These wastes will include low-level and transuranic wastes that are retrievably stored in the 200 Area burial grounds and facilities in addition to newly generated wastes. Certification of retrievably stored wastes processing in WRAP 1 is required to meet the waste acceptance criteria for onsite treatment and disposal of low-level waste and mixed low-level waste and the Waste Isolation Pilot Plant Waste Acceptance Criteria for the disposal of TRU waste. In addition, these wastes will need to be certified for packaging in TRUPACT-II shipping containers. Characterization of the retrievably stored waste is needed to support the certification process. Characterization data will be obtained from historical records, process knowledge, nondestructive examination nondestructive assay, visual inspection of the waste, head-gas sampling, and analysis of samples taken from the waste containers. Sample characterization refers to the method or methods that are used to test waste samples for specific analytes. The focus of this study is the sample characterization needed to accurately identify the hazardous and radioactive constituents present in the retrieved wastes that will be processed in WRAP 1. In addition, some sampling and characterization will be required to support NDA calculations and to provide an over-check for the characterization of newly generated wastes. This study results in the baseline definition of WRAP 1 sampling and analysis requirements and identifies alternative methods to meet these requirements in an efficient and economical manner.

Bergeson, C.L.

1994-09-30T23:59:59.000Z

383

Method for co-processing waste rubber and carbonaceous material  

DOE Patents [OSTI]

In a process for the co-processing of waste rubber and carbonaceous material to form a useful liquid product, the rubber and the carbonaceous material are combined and heated to the depolymerization temperature of the rubber in the presence of a source of hydrogen. The depolymerized rubber acts as a liquefying solvent for the carbonaceous material while a beneficial catalytic effect is obtained from the carbon black released on depolymerization the reinforced rubber. The reaction is carried out at liquefaction conditions of 380.degree.-600.degree. C. and 70-280 atmospheres hydrogen pressure. The resulting liquid is separated from residual solids and further processed such as by distillation or solvent extraction to provide a carbonaceous liquid useful for fuels and other purposes.

Farcasiu, Malvina (Pittsburgh, PA); Smith, Charlene M. (Pittsburgh, PA)

1991-01-01T23:59:59.000Z

384

Co-processing of agriculture and biomass waste with coal  

SciTech Connect (OSTI)

Biomass and bio-processed waste are potential candidates for co-liquefaction with coal. Specific materials used here include sawdust and poultry manure. Liquefaction experiments were run on each of these materials, separately and with coal, using tetralin as solvent at 350{degrees}C and 1000 psi(cold) hydrogen pressure for 1h. Total conversion was monitored, as well as conversion to asphaltenes, oils and gases. All the biomass samples are converted to oils and gases under the reaction conditions. Poultry manure seems to convert coal more completely, and to produce more oils and gases, than conventional liquefaction.

Stiller, A.H.; Dadyburjor, D.B.; Wann, J.P. [West Virginia Univ., Morgantown, WV (United States)

1995-12-01T23:59:59.000Z

385

Tank Waste Remediation System tank waste pretreatment and vitrification process development testing requirements assessment  

SciTech Connect (OSTI)

A multi-faceted study was initiated in November 1993 to provide assurance that needed testing capabilities, facilities, and support infrastructure (sampling systems, casks, transportation systems, permits, etc.) would be available when needed for process and equipment development to support pretreatment and vitrification facility design and construction schedules. This first major report provides a snapshot of the known testing needs for pretreatment, low-level waste (LLW) and high-level waste (HLW) vitrification, and documents the results of a series of preliminary studies and workshops to define the issues needing resolution by cold or hot testing. Identified in this report are more than 140 Hanford Site tank waste pretreatment and LLW/HLW vitrification technology issues that can only be resolved by testing. The report also broadly characterizes the level of testing needed to resolve each issue. A second report will provide a strategy(ies) for ensuring timely test capability. Later reports will assess the capabilities of existing facilities to support needed testing and will recommend siting of the tests together with needed facility and infrastructure upgrades or additions.

Howden, G.F.

1994-10-24T23:59:59.000Z

386

Activated sludge process: Waste treatment. (Latest citations from the Biobusiness database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations concerning the use of the activated sludge process in waste and wastewater treatment. Topics include biochemistry of the activated sludge process, effects of various pollutants on process activity, effects of environmental variables such as oxygen and water levels, and nutrient requirements of microorganisms employed in activated sludge processes. The citations also explore use of the process to treat specific wastes, such as halocarbons, metallic wastes, and petrochemical effluents; and wastes from pharmaceutical and dairy processes. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1996-01-01T23:59:59.000Z

387

Greater-than-Class C Low-Level Radioactive Waste (GTCC LLW) ...  

Broader source: Energy.gov (indexed) [DOE]

Greater-than-Class C Low-Level Radioactive Waste (GTCC LLW) Greater-than-Class C Low-Level Radioactive Waste (GTCC LLW) A transuranic (TRU) waste shipment makes its way to the...

388

Implications of Fast Reactor Transuranic Conversion Ratio  

SciTech Connect (OSTI)

Theoretically, the transuranic conversion ratio (CR), i.e. the transuranic production divided by transuranic destruction, in a fast reactor can range from near zero to about 1.9, which is the average neutron yield from Pu239 minus 1. In practice, the possible range will be somewhat less. We have studied the implications of transuranic conversion ratio of 0.0 to 1.7 using the fresh and discharge fuel compositions calculated elsewhere. The corresponding fissile breeding ratio ranges from 0.2 to 1.6. The cases below CR=1 (“burners”) do not have blankets; the cases above CR=1 (“breeders”) have breeding blankets. The burnup was allowed to float while holding the maximum fluence to the cladding constant. We