Sample records for transparent conducting oxide

  1. Precise Application of Transparent Conductive Oxide Coatings...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide (TCO)...

  2. Transparent conducting oxides and production thereof

    SciTech Connect (OSTI)

    Gessert, Timothy A.; Yoshida, Yuki; Coutts, Timothy J.

    2014-06-10T23:59:59.000Z

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber. The method may also comprise depositing a metal oxide on the target in the process chamber to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  3. Transparent conducting oxides and production thereof

    SciTech Connect (OSTI)

    Gessert, Timothy A; Yoshida, Yuki; Coutts, Timothy J

    2014-05-27T23:59:59.000Z

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target (110) doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber (100). The method may also comprise depositing a metal oxide on the target (110) to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  4. High quality transparent conducting oxide thin films

    DOE Patents [OSTI]

    Gessert, Timothy A. (Conifer, CO); Duenow, Joel N. (Golden, CO); Barnes, Teresa (Evergreen, CO); Coutts, Timothy J. (Golden, CO)

    2012-08-28T23:59:59.000Z

    A transparent conducting oxide (TCO) film comprising: a TCO layer, and dopants selected from the elements consisting of Vanadium, Molybdenum, Tantalum, Niobium, Antimony, Titanium, Zirconium, and Hafnium, wherein the elements are n-type dopants; and wherein the transparent conducting oxide is characterized by an improved electron mobility of about 42 cm.sup.2/V-sec while simultaneously maintaining a high carrier density of .about.4.4e.times.10.sup.20 cm.sup.-3.

  5. Transparent conducting oxides: A -doped superlattice approach

    SciTech Connect (OSTI)

    Cooper, Valentino R [ORNL; Seo, Sung Seok A. [University of Kentucky, Lexington; Lee, Suyoun [ORNL; Kim, Jun Sung [Pohang University of Science and Technology (POSTECH), Pohang, Republic of Korea; Choi, Woo Seok [ORNL; Okamoto, Satoshi [ORNL; Lee, Ho Nyung [ORNL

    2014-01-01T23:59:59.000Z

    Two-dimensional electron gases (2DEGs) at the interface of oxide heterostructures have been the subject of recent experiment and theory, due to the intriguing phenomena that occur in confined electronic states. However, while much has been done to understand the origin of 2DEGs and related phenomena, very little has been explored with regards to the control of conduction pathways and the distribution of charge carriers. Using first principles simulations and experimental thin film synthesis methods, we examine the effect of dimensionality on carrier transport in La delta-doped SrTiO3 (STO) superlattices, as a function of the thickness of the insulating STO spacer. Our computed Fermi surfaces and layer-resolved carrier density proles demonstrate that there is a critical thickness of the STO spacer, below which carrier transport is dominated by three-dimensional conduction of interface charges arising from appreciable overlap of the quantum mechanical wavefunctions between neighboring delta-doped layers. We observe that, experimentally, these superlattices remain highly transparent to visible light. Band structure calculations indicate that this is a result of the appropriately large gap between the O 2p and Ti d states. The tunability of the quantum mechanical wavefunctions and the optical transparency highlight the potential for using oxide heterostructures in novel opto-electronic devices; thus providing a route to the creation of novel transparent conducting oxides.

  6. High carrier concentration p-type transparent conducting oxide films

    DOE Patents [OSTI]

    Yan, Yanfa; Zhang, Shengbai

    2005-06-21T23:59:59.000Z

    A p-type transparent conducting oxide film is provided which is consisting essentially of, the transparent conducting oxide and a molecular doping source, the oxide and doping source grown under conditions sufficient to deliver the doping source intact onto the oxide.

  7. DEGRADATION OF TRANSPARENT CONDUCTIVE OXIDES: MECHANISTIC INSIGHTS AND INTERFACIAL ENGINEERING

    E-Print Network [OSTI]

    Rollins, Andrew M.

    DEGRADATION OF TRANSPARENT CONDUCTIVE OXIDES: MECHANISTIC INSIGHTS AND INTERFACIAL ENGINEERING;Degradation of Transparent Conductive Oxides: Mechanistic insights and Interfacial engineering Case Western;Dedicated to the science and engineering of photovoltaics, in an effort to make a better world. #12;Table

  8. Synthesis of transparent conducting oxide coatings

    DOE Patents [OSTI]

    Elam, Jeffrey W.; Martinson, Alex B. F.; Pellin, Michael J.; Hupp, Joseph T.

    2010-05-04T23:59:59.000Z

    A method and system for preparing a light transmitting and electrically conductive oxide film. The method and system includes providing an atomic layer deposition system, providing a first precursor selected from the group of cyclopentadienyl indium, tetrakis (dimethylamino) tin and mixtures thereof, inputting to the deposition system the first precursor for reaction for a first selected time, providing a purge gas for a selected time, providing a second precursor comprised of an oxidizer, and optionally inputting a second precursor into the deposition system for reaction and alternating for a predetermined number of cycles each of the first precursor, the purge gas and the second precursor to produce the oxide film.

  9. Nanostructured Transparent Conducting Oxides via Blockcopolymer Patterning

    E-Print Network [OSTI]

    Kim, Joung Youn Ellie

    2014-05-27T23:59:59.000Z

    . This can lead to new device designs of organic light emitting diodes (OLEDS), fuel cells, displays and solar cells. Moreover, the ability to incorporate other various functional materials to form a hybrid with the nanostructured TCO allows possibilities... cell work and the XPS measurements as well as other scientific insights. I am grateful to Dr. K.K. Banger for the help with conductivity measurements as well as the collaborative work on the amorphous TCO. His insights on sol-gel chemistry as well...

  10. Transparent and Conductive Carbon Nanotube Multilayer Thin Films Suitable as an Indium Tin Oxide Replacement 

    E-Print Network [OSTI]

    Park, Yong Tae

    2012-07-16T23:59:59.000Z

    Transparent electrodes made from metal oxides suffer from poor flexibility and durability. Highly transparent and electrically conductive thin films based on carbon nanotubes (CNTs) were assembled as a potential indium tin oxide (ITO) replacement...

  11. Magnetic transparent conducting oxide film and method of making

    DOE Patents [OSTI]

    Windisch Jr., Charles F.; Exarhos, Gregory J.; Sharma, Shiv K.

    2004-07-13T23:59:59.000Z

    Cobalt-nickel oxide films of nominal 100 nm thickness, and resistivity as low as 0.06 .OMEGA..multidot.cm have been deposited by spin-casting from both aqueous and organic precursor solutions followed by annealing at 450.degree. C. in air. Films deposited on sapphire substrates exhibit a refractive index of about 1.7 and are relatively transparent in the wavelength region from 0.6 to 10.0 .mu.m. They are also magnetic. The electrical and spectroscopic properties of the oxides have been studied as a function of x=Co/(Co+Ni) ratio. An increase in film resistivity was found upon substitution of other cations (e.g., Zn.sup.2+, Al.sup.3+) for Ni in the spinel structure. However, some improvement in the mechanical properties of the films resulted. On the other hand, addition of small amounts of Li decreased the resistivity. A combination of XRD, XPS, UV/Vis and Raman spectroscopy indicated that NiCo.sub.2 O.sub.4 is the primary conducting component and that the conductivity reaches a maximum at this stoichiometry. When x<0.67, NiO forms leading to an increase in resistivity; when x>0.67, the oxide was all spinel but the increased Co content lowered the conductivity. The influence of cation charge state and site occupancy in the spinel structure markedly affects calculated electron band structures and contributes to a reduction of p-type conductivity, the formation of polarons, and the reduction in population of mobile charge carriers that tend to limit transmission in the infrared.

  12. Quantitative analyses of damp-heat-induced degradation in transparent conducting oxides

    E-Print Network [OSTI]

    Park, Byungwoo

    Quantitative analyses of damp-heat-induced degradation in transparent conducting oxides Jae Ik Kim online 9 January 2014 Keywords: Transparent conducting oxides Al-doped ZnO Damp-heat test Photovoltaics oxides is essential for actual applications in photovoltaic devices or displays requiring long

  13. Magnetic Transparent Conducting Oxide Film And Method Of Making

    DOE Patents [OSTI]

    Windisch, Jr., Charles F. (Richland, WA); Exarhos, Gregory J. (Richland, WA); Sharma, Shiv K. (Honolulu, HI)

    2006-03-14T23:59:59.000Z

    Cobalt-nickel oxide films of nominal 100 nm thickness, and resistivity as low as 0.06 O·cm have been deposited by spin-casting from both aqueous and organic precursor solutions followed by annealing at 450° C. in air. An increase in film resistivity was found upon substitution of other cations (e.g., Zn2+, Al3+) for Ni in the spinel structure. However, some improvement in the mechanical properties of the films resulted. On the other hand, addition of small amounts of Li decreased the resistivity. A combination of XRD, XPS, UV/Vis and Raman spectroscopy indicated that NiCo2O4 is the primary conducting component and that the conductivity reaches a maximum at this stoichiometry. When x<0.67, NiO forms leading to an increase in resistivity; when x>0.67, the oxide was all spinel but the increased Co content lowered the conductivity.

  14. Impact of degenerate n-doping on the optical absorption edge in transparent conducting cadmium oxide

    E-Print Network [OSTI]

    Schleife, André

    n-type or can be heavily doped. Transparent conductive cadmium oxide (CdO) thin films, for instance devices or modern solar cells, material performance is critically important. A combination of high in the conduction bands of CdO can increase the conductivity up to values desired for technological applications

  15. Amorphous semiconducting and conducting transparent metal oxide thin films and production thereof

    DOE Patents [OSTI]

    Perkins, John (Boulder, CO); Van Hest, Marinus Franciscus Antonius Maria (Lakewood, CO); Ginley, David (Evergreen, CO); Taylor, Matthew (Golden, CO); Neuman, George A. (Holland, MI); Luten, Henry A. (Holland, MI); Forgette, Jeffrey A. (Hudsonville, MI); Anderson, John S. (Holland, MI)

    2010-07-13T23:59:59.000Z

    Metal oxide thin films and production thereof are disclosed. An exemplary method of producing a metal oxide thin film may comprise introducing at least two metallic elements and oxygen into a process chamber to form a metal oxide. The method may also comprise depositing the metal oxide on a substrate in the process chamber. The method may also comprise simultaneously controlling a ratio of the at least two metallic elements and a stoichiometry of the oxygen during deposition. Exemplary amorphous metal oxide thin films produced according to the methods herein may exhibit highly transparent properties, highly conductive properties, and/or other opto-electronic properties.

  16. Synthesis of Oxidation-Resistant Cupronickel Nanowires for Transparent Conducting Nanowire Networks

    SciTech Connect (OSTI)

    Rathmall, Aaron [Duke University; Nguyen, Minh [Duke University; Wiley, Benjamin J [Duke University

    2012-01-01T23:59:59.000Z

    Nanowires of copper can be coated from liquids to create flexible, transparent conducting films that can potentially replace the dominant transparent conductor, indium tin oxide, in displays, solar cells, organic light-emitting diodes, and electrochromic windows. One issue with these nanowire films is that copper is prone to oxidation. It was hypothesized that the resistance to oxidation could be improved by coating copper nanowires with nickel. This work demonstrates a method for synthesizing copper nanowires with nickel shells as well as the properties of cupronickel nanowires in transparent conducting films. Time- and temperature-dependent sheet resistance measurements indicate that the sheet resistance of copper and silver nanowire films will double after 3 and 36 months at room temperature, respectively. In contrast, the sheet resistance of cupronickel nanowires containing 20 mol % nickel will double in about 400 years. Coating copper nanowires to a ratio of 2:1 Cu:Ni gave them a neutral gray color, making them more suitable for use in displays and electrochromic windows. These properties, and the fact that copper and nickel are 1000 times more abundant than indium or silver, make cupronickel nanowires a promising alternative for the sustainable, efficient production of transparent conductors.

  17. Damp-Heat Induced Degradation of Transparent Conducting Oxides for Thin Film Solar Cells (Presentation)

    SciTech Connect (OSTI)

    Pern, J.; Noufi, R.; Li, X.; DeHart, C.; To, B.

    2008-05-01T23:59:59.000Z

    The objectives are: (1) To achieve a high long-term performance reliability for the thin-film CIGS PV modules with more stable materials, device structure designs, and moisture-resistant encapsulation materials and schemes; (2) to evaluate the DH stability of various transparent conducting oxides (TCOs); (3) to identify the degradation mechanisms and quantify degradation rates; (4) to seek chemical and/or physical mitigation methods, and explore new materials. It's important to note that direct exposure to DH represents an extreme condition that a well-encapsulated thin film PV module may never experience.

  18. Electrical and Optical Properties of Transparent Conducting Homologous Compounds in the IndiumGalliumZinc Oxide System

    E-Print Network [OSTI]

    Poeppelmeier, Kenneth R.

    , smart windows, and solar cells. Tin-doped indium oxide (ITO) is the commercial TCO of choice. ITO thin TRANSPARENT conducting oxides (TCOs) are used in a wide variety of applications, such as flat-panel displays, and lower cost are desired for use in demanding ap- plications such as next-generation flat-panel displays

  19. Data Mining-Aided Crystal Engineering for the Design of Transparent Conducting Oxides: Preprint

    SciTech Connect (OSTI)

    Suh, C.; Kim, K.; Berry, J. J.; Lee, J.; Jones, W. B.

    2010-12-01T23:59:59.000Z

    The purpose of this paper is to accelerate the pace of material discovery processes by systematically visualizing the huge search space that conventionally needs to be explored. To this end, we demonstrate not only the use of empirical- or crystal chemistry-based physical intuition for decision-making, but also to utilize knowledge-based data mining methodologies in the context of finding p-type delafossite transparent conducting oxides (TCOs). We report on examples using high-dimensional visualizations such as radial visualization combined with machine learning algorithms such as k-nearest neighbor algorithm (k-NN) to better define and visualize the search space (i.e. structure maps) of functional materials design. The vital role of search space generated from these approaches is discussed in the context of crystal chemistry of delafossite crystal structure.

  20. Tuning the properties of complex transparent conducting oxides: Role of crystal symmetry, chemical composition, and carrier generation

    E-Print Network [OSTI]

    Medvedeva, Julia E.

    Tuning the properties of complex transparent conducting oxides: Role of crystal symmetry, chemical; revised manuscript received 24 February 2010; published 17 March 2010 The electronic properties of singleO3, , and -Ga2O3, rock salt and wurtzite ZnO, and layered InGaZnO4 reveals the role of the following

  1. On the possibility to grow zinc oxide-based transparent conducting oxide films by hot-wire chemical vapor deposition

    SciTech Connect (OSTI)

    Abrutis, Adulfas, E-mail: adulfas.abrutis@chf.vu.lt; Silimavicus, Laimis; Kubilius, Virgaudas; Murauskas, Tomas; Saltyte, Zita; Kuprenaite, Sabina; Plausinaitiene, Valentina [Faculty of Chemistry, Vilnius University, Naugarduko 24, LT-03225 Vilnius (Lithuania)

    2014-03-15T23:59:59.000Z

    Hot-wire chemical vapor deposition (HW-CVD) was applied to grow zinc oxide (ZnO)-based transparent conducting oxide (TCO) films. Indium (In)-doped ZnO films were deposited using a cold wall pulsed liquid injection CVD system with three nichrome wires installed at a distance of 2?cm from the substrate holder. The wires were heated by an AC current in the range of 0–10 A. Zn and In 2,2,6,6-tetramethyl-3,5-heptanedionates dissolved in 1,2-dimethoxyethane were used as precursors. The hot wires had a marked effect on the growth rates of ZnO, In-doped ZnO, and In{sub 2}O{sub 3} films; at a current of 6–10 A, growth rates were increased by a factor of ?10–20 compared with those of traditional CVD at the same substrate temperature (400?°C). In-doped ZnO films with thickness of ?150?nm deposited on sapphire-R grown at a wire current of 9?A exhibited a resistivity of ?2?×?10{sup ?3} ?cm and transparency of >90% in the visible spectral range. These initial results reveal the potential of HW-CVD for the growth of TCOs.

  2. Application of Developed APCVD Transparent Conducting Oxides and Undercoat Technologies for Economical OLED Lighting

    SciTech Connect (OSTI)

    Martin Bluhm; James Coffey; Roman Korotkov; Craig Polsz; Alexandre Salemi; Robert Smith; Ryan Smith; Jeff Stricker; Chen Xu; Jasmine Shirazi; George Papakonstantopulous; Steve Carson; Claudia Goldman; Soren Hartmann; Frank Jessen; Bianca Krogmann; Christoph Rickers; Manfred Ruske; Holger Schwab; Dietrich Bertram

    2011-01-02T23:59:59.000Z

    Economics is a key factor for application of organic light emitting diodes (OLED) in general lighting relative to OLED flat panel displays that can handle high cost materials such as indium tin oxide (ITO) or Indium zinc oxide (IZO) as the transparent conducting oxide (TCO) on display glass. However, for OLED lighting to penetrate into general illumination, economics and sustainable materials are critical. The issues with ITO have been documented at the DOE SSL R&D and Manufacturing workshops for the last 5 years and the issue is being exacerbated by export controls from China (one of the major sources of elemental indium). Therefore, ITO is not sustainable because of the fluctuating costs and the United States (US) dependency on other nations such as China. Numerous alternatives to ITO/IZO are being evaluated such as Ag nanoparticles/nanowires, carbon nanotubes, graphene, and other metal oxides. Of these other metal oxides, doped zinc oxide has attracted a lot of attention over the last 10 years. The volume of zinc mined is a factor of 80,000 greater than indium and the US has significant volumes of zinc mined domestically, resulting in the ability for the US to be self-sufficient for this element that can be used in optoelectronic applications. The costs of elemental zinc is over 2 orders of magnitude less than indium, reflecting the relative abundance and availability of the elements. Arkema Inc. and an international primary glass manufacturing company, which is located in the United States, have developed doped zinc oxide technology for solar control windows. The genesis of this DOE SSL project was to determine if doped zinc oxide technology can be taken from the commodity based window market and translate the technology to OLED lighting. Thus, Arkema Inc. sought out experts, Philips Lighting, Pacific Northwest National Laboratories (PNNL) and National Renewable Research Laboratories (NREL), in OLED devices and brought them into the project. This project had a clear focus on economics and the work plan focused both on doped ZnO process and OLED device structure that would be consistent with the new TCO. The team successfully made 6 inch OLEDs with a serial construction. More process development is required to optimize commercial OLED structures. Feasibility was demonstrated on two different light extraction technologies: 1/4 lambda refractive index matching and high-low-high band pass filter. Process development was also completed on the key precursors for the TCO, which are ready for pilot-plant scale-up. Subsequently, Arkema has developed a cost of ownership model that is consistent with DOE SSL R&D Manufacturing targets as outlined in the DOE SSL R&D Manufacturing 2010 report. The overall outcome of this project was the demonstration that doped zinc oxide can be used for OLED devices without a drop-off in performance while gaining the economic and sustainable benefits of a more readily available TCO. The broad impact of this project, is the facilitation of OLED lighting market penetration into general illumination, resulting in significant energy savings, decreased greenhouse emissions, with no environmental impact issues such as mercury found in Fluorescent technology. The primary objective of this project was to develop a commercially viable process for 'Substrates' (Substrate/ undercoat/ TCO topcoat) to be used in production of OLED devices (lamps/luminaries/modules). This project focused on using Arkema's recently developed doped ZnO technology for the Fenestration industry and applying the technology to the OLED lighting industry. The secondary objective was the use of undercoat technology to improve light extraction from the OLED device. In optical fields and window applications, technology has been developed to mitigate reflection losses by selecting appropriate thicknesses and refractive indices of coatings applied either below or above the functional layer of interest. This technology has been proven and implemented in the fenestration industry for more than 15 years. Successful completion of

  3. Application of Developed APCVD Transparent Conducting Oxides and Undercoat Technologies for Economical OLED Lighting

    SciTech Connect (OSTI)

    Gary Silverman; Bluhm, Martin; Coffey, James; Korotkov, Roman; Polsz, Craig; Salemi, Alexandre; Smith, Robert; Smith, Ryan; Stricker, Jeff; Xu,Chen; Shirazi, Jasmine; Papakonstantopulous, George; Carson, Steve Philips Lighting GmbH Goldman, Claudia; Hartmann, Sören; Jessen, Frank; ,; Krogmann, Bianca; Rickers, Christoph; Ruske, Manfred, Schwab, Holger; Bertram, Dietrich

    2011-01-02T23:59:59.000Z

    Economics is a key factor for application of organic light emitting diodes (OLED) in general lighting relative to OLED flat panel displays that can handle high cost materials such as indium tin oxide (ITO) or Indium zinc oxide (IZO) as the transparent conducting oxide (TCO) on display glass. However, for OLED lighting to penetrate into general illumination, economics and sustainable materials are critical. The issues with ITO have been documented at the DOE SSL R&D and Manufacturing workshops for the last 5 years and the issue is being exaserbated by export controls from China (one of the major sources of elemental indium). Therefore, ITO is not sustainable because of the fluctuating costs and the United States (US) dependency on other nations such as China. Numerous alternatives to ITO/IZO are being evaluated such as Ag nanoparticles/nanowires, carbon nanotubes, graphene, and other metal oxides. Of these other metal oxides, doped zinc oxide has attracted a lot of attention over the last 10 years. The volume of zinc mined is a factor of 80,000 greater than indium and the US has significant volumes of zinc mined domestically, resulting in the ability for the US to be self-sufficient for this element that can be used in optoelectonic applications. The costs of elemental zinc is over 2 orders of magnitude less than indium, reflecting the relative abundance and availablility of the elements. Arkema Inc. and an international primary glass manufacturing company, which is located in the United States, have developed doped zinc oxide technology for solar control windows. The genesis of this DOE SSL project was to determine if doped zinc oxide technology can be taken from the commodity based window market and translate the technology to OLED lighting. Thus, Arkema Inc. sought out experts, Philips Lighting, Pacific Northwest National Laboratories (PNNL) and National Renewable Research Laboratories (NREL), in OLED devices and brought them into the project. This project had a clear focus on economics and the work plan focused both on doped ZnO process and OLED device structure that would be consistent with the new TCO. The team successfully made 6 inch OLEDs with a serial construction. More process development is required to optimize commercial OLED structures. Feasibility was demonstrated on two different light extraction technologies: 1/4 lambda refractive index matching and high-low-high band pass filter. Process development was also completed on the key precursors for the TCO, which are ready for pilot-plant scale-up. Subsequently, Arkema has developed a cost of ownership model that is consistent with DOE SSL R&D Manufacturing targets as outlined in the DOE SSL R&D Manufacturing 2010 report. The overall outcome of this project was the demonstration that doped zinc oxide can be used for OLED devices without a drop-off in performance while gaining the economic and sustainable benefits of a more readily available TCO. The broad impact of this project, is the facilitation of OLED lighting market penetration into general illumination, resulting in significant energy savings, decreased greenhouse emissions, with no environmental impact issues such as mercury found in Fluorescent technology.

  4. Plasmonic transparent conducting metal oxide nanoparticles and films for optical sensing applications

    DOE Patents [OSTI]

    Ohodnicki, Jr., Paul R; Wang, Congjun; Andio, Mark A

    2014-01-28T23:59:59.000Z

    The disclosure relates to a method of detecting a change in a chemical composition by contacting a doped oxide material with a monitored stream, illuminating the doped oxide material with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The doped metal oxide has a carrier concentration of at least 10.sup.18/cm.sup.3, a bandgap of at least 2 eV, and an electronic conductivity of at least 10.sup.1 S/cm, where parameters are specified at a temperature of 25.degree. C. The optical response of the doped oxide materials results from the high carrier concentration of the doped metal oxide, and the resulting impact of changing gas atmospheres on that relatively high carrier concentration. These changes in effective carrier densities of conducting metal oxide nanoparticles are postulated to be responsible for the change in measured optical absorption associated with free carriers. Exemplary doped metal oxides include but are not limited to Al-doped ZnO, Sn-doped In.sub.2O.sub.3, Nb-doped TiO.sub.2, and F-doped SnO.sub.2.

  5. Properties of TiO{sub 2}-based transparent conducting oxide thin films on GaN(0001) surfaces

    SciTech Connect (OSTI)

    Kasai, J.; Nakao, S.; Yamada, N. [Kanagawa Academy of Science and Technology (KAST), Kawasaki 213-0012 (Japan); Hitosugi, T. [Kanagawa Academy of Science and Technology (KAST), Kawasaki 213-0012 (Japan); Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577 (Japan); Moriyama, M.; Goshonoo, K. [Toyoda Gosei Co., Ltd., Nishikasugai, Aichi 452-8564 (Japan); Hoang, N. L. H. [Department of Chemistry, University of Tokyo, Tokyo 113-0033 (Japan); Hasegawa, T. [Kanagawa Academy of Science and Technology (KAST), Kawasaki 213-0012 (Japan); Department of Chemistry, University of Tokyo, Tokyo 113-0033 (Japan)

    2010-03-15T23:59:59.000Z

    Anatase Nb-doped TiO{sub 2} transparent conducting oxide has been formed on GaN(0001) surfaces using a sputtering method. Amorphous films deposited at room temperature were annealed at a substrate temperature of 500 deg. C in vacuum to form single-phase anatase films. Films with a thickness of 170 nm exhibited a resistivity of 8x10{sup -4} {Omega} cm with absorptance less than 5% at a wavelength of 460 nm. Furthermore, the refractive index of the Nb-doped TiO{sub 2} was well matched to that of GaN. These findings indicate that Nb-doped TiO{sub 2} is a promising material for use as transparent electrodes in GaN-based light emitting diodes (LEDs), particularly since reflection at the electrode/GaN boundary can be suppressed, enhancing the external quantum efficiency of blue LEDs.

  6. Transparent and Conductive Carbon Nanotube Multilayer Thin Films Suitable as an Indium Tin Oxide Replacement

    E-Print Network [OSTI]

    Park, Yong Tae

    2012-07-16T23:59:59.000Z

    and light-emitting diodes). For these electronic devices, transporting electrons to and from the electrode layer is required. In many cases, this electrode must transmit visible light because it is applied directly onto the surface of a transparent...

  7. Transparent and conductive indium doped cadmium oxide thin films prepared by pulsed filtered cathodic arc deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Yuankun; Mendelsberg, Rueben J.; Zhu, Jiaqi; Han, Jiecai; Anders, Andre

    2013-01-01T23:59:59.000Z

    Indium doped cadmium oxide (CdO:In) films with different In concentrations were prepared on low-cost glass substrates by pulsed filtered cathodic arc deposition (PFCAD). It is shown that polycrystalline CdO:In films with smooth surface and dense structure are obtained. In-doping introduces extra electrons leading to remarkable improvements of electron mobility and conductivity, as well as improvement in the optical transmittance due to the Burstein Moss effect. CdO:In films on glass substrates with thickness near 230 nm show low resistivity of 7.23 10-5 cm, high electron mobility of 142 cm2/Vs, and mean transmittance over 80percent from 500-1250 nm (including the glass substrate).more »These high quality pulsed arc-grown CdO:In films are potentially suitable for high efficiency multi-junction solar cells that harvest a broad range of the solar spectrum.« less

  8. Transparent and conductive indium doped cadmium oxide thin films prepared by pulsed filtered cathodic arc deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Yuankun [Harbin Institute of Technology (China). Center for Composite Materials and Structures; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Plasma Applications Group; Mendelsberg, Rueben J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Plasma Applications Group and Molecular Foundry; Zhu, Jiaqi [Harbin Institute of Technology (China). Center for Composite Materials and Structures; Han, Jiecai [Harbin Institute of Technology (China). Center for Composite Materials and Structures; Anders, Andre [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Plasma Applications Group

    2013-01-01T23:59:59.000Z

    Indium doped cadmium oxide (CdO:In) films with different In concentrations were prepared on low-cost glass substrates by pulsed filtered cathodic arc deposition (PFCAD). It is shown that polycrystalline CdO:In films with smooth surface and dense structure are obtained. In-doping introduces extra electrons leading to remarkable improvements of electron mobility and conductivity, as well as improvement in the optical transmittance due to the Burstein Moss effect. CdO:In films on glass substrates with thickness near 230 nm show low resistivity of 7.23 10-5 cm, high electron mobility of 142 cm2/Vs, and mean transmittance over 80percent from 500-1250 nm (including the glass substrate). These high quality pulsed arc-grown CdO:In films are potentially suitable for high efficiency multi-junction solar cells that harvest a broad range of the solar spectrum.

  9. Why MnIn{sub 2}O{sub 4} spinel is not a transparent conducting oxide?

    SciTech Connect (OSTI)

    Martinez-Lope, M.J. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Retuerto, M. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Department of Chemistry, Rutgers State University of New Jersey, Piscataway, NJ 08854-8087 (United States); Calle, C. de la [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain); Porcher, Florence [Laboratoire Leon Brillouin, CEA/Saclay, 91191 Gif Sur Ivette Cedex, France. (France); Alonso, J.A., E-mail: ja.alonso@icmm.csic.es [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco E-28049 Madrid (Spain)

    2012-03-15T23:59:59.000Z

    The title compound has been synthesized by a citrate technique. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3-bar m, Z=8, with a=9.0008(1) A at 295 K. It exhibits a crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively, with a slight degree of inversion, {lambda}=0.08. MnIn{sub 2}O{sub 4} shows antiferromagnetic interactions below T{sub N} Almost-Equal-To 40 K, due to the statistical distribution of Mn ions over the two available sites. Unlike the related MgIn{sub 2}O{sub 4} and CdIn{sub 2}O{sub 4} spinels, well known as transparent conducting oxides, MnIn{sub 2}O{sub 4} is not transparent and shows a poor conductivity ({sigma}=0.38 S cm{sup -1} at 1123 K): the presence of Mn ions, able to adopt mixed valence states, localizes the charges that, otherwise, would be delocalized in the spinel conduction band. - Graphical Abstract: From NPD data the crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, shows a slight degree of inversion, {lambda}=0.08 and a certain In deficiency. The presence of Mn ions, able to adopt mixed oxidation states, localize the charges that, otherwise, would be delocalized in the spinel conduction band; the presence of localized Mn{sup 2+} and Mn{sup 3+} ions provides the characteristic brown color. Highlights: Black-Right-Pointing-Pointer Accurate structural determination from NPD data: inversion degree (8%), and In deficiency. Black-Right-Pointing-Pointer Bond-valence indicates Mn{sup 2+}-Mn{sup 3+} ions; edge-sharing octahedra contain 90% In{sup 3+}+10% Mn{sup 3+} cations. Black-Right-Pointing-Pointer Conductivity several orders of magnitude lower than those of MgIn{sub 2}O{sub 4} or CdIn{sub 2}O{sub 4}. Black-Right-Pointing-Pointer Variability of Mn oxidation states cancels any electron-doping effect, emptying conduction band of mobile charge carriers. Black-Right-Pointing-Pointer Curie-Weiss behavior confirming the determined charge distribution.

  10. Fabrication of Transparent-Conducting-Oxide-Coated Inverse Opals as Mesostructured Architectures for Electrocatalysis Applications: A

    E-Print Network [OSTI]

    -energy conversion.1-9 For example, high-surface-area silica-based aerogels can be used as scaffolds for constructing), display both good light-harvesting and good charge collection.5-7,10 Since SiO2 aerogels are insulating of making high-surface-area electrodes (e.g., aerogels) directly from conducting materials (e.g., fluorine

  11. Degradation of transparent conductive oxides; Mechanistic insights across configurations and exposures

    E-Print Network [OSTI]

    Rollins, Andrew M.

    . An encapsulated configuration study was conducted on ITO and AZO, exposing samples to the above accel- erated applications, durability concerns arise. The cost and reliability of solar power are often cited as a primary been reported in thin film silicon solar modules123 , CIGS modules456 and OPV technologies78910

  12. al transparent conducting: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Reduction of graphene oxide films on Al foil for hybrid transparent conductive film applications...

  13. Transparent conducting thin films for spacecraft applications

    SciTech Connect (OSTI)

    Perez-Davis, M.E.; Malave-Sanabria, T.; Hambourger, P.; Rutledge, S.K.; Roig, D.; Degroh, K.K.; Hung, C.

    1994-01-01T23:59:59.000Z

    Transparent conductive thin films are required for a variety of optoelectronic applications: automotive and aircraft windows, and solar cells for space applications. Transparent conductive coatings of indium-tin-oxide (ITO)-magnesium fluoride (MgF2) and aluminum doped zinc oxide (AZO) at several dopant levels are investigated for electrical resistivity (sheet resistance), carrier concentration, optical properties, and atomic oxygen durability. The sheet resistance values of ITO-MgF2 range from 10[sup 2] to 10[sup 11] ohms/square, with transmittance of 75 to 86 percent. The AZO films sheet resistances range from 10[sup 7] to 10[sup 11] ohms/square with transmittances from 84 to 91 percent. It was found that in general, with respect to the optical properties, the zinc oxide (ZnO), AZO, and the high MgF2 content ITO-MgF2 samples, were all durable to atomic oxygen plasma, while the low MgF2 content of ITO-MgF2 samples were not durable to atomic oxygen plasma exposure.

  14. Carbon Nanotube Assemblies for Transparent Conducting Electrodes

    SciTech Connect (OSTI)

    Garrett, Matthew P [ORNL] [ORNL; Gerhardt, Rosario [ORNL] [ORNL

    2012-01-01T23:59:59.000Z

    The goal of this chapter is to introduce readers to the fundamental and practical aspects of nanotube assemblies made into transparent conducting networks and discuss some practical aspects of their characterization. Transparent conducting coatings (TCC) are an essential part of electro-optical devices, from photovoltaics and light emitting devices to electromagnetic shielding and electrochromic widows. The market for organic materials (including nanomaterials and polymers) based TCCs is expected to show a growth rate of 56.9% to reach nearly 20.3billionin2015,whilethemarketfortraditionalinorganictransparentelectronicswillexperiencegrowthwithratesof6.7103 billion in 2015. Emerging flexible electronic applications have brought additional requirements of flexibility and low cost for TCC. However, the price of indium (the major component in indium tin oxide TCC) continues to increase. On the other hand, the price of nanomaterials has continued to decrease due to development of high volume, quality production processes. Additional benefits come from the low cost, nonvacuum deposition of nanomaterials based TCC, compared to traditional coatings requiring energy intensive vacuum deposition. Among the materials actively researched as alternative TCC are nanoparticles, nanowires, and nanotubes with high aspect ratio as well as their composites. The figure of merit (FOM) can be used to compare TCCs made from dissimilar materials and with different transmittance and conductivity values. In the first part of this manuscript, we will discuss the seven FOM parameters that have been proposed, including one specifically intended for flexible applications. The approach for how to measure TCE electrical properties, including frequency dependence, will also be discussed. We will relate the macroscale electrical characteristics of TCCs to the nanoscale parameters of conducting networks. The fundamental aspects of nanomaterial assemblies in conducting networks will also be addressed. We will review recent literature on TCCs composed of carbon nanotubes of different types in terms of the FOM.

  15. Optically transparent yttrium oxide

    SciTech Connect (OSTI)

    Hartnett, T.; Greenberg, M.; Gentilman, R.L.

    1988-08-02T23:59:59.000Z

    A body is described comprising at least 99.9% yttrium oxide having a density of at least 99% of theoretically density, a sample of the body having a in-line transmission of at least 73%, over a wavelength range of 2-5 microns with the sample having a thickness of 0.375 inches.

  16. Effect of thermal annealing on the properties of transparent conductive In–Ga–Zn oxide thin films

    SciTech Connect (OSTI)

    Li, Ling [Key Laboratory of Physical Electronics and Devices of the Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, China and School of Information Science and Engineering, Shandong University, Jinan 250100 (China); Fan, Lina; Li, Yanhuai; Song, Zhongxiao; Ma, Fei, E-mail: mafei@mail.xjtu.edu.cn, E-mail: chlliu@mail.xjtu.edu.cn [State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049 (China); Liu, Chunliang, E-mail: mafei@mail.xjtu.edu.cn, E-mail: chlliu@mail.xjtu.edu.cn [Key Laboratory of Physical Electronics and Devices of the Ministry of Education, Xi'an Jiaotong University, Xi'an 710049 (China)

    2014-03-15T23:59:59.000Z

    Amorphous In–Ga–Zn oxide (IGZO) thin films were prepared using radio frequency magnetron sputtering at room temperature. Upon thermal annealing at temperatures even up to 500?°C, the amorphous characteristics were still maintained, but the electronic properties could be considerably enhanced. This could be ascribed to the increased optical band gap and the increased oxygen vacancies, as corroborated by the microstructure characterizations. In addition, the surface became smoother upon thermal annealing, guaranteeing good interface contact between electrode and a-IGZO. The optical transmittance at 400–800?nm exceeded 90% for all samples. All in all, thermal annealing at appropriate temperatures is expected to improve the performances of relevant a-IGZO thin film transistors.

  17. Percolation in Transparent and Conducting Carbon Nanotube Networks

    E-Print Network [OSTI]

    Gruner, George

    and chemical sensors9 , field emission devices10,11 , and transparent conductive coatings7 . We12 , and another. Transmission measurements also indicate the usefulness of nanotube network films as a transparent, conductive coating. Avenues for improvement of the network transparency are discussed. KEYWORDS Nanotubes, Networks

  18. Misfit layered Ca{sub 3}Co{sub 4}O{sub 9} as a high figure of merit p-type transparent conducting oxide film through solution processing

    SciTech Connect (OSTI)

    Aksit, M.; Kolli, S. K.; Slauch, I. M.; Robinson, R. D., E-mail: rdr82@cornell.edu [Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States)

    2014-04-21T23:59:59.000Z

    Ca{sub 3}Co{sub 4}O{sub 9} thin films synthesized through solution processing are shown to be high-performing, p-type transparent conducting oxides (TCOs). The synthesis method is a cost-effective and scalable process that consists of sol-gel chemistry, spin coating, and heat treatments. The process parameters can be varied to produce TCO thin films with sheet resistance as low as 5.7?k?/sq (????57 m? cm) or with average visible range transparency as high as 67%. The most conductive Ca{sub 3}Co{sub 4}O{sub 9} TCO thin film has near infrared region optical transmission as high as 85%. The figure of merit (FOM) for the top-performing Ca{sub 3}Co{sub 4}O{sub 9} thin film (151 M?{sup ?1}) is higher than FOM values reported in the literature for all other solution processed, p-type TCO thin films and higher than most others prepared by physical vapor deposition and chemical vapor deposition. Transparent conductivity in misfit layered oxides presents new opportunities for TCO compositions.

  19. Enhanced Thermal Conductivity Oxide Fuels

    SciTech Connect (OSTI)

    Alvin Solomon; Shripad Revankar; J. Kevin McCoy

    2006-01-17T23:59:59.000Z

    the purpose of this project was to investigate the feasibility of increasing the thermal conductivity of oxide fuels by adding small fractions of a high conductivity solid phase.

  20. Thin transparent conducting films of cadmium stannate

    DOE Patents [OSTI]

    Wu, Xuanzhi (Golden, CO); Coutts, Timothy J. (Lakewood, CO)

    2001-01-01T23:59:59.000Z

    A process for preparing thin Cd.sub.2 SnO.sub.4 films. The process comprises the steps of RF sputter coating a Cd.sub.2 SnO.sub.4 layer onto a first substrate; coating a second substrate with a CdS layer; contacting the Cd.sub.2 SnO.sub.4 layer with the CdS layer in a water- and oxygen-free environment and heating the first and second substrates and the Cd.sub.2 SnO.sub.4 and CdS layers to a temperature sufficient to induce crystallization of the Cd.sub.2 SnO.sub.4 layer into a uniform single-phase spinel-type structure, for a time sufficient to allow full crystallization of the Cd.sub.2 SnO.sub.4 layer at that temperature; cooling the first and second substrates to room temperature; and separating the first and second substrates and layers from each other. The process can be conducted at temperatures less than 600.degree. C., allowing the use of inexpensive soda lime glass substrates.

  1. Journal of the Korean Physical Society, Vol. 50, No. 3, March 2007, pp. 622625 Al-ZnO Thin Films as Transparent Conductive Oxides : Synthesis,

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    , and low-tech applications, such as antistatic coatings, touch display panels, solar cells, flat panel exhibit n-type conduction. It is caused by a deviation from stoichiometry due to native defects-31-290-7075; Department of Chemistry, Sungkyunkwan University, Suwon 440- 746 on glass substrates at different target

  2. Transparent Conducting Oxide - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2, 2003Tool ofTopoCarbon|default SignofDSO

  3. Transparent conductive grids via direct writing of silver nanoparticle inks Bok Yeop Ahn,a

    E-Print Network [OSTI]

    Lewis, Jennifer

    . Using this approach, microscale features ($1 mm) in one-dimensional (1D) to three-dimensional (3D transparency and electrical conductivity.6 Recent efforts have focused on printing and other solution routes and co-workers have produced transparent conductive arrays by inkjet printing of dilute silver

  4. Graphene growth on glass 1 Synthesis of conducting transparent few-layer graphene directly

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Graphene growth on glass 1 Synthesis of conducting transparent few-layer graphene directly on glass major hurdles that research has to overcome to get graphene out of research laboratories. Here, using transparent graphene layers at temperatures as low as 450 °C. Our few-layer graphene grows at the interface

  5. Damage mechanisms in thin film solar cells during sputtering deposition of transparent conductive coatings

    SciTech Connect (OSTI)

    Fan Qihua; Liao Xianbo [Department of Physics and Astronomy, University of Toledo, 2801 West Bancroft Street, Toledo, Ohio 43606 (United States); Deng, Michael [Xunlight Corporation, 3145 Nebraska Avenue, Toledo, Ohio 43607 (United States); Deng Xunming [Department of Physics and Astronomy, University of Toledo, 2801 West Bancroft Street, Toledo, Ohio 43606 (United States); Xunlight Corporation, 3145 Nebraska Avenue, Toledo, Ohio 43607 (United States)

    2009-02-01T23:59:59.000Z

    Amorphous silicon (a-Si) based thin film solar cell grown on flexible stainless steel substrate is one of the most promising energy conversion devices in the future. This type of solar cell uses a transparent conductive oxide (TCO) film as top electrode. It has been a widely accepted opinion that the radio frequency sputtering deposition of the TCO film produces a higher yield than direct current sputtering, and the reason is not clear. Here we show that the damage to the solar cell during the sputtering process is caused by a reverse bias applied to the n-i-p junction. This reverse bias is related to the characteristics of plasma discharge. The mechanism we reveal may significantly affect the solar cell process.

  6. Investigation of nanostructured transparent conductive films grown by rotational-sequential-sputtering

    SciTech Connect (OSTI)

    Lu, Jong-Hong, E-mail: jonghonglu@mail.mcut.edu.tw; Chen, Bo-Ying; Wang, Chih-Hsuan [Department of Materials Engineering, Ming Chi University of Technology, 84 Gungjuan Rd., Taishan Dist. New Taipei City 24301, Taiwan and Center for Thin Film Technologies and Applications, Ming Chi University of Technology, 84 Gungjuan Rd., Taishan Dist. New Taipei City 24301, Taiwan (China)

    2014-03-15T23:59:59.000Z

    This study fabricates three types of nanostructured conductive transparent films using a rotational-sequential-sputtering method. These films include (1) TiO{sub 2}/indium-tin oxide (ITO) and SiO{sub x}/ITO nanomultilayer films, the optical refractive indices of which can be manipulated in the range of 2.42–1.63 at a wavelength of 550?nm with a controlled resistivity range of 1?×?10{sup ?3} to 2?×?10{sup ?4} ?·cm. (2) Multilayer ITO films are deposited on polyethylene terephthalate substrates, providing good flexibility and resistivity as low as 5?×?10{sup ?4} ?·cm. Finally, (3) ultrathin ITO films ranging from subnanometer to a few nanometers in thickness enable exploration of ITO film growth and thermal stability. X-ray reflection characterization provides a rapid, non-destructive method to measure the single-layer thicknesses of the nanomultilayer films and ultrathin ITO films at subnanoscale resolution.

  7. Infrared-optical spectroscopy of transparent conducting perovskite (La,Ba)SnO{sub 3} thin films

    SciTech Connect (OSTI)

    Seo, Dongmin; Yu, Kwangnam; Jun Chang, Young; Choi, E. J., E-mail: echoi@uos.ac.kr [Department of Physics, University of Seoul, Seoul 130-743 (Korea, Republic of); Sohn, Egon; Hoon Kim, Kee [Center for Novel States of Complex Materials Research, Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of)

    2014-01-13T23:59:59.000Z

    We have performed optical transmission, reflection, spectroscopic ellipsometry, and Hall effect measurements on the electron-doped La{sub x}Ba{sub 1–x}SnO{sub 3} (x?=?0.04) transparent thin films. From the infrared Drude response and plasma frequency analysis we determine the effective mass of the conducting electron m*?=?0.35m{sub 0}. In the visible-UV region the optical band gap shifts to high energy in (La,Ba)SnO{sub 3} by 0.18?eV compared with undoped BaSnO{sub 3} which, in the context of the Burstein-Moss analysis, is consistent with the infrared-m*. m* of BaSnO{sub 3} is compared with other existing transparent conducting oxides (TCO), and implication on search for high-mobility TCO compounds is discussed.

  8. Transparent Conducting ZnO Thin Films Doped with Al and Mo

    SciTech Connect (OSTI)

    Duenow, J.; Gessert, T.; Wood, D.; Young, D.; Coutts, T.

    2007-01-01T23:59:59.000Z

    Transparent conducting oxide (TCO) thin films are a vital part of photovoltaic cells, flat-panel displays, and electrochromic windows. ZnO-based TCOs, due to the relative abundance of Zn, may reduce production costs compared to those of the prevalent TCO In2O3:Sn (ITO). Undoped ZnO, ZnO:Al (0.5, 1, and 2 wt.% Al2O3), and ZnO:Mo (2 wt.%) films were deposited by RF magnetron sputtering. Controlled incorporation of H2 in the Ar sputtering ambient increased mobility of undoped ZnO by a factor of ~20 to 48 cm2V-1s-1. H2 also appears to catalyze ionization of dopants. This enabled lightly doped ZnO:Al to provide comparable conductivity to the standard 2 wt.%-doped ZnO:Al while demonstrating reduced infrared absorption. Mo was found to be an n-type dopant of ZnO, though material properties did not match those of ZnO:Al. Scattering mechanisms were investigated using temperature-dependent Hall measurements and the method of four coefficients. This abstract is subject to government rights.

  9. Integration of Laser-Welded Ag Nanowire Transparent Conducting Layers on Photovoltaic Devices (DMR-0819860)

    E-Print Network [OSTI]

    Petta, Jason

    Integration of Laser-Welded Ag Nanowire Transparent Conducting Layers on Photovoltaic Devices (DMR conducting layers in applications ranging from organic flexible electronics to rigid photovoltaics. However of a hybrid organic photovoltaic device [1]. The NWs are dispersed on the device and the network is welded

  10. Bulk Phase Relations, Conductivity, and Transparency in Novel Bixbyite Transparent Conducting Oxide Solution in the

    E-Print Network [OSTI]

    Poeppelmeier, Kenneth R.

    /cm, mobilities of 28.3 cm2 /(V s), and carrier densities of 1.2 1021 .1 As areas increase in solar cells and flat electrodes in numerous applications such as photovoltaics, flat panel displays, heat reflective coatings panel displays, the electrode resistivity must decrease to prevent increased I2 R losses associated

  11. Thin film electronic devices with conductive and transparent gas and moisture permeation barriers

    DOE Patents [OSTI]

    Simpson, Lin Jay

    2013-12-17T23:59:59.000Z

    A thin film stack (100, 200) is provided for use in electronic devices such as photovoltaic devices. The stack (100, 200) may be integrated with a substrate (110) such as a light transmitting/transmissive layer. A electrical conductor layer (120, 220) is formed on a surface of the substrate (110) or device layer such as a transparent conducting (TC) material layer (120,220) with pin holes or defects (224) caused by manufacturing. The stack (100) includes a thin film (130, 230) of metal that acts as a barrier for environmental contaminants (226, 228). The metal thin film (130,230) is deposited on the conductor layer (120, 220) and formed from a self-healing metal such as a metal that forms self-terminating oxides. A permeation plug or block (236) is formed in or adjacent to the thin film (130, 230) of metal at or proximate to the pin holes (224) to block further permeation of contaminants through the pin holes (224).

  12. p-Type transparent conducting oxides and methods for preparation

    DOE Patents [OSTI]

    Shahriari, Dean Y. (Evanston, IL); Barnabe, Antoine (Toulouse, FR); Mason, Thomas O. (Evanston, IL); Poeppelmeier, Kenneth R. (Evanston, IL)

    2011-05-31T23:59:59.000Z

    A facile, low temperature and low pressure method for the preparation of a wide range of phase pure ABO.sub.2 compositions.

  13. Controlling Surface Properties of Transparent Conducting Oxides | ANSER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisitingContract Management Fermi Site Office (FSO) FSO HomeContributedCenter |

  14. Precise Application of Transparent Conductive Oxide Coatings for Flat Panel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah ProjectPRE-AWARD ACCOUNTING SYSTEM SURVEY Applicant:InsideDisplays

  15. Hematite-based Photo-oxidation of Water Using Transparent Distributed Current Collectors

    E-Print Network [OSTI]

    Hematite-based Photo-oxidation of Water Using Transparent Distributed Current Collectors Shannon C. Martinson*,, Argonne-Northwestern Solar Energy Research (ANSER) Center and § Department of Chemistry collection of photocurrent from ultrathin coatings of hematite layers, enabling the formation of photoanodes

  16. Structural stability of transparent conducting films assembled from length purified single-wall carbon nanotubes

    SciTech Connect (OSTI)

    J. M. Harris; G. R. S. Iyer; D. O. Simien; J. A. Fagan; J. Y. Huh; J. Y. Chung; S. D. Hudson; J. Obrzut; J. F. Douglas; C. M. Stafford; E. K. Hobbie

    2011-01-01T23:59:59.000Z

    Single-wall carbon nanotube (SWCNT) films show significant promise for transparent electronics applications that demand mechanical flexibility, but durability remains an outstanding issue. In this work, thin membranes of length purified single-wall carbon nanotubes (SWCNTs) are uniaxially and isotropically compressed by depositing them on prestrained polymer substrates. Upon release of the strain, the topography, microstructure, and conductivity of the films are characterized using a combination of optical/fluorescence microscopy, light scattering, force microscopy, electron microscopy, and impedance spectroscopy. Above a critical surface mass density, films assembled from nanotubes of well-defined length exhibit a strongly nonlinear mechanical response. The measured strain dependence reveals a dramatic softening that occurs through an alignment of the SWCNTs normal to the direction of prestrain, which at small strains is also apparent as an anisotropic increase in sheet resistance along the same direction. At higher strains, the membrane conductivities increase due to a compression-induced restoration of conductive pathways. Our measurements reveal the fundamental mode of elasto-plastic deformation in these films and suggest how it might be suppressed.

  17. Zinc oxyfluoride transparent conductor

    DOE Patents [OSTI]

    Gordon, Roy G. (Cambridge, MA)

    1991-02-05T23:59:59.000Z

    Transparent, electrically conductive and infrared-reflective films of zinc oxyfluoride are produced by chemical vapor deposition from vapor mixtures of zinc, oxygen and fluorine-containing compounds. The substitution of fluorine for some of the oxygen in zinc oxide results in dramatic increases in the electrical conductivity. For example, diethyl zinc, ethyl alcohol and hexafluoropropene vapors are reacted over a glass surface at 400.degree. C. to form a visibly transparent, electrically conductive, infrared reflective and ultraviolet absorptive film of zinc oxyfluoride. Such films are useful in liquid crystal display devices, solar cells, electrochromic absorbers and reflectors, energy-conserving heat mirrors, and antistatic coatings.

  18. Hydrogen plasma treatment for improved conductivity in amorphous aluminum doped zinc tin oxide thin films

    SciTech Connect (OSTI)

    Morales-Masis, M., E-mail: monica.moralesmasis@epfl.ch; Ding, L.; Dauzou, F. [Photovoltaics and Thin-Film Electronics Laboratory (PVLab), Institute of Microengineering (IMT), Ecole Polytechnique Fédérale de Lausanne - EPFL, Rue de la Maladière 71b, CH-2002 Neuchatel (Switzerland); Jeangros, Q. [Interdisciplinary Centre for Electron Microscopy, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne (Switzerland); Hessler-Wyser, A. [Photovoltaics and Thin-Film Electronics Laboratory (PVLab), Institute of Microengineering (IMT), Ecole Polytechnique Fédérale de Lausanne - EPFL, Rue de la Maladière 71b, CH-2002 Neuchatel (Switzerland); Interdisciplinary Centre for Electron Microscopy, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne (Switzerland); Nicolay, S. [Centre Suisse d’Electronique et de Microtechnique (CSEM) SA, Rue Jaquet-Droz 1, CH-2002 Neuchatel (Switzerland); Ballif, C. [Photovoltaics and Thin-Film Electronics Laboratory (PVLab), Institute of Microengineering (IMT), Ecole Polytechnique Fédérale de Lausanne - EPFL, Rue de la Maladière 71b, CH-2002 Neuchatel (Switzerland); Centre Suisse d’Electronique et de Microtechnique (CSEM) SA, Rue Jaquet-Droz 1, CH-2002 Neuchatel (Switzerland)

    2014-09-01T23:59:59.000Z

    Improving the conductivity of earth-abundant transparent conductive oxides (TCOs) remains an important challenge that will facilitate the replacement of indium-based TCOs. Here, we show that a hydrogen (H{sub 2})-plasma post-deposition treatment improves the conductivity of amorphous aluminum-doped zinc tin oxide while retaining its low optical absorption. We found that the H{sub 2}-plasma treatment performed at a substrate temperature of 50?°C reduces the resistivity of the films by 57% and increases the absorptance by only 2%. Additionally, the low substrate temperature delays the known formation of tin particles with the plasma and it allows the application of the process to temperature-sensitive substrates.

  19. Barium Titanate and Bismuth Oxide Nanocomposites Barium titanate, BaTiO3, and bismuth oxide Bi2O3 are transparent materials with

    E-Print Network [OSTI]

    Harmon, Julie P.

    Barium Titanate and Bismuth Oxide Nanocomposites Barium titanate, BaTiO3, and bismuth oxide Bi2O3 that are lead-free. If we cannot shield effectively at nanofiller levels where transparency is maintained, we, Condensed Matter, Vol. 15, 8927 (2003). 21. "Highly Nonlinear Bismuth-Oxide Fiber for Smooth Supercontinuun

  20. Low temperature proton conducting oxide devices

    DOE Patents [OSTI]

    Armstrong, Timothy R. (Clinton, TN); Payzant, Edward A. (Oak Ridge, TN); Speakman, Scott A. (Oak Ridge, TN); Greenblatt, Martha (Highland Park, NJ)

    2008-08-19T23:59:59.000Z

    A device for conducting protons at a temperature below 550.degree. C. includes a LAMOX ceramic body characterized by an alpha crystalline structure.

  1. Co-sputtered Aluminum Doped Zinc Oxide Thin Film as Transparent Anode for Organic Light-emitting Diodes

    E-Print Network [OSTI]

    Co-sputtered Aluminum Doped Zinc Oxide Thin Film as Transparent Anode for Organic Light and Technology, Clear Water Bay, Kowloon, Hong Kong, China ABSTRACT Aluminum doped zinc oxide (AZO that MTDATA matches better with AZO than CuPc, which served as hole injection layer. Keywords: Aluminum doped

  2. RF Characteristics of Room-Temperature-Deposited, Small Gate Dimension Indium Zinc Oxide TFTs

    E-Print Network [OSTI]

    Pearton, Stephen J.

    .16 These transparent conducting oxides may also be used as electrodes in solar cells and flat-panel

  3. Mössbauer study of conductive oxide glass

    SciTech Connect (OSTI)

    Matsuda, Koken; Kubuki, Shiro [Tokyo Metropolitan University, Hachi-Oji, Tokyo 192-0397 (Japan); Nishida, Tetsuaki, E-mail: nishida@fuk.kindai.ac.jp [Kinki University, Iizuka, Fukuoka 820-8555 (Japan)

    2014-10-27T23:59:59.000Z

    Heat treatment of barium iron vanadate glass, BaO?Fe{sub 2}O{sub 3}?V{sub 2}O{sub 5}, at temperatures higher than crystallization temperature causes a marked decrease in resistivity (?) from several M?cm to several ?cm. {sup 57}Fe Mössbauer spectrum of heat-treated vanadate glass shows a marked decrease in quadrupole splitting (?) of Fe{sup III}, reflecting a structural relaxation, i.e., an increased symmetry of 'distorted' FeO{sub 4} and VO{sub 4} tetrahedra which are connected to each other by sharing corner oxygen atoms. Structural relaxation of 3D-network of vanadate glass accompanies a decrease in the activation energy for the conduction, reflecting a decreased energy gap between the donor level and conduction band. A marked increase in the conductivity was observed in CuO- or Cu{sub 2}O-containing barium iron vanadate glass after heat treatment at 450 °C for 30 min or more. 'n-type semiconductor model combined with small polaron hopping theory' was proposed in order to explain the high conductivity.

  4. Polymer geometry and Li+ conduction in poly(ethylene oxide)

    E-Print Network [OSTI]

    Averbuch, Amir

    Polymer geometry and Li+ conduction in poly(ethylene oxide) L. Gitelman a , M. Israeli b, , A: Lithium battery Polymer molecule Brownian motion Simulation Conductivity PEO a b s t r a c t We study of the amorphous PE structure is increased by mechanical stretching due to the unraveling of loops in the polymer

  5. See-through amorphous silicon solar cells with selectively transparent and conducting photonic crystal back reflectors for building integrated photovoltaics

    SciTech Connect (OSTI)

    Yang, Yang [The Edward S. Rogers Sr. Department of Electrical and Computer Engineering, University of Toronto, 10 King's College Road, Room GB254B, Toronto, Ontario M5S 3G4 (Canada)] [The Edward S. Rogers Sr. Department of Electrical and Computer Engineering, University of Toronto, 10 King's College Road, Room GB254B, Toronto, Ontario M5S 3G4 (Canada); O’Brien, Paul G. [Department of Materials Science and Engineering, University of Toronto, 184 College Street, Room 140, Toronto, Ontario M5S 3E4 (Canada) [Department of Materials Science and Engineering, University of Toronto, 184 College Street, Room 140, Toronto, Ontario M5S 3E4 (Canada); Materials Chemistry Research Group, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6 (Canada); Ozin, Geoffrey A., E-mail: gozin@chem.utoronto.ca, E-mail: kherani@ecf.utoronto.ca [Materials Chemistry Research Group, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6 (Canada); Kherani, Nazir P., E-mail: gozin@chem.utoronto.ca, E-mail: kherani@ecf.utoronto.ca [The Edward S. Rogers Sr. Department of Electrical and Computer Engineering, University of Toronto, 10 King's College Road, Room GB254B, Toronto, Ontario M5S 3G4 (Canada); Department of Materials Science and Engineering, University of Toronto, 184 College Street, Room 140, Toronto, Ontario M5S 3E4 (Canada)

    2013-11-25T23:59:59.000Z

    Thin semi-transparent hydrogenated amorphous silicon (a-Si:H) solar cells with selectively transparent and conducting photonic crystal (STCPC) back-reflectors are demonstrated. Short circuit current density of a 135?nm thick a-Si:H cell with a given STCPC back-reflector is enhanced by as much as 23% in comparison to a reference cell with an ITO film functioning as its rear contact. Concurrently, solar irradiance of 295?W/m{sup 2} and illuminance of 3480 lux are transmitted through the cell with a given STCPC back reflector under AM1.5 Global tilt illumination, indicating its utility as a source of space heating and lighting, respectively, in building integrated photovoltaic applications.

  6. Ag-Pd-Cu alloy inserted transparent indium tin oxide electrodes for organic solar cells

    SciTech Connect (OSTI)

    Kim, Hyo-Joong; Seo, Ki-Won; Kim, Han-Ki, E-mail: imdlhkkim@khu.ac.kr [Department of Advanced Materials Engineering for Information and Electronics, Kyung-Hee University, 1 Seocheon-dong, Yongin-si, Gyeonggi-do 446-701 (Korea, Republic of); Noh, Yong-Jin; Na, Seok-In [Graduate School of Flexible and Printable Electronics, Chonbuk National University, 664-14, Deokjin-dong, Jeonju-si, Jeollabuk-do 561-756 (Korea, Republic of)

    2014-09-01T23:59:59.000Z

    The authors report on the characteristics of Ag-Pd-Cu (APC) alloy-inserted indium tin oxide (ITO) films sputtered on a glass substrate at room temperature for application as transparent anodes in organic solar cells (OSCs). The effect of the APC interlayer thickness on the electrical, optical, structural, and morphological properties of the ITO/APC/ITO multilayer were investigated and compared to those of ITO/Ag/ITO multilayer electrodes. At the optimized APC thickness of 8?nm, the ITO/APC/ITO multilayer exhibited a resistivity of 8.55?×?10{sup ?5} ? cm, an optical transmittance of 82.63%, and a figure-of-merit value of 13.54?×?10{sup ?3} ?{sup ?1}, comparable to those of the ITO/Ag/ITO multilayer. Unlike the ITO/Ag/ITO multilayer, agglomeration of the metal interlayer was effectively relieved with APC interlayer due to existence of Pd and Cu elements in the thin region of the APC interlayer. The OSCs fabricated on the ITO/APC/ITO multilayer showed higher power conversion efficiency than that of OSCs prepared on the ITO/Ag/ITO multilayer below 10?nm due to the flatness of the APC layer. The improved performance of the OSCs with ITO/APC/ITO multilayer electrodes indicates that the APC alloy interlayer prevents the agglomeration of the Ag-based metal interlayer and can decrease the thickness of the metal interlayer in the oxide-metal-oxide multilayer of high-performance OSCs.

  7. Fluorine compounds for doping conductive oxide thin films

    DOE Patents [OSTI]

    Gessert, Tim; Li, Xiaonan; Barnes, Teresa M; Torres, Jr., Robert; Wyse, Carrie L

    2013-04-23T23:59:59.000Z

    Methods of forming a conductive fluorine-doped metal oxide layer on a substrate by chemical vapor deposition are described. The methods may include heating the substrate in a processing chamber, and introducing a metal-containing precursor and a fluorine-containing precursor to the processing chamber. The methods may also include adding an oxygen-containing precursor to the processing chamber. The precursors are reacted to deposit the fluorine-doped metal oxide layer on the substrate. Methods may also include forming the conductive fluorine-doped metal oxide layer by plasma-assisted chemical vapor deposition. These methods may include providing the substrate in a processing chamber, and introducing a metal-containing precursor, and a fluorine-containing precursor to the processing chamber. A plasma may be formed that includes species from the metal-containing precursor and the fluorine-containing precursor. The species may react to deposit the fluorine-doped metal oxide layer on the substrate.

  8. Tungsten oxide-Prussian blue electrochromic system based on a proton-conducting polymer electrolyte

    SciTech Connect (OSTI)

    Ho, K.C.; Rukavina, T.G.; Greenberg, C.B. (PPG Industries, Inc., Pittsburgh, PA (United States). Glass Technology Center)

    1994-08-01T23:59:59.000Z

    A new solid-state electrochromic system is presented. It is transparent and is comprised of a tungsten oxide and Prussian blue (PB) thin film couple in combination with a proton-conducting, solid polymer electrolyte. This electrochromic system exhibits rapid and deep optical switching; characteristics of a complementary configuration, both electrochromic films color and bleach in phase. Complementary electrochromic cells with the tungsten oxide-PB couple have previously been based on Li[sup +] or K[sup +]-conducting electrolytes. A repetitively cycling cell has not previously been reported with a proton-conducting solid polymer electrolyte. The devices were operated at low applied voltages, +1.2 V to darken and [minus]0.6 V to bleach. Repeated reduction and oxidation of the current system over 20,000 cycles has been demonstrated, indicating a large number of switchings without great degradation or irreversible side reactions. The sustained, high overall coloration efficiency of the devices suggests the insertion/extraction of protons into and out of both WO[sub 3] and PB films. The effects of cell size and operating temperature on the switching response are discussed.

  9. Improved Electrical Conductivity of Graphene Films Integrated with Metal Nanowires

    E-Print Network [OSTI]

    tin oxide films in electrochromic (EC) devices. The successful integration of such graphene/NW films. KEYWORDS: Graphene, nanowires, transparent conductive films, electrochromic devices Due to low electron

  10. Electronically conductive ceramics for high temperature oxidizing environments

    DOE Patents [OSTI]

    Kucera, G.H.; Smith, J.L.; Sim, J.W.

    1983-11-10T23:59:59.000Z

    This invention pertains to a high temperature, ceramic composition having electronic conductivity as measured by resistivity below about 500 ohm-cm, chemical stability particularly with respect to cathode conditions in a molten carbonate fuel cell, and composed of an alkali metal, transition metal oxide containing a dopant metal in the crystalline structure to replace a portion of the alkali metal or transition metal.

  11. Transparent Conducting Electrodes based on 1D and 2D Ag Nanogratings for Organic Photovoltaics

    E-Print Network [OSTI]

    Zeng, Beibei; Bartoli, Filbert J

    2014-01-01T23:59:59.000Z

    The optical and electrical properties of optically-thin one-dimensional (1D) Ag nanogratings and two-dimensional (2D) Ag nanogrids are studied, and their use as transparent electrodes in organic photovoltaics are explored. A large broadband and polarization-insensitive optical absorption enhancement in the organic light-harvesting layers is theoretically and numerically demonstrated using either single-layer 2D Ag nanogrids or two perpendicular 1D Ag nanogratings, and is attributed to the excitation of surface plasmon resonances and plasmonic cavity modes. Total photon absorption enhancements of 150% and 200% are achieved for the optimized single-layer 2D Ag nanogrids and double (top and bottom) perpendicular 1D Ag nanogratings, respectively.

  12. Joining Mixed Conducting Oxides Using an Air-Fired Electrically Conductive Braze

    SciTech Connect (OSTI)

    Hardy, John S.; Kim, Jin Yong Y.; Weil, K. Scott

    2004-10-01T23:59:59.000Z

    Due to their mixed oxygen ion and electron conducting properties, ceramics such as lanthanum strontium cobalt ferrites (LSCF) are attractive materials for use in active electrochemical devices such as solid oxide fuel cells (SOFC) and oxygen separation membranes. However, to take full advantage of the unique properties of these materials, reliable joining techniques need to be developed. If such a joining technique yields a ceramic-to-metal junction that is also electrically conductive, the hermetic seals in the device could provide the added function of either drawing current from the mixed conducting oxide, in the case of SOFC applications, or carrying it to the oxide to initate ionic conduction, in the case of oxygen separation and electrocatalysis applications. This would greatly reduce the need for complex interconnect design, thereby simplifying one of the major challenges faced in SOFC development. A process referred to as reactive air brazing (RAB) has been developed in which firing a Ag-CuO filler material in air creates a functional ceramic-to-metal junction, in which the silver-based matrix of the braze affords both metallic ductility and conductivity in the joint. Investigating a range of Ag-CuO alloy combinations determined that compositions containing between 1.4 and 16 mol% CuO appear to offer the best combination of wettability, joint strength, and electrical conductivity.

  13. Investigation of Some Transparent Metal Oxides as Damp Heat Protective Coating for CIGS Solar Cells: Preprint

    SciTech Connect (OSTI)

    Pern, F. J.; Yan, F.; Zaaunbrecher, B.; To, B.; Perkins, J.; Noufi, R.

    2012-10-01T23:59:59.000Z

    We investigated the protective effectiveness of some transparent metal oxides (TMO) on CIGS solar cell coupons against damp heat (DH) exposure at 85oC and 85% relative humidity (RH). Sputter-deposited bilayer ZnO (BZO) with up to 0.5-um Al-doped ZnO (AZO) layer and 0.2-um bilayer InZnO were used as 'inherent' part of device structure on CdS/CIGS/Mo/SLG. Sputter-deposited 0.2-um ZnSnO and atomic layer deposited (ALD) 0.1-um Al2O3 were used as overcoat on typical BZO/CdS/CIGS/Mo/SLG solar cells. The results were all negative -- all TMO-coated CIGS cells exhibited substantial degradation in DH. Combining the optical photographs, PL and EL imaging, SEM surface micro-morphology, coupled with XRD, I-V and QE measurements, the causes of the device degradations are attributed to hydrolytic corrosion, flaking, micro-cracking, and delamination induced by the DH moisture. Mechanical stress and decrease in crystallinity (grain size effect) could be additional degrading factors for thicker AZO grown on CdS/CIGS.

  14. Solution-Processable Transparent Conductive Hole Injection Electrode for OLED SSL

    SciTech Connect (OSTI)

    None

    2012-07-15T23:59:59.000Z

    An interconnected network of silver nanowires has been used as transparent anode in OLED devices. This layer was deposited by spin-coating and slot-die coating from an aqueous nanowire suspension. The sheet resistance of the film was 10ohms/sq with a transmission (including the glass substrate) of higher than 85%. The first phase of the project focused on the implementation of this nanowire layer with a hole-injection-layer (HIL) which has been developed at Plextronics and has been shown to provide good stability and efficiency in conventional OLED devices. We modified the HIL solution such that it coated reasonably well with suitable surface morphology so that actual devices can be manufactured. During the second phase we investigated the hole-injection and stability of hole-onlydevices. We determined that the use of the nanowire network as anode does not introduce an additional degradation mechanism since the observed device characteristics did not differ from those made with ITO anode. We then proceeded to make actual OLED devices with this nanowire / HIL stack and achieved device characteristics similar state-of-the-art OLED devices with a single junction. In order to gain traction with potential OLED manufacturers, we decided to contract Novaled to prepare large-area demonstrators for us. For these devices, we used an allevaporated stack, i.e. we did use Novaledâ??s HIL material instead of Plextronicsâ??. We successfully fabricated demonstrators with an area of 25cm2 with a double or triple junction stack. Minor stack optimizations were necessary to achieve efficacies and lifetime equivalent with ITO devices made with the same devices stack. Due to the reduced microcavity effect, the color of the emitted light is significantly more stable with respect to the viewing angle compared to ITO devices. This fact in conjunction with the promise of lower production cost due to the elimination of the ITO sputtering process and the direct patterning of the anode layer are the obvious advantages of this technology. The project has shown that this nanowire technology is a viable option to achieve OLED devices with good lifetime and efficiency and we are currently working with manufacturers to utilize this technology in a production setting.

  15. Photovoltaic devices comprising cadmium stannate transparent conducting films and method for making

    DOE Patents [OSTI]

    Wu, X.; Coutts, T.J.; Sheldon, P.; Rose, D.H.

    1999-07-13T23:59:59.000Z

    A photovoltaic device is disclosed having a substrate, a layer of Cd[sub 2]SnO[sub 4] disposed on said substrate as a front contact, a thin film comprising two or more layers of semiconductor materials disposed on said layer of Cd[sub 2]SnO[sub 4], and an electrically conductive film disposed on said thin film of semiconductor materials to form a rear electrical contact to said thin film. The device is formed by RF sputter coating a Cd[sub 2]SnO[sub 4] layer onto a substrate, depositing a thin film of semiconductor materials onto the layer of Cd[sub 2]SnO[sub 4], and depositing an electrically conductive film onto the thin film of semiconductor materials. 10 figs.

  16. Photovoltaic devices comprising cadmium stannate transparent conducting films and method for making

    DOE Patents [OSTI]

    Wu, Xuanzhi (Golden, CO); Coutts, Timothy J. (Lakewood, CO); Sheldon, Peter (Lakewood, CO); Rose, Douglas H. (Golden, CO)

    1999-01-01T23:59:59.000Z

    A photovoltaic device having a substrate, a layer of Cd.sub.2 SnO.sub.4 disposed on said substrate as a front contact, a thin film comprising two or more layers of semiconductor materials disposed on said layer of Cd.sub.2 SnO.sub.4, and an electrically conductive film disposed on said thin film of semiconductor materials to form a rear electrical contact to said thin film. The device is formed by RF sputter coating a Cd.sub.2 SnO.sub.4 layer onto a substrate, depositing a thin film of semiconductor materials onto the layer of Cd.sub.2 SnO.sub.4, and depositing an electrically conductive film onto the thin film of semiconductor materials.

  17. Time-resolved electron thermal conduction by probing of plasma formation in transparent solids with high power subpicosecond laser pulses

    SciTech Connect (OSTI)

    Vu, B.T.V.

    1994-02-01T23:59:59.000Z

    This dissertation work includes a series of experimental measurements in a search for better understanding of high temperature (10{sup 4}-10{sup 6}K) and high density plasmas (10{sup 22}-10{sup 24}cm{sup {minus}3}) produced by irradiating a transparent solid target with high intensity (10{sup 13} - 10{sup 15}W/cm{sup 2}) and subpicosecond (10{sup {minus}12}-10{sup {minus}13}s) laser pulses. Experimentally, pump and probe schemes with both frontside (vacuum-plasma side) and backside (plasma-bulk material side) probes are used to excite and interrogate or probe the plasma evolution, thereby providing useful insights into the plasma formation mechanisms. A series of different experiments has been carried out so as to characterize plasma parameters and the importance of various nonlinear processes. Experimental evidence shows that electron thermal conduction is supersonic in a time scale of the first picosecond after laser irradiation, so fast that it was often left unresolved in the past. The experimental results from frontside probing demonstrate that upon irradiation with a strong (pump) laser pulse, a thin high temperature ({approximately}40eV) super-critical density ({approximately}10{sup 23}/cm{sup 3}) plasma layer is quickly formed at the target surface which in turn becomes strongly reflective and prevents further transmission of the remainder of the laser pulse. In the bulk region behind the surface, it is also found that a large sub-critical ({approximately}10{sup 18}/cm{sup 3}) plasma is produced by inverse Bremsstrahlung absorption and collisional ionization. The bulk underdense plasma is evidenced by large absorption of the backside probe light. A simple and analytical model, modified from the avalanche model, for plasma evolution in transparent materials is proposed to explain the experimental results. Elimination of the bulk plasma is then experimentally illustrated by using targets overcoated with highly absorptive films.

  18. Structural and electrochemical characterization of two proton conducting oxide thin films for a microfabricated solid oxide fuel cell

    E-Print Network [OSTI]

    Capozzoli, Peter M

    2006-01-01T23:59:59.000Z

    The use of proton conducting oxide materials as an electrolyte offers the potential to reduce the operating temperature of a solid oxide fuel cell (SOFC), leading to improved thermal management and material compatibility. ...

  19. High surface area, electrically conductive nanocarbon-supported metal oxide

    DOE Patents [OSTI]

    Worsley, Marcus A; Han, Thomas Yong-Jin; Kuntz, Joshua D; Cervanted, Octavio; Gash, Alexander E; Baumann, Theodore F; Satcher, Jr., Joe H

    2014-03-04T23:59:59.000Z

    A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.

  20. Highly transparent Nb-doped indium oxide electrodes for organic solar cells

    SciTech Connect (OSTI)

    Kim, Jun Ho; Seong, Tae-Yeon [Department of Materials Science and Engineering, Korea University, Seoul 136-713 (Korea, Republic of); Na, Seok-In [Professional Graduate School of Flexible and Printable Electronics, Chonbuk National University, 664-14, Deokjin-dong, Jeongju-si, Jellabuk-do 561-756 (Korea, Republic of); Chung, Kwun-Bum [Department of Physics, Dankook University, Mt. 29, Anseo-Dong, Chenan 330-714 (Korea, Republic of); Lee, Hye-Min; Kim, Han-Ki, E-mail: imdlhkkim@khu.ac.kr [Department of Advanced Materials Engineering for Information and Electronics, Kyung Hee University, 1 Seocheon-dong, Yongin, Gyeonggi-do 446-701 (Korea, Republic of)

    2014-03-15T23:59:59.000Z

    The authors investigated the characteristics of Nb-doped In{sub 2}O{sub 3} (INbO) films prepared by co-sputtering of Nb{sub 2}O{sub 5} and In{sub 2}O{sub 3} for use in transparent anodes for organic solar cells (OSCs). To optimize the Nb dopant composition in the In{sub 2}O{sub 3} matrix, the effect of the Nb doping power on the resistivity and transparency of the INbO films were examined. The electronic structure and microstructure of the INbO films were also investigated using synchrotron x-ray absorption spectroscopy and x-ray diffraction examinations in detail. At the optimized Nb co-sputtering power of 30?W, the INbO film exhibited a sheet resistance of 15??/sq, and an optical transmittance of 86.04% at 550?nm, which are highly acceptable for the use as transparent electrodes in the fabrication of OSCs. More importantly, the comparable power conversion efficiency (3.34%) of the OSC with an INbO anode with that (3.31%) of an OSC with a commercial ITO anode indicates that INbO films are promising as a transparent electrode for high performance OSCs.

  1. Thin Film Solar Cells with Light Trapping Transparent Conducting Oxide Layer

    E-Print Network [OSTI]

    Lu, Tianlin

    2012-07-16T23:59:59.000Z

    Thin film solar cells, if film thickness is thinner than the optical absorption length, typically give lower cell performance. For the thinner structure, electric current loss due to light penetration can offset the electric current gain obtained...

  2. Thin Film Solar Cells with Light Trapping Transparent Conducting Oxide Layer 

    E-Print Network [OSTI]

    Lu, Tianlin

    2012-07-16T23:59:59.000Z

    Thin film solar cells, if film thickness is thinner than the optical absorption length, typically give lower cell performance. For the thinner structure, electric current loss due to light penetration can offset the electric current gain obtained...

  3. Stability Issues of Transparent Conducting Oxides (TCOs) for Thin-Film Photovoltaics (Presentation)

    SciTech Connect (OSTI)

    Pern, J.

    2008-12-01T23:59:59.000Z

    Study of stability issues of TCOs for thin-film PV, including degradation of optical, electrical, and structural properties of TCOs in damp heat and required encapsulation to prevent moisture egress.

  4. Damp-Heat Induced Degradation of Transparent Conducting Oxides for Thin-Film Solar Cells: Preprint

    SciTech Connect (OSTI)

    Pern, F. J.; Noufi, R.; Li, X.; DeHart, C.; To, B.

    2008-05-01T23:59:59.000Z

    The stability of intrinsic and Al-doped single- and bi-layer ZnO for thin-film CuInGaSe2 solar cells, along with Al-doped Zn1-xMgxO alloy and Sn-doped In2O3 (ITO) and F-doped SnO2, was evaluated by direct exposure to damp heat (DH) at 85oC and 85% relative humidity. The results show that the DH-induced degradation rates followed the order of Al-doped ZnO and Zn1-xMgxO >> ITO > F:SnO2. The degradation rates of Al:ZnO were slower for films of higher thickness, higher substrate temperature in sputter-deposition, and with dry-out intervals. As inferred from the optical micro-imaging showing the initiation and propagation of degrading patterns and regions, the degradation behavior appears similar for all TCOs, despite the obvious difference in the degradation rate. A degradation mechanism is proposed to explain the temporal process involving thermal hydrolysis.

  5. KAg11(VO4)4 as a Candidate p-Type Transparent Conducting Oxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home as Ready for(SC)JointJournaland theory unveil a new

  6. Electronically conducting metal oxide nanoparticles and films for optical sensing applications

    SciTech Connect (OSTI)

    Ohodnicki, Jr., Paul R.; Wang, Congjun; Andio, Mark A

    2014-09-16T23:59:59.000Z

    The disclosure relates to a method of detecting a change in a chemical composition by contacting a conducting oxide material with a monitored stream, illuminating the conducting oxide material with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The conducting metal oxide has a carrier concentration of at least 10.sup.17/cm.sup.3, a bandgap of at least 2 eV, and an electronic conductivity of at least 10.sup.-1 S/cm, where parameters are specified at the gas stream temperature. The optical response of the conducting oxide materials is proposed to result from the high carrier concentration and electronic conductivity of the conducting metal oxide, and the resulting impact of changing gas atmospheres on that relatively high carrier concentration and electronic conductivity. These changes in effective carrier densities and electronic conductivity of conducting metal oxide films and nanoparticles are postulated to be responsible for the change in measured optical absorption associated with free carriers. Exemplary conducting metal oxides include but are not limited to Al-doped ZnO, Sn-doped In.sub.2O.sub.3, Nb-doped TiO.sub.2, and F-doped SnO.sub.2.

  7. Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Yang, Bin (Columbus, OH); Perry, Steven T. (Galloway, OH); Mazanec, Terry (Solon, OH); Arora, Ravi (New Albany, OH); Daly, Francis P. (Delaware, OH); Long, Richard (New Albany, OH); Yuschak, Thomas D. (Lewis Center, OH); Neagle, Paul W. (Westerville, OH); Glass, Amanda (Galloway, OH)

    2011-08-16T23:59:59.000Z

    Methods of oxidative dehydrogenation are described. Surprisingly, Pd and Au alloys of Pt have been discovered to be superior for oxidative dehydrogenation in microchannels. Methods of forming these catalysts via an electroless plating methodology are also described. An apparatus design that minimizes heat transfer to the apparatus' exterior is also described.

  8. Tunable Electrical Conductivity of Individual Graphene Oxide Sheets

    E-Print Network [OSTI]

    implementation is its mass production, and the chemical exfoliation of graphite through oxidation. Alternative approaches to large-scale production of graphene, such as the thermal exfoliation of graphite oxide3 and the liquid-phase exfoliation of graphite4 and expandable graphite5 powders, are also studied

  9. Catoptric electrodes: transparent metal electrodes using shaped surfaces

    E-Print Network [OSTI]

    Kik, Pieter

    -conductivity top contacts. © 2014 Optical Society of America OCIS codes: (310.7005) Transparent conductive coatings

  10. Light transmissive electrically conductive oxide electrode formed in the presence of a stabilizing gas

    DOE Patents [OSTI]

    Tran, Nang T. (Cottage Grove, MN); Gilbert, James R. (Maplewood, MN)

    1992-08-04T23:59:59.000Z

    A light transmissive, electrically conductive oxide is doped with a stabilizing gas such as H.sub.2 and H.sub.2 O. The oxide is formed by sputtering a light transmissive, electrically conductive oxide precursor onto a substrate at a temperature from 20.degree. C. to 300.degree. C. Sputtering occurs in a gaseous mixture including a sputtering gas and the stabilizing gas.

  11. A High Conducting Oxide Sulfide Composite Lithium Superionic Conductor

    SciTech Connect (OSTI)

    Rangasamy, Ezhiylmurugan [ORNL] [ORNL; Keum, Jong Kahk [ORNL] [ORNL; Sahu, Gayatri [ORNL] [ORNL; Rondinone, Adam Justin [ORNL; Dudney, Nancy J [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    A hybrid superionic conductor was fabricated utilizing the space charge effect between the LLZO and LPS interfaces. This space-charge effect resulted in an improvement over the individual bulk conductivities of the two systems. Sample with higher weight fractions of LLZO are limited by the porosity and grain boundary resistance arising from non-sintered membranes. By combining the properties of LLZO and LPS, the high temperature sintering step has been avoided thus facilitating easier materials processing. The interfacial resistances were also measured to be minimal at ambient conditions. This procedure thus opens a new avenue for improving the ionic conductivity and electrochemical properties of existing solid state electrolytes. High frequency impedance analyses could aid in resolving the ionic conductivity contributions from the space charge layer in the higher conducting composites while mechanical property investigations could illustrate an improvement in the composite electrolyte in comparison with the crystalline LPS membranes.

  12. Mechanical and transparent conductive properties of ZnO and Ga-doped ZnO films sputtered using electron-cyclotron-resonance plasma on polyethylene naphtalate substrates

    SciTech Connect (OSTI)

    Akazawa, Housei, E-mail: akazawa.housei@lab.ntt.co.jp [NTT Microsystem Integration Laboratories 3-1 Morinosato Wakamiya, Atsugi, Kanagawa 243-0198 (Japan)

    2014-03-15T23:59:59.000Z

    Transparent conductive ZnO and Ga-doped ZnO (GZO) films were deposited on polyethylene naphtalate (PEN) sheet substrates using electron cyclotron resonance plasma sputtering. Both ZnO and GZO films were highly adhesive to the PEN substrates without inserting an intermediate layer in the interface. When compared at the same thickness, the transparent conductive properties of GZO films on PEN substrates were only slightly inferior to those on glass substrates. However, the carrier concentration of ZnO films on PEN substrates was 1.5?times that of those on glass substrates, whereas their Hall mobility was only 60% at a thickness of 300?nm. The depth profile of elements measured by secondary ion mass spectroscopy revealed the diffusion of hydrocarbons out of the PEN substrate into the ZnO film. Hence, doped carbons may act as donors to enhance carrier concentration, and the intermixing of elements at the interface may deteriorate the crystallinity, resulting in the lower Hall mobility. When the ZnO films were thicker than 400?nm, cracks became prevalent because of the lattice mismatch strain between the film and the substrate, whereas GZO films were free of cracks. The authors investigated how rolling the films around a cylindrical pipe surface affected their conductive properties. Degraded conductivity occurred at a threshold pipe radius of 10?mm when tensile stress was applied to the film, but it occurred at a pipe radius of 5?mm when compressive stress was applied. These values are guidelines for bending actual devices fabricated on PEN substrates.

  13. Oxidative chemical vapor deposition of conductive polymers for use in novel photovoltaic device architectures

    E-Print Network [OSTI]

    Howden, Rachel M. (Rachel Mary)

    2013-01-01T23:59:59.000Z

    The conductive polymer poly(3,4-ethylenedioxythiophene), (PEDOT), deposited via oxidative chemical vapor deposition (oCVD) has been investigated for use in organic electronic devices. The oCVD process as well as the ...

  14. Microstructure of amorphous indium oxide and tin oxide thin films

    SciTech Connect (OSTI)

    Rauf, I.A.; Brown, L.M. (Univ. of Cambridge (United Kingdom))

    1994-03-15T23:59:59.000Z

    Indium oxide, tin oxide, and some other doped and undoped oxide semiconductors show an interesting and technologically important combination of properties. They have high luminous transparency, good electrical conductivity and high infrared reflectivity. Numerous techniques for depositing these materials have been developed and have undergone a number of changes during last two decades. An understanding of the basic physics of these materials has begun to dawn. Most of the literature on transparent conducting oxides consists of studying the dependence of the properties on the composition, preparation conditions, such as deposition rate, substrate temperature or post-deposition heat treatment. In this paper the authors have employed the transmission electron microscopy to study the microstructure of reactively evaporated, electron beam evaporated, ion-beam sputtered amorphous indium oxide and reactively evaporated amorphous tin oxide thin films. These films, which have received little attention in the past, can have enormous potential as transparent conductive coatings on heat-sensitive substrates and inexpensive solar cells.

  15. p-Type Zinc Oxide Spinels: Application to Transparent Conductors and Spintronics

    E-Print Network [OSTI]

    Stoica, Maria

    2013-01-01T23:59:59.000Z

    We report on the electronic and optical properties of two theoretically predicted stable spinel compounds of the form ZnB2O4, where B = Ni or Cu; neither compound has been previously synthesized, so we compare them to the previously studied p-type ZnCo2O4 spinel. These new materials exhibit spin polarization that is ideal for spintronics applications, and broad conductivity maxima near the valence band edge that facilitate p-type dopability. We show that 3d electrons on the octahedrally coordinated Zn atom fall deep within the valence band and do not contribute significantly to the electronic structure of the material, while the O 2p and tetrahedrally coordinated B 3d electrons hybridize broadly in the shallow valence states, resulting in increasing curvature (i.e., decreased electron effective mass) of valence bands near the band edge. In particular, ZnCu2O4 exhibits high electrical conductivities near the valence band edge that, at sigma = 2 x 10^4 S/cm, are twice the maximum found for ZnCo2O4, a previously...

  16. AC conductivity of nanoporous metal-oxide photoanodes for solar energy conversion

    E-Print Network [OSTI]

    Konezny, Steven J.

    AC conductivity of nanoporous metal-oxide photoanodes for solar energy conversion Steven J. Konezny% solar-to-electric energy conversion efficiency) exploited the large surface area of nanoporous thin for solar photoconversion is analyzed using a model based on fluctuation-induced tunneling conduction (FITC

  17. Conductivity and transparency of TiO2 from first principles Andre Schleife1, Joel B. Varley1,2, Anderson Janotti2, and Chris G. Van de Walle2

    E-Print Network [OSTI]

    Schleife, André

    transparent electronics3 devices. In addition, oxide materials have great potential for photocatalysis4 the properties for both the TCO and photocatalysis applications. Depending on the dopants that are used they can the absorption of visible light and paves the way for more efficient photocatalysis. In order to achieve

  18. Large scale, highly conductive and patterned transparent films of silver nanowires on arbitrary substrates and their application in touch screens

    E-Print Network [OSTI]

    Zhou, Chongwu

    devices, such as liquid crystal displays, light emitting diodes, solar cells and touch panels [1 diodes [21­23] and solar cells [24, 25], and have attracted significant interest. However, their pe of such a conductive silver nanowire film as an electrode in a touch panel has been demonstrated. (Some figures

  19. Development of a cost effective surface-patterned transparent conductive coating as top-contact of light emitting diodes

    SciTech Connect (OSTI)

    Haldar, Arpita [Department of Applied Optics and Photonics, University of Calcutta, Kolkata-700009 (India); Sol-Gel Division, CSIR-Central Glass and Ceramic Research Institute, Kolkata 700032 (India); Bera, Susanta; Jana, Sunirmal, E-mail: sjana@cgcri.res.in, E-mail: srirajib@yahoo.com [Sol-Gel Division, CSIR-Central Glass and Ceramic Research Institute, Kolkata 700032 (India); Bhattacharya, Kallol; Chakraborty, Rajib, E-mail: sjana@cgcri.res.in, E-mail: srirajib@yahoo.com [Department of Applied Optics and Photonics, University of Calcutta, Kolkata-700009 (India)

    2014-05-21T23:59:59.000Z

    Sol-gel process has been used to form indium zinc oxide films using an optimized combination of zinc to indium concentration in the precursor solutions. Different structures, like one (1D) and two-dimensional (2D) gratings and diffractive optical elements (DOEs) in the form of Fresnel lens are fabricated on the film surface of proposed top metal contact of LED by imprint soft lithography technique. These structures can enhance the LED's light extraction efficiency (LEE) or can shape the output beam pattern, respectively. Several characterizations are done to analyze the material and structural properties of the films. The presence of 1D and 2D gratings as well as DOEs is confirmed from field emission scanning electron and atomic force microscopes analyses. Although, X-ray diffraction shows amorphous nature of the film, but transmission electron microscopy study shows that it is nano crystalline in nature having fine particles (?8?nm) of hexagonal ZnO. Shrinkage behaviour of gratings as a function of curing temperature is explained by Fourier transform infra-red spectra and thermo gravimetric-differential thermal analysis. The visible transmission and sheet resistance of the sample are found comparable to tin doped indium oxide (ITO). Therefore, the film can compete as low cost substitute of ITO as top metal contact of LEDs.

  20. Thin film ion conducting coating

    DOE Patents [OSTI]

    Goldner, Ronald B. (Lexington, MA); Haas, Terry (Sudbury, MA); Wong, Kwok-Keung (Watertown, MA); Seward, George (Arlington, MA)

    1989-01-01T23:59:59.000Z

    Durable thin film ion conducting coatings are formed on a transparent glass substrate by the controlled deposition of the mixed oxides of lithium:tantalum or lithium:niobium. The coatings provide durable ion transport sources for thin film solid state storage batteries and electrochromic energy conservation devices.

  1. Electrical conductivity in oxygen-deficient phases of transition metal oxides from first-principles calculations.

    SciTech Connect (OSTI)

    Bondi, Robert James; Desjarlais, Michael Paul; Thompson, Aidan Patrick; Brennecka, Geoffrey L.; Marinella, Matthew

    2013-09-01T23:59:59.000Z

    Density-functional theory calculations, ab-initio molecular dynamics, and the Kubo-Greenwood formula are applied to predict electrical conductivity in Ta2Ox (0x5) as a function of composition, phase, and temperature, where additional focus is given to various oxidation states of the O monovacancy (VOn; n=0,1+,2+). Our calculations of DC conductivity at 300K agree well with experimental measurements taken on Ta2Ox thin films and bulk Ta2O5 powder-sintered pellets, although simulation accuracy can be improved for the most insulating, stoichiometric compositions. Our conductivity calculations and further interrogation of the O-deficient Ta2O5 electronic structure provide further theoretical basis to substantiate VO0 as a donor dopant in Ta2O5 and other metal oxides. Furthermore, this dopant-like behavior appears specific to neutral VO cases in both Ta2O5 and TiO2 and was not observed in other oxidation states. This suggests that reduction and oxidation reactions may effectively act as donor activation and deactivation mechanisms, respectively, for VO0 in transition metal oxides.

  2. CRAD, Conduct of Operations- Y-12 Enriched Uranium Operations Oxide Conversion Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a January, 2005 assessment of Conduct of Operations program at the Y-12 - Enriched Uranium Operations Oxide Conversion Facility.

  3. Stochastic model of lithium ion conduction in poly,,ethylene oxide... L. Gitelman,1

    E-Print Network [OSTI]

    Averbuch, Amir

    Stochastic model of lithium ion conduction in poly,,ethylene oxide... L. Gitelman,1 A. Averbuch,2,a of LiI salt. The current is due to diffusion and electric interactions with a permanent external field, the PEO charges, and ion-ion interactions. Potential barriers are created in the PEO by loops in structure

  4. Highly Conductive and Porous Activated Reduced Graphene Oxide Films for High-Power Supercapacitors

    E-Print Network [OSTI]

    Highly Conductive and Porous Activated Reduced Graphene Oxide Films for High-Power Supercapacitors for a free-standing carbon film reported to date. A two-electrode supercapacitor using these carbon films. KEYWORDS: Graphene, flexible film, chemical activation, supercapacitors Free-standing thin film materials

  5. Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

  6. Nickel vacancy behavior in the electrical conductance of nonstoichiometric nickel oxide film

    SciTech Connect (OSTI)

    Kim, Dong Soo; Lee, Hee Chul [Department of Electrical Engineering, Korea Advanced Institute of Science and Technology, 335 Gwahangno, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)

    2012-08-01T23:59:59.000Z

    Nickel vacancy behavior in electrical conductance is systematically investigated using various analysis methods on nickel oxide films deposited at different oxygen partial pressures. The results of Rutherford backscattering, x-ray diffraction, and Auger electron spectroscopy analyses demonstrate that the sputtered nickel oxide films are nickel-deficient. Through the deconvolution of Ni2p and O1s spectra in the x-ray photoelectron spectroscopy data, the number of Ni{sup 3+} ions is found to increase with the O{sub 2} ratio during the deposition. According to the vacancy model, nickel vacancies created from the non-stoichiometry are concluded to produce Ni{sup 3+} ions which lead to an increment of the conductivity of the nickel oxide films due to the increase of the hole concentration.

  7. Transparent conductive nano-composites

    DOE Patents [OSTI]

    Geohegan, David Bruce (Knoxville, TN); Ivanov, Ilia N. (Knoxville, TN); Puretzky, Alexander A. (Knoxville, TN); Jesse, Stephen (Knoxville, TN); Hu, Bin (Knoxville, TN); Garrett, Matthew (Knoxville, TN); Zhao, Bin (Easley, SC)

    2011-04-12T23:59:59.000Z

    The present invention, in one embodiment, provides a method of forming an organic electric device that includes providing a plurality of carbon nanostructures; and dispersing the plurality of carbon nanostructures in a polymeric matrix to provide a polymeric composite, wherein when the plurality of carbon nanostructures are present at a first concentration an interface of the plurality of carbon nanostructures and the polymeric matrix is characterized by charge transport when an external energy is applied, and when the plurality of carbon nanostructures are present at a second concentration the interface of the plurality of carbon nanostructures and the polymeric matrix are characterized by exciton dissociation when an external energy is applied, wherein the first concentration is less than the second concentration.

  8. Transparent conductive nano-composites

    DOE Patents [OSTI]

    Geohegan, David Bruce; Ivanov, Ilia N; Puretzky, Alexander A; Jesse, Stephen; Hu, Bin; Garrett, Matthew; Zhao, Bin

    2013-09-24T23:59:59.000Z

    The present invention, in one embodiment, provides a method of forming an organic electric device that includes providing a plurality of carbon nanostructures; and dispersing the plurality of carbon nanostructures in a polymeric matrix to provide a polymeric composite, wherein when the plurality of carbon nanostructures are present at a first concentration an interface of the plurality of carbon nanostructures and the polymeric matrix is characterized by charge transport when an external energy is applied, and when the plurality of carbon nanostructures are present at a second concentration the interface of the plurality of carbon nanostructures and the polymeric matrix are characterized by exciton dissociation when an external energy is applied, wherein the first concentration is less than the second concentration.

  9. Pressure effect on ionic conductivity in yttrium-oxide-doped single-crystal zirconium oxide

    SciTech Connect (OSTI)

    Park, E.T.; Park, J.H.

    1998-06-01T23:59:59.000Z

    In this study, the authors investigated the effect of pressure on the ionic conductivity of a 9.5 mol% yttria-stabilized zirconia (YSZ) single crystal. The experiment was conducted in the elastic region, and the oxygen ion transport number was unity (t{sub ion} > 0.99999). A conventional four-probe DC method was used to measure the ionic conductivity of the rectangular-shaped sample under uniaxial pressures up to 600 atm at 750 C in air. Measured ionic conductivity decreased as applied pressure increased. Based on henry Eyring`s absolute reaction rate theory, which states that the calculated activation volume has a positive value ({Delta}V{sup 2} = 2.08 cm{sup 3}/mol of O{sup {minus}2}) for oxygen ion transport in the fluoride cubic lattice, they concluded that the results they obtained could be explained by an oxygen ion transport mechanism. This mechanism can explain the fact that the interionic distance increases during oxygen ion transport from one unit cell to neighboring unit cells.

  10. Degradation of transparent conductive properties of undoped ZnO and Ga-doped ZnO films left in atmospheric ambient for several years and trials to recover initial conductance

    SciTech Connect (OSTI)

    Akazawa, Housei, E-mail: akazawa.housei@lab.ntt.co.jp [NTT Microsystem Integration Laboratories, 3-1 Morinosato Wakamiya, Atsugi, Kanagawa 243-0198 (Japan)

    2014-03-15T23:59:59.000Z

    This study evaluated the long-term stability of the transparent conductive properties of undoped ZnO and Ga-doped ZnO (GZO) films that had been left in an atmospheric ambient environment for 5 to 6 yr. When ZnO films are stored in a clean room with a controlled temperature and humidity of 23?°C and 45%, respectively, throughout the year, the increases in sheet resistance are less than 5% of their initial value. The ZnO films stored in a non-air-conditioned laboratory room, whose temperature varies between 5 and 35?°C and humidity varies between 30% and 70% per year, suffer from increases in the sheet resistance by almost 13%, which is associated with a slight rise in the near-infrared transmittance level. Postannealing of these degraded ZnO films at 150–200?°C recovers the initial conductance by removing the H{sub 2}O molecules that have penetrated the film. One hour of irradiation with electron cyclotron resonance Ar plasma effectively restores the conductive surfaces while maintaining a temperature below 70?°C. The GZO films containing a few weight percent of Ga{sub 2}O{sub 3} are stable even when stored in a non-air-conditioned laboratory room, with changes in the sheet resistance of less than 3%. The GZO films with a Ga{sub 2}O{sub 3} content larger than 10?wt. %, however, exhibit serious degradation probably due to the strong affinity of segregated Ga{sub 2}O{sub 3} domains with H{sub 2}O vapor molecules. Neither postannealing nor Ar plasma irradiation can recover the initial sheet resistance of these GZO films.

  11. STABLE HIGH CONDUCTIVITY BILAYERED ELECTROLYTES FOR LOW TEMPERATURE SOLID OXIDE FUEL CELLS

    SciTech Connect (OSTI)

    Eric D. Wachsman; Keith L. Duncan

    2002-03-31T23:59:59.000Z

    Solid oxide fuel cells (SOFCs) are the future of energy production in America. They offer great promise as a clean and efficient process for directly converting chemical energy to electricity while providing significant environmental benefits (they produce negligible hydrocarbons, CO, or NO{sub x} and, as a result of their high efficiency, produce about one-third less CO{sub 2} per kilowatt hour than internal combustion engines). Unfortunately, the current SOFC technology, based on a stabilized zirconia electrolyte, must operate in the region of 1000 C to avoid unacceptably high ohmic losses. These high temperatures demand (a) specialized (expensive) materials for the fuel cell interconnects and insulation, (b) time to heat up to the operating temperature and (c) energy input to arrive at the operating temperature. Therefore, if fuel cells could be designed to give a reasonable power output at low to intermediate temperatures tremendous benefits may be accrued. At low temperatures, in particular, it becomes feasible to use ferritic steel for interconnects instead of expensive and brittle ceramic materials such as those based on LaCrO{sub 3}. In addition, sealing the fuel cell becomes easier and more reliable; rapid startup is facilitated; thermal stresses (e.g., those caused by thermal expansion mismatches) are reduced; radiative losses ({approx}T{sup 4}) become minimal; electrode sintering becomes negligible and (due to a smaller thermodynamic penalty) the SOFC operating cycle (heating from ambient) would be more efficient. Combined, all these improvements further result in reduced initial and operating costs. The problem is, at lower temperatures the conductivity of the conventional stabilized zirconia electrolyte decreases to the point where it cannot supply electrical current efficiently to an external load. The primary objectives of the proposed research is to develop a stable high conductivity (> 0.05 S cm{sup -1} at {le} 550 C) electrolyte for lower temperature SOFCs. This objective is specifically directed toward meeting the lowest (and most difficult) temperature criteria for the 21st Century Fuel Cell Program. Meeting this objective provides a potential for future transportation applications of SOFCs, where their ability to directly use hydrocarbon fuels could permit refueling within the existing transportation infrastructure. In order to meet this objective we are developing a functionally gradient bilayer electrolyte comprised of a layer of erbia-stabilized bismuth oxide (ESB) on the oxidizing side and a layer of SDC or GDC on the reducing side, see Fig. 1. Bismuth oxide and doped ceria are among the highest ionic conducting electrolytes and in fact bismuth oxide based electrolytes are the only known solid oxide electrolytes to have an ionic conductivity that meets the program conductivity goal. In this arrangement, the ceria layer protects the bismuth oxide layer from decomposing by shielding it from very low P{sub O{sub 2}}'s and the ESB layer serves to block electronic flux through the electrolyte. This arrangement has two significant advantages over the YSZ/SDC bilayers investigated by others [1, 2]. The first advantage is that SDC is conductive enough to serve as an intermediate temperature SOFC electrolyte. Moreover, ESB is conductive enough to serve as a low temperature electrolyte. Consequently, at worst an SDC/ESB bilayered SOFC should have the conductivity of SDC but with improved efficiency due to the electronic flux barrier provided by ESB. The second advantage is that small (dopant) concentrations of SDC in ESB or ESB in SDC, have been found to have conductivities comparable to the host lattice [3, 4]. Therefore, if solid solutioning occurs at the SDC-ESB interface, it should not be detrimental to the performance of the bilayer. In contrast, solid solutions of SDC and YSZ have been found to be significantly less conductive than SDC or YSZ. Thus, it bears emphasizing that, at this time, only SDC/ESB electrolytes have potential in low temperature SOFC applications.

  12. Conductive” yttria-stabilized zirconia as an epitaxial template for oxide heterostructures

    SciTech Connect (OSTI)

    Caspers, C.; Müller, M., E-mail: mart.mueller@fz-juelich.de [Peter Grünberg Institut (PGI-6), Forschungszentrum Jülich, 52425 Jülich (Germany); Gloskovskii, A.; Drube, W. [DESY Photon Science, Deutsches Elektronen-Synchrotron, 22603 Hamburg (Germany); Schneider, C. M. [Peter Grünberg Institut (PGI-6), Forschungszentrum Jülich, 52425 Jülich (Germany); Fakultät für Physik and Center for Nanointegration Duisburg-Essen (CeNIDE), 47048 Duisburg (Germany)

    2014-05-07T23:59:59.000Z

    We report an in situ thermochemical treatment that significantly increases the macroscopic electrical conductivity of insulating yttria-stabilized zirconia (YSZ) (001) single-crystalline substrates. We demonstrate the high-quality surface crystalline structure of the resulting “conductive” cYSZ (001) by low- and high-energy electron diffraction. Soft- and hard X-ray photoemission spectroscopy measurements reveal a sizable reduction of Zr cations to a metallic state and their homogeneous distribution within the cYSZ. We discuss the correlation between the microscopic chemical processes leading to the increased macroscopic metallicity. Finally, the heteroepitaxial growth of a functional magnetic oxide model system, ultrathin EuO on cYSZ (001), was demonstrated. cYSZ (001) thereby enables both high quality oxide heteroepitaxy and the advanced sample characterization by high electron-fluence characterization techniques.

  13. STABLE HIGH CONDUCTIVITY BILAYERED ELECTROLYTES FOR LOW TEMPERATURE SOLID OXIDE FUEL CELLS

    SciTech Connect (OSTI)

    Eric D. Wachsman

    2000-10-01T23:59:59.000Z

    Solid oxide fuel cells (SOFCs) are the future of energy production in America. They offer great promise as a clean and efficient process for directly converting chemical energy to electricity while providing significant environmental benefits (they produce negligible CO, HC, or NOx and, as a result of their high efficiency, produce about one-third less CO{sub 2} per kilowatt hour than internal combustion engines). Unfortunately, the current SOFC technology, based on a stabilized zirconia electrolyte, must operate in the region of 1000 C to avoid unacceptably high ohmic losses. These high temperatures demand (a) specialized (expensive) materials for the fuel cell interconnects and insulation, (b) time to heat up to the operating temperature and (c) energy input to arrive at the operating temperature. Therefore, if fuel cells could be designed to give a reasonable power output at lower temperatures tremendous benefits may be accrued, not the least of which is reduced cost. The problem is, at lower temperatures the conductivity of the conventional stabilized zirconia electrolyte decreases to the point where it cannot supply electrical current efficiently to an external load. The primary objectives of the proposed research is to develop a stable high conductivity (>0.05 S cm{sup -1} at 550 C) electrolyte for lower temperature SOFCs. This objective is specifically directed toward meeting the lowest (and most difficult) temperature criteria for the 21st Century Fuel Cell Program. Meeting this objective provides a potential for future transportation applications of SOFCs, where their ability to directly use hydrocarbon fuels could permit refueling within the existing transportation infrastructure. In order to meet this objective we are developing a functionally gradient bilayer electrolyte comprised of bismuth oxide on the air side and ceria on the fuel side. Bismuth oxide and doped ceria are among the highest ionic conducting electrolytes and in fact bismuth oxide based electrolytes are the only known solid oxide electrolytes to have an ionic conductivity that meets the program conductivity goal. We have previously demonstrated that this concept works, that a bismuth oxide/ceria bilayer electrolyte provides near theoretical open circuit potential (OCP) and is stable for 1400 h of fuel cell operation under both open circuit and maximum power conditions. More recently, we developed a computer model to determine the defect transport in this bilayer and have found that a bilayer comprised primarily of the more conductive component (bismuth oxide) is stable for 500 C operation. In this first year of the project we are obtaining necessary thermochemical data to complete the computer model as well as initial SOFC results based on thick 1-2 mm single and bilayer ceria/bismuth oxide electrolytes. We will use the computer model to obtain the optimum relative layer thickness as a function of temperature and air/fuel conditions. SOFCs will be fabricated with 1-2 mm single and bilayer electrolytes based on the modeling results, tested for OCP, conductivity, and stability and compared against the predictions. The computer modeling is a continuation of previous work under support from GRI and the student was available at the inception of the contract. However, the experimental effort was delayed until the beginning of the Spring Semester because the contract was started in October, 2 months after the start of our Fall Semester, and after all of the graduate students were committed to other projects. The results from both of these efforts are described in the following two sections: (1) Experimental; and (2) Computer Modeling.

  14. STABLE HIGH CONDUCTIVITY BILAYERED ELECTROLYTES FOR LOW TEMPERATURE SOLID OXIDE FUEL CELLS

    SciTech Connect (OSTI)

    Eric D. Wachsman; Keith L. Duncan

    2002-09-30T23:59:59.000Z

    A bilayer electrolyte consisting of acceptor-doped ceria (on the fuel/reducing side) and cubic-stabilized bismuth oxide (on the oxidizing side) was developed. The bilayer electrolyte that was developed showed significant improvement in open-circuit potential versus a typical ceria based SOFC. Moreover, the OCP of the bilayer cells increased as the thickness of the bismuth oxide layer increased relative to the ceria layer. Thereby, verifying the bilayer concept. Although, because of the absence of a suitable cathode (a problem we are still working assiduously to solve), we were unable to obtain power density curves, our modeling work predicts a reduction in electrolyte area specific resistance of two orders of magnitude over cubic-stabilized zirconia and projects a maximum power density of 9 W/m{sup 2} at 800 C and 0.09 W/m{sup 2} at 500 C. Towards the development of the bilayer electrolyte other significant strides were made. Among these were, first, the development of a, bismuth oxide based, oxide ion conductor with the highest conductivity (0.56 S/cm at 800 C and 0.043 S/cm at 500 C) known to date. Second, a physical model of the defect transport mechanisms and the driving forces for the ordering phenomena in bismuth oxide and other fluorite systems was developed. Third, a model for point defect transport in oxide mixed ionic-electronic conductors was developed, without the typical assumption of a uniform distribution of ions and including the effect of variable loads on the transport properties of an SOFC (with either a single or bilayer electrolyte).

  15. Optimization of transparent and reflecting electrodes for amorphous-silicon solar cells. Final subcontract report, 1 May 1991--30 April 1994

    SciTech Connect (OSTI)

    Gordon, R.G.; Hu, J.; Lacks, D.; Musher, J.; Thornton, J.; Liang, H. [Harvard Univ., Cambridge, MA (United States)

    1994-07-01T23:59:59.000Z

    Fluorine-doped zinc oxide was shown to have the lowest absorption loss of any of the known transparent conductors. An apparatus was constructed to deposit textured, transparent, conductive, fluorine-doped zinc oxide layers with uniform thickness over a 10 cm by 10 cm area, using inexpensive, high-productivity atmospheric pressure chemical vapor deposition. Amorphous silicon solar cells grown on these textured films show very high peak quantum efficiencies (over 90%). However, a significant contact resistance develops at the interface between the amorphous silicon and the zinc oxide. Transparent, conductive gallium-doped zinc oxide films were grown by APCVD at a low enough temperature (260{degree}C) to be deposited on amorphous silicon as a final conductive back contact to solar cells. A quantum-mechanical theory of bonding was developed and applied to some metal oxides; it forms a basis for understanding TCO structures and the stability of their interfaces with silicon.

  16. CdO as the Archetypical Transparent Conducting Oxide. Systematics of Dopant Ionic Radius and Electronic Structure

    E-Print Network [OSTI]

    Medvedeva, Julia E.

    -color displays); and (4) chemical instability in certain device structures (e.g., corrosion in organic light-emitting diode (OLED) devices). In view of these issues, intense research has been focused on understanding

  17. Dopant Ion Size and Electronic Structure Effects on Transparent Conducting Oxides. Sc-Doped CdO Thin Films

    E-Print Network [OSTI]

    Medvedeva, Julia E.

    O Thin Films Grown by MOCVD Shu Jin,, Yu Yang,, Julia E. Medvedeva,,§ John R. Ireland,| Andrew W. Metz-doped CdO (CSO) thin films have been grown on both amorphous glass and single-crystal MgO(100) substrates) at a Sc doping level of 1.8 atom %. The CSO thin films exhibit an average transmittance >80

  18. Low temperature formation of electrode having electrically conductive metal oxide surface

    DOE Patents [OSTI]

    Anders, Simone (Albany, CA); Anders, Andre (Albany, CA); Brown, Ian G. (Berkeley, CA); McLarnon, Frank R. (Orinda, CA); Kong, Fanping (Berkeley, CA)

    1998-01-01T23:59:59.000Z

    A low temperature process is disclosed for forming metal suboxides on substrates by cathodic arc deposition by either controlling the pressure of the oxygen present in the deposition chamber, or by controlling the density of the metal flux, or by a combination of such adjustments, to thereby control the ratio of oxide to metal in the deposited metal suboxide coating. The density of the metal flux may, in turn, be adjusted by controlling the discharge current of the arc, by adjusting the pulse length (duration of on cycle) of the arc, and by adjusting the frequency of the arc, or any combination of these parameters. In a preferred embodiment, a low temperature process is disclosed for forming an electrically conductive metal suboxide, such as, for example, an electrically conductive suboxide of titanium, on an electrode surface, such as the surface of a nickel oxide electrode, by such cathodic arc deposition and control of the deposition parameters. In the preferred embodiment, the process results in a titanium suboxide-coated nickel oxide electrode exhibiting reduced parasitic evolution of oxygen during charging of a cell made using such an electrode as the positive electrode, as well as exhibiting high oxygen overpotential, resulting in suppression of oxygen evolution at the electrode at full charge of the cell.

  19. Black Conductive Titanium Oxide High-Capacity Materials for Battery Electrodes

    SciTech Connect (OSTI)

    Han, W.

    2011-05-18T23:59:59.000Z

    Stoichiometric titanium dioxide (TiO{sub 2}) is one of the most widely studied transitionmetal oxides because of its many potential applications in photoelectrochemical systems, such as dye-sensitized TiO{sub 2} electrodes for photovoltaic solar cells, and water-splitting catalysts for hydrogen generation, and in environmental purification for creating or degrading specific compounds. However, TiO{sub 2} has a wide bandgap and high electrical resistivity, which limits its use as an electrode. A set of non-stoichiometric titanium oxides called the Magneli phases, having a general formula of Ti{sub n}O{sub 2n-1} with n between 4 and 10, exhibits lower bandgaps and resistivities, with the highest electrical conductivities reported for Ti{sub 4}O{sub 7}. These phases have been formulated under different conditions, but in all reported cases the resulting oxides have minimum grain sizes on the order of micrometers, regardless of the size of the starting titanium compounds. In this method, nanoparticles of TiO{sub 2} or hydrogen titanates are first coated with carbon using either wet or dry chemistry methods. During this process the size and shape of the nanoparticles are 'locked in.' Subsequently the carbon-coated nanoparticles are heated. This results in the transformation of the original TiO{sub 2} or hydrogen titanates to Magneli phases without coarsening, so that the original size and shape of the nanoparticles are maintained to a precise degree. People who work on batteries, fuel cells, ultracapacitors, electrosynthesis cells, electro-chemical devices, and soil remediation have applications that could benefit from using nanoscale Magneli phases of titanium oxide. Application of these electrode materials may not be limited to substitution for TiO{sub 2} electrodes. Combining the robustness and photosensitivity of TiO{sub 2} with higher electrical conductivity may result in a general electrode material.

  20. Origin of Colossal Ionic Conductivity in Oxide Multilayers: Interface Induced Sublattice Disorder

    SciTech Connect (OSTI)

    Pennycook, Timothy J [ORNL; Beck, Matthew [Vanderbilt University; Varga, Kalman [ORNL; Varela del Arco, Maria [ORNL; Pennycook, Stephen J [ORNL; Pantelides, Sokrates T [ORNL

    2010-01-01T23:59:59.000Z

    Oxide ionic conductors typically operate at high temperatures, which limits their usefulness. Colossal room-temperature ionic conductivity was recently discovered in multilayers of yttria-stabilized zirconia (YSZ) and SrTiO3. Here we report density-functional calculations that trace the origin of the effect to a combination of lattice-mismatch strain and O-sublattice incompatibility. Strain alone in bulk YSZ enhances O mobility at high temperatures by inducing extreme O disorder. In multilayer structures, O-sublattice incompatibility causes the same extreme disorder at room temperature.

  1. TRANSPARENCY RECYCLING PROGRAM PROCEDURES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transparencies to be recycled. 2.) SEPARATE the transparencies from ringed binders, plastic or paper folders, envelopes, andor files. 3.) PLACE the transparencies (only) into...

  2. NREL Designs Promising New Oxides for Solar Cells (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-04-01T23:59:59.000Z

    High-efficiency, thin-film solar cells require electrical contacts with high electrical conductivity, and the top contact must also have high optical transparency. This need is currently met by transparent conducting oxides (TCOs), which conduct electricity but are 90% transparent to visible light. Scientists at the National Renewable Energy Laboratory (NREL) have derived three key design principles for selecting promising materials for TCO contacts. NREL's application of these design principles has resulted in a 10,000-fold improvement in conductivity for one TCO material.

  3. Oxidation Resistant, Cr Retaining, Electrically Conductive Coatings on Metallic Alloys for SOFC Interconnects

    SciTech Connect (OSTI)

    Vladimir Gorokhovsky

    2008-03-31T23:59:59.000Z

    This report describes significant results from an on-going, collaborative effort to enable the use of inexpensive metallic alloys as interconnects in planar solid oxide fuel cells (SOFCs) through the use of advanced coating technologies. Arcomac Surface Engineering, LLC, under the leadership of Dr. Vladimir Gorokhovsky, is investigating filtered-arc and filtered-arc plasma-assisted hybrid coating deposition technologies to promote oxidation resistance, eliminate Cr volatility, and stabilize the electrical conductivity of both standard and specialty steel alloys of interest for SOFC metallic interconnect (IC) applications. Arcomac has successfully developed technologies and processes to deposit coatings with excellent adhesion, which have demonstrated a substantial increase in high temperature oxidation resistance, stabilization of low Area Specific Resistance values and significantly decrease Cr volatility. An extensive matrix of deposition processes, coating compositions and architectures was evaluated. Technical performance of coated and uncoated sample coupons during exposures to SOFC interconnect-relevant conditions is discussed, and promising future directions are considered. Cost analyses have been prepared based on assessment of plasma processing parameters, which demonstrate the feasibility of the proposed surface engineering process for SOFC metallic IC applications.

  4. New insight into the properties of proton conducting oxides from neutron total scattering

    SciTech Connect (OSTI)

    Proffen, Thomas E [Los Alamos National Laboratory; Kim, Hyunjeong [Los Alamos National Laboratory; Malavasi, Lorenzo [U PAVIA, ITALY; Flor, Giorgio [U PAVIA, ITALY

    2008-01-01T23:59:59.000Z

    In recent years there has been a growing interest in searching for new proton conducting materials that could be successfully used in medium temperature solid oxide fuel cells (SOFC). In particular, proton conducting oxides have been the subject of a massive research activity. Among the most promising oxide the acceptor doped cerates appears to be those most appealing in view of practical applications. A relevant aspect of these materials is the investigation of the local distortion of the structure arising from water incorporation. This kind of study is of great help in defining how the structure changes in order to accommodate the proton which is usually thought to enter the structure in form of hydroxyl group where the oxygen vacancy results from the acceptor doping on the Ce site. Atomistic simulation work confirmed that the preferential location of dopant ions is on the Ce site. To the best of our knowledge the only experimental work addressing the role of dopant and water incorporation on the local structure of V-doped cerates is a X-ray absorption spectroscopy (XAS) work carried out by Longo and coworkers at the Y K-edge. The main conclusion of that work was the observation that Y-doping induces a distortion of the parent BaCe0{sub 3} structure resulting in a significantly distorted Y local environment. However, local structure information derived from XAS study does not provide a direct structural information and depends strongly upon the model used to calcualte theoretical {chi}(k) which is not unique. Moreover, the XAS analysis usually provide significant information only up to the second shell. As a consequence, a more reliable and useful technique to investigate the local arrangement in these proton conducting oxides appears to be the Pair Distribution Function (PDF) analysis derived from total neutron scattering measurements. In the present work we investigated the pure BaCeO{sub 3} and the acceptor doped BaCe{sub 0.90}Y{sub 0.10}O{sub 2.85} compounds. In both cases the samples have been measured at room temperature and after being exposed to dry and wet air (humidification attained through bubbling air in D{sub 2}O). Aim of this work is to look at the effect of Y-doping and water doping on the local structure of the above mentioned samples.

  5. Effects of hole localization on limiting p-type conductivity in oxide and nitride semiconductors

    SciTech Connect (OSTI)

    Lyons, J. L.; Janotti, A.; Van de Walle, C. G. [Materials Department, University of California, Santa Barbara, California 93106-5050 (United States)

    2014-01-07T23:59:59.000Z

    We examine how hole localization limits the effectiveness of substitutional acceptors in oxide and nitride semiconductors and explain why p-type doping of these materials has proven so difficult. Using hybrid density functional calculations, we find that anion-site substitutional impurities in AlN, GaN, InN, and ZnO lead to atomic-like states that localize on the impurity atom itself. Substitution with cation-site impurities, on the other hand, triggers the formation of polarons that become trapped on nearest-neighbor anions, generally leading to large ionization energies for these acceptors. Unlike shallow effective-mass acceptors, these two types of deep acceptors couple strongly with the lattice, significantly affecting the optical properties and severely limiting prospects for achieving p-type conductivity in these wide-band-gap materials.

  6. TRANSPARENT COATINGS FOR SOLAR CELLS RESEARCH

    SciTech Connect (OSTI)

    Glatkowski, P.J.; Landis, D.A.

    2013-04-16T23:59:59.000Z

    Todays solar cells are fabricated using metal oxide based transparent conductive coatings (TCC) or metal wires with optoelectronic performance exceeding that currently possible with Carbon Nanotube (CNT) based TCCs. The motivation for replacing current TCC is their inherent brittleness, high deposition cost, and high deposition temperatures; leading to reduced performance on thin substrates. With improved processing, application and characterization techniques Nanofiber and/or CNT based TCCs can overcome these shortcomings while offering the ability to be applied in atmospheric conditions using low cost coating processes At todays level of development, CNT based TCC are nearing commercial use in touch screens, some types of information displays (i.e. electronic paper), and certain military applications. However, the resistivity and transparency requirements for use in current commercial solar cells are more stringent than in many of these applications. Therefore, significant research on fundamental nanotube composition, dispersion and deposition are required to reach the required performance commanded by photovoltaic devices. The objective of this project was to research and develop transparent conductive coatings based on novel nanomaterial composite coatings, which comprise nanotubes, nanofibers, and other nanostructured materials along with binder materials. One objective was to show that these new nanomaterials perform at an electrical resistivity and optical transparency suitable for use in solar cells and other energy-related applications. A second objective was to generate new structures and chemistries with improved resistivity and transparency performance. The materials also included the binders and surface treatments that facilitate the utility of the electrically conductive portion of these composites in solar photovoltaic devices. Performance enhancement venues included: CNT purification and metallic tube separation techniques, chemical doping, CNT patterning and alignment, advances in commercial and research materials and field effect schemes. In addition, Eikos continued to develop improved efficiency coating materials and transfer methods suitable for batch and continuous roll-to-roll fabrication requirements. Finally, Eikos collaborated with NREL and the PV-community at large in fabricating and characterizing Invisicon���® enabled solar cells.

  7. Method of depositing an electrically conductive oxide film on a textured metallic substrate and articles formed therefrom

    DOE Patents [OSTI]

    Christen, David K. (Oak Ridge, TN); He, Qing (Bloomington, MN)

    2003-04-29T23:59:59.000Z

    The present invention provides a biaxially textured laminate article having a polycrystalline biaxially textured metallic substrate with an electrically conductive oxide layer epitaxially deposited thereon and methods for producing same. In one embodiment a biaxially texture Ni substrate has a layer of LaNiO.sub.3 deposited thereon. An initial layer of electrically conductive oxide buffer is epitaxially deposited using a sputtering technique using a sputtering gas which is an inert or forming gas. A subsequent layer of an electrically conductive oxide layer is then epitaxially deposited onto the initial layer using a sputtering gas comprising oxygen. The present invention will enable the formation of biaxially textured devices which include HTS wires and interconnects, large area or long length ferromagnetic and/or ferroelectric memory devices, large area or long length, flexible light emitting semiconductors, ferroelectric tapes, and electrodes.

  8. Method of depositing an electrically conductive oxide film on a textured metallic substrate and articles formed therefrom

    DOE Patents [OSTI]

    Christen, David K. (Oak Ridge, TN); He, Qing (Bloomington, MN)

    2001-01-01T23:59:59.000Z

    The present invention provides a biaxially textured laminate article having a polycrystalline biaxially textured metallic substrate with an electrically conductive oxide layer epitaxially deposited thereon and methods for producing same. In one embodiment a biaxially texture Ni substrate has a layer of LaNiO.sub.3 deposited thereon. An initial layer of electrically conductive oxide buffer is epitaxially deposited using a sputtering technique using a sputtering gas which is an inert or forming gas. A subsequent layer of an electrically conductive oxide layer is then epitaxially deposited onto the initial layer using a sputtering gas comprising oxygen. The present invention will enable the formation of biaxially textured devices which include HTS wires and interconnects, large area or long length ferromagnetic and/or ferroelectric memory devices, large area or long length, flexible light emitting semiconductors, ferroelectric tapes, and electrodes.

  9. Laser Direct Write Patterned Indium Tin Oxide Films for Photomasks and Anisotropic Resist Applications

    E-Print Network [OSTI]

    Chapman, Glenn H.

    Laser Direct Write Patterned Indium Tin Oxide Films for Photomasks and Anisotropic Resist bimetallic Sn/In film into a indium tin oxide layer. Sn over In films (15-120nm thick) with a 1:10 thickness mask, etch resist. 1. Introduction The transparent and conductive films like indium tin oxide (ITO

  10. Patterning of indium tin oxide by projection photoablation and lift-off process for fabrication of flat-panel displays

    E-Print Network [OSTI]

    Jain, Kanti

    Patterning of indium tin oxide by projection photoablation and lift-off process for fabrication online 25 June 2007 Indium tin oxide ITO , an important material used as a transparent conductive oxide in such fabrication. Therefore, innovations in patterning tech- nology, especially for materials such as indium tin

  11. Conductive Polypyrrole/Tungsten Oxide Metacomposites with Negative Permittivity Jiahua Zhu,

    E-Print Network [OSTI]

    Guo, John Zhanhu

    to the inherently conductive conjugated polymers, because they are infusible in nature and generally insoluble

  12. Resistive switching and conductance quantization in Ag/SiO{sub 2}/indium tin oxide resistive memories

    SciTech Connect (OSTI)

    Gao, S.; Chen, C.; Liu, H. Y.; Lin, Y. S.; Li, S. Z.; Lu, S. H.; Wang, G. Y.; Song, C.; Zeng, F., E-mail: zengfei@mail.tsinghua.edu.cn; Pan, F., E-mail: panf@mail.tsinghua.edu.cn [Laboratory of Advanced Materials (MOE), School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Zhai, Z. [Department of Metallurgical Engineering, College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024 (China)

    2014-08-11T23:59:59.000Z

    The Ag/SiO{sub 2}/indium tin oxide (ITO) devices exhibit bipolar resistive switching with a large memory window of ?10{sup 2}, satisfactory endurance of >500 cycles, good retention property of >2000?s, and fast operation speed of <100?ns, thus being a type of promising resistive memory. Under slow voltage sweep measurements, conductance plateaus with a conductance value of integer or half-integer multiples of single atomic point contact have been observed, which agree well with the physical phenomenon of conductance quantization. More importantly, the Ag/SiO{sub 2}/ITO devices exhibit more distinct quantized conductance plateaus under pulse measurements, thereby showing the potential for realizing ultra-high storage density.

  13. Electronic devices containing switchably conductive silicon oxides as a switching element and methods for production and use thereof

    DOE Patents [OSTI]

    Tour, James M; Yao, Jun; Natelson, Douglas; Zhong, Lin; He, Tao

    2013-11-26T23:59:59.000Z

    In various embodiments, electronic devices containing switchably conductive silicon oxide as a switching element are described herein. The electronic devices are two-terminal devices containing a first electrical contact and a second electrical contact in which at least one of the first electrical contact or the second electrical contact is deposed on a substrate to define a gap region therebetween. A switching layer containing a switchably conductive silicon oxide resides in the the gap region between the first electical contact and the second electrical contact. The electronic devices exhibit hysteretic current versus voltage properties, enabling their use in switching and memory applications. Methods for configuring, operating and constructing the electronic devices are also presented herein.

  14. Optimization of transparent and reflecting electrodes for amorphous silicon solar cells. Annual technical report, April 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Gordon, R.G.; Sato, H.; Liang, H.; Liu, X.; Thornton, J. [Harvard Univ., Cambridge, MA (United States)

    1996-08-01T23:59:59.000Z

    The general objective is to develop methods to deposit materials which can be used to make more efficient solar cells. The work is organized into three general tasks: Task 1. Develop improved methods for depositing and using transparent conductors of fluorine-doped zinc oxide in amorphous silicon solar cells Task 2. Deposit and evaluate titanium oxide as a reflection-enhancing diffusion barrier between amorphous silicon and an aluminum or silver back-reflector. Task 3. Deposit and evaluate electrically conductive titanium oxide as a transparent conducting layer on which more efficient and more stable superstrate cells can be deposited. About one-third of the current project resources are allocated to each of these three objectives.

  15. Optimization of transparent and reflecting electrodes for amorphous silicon solar cells. Annual subcontract report, April 1, 1994--March 31, 1995

    SciTech Connect (OSTI)

    Gordon, R.G. [Harvard Univ., Cambridge, MA (United States)

    1995-10-01T23:59:59.000Z

    Transparent and reflecting electrodes are important parts of the structure of amorphous silicon solar cells. We report improved methods for depositing zinc oxide, deposition of tin nitride as a potential reflection-enhancing diffusion barrier between the a-Si and back metal electrodes. Highly conductive and transparent fluorine-doped zinc oxide was successfully produced on small areas by atmospheric pressure CVD from a less hazardous zinc precursor, zinc acetylacetonate. The optical properties measured for tin nitride showed that the back-reflection would be decreased if tin nitride were used instead of zinc oxide as a barrier layer over silver on aluminum. Niobium-doped titanium dioxide was produced with high enough electrical conductivity so that normal voltages and fill factors were obtained for a-Si cells made on it.

  16. Self-templated synthesis and thermal conductivity investigation for ultrathin perovskite oxide nanowires

    E-Print Network [OSTI]

    Ruan, Xiulin

    conductivity of the bulk pellet made by compressing nanowire powder using spark plasma sintering shows a 64 conductivity of the bulk pellet fabricated by compressing these SrTiO3 nanowire powder using spark plasma sintering can be reduced by 64% at 1000 K. The self-templated synthesis approach involves two steps that can

  17. Modeling and simulation of Li-ion conduction in poly(ethylene oxide)

    E-Print Network [OSTI]

    Averbuch, Amir

    rechargeable batteries for consumer portable applications. A lithium-ion battery employs a metal oxide/discharge voltage depends on the current and resistance of all battery components. In most solid-state lithium-ion of Computational Physics 227 (2007) 1162­1175 www.elsevier.com/locate/jcp #12;1. Introduction Lithium and lithium-ion

  18. Oxide Electronic Conductivity and Hydrogen Pickup Fraction in Zr alloys Adrien Coueta

    E-Print Network [OSTI]

    Motta, Arthur T.

    and instantaneous hydrogen pickup fractions was measured using in-situ Electrochemical Impedance Spectroscopy (EIS it with the observed hydrogen pickup fraction variations. In-Situ Electrochemical Impedance Spectroscopy Impedance-up and oxide growth were precisely measured as a function of exposure time in an autoclave for a set

  19. Electrical and thermal conductivities of reduced graphene oxide/polystyrene Wonjun Park, Jiuning Hu, Luis A. Jauregui, Xiulin Ruan, and Yong P. Chen

    E-Print Network [OSTI]

    Chen, Yong P.

    conductive polymer composites are used as heat sinks for device packaging requiring a high thermalElectrical and thermal conductivities of reduced graphene oxide/polystyrene composites Wonjun Park. The electrical conductivity (r) of RGO/PS composites with different RGO concentrations at room temperature shows

  20. Graphene oxide based conductive glue as a binder for ultracapacitor Jiayan Luo,a

    E-Print Network [OSTI]

    Huang, Jiaxing

    nanoparticle based ultracapacitors. Since the functional nanoparticles are immersed in this conductive gel is mainly functionalized by carboxylic acid groups.8,9 Therefore, GO can be viewed as an unconventional type

  1. Method of depositing an electrically conductive oxide buffer layer on a textured substrate and articles formed therefrom

    DOE Patents [OSTI]

    Paranthaman, M. Parans; Aytug, Tolga; Christen, David K.

    2005-10-18T23:59:59.000Z

    An article with an improved buffer layer architecture includes a substrate having a textured metal surface, and an electrically conductive lanthanum metal oxide epitaxial buffer layer on the surface of the substrate. The article can also include an epitaxial superconducting layer deposited on the epitaxial buffer layer. An epitaxial capping layer can be placed between the epitaxial buffer layer and the superconducting layer. A method for preparing an epitaxial article includes providing a substrate with a metal surface and depositing on the metal surface a lanthanum metal oxide epitaxial buffer layer. The method can further include depositing a superconducting layer on the epitaxial buffer layer, and depositing an epitaxial capping layer between the epitaxial buffer layer and the superconducting layer.

  2. Method of depositing an electrically conductive oxide buffer layer on a textured substrate and articles formed therefrom

    DOE Patents [OSTI]

    Paranthaman, M. Parans; Aytug, Tolga; Christen, David K.

    2003-09-09T23:59:59.000Z

    An article with an improved buffer layer architecture includes a substrate having a textured metal surface, and an electrically conductive lanthanum metal oxide epitaxial buffer layer on the surface of the substrate. The article can also include an epitaxial superconducting layer deposited on the epitaxial buffer layer. An epitaxial capping layer can be placed between the epitaxial buffer layer and the superconducting layer. A method for preparing an epitaxial article includes providing a substrate with a metal surface and depositing on the metal surface a lanthanum metal oxide epitaxial buffer layer. The method can further include depositing a superconducting layer on the epitaxial buffer layer, and depositing an epitaxial capping layer between the epitaxial buffer layer and the superconducting layer.

  3. Investigation of zinc oxide doped with metal impurities for use as thin film conductive phosphors

    E-Print Network [OSTI]

    Evatt, Steven R.

    1994-01-01T23:59:59.000Z

    . Illustration of planar field emission diode developed by Weichold et al. . . . . . 48 Fig. 29. I-V data from vacuum field emission light emitting diode structure, after Williams, 1994. . . . . . . . . . 49 Fig. 30. Illustration of the oxidized porous silicon... carriers into a forward biased p-n junction will result in light emission if radiative transitions take place [3]. These semiconductors find applications in light emitting diodes. Other phosphors will produce light emission when they are placed...

  4. Fabrication of transparent ceramics using nanoparticles

    DOE Patents [OSTI]

    Cherepy, Nerine J; Tillotson, Thomas M; Kuntz, Joshua D; Payne, Stephen A

    2012-09-18T23:59:59.000Z

    A method of fabrication of a transparent ceramic using nanoparticles synthesized via organic acid complexation-combustion includes providing metal salts, dissolving said metal salts to produce an aqueous salt solution, adding an organic chelating agent to produce a complexed-metal sol, heating said complexed-metal sol to produce a gel, drying said gel to produce a powder, combusting said powder to produce nano-particles, calcining said nano-particles to produce oxide nano-particles, forming said oxide nano-particles into a green body, and sintering said green body to produce the transparent ceramic.

  5. Thickness influence on surface morphology and ozone sensing properties of nanostructured ZnO transparent

    E-Print Network [OSTI]

    , 71004 Heraklion, Crete, Greece Available online 19 January 2006 Abstract Transparent zinc oxide (Zn Keywords: Zinc oxide; PLD; AFM; Ozone 1. Introduction Zinc oxide (ZnO) is an n-type semiconductor devices [3], varistors, planar optical waveguides [4], transparent electrodes [5,6], ultraviolet

  6. Efficient Electro-Optical Modulation Based on Indium Tin Oxide

    E-Print Network [OSTI]

    Shi, Kaifeng

    2015-01-01T23:59:59.000Z

    We experimentally demonstrate several electro-optical modulators based on transparent conducting oxides. Our previous work demonstrated the modulator structure on glass substrate with broadband bias polarity-dependent modulation. Further exploration shows similar modulation effect of the modulator on quartz and silicon substrate.

  7. Use of impure inert gases in the controlled heating and cooling of mixed conducting metal oxide materials

    DOE Patents [OSTI]

    Carolan, Michael Francis (Allentown, PA); Bernhart, John Charles (Fleetwood, PA)

    2012-08-21T23:59:59.000Z

    Method for processing an article comprising mixed conducting metal oxide material. The method comprises contacting the article with an oxygen-containing gas and either reducing the temperature of the oxygen-containing gas during a cooling period or increasing the temperature of the oxygen-containing gas during a heating period; during the cooling period, reducing the oxygen activity in the oxygen-containing gas during at least a portion of the cooling period and increasing the rate at which the temperature of the oxygen-containing gas is reduced during at least a portion of the cooling period; and during the heating period, increasing the oxygen activity in the oxygen-containing gas during at least a portion of the heating period and decreasing the rate at which the temperature of the oxygen-containing gas is increased during at least a portion of the heating period.

  8. High Temperature Oxidation Resistance and Surface Electrical Conductivity of Stainless Steels with Filtered Arc Cr-Al-N Multilayer and/or Superlattice Coatings

    SciTech Connect (OSTI)

    Gannon, Paul E.; Tripp, C.; Knospe, Anders; Ramana, C. V.; Deibert, Max; Smith, Richard J.; Gorokhovsky, Vladimir I.; Shutthanandan, V.; Gelles, David S.

    2004-11-01T23:59:59.000Z

    The requirements for low cost and high-tempurater corrosion resistance for bipolar interconnect plates in solid oxide fuel cell (SOFC) stacks has directed attention to the use of metal plates with oxidation resistant coatings. Candidate coatings must exhibit chemical and thermal-mechanical stability and high electrical conductivity during long-term (>400,000 hrs) exposure to SOFC operatong conditions. The high temperature oxidation resistance and surface electrical donductivity of 304, 440A,a dn Crofer-22 APU steel coupons, with and without multilayer and/or superlattice coatings from a Cr-Al-N system were investigated as a function of exposure in an oxidization atmosphere at high temperatures. The coatins were deposited using large area filtered arc depsition (LAFAD) technology [1], and subsequently annealed in air at 800 degrees C for varying times. Area specific resistance and activation energy for electrical conductivity of oxidized coupons were measured using a 4-point technique with Pt paste for electrical contact between facing oxidized coupon surfaces. The surface compositon, structure and morphology of the coupons were characterized using RBS, nuclear reaction analysis, XPS, SEM, and AFM techniques. The structure of the CRN/CrAlN multilayered superlattice coatings was characterized by TEM. By altering the architecture of the coating layers, both surface electrical conductivity and oxidation resistance [2] improved signigicantly for some of the coated samples tested up to ~100hrs.

  9. Spatial dependence of polycrystalline FTO’s conductance analyzed by conductive atomic force microscope (C-AFM)

    SciTech Connect (OSTI)

    Peixoto, Alexandre Pessoa; Costa, J. C. da [Department of Electrical Engineering, University of Brasília, Campus Universitário Darcy Ribeiro, Asa Norte, PO Box 4386, Brasília - DF, 70919-970 (Brazil)

    2014-05-15T23:59:59.000Z

    Fluorine-doped Tin oxide (FTO) is a highly transparent, electrically conductive polycrystalline material frequently used as an electrode in organic solar cells and optical-electronic devices [1–2]. In this work a spatial analysis of the conductive behavior of FTO was carried out by Conductive-mode Atomic Force Microscopy (C-AFM). Rare highly oriented grains sample give us an opportunity to analyze the top portion of polycrystalline FTO and compare with the border one. It is shown that the current flow essentially takes place through the polycrystalline edge at grain boundaries.

  10. Flexible and Transparent Memory

    E-Print Network [OSTI]

    KIM, SUNG MIN

    2012-01-01T23:59:59.000Z

    H. Seo and K. L. Wang. , “Flexible and Transparent Memory”2] S. Kim and J. Lee “Flexible Organic Transistor MemoryMemory Transistors for Flexible Sensor Arrays” Science, Vol.

  11. Supersymmetric transparent optical intersections

    E-Print Network [OSTI]

    Stefano Longhi

    2015-01-09T23:59:59.000Z

    Supersymmetric (SUSY) optical structures provide a versatile platform to manipulate the scattering and localization properties of light, with potential applications to mode conversion, spatial multiplexing and invisible devices. Here we show that SUSY can be exploited to realize broadband transparent intersections between guiding structures in optical networks for both continuous and discretized light. These include transparent crossing of high-contrast-index waveguides and directional couplers, as well as crossing of guiding channels in coupled resonator lattices.

  12. List of Journal Publications (updated April 2014) R. Justin, B. Chen*: Strong and conductive polymer-reduced graphene oxide

    E-Print Network [OSTI]

    Ojovan, Michael

    polymer-reduced graphene oxide nanocomposites for transdermal drug deliveyr. Journal of Materials*: Characterisation and drug release performance of biodegradable chitosan-graphene oxide nanocomposites. Carbohydrate Polymers. 2014, 103, 70-80. · R. Justin, B. Chen*: Body temperature reduction of graphene oxide through

  13. Application of Single Wall Carbon Nanotubes as Transparent Electrodes in Cu(In,Ga)Se2-Based Solar Cells: Preprint

    SciTech Connect (OSTI)

    Contreras, M.; Barnes, T.; van de Lagemaat, J.; Rumbles, G.; Coutts, T. J.; Weeks, C.; Glatkowski, P.; Levitsky, I.; Peltola, J.

    2006-05-01T23:59:59.000Z

    We present a new thin-film solar cell structure in which the traditional transparent conductive oxide electrode (ZnO) is replaced by a transparent conductive coating consisting of a network of bundled single-wall carbon nanotubes. Optical transmission properties of these coatings are presented in relation to their electrical properties (sheet resistance), along with preliminary solar cell results from devices made using CuIn1-xGaxSe2 thin-film absorber materials. Achieving an energy conversion efficiency of >12% and a quantum efficiency of {approx}80% demonstrate the feasibility of the concept. A discussion of the device structures will be presented considering the physical properties of the new electrodes comparing current-voltage results from the new solar cell structure and those from standard ZnO/CdS/Cu(In,Ga)Se2/Mo solar cells.

  14. Transparent Cost Database | Transparent Cost Database

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown of Ladoga, Indiana (Utility Company)Library < TransmissionTransparent

  15. Remarkable Thermal Stability of Amorphous In-Zn-O Transparent Conductors

    SciTech Connect (OSTI)

    Taylor, M. P.; Readey, D. W.; van Hest, M. F. A. M.; Teplin, C. W.; Alleman, J. L.; Dabney, M. S.; Gedvilas, L. M.; Keyes, B. M.; To, B.; Perkins, J. D.; Ginley, D. S.

    2008-10-01T23:59:59.000Z

    Transparent conducting oxides (TCOs) are increasingly critical components in photovoltaic cells, low-e windows, flat panel displays, electrochromic devices, and flexible electronics. The conventional TCOs, such as Sn-doped In{sub 2}O{sub 3}, are crystalline single phase materials. Here, we report on In-Zn-O (IZO), a compositionally tunable amorphous TCO with some significantly improved properties. Compositionally graded thin film samples were deposited by co-sputtering from separate In{sub 2}O{sub 3} and ZnO targets onto glass substrates at 100 C. For the metals composition range of 55-84 cation% indium, the as-deposited IZO thin films are amorphous, smooth (R{sub RMS} < 0.4 nm), conductive ({sigma} {approx} 3000 {Omega}{sup -1} {center_dot} cm{sup -1}), and transparent in the visible (T{sub Vis} > 90%). Furthermore, the amorphous IZO thin films demonstrate remarkable functional and structural stability with respect to heating up to 600 C in either air or argon. Hence, though not completely understood at present, these amorphous materials constitute a new class of fundamentally interesting and technologically important high performance transparent conductors.

  16. Final Technical Report CONDUCTIVE COATINGS FOR SOLAR CELLS USING CARBON NANOTUBES

    SciTech Connect (OSTI)

    Paul J Glatkowski; Jorma Peltola; Christopher Weeks; Mike Trottier; David Britz

    2007-09-30T23:59:59.000Z

    US Department of Energy (DOE) awarded a grant for Eikos Inc. to investigate the feasibility of developing and utilizing Transparent Conducting Coatings (TCCs) based on carbon nanotubes (CNT) for solar cell applications. Conventional solar cells today employ metal oxide based TCCs with both Electrical Resistivity (R) and Optical Transparency (T), commonly referred to as optoelectronic (RT) performance significantly higher than with those possible with CNT based TCCs available today. Transparent metal oxide based coatings are also inherently brittle requiring high temperature in vacuum processing and are thus expensive to manufacture. One such material is indium tin oxide (ITO). Global demand for indium has recently increased rapidly while supply has diminished causing substantial spikes in raw material cost and availability. In contrast, the raw material, carbon, needed for CNT fabrication is abundantly available. Transparent Conducting Coatings based on CNTs can overcome not only cost and availability constraints while also offering the ability to be applied by existing, low cost process technologies under ambient conditions. Processes thus can readily be designed both for rigid and flexible PV technology platforms based on mature spray or dip coatings for silicon based solar cells and continuous roll to roll coating processes for polymer solar applications.

  17. 335Nanostructured ZnO and ZAO transparent thin films by sputteringsurface characterization Corresponding author: M. Suchea, e-mail: mirasuchea@iesl.forth.gr

    E-Print Network [OSTI]

    as transparent electrode in solar cells and flat panel displays as well as for the fabrication of gratings Abstract. Zinc oxide (ZnO) and aluminum zinc oxide (ZAO) transparent thin films with different thickness Zinc oxide is one of the earliest discovered metal oxide gas sensing materials. It is an n-type semi

  18. Product Information Transparent

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    , transformers, amplifiers, high voltage resistor packs, and relays; adhesive/encapsulant for solar cellsProduct Information Solar FEATURES · Transparent · Cures to flexible elastomer · Constant cure rate elastomer, which is suited for the protection of electrical/electronic devices in solar applications. HOW

  19. A new architecture as transparent electrodes for solar and IR applications based on photonic structures via soft lithography

    SciTech Connect (OSTI)

    Kuang, Ping

    2011-05-15T23:59:59.000Z

    Transparent conducting electrodes with the combination of high optical transmission and good electrical conductivity are essential for solar energy harvesting and electric lighting devices. Currently, indium tin oxide (ITO) is used because ITO offers relatively high transparency (>80%) to visible light and low sheet resistance (R{sub s} = 10 ohms/square ({Omega}#2;/?)) for electrical conduction. However, ITO is costly due to limited indium reserves, and it is brittle. These disadvantages have motivated the search for other conducting electrodes with similar or better properties. There has been research on a variety of electrode structures involving carbon nanotube networks, graphene films, nanowire and nanopatterned meshes and grids. Due to their novel characteristics in light manipulation and collection, photonic crystal structures show promise for further improvement. Here, we report on a new architecture consisting of nanoscale high aspect ratio metallic photonic structures as transparent electrodes fabricated via a combination of processes. For (Au) and silver (Ag) structures, the visible light transmission can reach as high as 80%, and the sheet resistance of the structure can be as low as 3.2{Omega}#2;/?. The optical transparency of the high aspect ratio metal structures at visible wavelength range is comparable to that of ITO glass, while their sheet resistance is more than 3 times lower, which indicates a much higher electrical conductivity of the metal structures. Furthermore, the high aspect ratio metal structures have very high infrared (IR) reflection (90%) for the transverse magnetic (TM) mode, which can lead to the development of fabrication of metallic structures as IR filters for heat control applications. Investigations of interdigitated structures based on the high aspect ratio metal electrodes are ongoing to study the feasibility in smart window applications in light transmission modulation.

  20. Obtaining Mixed Ionic/Electronic Conductivity in Perovskite Oxides in a Reducing Environment: A Computational Prediction for Doped SrTiO3

    SciTech Connect (OSTI)

    Suthirakun, Suwit; Ammal, Salai Cheettu; Xiao, Guoliang; Chen, Fanglin; Huang, Kevin; zur Loye, Hans-Conrad; Heyden, Andreas

    2012-11-30T23:59:59.000Z

    The electronic conductivity and thermodynamic stability of mixed p- and n-doped SrTiO3 perovskites have been investigated under anodic solid oxide fuel cell conditions using density functional theory (DFT). In particular, constrained ab initio thermodynamic calculations have been performed to evaluate the phase stability of various Ga- and La-doped SrTiO3 at synthesized and anodic SOFC conditions. The density of states (DOS) of these materials was analyzed to determine the number of charge carriers and the degree of electronic conductivity. We find that a mixed ionic/electronic conductor can be obtained when doping SrTiO3 perovskite oxide with both p-type and n-type dopants. Calculations show that 10% Ga- and 20% La-doped SrTiO3 exhibit mixed ionic/electronic conductivity at high temperature and low oxygen partial pressure whereas doping with higher concentrations of Ga, e.g., 20%, diminishes the electronic conductivity of the material. Furthermore, changing the n-dopant from La (A-site) to Nb (B-site) does not significantly affect the reducibility and number of charge carriers in p- and n-doped SrTiO3. However, a higher degree of oxygen vacancy clustering is observed for the La-doped material which reduces the oxygen ion diffusion rate and traps electrons. Nevertheless, our findings suggest that independent of doping site, mixed ionic/ electronic conductivity can be obtained in SrTiO3 perovskite oxides under reducing conditions and high temperatures when using a mixed p- and n-type doping strategy that uses a p-dopant concentration smaller than the n-dopant concentration.

  1. Development of hybrid organic-inorganic light emitting diodes using conducting polymers deposited by oxidative chemical vapor deposition process

    E-Print Network [OSTI]

    Chelawat, Hitesh

    2010-01-01T23:59:59.000Z

    Difficulties with traditional methods of synthesis and film formation for conducting polymers, many of which are insoluble, motivate the development of CVD methods. Indeed, conjugated polymers with rigid linear backbones ...

  2. 2011 Annual Health Physics Report for the HEU transparency Program

    SciTech Connect (OSTI)

    Radev, R

    2012-04-30T23:59:59.000Z

    During the 2008 calendar year, Lawrence Livermore National Laboratory (LLNL) provided health physics support for the Highly Enriched Uranium (HEU) Transparency Program for external and internal radiation protection. They also provided technical expertise related to BDMS radioactive sources and Russian radiation safety regulatory compliance. For the calendar year 2008, there were 158 person-trips that required dose monitoring of the U.S. monitors. Of the 158 person-trips, 148 person-trips were SMVs and 10 person-trips were Transparency Monitoring Office (TMO) trips. There were 6 monitoring visits by TMO monitors to facilities other than UEIE and 8 to UEIE itself. There were three monitoring visits (source changes) that were back-to-back with a total of 24 monitors. LLNL's Hazard Control Department laboratories provided the dosimetry services for the HEU Transparency monitors. In 2008, the HEU Transparency activities in Russia were conducted in a radiologically safe manner for the HEU Transparency monitors in accordance with the expectations of the HEU Transparency staff, NNSA and DOE. The HEU Transparency now has thirteen years of successful experience in developing and providing health and safety support in meeting its technical objectives.

  3. Transparent fluids for 157-nm immersion lithography

    E-Print Network [OSTI]

    Rollins, Andrew M.

    Lawrence, Massachusetts 01843 Abstract. More than 50 fluorocarbon liquids are measured for transpar- ency; transpar- ency; fluorocarbon; fluoroether. Paper 014013 received Aug. 4, 2003; revised manuscript received

  4. Carrier dynamics in bulk ZnO. I. Intrinsic conductivity measured by terahertz time-domain spectroscopy

    E-Print Network [OSTI]

    at room temperature.3 Thin films of ZnO are useful in transparent transistors and transparent conducting coatings because of their combination of wide band gap, high conductivity, and processability.4

  5. Transparent Conductive Nano-Composites - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2, 2003Tool ofTopoCarbon|default SignofDSOSolar

  6. Enhancement of conduction noise absorption by hybrid absorbers composed of indium-tin-oxide thin film and magnetic composite sheet on a microstrip line

    SciTech Connect (OSTI)

    Kim, Sun-Hong; Kim, Sung-Soo, E-mail: sskim@chungbuk.ac.kr [Department of Advanced Materials Engineering, Chungbuk National University, Cheongju 361-763 (Korea, Republic of)

    2014-05-05T23:59:59.000Z

    In order to develop wide-band noise absorbers with a focused design for low frequency performance, this study investigates hybrid absorbers that are composed of conductive indium-tin-oxide (ITO) thin film and magnetic composite sheets. The ITO films prepared via reactive sputtering exhibit a typical value of electrical resistivity of ?10{sup ?4} ? m. Rubber composites with flaky Fe-Si-Al particles are used as the magnetic sheet with a high permeability and high permittivity. For the ITO film with a low surface resistance and covered by the magnetic sheet, approximately 90% power absorption can be obtained at 1?GHz, which is significantly higher than that of the original magnetic sheet or ITO film. The high power absorption of the hybrid absorber is attributed to the enhanced ohmic loss of the ITO film through increased electric field strength bounded by the upper magnetic composite sheet. However, for the reverse layering sequence of the ITO film, the electric field experienced by ITO film is very weak due to the electromagnetic shielding by the under layer of magnetic sheet, which does not result in enhanced power absorption.

  7. Lithium intercalation in sputter deposited antimony-doped tin oxide thin films: Evidence from electrochemical and optical measurements

    SciTech Connect (OSTI)

    Montero, J., E-mail: jose.montero@angstrom.uu.se; Granqvist, C. G.; Niklasson, G. A. [Department of Engineering Sciences, The A°ngström Laboratory, Uppsala University, P.O. Box 534, SE-751 21 Uppsala (Sweden); Guillén, C.; Herrero, J. [Department of Energy, Ciemat, Avda. Complutense 40, Ed. 42, E-28040 Madrid (Spain)

    2014-04-21T23:59:59.000Z

    Transparent conducting oxides are used as transparent electrical contacts in a variety of applications, including in electrochromic smart windows. In the present work, we performed a study of transparent conducting antimony-doped tin oxide (ATO) thin films by chronopotentiometry in a Li{sup +}-containing electrolyte. The open circuit potential vs. Li was used to investigate ATO band lineups, such as those of the Fermi level and the ionization potential, as well as the dependence of these lineups on the preparation conditions for ATO. Evidence was found for Li{sup +} intercalation when a current pulse was set in a way so as to drive ions from the electrolyte into the ATO lattice. Galvanostatic intermittent titration was then applied to determine the lithium diffusion coefficient within the ATO lattice. The electrochemical density of states of the conducting oxide was studied by means of the transient voltage recorded during the chronopotentiometry experiments. These measurements were possible because, as Li{sup +} intercalation took place, charge compensating electrons filled the lowest part of the conduction band in ATO. Furthermore, the charge insertion modified the optical properties of ATO according to the Drude model.

  8. Transparent self-cleaning dust shield

    DOE Patents [OSTI]

    Mazumder, Malay K.; Sims, Robert A.; Wilson, James D.

    2005-06-28T23:59:59.000Z

    A transparent electromagnetic shield to protect solar panels and the like from dust deposition. The shield is a panel of clear non-conducting (dielectric) material with embedded parallel electrodes. The panel is coated with a semiconducting film. Desirably the electrodes are transparent. The electrodes are connected to a single-phase AC signal or to a multi-phase AC signal that produces a travelling electromagnetic wave. The electromagnetic field produced by the electrodes lifts dust particles away from the shield and repels charged particles. Deposited dust particles are removed when the electrodes are activated, regardless of the resistivity of the dust. Electrostatic charges on the panel are discharged by the semiconducting film. When used in conjunction with photovoltaic cells, the power for the device may be obtained from the cells themselves. For other surfaces, such as windshields, optical windows and the like, the power must be derived from an external source. One embodiment of the invention employs monitoring and detection devices to determine when the level of obscuration of the screen by dust has reached a threshold level requiring activation of the dust removal feature.

  9. Electrically conductive diamond electrodes

    DOE Patents [OSTI]

    Swain, Greg (East Lansing, MI); Fischer, Anne (Arlington, VA),; Bennett, Jason (Lansing, MI); Lowe, Michael (Holt, MI)

    2009-05-19T23:59:59.000Z

    An electrically conductive diamond electrode and process for preparation thereof is described. The electrode comprises diamond particles coated with electrically conductive doped diamond preferably by chemical vapor deposition which are held together with a binder. The electrodes are useful for oxidation reduction in gas, such as hydrogen generation by electrolysis.

  10. Electrochromism in copper oxide thin films

    SciTech Connect (OSTI)

    Richardson, T.J.; Slack, J.L.; Rubin, M.D.

    2000-08-15T23:59:59.000Z

    Transparent thin films of copper(I) oxide prepared on conductive SnO2:F glass substrates by anodic oxidation of sputtered copper films or by direct electrodeposition of Cu2O transformed reversibly to opaque metallic copper films when reduced in alkaline electrolyte. In addition, the same Cu2O films transform reversibly to black copper(II) oxide when cycled at more anodic potentials. Copper oxide-to-copper switching covered a large dynamic range, from 85% and 10% photopic transmittance, with a coloration efficiency of about 32 cm2/C. Gradual deterioration of the switching range occurred over 20 to 100 cycles. This is tentatively ascribed to coarsening of the film and contact degradation caused by the 65% volume change on conversion of Cu to Cu2O. Switching between the two copper oxides (which have similar volumes) was more stable and more efficient (CE = 60 cm2/C), but covered a smaller transmittance range (60% to 44% T). Due to their large electrochemical storage capacity and tolerance for alkaline electrolytes, these cathodically coloring films may be useful as counter electrodes for anodically coloring electrode films such as nickel oxide or metal hydrides.

  11. Transparent lithium-ion batteries , Sangmoo Jeongb

    E-Print Network [OSTI]

    Cui, Yi

    voltage window. For example, LiCoO2 and graphite, the most common cathode and anode in Li-ion batteriesTransparent lithium-ion batteries Yuan Yanga , Sangmoo Jeongb , Liangbing Hua , Hui Wua , Seok Woo, and solar cells; however, transparent batteries, a key component in fully integrated transparent devices

  12. The efficiency of depth discrimination for non-transparent and transparent stereoscopic surfaces

    E-Print Network [OSTI]

    Mamassian, Pascal

    The efficiency of depth discrimination for non-transparent and transparent stereoscopic surfaces investigate here how well human observers cope with stereo transparency by comparing their efficiency between transparent and opaque depth judgments. In two experiments, the efficiency measure was computed relative

  13. Electrode with transparent series resistance for uniform switching of optical modulation devices

    SciTech Connect (OSTI)

    Tench, D. Morgan (Camarillo, CA); Cunningham, Michael A. (Thousand Oaks, CA); Kobrin, Paul H. (Newbury Park, CA)

    2008-01-08T23:59:59.000Z

    Switching uniformity of an optical modulation device for controlling the propagation of electromagnetic radiation is improved by use of an electrode comprising an electrically resistive layer that is transparent to the radiation. The resistive layer is preferably an innerlayer of a wide-bandgap oxide sandwiched between layers of indium tin oxide or another transparent conductor, and may be of uniform thickness, or may be graded so as to provide further improvement in the switching uniformity. The electrode may be used with electrochromic and reversible electrochemical mirror (REM) smart window devices, as well as display devices based on various technologies.

  14. Energy dependence of color transparency

    SciTech Connect (OSTI)

    Jennings, B.K. (TRIUMF, 4004 Wesbrook Mall, Vancouver, British Columbia, Canada V6T 2A3 (CA) Institute for Nuclear Theory, HN-12, University of Washington, Seattle, WA (USA)); Miller, G.A. (Department of Physics, FM-15, University of Washington, Seattle, WA (USA) Institute for Nuclear Theory, HN-12, University of Washington, Seattle, WA (USA))

    1991-08-01T23:59:59.000Z

    A quantum-mechanical approach is used to study high-momentum-transfer reactions in which a nucleon is knocked out of a target nucleus. It is found that the nuclear interactions of the wave packet produced in such a hard interaction may cancel, so that the nuclear medium is transparent. Expressions for the effective wave-packet--nucleon interaction and the corresponding distorted waves are presented. An analysis of existing ({ital p},{ital pp}) data at beam momenta from about 5 to 12 GeV/{ital c} suggests that only the nucleon and Roper resonance components of the wave packet contribute to the scattering amplitude. The ({ital p},{ital pp}) data and our theory imply that color-transparency effects in the ({ital e},{ital e}{prime}{ital p}) reaction may be significant at relatively low-momentum transfers of {ital Q}{sup 2}{approx}3--6 GeV{sup 2}.

  15. Transparent electrode for optical switch

    DOE Patents [OSTI]

    Goldhar, J.; Henesian, M.A.

    1984-10-19T23:59:59.000Z

    The invention relates generally to optical switches and techniques for applying a voltage to an electro-optical crystal, and more particularly, to transparent electodes for an optical switch. System architectures for very large inertial confinement fusion (ICF) lasers require active optical elements with apertures on the order of one meter. Large aperture optical switches are needed for isolation of stages, switch-out from regenerative amplifier cavities and protection from target retroreflections.

  16. Spectroscopic Characterization of a Multiband Complex Oxide:...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a Multiband Complex Oxide: Insulating and Conducting Cement 12CaO·7AlO. Spectroscopic Characterization of a Multiband Complex Oxide: Insulating and Conducting Cement...

  17. Electronic Durability of Flexible Transparent Films from Type-Specific Single-Wall Carbon Nanotubes

    SciTech Connect (OSTI)

    Harris, J; Iyer, S; Bernhardt, A; Huh, JY; Hudson, S; Fagan, J; Hobbie, E.

    2011-12-11T23:59:59.000Z

    The coupling between mechanical flexibility and electronic performance is evaluated for thin films of metallic and semiconducting single-wall carbon nanotubes (SWCNTs) deposited on compliant supports. Percolated networks of type-purified SWCNTs are assembled as thin conducting coatings on elastic polymer substrates, and the sheet resistance is measured as a function of compression and cyclic strain through impedance spectroscopy. The wrinkling topography, microstructure and transparency of the films are independently characterized using optical microscopy, electron microscopy, and optical absorption spectroscopy. Thin films made from metallic SWCNTs show better durability as flexible transparent conductive coatings, which we attribute to a combination of superior mechanical performance and higher interfacial conductivity.

  18. NREL scientists develop robust, high-performance IZO transparent contact for CIGS solar cells.

    E-Print Network [OSTI]

    NREL scientists develop robust, high-performance IZO transparent contact for CIGS solar cells indium gallium diselenide (CIGS) solar cell is zinc oxide (ZnO). The problem is that unprotected Zn is a lifetime-limiting problem that is currently addressed solely through encapsulation. Fundamentally improving

  19. Three-terminal resistive switching memory in a transparent vertical-configuration device

    SciTech Connect (OSTI)

    Ungureanu, Mariana; Llopis, Roger [CIC nanoGUNE Consolider, Donostia - San Sebastian (Spain)] [CIC nanoGUNE Consolider, Donostia - San Sebastian (Spain); Casanova, Fèlix; Hueso, Luis E. [CIC nanoGUNE Consolider, Donostia - San Sebastian (Spain) [CIC nanoGUNE Consolider, Donostia - San Sebastian (Spain); Ikerbasque, Basque Foundation for Science, Bilbao (Spain)

    2014-01-06T23:59:59.000Z

    The resistive switching phenomenon has attracted much attention recently for memory applications. It describes the reversible change in the resistance of a dielectric between two non-volatile states by the application of electrical pulses. Typical resistive switching memories are two-terminal devices formed by an oxide layer placed between two metal electrodes. Here, we report on the fabrication and operation of a three-terminal resistive switching memory that works as a reconfigurable logic component and offers an increased logic density on chip. The three-terminal memory device we present is transparent and could be further incorporated in transparent computing electronic technologies.

  20. New York City Benchmarking and Transparency Policy Impact Evaluation...

    Energy Savers [EERE]

    New York City Benchmarking and Transparency Policy Impact Evaluation Report New York City Benchmarking and Transparency Policy Impact Evaluation Report Prepared for the U.S....

  1. Sandia National Laboratories: electronic conducting transition...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electronic conducting transition metal oxides Joint Hire Increases Materials Science Collaboration for Sandia, UNM On September 16, 2014, in Advanced Materials Laboratory,...

  2. Properties of thin film europium oxide by x-ray magnetic circular dichroism Johnathon Holroyda)

    E-Print Network [OSTI]

    Idzerda, Yves

    Properties of thin film europium oxide by x-ray magnetic circular dichroism Johnathon Holroyda Institute of Physics. DOI: 10.1063/1.1688653 I. INTRODUCTION Europium oxide is optically transparent

  3. Atomic-Layer-Deposited Transparent Electrodes for Silicon Heterojunction Solar Cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Demaurex, Benedicte; Seif, Johannes P.; Smit, Sjoerd; Macco, Bart; Kessels, W. M.; Geissbuhler, Jonas; De Wolf, Stefaan; Ballif, Christophe

    2014-11-01T23:59:59.000Z

    We examine damage-free transparent-electrode deposition to fabricate high-efficiency amorphous silicon/crystalline silicon heterojunction solar cells. Such solar cells usually feature sputtered transparent electrodes, the deposition of which may damage the layers underneath. Using atomic layer deposition, we insert thin protective films between the amorphous silicon layers and sputtered contacts and investigate their effect on device operation. We find that a 20-nm-thick protective layer suffices to preserve, unchanged, the amorphous silicon layers beneath. Insertion of such protective atomic-layer-deposited layers yields slightly higher internal voltages at low carrier injection levels. However, we identify the presence of a silicon oxide layer, formed during processing,more »between the amorphous silicon and the atomic-layer-deposited transparent electrode that acts as a barrier, impeding hole and electron collection.« less

  4. Atomic-Layer-Deposited Transparent Electrodes for Silicon Heterojunction Solar Cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Demaurex, Benedicte; Seif, Johannes P.; Smit, Sjoerd; Macco, Bart; Kessels, W. M.; Geissbuhler, Jonas; De Wolf, Stefaan; Ballif, Christophe

    2014-11-01T23:59:59.000Z

    We examine damage-free transparent-electrode deposition to fabricate high-efficiency amorphous silicon/crystalline silicon heterojunction solar cells. Such solar cells usually feature sputtered transparent electrodes, the deposition of which may damage the layers underneath. Using atomic layer deposition, we insert thin protective films between the amorphous silicon layers and sputtered contacts and investigate their effect on device operation. We find that a 20-nm-thick protective layer suffices to preserve, unchanged, the amorphous silicon layers beneath. Insertion of such protective atomic-layer-deposited layers yields slightly higher internal voltages at low carrier injection levels. However, we identify the presence of a silicon oxide layer, formed during processing, between the amorphous silicon and the atomic-layer-deposited transparent electrode that acts as a barrier, impeding hole and electron collection.

  5. Scientists produce transparent, light-harvesting material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    light-harvesting material The material could be used in development of transparent solar panels. November 3, 2010 Los Alamos National Laboratory sits on top of a once-remote...

  6. Microsoft Word - Net Requirements Transparency Process_09302014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 As part of its Net Requirements Transparency process, on July 31, 2014 BPA published the SliceBlock and Block customers' FY2013 and forecast FY2015 Total Retail Load (TRL) and...

  7. Beyond transparency : collective engagement in sustainable design

    E-Print Network [OSTI]

    Bonanni, Leonardo Amerigo, 1977-

    2010-01-01T23:59:59.000Z

    For a timely answer to the question of sustainability, or how to provide for future generations, there needs to be shared accounting of our social and physical resources. Supply chain transparency makes it possible to map ...

  8. Electrically conductive material

    DOE Patents [OSTI]

    Singh, J.P.; Bosak, A.L.; McPheeters, C.C.; Dees, D.W.

    1993-09-07T23:59:59.000Z

    An electrically conductive material is described for use in solid oxide fuel cells, electrochemical sensors for combustion exhaust, and various other applications possesses increased fracture toughness over available materials, while affording the same electrical conductivity. One embodiment of the sintered electrically conductive material consists essentially of cubic ZrO[sub 2] as a matrix and 6-19 wt. % monoclinic ZrO[sub 2] formed from particles having an average size equal to or greater than about 0.23 microns. Another embodiment of the electrically conductive material consists essentially at cubic ZrO[sub 2] as a matrix and 10-30 wt. % partially stabilized zirconia (PSZ) formed from particles having an average size of approximately 3 microns. 8 figures.

  9. Multilayered YSZ/GZO films with greatly enhanced ionic conduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    YSZGZO films with greatly enhanced ionic conduction for low temperature solid oxide fuel cells. Multilayered YSZGZO films with greatly enhanced ionic conduction for low...

  10. On-cue detachment of hydrogels and cells from optically transparent electrodesw

    E-Print Network [OSTI]

    Revzin, Alexander

    of composition or conformation of self-assembled molecules is to remove these molecules altogether) is optically transparent yet conductive material that is well-suited for cell cultivation and observation was highly significant because it permitted both spatial and temporal control over the release of polymer

  11. EFFECTS OF TRITIUM GAS EXPOSURE ON ELECTRICALLY CONDUCTING POLYMERS

    SciTech Connect (OSTI)

    Kane, M.; Clark, E.; Lascola, R.

    2009-12-16T23:59:59.000Z

    Effects of beta (tritium) and gamma irradiation on the surface electrical conductivity of two types of conducting polymer films are documented to determine their potential use as a sensing and surveillance device for the tritium facility. It was shown that surface conductivity was significantly reduced by irradiation with both gamma and tritium gas. In order to compare the results from the two radiation sources, an approximate dose equivalence was calculated. The materials were also sensitive to small radiation doses (<10{sup 5} rad), showing that there is a measurable response to relatively small total doses of tritium gas. Spectroscopy was also used to confirm the mechanism by which this sensing device would operate in order to calibrate this sensor for potential use. It was determined that one material (polyaniline) was very sensitive to oxidation while the other material (PEDOT-PSS) was not. However, polyaniline provided the best response as a sensing material, and it is suggested that an oxygen-impermeable, radiation-transparent coating be applied to this material for future device prototype fabrication. A great deal of interest has developed in recent years in the area of conducting polymers due to the high levels of conductivity that can be achieved, some comparable to that of metals [Gerard 2002]. Additionally, the desirable physical and chemical properties of a polymer are retained and can be exploited for various applications, including light emitting diodes (LED), anti-static packaging, electronic coatings, and sensors. The electron transfer mechanism is generally accepted as one of electron 'hopping' through delocalized electrons in the conjugated backbone, although other mechanisms have been proposed based on the type of polymer and dopant [Inzelt 2000, Gerard 2002]. The conducting polymer polyaniline (PANi) is of particular interest because there are extensive studies on the modulation of the conductivity by changing either the oxidation state of the main backbone chain, or by protonation of the imine groups [de Acevedo, 1999]. There are several types of radiation sensors commercially available, including ionization chambers, geiger counters, proportional counters, scintillators and solid state detectors. Each type has advantages, although many of these sensors require expensive electronics for signal amplification, are large and bulky, have limited battery life or require expensive materials for fabrication. A radiation sensor constructed of a polymeric material could be flexible, light, and the geometry designed to suit the application. Very simple and inexpensive electronics would be necessary to measure the change in conductivity with exposure to radiation and provide an alarm system when a set change of conductivity occurs in the sensor that corresponds to a predetermined radiation dose having been absorbed by the polymer. The advantages of using a polymeric sensor of this type rather than those currently in use are the flexibility of sensor geometry and relatively low cost. It is anticipated that these sensors can be made small enough for glovebox applications or have the ability to monitor the air tritium levels in places where a traditional monitor cannot be placed. There have been a few studies on the changes in conductivity of polyaniline specifically for radiation detection [de Acevedo, 1999; Lima Pacheco, 2003], but there have been no reports on the effects of tritium (beta radiation) on conducting polymers, such as polyaniline or polythiophene. The direct implementation of conducting polymers as radiation sensor materials has not yet been commercialized due to differing responses with total dose, dose rate, etc. Some have reported a large increase in the surface conductivity with radiation dose while others report a marked decrease in conductive properties; these differing observations may reflect the competing mechanisms of chain scission and cross-linking. However, it is clear that the radiation dose effects on conducting polymers must be fully understood before these materials can be used

  12. Radio-transparent multi-layer insulation for radiowave receivers

    SciTech Connect (OSTI)

    Choi, J. [Korea University, Anam-dong Seongbuk-gu, Seoul 136-713 (Korea, Republic of)] [Korea University, Anam-dong Seongbuk-gu, Seoul 136-713 (Korea, Republic of); Ishitsuka, H. [Department of Particle and Nuclear Physics, School of High Energy Accelerator Science, The Graduate University for Advanced Studies (SOKENDAI), Shonan Village, Hayama, Kanagawa 240-0193 (Japan)] [Department of Particle and Nuclear Physics, School of High Energy Accelerator Science, The Graduate University for Advanced Studies (SOKENDAI), Shonan Village, Hayama, Kanagawa 240-0193 (Japan); Mima, S. [Terahertz Sensing and Imaging Team, Terahertz-wave Research Group, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan)] [Terahertz Sensing and Imaging Team, Terahertz-wave Research Group, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Oguri, S., E-mail: shugo@post.kek.jp [Institute of Particle and Nuclear Studies, High Energy Accelerator Research Organization (KEK), Oho, Tsukuba, Ibaraki 305-0801 (Japan); Takahashi, K. [Terahertz Sensing and Imaging Team, Terahertz-wave Research Group, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan) [Terahertz Sensing and Imaging Team, Terahertz-wave Research Group, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Department of Physics, Tohoku University, Sendai, Miyagi 980-8578 (Japan); Tajima, O. [Department of Particle and Nuclear Physics, School of High Energy Accelerator Science, The Graduate University for Advanced Studies (SOKENDAI), Shonan Village, Hayama, Kanagawa 240-0193 (Japan) [Department of Particle and Nuclear Physics, School of High Energy Accelerator Science, The Graduate University for Advanced Studies (SOKENDAI), Shonan Village, Hayama, Kanagawa 240-0193 (Japan); Institute of Particle and Nuclear Studies, High Energy Accelerator Research Organization (KEK), Oho, Tsukuba, Ibaraki 305-0801 (Japan)

    2013-11-15T23:59:59.000Z

    In the field of radiowave detection, enlarging the receiver aperture to enhance the amount of light detected is essential for greater scientific achievements. One challenge in using radio transmittable apertures is keeping the detectors cool. This is because transparency to thermal radiation above the radio frequency range increases the thermal load. In shielding from thermal radiation, a general strategy is to install thermal filters in the light path between aperture and detectors. However, there is difficulty in fabricating metal mesh filters of large diameters. It is also difficult to maintain large diameter absorptive-type filters in cold because of their limited thermal conductance. A technology that maintains cold conditions while allowing larger apertures has been long-awaited. We propose radio-transparent multi-layer insulation (RT-MLI) composed from a set of stacked insulating layers. The insulator is transparent to radio frequencies, but not transparent to infrared radiation. The basic idea for cooling is similar to conventional multi-layer insulation. It leads to a reduction in thermal radiation while maintaining a uniform surface temperature. The advantage of this technique over other filter types is that no thermal links are required. As insulator material, we used foamed polystyrene; its low index of refraction makes an anti-reflection coating unnecessary. We measured the basic performance of RT-MLI to confirm that thermal loads are lowered with more layers. We also confirmed that our RT-MLI has high transmittance to radiowaves, but blocks infrared radiation. For example, RT-MLI with 12 layers has a transmittance greater than 95% (lower than 1%) below 200 GHz (above 4 THz). We demonstrated its effects in a system with absorptive-type filters, where aperture diameters were 200 mm. Low temperatures were successfully maintained for the filters. We conclude that this technology significantly enhances the cooling of radiowave receivers, and is particularly suitable for large-aperture systems. This technology is expected to be applicable to various fields, including radio astronomy, geo-environmental assessment, and radar systems.

  13. Conductive Polymers

    SciTech Connect (OSTI)

    Bohnert, G.W.

    2002-11-22T23:59:59.000Z

    Electroluminescent devices such as light-emitting diodes (LED) and high-energy density batteries. These new polymers offer cost savings, weight reduction, ease of processing, and inherent rugged design compared to conventional semiconductor materials. The photovoltaic industry has grown more than 30% during the past three years. Lightweight, flexible solar modules are being used by the U.S. Army and Marine Corps for field power units. LEDs historically used for indicator lights are now being investigated for general lighting to replace fluorescent and incandescent lights. These so-called solid-state lights are becoming more prevalent across the country since they produce efficient lighting with little heat generation. Conductive polymers are being sought for battery development as well. Considerable weight savings over conventional cathode materials used in secondary storage batteries make portable devices easier to carry and electric cars more efficient and nimble. Secondary battery sales represent an $8 billion industry annually. The purpose of the project was to synthesize and characterize conductive polymers. TRACE Photonics Inc. has researched critical issues which affect conductivity. Much of their work has focused on production of substituted poly(phenylenevinylene) compounds. These compounds exhibit greater solubility over the parent polyphenylenevinylene, making them easier to process. Alkoxy substituted groups evaluated during this study included: methoxy, propoxy, and heptyloxy. Synthesis routes for production of alkoxy-substituted poly phenylenevinylene were developed. Considerable emphasis was placed on final product yield and purity.

  14. Contributing Storage using the Transparent File System

    E-Print Network [OSTI]

    Berger, Emery

    Contributing Storage using the Transparent File System JAMES CIPAR and MARK D. CORNER and EMERY D barrier to the adoption of contributory storage systems is that contributing a large quantity of local--all of the currently available space-- without impacting the performance of ordinary file access operations. We show

  15. Process for forming transparent aerogel insulating arrays

    DOE Patents [OSTI]

    Tewari, P.H.; Hunt, A.J.

    1985-09-04T23:59:59.000Z

    An improved supercritical drying process for forming transparent silica aerogel arrays is described. The process is of the type utilizing the steps of hydrolyzing and condensing aloxides to form alcogels. A subsequent step removes the alcohol to form aerogels. The improvement includes the additional step, after alcogels are formed, of substituting a solvent, such as CO/sub 2/, for the alcohol in the alcogels, the solvent having a critical temperature less than the critical temperature of the alcohol. The resulting gels are dried at a supercritical temperature for the selected solvent, such as CO/sub 2/, to thereby provide a transparent aerogel array within a substantially reduced (days-to-hours) time period. The supercritical drying occurs at about 40/sup 0/C instead of at about 270/sup 0/C. The improved process provides increased yields of large scale, structurally sound arrays. The transparent aerogel array, formed in sheets or slabs, as made in accordance with the improved process, can replace the air gap within a double glazed window, for example, to provide a substantial reduction in heat transfer. The thus formed transparent aerogel arrays may also be utilized, for example, in windows of refrigerators and ovens, or in the walls and doors thereof or as the active material in detectors for analyzing high energy elementary particles or cosmic rays.

  16. Process for forming transparent aerogel insulating arrays

    DOE Patents [OSTI]

    Tewari, Param H. (Milpitas, CA); Hunt, Arlon J. (Oakland, CA)

    1986-01-01T23:59:59.000Z

    An improved supercritical drying process for forming transparent silica aerogel arrays is described. The process is of the type utilizing the steps of hydrolyzing and condensing aloxides to form alcogels. A subsequent step removes the alcohol to form aerogels. The improvement includes the additional step, after alcogels are formed, of substituting a solvent, such as CO.sub.2, for the alcohol in the alcogels, the solvent having a critical temperature less than the critical temperature of the alcohol. The resulting gels are dried at a supercritical temperature for the selected solvent, such as CO.sub.2, to thereby provide a transparent aerogel array within a substantially reduced (days-to-hours) time period. The supercritical drying occurs at about 40.degree. C. instead of at about 270.degree. C. The improved process provides increased yields of large scale, structurally sound arrays. The transparent aerogel array, formed in sheets or slabs, as made in accordance with the improved process, can replace the air gap within a double glazed window, for example, to provide a substantial reduction in heat transfer. The thus formed transparent aerogel arrays may also be utilized, for example, in windows of refrigerators and ovens, or in the walls and doors thereof or as the active material in detectors for analyzing high energy elementry particles or cosmic rays.

  17. Deformable Transparent All-Carbon-Nanotube Transistors

    E-Print Network [OSTI]

    Maruyama, Shigeo

    and organic materials16,17 are candidates for next-generation flexible and transparent electronic devices-carbon-nanotube field-effect transistors (CNT- FETs), making use of the flexible yet robust nature of single than those used in other flexible CNT-FETs allowed our devices to be highly deformable without

  18. Texas Cities in the Era of Government Transparency

    E-Print Network [OSTI]

    Bearfield, Domonic; Bowman, Ann O'M

    We are in the Era of Government Transparency. Recently, politicians from President Barack Obama to Texas Governor Rick Perry have touted a commitment to openness and transparency in their respective administrations. Citizens have also embraced...

  19. Electromagnetically induced transparency with broadband laser pulses D. D. Yavuz

    E-Print Network [OSTI]

    Yavuz, Deniz

    Electromagnetically induced transparency with broadband laser pulses D. D. Yavuz Department pulses inside an atomic medium using electromag- netically induced transparency. Extending the suggestion.65. k Over the last decade, counterintuitive optical effects using electromagnetically induced

  20. Characterization of Light Scattering in Transparent Polycrystalline Laser Ceramics

    E-Print Network [OSTI]

    Sharma, Saurabh

    2013-01-01T23:59:59.000Z

    Laser Media (PLM) …………………………..… 4 Bulk Scatteringacross and through the entire PLM regardless of dimensions.42 Characterization of Transparent PLM …………………………. 43

  1. Optimization of transparent and reflecting electrodes for amorphous silicon solar cells. Annual subcontract report, 1 May 1991--30 April 1992

    SciTech Connect (OSTI)

    Gordon, R.G. [Harvard Univ., Cambridge, MA (United States). Dept. of Chemistry

    1993-04-01T23:59:59.000Z

    This report describes work to improve the performance of solar cells by improving the electrical and optical properties of their transparent conducting oxides (TCO) layers. Boron-doped zinc-oxide films were deposited by atmospheric pressure chemical vapor deposition in a laminar-flow reactor from diethyl zinc, tert-butanol, and diborane in the temperature range between 300{degrees}C and 420{degrees}C. When the deposition temperature was above 320{degrees}C, both doped and undoped films have highly oriented crystallites with their c-axes perpendicular to the substrate plane. Films deposited from 0.07% diethyl zinc and 2.4% tert-butanol have electron densities between 3.5 {times} 10{sup 20} cm{sup {minus}3} and 5.5 {times} 10{sup 20} cm{sup {minus}3}, conductivities between 250 {Omega}{sup {minus}1} and 2500 {Omega}{sup {minus}1} and mobilities between 2.5 cm{sup 2}/V-s and 35.0 cm{sup 2}/V-s, depending on dopant concentration, film thickness, and deposition temperature. Optical measurements show that the maximum infrared reflectance of the doped films is close to 90%, compared to about 20% for undoped films. Film visible absorption and film conductivity were found to increase with film thickness. The ratio of conductivity to visible absorption coefficient for doped films was between 0.1 {Omega} and 1.1 {Omega}{sup {minus}1}. The band gap of the film changes from 3.3 eV to 3.7 eV when the film is doped with 0.012% diborane.

  2. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  3. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  4. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  5. Transparent monolithic metal ion containing nanophase aerogels

    SciTech Connect (OSTI)

    Risen, W. M., Jr.; Hu, X.; Ji, S.; Littrell, K.

    1999-12-01T23:59:59.000Z

    The formation of monolithic and transparent transition metal containing aerogels has been achieved through cooperative interactions of high molecular weight functionalized carbohydrates and silica precursors, which strongly influence the kinetics of gelation. After initial gelation, subsequent modification of the ligating character of the system, coordination of the group VIII metal ions, and supercritical extraction afford the aerogels. The structures at the nanophase level have been probed by photon and electron transmission and neutron scattering techniques to help elucidate the basis for structural integrity together with the small entity sizes that permit transparency in the visible range. They also help with understanding the chemical reactivities of the metal-containing sites in these very high surface area materials. These results are discussed in connection with new reaction studies.

  6. Theory of Dipole Induced Electromagnetic Transparency

    E-Print Network [OSTI]

    Puthumpally-Joseph, Raiju; Sukharev, Maxim; Charron, Eric

    2015-01-01T23:59:59.000Z

    A detailed theory describing linear optics of vapors comprised of interacting multi-level quantum emitters is proposed. It is shown both by direct integration of Maxwell-Bloch equations and using a simple analytical model that at large densities narrow transparency windows appear in otherwise completely opaque spectra. The existence of such windows is attributed to overlapping resonances. This effect, first introduced for three-level systems in [R. Puthumpally-Joseph, M. Sukharev, O. Atabek and E. Charron, Phys. Rev. Lett. 113, 163603 (2014)], is due to strongly enhanced dipole-dipole interactions at high emitters' densities. The presented theory extends this effect to the case of multilevel systems. The theory is applied to the D1 transitions of interacting Rb-85 atoms. It is shown that at high atomic densities, Rb-85 atoms can behave as three-level emitters exhibiting all the properties of dipole induced electromagnetic transparency. Applications including slow light and laser pulse shaping are also propose...

  7. Dynamic, transparent Internet server replication using HYDRANET 

    E-Print Network [OSTI]

    Dillon, Geoffrey A.

    1998-01-01T23:59:59.000Z

    -tolerance through redundancy, since Replicas can continue to function when their Origin Servers are no longer online. HYDRANET accomplishes these objectives by replicating Transport-level Service Access Points (TSAPs) [8] of servers in the operating system of our... modified Repli- cation Server. A modified IP-router provides the client traffic redirection by IP-in-IP tunneling. The use of TSAPs in this scheme allows us to selectively and transpar- ently replicate services from specific hosts without disrupting...

  8. Transparent heat-spreader for optoelectronic applications

    DOE Patents [OSTI]

    Minano, Juan Carlos; Benitez, Pablo

    2014-11-04T23:59:59.000Z

    An optoelectronic cooling system is equally applicable to an LED collimator or a photovoltaic solar concentrator. A transparent fluid conveys heat from the optoelectronic chip to a hollow cover over the system aperture. The cooling system can keep a solar concentrator chip at the same temperature as found for a one-sun flat-plate solar cell. Natural convection or forced circulation can operate to convey heat from the chip to the cover.

  9. Thermodynamics and Ionic Conductivity of Block Copolymer Electrolytes

    E-Print Network [OSTI]

    Wanakule, Nisita Sidra

    2010-01-01T23:59:59.000Z

    of Poly(Ethylene Oxide) Molten-Salt Rubbery Electrolytes.Imides: A New Family of Molten Salts and Conductive Plasticof Poly(Ethylene Oxide) Molten-Salt Rubbery Electrolytes.

  10. Ionic conductivity of Bi{sub 2}Ni{sub x}V{sub 1?x}O{sub 5.5?3x/2} (0.1 ? x ? 0.2) oxides prepared by a low temperature sol-gel route

    SciTech Connect (OSTI)

    Rusli, Rolan; Patah, Aep, E-mail: ismu@chem.itb.ac.id; Prijamboedi, Bambang, E-mail: ismu@chem.itb.ac.id; Ismunandar, E-mail: ismu@chem.itb.ac.id [Inorganic and Physical Chemistry Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia); Abrahams, Isaac [Materials Research Institute, School of Biological and Chemical Sciences, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom)

    2014-03-24T23:59:59.000Z

    Solid oxides fuel cells (SOFCs) is one technology that could contribute toward future sustainable energy. One of the most important components of an SOFC is the electrolyte, which must have high ionic conductivity. Cation substitution of vanadium in Bi{sub 4}V{sub 2}O{sub 11} yields a family of fast oxide ion conducting solids known collectively as the BIMEVOXes (bismuth metal vanadium oxide), which have the potential to be applied as electrolytes in SOFCs. The purpose of this work is to study the effect of Ni concentration, when used as a dopant, on the ionic conductivity of Bi{sub 2}Ni{sub x}V{sub 1?x}O{sub 5.5?3x/2} (BINIVOX) oxides (0.1 ? x ? 0.2) when prepared by a sol gel method. The gels were calcined at 600 °C for 24 h to produce pure BINIVOX. These oxides were found to exhibit the ?-phase structure with tetragonal symmetry in space group I4/mmm. Ionic conductivity of BINIVOX at 300 °C were 6.9 × 10{sup ?3} S cm{sup ?1}, 1.2 × 10{sup ?3} S cm{sup ?1}, and 8.2 × 10{sup ?4} S cm{sup ?1}, for x = 0.1; 0.15; and 0.2; respectively; and at 600 °C were 1.1 × 10{sup ?1} S cm{sup ?1}, 5.3 × 10{sup ?2} S cm{sup ?1}, and 2.8 ×10{sup ?2} S cm{sup ?1}, for x = 0.1; 0.15; and 0.2; respectively.

  11. Method for making monolithic metal oxide aerogels

    DOE Patents [OSTI]

    Droege, M.W.; Coronado, P.R.; Hair, L.M.

    1995-03-07T23:59:59.000Z

    Transparent, monolithic metal oxide aerogels of varying densities are produced using a method in which a metal alkoxide solution and a catalyst solution are prepared separately and reacted. The resulting hydrolyzed-condensed colloidal solution is gelled, and the wet gel is contained within a sealed, but gas permeable, containment vessel during supercritical extraction of the solvent. The present invention is especially advantageous for making metal oxides other than silica that are prone to forming opaque, cracked aerogels. 6 figs.

  12. Method for making monolithic metal oxide aerogels

    DOE Patents [OSTI]

    Droege, Michael W. (Livermore, CA); Coronado, Paul R. (Livermore, CA); Hair, Lucy M. (Livermore, CA)

    1995-01-01T23:59:59.000Z

    Transparent, monolithic metal oxide aerogels of varying densities are produced using a method in which a metal alkoxide solution and a catalyst solution are prepared separately and reacted. The resulting hydrolyzed-condensed colloidal solution is gelled, and the wet gel is contained within a sealed, but gas permeable, containment vessel during supercritical extraction of the solvent. The present invention is especially advantageous for making metal oxides other than silica that are prone to forming opaque, cracked aerogels.

  13. Thin film method of conducting lithium-ions

    DOE Patents [OSTI]

    Zhang, Ji-Guang (Golden, CO); Benson, David K. (Golden, CO); Tracy, C. Edwin (Golden, CO)

    1998-11-10T23:59:59.000Z

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.

  14. Thin film method of conducting lithium-ions

    DOE Patents [OSTI]

    Zhang, J.G.; Benson, D.K.; Tracy, C.E.

    1998-11-10T23:59:59.000Z

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li{sub 2}O-CeO{sub 2}-SiO{sub 2} system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications. 12 figs.

  15. Influence of growth temperature on electrical, optical, and plasmonic properties of aluminum:zinc oxide films grown by radio frequency magnetron sputtering

    SciTech Connect (OSTI)

    Dondapati, Hareesh; Santiago, Kevin; Pradhan, A. K. [Center for Materials Research, Norfolk State University, 700 Park Avenue, Norfolk, Virginia 23504 (United States)] [Center for Materials Research, Norfolk State University, 700 Park Avenue, Norfolk, Virginia 23504 (United States)

    2013-10-14T23:59:59.000Z

    We have investigated the responsible mechanism for the observation of metallic conductivity at room temperature and metal-semiconductor transition (MST) at lower temperatures for aluminum-doped zinc oxide (AZO) films. AZO films were grown on glass substrates by radio-frequency magnetron sputtering with varying substrate temperatures (T{sub s}). The films were found to be crystalline with the electrical resistivity close to 1.1 × 10{sup ?3} ? cm and transmittance more than 85% in the visible region. The saturated optical band gap of 3.76 eV was observed for the sample grown at T{sub s} of 400 °C, however, a slight decrease in the bandgap was noticed above 400 °C, which can be explained by Burstein–Moss effect. Temperature dependent resistivity measurements of these highly conducting and transparent films showed a MST at ?110 K. The observed metal-like and metal-semiconductor transitions are explained by taking into account the Mott phase transition and localization effects due to defects. All AZO films demonstrate crossover in permittivity from positive to negative and low loss in the near-infrared region, illustrating its applications for plasmonic metamaterials, including waveguides for near infrared telecommunication region. Based on the results presented in this study, the low electrical resistivity and high optical transmittance of AZO films suggested a possibility for the application in the flexible electronic devices, such as transparent conducting oxide film on LEDs, solar cells, and touch panels.

  16. NPT Transparency Visit | National Nuclear Security Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated CodesTransparency Visit | National Nuclear Security Administration Facebook

  17. Multiple-scattering series for color transparency

    SciTech Connect (OSTI)

    Greenberg, W.R.; Miller, G.A. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1993-03-01T23:59:59.000Z

    Cold transparency (CT) depends on the formation of a wave packet of small spatial extent. It is useful to interpret experimental searches for CT with a multiple-scattering series based on wave-packet--nucleon scattering instead of the standard one using nucleon-nucleon scattering. We develop several new techniques which are valid for differing ranges of energy. These techniques are applied to verify some early approximations, study new forms of the wave-packet--nucleon interaction, examine effects of treating wave packets of nonzero size, and predict the production of [ital N][sup *]'s in electron scattering experiments.

  18. Transparent Cost Database | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown of Ladoga, Indiana (Utility Company)Library < TransmissionTransparent Cost

  19. Oxidation Resistant Graphite Studies

    SciTech Connect (OSTI)

    W. Windes; R. Smith

    2014-07-01T23:59:59.000Z

    The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

  20. Near-infrared photodetector consisting of J-aggregating cyanine dye and metal oxide thin films

    E-Print Network [OSTI]

    Osedach, Timothy P.

    We demonstrate a near-infrared photodetector that consists of a thin film of the J-aggregating cyanine dye, U3, and transparent metal-oxide charge transport layers. The high absorption coefficient of the U3 film, combined ...

  1. atmospheric transparency studies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    pressures lower than 0.1 bar, transparency to thermal radiation allows shortwave heating to dominate, creating a stratosphere. At higher pressures, atmospheres become...

  2. Net Requirements Transparency Process for Slice/Block Customers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 2012 Net Requirements Transparency Process for SliceBlock Customers Description of Changes and a Response to Comments September 24, 2012 Background and Description of Changes:...

  3. Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in Organic Solar Cells Home > Research > ANSER Research Highlights > Sorted Single-Walled Carbon Nanotube...

  4. Transparency of 0.2% GdCl3 Doped Water in a Stainless Steel Test Environment

    E-Print Network [OSTI]

    W. Coleman; A. Bernstein; S. Dazeley; R. Svoboda

    2008-06-11T23:59:59.000Z

    The possibility of neutron and neutrino detection using water Cerenkov detectors doped with gadolinium holds the promise of constructing very large high-efficiency detectors with wide-ranging application in basic science and national security. This study addressed a major concern regarding the feasibility of such detectors: the transparency of the doped water to the ultraviolet Cerenkov light. We report on experiments conducted using a 19-meter water transparency measuring instrument and associated materials test tank. Sensitive measurements of the transparency of water doped with 0.2% GdCl3 at 337nm, 400nm and 420nm were made using this instrument. These measurements indicate that GdCl3 is not an appropriate dopant in stainless steel constructed water Cerenkov detectors.

  5. Conduction at a ferroelectric interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Marshall, Matthew S. J.; Malashevich, Andrei; Disa, Ankit S.; Han, Myung-Guen; Chen, Hanghui; Zhu, Yimei; Ismail-Beigi, Sohrab; Walker, Frederick J.; Ahn, Charles H.

    2014-11-01T23:59:59.000Z

    Typical logic elements utilizing the field effect rely on the change in carrier concentration due to the field in the channel region of the device. Ferroelectric-field-effect devices provide a nonvolatile version of this effect due to the stable polarization order parameter in the ferroelectric. In this work, we describe an oxide/ oxide ferroelectric heterostructure device based on (001)-oriented PbZr??.?Ti?.?O?-LaNiO? where the dominant change in conductivity is a result of a significant mobility change in the interfacial channel region. The effect is confined to a few atomic layers at the interface and is reversible by switching the ferroelectric polarization. More interestingly,more »in one polarization state, the field effect induces a 1.7-eV shift of the interfacial bands to create a new conducting channel in the interfacial PbO layer of the ferroelectric.« less

  6. Conduction at a ferroelectric interface

    SciTech Connect (OSTI)

    Marshall, Matthew S. J. [Yale Univ., New Haven, CT (United States); Malashevich, Andrei [Yale Univ., New Haven, CT (United States); Disa, Ankit S. [Yale Univ., New Haven, CT (United States); Han, Myung-Guen [Brookhaven National Lab. (BNL), Upton, NY (United States); Chen, Hanghui [Yale Univ., New Haven, CT (United States); Zhu, Yimei [Brookhaven National Lab. (BNL), Upton, NY (United States); Ismail-Beigi, Sohrab [Yale Univ., New Haven, CT (United States); Walker, Frederick J. [Yale Univ., New Haven, CT (United States); Ahn, Charles H. [Yale Univ., New Haven, CT (United States);

    2014-11-01T23:59:59.000Z

    Typical logic elements utilizing the field effect rely on the change in carrier concentration due to the field in the channel region of the device. Ferroelectric-field-effect devices provide a nonvolatile version of this effect due to the stable polarization order parameter in the ferroelectric. In this work, we describe an oxide/ oxide ferroelectric heterostructure device based on (001)-oriented PbZr??.?Ti?.?O?-LaNiO? where the dominant change in conductivity is a result of a significant mobility change in the interfacial channel region. The effect is confined to a few atomic layers at the interface and is reversible by switching the ferroelectric polarization. More interestingly, in one polarization state, the field effect induces a 1.7-eV shift of the interfacial bands to create a new conducting channel in the interfacial PbO layer of the ferroelectric.

  7. Perception-Based Transparency Optimization for Direct Volume Rendering

    E-Print Network [OSTI]

    Chen, Wei

    Perception-Based Transparency Optimization for Direct Volume Rendering Ming-Yuen Chan, Student. Perceptual enhancement on transparent layers in direct volume rendered images: a CT head dataset with layered structures (left); layers are enhanced using our proposed rendering optimization method (right). Abstract

  8. Matched slow pulses using double electromagnetically induced transparency

    E-Print Network [OSTI]

    Lvovsky, Alexander

    Matched slow pulses using double electromagnetically induced transparency Andrew MacRae,* Geoff, 2008 We implement double electromagnetically induced transparency (DEIT) in rubidium vapor using Optical Society of America OCIS codes: 270.1670, 270.5585, 190.5530. Electromagnetically induced

  9. Eyo: Device-Transparent Personal Storage Jacob Strauss

    E-Print Network [OSTI]

    Gummadi, Ramakrishna

    Eyo: Device-Transparent Personal Storage Jacob Strauss Justin Mazzola Paluska Chris Lesniewski on multiple personal devices, each of which typically offers a storage management interface oblivious. This paper presents Eyo, a novel personal storage sys- tem that provides device transparency: a user can

  10. Integrated broadband bowtie antenna on transparent substrate

    E-Print Network [OSTI]

    Zhang, Xingyu; Subbaraman, Harish; Zhan, Qiwen; Pan, Zeyu; Chung, Chi-jui; Yan, Hai; Chen, Ray T

    2015-01-01T23:59:59.000Z

    The bowtie antenna is a topic of growing interest in recent years. In this paper, we design, fabricate, and characterize a modified gold bowtie antenna integrated on a transparent glass substrate. We numerically investigate the antenna characteristics, specifically its resonant frequency and enhancement factor. We simulate the dependence of resonance frequency on bowtie geometry, and verify the simulation results through experimental investigation, by fabricating different sets of bowtie antennas on glass substrates utilizing CMOS compatible processes and measuring their resonance frequencies. Our designed bowtie antenna provides a strong broadband electric field enhancement in its feed gap. The far-field radiation pattern of the bowtie antenna is measured, and it shows dipole-like characteristics with large beam width. Such a broadband antenna will be useful for a myriad of applications, ranging from wireless communications to electromagnetic wave detection.

  11. Gravitational Lensing Characteristics of the Transparent Sun

    E-Print Network [OSTI]

    Bijunath Patla; Robert J. Nemiroff

    2011-12-12T23:59:59.000Z

    The transparent Sun is modeled as a spherically symmetric and centrally condensed gravitational lens using recent Standard Solar Model (SSM) data. The Sun's minimum focal length is computed to a refined accuracy of 23.5 +/- 0.1 AU, just beyond the orbit of Uranus. The Sun creates a single image of a distant point source visible to observers inside this minimum focal length and to observers sufficiently removed from the line connecting the source through the Sun's center. Regions of space are mapped where three images of a distant point source are created, along with their associated magnifications. Solar caustics, critical curves, and Einstein rings are computed and discussed. Extremely high gravitational lens magnifications exist for observers situated so that an angularly small, unlensed source appears near a three-image caustic. Types of radiations that might undergo significant solar lens magnifications as they can traverse the core of the Sun, including neutrinos and gravitational radiation, are discussed.

  12. Overview of Transparent Metal Mesh Electrode Technologies

    Energy Savers [EERE]

    range that is transmitted by the conductive coating and substrate. Often the absorption of the substrate is subtracted and the transmission of the coating itself reported....

  13. Application of CVD graphene in organic photovoltaics as transparent conducting electrodes

    E-Print Network [OSTI]

    Park, Hyesung, Ph. D. Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    Graphene, a hexagonal arrangement of carbon atoms forming a one-atom thick planar sheet, has gained much attention due to its remarkable physical properties. Apart from the micromechanical cleavage of highly ordered pyrolytic ...

  14. TRANSPARENT CONDUCTING ZNO FILMS BY REACTIVE DC MAGNETRON SPUTTERING FROM METALLIC TARGETS

    E-Print Network [OSTI]

    Scofield, John H.

    , Oberlin College, Oberlin, OH 44074, USA 2 Ohio Aerospace Institute, Brookpark, OH 44142, USA 3 NASA Glenn pieces of Al over the Zn target, 2) sputtering from a Zn98Al02 alloy target, and 3) depostion

  15. Nano Res (2010) 3: 564573564 Uniform, Highly Conductive, and Patterned Transparent Films

    E-Print Network [OSTI]

    Zhou, Chongwu

    2010-01-01T23:59:59.000Z

    problem. In addition, our method also allows the preparation of high quality patterned films of silver. Carbon nanotube (CNT) films [11­15] and, more recently, graphene films [16­19] have attracted significant

  16. Center for Inverse Design Highlight: Anomalous Surface Conductivity in In2O3 Transparent Conductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccess StoriesFebruaryMetalControl SystemLightWhite Light

  17. Electrochromic properties of nickel oxide thin films prepared by the sol-gel method

    SciTech Connect (OSTI)

    Miki, Takeshi; Yoshimura, Kazuki; Tai, Yutaka; Tazawa, Masato; Jin, P.; Tanemura, Sakae [National Industrial Research Inst., Nagoya (Japan). Multifunctional Material Science Dept.

    1995-12-31T23:59:59.000Z

    Recently electrochromic (EC) device has been attractive as a smart glazing to control heating, cooling and lighting loads of buildings and housing. Among various electrochromic materials, nickel oxide is one of the typical anode type materials. Here, the electrochromic nickel oxide films were prepared onto transparent conducting film on glass substrate by the sol-gel method using an ethylene glycol solution of nickel nitrate hexahydrate. The films produced by the dip-coating method and calcined at 250, 300 and 350 C. The formed films were characterized by their electrochromic behavior in cyclic voltammetry. The formed films showed electrochromic behavior in 1M KOH aqueous solution as electrolytic solution. The cyclic voltammograms were recorded up to 100 cycles for each film. The anodic peak of the coloration reaction appeared at approximately +400 mV, while the cathodic peak of the bleaching reaction occurred at about +200 mV vs. Ag/AgCl. Both the anodic peak and the cathodic peak increased with an increase of the cyclic numbers in voltammograms, whereas these peaks at 100 cycles decreased with an increase of the calcination temperature of nickel oxide films. The calcination gave great influence on the other electrochromic behaviors of nickel oxide films.

  18. Copper and Transparent-Conductor Reflectarray Elements on Thin-Film Solar Cell Panels

    E-Print Network [OSTI]

    Dreyer, Philippe; Nicolay, Sylvain; Ballif, Christophe; Perruisseau-Carrier, Julien

    2013-01-01T23:59:59.000Z

    This work addresses the integration of reflectarray antennas (RA) on thin film Solar Cell (SC) panels, as a mean to save real estate, weight, or cost in platforms such as satellites or transportable autonomous antenna systems. Our goal is to design a good RA unit cell in terms of phase response and bandwidth, while simultaneously achieving high optical transparency and low microwave loss, to preserve good SC and RA energy efficiencies, respectively. Since there is a trade-off between the optical transparency and microwave surface conductivity of a conductor, here both standard copper and transparent conductors are considered. The results obtained at the unit cell level demonstrates the feasibility of integrating RA on a thin-film SC, preserving for the first time good performance in terms of both SC and RA efficiency. For instance, measurement at X-band demonstrate families of cells providing a phase range larger than 270{\\deg} with average microwave loss of -2.45dB (resp. -0.25dB) and average optical transpa...

  19. Layer-by-layer assembly of electrically conductive polymer thin films

    E-Print Network [OSTI]

    Jan, Chien Sy Jason

    2007-09-17T23:59:59.000Z

    Layer-by-layer (LbL) assembly was used to produce highly conductive thin films with carbon black (CB) and polyelectrolytes. The effects of sonication and pHadjustment of the deposition mixtures on the conductivity and transparency of deposited films...

  20. Information sources for transparency measures at sensitive facilities

    SciTech Connect (OSTI)

    Stanbro, W.D.; Olinger, C.T.; Close, D.A.; Kniss, B.

    1993-08-01T23:59:59.000Z

    The concept of transparency stems from a desire to assure other parties that some action such as the dismantlement of a weapons system is taking place while avoiding the intrusiveness, complexity, and lengthy negotiations associated with formal verification measures. By their nature, transparency measures may fall short of providing the degree of confidence associated with arms control treaties, such as INF or START, but can be more quickly and easily implemented. This paper discusses information sources that could form the basis of transparency measures at sensitive facilities.

  1. Information sources for transparency measures at sensitive facilities

    SciTech Connect (OSTI)

    Stanbro, W.D.; Olinger, C.T.; Close, D.A.; Kniss, B. [Los Alamos National Lab., NM (United States)

    1993-12-31T23:59:59.000Z

    The concept of transparency stems from a desire to assure other parties that some action such as the dismantlement of a weapons system is taking place while avoiding the intrusiveness, complexity, and lengthy negotiations associated with formal verification measures. By their nature, transparency measures may fall short of providing the degree of confidence associated with arms control treaties, such as INF or START, but can be more quickly and easily implemented. This paper discusses information sources that could form the basis of transparency measures at sensitive facilities.

  2. Solid lithium ion conducting electrolytes and methods of preparation

    DOE Patents [OSTI]

    Narula, Chaitanya K; Daniel, Claus

    2013-05-28T23:59:59.000Z

    A composition comprised of nanoparticles of lithium ion conducting solid oxide material, wherein the solid oxide material is comprised of lithium ions, and at least one type of metal ion selected from pentavalent metal ions and trivalent lanthanide metal ions. Solution methods useful for synthesizing these solid oxide materials, as well as precursor solutions and components thereof, are also described. The solid oxide materials are incorporated as electrolytes into lithium ion batteries.

  3. Directed Social Queries With Transparent User Models Saiph Savage1

    E-Print Network [OSTI]

    California at Santa Barbara, University of

    .forbes@cs, holl@cs}.ucsb.edu 2 Universidad Nacional Aut´onoma de M´exico {rodrigosavage@comunidad, norma?" Computers Music Pets Cooking Transparent Interface Socially Aware Interface "Mexican Food and Salsa Dancing

  4. Acoustical “transparency” induced by local resonance in Bragg bandgaps

    SciTech Connect (OSTI)

    Yu, Gaokun; Wang, Xinlong, E-mail: xlwang@nju.edu.cn [Key Laboratory of Modern Acoustics and Institute of Acoustics, Nanjing University, Nanjing 210093 (China)

    2014-01-28T23:59:59.000Z

    We show that sound waves can resonantly transmit through Bragg bandgaps in an acoustical duct periodically attached with an array of Helmholtz resonators, forming within the normally forbidden band a transparency window with group velocity smaller than the normal speed of sound. The transparency occurs for the locally resonant frequency so much close to the Bragg one that both the local-resonance-induced bandgap and the Bragg one heavily overlap with each other. The phenomenon seems an acoustical analog of the well-known electromagnetically induced transparency by quantum interference. Different from the Fano-like interference explanation, we also provide a mechanism for the transparency window phenomenon which makes it possible to extend the phenomenon in general.

  5. Device Transparency: a New Model for Mobile Storage

    E-Print Network [OSTI]

    Strauss, Jacob A.

    This paper proposes a new storage model, device transparency, in which users view and manage their entire data collection from any of their devices, even from disconnected storage-limited devices holding only a subset of ...

  6. DMTCP: Transparent Checkpointing for Cluster Computations and the Desktop

    E-Print Network [OSTI]

    Arya, Kapil

    DMTCP (Distributed MultiThreaded CheckPointing) is a transparent user-level checkpointing package for distributed applications. Checkpointing and restart is demonstrated for a wide range of over 20 well known applications, ...

  7. alternative transparent electrodes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    large fraction of power incident on a curved primary mirror using an on-axis secondary mirror Kik, Pieter 7 Electrospun Metal Nanofiber Webs as High-Performance Transparent...

  8. Net Requirements Transparency Process for Slice/Block and Block...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 As part of its Net Requirements Transparency process, on July 31, 2013 BPA published the SliceBlock and Block customers' FY2012 and forecast FY2014 Total Retail Load (TRL) and...

  9. Slip casting nano-particle powders for making transparent ceramics

    DOE Patents [OSTI]

    Kuntz, Joshua D. (Livermore, CA); Soules, Thomas F. (Livermore, CA); Landingham, Richard Lee (Livermore, CA); Hollingsworth, Joel P. (Oakland, CA)

    2011-04-12T23:59:59.000Z

    A method of making a transparent ceramic including the steps of providing nano-ceramic powders in a processed or unprocessed form, mixing the powders with de-ionized water, the step of mixing the powders with de-ionized water producing a slurry, sonifing the slurry to completely wet the powder and suspend the powder in the de-ionized water, separating very fine particles from the slurry, molding the slurry, and curing the slurry to produce the transparent ceramic.

  10. Coupled-resonator-induced transparency with a squeezed vacuum

    E-Print Network [OSTI]

    Ke Di; Changde Xie; Jing Zhang

    2011-03-17T23:59:59.000Z

    We present the first experimental observation of quantum fluctuation spectra in two coupled optical cavities with an injected squeezed vacuum light. The quadrature components of the reflected squeezed vacuum spectra are measured by phase sensitive homodyne detector. The experimental results demonstrate coupled-resonator-induced transparency in the quantum regime, in which electromagnetically-induced-transparency-like characteristic of the absorption and dispersion properties of the coupled optical cavities determines the line-shape of the reflected quantum noise spectra.

  11. Realistic hadronic matrix element approach to color transparency

    SciTech Connect (OSTI)

    Jennings, B.K. (TRIUMF, Vancouver, British Columbia, V6T 2A3 (Canada)); Miller, G.A. (Physics Department, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1992-12-21T23:59:59.000Z

    Color transparency occurs if a small-sized wave packet, formed in a high momentum transfer process, escapes the nucleus before expanding. The time required for the expansion depends on the masses of the baryonic components of the wave packet. Measured proton diffractive dissociation and electron deep inelastic scattering cross sections are used to examine and severely constrain the relevant masses. These constraints allow significant color transparency effects to occur at experimentally accessible momentum transfers.

  12. Color transparency and Landshoff multiple-scattering processes

    SciTech Connect (OSTI)

    Botts, J. (Department of Physics, FM-15, University of Washington, Seattle, Washington (USA))

    1991-11-01T23:59:59.000Z

    In the following, the leading and nonleading contributions to fixed angle hadron-hadron elastic scattering are included in a qualitative analysis of {ital T}({ital s}), the transparency of {ital pN} quasielastic scattering. A simple model is given to predict the center-of-mass energies at which a target nuclei will become transparent to hard- and triple- (Landshoff-) scattered protons.

  13. NEPA Success Stories: Celebrating 40 Years of Transparency and Open Government

    Broader source: Energy.gov [DOE]

    NEPA Success Stories: Celebrating 40 Years of Transparency and Open Government, Environmental Law Institute, 2010.

  14. Nuclear transparency in 90c.m. quasielastic A,,p,2p... reactions

    E-Print Network [OSTI]

    Christensen, Nelson

    Nuclear transparency in 90c.m. ° quasielastic A,,p,2p... reactions J. Aclander,7 J. Alster,7 G Synchrotron of BNL to measure the nuclear transparency of nuclei measured in the A p,2p quasielastic of the energy dependence of the nuclear transparency. In E850 the angular dependence of the nuclear transparency

  15. Nanostructured Transparent Conductors Have Potential for Thin-Film Photovoltaics (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-08-01T23:59:59.000Z

    Possible alternatives to transparent conductors show promise for enabling new processes and reducing costs.

  16. Is Opacity A Basic Feature? It's Not Transparent. Randall S. Birnkrant Jeremy M. Wolfe Hermie Mendoza

    E-Print Network [OSTI]

    transparent objects and/or vice versa? Stimuli: Transparent bars were created by moving a virtual green filter Mendoza Brigham & Women's Hospital Brigham & Women's Hospital & Harvard Medical School OPAQUE You spotted as a basic feature? TRANSPARENT Exp. 1: Does an opaque object stick out among transparent objects and/or vice

  17. Nuclear waste repository transparency technology test bed demonstrations at WIPP

    SciTech Connect (OSTI)

    BETSILL,J. DAVID; ELKINS,NED Z.; WU,CHUAN-FU; MEWHINNEY,JAMES D.; AAMODT,PAUL

    2000-01-27T23:59:59.000Z

    Secretary of Energy, Bill Richardson, has stated that one of the nuclear waste legacy issues is ``The challenge of managing the fuel cycle's back end and assuring the safe use of nuclear power.'' Waste management (i.e., the back end) is a domestic and international issue that must be addressed. A key tool in gaining acceptance of nuclear waste repository technologies is transparency. Transparency provides information to outside parties for independent assessment of safety, security, and legitimate use of materials. Transparency is a combination of technologies and processes that apply to all elements of the development, operation, and closure of a repository system. A test bed for nuclear repository transparency technologies has been proposed to develop a broad-based set of concepts and strategies for transparency monitoring of nuclear materials at the back end of the fuel/weapons cycle. WIPP is the world's first complete geologic repository system for nuclear materials at the back end of the cycle. While it is understood that WIPP does not currently require this type of transparency, this repository has been proposed as realistic demonstration site to generate and test ideas, methods, and technologies about what transparency may entail at the back end of the nuclear materials cycle, and which could be applicable to other international repository developments. An integrated set of transparency demonstrations was developed and deployed during the summer, and fall of 1999 as a proof-of-concept of the repository transparency technology concept. These demonstrations also provided valuable experience and insight into the implementation of future transparency technology development and application. These demonstrations included: Container Monitoring Rocky Flats to WIPP; Underground Container Monitoring; Real-Time Radiation and Environmental Monitoring; Integrated level of confidence in the system and information provided. As the world's only operating deep geologic repository, the Waste Isolation Pilot Plant (WIPP) offers a unique opportunity to serve as an international cooperative test bed for developing and demonstrating technologies and processes in a fully operational repository system setting. To address the substantial national security implications for the US resulting from the lack of integrated, transparent management and disposition of nuclear materials at the back-end of the nuclear fuel and weapons cycles, it is proposed that WIPP be used as a test bed to develop and demonstrate technologies that will enable the transparent and proliferation-resistant geologic isolation of nuclear materials. The objectives of this initiative are to: (1) enhance public confidence in safe, secure geologic isolation of nuclear materials; (2) develop, test, and demonstrate transparency measures and technologies for the back-end of nuclear fuel cycle; and (3) foster international collaborations leading to workable, effective, globally-accepted standards for the transparent monitoring of geological repositories for nuclear materials. Test-bed activities include: development and testing of monitoring measures and technologies; international demonstration experiments; transparency workshops; visiting scientist exchanges; and educational outreach. These activities are proposed to be managed by the Department of Energy/Carlsbad Area Office (DOE/CAO) as part of The Center for Applied Repository and Underground Studies (CARUS).

  18. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  19. Method for making monolithic metal oxide aerogels

    SciTech Connect (OSTI)

    Coronado, Paul R. (Livermore, CA)

    1999-01-01T23:59:59.000Z

    Transparent, monolithic metal oxide aerogels of varying densities are produced using a method in which a metal alkoxide solution and a catalyst solution are prepared separately and reacted. The resulting hydrolyzed-condensed colloidal solution is gelled, and the wet gel is contained within a sealed, but gas permeable, containment vessel during supercritical extraction of the solvent. The containment vessel is enclosed within an aqueous atmosphere that is above the supercritical temperature and pressure of the solvent of the metal alkoxide solution.

  20. First-principles study of the optical properties of BeO in its ambient and high-pressure phases

    E-Print Network [OSTI]

    Pandey, Ravi

    application as an ultraviolet (UV) transparent conduction oxide in flat-panel displays and solar cells can

  1. REVIEW OF PLUTONIUM OXIDATION LITERATURE

    SciTech Connect (OSTI)

    Korinko, P.

    2009-11-12T23:59:59.000Z

    A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles (<15 {micro}m), moderately sized particles (15 < x < 250 {micro}m) and large particles (> 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

  2. Matched Slow Pulses Using Double Electromagnetically Induced Transparency

    E-Print Network [OSTI]

    Andrew MacRae; Geoff Campbell; A. I. Lvovsky

    2008-09-29T23:59:59.000Z

    We implement double electromagnetically-induced transparency (double EIT) in rubidium vapor, using a tripod-shaped energy level scheme consisting of hyperfine and magnetic sublevels of the 5S1/2 to 5P1/2 transition. We show experimentally that through the use of double EIT one can control the contrast of transparency windows as well as group velocities of the two signal fields. In particular, the group velocities can be equalized, which holds promise to greatly enhance nonlinear optical interaction between these fields.

  3. Electrically conductive composite material

    DOE Patents [OSTI]

    Clough, R.L.; Sylwester, A.P.

    1988-06-20T23:59:59.000Z

    An electrically conductive composite material is disclosed which comprises a conductive open-celled, low density, microcellular carbon foam filled with a non-conductive polymer or resin. The composite material is prepared in a two-step process consisting of first preparing the microcellular carbon foam from a carbonizable polymer or copolymer using a phase separation process, then filling the carbon foam with the desired non-conductive polymer or resin. The electrically conductive composites of the present invention has a uniform and consistent pattern of filler distribution, and as a result is superior over prior art materials when used in battery components, electrodes, and the like. 2 figs.

  4. Electrically conductive composite material

    DOE Patents [OSTI]

    Clough, R.L.; Sylwester, A.P.

    1989-05-23T23:59:59.000Z

    An electrically conductive composite material is disclosed which comprises a conductive open-celled, low density, microcellular carbon foam filled with a non-conductive polymer or resin. The composite material is prepared in a two-step process consisting of first preparing the microcellular carbon foam from a carbonizable polymer or copolymer using a phase separation process, then filling the carbon foam with the desired non-conductive polymer or resin. The electrically conductive composites of the present invention has a uniform and consistent pattern of filler distribution, and as a result is superior over prior art materials when used in battery components, electrodes, and the like. 2 figs.

  5. Electrically conductive composite material

    DOE Patents [OSTI]

    Clough, Roger L. (Albuquerque, NM); Sylwester, Alan P. (Albuquerque, NM)

    1989-01-01T23:59:59.000Z

    An electrically conductive composite material is disclosed which comprises a conductive open-celled, low density, microcellular carbon foam filled with a non-conductive polymer or resin. The composite material is prepared in a two-step process consisting of first preparing the microcellular carbon foam from a carbonizable polymer or copolymer using a phase separation process, then filling the carbon foam with the desired non-conductive polymer or resin. The electrically conductive composites of the present invention has a uniform and consistant pattern of filler distribution, and as a result is superior over prior art materials when used in battery components, electrodes, and the like.

  6. Conductive ceramic composition and method of preparation

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL); Kucera, Eugenia H. (Downers Grove, IL)

    1991-01-01T23:59:59.000Z

    A ceramic anode composition is formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The anode is prepared as a non-stoichiometric crystalline structure by reaction and conditioning in a hydrogen gas cover containing minor proportions of carbon dioxide and water vapor. The structure exhibits a single phase and substantially enhanced electrical conductivity over that of the corresponding stoichiometric structure. Unexpectedly, such oxides and oxygenates are found to be stable in the reducing anode fuel gas of a molten carbonate fuel cell.

  7. Conductive ceramic composition and method of preparation

    DOE Patents [OSTI]

    Smith, J.L.; Kucera, E.H.

    1991-04-16T23:59:59.000Z

    A ceramic anode composition is formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The anode is prepared as a non-stoichiometric crystalline structure by reaction and conditioning in a hydrogen gas cover containing minor proportions of carbon dioxide and water vapor. The structure exhibits a single phase and substantially enhanced electrical conductivity over that of the corresponding stoichiometric structure. Unexpectedly, such oxides and oxygenates are found to be stable in the reducing anode fuel gas of a molten carbonate fuel cell. 4 figures.

  8. advanced transparency framework: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Tesla: A Transparent, Extensible Session-Layer Framework for End-to-end Network Services...

  9. Jones phase microscopy of transparent and anisotropic samples

    E-Print Network [OSTI]

    Gillette, Martha U.

    with a transparent sample. JPM uses a modified version of the Hilbert phase microscope (HPM) [15,16]. HPM is similar,20], in the sense that it uses spatial modulation to encode the phase information of the object. How- ever, in HPM

  10. Radiation-transparent windows, method for imaging fluid transfers

    DOE Patents [OSTI]

    Shu, Deming (Darien, IL); Wang, Jin (Burr Ridge, IL)

    2011-07-26T23:59:59.000Z

    A thin, x-ray-transparent window system for environmental chambers involving pneumatic pressures above 40 bar is presented. The window allows for x-ray access to such phenomena as fuel sprays injected into a pressurized chamber that mimics realistic internal combustion engine cylinder operating conditions.

  11. PodBase: Transparent storage management for personal devices

    E-Print Network [OSTI]

    Druschel, Peter

    PodBase: Transparent storage management for personal devices Ansley Post Petr Kuznetsov PeterBase, a system that automatically manages the data and storage across a household's personal devices and frees Druschel Max Planck Institute for Software Systems Rice University 1. INTRODUCTION Personal electronic

  12. Device-Transparent Personal Storage Jacob Alo Strauss

    E-Print Network [OSTI]

    Gummadi, Ramakrishna

    Device-Transparent Personal Storage by Jacob Alo Strauss S.B., Massachusetts Institute personal devices, each of which typically presents the user with a storage management interface isolated and drift out of sync. This thesis presents Eyo, a novel personal storage system that provides device trans

  13. Creating transparency in the Chinese real estate development industry : a case study

    E-Print Network [OSTI]

    Han, Feng, S.M. Massachusetts Institute of Technology

    2005-01-01T23:59:59.000Z

    Transparency issue remains one of the top issues that have discouraged foreign investors to invest China's real estate market. This thesis establishes a framework for Chinese developers to create transparency for their ...

  14. Graphene transparency in weak magnetic fields

    E-Print Network [OSTI]

    David Valenzuela; Saúl Hernández-Ortiz; Marcelo Loewe; Alfredo Raya

    2014-10-20T23:59:59.000Z

    We carry out an explicit calculation of the vacuum polarization tensor for an effective low-energy model of monolayer graphene in the presence of a weak magnetic field of intensity $B$ perpendicularly aligned to the membrane. By expanding the quasiparticle propagator in the Schwinger proper time representation up to order $(eB)^2$, where $e$ is the unit charge, we find an explicitly transverse tensor, consistent with gauge invariance. Furthermore, assuming that graphene is radiated with monochromatic light of frequency $\\omega$ along the external field direction, from the modified Maxwell's equations we derive the intensity of transmitted light and the angle of polarization rotation in terms of the longitudinal ($\\sigma_{xx}$) and transverse ($\\sigma_{xy}$) conductivities. Corrections to these quantities, both calculated and measured, are of order $(eB)^2/\\omega^4$. Our findings generalize and complement previously known results reported in literature regarding the light absorption problem in graphene from the experimental and theoretical points of view, with and without external magnetic fields.

  15. Cermet fuel thermal conductivity 

    E-Print Network [OSTI]

    Alvis, John Mark

    1988-01-01T23:59:59.000Z

    particles of low conductivity dispersed in a metal matrix of high conductivity. A computer code was developed in order to compute the conductivity of cermet fuels as predicted by existing models and an additional model derived in this work... gas release from the fuel particle and contact resistance at the fuel-matrix interface. A description of the methodology used to construct the model is given in Chapter 3. Comparisons between the analytic predictions and the experimental data...

  16. Text-Alternative Version of TAP Webinar: Measuring the Impact of Benchmarking & Transparency

    Broader source: Energy.gov [DOE]

    Transcript of the June TAP webinar, Measuring the Impact of Benchmarking & Transparency - Methodologies and the NYC Example.

  17. Electrically conductive cellulose composite

    DOE Patents [OSTI]

    Evans, Barbara R.; O'Neill, Hugh M.; Woodward, Jonathan

    2010-05-04T23:59:59.000Z

    An electrically conductive cellulose composite includes a cellulose matrix and an electrically conductive carbonaceous material incorporated into the cellulose matrix. The electrical conductivity of the cellulose composite is at least 10 .mu.S/cm at 25.degree. C. The composite can be made by incorporating the electrically conductive carbonaceous material into a culture medium with a cellulose-producing organism, such as Gluconoacetobacter hansenii. The composites can be used to form electrodes, such as for use in membrane electrode assemblies for fuel cells.

  18. Tesla: A Transparent, Extensible Session-Layer Framework for End-to-end Network Services

    E-Print Network [OSTI]

    Gummadi, Ramakrishna

    Tesla: A Transparent, Extensible Session-Layer Framework for End-to-end Network Services by . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Arthur C. Smith Chairman, Department Committee on Graduate Students #12;2 #12;Tesla: A Transparent of these services, we describe Tesla, a transparent and extensible framework that allows session-layer services

  19. TESLA: A Transparent, Extensible Session-Layer Architecture for End-to-end Network Services

    E-Print Network [OSTI]

    TESLA: A Transparent, Extensible Session-Layer Architecture for End-to-end Network Services Jon describes TESLA, a transparent and extensible framework allowing session- layer services to be developed using a high-level flow- based abstraction. TESLA services can be deployed transparently using dynamic

  20. Tesla: A Transparent, Extensible Session-Layer Framework for End-to-end Network Services

    E-Print Network [OSTI]

    Tesla: A Transparent, Extensible Session-Layer Framework for End-to-end Network Services by . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Arthur C. Smith Chairman, Department Committee on Graduate Students #12; 2 #12; Tesla: A Transparent of these services, we describe Tesla, a transparent and extensible framework that allows session-layer services

  1. TESLA: A Transparent, Extensible Session-Layer Architecture for End-to-end Network Services

    E-Print Network [OSTI]

    Gummadi, Ramakrishna

    TESLA: A Transparent, Extensible Session-Layer Architecture for End-to-end Network Services Jon describes TESLA, a transparent and extensible framework allowing session- layer services to be developed using a high-level ¤ow- based abstraction. TESLA services can be deployed transparently using dynamic

  2. Transparent Incremental State Saving in Time Warp Parallel Discrete Event Robert Rnngren, Michael Liljenstam Johan Montagnat

    E-Print Network [OSTI]

    Boyer, Edmond

    Transparent Incremental State Saving in Time Warp Parallel Discrete Event Simulation Robert is the state saving mechanism. It should not only allow efficient state saving, but also support efficient is transparent to the user. In this paper we present a method to implement a transparent incremental state saving

  3. An Innovative High Thermal Conductivity Fuel Design

    SciTech Connect (OSTI)

    Jamil A. Khan

    2009-11-21T23:59:59.000Z

    Thermal conductivity of the fuel in today's Light Water Reactors, Uranium dioxide, can be improved by incorporating a uniformly distributed heat conducting network of a higher conductivity material, Silicon Carbide. The higher thermal conductivity of SiC along with its other prominent reactor-grade properties makes it a potential material to address some of the related issues when used in UO2 [97% TD]. This ongoing research, in collaboration with the University of Florida, aims to investigate the feasibility and develop a formal methodology of producing the resultant composite oxide fuel. Calculations of effective thermal conductivity of the new fuel as a function of %SiC for certain percentages and as a function of temperature are presented as a preliminary approach. The effective thermal conductivities are obtained at different temperatures from 600K to 1600K. The corresponding polynomial equations for the temperature-dependent thermal conductivities are given based on the simulation results. Heat transfer mechanism in this fuel is explained using a finite volume approach and validated against existing empirical models. FLUENT 6.1.22 was used for thermal conductivity calculations and to estimate reduction in centerline temperatures achievable within such a fuel rod. Later, computer codes COMBINE-PC and VENTURE-PC were deployed to estimate the fuel enrichment required, to maintain the same burnup levels, corresponding to a volume percent addition of SiC.

  4. Transparent runtime parallelization of the R scripting language

    SciTech Connect (OSTI)

    Yoginath, Srikanth B [ORNL

    2011-01-01T23:59:59.000Z

    Scripting languages such as R and Matlab are widely used in scientific data processing. As the data volume and the complexity of analysis tasks both grow, sequential data processing using these tools often becomes the bottleneck in scientific workflows. We describe pR, a runtime framework for automatic and transparent parallelization of the popular R language used in statistical computing. Recognizing scripting languages interpreted nature and data analysis codes use pattern, we propose several novel techniques: (1) applying parallelizing compiler technology to runtime, whole-program dependence analysis of scripting languages, (2) incremental code analysis assisted with evaluation results, and (3) runtime parallelization of file accesses. Our framework does not require any modification to either the source code or the underlying R implementation. Experimental results demonstrate that pR can exploit both task and data parallelism transparently and overall has better performance as well as scalability compared to an existing parallel R package that requires code modification.

  5. Enhanced thermal conductivity through the development of nanofluids

    SciTech Connect (OSTI)

    Eastman, J.A.; Choi, U.S.; Li, S.; Thompson, L.J.; Lee, S.

    1996-11-01T23:59:59.000Z

    Low thermal conductivity is a primary limitation in the development of energy-efficient heat transfer fluids required in many industrial applications. To overcome this limitation, a new class of heat transfer fluids is being developed by suspending nanocrystalline particles in liquids such as water or oil. The resulting nanofluids possess extremely high thermal conductivities compared to the liquids without dispersed nanocrystalline particles. For example, 5 volume % of nanocrystalline copper oxide particles suspended in water results in an improvement in thermal conductivity of almost 60% compared to water without nanoparticles. Excellent suspension properties are also observed, with no significant settling of nanocrystalline oxide particles occurring in stationary fluids over time periods longer than several days. Direct evaporation of Cu nanoparticles into pump oil results in similar improvements in thermal conductivity compared to oxide-in-water systems, but importantly, requires far smaller concentrations of dispersed nanocrystalline powder.

  6. Ultraslow Propagation of Squeezed Vacuum Pulses with Electromagnetically Induced Transparency

    E-Print Network [OSTI]

    Daisuke Akamatsu; Yoshihiko Yokoi; Manabu Arikawa; Satoshi Nagatsuka; Takahito Tanimura; Akira Furusawa; Mikio Kozuma

    2008-01-27T23:59:59.000Z

    We have succeeded in observing ultraslow propagation of squeezed vacuum pulses with electromagnetically induced transparency. Squeezed vacuum pulses (probe lights) were incident on a laser cooled 87Rb gas together with an intense coherent light (control light). A homodyne method sensitive to the vacuum state was employed for detecting the probe pulse passing through the gas. A delay of 3.1us was observed for the probe pulse having a temporal width of 10 us.

  7. Nanoantennas for enhanced light trapping in transparent organic solar cells

    E-Print Network [OSTI]

    Voroshilov, Pavel M; Belov, Pavel A

    2014-01-01T23:59:59.000Z

    We propose a light-trapping structure offering a significant enhancement of photovoltaic absorption in transparent organic solar cells operating at infrared while the visible light transmission keeps sufficiently high. The main mechanism of light trapping is related with the excitation of collective oscillations of the metal nanoantenna arrays, characterized by advantageous field distribution in the volume of the solar cell. It allows more than triple increase of infrared photovoltaic absorption.

  8. Total neutron-nucleus cross sections and color transparency

    SciTech Connect (OSTI)

    Jennings, B.K. (TRIUMF, Vancouver, V6T2A3 (Canada)); Miller, G.A. (Nuclear Theory Group, Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1994-05-01T23:59:59.000Z

    The neutron-nucleus cross section at Fermi lab energies is computed using Glauber-Gribov multiple scattering theory. The effects of higher moments in the cross section fluctuations are included and their physical origin discussed. The validity of the frozen approximation is critically examined. These studies of the nucleon-nucleus total cross sections provide a test of the [ital pp][r arrow][ital Xp] diffractive amplitudes used in calculations of color transparency effects.

  9. Facile, Noncovalent Decoration of Graphene Oxide Sheets with Nanocrystals

    E-Print Network [OSTI]

    Chen, Junhong

    [12 14], hydrogen storage media [15 17], and transparent conducting electrodes [18 20, such as in nanocomposites, chemical sensors, biosensors, nanoelectronics, photovoltaic cells, fuel cells, and perhaps for hydrogen storage. Solution-based chemical methods have been reported for the production of graphene

  10. Measurement approaches to support future warhead arms control transparency

    SciTech Connect (OSTI)

    Olinger, C.T.; Frankle, C.M.; Johnson, M.W.; Poths, J.

    1998-12-31T23:59:59.000Z

    Transparency on warhead stockpiles, warhead dismantlement, and fissile material stockpiles in nuclear weapons states will become increasingly important in the move beyond START II toward lower quantities of warheads. Congressional support for further warhead reductions will likely depend on the degree of irreversibility, or in other words, the rapidity with which warhead inventories could be reconstituted. Whether irreversibility considerations can be satisfied will depend on monitoring dismantlement as well as constraining the available stockpile of fissile materials for possible refabrication into warheads. Measurement techniques designed to address the above problems will need to consider NPT Article 1 obligations as well as Russian and US classification regulations, which prohibit or restrict the transfer of nuclear warhead design information to other states. Classification considerations currently limit the potential completeness of future inspections of weapons materials. Many conventional international safeguards approaches are not currently viable for arms control applications because they would reveal weapons design information. The authors discuss a variety of technical measures that may help to improve transparence of warhead and fissile material stockpiles and may enable limited warhead dismantlement transparency.

  11. Conduct of Operations

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-06-29T23:59:59.000Z

    This Order defines the requirements for establishing and implementing Conduct of Operations Programs at Department of Energy (DOE), including National Nuclear Security Administration (NNSA), facilities and projects. Cancels DOE O 5480.19. Admin Chg 1, 6-25-13

  12. Dissecting holographic conductivities

    E-Print Network [OSTI]

    Richard A. Davison; Blaise Goutéraux

    2015-05-19T23:59:59.000Z

    The DC thermoelectric conductivities of holographic systems in which translational symmetry is broken can be efficiently computed in terms of the near-horizon data of the dual black hole. By calculating the frequency dependent conductivities to the first subleading order in the momentum relaxation rate, we give a physical explanation for these conductivities in the simplest such example, in the limit of slow momentum relaxation. Specifically, we decompose each conductivity into the sum of a coherent contribution due to momentum relaxation and an incoherent contribution, due to intrinsic current relaxation. This decomposition is different from those previously proposed, and is consistent with the known hydrodynamic properties in the translationally invariant limit. This is the first step towards constructing a consistent theory of charged hydrodynamics with slow momentum relaxation.

  13. Self-activated ultrahigh chemosensitivity of oxide thin film nanostructures for transparent sensors

    E-Print Network [OSTI]

    Moon, Hi Gyu

    One of the top design priorities for semiconductor chemical sensors is developing simple, low-cost, sensitive and reliable sensors to be built in handheld devices. However, the need to implement heating elements in sensor ...

  14. Dye-sensitized solar cell with a titanium-oxide-modified carbon nanotube transparent electrode

    E-Print Network [OSTI]

    Demir, Hilmi Volkan

    reaction limits their application as a working electrode in a liquid-type dye-sensitized solar cell (DSSC in a DSSC containing iodide/triiodide redox couples. This implementation is realized by inhibiting-sensitized solar cell (DSSC) to date because of their well-known catalytic property to redox reaction. Thus, it has

  15. Indium-Vanadium Oxides Deposited by Radio Frequency Sputtering: New Thin Film Transparent

    E-Print Network [OSTI]

    Artuso, Florinda

    in order to determine their possible applications in electrochromic devices as optically passive ion-vis-NIR transmittance and reflectance modes, have demonstrated that films are electrochromic, but the presence in electrochromic devices (ECD) with variable light transmission ("smart windows").2,3 As has been demonstrated

  16. Low thermal conductivity skutterudites

    SciTech Connect (OSTI)

    Fleurial, J.P.; Caillat, T.; Borshchevsky, A.

    1997-07-01T23:59:59.000Z

    Recent experimental results on semiconductors with the skutterudite crystal structure show that these materials possess attractive transport properties and have a good potential for achieving ZT values substantially larger than for state-of-the-art thermoelectric materials. Both n-type and p-type conductivity samples have been obtained, using several preparation techniques. Associated with a low hole effective mass, very high carrier mobilities, low electrical resistivities and moderate Seebeck coefficients are obtained in p-type skutterudites. For a comparable doping level, the carrier mobilities of n-type samples are about an order of magnitude lower than the values achieved on p-type samples. However, the much larger electron effective masses and Seebeck coefficients on p-type samples. However, the much larger electron effective masses and Seebeck coefficients make n-type skutterudite promising candidates as well. Unfortunately, the thermal conductivities of the binary skutterudites compounds are too large, particularly at low temperatures, to be useful for thermoelectric applications. Several approaches to the reduction of the lattice thermal conductivity in skutterudites are being pursued: heavy doping, formation of solid solutions and alloys, study of novel ternary and filled skutterudite compounds. All those approaches have already resulted in skutterudite compositions with substantially lower thermal conductivity values in these materials. Recently, superior thermoelectric properties in the moderate to high temperature range were achieved for compositions combining alloying and filling of the skutterudite structure. Experimental results and mechanisms responsible for low thermal conductivity in skutterudites are discussed.

  17. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a long time, it was thought that their chemical complexity would preclude their use in device applications. All changed in 2004 with the discovery that the interface between...

  18. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1A Month toA NewAA New RouteAA

  19. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1A Month toA NewAA New RouteAAA

  20. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1A Month toA NewAA New RouteAAAA

  1. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1A Month toA NewAA New

  2. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1A Month toA NewAA NewA New

  3. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1A Month toA NewAA NewA NewA New

  4. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced Charged-CurrentN N U A L R EAAAAAAA

  5. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced Charged-CurrentN N U A L R

  6. Conduct of Operations

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-06-29T23:59:59.000Z

    This Order defines the requirements for establishing and implementing Conduct of Operations Programs at Department of Energy (DOE), including National Nuclear Security Administration (NNSA), facilities and projects. Cancels DOE O 5480.19. Admin Chg 1, dated 6-25-13, cancels DOE O 422.1. Certified 12-3-14.

  7. Conduct of Operations

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-06-29T23:59:59.000Z

    This Order defines the requirements for establishing and implementing Conduct of Operations Programs at Department of Energy (DOE), including National Nuclear Security Administration (NNSA), facilities and projects. Cancels DOE O 5480.19. Admin Chg 2, dated 12-3-14, cancels Admin Chg 1.

  8. Lithium ion conducting electrolytes

    DOE Patents [OSTI]

    Angell, C. Austen (Tempe, AZ); Liu, Changle (Tempe, AZ)

    1996-01-01T23:59:59.000Z

    A liquid, predominantly lithium-conducting, ionic electrolyte having exceptionally high conductivity at temperatures of 100.degree. C. or lower, including room temperature, and comprising the lithium salts selected from the group consisting of the thiocyanate, iodide, bromide, chloride, perchlorate, acetate, tetrafluoroborate, perfluoromethane sulfonate, perfluoromethane sulfonamide, tetrahaloaluminate, and heptahaloaluminate salts of lithium, with or without a magnesium-salt selected from the group consisting of the perchlorate and acetate salts of magnesium. Certain of the latter embodiments may also contain molecular additives from the group of acetonitrile (CH.sub.3 CN) succinnonitrile (CH.sub.2 CN).sub.2, and tetraglyme (CH.sub.3 --O--CH.sub.2 --CH.sub.2 --O--).sub.2 (or like solvents) solvated to a Mg.sup.+2 cation to lower the freezing point of the electrolyte below room temperature. Other particularly useful embodiments contain up to about 40, but preferably not more than about 25, mol percent of a long chain polyether polymer dissolved in the lithium salts to provide an elastic or rubbery solid electrolyte of high ambient temperature conductivity and exceptional 100.degree. C. conductivity. Another embodiment contains up to about but not more than 10 mol percent of a molecular solvent such as acetone.

  9. Lithium ion conducting electrolytes

    DOE Patents [OSTI]

    Angell, C.A.; Liu, C.

    1996-04-09T23:59:59.000Z

    A liquid, predominantly lithium-conducting, ionic electrolyte is described having exceptionally high conductivity at temperatures of 100 C or lower, including room temperature, and comprising the lithium salts selected from the group consisting of the thiocyanate, iodide, bromide, chloride, perchlorate, acetate, tetrafluoroborate, perfluoromethane sulfonate, perfluoromethane sulfonamide, tetrahaloaluminate, and heptahaloaluminate salts of lithium, with or without a magnesium-salt selected from the group consisting of the perchlorate and acetate salts of magnesium. Certain of the latter embodiments may also contain molecular additives from the group of acetonitrile (CH{sub 3}CN), succinnonitrile (CH{sub 2}CN){sub 2}, and tetraglyme (CH{sub 3}--O--CH{sub 2}--CH{sub 2}--O--){sub 2} (or like solvents) solvated to a Mg{sup +2} cation to lower the freezing point of the electrolyte below room temperature. Other particularly useful embodiments contain up to about 40, but preferably not more than about 25, mol percent of a long chain polyether polymer dissolved in the lithium salts to provide an elastic or rubbery solid electrolyte of high ambient temperature conductivity and exceptional 100 C conductivity. Another embodiment contains up to about but not more than 10 mol percent of a molecular solvent such as acetone. 2 figs.

  10. Lithium ion conducting electrolytes

    DOE Patents [OSTI]

    Angell, Charles Austen (Mesa, AZ); Liu, Changle (Midland, MI); Xu, Kang (Montgomery Village, MD); Skotheim, Terje A. (Tucson, AZ)

    1999-01-01T23:59:59.000Z

    The present invention relates generally to highly conductive alkali-metal ion non-crystalline electrolyte systems, and more particularly to novel and unique molten (liquid), rubbery, and solid electrolyte systems which are especially well suited for use with high current density electrolytic cells such as primary and secondary batteries.

  11. Rapid process for producing transparent, monolithic porous glass

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA)

    2006-02-14T23:59:59.000Z

    A process for making transparent porous glass monoliths from gels. The glass is produced much faster and in much larger sizes than present technology for making porous glass. The process reduces the cost of making large porous glass monoliths because: 1) the process does not require solvent exchange nor additives to the gel to increase the drying rates, 2) only moderate temperatures and pressures are used so relatively inexpensive equipment is needed, an 3) net-shape glass monoliths are possible using this process. The process depends on the use of temperature to control the partial pressure of the gel solvent in a closed vessel, resulting in controlled shrinking during drying.

  12. Is the Universe transparent to TeV photons?

    E-Print Network [OSTI]

    W. Kluzniak

    1999-05-26T23:59:59.000Z

    If Lorentz invariance is broken at an energy scale Eq, as has recently been suggested in the context of attempts to quantize gravity, the kinematics of photon-photon collisions would be profoundly affected at lower energies. Specifically, electron-positron pair creation on soft photons may be forbidden at photon energies as low as 30 TeV times square root of (Eq/10**17 GeV) and the Universe would then be transparent to high energy photons. The proposition that Lorentz invariance is broken may be falsified by the techniques of TeV astronomy.

  13. Few-cycle self-induced-transparency solitons

    SciTech Connect (OSTI)

    Lin, Yuan Yao; Chen, I-Hong; Lee, Ray-Kuang [Institute of Photonics Technologies, National Tsing Hua University Hsinchu, Taiwan (China)

    2011-04-15T23:59:59.000Z

    We reveal the existence of an optical self-induced-transparency soliton family in a two-level absorbing system down to the few-cycle limit. Based on the few-cycle envelope approximation, we introduce a systematical method of reducing the Maxwell-Bloch equations beyond the slowly varying envelope approximation and characterize the parameter space to achieve slow and fast lights. Verified by direct numerical simulations with full vectorial Maxwell-Bloch equations, we also give the relationships for a number of optical cycles on area theory and pulse group velocity, which demonstrate possible coherent photon-matter interactions.

  14. Electromagnetically induced transparency in mechanical effects of light

    SciTech Connect (OSTI)

    Agarwal, G. S.; Huang, Sumei [Department of Physics, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)

    2010-04-15T23:59:59.000Z

    We consider the dynamical behavior of a nanomechanical mirror in a high-quality cavity under the action of a coupling laser and a probe laser. We demonstrate the existence of the analog of electromagnetically induced transparency (EIT) in the output field at the probe frequency. Our calculations show explicitly the origin of EIT-like dips as well as the characteristic changes in dispersion from anomalous to normal in the range where EIT dips occur. Remarkably the pump-probe response for the optomechanical system shares all the features of the {Lambda} system as discovered by Harris and collaborators.

  15. Electromagnetically induced transparency with quantized fields in optocavity mechanics

    SciTech Connect (OSTI)

    Huang Sumei; Agarwal, G. S. [Department of Physics, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)

    2011-04-15T23:59:59.000Z

    We report electromagnetically induced transparency (EIT) using quantized fields in optomechanical systems. The weak probe field is a narrowband squeezed field. We present a homodyne detection of EIT in the output quantum field. We find that the EIT dip exists even though the photon number in the squeezed vacuum is at the single-photon level. The EIT with quantized fields can be seen even at temperatures on the order of 100 mK, thus paving the way for using optomechanical systems as memory elements.

  16. Graphene-Silica Composite Thin Films as Transparent Conductors

    E-Print Network [OSTI]

    as fillers for a broad range of composite materials. Attempts to exfoliate graphene-based sheets by intercalation of graphite with potassium metal have been discussed;34 however, the exfoliated nanoplatelets oxide-based sheets35,36 produced by complete exfoliation of graphite oxide (GO) as an entry

  17. Super ionic conductive glass

    DOE Patents [OSTI]

    Susman, Sherman (Park Forest, IL); Volin, Kenneth J. (Fort Collins, CO)

    1984-01-01T23:59:59.000Z

    An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

  18. Cermet fuel thermal conductivity

    E-Print Network [OSTI]

    Alvis, John Mark

    1988-01-01T23:59:59.000Z

    ? ) is expressed by k ( + + ) (3 21) where llg? gap conductance (W/mz-'K) kg? ? conductivity of the gas mixture (W/m-'K) d = actual gap dimension (m) gt gz= temperature jump distances at the fuel and cladding surfaces (cm) The value of d in Equation 3. 21...- ?, )+ ( ") 3 (I- ?, ) - ( ? ) 3 1 yvM trMT b 1+ vF g?T a 1-v?a 1-vF (3. 31) and finally, 2aFBF T 2EMC3M 1 1-2va 1-va 1+vM a (3, 32) 21 Once the constants have been determined, Equation 3. 28 can be solved at the fuel particle outer radius to determine...

  19. Electrically conductive alternating copolymers

    DOE Patents [OSTI]

    Aldissi, M.; Jorgensen, B.S.

    1987-08-31T23:59:59.000Z

    Polymers which are soluble in common organic solvents and are electrically conductive, but which also may be synthesized in such a manner that they become nonconductive. Negative ions from the electrolyte used in the electrochemical synthesis of a polymer are incorporated into the polymer during the synthesis and serve as a dopant. A further electrochemical step may be utilized to cause the polymer to be conductive. The monomer repeat unit is comprised of two rings, a pyrrole molecule joined to a thienyl group, or a furyl group, or a phenyl group. The individual groups of the polymers are arranged in an alternating manner. For example, the backbone arrangement of poly(furylpyrrole) is -furan-pyrrole-furan-pyrrole- furan-pyrrole. An alkyl group or phenyl group may be substituted for either or both of the hydrogen atoms of the pyrrole ring.

  20. High conductivity composite metal

    DOE Patents [OSTI]

    Zhou, R.; Smith, J.L.; Embury, J.D.

    1998-01-06T23:59:59.000Z

    Electrical conductors and methods of producing them are disclosed, where the conductors possess both high strength and high conductivity. Conductors are comprised of carbon steel and a material chosen from a group consisting of copper, nickel, silver, and gold. Diffusion barriers are placed between these two materials. The components of a conductor are assembled and then the assembly is subjected to heat treating and mechanical deformation steps. 10 figs.

  1. High conductivity composite metal

    DOE Patents [OSTI]

    Zhou, Ruoyi (Los Alamos, NM); Smith, James L. (Los Alamos, NM); Embury, John David (Hamilton, CA)

    1998-01-01T23:59:59.000Z

    Electrical conductors and methods of producing them, where the conductors possess both high strength and high conductivity. Conductors are comprised of carbon steel and a material chosen from a group consisting of copper, nickel, silver, and gold. Diffusion barriers are placed between these two materials. The components of a conductor are assembled and then the assembly is subjected to heat treating and mechanical deformation steps.

  2. Conduction cooled tube supports

    DOE Patents [OSTI]

    Worley, Arthur C. (Mt. Tabor, NJ); Becht, IV, Charles (Morristown, NJ)

    1984-01-01T23:59:59.000Z

    In boilers, process tubes are suspended by means of support studs that are in thermal contact with and attached to the metal roof casing of the boiler and the upper bend portions of the process tubes. The support studs are sufficiently short that when the boiler is in use, the support studs are cooled by conduction of heat to the process tubes and the roof casing thereby maintaining the temperature of the stud so that it does not exceed 1400.degree. F.

  3. An Efficient Transparent Test Scheme for Embedded Word-Oriented Memories

    E-Print Network [OSTI]

    Li, Jin-Fu; Wey, Chin-Long

    2011-01-01T23:59:59.000Z

    Memory cores are usually the densest portion with the smallest feature size in system-on-chip (SOC) designs. The reliability of memory cores thus has heavy impact on the reliability of SOCs. Transparent test is one of useful technique for improving the reliability of memories during life time. This paper presents a systematic algorithm used for transforming a bit-oriented march test into a transparent word-oriented march test. The transformed transparent march test has shorter test complexity compared with that proposed in the previous works [Theory of transparent BIST for RAMs, A transparent online memory test for simultaneous detection of functional faults and soft errors in memories]. For example, if a memory with 32-bit words is tested with March C-, time complexity of the transparent word-oriented test transformed by the proposed scheme is only about 56% or 19% time complexity of the transparent word-oriented test converted by the scheme reported in [Theory of transparent BIST for RAMs] or [A transparent...

  4. Experimental tests of dropwise cooling on infrared-transparent media

    SciTech Connect (OSTI)

    Tarozzi, Luca; Muscio, Alberto; Tartarini, Paolo [Department of Mechanical and Civil Engineering, University of Modena and Reggio Emilia, Via Vignolese, 905, 41100 Modena (Italy)

    2007-08-15T23:59:59.000Z

    The present work is aimed at analyzing the cooling of hot solid surfaces induced by liquid droplets. In particular, the study is focused on the non-intrusive measurement of the transient contact temperature between impinging droplets and hot solid surfaces. An experimental apparatus was built and set up in order to approach the non-trivial problem of the measurement of a solid-liquid interface temperature after droplet impingement. The solid-liquid interface temperature was monitored from below through a transparent-to-infrared material. That material had been coated with a very thin layer of high-emissivity, opaque paint on its upper side, so that it could effectively respond to the infrared camera located below. The paper reports the main results that have been collected to date, with particular regard to the approaches used to coat the transparent solid. Some considerations are also expressed about the effectiveness of the proposed method and about the improvements that are currently being implemented to get new and more accurate interface temperature measurements. (author)

  5. TRANSPORT INVOLVING CONDUCTING FIBERS IN A NON-CONDUCTING MATRIX

    E-Print Network [OSTI]

    Walker, D. Greg

    to sev- eral applications including flexible thin-film transistors, PEM fuel cells, and direct energy, particularly Peltier devices, high electrical conductivity and low thermal conductivity are preferred

  6. Oxidation catalyst

    DOE Patents [OSTI]

    Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

    2010-11-09T23:59:59.000Z

    The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

  7. Conductance modulation in topological insulator Bi{sub 2}Se{sub 3} thin films with ionic liquid gating

    SciTech Connect (OSTI)

    Son, Jaesung; Banerjee, Karan; Yang, Hyunsoo, E-mail: eleyang@nus.edu.sg [Department of Electrical and Computer Engineering, National University of Singapore, 4 Engineering Drive 3, Singapore 117576 (Singapore)] [Department of Electrical and Computer Engineering, National University of Singapore, 4 Engineering Drive 3, Singapore 117576 (Singapore); Brahlek, Matthew; Koirala, Nikesh; Oh, Seongshik [Department of Physics and Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, New Jersey 08854 (United States)] [Department of Physics and Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, New Jersey 08854 (United States); Lee, Seoung-Ki [School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of) [School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); School of Electrical and Electronic Engineering, Yonsei University, Seoul 120-749 (Korea, Republic of); Ahn, Jong-Hyun [School of Electrical and Electronic Engineering, Yonsei University, Seoul 120-749 (Korea, Republic of)] [School of Electrical and Electronic Engineering, Yonsei University, Seoul 120-749 (Korea, Republic of)

    2013-11-18T23:59:59.000Z

    A Bi{sub 2}Se{sub 3} topological insulator field effect transistor is investigated by using ionic liquid as an electric double layer gating material, leading to a conductance modulation of 365% at room temperature. We discuss the role of charged impurities on the transport properties. The conductance modulation with gate bias is due to a change in the carrier concentration, whereas the temperature dependent conductance change is originated from a change in mobility. Large conductance modulation at room temperature along with the transparent optical properties makes topological insulators as an interesting (opto)electronic material.

  8. Optical storage with electromagnetically induced transparency in a dense cold atomic ensemble

    E-Print Network [OSTI]

    Du, Shengwang

    Optical storage with electromagnetically induced transparency in a dense cold atomic ensemble storage with electromagnetically induced transparency in a dense cold 85 Rb atomic ensemble. By varying the optical depth (OD) from 0 to 140, we observe that the optimal storage effi- ciency has a saturation value

  9. Elastic properties of transparent nano-polycrystalline diamond measured by GHz-ultrasonic interferometry and resonant

    E-Print Network [OSTI]

    Jacobsen, Steven D.

    Elastic properties of transparent nano-polycrystalline diamond measured by GHz-ultrasonic interferometry Sphere resonance Nano-polycrystalline diamond NPD Elastic properties Superhard materials a b s t r a c t The sound velocities and elastic moduli of transparent nano-polycrystalline diamond (NPD) have

  10. Middleware Transparent Software Development & the MDA Devon Simmonds, Sudipto Ghosh, Robert France

    E-Print Network [OSTI]

    Simmonds, Devon M.

    Middleware Transparent Software Development & the MDA Devon Simmonds, Sudipto Ghosh, Robert France of middleware technologies and the pervasiveness of distributed systems. The Model Driven Architecture (MDA of the target middleware. To support the MDA vision we have developed an aspect-oriented middleware transparent

  11. On the Benefits of Transparent Compression for Cost-Effective Cloud Data Storage

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    On the Benefits of Transparent Compression for Cost-Effective Cloud Data Storage Bogdan Nicolae of IaaS middleware: excessive storage costs associated with both user data and VM images might make-off resulting from transparently applying data compression to conserve storage space and bandwidth at the cost

  12. ISIS technical report series, Vol. 2002-06 User Transparency: A Fully Sequential

    E-Print Network [OSTI]

    Seinstra, Frank J.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 4 A Sustainable Software Architecture for User Transparent Parallel Image Processing 12 4 to provide such a tool, we have designed a software architecture that allows transparent (i.e., se- quential the software architecture, and gives an assessment of the architecture's effectiveness in providing signif

  13. ISIS technical report series, Vol. 2002-06 User Transparency: A Fully Sequential

    E-Print Network [OSTI]

    Seinstra, Frank J.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 4 A Sustainable Software Architecture for User Transparent Parallel Image Processing 12 4 to provide such a tool, we have designed a software architecture that allows transparent (i.e., se- quential the software architecture, and gives an assessment of the architecture's e#11;ectiveness in providing signif

  14. Infrared transparent frequency selective surface based on metallic meshes

    SciTech Connect (OSTI)

    Yu, Miao [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China) [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China); University of Chinese Academy of Sciences, Beijing, 100049 (China); Xu, Nianxi; Liu, Hai; Gao, Jinsong, E-mail: gaojs@ciomp.ac.cn [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China)] [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China)

    2014-02-15T23:59:59.000Z

    This paper presents an infrared transparent frequency selective surface (ITFSS) based on metallic meshes. In this ITFSS structure, periodic cross-slot units are integrated on square metallic meshes empowered by coating and UV-lithography. A matching condition is proposed to avoid the distortion of units. Experimental results show that this ITFSS possesses a good transmittance of 80% in the infrared band of 3–5 ?m, and also a stable band-pass behavior at the resonance frequency of 36.4 GHz with transmittance of ?0.56 dB. Theoretical simulations about the ITFSS diffractive characteristics and frequency responses are also investigated. The novel ITFSS will attract renewed interest and be exploited for applications in various fields.

  15. Optically transparent, scratch-resistant, diamond-like carbon coatings

    DOE Patents [OSTI]

    He, Xiao-Ming; Lee, Deok-Hyung; Nastasi, Michael A.; Walter, Kevin C.; Tuszewski, Michel G.

    2003-06-03T23:59:59.000Z

    A plasma-based method for the deposition of diamond-like carbon (DLC) coatings is described. The process uses a radio-frequency inductively coupled discharge to generate a plasma at relatively low gas pressures. The deposition process is environmentally friendly and scaleable to large areas, and components that have geometrically complicated surfaces can be processed. The method has been used to deposit adherent 100-400 nm thick DLC coatings on metals, glass, and polymers. These coatings are between three and four times harder than steel and are therefore scratch resistant, and transparent to visible light. Boron and silicon doping of the DLC coatings have produced coatings having improved optical properties and lower coating stress levels, but with slightly lower hardness.

  16. Tunable electromagnetically induced transparency and absorption with dressed superconducting qubits

    SciTech Connect (OSTI)

    Ian, Hou [Advanced Science Institute, RIKEN, Wako-shi, Saitama 351-0198 (Japan); Liu, Yu-xi [Advanced Science Institute, RIKEN, Wako-shi, Saitama 351-0198 (Japan); Institute of Microelectronics, Tsinghua University, Beijing 100084 (China); Tsinghua National Laboratory for Information Science and Technology (TNList), Tsinghua University, Beijing 100084 (China); Nori, Franco [Advanced Science Institute, RIKEN, Wako-shi, Saitama 351-0198 (Japan); Physics Department, The University of Michigan, Ann Arbor, Michagan 48109 (United States)

    2010-06-15T23:59:59.000Z

    Electromagnetically induced transparency and absorption (EIT and EIA) are usually demonstrated using three-level atomic systems. In contrast to the usual case, we theoretically study the EIT and EIA in an equivalent three-level system: a superconducting two-level system (qubit) dressed by a single-mode cavity field. In this equivalent system, we find that both the EIT and the EIA can be tuned by controlling the level-spacing of the superconducting qubit and hence controlling the dressed system. This tunability is due to the dressed relaxation and dephasing rates which vary parametrically with the level-spacing of the original qubit and thus affect the transition properties of the dressed qubit and the susceptibility. These dressed relaxation and dephasing rates characterize the reaction of the dressed qubit to an incident probe field. Using recent experimental data on superconducting qubits (charge, phase, and flux qubits) to demonstrate our approach, we show the possibility of experimentally realizing this proposal.

  17. Tunable electromagnetically induced transparency with a coupled superconducting system

    E-Print Network [OSTI]

    Xin Wang; Hong-rong Li; Wen-xiao Liu; Fu-li Li

    2015-02-08T23:59:59.000Z

    Electromagnetically induced transparency (EIT) has usually been demonstrated by using three-level atomic systems. In this paper, we theoretically proposed an efficient method to realize EIT in microwave regime through a coupled system consisting of a flux qubit and a superconducting LC resonator with relatively high quality factor. In the present composed system, the working levels are the dressed states of a two-level flux qubit and the resonators with a probe pump field. There exits a second order coherent transfer between the dressed states. By comparing the results with those in the conventional atomic system we have revealed the physical origin of the EIT phenomenon in this composed system. Since the whole system is artificial and tunable, our scheme may have potential applications in various domains.

  18. Semi-transparent solar energy thermal storage device

    DOE Patents [OSTI]

    McClelland, John F. (Ames, IA)

    1985-06-18T23:59:59.000Z

    A visually transmitting solar energy absorbing thermal storage module includes a thermal storage liquid containment chamber defined by an interior solar absorber panel, an exterior transparent panel having a heat mirror surface substantially covering the exterior surface thereof and associated top, bottom and side walls, Evaporation of the thermal storage liquid is controlled by a low vapor pressure liquid layer that floats on and seals the top surface of the liquid. Porous filter plugs are placed in filler holes of the module. An algicide and a chelating compound are added to the liquid to control biological and chemical activity while retaining visual clarity. A plurality of modules may be supported in stacked relation by a support frame to form a thermal storage wall structure.

  19. Semi-transparent solar energy thermal storage device

    DOE Patents [OSTI]

    McClelland, John F. (Ames, IA)

    1986-04-08T23:59:59.000Z

    A visually transmitting solar energy absorbing thermal storage module includes a thermal storage liquid containment chamber defined by an interior solar absorber panel, an exterior transparent panel having a heat mirror surface substantially covering the exterior surface thereof and associated top, bottom and side walls. Evaporation of the thermal storage liquid is controlled by a low vapor pressure liquid layer that floats on and seals the top surface of the liquid. Porous filter plugs are placed in filler holes of the module. An algicide and a chelating compound are added to the liquid to control biological and chemical activity while retaining visual clarity. A plurality of modules may be supported in stacked relation by a support frame to form a thermal storage wall structure.

  20. Electromagnetically Induced Transparency and Slow Light with Optomechanics

    E-Print Network [OSTI]

    Safavi-Naeini, Amir H; Chan, Jasper; Eichenfield, Matt; Winger, Martin; Lin, Qiang; Hill, Jeffrey T; Chang, Darrick; Painter, Oskar

    2010-01-01T23:59:59.000Z

    Controlling the interaction between localized optical and mechanical excitations has recently become possible following advances in micro- and nano-fabrication techniques. To date, most experimental studies of optomechanics have focused on measurement and control of the mechanical subsystem through its interaction with optics, and have led to the experimental demonstration of dynamical back-action cooling and optical rigidity of the mechanical system. Converseley, the optical response of these systems is also modified in the presence of mechanical interactions, leading to strong nonlinear optical effects such as Electromagnetically Induced Transparency (EIT) and parametric normal-mode splitting. In atomic systems, seminal experiments and proposals to slow and stop the propagation of light, and their applicability to modern optical networks, and future quantum networks, have thrust EIT to the forefront of experimental study during the last two decades. In a similar fashion, here we use the optomechanical nonli...

  1. Lateral conduction infrared photodetector

    DOE Patents [OSTI]

    Kim, Jin K. (Albuquerque, NM); Carroll, Malcolm S. (Albuquerque, NM)

    2011-09-20T23:59:59.000Z

    A photodetector for detecting infrared light in a wavelength range of 3-25 .mu.m is disclosed. The photodetector has a mesa structure formed from semiconductor layers which include a type-II superlattice formed of alternating layers of InAs and In.sub.xGa.sub.1-xSb with 0.ltoreq.x.ltoreq.0.5. Impurity doped regions are formed on sidewalls of the mesa structure to provide for a lateral conduction of photo-generated carriers which can provide an increased carrier mobility and a reduced surface recombination. An optional bias electrode can be used in the photodetector to control and vary a cut-off wavelength or a depletion width therein. The photodetector can be formed as a single-color or multi-color device, and can also be used to form a focal plane array which is compatible with conventional read-out integrated circuits.

  2. Electromagnetically Induced Transparency and Slow Light with Optomechanics

    E-Print Network [OSTI]

    Amir H. Safavi-Naeini; Thiago P. Mayer Alegre; Jasper Chan; Matt Eichenfield; Martin Winger; Qiang Lin; Jeffrey T. Hill; Darrick Chang; Oskar Painter

    2010-12-14T23:59:59.000Z

    Controlling the interaction between localized optical and mechanical excitations has recently become possible following advances in micro- and nano-fabrication techniques. To date, most experimental studies of optomechanics have focused on measurement and control of the mechanical subsystem through its interaction with optics, and have led to the experimental demonstration of dynamical back-action cooling and optical rigidity of the mechanical system. Conversely, the optical response of these systems is also modified in the presence of mechanical interactions, leading to strong nonlinear effects such as Electromagnetically Induced Transparency (EIT) and parametric normal-mode splitting. In atomic systems, seminal experiments and proposals to slow and stop the propagation of light, and their applicability to modern optical networks, and future quantum networks, have thrust EIT to the forefront of experimental study during the last two decades. In a similar fashion, here we use the optomechanical nonlinearity to control the velocity of light via engineered photon-phonon interactions. Our results demonstrate EIT and tunable optical delays in a nanoscale optomechanical crystal device, fabricated by simply etching holes into a thin film of silicon (Si). At low temperature (8.7 K), we show an optically-tunable delay of 50 ns with near-unity optical transparency, and superluminal light with a 1.4 microseconds signal advance. These results, while indicating significant progress towards an integrated quantum optomechanical memory, are also relevant to classical signal processing applications. Measurements at room temperature and in the analogous regime of Electromagnetically Induced Absorption (EIA) show the utility of these chip-scale optomechanical systems for optical buffering, amplification, and filtering of microwave-over-optical signals.

  3. Electrically conductive polycrystalline diamond and particulate metal based electrodes

    DOE Patents [OSTI]

    Swain, Greg M.; Wang, Jian

    2005-04-26T23:59:59.000Z

    An electrically conducting and dimensionally stable diamond (12, 14) and metal particle (13) electrode produced by electrodepositing the metal on the diamond is described. The electrode is particularly useful in harsh chemical environments and at high current densities and potentials. The electrode is particularly useful for generating hydrogen, and for reducing oxygen and oxidizing methanol in reactions which are of importance in fuel cells.

  4. Do More Transparent Corporate Actions Following a Restatement Influence the SEC's Decision to Issue an Enforcement Action? 

    E-Print Network [OSTI]

    Files, Rebecca Lynn

    2010-10-12T23:59:59.000Z

    This study examines whether corporate transparency about a restatement influences the Securities and Exchange Commission's (SEC) decision to issue an enforcement action. I consider corporate transparency to be higher when ...

  5. Electromagnetically induced transparency and four-wave mixing in a cold atomic ensemble with large optical depth

    E-Print Network [OSTI]

    J. Geng; G. T. Campbell; J. Bernu; D. Higginbottom; B. M. Sparkes; S. M. Assad; W. P. Zhang; N. P. Robins; P. K. Lam; B. C. Buchler

    2014-08-11T23:59:59.000Z

    We report on the delay of optical pulses using electromagnetically induced transparency in an ensemble of cold atoms with an optical depth exceeding 500. To identify the regimes in which four-wave mixing impacts on EIT behaviour, we conduct the experiment in both rubidium 85 and rubidium 87. Comparison with theory shows excellent agreement in both isotopes. In rubidium 87, negligible four-wave mixing was observed and we obtained one pulse-width of delay with 50% efficiency. In rubidium 85, four-wave-mixing contributes to the output. In this regime we achieve a delay-bandwidth product of 3.7 at 50% efficiency, allowing temporally multimode delay, which we demonstrate by compressing two pulses into the memory medium.

  6. Synthesis of High-Purity alpha-and beta-PbO and Possible Applications to Synthesis and Processing of Other Lead Oxide Materials

    E-Print Network [OSTI]

    Perry, Dale L.

    2011-01-01T23:59:59.000Z

    and Processing of Other Lead Oxide Materials D. L. PERRY andred, tetragonal form of lead oxide, ?-PbO, litharge, and thedifferent conducting lead oxides and other related materials

  7. Aluminum Foil Mediated Noncatalytic Growth of ZnO Nanowire Arrays on an Indium Tin Oxide Substrate

    E-Print Network [OSTI]

    Kim, Bongsoo

    substrate would find useful applications in field emission displays and solar cells. Introduction Zinc oxide in optoelectronics such as field emission displays (FEDs) and solar cells.3,4 Developing convenient and reproducible applications because it has been widely used as a transparent electrode in conventional flat panel displays

  8. Gas Code of Conduct (Connecticut)

    Broader source: Energy.gov [DOE]

    The Gas Code of Conduct sets forth the standard of conduct for transactions, direct or indirect, between gas companies and their affiliates. The purpose of these regulations is to promote...

  9. Thermal Conductivity of Coated Paper

    SciTech Connect (OSTI)

    Kerr, Lei L [ORNL; Pan, Yun-Long [Smart Papers, Hamilton, OH 45013; Dinwiddie, Ralph Barton [ORNL; Wang, Hsin [ORNL; Peterson, Robert C. [Miami University, Oxford, OH

    2009-01-01T23:59:59.000Z

    In this paper, we introduce a method for measuring the thermal conductivity of paper using a hot disk system. To the best of our knowledge, few publications are found discussing the thermal conductivity of a coated paper although it is important to various forms of today s digital printing where heat is used for imaging as well as for toner fusing. This motivates us to investigate the thermal conductivity of paper coating. Our investigation demonstrates that thermal conductivity is affected by the coat weight and the changes in the thermal conductivity affect ink gloss and density. As the coat weight increases, the thermal conductivity increases. Both the ink gloss and density decrease as the thermal conductivity increases. The ink gloss appears to be more sensitive to the changes in the thermal conductivity.

  10. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming (Framingham, MA); Chung, Sung-Yoon (Seoul, KR); Bloking, Jason T. (Cambridge, MA); Andersson, Anna M. (Uppsala, SE)

    2008-03-18T23:59:59.000Z

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z(A.sub.1-aM''.sub.a).s- ub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001conductivity at 27.degree. C. of at least about 10.sup.-8 S/cm. The compound can be a doped lithium phosphate that can intercalate lithium or hydrogen. The compound can be used in an electrochemical device including electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

  11. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming (Framingham, MA); Chung, Sung-Yoon (Incheon, KR); Bloking, Jason T. (Mountain View, CA); Andersson, Anna M. (Vasteras, SE)

    2012-04-03T23:59:59.000Z

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z (A.sub.1-aM''.sub.a).sub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001conductivity at 27.degree. C. of at least about 10.sup.-8 S/cm. The compound can be a doped lithium phosphate that can intercalate lithium or hydrogen. The compound can be used in an electrochemical device including electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

  12. Ab-initio Kinetic Monte Carlo Model of Ionic Conduction in Bulk Yttria-stabilized Zirconia

    E-Print Network [OSTI]

    Cai, Wei

    oxide fuel cell (SOFC) and oxygen sensor, and hence has been extensively studied. In particular, the necessity of reducing the operating temperature of SOFC without losing ionic conductivity encourages

  13. Dipole induced transparency in drop-filter cavity-waveguide systems

    E-Print Network [OSTI]

    Edo Waks; Jelena Vuckovic

    2005-12-05T23:59:59.000Z

    We show that a waveguide that is normally opaque due to interaction with a drop-filter cavity can be made transparent when the drop filter is also coupled to a dipole. A transparency condition is derived between the cavity lifetime and vacuum Rabi frequency of the dipole. This condition is much weaker than strong coupling, and amounts to simply achieving large Purcell factors. Thus, we can observe transparency in the weak coupling regime. We describe how this effect can be useful for designing quantum repeaters for long distance quantum communication.

  14. Electromagnetically-induced transparency and light storing of a pair of pulses

    E-Print Network [OSTI]

    A. Raczynski; J. Zaremba; S. Zielinska-Kaniasty

    2003-07-30T23:59:59.000Z

    Electromagnetically-induced transparency and light storing are studied in the case of a medium of atoms in a double Lambda configuration, both in terms of dark- and bright-state polatitons and atomic susceptibility. It is proven that the medium can be made transparent simultaneously for two pulses following their self-adjusting so that a condition for an adiabatic evolution has become fulfilled. Analytic formulas are given for the shapes and phases of the transmitted/stored pulses. The level of transparency can be regulated by adjusting the heights and phases of the control fields.

  15. Oxidation Characteristics of Fe-18Cr-18Mn-stainless alloys

    SciTech Connect (OSTI)

    James Rawers

    2010-10-01T23:59:59.000Z

    Air oxidation studies of Fe-18Cr-18Mn stainless steels were conducted at 525°C, 625°C, and 725°C. Alloys were evaluated with respect to changes in oxidation properties as a result of interstitial additions of nitrogen and carbon and of minor solute additions of silicon, molybdenum, and nickel. Interstitial concentrations possibly had a small, positive effect on oxidation resistance. Minor solute additions significantly improved oxidation resistance but could also reduce interstitial solubility resulting in formation of chromium carbides. Loss of solute chromium resulted in a slight reduction in oxidation protection. Oxidation lasting over 500 hours produced a manganese rich, duplex oxide structure: an outer sesquioxide and an inner spinel oxide.

  16. Tunable Electromagnetically Induced Transparency and Absorption with Dressed Superconducting Qubits

    E-Print Network [OSTI]

    Hou Ian; Yu-xi Liu; Franco Nori

    2010-07-06T23:59:59.000Z

    Electromagnetically induced transparency and absorption (EIT and EIA) are usually demonstrated by three-level atomic or atom-like systems. In contrast to the usual case, we theoretically study the EIT and EIA in an equivalent three-level system, which is constructed by dressing a superconducting two-level system (qubit) dressed by a single-mode cavity field. In this equivalent system, we find that both the EIT and the EIA can be tuned by controlling the level-spacing of the superconducting qubit and hence controlling the dressed system. This tunability is due to the dressed relaxation and dephasing rates which vary parametrically with the level-spacing of the original qubit and thus affect the transition properties of the dressed qubit and the susceptibility. These dressed relaxation and dephasing rates characterize the reaction of the dressed qubit to an incident probe field. We also use recent experimental data on superconducting qubits (charge, phase, and flux qubits) to demonstrate our approach and show the possibility of experimentally realizing this proposal.

  17. Improving chemical vapor deposition graphene conductivity using molybdenum trioxide: An in-situ field effect transistor study

    SciTech Connect (OSTI)

    Han, Cheng [Department of Physics and Institute for Advanced Study, Nanchang University, 999 Xue Fu Da Dao, Nanchang (China) [Department of Physics and Institute for Advanced Study, Nanchang University, 999 Xue Fu Da Dao, Nanchang (China); Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Lin, Jiadan; Xiang, Du [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore)] [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Wang, Chaocheng; Wang, Li [Department of Physics and Institute for Advanced Study, Nanchang University, 999 Xue Fu Da Dao, Nanchang (China)] [Department of Physics and Institute for Advanced Study, Nanchang University, 999 Xue Fu Da Dao, Nanchang (China); Chen, Wei [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore) [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 and Graphene Research Centre, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore)

    2013-12-23T23:59:59.000Z

    By using in situ field effect transistor characterization integrated with molecular beam epitaxy technique, we demonstrate the strong surface transfer p-type doping effect of single layer chemical vapor deposition (CVD) graphene, through the surface functionalization of molybdenum trioxide (MoO{sub 3}) layer. After doping, both the hole and electron mobility of CVD graphene are nearly retained, resulting in significant enhancement of graphene conductivity. With coating of 10 nm MoO{sub 3}, the conductivity of CVD graphene can be increased by about 7 times, showing promising application for graphene based electronics and transparent, conducting, and flexible electrodes.

  18. Programmable window : a large-scale transparent electronic display using SPD film

    E-Print Network [OSTI]

    Ramos, Martin (Ramos Rizo-Patron)

    2004-01-01T23:59:59.000Z

    This research demonstrates that Suspended Particle Device (SPD) film is a viable option for the development of large-scale transparent display systems. The thesis analyzes the SPD film from an architectural display application ...

  19. GC Commits to Transparency on Nuclear Waste Fund Fee Adequacy Decisions

    Broader source: Energy.gov [DOE]

    Consistent with the Administration's commitment to transparency, DOE General Counsel Scott Blake Harris has decided that all future determinations as to the adequacy of the Nuclear Waste Fund fee...

  20. Evidence for the Onset of Color Transparency in ?0 Electroproduction off Nuclei

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, L; Hanretty, C; Hicks, K; Holt, R J; Hyde, C E; Ilieva, Y; Ireland, D G; Ishkhanov, B S; Isupov, E L; Jawalker, S S; Keller, D; Khandaker, M; Kheterpal, P; Kim, A; Kim, W; Klein, A; Klein, F J; Kubarovsky, V; Kuhn, S E; Kuleshov, S V; Kuznetsov, V; Laget, J M; Lu, H Y; MacGregor, I.D. J; Mao, Y; Markov, N; Mayer, M; McAndrew, J; McKinnon, B; Meyer, C A; Mineeva, T; Mirazita, M; Mokeev, V; Moreno, B; Moutarde, H; Muneva, E; Nadel-Turonski, P; Ni, A; Niccolai, S; Niculescu, G; Niculescu, I; Osipenko, M; Ostrovidov, A I; Pappalardo, L; Paremuzyan, R; Park, K; Park, S; Pasyuk, E; Anefalos Pereira, S; Phelps, E; Pisano, S; Pozdniakov, S; Price, J W; Procureur, S; Protopopescu, D; Raue, B A; Reimer, P E; Ricco, G; Rimal, D; Ripani, M; Ritchie, B G; Rosner, G; Rossi, P; Sabatie, F; Saini, M S; Salgado, C; Schott, D; Schumacher, R A; Seraydaryan, H; Sharabian, Y G; Smith, E S; Smith, G D; Sober, D I; Sokhan, D; Stepanyan, S S; Stepanyan, S; Stoler, P; Strauch, S; Taiuti, M; Tang, W; Taylor, C E; Tedeschi, D J; Tkachenko, S; Ungaro, M; Vernarsky, B; Vineyard, M F; Voskanyan, H; Voutier, E; Watts, D; Weinstein, L B; Weygand, D P; Wood, M H; Zachariou, N; Zhao, B; Zhao, Z W

    2012-06-12T23:59:59.000Z

    We have measured the nuclear transparency of the incoherent diffractive A(e,e'?0) process in 12C and 56Fe targets relative to 2H using a 5 GeV electron beam. The nuclear transparency, the ratio of the produced {rho}{sup 0}'s on a nucleus relative to deuterium, which is sensitive to ?A interaction, was studied as function of the coherence length (Ic), a lifetime of the hadronic fluctuation of the virtual photon, and the four-momentum transfer squared (Q2). While the transparency for both 12C and 56Fe showed no Ic dependence, a significant Q2 dependence was measured, which is consistent with calculations that included the color transparency effects.

  1. Synthesis of mono-to-multi-layer graphene for transparent electrode applications

    E-Print Network [OSTI]

    Choi, Minseok

    2012-01-01T23:59:59.000Z

    In this thesis, mono-to-multilayer graphene for transparent electrode applications was synthesized by Atmospheric Pressure Chemical Vapor Deposition (APCVD) and the key factors that determine the electrical and optical ...

  2. Patternable transparent carbon nanotube films for electrochromic devices Liangbing Hu and George Grunera

    E-Print Network [OSTI]

    Gruner, George

    Patternable transparent carbon nanotube films for electrochromic devices Liangbing Hu and George nanotube films on polyethylene terephthalate as flexible electrodes in electrochromic devices using. Electrochromic devices attract much interest due to their potential use in applications such as smart windows

  3. Polymer material selection and testing of resistive wire arrangement for a transparent infant warming blanket

    E-Print Network [OSTI]

    Salazar, Madeline

    2013-01-01T23:59:59.000Z

    The ThermoCloud was designed as a portable, scalable, transparent electrical blanket to warm and insulate infants, while permitting hassle-free medical transportation and maximum visualization of a patient's thorax and ...

  4. Evidence for the Onset of Color Transparency in $?^0$ Electroproduction off Nuclei

    E-Print Network [OSTI]

    L. El Fassi; L. Zana; K. Hafidi; M. Holtrop; B. Mustapha; W. K. Brooks; H. Hakobyan; X. Zheng; K. P. Adhikari; D. Adikaram; M. Aghasyan; M. J. Amaryan; M. Anghinolfi; J. Arrington; H. Avakian; H. Baghdasaryan; M. Battaglieri; V. Batourine; I. Bedlinskiy; A. S. Biselli; C. Bookwalter; D. Branford; W. J. Briscoe; S. Bultmann; V. D. Burkert; D. S. Carman; A. Celentano; S. Chandavar; P. L. Cole; M. Contalbrigo; V. Crede; A. D'Angelo; A. Daniel; N. Dashyan; R. De Vita; E. De Sanctis; A. Deur; B. Dey; R. Dickson; C. Djalali; G. E. Dodge; D. Doughty; R. Dupre; H. Egiyan; A. El Alaoui; L. Elouadrhiri; P. Eugenio; G. Fedotov; S. Fegan; M. Y. Gabrielyan; M. Garcon; N. Gevorgyan; G. P. Gilfoyle; K. L. Giovanetti; F. X. Girod; J. T. Goetz; W. Gohn; E. Golovatch; R. W. Gothe; K. A. Griffioen; M. Guidal; L. Guo; C. Hanretty; D. Heddle; K. Hicks; R. J. Holt; C. E. Hyde; Y. Ilieva; D. G. Ireland; B. S. Ishkhanov; E. L. Isupov; S. S. Jawalkar; D. Keller; M. Khandaker; P. Khetarpal; A. Kim; W. Kim; A. Klein; F. J. Klein; V. Kubarovsky; S. E. Kuhn; S. V. Kuleshov; V. Kuznetsov; J. M. Laget; H. Y. Lu; I. J. D. MacGregor; Y. Mao; N. Markov; M. Mayer; J. McAndrew; B. McKinnon; C. A. Meyer; T. Mineeva; M. Mirazita; V. Mokeev; B. Moreno; H. Moutarde; E. Munevar; P. Nadel-Turonski; A. Ni; S. Niccolai; G. Niculescu; I. Niculescu; M. Osipenko; A. I. Ostrovidov; L. Pappalardo; R. Paremuzyan; K. Park; S. Park; E. Pasyuk; S. Anefalos Pereira; E. Phelps; S. Pisano; S. Pozdniakov; J. W. Price; S. Procureur; D. Protopopescu; B. A. Raue; P. E. Reimer; G. Ricco; D. Rimal; M. Ripani; B. G. Ritchie; G. Rosner; P. Rossi; F. Sabatie; M. S. Saini; C. Salgado; D. Schott; R. A. Schumacher; H. Seraydaryan; Y. G. Sharabian; E. S. Smith; G. D. Smith; D. I. Sober; D. Sokhan; S. S. Stepanyan; S. Stepanyan; P. Stoler; S. Strauch; M. Taiuti; W. Tang; C. E. Taylor; D. J. Tedeschi; S. Tkachenko; M. Ungaro; B . Vernarsky; M. F. Vineyard; H. Voskanyan; E. Voutier; D. Watts; L. B. Weinstein; D. P. Weygand; M. H. Wood; N. Zachariou; B. Zhao; Z. W. Zhao

    2012-05-11T23:59:59.000Z

    We have measured the nuclear transparency of the incoherent diffractive $A(e,e'\\rho^0)$ process in $^{12}$C and $^{56}$Fe targets relative to $^2$H using a 5 GeV electron beam. The nuclear transparency, the ratio of the produced $\\rho^0$'s on a nucleus relative to deuterium, which is sensitive to $\\rho A$ interaction, was studied as function of the coherence length ($l_c$), a lifetime of the hadronic fluctuation of the virtual photon, and the four-momentum transfer squared ($Q^2$). While the transparency for both $^{12}$C and $^{56}$Fe showed no $l_c$ dependence, a significant $Q^2$ dependence was measured, which is consistent with calculations that included the color transparency effects.

  5. Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt

    E-Print Network [OSTI]

    Suo, Zhigang

    Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt 2014; published online 14 October 2014) Polyacrylamide hydrogels containing salt as electrolyte have of polyacrylamide hydrogel by introducing highly hydratable salts into the hydrogel. These hydrogels show enhanced

  6. Demonstration of a hitless bypass switch using nanomechanical perturbation for high-bitrate transparent networks

    E-Print Network [OSTI]

    Chatterjee, Rohit

    We demonstrate an optical hitless bypass switch based on nanomechanical proximity perturbation for high-bitrate transparent networks. Embedded in a single-level ?-imbalanced Mach-Zehnder interferometer, the two ...

  7. Transparent, near-infrared organic photovoltaic solar cells for window and energy-scavenging applications

    E-Print Network [OSTI]

    Lunt, Richard R.

    We fabricate near-infrared absorbing organic photovoltaics that are highly transparent to visible light. By optimizing near-infrared optical-interference, we demonstrate power efficiencies of 1.3±0.1% with simultaneous ...

  8. Measurement of nuclear transparency from A(e,e'[pi]?) reactions

    E-Print Network [OSTI]

    Clasie, Benjamin Michael Patrick

    2006-01-01T23:59:59.000Z

    The color transparency phenomenon refers to the suppression of final-state interactions of a hadron propagating through the nuclear medium at large momentum transfer when the hadron is produced with small transverse size. ...

  9. Thick and Thin Film Polymer CNT Nanocomposites for Thermoelectric Energy Conversion and Transparent Electrodes

    E-Print Network [OSTI]

    Fisher, Frank

    Thick and Thin Film Polymer ­ CNT Nanocomposites for Thermoelectric Energy Conversion gradient. Thermoelectric materials harvest electricity from waste heat or any temperature gradient]. The PDDA/(SWNT+DOC) system produced transparent (> 82% visible light transmittance) and electrically

  10. Color transparency and high-energy ( p ,2 p ) nuclear reactions

    SciTech Connect (OSTI)

    Lee, T.H. (Physics Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)); Miller, G.A. (Department of Physics FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1992-04-01T23:59:59.000Z

    Predictions relevant for exploring color transparency in ({ital p},2{ital p}) nuclear reactions are often made by using simplified treatments of nuclear dynamics. We examine the extent to which the earlier predictions are valid by carrying out calculations using an improved treatment of the proton scattering wave functions, nucleon Fermi motion, and the effects of long- and short-range nuclear correlations. The consequences of two existing models of color transparency are also presented.

  11. Transparent building-integrated PV modules. Phase 1: Comprehensive report

    SciTech Connect (OSTI)

    NONE

    1998-09-28T23:59:59.000Z

    This Comprehensive Report encompasses the activities that have been undertaken by Kiss + Cathcart, Architects, in conjunction with Energy Photovoltaics, Incorporated (EPV), to develop a flexible patterning system for thin-film photovoltaic (PV) modules for building applications. There are two basic methods for increasing transparency/light transmission by means of patterning the PV film: widening existing scribe lines, or scribing a second series of lines perpendicular to the first. These methods can yield essentially any degree of light transmission, but both result in visible patterns of light and dark on the panel surface. A third proposed method is to burn a grid of dots through the films, independent of the normal cell scribing. This method has the potential to produce a light-transmitting panel with no visible pattern. Ornamental patterns at larger scales can be created using combinations of these techniques. Kiss + Cathcart, Architects, in conjunction with EPV are currently developing a complementary process for the large-scale lamination of thin-film PVs, which enables building integrated (BIPV) modules to be produced in sizes up to 48 in. x 96 in. Flexible laser patterning will be used for three main purposes, all intended to broaden the appeal of the product to the building sector: To create semitransparent thin-film modules for skylights, and in some applications, for vision glazing.; to create patterns for ornamental effects. This application is similar to fritted glass, which is used for shading, visual screening, graphics, and other purposes; and to allow BIPV modules to be fabricated in various sizes and shapes with maximum control over electrical characteristics.

  12. The new geospatial tools: global transparency enhancing safeguards verification

    SciTech Connect (OSTI)

    Pabian, Frank Vincent [Los Alamos National Laboratory

    2010-09-16T23:59:59.000Z

    This paper focuses on the importance and potential role of the new, freely available, geospatial tools for enhancing IAEA safeguards and how, together with commercial satellite imagery, they can be used to promote 'all-source synergy'. As additional 'open sources', these new geospatial tools have heralded a new era of 'global transparency' and they can be used to substantially augment existing information-driven safeguards gathering techniques, procedures, and analyses in the remote detection of undeclared facilities, as well as support ongoing monitoring and verification of various treaty (e.g., NPT, FMCT) relevant activities and programs. As an illustration of how these new geospatial tools may be applied, an original exemplar case study provides how it is possible to derive value-added follow-up information on some recent public media reporting of a former clandestine underground plutonium production complex (now being converted to a 'Tourist Attraction' given the site's abandonment by China in the early 1980s). That open source media reporting, when combined with subsequent commentary found in various Internet-based Blogs and Wikis, led to independent verification of the reporting with additional ground truth via 'crowdsourcing' (tourist photos as found on 'social networking' venues like Google Earth's Panoramio layer and Twitter). Confirmation of the precise geospatial location of the site (along with a more complete facility characterization incorporating 3-D Modeling and visualization) was only made possible following the acquisition of higher resolution commercial satellite imagery that could be correlated with the reporting, ground photos, and an interior diagram, through original imagery analysis of the overhead imagery.

  13. Optical indices of lithiated electrochromic oxides

    SciTech Connect (OSTI)

    Rubin, M.; Rottkay, K. von; Wen, S.J.; Ozer, N.; Slack, J.

    1996-09-01T23:59:59.000Z

    Optical indices have been determined for thin films of several electrochromic oxide materials. One of the most important materials in electrochromic devices, WO{sub 3}, was thoroughly characterized for a range of electrochromic states by sequential injection of Li ions. Another promising material, Li{sub 0.5}Ni{sub 0.5}O, was also studied in detail. Less detailed results are presented for three other common lithium-intercalating electrochromic electrode materials: V{sub 2}O{sub 5}, LiCoO{sub 2}, and CeO{sub 2}-TiO{sub 2}. The films were grown by sputtering, pulsed laser deposition (PLD) and sol-gel techniques. Measurements were made using a combination of variable-angle spectroscopy ellipsometry and spectroradiometry. The optical constants were then extracted using physical and spectral models appropriate to each material. Optical indices of the underlying transparent conductors, determined in separate studies, were fixed in the models of this work. The optical models frequently agree well with independent physical measurements of film structure, particularly surface roughness by atomic force microscopy. Inhomogeneity due to surface roughness, gradient composition, and phase separation are common in both the transparent conductors and electrochromics, resulting sometimes in particularly complex models for these materials. Complete sets of data are presented over the entire solar spectrum for a range of colored states. This data is suitable for prediction of additional optical properties such as oblique transmittance and design of complete electrochromic devices.

  14. Optical Conductivity with Holographic Lattices

    E-Print Network [OSTI]

    Gary T. Horowitz; Jorge E. Santos; David Tong

    2012-08-03T23:59:59.000Z

    We add a gravitational background lattice to the simplest holographic model of matter at finite density and calculate the optical conductivity. With the lattice, the zero frequency delta function found in previous calculations (resulting from translation invariance) is broadened and the DC conductivity is finite. The optical conductivity exhibits a Drude peak with a cross-over to power-law behavior at higher frequencies. Surprisingly, these results bear a strong resemblance to the properties of some of the cuprates.

  15. Asphalt Oxidation Kinetics and Pavement Oxidation Modeling

    E-Print Network [OSTI]

    Jin, Xin

    2012-07-16T23:59:59.000Z

    Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

  16. Appendix C Conducting Structured Walkthroughs

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1997-05-21T23:59:59.000Z

    This guide describes how to conduct a structured walkthroughs during the lifecycle stages of software engineering projects, regardless of hardware platform.

  17. Communiquer dans un monde de normes l 198 Boutaud J-J. (2005), La transparence, nouveau rgime visible , Transparence & communication, MEI, n 22, Paris, L'Harmattan,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    visible », Transparence & communication, MEI, n° 22, Paris, L'Harmattan, pp. 1-7. Debord G. (1967), La communication, Paris, L'Harmattan, pp. 207-225. Introduction La communication proposée s'inscrit dans la

  18. Enhancement of Topological Insulators Surface Conduction

    E-Print Network [OSTI]

    Yu, Xinxin

    2012-01-01T23:59:59.000Z

    Enhancement of Topological Insulators Surface Conduction AEnhancement of Topological Insulators Surface Conduction byTopological Insulator

  19. Method for producing metal oxide aerogels

    SciTech Connect (OSTI)

    Tillotson, Thomas M. (Tracy, CA); Poco, John F. (Livermore, CA); Hrubesh, Lawrence W. (Pleasanton, CA); Thomas, Ian M. (Livermore, CA)

    1995-01-01T23:59:59.000Z

    A two-step hydrolysis-condensation method was developed to form metal oxide aerogels of any density, including densities of less than 0.003g/cm.sup.3 and greater than 0.27g/cm.sup.3. High purity metal alkoxide is reacted with water, alcohol solvent, and an additive to form a partially condensed metal intermediate. All solvent and reaction-generated alcohol is removed, and the intermediate is diluted with a nonalcoholic solvent. The intermediate can be stored for future use to make aerogels of any density. The aerogels are formed by reacting the intermediate with water, nonalcoholic solvent, and a catalyst, and extracting the nonalcoholic solvent directly. The resulting monolithic aerogels are hydrophobic and stable under atmospheric conditions, and exhibit good optical transparency, high clarity, and homogeneity. The aerogels have high thermal insulation capacity, high porosity, mechanical strength and stability, and require shorter gelation times than aerogels formed by conventional methods.

  20. Method for producing metal oxide aerogels

    SciTech Connect (OSTI)

    Tillotson, T.M.; Poco, J.F.; Hrubesh, L.W.; Thomas, I.M.

    1995-04-25T23:59:59.000Z

    A two-step hydrolysis-condensation method was developed to form metal oxide aerogels of any density, including densities of less than 0.003g/cm{sup 3} and greater than 0.27g/cm{sup 3}. High purity metal alkoxide is reacted with water, alcohol solvent, and an additive to form a partially condensed metal intermediate. All solvent and reaction-generated alcohol is removed, and the intermediate is diluted with a nonalcoholic solvent. The intermediate can be stored for future use to make aerogels of any density. The aerogels are formed by reacting the intermediate with water, nonalcoholic solvent, and a catalyst, and extracting the nonalcoholic solvent directly. The resulting monolithic aerogels are hydrophobic and stable under atmospheric conditions, and exhibit good optical transparency, high clarity, and homogeneity. The aerogels have high thermal insulation capacity, high porosity, mechanical strength and stability, and require shorter gelation times than aerogels formed by conventional methods. 8 figs.

  1. Electrical properties and defect structures of praseodymium-cerium oxide solid solutions

    E-Print Network [OSTI]

    Stefanik, Todd Stanley, 1973-

    2004-01-01T23:59:59.000Z

    A defect chemistry model consistent with observed trends in the pO2 and temperature dependence of electrical conductivity in praseodymium cerium oxide (PCO) was developed. Four point DC conductivity measurements were made ...

  2. Electrospun Polyaniline/Poly (ethylene oxide) Composite Nanofibers Based Gas Sensor

    E-Print Network [OSTI]

    Li, Changling

    2013-01-01T23:59:59.000Z

    polymer composite nanofibers ( i.e. , (+)- camphor-10-sulfonic acid (HCSA) doped polyanline PANI (conductive)conductive hosting polymers such as poly(ethylene oxide), polyvinylpyrrolidone and cellulose acetate which have been used to assist polyaniline to form composite

  3. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05T23:59:59.000Z

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  4. Enhanced electronic conductivity by controlled self-doping in pyrochlores

    SciTech Connect (OSTI)

    Xiao, Haiyan [University of Tennessee, Knoxville (UTK); Zhang, Yanwen [ORNL; Weber, William J [ORNL

    2012-01-01T23:59:59.000Z

    Most 5d transition-metal (TM) pyrochlores exhibit metallic behavior, but 3d and 4d TM pyrochlores are generally electronic semiconductors or insulators. Here, we report a semiconductor metal transition induced by introducing excess Ti metal as interstitials into Y2Ti2O7. These Ti interstitials prefer anion vacant 8a sites or bridge sites between two neighboring cations along the h010i direction. Density functional theory calculations suggest that an increased electronic conductivity originates from the interplay between the extra Ti and its neighboring cations. These findings suggest a means for achieving metallic behavior in semiconducting pyrochlore oxides and tuning the electronic conduction in pyrochlores for their electrochemical applications in solid oxide fuel cells.

  5. Penetrating the Oxide Barrier in Situ and Separating Freestanding Porous

    E-Print Network [OSTI]

    , such as polycarbonate membranes, well-fabricated anodic alumina oxide (AAO) membranes possess a much higher pore conducting substrate in applications such as dc electrodeposition of nanowires and * To whom correspondence

  6. Nanoengineered Thin Films for Solid Oxide Fuel Cells

    E-Print Network [OSTI]

    Su, Qing

    2013-11-21T23:59:59.000Z

    Solid oxide fuel cells (SOFCs) are very attractive as energy generation devices because of their high energy efficiency, flexible fuel selections and clean energy conversion. To avoid cell cracking and formation of non-conducting compounds...

  7. Cost and Schedule of the Mixed Oxide Fuel Fabrication Facility...

    Broader source: Energy.gov (indexed) [DOE]

    project review conducted by NNSA 1 Mixed oxide fuel is produced by mixing plutonium with depleted uranium. concluded that the MOX Facility had a very low probability of being...

  8. Nanoengineered Thin Films for Solid Oxide Fuel Cells 

    E-Print Network [OSTI]

    Su, Qing

    2013-11-21T23:59:59.000Z

    Solid oxide fuel cells (SOFCs) are very attractive as energy generation devices because of their high energy efficiency, flexible fuel selections and clean energy conversion. To avoid cell cracking and formation of non-conducting compounds...

  9. Composites of Single-Walled Carbon Nanotubes and Polystyrene: Preparation and Electrical Conductivity

    E-Print Network [OSTI]

    Resasco, Daniel

    and nitric acid oxidized SWNT. From measurements of the electrical conductivities of the composites over of SWNT, composites made with HiPco tubes had the highest conductivity. Introduction Carbon nanotubes conductivi- ties of CNT-polymer composites have percolation thresholds ranging from 0.0025%5 to several

  10. Conductive polymer-based material

    DOE Patents [OSTI]

    McDonald, William F. (Utica, OH); Koren, Amy B. (Lansing, MI); Dourado, Sunil K. (Ann Arbor, MI); Dulebohn, Joel I. (Lansing, MI); Hanchar, Robert J. (Charlotte, MI)

    2007-04-17T23:59:59.000Z

    Disclosed are polymer-based coatings and materials comprising (i) a polymeric composition including a polymer having side chains along a backbone forming the polymer, at least two of the side chains being substituted with a heteroatom selected from oxygen, nitrogen, sulfur, and phosphorus and combinations thereof; and (ii) a plurality of metal species distributed within the polymer. At least a portion of the heteroatoms may form part of a chelation complex with some or all of the metal species. In many embodiments, the metal species are present in a sufficient concentration to provide a conductive material, e.g., as a conductive coating on a substrate. The conductive materials may be useful as the thin film conducting or semi-conducting layers in organic electronic devices such as organic electroluminescent devices and organic thin film transistors.

  11. Experimental thermal conductivity and contact conductance of graphite composites 

    E-Print Network [OSTI]

    Jackson, Marian Christine

    1998-01-01T23:59:59.000Z

    Graphite fiber organic matrix composites were reviewed ics. for potential heat sink applications in the electronics packaging determined the effective transverse and longitudinal thermal industry. This experimental investigation conductivity...

  12. Experimental thermal conductivity and contact conductance of graphite composites

    E-Print Network [OSTI]

    Jackson, Marian Christine

    1998-01-01T23:59:59.000Z

    Graphite fiber organic matrix composites were reviewed ics. for potential heat sink applications in the electronics packaging determined the effective transverse and longitudinal thermal industry. This experimental investigation conductivity...

  13. High ethylene to ethane processes for oxidative coupling

    DOE Patents [OSTI]

    Chafin, Richard B. (Hurricane, WV); Warren, Barbara K. (Charleston, WV)

    1991-01-01T23:59:59.000Z

    Oxidative coupling of lower alkane to higher hydrocarbon is conducted using catalyst comprising barium and/or strontium component and a metal oxide combustion promoter in the presence of vapor phase halogen component. High ethylene to ethane mole ratios in the product can be obtained over extended operating periods.

  14. High ethylene to ethane processes for oxidative coupling

    DOE Patents [OSTI]

    Chafin, R.B.; Warren, B.K.

    1991-12-17T23:59:59.000Z

    Oxidative coupling of lower alkane to higher hydrocarbon is conducted using a catalyst comprising barium and/or strontium component and a metal oxide combustion promoter in the presence of vapor phase halogen component. High ethylene to ethane mole ratios in the product can be obtained over extended operating periods.

  15. Long term experience with semi-conductive glaze high voltage post insulators

    SciTech Connect (OSTI)

    Baker, A.C.; Maney, J.W.; Szilagyi, Z. (Lapp Insulator Co., LeRoy, NY (US))

    1990-01-01T23:59:59.000Z

    Insulators using semi-conductive glaze have long been known for their superior contamination performance. Early glazes for this type however were not stable and successful use of semi-conductive glazed porcelain insulators was delayed many years until tin-antimony oxide glazes were developed. Service experience of eighteen years is now available for line and station post insulators with this type of glaze. Based on this experience, the aging characteristics of tin-antimony oxide semi-conductive glazes are described and quantified. Several different applications of these insulators are also described.

  16. Photo-oxidation catalysts

    DOE Patents [OSTI]

    Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

    2009-07-14T23:59:59.000Z

    Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

  17. Metal current collect protected by oxide film

    DOE Patents [OSTI]

    Jacobson, Craig P. (Lafayette, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2004-05-25T23:59:59.000Z

    Provided are low-cost, mechanically strong, highly electronically conductive current collects and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical devices having as current interconnects a ferritic steel felt or screen coated with a protective oxide film.

  18. CONDUCTANCE OF NANOSYSTEMS WITH INTERACTION

    E-Print Network [OSTI]

    Ramsak, Anton

    -beam lithography or small metallic grains,[1] semiconductor quantum dots,[2] or a single large molecule of an atomic-size bridge that forms in the break,[3] or even measure the conductance of a single hydrogen

  19. Continuous production of conducting polymer

    E-Print Network [OSTI]

    Gaige, Terry A. (Terry Alden), 1981-

    2004-01-01T23:59:59.000Z

    A device to continuously produce polypyrrole was designed, manufactured, and tested. Polypyrrole is a conducting polymer which has potential artificial muscle applications. The objective of continuous production was to ...

  20. Plasma conductivity at finite coupling

    E-Print Network [OSTI]

    Babiker Hassanain; Martin Schvellinger

    2011-08-31T23:59:59.000Z

    By taking into account the full order(\\alpha'^3) type IIB string theory corrections to the supergravity action, we compute the leading finite 't Hooft coupling order(\\lambda^{-3/2}) corrections to the conductivity of strongly-coupled SU(N) {\\cal {N}}=4 supersymmetric Yang-Mills plasma in the large N limit. We find that the conductivity is enhanced by the corrections, in agreement with the trend expected from previous perturbative weak-coupling computations.

  1. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31T23:59:59.000Z

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.

  2. Mixed Conduction in Rare-Earth Phosphates

    E-Print Network [OSTI]

    Ray, Hannah Leung

    2012-01-01T23:59:59.000Z

    Conduction  in  Rare-­Earth  Phosphates   by   Hannah  Conduction  in  Rare-­?Earth  Phosphates   by   Hannah  conduction  in  rare  earth  phosphates.  Specifically,  

  3. Interfacial material for solid oxide fuel cell

    DOE Patents [OSTI]

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    1999-01-01T23:59:59.000Z

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  4. Energy Dependence of Nuclear Transparency in C(p,2p) Scattering

    E-Print Network [OSTI]

    A. Leksanov; J. Alster; G. Asryan; Y. Averichev; D. Barton; V. Baturin; N. Bukhtoyarova; A. Carroll; S. Heppelmann; T. Kawabata; Y. Makdisi; E. Minina; I. Navon; A. Malki; H. Nicholson; A. Ogawa; Yu. Panebratsev; E. Piasetzky; A. Schetkovsky; S. Shimanskiy; A. Tang; J. W. Watson; H. Yoshida; D. Zhalov

    2001-07-20T23:59:59.000Z

    The transparency of carbon for (p,2p) quasi-elastic events was measured at beam energies ranging from 6 to 14.5 GeV at 90 degrees c.m. The four momentum transfer squared q*q ranged from 4.8 to 16.9 (GeV/c)**2. We present the observed energy dependence of the ratio of the carbon to hydrogen cross sections. We also apply a model for the nuclear momentum distribution of carbon to normalize this transparency ratio. We find a sharp rise in transparency as the beam energy is increased to 9 GeV and a reduction to approximately the Glauber level at higher energies.

  5. Control of microwave signals using bichromatic electromechanically induced transparency in three-mode circuit electromechanical systems

    E-Print Network [OSTI]

    Cheng Jiang; Yuanshun Cui; Xiaowei Li

    2014-08-17T23:59:59.000Z

    We theoretically investigate the tunable slowing and advancing of microwave signals based on bichromatic electromechanically induced transparency in a three-mode circuit electromechanical system, where two mechanical oscillators with closely spaced frequencies are independently coupled to a common microwave cavity. In the presence of a strong microwave pump field, we obtain two transparency windows accompanied by steep phase dispersion in the transmitted microwave probe field. The width of the transparency window and the group delay of the probe field can be controlled effectively by the power of the pump field. It is shown that the maximum group delay of 0.12 ms and the advance of 0.27 ms can be obtained in the current experiments.

  6. Performance of Europium-Doped Strontium Iodide, Transparent Ceramics and Bismuth-loaded Polymer Scintillators

    SciTech Connect (OSTI)

    Cherepy, N J; Payne, S A; Sturm, B W; O'Neal, S P; Seeley, Z M; Drury, O B; Haselhorst, L K; Rupert, B L; Sanner, R D; Thelin, P A; Fisher, S E; Hawrami, R; Shah, K S; Burger, A; Ramey, J O; Boatner, L A

    2011-08-30T23:59:59.000Z

    Recently discovered scintillators for gamma ray spectroscopy, single crystal SrI{sub 2}(Eu), GYGAG(Ce) transparent ceramic and Bismuth-loaded plastics, offer resolution and fabrication advantages compared to commercial scintillators, such as NaI(Tl) and standard PVT plastic. Energy resolution at 662 keV of 2.7% is obtained with SrI{sub 2}(Eu), while 4.5% is obtained with GYGAG(Ce). A new transparent ceramic scintillator for radiographic imaging systems, GLO(Eu) offers high light yield of 70,000 Photons/MeV, high stopping, and low radiation damage. Implementation of single crystal SrI{sub 2}(Eu), Gd-based transparent ceramics, and Bi-loaded plastic scintillators can advance the state-of-the art in ionizing radiation detection systems.

  7. Transparent ultralow-density silica aerogels prepared by a two-step sol-gel process

    SciTech Connect (OSTI)

    Tillotson, T.M.; Hrubesh, L.W.

    1991-09-01T23:59:59.000Z

    Conventional silica sol-gel chemistry is limited for the production of transparent ultralow-density aerogels because (1) gelation is either slow or unachievable, and (2) even when gelation is achieved, the large pore sizes result in loss of transparency for aerogels <.020 g/cc. We have developed a two-step sol-gel process that circumvents the limitations of the conventional process and allows the formation of ultralow-density gels in a matter of hours. we have found that the gel time is dependent on the catalyst concentration. After supercritical extraction, the aerogels are transparent, uncracked tiles with densities as low as .003 g/cc. 6 figs., 11 refs.

  8. Modified cermet fuel electrodes for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Ruka, Roswell J. (Churchill Boro, PA); Spengler, Charles J. (Murrysville, PA)

    1991-01-01T23:59:59.000Z

    An exterior porous electrode (10), bonded to a solid oxygen ion conducting electrolyte (13) which is in contact with an interior electrode (14), contains coarse metal particles (12) of nickel and/or cobalt, having diameters from 3 micrometers to 35 micrometers, where the coarse particles are coated with a separate, porous, multiphase layer (17) containing fine metal particles of nickel and/or cobalt (18), having diameters from 0.05 micrometers to 1.75 micrometers and conductive oxide (19) selected from cerium oxide, doped cerium oxide, strontium titanate, doped strontium titanate and mixtures thereof.

  9. Oxidation of propylene over copper oxide catalysts

    E-Print Network [OSTI]

    Billingsley, David Stuart

    1958-01-01T23:59:59.000Z

    results were obtained using an asbestos supported CuO-Cr203 catalyst. Venkataramam and his co-workers (66) studied the catalytic oxidation of ethylene to ethylene oxide by the fluidized bed technique using a static bed of catalyst. Precipitated Ag20... in the air-ethylene ratio to maintain good yields of ethylene oxide. Wan (68) reported the oxidation of ethylene to acetaldehyde by use of a silver catalyst in a 5/16 dnch inner diameter stainless steel tube with a catalyst bed up to 30. 3 centimeters...

  10. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Award In order to produce power more efficiently and cleanly, the next generation of power plant boilers, turbines, solid oxide fuel cells (SOFCs) and other essential...

  11. The Use of Large Transparent Ceramics in a High Powered, Diode Pumped Solid State Laser

    SciTech Connect (OSTI)

    Yamamoto, R; Bhachu, B; Cutter, K; Fochs, S; Letts, S; Parks, C; Rotter, M; Soules, T

    2007-09-24T23:59:59.000Z

    The advent of large transparent ceramics is one of the key enabling technological advances that have shown that the development of very high average power compact solid state lasers is achievable. Large ceramic neodymium doped yttrium aluminum garnet (Nd:YAG) amplifier slabs are used in Lawrence Livermore National Laboratory's (LLNL) Solid State Heat Capacity Laser (SSHCL), which has achieved world record average output powers in excess of 67 kilowatts. We will describe the attributes of using large transparent ceramics, our present system architecture and corresponding performance; as well as describe our near term future plans.

  12. Sun-tracking optical element realized using thermally activated transparency-switching material

    E-Print Network [OSTI]

    Apostoleris, Harry; Lilliu, Samuele; Chiesa, Matteo

    2015-01-01T23:59:59.000Z

    We present a proof of concept demonstration of a novel optical element: a light-responsive aperture that can track a moving light beam. The element is created using a thermally-activated transparency-switching material composed of paraffin wax and polydimethylsiloxane (PDMS). Illumination of the material with a focused beam causes the formation of a localized transparency at the focal spot location, due to local heating caused by absorption of a portion of the incident light. An application is proposed in a new design for a self-tracking solar collector.

  13. Electromagnetically induced transparency from two-phonon processes in quadratically coupled membranes

    SciTech Connect (OSTI)

    Huang, Sumei; Agarwal, G. S. [Department of Physics, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)

    2011-02-15T23:59:59.000Z

    We describe how electromagnetically induced transparency can arise in quadratically coupled optomechanical systems. Due to quadratic coupling, the underlying optical process involves a two-phonon process in an optomechanical system, and this two-phonon process makes the mean displacement, which plays the role of atomic coherence in traditional electromagnetically induced transparency (EIT), zero. We show how the fluctuation in displacement can play a role similar to atomic coherence and can lead to EIT-like effects in quadratically coupled optomechanical systems. We show how such effects can be studied using the existing optomechanical systems.

  14. Thermally conductive cementitious grout for geothermal heat pump systems

    DOE Patents [OSTI]

    Allan, Marita (Old Field, NY)

    2001-01-01T23:59:59.000Z

    A thermally conductive cement-sand grout for use with a geothermal heat pump system. The cement sand grout contains cement, silica sand, a superplasticizer, water and optionally bentonite. The present invention also includes a method of filling boreholes used for geothermal heat pump systems with the thermally conductive cement-sand grout. The cement-sand grout has improved thermal conductivity over neat cement and bentonite grouts, which allows shallower bore holes to be used to provide an equivalent heat transfer capacity. In addition, the cement-sand grouts of the present invention also provide improved bond strengths and decreased permeabilities. The cement-sand grouts can also contain blast furnace slag, fly ash, a thermoplastic air entraining agent, latex, a shrinkage reducing admixture, calcium oxide and combinations thereof.

  15. Electrically Conductive Bacterial Nanowires Produced by Shewanella...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conductive Bacterial Nanowires Produced by Shewanella Oneidensis Strain MR-1 and Other Microorganisms . Electrically Conductive Bacterial Nanowires Produced by Shewanella...

  16. Optical conductivity of curved graphene

    E-Print Network [OSTI]

    A. J. Chaves; T. Frederico; O. Oliveira; W. de Paula; M. C. Santos

    2014-05-01T23:59:59.000Z

    We compute the optical conductivity for an out-of-plane deformation in graphene using an approach based on solutions of the Dirac equation in curved space. Different examples of periodic deformations along one direction translates into an enhancement of the optical conductivity peaks in the region of the far and mid infrared frequencies for periodicities $\\sim100\\,$nm. The width and position of the peaks can be changed by dialling the parameters of the deformation profiles. The enhancement of the optical conductivity is due to intraband transitions and the translational invariance breaking in the geometrically deformed background. Furthemore, we derive an analytical solution of the Dirac equation in a curved space for a general deformation along one spatial direction. For this class of geometries, it is shown that curvature induces an extra phase in the electron wave function, which can also be explored to produce interference devices of the Aharonov-Bohm type.

  17. Conductive Channel for Energy Transmission

    SciTech Connect (OSTI)

    Apollonov, Victor V. [A.M. Prokhorov General Physics Institute, Vavilov Str. 38, Moscow, 119991 (Russian Federation)

    2011-11-10T23:59:59.000Z

    For many years the attempts to create conductive channels of big length were taken in order to study the upper atmosphere and to settle special tasks, related to energy transmission. There upon the program of creation of 'Impulsar' represents a great interest, as this program in a combination with high-voltage high repetition rate electrical source can be useful to solve the above mentioned problems (N. Tesla ideas for the days of high power lasers). The principle of conductive channel production can be shortly described as follows. The 'Impulsar' - laser jet engine vehicle - propulsion take place under the influence of powerful high repetition rate pulse-periodic laser radiation. In the experiments the CO{sub 2}-laser and solid state Nd:YAG laser systems had been used. Active impulse appears thanks to air breakdown (<30 km) or to the breakdown of ablated material on the board (>30 km), placed in the vicinity of the focusing mirror-acceptor of the breakdown waves. With each pulse of powerful laser the device rises up, leaving a bright and dense trace of products with high degree of ionization and metallization by conductive nano-particles due to ablation. Conductive dust plasma properties investigation in our experiments was produced by two very effective approaches: high power laser controlled ablation and by explosion of wire. Experimental and theoretical results of conductive canal modeling will be presented. The estimations show that with already experimentally demonstrated figures of specific thrust impulse the lower layers of the Ionosphere can be reached in several ten seconds that is enough to keep the high level of channel conductivity and stability with the help of high repetition rate high voltage generator. Some possible applications for new technology are highlighted.

  18. Lithium ion conducting ionic electrolytes

    DOE Patents [OSTI]

    Angell, C.A.; Xu, K.; Liu, C.

    1996-01-16T23:59:59.000Z

    A liquid, predominantly lithium-conducting, ionic electrolyte is described which has exceptionally high conductivity at temperatures of 100 C or lower, including room temperature. It comprises molten lithium salts or salt mixtures in which a small amount of an anionic polymer lithium salt is dissolved to stabilize the liquid against recrystallization. Further, a liquid ionic electrolyte which has been rubberized by addition of an extra proportion of anionic polymer, and which has good chemical and electrochemical stability, is described. This presents an attractive alternative to conventional salt-in-polymer electrolytes which are not cationic conductors. 4 figs.

  19. Lithium ion conducting ionic electrolytes

    DOE Patents [OSTI]

    Angell, C. Austen (Mesa, AZ); Xu, Kang (Tempe, AZ); Liu, Changle (Tulsa, OK)

    1996-01-01T23:59:59.000Z

    A liquid, predominantly lithium-conducting, ionic electrolyte is described which has exceptionally high conductivity at temperatures of 100.degree. C. or lower, including room temperature. It comprises molten lithium salts or salt mixtures in which a small amount of an anionic polymer lithium salt is dissolved to stabilize the liquid against recrystallization. Further, a liquid ionic electrolyte which has been rubberized by addition of an extra proportion of anionic polymer, and which has good chemical and electrochemical stability, is described. This presents an attractive alternative to conventional salt-in-polymer electrolytes which are not cationic conductors.

  20. Electroosmosis in conducting nanofluidic channels

    E-Print Network [OSTI]

    Zhao, Cunlu

    2010-01-01T23:59:59.000Z

    Theoretical modeling of electroosmosis through conducting (ideally polarizable) nanochannels is reported. Based on the theory of induced charge electrokinetics, a novel nanofluidic system which possesses both adjustable ion selective characteristics and flexible flow control is proposed. Such nanofluidic devices operate only with very low gate control voltage applied on the conductive walls of nanochannels, and thus even can be energized by normal batteries. We believe that it is possible to use such metal-electrolyte configurations to overcome the difficulties met with conventional metal-isolator-electrolyte systems for nanofluidic applications.

  1. Tuning the Properties of Transparent Oxide Conductors. Dopant Ion Size and Electronic Structure Effects on CdO-Based

    E-Print Network [OSTI]

    Medvedeva, Julia E.

    as key components in optoelectronic devices such as flat panel displays (FPDs), organic light-emitting diodes (OLEDs), photovoltaics, solar cells, optical waveguides, and energy-efficient windows.1

  2. Zinc Oxide Modified with Benzylphosphonic Acids as Transparent Electrodes in Regular and Inverted Organic Solar Cell Structures

    E-Print Network [OSTI]

    Ilja Lange; Sina Reiter; Juliane Kniepert; Fortunato Piersimoni; Michael Paetzel; Jana Hildebrandt; Thomas Brenner; Stefan Hecht; Dieter Neher

    2015-02-05T23:59:59.000Z

    An approach is presented to modify the WF of solution-processed sol-gel derived ZnOover an exceptionally wide range of more than 2.3 eV. This approach relies on the formation of dense and homogeneous self-assembled monolayers based on phosphonic acids with different dipole moments. This allows us to apply ZnO as charge selective bottom electrodes in either regular or inverted solar cell structures, using P3HT:PCBM as the active layer. These devices compete with or even exceed the performance of the reference cell on ITO/PEDOT:PSS. Our finding challenges the current view that bottom electrodes in inverted solar cells need to be electron-blocking for good device performance.

  3. Electrically conductive rigid polyurethane foam

    DOE Patents [OSTI]

    Neet, T.E.; Spieker, D.A.

    1983-12-08T23:59:59.000Z

    A rigid, moldable polyurethane foam comprises about 2 to 10 weight percent, based on the total foam weight, of a carbon black which is CONDUCTEX CC-40-220 or CONDUCTEX SC, whereby the rigid polyurethane foam is electrically conductive and has essentially the same mechanical properties as the same foam without carbon black added.

  4. Conducting Your Own Energy Audit

    E-Print Network [OSTI]

    Phillips, J.

    2008-01-01T23:59:59.000Z

    Why should you or anyone be interested in conducting a time intensive energy audit. What equipment is needed? When should you get started? Who should do it? The answer to Why is that energy costs are cutting into a company’s profit every minute...

  5. Electrically conductive rigid polyurethane foam

    DOE Patents [OSTI]

    Neet, Thomas E. (Grandview, MO); Spieker, David A. (Olathe, KS)

    1985-03-19T23:59:59.000Z

    A rigid, polyurethane foam comprises about 2-10 weight percent, based on the total foam weight, of a carbon black which is CONDUCTEX CC-40-220 or CONDUCTEX SC, whereby the rigid polyurethane foam is electrically conductive and has essentially the same mechanical properties as the same foam without carbon black added.

  6. Improved Thermo-Electric Efficiency through Decreased Thermal Conductivity due to Engineered Nano-Structures

    E-Print Network [OSTI]

    Vardi, Amichay

    transparent polycrystalline YAG specimens by means of the Spark Plasma Sintering (SPS) technique. The presence

  7. Photoelectrochemical investigation of a poly(ethylene oxide) cell

    SciTech Connect (OSTI)

    Sammells, A.F.; Ang, G.P.

    1984-03-01T23:59:59.000Z

    The photoelectrochemical properties of cells based on the solid polymer electrolyte (SPE) poly(ethylene oxide)/NaSCN with Na2S/S as a redox species are investigated experimentally. The preparation of the SPE is described in detail. Current/voltage curves or voltage/time are shown for cells using p-InP/SPE/conducting-glass, n-GaAs/SPE/conducting-glass, and p-InP/SPE/n-CdS structures. It is concluded that practical cells based on SPE of this type will require increases in the ionic conductivity of poly(ethylene oxide). 13 references.

  8. Formation of metal oxides by cathodic arc deposition

    SciTech Connect (OSTI)

    Anders, S.; Anders, A.; Rubin, M.; Wang, Z.; Raoux, S.; Kong, F.; Brown, I.G.

    1995-03-01T23:59:59.000Z

    Metal oxide thin films are of interest for a number of applications. Cathodic arc deposition, an established, industrially applied technique for formation of nitrides (e.g. TiN), can also be used for metal oxide thin film formation. A cathodic arc plasma source with desired cathode material is operated in an oxygen atmosphere, and metal oxides of various stoichiometric composition can be formed on different substrates. We report here on a series of experiments on metal oxide formation by cathodic arc deposition for different applications. Black copper oxide has been deposited on ALS components to increase the radiative heat transfer between the parts. Various metal oxides such as tungsten oxide, niobium oxide, nickel oxide and vanadium oxide have been deposited on ITO glass to form electrochromic films for window applications. Tantalum oxide films are of interest for replacing polymer electrolytes. Optical waveguide structures can be formed by refractive index variation using oxide multilayers. We have synthesized multilayers of Al{sub 2}O{sub 3}/Y{sub 2}O{sub 3}/AI{sub 2}O{sub 3}/Si as possible basic structures for passive optoelectronic integrated circuits, and Al{sub 2-x}Er{sub x}O{sub 3} thin films with a variable Er concentration which is a potential component layer for the production of active optoelectronic integrated devices such as amplifiers or lasers at a wavelength of 1.53 {mu}m. Aluminum and chromium oxide films have been deposited on a number of substrates to impart improved corrosion resistance at high temperature. Titanium sub-oxides which are electrically conductive and corrosion resistant and stable in a number of aggressive environments have been deposited on various substrates. These sub-oxides are of great interest for use in electrochemical cells.

  9. Photoactive transparent nano-crystalline glass-ceramic for remazole red dye degradation

    SciTech Connect (OSTI)

    Gad-Allah, Tarek A., E-mail: tareqabdelshafy@yahoo.ca [Water Pollution Research Department, National Research Centre, Cairo 12311 (Egypt); Margha, Fatma H. [Department of Glass Research, National Research Centre, Cairo 12311 (Egypt)] [Department of Glass Research, National Research Centre, Cairo 12311 (Egypt)

    2012-12-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: ? Preparation and characterization of novel transparent nanocrystalline glass-ceramic. ? Precipitation of photoactive phases by using controlled heat-treatment. ? Conservation of transparency along with photoactivity. ? Using the prepared nanocrystalline glass-ceramic in water purification. -- Abstract: Transparent glass ceramic material was prepared from alkali-borosilicate glass containing titania by proper heat treatment scheme. The prepared samples were characterized using differential thermal analysis, X-ray diffraction, transmission electron microscope, selected area electron diffraction and UV–visible spectroscopy. The applied heat treatment program allowed the crystallization of nano-crystalline anatase, rutile, barium titanate, titanium borate and silicate phases while maintaining the transparency. The precipitated nano-crystalline anatase and rutile phases were responsible for the observed high photocatalytic activity of the prepared samples. Samples of 24.29 and 32.39 TiO{sub 2} wt% showed better efficiency for the decolorization of remazole red dye compared with commercial-TiO{sub 2} used in preparation of glass-ceramic. The reuse of prepared glass-ceramic photocatalyst with nearly same efficiency for different times was also proved.

  10. What is the Transparent, Activity-Based Budget System and why is it being done?

    E-Print Network [OSTI]

    Saskatchewan, University of

    What is the Transparent, Activity-Based Budget System and why is it being done? This project, and systematic way; link budgets to cycles of integrated planning; ensure resources are put behind strategic Planning (PCIP) in financial decision-making; · NOT result in zero-based budgeting (zero-based budgeting

  11. Hair Self Shadowing and Transparency Depth Ordering Using Occupancy maps Erik Sintorn

    E-Print Network [OSTI]

    Assarsson, Ulf

    approximate visibility function for high frequency semi- transparent geometry such as hair. We can then reconstruct the vis- ibility for any fragment without the expensive compression needed by Deep Shadow Maps cylinders or as line primitives, the two main challenges are the self-shadowing effects within the volume

  12. RemusDB: Transparent High Availability for Database Umar Farooq Minhas

    E-Print Network [OSTI]

    Aboulnaga, Ashraf

    system (DBMS). The proposed tech- nique can be applied to any DBMS with little or no customization transparent HA and failover capabilities. We show that while Remus and similar systems can protect a DBMS, database workloads incur a performance overhead of up to 32% as compared to an unprotected DBMS. We

  13. aerogels isolants transparent-super: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aerogels isolants transparent-super First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Recent progress in...

  14. Transparent Triboelectric Nanogenerators and Self-Powered Pressure Sensors Based on Micropatterned Plastic Films

    E-Print Network [OSTI]

    Wang, Zhong L.

    sensors, and artificial skins.9-12 Indeed, building flexible transparent energy con- version and storage process for energy conversion has three important steps: charge generation, charge separation, and charge States State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College

  15. Reconstructing the Surface of Inhomogeneous Transparent Scenes by Scatter-Trace Photography

    E-Print Network [OSTI]

    Toronto, University of

    . W. Morris Kiriakos N. Kutulakos University of Toronto Abstract We present a new method one or more viewpoints while moving a proxi- mal light source to a 2D or 3D set of positions is that even though light trans- port within a transparent scene's interior can be exceed- ingly complex

  16. Shock-wave generation in transparent media from ultra-fast lasers R. Bernath*a

    E-Print Network [OSTI]

    Van Stryland, Eric

    Shock-wave generation in transparent media from ultra-fast lasers R. Bernath*a , C. G. Browna , J a harmonic of the pump laser frequency. Experiments also include burst-mode operation, where a train of ultra. Aspiotisa , M. Fishera , & M. Richardsona a Laser Plasma Laboratory, College of Optics & Photonics: CREOL

  17. Flexible and transparent supercapacitor based on In2O3 nanowire/carbon nanotube heterogeneous films

    E-Print Network [OSTI]

    Zhou, Chongwu

    ; accepted 17 December 2008; published online 28 January 2009 In this paper, a supercapacitor which may find applications in heads-up display, automobile wind-shield display, and conformable transparent and/or flexible energy conversion and storage units with high energy storage and power density

  18. THE MICROSTRUCTURAL LOCATION OF THE INTERGRANULAR METAL OXIDE PHASE IN A ZINC OXIDE VARISTOR

    E-Print Network [OSTI]

    Clarke, D. E

    2011-01-01T23:59:59.000Z

    OXIDE PHASE IN A ZINC OXIDE VARISTOR MICROSI'RUCTIJRALMETAL OXIDE PHASE IN A ZINC OXIDE VARISTOR David R. Clarke

  19. Anomalously increased effective thermal conductivities of ethylene glycol-based nanofluids containing copper nanoparticles

    SciTech Connect (OSTI)

    Eastman, J. A.; Choi, S. U. S.; Li, S.; Yu, W.; Thompson, L. J.

    2001-02-05T23:59:59.000Z

    It is shown that a ''nanofluid'' consisting of copper nanometer-sized particles dispersed in ethylene glycol has a much higher effective thermal conductivity than either pure ethylene glycol or ethylene glycol containing the same volume fraction of dispersed oxide nanoparticles. The effective thermal conductivity of ethylene glycol is shown to be increased by up to 40% for a nanofluid consisting of ethylene glycol containing approximately 0.3 vol% Cu nanoparticles of mean diameter <10 nm. The results are anomalous based on previous theoretical calculations that had predicted a strong effect of particle shape on effective nanofluid thermal conductivity, but no effect of either particle size or particle thermal conductivity.

  20. High-temperature electrically conductive ceramic composite and method for making same

    DOE Patents [OSTI]

    Beck, David E. (Knoxville, TN); Gooch, Jack G. (Seymour, TN); Holcombe, Jr., Cressie E. (Knoxville, TN); Masters, David R. (Knoxville, TN)

    1983-01-01T23:59:59.000Z

    The present invention relates to a metal-oxide ceramic composition useful in induction heating applications for treating uranium and uranium alloys. The ceramic composition is electrically conductive at room temperature and is nonreactive with molten uranium. The composition is prepared from a particulate admixture of 20 to 50 vol. % niobium and zirconium oxide which may be stabilized with an addition of a further oxide such as magnesium oxide, calcium oxide, or yttria. The composition is prepared by blending the powders, pressing or casting the blend into the desired product configuration, and then sintering the casting or compact in an inert atmosphere. In the casting operation, calcium aluminate is preferably added to the admixture in place of a like quantity of zirconia for providing a cement to help maintain the integrity of the sintered product.

  1. A new approach to low-conductivity, environmentally acceptable thermal insulation. Final report

    SciTech Connect (OSTI)

    Buckley, B.; Day, J.; Ferrero-Heredia, M.; Shanklin, E.; Varadarajan, G.; Woodruff, L.

    1996-02-01T23:59:59.000Z

    The object of this work was to develop a low-conductivity, economical, environmentally benign insulation. Specific objectives were to develop the following: (1) a very low conductivity use as ``super insulation`` in refrigerators, and (2) a general-purpose insulation for buildings and other applications. The technical goals of this work were to minimize gas phase, solid phase, and radiative conductivity. The novel approach pursued to achieve low gas phase conductivity was to blow foam with a removable gas or vapor, encapsulate the foam panel in a pouch made with a barrier film, and introduce a very low conductivity gas as the insulating gas phase. For super insulation and general-purpose insulation, the gases of choice were xenon and krypton, respectively. To control cost, the gases were present at low pressure, and the insulating panel was encapsulated with an impermeable polymeric film. Solid-phase conductivity was minimized by using low-density, open-cell, polyurethane foam. For super insulation, radiative heat transfer was impeded by placing aluminized Mylar films between relatively transparent 70-mil foam slabs. For general-purpose insulation, it was projected to impede radiative heat transfer by achieving the same very small cell size with open-cell CO{sub 2}-blown foam as is now achieved with closed-cell CO{sub 2}-blown foam.

  2. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1990-03-13T23:59:59.000Z

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  3. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, Jack J. (Shirley, NY); Elling, David (Centereach, NY); Reams, Walter (Shirley, NY)

    1990-01-01T23:59:59.000Z

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  4. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1988-05-26T23:59:59.000Z

    A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

  5. Hydraulic Conductivity Measurements Barrow 2014

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Katie McKnight; Tim Kneafsey; Craig Ulrich; Jil Geller

    Six individual ice cores were collected from Barrow Environmental Observatory in Barrow, Alaska, in May of 2013 as part of the Next Generation Ecosystem Experiment (NGEE). Each core was drilled from a different location at varying depths. A few days after drilling, the cores were stored in coolers packed with dry ice and flown to Lawrence Berkeley National Laboratory (LBNL) in Berkeley, CA. 3-dimensional images of the cores were constructed using a medical X-ray computed tomography (CT) scanner at 120kV. Hydraulic conductivity samples were extracted from these cores at LBNL Richmond Field Station in Richmond, CA, in February 2014 by cutting 5 to 8 inch segments using a chop saw. Samples were packed individually and stored at freezing temperatures to minimize any changes in structure or loss of ice content prior to analysis. Hydraulic conductivity was determined through falling head tests using a permeameter [ELE International, Model #: K-770B]. After approximately 12 hours of thaw, initial falling head tests were performed. Two to four measurements were collected on each sample and collection stopped when the applied head load exceeded 25% change from the original load. Analyses were performed between 2 to 3 times for each sample. The final hydraulic conductivity calculations were computed using methodology of Das et al., 1985.

  6. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, C.C.; Mrazek, F.C.

    1988-08-02T23:59:59.000Z

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

  7. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, Charles C. (Plainfield, IL); Mrazek, Franklin C. (Hickory Hills, IL)

    1988-01-01T23:59:59.000Z

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

  8. Developing a High Thermal Conductivity Fuel with Silicon Carbide Additives

    SciTech Connect (OSTI)

    baney, Ronald; Tulenko, James

    2012-11-20T23:59:59.000Z

    The objective of this research is to increase the thermal conductivity of uranium oxide (UO{sub 2}) without significantly impacting its neutronic properties. The concept is to incorporate another high thermal conductivity material, silicon carbide (SiC), in the form of whiskers or from nanoparticles of SiC and a SiC polymeric precursor into UO{sub 2}. This is expected to form a percolation pathway lattice for conductive heat transfer out of the fuel pellet. The thermal conductivity of SiC would control the overall fuel pellet thermal conductivity. The challenge is to show the effectiveness of a low temperature sintering process, because of a UO{sub 2}-SiC reaction at 1,377°C, a temperature far below the normal sintering temperature. Researchers will study three strategies to overcome the processing difficulties associated with pore clogging and the chemical reaction of SiC and UO{sub 2} at temperatures above 1,300°C:

  9. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15T23:59:59.000Z

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  10. Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide

    E-Print Network [OSTI]

    Kim, Sehun

    Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

  11. Implications of mercury interactions with band-gap semiconductor oxides

    SciTech Connect (OSTI)

    Granite, E.J.; King, W.P.; Stanko, D.C.; Pennline, H.W.

    2008-09-01T23:59:59.000Z

    Titanium dioxide is a well-known photooxidation catalyst. It will oxidize mercury in the presence of ultraviolet light from the sun and oxygen and/or moisture to form mercuric oxide. Several companies manufacture self-cleaning windows. These windows have a transparent coating of titanium dioxide. The titanium dioxide is capable of destroying organic contaminants in air in the presence of ultraviolet light from the sun, thereby keeping the windows clean. The commercially available self-cleaning windows were used to sequester mercury from oxygen–nitrogen mixtures. Samples of the self-cleaning glass were placed into specially designed photo-reactors in order to study the removal of elemental mercury from oxygen–nitrogen mixtures resembling air. The possibility of removing mercury from ambient air with a self-cleaning glass apparatus is examined. The intensity of 365-nm ultraviolet light was similar to the natural intensity from sunlight in the Pittsburgh region. Passive removal of mercury from the air may represent an option in lieu of, or in addition to, point source clean-up at combustion facilities. There are several common band-gap semiconductor oxide photocatalysts. Sunlight (both the ultraviolet and visible light components) and band-gap semiconductor particles may have a small impact on the global cycle of mercury in the environment. The potential environmental consequences of mercury interactions with band-gap semiconductor oxides are discussed. Heterogeneous photooxidation might impact the global transport of elemental mercury emanating from flue gases.

  12. PLUTONIUM METAL: OXIDATION CONSIDERATIONS AND APPROACH

    SciTech Connect (OSTI)

    Estochen, E.

    2013-03-20T23:59:59.000Z

    Plutonium is arguably the most unique of all metals when considered in the combined context of metallurgical, chemical, and nuclear behavior. Much of the research in understanding behavior and characteristics of plutonium materials has its genesis in work associated with nuclear weapons systems. However, with the advent of applications in fuel materials, the focus in plutonium science has been more towards nuclear fuel applications, as well as long term storage and disposition. The focus of discussion included herein is related to preparing plutonium materials to meet goals consistent with non-proliferation. More specifically, the emphasis is on the treatment of legacy plutonium, in primarily metallic form, and safe handling, packaging, and transport to meet non-proliferation goals of safe/secure storage. Elevated temperature oxidation of plutonium metal is the treatment of choice, due to extensive experiential data related to the method, as the oxide form of plutonium is one of only a few compounds that is relatively simple to produce, and stable over a large temperature range. Despite the simplicity of the steps required to oxidize plutonium metal, it is important to understand the behavior of plutonium to ensure that oxidation is conducted in a safe and effective manner. It is important to understand the effect of changes in environmental variables on the oxidation characteristics of plutonium. The primary purpose of this report is to present a brief summary of information related to plutonium metal attributes, behavior, methods for conversion to oxide, and the ancillary considerations related to processing and facility safety. The information provided is based on data available in the public domain and from experience in oxidation of such materials at various facilities in the United States. The report is provided as a general reference for implementation of a simple and safe plutonium metal oxidation technique.

  13. Conductive and robust nitride buffer layers on biaxially textured substrates

    DOE Patents [OSTI]

    Sankar, Sambasivan [Chicago, IL; Goyal, Amit [Knoxville, TN; Barnett, Scott A [Evanston, IL; Kim, Ilwon [Skokie, IL; Kroeger, Donald M [Knoxville, TN

    2009-03-31T23:59:59.000Z

    The present invention relates to epitaxial, electrically conducting and mechanically robust, cubic nitride buffer layers deposited epitaxially on biaxially textured substrates such as metals and alloys. The invention comprises of a biaxially textured substrate with epitaxial layers of nitrides. The invention also discloses a method to form such epitaxial layers using a high rate deposition method as well as without the use of forming gases. The invention further comprises epitaxial layers of oxides on the biaxially textured nitride layer. In some embodiments the article further comprises electromagnetic devices which may have superconducting properties.

  14. Transfer of Large-Area Graphene Films for High-Performance Transparent

    E-Print Network [OSTI]

    reduction of exfoliated graphite oxide layers can produce large quantities of reduced graphene oxide of exfoliated natural graphite. This is possibly due to a combination of factors, such as damage of the graphene oxide.15 Graphite has also been partially exfoliated and dispersed in certain solvents,5

  15. Variable-Temperature Electrical Measurements of Zinc Oxide/Tin Oxide-Cosubstituted Indium Oxide

    E-Print Network [OSTI]

    Poeppelmeier, Kenneth R.

    as transparent electrodes in solar cells, flat panel displays, and many other applications. The commercial TCO: Flat Panel Display Mater. Large Area Processes 1998, 508, 308. (4) Minami, T.; Takata, S.; Kakumu, T

  16. Sintered electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Warner, Kathryn A. (Bryan, TX)

    1999-01-01T23:59:59.000Z

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation.

  17. Method for producing metal oxide aerogels having densities less than 0. 02 g/cc

    DOE Patents [OSTI]

    Tillotson, T.M.; Poco, J.F.; Hrubesh, L.W.; Thomas, I.M.

    1994-01-04T23:59:59.000Z

    A two-step method is described for making transparent aerogels which have a density of less than 0.003 g/cm[sup 3] to those with a density of more than 0.8 g/cm[sup 3], by a sol/gel process and supercritical extraction. Condensed metal oxide intermediate made with purified reagents can be diluted to produce stable aerogels with a density of less than 0.02 g/cm[sup 3]. High temperature, direct supercritical extraction of the liquid phase of the gel produces hydrophobic aerogels which are stable at atmospheric moisture conditions. Monolithic, homogeneous silica aerogels with a density of less than 0.02 to higher than 0.8 g/cm[sup 3], with high thermal insulation capacity, improved mechanical strength and good optical transparency, are described. 7 figures.

  18. Method for producing metal oxide aerogels having densities less than 0.02 g/cc

    DOE Patents [OSTI]

    Tillotson, Thomas M. (Tracy, CA); Poco, John F. (Livermore, CA); Hrubesh, Lawrence W. (Pleasanton, CA); Thomas, Ian M. (Livermore, CA)

    1994-01-01T23:59:59.000Z

    A two-step method is described for making transparent aerogels which have a density of less than 0.003 g/cm.sup.3 to those with a density of more than 0.8 g/cm.sup.3, by a sol/gel process and supercritical extraction. Condensed metal oxide intermediate made with purified reagents can be diluted to produce stable aerogels with a density of less than 0.02 g/cm.sup.3. High temperature, direct supercritical extraction of the liquid phase of the gel produces hydrophobic aerogels which are stable at atmospheric moisture conditions. Monolithic, homogeneous silica aerogels with a density of less than 0.02 to higher than 0.8 g/cm.sup.3, with high thermal insulation capacity, improved mechanical strength and good optical transparency, are described.

  19. Water-soluble conductive polymers

    DOE Patents [OSTI]

    Aldissi, M.

    1988-02-12T23:59:59.000Z

    Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

  20. Water-soluble conductive polymers

    DOE Patents [OSTI]

    Aldissi, Mahmoud (Sante Fe, NM)

    1989-01-01T23:59:59.000Z

    Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

  1. Advances in inherently conducting polymers

    SciTech Connect (OSTI)

    Aldissi, M.

    1987-09-01T23:59:59.000Z

    The discovery of polyacetylene as the prototype material led to extensive research on its synythesis and characterization. The techniques that emerged as the most important and promising ones are those that dealt with molecular orientation and that resulted in conductivities almost as high as that of copper. The study of dozens of other materials followed. Interest in conducting polymers stems from their nonclassical optical and electronic properties as well as their potential technological applications. However, some of the factors currently limiting their use are the lack of long-term stability and the need to develop conventional low-cost techniques for easy processing. Therefore, research was extended toward solving these problems, and progress has been recently made in that direction. The synthesis of new materials such as stable and easily processable alkylthiophenes, water-soluble polymers, and multicomponent systems, including copolymers and composites, constitutes an important step forward in the area of synthetic metals. However, a full understanding of materials chemistry and properties requires more work in the years to come. Although, few small-scale applications have proven to be successful, long-term stability and applicability tests are needed before their commercial use becomes reality.

  2. Water-soluble conductive polymers

    DOE Patents [OSTI]

    Aldissi, Mahmoud (Sante Fe, NM)

    1990-01-01T23:59:59.000Z

    Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

  3. Phase Relationships and Physical Properties of Homologous Compounds in the Zinc OxideIndium Oxide System

    E-Print Network [OSTI]

    Poeppelmeier, Kenneth R.

    , are widely used as transparent electrodes for flat panel displays and solar cells. Commercial, thin-film tin

  4. Ionic conductors for solid oxide fuel cells

    DOE Patents [OSTI]

    Krumpelt, Michael (Naperville, IL); Bloom, Ira D. (Bolingbrook, IL); Pullockaran, Jose D. (Hanover Park, IL); Myles, Kevin M. (Downers Grove, IL)

    1993-01-01T23:59:59.000Z

    An electrolyte that operates at temperatures ranging from 600.degree. C. to 800.degree. C. is provided. The electrolyte conducts charge ionically as well as electronically. The ionic conductors include molecular framework structures having planes or channels large enough to transport oxides or hydrated protons and having net-positive or net-negative charges. Representative molecular framework structures include substituted aluminum phosphates, orthosilicates, silicoaluminates, cordierites, apatites, sodalites, and hollandites.

  5. METAL OXIDE NANOPARTICLES

    SciTech Connect (OSTI)

    FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

    2007-10-01T23:59:59.000Z

    This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

  6. Development of transparent silica aerogel over a wide range of densities

    E-Print Network [OSTI]

    Makoto Tabata; Ichiro Adachi; Yoshikazu Ishii; Hideyuki Kawai; Takayuki Sumiyoshi; Hiroshi Yokogawa

    2011-12-21T23:59:59.000Z

    We have succeeded in developing hydrophobic silica aerogels over a wide range of densities (i.e. refractive indices). A pinhole drying method was invented to make possible producing highly transparent aerogels with entirely new region of refractive indices of 1.06-1.26. Obtained aerogels are more transparent than conventional ones, and the refractive index is well controlled in the pinhole drying process. A test beam experiment was carried out in order to evaluate the performance of the pinhole-dried aerogels as a Cherenkov radiator. A clear Cherenkov ring was successfully observed by a ring imaging Cherenkov counter. We also developed monolithic and hydrophobic aerogels with a density of 0.01 g/cm^3 (a low refractive index of 1.0026) as a cosmic dust capturer for the first time. Consequently, aerogels with any refractive indices between 1.0026 and 1.26 can be produced freely.

  7. Development of transparent silica aerogel over a wide range of densities

    E-Print Network [OSTI]

    Tabata, Makoto; Ishii, Yoshikazu; Kawai, Hideyuki; Sumiyoshi, Takayuki; Yokogawa, Hiroshi; 10.1016/j.nima.2010.02.241

    2011-01-01T23:59:59.000Z

    We have succeeded in developing hydrophobic silica aerogels over a wide range of densities (i.e. refractive indices). A pinhole drying method was invented to make possible producing highly transparent aerogels with entirely new region of refractive indices of 1.06-1.26. Obtained aerogels are more transparent than conventional ones, and the refractive index is well controlled in the pinhole drying process. A test beam experiment was carried out in order to evaluate the performance of the pinhole-dried aerogels as a Cherenkov radiator. A clear Cherenkov ring was successfully observed by a ring imaging Cherenkov counter. We also developed monolithic and hydrophobic aerogels with a density of 0.01 g/cm^3 (a low refractive index of 1.0026) as a cosmic dust capturer for the first time. Consequently, aerogels with any refractive indices between 1.0026 and 1.26 can be produced freely.

  8. Growth and optical properties of partially transparent Eu doped CaF{sub 2} ceramic

    SciTech Connect (OSTI)

    Ghosh, Manoranjan, E-mail: mghosh@barc.gov.in; Sen, Shashwati, E-mail: mghosh@barc.gov.in; Pitale, S. S., E-mail: mghosh@barc.gov.in; Goutam, U. K., E-mail: mghosh@barc.gov.in; Shinde, Seema, E-mail: mghosh@barc.gov.in; Patra, G. D., E-mail: mghosh@barc.gov.in; Gadkari, S. C., E-mail: mghosh@barc.gov.in [Technical Physics Division, Bhabha Atomic Research Centre, Mumbai - 400085 (India)

    2014-04-24T23:59:59.000Z

    Partially transparent ceramic of 2 at.% Eu doped CaF{sub 2} have been grown preferentially towards [111] direction. For this purpose, Eu doped CaF{sub 2} nanoparticles (size?12 nm) obtained by a low temperature solution growth method has been pressed at 1000°C under vacuum. The preferentially grown ceramic shows 15% transparency within the visible range of spectrum. As confirmed by the X-ray diffraction result, the hot pressed ceramic exhibits reduced lattice volume than the nanopowder. It indicates Eu{sup 3+} as the dominant substituting ions at the Ca{sup 2+} sites of CaF{sub 2} lattice in the hot pressed ceramic material. It is corroborated by the photoluminescence results of hot pressed ceramic which shows strong red emission corresponding to Eu{sup 3+} sites. However, photoluminescence of nanopowder exhibits intense peak in the blue region of the spectrum which is characteristics of Eu2+ sites.

  9. CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE

    E-Print Network [OSTI]

    Sanandaji, Borhan M.

    CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE Borhan M dynamic model of a solid oxide fuel cell stack. Using a detailed physical model as a starting point, we (usually air) on the cathode side. Solid-oxide fuel cells (SOFCs) utilize a ceramic oxygen-ion conducting

  10. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24T23:59:59.000Z

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  11. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01T23:59:59.000Z

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  12. Cavity cooling of a trapped atom using Electromagnetically-Induced Transparency

    E-Print Network [OSTI]

    Marc Bienert; Giovanna Morigi

    2011-12-01T23:59:59.000Z

    A cooling scheme for trapped atoms is proposed, which combines cavity-enhanced scattering and electromagnetically induced transparency. The cooling dynamics exploits a three-photon resonance, which combines laser and cavity excitations. It is shown that relatively fast ground-state cooling can be achieved in the Lamb-Dicke regime and for large cooperativity. Efficient ground-state cooling is found for parameters of ongoing experiments.

  13. Color transparency after the NE18 and E665 experiments: Outllok and perspectives at CEBAF

    E-Print Network [OSTI]

    J. Nemchik; N. N. Nikolaev; B. G. Zakharov

    1994-06-06T23:59:59.000Z

    CEBAF is a high-luminocity factory of virtual photons with variable virtuality $Q^{2}$ and transverse size. This makes CEBAF, in particular after the energy upgrade to (8-12)GeV, an ideal facility for uncovering new phenomena, and opening new windows, at the interface of the perturbative and nonperturbative QCD. We discuss color transparency as the case for a broad program on electroproduction of vector mesons $\\rho^{0},\\,\\omega^{0},\\,\\phi^{0}$ and their radial excitations $\\rho',\\,\\omega',\\,\\phi'$ at CEBAF. We also comment on the second generation of experiments on color transparency in $^{4}He(e,e'p)$ scattering, which are also feasible at CEBAF. In 1994, we can make more reliable projections into future because our understanding of the onset of color transparency has greatly been augmented by two experiments completed in 1993:\\\\ i) no effect of CT was seen in the SLAC NE18 experiment on $A(e,e'p)$ scattering at virtualities of the exchanged photon $Q^{2} \\lsim 7$ GeV$^{2}$, \\\\ ii) strong signal of CT was observed in the FNAL E665 experiment on exclusive $\\rho^{0}$- meson production in deep inelastic scattering in the same range of $Q^{2}$. \\\\ We discuss the impact of these observations on the CEBAF experimental program. We argue they both are good news, both were anticipated theoretically, and both rule in the correct QCD mechanism of the onset of CT.

  14. Nuclear transparency and effective kaon-nucleon cross section from the A(e,e?K+) reaction

    E-Print Network [OSTI]

    Clasie, Benjamin Michael Patrick

    We have determined the transparency of the nuclear medium to kaons from A(e,e[superscript ?]K+) measurements on [superscript 12]C, [superscript 63]Cu, and [superscript 197]Au targets. The measurements were performed at the ...

  15. Inhibition of Oxidation in Nuclear Graphite

    SciTech Connect (OSTI)

    Phil Winston; James W. Sterbentz; William E. Windes

    2013-10-01T23:59:59.000Z

    Graphite is a fundamental material of high temperature gas cooled nuclear reactors, providing both structure and neutron moderation. Its high thermal conductivity, chemical inertness, thermal heat capacity, and high thermal structural stability under normal and off normal conditions contribute to the inherent safety of these reactor designs. One of the primary safety issues for a high temperature graphite reactor core is the possibility of rapid oxidation of the carbon structure during an off normal design basis event where an oxidizing atmosphere (air ingress) can be introduced to the hot core. Although the current Generation IV high temperature reactor designs attempt to mitigate any damage caused by a postualed air ingress event, the use of graphite components that inhibit oxidation is a logical step to increase the safety of these reactors. Recent experimental studies of graphite containing between 5.5 and 7 wt% boron carbide (B4C) indicate that oxidation is dramatically reduced even at prolonged exposures at temperatures up to 900°C. The proposed addition of B4C to graphite components in the nuclear core would necessarily be enriched in B-11 isotope in order to minimize B-10 neutron absorption and graphite swelling. The enriched boron can be added to the graphite during billet fabrication. Experimental oxidation rate results and potential applications for borated graphite in nuclear reactor components will be discussed.

  16. Highly conductive PEDOT:PSS on flexible substrate as ITO-free anode for polymer solar cells

    SciTech Connect (OSTI)

    Del Mauro, A. De Girolamo; Ricciardi, R.; Montanino, M.; Morvillo, P.; Minarini, C. [Italian National Agency for New Technologies, Energy and Sustainable Economic Development (ENEA), Portici Research Centre, p.le E. Fermi 1, 80055 Portici (Italy)

    2014-05-15T23:59:59.000Z

    In this work, highly conductive anode based on PEDOT:PSS is proposed as substitute of Indio-Tin Oxide (ITO) in flexible solar cells. The anodic conductive polymer was spin coated on a 125 ?m thick polyethylene naphthalate (PEN) substrate. The obtained film was characterized in terms of structure and physical- chemical proprieties. The obtained results are very promising and the conductive film will be investigated in future as electrode in a complete polymeric solar cell.

  17. Synthesis and Characterization of Simultaneous Electronic and Ionic Conducting Block Copolymers for Lithium Battery Electrodes

    E-Print Network [OSTI]

    Patel, Shrayesh

    2013-01-01T23:59:59.000Z

    Battery Electrodes by Shrayesh Naran Patel Abstract Synthesis and Characterizationand Characterization of Simultaneous Electronic and Ionic Conducting Block Copolymers for Lithium BatteryBattery Design ..10 1.6 Outline of Dissertation 12 Chapter 2 –Poly(3-alkylthiophene-block-ethylene oxide) Synthesis and Characterization .

  18. DOI: 10.1002/adma.200702672 Intact Pattern Transfer of Conductive Exfoliated Graphite

    E-Print Network [OSTI]

    Lee, Ilsoon

    DOI: 10.1002/adma.200702672 Intact Pattern Transfer of Conductive Exfoliated Graphite Nanoplatelet as biosensors[8,9] or in drug deliv- ery.[10,11] Exfoliated graphite has been incorporated into PEM and other incorporated into PEM.[15­18] Oxidized graphite is created by the acid treatment of graphite, which exfoliates

  19. Analysis of the empirical relations between visible solar radiation, the solar altitude and the transparency of the atmosphere

    E-Print Network [OSTI]

    Garcia Occhipinti, Antonio

    1965-01-01T23:59:59.000Z

    ANALYSIS OF THE EMPIRICAL RELATIONS BETWEEN VISUAL SOLAR RADIATION, THE SOLAR ALTITUDE AND THE TRANSPARENCY OF THE ATMOSPHERE A Thesis A. Garcia Occhipinti Submitted to the Graduate College of the Texas ARM Untverstty in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE January 1965 Major Subject: Oceanography ANALYSIS OF THE EMPIRICAL RELATIONS BETWEEN VISIBLE SOLAR RADIATION, THE SOLAR ALTITUDE AND THE TRANSPARENCY OF THE ATMOSPHERE A Thesis A. Garcia Occhipinti...

  20. Planar ceramic membrane assembly and oxidation reactor system

    DOE Patents [OSTI]

    Carolan, Michael Francis (Allentown, PA); Dyer, legal representative, Kathryn Beverly (Allentown, PA); Wilson, Merrill Anderson (West Jordan, UT); Ohrn, Ted R. (Alliance, OH); Kneidel, Kurt E. (Alliance, OH); Peterson, David (Uniontown, OH); Chen, Christopher M. (Allentown, PA); Rackers, Keith Gerard (Louisville, OH); Dyer, Paul Nigel (Allentown, PA)

    2009-04-07T23:59:59.000Z

    Planar ceramic membrane assembly comprising a dense layer of mixed-conducting multi-component metal oxide material, wherein the dense layer has a first side and a second side, a porous layer of mixed-conducting multi-component metal oxide material in contact with the first side of the dense layer, and a ceramic channeled support layer in contact with the second side of the dense layer. The planar ceramic membrane assembly can be used in a ceramic wafer assembly comprising a planar ceramic channeled support layer having a first side and a second side; a first dense layer of mixed-conducting multi-component metal oxide material having an inner side and an outer side, wherein the inner side is in contact with the first side of the ceramic channeled support layer; a first outer support layer comprising porous mixed-conducting multi-component metal oxide material and having an inner side and an outer side, wherein the inner side is in contact with the outer side of the first dense layer; a second dense layer of mixed-conducting multi-component metal oxide material having an inner side and an outer side, wherein the inner side is in contact with the second side of the ceramic channeled layer; and a second outer support layer comprising porous mixed-conducting multi-component metal oxide material and having an inner side and an outer side, wherein the inner side is in contact with the outer side of the second dense layer.

  1. Planar ceramic membrane assembly and oxidation reactor system

    DOE Patents [OSTI]

    Carolan, Michael Francis (Allentown, PA); Dyer, legal representative, Kathryn Beverly (Allentown, PA); Wilson, Merrill Anderson (West Jordan, UT); Ohm, Ted R. (Alliance, OH); Kneidel, Kurt E. (Alliance, OH); Peterson, David (Uniontown, OH); Chen, Christopher M. (Allentown, PA); Rackers, Keith Gerard (Louisville, OH); Dyer, deceased, Paul Nigel (Allentown, PA)

    2007-10-09T23:59:59.000Z

    Planar ceramic membrane assembly comprising a dense layer of mixed-conducting multi-component metal oxide material, wherein the dense layer has a first side and a second side, a porous layer of mixed-conducting multi-component metal oxide material in contact with the first side of the dense layer, and a ceramic channeled support layer in contact with the second side of the dense layer. The planar ceramic membrane assembly can be used in a ceramic wafer assembly comprising a planar ceramic channeled support layer having a first side and a second side; a first dense layer of mixed-conducting multi-component metal oxide material having an inner side and an outer side, wherein the inner side is in contact with the first side of the ceramic channeled support layer; a first outer support layer comprising porous mixed-conducting multi-component metal oxide material and having an inner side and an outer side, wherein the inner side is in contact with the outer side of the first dense layer; a second dense layer of mixed-conducting multi-component metal oxide material having an inner side and an outer side, wherein the inner side is in contact with the second side of the ceramic channeled layer; and a second outer support layer comprising porous mixed-conducting multi-component metal oxide material and having an inner side and an outer side, wherein the inner side is in contact with the outer side of the second dense layer.

  2. Effect of alkali addition on DC conductivity and thermal properties of vanadium-bismo-borate glasses

    SciTech Connect (OSTI)

    Khasa, S., E-mail: skhasa@rediff.com; Dahiya, M. S., E-mail: skhasa@rediff.com [Physics Department, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131039 (India); Agarwal, A. [Physics Department, Guru Jambheshwara University of Science and Technology, Hisar-125001 (India)

    2014-04-24T23:59:59.000Z

    The DC Conductivity and Differential Thermal Analysis of glasses with composition (30?x)Li{sub 2}O?xV{sub 2}O{sub 5}?20Bi{sub 2}O{sub 3}?50B{sub 2}O{sub 3}(x=15, 10, 5) has been carried out in order to study the effect of replacing the Transition Metal Oxide (TMO) with alkali oxide. A significant increase in the DC conductivity has been observed with increase in alkali content. Again the thermal measurements have shown the decrease in both glass transition temperature (T{sub g}) and crystallization temperature (T{sub x}). The Glass Stability (GS) and Glass Forming Ability (GFA) have also been calculated and these also were found to decrease with increase in alkali oxide content at the cost of TMO.

  3. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C oCNMSStaffCerium Oxide Coating for Oxidation

  4. Degradation in Solid Oxide Cells During High Temperature Electrolysis

    SciTech Connect (OSTI)

    Manohar Sohal

    2009-05-01T23:59:59.000Z

    Idaho National Laboratory has an ongoing project to generate hydrogen from steam using solid oxide electrolysis cells. One goal of that project is to address the technical and degradation issues associated with solid oxide electrolysis cells. This report covers a variety of these degradation issues, which were discussed during a workshop on “Degradation in Solid Oxide Electrolysis Cells and Strategies for its Mitigation,” held in Phoenix, AZ on October 27, 2008. Three major degradation issues related to solid oxide electrolysis cells discussed at the workshop are: • Delamination of O2-electrode and bond layer on steam/O2-electrode side • Contaminants (Ni, Cr, Si, etc.) on reaction sites (triple-phase boundary) • Loss of electrical/ionic conductivity of electrolyte. This list is not all inclusive, but the workshop summary can be useful in providing a direction for future research related to the degradation of solid oxide electrolysis cells.

  5. Kinetics of the reactions of hydrogen fluoride with calcium oxide

    SciTech Connect (OSTI)

    Kossaya, A.M.; Belyakov, B.P.; Kuchma, Z.V.; Sandrozd, M.K.; Vasil'eva, V.G.

    1986-08-01T23:59:59.000Z

    This paper studies the kinetics of interaction of gaseous hydrogen fluoride with calcium oxide at temperatures 300-700 degrees. The experiments were conducted in a laboratory adsorption apparatus modified and adapted for work with corrosive hydrogen fluoride. Calcium oxide samples in granulated form and deposited on gamma-alumina were used in the experiments. Kinetic curves representing variations of the degree of conversion of the solid samples with time are shown. The influence of retardation dure to diffusion was observed in the experiments. The influence of diffusion control on the reaction rate was also observed in a study of the reaction kinetics on supported layers of calcium oxide.

  6. Optical and electrical studies of cerium mixed oxides

    SciTech Connect (OSTI)

    Sherly, T. R., E-mail: trsherly@gmail.com [Post Graduate Department of Physics, Sanathana Dharma College, Alappuzha, Kerala (India); Raveendran, R. [Nanoscience Research Laboratory, Sree Narayana College, Kollam, Kerala 691001 (India)

    2014-10-15T23:59:59.000Z

    The fast development in nanotechnology makes enthusiastic interest in developing nanomaterials having tailor made properties. Cerium mixed oxide materials have received great attention due to their UV absorption property, high reactivity, stability at high temperature, good electrical property etc and these materials find wide applications in solid oxide fuel cells, solar control films, cosmetics, display units, gas sensors etc. In this study cerium mixed oxide compounds were prepared by co-precipitation method. All the samples were doped with Zn (II) and Fe (II). Preliminary characterizations such as XRD, SEM / EDS, TEM were done. UV - Vis, Diffuse reflectance, PL, FT-IR, Raman and ac conductivity studies of the samples were performed.

  7. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

    1988-01-01T23:59:59.000Z

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  8. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Nyaiesh, A.R.; Garwin, E.L.

    1986-08-04T23:59:59.000Z

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  9. Reducible oxide based catalysts

    DOE Patents [OSTI]

    Thompson, Levi T.; Kim, Chang Hwan; Bej, Shyamal K.

    2010-04-06T23:59:59.000Z

    A catalyst is disclosed herein. The catalyst includes a reducible oxide support and at least one noble metal fixed on the reducible oxide support. The noble metal(s) is loaded on the support at a substantially constant temperature and pH.

  10. Transparent Flexible Conductive Polymer Antennas Nicholas A. Vacirca, Nicholas J. Kirsch, Elizabeth E. Plowman, Adam K. Fontecchio, Kapil R. Dandekar, Timothy P. Kurzweg

    E-Print Network [OSTI]

    Kurzweg, Timothy P.

    ProcessesIntroduction There is a consistent demand for unobtrusive communication between two points, whether-temperature printing methods also enable the use of many non-traditional substrates including polymers and plastics or exposure to the physical strains of milling such as plastics, papers, fabrics, and biological surfaces

  11. Prediction of new thermodynamically stable aluminum oxides

    E-Print Network [OSTI]

    Liu, Yue; Wang, Shengnan; Zhu, Qiang; Dong, Xiao; Kresse, Georg

    2015-01-01T23:59:59.000Z

    Recently, it has been shown that under pressure, unexpected and counterintuitive chemical compounds become stable. Laser shock experiments (A. Rode, unpublished) on alumina (Al2O3) have shown non-equilibrium decomposition of alumina with the formation of free Al and a mysterious transparent phase. Inspired by these observations, with have explored the possibility of the formation of new chemical compounds in the system Al-O. Using the variable-composition structure prediction algorithm USPEX, in addition to the well-known Al2O3, we have found two extraordinary compounds Al4O7 and AlO2 to be thermodynamically stable in the pressure range 330-443 GPa and above 332 GPa, respectively. Both of these compounds at the same time contain oxide O2- and peroxide O22- ions, and both are insulating. Peroxo-groups are responsible for gap states, which significantly reduce the electronic band gap of both Al4O7 and AlO2.

  12. Electronically conductive polymer composites and microstructures

    SciTech Connect (OSTI)

    Van Dyke, L.S.

    1993-01-01T23:59:59.000Z

    Composites of electronically conductive polymers with insulating host materials are investigated. A template synthesis method was developed for the production of electronically conductive polymer microstructures. In template synthesis the pores of a porous host membrane act as templates for the polymerization of a conductive polymer. The template synthetic method can be used to form either solid microfibrils or hollow microtubules. The electrochemical properties of conductive polymers produced via the template synthesis method are superior to those of conventionally synthesized conductive polymers. Electronically conductive polymers are used to impart conductivity to non-conductive materials. Two different approaches are used. First, thin film composites of conductive polymers with fluoropolymers are made by the polymerization of conductive polymers onto fluoropolymer films. Modification of the fluoropolymer surface prior to conductive polymer polymerization is necessary to obtain good adhesion between the two materials. The difference in adhesion of the conductive polymer to the modified and unmodified fluoropolymer surfaces can be used to pattern the conductive polymer coating. Patterning of the conductive polymer coating can alternatively be done via UV laser ablation of the conductive polymer. The second method by which conductive polymers were used to impart conductivity to an insulating polymer was via the formation of a graft copolymer. In this approach, heterocyclic monomers grafted to an insulating polyphosphazene backbone were polymerized to yield semiconductive materials. Finally the measurement of electrolyte concentration in polypyrrole and the effects of hydroxide anion on the electrochemical and electrical properties of polypyrrole are described. It is shown that treatment of polypyrrole with hydroxide anion increases the potential window over which polypyrrole is a good electronic conductor.

  13. CONDUCTIVE POLYCARBONATE NANOCOMPOSITES with HYBRID NANOFILLERS

    E-Print Network [OSTI]

    Collins, Gary S.

    CONDUCTIVE POLYCARBONATE NANOCOMPOSITES with HYBRID NANOFILLERS Catherine Smith, Brooks Lively, Wei of polymers. Emerging technologies have demonstrated the crucial need for highly conductive polymer combination between polycarbonate (PC) and hybrid concentrations of CNT and GNP nanofillers was investigated

  14. Increasing the CO tolerance of PEM fuel cells via current pulsing and self-oxidation 

    E-Print Network [OSTI]

    Thomason, Arthur Hugh

    2004-09-30T23:59:59.000Z

    An investigation was conducted to determine and compare the effect of cell current pulsing and "self-oxidation" in increasing the CO tolerance of a PEM fuel cell. The most effective pulsing parameter values were also ...

  15. Conjugated linoleic acid reduces lipid oxidation in irradiated, cooked ground beef patties

    E-Print Network [OSTI]

    Chae, Sung Hee

    2007-09-17T23:59:59.000Z

    This study was conducted to examine the antioxidative effect of conjugated linoleic acid (CLA) in irradiated, cooked ground beef patties. The hypothesis was that CLA would be retained during irradiation and would reduce lipid oxidation...

  16. Increasing the CO tolerance of PEM fuel cells via current pulsing and self-oxidation

    E-Print Network [OSTI]

    Thomason, Arthur Hugh

    2004-09-30T23:59:59.000Z

    An investigation was conducted to determine and compare the effect of cell current pulsing and "self-oxidation" in increasing the CO tolerance of a PEM fuel cell. The most effective pulsing parameter values were also determined. Current pulsing...

  17. Method for enhancement of useful luminescence from vacancy defects in refractory oxides for tunable lasers

    DOE Patents [OSTI]

    Chen, Yok (Oak Ridge, TN)

    1990-01-01T23:59:59.000Z

    Refractory oxide crystals suitable for use in tunable lasers and a method for preparing the same are provided. The crystals are characterized by high quantum efficiency, high thermal stability, good crystal transparency, and a high percentage of useful luminescence. The method for preparation of the crystals involves removing substantially all the hydrogen, thermochemically reducing the crystal's oxygen content to produce oxygen (anion) vacancy defects, and subsequently irradiating the crystal with electrons to inactivate trace H.sup.- ions so that an increased amount of short lived F.sup.+ luminescence is produced when the crystal is optically excited.

  18. Properties and characterization of an oxide/oxide composite filter

    SciTech Connect (OSTI)

    Lane, J.E.; Painter, C.J.; Su, W.F.A.; Radford, K.C. [Westinghouse Electric Corp., Pittsburgh, PA (United States). Science and Technology Center; LeCostaouec, J.F. [Techniweave, Inc., Rochester, NH (United States)

    1996-12-31T23:59:59.000Z

    Westinghouse, with Techniweave as a major subcontractor, is conducting a three-phase program aimed at providing advanced candle filters for a 1997 pilot scale demonstration in one of the two hot gas filter system at Southern Company Service`s Wilsonville PSD Facility. This program`s objective is to develop an oxide CFCC (continuous fiber ceramic composite) candle filter that is cost competitive with prototype next generation filters through the development of a low cost sol-gel fabrication process and a 3D fiber architecture optimized for high volume filter manufacturing. Phase 1, Filter Material Development and Evaluation, results will be presented. Phase 1 activities included laboratory-scale development, characterization, and testing of a mullite matrix 3D fiber-reinforced (Nextel 550) ceramic composite filter material. Eleven 3D architectures were designed, preforms and ceramic matrix composite (CMC) filter materials were made, tested and evaluated. The CMC fabrication process was optimized for reduced cost and acceptable filter performance. Permeability, 4-pt bend and microstructural evaluation results, previously presented, were used to downselect to one 3D architecture and CMC processing method. The downselected filter material was fabricated and tested via permeability and 4-pt bend; Weibull modulus was determined. High-temperature flow-through corrosion tests and thermal aging tests in static air up to 5,000 h were conducted. SEM and XRD have been used to characterize microstructural and phase changes, if any, from high temperature exposure testing. Weaving feasibility studies for the flange and the closed end of a candle filter have been conducted in order to develop a low cost weaving method to make a single piece candle filter fiber preform. Results and conclusions for the evaluation of the downselected filter material above will be presented and discussed.

  19. Organic conductive films for semiconductor electrodes

    DOE Patents [OSTI]

    Frank, A.J.

    1984-01-01T23:59:59.000Z

    According to the present invention, improved electrodes overcoated with conductive polymer films and preselected catalysts are provided. The electrodes typically comprise an inorganic semiconductor over-coated with a charge conductive polymer film comprising a charge conductive polymer in or on which is a catalyst or charge-relaying agent.

  20. Optical absorption in ZrO2-x-C nanocomposite films on polymer substrates : application of an effective medium theory

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1- Introduction Transparent conductive oxides have received considerable attention since in order to increase the conductivity of the composite via percolation or percolation-tunneling mechanisms polycarbonate substrates, have been determined by means of reflectance measurements over the visible range