National Library of Energy BETA

Sample records for transfer electronic transmission

  1. Electron Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Pierre Kennepohl1,2 and Edward Solomon1* 1Department of Chemistry, Stanford University, Stanford, CA 94305 Electron transfer, or the act of moving an electron from one place to another, is amongst the simplest of chemical processes, yet certainly one of the most critical. The process of efficiently and controllably moving electrons around is one of the primary regulation mechanisms in biology. Without stringent control of electrons in living organisms, life could simply not exist. For example,

  2. Dynamic Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Evans, James E.; Jungjohann, K. L.; Browning, Nigel D.

    2012-10-12

    Dynamic transmission electron microscopy (DTEM) combines the benefits of high spatial resolution electron microscopy with the high temporal resolution of ultrafast lasers. The incorporation of these two components into a single instrument provides a perfect platform for in situ observations of material processes. However, previous DTEM applications have focused on observing structural changes occurring in samples exposed to high vacuum. Therefore, in order to expand the pump-probe experimental regime to more natural environmental conditions, in situ gas and liquid chambers must be coupled with Dynamic TEM. This chapter describes the current and future applications of in situ liquid DTEM to permit time-resolved atomic scale observations in an aqueous environment, Although this chapter focuses mostly on in situ liquid imaging, the same research potential exists for in situ gas experiments and the successful integration of these techniques promises new insights for understanding nanoparticle, catalyst and biological protein dynamics with unprecedented spatiotemporal resolution.

  3. Ponderomotive phase plate for transmission electron microscopes

    DOE Patents [OSTI]

    Reed, Bryan W. (Livermore, CA)

    2012-07-10

    A ponderomotive phase plate system and method for controllably producing highly tunable phase contrast transfer functions in a transmission electron microscope (TEM) for high resolution and biological phase contrast imaging. The system and method includes a laser source and a beam transport system to produce a focused laser crossover as a phase plate, so that a ponderomotive potential of the focused laser crossover produces a scattering-angle-dependent phase shift in the electrons of the post-sample electron beam corresponding to a desired phase contrast transfer function.

  4. In Situ Transmission Electron Microscopy

    Office of Scientific and Technical Information (OSTI)

    In Situ Transmission Electron Microscopy Katherine Jungjohann & Yang Liu Sandia National Laboratories, Albuquerque, New Mexico 87185 cint.lanl.gov * Adjustable HT: 100-300 kV * EDAX EDS Detector * Gatan Tridiem GIF * ADF STEM Detector * HAADF STEM Detector * BF STEM Detector * 2.0 A resolution in TEM * 1.9 A resolution in STEM * High resolution videos using Gatan Ultrascan CCD camera * Simultaneous BF and HAADF STEM imaging * EDS and EELS mapping * Energy-filtered imaging Sample Preparation

  5. Scientific Achievement Analytical Transmission Electron Microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analytical Transmission Electron Microscopy (TEM) method was developed to determine thickness and wrinkles in electron beam sensitive 2-dimensional (2D) MFI nanosheets....

  6. Transmission electron microscope CCD camera

    DOE Patents [OSTI]

    Downing, Kenneth H. (Lafayette, CA)

    1999-01-01

    In order to improve the performance of a CCD camera on a high voltage electron microscope, an electron decelerator is inserted between the microscope column and the CCD. This arrangement optimizes the interaction of the electron beam with the scintillator of the CCD camera while retaining optimization of the microscope optics and of the interaction of the beam with the specimen. Changing the electron beam energy between the specimen and camera allows both to be optimized.

  7. Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer

    Office of Scientific and Technical Information (OSTI)

    on Nanocrystalline Thin Films and Single Crystal (Technical Report) | SciTech Connect Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer on Nanocrystalline Thin Films and Single Crystal Citation Details In-Document Search Title: Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer on Nanocrystalline Thin Films and Single Crystal The long-term goal of the proposed research is to understand electron transfer dynamics in nanoparticle/liquid interface.

  8. "Covalent functionalization and electron-transfer properties...

    Office of Scientific and Technical Information (OSTI)

    "Covalent functionalization and electron-transfer properties of vertically aligned carbon nanofibers: The importance of edge-plane sites" Citation Details In-Document Search Title: ...

  9. Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer

    Office of Scientific and Technical Information (OSTI)

    on Nanocrystalline Thin Films and Single Crystal (Technical Report) | SciTech Connect Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer on Nanocrystalline Thin Films and Single Crystal Citation Details In-Document Search Title: Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer on Nanocrystalline Thin Films and Single Crystal × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's

  10. In situ transmission electron microscopy investigation of the...

    Office of Scientific and Technical Information (OSTI)

    In situ transmission electron microscopy investigation of the interfacial reaction between Ni and Al during rapid heating in a nanocalorimeter Grapes, Michael D. Department of...

  11. In situ transmission electron microscopy investigation of the...

    Office of Scientific and Technical Information (OSTI)

    Published Article: In situ transmission electron microscopy investigation of the interfacial reaction between Ni and Al during rapid heating in a nanocalorimeter Title: In situ...

  12. Photo-induced electron transfer method

    DOE Patents [OSTI]

    Wohlgemuth, Roland (2823 Hillegass Ave., Berkeley, CA 94705); Calvin, Melvin (2683 Buena Vista Way, Berkeley, CA 94708)

    1984-01-01

    The efficiency of photo-induced electron transfer reactions is increased and the back transfer of electrons in such reactions is greatly reduced when a photo-sensitizer zinc porphyrin-surfactant and an electron donor manganese porphyrin-surfactant are admixed into phospho-lipid membranes. The phospholipids comprising said membranes are selected from phospholipids whose head portions are negatively charged. Said membranes are contacted with an aqueous medium in which an essentially neutral viologen electron acceptor is admixed. Catalysts capable of transfering electrons from reduced viologen electron acceptor to hydrogen to produce elemental hydrogen are also included in the aqueous medium. An oxidizable olefin is also admixed in the phospholipid for the purpose of combining with oxygen that coordinates with oxidized electron donor manganese porphyrin-surfactant.

  13. Photo-induced electron transfer method

    DOE Patents [OSTI]

    Wohlgemuth, R.; Calvin, M.

    1984-01-24

    The efficiency of photo-induced electron transfer reactions is increased and the back transfer of electrons in such reactions is greatly reduced when a photo-sensitizer zinc porphyrin-surfactant and an electron donor manganese porphyrin-surfactant are admixed into phospholipid membranes. The phospholipids comprising said membranes are selected from phospholipids whose head portions are negatively charged. Said membranes are contacted with an aqueous medium in which an essentially neutral viologen electron acceptor is admixed. Catalysts capable of transferring electrons from reduced viologen electron acceptor to hydrogen to produce elemental hydrogen are also included in the aqueous medium. An oxidizable olefin is also admixed in the phospholipid for the purpose of combining with oxygen that coordinates with oxidized electron donor manganese porphyrin-surfactant.

  14. Scanning Transmission Electron Microscopy Investigations of Complex Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Stanford Synchrotron Radiation Lightsource Scanning Transmission Electron Microscopy Investigations of Complex Oxides Monday, May 23, 2011 - 3:30pm SSRL Conference room 137-322 Professor Tom Vogt, NanoCenter & Department of Chemistry, University of South Carolina High-Angle-Annular-Dark-Field/Scanning Transmission Electron Microscopy (HAADF/STEM) is a technique uniquely suited for detailed studies of the structure and composition of complex oxides. The HAADF detector collects electrons

  15. In Situ Transmission Electron Microscopy. (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    In Situ Transmission Electron Microscopy. Citation Details In-Document Search Title: In Situ Transmission Electron Microscopy. Abstract not provided. Authors: Jungjohann, Katherine Leigh ; Liu, Yang Publication Date: 2015-02-01 OSTI Identifier: 1238312 Report Number(s): SAND2015-0858C 563495 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the Advanced Electron Microscopy (AEM) Workshop held February 11-13, 2015 in San

  16. Iran Thomas Auditorium, 8600 Environmental Transmission Electron Microscopy for Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April 26, 2012 11:00 am Iran Thomas Auditorium, 8600 Environmental Transmission Electron Microscopy for Catalysis Research: The Example of Carbon Nanotubes Eric A. Stach Center for Functional Nanomaterials Brookhaven National Laboratory CNMS D D I I S S C C O O V V E E R R Y Y SEMINAR SERIES Abstract: Environmental transmission electron microscopy allows the imaging of materials in the presence of relatively high pressures of gas (several Torr) without loss of either spatial or temporal

  17. Reaction coordinates for electron transfer reactions

    SciTech Connect (OSTI)

    Rasaiah, Jayendran C.; Zhu Jianjun

    2008-12-07

    The polarization fluctuation and energy gap formulations of the reaction coordinate for outer sphere electron transfer are linearly related to the constant energy constraint Lagrangian multiplier m in Marcus' theory of electron transfer. The quadratic dependence of the free energies of the reactant and product intermediates on m and m+1, respectively, leads to similar dependence of the free energies on the reaction coordinates and to the same dependence of the activation energy on the reorganization energy and the standard reaction free energy. Within the approximations of a continuum model of the solvent and linear response of the longitudinal polarization to the electric field in Marcus' theory, both formulations of the reaction coordinate are expected to lead to the same results.

  18. Custody transfer enhanced by electronic billing system

    SciTech Connect (OSTI)

    Knox, R.M.

    1986-10-20

    Transcontinental Gas Pipe Line (TGPL) Corp. engineers have developed an electronic billing system for custody transfer that can reduce the cost of doing business and improve the accuracy of transfer measurements. The system accurately measures gas flow and quality, transmits gas data to a central facility, provides a capability to review the collected data, prepares bills based upon these data, and reduces staffing associated with the data collection and billing process. On-line flow computers are keys to this electronic billing system. These computers, referred to as remote terminal units (RTU's), are currently in service at TGPL at more than 30 locations with 30 more locations due to be on-line within 6 months and an additional 40 locations due within 15 months. These RTU's will be obtaining gas data from metering stations located in New York, New Jersey, Pennsylvania, Maryland, Virginia, North Carolina, Georgia, Louisiana, and Texas.

  19. Transmission Services WIST Task Force Dynamic Transfer Capability...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ("WIST"), a Task Force of technical staff primarily from Northwest and California transmission providers and sub-regional entities, completed a report documenting Phase 1 of its...

  20. Studying localized corrosion using liquid cell transmission electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chee, See Wee; Pratt, Sarah H.; Hattar, Khalid; Duquette, David; Ross, Frances M.; Hull, Robert

    2014-11-07

    Using liquid cell transmission electron microscopy (LCTEM), localized corrosion of Cu and Al thin films immersed in aqueous NaCl solutions was studied. We demonstrate that potentiostatic control can be used to initiate pitting and that local compositional changes, due to focused ion beam implantation of Au+ ions, can modify the corrosion susceptibility of Al films. Likewise, a discussion on strategies to control the onset of pitting is also presented.

  1. Studying localized corrosion using liquid cell transmission electron microscopy

    SciTech Connect (OSTI)

    Chee, See Wee; Pratt, Sarah H.; Hattar, Khalid; Duquette, David; Ross, Frances M.; Hull, Robert

    2014-11-07

    Using liquid cell transmission electron microscopy (LCTEM), localized corrosion of Cu and Al thin films immersed in aqueous NaCl solutions was studied. We demonstrate that potentiostatic control can be used to initiate pitting and that local compositional changes, due to focused ion beam implantation of Au+ ions, can modify the corrosion susceptibility of Al films. Likewise, a discussion on strategies to control the onset of pitting is also presented.

  2. Quantum tunneling resonant electron transfer process in Lorentzian plasmas

    SciTech Connect (OSTI)

    Hong, Woo-Pyo; Jung, Young-Dae

    2014-08-15

    The quantum tunneling resonant electron transfer process between a positive ion and a neutral atom collision is investigated in nonthermal generalized Lorentzian plasmas. The result shows that the nonthermal effect enhances the resonant electron transfer cross section in Lorentzian plasmas. It is found that the nonthermal effect on the classical resonant electron transfer cross section is more significant than that on the quantum tunneling resonant charge transfer cross section. It is shown that the nonthermal effect on the resonant electron transfer cross section decreases with an increase of the Debye length. In addition, the nonthermal effect on the quantum tunneling resonant electron transfer cross section decreases with increasing collision energy. The variation of nonthermal and plasma shielding effects on the quantum tunneling resonant electron transfer process is also discussed.

  3. Concurrent in situ ion irradiation transmission electron microscope

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hattar, K.; Bufford, D. C.; Buller, D. L.

    2014-08-29

    An in situ ion irradiation transmission electron microscope has been developed and is operational at Sandia National Laboratories. This facility permits high spatial resolution, real time observation of electron transparent samples under ion irradiation, implantation, mechanical loading, corrosive environments, and combinations thereof. This includes the simultaneous implantation of low-energy gas ions (0.8–30 keV) during high-energy heavy ion irradiation (0.8–48 MeV). In addition, initial results in polycrystalline gold foils are provided to demonstrate the range of capabilities.

  4. Photocathode Optimization for a Dynamic Transmission Electron Microscope: Final Report

    SciTech Connect (OSTI)

    Ellis, P; Flom, Z; Heinselman, K; Nguyen, T; Tung, S; Haskell, R; Reed, B W; LaGrange, T

    2011-08-04

    The Dynamic Transmission Electron Microscope (DTEM) team at Harvey Mudd College has been sponsored by LLNL to design and build a test setup for optimizing the performance of the DTEM's electron source. Unlike a traditional TEM, the DTEM achieves much faster exposure times by using photoemission from a photocathode to produce electrons for imaging. The DTEM team's work is motivated by the need to improve the coherence and current density of the electron cloud produced by the electron gun in order to increase the image resolution and contrast achievable by DTEM. The photoemission test setup is nearly complete and the team will soon complete baseline tests of electron gun performance. The photoemission laser and high voltage power supply have been repaired; the optics path for relaying the laser to the photocathode has been finalized, assembled, and aligned; the internal setup of the vacuum chamber has been finalized and mostly implemented; and system control, synchronization, and data acquisition has been implemented in LabVIEW. Immediate future work includes determining a consistent alignment procedure to place the laser waist on the photocathode, and taking baseline performance measurements of the tantalum photocathode. Future research will examine the performance of the electron gun as a function of the photoemission laser profile, the photocathode material, and the geometry and voltages of the accelerating and focusing components in the electron gun. This report presents the team's progress and outlines the work that remains.

  5. In-Situ Electrochemical Transmission Electron Microscopy for Battery Research

    SciTech Connect (OSTI)

    Mehdi, Beata L; Gu, Meng; Parent, Lucas; Xu, WU; Nasybulin, Eduard; Chen, Xilin; Unocic, Raymond R; Xu, Pinghong; Welch, David; Abellan, Patricia; Zhang, Ji-Guang; Liu, Jun; Wang, Chongmin; Arslan, Ilke; Evans, James E; Browning, Nigel

    2014-01-01

    The recent development of in-situ liquid stages for (scanning) transmission electron microscopes now makes it possible for us to study the details of electrochemical processes under operando conditions. As electrochemical processes are complex, care must be taken to calibrate the system before any in-situ/operando observations. In addition, as the electron beam can cause effects that look similar to electrochemical processes at the electrolyte/electrode interface, an understanding of the role of the electron beam in modifying the operando observations must also be understood. In this paper we describe the design, assembly, and operation of an in-situ electrochemical cell, paying particular attention to the method for controlling and quantifying the experimental parameters. The use of this system is then demonstrated for the lithiation/delithiation of silicon nanowires.

  6. Electron flow stability in magnetically insulated vacuum transmission lines

    SciTech Connect (OSTI)

    Rose, D. V.; Genoni, T. C.; Clark, R. E.; Welch, D. R. [Voss Scientific, LLC, Albuquerque, New Mexico 87108 (United States); Stygar, W. A. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)

    2011-03-15

    We evaluate the stability of electron current flow in high-power magnetically insulated transmission lines (MITLs). A detailed model of electron flow in cross-field gaps yields a dispersion relation for electromagnetic (EM) transverse magnetic waves [R. C. Davidson et al., Phys. Fluids 27, 2332 (1984)] which is solved numerically to obtain growth rates for unstable modes in various sheath profiles. These results are compared with two-dimensional (2D) EM particle-in-cell (PIC) simulations of electron flow in high-power MITLs. We find that the macroscopic properties (charge and current densities and self-fields) of the equilibrium profiles observed in the simulations are well represented by the laminar-flow model of Davidson et al. Idealized simulations of sheared flow in electron sheaths yield growth rates for both long (diocotron) and short (magnetron) wavelength instabilities that are in good agreement with the dispersion analysis. We conclude that electron sheaths that evolve self-consistently from space-charged-limited emission of electrons from the cathode in well-resolved 2D EM PIC simulations form stable profiles.

  7. Electron flow stability in magnetically insulated vacuum transmission lines.

    SciTech Connect (OSTI)

    Genoni, Thomas C. (Voss Scientific, LLC, Albuquerque, NM); Stygar, William A.; Welch, Dale Robert (Voss Scientific, LLC, Albuquerque, NM); Clark, R. E. (Voss Scientific, LLC, Albuquerque, NM); Rose, David V. (Voss Scientific, LLC, Albuquerque, NM)

    2010-11-01

    We evaluate the stability of electron current flow in high-power magnetically insulated transmission lines (MITLs). A detailed model of electron flow in cross-field gaps yields a dispersion relation for electromagnetic (EM) transverse magnetic waves [R. C. Davidson et al., Phys. Fluids 27, 2332 (1984)] which is solved numerically to obtain growth rates for unstable modes in various sheath profiles. These results are compared with two-dimensional (2D) EM particle-in-cell (PIC) simulations of electron flow in high-power MITLs. We find that the macroscopic properties (charge and current densities and self-fields) of the equilibrium profiles observed in the simulations are well represented by the laminar-flow model of Davidson et al. Idealized simulations of sheared flow in electron sheaths yield growth rates for both long (diocotron) and short (magnetron) wavelength instabilities that are in good agreement with the dispersion analysis. We conclude that electron sheaths that evolve self-consistently from space-charged-limited emission of electrons from the cathode in well-resolved 2D EM PIC simulations form stable profiles.

  8. Simultaneous orientation and thickness mapping in transmission electron microscopy

    SciTech Connect (OSTI)

    Tyutyunnikov, Dmitry; zdl, V. Burak; Koch, Christoph T.

    2014-12-04

    In this paper we introduce an approach for simultaneous thickness and orientation mapping of crystalline samples by means of transmission electron microscopy. We show that local thickness and orientation values can be extracted from experimental dark-field (DF) image data acquired at different specimen tilts. The method has been implemented to automatically acquire the necessary data and then map thickness and crystal orientation for a given region of interest. We have applied this technique to a specimen prepared from a commercial semiconductor device, containing multiple 22 nm technology transistor structures. The performance and limitations of our method are discussed and compared to those of other techniques available.

  9. Electronic overfill protection for crude oil transfer

    SciTech Connect (OSTI)

    Kilgore, D.R.; Miles, D.C.

    1995-12-31

    There are many considerations involved in the transfer of crude oil, but the most catastrophic consequences may come as the result of a spill during loading or unloading. The safety and well-being of personnel in the vicinity is of the utmost concern. Should one be fortunate enough that an explosion or fire is not the results of a spill, the one must contend with the dilemma of containment. Preserving environmental integrity is a subject that is high on everyone`s list. The phrase ``reportable spill`` can send chills up and down anyone`s back. The repercussions continue: Ground water contamination; Soil remediation; Regulatory fines and penalties; Litigation. And this is all topped off by the ``black eye`` that the company receives with the perception of the public. For these reasons, and more, the carriers of crude oil are choosing self imposed compliances to reduce the frequency of spills. Electronic Overfill Protection has been modified to meet the specific needs and requirements of the crude oil industry. Here, the authors will examine how this type of system evolved, how it functions, and where it may lead.

  10. Simultaneous orientation and thickness mapping in transmission electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tyutyunnikov, Dmitry; Özdöl, V. Burak; Koch, Christoph T.

    2014-12-04

    In this paper we introduce an approach for simultaneous thickness and orientation mapping of crystalline samples by means of transmission electron microscopy. We show that local thickness and orientation values can be extracted from experimental dark-field (DF) image data acquired at different specimen tilts. The method has been implemented to automatically acquire the necessary data and then map thickness and crystal orientation for a given region of interest. We have applied this technique to a specimen prepared from a commercial semiconductor device, containing multiple 22 nm technology transistor structures. The performance and limitations of our method are discussed and comparedmore » to those of other techniques available.« less

  11. Transmission electron microscope sample holder with optical features

    DOE Patents [OSTI]

    Milas, Mirko (Port Jefferson, NY); Zhu, Yimei (Stony Brook, NY); Rameau, Jonathan David (Coram, NY)

    2012-03-27

    A sample holder for holding a sample to be observed for research purposes, particularly in a transmission electron microscope (TEM), generally includes an external alignment part for directing a light beam in a predetermined beam direction, a sample holder body in optical communication with the external alignment part and a sample support member disposed at a distal end of the sample holder body opposite the external alignment part for holding a sample to be analyzed. The sample holder body defines an internal conduit for the light beam and the sample support member includes a light beam positioner for directing the light beam between the sample holder body and the sample held by the sample support member.

  12. Rudolph A. Marcus and His Theory of Electron Transfer Reactions

    Office of Scientific and Technical Information (OSTI)

    Rudolph A. Marcus and His Theory of Electron Transfer Reactions Resources with Additional Information * Interviews * Marcus Theory Rudolph A. Marcus Courtesy of Brookhaven National Laboratory Rudolph A. Marcus was awarded the 1992 Nobel Prize in Chemistry "for his contributions to the theory of electron transfer reactions in chemical systems". 'According to Chemistry Chairman Norman Sutin, some of the early definitive tests of Marcus's theoretical work were done ... at [Brookhaven

  13. Light-harvesting, Excitation Energy/Electron Transfer, and Photoregulation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Artificial Photosynthetic Systems Light-harvesting, Excitation Energy/Electron Transfer, and Photoregulation in Artificial Photosynthetic Systems Authors: Terazono, Y., Moore, T. A., Moore, A.L., and Gust, D. Title: Light-harvesting, Excitation Energy/Electron Transfer, and Photoregulation in Artificial Photosynthetic Systems Source: Year: 2012 Volume: In: Multiporphyrin Arrays: Fundamentals and Applications edited by Dongho Kim, Pan Stanford Publishing Pages: 349-387 ABSTRACT: This

  14. Transmission electron microscopy of whiskers and hillocks formed on Al films deposited onto a glass

    SciTech Connect (OSTI)

    Saka, H.; Fujino, S.; Kuroda, K. [Department of Quantum Engineering, Nagoya University, Nagoya 464-01 (Japan); Tsujimoto, K.; Tsuji, S. [Display Technology, IBM Japan, Ltd., Shimotsuruma, Yamato, Kanagawa 242 (Japan); Takatsuji, H. [Display Technology, IBM Japan, Ltd., Ichimiyake, Yasu-gun, Shiga 520-23 (Japan)

    1998-01-05

    Whiskers and hillocks formed on an Al film deposited onto a glass substrate have been observed by means of a variety of transmission electron microscopy technique.

  15. A TRANSMISSION ELECTRON MICROSCOPY STUDY OF PRESOLAR HIBONITE

    SciTech Connect (OSTI)

    Zega, Thomas J.; Stroud, Rhonda M.; Alexander, Conel M. O'D.; Nittler, Larry R.

    2011-04-01

    We report isotopic and microstructural data on five presolar hibonite grains (KH1, KH2, KH6, KH15, and KH21) identified in an acid residue of the Krymka LL3.1 ordinary chondrite. Isotopic measurements by secondary ion mass spectrometry (SIMS) verified a presolar circumstellar origin for the grains. Transmission electron microscopy (TEM) examination of the crystal structure and chemistry of the grains was enabled by in situ sectioning and lift-out with a focused-ion-beam scanning-electron microscope (FIB-SEM). Comparisons of isotopic compositions with models indicate that four of the five grains formed in low-mass stars that evolved through the red giant/asymptotic giant branches (RGBs/AGBs), whereas one grain formed in the ejecta of a Type II supernova. Selected-area electron-diffraction patterns show that all grains are single crystals of hibonite. Some grains contain minor structural perturbations (stacking faults) and small spreads in orientation that can be attributed to a combination of growth defects and mechanical processing by grain-grain collisions. The similar structure of the supernova grain to those from RGB/AGB stars indicates a similarity in the formation conditions. Radiation damage (e.g., point defects), if present, occurs below our detection limit. Of the five grains we studied, only one has the pure hibonite composition of CaAl{sub 12}O{sub 19}. All others contain minor amounts of Mg, Si, Ti, and Fe. The microstructural data are generally consistent with theoretical predictions, which constrain the circumstellar condensation temperature to a range of 1480-1743 K, assuming a corresponding total gas pressure between 1 x 10{sup -6} and 1 x 10{sup -3} atm. The TEM data were also used to develop a calibration for SIMS determination of Ti contents in oxide grains. Grains with extreme {sup 18}O depletions, indicating deep mixing has occurred in their parent AGB stars, are slightly Ti enriched compared with grains from stars without deep mixing, most likely reflecting differences in grain condensation conditions.

  16. Electron transfer statistics and thermal fluctuations in molecular junctions

    SciTech Connect (OSTI)

    Goswami, Himangshu Prabal; Harbola, Upendra

    2015-02-28

    We derive analytical expressions for probability distribution function (PDF) for electron transport in a simple model of quantum junction in presence of thermal fluctuations. Our approach is based on the large deviation theory combined with the generating function method. For large number of electrons transferred, the PDF is found to decay exponentially in the tails with different rates due to applied bias. This asymmetry in the PDF is related to the fluctuation theorem. Statistics of fluctuations are analyzed in terms of the Fano factor. Thermal fluctuations play a quantitative role in determining the statistics of electron transfer; they tend to suppress the average current while enhancing the fluctuations in particle transfer. This gives rise to both bunching and antibunching phenomena as determined by the Fano factor. The thermal fluctuations and shot noise compete with each other and determine the net (effective) statistics of particle transfer. Exact analytical expression is obtained for delay time distribution. The optimal values of the delay time between successive electron transfers can be lowered below the corresponding shot noise values by tuning the thermal effects.

  17. Transferred metal electrode films for large-area electronic devices

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Transferred metal electrode films for large-area electronic devices Citation Details In-Document Search Title: Transferred metal electrode films for large-area electronic devices The evaporation of metal-film gate electrodes for top-gate organic field-effect transistors (OFETs) limits the minimum thickness of the polymer gate dielectric to typically more than 300 nm due to deep hot metal atom penetration and damage of the dielectric. We show here that the

  18. Theory of ultrafast heterogeneous electron transfer: Contributions of direct charge transfer excitations to the absorbance

    SciTech Connect (OSTI)

    Wang, Luxia; Willig, Frank; May, Volkhard

    2007-04-07

    Absorption spectra related to heterogeneous electron transfer are analyzed with the focus on direct charge transfer transition from the surface attached molecule into the semiconductor band states. The computations are based on a model of reduced dimensionality with a single intramolecular vibrational coordinate but a complete account for the continuum of conduction band states. The applicability of this model to perylene on TiO{sub 2} has been demonstrated in a series of earlier papers. Here, based on a time-dependent formulation, the absorbance is calculated with the inclusion of charge transfer excitations. A broad parameter set inspired by the perylene TiO{sub 2} systems is considered. In particular, the description generalizes the Fano effect to heterogeneous electron transfer reactions. Preliminary simulations of measured spectra are presented for perylene-catechol attached to TiO{sub 2}.

  19. CORRELATING ELECTRONIC AND VIBRATIONAL MOTIONS IN CHARGE TRANSFER SYSTEMS

    SciTech Connect (OSTI)

    Khalil, Munira

    2014-06-27

    The goal of this research program was to measure coupled electronic and nuclear motions during photoinduced charge transfer processes in transition metal complexes by developing and using novel femtosecond spectroscopies. The scientific highlights and the resulting scientific publications from the DOE supported work are outlined in the technical report.

  20. Transmission

    Energy Savers [EERE]

    ~ Transmission ,... ,...vc- "' ""'\ S I r;. Dr. Jerry Pell, CCM Principal NEP A Document Manager Permitting, Siting, and Analysis (OE-20) Office of Electricity Delivery and Energy Reliability U.S. Department of Energy 1 000 Independence A venue SW Washington, D.C. 20585-0001 Subject: Champlain Hudson Power Express Project Submittal of Amendment Application Dear Dr. Pell: February 28, 2012 On January 25, 2010, Transmission Developers, Inc. ("TDI") submitted on behalf of

  1. Electronic Funds Transfer Authorization Form 4/2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vendor Information Company Name or DBA: Address: City/State/Zip: Internal Use Only Electronic Funds Transfer Authorization Form I, an authorized signer on the below account, hereby authorize Los Alamos National Laboratory, hereinafter called the Laboratory, to originate Automated Clearinghouse (ACH) credits for invoice payments (vendors), travel reimbursements, small purchase reimbursements and royalty payments (employees). I further authorize the Laboratory to originate ACH debits to this

  2. Application of Electron-Transfer Theory to Several Systems of Biological Interest

    DOE R&D Accomplishments [OSTI]

    Marcus, R. A.; Sutin, N.

    1985-03-23

    Electron-transfer reaction rates are compared with theoretically calculated values for several reactions in the bacterial photosynthetic reaction center. A second aspect of the theory, the cross-relation, is illustrated using protein-protein electron transfers.

  3. Aberration corrected 1.2-MV cold field-emission transmission electron microscope with a sub-50-pm resolution

    SciTech Connect (OSTI)

    Akashi, Tetsuya; Takahashi, Yoshio; Tanigaki, Toshiaki Shimakura, Tomokazu; Kawasaki, Takeshi; Furutsu, Tadao; Shinada, Hiroyuki; Osakabe, Nobuyuki; Mller, Heiko; Haider, Maximilian; Tonomura, Akira

    2015-02-16

    Atomic-resolution electromagnetic field observation is critical to the development of advanced materials and to the unveiling of their fundamental physics. For this purpose, a spherical-aberration corrected 1.2-MV cold field-emission transmission electron microscope has been developed. The microscope has the following superior properties: stabilized accelerating voltage, minimized electrical and mechanical fluctuation, and coherent electron emission. These properties have enabled to obtain 43-pm information transfer. On the bases of these performances, a 43-pm resolution has been obtained by correcting lens aberrations up to the third order. Observations of GaN [411] thin crystal showed a projected atomic locations with a separation of 44?pm.

  4. Imaging and microanalysis of thin ionomer layers by scanning transmission electron microscopy

    SciTech Connect (OSTI)

    Cullen, David A; Koestner, Roland; Kukreja, Ratan; Minko, Sergiy; Trotsenko, Oleksandr; Tokarev, Alexander V; Guetaz, Laure; Meyer III, Harry M; Parish, Chad M; More, Karren Leslie

    2014-01-01

    Improved conditions for imaging and spectroscopic mapping of thin perfluorosulfonic acid (PFSA) ionomer layers in fuel cell electrodes by scanning transmission electron microscopy (STEM) have been investigated. These conditions are first identified on model systems of Nafion ionomer-coated nanostructured thin films and nanoporous Si. The optimized conditions are then applied in a quantitative study of the ionomer through-layer loading for two typical electrode catalyst coatings using electron energy loss and energy dispersive X-ray spectroscopy in the transmission electron microscope. The e-beam induced damage to the perfluorosulfonic acid (PFSA) ionomer is quantified by following the fluorine mass loss with electron exposure and is then mitigated by a few orders of magnitude using cryogenic specimen cooling and a higher incident electron voltage. Multivariate statistical analysis is also applied to the analysis of spectrum images for data denoising and unbiased separation of independent components related to the catalyst, ionomer, and support.

  5. A single-shot transmissive spectrometer for hard x-ray free electron lasers

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: A single-shot transmissive spectrometer for hard x-ray free electron lasers Citation Details In-Document Search Title: A single-shot transmissive spectrometer for hard x-ray free electron lasers We report hard x-ray single-shot spectral measurements of the Linac Coherent Light Source. The spectrometer is based on a 10 {mu}m thick cylindrically bent Si single crystal operating in the symmetric Bragg geometry

  6. Characterization of aluminum oxide tunnel barriers by combining transport measurements and transmission electron microscopy imaging

    SciTech Connect (OSTI)

    Aref, T.; Averin, A.; Nguyend, H. Q.; Pekola, J. P.; Dijken, S. van; Yao, L. D.; Ferring, A.; Koberidze, M.; Nieminen, R. M.

    2014-08-21

    We present two approaches for studying the uniformity of a tunnel barrier. The first approach is based on measuring single-electron and two-electron tunneling in a hybrid single-electron transistor. Our measurements indicate that the effective area of a conduction channel is about one order of magnitude larger than predicted by theoretical calculations. With the second method, transmission electron microscopy, we demonstrate that variations in the barrier thickness are a plausible explanation for the larger effective area and an enhancement of higher order tunneling processes.

  7. A stochastic reorganizational bath model for electronic energy transfer

    SciTech Connect (OSTI)

    Fujita, Takatoshi E-mail: aspuru@chemistry.harvard.edu; Huh, Joonsuk; Aspuru-Guzik, Aln E-mail: aspuru@chemistry.harvard.edu

    2014-06-28

    Environmentally induced fluctuations of the optical gap play a crucial role in electronic energy transfer dynamics. One of the simplest approaches to incorporate such fluctuations in energy transfer dynamics is the well known Haken-Strobl-Reineker (HSR) model, in which the energy-gap fluctuation is approximated as white noise. Recently, several groups have employed molecular dynamics simulations and excited-state calculations in conjunction to account for excitation energies thermal fluctuations. On the other hand, since the original work of HSR, many groups have employed stochastic models to simulate the same transfer dynamics. Here, we discuss a rigorous connection between the stochastic and the atomistic bath models. If the phonon bath is treated classically, time evolution of the exciton-phonon system can be described by Ehrenfest dynamics. To establish the relationship between the stochastic and atomistic bath models, we employ a projection operator technique to derive the generalized Langevin equations for the energy-gap fluctuations. The stochastic bath model can be obtained as an approximation of the atomistic Ehrenfest equations via the generalized Langevin approach. Based on this connection, we propose a novel scheme to take account of reorganization effects within the framework of stochastic models. The proposed scheme provides a better description of the population dynamics especially in the regime of strong exciton-phonon coupling. Finally, we discuss the effect of the bath reorganization in the absorption and fluorescence spectra of ideal J-aggregates in terms of the Stokes shifts. We find a simple expression that relates the reorganization contribution to the Stokes shifts the reorganization shift to the ideal or non-ideal exciton delocalization in a J-aggregate. The reorganization shift can be described by three parameters: the monomer reorganization energy, the relaxation time of the optical gap, and the exciton delocalization length. This simple relationship allows one to understand the physical origin of the Stokes shifts in molecular aggregates.

  8. Method and apparatus for a high-resolution three dimensional confocal scanning transmission electron microscope

    DOE Patents [OSTI]

    de Jonge, Niels (Oak Ridge, TN) [Oak Ridge, TN

    2010-08-17

    A confocal scanning transmission electron microscope which includes an electron illumination device providing an incident electron beam propagating in a direction defining a propagation axis, and a precision specimen scanning stage positioned along the propagation axis and movable in at least one direction transverse to the propagation axis. The precision specimen scanning stage is configured for positioning a specimen relative to the incident electron beam. A projector lens receives a transmitted electron beam transmitted through at least part of the specimen and focuses this transmitted beam onto an image plane, where the transmitted beam results from the specimen being illuminated by the incident electron beam. A detection system is placed approximately in the image plane.

  9. Light-induced electron transfer vs. energy transfer in molecular thin-film systems

    SciTech Connect (OSTI)

    Renschler, C. L.; Faulkner, L. R.

    1980-01-01

    Quenching of fluoranthene (FA) singlets by tetrabromo-o-benzoquinone (TBBQ) and N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) was studied both in xylene solutions and in spin-cast polystyrene (PS) films. Emphasis was placed on time-resolved fluorescence transients resulting from pulsed excitation. Linear Stern-Volmer plots were obtained for quenching in solution and gave diffusion-controlled rate constants, of 1.45 x 10/sup 10/ M/sup -1/ sec/sup -1/ and 1.53 x 10/sup 10/ M/sup -1/ sec/sup -1/ for TBBQ and TMPD, respectively. TBBQ was found to quench FA singlets in PS over the studied concentration range 12 mM < (TBBQ) < 48 mM, but in its presence FA singlets decayed nonexponentially. The results were interpreted quantitatively in terms of pure Foerster's transfer from FA to TBBQ without diffusion of excitons. The critical transfer radius R/sub 0/ was experimentally determined to be 24.3 A, which is in good agreement with the theoretical value of 23 A calculated from spectral data. Quenching of FA singlets in PS films was found to be independent of FA concentration over a 300 mM to 1200 mM FA concentration range for a constant TBBQ concentration of 24.0 mM. TMPD was only slightly effective as a quencher of FA singlets in PS because it apparently behaves strictly as a contact quencher based on reversible charge transfer. The implications of these results for the design of systems intended to exploit light-induced electron transfer are discussed.

  10. Investigating the mesostructure of ordered porous silica nanocomposites by transmission electron microscopy techniques

    SciTech Connect (OSTI)

    Bullita, S.; Casula, M. F.; Piludu, M.; Falqui, A.; Carta, D.; Corrias, A.

    2014-10-21

    Nanocomposites made out of FeCo alloy nanocrystals supported onto pre-formed mesoporous ordered silica which features a cubic arrangement of pores (SBA-16) were investigated. Information on the effect of the nanocrystals on the mesostructure (i.e. pore arrangement symmetry, pore size, and shape) were deduced by a multitechnique approach including N2 physisorption, low angle X-ray diffraction, and Transmission electron microscopy. It is shown that advanced transmission electron microscopy techniques are required, however, to gain direct evidence on key compositional and textural features of the nanocomposites. In particular, electron tomography and microtomy techniques make clear that the FeCo nanocrystals are located within the pores of the SBA-16 silica, and that the ordered mesostructure of the nanocomposite is retained throughout the observed specimen.

  11. Nanoscale deformation analysis with high-resolution transmission electron microscopy and digital image correlation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Xueju; Pan, Zhipeng; Fan, Feifei; Wang, Jiangwei; Liu, Yang; Mao, Scott X.; Zhu, Ting; Xia, Shuman

    2015-09-10

    We present an application of the digital image correlation (DIC) method to high-resolution transmission electron microscopy (HRTEM) images for nanoscale deformation analysis. The combination of DIC and HRTEM offers both the ultrahigh spatial resolution and high displacement detection sensitivity that are not possible with other microscope-based DIC techniques. We demonstrate the accuracy and utility of the HRTEM-DIC technique through displacement and strain analysis on amorphous silicon. Two types of error sources resulting from the transmission electron microscopy (TEM) image noise and electromagnetic-lens distortions are quantitatively investigated via rigid-body translation experiments. The local and global DIC approaches are applied for themore » analysis of diffusion- and reaction-induced deformation fields in electrochemically lithiated amorphous silicon. As a result, the DIC technique coupled with HRTEM provides a new avenue for the deformation analysis of materials at the nanometer length scales.« less

  12. Nanoscale deformation analysis with high-resolution transmission electron microscopy and digital image correlation

    SciTech Connect (OSTI)

    Wang, Xueju; Pan, Zhipeng; Fan, Feifei; Wang, Jiangwei; Liu, Yang; Mao, Scott X.; Zhu, Ting; Xia, Shuman

    2015-09-10

    We present an application of the digital image correlation (DIC) method to high-resolution transmission electron microscopy (HRTEM) images for nanoscale deformation analysis. The combination of DIC and HRTEM offers both the ultrahigh spatial resolution and high displacement detection sensitivity that are not possible with other microscope-based DIC techniques. We demonstrate the accuracy and utility of the HRTEM-DIC technique through displacement and strain analysis on amorphous silicon. Two types of error sources resulting from the transmission electron microscopy (TEM) image noise and electromagnetic-lens distortions are quantitatively investigated via rigid-body translation experiments. The local and global DIC approaches are applied for the analysis of diffusion- and reaction-induced deformation fields in electrochemically lithiated amorphous silicon. As a result, the DIC technique coupled with HRTEM provides a new avenue for the deformation analysis of materials at the nanometer length scales.

  13. In situ transmission electron microscopy of individual carbon nanotetrahedron/nanoribbon structures in Joule heating

    SciTech Connect (OSTI)

    Masuda, Yusuke; Yoshida, Hideto; Takeda, Seiji; Kohno, Hideo

    2014-08-25

    Collapse of a carbon nanotube results in the formation of a nanoribbon, and a switching of the collapse direction yields a nanotetrahedron in the middle of a nanoribbon. Here, we report in-situ transmission electron microscopy observations of the behavior of carbon nanotetrahedron/nanoribbon structures during Joule heating to reveal their thermal stability. In addition, we propose that the observed process is related to the formation process of the structure.

  14. Comparison of preparation techniques for nuclear materials for transmission electron microscopy (TEM)

    SciTech Connect (OSTI)

    Aitkaliyeva, Assel; Madden, James W.; Miller, Brandon D; Cole, James I; Gan, Jian

    2015-04-01

    Preparation of highly radioactive and irradiated nuclear fuels and materials for transmission electron microscopy (TEM) is conjoined with a set of unique challenges, including but not limited to personnel radiation exposure and contamination. The paper evaluates three specimen preparation techniques for preparation of irradiated materials and determines which technique yields to the most reliable characterization of radiation damage microstructure. Various specimen preparation artifacts associated with each technique are considered and ways of minimizing these artifacts are addressed.

  15. Defects in paramagnetic Co-doped ZnO films studied by transmission electron microscopy

    SciTech Connect (OSTI)

    Kovacs, Andras; Ney, A.; Duchamp, Martial; Ney, V.; Boothroyd, Chris; Galindo, Pedro L.; Kaspar, Tiffany C.; Chambers, Scott A.; Dunin-Borkowski, Rafal

    2013-12-23

    We have studied planar defects in epitaxial Co:ZnO dilute magnetic semiconductor thin films deposited on c-plane sapphire (Al2O3) and the Co:ZnO/Al2O3 interface structure at atomic resolution using aberration-corrected transmission electron microscopy (TEM) and electron energy-loss spectroscopy (EELS). Comparing Co:ZnO samples deposited by pulsed laser deposition and reactive magnetron sputtering, both exhibit extrinsic stacking faults, incoherent interface structures, and compositional variations within the first 3-4 Co:ZnO layers at the interface.. In addition, we have measured the local strain which reveals the lattice distortion around the stacking faults.

  16. Concurrent in situ ion irradiation transmission electron microscope

    SciTech Connect (OSTI)

    Hattar, K.; Bufford, D. C.; Buller, D. L.

    2014-08-29

    An in situ ion irradiation transmission electron microscope has been developed and is operational at Sandia National Laboratories. This facility permits high spatial resolution, real time observation of electron transparent samples under ion irradiation, implantation, mechanical loading, corrosive environments, and combinations thereof. This includes the simultaneous implantation of low-energy gas ions (0.830 keV) during high-energy heavy ion irradiation (0.848 MeV). In addition, initial results in polycrystalline gold foils are provided to demonstrate the range of capabilities.

  17. Thermal transfer structures coupling electronics card(s) to coolant-cooled structure(s)

    DOE Patents [OSTI]

    David, Milnes P; Graybill, David P; Iyengar, Madhusudan K; Kamath, Vinod; Kochuparambil, Bejoy J; Parida, Pritish R; Schmidt, Roger R

    2014-12-16

    Cooling apparatuses and coolant-cooled electronic systems are provided which include thermal transfer structures configured to engage with a spring force one or more electronics cards with docking of the electronics card(s) within a respective socket(s) of the electronic system. A thermal transfer structure of the cooling apparatus includes a thermal spreader having a first thermal conduction surface, and a thermally conductive spring assembly coupled to the conduction surface of the thermal spreader and positioned and configured to reside between and physically couple a first surface of an electronics card to the first surface of the thermal spreader with docking of the electronics card within a socket of the electronic system. The thermal transfer structure is, in one embodiment, metallurgically bonded to a coolant-cooled structure and facilitates transfer of heat from the electronics card to coolant flowing through the coolant-cooled structure.

  18. Nucleation of diamond by pure carbon ion bombardment--a transmission electron microscopy study

    SciTech Connect (OSTI)

    Yao, Y.; Liao, M.Y.; Wang, Z.G.; Lifshitz, Y.; Lee, S.

    2005-08-08

    A cross-sectional high-resolution transmission electron microscopy (HRTEM) study of a film deposited by a 1 keV mass-selected carbon ion beam onto silicon held at 800 deg. C is presented. Initially, a graphitic film with its basal planes perpendicular to the substrate is evolving. The precipitation of nanodiamond crystallites in upper layers is confirmed by HRTEM, selected area electron diffraction, and electron energy loss spectroscopy. The nucleation of diamond on graphitic edges as predicted by Lambrecht et al. [W. R. L. Lambrecht, C. H. Lee, B. Segall, J. C. Angus, Z. Li, and M. Sunkara, Nature, 364 607 (1993)] is experimentally confirmed. The results are discussed in terms of our recent subplantation-based diamond nucleation model.

  19. Structural defects in GaN revealed by Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Liliental-Weber, Zuzanna

    2014-04-18

    This paper reviews the various types of structural defects observed by Transmission Electron Microscopy in GaN heteroepitaxial layers grown on foreign substrates and homoepitaxial layers grown on bulk GaN substrates. The structural perfection of these layers is compared to the platelet self-standing crystals grown by High Nitrogen Pressure Solution. Defects in undoped and Mg doped GaN are discussed. Some models explaining the formation of inversion domains in heavily Mg doped layers that are possible defects responsible for the difficulties of p-doping in GaN are also reviewed.

  20. In situ transmission electron microscopy analysis of conductive filament during solid electrolyte resistance switching

    SciTech Connect (OSTI)

    Fujii, Takashi; Arita, Masashi; Takahashi, Yasuo; Fujiwara, Ichiro

    2011-05-23

    An in situ transmission electron microscopy (TEM) analysis of a solid electrolyte, Cu-GeS, during resistance switching is reported. Real-time observations of the filament formation and disappearance process were performed in the TEM instrument and the conductive-filament-formation model was confirmed experimentally. Narrow conductive filaments were formed corresponding to resistance switching from high- to low-resistance states. When the resistance changed to high-resistance state, the filament disappeared. It was also confirmed by use of selected area diffractometry and energy-dispersive x-ray spectroscopy that the conductive filament was made of nanocrystals composed mainly of Cu.

  1. Studying The Kinetics Of Crystalline Silicon Nanoparticle Lithiation With In-Situ Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Mcdowell, Matthew T.; Ryu, Ill; Lee, Seokwoo; Wang, Chong M.; Nix, William D.; Cui, Yi

    2012-11-27

    Silicon is an attractive high-capacity anode material for Li-ion batteries, but a comprehensive understanding of the massive ~300% volume change and fracture during lithiation/delithiation is necessary to reliably employ Si anodes. Here, in-situ transmission electron microscopy (TEM) of the lithiation of crystalline Si nanoparticles reveals that the reaction slows down as it progresses into the particle interior. Analysis suggests that this behavior is due to the influence of mechanical stress at the reaction front on the driving force for the reaction. These experiments give insight into the factors controlling the kinetics of this unique reaction.

  2. Gas mixing system for imaging of nanomaterials under dynamic environments by environmental transmission electron microscopy

    SciTech Connect (OSTI)

    Akatay, M. Cem; Zvinevich, Yury; Ribeiro, Fabio H. E-mail: estach@bnl.gov; Baumann, Philipp; Stach, Eric A. E-mail: estach@bnl.gov

    2014-03-15

    A gas mixing manifold system that is capable of delivering a stable pressure stream of a desired composition of gases into an environmental transmission electron microscope has been developed. The system is designed to provide a stable imaging environment upon changes of either the composition of the gas mixture or upon switching from one gas to another. The design of the system is described and the response of the pressure inside the microscope, the sample temperature, and sample drift in response to flow and composition changes of the system are reported.

  3. Biological Applications and Transmission Electron Microscopy Investigations of Mesoporous Silica Nanoparticles

    SciTech Connect (OSTI)

    Brian G. Trewyn

    2006-05-01

    The research presented and discussed within involves the development of novel biological applications of mesoporous silica nanoparticles (MSN) and an investigation of mesoporous material by transmission electron microscopy (TEM). Mesoporous silica nanoparticles organically functionalized shown to undergo endocytosis in cancer cells and drug release from the pores was controlled intracellularly and intercellularly. Transmission electron microscopy investigations demonstrated the variety of morphologies produced in this field of mesoporous silica nanomaterial synthesis. A series of room-temperature ionic liquid (RTIL) containing mesoporous silica nanoparticle (MSN) materials with various particle morphologies, including spheres, ellipsoids, rods, and tubes, were synthesized. By changing the RTIL template, the pore morphology was tuned from the MCM-41 type of hexagonal mesopores to rotational moire type of helical channels, and to wormhole-like porous structures. These materials were used as controlled release delivery nanodevices to deliver antibacterial ionic liquids against Escherichia coli K12. The involvement of a specific organosiloxane function group, covalently attached to the exterior of fluorescein doped mesoporous silica nanoparticles (FITC-MSN), on the degree and kinetics of endocytosis in cancer and plant cells was investigated. The kinetics of endocystosis of TEG coated FITC-MSN is significantly quicker than FITC-MSN as determined by flow cytometry experiments. The fluorescence confocal microscopy investigation showed the endocytosis of TEG coated-FITC MSN triethylene glycol grafted fluorescein doped MSN (TEG coated-FITC MSN) into both KeLa cells and Tobacco root protoplasts. Once the synthesis of a controlled-release delivery system based on MCM-41-type mesoporous silica nanorods capped by disulfide bonds with superparamagnetic iron oxide nanoparticles was completed. The material was characterized by general methods and the dosage and kinetics of the antioxidant dependent release was measured. Finally, the biological interaction of the material was determined along with TEM measurements. An electron investigation proved that the pore openings of the MSN were indeed blocked by the Fe{sub 3}O{sub 4} nanoparticles. The biological interaction investigation demonstrated Fe{sub 3}O{sub 4}-capped MSN endocytosis into HeLa cells. Not only does the material enter the cells through endocytosis, but it seems that fluorescein was released from the pores most probably caused by disulfide bond reducing molecules, antioxidants. In addition to endocytosis and release, the Fe{sub 3}O{sub 4}-capped MSN propelled the cells across a cuvette upon induction of a magnet force. Finally, an important aspect of materials characterization is transmission electron microscopy. A TEM investigation demonstrated that incorporating different functional groups during the synthesis (co-condensation) changed the particle and pore morphologies.

  4. Mimicking the electron transfer chain in photosystem II with a molecular

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    triad thermodynamically capable of water oxidation Mimicking the electron transfer chain in photosystem II with a molecular triad thermodynamically capable of water oxidation Authors: Megiatto, J. D., Antoniuk-Pablant, A., Sherman, B. D., Kodis, G., Gervaldo, M., Moore, T. A., Moore, A. L., and Gust, D. Title: Mimicking the electron transfer chain in photosystem II with a molecular triad thermodynamically capable of water oxidation Source: Proceedings of the National Academy of Sciences

  5. "Covalent functionalization and electron-transfer properties of vertically

    Office of Scientific and Technical Information (OSTI)

    aligned carbon nanofibers: The importance of edge-plane sites" (Journal Article) | SciTech Connect "Covalent functionalization and electron-transfer properties of vertically aligned carbon nanofibers: The importance of edge-plane sites" Citation Details In-Document Search Title: "Covalent functionalization and electron-transfer properties of vertically aligned carbon nanofibers: The importance of edge-plane sites" The use of covalently bonded molecular layers

  6. Center for Biological Electron Transfer and Catalysis (BETCy) | U.S. DOE

    Office of Science (SC) Website

    Office of Science (SC) Center for Biological Electron Transfer and Catalysis (BETCy) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Center for Biological Electron Transfer and Catalysis (BETCy) Print Text Size: A A A FeedbackShare Page BETCy Header Director John Peters Lead Institution Montana State University Year Established 2014 Mission To investigate the

  7. Measured Radiation and Background Levels During Transmission of Megawatt Electron Beams Through Millimeter Apertures

    SciTech Connect (OSTI)

    Alarcon, Ricardo [Arizona State University, Glendale, AZ (United States); Balascuta, S. [Arizona State University, Glendale, AZ (United States); Benson, Stephen V. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Bertozzi, William [Massachusetts Institute of Technology, Cambridge, MA (United States); Boyce, James R. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Cowan, Ray [Massachusetts Institute of Technology, Cambridge, MA (United States); Douglas, David R. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Evtushenko, Pavel [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Fisher, P. [Massachusetts Institute of Technology, Cambridge, MA (United States); Ihloff, Ernest E. [Hampton University, Hampton, VA (United States); Kalantarians, Narbe [Hampton University, Hampton, VA (United States); Kelleher, Aidan Michael [Massachusetts Institute of Technology, Cambridge, MA (United States); Krossler, W. J. [William and Mary College, Williamsburg, VA (United States); Legg, Robert A. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Long, Elena [University of New Hampshire, Durham, NH (United States); Milner, Richard [Massachusetts Institute of Technology, Cambridge, MA (United States); Neil, George R. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Ou, Longwu [Massachusetts Institute of Technology, Cambridge, MA (United States); Schmookler, Barack Abraham [Massachusetts Institute of Technology, Cambridge, MA (United States); Tennant, Christopher D. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Tschalar, C. [Massachusetts Institute of Technology, Cambridge, MA (United States); Williams, Gwyn P. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Zhang, Shukui [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States)

    2013-11-01

    We report measurements of photon and neutron radiation levels observed while transmitting a 0.43 MW electron beam through millimeter-sized apertures and during beam-off, but accelerating gradient RF-on, operation. These measurements were conducted at the Free-Electron Laser (FEL) facility of the Jefferson National Accelerator Laboratory (JLab) using a 100 MeV electron beam from an energy-recovery linear accelerator. The beam was directed successively through 6 mm, 4 mm, and 2 mm diameter apertures of length 127 mm in aluminum at a maximum current of 4.3 mA (430 kW beam power). This study was conducted to characterize radiation levels for experiments that need to operate in this environment, such as the proposed DarkLight Experiment. We find that sustained transmission of a 430 kW continuous-wave (CW) beam through a 2 mm aperture is feasible with manageable beam-related backgrounds. We also find that during beam-off, RF-on operation, multipactoring inside the niobium cavities of the accelerator cryomodules is the primary source of ambient radiation when the machine is tuned for 130 MeV operation.

  8. Solving the Accelerator-Condenser Coupling Problem in a Nanosecond Dynamic Transmission Electron Microscope

    SciTech Connect (OSTI)

    Reed, B W; LaGrange, T; Shuttlesworth, R M; Gibson, D J; Campbell, G H; Browning, N D

    2009-12-29

    We describe a modification to a transmission electron microscope (TEM) that allows it to briefly (using a pulsed-laser-driven photocathode) operate at currents in excess of 10 mA while keeping the effects of condenser lens aberrations to a minimum. This modification allows real-space imaging of material microstructure with a resolution of order 10 nm over regions several {micro}m across with an exposure time of 15 ns. This is more than 6 orders of magnitude faster than typical video-rate TEM imaging. The key is the addition of a weak magnetic lens to couple the large-diameter high-current beam exiting the accelerator into the acceptance aperture of a conventional TEM condenser lens system. We show that the performance of the system is essentially consistent with models derived from ray tracing and finite element simulations. The instrument can also be operated as a conventional TEM by using the electron gun in a thermionic mode. The modification enables very high electron current densities in {micro}m-sized areas and could also be used in a non-pulsed system for high-throughput imaging and analytical TEM.

  9. Insights into proton-coupled electron transfer mechanisms of electrocatalytic H2 oxidation and production

    SciTech Connect (OSTI)

    Horvath, Samantha; Fernandez, Laura; Soudackov, Alexander V.; Hammes-Schiffer, Sharon

    2012-09-25

    The design of molecular electrocatalysts for H2 oxidation and production is important for the development of alternative renewable energy sources that are abundant, inexpensive, and environmentally benign. Recently nickel-based molecular electrocatalysts with pendant amines that act as proton relays for the nickel center were shown to effectively catalyze H2 oxidation and production. We developed a quantum mechanical approach for studying proton-coupled electron transfer processes in these types of molecular electrocatalysts. This theoretical approach is applied to a nickel-based catalyst in which phosphorous atoms are directly bonded to the nickel center and nitrogen atoms of the ligand rings act as proton relays. The cataly c step of interest involves electron transfer between the nickel complex and the electrode as well as intramolecular proton transfer between the nickel and nitrogen atoms. This process can occur sequentially, with either the electron or proton transferring first, or concertedly, with the electron and proton transferring simultaneously without a stable intermediate. The heterogeneous rate constants are calculated as functions of overpotential for the concerted electron-proton transfer reaction and the two electron transfer reactions in the sequential mechanisms. Our calculations illustrate that the concerted electron-proton transfer standard rate constant will increase as the equilibrium distance between the nickel and nitrogen atoms decreases and as the nitrogen atoms become more mobile to facilitate the contraction of this distance. This approach assists in the identification of the favored mechanisms under various experimental conditions and provides insight into the qualitative impact of substituents on the nitrogen and phosphorous atoms. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under FWP 56073.

  10. High resolution transmission electron microscopic in-situ observations of plastic deformation of compressed nanocrystalline gold

    SciTech Connect (OSTI)

    Wang, Guoyong; Lian, Jianshe; Jiang, Qing; Sun, Sheng; Zhang, Tong-Yi

    2014-09-14

    Nanocrystalline (nc) metals possess extremely high strength, while their capability to deform plastically has been debated for decades. Low ductility has hitherto been considered an intrinsic behavior for most nc metals, due to the lack of five independent slip systems actively operating during deformation in each nanograin. Here we report in situ high resolution transmission electron microscopic (HRTEM) observations of deformation process of nc gold under compression, showing the excellent ductility of individual and aggregate nanograins. Compression causes permanent change in the profile of individual nanograins, which is mediated by dislocation slip and grain rotation. The high rate of grain boundary sliding and large extent of widely exited grain rotation may meet the boundary compatibility requirements during plastic deformation. The in situ HRTEM observations suggest that nc gold is not intrinsically brittle under compressive loading.

  11. Rendering graphene supports hydrophilic with non-covalent aromatic functionalization for transmission electron microscopy

    SciTech Connect (OSTI)

    Pantelic, Radosav S., E-mail: pantelic@imbb.forth.gr [National Cancer Institute, 50 South Drive, Building 50, Room 4306, Bethesda, Maryland 20892 (United States); Fu, Wangyang; Schoenenberger, Christian [Department of Physics, University of Basel, Klingelbergstrasse 82, Basel CH-4056 (Switzerland); Stahlberg, Henning [Center for Cellular Imaging and NanoAnalytics, Biozentrum, University of Basel, Mattenstrasse 26, WRO-1058, Basel CH-4058 (Switzerland)

    2014-03-31

    Amorphous carbon films have been routinely used to enhance the preparation of frozen-hydrated samples for transmission electron microscopy (TEM), either in retaining protein concentration, providing mechanical stability or dissipating sample charge. However, strong background signal from the amorphous carbon support obstructs that of the sample, and the insulating properties of thin amorphous carbon films preclude any efficiency in dispersing charge. Graphene addresses the limitations of amorphous carbon. Graphene is a crystalline material with virtually no phase or amplitude contrast and unparalleled, high electrical carrier mobility. However, the hydrophobic properties of graphene have prevented its routine application in Cryo-TEM. This Letter reports a method for rendering graphene TEM supports hydrophilica convenient approach maintaining graphene's structural and electrical properties based on non-covalent, aromatic functionalization.

  12. Transmission electron microscopy of oxide dispersion strengthened (ODS) molybdenum: effects of irradiation on material microstructure

    SciTech Connect (OSTI)

    Baranwal, R. and Burke, M.G.

    2003-03-03

    Oxide dispersion strengthened (ODS) molybdenum has been characterized using transmission electron microscopy (TEM) to determine the effects of irradiation on material microstructure. This work describes the results-to-date from TEM characterization of unirradiated and irradiated ODS molybdenum. The general microstructure of the unirradiated material consists of fine molybdenum grains (< 5 {micro}m average grain size) with numerous low angle boundaries and isolated dislocation networks. 'Ribbon'-like lanthanum oxides are aligned along the working direction of the product form and are frequently associated with grain boundaries, serving to inhibit grain boundary and dislocation movement. In addition to the 'ribbons', discrete lanthanum oxide particles have also been detected. After irradiation, the material is characterized by the presence of nonuniformly distributed large ({approx} 20 to 100 nm in diameter), multi-faceted voids, while the molybdenum grain size and oxide morphology appear to be unaffected by irradiation.

  13. Dynamics of soft Nanomaterials captured by transmission electron microscopy in liquid water

    SciTech Connect (OSTI)

    Proetto, Maria T.; Rush, Anthony M.; Chien, Miao-Ping; Abellan Baeza, Patricia; Patterson, Joseph P.; Thompson, Matthew P.; Olson, Norman H.; Moore, Curtis E.; Rheingold, Arnold L.; Andolina, Christopher; Millstone, Jill; Howell, Stephen B.; Browning, Nigel D.; Evans, James E.; Gianneschi, Nathan C.

    2014-01-14

    In this paper we present in situ transmission electron microscopy (TEM) of soft, synthetic nanoparticles with a comparative analysis using conventional TEM methods. This comparison is made with the simple aim of describing what is an unprecedented example of in situ imaging by TEM. However, we contend the technique will quickly become essential in the characterization of analogous systems, especially where dynamics are of interest in the solvated state. In this case, particles were studied which were obtained from the direct polymerization of an oxaliplatin analog, designed for an ongoing program in novel chemotherapeutic delivery systems. The resulting nanoparticles provided sufficient contrast for facile imaging in situ, and point toward key design parameters that enable this new characterization approach for organic nanomaterials. We describe the preparation of the synthetic micellar nanoparticles to- gether with their characterization in liquid water.

  14. Contribution of charge-transfer processes to ion-induced electron emission

    SciTech Connect (OSTI)

    Roesler, M.

    1996-12-01

    Charge changing events of ions moving inside metals are shown to contribute significantly to electron emission in the intermediate velocity regime via electrons coming from projectile ionization. Inclusion of equilibrium charge state fractions, together with two-electron Auger processes and resonant-coherent electron loss from the projectile, results in reasonable agreement with previous calculations for frozen protons, though a significant part of the emission is now interpreted in terms of charge exchange. The quantal character of the surface barrier transmission is shown to play an important role. The theory compares well with experimental observations for {ital H} projectiles. {copyright} {ital 1996 The American Physical Society.}

  15. Defects in paramagnetic Co-doped ZnO films studied by transmission electron microscopy

    SciTech Connect (OSTI)

    Kovcs, A.; Duchamp, M.; Boothroyd, C. B.; Dunin-Borkowski, R. E.; Ney, A.; Ney, V.; Galindo, P. L.; Kaspar, T. C.; Chambers, S. A.

    2013-12-28

    We study planar defects in epitaxial Co:ZnO dilute magnetic semiconductor thin films deposited on c-plane sapphire (Al{sub 2}O{sub 3}), as well as the Co:ZnO/Al{sub 2}O{sub 3} interface, using aberration-corrected transmission electron microscopy and electron energy-loss spectroscopy. Co:ZnO samples that were deposited using pulsed laser deposition and reactive magnetron sputtering are both found to contain extrinsic stacking faults, incoherent interface structures, and compositional variations within the first 34 Co:ZnO layers next to the Al{sub 2}O{sub 3} substrate. The stacking fault density is in the range of 10{sup 17} cm{sup ?3}. We also measure the local lattice distortions around the stacking faults. It is shown that despite the relatively high density of planar defects, lattice distortions, and small compositional variation, the Co:ZnO films retain paramagnetic properties.

  16. Lithium electrodeposition dynamics in aprotic electrolyte observed in situ via transmission electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leenheer, Andrew Jay; Jungjohann, Katherine Leigh; Zavadil, Kevin Robert; Sullivan, John P.; Harris, Charles Thomas

    2015-03-18

    Electrodeposited metallic lithium is an ideal negative battery electrode, but nonuniform microstructure evolution during cycling leads to degradation and safety issues. A better understanding of the Li plating and stripping processes is needed to enable practical Li-metal batteries. Here we use a custom microfabricated, sealed liquid cell for in situ scanning transmission electron microscopy (STEM) to image the first few cycles of lithium electrodeposition/dissolution in liquid aprotic electrolyte at submicron resolution. Cycling at current densities from 1 to 25 mA/cm2 leads to variations in grain structure, with higher current densities giving a more needle-like, higher surface area deposit. The effectmore » of the electron beam was explored, and it was found that, even with minimal beam exposure, beam-induced surface film formation could alter the Li microstructure. The electrochemical dissolution was seen to initiate from isolated points on grains rather than uniformly across the Li surface, due to the stabilizing solid electrolyte interphase surface film. As a result, we discuss the implications for operando STEM liquid-cell imaging and Li-battery applications.« less

  17. The transfer between electron bulk kinetic energy and thermal energy in collisionless magnetic reconnection

    SciTech Connect (OSTI)

    Lu, San; Lu, Quanming; Huang, Can; Wang, Shui

    2013-06-15

    By performing two-dimensional particle-in-cell simulations, we investigate the transfer between electron bulk kinetic and electron thermal energy in collisionless magnetic reconnection. In the vicinity of the X line, the electron bulk kinetic energy density is much larger than the electron thermal energy density. The evolution of the electron bulk kinetic energy is mainly determined by the work done by the electric field force and electron pressure gradient force. The work done by the electron gradient pressure force in the vicinity of the X line is changed to the electron enthalpy flux. In the magnetic island, the electron enthalpy flux is transferred to the electron thermal energy due to the compressibility of the plasma in the magnetic island. The compression of the plasma in the magnetic island is the consequence of the electromagnetic force acting on the plasma as the magnetic field lines release their tension after being reconnected. Therefore, we can observe that in the magnetic island the electron thermal energy density is much larger than the electron bulk kinetic energy density.

  18. Probing the dependence of electron transfer on size and coverage in carbon nanotube-quantum dot heterostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Lei; Wong, Stanislaus S.; Han, Jinkyu; Zhu, Yuqi; Jaye, Cherno; Liu, Haiqing; Li, Zhuo -Qun; Taylor, Gordon T.; Fischer, Daniel A.; Appenzeller, Joerg; et al

    2015-11-16

    As a model system for understanding charge transfer in novel architectural designs for solar cells, double-walled carbon nanotube (DWNT)–CdSe quantum dot (QD) (QDs with average diameters of 2.3, 3.0, and 4.1 nm) heterostructures have been fabricated. The individual nanoscale building blocks were successfully attached and combined using a hole-trapping thiol linker molecule, i.e., 4-mercaptophenol (MTH), through a facile, noncovalent π–π stacking attachment strategy. Transmission electron microscopy confirmed the attachment of QDs onto the external surfaces of the DWNTs. We herein demonstrate a meaningful and unique combination of near-edge X-ray absorption fine structure (NEXAFS) and Raman spectroscopies bolstered by complementary electricalmore » transport measurements in order to elucidate the synergistic interactions between CdSe QDs and DWNTs, which are facilitated by the bridging MTH molecules that can scavenge photoinduced holes and potentially mediate electron redistribution between the conduction bands in CdSe QDs and the C 2p-derived states of the DWNTs. Specifically, we correlated evidence of charge transfer as manifested by (i) changes in the NEXAFS intensities of π* resonance in the C K-edge and Cd M3-edge spectra, (ii) a perceptible outer tube G-band downshift in frequency in Raman spectra, as well as (iii) alterations in the threshold characteristics present in transport data as a function of CdSe QD deposition onto the DWNT surface. Furthermore, the separate effects of (i) varying QD sizes and (ii) QD coverage densities on the electron transfer were independently studied.« less

  19. Probing the dependence of electron transfer on size and coverage in carbon nanotube-quantum dot heterostructures

    SciTech Connect (OSTI)

    Wang, Lei; Wong, Stanislaus S.; Han, Jinkyu; Zhu, Yuqi; Jaye, Cherno; Liu, Haiqing; Li, Zhuo -Qun; Taylor, Gordon T.; Fischer, Daniel A.; Appenzeller, Joerg; Zhu, Ruiping

    2015-11-16

    As a model system for understanding charge transfer in novel architectural designs for solar cells, double-walled carbon nanotube (DWNT)CdSe quantum dot (QD) (QDs with average diameters of 2.3, 3.0, and 4.1 nm) heterostructures have been fabricated. The individual nanoscale building blocks were successfully attached and combined using a hole-trapping thiol linker molecule, i.e., 4-mercaptophenol (MTH), through a facile, noncovalent ?? stacking attachment strategy. Transmission electron microscopy confirmed the attachment of QDs onto the external surfaces of the DWNTs. We herein demonstrate a meaningful and unique combination of near-edge X-ray absorption fine structure (NEXAFS) and Raman spectroscopies bolstered by complementary electrical transport measurements in order to elucidate the synergistic interactions between CdSe QDs and DWNTs, which are facilitated by the bridging MTH molecules that can scavenge photoinduced holes and potentially mediate electron redistribution between the conduction bands in CdSe QDs and the C 2p-derived states of the DWNTs. Specifically, we correlated evidence of charge transfer as manifested by (i) changes in the NEXAFS intensities of ?* resonance in the C K-edge and Cd M3-edge spectra, (ii) a perceptible outer tube G-band downshift in frequency in Raman spectra, as well as (iii) alterations in the threshold characteristics present in transport data as a function of CdSe QD deposition onto the DWNT surface. Furthermore, the separate effects of (i) varying QD sizes and (ii) QD coverage densities on the electron transfer were independently studied.

  20. Convective Heat Transfer Coefficients of Automatic Transmission Fluid Jets with Implications for Electric Machine Thermal Management: Preprint

    SciTech Connect (OSTI)

    Bennion, Kevin; Moreno, Gilberto

    2015-09-29

    Thermal management for electric machines (motors/ generators) is important as the automotive industry continues to transition to more electrically dominant vehicle propulsion systems. Cooling of the electric machine(s) in some electric vehicle traction drive applications is accomplished by impinging automatic transmission fluid (ATF) jets onto the machine's copper windings. In this study, we provide the results of experiments characterizing the thermal performance of ATF jets on surfaces representative of windings, using Ford's Mercon LV ATF. Experiments were carried out at various ATF temperatures and jet velocities to quantify the influence of these parameters on heat transfer coefficients. Fluid temperatures were varied from 50 degrees C to 90 degrees C to encompass potential operating temperatures within an automotive transaxle environment. The jet nozzle velocities were varied from 0.5 to 10 m/s. The experimental ATF heat transfer coefficient results provided in this report are a useful resource for understanding factors that influence the performance of ATF-based cooling systems for electric machines.

  1. High resolution transmission electron microscopy of melamine-formaldehyde aerogels and silica aerogels

    SciTech Connect (OSTI)

    Ruben, G.C. (Dartmouth Coll., Hanover, NH (United States). Dept. of Biological Sciences)

    1991-09-01

    The goal of the high resolution transmission electron microscopy (HRTEM) was to image the structure of two tetramethyl orthosilicate (TMOS) and two melamine-formaldehyde (MF) aerogels at the single polymer chain level{sup 1,2}. With this level of structural resolution we hoped to interrelate each aerogel's structure with its physical properties and its method of synthesis. Conventional single-step base catalysed TMOS aerogels show strings of spheroidal particles linked together with minimal necking. The spheroidal particles range from 86--132 {Angstrom} and average 113{plus minus}10 {Angstrom} in diameter{sup 2}. In contrast the TMOS aerogels reported on here were made by a two step method. After extended silica chains are grown in solution under acidic conditions with a substoichiometric amount of water, the reaction is stopped and the methanol hydrolysed from TMOS is removed. Then base catalysis and additional water are added to cause gel formation is a nonalcoholic solvent. The MF aerogels were prepared for HRTEM by fracturing them on a stereo microscope stage with razor knife so that fractured pieces with smooth flat surfaces could be selected for platinum-carbon replication. The two silica (TMOS) aerogels were both transparent and difficult to see. These aerogels were fractured on a stereo microscope stage with tweezers. 6 refs., 4 figs.

  2. Real-time studies of battery electrochemical reactions inside a transmission electron microscope.

    SciTech Connect (OSTI)

    Leung, Kevin; Hudak, Nicholas S.; Liu, Yang; Liu, Xiaohua H.; Fan, Hongyou; Subramanian, Arunkumar; Shaw, Michael J.; Sullivan, John Patrick; Huang, Jian Yu

    2012-01-01

    We report the development of new experimental capabilities and ab initio modeling for real-time studies of Li-ion battery electrochemical reactions. We developed three capabilities for in-situ transmission electron microscopy (TEM) studies: a capability that uses a nanomanipulator inside the TEM to assemble electrochemical cells with ionic liquid or solid state electrolytes, a capability that uses on-chip assembly of battery components on to TEM-compatible multi-electrode arrays, and a capability that uses a TEM-compatible sealed electrochemical cell that we developed for performing in-situ TEM using volatile battery electrolytes. These capabilities were used to understand lithiation mechanisms in nanoscale battery materials, including SnO{sub 2}, Si, Ge, Al, ZnO, and MnO{sub 2}. The modeling approaches used ab initio molecular dynamics to understand early stages of ethylene carbonate reduction on lithiated-graphite and lithium surfaces and constrained density functional theory to understand ethylene carbonate reduction on passivated electrode surfaces.

  3. Powering microbes with electricity: direct electron transfer from electrodes to microbes

    SciTech Connect (OSTI)

    Lovley, DR

    2010-09-16

    P>The discovery of electrotrophs, microorganisms that can directly accept electrons from electrodes for the reduction of terminal electron acceptors, has spurred the investigation of a wide range of potential applications. To date, only a handful of pure cultures have been shown to be capable of electrotrophy, but this process has also been inferred in many studies with undefined consortia. Potential electron acceptors include: carbon dioxide, nitrate, metals, chlorinated compounds, organic acids, protons and oxygen. Direct electron transfer from electrodes to cells has many advantages over indirect electrical stimulation of microbial metabolism via electron shuttles or hydrogen production. Supplying electrons with electrodes for the bioremediation of chlorinated compounds, nitrate or toxic metals may be preferable to adding organic electron donors or hydrogen to the subsurface or bioreactors. The most transformative application of electrotrophy may be microbial electrosynthesis in which carbon dioxide and water are converted to multi-carbon organic compounds that are released extracellularly. Coupling photovoltaic technology with microbial electrosynthesis represents a novel photosynthesis strategy that avoids many of the drawbacks of biomass-based strategies for the production of transportation fuels and other organic chemicals. The mechanisms for direct electron transfer from electrodes to microorganisms warrant further investigation in order to optimize envisioned applications.

  4. Constraint-Based Modeling of Carbon Fixation and the Energetics of Electron Transfer in Geobacter metallireducens

    SciTech Connect (OSTI)

    Feist, AM; Nagarajan, H; Rotaru, AE; Tremblay, PL; Zhang, T; Nevin, KP; Lovley, DR; Zengler, K

    2014-04-24

    Geobacter species are of great interest for environmental and biotechnology applications as they can carry out direct electron transfer to insoluble metals or other microorganisms and have the ability to assimilate inorganic carbon. Here, we report on the capability and key enabling metabolic machinery of Geobacter metallireducens GS-15 to carry out CO2 fixation and direct electron transfer to iron. An updated metabolic reconstruction was generated, growth screens on targeted conditions of interest were performed, and constraint-based analysis was utilized to characterize and evaluate critical pathways and reactions in G. metallireducens. The novel capability of G. metallireducens to grow autotrophically with formate and Fe(III) was predicted and subsequently validated in vivo. Additionally, the energetic cost of transferring electrons to an external electron acceptor was determined through analysis of growth experiments carried out using three different electron acceptors (Fe(III), nitrate, and fumarate) by systematically isolating and examining different parts of the electron transport chain. The updated reconstruction will serve as a knowledgebase for understanding and engineering Geobacter and similar species. Author Summary The ability of microorganisms to exchange electrons directly with their environment has large implications for our knowledge of industrial and environmental processes. For decades, it has been known that microbes can use electrodes as electron acceptors in microbial fuel cell settings. Geobacter metallireducens has been one of the model organisms for characterizing microbe-electrode interactions as well as environmental processes such as bioremediation. Here, we significantly expand the knowledge of metabolism and energetics of this model organism by employing constraint-based metabolic modeling. Through this analysis, we build the metabolic pathways necessary for carbon fixation, a desirable property for industrial chemical production. We further discover a novel growth condition which enables the characterization of autotrophic (i.e., carbon-fixing) metabolism in Geobacter. Importantly, our systems-level modeling approach helped elucidate the key metabolic pathways and the energetic cost associated with extracellular electron transfer. This model can be applied to characterize and engineer the metabolism and electron transfer capabilities of Geobacter for biotechnological applications.

  5. Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

    SciTech Connect (OSTI)

    Warren, Jeffrey J.; Tronic, Tristan A.; Mayer, James M.

    2010-12-08

    Many, if not most, redox reactions are coupled to proton transfers. This includes most common sources of chemical potential energy, from the bioenergetic processes that power cells to the fossil fuel combustion that powers cars. These proton-coupled electron transfer or PCET processes may involve multiple electrons and multiple protons, as in the 4 e, 4 H+ reduction of dioxygen (O2) to water (eq 1), or can involve one electron and one proton such as the formation of tyrosyl radicals from tyrosine residues (TyrOH) in enzymatic catalytic cycles (eq 2). In addition, many multi-electron, multi-proton processes proceed in one-electron and one-proton steps. Organic reactions that proceed in one-electron steps involve radical intermediates, which play critical roles in a wide range of chemical, biological, and industrial processes. This broad and diverse class of PCET reactions are central to a great many chemical and biochemical processes, from biological catalysis and energy transduction, to bulk industrial chemical processes, to new approaches to solar energy conversion. PCET is therefore of broad and increasing interest, as illustrated by this issue and a number of other recent reviews.

  6. Quantum DotBridgeFullerene Heterodimers with Controlled Photoinduced Electron Transfer

    SciTech Connect (OSTI)

    Cotlet, M.; Xu, Z.

    2011-06-27

    A series of donor-bridge-acceptor systems in the form of core/shell CdSe/ZnS quantum dot-bridge-fullerene heterodimers (see picture) with varying bridge length and varying quantum dot size were self-assembled by a surface-based stepwise method to demonstrate control of the rate and of the magnitude of fluctuations of photoinduced electron transfer at the single-molecule level.

  7. Metal complex-based electron-transfer mediators in dye-sensitized solar cells

    DOE Patents [OSTI]

    Elliott, C. Michael (Fort Collins, CO); Sapp, Shawn A. (Broomfield, CO); Bignozzi, Carlo Alberto (Ferrara, IT); Contado, Cristiano (Legnago, IT); Caramori, Stefano (Viconovo, IT)

    2006-03-28

    This present invention provides a metal-ligand complex and methods for using and preparing the same. In particular, the metal-ligand complex of the present invention is of the formula: L.sub.a-M-X.sub.b where L, M, X, a, and b are those define herein. The metal-ligand complexes of the present invention are useful in a variety of applications including as electron-transfer mediators in dye-sensitized solar cells and related photoelectrochromic devices.

  8. A single-shot transmissive spectrometer for hard x-ray free electron...

    Office of Scientific and Technical Information (OSTI)

    characteristic of a self-amplified spontaneous emission x-ray free electron laser source. ... Resource Relation: Journal Name: Applied Physics Letters; Journal Volume: 101; Journal ...

  9. Proton-Coupled Electron Transfer in Molecular Electrocatalysis: Theoretical Methods and Design Principles

    SciTech Connect (OSTI)

    Solis, Brian H.; Hammes-Schiffer, Sharon

    2014-07-07

    Molecular electrocatalysts play an essential role in a wide range of energy conversion processes. The objective of electrocatalyst design is to maximize the turnover frequency and minimize the overpotential for the overall catalytic cycle. Typically the catalytic cycle is dominated by key proton-coupled electron transfer (PCET) processes comprised of sequential or concerted electron transfer and proton transfer steps. A variety of theoretical methods have been developed to investigate the mechanisms, thermodynamics, and kinetics of PCET processes in electrocatalytic cycles. Electronic structure methods can be used to calculate the reduction potentials and pKa’s and to generate thermodynamic schemes, free energy reaction pathways, and Pourbaix diagrams, which indicate the most stable species at each pH and potential. These types of calculations have assisted in identifying the thermodynamically favorable mechanisms under specified experimental conditions, such as acid strength and overpotential. Such calculations have also revealed linear correlations among the thermodynamic properties, which can be used to predict the impact of modifying the ligand, substituents, or metal center. The role of non-innocent ligands, namely ligand protonation or reduction, has also been examined theoretically. In addition, the rate constants for electron and proton transfer reactions, as well as concerted PCET reactions, have been calculated to investigate the kinetics of molecular electrocatalysts. The concerted PCET mechanism is thought to lower the overpotential required for catalysis by avoiding high-energy intermediates. Rate constant calculations have revealed that the concerted mechanism involving intramolecular proton transfer will be favored by designing more flexible ligands that facilitate the proton donor-acceptor motion while also maintaining a sufficiently short equilibrium proton donor-acceptor distance. Overall, theoretical methods have assisted in the interpretation of experimental data and the design of more effective molecular electrocatalysts. The research on the Ni(P2N2)2 catalysts was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

  10. Largely defocused probe scanning transmission electron microscopy for imaging local modulation of strain field in a hetero interface

    SciTech Connect (OSTI)

    Kim, Suhyun Jung, Younheum; Kim, Joong Jung; Lee, Sunyoung; Lee, Haebum; Oshima, Yoshifumi

    2014-10-13

    We present an innovative method for characterizing the strain field in three dimensions in a hetero interface. Largely defocused probe scanning transmission electron microscopy (LDP-STEM) was employed for imaging the inhomogeneous strain field in a germanium (Ge) layer deposited on a silicon (Si) substrate. In the LDP-STEM image, Ge-atomic columns that are relaxed or strained to the Si substrate in the Si/Ge hetero interface were observed to be distinguishable, allowing for the qualitative characterization of the coherency of the crystal growth. Our results revealed that the strain field is locally modulated along the in-plane direction in the Si/Ge hetero interface.

  11. In-situ optical transmission electron microscope study of exciton phonon replicas in ZnO nanowires by cathodoluminescence

    SciTech Connect (OSTI)

    Yang, Shize; Tian, Xuezeng; Wang, Lifen; Wei, Jiake; Qi, Kuo; Li, Xiaomin; Xu, Zhi E-mail: xdbai@iphy.ac.cn Wang, Wenlong; Zhao, Jimin; Bai, Xuedong E-mail: xdbai@iphy.ac.cn; Wang, Enge E-mail: xdbai@iphy.ac.cn

    2014-08-18

    The cathodoluminescence spectrum of single zinc oxide (ZnO) nanowires is measured by in-situ optical Transmission Electron Microscope. The coupling between exciton and longitudinal optical phonon is studied. The band edge emission varies for different excitation spots. This effect is attributed to the exciton propagation along the c axis of the nanowire. Contrary to free exciton emission, the phonon replicas are well confined in ZnO nanowire. They travel along the c axis and emit at the end surface. Bending strain increases the relative intensity of second order phonon replicas when excitons travel along the c-axis.

  12. Transfers

    Broader source: Energy.gov [DOE]

    Transfer means a change of an employee, from one Federal government branch (executive, legislative, judicial) to another or from one agency to another without a break in service of 1 full work day. 

  13. Room temperature, hybrid sodium-based flow batteries with multi-electron transfer redox reactions

    SciTech Connect (OSTI)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volume of the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. Furthermore, the critical barriers to mature this new HNFBs have also been explored.

  14. Room Temperature, Hybrid Sodium-Based Flow Batteries with Multi-Electron Transfer Redox Reactions

    SciTech Connect (OSTI)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volume of the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. The critical barriers to mature this new HNFBs have also been explored.

  15. Electronic and vibronic properties of a discotic liquid-crystal and its charge transfer complex

    SciTech Connect (OSTI)

    Haverkate, Lucas A.; Mulder, Fokko M.; Zbiri, Mohamed Johnson, Mark R.; Carter, Elizabeth; Kotlewski, Arek; Picken, S.

    2014-01-07

    Discotic liquid crystalline (DLC) charge transfer (CT) complexes combine visible light absorption and rapid charge transfer characteristics, being favorable properties for photovoltaic (PV) applications. We present a detailed study of the electronic and vibrational properties of the prototypic 1:1 mixture of discotic 2,3,6,7,10,11-hexakishexyloxytriphenylene (HAT6) and 2,4,7-trinitro-9-fluorenone (TNF). It is shown that intermolecular charge transfer occurs in the ground state of the complex: a charge delocalization of about 10{sup ?2} electron from the HAT6 core to TNF is deduced from both Raman and our previous NMR measurements [L. A. Haverkate, M. Zbiri, M. R. Johnson, B. Deme, H. J. M. de Groot, F. Lefeber, A. Kotlewski, S. J. Picken, F. M. Mulder, and G. J. Kearley, J. Phys. Chem. B 116, 13098 (2012)], implying the presence of permanent dipoles at the donor-acceptor interface. A combined analysis of density functional theory calculations, resonant Raman and UV-VIS absorption measurements indicate that fast relaxation occurs in the UV region due to intramolecular vibronic coupling of HAT6 quinoidal modes with lower lying electronic states. Relatively slower relaxation in the visible region the excited CT-band of the complex is also indicated, which likely involves motions of the TNF nitro groups. The fast quinoidal relaxation process in the hot UV band of HAT6 relates to pseudo-Jahn-Teller interactions in a single benzene unit, suggesting that the underlying vibronic coupling mechanism can be generic for polyaromatic hydrocarbons. Both the presence of ground state CT dipoles and relatively slow relaxation processes in the excited CT band can be relevant concerning the design of DLC based organic PV systems.

  16. Magnetic properties and transmission electron microscopy studies of Ni nanoparticles encapsulated in carbon nanocages and carbon nanotubes

    SciTech Connect (OSTI)

    He Chunnian; Zhao Naiqin Shi Chunsheng; Li Jiajun; Li Haipeng

    2008-08-04

    Three types of carbon nanomaterials, including bamboo-shaped carbon nanotubes with Ni encapsulated and hollow and Ni catalytic particles filled carbon nanocages, have been prepared by methane catalytic decomposition at a relatively low temperature. Transmission electron microscopy observations showed that fascinating fullerene-like Ni-C (graphitic) core-shell nanostructures predominated. Detailed examination of high-resolution transmission electron microscopy showed that the walls of bamboo-shaped carbon nanotubes with quasi-cone catalytic particles encapsulated consisted of oblique graphene planes with respect to the tube axis. The Ni particles encapsulated in the carbon nanocages were larger than that encapsulated in carbon nanotubes, but the diameters of the cores of hollow carbon nanocages were less than that of Ni particles encapsulated in carbon nanotubes, suggesting that the sizes of catalyst particles played an important role during carbon nanomaterial growth. The magnetic properties of the carbon nanomaterials were measured, which showed relatively large coercive force (H{sub c} = 138.4 O{sub e}) and good ferromagnetism (M{sub r}/M{sub s} = 0.325)

  17. Fragment transition density method to calculate electronic coupling for excitation energy transfer

    SciTech Connect (OSTI)

    Voityuk, Alexander A.

    2014-06-28

    A general approach, the Fragment Transition Density (FTD) scheme, is introduced to estimate electronic coupling for excitation energy transfer in a molecular system. Within this method, the excitation energies and transition densities of the system are used to derive the coupling matrix element. The scheme allows one to treat systems where exciton donor and acceptor are close together and their exchange interaction and orbital overlap are significant. The FTD method can be applied in combination with any quantum mechanical approach to treat excited states of general nature including single-, double-, and higher excitations. Using FTD approach, we derive excitonic couplings for several systems computed with the CIS, TD DFT and MS-CASPT2 methods. In particular, it is shown that the estimated coupling values in DNA ?-stacks are strongly affected by the short-range electronic interaction of adjacent nucleobases.

  18. Ultrafast electron transfer at organic semiconductor interfaces: Importance of molecular orientation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ayzner, Alexander L.; Nordlund, Dennis; Kim, Do -Hwan; Bao, Zhenan; Toney, Michael F.

    2014-12-04

    Much is known about the rate of photoexcited charge generation in at organic donor/acceptor (D/A) heterojunctions overaged over all relative arrangements. However, there has been very little experimental work investigating how the photoexcited electron transfer (ET) rate depends on the precise relative molecular orientation between D and A in thin solid films. This is the question that we address in this work. We find that the ET rate depends strongly on the relative molecular arrangement: The interface where the model donor compound copper phthalocyanine is oriented face-on with respect to the fullerene C60 acceptor yields a rate that is approximatelymore » 4 times faster than that of the edge-on oriented interface. Our results suggest that the D/A electronic coupling is significantly enhanced in the face-on case, which agrees well with theoretical predictions, underscoring the importance of controlling the relative interfacial molecular orientation.« less

  19. Ultrafast electron transfer at organic semiconductor interfaces: Importance of molecular orientation

    SciTech Connect (OSTI)

    Ayzner, Alexander L.; Nordlund, Dennis; Kim, Do -Hwan; Bao, Zhenan; Toney, Michael F.

    2014-12-04

    Much is known about the rate of photoexcited charge generation in at organic donor/acceptor (D/A) heterojunctions overaged over all relative arrangements. However, there has been very little experimental work investigating how the photoexcited electron transfer (ET) rate depends on the precise relative molecular orientation between D and A in thin solid films. This is the question that we address in this work. We find that the ET rate depends strongly on the relative molecular arrangement: The interface where the model donor compound copper phthalocyanine is oriented face-on with respect to the fullerene C60 acceptor yields a rate that is approximately 4 times faster than that of the edge-on oriented interface. Our results suggest that the D/A electronic coupling is significantly enhanced in the face-on case, which agrees well with theoretical predictions, underscoring the importance of controlling the relative interfacial molecular orientation.

  20. High-speed multiframe dynamic transmission electron microscope image acquisition system with arbitrary timing

    DOE Patents [OSTI]

    Reed, Bryan W.; DeHope, William J.; Huete, Glenn; LaGrange, Thomas B.; Shuttlesworth, Richard M.

    2015-10-20

    An electron microscope is disclosed which has a laser-driven photocathode and an arbitrary waveform generator (AWG) laser system ("laser"). The laser produces a train of temporally-shaped laser pulses of a predefined pulse duration and waveform, and directs the laser pulses to the laser-driven photocathode to produce a train of electron pulses. An image sensor is used along with a deflector subsystem. The deflector subsystem is arranged downstream of the target but upstream of the image sensor, and has two pairs of plates arranged perpendicular to one another. A control system controls the laser and a plurality of switching components synchronized with the laser, to independently control excitation of each one of the deflector plates. This allows each electron pulse to be directed to a different portion of the image sensor, as well as to be provided with an independently set duration and independently set inter-pulse spacings.

  1. Coupled electron-nuclear dynamics: Charge migration and charge transfer initiated near a conical intersection

    SciTech Connect (OSTI)

    Mendive-Tapia, David; Vacher, Morgane; Bearpark, Michael J.; Robb, Michael A.

    2013-07-28

    Coupled electron-nuclear dynamics, implemented using the Ehrenfest method, has been used to study charge migration with fixed nuclei, together with charge transfer when nuclei are allowed to move. Simulations were initiated at reference geometries of neutral benzene and 2-phenylethylamine (PEA), and at geometries close to potential energy surface crossings in the cations. Cationic eigenstates, and the so-called sudden approximation, involving removal of an electron from a correlated ground-state wavefunction for the neutral species, were used as initial conditions. Charge migration without coupled nuclear motion could be observed if the Ehrenfest simulation, using the sudden approximation, was started near a conical intersection where the states were both strongly coupled and quasi-degenerate. Further, the main features associated with charge migration were still recognizable when the nuclear motion was allowed to couple. In the benzene radical cation, starting from the reference neutral geometry with the sudden approximation, one could observe sub-femtosecond charge migration with a small amplitude, which results from weak interaction with higher electronic states. However, we were able to engineer large amplitude charge migration, with a period between 10 and 100 fs, corresponding to oscillation of the electronic structure between the quinoid and anti-quinoid cationic electronic configurations, by distorting the geometry along the derivative coupling vector from the D{sub 6h} Jahn-Teller crossing to lower symmetry where the states are not degenerate. When the nuclear motion becomes coupled, the period changes only slightly. In PEA, in an Ehrenfest trajectory starting from the D{sub 2} eigenstate and reference geometry, a partial charge transfer occurs after about 12 fs near the first crossing between D{sub 1}, D{sub 2} (N{sup +}-Phenyl, N-Phenyl{sup +}). If the Ehrenfest propagation is started near this point, using the sudden approximation without coupled nuclear motion, one observes an oscillation of the spin density charge migration between the N atom and the phenyl ring with a period of 4 fs. When the nuclear motion becomes coupled, this oscillation persists in a damped form, followed by an effective charge transfer after 30 fs.

  2. Mechanisms for Electron Transfer Through Pili to Fe(III) Oxide in Geobacter

    SciTech Connect (OSTI)

    Lovley, Derek R.

    2015-03-09

    The purpose of these studies was to aid the Department of Energy in its goal of understanding how microorganisms involved in the bioremediation of metals and radionuclides sustain their activity in the subsurface. This information is required in order to incorporate biological processes into decision making for environmental remediation and long-term stewardship of contaminated sites. The proposed research was designed to elucidate the mechanisms for electron transfer to Fe(III) oxides in Geobacter species because Geobacter species are abundant dissimilatory metal-reducing microorganisms in a diversity of sites in which uranium is undergoing natural attenuation via the reduction of soluble U(VI) to insoluble U(IV) or when this process is artificially stimulated with the addition of organic electron donors. This study investigated the novel, but highly controversial, concept that the final conduit for electron transfer to Fe(III) oxides are electrically conductive pili. The specific objectives were to: 1) further evaluate the conductivity along the pili of Geobacter sulfurreducens and related organisms; 2) determine the mechanisms for pili conductivity; and 3) investigate the role of pili in Fe(III) oxide reduction. The studies demonstrated that the pili of G. sulfurreducens are conductive along their length. Surprisingly, the pili possess a metallic-like conductivity similar to that observed in synthetic organic conducting polymers such as polyaniline. Detailed physical analysis of the pili, as well as studies in which the structure of the pili was genetically modified, demonstrated that the metallic-like conductivity of the pili could be attributed to overlapping pi-pi orbitals of aromatic amino acids. Other potential mechanisms for conductivity, such as electron hopping between cytochromes associated with the pili were definitively ruled out. Pili were also found to be essential for Fe(III) oxide reduction in G. metallireducens. Ecological studies demonstrated that electron conduction along pili is a better strategy for Fe(III) oxide reduction under conditions found in the subsurface than producing an electron shuttle. The role of pili in uranium reduction was also elucidated. Our results are the first example of metallic-like conductivity in a biological protein and represent a paradigm shift in the understanding of long-range biological electron transport. The results are of importance not only for understanding subsurface microbial processes involved in the mobility of metal contaminants and carbon cycling, but also make a basic contribution to microbiology and the emerging field of bioelectronics.

  3. Fundamental studies of energy-and hole/electron- transfer in hydroporphyrin architectures

    SciTech Connect (OSTI)

    Bocian, David F.

    2014-08-20

    The long-term objective of the Bocian/Holten/Lindsey research program is to design, synthesize, and characterize tetrapyrrole-based molecular architectures that absorb sunlight, funnel energy, and separate charge with high efficiency and in a manner compatible with current and future solar-energy conversion schemes. The synthetic tetrapyrroles include porphyrins and hydroporphyrins; the latter classes of molecules encompass analogues of the naturally occurring chlorophylls and bacteriochlorophylls (e.g., chlorins, bacteriochlorins, and their derivatives). The attainment of the goals of the research program requires the close interplay of molecular design and synthesis (Lindsey group), static and time-resolved optical spectroscopic measurements (Holten group), and electrochemical, electron paramagnetic resonance, and resonance Raman studies, as well as density functional theory calculations (Bocian Group). The proposed research encompasses four interrelated themes: (1) Determination of the rates of ground-state hole/electron transfer between (hydro)porphyrins in multipigment arrays as a function of array size, distance between components, linker type, site of linker connection, and frontier molecular orbital composition. (2) Examination of excited-state energy transfer among hydroporphyrins in multipigment arrrays, including both pairwise and non-adjacent transfer, with a chief aim to identify the relative contributions of through-space (Förster) and through-bond (Dexter) mechanisms of energy transfer, including the roles of site of linker connection and frontier molecular orbital composition. (3) Elucidation of the role of substituents in tuning the spectral and electronic properties of bacteriochlorins, with a primary aim of learning how to shift the long-wavelength absorption band deeper into the near-infrared region. (4) Continued development of the software package PhotochemCAD for spectral manipulations and calculations through the compilation of a database of spectra for naturally occurring and synthetic hydroporphyrins. The availability of such data should augment efforts in the design of light-harvesting systems where spectral coverage in the red and near-infrared regions is desired. Collectively, the proposed studies will provide fundamental insights into molecular properties, interactions, and processes relevant to the design of molecular architectures for solar-energy conversion. The accomplishment of these goals is only possible through a highly synergistic program that encompasses molecular design, synthesis, and characterization.

  4. Dynamic Processes in Biology, Chemistry, and Materials Science: Opportunities for UltraFast Transmission Electron Microscopy - Workshop Summary Report

    SciTech Connect (OSTI)

    Kabius, Bernd C.; Browning, Nigel D.; Thevuthasan, Suntharampillai; Diehl, Barbara L.; Stach, Eric A.

    2012-07-25

    This report summarizes a 2011 workshop that addressed the potential role of rapid, time-resolved electron microscopy measurements in accelerating the solution of important scientific and technical problems. A series of U.S. Department of Energy (DOE) and National Academy of Science workshops have highlighted the critical role advanced research tools play in addressing scientific challenges relevant to biology, sustainable energy, and technologies that will fuel economic development without degrading our environment. Among the specific capability needs for advancing science and technology are tools that extract more detailed information in realistic environments (in situ or operando) at extreme conditions (pressure and temperature) and as a function of time (dynamic and time-dependent). One of the DOE workshops, Future Science Needs and Opportunities for Electron Scattering: Next Generation Instrumentation and Beyond, specifically addressed the importance of electron-based characterization methods for a wide range of energy-relevant Grand Scientific Challenges. Boosted by the electron optical advancement in the last decade, a diversity of in situ capabilities already is available in many laboratories. The obvious remaining major capability gap in electron microscopy is in the ability to make these direct in situ observations over a broad spectrum of fast (µs) to ultrafast (picosecond [ps] and faster) temporal regimes. In an effort to address current capability gaps, EMSL, the Environmental Molecular Sciences Laboratory, organized an Ultrafast Electron Microscopy Workshop, held June 14-15, 2011, with the primary goal to identify the scientific needs that could be met by creating a facility capable of a strongly improved time resolution with integrated in situ capabilities. The workshop brought together more than 40 leading scientists involved in applying and/or advancing electron microscopy to address important scientific problems of relevance to DOE’s research mission. This workshop built on previous workshops and included three breakout sessions identifying scientific challenges in biology, biogeochemistry, catalysis, and materials science frontier areas of fundamental science that underpin energy and environmental science that would significantly benefit from ultrafast transmission electron microscopy (UTEM). In addition, the current status of time-resolved electron microscopy was examined, and the technologies that will enable future advances in spatio-temporal resolution were identified in a fourth breakout session.

  5. Electron line shape and transmission function of the KATRIN monitor spectrometer

    SciTech Connect (OSTI)

    Slezk, M. [Faculty of Mathematics and Physics, Charles University, Ke Karlovu 3, 12116 Prague, Czech Republic and Nuclear Physics Institute, Academy of Sciences of the Czech Republic, Hlavn 130, 25068 ?e (Czech Republic)

    2013-12-30

    Knowledge of the neutrino mass is of particular interest in modern neutrino physics. Besides the neutrinoless double beta decay and cosmological observation information about the neutrino mass is obtained from single beta decay by observing the shape of the electron spectrum near the endpoint. The KATRIN ? decay experiment aims to push the limit on the effective electron antineutrino mass down to 0.2 eV/c{sup 2}. To reach this sensitivity several systematic effects have to be under control. One of them is the fluctuations of the absolute energy scale, which therefore has to be continuously monitored at very high precision. This paper shortly describes KATRIN, the technique for continuous monitoring of the absolute energy scale and recent improvements in analysis of the monitoring data.

  6. REAL-TIME TRACER MONITORING OF RESERVOIR STIMULATION PROCEDURES VIA ELECTRONIC WIRELINE AND TELEMETRY DATA TRANSMISSION

    SciTech Connect (OSTI)

    George Scott III

    2003-08-01

    Ongoing Phase 2-3 work comprises the final development and field-testing of two complementary real-time reservoir technologies; a stimulation process and a tracer fracturing diagnostic system. Initial DE-FC26-99FT40129 project work included research, development, and testing of the patented gamma tracer fracturing diagnostic system. This process was field-proven to be technically useful in providing tracer measurement of fracture height while fracturing; however, technical licensing restrictions blocked Realtimezone from fully field-testing this real-time gamma diagnostic system, as originally planned. Said restrictions were encountered during Phase 2 field test work as result of licensing limitations and potential conflicts between service companies participating in project work, as related to their gamma tracer logging tool technology. Phase 3 work principally demonstrated field-testing of Realtimezone (RTZ) and NETL's Downhole-mixed Reservoir Stimulation process. Early on, the simplicity of and success of downhole-mixing was evident from well tests, which were made commercially productive. A downhole-mixed acid stimulation process was tested successfully and is currently commercially used in Canada. The fourth well test was aborted due to well bore conditions, and an alternate test project is scheduled April, 2004. Realtimezone continues to effectuate ongoing patent protection in the United States and foreign markets. In 2002, Realtimezone and the NETL licensed their United States patent to Halliburton Energy Services (HES). Additional licensing arrangements with other industry companies are anticipated in 2004-2005. Ongoing Phase 2 and Phase 3 field-testing continues to confirm applications of both real-time technologies. Technical data transfer to industry is ongoing via Internet tech-transfer and various industry presentations and publications including Society of Petroleum Engineers. These real-time enhanced stimulation procedures should significantly increase future petroleum well recoveries in the United States, onshore and offshore, and in vertical and horizontal wells.

  7. Combining nanocalorimetry and dynamic transmission electron microscopy for in situ characterization of materials processes under rapid heating and cooling

    SciTech Connect (OSTI)

    Grapes, Michael D.; LaGrange, Thomas; Reed, Bryan W.; Campbell, Geoffrey H.; Friedman, Lawrence H.; LaVan, David A.; Weihs, Timothy P.

    2014-08-15

    Nanocalorimetry is a chip-based thermal analysis technique capable of analyzing endothermic and exothermic reactions at very high heating and cooling rates. Here, we couple a nanocalorimeter with an extremely fast in situ microstructural characterization tool to identify the physical origin of rapid enthalpic signals. More specifically, we describe the development of a system to enable in situ nanocalorimetry experiments in the dynamic transmission electron microscope (DTEM), a time-resolved TEM capable of generating images and electron diffraction patterns with exposure times of 30 ns500 ns. The full experimental system consists of a modified nanocalorimeter sensor, a custom-built in situ nanocalorimetry holder, a data acquisition system, and the DTEM itself, and is capable of thermodynamic and microstructural characterization of reactions over a range of heating rates (10{sup 2} K/s10{sup 5} K/s) accessible by conventional (DC) nanocalorimetry. To establish its ability to capture synchronized calorimetric and microstructural data during rapid transformations, this work describes measurements on the melting of an aluminum thin film. We were able to identify the phase transformation in both the nanocalorimetry traces and in electron diffraction patterns taken by the DTEM. Potential applications for the newly developed system are described and future system improvements are discussed.

  8. Hot-stage transmission electron microscopy study of (Na, K)NbO{sub 3} based lead-free piezoceramics

    SciTech Connect (OSTI)

    Lu, Shengbo; Xu, Zhengkui; Kwok, K. W.; Chan, Helen L. W.

    2014-07-28

    Hierarchical nanodomains assembled into micron-sized stripe domains, which is believed to be associated with outstanding piezoelectric properties, were observed at room temperature in a typical lead free piezoceramics, (Na{sub 0.52}K{sub 0.48?x})(Nb{sub 0.95?x}Ta{sub 0.05})-xLiSbO{sub 3}, with finely tuned polymorphic phase boundaries (x?=?0.0465) by transmission electron microscopy. The evolution of domain morphology and crystal structure under heating and cooling cycles in the ceramic was investigated by in-situ hot stage study. It is found that the nanodomains are irreversibly transformed into micron-sized rectangular domains during heating and cooling cycles, which lead to the thermal instability of piezoelectric properties of the materials.

  9. Real-time observation of morphological transformations in II-VI semiconducting nanobelts via environmental transmission electron microscopy

    SciTech Connect (OSTI)

    Agarwal, Rahul; Zakharov, Dmitri N.; Krook, Nadia M.; Liu, Wenjing; Berger, Jacob; Stach, Eric A.; Agarwal, Ritesh

    2015-05-01

    It has been observed that wurtzite II–VI semiconducting nanobelts transform into single-crystal, periodically branched nanostructures upon heating. The mechanism of this novel transformation has been elucidated by heating II–VI nanobelts in an environmental transmission electron microscope (ETEM) in oxidizing, reducing and inert atmospheres while observing their structural changes with high spatial resolution. The interplay of surface reconstruction of high-energy surfaces of the wurtzite phase and environment-dependent anisotropic chemical etching of certain crystal surfaces in the branching mechanism of nanobelts has been observed. Understanding of structural and chemical transformations of materials via in situ microscopy techniques and their role in designing new nanostructured materials is discussed.

  10. Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Unocic, Raymond R; Sun, Xiao-Guang; Sacci, Robert L; Adamczyk, Leslie A; Alsem, Daan Hein; Dai, Sheng; Dudney, Nancy J; More, Karren Leslie

    2014-01-01

    Complex, electrochemically driven transport processes form the basis of electrochemical energy storage devices. The direct imaging of electrochemical processes at high spatial resolution and within their native liquid electrolyte would significantly enhance our understanding of device functionality, but has remained elusive. In this work we use a recently developed liquid cell for in situ electrochemical transmission electron microscopy to obtain insight into the electrolyte decomposition mechanisms and kinetics in lithium-ion (Li-ion) batteries by characterizing the dynamics of solid electrolyte interphase (SEI) formation and evolution. Here we are able to visualize the detailed structure of the SEI that forms locally at the electrode/electrolyte interface during lithium intercalation into natural graphite from an organic Li-ion battery electrolyte. We quantify the SEI growth kinetics and observe the dynamic self-healing nature of the SEI with changes in cell potential.

  11. High-resolution transmission electron microscopy study of carbon deposited on the NiO/MgO solid solution catalysts

    SciTech Connect (OSTI)

    Hu, Y.H.; Ruckenstein, E.

    1999-05-15

    The carbon deposition due to the CH{sub 4} decomposition at 790 C over NiO/MgO catalysts was investigated by high-resolution transmission electron microscopy. While no deposits could be detected over the catalysts with a NiO content smaller than 9.1 wt%, they were detected over the catalysts with NiO contents of 23 and 50 wt%. The carbon deposits are composed of platelets located at distances of about 0.34 nm, corresponding to the graphitic carbon. Various structures of the deposited carbon were observed: (a) carbon consisting of platelets parallel to the surface of the particle, which covers a catalyst particle, (b) nanotubes composed of platelets parallel to their axis, and (c) carbon vortexes consisting of platelets parallel to their axis.

  12. Real-time observation of morphological transformations in II-VI semiconducting nanobelts via environmental transmission electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Agarwal, Rahul; Zakharov, Dmitri N.; Krook, Nadia M.; Liu, Wenjing; Berger, Jacob; Stach, Eric A.; Agarwal, Ritesh

    2015-05-01

    It has been observed that wurtzite II–VI semiconducting nanobelts transform into single-crystal, periodically branched nanostructures upon heating. The mechanism of this novel transformation has been elucidated by heating II–VI nanobelts in an environmental transmission electron microscope (ETEM) in oxidizing, reducing and inert atmospheres while observing their structural changes with high spatial resolution. The interplay of surface reconstruction of high-energy surfaces of the wurtzite phase and environment-dependent anisotropic chemical etching of certain crystal surfaces in the branching mechanism of nanobelts has been observed. Understanding of structural and chemical transformations of materials via in situ microscopy techniques and their role in designingmore » new nanostructured materials is discussed.« less

  13. Optimal experimental design for the detection of light atoms from high-resolution scanning transmission electron microscopy images

    SciTech Connect (OSTI)

    Gonnissen, J.; De Backer, A.; Martinez, G. T.; Van Aert, S.; Dekker, A. J. den; Rosenauer, A.; Sijbers, J.

    2014-08-11

    We report an innovative method to explore the optimal experimental settings to detect light atoms from scanning transmission electron microscopy (STEM) images. Since light elements play a key role in many technologically important materials, such as lithium-battery devices or hydrogen storage applications, much effort has been made to optimize the STEM technique in order to detect light elements. Therefore, classical performance criteria, such as contrast or signal-to-noise ratio, are often discussed hereby aiming at improvements of the direct visual interpretability. However, when images are interpreted quantitatively, one needs an alternative criterion, which we derive based on statistical detection theory. Using realistic simulations of technologically important materials, we demonstrate the benefits of the proposed method and compare the results with existing approaches.

  14. In situ observation on hydrogenation of Mg-Ni films using environmental transmission electron microscope with aberration correction

    SciTech Connect (OSTI)

    Matsuda, Junko; Yoshida, Kenta; Sasaki, Yukichi; Uchiyama, Naoki; Akiba, Etsuo

    2014-08-25

    In situ transmission electron microscopy (TEM) was performed to observe the hydrogenation of Mg-Ni films in a hydrogen atmosphere of 80100?Pa. An aberration-corrected environmental TEM with a differential pumping system allows us to reveal the Angstrom-scale structure of the films in the initial stage of hydrogenation: first, nucleation and growth of Mg{sub 2}NiH{sub 4} crystals with a lattice spacing of 0.22?nm in an Mg-rich amorphous matrix of the film occurs within 20 s after the start of the high-resolution observation, then crystallization of MgH{sub 2} with a smaller spacing of 0.15?nm happens after approximately 1?min. Our in situ TEM method is also applicable to the analysis of other hydrogen-related materials.

  15. Kinetics of liquid-mediated crystallization of amorphous Ge from multi-frame dynamic transmission electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Santala, M. K.; Raoux, S.; Campbell, G. H.

    2015-12-24

    The kinetics of laser-induced, liquid-mediated crystallization of amorphous Ge thin films were studied using multi-frame dynamic transmission electron microscopy (DTEM), a nanosecond-scale photo-emission transmission electron microscopy technique. In these experiments, high temperature gradients are established in thin amorphous Ge films with a 12-ns laser pulse with a Gaussian spatial profile. The hottest region at the center of the laser spot crystallizes in ~100 ns and becomes nano-crystalline. Over the next several hundred nanoseconds crystallization continues radially outward from the nano-crystalline region forming elongated grains, some many microns long. The growth rate during the formation of these radial grains is measuredmore » with time-resolved imaging experiments. Crystal growth rates exceed 10 m/s, which are consistent with crystallization mediated by a very thin, undercooled transient liquid layer, rather than a purely solid-state transformation mechanism. The kinetics of this growth mode have been studied in detail under steady-state conditions, but here we provide a detailed study of liquid-mediated growth in high temperature gradients. Unexpectedly, the propagation rate of the crystallization front was observed to remain constant during this growth mode even when passing through large local temperature gradients, in stark contrast to other similar studies that suggested the growth rate changed dramatically. As a result, the high throughput of multi-frame DTEM provides gives a more complete picture of the role of temperature and temperature gradient on laser crystallization than previous DTEM experiments.« less

  16. Electronic-excitation energy transfer in heterogeneous dye solutions under laser excitation

    SciTech Connect (OSTI)

    Levshin, L.V.; Mukushev, B.T.; Saletskii, A.M.

    1995-10-01

    An experimental study has been made of electronic-excitation energy transfer (EEET) among dye molecules of different types for different exciting-fight wavelengths and temperatures. Upon selective laser excitation of the donor, the inhomogeneous broadening of molecular levels increases the probability of EEET from the donor to acceptor molecules. The efficiency of this process is directly proportional to the acceptor molecule concentration and is temperature dependent. The EEET is accompanied by the spectral migration of energy among donor molecules, which reduces the fluorescence quantum efficiency of the donor. Increasing the frequency of the exciting light decreases in the donor fluorescence quantum efficiency. An increase in the acceptor molecule concentration results in a decrease of the spectral migration of excitation in the donor molecule system. 5 refs., 5 figs.

  17. Charge Transfer Fluorescence and 34 nm Exciton Diffusion Length in Polymers with Electron Acceptor End Traps

    SciTech Connect (OSTI)

    Zaikowski, L.; Mauro, G.; Bird, M.; Karten, B.; Asaoka, S.; Wu, Q.; Cook, A. R.; Miller, J.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are as large as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. The efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.

  18. Charge transfer fluorescence and 34 nm exciton diffusion length in polymers with electron acceptor end traps

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zaikowski, Lori; Mauro, Gina; Bird, Matthew; Karten, Brianne; Asaoka, Sadayuki; Wu, Qin; Cook, Andrew R.; Miller, John R.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are asmore » large as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. As a result, the efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.« less

  19. Room temperature, hybrid sodium-based flow batteries with multi-electron transfer redox reactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volumemore » of the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. Furthermore, the critical barriers to mature this new HNFBs have also been explored.« less

  20. Room Temperature, Hybrid Sodium-Based Flow Batteries with Multi-Electron Transfer Redox Reactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volumemoreof the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. The critical barriers to mature this new HNFBs have also been explored.less

  1. Lithium electrodeposition dynamics in aprotic electrolyte observed in situ via transmission electron microscopy

    SciTech Connect (OSTI)

    Leenheer, Andrew Jay; Jungjohann, Katherine Leigh; Zavadil, Kevin Robert; Sullivan, John P.; Harris, Charles Thomas

    2015-03-18

    Electrodeposited metallic lithium is an ideal negative battery electrode, but nonuniform microstructure evolution during cycling leads to degradation and safety issues. A better understanding of the Li plating and stripping processes is needed to enable practical Li-metal batteries. Here we use a custom microfabricated, sealed liquid cell for in situ scanning transmission electron microscopy (STEM) to image the first few cycles of lithium electrodeposition/dissolution in liquid aprotic electrolyte at submicron resolution. Cycling at current densities from 1 to 25 mA/cm2 leads to variations in grain structure, with higher current densities giving a more needle-like, higher surface area deposit. The effect of the electron beam was explored, and it was found that, even with minimal beam exposure, beam-induced surface film formation could alter the Li microstructure. The electrochemical dissolution was seen to initiate from isolated points on grains rather than uniformly across the Li surface, due to the stabilizing solid electrolyte interphase surface film. As a result, we discuss the implications for operando STEM liquid-cell imaging and Li-battery applications.

  2. In-situ Study of Dynamic Phenomena at Metal Nanosolder Interfaces Using Aberration Corrected Scanning Transmission Electron Microcopy.

    SciTech Connect (OSTI)

    Lu, Ping

    2014-10-01

    Controlling metallic nanoparticle (NP) interactions plays a vital role in the development of new joining techniques (nanosolder) that bond at lower processing temperatures but remain viable at higher temperatures. The pr imary objective of this project is t o develop a fundamental understanding of the actual reaction processes, associated atomic mechanisms, and the resulting microstructure that occur during thermally - driven bond formation concerning metal - metal nano - scale (<50nm) interfaces. In this LDRD pr oject, we have studied metallic NPs interaction at the elevated temperatures by combining in - situ transmission electron microscopy (TEM ) using an aberration - corrected scanning transmission electron microscope (AC - STEM) and atomic - scale modeling such as m olecular dynamic (MD) simulations. Various metallic NPs such as Ag, Cu and Au are synthesized by chemical routines. Numerous in - situ e xperiments were carried out with focus of the research on study of Ag - Cu system. For the first time, using in - situ STEM he ating experiments , we directly observed t he formation of a 3 - dimensional (3 - D) epitaxial Cu - Ag core - shell nanoparticle during the thermal interaction of Cu and Ag NPs at elevated temperatures (150 - 300 o C). The reaction takes place at temperatures as low as 150 o C and was only observed when care was taken to circumvent the effects of electron beam irradiation during STEM imaging. Atomic - scale modeling verified that the Cu - Ag core - shell structure is energetically favored, and indicated that this phenomenon is a nano - scale effect related to the large surface - to - volume ratio of the NPs. The observation potentially can be used for developing new nanosolder technology that uses Ag shell as the %22glue%22 that stic ks the particles of Cu together. The LDRD has led to several journal publications and numerous conference presentations, and a TA. In addition, we have developed new TEM characterization techniques and phase - field modeling tools that can be used for future materials research at Sandia. Acknowledgeme nts This work was supported by the Laboratory Directed Research and Development (LDRD) program of Sandia National Laboratories. Sandia National Laboratories is a multi - program laboratory managed and operated by Sandia Corporation, a wholly owned subsidia ry of Lockheed Martin Corporation, for the US Department of Energy's National Nuclear Security Administration under contract DE - AC04 - 94AL85000.

  3. Directly correlated transmission electron microscopy and atom probe tomography of grain boundary oxidation in a Ni-Al binary alloy exposed to high-temperature water.

    SciTech Connect (OSTI)

    Schreiber, Daniel K.; Olszta, Matthew J.; Bruemmer, Stephen M.

    2013-10-30

    Intergranular oxidation of a Ni-4Al alloy exposed to hydrogenated, high-temperature water was characterized using directly correlated transmission electron microscopy and atom probe tomography. These combined analyses revealed that discrete, well-separated oxides (NiAl2O4) precipitated along grain boundaries in the metal. Aluminum was depleted from the grain boundary between oxides and also from one side of the boundary as a result of grain boundary migration. The discrete oxide morphology, disconnected from the continuous surface oxidation, suggests intergranular solid-state internal oxidation of Al. Keywords: oxidation; grain boundaries; nickel alloys; atom probe tomography; transmission electron microscopy (TEM)

  4. Excitonic splitting and coherent electronic energy transfer in the gas-phase benzoic acid dimer

    SciTech Connect (OSTI)

    Ottiger, Philipp; Leutwyler, Samuel

    2012-11-28

    The benzoic acid dimer, (BZA){sub 2}, is a paradigmatic symmetric hydrogen bonded dimer with two strong antiparallel hydrogen bonds. The excitonic S{sub 1}/S{sub 2} state splitting and coherent electronic energy transfer within supersonically cooled (BZA){sub 2} and its {sup 13}C-, d{sub 1}-, d{sub 2}-, and {sup 13}C/d{sub 1}- isotopomers have been investigated by mass-resolved two-color resonant two-photon ionization spectroscopy. The (BZA){sub 2}-(h-h) and (BZA){sub 2}-(d-d) dimers are C{sub 2h} symmetric, hence only the S{sub 2} Leftwards-Arrow S{sub 0} transition can be observed, the S{sub 1} Leftwards-Arrow S{sub 0} transition being strictly electric-dipole forbidden. A single {sup 12}C/{sup 13}C or H/D isotopic substitution reduces the symmetry of the dimer to C{sub s}, so that the isotopic heterodimers (BZA){sub 2}-{sup 13}C, (BZA){sub 2}-(h-d), (BZA){sub 2}-(h{sup 13}C-d), and (BZA){sub 2}-(h-d{sup 13}C) show both S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} bands. The S{sub 1}/S{sub 2} exciton splitting inferred is {Delta}{sub exc}= 0.94 {+-} 0.1 cm{sup -1}. This is the smallest splitting observed so far for any H-bonded gas-phase dimer. Additional isotope-dependent contributions to the splittings, {Delta}{sub iso}, arise from the change of the zero-point vibrational energy upon electronic excitation and range from {Delta}{sub iso}= 3.3 cm{sup -1} upon {sup 12}C/{sup 13}C substitution to 14.8 cm{sup -1} for carboxy H/D substitution. The degree of excitonic localization/delocalization can be sensitively measured via the relative intensities of the S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} origin bands; near-complete localization is observed even for a single {sup 12}C/{sup 13}C substitution. The S{sub 1}/ S{sub 2} energy gap of (BZA){sub 2} is {Delta}{sub calc}{sup exc}=11 cm{sup -1} when calculated by the approximate second-order perturbation theory (CC2) method. Upon correction for vibronic quenching, this decreases to {Delta}{sub vibron}{sup exc}=2.1 cm{sup -1} [P. Ottiger et al., J. Chem. Phys. 136, 174308 (2012)], in good agreement with the observed {Delta}{sub exc}= 0.94 cm{sup -1}. The observed excitonic splittings can be converted to exciton hopping times {tau}{sub exc}. For the (BZA){sub 2}-(h-h) homodimer {tau}{sub exc}= 18 ps, which is nearly 40 times shorter than the double proton transfer time of (BZA){sub 2} in its excited state [Kalkman et al., ChemPhysChem 9, 1788 (2008)]. Thus, the electronic energy transfer is much faster than the proton-transfer in (BZA){sub 2}{sup *}.

  5. Redox linked flavin sites in extracellular decaheme proteins involved in microbe-mineral electron transfer.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Edwards, Marcus J.; White, Gaye F.; Norman, Michael; Tome-Fernandez, Alice; Ainsworth, Emma; Shi, Liang; Fredrickson, Jim K.; Zachara, John M.; Butt, Julea N.; Richardson, David J.; et al

    2015-07-01

    Extracellular microbe-mineral electron transfer is a major driving force for the oxidation of organic carbon in many subsurface environments. Extracellular multi-heme cytochromes of the Shewenella genus play a major role in this process but the mechanism of electron exchange at the interface between cytochrome and acceptor is widely debated. The 1.8 Å x-ray crystal structure of the decaheme MtrC revealed a highly conserved CX₈C disulfide that, when substituted for AX₈A, severely compromised the ability of S. oneidensis to grow under aerobic conditions. Reductive cleavage of the disulfide in the presence of flavin mononucleotide (FMN) resulted in the reversible formation ofmore » a stable flavocytochrome. Similar results were also observed with other decaheme cytochromes, OmcA, MtrF and UndA. The data suggest that these decaheme cytochromes can transition between highly reactive flavocytochromes or less reactive cytochromes, and that this transition is controlled by a redox active disulfide that responds to the presence of oxygen.« less

  6. Redox linked flavin sites in extracellular decaheme proteins involved in microbe-mineral electron transfer.

    SciTech Connect (OSTI)

    Edwards, Marcus J.; White, Gaye F.; Norman, Michael; Tome-Fernandez, Alice; Ainsworth, Emma; Shi, Liang; Fredrickson, Jim K.; Zachara, John M.; Butt, Julea N.; Richardson, David J.; Clarke, Thomas A.

    2015-07-01

    Extracellular microbe-mineral electron transfer is a major driving force for the oxidation of organic carbon in many subsurface environments. Extracellular multi-heme cytochromes of the Shewenella genus play a major role in this process but the mechanism of electron exchange at the interface between cytochrome and acceptor is widely debated. The 1.8 Å x-ray crystal structure of the decaheme MtrC revealed a highly conserved CX₈C disulfide that, when substituted for AX₈A, severely compromised the ability of S. oneidensis to grow under aerobic conditions. Reductive cleavage of the disulfide in the presence of flavin mononucleotide (FMN) resulted in the reversible formation of a stable flavocytochrome. Similar results were also observed with other decaheme cytochromes, OmcA, MtrF and UndA. The data suggest that these decaheme cytochromes can transition between highly reactive flavocytochromes or less reactive cytochromes, and that this transition is controlled by a redox active disulfide that responds to the presence of oxygen.

  7. Interaction potentials of anisotropic nanocrystals from the trajectory sampling of particle motion using in situ liquid phase transmission electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Qian; Cho, Hoduk; Manthiram, Karthish; Yoshida, Mark; Ye, Xingchen; Alivisatos, A. Paul

    2015-03-23

    We demonstrate a generalizable strategy to use the relative trajectories of pairs and groups of nanocrystals, and potentially other nanoscale objects, moving in solution which can now be obtained by in situ liquid phase transmission electron microscopy (TEM) to determine the interaction potentials between nanocrystals. Such nanoscale interactions are crucial for collective behaviors and applications of synthetic nanocrystals and natural biomolecules, but have been very challenging to measure in situ at nanometer or sub-nanometer resolution. Here we use liquid phase TEM to extract the mathematical form of interaction potential between nanocrystals from their sampled trajectories. We show the power ofmore » this approach to reveal unanticipated features of nanocrystal–nanocrystal interactions by examining the anisotropic interaction potential between charged rod-shaped Au nanocrystals (Au nanorods); these Au nanorods assemble, in a tip-to-tip fashion in the liquid phase, in contrast to the well-known side-by-side arrangements commonly observed for drying-mediated assembly. These observations can be explained by a long-range and highly anisotropic electrostatic repulsion that leads to the tip-selective attachment. As a result, Au nanorods stay unassembled at a lower ionic strength, as the electrostatic repulsion is even longer-ranged. Our study not only provides a mechanistic understanding of the process by which metallic nanocrystals assemble but also demonstrates a method that can potentially quantify and elucidate a broad range of nanoscale interactions relevant to nanotechnology and biophysics.« less

  8. Transmission Electron Microscope In Situ Straining Technique to Directly Observe Defects and Interfaces During Deformation in Magnesium

    SciTech Connect (OSTI)

    Morrow, Benjamin M.; Cerreta, E. K.; McCabe, R. J.; Tom, C. N.

    2015-05-14

    In-situ straining was used to study deformation behavior of hexagonal close-packed (hcp) metals.Twinning and dislocation motion, both essential to plasticity in hcp materials, were observed.Typically, these processes are characterized post-mortem by examining remnant microstructural features after straining has occurred. By imposing deformation during imaging, direct observation of active deformation mechanisms is possible. This work focuses on straining of structural metals in a transmission electron microscope (TEM), and a recently developed technique that utilizes familiar procedures and equipment to increase ease of experiments. In-situ straining in a TEM presents several advantages over conventional post-mortem characterization, most notably time-resolution of deformation and streamlined identification of active deformation mechanisms. Drawbacks to the technique and applicability to other studies are also addressed. In-situ straining is used to study twin boundary motion in hcp magnesium. A {1012} twin was observed during tensile and compressive loading. Twin-dislocation interactions are directly observed. Notably, dislocations are observed to remain mobile, even after multiple interactions with twin boundaries, a result which suggests that Basinkis dislocation transformation mechanism by twinning is not present in hcp metals. The coupling of in-situ straining with traditional post-mortem characterization yields more detailed information about material behavior during deformation than either technique alone.

  9. Imaging individual lanthanum atoms in zeolite Y by scanning transmission electron microscopy: evidence of lanthanum pair sites

    SciTech Connect (OSTI)

    Xu, Pinghong; Lu, Jing; Aydin, C.; Debefve, Louise M.; Browning, Nigel D.; Chen, Cong-Yan; Gates, Bruce C.

    2015-09-01

    Images of La-exchanged NaY zeolite obtained with aberration-corrected scanning transmission electron microscopy (STEM) show that about 80% of the La cations were present as site-isolated species, with the remainder in pair sites. The distance between La cations in the pair sites ranged from 1.44 to 3.84 , consistent with the presence of pairs of cations tilted at various angles with respect to the support surface. The actual distance between La cations in the pair sites is inferred to be approximately 3.84 , which is shorter than the distance between the nearest Al sites in the zeolite (4.31 ). The results therefore suggest the presence of dimeric structures of La cations bridged with OH groups, and the presence of such species has been inferred previously on the basis of X-ray photoelectron spectroscopy (W. Grnert, U. Sauerlandt, R. Schlgl, H.G. Karge, J. Phys. Chem., 97 (1993) 1413).

  10. Transmission Electron Microscope In Situ Straining Technique to Directly Observe Defects and Interfaces During Deformation in Magnesium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Morrow, Benjamin M.; Cerreta, E. K.; McCabe, R. J.; Tomé, C. N.

    2015-05-14

    In-situ straining was used to study deformation behavior of hexagonal close-packed (hcp) metals.Twinning and dislocation motion, both essential to plasticity in hcp materials, were observed.Typically, these processes are characterized post-mortem by examining remnant microstructural features after straining has occurred. By imposing deformation during imaging, direct observation of active deformation mechanisms is possible. This work focuses on straining of structural metals in a transmission electron microscope (TEM), and a recently developed technique that utilizes familiar procedures and equipment to increase ease of experiments. In-situ straining in a TEM presents several advantages over conventional post-mortem characterization, most notably time-resolution of deformation andmore » streamlined identification of active deformation mechanisms. Drawbacks to the technique and applicability to other studies are also addressed. In-situ straining is used to study twin boundary motion in hcp magnesium. A {101¯2} twin was observed during tensile and compressive loading. Twin-dislocation interactions are directly observed. Notably, dislocations are observed to remain mobile, even after multiple interactions with twin boundaries, a result which suggests that Basinki’s dislocation transformation mechanism by twinning is not present in hcp metals. The coupling of in-situ straining with traditional post-mortem characterization yields more detailed information about material behavior during deformation than either technique alone.« less

  11. Atomic-resolution study of polarity reversal in GaSb grown on Si by scanning transmission electron microscopy

    SciTech Connect (OSTI)

    Hosseini Vajargah, S.; Woo, S. Y.; Botton, G. A.; Ghanad-Tavakoli, S.; Kleiman, R. N.; Preston, J. S.

    2012-11-01

    The atomic-resolved reversal of the polarity across an antiphase boundary (APB) was observed in GaSb films grown on Si by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM). The investigation of the interface structure at the origin of the APB reveals that coalescence of two domains with Ga-prelayer and Sb-prelayer causes the sublattice reversal. The local strain and lattice rotation distributions of the APB, attributed to the discordant bonding length at the APB with the surrounding GaSb lattice, were further studied using the geometric phase analysis technique. The crystallographic characteristics of the APBs and their interaction with other planar defects were observed with HAADF-STEM. The quantitative agreement between experimental and simulated images confirms the observed polarities in the acquired HAADF-STEM data. The self-annihilation mechanism of the APBs is addressed based on the rotation induced by anti-site bonds and APBs' faceting.

  12. Real time nanoscale structural evaluation of gold structures on Si (100) surface using in-situ transmission electron microscopy

    SciTech Connect (OSTI)

    Rath, A. E-mail: ashutosh.phy@gmail.com E-mail: pvsatyam22@gmail.com; Juluri, R. R.; Satyam, P. V. E-mail: ashutosh.phy@gmail.com E-mail: pvsatyam22@gmail.com

    2014-05-14

    Transport behavior of gold nanostructures on Si(100) substrate during annealing under high vacuum has been investigated using in-situ real time transmission electron microscopy (TEM). A comparative study has been done on the morphological changes due to annealing under different vacuum environments. Au thin films of thickness ?2.0?nm were deposited on native oxide covered silicon substrate by using thermal evaporation system. In-situ real time TEM measurements at 850?C showed the isotropic growth of rectangular/square shaped gold-silicon alloy structures. During the growth, it is observed that the alloying occurs in liquid phase followed by transformation into the rectangular shapes. For similar system, ex-situ annealing in low vacuum (10{sup ?2} millibars) at 850?C showed the spherical gold nanostructures with no Au-Si alloy formation. Under low vacuum annealing conditions, the rate of formation of the oxide layer dominates the oxide desorption rate, resulting in the creation of a barrier layer between Au and Si, which restricts the inter diffusion of Au in to Si. This work demonstrates the important role of interfacial oxide layer on the growth of nanoscale Au-Si alloy structures during the initial growth. The time dependent TEM images are presented to offer a direct insight into the fundamental dynamics of the sintering process at the nanoscale.

  13. Transparent Conductors from Carbon Nanotubes LBL-Assembled with Polymer Dopant with ?-? Electron Transfer

    SciTech Connect (OSTI)

    Zhu, Jian; Shim, Bong Sup; Di Prima, Matthew; Kotov, Nicholas A.

    2011-01-01

    Single-walled carbon nanotube (SWNT) and other carbon-based coatings are being considered as replacements for indium tin oxide (ITO). The problems of transparent conductors (TCs) coatings from SWNT and similar materials include poor mechanical properties, high roughness, low temperature resilience, and fast loss of conductivity. The simultaneous realization of these desirable characteristics can be achieved using high structural control of layer-by-layer (LBL) deposition, which is demonstrated by the assembly of hydroethyl cellulose (HOCS) and sulfonated polyetheretherketone (SPEEK)-SWNTs. A new type of SWNT doping based on electron transfer from valence bands of nanotubes to unoccupied levels of SPEEK through ?-? interactions was identified for this system. It leads to a conductivity of 1.1 10? S/m at 66 wt % loadings of SWNT. This is better than other polymer/SWNT composites and translates into surface conductivity of 920 ?/? and transmittance of 86.7% at 550 nm. The prepared LBL films also revealed unusually high temperature resilience up to 500 C, and low roughness of 3.5 nm (ITO glass -2.4 nm). Tensile modulus, ultimate strength, and toughness of such coatings are 13 2 GPa, 366 35 MPa, and 8 3 kJ/m, respectively, and exceed corresponding parameters of all similar TCs. The cumulative figure of merit, ?TC, which included the critical failure strain relevant for flexible electronics, was ?TC = 0.022 and should be compared to ?TC = 0.006 for commercial ITO. Further optimization is possible using stratified nanoscale coatings and improved doping from the macromolecular LBL components.

  14. Visualizing the non-equilibrium dynamics of photoinduced intramolecular electron transfer with femtosecond X-ray pulses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Canton, Sophie E.; Kjær, Kasper S.; Vankó, György; van Driel, Tim B.; Adachi, Shin -ichi; Bordage, Amélie; Bressler, Christian; Chabera, Pavel; Christensen, Morten; Dohn, Asmus O.; et al

    2015-03-02

    Ultrafast photoinduced electron transfer preceding energy equilibration still poses many experimental and conceptual challenges to the optimization of photoconversion since an atomic-scale description has so far been beyond reach. Here we combine femtosecond transient optical absorption spectroscopy with ultrafast X-ray emission spectroscopy and diffuse X-ray scattering at the SACLA facility to track the non-equilibrated electronic and structural dynamics within a bimetallic donor–acceptor complex that contains an optically dark centre. Exploiting the 100-fold increase in temporal resolution as compared with storage ring facilities, these measurements constitute the first X-ray-based visualization of a non-equilibrated intramolecular electron transfer process over large interatomic distances.more » Thus experimental and theoretical results establish that mediation through electronically excited molecular states is a key mechanistic feature. The present study demonstrates the extensive potential of femtosecond X-ray techniques as diagnostics of non-adiabatic electron transfer processes in synthetic and biological systems, and some directions for future studies, are outlined.« less

  15. Visualizing the non-equilibrium dynamics of photoinduced intramolecular electron transfer with femtosecond X-ray pulses

    SciTech Connect (OSTI)

    Canton, Sophie E.; Kjr, Kasper S.; Vank, Gyrgy; van Driel, Tim B.; Adachi, Shin -ichi; Bordage, Amlie; Bressler, Christian; Chabera, Pavel; Christensen, Morten; Dohn, Asmus O.; Galler, Andreas; Gawelda, Wojciech; Gosztola, David; Haldrup, Kristoffer; Harlang, Tobias; Liu, Yizhu; Mller, Klaus B.; Nmeth, Zoltn; Nozawa, Shunsuke; Ppai, Mtys; Sato, Tokushi; Sato, Takahiro; Suarez-Alcantara, Karina; Togashi, Tadashi; Tono, Kensuke; Uhlig, Jens; Vithanage, Dimali A.; Wrnmark, Kenneth; Yabashi, Makina; Zhang, Jianxin; Sundstrm, Villy; Nielsen, Martin M.

    2015-03-02

    Ultrafast photoinduced electron transfer preceding energy equilibration still poses many experimental and conceptual challenges to the optimization of photoconversion since an atomic-scale description has so far been beyond reach. Here we combine femtosecond transient optical absorption spectroscopy with ultrafast X-ray emission spectroscopy and diffuse X-ray scattering at the SACLA facility to track the non-equilibrated electronic and structural dynamics within a bimetallic donoracceptor complex that contains an optically dark centre. Exploiting the 100-fold increase in temporal resolution as compared with storage ring facilities, these measurements constitute the first X-ray-based visualization of a non-equilibrated intramolecular electron transfer process over large interatomic distances. Thus experimental and theoretical results establish that mediation through electronically excited molecular states is a key mechanistic feature. The present study demonstrates the extensive potential of femtosecond X-ray techniques as diagnostics of non-adiabatic electron transfer processes in synthetic and biological systems, and some directions for future studies, are outlined.

  16. Dynamics of electron solvation in methanol: Excited state relaxation and generation by charge-transfer-to-solvent

    SciTech Connect (OSTI)

    Elkins, Madeline H.; Williams, Holly L.; Neumark, Daniel M.

    2015-06-21

    The charge-transfer-to-solvent dynamics (CTTS) and excited state relaxation mechanism of the solvated electron in methanol are studied by time-resolved photoelectron spectroscopy on a liquid methanol microjet by means of two-pulse and three-pulse experiments. In the two-pulse experiment, CTTS excitation is followed by a probe photoejection pulse. The resulting time-evolving photoelectron spectrum reveals multiple time scales characteristic of relaxation and geminate recombination of the initially generated electron which are consistent with prior results from transient absorption. In the three-pulse experiment, the relaxation dynamics of the solvated electron following electronic excitation are measured. The internal conversion lifetime of the excited electron is found to be 130 40 fs, in agreement with extrapolated results from clusters and the non-adiabatic relaxation mechanism.

  17. Rational engineering of Geobacter sulfurreducens electron transfer components: A foundation for building improved Geobacter-based bioelectrochemical technologies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dantas, Joana M.; Morgado, Leonor; Aklujkar, Muktak; Bruix, Marta; Londer, Yuri Y.; Schiffer, Marianne; Pokkuluri, P. Raj; Salgueiro, Carlos A.

    2015-07-30

    Multiheme cytochromes have been implicated in Geobacter sulfurreducens extracellular electron transfer (EET). These proteins are potential targets to improve EET and enhance bioremediation and electrical current production by G. sulfurreducens. However, the functional characterization of multiheme cytochromes is particularly complex due to the co-existence of several microstates in solution, connecting the fully reduced and fully oxidized states. Throughout the last decade, new strategies have been developed to characterize multiheme redox proteins functionally and structurally. These strategies were used to reveal the functional mechanism of G. sulfurreducens multiheme cytochromes and also to identify key residues in these proteins for EET. Inmore » previous studies, we set the foundations for enhancement of the EET abilities of G. sulfurreducens by characterizing a family of five triheme cytochromes (PpcA-E). These periplasmic cytochromes are implicated in electron transfer between the oxidative reactions of metabolism in the cytoplasm and the reduction of extracellular terminal electron acceptors at the cell's outer surface. The results obtained suggested that PpcA can couple e-/H+ transfer, a property that might contribute to the proton electrochemical gradient across the cytoplasmic membrane for metabolic energy production. The structural and functional properties of PpcA were characterized in detail and used for rational design of a family of 23 single site PpcA mutants. In this review, we summarize the functional characterization of the native and mutant proteins. Mutants that retain the mechanistic features of PpcA and adopt preferential e-/H+ transfer pathways at lower reduction potential values compared to the wild-type protein were selected for in vivo studies as the best candidates to increase the electron transfer rate of G. sulfurreducens. For the first time G. sulfurreducens strains have been manipulated by the introduction of mutant forms of essential proteins with the aim to develop and improve bioelectrochemical technologies.« less

  18. Rapid Laser Induced Crystallization of Amorphous NiTi Films Observed by Nanosecond Dynamic Transmission Electron Microscopy (DTEM)

    SciTech Connect (OSTI)

    LaGrange, T; Campbell, G H; Browning, N D; Reed, B W; Grummon, D S

    2010-03-01

    The crystallization processes of the as-deposited, amorphous NiTi thin films have been studied in detail using techniques such as differential scanning calorimetry and, in-situ TEM. The kinetic data have been analyzed in terms of Johnson-Mehl-Avrami-Kolomogrov (JMAK) semi-empirical formula. The kinetic parameters determined from this analysis have been useful in defining process control parameters for tailoring microstructural features and shape memory properties. Due to the commercial push to shrink thin film-based devices, unique processing techniques have been developed using laser-based annealing to spatially control the microstructure evolution down to sub-micron levels. Nanosecond, pulse laser annealing is particularly attractive since it limits the amount of peripheral heating and unwanted microstructural changes to underlying or surrounding material. However, crystallization under pulsed laser irradiation can differ significantly from conventional thermal annealing, e.g., slow heating in a furnace. This is especially true for amorphous NiTi materials and relevant for shape memory thin film based microelectromechanical systems (MEMS) applications. There is little to no data on the crystallization kinetics of NiTi under pulsed laser irradiation, primarily due to the high crystallization rates intrinsic to high temperature annealing and the spatial and temporal resolution limits of standard techniques. However, with the high time and spatial resolution capabilities of the dynamic transmission electron microscope (DTEM) constructed at Lawrence Livermore National Laboratory, the rapid nucleation events occurring from pulsed laser irradiation can be directly observed and nucleation rates can be quantified. This paper briefly explains the DTEM approach and how it used to investigate the pulsed laser induced crystallization processes in NiTi and to determine kinetic parameters.

  19. Sulfur oxidation to sulfate coupled with electron transfer to electrodes by Desulfuromonas strain TZ1

    SciTech Connect (OSTI)

    Zhang, T; Bain, TS; Barlett, MA; Dar, SA; Snoeyenbos-West, OL; Nevin, KP; Lovley, DR

    2014-01-02

    Microbial oxidation of elemental sulfur with an electrode serving as the electron acceptor is of interest because this may play an important role in the recovery of electrons from sulfidic wastes and for current production in marine benthic microbial fuel cells. Enrichments initiated with a marine sediment inoculum, with elemental sulfur as the electron donor and a positively poised (+300 mV versus Ag/AgCl) anode as the electron acceptor, yielded an anode biofilm with a diversity of micro-organisms, including Thiobacillus, Sulfurimonas, Pseudomonas, Clostridium and Desulfuromonas species. Further enrichment of the anode biofilm inoculum in medium with elemental sulfur as the electron donor and Fe(III) oxide as the electron acceptor, followed by isolation in solidified sulfur/Fe(III) medium yielded a strain of Desulfuromonas, designated strain TZ1. Strain TZ1 effectively oxidized elemental sulfur to sulfate with an anode serving as the sole electron acceptor, at rates faster than Desulfobulbus propionicus, the only other organism in pure culture previously shown to oxidize S with current production. The abundance of Desulfuromonas species enriched on the anodes of marine benthic fuel cells has previously been interpreted as acetate oxidation driving current production, but the results presented here suggest that sulfur-driven current production is a likely alternative.

  20. GHz laser-free time-resolved transmission electron microscopy: A stroboscopic high-duty-cycle method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qiu, Jiaqi; Zhu, Yimei; Ha, Gwanghui; Jing, Chunguang; Baryshev, Sergey V.; Reed, Bryan W.; Lau, June W.

    2015-11-10

    In this study, a device and a method for producing ultrashort electron pulses with GHz repetition rates via pulsing an input direct current (dc) electron beam are provided. The device and the method are based on an electromagnetic-mechanical pulser (EMMP) that consists of a series of transverse deflecting cavities and magnetic quadrupoles. The EMMP modulates and chops the incoming dc electron beam and converts it into pico- and sub-pico-second electron pulse sequences (pulse trains) at >1 GHz repetition rates, as well as controllably manipulates the resulting pulses. Ultimately, it leads to negligible electron pulse phase-space degradation compared to the incomingmore » dc beam parameters. The temporal pulse length and repetition rate for the EMMP can be continuously tunable over wide ranges.« less

  1. GHz laser-free time-resolved transmission electron microscopy: A stroboscopic high-duty-cycle method

    SciTech Connect (OSTI)

    Qiu, Jiaqi; Zhu, Yimei; Ha, Gwanghui; Jing, Chunguang; Baryshev, Sergey V.; Reed, Bryan W.; Lau, June W.

    2015-11-10

    In this study, a device and a method for producing ultrashort electron pulses with GHz repetition rates via pulsing an input direct current (dc) electron beam are provided. The device and the method are based on an electromagnetic-mechanical pulser (EMMP) that consists of a series of transverse deflecting cavities and magnetic quadrupoles. The EMMP modulates and chops the incoming dc electron beam and converts it into pico- and sub-pico-second electron pulse sequences (pulse trains) at >1 GHz repetition rates, as well as controllably manipulates the resulting pulses. Ultimately, it leads to negligible electron pulse phase-space degradation compared to the incoming dc beam parameters. The temporal pulse length and repetition rate for the EMMP can be continuously tunable over wide ranges.

  2. Communication: Microsecond dynamics of the protein and water affect electron transfer in a bacterial bc{sub 1} complex

    SciTech Connect (OSTI)

    Martin, Daniel R.; Matyushov, Dmitry V.

    2015-04-28

    Cross-membrane electron transport between cofactors localized in proteins of mitochondrial respiration and bacterial photosynthesis is the source of all biological energy. The statistics and dynamics of nuclear fluctuations in these protein/membrane/water heterogeneous systems are critical for their energetic efficiency. The results of 13 ?s of atomistic molecular dynamics simulations of the membrane-bound bc{sub 1} bacterial complex are analyzed here. The reaction is affected by a broad spectrum of nuclear modes, with the slowest dynamics in the range of time-scales ?0.1-1.6 ?s contributing half of the reaction reorganization energy. Two reorganization energies are required to describe protein electron transfer due to dynamical arrest of protein conformations on the observation window. This mechanistic distinction allows significant lowering of activation barriers for reactions in proteins.

  3. Blinking suppression of CdTe quantum dots on epitaxial graphene and the analysis with Marcus electron transfer

    SciTech Connect (OSTI)

    Hirose, Takuya; Tamai, Naoto, E-mail: tamai@kwansei.ac.jp [Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337 (Japan); Kutsuma, Yasunori; Kurita, Atsusi; Kaneko, Tadaaki [Department of Physics, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337 (Japan)

    2014-08-25

    We have prepared epitaxial graphene by a Si sublimation method from 4H-SiC. Single-particle spectroscopy of CdTe quantum dots (QDs) on epitaxial graphene covered with polyvinylpyrrolidone (PVP) or polyethylene glycol (PEG) showed the suppression of luminescence blinking and ?10 times decreased luminescence intensity as compared with those on a glass. The electronic coupling constant, H{sub 01}, between CdTe QDs and graphene was calculated to be (3.3??0.4)??10{sup 2?}cm{sup ?1} in PVP and (3.7??0.8)??10{sup 2?}cm{sup ?1} in PEG based on Marcus theory of electron transfer and Tang-Marcus model of blinking with statistical distribution.

  4. Nano-scale luminescence characterization of individual InGaN/GaN quantum wells stacked in a microcavity using scanning transmission electron microscope cathodoluminescence

    SciTech Connect (OSTI)

    Schmidt, Gordon Mller, Marcus; Veit, Peter; Bertram, Frank; Christen, Jrgen; Glauser, Marlene; Carlin, Jean-Franois; Cosendey, Gatien; Butt, Raphal; Grandjean, Nicolas

    2014-07-21

    Using cathodoluminescence spectroscopy directly performed in a scanning transmission electron microscope at liquid helium temperatures, the optical and structural properties of a 62 InGaN/GaN multiple quantum well embedded in an AlInN/GaN based microcavity are investigated at the nanometer scale. We are able to spatially resolve a spectral redshift between the individual quantum wells towards the surface. Cathodoluminescence spectral linescans allow directly visualizing the critical layer thickness in the quantum well stack resulting in the onset of plastic relaxation of the strained InGaN/GaN system.

  5. High resolution low dose transmission electron microscopy real-time imaging and manipulation of nano-scale objects in the electron beam

    DOE Patents [OSTI]

    Brown, Jr., R. Malcolm (Austin, TX); Barnes, Zack (Austin, TX); Sawatari, Chie (Shizuoka, JP); Kondo, Tetsuo (Kukuoka, JP)

    2008-02-26

    The present invention includes a method, apparatus and system for nanofabrication in which one or more target molecules are identified for manipulation with an electron beam and the one or more target molecules are manipulated with the electron beam to produce new useful materials.

  6. Electron transfer activation of a second water channel for proton transport in [FeFe]-hydrogenase

    SciTech Connect (OSTI)

    Sode, Olaseni; Voth, Gregory A.

    2014-12-14

    Hydrogenase enzymes are important because they can reversibly catalyze the production of molecular hydrogen. Proton transport mechanisms have been previously studied in residue pathways that lead to the active site of the enzyme via residues Cys299 and Ser319. The importance of this pathway and these residues has been previously exhibited through site-specific mutations, which were shown to interrupt the enzyme activity. It has been shown recently that a separate water channel (WC2) is coupled with electron transport to the active site of the [FeFe]-hydrogenase. The water-mediated proton transport mechanisms of the enzyme in different electronic states have been studied using the multistate empirical valence bond reactive molecular dynamics method, in order to understand any role WC2 may have in facilitating the residue pathway in bringing an additional proton to the enzyme active site. In a single electronic state A{sup 2?}, a water wire was formed through which protons can be transported with a low free energy barrier. The remaining electronic states were shown, however, to be highly unfavorable to proton transport in WC2. A double amino acid substitution is predicted to obstruct proton transport in electronic state A{sup 2-} by closing a cavity that could otherwise fill with water near the proximal Fe of the active site.

  7. Role of Quinones in Electron Transfer of PQQ–Glucose Dehydrogenase Anodes—Mediation or Orientation Effect

    SciTech Connect (OSTI)

    Babanova, Sofia; Matanovic, Ivana; Chavez, Madelaine Seow; Atanassov, Plamen

    2015-06-24

    In this study, the influence of two quinones (1,2- and 1,4-benzoquinone) on the operation and mechanism of electron transfer in PQQ-dependent glucose dehydrogenase (PQQ–sGDH) anodes has been determined. Benzoquinones were experimentally explored as mediators present in the electrolyte. The electrochemical performance of the PQQ–sGDH anodes with and without the mediators was examined and for the first time molecular docking simulations were used to gain a fundamental understanding to explain the role of the mediator molecules in the design and operation of the enzymatic electrodes. It was proposed that the higher performance of the PQQ–sGDH anodes in the presence of 1,2- and 1,4-benzoquinones introduced in the solution is due to the shorter distance between these molecules and PQQ in the enzymatic molecule. It was also hypothesized that when 1,4-benzoquinone is adsorbed on a carbon support, it would play the dual role of a mediator and an orienting agent. At the same time, when 1,2-benzoquinone and ubiquinone are adsorbed on the electrode surface, the enzyme would transfer the electrons directly to the support, and these molecules would primarily play the role of an orienting agent.

  8. Role of quinones in electron transfer of PQQ–glucose dehydrogenase anodes—mediation or orientation effect

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Babanova, Sofia; Matanovic, Ivana; Chavez, Madelaine Seow; Atanassov, Plamen

    2015-06-16

    In this study, the influence of two quinones (1,2- and 1,4-benzoquinone) on the operation and mechanism of electron transfer in PQQ-sGDH anodes has been determined. Benzoquinones were experimentally explored as mediators present in the electrolyte. The electrochemical performance of the PQQ–sGDH anodes with and without the mediators was examined and for the first time molecular docking simulations were used to gain a fundamental understanding to explain the role of the mediator molecules in the design and operation of the enzymatic electrodes. It was proposed that the higher performance of the PQQ–sGDH anodes in the presence of 1,2- and 1,4-benzoquinones introducedmore » in the solution is due to the shorter distance between these molecules and PQQ in the enzymatic molecule. It was also hypothesized that when 1,4-benzoquinone is adsorbed on a carbon support, it would play the dual role of a mediator and an orienting agent. At the same time, when 1,2-benzoquinone and ubiquinone are adsorbed on the electrode surface, the enzyme would transfer the electrons directly to the support, and these molecules would primarily play the role of an orienting agent.« less

  9. Role of quinones in electron transfer of PQQglucose dehydrogenase anodesmediation or orientation effect

    SciTech Connect (OSTI)

    Babanova, Sofia; Matanovic, Ivana; Chavez, Madelaine Seow; Atanassov, Plamen

    2015-06-16

    In this study, the influence of two quinones (1,2- and 1,4-benzoquinone) on the operation and mechanism of electron transfer in PQQ-sGDH anodes has been determined. Benzoquinones were experimentally explored as mediators present in the electrolyte. The electrochemical performance of the PQQsGDH anodes with and without the mediators was examined and for the first time molecular docking simulations were used to gain a fundamental understanding to explain the role of the mediator molecules in the design and operation of the enzymatic electrodes. It was proposed that the higher performance of the PQQsGDH anodes in the presence of 1,2- and 1,4-benzoquinones introduced in the solution is due to the shorter distance between these molecules and PQQ in the enzymatic molecule. It was also hypothesized that when 1,4-benzoquinone is adsorbed on a carbon support, it would play the dual role of a mediator and an orienting agent. At the same time, when 1,2-benzoquinone and ubiquinone are adsorbed on the electrode surface, the enzyme would transfer the electrons directly to the support, and these molecules would primarily play the role of an orienting agent.

  10. Power Electronics for Distributed Energy Systems and Transmission and Distribution Applications: Assessing the Technical Needs for Utility Applications

    SciTech Connect (OSTI)

    Tolbert, L.M.

    2005-12-21

    Power electronics can provide utilities the ability to more effectively deliver power to their customers while providing increased reliability to the bulk power system. In general, power electronics is the process of using semiconductor switching devices to control and convert electrical power flow from one form to another to meet a specific need. These conversion techniques have revolutionized modern life by streamlining manufacturing processes, increasing product efficiencies, and increasing the quality of life by enhancing many modern conveniences such as computers, and they can help to improve the delivery of reliable power from utilities. This report summarizes the technical challenges associated with utilizing power electronics devices across the entire spectrum from applications to manufacturing and materials development, and it provides recommendations for research and development (R&D) needs for power electronics systems in which the U.S. Department of Energy (DOE) could make a substantial impact toward improving the reliability of the bulk power system.

  11. Nanowires, Capacitors, and Other Novel Outer-Surface Components Involved in Electron Transfer to Fe(III) Oxides in Geobacter Species

    SciTech Connect (OSTI)

    Lovley, Derek, R.

    2008-12-22

    The overall goal of this project was to better understand the mechanisms by which Geobacter species transfer electrons outside the cell onto Fe(III) oxides. The rationale for this study was that Geobacter species are often the predominant microorganisms involved in in situ uranium bioremediation and the growth and activity of the Geobacter species during bioremediation is primarily supported by electron transfer to Fe(III) oxides. These studies greatly expanded the understanding of electron transfer to Fe(III). Novel concepts developed included the potential role of microbial nanowires for long range electron transfer in Geobacter species and the importance of extracytoplasmic cytochromes functioning as capacitors to permit continued electron transfer during the hunt for Fe(III) oxide. Furthermore, these studies provided target sequences that were then used in other studies to tract the activity of Geobacter species in the subsurface through monitoring the abundance of gene transcripts of the target genes. A brief summary of the major accomplishments of the project is provided.

  12. Ensemble density functional theory method correctly describes bond dissociation, excited state electron transfer, and double excitations

    SciTech Connect (OSTI)

    Filatov, Michael; Huix-Rotllant, Miquel; Burghardt, Irene

    2015-05-14

    State-averaged (SA) variants of the spin-restricted ensemble-referenced Kohn-Sham (REKS) method, SA-REKS and state-interaction (SI)-SA-REKS, implement ensemble density functional theory for variationally obtaining excitation energies of molecular systems. In this work, the currently existing version of the SA-REKS method, which included only one excited state into the ensemble averaging, is extended by adding more excited states to the averaged energy functional. A general strategy for extension of the REKS-type methods to larger ensembles of ground and excited states is outlined and implemented in extended versions of the SA-REKS and SI-SA-REKS methods. The newly developed methods are tested in the calculation of several excited states of ground-state multi-reference systems, such as dissociating hydrogen molecule, and excited states of donor–acceptor molecular systems. For hydrogen molecule, the new method correctly reproduces the distance dependence of the lowest excited state energies and describes an avoided crossing between the doubly excited and singly excited states. For bithiophene–perylenediimide stacked complex, the SI-SA-REKS method correctly describes crossing between the locally excited state and the charge transfer excited state and yields vertical excitation energies in good agreement with the ab initio wavefunction methods.

  13. More stable hybrid organic solar cells deposited on amorphous Si electron transfer layer

    SciTech Connect (OSTI)

    Samiee, Mehran; Modtland, Brian; Dalal, Vikram L.; Aidarkhanov, Damir

    2014-05-26

    We report on defect densities, performance, and stability of organic/inorganic hybrid solar cells produced using n-doped inorganic amorphous silicon-carbide layers as the electron transport layer (ETL). The organic material was poly-3-hexyl-thiophene (P3HT) and heterojunction was formed using phenyl-C{sub 71}-Butyric-Acid-Methyl Ester (PCBM). For comparison, inverted solar cells fabricated using Cs{sub 2}CO{sub 3} as ETL were fabricated. Defect densities and subgap quantum efficiency curves were found to be nearly identical for both types of cells. The cells were subjected to 2xsun illumination and it was found that the cells produced using doped a-Si as ETL were much more stable than the cells produced using Cs{sub 2}CO{sub 3}.

  14. Atomic arrangement at ZnTe/CdSe interfaces determined by high resolution scanning transmission electron microscopy and atom probe tomography

    SciTech Connect (OSTI)

    Bonef, Bastien; Rouvire, Jean-Luc; Jouneau, Pierre-Henri; Bellet-Amalric, Edith; Grard, Lionel; Mariette, Henri; Andr, Rgis; Bougerol, Catherine; Grenier, Adeline

    2015-02-02

    High resolution scanning transmission electron microscopy and atom probe tomography experiments reveal the presence of an intermediate layer at the interface between two binary compounds with no common atom, namely, ZnTe and CdSe for samples grown by Molecular Beam Epitaxy under standard conditions. This thin transition layer, of the order of 1 to 3 atomic planes, contains typically one monolayer of ZnSe. Even if it occurs at each interface, the direct interface, i.e., ZnTe on CdSe, is sharper than the reverse one, where the ZnSe layer is likely surrounded by alloyed layers. On the other hand, a CdTe-like interface was never observed. This interface knowledge is crucial to properly design superlattices for optoelectronic applications and to master band-gap engineering.

  15. A transmission electron microscopy study of the deformation behavior underneath nanoindents in nano-scale Al-TiN multilayered composites

    SciTech Connect (OSTI)

    Bhattacharyya, Dhriti; Mara, Nathan A; Dickerson, Patricia O; Misra, Amit; Hoagland, R G

    2009-01-01

    Nano-scale multilayered Al-TiN composites were deposited with DC magnetron sputtering technique in two different layer thickness ratios - Al:TiN = 1:1 and Al:TiN = 9:1. The Al layer thickness varied from 2 nm to 450 nm. The hardness of the samples was tested by nanoindentation using a Berkovich tip. Cross-sectional Transmission Electron Microscopy (TEM) was carried out on samples extracted with Focused Ion Beam (FIB) from below the nanoindents. This paper presents the results of the hardness tests in the Al-TiN multilayers with the two different thickness ratios and the observations from the cross-sectional TEM studies of the regions underneath the indents. These studies showed remarkable strength in the multilayers, as well as some very interesting deformation behavior in the TiN layers at extremely small length scales, where the hard TiN layers undergo co-deformation with the Al layers.

  16. Transition Metal Donor-Peptide-Acceptor Complexes: From Intramolecular Electron Transfer Reactions to the Study of Reactive Intermediates

    SciTech Connect (OSTI)

    Isied, Stephan S.

    2003-03-11

    The trans-polyproline (PII) oligomers (Figure 1) are unusually rigid peptide structures which have been extensively studied by our group for peptide mediated intramolecular electron transfer (ET) at long distances. We have previously studied ET across a series of metal ion donor (D) acceptor (A) oligoproline peptides with different distances, driving forces and reorganizational energies. The majority of these experiments involve generating the ET intermediate using pulse radiolysis methods, although more recently photochemical methods are also used. Results of these studies showed that ET across peptides can vary by more than twelve orders of magnitude. Using ruthenium bipyridine donors, ET reaction rate constants across several proline residues (n = 4 - 9) occurred in the millisecond (ms) to {micro}s timescale, thus limiting the proline peptide conformational motions to only minor changes (far smaller than the large changes that occur on the ms to sec timescale, such as trans to cis proline isomerization). The present report describes our large data base of experimental results for D-peptide-A complexes in terms of a model where the involvement of both superexchange and hopping (hole and electron) mechanisms account for the long range ET rate constants observed. Our data shows that the change from superexchange to hopping mechanisms occurs at different distances depending on the type of D and A and their interactions with the peptides. Our model is also consistent with generalized models for superexchange and hopping which have been put forward by a number of theoretical groups to account for long range ET phenomena.

  17. EXTRACTION OF FRACTURE-MECHANICS AND TRANSMISSION-ELECTRON-MICROSCOPY SAMPLES FROM TRITIUM-EXPOSED RESERVOIRS USING ELECTRIC-DISCHARGE MACHINING

    SciTech Connect (OSTI)

    Morgan, M; Ken Imrich, K; Michael Tosten, M

    2006-08-31

    The Enhanced Surveillance Campaign is funding a program to investigate tritium aging effects on the structural properties of tritium reservoir steels. The program is designed to investigate how the structural properties of reservoir steels change during tritium service and to examine the role of microstructure and reservoir manufacturing on tritium compatibility. New surveillance tests are also being developed that can better gauge the long-term effects of tritium and its radioactive decay product, helium-3, on the properties of reservoir steels. In order to conduct these investigations, three types of samples are needed from returned reservoirs: tensile, fracture mechanics, and transmission-electron microscopy (TEM). An earlier report demonstrated how the electric-discharge machining (EDM) technique can be used for cutting tensile samples from serial sections of a 3T reservoir and how yield strength, ultimate strength and elongation could be measured from those samples. In this report, EDM was used successfully to section sub-sized fracture-mechanics samples from the inner and outer walls of a 3T reservoir and TEM samples from serial sections of a 1M reservoir. This report fulfills the requirements for the FY06 Level 3 milestone, TSR 15.1 ''Cut Fracture-Mechanics Samples from Tritium-Exposed Reservoir'' and TSR 15.2 ''Cut Transmission-electron-microscopy foils from Tritium-Exposed Reservoir'' for the Enhance Surveillance Campaign (ESC). This was in support of ESC L2-1870 Milestone-''Provide aging and lifetime assessments of selected components and materials for multiple enduring stockpile systems''.

  18. Electronic Coupling Dependence of Ultrafast Interfacial Electron...

    Office of Scientific and Technical Information (OSTI)

    Electron Transfer on Nanocrystalline Thin Films and Single Crystal Lian, Tianquan 14 SOLAR ENERGY The long-term goal of the proposed research is to understand electron transfer...

  19. A method for measuring the local gas pressure within a gas-flow stage in situ in the transmission electron microscope

    SciTech Connect (OSTI)

    Colby, Robert J.; Alsem, Daan H.; Liyu, Andrey V.; Kabius, Bernd C.

    2015-06-01

    The development of environmental transmission electron microscopy (TEM) has enabled in situ experiments in a gaseous environment with high resolution imaging and spectroscopy. Addressing scientific challenges in areas such as catalysis, corrosion, and geochemistry can require pressures much higher than the ~20 mbar achievable with a differentially pumped, dedicated environmental TEM. Gas flow stages, in which the environment is contained between two semi-transparent thin membrane windows, have been demonstrated at pressures of several atmospheres. While this constitutes significant progress towards operando measurements, the design of many current gas flow stages is such that the pressure at the sample cannot necessarily be directly inferred from the pressure differential across the system. Small differences in the setup and design of the gas flow stage can lead to very different sample pressures. We demonstrate a method for measuring the gas pressure directly, using a combination of electron energy loss spectroscopy and TEM imaging. This method requires only two energy filtered TEM images, limiting the measurement time to a few seconds and can be performed during an ongoing experiment at the region of interest. This approach provides a means to ensure reproducibility between different experiments, and even between very differently designed gas flow stages.

  20. Transmission Workshop

    Broader source: Energy.gov [DOE]

    On November 1-2, 2012, the GTT presented a workshop on grid integration on the transmission system at the DoubleTree Crystal City near Washington, DC.

  1. Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes

    SciTech Connect (OSTI)

    Gu, Meng; Parent, Lucas R.; Mehdi, Beata L.; Unocic, Raymond R.; Mcdowell, Matthew T.; Sacci, Robert L.; Xu, Wu; Connell, Justin G.; Xu, Pinghong; Abellan Baeza, Patricia; Chen, Xilin; Zhang, Yaohui; Perea, Daniel E.; Evans, James E.; Lauhon, Lincoln; Zhang, Jiguang; Liu, Jun; Browning, Nigel D.; Cui, Yi; Arslan, Ilke; Wang, Chong M.

    2013-12-11

    Over the last few years, in-situ transmission electron microscopy (TEM) studies of lithium ion batteries using an open-cell configuration have helped us to gain fundamental insights into the structural and chemical evolution of the electrode materials in real time. In the standard open-cell configuration, the electrolyte is either solid lithium oxide or an ionic liquid, which is point-contacted with the electrode. This cell design is inherently different from a real battery, where liquid electrolyte forms conformal contact with electrode materials. The knowledge learnt from open cells can deviate significantly from the real battery, calling for operando TEM technique with conformal liquid electrolyte contact. In this paper, we developed an operando TEM electrochemical liquid cell to meet this need, providing the configuration of a real battery and in a relevant liquid electrolyte. To demonstrate this novel technique, we studied the lithiation/delithiation behavior of single Si nanowires. Some of lithiation/delithation behaviors of Si obtained using the liquid-cell are consistent with the results from the open-cell studies. However, we also discovered new insights different from the open cell configuration - the dynamics of the electrolyte and, potentially, a future quantitative characterization of the SEI layer formation and structural and chemical evolution.

  2. Evaluation of stacking faults and associated partial dislocations in AlSb/GaAs (001) interface by aberration-corrected high-resolution transmission electron microscopy

    SciTech Connect (OSTI)

    Wen, C.; Ge, B. H.; Cui, Y. X.; Li, F. H.; Zhu, J.; Yu, R.; Cheng, Z. Y.

    2014-11-15

    The stacking faults (SFs) in an AlSb/GaAs (001) interface were investigated using a 300 kV spherical aberration-corrected high-resolution transmission electron microscope (HRTEM). The structure and strain distribution of the single and intersecting (V-shaped) SFs associated with partial dislocations (PDs) were characterized by the [110] HRTEM images and geometric phase analysis, respectively. In the biaxial strain maps ?{sub xx} and ?{sub yy}, a SF can be divided into several sections under different strain states (positive or negative strain values). Furthermore, the strain state for the same section of a SF is in contrast to each other in ?{sub xx} and ?{sub yy} strain maps. The modification in the strain states was attributed to the variation in the local atomic displacements for the SF in the AlSb film on the GaAs substrate recorded in the lattice image. Finally, the single SF was found to be bounded by two 30 PDs. A pair of 30 PDs near the heteroepitaxial interface reacted to form a Lomer-Cottrell sessile dislocation located at the vertices of V-shaped SFs with opposite screw components. The roles of misfit dislocations, such as the PDs, in strain relaxation were also discussed.

  3. In-situ high resolution transmission electron microscopy observation of silicon nanocrystal nucleation in a SiO{sub 2} bilayered matrix

    SciTech Connect (OSTI)

    Yang, T. C.-J. Wu, L.; Lin, Z.; Jia, X.; Puthen-Veettil, B.; Zhang, T.; Conibeer, G.; Perez-Wurfl, I.; Kauffmann, Y.; Rothschild, A.

    2014-08-04

    Solid-state nucleation of Si nanocrystals in a SiO{sub 2} bilayered matrix was observed at temperatures as low as 450?C. This was achieved by aberration corrected high-resolution transmission electron microscopy (HRTEM) with real-time in-situ heating up to 600?C. This technique is a valuable characterization tool especially with the recent interest in Si nanostructures for light emitting devices, non-volatile memories, and third-generation photovoltaics which all typically require a heating step in their fabrication. The control of size, shape, and distribution of the Si nanocrystals are critical for these applications. This experimental study involves in-situ observation of the nucleation of Si nanocrystals in a SiO{sub 2} bilayered matrix fabricated through radio frequency co-sputtering. The results show that the shapes of Si nanocrystals in amorphous SiO{sub 2} bilayered matrices are irregular and not spherical, in contrast to many claims in the literature. Furthermore, the Si nanocrystals are well confined within their layers by the amorphous SiO{sub 2}. This study demonstrates the potential of in-situ HRTEM as a tool to observe the real time nucleation of Si nanocrystals in a SiO{sub 2} bilayered matrix. Furthermore, ideas for improvements on this in-situ heating HRTEM technique are discussed.

  4. Accompanying coordinate expansion and recurrence relation method using a transfer relation scheme for electron repulsion integrals with high angular momenta and long contractions

    SciTech Connect (OSTI)

    Hayami, Masao; Seino, Junji; Nakai, Hiromi

    2015-05-28

    An efficient algorithm for the rapid evaluation of electron repulsion integrals is proposed. The present method, denoted by accompanying coordinate expansion and transferred recurrence relation (ACE-TRR), is constructed using a transfer relation scheme based on the accompanying coordinate expansion and recurrence relation method. Furthermore, the ACE-TRR algorithm is extended for the general-contraction basis sets. Numerical assessments clarify the efficiency of the ACE-TRR method for the systems including heavy elements, whose orbitals have long contractions and high angular momenta, such as f- and g-orbitals.

  5. Catching the role of anisotropic electronic distribution and charge transfer in halogen bonded complexes of noble gases

    SciTech Connect (OSTI)

    Bartocci, Alessio; Cappelletti, David; Pirani, Fernando; Belpassi, Leonardo; Falcinelli, Stefano; Grandinetti, Felice; Tarantelli, Francesco

    2015-05-14

    The systems studied in this work are gas-phase weakly bound adducts of the noble-gas (Ng) atoms with CCl{sub 4} and CF{sub 4}. Their investigation was motivated by the widespread current interest for the intermolecular halogen bonding (XB), a structural motif recognized to play a role in fields ranging from elementary processes to biochemistry. The simulation of the static and dynamic behaviors of complex systems featuring XB requires the formulation of reliable and accurate model potentials, whose development relies on the detailed characterization of strength and nature of the interactions occurring in simple exemplary halogenated systems. We thus selected the prototypical Ng-CCl{sub 4} and Ng-CF{sub 4} and performed high-resolution molecular beam scattering experiments to measure the absolute scale of their intermolecular potentials, with high sensitivity. In general, we expected to probe typical van der Waals interactions, consisting of a combination of size (exchange) repulsion with dispersion/induction attraction. For the He/Ne-CF{sub 4}, the analysis of the glory quantum interference pattern, observable in the velocity dependence of the integral cross section, confirmed indeed this expectation. On the other hand, for the He/Ne/Ar-CCl{sub 4}, the scattering data unravelled much deeper potential wells, particularly for certain configurations of the interacting partners. The experimental data can be properly reproduced only including a shifting of the repulsive wall at shorter distances, accompanied by an increased role of the dispersion attraction, and an additional short-range stabilization component. To put these findings on a firmer ground, we performed, for selected geometries of the interacting complexes, accurate theoretical calculations aimed to evaluate the intermolecular interaction and the effects of the complex formation on the electron charge density of the constituting moieties. It was thus ascertained that the adjustments of the potential suggested by the analysis of the experiments actually reflect two chemically meaningful contributions, namely, a stabilizing interaction arising from the anisotropy of the charge distribution around the Cl atom in CCl{sub 4} and a stereospecific electron transfer that occurs at the intermolecular distances mainly probed by the experiments. Our model calculations suggest that the largest effect is for the vertex geometry of CCl{sub 4} while other geometries appear to play a minor to negligible role.

  6. Transmission decisions

    SciTech Connect (OSTI)

    Ellison, C.T. )

    1993-03-01

    As the US FERC moves forward to implement the transmission access provisions of the National Energy Policy Act of 1992, the debate over Regional Transmission Groups continues. Independent energy producers have much at stake in this debate and their reaction to the general RTG concept and to specific RTG proposals will weigh heavily in determining the fate of these proposals.

  7. On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. V. Comparison and Properties of Electrochemical and Chemical Rate Constants

    DOE R&D Accomplishments [OSTI]

    Marcus, R. A.

    1962-01-01

    Using a theory of electron transfers which takes cognizance of reorganization of the medium outside the inner coordination shell and of changes of bond lengths inside it, relations between electrochemical and related chemical rate constants are deduced and compared with the experimental data. A correlation is found, without the use of arbitrary parameters. Effects of weak complexes with added electrolytes are included under specified conditions. The deductions offer a way of coordinating a variety of data in the two fields, internally as well as with each those in another. For example, the rate of oxidation or reduction of a series of related reactants by one reagent is correlated with that of another and with that of the corresponding electrochemical oxidation-reduction reaction, under certain specified conditions. These correlations may also provide a test for distinguishing an electron from an atom transfer mechanism. (auth)

  8. PC Electronic Data Reporting Option (PEDRO) System

    Gasoline and Diesel Fuel Update (EIA)

    System Released: February 22, 2011 Download Pedro Application Patch Archive Background The PC Electronic Data Reporting Option, or PEDRO, system enables users to enter Energy Information Administration (EIA) survey form data on a personal computer (PC) using interactive data entry screens and validate the accuracy of the data through an electronic data editing process. A communication program included as part of the system transfers the data to EIA and verifies the accuracy of the transmission.

  9. Direct imaging of crystal structure and defects in metastable Ge{sub 2}Sb{sub 2}Te{sub 5} by quantitative aberration-corrected scanning transmission electron microscopy

    SciTech Connect (OSTI)

    Ross, Ulrich; Lotnyk, Andriy Thelander, Erik; Rauschenbach, Bernd

    2014-03-24

    Knowledge about the atomic structure and vacancy distribution in phase change materials is of foremost importance in order to understand the underlying mechanism of fast reversible phase transformation. In this Letter, by combining state-of-the-art aberration-corrected scanning transmission electron microscopy with image simulations, we are able to map the local atomic structure and composition of a textured metastable Ge{sub 2}Sb{sub 2}Te{sub 5} thin film deposited by pulsed laser deposition with excellent spatial resolution. The atomic-resolution scanning transmission electron microscopy investigations display the heterogeneous defect structure of the Ge{sub 2}Sb{sub 2}Te{sub 5} phase. The obtained results are discussed. Highly oriented Ge{sub 2}Sb{sub 2}Te{sub 5} thin films appear to be a promising approach for further atomic-resolution investigations of the phase change behavior of this material class.

  10. Rational engineering of Geobacter sulfurreducens electron transfer components: A foundation for building improved Geobacter-based bioelectrochemical technologies

    SciTech Connect (OSTI)

    Dantas, Joana M.; Morgado, Leonor; Aklujkar, Muktak; Bruix, Marta; Londer, Yuri Y.; Schiffer, Marianne; Pokkuluri, P. Raj; Salgueiro, Carlos A.

    2015-07-30

    Multiheme cytochromes have been implicated in Geobacter sulfurreducens extracellular electron transfer (EET). These proteins are potential targets to improve EET and enhance bioremediation and electrical current production by G. sulfurreducens. However, the functional characterization of multiheme cytochromes is particularly complex due to the co-existence of several microstates in solution, connecting the fully reduced and fully oxidized states. Throughout the last decade, new strategies have been developed to characterize multiheme redox proteins functionally and structurally. These strategies were used to reveal the functional mechanism of G. sulfurreducens multiheme cytochromes and also to identify key residues in these proteins for EET. In previous studies, we set the foundations for enhancement of the EET abilities of G. sulfurreducens by characterizing a family of five triheme cytochromes (PpcA-E). These periplasmic cytochromes are implicated in electron transfer between the oxidative reactions of metabolism in the cytoplasm and the reduction of extracellular terminal electron acceptors at the cell's outer surface. The results obtained suggested that PpcA can couple e-/H+ transfer, a property that might contribute to the proton electrochemical gradient across the cytoplasmic membrane for metabolic energy production. The structural and functional properties of PpcA were characterized in detail and used for rational design of a family of 23 single site PpcA mutants. In this review, we summarize the functional characterization of the native and mutant proteins. Mutants that retain the mechanistic features of PpcA and adopt preferential e-/H+ transfer pathways at lower reduction potential values compared to the wild-type protein were selected for in vivo studies as the best candidates to increase the electron transfer rate of G. sulfurreducens. For the first time G. sulfurreducens strains have been manipulated by the introduction of mutant forms of essential proteins with the aim to develop and improve bioelectrochemical technologies.

  11. Evolution of titania nanotubes-supported WO{sub x} species by in situ thermo-Raman spectroscopy, X-ray diffraction and high resolution transmission electron microscopy

    SciTech Connect (OSTI)

    Cortes-Jacome, M.A.; Angeles-Chavez, C.; Morales, M.; Lopez-Salinas, E.; Toledo-Antonio, J.A.

    2007-10-15

    Structural evolution of WO{sub x} species on the surface of titania nanotubes was followed by in situ thermo-Raman spectroscopy. A total of 15 wt% of W atoms were loaded on the surface of a hydroxylated titania nanotubes by impregnation with ammonium metatungstate solution and then, the sample was thermally treated in a Linkam cell at different temperatures in nitrogen flow. The band characteristic of the W=O bond was observed at 962 cm{sup -1} in the dried sample, which vanished between 300 and 700 deg. C, and reappear again after annealing at 800 deg. C, along with a broad band centered at 935 cm{sup -1}, attributed to the v{sub 1} vibration of W=O in tetrahedral coordination. At 900 and 1000 deg. C, the broad band decomposed into four bands at 923, 934, 940 and 950 cm{sup -1}, corresponding to the symmetric and asymmetric vibration of W=O bonds in Na{sub 2}WO{sub 4} and Na{sub 2}W{sub 2}O{sub 7} phases as determined by X-ray diffraction and High resolution transmission electron microscopy (HRTEM). The structure of the nanotubular support was kept at temperatures below 450 deg. C, thereafter, it transformed into anatase being stabilized at temperatures as high as 900 deg. C. At 1000 deg. C, anatase phase partially converted into rutile. After annealing at 1000 deg. C, a core-shell model material was obtained, with a shell of ca. 5 nm thickness, composed of sodium tungstate nanoclusters, and a core composed mainly of rutile TiO{sub 2} phase. - Graphical abstract: Titania nanotubes loaded with 15 wt% W atoms were characterized from room temperature (rt) to 1000 deg. C by thermo-Raman spectroscopy in N{sub 2}. At 1000 deg. C, a core-shell model material was obtained, with a shell thickness of ca. 5 nm composed by nanoclusters of sodium tungstate, and a core composed mainly of rutile TiO{sub 2} phase.

  12. Photo-induced water oxidation at the aqueous GaN (1010) interface: Deprotonation kinetics of the first proton-coupled electron-transfer step

    SciTech Connect (OSTI)

    Ertem, Mehmed Z.; Kharche, Neerav; Batista, Victor S.; Hybertsen, Mark S.; Tully, John C.; Muckerman, James T.

    2015-03-12

    Photoeclectrochemical water splitting plays a key role in a promising path to the carbon-neutral generation of solar fuels. Wurzite GaN and its alloys (e.g., GaN/ZnO and InGaN) are demonstrated photocatalysts for water oxidation, and they can drive the overall water splitting reaction when coupled with co-catalysts for proton reduction. In the present work, we investigate the water oxidation mechanism on the prototypical GaN (1010) surface using a combined ab initio molecular dynamics and molecular cluster model approach taking into account the role of water dissociation and hydrogen bonding within the first solvation shell of the hydroxylated surface. The investigation of free-energy changes for the four proton-coupled electron-transfer (PCET) steps of the water oxidation mechanism shows that the first PCET step for the conversion of Ga-OH to Ga-O?? requires the highest energy input. We further examine the sequential PCETs, with the proton transfer (PT) following the electron transfer (ET), and find that photo-generated holes localize on surface NH sites is thermodynamically more favorable than OH sites. However, proton transfer from OH sites with subsequent localization of holes on oxygen atoms is kinetically favored owing to hydrogen bonding interactions at the GaN (1010)water interface. We find that the deprotonation of surface OH sites is the limiting factor for the generation of reactive oxyl radical ion intermediates and consequently for water oxidation.

  13. Photo-induced water oxidation at the aqueous GaN (101¯0) interface: Deprotonation kinetics of the first proton-coupled electron-transfer step

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ertem, Mehmed Z.; Kharche, Neerav; Batista, Victor S.; Hybertsen, Mark S.; Tully, John C.; Muckerman, James T.

    2015-03-12

    Photoeclectrochemical water splitting plays a key role in a promising path to the carbon-neutral generation of solar fuels. Wurzite GaN and its alloys (e.g., GaN/ZnO and InGaN) are demonstrated photocatalysts for water oxidation, and they can drive the overall water splitting reaction when coupled with co-catalysts for proton reduction. In the present work, we investigate the water oxidation mechanism on the prototypical GaN (101¯0) surface using a combined ab initio molecular dynamics and molecular cluster model approach taking into account the role of water dissociation and hydrogen bonding within the first solvation shell of the hydroxylated surface. The investigation ofmore » free-energy changes for the four proton-coupled electron-transfer (PCET) steps of the water oxidation mechanism shows that the first PCET step for the conversion of –Ga-OH to –Ga-O˙⁻ requires the highest energy input. We further examine the sequential PCETs, with the proton transfer (PT) following the electron transfer (ET), and find that photo-generated holes localize on surface –NH sites is thermodynamically more favorable than –OH sites. However, proton transfer from –OH sites with subsequent localization of holes on oxygen atoms is kinetically favored owing to hydrogen bonding interactions at the GaN (101¯0)–water interface. We find that the deprotonation of surface –OH sites is the limiting factor for the generation of reactive oxyl radical ion intermediates and consequently for water oxidation.« less

  14. Transmission Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transmission Services BPA Clarifications on the DSO216 1 Document updated on 2242015 at 3:29:25 PM B O N N E V I L L E P O W E R A D M I N I S T R A T I O N BPA Clarifications on...

  15. Transmission | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmission Transmission Below are resources for Tribes on transmission. Transmission 101 Presentation from the National Council on Electricity Policy's Transmissions Technologies workshop. Includes information on transmission technology, costs, and how to plan the system. Transmission on Tribal Land Basics The Tribal Energy and Environmental Information Clearinghouse provides resources for development on tribal lands. Topics covered include transmission technology basics, potential impacts,

  16. Electron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    density measurement by differential interferometry W. X. Ding, D. L. Brower, B. H. Deng, and T. Yates Electrical Engineering Department, University of California-Los Angeles, Los Angeles, California 90095 ͑Received 5 May 2006; presented on 10 May 2006; accepted 16 June 2006; published online 26 September 2006͒ A novel differential interferometer is being developed to measure the electron density gradient and its fluctuations. Two separate laser beams with slight spatial offset and frequency

  17. Theoretical analysis of the sequential proton-coupled electron transfer mechanisms for H2 oxidation and production pathways catalyzed by nickel molecular electrocatalysts

    SciTech Connect (OSTI)

    Fernandez, Laura; Horvath, Samantha; Hammes-Schiffer, Sharon

    2012-02-02

    The design of electrocatalysts for the oxidation and production of H2 is important for the development of alternative energy sources. This paper focuses on the electrocatalysts, where denotes 1,5-diaza-3,7-diphosphacyclooctane ligands with substituent groups R and R' covalently bound to the phosphorus and nitrogen atoms, respectively. Theoretical methods are used to investigate the mechanism of the step in the catalytic cycle corresponding to e ? for H2 oxidation and the reverse reaction for H2 production. This step involves electron transfer (ET) between the Ni complex and the electrode as well as proton transfer (PT) between the Ni and the N. The sequential mechanisms, PTET and ETPT, are investigated for the following (R,R) substituents: (Me,Me), (Ph,Ph), and (Ph,Bz), where Me, Ph, and Bz denote methyl, phenyl, and benzyl substituents. Density functional theory is used to calculate reduction potentials, pKas, and PT pathways, and Marcus theory is used to describe the electrochemical electron transfer, including the effects of solute and solvent reorganization energies. For the (Ph,Ph) and (Ph,Bz) systems, the sequential PTET mechanism would require surmounting a large free energy barrier for the initial PT step, followed by thermodynamically favorable or thermoneutral ET. The sequential ETPT mechanism for these systems would require a relatively large initial applied overpotential, followed by a PT reaction with a relatively low free energy barrier. Consistent with experimental data, the calculated overpotential required for the initial reduction in the ETPT mechanism is lower for the (Ph,Bz) system than for the (Ph,Ph) system. The concerted mechanism, in which the electron and proton transfer simultaneously without a stable intermediate, may be thermodynamically favorable and is a direction of future research. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences under FWP56073.

  18. Photoreactivity of ZnO nanoparticles in visible light: Effect of surface states on electron transfer reaction

    SciTech Connect (OSTI)

    Baruah, Sunandan; Dutta, Joydeep; Sinha, Sudarson Sekhar; Ghosh, Barnali; Pal, Samir Kumar; Raychaudhuri, A. K.

    2009-04-01

    Wide band gap metal oxide semiconductors such as zinc oxide (ZnO) show visible band photolysis that has been employed, among others, to degrade harmful organic contaminants into harmless mineral acids. Metal oxides show enhanced photocatalytic activity with the increase in electronic defects in the crystallites. By introducing defects into the crystal lattice of ZnO nanoparticles, we observe a redshift in the optical absorption shifting from the ultraviolet region to the visible region (400-700 nm), which is due to the creation of intermediate defect states that inhibit the electron hole recombination process. The defects were introduced by fast nucleation and growth of the nanoparticles by rapid heating using microwave irradiation and subsequent quenching during the precipitation reaction. To elucidate the nature of the photodegradation process, picosecond resolved time correlated single photon count (TCSPC) spectroscopy was carried out to record the electronic transitions resulting from the de-excitation of the electrons to their stable states. Photodegradation and TCSPC studies showed that defect engineered ZnO nanoparticles obtained through fast crystallization during growth lead to a faster initial degradation rate of methylene blue as compared to the conventionally synthesized nanoparticles.

  19. Electron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron thermal transport within magnetic islands in the reversed-field pinch a... H. D. Stephens, 1,b͒ D. J. Den Hartog, 1,3 C. C. Hegna, 1,2 and J. A. Reusch 1 1 Department of Physics, University of Wisconsin-Madison, 1150 University Ave., Madison, Wisconsin 53706, USA 2 Department of Engineering Physics, University of Wisconsin-Madison, 1500 Engineering Drive, Madison, Wisconsin 53706, USA 3 Center for Magnetic Self-Organization in Laboratory and Astrophysical Plasmas, University of

  20. Transmission Business Line

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transmission Business Line Non-Federal Financing of Transmission Projects - March 2004 Critical paths on the Northwest transmission grid are congested and the system is near or at...

  1. Photoinduced electron transfer double fragmentation. An oxygen-mediated radical chain process in the cofragmentation of aminopinacol donors with organic halides

    SciTech Connect (OSTI)

    Chen, L.; Farahat, M.S.; Gan, H.; Whitten, D.G.; Farid, S. |

    1995-06-14

    We reprot an investigation in which excited states of amino pinacols 1-3 are reacted with the halides CCl{sub 4}, benzyl bromide, and p-cyanobenzyl bromide. Interesting results from this study include the finding that low-to-moderate quantum efficiencies for reaction are observed when the reactions are carried out under degassed conditions, indicating that the halide radical anions must survive long enough within the initial ion pair formed in the quenching step to undergo considerable return electron transfer. More strikingly we find that for certain pinacol-halide combinations reaction in aerared solutions leads to much higher efficiencies, which can be attributed to a chain reaction involving oxygen capture of a primary radical product. 25 refs., 1 fig., 1 tab.

  2. DOE Transmission Workshop

    Broader source: Energy.gov (indexed) [DOE]

    Order No. 1000 Transmission Ratemaking Enabling New Resources - Demand Response - Variable Generation - Storage 2 Stages of Transmission Planning - Local, ...

  3. Optical characterization of free electron concentration in heteroepitaxial InN layers using Fourier transform infrared spectroscopy and a 2 Multiplication-Sign 2 transfer-matrix algebra

    SciTech Connect (OSTI)

    Katsidis, C. C.; Ajagunna, A. O.; Georgakilas, A.

    2013-02-21

    Fourier Transform Infrared (FTIR) reflectance spectroscopy has been implemented as a non-destructive, non-invasive, tool for the optical characterization of a set of c-plane InN single heteroepitaxial layers spanning a wide range of thicknesses (30-2000 nm). The c-plane (0001) InN epilayers were grown by plasma-assisted molecular beam epitaxy (PAMBE) on GaN(0001) buffer layers which had been grown on Al{sub 2}O{sub 3}(0001) substrates. It is shown that for arbitrary multilayers with homogeneous anisotropic layers having their principal axes coincident with the laboratory coordinates, a 2 Multiplication-Sign 2 matrix algebra based on a general transfer-matrix method (GTMM) is adequate to interpret their optical response. Analysis of optical reflectance in the far and mid infrared spectral range has been found capable to discriminate between the bulk, the surface and interface contributions of free carriers in the InN epilayers revealing the existence of electron accumulation layers with carrier concentrations in mid 10{sup 19} cm{sup -3} at both the InN surface and the InN/GaN interface. The spectra could be fitted with a three-layer model, determining the different electron concentration and mobility values of the bulk and of the surface and the interface electron accumulation layers in the InN films. The variation of these values with increasing InN thickness could be also sensitively detected by the optical measurements. The comparison between the optically determined drift mobility and the Hall mobility of the thickest sample reveals a value of r{sub H} = 1.49 for the Hall factor of InN at a carrier concentration of 1.11 Multiplication-Sign 10{sup 19} cm{sup -3} at 300 Degree-Sign {Kappa}.

  4. Final Report Navajo Transmission Project (NTP)

    SciTech Connect (OSTI)

    Bennie Hoisington; Steven Begay

    2006-09-14

    The Din Power Authority is developing the Navajo Transmission Project (NTP) to relieve the constraints on the transmission of electricity west of the Four Corners area and to improve the operation flexibility and reliability of the extra-high-voltage transmission system in the region. The NTP creates the wholesale transmission capacity for more economical power transfers, sales, and purchases in the region. It will facilitate the development of Navajo energy resources, improve economic conditions on the Navajo Nation as well as allow DPA to participate in the western electrical utility industry.

  5. Electron energy loss spectroscopy of gold nanoparticles on graphene

    SciTech Connect (OSTI)

    DeJarnette, Drew [Microelectronics and Photonics Graduate Program, University of Arkansas, Fayetteville, Arkansas 72701 (United States); Roper, D. Keith, E-mail: dkroper@uark.edu [Microelectronics and Photonics Graduate Program, University of Arkansas, Fayetteville, Arkansas 72701 (United States); Department of Chemical Engineering, University of Arkansas, Fayetteville, Arkansas 72701 (United States)

    2014-08-07

    Plasmon excitation decay by absorption, scattering, and hot electron transfer has been distinguished from effects induced by incident photons for gold nanoparticles on graphene monolayer using electron energy loss spectroscopy (EELS). Gold nano-ellipses were evaporated onto lithographed graphene, which was transferred onto a silicon nitride transmission electron microscopy grid. Plasmon decay from lithographed nanoparticles measured with EELS was compared in the absence and presence of the graphene monolayer. Measured decay values compared favorably with estimated radiative and non-radiative contributions to decay in the absence of graphene. Graphene significantly enhanced low-energy plasmon decay, increasing mode width 38%, but did not affect higher energy plasmon or dark mode decay. This decay beyond expected radiative and non-radiative mechanisms was attributed to hot electron transfer, and had quantum efficiency of 20%, consistent with previous reports.

  6. RAPID/BulkTransmission/Transmission Siting & Interconnection...

    Open Energy Info (EERE)

    federal review). Bulk Transmission Transmission Siting & Interconnection in New Mexico New Mexico Statutes (N.M.S.) 62-9-1, 62-9-3(B), and 62-9-3.2 No Location Permit may be...

  7. Electron Microscopy Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Microscopy Lab Electron Microscopy Lab Focusing on the study of microstructures with electron and ion beam instruments, including crystallographic and chemical techniques. April 12, 2012 Transmission electron microscope Rob Dickerson examines a multiphase oxide scale using the FEI Titan 80-300 transmission electron microscope. Contact Rob Dickerson (505) 667-6337 Email Rod McCabe (505) 606-1649 Email Pat Dickerson (505) 665-3036 Email Tom Wynn (505) 665-6861 Email Dedicated to the

  8. National Transmission Grid Study

    Office of Environmental Management (EM)

    Grid Study U.S. Department of Energy The Honorable Spencer Abraham Secretary of Energy May 2002 ii National Transmission Grid Study National Transmission Grid Study i ii National Transmission Grid Study National Transmission Grid Study iii How This Study Was Conducted The National Energy Policy Plan directed the U.S. Department of Energy (DOE) to conduct a study to examine the benefits of establishing a national electricity transmission grid and to identify transmission bottlenecks and measures

  9. Transmission Capacity Forum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Email Address: Name: Organization Entity Type: Select the best fit for your role... Energy Trader Transmission Provider Employee Transmission Purchaser Energy Scheduler...

  10. Electricity Generation, Transmission ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Generation, Transmission and Energy Storage Systems Utilities and other electricity and transmission providers and regulators often require that equipment be proven safe and ...

  11. Survey of Transmission Cost Allocation Methodologies for Regional Transmission Organizations

    SciTech Connect (OSTI)

    Fink, S.; Porter, K.; Mudd, C.; Rogers, J.

    2011-02-01

    The report presents transmission cost allocation methodologies for reliability transmission projects, generation interconnection, and economic transmission projects for all Regional Transmission Organizations.

  12. Sandia Energy - Transmission Grid Integration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transmission Grid Integration Home Stationary Power Energy Conversion Efficiency Solar Energy Photovoltaics Grid Integration Transmission Grid Integration Transmission Grid...

  13. Fact #802: November 4, 2013 Market Share by Transmission Type | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2: November 4, 2013 Market Share by Transmission Type Fact #802: November 4, 2013 Market Share by Transmission Type The variety of transmission technologies has increased as manufacturers seek more efficient ways of transferring power from the engine to the wheels of the vehicles. Automatic transmissions with lockup remain the dominant transmission type but Continuously Variable Transmissions (CVT) have seen greater use in recent years, accounting for about 10 percent of all

  14. Transferring Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Transferring Data Advice and Overview NERSC provides many facilities for storing data and performing analysis. However, transfering data - whether over the wide area network...

  15. Scanning Transmission Electron Microscopy Investigations of Complex...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxidation of light paraffins and olefins, as well as the partial oxidation of methanol. We present HAADF-STEM investigations of various complex oxide phases and show that...

  16. Automated manual transmission controller

    DOE Patents [OSTI]

    Lawrie, Robert E. (Whitmore Lake, MI); Reed, Jr., Richard G. (Royal Oak, MI); Bernier, David R. (Rochester Hills, MI)

    1999-12-28

    A powertrain system for a hybrid vehicle. The hybrid vehicle includes a heat engine, such as a diesel engine, and an electric machine, which operates as both an electric motor and an alternator, to power the vehicle. The hybrid vehicle also includes a manual-style transmission configured to operate as an automatic transmission from the perspective of the driver. The engine and the electric machine drive an input shaft which in turn drives an output shaft of the transmission. In addition to driving the transmission, the electric machine regulates the speed of the input shaft in order to synchronize the input shaft during either an upshift or downshift of the transmission by either decreasing or increasing the speed of the input shaft. When decreasing the speed of the input shaft, the electric motor functions as an alternator to produce electrical energy which may be stored by a storage device. Operation of the transmission is controlled by a transmission controller which receives input signals and generates output signals to control shift and clutch motors to effect smooth launch, upshift shifts, and downshifts of the transmission, so that the transmission functions substantially as an automatic transmission from the perspective of the driver, while internally substantially functioning as a manual transmission.

  17. EC Transmission Line Materials

    SciTech Connect (OSTI)

    Bigelow, Tim S

    2012-05-01

    The purpose of this document is to identify materials acceptable for use in the US ITER Project Office (USIPO)-supplied components for the ITER Electron cyclotron Heating and Current Drive (ECH&CD) transmission lines (TL), PBS-52. The source of material property information for design analysis shall be either the applicable structural code or the ITER Material Properties Handbook. In the case of conflict, the ITER Material Properties Handbook shall take precedence. Materials selection, and use, shall follow the guidelines established in the Materials Assessment Report (MAR). Materials exposed to vacuum shall conform to the ITER Vacuum Handbook. [Ref. 2] Commercial materials shall conform to the applicable standard (e.g., ASTM, JIS, DIN) for the definition of their grade, physical, chemical and electrical properties and related testing. All materials for which a suitable certification from the supplier is not available shall be tested to determine the relevant properties, as part of the procurement. A complete traceability of all the materials including welding materials shall be provided. Halogenated materials (example: insulating materials) shall be forbidden in areas served by the detritiation systems. Exceptions must be approved by the Tritium System and Safety Section Responsible Officers.

  18. Data Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Transfer Data Transfer DQ2 is an ATLAS tool for defining and handling datasets and transferring the datasets on the grid. It was developed as part of the ATLAS Distributed Data Management (DDM) project. Instructions for using DQ2 on PDSF are provided by the LBNL ATLAS group and can be found here. Last edited: 2016-02-01 08:07:00

  19. Series Transmission Line Transformer

    DOE Patents [OSTI]

    Buckles, Robert A.; Booth, Rex; Yen, Boris T.

    2004-06-29

    A series transmission line transformer is set forth which includes two or more of impedance matched sets of at least two transmissions lines such as shielded cables, connected in parallel at one end ans series at the other in a cascading fashion. The cables are wound about a magnetic core. The series transmission line transformer (STLT) which can provide for higher impedance ratios and bandwidths, which is scalable, and which is of simpler design and construction.

  20. Current Transmission Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  1. Previous Transmission Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  2. Collaborative Transmission Technology Roadmap

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Addendum to the Collaborative Transmission Technology Roadmap March 2014 Bonneville Power Administration Enhanced PDF Functionality Functionality of the PDF version of this...

  3. Transmission Infrastructure Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Loan Facility Construction of a 219-mile, 230 kilovolt transmission line from Great Falls, Montana to Lethbridge, Alberta to facilitate delivery of Naturenr Rim Rock wind project. ...

  4. 2012 Transmission Rate Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2014 Transmission, Ancillary, and Control Area Service Rate Schedules and General Rate Schedule Provisions (FY 2014-2015) October 2013 United States Department of Energy...

  5. Transmission - Contact Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact-Information-Transmission Sign In About | Careers | Contact | Investors | bpa.gov Search News & Us Expand News & Us Projects & Initiatives Expand Projects &...

  6. Transmission Line Security Monitor

    ScienceCinema (OSTI)

    None

    2013-05-28

    The Transmission Line Security Monitor is a multi-sensor monitor that mounts directly on high-voltage transmission lines to detect, characterize and communicate terrorist activity, human tampering and threatening conditions around support towers. For more information about INL's critical infrastructure protection research, visit http://www.facebook.com/idahonationallaboratory.

  7. Transmission Line Security Monitor

    SciTech Connect (OSTI)

    2011-01-01

    The Transmission Line Security Monitor is a multi-sensor monitor that mounts directly on high-voltage transmission lines to detect, characterize and communicate terrorist activity, human tampering and threatening conditions around support towers. For more information about INL's critical infrastructure protection research, visit http://www.facebook.com/idahonationallaboratory.

  8. Magnetically insulated transmission line oscillator

    DOE Patents [OSTI]

    Bacon, Larry D. (Albuquerque, NM); Ballard, William P. (Albuquerque, NM); Clark, M. Collins (Albuquerque, NM); Marder, Barry M. (Albuquerque, NM)

    1988-01-01

    A magnetically insulated transmission line oscillator employs self-generated magnetic fields to generate microwave energy. An anode of the oscillator includes slow-wave structures which are formed of a plurality of thin conductive vanes defining cavities therebetween, and a gap is formed between the anode and a cathode of the oscillator. In response to a pulsed voltage applied to the anode and cathode, self-generated magnetic fields arfe produced in a cross-field orientation with respect to the orientation of the electric field between the anode and the cathode. The cross-field magnetic fields insulate the flow of electrons in the gap and confine the flow of electrons within the gap.

  9. Magnetically insulated transmission line oscillator

    DOE Patents [OSTI]

    Bacon, L.D.; Ballard, W.P.; Clark, M.C.; Marder, B.M.

    1987-05-19

    A magnetically insulated transmission line oscillator employs self-generated magnetic fields to generate microwave energy. An anode of the oscillator includes slow-wave structures which are formed of a plurality of thin conductive vanes defining cavities therebetween, and a gap is formed between the anode and a cathode of the oscillator. In response to a pulsed voltage applied to the anode and cathode, self-generated magnetic fields are produced in a cross-field orientation with respect to the orientation of the electric field between the anode and the cathode. The cross-field magnetic fields insulate the flow of electrons in the gap and confine the flow of electrons within the gap. 11 figs.

  10. Characterization and Development of Advanced Heat Transfer Technologie...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Characterization and Development of Advanced Heat Transfer Technologies Advanced Power Electronics and Electric Machines Compact,...

  11. Transmission Grid Integration

    Broader source: Energy.gov [DOE]

    The levels of solar energy penetration envisioned by the DOE SunShot Initiative must be interconnected effectively onto the transmission grid. This interconnection requires an in-depth...

  12. Downhole transmission system

    DOE Patents [OSTI]

    Hall, David R. (Provo, UT); Fox, Joe (Spanish Fork, UT)

    2008-01-15

    A transmission system in a downhole component comprises a data transmission element in both ends of the downhole component. Each data transmission element houses an electrically conducting coil in a MCEI circular trough. An electrical conductor connects both the transmission elements. The electrical conductor comprises at least three electrically conductive elements insulated from each other. In the preferred embodiment the electrical conductor comprises an electrically conducting outer shield, an electrically conducting inner shield and an electrical conducting core. In some embodiments of the present invention, the electrical conductor comprises an electrically insulating jacket. In other embodiments, the electrical conductor comprises a pair of twisted wires. In some embodiments, the electrical conductor comprises semi-conductive material.

  13. Down hole transmission system

    DOE Patents [OSTI]

    Hall, David R. (Provo, UT); Hall, Jr., H. Tracy (Provo, UT)

    2007-07-24

    A transmission system in a downhole component comprises a data transmission element in both ends of the downhole component. Each data transmission element houses an electrically conducting coil in a MCEI circular trough. The electrically conducting coil comprises at least two generally fractional loops. In the preferred embodiment, the transmission elements are connected by an electrical conductor. Preferably, the electrical conductor is a coaxial cable. Preferably, the MCEI trough comprises ferrite. In the preferred embodiment, the fractional loops are connected by a connecting cable. In one aspect of the present invention, the connecting cable is a pair of twisted wires. In one embodiment the connecting cable is a shielded pair of twisted wires. In another aspect of the present invention, the connecting cable is a coaxial cable. The connecting cable may be disposed outside of the MCEI circular trough.

  14. Transmission Developers Inc.

    Energy Savers [EERE]

    ' % ~ Transmission Developers Inc. July 7, 2011 Mr. Anthony J. Como Director, Permitting and Siting Office ofElectricity Delivery and Energy Reliability (OE-20) U.S. Department of Energy 1000 Independence A venue SW, Room 8G-024 Washington, D.C. 20585 Subject: Champlain Hudson Power Express Project U.S. Department of Energy Presidential Permit Application PP-362 Dear Mr. Como: On January 25, 2010, Transmission Developers, Inc. ("TDI'' or "Applicants") submitted on behalf of

  15. Transmission Infrastructure Program

    Energy Savers [EERE]

    TRANSMISSION INFRASTRUCTURE PROGRAM DOE Tribal Energy Summit 2015 SECRETARYOF ENERGY'S FINANCING ROUNDTABLE Tracey A. LeBeau Senior Vice President & Transmission Infrastructure Program Manager 1 Program Description Western's Loan Authority * $3.25 billion permanent authority (revolving) * Goal: Attract investment in infrastructure & address market needs * Commercial underwriting standards TIP Portfolio Management Fundamentals * Reflective of Market Need(s) * Ensure Funds Revolve 2 Recent

  16. Electricity Transmission, A Primer

    Office of Environmental Management (EM)

    Transmission A Primer National Council on Electricity Policy National Council on Electricity Policy i Electricity Transmission A Primer By Matthew H. Brown, National Conference of State Legislatures Richard P. Sedano, The Regulatory Assistance Project National Council on Electric Policy The National Council on Electricity Policy is a joint venture among the National Conference of State Legislatures (NCSL), the National Association of Regulatory Utility Commissioners (NARUC) and the National

  17. EIS-0411: Transmission Agency of Northern California Transmission Project

    Broader source: Energy.gov [DOE]

    This EIS is for the Western Area Power Administration construction, operation, and maintenance of the proposed transmission agency of Northern California Transmission Project, California.

  18. National transmission grid study

    SciTech Connect (OSTI)

    Abraham, Spencer

    2003-05-31

    The National Energy Policy Plan directed the U.S. Department of Energy (DOE) to conduct a study to examine the benefits of establishing a national electricity transmission grid and to identify transmission bottlenecks and measures to address them. DOE began by conducting an independent analysis of U.S. electricity markets and identifying transmission system bottlenecks using DOE’s Policy Office Electricity Modeling System (POEMS). DOE’s analysis, presented in Section 2, confirms the central role of the nation’s transmission system in lowering costs to consumers through increased trade. More importantly, DOE’s analysis also confirms the results of previous studies, which show that transmission bottlenecks and related transmission system market practices are adding hundreds of millions of dollars to consumers’ electricity bills each year. A more detailed technical overview of the use of POEMS is provided in Appendix A. DOE led an extensive, open, public input process and heard a wide range of comments and recommendations that have all been considered.1 More than 150 participants registered for three public workshops held in Detroit, MI (September 24, 2001); Atlanta, GA (September 26, 2001); and Phoenix, AZ (September 28, 2001).

  19. ITC Transmission | Open Energy Information

    Open Energy Info (EERE)

    ITC Transmission Jump to: navigation, search Name: ITC Transmission Place: Michigan Phone Number: Western Michigan Office: (269) 792-7223 -- Northern Michigan Office: (989)...

  20. MGI Electronics LLC | Open Energy Information

    Open Energy Info (EERE)

    MGI Electronics LLC Jump to: navigation, search Name: MGI Electronics LLC Place: Temple, Arizona Zip: 85282 Product: US-based manufacturer of wafer transfer and PV cell handling...

  1. Pressure dependence on the kinetics of photoinduced intramolecular charge separation in 9,9 prime -bianthryl monitored by picosecond transient absorption: Comparison with electron transfer in photosynthesis

    SciTech Connect (OSTI)

    Lueck, H.; Windsor, M.W. ); Rettig, W. )

    1990-05-31

    Transient absorption spectra of 9,9{prime}-bianthryl (BA) in the picosecond time range have been recorded in nonpolar cyclohexane (CH), in polar acetonitrile (ACN), and in the highly viscous solvent glycerol triacetate (GTA). High pressure (0.1-300 MPa) is employed to vary the solvent properties of GTA over an unusually wide range. To our knowledge, this is the first time that picosecond absorption spectra at high pressures have been reported. Transient spectra (25-ps resolution) in GTA can be resolved into an anthracene-like band corresponding to the locally excited state (LE) and a longer wavelength band corresponding to the twisted intramolecular charge transfer state (TICT). Comparisons are made between ET in BA/GTA and ET in the photosynthetic bacterial reaction center. They suggest that the microscopic structure of the protein in which the chromophores are embedded not only induces the asymmetric charge separation but also provides a polar solvent environment optimized for fast activationless ET and preformed to stabilize the charge-separated chromophores.

  2. EC Transmission Line Risk Identification and Analysis

    SciTech Connect (OSTI)

    Bigelow, Tim S

    2012-04-01

    The purpose of this document is to assist in evaluating and planning for the cost, schedule, and technical project risks associated with the delivery and operation of the EC (Electron cyclotron) transmission line system. In general, the major risks that are anticipated to be encountered during the project delivery phase associated with the implementation of the Procurement Arrangement for the EC transmission line system are associated with: (1) Undefined or changing requirements (e.g., functional or regulatory requirements) (2) Underperformance of prototype, first unit, or production components during testing (3) Unavailability of qualified vendors for critical components Technical risks associated with the design and operation of the system are also identified.

  3. 2009 National Electric Transmission Congestion Study Workshops...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmission Planning Congestion Studies 2009 Congestion Study 2009 National Electric Transmission Congestion Study Workshops 2009 National Electric Transmission...

  4. Transmission line capital costs

    SciTech Connect (OSTI)

    Hughes, K.R.; Brown, D.R.

    1995-05-01

    The displacement or deferral of conventional AC transmission line installation is a key benefit associated with several technologies being developed with the support of the U.S. Department of Energy`s Office of Energy Management (OEM). Previous benefits assessments conducted within OEM have been based on significantly different assumptions for the average cost per mile of AC transmission line. In response to this uncertainty, an investigation of transmission line capital cost data was initiated. The objective of this study was to develop a database for preparing preliminary estimates of transmission line costs. An extensive search of potential data sources identified databases maintained by the Bonneville Power Administration (BPA) and the Western Area Power Administration (WAPA) as superior sources of transmission line cost data. The BPA and WAPA data were adjusted to a common basis and combined together. The composite database covers voltage levels from 13.8 to 765 W, with cost estimates for a given voltage level varying depending on conductor size, tower material type, tower frame type, and number of circuits. Reported transmission line costs vary significantly, even for a given voltage level. This can usually be explained by variation in the design factors noted above and variation in environmental and land (right-of-way) costs, which are extremely site-specific. Cost estimates prepared from the composite database were compared to cost data collected by the Federal Energy Regulatory Commission (FERC) for investor-owned utilities from across the United States. The comparison was hampered because the only design specifications included with the FERC data were voltage level and line length. Working within this limitation, the FERC data were not found to differ significantly from the composite database. Therefore, the composite database was judged to be a reasonable proxy for estimating national average costs.

  5. NREL: Transmission Grid Integration - Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Publications Want updates about future transmission grid integration webinars and publications? Join our mailing list. NREL has an extensive collection of publications related to transmission integration research. Explore the resources below to learn more. Selected Project Publications Read selected publications related to these transmission integration projects: Western Wind and Solar Integration Study Eastern Renewable Generation Integration Study Oahu Wind Integration and Transmission Study

  6. Printed circuit dispersive transmission line

    DOE Patents [OSTI]

    Ikezi, H.; Lin-Liu, Y.R.; DeGrassie, J.S.

    1991-08-27

    A printed circuit dispersive transmission line structure is disclosed comprising an insulator, a ground plane formed on one surface of the insulator, a first transmission line formed on a second surface of the insulator, and a second transmission line also formed on the second surface of the insulator and of longer length than the first transmission line and periodically intersecting the first transmission line. In a preferred embodiment, the transmission line structure exhibits highly dispersive characteristics by designing the length of one of the transmission line between two adjacent periodic intersections to be longer than the other. 5 figures.

  7. Printed circuit dispersive transmission line

    DOE Patents [OSTI]

    Ikezi, Hiroyuki (Rancho Santa Fe, CA); Lin-Liu, Yuh-Ren (San Diego, CA); DeGrassie, John S. (Encinitas, CA)

    1991-01-01

    A printed circuit dispersive transmission line structure is disclosed comprising an insulator, a ground plane formed on one surface of the insulator, a first transmission line formed on a second surface of the insulator, and a second transmission line also formed on the second surface of the insulator and of longer length than the first transmission line and periodically intersecting the first transmission line. In a preferred embodiment, the transmission line structure exhibits highly dispersive characteristics by designing the length of one of the transmission line between two adjacent periodic intersections to be longer than the other.

  8. Borehole data transmission apparatus

    DOE Patents [OSTI]

    Kotlyar, O.M.

    1993-03-23

    A borehole data transmission apparatus is described whereby a centrifugal pump impeller(s) is used to provide a turbine stage having substantial pressure characteristics in response to changing rotational speed of a shaft for the pressure pulsing of data from the borehole through the drilling mud to the surface of the earth.

  9. Borehole data transmission apparatus

    DOE Patents [OSTI]

    Kotlyar, Oleg M. (1739 Grandview #2, Idaho Falls, ID 83402)

    1993-01-01

    A borehole data transmission apparatus whereby a centrifugal pump impeller(s) is used to provide a turbine stage having substantial pressure characteristics in response to changing rotational speed of a shaft for the pressure pulsing of data from the borehole through the drilling mud to the surface of the earth.

  10. Autonomous data transmission apparatus

    DOE Patents [OSTI]

    Kotlyar, Oleg M. (4675 W. 3825 S, Salt Lake City, UT 84120)

    1997-01-01

    A autonomous borehole data transmission apparatus for transmitting measurement data from measuring instruments at the downhole end of a drill string by generating pressure pulses utilizing a transducer longitudinally responsive to magnetic field pulses caused by electrical pulses corresponding to the measured downhole parameters.

  11. Autonomous data transmission apparatus

    DOE Patents [OSTI]

    Kotlyar, O.M.

    1997-03-25

    A autonomous borehole data transmission apparatus is described for transmitting measurement data from measuring instruments at the downhole end of a drill string by generating pressure pulses utilizing a transducer longitudinally responsive to magnetic field pulses caused by electrical pulses corresponding to the measured downhole parameters. 4 figs.

  12. Counting graphene layers with very slow electrons

    SciTech Connect (OSTI)

    Frank, Lud?k; Mikmekov, Elika; Mllerov, Ilona; Lejeune, Michal

    2015-01-05

    The study aimed at collection of data regarding the transmissivity of freestanding graphene for electrons across their full energy scale down to the lowest energies. Here, we show that the electron transmissivity of graphene drops with the decreasing energy of the electrons and remains below 10% for energies below 30?eV, and that the slow electron transmissivity value is suitable for reliable determination of the number of graphene layers. Moreover, electrons incident below 50?eV release adsorbed hydrocarbon molecules and effectively clean graphene in contrast to faster electrons that decompose these molecules and create carbonaceous contamination.

  13. Drill string transmission line

    DOE Patents [OSTI]

    Hall, David R. (Provo, UT); Hall, Jr., H. Tracy (Provo, UT); Pixton, David S. (Lehi, UT); Bradford, Kline (Orem, UT); Fox, Joe (Spanish Fork, UT)

    2006-03-28

    A transmission line assembly for transmitting information along a downhole tool comprising a pin end, a box end, and a central bore traveling between the pin end and the box end, is disclosed in one embodiment of the invention as including a protective conduit. A transmission line is routed through the protective conduit. The protective conduit is routed through the central bore and the ends of the protective conduit are routed through channels formed in the pin end and box end of the downhole tool. The protective conduit is elastically forced into a spiral or other non-linear path along the interior surface of the central bore by compressing the protective conduit to a length within the downhole tool shorter than the protective conduit.

  14. Transmission Grid Integration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transmission Grid Integration - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  15. Transmission Siting_071508.indd

    Energy Savers [EERE]

    Coordinating Interstate Electric Transmission Siting: An Introduction to the Debate The National Council on Electricity Policy 2 DISCLAIMER: The National Council on Electricity Policy is funded by the U.S. Department of Energy and the U.S. Environmental Protection Agency. The views and opinions expressed herein are strictly those of the authors and may not necessarily agree with the positions of the National Council on Electricity Policy, its committ ee members or the organizations they

  16. Transmission and Storage Operations

    Energy Savers [EERE]

    Transmission and Storage Operations Natural Gas Infrastructure R&D and Methane Mitigation Workshop Mary Savalle, PMP, LSSGB Compression Reliability Engineer November 12, 2014 Agenda * DTE Gas Snapshot * NOx & CO - Combustion stability * Methane - Packing - Blowdowns * Capture vs Flare 2 SNAPSHOT * DTE Gas - 41 Units * Age Range: 8-59yrs (Average 45yrs) - 118,200HP * 1,000-15,000HP - 7 different manufacturers * Cooper-Bessemer, Solar, Waukesha, DeLaval, IR, CAT, Ariel - Complete Mixture *

  17. Transfer matrix theory of monolayer graphene/bilayer graphene heterostructure superlattice

    SciTech Connect (OSTI)

    Wang, Yu

    2014-10-28

    We have formulated a transfer matrix method to investigate electronic properties of graphene heterostructure consisting of monolayer graphene and bilayer counterpart. By evaluating transmission, conductance, and band dispersion, we show that, irrespective of the different carrier chiralities in monolayer graphene and bilayer graphene, superlattice consisting of biased bilayer graphene barrier and monolayer graphene well can mimic the electronic properties of conventional semiconductor superlattice, displaying the extended subbands in the quantum tunneling regime and producing anisotropic minigaps for the classically allowed transport. Due to the lateral confinement, the lowest mode has shifted away from the charge neutral point of monolayer graphene component, opening a sizeable gap in concerned structure. Following the gate-field and geometry modulation, all electronic states and gaps between them can be externally engineered in an electric-controllable strategy.

  18. Technology Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Booth Myers, Hao-Lin Chen, Glenn Meyer, Dino Ciarlo 1997 Sealed-Tube Electron Beam Guns for Material Processing Luis Zapata, Lloyd Hackel, Damon Matteo 1997 High Power, High...

  19. NREL: Transmission Grid Integration - Transmission Planning and Analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transmission Planning and Analysis Thumbnail of map the United States that shows wind resources and transmission lines. Enlarge image This map shows the location of wind resources and transmission lines in the United States. See a larger image or state maps. NREL researchers are engaged in transmission planning and analysis to strengthen the electric power system through the integration of solar and wind power. As demand for electricity increases, electric power system operators must plan for

  20. Even-odd oscillation and valley polarization of transmission between multilayer graphenes

    SciTech Connect (OSTI)

    Nakanishi, Takeshi; Ando, Tsuneya

    2013-12-04

    Electron transmission through a boundary between multi-layer graphenes with Bernal stacking consisting of different number of layers is studied. A valley polarization in transmission probability appears as in monolayer and bilayer systems, exhibits considerable oscillation depending of even or odd layer numbers, and its amplitude gradually decreases with the layer number. The total transmission shows oscillation with much smaller amplitude.

  1. Free electron laser

    DOE Patents [OSTI]

    Villa, Francesco (Alameda, CA)

    1990-01-01

    A high gain, single-pass free electron laser formed of a high brilliance electron injector source, a linear accelerator which imparts high energy to the electron beam, and an undulator capable of extremely high magnetic fields, yet with a very short period. The electron injector source is the first stage (gap) of the linear accelerator or a radial line transformer driven by fast circular switch. The linear accelerator is formed of a plurality of accelerating gaps arranged in series. These gaps are energized in sequence by releasing a single pulse of energy which propagates simultaneously along a plurality of transmission lines, each of which feeds the gaps. The transmission lines are graduated in length so that pulse power is present at each gap as the accelerated electrons pass therethrough. The transmission lines for each gap are open circuited at their ends. The undualtor has a structure similar to the accelerator, except that the transmission lines for each gap are substantially short circuited at their ends, thus converting the electric field into magnetic field. A small amount of resistance is retained in order to generate a small electric field for replenishing the electron bunch with the energy lost as it traverses through the undulator structure.

  2. Geothermal Resources and Transmission Planning

    Broader source: Energy.gov [DOE]

    This project addresses transmission-related barriers to utility-scale deployment of geothermal electric generation technologies.

  3. National Electric Transmission Congestion Study

    Office of Environmental Management (EM)

    Electric Transmission Congestion Study September 2015 United States Department of Energy Washington, DC 20585 U.S. Department of Energy | September 2015 National Electric Transmission Congestion Study | Page i Message from the Secretary In this study, the U.S. Department of Energy (DOE, the Department) seeks to provide information about transmission congestion by focusing on specific indications of transmission constraints and congestion and their consequences. The study focuses primarily on a

  4. Electric Transmission Line Siting Compact

    Office of Environmental Management (EM)

    Electric Transmission Line Siting Compact 1 ______________________________________________________________________________ 2 ARTICLE I 3 PURPOSE 4 5 Siting electric transmission lines across state borders and federal lands is an issue for states, the 6 federal government, transmission utilities, consumers, environmentalists, and other stakeholders. 7 The current, multi-year application review process by separate and equal jurisdictions constitutes 8 a sometimes inefficient and redundant process

  5. Towards More Transmission Asset Utilization through Real-time Path Rating

    SciTech Connect (OSTI)

    Diao, Ruisheng; Huang, Zhenyu; Jin, Chunlian; Vyakaranam, Bharat GNVSR; Jin, Shuangshuang; Makarov, Yuri V.

    2013-10-21

    Ratings of transmission paths, typically determined in an offline environment, are static and tend to be conservative, leading to underutilization of transmission assets, higher costs of system operation and renewable energy integration, and lower efficiency and savings. With the ever-increasing transmission congestion costs and new challenges from renewable integration, increasing transfer capacity of existing transmission lines is essential. Real-time path rating provides a promising approach to enabling additional power transfer capability and fully utilizing transfer capability. In this paper, the feasibility of real-time path rating is investigated. Several promising technologies to achieve real-time path rating are discussed. Various benefits that can be expected from real-time path rating, such as increased transfer capability and reduced total generation cost, are demonstrated through simulations conducted on the Western Electricity Coordinating Council system model.

  6. TECHNOLOGY TRANSFER

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    404-NOV. 1, 2000 TECHNOLOGY TRANSFER COMMERCIALIZATION ACT OF 2000 VerDate 11-MAY-2000 04:52 Nov 16, 2000 Jkt 089139 PO 00000 Frm 00001 Fmt 6579 Sfmt 6579 E:\PUBLAW\PUBL404.106 APPS27 PsN: PUBL404 114 STAT. 1742 PUBLIC LAW 106-404-NOV. 1, 2000 Public Law 106-404 106th Congress An Act To improve the ability of Federal agencies to license federally owned inventions. Be it enacted by the Senate and House of Representatives of the United States of America in Congress assembled, SECTION 1. SHORT

  7. Microsoft Word - Electron transfer.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    correspondence: edward.solomon@stanford.edu 2 Present Address: Department of Chemistry, University of British Columbia, Vancouver, BC, Canada V6T 1Z1 Science Highlight - June 2003 A A N N e e w w L L o o o o k k a a t t B B i i o o l l o o g g i i c c a a l l E E l l e e c c t t r r o o n n T T r r a a n n s s f f e e r r : : E E l l e e c c t t r r o o n n i i c c R R e e l l a a x x a a t t i i o o n n i i n n R R u u b b r r e e d d o o x x i i n n s s 1 1, , 2 2, , 3 3 Pierre Kennepohl 1,2

  8. Colorado Electrical Transmission Grid

    SciTech Connect (OSTI)

    Zehner, Richard E.

    2012-02-01

    Citation Information: Originator: Earth Science &Observation Center (ESOC), CIRES, University of Colorado at Boulder Originator: Xcel Energy Publication Date: 2012 Title: Colorado XcelEnergy NonXcel Transmission Network Edition: First Publication Information: Publication Place: Earth Science & Observation Center, Cooperative Institute for Research in Environmental Science (CIRES), University of Colorado, Boulder Publisher: Earth Science &Observation Center (ESOC), CIRES, University of Colorado at Boulder Description: This layer contains transmission network of Colorado Spatial Domain: Extent: Top: 4540689.017558 m Left: 160606.141934 m Right: 758715.946645 m Bottom: 4098910.893397m Contact Information: Contact Organization: Earth Science &Observation Center (ESOC), CIRES, University of Colorado at Boulder Contact Person: Khalid Hussein Address: CIRES, Ekeley Building Earth Science & Observation Center (ESOC) 216 UCB City: Boulder State: CO Postal Code: 80309-0216 Country: USA Contact Telephone: 303-492-6782 Spatial Reference Information: Coordinate System: Universal Transverse Mercator (UTM) WGS1984 Zone 13N False Easting: 500000.00000000 False Northing: 0.00000000 Central Meridian: -105.00000000 Scale Factor: 0.99960000 Latitude of Origin: 0.00000000 Linear Unit: Meter Datum: World Geodetic System 1984 (WGS 1984) Prime Meridian: Greenwich Angular Unit: Degree Digital Form: Format Name: Shapefile

  9. Automated manual transmission clutch controller

    DOE Patents [OSTI]

    Lawrie, Robert E. (9375 Kearney Rd., Whitmore Lake, MI 48189); Reed, Jr., Richard G. (3003 Bembridge, Royal Oak, MI 48073); Rausen, David J. (519 S. Gaylord St., Denver, CO 80209)

    1999-11-30

    A powertrain system for a hybrid vehicle. The hybrid vehicle includes a heat engine, such as a diesel engine, and an electric machine, which operates as both an electric motor and an alternator, to power the vehicle. The hybrid vehicle also includes a manual-style transmission configured to operate as an automatic transmission from the perspective of the driver. The engine and the electric machine drive an input shaft which in turn drives an output shaft of the transmission. In addition to driving the transmission, the electric machine regulates the speed of the input shaft in order to synchronize the input shaft during either an upshift or downshift of the transmission by either decreasing or increasing the speed of the input shaft. When decreasing the speed of the input shaft, the electric motor functions as an alternator to produce electrical energy which may be stored by a storage device. Operation of the transmission is controlled by a transmission controller which receives input signals and generates output signals to control shift and clutch motors to effect smooth launch, upshift shifts, and downshifts of the transmission, so that the transmission functions substantially as an automatic transmission from the perspective of the driver, while internally substantially functioning as a manual transmission.

  10. Accelerating the transfer in Technology Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Accelerating the transfer in Technology Transfer Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue: Dec. 2015-Jan. 2016...

  11. FACILITY SURVEY & TRANSFER Facility Survey & Transfer Overview

    Office of Environmental Management (EM)

    will become candidate for transfer to DOE-EM for deactivation and decommissioning. ... used for transferring facilities from a transition status to a deactivation status. ...

  12. Determination of the displacement energy of O, Si and Zr under electron beam irradiation

    SciTech Connect (OSTI)

    Edmondson, Philip D; Weber, William J; Namavar, Fereydoon; Zhang, Yanwen

    2012-01-01

    The response of nanocrystalline, stabilizer-free cubic zirconia thin films on a Si substrate to electron beam irradiation with energies of 4, 110 and 200 keV and fluences up to {approx}1.5 x 10{sup 22} e m{sup -2} has been studied to determine the displacement energies. The 110 and 200 keV irradiations were performed in situ using a transmission electron microscope; the 4 keV irradiations were performed ex situ using an electron gun. In all three irradiations, no structural modification of the zirconia was observed, despite the high fluxes and fluences. However the Si substrate on which the zirconia film was deposited was amorphized under the 200 keV electron irradiation. Examination of the electron-solid interactions reveals that the kinetic energy transfer from the 200 keV electrons to the silicon lattice is sufficient to cause atomic displacements, resulting in amorphization. The kinetic energy transfer from the 200 keV electrons to the oxygen sub-lattice of the zirconia may be sufficient to induce defect production, however, no evidence of defect production was observed. The displacement cross-section value of Zr was found to be {approx}400 times greater than that of O indicating that the O atoms are effectively screened from the electrons by the Zr atoms, and, therefore, the displacement of O is inefficient.

  13. Determination of the Displacement Energies of O, Si and Zr Under Electron Beam Irradiation

    SciTech Connect (OSTI)

    Edmondson, P. D.; Weber, William J.; Namavar, Fereydoon; Zhang, Yanwen

    2012-03-01

    The response of nanocrystalline, stabilizer-free cubic zirconia thin films on a Si substrate to electron beam irradiation with energies of 4, 110 and 200 keV and fluences up to ~1.5 x 10e m has been studied to determine the displacement energies. The 110 and 200 keV irradiations were performed in situ using a transmission electron microscope; the 4 keV irradiations were performed ex situ using an electron gun. In all three irradiations, no structural modification of the zirconia was observed, despite the high fluxes and fluences. However the Si substrate on which the zirconia film was deposited was amorphized under the 200 keV electron irradiation. Examination of the electronsolid interactions reveals that the kinetic energy transfer from the 200 keV electrons to the silicon lattice is sufficient to cause atomic displacements, resulting in amorphization. The kinetic energy transfer from the 200 keV electrons to the oxygen sub-lattice of the zirconia may be sufficient to induce defect production, however, no evidence of defect production was observed. The displacement cross-section value of Zr was found to be ~400 times greater than that of O indicating that the O atoms are effectively screened from the electrons by the Zr atoms, and, therefore, the displacement of O is inefficient.

  14. RAPID/Bulk Transmission | Open Energy Information

    Open Energy Info (EERE)

    Page Edit History RAPIDBulk Transmission < RAPID(Redirected from RAPIDOverviewBulkTransmission) Redirect page Jump to: navigation, search REDIRECT RAPIDBulkTransmission...

  15. Bordertown to California Transmission | Open Energy Information

    Open Energy Info (EERE)

    Transmission EIS Bordertown to California 120kV Transmission Line Project Environmental Impact Statement General NEPA Document Info Energy Sector Transmission Environmental...

  16. Electricity Transmission, A Primer | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Transmission, A Primer Electricity Transmission, A Primer This primer on electric transmission is intended to help policymakers understand the physics of the...

  17. EERE-SBIR Technology Transfer Opportunity: H2 Safety Sensors...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sensors for H2 EERE-SBIR Technology Transfer Opportunity Develop low cost electronics packaging manufacturable at high volume, and integrate LANL sensor into a commercial package...

  18. Energy Department, Arizona Utilities Announce Transmission Infrastruct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Arizona Utilities Announce Transmission Infrastructure Project Energization Energy Department, Arizona Utilities Announce Transmission Infrastructure Project Energization February ...

  19. 2012 National Electric Transmission Congestion Study: Presentation...

    Energy Savers [EERE]

    2012 National Electric Transmission Congestion Study: Presentation from Congestion Study Webinar Series 2012 National Electric Transmission Congestion Study: Presentation from...

  20. Transmission Planning | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Planning Transmission Planning Modernizing America's electricity infrastructure is one of the U.S. Department of Energy's top priorities. The National Transmission Grid Study made clear that without dramatic improvements and upgrades over the next decade our nation's transmission system will fall short of the reliability standards our economy requires, and will result in higher electricity costs to consumers. The Department's research into a variety of tools that will improve advanced system

  1. Electrostatic transfer of epitaxial graphene to glass. (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Electrostatic transfer of epitaxial graphene to glass. Citation Details In-Document Search Title: Electrostatic transfer of epitaxial graphene to glass. We report on a scalable electrostatic process to transfer epitaxial graphene to arbitrary glass substrates, including Pyrex and Zerodur. This transfer process could enable wafer-level integration of graphene with structured and electronically-active substrates such as MEMS and CMOS. We will describe the electrostatic transfer

  2. Vice President, Transmission System Operations

    Broader source: Energy.gov [DOE]

    The VP for Transmission System Operations provides strategic leadership, direction, and oversight of the people, business processes, and systems that are responsible for the safe, reliable, and...

  3. Transmission Planning | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Load as a Resource Program Peer Review 2012 Reliability & Markets Peer Review 2012 Advanced Applications Research & Development Peer Review 2010 Transmission Reliability ...

  4. AGENDA: PETROLEUM PRODUCT TRANSMISSION & DISTRIBUTION

    Broader source: Energy.gov [DOE]

    The agenda for the Quadrennial Energy Review (QER) public stakeholder meeting in New Orleans on petroleum product transmission, distribution, and storage.

  5. Transmission Expansion in the Midwest

    Broader source: Energy.gov [DOE]

    At this unique forum, participants will hear top executives from the area's RTOs, utilities, transmission developers, and state regulatory agencies discuss and debate the most critical issues...

  6. DOE Transmission Capacity Report | Department of Energy

    Office of Environmental Management (EM)

    Transmission Capacity Report DOE Transmission Capacity Report DOE Transmission Capacity Report: Transmission lines, substations, circuit breakers, capacitors, and other equipment provide more than just a highway to deliver energy and power from generating units to distribution systems. Transmission systems both complement and substitute for generation. Transmission generally enhances reliability; lowers the cost of electricity delivered to consumers; limits the ability of generators to exercise

  7. Small passenger car transmission test: Chevrolet Luv transmission

    SciTech Connect (OSTI)

    Bujold, M.P.

    1980-06-01

    The small passenger car transmission test was initiated to supply electric vehicle manufacturers with technical information regarding the performance of commercially available transmissions. This information would enable EV manufacturers to design a more energy efficient vehicle. With this information the manufacturers would be able to estimate vehicle driving range as well as speed and torque requirements for specific roadload performance characteristics. This report covers the 1978 Chevrolet Luv Truck manual transmission. This transmission was tested per a passenger car automatic transmission test code (SAE J65lb) which required drive performance, coast performance, and no load test conditions. The portion of the test code which involved the throttle valve modulation and line pressure were deleted since they did not apply to the manual transmission. Under these test conditions the transmission attained maximum efficiencies in the upper 90% range at rated load for both drive performance tests and coast performance tests. The major results of this test are the torque speed and efficiency curves which are located in the data section of this report. These graphs map the complete performance characteristics for the Chevrolet Luv Truck Manual transmission. This information will facilitate the vehicle manufacturer in the design of a more energy efficient vehicle.

  8. HVDC power transmission technology assessment

    SciTech Connect (OSTI)

    Hauth, R.L.; Tatro, P.J.; Railing, B.D.; Johnson, B.K.; Stewart, J.R.; Fink, J.L.

    1997-04-01

    The purpose of this study was to develop an assessment of the national utility system`s needs for electric transmission during the period 1995-2020 that could be met by future reduced-cost HVDC systems. The assessment was to include an economic evaluation of HVDC as a means for meeting those needs as well as a comparison with competing technologies such as ac transmission with and without Flexible AC Transmission System (FACTS) controllers. The role of force commutated dc converters was to be assumed where appropriate. The assessment begins by identifying the general needs for transmission in the U.S. in the context of a future deregulated power industry. The possible roles for direct current transmission are then postulated in terms of representative scenarios. A few of the scenarios are illustrated with the help of actual U.S. system examples. non-traditional applications as well as traditional applications such as long lines and asynchronous interconnections are discussed. The classical ``break-even distance`` concept for comparing HVDC and ac lines is used to assess the selected scenarios. The impact of reduced-cost converters is reflected in terms of the break-even distance. This report presents a comprehensive review of the functional benefits of HVDC transmission and updated cost data for both ac and dc system components. It also provides some provocative thoughts on how direct current transmission might be applied to better utilize and expand our nation`s increasingly stressed transmission assets.

  9. Energy Transmission and Infrastructure

    SciTech Connect (OSTI)

    Mathison, Jane

    2012-12-31

    The objective of Energy Transmission and Infrastructure Northern Ohio (OH) was to lay the conceptual and analytical foundation for an energy economy in northern Ohio that will: improve the efficiency with which energy is used in the residential, commercial, industrial, agricultural, and transportation sectors for Oberlin, Ohio as a district-wide model for Congressional District OH-09; identify the potential to deploy wind and solar technologies and the most effective configuration for the regional energy system (i.e., the ratio of distributed or centralized power generation); analyze the potential within the district to utilize farm wastes to produce biofuels; enhance long-term energy security by identifying ways to deploy local resources and building Ohio-based enterprises; identify the policy, regulatory, and financial barriers impeding development of a new energy system; and improve energy infrastructure within Congressional District OH-09. This objective of laying the foundation for a renewable energy system in Ohio was achieved through four primary areas of activity: 1. district-wide energy infrastructure assessments and alternative-energy transmission studies; 2. energy infrastructure improvement projects undertaken by American Municipal Power (AMP) affiliates in the northern Ohio communities of Elmore, Oak Harbor, and Wellington; 3. Oberlin, OH-area energy assessment initiatives; and 4. a district-wide conference held in September 2011 to disseminate year-one findings. The grant supported 17 research studies by leading energy, policy, and financial specialists, including studies on: current energy use in the district and the Oberlin area; regional potential for energy generation from renewable sources such as solar power, wind, and farm-waste; energy and transportation strategies for transitioning the City of Oberlin entirely to renewable resources and considering pedestrians, bicyclists, and public transportation as well as drivers in developing transportation policies; energy audits and efficiency studies for Oberlin-area businesses and Oberlin College; identification of barriers to residential energy efficiency and development of programming to remove these barriers; mapping of the solar-photovoltaic and wind-energy supply chains in northwest Ohio; and opportunities for vehicle sharing and collaboration among the ten organizations in Lorain County from the private, government, non-profit, and educational sectors. With non-grant funds, organizations have begun or completed projects that drew on the findings of the studies, including: creation of a residential energy-efficiency program for the Oberlin community; installation of energy-efficient lighting in Oberlin College facilities; and development by the City of Oberlin and Oberlin College of a 2.27 megawatt solar photovoltaic facility that is expected to produce 3,000 megawatt-hours of renewable energy annually, 12% of the Colleges yearly power needs. Implementation of these and other projects is evidence of the economic feasibility and technical effectiveness of grant-supported studies, and additional projects are expected to advance to implementation in the coming years. The public has benefited through improved energydelivery systems and reduced energy use for street lighting in Elmore, Oak Harbor, and Wellington; new opportunities for assistance and incentives for residential energy efficiency in the Oberlin community; new opportunities for financial and energy savings through vehicle collaboration within Lorain County; and decreased reliance on fossil fuels and expanded production of renewable energy in the region. The dissemination conference and the summary report developed for the conference also benefited the public, but making the findings and recommendations of the regional studies broadly available to elected officials, city managers, educators, representatives of the private sector, and the general public.

  10. Regional Transmission Projects: Finding Solutions

    SciTech Connect (OSTI)

    The Keystone Center

    2005-06-15

    The Keystone Center convened and facilitated a year-long Dialogue on "Regional Transmission Projects: Finding Solutions" to develop recommendations that will help address the difficult and contentious issues related to expansions of regional electric transmission systems that are needed for reliable and economic transmission of power within and across regions. This effort brought together a cross-section of affected stakeholders and thought leaders to address the problem with the collective wisdom of their experience and interests. Transmission owners sat at the table with consumer advocates and environmental organizations. Representatives from regional transmission organizations exchanged ideas with state and federal regulators. Generation developers explored common interests with public power suppliers. Together, the Dialogue participants developed consensus solutions about how to begin unraveling some of the more intractable issues surrounding identification of need, allocation of costs, and reaching consensus on siting issues that can frustrate the development of regional transmission infrastructure. The recommendations fall into three broad categories: 1. Recommendations on appropriate institutional arrangements and processes for achieving regional consensus on the need for new or expanded transmission infrastructure 2. Recommendations on the process for siting of transmission lines 3. Recommendations on the tools needed to support regional planning, cost allocation, and siting efforts. List of Dialogue participants: List of Dialogue Participants: American Electric Power American Transmission Company American Wind Energy Association California ISO Calpine Corporation Cinergy Edison Electric Institute Environmental Defense Federal Energy Regulatory Commission Great River Energy International Transmission Company ISO-New England Iowa Public Utility Board Kanner & Associates Midwest ISO National Association of Regulatory Utility Commissioners National Association of State Utility Consumer Advocates National Grid Northeast Utilities PA Office of Consumer Advocates Pacific Gas & Electric Corporation Pennsylvania Public Utility Commission PJM Interconnection The Electricity Consumers Resource Council U.S. Department of Energy US Department of the Interior Van Ness Feldman Western Interstate Energy Board Wind on the Wires Wisconsin Public Service Commission Xcel Energy

  11. Ultrasonic power transfer from a spherical acoustic wave source to a free-free piezoelectric receiver: Modeling and experiment

    SciTech Connect (OSTI)

    Shahab, S.; Gray, M.; Erturk, A.

    2015-03-14

    Contactless powering of small electronic components has lately received growing attention for wireless applications in which battery replacement or tethered charging is undesired or simply impossible, and ambient energy harvesting is not a viable solution. As an alternative to well-studied methods of contactless energy transfer, such as the inductive coupling method, the use of ultrasonic waves transmitted and received by piezoelectric devices enables larger power transmission distances, which is critical especially for deep-implanted electronic devices. Moreover, energy transfer by means of acoustic waves is well suited in situations where no electromagnetic fields are allowed. The limited literature of ultrasonic acoustic energy transfer is mainly centered on proof-of-concept experiments demonstrating the feasibility of this method, lacking experimentally validated modeling efforts for the resulting multiphysics problem that couples the source and receiver dynamics with domain acoustics. In this work, we present fully coupled analytical, numerical, and experimental multiphysics investigations for ultrasonic acoustic energy transfer from a spherical wave source to a piezoelectric receiver bar that operates in the 33-mode of piezoelectricity. The fluid-loaded piezoelectric receiver under free-free mechanical boundary conditions is shunted to an electrical load for quantifying the electrical power output for a given acoustic source strength of the transmitter. The analytical acoustic-piezoelectric structure interaction modeling framework is validated experimentally, and the effects of system parameters are reported along with optimal electrical loading and frequency conditions of the receiver.

  12. Computers and data-transmission equipment. Alpha-numeric codes

    SciTech Connect (OSTI)

    Not Available

    1986-02-04

    In this translated Soviet document, a standard is extended to a binary seven-element code (symbols and their code designations), which is intended for the representation of information at the inputs and outputs of the data transmission equipment, electronic computers, and input/output units.

  13. Data Transfer Nodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transfer » Data Transfer Nodes Data Transfer Nodes A redirector page has been set up without anywhere to redirect to. Last edited: 2016-02-24 13:40:09

  14. Electrical transmission line diametrical retainer

    DOE Patents [OSTI]

    Hall, David R.; Hall, Jr., H. Tracy; Pixton, David; Dahlgren, Scott; Sneddon, Cameron; Briscoe, Michael; Fox, Joe

    2004-12-14

    The invention is a mechanism for retaining an electrical transmission line. In one embodiment of the invention it is a system for retaining an electrical transmission line within down hole components. In accordance with one aspect of the invention, the system includes a plurality of downhole components, such as sections of pipe in a drill string. The system also includes a coaxial cable running between the first and second end of a drill pipe, the coaxial cable having a conductive tube and a conductive core within it. The invention allows the electrical transmission line to with stand the tension and compression of drill pipe during routine drilling cycles.

  15. Bandwidth and Transfer Activity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    average. Graphs for the last 8 days. Historical yearly peak days. Daily Storage Concurrency Transfer Activity This graph shows the number of transfers to the storage systems...

  16. Localized radio frequency communication using asynchronous transfer mode protocol

    DOE Patents [OSTI]

    Witzke, Edward L.; Robertson, Perry J.; Pierson, Lyndon G.

    2007-08-14

    A localized wireless communication system for communication between a plurality of circuit boards, and between electronic components on the circuit boards. Transceivers are located on each circuit board and electronic component. The transceivers communicate with one another over spread spectrum radio frequencies. An asynchronous transfer mode protocol controls communication flow with asynchronous transfer mode switches located on the circuit boards.

  17. Transmission Services Product Pricing Validation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and 09:00 PPT on the above effective date. On October 15, 2013, at 08:00 (PPT), Transmission Services will be updating the OASIS default product prices to reflect the 2014...

  18. Transmission Services Product Pricing Validation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and 12:00 PPT on the above effective date. On October 1, 2015, at 11:00 (PPT), Transmission Services will be updating the OASIS default product prices to reflect the 2016...

  19. EIS-0231: Navajo Transmission Project

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of a proposal to by Dine Power Authority, a Navajo Nation enterprise, to construct, operate, and maintain a 500 kilovolt (kV) transmission line planned...

  20. Transmission Reliability | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmission Reliability Transmission Reliability Modernizing America's electricity infrastructure is one of the U.S. Department of Energy's top priorities. The DOE Strategic Plan states that today's electric grid needs to be more efficient, reliable, and secure. A modern, smarter electric grid may save consumers money, help our economy run more efficiently, allow rapid growth in renewable energy sources, and enhance energy reliability. The Department's research into a variety of tools that will

  1. Transmission SEAB Presentation | Department of Energy

    Energy Savers [EERE]

    Transmission SEAB Presentation Transmission SEAB Presentation PDF icon Transmission SEAB Presentation More Documents & Publications Before House Natural Resources Committee QER - Comment of American Public Power Association 5 Before the House Committee on Natural Resources

  2. Chapter 4 Transmission Adequacy | Department of Energy

    Office of Environmental Management (EM)

    4 Transmission Adequacy Chapter 4 Transmission Adequacy Transmission lines are the critical link between the point of electricity generation and consumers. The U.S. transmission grid infrastructure is owned and operated by approximately 3,000 distribution utilities and 500 transmission owners. This structure presents a distinct set of challenges in transmission planning, siting, cost allocation, grid operations and management, technological innovation, financing and construction. The development

  3. In situ transmission electron microscopy study of electrochemical...

    Office of Scientific and Technical Information (OSTI)

    Number: SC0001160 Resource Type: Journal Article Resource Relation: Journal Name: ACS Nano; Journal Volume: 7; Related Information: NEES partners with University of Maryland...

  4. Check Heat Transfer Surfaces

    Broader source: Energy.gov [DOE]

    This tip sheet discusses the importance of checking heat transfer surfaces in process heating systems.

  5. Wireless Power Transfer

    SciTech Connect (OSTI)

    2013-07-22

    Wireless Power Transfer is an innovative approach using magnetic resonance coupling of air core transformers designed for today's growing plug-in electric vehicle market. This technology can provide a convenient, safe and flexible means to charge electric vehicles under stationary and dynamic conditions. Plug-in Electric Vehicles (PEV) are burdened by the need for cable and plug charger, galvanic isolation of the on-board electronics, bulk and cost of this charger and the large energy storage system (ESS) packs needed. With a system where you have to physically plug in there are a number of occasions where the owner could very well forget to charge the vehicle. For stationary applications (like charging of a PHEV at home), ORNL's innovative wireless power transfer technology adds a convenience factor compared to actually plugging in which will mean that the vehicle will have a full charge every morning. Electric vehicle charging must be safe, compact and efficient in order to be convenient for customers. By reconfiguring the transformer and altering the resonance frequency, energy is transferred to the battery with lower energy losses and with fewer demands on the primary circuit by the rest of the transformer system. The ORNL discovery shows that sufficient power for the battery can be transferred from the primary to secondary circuits without significant energy losses if the operating frequency is set at 50% to 95% of the resonance frequency of the circuit. The electrical power is then transmitted to the chargeable battery, which is electrically coupled to the secondary circuit through the air core transformer. Some advantages include: Reduced energy losses during transfer of energy to the battery; A charge potential that is relatively unaffected by up to 25% misalignment of vehicle; and Other receiving components draw less power from the primary circuit. These advantages allow wireless power technology applications to expand at the workplace and beyond as the demand for EV rises. For vehicles that operate over a fixed route such as busses and shuttle vehicles, Wireless Power Transfer (WPT) means that a smaller battery pack can be used. In the traditional system, the battery pack is designed to accommodate the needs of the entire route or shift. With WPT the battery can be downsized because it can be charged when the vehicle stops on its route (a rental car shuttle bus, for example, can charge when it waits in the terminal and again when it waits at the rental car place. Thus the battery only needs enough charge to get to the next stop. This decrease in battery size means significant cost savings to electrify the vehicle. This technology enables efficient "opportunity charging stations" for predefined routes and planned stops reducing down time. Charging can occur in minutes. This improvement also eliminates the harmful emissions that occur in garages while buses are at idle during charging. In larger cities, dynamic charging offers an even greater impact utilizing existing infrastructure. As vehicles travel along busy freeways and interstate systems, wireless charging can occur while the vehicle is in motion. With this technology a vehicle essentially has unlimited electric range while using a relatively small battery pack. In-motion charging stations use vehicle sensors to alert the driver. Traveling at normal speeds, sensors establish in-motion charging. WPT transmit pads sequentially energize to the negotiated power level based on vehicle speed and its requested charging energy. Lower power when vehicle speed is slow and much higher power for faster moving vehicles. Vehicle to Infrastructure communications (V2I) coordinates WPT charging level according to on-board battery pack state-of-charge. V2I activates the roadway transmit pads placing them in standby mode and negotiates charging fee based on prevailing grid rate and vehicle energy demand. Dynamic charging would allow electricity to supply a very large fraction of the energy for the transportation sector and reduce greatly petroleum consump

  6. Electric Transmission Siting | Open Energy Information

    Open Energy Info (EERE)

    OtherOther: Electric Transmission SitingLegal Abstract Brief overview of the California Public Utilities Commission's process for siting of electric transmission lines. Published...

  7. Midwest Independent Transmission System Operator | Open Energy...

    Open Energy Info (EERE)

    Midwest Independent Transmission System Operator Jump to: navigation, search Name: Midwest Independent Transmission System Operator Place: Carmel, IN References: SGIC1 This...

  8. Transmission Losses Product (pbl/products)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wind Smoothing and Intertie Service (Pilot) Firstgov Pricing for Transmission Losses Product Bonneville Power Administration (BPA) Power Services offers to sell transmission...

  9. Southwest Transmission Cooperative, Inc. Smart Grid Project ...

    Open Energy Info (EERE)

    syntax: * Display map References ARRA Smart Grid Investment Grants1 Southwest Transmission Cooperative Award2 Southwest Transmission Cooperative, Inc., located in Benson,...

  10. 2006 National Electric Transmission Congestion Study | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 National Electric Transmission Congestion Study 2006 National Electric Transmission Congestion Study Section 216(a) of the Federal Power Act, as amended by the Energy Policy Act...

  11. 2006 National Electric Transmission Congestion Study Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 National Electric Transmission Congestion Study Federal Register Notice & Comments 2006 National Electric Transmission Congestion Study Federal Register Notice & Comments The...

  12. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in the Texas Interconnection Interconnection-Wide Transmission Planning Initiative: Topic B, State Agency Input Regarding Electric Resource and Transmission Planning in the...

  13. Lone Star Transmission LLC | Open Energy Information

    Open Energy Info (EERE)

    Transmission LLC Jump to: navigation, search Name: Lone Star Transmission LLC Place: Juno Beach, Florida Zip: 33408 Product: Wholly owned subsidiary of FPL Energy, developing...

  14. Electricity Transmission, A Primer | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    This primer on electric transmission is intended to help policymakers understand the physics of the transmission system, the economics, and the policies. PDF icon Electricity ...

  15. American Transmission Systems Inc | Open Energy Information

    Open Energy Info (EERE)

    American Transmission Systems Inc Jump to: navigation, search Name: American Transmission Systems Inc Place: Ohio Website: www.atcllc.com Twitter: @amertransco References: EIA...

  16. Transmission Capital Limited | Open Energy Information

    Open Energy Info (EERE)

    Transmission Capital Limited Jump to: navigation, search Name: Transmission Capital Limited Place: London, United Kingdom Zip: EC2V 7HR Sector: Renewable Energy, Services Product:...

  17. 2009 National Electric Transmission Congestion Study | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9 National Electric Transmission Congestion Study 2009 National Electric Transmission Congestion Study Section 216(a) of the Federal Power Act, as amended by the Energy Policy Act...

  18. Data Transfer Nodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Transfer Nodes Data Transfer Nodes PDSF has dedicated nodes for grid services and data transfers named pdsfdtn1.nersc.gov and pdsfdtn2.nersc.gov. Both nodes have 10 Gb/s network connections to the NERSC network. Please avoid using the interactive nodes for bulk data transfer. Not only can it be disruptive to other users but the network connection is only 1 Gb/s so it will take longer. For transfers using /project and/or HPSS use the NERSC data transfer nodes - see the NERSC data transfer

  19. TECHNOLOGY TRANSFER COORDINATORS

    Broader source: Energy.gov [DOE]

    Mark Hartney, Director of the Office of Strategic Planning, SLAC, discussed technology transfer at SLAC. Bob Hwang, Director, Transportation Energy Center, Combustion Research Facility, SNL presented on technology transfer at SNL. Elsie Quaite-Randall, Chief Technology Transfer Officer, Innovation and Partnerships Office, LBNL, presented on technology transfer at LBNL. Richard A. Rankin, Director, Industrial Partnerships Office and Economic Development Office (Interim), LLNL, presented on technology transfer at LLNL.

  20. Interconnection Transmission Planning: Awards | Department of Energy

    Energy Savers [EERE]

    Interconnection Transmission Planning: Awards Interconnection Transmission Planning: Awards List of Interconnection Transmission Planning awards under the American Recovery and Reinvestment Act organized by interconnection including the organization and amount of Recovery Act funding PDF icon Interconnection Transmission Planning: Awards More Documents & Publications EAC Recommendations for DOE Action Regarding Interconnection-Wide Planning - June 6, 2013 Report: Impacts of Demand-Side

  1. Energy Department, Arizona Utilities Announce Transmission Infrastructure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Project Energization | Department of Energy Arizona Utilities Announce Transmission Infrastructure Project Energization Energy Department, Arizona Utilities Announce Transmission Infrastructure Project Energization February 12, 2015 - 2:30pm Addthis News Media Contact 202 586 4940 DOENews@hq.doe.gov Energy Department, Arizona Utilities Announce Transmission Infrastructure Project Energization Transmission Line Increases Reliability, Access to Affordable Energy in Southwest States WASHINGTON

  2. Wind Integration, Transmission, and Resource Assessment and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Characterization Projects | Department of Energy Integration, Transmission, and Resource Assessment and Characterization Projects Wind Integration, Transmission, and Resource Assessment and Characterization Projects This report covers the Wind and Water Power Technologies Office's Wind integration, transmission, and resource assessment and characterization projects from fiscal years 2006 to 2014. PDF icon Wind Integration, Transmission, and Resource Assessment and Characterization Projects

  3. Wireless adiabatic power transfer

    SciTech Connect (OSTI)

    Rangelov, A.A.; Suchowski, H.; Silberberg, Y.; Vitanov, N.V.

    2011-03-15

    Research Highlights: > Efficient and robust mid-range wireless energy transfer between two coils. > The adiabatic energy transfer is analogous to adiabatic passage in quantum optics. > Wireless energy transfer is insensitive to any resonant constraints. > Wireless energy transfer is insensitive to noise in the neighborhood of the coils. - Abstract: We propose a technique for efficient mid-range wireless power transfer between two coils, by adapting the process of adiabatic passage for a coherently driven two-state quantum system to the realm of wireless energy transfer. The proposed technique is shown to be robust to noise, resonant constraints, and other interferences that exist in the neighborhood of the coils.

  4. Power superconducting power transmission cable

    DOE Patents [OSTI]

    Ashworth, Stephen P. (Cambridge, GB)

    2003-01-01

    The present invention is for a compact superconducting power transmission cable operating at distribution level voltages. The superconducting cable is a conductor with a number of tapes assembled into a subconductor. These conductors are then mounted co-planarly in an elongated dielectric to produce a 3-phase cable. The arrangement increases the magnetic field parallel to the tapes thereby reducing ac losses.

  5. Power superconducting power transmission cable

    DOE Patents [OSTI]

    Ashworth, Stephen P.

    2003-06-10

    The present invention is for a compact superconducting power transmission cable operating at distribution level voltages. The superconducting cable is a conductor with a number of tapes assembled into a subconductor. These conductors are then mounted co-planarly in an elongated dielectric to produce a 3-phase cable. The arrangement increases the magnetic field parallel to the tapes thereby reducing ac losses.

  6. Transmission Access Resources | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmission Access Resources Transmission Access Resources Historically, the addition of new electric generation facilities has been accompanied by new transmission systems. For example, large nuclear and coal plants built in the 1960s and 1970s required interstate transmission infrastructure to deliver the electricity they produced. Likewise, the development of solar and wind generation in the United States will likely involve the development of new transmission. Although the cost of building

  7. In vitro assembly of a prohead-like structure of the Rhodobacter capsulatus gene transfer agent

    SciTech Connect (OSTI)

    Spano, Anthony J. . E-mail: ajs6z@virginia.edu; Chen, Frank S.; Goodman, Benjamin E.; Sabat, Agnes E.; Simon, Martha N.; Wall, Joseph S.; Correia, John J.; McIvor, Wilson; Newcomb, William W.; Brown, Jay C.; Schnur, Joel M.; Lebedev, Nikolai

    2007-07-20

    The gene transfer agent (GTA) is a phage-like particle capable of exchanging double-stranded DNA fragments between cells of the photosynthetic bacterium Rhodobacter capsulatus. Here we show that the major capsid protein of GTA, expressed in E. coli, can be assembled into prohead-like structures in the presence of calcium ions in vitro. Transmission electron microscopy (TEM) of uranyl acetate staining material and thin sections of glutaraldehyde-fixed material demonstrates that these associates have spherical structures with diameters in the range of 27-35 nm. The analysis of scanning TEM images revealed particles of mass {approx} 4.3 MDa, representing 101 {+-} 11 copies of the monomeric subunit. The establishment of this simple and rapid method to form prohead-like particles permits the GTA system to be used for genome manipulation within the photosynthetic bacterium, for specific targeted drug delivery, and for the construction of biologically based distributed autonomous sensors for environmental monitoring.

  8. NETL: Tech Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Licensing & Technology Transfer Technology transfer is the process of transferring new technologies from the laboratory to the marketplace, transforming research into new products and companies so inventions benefit the greatest number of people as quickly and efficiently as possible. At NETL, researchers work every day to develop technology solutions to difficult problems. NETL Technology Transfer works with entrepreneurs, companies, universities and the public sector to move federally

  9. Transmission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Volunteers - Sign Up About Science Bowl Curriculum and Activities How to Build a Motor The Great Marble Drop How to Build a Turbine How to Build a Tower Classroom...

  10. Electron radiography

    DOE Patents [OSTI]

    Merrill, Frank E.; Morris, Christopher

    2005-05-17

    A system capable of performing radiography using a beam of electrons. Diffuser means receive a beam of electrons and diffuse the electrons before they enter first matching quadrupoles where the diffused electrons are focused prior to the diffused electrons entering an object. First imaging quadrupoles receive the focused diffused electrons after the focused diffused electrons have been scattered by the object for focusing the scattered electrons. Collimator means receive the scattered electrons and remove scattered electrons that have scattered to large angles. Second imaging quadrupoles receive the collimated scattered electrons and refocus the collimated scattered electrons and map the focused collimated scattered electrons to transverse locations on an image plane representative of the electrons' positions in the object.

  11. Computer controllable synchronous shifting of an automatic transmission

    DOE Patents [OSTI]

    Davis, R.I.; Patil, P.B.

    1989-08-08

    A multiple forward speed automatic transmission produces its lowest forward speed ratio when a hydraulic clutch and hydraulic brake are disengaged and a one-way clutch connects a ring gear to the transmission casing. Second forward speed ratio results when the hydraulic clutch is engaged to connect the ring gear to the planetary carrier of a second gear set. Reverse drive and regenerative operation result when an hydraulic brake fixes the planetary and the direction of power flow is reversed. Various sensors produce signals representing the torque at the output of the transmission or drive wheels, the speed of the power source, and the hydraulic pressure applied to a clutch and brake. A control algorithm produces input data representing a commanded upshift, a commanded downshift, a commanded transmission output torque, and commanded power source speed. A microprocessor processes the inputs and produces a response to them in accordance with the execution of a control algorithm. Output or response signals cause selective engagement and disengagement of the clutch and brake at a rate that satisfies the requirements for a short gear ratio change and smooth torque transfer between the friction elements. 6 figs.

  12. Computer controlled synchronous shifting of an automatic transmission

    DOE Patents [OSTI]

    Davis, Roy I. (9214 Abbey La., Ypsilanti, MI 48198); Patil, Prabhakar B. (10294 W. Outer Dr., Detroit, MI 48223)

    1989-01-01

    A multiple forward speed automatic transmission produces its lowest forward speed ratio when a hydraulic clutch and hydraulic brake are disengaged and a one-way clutch connects a ring gear to the transmission casing. Second forward speed ratio results when the hydraulic clutch is engaged to connect the ring gear to the planetary carrier of a second gear set. Reverse drive and regenerative operation result when an hydraulic brake fixes the planetary and the direction of power flow is reversed. Various sensors produce signals representing the torque at the output of the transmission or drive wheels, the speed of the power source, and the hydraulic pressure applied to a clutch and brake. A control algorithm produces input data representing a commanded upshift, a commanded downshift, a commanded transmission output torque, and commanded power source speed. A microprocessor processes the inputs and produces a response to them in accordance with the execution of a control algorithm. Output or response signals cause selective engagement and disengagement of the clutch and brake at a rate that satisfies the requirements for a short gear ratio change and smooth torque transfer between the friction elements.

  13. Directional Reactive Power Ground Plane Transmission - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Find More Like This Return to Search Directional Reactive Power Ground Plane Transmission Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryORNL researchers have developed a pioneering power alternative to batteries using directional reactive power. Batteries are currently the primary option for powering mobile electronic equipment; however, batteries are heavy and battery

  14. Heat transfer system

    DOE Patents [OSTI]

    McGuire, Joseph C. (Richland, WA)

    1982-01-01

    A heat transfer system for a nuclear reactor. Heat transfer is accomplished within a sealed vapor chamber which is substantially evacuated prior to use. A heat transfer medium, which is liquid at the design operating temperatures, transfers heat from tubes interposed in the reactor primary loop to spaced tubes connected to a steam line for power generation purposes. Heat transfer is accomplished by a two-phase liquid-vapor-liquid process as used in heat pipes. Condensible gases are removed from the vapor chamber through a vertical extension in open communication with the chamber interior.

  15. Heat transfer system

    DOE Patents [OSTI]

    Not Available

    1980-03-07

    A heat transfer system for a nuclear reactor is described. Heat transfer is accomplished within a sealed vapor chamber which is substantially evacuated prior to use. A heat transfer medium, which is liquid at the design operating temperatures, transfers heat from tubes interposed in the reactor primary loop to spaced tubes connected to a steam line for power generation purposes. Heat transfer is accomplished by a two-phase liquid-vapor-liquid process as used in heat pipes. Condensible gases are removed from the vapor chamber through a vertical extension in open communication with the chamber interior.

  16. Defect tolerant transmission lithography mask

    DOE Patents [OSTI]

    Vernon, Stephen P. (Pleasanton, CA)

    2000-01-01

    A transmission lithography mask that utilizes a transparent substrate or a partially transparent membrane as the active region of the mask. A reflective single layer or multilayer coating is deposited on the membrane surface facing the illumination system. The coating is selectively patterned (removed) to form transmissive (bright) regions. Structural imperfections and defects in the coating have negligible effect on the aerial image of the mask master pattern since the coating is used to reflect radiation out of the entrance pupil of the imaging system. Similarly, structural imperfections in the clear regions of the membrane have little influence on the amplitude or phase of the transmitted electromagnetic fields. Since the mask "discards," rather than absorbs, unwanted radiation, it has reduced optical absorption and reduced thermal loading as compared to conventional designs. For EUV applications, the mask circumvents the phase defect problem, and is independent of the thermal load during exposure.

  17. Wave transmission over submerged breakwaters

    SciTech Connect (OSTI)

    Kobayashi, N.; Wurjanto, A. )

    1989-09-01

    Monochromatic wave reflection and transmission over a submerged impermeable breakwater is predicted numerically by slightly modifying the numerical model developed previously for predicting wave reflection and run-up on rough or smooth impermeable slopes. The slight modification is related to the landward boundary condition required for the transmitted wave propagating landward. In addition to the conservation equations of mass and momentum used to compute the flow field, an equation of energy is derived to estimate the rate of energy dissipation due to wave breaking. The computed reflection and transmission coefficients are shown to be in agreement with available small-scale test data. The numerical model also predicts the spatial variation of the energy dissipation, the mean water level difference, and the time-averaged volume flux per unit width, although available measurements are not sufficient for evaluating the capabilities and limitations of the numerical model for predicting these quantities.

  18. Midwest Transmission Workshop II Summary

    SciTech Connect (OSTI)

    Kevin Bryan

    2002-12-05

    OAK-B135 After introductions of all participants, Abby Arnold, RESOLVE, reviewed the purpose of the meeting and the agenda. The purpose of the workshop was to share the results of the Midwest Independent System Operator (MISO) scenario development for wind and other fuel sources and the corresponding implications for transmission throughout the MISO control area. The workshop agenda is included in Attachment A.

  19. NREL: Transmission Grid Integration - Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Projects NREL's transmission integration projects provide data and models that help utilities and policymakers make informed decisions about the integration of variable generation, such as solar and wind energy, into the electric power system. Researchers are exploring the potential impacts of higher penetrations of solar and wind power on system operations. Our projects provide insights that enable improved and economical operation practices. Some projects also analyze bulk power market

  20. NREL: Transmission Grid Integration - Webmaster

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Webmaster Please enter your name and email address in the boxes provided, and then type your message below. When you are finished, click the "Send Message" button. NOTE: If you enter your email address incorrectly, we will be unable to reply. Your name: Your email address: Your message: Send Message Printable Version Transmission Grid Integration Home Issues Projects Research Staff Working with Us Publications Webinars Data & Resources News Did you find what you needed? Yes 1 No 0

  1. Coiled transmission line pulse generators

    DOE Patents [OSTI]

    McDonald, Kenneth Fox (Columbia, MO)

    2010-11-09

    Methods and apparatus are provided for fabricating and constructing solid dielectric "Coiled Transmission Line" pulse generators in radial or axial coiled geometries. The pour and cure fabrication process enables a wide variety of geometries and form factors. The volume between the conductors is filled with liquid blends of monomers, polymers, oligomers, and/or cross-linkers and dielectric powders; and then cured to form high field strength and high dielectric constant solid dielectric transmission lines that intrinsically produce ideal rectangular high voltage pulses when charged and switched into matched impedance loads. Voltage levels may be increased by Marx and/or Blumlein principles incorporating spark gap or, preferentially, solid state switches (such as optically triggered thyristors) which produce reliable, high repetition rate operation. Moreover, these Marxed pulse generators can be DC charged and do not require additional pulse forming circuitry, pulse forming lines, transformers, or an a high voltage spark gap output switch. The apparatus accommodates a wide range of voltages, impedances, pulse durations, pulse repetition rates, and duty cycles. The resulting mobile or flight platform friendly cylindrical geometric configuration is much more compact, light-weight, and robust than conventional linear geometries, or pulse generators constructed from conventional components. Installing additional circuitry may accommodate optional pulse shape improvements. The Coiled Transmission Lines can also be connected in parallel to decrease the impedance, or in series to increase the pulse length.

  2. Revealing the atomic and electronic structure of a SrTiO{sub 3}/LaNiO{sub 3}/SrTiO{sub 3} heterostructure interface

    SciTech Connect (OSTI)

    Zhang, Zaoli; Soltan, S.; Schmid, H.; Habermeier, H.-U.; Keimer, B.; Kaiser, U.

    2014-03-14

    The atomic structures of SrTiO{sub 3} (STO)/LaNiO{sub 3} (LNO)/STO heterostructure interfaces were investigated by spherical aberration-corrected (C{sub S}) (scanning) transmission electron microscopy. Atomic displacement and lattice distortion measurements and electron energy loss spectroscopy (EELS) were used to quantitatively analyze the distortion of the interfacial octahedra and the bond length at the interfaces. Combined with high-resolution transmission electron microscopy (HRTEM) and scanning transmission electron microscopy analyses, two distinct interfacial atomic terminating layers are unambiguously determined. Ensuing quantitative HRTEM measurements revealed that the Ni-O bond length in the interfacial octahedral is elongated at the bottom interface (NiO{sub 2}-SrO). Atomic displacement shows structural relaxation effects when crossing the interfaces and lattice distortions across the interface is more pronounced in LNO than in STO. The Ti/O atomic ratio, La and Ti relative atomic ratio as derived by EELS quantification indicate non-stoichiometric composition at the interfaces. Distinct fine structures of Ti-L{sub 2,3} edge and O-K edge at the bottom and top interfaces are observed. By comparison, we are able to estimate Ti valency at both interfaces. Combining the structural distortions and Ti valency, the polar discontinuity and charge transfer at the interfaces are discussed.

  3. Wireless Power Transfer

    ScienceCinema (OSTI)

    None

    2013-11-19

    Wireless Power Transfer is an innovative approach using magnetic resonance coupling of air core transformers designed for today's growing plug-in electric vehicle market. This technology can provide a convenient, safe and flexible means to charge electric vehicles under stationary and dynamic conditions. Plug-in Electric Vehicles (PEV) are burdened by the need for cable and plug charger, galvanic isolation of the on-board electronics, bulk and cost of this charger and the large energy storage system (ESS) packs needed. With a system where you have to physically plug in there are a number of occasions where the owner could very well forget to charge the vehicle. For stationary applications (like charging of a PHEV at home), ORNL's innovative wireless power transfer technology adds a convenience factor compared to actually plugging in which will mean that the vehicle will have a full charge every morning. Electric vehicle charging must be safe, compact and efficient in order to be convenient for customers. By reconfiguring the transformer and altering the resonance frequency, energy is transferred to the battery with lower energy losses and with fewer demands on the primary circuit by the rest of the transformer system. The ORNL discovery shows that sufficient power for the battery can be transferred from the primary to secondary circuits without significant energy losses if the operating frequency is set at 50% to 95% of the resonance frequency of the circuit. The electrical power is then transmitted to the chargeable battery, which is electrically coupled to the secondary circuit through the air core transformer. Some advantages include: Reduced energy losses during transfer of energy to the battery; A charge potential that is relatively unaffected by up to 25% misalignment of vehicle; and Other receiving components draw less power from the primary circuit. These advantages allow wireless power technology applications to expand at the workplace and beyond as the demand for EV rises. For vehicles that operate over a fixed route such as busses and shuttle vehicles, Wireless Power Transfer (WPT) means that a smaller battery pack can be used. In the traditional system, the battery pack is designed to accommodate the needs of the entire route or shift. With WPT the battery can be downsized because it can be charged when the vehicle stops on its route (a rental car shuttle bus, for example, can charge when it waits in the terminal and again when it waits at the rental car place. Thus the battery only needs enough charge to get to the next stop. This decrease in battery size means significant cost savings to electrify the vehicle. This technology enables efficient "opportunity charging stations" for predefined routes and planned stops reducing down time. Charging can occur in minutes. This improvement also eliminates the harmful emissions that occur in garages while buses are at idle during charging. In larger cities, dynamic charging offers an even greater impact utilizing existing infrastructure. As vehicles travel along busy freeways and interstate systems, wireless charging can occur while the vehicle is in motion. With this technology a vehicle essentially has unlimited electric range while using a relatively small battery pack. In-motion charging stations use vehicle sensors to alert the driver. Traveling at normal speeds, sensors establish in-motion charging. WPT transmit pads sequentially energize to the negotiated power level based on vehicle speed and its requested charging energy. Lower power when vehicle speed is slow and much higher power for faster moving vehicles. Vehicle to Infrastructure communications (V2I) coordinates WPT charging level according to on-board battery pack state-of-charge. V2I activates the roadway transmit pads placing them in standby mode and negotiates charging fee based on prevailing grid rate and vehicle energy demand. Dynamic charging would allow electricity to supply a very large fraction of the energy for the transportation sector and reduce greatly petroleum consumption. Previously worrisome traffic delays now provide longer periods of charge while passing over in-motion chargers. Inclement weather such as rain and snow do not affect the charging capability. At ORNL, we are working to develop the robust nature of wireless power technology to provide a convenient, safe and flexible means to charge electric vehicles under stationary and dynamic conditions.

  4. Foil Electron Multiplier

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); Baldonado, Juan R. (Los Alamos, NM); Dors, Eric E. (Los Alamos, NM); Harper, Ronnie W. (Los Alamos, NM); Skoug, Ruth M. (Los Alamos, NM)

    2006-03-28

    An apparatus for electron multiplication by transmission that is designed with at least one foil having a front side for receiving incident particles and a back side for transmitting secondary electrons that are produced from the incident particles transiting through the foil. The foil thickness enables the incident particles to travel through the foil and continue on to an anode or to a next foil in series with the first foil. The foil, or foils, and anode are contained within a supporting structure that is attached within an evacuated enclosure. An electrical power supply is connected to the foil, or foils, and the anode to provide an electrical field gradient effective to accelerate negatively charged incident particles and the generated secondary electrons through the foil, or foils, to the anode for collection.

  5. Integrated Transmission and Distribution Control

    SciTech Connect (OSTI)

    Kalsi, Karanjit; Fuller, Jason C.; Tuffner, Francis K.; Lian, Jianming; Zhang, Wei; Marinovici, Laurentiu D.; Fisher, Andrew R.; Chassin, Forrest S.; Hauer, Matthew L.

    2013-01-16

    Distributed, generation, demand response, distributed storage, smart appliances, electric vehicles and renewable energy resources are expected to play a key part in the transformation of the American power system. Control, coordination and compensation of these smart grid assets are inherently interlinked. Advanced control strategies to warrant large-scale penetration of distributed smart grid assets do not currently exist. While many of the smart grid technologies proposed involve assets being deployed at the distribution level, most of the significant benefits accrue at the transmission level. The development of advanced smart grid simulation tools, such as GridLAB-D, has led to a dramatic improvement in the models of smart grid assets available for design and evaluation of smart grid technology. However, one of the main challenges to quantifying the benefits of smart grid assets at the transmission level is the lack of tools and framework for integrating transmission and distribution technologies into a single simulation environment. Furthermore, given the size and complexity of the distribution system, it is crucial to be able to represent the behavior of distributed smart grid assets using reduced-order controllable models and to analyze their impacts on the bulk power system in terms of stability and reliability. The objectives of the project were to: • Develop a simulation environment for integrating transmission and distribution control, • Construct reduced-order controllable models for smart grid assets at the distribution level, • Design and validate closed-loop control strategies for distributed smart grid assets, and • Demonstrate impact of integrating thousands of smart grid assets under closed-loop control demand response strategies on the transmission system. More specifically, GridLAB-D, a distribution system tool, and PowerWorld, a transmission planning tool, are integrated into a single simulation environment. The integrated environment allows the load flow interactions between the bulk power system and end-use loads to be explicitly modeled. Power system interactions are modeled down to time intervals as short as 1-second. Another practical issue is that the size and complexity of typical distribution systems makes direct integration with transmission models computationally intractable. Hence, the focus of the next main task is to develop reduced-order controllable models for some of the smart grid assets. In particular, HVAC units, which are a type of Thermostatically Controlled Loads (TCLs), are considered. The reduced-order modeling approach can be extended to other smart grid assets, like water heaters, PVs and PHEVs. Closed-loop control strategies are designed for a population of HVAC units under realistic conditions. The proposed load controller is fully responsive and achieves the control objective without sacrificing the end-use performance. Finally, using the T&D simulation platform, the benefits to the bulk power system are demonstrated by controlling smart grid assets under different demand response closed-loop control strategies.

  6. California - Establishing Transmission Project Review Streamlining...

    Open Energy Info (EERE)

    Regulatory Guidance - Supplemental Material: California - Establishing Transmission Project Review Streamlining DirectivesPermittingRegulatory GuidanceSupplemental Material...

  7. Transmission Infrastructure Investment Projects (2009) | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Transmission Infrastructure Investment Projects (2009) More Documents & Publications Financial Institution Partnership Program - Commercial Technology Renewable Energy Generation...

  8. Agenda: Electricity Transmission and Distribution- East

    Broader source: Energy.gov [DOE]

    Quadrennial Energy Review Public Meeting in Newark, NJ. September 8, 2014. Electricity Transmission and Distribution - Eastern Interconnection

  9. Washington/Transmission | Open Energy Information

    Open Energy Info (EERE)

    Avista, Pacificorp, Puget Sound Energy, Tacoma Public Utilities, Bonneville Power Administration, Columbia Grid, Northern Tier Transmission Group, and Seattle City...

  10. Environmental Recommendations for Transmission Planning | Open...

    Open Energy Info (EERE)

    generation resources, energy policies, technology costs, impacts on transmission reliability, and emissions is anticipated to facilitate collaborative and comprehensive...

  11. NREL: Technology Transfer - Commercialization Programs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    303-275-3051. Printable Version Technology Transfer Home About Technology Transfer Technology Partnership Agreements Licensing Agreements Nondisclosure Agreements...

  12. Energy transfer dynamics in trimers and aggregates of light-harvesting

    Office of Scientific and Technical Information (OSTI)

    complex II probed by 2D electronic spectroscopy (Journal Article) | SciTech Connect Energy transfer dynamics in trimers and aggregates of light-harvesting complex II probed by 2D electronic spectroscopy Citation Details In-Document Search Title: Energy transfer dynamics in trimers and aggregates of light-harvesting complex II probed by 2D electronic spectroscopy The pathways and dynamics of excitation energy transfer between the chlorophyll (Chl) domains in solubilized trimeric and

  13. Via Electronic Submission

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Via Electronic Submission January 22, 2015 Mr. David Henderson U.S. Department of Energy Office of Nuclear Energy Mailstop NE-52 19901 Germantown Road Germantown, Maryland 20874-1290 Re: Excess Uranium Management: Effects of DOE Transfers of Excess Uranium on Domestic Uranium Mining, Conversion and Enrichment Industries: Request for Information Dear Mr. Henderson: URENCO USA Inc. ("UUSA, Inc.") appreciates the opportunity to submit comments to assist the Department of Energy (DOE) in

  14. Fuel transfer system

    DOE Patents [OSTI]

    Townsend, Harold E. (Campbell, CA); Barbanti, Giancarlo (Cupertino, CA)

    1994-01-01

    A nuclear fuel bundle fuel transfer system includes a transfer pool containing water at a level above a reactor core. A fuel transfer machine therein includes a carriage disposed in the transfer pool and under the water for transporting fuel bundles. The carriage is selectively movable through the water in the transfer pool and individual fuel bundles are carried vertically in the carriage. In a preferred embodiment, a first movable bridge is disposed over an upper pool containing the reactor core, and a second movable bridge is disposed over a fuel storage pool, with the transfer pool being disposed therebetween. A fuel bundle may be moved by the first bridge from the reactor core and loaded into the carriage which transports the fuel bundle to the second bridge which picks up the fuel bundle and carries it to the fuel storage pool.

  15. Fuel transfer system

    DOE Patents [OSTI]

    Townsend, H.E.; Barbanti, G.

    1994-03-01

    A nuclear fuel bundle fuel transfer system includes a transfer pool containing water at a level above a reactor core. A fuel transfer machine therein includes a carriage disposed in the transfer pool and under the water for transporting fuel bundles. The carriage is selectively movable through the water in the transfer pool and individual fuel bundles are carried vertically in the carriage. In a preferred embodiment, a first movable bridge is disposed over an upper pool containing the reactor core, and a second movable bridge is disposed over a fuel storage pool, with the transfer pool being disposed therebetween. A fuel bundle may be moved by the first bridge from the reactor core and loaded into the carriage which transports the fuel bundle to the second bridge which picks up the fuel bundle and carries it to the fuel storage pool. 6 figures.

  16. National Electric Transmission Congestion Study: Preliminary Findings |

    Office of Environmental Management (EM)

    Department of Energy Study: Preliminary Findings National Electric Transmission Congestion Study: Preliminary Findings The Department hosted three webinars in August 2012 to receive input and suggestions concerning the preliminary findings of the National Electric Transmission Congestion Study. The updated presentation used in the webinars is now available. PDF icon National Electric Transmission Congestion Study: Preliminary Findings - updated presentation More Documents & Publications

  17. Technology Transfer - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PAZ0004_v2.jpg Technology Transfer Who We Are JCAP Mission JCAP At A Glance Fact Sheets Organizational Chart Recent Science Technology Transfer Awards & Honors Senior Management Scientific Leadership Researchers Governance & Advisory Boards Operations & Administration Who we are Overview JCAP Mission JCAP At A Glance Fact Sheets Organizational Chart Our Achievements Recent Science Technology Transfer Awards & Honors Our People Senior Management Scientific Leadership Researchers

  18. Technology Transfer at DOE

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Transfer at DOE Karina Edmonds Technology Transfer Coordinator US Department of Energy March 13, 2012 Goals (As presented 11/2010)  Improve contractual vehicles  Update and streamline WFO and CRADA agreements  Create new opportunities to partner with industry  Inreach  Educate tech transfer offices to improve consistency, streamline processes  Improve relationships with inventors to increase IP captured, manage expectations  Outreach  Develop interagency

  19. Material Transfer Agreements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Material Transfer Agreements Material Transfer Agreements Enables the transfer of tangible consumable research materials between two organizations, when the recipient intends to use the material for research purposes Contact thumbnail of Marcus Lucero Head of Licensing Marcus Lucero Richard P. Feynman Center for Innovation (505) 665-6569 Email Overview The ability to exchange materials freely and without delay is an important part of a healthy scientific laboratory. Los Alamos National

  20. Method for fabricating five-level microelectromechanical structures and microelectromechanical transmission formed

    DOE Patents [OSTI]

    Rodgers, M. Steven (Albuquerque, NM); Sniegowski, Jeffry J. (Edgewood, NM); Miller, Samuel L. (Albuquerque, NM); McWhorter, Paul J. (Albuquerque, NM)

    2000-01-01

    A process for forming complex microelectromechanical (MEM) devices having five layers or levels of polysilicon, including four structural polysilicon layers wherein mechanical elements can be formed, and an underlying polysilicon layer forming a voltage reference plane. A particular type of MEM device that can be formed with the five-level polysilicon process is a MEM transmission for controlling or interlocking mechanical power transfer between an electrostatic motor and a self-assembling structure (e.g. a hinged pop-up mirror for use with an incident laser beam). The MEM transmission is based on an incomplete gear train and a bridging set of gears that can be moved into place to complete the gear train to enable power transfer. The MEM transmission has particular applications as a safety component for surety, and for this purpose can incorporate a pin-in-maze discriminator responsive to a coded input signal.

  1. NREL: Technology Transfer - Contacts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you may have about NREL's technology transfer opportunities. Partnering with NREL Anne Miller, 303-384-7353 Licensing NREL Technologies Eric Payne, 303-275-3166 Printable Version...

  2. Bandwidth and Transfer Activity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Activity Bandwidth and Transfer Activity Data Rate vs. File Size The graph below shows the bandwidth for individual file transfers for one day. The graph also gives a quick overview of the traffic and maximum bandwidth and file size for a given day. Historical yearly peak days. Daily Rate vs. Size Aggregate Transfer Bandwidth This graph shows the aggregate transfer rate to the storage systems as a function of time of day. The red line is the peak bandwidth observed within each one minute

  3. Inverse Energy Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    inertial waves induced by rotation. Rotating stratified turbulence has similar prop- erties 8. The mechanism responsible for the inverse transfer is not understood,...

  4. Pulse shaping with transmission lines

    DOE Patents [OSTI]

    Wilcox, Russell B.

    1987-01-01

    A method and apparatus for forming shaped voltage pulses uses passive reflection from a transmission line with nonuniform impedance. The impedance of the reflecting line varies with length in accordance with the desired pulse shape. A high voltage input pulse is transmitted to the reflecting line. A reflected pulse is produced having the desired shape and is transmitted by pulse removal means to a load. Light activated photoconductive switches made of silicon can be utilized. The pulse shaper can be used to drive a Pockels cell to produce shaped optical pulses.

  5. Pulse shaping with transmission lines

    DOE Patents [OSTI]

    Wilcox, R.B.

    1985-08-15

    A method and apparatus for forming shaped voltage pulses uses passive reflection from a transmission line with nonuniform impedance. The impedance of the reflecting line varies with length in accordance with the desired pulse shape. A high voltage input pulse is transmitted to the reflecting line. A reflected pulse is produced having the desired shape and is transmitted by pulse removal means to a load. Light activated photoconductive switches made of silicon can be utilized. The pulse shaper can be used to drive a Pockels cell to produce shaped optical pulses.

  6. New insight for enhancing photocatalytic activity of MWCNT/TiO{sub 2} by decorating palladium nanoparticles as charge-transfer channel

    SciTech Connect (OSTI)

    Zhang, Feng-Jun; Department of Advanced Materials and Science Engineering, Hanseo University, Seosan-si, Chungnam-do 356-706 ; Oh, Won-Chun; Zhang, Kan; Center for Superfunctional Materials, Department of Chemistry, Pohang University of Science and Technology, Hyojadong, Namgu, Pohang 790-784

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer A new insight for further improving photoactivity of MWCNT/TiO{sub 2} was reported. Black-Right-Pointing-Pointer The Pd as charge transfer channel trap electrons from MWCNT to TiO{sub 2} surface. Black-Right-Pointing-Pointer The Pd content can also influence photoactivity of MWCNT/TiO{sub 2} photocatalyst. Black-Right-Pointing-Pointer The approach is practically usable for other nanocarbon/semiconductor materials. -- Abstract: A surface bond-grafted multi-walled carbon nanotube (MWCNT)/TiO{sub 2} as supporter, palladium nanoparticles, approximately 3 nm in diameter, are uniformly deposited on the functional MWCNT surface in first, constructing a novel Pd-MWCNT/TiO{sub 2} photocatalyst for photocatalytic solar conversion. The characterization of photocatalysts by a series of joint techniques, including BET surface area, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive X-ray (EDX), Raman spectroscopy and ultraviolet/visible (UV/vis) diffuse reflectance spectra, discloses that palladium nanoparticles has a crucial role in enhancement of photocatalytic activity of MWCNT/TiO{sub 2}, that is to act as a charge transfer channel, which helps to trap electrons from MWCNT to TiO{sub 2}.

  7. Comments of New England Electric Transmission Corporation on Proposed Open

    Office of Environmental Management (EM)

    Access Requirement for International Electric Transmission Facilities | Department of Energy New England Electric Transmission Corporation on Proposed Open Access Requirement for International Electric Transmission Facilities Comments of New England Electric Transmission Corporation on Proposed Open Access Requirement for International Electric Transmission Facilities Motion to intervene out of time and comments of New England Electric Transmission Corporation, New England Hydro-Transmission

  8. Automated manual transmission shift sequence controller

    DOE Patents [OSTI]

    Lawrie, Robert E. (Whitmore Lake, MI); Reed, Richard G. (Royal Oak, MI); Rausen, David J. (Denver, CO)

    2000-02-01

    A powertrain system for a hybrid vehicle. The hybrid vehicle includes a heat engine, such as a diesel engine, and an electric machine, which operates as both, an electric motor and an alternator, to power the vehicle. The hybrid vehicle also includes a manual-style transmission configured to operate as an automatic transmission from the perspective of the driver. The engine and the electric machine drive an input shaft which in turn drives an output shaft of the transmission. In addition to driving the transmission, the electric machine regulates the speed of the input shaft in order to synchronize the input shaft during either an upshift or downshift of the transmission by either decreasing or increasing the speed of the input shaft. When decreasing the speed of the input shaft, the electric motor functions as an alternator to produce electrical energy which may be stored by a storage device. Operation of the transmission is controlled by a transmission controller which receives input signals and generates output signals to control shift and clutch motors to effect smooth launch, upshift shifts, and downshifts of the transmission, so that the transmission functions substantially as an automatic transmission from the perspective of the driver, while internally substantially functioning as a manual transmission.

  9. Automated manual transmission mode selection controller

    DOE Patents [OSTI]

    Lawrie, Robert E. (Whitmore Lake, MI)

    1999-11-09

    A powertrain system for a hybrid vehicle. The hybrid vehicle includes a heat engine, such as a diesel engine, and an electric machine, which operates as both an electric motor and an alternator, to power the vehicle. The hybrid vehicle also includes a manual-style transmission configured to operate as an automatic transmission from the perspective of the driver. The engine and the electric machine drive an input shaft which in turn drives an output shaft of the transmission. In addition to driving the transmission, the electric machine regulates the speed of the input shaft in order to synchronize the input shaft during either an upshift or downshift of the transmission by either decreasing or increasing the speed of the input shaft. When decreasing the speed of the input shaft, the electric motor functions as an alternator to produce electrical energy which may be stored by a storage device. Operation of the transmission is controlled by a transmission controller which receives input signals and generates output signals to control shift and clutch motors to effect smooth launch, upshift shifts, and downshifts of the transmission, so that the transmission functions substantially as an automatic transmission from the perspective of the driver, while internally substantially functioning as a manual transmission.

  10. Open Access Transmission and Renewable Energy Technologies

    SciTech Connect (OSTI)

    Porter, K.

    1996-09-01

    In April 1996, the Federal Regulatory Commission (PERC) approved Orders 888 and 889 and released a draft rule for public comment on capacity reservation tariffs (CRTs). Order No. 888 requires electric utilities to file transmission tariffs that would allow transmission access to third parties who want to conduct wholesale transactions, and Order No. 889 requires transmission-owning utilities to set up open access, same-time information systems (OASIS), using commercial software and Internet protocols. This paper discusses these Orders in detail, as well as some of the issues before FERC with implications for renewables, which include: transmission pricing; transmission terms and conditions; reassignment of transmission capacity; defining state and FERC jurisdiction over transmission and distribution; the pricing of ancillary services; and the adoption and implementation of independent system operators.

  11. RAPID/BulkTransmission/Land Access | Open Energy Information

    Open Energy Info (EERE)

    RAPIDBulkTransmissionLand Access < RAPID | BulkTransmission(Redirected from RAPIDBulkTransmissionLeasing) Jump to: navigation, search RAPID Regulatory and Permitting...

  12. RAPID/BulkTransmission/Land Use | Open Energy Information

    Open Energy Info (EERE)

    RAPIDBulkTransmissionLand Use < RAPID | BulkTransmission Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission...

  13. Phase 2 Report: Oahu Wind Integration and Transmission Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase 2 Report: Oahu Wind Integration and Transmission Study (OWITS); Hawaiian Islands Transmission Interconnection Project Phase 2 Report: Oahu Wind Integration and Transmission ...

  14. 2009 Electric Transmission Congestion Study | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2009 Electric Transmission Congestion Study 2009 Electric Transmission Congestion Study The 2009 National Congestion Electric Transmission Study, required by section 216(a) of the...

  15. Comments of New England Electric Transmission Corporation on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New England Electric Transmission Corporation, New England Hydro-Transmission Electric Company, Inc. and New England Hydro-Transmission Corporation and New England Power Company. ...

  16. RAPID/BulkTransmission/Water Use | Open Energy Information

    Open Energy Info (EERE)

    RAPIDBulkTransmissionWater Use < RAPID | BulkTransmission Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission...

  17. RAPID/BulkTransmission/Air Quality | Open Energy Information

    Open Energy Info (EERE)

    BulkTransmissionAir Quality < RAPID | BulkTransmission Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission...

  18. Transfer Activity Last 8 Days

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Activity Last 8 Days Transfer Activity Last 8 Days These graphs show the transfer activity statistics for the past eight days with the most recent day shown first. BE CAREFUL because the graphs are autoscaling - check the scales on each axis before you compare graphs. Transfers started/in progress (Both Systems) Transfers started/in progress (Both Systems) Transfers started/in progress (Both Systems) Transfers started/in progress (Both Systems) Transfers started/in progress (Both Systems)

  19. Shock transmissibility of threaded joints

    SciTech Connect (OSTI)

    Hansen, N.R.; Bateman, V.I.; Brown, F.A.

    1996-12-31

    Sandia National Laboratories (SNL) designs mechanical systems with threaded joints that must survive high shock environments. These mechanical systems include penetrators that must survive soil and rock penetration; drilling pipe strings that must survive rock-cutting, shock environments; and laydown weapons that must survive delivery impact shock. This paper summarizes an analytical study and an experimental evaluation of compressive, one-dimensional, shock transmission through a threaded joint in a split Hopkinson bar configuration. Thread geometries were scaled to simulate large diameter threaded joints with loadings parallel to the axis of the threads. Both strain and acceleration were evaluated with experimental measurements and analysis. Analytical results confirm the experimental conclusions that in this split Hopkinson bar configuration, the change in the one-dimensional shock wave by the threaded joint is localized to a length equal to a few diameters` length beyond the threaded joint.

  20. Superconducting transmission line particle detector

    DOE Patents [OSTI]

    Gray, Kenneth E. (Naperville, IL)

    1989-01-01

    A microvertex particle detector for use in a high energy physic collider including a plurality of parallel superconducting thin film strips separated from a superconducting ground plane by an insulating layer to form a plurality of superconducting waveguides. The microvertex particle detector indicates passage of a charged subatomic particle by measuring a voltage pulse measured across a superconducting waveguide caused by the transition of the superconducting thin film strip from a superconducting to a non-superconducting state in response to the passage of a charged particle. A plurality of superconducting thin film strips in two orthogonal planes plus the slow electromagnetic wave propogating in a superconducting transmission line are used to resolve N.sup.2 ambiguity of charged particle events.

  1. Superconducting transmission line particle detector

    DOE Patents [OSTI]

    Gray, K.E.

    1988-07-28

    A microvertex particle detector for use in a high energy physic collider including a plurality of parallel superconducting thin film strips separated from a superconducting ground plane by an insulating layer to form a plurality of superconducting waveguides. The microvertex particle detector indicates passage of a charged subatomic particle by measuring a voltage pulse measured across a superconducting waveguide caused by the transition of the superconducting thin film strip from a superconducting to a non- superconducting state in response to the passage of a charged particle. A plurality of superconducting thin film strips in two orthogonal planes plus the slow electromagnetic wave propagating in a superconducting transmission line are used to resolve N/sup 2/ ambiguity of charged particle events. 6 figs.

  2. 2006 Final Transmission Proposal: Revenue Requirements Study.

    SciTech Connect (OSTI)

    United States. Bonneville Power Administration.

    2005-06-01

    The purpose of the Revenue Requirement Study (Study) is to establish the level of revenues needed from rates for Bonneville Power Administration's (BPA's) transmission and ancillary services to recover, in accordance with sound business principles, costs associated with the transmission of electric power over the Federal Columbia River Transmission System (FCRTS). The FCRTS is part of the larger Federal Columbia River Power System (FCRPS) which also includes the hydroelectric, multipurpose facilities constructed and operated by the U.S. Army Corps of Engineers and the Bureau of Reclamation in the Pacific Northwest. The FCRPS costs that are not included in the FCRTS costs are funded and repaid through BPA power rates. The transmission revenue requirements herein include: recovery of the Federal investment in transmission and transmission-related assets; the operations and maintenance (O&M) and other annual expenses associated with the provision of transmission and ancillary services; the cost of generation inputs for ancillary services and other between business-line services necessary for the transmission of power; and all other transmission-related costs incurred by the Administrator. The cost evaluation period for this rate proposal includes Fiscal Years (FYs) 2005-2007, the period extending from the last year for which historical information is available through the proposed rate test period. The Study includes the transmission revenue requirements for the rate test period, FYs 2006-2007 (Rate Period) and the results of transmission repayment studies. This Study outlines the policies, forecasts, assumptions, and calculations used to determine BPA's transmission revenue requirements. Legal requirements are summarized in Chapter 5 of this Study. The Revenue Requirement Study Documentation (Documentation), TR-06-FS-BPA-01A, contains key technical assumptions and calculations, the results of the transmission repayment studies, and a further explanation of the repayment inputs and its outputs.

  3. Theoretical analysis of sound transmission loss through graphene sheets

    SciTech Connect (OSTI)

    Natsuki, Toshiaki; Ni, Qing-Qing

    2014-11-17

    We examine the potential of using graphene sheets (GSs) as sound insulating materials that can be used for nano-devices because of their small size, super electronic, and mechanical properties. In this study, a theoretical analysis is proposed to predict the sound transmission loss through multi-layered GSs, which are formed by stacks of GS and bound together by van der Waals (vdW) forces between individual layers. The result shows that the resonant frequencies of the sound transmission loss occur in the multi-layered GSs and the values are very high. Based on the present analytical solution, we predict the acoustic insulation property for various layers of sheets under both normal incident wave and acoustic field of random incidence source. The scheme could be useful in vibration absorption application of nano devices and materials.

  4. Proton transfer in nucleobases is mediated by water

    SciTech Connect (OSTI)

    Khistyaev, Kirill; Golan, Amir; Bravaya, Ksenia B.; Orms, Natalie; Krylov, Anna I.; Ahmed, Musahid

    2013-04-29

    Water plays a central role in chemistry and biology by mediating the interactions between molecules, altering energy levels of solvated species, modifying potential energy proles along reaction coordinates, and facilitating ecient proton transport through ion channels and interfaces. This study investigates proton transfer in a model system comprising dry and microhydrated clusters of nucleobases. With mass spectrometry and tunable vacuum ultraviolet synchrotron radiation, we show that water shuts down ionization-induced proton transfer between nucleobases, which is very ecient in dry clusters. Instead, a new pathway opens up in which protonated nucleo bases are generated by proton transfer from the ionized water molecule and elimination of a hydroxyl radical. Electronic structure calculations reveal that the shape of the potential energy prole along the proton transfer coordinate depends strongly on the character of the molecular orbital from which the electron is removed, i.e., the proton transfer from water to nucleobases is barrierless when an ionized state localized on water is accessed. The computed energetics of proton transfer is in excellent agreement with the experimental appearance energies. Possible adiabatic passage on the ground electronic state of the ionized system, while energetically accessible at lower energies, is not ecient. Thus, proton transfer is controlled electronically, by the character of the ionized state, rather than statistically, by simple energy considerations.

  5. Technology transfer 1994

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    This document, Technology Transfer 94, is intended to communicate that there are many opportunities available to US industry and academic institutions to work with DOE and its laboratories and facilities in the vital activity of improving technology transfer to meet national needs. It has seven major sections: Introduction, Technology Transfer Activities, Access to Laboratories and Facilities, Laboratories and Facilities, DOE Office, Technologies, and an Index. Technology Transfer Activities highlights DOE`s recent developments in technology transfer and describes plans for the future. Access to Laboratories and Facilities describes the many avenues for cooperative interaction between DOE laboratories or facilities and industry, academia, and other government agencies. Laboratories and Facilities profiles the DOE laboratories and facilities involved in technology transfer and presents information on their missions, programs, expertise, facilities, and equipment, along with data on whom to contact for additional information on technology transfer. DOE Offices summarizes the major research and development programs within DOE. It also contains information on how to access DOE scientific and technical information. Technologies provides descriptions of some of the new technologies developed at DOE laboratories and facilities.

  6. Revenue reconciled optimum pricing of transmission services

    SciTech Connect (OSTI)

    Perera, B.L.P.P.; Farmer, E.D.; Cory, B.J.

    1996-08-01

    This paper describes a methodology for evaluating an optimal set of transmission prices, to be charged for use of a transmission system on a time-of-use basis. The transmission prices are determined by maximizing the global benefit of using the transmission system that allocates both capacity and operational costs. The security considerations are explicitly taken into account by incorporating security factors in the algorithm. The important issue of revenue recovery by the transmission utility is addressed by modifying the optimum prices without affecting the consumer behavior. This can be achieved by setting the prices within indifference intervals over which consumers are insensitive to transmission prices. Application of the methodology is illustrated on the IEEE 24 bus test system.

  7. SunZia Southwest Transmission Project Comments

    Broader source: Energy.gov (indexed) [DOE]

    SunZia Southwest Transmission Project Comments Provided to the US Department of Energy Office of Electricity Delivery and Energy Reliability Request for Information Relating to the Permitting of Transmission Lines Submitted as of March 28, 2012 2 1.0 Background. SunZia Southwest Transmission Project (SunZia or the Project) is a joint development effort currently underway in Arizona and New Mexico. The Project definition includes licensing, permitting, financing, constructing and operating up to

  8. National Electric Transmission Congestion Study - Philadelphia Workshop |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Philadelphia Workshop National Electric Transmission Congestion Study - Philadelphia Workshop On December 6, 2011, DOE hosted a regional pre-study workshop in Philadelphia, PA to receive input and suggestions concerning the National Electric Transmission Congestion Study. The workshop flyer, agenda, presentations, and full transcript are available below. PDF icon National Electric Transmission Congestion Study Eastern Workshops PDF icon 12-06-11 Congestion Workshop

  9. NREL: Transmission Grid Integration - Research Staff

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Staff NREL's transmission and grid integration research staff work to incorporate renewable energy into the transmission system primarily through NREL's Power Systems Engineering Center. Photo of Barbara O'Neill Barbara O'Neill, Transmission and Grid Integration Group Manager M.S., Energy Management and Policy, University of Pennsylvania Engineering Diploma, Petroleum Economics and Management, French Institute of Petroleum B.S., Electrical Engineering, Pratt Institute Barbara has a

  10. RRTT - Rapid Response Team for Transmission

    Energy Savers [EERE]

    Rapid Response Team- Transmission Exploring the Business Link Opportunity: Transmission & Clean Energy Development in the West TRIBAL LEADER FORUM SERIES February 7, 2012 Laura Smith Morton Department of Energy Laura.morton@hq.doe.gov Nine Agency MOU * Improves uniformity, consistency, and transparency - Establishes the roles and responsibilities of the nine signatory agencies regarding electric transmission infrastructure project applicants * Provides single point of contact for

  11. TRIDEC Land TRIDEC Land Transfer REQUEST Transfer REQUEST

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area TRIDEC Land TRIDEC Land Transfer REQUEST Transfer REQUEST 300 Acres 300 Acres Additional Lands Additional Lands Identified for Identified for EA Analysis EA Analysis 2,772...

  12. NREL: Technology Transfer - Webmaster

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Webmaster To report any problems on or ask a question about the NREL Technology Transfer Web site, you may contact the Webmaster using the online form below. If you have a question...

  13. Data Transfer Nodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to data transfer of some form or fashion. Examples of intended usage would be running python scripts to download data from a remote source, running client software to load data...

  14. Electricity Transmission, A Primer | Open Energy Information

    Open Energy Info (EERE)

    LibraryAdd to library Report: Electricity Transmission, A Primer Authors Matthew H. Brown, National Conference of State Legislatures, Richard P. Sedano and The Regulatory...

  15. State action in regional transmission groups

    SciTech Connect (OSTI)

    Rokach, J.Z.

    1994-12-01

    States should participate in coordinated transmission planning through regional transmission groups, while reserving their right to pass upon transmission planning. This would smooth an otherwise difficult transition, as FERC and state regulators seek to facilitate a competitive bulk power market that ignores arbitrary jurisdiction lines. Since the Federal Energy Regulatory Commission issued its Policy Statement on Regional Transmission Groups, two RTG`s, the Western Regional Transmission Association and the Southwest Regional Transmission Association, have gained conditional approval from FERC. A third, the Northwest Regional Transmission Association, files its governing agreement with the Commission, seeking FERC`s approval. Price setting within RTGs and information exchanges involved in planning the grid raise questions of the legality of these collective actions under the antitrust laws. All three agreements allow for exchanges of commercial and planning information, but, conspicuously, do not set transmission prices. For the moment, therefore, antitrust liability for RTGs would arise out of the information exchanges involved in planning the grid. In addition, with FERC pushing for `restructuring` at the wholesale level through open access and the states becoming aggressive in trying to institute competition at the consumer level through retail wheeling, issues of federal-state jurisdiction in transmission have come to the fore.

  16. Transmission Services Commercial Systems Support and Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Call Agenda This customer conference call will provide updates concerning BPA Transmission Services' commercial systems support and development efforts. It will also provide...

  17. Transmission Line Security Monitor: Final Report

    SciTech Connect (OSTI)

    John Svoboda

    2011-04-01

    The Electric Power Transmission Line Security Monitor System Operational Test is a project funded by the Technical Support Working Group (TSWG). TSWG operates under the Combating Terrorism Technical Support Office that functions under the Department of Defense. The Transmission Line Security Monitor System is based on technology developed by Idaho National Laboratory. The technology provides a means for real-time monitoring of physical threats and/or damage to electrical transmission line towers and conductors as well as providing operational parameters to transmission line operators to optimize transmission line operation. The end use is for monitoring long stretches of transmission lines that deliver electrical power from remote generating stations to cities and industry. These transmission lines are generally located in remote transmission line corridors where security infrastructure may not exist. Security and operational sensors in the sensor platform on the conductors take power from the transmission line and relay security and operational information to operations personnel hundreds of miles away without relying on existing infrastructure. Initiated on May 25, 2007, this project resulted in pre-production units tested in realistic operational environments during 2010. A technology licensee, Lindsey Manufacturing of Azusa California, is assisting in design, testing, and ultimately production. The platform was originally designed for a security monitoring mission, but it has been enhanced to include important operational features desired by electrical utilities.

  18. Southline Transmission Line | Open Energy Information

    Open Energy Info (EERE)

    Analysis Type EIS Applicant Southline Transmission, LLC, a subsidiary of Hunt Power L.P. Consultant SWCA Environmental Consultants Geothermal Area Project Location Project...

  19. State Generation & Transmission Siting Directory | Open Energy...

    Open Energy Info (EERE)

    Directory Jump to: navigation, search OpenEI Reference LibraryAdd to library General: State Generation & Transmission Siting Directory Abstract A guide of generation and...

  20. State Strategies for Accelerating Transmission Development for...

    Open Energy Info (EERE)

    Strategies for Accelerating Transmission Development for Renewable Energy Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: State Strategies for...

  1. RAPID/Geothermal/Transmission Siting & Interconnection | Open...

    Open Energy Info (EERE)

    to the public for compensation. See AS 42.05.990(5) for additional information. NA Geothermal Transmission Siting & Interconnection in California California Energy...

  2. Detonator comprising a nonlinear transmission line

    DOE Patents [OSTI]

    Elizondo-Decanini, Juan M

    2014-12-30

    Detonators are described herein. In a general embodiment, the detonator includes a nonlinear transmission line that has a variable capacitance. Capacitance of the nonlinear transmission line is a function of voltage on the nonlinear transmission line. The nonlinear transmission line receives a voltage pulse from a voltage source and compresses the voltage pulse to generate a trigger signal. Compressing the voltage pulse includes increasing amplitude of the voltage pulse and decreasing length of the voltage pulse in time. An igniter receives the trigger signal and detonates an explosive responsive to receipt of the trigger signal.

  3. RAPID/BulkTransmission | Open Energy Information

    Open Energy Info (EERE)

    regulatory processes and requirements by searching our regulatory flowchart library. Learn more about bulk transmission. BulkTransCoverage.png Regulations and permitting...

  4. SunZia Southwest Transmission Project Comments

    Broader source: Energy.gov (indexed) [DOE]

    Transmission Project Comments Provided to the US Department of Energy Office of Electricity Delivery and Energy Reliability Request for Information Relating to the Permitting...

  5. Northern Pass Transmission Line Project Environmental Impact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Northern Pass Transmission Line Project Environmental Impact Statement: Announcement of Change in Public Meeting Location: Federal Register Notice Volume 78, No. 181 - September ...

  6. EEI/DOE Transmission Capacity Report

    Broader source: Energy.gov (indexed) [DOE]

    ... The data show a continuation of past trends. Specifically, transmission capacity is being ... 1978 through 2012. These results show trends over time at the national and regional ...

  7. Briefing Memo: Petroleum Product Transmission & Distribution...

    Broader source: Energy.gov (indexed) [DOE]

    PDF of the briefing memo. Briefing Memo More Documents & Publications Briefing Memo: Petroleum Product Transmission & Distribution The Quadrennial Energy Review (Full Report)...

  8. Transmission Services Commercial Systems Support and Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Commercial Systems Support and Development Customer Conference Call Agenda This customer conference call will provide updates concerning BPA Transmission Services' commercial...

  9. Transmission/Resource Library | Open Energy Information

    Open Energy Info (EERE)

    electric transmission systems, including in-depth discussion direct current, below-ground, and high-temperature superconductor lines. Includes sections on design features as...

  10. National Electric Transmission Congestion Study Webinars | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to present the preliminary findings of DOE's National Electric Transmission Congestion Study, with time in each for dialogue and discussion. Two of the webinars were to discuss...

  11. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Eastern Interconnection on Electric Resource...

  12. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Western Interconnection on Electric Resource...

  13. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis and Planning Interconnection-Wide Transmission Planning Initiative: Topic A, Interconnection-Level Analysis and Planning A description of the requirements for...

  14. Transmission Reliability Program 2015 Reliability & Markets Peer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program 2015 Reliability & Markets Peer Review Materials Available Transmission Reliability Program 2015 Reliability & Markets Peer Review Materials Available September 16, 2015 -...

  15. NREL: Transmission Grid Integration Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    insolation. This variability affects how transmission systems with high penetrations of renewable energy sources operate. NREL researchers are identifying these effects and...

  16. Generation and Transmission Maximization Model | Open Energy...

    Open Energy Info (EERE)

    its limited energy and transmission resources, but also firm contracts, independent power producer (IPP) agreements, and bulk power transaction opportunities on the spot...

  17. ETrans Federal Permitting Transmission Tracking System | Open...

    Open Energy Info (EERE)

    More recently, the Rapid Response Team for Transmission (RRTT) was created, which extends activity outside of federal lands. This website hosts a tracking system and search feature...

  18. Transmission Reassignment Reporting Requirement - April 2, 2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    capacity reassignments, including but not limited to pricing information, on BPA's Open Access Same-Time Information System (OASIS). Customers reassigning transmission...

  19. Wyoming/Transmission | Open Energy Information

    Open Energy Info (EERE)

    Lower Valley Energy, High West Energy, Western Area Power Administration, Bonneville Power Administration, Tri-State Generation and Transmission Association, Inc., and Rocky...

  20. California/Transmission | Open Energy Information

    Open Energy Info (EERE)

    San Diego Gas & Electric, Sacramento Municipal Utility District, PacifiCorp, Bonneville Power Administration, Transmission Agency of Northern California, and Western Area Power...

  1. Nevada/Transmission | Open Energy Information

    Open Energy Info (EERE)

    own transmission facilities in the State of Nevada: NV Energy, Bonneville Power Administration, and Valley Electric Association, Colorado River Commission, Los...

  2. Oregon/Transmission | Open Energy Information

    Open Energy Info (EERE)

    Electric Cooperative, Columbia Grid, Northern Tier Transmission Group, and Bonneville Power Administration. Oregon Energy Policy The Oregon Department of Energy's Governor's...

  3. Proponent's Environmental Assessment (PEA) Checklist for Transmission...

    Open Energy Info (EERE)

    Proponent's Environmental Assessment (PEA) Checklist for Transmission Line and Substation Projects Jump to: navigation, search OpenEI Reference LibraryAdd to library Permitting...

  4. Reminder: Transmission Services Product Pricing Validation -...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Teams Customer Training Interconnection Notices Rates Standards of Conduct Tariff TF Web Based Training Notice: Reminder: Transmission Services Product Pricing Validation This...

  5. Transmission Services Product Pricing Validation - September...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Teams Customer Training Interconnection Notices Rates Standards of Conduct Tariff TF Web Based Training Notice: Transmission Services Product Pricing Validation On October 1,...

  6. Coordination of Federal Authorizations for Electric Transmission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coordination of Federal Authorizations for Electric Transmission Facilities: Federal Register Notice Volume 73, No. 183 - Sep. 19, 2008 Coordination of Federal Authorizations for...

  7. Category:NEPA Transmission | Open Energy Information

    Open Energy Info (EERE)

    Pages in category "NEPA Transmission" This category contains only the following page. T TransWest Retrieved from "http:en.openei.orgwindex.php?titleCategory:NEPATransmiss...

  8. Renewable Energy Transmission Roadmap | Open Energy Information

    Open Energy Info (EERE)

    Roadmap Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Renewable Energy Transmission Roadmap Abstract Renewable energy is becoming an...

  9. Template:Nepa Transmission | Open Energy Information

    Open Energy Info (EERE)

    General NEPA Document Information TransmissionType - Energy Sector (e.g. Geothermal, Solar, Wind) (page: Category:ElectricityGeneratingTechnologies) EnvironmentalAnalysisTyp...

  10. Supervisory Transmission Lines and Substation Maintenance Manager

    Broader source: Energy.gov [DOE]

    (See Frequently Asked Questions for more information). Where would I be working? Western Area Power Administration Desert Southwest Region Transmission Lines and Substation Maintenance (G5200) 615...

  11. Richard Shaheen named Senior VP of Transmission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transmission lines and initiated upgrades to Celilo Substation and the Pacific Direct Current Intertie. "Richard is an excellent leader, and his 25-plus years of experience at a...

  12. Nevada Transmission Siting Information | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: Nevada Transmission Siting InformationPermittingRegulatory GuidanceGuide...

  13. Articles about Grid Integration and Transmission | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    about grid integration and transmission featured by the U.S. Department of Energy (DOE) Wind Program. September 16, 2015 Argonne National Laboratory Develops New Model to Quantify...

  14. Especial Gear Transmissions EGT | Open Energy Information

    Open Energy Info (EERE)

    EGT Jump to: navigation, search Name: Especial Gear Transmissions (EGT) Place: Spain Sector: Wind energy Product: Designs, manufactures and repairs industrial wind gear reducers...

  15. Recovery Act Interconnection Transmission Planning | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    resource and transmission planning studies in 2011, with updated documents in 2013. The knowledge and perspective gained from this work will inform policy and regulatory...

  16. Memorandum of Understanding Regarding Transmission Siting on...

    Open Energy Info (EERE)

    Transmission Siting on Federal Land (2006)Legal Author Federal Agencies Organizations United States Department of Energy, United States Department of Defense, United States...

  17. Microsoft Word - 20140522 Petroleum Transmission Storage and...

    Broader source: Energy.gov (indexed) [DOE]

    ... Perhaps foremost was the interdependency of liquids transmission and electrical generation. Widespread power outages, coupled with reliance of the fuel pumping facilities and ...

  18. NREL: Technology Transfer - Ombuds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology Transfer Ombuds NREL's Technology Transfer Ombuds offers an informal process to help resolve issues and concerns regarding the laboratory's technology partnership, patent, and licensing activities. As a designated neutral party, our ombuds provides confidential, resolution-focused services. Through the ombuds process, we encourage collaborative techniques such as mediation to facilitate the speedy and low-cost resolution of complaints and disputes, when appropriate. The NREL Ombuds

  19. PP-230-1 International Transmission Company | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 International Transmission Company PP-230-1 International Transmission Company Presidential permit authorizing British Columbia Electric Company, Limited to construct, operate, and maintain electric transmission facilities at the U.S-Canadian border. PDF icon PP-230-1 International Transmission Company More Documents & Publications PP-230-2 International Transmission Company PP-230 International Transmission Company PP-221 Detroit Edison Company

  20. Transmission mode terahertz computed tomography

    DOE Patents [OSTI]

    Ferguson, Bradley Stuart; Wang, Shaohong; Zhang, Xi-Cheng

    2006-10-10

    A method of obtaining a series of images of a three-dimensional object by transmitting pulsed terahertz (THz) radiation through the entire object from a plurality of angles, optically detecting changes in the transmitted THz radiation using pulsed laser radiation, and constructing a plurality of imaged slices of the three-dimensional object using the detected changes in the transmitted THz radiation. The THz radiation is transmitted through the object as a scanning spot. The object is placed within the Rayleigh range of the focused THz beam and a focusing system is used to transfer the imaging plane from adjacent the object to a desired distance away from the object. A related system is also disclosed.

  1. Application for Presidential Permit OE Docket No. PP-230-4 International Transmission Company: Letter from New York Transmission Owners

    Broader source: Energy.gov [DOE]

    Application from International Transmission Company to construct, operate, and maintain electric transmission facilities at the U.S. - Canada border.

  2. Electroweak nuclear response at moderate momentum transfer

    SciTech Connect (OSTI)

    Ankowski, Artur M.; Benhar, Omar

    2011-05-15

    We discuss the convergence of the expansion of the nuclear electroweak current in powers of |k|/M, where M is the nucleon mass and k denotes either the momentum transfer or the momentum of the struck nucleon. We have computed the electron and neutrino scattering cross sections off uniform nuclear matter at equilibrium density using correlated wave functions and the cluster expansion formalism. The results of our work suggest that the proposed approach provides accurate estimates of the measured electron scattering cross sections. On the other hand, the description of the current based on the widely used leading-order approximation does not appear to be adequate, even at momentum transfer as low as 300 MeV.

  3. Generation and Transmission Maximization Model

    Energy Science and Technology Software Center (OSTI)

    2001-04-05

    GTMax was developed to study complex marketing and system operational issues facing electric utility power systems. The model maximizes the value of the electric system taking into account not only a single system''s limited energy and transmission resources but also firm contracts, independent power producer (IPP) agreements, and bulk power transaction opportunities on the spot market. GTMax maximizes net revenues of power systems by finding a solution that increases income while keeping expenses at amore » minimum. It does this while ensuring that market transactions and system operations are within the physical and institutional limitations of the power system. When multiple systems are simulated, GTMax identifies utilities that can successfully compete on the market by tracking hourly energy transactions, costs, and revenues. Some limitations that are modeled are power plant seasonal capabilities and terms specified in firm and IPP contracts. GTMax also considers detaile operational limitations such as power plant ramp rates and hydropower reservoir constraints.« less

  4. Transferring Data from Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transferring Data from Batch Jobs Transferring Data from Batch Jobs Examples Once you are set up for automatic authentication (see HPSS Passwords) you can access HPSS within batch...

  5. Ames Lab 101: Technology Transfer

    ScienceCinema (OSTI)

    Covey, Debra

    2012-08-29

    Ames Laboratory Associate Laboratory Director, Sponsored Research Administration, Debra Covey discusses technology transfer. Covey also discusses Ames Laboratory's most successful transfer, lead-free solder.

  6. Ombuds Services for Technology Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ombuds Program Tech Transfer Ombuds Ombuds Services for Technology Transfer Committed to the fair and equitable treatment of all employees, contractors, and persons doing...

  7. Early results of microwave transmission experiments through an overly dense rectangular plasma sheet with microparticle injection

    SciTech Connect (OSTI)

    Gillman, Eric D.; Amatucci, W. E.

    2014-06-15

    These experiments utilize a linear hollow cathode to create a dense, rectangular plasma sheet to simulate the plasma layer surrounding vehicles traveling at hypersonic velocities within the Earth's atmosphere. Injection of fine dielectric microparticles significantly reduces the electron density and therefore lowers the electron plasma frequency by binding a significant portion of the bulk free electrons to the relatively massive microparticles. Measurements show that microwave transmission through this previously overly dense, impenetrable plasma layer increases with the injection of alumina microparticles approximately 60 ?m in diameter. This method of electron depletion is a potential means of mitigating the radio communications blackout experienced by hypersonic vehicles.

  8. Ecological benefits of dc power transmission

    SciTech Connect (OSTI)

    Kutuzova, N. B.

    2011-05-15

    The environmental effects of dc overhead transmission lines are examined. The major effects of ac and dc transmission lines are compared. Dc lines have advantages compared to ac lines in terms of electrical safety for people under the lines, biological effects, corona losses, and clearance width.

  9. Electricity Transmission and Distribution Technologies Available for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Licensing - Energy Innovation Portal Electricity Transmission Site Map Printable Version Share this resource About Search Categories (15) Advanced Materials Biomass and Biofuels Building Energy Efficiency Electricity Transmission Marketing Summaries (70) Success Stories (2) Energy Analysis Energy Storage Geothermal Hydrogen and Fuel Cell Hydropower, Wave and Tidal Industrial Technologies Solar Photovoltaic Solar Thermal Startup America Vehicles and Fuels Wind Energy Partners (27) Visual

  10. Catching the role of anisotropic electronic distribution and charge

    Office of Scientific and Technical Information (OSTI)

    transfer in halogen bonded complexes of noble gases (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Catching the role of anisotropic electronic distribution and charge transfer in halogen bonded complexes of noble gases Citation Details In-Document Search Title: Catching the role of anisotropic electronic distribution and charge transfer in halogen bonded complexes of noble gases The systems studied in this work are gas-phase weakly bound adducts of the

  11. Conductive Channel for Energy Transmission

    SciTech Connect (OSTI)

    Apollonov, Victor V. [A.M. Prokhorov General Physics Institute, Vavilov Str. 38, Moscow, 119991 (Russian Federation)

    2011-11-10

    For many years the attempts to create conductive channels of big length were taken in order to study the upper atmosphere and to settle special tasks, related to energy transmission. There upon the program of creation of 'Impulsar' represents a great interest, as this program in a combination with high-voltage high repetition rate electrical source can be useful to solve the above mentioned problems (N. Tesla ideas for the days of high power lasers). The principle of conductive channel production can be shortly described as follows. The 'Impulsar' - laser jet engine vehicle - propulsion take place under the influence of powerful high repetition rate pulse-periodic laser radiation. In the experiments the CO{sub 2}-laser and solid state Nd:YAG laser systems had been used. Active impulse appears thanks to air breakdown (<30 km) or to the breakdown of ablated material on the board (>30 km), placed in the vicinity of the focusing mirror-acceptor of the breakdown waves. With each pulse of powerful laser the device rises up, leaving a bright and dense trace of products with high degree of ionization and metallization by conductive nano-particles due to ablation. Conductive dust plasma properties investigation in our experiments was produced by two very effective approaches: high power laser controlled ablation and by explosion of wire. Experimental and theoretical results of conductive canal modeling will be presented. The estimations show that with already experimentally demonstrated figures of specific thrust impulse the lower layers of the Ionosphere can be reached in several ten seconds that is enough to keep the high level of channel conductivity and stability with the help of high repetition rate high voltage generator. Some possible applications for new technology are highlighted.

  12. Supervisory Electronics Engineer

    Broader source: Energy.gov [DOE]

    This position is located in an Operations and Maintenance (O&M;) District under one of the three Senior O&M; Managers, Transmission Field Services (TF), Transmission Services. Transmission...

  13. Dynamic imaging with electron microscopy

    ScienceCinema (OSTI)

    Campbell, Geoffrey; McKeown, Joe; Santala, Melissa

    2014-05-30

    Livermore researchers have perfected an electron microscope to study fast-evolving material processes and chemical reactions. By applying engineering, microscopy, and laser expertise to the decades-old technology of electron microscopy, the dynamic transmission electron microscope (DTEM) team has developed a technique that can capture images of phenomena that are both very small and very fast. DTEM uses a precisely timed laser pulse to achieve a short but intense electron beam for imaging. When synchronized with a dynamic event in the microscope's field of view, DTEM allows scientists to record and measure material changes in action. A new movie-mode capability, which earned a 2013 R&D 100 Award from R&D Magazine, uses up to nine laser pulses to sequentially capture fast, irreversible, even one-of-a-kind material changes at the nanometer scale. DTEM projects are advancing basic and applied materials research, including such areas as nanostructure growth, phase transformations, and chemical reactions.

  14. Consumer Electronics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Events Expand News & Events Skip navigation links Residential Residential Lighting Energy Star Appliances Consumer Electronics Heat Pump Water Heaters Electric Storage Water...

  15. PP-230 International Transmission Company | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    International Transmission Company PP-230 International Transmission Company Presidential permit authorizing International Transmission Company to construct, operate, and maintain electric transmission facilities at the U.S-Canadian border. PDF icon PP-230 International Transmission Company More Documents & Publications PP-230-2 International Transmission Company Application for presidential permit OE Docket No. PP-230-4 International Transmission Company: Federal Register Notice Volume 74,

  16. PP-230-2 International Transmission Company | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 International Transmission Company PP-230-2 International Transmission Company Presidential permit authorizing International Transmission Company to construct, operate, and maintain electric transmission facilities at the U.S-Canadian border. PDF icon PP-230-2 International Transmission Company More Documents & Publications PP-230 International Transmission Company Application for presidential permit OE Docket No. PP-230-4 International Transmission Company: Federal Register Notice Volume

  17. VOLUNTARY LEAVE TRANSFER PROGRAM

    Office of Environmental Management (EM)

    VOLUNTARY LEAVE TRANSFER PROGRAM (Eligible employees are listed at the end of this narrative) Under the Voluntary Leave Transfer Program you can apply, based on a medical emergency, to receive annual leave donated by other employees. A medical emergency is generally defined as a medical condition of the employee or family member that is likely to keep you (the employee) away from work and cause a loss of pay of at least 24 hours. You are required to submit an Office of Personnel Management (OPM)

  18. VOLUNTARY LEAVE TRANSFER PROGRAM

    Broader source: Energy.gov (indexed) [DOE]

    VOLUNTARY LEAVE TRANSFER PROGRAM (Eligible employees are listed at the end of this narrative) Under the Voluntary Leave Transfer Program you can apply, based on a medical emergency, to receive annual leave donated by other employees. A medical emergency is generally defined as a medical condition of the employee or family member that is likely to keep you (the employee) away from work and cause a loss of pay of at least 24 hours. You are required to submit an Office of Personnel Management (OPM)

  19. VOLUNTARY LEAVE TRANSFER PROGRAM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    VOLUNTARY LEAVE TRANSFER PROGRAM (Eligible employees are listed at the end of this narrative) Under the Voluntary Leave Transfer Program you can apply, based on a medical emergency, to receive annual leave donated by other employees. A medical emergency is generally defined as a medical condition of the employee or family member that is likely to keep you (the employee) away from work and cause a loss of pay of at least 24 hours. You are required to submit an Office of Personnel Management (OPM)

  20. Transfer Activity Historical Yearly Peak

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Activity Historical Yearly Peak Transfer Activity Historical Yearly Peak The plots below show the yearly peak days from 2000 to the present. BE CAREFUL because the graphs are autoscaling - check the scales on each axis before you compare graphs. Note that the graph for the current year shows the data for the year-to-date peak. Transfers Started/In Progress Transfers Started/In Progress Transfers Started/In Progress Transfers Started/In Progress Transfers Started/In Progress Transfers Started/In

  1. Detailed high-accuracy megavoltage transmission measurements: A sensitive experimental benchmark of EGSnrc

    SciTech Connect (OSTI)

    Ali, E. S. M.; McEwen, M. R.; Rogers, D. W. O.

    2012-10-15

    Purpose: There are three goals for this study: (a) to perform detailed megavoltage transmission measurements in order to identify the factors that affect the measurement accuracy, (b) to use the measured data as a benchmark for the EGSnrc system in order to identify the computational limiting factors, and (c) to provide data for others to benchmark Monte Carlo codes. Methods: Transmission measurements are performed at the National Research Council Canada on a research linac whose incident electron parameters are independently known. Automated transmission measurements are made on-axis, down to a transmission value of {approx}1.7%, for eight beams between 10 MV (the lowest stable MV beam on the linac) and 30 MV, using fully stopping Be, Al, and Pb bremsstrahlung targets and no fattening filters. To diversify energy differentiation, data are acquired for each beam using low-Z and high-Z attenuators (C and Pb) and Farmer chambers with low-Z and high-Z buildup caps. Experimental corrections are applied for beam drifts (2%), polarity (2.5% typical maximum, 6% extreme), ion recombination (0.2%), leakage (0.3%), and room scatter (0.8%)-the values in parentheses are the largest corrections applied. The experimental setup and the detectors are modeled using EGSnrc, with the newly added photonuclear attenuation included (up to a 5.6% effect). A detailed sensitivity analysis is carried out for the measured and calculated transmission data. Results: The developed experimental protocol allows for transmission measurements with 0.4% uncertainty on the smallest signals. Suggestions for accurate transmission measurements are provided. Measurements and EGSnrc calculations agree typically within 0.2% for the sensitivity of the transmission values to the detector details, to the bremsstrahlung target material, and to the incident electron energy. Direct comparison of the measured and calculated transmission data shows agreement better than 2% for C (3.4% for the 10 MV beam) and typically better than 1% for Pb. The differences can be explained by acceptable photon cross section changes of Less-Than-Or-Slanted-Equal-To 0.4%. Conclusions: Accurate transmission measurements require accounting for a number of influence quantities which, if ignored, can collectively introduce errors larger than 10%. Accurate transmission calculations require the use of the most accurate data and physics options available in EGSnrc, particularly the more accurate bremsstrahlung angular sampling option and the newly added modeling of photonuclear attenuation. Comparison between measurements and calculations implies that EGSnrc is accurate within 0.2% for relative ion chamber response calculations. Photon cross section uncertainties are the ultimate limiting factor for the accuracy of the calculated transmission data (Monte Carlo or analytical).

  2. Measuring inside damage of individual multi-walled carbon nanotubes using scanning transmission X-ray microscopy

    SciTech Connect (OSTI)

    Liu, Jinyin; Bai, Lili; Zhao, Guanqi; Sun, Xuhui E-mail: jzhong@suda.edu.cn; Zhong, Jun E-mail: jzhong@suda.edu.cn; Wang, Jian

    2014-06-16

    The electronic structure of individual multi-walled carbon nanotubes (MWCNTs) has been probed using scanning transmission X-ray microscopy (STXM). Although transmission electron microscope (TEM) images show that the exterior of the MWCNTs are clean and straight; the inside structure of some of the MWCNTs is much less well ordered, as revealed by STXM. The amorphization of the interior tubes can be introduced in the growth or modification processes. Moreover, TEM measurement with high dose may also lead to the inside damage. Our results reveal that the structure of individual MWCNTs can be complex and suggest that electronic structure measurements are an important tool for characterizing carbon nanomaterials.

  3. Advanced Heat Transfer Technologies Increase Vehicle Performance and Reliability; The Spectrum of Clean Energy Innovation (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-06-01

    Fact sheet describes NREL's work with heat transfer technologies to keep hybrid electric and all-electric vehicle power electronic components cool.

  4. Concurrent Wind Cooling in Power Transmission Lines

    SciTech Connect (OSTI)

    Jake P Gentle

    2012-08-01

    Idaho National Laboratory and the Idaho Power Company, with collaboration from Idaho State University, have been working on a project to monitor wind and other environmental data parameters along certain electrical transmission corridors. The combination of both real-time historical weather and environmental data is being used to model, validate, and recommend possibilities for dynamic operations of the transmission lines for power and energy carrying capacity. The planned results can also be used to influence decisions about proposed design criteria for or upgrades to certain sections of the transmission lines.

  5. Technology Transfer Overview

    Broader source: Energy.gov [DOE]

    DOE's capabilities, and the innovations it supports, help ensure the country's role as a leader in science and technology. In particular, technology transfer supports the maturation and deployment of DOE discoveries, providing ongoing economic, security and environmental benefits for all Americans.

  6. Decal transfer microfabrication

    DOE Patents [OSTI]

    Nuzzo, Ralph G.; Childs, William Robert

    2004-10-19

    A method of making a microstructure includes forming a pattern in a surface of a silicon-containing elastomer, oxidizing the pattern, contacting the pattern with a substrate; and bonding the oxidized pattern and the substrate such that the pattern and the substrate are irreversibly attached. The silicon-containing elastomer may be removably attached to a transfer pad.

  7. Comparison of the One-electron Oxidations of CO-Bridged vs Unbridged Bimetallic Complexes: Electron-transfer Chemistry of Os2Cp2(CO)4 and Os2Cp*2(?-CO)2(CO)2 (Cp = ?5-C5H5, Cp* = ?5-C5Me5)

    SciTech Connect (OSTI)

    Laws, Derek R.; Bullock, R. Morris; Lee, Richmond; Huang, Kuo-Wei; Geiger, William J.

    2014-09-22

    The one-electron oxidations of two dimers of half-sandwich osmium carbonyl complexes have been examined by electrochemistry, spectro-electrochemistry, and computational methods. The all-terminal carbonyl complex Os2Cp2(CO)4 (1, Cp = ?5-C5H5) undergoes a reversible one-electron anodic reaction at E1/2 = 0.41 V vs ferrocene in CH2Cl2/0.05 M [NBu4][B(C6F5)4], giving a rare example of a metal-metal bonded radical cation unsupported by bridging ligands. The IR spectrum of 1+ is consistent with an approximately 1:1 mixture of anti and gauche structures for the 33 e- radical cation in which it has retained all-terminal bonding of the CO ligands. DFT calculations, including orbital-occupancy-perturbed Mayer bond-order analyses, show that the HOMOs of anti-1 and gauche-1 are metal-ligand delocalized. Removal of an electron from 1 has very little effect on the Os-Os bond order, accounting for the resistance of 1+ to heterolytic cleavage. The Os-Os bond distance is calculated to decrease by 0.10 and 0.06 as a consequence of one-electron oxidation of anti-1 and gauche-1, respectively. The CO-bridged complex Os2Cp*2(?-CO)2(CO)2 (Cp* = ?5-C5Me5), trans-2, undergoes a more facile oxidation, E1/2 = - 0.11 V, giving a persistent radical cation shown by solution IR analysis to preserve its bridged-carbonyl structure. However, ESR analysis of frozen solutions of 2+ is interpreted in terms of the presence of two isomers, most likely anti-2+ and trans-2+, at low temperature. Calculations show that the HOMO of trans-2 is highly delocalized over the metal-ligand framework, with the bridging carbonyls accounting for about half of the orbital makeup. The Os-Os bond order again changes very little with removal of an electron, and the Os-Os bond length actually undergoes minor shortening. Calculations suggest that the second isomer of 2+ has both the trans CO-bridged and the anti all-terminal CO structures. DRL and WEG acknowledge the support of the National Science Foundation under grant CHE-0808909. K-WH acknowledges financial support from KAUST. RMB thanks the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences for support. Pacific Northwest National Laboratory is a multiprogram national laboratory operated by Battelle for the U.S. Department of Energy. We thank Dr. S. I. Gorelsky for the discussion on the OOP analysis.

  8. Oahu Wind Integration and Transmission Study (OWITS): Hawaiian Islands

    Energy Savers [EERE]

    Transmission Interconnection Project | Department of Energy Oahu Wind Integration and Transmission Study (OWITS): Hawaiian Islands Transmission Interconnection Project Oahu Wind Integration and Transmission Study (OWITS): Hawaiian Islands Transmission Interconnection Project This report provides an independent review included an initial evaluation of the technical configuration and capital costs of establishing an undersea cable system and examining impacts to the existing electric

  9. Phase 2 Report: Oahu Wind Integration and Transmission Study (OWITS);

    Energy Savers [EERE]

    Hawaiian Islands Transmission Interconnection Project | Department of Energy Phase 2 Report: Oahu Wind Integration and Transmission Study (OWITS); Hawaiian Islands Transmission Interconnection Project Phase 2 Report: Oahu Wind Integration and Transmission Study (OWITS); Hawaiian Islands Transmission Interconnection Project This report provides an independent review included an initial evaluation of the technical configuration and capital costs of establishing an undersea cable system and

  10. Pattern transfer printing by kinetic control of adhesion to an elastomeric stamp

    DOE Patents [OSTI]

    Nuzzo, Ralph G. (Champaign, IL); Rogers, John A. (Champaign, IL); Menard, Etienne (Urbana, IL); Lee, Keon Jae (Tokyo, JP); Khang, Dahl-Young (Urbana, IL); Sun, Yugang (Champaign, IL); Meitl, Matthew (Champaign, IL); Zhu, Zhengtao (Urbana, IL)

    2011-05-17

    The present invention provides methods, systems and system components for transferring, assembling and integrating features and arrays of features having selected nanosized and/or microsized physical dimensions, shapes and spatial orientations. Methods of the present invention utilize principles of `soft adhesion` to guide the transfer, assembly and/or integration of features, such as printable semiconductor elements or other components of electronic devices. Methods of the present invention are useful for transferring features from a donor substrate to the transfer surface of an elastomeric transfer device and, optionally, from the transfer surface of an elastomeric transfer device to the receiving surface of a receiving substrate. The present methods and systems provide highly efficient, registered transfer of features and arrays of features, such as printable semiconductor element, in a concerted manner that maintains the relative spatial orientations of transferred features.

  11. Electrical Transmission Line Diametrical Retention Mechanism

    DOE Patents [OSTI]

    Hall, David R.; Hall, Jr., H. Tracy; Pixton, David; Dahlgren, Scott; Sneddon, Cameron; Briscoe, Michael; Fox, Joe

    2006-01-03

    The invention is a mechanism for retaining an electrical transmission line. In one embodiment of the invention it is a system for retaining an electrical transmission line within downhole components. The invention allows a transmission line to be attached to the internal diameter of drilling components that have a substantially uniform drilling diameter. In accordance with one aspect of the invention, the system includes a plurality of downhole components, such as sections of pipe in a drill string, drill collars, heavy weight drill pipe, and jars. The system also includes a coaxial cable running between the first and second end of a drill pipe, the coaxial cable having a conductive tube and a conductive core within it. The invention allows the electrical transmission line to withstand the tension and compression of drill pipe during routine drilling cycles.

  12. Data transmission element for downhole drilling components

    DOE Patents [OSTI]

    Hall, David R.; Hall, Jr., H. Tracy; Pixton, David S.; Dahlgren, Scott; Fox, Joe; Sneddon, Cameron; Briscoe, Michael

    2006-01-31

    A robust data transmission element for transmitting information between downhole components, such as sections of drill pipe, in the presence of hostile environmental conditions, such as heat, dirt, rocks, mud, fluids, lubricants, and the like. The data transmission element components include a generally U-shaped annular housing, a generally U-shaped magnetically conductive, electrically insulating element such as ferrite, and an insulated conductor. Features on the magnetically conducting, electrically insulating element and the annular housing create a pocket when assembled. The data transmission element is filled with a polymer to retain the components within the annular housing by filling the pocket with the polymer. The polymer can bond with the annular housing and the insulated conductor but preferably not the magnetically conductive, electrically insulating element. A data transmission element is mounted within a recess proximate a mating surface of a downhole drilling component, such as a section of drill pipe.

  13. Agenda: Electricity Transmission, Storage and Distribution- West

    Broader source: Energy.gov [DOE]

    The subject of transmission has many facets: its role in bulk power reliability, including how to maintain reliability with a changing resource mix; the planning, cost-allocation and state &...

  14. Load-resistant coaxial transmission line

    DOE Patents [OSTI]

    Hall, David R.; Fox, Joe

    2006-01-03

    A transmission line for downhole tools that make up all or part of a tool string for drilling and production of oil, gas, and geothermal wells that can withstand the dynamic gravitational forces and other accelerations associated with downhole excavations. The transmission line has a metal tube, or outer conductor, that houses a coaxial wire inner conductor. A non-metallic dielectric material is interposed between the inner and outer conductors. The outer and inner conductors and the dielectric are sufficiently compressed together so that independent motion between them is abated. Compression of the components of the transmission line may be achieved by drawing the transmission through one or more dies in order to draw down the outer conductor onto the dielectric, or by expanding the inner conductor against the dielectric using a mandrel or hydraulic pressure. Non-metallic bead segments may be used in aid of the compression necessary to resist the dynamic forces and accelerations of drilling.

  15. Georgia Transmission Corp | Open Energy Information

    Open Energy Info (EERE)

    Corp Jump to: navigation, search Name: Georgia Transmission Corp Place: Georgia References: EIA Form EIA-861 Final Data File for 2010 - File1a1 EIA Form 861 Data Utility Id 7197...

  16. EIS-0285: Transmission System Vegetation Management Program

    Broader source: Energy.gov [DOE]

    Bonneville Power Administration (Bonneville) is responsible for maintaining a network of 24,000 kilometers (km) or 15,000 miles (mi.) of electric transmission lines and 350 substations. This...

  17. Infrastructure Needs: Natural Gas/Electricity Transmission,...

    Broader source: Energy.gov (indexed) [DOE]

    miles of transmission lines, 72,000 miles of distribution lines, and 6,300 miles of natural gas pipelines. Our over 8,600 employees are committed to our mission to deliver...

  18. National Electric Transmission Congestion Study- Portland Workshop

    Broader source: Energy.gov [DOE]

    On December 13, 2011, DOE hosted a regional pre-study workshop in Portland, OR to receive input and suggestions concerning the National Electric Transmission Congestion Study. The workshop flyer, agenda, presentations, and full transcript are available below.

  19. American Transmission Company LLC | Open Energy Information

    Open Energy Info (EERE)

    LLC Jump to: navigation, search Name: American Transmission Company LLC Place: Waukesha, WI References: SGIC1 This article is a stub. You can help OpenEI by expanding it....

  20. Transmission Reliability Peer Review Materials Now Available

    Broader source: Energy.gov [DOE]

    The Office of Electricity Delivery and Energy Reliability held a peer review of the Transmission Reliability Program on June 10-11, 2015, in Washington, DC. Materials including the agenda and presentations are now available for download.

  1. Electrician - Foreman II (Transmission Lines & Substations) ...

    Broader source: Energy.gov (indexed) [DOE]

    Region Transmission Lines and Substation Maintenance (G5200) 615 S. 43rd Avenue Phoenix, AZ 85009 Duty Location is Page, AZ Find out more about living conditions at this...

  2. Wind Energy Transmission | Open Energy Information

    Open Energy Info (EERE)

    Wind Energy Transmission Jump to: navigation, search Photoshop art created from two NREL-PIX photos (10929 & 15185) of a sunset view of electrical power towers combined with wind...

  3. Experimental Investigation of Turbine Vane Heat Transfer for Alternative Fuels

    SciTech Connect (OSTI)

    Nix, Andrew Carl

    2015-03-23

    The focus of this program was to experimentally investigate advanced gas turbine cooling schemes and the effects of and factors that contribute to surface deposition from particulate matter found in coal syngas exhaust flows on turbine airfoil heat transfer and film cooling, as well as to characterize surface roughness and determine the effects of surface deposition on turbine components. The program was a comprehensive, multi-disciplinary collaborative effort between aero-thermal and materials faculty researchers and the Department of Energy, National Energy Technology Laboratory (NETL). The primary technical objectives of the program were to evaluate the effects of combustion of syngas fuels on heat transfer to turbine vanes and blades in land-based power generation gas turbine engines. The primary questions to be answered by this investigation were; What are the factors that contribute to particulate deposition on film cooled gas turbine components? An experimental program was performed in a high-temperature and pressure combustion rig at the DOE NETL; What is the effect of coal syngas combustion and surface deposition on turbine airfoil film cooling? Deposition of particulate matter from the combustion gases can block film cooling holes, decreasing the flow of the film coolant and the film cooling effectiveness; How does surface deposition from coal syngas combustion affect turbine surface roughness? Increased surface roughness can increase aerodynamic losses and result in decreased turbine hot section efficiency, increasing engine fuel consumption to maintain desired power output. Convective heat transfer is also greatly affected by the surface roughness of the airfoil surface; Is there any significant effect of surface deposition or erosion on integrity of turbine airfoil thermal barrier coatings (TBC) and do surface deposits react with the TBC in any way to decrease its thermal insulating capability? Spallation and erosion of TBC is a persistent problem in modern turbine engines; and What advancements in film cooling hole geometry and design can increase effectiveness of film cooling in turbines burning high-hydrogen coal syngas due to the higher heat loads and mass flow rates of the core flow? Experimental and numerical investigations of advanced cooling geometries that can improve resistance to surface deposition were performed. The answers to these questions were investigated through experimental measurements of turbine blade surface temperature and coolant coverage (via infrared camera images and thermocouples) and time-varying surface roughness in the NETL high-pressure combustion rig with accelerated, simulated surface deposition and advanced cooling hole concepts, coupled with detailed materials analysis and characterization using conventional methods of Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-Ray Diffraction (XRD), 3-D Surface Topography (using a 3-D stylus profilometer). Detailed surface temperatures and cooling effectiveness could not be measured due to issues with the NETL infrared camera system. In collaboration with faculty startup funding from the principal investigator, experimental and numerical investigations were performed of an advanced film cooling hole geometry, the anti-vortex hole (AVH), focusing on improving cooling effectiveness and decreasing the counter-rotating vortex of conventional cooling holes which can entrain mainstream particulate matter to the surface. The potential benefit of this program is in gaining a fundamental understanding of how the use of alternative fuels will effect the operation of modern gas turbine engines, providing valuable data for more effective cooling designs for future turbine systems utilizing alternative fuels.

  4. X-ray transmissive debris shield

    DOE Patents [OSTI]

    Spielman, Rick B. (Albuquerque, NM)

    1994-01-01

    A composite window structure is described for transmitting x-ray radiation and for shielding radiation generated debris. In particular, separate layers of different x-ray transmissive materials are laminated together to form a high strength, x-ray transmissive debris shield which is particularly suited for use in high energy fluences. In one embodiment, the composite window comprises alternating layers of beryllium and a thermoset polymer.

  5. Transmission Infrastructure: FERCs Role

    U.S. Energy Information Administration (EIA) Indexed Site

    Transmission Incentives Transmission Incentives P. Kumar Agarwal P. Kumar Agarwal Acting Director, Division of Reliability & Acting Director, Division of Reliability & Engineering Services Engineering Services Federal Energy Regulatory Commission Federal Energy Regulatory Commission U.S. DOE, Energy Information Administration U.S. DOE, Energy Information Administration 2009 Energy Conference 2009 Energy Conference Washington, DC Washington, DC April 7, 2009 April 7, 2009 2 2 History

  6. NREL: Transmission Grid Integration - Working With Us

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Working With Us NREL works with industry, government, and academia on transmission integration research. Learn how you can work with us. Develop Technology Partnerships There are a variety of ways to get involved with NREL's transmission integration activities. You can: Work collaboratively with NREL through cooperative research and development agreements. This is the most common means of industrial collaboration. Participate in subcontracted research. Close to half NREL's budget supports

  7. Electron Transfer Dynamics in Efficient Molecular Solar Cells

    SciTech Connect (OSTI)

    Meyer, Gerald John

    2014-10-01

    This research provided new mechanistic insights into surface mediated photochemical processes relevant to solar energy conversion. In this past three years our research has focused on oxidation photo-redox chemistry and on the role surface electric fields play on basic spectroscopic properties of molecular-semiconductor interfaces. Although this research as purely fundamental science, the results and their interpretation have relevance to applications in dye sensitized and photogalvanic solar cells as well as in the storage of solar energy in the form of chemical bonds.

  8. Photoinduced electron transfer in perylene-TiO2 nanoassemblies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nanoassemblies Authors: Llansola-Portols, M.J., Bergkamp, J.J., Tomlin, J., Moore, T.A., Kodis, G., Moore, A.L., Cosa, G., and Palacios, R.E. Title: Photoinduced...

  9. Subcooled Boiling Heat Transfer for Cooling of Power Electronics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    radiator and associated pumping system are still required in HEVs. This additional cooling system adds weight and cost while decreasing the efficiency of HEVs. With the...

  10. Transferred metal electrode films for large-area electronic devices...

    Office of Scientific and Technical Information (OSTI)

    High-quality OFETs with sub-10 V operational voltages have been obtained this way using conventional polymer dielectrics and a high-mobility polymer semiconductor ...

  11. Interfacial electron transfer dynamics of photosensitized zinc oxide nanoclusters

    SciTech Connect (OSTI)

    Murakoshi, Kei; Yanagida, Shozo; Capel, M.

    1997-06-01

    The authors have prepared and characterized photosensitized zinc oxide (ZnO) nanoclusters, dispersed in methanol, using carboxylated coumarin dyes for surface adsorption. Femtosecond time-resolved emission spectroscopy allows the authors to measure the photo-induced charge carrier injection rate constant from the adsorbed photosensitizer to the n-type semiconductor nanocluster. These results are compared with other photosensitized semiconductors.

  12. Mimicking the electron transfer chain in photosystem II with...

    Office of Scientific and Technical Information (OSTI)

    Authors: Megiatto Jr., Jackson D. ; Antoniuk-Pablant, Antaeres' ; Sherman, Ben ; Gervaldo, Miguel ; Moore, Thomas A. ; Moore, Ana L. ; Gust, Devens Publication Date: 2012-09-25 ...

  13. SF 9424-EFT;Electronic Funds Transfer Agreement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    shall be responsible for any loss which may arise by reason of any error, mistake or fraud regarding the information provided herein, or any subsequent change. Any other loss...

  14. 2012 ELECTRON DONOR-ACCEPTOR INTERACTIONS GORDON RESEARCH CONFERENCE, AUGUST 5-10, 2012

    SciTech Connect (OSTI)

    McCusker, James

    2012-08-10

    The upcoming incarnation of the Gordon Research Conference on Electron Donor Acceptor Interactions will feature sessions on classic topics including proton-coupled electron transfer, dye-sensitized solar cells, and biological electron transfer, as well as emerging areas such as quantum coherence effects in donor-acceptor interactions, spintronics, and the application of donor-acceptor interactions in chemical synthesis.

  15. Swipe transfer assembly

    DOE Patents [OSTI]

    Christiansen, Robert M. (Blackfoot, ID); Mills, William C. (McKeesport, PA)

    1992-01-01

    The swipe transfer assembly is a mechanical assembly which is used in conjunction with glove boxes and other sealed containments. It is used to pass small samples into or out of glove boxes without an open breach of the containment, and includes a rotational cylinder inside a fixed cylinder, the inside cylinder being rotatable through an arc of approximately 240.degree. relative to the outer cylinder. An offset of 120.degree. from end to end allows only one port to be opened at a time. The assembly is made of stainless steel or aluminum and clear acrylic plastic to enable visual observation. The assembly allows transfer of swipes and smears from radiological and other specially controlled environments.

  16. Plastic container bagless transfer

    DOE Patents [OSTI]

    Tibrea, Steven L.; D'Amelio, Joseph A.; Daugherty, Brent A.

    2003-11-18

    A process and apparatus are provided for transferring material from an isolated environment into a storage carrier through a conduit that can be sealed with a plug. The plug and conduit can then be severed to provide a hermetically sealed storage carrier containing the material which may be transported for storage or disposal and to maintain a seal between the isolated environment and the ambient environment.

  17. 2006 Technology Transfer Awards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology Transfer Awards Carrying on the tradition of world-changing innovation Los Alamos National Laboratory, an affirmative action/equal opportunity employer, is operated by Los Alamos National Security, LLC, for the National Nuclear Security Administration of the U.S. Department of Energy under contract DE-AC52-06NA25396. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its

  18. 2007 Technology Transfer Awards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Technology Transfer Awards Los Alamos National Laboratory, an affirmative action/equal opportunity employer, is operated by Los Alamos National Security, LLC, for the National Nuclear Security Administration of the U.S.Department of Energy under contract DE-AC52-06NA25396. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the Los

  19. Technology Transfer | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology Transfer Through partnerships and licensing of its intellectual property rights, NREL seeks to reduce private sector risk in early stage technologies, enable investment in the adoption of renewable energy and energy efficiency technologies, reduce U.S. reliance on foreign energy sources, reduce carbon emissions, and increase U.S. industrial competitiveness. A photo of three men looking at a colorful, floor-to-ceiling, 3-D visualization of a biomass analysis model. View a summary of

  20. Study of transmission line attenuation in broad band millimeter wave frequency range

    SciTech Connect (OSTI)

    Pandya, Hitesh Kumar B.; Austin, M. E.; Ellis, R. F.

    2013-10-15

    Broad band millimeter wave transmission lines are used in fusion plasma diagnostics such as electron cyclotron emission (ECE), electron cyclotron absorption, reflectometry and interferometry systems. In particular, the ECE diagnostic for ITER will require efficient transmission over an ultra wide band, 100 to 1000 GHz. A circular corrugated waveguide transmission line is a prospective candidate to transmit such wide band with low attenuation. To evaluate this system, experiments of transmission line attenuation were performed and compared with theoretical loss calculations. A millimeter wave Michelson interferometer and a liquid nitrogen black body source are used to perform all the experiments. Atmospheric water vapor lines and continuum absorption within this band are reported. Ohmic attenuation in corrugated waveguide is very low; however, there is Bragg scattering and higher order mode conversion that can cause significant attenuation in this transmission line. The attenuation due to miter bends, gaps, joints, and curvature are estimated. The measured attenuation of 15 m length with seven miter bends and eighteen joints is 1 dB at low frequency (300 GHz) and 10 dB at high frequency (900 GHz), respectively.

  1. PP-76 The Vermont Electric Transmission Company | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 The Vermont Electric Transmission Company PP-76 The Vermont Electric Transmission Company Presidential Permit authorizing The Vermont Electric Transmission Company to construct, operate, and maintain transmission facilities at the U.S. - Canada Border. PDF icon PP-76 The Vermont Electric Transmission Company More Documents & Publications PP-76-1 The Vermont Electric Transmission Company PP-66-1 Vermont Electric Power Company, Inc. PP-228 Edison Sault Electric

  2. National Transmission Grid Study: 2002 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmission Grid Study: 2002 National Transmission Grid Study: 2002 National Transmission Grid Study: The National Energy Policy Plan directed the U.S. Department of Energy (DOE) to conduct a study to examine the benefits of establishing a national electricity transmission grid and to identify transmission bottlenecks and measures to address them. PDF icon National Transmission Grid Study More Documents & Publications Report to Congress:Impacts of the Federal Energy Regulatory Commission's

  3. Draft Chapter 4: Transmission Adequacy | Department of Energy

    Office of Environmental Management (EM)

    4: Transmission Adequacy Draft Chapter 4: Transmission Adequacy A robust interstate electric transmission network must be developed to enable our electricity future. PDF icon Draft Chapter 4: Transmission Adequacy More Documents & Publications DOE EAC Electricity Adequacy Report. Transmission Chapter DRAFT- September 18, 2008 DOE EAC Electricity Adequacy Report. CHAPTER 4: Transmission Adequacy. October 17, 2008 DRAFT Electricity Advisory Committee Meeting, September 25, 2008: Minutes

  4. Tribal Renewable Energy Webinar: Transmission and Grid Basics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmission and Grid Basics for Tribal Economic and Energy Development Tribal Renewable Energy Webinar: Transmission and Grid Basics for Tribal Economic and Energy Development...

  5. EIS-0499: Great Northern Transmission Line Project, Minnesota...

    Broader source: Energy.gov (indexed) [DOE]

    and connect a new 883-megawatt electric transmission system across the U.S.-Canada border. The proposed 220 mile transmission line would cross the border near Roseau,...

  6. Tri State Generation and Transmission Association Inc | Open...

    Open Energy Info (EERE)

    and Transmission Association Inc Place: Westminster, Colorado Zip: 80234 Product: A wholesale electric power asset operator and transmission grid. Coordinates: 43.07212,...

  7. Plan to Conduct Electric Transmission Congestion Study: Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmission Congestion Study Notice of Inquiry: Federal Register Notice Volume 73, No. 108 - Jun. 4, 2008 National Electric Transmission Congestion Study - Philadelphia Workshop...

  8. Self-Aligning Mirror Mechanism for Transmission Line Offset Correction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Self-Aligning Mirror Mechanism for Transmission Line Offset Correction The Self-Aligning Mirror Mechanism for Transmission Line Offset Correction is a self-aligning mechanism which...

  9. RAPID/BulkTransmission/Exploration | Open Energy Information

    Open Energy Info (EERE)

    search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us RAPID Bulk Transmission ...

  10. RAPID/BulkTransmission/Power Plant | Open Energy Information

    Open Energy Info (EERE)

    RAPIDBulkTransmissionPower Plant < RAPID | BulkTransmission Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk...

  11. American Transmission Company LLC II Smart Grid Project | Open...

    Open Energy Info (EERE)

    your syntax: * Display map References ARRA Smart Grid Investment Grants1 American Transmission Smart Grid2 American Transmission Company, LLC has been selected by the U.S....

  12. OAHU Wind Integration And Transmission Study: Summary Report...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon 48632.pdf More Documents & Publications Phase 2 Report: Oahu Wind Integration and Transmission Study (OWITS); Hawaiian Islands Transmission Interconnection Project Oahu ...

  13. Oahu Wind Integration and Transmission Study (OWITS): Hawaiian...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon 50411.pdf More Documents & Publications Phase 2 Report: Oahu Wind Integration and Transmission Study (OWITS); Hawaiian Islands Transmission Interconnection Project OAHU ...

  14. Proposed Project: Plains & Eastern Clean Line Transmission Line...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Section 1222 of the Energy Policy Act 2005 Proposed Project: Plains & Eastern Clean Line Transmission Line Proposed Project: Plains & Eastern Clean Line Transmission Line On ...

  15. Plains and Eastern Clean Line Transmission Line: Federal Register...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plains and Eastern Clean Line Transmission Line: Federal Register Notice, Volume 80, No. 81 - April 28, 2015 Plains and Eastern Clean Line Transmission Line: Federal Register ...

  16. EIS-0514: Colusa-Sutter 500-kilovolt Transmission Line Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    514: Colusa-Sutter 500-kilovolt Transmission Line Project; Colusa and Sutter Counties, California EIS-0514: Colusa-Sutter 500-kilovolt Transmission Line Project; Colusa and Sutter ...

  17. Especial Gear Transmissions s founders | Open Energy Information

    Open Energy Info (EERE)

    Especial Gear Transmissions s founders Jump to: navigation, search Name: Especial Gear Transmissions's founders Place: Spain Product: EGT's founders References: Especial Gear...

  18. Steps to Establish a Real-Time Transmission Monitoring System...

    Broader source: Energy.gov (indexed) [DOE]

    Steps to establish a real-time transmission monitoring system for transmission owners and ... Eastern and Western Interconnections real-time information on the functional status of ...

  19. An Introduction to Electric Power Transmission | Open Energy...

    Open Energy Info (EERE)

    An Introduction to Electric Power Transmission Jump to: navigation, search OpenEI Reference LibraryAdd to library General: An Introduction to Electric Power Transmission Abstract...

  20. 2006 National Electric Transmission Congestion Study and Related...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 National Electric Transmission Congestion Study and Related Materials 2006 National Electric Transmission Congestion Study and Related Materials The 2006 National Congestion...