Sample records for tracer gas methods

  1. Preliminary Investigation of Tracer Gas Reaeration Method for Shallow Bays

    E-Print Network [OSTI]

    Baker, Sarah H.; Holley, Edward R.

    apparently the first tests to be performed using the tracer gas technique in bays. As a result, the emphasis was on the development of techniques rather than on obtaining data. It appears that workable techniques have been developed, but they now need...

  2. Experiments to Evaluate and Implement Passive Tracer Gas Methods to Measure

    E-Print Network [OSTI]

    1 Experiments to Evaluate and Implement Passive Tracer Gas Methods to Measure Ventilation Rates the concentrations of pollutants emitted by indoor sources and brings in pollutants from the outdoors. The air gas techniques. One method involves either real-time injections of tracer gases or real

  3. Biological tracer method

    DOE Patents [OSTI]

    Strong-Gunderson, J.M.; Palumbo, A.V.

    1998-09-15T23:59:59.000Z

    The present invention is a biological tracer method for characterizing the movement of a material through a medium, comprising the steps of: introducing a biological tracer comprising a microorganism having ice nucleating activity into a medium; collecting at least one sample of the medium from a point removed from the introduction point; and analyzing the sample for the presence of the biological tracer. The present invention is also a method for using a biological tracer as a label for material identification by introducing a biological tracer having ice nucleating activity into a material, collecting a sample of a portion of the labelled material and analyzing the sample for the presence of the biological tracer. 2 figs.

  4. Biological tracer method

    DOE Patents [OSTI]

    Strong-Gunderson, Janet M. (Ten Mile, TN); Palumbo, Anthony V. (Oak Ridge, TN)

    1998-01-01T23:59:59.000Z

    The present invention is a biological tracer method for characterizing the movement of a material through a medium, comprising the steps of: introducing a biological tracer comprising a microorganism having ice nucleating activity into a medium; collecting at least one sample of the medium from a point removed from the introduction point; and analyzing the sample for the presence of the biological tracer. The present invention is also a method for using a biological tracer as a label for material identification by introducing a biological tracer having ice nucleating activity into a material, collecting a sample of a portion of the labelled material and analyzing the sample for the presence of the biological tracer.

  5. Uncertainties in Air Exchange using Continuous-Injection, Long-Term Sampling Tracer-Gas Methods

    SciTech Connect (OSTI)

    Sherman, Max H.; Walker, Iain S.; Lunden, Melissa M.

    2013-12-01T23:59:59.000Z

    The PerFluorocarbon Tracer (PFT) method is a low-cost approach commonly used for measuring air exchange in buildings using tracer gases. It is a specific application of the more general Continuous-Injection, Long-Term Sampling (CILTS) method. The technique is widely used but there has been little work on understanding the uncertainties (both precision and bias) associated with its use, particularly given that it is typically deployed by untrained or lightly trained people to minimize experimental costs. In this article we will conduct a first-principles error analysis to estimate the uncertainties and then compare that analysis to CILTS measurements that were over-sampled, through the use of multiple tracers and emitter and sampler distribution patterns, in three houses. We find that the CILTS method can have an overall uncertainty of 10-15percent in ideal circumstances, but that even in highly controlled field experiments done by trained experimenters expected uncertainties are about 20percent. In addition, there are many field conditions (such as open windows) where CILTS is not likely to provide any quantitative data. Even avoiding the worst situations of assumption violations CILTS should be considered as having a something like a ?factor of two? uncertainty for the broad field trials that it is typically used in. We provide guidance on how to deploy CILTS and design the experiment to minimize uncertainties.

  6. Tracers and Tracer Testing: Design, Implementation, Tracer Selection, and Interpretation Methods

    SciTech Connect (OSTI)

    G. Michael Shook; Shannon L.; Allan Wylie

    2004-01-01T23:59:59.000Z

    Conducting a successful tracer test requires adhering to a set of steps. The steps include identifying appropriate and achievable test goals, identifying tracers with the appropriate properties, and implementing the test as designed. When these steps are taken correctly, a host of tracer test analysis methods are available to the practitioner. This report discusses the individual steps required for a successful tracer test and presents methods for analysis. The report is an overview of tracer technology; the Suggested Reading section offers references to the specifics of test design and interpretation.

  7. Photoacoustic infrared spectroscopy for conducting gas tracer tests and measuring water saturations in landfills

    SciTech Connect (OSTI)

    Jung, Yoojin; Han, Byunghyun; Mostafid, M. Erfan; Chiu, Pei [Department of Civil and Environmental Engineering, University of Delaware, Newark, DE 19716 (United States); Yazdani, Ramin [Yolo County Planning and Public Works Department, Division of Integrated Waste Management, Yolo County, 44090 County Rd. 28H, Woodland, CA 95776 (United States); Imhoff, Paul T., E-mail: imhoff@udel.edu [Department of Civil and Environmental Engineering, University of Delaware, Newark, DE 19716 (United States)

    2012-02-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Photoacoustic infrared spectroscopy tested for measuring tracer gas in landfills. Black-Right-Pointing-Pointer Measurement errors for tracer gases were 1-3% in landfill gas. Black-Right-Pointing-Pointer Background signals from landfill gas result in elevated limits of detection. Black-Right-Pointing-Pointer Technique is much less expensive and easier to use than GC. - Abstract: Gas tracer tests can be used to determine gas flow patterns within landfills, quantify volatile contaminant residence time, and measure water within refuse. While gas chromatography (GC) has been traditionally used to analyze gas tracers in refuse, photoacoustic spectroscopy (PAS) might allow real-time measurements with reduced personnel costs and greater mobility and ease of use. Laboratory and field experiments were conducted to evaluate the efficacy of PAS for conducting gas tracer tests in landfills. Two tracer gases, difluoromethane (DFM) and sulfur hexafluoride (SF{sub 6}), were measured with a commercial PAS instrument. Relative measurement errors were invariant with tracer concentration but influenced by background gas: errors were 1-3% in landfill gas but 4-5% in air. Two partitioning gas tracer tests were conducted in an aerobic landfill, and limits of detection (LODs) were 3-4 times larger for DFM with PAS versus GC due to temporal changes in background signals. While higher LODs can be compensated by injecting larger tracer mass, changes in background signals increased the uncertainty in measured water saturations by up to 25% over comparable GC methods. PAS has distinct advantages over GC with respect to personnel costs and ease of use, although for field applications GC analyses of select samples are recommended to quantify instrument interferences.

  8. Measurement of the odor impact of a waste deposit using the SF6-tracer method

    SciTech Connect (OSTI)

    Roetzer, H.; Muehldorf, V.; Riesing, J.

    1994-12-01T23:59:59.000Z

    Landfill gas emitted from a waste disposal often causes odor nuisance in the vicinity. To verify that the odor concentrations were below these limit values, the odor contributions of different sources had to be distinguished. A tracer method was applied to measure the odor impact of the sanitary landfill to its environment. The emitted landfill gas was labelled with the tracer gas SF6. The tracer gas was parted to even amounts and released through ten special nozzles equally distributed over the surface of the landfill. In the area around the landfill the concentration of the tracer gas was measured by collecting air samples and analyzing them with a gas chromatograph with an electron capture detector. Fifteen air sampling units were used to collect eight consecutive air samples at each selected point. These measurements gave the relation between the emission of landfill gas and the resulting concentrations in ambient air.

  9. Advancing Reactive Tracer Methods for Measuring Thermal Evolution...

    Open Energy Info (EERE)

    Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2- and Water-Based Geothermal Reservoirs Geothermal Lab Call Project Jump to: navigation, search Last...

  10. Tracer-dilution method indicates flowrate through compressor

    SciTech Connect (OSTI)

    Lagus, P.L.; Flanagan, B.S. (Lagus Applied Technology Inc., San Diego, CA (US)); Peterson, M.E. (Tennessee Gas Pipeline Co., Middleton, TN (US)); Clowney, S.L. (Tenneco Gas, Houston, TX (US))

    1991-02-25T23:59:59.000Z

    A technique for measuring compressor flowrate through an operating natural-gas centrifugal compressor has been tested and found to have a precisions approaching {plus minus}1.5%. The technique employs constant-flow tracer dilution. Testing demonstrated that use of a critical-flow nozzle to inject a constant, known flow of tracer into a flowing natural-gas stream is feasible. Effects of potential pulsation on a tracer flow measurement appear to be eliminated by this technique. With experimental and operational streamlining, the constant-flow tracer dilution technique is capable of being used to measure the flowrate through operating centrifugal compressors with sufficient precisions and accuracy to allow compressor operating characteristics to be determined. This technique is especially useful in situations in which an orifice-flow measurement cannot be performed because of physical space limits or economic considerations.

  11. Method of dispersing particulate aerosol tracer

    DOE Patents [OSTI]

    O'Holleran, Thomas P. (Belleville, MI)

    1988-01-01T23:59:59.000Z

    A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

  12. Methods and systems using encapsulated tracers and chemicals for reservoir interrogation and manipulation

    DOE Patents [OSTI]

    Roberts, Jeffery; Aines, Roger D; Duoss, Eric B; Spadaccini, Christopher M

    2014-11-04T23:59:59.000Z

    An apparatus, method, and system of reservoir interrogation. A tracer is encapsulating in a receptacle. The receptacle containing the tracer is injected into the reservoir. The tracer is analyzed for reservoir interrogation.

  13. Tracer Gas as a Practical Field Diagnostic Tool for Assessing Duct System Leaks

    E-Print Network [OSTI]

    Cummings, J. B.

    1989-01-01T23:59:59.000Z

    A methodology is presented for using tracer gas testing to detect and quantify duct leakage in homes. Since air is invisible, leakage of air from duct systems often remains undetected. Smoke sticks used in conjunction with blower doors are excellent...

  14. Advancing reactive tracer methods for measuring thermal evolution...

    Broader source: Energy.gov (indexed) [DOE]

    ability to accurately detect reservoir characteristics including fluid pathways, dynamics, residence time, etc." - 4.1.5.1-Barrier J: "Inadequate tracers andor tracer...

  15. New Tracers Identify Hydraulic Fracturing Fluids and Accidental Releases from Oil and Gas Operations

    E-Print Network [OSTI]

    Jackson, Robert B.

    New Tracers Identify Hydraulic Fracturing Fluids and Accidental Releases from Oil and Gas produced waters sampled from conventional oil and gas wells. We posit that boron isotope geochemistry can tool is validated by examining the composition of effluent discharge from an oil and gas brine

  16. Iodine as a tracer of organic material: 129 I results from gas hydrate

    E-Print Network [OSTI]

    Fehn, Udo

    Iodine as a tracer of organic material: 129 I results from gas hydrate systems and fore arc fluids of this system, investigations of gas hydrates from the Peru Margin (ODP 201, Site 1230) and of fluids collected for these fluids. The results are in good agreement with earlier investigations of gas hydrate systems at Blake

  17. Seasonal Variation in Monthly Average Air Change Rates Using Passive Tracer Gas Measurements

    E-Print Network [OSTI]

    Hansen, René Rydhof

    of indoor air pollution sources. Concurrently, great efforts are made to make buildings energy efficient 1970s, while less attention has been paid to IAQ. Insufficient venting of indoor air pollutantsSeasonal Variation in Monthly Average Air Change Rates Using Passive Tracer Gas Measurements Marie

  18. A coupled isotope tracer method to characterize input water to lakes

    E-Print Network [OSTI]

    Edwards, Thomas W.D.

    of input waters after accounting for the effects of secondary evaporative isotopic enrichment. As shownA coupled isotope tracer method to characterize input water to lakes Yi Yi a,*, Bronwyn E. Brock in revised form 7 November 2007; accepted 9 November 2007 KEYWORDS Water isotope tracers; Isotope hydrology

  19. Potential method for measurement of CO2 leakage from underground sequestration fields using radioactive tracers

    SciTech Connect (OSTI)

    Bachelor, Paula P.; McIntyre, Justin I.; Amonette, James E.; Hayes, James C.; Milbrath, Brian D.; Saripalli, Prasad

    2008-07-01T23:59:59.000Z

    Reduction of anthropogenic carbon dioxide (CO2) release to the environment is a pressing challenge that should be addressed to avert the potential devastating effects of global warming. Within the United States, the most abundant sources of CO2 emissions are those generate from coal- or gas-fired power plants; one method to control CO2 emissions is to sequester it in deep underground geological formations. From integrated assessment models the overall leakage rates from these storage locations must be less than 0.1% of stored volume per year for long-term control. The ability to detect and characterize nascent leaks, in conjunction with subsequent remediation efforts, will significantly decrease the amount of CO2 released back into the environment. Because potential leakage pathways are not necessarily known a priori, onsite monitoring must be performed; the monitoring region in the vicinity of a CO2 injection well may be as large as 100 km2, which represents the estimated size of a supercritical CO2 bubble that would form under typical injection scenarios. By spiking the injected CO2 with a radiological or stable isotope tracer, it will be possible to detect ground leaks from the sequestered CO2 using fewer sampling stations, with greater accuracy than would be possible using simple CO2 sensors. The relative merits of various sorbent materials, radiological and stable isotope tracers, detection methods and potential interferences will be discussed.

  20. THE NEW YORK CITY URBAN DISPERSION PROGRAM MARCH 2005 FIELD STUDY: TRACER METHODS AND RESULTS.

    SciTech Connect (OSTI)

    WATSON, T.B.; HEISER, J.; KALB, P.; DIETZ, R.N.; WILKE, R.; WIESER, R.; VIGNATO, G.

    2005-10-01T23:59:59.000Z

    The Urban Dispersion Program March 2005 Field Study tracer releases, sampling, and analytical methods are described in detail. There were two days where tracer releases and sampling were conducted. A total of 16.0 g of six tracers were released during the first test day or Intensive Observation Period (IOP) 1 and 15.7 g during IOP 2. Three types of sampling instruments were used in this study. Sequential air samplers, or SAS, collected six-minute samples, while Brookhaven atmospheric tracer samplers (BATS) and personal air samplers (PAS) collected thirty-minute samples. There were a total of 1300 samples resulting from the two IOPs. Confidence limits in the sampling and analysis method were 20% as determined from 100 duplicate samples. The sample recovery rate was 84%. The integrally averaged 6-minute samples were compared to the 30-minute samples. The agreement was found to be good in most cases. The validity of using a background tracer to calculate sample volumes was examined and also found to have a confidence level of 20%. Methods for improving sampling and analysis are discussed. The data described in this report are available as Excel files. An additional Excel file of quality assured tracer data for use in model validation efforts is also available. The file consists of extensively quality assured BATS tracer data with background concentrations subtracted.

  1. New Multi-functional Diagnostic Method with Tracer-encapsulated Pellet Injection on LHD

    SciTech Connect (OSTI)

    Sudo, S. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Graduate Univ. Advanced Studies, Hayama 240-0193 (Japan); Tamura, N.; Sato, K.; Matsubara, A.; Inagaki, S.; Goncharov, P.R.; Ozaki, T. [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Kalinina, D.V. [Graduate Univ. Advanced Studies, Hayama 240-0193 (Japan); Stutman, D.; Finkenthal, M. [Johns Hopkins University, Baltimore, MD 21218 (United States)

    2005-05-27T23:59:59.000Z

    The Tracer-Encapsulated Solid PELlet (TESPEL) injection is one of the simplest new ideas to study the impurity confinement and other plasma properties. The special features of this method are: (a) local deposition inside the plasma, (b) precise knowledge of the deposited tracer amount, (c) wide selection of tracer materials. The achievements of the multi-functional diagnostics using TESPEL injection on LHD are to measure: (a) impurity transport properties, (b) heat diffusivity, (c) particle flow features in and out of the magnetic island, and (d) fast neutral particle fluxes.

  2. Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. This project aims to develop reactive tracer method for monitoring thermal drawdown in enhanced geothermal systems.

  3. ADVANCING REACTIVE TRACER METHODS FOR MONITORING THERMAL DRAWDOWN IN GEOTHERMAL ENHANCED GEOTHERMAL RESERVOIRS

    SciTech Connect (OSTI)

    Mitchell A. Plummer; Carl D. Palmer; Earl D. Mattson; George D. Redden; Laurence C. Hull

    2010-10-01T23:59:59.000Z

    Reactive tracers have long been considered a possible means of measuring thermal drawdown in a geothermal system, before significant cooling occurs at the extraction well. Here, we examine the sensitivity of the proposed method to evaluate reservoir cooling and demonstrate that while the sensitivity of the method as generally proposed is low, it may be practical under certain conditions.

  4. Recover Act: Verification of Geothermal Tracer Methods in Highly Constrained Field Experiments

    SciTech Connect (OSTI)

    Becker, Matthew

    2014-05-16T23:59:59.000Z

    The prediction of the geothermal system efficiency is strong linked to the character of the flow system that connects injector and producer wells. If water flow develops channels or “short circuiting” between injection and extraction wells thermal sweep is poor and much of the reservoir is left untapped. The purpose of this project was to understand how channelized flow develops in fracture geothermal reservoirs and how it can be measured in the field. We explored two methods of assessing channelization: hydraulic connectivity tests and tracer tests. These methods were tested at a field site using two verification methods: ground penetrating radar (GPR) images of saline tracer and heat transfer measurements using distributed temperature sensing (DTS). The field site for these studies was the Altona Flat Fractured Rock Research Site located in northeastern New York State. Altona Flat Rock is an experimental site considered a geologic analog for some geothermal reservoirs given its low matrix porosity. Because soil overburden is thin, it provided unique access to saturated bedrock fractures and the ability image using GPR which does not effectively penetrate most soils. Five boreholes were drilled in a “five spot” pattern covering 100 m2 and hydraulically isolated in a single bedding plane fracture. This simple system allowed a complete characterization of the fracture. Nine small diameter boreholes were drilled from the surface to just above the fracture to allow the measurement of heat transfer between the fracture and the rock matrix. The focus of the hydraulic investigation was periodic hydraulic testing. In such tests, rather than pumping or injection in a well at a constant rate, flow is varied to produce an oscillating pressure signal. This pressure signal is sensed in other wells and the attenuation and phase lag between the source and receptor is an indication of hydraulic connection. We found that these tests were much more effective than constant pumping tests in identifying a poorly connected well. As a result, we were able to predict which well pairs would demonstrate channelized flow. The focus of the tracer investigation was multi-ionic tests. In multi-ionic tests several ionic tracers are injected simultaneously and the detected in a nearby pumping well. The time history of concentration, or breakthrough curve, will show a separation of the tracers. Anionic tracers travel with the water but cationic tracer undergo chemical exchange with cations on the surface of the rock. The degree of separation is indicative of the surface area exposed to the tracer. Consequently, flow channelization will tend to decrease the separation in the breakthrough. Estimation of specific surface area (the ration of fracture surface area to formation volume) is performed through matching the breakthrough curve with a transport model. We found that the tracer estimates of surface area were confirmed the prediction of channelized flow between well pairs produced by the periodic hydraulic tests. To confirm that the hydraulic and tracer tests were correctly predicting channelize flow, we imaged the flow field using surface GPR. Saline water was injected between the well pairs which produced a change in the amplitude and phase of the reflected radar signal. A map was produced of the migration of saline tracer from these tests which qualitatively confirmed the flow channelization predicted by the hydraulic and tracer tests. The resolution of the GPR was insufficient to quantitatively estimate swept surface area, however. Surface GPR is not applicable in typical geothermal fields because the penetration depths do not exceed 10’s of meters. Nevertheless, the method of using of phase to measure electrical conductivity and the assessment of antennae polarization represent a significant advancement in the field of surface GPR. The effect of flow character on fracture / rock thermal exchange was evaluated using heated water as a tracer. Water elevated 30 degrees C above the formation water was circulated between two wells pairs. One

  5. Single-well tracer methods for hydrogeologic evaluation of target aquifers

    SciTech Connect (OSTI)

    Hall, S.H.

    1994-11-01T23:59:59.000Z

    Designing an efficient well field for an aquifer thermal energy storage (ATES) project requires measuring local groundwater flow parameters as well as estimating horizontal and vertical inhomogeneity. Effective porosity determines the volume of aquifer needed to store a given volume of heated or chilled water. Ground-water flow velocity governs the migration of the thermal plume, and dispersion and heat exchange along the flow path reduces the thermal intensity of the recovered plume. Stratigraphic variations in the aquifer will affect plume dispersion, may bias the apparent rate of migration of the plume, and can prevent efficient hydraulic communication between wells. Single-well tracer methods using a conservative flow tracer such as bromide, along with pumping tests and water-level measurements, provide a rapid and cost-effective means for estimating flow parameters. A drift-and-pumpback tracer test yields effective porosity and flow velocity. Point-dilution tracer testing, using new instrumentation for downhole tracer measurement and a new method for calibrating the point-dilution test itself, yields depth-discrete hydraulic conductivity as it is affected by stratigraphy, and can be used to estimate well transmissivity. Experience in conducting both drift-and-pumpback and point-dilution tests at three different test sites has yielded important information that highlights both the power and the limitations of the single-well tracer methods. These sites are the University of Alabama Student Recreation Center (UASRC) ATES well field and the VA Medical Center (VA) ATES well field, both located in Tuscaloosa, Alabama, and the Hanford bioremediation test site north of Richland, Washington.

  6. Tracer airflow measurement system (TRAMS)

    DOE Patents [OSTI]

    Wang, Duo (Albany, CA)

    2007-04-24T23:59:59.000Z

    A method and apparatus for measuring fluid flow in a duct is disclosed. The invention uses a novel high velocity tracer injector system, an optional insertable folding mixing fan for homogenizing the tracer within the duct bulk fluid flow, and a perforated hose sampling system. A preferred embodiment uses CO.sub.2 as a tracer gas for measuring air flow in commercial and/or residential ducts. In extant commercial buildings, ducts not readily accessible by hanging ceilings may be drilled with readily plugged small diameter holes to allow for injection, optional mixing where desired using a novel insertable foldable mixing fan, and sampling hose.

  7. Motorola's Exhaust Optimization Program: Tracer Gas Application for Gas Panel Enclosures

    E-Print Network [OSTI]

    Myart, H. R.; Camacho, R.

    The Motorola Exhaust Optimization Program strives toward identifying the optimum exhaust requirements for gas panel enclosures to help conserve energy and provide future exhaust capacity for new tools. Various Motorola studies have shown...

  8. Advancing Reactive Tracer Methods for Measurement of Thermal Evolution in Geothermal Reservoirs: Final Report

    SciTech Connect (OSTI)

    Mitchell A. Plummer; Carl D. Palmer; Earl D. Mattson; Laurence C. Hull; George D. Redden

    2011-07-01T23:59:59.000Z

    The injection of cold fluids into engineered geothermal system (EGS) and conventional geothermal reservoirs may be done to help extract heat from the subsurface or to maintain pressures within the reservoir (e.g., Rose et al., 2001). As these injected fluids move along fractures, they acquire heat from the rock matrix and remove it from the reservoir as they are extracted to the surface. A consequence of such injection is the migration of a cold-fluid front through the reservoir (Figure 1) that could eventually reach the production well and result in the lowering of the temperature of the produced fluids (thermal breakthrough). Efficient operation of an EGS as well as conventional geothermal systems involving cold-fluid injection requires accurate and timely information about thermal depletion of the reservoir in response to operation. In particular, accurate predictions of the time to thermal breakthrough and subsequent rate of thermal drawdown are necessary for reservoir management, design of fracture stimulation and well drilling programs, and forecasting of economic return. A potential method for estimating migration of a cold front between an injection well and a production well is through application of reactive tracer tests, using chemical whose rate of degradation is dependent on the reservoir temperature between the two wells (e.g., Robinson 1985). With repeated tests, the rate of migration of the thermal front can be determined, and the time to thermal breakthrough calculated. While the basic theory behind the concept of thermal tracers has been understood for some time, effective application of the method has yet to be demonstrated. This report describes results of a study that used several methods to investigate application of reactive tracers to monitoring the thermal evolution of a geothermal reservoir. These methods included (1) mathematical investigation of the sensitivity of known and hypothetical reactive tracers, (2) laboratory testing of novel tracers that would improve method sensitivity, (3) development of a software tool for design and interpretation of reactive tracer tests and (4) field testing of the reactive tracer temperature monitoring concept.

  9. PERFLUOROCARBON GAS TRACER STUDIES TO SUPPORT RISK ASSESSMENT MODELING OF CRITICAL INFRASTRUCTURE SUBJECTED TO TERRORIST ATTACKS.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; HEISER, J.; WATSON, T.; ALLWINE, K.J.; FLAHERTY, J.E.

    2006-05-06T23:59:59.000Z

    Development of real-time predictive modeling to identify the dispersion and/or source(s) of airborne weapons of mass destruction including chemical, biological, radiological, and nuclear material in urban environments is needed to improve response to potential releases of these materials via either terrorist or accidental means. These models will also prove useful in defining airborne pollution dispersion in urban environments for pollution management/abatement programs. Predicting gas flow in an urban setting on a scale of less than a few kilometers is a complicated and challenging task due to the irregular flow paths that occur along streets and alleys and around buildings of different sizes and shapes, i.e., ''urban canyons''. In addition, air exchange between the outside and buildings and subway areas further complicate the situation. Transport models that are used to predict dispersion of WMD/CBRN materials or to back track the source of the release require high-density data and need defensible parameterizations of urban processes. Errors in the data or any of the parameter inputs or assumptions will lead to misidentification of the airborne spread or source release location(s). The need for these models to provide output in a real-time fashion if they are to be useful for emergency response provides another challenge. To improve the ability of New York City's (NYC's) emergency management teams and first response personnel to protect the public during releases of hazardous materials, the New York City Urban Dispersion Program (UDP) has been initiated. This is a four year research program being conducted from 2004 through 2007. This paper will discuss ground level and subway Perfluorocarbon tracer (PFT) release studies conducted in New York City. The studies released multiple tracers to study ground level and vertical transport of contaminants. This paper will discuss the results from these tests and how these results can be used for improving transport models needed for risk assessment.

  10. Perfluorocarbon tracer method for air-infiltration measurements

    DOE Patents [OSTI]

    Dietz, R.N.

    1982-09-23T23:59:59.000Z

    A method of measuring air infiltration rates suitable for use in rooms of homes and buildings comprises the steps of emitting perfluorocarbons in the room to be measured, sampling the air containing the emitted perfluorocarbons over a period of time, and analyzing the samples at a laboratory or other facility.

  11. Method of Liquifying a gas

    DOE Patents [OSTI]

    Zollinger, William T.; Bingham, Dennis N.; McKellar, Michael G.; Wilding, Bruce M.; Klingler, Kerry M.

    2006-02-14T23:59:59.000Z

    A method of liquefying a gas is disclosed and which includes the steps of pressurizing a liquid; mixing a reactant composition with the pressurized liquid to generate a high pressure gas; supplying the high pressure gas to an expansion engine which produces a gas having a reduced pressure and temperature, and which further generates a power and/or work output; coupling the expansion engine in fluid flowing relation relative to a refrigeration assembly, and wherein the gas having the reduced temperature is provided to the refrigeration assembly; and energizing and/or actuating the refrigeration assembly, at least in part, by supplying the power and/or work output generated by the expansion engine to the refrigeration assembly, the refrigeration assembly further reducing the temperature of the gas to liquefy same.

  12. Tracer Detection by Laser Spectroscopy for Applications in the Oil and Gas R. Nava, Texas A&M University, H. Schuessler, M. Fahes and H. Nasrabadi, Texas A&M University at Qatar, and

    E-Print Network [OSTI]

    Schuessler, Hans

    SPE 124689 Tracer Detection by Laser Spectroscopy for Applications in the Oil and Gas Industry R and more accurate option for applications in the oil and gas industry. The research work is currently being applications in the oil and gas industry. Chemical or radioactive tracers are used to label fluids from

  13. Retention of Tracer Gas from Instantaneous Releases of SF6 in an Urban Environment

    SciTech Connect (OSTI)

    Doran, J. C.; Allwine, K Jerry; Clawson, Kirk L.; Carter, Roger G.

    2006-01-01T23:59:59.000Z

    Data from a series of instantaneous releases of SF6 tracer during the Joint Urban 2003 study in Oklahoma City have been analyzed to determine characteristic retention times for puffs in an urban environment. Results from nine real-time tracer detectors with a time response of 0.5 seconds were used in the analysis. Distances from the source ranged from less than 200 m to over 1 km. For each individual intensive operating period (IOP), the detector locations were adjusted so that, given the expected wind directions during the releases, the detectors would lie generally downwind of the release point. As a result, building characteristics upwind of the detectors varied from one IOP to the next. Animations of the tracer concentrations show clear evidence of channeling along street canyons approximately parallel to the prevailing wind directions, trapping in street canyons perpendicular to the flow, and other complex circulation patterns. Retention times for individual puffs ranged from a few minutes to over 20 minutes, with a strong mode in the distribution around 11 minutes. There was surprisingly little correlation with wind speed or direction. Comparisons with simple puff models are presented.

  14. (bulb) , (1) Gas(1) Gas(1) Gas(1) Gas----saturation methodsaturation methodsaturation methodsaturation method

    E-Print Network [OSTI]

    Hong, Deog Ki

    (bulb) , . . , . . 1. . (1) Gas(1Static MethodStatic Method Isoteniscope bulb U-tube . bulb U-tube bulb . bulb . U bulb . manometer . . Isoteniscope Boling Point Method . #12;2. (1) Boiling

  15. Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS)

    Broader source: Energy.gov [DOE]

    Project objectives: identify tracers with sorption properties favorable for EGS applications; apply reversibly sorbing tracers to determine the fracture-matrix interface area available for heat transfer; and; explore the feasibility of obtaining fracture-matrix interface area from non-isothermal; single-well injection-withdrawal (SWIW) tests.

  16. Gas cleaning system and method

    DOE Patents [OSTI]

    Newby, Richard Allen

    2006-06-06T23:59:59.000Z

    A gas cleaning system for removing at least a portion of contaminants, such as halides, sulfur, particulates, mercury, and others, from a synthesis gas (syngas). The gas cleaning system may include one or more filter vessels coupled in series for removing halides, particulates, and sulfur from the syngas. The gas cleaning system may be operated by receiving gas at a first temperature and pressure and dropping the temperature of the syngas as the gas flows through the system. The gas cleaning system may be used for an application requiring clean syngas, such as, but not limited to, fuel cell power generation, IGCC power generation, and chemical synthesis.

  17. Synthesis gas method and apparatus

    DOE Patents [OSTI]

    Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie R.; Kosowski, Lawrence W.; Robinson, Charles

    2013-01-08T23:59:59.000Z

    A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube.

  18. Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

    DOE Patents [OSTI]

    Wilding, Bruce M; Turner, Terry D

    2014-12-02T23:59:59.000Z

    A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

  19. THE BROOKHAVEN NATIONAL LABORATORY PERFLUOROCARBON TRACER TECHNOLOGY: A PROVEN AND COST EFFECTIVE METHOD TO VERIFY INTEGRITY AND MONITOR LONG TERM PERFORMANCE OF WALLS, FLOORS, CAPS, AND COVER SYSTEMS.

    SciTech Connect (OSTI)

    HEISER, J.; SULLIVAN, T.

    2002-03-11T23:59:59.000Z

    Currently, containment system failures are detected by monitoring wells downstream of the waste site. Clearly this approach is inefficient, as the contaminants will have migrated from the disposal area before they are detected. Methods that indicate early cover failure (prior to contaminant release) or predict impending cover failure are needed. The Brookhaven National Laboratory (BNL) Perfluorocarbon Tracer (PFT) technology can measure performance changes and integrity losses as the cover ages. This allows early detection of cover failure or pending failure so that repair or replacement can be made before contaminants leave the disposal cell. The PFT technology has been successfully applied to four subsurface barrier problems, one leak detection problem from underground ducts, and one surface cover problem. Testing has demonstrated that the PFTs are capable of accurately detecting and locating leaks down to fractions of an inch. The PFT technology has several advantages over competing approaches. The ability to simultaneously use multiple PFTs separates it from other gas tracer technologies. Using multiple tracers provides independent confirmation of flaw location, helps to clearly define transport pathways, and can be used for confirmatory testing (e.g., repeat the test using a new tracer). The PFT tests provide a direct measure of flaws in a barrier, whereas other measurements (pressure, moisture content, temperature, subsidence) provide indirect measures that need interpretation. The focus of the six PFT demonstrations has been on engineering aspects of the technology with the intent of finding if a flaw existed in the barrier. Work remains to be done on the scientific basis for this technology. This includes determining PFT diffusion rates through various materials (soils and barrier) as a function of moisture content, determining the effects of barometric pumping on PFT flow for cover systems, and determining wind effects on side slopes of cover systems and their impact on PFT performance. It also includes application of models to assist in the design of the monitoring system and the interpretation of the data. The set of demonstrations was performed on small sites (< 1/4 acre). Future work also needs to consider scaling issues to develop and design optimal techniques for delivery and monitoring of the PFTs.

  20. Extraplanar Dust: a Tracer of Cold Dense Gas in the Thick Disks of Spiral Galaxies

    E-Print Network [OSTI]

    J. Christopher Howk

    2004-10-15T23:59:59.000Z

    The interstellar thick disks of galaxies contain not only gas, but significant quantities of dust. Most of our knowledge of extraplanar dust in disk galaxies comes from direct broadband optical imaging of these systems, wherein the dust is identified due to the irregular extinction it produces against the thick disk and bulge stars. This observational technique is sensitive to only the most dense material, and we argue much of the material identified in this way traces a cold phase of the interstellar thick disks in galaxies. The presence of a cold, dense phase likely implies the interstellar pressures in the thick disks of spiral galaxies can be quite high. This dense phase of the interstellar medium may also fueling thick disk star formation, and H-alpha observations are now revealing H II regions around newly-formed OB stars associations in several galaxies. We argue that the large quantities of dust and the morphologies of the structures traced by the dust imply that much of the extraplanar material in disk galaxies must have been expelled from the underlying thin disk.

  1. Method for detecting gas turbine engine flashback

    DOE Patents [OSTI]

    Singh, Kapil Kumar; Varatharajan, Balachandar; Kraemer, Gilbert Otto; Yilmaz, Ertan; Lacy, Benjamin Paul

    2012-09-04T23:59:59.000Z

    A method for monitoring and controlling a gas turbine, comprises predicting frequencies of combustion dynamics in a combustor using operating conditions of a gas turbine, receiving a signal from a sensor that is indicative of combustion dynamics in the combustor, and detecting a flashback if a frequency of the received signal does not correspond to the predicted frequencies.

  2. Gas sensitive materials for gas detection and method of making

    DOE Patents [OSTI]

    Trakhtenberg, Leonid Israilevich; Gerasimov, Genrikh Nikolaevich; Gromov, Vladimir Fedorovich; Rozenberg, Valeriya Isaakovna

    2012-12-25T23:59:59.000Z

    A gas sensitive material comprising SnO2 nanocrystals doped with In2O3 and an oxide of a platinum group metal, and a method of making the same. The platinum group metal is preferably Pd, but also may include Pt, Ru, Ir, and combinations thereof. The SnO2 nanocrystals have a specific surface of 7 or greater, preferably about 20 m2/g, and a mean particle size of between about 10 nm and about 100 nm, preferably about 40 nm. A gas detection device made from the gas sensitive material deposited on a substrate, the gas sensitive material configured as a part of a current measuring circuit in communication with a heat source.

  3. Gas sensitive materials for gas detection and methods of making

    DOE Patents [OSTI]

    Trakhtenberg, Leonid Israilevich; Gerasimov, Genrikh Nikolaevich; Gromov, Vladimir Fedorovich; Rozenberg, Valeriya Isaakovna

    2014-07-15T23:59:59.000Z

    A gas sensitive material comprising SnO.sub.2 nanocrystals doped with In.sub.2O.sub.3 and an oxide of a platinum group metal, and a method of making the same. The platinum group metal is preferably Pd, but also may include Pt, Ru, Ir, and combinations thereof. The SnO.sub.2 nanocrystals have a specific surface of 7 or greater, preferably about 20 m2/g, and a mean particle size of between about 10 nm and about 100 nm, preferably about 40 nm. A gas detection device made from the gas sensitive material deposited on a substrate, the gas sensitive material configured as a part of a current measuring circuit in communication with a heat source.

  4. Innovative techniques for the description of reservoir heterogeneity using tracers. Second technical annual progress report, October 1991--September 1992

    SciTech Connect (OSTI)

    Pope, G.A.; Sepehrnoori, K.

    1992-12-31T23:59:59.000Z

    This second annual report on innovative uses of tracers for reservoir characterization contains four sections each describing a novel use of oilfield tracers. The first section describes and illustrates the use of a new single-well tracer test to estimate wettability. This test consists of the injection of brine containing tracers followed by oil containing tracers, a shut-in period to allow some of the tracers to react, and then production of the tracers. The inclusion of the oil injection slug with tracers is unique to this test, and this is what makes the test work. We adapted our chemical simulator, UTCHEM, to enable us to study this tracer method and made an extensive simulation study to evaluate the effects of wettability based upon characteristic curves for relative permeability and capillary pressure for differing wetting states typical of oil reservoirs. The second section of this report describes a new method for analyzing interwell tracer data based upon a type-curve approach. Theoretical frequency response functions were used to build type curves of ``transfer function`` and ``phase spectrum`` that have dimensionless heterogeneity index as a parameter to characterize a stochastic permeability field. We illustrate this method by analyzing field tracer data. The third section of this report describes a new theory for interpreting interwell tracer data in terms of channeling and dispersive behavior for reservoirs. Once again, a stochastic approach to reservoir description is taken. The fourth section of this report describes our simulation of perfluorocarbon gas tracers. This new tracer technology developed at Brookhaven National Laboratory is being tested at the Elk Hills Naval Petroleum Reserve No. 1 in California. We report preliminary simulations made of these tracers in one of the oil reservoirs under evaluation with these tracers in this field. Our compostional simulator (UTCOMP) was used for this simulation study.

  5. Method for the production of synthesis gas

    SciTech Connect (OSTI)

    Escher, G.; Harjung, J.; Wenning, H.P.

    1981-11-24T23:59:59.000Z

    A method is claimed for the continuous production of synthesis gas comprising of carbon monoxide and hydrogen through the autothermal gasification of solid combustibles in a pressure reactor. The method involves the following: introducing into a screw machine containing two parallely ordered shafts, a finely divided solid combustible; moistening and intimately mixing the solid combustible with 2 to 30% by weight of water, degasing and compressing the moist solid combustible to a pressure higher than that of the reactor; adding the gas-tight compressed and moist solid combustible to a reaction chamber-through a burner where the combustible is brought into contact with the gasification medium; evaporating the water in the compressed and moist solid combustible and producing a comminuted dispersion of the solid combustible in the mixture of the gasification medium and water vapor; reacting the combustible dispersion to give a raw synthesis gas; and removing the raw synthesis gas from the reactor.

  6. Verifying Greenhouse Gas Emissions: Methods to Support International...

    Open Energy Info (EERE)

    Verifying Greenhouse Gas Emissions: Methods to Support International Climate Agreements Jump to: navigation, search Tool Summary Name: Verifying Greenhouse Gas Emissions: Methods...

  7. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, Charles L. (Lincoln, MA); He, Bo X. (Newton, MA)

    1990-01-01T23:59:59.000Z

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from when it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel.

  8. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, C.L.; He, B.X.

    1990-11-13T23:59:59.000Z

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from where it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel. 4 figs.

  9. Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Tracers to Characterize Fractures in Engineered Geothermal Systems Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs...

  10. Conversion method for gas streams containing hydrocarbons

    DOE Patents [OSTI]

    Mallinson, Richard G. (Norman, OK); Lobban, Lance (Norman, OK); Liu, Chang-jun (Tianjin, CN)

    2000-01-01T23:59:59.000Z

    An apparatus and a method of using the apparatus are provided for converting a gas stream containing hydrocarbons to a reaction product containing effluent molecules having at least one carbon atom, having at least one interior surface and at least one exterior surface, a first electrode and a second electrode with the first and second electrodes being selectively movable in relation to each other and positioned within the housing so as to be spatially disposed a predetermined distance from each other, a plasma discharge generator between the first and second electrodes, gas stream introducer and a collector for collecting the reaction product effluent produced by the reaction of the gas stream containing hydrocarbons with the plasma discharge between the first and second electrodes.

  11. Marine electromagnetic methods for gas hydrate characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen Andrea

    2008-01-01T23:59:59.000Z

    1.2 Gas Hydrates . . . . . . . .1.2.1 Distribution of Gas Hydrates . . . . . . . . . . .1.2.2 Importance of Gas Hydrates . . . . .

  12. Marine Electromagnetic Methods for Gas Hydrate Characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen A

    2008-01-01T23:59:59.000Z

    1.2 Gas Hydrates . . . . . . . .1.2.1 Distribution of Gas Hydrates . . . . . . . . . . .1.2.2 Importance of Gas Hydrates . . . . .

  13. Method and apparatus for producing synthesis gas

    DOE Patents [OSTI]

    Hemmings, John William (Katy, TX); Bonnell, Leo (Houston, TX); Robinson, Earl T. (Mentor, OH)

    2010-03-03T23:59:59.000Z

    A method and apparatus for reacting a hydrocarbon containing feed stream by steam methane reforming reactions to form a synthesis gas. The hydrocarbon containing feed is reacted within a reactor having stages in which the final stage from which a synthesis gas is discharged incorporates expensive high temperature materials such as oxide dispersed strengthened metals while upstream stages operate at a lower temperature allowing the use of more conventional high temperature alloys. Each of the reactor stages incorporate reactor elements having one or more separation zones to separate oxygen from an oxygen containing feed to support combustion of a fuel within adjacent combustion zones, thereby to generate heat to support the endothermic steam methane reforming reactions.

  14. Method for controlling gas metal arc welding

    DOE Patents [OSTI]

    Smartt, Herschel B. (Idaho Falls, ID); Einerson, Carolyn J. (Idaho Falls, ID); Watkins, Arthur D. (Idaho Falls, ID)

    1989-01-01T23:59:59.000Z

    The heat input and mass input in a Gas Metal Arc welding process are controlled by a method that comprises calculating appropriate values for weld speed, filler wire feed rate and an expected value for the welding current by algorithmic function means, applying such values for weld speed and filler wire feed rate to the welding process, measuring the welding current, comparing the measured current to the calculated current, using said comparison to calculate corrections for the weld speed and filler wire feed rate, and applying corrections.

  15. Method for controlling gas metal arc welding

    DOE Patents [OSTI]

    Smartt, H.B.; Einerson, C.J.; Watkins, A.D.

    1987-08-10T23:59:59.000Z

    The heat input and mass input in a Gas Metal Arc welding process are controlled by a method that comprises calculating appropriate values for weld speed, filler wire feed rate and an expected value for the welding current by algorithmic function means, applying such values for weld speed and filler wire feed rate to the welding process, measuring the welding current, comparing the measured current to the calculated current, using said comparison to calculate corrections for the weld speed and filler wire feed rate, and applying corrections. 3 figs., 1 tab.

  16. Using dissolved noble gas and isotopic tracers to evaluate the vulnerability of groundwater resources in a small, high elevation catchment to predicted climate changes

    SciTech Connect (OSTI)

    Singleton, M J; Moran, J E

    2009-10-02T23:59:59.000Z

    We use noble gas concentrations and multiple isotopic tracers in groundwater and stream water in a small high elevation catchment to provide a snapshot of temperature, altitude, and physical processes at the time of recharge; and to determine subsurface residence times of different groundwater components. They identify three sources that contribute to groundwater flow: (1) seasonal groundwater recharge with short travel times, (2) water from bedrock aquifers that have elevated radiogenic {sup 4}He, and (3) upwelling of deep fluids that have 'mantle' helium and hydrothermal carbon isotope signatures. Although a bimodal distribution in apparent groundwater age indicates that groundwater storage times range from less than a year to several decades, water that recharges seasonally is the largest likely contributor to stream baseflow. Under climate change scnearios with earlier snowmelt, the groundwater that moves through the alluvial aquifer seasonally will be depleted earlier, providing less baseflow and possible extreme low flows in the creek during summer and fall. Dissolved noble gas measurements indciate recharge temperatures are 5 to 11 degrees higher than would be expected for direct influx of snowmelt, and that excess air concentrations are lower than would be expected for recharge through bedrock fractures. Instead, recharge likely occurs over diffuse vegetated areas, as indicated by {delta}{sup 13}C-DIC values that are consistent with incorporation of CO{sub 2} from soil respiration. Recharge temperatures are close to or slightly higher than mean annual air temperature, and are consistent with recharge during May and June, when snowpack melting occurs.

  17. Petroleum characterization by perfluorocarbon tracers

    SciTech Connect (OSTI)

    Senum, G.I.; Fajer, R.W. (Brookhaven National Lab., Upton, NY (United States)); Harris, B.R. Jr. (USDOE Naval Petroleum Reserves in California, Tupman, CA (United States)); DeRose, W.E. (Bechtel Petroleum Operations, Inc., Tupman, CA (United States)); Ottaviani, W.L. (Chevron U.S.A., Inc., Bakersfield, CA (United States))

    1992-02-01T23:59:59.000Z

    Perfluorocarbon tracers (PFTs), a class of six compounds, were used to help characterize the Shallow Oil Zone (SOZ) reservoir at the Naval Petroleum Reserve in California (NPRC) at Elk Hills. The SOZ reservoir is undergoing a pilot gas injection program to assess the technical feasibility and economic viability of injecting gas into the SOZ for improved oil recovery. PFTs were utilized in the pilot gas injection to qualitatively assess the extent of the pilot gas injection so as to determine the degree of gas containment within the SOZ reservoir.

  18. Method for route selection of transcontinental natural gas pipelines

    E-Print Network [OSTI]

    Kouroupetroglou, Georgios

    1 Method for route selection of transcontinental natural gas pipelines Fotios G. Thomaidis1@kepa.uoa.gr Abstract. The route of transcontinental natural gas pipelines is characterized by complexity, compared choices. Keywords: Optimum route method, natural gas, transcontinental pipelines, Caspian Region ­ E

  19. Methods developed for detecting hazardous elements in produced gas

    SciTech Connect (OSTI)

    Chao, S.; Attari, A. (Inst. of Gas Technology, Des Plaines, IL (United States))

    1995-01-16T23:59:59.000Z

    The Institute of Gas Technology, Des Plaines, Ill. has been developing sampling and analytical methods to detect in natural gas various trace constituents that may pose health, safety, or operational risks. The constituents of interest include paraffinic and aromatic hydrocarbons, H[sub 2]S, organic sulfur compounds, arsenic, mercury, radon, and others. Better sampling and analytical techniques for produced natural gas, similar to those developed by IGT for processed gas, will enhance producers and processors' abilities to monitor undesirable constituents in raw gas streams and improve their clean-up processes. The methods developed at IGT were modifications of air sampling and analytical methods that are commonly used for air toxic substances. These monitoring methods, when applied to natural gas, present special challenges because gas has a much more complex matrix than the air. Methods for the analysis of the following are discussed: arsenic, mercury, radon, sulfur compounds, hydrocarbons, and aromatics including BTEX and PAHs.

  20. System and method for detecting gas

    DOE Patents [OSTI]

    Chow, Oscar Ken (Simsbury, CT); Moulthrop, Lawrence Clinton (Windsor, CT); Dreier, Ken Wayne (Madison, CT); Miller, Jacob Andrew (Dexter, MI)

    2010-03-16T23:59:59.000Z

    A system to detect a presence of a specific gas in a mixture of gaseous byproducts comprising moisture vapor is disclosed. The system includes an electrochemical cell, a transport to deliver the mixture of gaseous byproducts from the electrochemical cell, a gas sensor in fluid communication with the transport, the sensor responsive to a presence of the specific gas to generate a signal corresponding to a concentration of the specific gas, and a membrane to prevent transmission of liquid moisture, the membrane disposed between the transport and the gas sensor.

  1. Method for mapping a natural gas leak

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2009-02-03T23:59:59.000Z

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formatted into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimposed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  2. Method and apparatus for manufacturing gas tags

    DOE Patents [OSTI]

    Gross, Kenny C. (Bolingbrook, IL); Laug, Matthew T. (Idaho Falls, ID)

    1996-01-01T23:59:59.000Z

    For use in the manufacture of gas tags employed in a gas tagging failure detection system for a nuclear reactor, a plurality of commercial feed gases each having a respective noble gas isotopic composition are blended under computer control to provide various tag gas mixtures having selected isotopic ratios which are optimized for specified defined conditions such as cost. Using a new approach employing a discrete variable structure rather than the known continuous-variable optimization problem, the computer controlled gas tag manufacturing process employs an analytical formalism from condensed matter physics known as stochastic relaxation, which is a special case of simulated annealing, for input feed gas selection. For a tag blending process involving M tag isotopes with N distinct feed gas mixtures commercially available from an enriched gas supplier, the manufacturing process calculates the cost difference between multiple combinations and specifies gas mixtures which approach the optimum defined conditions. The manufacturing process is then used to control tag blending apparatus incorporating tag gas canisters connected by stainless-steel tubing with computer controlled valves, with the canisters automatically filled with metered quantities of the required feed gases.

  3. Method and apparatus for manufacturing gas tags

    DOE Patents [OSTI]

    Gross, K.C.; Laug, M.T.

    1996-12-17T23:59:59.000Z

    For use in the manufacture of gas tags employed in a gas tagging failure detection system for a nuclear reactor, a plurality of commercial feed gases each having a respective noble gas isotopic composition are blended under computer control to provide various tag gas mixtures having selected isotopic ratios which are optimized for specified defined conditions such as cost. Using a new approach employing a discrete variable structure rather than the known continuous-variable optimization problem, the computer controlled gas tag manufacturing process employs an analytical formalism from condensed matter physics known as stochastic relaxation, which is a special case of simulated annealing, for input feed gas selection. For a tag blending process involving M tag isotopes with N distinct feed gas mixtures commercially available from an enriched gas supplier, the manufacturing process calculates the cost difference between multiple combinations and specifies gas mixtures which approach the optimum defined conditions. The manufacturing process is then used to control tag blending apparatus incorporating tag gas canisters connected by stainless-steel tubing with computer controlled valves, with the canisters automatically filled with metered quantities of the required feed gases. 4 figs.

  4. atmospheric tracer experiments: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    112 6.1. Meteorological conditions 112 6.2. Roughness length 6 Uncertainties in gas exchange parameterization during the SAGE dual-tracer experiment Geosciences Websites...

  5. Method for processing coke oven gas

    SciTech Connect (OSTI)

    Flockenhaus, C.; Meckel, J.F.; Wagener, D.

    1980-11-25T23:59:59.000Z

    Coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation or any purification operation other than desulfurization, to a catalytic cracking operation to form a hot cracked gas which is rich in hydrogen and carbon monoxide. The catalytic cracking reaction is carried out in the presence of a hydrogen-containing and/or CO2-containing gas, with a steam reforming catalyst.

  6. System and method for cooling a combustion gas charge

    DOE Patents [OSTI]

    Massey, Mary Cecelia; Boberg, Thomas Earl

    2010-05-25T23:59:59.000Z

    The present invention relates to a system and method for cooling a combustion gas charge prior. The combustion gas charge may include compressed intake air, exhaust gas, or a mixture thereof. An evaporator is provided that may then receive a relatively high temperature combustion gas charge and discharge at a relatively lower temperature. The evaporator may be configured to operate with refrigeration cycle components and/or to receive a fluid below atmospheric pressure as the phase-change cooling medium.

  7. An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs...

    Open Energy Info (EERE)

    Method For Exploration Of Gas Hydrate Reservoirs In Marine Areas Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: An Integrated Study Method For...

  8. Method and apparatus for pressurizing a liquefied gas

    DOE Patents [OSTI]

    Bingham, Dennis N.

    2005-07-26T23:59:59.000Z

    Apparatus providing at least one thermoelectric device for pressurizing a liquefied gas container and methods employing same are disclosed. A thermoelectric device including a heating surface and a cooling surface is used for pressurizing a container by vaporizing liquefied gas within the container by transferring heat energy from a portion of the liquefied gas in contact with the cooling surface to another portion of the liquefied gas in contact with the heating surface of the thermoelectric device to convert some of the liquefied gas to a vapor state. Liquefied gas vapor and/or liquid phase may be supplied by disclosed apparatus and methods. The apparatus may also be used as a vapor pump or a liquid pump, or fluid pump. Methods of operation are also disclosed.

  9. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, Stark County, OH)

    1998-08-18T23:59:59.000Z

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  10. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, OH)

    1998-09-29T23:59:59.000Z

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  11. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-09-29T23:59:59.000Z

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  12. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-08-18T23:59:59.000Z

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  13. Method and apparatus for recovering a gas from a gas hydrate located on the ocean floor

    DOE Patents [OSTI]

    Wyatt, Douglas E. (Aiken, SC)

    2001-01-01T23:59:59.000Z

    A method and apparatus for recovering a gas from a gas hydrate on the ocean floor includes a flexible cover, a plurality of steerable base members secured to the cover, and a steerable mining module. A suitable source for inflating the cover over the gas hydrate deposit is provided. The mining module, positioned on the gas hydrate deposit, is preferably connected to the cover by a control cable. A gas retrieval conduit or hose extends upwardly from the cover to be connected to a support ship on the ocean surface.

  14. Method for nonlinear optimization for gas tagging and other systems

    DOE Patents [OSTI]

    Chen, T.; Gross, K.C.; Wegerich, S.

    1998-01-06T23:59:59.000Z

    A method and system are disclosed for providing nuclear fuel rods with a configuration of isotopic gas tags. The method includes selecting a true location of a first gas tag node, selecting initial locations for the remaining n-1 nodes using target gas tag compositions, generating a set of random gene pools with L nodes, applying a Hopfield network for computing on energy, or cost, for each of the L gene pools and using selected constraints to establish minimum energy states to identify optimal gas tag nodes with each energy compared to a convergence threshold and then upon identifying the gas tag node continuing this procedure until establishing the next gas tag node until all remaining n nodes have been established. 6 figs.

  15. Method for nonlinear optimization for gas tagging and other systems

    DOE Patents [OSTI]

    Chen, Ting (Chicago, IL); Gross, Kenny C. (Bolingbrook, IL); Wegerich, Stephan (Glendale Heights, IL)

    1998-01-01T23:59:59.000Z

    A method and system for providing nuclear fuel rods with a configuration of isotopic gas tags. The method includes selecting a true location of a first gas tag node, selecting initial locations for the remaining n-1 nodes using target gas tag compositions, generating a set of random gene pools with L nodes, applying a Hopfield network for computing on energy, or cost, for each of the L gene pools and using selected constraints to establish minimum energy states to identify optimal gas tag nodes with each energy compared to a convergence threshold and then upon identifying the gas tag node continuing this procedure until establishing the next gas tag node until all remaining n nodes have been established.

  16. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond (Avondale, AZ)

    2012-08-07T23:59:59.000Z

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  17. Method and apparatus for off-gas composition sensing

    DOE Patents [OSTI]

    Ottesen, David Keith (Livermore, CA); Allendorf, Sarah Williams (Fremont, CA); Hubbard, Gary Lee (Richmond, CA); Rosenberg, David Ezechiel (Columbia, MD)

    1999-01-01T23:59:59.000Z

    An apparatus and method for non-intrusive collection of off-gas data in a steelmaking furnace includes structure and steps for transmitting a laser beam through the off-gas produced by a steelmaking furnace, for controlling the transmitting to repeatedly scan the laser beam through a plurality of wavelengths in its tuning range, and for detecting the laser beam transmitted through the off-gas and converting the detected laser beam to an electrical signal. The electrical signal is processed to determine characteristics of the off-gas that are used to analyze and/or control the steelmaking process.

  18. Method of preparing pure fluorine gas

    DOE Patents [OSTI]

    Asprey, Larned B. (Los Alamos, NM)

    1976-01-01T23:59:59.000Z

    A simple, inexpensive system for purifying and storing pure fluorine is described. The method utilizes alkali metal-nickel fluorides to absorb tank fluorine by forming nickel complex salts and leaving the gaseous impurities which are pumped away. The complex nickel fluoride is then heated to evolve back pure gaseous fluorine.

  19. Method of gas purification and system therefor

    DOE Patents [OSTI]

    Szwarc, R.

    1983-12-29T23:59:59.000Z

    A method and device are disclosed for conducting gettering. The gettering is conducted with one of an LiB, LiSi or LiAl system. Preferably the LiB system is of the formula Li/sub x/B/sub 1-x/ wherein 0 < x < 1 with gettering conducted at room or slightly elevated temperature of about 100 to 200/sup 0/C.

  20. Method of removing nitrogen oxides from exhaust gas mixtures

    SciTech Connect (OSTI)

    Batha, H.D.; Mason, J.H.; Thompson, S.R.

    1980-03-04T23:59:59.000Z

    A method of removing nitrogen oxides (NOX) from exhaust gas mixtures is described. The removal of NOX from exhaust gas mixtures is accomplished by exposing the exhaust gas mixture, in a manner that does not substantially impede the gas flow, to a ceramic material containing from about 75% to about 95% by weight silicon carbide and from about 0.3% to about 10.0% silica. A reduction of at least 85% of NOX from the mixture is to be expected and reductions up to 95 to 100% are attainable. Ceramic mixtures containing silicon nitride in amounts between about 10% and about 30% are found to reduce the amount of NOX in exhaust gases at temperatures as low as 200* C.

  1. Method and apparatus for fuel gas moisturization and heating

    DOE Patents [OSTI]

    Ranasinghe, Jatila (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01T23:59:59.000Z

    Fuel gas is saturated with water heated with a heat recovery steam generator heat source. The heat source is preferably a water heating section downstream of the lower pressure evaporator to provide better temperature matching between the hot and cold heat exchange streams in that portion of the heat recovery steam generator. The increased gas mass flow due to the addition of moisture results in increased power output from the gas and steam turbines. Fuel gas saturation is followed by superheating the fuel, preferably with bottom cycle heat sources, resulting in a larger thermal efficiency gain compared to current fuel heating methods. There is a gain in power output compared to no fuel heating, even when heating the fuel to above the LP steam temperature.

  2. Method for eliminating gas blocking in electrokinetic pumping systems

    DOE Patents [OSTI]

    Arnold, Don W. (Livermore, CA); Paul, Phillip H. (Livermore, CA); Schoeniger, Joseph S. (Oakland, CA)

    2001-09-11T23:59:59.000Z

    A method for eliminating gas bubble blockage of current flow during operation of an electrokinetic pump. By making use of the ability to modify the surface charge on the porous dielectric medium used in electrokinetic pumps, it becomes possible to place electrodes away from the pressurized region of the electrokinetic pump. While gas is still generated at the electrodes they are situated such that the generated gas can escape into a larger buffer reservoir and not into the high pressure region of the pump where the gas bubbles can interrupt current flow. Various combinations of porous dielectric materials and ionic conductors can be used to create pumps that have desirable electrical, material handling, and flow attributes.

  3. Method for treating a nuclear process off-gas stream

    DOE Patents [OSTI]

    Pence, Dallas T. (San Diego, CA); Chou, Chun-Chao (San Diego, CA)

    1984-01-01T23:59:59.000Z

    Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

  4. Control method for mixed refrigerant based natural gas liquefier

    DOE Patents [OSTI]

    Kountz, Kenneth J. (Palatine, IL); Bishop, Patrick M. (Chicago, IL)

    2003-01-01T23:59:59.000Z

    In a natural gas liquefaction system having a refrigerant storage circuit, a refrigerant circulation circuit in fluid communication with the refrigerant storage circuit, and a natural gas liquefaction circuit in thermal communication with the refrigerant circulation circuit, a method for liquefaction of natural gas in which pressure in the refrigerant circulation circuit is adjusted to below about 175 psig by exchange of refrigerant with the refrigerant storage circuit. A variable speed motor is started whereby operation of a compressor is initiated. The compressor is operated at full discharge capacity. Operation of an expansion valve is initiated whereby suction pressure at the suction pressure port of the compressor is maintained below about 30 psig and discharge pressure at the discharge pressure port of the compressor is maintained below about 350 psig. Refrigerant vapor is introduced from the refrigerant holding tank into the refrigerant circulation circuit until the suction pressure is reduced to below about 15 psig, after which flow of the refrigerant vapor from the refrigerant holding tank is terminated. Natural gas is then introduced into a natural gas liquefier, resulting in liquefaction of the natural gas.

  5. Tracer studies of sheet flow in the Florida Everglades David T. Ho,1,2

    E-Print Network [OSTI]

    Ho, David

    Tracer Release Experiment (EverTREx), two SF6 tracer releases were conducted to measure sheet flow. [5] EverTREx represents the first application of sulfur hexafluoride (SF6) in a shallow-water vegetated environ- ment. SF6, a gas tracer that has been applied previously in investigations of transport

  6. Selection of hydrate suppression methods for gas streams

    SciTech Connect (OSTI)

    Behrens, S.D.; Covington, K.K.; Collie, J.T. III

    1999-07-01T23:59:59.000Z

    This paper will discuss and compare the methods used to suppress hydrate formation in natural gas streams. Included in the comparison will be regenerated systems using ethylene glycol and non-regenerated systems using methanol. A comparison will be made between the quantities of methanol and ethylene glycol required to achieve a given a suppression. A discussion of BTEX emissions resulting from the ethylene glycol regenerator along with the effect or process variables on these emissions is also given.

  7. Method and apparatus for controlling gas evolution from chemical reactions

    DOE Patents [OSTI]

    Skorpik, James R. (Kennewick, WA); Dodson, Michael G. (Richland, WA)

    1999-01-01T23:59:59.000Z

    The present invention is directed toward monitoring a thermally driven gas evolving chemical reaction with an acoustic apparatus. Signals from the acoustic apparatus are used to control a heater to prevent a run-away condition. A digestion module in combination with a robotic arm further automate physical handling of sample material reaction vessels. The invention is especially useful for carrying out sample procedures defined in EPA Methods SW-846.

  8. Method and apparatus for controlling gas evolution from chemical reactions

    DOE Patents [OSTI]

    Skorpik, J.R.; Dodson, M.G.

    1999-05-25T23:59:59.000Z

    The present invention is directed toward monitoring a thermally driven gas evolving chemical reaction with an acoustic apparatus. Signals from the acoustic apparatus are used to control a heater to prevent a run-away condition. A digestion module in combination with a robotic arm further automate physical handling of sample material reaction vessels. The invention is especially useful for carrying out sample procedures defined in EPA Methods SW-846. 8 figs.

  9. Self-contained cryogenic gas sampling apparatus and method

    DOE Patents [OSTI]

    McManus, G.J.; Motes, B.G.; Bird, S.K.; Kotter, D.K.

    1996-03-26T23:59:59.000Z

    Apparatus for obtaining a whole gas sample, is composed of: a sample vessel having an inlet for receiving a gas sample; a controllable valve mounted for controllably opening and closing the inlet; a valve control coupled to the valve for opening and closing the valve at selected times; a portable power source connected for supplying operating power to the valve control; and a cryogenic coolant in thermal communication with the vessel for cooling the interior of the vessel to cryogenic temperatures. A method is described for obtaining an air sample using the apparatus described above, by: placing the apparatus at a location at which the sample is to be obtained; operating the valve control to open the valve at a selected time and close the valve at a selected subsequent time; and between the selected times maintaining the vessel at a cryogenic temperature by heat exchange with the coolant. 3 figs.

  10. Self-contained cryogenic gas sampling apparatus and method

    DOE Patents [OSTI]

    McManus, Gary J. (Idaho Falls, ID); Motes, Billy G. (Idaho Falls, ID); Bird, Susan K. (Idaho Falls, ID); Kotter, Dale K. (Shelley, ID)

    1996-01-01T23:59:59.000Z

    Apparatus for obtaining a whole gas sample, composed of: a sample vessel having an inlet for receiving a gas sample; a controllable valve mounted for controllably opening and closing the inlet; a valve control coupled to the valve for opening and closing the valve at selected times; a portable power source connected for supplying operating power to the valve control; and a cryogenic coolant in thermal communication with the vessel for cooling the interior of the vessel to cryogenic temperatures. A method of obtaining an air sample using the apparatus described above, by: placing the apparatus at a location at which the sample is to be obtained; operating the valve control to open the valve at a selected time and close the valve at a selected subsequent time; and between the selected times maintaining the vessel at a cryogenic temperature by heat exchange with the coolant.

  11. Tracers and Tracer Interpretation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown of Ladoga, Indiana (Utility Company) Jump to:TownTownerOpenEnergyG,Tracers and

  12. Development of NDE methods for hot gas filters.

    SciTech Connect (OSTI)

    Deemer, C.; Ellingson, W. A.; Koehl, E. R.; Lee, H.; Spohnholtz, T.; Sun, J. G.

    1999-07-21T23:59:59.000Z

    Ceramic hot gas candle filters are currently under development for hot gas particulate cleanup in advanced coal-based power systems. The ceramic materials for these filters include nonoxide monolithic, nonoxide-fiber-reinforced composites, and nonoxide reticulated foam. A concern is the lack of reliable data on which to base decisions for reusing or replacing hot gas filters during plant shutdowns. The work in this project is aimed at developing nondestructive evaluation (FIDE) technology to allow detection, and determination of extent, of life-limiting characteristics such as thermal fatigue, oxidation, damage from ash bridging such as localized cracking, damage from local burning, and elongation at elevated temperature. Although in-situ NDE methods are desirable in order to avoid disassembly of the candle filter vessels, the current vessel designs, the presence of filter cakes and possible ash bridging, and the state of NDE technology prevent this. Candle filter producers use a variety of NDE methods to ensure as-produced quality. While impact acoustic resonance offers initial promise for examining new as-produced filters and for detecting damage in some monolithic filters when removed from service, it presents difficulties in data interpretation, it lacks localization capability, and its applicability to composites has yet to be demonstrated. Additional NDE technologies being developed and evaluated in this program and whose applicability to both monolithics and composites has been demonstrated include (a) full-scale thermal imaging for analyzing thermal property variations; (b) fret, high-spatial-resolution X-ray imaging for detecting density variations and dimensional changes; (c) air-coupled ultrasonic methods for determining through-thickness compositional variations; and (d) acoustic emission technology with mechanical loading for detecting localized bulk damage. New and exposed clay-bonded SiC filters and CVI-SiC composite filters have been tested with these additional NDE methods.

  13. Investigation of two-fluid methods for Large Eddy Simulation of spray combustion in Gas Turbines

    E-Print Network [OSTI]

    Investigation of two-fluid methods for Large Eddy Simulation of spray combustion in Gas Turbines the EL method well suited for gas turbine computations, but RANS with the EE approach may also be found

  14. Method and apparatus for dispensing compressed natural gas and liquified natural gas to natural gas powered vehicles

    DOE Patents [OSTI]

    Bingham, Dennis A.; Clark, Michael L.; Wilding, Bruce M.; Palmer, Gary L.

    2005-05-31T23:59:59.000Z

    A fueling facility and method for dispensing liquid natural gas (LNG), compressed natural gas (CNG) or both on-demand. The fueling facility may include a source of LNG, such as cryogenic storage vessel. A low volume high pressure pump is coupled to the source of LNG to produce a stream of pressurized LNG. The stream of pressurized LNG may be selectively directed through an LNG flow path or to a CNG flow path which includes a vaporizer configured to produce CNG from the pressurized LNG. A portion of the CNG may be drawn from the CNG flow path and introduced into the CNG flow path to control the temperature of LNG flowing therethrough. Similarly, a portion of the LNG may be drawn from the LNG flow path and introduced into the CNG flow path to control the temperature of CNG flowing therethrough.

  15. Method For Enhanced Gas Monitoring In High Density Flow Streams

    DOE Patents [OSTI]

    Von Drasek, William A. (Oak Forest, IL); Mulderink, Kenneth A. (Countryside, IL); Marin, Ovidiu (Lisle, IL)

    2005-09-13T23:59:59.000Z

    A method for conducting laser absorption measurements in high temperature process streams having high levels of particulate matter is disclosed. An impinger is positioned substantially parallel to a laser beam propagation path and at upstream position relative to the laser beam. Beam shielding pipes shield the beam from the surrounding environment. Measurement is conducted only in the gap between the two shielding pipes where the beam propagates through the process gas. The impinger facilitates reduced particle presence in the measurement beam, resulting in improved SNR (signal-to-noise) and improved sensitivity and dynamic range of the measurement.

  16. Adsorptive method for the separation of a gas mixture

    SciTech Connect (OSTI)

    Linde, G.

    1984-05-15T23:59:59.000Z

    A method of recovering at least two product fractions each highly enriched in a respective component of a gas mixture containing at least such components are recovered by separating a stream of the mixture into at least two partial streams and passing this stream separately through respective beds of respective adsorbents and selectively retaining at least one component from each mixture so that the respective product fractions emerge from the adsorbents highly enriched in respective components of this mixture, each adsorbent for a particular one of the fractions has a composition that retains at least one component in which the other fractions is enriched.

  17. An improved method for the determination of the wellstream gas specific gravity for retrograde gases

    E-Print Network [OSTI]

    Gold, David Keith

    1988-01-01T23:59:59.000Z

    calculations. The wellstream gas specific gravity for a retrograde gas reservoir can be determined using two methods. The first method requires fluid samples of the primary separator liquid and gas to be obtained from the well, their respective compositions... the most accurate estimate of the wellstream gas specific gravity, but using the field production information can provide a very reliable estimate as well. The equation for calculating the wellstream gas specific gravity using production information...

  18. Apparatus and method for monitoring of gas having stable isotopes

    DOE Patents [OSTI]

    Clegg, Samuel M; Fessenden-Rahn, Julianna E

    2013-03-05T23:59:59.000Z

    Gas having stable isotopes is monitored continuously by using a system that sends a modulated laser beam to the gas and collects and transmits the light not absorbed by the gas to a detector. Gas from geological storage, or from the atmosphere can be monitored continuously without collecting samples and transporting them to a lab.

  19. Completion methods in thick, multilayered tight gas sands

    E-Print Network [OSTI]

    Ogueri, Obinna Stavely

    2009-05-15T23:59:59.000Z

    Tight gas sands, coal-bed methane, and gas shales are commonly called unconventional reservoirs. Tight gas sands (TGS) are often described as formations with an expected average permeability of 0.1mD or less. Gas production rates from TGS reservoirs...

  20. Completion methods in thick, multilayered tight gas sands

    E-Print Network [OSTI]

    Ogueri, Obinna Stavely

    2008-10-10T23:59:59.000Z

    Tight gas sands, coal-bed methane, and gas shales are commonly called unconventional reservoirs. Tight gas sands (TGS) are often described as formations with an expected average permeability of 0.1mD or less. Gas production rates from TGS reservoirs...

  1. Enhanced Oil Recovery: Aqueous Flow Tracer Measurement

    SciTech Connect (OSTI)

    Joseph Rovani; John Schabron

    2009-02-01T23:59:59.000Z

    A low detection limit analytical method was developed to measure a suite of benzoic acid and fluorinated benzoic acid compounds intended for use as tracers for enhanced oil recovery operations. Although the new high performance liquid chromatography separation successfully measured the tracers in an aqueous matrix at low part per billion levels, the low detection limits could not be achieved in oil field water due to interference problems with the hydrocarbon-saturated water using the system's UV detector. Commercial instrument vendors were contacted in an effort to determine if mass spectrometry could be used as an alternate detection technique. The results of their work demonstrate that low part per billion analysis of the tracer compounds in oil field water could be achieved using ultra performance liquid chromatography mass spectrometry.

  2. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R.K.; Im, K.H.

    1996-04-02T23:59:59.000Z

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines. 13 figs.

  3. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R. K. (6440 Hillcrest Dr., Burr Ridge, IL 60521); Im, K. H. (925 Lehigh Cir., Naperville, IL 60565)

    1996-01-01T23:59:59.000Z

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

  4. Method for controlling exhaust gas heat recovery systems in vehicles

    DOE Patents [OSTI]

    Spohn, Brian L.; Claypole, George M.; Starr, Richard D

    2013-06-11T23:59:59.000Z

    A method of operating a vehicle including an engine, a transmission, an exhaust gas heat recovery (EGHR) heat exchanger, and an oil-to-water heat exchanger providing selective heat-exchange communication between the engine and transmission. The method includes controlling a two-way valve, which is configured to be set to one of an engine position and a transmission position. The engine position allows heat-exchange communication between the EGHR heat exchanger and the engine, but does not allow heat-exchange communication between the EGHR heat exchanger and the oil-to-water heat exchanger. The transmission position allows heat-exchange communication between the EGHR heat exchanger, the oil-to-water heat exchanger, and the engine. The method also includes monitoring an ambient air temperature and comparing the monitored ambient air temperature to a predetermined cold ambient temperature. If the monitored ambient air temperature is greater than the predetermined cold ambient temperature, the two-way valve is set to the transmission position.

  5. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean (Castle Rock, CO); Schlager, Richard John (Aurora, CO); Ebner, Timothy George (Westminster, CO); Stewart, Robin Michele (Arvada, CO); Hyatt, David E. (Denver, CO); Bustard, Cynthia Jean (Littleton, CO); Sjostrom, Sharon (Denver, CO)

    1998-01-01T23:59:59.000Z

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  6. Apparatus for the liquefaction of a gas and methods relating to same

    DOE Patents [OSTI]

    Turner, Terry D. (Idaho Falls, ID) [Idaho Falls, ID; Wilding, Bruce M. (Idaho Falls, ID) [Idaho Falls, ID; McKellar, Michael G. (Idaho Falls, ID) [Idaho Falls, ID

    2009-12-29T23:59:59.000Z

    Apparatuses and methods are provided for producing liquefied gas, such as liquefied natural gas. In one embodiment, a liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream may be sequentially pass through a compressor and an expander. The process stream may also pass through a compressor. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. A portion of the liquid gas may be used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line.

  7. Method of coverning the working gas temperature of a solar heated hot gas engine

    SciTech Connect (OSTI)

    Almstrom, S.-H.; Nelving, H.G.

    1984-07-03T23:59:59.000Z

    A closed-cycle hot gas engine heated by solar radiation is provided with a governing system varying the working gas pressure so as to vary the power output at a constant high temperature level of the working gas and-at least partly-at a constant engine speed.

  8. Method of governing the working gas temperature of a solar heated hot gas engine

    SciTech Connect (OSTI)

    Almstrom, S.H.; Nelving, H.G.

    1984-07-03T23:59:59.000Z

    A closed-cycle hot gas engine heated by solar radiation is provided with a governing system varying the working gas pressure so as to vary the power output at a constant high temperature level of the working gas and-at least partly-at a constant engine speed.

  9. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2006-04-25T23:59:59.000Z

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  10. Methods For Delivering Liquified Gas To An Engine

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); O'Brien, James E. (Idaho Falls, ID); Siahpush, Ali S. (Idaho Falls, ID); Brown, Kevin B. (Idaho Falls, ID)

    2005-10-11T23:59:59.000Z

    A liquified gas delivery system for a motorized platform includes a holding tank configured to receive liquified gas. A first conduit extends from a vapor holding portion of the tank to a valve device. A second conduit extends from a liquid holding portion of the tank to the valve device. Fluid coupled to the valve device is a vaporizer which is in communication with an engine. The valve device selectively withdraws either liquified gas or liquified gas vapor from the tank depending on the pressure within the vapor holding portion of the tank. Various configurations of the delivery system can be utilized for pressurizing the tank during operation.

  11. Systems and method for delivering liquified gas to an engine

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); O'Brien, James E. (Idaho Falls, ID); Siahpush, Ali S. (Idaho Falls, ID); Brown, Kevin B. (Idaho Falls, ID)

    2002-01-01T23:59:59.000Z

    A liquified gas delivery system for a motorized platform includes a holding tank configured to receive liquified gas. A first conduit extends from a vapor holding portion of the tank to a valve device. A second conduit extends from a liquid holding portion of the tank to the valve device. Fluid coupled to the valve device is a vaporizer which is in communication with an engine. The valve device selectively withdraws either liquified gas or liquified gas vapor from the tank depending on the pressure within the vapor holding portion of the tank. Various configurations of the delivery system can be utilized for pressurizing the tank during operation.

  12. Method for the removal of elemental mercury from a gas stream

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Downers Grove, IL); Huang, Hann-Sheng (Darien, IL)

    1999-01-01T23:59:59.000Z

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents.

  13. Method for the removal of elemental mercury from a gas stream

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Huang, H.S.

    1999-05-04T23:59:59.000Z

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents. 7 figs.

  14. Application of the Cell Potential Method To Predict Phase Equilibria of Multicomponent Gas Hydrate Systems

    E-Print Network [OSTI]

    Bazant, Martin Z.

    Application of the Cell Potential Method To Predict Phase Equilibria of Multicomponent Gas Hydrate the first documentation nearly two centuries ago,2 natural gas clathrate-hydrates, called clathrates, have at understanding and avoiding clathrate formation. More recently, natural gas hydrates have been proposed

  15. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Turner, Terry D. (Ammon, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID)

    2009-09-22T23:59:59.000Z

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates a vapor from the liquid natural gas. A portion of the liquid gas is used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line or recirculation within the system for further processing.

  16. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

    1998-11-10T23:59:59.000Z

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

  17. Method of cooling gas only nozzle fuel tip

    DOE Patents [OSTI]

    Bechtel, William Theodore (Scotia, NY); Fitts, David Orus (Ballston Spa, NY); DeLeonardo, Guy Wayne (Glenville, NY)

    2002-01-01T23:59:59.000Z

    A diffusion flame nozzle gas tip is provided to convert a dual fuel nozzle to a gas only nozzle. The nozle tip diverts compressor discharge air from the passage feeding the diffusion nozzle air swirl vanes to a region vacated by removal of the dual fuel components, so that the diverted compressor discharge air can flow to and through effusion holes in the end cap plate of the nozzle tip. In a preferred embodiment, the nozzle gas tip defines a cavity for receiving the compressor discharge air from a peripheral passage of the nozzle for flow through the effusion openings defined in the end cap plate.

  18. Method for combined removal of mercury and nitrogen oxides from off-gas streams

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

    2006-10-10T23:59:59.000Z

    A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

  19. Comparison of Various Deterministic Forecasting Techniques in Shale Gas Reservoirs with Emphasis on the Duong Method

    E-Print Network [OSTI]

    Joshi, Krunal Jaykant

    2012-10-19T23:59:59.000Z

    There is a huge demand in the industry to forecast production in shale gas reservoirs accurately. There are many methods including volumetric, Decline Curve Analysis (DCA), analytical simulation and numerical simulation. Each one of these methods...

  20. Method and apparatus for processing exhaust gas with corona discharge

    DOE Patents [OSTI]

    Barlow, S.E.; Orlando, T.M.; Tonkyn, R.G.

    1999-06-22T23:59:59.000Z

    The present invention is placing a catalyst coating upon surfaces surrounding a volume containing corona discharge. In addition, the electrodes are coated with a robust dielectric material. Further, the electrodes are arranged so that at least a surface portion of each electrode extends into a flow path of the exhaust gas to be treated and there is only exhaust gas in the volume between each pair of electrodes. 12 figs.

  1. Method and apparatus for processing exhaust gas with corona discharge

    DOE Patents [OSTI]

    Barlow, Stephan E. (Richland, WA); Orlando, Thomas M. (Kennewick, WA); Tonkyn, Russell G. (Kennewick, WA)

    1999-01-01T23:59:59.000Z

    The present invention is placing a catalyst coating upon surfaces surrounding a volume containing corona discharge. In addition, the electrodes are coated with a robust dielectric material. Further, the electrodes are arranged so that at least a surface portion of each electrode extends into a flow path of the exhaust gas to be treated and there is only exhaust gas in the volume between each pair of electrodes.

  2. Radiative feedback and cosmic molecular gas: numerical method

    E-Print Network [OSTI]

    Margarita Petkova; Umberto Maio

    2012-02-27T23:59:59.000Z

    We present results from self-consistent 3D numerical simulations of cosmic structure formation with a multi-frequency radiative transfer scheme and non-equilibrium molecular chemistry of 13 primordial species (e-, H, H+, H-, He, He+, He++, H2, H2+, D, D+, HD, HeH+), performed by using the simulation code GADGET. We describe our implementation and show tests for ionized sphere expansion in a static and dynamic density field around a central radiative source, and for cosmological abundance evolution coupled with the cosmic microwave background radiation. As a demonstrative application of radiative feedback on molecular gas, we run also cosmological simulations of early structure formation in a ~1Mpc size box. Our tests agree well with analytical and numerical expectations. Consistently with other works, we find that ionization fronts from central sources can boost H2 fractions in shock-compressed gas. The tight dependence on H2 lead to a corresponding boost of HD fractions, as well. We see a strong lowering of the the typical molecular abundances up to several orders of magnitudes which partially hinders further gas collapse of pristine neutral gas, and clearly suggests the need of re-ionized gas or metal cooling for the formation of the following generation of structures.

  3. Method for removing hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Ritter, H.

    1982-08-03T23:59:59.000Z

    An improved sulfur-ammonia process is disclosed for removing hydrogen sulfide from coke oven gases. In the improved process, a concentrator formerly used for standby operation is used at all normal times as an ammonia scrubber to improve the efficiency of gas separation during normal operation and is used as a concentrator for its intended standby functions during the alternative operations. In its normal function, the concentrator/scrubber functions as a scrubber to strip ammonia gas from recirculating liquid streams and to permit introduction of an ammonia-rich gas into a hydrogen sulfide scrubber to increase the separation efficiency of that unit. In the standby operation, the same concentrator/scrubber serves as a concentrator to concentrate hydrogen sulfide in a ''strong liquor'' stream for separate recovery as a strong liquor.

  4. Analysis of a geopressured gas reservoir using solution plot method

    E-Print Network [OSTI]

    Hussain, Syed Muqeedul

    1992-01-01T23:59:59.000Z

    reservoir to estimate OGIP, c~ and W~. The only input parameters required are the pressure-production data. 2. It is important to recognize that all the energy sources i. e. expansion of gas, rock and water, and water influx may be active at any time... geopressured gas reservoir has been observed to deviate from the theoretical straight line of the Solution plot. These deviations have been designated as Tail 1 and Tail 2. Tail 1, exhibiting increasing effective compressibility is a response to rock...

  5. Evaporation system and method for gas jet deposition of thin film materials

    DOE Patents [OSTI]

    Schmitt, Jerome J. (New Haven, CT); Halpern, Bret L. (Bethany, CT)

    1994-01-01T23:59:59.000Z

    A method and apparatus for depositing thin films of materials such as metals, oxides and nitrides at low temperature relies on a supersonic free jet of inert carrier gas to transport vapor species generated from an evaporation source to the surface of a substrate. Film deposition vapors are generated from solid film precursor materials, including those in the form of wires or powders. The vapor from these sources is carried downstream in a low pressure supersonic jet of inert gas to the surface of a substrate where the vapors deposit to form a thin film. A reactant gas can be introduced into the gas jet to form a reaction product with the evaporated material. The substrate can be moved from the gas jet past a gas jet containing a reactant gas in which a discharge has been generated, the speed of movement being sufficient to form a thin film which is chemically composed of the evaporated material and reactant gases.

  6. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID) [Idaho Falls, ID; McKellar, Michael G. (Idaho Falls, ID) [Idaho Falls, ID; Turner, Terry D. (Ammon, ID) [Ammon, ID; Carney, Francis H. (Idaho Falls, ID) [Idaho Falls, ID

    2009-09-29T23:59:59.000Z

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream.

  7. System and method to determine thermophysical properties of a multi-component gas

    DOE Patents [OSTI]

    Morrow, Thomas B.; Behring II, Kendricks A.

    2003-08-05T23:59:59.000Z

    A system and method to characterize natural gas hydrocarbons using a single inferential property, such as standard sound speed, when the concentrations of the diluent gases (e.g., carbon dioxide and nitrogen) are known. The system to determine a thermophysical property of a gas having a first plurality of components comprises a sound velocity measurement device, a concentration measurement device, and a processor to determine a thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the concentration measurements, wherein the number of concentration measurements is less than the number of components in the gas. The method includes the steps of determining the speed of sound in the gas, determining a plurality of gas component concentrations in the gas, and determining the thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the plurality of concentrations.

  8. Apparatus and method to inject a reductant into an exhaust gas feedstream

    SciTech Connect (OSTI)

    Viola, Michael B. (Macomb Township, MI)

    2009-09-22T23:59:59.000Z

    An exhaust aftertreatment system for an internal combustion engine is provided including an apparatus and method to inject a reductant into the exhaust gas feedstream. Included is a fuel metering device adapted to inject reductant into the exhaust gas feedstream and a controllable pressure regulating device. A control module is operatively connected to the reductant metering device and the controllable pressure regulating device, and, adapted to effect flow of reductant into the exhaust gas feedstream over a controllable flow range.

  9. An Analytical Solution for Slug-Tracer Tests in FracturedReservoirs

    SciTech Connect (OSTI)

    Shan, Chao; Pruess, Karsten

    2005-03-02T23:59:59.000Z

    The transport of chemicals or heat in fractured reservoirs is strongly affected by the fracture-matrix interfacial area. In a vapor-dominated geothermal reservoir, this area can be estimated by inert gas tracer tests, where gas diffusion between the fracture and matrix causes the tracer breakthrough curve (BTC) to have a long tail determined by the interfacial area. For water-saturated conditions, recent studies suggest that sorbing solute tracers can also generate strong tails in BTCs that may allow a determination of the fracture-matrix interfacial area. To theoretically explore such a useful phenomenon, this paper develops an analytical solution for BTCs in slug-tracer tests in a water-saturated fractured reservoir. The solution shows that increased sorption should have the same effect on BTCs as an increase of the diffusion coefficient. The solution is useful for understanding transport mechanisms, verifying numerical codes, and for identifying appropriate chemicals as tracers for the characterization of fractured reservoirs.

  10. Optical methods and systems for detecting a constituent in a gas containing oxygen in harsh environments

    DOE Patents [OSTI]

    Carpenter, Michael A. (Scotia, NY); Sirinakis, George (Bronx, NY)

    2011-01-04T23:59:59.000Z

    A method for detecting a gas phase constituent such as carbon monoxide, nitrogen dioxide, hydrogen, or hydrocarbons in a gas comprising oxygen such as air, includes providing a sensing material or film having a metal embedded in a catalytically active matrix such as gold embedded in a yttria stabilized zirconia (YSZ) matrix. The method may include annealing the sensing material at about 900.degree. C., exposing the sensing material and gas to a temperature above 400.degree. C., projecting light onto the sensing material, and detecting a change in the absorption spectrum of the sensing material due to the exposure of the sensing material to the gas in air at the temperature which causes a chemical reaction in the sensing material compared to the absorption spectrum of the sensing material in the absence of the gas. Systems employing such a method are also disclosed.

  11. Method of generating hydrogen gas from sodium borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester, Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2007-12-11T23:59:59.000Z

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  12. High Accuracy Numerical Methods for Thermally Perfect Gas Flows with Chemistry

    E-Print Network [OSTI]

    Soatto, Stefano

    High Accuracy Numerical Methods for Thermally Perfect Gas Flows with Chemistry Ronald P. Fedkiw with calculations of a 1-D reacting shock tube and a 2-D combustor. 2 #12; 1 Introduction Chemically reacting, high or the incineration of waste in a dump combustor. The combination of energetic chemical reactions and compressible gas

  13. Mass spectral characterization of petroleum dyes, tracers, and additives

    SciTech Connect (OSTI)

    Youngless, T.L.; Swansiger, J.T.; Danner, D.A.; Greco, M.

    1985-08-01T23:59:59.000Z

    Petroleum dyes, additives, and tracers are important for identifying gasolines in spill and contamination problems. High-resolution mass spectrometry (HRMS) was used for the characterization of 21 commercial petroleum dyes. Many contained common chromophores, typically azo or anthraquinone groups, and often differed only in their degree of alkyl substitution. Few dyes were pure and typically contained several chromogens with homologous series of substituents. A separation method was developed to concentrate the polar fractions containing the additives. Subsequent characterization of the polar fraction by GC/MS showed distinct differences between different gasolines. Various colorless tracers were evaluated in terms of detectability, soil adsorption, and cost. Many tracers exhibited soil adsorption and interferences which limited their detectability. Alcohols in the C8-C10 range were found to be the most suitable tracers with GC/MS detection limits of 1 ppm. 22 references, 4 figures, 3 tables.

  14. Method for removal of mercury from various gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2003-06-10T23:59:59.000Z

    The invention provides for a method for removing elemental mercury from a fluid, the method comprising irradiating the mercury with light having a wavelength of approximately 254 nm. The method is implemented in situ at various fuel combustion locations such as power plants and municipal incinerators.

  15. Standard test method for determination of total hydrogen content of uranium oxide powders and pellets by carrier gas extraction

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2000-01-01T23:59:59.000Z

    Standard test method for determination of total hydrogen content of uranium oxide powders and pellets by carrier gas extraction

  16. Oil and Gas CDT Downscaling-Upscaling: A Robust Method of Linking

    E-Print Network [OSTI]

    Henderson, Gideon

    Oil and Gas CDT Downscaling-Upscaling: A Robust Method of Linking Geomechanical Simulations Geomechanical simulation; fractures; strain; flow upscaling Overview Geomechanical simulations of trap geomechanical simulation outputs as a starting point, the project will demonstrate and test the value

  17. Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2000-01-01T23:59:59.000Z

    A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

  18. Water augmented indirectly-fired gas turbine systems and method

    DOE Patents [OSTI]

    Bechtel, Thomas F. (Lebanon, PA); Parsons, Jr., Edward J. (Morgantown, WV)

    1992-01-01T23:59:59.000Z

    An indirectly-fired gas turbine system utilizing water augmentation for increasing the net efficiency and power output of the system is described. Water injected into the compressor discharge stream evaporatively cools the air to provide a higher driving temperature difference across a high temperature air heater which is used to indirectly heat the water-containing air to a turbine inlet temperature of greater than about 1,000.degree. C. By providing a lower air heater hot side outlet temperature, heat rejection in the air heater is reduced to increase the heat recovery in the air heater and thereby increase the overall cycle efficiency.

  19. Chemical tracers of episodic accretion in low-mass protostars

    E-Print Network [OSTI]

    Visser, Ruud; Jorgensen, Jes K

    2015-01-01T23:59:59.000Z

    Aims: Accretion rates in low-mass protostars can be highly variable in time. Each accretion burst is accompanied by a temporary increase in luminosity, heating up the circumstellar envelope and altering the chemical composition of the gas and dust. This paper aims to study such chemical effects and discusses the feasibility of using molecular spectroscopy as a tracer of episodic accretion rates and timescales. Methods: We simulate a strong accretion burst in a diverse sample of 25 spherical envelope models by increasing the luminosity to 100 times the observed value. Using a comprehensive gas-grain network, we follow the chemical evolution during the burst and for up to 10^5 yr after the system returns to quiescence. The resulting abundance profiles are fed into a line radiative transfer code to simulate rotational spectra of C18O, HCO+, H13CO+, and N2H+ at a series of time steps. We compare these spectra to observations taken from the literature and to previously unpublished data of HCO+ and N2H+ 6-5 from th...

  20. A method of evaluating the performance deterioration of aircraft gas-turbines

    E-Print Network [OSTI]

    Subramanian, V

    1978-01-01T23:59:59.000Z

    A METHOD OF EVALUATING THE PERFORMANCE DETERIORATION OF AIRCRAFT GAS-TURBINES A Thesis by V. SUBRAMANIAN Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... May 1978 Major Subject: Mechanical Engineering A METHOD OF EVALUATING THE PERFORMANCE DETERIORATION OF AIRCRAFT GAS-TURBINES A Thesis by V. SUBRAMANIAN Approved as to style and content by: Charrman o Commztt (Head o D pa ment Sg D~ Member...

  1. Gas turbine nozzle vane insert and methods of installation

    DOE Patents [OSTI]

    Miller, William John (Simpsonville, SC); Predmore, Daniel Ross (Clifton Park, NY); Placko, James Michael (West Chester, OH)

    2002-01-01T23:59:59.000Z

    A pair of hollow elongated insert bodies are disposed in one or more of the nozzle vane cavities of a nozzle stage of a gas turbine. Each insert body has an outer wall portion with apertures for impingement-cooling of nozzle wall portions in registration with the outer wall portion. The insert bodies are installed into the cavity separately and spreaders flex the bodies toward and to engage standoffs against wall portions of the nozzle whereby the designed impingement gap between the outer wall portions of the insert bodies and the nozzle wall portions is achieved. The spreaders are secured to the inner wall portions of the insert bodies and the bodies are secured to one another and to the nozzle vane by welding or brazing.

  2. Methods of Gas Phase Capture of Iodine from Fuel Reprocessing Off-Gas: A Literature Survey

    SciTech Connect (OSTI)

    Daryl Haefner

    2007-02-01T23:59:59.000Z

    A literature survey was conducted to collect information and summarize the methods available to capture iodine from fuel reprocessing off-gases. Techniques were categorized as either wet scrubbing or solid adsorbent methods, and each method was generally described as it might be used under reprocessing conditions. Decontamination factors are quoted only to give a rough indication of the effectiveness of the method. No attempt is made to identify a preferred capture method at this time, although activities are proposed that would provide a consistent baseline that would aid in evaluating technologies.

  3. Method and apparatus for filtering gas with a moving granular filter bed

    DOE Patents [OSTI]

    Brown, Robert C. (Ames, IA); Wistrom, Corey (Ames, IA); Smeenk, Jerod L. (Ames, IA)

    2007-12-18T23:59:59.000Z

    A method and apparatus for filtering gas (58) with a moving granular filter bed (48) involves moving a mass of particulate filter material (48) downwardly through a filter compartment (35); tangentially introducing gas into the compartment (54) to move in a cyclonic path downwardly around the moving filter material (48); diverting the cyclonic path (58) to a vertical path (62) to cause the gas to directly interface with the particulate filter material (48); thence causing the gas to move upwardly through the filter material (48) through a screened partition (24, 32) into a static upper compartment (22) of a filter compartment for exodus (56) of the gas which has passed through the particulate filter material (48).

  4. Advancing New 3D Seismic Interpretation Methods for Exploration and Development of Fractured Tight Gas Reservoirs

    SciTech Connect (OSTI)

    James Reeves

    2005-01-31T23:59:59.000Z

    In a study funded by the U.S. Department of Energy and GeoSpectrum, Inc., new P-wave 3D seismic interpretation methods to characterize fractured gas reservoirs are developed. A data driven exploratory approach is used to determine empirical relationships for reservoir properties. Fractures are predicted using seismic lineament mapping through a series of horizon and time slices in the reservoir zone. A seismic lineament is a linear feature seen in a slice through the seismic volume that has negligible vertical offset. We interpret that in regions of high seismic lineament density there is a greater likelihood of fractured reservoir. Seismic AVO attributes are developed to map brittle reservoir rock (low clay) and gas content. Brittle rocks are interpreted to be more fractured when seismic lineaments are present. The most important attribute developed in this study is the gas sensitive phase gradient (a new AVO attribute), as reservoir fractures may provide a plumbing system for both water and gas. Success is obtained when economic gas and oil discoveries are found. In a gas field previously plagued with poor drilling results, four new wells were spotted using the new methodology and recently drilled. The wells have estimated best of 12-months production indicators of 2106, 1652, 941, and 227 MCFGPD. The latter well was drilled in a region of swarming seismic lineaments but has poor gas sensitive phase gradient (AVO) and clay volume attributes. GeoSpectrum advised the unit operators that this location did not appear to have significant Lower Dakota gas before the well was drilled. The other three wells are considered good wells in this part of the basin and among the best wells in the area. These new drilling results have nearly doubled the gas production and the value of the field. The interpretation method is ready for commercialization and gas exploration and development. The new technology is adaptable to conventional lower cost 3D seismic surveys.

  5. Lattice Boltzmann method and gas-kinetic BGK scheme in the low-Mach number viscous flow simulations

    E-Print Network [OSTI]

    Xu, Kun

    and collisions process. On the other hand, the gas-kinetic BGK scheme is a finite volume scheme, where the timeLattice Boltzmann method and gas-kinetic BGK scheme in the low-Mach number viscous flow simulations method (LBM) and the gas-kinetic BGK scheme are based on the numerical discretization of the Boltzmann

  6. Apparatus and method for a gas turbine nozzle

    DOE Patents [OSTI]

    Zuo, Baifang; Ziminsky, Willy Steve; Johnson, Thomas Edward; Intile, John Charles; Lacy, Benjamin Paul

    2013-02-05T23:59:59.000Z

    A nozzle includes an inlet, an outlet, and an axial centerline. A shroud surrounding the axial centerline extends from the inlet to the outlet and defines a circumference. The circumference proximate the inlet is greater than the circumference at a first point downstream of the inlet, and the circumference at the first point downstream of the inlet is less than the circumference at a second point downstream of the first point. A method for supplying a fuel through a nozzle directs a first airflow along a first path and a second airflow along a second path separate from the first path. The method further includes injecting the fuel into at least one of the first path or the second path and accelerating at least one of the first airflow or the second airflow.

  7. Control method for turbocharged diesel engines having exhaust gas recirculation

    DOE Patents [OSTI]

    Kolmanovsky, Ilya V. (Ypsilanti, MI); Jankovic, Mrdjan J (Birmingham, MI); Jankovic, Miroslava (Birmingham, MI)

    2000-03-14T23:59:59.000Z

    A method of controlling the airflow into a compression ignition engine having an EGR and a VGT. The control strategy includes the steps of generating desired EGR and VGT turbine mass flow rates as a function of the desired and measured compressor mass airflow values and exhaust manifold pressure values. The desired compressor mass airflow and exhaust manifold pressure values are generated as a function of the operator-requested fueling rate and engine speed. The EGR and VGT turbine mass flow rates are then inverted to corresponding EGR and VGT actuator positions to achieve the desired compressor mass airflow rate and exhaust manifold pressure. The control strategy also includes a method of estimating the intake manifold pressure used in generating the EGR valve and VGT turbine positions.

  8. Linear nozzle with tailored gas plumes and method

    DOE Patents [OSTI]

    Leon, David D. (Murrysville, PA); Kozarek, Robert L. (Apollo, PA); Mansour, Adel (Mentor, OH); Chigier, Norman (Pittsburgh, PA)

    1999-01-01T23:59:59.000Z

    There is claimed a method for depositing fluid material from a linear nozzle in a substantially uniform manner across and along a surface. The method includes directing gaseous medium through said nozzle to provide a gaseous stream at the nozzle exit that entrains fluid material supplied to the nozzle, said gaseous stream being provided with a velocity profile across the nozzle width that compensates for the gaseous medium's tendency to assume an axisymmetric configuration after leaving the nozzle and before reaching the surface. There is also claimed a nozzle divided into respective side-by-side zones, or preferably chambers, through which a gaseous stream can be delivered in various velocity profiles across the width of said nozzle to compensate for the tendency of this gaseous medium to assume an axisymmetric configuration.

  9. Thermal chemical recuperation method and system for use with gas turbine systems

    DOE Patents [OSTI]

    Yang, Wen-Ching (Export, PA); Newby, Richard A. (Pittsburgh, PA); Bannister, Ronald L. (Winter Springs, FL)

    1999-01-01T23:59:59.000Z

    A system and method for efficiently generating power using a gas turbine, a steam generating system (20, 22, 78) and a reformer. The gas turbine receives a reformed fuel stream (74) and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer (18). The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine.

  10. Thermal chemical recuperation method and system for use with gas turbine systems

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Bannister, R.L.

    1999-04-27T23:59:59.000Z

    A system and method are disclosed for efficiently generating power using a gas turbine, a steam generating system and a reformer. The gas turbine receives a reformed fuel stream and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer. The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine. 2 figs.

  11. A method for the determination of dissolved organic carbon in sea water by gas chromatography

    E-Print Network [OSTI]

    Fredericks, Alan D

    1965-01-01T23:59:59.000Z

    OF PLATES Plate Page I Front Oblique View of Ampoule Flushing and Sealing Apparatus . 15 2 Side View of Ampoule Flushing and Sealing Apparatus . 17 3 Ampoule Crushing Apparatus 4 Two Position Gas Valve 5 Carbon Dioxide Analysis Apparatus 29 37 45... is passed through an infrared analyzer using nitrogen as a carrier gas. The purpose of this investigation was to develop a shipboard method for determining the concentration of dissolved organic carbon in sea water samples. Sea water was sealed in glass...

  12. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08T23:59:59.000Z

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  13. An Embedded Boundary Method for the Modeling of Unsteady Combustion in an Industrial GasFired Furnace \\Lambda

    E-Print Network [OSTI]

    An Embedded Boundary Method for the Modeling of Unsteady Combustion in an Industrial Gas the simulation of an experimental natural gas­fired furnace are shown. \\Lambda This work was performed under

  14. Method for the photocatalytic conversion of gas hydrates

    DOE Patents [OSTI]

    Taylor, Charles E. (Pittsburg, PA); Noceti, Richard P. (Pittsburg, PA); Bockrath, Bradley C. (Bethel Park, PA)

    2001-01-01T23:59:59.000Z

    A method for converting methane hydrates to methanol, as well as hydrogen, through exposure to light. The process includes conversion of methane hydrates by light where a radical initiator has been added, and may be modified to include the conversion of methane hydrates with light where a photocatalyst doped by a suitable metal and an electron transfer agent to produce methanol and hydrogen. The present invention operates at temperatures below 0.degree. C., and allows for the direct conversion of methane contained within the hydrate in situ.

  15. Methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Nelson, Lee O. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

    2009-02-24T23:59:59.000Z

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  16. Horizontal natural gas storage caverns and methods for producing same

    DOE Patents [OSTI]

    Russo, Anthony (Albuquerque, NM)

    1995-01-01T23:59:59.000Z

    The invention provides caverns and methods for producing caverns in bedded salt deposits for the storage of materials that are not solvents for salt. The contemplated salt deposits are of the bedded, non-domed variety, more particularly salt found in layered formations that are sufficiently thick to enable the production of commercially usefully sized caverns completely encompassed by walls of salt of the formation. In a preferred method, a first bore hole is drilled into the salt formation and a cavity for receiving insolubles is leached from the salt formation. Thereafter, at a predetermined distance away from the first bore hole, a second bore hole is drilled towards the salt formation. As this drill approaches the salt, the drill assumes a slant approach and enters the salt and drills through it in a horizontal direction until it intersects the cavity for receiving insolubles. This produces a substantially horizontal conduit from which solvent is controlledly supplied to the surrounding salt formation, leaching the salt and producing a concentrated brine which is removed through the first bore hole. Insolubles are collected in the cavity for receiving insolubles. By controlledly supplying solvent, a horizontal cavern is produced with two bore holes extending therefrom.

  17. Evaporation system and method for gas jet deposition of thin film materials

    DOE Patents [OSTI]

    Schmitt, J.J.; Halpern, B.L.

    1994-10-18T23:59:59.000Z

    A method and apparatus are disclosed for depositing thin films of materials such as metals, oxides and nitrides at low temperature relies on a supersonic free jet of inert carrier gas to transport vapor species generated from an evaporation source to the surface of a substrate. Film deposition vapors are generated from solid film precursor materials, including those in the form of wires or powders. The vapor from these sources is carried downstream in a low pressure supersonic jet of inert gas to the surface of a substrate where the vapors deposit to form a thin film. A reactant gas can be introduced into the gas jet to form a reaction product with the evaporated material. The substrate can be moved from the gas jet past a gas jet containing a reactant gas in which a discharge has been generated, the speed of movement being sufficient to form a thin film which is chemically composed of the evaporated material and reactant gases. 8 figs.

  18. Apparatus For The Liquefaaction Of Natural Gas And Methods Relating To Same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID); Bingham, Dennis N. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID); Rateman, Kevin T. (Idaho Falls, ID); Palmer, Gary L. (Shelley, ID); Klinger, Kerry M. (Idaho Falls, ID); Vranicar, John J. (Concord, CA)

    2005-11-08T23:59:59.000Z

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO2) clean-up cycle.

  19. Apparatus For The Liquefaaction Of Natural Gas And Methods Relating To Same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID); Bingham, Dennis N. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID); Raterman, Kevin T. (Idaho Falls, ID); Palmer, Gary L. (Shelley, ID); Klingler, Kerry M. (Idaho Falls, ID); Vranicar, John J. (Concord, CA)

    2003-06-24T23:59:59.000Z

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO.sub.2) clean-up cycle.

  20. Apparatus For The Liquefaaction Of Natural Gas And Methods Relating To Same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID); Bingham, Dennis N. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID); Raterman, Kevin T. (Idaho Falls, ID); Palmer, Gary L. (Shelley, ID); Klingler, Kerry M. (Idaho Falls, ID); Vranicar, John J. (Concord, CA)

    2005-05-03T23:59:59.000Z

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO2) clean-up cycle.

  1. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID); Bingham, Dennis N. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID); Raterman, Kevin T. (Idaho Falls, ID); Palmer, Gary L. (Shelley, ID); Klingler, Kerry M. (Idaho Falls, ID); Vranicar, John J. (Concord, CA)

    2007-05-22T23:59:59.000Z

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO.sub.2) clean-up cycle.

  2. A critical review of methods used in the estimation of natural gas reserves 

    E-Print Network [OSTI]

    Gruy, Henry Jones

    1956-01-01T23:59:59.000Z

    for the de- gree of PROFESSIONAL ENGINEER MA JOR SU% JEGT: PETROLEUM ENGINEERING itay f956 A GR1TLGAL REVXE? 0$' METHODS gSED THE ESTIMATION op NATURAL GAS RESERVES 8y Henry J. Gruy Approved as to style and content by Ghairman of C, ommittee hiay... Reserves 21 Refereaces 22 CO LA CA 4J CO 2'79098 TASLE OF ILLUSTRATIONS A CRITICAL REVIEW Ol' METHODS USED IN THE ESTIMATION QF NATURAL GAS RESERVE Curves Curve No. Curves Showing Change in the Compres- sibility Factor with Depth and Gomposf...

  3. Efficient method of gas laser pumping by an electron beam in the SIGE-1 experimental setup

    SciTech Connect (OSTI)

    Arlantsev, S. V., E-mail: arlantsev@mail.ru [Orlov Special Design Engineering Bureau of High-Energy Lasers 'Granat,' (Russian Federation); Kuz'min, G. P.; Minaev, I. M.; Mkheidze, G. P.; Tikhonevich, O. V.; Ul'yanov, D. K. [Russian Academy of Sciences, Prokhorov Institute of General Physics (Russian Federation)

    2011-12-15T23:59:59.000Z

    Lasers, sources of coherent UV and vacuum UV radiation, plasmachemical reactors, reactors for cleaning fouled gases, etc., can be classified as devices the working medium of which is plasma formed as a result of the interaction of a high-current relativistic electronic beam with gas. Efficiency of such devices which are united under the common name 'systems of injection gas electronics' (SIGE) depends mainly on the efficiency of energy transfer from a beam to gas ({eta}g = W{sub g}/W{sub b}) and that of the transform of the energy transferred to gas into the energy of the ultimate product W{sub in} ({eta}{sub in} = W{sub in}/W{sub g}). As a special case of SIGE, an experimental bench laser is considered. The new efficient method of pumping is supposed to be implemented on this laser to optimize the energy contribution {eta}{sub g} and useful output {eta}{sub in}.

  4. Method and apparatus for noble gas atom detection with isotopic selectivity

    DOE Patents [OSTI]

    Hurst, G. Samuel (Oak Ridge, TN); Payne, Marvin G. (Harriman, TN); Chen, Chung-Hsuan (Knoxville, TN); Parks, James E. (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    Apparatus and methods of operation are described for determining, with isotopic selectivity, the number of noble gas atoms in a sample. The analysis is conducted within an evacuated chamber which can be isolated by a valve from a vacuum pumping system capable of producing a pressure of 10.sup.-8 Torr. Provision is made to pass pulses of laser beams through the chamber, these pulses having wavelengths appropriate for the resonance ionization of atoms of the noble gas under analysis. A mass filter within the chamber selects ions of a specific isotope of the noble gas, and means are provided to accelerate these selected ions sufficiently for implantation into a target. Specific types of targets are discussed. An electron measuring device produces a signal relatable to the number of ions implanted into the target and thus to the number of atoms of the selected isotope of the noble gas removed from the gas sample. The measurement can be continued until a substantial fraction, or all, of the atoms in the sample have been counted. Furthermore, additional embodiments of the apparatus are described for bunching the atoms of a noble gas for more rapid analysis, and for changing the target for repetitive cycling of the gas in the chamber. The number of repetitions of the cyclic steps depend upon the concentration of the isotope of interest, the separative efficiency of the mass filter, etc. The cycles are continued until a desired selectivity is achieved. Also described are components and a method of operation for a pre-enrichment operation for use when an introduction of a total sample would elevate the pressure within the chamber to levels in excess of those for operation of the mass filter, specifically a quadrupole mass filter. Specific examples of three noble gas isotope analyses are described.

  5. Groundwater prospecting for sandstone-type uranium deposits: the merits of mineral-solution equilibria versus single element tracer methods. Volume II

    SciTech Connect (OSTI)

    Wanty, R.B.; Langmuir, D.; Chatham, J.R.

    1981-08-01T23:59:59.000Z

    This report presents the results of further research on the groundwater geochemistry of 96 well waters in two uraniferous aquifers in Texas and Wyoming, and is a continuation of the work presented by Chatham et al. (1981). In this study variations in concentrations of U, As, Mo, Se and V were compared with the saturation state of the groundwater with respect to mineral phases of these elements known or expected to occur in each area. The non-radiogenic trace elements exhibited strong redox dependence consistent with thermodynamic predictions, but their variations did not pinpoint existing uranium ore bodies, because of a shift in groundwater flow patterns since the time of ore emplacement. Saturation levels of trace element minerals such as realgar, native Se, and molybdenite showed broad anomalies around the ore-bearing areas, similar to patterns found for U minerals by Langmuir and Chatham (1980), and Chatham et al. (1981). The radiogenic elements Ra and Rn showed significant anomalies directly within the ore zones. Helium anomalies were displaced in the direction of groundwater flow, but by their magnitude and areal extent provided strong evidence for the existence of nearby uranium accumulations. Uranium isotope ratios showed no systematic variations within the two aquifers studied. Saturation maps for kaolinite, illite, montmorillonite and the zeolites analcime and clinoptilolite provided 1 to 2 km anomalies around the ore at the Texas site. Saturation values for the gangue minerals pyrite and calcite defined the redox interface and often suggested the position of probable uranium mineralization. When properly used, the groundwater geochemical concepts for exploration can accurately pinpoint uranium mineralization at a fraction of the cost of conventional methods that involve test drilling and geophysical and core logging.

  6. Method of washing hydrogen sulfide from coke oven gas by the ammonium sulfide method

    SciTech Connect (OSTI)

    Ritter, H.

    1985-05-21T23:59:59.000Z

    An improved coke oven gas washing process for removing hydrogen sulfide is proposed wherein the coke oven gas is treated in a hydrogen sulfide scrubber by counterflow with an aqueous ammonia wash water. A stream of aqueous weak ammonia liquor is cooled and sprayed through nozzles in the mid-region of the hydrogen sulfide scrubber. A quantity of aqueous ammonia liquor, corresponding to the quantity which is sprayed through the said nozzles, is withdrawn from the hydrogen sulfide scrubber at a level below the nozzles and is introduced into the top of the said hydrogen sulfide scrubber. Ammonia vapor released at the nozzles has a higher partial pressure than the ammonia partial pressure of the coke oven gas in the region of the nozzle. The aqueous ammonia liquor from the deacidifier is the source of the cooled aqueous ammonia liquor which is introduced through the nozzles. A portion of the aqueous ammonia liquor from the deacidifier is introduced directly into the top of the hydrogen sulfide scrubber as a portion of the required aqueous ammonia wash water.

  7. Method to prevent recession loss of silica and silicon-containing materials in combustion gas environments

    DOE Patents [OSTI]

    Brun, Milivoj Konstantin (Ballston Lake, NY); Luthra, Krishan Lal (Niskayuna, NY)

    2003-01-01T23:59:59.000Z

    While silicon-containing ceramics or ceramic composites are prone to material loss in combustion gas environments, this invention introduces a method to prevent or greatly reduce the thickness loss by injecting directly an effective amount, generally in the part per million level, of silicon or silicon-containing compounds into the combustion gases.

  8. Cooling air recycling for gas turbine transition duct end frame and related method

    DOE Patents [OSTI]

    Cromer, Robert Harold (Johnstown, NY); Bechtel, William Theodore (Scotia, NY); Sutcu, Maz (Niskayuna, NY)

    2002-01-01T23:59:59.000Z

    A method of cooling a transition duct end frame in a gas turbine includes the steps of a) directing cooling air into the end frame from a region external of the transition duct and the impingement cooling sleeve; and b) redirecting the cooling air from the end frame into the annulus between the transition duct and the impingement cooling sleeve.

  9. Method of purifying a gas stream using 1,2,3-triazolium ionic liquids

    DOE Patents [OSTI]

    Luebke, David; Nulwala, Hunald; Tang, Chau

    2014-12-09T23:59:59.000Z

    A method for separating a target gas from a gaseous mixture using 1,2,3-triazolium ionic liquids is presented. Industrial effluent streams may be cleaned by removing carbon dioxide from the stream by contacting the effluent stream with a 1,2,3-triazolium ionic liquid compound.

  10. Catalyst for selective conversion of synthesis gas and method of making the catalyst

    DOE Patents [OSTI]

    Dyer, Paul N. (Allentown, PA); Pierantozzi, Ronald (Macungie, PA)

    1986-01-01T23:59:59.000Z

    A Fischer-Tropsch (F-T) catalyst, a method of making the catalyst and an F-T process utilizing the catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range. In general, the selective and notably stable catalyst, consists of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of an F-T metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

  11. SENSITIVITY OF A REACTIVE-TRACER BASED ESTIMATE OF THERMAL BREAKTHROUGH IN AN EGS TO PROPERTIES OF THE RESERVOIR AND TRACER

    SciTech Connect (OSTI)

    Mitchell A. Plummer; Carl D. Palmer; Laurence C. Hull; Earl D. Mattson

    2010-02-01T23:59:59.000Z

    Reactive tracers have long been considered a possible means of measuring thermal drawdown in a geothermal system, before significant cooling occurs at the extraction well. Here, we examine the sensitivity of the proposed method to reservoir cooling and demonstrate that while the sensitivity of the method as generally proposed is low, it may be practical under certain conditions. Our analyses suggest that modifications to that method, where practical, could provide much greater sensitivity. In particular, if the reaction can be quenched before maximum temperature is reached, the sensitivity is greatly enhanced. Push-pull tracer tests conducted at the injection well demonstrate similar advantages. Other alternatives, such as combinations of tracers, and tracers with parallel or chain decay behavior may offer similar advantages.

  12. Method and apparatus for confinement of ions in the presence of a neutral gas

    DOE Patents [OSTI]

    Peurrung, A.J.; Barlow, S.E.

    1999-08-03T23:59:59.000Z

    The present invention is an apparatus and method for combining ions with a neutral gas and flowing the mixture with a radial flow component through a magnetic field so that the weakly ionized gas is confined by the neutral gas. When the weakly ionized gas is present in sufficient density, a weakly ionized non-neutral plasma is formed that may be trapped in accordance with the present invention. Applications for a weakly ionized non-neutral plasma exploit the trap`s ability to store and manipulate ionic species in the presence of neutral gas. The trap may be connected to a mass spectrometer thereby permitting species identification after a fixed period of time. Delicate and/or heavy particles such as clusters may be held and studied in a ``gentle`` environment. In addition, the trap can provide a relatively intense, low-energy source of a particular ion species for surface implantation or molecular chemistry. Finally, a long trap may permit spectroscopy of unprecedented accuracy to be performed on ionic species. 4 figs.

  13. Method and apparatus for confinement of ions in the presence of a neutral gas

    DOE Patents [OSTI]

    Peurrung, Anthony J. (Richland, WA); Barlow, Stephan E. (Richland, WA)

    1999-01-01T23:59:59.000Z

    The present invention is an apparatus and method for combining ions with a neutral gas and flowing the mixture with a radial flow component through a magnetic field so that the weakly ionized gas is confined by the neutral gas. When the weakly ionized gas is present in sufficient density, a weakly ionized non-neutral plasma is formed that may be trapped in accordance with the present invention. Applications for a weakly ionized non-neutral plasma exploit the trap's ability to store and manipulate ionic species in the presence of neutral gas. The trap may be connected to a mass spectrometer thereby permitting species identification after a fixed period of time. Delicate and/or heavy particles such as clusters may be held and studied in a "gentle" environment. In addition, the trap can provide a relatively intense, low-energy source of a particular ion species for surface implantation or molecular chemistry. Finally, a long trap may permit spectroscopy of unprecedented accuracy to be performed on ionic species.

  14. Decision Matrix Screening Tool to Identify the Best Artificial Lift Method for Liquid-loaded Gas Wells

    E-Print Network [OSTI]

    Soponsakulkaew, Nitsupon

    2010-10-12T23:59:59.000Z

    Liquid loading is a serious problem in gas wells. Many proven artificial lift methods have been used to alleviate this problem. However, a complete workflow to determine the most suitable artificial lift method for given well conditions does...

  15. A critical review of methods used in the estimation of natural gas reserves: Natural gas reserves in the state of Texas. Some educational prerequisites in the field of petroleum economics and evaluation. 

    E-Print Network [OSTI]

    Crichton, John Alston

    1953-01-01T23:59:59.000Z

    A CRITICAL REVIEW OF METHODS USED IN THE ESTIMATION OF NATURAL GAS RESERVES NATURAL GAS RESERVES IN THE SI'AT. S OF TEXAS SOME EDUCATIONAL PREREQUISITES IN THE FIELD OF PETROLEUM ECONOMICS AND EVAI UATION Sy John Alston Crichton... ENGINEERING TABLE of CONTENTS ~Pa e A CRITICAL REVIEW OF METHODS USED IN THE ESTIMATION OF NATURAL GAS RESERVES Abstract Introdu=tion History of the Estimation of Gas Reserves Present Methods of Estimating Gas Reserves Meth& ds of Estimating Non...

  16. 5, 58415874, 2005 Ozone/tracer

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et al. Title Page Discussions Impact of mixing and chemical change on ozone-tracer relations in the polar vortex R. M¨uller 1 Commons License. 5841 #12;ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et

  17. Tracer Testing | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown of Ladoga, Indiana (Utility Company) Jump to:TownTownerOpenEnergyG, andTracer

  18. A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene...

    Open Energy Info (EERE)

    Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase Tracer at the Coso Geothermal Field Jump to: navigation, search OpenEI Reference LibraryAdd...

  19. Standard test method for isotopic analysis of uranium hexafluoride by double standard single-collector gas mass spectrometer method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2010-01-01T23:59:59.000Z

    1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1 and 5.0 mass %. 1.2 This test method may be applicable for the entire range of 235U concentrations for which adequate standards are available. 1.3 This test method is for analysis by a gas magnetic sector mass spectrometer with a single collector using interpolation to determine the isotopic concentration of an unknown sample between two characterized UF6 standards. 1.4 This test method is to replace the existing test method currently published in Test Methods C761 and is used in the nuclear fuel cycle for UF6 isotopic analyses. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appro...

  20. Method and apparatus to selectively reduce NO.sub.x in an exhaust gas feedstream

    SciTech Connect (OSTI)

    Schmieg, Steven J. (Troy, MI); Blint, Richard J. (Shelby Township, MI); Den, Ling (Sterling Heights, MI); Viola, Michael B. (Macomb Township, MI); Lee, Jong-Hwan (Rochester Hills, MI)

    2011-08-30T23:59:59.000Z

    A method and apparatus are described to selectively reduce NO.sub.x emissions of an internal combustion engine. An exhaust aftertreatment system includes an injection device operative to dispense a hydrocarbon reductant upstream of a silver-alumina catalytic reactor device. A control system determines a NO.sub.x concentration and hydrocarbon/NOx ratio based upon selected parameters of the exhaust gas feedstream and dispenses hydrocarbon reductant during lean engine operation. Included is a method to control elements of the feedstream during lean operation. The hydrocarbon reductant may include engine fuel.

  1. A System And Method To Determine Thermophysical Properties Of A Multi-Component Gas At Arbitrary Temperature And Pressure

    DOE Patents [OSTI]

    Morrow, Thomas E. (San Antonio, TX); Behring, II, Kendricks A. (Gilbert, AZ)

    2004-03-09T23:59:59.000Z

    A method to determine thermodynamic properties of a natural gas hydrocarbon, when the speed of sound in the gas is known at an arbitrary temperature and pressure. Thus, the known parameters are the sound speed, temperature, pressure, and concentrations of any dilute components of the gas. The method uses a set of reference gases and their calculated density and speed of sound values to estimate the density of the subject gas. Additional calculations can be made to estimate the molecular weight of the subject gas, which can then be used as the basis for mass flow calculations, to determine the speed of sound at standard pressure and temperature, and to determine various thermophysical characteristics of the gas.

  2. Identification and characterization of conservative organic tracers for use as hydrologic tracers for the Yucca Mountain Site Characterization Study; Progress report, January 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Stetzenbach, K.J.

    1991-12-31T23:59:59.000Z

    Studies continue on the use of organic acids as tracers in hydrology studies of Yucca Mountain. Work performed during this time period has been concentrated in three main areas: the familiarization with, and optimization of, the LC-MS hardware and data system; the initial development of soil column test procedures, which are used for evaluation of both the columns themselves and the tracer compounds; and continuation of the batch sorption and degradation studies for the potential tracers. All three of these tasks will continue, as the addition of new tracer compounds, analytical information, and equipment will necessitate further evaluation of existing methods and procedures. Also included in this report is the final report on an information system.

  3. Methods for manufacturing porous nuclear fuel elements for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L. (Albuquerque, NM); Williams, Brian E. (Pocoima, CA); Benander, Robert E. (Pacoima, CA)

    2010-02-23T23:59:59.000Z

    Methods for manufacturing porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's). Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, a thin coating of nuclear fuel may be deposited inside of a highly porous skeletal structure made, for example, of reticulated vitreous carbon foam.

  4. Method of making improved gas storage carbon with enhanced thermal conductivity

    DOE Patents [OSTI]

    Burchell, Timothy D. (Oak Ridge, TN); Rogers, Michael R. (Knoxville, TN)

    2002-11-05T23:59:59.000Z

    A method of making an adsorbent carbon fiber based monolith having improved methane gas storage capabilities is disclosed. Additionally, the monolithic nature of the storage carbon allows it to exhibit greater thermal conductivity than conventional granular activated carbon or powdered activated carbon storage beds. The storage of methane gas is achieved through the process of physical adsorption in the micropores that are developed in the structure of the adsorbent monolith. The disclosed monolith is capable of storing greater than 150 V/V of methane [i.e., >150 STP (101.325 KPa, 298K) volumes of methane per unit volume of storage vessel internal volume] at a pressure of 3.5 MPa (500 psi).

  5. Method for the catalytic conversion of organic materials into a product gas

    DOE Patents [OSTI]

    Elliott, Douglas C. (Richland, WA); Sealock, Jr., L. John (Richland, WA); Baker, Eddie G. (Richland, WA)

    1997-01-01T23:59:59.000Z

    A method for converting organic material into a product gas includes: a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300.degree. C. to about 450.degree. C.; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen.

  6. Method for the catalytic conversion of organic materials into a product gas

    DOE Patents [OSTI]

    Elliott, D.C.; Sealock, L.J. Jr.; Baker, E.G.

    1997-04-01T23:59:59.000Z

    A method for converting organic material into a product gas includes: (a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; (b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and (c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300 C to about 450 C; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen. 5 figs.

  7. Unraveling DPF Degradation using Chemical Tracers and Opportunities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Unraveling DPF Degradation using Chemical Tracers and Opportunities for Extending Filter Life Unraveling DPF Degradation using Chemical Tracers and Opportunities for Extending...

  8. Method for resurrecting negative electron affinity photocathodes after exposure to an oxidizing gas

    DOE Patents [OSTI]

    Mulhollan, Gregory A; Bierman, John C

    2012-10-30T23:59:59.000Z

    A method by which negative electron affinity photocathodes (201), single crystal, amorphous, or otherwise ordered, can be made to recover their quantum yield following exposure to an oxidizing gas has been discovered. Conventional recovery methods employ the use of cesium as a positive acting agent (104). In the improved recovery method, an electron beam (205), sufficiently energetic to generate a secondary electron cloud (207), is applied to the photocathode in need of recovery. The energetic beam, through the high secondary electron yield of the negative electron affinity surface (203), creates sufficient numbers of low energy electrons which act on the reduced-yield surface so as to negate the effects of absorbed oxidizing atoms thereby recovering the quantum yield to a pre-decay value.

  9. Tracer Study of Mixing and Transport in the Upper Hudson River

    E-Print Network [OSTI]

    Ho, David

    ; Peter Schlosser2 ; and David T. Ho3 Abstract: In October 2001, 0.2 mol of SF6 was injected reduce longitudinal dispersion below the value expected in a natural channel with the same discharge. SF6, and gas exchange in a river by means of a deliberately released tracer, sulfur hexafluoride SF6

  10. Method for fabricating wrought components for high-temperature gas-cooled reactors and product

    DOE Patents [OSTI]

    Thompson, Larry D. (San Diego, CA); Johnson, Jr., William R. (San Diego, CA)

    1985-01-01T23:59:59.000Z

    A method and alloys for fabricating wrought components of a high-temperature gas-cooled reactor are disclosed. These wrought, nickel-based alloys, which exhibit strength and excellent resistance to carburization at elevated temperatures, include aluminum and titanium in amounts and ratios to promote the growth of carburization resistant films while preserving the wrought character of the alloys. These alloys also include substantial amounts of molybdenum and/or tungsten as solid-solution strengtheners. Chromium may be included in concentrations less than 10% to assist in fabrication. Minor amounts of carbon and one or more carbide-forming metals also contribute to high-temperature strength.

  11. Means and method for the destruction of particles entrained in a gas stream

    DOE Patents [OSTI]

    Botts, Thomas E. (Wading River, NY); Powell, James R. (Shoreham, NY)

    1980-01-01T23:59:59.000Z

    An apparatus and method for the destruction of particles entrained in a gas stream are disclosed. Destruction in the context of the subject invention means the fragmentation and/or vaporization of particles above a certain size limit. The subject invention contemplates destroying such particles by exposing them to intense bursts of laser light, such light having a frequency approximately equal to or less than the mean size of such particles. This invention is particularly adopted to the protection of turbine blades in open cycle coal-fired turbine systems. Means for introducing various chemical species and activating them by exposure to laser light are also disclosed.

  12. Method and apparatus for the gas phase decontamination of chemical and biological agents

    DOE Patents [OSTI]

    O'Neill, Hugh J.; Brubaker, Kenneth L.

    2003-10-07T23:59:59.000Z

    An apparatus and method for decontaminating chemical and biological agents using the reactive properties of both the single atomic oxygen and the hydroxyl radical for the decontamination of chemical and biological agents. The apparatus is self contained and portable and allows for the application of gas reactants directly at the required decontamination point. The system provides for the use of ultraviolet light of a specific spectral range to photolytically break down ozone into molecular oxygen and hydroxyl radicals where some of the molecular oxygen is in the first excited state. The excited molecular oxygen will combine with water vapor to produce two hydroxyl radicals.

  13. Method for gas bubble and void control and removal from metals

    DOE Patents [OSTI]

    Siclen, C.D. Van; Wright, R.N.

    1996-02-06T23:59:59.000Z

    A method is described for enhancing the diffusion of gas bubbles or voids attached to impurity precipitates, and biasing their direction of migration out of the host metal (or metal alloy) by applying a temperature gradient across the host metal (or metal alloy). In the preferred embodiment of the present invention, the impurity metal is insoluble in the host metal and has a melting point lower than the melting point of the host material. Also, preferably the impurity metal is lead or indium and the host metal is aluminum or a metal alloy. 2 figs.

  14. Analysis of well test data from gas condensate reservoirs using single-phase dry gas methods: guidelines and examples

    E-Print Network [OSTI]

    Bonilla Kalil, Jose Ricardo

    1998-01-01T23:59:59.000Z

    drop functions versus flowing time, Arun Well A-70 (second drawdown). . 141 A-49 Early-time plot: pseudopressure versus flowing time, Arun Well A-70 (third drawdown). . 145 A-50 Semilog plot: pseudopressure versus flowing time, Arun Well A-70... due to its simplicity (the saturation history is not required). Our desire is to successfully demonstrate the analysis and interpretation of well test data in gas condensate systems using the "dry gas" analog. The primary deliverable of this thesis...

  15. GEOLOGIC ASSESSMENT OF DRILLING, COMPLETION, AND STIMULATION METHODS IN SELECTED GAS SHALE PLAYS WORLDWIDE

    E-Print Network [OSTI]

    Patel, Harsh Jay

    2014-04-11T23:59:59.000Z

    The United States regularly imports majority of the transportation oil, and several TCF of natural gas annually. Nevertheless, there is very large resource of natural gas in unconventional reservoirs, with over 2,200 TCF of natural gas in just...

  16. Method for minimizing contaminant particle effects in gas-insulated electrical apparatus

    DOE Patents [OSTI]

    Pace, Marshall O. (Knoxville, TN); Adcock, James L. (Knoxville, TN); Christophorou, Loucas G. (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    Electrical breakdown of a gas insulator in high voltage apparatus is preved by placing an electrical insulative coating on contaminant particles in the gas insulator.

  17. Patient Positioning Based on a Radioactive Tracer Implanted in Patients With Localized Prostate Cancer: A Performance and Safety Evaluation

    SciTech Connect (OSTI)

    Kruijf, Willy J.M. de, E-mail: kruijf.de.w@bvi.nl [Institute Verbeeten, Tilburg (Netherlands); Verstraete, Jan [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium)] [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium); Neustadter, David [Navotek Medical Ltd, Yokneam (Israel)] [Navotek Medical Ltd, Yokneam (Israel); Corn, Benjamin W. [Tel Aviv Medical Center, Tel Aviv (Israel)] [Tel Aviv Medical Center, Tel Aviv (Israel); Hol, Sandra; Venselaar, Jack L.M. [Institute Verbeeten, Tilburg (Netherlands)] [Institute Verbeeten, Tilburg (Netherlands); Davits, Rob J.; Wijsman, Bart P. [TweeSteden Hospital, Tilburg (Netherlands)] [TweeSteden Hospital, Tilburg (Netherlands); Van den Bergh, Laura; Budiharto, Tom [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium)] [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium); Oyen, Raymond [Department of Radiology, University Hospitals Leuven, Leuven (Belgium)] [Department of Radiology, University Hospitals Leuven, Leuven (Belgium); Haustermans, Karin [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium)] [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium); Poortmans, Philip M.P. [Institute Verbeeten, Tilburg (Netherlands)] [Institute Verbeeten, Tilburg (Netherlands)

    2013-02-01T23:59:59.000Z

    Purpose: To evaluate the performance and safety of a radiation therapy positioning system (RealEye) based on tracking a radioactive marker (Tracer) implanted in patients with localized prostate cancer. Methods and Materials: We performed a single-arm multi-institutional trial in 20 patients. The iridium-192 ({sup 192}Ir)-containing Tracer was implanted in the patient together with 4 standard gold seed fiducials. Patient prostate-related symptoms were evaluated with the International Prostate Symptom Score (IPSS) questionnaire. Computed tomography (CT) was performed for treatment planning, during treatment, and after treatment to evaluate the migration stability of the Tracer. At 5 treatment sessions, cone beam CT was performed to test the positioning accuracy of the RealEye. Results: The Tracer was successfully implanted in all patients. No device or procedure-related adverse events occurred. Changes in IPSS scores were limited. The difference between the mean change in Tracer-fiducial distance and the mean change in fiducial-fiducial distance was -0.39 mm (95% confidence interval [CI] upper boundary, -0.22 mm). The adjusted mean difference between Tracer position according to RealEye and the Tracer position on the CBCT for all patients was 1.34 mm (95% CI upper boundary, 1.41 mm). Conclusions: Implantation of the Tracer is feasible and safe. Migration stability of the Tracer is good. Prostate patients can be positioned and monitored accurately by using RealEye.

  18. Method of detecting leakage from geologic formations used to sequester CO.sub.2

    DOE Patents [OSTI]

    White, Curt (Pittsburgh, PA); Wells, Arthur (Bridgeville, PA); Diehl, J. Rodney (Pittsburgh, PA); Strazisar, Brian (Venetia, PA)

    2010-04-27T23:59:59.000Z

    The invention provides methods for the measurement of carbon dioxide leakage from sequestration reservoirs. Tracer moieties are injected along with carbon dioxide into geological formations. Leakage is monitored by gas chromatographic analyses of absorbents. The invention also provides a process for the early leak detection of possible carbon dioxide leakage from sequestration reservoirs by measuring methane (CH.sub.4), ethane (C.sub.2H.sub.6), propane (C.sub.3H.sub.8), and/or radon (Rn) leakage rates from the reservoirs. The invention further provides a method for branding sequestered carbon dioxide using perfluorcarbon tracers (PFTs) to show ownership.

  19. On-line fast response device and method for measuring dissolved gas in a fluid

    DOE Patents [OSTI]

    Tutu, Narinder Kumar (Manorville, NY)

    2011-01-11T23:59:59.000Z

    A method and device for the measurement of dissolved gas within a fluid. The fluid, substantially a liquid, is pumped into a pipe. The flow of the fluid is temporally restricted, creating one or more low pressure regions. A measurement indicative of trapped air is taken before and after the restriction. The amount of dissolved air is calculated from the difference between the first and second measurements. Preferably measurements indicative of trapped air is obtained from one or more pressure transducers, capacitance transducers, or combinations thereof. In the alternative, other methods such as those utilizing x-rays or gamma rays may also be used to detect trapped air. Preferably, the fluid is a hydraulic fluid, whereby dissolved air in the fluid is detected.

  20. Reserves determination using type-curve matching and EMB methods in the Medicine Hat shallow gas field

    SciTech Connect (OSTI)

    West, S.L. [Imperial Oil Resources Ltd., Calgary, Alberta (Canada); Cochrane, P.J.R. [Imperial Oil Resources Ltd., Cold Lake, Alberta (Canada)

    1995-05-01T23:59:59.000Z

    Tight, shallow gas reservoirs in the Western Canada basin present a number of unique challenges in determining reserves accurately. Traditional methods such as decline analysis and material balance are inaccurate owing to the formation`s low permeabilities and poor pressure data. The low permeabilities cause long transient periods that are not separated easily from production decline with conventional decline analysis, resulting in lower confidence in selecting the appropriate decline characteristics (exponential or harmonic), which effects recovery factors and remaining reserves significantly. Limited, poor-quality pressure data and commingled production from the three producing zones results in nonrepresentative pressure data and hence inaccurate material-balance analysis. This paper presents two new methods of reserve evaluation that address the problems described above for tight, shallow gas in the Medicine Hat field. The first method applies type-curve matching, which combines the analytical pressure solutions of the diffusivity equation (transient) with the empirical decline equation. The second method is an extended material balance (EMB), which incorporates the gas deliverability theory to allow selection of appropriate p/z derivatives without relying on pressure data. Excellent results were obtained when these two methods were applied to 10 properties that gather gas from 2,300 wells. The two independent techniques resulted in similar production forecasts and reserves, confirming their validity. They proved to be valuable, practical tools in overcoming the various challenges of tight, shallow gas and in improving the accuracy in gas-reserves determination in the Medicine Hat field.

  1. Isotopic mass-dependence of noble gas diffusion coefficients inwater

    SciTech Connect (OSTI)

    Bourg, I.C.; Sposito, G.

    2007-06-25T23:59:59.000Z

    Noble gas isotopes are used extensively as tracers inhydrologic and paleoclimatic studies. These applications requireknowledge of the isotopic mass (m) dependence of noble gas diffusioncoefficients in water (D), which has not been measured but is estimatedusing experimental D-values for the major isotopes along with an untestedrelationship from kinetic theory, D prop m-0.5. We applied moleculardynamics methods to determine the mass dependence of D for four noblegases at 298 K, finding that D prop m-beta with beta<0.2, whichrefutes the kinetic theory model underlying all currentapplications.

  2. A METHOD FOR ESTIMATING GAS PRESSURE IN 3013 CONTAINERS USING AN ISP DATABASE QUERY

    SciTech Connect (OSTI)

    Friday, G; L. G. Peppers, L; D. K. Veirs, D

    2008-07-31T23:59:59.000Z

    The U.S. Department of Energy's Integrated Surveillance Program (ISP) is responsible for the storage and surveillance of plutonium-bearing material. During storage, plutonium-bearing material has the potential to generate hydrogen gas from the radiolysis of adsorbed water. The generation of hydrogen gas is a safety concern, especially when a container is breached within a glove box during destructive evaluation. To address this issue, the DOE established a standard (DOE, 2004) that sets the criteria for the stabilization and packaging of material for up to 50 years. The DOE has now packaged most of its excess plutonium for long-term storage in compliance with this standard. As part of this process, it is desirable to know within reasonable certainty the total maximum pressure of hydrogen and other gases within the 3013 container if safety issues and compliance with the DOE standards are to be attained. The principal goal of this investigation is to document the method and query used to estimate total (i.e. hydrogen and other gases) gas pressure within a 3013 container based on the material properties and estimated moisture content contained in the ISP database. Initial attempts to estimate hydrogen gas pressure in 3013 containers was based on G-values (hydrogen gas generation per energy input) derived from small scale samples. These maximum G-values were used to calculate worst case pressures based on container material weight, assay, wattage, moisture content, container age, and container volume. This paper documents a revised hydrogen pressure calculation that incorporates new surveillance results and includes a component for gases other than hydrogen. The calculation is produced by executing a query of the ISP database. An example of manual mathematical computations from the pressure equation is compared and evaluated with results from the query. Based on the destructive evaluation of 17 containers, the estimated mean absolute pressure was significantly higher (P<.01) than the mean GEST pressure. There was no significant difference (P>.10) between the mean pressures from DR and the calculation. The mean predicted absolute pressure was consistently higher than GEST by an average difference of 57 kPa (8 psi). The mean difference between the estimated pressure and digital radiography was 11 kPa (2 psi). Based on the initial results of destructive evaluation, the pressure query was found to provide a reasonably conservative estimate of the total pressure in 3013 containers whose material contained minimal moisture content.

  3. A critical review of methods used in the estimation of natural gas reserves: Natural gas reserves in the state of Texas. Some educational prerequisites in the field of petroleum economics and evaluation.

    E-Print Network [OSTI]

    Crichton, John Alston

    1953-01-01T23:59:59.000Z

    for oil. In order to make an a- urete determination of the recovery factor, it is necessary to pre-determine the pressure history of the field. by material balance and water influx calculations, or by extra- polatutg a curve cf pressure agatnst...-Associated Gas Reserves Volumetr ic Method Discussion of the Factors in tne Volumetri. Formula The Decline Curve Method 7 7 12 Ie Methods of Estimating Associated Gas Reserves Methods of Estimatmg Dissolved Gas Reserves Water Drive Constant Voluxne...

  4. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    Section B (NIMB) Using Biofuel Tracers to Study Alternativeinjection. We investigate biofuel HCCI combustion, and use

  5. Apparatus and methods for determining gas saturation and porosity of a formation penetrated by a gas filled or liquid filled borehole

    DOE Patents [OSTI]

    Wilson, Robert D. (477 W. Scenic Dr., Grand Junction, CO 81503)

    2001-03-27T23:59:59.000Z

    Methods and apparatus are disclosed for determining gas saturation, liquid saturation, porosity and density of earth formations penetrated by a well borehole. Determinations are made from measures of fast neutron and inelastic scatter gamma radiation induced by a pulsed, fast neutron source. The system preferably uses two detectors axially spaced from the neutron source. One detector is preferably a scintillation detector responsive to gamma radiation, and a second detector is preferably an organic scintillator responsive to both neutron and gamma radiation. The system can be operated in cased boreholes which are filled with either gas or liquid. Techniques for correcting all measurements for borehole conditions are disclosed.

  6. Gas Hydrate Characterization in the GoM using Marine EM Methods

    SciTech Connect (OSTI)

    Steven Constable

    2012-03-31T23:59:59.000Z

    In spite of the importance of gas hydrate as a low-carbon fuel, a possible contributor to rapid climate change, and a significant natural hazard, our current understanding about the amount and distribution of submarine gas hydrate is somewhat poor; estimates of total volume vary by at least an order of magnitude, and commercially useful concentrations of hydrate have remained an elusive target. This is largely because conventional geophysical tools have intrinsic limitations in their ability to quantitatively image hydrate. It has long been known from well logs that gas hydrate is resistive compared to the host sediments, and electrical and electromagnetic methods have been proposed and occasionally used to image hydrates. This project seeks to expand our capabilities to use electromagnetic methods to explore for gas hydrate in the marine environment. An important basic science aspect of our work was to quantify the resistivity of pure gas hydrate as a function of temperature at seafloor pressures. We designed, constructed, and tested a highpressure cell in which hydrate could be synthesized and then subjected to electrical conductivity measurements. Impedance spectroscopy at frequencies between 20 Hz and 2 MHz was used to separate the effect of the blocking electrodes from the intrinsic conductivity of the hydrate. We obtained very reproducible results that showed that pure methane hydrate was several times more resistive than the water ice that seeded the synthesis, 20,000 {Ohm}m at 0{degrees}#14;C, and that the activation energy is 30.6 kJ/mol over the temperature range of -15 to 15{degrees}#14;C. Adding silica sand to the hydrate, however, showed that the addition of the extra phase caused the conductivity of the assemblage to increase in a counterintuitive way. The fact that the increased conductivity collapsed after a percolation threshold was reached, and that the addition of glass beads does not produce a similar increase in conductivity, together suggest that while the surface of the gas hydrate grains are not intrinsically conductive, the presence of sand does increase their conductivity. In the field component of this project, we carried out an 18day cruise on the R.V. Roger Revelle in the Gulf of Mexico from 7th-Ã?Â?26th October 2008 to collect controlled-source electromagnetic (CSEM) data over four hydrate prospects; blocks AC 818, WR 313, GC 955, and MC 118. During these surveys we deployed 30 ocean bottom electromagnetic (OBEM) recorders a total of 94 times at four survey areas and towed the Scripps Undersea Electromagnetic Source Instrument (SUESI) a total of 103 hours. SUESI transmission was 200 A on a 50 m dipole antenna at heights of 70-100 m above the seafloor. We also towed a neutrally buoyant 3-axis electric field recorder behind the SUESI antenna at a constant offset of 300 m. The use of a towed receiver that is "flown" above the seafloor allowed us to operate in areas where seafloor infrastructure such as wellheads, pipelines, and installed scientific equipment existed. We reduced the data to apparent resistivity psuedosections. The most compelling results come from the hydrate observatory at MC 118, where a localized resistivity anomaly is clearly identified under the southeast crater in an otherwise uniform 1 {Ohm}m background. The data from MC 118 also show that authigenic carbonate does not necessarily express itself as a confounding resistor, as was feared at the start of this project. While the results from the other prospects are much more complicated, the data are well correlated with known geology, and line to line agreement is good. Although these data are not amenable to 1D inversion as was initially hoped, we expect to use a newly developed 2D CSEM inversion code to continue to get useful information from this rich data set.

  7. The Modeling of a Laboratory Natural GasFired Furnace with a HigherOrder Projection Method for Unsteady Combustion \\Lambda

    E-Print Network [OSTI]

    method for axisymmetric, unsteady, low­ Mach number combustion is used to model a natural gas flame fromThe Modeling of a Laboratory Natural Gas­Fired Furnace with a Higher­Order Projection Method of Pember et al. [1] by using it to simulate a natural gas flame from a 300kW IFRF burner in the Burner

  8. Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H.J. (Cambridge, MA)

    2000-01-01T23:59:59.000Z

    An apparatus and a method are disclosed for converting hydrocarbon fuel or an alcohol into hydrogen gas and carbon dioxide. The apparatus includes a first vessel having a partial oxidation reaction zone and a separate steam reforming reaction zone that is distinct from the partial oxidation reaction zone. The first vessel has a first vessel inlet at the partial oxidation reaction zone and a first vessel outlet at the steam reforming zone. The reformer also includes a helical tube extending about the first vessel. The helical tube has a first end connected to an oxygen-containing source and a second end connected to the first vessel at the partial oxidation reaction zone. Oxygen gas from an oxygen-containing source can be directed through the helical tube to the first vessel. A second vessel having a second vessel inlet and second vessel outlet is annularly disposed about the first vessel. The helical tube is disposed between the first vessel and the second vessel and gases from the first vessel can be directed through second vessel.

  9. Method and apparatus for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl (Pinson, AL) [Pinson, AL; Felix, Larry Gordon (Pelham, AL) [Pelham, AL; Snyder, Todd Robert (Birmingham, AL) [Birmingham, AL

    2008-02-12T23:59:59.000Z

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  10. Method and apparatus maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl (Pinson, AL); Felix, Larry Gordon (Pelham, AL); Snyder, Todd Robert (Birmingham, AL)

    2009-12-15T23:59:59.000Z

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  11. Method for forming a liquid cooled airfoil for a gas turbine

    DOE Patents [OSTI]

    Grondahl, Clayton M. (Clifton Park, NY); Willmott, Leo C. (Ballston Spa, NY); Muth, Myron C. (Amsterdam, NY)

    1981-01-01T23:59:59.000Z

    A method for forming a liquid cooled airfoil for a gas turbine is disclosed. A plurality of holes are formed at spaced locations in an oversized airfoil blank. A pre-formed composite liquid coolant tube is bonded into each of the holes. The composite tube includes an inner member formed of an anti-corrosive material and an outer member formed of a material exhibiting a high degree of thermal conductivity. After the coolant tubes have been bonded to the airfoil blank, the airfoil blank is machined to a desired shape, such that a portion of the outer member of each of the composite tubes is contiguous with the outer surface of the machined airfoil blank. Finally, an external skin is bonded to the exposed outer surface of both the machined airfoil blank and the composite tubes.

  12. Method for reducing sulfate formation during regeneration of hot-gas desulfurization sorbents

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV); Strickland, Larry D. (Morgantown, WV); Rockey, John M. (Westover, WV)

    1994-01-01T23:59:59.000Z

    The regeneration of sulfur sorbents having sulfate forming tendencies and used for desulfurizing hot product gas streams such as provided by coal gasification is provided by employing a two-stage regeneration method. Air containing a sub-stoichiometric quantity of oxygen is used in the first stage for substantially fully regenerating the sorbent without sulfate formation and then regeneration of the resulting partially regenerated sorbent is completed in the second stage with air containing a quantity of oxygen slightly greater than the stoichiometric amount adequate to essentially fully regenerate the sorbent. Sulfate formation occurs in only the second stage with the extent of sulfate formation being limited only to the portion of the sulfur species contained by the sorbent after substantially all of the sulfur species have been removed therefrom in the first stage.

  13. Application of a method for evaluating alternative oil- and gas-leasing systems

    SciTech Connect (OSTI)

    Kretz, A.L.

    1982-01-01T23:59:59.000Z

    A substantial portion of oil and natural gas in the United States lies under portions of the Outer Continental Shelf owned and managed by the federal government. Under the 1978 Outer Continental Shelf Lands Act amendments, the Department of Interior was required to use new bidding systems on between 20 and 60% of all tracts leased in a given sale. The proposed systems would utilize a variety of bidding variables in addition to the traditional bonus, including the royalty rate and a profit share. Fixed payments could include higher royalties, sliding-scale royalties, fixed profit shares, and bonuses. This study develops and applies a method for determining how bidders will react to some of the new systems. This evaluation assumes that the new systems succeed in generating a higher number of bids per tract offered. A game-theoretic bidding model with multiplicative strategies can be used to generate the relative bid levels achieved by the new systems relative to those of existing bonus systems with the assumption of more bidders per tract. For some types of probability distributions representing resource-value uncertainty, their parameters can be estimated with maximum likelihood methods using bid data from previous OCS sales. The main conclusion is that there is no need to exclude the use of any of the alternative systems studied in oil and gas lease sales. For most sales, they provided more total revenue to the public than the current bonus system would have at comparable levels of competition without reducing the number of tracts reaching production.

  14. Use of tracers in materials-holdup study

    SciTech Connect (OSTI)

    Pillay, K.K.S.

    1983-01-01T23:59:59.000Z

    Holdup measurements of special nuclear materials in large processing facilities offer considerable challenges to conventional nondestructive-assay techniques. The use of judiciously chosen radioactive tracers offer a unique method of overcoming this difficulty. Three examples involving the use of /sup 46/Sc and fission products from activated uranium in large-scale experimental studies of uranium holdup are discussed. A justification for the method and its advantages along with examples of successful applications of this technique for large-sale experimental studies are presented.

  15. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean (Castle Rock, CO); Schlager, Richard John (Aurora, CO); Ebner, Timothy George (Westminster, CO); Stewart, Robin Michele (Arvada, CO); Bustard, Cynthia Jean (Littleton, CO)

    1999-01-01T23:59:59.000Z

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  16. Oil and gas exploration system and method for detecting trace amounts of hydrocarbon gases in the atmosphere

    DOE Patents [OSTI]

    Wamsley, Paula R. (Littleton, CO); Weimer, Carl S. (Littleton, CO); Nelson, Loren D. (Evergreen, CO); O'Brien, Martin J. (Pine, CO)

    2003-01-01T23:59:59.000Z

    An oil and gas exploration system and method for land and airborne operations, the system and method used for locating subsurface hydrocarbon deposits based upon a remote detection of trace amounts of gases in the atmosphere. The detection of one or more target gases in the atmosphere is used to indicate a possible subsurface oil and gas deposit. By mapping a plurality of gas targets over a selected survey area, the survey area can be analyzed for measurable concentration anomalies. The anomalies are interpreted along with other exploration data to evaluate the value of an underground deposit. The system includes a differential absorption lidar (DIAL) system with a spectroscopic grade laser light and a light detector. The laser light is continuously tunable in a mid-infrared range, 2 to 5 micrometers, for choosing appropriate wavelengths to measure different gases and avoid absorption bands of interference gases. The laser light has sufficient optical energy to measure atmospheric concentrations of a gas over a path as long as a mile and greater. The detection of the gas is based on optical absorption measurements at specific wavelengths in the open atmosphere. Light that is detected using the light detector contains an absorption signature acquired as the light travels through the atmosphere from the laser source and back to the light detector. The absorption signature of each gas is processed and then analyzed to determine if a potential anomaly exists.

  17. Geologic flow characterization using tracer techniques

    SciTech Connect (OSTI)

    Klett, R. D.; Tyner, C. E.; Hertel, Jr., E. S.

    1981-04-01T23:59:59.000Z

    A new tracer flow-test system has been developed for in situ characterization of geologic formations. This report describes two sets of test equipment: one portable and one for testing in deep formations. Equations are derived for in situ detector calibration, raw data reduction, and flow logging. Data analysis techniques are presented for computing porosity and permeability in unconfined isotropic media, and porosity, permeability and fracture characteristics in media with confined or unconfined two-dimensional flow. The effects of tracer pulse spreading due to divergence, dispersion, and porous formations are also included.

  18. Gas seal for an in situ oil shale retort and method of forming thermal barrier

    DOE Patents [OSTI]

    Burton, III, Robert S. (Mesa, CO)

    1982-01-01T23:59:59.000Z

    A gas seal is provided in an access drift excavated in a subterranean formation containing oil shale. The access drift is adjacent an in situ oil shale retort and is in gas communication with the fragmented permeable mass of formation particles containing oil shale formed in the in situ oil shale retort. The mass of formation particles extends into the access drift, forming a rubble pile of formation particles having a face approximately at the angle of repose of fragmented formation. The gas seal includes a temperature barrier which includes a layer of heat insulating material disposed on the face of the rubble pile of formation particles and additionally includes a gas barrier. The gas barrier is a gas-tight bulkhead installed across the access drift at a location in the access drift spaced apart from the temperature barrier.

  19. Quantitative interpretation of tracer test data | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethod Jump to:ThisPublicPutnamQuail Valley, California:tracer

  20. Portable instrument and method for detecting reduced sulfur compounds in a gas

    DOE Patents [OSTI]

    Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

    1983-06-01T23:59:59.000Z

    A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

  1. A method for evaluating a gas reservoir using a digital computer

    E-Print Network [OSTI]

    Garb, Forrest Allan

    1963-01-01T23:59:59.000Z

    when natural gas was first used for lighting the city of Fredonia, New York. In 1947, coal satisfied about 50 percent of the nation's energy requirements. Just 15 years later hydrocarbons were providing about 73 percent of the en- ergy... and it is estimated that by 1970, natural gas will supply 35 percent and oil 41 percent of the total energy requirements in the United States. Total natural gas sales today are increasing at about nine percent per 1 year. The first natural gas pipeline was a 25...

  2. Apparatus and method for fast recovery and charge of insulation gas

    DOE Patents [OSTI]

    Jordan, Kevin

    2013-09-03T23:59:59.000Z

    An insulation gas recovery and charge apparatus is provided comprising a pump, a connect, an inflatable collection device and at least one valve.

  3. An Embedded Boundary Method for the Modeling of Unsteady Combustion in an Industrial GasFired Furnace \\Lambda

    E-Print Network [OSTI]

    for the convective, viscous, and radiative heat transport terms in the mixed cells, while a finite element [20] which accounts for species diffusion, convective and radiative heat transfer, viscous transportAn Embedded Boundary Method for the Modeling of Unsteady Combustion in an Industrial Gas

  4. Method of making a continuous ceramic fiber composite hot gas filter

    DOE Patents [OSTI]

    Hill, Charles A. (Lynchburg, VA); Wagner, Richard A. (Lynchburg, VA); Komoroski, Ronald G. (Lynchburg, VA); Gunter, Greg A. (Lynchburg, VA); Barringer, Eric A. (Lynchburg, VA); Goettler, Richard W. (Lynchburg, VA)

    1999-01-01T23:59:59.000Z

    A ceramic fiber composite structure particularly suitable for use as a hot gas cleanup ceramic fiber composite filter and method of making same from ceramic composite material has a structure which provides for increased strength and toughness in high temperature environments. The ceramic fiber composite structure or filter is made by a process in which a continuous ceramic fiber is intimately surrounded by discontinuous chopped ceramic fibers during manufacture to produce a ceramic fiber composite preform which is then bonded using various ceramic binders. The ceramic fiber composite preform is then fired to create a bond phase at the fiber contact points. Parameters such as fiber tension, spacing, and the relative proportions of the continuous ceramic fiber and chopped ceramic fibers can be varied as the continuous ceramic fiber and chopped ceramic fiber are simultaneously formed on the porous vacuum mandrel to obtain a desired distribution of the continuous ceramic fiber and the chopped ceramic fiber in the ceramic fiber composite structure or filter.

  5. Method to Assess the Radionuclide Inventory of Irradiated Graphite from Gas-Cooled Reactors - 13072

    SciTech Connect (OSTI)

    Poncet, Bernard [EDF-CIDEN, 154 Avenue Thiers, CS 60018, F-69458 LYON cedex 06 (France)] [EDF-CIDEN, 154 Avenue Thiers, CS 60018, F-69458 LYON cedex 06 (France)

    2013-07-01T23:59:59.000Z

    About 17,000 t of irradiated graphite waste will be produced from the decommissioning of the six French gas-cooled nuclear reactors. Determining the radionuclide (RN) content of this waste is of relevant importance for safety reasons and in order to determine the best way to manage them. For many reasons the impurity content that gave rise to the RNs in irradiated graphite by neutron activation during operation is not always well known and sometimes actually unknown. So, assessing the RN content by the use of traditional calculation activation, starting from assumed impurity content, leads to a false assessment. Moreover, radiochemical measurements exhibit very wide discrepancies especially on RN corresponding to precursor at the trace level such as natural chlorine corresponding to chlorine 36. This wide discrepancy is unavoidable and is due to very simple reasons. The level of impurity is very low because the uranium fuel used at that very moment was not enriched, so it was a necessity to have very pure nuclear grade graphite and the very low size of radiochemical sample is a simple technical constraint because device size used to get mineralization product for measurement purpose is limited. The assessment of a radionuclide inventory only based on few number of radiochemical measurements lead in most cases, to a gross over or under-estimation that is detrimental for graphite waste management. A method using an identification calculation-measurement process is proposed in order to assess a radiological inventory for disposal sizing purpose as precise as possible while guaranteeing its upper character. This method present a closer approach to the reality of the main phenomenon at the origin of RNs in a reactor, while also incorporating the secondary effects that can alter this result such as RN (or its precursor) release during reactor operation. (authors)

  6. Informal Report USE OF PERFLUOROCARBON TRACER (PFT) TECHNOLOGY

    E-Print Network [OSTI]

    BNL-66726 Informal Report USE OF PERFLUOROCARBON TRACER (PFT) TECHNOLOGY FOR SUBSURFACE BARRIER and concentrations in the range of a few hundred ppm. Approximately 65 liters of air laced with tracer was injected

  7. GEOLOGIC ASSESSMENT OF DRILLING, COMPLETION, AND STIMULATION METHODS IN SELECTED GAS SHALE PLAYS WORLDWIDE 

    E-Print Network [OSTI]

    Patel, Harsh Jay

    2014-04-11T23:59:59.000Z

    the gas shale formations that have been identified in the world energy consortium. The natural gas in shales and other unconventional reservoirs can be easily used to generate electricity, or it can be turned into liquids and used by the transportation...

  8. An Advisory System For Selecting Drilling Technologies and Methods in Tight Gas Reservoirs

    E-Print Network [OSTI]

    Pilisi, Nicolas

    2010-01-16T23:59:59.000Z

    The supply and demand situation is crucial for the oil and gas industry during the first half of the 21st century. For the future, we will see two trends going in opposite directions: a decline in discoveries of conventional oil and gas reservoirs...

  9. Chelated Indium Activable Tracers for Geothermal Reservoirs

    E-Print Network [OSTI]

    Stanford University

    Center (SLAC), for providing the califclmiurh-252 neutron source. Appreciation is extended to Lew, rock size, and temperature on the tracer adsoqjtion and ther- mal degradation. The rock employed for these measurements was gragwacke, a prek valent rock type at The Geysers, California geothermal field. The re

  10. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Bustard, C.J.

    1999-04-13T23:59:59.000Z

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 5 figs.

  11. A continuous fast-response dual-tracer analyzer for halogenated atmospheric tracer studies

    SciTech Connect (OSTI)

    Rydock, J.P.; Lamb, B.K. [Washington State Univ., Pullman, WA (United States)] [Washington State Univ., Pullman, WA (United States)

    1994-10-01T23:59:59.000Z

    An apparatus for the simultaneous measurement of two tracers, sulfur hexafluoride (SF6) and a perfluorocarbon compound, is introduced. The new instrument is a modification of a commercially available fast-response, continuous analyzer for single halogenated atmospheric tracer studies. A two-channel flow system was implemented consisting of an alumina cartridge in one channel and a glass beads cartridge of equal flow resistance in the second channel. The alumina passes only sulfur hexafluoride, while the glass beads pass both SF6 and the perfluoroarbon tracer. The SF6 is quantified directly from the electron capture detector (ECD) signal in the alumina channel, and the perfluorocarbon concentration is obtained from the difference of the ECD responses in the two channels. The dual-tracer analyzer is field portable for mobile operations or fixed-location monitoring, has a response time of 1.2 s, and has limits of detection of about 15 pptv for SF6 and 10 pptv for perfluoro-methylcyclohexane, which was the principal perfluorocarbon tracer used in this study. The present instrument configuration, which requires periodic purging of the adsorbent trap, can obtain continuous measurements for a 10-15-min segment in every half hour of operation. Dual-tracer data from a field demonstration test are presented.

  12. Influence of mechanical-biological waste pre-treatment methods on the gas formation in landfills

    SciTech Connect (OSTI)

    Bockreis, A. [Technische Universitaet Darmstadt, Darmstadt University of Technology, Institute for Water Supply and Groundwater Protection, Wastewater Technology, Waste Management, Industrial Material Flows and Environmental Planning (Institute WAR), Chair of Waste Management and Waste Technology, Darmstadt (Germany)]. E-mail: a.bockreis@iwar.tu-darmstadt.de; Steinberg, I. [Technische Universitaet Darmstadt, Darmstadt University of Technology, Institute for Water Supply and Groundwater Protection, Wastewater Technology, Waste Management, Industrial Material Flows and Environmental Planning (Institute WAR), Chair of Waste Management and Waste Technology, Darmstadt (Germany)

    2005-07-01T23:59:59.000Z

    In order to minimise emissions and environmental impacts, only pre-treated waste should be disposed of. For the last six years, a series of continuous experiments has been conducted at the Institute WAR, TU Darmstadt, in order to determine the emissions from pre-treated waste. Different kinds of pre-treated waste were incubated in several reactors and various data, including production and composition of the gas and the leachate, were collected. In this paper, the interim results of gas production and the gas composition from different types of waste after a running time of six years are presented and discussed.

  13. Systems and methods for using a boehmite bond-coat with polyimide membranes for gas separation

    DOE Patents [OSTI]

    Polishchuk, Kimberly Ann

    2013-03-05T23:59:59.000Z

    The subject matter disclosed herein relates to gas separation membranes and, more specifically, to polyimide gas separation membranes. In an embodiment, a gas separation membrane includes a porous substrate, a substantially continuous polyimide membrane layer, and one or more layers of boehmite nanoparticles disposed between the porous substrate and the polyimide membrane layer to form a bond-coat layer. The bond-coat layer is configured to improve the adhesion of the polyimide membrane layer to the porous substrate, and the polyimide membrane layer has a thickness approximately 100 nm or less.

  14. System and method for monitoring wet bulb temperature in a flue gas stream

    SciTech Connect (OSTI)

    Glover, R.L.; Bland, V.V.

    1990-01-02T23:59:59.000Z

    This patent describes in a system for monitoring wet bulb temperature in a flue gas stream means for extracting a sample of the gas from the flue, means for heating the sample to maintain the sample at substantially the same temperature as the gas in the flue, a sensor for measuring the wet bulb temperature of the sample, a reservoir of liquid, a liquid absorbent wick surrounding the sensor and extending into the liquid in the reservoir, and means for maintaining the liquid in the reservoir at a substantially constant level.

  15. A New Method for History Matching and Forecasting Shale Gas/Oil Reservoir Production Performance with Dual and Triple Porosity Models

    E-Print Network [OSTI]

    Samandarli, Orkhan

    2012-10-19T23:59:59.000Z

    Different methods have been proposed for history matching production of shale gas/oil wells which are drilled horizontally and usually hydraulically fractured with multiple stages. These methods are simulation, analytical models, and empirical...

  16. Method for removal and stabilization of mercury in mercury-containing gas streams

    DOE Patents [OSTI]

    Broderick, Thomas E.

    2005-09-13T23:59:59.000Z

    The present invention is directed to a process and apparatus for removing and stabilizing mercury from mercury-containing gas streams. A gas stream containing vapor phase elemental and/or speciated mercury is contacted with reagent, such as an oxygen-containing oxidant, in a liquid environment to form a mercury-containing precipitate. The mercury-containing precipitate is kept or placed in solution and reacts with one or more additional reagents to form a solid, stable mercury-containing compound.

  17. Method of Generating Hydrocarbon Reagents from Diesel, Natural Gas and Other Logistical Fuels

    DOE Patents [OSTI]

    Herling, Darrell R (Richland, WA) [Richland, WA; Aardahl, Chris L. (Richland, WA) [Richland, WA; Rozmiarek, Robert T. (Middleton, WI) [Middleton, WI; Rappe, Kenneth G. (Richland, WA) [Richland, WA; Wang, Yong (Richland, WA) [Richland, WA; Holladay, Jamelyn D. (Kennewick, WA) [Kennewick, WA

    2008-10-14T23:59:59.000Z

    The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

  18. Method of generating hydrocarbon reagents from diesel, natural gas and other logistical fuels

    DOE Patents [OSTI]

    Herling, Darrell R. (Richland, WA); Aardahl, Chris L. (Richland, WA); Rozmiarek, Robert T. (Middleton, WI); Rappe, Kenneth G. (Richland, WA); Wang, Yong (Richland, WA); Holladay, Jamelyn D. (Kennewick, WA)

    2010-06-29T23:59:59.000Z

    The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

  19. Method for microwave plasma assisted supersonic gas jet deposition of thin films

    DOE Patents [OSTI]

    Schmitt, III, Jerome J. (New Haven, CT); Halpern, Bret L. (Bethany, CT)

    1994-01-01T23:59:59.000Z

    A thin film is formed on a substrate positioned in a vacuum chamber by use of a gas jet apparatus affixed to a vacuum chamber port and having an outer nozzle with an interior cavity into which carrier gas is fed, an inner nozzle located within the outer nozzle interior cavity into which reactant gas is introduced, a tip of the inner nozzle being recessed from the vacuum chamber port within the outer nozzle interior cavity, and a microwave discharge device configured about the apparatus for generating a discharge in the carrier gas and reactant gas only in a portion of the outer nozzle interior cavity extending from approximately the inner nozzle tip towards the vacuum chamber. A supersonic free jet of carrier gas transports vapor species generated in the microwave discharge to the surface of the substrate to form a thin film on the substrate. The substrate can be translated from the supersonic jet to a second supersonic jet in less time than needed to complete film formation so that the film is chemically composed of chemical reaction products of vapor species in the jets.

  20. Method for microwave plasma assisted supersonic gas jet deposition of thin films

    DOE Patents [OSTI]

    Schmitt, J.J. III; Halpern, B.L.

    1994-10-18T23:59:59.000Z

    A thin film is formed on a substrate positioned in a vacuum chamber by use of a gas jet apparatus affixed to a vacuum chamber port and having an outer nozzle with an interior cavity into which carrier gas is fed, an inner nozzle located within the outer nozzle interior cavity into which reactant gas is introduced, a tip of the inner nozzle being recessed from the vacuum chamber port within the outer nozzle interior cavity, and a microwave discharge device configured about the apparatus for generating a discharge in the carrier gas and reactant gas only in a portion of the outer nozzle interior cavity extending from approximately the inner nozzle tip towards the vacuum chamber. A supersonic free jet of carrier gas transports vapor species generated in the microwave discharge to the surface of the substrate to form a thin film on the substrate. The substrate can be translated from the supersonic jet to a second supersonic jet in less time than needed to complete film formation so that the film is chemically composed of chemical reaction products of vapor species in the jets. 5 figs.

  1. Use of thermal desorption/gas chromatography as a performance-based screening method for petroleum hydrocarbons

    SciTech Connect (OSTI)

    Slavin, P.J. [GRAM, Inc., Albuquerque, NM (United States)]|[Sandia National Labs., Albuquerque, NM (United States); Crandall, K. [Brown and Root Environmental, Albuquerque, NM (United States); Dawson, L.; Kottenstette, R. [Sandia National Labs., Albuquerque, NM (United States); Wade, M. [INTERA, Inc., Albuquerque, NM (United States)]|[Sandia National Labs., Albuquerque, NM (United States)

    1996-08-01T23:59:59.000Z

    Thermal desorption/gas chromatography (TD/GC) was used to screen soil samples on site for total petroleum hydrocarbon (TPH) content during a RCRA Facility Investigation (RFI). It proved to be a rapid, cost- effective tool for detecting non-aromatic mineral oil in soil. The on- site TD/GC results correlated well with those generated at an off- site laboratory for samples analyzed in accordance with EPA Method 418.1.

  2. Asian Tracer Experiment and Atmospheric Modeling (TEAM) Project: Draft Field Work Plan for the Asian Long-Range Tracer Experiment

    SciTech Connect (OSTI)

    Allwine, K Jerry; Flaherty, Julia E.

    2007-08-01T23:59:59.000Z

    This report provides an experimental plan for a proposed Asian long-range tracer study as part of the international Tracer Experiment and Atmospheric Modeling (TEAM) Project. The TEAM partners are China, Japan, South Korea and the United States. Optimal times of year to conduct the study, meteorological measurements needed, proposed tracer release locations, proposed tracer sampling locations and the proposed durations of tracer releases and subsequent sampling are given. Also given are the activities necessary to prepare for the study and the schedule for completing the preparation activities leading to conducting the actual field operations. This report is intended to provide the TEAM members with the information necessary for planning and conducting the Asian long-range tracer study. The experimental plan is proposed, at this time, to describe the efforts necessary to conduct the Asian long-range tracer study, and the plan will undoubtedly be revised and refined as the planning goes forward over the next year.

  3. Systems and methods for detecting a flame in a fuel nozzle of a gas turbine

    DOE Patents [OSTI]

    Kraemer, Gilbert Otto; Storey, James Michael; Lipinski, John; Mestroni, Julio Enrique; Williamson, David Lee; Marshall, Jason Randolph; Krull, Anthony

    2013-05-07T23:59:59.000Z

    A system may detect a flame about a fuel nozzle of a gas turbine. The gas turbine may have a compressor and a combustor. The system may include a first pressure sensor, a second pressure sensor, and a transducer. The first pressure sensor may detect a first pressure upstream of the fuel nozzle. The second pressure sensor may detect a second pressure downstream of the fuel nozzle. The transducer may be operable to detect a pressure difference between the first pressure sensor and the second pressure sensor.

  4. ANALYSIS OF GAS PRODUCTION FROM HYDRAULICALLY FRACTURED WELLS IN THE HAYNESVILLE SHALE USING SCALING METHODS

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    unconventional gas plays in the US. It is also one of the deepest, with wells reaching more than 10,000 feet,580 wells which have entered exponential decline due to pressure interference. We use a simple physical et al. (2013), developed to study the Barnett Shale, to determine well decline curves

  5. Gas stream clean-up filter and method for forming same

    DOE Patents [OSTI]

    Mei, Joseph S. (Morgantown, WV); DeVault, James (Fairmont, WV); Halow, John S. (Waynesburg, PA)

    1993-01-01T23:59:59.000Z

    A gas cleaning filter is formed in-situ within a vessel containing a fluidizable bed of granular material of a relatively large size fraction. A filter membrane provided by a porous metal or ceramic body or such a body supported a perforated screen on one side thereof is coated in-situ with a layer of the granular material from the fluidized bed by serially passing a bed-fluidizing gas stream through the bed of granular material and the membrane. The layer of granular material provides the filtering medium for the combined membrane-granular layer filter. The filter is not blinded by the granular material and provides for the removal of virtually all of the particulates from a process gas stream. The granular material can be at least partially provided by a material capable of chemically reacting with and removing sulfur compounds from the process gas stream. Low level radioactive waste containing organic material may be incinerated in a fluidized bed in communication with the described filter for removing particulates from the gaseous combustion products.

  6. Inductively coupled plasma mass spectrometry for stable isotope metabolic tracer studies of living systems

    SciTech Connect (OSTI)

    Luong, E.

    1999-05-10T23:59:59.000Z

    This dissertation focuses on the development of methods for stable isotope metabolic tracer studies in living systems using inductively coupled plasma single and dual quadrupole mass spectrometers. Sub-nanogram per gram levels of molybdenum (Mo) from human blood plasma are isolated by the use of anion exchange alumina microcolumns. Million-fold more concentrated spectral and matrix interferences such as sodium, chloride, sulfate, phosphate, etc. in the blood constituents are removed from the analyte. The recovery of Mo from the alumina column is 82 {+-} 5% (n = 5). Isotope dilution inductively coupled plasma mass spectrometry (ID-ICP-MS) is utilized for the quantitative ultra-trace concentration determination of Mo in bovine and human blood samples. The average Mo concentration in reference bovine serum determined by this method is 10.2 {+-} 0.4 ng/g, while the certified value is 11.5 {+-} 1.1 ng/g (95% confidence interval). The Mo concentration of one pool of human blood plasma from two healthy male donors is 0.5 {+-} 0.1 ng/g. The inductively coupled plasma twin quadrupole mass spectrometer (ICP-TQMS) is used to measure the carbon isotope ratio from non-volatile organic compounds and bio-organic molecules to assess the ability as an alternative analytical method to gas chromatography combustion isotope ratio mass spectrometry (GC-combustion-IRMS). Trytophan, myoglobin, and {beta}-cyclodextrin are chosen for the study, initial observation of spectral interference of {sup 13}C{sup +} with {sup 12}C{sup 1}H{sup +} comes from the incomplete dissociation of myoglobin and/or {beta}-cyclodextrin.

  7. Method of determining the extent to which a nickel structure has been attached by a fluorine-containing gas

    DOE Patents [OSTI]

    Brusie, James P. (Oak Ridge, TN)

    2004-07-13T23:59:59.000Z

    The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

  8. Method of Determining the Extent to which a Nickel Structure has been Attached by a Fluorine-Containing Gas

    DOE Patents [OSTI]

    Brusie, James P.

    2004-07-13T23:59:59.000Z

    The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

  9. Method of joining a vane cavity insert to a nozzle segment of a gas turbine

    DOE Patents [OSTI]

    Burdgick, Steven Sebastian (Schenectady, NY)

    2002-01-01T23:59:59.000Z

    An insert containing apertures for impingement cooling a nozzle vane of a nozzle segment in a gas turbine is inserted into one end of the vane. The leading end of the insert is positioned slightly past a rib adjacent the opposite end of the vane through which the insert is inserted. The end of the insert is formed or swaged into conformance with the inner margin of the rib. The insert is then brazed or welded to the rib.

  10. Method and apparatus for selective capture of gas phase analytes using metal .beta.-diketonate polymers

    DOE Patents [OSTI]

    Harvey, Scott D [Kennewick, WA

    2011-06-21T23:59:59.000Z

    A process and sensor device are disclosed that employ metal .beta.-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal .beta.-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.

  11. An Integrated Approach to Characterizing Bypassed Oil in Heterogeneous and Fractured Reservoirs Using Partitioning Tracers

    SciTech Connect (OSTI)

    Akhil Datta-Gupta

    2006-12-31T23:59:59.000Z

    We explore the use of efficient streamline-based simulation approaches for modeling partitioning interwell tracer tests in hydrocarbon reservoirs. Specifically, we utilize the unique features of streamline models to develop an efficient approach for interpretation and history matching of field tracer response. A critical aspect here is the underdetermined and highly ill-posed nature of the associated inverse problems. We have investigated the relative merits of the traditional history matching ('amplitude inversion') and a novel travel time inversion in terms of robustness of the method and convergence behavior of the solution. We show that the traditional amplitude inversion is orders of magnitude more non-linear and the solution here is likely to get trapped in local minimum, leading to inadequate history match. The proposed travel time inversion is shown to be extremely efficient and robust for practical field applications. The streamline approach is generalized to model water injection in naturally fractured reservoirs through the use of a dual media approach. The fractures and matrix are treated as separate continua that are connected through a transfer function, as in conventional finite difference simulators for modeling fractured systems. A detailed comparison with a commercial finite difference simulator shows very good agreement. Furthermore, an examination of the scaling behavior of the computation time indicates that the streamline approach is likely to result in significant savings for large-scale field applications. We also propose a novel approach to history matching finite-difference models that combines the advantage of the streamline models with the versatility of finite-difference simulation. In our approach, we utilize the streamline-derived sensitivities to facilitate history matching during finite-difference simulation. The use of finite-difference model allows us to account for detailed process physics and compressibility effects. The approach is very fast and avoids much of the subjective judgments and time-consuming trial-and-errors associated with manual history matching. We demonstrate the power and utility of our approach using a synthetic example and two field examples. We have also explored the use of a finite difference reservoir simulator, UTCHEM, for field-scale design and optimization of partitioning interwell tracer tests. The finite-difference model allows us to include detailed physics associated with reactive tracer transport, particularly those related with transverse and cross-streamline mechanisms. We have investigated the potential use of downhole tracer samplers and also the use of natural tracers for the design of partitioning tracer tests. Finally, we discuss several alternative ways of using partitioning interwell tracer tests (PITTs) in oil fields for the calculation of oil saturation, swept pore volume and sweep efficiency, and assess the accuracy of such tests under a variety of reservoir conditions.

  12. Tracers and Exploration Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic|Industrial Sector,DepartmentFebruary 19,TopProcess |Town o5Tracers

  13. abdominal tracer activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the curvature of the tracer affects its translational and rotational motion in an active environment. We find that even very small amounts of curvature are sufficient for the...

  14. Using Thermally-Degrading, Partitioning, and Nonreactive Tracers...

    Broader source: Energy.gov (indexed) [DOE]

    surface area to volume ratios in fractured rock groundwater systems - differential tracer transport has also been used by Brookhaven National Laboratory (BNL) and others in oil...

  15. Apparatus and method for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Felix, Larry Gordon; Farthing, William Earl; Irvin, James Hodges; Snyder, Todd Robert

    2010-05-11T23:59:59.000Z

    A dilution apparatus for diluting a gas sample. The apparatus includes a sample gas conduit having a sample gas inlet end and a diluted sample gas outlet end, and a sample gas flow restricting orifice disposed proximate the sample gas inlet end connected with the sample gas conduit and providing fluid communication between the exterior and the interior of the sample gas conduit. A diluted sample gas conduit is provided within the sample gas conduit having a mixing end with a mixing space inlet opening disposed proximate the sample gas inlet end, thereby forming an annular space between the sample gas conduit and the diluted sample gas conduit. The mixing end of the diluted sample gas conduit is disposed at a distance from the sample gas flow restricting orifice. A dilution gas source connected with the sample gas inlet end of the sample gas conduit is provided for introducing a dilution gas into the annular space, and a filter is provided for filtering the sample gas. The apparatus is particularly suited for diluting heated sample gases containing one or more condensable components.

  16. Standard Test Method for Isotopic Analysis of Uranium Hexafluoride by Single-Standard Gas Source Multiple Collector Mass Spectrometer Method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2011-01-01T23:59:59.000Z

    1.1 This test method is applicable to the isotopic analysis of uranium hexafluoride (UF6) with 235U concentrations less than or equal to 5 % and 234U, 236U concentrations of 0.0002 to 0.1 %. 1.2 This test method may be applicable to the analysis of the entire range of 235U isotopic compositions providing that adequate Certified Reference Materials (CRMs or traceable standards) are available. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety health practices and determine the applicability of regulatory limitations prior to use.

  17. Molecular gas and AGN fueling

    E-Print Network [OSTI]

    F. Combes

    2003-08-01T23:59:59.000Z

    CO emission, tracing the molecular content and distribution in galaxies, is a privileged tool to trace gas towards the nucleus, since the HI tracer is in general depleted there. A review is done of recent CO line observations, with sufficient spatial resolution to indicate the morphology and kinematics of the gas near the nucleus. The puzzling result that nuclei presently observed in an active phase have little sign of fueling, is discussed.

  18. Iron catalyst for preparation of polymethylene from synthesis gas and method for producing the catalyst

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.

    1990-05-15T23:59:59.000Z

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

  19. Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas (Morgantown, WV)

    1989-01-01T23:59:59.000Z

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

  20. Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor

    DOE Patents [OSTI]

    Mahajan, Devinder

    2005-07-26T23:59:59.000Z

    The invention provides a homogenous catalyst for the production of methanol from purified synthesis gas at low temperature and low pressure which includes a transition metal capable of forming transition metal complexes with coordinating ligands and an alkoxide, the catalyst dissolved in a methanol solvent system, provided the transition metal complex is not transition metal carbonyl. The coordinating ligands can be selected from the group consisting of N-donor ligands, P-donor ligands, O-donor ligands, C-donor ligands, halogens and mixtures thereof.

  1. Iron catalyst for preparation of polymethylene from synthesis gas and method for producing the catalyst

    DOE Patents [OSTI]

    Sapienza, Richard S. (1 Miller Ave., Shoreham, NY 11786); Slegeir, William A. (7 Florence Rd., Hampton Bays, NY 11946)

    1990-01-01T23:59:59.000Z

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

  2. Gas-Tight Sealing Method for Solid Oxide Fuel Cells - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.Newof EnergyFunding OpportunityF GGaryPortal Gas-Tight

  3. Development and introduction of methods for extracting hydrogen sulfide and hydrogen cyanide from coke-oven gas

    SciTech Connect (OSTI)

    Litvinenko, M.S.; Zaichenko, V.M.

    1980-01-01T23:59:59.000Z

    The progress between 1933 and the present in desulfurizing coal gas from coke ovens and making use of the by-products to produce sulfuric acid, thioyanates, etc. is described. The vacuum carbonate process and the monoethanolamine method are apparently now preferred, but some plants are still using modified arsenic-soda processes. More recently additional by-products have been thiocyanates (for producing acrylonitrile fiber) and hydrogen xanthanates. The production of other organic sulfur and cyanide compounds has been investigated for use as herbicides, corrosion inhibitors, etc. (LTN)

  4. Method for extending the useful shelf-life of refrigerated red blood cells by flushing with inert gas

    DOE Patents [OSTI]

    Bitensky, M.W.; Yoshida, Tatsuro

    1997-04-29T23:59:59.000Z

    A method is disclosed using oxygen removal for extending the useful shelf-life of refrigerated red blood cells. A cost-effective, 4 C storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. Preservation of adenosine triphosphate levels and reduction in hemolysis and in membrane vesicle production of red blood cells stored at 4 C for prolonged periods of time is achieved by removing oxygen from the red blood cells at the time of storage; in particular, by flushing with an inert gas. Adenosine triphosphate levels of the stored red blood cells are boosted in some samples by addition of ammonium phosphate. 4 figs.

  5. Method for extending the useful shelf-life of refrigerated red blood cells by flushing with inert gas

    DOE Patents [OSTI]

    Bitensky, Mark W. (Los Alamos, NM); Yoshida, Tatsuro (Los Alamos, NM)

    1997-01-01T23:59:59.000Z

    Method using oxygen removal for extending the useful shelf-life of refrigerated red blood cells. A cost-effective, 4.degree. C. storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. Preservation of adenosine triphosphate levels and reduction in hemolysis and in membrane vesicle production of red blood cells stored at 4.degree. C. for prolonged periods of time is achieved by removing oxygen therefrom at the time of storage; in particular, by flushing with an inert gas. Adenosine triphosphate levels of the stored red blood cells are boosted in some samples by addition of ammonium phosphate.

  6. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, D. Kwok-Keung; Chang, Shih-Ger

    1987-08-25T23:59:59.000Z

    The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

  7. Adding Environmental Gas Physics to the Semi-Analytic Method for Galaxy Formation: Gravitational Heating

    E-Print Network [OSTI]

    S. Khochfar; J. P. Ostriker

    2008-02-12T23:59:59.000Z

    We present results of an attempt to include more detailed gas physics motivated from hydrodynamical simulations within semi-analytic models (SAM) of galaxy formation, focusing on the role that environmental effects play. The main difference to previous SAMs is that we include 'gravitational' heating of the intra-cluster medium (ICM) by the net surplus of gravitational potential energy released from gas that has been stripped from infalling satellites. Gravitational heating appears to be an efficient heating source able to prevent cooling in environments corresponding to dark matter halos more massive than $\\sim 10^{13} $M$_{\\odot}$. The energy release by gravitational heating can match that by AGN-feedback in massive galaxies and can exceed it in the most massive ones. However, there is a fundamental difference in the way the two processes operate. Gravitational heating becomes important at late times, when the peak activity of AGNs is already over, and it is very mass dependent. This mass dependency and time behaviour gives the right trend to recover down-sizing in the star-formation rate of massive galaxies. Abridged...

  8. Systems and methods of monitoring acoustic pressure to detect a flame condition in a gas turbine

    DOE Patents [OSTI]

    Ziminsky, Willy Steve (Simpsonville, SC); Krull, Anthony Wayne (Anderson, SC); Healy, Timothy Andrew (Simpsonville, SC), Yilmaz, Ertan (Glenville, NY)

    2011-05-17T23:59:59.000Z

    A method may detect a flashback condition in a fuel nozzle of a combustor. The method may include obtaining a current acoustic pressure signal from the combustor, analyzing the current acoustic pressure signal to determine current operating frequency information for the combustor, and indicating that the flashback condition exists based at least in part on the current operating frequency information.

  9. Cooling circuit for and method of cooling a gas turbine bucket

    DOE Patents [OSTI]

    Jacala, Ariel C. P. (Simpsonville, SC)

    2002-01-01T23:59:59.000Z

    A closed internal cooling circuit for a gas turbine bucket includes axial supply and return passages in the dovetail of the bucket. A first radial outward supply passage provides cooling medium to and along a passageway adjacent the leading edge and then through serpentine arranged passageways within the airfoil to a chamber adjacent the airfoil tip. A second radial passage crosses over the radial return passage for supplying cooling medium to and along a pair of passageways along the trailing edge of the airfoil section. The last passageway of the serpentine passageways and the pair of passageways communicate one with the other in the chamber for returning spent cooling medium radially inwardly along divided return passageways to the return passage. In this manner, both the leading and trailing edges are cooled using the highest pressure, lowest temperature cooling medium.

  10. Compressor discharge bleed air circuit in gas turbine plants and related method

    DOE Patents [OSTI]

    Anand, Ashok Kumar (Niskayuna, NY); Berrahou, Philip Fadhel (Latham, NY); Jandrisevits, Michael (Clifton Park, NY)

    2003-04-08T23:59:59.000Z

    A gas turbine system that includes a compressor, a turbine component and a load, wherein fuel and compressor discharge bleed air are supplied to a combustor and gaseous products of combustion are introduced into the turbine component and subsequently exhausted to atmosphere. A compressor discharge bleed air circuit removes bleed air from the compressor and supplies one portion of the bleed air to the combustor and another portion of the compressor discharge bleed air to an exhaust stack of the turbine component in a single cycle system, or to a heat recovery steam generator in a combined cycle system. In both systems, the bleed air diverted from the combustor may be expanded in an air expander to reduce pressure upstream of the exhaust stack or heat recovery steam generator.

  11. Compressor discharge bleed air circuit in gas turbine plants and related method

    DOE Patents [OSTI]

    Anand, Ashok Kumar (Niskayuna, NY); Berrahou, Philip Fadhel (Latham, NY); Jandrisevits, Michael (Clifton Park, NY)

    2002-01-01T23:59:59.000Z

    A gas turbine system that includes a compressor, a turbine component and a load, wherein fuel and compressor discharge bleed air are supplied to a combustor and gaseous products of combustion are introduced into the turbine component and subsequently exhausted to atmosphere. A compressor discharge bleed air circuit removes bleed air from the compressor and supplies one portion of the bleed air to the combustor and another portion of the compressor discharge bleed air to an exhaust stack of the turbine component in a single cycle system, or to a heat recovery steam generator in a combined cycle system. In both systems, the bleed air diverted from the combustor may be expanded in an air expander to reduce pressure upstream of the exhaust stack or heat recovery steam generator.

  12. Multispecies Reactive Tracer Test in a Sand and

    E-Print Network [OSTI]

    Multispecies Reactive Tracer Test in a Sand and Gravel Aquifer, Cape Cod, Massachusetts United;Multispecies Reactive Tracer Test in a Sand and Gravel Aquifer, Cape Cod, Massachusetts Part 2 Transport- effectiveness for prevention and control of pollution to air, land, water, and subsurface resources; protection

  13. DESCRIPTION OF HETEROGENEOUS USING PRESSURE AND TRACER DATA

    E-Print Network [OSTI]

    Stanford University

    DESCRIPTION OF HETEROGENEOUS RESERVOIRS USING PRESSURE AND TRACER DATA A DISSERTATION SUBMITTED of characterizing areally heterogeneous reservoirs through the interpretation of pressure data and tracer data for the selected reservoir model, increases the tolerance to noise in the data, increases the confidence

  14. Batch methods for enriching trace impurities in hydrogen gas for their further analysis

    DOE Patents [OSTI]

    Ahmed, Shabbir; Lee, Sheldon H.D.; Kumar, Romesh; Papdias, Dionissios D.

    2014-07-15T23:59:59.000Z

    Provided herein are batch methods and devices for enriching trace quantities of impurities in gaseous mixtures, such as hydrogen fuel. The methods and devices rely on concentrating impurities using hydrogen transport membranes wherein the time period for concentrating the sample is calculated on the basis of optimized membrane characteristics, comprising its thickness and permeance, with optimization of temperature, and wherein the enrichment of trace impurities is proportional to the pressure ratio P.sub.hi/P.sub.lo and the volume ratio V.sub.1/V.sub.2, with following detection of the impurities using commonly-available detection methods.

  15. Application of the Continuous EUR Method to Estimate Reserves in Unconventional Gas Reservoirs

    E-Print Network [OSTI]

    Currie, Stephanie M.

    2010-10-12T23:59:59.000Z

    to generate a time-dependent profile of the estimated ultimate recovery (EUR). The "objective" is to estimate the final EUR value(s) from several complimentary analyses. In this work we present the "Continuous EUR Method" to estimate reserves...

  16. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOE Patents [OSTI]

    Koermer, Gerald S. (Basking Ridge, NJ); Moini, Ahmad (Princeton, NJ); Furbeck, Howard (Hamilton, NJ); Castellano, Christopher R. (Ringoes, NJ)

    2012-05-08T23:59:59.000Z

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver on a particulate alumina support, the silver having a diameter of less than about 20 nm. Methods of manufacturing catalysts are described in which ionic silver is impregnated on particulate hydroxylated alumina particles.

  17. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOE Patents [OSTI]

    Castellano, Christopher R. (Ringoes, NJ); Moini, Ahmad (Princeton, NJ); Koermer, Gerald S. (Basking Ridge, NJ); Furbeck, Howard (Hamilton, NJ); Schmieg, Steven J. (Troy, MI); Blint, Richard J. (Shelby Township, MI)

    2011-05-17T23:59:59.000Z

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver and a platinum group metal on a particulate alumina support, the atomic fraction of the platinum group metal being less than or equal to about 0.25. Methods of manufacturing catalysts are described in which silver is impregnated on alumina particles.

  18. Microseismic Tracer Particles for Hydraulic Fracturing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The trend toward production of hydrocarbons from unconventional reservoirs (tight gas, shale oilgas) has caused a large increase in the use of hydraulic fracture stimulation of...

  19. Development and validation of scale nuclear analysis methods for high temperature gas-cooled reactors

    SciTech Connect (OSTI)

    Gehin, Jess C [ORNL] [ORNL; Jessee, Matthew Anderson [ORNL] [ORNL; Williams, Mark L [ORNL] [ORNL; Lee, Deokjung [ORNL] [ORNL; Goluoglu, Sedat [ORNL] [ORNL; Ilas, Germina [ORNL] [ORNL; Ilas, Dan [ORNL] [ORNL; Bowman, Steve A [ORNL] [ORNL

    2010-01-01T23:59:59.000Z

    In support of the U.S. Nuclear Regulatory Commission, ORNL is updating the nuclear analysis methods and data in the SCALE code system to support modeling of HTGRs. Development activities include methods used for reactor physics, criticality safety, and radiation shielding. This paper focuses on the nuclear methods in support of reactor physics, which primarily include lattice physics for cross-section processing of both prismatic and pebble-bed designs, Monte Carlo depletion methods and efficiency improvements for double heterogeneous fuels, and validation against relevant experiments. These methods enhancements are being validated using available experimental data from the HTTR and HTR-10 startup and initial criticality experiments. Results obtained with three-dimensional Monte Carlo models of the HTTR initial core critical configurations with SCALE6/KENO show excellent agreement between the continuous energy and multigroup methods and the results are consistent with results obtained by others. A three-dimensional multigroup Monte Carlo model for the initial critical core of the HTR-10 has been developed with SCALE6/KENO based on the benchmark specifications included in the IRPhE Handbook. The core eigenvalue obtained with this model is in very good agreement with the corresponding value obtained with a consistent continuous energy MCNP5 core model.

  20. National Biomedical Tracer Facility. Project definition study

    SciTech Connect (OSTI)

    Schafer, R.

    1995-02-14T23:59:59.000Z

    We request a $25 million government-guaranteed, interest-free loan to be repaid over a 30-year period for construction and initial operations of a cyclotron-based National Biomedical Tracer Facility (NBTF) in North Central Texas. The NBTF will be co-located with a linear accelerator-based commercial radioisotope production facility, funded by the private sector at approximately $28 million. In addition, research radioisotope production by the NBTF will be coordinated through an association with an existing U.S. nuclear reactor center that will produce research and commercial radioisotopes through neutron reactions. The combined facilities will provide the full range of technology for radioisotope production and research: fast neutrons, thermal neutrons, and particle beams (H{sup -}, H{sup +}, and D{sup +}). The proposed NBTF facility includes an 80 MeV, 1 mA H{sup -} cyclotron that will produce proton-induced (neutron deficient) research isotopes.

  1. APPLICATIONS OF CFD METHOD TO GAS MIXING ANALYSIS IN A LARGE-SCALED TANK

    SciTech Connect (OSTI)

    Lee, S; Richard Dimenna, R

    2007-03-19T23:59:59.000Z

    The computational fluid dynamics (CFD) modeling technique was applied to the estimation of maximum benzene concentration for the vapor space inside a large-scaled and high-level radioactive waste tank at Savannah River site (SRS). The objective of the work was to perform the calculations for the benzene mixing behavior in the vapor space of Tank 48 and its impact on the local concentration of benzene. The calculations were used to evaluate the degree to which purge air mixes with benzene evolving from the liquid surface and its ability to prevent an unacceptable concentration of benzene from forming. The analysis was focused on changing the tank operating conditions to establish internal recirculation and changing the benzene evolution rate from the liquid surface. The model used a three-dimensional momentum coupled with multi-species transport. The calculations included potential operating conditions for air inlet and exhaust flows, recirculation flow rate, and benzene evolution rate with prototypic tank geometry. The flow conditions are assumed to be fully turbulent since Reynolds numbers for typical operating conditions are in the range of 20,000 to 70,000 based on the inlet conditions of the air purge system. A standard two-equation turbulence model was used. The modeling results for the typical gas mixing problems available in the literature were compared and verified through comparisons with the test results. The benchmarking results showed that the predictions are in good agreement with the analytical solutions and literature data. Additional sensitivity calculations included a reduced benzene evolution rate, reduced air inlet and exhaust flow, and forced internal recirculation. The modeling results showed that the vapor space was fairly well mixed and that benzene concentrations were relatively low when forced recirculation and 72 cfm ventilation air through the tank boundary were imposed. For the same 72 cfm air inlet flow but without forced recirculation, the heavier benzene gas was stratified. The results demonstrated that benzene concentrations were relatively low for typical operating configurations and conditions. Detailed results and the cases considered in the calculations will be discussed here.

  2. Environmental Tracers for Determining Water Resource Vulnerability to Climate Change

    SciTech Connect (OSTI)

    Singleton, M

    2009-07-08T23:59:59.000Z

    Predicted changes in the climate will have profound impacts on water availability in the Western US, but large uncertainties exist in our ability to predict how natural and engineered hydrological systems will respond. Most predictions suggest that the impacts of climate change on California water resources are likely to include a decrease in the percentage of precipitation that falls as snow, earlier onset of snow-pack melting, and an increase in the number of rain on snow events. These processes will require changes in infrastructure for water storage and flood control, since much of our current water supply system is built around the storage of winter precipitation as mountain snow pack. Alpine aquifers play a critical role by storing and releasing snowmelt as baseflow to streams long after seasonal precipitation and the disappearance of the snow pack, and in this manner significantly impact the stream flow that drives our water distribution systems. Mountain groundwater recharge and, in particular, the contribution of snowmelt to recharge and baseflow, has been identified as a potentially significant effect missing from current climate change impact studies. The goal of this work is to understand the behavior of critical hydrologic systems, with an emphasis on providing ground truth for next generation models of climate-water system interactions by implementing LLNL capabilities in environmental tracer and isotopic science. We are using noble gas concentrations and multiple isotopic tracers ({sup 3}H/{sup 3}He, {sup 35}S, {sup 222}Rn, {sup 2}H/{sup 1}H, {sup 18}O/{sup 16}O, and {sup 13}C/{sup 12}C) in groundwater and stream water in a small alpine catchment to (1) provide a snapshot of temperature, altitude, and physical processes at the time of recharge, (2) determine subsurface residence times (over time scales ranging from months to decades) of different groundwater age components, and (3) deconvolve the contribution of these different groundwater components to alpine stream baseflow. This research is showing that groundwater in alpine areas spends between a few years to several decades in the saturated zone below the surface, before feeding into streams or being pumped for use. This lag time may act to reduce the impact on water resources from extreme wet or dry years. Furthermore, our measurements show that the temperature of water when it reaches the water table during recharge is 4 to 9 degrees higher than would be expected for direct influx of snowmelt, and that recharge likely occurs over diffuse vegetated areas, rather than along exposed rock faces and fractures. These discoveries have implications for how alpine basins will respond to climate effects that lead to more rain than snow and earlier snow pack melting.

  3. Introduction of the Development ofIntroduction of the Development of New PET TracersNew PET Tracers

    E-Print Network [OSTI]

    Introduction of the Development ofIntroduction of the Development of New PET TracersNew PET Tracers The Center for Translational Neuroimaging KunKun--EekEek KilKil #12;Principles of PET-1 PET: Positron Emission Tomography #12;Principles of PET-2 Cyclotron Scanner #12;Principles of PET-3 0 0.01 0.02 0.03 0

  4. Method and system for capturing carbon dioxide and/or sulfur dioxide from gas stream

    DOE Patents [OSTI]

    Chang, Shih-Ger; Li, Yang; Zhao, Xinglei

    2014-07-08T23:59:59.000Z

    The present invention provides a system for capturing CO.sub.2 and/or SO.sub.2, comprising: (a) a CO.sub.2 and/or SO.sub.2 absorber comprising an amine and/or amino acid salt capable of absorbing the CO.sub.2 and/or SO.sub.2 to produce a CO.sub.2- and/or SO.sub.2-containing solution; (b) an amine regenerator to regenerate the amine and/or amino acid salt; and, when the system captures CO.sub.2, (c) an alkali metal carbonate regenerator comprising an ammonium catalyst capable catalyzing the aqueous alkali metal bicarbonate into the alkali metal carbonate and CO.sub.2 gas. The present invention also provides for a system for capturing SO.sub.2, comprising: (a) a SO.sub.2 absorber comprising aqueous alkali metal carbonate, wherein the alkali metal carbonate is capable of absorbing the SO.sub.2 to produce an alkali metal sulfite/sulfate precipitate and CO.sub.2.

  5. Casting Apparatus Including A Gas Driven Molten Metal Injector And Method

    DOE Patents [OSTI]

    Meyer, Thomas N. (Murrysville, PA)

    2004-06-01T23:59:59.000Z

    The casting apparatus (50) includes a holding vessel (10) for containing a supply of molten metal (12) and a casting mold (52) located above the holding vessel (10) and having a casting cavity (54). A molten metal injector (14) extends into the holding vessel (10) and is at least partially immersed in the molten metal (12) in the holding vessel (10). The molten metal injector (14) is in fluid communication with the casting cavity (54). The molten metal injector (14) has an injector body (16) defining an inlet opening (24) for receiving molten metal into the injector body (16). A gas pressurization source (38) is in fluid communication with the injector body (16) for cyclically pressurizing the injector body (16) and inducing molten metal to flow from the injector body (16) to the casting cavity (54). An inlet valve (42) is located in the inlet opening (24) in the injector body (16) for filling molten metal into the injector body (16). The inlet valve (42) is configured to prevent outflow of molten metal from the injector body (16) during pressurization and permit inflow of molten metal into the injector body (16) after pressurization. The inlet valve (42) has an inlet valve actuator (44) located above the surface of the supply of molten metal (12) and is operatively connected to the inlet valve (42) for operating the inlet valve (42) between open and closed positions.

  6. Methods for disassembling, replacing and assembling parts of a steam cooling system for a gas turbine

    DOE Patents [OSTI]

    Wilson, Ian D. (Mauldin, SC); Wesorick, Ronald R. (Albany, NY)

    2002-01-01T23:59:59.000Z

    The steam cooling circuit for a gas turbine includes a bore tube assembly supplying steam to circumferentially spaced radial tubes coupled to supply elbows for transitioning the radial steam flow in an axial direction along steam supply tubes adjacent the rim of the rotor. The supply tubes supply steam to circumferentially spaced manifold segments located on the aft side of the 1-2 spacer for supplying steam to the buckets of the first and second stages. Spent return steam from these buckets flows to a plurality of circumferentially spaced return manifold segments disposed on the forward face of the 1-2 spacer. Crossover tubes couple the steam supply from the steam supply manifold segments through the 1-2 spacer to the buckets of the first stage. Crossover tubes through the 1-2 spacer also return steam from the buckets of the second stage to the return manifold segments. Axially extending return tubes convey spent cooling steam from the return manifold segments to radial tubes via return elbows. The bore tube assembly, radial tubes, elbows, manifold segments and crossover tubes are removable from the turbine rotor and replaceable.

  7. Flow injection trace gas analysis method for on-site determination of organoarsenicals

    DOE Patents [OSTI]

    Aldstadt, III, Joseph H. (Orland Park, IL)

    1997-01-01T23:59:59.000Z

    A method for real-time determination of the concentration of Lewisite in the ambient atmosphere, the method includes separating and collecting a Lewisite sample from the atmosphere in a collection chamber, converting the collected Lewisite to an arsenite ion solution sample, pumping the arsenite ion containing sample to an electrochemical detector connected to the collection chamber, and electrochemically detecting the converted arsenite ions in the sample, whereby the concentration of arsenite ions detected is proportional to the concentration of Lewisite in the atmosphere.

  8. Flow injection trace gas analysis method for on-site determination of organoarsenicals

    DOE Patents [OSTI]

    Aldstadt, J.H. III

    1997-06-24T23:59:59.000Z

    A method is described for real-time determination of the concentration of Lewisite in the ambient atmosphere, the method includes separating and collecting a Lewisite sample from the atmosphere in a collection chamber, converting the collected Lewisite to an arsenite ion solution sample, pumping the arsenite ion containing sample to an electrochemical detector connected to the collection chamber, and electrochemically detecting the converted arsenite ions in the sample, whereby the concentration of arsenite ions detected is proportional to the concentration of Lewisite in the atmosphere. 2 figs.

  9. Comparison of Monte-Carlo and Einstein methods in the light-gas interactions

    E-Print Network [OSTI]

    Jacques Moret-Bailly

    2010-01-18T23:59:59.000Z

    To study the propagation of light in nebulae, many astrophysicists use a Monte-Carlo computation which does not take interferences into account. Replacing the wrong method by Einstein coefficients theory gives, on an example, a theoretical spectrum much closer to the observed one.

  10. Kinetic analysis of 18F-fluorodihydrorotenone as a deposited myocardial flow tracer: Comparison to thallium-201.

    SciTech Connect (OSTI)

    Marshall, Robert C.; Powers-Risius, Patricia; Reutter, Bryan W.; O'Neil, James P.; La Belle, Michael; Huesman, Ronald H.; VanBrocklin, Henry F.

    2004-03-01T23:59:59.000Z

    The goal of this investigation was to assess the accuracy of 18F-fluorodihydrorotenone (18F-FDHR) as a new deposited myocardial flow tracer and compare the results to those for 201Tl. Methods. The kinetics of these flow tracers were evaluated in 22 isolated, erythrocyte- and albumin-perfused rabbit hearts over a flow range encountered in patients. The two flow tracers plus a vascular reference tracer (131I-albumin) were introduced as a bolus through a port just above the aortic cannula. Myocardial extraction, retention, washout, and uptake parameters were computed from the venous outflow curves using the multiple indicator dilution technique and spectral analysis. Results. The mean initial extraction fractions of 18F-FDHR (0.85 +- 0.07) and 201Tl (0.87 +- 0.05) were not significantly different, although the initial extraction fraction for 18F-FDHR declined with flow (P < 0.0001), whereas the initial extraction fraction of 201Tl did not. Washout of 201Tl was faster (P < 0.001) and more affected by flow (P < 0.05) than 18F-FDHR washout. Except for initial extraction fraction, 18F-FDHR retention was greater (P < 0.001) and less affected by flow (P < 0.05) than 201Tl retention. Reflecting its superior retention, net uptake of 18F-FDHR was better correlated with flow than 201Tl uptake at both one and fifteen minutes after tracer introduction (P < 0.0001 for both comparisons). Conclusion. The superior correlation of 18F-FDHR uptake with flow indicates that it is a better flow tracer than 201Tl in the isolated rabbit heart. Compared to the other currently available positron-emitting flow tracers (82Rb, 13N-ammonia, and 15O-water), 18F-FDHR has the potential of providing excellent image resolution without the need for an on-site cyclotron.

  11. Hillslope Hydrological Processes in a Costa Rican Rainforest: Water Supply Partitioning Using Isotope Tracers

    E-Print Network [OSTI]

    DuMont, Andrea Lyn

    2014-04-24T23:59:59.000Z

    Blancas Hydroelectric Project, and for improved predictions in similar, ungauged watersheds (ICE 2002). Study Watershed The study watershed is located in San Juan de Peñas Blancas, east of the Cordillera de Tilarán mountain range backing up... peaks. These goals were accomplished by supplementing hydraulic and physical data already available at the site with use of isotope tracers. Methods Study Site The 2.2 ha watershed used in this research is located in Peñas Blancas, Costa Rica...

  12. Preferred methods of analysis for chemical tracers in moderate...

    Open Energy Info (EERE)

    of contamination or error are discussed in detail. Authors Kroneman, R. L.; Yorgason, K. R.; Moore and J. N. Published DOE Information Bridge, 1211984 DOI 10.21725121460...

  13. Tracer Methods for Characterizing Fracture Creation in Enhanced...

    Broader source: Energy.gov (indexed) [DOE]

    Geothermal Systems (EGS); 2010 Geothermal Technology Program Peer Review Report Fracture Characterization in Enhanced Geothermal Systems by Wellbore and Reservoir Analysis; 2010...

  14. Tracer Methods for Characterizing Fracture Stimulation in Enhanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Systems; 2010 Geothermal Technology Program Peer Review Report Fracture Characterization in Enhanced Geothermal Systems by Wellbore and Reservoir Analysis; 2010...

  15. Tracer Methods for Characterizing Fracture Stimulation in Enhanced...

    Broader source: Energy.gov (indexed) [DOE]

    good progress. Strongly recommend looking at heterogeneous earth, not just homogeneous medium. 4.6.7.3 Accomplishments, Expected Outcomes and Progress Ratings of Five-member...

  16. Verification of Geothermal Tracer Methods in Highly Constrained...

    Open Energy Info (EERE)

    The heat exchange between hot water injected into the fracture and the relatively cool rock is measured using a fiber optic distributed temperature sensor which will produce...

  17. Preferred methods of analysis for chemical tracers in moderate- and

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation,Pillar Group BV Jump to: navigation,Power Rental MarketEthanolhigh-temperature

  18. Validation of Geothermal Tracer Methods in Highly Constrained Field

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your DensityEnergy U.S.-China Electric Vehicle and03/02 TUE 08:59CapabilityVulnerabilities|VWD-0006

  19. Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic|Industrial Sector,DepartmentFebruary 19,TopProcess |Town o

  20. Tracer Methods for Characterizing Fracture Stimulation in Enhanced

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic|Industrial Sector,DepartmentFebruary 19,TopProcess |Town o5

  1. Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreakingMayDepartmentTest for PumpingThe|of Energy Top 9Systems |

  2. Verification of Geothermal Tracer Methods in Highly Constrained Field

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown of Ladoga,planning methodologiesVenkataraya Fibres PvtVerdi

  3. Apparatus and method for mixing fuel in a gas turbine nozzle

    DOE Patents [OSTI]

    Johnson, Thomas Edward; Ziminsky, Willy Steve; Berry, Jonathan Dwight

    2014-08-12T23:59:59.000Z

    A nozzle includes a fuel plenum and an air plenum downstream of the fuel plenum. A primary fuel channel includes an inlet in fluid communication with the fuel plenum and a primary air port in fluid communication with the air plenum. Secondary fuel channels radially outward of the primary fuel channel include a secondary fuel port in fluid communication with the fuel plenum. A shroud circumferentially surrounds the secondary fuel channels. A method for mixing fuel and air in a nozzle prior to combustion includes flowing fuel to a fuel plenum and flowing air to an air plenum downstream of the fuel plenum. The method further includes injecting fuel from the fuel plenum through a primary fuel passage, injecting fuel from the fuel plenum through secondary fuel passages, and injecting air from the air plenum through the primary fuel passage.

  4. Solubility trapping in formation water as dominant CO2 sink in natural gas fields

    E-Print Network [OSTI]

    Haszeldine, Stuart

    LETTERS Solubility trapping in formation water as dominant CO2 sink in natural gas fields Stuart M removal in nine natural gas fields in North America, China and Europe, using noble gas and carbon isotope tracers. The natural gas fields investigated in our study are dominated by a CO2 phase and provide

  5. Catalysts, systems and methods to reduce NOX in an exhaust gas stream

    DOE Patents [OSTI]

    Castellano, Christopher R. (Ringoes, NJ); Moini, Ahmad (Princeton, NJ); Koermer, Gerald S. (Basking Ridge, NJ); Furbeck, Howard (Hamilton, NJ)

    2010-07-20T23:59:59.000Z

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having an SCR catalyst comprising silver tungstate on an alumina support. The emissions treatment system may be used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines. An emissions treatment system may further comprise an injection device operative to dispense a hydrocarbon reducing agent upstream of the catalyst.

  6. Device and method for the measurement of gas permeability through membranes

    DOE Patents [OSTI]

    Agarwal, Pradeep K.; Ackerman, John; Borgialli, Ron; Hamann, Jerry; Muknahalliptna, Suresh

    2006-08-08T23:59:59.000Z

    A device for the measuring membrane permeability in electrical/electrochemical/photo-electrochemical fields is provided. The device is a permeation cell and a tube mounted within the cell. An electrode is mounted at one end of the tube. A membrane is mounted within the cell wherein a corona is discharged from the electrode in a general direction toward the membrane thereby generating heated hydrogen atoms adjacent the membrane. A method for measuring the effects of temperature and pressure on membrane permeability and selectivity is also provided.

  7. Nonthermal plasma systems and methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C.; Nelson, Lee O.; Detering, Brent A.

    2005-05-24T23:59:59.000Z

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  8. Process Design, Simulation and Integration of Dimethyl Ether (DME) Production from Shale Gas by Direct and Indirect Methods 

    E-Print Network [OSTI]

    Karagoz, Secgin

    2014-08-11T23:59:59.000Z

    may be obtained from shale gas is dimethyl ether (DME). Dimethyl ether can be used in many areas such as power generation, transportation fuel, and domestic heating and cooking. Dimethyl ether is currently produced from natural gas, coal and biomass...

  9. A Simple Method to Continuous Measurement of Energy Consumption of Tank Less Gas Water Heaters for Commercial Buildings

    E-Print Network [OSTI]

    Yamaha, M.; Fujita, M.; Miyoshi, T.

    2006-01-01T23:59:59.000Z

    energy consumptions of hot water supply in restaurants or residential houses are large amount, guidelines for optimal design are not presented. measurements of energy consumption of tank less gas water heaters very difficult unless gas flow meters...

  10. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    Simulation of Natural Gas HCCI Combustion: Gas Compositionfor heating the flowing gas. Combustion timing is consideredup. Exhaust gas samples were collected at varying combustion

  11. Method for improving dissolution efficiency in gas-absorption and liquid extraction processes. [Patent application

    DOE Patents [OSTI]

    Kanak, B.E.; Stephenson, M.J.

    1980-01-11T23:59:59.000Z

    A method is described for improving dissolution efficiency in processes in which a feed fluid is introduced to a zone where it is contacted with a liquid solvent for preferentially removing a component of the feed and where part of the solvent so contacted undergoes transfer into the feed fluid to saturate the same. It has been found that such transfer significantly impairs dissolution efficiency. In accordance with the invention, an amount of the above-mentioned solvent is added to the feed fluid being introduced to the contact zone, the solvent being added in an amount sufficient to effect reduction or elimination of the above-mentioned transfer. Preferably, the solvent is added to the feed fluid in an amount saturating or supersaturating the feed fluid under the conditions prevailing in the contact zone.

  12. HIGH-RESOLUTION FINITE VOLUME METHODS FOR DUSTY GAS JETS AND MARICA PELANTI AND RANDALL J. LEVEQUE

    E-Print Network [OSTI]

    LeVeque, Randy

    (since the sound speed is zero in the absence of pressure) and have a degenerate structure in which delta is lower than the sound speed of the pure gas phase, and can be substantially lower at high dust densities" (though in some contexts it could represent liquid droplets) and the mixture as a "dusty gas". Dusty gas

  13. A new method for infrared imaging of air currents in and around critical hazard fume hoods

    SciTech Connect (OSTI)

    Mulac, W.A.; McCreary, J.R. (Argonne National Lab., IL (United States)); Schmalz, H. (Argonne National Lab., IL (United States) Thermal Surveys, Inc., Rockford, IL (United States))

    1992-01-01T23:59:59.000Z

    A real time method of measuring and recording the efficacy of vapor containment in and around critical hazard fume hoods is being developed. An infrared camera whose response is restricted to a spectral range that overlaps a strong absorption band in a non-toxic gas is used to render real-time video images of the presence and flow of the gas. The gas, nitrous oxide, is ejected in a continuous stream in and around fume hoods that are to be certified capable of containing hazardous fumes. The principle advantage is that various scenarios of air flow displacement in and outside the hood can be easily investigated; the principle limitation is the necessity of high tracer gas concentration to obtain strong visualizations. We hope that this technique can be found to be an effective and safe method to test hoods in locations that were built before present regulations were promulgated.

  14. A new method for infrared imaging of air currents in and around critical hazard fume hoods

    SciTech Connect (OSTI)

    Mulac, W.A.; McCreary, J.R. [Argonne National Lab., IL (United States); Schmalz, H. [Argonne National Lab., IL (United States)]|[Thermal Surveys, Inc., Rockford, IL (United States)

    1992-11-01T23:59:59.000Z

    A real time method of measuring and recording the efficacy of vapor containment in and around critical hazard fume hoods is being developed. An infrared camera whose response is restricted to a spectral range that overlaps a strong absorption band in a non-toxic gas is used to render real-time video images of the presence and flow of the gas. The gas, nitrous oxide, is ejected in a continuous stream in and around fume hoods that are to be certified capable of containing hazardous fumes. The principle advantage is that various scenarios of air flow displacement in and outside the hood can be easily investigated; the principle limitation is the necessity of high tracer gas concentration to obtain strong visualizations. We hope that this technique can be found to be an effective and safe method to test hoods in locations that were built before present regulations were promulgated.

  15. National Biomedical Tracer Facility: Project definition study

    SciTech Connect (OSTI)

    Heaton, R.; Peterson, E. [Los Alamos National Lab., NM (United States); Smith, P. [Smith (P.A.) Concepts and Designs (United States)

    1995-05-31T23:59:59.000Z

    The Los Alamos National Laboratory is an ideal institution and New Mexico is an ideal location for siting the National Biomedical Tracer Facility (NBTF). The essence of the Los Alamos proposal is the development of two complementary irradiation facilities that combined with our existing radiochemical processing hot cell facilities and waste handling and disposal facilities provide a low cost alternative to other proposals that seek to satisfy the objectives of the NBTF. We propose the construction of a 30 MeV cyclotron facility at the site of the radiochemical facilities, and the construction of a 100 MeV target station at LAMPF to satisfy the requirements and objectives of the NBTF. We do not require any modifications to our existing radiochemical processing hot cell facilities or our waste treatment and disposal facilities to accomplish the objectives of the NBTF. The total capital cost for the facility defined by the project definition study is $15.2 M. This cost estimate includes $9.9 M for the cyclotron and associated facility, $2.0 M for the 100 MeV target station at LAMPF, and $3.3 M for design.

  16. Quantum Dot Tracers for Use in Engineered Geothermal Systems

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objective: To develop and demonstrate a new class of tracers?semiconductor nanoparticles(quantum dots)?that offer great promise for use in characterizing fracture networks in EGS reservoirs.

  17. Tracking thermal fronts with temperature-sensitive, chemically reactive tracers

    SciTech Connect (OSTI)

    Robinson, B.A.; Birdsell, S.A.

    1987-01-01T23:59:59.000Z

    Los Alamos is developing tracer techniques using reactive chemicals to track thermal fronts in fractured geothermal reservoirs. If a nonadsorbing tracer flowing from the injection to production well chemically reacts, its reaction rate will be a strong function of temperature. Thus the extent of chemical reaction will be greatest early in the lifetime of the system, and less as the thermal front progresses from the injection to production well. Early laboratory experiments identified tracers with chemical kinetics suitable for reservoirs in the temperature range of 75 to 100/sup 0/C. Recent kinetics studies have focused on the kinetics of hydrolysis of derivatives of bromobenzene. This class of reactions can be used in reservoirs ranging in temperature from 150 to 275/sup 0/C, which is of greater interest to the geothermal industry. Future studies will include laboratory adsorption experiments to identify possibly unwanted adsorption on granite, development of sensitive analytical techniques, and a field demonstration of the reactive tracer concept.

  18. Microfluidic Investigation of Tracer Dye Diffusion in Alumina Nanofluids 

    E-Print Network [OSTI]

    Ozturk, Serdar 1979-

    2012-10-05T23:59:59.000Z

    on enhanced mass diffusion and the possibility of tailoring mass transport by direct manipulation of molecular diffusion. Therefore, a microfluidic approach capable of directly probing tracer diffusion between nanoparticle-laden fluid streams was developed...

  19. Inverse modeling of partitioning interwell tracer tests: A streamline approach

    E-Print Network [OSTI]

    Datta-Gupta, Akhil

    computations, inverse modeling 1. Introduction [2] It is recognized that the presence of nonaqueous phaseInverse modeling of partitioning interwell tracer tests: A streamline approach Akhil Datta orders of magnitude. INDEX TERMS: 1832 Hydrology: Groundwater transport; 1829 Hydrology: Groundwater

  20. A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcat 1 WindtheEnergySulfonate as a Liquid-Phase Tracer at the Coso

  1. A Study Plan for Determining Recharge Rates at the Hanford Site Using Environmental Tracers

    SciTech Connect (OSTI)

    Murphy,, E. M.; Szecsody,, J. E.; Phillips,, S. J.

    1991-02-01T23:59:59.000Z

    This report presents a study plan tor estimating recharge at the Hanford Site using environmental tracers. Past operations at the Hanford Site have led to both soil and groundwater contamination, and recharge is one of the primary mechanisms for transporting contaminants through the vadose zone and into the groundwater. The prediction of contaminant movement or transport is one aspect of performance assessment and an important step in the remedial investigation/feasibility study (RI/FS) process. In the past, recharge has been characterized by collecting lysimeter data. Although lysimeters can generate important and reliable data, their limitations include 1) fixed location, 2) fixed sediment contents, 3) edge effects, 4) low rates, and 5) relatively short duration of measurement. These limitations impact the ability to characterize the spatial distribution of recharge at the Hanford Site, and thus the ability to predict contaminant movement in the vadose zone. An alternative to using fixed lysimeters for determining recharge rates in the vadose zone is to use environmental tracers. Tracers that have been used to study water movement in the vadose zone include total chloride, {sup 36}CI, {sup 3}H, and {sup 2}H/{sup 18}O. Atmospheric levels of {sup 36}CI and {sup 3}H increased during nuclear bomb testing in the Pacific, and the resulting "bomb pulse" or peak concentration can be measured in the soil profile. Locally, past operations at the Hanford Site have resu~ed in the atmospheric release of numerous chemical and isotopic tracers, including nitrate, {sup 129}I, and {sup 99}Tc. The radionuclides, in particular, reached a well-defined atmospheric peak in 1945. Atmospheric releases of {sup 129}I and {sup 99}Tc were greatly reduced by mid-1946, but nitrogen oxides continued to be released from the uranium separations facilities. As a result, the nitrate concentrations probably peaked in the mid-1950s, when the greatest number of separations facilities were operating. Seven study sites on the Hanford Site have been selected, in two primary soil types that are believed to represent the extremes in recharge, the Quincy sand and the Warden silt loam. An additional background study site upwind of the Hanford facilities has been chosen at the Yakima Firing Center. Study sites at Hanford were chosen close to micrometeorology stations on downwind transects from the operational facilities. Initial testing will be done on sites that lack perennial vegetation. Six tracer techniques (total chlortde, {sup 36}Cl, {sup 3}H, nitrate, {sup 129}I, and {sup 99}Tc) will be tested on at least one site in the Quincy sand, one site in the Warden si~ loam, and the background site, to determine which combination of tracers wortks best for a given soil type. In subsequent years, additional sites will be investigated to determine the effect of vegetation on recharge estimates and on the performance of individual tracers. The use of environmental tracers is perhaps the only cost-effective method for estimating the spatial vartability of recharge at a site as large as Hanford. The tracer techniques used at Hanford have wide applicability at other and sites operated by the U.S. Department of Energy as well as at low-level radioactive waste disposal sites.

  2. The feasibility of ethyl iodide as an atmospheric tracer

    E-Print Network [OSTI]

    Everett, Joe Vincent

    1976-01-01T23:59:59.000Z

    of Advisory Committee: Dr. R. D. Neff Interest in atmospheric diffusion has been heightened within the last decade by the increasing concern of air pollution and the possibility of radiation hazards intro- duced into the air from nuclear facilities.... Gaseous tracers provide an excellent means of measuring concentration levels at various points downwind of a facility. However, for long range stud cs, ve y low detectable levels are needed. Many problems encountered with tracers for use in long range...

  3. USING PERFLUOROCARBON TRACERS FOR VERIFICATION OF CAP AND COVER SYSTEMS PERFORMANCE.

    SciTech Connect (OSTI)

    HEISER,J.; SULLIVAN,T.

    2001-11-01T23:59:59.000Z

    The Department of Energy (DOE) Environmental Management (EM) office has committed itself to an accelerated cleanup of its national facilities. The goal is to have much of the DOE legacy waste sites remediated by 2006. This includes closure of several sites (e.g., Rocky Flats and Fernald). With the increased focus on accelerated cleanup, there has been considerable concern about long-term stewardship issues in general, and verification and long-term monitoring (LTM) of caps and covers, in particular. Cap and cover systems (covers) are vital remedial options that will be extensively used in meeting these 2006 cleanup goals. Every buried waste site within the DOE complex will require some form of cover system. These covers are expected to last from 100 to 1000 years or more. The stakeholders can be expected to focus on system durability and sustained performance. DOE EM has set up a national committee of experts to develop a long-term capping (LTC) guidance document. Covers are subject to subsidence, erosion, desiccation, animal intrusion, plant root infiltration, etc., all of which will affect the overall performance of the cover. Very little is available in terms of long-term monitoring other than downstream groundwater or surface water monitoring. By its very nature, this can only indicate that failure of the cover system has already occurred and contaminants have been transported away from the site. This is unacceptable. Methods that indicate early cover failure (prior to contaminant release) or predict approaching cover failure are needed. The LTC committee has identified predictive monitoring technologies as a high priority need for DOE, both for new covers as well as existing covers. The same committee identified a Brookhaven National Laboratory (BNL) technology as one approach that may be capable of meeting the requirements for LTM. The Environmental Research and Technology Division (ERTD) at BNL developed a novel methodology for verifying and monitoring subsurface barriers (1,2). The technology uses perfluorocarbon tracers (PFTs) to determine flaws (e.g., holes or cracks) and high permeability areas in subsurface barriers. Gaseous tracers are injected on one side of the barrier and searched for on the opposite side of the barrier. The sampling grid, concentration, and time of arrival of the tracer(s) on the opposite side are used to determine the size and location of flaws and relative permeability of the barrier. In addition, there are multiple tracers available, which allows different tracers to be injected in different quadrants of the barrier. This yields additional information on transport phenomena of the barrier.

  4. Resuspension rates from aged inert-tracer sources

    SciTech Connect (OSTI)

    Sehmel, G.A.

    1982-11-01T23:59:59.000Z

    Wind-caused particle resuspension rates were investigated with molybdenum tracers at two circular resuspension sites in the Hanford area. The tracer particles were calcium molybdate. The radii of each circular tracer-source area were 22.9 m and 29.9 m respectively for tracer deposited on 2 October 1973 and 29 May 1979. Resuspension rates were investigated by sampling resuspended tracer with air sampling equipment mounted as a function of height on a centrally located sampling tower at each site. Sampling equipment was operated as a function of wind speed increments in order to investigate resuspension rates, wind speed dependencies of resuspension rates, and for subsequent comparisons of resuspension rate changes as a function of time for constant wind speed ranges. Experimental results are reported for measurements over several years. Resuspension rates ranged from about 10/sup -13/ to 10/sup -6/ fraction of the tracer source resuspended per second. Resuspension rates tended to increase with increasing wind speed. At one investigation site, resuspension rates were nearly constant, except for seasonal variations, for a four-year time period. Resuspension rates appear higher in the autumn than in the spring and summer.

  5. HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS

    SciTech Connect (OSTI)

    Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

    2012-01-01T23:59:59.000Z

    The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

  6. Method and apparatus for the separation of a gas-solids mixture in a circulating fluidized bed reactor

    DOE Patents [OSTI]

    Vimalchand, Pannalal (Birmingham, AL); Liu, Guohai (Birmingham, AL); Peng, WanWang (Birmingham, AL)

    2010-08-10T23:59:59.000Z

    The system of the present invention includes a centripetal cyclone for separating particulate material from a particulate laden gas solids stream. The cyclone includes a housing defining a conduit extending between an upstream inlet and a downstream outlet. In operation, when a particulate laden gas-solids stream passes through the upstream housing inlet, the particulate laden gas-solids stream is directed through the conduit and at least a portion of the solids in the particulate laden gas-solids stream are subjected to a centripetal force within the conduit.

  7. Primer on gas integrated resource planning

    SciTech Connect (OSTI)

    Goldman, C.; Comnes, G.A.; Busch, J.; Wiel, S. [Lawrence Berkeley Lab., CA (United States)

    1993-12-01T23:59:59.000Z

    This report discusses the following topics: gas resource planning: need for IRP; gas integrated resource planning: methods and models; supply and capacity planning for gas utilities; methods for estimating gas avoided costs; economic analysis of gas utility DSM programs: benefit-cost tests; gas DSM technologies and programs; end-use fuel substitution; and financial aspects of gas demand-side management programs.

  8. Single-particle spectral density of the unitary Fermi gas: Novel approach based on the operator product expansion, sum rules and the maximum entropy method

    E-Print Network [OSTI]

    Philipp Gubler; Naoki Yamamoto; Tetsuo Hatsuda; Yusuke Nishida

    2015-01-24T23:59:59.000Z

    Making use of the operator product expansion, we derive a general class of sum rules for the imaginary part of the single-particle self-energy of the unitary Fermi gas. The sum rules are analyzed numerically with the help of the maximum entropy method, which allows us to extract the single-particle spectral density as a function of both energy and momentum. These spectral densities contain basic information on the properties of the unitary Fermi gas, such as the dispersion relation and the superfluid pairing gap, for which we obtain reasonable agreement with the available results based on quantum Monte-Carlo simulations.

  9. Single-particle spectral density of the unitary Fermi gas: Novel approach based on the operator product expansion, sum rules and the maximum entropy method

    E-Print Network [OSTI]

    Gubler, Philipp; Hatsuda, Tetsuo; Nishida, Yusuke

    2015-01-01T23:59:59.000Z

    Making use of the operator product expansion, we derive a general class of sum rules for the imaginary part of the single-particle self-energy of the unitary Fermi gas. The sum rules are analyzed numerically with the help of the maximum entropy method, which allows us to extract the single-particle spectral density as a function of both energy and momentum. These spectral densities contain basic information on the properties of the unitary Fermi gas, such as the dispersion relation and the superfluid pairing gap, for which we obtain reasonable agreement with the available results based on quantum Monte-Carlo simulations.

  10. Spectral analysis for evaluation of myocardial tracers for medical imaging

    SciTech Connect (OSTI)

    Huesman, Ronald H.; Reutter, Bryan W.; Marshall, Robert C.

    2000-10-11T23:59:59.000Z

    Kinetic analysis of dynamic tracer data is performed with the goal of evaluating myocardial radiotracers for cardiac nuclear medicine imaging. Data from experiments utilizing the isolated rabbit heart model are acquired by sampling the venous blood after introduction of a tracer of interest and a reference tracer. We have taken the approach that the kinetics are properly characterized by an impulse response function which describes the difference between the reference molecule (which does not leave the vasculature) and the molecule of interest which is transported across the capillary boundary and is made available to the cell. Using this formalism we can model the appearance of the tracer of interest in the venous output of the heart as a convolution of the appearance of the reference tracer with the impulse response. In this work we parameterize the impulse response function as the sum of a large number of exponential functions whose predetermined decay constants form a spectrum, and each is required only to have a nonnegative coefficient. This approach, called spectral analysis, has the advantage that it allows conventional compartmental analysis without prior knowledge of the number of compartments which the physiology may require or which the data will support.

  11. Gas mixing in the wall layer of a CFB boiler

    SciTech Connect (OSTI)

    Sterneus, J.; Johnsson, F. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Energy Conversion

    1997-12-31T23:59:59.000Z

    Tracer-gas measurements were carried out in the transport zone of a 12 MW CFB boiler with special emphasis on the wall-layer flow. Helium (He) was used as tracer gas and a mass spectrometer was used to determine the He-concentrations. The primary gas velocity, U{sub 0}, was 1.2, 2.6 and 4.3 m/s (no secondary air) and the bed material was silica sand with an average particle diameter of 0.32 mm. Tracer gas was injected at different distances from one of the furnace walls and sampled above and below the injection level. In the wall layer, tracer-gas concentrations were detected above (C{sub above}) as well as below (C{sub below}) the injection height for all operating conditions, i.e., the gas flows both up and down from the injection point. The data show that the net flow of tracer gas in the wall layer depends on the operating conditions, and the concentration ratio of the down- and up-flowing gas, {psi} = C{sub below}/C{sub above}, decreases with increased gas velocity ({psi} > 1 for U{sub 0} = 1.2 m/s, {psi} {approx} 1 for U{sub 0} = 2.6 m/s and {psi} < 1 for U{sub 0} = 4.3 m/s). There exists a gas exchange between the core region and the wall-layer. A plug flow model applied to the core region gives a radial dispersion coefficient, D{sub r}, in the range of 0.015--0.025 m{sup 2}/s which is higher than the D{sub r} values reported in literature which are below 0.01 m{sup 2}/x. However, the latter values were obtained in tall and narrow risers.

  12. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

    1989-01-01T23:59:59.000Z

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  13. A study of diesel combustion process under the condition of EGR and high-pressure fuel injection with gas sampling method

    SciTech Connect (OSTI)

    Shimazaki, Naoki; Hatanaka, Hirokazu; Yokota, Katsuhiko; Nakahira, Toshio

    1996-09-01T23:59:59.000Z

    It is well known that a high-pressure fuel injection is effective for the reduction in particulates and smoke emissions. Exhaust gas recirculation (EGR) is effective for the reduction in NO{sub x} emission. In this study an experiment aiming to understand more comprehensive combustion under the condition of EGR and high-pressure fuel injection was carried out by using gas sampling method for the purpose of understanding what occurred inside the spray before and after combustion. The number of combustion cycles in this engine can be controlled in order to change EGR conditions by adjusting the residual gas concentration in the cylinder. Main results were: (1) close to the nozzle tip, the sampling gas data showed little reaction which implies that combustion never occurs in this area during the injection period; (2) in the case of high-pressure fuel injection O{sub 2} concentration decreased faster and air dilution was more active and earlier, this may cause the decrease of smoke emissions due to accelerated soot oxidation; (3) in the case of EGR, combustion was poor since oxygen concentration was insufficient, thus, inactivity of oxidation reaction caused reduction in NO{sub x} emission; (4) in the case of increasing the amounts of N{sub 2} gas while keeping the O{sub 2} content constant (same amount as without EGR), NO{sub x} emission decreased without deterioration of smoke emission and Pmi.

  14. Development and verification of new semi-analytical methods for the analysis and prediction of gas well performance

    E-Print Network [OSTI]

    Knowles, Robert Stephen

    1999-01-01T23:59:59.000Z

    . We have developed two new relations (p² and (p/z)² results) that predict gas well rate-time performance within engineering accuracy of the rigorous solution. Unlike the pseudopressure-pseudotime relation, our new solutions require only knowledge...

  15. Effects from influent boundary conditions on tracer migration and spatial variability features in intermediate-scale experiments

    SciTech Connect (OSTI)

    Fuentes, H.R.; Polzer, W.L.; Springer, E.P.

    1987-04-01T23:59:59.000Z

    In previous unsaturated transport studies at Los Alamos dispersion coefficients were estimated to be higher close to the tracer source than at greater distances from the source. Injection of tracers through discrete influent outlets could have accounted for those higher dispersions. Also, a lack of conservation of mass of the tracers was observed and suspected to be due to spatial variability in transport. In the present study experiments were performed under uniform influent (ponded) conditions in which breakthrough of tracers was monitored at four locations at each of four depths. All other conditions were similar to those of the unsaturated transport experiments. A comparison of results from these two sets of experiments indicates differences in the parameter estimates. Estimates were made for the dispersion coefficient and the retardation factor by the one-dimensional steady flow computer code, CFITIM. Estimates were also made for mass and for velocity and the dispersion coefficient by the method of moments. The dispersion coefficient decreased with depth under discrete influent application and increased with depth under ponded influent application. Retardation was predicted better under the discrete influent application than under ponded influent application. Differences in breakthroughs and in estimated parameters among locations at the same depth were observed under ponded influent application. Those differences indicate that there is a lack of conservation of mass as well as significant spatial variability across the experimental domain. 14 refs., 9 figs., 8 tabs.

  16. Optical sensing elements for nitrogen dioxide (NO.sub.2) gas detection, a sol-gel method for making the sensing elements and fiber optic sensors incorporating nitrogen dioxide gas optical sensing elements

    DOE Patents [OSTI]

    Mechery, Shelly John (Mississippi State, MS); Singh, Jagdish P. (Starkville, MS)

    2007-07-03T23:59:59.000Z

    A sensing element, a method of making a sensing element, and a fiber optic sensor incorporating the sensing element are described. The sensor can be used for the quantitative detection of NO.sub.2 in a mixture of gases. The sensing element can be made by incorporating a diazotizing reagent which reacts with nitrous ions to produce a diazo compound and a coupling reagent which couples with the diazo compound to produce an azo dye into a sol and allowing the sol to form an optically transparent gel. The sensing element changes color in the presence of NO.sub.2 gas. The temporal response of the absorption spectrum at various NO.sub.2 concentrations has also been recorded and analyzed. Sensors having different design configurations are described. The sensing element can detect NO.sub.2 gas at levels of parts per billion.

  17. 36Cl as a tracer in geothermal systems- Example from Valles Caldera...

    Open Energy Info (EERE)

    Cl as a tracer in geothermal systems- Example from Valles Caldera, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: 36Cl as a tracer...

  18. Time-scales of passive tracers in the ocean with paleoapplications

    E-Print Network [OSTI]

    Siberlin, Charlotte

    2010-01-01T23:59:59.000Z

    Quantifying time-responses of the ocean to passive and active tracers is critical when interpreting paleodata from sediment cores. Surface-injected tracers are not spreading instantaneously or uniformly throughout the ...

  19. Measurement of the Tracer Gradient and Sampling System Bias of the Hot Fuel Examination Facility Stack Air Monitoring System

    SciTech Connect (OSTI)

    Glissmeyer, John A.; Flaherty, Julia E.

    2011-07-20T23:59:59.000Z

    This report describes tracer gas uniformity and bias measurements made in the exhaust air discharge of the Hot Fuel Examination Facility at Idaho National Laboratory. The measurements were a follow-up on earlier measurements which indicated a lack of mixing of the two ventilation streams being discharged via a common stack. The lack of mixing is detrimental to the accuracy of air emission measurements. The lack of mixing was confirmed in these new measurements. The air sampling probe was found to be out of alignment and that was corrected. The suspected sampling bias in the air sample stream was disproved.

  20. Calibration of hydraulic and tracer tests in fractured media

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    Calibration of hydraulic and tracer tests in fractured media represented by a DFN Model L. D. Donado, X. Sanchez-Vila, E. Ruiz* & F. J. Elorza** * Enviros Spain S.L. ** UPM #12;Fractured Media Water flows through fractures (matrix basically impervious ­ though relevant to transport) Fractures at all

  1. Analysis of Tracer Dispersion During a Prescribed Forest Burn

    E-Print Network [OSTI]

    Collins, Gary S.

    . Additionally, a sulfur hexafluoride (SF6) tracer dispersion test was conducted by releasing SF6 from a line source within the burn and measuring SF6 concentrations at the supertower. Supertower Instrumentation (TGAPS) connected to a CO2 closed path Licor LI-6262 and a SF6 detector (7 inlet locations) ·Cambell CSAT

  2. Diagnostic Implications of the Reactivity of Fluorescence Tracers

    SciTech Connect (OSTI)

    Sick, V; Westbrook, C

    2008-07-14T23:59:59.000Z

    Measurements of fuel concentration distributions with planar laser induced fluorescence of tracer molecules that are added to a base fuel are commonly used in combustion research and development. It usually is assumed that the tracer concentration follows the parent fuel concentration if physical properties such as those determining evaporation are matched. As an example to address this general issue a computational study of combustion of biacetyl/iso-octane mixtures was performed to investigate how well the concentration of biacetyl represents the concentration of iso-octane. For premixed mixture conditions with flame propagation the spatial concentration profiles of the two species in the flame front are separated by 110 {micro}m at 1 bar and by 11 {micro}m at 10 bar. For practical applications this spatial separation is insignificantly small. However, for conditions that mimic ignition and combustion in diesel and HCCI-like operation the differences in tracer and fuel concentration can be significant, exceeding hundreds of percent. At low initial temperature biacetyl was found to be more stable whereas at higher temperature (>1000K) iso-octane is more stable. Similar findings were obtained for a multi-component fuel comprised of iso-octane, n-heptane, methylcyclohexane, and toluene. It may be assumed that similar differences can exist for other tracer/fuel combinations. Caution has therefore to be applied when interpreting PLIF measurements in homogeneous reaction conditions such as in HCCI engine studies.

  3. Diss. ETH Nr. 10714 Helium und Tritium als Tracer fr

    E-Print Network [OSTI]

    Aeschbach-Hertig, Werner

    Diss. ETH Nr. 10714 Helium und Tritium als Tracer für physikalische Prozesse in Seen ABHANDLUNG zur Zürich 1994 #12;Kurzfassung ix Kurzfassung Der radioaktive Zerfall von 3H (Tritium) zu 3He mit einer Fluide aus dem Erdinnern. Helium und Tritium werden massenspektrometrisch analysiert. Im Rahmen dieser Ar

  4. THE EFFECT OF TRANSVERSE MIXING ON TRACER DISPERSION

    E-Print Network [OSTI]

    Stanford University

    Hardware Data Acquisition And Analysis Software Experimental Procedure Analysis Procedure Results: Taylor. The theoretical response for linear Taylor dispersion was matched to the data to determine the non-linear Of Tracer Valve Constant-pressure Reservoir Design Schematic Drawing Of Electrode Circuit Results: Run 16

  5. Application of a NAPL partitioning interwell tracer test (PITT) to support DNAPL remediation at the Sandia National Laboratories/New Mexico chemical waste landfill

    SciTech Connect (OSTI)

    Studer, J.E. [INTERA Inc., Albuquerque, NM (United States); Mariner, P.; Jin, M. [INTERA Inc., Austin, TX (United States)] [and others

    1996-05-01T23:59:59.000Z

    Chlorinated solvents as dense non-aqueous phase liquid (DNAPL) are present at a large number of hazardous waste sites across the U.S. and world. DNAPL is difficult to detect in the subsurface, much less characterize to any degree of accuracy. Without proper site characterization, remedial decisions are often difficult to make and technically effective, cost-efficient remediations are even more difficult to obtain. A new non-aqueous phase liquid (NAPL) characterization technology that is superior to conventional technologies has been developed and applied at full-scale. This technology, referred to as the Partitioning Interwell Tracer Test (PITT), has been adopted from oil-field practices and tailored to environmental application in the vadose and saturated zones. A PITT has been applied for the first time at full-scale to characterize DNAPL in the vadose zone. The PITT was applied in December 1995 beneath two side-by-side organic disposal pits at Sandia National Laboratories/New Mexico (SNL/NM) RCRA Interim Status Chemical Waste Landfill (CWL), located in Albuquerque, New Mexico. DNAPL, consisting of a mixture of chlorinated solvents, aromatic hydrocarbons, and PCE oils, is known to exist in at least one of the two buried pits. The vadose zone PITT was conducted by injecting a slug of non-partitioning and NAPL-partitioning tracers into and through a zone of interest under a controlled forced gradient. The forced gradient was created by a balanced extraction of soil gas at a location 55 feet from the injector. The extracted gas stream was sampled over time to define tracer break-through curves. Soil gas sampling ports from multilevel monitoring installations were sampled to define break-through curves at specific locations and depths. Analytical instrumentation such as gas chromatographs and a photoacoustical analyzers operated autonomously, were used for tracer detection.

  6. Angel wing seals for blades of a gas turbine and methods for determining angel wing seal profiles

    DOE Patents [OSTI]

    Wang, John Zhiqiang (Greenville, SC)

    2003-01-01T23:59:59.000Z

    A gas turbine has buckets rotatable about an axis, the buckets having angel wing seals. The seals have outer and inner surfaces, at least one of which, and preferably both, extend non-linearly between root radii and the tip of the seal body. The profiles are determined in a manner to minimize the weight of the seal bodies, while maintaining the stresses below predetermined maximum or allowable stresses.

  7. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    Simulation of Natural Gas HCCI Combustion: Gas CompositionPeroxide (DTBP) Additive on HCCI Combustion of Fuel BlendsCharge Compression Ignition (HCCI) Engines: Key Research and

  8. Home Safety: Radon Gas 

    E-Print Network [OSTI]

    Shaw, Bryan W.; Denny, Monica L.

    1999-11-12T23:59:59.000Z

    Every home should be tested for radon, an invisible, odorless, radioactive gas that occurs naturally. This publication explains the health risks, testing methods, and mitigation and reduction techniques....

  9. Home Safety: Radon Gas

    E-Print Network [OSTI]

    Shaw, Bryan W.; Denny, Monica L.

    1999-11-12T23:59:59.000Z

    Every home should be tested for radon, an invisible, odorless, radioactive gas that occurs naturally. This publication explains the health risks, testing methods, and mitigation and reduction techniques....

  10. Monitoring of saline tracer movement with vertically distributed self-potential measurements at the HOBE agricultural test site, Voulund, Denmark

    E-Print Network [OSTI]

    Jougnot, Damien; Haarder, Eline B; Looms, Majken C

    2015-01-01T23:59:59.000Z

    The self-potential (SP) method is sensitive to water fluxes in saturated and partially saturated porous media, such as those associated with rainwater infiltration and groundwater recharge. We present a field-based study at the Voulund agricultural test site, Denmark, that is, to the best of our knowledge, the first to focus on the vertical self-potential distribution prior to and during a saline tracer test. A coupled hydrogeophysical modeling framework is used to simulate the SP response to precipitation and saline tracer infiltration. A layered hydrological model is first obtained by inverting dielectric and matric potential data. The resulting model that compares favorably with electrical resistance tomography models is subsequently used to predict the SP response. The electrokinetic contribution (caused by water fluxes in a charged porous soil) is modeled by an effective excess charge approach that considers both water saturation and pore water salinity. Our results suggest that the effective excess char...

  11. Core follow calculation with the nTRACER numerical reactor and verification using power reactor measurement data

    SciTech Connect (OSTI)

    Jung, Y. S.; Joo, H. G. [Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul (Korea, Republic of); Yoon, J. I. [KEPCO Nuclear Fuel, 1047 Daedukdae-ro, Yuseong-gu, Daejeon (Korea, Republic of)

    2013-07-01T23:59:59.000Z

    The nTRACER direct whole core transport code employing the planar MOC solution based 3-D calculation method, the subgroup method for resonance treatment, the Krylov matrix exponential method for depletion, and a subchannel thermal/hydraulic calculation solver was developed for practical high-fidelity simulation of power reactors. Its accuracy and performance is verified by comparing with the measurement data obtained for three pressurized water reactor cores. It is demonstrated that accurate and detailed multi-physic simulation of power reactors is practically realizable without any prior calculations or adjustments. (authors)

  12. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. ???, XXXX, DOI:10.1029/, What is the skill of ocean tracers in reducing uncertainties

    E-Print Network [OSTI]

    Haran, Murali

    in current Earth system models and (ii) imperfect knowledge of model parameters. Ocean tracers observa- tions

  13. Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, T.

    1988-04-05T23:59:59.000Z

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

  14. Application of the isochronal, transient p/z plotting method for determination of original gas in place, to low permeability reservoirs

    E-Print Network [OSTI]

    Protos, Nicholas Emmanuel

    1991-01-01T23:59:59.000Z

    APPLICATION OF THE ISOCHRONAL, TRANZIENT PfL PLOTllNG METHOD FOR DETERMINATION OF ORIGINAL GAS IN PLACE, TO LOW PERh4EABILITY RESERVOIRS A Thesis by NICHOLAS EMMANUEL PROTOS Submitted to the Office of Gradaute Studies of Texas A&M University... RESERVOIRS A Thesis by NICHOLAS E~UEL PROTOS Approved as to style and content by: Steven W. Poston (Chair of Committee) arry D. ip (membe Robert R. Berg (member) William . Von Gonten (Head of Depanment) August 1991 ABSTRACT Application...

  15. A Finite-Difference Numerical Method for Onsager's Pancake Approximation for Fluid Flow in a Gas Centrifuge

    SciTech Connect (OSTI)

    de Stadler, M; Chand, K

    2007-11-12T23:59:59.000Z

    Gas centrifuges exhibit very complex flows. Within the centrifuge there is a rarefied region, a transition region, and a region with an extreme density gradient. The flow moves at hypersonic speeds and shock waves are present. However, the flow is subsonic in the axisymmetric plane. The analysis may be simplified by treating the flow as a perturbation of wheel flow. Wheel flow implies that the fluid is moving as a solid body. With the very large pressure gradient, the majority of the fluid is located very close to the rotor wall and moves at an azimuthal velocity proportional to its distance from the rotor wall; there is no slipping in the azimuthal plane. The fluid can be modeled as incompressible and subsonic in the axisymmetric plane. By treating the centrifuge as long, end effects can be appropriately modeled without performing a detailed boundary layer analysis. Onsager's pancake approximation is used to construct a simulation to model fluid flow in a gas centrifuge. The governing 6th order partial differential equation is broken down into an equivalent coupled system of three equations and then solved numerically. In addition to a discussion on the baseline solution, known problems and future work possibilities are presented.

  16. Acidic gas capture by diamines

    DOE Patents [OSTI]

    Rochelle, Gary (Austin, TX); Hilliard, Marcus (Missouri City, TX)

    2011-05-10T23:59:59.000Z

    Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

  17. Development of Models to Simulate Tracer Tests for Characterization of Enhanced Geothermal Systems

    SciTech Connect (OSTI)

    Williams, Mark D.; Reimus, Paul; Vermeul, Vincent R.; Rose, Peter; Dean, Cynthia A.; Watson, Tom B.; Newell, D.; Leecaster, Kevin; Brauser, Eric

    2013-05-01T23:59:59.000Z

    A recent report found that power and heat produced from enhanced (or engineered) geothermal systems (EGSs) could have a major impact on the U.S energy production capability while having a minimal impact on the environment. EGS resources differ from high-grade hydrothermal resources in that they lack sufficient temperature distribution, permeability/porosity, fluid saturation, or recharge of reservoir fluids. Therefore, quantitative characterization of temperature distributions and the surface area available for heat transfer in EGS is necessary for the design and commercial development of the geothermal energy of a potential EGS site. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate this characterization. This project was initially focused on tracer development with the application of perfluorinated tracer (PFT) compounds, non-reactive tracers used in numerous applications from atmospheric transport to underground leak detection, to geothermal systems, and evaluation of encapsulated PFTs that would release tracers at targeted reservoir temperatures. After the 2011 midyear review and subsequent discussions with the U.S. Department of Energy Geothermal Technology Program (GTP), emphasis was shifted to interpretive tool development, testing, and validation. Subsurface modeling capabilities are an important component of this project for both the design of suitable tracers and the interpretation of data from in situ tracer tests, be they single- or multi-well tests. The purpose of this report is to describe the results of the tracer and model development for simulating and conducting tracer tests for characterizing EGS parameters.

  18. RESEARCH ROADMAP FOR GREENHOUSE GAS INVENTORY

    E-Print Network [OSTI]

    RESEARCH ROADMAP FOR GREENHOUSE GAS INVENTORY METHODS Prepared For: California Energy Commission.........................................................................................................................1 Roadmap Organization

  19. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-01-01T23:59:59.000Z

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO?-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore »proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO?. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO? will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO? driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO? to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As part of the Big Sky Carbon Sequestration Project the INL-CAES has developed a rapid, easy to use proces

  20. Interpretation of Colloid-Homologue Tracer Test 10-03, Including Comparisons to Test 10-01

    SciTech Connect (OSTI)

    Reimus, Paul W. [Los Alamos National Laboratory

    2012-06-26T23:59:59.000Z

    This presentation covers the interpretations of colloid-homologue tracer test 10-03 conducted at the Grimsel Test Site, Switzerland, in 2010. It also provides a comparison of the interpreted test results with those of tracer test 10-01, which was conducted in the same fracture flow system and using the same tracers than test 10-03, but at a higher extraction flow rate. A method of correcting for apparent uranine degradation in test 10-03 is presented. Conclusions are: (1) Uranine degradation occurred in test 10-03, but not in 10-01; (2) Uranine correction based on apparent degradation rate in injection loop in test 11-02 seems reasonable when applied to data from test 10-03; (3) Colloid breakthrough curves quite similar in the two tests with similar recoveries relative to uranine (after correction); and (4) Much slower apparent desorption of homologues in test 10-03 than in 10-01 (any effect of residual homologues from test 10-01 in test 10-03?).

  1. COMPARISON OF THREE TRACER TESTS AT THE RAFT RIVER GEOTHERMAL SITE

    SciTech Connect (OSTI)

    Earl D Mattson; Mitchell Plummer; Carl Palmer; Larry Hull; Samantha Miller; Randy Nye

    2011-02-01T23:59:59.000Z

    Three conservative tracer tests have been conducted through the Bridge Fault fracture zone at the Raft River Geothermal (RRG) site. All three tests were conducted between injection well RRG-5 and production wells RRG-1 (790 m distance) and RRG-4 (740 m distance). The injection well is used during the summer months to provide pressure support to the production wells. The first test was conducted in 2008 using 136 kg of fluorescein tracer. Two additional tracers were injected in 2010. The first 2010 tracer injected was 100 kg fluorescein disodium hydrate salt on June, 21. The second tracer (100 kg 2,6-naphthalene disulfonic acid sodium salt) was injected one month later on July 21. Sampling of the two productions wells is still being performed to obtain the tail end of the second 2010 tracer test. Tracer concentrations were measured using HPLC with a fluorescence detector. Results for the 2008 test, suggest 80% tracer recover at the two production wells. Of the tracer recovered, 85% of tracer mass was recovered in well RRG-4 indicating a greater flow pathway connection between injection well and RRG-4 than RRG-1. Fluorescein tracer results appear to be similar between the 2008 and 2010 tests for well RRG-4 with peak concentrations arriving approximately 20 days after injection despite the differences between the injection rates for the two tests (~950 gpm to 475 gpm) between the 2008 and 2010. The two 2010 tracer tests will be compared to determine if the results support the hypothesis that rock contraction along the flow pathway due to the 55 oC cooler water injection alters the flow through the ~140 oC reservoir.

  2. Exit chimney joint and method of forming the joint for closed circuit steam cooled gas turbine nozzles

    DOE Patents [OSTI]

    Burdgick, Steven Sebastian (Schenectady, NY); Burns, James Lee (Schenectady, NY)

    2002-01-01T23:59:59.000Z

    A nozzle segment for a gas turbine includes inner and outer band portions and a vane extending between the band portions. The inner and outer band portions are each divided into first and second plenums separated by an impingement plate. Cooling steam is supplied to the first cavity for flow through the apertures to cool the outer nozzle wall. The steam flows through a leading edge cavity in the vane into the first cavity of the inner band portion for flow through apertures of the impingement plate to cool the inner nozzle wall. Spent cooling steam flows through a plurality of cavities in the vane, exiting through an exit chimney in the outer band. The exit chimney is secured at its inner end directly to the nozzle vane wall surrounding the exit cavities, to the margin of the impingement plate at a location intermediate the ends of the exit chimney and to margins of an opening through the cover whereby each joint is externally accessible for joint formation and for subsequent inspection.

  3. Tracer Testing At Coso Geothermal Area (1993) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f <MaintainedInformationThePtyTown Hall MeetingTracer Testing

  4. Tracer Testing At Coso Geothermal Area (2004) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f <MaintainedInformationThePtyTown Hall MeetingTracer TestingTesting

  5. Tracer Testing At Coso Geothermal Area (2006) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f <MaintainedInformationThePtyTown Hall MeetingTracer

  6. Tracer Testing At East Mesa Geothermal Area (1983) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f <MaintainedInformationThePtyTown Hall MeetingTracerInformation

  7. Tracer Testing At East Mesa Geothermal Area (1984) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f <MaintainedInformationThePtyTown Hall MeetingTracerInformation

  8. Natural Gas Prices Forecast Comparison--AEO vs. Natural Gas Markets

    E-Print Network [OSTI]

    Wong-Parodi, Gabrielle; Lekov, Alex; Dale, Larry

    2005-01-01T23:59:59.000Z

    of two methods to forecast natural gas prices: using theof two methods to forecast natural gas prices is performed:accurate average forecast of natural gas prices than the

  9. AN INTERCOMPARISON OF TRACER GASES USED FOR AIR INFILTRATION MEASUREMENTS

    E-Print Network [OSTI]

    Grimsrud, D.T.

    2011-01-01T23:59:59.000Z

    Janssen, A.N. Pearman, Honeywell, Inc. , Minneapolis, MN,gas. TABLE Z Research Group Honeywell Princeton LBL LBL LBL

  10. Rapid and sensitive gas chromatography ion-trap mass spectrometry method for the determination of tobacco specific N-nitrosamines in secondhand smoke

    SciTech Connect (OSTI)

    SLEIMAN, Mohamad; MADDALENA, Randy L.; GUNDEL, Lara A.; DESTAILLATS, Hugo

    2009-07-01T23:59:59.000Z

    Tobacco-specific nitrosamines (TSNAs) are some of the most potent carcinogens in tobacco and cigarette smoke. Accurate quantification of these chemicals is needed to help assess public health risks. We developed and validated a specific and sensitive method to measure four TSNAs in both the gas- and particle-phase of secondhand smoke (SHS) using gas chromatography and ion-trap tandem mass spectrometry,. A smoking machine in an 18-m3 room-sized chamber generated relevant concentrations of SHS that were actively sampled on Teflon coated fiber glass (TCFG) filters, and passively sampled on cellulose substrates. A simple solid-liquid extraction protocol using methanol as solvent was successfully applied to both filters with high recoveries ranging from 85 to 115percent. Tandem MS parameters were optimized to obtain the best sensitivity in terms of signal to-noise ratio (S/N) for the target compounds. For each TSNA, the major fragmentation pathways as well as ion structures were elucidated and compared with previously published data. The method showed excellent performances with a linear dynamic range between 2 and 1000 ng mL-1, low detection limits (S/N> 3) of 30-300 pg.ml-1 and precision with experimental errors below 10percent for all compounds. Moreover, no interfering peaks were observed indicating a high selectivity of MS/MS without the need for a sample clean up step. The sampling and analysis method provides a sensitive and accurate tool to detect and quantify traces of TSNA in SHS polluted indoor environments.

  11. Novel Multi-dimensional Tracers for Geothermal Inter-wall Diagnostics

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. The objective of this project is to develop a matrix of the smart geothermal tracer and its interpretation tools.

  12. An Analytical Solution for Slug-Tracer Tests in Fractured Reservoirs

    E-Print Network [OSTI]

    Shan, Chao; Pruess, Karsten

    2005-01-01T23:59:59.000Z

    Tracer Tests in Fractured Reservoirs Chao Shan and Karstenof chemicals or heat in fractured reservoirs is stronglyin a water-saturated fractured reservoir. The solution shows

  13. AN INTEGRATED APPROACH TO CHARACTERIZING BYPASSED OIL IN HETEROGENEOUS AND FRACTURED RESERVOIRS USING PARTITIONING TRACERS

    SciTech Connect (OSTI)

    Akhil Datta-Gupta

    2003-08-01T23:59:59.000Z

    We explore the use of efficient streamline-based simulation approaches for modeling partitioning interwell tracer tests in hydrocarbon reservoirs. Specifically, we utilize the unique features of streamline models to develop an efficient approach for interpretation and history matching of field tracer response. A critical aspect here is the underdetermined and highly ill-posed nature of the associated inverse problems. We have adopted an integrated approach whereby we combine data from multiple sources to minimize the uncertainty and non-uniqueness in the interpreted results. For partitioning interwell tracer tests, these are primarily the distribution of reservoir permeability and oil saturation distribution. A novel approach to multiscale data integration using Markov Random Fields (MRF) has been developed to integrate static data sources from the reservoir such as core, well log and 3-D seismic data. We have also explored the use of a finite difference reservoir simulator, UTCHEM, for field-scale design and optimization of partitioning interwell tracer tests. The finite-difference model allows us to include detailed physics associated with reactive tracer transport, particularly those related with transverse and cross-streamline mechanisms. We have investigated the potential use of downhole tracer samplers and also the use of natural tracers for the design of partitioning tracer tests. Finally, the behavior of partitioning tracer tests in fractured reservoirs is investigated using a dual-porosity finite-difference model.

  14. Steam tracer experiment at the Hoe Creek No. 3 underground coal gasification field test

    SciTech Connect (OSTI)

    Thorsness, C.B.

    1980-11-26T23:59:59.000Z

    Water plays an important role in in-situ coal gasification. To better understand this role, we conducted a steam tracer test during the later stages of the Hoe Creek No. 3 underground coal gasification field test. Deuterium oxide was used as the tracer. This report describes the tracer test and the analysis of the data obtained. The analysis indicates that at Hoe Creek the injected steam interacts with a large volume of water as it passes through the underground system. We hypothesize that this water is undergoing continual reflux in the underground system, resulting in a tracer response typical of a well-stirred tank.

  15. Method of removing SO.sub.2, NO.sub.X and particles from gas mixtures using streamer corona

    DOE Patents [OSTI]

    Mizuno, Akira (Toyohashi, JP); Clements, Judson S. (Tallahassee, FL)

    1987-01-01T23:59:59.000Z

    A method for converting sulfur dioxide and/or nitrogen oxide gases to acid mist and or particle aerosols is disclosed in which the gases are passed through a streamer corona discharge zone having electrodes of a wire-cylinder or wire-plate geometry.

  16. Study of Particle Rotation Effect in Gas-Solid Flows using Direct Numerical Simulation with a Lattice Boltzmann Method

    SciTech Connect (OSTI)

    Kwon, Kyung; Fan, Liang-Shih; Zhou, Qiang; Yang, Hui

    2014-09-30T23:59:59.000Z

    A new and efficient direct numerical method with second-order convergence accuracy was developed for fully resolved simulations of incompressible viscous flows laden with rigid particles. The method combines the state-of-the-art immersed boundary method (IBM), the multi-direct forcing method, and the lattice Boltzmann method (LBM). First, the multi-direct forcing method is adopted in the improved IBM to better approximate the no-slip/no-penetration (ns/np) condition on the surface of particles. Second, a slight retraction of the Lagrangian grid from the surface towards the interior of particles with a fraction of the Eulerian grid spacing helps increase the convergence accuracy of the method. An over-relaxation technique in the procedure of multi-direct forcing method and the classical fourth order Runge-Kutta scheme in the coupled fluid-particle interaction were applied. The use of the classical fourth order Runge-Kutta scheme helps the overall IB-LBM achieve the second order accuracy and provides more accurate predictions of the translational and rotational motion of particles. The preexistent code with the first-order convergence rate is updated so that the updated new code can resolve the translational and rotational motion of particles with the second-order convergence rate. The updated code has been validated with several benchmark applications. The efficiency of IBM and thus the efficiency of IB-LBM were improved by reducing the number of the Lagragian markers on particles by using a new formula for the number of Lagrangian markers on particle surfaces. The immersed boundary-lattice Boltzmann method (IBLBM) has been shown to predict correctly the angular velocity of a particle. Prior to examining drag force exerted on a cluster of particles, the updated IB-LBM code along with the new formula for the number of Lagrangian markers has been further validated by solving several theoretical problems. Moreover, the unsteadiness of the drag force is examined when a fluid is accelerated from rest by a constant average pressure gradient toward a steady Stokes flow. The simulation results agree well with the theories for the short- and long-time behavior of the drag force. Flows through non-rotational and rotational spheres in simple cubic arrays and random arrays are simulated over the entire range of packing fractions, and both low and moderate particle Reynolds numbers to compare the simulated results with the literature results and develop a new drag force formula, a new lift force formula, and a new torque formula. Random arrays of solid particles in fluids are generated with Monte Carlo procedure and Zinchenko's method to avoid crystallization of solid particles over high solid volume fractions. A new drag force formula was developed with extensive simulated results to be closely applicable to real processes over the entire range of packing fractions and both low and moderate particle Reynolds numbers. The simulation results indicate that the drag force is barely affected by rotational Reynolds numbers. Drag force is basically unchanged as the angle of the rotating axis varies.

  17. Process studies for a new method of removing H/sub 2/S from industrial gas streams

    SciTech Connect (OSTI)

    Neumann, D.W.; Lynn, S.

    1986-07-01T23:59:59.000Z

    A process for the removal of hydrogen sulfide from coal-derived gas streams has been developed. The basis for the process is the absorption of H/sub 2/S into a polar organic solvent where it is reacted with dissolved sulfur dioxide to form elemental sulfur. After sulfur is crystallized from solution, the solvent is stripped to remove dissolved gases and water formed by the reaction. The SO/sub 2/ is generated by burning a portion of the sulfur in a furnace where the heat of combustion is used to generate high pressure steam. The SO/sub 2/ is absorbed into part of the lean solvent to form the solution necessary for the first step. The kinetics of the reaction between H/sub 2/S and SO/sub 2/ dissolved in mixtures of N,N-Dimethylaniline (DMA)/ Diethylene Glycol Monomethyl Ether and DMA/Triethylene Glycol Dimethyl Ether was studied by following the temperature rise in an adiabatic calorimeter. This irreversible reaction was found to be first-order in both H/sub 2/S and SO/sub 2/, with an approximates heat of reaction of 28 kcal/mole of SO/sub 2/. The sole products of the reaction appear to be elemental sulfur and water. The presence of DMA increases the value of the second-order rate constant by an order of magnitude over that obtained in the glycol ethers alone. Addition of other tertiary aromatic amines enhances the observed kinetics; heterocyclic amines (e.g., pyridine derivatives) have been found to be 10 to 100 times more effective as catalysts when compared to DMA.

  18. Method for identifying subsurface fluid migration and drainage pathways in and among oil and gas reservoirs using 3-D and 4-D seismic imaging

    DOE Patents [OSTI]

    Anderson, R.N.; Boulanger, A.; Bagdonas, E.P.; Xu, L.; He, W.

    1996-12-17T23:59:59.000Z

    The invention utilizes 3-D and 4-D seismic surveys as a means of deriving information useful in petroleum exploration and reservoir management. The methods use both single seismic surveys (3-D) and multiple seismic surveys separated in time (4-D) of a region of interest to determine large scale migration pathways within sedimentary basins, and fine scale drainage structure and oil-water-gas regions within individual petroleum producing reservoirs. Such structure is identified using pattern recognition tools which define the regions of interest. The 4-D seismic data sets may be used for data completion for large scale structure where time intervals between surveys do not allow for dynamic evolution. The 4-D seismic data sets also may be used to find variations over time of small scale structure within individual reservoirs which may be used to identify petroleum drainage pathways, oil-water-gas regions and, hence, attractive drilling targets. After spatial orientation, and amplitude and frequency matching of the multiple seismic data sets, High Amplitude Event (HAE) regions consistent with the presence of petroleum are identified using seismic attribute analysis. High Amplitude Regions are grown and interconnected to establish plumbing networks on the large scale and reservoir structure on the small scale. Small scale variations over time between seismic surveys within individual reservoirs are identified and used to identify drainage patterns and bypassed petroleum to be recovered. The location of such drainage patterns and bypassed petroleum may be used to site wells. 22 figs.

  19. Method for identifying subsurface fluid migration and drainage pathways in and among oil and gas reservoirs using 3-D and 4-D seismic imaging

    DOE Patents [OSTI]

    Anderson, Roger N. (New York, NY); Boulanger, Albert (New York, NY); Bagdonas, Edward P. (Brookline, MA); Xu, Liqing (New Milford, NJ); He, Wei (New Milford, NJ)

    1996-01-01T23:59:59.000Z

    The invention utilizes 3-D and 4-D seismic surveys as a means of deriving information useful in petroleum exploration and reservoir management. The methods use both single seismic surveys (3-D) and multiple seismic surveys separated in time (4-D) of a region of interest to determine large scale migration pathways within sedimentary basins, and fine scale drainage structure and oil-water-gas regions within individual petroleum producing reservoirs. Such structure is identified using pattern recognition tools which define the regions of interest. The 4-D seismic data sets may be used for data completion for large scale structure where time intervals between surveys do not allow for dynamic evolution. The 4-D seismic data sets also may be used to find variations over time of small scale structure within individual reservoirs which may be used to identify petroleum drainage pathways, oil-water-gas regions and, hence, attractive drilling targets. After spatial orientation, and amplitude and frequency matching of the multiple seismic data sets, High Amplitude Event (HAE) regions consistent with the presence of petroleum are identified using seismic attribute analysis. High Amplitude Regions are grown and interconnected to establish plumbing networks on the large scale and reservoir structure on the small scale. Small scale variations over time between seismic surveys within individual reservoirs are identified and used to identify drainage patterns and bypassed petroleum to be recovered. The location of such drainage patterns and bypassed petroleum may be used to site wells.

  20. Inversion of Hydrological Tracer Test Data Using TomogrpahicConstraints

    SciTech Connect (OSTI)

    Linde, Niklas; Finsterle, Stefan; Hubbard, Susan

    2004-11-11T23:59:59.000Z

    A reasonable description of the hydraulic conductivity structure is a prerequisite for modeling contaminant transport. However, formulations of hydrogeological inverse problems utilizing hydrogeological data only often fail to reliably resolve features at a resolution required for accurately predicting transport. Incorporation of geophysical data into the inverse problem offers the potential to increase this resolution. In this study, we invert hydrological tracer test data using the shape and relative magnitude variations derived from geophysical tomographic data to regionalize a hydrogeological inverse problem in order to estimate the hydraulic conductivity structure. Our approach does not require that the petrophysical relationship be known a-priori, but that it is linear and stationary within each geophysical anomaly. However, tomograms are imperfect models of geophysical properties and geophysical properties are not necessarily strongly linked to hydraulic conductivity. Therefore, we focus on synthetic examples where the correlation between radar velocity and hydraulic conductivity, as well as the geophysical data acquisition errors, are varied in order to assess what aspects of the hydraulic conductivity structure we can expect to resolve under different conditions. The results indicate that regularization of the tracer inversion procedure using geophysical data improves estimates of hydraulic conductivity. We find that even under conditions of corrupted geophysical data, we can accurately estimate the effective hydraulic conductivity and areas of high and low hydraulic conductivity. However, given imperfect geophysical data, our results suggest that we cannot expect accurate estimates of the variability of the hydraulic conductivity structure.

  1. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D. (Alliance, OH); Downs, William (Alliance, OH); Jankura, Bryan J. (Mogadore, OH); McCoury, Jr., John M. (Mineral City, OH)

    1990-01-01T23:59:59.000Z

    An apparatus and method for sampling gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extends in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  2. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D. (Alliance, OH); Downs, William (Alliance, OH); Jankura, Bryan J. (Mogadore, OH); McCoury, Jr., John M. (Mineral City, OH)

    1989-01-01T23:59:59.000Z

    An apparatus and method for sampling a gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extend in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  3. 3D Modeling of One and Two Component Gas Flow in Fibrous Microstructures in Fuel Cells by Using the Lattice-Boltzmann Method

    E-Print Network [OSTI]

    Schmidt, Volker

    In fuel cells, a homogeneous distribution of gas flow is desirable for optimal performance. The gas3D Modeling of One and Two Component Gas Flow in Fibrous Microstructures in Fuel Cells by Using: Fuel Cells, 52425 Jülich, Germany b Institute of Stochastics, Ulm University, 89069 Ulm, Germany

  4. ADVANCES IN ATMOSPHERIC SCIENCES, VOL. 25, NO. 5, 2008, 805814 Diagnosing Ocean Tracer Transport from Sellafield

    E-Print Network [OSTI]

    Drange, Helge

    2 Bjerknes Centre for Climate Research, Bergen, Norway 3 Nansen-Zhu International Research Centre of biogeochemi- cal tracers influencing the oceanic carbon cycle are just two examples of where such information tracer concentration from idealized pulse releases from the British nuclear fuel reprocessing plants

  5. First Tracer Test After Circulation in Desert Peak 27-15

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Rose, Peter

    Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

  6. Heat as a tracer to determine streambed water exchanges Jim Constantz1

    E-Print Network [OSTI]

    Heat as a tracer to determine streambed water exchanges Jim Constantz1 Received 13 March 2008 of heat as a tracer of shallow groundwater movement and describes current temperature-based approaches relying on traditional observation wells, and remote sensing and other large-scale advanced temperature

  7. First Tracer Test After Circulation in Desert Peak 27-15

    SciTech Connect (OSTI)

    Rose, Peter

    2013-11-16T23:59:59.000Z

    Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

  8. TRACER ANALYSIS IN A FRACTURED GEO'MERMAL RESERVOIR: FIELD RESULTS FROM WAIRAKEI, NEW ZEALAND

    E-Print Network [OSTI]

    Stanford University

    TRACER ANALYSIS IN A FRACTURED GEO'MERMAL RESERVOIR: FIELD RESULTS FROM WAIRAKEI, NEW ZEALAND . . . . . . . . . . . . . . . . . . . . . . . . . . . 122 -V- #12;Chapter I INTRODUCTION Interwell tracers have been used extensively in oil reservoirs to detect reservoir heterogeneities. High permeability production zones can channel a disproportionate

  9. Numerical study of the diapycnal flow through a tidal front with passive tracers

    E-Print Network [OSTI]

    Dong, Changming "Charles"

    . This qualitatively agrees with a recent field experiment using a dye tracer on Georges Bank. Additional experiments are performed to investigate the sensitivity of the tracer dispersion to the tidal phase and the location, the previous studies indicated Eulerian cross-front mean circu- lation maybe is in a multiple-cell structure

  10. SOURCES AND EFFECTS OF MINING-RELATED AND NATURAL ACID ROCK DRAINAGE QUANTIFIED USING TRACER

    E-Print Network [OSTI]

    Ryan, Joe

    SOURCES AND EFFECTS OF MINING-RELATED AND NATURAL ACID ROCK DRAINAGE QUANTIFIED USING TRACER, and Architectural Engineering 2006 #12;ii This thesis entitled: Sources and Effects of Mining-Related and Natural Acid Rock Drainage Quantified Using Tracer Dilution, Coal Creek Watershed, Gunnison County, Colorado

  11. Slew-rate dependence of tracer magnetization response in magnetic particle imaging

    SciTech Connect (OSTI)

    Shah, Saqlain A.; Krishnan, K. M., E-mail: kannanmk@uw.edu [Materials Science and Engineering, University of Washington, Seattle, Washington 98195 (United States); Ferguson, R. M. [LodeSpin Labs, P.O. Box 95632, Seattle, Washington 98145 (United States)

    2014-10-28T23:59:59.000Z

    Magnetic Particle Imaging (MPI) is a new biomedical imaging technique that produces real-time, high-resolution tomographic images of superparamagnetic iron oxide nanoparticle tracers. Currently, 25?kHz and 20?mT/?{sub 0} excitation fields are common in MPI, but lower field amplitudes may be necessary for patient safety in future designs. Here, we address fundamental questions about MPI tracer magnetization dynamics and predict tracer performance in future scanners that employ new combinations of excitation field amplitude (H{sub o}) and frequency (?). Using an optimized, monodisperse MPI tracer, we studied how several combinations of drive field frequencies and amplitudes affect the tracer's response, using Magnetic Particle Spectrometry and AC hysteresis, for drive field conditions at 15.5, 26, and 40.2?kHz, with field amplitudes ranging from 7 to 52?mT/?{sub 0}. For both fluid and immobilized nanoparticle samples, we determined that magnetic response was dominated by Néel reversal. Furthermore, we observed that the peak slew-rate (?H{sub o}) determined the tracer magnetic response. Smaller amplitudes provided correspondingly smaller field of view, sometimes resulting in excitation of minor hysteresis loops. Changing the drive field conditions but keeping the peak slew-rate constant kept the tracer response almost the same. Higher peak slew-rates led to reduced maximum signal intensity and greater coercivity in the tracer response. Our experimental results were in reasonable agreement with Stoner-Wohlfarth model based theories.

  12. INTERPRETATION OF TRACER SURFACE DIFFUSION EXPERIMENTS ON UO2 ROLES OF GAS AND SOLID TRANSPORT PROCESSES

    E-Print Network [OSTI]

    Olander, D.R.

    2013-01-01T23:59:59.000Z

    hydrogen. This extrapolation was made using Eq [2) and the values of the trans- port properties (hydrogen in the MK experiment means that the UO is probably not stoichiometric. That this transport property

  13. The Critical Density and the Effective Excitation Density of Commonly Observed Molecular Dense Gas Tracers

    E-Print Network [OSTI]

    Shirley, Yancy L

    2015-01-01T23:59:59.000Z

    The optically thin critical densities and the effective excitation densities to produce a 1 K km/s (or 0.818 Jy km/s $(\\frac{\

  14. L\\'evy Fluctuations and Tracer Diffusion in Dilute Suspensions of Algae and Bacteria

    E-Print Network [OSTI]

    Zaid, Irwin M; Yeomans, Julia M

    2010-01-01T23:59:59.000Z

    Swimming microorganisms rely on effective mixing strategies to achieve efficient nutrient influx. Recent experiments, probing the mixing capability of unicellular biflagellates, revealed that passive tracer particles exhibit anomalous non-Gaussian diffusion when immersed in a dilute suspension of self-motile Chlamydomonas reinhardtii algae. Qualitatively, this observation can be explained by the fact that the algae induce a fluid flow that may occasionally accelerate the colloidal tracers to relatively large velocities. A satisfactory quantitative theory of enhanced mixing in dilute active suspensions, however, is lacking at present. In particular, it is unclear how non-Gaussian signatures in the tracers' position distribution are linked to the self-propulsion mechanism of a microorganism. Here, we develop a systematic theoretical description of anomalous tracer diffusion in active suspensions, based on a simplified tracer-swimmer interaction model that captures the typical distance scaling of a microswimmer'...

  15. Curvature Induced Activation of a Passive Tracer in an Active Bath

    E-Print Network [OSTI]

    S. A. Mallory; C. Valeriani; A. Cacciuto

    2014-09-25T23:59:59.000Z

    We use numerical simulations to study the motion of a large asymmetric tracer immersed in a low density suspension of self-propelled nanoparticles in two dimensions. Specifically, we analyze how the curvature of the tracer affects its translational and rotational motion in an active environment. We find that even very small amounts of curvature are sufficient for the active bath to impart directed motion to the tracer which results in its effective activation. We propose simple scaling arguments to characterize this induced activity in terms of the curvature of the tracer and the strength of the self-propelling force. Our results suggest new ways of controlling the transport properties of passive tracers in an active medium by carefully tailoring their geometry.

  16. THE EFFECTS OF NUMERICAL METHODS ON THE STATISTICAL COMPARISON BETWEEN EXPERIMENTS AND SIMULATIONS OF SHOCKED GAS CYLINDERS.

    SciTech Connect (OSTI)

    Rider, William; Kamm, J. R. (James R.); Tomkins, C. D. (Chris D.); Prestridge, K. P. (Katherine P.); Rightley, P. M. (Paul M.); Benjamin, R. F. (Robert F.); Zoldi, C. A. (Cindy A.)

    2001-01-01T23:59:59.000Z

    Validation of numerical simulations, Le., the quantitative comparison of calculated results with experimental data, is an essential practice in computational fluid dynamics. These comparisons are particularly difficult in the field of shock-accelerated fluid mixing, which can be dominated by irregular structures induced by flow instabilities. Such flows exhibit non-deterministic behavior, which eliminates my direct way to establish correspondence between experimental data and numerical simulation. We examine the detailed structures of mixing experiments and their simulation for Richtmyer-Meshkov (RM) experiments of Prestridge et al., Tomkins et al., and Jacobs. Numerical simulations of these experiments will be performed with several different high-resolution shock capturing schemes, including a variety of finite volume Godunov methods. We compare the experimental data for cOnfigurations of one and two diffuse cylinders of SF6 in air with numerical results using several multiscale metrics: fractal analysis, continuous wavelet transforms, and generalized correlations; these measures complement traditional metrics such as PDFs, mix fractions, and integral mixing widths.

  17. Integrated vacuum absorption steam cycle gas separation

    DOE Patents [OSTI]

    Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

    2011-11-22T23:59:59.000Z

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  18. Using Biofuel Tracers to Study Alternative Combustion Regimes

    SciTech Connect (OSTI)

    Mack, J H; Flowers, D L; Buchholz, B A; Dibble, R W

    2006-02-14T23:59:59.000Z

    Interest in the use of alternative fuels and combustion regimes is increasing as the price of petroleum climbs. The inherently higher efficiency of Diesel engines has led to increased adoption of Diesels in Europe, capturing approximately 40% of the new passenger car market. Unfortunately, lower CO{sub 2} emissions are countered with higher nitrogen oxides (NOx) and particulate matter (PM) emissions, and higher noise. Noise and PM have traditionally been the obstacles toward consumer acceptance of Diesel passenger cars in North America, while NOx (a key component in photochemical smog) has been more of an engineering challenge. Diesels are lean burning (combustion with excess oxygen) and reducing NOx to N2 in an oxygen rich environment is difficult. Adding oxygenated compounds to the fuel helps reduce PM emissions, but relying on fuel alone to reduce PM is unrealistic. Keeping peak combustion temperature below 1700 K prevents NOx formation. Altering the combustion regime to burn at temperatures below the NOx threshold and accept a wide variety of fuels seems like a promising alternative for future engines. Homogeneous Charge Compression Ignition (HCCI) is a possible solution. Fuel and air are well mixed prior to intake into a cylinder (homogeneous charge) and ignition occurs by compression of the fuel-air mixture by the piston. HCCI is rapid and relatively cool, producing little NOx and PM. Unfortunately, it is hard to control since HCCI is initiated by temperature and pressure instead of a spark or direct fuel injection. We investigate biofuel HCCI combustion, and use intrinsically labeled biofuels as tracers of HCCI combustion. Data from tracer experiments are used to validate combustion modeling.

  19. PROOF OF CONCEPT TEST OF A UNIQUE GASEOUS PERFLUROCARBON TRACER SYSTEM FOR VERIFICATION AND LONG TERM MONITORING OF CAPS AND COVER SYSTEMS CONDUCTED AT THE SAVANNAH RIVER SITE BENTONITE MAT TEST FACILITY.

    SciTech Connect (OSTI)

    HEISER,J.; SULLIVAN,T.; SERRATO,M.

    2002-02-24T23:59:59.000Z

    Engineered covers have been placed on top of buried/subsurface wastes to minimize water infiltration and therefore, release of hazardous contaminants. In order for the cover to protect the environment it must remain free of holes and breaches throughout its service life. Covers are subject to subsidence, erosion, animal intrusion, plant root infiltration, etc., all of which will affect the overall performance of the cover. The U.S. Department of Energy Environmental Management (DOE-EM) Program 2006 Accelerated Cleanup Plan is pushing for rapid closure of many of the DOE facilities. This will require a great number of new cover systems. Some of these new covers are expected to maintain their performance for periods of up to 1000 years. Long-term stewardship will require monitoring/verification of cover performance over the course of the designed lifetime. In addition, many existing covers are approaching the end of their design life and will need validation of current performance (if continued use is desired) or replacement (if degraded). The need for a reliable method of verification and long-term monitoring is readily apparent. Currently, failure is detected through monitoring wells downstream of the waste site. This is too late as the contaminants have already left the disposal area. The proposed approach is the use of gaseous Perfluorocarbon tracers (PFT) to verify and monitor cover performance. It is believed that PFTs will provide a technology that can verify a cover meets all performance objectives upon installation, be capable of predicting changes in cover performance and failure (defined as contaminants leaving the site) before it happens, and be cost-effective in supporting stewardship needs. The PFTs are injected beneath the cover and air samples taken above (either air samples or soil gas samples) at the top of the cover. The location, concentrations, and time of arrival of the tracer(s) provide a direct measure of cover performance. PFT technology can be used as a non-invasive method (if injection ports are emplaced prior to cover emplacement) on new covers or a minimally invasive method on existing covers. PFT verification will be useful at all buried waste sites using a cover system (e.g., treated or untreated chemical waste landfills) including DOE, commercial, and private sector sites. This paper discusses the initial field trial of the PFT cover monitoring system performed at the Savannah River Site (SRS) in FY01. The experiments provided a successful proof-of-principle test of the PFT technology in monitoring caps and covers. An injection and sampling array was installed in the Bentomat test cap at the SRS Caps Test Facility. This system contained 6 feet of sandy soil beneath a 1/2 inch geosynthetic clay liner covered by an HDPE liner which was covered by 2 feet of clayey top soil. PFTs were injected into the sandy soil though a pre-existing system of access pipes below the cap and soil gas samples were taken on top of the cap. Mid-way into the injection period a series of 1 1/2 inch holes were punched into the cap (through the geomembrane) to provide a positive breach in the cap. Data will be presented that shows the initial cap was fairly tight and leak free and that the artificially induced leaks were detectable within two hours of occurrence.

  20. Comparison of SF6 and Fluorescein as Tracers for Measuring Transport Processes in a Large Tidal River

    E-Print Network [OSTI]

    Ho, David

    Comparison of SF6 and Fluorescein as Tracers for Measuring Transport Processes in a Large Tidal SF6 as tracers of advection and longitudinal dispersion from a dual tracer release experiment of SF6 were injected into the Hudson River at an averaged depth of 9.5 m, 1 m above the bottom, near

  1. FeCycle: Attempting an iron biogeochemical budget from a mesoscale SF6 tracer experiment in unperturbed low iron waters

    E-Print Network [OSTI]

    Wilhelm, Steven W.

    FeCycle: Attempting an iron biogeochemical budget from a mesoscale SF6 tracer experiment to ocean physics. In summer 2003 we conducted FeCycle, a 10-day mesoscale tracer release in HNLC waters SE biogeochemical budget from a mesoscale SF6 tracer experiment in unperturbed low iron waters, Global Biogeochem

  2. Cryogenic treatment of gas

    DOE Patents [OSTI]

    Bravo, Jose Luis (Houston, TX); Harvey, III, Albert Destrehan (Kingwood, TX); Vinegar, Harold J. (Bellaire, TX)

    2012-04-03T23:59:59.000Z

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  3. Control methods and valve arrangement for start-up and shutdown of pressurized combustion and gasification systems integrated with a gas turbine

    DOE Patents [OSTI]

    Provol, Steve J. (Carlsbad, CA); Russell, David B. (San Diego, CA); Isaksson, Matti J. (Karhula, FI)

    1994-01-01T23:59:59.000Z

    A power plant having a system for converting coal to power in a gas turbine comprises a coal fed pressurized circulating bed for converting coal to pressurized gases, a gas turbine having a compressor for pressurizing air for the pressurized circulating bed and expander for receiving and expanding hot combustion gases for powering a generator, a first fast acting valve for controlling the pressurized air, a second fast acting valve means for controlling pressurized gas from the compressor to the expander.

  4. Analysis of Injection-Backflow Tracer Tests in Fractured Geothermal Reservoirs

    SciTech Connect (OSTI)

    Kocabas, I.; Horne, R.N.

    1987-01-20T23:59:59.000Z

    Tracer tests have been an important technique for determining the flow and reservoir characteristics in various rock matrix systems. While the interwell tracer tests are aimed at the characterization of the regions between the wells, single-well injection-backflow tracer tests may be useful tools of preliminary evaluation, before implementing long term interwell tracer tests. This work is concerned with the quantitative evaluation of the tracer return profiles obtained from single well injection-backflow tracer tests. First, two mathematical models of tracer transport through fractures, have been reviewed. These two models are based on two different principles: Taylor Dispersion along the fracture and simultaneous diffusion in and out of the adjacent matrix. Then the governing equations for the transport during the injection-backflow tests have been solved. Finally the results were applied to field data obtained from Raft River and East Mesa geothermal fields. In order to determine the values of the parameters of the models that define the transport mechanisms through fractures a non-linear optimization technique was employed. 26 refs., 10 figs.

  5. Dynamic mean field theory for lattice gas models of fluids confined in porous materials: Higher order theory based on the Bethe-Peierls and path probability method approximations

    SciTech Connect (OSTI)

    Edison, John R.; Monson, Peter A. [Department of Chemical Engineering, University of Massachusetts, Amherst, Massachusetts 01003-9303 (United States)

    2014-07-14T23:59:59.000Z

    Recently we have developed a dynamic mean field theory (DMFT) for lattice gas models of fluids in porous materials [P. A. Monson, J. Chem. Phys. 128(8), 084701 (2008)]. The theory can be used to describe the relaxation processes in the approach to equilibrium or metastable states for fluids in pores and is especially useful for studying system exhibiting adsorption/desorption hysteresis. In this paper we discuss the extension of the theory to higher order by means of the path probability method (PPM) of Kikuchi and co-workers. We show that this leads to a treatment of the dynamics that is consistent with thermodynamics coming from the Bethe-Peierls or Quasi-Chemical approximation for the equilibrium or metastable equilibrium states of the lattice model. We compare the results from the PPM with those from DMFT and from dynamic Monte Carlo simulations. We find that the predictions from PPM are qualitatively similar to those from DMFT but give somewhat improved quantitative accuracy, in part due to the superior treatment of the underlying thermodynamics. This comes at the cost of greater computational expense associated with the larger number of equations that must be solved.

  6. Tracers for monitoring the activity of sodium/glucose cotransporters in health and disease

    DOE Patents [OSTI]

    Wright, Ernest M; Barrio, Jorge R; Hirayama, Bruce A; Kepe, Vladimir

    2014-09-30T23:59:59.000Z

    Radiolabeled tracers for sodium/glucose cotransporters (SGLTs), their synthesis, and their use are provided. The tracers are methyl or ethyl pyranosides having an equatorial hydroxyl group at carbon-2 and a C 1 preferred conformation, radiolabeled with .sup.18F, .sup.123I, or .sup.124I, or free hexoses radiolabeled with .sup.18F, .sup.123I, or .sup.124. Also provided are in vivo and in vitro techniques for using these and other tracers as analytical and diagnostic tools to study glucose transport, in health and disease, and to evaluate therapeutic interventions.

  7. A Simple, Fast Method of Estimating Fractured Reservoir Geometry...

    Open Energy Info (EERE)

    Simple, Fast Method of Estimating Fractured Reservoir Geometry from Tracer Tests Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: A Simple, Fast...

  8. RESULTS FROM THE (1) DATA COLLECTION WORKSHOP, (2) MODELING WORKSHOP AND (3) DRILLING AND CORING METHODS WORKSHOP AS PART OF THE JOINT INDUSTRY PARTICIPATION (JIP) PROJECT TO CHARACTERIZE NATURAL GAS HYDRATES IN THE DEEPWATER GULF OF MEXICO

    SciTech Connect (OSTI)

    Stephen A. Holditch; Emrys Jones

    2002-09-01T23:59:59.000Z

    In 2000, Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deepwater portions of the Gulf of Mexico. A Joint Industry Participation (JIP) group was formed in 2001, and a project partially funded by the U.S. Department of Energy (DOE) began in October 2001. The primary objective of this project is to develop technology and data to assist in the characterization of naturally occurring gas hydrates in the deepwater Gulf of Mexico. These naturally occurring gas hydrates can cause problems relating to drilling and production of oil and gas, as well as building and operating pipelines. Other objectives of this project are to better understand how natural gas hydrates can affect seafloor stability, to gather data that can be used to study climate change, and to determine how the results of this project can be used to assess if and how gas hydrates act as a trapping mechanism for shallow oil or gas reservoirs. As part of the project, three workshops were held. The first was a data collection workshop, held in Houston during March 14-15, 2002. The purpose of this workshop was to find out what data exist on gas hydrates and to begin making that data available to the JIP. The second and third workshop, on Geoscience and Reservoir Modeling, and Drilling and Coring Methods, respectively, were held simultaneously in Houston during May 9-10, 2002. The Modeling Workshop was conducted to find out what data the various engineers, scientists and geoscientists want the JIP to collect in both the field and the laboratory. The Drilling and Coring workshop was to begin making plans on how we can collect the data required by the project's principal investigators.

  9. Alternative High-z Cosmic Tracers and the Dark Energy Equation of State

    E-Print Network [OSTI]

    Plionis, M; Basilakos, S; Bresolin, F; Terlevich, E; Melnick, J; Georgantopoulos, I

    2009-01-01T23:59:59.000Z

    We propose to use alternative cosmic tracers to measure the dark energy equation of state and the matter content of the Universe [w(z) & \\Omega_m]. Our proposed method consists of two components: (a) tracing the Hubble relation using HII-like starburst galaxies, as an alternative to SNIa, which can be detected up to very large redshifts, z~4, and (b) measuring the clustering pattern of X-ray selected AGN at a median redshift of ~1. Each component of the method can in itself provide interesting constraints on the cosmological parameters, especially under our anticipation that we will reduce the corresponding random and systematic errors significantly. However, by joining their likelihood functions we will be able to put stringent cosmological constraints and break the known degeneracies between the dark energy equation of state (whether it is constant or variable) and the matter content of the universe and provide a powerful and alternative rute to measure the contribution to the global dynamics, and the e...

  10. Constraining the Dark Energy Equation of State using Alternative High-z Cosmic Tracers

    E-Print Network [OSTI]

    Plionis, M; Basilakos, S; Bressolin, F; Terlevich, E; Melnick, J; Chavez, R

    2009-01-01T23:59:59.000Z

    We propose to use alternative cosmic tracers to measure the dark energy equation of state and the matter content of the Universe [w(z) & Omega_m]. Our proposed method consists of two components: (a) tracing the Hubble relation using HII galaxies which can be detected up to very large redshifts, z~4, as an alternative to supernovae type Ia, and (b) measuring the clustering pattern of X-ray selected AGN at a median redshift of z~1. Each component of the method can in itself provide interesting constraints on the cosmological parameters, especially under our anticipation that we will reduce the corresponding random and systematic errors significantly. However, by joining their likelihood functions we will be able to put stringent cosmological constraints and break the known degeneracies between the dark energy equation of state (whether it is constant or variable) and the matter content of the universe and provide a powerful and alternative route to measure the contribution to the global dynamics and the equ...

  11. Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system

    DOE Patents [OSTI]

    Tomlinson, Leroy Omar (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01T23:59:59.000Z

    In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

  12. Vapor spill monitoring method

    DOE Patents [OSTI]

    Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

  13. Shale Gas Opportunities It's no secret that petroleum and natural gas engineers are currently in great

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Shale Gas Opportunities It's no secret that petroleum and natural gas engineers are currently and natural gas engineers design and develop methods for getting oil and gas from underground deposits's Department of Petroleum and Natural Gas Engineering is competitive, with qualified applicants receiving

  14. Tracer diffusion at low temperature in kinetically constrained models

    E-Print Network [OSTI]

    Oriane Blondel

    2015-05-15T23:59:59.000Z

    We describe the motion of a tracer in an environment given by a kinetically constrained spin model (KCSM) at equilibrium. We check convergence of its trajectory properly rescaled to a Brownian motion and positivity of the diffusion coefficient $D$ as soon as the spectral gap of the environment is positive (which coincides with the ergodicity region under general conditions). Then we study the asymptotic behavior of $D$ when the density $1-q$ of the environment goes to $1$ in two classes of KCSM. For noncooperative models, the diffusion coefficient $D$ scales like a power of $q$, with an exponent that we compute explicitly. In the case of the Fredrickson-Andersen one-spin facilitated model, this proves a prediction made in Jung, Garrahan and Chandler [Phys. Rev. E 69 (2004) 061205]. For the East model, instead we prove that the diffusion coefficient is comparable to the spectral gap, which goes to zero faster than any power of $q$. This result contradicts the prediction of physicists (Jung, Garrahan and Chandler [Phys. Rev. E 69 (2004) 061205; J. Chem. Phys. 123 (2005) 084509]), based on numerical simulations, that suggested $D\\sim \\operatorname {gap}^{\\xi}$ with $\\xi<1$.

  15. GASEOUS CO ABUNDANCE-AN EVOLUTIONARY TRACER FOR MOLECULAR CLOUDS

    SciTech Connect (OSTI)

    Liu Tie; Wu Yuefang; Zhang Huawei, E-mail: liutiepku@gmail.com, E-mail: ywu@pku.edu.cn [Department of Astronomy, Peking University, Beijing 100871 (China)

    2013-09-20T23:59:59.000Z

    Planck cold clumps are among the most promising objects to investigate the initial conditions of the evolution of molecular clouds. In this work, by combing the dust emission data from the survey of the Planck satellite with the molecular data of {sup 12}CO/{sup 13}CO/C{sup 18}O (1-0) lines from observations with the Purple Mountain Observatory 13.7 m telescope, we investigate the CO abundance, CO depletion, and CO-to-H{sub 2} conversion factor of 674 clumps in the early cold cores sample. The median and mean values of the CO abundance are 0.89 Multiplication-Sign 10{sup -4} and 1.28 Multiplication-Sign 10{sup -4}, respectively. The mean and median of CO depletion factor are 1.7 and 0.9, respectively. The median value of X{sub CO-to-H{sub 2}} for the whole sample is 2.8 Multiplication-Sign 10{sup 20} cm{sup -2} K{sup -1} km{sup -1} s. The CO abundance, CO depletion factor, and CO-to-H{sub 2} conversion factor are strongly (anti-)correlated to other physical parameters (e.g., dust temperature, dust emissivity spectral index, column density, volume density, and luminosity-to-mass ratio). To conclude, the gaseous CO abundance can be used as an evolutionary tracer for molecular clouds.

  16. Dynamic Reservoir Characterization Of Naturally Fractured Reservoirs From An Inter-Well Tracer Test

    E-Print Network [OSTI]

    Kilicaslan, Ufuk

    2013-12-03T23:59:59.000Z

    After field redevelopment in the Sherrod Unit of the Spraberry Trend Area, an inter-well tracer test was conducted at the field scale in order to understand the fracture system, which forms preferential flow paths for better management...

  17. Author's personal copy Thorium-234 as a tracer of spatial, temporal and vertical variability

    E-Print Network [OSTI]

    Buesseler, Ken

    Author's personal copy Thorium-234 as a tracer of spatial, temporal and vertical variability 2009 Accepted 6 April 2009 Available online 16 April 2009 Keywords: Thorium-234 Particle flux Sediment

  18. Radium isotopes as tracers of coastal circulation pathways in the Mid-Atlantic Blight

    E-Print Network [OSTI]

    Rasmussen, Linda L

    2003-01-01T23:59:59.000Z

    Pathways of exchange between the shelf and slope in the Mid-Atlantic Bight were investigated using a combination of radiochemical tracer and hydrographic measurements. The motivation was to provide evidence of transport ...

  19. USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS...

    Open Energy Info (EERE)

    IN THE COSO EGS PROJECT Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE...

  20. Inversion of tracer test data using tomographic constraints Niklas Linde,1,2

    E-Print Network [OSTI]

    Hubbard, Susan

    Inversion of tracer test data using tomographic constraints Niklas Linde,1,2 Stefan Finsterle,3 be limited to field sites where this condition is partially or fully satisfied. Citation: Linde, N., S

  1. Development of Models to Simulate Tracer Behavior in Enhanced Geothermal Systems

    SciTech Connect (OSTI)

    Williams, Mark D.; Vermeul, Vincent R.; Reimus, P. W.; Newell, D.; Watson, Tom B.

    2010-06-01T23:59:59.000Z

    A recent report found that power and heat produced from engineered (or enhanced) geothermal systems (EGSs) could have a major impact on the United States while incurring minimal environmental impacts. EGS resources differ from high-grade hydrothermal resources in that they lack sufficient temperature distributions, permeability/porosity, fluid saturation, or recharge of reservoir fluids. Therefore, quantitative characterization of temperature distributions and the surface area available for heat transfer in EGS is necessary for commercial development of geothermal energy. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate this characterization. Modeling capabilities are being developed as part of this project to support laboratory and field testing to characterize engineered geothermal systems in single- and multi-well tests using tracers. The objective of this report is to describe the simulation plan and the status of model development for simulating tracer tests for characterizing EGS.

  2. CHEMICAL TRACER RETENTION IN POROUS MEDIA Submitted to the Department of Petroleum Engineering

    E-Print Network [OSTI]

    Stanford University

    * CHEMICAL TRACER RETENTION IN POROUS MEDIA A Report Submitted to the Department of Petroleum Engineering of Stanford University in Fulfillment of the Requirement for the Degree of Master of Science

  3. Glass mixing theory and tracer study results from the SF-10 run

    SciTech Connect (OSTI)

    Bowman, B.W.; Routt, K.R.

    1988-08-01T23:59:59.000Z

    A general, partial differential equation governing glass mixing in the Slurry Fed Ceramic Melter (SFCM) was derived and a solution obtained based upon certain simplifying assumptions. Tracer studies were then conducted in the SFCM during the SF-10 run to test the theory and characterize glass mixing in this melter. Analysis of the tracer data shows that glass mixing in the SFCM can be explained by use of a model of two, well-mixed tanks in series.

  4. A Laboratory Study of the Schmidt Number Dependency of Air-Water Gas

    E-Print Network [OSTI]

    Jaehne, Bernd

    . Sc = /D denotes the Schmidt number, the ratio of kinematic viscosity of water and the tracersA Laboratory Study of the Schmidt Number Dependency of Air-Water Gas Transfer Kerstin Richter1 of exchange hap- pens with an exponent of 1/2 and links this fraction with a physical property of the wave

  5. Supersonic gas compressor

    DOE Patents [OSTI]

    Lawlor, Shawn P. (Bellevue, WA); Novaresi, Mark A. (San Diego, CA); Cornelius, Charles C. (Kirkland, WA)

    2007-11-13T23:59:59.000Z

    A gas compressor based on the use of a driven rotor having a compression ramp traveling at a local supersonic inlet velocity (based on the combination of inlet gas velocity and tangential speed of the ramp) which compresses inlet gas against a stationary sidewall. In using this method to compress inlet gas, the supersonic compressor efficiently achieves high compression ratios while utilizing a compact, stabilized gasdynamic flow path. Operated at supersonic speeds, the inlet stabilizes an oblique/normal shock system in the gasdyanamic flow path formed between the rim of the rotor, the strakes, and a stationary external housing. Part load efficiency is enhanced by the use of a pre-swirl compressor, and using a bypass stream to bleed a portion of the intermediate pressure gas after passing through the pre-swirl compressor back to the inlet of the pre-swirl compressor. Inlet guide vanes to the compression ramp enhance overall efficiency.

  6. Urban Dispersion Program MSG05 Field Study: Summary of Tracer and Meteorological Measurements

    SciTech Connect (OSTI)

    Allwine, K Jerry; Flaherty, Julia E.

    2006-08-09T23:59:59.000Z

    The Urban Dispersion Program is a multi-year project, funded by the U.S. Department of Homeland Security, to better understand the flow and dispersion of airborne contaminants through and around the deep street canyons of New York City. The first tracer and meteorological field study was a limited study conducted during March 2005 near the Madison Square Garden in midtown Manhattan. Six safe, inert, gaseous perfluorocarbon tracers were released simultaneously at five street-level locations during two experimental days. In addition to collecting tracer data, meteorological data were also collected. Brookhaven National Laboratory conducted the bulk of the tracer and meteorological field efforts with Pacific Northwest National Laboratory and Stevens Institute of Technology assisting by measuring the vertical profile of winds. The Environmental Protection Agency worked with Brookhaven National Laboratory in accomplishing the personal exposure component of the study. This report presents some results from this analysis. In general, different release locations showed vastly different plume footprints for tracer materials, and the situation was made very complex with upwind and/or crosswind transport of tracer near street-level for the different release locations. Overall wind speeds and directions upwind and over the city were generally constant throughout each of the two experimental periods.

  7. Lévy Fluctuations and Tracer Diffusion in Dilute Suspensions of Algae and Bacteria

    E-Print Network [OSTI]

    Irwin M. Zaid; Jörn Dunkel; Julia M. Yeomans

    2010-09-20T23:59:59.000Z

    Swimming microorganisms rely on effective mixing strategies to achieve efficient nutrient influx. Recent experiments, probing the mixing capability of unicellular biflagellates, revealed that passive tracer particles exhibit anomalous non-Gaussian diffusion when immersed in a dilute suspension of self-motile Chlamydomonas reinhardtii algae. Qualitatively, this observation can be explained by the fact that the algae induce a fluid flow that may occasionally accelerate the colloidal tracers to relatively large velocities. A satisfactory quantitative theory of enhanced mixing in dilute active suspensions, however, is lacking at present. In particular, it is unclear how non-Gaussian signatures in the tracers' position distribution are linked to the self-propulsion mechanism of a microorganism. Here, we develop a systematic theoretical description of anomalous tracer diffusion in active suspensions, based on a simplified tracer-swimmer interaction model that captures the typical distance scaling of a microswimmer's flow field. We show that the experimentally observed non-Gaussian tails are generic and arise due to a combination of truncated L\\'evy statistics for the velocity field and algebraically decaying time correlations in the fluid. Our analytical considerations are illustrated through extensive simulations, implemented on graphics processing units to achieve the large sample sizes required for analyzing the tails of the tracer distributions.

  8. Field application of an interpretation method of downhole temperature and pressure data for detecting water entry in horizontal/highly inclined gas wells

    E-Print Network [OSTI]

    Achinivu, Ochi I.

    2009-05-15T23:59:59.000Z

    In the oil and gas industry today, continuous wellbore data can be obtained with high precision. This accurate and reliable downhole data acquisition is made possible by advancements in permanent monitoring systems such as downhole pressure...

  9. An evaluation of joint repair methods for cast iron natural gas distribution mains and the preliminary development of an alternative joint seal

    E-Print Network [OSTI]

    Rogers, Thomas Edward

    1984-01-01T23:59:59.000Z

    Approximately 10 percent of the natural gas pumped into distribution systems is unaccounted for. A significant portion of this amount is leakage from joints in 50 to 100 year old cast iron main. Because of the cumulative ...

  10. Side-by-Side Thermal Tests of Modular Offices: A Validation Study of the STEM Method

    SciTech Connect (OSTI)

    Judkoff, R.; Balcomb, J.D.; Hancock, C.E.; Barker, G.; Subbarao, K.

    2001-01-11T23:59:59.000Z

    Two modular office units were tested at the National Renewable Energy Laboratory (NREL) to establish each unit's thermal performance. The two units were nearly identical in appearance, but one was built with structural insulating panels (SIP), and the other was built using standard frame construction. The primary objective of these tests was to compare the thermal performance of buildings using SIP and standard frame construction. Both units were tested under carefully controlled steady-state conditions in the NREL large-scale environmental enclosure. They were then moved outdoors where Short-Term Energy Monitoring (STEM) tests were performed, and long-term heating and cooling energy use was measured. A secondary objective was to evaluate the accuracy of the NREL STEM method by comparing the results of outdoor STEM tests to steady-state indoor test results. STEM is a method developed by NREL to determine key thermal parameters of a building in-situ, based on a 3-day test sequence. The indoor test facility also provided the opportunity to investigate the phenomenon of infiltration heat recovery in a real building, under carefully controlled conditions, to evaluate the stability of the concentration decay method of tracer gas-based infiltration monitoring, and to compare the blower-door method with the tracer-gas technique in determining infiltration.This project was a cooperative effort with the Structural Insulated Panel Association, the Modular Building Institute, All-American Modular (AAM, the manufacturer of the units), and GE Capitol (the owner of the units). Richard Harmon, the president of AAM, requested NREL's assistance in exploring the feasibility of converting his manufacturing process to SIP construction. His engineering staff needed to assess which comfort and energy benefits might be associated with this new technology. AAM manufactured the two units, and NREL tested the modules for 8 months.

  11. Comparing Price Forecast Accuracy of Natural Gas Models and Futures Markets

    E-Print Network [OSTI]

    Wong-Parodi, Gabrielle; Dale, Larry; Lekov, Alex

    2005-01-01T23:59:59.000Z

    to accurately forecast natural gas prices. Many policyseek alternative methods to forecast natural gas prices. Thethe accuracy of forecasts for natural gas prices as reported

  12. Crystalline mesoporous tungsten oxide nanoplate monoliths synthesized by directed soft template method for highly sensitive NO{sub 2} gas sensor applications

    SciTech Connect (OSTI)

    Hoa, Nguyen Duc, E-mail: ndhoa@itims.edu.vn [International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology (HUST) (Viet Nam); Duy, Nguyen Van [International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology (HUST) (Viet Nam)] [International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology (HUST) (Viet Nam); Hieu, Nguyen Van, E-mail: hieu@itims.edu.vn [International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology (HUST) (Viet Nam)

    2013-02-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: ? Mesoporous WO{sub 3} nanoplate monoliths were obtained by direct templating synthesis. ? Enable effective accession of the analytic molecules for the sensor applications. ? The WO{sub 3} sensor exhibited a high performance to NO{sub 2} gas at low temperature. -- Abstract: Controllable synthesis of nanostructured metal oxide semiconductors with nanocrystalline size, porous structure, and large specific surface area is one of the key issues for effective gas sensor applications. In this study, crystalline mesoporous tungsten oxide nanoplate-like monoliths with high specific surface areas were obtained through instant direct-templating synthesis for highly sensitive nitrogen dioxide (NO{sub 2}) sensor applications. The copolymer soft template was converted into a solid carbon framework by heat treatment in an inert gas prior to calcinations in air to sustain the mesoporous structure of tungsten oxide. The multidirectional mesoporous structures of tungsten oxide with small crystalline size, large specific surface area, and superior physical characteristics enabled the rapid and effective accession of analytic gas molecules. As a result, the sensor response was enhanced and the response and recovery times were reduced, in which the mesoporous tungsten oxide based gas sensor exhibited a superior response of 21,155% to 5 ppm NO{sub 2}. In addition, the developed sensor exhibited selective detection of low NO{sub 2} concentration in ammonia and ethanol at a low temperature of approximately 150 °C.

  13. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    Internal Combustion Engines The methods described below for tracing fuel component carbon in the emissions

  14. The Dark Energy Equation of State using Alternative High-z Cosmic Tracers

    E-Print Network [OSTI]

    M. Plionis; R. Terlevich; S. Basilakos; F. Bresolin; E. Terlevich; J. Melnick; R. Chavez

    2010-01-18T23:59:59.000Z

    We propose to use alternative cosmic tracers to measure the dark energy equation of state and the matter content of the Universe [w(z) & Omega_m]. Our proposed method consists of two components: (a) tracing the Hubble relation using HII galaxies which can be detected up to very large redshifts, z~4, as an alternative to supernovae type Ia, and (b) measuring the clustering pattern of X-ray selected AGN at a median redshift of z~1. Each component of the method can in itself provide interesting constraints on the cosmological parameters, especially under our anticipation that we will reduce the corresponding random and systematic errors significantly. However, by joining their likelihood functions we will be able to put stringent cosmological constraints and break the known degeneracies between the dark energy equation of state (whether it is constant or variable) and the matter content of the universe and provide a powerful and alternative route to measure the contribution to the global dynamics and the equation of state of dark energy. A preliminary joint analysis of X-ray selected AGN (based on the largest to-date XMM survey; the 2XMM) and the currently largest SNIa sample (Hicken et al.), using as priors a flat universe and the WMAP5 normalization of the power-spectrum, provides: Omega_m=0.27+-0.02 and w=-0.96+-0.07. Equivalent and consistent results are provided by the joint analysis of X-ray selected AGN clustering and the latest Baryonic Acoustic Oscillation measures, providing: Omega_m=0.27+-0.02 and w=-0.97+-0.04.

  15. Results of injection and tracer tests in Olkaria north east field in Kenya

    SciTech Connect (OSTI)

    Karingithi, C.W. [Kenya Power Company Ltd., Naivasha (Kenya)

    1995-12-31T23:59:59.000Z

    Tracer and injection tests were performed in the Olkaria North East Field with the objective to reduce uncertainty in the engineering design and to determine the suitability of well OW-704 as a re-injection well for the waste brine from the steam field during production. An organic dye (sodium fluorescein) was injected into well OW-704 as a slug. The tracer returns were observed in well OW-M2 which is 580 m deep, 620 m from well OW-704 and well OW-716 which is 900 m from well OW-704. The other wells on discharge, OW-714, and OW-725 did not show any tracer returns. However, other chemical constituents suggested., that well OW-716 experienced a chemical breakthrough earlier than OW-M2. Tracer return velocities of 0.31 m/hr and 1.3 m/hr were observed. Results of the tracer and injection tests indicate that OW-704 may be used as a re-injection well provided a close monitoring program is put in place.

  16. Laboratory testing and modeling to evaluate perfluorocarbon compounds as tracers in geothermal systems

    SciTech Connect (OSTI)

    Reimus, Paul W [Los Alamos National Laboratory

    2011-01-21T23:59:59.000Z

    The thermal stability and adsorption characteristics of three perfluorinated hydrocarbon compounds were evaluated under geothermal conditions to determine the potential to use these compounds as conservative or thermally-degrading tracers in Engineered (or Enhanced) Geothermal Systems (EGS). The three compounds tested were perfluorodimethyl-cyclobutane (PDCB), perfluoromethylcyclohexane (PMCH), and perfluorotrimethylcyclohexane (PTCH), which are collectively referred to as perfluorinated tracers, or PFTs. Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second pair was charged with the brine-PFT mixture plus a mineral assemblage chosen to be representative of activated fractures in an EGS reservoir. A fifth reactor was charged with deionized water containing the three PFTs. The experiments were conducted at {approx}100 bar, with temperatures ranging from 230 C to 300 C. Semi-analytical and numerical modeling was also conducted to show how the PFTs could be used in conjunction with other tracers to interrogate surface area to volume ratios and temperature profiles in EGS reservoirs. Both single-well and cross-hole tracer tests are simulated to illustrate how different suites of tracers could be used to accomplish these objectives. The single-well tests are especially attractive for EGS applications because they allow the effectiveness of a stimulation to be evaluated without drilling a second well.

  17. Neutral carbon and CO in 76 (U)LIRGs and starburst galaxy centers A method to determine molecular gas properties in luminous galaxies

    E-Print Network [OSTI]

    Israel, F P; van der Werf, P

    2015-01-01T23:59:59.000Z

    We present fluxes in both neutral carbon [CI] lines at the centers of 76 galaxies with FIR luminosities between 10^{9} and 10^{12} L(o) obtained with Herschel-SPIRE and with ground-based facilities, along with the J=7-6, J=4-3, J=2-1 12CO and J=2-1 13CO line fluxes. We investigate whether these lines can be used to characterize the molecular ISM of the parent galaxies in simple ways and how the molecular gas properties define the model results. In most starburst galaxies, the [CI]/13CO flux ratio is much higher than in Galactic star-forming regions, and it is correlated to the total FIR luminosity. The [CI](1-0)/CO(4-3), the [CI](2-1) (2-1)/CO(7-6), and the [CI] (2-1)/(1-0) flux ratios are also correlated, and trace the excitation of the molecular gas. In the most luminous infrared galaxies (LIRGs), the ISM is fully dominated by dense and moderately warm gas clouds that appear to have low [C]/[CO] and [13CO]/[12CO] abundances. In less luminous galaxies, emission from gas clouds at lower densities becomes prog...

  18. Rapid gas hydrate formation process

    DOE Patents [OSTI]

    Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

    2013-01-15T23:59:59.000Z

    The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

  19. Interpretations of Tracer Tests Performed in the Culebra Dolomite at the Waste Isolation Pilot Plant Site

    SciTech Connect (OSTI)

    MEIGS,LUCY C.; BEAUHEIM,RICHARD L.; JONES,TOYA L.

    2000-08-01T23:59:59.000Z

    This report provides (1) an overview of all tracer testing conducted in the Culebra Dolomite Member of the Rustler Formation at the Waste Isolation Pilot Plant (WPP) site, (2) a detailed description of the important information about the 1995-96 tracer tests and the current interpretations of the data, and (3) a summary of the knowledge gained to date through tracer testing in the Culebra. Tracer tests have been used to identify transport processes occurring within the Culebra and quantify relevant parameters for use in performance assessment of the WIPP. The data, especially those from the tests performed in 1995-96, provide valuable insight into transport processes within the Culebra. Interpretations of the tracer tests in combination with geologic information, hydraulic-test information, and laboratory studies have resulted in a greatly improved conceptual model of transport processes within the Culebra. At locations where the transmissivity of the Culebra is low (< 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a single-porosity medium in which advection occurs largely through the primary porosity of the dolomite matrix. At locations where the transmissivity of the Culebra is high (> 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a heterogeneous, layered, fractured medium in which advection occurs largely through fractures and solutes diffuse between fractures and matrix at multiple rates. The variations in diffusion rate can be attributed to both variations in fracture spacing (or the spacing of advective pathways) and matrix heterogeneity. Flow and transport appear to be concentrated in the lower Culebra. At all locations, diffusion is the dominant transport process in the portions of the matrix that tracer does not access by flow.

  20. A radiocarbon method and multi-tracer approach to quantifying groundwater discharge to coastal waters

    E-Print Network [OSTI]

    Gramling, Carolyn M

    2003-01-01T23:59:59.000Z

    Groundwater discharge into estuaries and the coastal ocean is an important mechanism for the transport of dissolved chemical species to coastal waters. Because many dissolved species are present in groundwater in concentrations ...

  1. Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2-

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcat 1AMEE Jump to:Ohio:Ads-tecInformation Circa 2007 Jumpand

  2. A CFD study of gas-solid jet in a CFB riser flow

    SciTech Connect (OSTI)

    Li, Tingwen; Guenther, Chris

    2012-03-01T23:59:59.000Z

    Three-dimensional high-resolution numerical simulations of a gas–solid jet in a high-density riser flow were conducted. The impact of gas–solid injection on the riser flow hydrodynamics was investigated with respect to voidage, tracer mass fractions, and solids velocity distribution. The behaviors of a gas–solid jet in the riser crossflow were studied through the unsteady numerical simulations. Substantial separation of the jetting gas and solids in the riser crossflow was observed. Mixing of the injected gas and solids with the riser flow was investigated and backmixing of gas and solids was evaluated. In the current numerical study, both the overall hydrodynamics of riser flow and the characteristics of gas–solid jet were reasonably predicted compared with the experimental measurements made at NETL.

  3. Correction to ``Stratospheric CO2 isotopic anomalies and SF6 and CFC tracer concentrations in the Arctic

    E-Print Network [OSTI]

    Alexander, Becky

    Correction to ``Stratospheric CO2 isotopic anomalies and SF6 and CFC tracer concentrations anomalies and SF6 and CFC tracer concentrations in the Arctic polar vortex'' [Alexander et al., 2001 of the approx- imate mean SF6 ages versus Á17 O (diamonds) and d18 O (circles). References Alexander, B., M. K

  4. Ventilation of the deep ocean constrained with tracer observations and implications for radiocarbon estimates of ideal mean age

    E-Print Network [OSTI]

    Khatiwala, Samar

    Ventilation of the deep ocean constrained with tracer observations and implications for radiocarbon: ocean ventilation tracers ideal mean age radiocarbon age Green function inverse modeling Ocean ventilation is the process that transports water and climatically important trace gases such as carbon dioxide

  5. Characterizing the Hydrology of Shallow Floodplain Lakes in the Slave River Delta, NWT, Canada, Using Water Isotope Tracers

    E-Print Network [OSTI]

    Edwards, Thomas W.D.

    , all delta lakes underwent heavy-isotope enrichment due to evaporation, although lakes flooded, Using Water Isotope Tracers Bronwyn E. Brock*{ Brent B. Wolfe*{ and Thomas W. D. Edwards* *Department using water isotope tracers and total suspended sediment (TSS) analyses. A suite of 41 lakes from three

  6. GeneTracer: Gene Sequence Analysis of Disease Mutations VAST 2010 Mini Challenge 3 Award: Excellent Process Explanation

    E-Print Network [OSTI]

    Stasko, John T.

    GeneTracer: Gene Sequence Analysis of Disease Mutations VAST 2010 Mini Challenge 3 Award: ExcellentTracer, developed for the VAST 2010 genetic sequence mini challenge, visualizes gene sequences of cur- rent outbreaks and native sequences along with disease character- istics. We successfully used Gene

  7. Polymide gas separation membranes

    DOE Patents [OSTI]

    Ding, Yong; Bikson, Benjamin; Nelson, Joyce Katz

    2004-09-14T23:59:59.000Z

    Soluble polyamic acid salt (PAAS) precursors comprised of tertiary and quaternary amines, ammonium cations, sulfonium cations, or phosphonium cations, are prepared and fabricated into membranes that are subsequently imidized and converted into rigid-rod polyimide articles, such as membranes with desirable gas separation properties. A method of enhancing solubility of PAAS polymers in alcohols is also disclosed.

  8. Gas turbine diagnostic system

    E-Print Network [OSTI]

    Talgat, Shuvatov

    2011-01-01T23:59:59.000Z

    In the given article the methods of parametric diagnostics of gas turbine based on fuzzy logic is proposed. The diagnostic map of interconnection between some parts of turbine and changes of corresponding parameters has been developed. Also we have created model to define the efficiency of the compressor using fuzzy logic algorithms.

  9. Total Matrix Intercomparison: A Method for Determining the Geometry of Water-Mass Pathways

    E-Print Network [OSTI]

    Gebbie, Geoffrey

    Ocean tracer distributions have long been used to decompose the deep ocean into constituent water masses, but previous inverse methods have generally been limited to just a few water masses that have been defined by a ...

  10. Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and Fracture/Heat Transfer Surface Area in Geothermal Reservoirs

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Project Summary. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate quantitative characterization of temperature distributions and surface area available for heat transfer in EGS.

  11. Tracer studies of pathways and rates of meltwater transport through Arctic summer sea ice

    E-Print Network [OSTI]

    Eicken, Hajo

    Tracer studies of pathways and rates of meltwater transport through Arctic summer sea ice H. Eicken) program's field site in the northern Chukchi Sea, snow and ice meltwater flow was found to have a strong impact on the heat and mass balance of sea ice during the summer of 1998. Pathways and rates of meltwater

  12. Assessment of the detection abilities of monitoring networks for passive tracers at local and regional scales

    E-Print Network [OSTI]

    Mallet, Vivien

    -field studies involve measurement sensors placed within 30 km of nuclear power plants, whether at fixed to power plant locations. They have been carried out at several spatial scales, from local to global: nearAssessment of the detection abilities of monitoring networks for passive tracers at local

  13. Physical causes and modeling challenges of anomalous diffusion of sediment tracers

    E-Print Network [OSTI]

    Physical causes and modeling challenges of anomalous diffusion of sediment tracers Douglas] #12;Velocity autocorrelation: Controlled by inertia 0.1 1 Dispersion: inertial at short time particles spend much more time at rest than in motion. Stochastic modeling approach: Direct solution of f

  14. 6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS AND TRACERS OF GALACTIC

    E-Print Network [OSTI]

    Richardson Jr., James E.

    6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS AND TRACERS OF GALACTIC STRUCTURE A Dissertation Jagadheep Dhanasekara Pandian ALL RIGHTS RESERVED #12;6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS transition of methanol is the strongest of methanol masers, and is the second strongest maser transition ever

  15. Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum Oxide Catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum of propane over ZrO2-supported MoOx catalysts. Competitive reactions of C3H6 and CH3 13 CH2CH3 showed combustion of propene, or by direct combustion of propane. A mixture of C3H8 and C3D8 undergoes oxidative

  16. Tracer transport in the presence of steady zonal jets in a forced and viscous barotropic model

    E-Print Network [OSTI]

    Collier, Jonathan Craig

    2000-01-01T23:59:59.000Z

    Tracers released into a barotropic fluid which was not subject to the beta-effect were seen to disperse according to the classical laws given by G.I. Taylor in 1921. In the short-time limit, the average total displacement was proportional...

  17. TRACER AND DARCY-BASED IDENTIFICATION OF SUBSURFACE FLOW, BUKIT TIMAH FOREST,

    E-Print Network [OSTI]

    Chappell, Nick A

    that catchment or even slope scale simulation using parameters of the Darcy-Buckingham-Richards equation, the validity of the Richards equation (or the Darcy- Buckingham equation in its steady-state form) at slopeTRACER AND DARCY-BASED IDENTIFICATION OF SUBSURFACE FLOW, BUKIT TIMAH FOREST, SINGAPORE M

  18. TRACER: A Trace Replay Tool to Evaluate Energy-Efficiency of Mass Storage Systems

    E-Print Network [OSTI]

    Qin, Xiao

    TRACER: A Trace Replay Tool to Evaluate Energy-Efficiency of Mass Storage Systems Zhuo Liu1 , Fei of accurately evaluating energy-efficient storage systems and objectively comparing a wide range of energy RAID5 enterprise disk array. Our experiments demonstrate that energy-efficient mass storage systems can

  19. Fracture Model, Ground Displacements and Tracer Observations: Fruitland Coals, San Juan Basin, New Mexico,

    E-Print Network [OSTI]

    Wilson, Thomas H.

    that the coal reservoirs consist of six separate coal beds rather than three. Perfluorocarbon tracer monitoring the site consist of two coal beds, each separated by a shale parting. This observation indicates will improve our understanding of Fruitland coal reservoirs; help develop more effective strategies to enhance

  20. Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period

    E-Print Network [OSTI]

    Price, P. Buford

    Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period R ash layers determined by remote optical borehole logging and core assays. We find that the Antarctic. These globally coincident volcanics were associated with abrupt cooling, often simultaneous with onsets or sudden

  1. Small-scale mixing, large-scale advection and stratospheric tracer distributions

    E-Print Network [OSTI]

    Vanneste, Jacques

    , United Kingdom. Email: J.Vanneste@ed.ac.uk #12;The vertical mixing of tracers in the stratosphere distributions which are demonstrated using numerical simulations based on observed stratospheric winds. Specif in the turbulent-energy input, three-dimensional turbulence is confined within patches that are lo- calized

  2. Flammable gas project topical report

    SciTech Connect (OSTI)

    Johnson, G.D.

    1997-01-29T23:59:59.000Z

    The flammable gas safety issue was recognized in 1990 with the declaration of an unreviewed safety question (USQ) by the U. S. Department of Energy as a result of the behavior of the Hanford Site high-level waste tank 241-SY-101. This tank exhibited episodic releases of flammable gas that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years there has been a considerable amount of knowledge gained about the chemical and physical processes that govern the behavior of tank 241-SY-1 01 and other tanks associated with the flammable gas safety issue. This report was prepared to provide an overview of that knowledge and to provide a description of the key information still needed to resolve the issue. Items covered by this report include summaries of the understanding of gas generation, retention and release mechanisms, the composition and flammability behavior of the gas mixture, the amounts of stored gas, and estimated gas release fractions for spontaneous releases. `Me report also discusses methods being developed for evaluating the 177 tanks at the Hanford Site and the problems associated with these methods. Means for measuring the gases emitted from the waste are described along with laboratory experiments designed to gain more information regarding rates of generation, species of gases emitted and modes of gas storage and release. Finally, the process for closing the USQ is outlined as are the information requirements to understand and resolve the flammable gas issue.

  3. Gas turbine combustor transition

    DOE Patents [OSTI]

    Coslow, Billy Joe (Winter Park, FL); Whidden, Graydon Lane (Great Blue, CT)

    1999-01-01T23:59:59.000Z

    A method of converting a steam cooled transition to an air cooled transition in a gas turbine having a compressor in fluid communication with a combustor, a turbine section in fluid communication with the combustor, the transition disposed in a combustor shell and having a cooling circuit connecting a steam outlet and a steam inlet and wherein hot gas flows from the combustor through the transition and to the turbine section, includes forming an air outlet in the transition in fluid communication with the cooling circuit and providing for an air inlet in the transition in fluid communication with the cooling circuit.

  4. Gas turbine combustor transition

    DOE Patents [OSTI]

    Coslow, B.J.; Whidden, G.L.

    1999-05-25T23:59:59.000Z

    A method is described for converting a steam cooled transition to an air cooled transition in a gas turbine having a compressor in fluid communication with a combustor, a turbine section in fluid communication with the combustor, the transition disposed in a combustor shell and having a cooling circuit connecting a steam outlet and a steam inlet and wherein hot gas flows from the combustor through the transition and to the turbine section, includes forming an air outlet in the transition in fluid communication with the cooling circuit and providing for an air inlet in the transition in fluid communication with the cooling circuit. 7 figs.

  5. Adaptive Methods for Modelling Transport Processes in Fractured Subsurface Systems

    E-Print Network [OSTI]

    Cirpka, Olaf Arie

    ­ discrete Galerkin method applying finite differences for the discretization in time and the StreamlineAdaptive Methods for Modelling Transport Processes in Fractured Subsurface Systems 3rd­adaptive methods for modelling transport processes in fractured rock. As a simplification, ideal tracers

  6. Method and apparatus utilizing ionizing and microwave radiation for saturation determination of water, oil and a gas in a core sample

    DOE Patents [OSTI]

    Maerefat, Nicida L. (Sugar Land, TX); Parmeswar, Ravi (Marlton, NJ); Brinkmeyer, Alan D. (Tulsa, OK); Honarpour, Mehdi (Bartlesville, OK)

    1994-01-01T23:59:59.000Z

    A system for determining the relative permeabilities of gas, water and oil in a core sample has a microwave emitter/detector subsystem and an X-ray emitter/detector subsystem. A core holder positions the core sample between microwave absorbers which prevent diffracted microwaves from reaching a microwave detector where they would reduce the signal-to-noise ratio of the microwave measurements. The microwave emitter/detector subsystem and the X-ray emitter/detector subsystem each have linear calibration characteristics, allowing one subsystem to be calibrated with respect to the other subsystem. The dynamic range of microwave measurements is extended through the use of adjustable attenuators. This also facilitates the use of core samples with wide diameters. The stratification characteristics of the fluids may be observed with a windowed cell separator at the outlet of the core sample. The condensation of heavy hydrocarbon gas and the dynamic characteristics of the fluids are observed with a sight glass at the outlet of the core sample.

  7. Comparison of 13CO Line and Far-Infrared Continuum Emission as a Diagnostic of Dust and Molecular Gas Physical Conditions: II. The Simulations: Testing the Method

    E-Print Network [OSTI]

    W. F. Wall

    2006-01-24T23:59:59.000Z

    The reliability of modeling the far-IR continuum to 13CO J=1-0 spectral line ratios applied to the Orion clouds (Wall 2006) is tested by applying the models to simulated data. The two-component models are found to give the dust-gas temperature difference, $\\DT$, to within 1 or 2$ $K. However, other parameters like the column density per velocity interval and the gas density can be wrong by an order of magnitude or more. In particular, the density can be systematically underestimated by an order of magnitude or more. The overall mass of the clouds is estimated correctly to within a few percent. The one-component models estimate the column density per velocity interval and density within factors of 2 or 3, but their estimates of $\\DT$ can be wrong by 20$ $K. They also underestimate the mass of the clouds by 40-50%. These results may permit us to reliably constrain estimates of the Orion clouds' physical parameters, based on the real observations of the far-IR continuum and 13CO J=1-0 spectral line. Nevertheless, other systematics must be treated first. These include the effects of background/foreground subtraction, effects of the HI component of the ISM, and others. These will be discussed in a future paper (Wall 2006a).

  8. Method and apparatus utilizing ionizing and microwave radiation for saturation determination of water, oil and a gas in a core sample

    DOE Patents [OSTI]

    Maerefat, N.L.; Parmeswar, R.; Brinkmeyer, A.D.; Honarpour, M.

    1994-08-23T23:59:59.000Z

    A system is described for determining the relative permeabilities of gas, water and oil in a core sample has a microwave emitter/detector subsystem and an X-ray emitter/detector subsystem. A core holder positions the core sample between microwave absorbers which prevent diffracted microwaves from reaching a microwave detector where they would reduce the signal-to-noise ratio of the microwave measurements. The microwave emitter/detector subsystem and the X-ray emitter/detector subsystem each have linear calibration characteristics, allowing one subsystem to be calibrated with respect to the other subsystem. The dynamic range of microwave measurements is extended through the use of adjustable attenuators. This also facilitates the use of core samples with wide diameters. The stratification characteristics of the fluids may be observed with a windowed cell separator at the outlet of the core sample. The condensation of heavy hydrocarbon gas and the dynamic characteristics of the fluids are observed with a sight glass at the outlet of the core sample. 11 figs.

  9. Evidence of Multi-Process Matrix Diffusion in a Single Fracturefrom a Field Tracer Test

    SciTech Connect (OSTI)

    Zhou, Quanlin; Liu, Hui-Hai; Bodvarsson, Gudmundur; Molz, Fred J.

    2005-06-11T23:59:59.000Z

    Compared to values inferred from laboratory tests on matrix cores, many field tracer tests in fractured rock have shown enhanced matrix diffusion coefficient values (obtained using a single-process matrix-diffusion model with a homogeneous matrix diffusion coefficient). To investigate this phenomenon, a conceptual model of multi-process matrix diffusion in a single-fracture system was developed. In this model, three matrix diffusion processes of different diffusion rates were assumed to coexist: (1) diffusion into stagnant water and infilling materials within fractures, (2) diffusion into a degraded matrix zone, and (3) further diffusion into an intact matrix zone. The validity of the conceptual model was then demonstrated by analyzing a unique tracer test conducted using a long-time constant-concentration injection. The tracer-test analysis was conducted using a numerical model capable of tracking the multiple matrix-diffusion processes. The analysis showed that in the degraded zone, a diffusion process with an enhanced diffusion rate controlled the steep rising limb and decay-like falling limb in the observed breakthrough curve, whereas in the intact matrix zone, a process involving a lower diffusion rate affected the long-term middle platform of slowly increasing tracer concentration. The different matrix-diffusion-coefficient values revealed from the field tracer test are consistent with the variability of matrix diffusion coefficient measured for rock cores with different degrees of fracture coating at the same site. By comparing to the matrix diffusion coefficient calibrated using single-process matrix diffusion, we demonstrated that this multi-process matrix diffusion may contribute to the enhanced matrix-diffusion-coefficient values for single-fracture systems at the field scale.

  10. Applications of Ensemble-based Data Assimilation Techniques for Aquifer Characterization using Tracer Data at Hanford 300 Area

    SciTech Connect (OSTI)

    Chen, Xingyuan; Hammond, Glenn E.; Murray, Christopher J.; Rockhold, Mark L.; Vermeul, Vincent R.; Zachara, John M.

    2013-10-31T23:59:59.000Z

    Subsurface aquifer characterization often involves high parameter dimensionality and requires tremendous computational resources if employing a full Bayesian approach. Ensemble-based data assimilation techniques, including filtering and smoothing, are computationally efficient alternatives. Despite the increasing number of applications of ensemble-based methods in assimilating flow and transport related data for subsurface aquifer charaterization, most are limited to either synthetic studies or two-dimensional problems. In this study, we applied ensemble-based techniques for assimilating field tracer experimental data obtained from the Integrated Field Research Challenge (IFRC) site at the Hanford 300 Area. The forward problem was simulated using the massively-parallel three-dimensional flow and transport code PFLOTRAN to effectively deal with the highly transient flow boundary conditions at the site and to meet the computational demands of ensemble-based methods. This study demonstrates the effectiveness of ensemble-based methods for characterizing a heterogeneous aquifer by sequentially assimilating multiple types of data. The necessity of employing high performance computing is shown to enable increasingly mechanistic non-linear forward simulations to be performed within the data assimilation framework for a complex system with reasonable turnaround time.

  11. Rotanone analogs: method of preparation and use

    SciTech Connect (OSTI)

    2013-10-08T23:59:59.000Z

    The present invention provides rotenone analogs and methods of making and using them. Labeled with single photon and positron emitting isotopes, the rotenone analogs of the present invention are useful in, for example, clinical imaging applications as tracers to measure cardiac blood flow and detect regions of ischemia.

  12. DIVISION S-3-NOTES HYDROLOGIC TRACER EFFECTS ON SOIL

    E-Print Network [OSTI]

    Gold, Art

    ,* ARTHUR J. GOLD, AND GALEN HOWARD Abstract While muchresearch has shown thatthecommonly used hydrologic such P.M. Groffman, Inst. of Ecosystem Studies, Box AB, Millbrook, NY 12545; A.J. Gold and G. Howard, Dep. Methods The soil used for these experiments is a Rainbow silt loam (coarse-loamy, mixed, mesic Aquic

  13. NuclearHydrogen Oil and gas

    E-Print Network [OSTI]

    Birmingham, University of

    Policy NuclearHydrogen Transport Education Oil and gas Distribution Society Supply Ecology Demand Hydrogen 08 Policy and society 10 Environment 11 Transport 12 Manufacturing 14 Oil and gas 15 Nuclear 16 and infrastructure, and broaden our methods of generation. Our declining reserves of oil and gas must be repla

  14. Retained Gas Sampler Calibration and Simulant Tests

    SciTech Connect (OSTI)

    CRAWFORD, B.A.

    2000-01-05T23:59:59.000Z

    This test plan provides a method for calibration of the retained gas sampler (RGS) for ammonia gas analysis. Simulant solutions of ammonium hydroxide at known concentrations will be diluted with isotopically labeled 0.04 M ammonium hydroxide solution. Sea sand solids will also be mixed with ammonium hydroxide solution and diluent to determine the accuracy of the system for ammonia gas analysis.

  15. Numerical Simulation of Cooling Gas Injection Using

    E-Print Network [OSTI]

    Numerical Simulation of Cooling Gas Injection Using Adaptive Multiscale Techniques Wolfgang Dahmen: finite volume method, film cooling, cooling gas injection, multiscale techniques, grid adaptation AMS@igpm.rwth-aachen.de (Thomas Gotzen) #12;Numerical simulation of cooling gas injection using adaptive multiscale techniques

  16. Laser cross-flow gas system

    DOE Patents [OSTI]

    Duncan, D.B.

    1992-11-24T23:59:59.000Z

    A method and laser apparatus are disclosed which provide for a cross-flow of gas near one end of a laser discharge tube. The cross-flow of gas causes a concentration gradient which affects diffusion of contaminants in the discharge tube towards the cross-flow of the gas, which contaminants are then withdrawn from the discharge tube. 1 figure.

  17. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01T23:59:59.000Z

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  18. Water-saving liquid-gas conditioning system

    DOE Patents [OSTI]

    Martin, Christopher; Zhuang, Ye

    2014-01-14T23:59:59.000Z

    A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

  19. Overview of SIMS-Based Experimental Studies of Tracer Diffusion in Solids and Application to Mg Self-Diffusion

    SciTech Connect (OSTI)

    Kulkarni, Nagraj S [ORNL; Warmack, Robert J Bruce [ORNL; Radhakrishnan, Balasubramaniam [ORNL; HunterJr., Jerry [Virginia Polytechnic Institute and State University; Sohn, Yong Ho [University of Central Florida; Coffey, Kevin [University of Central Florida; Murch, Prof. Graeme [University of Newcastle, NSW, Australia; Belova, Irina [University of Newcastle, NSW, Australia

    2014-01-01T23:59:59.000Z

    Tracer diffusivities provide the most fundamental information on diffusion in materials and are the foundation of robust diffusion databases. Compared to traditional radiotracer techniques that utilize radioactive isotopes, the secondary ion mass spectrometry (SIMS) based thin-film technique for tracer diffusion is based on the use of enriched stable isotopes that can be accurately profiled using SIMS. Experimental procedures & techniques that are utilized for the measurement of tracer diffusion coefficients are presented for pure magnesium, which presents some unique challenges due to the ease of oxidation. The development of a modified Shewmon-Rhines diffusion capsule for annealing Mg and an ultra-high vacuum (UHV) system for sputter deposition of Mg isotopes are discussed. Optimized conditions for accurate SIMS depth profiling in polycrystalline Mg are provided. An automated procedure for the correction of heat-up and cool-down times during tracer diffusion annealing is discussed. The non-linear fitting of a SIMS depth profile data using the thin film Gaussian solution to obtain the tracer diffusivity along with the background tracer concentration and tracer film thickness is discussed. An Arrhenius fit of the Mg self-diffusion data obtained using the low-temperature SIMS measurements from this study and the high-temperature radiotracer measurements of Shewmon and Rhines (1954) was found to be a good representation of both types of diffusion data that cover a broad range of temperatures between 250 - 627 C (523 900 K).

  20. Methane hydrate gas production: evaluating and exploiting the solid gas resource

    SciTech Connect (OSTI)

    McGuire, P.L.

    1981-01-01T23:59:59.000Z

    Methane hydrate gas could be a tremendous energy resource if methods can be devised to produce this gas economically. This paper examines two methods of producing gas from hydrate deposits by the injection of hot water or steam, and also examines the feasibility of hydraulic fracturing and pressure reduction as a hydrate gas production technique. A hydraulic fracturing technique suitable for hydrate reservoirs and a system for coring hydrate reservoirs are also described.

  1. Development and analytical validation of a gas chromatography-mass spectrometry method for the assessment of gastrointestinal permeability and intestinal absorptive capacity in dogs

    E-Print Network [OSTI]

    Rodriguez Frausto, Heriberto

    2009-05-15T23:59:59.000Z

    , xylose (X) and 3-O-methylglucose (M) for the evaluation of intestinal absorptive capacity, and sucrose (S) for the assessment of gastric permeability. Traditionally, various methods have been used to quantify these markers in the urine after orogastric...

  2. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09T23:59:59.000Z

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  3. NATURAL GAS MARKET ASSESSMENT

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

  4. Simultaneous Measurement of Tracer and Interdiffusion Coefficients: An Isotopic Phenomenological Diffusion Formalism for the Binary Alloy

    SciTech Connect (OSTI)

    Belova, Irina [University of Newcastle, NSW, Australia; Kulkarni, Nagraj S [ORNL; Sohn, Yong Ho [University of Central Florida; Murch, Prof. Graeme [University of Newcastle, NSW, Australia

    2013-01-01T23:59:59.000Z

    In this paper, a new development of the classic Onsager phenomenological formalism is derived using relations based on linear response theory. The development concerns the correct description of the fluxes of the atomic isotopes. The resulting expressions in the laboratory frame are surprisingly simple and consist of terms coming from the standard interdiffusion expressions and from Fick s first law where the tracer diffusion coefficient is involved thus providing a better understanding of the relationship between the two approaches - Fick s first law and the Onsager phenomenological formalism. From an experimental application perspective, the new development is applied to the binary alloy case. The formalism provides the means to obtain the interdiffusion coefficient and tracer diffusion coefficients simultaneously from analysis of the interdiffusion concentration profiles in a single experiment.

  5. Gas turbine premixing systems

    DOE Patents [OSTI]

    Kraemer, Gilbert Otto; Varatharajan, Balachandar; Evulet, Andrei Tristan; Yilmaz, Ertan; Lacy, Benjamin Paul

    2013-12-31T23:59:59.000Z

    Methods and systems are provided for premixing combustion fuel and air within gas turbines. In one embodiment, a combustor includes an upstream mixing panel configured to direct compressed air and combustion fuel through premixing zone to form a fuel-air mixture. The combustor includes a downstream mixing panel configured to mix additional combustion fuel with the fule-air mixture to form a combustion mixture.

  6. Inversion of field-scale partitioning tracer response for characterizing oil saturation distribution: a streamline approach

    E-Print Network [OSTI]

    Iliassov, Pavel Alexandrovich

    2000-01-01T23:59:59.000Z

    INVERSION OF FIELD-SCALE PARTITIONING TRACER RESPONSE FOR CHARACTERIZING OIL SATURATION DISTRIBUTION: A STREAMLINE APPROACH A Thesis by PAVEL ALEXANDROVICH ILIASSOV Submitted to the Office of Graduate Studies of Texas A&M University... A Thesis by PAVEL ALEXANDROVICH ILIASSOV Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved as to style and content by: c 4- Akhil Datta-Gupta (Chair of Committee...

  7. ELIXYS - a fully automated, three-reactor high-pressure radiosynthesizer for development and routine production of diverse PET tracers.

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    cancer treatment with PET/CT: does it make a difference? Jfor decentralized production of PET tracers. In Positronprobes FMAU, FHBG, and FHPG as PET imaging agents for HSV1-

  8. Thorium-234 as a tracer of spatial, temporal and vertical variability in particle flux in the North Pacific

    E-Print Network [OSTI]

    Siegel, David A.

    Thorium-234 as a tracer of spatial, temporal and vertical variability in particle flux in the North Available online 16 April 2009 Keywords: Thorium-234 Particle flux Sediment trap Scavenging North Pacific

  9. Integrated Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. This objective of this project is to develop an innovative approach to estimate fracture surface area and spacing through interpretation of signals of natural chemical and isotopic tracers.

  10. Interpreting Energy and Tracer Spectra of Upper-Ocean Turbulence in the Submesoscale Range (1–200 km)

    E-Print Network [OSTI]

    Ferrari, Raffaele

    Submesoscale (1–200 km) wavenumber spectra of kinetic and potential energy and tracer variance are obtained from in situ observations in the Gulf Stream region and in the eastern subtropical North Pacific. In the Gulf ...

  11. Field studies of streamflow generation using natural and injected tracers on Bickford and Walker Branch Watersheds

    SciTech Connect (OSTI)

    Genereux, D.; Hemond, H. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Civil Engineering; Mulholland, P. [Oak Ridge National Lab., TN (United States)

    1992-05-01T23:59:59.000Z

    Field studies of streamflow generation were undertaken on two forested watersheds, the West Road subcatchment of Bickford Watershed in central Massachusetts and the West Fork of Walker Branch Watershed in eastern Tennessee. A major component of the research was development of a two-stage methodology for the use of naturally-occurring {sup 222}Rn as a tracer. The first of the two stages was solving a mass-balance equation for {sup 222}Rn around a stream reach of interest in order to calculate Rn{sub q}, the {sup 222}Rn content of the lateral inflow to the reach; a conservative tracer (chloride) and a volatile tracer (propane) were injected into the study stream to account for lateral inflow to, and volatilization from, the study reach. The second stage involved quantitative comparison of Rn{sub q} to the measured {sup 222}Rn concentrations of different subsurface waters in order to assess how important these waters were in contributing lateral inflow to the stream reach.

  12. Filtering a statistically exactly solvable test model for turbulent tracers from partial observations

    SciTech Connect (OSTI)

    Gershgorin, B., E-mail: borisg@cims.nyu.ed [Department of Mathematics and Center for Atmosphere and Ocean Science, Courant Institute of Mathematical Sciences, New York University, NY 10012 (United States); Majda, A.J. [Department of Mathematics and Center for Atmosphere and Ocean Science, Courant Institute of Mathematical Sciences, New York University, NY 10012 (United States)

    2011-02-20T23:59:59.000Z

    A statistically exactly solvable model for passive tracers is introduced as a test model for the authors' Nonlinear Extended Kalman Filter (NEKF) as well as other filtering algorithms. The model involves a Gaussian velocity field and a passive tracer governed by the advection-diffusion equation with an imposed mean gradient. The model has direct relevance to engineering problems such as the spread of pollutants in the air or contaminants in the water as well as climate change problems concerning the transport of greenhouse gases such as carbon dioxide with strongly intermittent probability distributions consistent with the actual observations of the atmosphere. One of the attractive properties of the model is the existence of the exact statistical solution. In particular, this unique feature of the model provides an opportunity to design and test fast and efficient algorithms for real-time data assimilation based on rigorous mathematical theory for a turbulence model problem with many active spatiotemporal scales. Here, we extensively study the performance of the NEKF which uses the exact first and second order nonlinear statistics without any approximations due to linearization. The role of partial and sparse observations, the frequency of observations and the observation noise strength in recovering the true signal, its spectrum, and fat tail probability distribution are the central issues discussed here. The results of our study provide useful guidelines for filtering realistic turbulent systems with passive tracers through partial observations.

  13. Tracer measurements during long-term circulation of the Rosemanowes HDR geothermal system

    SciTech Connect (OSTI)

    Kwakwa, K.A.

    1988-01-01T23:59:59.000Z

    Circulation experiments have been in operation for over two years in the artificially stimulated hot dry rock (HDR) doublet of the Camborne School of Mines (CSM) research facility in Cornwall, England. During that period tracer tests have been run at intervals using inert and reactive compounds. Initially, the results of the inert tracer investigations showed that the active volume (indicated by modal and median volumes) of the circulating system was dormant. Then, after a period of sustained oscillation, notable increases in active volume were observed which depended on both the subsequent flow rate changes and circulation time. these dynamic changes had almost reached optimum values when a downhole pump was introduced in the production well. The drawdown in the production well caused a reduction of the modal volume, whilst the median volume remained almost the same. Since then, the active volume has remained unchanged and irresponsive to circulation time and flow rate. The results of the reactive tracer tests confirm increasing chemical reaction with increasing circulation time and correlate qualitatively with the opening of newer and hotter pathways within the reservoir. However, repeated production logs throughout the circulation have identified flow paths that have depleted thermally; a discrepancy that can be explained by the geometry of the system and the preferential downward reservoir growth.

  14. Semianalytical Solutions of Radioactive or Reactive Tracer Transport in Layered Fractured Media

    SciTech Connect (OSTI)

    G.J. Moridis; G. S. Bodvarsson

    2001-10-01T23:59:59.000Z

    In this paper, semianalytical solutions are developed for the problem of transport of radioactive or reactive tracers (solutes or colloids) through a layered system of heterogeneous fractured media with misaligned fractures. The tracer transport equations in the matrix account for (a) diffusion, (b) surface diffusion (for solutes only), (c) mass transfer between the mobile and immobile water fractions, (d) linear kinetic or equilibrium physical, chemical, or combined solute sorption or colloid filtration, and (e) radioactive decay or first order chemical reactions. Any number of radioactive decay daughter products (or products of a linear, first-order reaction chain) can be tracked. The tracer-transport equations in the fractures account for the same processes, in addition to advection and hydrodynamic dispersion. Additionally, the colloid transport equations account for straining and velocity adjustments related to the colloidal size. The solutions, which are analytical in the Laplace space, are numerically inverted to provide the solution in time and can accommodate any number of fractured and/or porous layers. The solutions are verified using analytical solutions for limiting cases of solute and colloid transport through fractured and porous media. The effect of important parameters on the transport of {sup 3}H, {sup 237}Np and {sup 239}Pu (and its daughters) is investigated in several test problems involving layered geological systems of varying complexity. {sup 239}Pu colloid transport problems in multilayered systems indicate significant colloid accumulations at straining interfaces but much faster transport of the colloid than the corresponding strongly sorbing solute species.

  15. ALPHA SPECTROMETRIC EVALUATION OF SRM-995 AS A POTENTIAL URANIUM/THORIUM DOUBLE TRACER SYSTEM FOR AGE-DATING URANIUM MATERIALS

    SciTech Connect (OSTI)

    Beals, D.

    2011-12-06T23:59:59.000Z

    Uranium-233 (t{sub 1/2} {approx} 1.59E5 years) is an artificial, fissile isotope of uranium that has significant importance in nuclear forensics. The isotope provides a unique signature in determining the origin and provenance of uranium-bearing materials and is valuable as a mass spectrometric tracer. Alpha spectrometry was employed in the critical evaluation of a {sup 233}U standard reference material (SRM-995) as a dual tracer system based on the in-growth of {sup 229}Th (t{sub 1/2} {approx} 7.34E3 years) for {approx}35 years following radiochemical purification. Preliminary investigations focused on the isotopic analysis of standards and unmodified fractions of SRM-995; all samples were separated and purified using a multi-column anion-exchange scheme. The {sup 229}Th/{sup 233}U atom ratio for SRM-995 was found to be 1.598E-4 ({+-} 4.50%) using recovery-corrected radiochemical methods. Using the Bateman equations and relevant half-lives, this ratio reflects a material that was purified {approx} 36.8 years prior to this analysis. The calculated age is discussed in contrast with both the date of certification and the recorded date of last purification.

  16. Georgia Tech Dangerous Gas

    E-Print Network [OSTI]

    Sherrill, David

    1 Georgia Tech Dangerous Gas Safety Program March 2011 #12;Georgia Tech Dangerous Gas Safety.......................................................................................................... 5 6. DANGEROUS GAS USAGE REQUIREMENTS................................................. 7 6.1. RESTRICTED PURCHASE/ACQUISITION RULES: ................................................ 7 7. FLAMMABLE GAS

  17. Neural net controlled tag gas sampling system for nuclear reactors

    DOE Patents [OSTI]

    Gross, Kenneth C. (Bolingbrook, IL); Laug, Matthew T. (Idaho Fall, ID); Lambert, John D. B. (Wheaton, IL); Herzog, James P. (Downers Grove, IL)

    1997-01-01T23:59:59.000Z

    A method and system for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod.

  18. Neural net controlled tag gas sampling system for nuclear reactors

    DOE Patents [OSTI]

    Gross, K.C.; Laug, M.T.; Lambert, J.B.; Herzog, J.P.

    1997-02-11T23:59:59.000Z

    A method and system are disclosed for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod. 12 figs.

  19. On-line gas chromatographic analysis of airborne particles

    DOE Patents [OSTI]

    Hering, Susanne V. (Berkeley, CA); Goldstein, Allen H. (Orinda, CA)

    2012-01-03T23:59:59.000Z

    A method and apparatus for the in-situ, chemical analysis of an aerosol. The method may include the steps of: collecting an aerosol; thermally desorbing the aerosol into a carrier gas to provide desorbed aerosol material; transporting the desorbed aerosol material onto the head of a gas chromatography column; analyzing the aerosol material using a gas chromatograph, and quantizing the aerosol material as it evolves from the gas chromatography column. The apparatus includes a collection and thermal desorption cell, a gas chromatograph including a gas chromatography column, heated transport lines coupling the cell and the column; and a quantization detector for aerosol material evolving from the gas chromatography column.

  20. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida (Katy, TX); Del Paggio, Alan Anthony (Spring, TX); Nair, Vijay (Katy, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX)

    2011-12-06T23:59:59.000Z

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.