National Library of Energy BETA

Sample records for tracer gas methods

  1. Preliminary Investigation of Tracer Gas Reaeration Method for Shallow Bays 

    E-Print Network [OSTI]

    Baker, Sarah H.; Holley, Edward R.

    1987-01-01

    Accurate estimates of surface exchange rates for volatile pollutants in bays are needed to allow predictions of pollutant movement and retention time. The same types of estimates can be used to calculate reaeration rates. The tracer gas technique...

  2. Development of Atmospheric Tracer Methods To Measure Methane Emissions from Natural Gas Facilities and Urban Areas

    E-Print Network [OSTI]

    1995-01-01

    an urban area is used with crosswind integrated tracerCWI,) and the average crosswind concen- tration of methane (directly, and the crosswind average methane concentration

  3. A Modified Tracer-Gas-Concentration Decay Method for Ventilation Rate Measurements in Large, Long, and Narrow Spaces

    E-Print Network [OSTI]

    Chen, Qingyan "Yan"

    obtained by the CO2-concentration decay method. However, this method requires a large amount of tracer method for ventilation rate measurements in large, long, and narrow spaces," Indoor and Built Environment

  4. Development of Atmospheric Tracer Methods To Measure Methane Emissions from Natural Gas Facilities and Urban Areas

    E-Print Network [OSTI]

    1995-01-01

    to coal and 30% less compared to fuel oil, switching fromcoal and fuel oil to natural gas has the potential to reducehydrocarbon emissions from an oil refinery wastewater

  5. Tracer Methods for Characterizing Fracture Stimulation in Enhanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tracer Methods for Characterizing Fracture Stimulation in Enhanced Geothermal Systems (EGS); 2010 Geothermal Technology Program Peer Review Report Tracer Methods for Characterizing...

  6. Tracer Methods for Characterizing Fracture Creation in Enhanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal Systems; 2010 Geothermal Technology Program Peer Review Report Tracer Methods for Characterizing Fracture...

  7. Validation of Geothermal Tracer Methods in Highly Constrained...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs Fracture Evolution Following a Hydraulic Stimulation within an EGS Reservoir...

  8. Methods and systems using encapsulated tracers and chemicals for reservoir interrogation and manipulation

    DOE Patents [OSTI]

    Roberts, Jeffery; Aines, Roger D; Duoss, Eric B; Spadaccini, Christopher M

    2014-11-04

    An apparatus, method, and system of reservoir interrogation. A tracer is encapsulating in a receptacle. The receptacle containing the tracer is injected into the reservoir. The tracer is analyzed for reservoir interrogation.

  9. Appraisal of transport and deformation in shale reservoirs using natural noble gas tracers

    SciTech Connect (OSTI)

    Heath, Jason E.; Kuhlman, Kristopher L.; Robinson, David G.; Bauer, Stephen J.; Gardner, William Payton

    2015-09-01

    This report presents efforts to develop the use of in situ naturally-occurring noble gas tracers to evaluate transport mechanisms and deformation in shale hydrocarbon reservoirs. Noble gases are promising as shale reservoir diagnostic tools due to their sensitivity of transport to: shale pore structure; phase partitioning between groundwater, liquid, and gaseous hydrocarbons; and deformation from hydraulic fracturing. Approximately 1.5-year time-series of wellhead fluid samples were collected from two hydraulically-fractured wells. The noble gas compositions and isotopes suggest a strong signature of atmospheric contribution to the noble gases that mix with deep, old reservoir fluids. Complex mixing and transport of fracturing fluid and reservoir fluids occurs during production. Real-time laboratory measurements were performed on triaxially-deforming shale samples to link deformation behavior, transport, and gas tracer signatures. Finally, we present improved methods for production forecasts that borrow statistical strength from production data of nearby wells to reduce uncertainty in the forecasts.

  10. Advancing Reactive Tracer Methods for Measuring Thermal Evolution...

    Open Energy Info (EERE)

    and Tracer Interpretation Project Description The concepts and theory behind the use of heat-sensitive tracers to study the thermal evolution of geothermal reservoirs was...

  11. Validation of Geothermal Tracer Methods in Highly Constrained Field Experiments

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Project Summary. This project will test smartdiffusive tracers for measuring heat exchange.

  12. New Tracers Identify Hydraulic Fracturing Fluids and Accidental Releases from Oil and Gas Operations

    E-Print Network [OSTI]

    Jackson, Robert B.

    New Tracers Identify Hydraulic Fracturing Fluids and Accidental Releases from Oil and Gas produced waters sampled from conventional oil and gas wells. We posit that boron isotope geochemistry can tool is validated by examining the composition of effluent discharge from an oil and gas brine

  13. Verification of Geothermal Tracer Methods in Highly Constrained...

    Open Energy Info (EERE)

    wells, much of the reservoir is left untapped. Artificial tracers added to the injected water are used to estimate the potential for short circuiting in geothermal reservoirs,...

  14. Seasonal Variation in Monthly Average Air Change Rates Using Passive Tracer Gas Measurements

    E-Print Network [OSTI]

    Hansen, René Rydhof

    of indoor air pollution sources. Concurrently, great efforts are made to make buildings energy efficient 1970s, while less attention has been paid to IAQ. Insufficient venting of indoor air pollutantsSeasonal Variation in Monthly Average Air Change Rates Using Passive Tracer Gas Measurements Marie

  15. Tracer Gas as a Practical Field Diagnostic Tool for Assessing Duct System Leaks 

    E-Print Network [OSTI]

    Cummings, J. B.

    1989-01-01

    diagnostic tools for detecting and locating leaks in the air distribution system. The tracer gas tests described are a good complement to these tools in the detection, location, and measurement of duct leakage. Testing for house infiltration once with the air...

  16. Analysis of volatile phase transport in soils using natural radon gas as a tracer

    SciTech Connect (OSTI)

    Chen, C.; Thomas, D.M.

    1992-12-31

    We have conducted a field study of soil gas transport processes using radon gas as a naturally occurring tracer. The .experiment monitored soil gas radon activity, soil moisture, and soil temperature at three depths in the shallow soil column; barometric pressure, rainfall and wind speed were monitored at the soil surface. Linear and multiple regression analysis of the data sets has shown that the gas phase radon activities under natural environmental conditions are influenced by soil moisture content, barometric pressure variations, soil temperature and soil structure. The effect of wind speed on subsurface radon activities under our field conditions has not been demonstrated.

  17. Analysis of volatile phase transport in soils using natural radon gas as a tracer

    SciTech Connect (OSTI)

    Chen, C.; Thomas, D.M.

    1992-01-01

    We have conducted a field study of soil gas transport processes using radon gas as a naturally occurring tracer. The .experiment monitored soil gas radon activity, soil moisture, and soil temperature at three depths in the shallow soil column; barometric pressure, rainfall and wind speed were monitored at the soil surface. Linear and multiple regression analysis of the data sets has shown that the gas phase radon activities under natural environmental conditions are influenced by soil moisture content, barometric pressure variations, soil temperature and soil structure. The effect of wind speed on subsurface radon activities under our field conditions has not been demonstrated.

  18. THE NEW YORK CITY URBAN DISPERSION PROGRAM MARCH 2005 FIELD STUDY: TRACER METHODS AND RESULTS.

    SciTech Connect (OSTI)

    WATSON, T.B.; HEISER, J.; KALB, P.; DIETZ, R.N.; WILKE, R.; WIESER, R.; VIGNATO, G.

    2005-10-01

    The Urban Dispersion Program March 2005 Field Study tracer releases, sampling, and analytical methods are described in detail. There were two days where tracer releases and sampling were conducted. A total of 16.0 g of six tracers were released during the first test day or Intensive Observation Period (IOP) 1 and 15.7 g during IOP 2. Three types of sampling instruments were used in this study. Sequential air samplers, or SAS, collected six-minute samples, while Brookhaven atmospheric tracer samplers (BATS) and personal air samplers (PAS) collected thirty-minute samples. There were a total of 1300 samples resulting from the two IOPs. Confidence limits in the sampling and analysis method were 20% as determined from 100 duplicate samples. The sample recovery rate was 84%. The integrally averaged 6-minute samples were compared to the 30-minute samples. The agreement was found to be good in most cases. The validity of using a background tracer to calculate sample volumes was examined and also found to have a confidence level of 20%. Methods for improving sampling and analysis are discussed. The data described in this report are available as Excel files. An additional Excel file of quality assured tracer data for use in model validation efforts is also available. The file consists of extensively quality assured BATS tracer data with background concentrations subtracted.

  19. Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. This project aims to develop reactive tracer method for monitoring thermal drawdown in enhanced geothermal systems.

  20. ADVANCING REACTIVE TRACER METHODS FOR MONITORING THERMAL DRAWDOWN IN GEOTHERMAL ENHANCED GEOTHERMAL RESERVOIRS

    SciTech Connect (OSTI)

    Mitchell A. Plummer; Carl D. Palmer; Earl D. Mattson; George D. Redden; Laurence C. Hull

    2010-10-01

    Reactive tracers have long been considered a possible means of measuring thermal drawdown in a geothermal system, before significant cooling occurs at the extraction well. Here, we examine the sensitivity of the proposed method to evaluate reservoir cooling and demonstrate that while the sensitivity of the method as generally proposed is low, it may be practical under certain conditions.

  1. Recover Act. Verification of Geothermal Tracer Methods in Highly Constrained Field Experiments

    SciTech Connect (OSTI)

    Becker, Matthew W.

    2014-05-16

    The prediction of the geothermal system efficiency is strong linked to the character of the flow system that connects injector and producer wells. If water flow develops channels or “short circuiting” between injection and extraction wells thermal sweep is poor and much of the reservoir is left untapped. The purpose of this project was to understand how channelized flow develops in fracture geothermal reservoirs and how it can be measured in the field. We explored two methods of assessing channelization: hydraulic connectivity tests and tracer tests. These methods were tested at a field site using two verification methods: ground penetrating radar (GPR) images of saline tracer and heat transfer measurements using distributed temperature sensing (DTS). The field site for these studies was the Altona Flat Fractured Rock Research Site located in northeastern New York State. Altona Flat Rock is an experimental site considered a geologic analog for some geothermal reservoirs given its low matrix porosity. Because soil overburden is thin, it provided unique access to saturated bedrock fractures and the ability image using GPR which does not effectively penetrate most soils. Five boreholes were drilled in a “five spot” pattern covering 100 m2 and hydraulically isolated in a single bedding plane fracture. This simple system allowed a complete characterization of the fracture. Nine small diameter boreholes were drilled from the surface to just above the fracture to allow the measurement of heat transfer between the fracture and the rock matrix. The focus of the hydraulic investigation was periodic hydraulic testing. In such tests, rather than pumping or injection in a well at a constant rate, flow is varied to produce an oscillating pressure signal. This pressure signal is sensed in other wells and the attenuation and phase lag between the source and receptor is an indication of hydraulic connection. We found that these tests were much more effective than constant pumping tests in identifying a poorly connected well. As a result, we were able to predict which well pairs would demonstrate channelized flow. The focus of the tracer investigation was multi-ionic tests. In multi-ionic tests several ionic tracers are injected simultaneously and the detected in a nearby pumping well. The time history of concentration, or breakthrough curve, will show a separation of the tracers. Anionic tracers travel with the water but cationic tracer undergo chemical exchange with cations on the surface of the rock. The degree of separation is indicative of the surface area exposed to the tracer. Consequently, flow channelization will tend to decrease the separation in the breakthrough. Estimation of specific surface area (the ration of fracture surface area to formation volume) is performed through matching the breakthrough curve with a transport model. We found that the tracer estimates of surface area were confirmed the prediction of channelized flow between well pairs produced by the periodic hydraulic tests. To confirm that the hydraulic and tracer tests were correctly predicting channelize flow, we imaged the flow field using surface GPR. Saline water was injected between the well pairs which produced a change in the amplitude and phase of the reflected radar signal. A map was produced of the migration of saline tracer from these tests which qualitatively confirmed the flow channelization predicted by the hydraulic and tracer tests. The resolution of the GPR was insufficient to quantitatively estimate swept surface area, however. Surface GPR is not applicable in typical geothermal fields because the penetration depths do not exceed 10’s of meters. Nevertheless, the method of using of phase to measure electrical conductivity and the assessment of antennae polarization represent a significant advancement in the field of surface GPR. The effect of flow character on fracture / rock thermal exchange was evaluated using heated water as a tracer. Water elevated 30 degrees C above the formation water was circulated between two wells pairs. One

  2. Preferred methods of analysis for chemical tracers in moderate...

    Open Energy Info (EERE)

    and sample preservation techniques, analytical methods and possible sources of contamination or error are discussed in detail. Authors Kroneman, R. L.; Yorgason, K. R.; Moore...

  3. Perfluorocarbon tracer method for air-infiltration measurements

    DOE Patents [OSTI]

    Dietz, R.N.

    1982-09-23

    A method of measuring air infiltration rates suitable for use in rooms of homes and buildings comprises the steps of emitting perfluorocarbons in the room to be measured, sampling the air containing the emitted perfluorocarbons over a period of time, and analyzing the samples at a laboratory or other facility.

  4. Tracer airflow measurement system (TRAMS)

    DOE Patents [OSTI]

    Wang, Duo (Albany, CA)

    2007-04-24

    A method and apparatus for measuring fluid flow in a duct is disclosed. The invention uses a novel high velocity tracer injector system, an optional insertable folding mixing fan for homogenizing the tracer within the duct bulk fluid flow, and a perforated hose sampling system. A preferred embodiment uses CO.sub.2 as a tracer gas for measuring air flow in commercial and/or residential ducts. In extant commercial buildings, ducts not readily accessible by hanging ceilings may be drilled with readily plugged small diameter holes to allow for injection, optional mixing where desired using a novel insertable foldable mixing fan, and sampling hose.

  5. Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS)

    Broader source: Energy.gov [DOE]

    Project objectives: identify tracers with sorption properties favorable for EGS applications; apply reversibly sorbing tracers to determine the fracture-matrix interface area available for heat transfer; and; explore the feasibility of obtaining fracture-matrix interface area from non-isothermal; single-well injection-withdrawal (SWIW) tests.

  6. Tracer Detection by Laser Spectroscopy for Applications in the Oil and Gas R. Nava, Texas A&M University, H. Schuessler, M. Fahes and H. Nasrabadi, Texas A&M University at Qatar, and

    E-Print Network [OSTI]

    Schuessler, Hans

    SPE 124689 Tracer Detection by Laser Spectroscopy for Applications in the Oil and Gas Industry R and more accurate option for applications in the oil and gas industry. The research work is currently being applications in the oil and gas industry. Chemical or radioactive tracers are used to label fluids from

  7. Pre-fire warning system and method using a perfluorocarbon tracer

    DOE Patents [OSTI]

    Dietz, Russell N. (Patchogue, NY); Senum, Gunnar I. (Patchogue, NY)

    1994-01-01

    A composition and method for detecting thermal overheating of an apparatus or system and for quickly and accurately locating the portions of the apparatus or system that experience a predetermined degree of such overheating. A composition made according to the invention includes perfluorocarbon tracers (PFTs) mixed with certain non-reactive carrier compounds that are effective to trap or block the PFTs within the composition at normal room temperature or at normal operating temperature of the coated apparatus or system. When a predetermined degree of overheating occurs in any of the coated components of the apparatus or system, PFTs are emitted from the compositions at a rate corresponding to the degree of overheating of the component. An associated PFT detector (or detectors) is provided and monitored to quickly identify the type of PFTs emitted so that the PFTs can be correlated with the respective PFT in the coating compositions applied on respective components in the system, thereby to quickly and accurately localize the source of the overheating of such components.

  8. Pre-fire warning system and method using a perfluorocarbon tracer

    DOE Patents [OSTI]

    Dietz, R.N.; Senum, G.I.

    1994-11-08

    A composition and method are disclosed for detecting thermal overheating of an apparatus or system and for quickly and accurately locating the portions of the apparatus or system that experience a predetermined degree of such overheating. A composition made according to the invention includes perfluorocarbon tracers (PFTs) mixed with certain non-reactive carrier compounds that are effective to trap or block the PFTs within the composition at normal room temperature or at normal operating temperature of the coated apparatus or system. When a predetermined degree of overheating occurs in any of the coated components of the apparatus or system, PFTs are emitted from the compositions at a rate corresponding to the degree of overheating of the component. An associated PFT detector (or detectors) is provided and monitored to quickly identify the type of PFTs emitted so that the PFTs can be correlated with the respective PFT in the coating compositions applied on respective components in the system, thereby to quickly and accurately localize the source of the overheating of such components. 4 figs.

  9. Method for hot gas conditioning

    DOE Patents [OSTI]

    Paisley, Mark A. (Upper Arlington, OH)

    1996-02-27

    A method for cracking and shifting a synthesis gas by the steps of providing a catalyst consisting essentially of alumina in a reaction zone; contacting the catalyst with a substantially oxygen free mixture of gases comprising water vapor and hydrocarbons having one or more carbon atoms, at a temperature between about 530.degree. C. (1000.degree. F.) to about 980.degree. C. (1800.degree. F.); and whereby the hydrocarbons are cracked to form hydrogen, carbon monoxide and/or carbon dioxide and the hydrogen content of the mixture increases with a corresponding decrease in carbon monoxide, and carbon formation is substantially eliminated.

  10. Method for hot gas conditioning

    SciTech Connect (OSTI)

    Paisley, M.A.

    1996-02-27

    A method is described for cracking and shifting a synthesis gas by the steps of providing a catalyst consisting essentially of alumina in a reaction zone; contacting the catalyst with a substantially oxygen free mixture of gases comprising water vapor and hydrocarbons having one or more carbon atoms, at a temperature between about 530 C (1000 F) to about 980 C (1800 F); and whereby the hydrocarbons are cracked to form hydrogen, carbon monoxide and/or carbon dioxide and the hydrogen content of the mixture increases with a corresponding decrease in carbon monoxide, and carbon formation is substantially eliminated. 3 figs.

  11. Reducing gas generators and methods for generating a reducing gas

    SciTech Connect (OSTI)

    Scotto, Mark Vincent; Perna, Mark Anthony

    2015-11-03

    One embodiment of the present invention is a unique reducing gas generator. Another embodiment is a unique method for generating a reducing gas. Other embodiments include apparatuses, systems, devices, hardware, methods, and combinations for generating reducing gas. Further embodiments, forms, features, aspects, benefits, and advantages of the present application will become apparent from the description and figures provided herewith.

  12. Quantifying Reaeration Rates in Alpine Streams Using Deliberate Gas Tracer Experiments

    E-Print Network [OSTI]

    2014-01-01

    reaeration rates. Int. J. Air Water Pollut. 1962, 6, 467–studies in streams. Int. J. Air Water Pollut. 30. Bennett,Multiplicative Error. In: Air-Water Gas Transfer; Jähne,

  13. Gas cleaning system and method

    DOE Patents [OSTI]

    Newby, Richard Allen

    2006-06-06

    A gas cleaning system for removing at least a portion of contaminants, such as halides, sulfur, particulates, mercury, and others, from a synthesis gas (syngas). The gas cleaning system may include one or more filter vessels coupled in series for removing halides, particulates, and sulfur from the syngas. The gas cleaning system may be operated by receiving gas at a first temperature and pressure and dropping the temperature of the syngas as the gas flows through the system. The gas cleaning system may be used for an application requiring clean syngas, such as, but not limited to, fuel cell power generation, IGCC power generation, and chemical synthesis.

  14. Synthesis gas method and apparatus

    DOE Patents [OSTI]

    Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie R.; Kosowski, Lawrence W.; Robinson, Charles

    2013-01-08

    A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube.

  15. Formaldehyde as a Tracer of Extragalactic Molecular Gas I. Para-H_2CO Emission From M 82

    E-Print Network [OSTI]

    Mühle, S; Henkel, C

    2007-01-01

    Using the IRAM 30-m telescope and the 15-m JCMT, we explore the value of para-formaldehyde (p-H_2CO) as a tracer of density and temperature of the molecular gas in external galaxies. The target of our observations are the lobes of the molecular ring around the center of the nearby prototypical starburst galaxy M 82. It is shown that p-H_2CO provides one of the rare direct molecular thermometers. Reproducing the measured line intensities with a large velocity gradient (LVG) model, we find densities of n_H2 ~ 7 10^3 cm^-3 and kinetic temperatures of T_kin ~ 200 K. The derived kinetic temperature is significantly higher than the dust temperature or the temperature deduced from ammonia (NH_3) lines, but our results agree well with the properties of the high-excitation component seen in CO. We also present the serendipitous discovery of the 4_2 - 3_1 line of methanol (CH_3OH) in the northeastern lobe, which shows -- unlike CO and H_2CO -- significantly different line intensities in the two lobes.

  16. Formaldehyde as a Tracer of Extragalactic Molecular Gas I. Para-H_2CO Emission From M 82

    E-Print Network [OSTI]

    S. Mühle; E. R. Seaquist; C. Henkel

    2007-08-13

    Using the IRAM 30-m telescope and the 15-m JCMT, we explore the value of para-formaldehyde (p-H_2CO) as a tracer of density and temperature of the molecular gas in external galaxies. The target of our observations are the lobes of the molecular ring around the center of the nearby prototypical starburst galaxy M 82. It is shown that p-H_2CO provides one of the rare direct molecular thermometers. Reproducing the measured line intensities with a large velocity gradient (LVG) model, we find densities of n_H2 ~ 7 10^3 cm^-3 and kinetic temperatures of T_kin ~ 200 K. The derived kinetic temperature is significantly higher than the dust temperature or the temperature deduced from ammonia (NH_3) lines, but our results agree well with the properties of the high-excitation component seen in CO. We also present the serendipitous discovery of the 4_2 - 3_1 line of methanol (CH_3OH) in the northeastern lobe, which shows -- unlike CO and H_2CO -- significantly different line intensities in the two lobes.

  17. Detection of high molecular weight organic tracers in vegetation smoke samples by high-temperature gas chromatography-mass spectrometry

    SciTech Connect (OSTI)

    Elias, V.O.; Simoneit, B.R.T. ); Pereira, A.S.; Cardoso, J.N. ); Cabral, J.A. )

    1999-07-15

    High-temperature high-resolution gas chromatography (HTGC) is an established technique for the separation of complex mixtures of high molecular weight (HMW) compounds which do not elute when analyzed on conventional GC columns. The combination of this technique with mass spectrometry is not so common and application to aerosols is novel. The HTGC and HTGC-MS analyses of smoke samples taken by particle filtration from combustion of different species of plants provided the characterization of various classes of HMW compounds reported to occur for the first time in emissions from biomass burning. Among these components are a series of wax esters with up to 58 carbon numbers, aliphatic hydrocarbons, triglycerides, long chain methyl ketones, alkanols and a series of triterpenyl fatty acid esters which have been characterized as novel natural products. Long chain fatty acids with more than 32 carbon numbers are not present in the smoke samples analyzed. The HMW compounds in smoke samples from the burning of plants from Amazonia indicate the input of directly volatilized natural products in the original plants during their combustion. However, the major organic compounds extracted from smoke consist of a series of lower molecular weight polar components, which are not natural products but the result of the thermal breakdown of cellulose and lignin. In contrast, the HMW natural products may be suitable tracers for specific sources of vegetation combustion because they are emitted as particles without thermal alternation in the smoke and can thus be related directly to the original plant material.

  18. In Situ Tracer method for establishing the presence and predicting the activity of heavy metal-reducing microbes in the subsurface. Final Report

    SciTech Connect (OSTI)

    Hatfield, K.

    2003-07-01

    Tracer method to establish presence and distribution of chromium reducing microbes. The primary objective of this research was to establish an in situ tracer method for detecting the presence. distribution. and activity of subsurface heavy metal-reducing microorganisms. Research focused on microbial systems responsible for the reduction of chromium and a suite of biotracers coupled to the reduction process. The tracer method developed may be used to characterize sites contaminated with chromium or expedite bioremediation: and although research focused on chromium. the method can be easily extended to other metals, organics, and radionuclides. This brief final report contains three major sections. The first identifies specific products of the research effort such as students supported and publications. The second section briefly presents major research findings, while the last section summarizes the overall research effort.

  19. Innovative techniques for the description of reservoir heterogeneity using tracers. Second technical annual progress report, October 1991--September 1992

    SciTech Connect (OSTI)

    Pope, G.A.; Sepehrnoori, K.

    1992-12-31

    This second annual report on innovative uses of tracers for reservoir characterization contains four sections each describing a novel use of oilfield tracers. The first section describes and illustrates the use of a new single-well tracer test to estimate wettability. This test consists of the injection of brine containing tracers followed by oil containing tracers, a shut-in period to allow some of the tracers to react, and then production of the tracers. The inclusion of the oil injection slug with tracers is unique to this test, and this is what makes the test work. We adapted our chemical simulator, UTCHEM, to enable us to study this tracer method and made an extensive simulation study to evaluate the effects of wettability based upon characteristic curves for relative permeability and capillary pressure for differing wetting states typical of oil reservoirs. The second section of this report describes a new method for analyzing interwell tracer data based upon a type-curve approach. Theoretical frequency response functions were used to build type curves of ``transfer function`` and ``phase spectrum`` that have dimensionless heterogeneity index as a parameter to characterize a stochastic permeability field. We illustrate this method by analyzing field tracer data. The third section of this report describes a new theory for interpreting interwell tracer data in terms of channeling and dispersive behavior for reservoirs. Once again, a stochastic approach to reservoir description is taken. The fourth section of this report describes our simulation of perfluorocarbon gas tracers. This new tracer technology developed at Brookhaven National Laboratory is being tested at the Elk Hills Naval Petroleum Reserve No. 1 in California. We report preliminary simulations made of these tracers in one of the oil reservoirs under evaluation with these tracers in this field. Our compostional simulator (UTCOMP) was used for this simulation study.

  20. Novel Multidimensional Tracers for Geothermal Inter-Well Diagnostics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Tracers to Characterize Fractures in Engineered Geothermal Systems Advancing reactive tracer methods for measuring thermal evolution in CO2-and water-based geothermal reservoirs...

  1. Method for detecting gas turbine engine flashback

    DOE Patents [OSTI]

    Singh, Kapil Kumar; Varatharajan, Balachandar; Kraemer, Gilbert Otto; Yilmaz, Ertan; Lacy, Benjamin Paul

    2012-09-04

    A method for monitoring and controlling a gas turbine, comprises predicting frequencies of combustion dynamics in a combustor using operating conditions of a gas turbine, receiving a signal from a sensor that is indicative of combustion dynamics in the combustor, and detecting a flashback if a frequency of the received signal does not correspond to the predicted frequencies.

  2. Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

    DOE Patents [OSTI]

    Wilding, Bruce M; Turner, Terry D

    2014-12-02

    A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

  3. Gas sensitive materials for gas detection and methods of making

    DOE Patents [OSTI]

    Trakhtenberg, Leonid Israilevich; Gerasimov, Genrikh Nikolaevich; Gromov, Vladimir Fedorovich; Rozenberg, Valeriya Isaakovna

    2014-07-15

    A gas sensitive material comprising SnO.sub.2 nanocrystals doped with In.sub.2O.sub.3 and an oxide of a platinum group metal, and a method of making the same. The platinum group metal is preferably Pd, but also may include Pt, Ru, Ir, and combinations thereof. The SnO.sub.2 nanocrystals have a specific surface of 7 or greater, preferably about 20 m2/g, and a mean particle size of between about 10 nm and about 100 nm, preferably about 40 nm. A gas detection device made from the gas sensitive material deposited on a substrate, the gas sensitive material configured as a part of a current measuring circuit in communication with a heat source.

  4. Gas sensitive materials for gas detection and method of making

    DOE Patents [OSTI]

    Trakhtenberg, Leonid Israilevich; Gerasimov, Genrikh Nikolaevich; Gromov, Vladimir Fedorovich; Rozenberg, Valeriya Isaakovna

    2012-12-25

    A gas sensitive material comprising SnO2 nanocrystals doped with In2O3 and an oxide of a platinum group metal, and a method of making the same. The platinum group metal is preferably Pd, but also may include Pt, Ru, Ir, and combinations thereof. The SnO2 nanocrystals have a specific surface of 7 or greater, preferably about 20 m2/g, and a mean particle size of between about 10 nm and about 100 nm, preferably about 40 nm. A gas detection device made from the gas sensitive material deposited on a substrate, the gas sensitive material configured as a part of a current measuring circuit in communication with a heat source.

  5. Method of producing a high pressure gas

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Zollinger, William T.

    2006-07-18

    A method of producing a high pressure gas is disclosed and which includes providing a container; supplying the container with a liquid such as water; increasing the pressure of the liquid within the container; supplying a reactant composition such as a chemical hydride to the liquid under pressure in the container and which chemically reacts with the liquid to produce a resulting high pressure gas such as hydrogen at a pressure of greater than about 100 pounds per square inch of pressure; and drawing the resulting high pressure gas from the container.

  6. Verifying Greenhouse Gas Emissions: Methods to Support International...

    Open Energy Info (EERE)

    Verifying Greenhouse Gas Emissions: Methods to Support International Climate Agreements Jump to: navigation, search Tool Summary Name: Verifying Greenhouse Gas Emissions: Methods...

  7. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, Charles L. (Lincoln, MA); He, Bo X. (Newton, MA)

    1990-01-01

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from when it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel.

  8. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, C.L.; He, B.X.

    1990-11-13

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from where it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel. 4 figs.

  9. Conversion method for gas streams containing hydrocarbons

    DOE Patents [OSTI]

    Mallinson, Richard G. (Norman, OK); Lobban, Lance (Norman, OK); Liu, Chang-jun (Tianjin, CN)

    2000-01-01

    An apparatus and a method of using the apparatus are provided for converting a gas stream containing hydrocarbons to a reaction product containing effluent molecules having at least one carbon atom, having at least one interior surface and at least one exterior surface, a first electrode and a second electrode with the first and second electrodes being selectively movable in relation to each other and positioned within the housing so as to be spatially disposed a predetermined distance from each other, a plasma discharge generator between the first and second electrodes, gas stream introducer and a collector for collecting the reaction product effluent produced by the reaction of the gas stream containing hydrocarbons with the plasma discharge between the first and second electrodes.

  10. Experiments to Evaluate and Implement Passive Tracer Gas Methods to Measure Ventilation Rates in Homes

    E-Print Network [OSTI]

    Lunden, Melissa

    2014-01-01

    of 1-bromo-4-fluorobenzene (BFB) prepared continuously in a174, 176 were scanned for the BFB internal standard. The MSwith pure standard using BFB as an internal standard.

  11. Method and apparatus for producing synthesis gas

    DOE Patents [OSTI]

    Hemmings, John William (Katy, TX); Bonnell, Leo (Houston, TX); Robinson, Earl T. (Mentor, OH)

    2010-03-03

    A method and apparatus for reacting a hydrocarbon containing feed stream by steam methane reforming reactions to form a synthesis gas. The hydrocarbon containing feed is reacted within a reactor having stages in which the final stage from which a synthesis gas is discharged incorporates expensive high temperature materials such as oxide dispersed strengthened metals while upstream stages operate at a lower temperature allowing the use of more conventional high temperature alloys. Each of the reactor stages incorporate reactor elements having one or more separation zones to separate oxygen from an oxygen containing feed to support combustion of a fuel within adjacent combustion zones, thereby to generate heat to support the endothermic steam methane reforming reactions.

  12. Petroleum characterization by perfluorocarbon tracers

    SciTech Connect (OSTI)

    Senum, G.I.; Fajer, R.W. (Brookhaven National Lab., Upton, NY (United States)); Harris, B.R. Jr. (USDOE Naval Petroleum Reserves in California, Tupman, CA (United States)); DeRose, W.E. (Bechtel Petroleum Operations, Inc., Tupman, CA (United States)); Ottaviani, W.L. (Chevron U.S.A., Inc., Bakersfield, CA (United States))

    1992-02-01

    Perfluorocarbon tracers (PFTs), a class of six compounds, were used to help characterize the Shallow Oil Zone (SOZ) reservoir at the Naval Petroleum Reserve in California (NPRC) at Elk Hills. The SOZ reservoir is undergoing a pilot gas injection program to assess the technical feasibility and economic viability of injecting gas into the SOZ for improved oil recovery. PFTs were utilized in the pilot gas injection to qualitatively assess the extent of the pilot gas injection so as to determine the degree of gas containment within the SOZ reservoir.

  13. Method for controlling gas metal arc welding

    DOE Patents [OSTI]

    Smartt, Herschel B. (Idaho Falls, ID); Einerson, Carolyn J. (Idaho Falls, ID); Watkins, Arthur D. (Idaho Falls, ID)

    1989-01-01

    The heat input and mass input in a Gas Metal Arc welding process are controlled by a method that comprises calculating appropriate values for weld speed, filler wire feed rate and an expected value for the welding current by algorithmic function means, applying such values for weld speed and filler wire feed rate to the welding process, measuring the welding current, comparing the measured current to the calculated current, using said comparison to calculate corrections for the weld speed and filler wire feed rate, and applying corrections.

  14. Method for controlling gas metal arc welding

    DOE Patents [OSTI]

    Smartt, H.B.; Einerson, C.J.; Watkins, A.D.

    1987-08-10

    The heat input and mass input in a Gas Metal Arc welding process are controlled by a method that comprises calculating appropriate values for weld speed, filler wire feed rate and an expected value for the welding current by algorithmic function means, applying such values for weld speed and filler wire feed rate to the welding process, measuring the welding current, comparing the measured current to the calculated current, using said comparison to calculate corrections for the weld speed and filler wire feed rate, and applying corrections. 3 figs., 1 tab.

  15. Atmospheric and soil-gas monitoring for surface leakage at the San Juan Basin CO{sub 2} pilot test site at Pump Canyon New Mexico, using perfluorocarbon tracers, CO{sub 2} soil-gas flux and soil-gas hydrocarbons

    SciTech Connect (OSTI)

    Wells, Arthur W.; Diehl, J. Rodney; Strazisar, Brian R.; Wilson, Thomas; H Stanko, Dennis C.

    2012-05-01

    Near-surface monitoring and subsurface characterization activities were undertaken in collaboration with the Southwest Regional Carbon Sequestration Partnership on their San Juan Basin coal-bed methane pilot test site near Navajo City, New Mexico. Nearly 18,407 short tons (1.670 × 107 kg) of CO{sub 2} were injected into 3 seams of the Fruitland coal between July 2008 and April 2009. Between September 18 and October 30, 2008, two additions of approximately 20 L each of perfluorocarbon (PFC) tracers were mixed with the CO{sub 2} at the injection wellhead. PFC tracers in soil-gas and in the atmosphere were monitored over a period of 2 years using a rectangular array of permanent installations. Additional monitors were placed near existing well bores and at other locations of potential leakage identified during the pre-injection site survey. Monitoring was conducted using sorbent containing tubes to collect any released PFC tracer from soil-gas or the atmosphere. Near-surface monitoring activities also included CO{sub 2} surface flux and carbon isotopes, soil-gas hydrocarbon levels, and electrical conductivity in the soil. The value of the PFC tracers was demonstrated when a significant leakage event was detected near an offset production well. Subsurface characterization activities, including 3D seismic interpretation and attribute analysis, were conducted to evaluate reservoir integrity and the potential that leakage of injected CO{sub 2} might occur. Leakage from the injection reservoir was not detected. PFC tracers made breakthroughs at 2 of 3 offset wells which were not otherwise directly observable in produced gases containing 20–30% CO{sub 2}. These results have aided reservoir geophysical and simulation investigations to track the underground movement of CO{sub 2}. 3D seismic analysis provided a possible interpretation for the order of appearance of tracers at production wells.

  16. Method for route selection of transcontinental natural gas pipelines

    E-Print Network [OSTI]

    Kouroupetroglou, Georgios

    1 Method for route selection of transcontinental natural gas pipelines Fotios G. Thomaidis1@kepa.uoa.gr Abstract. The route of transcontinental natural gas pipelines is characterized by complexity, compared choices. Keywords: Optimum route method, natural gas, transcontinental pipelines, Caspian Region ­ E

  17. System and method for detecting gas

    DOE Patents [OSTI]

    Chow, Oscar Ken (Simsbury, CT); Moulthrop, Lawrence Clinton (Windsor, CT); Dreier, Ken Wayne (Madison, CT); Miller, Jacob Andrew (Dexter, MI)

    2010-03-16

    A system to detect a presence of a specific gas in a mixture of gaseous byproducts comprising moisture vapor is disclosed. The system includes an electrochemical cell, a transport to deliver the mixture of gaseous byproducts from the electrochemical cell, a gas sensor in fluid communication with the transport, the sensor responsive to a presence of the specific gas to generate a signal corresponding to a concentration of the specific gas, and a membrane to prevent transmission of liquid moisture, the membrane disposed between the transport and the gas sensor.

  18. Method for mapping a natural gas leak

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2009-02-03

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formatted into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimposed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  19. Method and apparatus for manufacturing gas tags

    DOE Patents [OSTI]

    Gross, Kenny C. (Bolingbrook, IL); Laug, Matthew T. (Idaho Falls, ID)

    1996-01-01

    For use in the manufacture of gas tags employed in a gas tagging failure detection system for a nuclear reactor, a plurality of commercial feed gases each having a respective noble gas isotopic composition are blended under computer control to provide various tag gas mixtures having selected isotopic ratios which are optimized for specified defined conditions such as cost. Using a new approach employing a discrete variable structure rather than the known continuous-variable optimization problem, the computer controlled gas tag manufacturing process employs an analytical formalism from condensed matter physics known as stochastic relaxation, which is a special case of simulated annealing, for input feed gas selection. For a tag blending process involving M tag isotopes with N distinct feed gas mixtures commercially available from an enriched gas supplier, the manufacturing process calculates the cost difference between multiple combinations and specifies gas mixtures which approach the optimum defined conditions. The manufacturing process is then used to control tag blending apparatus incorporating tag gas canisters connected by stainless-steel tubing with computer controlled valves, with the canisters automatically filled with metered quantities of the required feed gases.

  20. Method and apparatus for manufacturing gas tags

    DOE Patents [OSTI]

    Gross, K.C.; Laug, M.T.

    1996-12-17

    For use in the manufacture of gas tags employed in a gas tagging failure detection system for a nuclear reactor, a plurality of commercial feed gases each having a respective noble gas isotopic composition are blended under computer control to provide various tag gas mixtures having selected isotopic ratios which are optimized for specified defined conditions such as cost. Using a new approach employing a discrete variable structure rather than the known continuous-variable optimization problem, the computer controlled gas tag manufacturing process employs an analytical formalism from condensed matter physics known as stochastic relaxation, which is a special case of simulated annealing, for input feed gas selection. For a tag blending process involving M tag isotopes with N distinct feed gas mixtures commercially available from an enriched gas supplier, the manufacturing process calculates the cost difference between multiple combinations and specifies gas mixtures which approach the optimum defined conditions. The manufacturing process is then used to control tag blending apparatus incorporating tag gas canisters connected by stainless-steel tubing with computer controlled valves, with the canisters automatically filled with metered quantities of the required feed gases. 4 figs.

  1. Marine Electromagnetic Methods for Gas Hydrate Characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen A

    2008-01-01

    data: an electromagnetic survey at Hydrate Ridge, Oregon made possible by funding from Exxon MobilExxon Mobil and from GERD, Japan to study gas hydrates. We only had 3 days of data

  2. Marine electromagnetic methods for gas hydrate characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen Andrea

    2008-01-01

    data: an electromagnetic survey at Hydrate Ridge, Oregon made possible by funding from Exxon MobilExxon Mobil and from GERD, Japan to study gas hydrates. We only had 3 days of data

  3. System and method for cooling a combustion gas charge

    DOE Patents [OSTI]

    Massey, Mary Cecelia; Boberg, Thomas Earl

    2010-05-25

    The present invention relates to a system and method for cooling a combustion gas charge prior. The combustion gas charge may include compressed intake air, exhaust gas, or a mixture thereof. An evaporator is provided that may then receive a relatively high temperature combustion gas charge and discharge at a relatively lower temperature. The evaporator may be configured to operate with refrigeration cycle components and/or to receive a fluid below atmospheric pressure as the phase-change cooling medium.

  4. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, Stark County, OH)

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  5. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, OH)

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  6. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  7. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  8. Method and apparatus for pressurizing a liquefied gas

    DOE Patents [OSTI]

    Bingham, Dennis N.

    2005-07-26

    Apparatus providing at least one thermoelectric device for pressurizing a liquefied gas container and methods employing same are disclosed. A thermoelectric device including a heating surface and a cooling surface is used for pressurizing a container by vaporizing liquefied gas within the container by transferring heat energy from a portion of the liquefied gas in contact with the cooling surface to another portion of the liquefied gas in contact with the heating surface of the thermoelectric device to convert some of the liquefied gas to a vapor state. Liquefied gas vapor and/or liquid phase may be supplied by disclosed apparatus and methods. The apparatus may also be used as a vapor pump or a liquid pump, or fluid pump. Methods of operation are also disclosed.

  9. Smoothing method aids gas-inventory variance trending

    SciTech Connect (OSTI)

    Mason, R.G. )

    1992-03-23

    This paper reports on a method for determining gas-storage inventory and variance in a natural-gas storage field which uses the equations developed to determine gas-in-place in a production field. The calculations use acquired data for shut-in pressures, reservoir pore volume, and storage gas properties. These calculations are then graphed and trends are developed. Evaluating trends in inventory variance can be enhanced by use of a technique, described here, that smooths the peaks and valleys of an inventory-variance curve. Calculations using the acquired data determine inventory for a storage field whose drive mechanism is gas expansion (that is, volumetric). When used for a dry gas, condensate, or gas-condensate reservoir, the formulas require no further modification. Inventory in depleted oil fields can be determined in this same manner, as well. Some additional calculations, however, must be made to assess the influence of oil production on the gas-storage process.

  10. Method for nonlinear optimization for gas tagging and other systems

    DOE Patents [OSTI]

    Chen, T.; Gross, K.C.; Wegerich, S.

    1998-01-06

    A method and system are disclosed for providing nuclear fuel rods with a configuration of isotopic gas tags. The method includes selecting a true location of a first gas tag node, selecting initial locations for the remaining n-1 nodes using target gas tag compositions, generating a set of random gene pools with L nodes, applying a Hopfield network for computing on energy, or cost, for each of the L gene pools and using selected constraints to establish minimum energy states to identify optimal gas tag nodes with each energy compared to a convergence threshold and then upon identifying the gas tag node continuing this procedure until establishing the next gas tag node until all remaining n nodes have been established. 6 figs.

  11. Method for nonlinear optimization for gas tagging and other systems

    DOE Patents [OSTI]

    Chen, Ting (Chicago, IL); Gross, Kenny C. (Bolingbrook, IL); Wegerich, Stephan (Glendale Heights, IL)

    1998-01-01

    A method and system for providing nuclear fuel rods with a configuration of isotopic gas tags. The method includes selecting a true location of a first gas tag node, selecting initial locations for the remaining n-1 nodes using target gas tag compositions, generating a set of random gene pools with L nodes, applying a Hopfield network for computing on energy, or cost, for each of the L gene pools and using selected constraints to establish minimum energy states to identify optimal gas tag nodes with each energy compared to a convergence threshold and then upon identifying the gas tag node continuing this procedure until establishing the next gas tag node until all remaining n nodes have been established.

  12. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond (Avondale, AZ)

    2012-08-07

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  13. Method and apparatus for recovering a gas from a gas hydrate located on the ocean floor

    DOE Patents [OSTI]

    Wyatt, Douglas E. (Aiken, SC)

    2001-01-01

    A method and apparatus for recovering a gas from a gas hydrate on the ocean floor includes a flexible cover, a plurality of steerable base members secured to the cover, and a steerable mining module. A suitable source for inflating the cover over the gas hydrate deposit is provided. The mining module, positioned on the gas hydrate deposit, is preferably connected to the cover by a control cable. A gas retrieval conduit or hose extends upwardly from the cover to be connected to a support ship on the ocean surface.

  14. Analysis of a geopressured gas reservoir using solution plot method 

    E-Print Network [OSTI]

    Hussain, Syed Muqeedul

    1992-01-01

    ANALYSIS OF A GEOPRESSURED GAS RESERVOIR USING SOLUTION PLOT METHOD A Thesis by SYED MUQEEDUL HUSSAIN Submitted to the Office of Cuaduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE December 1992 Major Subject: Petroleum Engineering ANALYSIS OF A GEOPRESSURED GAS RESERVOIR USING SOLUTION PLOT METHOD A Thesis by SYED MUQEEDUL HUSSAIN Approved as to style and content by: S. W. Poston (Chair of Committee) R. R. Berg...

  15. Method and apparatus for off-gas composition sensing

    DOE Patents [OSTI]

    Ottesen, David Keith (Livermore, CA); Allendorf, Sarah Williams (Fremont, CA); Hubbard, Gary Lee (Richmond, CA); Rosenberg, David Ezechiel (Columbia, MD)

    1999-01-01

    An apparatus and method for non-intrusive collection of off-gas data in a steelmaking furnace includes structure and steps for transmitting a laser beam through the off-gas produced by a steelmaking furnace, for controlling the transmitting to repeatedly scan the laser beam through a plurality of wavelengths in its tuning range, and for detecting the laser beam transmitted through the off-gas and converting the detected laser beam to an electrical signal. The electrical signal is processed to determine characteristics of the off-gas that are used to analyze and/or control the steelmaking process.

  16. Method for making hydrogen rich gas from hydrocarbon fuel

    DOE Patents [OSTI]

    Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

    1999-01-01

    A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

  17. Method for making hydrogen rich gas from hydrocarbon fuel

    DOE Patents [OSTI]

    Krumpelt, M.; Ahmed, S.; Kumar, R.; Doshi, R.

    1999-07-27

    A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400 C for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide. 4 figs.

  18. Method for treating a nuclear process off-gas stream

    DOE Patents [OSTI]

    Pence, Dallas T. (San Diego, CA); Chou, Chun-Chao (San Diego, CA)

    1984-01-01

    Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

  19. Method for eliminating gas blocking in electrokinetic pumping systems

    DOE Patents [OSTI]

    Arnold, Don W. (Livermore, CA); Paul, Phillip H. (Livermore, CA); Schoeniger, Joseph S. (Oakland, CA)

    2001-09-11

    A method for eliminating gas bubble blockage of current flow during operation of an electrokinetic pump. By making use of the ability to modify the surface charge on the porous dielectric medium used in electrokinetic pumps, it becomes possible to place electrodes away from the pressurized region of the electrokinetic pump. While gas is still generated at the electrodes they are situated such that the generated gas can escape into a larger buffer reservoir and not into the high pressure region of the pump where the gas bubbles can interrupt current flow. Various combinations of porous dielectric materials and ionic conductors can be used to create pumps that have desirable electrical, material handling, and flow attributes.

  20. Method and apparatus for fuel gas moisturization and heating

    DOE Patents [OSTI]

    Ranasinghe, Jatila (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01

    Fuel gas is saturated with water heated with a heat recovery steam generator heat source. The heat source is preferably a water heating section downstream of the lower pressure evaporator to provide better temperature matching between the hot and cold heat exchange streams in that portion of the heat recovery steam generator. The increased gas mass flow due to the addition of moisture results in increased power output from the gas and steam turbines. Fuel gas saturation is followed by superheating the fuel, preferably with bottom cycle heat sources, resulting in a larger thermal efficiency gain compared to current fuel heating methods. There is a gain in power output compared to no fuel heating, even when heating the fuel to above the LP steam temperature.

  1. The repair and rehabilitation method of Tokyo gas

    SciTech Connect (OSTI)

    Yagi, Shuichi [Tokyo Gas Co., Ltd. (Japan)

    1996-08-01

    It has been an important matter for gas utilities to maintain their pipelines easily and economically. But pipes that have become old suffer from progressive corrosion, and as a result of vibration caused by traffic or the effects of land subsidence, joints can become loosened. To repair pipes that have suffered in such ways, the usual method to do is to dig them up and replace them with new ones. But this method requires a large amount of excavation, so the work takes a long time to complete and is costly. To deal with these problems, Tokyo Gas developed number of repair and rehabilitation methods to permit renewal of pipelines without replacing them. In this paper, I would like to introduce our repair and rehabilitation methods for low-pressure pipeline. 4 refs., 9 figs., 4 tabs.

  2. Methods for gas detection using stationary hyperspectral imaging sensors

    DOE Patents [OSTI]

    Conger, James L. (San Ramon, CA); Henderson, John R. (Castro Valley, CA)

    2012-04-24

    According to one embodiment, a method comprises producing a first hyperspectral imaging (HSI) data cube of a location at a first time using data from a HSI sensor; producing a second HSI data cube of the same location at a second time using data from the HSI sensor; subtracting on a pixel-by-pixel basis the second HSI data cube from the first HSI data cube to produce a raw difference cube; calibrating the raw difference cube to produce a calibrated raw difference cube; selecting at least one desired spectral band based on a gas of interest; producing a detection image based on the at least one selected spectral band and the calibrated raw difference cube; examining the detection image to determine presence of the gas of interest; and outputting a result of the examination. Other methods, systems, and computer program products for detecting the presence of a gas are also described.

  3. Control method for mixed refrigerant based natural gas liquefier

    DOE Patents [OSTI]

    Kountz, Kenneth J. (Palatine, IL); Bishop, Patrick M. (Chicago, IL)

    2003-01-01

    In a natural gas liquefaction system having a refrigerant storage circuit, a refrigerant circulation circuit in fluid communication with the refrigerant storage circuit, and a natural gas liquefaction circuit in thermal communication with the refrigerant circulation circuit, a method for liquefaction of natural gas in which pressure in the refrigerant circulation circuit is adjusted to below about 175 psig by exchange of refrigerant with the refrigerant storage circuit. A variable speed motor is started whereby operation of a compressor is initiated. The compressor is operated at full discharge capacity. Operation of an expansion valve is initiated whereby suction pressure at the suction pressure port of the compressor is maintained below about 30 psig and discharge pressure at the discharge pressure port of the compressor is maintained below about 350 psig. Refrigerant vapor is introduced from the refrigerant holding tank into the refrigerant circulation circuit until the suction pressure is reduced to below about 15 psig, after which flow of the refrigerant vapor from the refrigerant holding tank is terminated. Natural gas is then introduced into a natural gas liquefier, resulting in liquefaction of the natural gas.

  4. Dispersion of Passive Tracers in the Surfzone

    E-Print Network [OSTI]

    Fedderson, Falk; Guza, Robert T.

    2007-01-01

    Dispersion of passive tracers in the surfzone Feddersen andThe dispersion of passive tracers, such as pollutants, in

  5. Selection of hydrate suppression methods for gas streams

    SciTech Connect (OSTI)

    Behrens, S.D.; Covington, K.K.; Collie, J.T. III

    1999-07-01

    This paper will discuss and compare the methods used to suppress hydrate formation in natural gas streams. Included in the comparison will be regenerated systems using ethylene glycol and non-regenerated systems using methanol. A comparison will be made between the quantities of methanol and ethylene glycol required to achieve a given a suppression. A discussion of BTEX emissions resulting from the ethylene glycol regenerator along with the effect or process variables on these emissions is also given.

  6. Gas phase fractionation method using porous ceramic membrane

    DOE Patents [OSTI]

    Peterson, Reid A. (Madison, WI); Hill, Jr., Charles G. (Madison, WI); Anderson, Marc A. (Madison, WI)

    1996-01-01

    Flaw-free porous ceramic membranes fabricated from metal sols and coated onto a porous support are advantageously used in gas phase fractionation methods. Mean pore diameters of less than 40 .ANG., preferably 5-20 .ANG. and most preferably about 15 .ANG., are permeable at lower pressures than existing membranes. Condensation of gases in small pores and non-Knudsen membrane transport mechanisms are employed to facilitate and increase membrane permeability and permselectivity.

  7. Method and apparatus for controlling gas evolution from chemical reactions

    DOE Patents [OSTI]

    Skorpik, J.R.; Dodson, M.G.

    1999-05-25

    The present invention is directed toward monitoring a thermally driven gas evolving chemical reaction with an acoustic apparatus. Signals from the acoustic apparatus are used to control a heater to prevent a run-away condition. A digestion module in combination with a robotic arm further automate physical handling of sample material reaction vessels. The invention is especially useful for carrying out sample procedures defined in EPA Methods SW-846. 8 figs.

  8. Method and apparatus for controlling gas evolution from chemical reactions

    DOE Patents [OSTI]

    Skorpik, James R. (Kennewick, WA); Dodson, Michael G. (Richland, WA)

    1999-01-01

    The present invention is directed toward monitoring a thermally driven gas evolving chemical reaction with an acoustic apparatus. Signals from the acoustic apparatus are used to control a heater to prevent a run-away condition. A digestion module in combination with a robotic arm further automate physical handling of sample material reaction vessels. The invention is especially useful for carrying out sample procedures defined in EPA Methods SW-846.

  9. Enhanced Oil Recovery: Aqueous Flow Tracer Measurement

    SciTech Connect (OSTI)

    Joseph Rovani; John Schabron

    2009-02-01

    A low detection limit analytical method was developed to measure a suite of benzoic acid and fluorinated benzoic acid compounds intended for use as tracers for enhanced oil recovery operations. Although the new high performance liquid chromatography separation successfully measured the tracers in an aqueous matrix at low part per billion levels, the low detection limits could not be achieved in oil field water due to interference problems with the hydrocarbon-saturated water using the system's UV detector. Commercial instrument vendors were contacted in an effort to determine if mass spectrometry could be used as an alternate detection technique. The results of their work demonstrate that low part per billion analysis of the tracer compounds in oil field water could be achieved using ultra performance liquid chromatography mass spectrometry.

  10. Statistical Methods Handbook for Advanced Gas Reactor Fuel Materials

    SciTech Connect (OSTI)

    J. J. Einerson

    2005-05-01

    Fuel materials such as kernels, coated particles, and compacts are being manufactured for experiments simulating service in the next generation of high temperature gas reactors. These must meet predefined acceptance specifications. Many tests are performed for quality assurance, and many of these correspond to criteria that must be met with specified confidence, based on random samples. This report describes the statistical methods to be used. The properties of the tests are discussed, including the risk of false acceptance, the risk of false rejection, and the assumption of normality. Methods for calculating sample sizes are also described.

  11. Self-contained cryogenic gas sampling apparatus and method

    DOE Patents [OSTI]

    McManus, G.J.; Motes, B.G.; Bird, S.K.; Kotter, D.K.

    1996-03-26

    Apparatus for obtaining a whole gas sample, is composed of: a sample vessel having an inlet for receiving a gas sample; a controllable valve mounted for controllably opening and closing the inlet; a valve control coupled to the valve for opening and closing the valve at selected times; a portable power source connected for supplying operating power to the valve control; and a cryogenic coolant in thermal communication with the vessel for cooling the interior of the vessel to cryogenic temperatures. A method is described for obtaining an air sample using the apparatus described above, by: placing the apparatus at a location at which the sample is to be obtained; operating the valve control to open the valve at a selected time and close the valve at a selected subsequent time; and between the selected times maintaining the vessel at a cryogenic temperature by heat exchange with the coolant. 3 figs.

  12. Following the flow: tracer particles in astrophysical fluid simulations

    E-Print Network [OSTI]

    Genel, Shy; Nelson, Dylan; Sijacki, Debora; Springel, Volker; Hernquist, Lars

    2013-01-01

    We present two independent numerical schemes for passive tracer particles in the hydrodynamical moving-mesh code Arepo, and compare their performance for various problems, from simple tests to cosmological simulations. The purpose of tracer particles is to allow the flow to be followed in a Lagrangian way, reliably tracing the evolution of the fluid. Such tracer particles can subsequently measure any local instantaneous fluid property, thereby recording the thermodynamical history of individual fluid parcels. We begin by discussing "velocity field tracers", which are advected according to the local velocity field of the fluid, and which have been commonly used in the literature. We find that such tracers do not in general follow the mass flow correctly, particularly in complex flows, and explain why this is the case. This weakness of the method can result in orders-of-magnitude biases in simulations of driven turbulence and in cosmological simulations of structure formation, rendering the velocity field trace...

  13. Method For Enhanced Gas Monitoring In High Density Flow Streams

    DOE Patents [OSTI]

    Von Drasek, William A. (Oak Forest, IL); Mulderink, Kenneth A. (Countryside, IL); Marin, Ovidiu (Lisle, IL)

    2005-09-13

    A method for conducting laser absorption measurements in high temperature process streams having high levels of particulate matter is disclosed. An impinger is positioned substantially parallel to a laser beam propagation path and at upstream position relative to the laser beam. Beam shielding pipes shield the beam from the surrounding environment. Measurement is conducted only in the gap between the two shielding pipes where the beam propagates through the process gas. The impinger facilitates reduced particle presence in the measurement beam, resulting in improved SNR (signal-to-noise) and improved sensitivity and dynamic range of the measurement.

  14. Method of purifying a gas stream using 1,2,3-triazolium ionic...

    Office of Scientific and Technical Information (OSTI)

    Method of purifying a gas stream using 1,2,3-triazolium ionic liquids Citation Details In-Document Search Title: Method of purifying a gas stream using 1,2,3-triazolium ionic...

  15. Method and apparatus for dispensing compressed natural gas and liquified natural gas to natural gas powered vehicles

    DOE Patents [OSTI]

    Bingham, Dennis A.; Clark, Michael L.; Wilding, Bruce M.; Palmer, Gary L.

    2005-05-31

    A fueling facility and method for dispensing liquid natural gas (LNG), compressed natural gas (CNG) or both on-demand. The fueling facility may include a source of LNG, such as cryogenic storage vessel. A low volume high pressure pump is coupled to the source of LNG to produce a stream of pressurized LNG. The stream of pressurized LNG may be selectively directed through an LNG flow path or to a CNG flow path which includes a vaporizer configured to produce CNG from the pressurized LNG. A portion of the CNG may be drawn from the CNG flow path and introduced into the CNG flow path to control the temperature of LNG flowing therethrough. Similarly, a portion of the LNG may be drawn from the LNG flow path and introduced into the CNG flow path to control the temperature of CNG flowing therethrough.

  16. Apparatus and method for monitoring of gas having stable isotopes

    DOE Patents [OSTI]

    Clegg, Samuel M; Fessenden-Rahn, Julianna E

    2013-03-05

    Gas having stable isotopes is monitored continuously by using a system that sends a modulated laser beam to the gas and collects and transmits the light not absorbed by the gas to a detector. Gas from geological storage, or from the atmosphere can be monitored continuously without collecting samples and transporting them to a lab.

  17. Completion methods in thick, multilayered tight gas sands 

    E-Print Network [OSTI]

    Ogueri, Obinna Stavely

    2009-05-15

    Tight gas sands, coal-bed methane, and gas shales are commonly called unconventional reservoirs. Tight gas sands (TGS) are often described as formations with an expected average permeability of 0.1mD or less. Gas production rates from TGS reservoirs...

  18. Method for directly recovering fluorine from gas streams

    DOE Patents [OSTI]

    Orlett, Michael J. (Portsmouth, OH); Saraceno, Anthony J. (Waverly, OH)

    1981-01-01

    This invention is a process for the direct recovery of gaseous fluorine from waste-gas streams or the like. The process comprises passing the gas stream through a bed of anhydrous K.sub.3 NiF.sub.6 pellets to fluorinate the same to K.sub.3 NiF.sub.7 and subsequently desorbing the fluorine by heating the K.sub.3 NiF.sub.7 pellets to a temperature re-converting them to K.sub.3 NiF.sub.6. The efficiency of the fluorine-absorption step is maximized by operating in a selected and conveniently low temperature. The desorbed fluorine is highly pure and is at a pressure of several atmospheres. Preferably, the K.sub.3 NiF.sub.6 pellets are prepared by a method including the steps of forming agglomerates of hydrated K.sub.3 NiF.sub.5, sintering the agglomerates to form K.sub.3 NiF.sub.5 pellets of enhanced reactivity with respect to fluorine, and fluorinating the sintered pellets to K.sub.3 NiF.sub.6.

  19. Method for controlling exhaust gas heat recovery systems in vehicles

    DOE Patents [OSTI]

    Spohn, Brian L.; Claypole, George M.; Starr, Richard D

    2013-06-11

    A method of operating a vehicle including an engine, a transmission, an exhaust gas heat recovery (EGHR) heat exchanger, and an oil-to-water heat exchanger providing selective heat-exchange communication between the engine and transmission. The method includes controlling a two-way valve, which is configured to be set to one of an engine position and a transmission position. The engine position allows heat-exchange communication between the EGHR heat exchanger and the engine, but does not allow heat-exchange communication between the EGHR heat exchanger and the oil-to-water heat exchanger. The transmission position allows heat-exchange communication between the EGHR heat exchanger, the oil-to-water heat exchanger, and the engine. The method also includes monitoring an ambient air temperature and comparing the monitored ambient air temperature to a predetermined cold ambient temperature. If the monitored ambient air temperature is greater than the predetermined cold ambient temperature, the two-way valve is set to the transmission position.

  20. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R.K.; Im, K.H.

    1996-04-02

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines. 13 figs.

  1. Efficient numerical methods for the instationary solution of laminar reacting gas

    E-Print Network [OSTI]

    Vuik, Kees

    Efficient numerical methods for the instationary solution of laminar reacting gas flow problems Universiteit Delft Efficient numerical methods for the instationary solution of laminar reacting gas flow of laminar reacting gas flow problems Sander van Veldhuizen Production processes of high-purity, high

  2. Investigation of two-fluid methods for Large Eddy Simulation of spray combustion in Gas Turbines

    E-Print Network [OSTI]

    Investigation of two-fluid methods for Large Eddy Simulation of spray combustion in Gas Turbines the EL method well suited for gas turbine computations, but RANS with the EE approach may also be found and coupled with the LES solver of the gas phase. The equations used for each phase and the coupling terms

  3. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean (Castle Rock, CO); Schlager, Richard John (Aurora, CO); Ebner, Timothy George (Westminster, CO); Stewart, Robin Michele (Arvada, CO); Hyatt, David E. (Denver, CO); Bustard, Cynthia Jean (Littleton, CO); Sjostrom, Sharon (Denver, CO)

    1998-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  4. Applying the isochronal, transient p/z method to gas wells exhibiting wellbore storage effects 

    E-Print Network [OSTI]

    Deshpande, Anil

    1993-01-01

    Static reservoir pressures are required for gas material balance plz vs. Gp plots. A new method has been developed that uses wellbore storage distorted early time pressure buildup data to determine original gas in place (OGIP). Analysis...

  5. Using {sup 222}Rn as a tracer of geophysical processes in underground environments

    SciTech Connect (OSTI)

    Lacerda, T.; Anjos, R. M.; Silva, A. A. R. da; Yoshimura, E. M.

    2014-11-11

    Radon levels in two old mines in San Luis, Argentina, are reported and analyzed. These mines are today used for touristic visitation. Our goal was to assess the potential use of such radioactive noble gas as tracer of geological processes in underground environments. CR-39 nuclear track detectors were used during the winter and summer seasons. The findings show that the significant radon concentrations reported in this environment are subject to large seasonal modulations, due to the strong dependence of natural ventilation on the variations of outside temperature. The results also indicate that radon pattern distribution appear as a good method to localize unknown ducts, fissures or secondary tunnels in subterranean environments.

  6. Systems and method for delivering liquified gas to an engine

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); O'Brien, James E. (Idaho Falls, ID); Siahpush, Ali S. (Idaho Falls, ID); Brown, Kevin B. (Idaho Falls, ID)

    2002-01-01

    A liquified gas delivery system for a motorized platform includes a holding tank configured to receive liquified gas. A first conduit extends from a vapor holding portion of the tank to a valve device. A second conduit extends from a liquid holding portion of the tank to the valve device. Fluid coupled to the valve device is a vaporizer which is in communication with an engine. The valve device selectively withdraws either liquified gas or liquified gas vapor from the tank depending on the pressure within the vapor holding portion of the tank. Various configurations of the delivery system can be utilized for pressurizing the tank during operation.

  7. Methods For Delivering Liquified Gas To An Engine

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); O'Brien, James E. (Idaho Falls, ID); Siahpush, Ali S. (Idaho Falls, ID); Brown, Kevin B. (Idaho Falls, ID)

    2003-09-16

    A liquified gas delivery system for a motorized platform includes a holding tank configured to receive liquified gas. A first conduit extends from a vapor holding portion of the tank to a valve device. A second conduit extends from a liquid holding portion of the tank to the valve device. Fluid coupled to the valve device is a vaporizer which is in communication with an engine. The valve device selectively withdraws either liquified gas or liquified gas vapor from the tank depending on the pressure within the vapor holding portion of the tank. Various configurations of the delivery system can be utilized for pressurizing the tank during operation.

  8. Methods For Delivering Liquified Gas To An Engine

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); O'Brien, James E. (Idaho Falls, ID); Siahpush, Ali S. (Idaho Falls, ID); Brown, Kevin B. (Idaho Falls, ID)

    2005-10-11

    A liquified gas delivery system for a motorized platform includes a holding tank configured to receive liquified gas. A first conduit extends from a vapor holding portion of the tank to a valve device. A second conduit extends from a liquid holding portion of the tank to the valve device. Fluid coupled to the valve device is a vaporizer which is in communication with an engine. The valve device selectively withdraws either liquified gas or liquified gas vapor from the tank depending on the pressure within the vapor holding portion of the tank. Various configurations of the delivery system can be utilized for pressurizing the tank during operation.

  9. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2006-04-25

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  10. An efficient method for calculation of cooling in Lagrange computational gas dynamics

    E-Print Network [OSTI]

    E. P. Kurbatov

    2007-05-15

    A new method for computation of gas cooling for Lagrange approach is suggested. The method is based on precalculation of cooling law for known cooling function. Unlike implicit methods, this method is very efficient, it is an one-step method which is even more accurate than implicit methods of the same order.

  11. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

    1998-11-10

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

  12. Apparatus for the liquefaction of a gas and methods relating to same

    DOE Patents [OSTI]

    Turner, Terry D. (Idaho Falls, ID) [Idaho Falls, ID; Wilding, Bruce M. (Idaho Falls, ID) [Idaho Falls, ID; McKellar, Michael G. (Idaho Falls, ID) [Idaho Falls, ID

    2009-12-29

    Apparatuses and methods are provided for producing liquefied gas, such as liquefied natural gas. In one embodiment, a liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream may be sequentially pass through a compressor and an expander. The process stream may also pass through a compressor. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. A portion of the liquid gas may be used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line.

  13. Application of Phase-field Method in Predicting Gas Bubble Microstructure Evolution in Nuclear Fuels

    SciTech Connect (OSTI)

    Hu, Shenyang Y.; Li, Yulan; Sun, Xin; Gao, Fei; Devanathan, Ramaswami; Henager, Charles H.; Khaleel, Mohammad A.

    2010-04-30

    Fission product accumulation and gas bubble microstructure evolution in nuclear fuels strongly affect thermo-mechanical properties such as thermal conductivity, gas release, volumetric swelling and cracking, and hence the fuel performance. In this paper, a general phase-field model is developed to predict gas bubble formation and evolution. Important materials processes and thermodynamic properties including the generation of gas atoms and vacancies, sinks for vacancies and gas atoms, the elastic interaction among defects, gas re-solution, and inhomogeneity of elasticity and diffusivity are accounted for in the model. The simulations demonstrate the potential application of the phase-field method in investigating 1) heterogeneous nucleation of gas bubbles at defects; 2) effect of elastic interaction, inhomogeneity of material properties, and gas re-solution on gas bubble microstructures; and 3) effective properties from the output of phase-field simulations such as distribution of defects, gas bubbles, and stress fields.

  14. A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene...

    Open Energy Info (EERE)

    A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene Sulfonate as a Liquid-Phase Tracer at the Coso Geothermal Field Jump to: navigation, search OpenEI Reference...

  15. Method of cooling gas only nozzle fuel tip

    DOE Patents [OSTI]

    Bechtel, William Theodore (Scotia, NY); Fitts, David Orus (Ballston Spa, NY); DeLeonardo, Guy Wayne (Glenville, NY)

    2002-01-01

    A diffusion flame nozzle gas tip is provided to convert a dual fuel nozzle to a gas only nozzle. The nozle tip diverts compressor discharge air from the passage feeding the diffusion nozzle air swirl vanes to a region vacated by removal of the dual fuel components, so that the diverted compressor discharge air can flow to and through effusion holes in the end cap plate of the nozzle tip. In a preferred embodiment, the nozzle gas tip defines a cavity for receiving the compressor discharge air from a peripheral passage of the nozzle for flow through the effusion openings defined in the end cap plate.

  16. Gas-Kinetic Finite Volume Methods K. Xu, L. Martinelli, A. Jameson

    E-Print Network [OSTI]

    Jameson, Antony

    Gas-Kinetic Finite Volume Methods K. Xu, L. Martinelli, A. Jameson Department of M.A.E, Princeton University, Prificeton N.J. 08544, USA 1 Introduction Gas-kinetic schemes developed from the BGK model have been successfully applied to 1-D and 2-D flows [1,2]. One of the advantages of the gas-kinetic approach

  17. Method for the removal of elemental mercury from a gas stream

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Huang, H.S.

    1999-05-04

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents. 7 figs.

  18. Method to deduce local impurity transport quantities from the evolution of tomographically reconstructed bolometer signals during tracer injection at TJ-II

    SciTech Connect (OSTI)

    Zurro, B.; Ochando, M.A.; Baciero, A.; McCarthy, K.J.; Medina, F.; Lopez-Sanchez, A.; Rapisarda, D.; Jimenez, D.; Fernandez, A.; Pastor, I.; Herranz, J.; Dux, R. [Laboratorio Nacional de Fusion, Asociacion EURATOM/CIEMAT para Fusion, Madrid (Spain); Max Planck Institut fuer Plasmaphysik, Garching (Germany)

    2004-10-01

    A method to obtain local impurity transport from injected impurities in the TJ-II stellarator is presented. By using a one-dimensional full impurity transport code STRAHL, the transient behavior of the localized response of global radiation monitors to impurity injection is matched by the code results using an iterative method. The distinctive feature of the present approach with respect to other works is that we use tomographically reconstructed evolutions of total radiated power from a bolometer array. The method will be illustrated with analysis of blow-off results of experiments performed in the TJ-II stellarator.

  19. Method and apparatus for processing exhaust gas with corona discharge

    DOE Patents [OSTI]

    Barlow, S.E.; Orlando, T.M.; Tonkyn, R.G.

    1999-06-22

    The present invention is placing a catalyst coating upon surfaces surrounding a volume containing corona discharge. In addition, the electrodes are coated with a robust dielectric material. Further, the electrodes are arranged so that at least a surface portion of each electrode extends into a flow path of the exhaust gas to be treated and there is only exhaust gas in the volume between each pair of electrodes. 12 figs.

  20. Comparison of Various Deterministic Forecasting Techniques in Shale Gas Reservoirs with Emphasis on the Duong Method 

    E-Print Network [OSTI]

    Joshi, Krunal Jaykant

    2012-10-19

    There is a huge demand in the industry to forecast production in shale gas reservoirs accurately. There are many methods including volumetric, Decline Curve Analysis (DCA), analytical simulation and numerical simulation. Each one of these methods...

  1. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Turner, Terry D. (Ammon, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID)

    2009-09-22

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates a vapor from the liquid natural gas. A portion of the liquid gas is used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line or recirculation within the system for further processing.

  2. Method for combined removal of mercury and nitrogen oxides from off-gas streams

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

    2006-10-10

    A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

  3. Chemical tracers of episodic accretion in low-mass protostars

    E-Print Network [OSTI]

    Visser, Ruud; Jorgensen, Jes K

    2015-01-01

    Aims: Accretion rates in low-mass protostars can be highly variable in time. Each accretion burst is accompanied by a temporary increase in luminosity, heating up the circumstellar envelope and altering the chemical composition of the gas and dust. This paper aims to study such chemical effects and discusses the feasibility of using molecular spectroscopy as a tracer of episodic accretion rates and timescales. Methods: We simulate a strong accretion burst in a diverse sample of 25 spherical envelope models by increasing the luminosity to 100 times the observed value. Using a comprehensive gas-grain network, we follow the chemical evolution during the burst and for up to 10^5 yr after the system returns to quiescence. The resulting abundance profiles are fed into a line radiative transfer code to simulate rotational spectra of C18O, HCO+, H13CO+, and N2H+ at a series of time steps. We compare these spectra to observations taken from the literature and to previously unpublished data of HCO+ and N2H+ 6-5 from th...

  4. Method for removal of mercury from various gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2003-06-10

    The invention provides for a method for removing elemental mercury from a fluid, the method comprising irradiating the mercury with light having a wavelength of approximately 254 nm. The method is implemented in situ at various fuel combustion locations such as power plants and municipal incinerators.

  5. Method of generating hydrogen gas from sodium borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester, Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2007-12-11

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  6. Brush potential curve tracer

    DOE Patents [OSTI]

    Finch, Hilvan A. (Schenectady, NY)

    1987-01-01

    A device for analyzing commutating characteristics of a motor or generator includes a holder for supporting a plurality of probes adjacent a brush of the motor or generator. Measurements of electrical current characteristics in each of the probes provides information useful in analyzing operation of the machine. Methods for employing a device in accordance with the invention are also disclosed.

  7. Brush potential curve tracer

    DOE Patents [OSTI]

    Finch, H.A.

    1985-06-21

    A device for analyzing commutating characteristics of a motor or generator includes a holder for supporting a plurality of probes adjacent a brush of the motor or generator. Measurements of electrical current characteristics of the probes provides information useful in analyzing operation of the machine. Methods for employing a device in accordance with the invention are also disclosed.

  8. System and method to determine thermophysical properties of a multi-component gas

    DOE Patents [OSTI]

    Morrow, Thomas B.; Behring, II, Kendricks A.

    2003-08-05

    A system and method to characterize natural gas hydrocarbons using a single inferential property, such as standard sound speed, when the concentrations of the diluent gases (e.g., carbon dioxide and nitrogen) are known. The system to determine a thermophysical property of a gas having a first plurality of components comprises a sound velocity measurement device, a concentration measurement device, and a processor to determine a thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the concentration measurements, wherein the number of concentration measurements is less than the number of components in the gas. The method includes the steps of determining the speed of sound in the gas, determining a plurality of gas component concentrations in the gas, and determining the thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the plurality of concentrations.

  9. Water augmented indirectly-fired gas turbine systems and method

    DOE Patents [OSTI]

    Bechtel, Thomas F. (Lebanon, PA); Parsons, Jr., Edward J. (Morgantown, WV)

    1992-01-01

    An indirectly-fired gas turbine system utilizing water augmentation for increasing the net efficiency and power output of the system is described. Water injected into the compressor discharge stream evaporatively cools the air to provide a higher driving temperature difference across a high temperature air heater which is used to indirectly heat the water-containing air to a turbine inlet temperature of greater than about 1,000.degree. C. By providing a lower air heater hot side outlet temperature, heat rejection in the air heater is reduced to increase the heat recovery in the air heater and thereby increase the overall cycle efficiency.

  10. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID) [Idaho Falls, ID; McKellar, Michael G. (Idaho Falls, ID) [Idaho Falls, ID; Turner, Terry D. (Ammon, ID) [Ammon, ID; Carney, Francis H. (Idaho Falls, ID) [Idaho Falls, ID

    2009-09-29

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream.

  11. Evaporation system and method for gas jet deposition of thin film materials

    DOE Patents [OSTI]

    Schmitt, Jerome J. (New Haven, CT); Halpern, Bret L. (Bethany, CT)

    1994-01-01

    A method and apparatus for depositing thin films of materials such as metals, oxides and nitrides at low temperature relies on a supersonic free jet of inert carrier gas to transport vapor species generated from an evaporation source to the surface of a substrate. Film deposition vapors are generated from solid film precursor materials, including those in the form of wires or powders. The vapor from these sources is carried downstream in a low pressure supersonic jet of inert gas to the surface of a substrate where the vapors deposit to form a thin film. A reactant gas can be introduced into the gas jet to form a reaction product with the evaporated material. The substrate can be moved from the gas jet past a gas jet containing a reactant gas in which a discharge has been generated, the speed of movement being sufficient to form a thin film which is chemically composed of the evaporated material and reactant gases.

  12. Apparatus and method to inject a reductant into an exhaust gas feedstream

    DOE Patents [OSTI]

    Viola, Michael B. (Macomb Township, MI)

    2009-09-22

    An exhaust aftertreatment system for an internal combustion engine is provided including an apparatus and method to inject a reductant into the exhaust gas feedstream. Included is a fuel metering device adapted to inject reductant into the exhaust gas feedstream and a controllable pressure regulating device. A control module is operatively connected to the reductant metering device and the controllable pressure regulating device, and, adapted to effect flow of reductant into the exhaust gas feedstream over a controllable flow range.

  13. Optical methods and systems for detecting a constituent in a gas containing oxygen in harsh environments

    DOE Patents [OSTI]

    Carpenter, Michael A. (Scotia, NY); Sirinakis, George (Bronx, NY)

    2011-01-04

    A method for detecting a gas phase constituent such as carbon monoxide, nitrogen dioxide, hydrogen, or hydrocarbons in a gas comprising oxygen such as air, includes providing a sensing material or film having a metal embedded in a catalytically active matrix such as gold embedded in a yttria stabilized zirconia (YSZ) matrix. The method may include annealing the sensing material at about 900.degree. C., exposing the sensing material and gas to a temperature above 400.degree. C., projecting light onto the sensing material, and detecting a change in the absorption spectrum of the sensing material due to the exposure of the sensing material to the gas in air at the temperature which causes a chemical reaction in the sensing material compared to the absorption spectrum of the sensing material in the absence of the gas. Systems employing such a method are also disclosed.

  14. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Sinclair, B.W.

    1984-07-31

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a wellhead; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; separating LPG from gas vapors of the refrigerated natural gas; storing the separated LPG in a storage tank with a vapor space therein; and recirculating a portion of the LPG vapors in the storage tank with the natural gas exiting the wellhead to enhance recovery of LPG. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for refrigerating the compressed gases therefrom; at least one product separator downstream of the refrigerator unit for receiving refrigerated and compressed gases discharged from the refrigerator unit and separating LPG therein from gases remaining in vapor form; and a storage tank for receiving and storing the separated LPG therein, the storage tank having a vapor space therein connected upstream of the gas compressor through a pressure regulator allowing recirculation of some LPG vapors with the natural gases through said system.

  15. Gas turbine nozzle vane insert and methods of installation

    DOE Patents [OSTI]

    Miller, William John (Simpsonville, SC); Predmore, Daniel Ross (Clifton Park, NY); Placko, James Michael (West Chester, OH)

    2002-01-01

    A pair of hollow elongated insert bodies are disposed in one or more of the nozzle vane cavities of a nozzle stage of a gas turbine. Each insert body has an outer wall portion with apertures for impingement-cooling of nozzle wall portions in registration with the outer wall portion. The insert bodies are installed into the cavity separately and spreaders flex the bodies toward and to engage standoffs against wall portions of the nozzle whereby the designed impingement gap between the outer wall portions of the insert bodies and the nozzle wall portions is achieved. The spreaders are secured to the inner wall portions of the insert bodies and the bodies are secured to one another and to the nozzle vane by welding or brazing.

  16. Oil and Gas CDT Downscaling-Upscaling: A Robust Method of Linking

    E-Print Network [OSTI]

    Henderson, Gideon

    Oil and Gas CDT Downscaling-Upscaling: A Robust Method of Linking Geomechanical Simulations and Fluid Flow Simulations Heriot-Watt University, Institute of Petroleum Engineering Supervisory Team Prof Geomechanical simulation; fractures; strain; flow upscaling Overview Geomechanical simulations of trap

  17. Application of Fast Marching Method in Shale Gas Reservoir Model Calibration 

    E-Print Network [OSTI]

    Yang, Changdong

    2013-07-26

    and reservoir heterogeneity but also is time consuming. In this thesis, we propose and apply an efficient technique, fast marching method (FMM), to analyze the shale gas reservoirs. Our proposed approach stands midway between analytic techniques and numerical...

  18. A Simple, Fast Method of Estimating Fractured Reservoir Geometry...

    Open Energy Info (EERE)

    Fractured Reservoir Geometry from Tracer Tests Abstract A simple method of estimating flow geometry and pore geometry from conservative tracer tests in single phase geothermal...

  19. Analysis of Tracer Dispersion During a Prescribed Forest Burn

    E-Print Network [OSTI]

    Collins, Gary S.

    to manage global warming (Wiedinmyer, 2010) As land managers consider increased burning, air quality our understanding of pollutant emission rates associated with prescribed forest burns. Methods Site tracer and pollutant dispersion patterns. Modeling The WindTrax stochastic particle dispersion model

  20. Method of fabricating an integral gas seal for fuel cell gas distribution assemblies

    DOE Patents [OSTI]

    Dettling, Charles J. (E. Hanover, NJ); Terry, Peter L. (Chathum, NJ)

    1988-03-22

    A porous gas distribution plate assembly for a fuel cell, such as a bipolar assembly, includes an inner impervious region wherein the bipolar assembly has good surface porosity but no through-plane porosity and wherein electrical conductivity through the impervious region is maintained. A hot-pressing process for forming the bipolar assembly includes placing a layer of thermoplastic sealant material between a pair of porous, electrically conductive plates, applying pressure to the assembly at elevated temperature, and allowing the assembly to cool before removing the pressure whereby the layer of sealant material is melted and diffused into the porous plates to form an impervious bond along a common interface between the plates holding the porous plates together. The distribution of sealant within the pores along the surface of the plates provides an effective barrier at their common interface against through-plane transmission of gas.

  1. Integral gas seal for fuel cell gas distribution assemblies and method of fabrication

    DOE Patents [OSTI]

    Dettling, Charles J. (E. Hanover, NJ); Terry, Peter L. (Chatham Township, Morris County, NJ)

    1985-03-19

    A porous gas distribution plate assembly for a fuel cell, such as a bipolar assembly, includes an inner impervious region wherein the bipolar assembly has good surface porosity but no through-plane porosity and wherein electrical conductivity through the impervious region is maintained. A hot-pressing process for forming the bipolar assembly includes placing a layer of thermoplastic sealant material between a pair of porous, electrically conductive plates, applying pressure to the assembly at elevated temperature, and allowing the assembly to cool before removing the pressure whereby the layer of sealant material is melted and diffused into the porous plates to form an impervious bond along a common interface between the plates holding the porous plates together. The distribution of sealant within the pores along the surface of the plates provides an effective barrier at their common interface against through-plane transmission of gas.

  2. A method of evaluating the performance deterioration of aircraft gas-turbines 

    E-Print Network [OSTI]

    Subramanian, V

    1978-01-01

    A METHOD OF EVALUATING THE PERFORMANCE DETERIORATION OF AIRCRAFT GAS-TURBINES A Thesis by V. SUBRAMANIAN Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... May 1978 Major Subject: Mechanical Engineering A METHOD OF EVALUATING THE PERFORMANCE DETERIORATION OF AIRCRAFT GAS-TURBINES A Thesis by V. SUBRAMANIAN Approved as to style and content by: Charrman o Commztt (Head o D pa ment Sg D~ Member...

  3. Standard test method for determination of total hydrogen content of uranium oxide powders and pellets by carrier gas extraction

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2000-01-01

    Standard test method for determination of total hydrogen content of uranium oxide powders and pellets by carrier gas extraction

  4. Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    SciTech Connect (OSTI)

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2000-01-01

    A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

  5. A critical review of methods used in the estimation of natural gas reserves 

    E-Print Network [OSTI]

    Gruy, Henry Jones

    1956-01-01

    for the de- gree of PROFESSIONAL ENGINEER MA JOR SU% JEGT: PETROLEUM ENGINEERING itay f956 A GR1TLGAL REVXE? 0$' METHODS gSED THE ESTIMATION op NATURAL GAS RESERVES 8y Henry J. Gruy Approved as to style and content by Ghairman of C, ommittee hiay... l956 ThSLK OF CONTENTS hhstract Iatroductioa LLLstorF of Esthaatioa ef Gas Reserves Preseat Methods of Kstimatlag Oas ileserves 6 Methods of Kstimatiag Nm-hssociated flas Reserves 6 Volametric Method 6 Discassfea of Che Factors La...

  6. Apparatus and method for a gas turbine nozzle

    DOE Patents [OSTI]

    Zuo, Baifang; Ziminsky, Willy Steve; Johnson, Thomas Edward; Intile, John Charles; Lacy, Benjamin Paul

    2013-02-05

    A nozzle includes an inlet, an outlet, and an axial centerline. A shroud surrounding the axial centerline extends from the inlet to the outlet and defines a circumference. The circumference proximate the inlet is greater than the circumference at a first point downstream of the inlet, and the circumference at the first point downstream of the inlet is less than the circumference at a second point downstream of the first point. A method for supplying a fuel through a nozzle directs a first airflow along a first path and a second airflow along a second path separate from the first path. The method further includes injecting the fuel into at least one of the first path or the second path and accelerating at least one of the first airflow or the second airflow.

  7. Control method for turbocharged diesel engines having exhaust gas recirculation

    SciTech Connect (OSTI)

    Kolmanovsky, I.V.; Jankovic, M.J.; Jankovic, M.

    2000-03-14

    A method of controlling the airflow into a compression ignition engine having an EGR and a VGT. The control strategy includes the steps of generating desired EGR and VGT turbine mass flow rates as a function of the desired and measured compressor mass airflow values and exhaust manifold pressure values. The desired compressor mass airflow and exhaust manifold pressure values are generated as a function of the operator-requested fueling rate and engine speed. The EGR and VGT turbine mass flow rates are then inverted to corresponding EGR and VGT actuator positions to achieve the desired compressor mass airflow rate and exhaust manifold pressure. The control strategy also includes a method of estimating the intake manifold pressure used in generating the EGR valve and VGT turbine positions.

  8. SENSITIVITY OF A REACTIVE-TRACER BASED ESTIMATE OF THERMAL BREAKTHROUGH IN AN EGS TO PROPERTIES OF THE RESERVOIR AND TRACER

    SciTech Connect (OSTI)

    Mitchell A. Plummer; Carl D. Palmer; Laurence C. Hull; Earl D. Mattson

    2010-02-01

    Reactive tracers have long been considered a possible means of measuring thermal drawdown in a geothermal system, before significant cooling occurs at the extraction well. Here, we examine the sensitivity of the proposed method to reservoir cooling and demonstrate that while the sensitivity of the method as generally proposed is low, it may be practical under certain conditions. Our analyses suggest that modifications to that method, where practical, could provide much greater sensitivity. In particular, if the reaction can be quenched before maximum temperature is reached, the sensitivity is greatly enhanced. Push-pull tracer tests conducted at the injection well demonstrate similar advantages. Other alternatives, such as combinations of tracers, and tracers with parallel or chain decay behavior may offer similar advantages.

  9. Method for the photocatalytic conversion of gas hydrates

    DOE Patents [OSTI]

    Taylor, Charles E. (Pittsburg, PA); Noceti, Richard P. (Pittsburg, PA); Bockrath, Bradley C. (Bethel Park, PA)

    2001-01-01

    A method for converting methane hydrates to methanol, as well as hydrogen, through exposure to light. The process includes conversion of methane hydrates by light where a radical initiator has been added, and may be modified to include the conversion of methane hydrates with light where a photocatalyst doped by a suitable metal and an electron transfer agent to produce methanol and hydrogen. The present invention operates at temperatures below 0.degree. C., and allows for the direct conversion of methane contained within the hydrate in situ.

  10. Methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Nelson, Lee O. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

    2009-02-24

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  11. Horizontal natural gas storage caverns and methods for producing same

    DOE Patents [OSTI]

    Russo, Anthony (Albuquerque, NM)

    1995-01-01

    The invention provides caverns and methods for producing caverns in bedded salt deposits for the storage of materials that are not solvents for salt. The contemplated salt deposits are of the bedded, non-domed variety, more particularly salt found in layered formations that are sufficiently thick to enable the production of commercially usefully sized caverns completely encompassed by walls of salt of the formation. In a preferred method, a first bore hole is drilled into the salt formation and a cavity for receiving insolubles is leached from the salt formation. Thereafter, at a predetermined distance away from the first bore hole, a second bore hole is drilled towards the salt formation. As this drill approaches the salt, the drill assumes a slant approach and enters the salt and drills through it in a horizontal direction until it intersects the cavity for receiving insolubles. This produces a substantially horizontal conduit from which solvent is controlledly supplied to the surrounding salt formation, leaching the salt and producing a concentrated brine which is removed through the first bore hole. Insolubles are collected in the cavity for receiving insolubles. By controlledly supplying solvent, a horizontal cavern is produced with two bore holes extending therefrom.

  12. High upwind concentrations observed during an upslope tracer event

    SciTech Connect (OSTI)

    Ciolek, J.T. Jr.

    1993-10-01

    In February of 1991 the Rocky Flats Plant conducted twelve tracer experiments to validate an emergency response dispersion model known as the Terrain-Responsive Atmospheric Code (TRAC) (Hodgin 1985). Experimenters released 140 to 260 kilograms of inert tracer gas (sulfur hexafloride) from the plant over an 11 hour period. During each release, one hundred and sixty-five samples, most of which formed concentric rings of 8 and 16 km radius from the plant, recorded cumulative hourly concentrations of the tracer at one meter above ground level (AGL). Figure 1 contains a depiction of the sampler location, the terrain, and the meteorological stations available within the tracer study area. Brown (1991) describes the experimental setup in more detail. The subject of this paper is an event that occurred early in the fifth experiment, on February 9, 1991. In this experiment, tracer material released from 13:00 to 17:00 LST appeared both downwind and upwind of the source, with the highest concentrations upwind. During the fifth experiment, high pressure in Utah produced mostly sunny skis around Rocky Flats. For most of the day, one could find moderate (5 to 10 ms{sup {minus}1}) northerly (from the North) flow within the 700 to 500 mb level of the atmosphere (approximately 3000 to 5500 meters above Mean Sea Level (MSL)). Synoptic scale motions were isolated enough from the surface layer and heating was great enough to produce a 1 km deep upslope flow (flow from the East to the West) by late afternoon. The winds reversed and became downslope at approximately 17:30 LST.

  13. 5, 58415874, 2005 Ozone/tracer

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et al. Title Page Discussions Impact of mixing and chemical change on ozone-tracer relations in the polar vortex R. M¨uller 1 Commons License. 5841 #12;ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et

  14. Method and apparatus for filtering gas with a moving granular filter bed

    DOE Patents [OSTI]

    Brown, Robert C. (Ames, IA); Wistrom, Corey (Ames, IA); Smeenk, Jerod L. (Ames, IA)

    2007-12-18

    A method and apparatus for filtering gas (58) with a moving granular filter bed (48) involves moving a mass of particulate filter material (48) downwardly through a filter compartment (35); tangentially introducing gas into the compartment (54) to move in a cyclonic path downwardly around the moving filter material (48); diverting the cyclonic path (58) to a vertical path (62) to cause the gas to directly interface with the particulate filter material (48); thence causing the gas to move upwardly through the filter material (48) through a screened partition (24, 32) into a static upper compartment (22) of a filter compartment for exodus (56) of the gas which has passed through the particulate filter material (48).

  15. Advancing New 3D Seismic Interpretation Methods for Exploration and Development of Fractured Tight Gas Reservoirs

    SciTech Connect (OSTI)

    James Reeves

    2005-01-31

    In a study funded by the U.S. Department of Energy and GeoSpectrum, Inc., new P-wave 3D seismic interpretation methods to characterize fractured gas reservoirs are developed. A data driven exploratory approach is used to determine empirical relationships for reservoir properties. Fractures are predicted using seismic lineament mapping through a series of horizon and time slices in the reservoir zone. A seismic lineament is a linear feature seen in a slice through the seismic volume that has negligible vertical offset. We interpret that in regions of high seismic lineament density there is a greater likelihood of fractured reservoir. Seismic AVO attributes are developed to map brittle reservoir rock (low clay) and gas content. Brittle rocks are interpreted to be more fractured when seismic lineaments are present. The most important attribute developed in this study is the gas sensitive phase gradient (a new AVO attribute), as reservoir fractures may provide a plumbing system for both water and gas. Success is obtained when economic gas and oil discoveries are found. In a gas field previously plagued with poor drilling results, four new wells were spotted using the new methodology and recently drilled. The wells have estimated best of 12-months production indicators of 2106, 1652, 941, and 227 MCFGPD. The latter well was drilled in a region of swarming seismic lineaments but has poor gas sensitive phase gradient (AVO) and clay volume attributes. GeoSpectrum advised the unit operators that this location did not appear to have significant Lower Dakota gas before the well was drilled. The other three wells are considered good wells in this part of the basin and among the best wells in the area. These new drilling results have nearly doubled the gas production and the value of the field. The interpretation method is ready for commercialization and gas exploration and development. The new technology is adaptable to conventional lower cost 3D seismic surveys.

  16. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  17. Method and apparatus for perforating at cutting with a solid fueled gas mixture

    SciTech Connect (OSTI)

    Woytek, A.J.; Lileck, J.T.; Steigerwalt, E.J.

    1984-05-08

    A method for cutting pipe casings and concrete liners or perforating the same and localized portions of surrounding strata in an earth bore is set forth wherein a gas phase cutting or perforating jet mixture of fluorine and nitrogen trifluoride is delivered to the cutting or perforation site from the decomposition of a solid, normally stable, perfluoroammonium salt. An appropriate apparatus for delivering the gas mixture of fluorine and nitrogen trifluoride from the salt is also disclosed.

  18. Thermal chemical recuperation method and system for use with gas turbine systems

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Bannister, R.L.

    1999-04-27

    A system and method are disclosed for efficiently generating power using a gas turbine, a steam generating system and a reformer. The gas turbine receives a reformed fuel stream and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer. The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine. 2 figs.

  19. Thermal chemical recuperation method and system for use with gas turbine systems

    DOE Patents [OSTI]

    Yang, Wen-Ching (Export, PA); Newby, Richard A. (Pittsburgh, PA); Bannister, Ronald L. (Winter Springs, FL)

    1999-01-01

    A system and method for efficiently generating power using a gas turbine, a steam generating system (20, 22, 78) and a reformer. The gas turbine receives a reformed fuel stream (74) and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer (18). The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine.

  20. Tracers for Characterizing Enhanced Geothermal Systems

    SciTech Connect (OSTI)

    Karen Wright; George Redden; Carl D. Palmer; Harry Rollins; Mark Stone; Mason Harrup; Laurence C. Hull

    2010-02-01

    Information about the times of thermal breakthrough and subsequent rates of thermal drawdown in enhanced geothermal systems (EGS) is necessary for reservoir management, designing fracture stimulation and well drilling programs, and forecasting economic return. Thermal breakthrough in heterogeneous porous media can be estimated using conservative tracers and assumptions about heat transfer rates; however, tracers that undergo temperature-dependent changes can provide more detailed information about the thermal profile along the flow path through the reservoir. To be effectively applied, the thermal reaction rates of such temperature sensitive traces must be well characterized for the range of conditions that exist in geothermal systems. Reactive tracers proposed in the literature include benzoic and carboxylic acids (Adams) and organic esters and amides (Robinson et al.); however, the practical temperature range over which these tracers can be applied (100-275°C) is somewhat limited. Further, for organic esters and amides, little is known about their sorption to the reservoir matrix and how such reactions impact data interpretation. Another approach involves tracers where the reference condition is internal to the tracer itself. Two examples are: 1) racemization of polymeric amino acids, and 2) mineral thermoluminescence. In these cases internal ratios of states are measured rather than extents of degradation and mass loss. Racemization of poly-L-lactic acid (for example) is temperature sensitive and therefore can be used as a temperature-recording tracer depending on the rates of racemization and stability of the amino acids. Heat-induced quenching of thermoluminescence of pre-irradiated LiF can also be used. To protect the tracers from alterations (extraneous reactions, dissolution) in geothermal environments we are encapsulating the tracers in core-shell colloidal structures that will subsequently be tested for their ability to be transported and to protect the tracers from incidental reactions. We review the criteria for practical reactive tracers, which serves as the basis for experimental testing and characterization and can be used to identify other potential candidate tracers. We will also discuss the information obtainable from individual tracers, which has implications for using multiple tracers to obtain information about the thermal history of a reservoir. We will provide an update on our progress for conducting proof-of-principle tests for reactive tracers in the Raft River geothermal system.

  1. Apparatus For The Liquefaaction Of Natural Gas And Methods Relating To Same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID); Bingham, Dennis N. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID); Rateman, Kevin T. (Idaho Falls, ID); Palmer, Gary L. (Shelley, ID); Klinger, Kerry M. (Idaho Falls, ID); Vranicar, John J. (Concord, CA)

    2005-11-08

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO2) clean-up cycle.

  2. Apparatus For The Liquefaaction Of Natural Gas And Methods Relating To Same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID); Bingham, Dennis N. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID); Raterman, Kevin T. (Idaho Falls, ID); Palmer, Gary L. (Shelley, ID); Klingler, Kerry M. (Idaho Falls, ID); Vranicar, John J. (Concord, CA)

    2005-05-03

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO2) clean-up cycle.

  3. Apparatus For The Liquefaaction Of Natural Gas And Methods Relating To Same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID); Bingham, Dennis N. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID); Raterman, Kevin T. (Idaho Falls, ID); Palmer, Gary L. (Shelley, ID); Klingler, Kerry M. (Idaho Falls, ID); Vranicar, John J. (Concord, CA)

    2003-06-24

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO.sub.2) clean-up cycle.

  4. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID); Bingham, Dennis N. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID); Raterman, Kevin T. (Idaho Falls, ID); Palmer, Gary L. (Shelley, ID); Klingler, Kerry M. (Idaho Falls, ID); Vranicar, John J. (Concord, CA)

    2007-05-22

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO.sub.2) clean-up cycle.

  5. Evaporation system and method for gas jet deposition of thin film materials

    DOE Patents [OSTI]

    Schmitt, J.J.; Halpern, B.L.

    1994-10-18

    A method and apparatus are disclosed for depositing thin films of materials such as metals, oxides and nitrides at low temperature relies on a supersonic free jet of inert carrier gas to transport vapor species generated from an evaporation source to the surface of a substrate. Film deposition vapors are generated from solid film precursor materials, including those in the form of wires or powders. The vapor from these sources is carried downstream in a low pressure supersonic jet of inert gas to the surface of a substrate where the vapors deposit to form a thin film. A reactant gas can be introduced into the gas jet to form a reaction product with the evaporated material. The substrate can be moved from the gas jet past a gas jet containing a reactant gas in which a discharge has been generated, the speed of movement being sufficient to form a thin film which is chemically composed of the evaporated material and reactant gases. 8 figs.

  6. Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2001-03-27

    A hydrocarbon fuel reforming method is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first mixture of an oxygen-containing gas and a first fuel is directed into a first tube 108 to produce a first reaction reformate. A second mixture of steam and a second fuel is directed into a second tube 116 annularly disposed about the first tube 108 to produce a second reaction reformate. The first and second reaction reformates are then directed into a reforming zone 144 and subject to a catalytic reforming reaction. In another aspect of the method, a first fuel is combusted with an oxygen-containing gas in a first zone 108 to produce a reformate stream, while a second fuel under steam reforming in a second zone 116. Heat energy from the first zone 108 is transferred to the second zone 116.

  7. Cooling air recycling for gas turbine transition duct end frame and related method

    DOE Patents [OSTI]

    Cromer, Robert Harold (Johnstown, NY); Bechtel, William Theodore (Scotia, NY); Sutcu, Maz (Niskayuna, NY)

    2002-01-01

    A method of cooling a transition duct end frame in a gas turbine includes the steps of a) directing cooling air into the end frame from a region external of the transition duct and the impingement cooling sleeve; and b) redirecting the cooling air from the end frame into the annulus between the transition duct and the impingement cooling sleeve.

  8. Method to prevent recession loss of silica and silicon-containing materials in combustion gas environments

    DOE Patents [OSTI]

    Brun, Milivoj Konstantin (Ballston Lake, NY); Luthra, Krishan Lal (Niskayuna, NY)

    2003-01-01

    While silicon-containing ceramics or ceramic composites are prone to material loss in combustion gas environments, this invention introduces a method to prevent or greatly reduce the thickness loss by injecting directly an effective amount, generally in the part per million level, of silicon or silicon-containing compounds into the combustion gases.

  9. Method of purifying a gas stream using 1,2,3-triazolium ionic liquids

    DOE Patents [OSTI]

    Luebke, David; Nulwala, Hunald; Tang, Chau

    2014-12-09

    A method for separating a target gas from a gaseous mixture using 1,2,3-triazolium ionic liquids is presented. Industrial effluent streams may be cleaned by removing carbon dioxide from the stream by contacting the effluent stream with a 1,2,3-triazolium ionic liquid compound.

  10. Carbon nanocomposite sorbent and methods of using the same for separation of one or more materials from a gas stream

    DOE Patents [OSTI]

    Olson, Edwin S; Pavlish, John H

    2015-04-21

    The present invention relates to carbon nanocomposite sorbents. The present invention provides carbon nanocomposite sorbents, methods for making the same, and methods for separation of a pollutant from a gas that includes that pollutant. Various embodiments provide a method for reducing the mercury content of a mercury-containing gas.

  11. Unraveling DPF Degradation using Chemical Tracers and Opportunities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Unraveling DPF Degradation using Chemical Tracers and Opportunities for Extending Filter Life Unraveling DPF Degradation using Chemical Tracers and Opportunities for Extending...

  12. Patient Positioning Based on a Radioactive Tracer Implanted in Patients With Localized Prostate Cancer: A Performance and Safety Evaluation

    SciTech Connect (OSTI)

    Kruijf, Willy J.M. de, E-mail: kruijf.de.w@bvi.nl [Institute Verbeeten, Tilburg (Netherlands); Verstraete, Jan [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium)] [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium); Neustadter, David [Navotek Medical Ltd, Yokneam (Israel)] [Navotek Medical Ltd, Yokneam (Israel); Corn, Benjamin W. [Tel Aviv Medical Center, Tel Aviv (Israel)] [Tel Aviv Medical Center, Tel Aviv (Israel); Hol, Sandra; Venselaar, Jack L.M. [Institute Verbeeten, Tilburg (Netherlands)] [Institute Verbeeten, Tilburg (Netherlands); Davits, Rob J.; Wijsman, Bart P. [TweeSteden Hospital, Tilburg (Netherlands)] [TweeSteden Hospital, Tilburg (Netherlands); Van den Bergh, Laura; Budiharto, Tom [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium)] [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium); Oyen, Raymond [Department of Radiology, University Hospitals Leuven, Leuven (Belgium)] [Department of Radiology, University Hospitals Leuven, Leuven (Belgium); Haustermans, Karin [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium)] [Department of Radiation Oncology, Leuven Cancer Institute, University Hospitals Leuven, Leuven (Belgium); Poortmans, Philip M.P. [Institute Verbeeten, Tilburg (Netherlands)] [Institute Verbeeten, Tilburg (Netherlands)

    2013-02-01

    Purpose: To evaluate the performance and safety of a radiation therapy positioning system (RealEye) based on tracking a radioactive marker (Tracer) implanted in patients with localized prostate cancer. Methods and Materials: We performed a single-arm multi-institutional trial in 20 patients. The iridium-192 ({sup 192}Ir)-containing Tracer was implanted in the patient together with 4 standard gold seed fiducials. Patient prostate-related symptoms were evaluated with the International Prostate Symptom Score (IPSS) questionnaire. Computed tomography (CT) was performed for treatment planning, during treatment, and after treatment to evaluate the migration stability of the Tracer. At 5 treatment sessions, cone beam CT was performed to test the positioning accuracy of the RealEye. Results: The Tracer was successfully implanted in all patients. No device or procedure-related adverse events occurred. Changes in IPSS scores were limited. The difference between the mean change in Tracer-fiducial distance and the mean change in fiducial-fiducial distance was -0.39 mm (95% confidence interval [CI] upper boundary, -0.22 mm). The adjusted mean difference between Tracer position according to RealEye and the Tracer position on the CBCT for all patients was 1.34 mm (95% CI upper boundary, 1.41 mm). Conclusions: Implantation of the Tracer is feasible and safe. Migration stability of the Tracer is good. Prostate patients can be positioned and monitored accurately by using RealEye.

  13. Standard test method for isotopic analysis of uranium hexafluoride by double standard single-collector gas mass spectrometer method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1 and 5.0 mass %. 1.2 This test method may be applicable for the entire range of 235U concentrations for which adequate standards are available. 1.3 This test method is for analysis by a gas magnetic sector mass spectrometer with a single collector using interpolation to determine the isotopic concentration of an unknown sample between two characterized UF6 standards. 1.4 This test method is to replace the existing test method currently published in Test Methods C761 and is used in the nuclear fuel cycle for UF6 isotopic analyses. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appro...

  14. Decision Matrix Screening Tool to Identify the Best Artificial Lift Method for Liquid-loaded Gas Wells 

    E-Print Network [OSTI]

    Soponsakulkaew, Nitsupon

    2010-10-12

    Liquid loading is a serious problem in gas wells. Many proven artificial lift methods have been used to alleviate this problem. However, a complete workflow to determine the most suitable artificial lift method for given well conditions does...

  15. Method and apparatus for confinement of ions in the presence of a neutral gas

    DOE Patents [OSTI]

    Peurrung, Anthony J. (Richland, WA); Barlow, Stephan E. (Richland, WA)

    1999-01-01

    The present invention is an apparatus and method for combining ions with a neutral gas and flowing the mixture with a radial flow component through a magnetic field so that the weakly ionized gas is confined by the neutral gas. When the weakly ionized gas is present in sufficient density, a weakly ionized non-neutral plasma is formed that may be trapped in accordance with the present invention. Applications for a weakly ionized non-neutral plasma exploit the trap's ability to store and manipulate ionic species in the presence of neutral gas. The trap may be connected to a mass spectrometer thereby permitting species identification after a fixed period of time. Delicate and/or heavy particles such as clusters may be held and studied in a "gentle" environment. In addition, the trap can provide a relatively intense, low-energy source of a particular ion species for surface implantation or molecular chemistry. Finally, a long trap may permit spectroscopy of unprecedented accuracy to be performed on ionic species.

  16. Method and apparatus for confinement of ions in the presence of a neutral gas

    DOE Patents [OSTI]

    Peurrung, A.J.; Barlow, S.E.

    1999-08-03

    The present invention is an apparatus and method for combining ions with a neutral gas and flowing the mixture with a radial flow component through a magnetic field so that the weakly ionized gas is confined by the neutral gas. When the weakly ionized gas is present in sufficient density, a weakly ionized non-neutral plasma is formed that may be trapped in accordance with the present invention. Applications for a weakly ionized non-neutral plasma exploit the trap`s ability to store and manipulate ionic species in the presence of neutral gas. The trap may be connected to a mass spectrometer thereby permitting species identification after a fixed period of time. Delicate and/or heavy particles such as clusters may be held and studied in a ``gentle`` environment. In addition, the trap can provide a relatively intense, low-energy source of a particular ion species for surface implantation or molecular chemistry. Finally, a long trap may permit spectroscopy of unprecedented accuracy to be performed on ionic species. 4 figs.

  17. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01

    Section B (NIMB) Using Biofuel Tracers to Study Alternativeinjection. We investigate biofuel HCCI combustion, and use

  18. Method for forming synthesis gas using a plasma-catalyzed fuel reformer

    DOE Patents [OSTI]

    Hartvigsen, Joseph J; Elangovan, S; Czernichowski, Piotr; Hollist, Michele

    2015-04-28

    A method of forming a synthesis gas utilizing a reformer is disclosed. The method utilizes a reformer that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding apparatus and system are also disclosed herein.

  19. Method and apparatus to selectively reduce NO.sub.x in an exhaust gas feedstream

    DOE Patents [OSTI]

    Schmieg, Steven J. (Troy, MI); Blint, Richard J. (Shelby Township, MI); Den, Ling (Sterling Heights, MI); Viola, Michael B. (Macomb Township, MI); Lee, Jong-Hwan (Rochester Hills, MI)

    2011-08-30

    A method and apparatus are described to selectively reduce NO.sub.x emissions of an internal combustion engine. An exhaust aftertreatment system includes an injection device operative to dispense a hydrocarbon reductant upstream of a silver-alumina catalytic reactor device. A control system determines a NO.sub.x concentration and hydrocarbon/NOx ratio based upon selected parameters of the exhaust gas feedstream and dispenses hydrocarbon reductant during lean engine operation. Included is a method to control elements of the feedstream during lean operation. The hydrocarbon reductant may include engine fuel.

  20. Method of detecting leakage from geologic formations used to sequester CO.sub.2

    DOE Patents [OSTI]

    White, Curt (Pittsburgh, PA); Wells, Arthur (Bridgeville, PA); Diehl, J. Rodney (Pittsburgh, PA); Strazisar, Brian (Venetia, PA)

    2010-04-27

    The invention provides methods for the measurement of carbon dioxide leakage from sequestration reservoirs. Tracer moieties are injected along with carbon dioxide into geological formations. Leakage is monitored by gas chromatographic analyses of absorbents. The invention also provides a process for the early leak detection of possible carbon dioxide leakage from sequestration reservoirs by measuring methane (CH.sub.4), ethane (C.sub.2H.sub.6), propane (C.sub.3H.sub.8), and/or radon (Rn) leakage rates from the reservoirs. The invention further provides a method for branding sequestered carbon dioxide using perfluorcarbon tracers (PFTs) to show ownership.

  1. A critical review of methods used in the estimation of natural gas reserves: Natural gas reserves in the state of Texas. Some educational prerequisites in the field of petroleum economics and evaluation. 

    E-Print Network [OSTI]

    Crichton, John Alston

    1953-01-01

    A CRITICAL REVIEW OF METHODS USED IN THE ESTIMATION OF NATURAL GAS RESERVES NATURAL GAS RESERVES IN THE SI'AT. S OF TEXAS SOME EDUCATIONAL PREREQUISITES IN THE FIELD OF PETROLEUM ECONOMICS AND EVAI UATION Sy John Alston Crichton... ENGINEERING TABLE of CONTENTS ~Pa e A CRITICAL REVIEW OF METHODS USED IN THE ESTIMATION OF NATURAL GAS RESERVES Abstract Introdu=tion History of the Estimation of Gas Reserves Present Methods of Estimating Gas Reserves Meth& ds of Estimating Non...

  2. Method for the catalytic conversion of organic materials into a product gas

    DOE Patents [OSTI]

    Elliott, Douglas C. (Richland, WA); Sealock, Jr., L. John (Richland, WA); Baker, Eddie G. (Richland, WA)

    1997-01-01

    A method for converting organic material into a product gas includes: a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300.degree. C. to about 450.degree. C.; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen.

  3. Method for the catalytic conversion of organic materials into a product gas

    DOE Patents [OSTI]

    Elliott, D.C.; Sealock, L.J. Jr.; Baker, E.G.

    1997-04-01

    A method for converting organic material into a product gas includes: (a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; (b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and (c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300 C to about 450 C; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen. 5 figs.

  4. Methods for manufacturing porous nuclear fuel elements for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L. (Albuquerque, NM); Williams, Brian E. (Pocoima, CA); Benander, Robert E. (Pacoima, CA)

    2010-02-23

    Methods for manufacturing porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's). Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, a thin coating of nuclear fuel may be deposited inside of a highly porous skeletal structure made, for example, of reticulated vitreous carbon foam.

  5. Method of making improved gas storage carbon with enhanced thermal conductivity

    DOE Patents [OSTI]

    Burchell, Timothy D. (Oak Ridge, TN); Rogers, Michael R. (Knoxville, TN)

    2002-11-05

    A method of making an adsorbent carbon fiber based monolith having improved methane gas storage capabilities is disclosed. Additionally, the monolithic nature of the storage carbon allows it to exhibit greater thermal conductivity than conventional granular activated carbon or powdered activated carbon storage beds. The storage of methane gas is achieved through the process of physical adsorption in the micropores that are developed in the structure of the adsorbent monolith. The disclosed monolith is capable of storing greater than 150 V/V of methane [i.e., >150 STP (101.325 KPa, 298K) volumes of methane per unit volume of storage vessel internal volume] at a pressure of 3.5 MPa (500 psi).

  6. Method for resurrecting negative electron affinity photocathodes after exposure to an oxidizing gas

    DOE Patents [OSTI]

    Mulhollan, Gregory A; Bierman, John C

    2012-10-30

    A method by which negative electron affinity photocathodes (201), single crystal, amorphous, or otherwise ordered, can be made to recover their quantum yield following exposure to an oxidizing gas has been discovered. Conventional recovery methods employ the use of cesium as a positive acting agent (104). In the improved recovery method, an electron beam (205), sufficiently energetic to generate a secondary electron cloud (207), is applied to the photocathode in need of recovery. The energetic beam, through the high secondary electron yield of the negative electron affinity surface (203), creates sufficient numbers of low energy electrons which act on the reduced-yield surface so as to negate the effects of absorbed oxidizing atoms thereby recovering the quantum yield to a pre-decay value.

  7. An alternative method of gas boriding applied to the formation of borocarburized layer

    SciTech Connect (OSTI)

    Kulka, M. Makuch, N.; Pertek, A.; Piasecki, A.

    2012-10-15

    The borocarburized layers were produced by tandem diffusion processes: carburizing followed by boriding. An alternative method of gas boriding was proposed. Two-stage gas boronizing in N{sub 2}-H{sub 2}-BCl{sub 3} atmosphere was applied to the formation of iron borides on a carburized substrate. This process consisted in two stages, which were alternately repeated: saturation by boron and diffusion annealing. The microstructure and microhardness of produced layer were compared to those-obtained in case of continuous gas boriding in H{sub 2}-BCl{sub 3} atmosphere, earlier used. The first objective of two-stage boronizing, consisting in acceleration of boron diffusion, has been efficiently implemented. Despite the lower temperature and shorter duration of boronizing, about 1.5 times larger iron borides' zone has been formed on carburized steel. Second objective, the absolute elimination of brittle FeB phase, has failed. However, the amount of FeB phase has been considerably limited. Longer diffusion annealing should provide the boride layer with single-phase microstructure, without FeB phase. - Highlights: Black-Right-Pointing-Pointer Alternative method of gas boriding in H{sub 2}-N{sub 2}-BCl{sub 3} atmosphere was proposed. Black-Right-Pointing-Pointer The process consisted in two stages: saturation by boron and diffusion annealing. Black-Right-Pointing-Pointer These stages of short duration were alternately repeated. Black-Right-Pointing-Pointer The acceleration of boron diffusion was efficiently implemented. Black-Right-Pointing-Pointer The amount of FeB phase in the boride zone was limited.

  8. A System And Method To Determine Thermophysical Properties Of A Multi-Component Gas At Arbitrary Temperature And Pressure

    DOE Patents [OSTI]

    Morrow, Thomas E. (San Antonio, TX); Behring, II, Kendricks A. (Gilbert, AZ)

    2004-03-09

    A method to determine thermodynamic properties of a natural gas hydrocarbon, when the speed of sound in the gas is known at an arbitrary temperature and pressure. Thus, the known parameters are the sound speed, temperature, pressure, and concentrations of any dilute components of the gas. The method uses a set of reference gases and their calculated density and speed of sound values to estimate the density of the subject gas. Additional calculations can be made to estimate the molecular weight of the subject gas, which can then be used as the basis for mass flow calculations, to determine the speed of sound at standard pressure and temperature, and to determine various thermophysical characteristics of the gas.

  9. Importance Sampling Variance Reduction for the Fokker-Planck Rarefied Gas Particle Method

    E-Print Network [OSTI]

    Collyer, Benjamin; Lockerby, Duncan

    2015-01-01

    Models and methods that are able to accurately and efficiently predict the flows of low-speed rarefied gases are in high demand, due to the increasing ability to manufacture devices at micro and nano scales. One such model and method is a Fokker-Planck approximation to the Boltzmann equation, which can be solved numerically by a stochastic particle method. The stochastic nature of this method leads to noisy estimates of the thermodynamic quantities one wishes to sample when the signal is small in comparison to the thermal velocity of the gas. Recently, Gorji et al have proposed a method which is able to greatly reduce the variance of the estimators, by creating a correlated stochastic process which acts as a control variate for the noisy estimates. However, there are potential difficulties involved when the geometry of the problem is complex, as the method requires the density to be solved for independently. Importance sampling is a variance reduction technique that has already been shown to successfully redu...

  10. Method and apparatus for the gas phase decontamination of chemical and biological agents

    DOE Patents [OSTI]

    O'Neill, Hugh J.; Brubaker, Kenneth L.

    2003-10-07

    An apparatus and method for decontaminating chemical and biological agents using the reactive properties of both the single atomic oxygen and the hydroxyl radical for the decontamination of chemical and biological agents. The apparatus is self contained and portable and allows for the application of gas reactants directly at the required decontamination point. The system provides for the use of ultraviolet light of a specific spectral range to photolytically break down ozone into molecular oxygen and hydroxyl radicals where some of the molecular oxygen is in the first excited state. The excited molecular oxygen will combine with water vapor to produce two hydroxyl radicals.

  11. Method for gas bubble and void control and removal from metals

    DOE Patents [OSTI]

    Van Siclen, Clinton D. (Idaho Falls, ID); Wright, Richard N. (Idaho Falls, ID)

    1996-01-01

    A method for enhancing the diffusion of gas bubbles or voids attached to impurity precipitates, and biasing their direction of migration out of the host metal (or metal alloy) by applying a temperature gradient across the host metal (or metal alloy). In the preferred embodiment of the present invention, the impurity metal is insoluble in the host metal and has a melting point lower than the melting point of the host material. Also, preferably the impurity metal is lead or indium and the host metal is aluminum or a metal alloy.

  12. DEVELOPMENT AND FIELD IMPLEMENTATION OF AN IMPROVED METHOD FOR HEADSPACE GAS SAMPLING OF TRANSURANIC WASTE DRUMS

    SciTech Connect (OSTI)

    Polley, M.; Ankrom, J.; Wickland, T.; Warren, J.

    2003-02-27

    A fast, safe, and cost-effective method for obtaining headspace gas samples has been developed and implemented at Los Alamos National Laboratory (LANL). A sample port is installed directly into a drum lid using a pneumatic driver, allowing sampling with a side-port needle. Testing has shown that the sample port can be installed with no release of radioactive material. Use of this system at LANL has significantly reduced the time required for sampling, and eliminates the need for many safety precautions previously used. The system has significantly improved productivity and lowered radiation exposure and cost.

  13. Method for gas bubble and void control and removal from metals

    DOE Patents [OSTI]

    Siclen, C.D. Van; Wright, R.N.

    1996-02-06

    A method is described for enhancing the diffusion of gas bubbles or voids attached to impurity precipitates, and biasing their direction of migration out of the host metal (or metal alloy) by applying a temperature gradient across the host metal (or metal alloy). In the preferred embodiment of the present invention, the impurity metal is insoluble in the host metal and has a melting point lower than the melting point of the host material. Also, preferably the impurity metal is lead or indium and the host metal is aluminum or a metal alloy. 2 figs.

  14. Means and method for the destruction of particles entrained in a gas stream

    DOE Patents [OSTI]

    Botts, Thomas E. (Wading River, NY); Powell, James R. (Shoreham, NY)

    1980-01-01

    An apparatus and method for the destruction of particles entrained in a gas stream are disclosed. Destruction in the context of the subject invention means the fragmentation and/or vaporization of particles above a certain size limit. The subject invention contemplates destroying such particles by exposing them to intense bursts of laser light, such light having a frequency approximately equal to or less than the mean size of such particles. This invention is particularly adopted to the protection of turbine blades in open cycle coal-fired turbine systems. Means for introducing various chemical species and activating them by exposure to laser light are also disclosed.

  15. Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2000-09-26

    A method is disclosed for synthesizing hydrogen gas from hydrocarbon fuel. A first mixture of steam and a first fuel is directed into a first tube 208 to subject the first mixture to a first steam reforming reaction in the presence of a first catalyst 214. A stream of oxygen-containing gas is pre-heated by transferring heat energy from product gases. A second mixture of the pre-heated oxygen-containing gas and a second fuel is directed into a second tube 218 disposed about the first tube 208 to subject the second mixture to a partial oxidation reaction and to provide heat energy for transfer to the first tube 208. A first reaction reformate from the first tube 208 and a second reaction reformate from the second tube 218 are directed into a third tube 224 disposed about the second tube 218 to subject the first and second reaction reformates to a second steam reforming reaction, wherein heat energy is transferred to the third tube 224 from the second tube 218.

  16. On-line fast response device and method for measuring dissolved gas in a fluid

    DOE Patents [OSTI]

    Tutu, Narinder Kumar (Manorville, NY)

    2011-01-11

    A method and device for the measurement of dissolved gas within a fluid. The fluid, substantially a liquid, is pumped into a pipe. The flow of the fluid is temporally restricted, creating one or more low pressure regions. A measurement indicative of trapped air is taken before and after the restriction. The amount of dissolved air is calculated from the difference between the first and second measurements. Preferably measurements indicative of trapped air is obtained from one or more pressure transducers, capacitance transducers, or combinations thereof. In the alternative, other methods such as those utilizing x-rays or gamma rays may also be used to detect trapped air. Preferably, the fluid is a hydraulic fluid, whereby dissolved air in the fluid is detected.

  17. ANALYTICAL METHOD FOR MEASURING TOTAL PROTIUM AND TOTAL DEUTERIUM IN A GAS MIXTURE CONTAINING H2, D2,AND HD VIA GAS CHAROMATOGRAPHY

    SciTech Connect (OSTI)

    Sessions, H

    2007-08-07

    The most common analytical method of identifying and quantifying non-radioactive isotopic species of hydrogen is mass spectrometry. A low mass, high resolution mass spectrometer with adequate sensitivity and stability to identify and quantify hydrogen isotopes in the low ppm range is an expensive, complex instrument. A new analytical technique has been developed that measures both total protium (H) and total deuterium (D) in a gas mixture containing H{sub 2}, D{sub 2}, and HD using an inexpensive micro gas chromatograph (GC) with two molecular sieve columns. One column uses D{sub 2} as the carrier gas and the other uses H{sub 2} as the carrier gas. Laboratory tests have shown that when used in this configuration the GC can measure both total protium and total deuterium each with a detection and quantification limit of less than 20 ppm.

  18. Numerical method toward fast and accurate calculation of dilute quantum gas using Uehling-Uhlenbeck model equation

    E-Print Network [OSTI]

    Yano, Ryosuke

    2015-01-01

    We consider a fast and accurate numerical method to calculate the dilute quantum gas. To attain our aim, the Uehing-Uhlenbeck (U-U) model equation is calculated using the direct simulation Monte Carlo (DSMC) method. The proposed algorithm in the DSMC method enables us to obtain the accurate thermalization using a small number of sample particles and calculate the dilute quantum gas dynamics in practical time. Finally, we apply the proposed numerical method to the calculation of the viscosity coefficient on the basis of Green-Kubo expression.

  19. Diagnosis of Ocean Mesoscale Eddy Tracer Fluxes

    E-Print Network [OSTI]

    Fox-Kemper, Baylor

    Diagnosis of Ocean Mesoscale Eddy Tracer Fluxes Baylor Fox-Kemper U. Colorado-Boulder, with Scott - 10,000 km, yrs->centuries) => resolved · Mesoscale variability (10 - 100 km, mo -> yrs) => resolved) => parameterized Boundary Layer Models Mesoscale resolving models Climate models Submesoscale variability Coupling

  20. Identification and characterization of conservative organic tracers for use as hydrologic tracers for the Yucca Mountain site characterization study. Final report

    SciTech Connect (OSTI)

    Stetzenbach, K.; Farnham, I.

    1996-06-01

    Extensive tracer testing is expected to take place at the C-well complex in the Nevada Test Site as part of the Yucca Mountain Site Characterization Project. The C-well complex consists of one pumping well, C3, and two injection wells, C1 and C2 into which tracer will be introduced. The goal of this research was to provide USGS with numerous tracers to completed these tests. Several classes of fluorinated organic acids have been evaluated. These include numerous isomers of fluorinated benzoic acids, cinnamic acids, and salicylic acids. Also several derivatives of 2-hydroxy nicotinic acid (pyridone) have been tested. The stability of these compounds was determined using batch and column tests. Ames testing (mutagenicity/carcinogenicity) was conducted on the fluorinated benzoic acids and a literature review of toxicity of the fluorobenzoates and three perfluoro aliphatic acids was prepared. Solubilities were measured and method development work was performed to optimize the detection of these compounds. A Quality Assurance (QA) Program was developed under existing DOE and USGS guidelines. The program includes QA procedures and technical standard operating procedures. A tracer test, using sodium iodide, was performed at the C-well complex. HRC chemists performed analyses on site, to provide real time data for the USGS hydrologists and in the laboratories at UNLV. Over 2,500 analyses were performed. This report provides the results of the laboratory experiments and literature reviews used to evaluate the potential tracers and reports on the results of the iodide C-well tracer test.

  1. Passive Tracer Dispersion with Random or Periodic Source \\Lambda

    E-Print Network [OSTI]

    Passive Tracer Dispersion with Random or Periodic Source \\Lambda Jinqiao Duan Clemson University sources on the pattern formation and long­time behavior of concentration pro­ files of passive tracers Introduction The dispersion of passive tracers (or passive scalars) occur in various geo­ physical

  2. Passive Tracer Dispersion with Random or Periodic Source

    E-Print Network [OSTI]

    Passive Tracer Dispersion with Random or Periodic Source Jinqiao Duan Clemson University sources on the pattern formation and long-time behavior of concentration pro- #12;les of passive tracers #12;1 Introduction The dispersion of passive tracers (or passive scalars) occur in various geo

  3. Gas Hydrate Characterization in the GoM using Marine EM Methods

    SciTech Connect (OSTI)

    Steven Constable

    2012-03-31

    In spite of the importance of gas hydrate as a low-carbon fuel, a possible contributor to rapid climate change, and a significant natural hazard, our current understanding about the amount and distribution of submarine gas hydrate is somewhat poor; estimates of total volume vary by at least an order of magnitude, and commercially useful concentrations of hydrate have remained an elusive target. This is largely because conventional geophysical tools have intrinsic limitations in their ability to quantitatively image hydrate. It has long been known from well logs that gas hydrate is resistive compared to the host sediments, and electrical and electromagnetic methods have been proposed and occasionally used to image hydrates. This project seeks to expand our capabilities to use electromagnetic methods to explore for gas hydrate in the marine environment. An important basic science aspect of our work was to quantify the resistivity of pure gas hydrate as a function of temperature at seafloor pressures. We designed, constructed, and tested a highpressure cell in which hydrate could be synthesized and then subjected to electrical conductivity measurements. Impedance spectroscopy at frequencies between 20 Hz and 2 MHz was used to separate the effect of the blocking electrodes from the intrinsic conductivity of the hydrate. We obtained very reproducible results that showed that pure methane hydrate was several times more resistive than the water ice that seeded the synthesis, 20,000 {Ohm}m at 0{degrees}#14;C, and that the activation energy is 30.6 kJ/mol over the temperature range of -15 to 15{degrees}#14;C. Adding silica sand to the hydrate, however, showed that the addition of the extra phase caused the conductivity of the assemblage to increase in a counterintuitive way. The fact that the increased conductivity collapsed after a percolation threshold was reached, and that the addition of glass beads does not produce a similar increase in conductivity, together suggest that while the surface of the gas hydrate grains are not intrinsically conductive, the presence of sand does increase their conductivity. In the field component of this project, we carried out an 18day cruise on the R.V. Roger Revelle in the Gulf of Mexico from 7th-Ã?Â?26th October 2008 to collect controlled-source electromagnetic (CSEM) data over four hydrate prospects; blocks AC 818, WR 313, GC 955, and MC 118. During these surveys we deployed 30 ocean bottom electromagnetic (OBEM) recorders a total of 94 times at four survey areas and towed the Scripps Undersea Electromagnetic Source Instrument (SUESI) a total of 103 hours. SUESI transmission was 200 A on a 50 m dipole antenna at heights of 70-100 m above the seafloor. We also towed a neutrally buoyant 3-axis electric field recorder behind the SUESI antenna at a constant offset of 300 m. The use of a towed receiver that is "flown" above the seafloor allowed us to operate in areas where seafloor infrastructure such as wellheads, pipelines, and installed scientific equipment existed. We reduced the data to apparent resistivity psuedosections. The most compelling results come from the hydrate observatory at MC 118, where a localized resistivity anomaly is clearly identified under the southeast crater in an otherwise uniform 1 {Ohm}m background. The data from MC 118 also show that authigenic carbonate does not necessarily express itself as a confounding resistor, as was feared at the start of this project. While the results from the other prospects are much more complicated, the data are well correlated with known geology, and line to line agreement is good. Although these data are not amenable to 1D inversion as was initially hoped, we expect to use a newly developed 2D CSEM inversion code to continue to get useful information from this rich data set.

  4. Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H.J. (Cambridge, MA)

    2000-01-01

    An apparatus and a method are disclosed for converting hydrocarbon fuel or an alcohol into hydrogen gas and carbon dioxide. The apparatus includes a first vessel having a partial oxidation reaction zone and a separate steam reforming reaction zone that is distinct from the partial oxidation reaction zone. The first vessel has a first vessel inlet at the partial oxidation reaction zone and a first vessel outlet at the steam reforming zone. The reformer also includes a helical tube extending about the first vessel. The helical tube has a first end connected to an oxygen-containing source and a second end connected to the first vessel at the partial oxidation reaction zone. Oxygen gas from an oxygen-containing source can be directed through the helical tube to the first vessel. A second vessel having a second vessel inlet and second vessel outlet is annularly disposed about the first vessel. The helical tube is disposed between the first vessel and the second vessel and gases from the first vessel can be directed through second vessel.

  5. Method for reducing sulfate formation during regeneration of hot-gas desulfurization sorbents

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV); Strickland, Larry D. (Morgantown, WV); Rockey, John M. (Westover, WV)

    1994-01-01

    The regeneration of sulfur sorbents having sulfate forming tendencies and used for desulfurizing hot product gas streams such as provided by coal gasification is provided by employing a two-stage regeneration method. Air containing a sub-stoichiometric quantity of oxygen is used in the first stage for substantially fully regenerating the sorbent without sulfate formation and then regeneration of the resulting partially regenerated sorbent is completed in the second stage with air containing a quantity of oxygen slightly greater than the stoichiometric amount adequate to essentially fully regenerate the sorbent. Sulfate formation occurs in only the second stage with the extent of sulfate formation being limited only to the portion of the sulfur species contained by the sorbent after substantially all of the sulfur species have been removed therefrom in the first stage.

  6. Method for forming a liquid cooled airfoil for a gas turbine

    DOE Patents [OSTI]

    Grondahl, Clayton M. (Clifton Park, NY); Willmott, Leo C. (Ballston Spa, NY); Muth, Myron C. (Amsterdam, NY)

    1981-01-01

    A method for forming a liquid cooled airfoil for a gas turbine is disclosed. A plurality of holes are formed at spaced locations in an oversized airfoil blank. A pre-formed composite liquid coolant tube is bonded into each of the holes. The composite tube includes an inner member formed of an anti-corrosive material and an outer member formed of a material exhibiting a high degree of thermal conductivity. After the coolant tubes have been bonded to the airfoil blank, the airfoil blank is machined to a desired shape, such that a portion of the outer member of each of the composite tubes is contiguous with the outer surface of the machined airfoil blank. Finally, an external skin is bonded to the exposed outer surface of both the machined airfoil blank and the composite tubes.

  7. Apparatus and methods for determining gas saturation and porosity of a formation penetrated by a gas filled or liquid filled borehole

    DOE Patents [OSTI]

    Wilson, Robert D. (477 W. Scenic Dr., Grand Junction, CO 81503)

    2001-03-27

    Methods and apparatus are disclosed for determining gas saturation, liquid saturation, porosity and density of earth formations penetrated by a well borehole. Determinations are made from measures of fast neutron and inelastic scatter gamma radiation induced by a pulsed, fast neutron source. The system preferably uses two detectors axially spaced from the neutron source. One detector is preferably a scintillation detector responsive to gamma radiation, and a second detector is preferably an organic scintillator responsive to both neutron and gamma radiation. The system can be operated in cased boreholes which are filled with either gas or liquid. Techniques for correcting all measurements for borehole conditions are disclosed.

  8. Results of Chemical Analyses for Alcove 8/Niche 3 Tracer Studies

    SciTech Connect (OSTI)

    Daniels, Jeanette

    2006-02-23

    This is the final report detailing the analyses performed under ORD-FY04-011 "Chemical Analyses for Alcove 8/Niche 3 Tracer Studies." The work was performed under the University and Community College System of Nevada (UCCSN) and the Department of Energy (DOE) Cooperative Agreement Number DE-FC28-04RW12232. This task provided method development and analytical support for the Alcove 8/Niche 3 Tracer Studies in the Exploratory Studies Facility (ESF). Concentrations of tracers, as well as major anions and cations, were reported for samples provided by Lawrence Berkeley National Laboratory (LBNL) and the US Geological Survey (USGS). Samples were analyzed using High Performance Liquid Chromatography (HPLC) and Ion Chromatography (IC). Samples were analyzed and controlled according to Implementing Procedures (IP's) written and approved in accordance with the Office of Civilian Radioactive Waste Management (OCRWM) approved Nevada System of Higher Education (NSHE) Quality Assurance Program.

  9. Method and apparatus maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl (Pinson, AL); Felix, Larry Gordon (Pelham, AL); Snyder, Todd Robert (Birmingham, AL)

    2009-12-15

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  10. Method and apparatus for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl (Pinson, AL) [Pinson, AL; Felix, Larry Gordon (Pelham, AL) [Pelham, AL; Snyder, Todd Robert (Birmingham, AL) [Birmingham, AL

    2008-02-12

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  11. Application of the Continuous EUR Method to Estimate Reserves in Unconventional Gas Reservoirs 

    E-Print Network [OSTI]

    Currie, Stephanie M.

    2010-10-12

    for unconventional gas reservoirs using a rate-time analysis approach. This work offers a coherent process to reduce the uncertainty in reserves estimation for unconventional gas reservoirs by quantifying "upper" and "lower" limits of EUR prior to the onset...

  12. Tracers and Exploration Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaicsState ofSavings forTitle XVIIofTracers and Exploration

  13. ANALYSIS OF GAS PRODUCTION FROM HYDRAULICALLY FRACTURED WELLS IN THE HAYNESVILLE SHALE USING SCALING METHODS

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    ANALYSIS OF GAS PRODUCTION FROM HYDRAULICALLY FRACTURED WELLS IN THE HAYNESVILLE SHALE USING. The reservoir temperature is also high, up to 3000 F. These pressures are uniquely high among shale gas gas from the Haynesville Shale without horizontal wells and massive hydrofractures. In addition

  14. Methods for ensuring compliance in an international greenhouse gas trading system

    SciTech Connect (OSTI)

    Hargrave, T.; Helme, E.A.

    1998-12-31

    At the third Conference of the Parties to the UN Framework Convention on Climate Change held in December, 1997, the international community established binding greenhouse gas (GHG) emissions obligations for industrialized countries. The Parties to the new Kyoto Protocol also agreed on the use of a number of market-based mechanisms, including international GHG emissions trading. These market mechanisms were of critical to the importance because they have the potential to significantly reduce the costs of treaty compliance. In principle, an international cap-and-trade system appears to be one of the most cost-effective means of reducing GHG emissions. Maintaining the integrity of the trading system is of primary importance in ensuring that trading helps countries to meet their GHG commitments. This paper explores methods for ensuring compliance in an international greenhouse gas trading system, starting with a discussion of preconditions for participation in trading and then moving to features of an international compliance system. Achieving maximum compliance with international requirements may best be accomplished by limiting participation in trading to Annex I countries that maintain strong domestic compliance systems. Prior to the climate negotiations in Kyoto in December 1997, the US Administration proposed a number of preconditions for participation in trading, including the adoption of international measurement standards and the establishment of domestic compliance and enforcement programs. This paper explores these and other preconditions, including the establishment of tough domestic financial penalties on companies that exceed allowed emissions and seller responsibility for the delivery of real reductions. The paper also discusses several necessary features of the international compliance system.

  15. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean (Castle Rock, CO); Schlager, Richard John (Aurora, CO); Ebner, Timothy George (Westminster, CO); Stewart, Robin Michele (Arvada, CO); Bustard, Cynthia Jean (Littleton, CO)

    1999-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  16. Oil and gas exploration system and method for detecting trace amounts of hydrocarbon gases in the atmosphere

    DOE Patents [OSTI]

    Wamsley, Paula R. (Littleton, CO); Weimer, Carl S. (Littleton, CO); Nelson, Loren D. (Evergreen, CO); O'Brien, Martin J. (Pine, CO)

    2003-01-01

    An oil and gas exploration system and method for land and airborne operations, the system and method used for locating subsurface hydrocarbon deposits based upon a remote detection of trace amounts of gases in the atmosphere. The detection of one or more target gases in the atmosphere is used to indicate a possible subsurface oil and gas deposit. By mapping a plurality of gas targets over a selected survey area, the survey area can be analyzed for measurable concentration anomalies. The anomalies are interpreted along with other exploration data to evaluate the value of an underground deposit. The system includes a differential absorption lidar (DIAL) system with a spectroscopic grade laser light and a light detector. The laser light is continuously tunable in a mid-infrared range, 2 to 5 micrometers, for choosing appropriate wavelengths to measure different gases and avoid absorption bands of interference gases. The laser light has sufficient optical energy to measure atmospheric concentrations of a gas over a path as long as a mile and greater. The detection of the gas is based on optical absorption measurements at specific wavelengths in the open atmosphere. Light that is detected using the light detector contains an absorption signature acquired as the light travels through the atmosphere from the laser source and back to the light detector. The absorption signature of each gas is processed and then analyzed to determine if a potential anomaly exists.

  17. RCUT: A Non-Invasive Method for Detection, Location, and Quantification of Radiological Contaminants in Pipes and Ducts - 12514

    SciTech Connect (OSTI)

    Bratton, Wesley L.; Maresca, Joseph W. Jr.; Beck, Deborah A.

    2012-07-01

    Radiological Characterization Using Tracers (RCUT) is a minimally invasive method for detection and location of residual radiological contamination in pipes and ducts. The RCUT technology utilizes reactive gaseous tracers that dissociate when exposed to gamma and/or beta radiation emitting from a radiological contaminant in a pipe or duct. Sulfur hexafluoride (SF{sub 6}) was selected as a tracer for this radiological application, because it is a chemically inert gas that is both nonflammable, nontoxic, and breaks down when exposed to gamma radiation. Laboratory tests demonstrated that the tracer pair of SF{sub 6} and O{sub 2} formed SO{sub 2}F{sub 2} when exposed to a gamma or beta radioactive field, which indicated the presence of radiological contamination. Field application of RCUT involves first injecting the reactive tracers into the pipe to fill the pipe being inspected and allowing sufficient time for the tracer to interact with any contaminants present. This is followed by the injection of an inert gas at one end of the pipe to push the reactive tracer at a known or constant flow velocity along the pipe and then out the exit and sampling port at the end of the pipeline where its concentration is measured by a gas chromatograph. If a radiological contaminant is present in the pipe being tested, the presence of SO{sub 2}F{sub 2} will be detected. The time of arrival of the SO{sub 2}F{sub 2} can be used to locate the contaminant. If the pipe is free of radiological contamination, no SO{sub 2}F{sub 2} will be detected. RCUT and PCUT are both effective technologies that can be used to detect contamination within pipelines without the need for mechanical or human inspection. These methods can be used to detect, locate, and/or estimate the volume of a variety of radioactive materials and hazardous chemicals such as chlorinated solvents, petroleum products, and heavy metals. While further optimization is needed for RCUT, the key first step of identification of a tracer compound appropriate for the application of detecting radioactive pipeline contamination through the detection of decomposition products of SF{sub 6} has been demonstrated. Other tracer gases that will also undergo radiolysis will be considered in the future. The next step for the RCUT development process is conducting laboratory scale tests using short pipelines to define analytical requirements, establish performance boundaries, and develop strategies for lower exposure levels. Studies to identify additional analytical techniques using equipment that is more field rugged than a GC/MS would also be beneficial. (authors)

  18. Method of making a continuous ceramic fiber composite hot gas filter

    DOE Patents [OSTI]

    Hill, Charles A. (Lynchburg, VA); Wagner, Richard A. (Lynchburg, VA); Komoroski, Ronald G. (Lynchburg, VA); Gunter, Greg A. (Lynchburg, VA); Barringer, Eric A. (Lynchburg, VA); Goettler, Richard W. (Lynchburg, VA)

    1999-01-01

    A ceramic fiber composite structure particularly suitable for use as a hot gas cleanup ceramic fiber composite filter and method of making same from ceramic composite material has a structure which provides for increased strength and toughness in high temperature environments. The ceramic fiber composite structure or filter is made by a process in which a continuous ceramic fiber is intimately surrounded by discontinuous chopped ceramic fibers during manufacture to produce a ceramic fiber composite preform which is then bonded using various ceramic binders. The ceramic fiber composite preform is then fired to create a bond phase at the fiber contact points. Parameters such as fiber tension, spacing, and the relative proportions of the continuous ceramic fiber and chopped ceramic fibers can be varied as the continuous ceramic fiber and chopped ceramic fiber are simultaneously formed on the porous vacuum mandrel to obtain a desired distribution of the continuous ceramic fiber and the chopped ceramic fiber in the ceramic fiber composite structure or filter.

  19. Gas seal for an in situ oil shale retort and method of forming thermal barrier

    DOE Patents [OSTI]

    Burton, III, Robert S. (Mesa, CO)

    1982-01-01

    A gas seal is provided in an access drift excavated in a subterranean formation containing oil shale. The access drift is adjacent an in situ oil shale retort and is in gas communication with the fragmented permeable mass of formation particles containing oil shale formed in the in situ oil shale retort. The mass of formation particles extends into the access drift, forming a rubble pile of formation particles having a face approximately at the angle of repose of fragmented formation. The gas seal includes a temperature barrier which includes a layer of heat insulating material disposed on the face of the rubble pile of formation particles and additionally includes a gas barrier. The gas barrier is a gas-tight bulkhead installed across the access drift at a location in the access drift spaced apart from the temperature barrier.

  20. Apparatus and method for fast recovery and charge of insulation gas

    DOE Patents [OSTI]

    Jordan, Kevin

    2013-09-03

    An insulation gas recovery and charge apparatus is provided comprising a pump, a connect, an inflatable collection device and at least one valve.

  1. Portable instrument and method for detecting reduced sulfur compounds in a gas

    DOE Patents [OSTI]

    Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

    1983-06-01

    A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

  2. An Integrated Approach to Characterizing Bypassed Oil in Heterogeneous and Fractured Reservoirs Using Partitioning Tracers

    SciTech Connect (OSTI)

    Akhil Datta-Gupta

    2006-12-31

    We explore the use of efficient streamline-based simulation approaches for modeling partitioning interwell tracer tests in hydrocarbon reservoirs. Specifically, we utilize the unique features of streamline models to develop an efficient approach for interpretation and history matching of field tracer response. A critical aspect here is the underdetermined and highly ill-posed nature of the associated inverse problems. We have investigated the relative merits of the traditional history matching ('amplitude inversion') and a novel travel time inversion in terms of robustness of the method and convergence behavior of the solution. We show that the traditional amplitude inversion is orders of magnitude more non-linear and the solution here is likely to get trapped in local minimum, leading to inadequate history match. The proposed travel time inversion is shown to be extremely efficient and robust for practical field applications. The streamline approach is generalized to model water injection in naturally fractured reservoirs through the use of a dual media approach. The fractures and matrix are treated as separate continua that are connected through a transfer function, as in conventional finite difference simulators for modeling fractured systems. A detailed comparison with a commercial finite difference simulator shows very good agreement. Furthermore, an examination of the scaling behavior of the computation time indicates that the streamline approach is likely to result in significant savings for large-scale field applications. We also propose a novel approach to history matching finite-difference models that combines the advantage of the streamline models with the versatility of finite-difference simulation. In our approach, we utilize the streamline-derived sensitivities to facilitate history matching during finite-difference simulation. The use of finite-difference model allows us to account for detailed process physics and compressibility effects. The approach is very fast and avoids much of the subjective judgments and time-consuming trial-and-errors associated with manual history matching. We demonstrate the power and utility of our approach using a synthetic example and two field examples. We have also explored the use of a finite difference reservoir simulator, UTCHEM, for field-scale design and optimization of partitioning interwell tracer tests. The finite-difference model allows us to include detailed physics associated with reactive tracer transport, particularly those related with transverse and cross-streamline mechanisms. We have investigated the potential use of downhole tracer samplers and also the use of natural tracers for the design of partitioning tracer tests. Finally, we discuss several alternative ways of using partitioning interwell tracer tests (PITTs) in oil fields for the calculation of oil saturation, swept pore volume and sweep efficiency, and assess the accuracy of such tests under a variety of reservoir conditions.

  3. Category:Tracer Testing | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR Jump to:RAPID Roadmap ContactRockEuropeTelluricTracer Testing

  4. Apparatus and method for removing mercury vapor from a gas stream

    DOE Patents [OSTI]

    Ganesan, Kumar (Butte, MT)

    2008-01-01

    A metallic filter effectively removes mercury vapor from gas streams. The filter captures the mercury which then can be released and collected as product. The metallic filter is a copper mesh sponge plated with a six micrometer thickness of gold. The filter removes up to 90% of mercury vapor from a mercury contaminated gas stream.

  5. GEOLOGIC ASSESSMENT OF DRILLING, COMPLETION, AND STIMULATION METHODS IN SELECTED GAS SHALE PLAYS WORLDWIDE 

    E-Print Network [OSTI]

    Patel, Harsh Jay

    2014-04-11

    the gas shale formations that have been identified in the world energy consortium. The natural gas in shales and other unconventional reservoirs can be easily used to generate electricity, or it can be turned into liquids and used by the transportation...

  6. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Bustard, C.J.

    1999-04-13

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 5 figs.

  7. Tracer Testing at Dixie Valley, Nevada, Using Pyrene Tetrasulfonate...

    Open Energy Info (EERE)

    conducted at the Dixie Valley, Nevada, geothermal reservoir in order to determine fluid-flow processes and to evaluate candidate tracers for use in hydrothermal systems. These...

  8. The lattice Boltzmann method for isothermal micro-gaseous flow and its application in shale gas flow: a review

    E-Print Network [OSTI]

    Wang, Junjian; Kang, Qinjun; Rahman, Sheik S

    2015-01-01

    The lattice Boltzmann method (LBM) has experienced tremendous advances and been well accepted as a popular method of simulation of various fluid flow mechanisms on pore scale in tight formations. With the introduction of an effective relaxation time and slip boundary conditions, the LBM has been successfully extended to solve micro-gaseous related transport and phenomena. As gas flow in shale matrix is mostly in the slip flow and transition flow regimes, given the difficulties of experimental techniques to determine extremely low permeability, it appears that the computational methods especially the LBM can be an attractive choice for simulation of these micro-gaseous flows. In this paper an extensive overview on a number of relaxation time and boundary conditions used in LBM-like models for micro-gaseous flow are carried out and their advantages and disadvantages are discussed. Furthermore, potential application of the LBM in flow simulation in shale gas reservoirs on pore scale and representative elementary...

  9. Method of monitoring photoactive organic molecules in-situ during gas-phase deposition of the photoactive organic molecules

    DOE Patents [OSTI]

    Forrest, Stephen R.; Vartanian, Garen; Rolin, Cedric

    2015-06-23

    A method for in-situ monitoring of gas-phase photoactive organic molecules in real time while depositing a film of the photoactive organic molecules on a substrate in a processing chamber for depositing the film includes irradiating the gas-phase photoactive organic molecules in the processing chamber with a radiation from a radiation source in-situ while depositing the film of the one or more organic materials and measuring the intensity of the resulting photoluminescence emission from the organic material. One or more processing parameters associated with the deposition process can be determined from the photoluminescence intensity data in real time providing useful feedback on the deposition process.

  10. Influence of mechanical-biological waste pre-treatment methods on the gas formation in landfills

    SciTech Connect (OSTI)

    Bockreis, A. [Technische Universitaet Darmstadt, Darmstadt University of Technology, Institute for Water Supply and Groundwater Protection, Wastewater Technology, Waste Management, Industrial Material Flows and Environmental Planning (Institute WAR), Chair of Waste Management and Waste Technology, Darmstadt (Germany)]. E-mail: a.bockreis@iwar.tu-darmstadt.de; Steinberg, I. [Technische Universitaet Darmstadt, Darmstadt University of Technology, Institute for Water Supply and Groundwater Protection, Wastewater Technology, Waste Management, Industrial Material Flows and Environmental Planning (Institute WAR), Chair of Waste Management and Waste Technology, Darmstadt (Germany)

    2005-07-01

    In order to minimise emissions and environmental impacts, only pre-treated waste should be disposed of. For the last six years, a series of continuous experiments has been conducted at the Institute WAR, TU Darmstadt, in order to determine the emissions from pre-treated waste. Different kinds of pre-treated waste were incubated in several reactors and various data, including production and composition of the gas and the leachate, were collected. In this paper, the interim results of gas production and the gas composition from different types of waste after a running time of six years are presented and discussed.

  11. Systems and methods for using a boehmite bond-coat with polyimide membranes for gas separation

    DOE Patents [OSTI]

    Polishchuk, Kimberly Ann

    2013-03-05

    The subject matter disclosed herein relates to gas separation membranes and, more specifically, to polyimide gas separation membranes. In an embodiment, a gas separation membrane includes a porous substrate, a substantially continuous polyimide membrane layer, and one or more layers of boehmite nanoparticles disposed between the porous substrate and the polyimide membrane layer to form a bond-coat layer. The bond-coat layer is configured to improve the adhesion of the polyimide membrane layer to the porous substrate, and the polyimide membrane layer has a thickness approximately 100 nm or less.

  12. An Advisory System For Selecting Drilling Technologies and Methods in Tight Gas Reservoirs 

    E-Print Network [OSTI]

    Pilisi, Nicolas

    2010-01-16

    ranging between 177 Tcf and 379 Tcf. During the past few decades, gas production from tight sands field developments have taken place all around the world from South America (Argentina), Australia, Asia (China, Indonesia), the Russian Federation, Northern...

  13. Electrical apparatus for explosive gas atmospheres, Part 4: Method of test for ignition temperature 

    E-Print Network [OSTI]

    IEC Technical Committee

    1966-01-01

    This Recommendation was prepared by IEC Technical Committee No. 31 , Electrical Apparatus for Explosive Atmospheres. It forms one of a series of publications dealing with electrical apparatus for use in explosive gas ...

  14. Method for removal and stabilization of mercury in mercury-containing gas streams

    DOE Patents [OSTI]

    Broderick, Thomas E.

    2005-09-13

    The present invention is directed to a process and apparatus for removing and stabilizing mercury from mercury-containing gas streams. A gas stream containing vapor phase elemental and/or speciated mercury is contacted with reagent, such as an oxygen-containing oxidant, in a liquid environment to form a mercury-containing precipitate. The mercury-containing precipitate is kept or placed in solution and reacts with one or more additional reagents to form a solid, stable mercury-containing compound.

  15. Method of Generating Hydrocarbon Reagents from Diesel, Natural Gas and Other Logistical Fuels

    DOE Patents [OSTI]

    Herling, Darrell R (Richland, WA) [Richland, WA; Aardahl, Chris L. (Richland, WA) [Richland, WA; Rozmiarek, Robert T. (Middleton, WI) [Middleton, WI; Rappe, Kenneth G. (Richland, WA) [Richland, WA; Wang, Yong (Richland, WA) [Richland, WA; Holladay, Jamelyn D. (Kennewick, WA) [Kennewick, WA

    2008-10-14

    The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

  16. Method of generating hydrocarbon reagents from diesel, natural gas and other logistical fuels

    DOE Patents [OSTI]

    Herling, Darrell R. (Richland, WA); Aardahl, Chris L. (Richland, WA); Rozmiarek, Robert T. (Middleton, WI); Rappe, Kenneth G. (Richland, WA); Wang, Yong (Richland, WA); Holladay, Jamelyn D. (Kennewick, WA)

    2010-06-29

    The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

  17. Method for microwave plasma assisted supersonic gas jet deposition of thin films

    DOE Patents [OSTI]

    Schmitt, J.J. III; Halpern, B.L.

    1994-10-18

    A thin film is formed on a substrate positioned in a vacuum chamber by use of a gas jet apparatus affixed to a vacuum chamber port and having an outer nozzle with an interior cavity into which carrier gas is fed, an inner nozzle located within the outer nozzle interior cavity into which reactant gas is introduced, a tip of the inner nozzle being recessed from the vacuum chamber port within the outer nozzle interior cavity, and a microwave discharge device configured about the apparatus for generating a discharge in the carrier gas and reactant gas only in a portion of the outer nozzle interior cavity extending from approximately the inner nozzle tip towards the vacuum chamber. A supersonic free jet of carrier gas transports vapor species generated in the microwave discharge to the surface of the substrate to form a thin film on the substrate. The substrate can be translated from the supersonic jet to a second supersonic jet in less time than needed to complete film formation so that the film is chemically composed of chemical reaction products of vapor species in the jets. 5 figs.

  18. Method for microwave plasma assisted supersonic gas jet deposition of thin films

    DOE Patents [OSTI]

    Schmitt, III, Jerome J. (New Haven, CT); Halpern, Bret L. (Bethany, CT)

    1994-01-01

    A thin film is formed on a substrate positioned in a vacuum chamber by use of a gas jet apparatus affixed to a vacuum chamber port and having an outer nozzle with an interior cavity into which carrier gas is fed, an inner nozzle located within the outer nozzle interior cavity into which reactant gas is introduced, a tip of the inner nozzle being recessed from the vacuum chamber port within the outer nozzle interior cavity, and a microwave discharge device configured about the apparatus for generating a discharge in the carrier gas and reactant gas only in a portion of the outer nozzle interior cavity extending from approximately the inner nozzle tip towards the vacuum chamber. A supersonic free jet of carrier gas transports vapor species generated in the microwave discharge to the surface of the substrate to form a thin film on the substrate. The substrate can be translated from the supersonic jet to a second supersonic jet in less time than needed to complete film formation so that the film is chemically composed of chemical reaction products of vapor species in the jets.

  19. A New Method for History Matching and Forecasting Shale Gas/Oil Reservoir Production Performance with Dual and Triple Porosity Models 

    E-Print Network [OSTI]

    Samandarli, Orkhan

    2012-10-19

    Different methods have been proposed for history matching production of shale gas/oil wells which are drilled horizontally and usually hydraulically fractured with multiple stages. These methods are simulation, analytical models, and empirical...

  20. Use of Tracers to Characterize Fractures in Engineered Geothermal Systems

    Broader source: Energy.gov [DOE]

    Project Objectives: Measure interwell fracture surface area and fracture spacing using sorbing tracers; measure fracture surface areas adjacent to a single geothermal well using tracers and injection/backflow techniques; design, fabricate and test a downhole instrument for measuring fracture flow following a hydraulic stimulation experiment.

  1. National Biomedical Tracer Facility. Project definition study

    SciTech Connect (OSTI)

    Schafer, R.

    1995-02-14

    We request a $25 million government-guaranteed, interest-free loan to be repaid over a 30-year period for construction and initial operations of a cyclotron-based National Biomedical Tracer Facility (NBTF) in North Central Texas. The NBTF will be co-located with a linear accelerator-based commercial radioisotope production facility, funded by the private sector at approximately $28 million. In addition, research radioisotope production by the NBTF will be coordinated through an association with an existing U.S. nuclear reactor center that will produce research and commercial radioisotopes through neutron reactions. The combined facilities will provide the full range of technology for radioisotope production and research: fast neutrons, thermal neutrons, and particle beams (H{sup -}, H{sup +}, and D{sup +}). The proposed NBTF facility includes an 80 MeV, 1 mA H{sup -} cyclotron that will produce proton-induced (neutron deficient) research isotopes.

  2. Method for increasing the calorific value of gas produced by the in situ combustion of coal

    DOE Patents [OSTI]

    Shuck, Lowell Z. (Morgantown, WV)

    1978-01-01

    The present invention relates to the production of relatively high Btu gas by the in situ combustion of subterranean coal. The coal bed is penetrated with a horizontally-extending borehole and combustion is initiated in the coal bed contiguous to the borehole. The absolute pressure within the resulting combustion zone is then regulated at a desired value near the pore pressure within the coal bed so that selected quantities of water naturally present in the coal will flow into the combustion zone to effect a hydrogen and carbon monoxide-producing steam-carbon reaction with the hot carbon in the combustion zone for increasing the calorific value of the product gas.

  3. Systems and methods for detecting a flame in a fuel nozzle of a gas turbine

    DOE Patents [OSTI]

    Kraemer, Gilbert Otto; Storey, James Michael; Lipinski, John; Mestroni, Julio Enrique; Williamson, David Lee; Marshall, Jason Randolph; Krull, Anthony

    2013-05-07

    A system may detect a flame about a fuel nozzle of a gas turbine. The gas turbine may have a compressor and a combustor. The system may include a first pressure sensor, a second pressure sensor, and a transducer. The first pressure sensor may detect a first pressure upstream of the fuel nozzle. The second pressure sensor may detect a second pressure downstream of the fuel nozzle. The transducer may be operable to detect a pressure difference between the first pressure sensor and the second pressure sensor.

  4. Standard Test Method for Isotopic Analysis of Uranium Hexafluoride by Single-Standard Gas Source Multiple Collector Mass Spectrometer Method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2011-01-01

    1.1 This test method is applicable to the isotopic analysis of uranium hexafluoride (UF6) with 235U concentrations less than or equal to 5 % and 234U, 236U concentrations of 0.0002 to 0.1 %. 1.2 This test method may be applicable to the analysis of the entire range of 235U isotopic compositions providing that adequate Certified Reference Materials (CRMs or traceable standards) are available. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety health practices and determine the applicability of regulatory limitations prior to use.

  5. Gas stream clean-up filter and method for forming same

    DOE Patents [OSTI]

    Mei, Joseph S. (Morgantown, WV); DeVault, James (Fairmont, WV); Halow, John S. (Waynesburg, PA)

    1993-01-01

    A gas cleaning filter is formed in-situ within a vessel containing a fluidizable bed of granular material of a relatively large size fraction. A filter membrane provided by a porous metal or ceramic body or such a body supported a perforated screen on one side thereof is coated in-situ with a layer of the granular material from the fluidized bed by serially passing a bed-fluidizing gas stream through the bed of granular material and the membrane. The layer of granular material provides the filtering medium for the combined membrane-granular layer filter. The filter is not blinded by the granular material and provides for the removal of virtually all of the particulates from a process gas stream. The granular material can be at least partially provided by a material capable of chemically reacting with and removing sulfur compounds from the process gas stream. Low level radioactive waste containing organic material may be incinerated in a fluidized bed in communication with the described filter for removing particulates from the gaseous combustion products.

  6. Tracer Methods for Characterizing Fracture Creation in Enhanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clusters in Geothermal Reservoirs; 2010 Geothermal Technology Program Peer Review Report Fracture Characterization in Enhanced Geothermal Systems by Wellbore and Reservoir Analysis...

  7. Verification of Geothermal Tracer Methods in Highly Constrained Field

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al.,Turin, NewArkansas: EnergyVentnor City, NewVerdi EnergyExperiments

  8. Advancing Reactive Tracer Methods for Measurement of Thermal...

    Office of Scientific and Technical Information (OSTI)

    (e.g., Rose et al., 2001). As these injected fluids move along fractures, they acquire heat from the rock matrix and remove it from the reservoir as they are extracted to the...

  9. Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs,Department ofARPA-E Top 10 Things YouPotential|Agreement

  10. Advancing Reactive Tracer Methods for Measurement of Thermal Evolution in

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnicalInformation4563Abuse Tolerance(Conference)Geothermal Reservoirs: Final Report

  11. Advancing Reactive Tracer Methods for Measurement of Thermal Evolution in

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnicalInformation4563Abuse Tolerance(Conference)Geothermal Reservoirs: Final

  12. Preferred methods of analysis for chemical tracers in moderate- and

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII JumpQuarterly SmartDB-2, BluePoulsen Hybrid, LLCBiofuelsEthanolPredictive

  13. Tracer Methods for Characterizing Fracture Stimulation in Enhanced

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaicsState ofSavings forTitle XVIIof

  14. Characterization of a real-time tracer for Isoprene Epoxydiols-derived Secondary Organic Aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, W. W.; Campuzano-Jost, P.; Palm, B. B.; Day, D. A.; Ortega, A. M.; Hayes, P. L.; Krechmer, J. E.; Chen, Q.; Kuwata, M.; Liu, Y. J.; et al

    2015-04-16

    Substantial amounts of secondary organic aerosol (SOA) can be formed from isoprene epoxydiols (IEPOX), which are oxidation products of isoprene mainly under low-NO conditions. Total IEPOX-SOA, which may include SOA formed from other parallel isoprene low-NO oxidation pathways, was quantified by applying Positive Matrix Factorization (PMF) to aerosol mass spectrometer (AMS) measurements. The IEPOX-SOA fractions of OA in multiple field studies across several continents are summarized here and show consistent patterns with the concentration of gas-phase IEPOX simulated by the GEOS-Chem chemical transport model. During the SOAS study, 78% of IEPOX-SOA is accounted for the measured molecular tracers, making itmore »the highest level of molecular identification of an ambient SOA component to our knowledge. Enhanced signal at C5H6O+ (m/z 82) is found in PMF-resolved IEPOX-SOA spectra. To investigate the suitability of this ion as a tracer for IEPOX-SOA, we examine fC5H6O ( fC5H6O = C5H6O+/OA) across multiple field, chamber and source datasets. A background of ~ 1.7 ± 0.1‰ is observed in studies strongly influenced by urban, biomass-burning and other anthropogenic primary organic aerosol (POA). Higher background values of 3.1 ± 0.8‰ are found in studies strongly influenced by monoterpene emissions. The average laboratory monoterpene SOA value (5.5 ± 2.0‰) is 4 times lower than the average for IEPOX-SOA (22 ± 7‰). Locations strongly influenced by isoprene emissions under low-NO levels had higher fC5H6O (~ 6.5 ± 2.2‰ on average) than other sites, consistent with the expected IEPOX-SOA formation in those studies. fC5H6O in IEPOX-SOA is always elevated (12–40‰) but varies substantially between locations, which is shown to reflect large variations in its detailed molecular composition. The low fC5H6O (< 3‰) observed in non IEPOX-derived isoprene-SOA indicates that this tracer ion is specifically enhanced from IEPOX-SOA, and is not a tracer for all SOA from isoprene. We introduce a graphical diagnostic to study the presence and aging of IEPOX-SOA as a "triangle plot" of fCO2 vs. fC5H6O. Finally, we develop a simplified method to estimate ambient IEPOX-SOA mass concentrations, which is shown to perform well compared to the full PMF method. The uncertainty of the tracer method is up to a factor of ~ 2 if the fC5H6O of the local IEPOX-SOA is not available. When only unit mass resolution data is available, as with the aerosol chemical speciation monitor (ACSM), all methods may perform less well because of increased interferences from other ions at m/z 82. This study clarifies the strengths and limitations of the different AMS methods for detection of IEPOX-SOA and will enable improved characterization of this OA component.« less

  15. Environmental Tracers for Determining Water Resource Vulnerability to Climate Change

    SciTech Connect (OSTI)

    Singleton, M

    2009-07-08

    Predicted changes in the climate will have profound impacts on water availability in the Western US, but large uncertainties exist in our ability to predict how natural and engineered hydrological systems will respond. Most predictions suggest that the impacts of climate change on California water resources are likely to include a decrease in the percentage of precipitation that falls as snow, earlier onset of snow-pack melting, and an increase in the number of rain on snow events. These processes will require changes in infrastructure for water storage and flood control, since much of our current water supply system is built around the storage of winter precipitation as mountain snow pack. Alpine aquifers play a critical role by storing and releasing snowmelt as baseflow to streams long after seasonal precipitation and the disappearance of the snow pack, and in this manner significantly impact the stream flow that drives our water distribution systems. Mountain groundwater recharge and, in particular, the contribution of snowmelt to recharge and baseflow, has been identified as a potentially significant effect missing from current climate change impact studies. The goal of this work is to understand the behavior of critical hydrologic systems, with an emphasis on providing ground truth for next generation models of climate-water system interactions by implementing LLNL capabilities in environmental tracer and isotopic science. We are using noble gas concentrations and multiple isotopic tracers ({sup 3}H/{sup 3}He, {sup 35}S, {sup 222}Rn, {sup 2}H/{sup 1}H, {sup 18}O/{sup 16}O, and {sup 13}C/{sup 12}C) in groundwater and stream water in a small alpine catchment to (1) provide a snapshot of temperature, altitude, and physical processes at the time of recharge, (2) determine subsurface residence times (over time scales ranging from months to decades) of different groundwater age components, and (3) deconvolve the contribution of these different groundwater components to alpine stream baseflow. This research is showing that groundwater in alpine areas spends between a few years to several decades in the saturated zone below the surface, before feeding into streams or being pumped for use. This lag time may act to reduce the impact on water resources from extreme wet or dry years. Furthermore, our measurements show that the temperature of water when it reaches the water table during recharge is 4 to 9 degrees higher than would be expected for direct influx of snowmelt, and that recharge likely occurs over diffuse vegetated areas, rather than along exposed rock faces and fractures. These discoveries have implications for how alpine basins will respond to climate effects that lead to more rain than snow and earlier snow pack melting.

  16. Method of joining a vane cavity insert to a nozzle segment of a gas turbine

    DOE Patents [OSTI]

    Burdgick, Steven Sebastian (Schenectady, NY)

    2002-01-01

    An insert containing apertures for impingement cooling a nozzle vane of a nozzle segment in a gas turbine is inserted into one end of the vane. The leading end of the insert is positioned slightly past a rib adjacent the opposite end of the vane through which the insert is inserted. The end of the insert is formed or swaged into conformance with the inner margin of the rib. The insert is then brazed or welded to the rib.

  17. Method and apparatus for selective capture of gas phase analytes using metal .beta.-diketonate polymers

    DOE Patents [OSTI]

    Harvey, Scott D [Kennewick, WA

    2011-06-21

    A process and sensor device are disclosed that employ metal .beta.-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal .beta.-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.

  18. Self-tuning method for monitoring the density of a gas vapor component using a tunable laser

    DOE Patents [OSTI]

    Hagans, Karla (Livermore, CA); Berzins, Leon (Livermore, CA); Galkowski, Joseph (Livermore, CA); Seng, Rita (Tracy, CA)

    1996-01-01

    The present invention relates to a vapor density monitor and laser atomic absorption spectroscopy method for highly accurate, continuous monitoring of vapor densities, composition, flow velocity, internal and kinetic temperatures and constituent distributions. The vapor density monitor employs a diode laser, preferably of an external cavity design. By using a diode laser, the vapor density monitor is significantly less expensive and more reliable than prior art vapor density monitoring devices. In addition, the compact size of diode lasers enables the vapor density monitor to be portable. According to the method of the present invention, the density of a component of a gas vapor is calculated by tuning the diode laser to a frequency at which the amount of light absorbed by the component is at a minimum or a maximum within about 50 MHz of that frequency. Laser light from the diode laser is then transmitted at the determined frequency across a predetermined pathlength of the gas vapor. By comparing the amount of light transmitted by the diode laser to the amount of light transmitted after the laser light passes through the gas vapor, the density of the component can be determined using Beer's law.

  19. Self-tuning method for monitoring the density of a gas vapor component using a tunable laser

    DOE Patents [OSTI]

    Hagans, K.; Berzins, L.; Galkowski, J.; Seng, R.

    1996-08-27

    The present invention relates to a vapor density monitor and laser atomic absorption spectroscopy method for highly accurate, continuous monitoring of vapor densities, composition, flow velocity, internal and kinetic temperatures and constituent distributions. The vapor density monitor employs a diode laser, preferably of an external cavity design. By using a diode laser, the vapor density monitor is significantly less expensive and more reliable than prior art vapor density monitoring devices. In addition, the compact size of diode lasers enables the vapor density monitor to be portable. According to the method of the present invention, the density of a component of a gas vapor is calculated by tuning the diode laser to a frequency at which the amount of light absorbed by the component is at a minimum or a maximum within about 50 MHz of that frequency. Laser light from the diode laser is then transmitted at the determined frequency across a predetermined pathlength of the gas vapor. By comparing the amount of light transmitted by the diode laser to the amount of light transmitted after the laser light passes through the gas vapor, the density of the component can be determined using Beer`s law. 6 figs.

  20. Microseismic Tracer Particles for Hydraulic Fracturing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The trend toward production of hydrocarbons from unconventional reservoirs (tight gas, shale oilgas) has caused a large increase in the use of hydraulic fracture stimulation of...

  1. Method of determining the extent to which a nickel structure has been attached by a fluorine-containing gas

    DOE Patents [OSTI]

    Brusie, James P. (Oak Ridge, TN)

    2004-07-13

    The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

  2. Method of Determining the Extent to which a Nickel Structure has been Attached by a Fluorine-Containing Gas

    DOE Patents [OSTI]

    Brusie, James P.

    2004-07-13

    The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

  3. Tensor anisotropy as a tracer of cosmic voids

    E-Print Network [OSTI]

    Bustamante, Sebastian

    2015-01-01

    We present a new method to find voids in cosmological simulations based on the tidal and the velocity shear tensors definitions of the cosmic web. We use the fractional anisotropy (FA) computed from the eigenvalues of each web scheme as a void tracer. We identify voids using a watershed transform based on the local minima of the FA field without making any assumption on the shape or structure of the voids. We test the method on the Bolshoi simulation and report on the abundance and radial averaged profiles for the density, velocity and fractional anisotropy. We find that voids in the velocity shear web are smaller than voids in the tidal web, with a particular overabundance of very small voids in the inner region of filaments/sheets. We classify voids as subcompensated/overcompansated depending on the absence/presence of an overdense matter ridge in their density profile, finding that close to $65\\%$ and $35\\%$ of the total population are classified into each category, respectively. Finally, we find evidence ...

  4. Systems and methods of monitoring acoustic pressure to detect a flame condition in a gas turbine

    DOE Patents [OSTI]

    Ziminsky, Willy Steve (Simpsonville, SC); Krull, Anthony Wayne (Anderson, SC); Healy, Timothy Andrew (Simpsonville, SC), Yilmaz, Ertan (Glenville, NY)

    2011-05-17

    A method may detect a flashback condition in a fuel nozzle of a combustor. The method may include obtaining a current acoustic pressure signal from the combustor, analyzing the current acoustic pressure signal to determine current operating frequency information for the combustor, and indicating that the flashback condition exists based at least in part on the current operating frequency information.

  5. Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas (Morgantown, WV)

    1989-01-01

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

  6. Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor

    DOE Patents [OSTI]

    Mahajan, Devinder

    2005-07-26

    The invention provides a homogenous catalyst for the production of methanol from purified synthesis gas at low temperature and low pressure which includes a transition metal capable of forming transition metal complexes with coordinating ligands and an alkoxide, the catalyst dissolved in a methanol solvent system, provided the transition metal complex is not transition metal carbonyl. The coordinating ligands can be selected from the group consisting of N-donor ligands, P-donor ligands, O-donor ligands, C-donor ligands, halogens and mixtures thereof.

  7. Iron catalyst for preparation of polymethylene from synthesis gas and method for producing the catalyst

    DOE Patents [OSTI]

    Sapienza, Richard S. (1 Miller Ave., Shoreham, NY 11786); Slegeir, William A. (7 Florence Rd., Hampton Bays, NY 11946)

    1990-01-01

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

  8. Iron catalyst for preparation of polymethylene from synthesis gas and method for producing the catalyst

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.

    1990-05-15

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

  9. Gas-Tight Sealing Method for Solid Oxide Fuel Cells - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article)ForthcomingGENERALProblems I n QEstimates -GasPortal

  10. Method for silicon carbide production by reacting silica with hydrocarbon gas

    DOE Patents [OSTI]

    Glatzmaier, Gregory C. (Boulder, CO)

    1994-01-01

    A method is described for producing silicon carbide particles using a silicon source material and a hydrocarbon. The method is efficient and is characterized by high yield. Finely divided silicon source material is contacted with hydrocarbon at a temperature of 400.degree. C. to 1000.degree. C. where the hydrocarbon pyrolyzes and coats the particles with carbon. The particles are then heated to 1100.degree. C. to 1600.degree. C. to cause a reaction between the ingredients to form silicon carbide of very small particle size. No grinding of silicon carbide is required to obtain small particles. The method may be carried out as a batch process or as a continuous process.

  11. Batch methods for enriching trace impurities in hydrogen gas for their further analysis

    DOE Patents [OSTI]

    Ahmed, Shabbir; Lee, Sheldon H.D.; Kumar, Romesh; Papdias, Dionissios D.

    2014-07-15

    Provided herein are batch methods and devices for enriching trace quantities of impurities in gaseous mixtures, such as hydrogen fuel. The methods and devices rely on concentrating impurities using hydrogen transport membranes wherein the time period for concentrating the sample is calculated on the basis of optimized membrane characteristics, comprising its thickness and permeance, with optimization of temperature, and wherein the enrichment of trace impurities is proportional to the pressure ratio P.sub.hi/P.sub.lo and the volume ratio V.sub.1/V.sub.2, with following detection of the impurities using commonly-available detection methods.

  12. Method for silicon carbide production by reacting silica with hydrocarbon gas

    DOE Patents [OSTI]

    Glatzmaier, G.C.

    1994-06-28

    A method is described for producing silicon carbide particles using a silicon source material and a hydrocarbon. The method is efficient and is characterized by high yield. Finely divided silicon source material is contacted with hydrocarbon at a temperature of 400 C to 1000 C where the hydrocarbon pyrolyzes and coats the particles with carbon. The particles are then heated to 1100 C to 1600 C to cause a reaction between the ingredients to form silicon carbide of very small particle size. No grinding of silicon carbide is required to obtain small particles. The method may be carried out as a batch process or as a continuous process. 5 figures.

  13. Quantum Dot Tracers for Use in Engineered Geothermal Systems

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objective: To develop and demonstrate a new class of tracers?semiconductor nanoparticles(quantum dots)?that offer great promise for use in characterizing fracture networks in EGS reservoirs.

  14. Microfluidic Investigation of Tracer Dye Diffusion in Alumina Nanofluids 

    E-Print Network [OSTI]

    Ozturk, Serdar 1979-

    2012-10-05

    on enhanced mass diffusion and the possibility of tailoring mass transport by direct manipulation of molecular diffusion. Therefore, a microfluidic approach capable of directly probing tracer diffusion between nanoparticle-laden fluid streams was developed...

  15. Tracer advection by steady groundwater flow in a stratified aquifer

    SciTech Connect (OSTI)

    Sposito, Garrison; Weeks, Scott W.

    1997-01-02

    The perfectly stratified aquifer has often been investigated as a simple, tractable model for exploring new theoretical issues in subsurface hydrology. Adopting this approach, we show that steady groundwater flows in the perfectly stratified aquifer are always confined to a set of nonintersecting permanent surfaces, on which both streamlines and vorticity lines lie. This foliation of the flow domain exists as well for steady groundwater flows in any isotropic, spatially heterogeneous aquifer. In the present model example it is a direct consequence of the existence of a stream function, we then demonstrate that tracer plume advection by steady groundwater flow in a perfectly stratified aquifer is never ergodic, regardless of the initial size of the tracer plume. This nonergodicity, which holds also for tracer advection in any isotropic, spatially heterogeneous aquifer, implies that stochastic theories of purely advective tracer plume movement err in assuming ergodic behavior to simplify probabilistic calculations of plume spatial concentration moments.

  16. Adsorbed sulfur-gas methods for both near-surface exploration and downhole logging

    SciTech Connect (OSTI)

    Farwell, S.O.; Barinaga, C.J.; Dolenc, M.R.; Farwell, G.H.

    1986-08-01

    The use of sulfur-containing gases in petroleum exploration is supported by (1) the idea that sulfur may play a role in petroleum genesis, (2) the corresponding existence of sulfur-containing compounds in petroleum and the potential for vertical migration of the low-molecular-weight sulfur species from these reservoirs, (3) the production of H/sub 2/S by anaerobic microorganism populations that develop in the subsurface areas overlying petroleum reservoirs due to the concomitant supply of hydrocarbon nutrients, (4) the recent discovery of near-surface accumulations of pyrite and marcasite as the source of induction potential anomalies over certain fields, and (5) the strong adsorptive affinities of sulfur gases to solid surfaces, which enhance both the concentration and localization of such sulfur-expressed anomalies. During the past 3 years, numerous near-surface soil samples and well cuttings from the Utah-Wyoming Overthrust belt have been analyzed for adsorbed sulfur-gas content by two novel analytical techniques: thermal desorption/metal foil collection/flash desorption/sulfur-selective detection (TD/MFC/FD/SSD) and thermal desorption/cryogenic preconcentration/high-resolution-gas chromatography/optimized-flame photometry (TD/CP/HRGC/OFP).

  17. A Tracer Test Using Ethanol as a Two-Phase Tracer and 2-Naphthalene

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand Dalton JumpProgram |RecentSulfonate as a Liquid-Phase Tracer at the

  18. Method for extending the useful shelf-life of refrigerated red blood cells by flushing with inert gas

    DOE Patents [OSTI]

    Bitensky, M.W.; Yoshida, Tatsuro

    1997-04-29

    A method is disclosed using oxygen removal for extending the useful shelf-life of refrigerated red blood cells. A cost-effective, 4 C storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. Preservation of adenosine triphosphate levels and reduction in hemolysis and in membrane vesicle production of red blood cells stored at 4 C for prolonged periods of time is achieved by removing oxygen from the red blood cells at the time of storage; in particular, by flushing with an inert gas. Adenosine triphosphate levels of the stored red blood cells are boosted in some samples by addition of ammonium phosphate. 4 figs.

  19. Method for extending the useful shelf-life of refrigerated red blood cells by flushing with inert gas

    DOE Patents [OSTI]

    Bitensky, Mark W. (Los Alamos, NM); Yoshida, Tatsuro (Los Alamos, NM)

    1997-01-01

    Method using oxygen removal for extending the useful shelf-life of refrigerated red blood cells. A cost-effective, 4.degree. C. storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. Preservation of adenosine triphosphate levels and reduction in hemolysis and in membrane vesicle production of red blood cells stored at 4.degree. C. for prolonged periods of time is achieved by removing oxygen therefrom at the time of storage; in particular, by flushing with an inert gas. Adenosine triphosphate levels of the stored red blood cells are boosted in some samples by addition of ammonium phosphate.

  20. Effective thermal conductivity method for predicting spent nuclear fuel cladding temperatures in a dry fill gas

    SciTech Connect (OSTI)

    Bahney, Robert

    1997-12-19

    This paper summarizes the development of a reliable methodology for the prediction of peak spent nuclear fuel cladding temperature within the waste disposal package. The effective thermal conductivity method replaces other older methodologies.

  1. A Study Plan for Determining Recharge Rates at the Hanford Site Using Environmental Tracers

    SciTech Connect (OSTI)

    Murphy,, E. M.; Szecsody,, J. E.; Phillips,, S. J.

    1991-02-01

    This report presents a study plan tor estimating recharge at the Hanford Site using environmental tracers. Past operations at the Hanford Site have led to both soil and groundwater contamination, and recharge is one of the primary mechanisms for transporting contaminants through the vadose zone and into the groundwater. The prediction of contaminant movement or transport is one aspect of performance assessment and an important step in the remedial investigation/feasibility study (RI/FS) process. In the past, recharge has been characterized by collecting lysimeter data. Although lysimeters can generate important and reliable data, their limitations include 1) fixed location, 2) fixed sediment contents, 3) edge effects, 4) low rates, and 5) relatively short duration of measurement. These limitations impact the ability to characterize the spatial distribution of recharge at the Hanford Site, and thus the ability to predict contaminant movement in the vadose zone. An alternative to using fixed lysimeters for determining recharge rates in the vadose zone is to use environmental tracers. Tracers that have been used to study water movement in the vadose zone include total chloride, {sup 36}CI, {sup 3}H, and {sup 2}H/{sup 18}O. Atmospheric levels of {sup 36}CI and {sup 3}H increased during nuclear bomb testing in the Pacific, and the resulting "bomb pulse" or peak concentration can be measured in the soil profile. Locally, past operations at the Hanford Site have resu~ed in the atmospheric release of numerous chemical and isotopic tracers, including nitrate, {sup 129}I, and {sup 99}Tc. The radionuclides, in particular, reached a well-defined atmospheric peak in 1945. Atmospheric releases of {sup 129}I and {sup 99}Tc were greatly reduced by mid-1946, but nitrogen oxides continued to be released from the uranium separations facilities. As a result, the nitrate concentrations probably peaked in the mid-1950s, when the greatest number of separations facilities were operating. Seven study sites on the Hanford Site have been selected, in two primary soil types that are believed to represent the extremes in recharge, the Quincy sand and the Warden silt loam. An additional background study site upwind of the Hanford facilities has been chosen at the Yakima Firing Center. Study sites at Hanford were chosen close to micrometeorology stations on downwind transects from the operational facilities. Initial testing will be done on sites that lack perennial vegetation. Six tracer techniques (total chlortde, {sup 36}Cl, {sup 3}H, nitrate, {sup 129}I, and {sup 99}Tc) will be tested on at least one site in the Quincy sand, one site in the Warden si~ loam, and the background site, to determine which combination of tracers wortks best for a given soil type. In subsequent years, additional sites will be investigated to determine the effect of vegetation on recharge estimates and on the performance of individual tracers. The use of environmental tracers is perhaps the only cost-effective method for estimating the spatial vartability of recharge at a site as large as Hanford. The tracer techniques used at Hanford have wide applicability at other and sites operated by the U.S. Department of Energy as well as at low-level radioactive waste disposal sites.

  2. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOE Patents [OSTI]

    Castellano, Christopher R. (Ringoes, NJ); Moini, Ahmad (Princeton, NJ); Koermer, Gerald S. (Basking Ridge, NJ); Furbeck, Howard (Hamilton, NJ); Schmieg, Steven J. (Troy, MI); Blint, Richard J. (Shelby Township, MI)

    2011-05-17

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver and a platinum group metal on a particulate alumina support, the atomic fraction of the platinum group metal being less than or equal to about 0.25. Methods of manufacturing catalysts are described in which silver is impregnated on alumina particles.

  3. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOE Patents [OSTI]

    Koermer, Gerald S. (Basking Ridge, NJ); Moini, Ahmad (Princeton, NJ); Furbeck, Howard (Hamilton, NJ); Castellano, Christopher R. (Ringoes, NJ)

    2012-05-08

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver on a particulate alumina support, the silver having a diameter of less than about 20 nm. Methods of manufacturing catalysts are described in which ionic silver is impregnated on particulate hydroxylated alumina particles.

  4. Green River air quality model development: meteorological and tracer data, July/August 1982 field study in Brush Valley, Colorado

    SciTech Connect (OSTI)

    Whiteman, C.D.; Lee, R.N.; Orgill, M.M.; Zak, B.D.

    1984-06-01

    Meteorological and atmospheric tracer studies were conducted during a 3-week period in July and August of 1982 in the Brush Creek Valley of northwestern Colorado. The objective of the field experiments was to obtain data to evaluate a model, called VALMET, developed at PNL to predict dispersion of air pollutants released from an elevated stack located within a deep mountain valley in the post-sunrise temperature inversion breakup period. Three tracer experiments were conducted in the valley during the 2-week period. In these experiments, sulfur hexafluoride (SF/sub 6/) was released from a height of approximately 100 m, beginning before sunrise and continuing until the nocturnal down-valley winds reversed several hours after sunrise. Dispersion of the sulfur hexafluoride after release was evaluated by measuring SF/sub 6/ concentrations in ambient air samples taken from sampling devices operated within the valley up to about 8 km down valley from the source. An instrumented research aircraft was also used to measure concentrations in and above the valley. Tracer samples were collected using a network of radio-controlled bag sampling stations, two manually operated gas chromatographs, a continuous SF/sub 6/ monitor, and a vertical SF/sub 6/ profiler. In addition, basic meteorological data were collected during the tracer experiments. Frequent profiles of vertical wind and temperature structure were obtained with tethered balloons operated at the release site and at a site 7.7 km down the valley from the release site. 10 references, 63 figures, 50 tables.

  5. Resuspension rates from aged inert-tracer sources

    SciTech Connect (OSTI)

    Sehmel, G.A.

    1982-11-01

    Wind-caused particle resuspension rates were investigated with molybdenum tracers at two circular resuspension sites in the Hanford area. The tracer particles were calcium molybdate. The radii of each circular tracer-source area were 22.9 m and 29.9 m respectively for tracer deposited on 2 October 1973 and 29 May 1979. Resuspension rates were investigated by sampling resuspended tracer with air sampling equipment mounted as a function of height on a centrally located sampling tower at each site. Sampling equipment was operated as a function of wind speed increments in order to investigate resuspension rates, wind speed dependencies of resuspension rates, and for subsequent comparisons of resuspension rate changes as a function of time for constant wind speed ranges. Experimental results are reported for measurements over several years. Resuspension rates ranged from about 10/sup -13/ to 10/sup -6/ fraction of the tracer source resuspended per second. Resuspension rates tended to increase with increasing wind speed. At one investigation site, resuspension rates were nearly constant, except for seasonal variations, for a four-year time period. Resuspension rates appear higher in the autumn than in the spring and summer.

  6. Compressor discharge bleed air circuit in gas turbine plants and related method

    DOE Patents [OSTI]

    Anand, Ashok Kumar (Niskayuna, NY); Berrahou, Philip Fadhel (Latham, NY); Jandrisevits, Michael (Clifton Park, NY)

    2002-01-01

    A gas turbine system that includes a compressor, a turbine component and a load, wherein fuel and compressor discharge bleed air are supplied to a combustor and gaseous products of combustion are introduced into the turbine component and subsequently exhausted to atmosphere. A compressor discharge bleed air circuit removes bleed air from the compressor and supplies one portion of the bleed air to the combustor and another portion of the compressor discharge bleed air to an exhaust stack of the turbine component in a single cycle system, or to a heat recovery steam generator in a combined cycle system. In both systems, the bleed air diverted from the combustor may be expanded in an air expander to reduce pressure upstream of the exhaust stack or heat recovery steam generator.

  7. Compressor discharge bleed air circuit in gas turbine plants and related method

    DOE Patents [OSTI]

    Anand, Ashok Kumar (Niskayuna, NY); Berrahou, Philip Fadhel (Latham, NY); Jandrisevits, Michael (Clifton Park, NY)

    2003-04-08

    A gas turbine system that includes a compressor, a turbine component and a load, wherein fuel and compressor discharge bleed air are supplied to a combustor and gaseous products of combustion are introduced into the turbine component and subsequently exhausted to atmosphere. A compressor discharge bleed air circuit removes bleed air from the compressor and supplies one portion of the bleed air to the combustor and another portion of the compressor discharge bleed air to an exhaust stack of the turbine component in a single cycle system, or to a heat recovery steam generator in a combined cycle system. In both systems, the bleed air diverted from the combustor may be expanded in an air expander to reduce pressure upstream of the exhaust stack or heat recovery steam generator.

  8. HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS

    SciTech Connect (OSTI)

    Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

    2012-01-01

    The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

  9. Apparatus and method for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Felix, Larry Gordon; Farthing, William Earl; Irvin, James Hodges; Snyder, Todd Robert

    2010-05-11

    A dilution apparatus for diluting a gas sample. The apparatus includes a sample gas conduit having a sample gas inlet end and a diluted sample gas outlet end, and a sample gas flow restricting orifice disposed proximate the sample gas inlet end connected with the sample gas conduit and providing fluid communication between the exterior and the interior of the sample gas conduit. A diluted sample gas conduit is provided within the sample gas conduit having a mixing end with a mixing space inlet opening disposed proximate the sample gas inlet end, thereby forming an annular space between the sample gas conduit and the diluted sample gas conduit. The mixing end of the diluted sample gas conduit is disposed at a distance from the sample gas flow restricting orifice. A dilution gas source connected with the sample gas inlet end of the sample gas conduit is provided for introducing a dilution gas into the annular space, and a filter is provided for filtering the sample gas. The apparatus is particularly suited for diluting heated sample gases containing one or more condensable components.

  10. Method of and apparatus for measuring the mean concentration of thoron and/or radon in a gas mixture

    DOE Patents [OSTI]

    Lucas, Henry (P.O. Box 1454, Sedona, AZ 86336)

    1990-01-01

    A method of and an apparatus for detecting and accurately measuring the mean concentrations of .sup.222 Rn and .sup.220 Tn in a gas mixture, such as the ambient atmosphere in a mine, is provided. The apparatus includes an alpha target member which defines at least one operative target surface and which is preferably fabricated from a single piece of an alpha particle sensitive material. At least one portion of the operative target surface is covered with an alpha particle filter. The uncovered and filter covered operative surface is exposed to the gas mixture containing the .sup.222 Rn and .sup.220 Tn. In the radioactive decay series of these isotopes the maximum kinetic energy emitted by the alpha decay of .sup.222 Rn is about 1.1 MeV less than the maximum kinetic energy emitted by the alpha decay of a .sup.220 Tn. The alpha particle filter has a predetermined mass per unit area of the covered portion of the operative target surface that prevents penetration of alpha particles which originate from .sup.222 Rn decay, but which allows passage therethrough of the maximum kinetic energy alpha particles from .sup.220 Tn decay. Thus, a count of the alpha particle tracks in the uncovered portion of the target member is proportional to the mean concentration of sum of .sup.222 Rn and .sup.220 Tn in the gas mixture, while the count of alpha tracks in the target member under the filter is proportional to the concentration of only the .sup.220 Tn in the gas mixture.

  11. Flow injection trace gas analysis method for on-site determination of organoarsenicals

    DOE Patents [OSTI]

    Aldstadt, J.H. III

    1997-06-24

    A method is described for real-time determination of the concentration of Lewisite in the ambient atmosphere, the method includes separating and collecting a Lewisite sample from the atmosphere in a collection chamber, converting the collected Lewisite to an arsenite ion solution sample, pumping the arsenite ion containing sample to an electrochemical detector connected to the collection chamber, and electrochemically detecting the converted arsenite ions in the sample, whereby the concentration of arsenite ions detected is proportional to the concentration of Lewisite in the atmosphere. 2 figs.

  12. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, D. Kwok-Keung; Chang, Shih-Ger

    1987-08-25

    The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

  13. APPLICATIONS OF CFD METHOD TO GAS MIXING ANALYSIS IN A LARGE-SCALED TANK

    SciTech Connect (OSTI)

    Lee, S; Richard Dimenna, R

    2007-03-19

    The computational fluid dynamics (CFD) modeling technique was applied to the estimation of maximum benzene concentration for the vapor space inside a large-scaled and high-level radioactive waste tank at Savannah River site (SRS). The objective of the work was to perform the calculations for the benzene mixing behavior in the vapor space of Tank 48 and its impact on the local concentration of benzene. The calculations were used to evaluate the degree to which purge air mixes with benzene evolving from the liquid surface and its ability to prevent an unacceptable concentration of benzene from forming. The analysis was focused on changing the tank operating conditions to establish internal recirculation and changing the benzene evolution rate from the liquid surface. The model used a three-dimensional momentum coupled with multi-species transport. The calculations included potential operating conditions for air inlet and exhaust flows, recirculation flow rate, and benzene evolution rate with prototypic tank geometry. The flow conditions are assumed to be fully turbulent since Reynolds numbers for typical operating conditions are in the range of 20,000 to 70,000 based on the inlet conditions of the air purge system. A standard two-equation turbulence model was used. The modeling results for the typical gas mixing problems available in the literature were compared and verified through comparisons with the test results. The benchmarking results showed that the predictions are in good agreement with the analytical solutions and literature data. Additional sensitivity calculations included a reduced benzene evolution rate, reduced air inlet and exhaust flow, and forced internal recirculation. The modeling results showed that the vapor space was fairly well mixed and that benzene concentrations were relatively low when forced recirculation and 72 cfm ventilation air through the tank boundary were imposed. For the same 72 cfm air inlet flow but without forced recirculation, the heavier benzene gas was stratified. The results demonstrated that benzene concentrations were relatively low for typical operating configurations and conditions. Detailed results and the cases considered in the calculations will be discussed here.

  14. Casting Apparatus Including A Gas Driven Molten Metal Injector And Method

    DOE Patents [OSTI]

    Meyer, Thomas N. (Murrysville, PA)

    2004-06-01

    The casting apparatus (50) includes a holding vessel (10) for containing a supply of molten metal (12) and a casting mold (52) located above the holding vessel (10) and having a casting cavity (54). A molten metal injector (14) extends into the holding vessel (10) and is at least partially immersed in the molten metal (12) in the holding vessel (10). The molten metal injector (14) is in fluid communication with the casting cavity (54). The molten metal injector (14) has an injector body (16) defining an inlet opening (24) for receiving molten metal into the injector body (16). A gas pressurization source (38) is in fluid communication with the injector body (16) for cyclically pressurizing the injector body (16) and inducing molten metal to flow from the injector body (16) to the casting cavity (54). An inlet valve (42) is located in the inlet opening (24) in the injector body (16) for filling molten metal into the injector body (16). The inlet valve (42) is configured to prevent outflow of molten metal from the injector body (16) during pressurization and permit inflow of molten metal into the injector body (16) after pressurization. The inlet valve (42) has an inlet valve actuator (44) located above the surface of the supply of molten metal (12) and is operatively connected to the inlet valve (42) for operating the inlet valve (42) between open and closed positions.

  15. Method and system for capturing carbon dioxide and/or sulfur dioxide from gas stream

    DOE Patents [OSTI]

    Chang, Shih-Ger; Li, Yang; Zhao, Xinglei

    2014-07-08

    The present invention provides a system for capturing CO.sub.2 and/or SO.sub.2, comprising: (a) a CO.sub.2 and/or SO.sub.2 absorber comprising an amine and/or amino acid salt capable of absorbing the CO.sub.2 and/or SO.sub.2 to produce a CO.sub.2- and/or SO.sub.2-containing solution; (b) an amine regenerator to regenerate the amine and/or amino acid salt; and, when the system captures CO.sub.2, (c) an alkali metal carbonate regenerator comprising an ammonium catalyst capable catalyzing the aqueous alkali metal bicarbonate into the alkali metal carbonate and CO.sub.2 gas. The present invention also provides for a system for capturing SO.sub.2, comprising: (a) a SO.sub.2 absorber comprising aqueous alkali metal carbonate, wherein the alkali metal carbonate is capable of absorbing the SO.sub.2 to produce an alkali metal sulfite/sulfate precipitate and CO.sub.2.

  16. Methods for disassembling, replacing and assembling parts of a steam cooling system for a gas turbine

    DOE Patents [OSTI]

    Wilson, Ian D. (Mauldin, SC); Wesorick, Ronald R. (Albany, NY)

    2002-01-01

    The steam cooling circuit for a gas turbine includes a bore tube assembly supplying steam to circumferentially spaced radial tubes coupled to supply elbows for transitioning the radial steam flow in an axial direction along steam supply tubes adjacent the rim of the rotor. The supply tubes supply steam to circumferentially spaced manifold segments located on the aft side of the 1-2 spacer for supplying steam to the buckets of the first and second stages. Spent return steam from these buckets flows to a plurality of circumferentially spaced return manifold segments disposed on the forward face of the 1-2 spacer. Crossover tubes couple the steam supply from the steam supply manifold segments through the 1-2 spacer to the buckets of the first stage. Crossover tubes through the 1-2 spacer also return steam from the buckets of the second stage to the return manifold segments. Axially extending return tubes convey spent cooling steam from the return manifold segments to radial tubes via return elbows. The bore tube assembly, radial tubes, elbows, manifold segments and crossover tubes are removable from the turbine rotor and replaceable.

  17. A Really Good Hammer: Quantification of Mass Transfer Using Perfluorocarbon Tracers (475th Brookhaven Lecture)

    SciTech Connect (OSTI)

    Watson, Tom

    2012-02-15

    Brookhaven Lab’s perfluorocarbon tracer (PFT) technology can be viewed as a hammer looking for nails. But, according to Tom Watson, leader of the Lab’s Tracer Technology Group in the Environmental Research and Technology Division (ERTD), “It’s a really good hammer!” The colorless, odorless and safe gases have a number of research uses, from modeling how airborne contaminants might move through urban canyons to help first responders plan their response to potential terrorist attacks and accidents to locating leaks in underground gas pipes. Their extremely low background level — detectable at one part per quadrillion — allows their transport to be easily tracked. Lab researchers used PFTs during the 2005 Urban Dispersion Program field studies in New York City, gathering data to help improve models of how a gas or chemical release might move around Manhattan’s tall buildings and canyons. Closer to home, scientists also used PFTs to make ventilation measurements in Bldg. 400 on the Lab site to provide data to test air flow models used in determining the effects of passive and active air exchange on the levels of indoor and outdoor air pollution, and to determine the effects of an accidental or intentional release of hazardous substances in or around buildings.

  18. Apparatus and method for mixing fuel in a gas turbine nozzle

    DOE Patents [OSTI]

    Johnson, Thomas Edward; Ziminsky, Willy Steve; Berry, Jonathan Dwight

    2014-08-12

    A nozzle includes a fuel plenum and an air plenum downstream of the fuel plenum. A primary fuel channel includes an inlet in fluid communication with the fuel plenum and a primary air port in fluid communication with the air plenum. Secondary fuel channels radially outward of the primary fuel channel include a secondary fuel port in fluid communication with the fuel plenum. A shroud circumferentially surrounds the secondary fuel channels. A method for mixing fuel and air in a nozzle prior to combustion includes flowing fuel to a fuel plenum and flowing air to an air plenum downstream of the fuel plenum. The method further includes injecting fuel from the fuel plenum through a primary fuel passage, injecting fuel from the fuel plenum through secondary fuel passages, and injecting air from the air plenum through the primary fuel passage.

  19. Catalysts, systems and methods to reduce NOX in an exhaust gas stream

    DOE Patents [OSTI]

    Castellano, Christopher R. (Ringoes, NJ); Moini, Ahmad (Princeton, NJ); Koermer, Gerald S. (Basking Ridge, NJ); Furbeck, Howard (Hamilton, NJ)

    2010-07-20

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having an SCR catalyst comprising silver tungstate on an alumina support. The emissions treatment system may be used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines. An emissions treatment system may further comprise an injection device operative to dispense a hydrocarbon reducing agent upstream of the catalyst.

  20. Device and method for the measurement of gas permeability through membranes

    DOE Patents [OSTI]

    Agarwal, Pradeep K.; Ackerman, John; Borgialli, Ron; Hamann, Jerry; Muknahalliptna, Suresh

    2006-08-08

    A device for the measuring membrane permeability in electrical/electrochemical/photo-electrochemical fields is provided. The device is a permeation cell and a tube mounted within the cell. An electrode is mounted at one end of the tube. A membrane is mounted within the cell wherein a corona is discharged from the electrode in a general direction toward the membrane thereby generating heated hydrogen atoms adjacent the membrane. A method for measuring the effects of temperature and pressure on membrane permeability and selectivity is also provided.

  1. Nonthermal plasma systems and methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C.; Nelson, Lee O.; Detering, Brent A.

    2005-05-24

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  2. Method for improving dissolution efficiency in gas-absorption and liquid extraction processes. [Patent application

    DOE Patents [OSTI]

    Kanak, B.E.; Stephenson, M.J.

    1980-01-11

    A method is described for improving dissolution efficiency in processes in which a feed fluid is introduced to a zone where it is contacted with a liquid solvent for preferentially removing a component of the feed and where part of the solvent so contacted undergoes transfer into the feed fluid to saturate the same. It has been found that such transfer significantly impairs dissolution efficiency. In accordance with the invention, an amount of the above-mentioned solvent is added to the feed fluid being introduced to the contact zone, the solvent being added in an amount sufficient to effect reduction or elimination of the above-mentioned transfer. Preferably, the solvent is added to the feed fluid in an amount saturating or supersaturating the feed fluid under the conditions prevailing in the contact zone.

  3. Motorola's Exhaust Optimization Program: Tracer Gas Application for Gas Panel Enclosures 

    E-Print Network [OSTI]

    Myart, H. R.; Camacho, R.

    2003-01-01

    , May 13-16, 2003 APPENDIX A Tool A Test #1 Full Analysis at 61 CFM SAMPL~ LOCATION TIME PDCB CONC (PPB) ERC (PPB) %TLV SEMI S2-u:wu RESULT Ll 1 MIN 0 0 0.0% PASS 3MTN 0.164 54.7 0.2% PASS 5 MIN 1.27 423 1.7% PASS 6 MIN 0 0 0.0% PASS L2 1... MIN 0 0 0.0% PASS 3 MIN 1.14 380 1.5% PASS 5 MIN 3.85 1283 5.0% PASS 6MTN 0 0 0.0% PASS L3 1 MIN 0 0 0.0% PASS 3 MIN 0 0 0.0% PASS 5MTN 2.22 740 3.0% PASS 6 MIN 0 0 0.0% PASS Tool B Test #1 Full Analysis at 354 CFM Ll 1 MIN 0 0 0.0% PASS 3...

  4. The Tremaine-Weinberg method for pattern speeds using H-alpha emission from ionized gas

    E-Print Network [OSTI]

    John E. Beckman; Kambiz Fathi; Núria Piñol; Silvia Toonen; Olivier Hernandez; Claude Carignan

    2008-01-18

    The Fabry-Perot interferometer FaNTOmM was used at the 3.6m Canada France Hawaii Telescope and the 1.6m Mont Megantic Telescope to obtain data cubes in H-alpha of 9 nearby spiral galaxies from which maps in integrated intensity, velocity, and velocity dispersion were derived. We then applied the Tremaine-Weinberg method, in which the pattern speed can be deduced from its velocity field, by finding the integrated value of the mean velocity along a slit parallel to the major axis weighted by the intensity and divided by the weighted mean distance of the velocity points from the tangent point measured along the slit. The measured variables can be used either to make separate calculations of the pattern speed and derive a mean, or in a plot of one against the other for all the points on all slits, from which a best fit value can be derived. Linear fits were found for all the galaxies in the sample. For two galaxies a clearly separate inner pattern speed with a higher value, was also identified and measured.

  5. The Tremaine-Weinberg method for pattern speeds using H-alpha emission from ionized gas

    E-Print Network [OSTI]

    Beckman, John E; Piñol, Núria; Toonen, Silvia; Hernandez, Olivier; Carignan, Claude

    2007-01-01

    The Fabry-Perot interferometer FaNTOmM was used at the 3.6m Canada France Hawaii Telescope and the 1.6m Mont Megantic Telescope to obtain data cubes in H-alpha of 9 nearby spiral galaxies from which maps in integrated intensity, velocity, and velocity dispersion were derived. We then applied the Tremaine-Weinberg method, in which the pattern speed can be deduced from its velocity field, by finding the integrated value of the mean velocity along a slit parallel to the major axis weighted by the intensity and divided by the weighted mean distance of the velocity points from the tangent point measured along the slit. The measured variables can be used either to make separate calculations of the pattern speed and derive a mean, or in a plot of one against the other for all the points on all slits, from which a best fit value can be derived. Linear fits were found for all the galaxies in the sample. For two galaxies a clearly separate inner pattern speed with a higher value, was also identified and measured.

  6. Field data on testing of natural gas vehicle (NGV) containers using proposed ASTM standard test method for examination of gas-filled filament-wound pressure vessels using acoustic emission (ASTM-E070403-95/1)

    SciTech Connect (OSTI)

    Fultineer, R.D. Jr.; Mitchell, J.R.

    1999-07-01

    There are many composite wrapped pressure vessels in service. These containers are most widely used for gas storage in natural gas vehicles (NGV). A standard has been developed for the testing of these vessels by the subcommittee ASTM E07.04.03 Acoustic Emission (AE) applications. The AE test method is supported by both field test data and laboratory destructive testing. The test method describes a global volumetric testing technique which is offered as an alternative to the current practice of visual inspection.

  7. Equation of state of a weakly interacting two-dimensional Bose gas studied at zero temperature by means of quantum Monte Carlo methods

    SciTech Connect (OSTI)

    Astrakharchik, G. E.; Boronat, J.; Casulleras, J.; Kurbakov, I. L.; Lozovik, Yu. E.

    2009-05-15

    The equation of state of a weakly interacting two-dimensional Bose gas is studied at zero temperature by means of quantum Monte Carlo methods. Going down to as low densities as na{sup 2}{proportional_to}10{sup -100} permits us to obtain agreement on beyond mean-field level between predictions of perturbative methods and direct many-body numerical simulation, thus providing an answer to the fundamental question of the equation of state of a two-dimensional dilute Bose gas in the universal regime (i.e., entirely described by the gas parameter na{sup 2}). We also show that the measure of the frequency of a breathing collective oscillation in a trap at very low densities can be used to test the universal equation of state of a two-dimensional Bose gas.

  8. Effects from influent boundary conditions on tracer migration and spatial variability features in intermediate-scale experiments

    SciTech Connect (OSTI)

    Fuentes, H.R.; Polzer, W.L.; Springer, E.P.

    1987-04-01

    In previous unsaturated transport studies at Los Alamos dispersion coefficients were estimated to be higher close to the tracer source than at greater distances from the source. Injection of tracers through discrete influent outlets could have accounted for those higher dispersions. Also, a lack of conservation of mass of the tracers was observed and suspected to be due to spatial variability in transport. In the present study experiments were performed under uniform influent (ponded) conditions in which breakthrough of tracers was monitored at four locations at each of four depths. All other conditions were similar to those of the unsaturated transport experiments. A comparison of results from these two sets of experiments indicates differences in the parameter estimates. Estimates were made for the dispersion coefficient and the retardation factor by the one-dimensional steady flow computer code, CFITIM. Estimates were also made for mass and for velocity and the dispersion coefficient by the method of moments. The dispersion coefficient decreased with depth under discrete influent application and increased with depth under ponded influent application. Retardation was predicted better under the discrete influent application than under ponded influent application. Differences in breakthroughs and in estimated parameters among locations at the same depth were observed under ponded influent application. Those differences indicate that there is a lack of conservation of mass as well as significant spatial variability across the experimental domain. 14 refs., 9 figs., 8 tabs.

  9. Development and verification of new semi-analytical methods for the analysis and prediction of gas well performance 

    E-Print Network [OSTI]

    Knowles, Robert Stephen

    1999-01-01

    regarding gas properties (i.e., [] = constant, [] = constant, etc.), which eliminates the need for the pseudopressure and pseudotime functions. In particular, these new solutions should lend themselves to use for the analysis of low pressure gas reservoirs...

  10. A Simple Method to Continuous Measurement of Energy Consumption of Tank Less Gas Water Heaters for Commercial Buildings 

    E-Print Network [OSTI]

    Yamaha, M.; Fujita, M.; Miyoshi, T.

    2006-01-01

    energy consumptions of hot water supply in restaurants or residential houses are large amount, guidelines for optimal design are not presented. measurements of energy consumption of tank less gas water heaters very difficult unless gas flow meters...

  11. Microsoft Word - S04040_tracer.doc

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbinsMonumentThird Five-Year ReviewOffice ofDispersivity

  12. An Embedded Boundary Method for the Modeling of Unsteady Combustion in an Industrial GasFired Furnace \\Lambda

    E-Print Network [OSTI]

    Bell, John B.

    the simulation of an experimental natural gas­fired furnace are shown. \\Lambda This work was performed under

  13. An Embedded Boundary Method for the Modeling of Unsteady Combustion in an Industrial GasFired Furnace \\Lambda

    E-Print Network [OSTI]

    Bell, John B.

    the simulation of an experimental natural gas­fired furnace are shown. 1 Introduction The ability to model the simulation of an experimental natural gas­fired furnace are shown. \\Lambda This work was performed under a a two­step scheme for natural gas combustion [30] coupled with a simplified turbulent kinetics model [6

  14. COS: A new tracer to constrain photosynthetic CO2 fluxes

    E-Print Network [OSTI]

    Einat, Aharonov

    COS: A new tracer to constrain photosynthetic CO2 fluxes Dan Yakir1, Max Berkelhammer2, Hulin Chen2 COS (110-190) Indirect CS2, DMS (149-330) Unknown (~600) Stratosphere COSàSO2 OH uptake (82-110) Global COS Budget (Gg S a-1; Kettle et al., 2002; Montzka et al., 2007; Berry et al., 2013 ) Mean

  15. THE EFFECT OF TRANSVERSE MIXING ON TRACER DISPERSION

    E-Print Network [OSTI]

    Stanford University

    Hardware Data Acquisition And Analysis Software Experimental Procedure Analysis Procedure Results: Taylor. The theoretical response for linear Taylor dispersion was matched to the data to determine the non-linear Of Tracer Valve Constant-pressure Reservoir Design Schematic Drawing Of Electrode Circuit Results: Run 16

  16. Calibration of hydraulic and tracer tests in fractured media

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    Calibration of hydraulic and tracer tests in fractured media represented by a DFN Model L. D. Donado, X. Sanchez-Vila, E. Ruiz* & F. J. Elorza** * Enviros Spain S.L. ** UPM #12;Fractured Media Water flows through fractures (matrix basically impervious ­ though relevant to transport) Fractures at all

  17. Dispersivity estimates from a tracer experiment in a sandy aquifer

    SciTech Connect (OSTI)

    Mallants, D.; Espino, A.; Van Hoorick, M.; Feyen, J.; Vandenberghe, N.; Loy, W.

    2000-04-01

    The success or failure of transport models in predicting the migration of a contaminant plume is ground water depends to a large extent on the quality of flow and transport parameters used. In this study, the authors investigate the spatial variability in the tracer velocity and dispersivity in a shallow sandy aquifer in northern Belgium. Based on hydraulic conductivity measurements on cores sampled along a vertical profile, the aquifer was found to be mildly heterogeneous, i.e., with the variance of the log-transformed conductivity K, {sigma}{sup 2}{sub lnK}, equal to 0.22. By means of a natural gradient tracer experiment, transport of a chloride tracer was investigated in a three-dimensional network of multilevel point samplers (MLS). Least squares fitting of a two-dimensional transport model to the individual breakthrough curves resulted in an average longitudinal dispersivity that was 10 times larger than the transverse dispersivity. The results further showed the existence of a dispersion-scale effect whereby the depth-averaged longitudinal dispersivity increases with increasing travel distance. The average longitudinal dispersivity corresponding to a travel distance of 10 m was equal to 0.2 m. The authors finally show that theoretical expressions for the macroscopic dispersivity tensor, which require input on hydraulic conductivity heterogeneity, could be used here to approximate the observed dispersive behavior. These conceptually simple models are useful to estimate macroscopic dispersivities when no tracer data are available.

  18. Almost Periodic Passive Tracer Dispersion \\Lambda Hongjun Gao 1 , Jinqiao Duan 2 and Xinchu Fu 3

    E-Print Network [OSTI]

    Almost Periodic Passive Tracer Dispersion \\Lambda Hongjun Gao 1 , Jinqiao Duan 2 and Xinchu Fu 3 1 the impact of external sources on the pat­ tern formation of concentration profiles of passive tracers Science Foundation Grant DMS­ 9704345 and the UK EPSRC Grant GR/M36335. 1 #12; Key words: Passive tracer

  19. Passive tracer patchiness and particle trajectory stability in incompressible two-dimensional flows

    E-Print Network [OSTI]

    Olascoaga, Maria Josefina

    Passive tracer patchiness and particle trajectory stability in incompressible two-dimensional flows in Geophysics (2003) 1:1­8 Nonlinear Processes in Geophysics c European Geophysical Society 2003 Passive tracer." This leads to patchiness in the evolution of passive tracer distribu- tions. Also, it is argued

  20. Passive tracer reconstruction as a least-squares problem with a semi-Lagrangian constraint

    E-Print Network [OSTI]

    deYoung, Brad

    Passive tracer reconstruction as a least-squares problem with a semi-Lagrangian constraint-dimensional, nonstationary, passive tracer field in the ocean with open boundaries and a known velocity field. The observations, spatial smoothing terms and passive tracer conservation equation were included as weak

  1. Numerical simulations of radon as an in situ partitioning tracer for quantifying NAPL

    E-Print Network [OSTI]

    Semprini, Lewis

    Numerical simulations of radon as an in situ partitioning tracer for quantifying NAPL contamination­pull partitioning tracer tests using radon-222 to quantify non- aqueous phase liquid contamination. J. Contam. Hydrol. 58, 129­146] of push­pull tests using radon as a naturally occurring partitioning tracer

  2. SOURCES AND EFFECTS OF MINING-RELATED AND NATURAL ACID ROCK DRAINAGE QUANTIFIED USING TRACER

    E-Print Network [OSTI]

    Ryan, Joe

    SOURCES AND EFFECTS OF MINING-RELATED AND NATURAL ACID ROCK DRAINAGE QUANTIFIED USING TRACER Acid Rock Drainage Quantified Using Tracer Dilution, Coal Creek Watershed, Gunnison County, Colorado of Mining-Related and Natural Acid Drainage Quantified Using Tracer Dilution, Coal Creek Watershed, Gunnison

  3. Method and apparatus for the separation of a gas-solids mixture in a circulating fluidized bed reactor

    DOE Patents [OSTI]

    Vimalchand, Pannalal (Birmingham, AL); Liu, Guohai (Birmingham, AL); Peng, WanWang (Birmingham, AL)

    2010-08-10

    The system of the present invention includes a centripetal cyclone for separating particulate material from a particulate laden gas solids stream. The cyclone includes a housing defining a conduit extending between an upstream inlet and a downstream outlet. In operation, when a particulate laden gas-solids stream passes through the upstream housing inlet, the particulate laden gas-solids stream is directed through the conduit and at least a portion of the solids in the particulate laden gas-solids stream are subjected to a centripetal force within the conduit.

  4. A Spreadsheet Program for Two-Well Tracer Test Data Analysis

    SciTech Connect (OSTI)

    Tang, Guoping [ORNL; Watson, David [ORNL; Parker, Jack C. [University of Tennessee, Knoxville (UTK); Brooks, Scott C [ORNL

    2011-01-01

    Two-well tracer tests are often conducted to investigate subsurface solute transport in the field. Analyzing breakthrough curves in extraction and monitoring wells using numerical methods is nontrivial due to highly nonuniform flow conditions. We extended approximate analytical solutions for the advection-dispersion equation for an injection-extraction well doublet in a homogeneous confined aquifer under steady-state flow conditions for equal injection and extraction rates with no transverse dispersion and negligible ambient flow, and implemented the solutions in Microsoft Excel using Visual Basic for Application (VBA). Functions were implemented to calculate concentrations in extraction and monitoring wells at any location due to a step or pulse injection. Type curves for a step injection were compared with those calculated by numerically integrating the solution for a pulse injection. The results from the two approaches are similar when the dispersivity is small. As the dispersivity increases, the latter was found to be more accurate but requires more computing time. The code was verified by comparing the results with published-type curves and applied to analyze data from the literature. The method can be used as a first approximation for two-well tracer test design and data analysis, and to check accuracy of numerical solutions. The code and example files are publicly available.

  5. Please cite this article in press as: Gilfillan, S.M.V., et al., He and Ne as tracers of natural CO2 migration up a fault from a deep reservoir. Int. J. Greenhouse Gas Control (2011), doi:10.1016/j.ijggc.2011.08.008

    E-Print Network [OSTI]

    Wilkinson, Mark

    2011-01-01

    in the deep reservoir, can be traced along a fault plane to occur in waters from both groundwater wells2 migration up a fault from a deep reservoir. Int. J. Greenhouse Gas Control (2011), doi:10.1016/j migration up a fault from a deep reservoir Stuart M.V. Gilfillana, , Mark Wilkinsona , R. Stuart Haszeldinea

  6. Process Design, Simulation and Integration of Dimethyl Ether (DME) Production from Shale Gas by Direct and Indirect Methods 

    E-Print Network [OSTI]

    Karagoz, Secgin

    2014-08-11

    of sustainable energy. Over the last decade, the U.S has witnessed substantial growth in shale gas production. Consequently, shale gas has become a competitive feedstock for usage as energy and production of chemicals and petrochemicals. A valuable product which...

  7. Monitoring of saline tracer movement with vertically distributed self-potential measurements at the HOBE agricultural test site, Voulund, Denmark

    E-Print Network [OSTI]

    Jougnot, Damien; Haarder, Eline B; Looms, Majken C

    2015-01-01

    The self-potential (SP) method is sensitive to water fluxes in saturated and partially saturated porous media, such as those associated with rainwater infiltration and groundwater recharge. We present a field-based study at the Voulund agricultural test site, Denmark, that is, to the best of our knowledge, the first to focus on the vertical self-potential distribution prior to and during a saline tracer test. A coupled hydrogeophysical modeling framework is used to simulate the SP response to precipitation and saline tracer infiltration. A layered hydrological model is first obtained by inverting dielectric and matric potential data. The resulting model that compares favorably with electrical resistance tomography models is subsequently used to predict the SP response. The electrokinetic contribution (caused by water fluxes in a charged porous soil) is modeled by an effective excess charge approach that considers both water saturation and pore water salinity. Our results suggest that the effective excess char...

  8. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

    1989-01-01

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  9. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. ???, XXXX, DOI:10.1029/, What is the skill of ocean tracers in reducing uncertainties

    E-Print Network [OSTI]

    Haran, Murali

    in current Earth system models and (ii) imperfect knowledge of model parameters. Ocean tracers observa- tions

  10. Method and apparatus for removing non-condensible gas from a working fluid in a binary power system

    DOE Patents [OSTI]

    Mohr, Charles M. (Idaho Falls, ID); Mines, Gregory L. (Idaho Falls, ID); Bloomfield, K. Kit (Idaho Falls, ID)

    2002-01-01

    Apparatus for removing non-condensible gas from a working fluid utilized in a thermodynamic system comprises a membrane having an upstream side operatively connected to the thermodynamic system so that the upstream side of the membrane receives a portion of the working fluid. The first membrane separates the non-condensible gas from the working fluid. A pump operatively associated with the membrane causes the portion of the working fluid to contact the membrane and to be returned to the thermodynamic system.

  11. 90Sr liquid scintillation urine analysis utilizing different approaches for tracer recovery.

    SciTech Connect (OSTI)

    Piraner, Olga [Centers for Disease Control and Prevention, Atlanta, GA; Preston, Rose T. [Sandia Staffing Alliance, LLC, Albuquerque, NM; Shanks, Sonoya Toyoko; Jones, Robert [Centers for Disease Control and Prevention, Atlanta, GA

    2010-08-01

    90Sr is one of the isotopes most commonly produced by nuclear fission. This medium lived isotope presents serious challenges to radiation workers, the environment, and following a nuclear event, the general public. Methods of identifying this nuclide have been in existence for a number of years (e.g. Horwitz, E.P. [1], Maxwell, S.L.[2], EPA 905.0 [3]) which are time consuming, requiring a month or more for full analysis. This time frame is unacceptable in the present security environment. It is therefore important to have a dependable and rapid method for the determination of Sr. The purposes of this study are to reduce analysis time to less than half a day by utilizing a single method of radiation measurement while continuing to yield precise results. This paper presents findings on three methods that can meet this criteria; (1) stable Sr carrier, (2) 85Sr by gamma spectroscopy, and (3) 85Sr by LSC. Two methods of analyzing and calculating the 85Sr tracer recovery were investigated (gamma spectroscopy and a low energy window-Sr85LEBAB by LSC) as well as the use of two different types of Sr tracer (85Sr and stable Sr carrier). Three separate stock blank urine samples were spiked with various activity levels of 239Pu, 137Cs, 90Sr /90Y to determine the effectiveness of the Eichrome Sr-spec%C2%AE resin 2mL extractive columns. The objective was to compare the recoveries of 85Sr versus a stable strontium carrier, attempt to compare the rate at which samples can be processed by evaluating evaporation, neutralization, and removing the use of another instrument (gamma spectrometer) by using the LSC spectrometer to obtain 85Sr recovery. It was found that when using a calibration curve comprised of a different cocktail and a non-optimum discriminator setting reasonable results (bias of %C2%B1 25%) were achieved. The results from spiked samples containing 85Sr demonstrated that a higher recovery is obtained when using gamma spectroscopy (89-95%) than when using the LEB window from LSC (120-470%). The high recovery for 85Sr by LSC analysis may be due to the interference/cross talk from the alpha region since alpha counts were observed in all sample sets. After further investigation it was determined that the alpha counts were due to 239Pu breakthrough on the Sr-spec%C2%AE column. This requires further development to purify the Sr before an accurate tracer recovery determination can be made. Sample preparation times varied and ranged from 4-6 hours depending on the specific sample preparation process. The results from the spiked samples containing stable strontium nitrate Sr(NO3)2 carrier demonstrate that gravimetric analysis yields the most consistent high recoveries (97-101%) when evaporation is carefully performed. Since this method did not have a variation on the tracer recovery method, the samples were counted in 1) LEB/Alpha/Beta mode optimized for Sr-90, 2) DPM for Sr-90, and 3) general LEB/Alpha/Beta mode. The results (from the known) ranged from 79-104%, 107-177%, and 85-89% for 1, 2, and 3 respectively. Counting the prepared samples in a generic low energy beta/alpha/beta protocol yielded more accurate and consistent results and also yielded the shortest sample preparation turn-around-time of 3.5 hours.

  12. Development of Models to Simulate Tracer Tests for Characterization of Enhanced Geothermal Systems

    SciTech Connect (OSTI)

    Williams, Mark D.; Reimus, Paul; Vermeul, Vincent R.; Rose, Peter; Dean, Cynthia A.; Watson, Tom B.; Newell, D.; Leecaster, Kevin; Brauser, Eric

    2013-05-01

    A recent report found that power and heat produced from enhanced (or engineered) geothermal systems (EGSs) could have a major impact on the U.S energy production capability while having a minimal impact on the environment. EGS resources differ from high-grade hydrothermal resources in that they lack sufficient temperature distribution, permeability/porosity, fluid saturation, or recharge of reservoir fluids. Therefore, quantitative characterization of temperature distributions and the surface area available for heat transfer in EGS is necessary for the design and commercial development of the geothermal energy of a potential EGS site. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate this characterization. This project was initially focused on tracer development with the application of perfluorinated tracer (PFT) compounds, non-reactive tracers used in numerous applications from atmospheric transport to underground leak detection, to geothermal systems, and evaluation of encapsulated PFTs that would release tracers at targeted reservoir temperatures. After the 2011 midyear review and subsequent discussions with the U.S. Department of Energy Geothermal Technology Program (GTP), emphasis was shifted to interpretive tool development, testing, and validation. Subsurface modeling capabilities are an important component of this project for both the design of suitable tracers and the interpretation of data from in situ tracer tests, be they single- or multi-well tests. The purpose of this report is to describe the results of the tracer and model development for simulating and conducting tracer tests for characterizing EGS parameters.

  13. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO?-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore »proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO?. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO? will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO? driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO? to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As part of the Big Sky Carbon Sequestration Project the INL-CAES has developed a rapid, easy to use proces

  14. Interpretation of Colloid-Homologue Tracer Test 10-03, Including Comparisons to Test 10-01

    SciTech Connect (OSTI)

    Reimus, Paul W.

    2012-06-26

    This presentation covers the interpretations of colloid-homologue tracer test 10-03 conducted at the Grimsel Test Site, Switzerland, in 2010. It also provides a comparison of the interpreted test results with those of tracer test 10-01, which was conducted in the same fracture flow system and using the same tracers than test 10-03, but at a higher extraction flow rate. A method of correcting for apparent uranine degradation in test 10-03 is presented. Conclusions are: (1) Uranine degradation occurred in test 10-03, but not in 10-01; (2) Uranine correction based on apparent degradation rate in injection loop in test 11-02 seems reasonable when applied to data from test 10-03; (3) Colloid breakthrough curves quite similar in the two tests with similar recoveries relative to uranine (after correction); and (4) Much slower apparent desorption of homologues in test 10-03 than in 10-01 (any effect of residual homologues from test 10-01 in test 10-03?).

  15. Optical sensing elements for nitrogen dioxide (NO.sub.2) gas detection, a sol-gel method for making the sensing elements and fiber optic sensors incorporating nitrogen dioxide gas optical sensing elements

    DOE Patents [OSTI]

    Mechery, Shelly John (Mississippi State, MS); Singh, Jagdish P. (Starkville, MS)

    2007-07-03

    A sensing element, a method of making a sensing element, and a fiber optic sensor incorporating the sensing element are described. The sensor can be used for the quantitative detection of NO.sub.2 in a mixture of gases. The sensing element can be made by incorporating a diazotizing reagent which reacts with nitrous ions to produce a diazo compound and a coupling reagent which couples with the diazo compound to produce an azo dye into a sol and allowing the sol to form an optically transparent gel. The sensing element changes color in the presence of NO.sub.2 gas. The temporal response of the absorption spectrum at various NO.sub.2 concentrations has also been recorded and analyzed. Sensors having different design configurations are described. The sensing element can detect NO.sub.2 gas at levels of parts per billion.

  16. Computational fluid dynamics analysis of cold plasma carrier gas injected into a fluid using level set method

    E-Print Network [OSTI]

    Yu, K.N.

    , and water. Our objective was to develop a model to perform complete fluid dynamics and heat transfer cells. Specifically, the authors developed a three-phase-interaction model which was coupled with heat dynamics and heat transfer output variables, such as temperature, in three phases, i.e., air, helium gas

  17. A new method for in situ soil gas diffusivity measurement and applications in the monitoring of subsurface CO2 production

    E-Print Network [OSTI]

    Beltrami, Hugo

    -specific diffusivity measurements greatly improved the accuracy of CO2 production estimates. We observed a consistent and close correspondence between calculated profile CO2 production and (independently measured) soil CO2 surface flux. The subsurface CO2 production estimates acquired using in situ gas diffusivity measurements

  18. Final Progress Report for Project Entitled: Quantum Dot Tracers for Use in Engineered Geothermal Systems

    SciTech Connect (OSTI)

    Rose, Peter; Bartl, Michael; Reimus, Paul; Williams, Mark; Mella, Mike

    2015-09-12

    The objective of this project was to develop and demonstrate a new class of tracers that offer great promise for use in characterizing fracture networks in EGS reservoirs. From laboratory synthesis and testing through numerical modeling and field demonstrations, we have demonstrated the amazing versatility and applicability of quantum dot tracers. This report summarizes the results of four years of research into the design, synthesis, and characterization of semiconductor nanocrystals (quantum dots) for use as geothermal tracers.

  19. Novel Multi-dimensional Tracers for Geothermal Inter-wall Diagnostics

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. The objective of this project is to develop a matrix of the smart geothermal tracer and its interpretation tools.

  20. Angel wing seals for blades of a gas turbine and methods for determining angel wing seal profiles

    DOE Patents [OSTI]

    Wang, John Zhiqiang (Greenville, SC)

    2003-01-01

    A gas turbine has buckets rotatable about an axis, the buckets having angel wing seals. The seals have outer and inner surfaces, at least one of which, and preferably both, extend non-linearly between root radii and the tip of the seal body. The profiles are determined in a manner to minimize the weight of the seal bodies, while maintaining the stresses below predetermined maximum or allowable stresses.

  1. Inversion of Hydrological Tracer Test Data Using TomogrpahicConstraints

    SciTech Connect (OSTI)

    Linde, Niklas; Finsterle, Stefan; Hubbard, Susan

    2004-11-11

    A reasonable description of the hydraulic conductivity structure is a prerequisite for modeling contaminant transport. However, formulations of hydrogeological inverse problems utilizing hydrogeological data only often fail to reliably resolve features at a resolution required for accurately predicting transport. Incorporation of geophysical data into the inverse problem offers the potential to increase this resolution. In this study, we invert hydrological tracer test data using the shape and relative magnitude variations derived from geophysical tomographic data to regionalize a hydrogeological inverse problem in order to estimate the hydraulic conductivity structure. Our approach does not require that the petrophysical relationship be known a-priori, but that it is linear and stationary within each geophysical anomaly. However, tomograms are imperfect models of geophysical properties and geophysical properties are not necessarily strongly linked to hydraulic conductivity. Therefore, we focus on synthetic examples where the correlation between radar velocity and hydraulic conductivity, as well as the geophysical data acquisition errors, are varied in order to assess what aspects of the hydraulic conductivity structure we can expect to resolve under different conditions. The results indicate that regularization of the tracer inversion procedure using geophysical data improves estimates of hydraulic conductivity. We find that even under conditions of corrupted geophysical data, we can accurately estimate the effective hydraulic conductivity and areas of high and low hydraulic conductivity. However, given imperfect geophysical data, our results suggest that we cannot expect accurate estimates of the variability of the hydraulic conductivity structure.

  2. Primer on gas integrated resource planning

    SciTech Connect (OSTI)

    Goldman, C.; Comnes, G.A.; Busch, J.; Wiel, S. [Lawrence Berkeley Lab., CA (United States)

    1993-12-01

    This report discusses the following topics: gas resource planning: need for IRP; gas integrated resource planning: methods and models; supply and capacity planning for gas utilities; methods for estimating gas avoided costs; economic analysis of gas utility DSM programs: benefit-cost tests; gas DSM technologies and programs; end-use fuel substitution; and financial aspects of gas demand-side management programs.

  3. Isotopic tracer studies of Fischer-Tropsch Synthesis over Ru/TiO sub 2 catalysts

    SciTech Connect (OSTI)

    Krishna, K.R.

    1992-01-01

    Fischer-Tropsch synthesis is a process in which CO and H{sub 2} react to give predominantly liquid hydrocarbons. The reaction can be considered a special type of polymerization in which the monomer is produced in situ, and chain growth occurs by a sequence of independently repeated additions of the monomer to the growing chain. A investigation has been conducted to study the CO hydrogenation reaction in order to better understand catalyst deactivation and the elementary surface processes involved in chain growth. Isotopic tracers are used in conjunction with transient-response techniques in this study of Fischer-Tropsch synthesis over Ru/TiO{sub 2} catalysts. Experiments are conducted at a total pressure of 1 atmosphere, reaction temperatures of 453--498 K and D{sub 2}/CO (or H{sub 2}/CO) ratios of 2--5. Synthesis products are analyzed by gas chromatography or isotope-ratio gas chromatography-mass spectrometry. Rate constants for chain initiation, propagation and termination are evaluated under steady-state reaction conditions by using transients in isotopic composition. The activation energy for chain termination is much higher than that for propagation, accounting for the observed decrease in the chain growth parameter are also estimated. Coverages by reaction intermediates are also estimated. When small amounts of {sup 12}C-labelled ethylene are added to {sup 13}CO/H{sub 2} synthesis gas, ethylene acts as the sole chain initiator. Ethylene-derived carbon also accounts for 45% of the C{sub 1} monomer pool. 102 refs., 29 figs., 11 tabs.

  4. Isotopic tracer studies of Fischer-Tropsch Synthesis over Ru/TiO{sub 2} catalysts

    SciTech Connect (OSTI)

    Krishna, K.R.

    1992-01-01

    Fischer-Tropsch synthesis is a process in which CO and H{sub 2} react to give predominantly liquid hydrocarbons. The reaction can be considered a special type of polymerization in which the monomer is produced in situ, and chain growth occurs by a sequence of independently repeated additions of the monomer to the growing chain. A investigation has been conducted to study the CO hydrogenation reaction in order to better understand catalyst deactivation and the elementary surface processes involved in chain growth. Isotopic tracers are used in conjunction with transient-response techniques in this study of Fischer-Tropsch synthesis over Ru/TiO{sub 2} catalysts. Experiments are conducted at a total pressure of 1 atmosphere, reaction temperatures of 453--498 K and D{sub 2}/CO (or H{sub 2}/CO) ratios of 2--5. Synthesis products are analyzed by gas chromatography or isotope-ratio gas chromatography-mass spectrometry. Rate constants for chain initiation, propagation and termination are evaluated under steady-state reaction conditions by using transients in isotopic composition. The activation energy for chain termination is much higher than that for propagation, accounting for the observed decrease in the chain growth parameter are also estimated. Coverages by reaction intermediates are also estimated. When small amounts of {sup 12}C-labelled ethylene are added to {sup 13}CO/H{sub 2} synthesis gas, ethylene acts as the sole chain initiator. Ethylene-derived carbon also accounts for 45% of the C{sub 1} monomer pool. 102 refs., 29 figs., 11 tabs.

  5. Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, T.

    1988-04-05

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

  6. Dispersion of passive tracers in closed basins: Beyond the diffusion coefficient

    E-Print Network [OSTI]

    Cencini, Massimo

    Dispersion of passive tracers in closed basins: Beyond the diffusion coefficient V. Artale ENEA, 00185 Roma, Italy Received 25 April 1997; accepted 10 July 1997 We investigate the spreading of passive of diffusion and transport of passive tracers in a given velocity field has both theoretical and prac- tical

  7. First Tracer Test After Circulation in Desert Peak 27-15

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Rose, Peter

    2013-11-16

    Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

  8. First Tracer Test After Circulation in Desert Peak 27-15

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Rose, Peter

    Following the successful stimulation of Desert Peak target EGS well 27-15, a circulation test was initiated by injecting a conservative tracer (1,5-nds) in combination with a reactive tracer (7-amino-1,3-naphthalene disulfonate). The closest production well 74-21 was monitored over the subsequent several months.

  9. SYNTHESIS OF DIVERSE TRACERS ON EWOD MICRODEVICE FOR POSITRON EMISSION TOMOGRAPHY (PET)

    E-Print Network [OSTI]

    , spatial, and temporal measurement of biochemical processes. Applications of PET include studying disease-labeled PET tracers with electrowetting-on-dielectric (EWOD) technology [3],[4], the digital microfluidicSYNTHESIS OF DIVERSE TRACERS ON EWOD MICRODEVICE FOR POSITRON EMISSION TOMOGRAPHY (PET) S. Chen1

  10. ADVANCES IN ATMOSPHERIC SCIENCES, VOL. 25, NO. 5, 2008, 805814 Diagnosing Ocean Tracer Transport from Sellafield

    E-Print Network [OSTI]

    Drange, Helge

    applications thereof, idealized releases of passive tracers from the nuclear fuel reprocessing plants are considered; the former being representative of the actual historical discharges from the reprocessing plants tracer concentration from idealized pulse releases from the British nuclear fuel reprocessing plants

  11. A Finite-Difference Numerical Method for Onsager's Pancake Approximation for Fluid Flow in a Gas Centrifuge

    SciTech Connect (OSTI)

    de Stadler, M; Chand, K

    2007-11-12

    Gas centrifuges exhibit very complex flows. Within the centrifuge there is a rarefied region, a transition region, and a region with an extreme density gradient. The flow moves at hypersonic speeds and shock waves are present. However, the flow is subsonic in the axisymmetric plane. The analysis may be simplified by treating the flow as a perturbation of wheel flow. Wheel flow implies that the fluid is moving as a solid body. With the very large pressure gradient, the majority of the fluid is located very close to the rotor wall and moves at an azimuthal velocity proportional to its distance from the rotor wall; there is no slipping in the azimuthal plane. The fluid can be modeled as incompressible and subsonic in the axisymmetric plane. By treating the centrifuge as long, end effects can be appropriately modeled without performing a detailed boundary layer analysis. Onsager's pancake approximation is used to construct a simulation to model fluid flow in a gas centrifuge. The governing 6th order partial differential equation is broken down into an equivalent coupled system of three equations and then solved numerically. In addition to a discussion on the baseline solution, known problems and future work possibilities are presented.

  12. L\\'evy Fluctuations and Tracer Diffusion in Dilute Suspensions of Algae and Bacteria

    E-Print Network [OSTI]

    Zaid, Irwin M; Yeomans, Julia M

    2010-01-01

    Swimming microorganisms rely on effective mixing strategies to achieve efficient nutrient influx. Recent experiments, probing the mixing capability of unicellular biflagellates, revealed that passive tracer particles exhibit anomalous non-Gaussian diffusion when immersed in a dilute suspension of self-motile Chlamydomonas reinhardtii algae. Qualitatively, this observation can be explained by the fact that the algae induce a fluid flow that may occasionally accelerate the colloidal tracers to relatively large velocities. A satisfactory quantitative theory of enhanced mixing in dilute active suspensions, however, is lacking at present. In particular, it is unclear how non-Gaussian signatures in the tracers' position distribution are linked to the self-propulsion mechanism of a microorganism. Here, we develop a systematic theoretical description of anomalous tracer diffusion in active suspensions, based on a simplified tracer-swimmer interaction model that captures the typical distance scaling of a microswimmer'...

  13. Heat, 10B-Enriched Boric Acid, and Bromide as Recycled Groundwater Tracers for Managed Aquifer Recharge: Case Study

    E-Print Network [OSTI]

    Clark, J F

    2015-01-01

    water tracer. ” Ground Water, Bassett, R. L. (1990). “ Atemperature sensing. ” Ground Water, 51(5), 670–678. Becker,acid as recycled ground- water tracers for managed aquifer

  14. Hydroxyl as a Tracer of H2 in the Envelope of MBM40

    E-Print Network [OSTI]

    Cotten, David L; Wennerstrom, Elizabeth A; Douglas, Kevin A; Onello, Joseph S

    2012-01-01

    We observed 51 positions in the OH 1667 MHz main line transitions in the translucent, high latitude cloud MBM40. We detected OH in 8 out of 8 positions in the molecular core of the cloud and 24 out of 43 in the surrounding, lower extinction envelope and periphery of the cloud. Using a linear relationship between the integrated OH line intensity and E(B-V), we estimate the mass in the core, the envelope, and the periphery of the cloud to be 9.1, 13.7, and 1.5 solar masses. As much as 60% of the total cloud mass may be found in the envelope (0.12 \\leq E(B-V) \\leq 0.17 mag) and some molecular mass (6%) in the periphery (E(B-V) < 0.12 mag). The OH 1667 MHz line is an excellent tracers of gas in very low extinction regions and high-sensitivity mapping of the envelopes of molecular clouds may reveal the presence of significant quantities of molecular mass.

  15. A low cost Earth Observation method for monitoring Green House Gas emissions from forests in developing countries. 

    E-Print Network [OSTI]

    Mlambo, Reason

    2015-11-26

    Structure from Motion (SfM) from Unmanned Aerial Vehicles (UAV) is increasingly being utilised for a wide range of applications including characterisation of forests. The aim of this study was to evaluate SfM from UAVs as a potential low cost method...

  16. An SF6 Tracer Study of the Flow Dynamics in the Stockton Deep Water Ship Channel: Implications

    E-Print Network [OSTI]

    Ho, David

    An SF6 Tracer Study of the Flow Dynamics in the Stockton Deep Water Ship Channel: Implications6) tracer release experi- ment was conducted in the Stockton Deep Water Ship Channel (DWSC. Keywords Dissolved oxygen . Sacramento­San Joaquin delta . Stockton deep water ship channel . SF6 . Tracer

  17. FeCycle: Attempting an iron biogeochemical budget from a mesoscale SF6 tracer experiment in unperturbed low iron waters

    E-Print Network [OSTI]

    Wilhelm, Steven W.

    FeCycle: Attempting an iron biogeochemical budget from a mesoscale SF6 tracer experiment to ocean physics. In summer 2003 we conducted FeCycle, a 10-day mesoscale tracer release in HNLC waters SE biogeochemical budget from a mesoscale SF6 tracer experiment in unperturbed low iron waters, Global Biogeochem

  18. Passive tracers in a general circulation model of the Southern Ocean I. G. Stevens, D. P. Stevens

    E-Print Network [OSTI]

    Stevens, David

    Passive tracers in a general circulation model of the Southern Ocean I. G. Stevens, D. P. Stevens: 22 January 1999 / Accepted: 12 February 1999 Abstract. Passive tracers are used in an o-line version and provide information on the inter-ocean exchange of water masses. The use of passive tracers allows

  19. Study of Particle Rotation Effect in Gas-Solid Flows using Direct Numerical Simulation with a Lattice Boltzmann Method

    SciTech Connect (OSTI)

    Kwon, Kyung; Fan, Liang-Shih; Zhou, Qiang; Yang, Hui

    2014-09-30

    A new and efficient direct numerical method with second-order convergence accuracy was developed for fully resolved simulations of incompressible viscous flows laden with rigid particles. The method combines the state-of-the-art immersed boundary method (IBM), the multi-direct forcing method, and the lattice Boltzmann method (LBM). First, the multi-direct forcing method is adopted in the improved IBM to better approximate the no-slip/no-penetration (ns/np) condition on the surface of particles. Second, a slight retraction of the Lagrangian grid from the surface towards the interior of particles with a fraction of the Eulerian grid spacing helps increase the convergence accuracy of the method. An over-relaxation technique in the procedure of multi-direct forcing method and the classical fourth order Runge-Kutta scheme in the coupled fluid-particle interaction were applied. The use of the classical fourth order Runge-Kutta scheme helps the overall IB-LBM achieve the second order accuracy and provides more accurate predictions of the translational and rotational motion of particles. The preexistent code with the first-order convergence rate is updated so that the updated new code can resolve the translational and rotational motion of particles with the second-order convergence rate. The updated code has been validated with several benchmark applications. The efficiency of IBM and thus the efficiency of IB-LBM were improved by reducing the number of the Lagragian markers on particles by using a new formula for the number of Lagrangian markers on particle surfaces. The immersed boundary-lattice Boltzmann method (IBLBM) has been shown to predict correctly the angular velocity of a particle. Prior to examining drag force exerted on a cluster of particles, the updated IB-LBM code along with the new formula for the number of Lagrangian markers has been further validated by solving several theoretical problems. Moreover, the unsteadiness of the drag force is examined when a fluid is accelerated from rest by a constant average pressure gradient toward a steady Stokes flow. The simulation results agree well with the theories for the short- and long-time behavior of the drag force. Flows through non-rotational and rotational spheres in simple cubic arrays and random arrays are simulated over the entire range of packing fractions, and both low and moderate particle Reynolds numbers to compare the simulated results with the literature results and develop a new drag force formula, a new lift force formula, and a new torque formula. Random arrays of solid particles in fluids are generated with Monte Carlo procedure and Zinchenko's method to avoid crystallization of solid particles over high solid volume fractions. A new drag force formula was developed with extensive simulated results to be closely applicable to real processes over the entire range of packing fractions and both low and moderate particle Reynolds numbers. The simulation results indicate that the drag force is barely affected by rotational Reynolds numbers. Drag force is basically unchanged as the angle of the rotating axis varies.

  20. The spiral arms of the Milky Way: The relative location of each different arm tracer within a typical spiral arm width

    SciTech Connect (OSTI)

    Vallée, Jacques P., E-mail: jacques.vallee@nrc-cnrc.gc.ca [National Research Council Canada, National Science Infrastructure portfolio, Herzberg Astronomy and Astrophysics, 5071 West Saanich Road, Victoria, B.C., V9E 2E7 (Canada)

    2014-07-01

    From the Sun's location in the Galactic disk, different arm tracers (CO, H I, hot dust, etc.) have been employed to locate a tangent to each spiral arm. Using all various and different observed spiral arm tracers (as published elsewhere), we embark on a new goal, namely the statistical analysis of these published data (data mining) to statistically compute the mean location of each spiral arm tracer. We show for a typical arm cross-cut, a separation of 400 pc between the mid-arm and the dust lane (at the inner edge of the arm, toward the Galactic center). Are some arms major and others minor? Separating arms into two sets, as suggested by some, we find the same arm widths between the two sets. Our interpretation is that we live in a multiple (four-arm) spiral (logarithmic) pattern (around a pitch angle of 12°) for the stars and gas in the Milky Way, with a sizable interarm separation (around 3 kpc) at the Sun's location and the same arm width for each arm (near 400 pc from mid-arm to dust lane).

  1. Exit chimney joint and method of forming the joint for closed circuit steam cooled gas turbine nozzles

    DOE Patents [OSTI]

    Burdgick, Steven Sebastian (Schenectady, NY); Burns, James Lee (Schenectady, NY)

    2002-01-01

    A nozzle segment for a gas turbine includes inner and outer band portions and a vane extending between the band portions. The inner and outer band portions are each divided into first and second plenums separated by an impingement plate. Cooling steam is supplied to the first cavity for flow through the apertures to cool the outer nozzle wall. The steam flows through a leading edge cavity in the vane into the first cavity of the inner band portion for flow through apertures of the impingement plate to cool the inner nozzle wall. Spent cooling steam flows through a plurality of cavities in the vane, exiting through an exit chimney in the outer band. The exit chimney is secured at its inner end directly to the nozzle vane wall surrounding the exit cavities, to the margin of the impingement plate at a location intermediate the ends of the exit chimney and to margins of an opening through the cover whereby each joint is externally accessible for joint formation and for subsequent inspection.

  2. Process studies for a new method of removing H/sub 2/S from industrial gas streams

    SciTech Connect (OSTI)

    Neumann, D.W.; Lynn, S.

    1986-07-01

    A process for the removal of hydrogen sulfide from coal-derived gas streams has been developed. The basis for the process is the absorption of H/sub 2/S into a polar organic solvent where it is reacted with dissolved sulfur dioxide to form elemental sulfur. After sulfur is crystallized from solution, the solvent is stripped to remove dissolved gases and water formed by the reaction. The SO/sub 2/ is generated by burning a portion of the sulfur in a furnace where the heat of combustion is used to generate high pressure steam. The SO/sub 2/ is absorbed into part of the lean solvent to form the solution necessary for the first step. The kinetics of the reaction between H/sub 2/S and SO/sub 2/ dissolved in mixtures of N,N-Dimethylaniline (DMA)/ Diethylene Glycol Monomethyl Ether and DMA/Triethylene Glycol Dimethyl Ether was studied by following the temperature rise in an adiabatic calorimeter. This irreversible reaction was found to be first-order in both H/sub 2/S and SO/sub 2/, with an approximates heat of reaction of 28 kcal/mole of SO/sub 2/. The sole products of the reaction appear to be elemental sulfur and water. The presence of DMA increases the value of the second-order rate constant by an order of magnitude over that obtained in the glycol ethers alone. Addition of other tertiary aromatic amines enhances the observed kinetics; heterocyclic amines (e.g., pyridine derivatives) have been found to be 10 to 100 times more effective as catalysts when compared to DMA.

  3. Rapid and sensitive gas chromatography ion-trap mass spectrometry method for the determination of tobacco specific N-nitrosamines in secondhand smoke

    SciTech Connect (OSTI)

    SLEIMAN, Mohamad; MADDALENA, Randy L.; GUNDEL, Lara A.; DESTAILLATS, Hugo

    2009-07-01

    Tobacco-specific nitrosamines (TSNAs) are some of the most potent carcinogens in tobacco and cigarette smoke. Accurate quantification of these chemicals is needed to help assess public health risks. We developed and validated a specific and sensitive method to measure four TSNAs in both the gas- and particle-phase of secondhand smoke (SHS) using gas chromatography and ion-trap tandem mass spectrometry,. A smoking machine in an 18-m3 room-sized chamber generated relevant concentrations of SHS that were actively sampled on Teflon coated fiber glass (TCFG) filters, and passively sampled on cellulose substrates. A simple solid-liquid extraction protocol using methanol as solvent was successfully applied to both filters with high recoveries ranging from 85 to 115percent. Tandem MS parameters were optimized to obtain the best sensitivity in terms of signal to-noise ratio (S/N) for the target compounds. For each TSNA, the major fragmentation pathways as well as ion structures were elucidated and compared with previously published data. The method showed excellent performances with a linear dynamic range between 2 and 1000 ng mL-1, low detection limits (S/N> 3) of 30-300 pg.ml-1 and precision with experimental errors below 10percent for all compounds. Moreover, no interfering peaks were observed indicating a high selectivity of MS/MS without the need for a sample clean up step. The sampling and analysis method provides a sensitive and accurate tool to detect and quantify traces of TSNA in SHS polluted indoor environments.

  4. Estimation of fracture porosity in an unsaturated fractured welded tuff using gas tracer testing

    E-Print Network [OSTI]

    Freifeld, Barry

    2001-01-01

    of continuum modeling for analysis of air-injection pressurefor steady-state analysis of air-permeability tests, such asof a flow model analysis of air-injection data is subject to

  5. Estimation of fracture porosity in an unsaturated fractured welded tuff using gas tracer testing

    E-Print Network [OSTI]

    Freifeld, Barry

    2001-01-01

    for the Disposal of Radioactive Waste, Technical Report 91-for the Disposal of Radioactive Waste, Technical Report 91-

  6. Solubility trapping in formation water as dominant CO2 sink in natural gas fields

    E-Print Network [OSTI]

    Haszeldine, Stuart

    LETTERS Solubility trapping in formation water as dominant CO2 sink in natural gas fields Stuart M, dissolu- tion in formation water at a pH of 5­5.8 is the sole major sink for CO2. In two fields dissolved in water. Noble gas and CO2 carbon isotopes are powerful tracers of crustal fluid processes

  7. Predictions of tracer transport in interwell tracer tests at the C-Hole complex. Yucca Mountain site characterization project report milestone 4077

    SciTech Connect (OSTI)

    Reimus, P.W.

    1996-09-01

    This report presents predictions of tracer transport in interwell tracer tests that are to be conducted at the C-Hole complex at the Nevada Test Site on behalf of the Yucca Mountain Site Characterization Project. The predictions are used to make specific recommendations about the manner in which the tracer test should be conducted to best satisfy the needs of the Project. The objective of he tracer tests is to study flow and species transport under saturated conditions in the fractured tuffs near Yucca Mountain, Nevada, the site of a potential high-level nuclear waste repository. The potential repository will be located in the unsaturated zone within Yucca Mountain. The saturated zone beneath and around the mountain represents the final barrier to transport to the accessible environment that radionuclides will encounter if they breach the engineered barriers within the repository and the barriers to flow and transport provided by the unsaturated zone. Background information on the C-Holes is provided in Section 1.1, and the planned tracer testing program is discussed in Section 1.2.

  8. Tracers for monitoring the activity of sodium/glucose cotransporters in health and disease

    DOE Patents [OSTI]

    Wright, Ernest M; Barrio, Jorge R; Hirayama, Bruce A; Kepe, Vladimir

    2014-09-30

    Radiolabeled tracers for sodium/glucose cotransporters (SGLTs), their synthesis, and their use are provided. The tracers are methyl or ethyl pyranosides having an equatorial hydroxyl group at carbon-2 and a C 1 preferred conformation, radiolabeled with .sup.18F, .sup.123I, or .sup.124I, or free hexoses radiolabeled with .sup.18F, .sup.123I, or .sup.124. Also provided are in vivo and in vitro techniques for using these and other tracers as analytical and diagnostic tools to study glucose transport, in health and disease, and to evaluate therapeutic interventions.

  9. Alternative High-z Cosmic Tracers and the Dark Energy Equation of State

    E-Print Network [OSTI]

    Plionis, M; Basilakos, S; Bresolin, F; Terlevich, E; Melnick, J; Georgantopoulos, I

    2009-01-01

    We propose to use alternative cosmic tracers to measure the dark energy equation of state and the matter content of the Universe [w(z) & \\Omega_m]. Our proposed method consists of two components: (a) tracing the Hubble relation using HII-like starburst galaxies, as an alternative to SNIa, which can be detected up to very large redshifts, z~4, and (b) measuring the clustering pattern of X-ray selected AGN at a median redshift of ~1. Each component of the method can in itself provide interesting constraints on the cosmological parameters, especially under our anticipation that we will reduce the corresponding random and systematic errors significantly. However, by joining their likelihood functions we will be able to put stringent cosmological constraints and break the known degeneracies between the dark energy equation of state (whether it is constant or variable) and the matter content of the universe and provide a powerful and alternative rute to measure the contribution to the global dynamics, and the e...

  10. Constraining the Dark Energy Equation of State using Alternative High-z Cosmic Tracers

    E-Print Network [OSTI]

    Plionis, M; Basilakos, S; Bressolin, F; Terlevich, E; Melnick, J; Chavez, R

    2009-01-01

    We propose to use alternative cosmic tracers to measure the dark energy equation of state and the matter content of the Universe [w(z) & Omega_m]. Our proposed method consists of two components: (a) tracing the Hubble relation using HII galaxies which can be detected up to very large redshifts, z~4, as an alternative to supernovae type Ia, and (b) measuring the clustering pattern of X-ray selected AGN at a median redshift of z~1. Each component of the method can in itself provide interesting constraints on the cosmological parameters, especially under our anticipation that we will reduce the corresponding random and systematic errors significantly. However, by joining their likelihood functions we will be able to put stringent cosmological constraints and break the known degeneracies between the dark energy equation of state (whether it is constant or variable) and the matter content of the universe and provide a powerful and alternative route to measure the contribution to the global dynamics and the equ...

  11. Home Safety: Radon Gas 

    E-Print Network [OSTI]

    Shaw, Bryan W.; Denny, Monica L.

    1999-11-12

    Every home should be tested for radon, an invisible, odorless, radioactive gas that occurs naturally. This publication explains the health risks, testing methods, and mitigation and reduction techniques....

  12. Method for identifying subsurface fluid migration and drainage pathways in and among oil and gas reservoirs using 3-D and 4-D seismic imaging

    DOE Patents [OSTI]

    Anderson, Roger N. (New York, NY); Boulanger, Albert (New York, NY); Bagdonas, Edward P. (Brookline, MA); Xu, Liqing (New Milford, NJ); He, Wei (New Milford, NJ)

    1996-01-01

    The invention utilizes 3-D and 4-D seismic surveys as a means of deriving information useful in petroleum exploration and reservoir management. The methods use both single seismic surveys (3-D) and multiple seismic surveys separated in time (4-D) of a region of interest to determine large scale migration pathways within sedimentary basins, and fine scale drainage structure and oil-water-gas regions within individual petroleum producing reservoirs. Such structure is identified using pattern recognition tools which define the regions of interest. The 4-D seismic data sets may be used for data completion for large scale structure where time intervals between surveys do not allow for dynamic evolution. The 4-D seismic data sets also may be used to find variations over time of small scale structure within individual reservoirs which may be used to identify petroleum drainage pathways, oil-water-gas regions and, hence, attractive drilling targets. After spatial orientation, and amplitude and frequency matching of the multiple seismic data sets, High Amplitude Event (HAE) regions consistent with the presence of petroleum are identified using seismic attribute analysis. High Amplitude Regions are grown and interconnected to establish plumbing networks on the large scale and reservoir structure on the small scale. Small scale variations over time between seismic surveys within individual reservoirs are identified and used to identify drainage patterns and bypassed petroleum to be recovered. The location of such drainage patterns and bypassed petroleum may be used to site wells.

  13. Method for identifying subsurface fluid migration and drainage pathways in and among oil and gas reservoirs using 3-D and 4-D seismic imaging

    DOE Patents [OSTI]

    Anderson, R.N.; Boulanger, A.; Bagdonas, E.P.; Xu, L.; He, W.

    1996-12-17

    The invention utilizes 3-D and 4-D seismic surveys as a means of deriving information useful in petroleum exploration and reservoir management. The methods use both single seismic surveys (3-D) and multiple seismic surveys separated in time (4-D) of a region of interest to determine large scale migration pathways within sedimentary basins, and fine scale drainage structure and oil-water-gas regions within individual petroleum producing reservoirs. Such structure is identified using pattern recognition tools which define the regions of interest. The 4-D seismic data sets may be used for data completion for large scale structure where time intervals between surveys do not allow for dynamic evolution. The 4-D seismic data sets also may be used to find variations over time of small scale structure within individual reservoirs which may be used to identify petroleum drainage pathways, oil-water-gas regions and, hence, attractive drilling targets. After spatial orientation, and amplitude and frequency matching of the multiple seismic data sets, High Amplitude Event (HAE) regions consistent with the presence of petroleum are identified using seismic attribute analysis. High Amplitude Regions are grown and interconnected to establish plumbing networks on the large scale and reservoir structure on the small scale. Small scale variations over time between seismic surveys within individual reservoirs are identified and used to identify drainage patterns and bypassed petroleum to be recovered. The location of such drainage patterns and bypassed petroleum may be used to site wells. 22 figs.

  14. Tracer diffusion in compacted, water-saturated bentonite

    SciTech Connect (OSTI)

    Bourg, Ian C.; Sposito, Garrison; Bourg, Alain C.M.

    2005-08-04

    Compacted Na-bentonite clay barriers, widely used in theisolation of solid-waste landfills and other contaminated sites, havebeen proposed for a similar use in the disposal of high-level radioactivewaste. Molecular diffusion through the pore space in these barriers playsa key role in their performance, thus motivating recent measurements ofthe apparent diffusion coefficient tensor of water tracers in compacted,water-saturated Na-bentonites. In the present study, we introduce aconceptual model in which the pore space of water-saturated bentonite isdivided into 'macropore' and 'interlayer nanopore' compartments. Withthis model we determine quantitatively the relative contributions ofpore-network geometry (expressed as a geometric factor) and of thediffusive behavior of water molecules near montmorillonite basal surfaces(expressed as a contristivity factor) to the apparent diffusioncoefficient tensor. Our model predicts, in agreement with experiment,that the mean principal value of the apparent diffusion coefficienttensor follows a single relationship when plotted against the partialmontmorillonite dry density (mass of montmorillonite per combined volumeof montmorillonite and pore space). Using a single fitted parameter, themean principal geometric factor, our model successfully describes thisrelationship for a broad range of bentonite-water system, from dilute gelto highly-compacted bentonite with 80 percent of its pore water ininterlayer nanopores.

  15. Gas hydrates

    SciTech Connect (OSTI)

    Not Available

    1985-04-01

    There is a definite need for the US government to provide leadership for research in gas hydrates and to coordinate its activities with academia, industry, private groups, federal agencies, and their foreign counterparts. In response to this need, the DOE Morgantown Energy Technology Center implemented a gas hydrates R and D program. Understanding the resource will be achieved through: assessment of current technology; characterization of gas hydrate geology and reservoir engineering; and development of diagnostic tools and methods. Research to date has focused on geology. As work progressed, areas where gas hydrates are likely to occur were identified, and specific high potential areas were targeted for future detailed investigation. Initial research activities involved the development of the Geologic Analysis System (GAS); which will provide, through approximately 30 software packages, the capability to manipulate and correlate several types of geologic and petroleum data into maps, graphics, and reports. Preliminary mapping of hydrate prospects for the Alaskan North Slope is underway. Geological research includes physical system characterization which focuses on creating synthetic methane hydrates and developing synthetic hydrate cores using tetrahydrofuran, consolidated rock cores, frost base mixtures, water/ice base mixtures, and water base mixtures. Laboratory work produced measurements of the sonic velocity and electrical resistivity of these synthetic hydrates. During 1983, a sample from a natural hydrate core recovered from the Pacific coast of Guatemala was tested for these properties by METC. More recently, a natural hydrate sample from the Gulf of Mexico was also acquired and testing of this sample is currently underway. In addition to the development of GAS, modeling and systems analysis work focused on the development of conceptual gas hydrate production models. 16 figs., 6 tabs.

  16. Radium isotopes as tracers of coastal circulation pathways in the Mid-Atlantic Blight

    E-Print Network [OSTI]

    Rasmussen, Linda L

    2003-01-01

    Pathways of exchange between the shelf and slope in the Mid-Atlantic Bight were investigated using a combination of radiochemical tracer and hydrographic measurements. The motivation was to provide evidence of transport ...

  17. An automated tracer dispersal system for snow accumulation and saltation transport investigations

    E-Print Network [OSTI]

    Ratzlaff, Kenneth L.; Braaten, David A.

    1998-02-01

    . This instrument consists of an ultralow power timing system, a pneumatic system, and microsphere generators to periodically disperse a tracer of colored glass microspheres onto the snow surface. Snow sampling must be conducted before melting occurs, and subsequent...

  18. Development of Models to Simulate Tracer Behavior in Enhanced Geothermal Systems

    SciTech Connect (OSTI)

    Williams, Mark D.; Vermeul, Vincent R.; Reimus, P. W.; Newell, D.; Watson, Tom B.

    2010-06-01

    A recent report found that power and heat produced from engineered (or enhanced) geothermal systems (EGSs) could have a major impact on the United States while incurring minimal environmental impacts. EGS resources differ from high-grade hydrothermal resources in that they lack sufficient temperature distributions, permeability/porosity, fluid saturation, or recharge of reservoir fluids. Therefore, quantitative characterization of temperature distributions and the surface area available for heat transfer in EGS is necessary for commercial development of geothermal energy. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate this characterization. Modeling capabilities are being developed as part of this project to support laboratory and field testing to characterize engineered geothermal systems in single- and multi-well tests using tracers. The objective of this report is to describe the simulation plan and the status of model development for simulating tracer tests for characterizing EGS.

  19. Inversion of field-scale partitioning tracer response for characterizing oil saturation distribution: a streamline approach 

    E-Print Network [OSTI]

    Iliassov, Pavel Alexandrovich

    2000-01-01

    Identifying distribution of remaining oil in the reservoir is vital for evaluation of existing waterflood, design of tertiary recovery projects, and location of infill drilling candidates. In recent years, partitioning interwell tracer tests (PITT...

  20. Author's personal copy Thorium-234 as a tracer of spatial, temporal and vertical variability

    E-Print Network [OSTI]

    Buesseler, Ken

    Author's personal copy Thorium-234 as a tracer of spatial, temporal and vertical variability 2009 Accepted 6 April 2009 Available online 16 April 2009 Keywords: Thorium-234 Particle flux Sediment

  1. Dynamic Reservoir Characterization Of Naturally Fractured Reservoirs From An Inter-Well Tracer Test 

    E-Print Network [OSTI]

    Kilicaslan, Ufuk

    2013-12-03

    After field redevelopment in the Sherrod Unit of the Spraberry Trend Area, an inter-well tracer test was conducted at the field scale in order to understand the fracture system, which forms preferential flow paths for ...

  2. High-resolution quantification of groundwater flux using a heat tracer: laboratory sandbox tests

    E-Print Network [OSTI]

    Konetchy, Brant Evan

    2014-12-31

    and groundwater flux. In this work, we constructed a sandbox to simulate a sand aquifer and performed a series of heat tracer tests under different flow rates. By analyzing the temperature responses among different tests, we developed a quantitative temperature...

  3. USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS...

    Open Energy Info (EERE)

    USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE COSO EGS PROJECT Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference...

  4. The entrainment and homogenization of tracers within the cyclonic gulf stream recirculation gyre

    E-Print Network [OSTI]

    Pickart, Robert S

    1987-01-01

    The various distributions of tracer associated with the Northern Recirculation Gyre of the Gulf Stream (NRG) are studied to try to obtain information about the flow. An advective-diffusive numerical model is implemented ...

  5. Method of and apparatus for preheating pressurized fluidized bed combustor and clean-up subsystem of a gas turbine power plant

    DOE Patents [OSTI]

    Cole, Rossa W. (E. Rutherford, NJ); Zoll, August H. (Cedar Grove, NJ)

    1982-01-01

    In a gas turbine power plant having a pressurized fluidized bed combustor, gas turbine-air compressor subsystem and a gas clean-up subsystem interconnected for fluid flow therethrough, a pipe communicating the outlet of the compressor of the gas turbine-air compressor subsystem with the interior of the pressurized fluidized bed combustor and the gas clean-up subsystem to provide for flow of compressed air, heated by the heat of compression, therethrough. The pressurized fluidized bed combustor and gas clean-up subsystem are vented to atmosphere so that the heated compressed air flows therethrough and loses heat to the interior of those components before passing to the atmosphere.

  6. Lévy Fluctuations and Tracer Diffusion in Dilute Suspensions of Algae and Bacteria

    E-Print Network [OSTI]

    Irwin M. Zaid; Jörn Dunkel; Julia M. Yeomans

    2010-09-20

    Swimming microorganisms rely on effective mixing strategies to achieve efficient nutrient influx. Recent experiments, probing the mixing capability of unicellular biflagellates, revealed that passive tracer particles exhibit anomalous non-Gaussian diffusion when immersed in a dilute suspension of self-motile Chlamydomonas reinhardtii algae. Qualitatively, this observation can be explained by the fact that the algae induce a fluid flow that may occasionally accelerate the colloidal tracers to relatively large velocities. A satisfactory quantitative theory of enhanced mixing in dilute active suspensions, however, is lacking at present. In particular, it is unclear how non-Gaussian signatures in the tracers' position distribution are linked to the self-propulsion mechanism of a microorganism. Here, we develop a systematic theoretical description of anomalous tracer diffusion in active suspensions, based on a simplified tracer-swimmer interaction model that captures the typical distance scaling of a microswimmer's flow field. We show that the experimentally observed non-Gaussian tails are generic and arise due to a combination of truncated L\\'evy statistics for the velocity field and algebraically decaying time correlations in the fluid. Our analytical considerations are illustrated through extensive simulations, implemented on graphics processing units to achieve the large sample sizes required for analyzing the tails of the tracer distributions.

  7. Urban Dispersion Program MSG05 Field Study: Summary of Tracer and Meteorological Measurements

    SciTech Connect (OSTI)

    Allwine, K Jerry; Flaherty, Julia E.

    2006-08-09

    The Urban Dispersion Program is a multi-year project, funded by the U.S. Department of Homeland Security, to better understand the flow and dispersion of airborne contaminants through and around the deep street canyons of New York City. The first tracer and meteorological field study was a limited study conducted during March 2005 near the Madison Square Garden in midtown Manhattan. Six safe, inert, gaseous perfluorocarbon tracers were released simultaneously at five street-level locations during two experimental days. In addition to collecting tracer data, meteorological data were also collected. Brookhaven National Laboratory conducted the bulk of the tracer and meteorological field efforts with Pacific Northwest National Laboratory and Stevens Institute of Technology assisting by measuring the vertical profile of winds. The Environmental Protection Agency worked with Brookhaven National Laboratory in accomplishing the personal exposure component of the study. This report presents some results from this analysis. In general, different release locations showed vastly different plume footprints for tracer materials, and the situation was made very complex with upwind and/or crosswind transport of tracer near street-level for the different release locations. Overall wind speeds and directions upwind and over the city were generally constant throughout each of the two experimental periods.

  8. Final report on isotope tracer investigations in the Forebay of the Orange County groundwater basin.

    SciTech Connect (OSTI)

    Davisson, M; Woodside, G

    2003-12-13

    California is currently faced with some critical decisions about water resource infrastructure development in highly urbanized regions, whose outcome will dictate the future long-term viability of plentiful water. Among these is developing and safely implementing the reuse of advanced treated waste water. One of the most reliable strategies for this water resource is its indirect reuse via groundwater recharge and storage, with particular emphasis on supplementing annual water demand or during drought relief. The Orange County Water District (District) is currently implementing the first phase of a large-scale water reuse project that will advance-treat up to 60 million gallons per day of waste water and recharge it into existing percolation basins in the Forebay region of the Orange County groundwater basin. In order for the District to protect public health, the fate and potability of this recharged waste water needs to be understood. In particular, the direction and rates of flow into underlying aquifers need to be characterized so that changes in water quality can be quantified between the recharge basins and points of production. Furthermore, to ensure compliance to California Department of Health Services (DHS) draft regulations, the direction and rate of recharged waste water from these basins need to be understood to sufficient detail that small mixtures can be delineated in monitoring and production wells. Under proposed DHS guidelines, consumptive use of recycled water is permissive only if its residence time in an aquifer exceeds a specified six-month time-frame. DHS guidelines also limit the percentage of recycled water at production wells. However, attaining such detail using current hydrogeological and computer-assisted modeling tools is either cost-prohibitive or results in uncertainties too large to achieve regulatory confidence. To overcome this technical barrier, the District funded Lawrence Livermore National Laboratory (LLNL) from 1995-2001 to directly measure groundwater ages and perform two artificial tracer studies using isotope methods to quantify flowpath directions, groundwater residence times, and the rate and extent of recharge water and groundwater mixing. In addition, Jordan Clark at University of California, Santa Barbara also performed an artificial tracer experiment using sulfur-hexafluoride, whose results have been integrated into the LLNL findings.

  9. Acidic gas capture by diamines

    DOE Patents [OSTI]

    Rochelle, Gary (Austin, TX); Hilliard, Marcus (Missouri City, TX)

    2011-05-10

    Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

  10. RESEARCH ROADMAP FOR GREENHOUSE GAS INVENTORY

    E-Print Network [OSTI]

    RESEARCH ROADMAP FOR GREENHOUSE GAS INVENTORY METHODS Prepared For: California Energy Commission.........................................................................................................................1 Roadmap Organization

  11. 3D Modeling of One and Two Component Gas Flow in Fibrous Microstructures in Fuel Cells by Using the Lattice-Boltzmann Method

    E-Print Network [OSTI]

    Schmidt, Volker

    In fuel cells, a homogeneous distribution of gas flow is desirable for optimal performance. The gas3D Modeling of One and Two Component Gas Flow in Fibrous Microstructures in Fuel Cells by Using: Fuel Cells, 52425 Jülich, Germany b Institute of Stochastics, Ulm University, 89069 Ulm, Germany

  12. Identification and characterization of conservative organic tracers for use as hydrologic tracers for the Yucca Mountain site characterization study. Progress report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Stetzenbach, K.; Farnham, I.

    1994-12-31

    The bromide anion has been used extensively as a tracer for mapping the flow of groundwater. It has proven to be both a safe and reliable groundwater tracer. The goal in this study is to find several tracing compounds with characteristics similar to the bromide anion to be used in multiple well tracing tests. Four groups of fluorinated organic acids were selected as candidates for groundwater tracers. These groups include fluorinated benzoic acids (FBA), fluorinated salicylic acids (FSA), fluorinated toluic acids (FTA), and fluorinated cinnamic acids (FCA). These compounds have been shown to move readily with the flow of water and do not adsorb to soil. They are also non-toxic. In this study, the retention of the fluorinated organic acids on to a soil column is compared to that of the bromide ion. The time required for the elution of each analyte from the soil column is measured using a UV-Vis detector. The soils consist of the light, medium, and dark tuffs used in the batch study. The work performed during this quarter consists of the continuation of the batch studies for the fluorinated benzoic acids and column studies for several potential tracer compounds.

  13. Method and apparatus for container leakage testing

    DOE Patents [OSTI]

    Kronberg, James W. (Aiken, SC)

    1995-01-01

    An apparatus for use in one-hundred percent leak testing of food containers used in conjunction with a tracer gas. The apparatus includes a shell with entrance and exit air locks to create a controlled atmosphere through which a series of containers is conveyed by a conveyor belt. The pressure in the shell is kept lower than the pressure in the containers and the atmosphere is made to flow with the containers so that a tracer gas placed in the packages before sealing them will leak more readily, but the leaked tracer gas will remain associated with the leaking package as it moves through the shell. The leaks are detected with a sniffer probe in fluid communication with a gas chromatograph. The gas chromatograph issues a signal when it detects a leak to an ejector that will eject the leaking container from the conveyor. The system is timed so that the series of containers can move continuously into and out of the shell, past the probe and the ejector, without stopping, yet each package is tested for leaks and removed if leaking.

  14. The Dark Energy Equation of State using Alternative High-z Cosmic Tracers

    E-Print Network [OSTI]

    M. Plionis; R. Terlevich; S. Basilakos; F. Bresolin; E. Terlevich; J. Melnick; R. Chavez

    2010-01-18

    We propose to use alternative cosmic tracers to measure the dark energy equation of state and the matter content of the Universe [w(z) & Omega_m]. Our proposed method consists of two components: (a) tracing the Hubble relation using HII galaxies which can be detected up to very large redshifts, z~4, as an alternative to supernovae type Ia, and (b) measuring the clustering pattern of X-ray selected AGN at a median redshift of z~1. Each component of the method can in itself provide interesting constraints on the cosmological parameters, especially under our anticipation that we will reduce the corresponding random and systematic errors significantly. However, by joining their likelihood functions we will be able to put stringent cosmological constraints and break the known degeneracies between the dark energy equation of state (whether it is constant or variable) and the matter content of the universe and provide a powerful and alternative route to measure the contribution to the global dynamics and the equation of state of dark energy. A preliminary joint analysis of X-ray selected AGN (based on the largest to-date XMM survey; the 2XMM) and the currently largest SNIa sample (Hicken et al.), using as priors a flat universe and the WMAP5 normalization of the power-spectrum, provides: Omega_m=0.27+-0.02 and w=-0.96+-0.07. Equivalent and consistent results are provided by the joint analysis of X-ray selected AGN clustering and the latest Baryonic Acoustic Oscillation measures, providing: Omega_m=0.27+-0.02 and w=-0.97+-0.04.

  15. Thermal single-well injection-withdrawal tracer tests for determining fracture-matrix heat transfer area

    E-Print Network [OSTI]

    Pruess, K.

    2011-01-01

    Stimulations at the European EGS Site Soultz-sous-Forêts,Dual-Tracer Spikings during EGS Creation in Northern Germanenhanced geothermal systems (EGS) in rocks with insufficient

  16. Laboratory testing and modeling to evaluate perfluorocarbon compounds as tracers in geothermal systems

    SciTech Connect (OSTI)

    Reimus, Paul W [Los Alamos National Laboratory

    2011-01-21

    The thermal stability and adsorption characteristics of three perfluorinated hydrocarbon compounds were evaluated under geothermal conditions to determine the potential to use these compounds as conservative or thermally-degrading tracers in Engineered (or Enhanced) Geothermal Systems (EGS). The three compounds tested were perfluorodimethyl-cyclobutane (PDCB), perfluoromethylcyclohexane (PMCH), and perfluorotrimethylcyclohexane (PTCH), which are collectively referred to as perfluorinated tracers, or PFTs. Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second pair was charged with the brine-PFT mixture plus a mineral assemblage chosen to be representative of activated fractures in an EGS reservoir. A fifth reactor was charged with deionized water containing the three PFTs. The experiments were conducted at {approx}100 bar, with temperatures ranging from 230 C to 300 C. Semi-analytical and numerical modeling was also conducted to show how the PFTs could be used in conjunction with other tracers to interrogate surface area to volume ratios and temperature profiles in EGS reservoirs. Both single-well and cross-hole tracer tests are simulated to illustrate how different suites of tracers could be used to accomplish these objectives. The single-well tests are especially attractive for EGS applications because they allow the effectiveness of a stimulation to be evaluated without drilling a second well.

  17. Side-by-Side Thermal Tests of Modular Offices: A Validation Study of the STEM Method

    SciTech Connect (OSTI)

    Judkoff, R.; Balcomb, J.D.; Hancock, C.E.; Barker, G.; Subbarao, K.

    2001-01-11

    Two modular office units were tested at the National Renewable Energy Laboratory (NREL) to establish each unit's thermal performance. The two units were nearly identical in appearance, but one was built with structural insulating panels (SIP), and the other was built using standard frame construction. The primary objective of these tests was to compare the thermal performance of buildings using SIP and standard frame construction. Both units were tested under carefully controlled steady-state conditions in the NREL large-scale environmental enclosure. They were then moved outdoors where Short-Term Energy Monitoring (STEM) tests were performed, and long-term heating and cooling energy use was measured. A secondary objective was to evaluate the accuracy of the NREL STEM method by comparing the results of outdoor STEM tests to steady-state indoor test results. STEM is a method developed by NREL to determine key thermal parameters of a building in-situ, based on a 3-day test sequence. The indoor test facility also provided the opportunity to investigate the phenomenon of infiltration heat recovery in a real building, under carefully controlled conditions, to evaluate the stability of the concentration decay method of tracer gas-based infiltration monitoring, and to compare the blower-door method with the tracer-gas technique in determining infiltration.This project was a cooperative effort with the Structural Insulated Panel Association, the Modular Building Institute, All-American Modular (AAM, the manufacturer of the units), and GE Capitol (the owner of the units). Richard Harmon, the president of AAM, requested NREL's assistance in exploring the feasibility of converting his manufacturing process to SIP construction. His engineering staff needed to assess which comfort and energy benefits might be associated with this new technology. AAM manufactured the two units, and NREL tested the modules for 8 months.

  18. Control methods and valve arrangement for start-up and shutdown of pressurized combustion and gasification systems integrated with a gas turbine

    DOE Patents [OSTI]

    Provol, Steve J. (Carlsbad, CA); Russell, David B. (San Diego, CA); Isaksson, Matti J. (Karhula, FI)

    1994-01-01

    A power plant having a system for converting coal to power in a gas turbine comprises a coal fed pressurized circulating bed for converting coal to pressurized gases, a gas turbine having a compressor for pressurizing air for the pressurized circulating bed and expander for receiving and expanding hot combustion gases for powering a generator, a first fast acting valve for controlling the pressurized air, a second fast acting valve means for controlling pressurized gas from the compressor to the expander.

  19. Gas and dust in the star-forming region rho Oph A: The dust opacity exponent beta and the gas-to-dust mass ratio g2d

    E-Print Network [OSTI]

    Liseau, R; Lunttila, T; Olberg, M; Rydbeck, G; Bergman, P; Justtanont, K; Olofsson, G; de Vries, B L

    2015-01-01

    We aim at determining the spatial distribution of the gas and dust in star-forming regions and address their relative abundances in quantitative terms. We also examine the dust opacity exponent beta for spatial and/or temporal variations. Using mapping observations of the very dense rho Oph A core, we examined standard 1D and non-standard 3D methods to analyse data of far-infrared and submillimeter (submm) continuum radiation. The resulting dust surface density distribution can be compared to that of the gas. The latter was derived from the analysis of accompanying molecular line emission, observed with Herschel from space and with APEX from the ground. As a gas tracer we used N2H+, which is believed to be much less sensitive to freeze-out than CO and its isotopologues. Radiative transfer modelling of the N2H+(J=3-2) and (J=6-5) lines with their hyperfine structure explicitly taken into account provides solutions for the spatial distribution of the column density N(H2), hence the surface density distribution ...

  20. A radiocarbon method and multi-tracer approach to quantifying groundwater discharge to coastal waters

    E-Print Network [OSTI]

    Gramling, Carolyn M

    2003-01-01

    Groundwater discharge into estuaries and the coastal ocean is an important mechanism for the transport of dissolved chemical species to coastal waters. Because many dissolved species are present in groundwater in concentrations ...

  1. Advancing Reactive Tracer Methods for Measuring Thermal Evolution in CO2-

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand DaltonSolar Energy LLCAdemaInformation Vehicle ResearchResourceand

  2. Hot scatterers and tracers for the transfer of heat in collisional dynamics

    E-Print Network [OSTI]

    Raphael Lefevere; Lorenzo Zambotti

    2009-03-31

    We introduce stochastic models for the transport of heat in systems described by local collisional dynamics. The dynamics consists of tracer particles moving through an array of hot scatterers describing the effect of heat baths at fixed temperatures. Those models have the structure of Markov renewal processes. We study their ergodic properties in details and provide a useful formula for the cumulant generating function of the time integrated energy current. We observe that out of thermal equilibrium, the generating function is not analytic. When the set of temperatures of the scatterers is fixed by the condition that in average no energy is exchanged between the scatterers and the system, different behaviours may arise. When the tracer particles are allowed to travel freely through the whole array of scatterers, the temperature profile is linear. If the particles are locked in between scatterers, the temperature profile becomes nonlinear. In both cases, the thermal conductivity is interpreted as a frequency of collision between tracers and scatterers.

  3. gas.ps.gz

    E-Print Network [OSTI]

    2000-08-09

    Aug 9, 2000 ... can be used for simulating a liquid tracer injection and consists of the classical ...... Since natural gases such as methane, propane, butane, and ...

  4. Interpretations of Tracer Tests Performed in the Culebra Dolomite at the Waste Isolation Pilot Plant Site

    SciTech Connect (OSTI)

    MEIGS,LUCY C.; BEAUHEIM,RICHARD L.; JONES,TOYA L.

    2000-08-01

    This report provides (1) an overview of all tracer testing conducted in the Culebra Dolomite Member of the Rustler Formation at the Waste Isolation Pilot Plant (WPP) site, (2) a detailed description of the important information about the 1995-96 tracer tests and the current interpretations of the data, and (3) a summary of the knowledge gained to date through tracer testing in the Culebra. Tracer tests have been used to identify transport processes occurring within the Culebra and quantify relevant parameters for use in performance assessment of the WIPP. The data, especially those from the tests performed in 1995-96, provide valuable insight into transport processes within the Culebra. Interpretations of the tracer tests in combination with geologic information, hydraulic-test information, and laboratory studies have resulted in a greatly improved conceptual model of transport processes within the Culebra. At locations where the transmissivity of the Culebra is low (< 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a single-porosity medium in which advection occurs largely through the primary porosity of the dolomite matrix. At locations where the transmissivity of the Culebra is high (> 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a heterogeneous, layered, fractured medium in which advection occurs largely through fractures and solutes diffuse between fractures and matrix at multiple rates. The variations in diffusion rate can be attributed to both variations in fracture spacing (or the spacing of advective pathways) and matrix heterogeneity. Flow and transport appear to be concentrated in the lower Culebra. At all locations, diffusion is the dominant transport process in the portions of the matrix that tracer does not access by flow.

  5. Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system

    DOE Patents [OSTI]

    Tomlinson, Leroy Omar (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01

    In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

  6. Vapor spill monitoring method

    DOE Patents [OSTI]

    Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

    1985-01-01

    Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

  7. RESULTS FROM THE (1) DATA COLLECTION WORKSHOP, (2) MODELING WORKSHOP AND (3) DRILLING AND CORING METHODS WORKSHOP AS PART OF THE JOINT INDUSTRY PARTICIPATION (JIP) PROJECT TO CHARACTERIZE NATURAL GAS HYDRATES IN THE DEEPWATER GULF OF MEXICO

    SciTech Connect (OSTI)

    Stephen A. Holditch; Emrys Jones

    2002-09-01

    In 2000, Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deepwater portions of the Gulf of Mexico. A Joint Industry Participation (JIP) group was formed in 2001, and a project partially funded by the U.S. Department of Energy (DOE) began in October 2001. The primary objective of this project is to develop technology and data to assist in the characterization of naturally occurring gas hydrates in the deepwater Gulf of Mexico. These naturally occurring gas hydrates can cause problems relating to drilling and production of oil and gas, as well as building and operating pipelines. Other objectives of this project are to better understand how natural gas hydrates can affect seafloor stability, to gather data that can be used to study climate change, and to determine how the results of this project can be used to assess if and how gas hydrates act as a trapping mechanism for shallow oil or gas reservoirs. As part of the project, three workshops were held. The first was a data collection workshop, held in Houston during March 14-15, 2002. The purpose of this workshop was to find out what data exist on gas hydrates and to begin making that data available to the JIP. The second and third workshop, on Geoscience and Reservoir Modeling, and Drilling and Coring Methods, respectively, were held simultaneously in Houston during May 9-10, 2002. The Modeling Workshop was conducted to find out what data the various engineers, scientists and geoscientists want the JIP to collect in both the field and the laboratory. The Drilling and Coring workshop was to begin making plans on how we can collect the data required by the project's principal investigators.

  8. Generalized chloride mass balance: Forward and inverse solutions for one-dimensional tracer convection under transient flux

    SciTech Connect (OSTI)

    Ginn, T.R.; Murphy, E.M.

    1996-12-01

    Forward and inverse solutions are provided for analysis of inert tracer profiles resulting from one-dimensional convective transport under fluxes which vary with time and space separately. The developments are displayed as an extension of conventional chloride mass balance (CMB) techniques to account for transient as well as space-dependent water fluxes. The conventional chloride mass balance has been used over two decades to estimate recharge over large time scales in arid environments. In this mass balance approach, the chloride concentration in the pore water, originating from atmospheric fallout, is inversely proportional to the flux of water through the sediments. The CMB method is especially applicable to arid and semi-arid regions where evapotranspirative enrichment of the pore water produces a distinct chloride profile in the unsaturated zone. The solutions presented allow incorporation of transient fluxes and boundary conditions in CMB analysis, and allow analysis of tracer profile data which is not constant with depth below extraction zone in terms of a rational water transport model. A closed-form inverse solution is derived which shows uniqueness of model parameter and boundary condition (including paleoprecipitation) estimation, for the specified flow model. Recent expressions of the conventional chloride mass balance technique are derived from the general model presented here; the conventional CMB is shown to be fully compatible with this transient flow model and it requires the steady-state assumption on chloride mass deposition only (and not on water fluxes or boundary conditions). The solutions and results are demonstrated on chloride profile data from west central New Mexico.

  9. An evaluation of joint repair methods for cast iron natural gas distribution mains and the preliminary development of an alternative joint seal

    E-Print Network [OSTI]

    Rogers, Thomas Edward

    1984-01-01

    Approximately 10 percent of the natural gas pumped into distribution systems is unaccounted for. A significant portion of this amount is leakage from joints in 50 to 100 year old cast iron main. Because of the cumulative ...

  10. Using Thermally-Degrading, Partitioning, and Nonreactive Tracers to Determine Temperature Distribution and Fracture/Heat Transfer Surface Area in Geothermal Reservoirs

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Project Summary. The goal of this project is to provide integrated tracer and tracer interpretation tools to facilitate quantitative characterization of temperature distributions and surface area available for heat transfer in EGS.

  11. Carbon-13 Labeled Polymers: An Alternative Tracer for Depth Profiling of Polymer Films and

    E-Print Network [OSTI]

    Carbon-13 Labeled Polymers: An Alternative Tracer for Depth Profiling of Polymer Films profiling of polymer films and multilayers using secondary ion mass spectrometry (SIMS). Deuterium substitution has traditionally been used in depth profiling of polymers but can affect the phase behavior

  12. Controls on soil methane fluxes: Tests of biophysical mechanisms using stable isotope tracers

    E-Print Network [OSTI]

    Controls on soil methane fluxes: Tests of biophysical mechanisms using stable isotope tracers November 2006; published 4 May 2007. [1] Understanding factors that control methane exchange between soils-scale variations in soil methane emissions: (1) consumption of methane by methanotrophic bacteria, (2) quantity

  13. Using chemical tracers in hillslope soils to estimate the importance of chemical denudation under

    E-Print Network [OSTI]

    Mudd, Simon Marius

    Using chemical tracers in hillslope soils to estimate the importance of chemical denudation under mass. The model includes both sediment transport and chemical denudation. A simplified two-phase model is developed; the two phases are a chemically immobile phase, which has far lower solubility than the bulk soil

  14. Argon as a Tracer of Cross-Isopycnal Mixing in the Thermocline CARA C. HENNING

    E-Print Network [OSTI]

    Argon as a Tracer of Cross-Isopycnal Mixing in the Thermocline CARA C. HENNING University (Kelley and Van Scoy 1999), and observations of temperature or velocity microstructure measurements (e 1999), there is a consensus that the local cross-isopycnal diffusivity is on the order of 1­3 ( 10 5 m2

  15. Plumbing the Depths: Testing Natural Tracers of Subsurface CO2 Origin and

    E-Print Network [OSTI]

    Gilfillan, Stuart

    to be added to the CO2 at the time of injec- tion. This will marginally increase the cost of storagePlumbing the Depths: Testing Natural Tracers of Subsurface CO2 Origin and Migration, Utah Mark storage of fluid CO2 in porous subsurface rock will re- quire the ability to track, and identify

  16. Enhanced tracer transport by the spiral defect chaos state of a convecting fluid

    E-Print Network [OSTI]

    K. -H. Chiam; M. C. Cross; H. S. Greenside; P. F. Fischer

    2004-09-23

    To understand how spatiotemporal chaos may modify material transport, we use direct numerical simulations of the three-dimensional Boussinesq equations and of an advection-diffusion equation to study the transport of a passive tracer by the spiral defect chaos state of a convecting fluid. The simulations show that the transport is diffusive and is enhanced by the spatiotemporal chaos. The enhancement in tracer diffusivity follows two regimes. For large Peclet numbers (that is, small molecular diffusivities of the tracer), we find that the enhancement is proportional to the Peclet number. For small Peclet numbers, the enhancement is proportional to the square root of the Peclet number. We explain the presence of these two regimes in terms of how the local transport depends on the local wave numbers of the convection rolls. For large Peclet numbers, we further find that defects cause the tracer diffusivity to be enhanced locally in the direction orthogonal to the local wave vector but suppressed in the direction of the local wave vector.

  17. Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum Oxide Catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum of propane over ZrO2-supported MoOx catalysts. Competitive reactions of C3H6 and CH3 13 CH2CH3 showed combustion of propene, or by direct combustion of propane. A mixture of C3H8 and C3D8 undergoes oxidative

  18. 6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS AND TRACERS OF GALACTIC

    E-Print Network [OSTI]

    Richardson Jr., James E.

    6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS AND TRACERS OF GALACTIC STRUCTURE A Dissertation Jagadheep Dhanasekara Pandian ALL RIGHTS RESERVED #12;6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS transition of methanol is the strongest of methanol masers, and is the second strongest maser transition ever

  19. Chaotic Mixing of Tracer and Vorticity by Modulated Traveling Rossby Waves

    E-Print Network [OSTI]

    ,-- even though the physics of the present case is very different. We have produced two independent of subtler aspects of the mixing. It is shown the chaotic advection produces very nonlocal mixing which cannot be represented by eddy diffusivity. Also, the power spectrum of the tracer field is found to be k

  20. Tracer transport in the presence of steady zonal jets in a forced and viscous barotropic model 

    E-Print Network [OSTI]

    Collier, Jonathan Craig

    2000-01-01

    to the time since release, and in the long-time limit, to the square root of the time. Tracers released into a fluid which was anisotropic and contained steady zonal jets, exhibited an inhibition of meridional excursion. However, the length scale associated...

  1. Analysis of Pollutant and Tracer Dispersion During a Prescribed Forest Burn

    E-Print Network [OSTI]

    Collins, Gary S.

    Analysis of Pollutant and Tracer Dispersion During a Prescribed Forest Burn Y. Wu1, G. Allwine1, X the potential for catastrophic wildfires and to improve the health of forests, however, emissions of pollutants from prescribed fires contribute to local and regional air quality issues and health impacts. Emissions

  2. TRACER: A Trace Replay Tool to Evaluate Energy-Efficiency of Mass Storage Systems

    E-Print Network [OSTI]

    Qin, Xiao

    TRACER: A Trace Replay Tool to Evaluate Energy-Efficiency of Mass Storage Systems Zhuo Liu1 , Fei for Optoelectronics 1 Key Laboratory of Data Storage Systems,Ministry of Education of China 1 School of Computer Sci://www.eng.auburn.edu/xqin * Corresponding Author: wufei@hust.edu.cn Abstract--Improving energy efficiency of mass storage systems has become

  3. Verification of flow processes in soils with combined sprinkling and dye tracer experiments

    E-Print Network [OSTI]

    Weiler, Markus

    1 Verification of flow processes in soils with combined sprinkling and dye tracer experiments. Water flow in soils is influenced by macropores, by the heterogeneity of the soil matrix, and by the exchange of water between macropores and the soil matrix (interaction). The degree of interaction

  4. Marine Chemistry special issue: The renaissance of radium isotopic tracers in marine processes studies

    E-Print Network [OSTI]

    by the Marine Environment Laboratories, International Atomic Energy Agency (IAEA-MEL). There were 26Editorial Marine Chemistry special issue: The renaissance of radium isotopic tracers in marine interpretation and modeling of radium measurements in marine systems as well as perspectives on special

  5. Rotanone analogs: method of preparation and use

    SciTech Connect (OSTI)

    ;

    2013-10-08

    The present invention provides rotenone analogs and methods of making and using them. Labeled with single photon and positron emitting isotopes, the rotenone analogs of the present invention are useful in, for example, clinical imaging applications as tracers to measure cardiac blood flow and detect regions of ischemia.

  6. Long term performance of different radon remedial methods in Sweden

    E-Print Network [OSTI]

    Clavensjoe, B

    2002-01-01

    The object of this project was to investigate the long time effectiveness of different radon remedial methods. The ten years project started 1991. From start the investigation comprised of 105 dwellings (91 single-family houses and 14 flats in multi-family buildings). In all of the dwellings remedial measures were carried out in the eighties. Before and immediately after the reduction the local measured the radon concentrations. New measurements of the radon concentrations have been made every third year; in 1991, 1994, 1997 and in 2000. Twelve different radon remedial methods and method combinations were used. The radon sources were building materials as well as sub-soils. In all of the dwellings the radon concentrations were measured by nuclear track films during 3 months (January-March) measurements and in half of them the air change rates by passive tracer gas methods. The results of the 2000 and the 1991 (within brackets) studies showed that the radon concentration was up to 200 Bq/m sup 3 in 54 (54) sin...

  7. July 25, 2002 THE MOTION OF A TRACER PARTICLE

    E-Print Network [OSTI]

    P. F. Tupper Department of Mathematics and Statistics, McGill University Montr´eal, Qu´ebec, CANADA and interact through instantaneous energy- and momentum-conserving collisions. As the number of particles symplectic, the other energy-conserving, and assess the methods' ability to recapture the system's limiting

  8. Cryogenic treatment of gas

    DOE Patents [OSTI]

    Bravo, Jose Luis (Houston, TX); Harvey, III, Albert Destrehan (Kingwood, TX); Vinegar, Harold J. (Bellaire, TX)

    2012-04-03

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  9. Integrated vacuum absorption steam cycle gas separation

    DOE Patents [OSTI]

    Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

    2011-11-22

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  10. Constraining ultra large-scale cosmology with multiple tracers in optical and radio surveys

    E-Print Network [OSTI]

    Alonso, David

    2015-01-01

    Multiple tracers of the cosmic density field, with different bias, number and luminosity evolution, can be used to measure the large-scale properties of the Universe. We show how an optimal combination of tracers can be used to detect general-relativistic effects in the observed density of sources. We forecast for the detectability of these effects, as well as measurements of primordial non-Gaussianity and large-scale lensing magnification with current and upcoming large-scale structure experiments. In particular we quantify the significance of these detections in the short term with experiments such as the Dark Energy Survey (DES), and in the long term with the Large Synoptic Survey Telescope (LSST) and the Square Kilometre Array (SKA). We review the main observational challenges that must be overcome to carry out these measurements.

  11. Quantitative measurement of binary liquid distributions using multiple-tracer x-ray fluorescence and radiography

    SciTech Connect (OSTI)

    Halls, Benjamin R.; Meyer, Terrence R.; Kastengren, Alan L.

    2015-01-01

    The complex geometry and large index-of-refraction gradients that occur near the point of impingement of binary liquid jets present a challenging environment for optical interrogation. A simultaneous quadruple-tracer x-ray fluorescence and line-of-sight radiography technique is proposed as a means of distinguishing and quantifying individual liquid component distributions prior to, during, and after jet impact. Two different pairs of fluorescence tracers are seeded into each liquid stream to maximize their attenuation ratio for reabsorption correction and differentiation of the two fluids during mixing. This approach for instantaneous correction of x-ray fluorescence reabsorption is compared with a more time-intensive approach of using stereographic reconstruction of x-ray attenuation along multiple lines of sight. The proposed methodology addresses the need for a quantitative measurement technique capable of interrogating optically complex, near-field liquid distributions in many mixing systems of practical interest involving two or more liquid streams.

  12. Quantitative measurement of binary liquid distributions using multiple-tracer x-ray fluorescence and radiography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Halls, Benjamin R.; Meyer, Terrence R.; Kastengren, Alan L.

    2015-01-23

    The complex geometry and large index-of-refraction gradients that occur near the point of impingement of binary liquid jets present a challenging environment for optical interrogation. A simultaneous quadruple-tracer x-ray fluorescence and line-of-sight radiography technique is proposed as a means of distinguishing and quantifying individual liquid component distributions prior to, during, and after jet impact. Two different pairs of fluorescence tracers are seeded into each liquid stream to maximize their attenuation ratio for reabsorption correction and differentiation of the two fluids during mixing. This approach for instantaneous correction of x-ray fluorescence reabsorption is compared with a more time-intensive approach of usingmore »stereographic reconstruction of x-ray attenuation along multiple lines of sight. The proposed methodology addresses the need for a quantitative measurement technique capable of interrogating optically complex, near-field liquid distributions in many mixing systems of practical interest involving two or more liquid streams.« less

  13. Gas Mask 

    E-Print Network [OSTI]

    Unknown

    2011-09-05

    The gas industry fostered more efficient energy utilization long before the idea of energy conservation became fashionable. It became apparent in the late '60's that misguided Federal Legislation was discouraging necessary search for new gas...

  14. Fuel gas desulfurization

    DOE Patents [OSTI]

    Yang, Ralph T. (Tonawanda, NY); Shen, Ming-Shing (Rocky Point, NY)

    1981-01-01

    A method for removing sulfurous gases such as H.sub.2 S and COS from a fuel gas is disclosed wherein limestone particulates containing iron sulfide provide catalytic absorption of the H.sub.2 S and COS by the limestone. The method is effective at temperatures of 400.degree. C. to 700.degree. C. in particular.

  15. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  16. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye (Newton, MA)

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  17. Formaldehyde Silhouettes Against the Cosmic Microwave Background: A Mass-Limited, Distance-Independent, Extinction-Free Tracer of Star Formation Across the Epoch of Galaxy Evolution

    E-Print Network [OSTI]

    Darling, Jeremy

    2012-01-01

    We examine the absorption of cosmic microwave background (CMB) photons by formaldehyde (H2CO) over cosmic time. The K-doublet rotational transitions of H2CO become "refrigerated" - their excitation temperatures are driven below the CMB temperature - via collisional pumping by molecular hydrogen (H2). "Anti-inverted" H2CO line ratios thus provide an accurate measurement of the H2 density in molecular clouds. Using a radiative transfer model, we demonstrate that H2CO centimeter wavelength line excitation and detectability are nearly independent of redshift or gas kinetic temperature. Since the H2CO K-doublet lines absorb CMB light, and since the CMB lies behind every galaxy and provides an exceptionally uniform extended illumination source, H2CO is a distance-independent, extinction-free molecular gas mass-limited tracer of dense gas in galaxies. A Formaldehyde Deep Field could map the history of cosmic star formation in a uniquely unbiased fashion and may be possible with large bandwidth wide-field radio inter...

  18. Flux Measurements of Volatile Organic Compounds from an Urban Tower Platform in Houston, Texas: Trends and Tracers 

    E-Print Network [OSTI]

    Hale, Martin C

    2014-05-08

    and traffic counts except during variable working hours. To assign measured fluxes to local sources, we tested a bulk flux footprint model (Kormann and Meixner model) designed for uniform emission surface areas in this urban, heterogeneous landscape. Tracer...

  19. Thorium-234 as a tracer of spatial, temporal and vertical variability in particle flux in the North Pacific

    E-Print Network [OSTI]

    Siegel, David A.

    Thorium-234 as a tracer of spatial, temporal and vertical variability in particle flux in the North Available online 16 April 2009 Keywords: Thorium-234 Particle flux Sediment trap Scavenging North Pacific

  20. Integrated Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. This objective of this project is to develop an innovative approach to estimate fracture surface area and spacing through interpretation of signals of natural chemical and isotopic tracers.

  1. Semianalytical Solutions of Radioactive or Reactive Tracer Transport in Layered Fractured Media

    SciTech Connect (OSTI)

    G.J. Moridis; G. S. Bodvarsson

    2001-10-01

    In this paper, semianalytical solutions are developed for the problem of transport of radioactive or reactive tracers (solutes or colloids) through a layered system of heterogeneous fractured media with misaligned fractures. The tracer transport equations in the matrix account for (a) diffusion, (b) surface diffusion (for solutes only), (c) mass transfer between the mobile and immobile water fractions, (d) linear kinetic or equilibrium physical, chemical, or combined solute sorption or colloid filtration, and (e) radioactive decay or first order chemical reactions. Any number of radioactive decay daughter products (or products of a linear, first-order reaction chain) can be tracked. The tracer-transport equations in the fractures account for the same processes, in addition to advection and hydrodynamic dispersion. Additionally, the colloid transport equations account for straining and velocity adjustments related to the colloidal size. The solutions, which are analytical in the Laplace space, are numerically inverted to provide the solution in time and can accommodate any number of fractured and/or porous layers. The solutions are verified using analytical solutions for limiting cases of solute and colloid transport through fractured and porous media. The effect of important parameters on the transport of {sup 3}H, {sup 237}Np and {sup 239}Pu (and its daughters) is investigated in several test problems involving layered geological systems of varying complexity. {sup 239}Pu colloid transport problems in multilayered systems indicate significant colloid accumulations at straining interfaces but much faster transport of the colloid than the corresponding strongly sorbing solute species.

  2. ALPHA SPECTROMETRIC EVALUATION OF SRM-995 AS A POTENTIAL URANIUM/THORIUM DOUBLE TRACER SYSTEM FOR AGE-DATING URANIUM MATERIALS

    SciTech Connect (OSTI)

    Beals, D.

    2011-12-06

    Uranium-233 (t{sub 1/2} {approx} 1.59E5 years) is an artificial, fissile isotope of uranium that has significant importance in nuclear forensics. The isotope provides a unique signature in determining the origin and provenance of uranium-bearing materials and is valuable as a mass spectrometric tracer. Alpha spectrometry was employed in the critical evaluation of a {sup 233}U standard reference material (SRM-995) as a dual tracer system based on the in-growth of {sup 229}Th (t{sub 1/2} {approx} 7.34E3 years) for {approx}35 years following radiochemical purification. Preliminary investigations focused on the isotopic analysis of standards and unmodified fractions of SRM-995; all samples were separated and purified using a multi-column anion-exchange scheme. The {sup 229}Th/{sup 233}U atom ratio for SRM-995 was found to be 1.598E-4 ({+-} 4.50%) using recovery-corrected radiochemical methods. Using the Bateman equations and relevant half-lives, this ratio reflects a material that was purified {approx} 36.8 years prior to this analysis. The calculated age is discussed in contrast with both the date of certification and the recorded date of last purification.

  3. Supersonic gas compressor

    DOE Patents [OSTI]

    Lawlor, Shawn P. (Bellevue, WA); Novaresi, Mark A. (San Diego, CA); Cornelius, Charles C. (Kirkland, WA)

    2007-11-13

    A gas compressor based on the use of a driven rotor having a compression ramp traveling at a local supersonic inlet velocity (based on the combination of inlet gas velocity and tangential speed of the ramp) which compresses inlet gas against a stationary sidewall. In using this method to compress inlet gas, the supersonic compressor efficiently achieves high compression ratios while utilizing a compact, stabilized gasdynamic flow path. Operated at supersonic speeds, the inlet stabilizes an oblique/normal shock system in the gasdyanamic flow path formed between the rim of the rotor, the strakes, and a stationary external housing. Part load efficiency is enhanced by the use of a pre-swirl compressor, and using a bypass stream to bleed a portion of the intermediate pressure gas after passing through the pre-swirl compressor back to the inlet of the pre-swirl compressor. Inlet guide vanes to the compression ramp enhance overall efficiency.

  4. Heat as a Tracer to Examine Hydraulic Conductance Near the RussianRiver Bank Filtration Facility, Sonoma County, CA

    SciTech Connect (OSTI)

    Constantz, Jim; Su, Grace; Hatch, Christine

    2004-08-01

    Both the measurement of temperature and the simulation of heat and water transport have benefited from significant recent advances in data acquisition and computer resources. This has afforded the opportunity for routine use of heat as a tracer in a variety of hydrological regimes. Heat is particularly well suited for investigations of stream/groundwater exchanges. Dynamic temperature patterns between the stream and underlying sediments are typical, due to large stream surface area to volume ratios relative to other surface water bodies. Heat is a naturally occurring tracer, free from (real or perceived) issues of contamination associated with use of chemical tracers in stream environments. The use of heat as a tracer relies on the measurement of temperature gradients, and temperature is an extremely robust parameter to monitor. Temperature data is immediately available as opposed to chemical tracers, which often require significant laboratory analysis. In this work, we report on the progress in the use of heat as a tracer to determine the hydraulic conductance of the streambed along the middle reaches of the Russian River, located west of Santa Rosa, CA. The general hydrological setting is described and the unique matter in which the water resources are managed in an environment of increasing population, a rapid shift to agricultural crops requiring more irrigation, and a series of fishery related mandates.

  5. 100-NR-2 Apatite Treatability Test: Fall 2010 Tracer Infiltration Test (White Paper)

    SciTech Connect (OSTI)

    Vermeul, Vincent R.; Fritz, Brad G.; Fruchter, Jonathan S.; Greenwood, William J.; Johnson, Timothy C.; Horner, Jacob A.; Strickland, Christopher E.; Szecsody, James E.; Williams, Mark D.

    2011-04-14

    The primary objectives of the tracer infiltration test were to 1) determine whether field-scale hydraulic properties for the compacted roadbed materials and underlying Hanford fm. sediments comprising the zone of water table fluctuation beneath the site are consistent with estimates based laboratory-scale measurements on core samples and 2) characterize wetting front advancement and distribution of soil moisture achieved for the selected application rate. These primary objectives were met. The test successfully demonstrated that 1) the remaining 2 to 3 ft of compacted roadbed material below the infiltration gallery does not limit infiltration rates to levels that would be expected to eliminate near surface application as a viable amendment delivery approach and 2) the combined aqueous and geophysical monitoring approaches employed at this site, with some operational adjustments based on lessons learned, provides an effective means of assessing wetting front advancement and the distribution of soil moisture achieved for a given solution application. Reasonably good agreement between predicted and observed tracer and moisture front advancement rates was observed. During the first tracer infiltration test, which used a solution application rate of 0.7 cm/hr, tracer arrivals were observed at the water table (10 to 12 ft below the bottom of the infiltration gallery) after approximately 5 days, for an advancement rate of approximately 2 ft/day. This advancement rate is generally consistent with pre-test modeling results that predicted tracer arrival at the water table after approximately 5 days (see Figure 8, bottom left panel). This agreement indicates that hydraulic property values specified in the model for the compacted roadbed materials and underlying Hanford formation sediments, which were based on laboratory-scale measurements, are reasonable estimates of actual field-scale conditions. Additional work is needed to develop a working relationship between resistivity change and the associated change in moisture content so that 4D images of moisture content change can be generated. Results from this field test will be available for any future Ca-citrate-PO4 amendment infiltration tests, which would be designed to evaluate the efficacy of using near surface application of amendments to form apatite mineral phases in the upper portion of the zone of water table fluctuation.

  6. Method and apparatus utilizing ionizing and microwave radiation for saturation determination of water, oil and a gas in a core sample

    DOE Patents [OSTI]

    Maerefat, Nicida L. (Sugar Land, TX); Parmeswar, Ravi (Marlton, NJ); Brinkmeyer, Alan D. (Tulsa, OK); Honarpour, Mehdi (Bartlesville, OK)

    1994-01-01

    A system for determining the relative permeabilities of gas, water and oil in a core sample has a microwave emitter/detector subsystem and an X-ray emitter/detector subsystem. A core holder positions the core sample between microwave absorbers which prevent diffracted microwaves from reaching a microwave detector where they would reduce the signal-to-noise ratio of the microwave measurements. The microwave emitter/detector subsystem and the X-ray emitter/detector subsystem each have linear calibration characteristics, allowing one subsystem to be calibrated with respect to the other subsystem. The dynamic range of microwave measurements is extended through the use of adjustable attenuators. This also facilitates the use of core samples with wide diameters. The stratification characteristics of the fluids may be observed with a windowed cell separator at the outlet of the core sample. The condensation of heavy hydrocarbon gas and the dynamic characteristics of the fluids are observed with a sight glass at the outlet of the core sample.

  7. Method and apparatus utilizing ionizing and microwave radiation for saturation determination of water, oil and a gas in a core sample

    DOE Patents [OSTI]

    Maerefat, N.L.; Parmeswar, R.; Brinkmeyer, A.D.; Honarpour, M.

    1994-08-23

    A system is described for determining the relative permeabilities of gas, water and oil in a core sample has a microwave emitter/detector subsystem and an X-ray emitter/detector subsystem. A core holder positions the core sample between microwave absorbers which prevent diffracted microwaves from reaching a microwave detector where they would reduce the signal-to-noise ratio of the microwave measurements. The microwave emitter/detector subsystem and the X-ray emitter/detector subsystem each have linear calibration characteristics, allowing one subsystem to be calibrated with respect to the other subsystem. The dynamic range of microwave measurements is extended through the use of adjustable attenuators. This also facilitates the use of core samples with wide diameters. The stratification characteristics of the fluids may be observed with a windowed cell separator at the outlet of the core sample. The condensation of heavy hydrocarbon gas and the dynamic characteristics of the fluids are observed with a sight glass at the outlet of the core sample. 11 figs.

  8. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  9. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  10. FORMALDEHYDE AND TRACER GAS TRANSFER BETWEEN AIRSTREAMS IN ENTHALPY-TYPE AIR-TO-AIR HEAT EXCHANGERS

    E-Print Network [OSTI]

    Fisk, W.J.

    2014-01-01

    air- by this type of heat exchanger and, thus, returned toIN ENTHALPY-TYPE AIR-TO-AIR HEAT EXCHANGERS AIRSTRE&~S W.J.IN ENTHALPY-TYPE AIR-TQ-AIR HEAT EXCHANGERS William J. Fisk,

  11. FORMALDEHYDE AND TRACER GAS TRANSFER BETWEEN AIRSTREAMS IN ENTHALPY-TYPE AIR-TO-AIR HEAT EXCHANGERS

    E-Print Network [OSTI]

    Fisk, W.J.

    2014-01-01

    The generation of dry formaldehyde at ppb to ppm levels byT.G. et al. , 1983. "Formaldehyde release from pressed-woodmethod determination of formaldehyde in air". Analytical

  12. FORMALDEHYDE AND TRACER GAS TRANSFER BETWEEN AIRSTREAMS IN ENTHALPY-TYPE AIR-TO-AIR HEAT EXCHANGERS

    E-Print Network [OSTI]

    Fisk, W.J.

    2014-01-01

    ratios for HCHO, water, and dry air were calculated from thethen given up to the colder air- water vapor from the humidcoefficient in air; listed in table 1 for water vapor,

  13. A CFD study of gas-solid jet in a CFB riser flow

    SciTech Connect (OSTI)

    Li, Tingwen; Guenther, Chris

    2012-03-01

    Three-dimensional high-resolution numerical simulations of a gas–solid jet in a high-density riser flow were conducted. The impact of gas–solid injection on the riser flow hydrodynamics was investigated with respect to voidage, tracer mass fractions, and solids velocity distribution. The behaviors of a gas–solid jet in the riser crossflow were studied through the unsteady numerical simulations. Substantial separation of the jetting gas and solids in the riser crossflow was observed. Mixing of the injected gas and solids with the riser flow was investigated and backmixing of gas and solids was evaluated. In the current numerical study, both the overall hydrodynamics of riser flow and the characteristics of gas–solid jet were reasonably predicted compared with the experimental measurements made at NETL.

  14. Rapid gas hydrate formation process

    DOE Patents [OSTI]

    Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

    2013-01-15

    The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

  15. Internal corrosion monitoring of subsea oil and gas production equipment

    SciTech Connect (OSTI)

    Joosten, M.W.; Fischer, K.P.; Lunden, K.C.

    1995-04-01

    Nonintrusive techniques will dominate subsea corrosion monitoring compared with the intrusive methods because such methods do not interfere with pipeline operations. The long-term reliability of the nonintrusive techniques in general is considered to be much better than that of intrusive-type probes. The nonintrusive techniques based on radioactive tracers (TLA, NA) and FSM and UT are expected to be the main types of subsea corrosion monitoring equipment in the coming years. Available techniques that could be developed specifically for subsea applications are: electrochemical noise, corrosion potentials (using new types of reference electrodes), multiprobe system for electrochemical measurements, and video camera inspection (mini-video camera with light source). The following innovative techniques have potential but need further development: ion selective electrodes, radioactive tracers, and Raman spectroscopy.

  16. A new method for producing molybdenum-99 without the

    E-Print Network [OSTI]

    Langendoen, Koen

    -life Molybdenum-99 decays into technetium-99. It is this that is used as the actual tracer in medical imaging for molybdenum-99 to be produced in other nuclear reactors than those using uranium fission, improving worldwideA new method for producing molybdenum-99 without the need for enriched uranium can bring an end

  17. Polymide gas separation membranes

    DOE Patents [OSTI]

    Ding, Yong; Bikson, Benjamin; Nelson, Joyce Katz

    2004-09-14

    Soluble polyamic acid salt (PAAS) precursors comprised of tertiary and quaternary amines, ammonium cations, sulfonium cations, or phosphonium cations, are prepared and fabricated into membranes that are subsequently imidized and converted into rigid-rod polyimide articles, such as membranes with desirable gas separation properties. A method of enhancing solubility of PAAS polymers in alcohols is also disclosed.

  18. Gas turbine diagnostic system

    E-Print Network [OSTI]

    Talgat, Shuvatov

    2011-01-01

    In the given article the methods of parametric diagnostics of gas turbine based on fuzzy logic is proposed. The diagnostic map of interconnection between some parts of turbine and changes of corresponding parameters has been developed. Also we have created model to define the efficiency of the compressor using fuzzy logic algorithms.

  19. Water ice deuteration: a tracer of the chemical history of protostars

    E-Print Network [OSTI]

    Taquet, Vianney; Kahane, Claudine; Ceccarelli, Cecilia; Lòpez-Sepulcre, Ana; Toubin, Céline; Duflot, Denis; Wiesenfeld, Laurent

    2012-01-01

    Context. Millimetric observations have measured large degrees of molecular deuteration in several species seen around low-mass protostars. The Herschel Space Telescope, launched in 2009, is now providing new measures of the deuterium fractionation of water, the main constituent of interstellar ices. Aims. We aim at theoretically studying the formation and the deuteration of water which is believed to be formed on interstellar grain surfaces in molecular clouds. Methods. We used our gas-grain astrochemical model GRAINOBLE which considers the multilayer formation of interstellar ices. We varied several input parameters to study their impact on water deuteration. We included the treatment of ortho and para states of key species, including H2, that affects the deuterium fractionation of all molecules. The model also includes relevant laboratory and theoretical works on water formation and deuteration on grain surfaces. In particular, we computed the transmission probabilities of surface reactions using the Eckart...

  20. DIVE in the cosmic web: voids with Delaunay Triangulation from discrete matter tracer distributions

    E-Print Network [OSTI]

    Zhao, Cheng; Liang, Yu; Kitaura, Francisco-Shu; Chuang, Chia-Hsun

    2015-01-01

    We present a novel parameter-free cosmological void finder (\\textsc{dive}, Delaunay TrIangulation Void findEr) based on Delaunay Triangulation (DT), which efficiently computes the empty spheres constrained by a discrete set of tracers. We define the spheres as DT voids, and describe their properties, including an universal density profile together with an intrinsic scatter. We apply this technique on 100 halo catalogues with volumes of 2.5\\,$h^{-1}$Gpc side each, with a bias and number density similar to the BOSS CMASS Luminous Red Galaxies, performed with the \\textsc{patchy} code. Our results show that there are two main species of DT voids, which can be characterised by the radius: they have different responses to halo redshift space distortions, to number density of tracers, and reside in different dark matter environments. Based on dynamical arguments using the tidal field tensor, we demonstrate that large DT voids are hosted in expanding regions, whereas the haloes used to construct them reside in collap...

  1. A cubic matrix-fracture geometry model for radial tracer flow in naturally fractured reservoirs

    SciTech Connect (OSTI)

    Jetzabeth Ramirez-Sabag; Fernando Samaniego V.

    1992-01-01

    This study presents a general solution for the radial flow of tracers in naturally fractured reservoirs, with cubic blocks matrix-fracture geometry. Continuous and finite step injection of chemical and radioactive tracers are considered. The reservoir is treated as being composed of two regions: a mobile where dispersion and convection take place and a stagnant where only diffusion and adsorption are allowed. Radioactive decay is considered in both regions. The model of this study is thoroughly compared under proper simplified conditions to those previously presented in the literature. The coupled matrix to fracture solution in the Laplace space is numerically inverted by means of the Crump algorithm. A detailed validation of the model with respect to solutions previously presented and/or simplified physical conditions solutions (i.e., homogeneous case) or limit solutions (i.e., naturally fractured nearly homogeneous) was carried out. The influence of the three of the main dimensionless parameters that enter into the solution was carefully investigated. A comparison of results for three different naturally fractured systems, vertical fractures (linear flow), horizontal fractures (radial flow) and the cubic geometry model of this study, is presented.

  2. Two-solvent method synthesis of SnO{sub 2} nanoparticles embedded in SBA-15: Gas-sensing and photocatalytic properties study

    SciTech Connect (OSTI)

    Dai, Peng; Zhang, Lili; Li, Guang; Sun, Zhaoqi; Liu, Xiansong; Wu, Mingzai

    2014-02-01

    Graphical abstract: Different loadings of SnO{sub 2} nanoparticles embedded in mesoporous silica (sample S1, S2 and S3) show higher response to H{sub 2} at lower operating temperature than pure SnO{sub 2} nanoparticles. - Highlights: • Two-solvent method is firstly used to synthesize SnO{sub 2} nanoparticles embedded in mesoporous silica (SBA-15). • The SnO{sub 2}/SBA-15 nanocomposites show higher response to H{sub 2} at lower operating temperature than pure SnO{sub 2} nanoparticles. • The SnO{sub 2}/SBA-15 nanocomposites have higher photodegradation ability toward methylene blue than pure SnO{sub 2} nanoparticles. - Abstract: Different loadings of SnO{sub 2} nanoparticles embedded in mesoporous silica (SBA-15) were prepared via a two-solvent method with the ordered hexagonal mesoporous structure of SBA-15 kept. X-ray diffraction, transmission electron microscope, X-ray photoelectron spectroscopy and N{sub 2} adsorption porosimetry were employed to characterize the nanocomposites. Compared with pure SnO{sub 2} nanoparticles, the SnO{sub 2}/SBA-15 nanocomposites show higher response to H{sub 2} at lower operating temperature. The photocatalytic activity of as-prepared SnO{sub 2}/SBA-15 for degradation of methylene blue was investigated under UV light irradiation and the results show that the SnO{sub 2}/SBA-15 nanocomposites have higher photodegradation ability toward methylene blue than pure SnO{sub 2} nanoparticles.

  3. Gas turbine combustor transition

    DOE Patents [OSTI]

    Coslow, Billy Joe (Winter Park, FL); Whidden, Graydon Lane (Great Blue, CT)

    1999-01-01

    A method of converting a steam cooled transition to an air cooled transition in a gas turbine having a compressor in fluid communication with a combustor, a turbine section in fluid communication with the combustor, the transition disposed in a combustor shell and having a cooling circuit connecting a steam outlet and a steam inlet and wherein hot gas flows from the combustor through the transition and to the turbine section, includes forming an air outlet in the transition in fluid communication with the cooling circuit and providing for an air inlet in the transition in fluid communication with the cooling circuit.

  4. Gas turbine combustor transition

    DOE Patents [OSTI]

    Coslow, B.J.; Whidden, G.L.

    1999-05-25

    A method is described for converting a steam cooled transition to an air cooled transition in a gas turbine having a compressor in fluid communication with a combustor, a turbine section in fluid communication with the combustor, the transition disposed in a combustor shell and having a cooling circuit connecting a steam outlet and a steam inlet and wherein hot gas flows from the combustor through the transition and to the turbine section, includes forming an air outlet in the transition in fluid communication with the cooling circuit and providing for an air inlet in the transition in fluid communication with the cooling circuit. 7 figs.

  5. Flammable gas project topical report

    SciTech Connect (OSTI)

    Johnson, G.D.

    1997-01-29

    The flammable gas safety issue was recognized in 1990 with the declaration of an unreviewed safety question (USQ) by the U. S. Department of Energy as a result of the behavior of the Hanford Site high-level waste tank 241-SY-101. This tank exhibited episodic releases of flammable gas that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years there has been a considerable amount of knowledge gained about the chemical and physical processes that govern the behavior of tank 241-SY-1 01 and other tanks associated with the flammable gas safety issue. This report was prepared to provide an overview of that knowledge and to provide a description of the key information still needed to resolve the issue. Items covered by this report include summaries of the understanding of gas generation, retention and release mechanisms, the composition and flammability behavior of the gas mixture, the amounts of stored gas, and estimated gas release fractions for spontaneous releases. `Me report also discusses methods being developed for evaluating the 177 tanks at the Hanford Site and the problems associated with these methods. Means for measuring the gases emitted from the waste are described along with laboratory experiments designed to gain more information regarding rates of generation, species of gases emitted and modes of gas storage and release. Finally, the process for closing the USQ is outlined as are the information requirements to understand and resolve the flammable gas issue.

  6. VALIDATION OF NOMINATIONS IN GAS NETWORK OPTIMIZATION ...

    E-Print Network [OSTI]

    2013-11-17

    in gas transportation, namely the validation of nomination problem: Given a ...... Mathematical Methods in Fluid Dynamics, volume 67 of Pitman Monographs.

  7. Modeling the dynamics of a tracer particle in an elastic active gel

    E-Print Network [OSTI]

    E. Ben Isaac; É. Fodor; P. Visco; F. van Wijland; N. S. Gov

    2015-07-03

    The internal dynamics of active gels, both in artificial (in-vitro) model systems and inside the cytoskeleton of living cells, has been extensively studied by experiments of recent years. These dynamics are probed using tracer particles embedded in the network of biopolymers together with molecular motors, and distinct non-thermal behavior is observed. We present a theoretical model of the dynamics of a trapped active particle, which allows us to quantify the deviations from equilibrium behavior, using both analytic and numerical calculations. We map the different regimes of dynamics in this system, and highlight the different manifestations of activity: breakdown of the virial theorem and equipartition, different elasticity-dependent "effective temperatures" and distinct non-Gaussian distributions. Our results shed light on puzzling observations in active gel experiments, and provide physical interpretation of existing observations, as well as predictions for future studies.

  8. Modeling the dynamics of a tracer particle in an elastic active gel

    E-Print Network [OSTI]

    Isaac, E Ben; Visco, P; van Wijland, F; Gov, N S

    2015-01-01

    The internal dynamics of active gels, both in artificial (in-vitro) model systems and inside the cytoskeleton of living cells, has been extensively studied by experiments of recent years. These dynamics are probed using tracer particles embedded in the network of biopolymers together with molecular motors, and distinct non-thermal behavior is observed. We present a theoretical model of the dynamics of a trapped active particle, which allows us to quantify the deviations from equilibrium behavior, using both analytic and numerical calculations. We map the different regimes of dynamics in this system, and highlight the different manifestations of activity: breakdown of the virial theorem and equipartition, different elasticity-dependent "effective temperatures" and distinct non-Gaussian distributions. Our results shed light on puzzling observations in active gel experiments, and provide physical interpretation of existing observations, as well as predictions for future studies.

  9. Passive tracer in a flow corresponding to a two dimensional stochastic Navier Stokes equations

    E-Print Network [OSTI]

    Tomasz Komorowski; Szymon Peszat; Tomasz Szarek

    2012-04-26

    In this paper we prove the law of large numbers and central limit theorem for trajectories of a particle carried by a two dimensional Eulerian velocity field. The field is given by a solution of a stochastic Navier--Stokes system with a non-degenerate noise. The spectral gap property, with respect to Wasserstein metric, for such a system has been shown in [9]. In the present paper we show that a similar property holds for the environment process corresponding to the Lagrangian observations of the velocity. In consequence we conclude the law of large numbers and the central limit theorem for the tracer. The proof of the central limit theorem relies on the martingale approximation of the trajectory process.

  10. Rocky Flats 1990--91 winter validation tracer study: Volume 1

    SciTech Connect (OSTI)

    Brown, K.J.

    1991-10-01

    During the winter of 1990--91, North American Weather Consultants (NAWC) and its subcontractor, ABB Environmental Services (ABBES), conducted a Winter Validation Study (WVS) for EG&G Rocky Flats involving 12 separate tracer experiments conducted between February 3 and February 19, 1991. Six experiments were conducted during nighttime hours and four experiments were conducted during daytime hours. In addition, there was one day/night and one night/day transitional experiment conducted. The primary purpose of the WVS was to gather data to further the approval process for the Terrain Responsive Atmospheric Code (TRAC). TRAC is an atmospheric dispersion model developed and operated at the Department of Energy`s (DOE`s) Rocky Flats Plant (RFP) north of Denver, Colorado. A secondary objective was to gather data that will serve to validate the TRAC model physics.

  11. Gas Drill 

    E-Print Network [OSTI]

    Unknown

    2011-09-05

    .C. Wang, B.T. Lovell, Program, Summary Report TE4258-5-84, J. McCrank, "Topping of a Combined Gas DOE/ET/11292, Oct. 1984. and Steam Turbine Powerplant using a TAM Combustor," Thermo Electron [4J Final Report: "Thermionic Energy Report No. 4258... for each Btu fired in the burners has been cal culated with the process gas temperature as a variable. It was shown [2 ] that the maximum thermionic power produced is 18 kW per million Btu fired per hour. All com bustors are similar but progressively...

  12. Thorium isotopes as tracers of particles dynamics and deep water circulation in the Indian sector of the

    E-Print Network [OSTI]

    Coppola, Laurent

    Thorium isotopes as tracers of particles dynamics and deep water circulation in the Indian sector to study the distribution of thorium isotopes (234 Th, 232 Th and 230 Th) in the water column of the Indian in surface water (0­100 m) and a model was applied to estimate a residence time relative to the thorium

  13. Isolating the role of mesoscale eddies in mixing of a passive tracer in an eddy resolving model

    E-Print Network [OSTI]

    Miami, University of

    Isolating the role of mesoscale eddies in mixing of a passive tracer in an eddy resolving model February 2008; published 16 May 2008. [1] This study examines the role of mesoscale eddies in distribution was replaced by a down-gradient diffusive parameterization. Our results demonstrate that advection by mesoscale

  14. AMMONIA AS A TRACER OF CHEMICAL EQUILIBRIUM IN THE T7.5 DWARF GLIESE 570D D. Saumon,1

    E-Print Network [OSTI]

    AMMONIA AS A TRACER OF CHEMICAL EQUILIBRIUM IN THE T7.5 DWARF GLIESE 570D D. Saumon,1 M. S. Marley March 15; accepted 2006 April 25 ABSTRACT We present the first analysis of an optical to mid order of magnitude from the value obtained with chemical-equilibrium models. We model departures from

  15. Biased swimming cells do not disperse in pipes as tracers: A population model based on microscale behaviour

    E-Print Network [OSTI]

    Bearon, Rachel

    mask Biomicrofluidics 5, 022204 (2011) Analytical solution on Magnus wind turbine power performanceBiased swimming cells do not disperse in pipes as tracers: A population model based on microscale: A population model based on microscale behaviour R. N. Bearon,1,a) M. A. Bees,2 and O. A. Croze3 1 Department

  16. Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique Iglesia*

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique unlabeled products from mixtures of propene and propane-2-13C reactants. Aromatic products of propane-2-13C-Parmer) that allowed differential reactor operation (propane reactions were

  17. May 1999 POV-Ray 3.1g User Documentation Page 1 Persistence of Vision TM Ray-Tracer

    E-Print Network [OSTI]

    Sherrill, David

    May 1999 POV-Ray 3.1g User Documentation Page 1 Persistence of Vision TM Ray-Tracer POV-Ray TM Version 3.1g User's Documentation May 1999 Copyright 1999 POV-Team TM POV-Ray TM is based on DKBTrace 2

  18. Gas hydrates: technology status report

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    The DOE Morgantown Energy Technology Center (METC) implemented a gas hydrates R and D program that emphasized an understanding of the resource through (1) an assessment of current technology, (2) the characterization of gas hydrate geology and reservoir engineering, and (3) the development of diagnostic tools and methods. Recovery of natural gas from gas hydrates will be made possible through (1) improved instrumentation and recovery methods, (2) developing the capability to predict production performance, and (3) field verification of recovery methods. Gas hydrates research has focused primarily on geology. As work progressed, areas where gas hydrates are likely to occur were identified, and specific high potential areas were targeted for detailed investigation. A Geologic Analysis System (GAS) was developed. GAS contains approximately 30 software packages and can manipulate and correlate several types of geologic and petroleum data into maps, graphics, and reports. The system also contains all well information currently available from the Alaskan North Slope area. Laboratory research on gas hydrates includes the characterization of the physical system, which focuses on creating synthetic methane hydrates and developing synthetic hydrate cores using tetrahydrofuran (THF), consolidated rock cores, frost base mixtures, water/ice-base mixtures, and water-base mixtures. Laboratory work produced measurements of the sonic velocity and electrical resistivity of these synthetic hydrates. During 1983, a sample from a natural hydrate core recovered from the Pacific coast of Guatemala was tested for these properties by DOE/METC. More recently, natural hydrate samples acquired from the Gulf of Mexico are being tested. Modeling and systems analysis work has focused on the development of GAS and preliminary gas hydrate production models. 23 refs., 18 figs., 6 tabs.

  19. AN INTEGRATED APPROACH TO CHARACTERIZING BYPASSED OIL IN HETEROGENEOUS AND FRACTURED RESERVOIRS USING PARTITIONING TRACERS

    SciTech Connect (OSTI)

    Akhil Datta-Gupta

    2004-08-01

    We explore the use of efficient streamline-based simulation approaches for modeling and analysis partitioning interwell tracer tests in heterogeneous and fractured hydrocarbon reservoirs. The streamline approach is generalized to model water injection in naturally fractured reservoirs through the use of a dual media approach. The fractures and matrix are treated as separate continua that are connected through a transfer function, as in conventional finite difference simulators for modeling fractured systems. A detailed comparison with a commercial finite difference simulator shows very good agreement. Furthermore, an examination of the scaling behavior of the computation time indicates that the streamline approach is likely to result in significant savings for large-scale field applications. We also propose a novel approach to history matching finite-difference models that combines the advantage of the streamline models with the versatility of finite-difference simulation. In our approach, we utilize the streamline-derived sensitivities to facilitate history matching during finite-difference simulation. The use of finite-difference model allows us to account for detailed process physics and compressibility effects. The approach is very fast and avoids much of the subjective judgments and time-consuming trial-and-errors associated with manual history matching. We demonstrate the power and utility of our approach using a synthetic example and two field examples. Finally, we discuss several alternative ways of using partitioning interwell tracer tests (PITTs) in oil fields for the calculation of oil saturation, swept pore volume and sweep efficiency, and assess the accuracy of such tests under a variety of reservoir conditions.

  20. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  1. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  2. NuclearHydrogen Oil and gas

    E-Print Network [OSTI]

    Birmingham, University of

    Policy NuclearHydrogen Transport Education Oil and gas Distribution Society Supply Ecology Demand Hydrogen 08 Policy and society 10 Environment 11 Transport 12 Manufacturing 14 Oil and gas 15 Nuclear 16 and infrastructure, and broaden our methods of generation. Our declining reserves of oil and gas must be repla

  3. Laser cross-flow gas system

    DOE Patents [OSTI]

    Duncan, D.B.

    1992-11-24

    A method and laser apparatus are disclosed which provide for a cross-flow of gas near one end of a laser discharge tube. The cross-flow of gas causes a concentration gradient which affects diffusion of contaminants in the discharge tube towards the cross-flow of the gas, which contaminants are then withdrawn from the discharge tube. 1 figure.

  4. NOx reduction methods and apparatuses

    DOE Patents [OSTI]

    Tonkyn, Russell G.; Barlow, Stephan E.; Balmer, M. Lou; Maupin, Gary D.

    2004-10-26

    A NO.sub.x reduction method includes treating a first gas containing NO.sub.x, producing a second gas containing NO.sub.2, reducing a portion of the NO.sub.2 in the second gas to N.sub.2, and producing a third gas containing less NO.sub.x than the first gas, substantially all of the third gas NO.sub.x being NO. The method also includes treating the third gas, producing a fourth gas containing NO.sub.2, reducing a portion of the NO.sub.2 in the fourth gas to N.sub.2, and producing a fifth gas containing less NO.sub.x than the third gas, substantially all of the fifth gas NO.sub.x being NO. Treating the first and/or third gas can include treatment with a plasma. Reducing a portion of the NO.sub.2 in the second and/or fourth gas can include reducing with a catalyst. The method can further include controlling energy consumption of the plasmas independent of each other.

  5. Gas turbine premixing systems

    DOE Patents [OSTI]

    Kraemer, Gilbert Otto; Varatharajan, Balachandar; Evulet, Andrei Tristan; Yilmaz, Ertan; Lacy, Benjamin Paul

    2013-12-31

    Methods and systems are provided for premixing combustion fuel and air within gas turbines. In one embodiment, a combustor includes an upstream mixing panel configured to direct compressed air and combustion fuel through premixing zone to form a fuel-air mixture. The combustor includes a downstream mixing panel configured to mix additional combustion fuel with the fule-air mixture to form a combustion mixture.

  6. Tracer Methods for Characterizing Fracture Creation in Enhanced Geothermal Systems; 2010 Geothermal Technology Program Peer Review Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaicsState ofSavings forTitle XVIIof EnergyofTotalSystemsTown

  7. Marine electromagnetic methods for gas hydrate characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen Andrea

    2008-01-01

    with Logging While Drilling (LWD) 7.3.3 Comparison with MTlogging while drilling (LWD) data from Ocean Drillingat depth as compared xvii to the LWD. An overlay of the CSEM

  8. Marine Electromagnetic Methods for Gas Hydrate Characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen A

    2008-01-01

    with Logging While Drilling (LWD) 7.3.3 Comparison with MTlogging while drilling (LWD) data from Ocean Drillingat depth as compared xvii to the LWD. An overlay of the CSEM

  9. Marine Electromagnetic Methods for Gas Hydrate Characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen A

    2008-01-01

    possible by funding from Exxon Mobil and GERD, Japan. I wishvery limited funding from Exxon Mobil and from GERD, Japan

  10. Marine electromagnetic methods for gas hydrate characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen Andrea

    2008-01-01

    possible by funding from Exxon Mobil and GERD, Japan. I wishvery limited funding from Exxon Mobil and from GERD, Japan

  11. Water-saving liquid-gas conditioning system

    DOE Patents [OSTI]

    Martin, Christopher; Zhuang, Ye

    2014-01-14

    A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

  12. Using CO2 Lidar for Standoff Detection of a Perfluorocarbon Tracer in Air

    SciTech Connect (OSTI)

    Heiser,J.H.; Smith, S.; Sedlacek, A.

    2008-02-06

    The Tag, Track and Location System Program (TTL) is investigating the use of PFTs as tracers for tagging and tracking items of interest or fallen soldiers. In order for the tagging and tracking to be valuable there must be a location system that can detect the PFTs. This report details the development of an infrared lidar platform for standoff detection of PFTs released into the air from a tagged object or person. Furthering work performed using a table top lidar system in an indoor environment; a mobile mini lidar platform was assembled using an existing Raman lidar platform, a grating tunable CO{sub 2} IR laser, Judson HgCdTe detector and miscellaneous folding optics and electronics. The lidar achieved {approx}200 ppb-m sensitivity in laboratory and indoor testing and was then successfully demonstrated at an outdoor test. The lidar system was able to detect PFTs released into a vehicle from a distance of 100 meters. In its final, fully optimized configuration the lidar was capable of repeatedly detecting PFTs in the air released from tagged vehicles. Responses were immediate and clear. This report details the results of a proof-of-concept demonstration for standoff detection of a perfluorocarbon tracer (PFT) using infrared lidar. The project is part of the Tag, Track and Location System Program and was performed under a contract with Tracer Detection Technology Corp. with funding from the Office of Naval Research. A lidar capable of detecting PFT releases at distance was assembled by modifying an existing Raman lidar platform by incorporating a grating tunable CO{sub 2} IR laser, Judson HgCdTe detector and miscellaneous folding optics and electronics. The lidar achieved {approx}200 ppb-m sensitivity in laboratory and indoor testing and was successfully demonstrated at an outdoor test. The demonstration test (scripted by the sponsor) consisted of three parked cars, two of which were tagged with the PFT. The cars were located 70 (closest) to 100 meters (farthest) from the lidar (the lidar beam path was limited by site constraints and was {approx}100 meters). When one door of each of the cars was opened (sequentially), the lidar was clearly able to determine which vehicles had been tagged and which one was not. The lidar is probably capable of greater than 0.5 kilometer standoff distances based on the extreme amount of signal return achieved (so much that the system had to be de-tuned). The BNL lidar system, while optimized to the extent possible with available parts and budget, was not as sensitive as it could be. Steps to improve the lidar are detailed in this report and include using a better laser system (for more stable power output), dual wavelengths (to improve the sensitivity and allow common mode noise reduction and to allow the use of the lidar in a scanning configuration), heterodyning (for range resolved PFT detection) and an off-axis optical configuration (for improved near field sensitivity).

  13. NATURAL GAS MARKET ASSESSMENT

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

  14. Natural Gas Applications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Applications. If you need assistance viewing this page, please call (202) 586-8800. Energy Information Administration Home Page Home > Natural Gas > Natural Gas Applications...

  15. ,"Natural Gas Consumption",,,"Natural Gas Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    Census Division, 1999" ,"Natural Gas Consumption",,,"Natural Gas Expenditures" ,"per Building (thousand cubic feet)","per Square Foot (cubic feet)","per Worker (thousand cubic...

  16. Natural Gas

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production,Energy Office

  17. Methods of making transportation fuel

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

    2012-04-10

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation. The alkylated hydrocarbons may be blended with one or more components to produce transportation fuel.

  18. Preliminary Interpretation of a Radionuclide and Colloid Tracer Test in a Granodiorite Shear Zone at the Grimsel Test Site, Switzerland

    SciTech Connect (OSTI)

    Reimus, Paul W.

    2012-08-30

    In February and March 2012, a tracer test involving the injection of a radionuclide-colloid cocktail was conducted in the MI shear zone at the Grimsel Test Site, Switzerland, as part of the Colloids Formation and Migration (CFM) project. The colloids were derived from FEBEX bentonite, which is mined in Spain and is being considered as a potential waste package backfill in a Spanish nuclear waste repository. The tracer test, designated test 12-02 (second test in 2012), involved the injection of the tracer cocktail into borehole CFM 06.002i2 and extraction from the Pinkel surface packer at the main access tunnel wall approximately 6.1 m from the injection interval. The test configuration is depicted in Figure 1. This configuration has been used in several conservative tracer tests and two colloid-homologue tracer tests since 2007, and it is will be employed in an upcoming test involving the emplacement of a radionuclide-doped bentonite plug into CFM 06.002i2 to evaluate the swelling and erosion of the bentonite and the transport of bentonite colloids and radionuclides from the source to the extraction point at the tunnel wall. Interpretive analyses of several of the previous tracer tests, from 09-01 through 12-02 were provided in two previous Used Fuel Disposition Program milestone reports (Arnold et al., 2011; Kersting et al., 2012). However, only the data for the conservative tracer Amino-G Acid was previously analyzed from test 12-02 because the other tracer data from this test were not available at the time. This report documents the first attempt to quantitatively analyze the radionuclide and colloid breakthrough curves from CFM test 12-02. This report was originally intended to also include an experimental assessment of colloid-facilitated transport of uranium by bentonite colloids in the Grimsel system, but this assessment was not conducted because it was reported by German collaborators at the Karlsruhe Institute of Technology (KIT) that neither uranium nor neptunium adsorbed appreciably to FEBEX bentonite colloids in Grimsel groundwater (Huber et al., 2011). The Grimsel groundwater has a relatively high pH of {approx}9, so the lack of uranium and neptunium adsorption to clay is not surprising given the tendency for these actinides to form very stable negative or neutrally-charged uranyl- or calcium-uranyl-carbonate complexes at these pH, particularly in a water that is effectively saturated with respect to calcite. It was also observed in testing conducted at LANL earlier in 2012 that uranium did not adsorb measurably to Grimsel granodiorite in a synthetic Grimsel groundwater at pH {approx}8.5 (Kersting et al., 2012). Thus, the planned experimental work was not pursued because all the available information clearly pointed to an expected result that uranium transport would not be facilitated by clay colloids in the Grimsel system.

  19. Reservoir characterization based on tracer response and rank analysis of production and injection rates

    SciTech Connect (OSTI)

    Refunjol, B.T.; Lake, L.W.

    1997-08-01

    Quantification of the spatial distribution of properties is important for many reservoir-engineering applications. But, before applying any reservoir-characterization technique, the type of problem to be tackled and the information available should be analyzed. This is important because difficulties arise in reservoirs where production records are the only information for analysis. This paper presents the results of a practical technique to determine preferential flow trends in a reservoir. The technique is a combination of reservoir geology, tracer data, and Spearman rank correlation coefficient analysis. The Spearman analysis, in particular, will prove to be important because it appears to be insightful and uses injection/production data that are prevalent in circumstances where other data are nonexistent. The technique is applied to the North Buck Draw field, Campbell County, Wyoming. This work provides guidelines to assess information about reservoir continuity in interwell regions from widely available measurements of production and injection rates at existing wells. The information gained from the application of this technique can contribute to both the daily reservoir management and the future design, control, and interpretation of subsequent projects in the reservoir, without the need for additional data.

  20. Georgia Tech Dangerous Gas

    E-Print Network [OSTI]

    Li, Mo

    1 Georgia Tech Dangerous Gas Safety Program March 2011 #12;Georgia Tech Dangerous Gas Safety.......................................................................................................... 5 6. DANGEROUS GAS USAGE REQUIREMENTS................................................. 7 6.1. RESTRICTED PURCHASE/ACQUISITION RULES: ................................................ 7 7. FLAMMABLE GAS