Sample records for trace gas concentration

  1. atmospheric trace gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: enrichments of 22.8 f 2.2 in the concentrations of Ir, SC and the rare earths relative to Cl chondrites of refractory trace metals from a gas of solar...

  2. ARM - Measurement - Trace gas concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat flux ARM Data Discovery

  3. Tracing Noble Gas Radionuclides in the Environment

    E-Print Network [OSTI]

    P. Collon; W. Kutschera; Z. -T. Lu

    2004-02-11T23:59:59.000Z

    Trace analysis of radionuclides is an essential and versatile tool in modern science and technology. Due to their ideal geophysical and geochemical properties, long-lived noble gas radionuclides, in particular, 39Ar (t1/2 = 269 yr), 81Kr (t1/2 = 2.3x10^5 yr) and 85Kr (t1/2 = 10.8 yr), have long been recognized to have a wide range of important applications in Earth sciences. In recent years, significant progress has been made in the development of practical analytical methods, and has led to applications of these isotopes in the hydrosphere (tracing the flow of groundwater and ocean water). In this article, we introduce the applications of these isotopes and review three leading analytical methods: Low-Level Counting (LLC), Accelerator Mass Spectrometry (AMS) and Atom Trap Trace Analysis (ATTA).

  4. Background Concentrations of Trace Metals in

    E-Print Network [OSTI]

    Ma, Lena

    of Florida State University System of Florida FLORIDA CENTER FOR SOLID AND HAZARDOUS WASTE MANAGEMENT 2207 NW for evaluating land application of non-hazardous waste materials and monitoring the mobility of trace metals from 8,000 archived samples. l To validate the sampling protocol used by the Florida Cooperative Soil

  5. Prediction of rainwater acidity using trace element concentrations

    SciTech Connect (OSTI)

    Vong, R.J.; Peterson, R.E. (Univ. of Washington, Seattle (USA))

    1988-09-01T23:59:59.000Z

    It is of interest to be able to estimate the contribution of an anthropogenic emission source to downwind rainwater chemistry. The authors here consider the closure of a large copper smelter which operated in a region where background and other emission sources should contribute smaller amounts of atmospheric sulfur than the smelter. An additional simplification existed in that meteorology associated with rain was relatively well known and consistent. A field experiment was conducted in the winters of 1985 and 1986 to collect rainwater at sites upwind and downwind of the Tacoma, Washington smelter. The smelters SO{sub 2} emissions, their conversion to SO{sub 4}= via three oxidants (O{sub 3}, H{sub 2}O{sub 2}, and O{sub 2} - Fe catalyzed reactions), diffusion, transport, and aerosol/gas scavenging previously have been estimated while adjusting model parameters until the predictions fit the rainwater data. To take advantage of the unique experimental design afforded by the closure of the smelter, statistical analysis was performed on NO{sub 3}-, SO{sub 4}(xs)= (excess of seasalt), and pH data; analysis of variance (ANOVA) confirmed that the smelter had a significant (p < .01) influence on rainwater pH and SO{sub 4}(xs). The analysis presented here extends the ANOVA by applying a multivariate regression technique to new data for trace element concentrations for the same rain samples. To predict rainwater acidity, they derive fingerprints from trace element data, identify a source or process related to that fingerprint, and compare the predicted contributions for pre- and post- closure samples.

  6. Project AIRSTREAM: Trace gas final report

    SciTech Connect (OSTI)

    Leifer, R.

    1992-12-01T23:59:59.000Z

    The results of 10 years of sampling for trace gases in the upper troposphere and lower stratosphere are presented. These samples were collected under the auspices of the Atomic Energy Commission (AEC), the Energy Research and Development Administration (ERDA) and the Department of Energy (DOE). Almost 1000 whole air samples were collected during the years 1973 to 1983 under Project AIRSTREAM. Project AIRSTREAM was part of the Environmental Measurements Laboratory's (EML, at that time called the Health and Safety Laboratory/HASL) research effort to investigate the impact of the injection of radionuclides and stable compounds into the stratosphere. One or more of the following compounds were analyzed: CCl[sub 3]F, CCl[sub 2]F[sub 2], CCl[sub 4], N[sub 2]O, SF[sub 6], CO[sub 2], CH[sub 4], CH[sub 3]CCl[sub 3], and COS. Details of the Project's quality assurance program are discussed. Also included in the report are two-dimensional plots of the concentration of CCl[sub 3]F and a complete tabulation of the data.

  7. Project AIRSTREAM: Trace gas final report

    SciTech Connect (OSTI)

    Leifer, R.

    1992-12-01T23:59:59.000Z

    The results of 10 years of sampling for trace gases in the upper troposphere and lower stratosphere are presented. These samples were collected under the auspices of the Atomic Energy Commission (AEC), the Energy Research and Development Administration (ERDA) and the Department of Energy (DOE). Almost 1000 whole air samples were collected during the years 1973 to 1983 under Project AIRSTREAM. Project AIRSTREAM was part of the Environmental Measurements Laboratory`s (EML, at that time called the Health and Safety Laboratory/HASL) research effort to investigate the impact of the injection of radionuclides and stable compounds into the stratosphere. One or more of the following compounds were analyzed: CCl{sub 3}F, CCl{sub 2}F{sub 2}, CCl{sub 4}, N{sub 2}O, SF{sub 6}, CO{sub 2}, CH{sub 4}, CH{sub 3}CCl{sub 3}, and COS. Details of the Project`s quality assurance program are discussed. Also included in the report are two-dimensional plots of the concentration of CCl{sub 3}F and a complete tabulation of the data.

  8. Solar limb darkening and ray trace evaluation of solar concentrators

    SciTech Connect (OSTI)

    Negi, B.S.; Bhowmik, N.C.; Mathur, S.S.; Kandpal, T.C.

    1985-01-15T23:59:59.000Z

    A comparison of different correlations commonly used to describe the limb darkening effect is made. A somewhat new correlation is proposed which predicts the values to within +- 1.5% of the experimental values. Using a conventional ray trace technique and assigning proper weight factors to each ray, the distribution of the local concentration ratio over a flat absorber placed in the focal plane of a cylindrical parabolic trough is also determined.

  9. Gas concentration cells for utilizing energy

    DOE Patents [OSTI]

    Salomon, R.E.

    1987-06-30T23:59:59.000Z

    An apparatus and method are disclosed for utilizing energy, in which the apparatus may be used for generating electricity or as a heat pump. When used as an electrical generator, two gas concentration cells are connected in a closed gas circuit. The first gas concentration cell is heated and generates electricity. The second gas concentration cell repressurizes the gas which travels between the cells. The electrical energy which is generated by the first cell drives the second cell as well as an electrical load. When used as a heat pump, two gas concentration cells are connected in a closed gas circuit. The first cell is supplied with electrical energy from a direct current source and releases heat. The second cell absorbs heat. The apparatus has no moving parts and thus approximates a heat engine. 4 figs.

  10. Gas concentration cells for utilizing energy

    DOE Patents [OSTI]

    Salomon, Robert E. (Philadelphia, PA)

    1987-01-01T23:59:59.000Z

    An apparatus and method for utilizing energy, in which the apparatus may be used for generating electricity or as a heat pump. When used as an electrical generator, two gas concentration cells are connected in a closed gas circuit. The first gas concentration cell is heated and generates electricity. The second gas concentration cell repressurizes the gas which travels between the cells. The electrical energy which is generated by the first cell drives the second cell as well as an electrical load. When used as a heat pump, two gas concentration cells are connected in a closed gas circuit. The first cell is supplied with electrical energy from a direct current source and releases heat. The second cell absorbs heat. The apparatus has no moving parts and thus approximates a heat engine.

  11. Gas Source Tracing With a Mobile Robot Using an Adapted Moth Strategy

    E-Print Network [OSTI]

    Zell, Andreas

    Gas Source Tracing With a Mobile Robot Using an Adapted Moth Strategy Achim Lilienthal, Denis,reiman,zell}@informatik.uni-tuebingen.de Abstract. As a sub-task of the general gas source localisation problem, gas source tracing is supposed to guide a gas-sensitive mobile system towards a source by using the cues determined from the gas

  12. Wide range radioactive gas concentration detector

    DOE Patents [OSTI]

    Anderson, David F. (Los Alamos, NM)

    1984-01-01T23:59:59.000Z

    A wide range radioactive gas concentration detector and monitor which is capable of measuring radioactive gas concentrations over a range of eight orders of magnitude. The device of the present invention is designed to have an ionization chamber which is sufficiently small to give a fast response time for measuring radioactive gases but sufficiently large to provide accurate readings at low concentration levels. Closely spaced parallel plate grids provide a uniform electric field in the active region to improve the accuracy of measurements and reduce ion migration time so as to virtually eliminate errors due to ion recombination. The parallel plate grids are fabricated with a minimal surface area to reduce the effects of contamination resulting from absorption of contaminating materials on the surface of the grids. Additionally, the ionization chamber wall is spaced a sufficient distance from the active region of the ionization chamber to minimize contamination effects.

  13. Elevated Trace Element Concentrations in Southern Toads, Bufo terrestris, Exposed to Coal Combustion Waste

    E-Print Network [OSTI]

    Hopkins, William A.

    Elevated Trace Element Concentrations in Southern Toads, Bufo terrestris, Exposed to Coal, and behavioral abnormalities in amphibians to coal combustion wastes (coal ash). Few studies, however, have determined trace element concentrations in amphibians exposed to coal ash. In the current study we compare

  14. Role of trace impurities in large-volume noble gas atmospheric-pressure glow discharges

    E-Print Network [OSTI]

    Raja, Laxminarayan L.

    Role of trace impurities in large-volume noble gas atmospheric-pressure glow discharges Xiaohui. Large-volume APG discharges find numerous applications in processing of material surfaces,1 ozone-purity helium is presented, and the role of trace impurities in such noble gas plasmas is established. Trace

  15. High concentrations of trace metals in oysters from the Patuxent River, Maryland

    SciTech Connect (OSTI)

    Riedel, G.; Sanders, J.; Abbe, G. [Academy of Natural Sciences, St. Leonard, MD (United States). Benedict Estuarine Research Center

    1995-12-31T23:59:59.000Z

    Oyster (Crassostrea virginica) populations from the Patuxent River have been analyzed for trace metals by a number of organizations over at least the past 19 years. During that period, high concentrations of Cu (200--500 {micro}g/g dry weight), Cd (3--7 {micro}g/g) and Ag (2--8 /{micro}g/g) have been found in oysters from the oyster bars furthest up river. In particular, Cd values in oysters from this region have had concentrations approaching or exceeding current FDA warning levels throughout the period. In previous studies it was suggested that a coal-burning power plant located in that region, Chalk Point Steam Electric Station, was responsible for the copper enrichment due to the corrosion of Cu/Ni alloy condenser tubes. However, a monthly survey of trace elements in the nearby oyster populations from 1986 to the present showed only a small decline in copper concentrations after the plant switched from Cu/Ni to Ti alloy condenser tubes in 1987. Other potential sources for trace metals in the region include municipal and industrial discharges, atmospheric deposition, and biocides (anti-fouling paint in particular). The very rapid rise in trace element concentrations in oysters with position up river, and the lack of such a response by another local bivalve, the hooked mussel (Ischadium recurvum), suggests that a physiological effect of low salinity stress on oysters may be in part responsible for the high concentrations of trace metals in oysters in this region.

  16. "Trace Analysis of Speciality and Electronic Gases," Chapter 4, "Emerging Infrared Laser Absorption Spectroscopic Techniques for Gas Analysis"

    SciTech Connect (OSTI)

    Lascola, R.; McWhorter, S.; Tittel, F.; Lewicki, R.

    2013-07-01T23:59:59.000Z

    This chapter covers Laser Absorption Spectroscopic Techniques and Applications of Semiconductor LAS Based Trace Gas Sensor Systems.

  17. Measurements of trace element concentration profiles across the diameter of human hair with micro-pixe

    SciTech Connect (OSTI)

    Bos, A.J.J.; C.C.A.H.v.d. Stap.; Lenglet, W.J.M.; Valkovic, V.; Vis, R.D.

    1983-04-01T23:59:59.000Z

    Trace element distributions across single human hairs using a proton microbeam has been measured to study the origin of these elements in hair. A new way of concentration assignment for micro PIXE making use of both the Proton Induced characteristic X-rays and the Rutherford Backscattered protons is reported.

  18. Room-temperature mid-infrared laser sensor for trace gas detection

    E-Print Network [OSTI]

    , and pipeline leak detection. Applications such as landfill emissions monitoring require measurements of gasRoom-temperature mid-infrared laser sensor for trace gas detection Thomas To¨ pfer, Konstantin P of a compact, portable, room-temperature mid-infrared gas sensor is reported. The sensor is based on continuous

  19. Trace element chemistry of coal bed natural gas produced water in the Powder River Basin, Wyoming

    SciTech Connect (OSTI)

    Richard E. Jackson; K.J. Reddy [University of Wyoming, Laramie, WY (United States). Department of Renewable Resources

    2007-09-15T23:59:59.000Z

    Coal bed natural gas (CBNG) produced water is usually disposed into nearby constructed disposal ponds. Geochemistry of produced water, particularly trace elements interacting with a semiarid environment, is not clearly understood. The objective of this study was to collect produced water samples at outfalls and corresponding disposal ponds and monitor pH, iron (Fe), aluminum (Al), chromium (Cr), manganese (Mn), lead (Pb), copper (Cu), zinc (Zn), arsenic (As), boron (B), selenium (Se), molybdenum (Mo), cadmium (Cd), and barium (Ba). Outfalls and corresponding disposal ponds were sampled from five different watersheds including Cheyenne River (CHR), Belle Fourche River (BFR), Little Powder River (LPR), Powder River (PR), and Tongue River (TR) within the Powder River Basin (PRB), Wyoming from 2003 to 2005. Paired tests were conducted between CBNG outfalls and corresponding disposal ponds for each watershed. Results suggest that produced water from CBNG outfalls is chemically different from the produced water from corresponding disposal ponds. Most trace metal concentrations in the produced water increased from outfall to disposal pond except for Ba. In disposal ponds, Ba, As, and B concentrations increased from 2003 to 2005. Geochemical modeling predicted precipitation and dissolution reactions as controlling processes for Al, Cu, and Ba concentrations in CBNG produced water. Adsorption and desorption reactions appear to control As, Mo, and B concentrations in CBNG water in disposal ponds. Overall, results of this study will be important to determine beneficial uses (e.g., irrigation, livestock/wildlife water, and aquatic life) for CBNG produced water in the PRB, Wyoming. 18 refs., 4 figs., 3 tabs.

  20. What does stabilizing greenhouse gas concentrations mean?

    E-Print Network [OSTI]

    Jacoby, Henry D.; Schmalensee, Richard.; Reiner, David M.

    The MIT Emissions Prediction and Policy Analysis (EPPA) model is applied to an exploration of the national emissions obligations that would be required to stabilize atmospheric CO2 concentrations at levels now under active ...

  1. Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power

    E-Print Network [OSTI]

    . A facility with solar fraction less than 1 is a hybrid operating plant that combusts naturLife Cycle Greenhouse Gas Emissions from Concentrating Solar Power Over the last thirty years, more-scale concentrating solar power (CSP) systems. These LCAs have yielded wide-ranging results. Variation could

  2. Oil and gas exploration system and method for detecting trace amounts of hydrocarbon gases in the atmosphere

    DOE Patents [OSTI]

    Wamsley, Paula R. (Littleton, CO); Weimer, Carl S. (Littleton, CO); Nelson, Loren D. (Evergreen, CO); O'Brien, Martin J. (Pine, CO)

    2003-01-01T23:59:59.000Z

    An oil and gas exploration system and method for land and airborne operations, the system and method used for locating subsurface hydrocarbon deposits based upon a remote detection of trace amounts of gases in the atmosphere. The detection of one or more target gases in the atmosphere is used to indicate a possible subsurface oil and gas deposit. By mapping a plurality of gas targets over a selected survey area, the survey area can be analyzed for measurable concentration anomalies. The anomalies are interpreted along with other exploration data to evaluate the value of an underground deposit. The system includes a differential absorption lidar (DIAL) system with a spectroscopic grade laser light and a light detector. The laser light is continuously tunable in a mid-infrared range, 2 to 5 micrometers, for choosing appropriate wavelengths to measure different gases and avoid absorption bands of interference gases. The laser light has sufficient optical energy to measure atmospheric concentrations of a gas over a path as long as a mile and greater. The detection of the gas is based on optical absorption measurements at specific wavelengths in the open atmosphere. Light that is detected using the light detector contains an absorption signature acquired as the light travels through the atmosphere from the laser source and back to the light detector. The absorption signature of each gas is processed and then analyzed to determine if a potential anomaly exists.

  3. Validation of a Model of a Resonant Optothermoacoustic Trace Gas Sensor

    E-Print Network [OSTI]

    Minkoff, Susan E.

    Validation of a Model of a Resonant Optothermoacoustic Trace Gas Sensor N. Petra1, J. Zweck1, S. E optothermoacoustic sensor is validated by comparison with experiments performed with 0.5% acetylene in nitrogen Optical Society of America OCIS codes: 300.6430, 300.6340. 1. Introduction Quartz-Enhanced Photo

  4. Laser Spectroscopic Trace-Gas Sensor Networks for Atmospheric Monitoring Applications

    E-Print Network [OSTI]

    Zhong, Lin

    a laser based chemical sensing technology with wide-area autonomous wireless sensor networking@princeton.edu ABSTRACT Laser-based atmospheric trace-gas sensors have great potential for long-term, real such as CO2, NOx, and methane with exceptionally high specificity. Categories and Subject Descriptors C.3

  5. Evolution of the geothermal fluids at Los Azufres, Mexico, as traced by noble gas isotopes, 18

    E-Print Network [OSTI]

    Long, Bernard

    following over 25 years of geothermal fluid exploitation. Mantle helium dominates in fluids from the north field has been extensively studied in the past 30 years for its geological and tectonic features (DobsonEvolution of the geothermal fluids at Los Azufres, Mexico, as traced by noble gas isotopes, 18 O, D

  6. Batch methods for enriching trace impurities in hydrogen gas for their further analysis

    DOE Patents [OSTI]

    Ahmed, Shabbir; Lee, Sheldon H.D.; Kumar, Romesh; Papdias, Dionissios D.

    2014-07-15T23:59:59.000Z

    Provided herein are batch methods and devices for enriching trace quantities of impurities in gaseous mixtures, such as hydrogen fuel. The methods and devices rely on concentrating impurities using hydrogen transport membranes wherein the time period for concentrating the sample is calculated on the basis of optimized membrane characteristics, comprising its thickness and permeance, with optimization of temperature, and wherein the enrichment of trace impurities is proportional to the pressure ratio P.sub.hi/P.sub.lo and the volume ratio V.sub.1/V.sub.2, with following detection of the impurities using commonly-available detection methods.

  7. Wide-range radioactive-gas-concentration detector

    DOE Patents [OSTI]

    Anderson, D.F.

    1981-11-16T23:59:59.000Z

    A wide-range radioactive-gas-concentration detector and monitor capable of measuring radioactive-gas concentrations over a range of eight orders of magnitude is described. The device is designed to have an ionization chamber sufficiently small to give a fast response time for measuring radioactive gases but sufficiently large to provide accurate readings at low concentration levels. Closely spaced parallel-plate grids provide a uniform electric field in the active region to improve the accuracy of measurements and reduce ion migration time so as to virtually eliminate errors due to ion recombination. The parallel-plate grids are fabricated with a minimal surface area to reduce the effects of contamination resulting from absorption of contaminating materials on the surface of the grids. Additionally, the ionization-chamber wall is spaced a sufficient distance from the active region of the ionization chamber to minimize contamination effects.

  8. Tracing high density gas in M 82 and NGC 4038

    E-Print Network [OSTI]

    E. Bayet; C. Lintott; S. Viti; J. Martín-Pintado; S. Martín; D. A. Williams; J. M. C. Rawlings

    2008-08-20T23:59:59.000Z

    We present the first detection of CS in the Antennae galaxies towards the NGC 4038 nucleus, as well as the first detections of two high-J (5-4 and 7-6) CS lines in the center of M 82. The CS(7-6) line in M 82 shows a profile that is surprisingly different to those of other low-J CS transitions we observed. This implies the presence of a separate, denser and warmer molecular gas component. The derived physical properties and the likely location of the CS(7-6) emission suggests an association with the supershell in the centre of M 82.

  9. Measurement of Trace I-129 Concentrations in CsI Powder and Organic Liquid Scintillator with Accelerator Mass Spectrometry

    E-Print Network [OSTI]

    K. J. Dong

    2005-12-01T23:59:59.000Z

    Levels of trace radiopurity in active detector materials is a subject of major concern in low-background experiments. Procedures were devised to measure trace concentrations of I-129 in the inorganic salt CsI as well as in organic liquid scintillator with Accelerator Mass Spectrometry (AMS) which leads to improvement in sensitivities by several orders of magnitude over other methods. No evidence of their existence in these materials were observed. Limits of scintillator, respectively, were derived.These are the first results in a research program whose goals are to develop techniques to measure trace radioactivity in detector materials by AMS.

  10. Measurement of Trace $^{129}I$ Concentrations in CsI Powder and Organic Liquid Scintillator with Accelerator Mass Spectrometry

    E-Print Network [OSTI]

    Dong, K J

    2007-01-01T23:59:59.000Z

    Levels of trace radiopurity in active detector materials is a subject of major concern in low-background experiments. Procedures were devised to measure trace concentrations of I-129 in the inorganic salt CsI as well as in organic liquid scintillator with Accelerator Mass Spectrometry (AMS) which leads to improvement in sensitivities by several orders of magnitude over other methods. No evidence of their existence in these materials were observed. Limits of scintillator, respectively, were derived.These are the first results in a research program whose goals are to develop techniques to measure trace radioactivity in detector materials by AMS.

  11. Electrochemical separation and concentration of hydrogen sulfide from gas mixtures

    DOE Patents [OSTI]

    Winnick, Jack (Atlanta, GA); Sather, Norman F. (Naperville, IL); Huang, Hann S. (Darian, IL)

    1984-10-30T23:59:59.000Z

    A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4 -- or, in the case of H.sub.2 S, to S--. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

  12. Gas Source Localisation by Constructing Concentration Gridmaps with a Mobile Robot

    E-Print Network [OSTI]

    Duckett, Tom

    Gas Source Localisation by Constructing Concentration Gridmaps with a Mobile Robot Achim Lilienthal of a gas distribution by creating concentration gridmaps with a mobile robot equipped with a gas-sensitive system ("mobile nose"). By contrast to metric gridmaps extracted from sonar or laser range scans, a gas

  13. Trace Gas Emissions Data from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, and models and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Collections under the broad heading of Trace Gas Emissions are organized as Fossil-Fuel CO2 Emissions, Land-Use CO2 Emissions, Soil CO2 Emissions, and Methane.

  14. Effective destruction of CO by cosmic rays: implications for tracing H$_2$ gas in the Universe

    E-Print Network [OSTI]

    Bisbas, Thomas G; Viti, Serena

    2015-01-01T23:59:59.000Z

    We report on the effects of cosmic rays (CRs) on the abundance of CO in $\\rm H_2$ clouds under conditions typical for star-forming galaxies in the Universe. We discover that this most important molecule for tracing H$_2$ gas is very effectively destroyed in ISM environments with CR energy densities $\\rm U_{CR}\\sim(50-10^{3})\\times U_{CR,Gal}$, a range expected in numerous star-forming systems throughout the Universe. This density-dependent effect operates volumetrically rather than only on molecular cloud surfaces (i.e. unlike FUV radiation that also destroys CO), and is facilitated by: a) the direct destruction of CO by CRs, and b) a reaction channel activated by CR-produced He$^{+}$. The effect we uncover is strong enough to render Milky-Way type Giant Molecular Clouds (GMCs) very CO-poor (and thus CO-untraceable), even in ISM environments with rather modestly enhanced average CR energy densities of $\\rm U_{CR}\\sim(10-50)\\times\\rm U_{CR,Gal}$. We conclude that the CR-induced destruction of CO in molecular c...

  15. Reducing PM Concentrations in Simulated High Temperature Gas Streams

    E-Print Network [OSTI]

    Luehrs, Daniel R

    2014-08-07T23:59:59.000Z

    the reaction temperatures and capture the energy in the biomass. CGT has an approximant 16,300 kJ/kg (7,000 Btu/lb) of energy. The resulting synthetic gas (syngas) can have an energy content as high as 7,450 kJ/m^(3) (200 Btu/dscf) and can be fed directly...

  16. Adsorption process to recover hydrogen from feed gas mixtures having low hydrogen concentration

    DOE Patents [OSTI]

    Golden, Timothy Christopher; Weist, Jr., Edward Landis; Hufton, Jeffrey Raymond; Novosat, Paul Anthony

    2010-04-13T23:59:59.000Z

    A process for selectively separating hydrogen from at least one more strongly adsorbable component in a plurality of adsorption beds to produce a hydrogen-rich product gas from a low hydrogen concentration feed with a high recovery rate. Each of the plurality of adsorption beds subjected to a repetitive cycle. The process comprises an adsorption step for producing the hydrogen-rich product from a feed gas mixture comprising 5% to 50% hydrogen, at least two pressure equalization by void space gas withdrawal steps, a provide purge step resulting in a first pressure decrease, a blowdown step resulting in a second pressure decrease, a purge step, at least two pressure equalization by void space gas introduction steps, and a repressurization step. The second pressure decrease is at least 2 times greater than the first pressure decrease.

  17. Position for determining gas-phase volatile organic compound concentrations in transuranic waste containers. Revision 2

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States). Idaho National Engineering and Environmental Lab.] [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States). Idaho National Engineering and Environmental Lab.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R. [Benchmark Environmental Corp. (United States)] [Benchmark Environmental Corp. (United States)

    1998-06-01T23:59:59.000Z

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  18. Position for determining gas phase volatile organic compound concentrations in transuranic waste containers. Revision 1

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States); Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R. [Benchmark Environmental Corp., Albuquerque, NM (United States)

    1995-08-01T23:59:59.000Z

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering Laboratory (INEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  19. Flow injection trace gas analysis method for on-site determination of organoarsenicals

    DOE Patents [OSTI]

    Aldstadt, III, Joseph H. (Orland Park, IL)

    1997-01-01T23:59:59.000Z

    A method for real-time determination of the concentration of Lewisite in the ambient atmosphere, the method includes separating and collecting a Lewisite sample from the atmosphere in a collection chamber, converting the collected Lewisite to an arsenite ion solution sample, pumping the arsenite ion containing sample to an electrochemical detector connected to the collection chamber, and electrochemically detecting the converted arsenite ions in the sample, whereby the concentration of arsenite ions detected is proportional to the concentration of Lewisite in the atmosphere.

  20. Flow injection trace gas analysis method for on-site determination of organoarsenicals

    DOE Patents [OSTI]

    Aldstadt, J.H. III

    1997-06-24T23:59:59.000Z

    A method is described for real-time determination of the concentration of Lewisite in the ambient atmosphere, the method includes separating and collecting a Lewisite sample from the atmosphere in a collection chamber, converting the collected Lewisite to an arsenite ion solution sample, pumping the arsenite ion containing sample to an electrochemical detector connected to the collection chamber, and electrochemically detecting the converted arsenite ions in the sample, whereby the concentration of arsenite ions detected is proportional to the concentration of Lewisite in the atmosphere. 2 figs.

  1. Investigation of trace amounts of gas on microvave water-cut measurement

    E-Print Network [OSTI]

    Liu, Jin

    2006-08-16T23:59:59.000Z

    In recent years, the upstream oil and gas industry has dealt with some of the most challenging metering applications. One of these is the measurement of water percentage at the point of allocation. It is an essential requirement when test separators...

  2. Electrochemical separation and concentration of sulfur containing gases from gas mixtures

    DOE Patents [OSTI]

    Winnick, Jack (3805 Woodrail-on-the-Green, Columbia, MO 65201)

    1981-01-01T23:59:59.000Z

    A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4.sup.= or, in the case of H.sub.2 S, to S.sup.=. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

  3. Control of Gas Tungsten Arc welding pool shape by trace element addition to the weld pool

    DOE Patents [OSTI]

    Heiple, C.R.; Burgardt, P.

    1984-03-13T23:59:59.000Z

    An improved process for Gas Tungsten Arc welding maximizes the depth/width ratio of the weld pool by adding a sufficient amount of a surface active element to insure inward fluid flow, resulting in deep, narrow welds. The process is especially useful to eliminate variable weld penetration and shape in GTA welding of steels and stainless steels, particularly by using a sulfur-doped weld wire in a cold wire feed technique.

  4. Quantifying Climate Feedbacks from Abrupt Changes in High-Latitude Trace-Gas Emissions

    SciTech Connect (OSTI)

    Schlosser, Courtney Adam [MIT; Walter-Anthony, Katey [University of Alaska; Zhuang, Qianlai [Purdue University; Melillo, Jerry [Marine Biological Laboratory

    2013-04-26T23:59:59.000Z

    Our overall goal was to quantify the potential for threshold changes in natural emission rates of trace gases, particularly methane and carbon dioxide, from pan-arctic terrestrial systems under the spectrum of anthropogenically forced climate warming, and the extent to which these emissions provide a strong feedback mechanism to global climate warming. This goal is motivated under the premise that polar amplification of global climate warming will induce widespread thaw and degradation of the permafrost, and would thus cause substantial changes in the extent of wetlands and lakes, especially thermokarst (thaw) lakes, over the Arctic. Through a coordinated effort of field measurements, model development, and numerical experimentation with an integrated assessment model framework, we have investigated the following hypothesis: There exists a climate-warming threshold beyond which permafrost degradation becomes widespread and thus instigates strong and/or sharp increases in methane emissions (via thermokarst lakes and wetland expansion). These would outweigh any increased uptake of carbon (e.g. from peatlands) and would result in a strong, positive feedback to global climate warming.

  5. Tunable photonic cavities for in-situ spectroscopic trace gas detection

    DOE Patents [OSTI]

    Bond, Tiziana; Cole, Garrett; Goddard, Lynford

    2012-11-13T23:59:59.000Z

    Compact tunable optical cavities are provided for in-situ NIR spectroscopy. MEMS-tunable VCSEL platforms represents a solid foundation for a new class of compact, sensitive and fiber compatible sensors for fieldable, real-time, multiplexed gas detection systems. Detection limits for gases with NIR cross-sections such as O.sub.2, CH.sub.4, CO.sub.x and NO.sub.x have been predicted to approximately span from 10.sup.ths to 10s of parts per million. Exemplary oxygen detection design and a process for 760 nm continuously tunable VCSELS is provided. This technology enables in-situ self-calibrating platforms with adaptive monitoring by exploiting Photonic FPGAs.

  6. Quantifying Climate Feedbacks from Abrupt Changes in High-Latitude Trace-Gas Emissions

    SciTech Connect (OSTI)

    Qianlai Zhuang

    2012-11-16T23:59:59.000Z

    During the three-year project period, Purdue University has specifically accomplished the following: revised the existing Methane Dynamics Model (MDM) to consider the effects of changes of atmospheric pressure; applied the methane dynamics model (MDM) to Siberian region to demonstrate that ebullition estimates could increase previous estimates of regional terrestrial CH{sub 4} emissions 3- to 7-fold in Siberia; Conducted an analysis of the carbon balance of the Arctic Basin from 1997 to 2006 to show that terrestrial areas of the Arctic were a net source of 41.5 Tg CH{sub 4} yr{sup â??1} that increased by 0.6 Tg CH{sub 4} yr{sup â??1} during the decade of analysis, a magnitude that is comparable with an atmospheric inversion of CH{sub 4}; improved the quantification of CH{sub 4} fluxes in the Arctic with inversion methods; evaluated AIRS CH4 retrieval data with a transport and inversion model and surface flux and aircraft data; to better quantify methane emissions from wetlands, we extended the MDM within a biogeochemistry model, the Terrestrial Ecosystem Model (TEM), to include a large-scale hydrology model, the variable infiltration capacity (VIC) model; more recently, we developed a single box atmospheric chemistry model involving atmospheric methane (CH{sub 4}), carbon monoxide (CO) and radical hydroxyl (OH) to analyze atmospheric CH{sub 4} concentrations from 1984 to 2008.

  7. Final Report - Gas Retention and Release Tests Supporting the Concentrate Receipt Vessel (CRV-VSL-00002A/2B) Configuration

    SciTech Connect (OSTI)

    GUERRERO, HECTOR

    2004-09-01T23:59:59.000Z

    Gas Retention and Release (GR and R) tests were performed in the scaled Concentrate Receipt Vessel (CRV) Test Stand at the Savannah River National Laboratory to validate the capability of candidate Hybrid-Mixing systems for the CRV to safely release hydrogen during normal and upset conditions. Hydrogen is generated in the radioactive waste as a result of natural and plant processes and must not be allowed to accumulate above flammability limits. Two types of tests were conducted. Gas holdup tests determined the steady state amount of gas accumulated in the simulant under normal PJM only or PJM plus sparging conditions. Gas release tests determined what operating conditions are necessary to fully release gas after a steady state gas fraction of 4 per cent tank volume or more was reached in the simulant.

  8. Bubble columns for condensation at high concentrations of noncondensable gas: Heat-transfer model and experiments

    E-Print Network [OSTI]

    Narayan, G. Prakash

    Carrier gas based thermodynamic cycles are common in water desalination applications. These cycles often require condensation of water vapor out of the carrier gas stream. As the carrier gas is most likely a noncondensable ...

  9. Laboratory scale studies of Pd/y-Al2O3 sorbents for the removal of trace contaminents from coal-derived fuel gas at elevated temperatures

    SciTech Connect (OSTI)

    Rupp, Erik C.; Granite, Evan J.; Stanko, Dennis C.

    2010-12-31T23:59:59.000Z

    The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150-540 C) to hot (>540 C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/{gamma}-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

  10. Effect of low and high storage temperatures on head space gas concentrations and physical properties of wood pellets

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; Shahab Sokhansanj; C. Jim Lim; Tony Bi; Xingya Kuang; Staffan Melin

    2013-11-01T23:59:59.000Z

    Headspace gas concentrations and wood pellet properties were studied in sealed glass canisters at 5–40 degrees C storage temperatures. CO2 and CO concentrations at 5, 10, 20 and 40 degrees C at the end of 23–28 days of storage were 1600 and 200, 4700 and 1200, and 31 200 and 15 800 parts per million by volume (ppmv) respectively. Corresponding O2 concentration was about 19•49, 19•20, 18•0 and 2•07% respectively. Non-linear regression equations adequately described the gas concentrations in the storage container as a function of time. Safe level estimation functions developed were linear for O2 and logarithmic for CO and CO2 concentrations. Measured pellet properties moisture, length, diameter, unit, bulk and tapped density, durability, calorific value, ash content and per cent fines were in the range of 4•6–5•02%, 14–15 mm, 6•4–6•5 mm, 1125–1175 kg m-3, 750–770 kg m-3, 825–840 kg m-3, 73–74%, 18•32–18•78 MJ kg-1, 0•65–0•74% and 0•13–0•15%. Durability values of pellets decreased by 13% at 40 degrees C storage temperature and other properties changed marginally.

  11. Improved gas sensing and dielectric properties of Fe doped hydroxyapatite thick films: Effect of molar concentrations

    SciTech Connect (OSTI)

    Mene, Ravindra U. [PDEA's, Annasaheb Waghire College of Science, Arts and Commerce, Otur 412409, M.S. (India); School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431606, M.S. (India); Mahabole, Megha P. [School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431606, M.S. (India); Mohite, K.C. [Haribhai. V. Desai College, Pune 411002, M.S. (India); Khairnar, Rajendra S., E-mail: rskhairnarsps@gmail.com [School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431606, M.S. (India)

    2014-02-01T23:59:59.000Z

    Highlights: • We report improved gas sensing and dielectric characteristics of Fe ion exchanged HAp films. • Fe doped HAp film shows maximum gas response at relatively lower temperature. • Response and gas uptake capacity of sensors is improved for appropriate amount of Fe ions in HAp matrix. • Fe-HAp films exhibit remarkable improvement in dielectric properties compared to pure HAp. • Fe doped HAp films show significant improvement in gas sensing as well as in dielectric properties. - Abstract: In the present work Fe doped hydroxyapatite (Fe-HAp) thick films has been successfully utilized to improve the gas sensing as well as its dielectric properties. Initially, HAp nano powder is synthesized by chemical precipitation process and later on Fe ions are doped in HAp by ion exchange process. Structural and morphological modifications are observed by means of X-ray diffraction and scanning electron microscopy analysis. The sensing parameters such as operating temperature, response/recovery time and gas uptake capacity are experimentally determined. The Fe-HAp (0.05 M) film shows improved CO and CO{sub 2} gas sensing capacity at lower operating temperature compared to pure HAp. Moreover, variation of dielectric constant and dielectric loss for pure and Fe-HAp thick films are studied as a function of frequency in the range of 10 Hz–1 MHz. The study reveals that Fe doped HAp thick films improve the sensing and dielectric characteristics as compared to pure HAp.

  12. Theoretical study of gas heated in a porous material subjected to a concentrated solar radiation (*)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . An experimental reactor was constructed for the verification of the model; it was designed to be used with 6.5 k velocity in the axial direction ; Vo = fluid velocity in the empty column, Vo = 03B6v. (*) Presented), physics (drying, distillation), thermo- dynamics (thermo-helio-electric power plants), etc. The gas being

  13. Use of a directional spray system design to control respirable dust and free gas concentrations around a continuous mining machine

    SciTech Connect (OSTI)

    Goodman, G.V.R.; Pollock, D.E. [NIOSH, Pittsburgh, PA (US). Pittsburgh Research Lab.

    2004-12-15T23:59:59.000Z

    A laboratory study assessed the impacts of water spray pressure, face ventilation quantity, and line brattice setback distance on respirable dust and SF6 tracer gas concentrations around a continuous mining machine using a sprayfan or directional spray system. Dust levels were measured at locations representing the mining machine operator and the standard and off standard shuttle car operators, and in the return airway. The results showed that changes in all three independent variables significantly affected log-transformed dust levels at the three operator sampling locations. Changes in setback distance impacted return airway dust levels. Laboratory testing also identified numerous variable interactions affecting dust levels. Tracer gas levels were measured on the left and right sides of the cutting drum and in the return. Untransformed gas levels around the cutting drum were significantly affected by changes in water pressure, face ventilation quantity, and setback distance. Return gas levels measured at the low curtain quantity were generally unaffected by changes in water pressure or curtain setback distance. At the high curtain quantity, return airway gas levels were affected by curtain setback distance. A field study was conducted to assess the impact of these parameters in an actual mining operation. These data showed that respirable dust levels may have been impacted by a change in water pressure and, to a lesser extent, by an increase in curtain setback distance. A series of tracer gas pulse tests were also conducted during this study. The results showed that effectiveness of the face ventilation was impacted by changes in curtain flow quantity and setback distance.

  14. Leaf gas exchange and carbohydrate concentrations in Pinus pinaster plants subjected to elevated CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    to elevated CO2 and a soil drying cycle Catherine Picon-Cochard Jean-Marc Guehl Unité de recherches en.) were acclimated for 2 years under ambient (350 ?mol mol-1)and elevated (700 ?mol mol-1) CO2 concentrations ([CO2]). In the summer of the second growing season, the plants were subjected to a soil drying

  15. Apparatus to collect, classify, concentrate, and characterize gas-borne particles

    DOE Patents [OSTI]

    Rader, Daniel J.; Torczynski, John R.; Wally, Karl; Brockmann, John E.

    2003-12-16T23:59:59.000Z

    An aerosol lab-on-a-chip (ALOC) integrates one or more of a variety of particle collection, classification, concentration (enrichment), an characterization processes onto a single substrate or layered stack of such substrates. By mounting a UV laser diode laser light source on the substrate, or substrates tack, so that it is located down-stream of the sample inlet port and at right angle the sample particle stream, the UV light source can illuminate individual particles in the stream to induce a fluorescence response in those particles having a fluorescent signature such as biological particles, some of said particles. An illuminated particle having a fluorescent signal above a threshold signal would trigger a sorter module that would separate that particle from the particle stream.

  16. Meta-Analysis of Estimates of Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power: Preprint

    SciTech Connect (OSTI)

    Heath, G. A.; Burkhardt, J. J.

    2011-09-01T23:59:59.000Z

    In reviewing life cycle assessment (LCA) literature of utility-scale CSP systems, this analysis focuses on clarifying central tendency and reducing variability in estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emission estimates passing screens for quality and relevance: 19 for parabolic trough technology and 17 for power tower technology. The interquartile range (IQR) of published GHG emission estimates was 83 and 20 g CO2eq/kWh for trough and tower, respectively, with medians of 26 and 38 g CO2eq/kWh. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. Compared to the published estimates, IQR was reduced by 69% and median increased by 76% for troughs. IQR was reduced by 26% for towers, and median was reduced by 34%. A second level of harmonization was applied to five well-documented trough LC GHG emission estimates, harmonizing to consistent values for GHG emissions embodied in materials and from construction activities. As a result, their median was further reduced by 5%, while the range increased by 6%. In sum, harmonization clarified previous results.

  17. For information regarding the background concentration levels of macro and trace constituents, including elements of regulatory-interest such as arsenic, cadmium, chromium, lead,

    E-Print Network [OSTI]

    Model And Its Use In Contaminant Transport Modeling 2.1 Introduction The concentration of contaminants and groundwater systems, the reader is referred to Lindsay (1979), Hem (1985), Sposito (1989, 1994), Langmuir in groundwater1 is determined by the amount, concentration, and nature of contaminant present at the source, rate

  18. Apparatus to collect, classify, concentrate, and characterize gas-borne particles

    DOE Patents [OSTI]

    Rader, Daniel J. (Albuquerque, NM); Torczynski, John R. (Albuquerque, NM); Wally, Karl (Lafayette, CA); Brockmann, John E. (Albuquerque, NM)

    2002-01-01T23:59:59.000Z

    An aerosol lab-on-a-chip (ALOC) integrates one or more of a variety of aerosol collection, classification, concentration (enrichment), and characterization processes onto a single substrate or layered stack of such substrates. By taking advantage of modern micro-machining capabilities, an entire suite of discrete laboratory aerosol handling and characterization techniques can be combined in a single portable device that can provide a wealth of data on the aerosol being sampled. The ALOC offers parallel characterization techniques and close proximity of the various characterization modules helps ensure that the same aerosol is available to all devices (dramatically reducing sampling and transport errors). Micro-machine fabrication of the ALOC significantly reduces unit costs relative to existing technology, and enables the fabrication of small, portable ALOC devices, as well as the potential for rugged design to allow operation in harsh environments. Miniaturization also offers the potential of working with smaller particle sizes and lower pressure drops (leading to reduction of power consumption).

  19. Solid molecular basket sorbent for CO2 capture from gas streams with low CO2 concentration at ambient conditions

    SciTech Connect (OSTI)

    Wang, Xiaoxing [Pennsylvania State University; Ma, Xiaoliang [Pennsylvania State University; Schwartz, Viviane [ORNL; Clark, Jason C [ORNL; Overbury, Steven {Steve} H [ORNL; Zhao, Shuqi [Pennsylvania State University, University Park, PA; Xu, Xiaochun [Pennsylvania State University; Song, Chunshan [Pennsylvania State University

    2012-01-01T23:59:59.000Z

    In this paper, a solid molecular basket sorbent, 50 wt% PEI/SBA-15 was studied for CO2 capture from gas streams with low CO2 concentration at ambient conditions. The sorbent was able to effectively and selectively capture CO2 from a gas stream containing 1% CO2 at 75 C, with a breakthrough and saturation capacity of 63.1 and 66.7 mg/g, respectively, and a selectivity of 14 for CO2/CO and 185 for CO2/Ar. The sorption performance of the sorbent was influenced greatly by the operating temperature. The CO2-TPD study showed that the sorbent could be regenerated at mild conditions (50-110 C) and was stable in the cyclical operations for at least 20 cycles. Furthermore, the possibility for CO2 capture from air using the PEI/SBA-15 sorbent was studied by FTIR and proved by TPD. A capacity of 22.5 mg/g was attained at 75 C via TPD method using a simulated air with 400 ppmv CO2 in N2.

  20. Life Cycle Greenhouse Gas Emissions of Trough and Tower Concentrating Solar Power Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Burkhardt, J. J.; Heath, G.; Cohen, E.

    2012-04-01T23:59:59.000Z

    In reviewing life cycle assessment (LCA) literature of utility-scale concentrating solar power (CSP) systems, this analysis focuses on reducing variability and clarifying the central tendency of published estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emissions estimates passing screens for quality and relevance: 19 for parabolic trough (trough) technology and 17 for power tower (tower) technology. The interquartile range (IQR) of published estimates for troughs and towers were 83 and 20 grams of carbon dioxide equivalent per kilowatt-hour (g CO2-eq/kWh),1 respectively; median estimates were 26 and 38 g CO2-eq/kWh for trough and tower, respectively. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. The IQR and median were reduced by 87% and 17%, respectively, for troughs. For towers, the IQR and median decreased by 33% and 38%, respectively. Next, five trough LCAs reporting detailed life cycle inventories were identified. The variability and central tendency of their estimates are reduced by 91% and 81%, respectively, after light harmonization. By harmonizing these five estimates to consistent values for global warming intensities of materials and expanding system boundaries to consistently include electricity and auxiliary natural gas combustion, variability is reduced by an additional 32% while central tendency increases by 8%. These harmonized values provide useful starting points for policy makers in evaluating life cycle GHG emissions from CSP projects without the requirement to conduct a full LCA for each new project.

  1. Concentrations of trace and other elements in the organs of wild rats and birds from the Northern Guinea savanna of Nigeria

    SciTech Connect (OSTI)

    Kapu, M.M.; Schaeffer, D.J. (Univ. of Illinois, Urbana (United States)); Akanya, H.O. (Federal Univ. of Technology, Minna (Nigeria)); Ega, R.A.; Olofu, E.O.; Balarabe, M.L. (Ahmadu Bello Univ., Zaria (Nigeria)); Chafe, U.M. (Usmanu Danfodiyo Univ., Sokota (Nigeria))

    1991-01-01T23:59:59.000Z

    In regions of human activities, where metal enter local aquatic ecosystems from the atmosphere and through wastewater outfalls, metal concentrations in food chains can exceed natural background levels and be above the threshold levels for sensitive species. Accordingly, metal levels in the organs and tissues of livestock and wildlife have been extensively studied. However, there are no reports of metal concentrations in the organs and tissues of wild animals from the Northern Guinea savanna of Nigeria. The mole rat (Africanthus niloticus, L) and village weaver bird (Ploceus cucullatus, L) contribute significantly to farm crop losses from sowing to harvest. Because there are no industries capable of causing metal contamination in the study area, the present study was undertaken to determine the natural baseline levels of metals for wild rats and birds from this environment.

  2. CONTENTS Concentrated Gas Hydrate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C l a r8.0 - HOISTING AND RIGGING IN

  3. I/I ratios and halogen concentrations in pore waters of the Hydrate Ridge: Relevance for the origin of gas hydrates in ODP Leg 204

    E-Print Network [OSTI]

    Fehn, Udo

    in fluids associated with hydrocarbons, such as oil field brines (Moran et al., 1995) or coal-bed methane association of iodine with methane allows the identification of the organic source material responsible for iodine and methane in gas hydrates. In all cores, iodine concentrations were found to increase strongly

  4. (Astro)Physics 343 Lecture # 8: Green Bank trip + gas dynamics

    E-Print Network [OSTI]

    Baker, Andrew J.

    matter (i.e., dark matter). #12; A heretical alternative? A few bold souls have pointed out that once/T. #12; Gas dynamics: a Keplerian example From Herrnstein et al. (1999): water masers tracing orbital, based on the central concentration of luminous matter (stars and gas): #12; Rotation curves

  5. (Astro)Physics 343 Lecture # 8: Green Bank trip; gas dynamics

    E-Print Network [OSTI]

    Baker, Andrew J.

    matter (i.e., dark matter). #12; A heretical alternative? A few bold souls have pointed out that once/T. #12; Gas dynamics: a Keplerian example From Herrnstein et al. (1999): water masers tracing orbital, based on the central concentration of luminous matter (stars and gas): #12; Rotation curves

  6. Laboratory scale studies of Pd/{gamma}-Al{sub 2}O{sub 3} sorbents for the removal of trace contaminants from coal-derived fuel gas at elevated temperatures

    SciTech Connect (OSTI)

    Rupp, Erik C.; Granite, Evan J. [U.S. DOE; Stanko, Dennis C. [U.S. DOE

    2013-01-01T23:59:59.000Z

    The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150–540 °C) to hot (>540 °C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 °C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/?-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/?-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/?-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

  7. Lead Isotopic Composition of Fly Ash and Flue Gas Residues from Municipal Solid Waste Combustors in France: Implications for Atmospheric Lead Source Tracing.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Lead Isotopic Composition of Fly Ash and Flue Gas Residues from Municipal Solid Waste Combustors@crpg.cnrs-nancy.fr _______________________________________________________________________________________ Fly ash and flue gas residues from eight municipal solid waste combusters (MSWC) in France (1992 of "industrial Pb" is not an easy task because of its possible extreme heterogeneity. Municipal solid waste

  8. Trace metal uptake and accumulation pathways in Kemp's ridley sea turtles (Lepidochelys kempii)

    E-Print Network [OSTI]

    Wang, Hui-Chen

    2005-08-29T23:59:59.000Z

    Little is known of trace metal concentrations and their possible role in the mortality of critically endangered Kemp??s ridley sea turtles (Lepidochelys kempii). Research described herein characterized concentrations of seven trace metals ?? Ag, Cd...

  9. Gas concentration measurement instrument based on the effects of a wave-mixing interference on stimulated emissions

    DOE Patents [OSTI]

    Garrett, W. Ray (Oak Ridge, TN)

    1997-01-01T23:59:59.000Z

    A method and apparatus for measuring partial pressures of gaseous components within a mixture. The apparatus comprises generally at least one tunable laser source, a beam splitter, mirrors, optical filter, an optical spectrometer, and a data recorder. Measured in the forward direction along the path of the laser, the intensity of the emission spectra of the gaseous component, at wavelengths characteristic of the gas component being measured, are suppressed. Measured in the backward direction, the peak intensities characteristic of a given gaseous component will be wavelength shifted. These effects on peak intensity wavelengths are linearly dependent on the partial pressure of the compound being measured, but independent of the partial pressures of other gases which are present within the sample. The method and apparatus allow for efficient measurement of gaseous components.

  10. Gas concentration measurement instrument based on the effects of a wave-mixing interference on stimulated emissions

    DOE Patents [OSTI]

    Garrett, W.R.

    1997-11-11T23:59:59.000Z

    A method and apparatus are disclosed for measuring partial pressures of gaseous components within a mixture. The apparatus comprises generally at least one tunable laser source, a beam splitter, mirrors, optical filter, an optical spectrometer, and a data recorder. Measured in the forward direction along the path of the laser, the intensity of the emission spectra of the gaseous component, at wavelengths characteristic of the gas component being measured, are suppressed. Measured in the backward direction, the peak intensities characteristic of a given gaseous component will be wavelength shifted. These effects on peak intensity wavelengths are linearly dependent on the partial pressure of the compound being measured, but independent of the partial pressures of other gases which are present within the sample. The method and apparatus allow for efficient measurement of gaseous components. 9 figs.

  11. angstrom noble gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (AMS) and Atom Trap Trace Analysis (ATTA). Collon, P; Lu, Z T 2004-01-01 5 Tracing Noble Gas Radionuclides in the Environment Nuclear Experiment (arXiv) Summary: Trace analysis of...

  12. COFIN project Concentration Fluctuations

    E-Print Network [OSTI]

    COFIN project Concentration Fluctuations in Gas Releases by Industrial Accidents Final Summary of random concentration fluctuations in hazardous gas releases and the method was to derive empirical. In each measurement cycle the Lidar emits a short laser light pulse and detects the light Lidar reflected

  13. Oil and Gas CDT Using noble gas isotopes to develop a mechanistic understanding of shale gas

    E-Print Network [OSTI]

    Henderson, Gideon

    Oil and Gas CDT Using noble gas isotopes to develop a mechanistic understanding of shale gas, desorbtion, tracing, migration Overview The discovery of shale gas in UK Shales demonstrates how important and no doubt will vary from shale to shale. An improved understanding of the controls on gas production from

  14. Novel Sorbent-Based Process for High Temperature Trace Metal Removal

    SciTech Connect (OSTI)

    Gokhan Alptekin

    2008-09-30T23:59:59.000Z

    The objective of this project was to demonstrate the efficacy of a novel sorbent can effectively remove trace metal contaminants (Hg, As, Se and Cd) from actual coal-derived synthesis gas streams at high temperature (above the dew point of the gas). The performance of TDA's sorbent has been evaluated in several field demonstrations using synthesis gas generated by laboratory and pilot-scale coal gasifiers in a state-of-the-art test skid that houses the absorbent and all auxiliary equipment for monitoring and data logging of critical operating parameters. The test skid was originally designed to treat 10,000 SCFH gas at 250 psig and 350 C, however, because of the limited gas handling capabilities of the test sites, the capacity was downsized to 500 SCFH gas flow. As part of the test program, we carried out four demonstrations at two different sites using the synthesis gas generated by the gasification of various lignites and a bituminous coal. Two of these tests were conducted at the Power Systems Demonstration Facility (PSDF) in Wilsonville, Alabama; a Falkirk (North Dakota) lignite and a high sodium lignite (the PSDF operator Southern Company did not disclose the source of this lignite) were used as the feedstock. We also carried out two other demonstrations in collaboration with the University of North Dakota Energy Environmental Research Center (UNDEERC) using synthesis gas slipstreams generated by the gasification of Sufco (Utah) bituminous coal and Oak Hills (Texas) lignite. In the PSDF tests, we showed successful operation of the test system at the conditions of interest and showed the efficacy of sorbent in removing the mercury from synthesis gas. In Test Campaign No.1, TDA sorbent reduced Hg concentration of the synthesis gas to less than 5 {micro}g/m{sup 3} and achieved over 99% Hg removal efficiency for the entire test duration. Unfortunately, due to the relatively low concentration of the trace metals in the lignite feed and as a result of the intermittent operation of the PSDF gasifier (due to the difficulties in the handling of the low quality lignite), only a small fraction of the sorbent capacity was utilized (we measured a mercury capacity of 3.27 mg/kg, which is only a fraction of the 680 mg/kg Hg capacity measured for the same sorbent used at our bench-scale evaluations at TDA). Post reaction examination of the sorbent by chemical analysis also indicated some removal As and Se (we did not detect any significant amounts of Cd in the synthesis gas or over the sorbent). The tests at UNDEERC was more successful and showed clearly that the TDA sorbent can effectively remove Hg and other trace metals (As and Se) at high temperature. The on-line gas measurements carried out by TDA and UNDEERC separately showed that TDA sorbent can achieve greater than 95% Hg removal efficiency at 260 C ({approx}200g sorbent treated more than 15,000 SCF synthesis gas). Chemical analysis conducted following the tests also showed modest amounts of As and Se accumulation in the sorbent bed (the test durations were still short to show higher capacities to these contaminants). We also evaluated the stability of the sorbent and the fate of mercury (the most volatile and unstable of the trace metal compounds). The Synthetic Ground Water Leaching Procedure Test carried out by an independent environmental laboratory showed that the mercury will remain on the sorbent once the sorbent is disposed. Based on a preliminary engineering and cost analysis, TDA estimated the cost of mercury removal from coal-derived synthesis gas as $2,995/lb (this analysis assumes that this cost also includes the cost of removal of all other trace metal contaminants). The projected cost will result in a small increase (less than 1%) in the cost of energy.

  15. TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID...

    Open Energy Info (EERE)

    FLUID-INCLUSION GAS CHEMISTRY Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING...

  16. Tracing Geothermal Fluids

    SciTech Connect (OSTI)

    Michael C. Adams; Greg Nash

    2004-03-01T23:59:59.000Z

    Geothermal water must be injected back into the reservoir after it has been used for power production. Injection is critical in maximizing the power production and lifetime of the reservoir. To use injectate effectively the direction and velocity of the injected water must be known or inferred. This information can be obtained by using chemical tracers to track the subsurface flow paths of the injected fluid. Tracers are chemical compounds that are added to the water as it is injected back into the reservoir. The hot production water is monitored for the presence of this tracer using the most sensitive analytic methods that are economically feasible. The amount and concentration pattern of the tracer revealed by this monitoring can be used to evaluate how effective the injection strategy is. However, the tracers must have properties that suite the environment that they will be used in. This requires careful consideration and testing of the tracer properties. In previous and parallel investigations we have developed tracers that are suitable from tracing liquid water. In this investigation, we developed tracers that can be used for steam and mixed water/steam environments. This work will improve the efficiency of injection management in geothermal fields, lowering the cost of energy production and increasing the power output of these systems.

  17. Sensitive Multi-Species Emissions Monitoring: Infrared Laser-Based Detection of Trace-Level Contaminants.

    SciTech Connect (OSTI)

    Steill, Jeffrey D

    2015-01-01T23:59:59.000Z

    This report summarizes our development of spectroscopic chemical analysis techniques and spectral modeling for trace-gas measurements of highly-regulated low-concentration species present in flue gas emissions from utility coal boilers such as HCl under conditions of high humidity. Detailed spectral modeling of the spectroscopy of HCl and other important combustion and atmospheric species such as H 2 O, CO 2 , N 2 O, NO 2 , SO 2 , and CH 4 demonstrates that IR-laser spectroscopy is a sensitive multi-component analysis strategy. Experimental measurements from techniques based on IR laser spectroscopy are presented that demonstrate sub-ppm sensitivity levels to these species. Photoacoustic infrared spectroscopy is used to detect and quantify HCl at ppm levels with extremely high signal-to-noise even under conditions of high relative humidity. Additionally, cavity ring-down IR spectroscopy is used to achieve an extremely high sensitivity to combustion trace gases in this spectral region; ppm level CH 4 is one demonstrated example. The importance of spectral resolution in the sensitivity of a trace-gas measurement is examined by spectral modeling in the mid- and near-IR, and efforts to improve measurement resolution through novel instrument development are described. While previous project reports focused on benefits and complexities of the dual-etalon cavity ring-down infrared spectrometer, here details on steps taken to implement this unique and potentially revolutionary instrument are described. This report also illustrates and critiques the general strategy of IR- laser photodetection of trace gases leading to the conclusion that mid-IR laser spectroscopy techniques provide a promising basis for further instrument development and implementation that will enable cost-effective sensitive detection of multiple key contaminant species simultaneously.

  18. Inorganic hazardous air pollutants before and after a limestone flue gas desulfurization system as a function of <10 micrometer particle sizes and unit load

    SciTech Connect (OSTI)

    Maxwell, D.P.; Williams, W.A.; Flora, H.B. II [Radian Corp., Austin, TX (United States)

    1995-12-31T23:59:59.000Z

    Radian Corporation collected size-fractionated particulate samples from stack gas at a unit burning high sulfur coal with a venturi scrubber FGD system. Independent sample fractions were collected under high-load and low-load operating conditions and subjected to various techniques designed to measure the total composition and surface-extractable concentrations of selected trace elements. The relationships between unit load, particle-size distribution, total composition, and surface-extractable inorganic species are reported and compared to show the availability of trace elements relevant to potential health risks from flue gas particulate emissions.

  19. Investigation into the effects of trace coal syn gas species on the performance of solid oxide fuel cell anodes, PhD. thesis, Russ College of Engineering and Technology of Ohio University

    SciTech Connect (OSTI)

    Trembly, J.P.

    2007-06-01T23:59:59.000Z

    Coal is the United States’ most widely used fossil fuel for the production of electric power. Coal’s availability and cost dictates that it will be used for many years to come in the United States for power production. As a result of the environmental impact of burning coal for power production more efficient and environmentally benign power production processes using coal are sought. Solid oxide fuel cells (SOFCs) combined with gasification technologies represent a potential methodology to produce electric power using coal in a much more efficient and cleaner manner. It has been shown in the past that trace species contained in coal, such as sulfur, severely degrade the performance of solid oxide fuel cells rendering them useless. Coal derived syngas cleanup technologies have been developed that efficiently remove sulfur to levels that do not cause any performance losses in solid oxide fuel cells. The ability of these systems to clean other trace species contained in syngas is not known nor is the effect of these trace species on the performance of solid oxide fuel cells. This works presents the thermodynamic and diffusion transport simulations that were combined with experimental testing to evaluate the effects of the trace species on the performance of solid oxide fuel cells. The results show that some trace species contained in coal will interact with the SOFC anode. In addition to the transport and thermodynamic simulations that were completed experimental tests were completed investigating the effect of HCl and AsH3 on the performance of SOFCs.

  20. Trace element distribution and mercury speciation in a pilot-scale coal combustor burning Blacksville coal

    SciTech Connect (OSTI)

    Hargis, R.A.; Pennline, H.W. [Dept. of Energy, Pittsburgh, PA (United States). Federal Energy Technical Center

    1997-12-31T23:59:59.000Z

    A series of tests have been conducted on a nominal 500-pound-per-hour, pilot-scale combustion unit to characterize trace element emissions and mercury speciation. The coal fired during the testing was a Blacksville {number_sign}2, medium-sulfur coal, similar to that used by other researchers investigating mercury speciation. A description of the pilot unit operating conditions during the testing is provided. A summary of the gas/solid distribution of trace elements at various locations within the system, material balances, and baghouse removal efficiencies is also supplied. EPA Method 29 was used to determine trace element and speciated mercury concentrations before and after the baghouse. A comparison of these results with past trace element results from this unit and with the findings of other researchers who have used Blacksville coal is also presented. The pilot-scale combustion unit has been characterized in terms of trace element distribution during two tests while burning a medium-sulfur bituminous Blacksville coal. EPA sampling methodology at the inlet to the baghouse and at the stack was used. Results indicate that most of the elements are removed across the baghouse with the exception of mercury and selenium. Both of these elements were found predominantly in the vapor phase. The average mercury speciation revealed that the vapor-phase mercury was primarily in the oxidized form, which is consistent with the findings of other research with Blacksville coal. Material recoveries for most of the elements were very good. The average recovery for mercury further validates that this pilot unit will be a viable system for mercury sampling and control methods.

  1. Molecular gas and AGN fueling

    E-Print Network [OSTI]

    F. Combes

    2003-08-01T23:59:59.000Z

    CO emission, tracing the molecular content and distribution in galaxies, is a privileged tool to trace gas towards the nucleus, since the HI tracer is in general depleted there. A review is done of recent CO line observations, with sufficient spatial resolution to indicate the morphology and kinematics of the gas near the nucleus. The puzzling result that nuclei presently observed in an active phase have little sign of fueling, is discussed.

  2. Prediction of Peak Hydrogen Concentrations for Deep Sludge Retrieval in Tanks AN-101 and AN-106 from Historical Data of Spontaneous Gas Release Events

    SciTech Connect (OSTI)

    Wells, Beric E.; Cooley, Scott K.; Meacham, Joseph E.

    2013-10-21T23:59:59.000Z

    Radioactive and chemical wastes from nuclear fuel processing are stored in large underground storage tanks at the Hanford Site. The Tank Operations Contractor is continuing a program of moving solid wastes from single-shell tanks (SSTs) to double-shell tanks (DSTs) and preparing for waste feed delivery (WFD). A new mechanism for a large spontaneous gas release event (GRE) in deep sludge sediments has been postulated. The creation of this potential new GRE hazard, deep sludge gas release events (DSGREs), is the retrieval of sludge waste into a single DST that results in a sediment depth greater than operating experience has demonstrated is safe. The Tank Operations Contractor program of moving solid wastes from SSTs to DSTs and preparing for WFD is being negatively impacted by this sediment depth limit.

  3. AN ADVANCED E-PERM SYSTEM FOR SIMULTANEOUS MEASUREMENT OF CONCENTRATIONS OF RADON GAS, RADON PROGENY, EQUILIBRIUM RATIO AND UNATTACHED RADON PROGENY

    E-Print Network [OSTI]

    Paul Ph. D. Stieff; Rick Stieff; Lorin Stieff

    2003-01-01T23:59:59.000Z

    The detrimental effects of prolonged exposure to the decay products of radon, is well known and documented in the literature. The USEPA has set a primary standard for radon progeny exposure for the general public at 0.02 WL with a corresponding derived limit of 4 pCi/L for radon gas, assuming an equilibrium ratio of 50%. Because radon gas measurement is simpler and less expensive, more than 90 % of all the currently performed radon measurements in the US, measure radon gas and estimate the actual health risk via the assumed equilibrium factor for a residential structure. However, with increased concerns of radon related exposures in building with high air circulation rates (schools and commercial buildings) the 50 % equilibrium ratio assumption may not allow for proper characterization of the true exposure from radon measurements. In these cases a more rigorous characterization by direct measurements of radon decay products may be useful follow-up measurement after initial radon measurements have identified a potential concern. This paper describes a configuration radon and radon decay product measurement devices that can simultaneously measure radon and its decay products as well as provide an indication of the relative ratio of attached to unattached decay products. This unique combination of devices has numerous applications for designers of complex remediation systems and environmental consultants who have the responsibility of providing cost effective

  4. Thermodynamic analysis of interactions between Ni-based solid oxide fuel cells (SOFC) anodes and trace species in a survey of coal syngas

    SciTech Connect (OSTI)

    Andrew Martinez; Kirk Gerdes; Randall Gemmen; James Postona

    2010-03-20T23:59:59.000Z

    A thermodynamic analysis was conducted to characterize the effects of trace contaminants in syngas derived from coal gasification on solid oxide fuel cell (SOFC) anode material. The effluents from 15 different gasification facilities were considered to assess the impact of fuel composition on anode susceptibility to contamination. For each syngas case, the study considers the magnitude of contaminant exposure resulting from operation of a warm gas cleanup unit at two different temperatures and operation of a nickel-based SOFC at three different temperatures. Contaminant elements arsenic (As), phosphorous (P), and antimony (Sb) are predicted to be present in warm gas cleanup effluent and will interact with the nickel (Ni) components of a SOFC anode. Phosphorous is the trace element found in the largest concentration of the three contaminants and is potentially the most detrimental. Poisoning was found to depend on the composition of the syngas as well as system operating conditions. Results for all trace elements tended to show invariance with cleanup operating temperature, but results were sensitive to syngas bulk composition. Synthesis gas with high steam content tended to resist poisoning.

  5. A field study on the trace metal behavior in atmospheric circulating fluidized-bed coal combustion

    SciTech Connect (OSTI)

    Lind, T.; Kauppinen, E.I.; Jokiniemi, J.K.; Maenhaut, W.

    1994-12-31T23:59:59.000Z

    Trace element behavior in atmospheric circulating fluidized-bed combustion (CFBC) of Venezuelan bituminous coal was studied by determining particle size distributions in the CFBC flue gas. The size distributions of calcium, iron, aluminium, and 21 trace elements, Sc, V, Cr, Mn, Co, Ni, Zn, Ga, As, Se, Sr, Cd, Sb, Cs, Ba, La, Ce, Sm, Lu, Pb, and Th, in the size range 0.01--70{micro}m, were determined by collecting aerosols with a low-pressure impactor-cyclone sampling train from the flue gases of an 80-MW(th) CFBC boiler upstream of the electrostatic precipitator. The collected samples were analyzed gravimetrically and with instrumental neutron activation analysis (INAA), particle-induced X-ray emission analysis (PIXE), and inductively coupled plasma mass spectrometry (ICP-MS). The number size distributions of the aerosols were determined with a differential electrical mobility method in the size range 0.01--0.8 {micro}m. In the ultrafine particle mode, i.e., D{sub p} < 0.1 {micro}m, the CFBC number concentrations varied strongly during the experiments, being one to two orders of magnitude lower than those observed in pulverized coal combustion. For all of the elements studied, 75% or more were found in particles larger than 5{micro}m. None of the studied elements showed significant vaporization and subsequent chemical surface reaction or condensation in the CFBC. The Sr, Se, V, Zn, Ga, Cs, Ba, La, Sm, Lu, and Th size distributions resembled those of aluminium, suggesting their occurrence in aluminosilicate-rich particles in the fly ash. The association of the trace elements with aluminium in the fly ash particles may result from reactions of the trace elements with the aluminosilicate mineral particles inside the burning coal particles, or their initial occurrence in association with these minerals.

  6. Solar Tracing Sensors for Maximum Solar Concentrator Efficiency - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our Instagram Secretary Moniz9MorganYouof Energy Projects toSolar

  7. Natural gas leak mapper

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2008-05-20T23:59:59.000Z

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formated into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimosed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  8. Atom trap trace analysis of krypton isotopes

    SciTech Connect (OSTI)

    Bailey, K.; Chen, C. Y.; Du, X.; Li, Y. M.; Lu, Z.-T.; O'Connor, T. P.; Young, L.

    1999-11-17T23:59:59.000Z

    A new method of ultrasensitive isotope trace analysis has been developed. This method, based on the technique of laser manipulation of neutral atoms, has been used to count individual {sup 85}Kr and {sup 81}Kr atoms present in a natural krypton gas sample with isotopic abundances in the range of 10{sup {minus}11} and 10{sup {minus}13}, respectively. This method is free of contamination from other isotopes and elements and can be applied to several different isotope tracers for a wide range of applications. The demonstrated detection efficiency is 1 x 10{sup {minus}7}. System improvements could increase the efficiency by many orders of magnitude.

  9. In situ measurements of Krypton in Xenon gas with a quadrupole mass spectrometer following a cold-trap at a temporarily reduced pumping speed

    E-Print Network [OSTI]

    Ethan Brown; Stephan Rosendahl; Christian Huhmann; Christian Weinheimer; Hans Kettling

    2012-12-20T23:59:59.000Z

    A new method for measuring trace amounts of krypton in xenon using a cold trap with a residual gas analyzer has been developed, which achieves an increased sensitivity by temporarily reducing the pumping speed while expending a minimal amount of xenon. By partially closing a custom built butterfly valve between the measurement chamber and the turbomolecular pump, a sensitivity of 40 ppt has been reached. This method has been tested on an ultra-pure gas sample from Air Liquide with an unknown intrinsic krypton concentration, yielding a krypton concentration of $330 \\pm 200$ ppt.

  10. Mid-Infrared Laser based Gas Sensor Technologies for Environmental Monitoring,

    E-Print Network [OSTI]

    , quantification and monitoring of trace gas species and their applications in environmental and industrial process performing sensitive trace gas measurements in gas samples of a few mm3 in volume. QEPAS employs readilyChapter XX Mid-Infrared Laser based Gas Sensor Technologies for Environmental Monitoring, Medical

  11. Sandia National Laboratories: Concentrating Solar Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas Sectors in the United States View all EC Publications Related Topics Concentrating Solar Power CRF CSP EFRC Energy Energy Efficiency Energy Security National Solar Thermal...

  12. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2009-08-11T23:59:59.000Z

    Efficiencies greater than 50 percent (higher heating value) have been projected for solid oxide fuel cell (SOFC) systems fueled with gasified coal, even with carbon sequestration. Multiple minor and trace components are present in coal that could affect fuel cell performance, however, which vary widely depending on coal origin and type. Minor and trace components have been classified into three groups: elements with low volatility that are likely to remain in the ash, elements that will partition between solid and gas phases, and highly volatile elements that are unlikely to condense. Those in the second group are of most concern. In the following, an overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic coal gas. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  13. Concentrating collectors

    SciTech Connect (OSTI)

    Not Available

    1981-06-01T23:59:59.000Z

    Selected specifications from sixteen concentrating collector manufacturers are tabulated. Eleven are linear parabolic trough collectors, and the others include slats, cylindrical trough, linear Fresnel lens, parabolic cylindrical Fresnel lens, and two point focus parabolic dish collectors. Also included is a brief discussion of the operating temperatures and other design considerations for concentrating collectors. (LEW)

  14. Landfill gas cleanup for carbonate fuel cell power generation. Final report

    SciTech Connect (OSTI)

    Steinfield, G.; Sanderson, R.

    1998-02-01T23:59:59.000Z

    Landfill gas represents a significant fuel resource both in the US and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. A pilot plant cleaned approximately 970,000 scf of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations: less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorinated hydrocarbon; and 1.5 ppm sulfur dioxide.

  15. Trace elements in oil shale. Progress report, 1979-1980

    SciTech Connect (OSTI)

    Chappell, W R

    1980-01-01T23:59:59.000Z

    The purpose of this research program is to understand the potential impact of an oil shale industry on environmental levels of trace contaminants in the region. The program involves a comprehensive study of the sources, release mechanisms, transport, fate, and effects of toxic trace chemicals, principally the trace elements, in an oil shale industry. The overall objective of the program is to evaluate the environmental and health consequences of the release of toxic trace elements by shale and oil production and use. The baseline geochemical survey shows that stable trace elements maps can be constructed for numerous elements and that the trends observed are related to geologic and climatic factors. Shale retorted by above-ground processes tends to be very homogeneous (both in space and in time) in trace element content. Leachate studies show that significant amounts of B, F, and Mo are released from retorted shales and while B and Mo are rapidly flushed out, F is not. On the other hand, As, Se, and most other trace elements are not present in significant quantities. Significant amounts of F and B are also found in leachates of raw shales. Very large concentrations of reduced sulfur species are found in leachates of processed shale. Very high levels of B and Mo are taken up in some plants growing on processed shale with and without soil cover. There is a tendency for some trace elements to associate with specific organic fractions, indicating that organic chelation or complexation may play an important role. Many of the so-called standard methods for analyzing trace elements in oil shale-related materials are inadequate. A sampling manual is being written for the environmental scientist and practicing engineer. A new combination of methods is developed for separating the minerals in oil shale into different density fractions. Microbial investigations have tentatively identified the existence of thiobacilli in oil shale materials such as leachates. (DC)

  16. Boron isotope application for tracing sources of contamination in groundwater.

    E-Print Network [OSTI]

    Kasher, Roni

    Boron isotope application for tracing sources of contamination in groundwater. Abstract: Boron isotope composition and concentration of sewage effluent and pristine and contaminated groundwater from sodium perborate as a bleaching agent in detergents, leads to an enrichment of boron in wastewaters

  17. Heat-Traced Fluid Transfer Lines

    E-Print Network [OSTI]

    Schilling, R. E.

    1984-01-01T23:59:59.000Z

    HEAT-TRACED FLUID TRANSFER LINES Robert E. Schilling, P.E. Eaton Corporation Aurora, Ohio This paper discusses basic considerations in designing a heat tracing system using either steam or electrical tracing. Four basic reasons to heat...

  18. Epidemic Contact Tracing via Communication Traces Katayoun Farrahi1

    E-Print Network [OSTI]

    interactions, where contagious outbreaks propagate. However, due to privacy constraints and noisy data traces may be a viable option to arrest contagious outbreaks. Citation: Farrahi K, Emonet R, Cebrian M

  19. Adsorptive Stripping Voltammetric Measurements of Trace Uranium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Adsorptive Stripping Voltammetric Measurements of Trace Uranium at the Bismuth Film Electrode. Adsorptive Stripping Voltammetric Measurements of Trace Uranium at the Bismuth Film...

  20. Trace metal contamination of waters, sediments, and organisms of the Swan Lake area of Galveston Bay

    E-Print Network [OSTI]

    Park, Junesoo

    1995-01-01T23:59:59.000Z

    facility (Gulf Coast Waste Disposal Authority) is located north of the Wah Chang Ditch. Consequently there have been concerns about possible metal contamination in this area. I determined trace metal concentrations in water, sediments, and organisms (oyster...

  1. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09T23:59:59.000Z

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  2. Analysis of the trace element content of coals from the Wabaunsee Group southeastern Nebraska

    SciTech Connect (OSTI)

    Kaplan, S.S.; Carr, J.D.; Kelter, P.B.

    1983-01-01T23:59:59.000Z

    Eight coal samples obtained from the Honey Creek, Lorton, Wamego, Elmo, and Nodaway coals of the Wabaunsee Group (Upper Pennsylvanian) were analyzed for their concentration of certain trace elements. Analysis of the data suggests (a) a general decrease of trace element concentrations away from the Precambrian Nemaha Arch in a basinward direction, and (b) the post-diagenetic emplacement of lead, zinc and cadmium typical of mid-continent coals.

  3. Fate of trace elements in UK coals during gasification processes

    SciTech Connect (OSTI)

    Bushell, A.J.; Williamson, J. [Imperial College of Science, Technology and Medicine, London (United Kingdom)

    1996-12-31T23:59:59.000Z

    Five UK coals were selected to cover the range of mineral matter and ash contents typically encountered in UK bituminous coals. Trace element analysis was performed on both the whole coals and size separated fractions using ICP analysis for 21 trace elements, including Be, Cr, Co, Ni, As, Cd, Sb, Hg, and Pb, elements deemed to be the most environmentally hazardous. Small quantities of each coal were gasified in a laboratory gasifier in an atmosphere of N{sub 2} containing 15% O{sub 2}. Samples of bed ash, cyclone ash, and a fine gas-filtered ash were collected and analyzed to determine the partition of the trace elements between the gasification products. Mass balance calculations showed that the recovery of the trace elements varied from 20 to 97%; the low recovery of some trace elements highlighting the difficulties of collecting representative samples from a laboratory system. A parallel study on samples taken from a pilot plant gasifier showed significantly higher recovery rates, indicating the value of larger scale trials.

  4. Algorithm for Rapid Tomography of Gas Concentrations

    E-Print Network [OSTI]

    Price, P.N.

    2008-01-01T23:59:59.000Z

    sensing and computed tomography in industrial hygiene.American Industrial Hygiene Association Journal 51: 1165-indoor air. American Industrial Hygiene Association Journal

  5. Trace tritium and the H-mode density limit G.F. Matthews a,*, K.-D. Zastrow a

    E-Print Network [OSTI]

    Basse, Nils Plesner

    Trace tritium and the H-mode density limit G.F. Matthews a,*, K.-D. Zastrow a , P. Andrew a , B University, Princeton, NJ 08543, USA Abstract Trace amounts of tritium gas have been injected in short pus then saturation of the separatrix density implies clamping of the core density. Short pus of tritium were used

  6. Integrated vacuum absorption steam cycle gas separation

    DOE Patents [OSTI]

    Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

    2011-11-22T23:59:59.000Z

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  7. HD gas analysis with Gas Chromatography and Quadrupole Mass Spectrometer

    E-Print Network [OSTI]

    Ohta, T; Didelez, J -P; Fujiwara, M; Fukuda, K; Kohri, H; Kunimatsu, T; Morisaki, C; Ono, S; Rouille, G; Tanaka, M; Ueda, K; Uraki, M; Utsuro, M; Wang, S Y; Yosoi, M

    2011-01-01T23:59:59.000Z

    A gas analyzer system has been developed to analyze Hydrogen-Deuteride (HD) gas for producing frozen-spin polarized HD targets, which are used for hadron photoproduction experiments at SPring-8. Small amounts of ortho-H$_{2}$ and para-D$_{2}$ gas mixtures ($\\sim$0.01%) in the purified HD gas are a key to realize a frozen-spin polarized target. In order to obtain reliable concentrations of these gas mixtures in the HD gas, we produced a new gas analyzer system combining two independent measurements with the gas chromatography and the QMS. The para-H$_{2}$, ortho-H$_{2}$, HD, and D$_{2}$ are separated using the retention time of the gas chromatography and the mass/charge. It is found that the new gas analyzer system can measure small concentrations of $\\sim$0.01% for the otho-H$_2$ and D$_2$ with good S/N ratios.

  8. HD gas analysis with Gas Chromatography and Quadrupole Mass Spectrometer

    E-Print Network [OSTI]

    T. Ohta; S. Bouchigny; J. -P. Didelez; M. Fujiwara; K. Fukuda; H. Kohri; T. Kunimatsu; C. Morisaki; S. Ono; G. Rouille; M. Tanaka; K. Ueda; M. Uraki; M. Utsuro; S. Y. Wang; M. Yosoi

    2011-01-28T23:59:59.000Z

    A gas analyzer system has been developed to analyze Hydrogen-Deuteride (HD) gas for producing frozen-spin polarized HD targets, which are used for hadron photoproduction experiments at SPring-8. Small amounts of ortho-H$_{2}$ and para-D$_{2}$ gas mixtures ($\\sim$0.01%) in the purified HD gas are a key to realize a frozen-spin polarized target. In order to obtain reliable concentrations of these gas mixtures in the HD gas, we produced a new gas analyzer system combining two independent measurements with the gas chromatography and the QMS. The para-H$_{2}$, ortho-H$_{2}$, HD, and D$_{2}$ are separated using the retention time of the gas chromatography and the mass/charge. It is found that the new gas analyzer system can measure small concentrations of $\\sim$0.01% for the otho-H$_2$ and D$_2$ with good S/N ratios.

  9. Gas Exploration Software for Reducing Uncertainty in Gas Concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.Newof EnergyFunding OpportunityF GGary M. MignognaEstimates -

  10. Trace Metal Source Terms in Carbon Sequestration Environments

    SciTech Connect (OSTI)

    Karamalidis, Athanasios; Torres, Sharon G.; Hakala, Jacqueline A.; Shao, Hongbo; Cantrell, Kirk J.; Carroll, Susan A.

    2013-01-01T23:59:59.000Z

    ABSTRACT: Carbon dioxide sequestration in deep saline and depleted oil geologic formations is feasible and promising; however, possible CO2 or CO2-saturated brine leakage to overlying aquifers may pose environmental and health impacts. The purpose of this study was to experimentally define to provide a range of concentrations that can be used as the trace element source term for reservoirs and leakage pathways in risk simulations. Storage source terms for trace metals are needed to evaluate the impact of brines leaking into overlying drinking water aquifers. The trace metal release was measured from cements and sandstones, shales, carbonates, evaporites, and basalts from the Frio, In Salah, Illinois Basin, Decatur, Lower Tuscaloosa, Weyburn-Midale, Bass Islands, and Grand Ronde carbon sequestration geologic formations. Trace metal dissolution was tracked by measuring solution concentrations over time under conditions (e.g., pressures, temperatures, and initial brine compositions) specific to the sequestration projects. Existing metrics for maximum contaminant levels (MCLs) for drinking water as defined by the U.S. Environmental Protection Agency (U.S. EPA) were used to categorize the relative significance of metal concentration changes in storage environments because of the presence of CO2. Results indicate that Cr and Pb released from sandstone reservoir and shale cap rocks exceed the MCLs byan order of magnitude, while Cd and Cu were at or below drinking water thresholds. In carbonate reservoirs As exceeds the MCLs by an order of magnitude, while Cd, Cu, and Pb were at or below drinking water standards. Results from this study can be used as a reasonable estimate of the trace element source term for reservoirs and leakage pathways in risk simulations to further evaluate the impact of leakage on groundwater quality.

  11. Analytical instrument with apparatus and method for sample concentrating

    DOE Patents [OSTI]

    Zaromb, S.

    1986-08-04T23:59:59.000Z

    A system for analysis of trace concentrations of contaminants in air includes a portable liquid chromatograph and a preconcentrator for the contaminants to be analyzed. The preconcentrator includes a sample bag having an inlet valve and an outlet valve for collecting an air sample. When the sample is collected the sample bag is connected in series with a sorbing apparatus in a recirculation loop. The sorbing apparatus has an inner gas-permeable container containing a sorbent material and an outer gas-impermeable container. The sample is circulated through the outer container and around the inner container for trapping and preconcentrating the contaminants in the sorbent material. The sorbent material may be a liquid having the same composition as the mobile phase of the chromatograph for direct injection thereinto. Alternatively, the sorbent material may be a porous, solid body, to which mobile phase liquid is added after preconcentration of the contaminants for dissolving the contaminants, the liquid solution then being withdrawn for injection into the chromatograph.

  12. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    SciTech Connect (OSTI)

    Musich, Mark; Swanson, Michael; Dunham, Grant; Stanislowski, Joshua

    2010-10-05T23:59:59.000Z

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-?g/m{sup 3} (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-?g/m{sup 3} (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most effective arsine and hydrogen selenide sorbents. The noncarbon sorbent was able to reduce the concentration to 0 ppb from a starting concentration of 120 ppb. This compares to the target value of 5 ppb (~17?g/m{sup 3}). The EERC-prepared metal-based pellet and coprecipitate sorbents exhibited arsine reductions of 90% or greater, being below 10 ppb. Corning SR Liquid monoliths exhibited brief periods (<1 hour) of attaining 90% arsine reduction but were able to achieve greater than 80% reduction for several hours. With respect to hydrogen selenide, all Group IB and IIB metal-based sorbents tested exhibited 100% reduction from an inlet concentration of approximately 400 ppb. Corning SR Liquid monoliths exhibited an 82% reduction when two monoliths were tested simultaneously in series.

  13. ADVANCED GASIFICATION MERCURY/TRACE METAL CONTROL WITH MONOLITH TRAPS

    SciTech Connect (OSTI)

    Mark A. Musich; Michael L. Swanson; Grant E. Dunham; Joshua J. Stanislowski

    2010-07-31T23:59:59.000Z

    Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be the best monolith tested to date. The Corning SR Liquid monolith concept continues to be a strong candidate for mercury capture. Both monolith types allowed mercury reduction to below 5-?g/m3 (~5 ppb), a current U.S. Department of Energy (DOE) goal for trace metal control. Preparation methods for formulating the SR Liquid monolith impacted the ability of the monolith to capture mercury. The Energy & Environmental Research Center (EERC)-prepared Noncarbon Sorbents 1 and 2 appeared to offer potential for sustained and significant reduction of mercury concentration in the simulated fuel gas. The Noncarbon Sorbent 1 allowed sustained mercury reduction to below 5-?g/m3 (~5 ppb). The non-carbon-based sorbent appeared to offer the potential for regeneration, that is, desorption of mercury by temperature swing (using nitrogen and steam at temperatures above where adsorption takes place). A Corning cordierite monolith treated with a Group IB metal offered limited potential as a mercury sorbent. However, a Corning carbon-based monolith containing prereduced metallic species similar to those found on the noncarbon sorbents did not exhibit significant or sustained mercury reduction. EERC sorbents prepared with Group IB and IIB selenide appeared to have some promise for mercury capture. Unfortunately, these sorbents also released Se, as was evidenced by the measurement of H2Se in the effluent gas. All sorbents tested with arsine or hydrogen selenide, including Corning monoliths and the Group IB and IIB metal-based materials, showed an ability to capture arsine or hydrogen selenide at 400°F and 600 psig. Based on current testing, the noncarbon metal-based sorbents appear to be the most effective arsine and hydrogen selenide sorbents. The noncarbon sorbent was able to reduce the concentration to 0 ppb from a starting concentration of 120 ppb. This compares to the target value of 5 ppb (~17?g/m3). The EERC-prepared metal-based pellet and coprecipitate sorbents exhibited arsine reductions of 90% or greater, being below 10 ppb. Corning SR Liquid monoliths exhibited brief periods (<1 hour) of attaining 90% arsine reduction but were able to achieve greater than 80% reduction for several hours. With respect to hydrogen selenide, all Group IB and IIB metal-based sorbents tested exhibited 100% reduction from an inlet concentration of approximately 400 ppb. Corning SR Liquid monoliths exhibited an 82% reduction when two monoliths were tested simultaneously in series.

  14. Comparative assessment of the trace-element composition of coals, crude oils, and oil shales

    SciTech Connect (OSTI)

    M.Y. Shpirt; S.A. Punanova [Institute for Fossil Fuels, Moscow (Russian Federation)

    2007-10-15T23:59:59.000Z

    A comparative analysis of the amounts of 42 trace elements in coals, crude oils, and oil and black shales was performed. The degree of concentration of trace elements by caustobioliths and their ashes relative to their abundance in argillaceous rocks and the Earth's crust was calculated. Typomorphic trace elements were distinguished, of which many turned out to be common for the different kinds of caustobioliths in question. The trace elements were classified according to their concentration factors in different caustobioliths. The ash of crude oils is enriched in trace elements (Cs, V, Mo, Cu, Ag, Au, Zn, Hg, Se, Cr, Co, Ni, U) to the greatest extent (concentration factor above 3.5) and that of oil shales is enriched to the least extent (Re, Cs, Hg, Se). The ratios between typomorphic trace elements in general strongly differ from those in the Earth's crust and argillaceous rocks and are not identical in different caustobioliths. Quantitative parameters that make it possible to calculate a change in these ratios on passing from one caustobiolith type to another were proposed and the relative trace-element affinity of different caustobioliths was estimated.

  15. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D. (Alliance, OH); Downs, William (Alliance, OH); Jankura, Bryan J. (Mogadore, OH); McCoury, Jr., John M. (Mineral City, OH)

    1990-01-01T23:59:59.000Z

    An apparatus and method for sampling gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extends in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  16. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D. (Alliance, OH); Downs, William (Alliance, OH); Jankura, Bryan J. (Mogadore, OH); McCoury, Jr., John M. (Mineral City, OH)

    1989-01-01T23:59:59.000Z

    An apparatus and method for sampling a gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extend in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  17. Advanced Water-Gas Shift Membrane Reactor

    SciTech Connect (OSTI)

    Sean Emerson; Thomas Vanderspurt; Susanne Opalka; Rakesh Radhakrishnan; Rhonda Willigan

    2009-01-07T23:59:59.000Z

    The overall objectives for this project were: (1) to identify a suitable PdCu tri-metallic alloy membrane with high stability and commercially relevant hydrogen permeation in the presence of trace amounts of carbon monoxide and sulfur; and (2) to identify and synthesize a water gas shift catalyst with a high operating life that is sulfur and chlorine tolerant at low concentrations of these impurities. This work successfully achieved the first project objective to identify a suitable PdCu tri-metallic alloy membrane composition, Pd{sub 0.47}Cu{sub 0.52}G5{sub 0.01}, that was selected based on atomistic and thermodynamic modeling alone. The second objective was partially successful in that catalysts were identified and evaluated that can withstand sulfur in high concentrations and at high pressures, but a long operating life was not achieved at the end of the project. From the limited durability testing it appears that the best catalyst, Pt-Re/Ce{sub 0.333}Zr{sub 0.333}E4{sub 0.333}O{sub 2}, is unable to maintain a long operating life at space velocities of 200,000 h{sup -1}. The reasons for the low durability do not appear to be related to the high concentrations of H{sub 2}S, but rather due to the high operating pressure and the influence the pressure has on the WGS reaction at this space velocity.

  18. Sorbents for mercury capture from fuel gas with application to gasification systems

    SciTech Connect (OSTI)

    Granite, E.J.; Myers, C.R.; King, W.P.; Stanko, D.C.; Pennline, H.W. [US DOE, Pittsburgh, PA (United States)

    2006-06-21T23:59:59.000Z

    In regard to gasification for power generation, the removal of mercury by sorbents at elevated temperatures preserves the higher thermal efficiency of the integrated gasification combined cycle system. Unfortunately, most sorbents display poor capacity for elemental mercury at elevated temperatures. Previous experience with sorbents in flue gas has allowed for judicious selection of potential high-temperature candidate sorbents. The capacities of many sorbents for elemental mercury from nitrogen, as well as from four different simulated fuel gases at temperatures of 204-371{sup o}C, have been determined. The simulated fuel gas compositions contain varying concentrations of carbon monoxide, hydrogen, carbon dioxide, moisture, and hydrogen sulfide. Promising high-temperature sorbent candidates have been identified. Palladium sorbents seem to be the most promising for high-temperature capture of mercury and other trace elements from fuel gases. A collaborative research and development agreement has been initiated between the Department of Energy's National Energy Technology Laboratory (NETL) and Johnson Matthey for optimization of the sorbents for trace element capture from high-temperature fuel gas. Future directions for mercury sorbent development for fuel gas application will be discussed.

  19. Distributed trace using central performance counter memory

    DOE Patents [OSTI]

    Satterfield, David L; Sexton, James C

    2013-10-22T23:59:59.000Z

    A plurality of processing cores, are central storage unit having at least memory connected in a daisy chain manner, forming a daisy chain ring layout on an integrated chip. At least one of the plurality of processing cores places trace data on the daisy chain connection for transmitting the trace data to the central storage unit, and the central storage unit detects the trace data and stores the trace data in the memory co-located in with the central storage unit.

  20. Distributed trace using central performance counter memory

    DOE Patents [OSTI]

    Satterfield, David L.; Sexton, James C.

    2013-01-22T23:59:59.000Z

    A plurality of processing cores, are central storage unit having at least memory connected in a daisy chain manner, forming a daisy chain ring layout on an integrated chip. At least one of the plurality of processing cores places trace data on the daisy chain connection for transmitting the trace data to the central storage unit, and the central storage unit detects the trace data and stores the trace data in the memory co-located in with the central storage unit.

  1. LEARNING FROM BULLYING TRACES IN SOCIAL MEDIA

    E-Print Network [OSTI]

    Zhu, Xiaojin "Jerry"

    of bullying traces collected Lady Gaga Movie: Bully #12;Questions NLP Can Help with 8 Is the post a bullying

  2. Multi-Gas Assessment of the Kyoto Protocol John Reilly,*

    E-Print Network [OSTI]

    Multi-Gas Assessment of the Kyoto Protocol John Reilly,* Ronald G. Prinn,* Jochen Harnisch,* Jean in the protocol appear to be an adequate representation of trace gas climatic effects. The principal reason for the success of this simplified GWP approach in our calculations is that the mix of gas emissions resulting

  3. Casimir Effect and Trace formula Andreas Wirzba

    E-Print Network [OSTI]

    Wirzba, Andreas - Helmholtz-Institut für Strahlen- und Kernphysik (HISKP)

    1 Casimir Effect and Trace formula Andreas Wirzba Institut f¨ur Kernphysik Forschungszentrum J¨ulich · · Andreas Wirzba Casimir effect and trace formula Copenhagen, 17 May 2006 #12;1 Casimir Effect and Trace formula Andreas Wirzba Institut f¨ur Kernphysik Forschungszentrum J¨ulich 1. Introduction to the Casimir

  4. Measurements and Analyses of Urban Metabolism and Trace Gas Respiration

    E-Print Network [OSTI]

    McManus, J.B.

    2002-05-30T23:59:59.000Z

    Human society has well defined metabolic processes that can be characterized and quantified in the same way that an ecosystem’s metabolism can be defined and understood [Fischer-Kowalski, 1998.] The study of “industrial ...

  5. Trace Explosive Detection Using Nanosensors

    SciTech Connect (OSTI)

    Senesac, Larry R [ORNL; Thundat, Thomas George [ORNL

    2008-01-01T23:59:59.000Z

    Selective and sensitive detection of explosives is very important in countering terrorist threats. Detecting trace explosives has become a very complex and expensive endeavor because of a number of factors, such as the wide variety of materials that can be used as explosives, the lack of easily detectable signatures, the vast number of avenues by which these weapons can be deployed, and the lack of inexpensive sensors with high sensitivity and selectivity. High sensitivity and selectivity, combined with the ability to lower the deployment cost of sensors using mass production, is essential in winning the war on explosives-based terrorism. Nanosensors have the potential to satisfy all the requirements for an effective platform for the trace detection of explosives.

  6. Increased stray gas abundance in a subset of drinking water wells near Marcellus shale gas extraction

    E-Print Network [OSTI]

    Jackson, Robert B.

    Increased stray gas abundance in a subset of drinking water wells near Marcellus shale gas Pennsylvania, ex- amining natural gas concentrations and isotopic signatures with proximity to shale gas wells this transformation, with shale gas and other unconventional sources now yielding more than one- half of all US

  7. Monitoring hydrocarbons and trace metals in Beaufort Sea sediments and organisms. Final report

    SciTech Connect (OSTI)

    Boehm, P.; LeBlanc, L.; Trefry, J.; Marajh-Whittemore, P.; Brown, J.

    1990-10-01T23:59:59.000Z

    As part of the Minerals Management Service's environmental studies of oil and gas exploration and production activities in the Alaskan Beaufort Sea, a study was conducted in 1989 to monitor the marine environment for inputs of chemicals related to drilling and exploration. The 1989 Beaufort Sea Monitoring Program (BSMP) was designed to monitor sediments and selected benthic organisms for trace metals and hydrocarbons so as to infer any changes that might have resulted from drilling and production activities. A series of 49 stations were sampled during the program. The study area extended from Cape Halkett on the western end of Harrison Bay to Griffin Point, east of Barter Island. The sampling design combined an area-wide approach in which stations were treated as replicates of 8 specific geographic regions, with an activity-specific approach, which focused on the potential establishment of metal or hydrocarbon concentration gradients with distance from the Endicott Production Field in Prudhoe Bay. The analytical program focused on the analysis of the fine-fraction of the sediment for a series of trace metals and elements and the analysis of a suite of saturated and aromatic hydrocarbons in the bulk sediment. The total organic carbon (TOB) content and the grain size distribution in the sediments were determined as well. Benthic bivalve molluscs, representative of several feeding types were collected from those stations for which data previously existed from the 1984-1986 BSMP, and were analyzed for metals and saturated and aromatic hydrocarbons. The benthic amphipods were collected, pooled by station or region, and analyzed as well.

  8. Refinery gas waste heat energy conversion optimization in gas turbines

    SciTech Connect (OSTI)

    Rao, A.D.; Francuz, D.J.; West, E.W. [Fluor Daniel, Inc., Irvine, CA (United States)

    1996-12-31T23:59:59.000Z

    Utilization of refinery fuel gas in gas turbines poses special challenges due to the combustion characteristics of the fuel gas which contains significant concentrations of hydrogen. Proper modifications to the combustion system of the existing gas turbines are required in order to combust such fuel gas streams in gas turbines while minimizing the NO{sub x} emissions. A novel approach to the utilization of this hydrogen bearing fuel gas in gas turbines consists of humidifying the fuel gas with water vapor by direct contact with hot water in a counter-current column, the feed water to the humidifier being first circulated through the refinery to recover waste heat. The refinery waste heat produces additional motive fluid with a result that the waste heat is converted to power in the gas turbine. Furthermore, the water vapor introduced into the fuel gas reduces the NO{sub x} formation and increases the gas turbine output, while the hydrogen present in the fuel gas provides the flame stability required when combusting a fuel gas containing a large concentration of water vapor.

  9. Trace element emissions. Semi-annual report, October 1994--February 1995

    SciTech Connect (OSTI)

    Pigeaud, A.; Maru, H.; Wilemski, G.; Helble, J.

    1995-02-01T23:59:59.000Z

    Many trace elements can exist in raw coal gas either in the form of metallic vapors or gaseous compounds which, besides their action on potentially ``very clean`` advanced power generating systems such as fuel cells and gas turbines, can also be detrimental to plant and animal life when released into the atmosphere. Therefore, volatile trace contaminants from coal which can also be toxic must be removed before they become detrimental to both power plant performance/endurance and the environment. Five trace elements were selected in this project based on: abundance in solid coal, volatility during gasification, effects on downstream systems and toxicity to plant and animal life. An understanding was sought in this investigation of the interactions of these five trace elements (and their high temperature species) with the different components in integrated cleanup and power generating systems, as well as the ultimate effects with respect to atmospheric emissions. Utilizing thermodynamic calculations and various experimental techniques, it was determined that a number of trace contaminants that exist in coal may be substantially removed by flyash, and after that by different sorbent systems. High temperature cleanup of contaminants by sorbents such as zinc titanate, primarily to remove sulfur, can also absorb some metallic contaminants such as cadmium and antimony. Further polishing will be required, however, to eliminate trace contaminant species incorporating the elements arsenic, selemium, lead, and mercury.

  10. evaluation-concentrated-piperazine | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concentrated Piperazine for CO2 Capture from Coal-Fired Flue Gas Project No.: DE-FE0005654 URS Group, Inc. will investigate the use of concentrated piperazine (PZ) as a solvent for...

  11. Production of fullerenes using concentrated solar flux

    DOE Patents [OSTI]

    Fields, Clark L. (Greeley, CO); Pitts, John Roland (Lakewood, CO); King, David E. (Lakewood, CO); Hale, Mary Jane (Golden, CO); Bingham, Carl E. (Denver, CO); Lewandowski, Allan A. (Evergreen, CO)

    2000-01-01T23:59:59.000Z

    A method of producing soot containing high amounts of fullerenes comprising: providing a primary concentrator capable of impingement of a concentrated beam of sunlight onto a carbon source to cause vaporization of carbon and subsequent formation of fullerenes, or providing a solar furnace having a primary concentrator with a focal point that concentrates a solar beam of sunlight; providing a reflective secondary concentrator having an entrance aperture and an exit aperture at the focal point of the solar furnace; providing a carbon source at the exit aperture of the secondary concentrator; supplying an inert gas over the carbon source to keep the secondary concentrator free from vaporized carbon; and impinging a concentrated beam of sunlight from the secondary concentrator on the carbon source to vaporize the carbon source into a soot containing high amounts of fullerenes.

  12. The Natural Aerodynamic Sampling of Trace Explosives from the Human Body

    E-Print Network [OSTI]

    Settles, Gary S.

    The Natural Aerodynamic Sampling of Trace Explosives from the Human Body Gary S. Settles, Huban A. Gowadia, Sean B. Strine, and Timothy E. Johnson Gas Dynamics Lab, Mechanical Engineering Dept., 301D Reber developed for this purpose, their widespread use may be too slow for airport security use and may

  13. Trace Holdings | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlin Baxin Hydropower StationTown ofTown ofTown ofTrace Holdings Jump to:

  14. Trace Metal Source Terms in Carbon Sequestration Environments

    SciTech Connect (OSTI)

    Karamalidis, Athanasios K.; Torres, Sharon G.; Hakala, J. Alexandra; Shao, Hongbo; Cantrell, Kirk J.; Carroll, Susan

    2013-01-01T23:59:59.000Z

    Carbon dioxide sequestration in deep saline and depleted oil geologic formations is feasible and promising, however, possible CO{sub 2} or CO{sub 2}-saturated brine leakage to overlying aquifers may pose environmental and health impacts. The purpose of this study was to experimentally define trace metal source terms from the reaction of supercritical CO{sub 2}, storage reservoir brines, reservoir and cap rocks. Storage reservoir source terms for trace metals are needed to evaluate the impact of brines leaking into overlying drinking water aquifers. The trace metal release was measured from sandstones, shales, carbonates, evaporites, basalts and cements from the Frio, In Salah, Illinois Basin – Decatur, Lower Tuscaloosa, Weyburn-Midale, Bass Islands and Grand Ronde carbon sequestration geologic formations. Trace metal dissolution is tracked by measuring solution concentrations over time under conditions (e.g. pressures, temperatures, and initial brine compositions) specific to the sequestration projects. Existing metrics for Maximum Contaminant Levels (MCLs) for drinking water as defined by the U.S. Environmental Protection Agency (U.S. EPA) were used to categorize the relative significance of metal concentration changes in storage environments due to the presence of CO{sub 2}. Results indicate that Cr and Pb released from sandstone reservoir and shale cap rock exceed the MCLs by an order of magnitude while Cd and Cu were at or below drinking water thresholds. In carbonate reservoirs As exceeds the MCLs by an order of magnitude, while Cd, Cu, and Pb were at or below drinking water standards. Results from this study can be used as a reasonable estimate of the reservoir and caprock source term to further evaluate the impact of leakage on groundwater quality.

  15. Point-focus spectral splitting solar concentrator for multiple cells concentrating photovoltaic system

    E-Print Network [OSTI]

    Maragliano, Carlo; Stefancich, Marco

    2015-01-01T23:59:59.000Z

    In this paper we present and experimentally validate a low-cost design of a spectral splitting concentrator for the efficient conversion of solar energy. The optical device consists of a dispersive prismatic lens made of polycarbonate designed to simultaneously concentrate the solar light and split it into its spectral components. With respect to our previous implementation, this device concentrates the light along two axes and generates a light pattern compatible with the dimensions of a set of concentrating photovoltaic cells while providing a higher concentration ratio. The mathematical framework and the constructive approach used for the design are presented and the device performance is simulated using ray-tracing software. We obtain spectral separation in the visible range within a 3x1 cm2 area and a maximum concentration of 210x for a single wavelength. The device is fabricated by injection molding and its performance is experimentally investigated. We measure an optical transmissivity above 90% in the...

  16. The behavior of trace metals in the Geum Estuary, Korea

    SciTech Connect (OSTI)

    Byrd, J.T.; Smith, R.G.; Windom, H.L. (Skidaway Inst. of Oceanography, Savannah, GA (United States)); Lee, Kwang, W. (Hanyang Univ. Ansan, Kyunggi (Korea)); Lee, Dong, S. (Korea Ocean Research and Development Inst., Ansan, Kyunggi (Korea))

    1991-05-01T23:59:59.000Z

    The distributions of trace metals in the Geum Estuary of western Korea were studied with regard to changes in other estuarine chemical parameters. Dissolved oxygen, pH, and alkalinity increased with increasing salinity. Dissolved aluminum concentrations increased at low salinities and were perhaps influenced by the solubility of particulate aluminosilicate phases. Iron, manganese, cobalt, and zinc are removed from solution in the low salinity end of the estuary. Cobalt and nickel have mid-estuary concentration maxima that may be due to an anthropogenic source. Cadmium, copper, lead, and zinc concentrations also increased in the estuary, possibly as th result of remobilization in the sediments. Cadmium increases are also linked to remineralization from tidal flat sediments in the outer estuary. The source of an increase in dissolved lead at low salinity is unclear, but may be due to release from particles.

  17. Traces on Module Categories over Fusion Categories

    E-Print Network [OSTI]

    Gregor Schaumann

    2015-01-27T23:59:59.000Z

    We consider traces on module categories over pivotal fusion categories which are compatible with the module structure. It is shown that such module traces characterise the Morita classes of special haploid symmetric Frobenius algebras. Moreover, they are unique up to a scale factor and they equip the dual category with a pivotal structure. This implies that for each pivotal structure on a fusion category over the complex numbers there exists a conjugate pivotal structure defined by the canonical module trace.

  18. Automated gas chromatography

    DOE Patents [OSTI]

    Mowry, Curtis D. (Albuquerque, NM); Blair, Dianna S. (Albuquerque, NM); Rodacy, Philip J. (Albuquerque, NM); Reber, Stephen D. (Corrales, NM)

    1999-01-01T23:59:59.000Z

    An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute.

  19. Geothermal: Sponsored by OSTI -- Trace metal characterization...

    Office of Scientific and Technical Information (OSTI)

    Trace metal characterization and speciation in geothermal effluent by multiple scanning anodic stripping voltammetry and atomic absorpotion analysis. Annual progress report...

  20. Reactive trace metals in the stratified central North Pacific

    SciTech Connect (OSTI)

    Bruland, K.W. (Univ. of California, Santa Cruz, CA (United States)); Orians, K.J. (Univ. of British Columbia, Vancouver (Canada)); Cowen, J.P. (Univ. of Hawaii, Manoa, HI (United States))

    1994-08-01T23:59:59.000Z

    Vertical concentration profiles of the dissolved and suspended particulate phases were determined for a suite of reactive trace metals, Al, Fe, Mn, Zn, and Cd, during summertime at a station in the center of the North Pacific gyre. During summer the euphotic zone becomes stratified, forming a shallow (0-25 m), oligotrophic, mixed layer overlying a subsurface (25-140 m), strongly-stratified region. The physical, biological, and chemical structure within the euphotic zone during this period enhanced the effect of atmospheric inputs of Al, Fe, and Mn on mixed layer concentrations. For example, the concentration of dissolved Fe in the surface mixed layer was eighteen times that observed at a depth of 100 m. The observed aeolian signature of these metals matched that predicted from estimates of atmospheric input during the period between the onset of stratification and sampling. The distributions of suspended particulate Al, Fe, and Mn all exhibited minima in the euphotic zone and increased with depth into the main thermocline. Particulate Al and Fe were then uniform with depth below 1000 m before increasing in the near bottom nepheloid layer. Average particulate phase concentrations in intermediate and deep waters of the central North Pacific were 1.0, 0.31, and 0.055 nmol[center dot]kg[sup [minus]1] for Al, Fe, and Mn, respectively. The distribution of particulate Cd exhibited a maximum within the subsurface euphotic zone. Particulate zinc also exhibited a surface maximum, albeit a smaller one. Concentrations of particulate Zn and Cd in intermediate and deep waters were 17 and 0.2 pmol[center dot]kg[sup [minus]1]. Substantial interbasin differences in particulate trace metals occur. Concentrations of suspended particulate Al, Fe, and Mn were three to four times lower in the central North Pacific than recently reported for the central North Atlantic gyre, consistent with differences in atmospheric input to these two regions.

  1. Gas storage and separation by electric field swing adsorption

    DOE Patents [OSTI]

    Currier, Robert P; Obrey, Stephen J; Devlin, David J; Sansinena, Jose Maria

    2013-05-28T23:59:59.000Z

    Gases are stored, separated, and/or concentrated. An electric field is applied across a porous dielectric adsorbent material. A gas component from a gas mixture may be selectively separated inside the energized dielectric. Gas is stored in the energized dielectric for as long as the dielectric is energized. The energized dielectric selectively separates, or concentrates, a gas component of the gas mixture. When the potential is removed, gas from inside the dielectric is released.

  2. Concentrating Solar Power Forum Concentrating Photovoltaics (Presentation)

    SciTech Connect (OSTI)

    Kurtz, S.

    2008-05-06T23:59:59.000Z

    This presentation's summaries: a convenient truth, comparison of three concentrator technologies, value of high efficiency, and status of industry.

  3. Trace elements in coal by glow discharge mass spectrometry

    SciTech Connect (OSTI)

    Jacobs, M.L.; Wilson, C.R.; Pestovich, J. Jr. [WAL Inc., Wheat Ridge, CO (United States)] [and others

    1995-08-01T23:59:59.000Z

    A need and a demand exist for determining trace elements in coal and coal related by-products, especially those elements which may potentially be a health hazard. The provisions of the 1990 clean air act require that the EPA evaluate the emissions of electric utilities for trace elements and other potentially hazardous organic compounds. The coal fired electric utility industry supplies roughly 60% of the total generating capacity of 2,882,525 million kilowatt hours (nearly 3 trillion kilowatt hours) generated in the U.S. This is accomplished by 414 power plants scattered across the country that burned 813,508,000 short tons of coal in 1993. The relative volatility of some inorganic constituents in coal makes them more prone to be emitted to the atmosphere following combustion. The production of analytical data for trace elements is known to be a difficult task in coal and by-products of coal combustion (fly ash, bottom ash, gas streams, etc.), in terms of both sample collection and analytical determinations. There are several common analytical methods available to the analyst to determine trace elements in coal and coal by-products. In general analytical germs, the material to be analyzed can be totally solubilized (or extracted), or the elements analytes can be determined in the material as a solid. A relatively new elemental technique, Glow Discharge Mass Spectrometry (GDMS) can be used with solids as well. This new analytical technique had never before been applied directly to coal. The radio frequency-glow discharge quadropole mass spectrometer was used to analyze coal directly for the first time ever by rf-GDMS. The rf-GDMS technique is described.

  4. Estimating the benefits of greenhouse gas emission reduction from agricultural policy reform

    SciTech Connect (OSTI)

    Adger, W.N. (Univ. of East Anglia, Norwich (United Kingdom). Centre for Social and Economic Research on the Global Environment); Moran, D.C. (Univ. College, London (United Kingdom). Centre for Social and Economic Research on the Global Environment)

    1993-09-01T23:59:59.000Z

    Land use and agricultural activities contribute directly to the increased concentrations of atmospheric greenhouse gases. Economic support in industrialized countries generally increases agriculture's contribution to global greenhouse gas concentrations through fluxes associated with land use change and other sources. Changes in economic support offers opportunities to reduce net emissions, through this so far has gone unaccounted. Estimates are presented here of emissions of methane from livestock in the UK and show that, in monetary terms, when compared to the costs of reducing support, greenhouse gases are a significant factor. As signatory parties to the Climate Change Convection are required to stabilize emissions of all greenhouse gases, options for reduction of emissions of methane and other trace gases from the agricultural sector should form part of these strategies.

  5. Method for mapping a natural gas leak

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2009-02-03T23:59:59.000Z

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formatted into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimposed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  6. An atom trap trace analysis (ATTA) system for measuring ultra-low contamination by krypton in

    E-Print Network [OSTI]

    Zelevinsky, Tanya

    An atom trap trace analysis (ATTA) system for measuring ultra-low contamination by krypton in xenon ultra-low contamination by krypton in xenon dark matter detectors Tae Hyun Yoon The XENON dark matter analysis (ATTA) device to detect the ultra-low kryp- ton concentration in the xenon target. This project

  7. Concentrating Photovoltaics (Presentation)

    SciTech Connect (OSTI)

    Kurtz, S.

    2009-01-20T23:59:59.000Z

    Solar is growing rapidly, and the concentrating photovoltaics industry-both high- and low-concentration cell approaches-may be ready to ramp production in 2009.

  8. Concentrated Solar Thermoelectric Power

    Broader source: Energy.gov (indexed) [DOE]

    CONCENTRATING SOLAR POWER PROGRAM REVIEW 2013 Concentrated Solar Thermoelectric Power Principal Investigator: Prof. Gang Chen Massachusetts Institute of Technology Cambridge, MA...

  9. Indriect Measurement Of Nitrogen In A Mult-Component Natural Gas By Heating The Gas

    DOE Patents [OSTI]

    Morrow, Thomas B. (San Antonio, TX); Behring, II, Kendricks A. (Torrance, CA)

    2004-06-22T23:59:59.000Z

    Methods of indirectly measuring the nitrogen concentration in a natural gas by heating the gas. In two embodiments, the heating energy is correlated to the speed of sound in the gas, the diluent concentrations in the gas, and constant values, resulting in a model equation. Regression analysis is used to calculate the constant values, which can then be substituted into the model equation. If the diluent concentrations other than nitrogen (typically carbon dioxide) are known, the model equation can be solved for the nitrogen concentration.

  10. Method for remote detection of trace contaminants

    DOE Patents [OSTI]

    Simonson, Robert J.; Hance, Bradley G.

    2003-09-09T23:59:59.000Z

    A method for remote detection of trace contaminants in a target area comprises applying sensor particles that preconcentrate the trace contaminant to the target area and detecting the contaminant-sensitive fluorescence from the sensor particles. The sensor particles can have contaminant-sensitive and contaminant-insensitive fluorescent compounds to enable the determination of the amount of trace contaminant present in the target are by relative comparison of the emission of the fluorescent compounds by a local or remote fluorescence detector. The method can be used to remotely detect buried minefields.

  11. Infrared near-field spectroscopy of trace explosives using an...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spectroscopy of trace explosives using an external cavity quantum cascade laser. Infrared near-field spectroscopy of trace explosives using an external cavity quantum cascade...

  12. Workshop on L-functions and Trace Formula

    E-Print Network [OSTI]

    Ali Altug, Columbia University: Trace formula beyond endoscopy and analytic number theory. I will talk about trace formula and analytic number theory, and how ...

  13. Feasibility of the detection of trace elements in particulate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of trace elements in particulate matter using online High-Resolution Aerosol Mass Spectrometry. Feasibility of the detection of trace elements in particulate matter using online...

  14. atom trap trace: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 An atom trap trace analysis system for measuring krypton contamination in xenon dark matter detectors Physics Websites Summary: An atom trap trace analysis system for measuring...

  15. Radionuclides, Trace Metals, and Organic Compounds in Shells of Native Freshwater Mussels Along the Hanford Reach of the Columbia River: 6000 Years Before Present to Current Times

    SciTech Connect (OSTI)

    B. L. Tiller; T. E. Marceau

    2006-01-25T23:59:59.000Z

    This report documents concentrations of radionuclides, trace metals, and semivolatile organic compounds measured in shell samples of the western pearl shell mussel collected along the Hanford Reach of the Columbia River.

  16. Retained Gas Sampler Calibration and Simulant Tests

    SciTech Connect (OSTI)

    CRAWFORD, B.A.

    2000-01-05T23:59:59.000Z

    This test plan provides a method for calibration of the retained gas sampler (RGS) for ammonia gas analysis. Simulant solutions of ammonium hydroxide at known concentrations will be diluted with isotopically labeled 0.04 M ammonium hydroxide solution. Sea sand solids will also be mixed with ammonium hydroxide solution and diluent to determine the accuracy of the system for ammonia gas analysis.

  17. Laser cross-flow gas system

    DOE Patents [OSTI]

    Duncan, D.B.

    1992-11-24T23:59:59.000Z

    A method and laser apparatus are disclosed which provide for a cross-flow of gas near one end of a laser discharge tube. The cross-flow of gas causes a concentration gradient which affects diffusion of contaminants in the discharge tube towards the cross-flow of the gas, which contaminants are then withdrawn from the discharge tube. 1 figure.

  18. Privacy Vulnerability of Published Anonymous Mobility Traces

    E-Print Network [OSTI]

    2010-07-07T23:59:59.000Z

    Sep 20, 2010 ... locations of real users leading to the public availabilities of many such traces through .... infer the private information. ... are open to observations in public spaces. Hence, the ..... value is called the entropy rate of the process X.

  19. RESTRICTED-TRACE APPROXIMATION FOR NUCLEAR ANTIFERROMAGNETISM

    E-Print Network [OSTI]

    Boyer, Edmond

    1353 RESTRICTED-TRACE APPROXIMATION FOR NUCLEAR ANTIFERROMAGNETISM M. GOLDMAN and G. SARMA Service to predict several properties of nuclear antiferromagnetic structures : sublattice magnetization of nuclear dipolar magnetic ordering, either antiferromagnetic or ferromagnetic, has been reported

  20. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

    1984-01-01T23:59:59.000Z

    A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  1. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, M.; Wai, C.M.; Nagy, Z.

    1983-08-15T23:59:59.000Z

    A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  2. Combining Multicomponent Seismic Attributes, New Rock Physics Models, and In Situ Data to Estimate Gas-Hydrate Concentrations in Deep-Water, Near-Seafloor Strata of the Gulf of Mexico

    SciTech Connect (OSTI)

    Bureau of Economic Geology

    2009-04-30T23:59:59.000Z

    The Bureau of Economic Geology was contracted to develop technologies that demonstrate the value of multicomponent seismic technology for evaluating deep-water hydrates across the Green Canyon area of the Gulf of Mexico. This report describes the methodologies that were developed to create compressional (P-P) and converted-shear (P-SV) images of near-seafloor geology from four-component ocean-bottom-cable (4C OBC) seismic data and the procedures used to integrate P-P and P-SV seismic attributes with borehole calibration data to estimate hydrate concentration across two study areas spanning 16 and 25 lease blocks (or 144 and 225 square miles), respectively. Approximately 200 km of two-dimensional 4C OBC profiles were processed and analyzed over the course of the 3-year project. The strategies we developed to image near-seafloor geology with 4C OBC data are unique, and the paper describing our methodology was peer-recognized with a Best Paper Award by the Society of Exploration Geophysicists in the first year of the project (2006). Among the valuable research findings demonstrated in this report, the demonstrated ability to image deep-water near-seafloor geology with sub-meter resolution using a standard-frequency (10-200 Hz) air gun array on the sea surface and 4C sensors on the seafloor has been the accomplishment that has received the most accolades from professional peers. Our study found that hydrate is pervasive across the two study areas that were analyzed but exists at low concentrations. Although our joint inversion technique showed that in some limited areas, and in some geologic units across those small areas, hydrates occupied up to 40-percent of the sediment pore space, we found that when hydrate was present, hydrate concentration tended to occupy only 10-percent to 20-percent of the pore volume. We also found that hydrate concentration tended to be greater near the base of the hydrate stability zone than it was within the central part of the stability zone.

  3. Trace element analysis of Texas lignite

    E-Print Network [OSTI]

    Mahar, Sean

    1982-01-01T23:59:59.000Z

    or in the planning stages, Near surface lignite re- sources are estimated to be 21 billion metric tons in Texas, while deep basin reserves are estimated at 31 billion metric tons. Near (3] surface reserves alone could fulfill Texas' electrical needs for 100 years... for environmental and health concerns trace element characterization of lignites is important. A needed avenue of research is charact- erization of trace element pathways in lignite fired power plants. :hat is to say what percentage of a certain element...

  4. Methodology for flammable gas evaluations

    SciTech Connect (OSTI)

    Hopkins, J.D., Westinghouse Hanford

    1996-06-12T23:59:59.000Z

    There are 177 radioactive waste storage tanks at the Hanford Site. The waste generates flammable gases. The waste releases gas continuously, but in some tanks the waste has shown a tendency to trap these flammable gases. When enough gas is trapped in a tank`s waste matrix, it may be released in a way that renders part or all of the tank atmosphere flammable for a period of time. Tanks must be evaluated against previously defined criteria to determine whether they can present a flammable gas hazard. This document presents the methodology for evaluating tanks in two areas of concern in the tank headspace:steady-state flammable-gas concentration resulting from continuous release, and concentration resulting from an episodic gas release.

  5. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect (OSTI)

    MEIYU SHEN; ROYCE ABBOTT; T.D. WHEELOCK

    1998-09-30T23:59:59.000Z

    The agglomeration of ultrafine-size coal particles in an aqueous suspension by means of microscopic gas bubbles was demonstrated in numerous experiments with a scale model mixing system. Coal samples from both the Pittsburgh No. 8 Seam and the Upper Freeport Seam were used for these experiments. A small amount of i-octane was added to facilitate the process. Microscopic gas bubbles were generated by saturating the water used for suspending coal particles with gas under pressure and then reducing the pressure. Microagglomerates were produced which appeared to consist of gas bubbles encapsulated in coal particles. Since dilute particle suspensions were employed, it was possible to monitor the progress of agglomeration by observing changes in turbidity. By such means it became apparent that the rate of agglomeration depends on the concentration of microscopic gas bubbles and to a lesser extent on the concentration of i-octane. Similar results were obtained with both Pittsburgh No. 8 coal and Upper Freeport coal.

  6. Indirect measurement of diluents in a multi-component natural gas

    DOE Patents [OSTI]

    Morrow, Thomas B.; Owen, Thomas E.

    2006-03-07T23:59:59.000Z

    A method of indirectly measuring the diluent (nitrogen and carbon dioxide) concentrations in a natural gas mixture. The molecular weight of the gas is modeled as a function of the speed of sound in the gas, the diluent concentrations in the gas, and constant values, resulting in a model equation. A set of reference gas mixtures with known molecular weights and diluent concentrations is used to calculate the constant values. For the gas in question, if the speed of sound in the gas is measured at three states, the three resulting expressions of molecular weight can be solved for the nitrogen and carbon dioxide concentrations in the gas mixture.

  7. Low-Cost Installation of Concentrating Photovoltaic

    E-Print Network [OSTI]

    .5 megawatt power plant for the Pacific Gas and Electric Company near Tracy, CA ­ the first solar related with system components, and traditional solar designs that limit installation locations. Many offerings. Currently, no solar company provides a complete photovoltaic or concentrating photovoltaic

  8. The trace formula The Langevin process in R

    E-Print Network [OSTI]

    Herrmann, Samuel

    The trace formula The Langevin process in R Symmetric spaces and the Malliavin calculus and the trace formula Jean-Michel Bismut Universit´e Paris-Sud, Orsay `A la m´emoire de Paul Malliavin Jean-Michel Bismut The Malliavin calculus and the trace formula #12;The trace formula The Langevin process in R

  9. Concentrating Solar Power

    SciTech Connect (OSTI)

    Not Available

    2008-09-01T23:59:59.000Z

    Summarizes the goals and activities of the DOE Solar Energy Technologies Program efforts within its concentrating solar power subprogram.

  10. Mid-infrared gas sensing using a photonic bandgap fiber

    E-Print Network [OSTI]

    . The gas filling process of the air core is described, and qualitative methane concentrations measurements. Introduction Sensing of gas species and their concentrations is widely used for process control [1-proven technique requires a spectrometer and a sensing volume (gas cell) in which the light can interact

  11. Characterization of trace element emissions from a pilot-scale coal combustion unit

    SciTech Connect (OSTI)

    Hargis, R.A.; Pennline, H.W. [Dept. of Energy, Pittsburgh, PA (United States). Pittsburgh Energy Technology Center

    1996-12-31T23:59:59.000Z

    The flue gas cleanup projects in the in-house research program at the Pittsburgh Energy Technology Center range from laboratory-scale work to testing with the combustion products of coal at a scale equivalent to about 0.75 MW of electric power generation. The largest unit is a 500-pound-per-hour coal combustor, complete with ductwork, spray dryer, baghouse, and ancillary equipment. Over the past year, tests to investigate the distribution and fate of trace elements have been conducted with this pilot unit. These investigations are an integral component of the Air Toxics and Fine Particulate Control subprogrammatic area of the AR and ET Power Systems Program. The overall effort of this area focuses on the improvement of existing technologies and the development of new technologies for the control of hazardous air pollutants and fine particulates associated with coal combustion. A major endeavor within the subprogram is the characterization of trace elements in flue gas from coal combustion, including a special emphasis on mercury speciation. The study described in this paper examined the results from an investigation on the pilot unit; the distribution of trace elements in the ash streams and flue gas stream, material recoveries for the system, baghouse removal efficiencies, and enrichment of ash particulate. Also, a preliminary comparison between the results from the pilot unit and a full-scale utility that burned coal from the same coal batch is provided.

  12. Photovoltaic concentrator initiative: Concentrator cell development

    SciTech Connect (OSTI)

    Wohlgemuth, J.H.; Narayanan, S. [Solarex Corp., Frederick, MD (US)

    1993-05-01T23:59:59.000Z

    This project involves the development of a large-area, low-cost, high-efficiency concentrator solar cell for use in the Entech 22-sun linear-focus Fresnel lens concentrator system. The buried contact solar cell developed at the University of New South Wales was selected for this project. Both Entech and the University of New South Wales are subcontractors. This annual report presents the program efforts from November 1990 through December 1991, including the design of the cell, development of a baseline cell process, and presentation of the results of preliminary cell processing. Important results include a cell designed for operation in a real concentrator system and substitution of mechanical grooving for the previously utilized laser scribing.

  13. Cyclone Performance for Reducing Biochar Concentrations in Syngas

    E-Print Network [OSTI]

    Saucier, David Shane

    2013-05-28T23:59:59.000Z

    % synthesis gas (syngas) and 20% biochar. The concentration of biochar in the syngas needs to be reduced prior to the direct fueling of an internal combustion engine driving a generator for electricity production. It was estimated that direct fueling...

  14. Environmental Assessment and Metrics for Solar: Case Study of SolFocus Solar Concentrator Systems

    E-Print Network [OSTI]

    Reich-Weiser, Corinne; Dornfeld, David; Horne, Steve

    2008-01-01T23:59:59.000Z

    Greenhouse gas analysis of solar-thermal electricity gen-CdTe Concentrator PV Solar Thermal Wind Coal CC Gas Turbinefor the assessment of thermal solar systems,” Proceedings of

  15. Automated gas chromatography

    DOE Patents [OSTI]

    Mowry, C.D.; Blair, D.S.; Rodacy, P.J.; Reber, S.D.

    1999-07-13T23:59:59.000Z

    An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute. 7 figs.

  16. Local trace formulae for commuting Hamiltonians in Töplitz quantization

    E-Print Network [OSTI]

    Roberto Paoletti

    2015-01-10T23:59:59.000Z

    Let $(M,J,\\omega)$ be a quantizable compact K\\"ahler manifold, with quantizing Hermitian line bundle $(A,h)$, and associated Hardy space $H(X)$, where $X$ is the unit circle bundle. Given a collection of $r$ Poisson commuting quantizable Hamiltonian functions $f_j$ on $M$, there is an induced Abelian unitary action on $H(X)$, generated by certain T\\"oplitz operators naturally induced by the $f_j$'s. As a multi-dimensional analogue of the usual Weyl law and trace formula, we consider the problem of describing the asymptotic clustering of the joint eigenvalues of these T\\"oplitz operators along a given ray, and locally on $M$ the asymptotic concentration of the corresponding joint eigenfunctions. This problem naturally leads to a \\lq directional local trace formula\\rq, involving scaling asymptotics in the neighborhood of certain special loci in $M$. Under natural transversality assumption, we obtain asymptotic expansions related to the local geometry of the Hamiltonian action and flow.

  17. Trace fossil assemblages in selected shelf sandstones

    E-Print Network [OSTI]

    Locke, Kathleen Ann

    1983-01-01T23:59:59.000Z

    and decreasing marine 1nfluence. Individual trace fossil types are more abundant and show a greater d1versity 1n the delta-margin facies; several large, vert1cal crab(?) burrows are P ascot a d th bi g is do 1 t d by ~Ohio o h In the shelf sequences, mostly... ~Zoo h os, f d ly i th iddl -to. outer and outer shelf sequences. Continued study of trace fossils should provide more specific information than the general shelf locations described above. ACKNOWLEDGEMENTS The completion of this thesis marks...

  18. Trace element analysis of Texas lignite 

    E-Print Network [OSTI]

    Mahar, Sean

    1982-01-01T23:59:59.000Z

    . Gluskoter, and N. F. Shimp: Occurence and Distribution of Potentiall Volatile Trace Elements in Coal. Illinois State Geological Survey. Urbana, IL. (July, 1974). 39 [26] Andren, A. W. , D. H. Klein, and Y. Talmi: Selenium in Coal- Fired Plant Emissions.... Envir. Sci. and Tech. , 9:856, (Sept. , 1975). [27] Gluskoter, H. J. , R. R. Ruch, W. G. Miller, R. A. Cahill, G. B. Breher and J, K. Kuhn: Trace Elements in Coal: Occur- rence and Distribution. Illinois State Geological Sur- vey. Urbane, Illinois...

  19. Gas power, its promises and problems

    SciTech Connect (OSTI)

    Seay, J.G.

    1980-02-01T23:59:59.000Z

    In spite of the recent decline in natural gas supply, it is still the dominant domestic source of energy supply and the most widely used fuel in the industrial, commercial, and household sectors. The basic problem of the gas industry is that of finding new supplies cost-competitive with other fuels in order to maintain the delivery of adequate gaseous energy to its customers, utilizing the existing and literally irreplaceable underground transmission and distribution system. The decline in gas supplies is traced to regulation of the field price of natural gas at a level too low to insure continuing additions to reserves at a rate sufficient to balance production. As a result, the US is drawing down its inventory of gas supply. The higher prices for gas in the field established by the Natural Gas Policy Act of 1978 provides additional economic incentives for exploration and development of new natural gas, and it is hoped that the higher prices will elicit new supplies. The US has available a large resource base of gas yet to be discovered, natural gas in unconventional sources, and the potential of additional incremental supplies from gasification of coal, the largest remaining fossil fuel resource.

  20. Assessment of hot gas contaminant control

    SciTech Connect (OSTI)

    Rutkowski, M.D.; Klett, M.G.; Zaharchuk, R.

    1996-12-31T23:59:59.000Z

    The objective of this work is to gather data and information to assist DOE in responding to the NRC recommendation on hot gas cleanup by performing a comprehensive assessment of hot gas cleanup systems for advanced coal-based Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) including the status of development of the components of the hot gas cleanup systems, and the probable cost and performance impacts. The scope and time frame of information gathering is generally responsive to the boundaries set by the National Research council (NRC), but includes a broad range of interests and programs which cover hot gas cleanup through the year 2010. As the status of hot gas cleanup is continually changing, additional current data and information are being obtained for this effort from this 1996 METC Contractors` Review Meeting as well as from the 1996 Pittsburgh Coal Conference, and the University of Karlsruhe Symposium. The technical approach to completing this work consists of: (1) Determination of the status of hot gas cleanup technologies-- particulate collection systems, hot gas desulfurization systems, and trace contaminant removal systems; (2) Determination of hot gas cleanup systems cost and performance sensitivities. Analysis of conceptual IGCC and PFBC plant designs with hot gas cleanup have been performed. The impact of variations in hot gas cleanup technologies on cost and performance was evaluated using parametric analysis of the baseline plant designs and performance sensitivity.

  1. Micro-PIXE Analysis of Trace Elements in Sulfides

    SciTech Connect (OSTI)

    Hickmott, D.D.; Wetteland, C. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Stimac, J. [Philippine Geothermal, Makati City, (Philippines); Larocque, A.C.L. [Dept. of Geol. Sci., Univ. Manitoba, Winnipeg, MB, R3T 2N2 (Canada); Brearley, A. [Dept. Earth and Planet. Sci., Univ. New Mexico, Albuquerque, NM 87131 (United States)

    2003-08-26T23:59:59.000Z

    Micro-scale Proton-induced X-ray Emission (PIXE) of trace elements (TE) in sulfides provides insights into geologic processes including magmatic system evolution, ore forming events, and fluid-flow processes. The Los Alamos nuclear microprobe was used to determine TE concentrations and ratios in sulfides from diverse geologic environments including hydrothermal ore deposits, coal seams, and metamorphic rocks. Pyrrhotite (Po) from silicic volcanics contains high Cu and Ni; Po from the Clear Lake volcanic field has higher Mo than does Po from other volcanic fields. Coal pyrites contain high Cu, As, Se, Mo and Pb, and show high As/Se and Mo/Se in marine influenced sulfides from the Lower Kittanning coal, but not in other marine-influenced coals. Sulfides are amenable to micro-PIXE studies because of the difficulties in obtaining the homogeneous standards required for many other TE microanalytical techniques.

  2. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    SciTech Connect (OSTI)

    Michael L. Swanson; Grant E. Dunham; Mark A. Musich

    2007-02-01T23:59:59.000Z

    Three potential additives for controlling mercury emissions from syngas at temperatures ranging from 350 to 500 F (177 to 260 C) were developed. Current efforts are being directed at increasing the effective working temperature for these sorbents and also being able to either eliminate any potential mercury desorption or trying to engineer a trace metal removal system that can utilize the observed desorption process to repeatedly regenerate the same sorbent monolith for extended use. Project results also indicate that one of these same sorbents can also successfully be utilized for arsenic removal. Capture of the hydrogen selenide in the passivated tubing at elevated temperatures has resulted in limited results on the effective control of hydrogen selenide with these current sorbents, although lower-temperature results are promising. Preliminary economic analysis suggests that these Corning monoliths potentially could be more cost-effective than the conventional cold-gas (presulfided activated carbon beds) technology currently being utilized. Recent Hg-loading results might suggest that the annualized costs might be as high as 2.5 times the cost of the conventional technology. However, this annualized cost does not take into account the significantly improved thermal efficiency of any plant utilizing the warm-gas monolith technology currently being developed.

  3. advanced underground gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a stream of gas from a CO2 well in southwestern Colorado with a Vacuum Pressure Swing Adsorption (VPSA) plant. The gas from the well contains argon at a concentration of...

  4. Scattering Solar Thermal Concentrators

    Broader source: Energy.gov (indexed) [DOE]

    eere.energy.gov * energy.govsunshot DOEGO-102012-3669 * September 2012 MOTIVATION All thermal concentrating solar power (CSP) systems use solar tracking, which involves moving...

  5. Concentrated Thermoelectric Power

    Broader source: Energy.gov [DOE]

    This fact sheet describes a concentrated solar hydroelectric power project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by MIT, is working to demonstrate concentrating solar thermoelectric generators with >10% solar-to-electrical energy conversion efficiency while limiting optical concentration to less than a factor of 10 and potentially less than 4. When combined with thermal storage, CSTEGs have the potential to provide electricity day and night using no moving parts at both the utility and distributed scale.

  6. Concentrated Solar Thermoelectric Power

    Broader source: Energy.gov [DOE]

    This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23–25, 2013 near Phoenix, Arizona.

  7. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30T23:59:59.000Z

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  8. Effect of oil and gas well drilling fluids on shallow groundwater in western North Dakota

    SciTech Connect (OSTI)

    Murphy, E.C.; Kehew, A.E.

    1984-01-01T23:59:59.000Z

    Upon completion of an oil and gas well in North Dakota, the drilling fluid is buried in the reserve pit at the site. Reclamation of the drill site is expedited by digging a series of trenches which radiate out from the reserve pit. The majority of buried drilling fluid is ultimately contained within these 5-7-metre deep trenches. These fluids are commonly salt-based, i.e., they contain a concentration of 300,000 +- 20,000 ppM NaCl. In addition, these drilling fluids also contain additives including toxic trace-metal compounds. Four reclaimed oil and gas well sites were chosen for study in western North Dakota. The ages of these sites ranged from 2 to 23 years. A total of 31 piezometers and 22 soil water samplers were installed in and around the drill sites, and quarterly groundwater samples were obtained from these instruments. The local groundwater flow conditions were also determined at these sites. Results of both the water analyses and earth resistivity surveys indicate that leachate is being generated at all of the study sites. Water obtained from the unsaturated zone beneath the buried drilling fluid at all of the four study sites exceeds some of the recommended concentration limits and maximum permissible concentration limits for trace elements and major ions (As, Cl/sup -/, Pb, Se, and NO/sub 3//sup -/). These values are greatly reduced in the unsaturated zone as the depth from the buried drilling fluid increases. This reduction is assumed to be the result of attenuation of these ions by cation exchange on Na montmorillonitic clays. Two of these study sites represent the typical geohydrologic setting for the majority of oil and gas well sites in this area. At these sites the saturated zone was not monitored. The reduction in ion concentration in the unsaturated zone suggests that there would be very little impact on the groundwater from this buried drilling fluid at these two sites. 46 references, 58 figures, 3 tables.

  9. Trace element geochemistry of ordinary chondrite chondrules: the type I/type II chondrule dichotomy

    E-Print Network [OSTI]

    Jacquet, Emmanuel; Gounelle, Matthieu

    2015-01-01T23:59:59.000Z

    We report trace element concentrations of silicate phases in chondrules from LL3 ordinary chondrites Bishunpur and Semarkona. Results are similar to previously reported data for carbonaceous chondrites, with rare earth element (REE) concentrations increasing in the sequence olivine ~ 10 K/h) than type I chondrules. Appreciable Na concentrations (3-221 ppm) are measured in olivine from both chondrule types; type II chondrules seem to have behaved as closed systems, which may require chondrule formation in the vicinity of protoplanets or planetesimals. At any rate, higher solid concentrations in type II chondrule forming regions may explain the higher oxygen fugacities they record compared to type I chondrules. Type I and type II chondrules formed in different environments and the correlation between high solid concentrations and/or oxygen fugacities with rapid cooling rates is a key constraint that chondrule formation models must account for.

  10. Behavior of trace and companion elements of ULC-IF steel grades during RH-treatment

    SciTech Connect (OSTI)

    Jungreithmeier, A.; Viertauer, A.; Presslinger, H. [Voest-Alpine Stahl Linz GmbH (Austria)

    1996-12-31T23:59:59.000Z

    A large number of metallurgical reactions are caused by lowering the partial pressure during vacuum treatment. One of these reactions is the volatilization of elements with high vapor pressure. The concentration of trace and companion elements during RH-treatment mostly changes because of cooling scrap, deoxidation agents and ferro-alloy additions, slag/metal reactions, vaporization and also because of reactions with the RH-vessel lining. These changes in the concentration of trace and companion elements during RH-treatment are exemplified for ULC-IF (ultra low carbon--interstitial free) steel grades. The elements which are considered are chromium, nickel, molybdenum, copper, vanadium, tin, zinc, lead, phosphorus, sulfur and nitrogen. Calculations of the theoretical equilibrium solubility using thermodynamic data--in dependence of pressure and temperature--correspond well with the values obtained during steel production operations. 67 refs.

  11. Trace elements in Illinois coals before and after conventional coal preparation

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Ruch, R.R.; Steele, J.D. [Illinois State Geological Survey, Champaign, IL (United States)] [and others

    1994-12-31T23:59:59.000Z

    Responding to recent technological advances and renewed environmental concerns requires improved characterization of Illinois and other US coals. Much of the existing trace element data on Illinois coals are on channel samples; these data need to be supplemented with data on an-shipped coals. Such data will provide a factual basis for the assessment of noxious emissions at coal-fired electric power plants. The purpose of this study was to determine the trace element concentration in as-shipped coals from Illinois mines, and compare the results to data on channel samples thast represent coal in place prior to mining. Radioactivity of the as-shipped samples was calculated from concentrations of uranium, thorium, and potassium in the samples.

  12. Coal quality trends and distribution of Title III trace elements in Eastern Kentucky coals

    SciTech Connect (OSTI)

    Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States); Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    1995-12-31T23:59:59.000Z

    The quality characteristics of eastern Kentucky coal beds vary both spatially and stratigraphically. Average total sulfur contents are lowest, and calorific values highest, in the Big Sandy and Upper Cumberland Reserve Districts. Average coal thickness is greatest in these two districts as well. Conversely, the thinnest coal with the highest total sulfur content, and lowest calorific value, on average, occurs in the Princess and Southwest Reserve Districts. Several Title III trace elements, notably arsenic, cadmium, lead, mercury, and nickel, mirror this distribution (lower average concentrations in the Big Sandy and Upper Cumberland Districts, higher average concentrations in the Princess and Southwest Districts), probably because these elements are primarily associated with sulfide minerals in coal. Ash yields and total sulfur contents are observed to increase in a stratigraphically older to younger direction. Several Title III elements, notably cadmium, chromium, lead, and selenium follow this trend, with average concentrations being higher in younger coals. Average chlorine concentration shows a reciprocal distribution, being more abundant in older coals. Some elements, such as arsenic, manganese, mercury, cobalt, and, to a lesser extent, phosphorus show concentration spikes in coal beds directly above, or below, major marine zones. With a few exceptions, average Title III trace element concentrations for eastern Kentucky coals are comparable with element distributions in other Appalachian coal-producing states.

  13. Trace metals in sediments of coastal Siberia 

    E-Print Network [OSTI]

    Esnough, Teresa Elizabeth

    1996-01-01T23:59:59.000Z

    For the work described in this thesis, a total of 218 samples from 104 cores from the East Siberian, Laptev, Kara, and Pechora Seas and the Ob and Yenisei Rivers were analyzed for the trace metals Ag, As, Ba, Cd, Cr, Cu, Fe, Hg, Ni, Pb, Sb, and Zn...

  14. Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs) in snow and ice sampled at Colle designed, built and tested. Melt water from inner part of ice core section was pumped to an ICP-SFMS and ICP-OES. Melt water from outer section was on-line extracted by solid-phase cartridges for semi

  15. Trace metals in sediments of coastal Siberia

    E-Print Network [OSTI]

    Esnough, Teresa Elizabeth

    1996-01-01T23:59:59.000Z

    For the work described in this thesis, a total of 218 samples from 104 cores from the East Siberian, Laptev, Kara, and Pechora Seas and the Ob and Yenisei Rivers were analyzed for the trace metals Ag, As, Ba, Cd, Cr, Cu, Fe, Hg, Ni, Pb, Sb, and Zn...

  16. Concentration in Green Design

    E-Print Network [OSTI]

    Shewchuk, Jonathan

    , energy, infrastructure or transport. Participants in this specialization area work closely with the GreenConcentration in Green Design Research and Education Opportunities Carnegie Mellon University Civil and Environmental Engineering www.ce.cmu.edu M.S. Concentration Green Design - Course Only Track As an extension

  17. Indirect Measurement Of Nitrogen In A Multi-Component Gas By Measuring The Speed Of Sound At Two States Of The Gas.

    DOE Patents [OSTI]

    Morrow, Thomas B. (San Antonio, TX); Behring, II, Kendricks A. (Torrance, CA)

    2004-10-12T23:59:59.000Z

    A methods of indirectly measuring the nitrogen concentration in a gas mixture. The molecular weight of the gas is modeled as a function of the speed of sound in the gas, the diluent concentrations in the gas, and constant values, resulting in a model equation. Regression analysis is used to calculate the constant values, which can then be substituted into the model equation. If the speed of sound in the gas is measured at two states and diluent concentrations other than nitrogen (typically carbon dioxide) are known, two equations for molecular weight can be equated and solved for the nitrogen concentration in the gas mixture.

  18. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01T23:59:59.000Z

    Analysis Preliminary calculations assuming pure CaCl 2 solutions were carried out to investigate relationships between salt concentration, HCl gas fugacity (? partial pressure), and condensate

  19. Trace metal concentration in blood of the Kemp's ridley sea turtle (Lepidochelys kempii)

    E-Print Network [OSTI]

    Orvik, Lisa Marie

    1997-01-01T23:59:59.000Z

    -1,300 ng/g, mean = 524 ng/g), lead (range = 0.00-34.3 ng/g, mean = 1 1.0 ng/g), mercury (range = 0.50-67.3 ng/g, mean = 18.0 ng/g), silver (range = 0.042-2.74 ng/g, mean = 0.94 ng/g) and zinc (range = 3,280-18,900 ng/g, mean = 7,500 ng/g). Metal...

  20. Methods for analyzing the concentration and speciation of major and trace elements in marine particles

    E-Print Network [OSTI]

    2015-01-01T23:59:59.000Z

    neighboring*atoms* Absorp'on* edge* EXAFS*region* Energy (eV) Energy ( eV) References Akagi, T. , Fu, F. -f. , Hongo,of metals in saline water by energy dispersive XRF using the

  1. Abstract Titanium is one of many trace elements to substitute for silicon in the mineral quartz. Here, we

    E-Print Network [OSTI]

    Watson, E. Bruce

    Abstract Titanium is one of many trace elements to substitute for silicon in the mineral quartz element--titanium--shows special promise in this regard. Concentrations of Ti in meta- morphic and igneous-006-0132-1 123 ORIGINAL PAPER TitaniQ: a titanium-in-quartz geothermometer David A. Wark Æ E. Bruce Watson

  2. Are the TRACE-P measurements representative of the western Pacific during March 2001?

    E-Print Network [OSTI]

    2004-01-01T23:59:59.000Z

    TRACE-P measurements representative of the western PacificTHE TRACE- P MEASUREMENTS REPRESENTATIVE? Pierce, R. B. , etTRACE-P measurements representative of the western Pacific

  3. 12.479 Trace-Element Geochemistry, Fall 2006

    E-Print Network [OSTI]

    Frey, Frederick August

    Focuses on element distribution in rocks and minerals using data obtained from natural and experimental systems. Emphasizes models describing trace-element partitioning and applications of trace-element geochemistry to ...

  4. 12.479 Trace-Element Geochemistry, Spring 2009

    E-Print Network [OSTI]

    Frey, Frederick

    The emphasis of this course is to use Trace Element Geochemistry to understand the origin and evolution of igneous rocks. The approach is to discuss the parameters that control partitioning of trace elements between phases ...

  5. A graphics architecture for ray tracing and photon mapping 

    E-Print Network [OSTI]

    Ling, Junyi

    2005-11-01T23:59:59.000Z

    and spatial locality, as well as eliminating unnecessary random memory accesses. A high level abstraction of the combined ray tracing and photon mapping streaming pipeline is introduced. Based on this abstraction, an e?cient ray tracing and photon...

  6. Steam Tracing...New Technologies for the 21st Century

    E-Print Network [OSTI]

    Pitzer, R. K.; Barth, R. E.; Bonorden, C.

    For decades, steam tracing has been an accepted practice in the heating of piping, vessels, and equipment. This paper presents recent product innovations such as "burn-safe" and "energy efficient" steam tracing products. For the many applications...

  7. The relation of seismic activity and radon concentration

    SciTech Connect (OSTI)

    Kulali, Feride, E-mail: feridekulali@gmail.com, E-mail: iskender@fef.sdu.edu.tr; Akkurt, ?skender, E-mail: feridekulali@gmail.com, E-mail: iskender@fef.sdu.edu.tr [Suleyman Demirel University, Science and Art Faculty, Isparta-Turkey (Turkey); Vogiannis, Efstratios, E-mail: svog@env.aegean.gr [Department of Environmental Studies, University of the Aegean,Mytilene (Greece)

    2014-10-06T23:59:59.000Z

    Radon, which is the largest source of natural ionizing radiation, reaches to surface as gas or dissolved form in the ground water. Emanation of radon can has a profile is disposed to increasing or decreasing depending on the effects of meteorological events or crust movements. In this work, the radon concentration in soil gas, which is transported from soil to AlphaGUARD, is continuously measured in Mytilene (Greece). A graph of radon concentration is prepared for comparison with simultaneous earthquake data. As a consequence of comparison, we determined that the radon concentration indicates anomalies before the earthquakes.

  8. Concentrating photovoltaic solar panel

    DOE Patents [OSTI]

    Cashion, Steven A; Bowser, Michael R; Farrelly, Mark B; Hines, Braden E; Holmes, Howard C; Johnson, Jr., Richard L; Russell, Richard J; Turk, Michael F

    2014-04-15T23:59:59.000Z

    The present invention relates to photovoltaic power systems, photovoltaic concentrator modules, and related methods. In particular, the present invention features concentrator modules having interior points of attachment for an articulating mechanism and/or an articulating mechanism that has a unique arrangement of chassis members so as to isolate bending, etc. from being transferred among the chassis members. The present invention also features adjustable solar panel mounting features and/or mounting features with two or more degrees of freedom. The present invention also features a mechanical fastener for secondary optics in a concentrator module.

  9. Scattering Solar Thermal Concentrators

    Broader source: Energy.gov [DOE]

    "This fact sheet describes a scattering solar thermal concentrators project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by the Pennsylvania State University, is working to demonstrate a new, scattering-based approach to concentrating sunlight that aims to improve the overall performance and reliability of the collector field. The research team aims to show that scattering solar thermal collectors are capable of achieving optical performance equal to state-of-the-art parabolic trough systems, but with the added benefits of immunity to wind-load tracking error, more efficient land use, and utilization of stationary receivers."

  10. System and method for detecting gas

    DOE Patents [OSTI]

    Chow, Oscar Ken (Simsbury, CT); Moulthrop, Lawrence Clinton (Windsor, CT); Dreier, Ken Wayne (Madison, CT); Miller, Jacob Andrew (Dexter, MI)

    2010-03-16T23:59:59.000Z

    A system to detect a presence of a specific gas in a mixture of gaseous byproducts comprising moisture vapor is disclosed. The system includes an electrochemical cell, a transport to deliver the mixture of gaseous byproducts from the electrochemical cell, a gas sensor in fluid communication with the transport, the sensor responsive to a presence of the specific gas to generate a signal corresponding to a concentration of the specific gas, and a membrane to prevent transmission of liquid moisture, the membrane disposed between the transport and the gas sensor.

  11. Ambient methods and apparatus for rapid laser trace constituent analysis

    DOE Patents [OSTI]

    Snyder, Stuart C. (Idaho Falls, ID); Partin, Judy K. (Idaho Falls, ID); Grandy, Jon D. (Idaho Falls, ID); Jeffery, Charles L. (Blackfoot, ID)

    2002-01-01T23:59:59.000Z

    A method and apparatus are disclosed for measuring trace amounts of constituents in samples by using laser induced breakdown spectroscopy and laser induced fluorescence under ambient conditions. The laser induced fluorescence is performed at a selected wavelength corresponding to an absorption state of a selected trace constituent. The intensity value of the emission decay signal which is generated by the trace constituent is compared to calibrated emission intensity decay values to determine the amount of trace constituent present.

  12. Organic photovoltaics and concentrators

    E-Print Network [OSTI]

    Mapel, Jonathan King

    2008-01-01T23:59:59.000Z

    The separation of light harvesting and charge generation offers several advantages in the design of organic photovoltaics and organic solar concentrators for the ultimate end goal of achieving a lower cost solar electric ...

  13. concentration 2-adrenoceptor

    E-Print Network [OSTI]

    Yang, Junfeng

    inhibitor concentration agonist acid expressed region isolated treatment 2-adrenoceptor serum stimulation acid product metabolism human treatment analysis new ester metabolites derivatives content isolated expression level binding complex mrna integrin collagen genes form normal synthesis production beta 1

  14. Water Sample Concentrator

    ScienceCinema (OSTI)

    Idaho National Laboratory

    2010-01-08T23:59:59.000Z

    Automated portable device that concentrates and packages a sample of suspected contaminated water for safe, efficient transport to a qualified analytical laboratory. This technology will help safeguard against pathogen contamination or chemical and biolog

  15. Joined concentric tubes

    DOE Patents [OSTI]

    DeJonghe, Lutgard; Jacobson, Craig; Tucker, Michael; Visco, Steven

    2013-01-01T23:59:59.000Z

    Tubular objects having two or more concentric layers that have different properties are joined to one another during their manufacture primarily by compressive and friction forces generated by shrinkage during sintering and possibly mechanical interlocking. It is not necessary for the concentric tubes to display adhesive-, chemical- or sinter-bonding to each other in order to achieve a strong bond. This facilitates joining of dissimilar materials, such as ceramics and metals.

  16. GAS EXPLORATION Winter 2006 GasTIPS 5

    E-Print Network [OSTI]

    Rubin, Yoram

    discriminate between economic and non-eco- nomic concentrations of gas. This is primarily because having 25% porosity and brine salinity of 0.07 ppm. The relation- ship between Rbulk and Sg has detection/mapping of hydrocarbon. A marine CSEM system consists of a ship- towed electric dipole source

  17. Methods developed for detecting hazardous elements in produced gas

    SciTech Connect (OSTI)

    Chao, S.; Attari, A. (Inst. of Gas Technology, Des Plaines, IL (United States))

    1995-01-16T23:59:59.000Z

    The Institute of Gas Technology, Des Plaines, Ill. has been developing sampling and analytical methods to detect in natural gas various trace constituents that may pose health, safety, or operational risks. The constituents of interest include paraffinic and aromatic hydrocarbons, H[sub 2]S, organic sulfur compounds, arsenic, mercury, radon, and others. Better sampling and analytical techniques for produced natural gas, similar to those developed by IGT for processed gas, will enhance producers and processors' abilities to monitor undesirable constituents in raw gas streams and improve their clean-up processes. The methods developed at IGT were modifications of air sampling and analytical methods that are commonly used for air toxic substances. These monitoring methods, when applied to natural gas, present special challenges because gas has a much more complex matrix than the air. Methods for the analysis of the following are discussed: arsenic, mercury, radon, sulfur compounds, hydrocarbons, and aromatics including BTEX and PAHs.

  18. Long term performance of boilers using landfill gas

    SciTech Connect (OSTI)

    Gulledge, J.; Cosulich, J.; Ahmed, S.L.

    1996-11-01T23:59:59.000Z

    The US EPA estimates that approximately 600 to 700 landfills produce sufficient gas for profitable energy production in the United States. The gas from these landfills could provide enough electricity for about 3 million homes. Yet, there are only about 120 operating landfill gas to energy facilities. A lack of information on successful projects may cause part of this shortfall. This paper provides information on 4 successful projects using landfill gas fired boilers, some of which have operated over a decade. Natural gas fired boilers can be easily converted to bum landfill gas. Several modifications to Districts` boilers, described in this paper, have resulted in many years of safe and corrosion free operation. Most of the modifications are minor. Conversion can be accomplished for under $100,000 in many cases. Information on the reliability and longevity of landfill gas supplies is also provided. Gas from a given landfill is generally available over 99.5% of the time with about 5 brief flow interruptions annually. Actual data from 3 landfills document the high availability of landfill gas. To show the longevity of landfill gas flows, data from the Palos Verdes Landfill are provided. The Palos Verdes Landfill closed in 1980. The Palos Verdes. Landfill Gas to Energy Facility is currently producing over 8 megawatts. Landfill gas pretreatment is not required for boilers. In cases where the landfill gas is being piped offsite, it is usually cost effective to dehydrate the landfill gas. Landfill gas bums cleaner than natural gas. NO{sub x} emissions from landfill gas fired boilers are lower because of the carbon dioxide in the landfill gas. Trace organic destruction efficiency is usually over 99% in landfill gas fired boilers. In addition, flare emissions are eliminated when landfill gas is used to displace fossil fuels in boilers.

  19. Greenhouse Gas Basics

    Broader source: Energy.gov [DOE]

    Greenhouse gases are trace gases in the lower atmosphere that trap heat through a natural process called the "greenhouse effect."

  20. Trace anomaly of the conformal gauge field

    E-Print Network [OSTI]

    Sladkowski, J

    1993-01-01T23:59:59.000Z

    The proposed by Bastianelli and van Nieuwenhuizen new method of calculations of trace anomalies is applied in the conformal gauge field case. The result is then reproduced by the heat equation method. An error in previous calculation is corrected. It is pointed out that the introducing gauge symmetries into a given system by a field-enlarging transformation can result in unexpected quantum effects even for trivial configurations.

  1. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Trace elements and alkaliTrace elements and alkali

    E-Print Network [OSTI]

    Zevenhoven, Ron

    elements in fossil - and waste-derived fuelsTrace elements in fossil - and waste-derived fuels Coal Peat Heavy fuel oil Pet coke MSW RDF Wood Waste wood Waste paper Scrap tyres Sew. sludge Hg 0.02-3 ~0.07 .153 Behaviour of trace elements in coalBehaviour of trace elements in coal combustion flue gasescombustion flue

  2. Reducing PM Concentrations in Simulated High Temperature Gas Streams 

    E-Print Network [OSTI]

    Luehrs, Daniel R

    2014-08-07T23:59:59.000Z

    . This characteristic is referred to as char having a low eutectic point. Biomasses with low eutectic points cannot be used in a combustion process because the char will result in slagging and fouling. We have used fluidized bed gasification (FBG) to control...

  3. Trace Analytical Techniques for Nuclear Forensics

    SciTech Connect (OSTI)

    Halverson, J.E.

    1999-04-28T23:59:59.000Z

    Over the history of the Savannah River Site, the Savannah River Technology Center (SRTC) has developed high sensitivity analytical capabilities in support of the Site's Environmental Monitoring Program and nuclear material protection process. Many of these techniques are applicable to the developing need for nuclear forensic analysis capabilities. Radiological and critically control procedures are in place at the SRTC, as well as clean room practices, to minimize the potential for a radiological evidentiary sample to contaminate personnel and the facility, as well as to minimize contaminating the sample thus rendering it useless by law enforcement agencies. Some of the trace analytical techniques available at the SRTC include ultra-low-level gamma and alpha spectrometry, high-sensitivity thermal ionization mass spectrometry, time-of-flight secondary ion mass spectrometry and trace organic analyses. These techniques have been tested during a planned domestic smuggling exercise and in the analysis of an unknown sample.In the event of an interdiction involving the illegal use or movement of radioactive material by U.S. law enforcement agencies (local, state or federal) forensic analyses will be used in developing and building a legal case against the perpetrators. The Savannah River Technology Center (SRTC) at the U.S. Department of Energy's Savannah River Site, a former nuclear production site currently conducting nuclear material stabilization missions, located in Aiken South Carolina, has a long history of performing trace analytical analyses for environmental monitoring. Many of these techniques are also applicable to nuclear forensic analyses. A summary of the trace analytical techniques used at the SRTC, which are applicable to Nuclear Forensics, is presented in this paper.Contamination control, of facilities and personnel involved in the analytical analyses, as well as preventing contamination of the sample, is a unique challenge for nuclear forensic analyses. A discussion of sample handling and contamination control procedures is included in this paper. Some of the applicable analytical techniques available at the SRTC for nuclear forensic analyses include: ultra-low-level gamma and alpha spectroscopy, high-sensitivity thermal-ionization mass spectrometry (TIMS), time-of-flight secondary ion mass spectrometry (TOF-SIMS), and trace organic analyses. Results from analyses of special nuclear material (SNM) standards, materials from nuclear smuggling exercises, and materials of unknown origin will be presented.

  4. ScalaTrace: Tracing, Analysis and Modeling of HPC Codes at Scale

    SciTech Connect (OSTI)

    Mueller, F; Wu, X; Schulz, M; de Supinski, B; Gamblin, T

    2010-03-31T23:59:59.000Z

    Characterizing the communication behavior of large-scale applications is a difficult and costly task due to code/system complexity and their long execution times. An alternative to running actual codes is to gather their communication traces and then replay them, which facilitates application tuning and future procurements. While past approaches lacked lossless scalable trace collection, we contribute an approach that provides orders of magnitude smaller, if not near constant-size, communication traces regardless of the number of nodes while preserving structural information. We introduce intra- and inter-node compression techniques of MPI events, we develop a scheme to preserve time and causality of communication events, and we present results of our implementation for BlueGene/L. Given this novel capability, we discuss its impact on communication tuning and on trace extrapolation. To the best of our knowledge, such a concise representation of MPI traces in a scalable manner combined with time-preserving deterministic MPI call replay are without any precedence.

  5. Trace water vapor determination in nitrogen and corrosive gases using infrared spectroscopy

    SciTech Connect (OSTI)

    Espinoza, L.H.; Niemczyk, T.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry; Stallard, B.R.; Garcia, M.J. [Sandia National Labs., Albuquerque, NM (United States)

    1997-06-01T23:59:59.000Z

    The generation of particles in gas handling systems as a result of corrosion is a major concern in the microelectronics industry. The corrosion can be caused by the presence of trace quantities of water in corrosive gases such as HCl or HBr. FTIR spectroscopy has been shown to be a method that can be made compatible with corrosive gases and is capable of detecting low ppb levels of water vapor. In this report, the application of FTIR spectroscopy combined with classical least squares multivariate calibration to detect trace H{sub 2}O in N{sub 2}, HCl and HBr is discussed. Chapter 2 discusses the gas handling system and instrumentation required to handle corrosive gases. A method of generating a background spectrum useful to the measurements discussed in this report, as well as in other application areas such as gas phase environmental monitoring, is discussed in Chapter 3. Experimental results obtained with the first system are presented in Chapter 4. Those results made it possible to optimize the design options for the construction of a dedicate system for low ppb water vapor determination. These designs options are discussed in Chapter 5. An FTIR prototype accessory was built. In addition, a commercially available evacuable FTIR system was obtained for evaluation. Test results obtained with both systems are discussed in Chapter 6. Experiments dealing with the interaction between H{sub 2}O-HCl and potential improvements to the detection system are discussed in Chapter 7.

  6. Airborne agent concentration analysis

    DOE Patents [OSTI]

    Gelbard, Fred

    2004-02-03T23:59:59.000Z

    A method and system for inferring airborne contaminant concentrations in rooms without contaminant sensors, based on data collected by contaminant sensors in other rooms of a building, using known airflow interconnectivity data. The method solves a least squares problem that minimizes the difference between measured and predicted contaminant sensor concentrations with respect to an unknown contaminant release time. Solutions are constrained to providing non-negative initial contaminant concentrations in all rooms. The method can be used to identify a near-optimal distribution of sensors within the building, when then number of available sensors is less than the total number of rooms. This is achieved by having a system-sensor matrix that is non-singular, and by selecting that distribution which yields the lowest condition number of all the distributions considered. The method can predict one or more contaminant initial release points from the collected data.

  7. Photovoltaic solar concentrator

    DOE Patents [OSTI]

    Nielson, Gregory N.; Okandan, Murat; Resnick, Paul J.; Cruz-Campa, Jose Luis

    2012-12-11T23:59:59.000Z

    A photovoltaic solar concentrator is disclosed with one or more transverse-junction solar cells (also termed point contact solar cells) and a lens located above each solar cell to concentrate sunlight onto the solar cell to generate electricity. Piezoelectric actuators tilt or translate each lens to track the sun using a feedback-control circuit which senses the electricity generated by one or more of the solar cells. The piezoelectric actuators can be coupled through a displacement-multiplier linkage to provide an increased range of movement of each lens. Each lens in the solar concentrator can be supported on a frame (also termed a tilt plate) having three legs, with the movement of the legs being controlled by the piezoelectric actuators.

  8. TCgen 2.0: A Tool to Automatically Generate Lossless Trace Compressors Martin Burtscher

    E-Print Network [OSTI]

    Burtscher, Martin

    TCgen 2.0: A Tool to Automatically Generate Lossless Trace Compressors Martin Burtscher Computer of TCgen, a tool for generating portable lossless trace compressors based on user-provided trace format for translating user-provided trace descriptions into fast and effective trace compressors. A typical trace

  9. 1. Introduction to the relative trace formula Give an idea of the relative trace formula along any of the sources [CPS90,

    E-Print Network [OSTI]

    Ould Ahmedou, Mohameden

    1. Introduction to the relative trace formula Give an idea of the relative trace formula along any (91h:11042) [Jac05] Herv´e Jacquet, A guide to the relative trace formula, Automorphic representations2192826 (2006g:11100) [Lap10] Erez M. Lapid, Some applications of the trace formula and the relative trace

  10. Gas energy meter for inferential determination of thermophysical properties of a gas mixture at multiple states of the gas

    DOE Patents [OSTI]

    Morrow, Thomas B. (San Antonio, TX); Kelner, Eric (San Antonio, TX); Owen, Thomas E. (Helotes, TX)

    2008-07-08T23:59:59.000Z

    A gas energy meter that acquires the data and performs the processing for an inferential determination of one or more gas properties, such as heating value, molecular weight, or density. The meter has a sensor module that acquires temperature, pressure, CO2, and speed of sound data. Data is acquired at two different states of the gas, which eliminates the need to determine the concentration of nitrogen in the gas. A processing module receives this data and uses it to perform a "two-state" inferential algorithm.

  11. Gas Distribution Modeling using Sparse Gaussian Process Mixture Models

    E-Print Network [OSTI]

    Stachniss, Cyrill

    Gas Distribution Modeling using Sparse Gaussian Process Mixture Models Cyrill Stachniss1 Christian-- In this paper, we consider the problem of learning a two dimensional spatial model of a gas distribution with a mobile robot. Building maps that can be used to accurately predict the gas concentration at query

  12. Rock-physics Models for Gas-hydrate Systems Associated

    E-Print Network [OSTI]

    Texas at Austin, University of

    Rock-physics Models for Gas-hydrate Systems Associated with Unconsolidated Marine Sediments Diana at Austin, Austin, Texas, U.S.A. ABSTRACT R ock-physics models are presented describing gas-hydrate systems associated with unconsolidated marine sediments. The goals are to predict gas-hydrate concentration from

  13. 1.0 GAS TRANSFER An important process used in water and wastewater treatment. Also very important when

    E-Print Network [OSTI]

    Stenstrom, Michael K.

    1.0 GAS TRANSFER An important process used in water and wastewater treatment. Also very important = CL (CL + HcVG) (6) where CL = liquid phase concentration, VL = liquid volume, CG = gas phase concentration, VG = gas volume, Hc = dimensionless Henry's law coefficient and M = mass of gas. Now use two

  14. NATURAL GAS MARKET ASSESSMENT

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

  15. GAS HYDRATE EQUILIBRIA FOR CO2-N2 AND CO2-CH4 GAS MIXTURES, EXPERIMENTS AND MODELLING

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    steelmaking plants, gas or coal power plants, chemical plants or natural gas production plants. Facing are by definition localized at the plants, like e.g. steelmaking plants, gas or coal power plants, chemical plants be in the order of several cubic meters of CO2 per second. In power plants, the concentration of CO2 is generally

  16. Molecular Gas in Galaxies

    E-Print Network [OSTI]

    F. Combes

    2000-07-21T23:59:59.000Z

    Knowledge of the molecular component of the ISM is fundamental to understand star formation. The H2 component appears to dominate the gas mass in the inner parts of galaxies, while the HI component dominates in the outer parts. Observation of the CO and other lines in normal and starburst galaxies have questioned the CO-to-H2 conversion factor, and detection of CO in dwarfs have shown how sensitive the conversion f actor is to metallicity. Our knowledge has made great progress in recent years, because of sensitivity and spatial resolution improvements. Large-scale CO maps of nearby galaxies are now available, which extend our knowledge on global properties, radial gradients, and spiral structure of the molecular ISM. Millimetric interferometers reveal high velocity gradients in galaxy nuclei, and formation of embedded structures, like bars within bars. Galaxy interactions are very effective to enhance gas concentrations and trigger starbursts. Nuclear disks or rings are frequently observed, that concentrate the star formation activity. Since the density of starbursting galaxies is strongly increasing with redshift, the CO lines and the mm dust emission are a privileged tool to follow evolution of galaxies and observe the ISM dynamics at high redshift: they could give an answer about the debated question of the star-formation history, since many massive remote starbursts could be dust-enshrouded.

  17. Sandia National Laboratories: concentrating photovoltaic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concentrating photovoltaic Sandia and EMCORE: Solar Photovoltaics, Fiber Optics, MODE, and Energy Efficiency On March 29, 2013, in Concentrating Solar Power, Energy, Partnership,...

  18. Gas sensing with acoustic devices

    SciTech Connect (OSTI)

    Martin, S.J.; Frye, G.C. [Sandia National Labs., Albuquerque, NM (United States); Spates, J.J. [Ktech Corp., Albuquerque, NM (United States); Butler, M.A. [Sandia National Labs., Albuquerque, NM (United States)

    1996-12-31T23:59:59.000Z

    A survey is made of acoustic devices that are suitable as gas and vapor sensors. This survey focuses on attributes such as operating frequency, mass sensitivity, quality factor (Q), and their ability to be fabricated on a semiconductor substrate to allow integration with electronic circuitry. The treatment of the device surface with chemically-sensitive films to detect species of interest is discussed. Strategies for improving discrimination are described, including sensor arrays and species concentration and separation schemes. The advantages and disadvantages of integrating sensors with microelectronics are considered, along with the effect on sensitivity of scaling acoustic gas sensors to smaller size.

  19. An investigation of the sub-grid variability of trace gases and aerosols for global climate modeling

    SciTech Connect (OSTI)

    Qian, Yun; Gustafson, William I.; Fast, Jerome D.

    2010-07-29T23:59:59.000Z

    One fundamental property and limitation of grid based models is their inability to identify spatial details smaller than the grid cell size. While decades of work have gone into developing sub-grid treatments for clouds and land surface processes in climate models, the quantitative understanding of sub-grid processes and variability for aerosols and their precursors is much poorer. In this study, WRF-Chem is used to simulate the trace gases and aerosols over central Mexico during the 2006 MILAGRO field campaign, with multiple spatial resolutions and emission/terrain scenarios. Our analysis focuses on quantifying the sub-grid variability (SGV) of trace gases and aerosols within a typical global climate model grid cell, i.e. 75x75 km2. Our results suggest that a simulation with 3-km horizontal grid spacing adequately reproduces the overall transport and mixing of trace gases and aerosols downwind of Mexico City, while 75-km horizontal grid spacing is insufficient to represent local emission and terrain-induced flows along the mountain ridge, subsequently affecting the transport and mixing of plumes from nearby sources. Therefore, the coarse model grid cell average may not correctly represent aerosol properties measured over polluted areas. Probability density functions (PDFs) for trace gases and aerosols show that secondary trace gases and aerosols, such as O3, sulfate, ammonium, and nitrate, are more likely to have a relatively uniform probability distribution (i.e. smaller SGV) over a narrow range of concentration values. Mostly inert and long-lived trace gases and aerosols, such as CO and BC, are more likely to have broad and skewed distributions (i.e. larger SGV) over polluted regions. Over remote areas, all trace gases and aerosols are more uniformly distributed compared to polluted areas. Both CO and O3 SGV vertical profiles are nearly constant within the PBL during daytime, indicating that trace gases are very efficiently transported and mixed vertically by turbulence. But, simulated horizontal variability indicates that trace gases and aerosols are not well mixed horizontally in the PBL. During nighttime the SGV for trace gases is maximum at the surface, and quickly decreases with height. Unlike the trace gases, the SGV of BC and secondary aerosols reaches a maximum at the PBL top during the day. The SGV decreases with distance away from the polluted urban area, has a more rapid decrease for long-lived trace gases and aerosols than for secondary ones, and is greater during daytime than nighttime. The SGV of trace gases and aerosols is generally larger than for meteorological quantities. Emissions can account for up to 50% of the SGV over urban areas such as Mexico City during daytime for less-reactive trace gases and aerosols, such as CO and BC. The impact of emission spatial variability on SGV decays with altitude in the PBL and is insignificant in the free troposphere. The emission variability affects SGV more significantly during daytime (rather than nighttime) and over urban (rather than rural or remote) areas. The terrain, through its impact on meteorological fields such as wind and the PBL structure, affects dispersion and transport of trace gases and aerosols and their SGV.

  20. Trace Element Geochemical Zoning in the Roosevelt Hot Springs...

    Open Energy Info (EERE)

    Capuano. 1980. Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area, Utah. In: Transactions. GRC Annual Meeting; 09091980; Salt Lake City, UT. Salt...

  1. Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters...

    Open Energy Info (EERE)

    Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters- Lessons Learned From Mammoth Mountain, USA Jump to: navigation, search OpenEI Reference LibraryAdd to...

  2. Monitoring Trace Radionuclides by ICP Mass Spectrometry with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    extensive monitoring programs for trace radionuclides relevant to the observation of illicit nuclear activities. FUNDING SOURCE: United States Department of Energy NA22 FOR MORE...

  3. The Effects of Trace Contaminants on Catalytic Processing of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Processing of Biomass-Derived Feedstocks . Abstract: Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to...

  4. Georgia Tech Dangerous Gas

    E-Print Network [OSTI]

    Sherrill, David

    1 Georgia Tech Dangerous Gas Safety Program March 2011 #12;Georgia Tech Dangerous Gas Safety.......................................................................................................... 5 6. DANGEROUS GAS USAGE REQUIREMENTS................................................. 7 6.1. RESTRICTED PURCHASE/ACQUISITION RULES: ................................................ 7 7. FLAMMABLE GAS

  5. Isotopic abundance in atom trap trace analysis

    DOE Patents [OSTI]

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18T23:59:59.000Z

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  6. ACTION CONCENTRATION FOR MIXTURES OF VOLATILE ORGANIC COMPOUNDS (VOC) & METHANE & HYDROGEN

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    2006-07-10T23:59:59.000Z

    Waste containers may contain volatile organic compounds (VOCs), methane, hydrogen and possibly propane. These constituents may occur individually or in mixtures. Determining if a waste container contains a flammable concentration of flammable gases and vapors (from VOCs) is important to the safety of the handling, repackaging and shipping activities. This report provides the basis for determining the flammability of mixtures of flammable gases and vapors. The concentration of a mixture that is at the lowest flammability limit for that mixture is called the action concentration. The action concentration can be determined using total VOC concentrations or actual concentration of each individual VOC. The concentrations of hydrogen and methane are included with the total VOC or individual VOC concentration to determine the action concentration. Concentrations below this point are not flammable. Waste containers with gas/vapor concentrations at or above the action concentration are considered flammable.

  7. Can the trace formula describe weak localisation?

    E-Print Network [OSTI]

    Robert S. Whitney; Igor V. Lerner; Robert A. Smith

    1999-02-24T23:59:59.000Z

    We attempt to systematically derive perturbative quantum corrections to the Berry diagonal approximation of the two-level correlation function (TLCF) for chaotic systems. To this end, we develop a ``weak diagonal approximation'' based on a recent description of the first weak localisation correction to conductance in terms of the Gutzwiller trace formula. This semiclassical method is tested by using it to derive the weak localisation corrections to the TLCF for a semiclassically disordered system. Unfortunately the method is unable to correctly reproduce the ``Hikami boxes'' (the relatively small regions where classical paths are glued together by quantum processes). This results in the method failing to reproduce the well known weak localisation expansion. It so happens that for the first order correction it merely produces the wrong prefactor. However for the second order correction, it is unable to reproduce certain contributions, and leads to a result which is of a different form to the standard one.

  8. Fixed Space of Positive Trace-Preserving Super-Operators

    E-Print Network [OSTI]

    Ansis Rosmanis

    2011-09-15T23:59:59.000Z

    We examine the fixed space of positive trace-preserving super-operators. We describe a specific structure that this space must have and what the projection onto it must look like. We show how these results, in turn, lead to an alternative proof of the complete characterization of the fixed space of completely positive trace-preserving super-operators.

  9. Accuracy of Memory Reference Traces of Parallel Computations

    E-Print Network [OSTI]

    Holliday, Mark A.

    , the trace-driven simulator uses the intrinsic traces and the sequence of loads and stores before the current cy- cle, to determine the next address. The mapping between load and store sequences and next addresses to issue, sometimes, requires partial program reexecution. Programs that do not require partial

  10. Initial conditions for paraxial ray tracing in inhomogeneous anisotropic media

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    , theoretical seismology, seismic anisotropy, wave propagation 1 Introduction By standard kinematic ray tracing and in numerical modelling and interpretation of high-frequency seismic wave #12;elds propagating in inhomogeneous to such important quantities as geometrical spreading and ray amplitudes. The limitations of kinematic ray tracing

  11. Autothermal production of synthesis gas

    SciTech Connect (OSTI)

    Lewis, J.L.

    1987-05-19T23:59:59.000Z

    An autothermal reactor is described for the production of a synthesis gas in which both primary reforming and secondary reforming are achieved at a high level of efficiency. The method comprises a heat exchange chamber having a first portion and a second portion, a first inlet connected to the heat exchange chamber for the introduction of steam and feed gas to the heat exchange chamber, reaction tubes mounted within the first portion of the heat exchanger chamber at a location spaced longitudinally from the first inlet in communication with the first inlet and in non-concentric relationship therewith so as to provide a flow path for the steam and feed gas from the first inlet through the plurality of reaction tubes.

  12. Nitrogen gas emissions from stormwater retention basins during wet weather events in the Phoenix Metropolitan area: an additional ecosystem service?

    E-Print Network [OSTI]

    Hall, Sharon J.

    . We pretreated the basin with a heavy N isotope (15N in NO3 ­ ) to trace the fate of the N added from any process by basin design. Data calculated from gas fluxes in chambers after water, but potentially producing considerable amounts of N2O, a greenhouse gas Incoming data will allow complete

  13. A better steam engine: Designing a distributed concentrating

    E-Print Network [OSTI]

    Kammen, Daniel M.

    collector costs dominate. 2 #12;Distributed generation optionsg p · Biomass - methane, alcohol, dung, syngas added globally in 2008 · Geothermal heat pump · Fossil fuels - diesel, natural gas, propane, li application study: Reducing water consumption of concentrating solar power electricity generation, Tech. rep

  14. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01T23:59:59.000Z

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  15. Gas hydrate research in the Gulf of Mexico: Final report

    SciTech Connect (OSTI)

    Bennet, R.

    1988-05-01T23:59:59.000Z

    The high energy seismic sections on the continental slope showed no evidence of a Bottom Simulating Reflector (BSR), which would indicate the presence of gas hydrates. There was no indication of metastable hydrates in continental shelf or slope sediments outside of the conventionally accepted temperature and pressure environment. Tracing the path of migrating gas from the source is much more straight forward than intercepting gas being transported and tracing it back to the source. Our study of low and medium energy seismic methods has shown that they could identify migrating gas. We feel strongly that there are hydrate zones in the Gulf of Mexico that are decomposing; they build up pressure and periodically release the trapped hydrocarbon gases. The released gases migrate vertically and/or laterally to mix with other types of gas or to form discrete pockets. Some of this gas may be emitted from underwater seeps into the overlying water column where it could be identified by a geochemical survey. The ratio of isobutane to normal butane determined by the geochemical survey can be used to assess the probability of the hydrocarbons emanating from a hydrate source. (The more the ratio exceeds 1.0 the greater the probability that the gas could be from a hydrate source.) As no indications of a hydrate zone (e.g., a BSR) were located, we were not able to establish a geophysical signature for gas hydrates; but the records indicate there are large volumes of gas migrating up the continental slope, some of which may have originated from a decomposing hydrate zone or from gas trapped below the hydrate cap. 20 refs., 13 figs., 1 tab.

  16. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D.; Bourcier, William L.

    2014-08-19T23:59:59.000Z

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  17. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D. (Livermore, CA); Bourcier, William L. (Livermore, CA)

    2010-11-09T23:59:59.000Z

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  18. Concentric tube support assembly

    SciTech Connect (OSTI)

    Rubio, Mark F.; Glessner, John C.

    2012-09-04T23:59:59.000Z

    An assembly (45) includes a plurality of separate pie-shaped segments (72) forming a disk (70) around a central region (48) for retaining a plurality of tubes (46) in a concentrically spaced apart configuration. Each segment includes a support member (94) radially extending along an upstream face (96) of the segment and a plurality of annularly curved support arms (98) transversely attached to the support member and radially spaced apart from one another away from the central region for receiving respective upstream end portions of the tubes in arc-shaped spaces (100) between the arms. Each segment also includes a radial passageway (102) formed in the support member for receiving a fluid segment portion (106) and a plurality of annular passageways (104) formed in the support arms for receiving respective arm portions (108) of the fluid segment portion from the radial passageway and for conducting the respective arm portions into corresponding annular spaces (47) formed between the tubes retained by the disk.

  19. System and method to determine thermophysical properties of a multi-component gas

    DOE Patents [OSTI]

    Morrow, Thomas B.; Behring II, Kendricks A.

    2003-08-05T23:59:59.000Z

    A system and method to characterize natural gas hydrocarbons using a single inferential property, such as standard sound speed, when the concentrations of the diluent gases (e.g., carbon dioxide and nitrogen) are known. The system to determine a thermophysical property of a gas having a first plurality of components comprises a sound velocity measurement device, a concentration measurement device, and a processor to determine a thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the concentration measurements, wherein the number of concentration measurements is less than the number of components in the gas. The method includes the steps of determining the speed of sound in the gas, determining a plurality of gas component concentrations in the gas, and determining the thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the plurality of concentrations.

  20. Project Approval Form Concentration in

    E-Print Network [OSTI]

    Goldberg, Bennett

    Project Approval Form Concentration in Nanotechnology Return completed form to ENG Undergraduate of Graduation:____________________________ Instructions: Please check one of the following ways in which you Plan to complete the project as a requirement for the concentration in Nanotechnology. Depending upon

  1. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    SciTech Connect (OSTI)

    Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

    2007-06-30T23:59:59.000Z

    Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

  2. Trace Assessment for BWR ATWS Analysis

    SciTech Connect (OSTI)

    Cheng, L.Y.; Diamond, D.; Arantxa Cuadra, Gilad Raitses, Arnold Aronson

    2010-04-22T23:59:59.000Z

    A TRACE/PARCS input model has been developed in order to be able to analyze anticipated transients without scram (ATWS) in a boiling water reactor. The model is based on one developed previously for the Browns Ferry reactor for doing loss-of-coolant accident analysis. This model was updated by adding the control systems needed for ATWS and a core model using PARCS. The control systems were based on models previously developed for the TRAC-B code. The PARCS model is based on information (e.g., exposure and moderator density (void) history distributions) obtained from General Electric Hitachi and cross sections for GE14 fuel obtained from an independent source. The model is able to calculate an ATWS, initiated by the closure of main steam isolation valves, with recirculation pump trip, water level control, injection of borated water from the standby liquid control system and actuation of the automatic depres-surization system. The model is not considered complete and recommendations are made on how it should be improved.

  3. Solid-phase chelation for the determination of trace elements by ICP-MS

    SciTech Connect (OSTI)

    Taylor, D.B.; Kingston, H.M.; Nogay, D. [Duquesne Univ., Pittsburgh, PA (United States)

    1995-12-31T23:59:59.000Z

    A low pressure method for the concentration of analytes and elimination of matrix elements prior to determination by ICP-MS is described. The method reduces the interferences caused by high concentrations of matrix elements in samples and biases caused by differences between samples and standards by delivering the analytes to the ICP-MS in a consistent nitric acid matrix. The method uses a commercially available low pressure sample manipulation system (PrepLab, Fisons) to perform Solid Phase Chelation (SPC) on an iminodiacetate column. The effectiveness of the method is demonstrated for the determination of Cd, Co, Cu, Mn, Ni, Pb, U, and Zn in the certified reference materials CASS-2, near shore seawater, NASS-4, open ocean seawater, and 1643b, trace elements in water. The detection limits for 10 mL samples ranged from 0.4 ng L{sup -1} for Co to 5.6 ng L{sup -1} for Ni and Zn.

  4. Flammable gas tank safety program: Technical basis for gas analysis and monitoring

    SciTech Connect (OSTI)

    Sherwood, D.J.

    1995-09-08T23:59:59.000Z

    Flammable gases generated in radioactive liquids. Twenty-five high level radioactive liquid waste storage tanks located underground at the Hanford Site are on a Flammable Gas Watch List because they contain waste which tends to retain the gases generated in it until rather large quantities are available for sudden release to the tank head space; if a tank is full it has little dome space, and a flammable concentration of gases could be produced--even if the tank is ventilated. If the waste has no tendency to retain gas generated in it then a continual flammable gas concentration in the tank dome space is established by the gas production rate and the tank ventilation rate (or breathing rate for unventilated tanks); this is also a potential problem for Flammable Gas Watch List tanks, and perhaps other Hanford tanks too. All Flammable Gas Watch List tanks will be fitted with Standard Hydorgen Monitoring Systems so that their behavior can be observed. In some cases, such as tank 241-SY-101, the data gathered from such observations will indicate that tank conditions need to be mitigated so that gas release events are either eliminated or rendered harmless. For example, a mixer pump was installed in tank 241-SY-101; operating the pump stirs the waste, replacing the large gas release events with small releases of gas that are kept below twenty-five percent of the lower flammability limit by the ventilation system. The concentration of hydrogen measured in Hanford waste tanks is greater than that of any other flammable gas. Hydrogen levels measured with a Standard Hydrogen Monitoring System in excess of 0.6 volume percent will cause Westinghouse Hanford Company to consider actions which will decrease the amount of flammable gas in the tank

  5. Method for removing hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Ritter, H.

    1982-08-03T23:59:59.000Z

    An improved sulfur-ammonia process is disclosed for removing hydrogen sulfide from coke oven gases. In the improved process, a concentrator formerly used for standby operation is used at all normal times as an ammonia scrubber to improve the efficiency of gas separation during normal operation and is used as a concentrator for its intended standby functions during the alternative operations. In its normal function, the concentrator/scrubber functions as a scrubber to strip ammonia gas from recirculating liquid streams and to permit introduction of an ammonia-rich gas into a hydrogen sulfide scrubber to increase the separation efficiency of that unit. In the standby operation, the same concentrator/scrubber serves as a concentrator to concentrate hydrogen sulfide in a ''strong liquor'' stream for separate recovery as a strong liquor.

  6. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. (Los Alamos National Lab., NM (United States)); Tie, X. (Scripps Institution of Oceanography, San Diego, CA (United States))

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth's radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  7. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. [Los Alamos National Lab., NM (United States); Tie, X. [Scripps Institution of Oceanography, San Diego, CA (United States)

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth`s radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  8. Redistribution of trace chemical species by a small convective cloud

    SciTech Connect (OSTI)

    Stith, J.L.; Alkezweeny, A.J.; Pleim, J.E.; Ching, J.K.S.

    1993-01-01T23:59:59.000Z

    The paper describes a new experiment with a SF6 tracer to determine the mixing history of a small region of cloud-base air. In situ measurements of the SF6 are made to follow the region and simultaneous measurements of natural trace gases are used to determine the dilution of the tagged region as it is affected by the cloud. After describing the experimental method, the results from an experiment with a small cumulus, which was ideally suited for the experiment, are explained. The goal of the paper is to better understand how convective clouds redistribute trace constituents (e.g. moisture, trace gases) in the vertical.

  9. Algorithms and analysis for underwater vehicle plume tracing.

    SciTech Connect (OSTI)

    Byrne, Raymond Harry; Savage, Elizabeth L. (Texas A& M University, College Station, TX); Hurtado, John Edward (Texas A& M University, College Station, TX); Eskridge, Steven E.

    2003-07-01T23:59:59.000Z

    The goal of this research was to develop and demonstrate cooperative 3-D plume tracing algorithms for miniature autonomous underwater vehicles. Applications for this technology include Lost Asset and Survivor Location Systems (L-SALS) and Ship-in-Port Patrol and Protection (SP3). This research was a joint effort that included Nekton Research, LLC, Sandia National Laboratories, and Texas A&M University. Nekton Research developed the miniature autonomous underwater vehicles while Sandia and Texas A&M developed the 3-D plume tracing algorithms. This report describes the plume tracing algorithm and presents test results from successful underwater testing with pseudo-plume sources.

  10. Corrosion in gas conditioning plants - An overview

    SciTech Connect (OSTI)

    Pearce, B.; Dupart, M.

    1987-01-01T23:59:59.000Z

    Since the early 1800's, fuel gases of various sorts (acetylene, blast furnace gas, flue water gas, carbureted water gas, coal gas, coke oven gas and producer gas) were transmitted at low pressures in pipelines and were conditioned for contaminate removal. The removal of such contaminates as H/sub 2/S was usually accomplished by solid absorbents such as iron oxide, a process that is still in use today. The discovery in the late 20's of a regenerative process employing alkanolamines was instrumental in rapid increase in the use of natural gas in large volumes. Also at this time, the development of wide diameter pipelines that could handle 500-700 psi gas pressure provided the means of handling these large volumes of gas. The protection of the pipeline from corrosion depended upon contaminate removal of water, carbon dioxide and hydrogen sulfide. In the process of contaminant removal, the process equipment suffered severe corrosion damage. Corrosion test methods and inhibitors were applied to those early processes and have advanced from weep holes and coupons to the present way of electronic and physical test methods. The trend is away from the primary amine at either low strength or inhibited at high concentration to less corrosive, ''tailor-made'' solvents that can be designed or formulated to perform a given task at acceptable corrosion rates and at much lower energy levels.

  11. Gas Storage Act (Illinois)

    Broader source: Energy.gov [DOE]

    Any corporation which is engaged in or desires to engage in, the distribution, transportation or storage of natural gas or manufactured gas, which gas, in whole or in part, is intended for ultimate...

  12. Gas Companies Program (Tennessee)

    Broader source: Energy.gov [DOE]

    The Gas Companies program is a set of rules that encourage the development of the natural gas industry in Tennessee. They empower gas companies to lay piped and extend conductors through the...

  13. Gas Utilities (Maine)

    Broader source: Energy.gov [DOE]

    Rules regarding the production, sale, and transfer of manufactured gas will also apply to natural gas. This section regulates natural gas utilities that serve ten or more customers, more than one...

  14. Gas Utilities (New York)

    Broader source: Energy.gov [DOE]

    This chapter regulates natural gas utilities in the State of New York, and describes standards and procedures for gas meters and accessories, gas quality, line and main extensions, transmission and...

  15. Future of Natural Gas

    Office of Environmental Management (EM)

    of Natural Gas Bill Eisele, CEM SC Electric & Gas Co Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral. Florida Agenda * Gas Facts *...

  16. Industrial Gas Turbines

    Broader source: Energy.gov [DOE]

    A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

  17. Supervisory Natural Gas Analyst

    Broader source: Energy.gov [DOE]

    The Department of Energys Office of Fossil Energy, Office of Oil and Natural Gas, Office of Oil and Gas Global Security and Supply (FE) is responsible for regulating natural gas imports and exports...

  18. Trace element partitioning in Texas lignite

    E-Print Network [OSTI]

    Acevedo, Lillian Esther

    1989-01-01T23:59:59.000Z

    lignites and largest individual deposits in Texas occur in the Wilcox group north of the Colorado River; the lowest quality lignite occurs in the Jackson group (2). A comparison between the elemental composition of lignite from the wilcox formation..., Rb, Sc, Th, U, V, Y, Yb, Zn and Zr are positively correlated and B decreases 10 in concentration with increasing levels of ash (15) Combustion. Texas can supply a large portion of its energy needs with its near surface lignite sources (21...

  19. Tracing spiral density waves in M81

    E-Print Network [OSTI]

    S. Kendall; R. C. Kennicutt; C. Clarke; M. D. Thornley

    2008-04-15T23:59:59.000Z

    We use SPITZER IRAC 3.6 and 4.5micron near infrared data from the Spitzer Infrared Nearby Galaxies Survey (SINGS), optical B, V and I and 2MASS Ks band data to produce mass surface density maps of M81. The IRAC 3.6 and 4.5micron data, whilst dominated by emission from old stellar populations, is corrected for small-scale contamination by young stars and PAH emission. The I band data are used to produce a mass surface density map by a B-V colour-correction, following the method of Bell and de Jong. We fit a bulge and exponential disc to each mass map, and subtract these components to reveal the non-axisymmetric mass surface density. From the residual mass maps we are able to extract the amplitude and phase of the density wave, using azimuthal profiles. The response of the gas is observed via dust emission in the 8micron IRAC band, allowing a comparison between the phase of the stellar density wave and gas shock. The relationship between this angular offset and radius suggests that the spiral structure is reasonably long lived and allows the position of corotation to be determined.

  20. Natural Gas Monthly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    other liquids including biofuels and natural gas liquids. Natural Gas Exploration and reserves, storage, imports and exports, production, prices, sales. Electricity Sales, revenue...

  1. Gas Production Tax (Texas)

    Broader source: Energy.gov [DOE]

    A tax of 7.5 percent of the market value of natural gas produced in the state of Texas is imposed on every producer of gas.

  2. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  3. Natural gas dehydration apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

    2006-11-07T23:59:59.000Z

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  4. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  5. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  6. Sodium storage facility trace heat system design description

    SciTech Connect (OSTI)

    Jones, D.D.

    1997-06-12T23:59:59.000Z

    This document describes the SSF PLC Ladder Logic, Cross references, and the software that was used to control the amount of power applied to the SSF Trace Heated components.

  7. L-?Functions and Trace Formula Workshop Schedule

    E-Print Network [OSTI]

    2015-05-11T23:59:59.000Z

    L-?Functions and Trace Formula Workshop Schedule. May 11 – May 13, 2015 at Purdue University. Monday, May 11. 9:15 am – 9:30 am: Casselman/Shahidi:.

  8. Inhibition of trace element release during Fe(II)-activatedrecrystall...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    impurities (e.g., Al) which are known to affect the chemical properties of such minerals. Here we explore the effect of Al(III), Cr(III), and Sn(IV) substitution on trace...

  9. TRACES Centre Thermo GFS35 Graphite Furnace Spectrometer

    E-Print Network [OSTI]

    Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

    TRACES Centre Thermo GFS35 Graphite Furnace Spectrometer Standard Operating Procedure 1. Turn. Click on the lamp icon a. ID the lamp of choice and click the `Off' button to `On' b. Non-Thermo lamps

  10. TRACES Centre Thermo iCE 3500 Flame AA Spectrometer

    E-Print Network [OSTI]

    Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

    TRACES Centre Thermo iCE 3500 Flame AA Spectrometer Standard Operating Procedure 1. Turn on the lamp icon a. ID the lamp of choice and click the `Off' button to `On' b. Non-Thermo lamps MUST

  11. Laboratory measurements and modeling of trace atmospheric species

    E-Print Network [OSTI]

    Sheehy, Philip M. (Philip Michael)

    2005-01-01T23:59:59.000Z

    Trace species play a major role in many physical and chemical processes in the atmosphere. Improving our understanding of the impact of each species requires a combination of laboratory exper- imentation, field measurements, ...

  12. Application of Reinforcement Learning to Requirements Engineering: Requirements Tracing

    E-Print Network [OSTI]

    Hayes, Jane E.

    of the Software Development Life Cycle (SDLC) can be appreciated by the customers who request and expect delivery the phases of the SDLC, a number of steps can be taken. Requirements tracing ensures that requirements

  13. A Virtuous Cycle: Tracing Democratic Quality through Equality 

    E-Print Network [OSTI]

    Ross, Ashley Dyan

    2011-10-21T23:59:59.000Z

    This dissertation asks the question: How do democracies improve in quality? Building on previous scholarship, the author offers a theoretical framework that traces democratic quality through equality of outcomes. The ...

  14. Ichnotaxonomic assessment of Mazon Creek area trace fossils, Illinois, USA

    E-Print Network [OSTI]

    LoBue, David J.

    2010-08-12T23:59:59.000Z

    The Francis Creek Shale Member (FCSM) of the Mid-Pennsylvanian Carbondale Formation along Mazon Creek in northern Illinois is known for soft-bodied organisms preserved within siderite concretions. Trace fossils, though ...

  15. active trace gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF GEOPHYSICAL RESEARCH, VOL. 94, NO. D13, PAGES 16,417-16,421,NOVEMBER 20, 1989 Greenhouse Effect of Chlorofluorocarbons and Other Trace Gases Environmental Sciences and Ecology...

  16. Affine braids, Markov traces and the category O Rosa Orellana

    E-Print Network [OSTI]

    Ram, Arun

    , affine BMW algebras, cyclotomic BMW algebras, Markov traces, Jacobi-Trudi type identities, dual pairs [Ze of affine braid groups of type A, (d) We define the affine BMW algebra (Birman-Murakami-Wenzl) and show

  17. High precision measurements of atmospheric concentrations and plant exchange rates of carbonyl

    E-Print Network [OSTI]

    Yakir, Dan

    High precision measurements of atmospheric concentrations and plant exchange rates of carbonyl K I R * *Environmental Sciences and Energy Research, The Weizmann Institute of Science, Rehovot. The results were consistent with those of nononline gas chromatography­mass spectrometry for COS and IR gas

  18. Trace determination of lead by helium-4 activation analysis 

    E-Print Network [OSTI]

    Vargas Bernal, Maria E.

    1984-01-01T23:59:59.000Z

    TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1984 Major Subject: Chemistry TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Approved as to style and format by: Emile A. Schweikert (Chairman of Committee) Marvin W. Rowe (Member) Gerald A. Sc...

  19. Trace determination of lead by helium-4 activation analysis

    E-Print Network [OSTI]

    Vargas Bernal, Maria E.

    1984-01-01T23:59:59.000Z

    TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1984 Major Subject: Chemistry TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Approved as to style and format by: Emile A. Schweikert (Chairman of Committee) Marvin W. Rowe (Member) Gerald A. Sc...

  20. The Fidelity and Trace Norm Distances for Quantifying Coherence

    E-Print Network [OSTI]

    Lian-He Shao; Zhengjun Xi; Heng Fan; Yongming Li

    2014-10-30T23:59:59.000Z

    We investigate the coherence measures induced by fidelity and trace norm, based on the recent proposed coherence quantification in [Phys. Rev. Lett. 113, 140401, 2014]. We show that the fidelity of coherence does not in general satisfy the monotonicity requirement as a measure of coherence under the subselection of measurements condition. We find that the trace norm of coherence can act as a measure of coherence for qubit case and some special class of qutrits.

  1. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect (OSTI)

    T.D. Wheelock

    1999-03-01T23:59:59.000Z

    The technical feasibility of a gas agglomeration method for cleaning coal was demonstrated by means of bench-scale tests conducted with a mixing system which enabled the treatment of ultra-fine coal particles with a colloidal suspension of microscopic gas bubbles in water. A suitable suspension of microbubbles was prepared by first saturating water with air or carbon dioxide under pressure then reducing the pressure to release the dissolved gas. The formation of microbubbles was facilitated by agitation and a small amount of i-octane. When the suspension of microbubbles and coal particles was mixed, agglomeration was rapid and small spherical agglomerates were produced. Since the agglomerates floated, they were separated from the nonfloating tailings in a settling chamber. By employing this process in numerous agglomeration tests of moderately hydrophobic coals with 26 wt.% ash, it was shown that the ash content would be reduced to 6--7 wt.% while achieving a coal recovery of 75 to 85% on a dry, ash-free basis. This was accomplished by employing a solids concentration of 3 to 5 w/w%, an air saturation pressure of 136 to 205 kPa (5 to 15 psig), and an i-octane concentration of 1.0 v/w% based on the weight of coal.

  2. Gas Feedback on Stellar Bar Evolution

    E-Print Network [OSTI]

    Ingo Berentzen; Isaac Shlosman; Inma Martinez-Valpuesta; Clayton Heller

    2007-05-27T23:59:59.000Z

    We analyze evolution of live disk-halo systems in the presence of various gas fractions, f_gas less than 8% in the disk. We addressed the issue of angular momentum (J) transfer from the gas to the bar and its effect on the bar evolution. We find that the weakening of the bar, reported in the literature, is not related to the J-exchange with the gas, but is caused by the vertical buckling instability in the gas-poor disks and by a steep heating of a stellar velocity dispersion by the central mass concentration (CMC) in the gas-rich disks. The gas has a profound effect on the onset of the buckling -- larger f_gas brings it forth due to the more massive CMCs. The former process leads to the well-known formation of the peanut-shaped bulges, while the latter results in the formation of progressively more elliptical bulges, for larger f_gas. The subsequent (secular) evolution of the bar differs -- the gas-poor models exhibit a growing bar while gas-rich models show a declining bar whose vertical swelling is driven by a secular resonance heating. The border line between the gas-poor and -rich models lies at f_gas ~ 3% in our models, but is model-dependent and will be affected by additional processes, like star formation and feedback from stellar evolution. The overall effect of the gas on the evolution of the bar is not in a direct J transfer to the stars, but in the loss of J by the gas and its influx to the center that increases the CMC. The more massive CMC damps the vertical buckling instability and depopulates orbits responsible for the appearance of peanut-shaped bulges. The action of resonant and non-resonant processes in gas-poor and gas-rich disks leads to a converging evolution in the vertical extent of the bar and its stellar dispersion velocities, and to a diverging evolution in the bulge properties.

  3. Investigation of trace amounts of gas on microvave water-cut measurement 

    E-Print Network [OSTI]

    Liu, Jin

    2006-08-16T23:59:59.000Z

    sampling probe or a sampling port on the pipeline. Then, the oil and water are separated using a centrifuge. Finally, the volume of the separated water is measured and the water-cut of the sample is calculated based on the total volume of the liquid... pipeline; 2. The oil/water monitor generates the current or electrical signal transmit to a zero-&- span adjuster; 3. From the zero-&-span adjuster, the data is transmitted from analog to digital at converter and calculator and to a comparator. 4...

  4. Estimation of mixing in the troposphere from1 Lagrangian trace gas reconstructions during2

    E-Print Network [OSTI]

    Legras, Bernard

    of Physics and Atmospheric Science, Dalhousie University, Halifax, Canada 7 Institut f¨ur Physik der Atmosph for Mathematical Sciences University of Cambridge (i.pisso@damtp.cam.ac.uk) 1 Department of Applied Mathematics

  5. COMPACT QEPAS SENSOR FOR TRACE METHANE AND AMMONIA DETECTION IN IMPURE HYDROGEN

    SciTech Connect (OSTI)

    Wright, J; Ferguson, B; Peters, B; Mcwhorter, S

    2011-11-02T23:59:59.000Z

    A compact two-gas sensor based on quartz enhanced photoacoustic spectroscopy (QEPAS) was developed for trace methane and ammonia quantification in impure hydrogen. The sensor is equipped with a micro-resonator to confine the sound wave and enhance QEPAS signal. The normalized noise-equivalent absorption coefficients (1{sigma}) of 2.45 x 10{sup -8} cm{sup -1}W/{radical}Hz and 9.1 x 10{sup -9} cm{sup -1}W/{radical}Hz for CH{sub 4} detection at 200 Torr and NH{sub 3} detection at 50 Torr were demonstrated with the QEPAS sensor configuration, respectively. The influence of water vapor on the CH{sub 4} channel was also investigated.

  6. Naturally fractured tight gas reservoir detection optimization. Quarterly report, January 1, 1997--March 31, 1997

    SciTech Connect (OSTI)

    NONE

    1998-04-01T23:59:59.000Z

    This document contains the quarterly report dated January 1-March 31, 1997 for the Naturally Fractured Tight Gas Reservoir Detection Optimization project. Topics covered in this report include AVOA modeling using paraxial ray tracing, AVOA modeling for gas- and water-filled fractures, 3-D and 3-C processing, and technology transfer material. Several presentations from a Geophysical Applications Workshop workbook, workshop schedule, and list of workshop attendees are also included.

  7. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01T23:59:59.000Z

    fuels (eg diesel, compressed natural gas). Electricity (infossil fuels, such as compressed natural gas and liquefied

  8. Compressed gas manifold

    DOE Patents [OSTI]

    Hildebrand, Richard J. (Edgemere, MD); Wozniak, John J. (Columbia, MD)

    2001-01-01T23:59:59.000Z

    A compressed gas storage cell interconnecting manifold including a thermally activated pressure relief device, a manual safety shut-off valve, and a port for connecting the compressed gas storage cells to a motor vehicle power source and to a refueling adapter. The manifold is mechanically and pneumatically connected to a compressed gas storage cell by a bolt including a gas passage therein.

  9. Noble gas magnetic resonator

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2014-04-15T23:59:59.000Z

    Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

  10. OIL & GAS INSTITUTE Introduction

    E-Print Network [OSTI]

    Mottram, Nigel

    OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

  11. Arthur-Selberg trace formula CRM, June 30-July 3, 2009

    E-Print Network [OSTI]

    Lapid, Erez

    #12;#12;Arthur-Selberg trace formula Erez Lapid CRM, June 30-July 3, 2009 #12;Contents Applications of the Selberg Trace Formula 1. Weyl's law #12;Contents Applications of the Selberg Trace Formula 1. Weyl's law 2. Prime Geodesic Theorem #12;Contents Applications of the Selberg Trace Formula 1. Weyl's law 2. Prime

  12. Effect of Sawtooth Activity on Tritium and Beam Deuterium Evolution in Trace Tritium Experiments on JET

    E-Print Network [OSTI]

    Effect of Sawtooth Activity on Tritium and Beam Deuterium Evolution in Trace Tritium Experiments on JET

  13. New Safety and Technical Challenges and Operational Experience on the JET First Trace Tritium Experiment

    E-Print Network [OSTI]

    New Safety and Technical Challenges and Operational Experience on the JET First Trace Tritium Experiment

  14. Process for concentrated biomass saccharification

    DOE Patents [OSTI]

    Hennessey, Susan M. (Avondale, PA); Seapan, Mayis (Landenberg, PA); Elander, Richard T. (Evergreen, CO); Tucker, Melvin P. (Lakewood, CO)

    2010-10-05T23:59:59.000Z

    Processes for saccharification of pretreated biomass to obtain high concentrations of fermentable sugars are provided. Specifically, a process was developed that uses a fed batch approach with particle size reduction to provide a high dry weight of biomass content enzymatic saccharification reaction, which produces a high sugars concentration hydrolysate, using a low cost reactor system.

  15. Declaration of Concentration in Nanotechnology

    E-Print Network [OSTI]

    Goldberg, Bennett

    Declaration of Concentration in Nanotechnology Return completed form to ENG Undergraduate Records:____________________________ Instructions: ENG students declaring a Concentration in Nanotechnology should complete this form, obtain REQUIRED COURSES (Choose 1) 1. ENG EC 481­ Fundamentals of Nanomaterials and Nanotechnology 4.0 ELECTIVES

  16. Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia

    SciTech Connect (OSTI)

    Vukasinovic-Pesic, V.; Rajakovic, L.J. [University of Montenegro, Podgorica (Montenegro)

    2009-07-01T23:59:59.000Z

    The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn in the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.

  17. Natural gas monthly

    SciTech Connect (OSTI)

    NONE

    1998-01-01T23:59:59.000Z

    The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the Natural Gas Monthly features articles designed to assist readers in using and interpreting natural gas information.

  18. LONG-TERM DETERMINATION OF AIRBORNE RADON PROGENY CONCENTRATIONS USING LR 115 DETECTORS

    E-Print Network [OSTI]

    Yu, K.N.

    LONG-TERM DETERMINATION OF AIRBORNE RADON PROGENY CONCENTRATIONS USING LR 115 DETECTORS dose in the lung is mainly due to short-lived radon progeny, i.e. 218 Po, 214 Pb, 214 Bi and 214 Po, but not the radon (222 Rn) gas itself. Accordingly, long-term measure- ments of the concentrations of radon progeny

  19. Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas M. V. Romalis

    E-Print Network [OSTI]

    Romalis, Mike

    Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas M. V. Romalis; published 7 December 2010) Optical pumping of an optically thick atomic vapor typically requires a quenching the atoms. We show that optical pumping of a trace contamination of Rb present in K metal results in a 4

  20. Evaluation of high-efficiency gas-liquid contactors for natural gas processing. Semi-annual report, April--September 1995

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    The objective of this proposed program is to ensure reliable supply of high-quality natural gas by reducing the cost of treating subquality natural gas containing H{sub 2}O, CO{sub 2}, H{sub 2}S and/or trace quantities of other gaseous impurities by applying high-efficiency rotating and structured packing gas liquid contactors. Work accomplished during this reporting period are discussed for the following tasks: Task 2, field experimental site seletion; Task 3, field experimental skid unit design and preliminary economic evaluations; and Task 6, fluid dynamic studies.

  1. Model for trace metal exposure in filter-feeding flamingos at alkaline Rift Valley Lake, Kenya

    SciTech Connect (OSTI)

    Nelson, Y.M.; DiSante, C.J.; Lion, L.W. [Cornell Univ., Ithaca, NY (United States). School of Civil and Environmental Engineering; Thampy, R.J.; Raini, J.A. [Worldwide Fund for Nature, Nakuru (Kenya). Lake Nakuru Conservation and Development Project; Motelin, G.K. [Egerton Univ., Njoro (Kenya). Dept. of Animal Health

    1998-11-01T23:59:59.000Z

    Toxic trace metals have been implicated as a potential cause of recent flamingo kills at Lake Nakuru, Kenya. Chromium (Cr), copper (Cu), lead (Pb), and zinc (Zn) have accumulated in the lake sediments as a result of unregulated discharges and because this alkaline lake has no natural outlet. Lesser flamingos (Phoeniconaias minor) at Lake Nakuru feed predominantly on the cyanobacterium Spirulina platensis, and because of their filter-feeding mechanism, they are susceptible to exposure to particle-bound metals. Trace metal adsorption isotherms to lake sediments and S. platensis were obtained under simulated lake conditions, and a mathematical model was developed to predict metal exposure via filter feeding based on predicted trace metal phase distribution. Metal adsorption to suspended solids followed the trend Pb {much_gt} Zn > Cr > Cu, and isotherms were linear up to 60 {micro}g/L. Adsorption to S. platensis cells followed the trend Pb {much_gt} Zn > Cu > Cr and fit Langmuir isotherms for Cr, Cu and Zn and a linear isotherm for Pb. Predicted phase distributions indicated that Cr and Pb in Lake Nakuru are predominantly associated with suspended solids, whereas Cu and Zn are distributed more evenly between the dissolved phase and particulate phases of both S. platensis and suspended solids. Based on established flamingo feeding rates and particle size selection, predicted Cr and Pb exposure occurs predominantly through ingestion of suspended solids, whereas Cu and Zn exposure occurs through ingestion of both suspended solids and S. platensis. For the lake conditions at the time of sampling, predicted ingestion rates based on measured metal concentrations in lake suspended solids were 0.71, 6.2, 0.81, and 13 mg/kg-d for Cr, Cu, Pb, and Zn, respectively.

  2. NO concentration imaging in turbulent nonpremixed flames

    SciTech Connect (OSTI)

    Schefer, R.W. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01T23:59:59.000Z

    The importance of NO as a pollutant species is well known. An understanding of the formation characteristics of NO in turbulent hydrocarbon flames is important to both the desired reduction of pollutant emissions and the validation of proposed models for turbulent reacting flows. Of particular interest is the relationship between NO formation and the local flame zone, in which the fuel is oxidized and primary heat release occurs. Planar imaging of NO provides the multipoint statistics needed to relate NO formation to the both the flame zone and the local turbulence characteristics. Planar imaging of NO has been demonstrated in turbulent flames where NO was seeded into the flow at high concentrations (2000 ppm) to determine the gas temperature distribution. The NO concentrations in these experiments were significantly higher than those expected in typical hydrocarbon-air flames, which require a much lower detectability limit for NO measurements. An imaging technique based on laser-induced fluorescence with sufficient sensitivity to study the NO formation mechanism in the stabilization region of turbulent lifted-jet methane flames.

  3. ADVANCED HOT GAS FILTER DEVELOPMENT

    SciTech Connect (OSTI)

    Matthew R. June; John L. Hurley; Mark W. Johnson

    1999-04-01T23:59:59.000Z

    Iron aluminide hot gas filters have been developed using powder metallurgy techniques to form seamless cylinders. Three alloys were short-term corrosion tested in simulated IGCC atmospheres with temperatures between 925 F and 1200 F with hydrogen sulfide concentrations ranging from 783 ppm{sub v} to 78,300 ppm{sub v}. Long-term testing was conducted for 1500 hours at 925 F with 78,300 ppm{sub v}. The FAS and FAL alloys were found to be corrosion resistant in the simulated environments. The FAS alloy has been commercialized.

  4. Gas separation using ultrasound and light absorption

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM)

    2012-07-31T23:59:59.000Z

    An apparatus and method for separating a chosen gas from a mixture of gases having no moving parts and utilizing no chemical processing is described. The separation of particulates from fluid carriers thereof has been observed using ultrasound. In a similar manner, molecular species may be separated from carrier species. It is also known that light-induced drift may separate light-absorbing species from carrier species. Therefore, the combination of temporally pulsed absorption of light with ultrasonic concentration is expected to significantly increase the efficiency of separation by ultrasonic concentration alone. Additionally, breaking the spatial symmetry of a cylindrical acoustic concentrator decreases the spatial distribution of the concentrated particles, and increases the concentration efficiency.

  5. Automated micro-tracking planar solar concentrators

    E-Print Network [OSTI]

    Hallas, Justin Matthew

    2011-01-01T23:59:59.000Z

    E. Ford, “Reactive self-tracking solar concentration: designFord, “Reactive self- tracking solar concentration: designAutomated Micro-Tracking Planar Solar Concentrators by

  6. Tax credit for tight-sands gas

    SciTech Connect (OSTI)

    Schugart, G.L.

    1985-06-01T23:59:59.000Z

    There is a $3 per barrel tax credit, which is tied to crude oil prices, in the Windfall Profits Tax (WPT) for producing fuels from certain unconventional sources. Concentrating on the tight gas formations section of qualifying fuels, the author examines the tax credit and certain factors natural gas producers may want to consider in deciding on whether to choose the tax credit or the incentive prices of the Natural Gas Policy Act. The decline in oil prices is significant enough to provide some producers an opportunity to take advantage of the tax credit. They should do some tax planning by calculating the estimated break-even point for NGPA incentive prices and the nonconventional gas production tax credit.

  7. Development of large-capacity gas-insulated transformer

    SciTech Connect (OSTI)

    Takahashi, E.; Tanaka, K. [Tokyo Electric Power Co., Ltd. (Japan)] [Tokyo Electric Power Co., Ltd. (Japan); Toda, K.; Ikeda, M.; Teranishi, T.; Inaba, M.; Yanari, T. [Toshiba Corp., Kawasaki (Japan)] [Toshiba Corp., Kawasaki (Japan)

    1996-04-01T23:59:59.000Z

    Concentrations of population and business activities result in high electricity demand in urban areas. This requires the construction of large-capacity underground substations. Oilless, non-flammable and non-explosive equipment is recommended for underground substations. Therefore, several types of large-capacity gas-insulated transformer have been developed. Because the gas forced cooling type was considered to be available up to approximately 60 MVA, all of these gas-insulated transformers are liquid cooled. But the liquid cooling type has the disadvantage of a complex structure for liquid cooling. For this reason, the authors have been studying the development of a simple design for a gas forced cooling, large-capacity gas-insulated transformer. This paper discusses research and development of cooling and insulation technology for a large-capacity gas-insulated transformer and the development of a 275 kV, 300 MVA gas-insulated transformer.

  8. Inferential determination of various properties of a gas mixture

    DOE Patents [OSTI]

    Morrow, Thomas B. (San Antonio, TX); Behring, II, Kendricks A. (Torrance, CA)

    2007-03-27T23:59:59.000Z

    Methods for inferentially determining various properties of a gas mixture, when the speed of sound in the gas is known at an arbitrary temperature and pressure. The method can be applied to natural gas mixtures, where the known parameters are the sound speed, temperature, pressure, and concentrations of any dilute components of the gas. The method uses a set of reference gases and their calculated density and speed of sound values to estimate the density of the subject gas. Additional calculations can be made to estimate the molecular weight of the subject gas, which can then be used as the basis for heating value calculations. The method may also be applied to inferentially determine density and molecular weight for gas mixtures other than natural gases.

  9. Sulfur doping of diamond films: Spectroscopic, electronic, and gas-phase studies

    E-Print Network [OSTI]

    Bristol, University of

    with various levels of H2S addition 100­5000 ppm , using both microwave MW plasma enhanced CVD and hot filament is virtually unaffected by gas phase H2S concentration, and the films remain highly resistive. In contrast of S incorporation is directly proportional to the H2S concentration in the gas phase. Secondary electron microscopy

  10. Design of inflatable solar concentrator

    E-Print Network [OSTI]

    Carrasquillo, Omar (Omar Y. Carrasquillo De Armas)

    2013-01-01T23:59:59.000Z

    Solar concentrators improve the performance of solar collection systems by increasing the amount of usable energy available for a given collector size. Unfortunately, they are not known for their light weight and portability, ...

  11. Energy 101: Concentrating Solar Power

    Broader source: Energy.gov [DOE]

    From towers to dishes to linear mirrors to troughs, concentrating solar power (CSP) technologies reflect and collect solar heat to generate electricity. A single CSP plant can generate enough power...

  12. Physics and Astronomy Geophysics Concentration

    E-Print Network [OSTI]

    Thaxton, Christopher S.

    Physics and Astronomy Geophysics Concentration Strongly recommended courses Credits Term Dept. to Geophysics 3 PHY 3230 Thermal Physics 3 CHE 1101 Introductory Chemistry - I 3 CHE 1110 Introductory Chemistry

  13. Optimal concentrations in transport systems

    E-Print Network [OSTI]

    Kim, Wonjung

    Many biological and man-made systems rely on transport systems for the distribution of material, for example matter and energy. Material transfer in these systems is determined by the flow rate and the concentration of ...

  14. Reversible concentric ring microfluidic interconnects

    E-Print Network [OSTI]

    Thompson, Mary Kathryn, 1980-

    2004-01-01T23:59:59.000Z

    A reversible, Chip-to-Chip microfluidic interconnect was designed for use in high temperature, high pressure applications such as chemical microreactor systems. The interconnect uses two sets of concentric, interlocking ...

  15. Optimal concentrations in nectar feeding

    E-Print Network [OSTI]

    Kim, Wonjung

    Nectar drinkers must feed quickly and efficiently due to the threat of predation. While the sweetest nectar offers the greatest energetic rewards, the sharp increase of viscosity with sugar concentration makes it the most ...

  16. Concentrated solar power on demand

    E-Print Network [OSTI]

    Codd, Daniel Shawn

    2011-01-01T23:59:59.000Z

    This thesis describes a new concentrating solar power central receiver system with integral thermal storage. Hillside mounted heliostats direct sunlight into a volumetric absorption molten salt pool, which also functions ...

  17. AN OVERVIEW OF TOOL FOR RESPONSE ACTION COST ESTIMATING (TRACE)

    SciTech Connect (OSTI)

    FERRIES SR; KLINK KL; OSTAPKOWICZ B

    2012-01-30T23:59:59.000Z

    Tools and techniques that provide improved performance and reduced costs are important to government programs, particularly in current times. An opportunity for improvement was identified for preparation of cost estimates used to support the evaluation of response action alternatives. As a result, CH2M HILL Plateau Remediation Company has developed Tool for Response Action Cost Estimating (TRACE). TRACE is a multi-page Microsoft Excel{reg_sign} workbook developed to introduce efficiencies into the timely and consistent production of cost estimates for response action alternatives. This tool combines costs derived from extensive site-specific runs of commercially available remediation cost models with site-specific and estimator-researched and derived costs, providing the best estimating sources available. TRACE also provides for common quantity and key parameter links across multiple alternatives, maximizing ease of updating estimates and performing sensitivity analyses, and ensuring consistency.

  18. Cost of Gas Adjustment for Gas Utilities (Maine)

    Broader source: Energy.gov [DOE]

    This rule, applicable to gas utilities, establishes rules for calculation of gas cost adjustments, procedures to be followed in establishing gas cost adjustments and refunds, and describes reports...

  19. Electrochromically switched, gas-reservoir metal hydride devices with application to energy-efficient windows

    E-Print Network [OSTI]

    concentration) in the gas volume between glass panes of the insulated glass units (IGUs). The elimination is an option but it requires well controlled gas exchange processes. Alternatively, and from many pointsElectrochromically switched, gas-reservoir metal hydride devices with application to energy

  20. Combined-cycle solarised gas turbine with steam, organic and CO2 bottoming cycles

    E-Print Network [OSTI]

    Combined-cycle solarised gas turbine with steam, organic and CO2 bottoming cycles John Pye, Keith of the technical feasibility a solarised combined-cycle gas turbines with a dish concentrator, with several, optimised for the new SG4 collector. This study aims to determine whether a combined-cycle gas turbine (CCGT

  1. Study of Marine Gas Hydrate on the Northern Cascadia Margin: Constraints from Logging and

    E-Print Network [OSTI]

    Study of Marine Gas Hydrate on the Northern Cascadia Margin: Constraints from Logging and Seismic and gas explaining the high hydrate concentrations at shallow depths of less than 100 meters below of the degree of Master of Science © Xuan Wang 2009 #12; i ABSTRACT This thesis presents estimates of gas

  2. Enhanced membrane gas separations

    SciTech Connect (OSTI)

    Prasad, R.

    1993-07-13T23:59:59.000Z

    An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

  3. Trace metal mapping by laser-induced breakdown spectroscopy

    SciTech Connect (OSTI)

    Kaiser, Jozef [ORNL; Novotny, Dr. Karel [Masaryk University; Hrdlicka, A [Brno University of Technology, Czech Republic; Malina, R [Brno University of Technology, Czech Republic; Hartl, M [Brno University of Technology, Czech Republic; Kizek, R [Mendel University of Brno; Adam, V [Mendel University of Brno

    2012-01-01T23:59:59.000Z

    Abstract: Laser-Induced Breakdown Spectroscopy (LIBS) is a sensitive optical technique capable of fast multi-elemental analysis of solid, gaseous and liquid samples. The potential applications of lasers for spectrochemical analysis were developed shortly after its invention; however the massive development of LIBS is connected with the availability of powerful pulsed laser sources. Since the late 80s of 20th century LIBS dominated the analytical atomic spectroscopy scene and its application are developed continuously. Here we review the utilization of LIBS for trace elements mapping in different matrices. The main emphasis is on trace metal mapping in biological samples.

  4. Separation of sulfur and trace elements from high-viscosity petroleums and tar sands

    SciTech Connect (OSTI)

    Nadirov, N.K.; Bychkova, L.V.; Rudenko, N.V.; Dzhakupova, A.N.; Sarsembaeva, B.K.

    1992-07-10T23:59:59.000Z

    Characteristic features of high-viscosity petroleums and tar sands of western Kazakhstan are a great chemical nonuniformity, a diverse combination of proportions of aromatic and heteroatomic structures, and a wide variation in trace-element composition. They contain, moreover, large quantities of aliphatic ethers and esters, sulfo acids, cyclic hydrocarbons, and other valuable components that may be used in the chemical, petrochemical, and other industries. The authors study employed acetylacetone or propanol for organic solvent extraction of a sulfurous concentrate, magnifying the selective separation of organosulfur compounds with the use of ultrasonic phase stratification. Oxidation of organosulfur compounds to sulfoxides, sulfones, and sulfo acids was accomplished with ionizing radiation from Co{sup 60}. 17 refs., 2 tabs.

  5. The impact of scavenging on trace metal budgets in Puget Sound

    SciTech Connect (OSTI)

    Paulson, A.J.; Feely, R.A.; Curl, H.C. Jr.; Geiselman, T. (National Oceanic and Atmospheric Administration, Seattle, WA (USA)); Crecelius, E.A. (Battelle Marine Research Laboratory, Sequim, WA (USA))

    1988-07-01T23:59:59.000Z

    The distributions of dissolved and particulate Mn, Pb, Cu and Zn in Puget Sound, its tributaries, and its sediments were determined to illustrate the impact of scavenging reactions on trace metal budgets of a large fjordlike estuary. About 75% of the dissolved Pb discharged into the main basin of Puget Sound was scavenged from the dissolved phase. The high particulate Pb concentrations in regions of high particulate Mn concentrations and the significant correlations between Pb and Mn concentrations on suspended particles demonstrate the importance of hydrous manganese oxide phases in scavenging dissolved Pb. Since particles are effectively retained within the main basin, scavenging results in the sedimentation of about 70% of the total Pb added to the main basin. Only isolated instances of scavenging of dissolved Cu and Zn were observed and the discharge rates of dissolved Cu and Zn from known sources were equal to their rates of advective removal within the errors of the budge. The remineralization of organically-bound particulate Cu is partly responsible for its quasi-conservative behavior within the main basin of Puget Sound. The fates of Cu and Zn are controlled mainly by physical processes such as advection and settling of particles. Advection removes about 60% of the total Cu and Zn added to the main basin while 40% is deposited in the sediments of Puget Sound.

  6. Trace species detection: Spectroscopy and molecular energy transfer at high temperature

    SciTech Connect (OSTI)

    Gray, J.A. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01T23:59:59.000Z

    Monitoring the concentration of trace species such as atomic and molecular free radicals is essential in forming predictive models of combustion processes. LIF-based techniques have the necessary sensitivity for concentration and temperature measurements but have limited accuracy due to collisional quenching in combustion applications. The goal of this program is to use spectroscopic and kinetic measurements to quantify nonradiative and collisional effects on LIF signals and to develop new background-free alternatives to LIF. The authors have measured the natural linewidth of several OH A-X (3,0) rotational transitions to determine predissociation lifetimes in the upper state, which were presumed to be short compared to quenching lifetimes, and as a result, quantitative predictions about the applicability of predissociation fluorescence methods at high pressures are made. The authors are investigating collisional energy transfer in the A-state of NO. Quenching rates which enable direct corrections to NO LIF quantum yields at high temperature were calculations. These quenching rates are now being used in studies of turbulence/chemistry interactions. The authors have measured the electric dipole moment {mu} of excited-state NO using Stark quantum-beat spectroscopy. {mu} is an essential input to a harpoon model which predicts quenching efficiencies for NO (A) by a variety of combustion-related species. The authors are developing new coherent multiphoton techniques for measurements of atomic hydrogen concentration in laboratory flames to avoid the quenching problems associated with previous multiphoton LIF schemes.

  7. Soil and Water Science Department University of Florida Background concentrations of trace metals in Florida surface soils

    E-Print Network [OSTI]

    Ma, Lena

    using Teflon pressure bombs in a microwave digestion oven and analyzed using a graphite furnace atomic absorption spectrometer (GFAAS), an inductively coupled plasma-mass spectrometer (ICP/MS) and an inductively

  8. Concentrating Solar Power: Efficiently Leveraging Equilibrium...

    Office of Environmental Management (EM)

    Concentrating Solar Power: Efficiently Leveraging Equilibrium Mechanisms for Engineering New Thermochemical Storage Concentrating Solar Power: Efficiently Leveraging Equilibrium...

  9. Homogeneous and Heterogeneous Reaction and Transformation of Hg and Trace Metals in Combustion Systems

    SciTech Connect (OSTI)

    J. Helble; Clara Smith; David Miller

    2009-08-31T23:59:59.000Z

    The overall goal of this project was to produce a working dynamic model to predict the transformation and partitioning of trace metals resulting from combustion of a broad range of fuels. The information provided from this model will be instrumental in efforts to identify fuels and conditions that can be varied to reduce metal emissions. Through the course of this project, it was determined that mercury (Hg) and arsenic (As) would be the focus of the experimental investigation. Experiments were therefore conducted to examine homogeneous and heterogeneous mercury oxidation pathways, and to assess potential interactions between arsenic and calcium. As described in this report, results indicated that the role of SO{sub 2} on Hg oxidation was complex and depended upon overall gas phase chemistry, that iron oxide (hematite) particles contributed directly to heterogeneous Hg oxidation, and that As-Ca interactions occurred through both gas-solid and within-char reaction pathways. Modeling based on this study indicated that, depending upon coal type and fly ash particle size, vaporization-condensation, vaporization-surface reaction, and As-CaO in-char reaction all play a role in arsenic transformations under combustion conditions.

  10. COMPUTATIONAL OPTIMIZATION OF GAS COMPRESSOR ...

    E-Print Network [OSTI]

    2015-02-26T23:59:59.000Z

    Feb 26, 2015 ... When considering cost-optimal operation of gas transport net- works ..... The four most frequently used drive types are gas turbines, gas driven.

  11. Purchased Gas Adjustment Rules (Tennessee)

    Broader source: Energy.gov [DOE]

    The Purchased Gas Adjustment Rules are implemented by the Tennessee Regulatory Authority (Authority). Purchased Gas Adjustment (PGA) Rules are intended to permit the company/LDC (local gas...

  12. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01T23:59:59.000Z

    natural gas and liquefied petroleum gas have continued to make small contributions to transportation,transportation actions include electric power sector actions, eg coal to natural gas

  13. Natural gas annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-09-01T23:59:59.000Z

    This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

  14. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, J.F.

    1992-02-25T23:59:59.000Z

    A positive displacement, recirculating Roots-type rotary gas compressor is described which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits which return compressed discharge gas to the compressor housing, where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor. 12 figs.

  15. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, John F. (601 Oakwood Loop, NE., Albuquerque, NM 87123)

    1992-01-01T23:59:59.000Z

    A positive displacement, recirculating Roots-type rotary gas compressor which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits (24 and 26) which return compressed discharge gas to the compressor housing (14), where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers (10 and 12) and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor.

  16. Gas and Oil (Maryland)

    Broader source: Energy.gov [DOE]

    The Department of the Environment has the authority to enact regulations pertaining to oil and gas production, but it cannot prorate or limit the output of any gas or oil well. A permit from the...

  17. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, Conrad M. (Antioch, CA)

    1996-01-01T23:59:59.000Z

    A microminiature gas chromatograph (.mu.GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode.

  18. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, C.M.

    1996-12-10T23:59:59.000Z

    A microminiature gas chromatograph ({mu}GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode. 7 figs.

  19. Thermal stress analysis of eccentric tube receiver using concentrated solar radiation

    SciTech Connect (OSTI)

    Wang, Fuqiang; Shuai, Yong; Yuan, Yuan; Yang, Guo; Tan, Heping [School of Energy Science and Engineering, Harbin Institute of Technology, 92, West Dazhi Street, Harbin 150001 (China)

    2010-10-15T23:59:59.000Z

    In the parabolic trough concentrator with tube receiver system, the heat transfer fluid flowing through the tube receiver can induce high thermal stress and deflection. In this study, the eccentric tube receiver is introduced with the aim to reduce the thermal stresses of tube receiver. The ray-thermal-structural sequential coupled numerical analyses are adopted to obtain the concentrated heat flux distributions, temperature distributions and thermal stress fields of both the eccentric and concentric tube receivers. During the sequential coupled numerical analyses, the concentrated heat flux distribution on the bottom half periphery of tube receiver is obtained by Monte-Carlo ray tracing method, and the fitting function method is introduced for the calculated heat flux distribution transformation from the Monte-Carlo ray tracing model to the CFD analysis model. The temperature distributions and thermal stress fields are obtained by the CFD and FEA analyses, respectively. The effects of eccentricity and oriented angle variation on the thermal stresses of eccentric tube receiver are also investigated. It is recommended to adopt the eccentric tube receiver with optimum eccentricity and 90 oriented angle as tube receiver for the parabolic trough concentrator system to reduce the thermal stresses. (author)

  20. Residual gas analysis device

    DOE Patents [OSTI]

    Thornberg, Steven M. (Peralta, NM)

    2012-07-31T23:59:59.000Z

    A system is provided for testing the hermeticity of a package, such as a microelectromechanical systems package containing a sealed gas volume, with a sampling device that has the capability to isolate the package and breach the gas seal connected to a pulse valve that can controllably transmit small volumes down to 2 nanoliters to a gas chamber for analysis using gas chromatography/mass spectroscopy diagnostics.

  1. Natural gas annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1995 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1991 to 1995 for each Census Division and each State. Annual historical data are shown at the national level.

  2. Natural gas annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-11-17T23:59:59.000Z

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1994 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1990 to 1994 for each Census Division and each State. Annual historical data are shown at the national level.

  3. Poly(methylmethacrylate) adsorption onto flat substrates of glass and silica: Influence of water traces in solvent

    SciTech Connect (OSTI)

    Berquier, J. [Laboratoire CNRS-Saint-Gobain (UMR 125) 39, Quai Lucien Lefranc, F-93303 Aubervilliers Cedex

    1996-01-01T23:59:59.000Z

    The adsorbed amount of PMMA on flat glass and silica is measured by infrared external reflection. The effect on PMMA adsorption of water traces in solvent is emphasized: the adsorbed amount increases with the water concentration. Flat glass and silica are compared: on contrary of what is expected, adsorbed amount on glass is higher than on silica. This result is interpreted as due to the difference of behaviour between glass and silica with respect to water adsorption. {copyright} {ital 1996 American Institute of Physics.}

  4. Gas separations using ceramic membranes. Final report, September 1988--February 1993

    SciTech Connect (OSTI)

    Lin, C.L.; Wu, J.C.S.; Gallaher, G.R.; Smith, G.W.; Flowers, D.L.; Gerdes, T.E.; Liu, P.K.T.

    1993-02-01T23:59:59.000Z

    This study covers a comprehensive evaluation of existing ceramic membranes for high temperature gas separations. Methodology has been established for microporous characterization stability and gas separation efficiency. A mathematical model was developed to predict gas separations with existing membranes. Silica and zeolitic modifications of existing membranes were pursued to enhance its separation efficiency. Some of which demonstrate unique separations properties. Use of the dense-silica membranes for hydrogen enrichment was identified as a promising candidate for future development. In addition, the decomposition of trace ammonia contaminant via a catalytic membrane reactor appears feasible. A further economic analysis is required to assess its commercial viability.

  5. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, C.A.; Rurbage, C.H.

    1982-03-17T23:59:59.000Z

    The invention is pneumatically operated valve assembly for simulatenously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two on the lines so closed. The value assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  6. Gas Cylinders: Proper Management

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    Compressed Gas Cylinders: Proper Management And Use Published by the Office of Environment, Health;1 Introduction University of California, Berkeley (UC Berkeley) departments that use compressed gas cylinders (MSDS) and your department's Job Safety Analyses (JSAs). Talk to your gas supplier about hands

  7. Static gas expansion cooler

    DOE Patents [OSTI]

    Guzek, J.C.; Lujan, R.A.

    1984-01-01T23:59:59.000Z

    Disclosed is a cooler for television cameras and other temperature sensitive equipment. The cooler uses compressed gas ehich is accelerated to a high velocity by passing it through flow passageways having nozzle portions which expand the gas. This acceleration and expansion causes the gas to undergo a decrease in temperature thereby cooling the cooler body and adjacent temperature sensitive equipment.

  8. Natural Gas Exploration

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    . Exploration and extraction of natural gas from the Marcellus shale is a potentially valuable economic stimulus for landowners. You might be wondering how the nation's economic situation is affecting the market for naturalNatural Gas Exploration: A Landowners Guide to Financial Management Natural Gas Exploration

  9. Sour landfill gas problem solved

    SciTech Connect (OSTI)

    Nagl, G.; Cantrall, R. [Wheelabrator Clean Air Systems, Inc., Schaumburg, IL (United States)

    1996-05-01T23:59:59.000Z

    In Broward County, Fla., near Pompano Beach, Waste Management of North America (WMNA, a subsidiary of WMX Technologies, Oak Brook, IL) operates the Central Sanitary Landfill and Recycling Center, which includes the country`s largest landfill gas-to-energy plant. The landfill consists of three collection sites: one site is closed, one is currently receiving garbage, and one will open in the future. Approximately 9 million standard cubic feet (scf) per day of landfill gas is collected from approximately 300 wells spread over the 250-acre landfill. With a dramatic increase of sulfur-containing waste coming to a South Florida landfill following Hurricane Andrew, odors related to hydrogen sulfide became a serious problem. However, in a matter of weeks, an innovative desulfurization unit helped calm the landfill operator`s fears. These very high H{sub 2}S concentrations caused severe odor problems in the surrounding residential area, corrosion problems in the compressors, and sulfur dioxide (SO{sub 2}) emission problems in the exhaust gas from the turbine generators.

  10. Evaluating impacts of CO2 gas intrusion into a confined sandstone aquifer: Experimental results

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31T23:59:59.000Z

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

  11. Interactive Distributed Ray Tracing of Highly Complex Models

    E-Print Network [OSTI]

    Wald, Ingo

    projects dealing with entire cars, ships, buildings, and processing plants. The complexity of such modelsInteractive Distributed Ray Tracing of Highly Complex Models Ingo Wald, Philipp Slusallek, Carsten- ulation of huge and complex 3D environments. Examples include large structural and mechanical engineering

  12. Trace Elements Greg Mullins, Extension Nutrient Management Specialist, Virginia Tech

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    the plants. Manganese (Mn) Manganese deficiency has been found on soybeans and peanuts grown in VirginiaTrace Elements Greg Mullins, Extension Nutrient Management Specialist, Virginia Tech Steve Heckendorn, Soil Test Laboratory Manager, Virginia Tech Soil Test Note #4 Introduction Your Soil Test Report

  13. Quantifying the Digital Traces of Hurricane Sandy on Flickr

    E-Print Network [OSTI]

    Stanley, H. Eugene

    Quantifying the Digital Traces of Hurricane Sandy on Flickr Tobias Preis1 *, Helen Susannah Moat1 social science. To investigate user attention to the Hurricane Sandy disaster in 2012, we analyze data to Hurricane Sandy bears a striking correlation to the atmospheric pressure in the US state New Jersey during

  14. Traces of Human Migrations in Helicobacter pylori Populations

    E-Print Network [OSTI]

    Wirth, Thierry

    Traces of Human Migrations in Helicobacter pylori Populations Daniel Falush,1 Thierry Wirth,1 Bodo Reichard,1 Elena Katzowitsch,8 Xiaoyan Wang,1 Mark Achtman,1 * Sebastian Suerbaum8 Helicobacter pylori tuberculosis (2), Haemophilus influenzae (3), and Helicobac- ter pylori (4­8). H. pylori, a Gram

  15. From transformation traces to transformation rules: Assisting Model Driven Engineering

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    From transformation traces to transformation rules: Assisting Model Driven Engineering approach. In this paper we are interested in semi-automatically gen- erating labelled graph (model) transformations conform to a particu- lar syntax (meta-model). Those transformations are basic operations in model driven

  16. ANIMAL TRACING: BENEFITS IN CATTLE INDUSTRY AND PRIVATE INCENTIVES

    E-Print Network [OSTI]

    McCarl, Bruce A.

    AND PRIVATE INCENTIVES The economic implications of foreign animal diseases and their mitigation options haveANIMAL TRACING: BENEFITS IN CATTLE INDUSTRY AND PRIVATE INCENTIVES LEVAN ELBAKIDZE Assistant Research Professor Department of Agricultural Economics Texas A&M University College Station, TX, 77843

  17. Execution Trace-Driven Automated Attack Signature Generation Susanta Nanda

    E-Print Network [OSTI]

    Chiueh, Tzi-cker

    Execution Trace-Driven Automated Attack Signature Generation Susanta Nanda Symantec Research Labs In its most general form, an attack signature is a program that can correctly determine if an input network packet se- quence can successfully attack a protected network appli- cation. Filter rules used

  18. A Feasibility Study: Mining Daily Traces for Home Heating Control

    E-Print Network [OSTI]

    Whitehouse, Kamin

    , prediction 1. INTRODUCTION Heating, ventilation and cooling (HVAC) contributes most to a home's energy billsA Feasibility Study: Mining Daily Traces for Home Heating Control Dezhi Hong and Kamin Whitehouse and make predictions of arrival times. Our approach requires the minimum ef- forts for heating controls

  19. Auto-Generation of Communication Benchmark Traces Vivek Deshpande

    E-Print Network [OSTI]

    Mueller, Frank

    Auto-Generation of Communication Benchmark Traces Vivek Deshpande North Carolina State University.edu Frank Mueller North Carolina State University Raleigh, NC, USA mueller@cs.ncsu.edu ABSTRACT Benchmarks creation is a tedious manual process. As a result, benchmarks tend to lag behind the development of complex

  20. RESEARCH ARTICLE Particles for tracing turbulent liquid helium

    E-Print Network [OSTI]

    Lathrop, Daniel P.

    RESEARCH ARTICLE Particles for tracing turbulent liquid helium Gregory P. Bewley Æ K. R of local flow velocities in turbulent liquid helium, using tracer particles. We survey and evaluate, we note that cryogenic helium is attractive for experimental studies because its kinematic viscosity

  1. PALEOZOIC TRACE FOSSILS FROM THE KUFRA BASIN, LIBYA

    E-Print Network [OSTI]

    Benton, Michael

    PALEOZOIC TRACE FOSSILS FROM THE KUFRA BASIN, LIBYA BRIAN R. TURNER AND MICHAEL J. BENTONPaleozoicsuccessionin the southeastern part ofthe Kufra Basin, Libya, comprises a sequence of sedimentary facies up to 250 m thick THEK u m BASINin southeast Libya (Figure 1)occupiesan area of about 400,000km2and is filled

  2. Developing Performance Models from Non-intrusive Monitoring Traces

    E-Print Network [OSTI]

    Murphy, John

    Developing Performance Models from Non- intrusive Monitoring Traces Daniela Mania, John Murphy transactions within the system at run-time using non-intrusive monitoring. Our belief is this methodology obtained by non-intrusive monitoring of an EJB-based e-commerce application. Moreover, the methodology

  3. Parallel Seismic Ray Tracing in a Global Earth Model

    E-Print Network [OSTI]

    Genaud, Stéphane

    1 Parallel Seismic Ray Tracing in a Global Earth Model Marc Grunberg * , Stéphane Genaud of the Earth interior, and seismic tomogra- phy is a means to improve knowledge in this #28;eld. In order present in this paper the de- sign of a software program implement- ing a fast seismic ray

  4. Balancing Privacy and Fidelity in Packet Traces for Security Evaluation

    E-Print Network [OSTI]

    Fahmy, Sonia

    for a certain network. Previous attempts at developing security benchmarks include the 1998 and 1999 evaluation1 Balancing Privacy and Fidelity in Packet Traces for Security Evaluation Sonia Fahmy and Christine.com Abstract Security mechanisms, such as firewalls and intrusion detection systems, protect networks

  5. Gas flows and bars in galaxies

    E-Print Network [OSTI]

    F. Combes

    2006-08-29T23:59:59.000Z

    Dynamical evolution of spiral galaxies is strongly dependent on non-axisymmetric patterns that develop from gravitational instabilities, either spontaneously or externally triggered. Some evolutionary sequences are described through which a galaxy could possibly concentrate mass and build bulges, how external gas accretion from cosmic filaments could be funneled to the galaxy disks, and intermittently driven to the galaxy center, to form nuclear starbursts and fuel an active nucleus. The frequency of both bars and lopsidedness can be used to constrain the gas accretion rate.

  6. Energy 101: Concentrating Solar Power

    ScienceCinema (OSTI)

    None

    2013-05-29T23:59:59.000Z

    From towers to dishes to linear mirrors to troughs, concentrating solar power (CSP) technologies reflect and collect solar heat to generate electricity. A single CSP plant can generate enough power for about 90,000 homes. This video explains what CSP is, how it works, and how systems like parabolic troughs produce renewable power. For more information on the Office of Energy Efficiency and Renewable Energy's CSP research, see the Solar Energy Technology Program's Concentrating Solar Power Web page at http://www1.eere.energy.gov/solar/csp_program.html.

  7. Welcome FUPWG- Natural Gas Overview

    Broader source: Energy.gov [DOE]

    Presentation—given at the Federal Utility Partnership Working Group (FUPWG) Fall 2008 meeting—provides an overview of natural gas, including emissions, compressed natural gas (CNG) vehicles, and landfill gas supplement for natural gas system.

  8. Gas Hydrate Storage of Natural Gas

    SciTech Connect (OSTI)

    Rudy Rogers; John Etheridge

    2006-03-31T23:59:59.000Z

    Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a lower heat transfer rate in the internal heat exchanger than was designed. It is believed that the fins on the heat-exchanger tubes did not make proper contact with the tubes transporting the chilled glycol, and pairs of fins were too close for interior areas of fins to serve as hydrate collection sites. A correction of the fabrication fault in the heat exchanger fin attachments could be easily made to provide faster formation rates. The storage success with the POC process provides valuable information for making the process an economically viable process for safe, aboveground natural-gas storage.

  9. Zevenhoven & Kilpinen TRACE ELEMENTS, ALKALI METALS 19.6.2001 8-1 Chapter 8 Trace elements,

    E-Print Network [OSTI]

    Zevenhoven, Ron

    air pollutants), "known or suspected of causing cancer or other serious health effects" (see also, in part stemming from anthropogenic sources, i.e. pollution. In wastes and waste-derived fuels the "trace to fouling of turbine blades (mainly Ca)or pollute or poison catalysts (mainly As) or sorbents downstream

  10. External combustor for gas turbine engine

    DOE Patents [OSTI]

    Santanam, Chandran B. (Indianapolis, IN); Thomas, William H. (Indianapolis, IN); DeJulio, Emil R. (Columbus, IN)

    1991-01-01T23:59:59.000Z

    An external combustor for a gas turbine engine has a cyclonic combustion chamber into which combustible gas with entrained solids is introduced through an inlet port in a primary spiral swirl. A metal draft sleeve for conducting a hot gas discharge stream from the cyclonic combustion chamber is mounted on a circular end wall of the latter adjacent the combustible gas inlet. The draft sleeve is mounted concentrically in a cylindrical passage and cooperates with the passage in defining an annulus around the draft sleeve which is open to the cyclonic combustion chamber and which is connected to a source of secondary air. Secondary air issues from the annulus into the cyclonic combustion chamber at a velocity of three to five times the velocity of the combustible gas at the inlet port. The secondary air defines a hollow cylindrical extension of the draft sleeve and persists in the cyclonic combustion chamber a distance of about three to five times the diameter of the draft sleeve. The hollow cylindrical extension shields the drive sleeve from the inlet port to prevent discharge of combustible gas through the draft sleeve.

  11. Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

  12. Hydrogen as an Indicator to Assess Biological Activity During Trace-Metal Bioremediation

    SciTech Connect (OSTI)

    Peter R. Jaffe, John Komlos, Derick Brown

    2005-09-27T23:59:59.000Z

    Trace-metal and/or radionuclide bioremediation schemes require that specific redox conditions be achieved at given zones of an aquifer. Tools are therefore needed to identify the terminal electron acceptor processes (TEAPs) that are being achieved during bioremediation in an aquifer. Dissolved hydrogen (H2) concentrations have been shown to correlate with specific TEAPs during bioremediation in an aquifer. Theoretical analysis has shown that these steady-state H2 levels are solely dependent upon the physiological parameters of the hydrogen-consuming microorganisms, with H2 concentrations increasing as each successive TEAP yields less energy for bacterial growth. The objective of this research was to determine if H2 can still be used as an indicator of TEAPs during a uranium bioremediation scheme where an organic substrate is injected into the subsurface and organisms may consume H2 and carbon simultaneously. In addition, the effect of iron bioavailability on H2 concentrations during iron reduction was observed. The first phase of research determined the effect of a competing electron donor (acetate) on the kinetics of H2 utilization by Geobacter sulfurreducens in batch cultures under iron reducing conditions. The results indicate that, though the Monod kinetic coefficients describing the rate of H2 utilization under iron-reducing conditions correlate energetically with the coefficients found in previous experiments under methanogenic and sulfate-reducing conditions, conventionally measured growth kinetics do not predict the steady state H2 levels typical for each TEAP. In addition, with acetate and H2 as simultaneous electron donors, there is slight inhibition between the two electron donors for G. sulfurreducens, and this can be modeled through competitive inhibition terms in the classic Monod formulation, resulting in slightly higher H2 concentrations under steady state conditions in the presence of acetate. This dual-donor model indicates that the steady state H2 concentration in the presence of an organic as electron donor is not only dependent on the biokinetic coefficients of the TEAP, but also the concentration of the organic substrate, and that the H2 concentration does not start to change very dramatically as long as the organic substrate concentration remains below the half saturation constant. The results for this phase of research are provided in Section 1. The second phase of research measured steady-state H2 concentrations under iron reducing conditions using NABIR Field Research Center background soil in a simulated bioremediation scenario involving acetate injection to stimulate indigenous microbial activity in a flow-through column. Steady-state H2 concentrations measured during this long-term (500 day) column experiment were higher than observed for iron-reducing conditions in the field even though evidence suggests that iron reduction was the dominant TEAP in the column. Additional column experiments were performed to determine the effect of iron bioavailability on steady-state H2 concentrations using the humics analogue, AQDS (9,10-anthraquinone-2,6-disulfonic acid). The iron reduction rate in the column with AQDS was double the rate in a parallel column without AQDS and lower steady state H2 levels were observed in the presence of AQDS, indicating that even though iron reduction does occur, a decreased bioavailability of iron may inhibit iron reduction such that H2 concentrations increase to levels that are more typical for less energetically favorable reactions (sulfate-reduction, methanogenigesis). The results for this phase of research are in Section 2. A final phase of research measured the effect of carbon concentration and iron bioavailability on surface bound iron reduction kinetics and steady-state H2 levels using synthetic iron oxide coated sand (IOCS). Results show a significant decrease in the microbial iron reduction and acetate oxidation rates for systems with surface bound Fe(III) (IOCS) compared to soluble Fe(III) (ferric citrate). The addition of AQDS did not affect the rate of iron r

  13. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01T23:59:59.000Z

    gas reservoirs for carbon sequestration and enhanced gasproduction and carbon sequestration, Society of Petroleumfeasibiilty of carbon sequestration with enhanced gas

  14. Matrix Optimization for the MALDI-TOF-MS Analysis of Trace Biodiesel Components (Poster)

    SciTech Connect (OSTI)

    McAlpin, C. R.; Voorhees, K. J.; Alleman, T. L.; McCormick, R. L.

    2009-01-01T23:59:59.000Z

    Trace biodiesel components that could reduce the fuel's operability in cold weather are analyzed using MALDI-TOF mass spectrometry.

  15. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01T23:59:59.000Z

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  16. A Thesis for the Degree of Master Design of Fair Tracing E-cash

    E-Print Network [OSTI]

    Kim, Kwangjo

    A Thesis for the Degree of Master Design of Fair Tracing E-cash System based on Blind Signature Tracing E-cash System based on Blind Signature #12;Design of Fair Tracing E-cash System based on Blind and Communications University A thesis submitted to the faculty of Information and Com- munications University

  17. TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE

    E-Print Network [OSTI]

    Laughlin, Robert B.

    TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE WAVELENGTH Grand Forks, ND 58202-9018 Keywords: scanning electron microscopy, trace metals, coal analysis ABSTRACT Scanningelectron microscopy with wavelength-dispersive spectrometry has been used to measure trace metals in coal

  18. Trace Formula in Noncommutative Geometry and the Zeros of the Riemann Zeta Function

    E-Print Network [OSTI]

    Connes, Alain

    Trace Formula in Noncommutative Geometry and the Zeros of the Riemann Zeta Function Alain CONNES interpretation of the explicit formulas of number theory as a trace formula on the noncommutative space of Adele classes. This reduces the Riemann hypothesis to the validity of the trace formula and eliminates

  19. A RELATIVE TRACE FORMULA FOR A COMPACT RIEMANN KIMBALL MARTIN, MARK MCKEE, AND ERIC WAMBACH

    E-Print Network [OSTI]

    Martin, Kimball

    A RELATIVE TRACE FORMULA FOR A COMPACT RIEMANN SURFACE KIMBALL MARTIN, MARK MCKEE, AND ERIC WAMBACH Abstract. We study a relative trace formula for a compact Riemann surface with respect to a closed geodesic estimates on the lengths of geodesic segments which start and end orthogonally on C. Variant trace formulas

  20. IEEE TRANSACTIONS ON MULTIMEDIA, VOL. 9, NO. 4, JUNE 2007 677 Digital Image Tracing by Sequential

    E-Print Network [OSTI]

    Fontanari, Claudio

    IEEE TRANSACTIONS ON MULTIMEDIA, VOL. 9, NO. 4, JUNE 2007 677 Digital Image Tracing by Sequential many interesting applications such as multimedia document tracing, data usage monitoring, mul- tiple--Asymmetric watermarking, image tracing, linear algebra, multiple watermarking. I. INTRODUCTION SECURITY of multimedia

  1. The effects of shifting modality between study and test: a fuzzy-trace theory analysis

    E-Print Network [OSTI]

    Gerkens, David Preston

    2001-01-01T23:59:59.000Z

    The present research was designed to test properties of the fuzzy-trace theory memory model. Fuzzy-trace theory is a global memory model that posits that multiple memory traces are formed for every experience. According to the theory there are two...

  2. RAY TRACING IN THE SMOOTHED ACOUSTIC SEG/EAGE SALT MODEL.

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    RAY TRACING IN THE SMOOTHED ACOUSTIC SEG/EAGE SALT MODEL. PART 1: SEISMOGRAMS V â?? ACLAV BUCHA­waves in the smoothed acoustic SEG/EAGE Salt Model are computed. The shot­receiver configuration is derived from that the smoothed SEG/EAGE Salt Model is suitable for two­point ray tracing. KEY WORDS Velocity model, ray tracing

  3. Spectrometer for measuring the concentration of components in a fluid stream and method for using same

    DOE Patents [OSTI]

    Durham, Michael D. (Castle Rock, CO); Stedman, Donald H. (Englewood, CO); Ebner, Timothy G. (Westminster, CO); Burkhardt, Mark R. (Englewood, CO)

    1991-01-01T23:59:59.000Z

    A device and method for measuring the concentrations of components of a fluid stream. Preferably, the fluid stream is an in situ gas stream, such as a fossil fuel fired flue gas in a smoke stack. The measurements are determined from the intensity of radiation over a selected range of radiation wavelengths using peak-to-trough calculations. The need for a reference intensity is eliminated.

  4. Spectrometer for measuring the concentration of components in a fluid stream and method for using same

    DOE Patents [OSTI]

    Durham, M.D.; Stedman, D.H.; Ebner, T.G.; Burkhardt, M.R.

    1991-12-03T23:59:59.000Z

    A device and method are described for measuring the concentrations of components of a fluid stream. Preferably, the fluid stream is an in-situ gas stream, such as a fossil fuel fired flue gas in a smoke stack. The measurements are determined from the intensity of radiation over a selected range of radiation wavelengths using peak-to-trough calculations. The need for a reference intensity is eliminated. 15 figures.

  5. Development of concentrator solar cells

    SciTech Connect (OSTI)

    Not Available

    1994-08-01T23:59:59.000Z

    A limited pilot production run on PESC silicon solar cells for use at high concentrations (200 to 400 suns) is summarized. The front contact design of the cells was modified for operation without prismatic covers. The original objective of the contract was to systematically complete a process consolidation phase, in which all the, process improvements developed during the contract would be combined in a pilot production run. This pilot run was going to provide, a basis for estimating cell costs when produced at high throughput. Because of DOE funding limitations, the Photovoltaic Concentrator Initiative is on hold, and Applied Solar`s contract was operated at a low level of effort for most of 1993. The results obtained from the reduced scope pilot run showed the effects of discontinuous process optimization and characterization. However, the run provided valuable insight into the technical areas that can be optimized to achieve the original goals of the contract.

  6. Cylindrical acoustic levitator/concentrator

    DOE Patents [OSTI]

    Kaduchak, Gregory (Los Alamos, NM); Sinha, Dipen N. (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    A low-power, inexpensive acoustic apparatus for levitation and/or concentration of aerosols and small liquid/solid samples having particulates up to several millimeters in diameter in air or other fluids is described. It is constructed from a commercially available, hollow cylindrical piezoelectric crystal which has been modified to tune the resonance frequency of the breathing mode resonance of the crystal to that of the interior cavity of the cylinder. When the resonance frequency of the interior cylindrical cavity is matched to the breathing mode resonance of the cylindrical piezoelectric transducer, the acoustic efficiency for establishing a standing wave pattern in the cavity is high. The cylinder does not require accurate alignment of a resonant cavity. Water droplets having diameters greater than 1 mm have been levitated against the force of gravity using; less than 1 W of input electrical power. Concentration of aerosol particles in air is also demonstrated.

  7. Gas mixing in the wall layer of a CFB boiler

    SciTech Connect (OSTI)

    Sterneus, J.; Johnsson, F. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Energy Conversion

    1997-12-31T23:59:59.000Z

    Tracer-gas measurements were carried out in the transport zone of a 12 MW CFB boiler with special emphasis on the wall-layer flow. Helium (He) was used as tracer gas and a mass spectrometer was used to determine the He-concentrations. The primary gas velocity, U{sub 0}, was 1.2, 2.6 and 4.3 m/s (no secondary air) and the bed material was silica sand with an average particle diameter of 0.32 mm. Tracer gas was injected at different distances from one of the furnace walls and sampled above and below the injection level. In the wall layer, tracer-gas concentrations were detected above (C{sub above}) as well as below (C{sub below}) the injection height for all operating conditions, i.e., the gas flows both up and down from the injection point. The data show that the net flow of tracer gas in the wall layer depends on the operating conditions, and the concentration ratio of the down- and up-flowing gas, {psi} = C{sub below}/C{sub above}, decreases with increased gas velocity ({psi} > 1 for U{sub 0} = 1.2 m/s, {psi} {approx} 1 for U{sub 0} = 2.6 m/s and {psi} < 1 for U{sub 0} = 4.3 m/s). There exists a gas exchange between the core region and the wall-layer. A plug flow model applied to the core region gives a radial dispersion coefficient, D{sub r}, in the range of 0.015--0.025 m{sup 2}/s which is higher than the D{sub r} values reported in literature which are below 0.01 m{sup 2}/x. However, the latter values were obtained in tall and narrow risers.

  8. ARM - Measurement - Particle number concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowband upwelling irradiancenumber concentration ARM Data

  9. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, D.

    1984-06-05T23:59:59.000Z

    An apparatus for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area.

  10. Geochemical, metagenomic and metaproteomic insights into trace metal utilization by methane-oxidizing microbial consortia in sulfidic marine sediments

    SciTech Connect (OSTI)

    Glass, DR. Jennifer [California Institute of Technology, Pasadena; Yu, DR. Hang [California Institute of Technology, Pasadena; Steele, Joshua [California Institute of Technology, Pasadena; Dawson, Katherine [California Institute of Technology, Pasadena; Sun, S [University of California, San Diego; Chourey, Karuna [ORNL; Hettich, Robert {Bob} L [ORNL; Orphan, V [California Institute of Technology, Pasadena

    2014-01-01T23:59:59.000Z

    Microbes have obligate requirements for trace metals in metalloenzymes that catalyze important biogeochemical reactions. In anoxic methane- and sulfide-rich environments, microbes may have unique adaptations for metal acquisition and utilization due to decreased bioavailability as a result of metal sulfide precipitation. However, micronutrient cycling is largely unexplored in cold ( 10 C) and sulfidic (>1 mM H2S) deep-sea methane seep ecosystems. We investigated trace metal geochemistry and microbial metal utilization in methane seeps offshore Oregon and California, USA, and report dissolved concentrations of nickel (0.5-270 nM), cobalt (0.5-6 nM), molybdenum (10-5,600 nM) and tungsten (0.3-8 nM) in Hydrate Ridge sediment porewaters. Despite low levels of cobalt and tungsten, metagenomic and metaproteomic data suggest that microbial consortia catalyzing anaerobic oxidation of methane utilize both scarce micronutrients in addition to nickel and molybdenum. Genetic machinery for cobalt-containing vitamin B12 biosynthesis was present in both anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB). Proteins affiliated with the tungsten-containing form of formylmethanofuran dehydrogenase were expressed in ANME from two seep ecosystems, the first evidence for expression of a tungstoenzyme in psychrotolerant microorganisms. Finally, our data suggest that chemical speciation of metals in highly sulfidic porewaters may exert a stronger influence on microbial bioavailability than total concentration

  11. Experiential Component Approval Form Concentration in Nanotechnology

    E-Print Network [OSTI]

    Goldberg, Bennett

    Experiential Component Approval Form Concentration in Nanotechnology Return completed form to ENG Plan to complete the experiential component as a requirement for the concentration in Nanotechnology to complete the experiential component for the Nanotechnology Concentration by: Research Experience in Lab

  12. Hydrogen as an Indicator to Assess Biological Activity During Trace-Metal Bioremediation

    SciTech Connect (OSTI)

    Jaffe, Peter R.; Lovley, Derek; Komlos, John; Brown, Derick

    2004-03-17T23:59:59.000Z

    The design and operation of a trace-metal or radionuclide bioremediation scheme requires that specific redox conditions be achieved at given zones of an aquifer for a pre-determined duration. Tools are therefore needed to identify and quantify the terminal electron accepting processes (TEAPs) that are being achieved during bioremediation in an aquifer, and that this be done at a high spatial resolution. Dissolved hydrogen (H{sub 2}) concentrations have been shown to correlate with specific TEAPs during bioremediation in an aquifer (Table 1). Theoretical analysis has shown that these steady-state hydrogen levels are solely dependent upon the physiological parameters of the hydrogen-consuming microorganisms, with hydrogen concentrations increasing as each successive TEAP yields less energy for bacterial growth. The assumptions for this statement may not hold during a bioremediation scheme in which an organic substrate is injected into the subsurface and where organisms may consume hydrogen and carbon simultaneously. This research examines the effects of simultaneous hydrogen and carbon utilization through obtaining kinetic parameters of both hydrogen and carbon consumption under iron reducing conditions in batch experiments. A dual-donor model was formulated and compared to flow-through column experiments.

  13. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, Charles A. (Oak Ridge, TN); Burbage, Charles H. (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    The invention is a pneumatically operated valve assembly for simultaneously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two of the lines so closed. The valve assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  14. Thermodynamics of Chaplygin gas

    E-Print Network [OSTI]

    Yun Soo Myung

    2011-05-11T23:59:59.000Z

    We clarify thermodynamics of the Chaplygin gas by introducing the integrability condition. All thermal quantities are derived as functions of either volume or temperature. Importantly, we find a new general equation of state, describing the Chaplygin gas completely. We confirm that the Chaplygin gas could show a unified picture of dark matter and energy which cools down through the universe expansion without any critical point (phase transition).

  15. Ray tracing a three dimensional scene using a grid

    SciTech Connect (OSTI)

    Wald, Ingo; Ize, Santiago; Parker, Steven G; Knoll, Aaron

    2013-02-26T23:59:59.000Z

    Ray tracing a three-dimensional scene using a grid. One example embodiment is a method for ray tracing a three-dimensional scene using a grid. In this example method, the three-dimensional scene is made up of objects that are spatially partitioned into a plurality of cells that make up the grid. The method includes a first act of computing a bounding frustum of a packet of rays, and a second act of traversing the grid slice by slice along a major traversal axis. Each slice traversal includes a first act of determining one or more cells in the slice that are overlapped by the frustum and a second act of testing the rays in the packet for intersection with any objects at least partially bounded by the one or more cells overlapped by the frustum.

  16. Molecular gas and the dynamics of galaxies

    E-Print Network [OSTI]

    F. Combes

    1999-02-01T23:59:59.000Z

    In this review, I discuss some highlights of recent research on molecular gas in galaxies; large-scale CO maps of nearby galaxies are being made, which extend our knowledge on global properties, radial gradients, and spiral structure of the molecular ISM. Very high resolution are provided by the interferometers, that reveal high velocity gradients in galaxy nuclei, and formation of embedded structures, like bars within bars. Observation of the CO and other lines in starburst galaxies have questioned the H2-to-CO conversion factor. Surveys of dwarfs have shown how the conversion factor depends on metallicity. The molecular content is not deficient in galaxy clusters, as is the atomic gas. Galaxy interactions are very effective to enhance gas concentrations and trigger starbursts. Nuclear disks or rings are frequently observed, that concentrate the star formation activity. Since the density of starbursting galaxies is strongly increasing with redshift, the CO lines are a privileged tool to follow evolution of galaxies and observe the ISM dynamics at high redshift: due to the high excitation of the molecular gas, the stronger high-$J$ CO lines are redshifted into the observable band, which facilitates the detection.

  17. Lyapunov exponents for 2D ray tracing without interfaces

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    Lyapunov exponents for 2­D ray tracing without interfaces LudŸek KlimeŸs Department of Geophysics@seis.karlov.mff.cuni.cz Summary The Lyapunov exponents asymptotically quantify the exponential divergence of rays. The ``Lyapunov exponent'' for a finite 2­D ray and the average ``Lyapunov exponents'' for a set of finite 2­D rays

  18. Home Safety: Radon Gas 

    E-Print Network [OSTI]

    Shaw, Bryan W.; Denny, Monica L.

    1999-11-12T23:59:59.000Z

    Every home should be tested for radon, an invisible, odorless, radioactive gas that occurs naturally. This publication explains the health risks, testing methods, and mitigation and reduction techniques....

  19. String Gas Baryogenesis

    E-Print Network [OSTI]

    G. L. Alberghi

    2010-02-19T23:59:59.000Z

    We describe a possible realization of the spontaneous baryogenesis mechanism in the context of extra-dimensional string cosmology and specifically in the string gas scenario.

  20. Natural gas annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-10-01T23:59:59.000Z

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1997 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1993 to 1997 for each Census Division and each State. Annual historical data are shown at the national level. 27 figs., 109 tabs.

  1. Home Safety: Radon Gas

    E-Print Network [OSTI]

    Shaw, Bryan W.; Denny, Monica L.

    1999-11-12T23:59:59.000Z

    Every home should be tested for radon, an invisible, odorless, radioactive gas that occurs naturally. This publication explains the health risks, testing methods, and mitigation and reduction techniques....

  2. Liquefied Natural Gas (Iowa)

    Broader source: Energy.gov [DOE]

    This document adopts the standards promulgated by the National Fire Protection Association as rules for the transportation, storage, handling, and use of liquefied natural gas. The NFPA standards...

  3. Oil and Gas Outlook

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas Outlook For Independent Petroleum Association of America November 13, 2014 | Palm Beach, FL By Adam Sieminski, Administrator U.S. Energy Information Administration Recent...

  4. Oil and Gas (Indiana)

    Broader source: Energy.gov [DOE]

    This division of the Indiana Department of Natural Resources provides information on the regulation of oil and gas exploration, wells and well spacings, drilling, plugging and abandonment, and...

  5. NETL: Oil & Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that address the unique nature and challenging locations of many of our remaining oil and natural gas accumulations. The National Energy Technology Laboratory's (NETL)...

  6. Reversible Acid Gas Capture

    ScienceCinema (OSTI)

    Dave Heldebrant

    2012-12-31T23:59:59.000Z

    Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

  7. Natural Gas Rules (Louisiana)

    Broader source: Energy.gov [DOE]

    The Louisiana Department of Natural Resources administers the rules that govern natural gas exploration and extraction in the state. DNR works with the Louisiana Department of Environmental...

  8. Gas venting system

    DOE Patents [OSTI]

    Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

    2010-06-29T23:59:59.000Z

    A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

  9. Automated micro-tracking planar solar concentrators

    E-Print Network [OSTI]

    Hallas, Justin Matthew

    2011-01-01T23:59:59.000Z

    System from Concentrix Solar," in Concentrator Photovoltaics,CPV systems that use arrays of optics and photovoltaics,system so that arrays of paired concentrators and photovoltaics

  10. Energy Secretary Moniz Dedicates World's Largest Concentrating...

    Office of Environmental Management (EM)

    Dedicates World's Largest Concentrating Solar Power Project Energy Secretary Moniz Dedicates World's Largest Concentrating Solar Power Project February 13, 2014 - 5:00am Addthis...

  11. Automated micro-tracking planar solar concentrators

    E-Print Network [OSTI]

    Hallas, Justin Matthew

    2011-01-01T23:59:59.000Z

    Solar," in Concentrator Photovoltaics, A.L. Luque, and V.M.in concentrating photovoltaics using laterally movingUsing optics to boost photovoltaics,” Optics and Photonics

  12. Concentrating Solar Power Resources and Technologies | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concentrating Solar Power Resources and Technologies Concentrating Solar Power Resources and Technologies Photo of a CSP dish glistening in the sun. Multiple solar mirrors reflect...

  13. Sandia National Laboratories: Concentrating Solar Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concentrating Solar Power National Solar Thermal Testing Facility Beam Profiling On November 2, 2012, in Concentrating Solar Power, News, Renewable Energy, Solar On Thursday, June...

  14. Sandia National Laboratories: multiscale concentrated solar power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concentrated solar power Solar Energy Research Institute for India and the United States Kick-Off On November 27, 2012, in Concentrating Solar Power, Energy, National Solar Thermal...

  15. Sandia National Laboratories: Concentrating Solar Power Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concentrating Solar Power Systems Air Force Research Laboratory Testing On November 2, 2012, in Concentrating Solar Power, Facilities, National Solar Thermal Test Facility, News,...

  16. Sandia National Laboratories: Concentrating Solar Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concentrating Solar Power Sandia Wins Funding for High-Temperature Falling-Particle Solar-Energy Receiver On August 8, 2012, in Concentrating Solar Power, Energy, Facilities,...

  17. Control of Trace Metal Emissions During Coal Combustion

    SciTech Connect (OSTI)

    Thomas C. Ho

    1996-10-01T23:59:59.000Z

    Emissions of toxic trace metals in the form of metal fumes or submicron particulate from a coal-fired combustion source have received greater environmental and regulatory concern over the past years. Current practice of controlling these emissions is to collect them at the cold-end of the process by air-pollution control devices (APCDS) such as electrostatic precipitators and baghouses. However, trace metal fumes may not always be effectively collected by these devices because the formed fumes are extremely small. The proposed research is to explore the opportunities for improved control of toxic trace metal emissions, alternatively, at the hot-end of the coal combustion process, i.e., in the combustion chamber. The technology proposed is to prevent the metal fumes from forming during the process, which would effectively eliminate the metal emission problems. Specifically, the technology is to employ suitable sorbents to (1) reduce the amount of metal volatilization during combustion and (2) capture volatilized metal vapors. The objectives of the project are to demonstrate the technology and to characterize the metal capture process during coal combustion in a fluidized bed combustor.

  18. 47 Natural Gas Market Trends NATURAL GAS MARKET TRENDS

    E-Print Network [OSTI]

    47 Natural Gas Market Trends Chapter 5 NATURAL GAS MARKET TRENDS INTRODUCTION Natural gas discusses current natural gas market conditions in California and the rest of North America, followed on the outlook for demand, supply, and price of natural gas for the forecasted 20-year horizon. It also addresses

  19. Trace-element geochemistry of gradient hole cuttings: Beowawe geothermal area, Nevada

    SciTech Connect (OSTI)

    Christensen, O.D.

    1980-12-01T23:59:59.000Z

    Multielement geochemical analysis of drill cuttings from 26 shallow temperature-gradient drill holes and of surface rock samples reveals trace element distributions developed within these rocks as a consequence of chemical interaction with thermal fluid within the Beowawe geothermal area. The presently discharging thermal fluids are dilute in all components except silica, suggesting that the residence time of these fluids within the thermal reservoir has been short and that chemical interaction with the reservoir rock minimal. Interaction between these dilute fluids and rocks within the system has resulted in the development of weak chemical signatures. The absence of stronger signatures in rocks associated with the present system suggests that fluids have had a similar dilute chemistry for some time. The spatial distribution of elements commonly associated with geothermal systems, such as As, Hg and Li, and neither laterally nor vertically continuous. This suggests that there is not now, nor has there been in the past, pervasive movement of thermal fluid throughout the sampled rock but, instead, that isolated chemical anomalies represent distinct fluid-flow chanels. Discontinuous As, Li and Hg concentrations near White Canyon to the east of the presently active surface features record the effects of chemical interaction of rocks with fluids chemically unlike the presently discharging fluids. The observed trace element distributions suggest that historically the Beowawe area has been the center of more than one hydrothermal event and that the near-surface portion of the present hot-water geothermal system is controlled by a single source fracture, the Malpais Fault, or an intersection of faults at the sinter terrace.

  20. Optically pumped alkali laser and amplifier using helium-3 buffer gas

    DOE Patents [OSTI]

    Beach, Raymond J. (Livermore, CA); Page, Ralph (Castro Valley, CA); Soules, Thomas (Livermore, CA); Stappaerts, Eddy (San Ramon, CA); Wu, Sheldon Shao Quan (Livermore, CA)

    2010-09-28T23:59:59.000Z

    In one embodiment, a laser oscillator is provided comprising an optical cavity, the optical cavity including a gain medium including an alkali vapor and a buffer gas, the buffer gas including .sup.3He gas, wherein if .sup.4He gas is also present in the buffer gas, the ratio of the concentration of the .sup.3He gas to the .sup.4He gas is greater than 1.37.times.10.sup.-6. Additionally, an optical excitation source is provided. Furthermore, the laser oscillator is capable of outputting radiation at a first frequency. In another embodiment, an apparatus is provided comprising a gain medium including an alkali vapor and a buffer gas including .sup.3He gas, wherein if .sup.4He gas is also present in the buffer gas, the ratio of the concentration of the .sup.3He gas to the .sup.4He gas is greater than 1.37.times.10.sup.-6. Other embodiments are also disclosed.

  1. Photoinduced nucleation: a novel tool for detecting molecules in air at ultra-low concentrations

    DOE Patents [OSTI]

    Katz, Joseph L. (Baltimore, MD); Lihavainen, Heikki (Masala, FI); Rudek, Markus M. (Bruchkoebel, DE); Salter, Brian C. (New Market, MD)

    2002-01-01T23:59:59.000Z

    A method and apparatus for determining the presence of molecules in a gas at concentrations of less than about 100 ppb. Light having wavelengths in the range from about 200 nm to about 350 nm is used to illuminate a flowing sample of the gas causing the molecules if present to form clusters. A mixture of the illuminated gas and a vapor is cooled until the vapor is supersaturated so that there is a small rate of homogeneous nucleation. The supersaturated vapor condenses on the clusters thus causing the clusters to grow to a size sufficient to be counted by light scattering and then the clusters are counted.

  2. Shale gas is natural gas trapped inside

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretary of EnergyFocus Group HSS/UnionGlossary Shale GasShale gas

  3. Bulk Viscosity of a Gas of Massless Pions

    E-Print Network [OSTI]

    Jiunn-Wei Chen; Juven Wang

    2009-03-31T23:59:59.000Z

    In the hadronic phase, the dominant configuration of QCD with two flavors of massless quarks is a gas of massless pions. We calculate the bulk viscosity (zeta) using the Boltzmann equation with the kinetic theory generalized to incorporate the trace anomaly. We find that the dimensionless ratio zeta/s, s being the entropy density, is monotonic increasing below T=120 MeV, where chiral perturbation theory is applicable. This, combined with previous results, shows that zeta/s reaches its maximum near the phase transition temperature Tc, while eta/s, eta being the shear viscosity, reaches its minimum near Tc in QCD with massless quarks.

  4. Minimization of steam requirements and enhancement of water-gas shift reaction with warm gas temperature CO2 removal

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Fisher, II, James C

    2013-12-31T23:59:59.000Z

    The disclosure utilizes a hydroxide sorbent for humidification and CO.sub.2 removal from a gaseous stream comprised of CO and CO.sub.2 prior to entry into a water-gas-shift reactor, in order to decrease CO.sub.2 concentration and increase H.sub.2O concentration and shift the water-gas shift reaction toward the forward reaction products CO.sub.2 and H.sub.2. The hydroxide sorbent may be utilized for absorbtion of CO.sub.2 exiting the water-gas shift reactor, producing an enriched H.sub.2 stream. The disclosure further provides for regeneration of the hydroxide sorbent at temperature approximating water-gas shift conditions, and for utilizing H.sub.2O product liberated as a result of the CO.sub.2 absorption.

  5. Concentrator Optics | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovationinConcentrating Solar Power Basics (The following text

  6. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01T23:59:59.000Z

    of Gas Price ($/Mscf) for Offshore Gas Hydrate StudyEvaluation of deepwater gas-hydrate systems. The Leadingfor Gas Production from Gas Hydrates Reservoirs. J. Canadian

  7. The Physics Analysis of a Gas Attenuator with Argon as a Working Gas

    SciTech Connect (OSTI)

    Ryutov,, D.D.

    2010-12-07T23:59:59.000Z

    A gas attenuator is an important element of the LCLS facility. The attenuator must operate in a broad range of x-ray energies, provide attenuation coefficient between 1 and 10{sup 4} with the accuracy of 1% and, at the same time, be reliable and allow for many months of un-interrupted operation. S. Shen has recently carried out a detailed design study of the attenuator based on the use of nitrogen as a working gas. In this note we assess the features of the attenuator based on the use of argon. We concentrate on the physics issues, not the design features.

  8. Nox control for high nitric oxide concentration flows through combustion-driven reduction

    DOE Patents [OSTI]

    Yeh, James T. (Bethel Park, PA); Ekmann, James M. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA); Drummond, Charles J. (Churchill, PA)

    1989-01-01T23:59:59.000Z

    An improved method for removing nitrogen oxides from concentrated waste gas streams, in which nitrogen oxides are ignited with a carbonaceous material in the presence of substoichiometric quantities of a primary oxidant, such as air. Additionally, reductants may be ignited along with the nitrogen oxides, carbonaceous material and primary oxidant to achieve greater reduction of nitrogen oxides. A scrubber and regeneration system may also be included to generate a concentrated stream of nitrogen oxides from flue gases for reduction using this method.

  9. Oil and Gas Exploration

    E-Print Network [OSTI]

    Tingley, Joseph V.

    , oil and gas, and geothermal activities and accomplishments in Nevada: production statistics Products 23. Sloan dolomite quarry 24. Weiser gypsum quarry Oil Fields 1. Blackburn field 2. North WillowMetals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada

  10. Illinois Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Withdrawals NA NA NA NA NA NA 1991-2014 From Gas Wells NA NA NA NA NA NA 1991-2014 From Oil Wells NA NA NA NA NA NA 1991-2014 From Shale Gas Wells NA NA NA NA NA NA 2007-2014...

  11. Montana Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Withdrawals NA NA NA NA NA NA 1991-2014 From Gas Wells NA NA NA NA NA NA 1991-2014 From Oil Wells NA NA NA NA NA NA 1991-2014 From Shale Gas Wells NA NA NA NA NA NA 2007-2014...

  12. Gas Kick Mechanistic Model

    E-Print Network [OSTI]

    Zubairy, Raheel

    2014-04-18T23:59:59.000Z

    -gain and temperature profile in the annulus. This research focuses on these changes in these parameters to be able to detect the occurrence of gas kick and the circulation of the gas kick out from the well. In this thesis, we have developed a model that incorporates...

  13. Fission gas detection system

    DOE Patents [OSTI]

    Colburn, Richard P. (Pasco, WA)

    1985-01-01T23:59:59.000Z

    A device for collecting fission gas released by a failed fuel rod which device uses a filter to pass coolant but which filter blocks fission gas bubbles which cannot pass through the filter due to the surface tension of the bubble.

  14. Western Europe's future gas supplies

    SciTech Connect (OSTI)

    Kardaun, G.

    1983-05-01T23:59:59.000Z

    Decline in indigenous natural gas production by 2000 will be compensated by imported natural gas and LNG and gas from unconventional sources. Coal gas will furnish about 10 percent of the demand, more natural gas imports will come from North Africa and the USSR and additional LNG will come from West Africa, the Middle East and the Western Hemisphere.

  15. Gas pump with movable gas pumping panels

    DOE Patents [OSTI]

    Osher, John E. (Alamo, CA)

    1984-01-01T23:59:59.000Z

    Apparatus for pumping gas continuously a plurality of articulated panels of getter material, each of which absorbs gases on one side while another of its sides is simultaneously reactivated in a zone isolated by the panels themselves from a working space being pumped.

  16. Shale gas production: potential versus actual greenhouse gas emissions

    E-Print Network [OSTI]

    O’Sullivan, Francis Martin

    Estimates of greenhouse gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level of GHG emissions from shale gas well hydraulic fracturing operations in the United States during ...

  17. Intermountain Gas Company (IGC)- Gas Heating Rebate Program

    Broader source: Energy.gov [DOE]

    The Intermountain Gas Company's (IGC) Gas Heating Rebate Program offers customers a $200 per unit rebate when they convert to a high efficiency natural gas furnace that replaces a heating system...

  18. Peoples Gas and North Shore Gas- Bonus Rebate Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Peoples Gas and North Shore Gas Natural Gas Savings Programs are offering the following bonus rebates (in addition to the joint utilities bonus rebate). For both offers below, installation must...

  19. Underground Storage of Natural Gas and Liquefied Petroleum Gas (Nebraska)

    Broader source: Energy.gov [DOE]

    This statute declares underground storage of natural gas and liquefied petroleum gas to be in the public interest if it promotes the conservation of natural gas and permits the accumulation of...

  20. EIA - Natural Gas Pipeline Network - Natural Gas Supply Basins...

    U.S. Energy Information Administration (EIA) Indexed Site

    Corridors About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates U.S. Natural Gas Supply Basins Relative to Major Natural...

  1. Supersonic gas compressor

    DOE Patents [OSTI]

    Lawlor, Shawn P. (Bellevue, WA); Novaresi, Mark A. (San Diego, CA); Cornelius, Charles C. (Kirkland, WA)

    2007-11-13T23:59:59.000Z

    A gas compressor based on the use of a driven rotor having a compression ramp traveling at a local supersonic inlet velocity (based on the combination of inlet gas velocity and tangential speed of the ramp) which compresses inlet gas against a stationary sidewall. In using this method to compress inlet gas, the supersonic compressor efficiently achieves high compression ratios while utilizing a compact, stabilized gasdynamic flow path. Operated at supersonic speeds, the inlet stabilizes an oblique/normal shock system in the gasdyanamic flow path formed between the rim of the rotor, the strakes, and a stationary external housing. Part load efficiency is enhanced by the use of a pre-swirl compressor, and using a bypass stream to bleed a portion of the intermediate pressure gas after passing through the pre-swirl compressor back to the inlet of the pre-swirl compressor. Inlet guide vanes to the compression ramp enhance overall efficiency.

  2. Cryogenic treatment of gas

    DOE Patents [OSTI]

    Bravo, Jose Luis (Houston, TX); Harvey, III, Albert Destrehan (Kingwood, TX); Vinegar, Harold J. (Bellaire, TX)

    2012-04-03T23:59:59.000Z

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  3. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P. (University of Hartford, West Hartford, CT); Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01T23:59:59.000Z

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of “staining” upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.

  4. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Liukang, Xu; Dayle, McDermitt; Tyler, Anderson; Brad, Riensche; Anatoly, Komissarov; Julie, Howe

    2012-05-01T23:59:59.000Z

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been utilized to randomize the noise introduced from potential etalons. It is expected that all original specifications contained within the initial proposal will be met. We are currently in the beginning stages of assembling the first generation prototypes and finalizing the remaining design elements. The first prototypes will initially be tested in our environmental calibration chamber in which specific gas concentrations, temperature and humidity levels can be controlled. Once operation in this controlled setting is verified, the prototypes will be deployed at LI-COR�¢����s Experimental Research Station (LERS). Deployment at the LERS site will test the instrument�¢����s robustness in a real-world situation.

  5. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27T23:59:59.000Z

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  6. Trace Metal Bioremediation: Assessment of Model Components from Laboratory and Field Studies to Identify Critical Variables

    SciTech Connect (OSTI)

    Peter Jaffe; Herschel Rabitz

    2003-02-14T23:59:59.000Z

    The objective of this project was to gain an insight into the modeling support needed for the understanding, design, and operation of trace metal/radionuclide bioremediation. To achieve this objective, a workshop was convened to discuss the elements such a model should contain. A ''protomodel'' was developed, based on the recommendations of the workshop, and was used to perform sensitivity analysis as well as some preliminary simulations in support for bioremediation test experiments at UMTRA sites. To simulate the numerous biogeochemical processes that will occur during the bioremediation of uranium contaminated aquifers, a time-dependent one-dimensional reactive transport model has been developed. The model consists of a set of coupled, steady state mass balance equations, accounting for advection, diffusion, dispersion, and a kinetic formulation of the transformations affecting an organic substrate, electron acceptors, corresponding reduced species, and uranium. This set of equations is solved numerically, using a finite element scheme. The redox conditions of the domain are characterized by estimating the pE, based on the concentrations of the dominant terminal electron acceptor and its corresponding reduced specie. This pE and the concentrations of relevant species are passed to a modified version of MINTEQA2, which calculates the speciation and solubilities of the species of interest. Kinetics of abiotic reactions are described as being proportional to the difference between the actual and equilibrium concentration. A global uncertainty assessment, determined by Random Sampling High Dimensional Model Representation (RS-HDMR), was performed to attain a phenomenological understanding of the origins of output variability and to suggest input parameter refinements as well as to provide guidance for field experiments to improve the quality of the model predictions. Results indicated that for the usually high nitrate contents found ate many DOE sites, overall bioremediation of trace metals was highly sensitive to the formulation of the denitrification process. Simulations were performed to illustrate the effect of biostimulation on the transport and precipitation of uranium in the subsurface, at conditions equivalent to UMTRA sites. These simulations predicted that uranium would precipitate in bands that are located relatively close to the acetate injection well. The simulations also showed the importance of properly determining U(IV) oxidative dissolution rates, in order to assess the stability of precipitates once oxygenated water reenters the aquifer after bioremediation is discontinued. The objective of this project was to provide guidance to NABIR's Systems Integration Element, on the development of models to simulate the bioremediation of trace metals and radionuclides. Such models necessarily need to integrate hydrological, geochemical, and microbiological processes. In order to gain a better understanding of the key processes that such a model should contain, it was deemed desirable to convene a workshop with experts from these different fields. The goal was to obtain a preliminary consensus on the required level of detail for the formulations of these different chemical, physical, and microbiological processes. The workshop was held on December 18, 1998.

  7. FLAMMABLE GAS DIFFUSION THROUGH SINGLE SHELL TANK (SST) DOMES

    SciTech Connect (OSTI)

    MEACHAM, J.E.

    2003-11-10T23:59:59.000Z

    This report quantified potential hydrogen diffusion through Hanford Site Single-Shell tank (SST) domes if the SSTs were hypothetically sealed airtight. Results showed that diffusion would keep headspace flammable gas concentrations below the lower flammability limit in the 241-AX and 241-SX SST. The purpose of this document is to quantify the amount of hydrogen that could diffuse through the domes of the SSTs if they were hypothetically sealed airtight. Diffusion is assumed to be the only mechanism available to reduce flammable gas concentrations. The scope of this report is limited to the 149 SSTs.

  8. Evolution of gas processing industry in Saudi Arabia

    SciTech Connect (OSTI)

    Showail, A.

    1983-01-01T23:59:59.000Z

    The beginning of the natural gas processing industry in Saudi Arabia is traced back to 1959 when Aramco embarked on a program to recover natural gas liquids (NGL) for export from low pressure gases such as stabilizer overhead, spheroid, tank farm, and refinery off-gases. The processing scheme involves compression and refrigeration to extract C3+ raw NGL, a raw NGL gathering system, and a fractionation plant to separate propane, butane, and natural gasoline. NGL extracted in Abqaiq and Ras Tanura is moved to Ras Tanura for fractionation, storage, and export. The system, built in several increments, has total design capacity of 500 MMscfd of feed gases to produce 320,000 bpd of NGL composed of 40% propane, 30% butane, and 30% natural gasoline. Phase II of the Saudi gas program envisages collection and processing of associated gas produced with Arabian medium and heavy crude oils largely in the northern onshore and offshore fields. Further domestic development may focus on more diversification in gas product utilization and on upgrading to higher value products.

  9. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel Morrison

    2005-09-14T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1, 2005 through June 30, 2005. During this time period efforts were directed toward (1) GSTC administration changes, (2) participating in the American Gas Association Operations Conference and Biennial Exhibition, (3) issuing a Request for Proposals (RFP) for proposal solicitation for funding, and (4) organizing the proposal selection meeting.

  10. Solvent refined coal (SRC) process: trace elements research and development report no. 53, interim report no. 34. Volume III. Pilot plant development work part 6: the fate of trace elements in the SRC process for the period, August 1, 1977 - February 28, 1979. [36 elements

    SciTech Connect (OSTI)

    Filby, R.H.; Khalil, S.R.; Grimm, C.A.; Ekabaram, V.; Hunt, M.L.

    1980-12-01T23:59:59.000Z

    This work reports the results of neutron activation analysis determination of the fate of trace elements in the SRC II process. Six coals were studied for their behavior in material balance runs carried out at the Fort Lewis Pilot Plant. The distribution of trace elements among products and input streams was determined by thermal neutron activation analysis using thermal neutron flux of 8 x 10/sup 12/ neutrons cm/sup -2/ sec/sup -1/ followed by Ge(Li) gamma ray spectroscopy. National Bureau of Standards Standard Reference Materials (SRM) were used to evaluate the analytical precision and accuracy of the methods used. For each material balance study the trace element input stream was taken as ground coal and the output streams were vacuum bottoms, SRC II product oil, and process water. In addition to these major components, oils, sludges and waters from liquid-liquid separators, effluent waters, biosludges, and by-product sulfur were also analyzed. Concerning the distribution of trace elements in the SRC II process, it was found that the vacuum bottoms was the major sink for all trace element studied, with the exception of Hg. Much lower trace element concentrations (except for Hg) were found in the SRC II product oil relative to the vacuum bottoms or the feed coal, irrespective of coal type. The results indicate excellent balances for the elements studied, except for Hg. Except for Hg, Se, and C1, the SRC II product and process waters contributed less than 1% of the elemental balances for light oil fractions and process waters indicates that Hg, and to a lesser degree As, Se, and Sb, exhibited volatile behavior in the SRC II process but that the degree of volatility is strongly dependent on conditions or coal type.

  11. Exploring Light's Interactions with Bubbles and Light Absorbers in Photoelectrochemical Devices using Ray Tracing

    SciTech Connect (OSTI)

    Stevens, John

    2013-12-31T23:59:59.000Z

    Ray tracing was used to perform optical optimization of arrays of photovoltaic microrods and explore the interaction between light and bubbles of oxygen gas on the surface of the microrods. The incident angle of light was varied over a wide range. The percent of incident light absorbed by the microrods and reflected by the bubbles was computed over this range. It was found that, for the 10 ?m diameter, 100 ?m tall SrTiO{sub 3} microrods simulated in the model, the optimal center-­?to-­?center spacing was 14 ?m for a square grid. This geometry produced 75% average and 90% maximum absorbance. For a triangular grid using the same microrods, the optimal center-­?to-­?center spacing was 14 ?m. This geometry produced 67% average and 85% maximum absorbance. For a randomly laid out grid of 5 ?m diameter, 100 ?m tall SrTiO! microrods with an average center-­?to-­?center spacing of 20 ?m, the average absorption was 23% and the maximum absorption was 43%. For a 50% areal coverage fraction of bubbles on the absorber surface, between 2%-­?20% of the incident light energy was reflected away from the rods by the bubbles, depending upon incident angle and bubble morphology.

  12. Assessment of gas flammability in transuranic waste container

    SciTech Connect (OSTI)

    Connolly, M.J. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States); Loehr, C.A.; Djordjevic, S.M.; Spangler, L.R. [Benchmark Environmental Corp., Albuquerque, NM (United States)

    1995-12-01T23:59:59.000Z

    The Safety Analysis Report for the TRUPACT-II Shipping Package [Transuranic Package Transporter-II (TRUPACT-II) SARP] set limits for gas generation rates, wattage limits, and flammable volatile organic compound (VOC) concentrations in transuranic (TRU) waste containers that would be shipped to the Waste Isolation Pilot Plant (WIPP). Based on existing headspace gas data for drums stored at the Idaho National Engineering Laboratory (INEL) and the Rocky Flats Environmental Technology Site (RFETS), over 30 percent of the contact-handled TRU waste drums contain flammable VOC concentrations greater than the limit. Additional requirements may be imposed for emplacement of waste in the WIPP facility. The conditional no-migration determination (NMD) for the test phase of the facility required that flame tests be performed if significant levels of flammable VOCs were present in TRU waste containers. This paper describes an approach for investigating the potential flammability of TRU waste drums, which would increase the allowable concentrations of flammable VOCS. A flammability assessment methodology is presented that will allow more drums to be shipped to WIPP without treatment or repackaging and reduce the need for flame testing on drums. The approach includes experimental work to determine mixture lower explosive limits (MLEL) for the types of gas mixtures observed in TRU waste, a model for predicting the MLEL for mixtures of VOCS, hydrogen, and methane, and revised screening limits for total flammable VOCs concentrations and concentrations of hydrogen and methane using existing drum headspace gas data and the model predictions.

  13. Questar Gas- Home Builder Gas Appliance Rebate Program

    Broader source: Energy.gov [DOE]

    Questar Gas provides incentives for home builders to construct energy efficient homes. Rebates are provided for both energy efficient gas equipment and whole home Energy Star certification. All...

  14. Questar Gas- Home Builder Gas Appliance Rebate Program

    Broader source: Energy.gov [DOE]

    Questar Gas provides incentives for home builders to construct energy efficient homes. Rebates are provided for energy efficient gas equipment. Builders can also receive whole house rebates for...

  15. Questar Gas- Home Builder Gas Appliance Rebate Program (Idaho)

    Broader source: Energy.gov [DOE]

    Questar Gas provides incentives for home builders who incorporate energy efficiency into new construction. Rebates are provided for energy efficient gas equipment placed into new construction....

  16. Questar Gas- Home Builder Gas Appliance Rebate Program

    Broader source: Energy.gov [DOE]

    Questar Gas provides incentives for home builders who incorporate energy efficiency into new construction. Rebates are provided for energy efficient gas equipment placed into new construction. ...

  17. ,"New York Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,"(202) 586-8800",,,"2262015 9:43:21 AM" "Back to Contents","Data 1: New York Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)"...

  18. natural gas+ condensing flue gas heat recovery+ water creation...

    Open Energy Info (EERE)

    natural gas+ condensing flue gas heat recovery+ water creation+ CO2 reduction+ cool exhaust gases+ Energy efficiency+ commercial building energy efficiency+ industrial energy...

  19. EIA - Natural Gas Pipeline Network - Largest Natural Gas Pipeline...

    U.S. Energy Information Administration (EIA) Indexed Site

    Interstate Pipelines Table About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Thirty Largest U.S. Interstate Natural...

  20. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2010-05-01T23:59:59.000Z

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  1. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    O. A. Marina; L. R. Pederson; R. Gemmen; K. Gerdes; H. Finklea; I. B. Celik

    2010-03-01T23:59:59.000Z

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  2. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31T23:59:59.000Z

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

  3. Oil and Gas Program (Tennessee)

    Broader source: Energy.gov [DOE]

    The Oil and Gas section of the Tennessee Code, found in Title 60, covers all regulations, licenses, permits, and laws related to the production of natural gas. The laws create the Oil and Gas...

  4. Oil and Gas Production (Missouri)

    Broader source: Energy.gov [DOE]

    A State Oil and Gas Council regulates and oversees oil and gas production in Missouri, and conducts a biennial review of relevant rules and regulations. The waste of oil and gas is prohibited. This...

  5. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L. (Albany, OR); Summers, Cathy A. (Albany, OR); Gerdemann, Steve (Albany, OR); Oryshchyn, Danylo B. (Philomath, OR); Turner, Paul (Independence, OR); Patrick, Brian R. (Chicago, IL)

    2011-10-18T23:59:59.000Z

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  6. Understanding reservoir mechanisms using phase and component streamline tracing

    E-Print Network [OSTI]

    Kumar, Sarwesh

    2009-05-15T23:59:59.000Z

    some important signatures of reservoir dynamics, such as dominant phase in flow, appearance and disappearance of phases (e.g. gas), and flow of components like CO2. In the work being presented, we demonstrate the benefits of visualizing phase...

  7. Survey and assessment of the effects of nonconventional gases on gas distribution equipment

    SciTech Connect (OSTI)

    Jasionowski, W.J.; Scott, M.I.; Gracey, W.C.

    1982-10-01T23:59:59.000Z

    A literature search and a survey of the gas industry were conducted to assess potential problems in the distribution of nonconventional gases. Available literature did not uncover data that would describe potential problems or substantiate the presence of harmful trace elements in final gas compositions produced from various SNG processes. Information from the survey indicates that some companies have encountered problems with nonconventional gases and extraneous additives such as landfill gas, refinery off-gases, oil gas, carbureted water gas, coke-oven gas, propane-air, and compressor lubricant oils. These nonconventional gases and compressor oils may 1) cause pipeline corrosion, 2) degrade some elastomeric materials and greases and affect the integrity of seals, gaskets, O-rings, and meter and regulator diaphragms, and 3) cause operational and safety problems. The survey indicated that 62% of the responding companies plan to use supplemental gas, with most planning on more than one type. Distribution companies intend to significantly increase their use of polyethylene piping from 11.6% in 1980 to 22.4% in 2000 for gas mains and from 33.4% to 50.3% in 2000 for gas service lines.

  8. Exhaust gas recirculation apparatus

    SciTech Connect (OSTI)

    Egnell, R.A.; Hansson, B.L.

    1981-07-14T23:59:59.000Z

    Apparatus is disclosed for recirculating combustion exhaust gases to the burner region of a Stirling cycle hot-gas engine to lower combustion temperature and reduct NO/sub x/ formation includes a first wall separating the exhaust gas stream from the inlet air stream, a second wall separating the exhaust gas stream from the burner region, and low flow resistance ejectors formed in the first and second walls for admitting the inlet air to the burner region and for entraining and mixing with the inlet air portion of the exhaust gas stream. In a preferred embodiment the ejectors are arranged around the periphery of a cylindrical burner region and oriented to admit the air/exhaust gas mixture tangentially to promote mixing. In another preferred embodiment a single annular ejector surrounds and feeds the air/exhaust gas mixture to a cylindrical burner region. The annular ejector includes an annular plate with radially-directed flow passages to provide an even distribution of the air/exhaust gas mixture to the burner region.

  9. The Rheology of Concentrated Suspensions

    SciTech Connect (OSTI)

    Andreas Acrivos

    2004-09-07T23:59:59.000Z

    Research program on the rheological properties of flowing suspensions. The primary purpose of the research supported by this grant was to study the flow characteristics of concentrated suspensions of non-colloidal solid particles and thereby construct a comprehensive and robust theoretical framework for modeling such systems quantitatively. At first glance, this seemed like a modest goal, not difficult to achieve, given that such suspensions were viewed simply as Newtonian fluids with an effective viscosity equal to the product of the viscosity of the suspending fluid times a function of the particle volume fraction. But thanks to the research findings of the Principal Investigator and of his Associates, made possible by the steady and continuous support which the PI received from the DOE Office of Basic Energy Sciences, the subject is now seen to be more complicated and therefore much more interesting in that concentrated suspensions have been shown to exhibit fascinating and unique rheological properties of their own that have no counterpart in flowing Newtonian or even non-Newtonian (polymeric) fluids. In fact, it is generally acknowledged that, as the result of these investigations for which the PI received the 2001 National Medal of Science, our understanding of how suspensions behave under flow is far more detailed and comprehensive than was the case even as recently as a decade ago. Thus, given that the flow of suspensions plays a crucial role in many diverse physical processes, our work has had a major and lasting impact in a subject having both fundamental as well as practical importance.

  10. Vacuum surface flashover and high pressure gas streamers

    SciTech Connect (OSTI)

    Elizondo, J.M.; Krogh, M.L.; Smith, D.; Stolz, D.; Wright, S.N. [Allied-Signal Aerospace Co., Kansas City, MO (United States). Kansas City Div.; Sampayan, S.E.; Caporaso, G.J.; Vitello, P.; Tishchenko, N. [Lawrence Livermore National Lab., CA (United States)

    1997-07-01T23:59:59.000Z

    Pre-breakdown current traces obtained during high pressure gas breakdown and vacuum surface flashover show similar signatures. The initial pre-breakdown current spike, a flat constant current phase, and the breakdown phase with voltage collapse and current surge differ mostly in magnitude. Given these similarities, a model, consisting of the initial current spike corresponding to a fast precursor streamer (ionization wave led by a photoionizing front), the flat current stage as the heating or glow phase, and the terminal avalanche and gap closure, is applied to vacuum surface flashover. A simple analytical approximation based on the resistivity changes induced in the vacuum and dielectric surface is presented. The approximation yields an excellent fit to pre-breakdown time delay vs applied field for previously published experimental data. A detailed kinetics model that includes surface and gas contributions is being developed based in the initial approximation.

  11. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2006-07-06T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission & distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1 to June 30, 2006. Key activities during this time period include: (1) Develop and process subcontract agreements for the eight projects selected for cofunding at the February 2006 GSTC Meeting; (2) Compiling and distributing the three 2004 project final reports to the GSTC Full members; (3) Develop template, compile listserv, and draft first GSTC Insider online newsletter; (4) Continue membership recruitment; (5) Identify projects and finalize agenda for the fall GSTC/AGA Underground Storage Committee Technology Transfer Workshop in San Francisco, CA; and (6) Identify projects and prepare draft agenda for the fall GSTC Technology Transfer Workshop in Pittsburgh, PA.

  12. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2007-06-30T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is crucial in meeting the needs of these new markets. To address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance the operational flexibility and deliverability of the nation's gas storage system, and provide a cost-effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1, 2007 through June 30, 2007. Key activities during this time period included: (1) Organizing and hosting the 2007 GSTC Spring Meeting; (2) Identifying the 2007 GSTC projects, issuing award or declination letters, and begin drafting subcontracts; (3) 2007 project mentoring teams identified; (4) New NETL Project Manager; (5) Preliminary planning for the 2007 GSTC Fall Meeting; (6) Collecting and compiling the 2005 GSTC project final reports; and (7) Outreach and communications.

  13. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2006-05-10T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of January 1, 2006 through March 31, 2006. Activities during this time period were: (1) Organize and host the 2006 Spring Meeting in San Diego, CA on February 21-22, 2006; (2) Award 8 projects for co-funding by GSTC for 2006; (3) New members recruitment; and (4) Improving communications.

  14. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2007-03-31T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is crucial in meeting the needs of these new markets. To address the gas storage needs of the natural gas industry, an industry-driven consortium was created - the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance the operational flexibility and deliverability of the nation's gas storage system, and provide a cost-effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of January1, 2007 through March 31, 2007. Key activities during this time period included: {lg_bullet} Drafting and distributing the 2007 RFP; {lg_bullet} Identifying and securing a meeting site for the GSTC 2007 Spring Proposal Meeting; {lg_bullet} Scheduling and participating in two (2) project mentoring conference calls; {lg_bullet} Conducting elections for four Executive Council seats; {lg_bullet} Collecting and compiling the 2005 GSTC Final Project Reports; and {lg_bullet} Outreach and communications.

  15. Trace-Element Distribution In An Active Hydrothermal System,...

    Open Energy Info (EERE)

    halo surrounding the thermal center; (4) concentrations of As in sulfides and Li in silicate alteration minerals immediately surrounding high-temperature fluid flow-controlling...

  16. Homeotropic alignment and Förster resonance energy transfer: The way to a brighter luminescent solar concentrator

    SciTech Connect (OSTI)

    Tummeltshammer, Clemens; Taylor, Alaric; Kenyon, Anthony J.; Papakonstantinou, Ioannis, E-mail: i.papakonstantinou@ucl.ac.uk [Department of Electronic and Electrical Engineering, University College London, London WC1E 7JE (United Kingdom)

    2014-11-07T23:59:59.000Z

    We investigate homeotropically aligned fluorophores and Förster resonance energy transfer (FRET) for luminescent solar concentrators using Monte-Carlo ray tracing. The homeotropic alignment strongly improves the trapping efficiency, while FRET circumvents the low absorption at homeotropic alignment by separating the absorption and emission processes. We predict that this design doped with two organic dye molecules can yield a 82.9% optical efficiency improvement compared to a single, arbitrarily oriented dye molecule. We also show that quantum dots are prime candidates for absorption/donor fluorophores due to their wide absorption band. The potentially strong re-absorption and low quantum yield of quantum dots is not a hindrance for this design.

  17. Gas only nozzle

    DOE Patents [OSTI]

    Bechtel, William Theodore (15 Olde Coach Rd., Scotia, NY 12302); Fitts, David Orus (286 Sweetman Rd., Ballston Spa, NY 12020); DeLeonardo, Guy Wayne (60 St. Stephens La., Glenville, NY 12302)

    2002-01-01T23:59:59.000Z

    A diffusion flame nozzle gas tip is provided to convert a dual fuel nozzle to a gas only nozzle. The nozzle tip diverts compressor discharge air from the passage feeding the diffusion nozzle air swirl vanes to a region vacated by removal of the dual fuel components, so that the diverted compressor discharge air can flow to and through effusion holes in the end cap plate of the nozzle tip. In a preferred embodiment, the nozzle gas tip defines a cavity for receiving the compressor discharge air from a peripheral passage of the nozzle for flow through the effusion openings defined in the end cap plate.

  18. Gas ampoule-syringe

    DOE Patents [OSTI]

    Gay, Don D. (Aiken, SC)

    1986-01-01T23:59:59.000Z

    A gas ampoule for the shipment and delivery of radioactive gases. The gas ampoule having a glass tube with serum bottle stopper on one end and a plunger tip in the opposite end all fitting in a larger plastic tube threaded on each end with absorbent between the tubes, is seated onto the internal needle assembly via a bushing associated with the plunger and locked into the syringe barrel via barrel-bushing locking caps. The design practically eliminates the possibility of personnel contamination due to an inadvertent exposure of such personnel to the contained radioactive gas.

  19. Gas ampoule-syringe

    DOE Patents [OSTI]

    Gay, D.D.

    1985-02-02T23:59:59.000Z

    A gas ampoule for the shipment and delivery of radioactive gases. The gas ampoule having a glass tube with serum bottle stopper on one and a plunger tip in the opposite end all fitting in a larger plastic tube threaded on each end with absorbent between the tubes, is seated onto the internal needle assembly via a bushing associated with the plunger and locked into the syringe barrel via barrel-bushing locking caps. The design practically eliminates the possibility of personnel contamination due to an inadvertent exposure of such personnel to the contained radioactive gas.

  20. Calculation of material properties and ray tracing in transformation media

    E-Print Network [OSTI]

    Schurig, D; Smith, D R

    2006-01-01T23:59:59.000Z

    Complex and interesting electromagnetic behavior can be found in spaces with non-flat topology. When considering the properties of an electromagnetic medium under an arbitrary coordinate transformation an alternative interpretation presents itself. The transformed material property tensors may be interpreted as a different set of material properties in a flat, Cartesian space. We describe the calculation of these material properties for coordinate transformations that describe spaces with spherical or cylindrical holes in them. The resulting material properties can then implement invisibility cloaks in flat space. We also describe a method for performing geometric ray tracing in these materials which are both inhomogeneous and anisotropic in their electric permittivity and magnetic permeability.