Powered by Deep Web Technologies
Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

It's Elemental - The Element Sulfur  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phosphorus Phosphorus Previous Element (Phosphorus) The Periodic Table of Elements Next Element (Chlorine) Chlorine The Element Sulfur [Click for Isotope Data] 16 S Sulfur 32.065 Atomic Number: 16 Atomic Weight: 32.065 Melting Point: 388.36 K (115.21°C or 239.38°F) Boiling Point: 717.75 K (444.60°C or 832.28°F) Density: 2.067 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Non-metal Period Number: 3 Group Number: 16 Group Name: Chalcogen What's in a name? From the Sanskrit word sulvere and the Latin word sulphurium. Say what? Sulfur is pronounced as SUL-fer. History and Uses: Sulfur, the tenth most abundant element in the universe, has been known since ancient times. Sometime around 1777, Antoine Lavoisier convinced the rest of the scientific community that sulfur was an element. Sulfur is a

2

Distribution of hazardous air pollutant trace elements, total sulfur, and ash in coals from five Tertiary basins in the Rocky Mountain Region  

SciTech Connect (OSTI)

Arithmetic mean values of the contents of hazardous air pollutant (HAP) trace elements named in the 1990 Clean Air Act Amendments (antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium, and uranium), ash, and total sulfur were statistically compared on a whole-coal basis for Paleocene coals from five Tertiary basins in the Rocky Mountain Region. The study of proximate and elemental analyses indicate a relationship between trace element contents and paleogeography.

Ellis, M.S.; Stricker, G.D.; Flores, R.M. [Geological Survey, Denver, CO (United States)

1994-12-31T23:59:59.000Z

3

Elemental sulfur recovery process  

DOE Patents [OSTI]

An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

Flytzani-Stephanopoulos, M.; Zhicheng Hu.

1993-09-07T23:59:59.000Z

4

Sulfur isotope and trace element data from ore sulfides in the Noranda district (Abitibi, Canada): implications for volcanogenic massive sulfide deposit genesis  

Science Journals Connector (OSTI)

We examine models for volcanogenic massive sulfide (VMS) mineralization in the ~2.7-Ga Noranda camp, Abitibi subprovince, Superior Province, Canada, using a combination of multiple sulfur isotope and trace ele...

Elizabeth R. Sharman; Bruce E. Taylor; William G. Minarik

2014-10-01T23:59:59.000Z

5

Improve reformer operation with trace sulfur removal  

SciTech Connect (OSTI)

Modern bimetallic reforming catalysts typically have feed specifications for sulfur of 0.5 to 1 wppm in the reformer naphtha carge. Sulfur in the raw naphtha is reduced to this level by naphtha hydrotreating. While most naphtha hydrotreating operations can usually obtain these levels without substantial problems. It is difficult to obtain levels much below 0.5 to 1 wppm with this process. Revamp of a constrained existing hydrotreater to reduce product sulfur slightly can be extremely costly typically entailing replacement or addition of a new reactor. At Engelhard the authors demonstrated that if the last traces of sulfur remaining from hydrotreating can be removed, the resulting ultra-low sulfur feed greatly improves the reformer operation and provides substantial economic benefit to the refiner. Removal of the remaining trace sulfur is accomplished in a simple manner with a special adsorbent bed, without adding complexity to the reforming operation.

McClung, R.G.; Novak, W.J.

1987-01-01T23:59:59.000Z

6

Catalyst for elemental sulfur recovery process  

DOE Patents [OSTI]

A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

Flytzani-Stephanopoulos, M.; Liu, W.

1995-01-24T23:59:59.000Z

7

Trace elements in oil shale. Progress report, 1979-1980  

SciTech Connect (OSTI)

The purpose of this research program is to understand the potential impact of an oil shale industry on environmental levels of trace contaminants in the region. The program involves a comprehensive study of the sources, release mechanisms, transport, fate, and effects of toxic trace chemicals, principally the trace elements, in an oil shale industry. The overall objective of the program is to evaluate the environmental and health consequences of the release of toxic trace elements by shale and oil production and use. The baseline geochemical survey shows that stable trace elements maps can be constructed for numerous elements and that the trends observed are related to geologic and climatic factors. Shale retorted by above-ground processes tends to be very homogeneous (both in space and in time) in trace element content. Leachate studies show that significant amounts of B, F, and Mo are released from retorted shales and while B and Mo are rapidly flushed out, F is not. On the other hand, As, Se, and most other trace elements are not present in significant quantities. Significant amounts of F and B are also found in leachates of raw shales. Very large concentrations of reduced sulfur species are found in leachates of processed shale. Very high levels of B and Mo are taken up in some plants growing on processed shale with and without soil cover. There is a tendency for some trace elements to associate with specific organic fractions, indicating that organic chelation or complexation may play an important role. Many of the so-called standard methods for analyzing trace elements in oil shale-related materials are inadequate. A sampling manual is being written for the environmental scientist and practicing engineer. A new combination of methods is developed for separating the minerals in oil shale into different density fractions. Microbial investigations have tentatively identified the existence of thiobacilli in oil shale materials such as leachates. (DC)

Chappell, W R

1980-01-01T23:59:59.000Z

8

Sulfide catalysts for reducing SO2 to elemental sulfur  

DOE Patents [OSTI]

A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

2001-01-01T23:59:59.000Z

9

Trace Element Analysis | Open Energy Information  

Open Energy Info (EERE)

Trace Element Analysis Trace Element Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Trace Element Analysis Details Activities (8) Areas (8) Regions (4) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Reconstructing the fluid circulation of a hydrothermal system Thermal: Cost Information Low-End Estimate (USD): 15.001,500 centUSD 0.015 kUSD 1.5e-5 MUSD 1.5e-8 TUSD / element Median Estimate (USD): 18.001,800 centUSD 0.018 kUSD 1.8e-5 MUSD 1.8e-8 TUSD / element High-End Estimate (USD): 106.0010,600 centUSD 0.106 kUSD 1.06e-4 MUSD 1.06e-7 TUSD / element

10

Amounts of Trace Elements in Marine Cephalopods  

Science Journals Connector (OSTI)

......Amounts of Trace Elements in Marine Cephalopods T. Ueda * M. Nakahara...H. Suzuki ** * Division of Marine Radioecology, National Institute...Power Reactor and Nuclear Fuel Development Cooperation, Tokyo...Co and Cs in 5 species of marine cephalopods were determined......

T. Ueda; M. Nakahara; T. Ishii; Y. Suzuki; H. Suzuki

1979-12-01T23:59:59.000Z

11

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Trace elements and alkaliTrace elements and alkali  

E-Print Network [OSTI]

elements in fossil - and waste-derived fuelsTrace elements in fossil - and waste-derived fuels Coal Peat Heavy fuel oil Pet coke MSW RDF Wood Waste wood Waste paper Scrap tyres Sew. sludge Hg 0.02-3 ~0.07 .153 Behaviour of trace elements in coalBehaviour of trace elements in coal combustion flue gasescombustion flue

Zevenhoven, Ron

12

Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil  

DOE Patents [OSTI]

The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

2014-07-08T23:59:59.000Z

13

Effect of Microbial Activity on Trace Element Release from Sewage  

E-Print Network [OSTI]

Effect of Microbial Activity on Trace Element Release from Sewage Sludge S H A B N A M Q U R E S H in mobilization of trace elements from land-applied wastewater sludge is not well-defined. Our study examined-effective management alternative. Unfor- tunately, sewage sludge also contains potentially toxic trace elements

Walter, M.Todd

14

Engineering development of selective agglomeration: Trace element removal study  

SciTech Connect (OSTI)

Southern Company Services, Inc., (SCS) was contracted in 1989 by the US Department of Energy (DOE) to develop a commercially acceptable selective agglomeration technology to enhance the use of high-sulfur coals by 1993. The project scope involved development of a bench-scale process and components, as well as the design, testing, and evaluation of a proof-of-concept (POC) facility. To that end, a two-ton-per-hour facility was constructed and tested near Wilsonville, Alabama. Although it was not the primary focus of the test program, SCS also measured the ability of selective agglomeration to remove trace elements from coal. This document describes the results of that program.

Not Available

1993-09-01T23:59:59.000Z

15

Trace element behavior in the fluidized bed gasification of solid recovered fuels A thermodynamic study  

Science Journals Connector (OSTI)

Gasification of biomass and recycled fuels is of particular interest for the efficient production of power and heat. Trace elements present as impurities in the product gas should be removed very efficiently. The objective of this work has been to develop and test thermodynamic models for the reactions of trace elements with chlorine and sulfur in the gasification processes of recycled fuels. In particular, the chemical reactions of trace elements with main thermochemical conversion products, main ash components, and bed and sorbent material are implemented into the model. The possibilities of gas cleaning devices in condensing and removing the trace element compounds are studied by establishing the volatilization tendency of trace element compounds in reducing gases. The results obtained with the model are compared with the measured data of trace elements of gasification experiments using solid recovered fuel as feedstock. Some corresponding studies in the literature are also critically reviewed and compared. The observed discrepancies may be attributed to differences in thermodynamic databases applied and experimental arrangements. The method of removing gaseous trace elements by condensation is already in use in the 160MWth waste gasification plant in Lahti, Finland.

Jukka Konttinen; Rainer Backman; M. Hupa; Antero Moilanen; Esa Kurkela

2013-01-01T23:59:59.000Z

16

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur.  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-06-01T23:59:59.000Z

17

Trace element content of magnetohydrodynamic coal combustion effluents  

Science Journals Connector (OSTI)

Trace element contents from effluents of a simulated coal-fired magnetohydrodynamic (MHD) combustion process have been determined using thermal neutron activation analysis techniques. The quality control consi...

M. S. Akanni; V. O. Ogugbuaja; W. D. James

1983-01-01T23:59:59.000Z

18

Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

K.C. Kwon

2005-11-01T23:59:59.000Z

19

Trace element emissions. Semi-annual report, October 1994--February 1995  

SciTech Connect (OSTI)

Many trace elements can exist in raw coal gas either in the form of metallic vapors or gaseous compounds which, besides their action on potentially ``very clean`` advanced power generating systems such as fuel cells and gas turbines, can also be detrimental to plant and animal life when released into the atmosphere. Therefore, volatile trace contaminants from coal which can also be toxic must be removed before they become detrimental to both power plant performance/endurance and the environment. Five trace elements were selected in this project based on: abundance in solid coal, volatility during gasification, effects on downstream systems and toxicity to plant and animal life. An understanding was sought in this investigation of the interactions of these five trace elements (and their high temperature species) with the different components in integrated cleanup and power generating systems, as well as the ultimate effects with respect to atmospheric emissions. Utilizing thermodynamic calculations and various experimental techniques, it was determined that a number of trace contaminants that exist in coal may be substantially removed by flyash, and after that by different sorbent systems. High temperature cleanup of contaminants by sorbents such as zinc titanate, primarily to remove sulfur, can also absorb some metallic contaminants such as cadmium and antimony. Further polishing will be required, however, to eliminate trace contaminant species incorporating the elements arsenic, selemium, lead, and mercury.

Pigeaud, A.; Maru, H.; Wilemski, G.; Helble, J.

1995-02-01T23:59:59.000Z

20

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

K. C. Kwon

2006-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

K. C. Kwon

2007-09-30T23:59:59.000Z

22

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

K.C. Kwon

2009-09-30T23:59:59.000Z

23

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Final report  

SciTech Connect (OSTI)

This project has investigated new metal oxide catalysts for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as CO. Significant progress in catalyst development has been made during the course of the project. We have found that fluorite oxides, CeO{sub 2} and ZrO{sub 2}, and rare earth zirconates such as Gd{sub 2}Zr{sub 2}O{sub 7} are active and stable catalysts for reduction Of SO{sub 2} by CO. More than 95% sulfur yield was achieved at reaction temperatures about 450{degrees}C or higher with the feed gas of stoichiometric composition. Reaction of SO{sub 2} and CO over these catalysts demonstrated a strong correlation of catalytic activity with the catalyst oxygen mobility. Furthermore, the catalytic activity and resistance to H{sub 2}O and CO{sub 2} poisoning of these catalysts were significantly enhanced by adding small amounts of transition metals, such as Co, Ni, Co, etc. The resulting transition metal-fluorite oxide composite catalyst has superior activity and stability, and shows promise in long use for the development of a greatly simplified single-step sulfur recovery process to treat variable and dilute SO{sub 2} concentration gas streams. Among various active composite catalyst systems the Cu-CeO{sub 2} system has been extensively studied. XRD, XPS, and STEM analyses of the used Cu-CeO{sub 2} catalyst found that the fluorite crystal structure of ceria was stable at the present reaction conditions, small amounts of copper was dispersed and stabilized on the ceria matrix, and excess copper oxide particles formed copper sulfide crystals of little contribution to catalytic activity. A working catalyst consisted of partially sulfated cerium oxide surface and partially sulfided copper clusters. The overall reaction kinetics were approximately represented by a first order equation.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1995-06-01T23:59:59.000Z

24

E-Print Network 3.0 - atmospheric trace element Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 6 2.0 Sources and Deposition of Trace Metals Trace elements enter the atmosphere via both natural... 5 Chapter 2: Sources and Deposition of Trace Metals...

25

Larval Behavior and Natural Trace Element Signatures as Indicators of Crustacean Population Connectivity  

E-Print Network [OSTI]

variability in an atlas of trace element signatures forin creating a trace element atlas, our results show thatstage to create a trace element atlas in 2009 (Table 4.2),

Miller, Seth Haylen

2011-01-01T23:59:59.000Z

26

A study on some trace elements in Chilean seafood  

Science Journals Connector (OSTI)

Levels of essential and toxic trace elements in six marine species greatly in demand in the international market (canned pink clams, razor clams, clams, king crab, sardines, and frozen albacore tuna fish) were...

N. Gras; L. Munoz; M. Thieck

1993-03-01T23:59:59.000Z

27

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range (400--650{degree}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2} formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1993-12-31T23:59:59.000Z

28

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 4, April--June 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant(reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400--650{degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams, The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, Wei; Flytzani-Stephanopoulos, M.; Sarofim, A.F.; Williams, R.S.

1993-12-31T23:59:59.000Z

29

Trace element fingerprinting of ancient Chinese gold with femtosecond laser  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace element fingerprinting of ancient Chinese gold with femtosecond laser Trace element fingerprinting of ancient Chinese gold with femtosecond laser ablation-inductivity coupled mass spectrometry Title Trace element fingerprinting of ancient Chinese gold with femtosecond laser ablation-inductivity coupled mass spectrometry Publication Type Journal Article Year of Publication 2009 Authors Brostoff, Lynn B., Jhanis J. Gonzalez, Paul Jett, and Richard E. Russo Journal Journal of Archeological Science Volume 36 Start Page 461 Issue 2 Pagination 461-466 Date Published 02/2009 Keywords Ancient gold, femtosecond, la-icp-ms, Trace element Abstract In this collaborative investigation, femtosecond laser ablation-inductively coupled mass spectrometry (LA-ICP-MS) was applied to the study of a remarkable group of ancient Chinese gold objects in the Smithsonian's Freer Gallery of Art and Arthur M. Sackler Gallery. Taking advantage of the superior ablation characteristics and high precision of a femtosecond 266 nm Ti:sapphire laser at Lawrence Berkeley National Laboratory, major, minor and trace element concentrations in the gold fragments were quantified. Results validate use of femtosecond LA-ICP-MS for revealing ''fingerprints'' in minute gold samples. These fingerprints allow us to establish patterns based on the association of silver, palladium and platinum that support historical, technical and stylistic relationships, and shed new light on these ancient objects.

30

Trace element partitioning between type B CAI melts and melilite and spinel: Implications for trace element distribution  

E-Print Network [OSTI]

. Partition coefficients between intermediate composition melilites and CAI melt are the following: Li, 0.5 size energetics analysis is used to assess isovalent partitioning into the different cation sites, interpreta- tion of the trace element and isotope compositions of CAIs, particularly the light elements Li

Mcdonough, William F.

31

Trace element partitioning in Texas lignite  

E-Print Network [OSTI]

), but collected from the one of the secondary tanks which contains the slurry that exits the scrubber tower and is either recycled or sent to the thickener tank. 10. Bag house FGD (flue gas desulfurization system) fly ash fines (BHA): white-gray, dry, fine... Station. Concentrations of 41 elements were determined by neutron activation analysis. The particle size distribution was determined by Coulter counter analysis for the fly ash collected from the electrostatic precipitator outlets and from the flue...

Acevedo, Lillian Esther

1989-01-01T23:59:59.000Z

32

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

NONE

1997-01-01T23:59:59.000Z

33

Microsoft Word - Vapor Phase Elemental Sulfur Tech Brief DRAFT bbl 08-24.docx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AT A GLANCE AT A GLANCE  eliminates excavation expense  applicable to large or small sites  straightforward deployment  uses heat to distribute sulfur throughout a soil  mercury reacts with sulfur to form immobile and insoluble minerals  patent applied for TechBrief Vapor Phase Elemental Sulfur Amendment for Sequestering Mercury in Contaminated Soil Scientists at the Savannah River National Laboratory (SRNL) have identified a method of targeting mercury in contaminated soil zone by use of sulfur vapor heated gas. Background Mercury contamination in soil is a common problem in the environment. The most common treatment is excavation - a method that works well for small sites where the

34

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October 1993--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400-650 {degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought {open_quotes}Claus-alternative{close_quotes} for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1996-01-01T23:59:59.000Z

35

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

NONE

1997-12-31T23:59:59.000Z

36

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Fifth quarterly technical progress report, December 1996  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1996-12-01T23:59:59.000Z

37

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Sixth quarterly technical progress report, January - March 1997  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-03-01T23:59:59.000Z

38

Advanced product recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Third quarterly technical progress report  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied to 72,000 MW of US, coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed form the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. Arthur D. Little, Inc., together with its industry and commercialization advisor, Engelhard Corporation, and its university partner, Tufts, plans to develop and scale-up an advanced, byproduct recovery technology that is a direct, catalytic process for reducing sulfur dioxide to elemental sulfur. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, they have planned a structured program including: market/process/cost/evaluation; lab-scale catalyst preparation/optimization studies; lab-scale, bulk/supported catalyst kinetic studies; bench-scale catalyst/process studies; and utility review. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning.

NONE

1996-07-01T23:59:59.000Z

39

STEIN'S METHOD, HEAT KERNEL, AND TRACES OF POWERS OF ELEMENTS OF COMPACT LIE GROUPS  

E-Print Network [OSTI]

STEIN'S METHOD, HEAT KERNEL, AND TRACES OF POWERS OF ELEMENTS OF COMPACT LIE GROUPS JASON FULMAN Abstract. Combining Stein's method with heat kernel techniques, we show that the trace of the jth power There is a large literature on the traces of powers of random elements of compact Lie groups. One of the earliest

Fulman, Jason

40

STEIN'S METHOD, HEAT KERNEL, AND TRACES OF POWERS OF ELEMENTS OF COMPACT LIE GROUPS  

E-Print Network [OSTI]

STEIN'S METHOD, HEAT KERNEL, AND TRACES OF POWERS OF ELEMENTS OF COMPACT LIE GROUPS JASON FULMAN Abstract. Combining Stein's method with heat kernel techniques, we show that the trace of the jth power on the traces of powers of random elements of compact Lie groups. One of the earliest results is due to Diaconis

Fulman, Jason

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Microbial acidification and pH effects on trace element release from sewage sludge  

E-Print Network [OSTI]

Microbial acidification and pH effects on trace element release from sewage sludge Shabnam Qureshia; Trace metals; Mobilization; Land application 1. Introduction Trace elements in land-applied wastewater sludge (sewage biosolids) are potentially phyto- or zoo-toxic if present in sufficient concentration

Walter, M.Todd

42

E-Print Network 3.0 - airborne trace element Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Sample search results for: airborne trace element Page: << < 1 2 3 4 5 > >> 1 AIR-DEPOSITED POLLUTION IN THE ANACOSTIA RIVER WATERSHED Summary: pollution in Lake...

43

Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases  

SciTech Connect (OSTI)

The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

2001-11-06T23:59:59.000Z

44

An evaluation of trace element release associated with acid mine drainage  

SciTech Connect (OSTI)

The determination of trace element release from geologic materials, such as oil shale and coal overburden, is important for proper solid waste management planning. The objective of this study was to determine a correlation between release using the following methods: (1) sequential selective dissolution for determining trace element residencies, (2) toxicity characteristic leaching procedure (TCLP), and (3) humidity cell weathering study simulating maximum trace element release. Two eastern oil shales were used, a New Albany shale that contains 4.6 percent pyrite, and a Chattanooga shale that contains 1.5 percent pyrite. Each shale was analyzed for elemental concentrations by soluble, adsorbed, organic, carbonate, and sulfide phases. The results of the results of the selective dissolution studies show that each trace element has a unique distribution between the various phases. Thus, it is possible to predict trace element release based on trace element residency. The TCLP results show that this method is suitable for assessing soluble trace element release but does not realistically assess potential hazards. The results of the humidity cell studies do demonstrate a more reasonable method for predicting trace element release and potential water quality hazards. The humidity cell methods, however, require months to obtain the required data with a large number of analytical measurements. When the selective dissolution data are compared to the trace element concentrations in the TCLP and humidity cell leachates, it is shown that leachate concentrations are predicted by the selective dissolution data. Therefore, selective dissolution may represent a rapid method to assess trace element release associated with acid mine drainage.

Sullivan, P.J.; Yelton, J.L. (Univ. of Wyoming Research Corp., Laramie (United States))

1988-12-01T23:59:59.000Z

45

Trace Element Analysis At Walker-Lane Transitional Zone Region (Coolbaugh,  

Open Energy Info (EERE)

Trace Element Analysis At Walker-Lane Transitional Zone Region (Coolbaugh, Trace Element Analysis At Walker-Lane Transitional Zone Region (Coolbaugh, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Walker-Lane Transitional Zone Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for

46

Trace Element Analysis At Nw Basin & Range Region (Coolbaugh, Et Al., 2010)  

Open Energy Info (EERE)

Trace Element Analysis At Nw Basin & Range Region (Coolbaugh, Et Al., 2010) Trace Element Analysis At Nw Basin & Range Region (Coolbaugh, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Nw Basin & Range Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Northwest Basin and Range Geothermal Region Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for

47

Trace element partitioning between baddeleyite and carbonatite melt at high pressures and high temperatures  

E-Print Network [OSTI]

as the heavy rare earth elements (HREE) prefer to enter baddeleyite rather than carbonate melts (D>1), whereas the light rare earth elements (LREE) and other trace elements behave incompatibly (D in carbonatite melts. Baddeleyite is known to accumulate the high field strength elements (HFSE) and some rare

48

JV Task-123 Determination of Trace Element Concentrations at an Eastern Bituminous Coal Plant Employing an SCR and Wet FGD  

SciTech Connect (OSTI)

The Energy & Environmental Research Center (EERC), in partnership with Babcock & Wilcox (B&W) and with funding from U.S. Department of Energy (DOE), conducting tests to prove that a high level of mercury control (>90%) can be achieved at a power plant burning a high-sulfur eastern bituminous coal. With funding from the Electric Power Research Institute (EPRI), DOE, and Center for Air Toxic Metals{reg_sign} (CATM{reg_sign}) Affiliates Program, the EERC completed an additional sampling project to provide data as to the behavior of a number of trace elements across the various pollution control devices, with a special emphasis on the wet flue gas desulfurization (FGD) system. Results showed that the concentrations of almost all the elements of interest leaving the stack were very low, and a high percentage of the trace elements were captured in the electrostatic precipitator (ESP) (for most, >80%). Although, with a few exceptions, the overall mass balances were generally quite good, the mass balances across the wet FGD were more variable. This is most likely a result of some of the concentrations being very low and also the uncertainties in determining flows within a wet FGD.

Dennis Laudal

2008-05-01T23:59:59.000Z

49

Trace-Element Distribution In An Active Hydrothermal System, Roosevelt Hot  

Open Energy Info (EERE)

Trace-Element Distribution In An Active Hydrothermal System, Roosevelt Hot Trace-Element Distribution In An Active Hydrothermal System, Roosevelt Hot Springs Thermal Area, Utah Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Trace-Element Distribution In An Active Hydrothermal System, Roosevelt Hot Springs Thermal Area, Utah Details Activities (3) Areas (1) Regions (0) Abstract: Chemical interaction of thermal fluids with reservoir rock in the Roosevelt Hot Springs thermal area, Utah, has resulted in the development of characteristic trace-element dispersion patterns. Multielement analyses of surface rock samples, soil samples and drill cuttings from deep exploration wells provide a three-dimensional perspective of chemical redistribution within this structurally-controlled hot-water geothermal system. Five distinctive elemental suites of chemical enrichment are

50

Trace Element Analysis At Socorro Mountain Area (Owens, Et Al., 2005) |  

Open Energy Info (EERE)

Trace Element Analysis At Socorro Mountain Area (Owens, Et Al., 2005) Trace Element Analysis At Socorro Mountain Area (Owens, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Socorro Mountain Area (Owens, Et Al., 2005) Exploration Activity Details Location Socorro Mountain Area Exploration Technique Trace Element Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes In order to determine which of the faults in these regions were active and open to hydrothermal fluid circulation, we have employed selective ion geochemistry that is a new geochemical method capable of detecting anomalous concentrations for up to 47 elements transported to soils by geochemical cells or low pressure vapors. Enzyme leach and Terrasol leach are two such techniques. This method has to datae been mostly applied to

51

Time Series of Trace Element Concentrations Calculated from  

E-Print Network [OSTI]

a). A total of 120 samples were collected at sites within the Bay, outside the Golden Gate receives many waste water discharges, especially in areas south of the Dumbarton Bridge, that contain trace

52

Oxidation of trace amounts of transplutonium elements to the tetravalent state in solutions of mineral acids and their stabilities  

SciTech Connect (OSTI)

The behavior of trace amounts of americium(IV) in sulfuric and nitric acid solutions as a function of the mineral acid, potassium phosphotungstate, and ammonium persulfate concentrations was investigated. The stability of americium(IV) was studied. The optimal conditions and time of oxidation of trace amounts of americium to the tetravalent state were found on the basis of the experimental data obtained.

Milyukova, M.S.; Varezhkina, N.S.; Kuzovkina, E.V.; Malikov, D.A.; Myasoedov, B.F.

1989-01-01T23:59:59.000Z

53

Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area,  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area, Utah Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area, Utah Abstract Chemical interaction of thermal brines with reservoir rock in the Roosevelt Hot Springs thermal area has resulted in the development of distinctive trace element signatures. Geochemical analysis of soil sample, shallow temperature gradient drill hole cuttings and deep drill hole cutting provides a three dimensional perspective of trace element distributions within the system. Distributions of As, Hg and Li provide the clearest expression of hydrothermal activity. Comparison of these distribution

54

Trace element mineral transformations associated with hydration and recarbonation of retorted oil shale  

Science Journals Connector (OSTI)

A laboratory study was conducted to evaluate the influence of hydration and recarbonation on the solidphase distribution of trace elements in retorted oil shale. The oil shale samples were retorted by the Paraho ...

M. E. Essington

55

E-Print Network 3.0 - aristotelis trace elements Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

results for: aristotelis trace elements Page: << < 1 2 3 4 5 > >> 1 Examen LA207 Matlab: applications en mecanique Summary: en imposant la vue de dessus avec la fonction...

56

ADVANCED BYPRODUCT RECOVERY: DIRECT CATALYTIC REDUCTION OF SO2 TO ELEMENTAL SULFUR  

SciTech Connect (OSTI)

Arthur D. Little, Inc., together with its commercialization partner, Engelhard Corporation, and its university partner Tufts, investigated a single-step process for direct, catalytic reduction of sulfur dioxide from regenerable flue gas desulfurization processes to the more valuable elemental sulfur by-product. This development built on recently demonstrated SO{sub 2}-reduction catalyst performance at Tufts University on a DOE-sponsored program and is, in principle, applicable to processing of regenerator off-gases from all regenerable SO{sub 2}-control processes. In this program, laboratory-scale catalyst optimization work at Tufts was combined with supported catalyst formulation work at Engelhard, bench-scale supported catalyst testing at Arthur D. Little and market assessments, also by Arthur D. Little. Objectives included identification and performance evaluation of a catalyst which is robust and flexible with regard to choice of reducing gas. The catalyst formulation was improved significantly over the course of this work owing to the identification of a number of underlying phenomena that tended to reduce catalyst selectivity. The most promising catalysts discovered in the bench-scale tests at Tufts were transformed into monolith-supported catalysts at Engelhard. These catalyst samples were tested at larger scale at Arthur D. Little, where the laboratory-scale results were confirmed, namely that the catalysts do effectively reduce sulfur dioxide to elemental sulfur when operated under appropriate levels of conversion and in conditions that do not contain too much water or hydrogen. Ways to overcome those limitations were suggested by the laboratory results. Nonetheless, at the end of Phase I, the catalysts did not exhibit the very stringent levels of activity or selectivity that would have permitted ready scale-up to pilot or commercial operation. Therefore, we chose not to pursue Phase II of this work which would have included further bench-scale testing, scale-up, pilot-scale (0.5 MW{sub e}) testing at conditions representative of various regenerable SO{sub 2}-control systems, preparation of a commercial process design, and development of a utility-scale demonstration plan.

Robert S. Weber

1999-05-01T23:59:59.000Z

57

Zevenhoven & Kilpinen TRACE ELEMENTS, ALKALI METALS 19.6.2001 8-1 Chapter 8 Trace elements,  

E-Print Network [OSTI]

air pollutants), "known or suspected of causing cancer or other serious health effects" (see also, in part stemming from anthropogenic sources, i.e. pollution. In wastes and waste-derived fuels the "trace to fouling of turbine blades (mainly Ca)or pollute or poison catalysts (mainly As) or sorbents downstream

Zevenhoven, Ron

58

Passivation of Si(100)2x1 surfaces with elemental sulfur  

SciTech Connect (OSTI)

Silicon and other semiconductors (GaAs, InP) are widely used in high-speed electronics, long-wavelength optical circuits (optoelectronics) and, mainly in space technology, as solar cells (photovoltaics). Deposition of elemental S on Si(100)2x1 surfaces at room temperature changes the reconstructed Si(100)2x1 to its original bulk-terminated Si(100)1x1 surface. Sulfur forms initially a (2x1) on the Si(100)2x1 surface and subsequently a (1x1) on the Si(100)1x1. Above 1 ML, sulfur is diffused into the Si bulk near the surface. The sticking coefficient of S on Si(100) surface is constant up to 2 ML. Deposition of S at RT up to 1 ML increases the work function of the surface by about .3 {+-} 0.05 eV. Above 1 ML, as the S is diffused into the Si bulk, the work function decreases.

Papageorgopoulos, A. [Clark Atlanta Univ., GA (United States)

1996-12-31T23:59:59.000Z

59

Trace elements in co-combustion of solid recovered fuel and coal  

Science Journals Connector (OSTI)

Trace element partitioning in co-combustion of a bituminous coal and a solid recovered fuel (SRF) was studied in an entrained flow reactor. The experiments were carried out at conditions similar to pulverized coal combustion, with SRF shares of 7.9wt.% (wet basis), 14.8wt.% and 25.0wt.%. In addition, the effect of additives such as NaCl, PVC, ammonium sulphate, and kaolinite on trace element partitioning was investigated. The trace elements studied were As, Cd, Cr, Pb, Sb and Zn, since these elements were significantly enriched in SRF as compared to coal. During the experiments, bottom ash was collected in a chamber, large fly ash particles were collected by a cyclone with a cut-off diameter of ~2.5?m, and the remaining fly ash particles were gathered in a filter. It was found that when coal was co-fired with SRF, the As, Cd, Pb, Sb and Zn content in filter ash/cyclone ash increased almost linearly with their content in fuel ash. This linear tendency was affected when the fuels were mixed with additives. The volatility of trace elements during combustion was assessed by applying a relative enrichment (RE) factor, and TEMEDS analysis was conducted to provide qualitative interpretations. The results indicated that As, Cd, Pb, Sb and Zn were highly volatile when co-firing coal and SRF, whereas the volatility of Cr was relatively low. Compared with coal combustion, co-firing of coal and SRF slightly enhanced the volatility of Cd, Pb and Zn, but reduced the volatility of Cr and Sb. The Cl-based additives increased the volatility of Cd, Pb and As, whereas addition of ammonium sulphate generally decreased the volatility of trace elements. Addition of kaolinite reduced the volatility of Pb, while the influence on other trace elements was insignificant. The results from the present work imply that trace element emission would be significantly increased when coal is co-fired with SRF, which may greatly enhance the toxicity of the dusts from coal-fired power plant. In order to minimize trace element emission in co-combustion, in addition to lowering the trace element content in SRF, utilizing SRF with low Cl content and coal with high S and aluminosilicates content would be desirable.

Hao Wu; Peter Glarborg; Flemming Jappe Frandsen; Kim Dam-Johansen; Peter Arendt Jensen; Bo Sander

2013-01-01T23:59:59.000Z

60

Trace Element Analysis At Central Nevada Seismic Zone Region (Coolbaugh, Et  

Open Energy Info (EERE)

Coolbaugh, Et Coolbaugh, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Central Nevada Seismic Zone Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Central Nevada Seismic Zone Geothermal Region Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for geothermal exploration, the analysis of lithium and other elements in tufa

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Effects of reactive element additions and sulfur removal on the oxidation behavior of FECRAL alloys  

SciTech Connect (OSTI)

The results of this study have shown that desulfurization of FeCrAl alloys by hydrogen annealing can result in improvements in cyclic oxidation comparable to that achieved by doping with reactive elements. Moreover, specimens of substantial thicknesses can be effectively desulfurized because of the high diffusivity of sulfur in bcc iron alloys. The results have also shown that there is less stress generation during the cyclic oxidation of Y-doped FeCrAl compared to Ti-doped or desulfurized FeCrAl. This indicates that the growth mechanism, as well as the strength of the oxide/alloy interface, influences the ultimate oxidation morphology and stress state which will certainly affect the length of time the alumina remains protective.

Stasik, M.C.; Pettit, F.S.; Meier, G.H. (Univ. of Pittsburgh, PA (United States). Dept. of Materials Science and Engineering); Ashary, A. (Praxair, Indianapolis, IN (United States)); Smialek, J.L. (NASA Lewis Research Center, Cleveland, OH (United States))

1994-12-15T23:59:59.000Z

62

Trace elements in brown coal and its products of combustion  

Science Journals Connector (OSTI)

Concentrations of 38 elements in brown coal, bottom ash and size fractionated ESP coal ash from the Belchatw I Power Plant were determined by INAA. Based on enrichment factors calculated relatively to iron an...

U. Tomza; P. Kaleta

1986-10-20T23:59:59.000Z

63

Trace Element Analysis At Roosevelt Hot Springs Area (Christensen, Et Al.,  

Open Energy Info (EERE)

Christensen, Et Al., Christensen, Et Al., 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Roosevelt Hot Springs Area (Christensen, Et Al., 1983) Exploration Activity Details Location Roosevelt Hot Springs Area Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes Three of the recognized trace-element suites are characteristic of the surface and near-surface environment. These are: (1) concentrations of As, Sb, Be and Hg associated with siliceous material at the location of liquid discharge, fluid mixing, or at boiling interfaces; (2) deposits of Mn and Fe oxides containing concentrations of Ba, W, Be, Co, Cu, As, Sb and Hg formed by the oxidation of cooled brines; and (3) high concentrations of Hg

64

Trace Element Analysis At Northern Basin & Range Region (Coolbaugh, Et Al.,  

Open Energy Info (EERE)

At Northern Basin & Range Region (Coolbaugh, Et Al., At Northern Basin & Range Region (Coolbaugh, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Northern Basin & Range Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Northern Basin and Range Geothermal Region Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for

65

Correlations of trace elements in breast human tissues: Evaluation of spatial distribution using {mu}-XRF  

SciTech Connect (OSTI)

The aim of this work is to investigate microscopic correlations between trace elements in breast human tissues. A synchrotron X-ray fluorescence microprobe system ({mu}-XRF) was used to obtain two-dimensional distribution of trace element Ca, Fe, Cu and Zn in normal (6 samples) and malignant (14 samples) breast tissues. The experiment was performed in X-ray Fluorescence beam line at Laboratorio Nacional de Luz Sincrotron (LNLS), Campinas, Brazil. The white microbeam was generated with a fine conical capillary with a 20 {mu}m output diameter. The samples were supported on a XYZ table. An optical microscope with motorized zoom was used for sample positioning and choice the area to be scanned. Automatic two-dimensional scans were programmed and performed with steps of 30 {mu}m in each direction (x, y) on the selected area. The fluorescence signals were recorded using a Si(Li) detector, positioned at 90 degrees with respect to the incident beam, with a collection time of 10 s per point. The elemental maps obtained from each sample were overlap to observe correlation between trace elements. Qualitative results showed that the pairs of elements Ca-Zn and Fe-Cu could to be correlated in malignant breast tissues. Quantitative results, achieved by Spearman correlation tests, indicate that there is a spatial correlation between these pairs of elements (p < 0.001) suggesting the importance of these elements in metabolic processes associated with the development of the tumor.

Piacenti da Silva, Marina; Silva, Deisy Mara da; Ribeiro-Silva, Alfredo; Poletti, Martin Eduardo [Departamento de Fisica, FFCLRP/USP, Av. dos Bandeirantes n. 3900, 14040-901 Ribeirao Preto - SP (Brazil); Departamento de Patologia, HCFM/USP, Av. dos Bandeirantes n. 3900, 14040-901 Ribeirao Preto - SP (Brazil); Departamento de Fisica, FFCLRP/USP, Av. dos Bandeirantes n. 3900, 14040-901 Ribeirao Preto - SP (Brazil)

2012-05-17T23:59:59.000Z

66

Distribution of trace elements in waters and sediments of the Seversky Donets  

E-Print Network [OSTI]

Distribution of trace elements in waters and sediments of the Seversky Donets transboundary sources in the transboundary watershed of the Seversky Donets River (Ukraine/Russia). Bed sediments, V) and Th were measured in stream water and sediments. The low levels and variability of Th

Paris-Sud XI, Université de

67

Elevated Trace Element Concentrations in Southern Toads, Bufo terrestris, Exposed to Coal Combustion Waste  

E-Print Network [OSTI]

, and behavioral abnormalities in amphibians to coal combustion wastes (coal ash). Few studies, however, have determined trace element concentrations in amphibians exposed to coal ash. In the current study we compare high levels of selenium and may be useful bioindicators in agricultural and coal ash-impacted habitats

Hopkins, William A.

68

Trace Elements in Tree Rings: Evidence of Recent and Historical Air Pollution  

E-Print Network [OSTI]

, or both. Tree rings have been used to construct records of climate (1), document heavy metal pollution (2Trace Elements in Tree Rings: Evidence of Recent and Historical Air Pollution C. F. Baes III and S and Historical Air Pollution Abstract. Annual growth rinks from short-leaf pine trees in the Great Smoky

Baes, Fred

69

Effect of Processing Mode on Trace Elements in Dewatered Sludge Products Brian K. Richards1  

E-Print Network [OSTI]

Effect of Processing Mode on Trace Elements in Dewatered Sludge Products Brian K. Richards1 *, John considering the land application of wastewater sludges. The effects of pelletization/drying, composting compared. A single day's production of dewatered anaerobically-digested sludge (Syracuse, NY) was used

Walter, M.Todd

70

Extractable trace elements in the soil profile after years of biosolids application  

SciTech Connect (OSTI)

The US Environmental Protection Agency (USEPA) and some state agencies regulate trace element additions to soil from land application of biosolids. The authors generally consider trace elements added in biosolids (sewage sludge) to accumulate in the soil surface without significant transport below the plow layer. They used 11 yr of field-study information from biosolids addition to dryland hard red winter wheat (Triticum aestivum L. Vona or TAM107) to determine the distribution of NH{sub 4}HCO{sub 3} diethylenetriaminepentaacetic acid (AB-DTPA)-extractable Cd, Cr, Cu, Mo, Ni, Pb, and Zn in 0 to 20 (plow layer), 20 to 60, 60 to 100, and 100 to 150 cm depth increments. This study is unique since it involves multiple biosolids application in a dryland summer fallow agroecosystem. The authors applied five or six applications of biosolids from the cities of Littleton and Englewood, CO, to Weld loam or Platner loam at four locations. This paper focuses on the 0 (control), the 56 or 67 kg of N ha{sup {minus}1} fertilizer rates, and the 6.7 and 26.8 dry Mg of biosolids ha{sup {minus}1} rates that they added every crop year. The authors observed significant (P < 0.10) accumulations of the trace elements in the plow layer of the biosolids-amended soils. Only Zn showed consistent increases in extractable levels below the plow layer at all four sites. The biosolids Zn concentration was larger than any other trace element resulting in larger loading of this element.

Barbarick, K.A.; Ippolito, J.A.; Westfall, D.G. [Colorado State Univ., Fort Collins, CO (United States). Dept. of Soil and Crop Sciences

1998-07-01T23:59:59.000Z

71

Trace Element Analysis At Long Valley Caldera Area (Klusman & Landress,  

Open Energy Info (EERE)

Klusman & Landress, Klusman & Landress, 1979) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Long Valley Caldera Area (Klusman & Landress, 1979) Exploration Activity Details Location Long Valley Caldera Area Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes This study involved the field collection and laboratory analysis of Al-horizon soil samples in the vicinity of a known geothermal source at Long Valley, California. The samples were analyzed for several constituents known to have influence on Hg retention by soils, including pH, hydrous Fe and Mn, and organic carbon, as well as Hg. The data compiled for these secondary parameters and the field-determined parameters of geology, soil

72

Investigation on thermal and trace element characteristics during co-combustion biomass with coal gangue  

Science Journals Connector (OSTI)

Abstract The thermochemical behaviors during co-combustion of coal gangue (CG), soybean stalk (SS), sawdust (SD) and their blends prepared at different ratios have been determined via thermogravimetric analysis. The simulate experiments in a fixed bed reactor were performed to investigate the partition behaviors of trace elements during co-combustion. The combustion profiles of biomass was more complicated than that of coal gangue. Ignition property and thermal reactivity of coal gangue could be enhanced by the addition of biomass. No interactions were observed between coal gangue and biomass during co-combustion. The volatilization ratios of trace elements decrease with the increasing proportions of biomass in the blends during co-combustion. Based on the results of heating value, activation energy, base/acid ratio and gaseous pollutant emissions, the blending ratio of 2030% biomass content is regarded as optimum composition for blending and could be applied directly at current combustion application with few modifications.

Chuncai Zhou; Guijian Liu; Ting Fang; Paul Kwan Sing Lam

2015-01-01T23:59:59.000Z

73

Evidence for a Plasma Core during Multibubble Sonoluminescence in Sulfuric Acid  

E-Print Network [OSTI]

.g., SOx, trace amounts of H2S, and elemental sulfur)7 are either highly soluble or solids. Prior MBSL to be problematic. These volatile products can have limited solubility in the liquid and therefore accumulate for the generation of higher temperatures during cavitation. Sulfuric acid is one such liquid because it has a very

Suslick, Kenneth S.

74

Stein's method, heat kernel, and traces of powers of elements of compact Lie groups  

E-Print Network [OSTI]

Combining Stein's method with heat kernel techniques, we show that the trace of the jth power of an element of U(n,C), USp(n,C) or SO(n,R) has a normal limit with error term of order j/n. In contrast to previous works, here j may be growing with n. The technique should prove useful in the study of the value distribution of approximate eigenfunctions of Laplacians.

Jason Fulman

2010-05-07T23:59:59.000Z

75

Lubricant oil consumption effects on diesel exhaust ash emissions using a sulfur dioxide trace technique and thermogravimetry  

E-Print Network [OSTI]

A detailed experimental study was conducted targeting lubricant consumption effects on ,diesel exhaust ash levels using a model year 2002 5.9L diesel engine, high and low Sulfur commercial lubricants, and clean diesel ...

Plumley, Michael J

2005-01-01T23:59:59.000Z

76

SULFUR POLYMER ENCAPSULATION.  

SciTech Connect (OSTI)

Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

KALB, P.

2001-08-22T23:59:59.000Z

77

Determination of organic inorganic associations of trace elements in New Albany shale kerogen  

SciTech Connect (OSTI)

The inorganic and organic trace element associations in the kerogen isolated from the New Albany shale were studied by analysis of kerogen fractions and a mineral residue obtained using density separations. Elemental mass balance data from these fractions indicate a predominantly inorganic association with pyrite and marcasite for several elements (As, Co, Ga, Mn, Ni, Sb and Se). The degree of inorganic association of these elements was determined by treatment of the mineral residue ({approximately}85% FeS{sub 2}) with dilute HNO{sub 3} to remove pyrite and marcasite. The association of several other elements in minerals which are insoluble in dilute HNO{sub 3} (rutile, zircon, etc.) were also determined. The results of these studies indicate an essentially total organic association for V and approximately 95% organic association for Ni in New Albany kerogen. The determination of organically combined elements is very difficult for those elements which are predominantly concentrated in the mineral fraction. Correction methods based on low temperature ashing, chemical removal of pyrite, and physical methods of separation are compared.

Mercer, G.E.; Filby, R.H. (Washington State Univ., Pullman (USA))

1989-03-01T23:59:59.000Z

78

Minor and Trace Element Determination of Food Spices and Pulses of Different Origins by NAA and PAA  

Science Journals Connector (OSTI)

INAA, RNAA and IPAA were employed to determine upto 26 trace elements in 32 spices of 18 species and 16 pulses of 8 species originating from different localities. The results are compared with each other and t...

Y. Miyamoto; A. Kajikawa; J. H. Zaidi

2000-03-01T23:59:59.000Z

79

Trace element mobility during sub-seafloor alteration of basaltic glass from Ocean Drilling Program site 953 (off Gran Canaria)  

Science Journals Connector (OSTI)

Trace element concentrations of altered basaltic glass shards (layer silicates) and zeolites in volcaniclastic sediments drilled in the volcanic apron northeast of Gran Canaria during Ocean Drilling Program (ODP)...

A. Utzmann; T. Hansteen; H.-U. Schmincke

2002-08-01T23:59:59.000Z

80

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

SciTech Connect (OSTI)

Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

2008-07-02T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Application of synchrotron radiation to x-ray fluorescence analysis of trace elements  

SciTech Connect (OSTI)

The development of synchrotron radiation x-ray sources has provided the means to greatly extend the capabilities of x-ray fluorescence analysis for determinations of trace element concentrations. A brief description of synchrotron radiation properties provides a background for a discussion of the improved detection limits compared to existing x-ray fluorescence techniques. Calculated detection limits for x-ray microprobes with micrometer spatial resolutions are described and compared with experimental results beginning to appear from a number of laboratories. The current activities and future plans for a dedicated x-ray microprobe beam line at the National Synchrotron Light Source (NSLS) of Brookhaven National Laboratory are presented.

Gordon, B.M.; Jones, K.W.; Hanson, A.L.

1986-08-01T23:59:59.000Z

82

Heterogeneous distribution of trace elements and fluorine in phosphogypsum by-product  

Science Journals Connector (OSTI)

Phosphogypsum (PG), a by-product from phosphate fertilizer production, is composed mainly of gypsum (CaSO42H2O) but also contains minor quantities of trace elements (TE), rare earth elements (REE) and F. Some elements may be elevated in quantities to be of environmental concern. This study determined the distribution of TE, REE and F among three size fractions (53 ?m) in \\{PGs\\} derived from three different phosphate rock sources. Fine fraction PG (<20 ?m) composed of <10% of total PG mass but was highly enriched in TE, REE and F compared to unfractionated PG. For PG derived from Idaho rock, Se in the fine fraction was enriched 830 times over soil and 415 times over shale while Cd was enriched in the fine fraction 70-fold over shale and soil. Fluorine was elevated 37 times in the fine fraction compared to shale. The same trends were observed for PG derived from Togo and Florida rocks. Elevated elemental concentrations in fine particles and particle sorting during PG deposition may contribute to chemical heterogeneity of PG repositories, and make elements more susceptible to mobilization processes, such as leaching and erosion. Removal of fines will improve the utilization of PG in other industries, such as for use as an amendment to agricultural soils.

J.M. Arocena; P.M. Rutherford; M.J. Dudas

1995-01-01T23:59:59.000Z

83

Trace element geochemical zoning in the Roosevelt Hot Springs thermal area, Utah  

SciTech Connect (OSTI)

Chemical interaction of thermal brines with reservoir rock in the Roosevelt Hot Springs thermal area has resulted in the development of distinctive trace element signatures. Geochemical analysis of soil samples, shallow temperature-gradient drill hole cuttings and deep drill hole cuttings provides a three-dimensional perspective of trace element distributions within the system. Distributions of As, Hg and Li provide the clearest expression of hydrothermal activity. Comparison of these distributions suggests that Li, followed by As and Hg, are progressively deposited by outward flowing, cooling, thermal fluids. Hg, in contrast to As and Li, is distributed only within the outer portions of the thermal system where temperatures are less than about 225/sup 0/C. Heating experiments indicate that extensive Hg remobilization in Roosevelt samples occurs at temperatures as low as 200/sup 0/ to 250/sup 0/C. This suggests that the distribution of Hg largely reflects the present system thermal configuration and that this distribution may be a useful soild geothermometer.

Christensen, O.D.; Moore, J.N.; Capuano, R.M.

1980-09-01T23:59:59.000Z

84

The distribution of ten trace elements and minerals in three lignite seams from the Mae Moh Mine, Thailand  

SciTech Connect (OSTI)

Understanding the association of major, minor and trace elements in lignites and their accompanying strata is important from a number of perspectives which include: potential health problems from environmental pollutants, rehabilitation after mining, combustion for power etc. The material which follows represents some preliminary observations on the mineralogy and distribution of 10 trace elements in lignites and accompanying sediments from the Mae Moh mine, Thailand. Samples collected from freshly exposed mine faces were air dried and analyzed for moisture and ash. Trace element concentrations were determined on {open_quotes}whole{close_quotes} coals and sediments by NAA and XRF. All chemical analyses are expressed as a fraction of the total dry sediment. Mineralogy of both LTA and sediments was determined by XRD. The chemistry and morphology of individual particles were examined by the Electron microprobe. The analyses are used to make some conclusions about the spatial occurrence of these elements within the seam and their partitioning between organic and inorganic phases.

Hart, B.; Powell, M.P.; Fyfe, W.S. [Univ. of Ontario (Canada)

1994-12-31T23:59:59.000Z

85

Emission factors for particles, elemental carbon, and trace gases from the Kuwait oil fires  

SciTech Connect (OSTI)

Emission factors are presented for particles, elemental carbon (i.e., soot), total organic carbon in particles and vapor, and for various trace gases from the 1991 Kuwait oil fires. Particle emissions accounted for {approximately} 2% of the fuel burned. In general, soot emission factors were substantially lower than those used in recent {open_quotes}nuclear winter{close_quotes} calculations. Differences in the emissions and appearances of some of the individual fires are discussed. Carbon budget data for the composite plumes from the Kuwait fires are summarized; most of the burned carbon in the plumes was in the form of CO{sub 2}. Fluxes are presented for several combustion products. 26 refs., 1 fig., 5 tabs.

Laursen, K.K.; Ferek, R.J.; Hobbs, P.V. [Univ. of Washington, Seattle, WA (United States); Rasmussen, R.A. [Oregon Graduate Institute of Science and Technology, Beaverton, OR (United States)

1992-09-20T23:59:59.000Z

86

Environmental impact assessment of radionuclides and trace elements at the Kurday U mining site, Kazakhstan  

Science Journals Connector (OSTI)

The Kurday uranium mining site in Kazakhstan operated from 1954 to 1965 as part of the USSR nuclear weapon programme. To assess the environmental impact of radionuclides and trace elements associated with the Kurday mining site, field expeditions were performed in 2006. In addition to in situ gamma and 220Rn dose rate measurements, sampling included at site fractionation of water as well as sampling of water, fish, sediment, soils and vegetation. The concentrations of U and associated trace metals were enriched in the Pit Lake and in the artesian water (U exceeding the WHO guideline value for drinking water), and decreased downstream from the mining area. Uranium, As, Mo and Ni were predominantly present as mobile low molecular mass species in waters, while a significant proportion of Cr, Mn and Fe were associated with colloids and particles. Due to oxidation of divalent iron in the artesian ground water upon contact with air, Fe served as scavenger for other elements, and peak concentrations of U-, Ra-isotopes, As and Mn were seen. Most radionuclides and trace elements were contained in minerals in soils and sediments, and good correlations were obtained between U and As, Cd, Mo and 226Ra. Based on sequential extractions, a significant fraction of U, Pb and Cd could be considered mobile. Radioactive particles carrying significant amount of trace metals may represent a hazard during strong wind events. The transfer of radionuclides and metals from soils or sediments to water was in general low. The Kd levels varied with the element in question, ranging from 0.5 to 3נ102L/kg d.w. for 238U being relatively mobile, 103 for 226Ra, As, Cd, Ni, to 104L/kg d.w. for Cu, Cr and Pb being rather inert The transfer of radionuclides and metals from soils to vegetation (TF) was low, while higher if the transfer to vegetation, especially underwater mosses, occurred via water (e.g., BCF 37L/kg w.w. for 238U and 3נ103L/kg w.w. for 226Ra). The transfer of Cd, Pb and As from water to fish liver (BCF) was rather high, showing \\{BCFs\\} in the range of 102103L/kg w.w., and may, if eaten, represent a health risk. Furthermore, the high Hg level in fish filet reaching 0.3mg/kg w.w. muscle and the tendency of biomagnification call for dietary restrictions. Total gamma and Rn dose rate to man amounted to about 6mSv/y, while the highest calculated dose rate for non-human species based on the ERICA Assessment Tool were obtained in aquatic plants, with calculated mean doses of 700 ?Gy/hr, mostly due to the U exposure. Overall, it is concluded that measures such as restricted access to the Pit Lake as well as dietary restrictions with respect to drinking water and intake of fish should be taken to reduce the environmental risk to man and biota.

B. Salbu; M. Burkitbaev; G. Strmman; I. Shishkov; P. Kayukov; B. Uralbekov; B.O. Rosseland

2013-01-01T23:59:59.000Z

87

EDDY RESOLVING NUTRIENT ECODYNAMICS IN THE GLOBAL PARALLEL OCEAN PROGRAM AND CONNECTIONS WITH TRACE GASES IN THE SULFUR, HALOGEN AND NMHC CYCLES  

SciTech Connect (OSTI)

Ecodynamics and the sea-air transfer of climate relevant trace gases are intimately coupled in the oceanic mixed layer. Ventilation of species such as dimethyl sulfide and methyl bromide constitutes a key linkage within the earth system. We are creating a research tool for the study of marine trace gas distributions by implementing coupled ecology-gas chemistry in the high resolution Parallel Ocean Program (POP). The fundamental circulation model is eddy resolving, with cell sizes averaging 0.15 degree (lat/long). Here we describe ecochemistry integration. Density dependent mortality and iron geochemistry have enhanced agreement with chlorophyll measurements. Indications are that dimethyl sulfide production rates must be adjusted for latitude dependence to match recent compilations. This may reflect the need for phytoplankton to conserve nitrogen by favoring sulfurous osmolytes. Global simulations are also available for carbonyl sulfide, the methyl halides and for nonmethane hydrocarbons. We discuss future applications including interaction with atmospheric chemistry models, high resolution biogeochemical snapshots and the study of open ocean fertilization.

S. CHU; S. ELLIOTT

2000-08-01T23:59:59.000Z

88

Turtle With Mad Input (trace Unlimited Rays Through Lumped Elements) -- A Computer Program For Simulating Charged Particle Beam Transport Systems And Decay Turtle Including Decay Calculations  

E-Print Network [OSTI]

Turtle With Mad Input (trace Unlimited Rays Through Lumped Elements) -- A Computer Program For Simulating Charged Particle Beam Transport Systems And Decay Turtle Including Decay Calculations

Carey, D C

1999-01-01T23:59:59.000Z

89

Advanced byproduct recovery: Direct catalytic reduction of SO{sub 2} to elemental sulfur. First quarterly technical progress report, [October--December 1995  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation will be conducting Phase I of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. this catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria or zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an ongoing DOE-sponsored University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicates that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. the performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

Benedek, K. [Little (Arthur D.), Inc., Cambridge, MA (United States); Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States)

1996-02-01T23:59:59.000Z

90

Hydrogenase of the hyperthermophile Pyrococcus furiosus is an elemental sulfur reductase or sulfhydrogenase: evidence for a sulfur-reducing hydrogenase ancestor  

Science Journals Connector (OSTI)

...polysulfide reduction/geothermal biolog/evolution...appears to be an energy-conserving reaction...The publication costs of this article...sulfur-rich, geothermal environ- ments...fact, represent an energy- conserving reaction...the Department of Energy (FG09-88ER13901...

K Ma; R N Schicho; R M Kelly; M W Adams

1993-01-01T23:59:59.000Z

91

POSTER INSTRUCTIONS International Symposium on Trace Elements in Man & Animals (TEMA 15) June 22-26, 2014  

E-Print Network [OSTI]

POSTER INSTRUCTIONS 15th International Symposium on Trace Elements in Man & Animals (TEMA 15) June 22-26, 2014 Orlando, Florida The B Resort in Walt Disney Poster Specifications Posters as during lunches on Monday and Tuesday. Posters will be limited to 4 feet high x 3 feet wide (1.22M high x

Jawitz, James W.

92

Correlation of mineralogy and trace element leaching behavior in modified in situ spent shales from Logan Wash, Colorado  

SciTech Connect (OSTI)

Oil shale retorting induces mineral and chemical reactions to occur on the macroscopic and microscopic levels in the kerogen-bearing marlstone. The nature and extent of the reactions is dependent upon process variables such as maximum temperature, time at temperature, atmosphere, and raw shale composition. This report describes the investigation of the mineral, chemical, and trace element release properties of spent shales retrieved from an experimental in situ retort at Occidental Oil Shale, Inc.'s Logan Wash site in Garfield County, Colorado. Correlation between mineralogy of the spent materials and the mobility of major, minor, and trace elements are indicated, and relationships with important process parameters are discussed. The progress of carbonate decomposition reactions and silication reactions is indicative of the processing conditions experienced by the shale materials and influences the mobility of major, minor, and trace elements when the solids are contacted by water. Shale minerals that are exposed to the extreme conditions reached in underground retorting form high temperature product phases including akermanite-gehlenite and diopside-augite solid solutions, kalsilite, monticellite, and forsterie. The persistence of relatively thermally stable phases, such as quartz, orthoclase, and albite provide insight into the extremes of processing conditions experienced by the spent shales. Leachate compositions suggest that several trace elements, including vanadium, boron, fluoride, and arsenic are not rendered immobile by the formation of the high-temperature silicate product phase akermanite-gehlenite.

Peterson, E.J.; O'Rourke, J.A.; Wagner, P.

1981-01-01T23:59:59.000Z

93

Trace element and isotope geochemistry of geothermal fluids, East Rift Zone, Kilauea, Hawaii  

SciTech Connect (OSTI)

A research program has been undertaken in an effort to better characterize the composition and the precipitation characteristic of the geothermal fluids produced by the HGP-A geothermal well located on the Kilauea East Rift Zone on the Island of Hawaii. The results of these studies have shown that the chemical composition of the fluids changed over the production life of the well and that the fluids produced were the result of mixing of at least two, and possibly three, source fluids. These source fluids were recognized as: a sea water composition modified by high temperature water-rock reactions; meteoric recharge; and a hydrothermal fluid that had been equilibrated with high temperature reservoir rocks and magmatic volatiles. Although the major alkali and halide elements show clearly increasing trends with time, only a few of the trace transition metals show a similar trend. The rare earth elements, were typically found at low concentrations and appeared to be highly variable with time. Studies of the precipitation characteristics of silica showed that amorphous silica deposition rates were highly sensitive to fluid pH and that increases in fluid pH above about 8.5 could flocculate more than 80% of the suspended colloidal silica in excess of its solubility. Addition of transition metal salts were also found to enhance the recovery fractions of silica from solution. The amorphous silica precipitate was also found to strongly scavenge the alkaline earth and transition metal ions naturally present in the brines; mild acid treatments were shown to be capable of removing substantial fractions of the scavenged metals from the silica flocs yielding a moderately pure gelatinous by-product. Further work on the silica precipitation process is recommended to improve our ability to control silica scaling from high temperature geothermal fluids or to recover a marketable silica by-product from these fluids prior to reinjection.

West, H.B.; Delanoy, G.A.; Thomas, D.M. (Hawaii Univ., Honolulu, HI (United States). Hawaii Inst. of Geophysics); Gerlach, D.C. (Lawrence Livermore National Lab., CA (United States)); Chen, B.; Takahashi, P.; Thomas, D.M. (Hawaii Univ., Honolulu, HI (United States) Evans (Charles) and Associates, Redwood City, CA (United States))

1992-01-01T23:59:59.000Z

94

Distribution of arsenic, selenium, and other trace elements in high pyrite Appalachian coals: Evidence for multiple episodes of pyrite formation  

Science Journals Connector (OSTI)

Pennsylvanian coals in the Appalachian Basin host pyrite that is locally enriched in potentially toxic trace elements such as As, Se, Hg, Pb, and Ni. A comparison of pyrite-rich coals from northwestern Alabama, eastern Kentucky, and West Virginia reveals differences in concentrations and mode of occurrence of trace elements in pyrite. Pyrite occurs as framboids, dendrites, or in massive crystalline form in cell lumens or crosscutting veins. Metal concentrations in pyrite vary over all scales, from microscopic to mine to regional, because trace elements are inhomogeneously distributed in the different morphological forms of pyrite, and in the multiple generations of sulfide mineral precipitates. Early diagenetic framboidal pyrite is usually depleted in As, Se, and Hg, and enriched in Pb and Ni, compared to other pyrite forms. In dendritic pyrite, maps of As distribution show a chemical gradient from As-rich centers to As-poor distal branches, whereas Se concentrations are highest at the distal edges of the branches. Massive crystalline pyrite that fills veins is composed of several generations of sulfide minerals. Pyrite in late-stage veins commonly exhibits As-rich growth zones, indicating a probable epigenetic hydrothermal origin. Selenium is concentrated at the distal edges of veins. A positive correlation of As and Se in pyrite veins from Kentucky coals, and of As and Hg in pyrite-filled veins from Alabama coals, suggests coprecipitation of these elements from the same fluid. In the Kentucky coal samples (n=18), As and Se contents in pyrite-filled veins average 4200ppm and 200ppm, respectively. In Alabama coal samples, As in pyrite-filled veins averages 2700ppm (n=34), whereas As in pyrite-filled cellular structures averages 6470ppm (n=35). In these same Alabama samples, Se averages 80ppm in pyrite-filled veins, but was below the detection limit in cell structures. In samples of West Virginia massive pyrite, As averages 1700ppm, and Se averages 270ppm (n=24). The highest concentration of Hg (?102ppm) is in Alabama pyrite veins. Improved detailed descriptions of sulfide morphology, sulfide mineral paragenesis, and trace-element concentration and distribution allow more informed predictions of: (1) the relative rate of release of trace elements during weathering of pyrite in coals, and (2) the relative effectiveness of various coal-cleaning procedures of removing pyrite. For example, trace element-rich pyrite has been shown to be more soluble than stoichiometric pyrite, and fragile fine-grained pyrite forms such as dendrites and framboids are more susceptible to dissolution and disaggregation but less amenable to removal during coal cleaning.

S.F. Diehl; M.B. Goldhaber; A.E. Koenig; H.A. Lowers; L.F. Ruppert

2012-01-01T23:59:59.000Z

95

doi:10.1016/j.gca.2004.06.037 Effect of melt composition on the partitioning of trace elements  

E-Print Network [OSTI]

coefficients for the rare earth elements and for Th, Nb, and Ta reveal a strong influence of melt composition amounts of rare earth elements (REE) and high field strength elements (HFSE), it may significantly affectdoi:10.1016/j.gca.2004.06.037 Effect of melt composition on the partitioning of trace elements

96

Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia  

SciTech Connect (OSTI)

The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn in the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.

Vukasinovic-Pesic, V.; Rajakovic, L.J. [University of Montenegro, Podgorica (Montenegro)

2009-07-01T23:59:59.000Z

97

Observations on the incorporation of trace elements in halite of Oligocene salt beds, Bourg-en-Bresse Basin, France  

SciTech Connect (OSTI)

It is common practice to employ trace elements found in chloride salts as indicators of the conditions of deposition. Because some halite contains abundant fluid inclusions, it is necessary to separate the salt from the inclusions before analysis. This study presents the data derived from the use of a simple preparative technique which permits analysis of the trace elements in solid halite, and provides a guide to test the success in elimination of the contaminants contained in the fluid inclusions. The differentiation is accomplished simply by crushing the salt in alcohol followed by separate analysis of the fluid and solid components, thus yielding accurate trace element concentrations in the solids (crystal lattice, dislocations, and grain boundaries) and the fluids. Br and K are present both in the solid and liquid phases of the halite, but Mg is exclusively in the fluid inclusions. The elimination of the Mg from the analysis of the solid phase may thus be employed as a monitor to indicate the degree of purification of the samples being analyzed.

Moretto, R. (Universite de Nancy I, Vandoeuvre-les-Nancy (France))

1988-12-01T23:59:59.000Z

98

Washability of trace elements in product coals from Illinois mines. Technical report, September 1--November 30, 1993  

SciTech Connect (OSTI)

The existing trace element washability data on Illinois coals are based on float-sink methods, and these data are not applicable to modern froth flotation or column flotation processes. Particularly, there is a lack of washability data on samples from modern preparation plants, as well as other product (as-shipped) coals. The goal of this project is to provide the needed trace element washability data on as-shipped coals that were collected during 1992--1993 from Illinois mines. The results generated by this project will promote Illinois coals for such prospective new markets as feed materials for advanced gasification processes, for synthetic organic chemicals, and to meet new environmental requirements for their use in utility steam generation. During the first quarter, each of 34 project samples were ground to about {approximately}100 mesh size and cleaned by use of a special froth flotation technique (release analysis). The flotation products were analyzed for ash, moisture, and heating value (BTU). The data were then used to construct a series of different-washability curves. For example, these curves can show variation in BTU or combustible recovery as a function of the amount of ash or S rejected, or as a function of the weight of the flotation products. From the relationship between %cumulative BTU and %cumulative weight, nine composite samples each having 80% of the total BTU were prepared from the individual flotation products and submitted for trace element analysis.

Demir, I.; Ruch, R.R.; Harvey, R.D.; Steele, J.D. [Illinois Dept. of Energy and Natural Resources, Springfield, IL (United States). Geological Survey

1993-12-31T23:59:59.000Z

99

Method for quantitative determination and separation of trace amounts of chemical elements in the presence of large quantities of other elements having the same atomic mass  

DOE Patents [OSTI]

Photoionization via autoionizing atomic levels combined with conventional mass spectroscopy provides a technique for quantitative analysis of trace quantities of chemical elements in the presence of much larger amounts of other elements with substantially the same atomic mass. Ytterbium samples smaller than 10 ng have been detected using an ArF* excimer laser which provides the atomic ions for a time-of-flight mass spectrometer. Elemental selectivity of greater than 5:1 with respect to lutetium impurity has been obtained. Autoionization via a single photon process permits greater photon utilization efficiency because of its greater absorption cross section than bound-free transitions, while maintaining sufficient spectroscopic structure to allow significant photoionization selectivity between different atomic species. Separation of atomic species from others of substantially the same atomic mass is also described.

Miller, C.M.; Nogar, N.S.

1982-09-02T23:59:59.000Z

100

Production of elemental sulfur and ammonium thiosulfate by the oxidation of H2S containing water vapor and ammonia over V/Zr-PILC catalysts  

Science Journals Connector (OSTI)

The catalytic oxidation of hydrogen sulfide in the presence of water and ammonia was studied over V2O5 supported on Zr-pillared clay catalysts (V/Zr-PILCs). The synthesized catalysts were examined using a variety of characterization techniques. A catalytic performance study using V/Zr-PILC catalysts showed that H2S was successfully converted to elemental sulfur and ammonium thiosulfate (ATS) without considerable emission of sulfur dioxide. The H2S conversion over V/Zr-PILCs increased with increasing the content of vanadia up to 6wt.%. This superior catalytic performance might be related to the uniform dispersion of vanadia species on the Zr-PILC support.

Kanattukara Vijayan Bineesh; Moon-il Kim; Goo-Hwa Lee; Manickam Selvaraj; Kyu Hyun; Dae-Won Park

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Comparative bioaccumulation of trace elements between Nautilus pompilius and N.1 macromphalus (Cephalopoda: Nautiloidea) from Vanuatu and New-Caledonia2  

E-Print Network [OSTI]

clearly highlighted that the digestive gland32 played a key role in the bioaccumulation and storage of Ag are exposed to trace elements that are present in their diet and dissolved in49 seawater. This double exposure bioavailability of53 the metal in diet and seawater (Rainbow and Wang, 2001). Comparative analysis of trace54

Paris-Sud XI, Université de

102

Microbial transformations of sulfur compounds  

Science Journals Connector (OSTI)

Oct 13, 1978 ... tains a large part of the chemical energy transferred ... ical energy is partly preserved in the bio- mass of .... ethanol to remove elemental sulfur.

2000-01-10T23:59:59.000Z

103

Trace element partitioning between apatite and silicate melts Stefan Prowatke a,1  

E-Print Network [OSTI]

). The experiments were conducted at pressures of 1.0 GPa and temperatures of 1250 °C. The rare earth elements (La polymerisation of the melt, apatite/melt partition coefficients for the rare earth elements increase for about occurring apatites contain large amounts of the rare earth elements and Sr, it has been well known

104

Precise lattice location of trace elements within minerals and at their surfaces with x?ray standing waves (abstract)  

Science Journals Connector (OSTI)

Using x?ray standing waves (XSW) generated by dynamical Bragg diffraction we have precisely measured lattice locations of trace elements within and at the surface of mineral single crystals. Natural calcite samples were cleaved along the (1014) plane to obtain pristine surfaces. After cleavage some samples were reacted with a dilute aqueous Pb solution to obtain Pb?sorbed surfaces. XSW measurements were then performed on both unreacted and reacted samples using the calcite (1014) Bragg reflection. Results of these XSW measurements show that the naturally occurring trace element M substitutes for C. On the Pb?reacted calcite sample Pb was located on the calcite (1014) lattice plane where C atoms also reside. Our measurements clearly demonstrate a new and powerful application of synchrotron radiation in earth and environmental sciences to provide element?specific atomic?scale structural information within and at the surface of minerals. The XSW measurements were made at the NSLS X15A and X25 beamlines.

Y. Qian

1996-01-01T23:59:59.000Z

105

Effect of Various Ions, pH, and Osmotic Pressure on Oxidation of Elemental Sulfur by Thiobacillus thiooxidans  

Science Journals Connector (OSTI)

...powdered sulfur added in large excess made cells sometimes less responsive...only partially (S0/DMSO). Lithium chloride was even more inhibitory...shown), sodium chloride and lithium chloride were no longer inhibitory...of potassium, sodium, or lithium chloride (left); potassium...

Isamu Suzuki; Douglas Lee; Byron Mackay; Lesia Harahuc; Jae Key Oh

1999-11-01T23:59:59.000Z

106

Effect of agricultural use of phosphogypsum on trace elements in soils and vegetation  

Science Journals Connector (OSTI)

The problem of the disposal of phosphogypsum, one of the main industrial wastes of phosphorus fertilizer production, is reviewed, from the point of view of element pollution of phosphate raw materials, when it is introduced to soil. When phosphogypsum from different phosphorus producing plants in the USSR is used in agriculture, the main element-pollutants are fluorine, sulphur, strontium and rare earth elements. Their concentration in soils and vegetation exceeds Clark values by 20100 times. The necessity for complex biogeochemical investigations to identify the hazards from these chemical elements in the environment is discussed.

A.V. Gorbunov; M.V. Frontasyeva; S.F. Gundorina; T.L. Onischenko; B.B. Maksjuta; Chen Sen Pal

1992-01-01T23:59:59.000Z

107

ADVANCED SULFUR CONTROL CONCEPTS  

SciTech Connect (OSTI)

Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

2003-01-01T23:59:59.000Z

108

Trace Elemental Variation in Dosidicus Gigas Statoliths Using LA-ICP-MS  

E-Print Network [OSTI]

classified as distinct group for the first time using these methods. Elemental fingerprint signatures were found to be significantly different at multiple ontogenic growth regions of the statolith. Seattle and California paralarvae exhibited similar...

Arbuckle, Nancy 1980-

2012-08-24T23:59:59.000Z

109

The distribution and association of trace elements in the bitumen, kerogen and pyrolysates from New Albany oil shale  

SciTech Connect (OSTI)

The distribution and association of trace elements in bitumen, kerogen and pyrolysates from New Albany oil shale were investigated using instrumental neutron activation analysis (INAA), x-ray diffraction (XRD), electron microprobe x-ray fluorescence (EMP-XRF), liquid chromatography, ultra-violet spectroscopy and mass spectrometry. The kerogen was found to contain several HCl/HF resistant minerals (determined by XRD), including pyrite, marcasite, chalcopyrite, rutile, and anatase, and the neoformed mineral ralstonite. Kerogens (prepared at UNOCAL, CA) which were fractionated in an aqueous ZnBr[sub 2] solution were found to contain [approximately]20% less acid-resistant minerals than traditional' HCl/HF isolated kerogens and were contaminated with Zn and Br. Kerogens (prepared at the University of Munich) treated with SnCl[sub 2]/H[sub 3]PO[sub 4] at 150-270[degrees]C (Kiba) and/or SnCl[sub 2]/HCl at 110[degrees]C were found to contain <10% of their original pyrite/marcasite (FeS[sub 2]), but were contaminated with large amounts of Sn. The Kiba treatment also appeared to demetallate Ni(II) and VO(II) porphyrins. The inorganic and organic associations of trace elements in New Albany kerogen were studied by analysis of kerogen fractions and a mineral residue ([approximately]85% FeS[sub 2]) obtained through density separations. The degree of association of several elements (As, Co, Mn, Mo, Ni, Sb, and Se) with FeS[sub 2] was determined through the analysis of individual mineral grains by EMP-XRF and by analysis of the mineral residue treated with dilute HNO[sub 3] to remove FeS[sub 2]. These studies indicated that essentially all of the V and [approximately]95% of the Ni present in New Albany kerogen is organically associated. Methods which are designed to account for the inorganic associations of trace elements in kerogens, including methods based on physical methods of separation, chemical removal of FeS[sub 2], EMP-XRF and low temperature ashing, are compared.

Mercer, G.E.

1992-01-01T23:59:59.000Z

110

Long-term leaching of trace elements in a heavily sludge-amended silty clay loam soil  

SciTech Connect (OSTI)

Analysis by ICP-MS of shallow groundwater collected at a field site in New York that had been heavily loaded with sewage sludge more than 15 years earlier revealed elevated concentrations of Cu, Zn, Sr, Rb, Mo, Cd, As, Cr, Ni, Sb, W, Ag, Hg, and Sn compared with a nearby control site. Enhanced leaching of some elements from this near-neutral, fine-textured (silty clay loam) soil could be explained by exchange of soil-bound elements by components of the added sludge. For most of the heavy metals, however, increased leaching was a response to the high metal loadings in the soil, probably facilitated by higher dissolved organic matter in the leachate. Laboratory-determined distribution coefficients, K{sub D}, for the metals in newly prepared sludge/soil mixtures were lower than K{sub D} values of the field-aged sludge-treated soil, suggesting that metal mobility may have been substantially higher shortly after sludge application than many years later. Cumulative losses of certain trace elements from the topsoil have been estimated relative to Cr, a comparatively immobile element. These suggest that relative long-term losses range from 20 to 80%, with the order being: Sr, Mo, Sb {gt} Ni, Cd, Cu {gt} Zn, Ag. Generally, those elements with the smallest K{sub D} values (most soluble) measured recently in the soil had the largest loss estimates. However, present leaching loss rates are too slow to explain the estimated relative losses of several of these elements from the topsoil over the 15 or more years since sludge application.

McBride, M.B.; Richards, B.K.; Steenhuis, T.; Spiers, G.

1999-09-01T23:59:59.000Z

111

Measurement of particulate matter and trace elements from a coal-fired power plant with electrostatic precipitators equipped the low temperature economizer  

Science Journals Connector (OSTI)

Abstract The particulate matter and trace elements from a 660MW coal-fired power plant boiler which equipped with a novel electrostatic precipitator were sampled and analyzed. To promote the thermal efficiency of power plants, a low temperature economizer was installed at the inlet of electrostatic precipitator to collect the heat generated from flue gas. The low temperature economizer can reduce flue gas temperature, and then affect the operation of electrostatic precipitator. Therefore, this experiment was carried out to investigate the collection characteristics of this novel electrostatic precipitator on particulate matter. In addition, the distribution of trace elements in solid combustion residues was also studied. The results indicate that the low temperature economizer can markedly decrease the amount of particulate matter at the outlet of electrostatic precipitator. The collection efficiency of electrostatic precipitator on particulate matter is significantly improved by the low temperature economizer, whereby the collection efficiencies of PM2.5 and PM1.0 can reach 99.7% and 99.2%, respectively. Most of the trace elements remain in the fly ash collected by the electrostatic precipitator, and less than 10% remain in the bottom ash, but very rare emit from the electrostatic precipitator. The low temperature economizer not only reduces the emission of particulate matter, but also diminishes the emissions of trace elements in flue gas. The enrichment characteristics of trace elements in submicron particles were also studied.

Chao Wang; Xiaowei Liu; Dong Li; Junping Si; Bo Zhao; Minghou Xu

2014-01-01T23:59:59.000Z

112

Bacterial Sulfur Storage Globules  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by I. J. Pickering and G. N. George by I. J. Pickering and G. N. George Sulfur is essential for all life, but it plays a particularly central role in the metabolism of many anaerobic microorganisms. Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for use when food is in short supply (Fig. 1). The chemical nature of the sulfur in these globules has been an enigma since they were first described as far back as 1887 (1); all known forms (or allotropes) of elemental sulfur are solid at room temperature, but globule sulfur has been described as "liquid", and it apparently has a low density – 1.3 compared to 2.1 for the common yellow allotrope a-sulfur. Various exotic forms of sulfur have been proposed to explain these properties, including micelles (small bubble-like structures) formed from long-chain polythionates, but all of these deductions have been based upon indirect evidence (for example the density was estimated by flotation of intact cells), and many questions remained.

113

Trace element chemistry of Apollo 14 lunar soil from Fra Mauro  

Science Journals Connector (OSTI)

Analytical data are presented for Apollo 14 fines ( Mauro Formation, possessed high concentrations (100200 chondrites) for many elements, prior to the excavation of the mare basins. A correlation may exist between Gd/Eu and Zr/Hf ratios in lunar materials.

S.R. Taylor; Patricia Muir; Maureen Kaye

1971-01-01T23:59:59.000Z

114

Association of trace elements with mineral species in the New Albany oil shale  

SciTech Connect (OSTI)

X-Ray diffraction (XRD), electron microprobe (EMP), scanning electron microscopy (SEM) and neutron activation analysis (NAA) were used to identify mineral species in the New Albany shale and kerogen isolates. Elemental abundances were determined by NAA and distributions of Ni, V, As, and other elements with-in mineral grains were determined by EMP-XRF. Vanadium in the New Albany shale was found to be associated primarily with clay minerals (illite, montmorrillonite). In the New Albany kerogen, Ni and V were shown to be predominantly associated with the organic matrix. Pyrite (and/or marcasite) was shown to occur in two forms, a euhedral variety and as framboidal clusters. The Ni content of the framboidal variety was found to be higher than that of the euhedral pyrite.

Fitzgerald, S.L.; Day, J.W.; Mercer, G.E.; Filby, R.H. (Washington State Univ., Pullman (USA))

1989-03-01T23:59:59.000Z

115

Determination of selected trace elements in human head hair by neutron activation analysis  

E-Print Network [OSTI]

the scope of this discussion. The final category of data contains barium and strontium. There was no data in the literature to use as a comparison, therefore the values of 49 ppm for barium and 87 ppm for strontium must stand on their own merit...) in Japan and of course, the current work in Texas. The results of the correlation analysis were that there were no significant correlations between any of the elements except in the case of strontium and barium which yielded a Pearson correlation coef...

Courson, Leonard Austin

2012-06-07T23:59:59.000Z

116

Multiple stirred-flow chamber assembly for simultaneous automatic fractionation of trace elements in fly ash samples using a multisyringe-based flow system  

SciTech Connect (OSTI)

There is a current trend in automation of leaching tests for trace elements in solid matrixes by use of flow injection based column approaches. However, as a result of the downscaled dimensions of the analytical manifold and execution of a single extraction at a time, miniaturized flow-through column approaches have merely found applications for periodic investigations of trace element mobility in highly homogeneous environmental solids. A novel flow-based configuration capitalized on stirred-flow cell extraction is proposed in this work for simultaneous fractionation of trace elements in three solid wastes with no limitation of sample amount up to 1.0 g. A two-step sequential extraction scheme involving water and acetic acid (or acetic acid/acetate buffer) is utilized for accurate assessment of readily mobilizable fractions of trace elements in fly ash samples. The W automated extraction system features high tolerance to flow rates ({<=} 6 mL min{sup -1}) and, as opposed to operationally defined batchwise methods, the solid to liquid ratio is not a critical parameter for, determination of overall readily leachable trace elements provided that exhaustive extraction is ensured. Analytical performance of the dynamic extractor is evaluated for fractionation analysis of a real coal fly ash and BCR-176R fly ash certified reference material. No significant differences were found at the 0.05 significance level between summation of leached concentrations in each fraction plus residue and concentration values of BCR-176R, thus revealing the accuracy of the automated method. Overall extractable pools of trace metals in three samples are separated in less than 115 min, even for highly contaminated ashes, versus 18-24 h per fraction in equilibrium leaching tests. The multiple stirred-flow cell assembly is thus suitable for routine risk assessment studies of industrial solid byproduct.

Boonjob, W.; Miro, M.; Cerda, V. [Mahidol University, Bangkok (Thailand). Faculty of Science

2008-10-01T23:59:59.000Z

117

Changes in trace element contents in ashes of oil shale fueled PF and CFB boilers during operation  

Science Journals Connector (OSTI)

Abstract Two oil shale combustion technologies, pulverized firing (PF) and circulated fluidized bed (CFB) were compared with respect to partitioning of selected elements (Ba, Cd, Co, Cr, Cu, Hg, Mn, Mo, Ni, Pb, Rb, Sb, Sn, Sr, Th, Tl, U, V, and Zn) in the ashes along the flue gas ducts. The ash samples were characterized by high-resolution ICP-MS. The average contents of toxic heavy metals in fly ash samples from the CFB boiler are lower compared to the PF boiler. Main differences in trace element contents between combustion technologies were as follows: Cd content in the fly ash samples of PF boiler was up to 0.9mg/kg while in CFB boiler it remained below 0.1mg/kg in all analyzed ash samples; Hg was observed in the ashes of electrostatic precipitator (ESP) of CFB boiler while in the PF boiler it was close to or below detection limit. In the PF boiler content of Sn was detected only in the ashes of ESPs, while in CFB boiler it was evenly distributed between bottom and fly ash samples. Highest content among heavy metals in ash samples was observed for Pb in the last field of ESP of the PF boiler (142mg/kg).

Janek Reinik; Natalya Irha; Eiliv Steinnes; Gary Urb; Jekaterina Jefimova; Eero Piirisalu; Jri Loosaar

2013-01-01T23:59:59.000Z

118

Simultaneous mobilization of trace elements and polycyclic aromatic hydrocarbon (PAH) compounds from soil with a nonionic surfactant and [S,S]-EDDS in admixture: Metals  

Science Journals Connector (OSTI)

This study evaluated the efficacy of soil washing with a nonionic surfactant (Brij98) in combination with a complexing reagent (ethylenediaminedisuccinic acid, [S,S]-EDDS) for the simultaneous mobilization of macro- and trace elements (MTEs) and PAH compounds from a field-contaminated soil. Soil fractionation studies indicated that an appreciable fraction of the Al, Ca, Cu, Fe and Mn was associated with the residual fraction but that much of the other trace elements (As, Cd, Cr, Ni, Pb and Zn) might be susceptible to soil washing. Ultrasonically aided mixing of the field contaminated soil with Brij98 and a sparing quantity (2mmol) of [S,S]-EDDS, simultaneously mobilized virtually all of the benzo[?]pyrene {B(a)P} and chrysene (CRY) and appreciable quantities of the trace elements (Cd, Cr, Mn, Ni, Pb, Zn) burdens. The recovery of both \\{PAHs\\} and trace elements were increased from the soil organic matter (SOM)-rich soil. This report concerns the fate of \\{MTEs\\} during soil washing. Multiple ultra-sonically aided washes (five or nine) with the same dosage of reagents mobilized virtually all of \\{PAHs\\} and decreased the levels of Cd, Cr, Ni, Pb and Zn to comply with recommended maxima. By contrast, the levels of As and Cu remained excessive after the treatments.

Yuexiang Wen; William D. Marshall

2011-01-01T23:59:59.000Z

119

TTG magmatism in the Congo craton; a view from major and trace element geochemistry, RbSr and SmNd systematics: case  

E-Print Network [OSTI]

TTG magmatism in the Congo craton; a view from major and trace element geochemistry, Rb­Sr and Sm of the Sangmelima region (Ntem complex, Congo craton) in southern Cameroon range in modal composition from rocks. TTG intrusions in the Sangmelima region represent a major Archaean accretion event in the Congo craton

Siebel, Wolfgang

120

The evolution of a complex type B allende inclusion: An ion microprobe trace element study  

SciTech Connect (OSTI)

USNM 5241 is a Type B1 refractory inclusion from Allende, first described by El Goresy et al. (1985), that consists of a 1.2 mm-thick melilite-rich and spinel-poor mantle enclosing a 0.6 cm-radius spinel-rich core; the inclusion contains xenoliths of spinel-free fassaite {plus minus} melilite {plus minus} anorthite incorporated within the spinel-rich core. Detailed ion microprobe analyses of individual phases in 5241 show that the rare earth element (REE) concentrations in mantle melilite vary irregularly with increasing distance from the rim of the inclusion, at first decreasing immediately below the rim and then remaining constant between {approximately}0.4 and 1.0 mm. More than 1.0 mm from the rim, the REE concentrations again decrease. Although counterintuitive in the context of traditional fractional crystallization models, these REE variations are in fact broadly consistent with such a model in light of recent experimental measurements of D{sub REE3+ (mel)}, that show a strong inverse correlation of D with the akermanite content of the melilite. Local variations, over distances of <20 {mu}m, in the akermanite content of mantle melilite--as much as 5-10 mol% Ak--with accompanying fluctuations in REE contents, are due to reaction of gehlenitic melilite with tiny inclusions of fassaite, producing narrow zones of more akermanitic melilite surrounding more fassaitic pyroxene. The authors interpret 5241 as having formed largely by fractional crystallization during the first {approximately}40% of its solidification; this was followed by fractional crystallization + xenolith assimilation during the last 60%.

MacPherson, G.J. (Smithsonian Institution, Washington, DC (USA)); Crozaz, G.; Lundberg, L.L. (Washington Univ., St. Louis, MO (USA))

1989-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Telling friends from foes : strontium isotope and trace element analysis of companion burials from Pusilh, Toledo District, Belize  

E-Print Network [OSTI]

uranium, and the rare earth elements (REE) can readilyof uranium and the rare earth elements are extremely low andconsumed in vivo. The rare earth element lanthanum, like

Somerville, Andrew D.

2010-01-01T23:59:59.000Z

122

Electrostatic Precipitator Collection Efficiency and Trace Element Emissions from Co-Combustion of Biomass and Recovered Fuel in Fluidized-Bed Combustion  

Science Journals Connector (OSTI)

Electrostatic Precipitator Collection Efficiency and Trace Element Emissions from Co-Combustion of Biomass and Recovered Fuel in Fluidized-Bed Combustion ... In this investigation, electrostatic precipitator fractional collection efficiency and trace metal emissions were determined experimentally at a 66 MW biomass-fueled bubbling fluidized-bed combustion plant. ... The solid fuel combustion-generated particle emissions typically consist of two types of particles:? fine particles approximately 0.1?1 ?m in diameter that are formed from the ash-forming species that are volatilized during combustion and residual ash particles larger than 1 ?m in diameter that are formed from mineral impurities in the fuels (4). ...

Terttaliisa Lind; Jouni Hokkinen; Jorma K. Jokiniemi; Sanna Saarikoski; Risto Hillamo

2003-05-08T23:59:59.000Z

123

PCB, PAH and trace element exposure in barn swallows nesting on the Grand Calumet River, IN, watershed  

SciTech Connect (OSTI)

The Grand Calumet River/Indiana Harbor Canal (GCR/IHC) is an International Joint Commission Area of Concern (AOC) and is heavily contaminated with polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and trace elements. Barn swallow hatchlings and nestlings were collected from four bridges which span the GCR/IHC and a reference location. PCB and PAH concentrations in hatchlings and nestlings were significantly higher in colonies along the GCR/IHC than the reference colony. For example, mean PCB concentrations in hatchlings and nestlings were significantly higher in colonies along the GCR/IHC than the reference colony. For example, mean PCB concentrations in hatchlings were 0.04 {micro}g/g wet weight at the reference colony and 20.42 {micro}g/g at one colony on the GCR/IHC; mean concentrations of PAHs were 0.05 {micro}g/g at the reference colony and 0.15 {micro}g/g at one colony on the GCR/IHC. PCBs accumulated in nestlings at a rate of 18.2 {micro}g/day at one colony on the GCR/IHC compared to 0.03 {micro}g/day at the reference colony. These data suggest that contaminants in the water and sediment of the GCR/IHC are being incorporated into the vertebrate food chain via aquatic insects. Because the contaminant data in the barn swallow hatchlings and nestlings seem to reflect the sediment chemistry nearby the colony, this study suggests that barn swallows are a useful biomonitoring species for this AOC.

Custer, T.W.; Sparks, D.W. [National Biological Service, La Crosse, WI (United States). Upper Mississippi Science Center; [Fish and Wildlife Service, Bloomington, IN (United States)

1995-12-31T23:59:59.000Z

124

Why Sequence Sulfur-Oxidizing Bacteria?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sulfur-Oxidizing Bacteria? Sulfur-Oxidizing Bacteria? Several environmental problems, such as acid rain, biocorrosion, etc., are caused by sulfur compounds, such as sulfur dioxide (SO2) and hydrogen sulfide (H2S). A sustainable process to remove these sulfur compounds is the production of elemental sulfur from H2S-containing gas streams by the use of sulfide-oxidizing bacteria. In this process, H2S is absorbed into the alkaline solution in the scrubber unit, followed by the biological oxidation of H2S to elemental sulfur and the recycling of water. With this two-step process, a variety of gas streams (i.e., natural gas, synthesis gas, biogas, and refinery gas) can be treated. For the treatment of sulfate-containing waste streams, an extra step has to be introduced: the transformation of sulfate into H2S by sulfate-reducing bacteria. In

125

Sulfur: its clinical and toxicologic aspects  

Science Journals Connector (OSTI)

Although there is no known dietary requirement for inorganic sulfur, it is an essential element for all animal species in as much as they all require the sulfur-containing amino acid methionine. There are three predominate forms of organic sulfur in animals and humans: 1) the thiomethyl of methionine residues in protein; 2) the sulfhydryl disulfides of protein; and 3) the compounds containing ester or amide bound sulfates of glycosaminoglycans, steroids, and many xenobiotic metabolites. Thus, sulfur becomes an important constituent of amino acids, proteins, enzymes, vitamins and other biomolecules. Unlike mammalian species, plants can use inorganic sulfur and synthesize methionine from which are synthesized all the other important sulfur compounds. Hence, sulfur deficiency occurs mainly when plants are grown in sulfur-depleted soils and when humans and animals consume low-protein diets. In recent times, however, the increasing prevalence of refining petroleum and smelting sulfur compounds of metallic minerals into free metals are having a large impact on the balance of sulfur in the environment. Sulfur toxicity is associated mainly with high levels of the element and its toxic volatile substances in the environment. Sulfur dioxide (SO2), a major air pollutant, may adversely affect animal and human health by causing bronchitis, bronchoconstriction, and increased pulmonary resistance.

Lioudmila A Komarnisky; Robert J Christopherson; Tapan K Basu

2003-01-01T23:59:59.000Z

126

Economic feasibility of biochemical processes for the upgrading of crudes and the removal of sulfur, nitrogen, and trace metals from crude oil -- Benchmark cost establishment of biochemical processes on the basis of conventional downstream technologies. Final report FY95  

SciTech Connect (OSTI)

During the past several years, a considerable amount of work has been carried out showing that microbially enhanced oil recovery (MEOR) is promising and the resulting biotechnology may be deliverable. At Brookhaven National Laboratory (BNL), systematic studies have been conducted which dealt with the effects of thermophilic and thermoadapted bacteria on the chemical and physical properties of selected types of crude oils at elevated temperatures and pressures. Current studies indicate that during the biotreatment several chemical and physical properties of crude oils are affected. The oils are (1) emulsified; (2) acidified; (3) there is a qualitative and quantitative change in light and heavy fractions of the crudes; (4) there are chemical changes in fractions containing sulfur compounds; (5) there is an apparent reduction in the concentration of trace metals; and (6) the qualitative and quantitative changes appear to be microbial species dependent; and (7) there is a distinction between biodegraded and biotreated oils. The downstream biotechnological crude oil processing research performed thus far is of laboratory scale and has focused on demonstrating the technical feasibility of downstream processing with different types of biocatalysts under a variety of processing conditions. Quantitative economic analysis is the topic of the present project which investigates the economic feasibility of the various biochemical downstream processes which hold promise in upgrading of heavy crudes, such as those found in California, e.g., Monterey-type, Midway Sunset, Honda crudes, and others.

Premuzic, E.T.

1996-08-01T23:59:59.000Z

127

E-Print Network 3.0 - aqueous sulfuric acid Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TRACE ATMOSPHERIC CONSTITUENTS Summary: . Reactions of Sulfur(IV) with Transition-Metal Ions in Aqueous Solutions Robert E. Huie and Norman C... . Peterson 3. Catalytic...

128

E-Print Network 3.0 - aqueous organic sulfur Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TRACE ATMOSPHERIC CONSTITUENTS Summary: . Reactions of Sulfur(IV) with Transition-Metal Ions in Aqueous Solutions Robert E. Huie and Norman C... . Peterson 3. Catalytic...

129

Trace elements found in the fuel and in-furnace fine particles collected from 80MW BFB combusting solid recovered fuel  

Science Journals Connector (OSTI)

The main fine particle (dpSRF) combustion the main elements were found to be: Ba, Br, Cr, Cu, Fe, Pb, Sb, Sn and Zn. Fine particle composition is presented for 6 different furnace heights of a bubbling fluidized bed (BFB) boiler. As the fine particles are formed of vaporized ash species the experimental results are discussed with the support of thermodynamic equilibrium modeling for estimating the forms of the gaseous elements in the furnace. The occurrence of bromine was found to be similar to chlorine as the main forms of bromine in the furnace were estimated to be KBr(g) and NaBr(g) complemented with CuBr3(g). It is proposed that the trace elements mentioned originate mainly from plastics and rubber where they are used as production additives, stabilisers, dyes, colorants and flame retardants. Cr, Cu and Zn may originate to a large extent from alloys and other metallic impurities. SEM-EDS analyses carried out for the SRF supports the postulated origin of the elements.

P. Vainikka; D. Lindberg; A. Moilanen; H. Ollila; M. Tiainen; J. Silvennoinen; M. Hupa

2013-01-01T23:59:59.000Z

130

Thermodynamic evaluation of the compounds of gold, silver, and other trace elements formed upon the combustion of brown coal  

Science Journals Connector (OSTI)

The thermodynamically most probable main compounds of Ag, Au, Ge, Se, Sr, U, and ash-forming elements formed upon the combustion of brown coal, which was close in the composition of organic and mineral matter ...

M. Ya. Shpirt; A. A. Lavrinenko; I. N. Kuznetsova

2013-09-01T23:59:59.000Z

131

PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT  

E-Print Network [OSTI]

elements. Over 25% of the raw shale gas five groups productsthe oil, in the raw oil shale gas, consequence of retortinggood product raw oil shale and input gases that is accounted

Fox, J. P.

2011-01-01T23:59:59.000Z

132

Trace element disequilibria and magnesium isotope heterogeneity in 3655A: Evidence for a complex multi-stage evolution of a typical Allende Type B1 CAI  

SciTech Connect (OSTI)

We used the Panurge ion microprobe to measure concentrations of the rare earth elements (REEs), Ba, Hf, and Sr in melilite, clinopyroxene. plagioclase, and perovskite and Mg isotopes in plagioclase, spinel, melilite, fassaite, hibonite, grossular, and monticellite from the Allende Type B1 calcium-, aluminum-rich inclusion (CAI), USNM 3655A. The distribution and concentration of Ba and the REE in melilite from the melilite-rich mantle of 3655A are unlike those predicted from melilite-melt REE partitioning experiments for closed system crystal fractionation. REE concentrations are lower than expected in the first crystallized gehlenitic melilite, increase rapidly to higher than expected concentrations in melilite with intermediate akermanite contents (Ak30-Ak40), and decrease as expected only during the late stage of mantle crystallization. Barium concentrations in melilite are 10-50 times those expected, and the LREE/HREE ratio increases continuously rather than remaining constant. The unexpected distribution of trace elements in melilite reflects a progressive enrichment of trace elements in the melt during the early stages of crystallization. A partial explanation for this observation is the dissolution of precursor perovskite that contained half or more of the total REE budget of the inclusion. The Mg isotope record of 3655A is distinguished by four salient features: (1) large {sup 26}Mg excesses correlated with the respective Al/Mg ratios in plagioclase, melilite, and hibonite, (2) F{sub Mg}, the mass-dependent fractionation of Mg, is positive. with enrichment of the heavier Mu isotopes in all primary phases, (3) a heterogeneous distribution of F{sub Mg} values. with F{sub Mg} in melilite systematically greater than in either spinel or fassaite, and (4) isotopically normal Mg in the secondary alteration phases, grossular and monticellite. 81 refs., 9 figs., 8 tabs.

Kennedy, A.K.; Hutcheon, I.D.; Beckett, J.R. [California Institute of Technology, Pasadena, CA (United States)] [and others] [California Institute of Technology, Pasadena, CA (United States); and others

1997-04-01T23:59:59.000Z

133

Sulfur minimization in bacterial leaching  

SciTech Connect (OSTI)

The production of sewage biosolids in Ontario in 1989 was estimated to be 7 million m{sup 3} of wet sludge per year. Of this amount, land application accounts for between 20 and 30% of the total. Unfortunately, the use of sewage biosolids on agricultural land is often prohibited because of heavy metal contamination of the biosolids. High cost and operational problems have made chemical methods of metal extraction unattractive. Consequently, microbiological methods of leaching of heavy metals have been studied for over a decade. A relatively simple microbiological process has been investigated in recent years in flask level experiments and recently in a semicontinuous system. The process exploits nonacidophilic and acidophilic indigenous thiobacilli to extract heavy metals from sewage biosolids. These thiobacilli use elemental sulfur as the energy source, producing sulfuric acid. However, the resulting decontaminated biosolids can cause environmental problems like acidification of the soil, when acid is generated from the residual sulfur in the biosolids. The present study examines the possibility of reducing the amount of sulfur added in batch and semicontinuous bacterial leaching systems, and maximizing sulfur oxidation efficiency, thereby reducing the residual sulfur in leached biosolids.

Seth, R.; Prasad, D.; Henry, J.G. [Univ. of Toronto, Ontario (Canada). Dept. of Civil Engineering

1996-11-01T23:59:59.000Z

134

Partitioning of radionuclides and trace elements in phosphogypsum and its source materials based on sequential extraction methods  

Science Journals Connector (OSTI)

Phosphogypsum is a waste produced by the phosphate fertilizer industry. Although phosphogypsum is mainly calcium sulphate dihydrate, it contains elevated levels of impurities, which originate from the source phosphate rock used in the phosphoric acid production. Among these impurities, radionuclides from 238U and 232Th decay series are of most concern due to their radiotoxicity. Other elements, such as rare earth elements (REE) and Ba are also enriched in the phosphogypsum. The bioavailability of radionuclides (226Ra, 210Pb and 232Th), rare earth elements and Ba to the surrounding aquatic system was evaluated by the application of sequential leaching of the phosphogypsum samples from the Brazilian phosphoric acid producers. The sequential extraction results show that most of the radium and lead are located in the iron oxide (non-CaSO4) fraction, and that only 1318% of these radionuclides are distributed in the most labile fraction. Th, REE and Ba were found predominantly in the residual phase, which corresponds to a small fraction of the phosphate rock or monazite that did not react and to insoluble compounds such as sulphates, phosphates and silicates. It can be concluded that although all these elements are enriched in the phosphogypsum samples they are not associated with CaSO4 itself and therefore do not represent a threat to the surrounding aquatic environment.

A.J.G. Santos; B.P. Mazzilli; D.I.T. Fvaro; P.S.C. Silva

2006-01-01T23:59:59.000Z

135

Crystal Site Location of Iron and Trace Elements in a Magnesium-Iron Olivine by a New Crystallographic Technique  

Science Journals Connector (OSTI)

...element A can be shown to depend only on Ns;, NMg, and NA as obtained from the two spectra. The analysis used to determine CFe, CMn, and CN, in Table 1 is essentially as described above. However, in order to improve the statistical accuracy, three...

J. TAFT; J. C. H. SPENCE

1982-10-01T23:59:59.000Z

136

Uncertainty Measurement for Trace Element Analysis of Uranium and Plutonium Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)  

SciTech Connect (OSTI)

The measurement uncertainty estimatino associated with trace element analysis of impurities in U and Pu was evaluated using the Guide to the Expression of Uncertainty Measurement (GUM). I this evalution the uncertainty sources were identified and standard uncertainties for the components were categorized as either Type A or B. The combined standard uncertainty was calculated and a coverage factor k = 2 was applied to obtain the expanded uncertainty, U. The ICP-AES and ICP-MS methods used were deveoped for the multi-element analysis of U and Pu samples. A typical analytical run consists of standards, process blanks, samples, matrix spiked samples, post digestion spiked samples and independent calibration verification standards. The uncertainty estimation was performed on U and Pu samples that have been analyzed previously as part of the U and Pu Sample Exchange Programs. Control chart results and data from the U and Pu metal exchange programs were combined with the GUM into a concentration dependent estimate of the expanded uncertainty. Comparison of trace element uncertainties obtained using this model was compared to those obtained for trace element results as part of the Exchange programs. This process was completed for all trace elements that were determined to be above the detection limit for the U and Pu samples.

Gallimore, David L. [Los Alamos National Laboratory

2012-06-13T23:59:59.000Z

137

Trace element and REE composition of five samples of the Yucca Mountain calcite-silica deposits. Special report No. 8  

SciTech Connect (OSTI)

The attached materials document the results of part of a recent effort of geochemical sampling and analysis at Yucca Mountain and nearby regions. The efforts come as a result of interest in comprehensive analyses of rare earth elements (REE), lanthanum (La) through lutecium (Lu). Several additional, non-REE analyses were obtained as well. Commercially available REE analyses have proved to be insufficiently sensitive for geochemical purposes. Dr. Roman Schmitt at the Radiation Center at Oregon State University in Corvallis was sent five samples as a trial effort. The results are very encouraging. The purpose of compiling Dr. Schmitt`s report and the other materials is to inform the sponsor of his independent observations of these results and other information that sent to him. To provide a more complete appreciation of the utility of REE analyses a copy of Dave Vaniman`s recent article is included in which he notes that REE analyses from Yucca Mountain indicate the occurrence of two distinctly different REE patterns as do several other chemical parameters of the calcite-silica deposits. Our four samples with high equivalent CaCO{sub 3} were collected from sites we believe to be spring deposits. One sample, 24D, is from southern Crater Flat which is acknowledged by U.S.G.S. investigators to be a spring deposit. All four of these samples have REE patterns similar to those from the saturated zone reported by Vaniman.

Livingston, D.

1993-07-01T23:59:59.000Z

138

It's Elemental - The Element Phosphorus  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Silicon Silicon Previous Element (Silicon) The Periodic Table of Elements Next Element (Sulfur) Sulfur The Element Phosphorus [Click for Isotope Data] 15 P Phosphorus 30.973762 Atomic Number: 15 Atomic Weight: 30.973762 Melting Point: 317.30 K (44.15°C or 111.47°F) Boiling Point: 553.65 K (280.5°C or 536.9°F) Density: 1.82 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Non-metal Period Number: 3 Group Number: 15 Group Name: Pnictogen What's in a name? From the Greek word for light bearing, phosphoros. Say what? Phosphorus is pronounced as FOS-fer-es. History and Uses: In what is perhaps the most disgusting method of discovering an element, phosphorus was first isolated in 1669 by Hennig Brand, a German physician and alchemist, by boiling, filtering and otherwise processing as many as 60

139

Isotope and trace element evolution of the Naica aquifer (Chihuahua, Mexico) over the past 60,000yr revealed by speleothems  

Science Journals Connector (OSTI)

Abstract The espada speleothems of Cueva de las Espadas (Naica Mine, Chihuahua, Mexico) comprise a high-purity selenite core overlain by successive deposits of calcite, gypsum and aragonite. Gypsum precipitated under water from a hydrothermal solution (~58C) when the water table was above the cave level ca. 57ka, during the last glaciation, and some intervals during deglaciation and the Holocene. Aragonite was deposited at lower temperatures (~26C) in a perched lake occupying the cave bottom, when the water table dropped below the cave level during brief dry intervals during deglaciation and the early Holocene. The isotopic composition of gypsum water of crystallization shows that the deglaciationHolocene aquifer water was enriched in deuterium by 12.88.7 relative to water from the last glaciation. This is attributed to an increased relative moisture contribution from the Gulf of Mexico during deglaciation and the Holocene compared to the last glaciation. This indicates that drier conditions occurred in the Naica area during the Holocene than around 57ka. Furthermore, trace element analyses of gypsum served to deduce the circulation regime of the Naica aquifer during the past 60,000yr, and also suggest that higher aquifer recharge occurred during the last glaciation.

Fernando Gzquez; Jos-Mara Calaforra; Heather Stoll; Laura Sanna; Paolo Forti; Stein-Erik Lauritzen; Antonio Delgado; Fernando Rull; Jess Martnez-Fras

2013-01-01T23:59:59.000Z

140

Abstracts from a workshop on processes determining the input, behavior and fate of radionuclides and trace elements in continental shelf environments  

SciTech Connect (OSTI)

Abstracts of workshop presentations concerning input, behavior, and fate of trace metals and radionuclides in the marine system are presented. (ACR)

Not Available

1980-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Offshore Sulfur Comes In  

Science Journals Connector (OSTI)

Offshore Sulfur Comes In ... "The deposit is a major new source of sulfur," say Hines H. Baker, president of Humble Oil, and Langbourne M. Williams, president of Freeport Sulphur. ... Humble's deposit, known as Grand Isle (Block 18), was discovered in the course of offshore oil exploration and it ranks among the most important sulfur discoveries of recent years. ...

1956-10-01T23:59:59.000Z

142

The reaction kinetics of gasoline sulfur compounds: Catalytic mechanisms for sulfur reduction  

SciTech Connect (OSTI)

One of the key elements of reformulated gasoline is the reduction of the sulfur compounds produced by fluid catalytic cracking. This paper probes the reaction kinetics of refractory gasoline-range thiophene derivatives (thiophene, tetrahydrothiophene, and alkylthiophenes) in an effort to determine the mechanisms of sulfur compound cracking in the FCC unit. The gasoline-range sulfur compounds were analyzed using gas chromatography with an atomic emission detector. The authors` results show that the FCC catalysts affects the cracking of sulfur compounds through both hydrogen transfer and zeolite pore restriction mechanisms. An experimental FCC catalyst is shown to reduce gasoline sulfur content in the Davidson Circulating Riser (DCR{sup TM}) pilot unit. Model compound tests show that the activity of the catalyst is due to both its catalytic and adsorptive properties. Tetrahydrothiophene, which is produced from thiophenes by hydrogen transfer, is completely removed by the experimental catalyst.

Harding, R.H.; Gatte, R.R.; Albro, T.G.; Wormsbecher, R.F. [W.R. Grace & Co. Conn, Columbia, MD (United States)

1993-12-31T23:59:59.000Z

143

Trace gas contaminant control in a space station atmosphere using adsorption  

SciTech Connect (OSTI)

Trace contaminants enter spacecraft atmospheres through offgassing of spacecraft materials and as products of crew metabolism. The consequences of fire or accidental release of toxic vapors from onboard systems is also a crew safety concern. The purpose of this work was to determine how these contaminants could be limited to safe concentrations in the atmosphere of the proposed space station. Contaminant source models were developed from spacecraft material offgassing and human metabolic production rate measurements. Contaminants were represented with a simplified model of 30 compounds by grouping similar species together. A trace contaminant control process, which consists of chemisorption of ammonia on phosphoric acid-impregnated activated carbon, ambient temperature catalytic oxidation of hydrogen and carbon monoxide, catalytic conversion of the sulfur in hydrogen sulfide and mercaptans to elemental sulfur, and adsorption of the other contaminants in a regenerable activated carbon adsorber, was proposed. Trace contaminant adsorption rate and equilibrium equations were derived. Various adsorbents were evaluated to determine the optimum sorbents for this application. Removal system performance limits were established, and optimum design ranges for process parameters were developed. Trace gas contaminants can be limited to safe concentrations by the process proposed under normal conditions using as little as 1 Kg/man-year of ammonia chemisorbent. The most likely accidental contaminant releases can be removed in {approximately}20 hours using frequent adsorber regenerations.

Winter, J.D.

1988-01-01T23:59:59.000Z

144

It's Elemental - The Element Chlorine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sulfur Sulfur Previous Element (Sulfur) The Periodic Table of Elements Next Element (Argon) Argon The Element Chlorine [Click for Isotope Data] 17 Cl Chlorine 35.453 Atomic Number: 17 Atomic Weight: 35.453 Melting Point: 171.65 K (-101.5°C or -150.7°F) Boiling Point: 239.11 K (-34.04°C or -29.27°F) Density: 0.003214 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 3 Group Number: 17 Group Name: Halogen What's in a name? From the Greek word for greenish yellow, chloros. Say what? Chlorine is pronounced as KLOR-een or as KLOR-in. History and Uses: Since it combines directly with nearly every element, chlorine is never found free in nature. Chlorine was first produced by Carl Wilhelm Scheele, a Swedish chemist, when he combined the mineral pyrolusite (MnO2) with

145

ARM - Measurement - Trace gas concentration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

govMeasurementsTrace gas concentration govMeasurementsTrace gas concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Trace gas concentration The amount per unit volume of trace gases other than carbon dioxide, ozone and water vapor, typically measured in conjunction with in situ aerosol measurements, e.g. carbon monoxide, nitrogen oxides, sulfur dioxide. Categories Atmospheric Carbon, Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments CO : Carbon Monoxide Mixing Ratio System

146

E-Print Network 3.0 - analyzing elemental composition Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SIMS trace- element data (up to 33 elements analyzed) are among... thermal processing. Bulk trace-element compositions: Our broad- beam SIMS data imply that vapor... refractory...

147

Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single...

148

Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Materials Advanced Materials Find More Like This Return to Search Sulfur-Graphene Oxide Nanocomposite Cathodes for LithiumSulfur Cells Lawrence Berkeley National...

149

Chapter 11 - Sulfur Recovery  

Science Journals Connector (OSTI)

Abstract Sulfur is present in many raw industrial gases and in natural gas in the form of hydrogen sulfide. Sulfur removal facilities are located at the majority of oil and gas processing facilities throughout the world. The sulfur recovery unit does not make a profit for the operator but it is an essential processing step to allow the overall facility to operate, as the discharge of sulfur compounds to the atmosphere is severely restricted by environmental regulations. Concentration levels of H2S vary significantly depending upon their source. H2S produced from absorption processes, such as amine treating of natural gas or refinery gas, can contain 5075% H2S by volume or higher. This chapter provides information about fundamentals of sulfur removal facilities in the natural gas industry.

Alireza Bahadori

2014-01-01T23:59:59.000Z

150

It's Elemental - Isotopes of the Element Chlorine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sulfur Sulfur Previous Element (Sulfur) The Periodic Table of Elements Next Element (Argon) Argon Isotopes of the Element Chlorine [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 35 75.76% STABLE 37 24.24% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 28 No Data Available Proton Emission (suspected) No Data Available 29 < 20 nanoseconds Proton Emission No Data Available 30 < 30 nanoseconds Proton Emission No Data Available 31 150 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 0.70% 32 298 milliseconds Electron Capture 100.00%

151

It's Elemental - The Element Indium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cadmium Cadmium Previous Element (Cadmium) The Periodic Table of Elements Next Element (Tin) Tin The Element Indium [Click for Isotope Data] 49 In Indium 114.818 Atomic Number: 49 Atomic Weight: 114.818 Melting Point: 429.75 K (156.60°C or 313.88°F) Boiling Point: 2345 K (2072°C or 3762°F) Density: 7.31 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 5 Group Number: 13 Group Name: none What's in a name? Named after the bright indigo line in its spectrum. Say what? Indium is pronounced as IN-dee-em. History and Uses: Indium was discovered by the German chemists Ferdinand Reich and Hieronymus Theodor Richter in 1863. Reich and Richter had been looking for traces of the element thallium in samples of zinc ores. A brilliant indigo line in

152

Effects of Fuel Sulfur Content and Diesel Oxidation Catalyst on PM Emitted from Light-Duty Diesel Engine  

Science Journals Connector (OSTI)

This work aims at the particle number concentrations and size distributions, sulfate and trace metals emitted from a diesel engine fueled with three different sulfur content fuels, operating with and without DOC. ... Figure 2. Sulfate emission rate and fuel consumption as a function of sulfur content at engine speed of 2690 rpm. ... Thus, the use of low metal fuels and lubricating oil is as important to the environment and human health as low sulfur fuels, especially for engines with after-treatment devices. ...

Hong Zhao; Yunshan Ge; Xiaochen Wang; Jianwei Tan; Aijuan Wang; Kewei You

2010-01-05T23:59:59.000Z

153

Enrichment of trace elements in rare-metal bearing pegmatites of the muscovite class: Examples from the Jasper, Thomaston-Barnesville, Troup and Cherokee-Pickens districts in Georgia  

SciTech Connect (OSTI)

Pegmatites from four important mining districts in Georgia: the Cherokee-Pickens district (mica and beryl), the Thomaston-Barnesville (mica), Troup (beryl), and Jasper County (feldspar) districts, generally contain quartz, muscovite, K-feldspar and oligoclase and can be included in the muscovite class of pegmatites. No source intrusions are known for any of these pegmatite districts. The Thomaston-Barnesville district covers about 2,000 km[sup 2] compared to the < 100 km[sup 2] of the other three districts and includes 3--4 times as many pegmatites as each of the other districts. The more highly fractionated pegmatites represent 42 to 48 % of the total number of pegmatites sampled in each district except for the Thomaston-Barnesville district in which only 7 % are more highly fractionated. Muscovites from the more highly fractionated pegmatites in these districts contain mean trace element values of 1,118--1,732 ppm Rb, 1,867--3,083 ppm F, 91--278 ppm Li, 7.7-31 ppm Be, 122--147 ppm Ga, 122--315 ppm Nb, and 137--254 ppm Zn. These pegmatites have mean Ba/Rb and Rb/K[sub 2]O ratios of 0.01--0.21 and 129--177 ppm. Mean Ba is 19--234 ppm. Mean trace element values of muscovites from the least fractionated pegmatites are 381--675 ppm Rb, 748--1,622 ppm F, 33--221 ppm Li, 4:8--20.6 ppm Be, 56--80 ppm Ga, 32--152 ppm Nb, and 59--113 ppm Zn. These pegmatites have mean Ba/Rb and Rb/K[sub 2]O ratios of 0.44--2.83 and 39--76. Mean Ba is 218--857 ppm. In each district, the more highly fractionated pegmatites contain beryl or are in the vicinity of beryl-bearing pegmatites.

Cocker, M.D. (Georgia Geologic Survey, Atlanta, GA (United States))

1992-01-01T23:59:59.000Z

154

Freeport Begins Offshore Sulfur Plant  

Science Journals Connector (OSTI)

Freeport Begins Offshore Sulfur Plant ... Discovered by Humble Oil & Refining, the sulfur deposit off Grand Isle is believed by industry observers to be one of the largest discovered in recent years. ...

1958-07-07T23:59:59.000Z

155

TURTLE with MAD input (Trace Unlimited Rays Through Lumped Elements) -- A computer program for simulating charged particle beam transport systems and DECAY TURTLE including decay calculations  

SciTech Connect (OSTI)

TURTLE is a computer program useful for determining many characteristics of a particle beam once an initial design has been achieved, Charged particle beams are usually designed by adjusting various beam line parameters to obtain desired values of certain elements of a transfer or beam matrix. Such beam line parameters may describe certain magnetic fields and their gradients, lengths and shapes of magnets, spacings between magnetic elements, or the initial beam accepted into the system. For such purposes one typically employs a matrix multiplication and fitting program such as TRANSPORT. TURTLE is designed to be used after TRANSPORT. For convenience of the user, the input formats of the two programs have been made compatible. The use of TURTLE should be restricted to beams with small phase space. The lumped element approximation, described below, precludes the inclusion of the effect of conventional local geometric aberrations (due to large phase space) or fourth and higher order. A reading of the discussion below will indicate clearly the exact uses and limitations of the approach taken in TURTLE.

Carey, D.C.

1999-12-09T23:59:59.000Z

156

It's Elemental - Isotopes of the Element Phosphorus  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Silicon Silicon Previous Element (Silicon) The Periodic Table of Elements Next Element (Sulfur) Sulfur Isotopes of the Element Phosphorus [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 31 100% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 24 No Data Available Electron Capture (suspected) No Data Available Proton Emission (suspected) No Data Available 25 < 30 nanoseconds Proton Emission 100.00% 26 43.7 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission No Data Available 27 260 milliseconds Electron Capture 100.00% Electron Capture with

157

Sulfur/three-dimensional graphene composite for high performance lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract A sulfur/graphene composite is prepared by loading elemental sulfur into three-dimensional graphene (3D graphene), which is assembled using a metal ions assisted hydrothermal method. When used as cathode materials for lithiumsulfur (LiS) batteries, the sulfur/graphene composite (S@3D-graphene) with 73wt % sulfur shows a significantly enhanced cycling performance (>700mAhg?1 after 100 cycles at 0.1C rate with a Coulombic efficiency>96%) as well as high rate capability with a capacity up to 500mAhg?1 at 2C rate (3.35Ag?1). The superior electrochemical performance could be attributed to the highly porous structure of three-dimensional graphene that not only enables stable and continue pathway for rapid electron and ion transportation, but also restrain soluble polysulfides and suppress the shuttle effect. Moreover, the robust structure of 3D graphene can keep cathode integrity and accommodate the volume change during high-rate charge/discharge processes, making it a promising candidate as cathode for high performance LiS batteries.

Chunmei Xu; Yishan Wu; Xuyang Zhao; Xiuli Wang; Gaohui Du; Jun Zhang; Jiangping Tu

2015-01-01T23:59:59.000Z

158

Why sequence Alkaliphilic sulfur oxidizing bacteria for sulfur pollution  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alkaliphilic sulfur oxidizing Alkaliphilic sulfur oxidizing bacteria for sulfur pollution remediation? Burning sulfur-containing fuels, such as coal, oil, and natural gas, contributes significantly to global environmental problems, such as air pollution and acid rain, besides contributing to the loss of the ozone layer. One method of managing sulfur compounds released as byproducts from industrial processes is to scrub them out using chemical treatments and activated charcoal beds. A lower-cost solution relies on incorporating alkaliphic sulfur-oxidizing bacteria into biofilters to convert the volatile and toxic compounds into insoluble sulfur for easier removal. Discovered in the last decade, these bacteria have been found to thrive in habitats that span the full pH range. The bacteria could have applications

159

Direct sulfur recovery during sorbent regeneration. Final report  

SciTech Connect (OSTI)

The objective of this research project was to improve the direct elemental sulfur yields that occur during the regeneration of SO{sub 2}-saturated MgO-vermiculite sorbents (MagSorbents) by examining three approaches or strategies. The three approaches were regeneration-gas recycle, high-pressure regeneration, and catalytic reduction of the SO{sub 2} gas using a new catalyst developed by Research Triangle Institute (RTI). Prior to the project, Sorbent Technologies Corporation (Sorbtech) had developed a sorbent-regeneration process that yielded directly a pure elemental sulfur product. In the process, typically about 25 to 35 percent of the liberated S0{sub 2} was converted directly to elemental sulfur. The goal of this project was to achieve a conversion rate of over 90 percent. Good success was attained in the project. About 90 percent or more conversion was achieved with two of the approaches that were examined, regeneration-gas recycle and use of the RTI catalyst. Of these approaches, regeneration-gas recycle gave the best results (essentially 100 percent conversion in some cases). In the regeneration-gas recycle approach, saturated sorbent is simply heated to about 750{degree}C in a reducing gas (methane) atmosphere. During heating, a gas containing elemental sulfur, water vapor, H{sub 2}S, S0{sub 2}, and C0{sub 2} is evolved. The elemental sulfur and water vapor in the gas stream are condensed and removed, and the remaining gas is recycled back through the sorbent bed. After several recycles, the S0{sub 2} and H{sub 2}S completely disappear from the gas stream, and the stream contains only elemental sulfur, water vapor and C0{sub 2}.

Nelson, S.G.; Little, R.C. [Sorbent Technologies Corp., Twinsburg, OH (United States)

1993-08-01T23:59:59.000Z

160

Why sequence purple sulfur bacteria?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

purple sulfur bacteria? purple sulfur bacteria? The process by which plants and some bacteria can convert light energy to sugar, or photosynthesis, is crucial to global food webs, and complicated. Very little is known about the photosynthetic bacteria in the purple sulfur bacteria group, which may represent one of the most primitive photosynthetic organisms and are capable of carbon fixation and sequestration in both light and dark conditions with the help of sulfur compounds. Purple sulfur bacteria are autotrophic and can synthesize organic compounds from inorganic sources. Researchers hope to learn more by sequencing nine type strains of purple sulfur bacteria that are found in freshwater, brackish and marine systems. The information would lead to a better understanding of the process of photosynthesis as well as the global

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Accretionary wedge harzburgite serpentinization and rodingitization constrained by perovskite U/Pb SIMS age, trace elements and Sm/Nd isotopes: Case study from the Western Carpathians, Slovakia  

Science Journals Connector (OSTI)

Abstract Perovskite-bearing harzburgites occur in a mlange type blueschist-bearing accretionary wedge complex of the Inner Western Carpathians Meliata Unit in Slovakia. Although dark rounded, slightly hydrated relic cores of harzburgite boulders are perovskite-free, perovskite (Prv) occurrence in the surrounding serpentinites and rodingites enabled dating of hydration, resulting in two metamorphicmetasomatic Prv generations. Perovskite (1) grows parallel to relic clinopyroxene exsolution lamellae or forms randomly oriented grain clusters in serpentinized orthopyroxene (Opx1) porphyroclasts, often accompanied by tiny andradite lamellae clusters, or it is partly replaced by Ti-andradite. Perovskite crystallization indicates evolving rodingitization fluids pervading the boundary between the harzburgite cores and Prv-free serpentinite. This strictly limited occurrence of Prv (1) within a 1 to 20-cm across-zone implies slightly postponed Prv crystallization to serpentinization by LREE(Ce,La), Ca2+, Ti/Fe3+-enriched aqueous fluids. A grain scale metasomatic mechanism partitioned Ca and Ti from the host orthopyroxene porphyroclasts, spinel (Ti) and grain-boundary pervasive fluids to Prv. In contrast, Prv (2) occurs in a 1 to 3cm across chlorite-rich blackwall zone between hosting serpentinite and rodingite veins, thus indicating channelled rodingitization fluid flow and accompanying hydraulic fracturing. Here, Prv (2) is ingrown by chlorite and apatite. Part of this Prv (2) formed in a rodingite vein mineral assemblage composed of diopside, andradite, vesuvianite, epidote/zoisite, apatite and chlorite. Both perovskite 1 and 2 are replaced by pyrophanite along the grain rims and interiors; most likely via fluid-aided coupled dissolutionreprecipitation at increased SiFeMnAl element solubility in rodingitization fluids pervading serpentinized harzburgite. Both Prv generations, especially Prv (2), can be partly to almost totally replaced by (Ti-) Adr. Overgrowths of spinel by andradite are occasionally observed in contact zones between the serpentinites and rodingites. LA-ICP-MS study revealed strong depletion in LREE from Prv (1) to Prv (2), and a more typically positive Eu anomaly for Prv (2). Our spider diagram depicts relative enrichment in U, Nb, La, Ce, Pr, Nd, and decreased Rb, Ba, Th, Ta, Pb, Sr, Zr in both Prv generations. The U/Pb SIMS concordia ages of Prv (1) from 3 samples range from 1371Ma to 1351Ma, with a mean of 135.60.58Ma, while Prv (2) was dated at 133.75.4Ma. Such negligible age differences imply a relatively short-lived rodingitization event responsible for crystallization of both Prv generations. The 143Nd/144Nd mean value of Prv (1) is 0.5121530.000017 by LA-MC-ICP-MS, thus corresponding to the initial ?Nd(t=135)=?8.20.4 (math's mean). This suggests that the subducted and dehydrated continental crust was the main source of the interactive fluids which initiated serpentinization and rodingitization in the Neotethyan Meliatic accretionary wedge following closure of the MeliataHallstatt Triassic to Jurassic oceanic back-arc basin and the high-pressure metamorphism dated at ca. 160150Ma by 40Ar/39Ar.

Xian-Hua Li; Marin Puti; Yue-Heng Yang; Mat Koppa; Marian Dyda

2014-01-01T23:59:59.000Z

162

It's Elemental - The Element Iodine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tellurium Tellurium Previous Element (Tellurium) The Periodic Table of Elements Next Element (Xenon) Xenon The Element Iodine [Click for Isotope Data] 53 I Iodine 126.90447 Atomic Number: 53 Atomic Weight: 126.90447 Melting Point: 386.85 K (113.7°C or 236.7°F) Boiling Point: 457.55 K (184.4°C or 364.0°F) Density: 4.93 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Non-metal Period Number: 5 Group Number: 17 Group Name: Halogen What's in a name? From the Greek word for violet, iodes. Say what? Iodine is pronounced as EYE-eh-dine or as EYE-eh-din. History and Uses: Iodine was discovered by the French chemist Barnard Courtois in 1811. Courtois was extracting sodium and potassium compounds from seaweed ash. Once these compounds were removed, he added sulfuric acid (H2SO4) to

163

Sulfide, phosphate, and minor element enrichment in the New Albany Shale (Devonian-Mississippian) of southern Indiana  

SciTech Connect (OSTI)

The upper part of the New Albany Shale is divided into three members, which in ascending order are: (1) the Morgan Trail Member, a laminated brownish-black shale; (2) the Camp Run Member, an interbedded brownish-black and greenish-gray shale; and (3) the Clegg Creek Member, also a laminated brownish-black shale. The Morgan Trail and Camp Run Members contain 5 to 6% total organic carbon (TOC) and 2% sulfide sulfur. Isotopic composition of sulfide in these members ranges from -5.0 to -20.0%. C/S plots indicate linear relationships between abundances of these elements characteristic of sediments deposited in a noneuxinic marine environment. The Clegg Creek Member contains 10 to 15% TOC and 2 to 6% sulfide sulfur. Isotopic composition of sulfide ranges from -5.0 to -40.0%. The most negative values are characteristic of syngenetic pyrite formed within an anoxic water column. Abundances of carbon and sulfur are higher and uncorrelated in this member, consistent with deposition in an euxinic environment. Further, DOP (degree of pyritization) values suggest that pyrite formation was generally iron limited throughout Clegg Creek deposition, but sulfur isotopes indicate that syngenetic (water column) pyrite becomes an important component in the sediment only in the upper part of the member. At the top of the Clegg Creek Member a zone of phosphate nodules and trace metal enrichment coincides with maximal TOC values. During euxinic deposition, phosphate and trace metals accumulated below the chemocline due to limited vertical circulation in the water column. Phosphate and trace metals released for organic matter during early diagenesis resulted in precipitation of metal-rich phosphate nodules.

Beier, J.A.

1988-01-01T23:59:59.000Z

164

Trace elements in zooplankton particulate products  

Science Journals Connector (OSTI)

... the Martin and Knauer4 method. Samples along with appropriate blanks and standards were analysed by flameless or flame atomic absorption spectro-photometry10 and instrumental neutron activation11.

SCOTT W. FOWLER

1977-09-01T23:59:59.000Z

165

Trace Element and Isotopic Fluxes/ Subducted Slab  

E-Print Network [OSTI]

MODELS OF SUBDUCTION 5 3.20.4 EARLY-STAGE PROCESSING OF SEDIMENTS AND PORE WATERS IN TRENCH AND SHALLOW FOREARC SETTINGS (Early Subduction Chemistries of HP and UHP Suites 28 3.20.5.10 Forearc to Subarc: Summary and Outstanding Questions 30 3

Bebout, Gray E.

166

Role of Trace Elements in Cancer  

Science Journals Connector (OSTI)

...from less than 30 @zg/g,wet weight, to 170 and 50 to 460...were observed in 5 patients in corn plete remission, and values...may be introduced during the milling process. It has been suggested...manganese (1.5 2 @g/g,wet weight) and manganese isprimarily...

Morton K. Schwartz

1975-11-01T23:59:59.000Z

167

Trace element analysis of Texas lignite  

E-Print Network [OSTI]

or in the planning stages, Near surface lignite re- sources are estimated to be 21 billion metric tons in Texas, while deep basin reserves are estimated at 31 billion metric tons. Near (3] surface reserves alone could fulfill Texas' electrical needs for 100 years... or in the planning stages, Near surface lignite re- sources are estimated to be 21 billion metric tons in Texas, while deep basin reserves are estimated at 31 billion metric tons. Near (3] surface reserves alone could fulfill Texas' electrical needs for 100 years...

Mahar, Sean

2012-06-07T23:59:59.000Z

168

Production of elemental sulfur and methane from H{sub 2}S and CO{sub 2} derived from a coal desulfurization process. Annual technical progress report, October 1, 1995--September 30, 1996; Quarterly technical progress report, July 1--September 30, 1996  

SciTech Connect (OSTI)

This annual report summarizes the results of the project during the third year period. The purpose of this study was to develop an experimental and theoretical procedure to investigate the feasibility of producing elemental sulfur, carbon monoxide, hydrogen and possibly methane from hydrogen sulfide and carbon dioxide through catalytic reactions. A standard experimental system that can evaluate potential catalysts under controlled laboratory conditions has been designed and constructed. And an effective simulation program capable of providing valuable thermodynamic information on the reaction system has been compiled. During this project year, the modified experimental system for the catalytic reaction studies was installed and the temperature distribution profile inside the reactor has been characterized. New flowmeters were replaced in the reaction system and calibrated to control the flowrates of H{sub 2}S, CO{sub 2}, H{sub 2} and N{sub 2}. Based on the experimental results of H{sub 2}S decomposition under both non-catalytic and catalytic conditions, bench scale experiments were performed with the CoO-MoO{sub 3}-Alumina catalyst at moderate temperatures, around 550 C, to investigate the adsorption effects using solid sorbents within a sulfur vapor environment. Four kinds of adsorbents have been tested. In addition to the above baseline tests, several designs of solid adsorbent feed system have been tested. Under both an inert and a real reaction environment, bench scale experiments were performed to investigate the characteristics and efficiency of activated carbon passing through the CoO-MoO{sub 3}-Alumina catalyst bed.

Jiang, X.; Khang, S.J.; Keener, T.C.

1996-12-31T23:59:59.000Z

169

Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes  

SciTech Connect (OSTI)

Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm..

Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuiliang; Li, Xiaolin

2014-06-17T23:59:59.000Z

170

Assessing Potential Acidification of Marine Archaeological Wood Based on Concentration of Sulfur Species  

SciTech Connect (OSTI)

The presence of sulfur in marine archaeological wood presents a challenge to conservation. Upon exposure to oxygen, sulfur compounds in waterlogged wooden artifacts are being oxidized, producing sulfuric acid. This speeds the degradation of the wood, potentially damaging specimens beyond repair. Sulfur K-edge x-ray absorption spectroscopy was used to identify the species of sulfur present in samples from the timbers of the Mary Rose, a preserved 16th century warship known to undergo degradation through acidification. The results presented here show that sulfur content varied significantly on a local scale. Only certain species of sulfur have the potential to produce sulfuric acid by contact with oxygen and seawater in situ, such as iron sulfides and elemental sulfur. Organic sulfurs, such as the amino acids cysteine and methionine, may produce acid but are integral parts of the wood's structure and may not be released from the organic matrix. The sulfur species contained in the sample reflect the exposure to oxygen while submerged, and this exposure can differ greatly over time and position. A better understanding of the species pathway to acidifications required, along with its location, in order to suggest a more customized and effective preservation strategy. Waterlogged archaeological wood, frequently in the form of shipwrecks, is being excavated for historical purposes in many countries around the world. Even after extensive efforts towards preservation, scientists are discovering that accumulation of sulfate salts results in acidic conditions on the surfaces of the artifacts. Sulfuric acid degrades structural fibers in the wood by acid hydrolysis of cellulose, accelerating the decomposition of the ship timbers. Determining the sulfur content of waterlogged wood is now of great importance in maritime archaeology. Artifact preservation is often more time consuming and expensive than the original excavation; but it is key to the availability of objects for future study as well as maintaining the integrity of historical data and preserving the value of museum pieces. Sulfur occurs in a wide number of oxidation states from -2 to +6, and appears in numerous organic and inorganic compounds in nature. However, it is a very minor component of wood. Sulfur K-edge x-ray absorption spectroscopy (XAS) is a valuable technique because it has the ability to detect very low concentrations of sulfur in the specimen. XAS is also sensitive to differences in oxidation states, as well as long and short range order in molecules.

Not Available

2011-06-22T23:59:59.000Z

171

HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING  

SciTech Connect (OSTI)

This second quarter report of 2002 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf (service mark of CrystaTech, Inc.) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant in west Texas. Previous reports described development of a catalyst with the required selectivity and efficiency for producing sulfur dioxide from H{sub 2}S. In the laboratory, the catalyst was shown to be robust and stable in the presence of several intentionally added contaminants, including condensate from the pilot plant site. This report describes testing using the laboratory apparatus but operated at the pilot plant using the actual pilot plant gas, which contains far more contaminants than can be simulated in the laboratory. The results are very encouraging, with stable and efficient operation being obtained for a prolonged period of time.

Girish Srinivas; Steven C. Gebhard; David W. DeBerry

2002-07-01T23:59:59.000Z

172

Production of elemental sulfur and methane from H{sub 2}S and CO{sub 2} derived from a coal desulfurization process. Annual technical progress report, October 1, 1994--September 30, 1995; Quarterly technical progress report, July 1--September 30, 1995  

SciTech Connect (OSTI)

This study is to develop an experimental and theoretical procedure to investigate the feasibility of producing elemental sulfur, CO, H{sub 2} and possibly CH{sub 4} from H{sub 2}S and CO{sub 2} through catalytic reactions. A standard experimental system that can evaluate potential catalysts under controlled laboratory conditions has been designed and constructed. An effective simulation program capable of providing valuable thermodynamic information of the reaction system has been compiled. During this second project year, the modified experimental system for the laboratory catalytic reaction studies has been installed and temperature distribution profile inside the reactor has been characterized. Based on the experimental decomposition of H{sub 2}S under both non-catalytic and catalytic conditions with the CoO-MoO{sub 3}-alumina catalyst at moderate temperatures, around 550 C, further thermodynamic analyses of the theoretical conversion of H{sub 2}S for various temperatures, pressures and ratios of H{sub 2}S to CO{sub 2} were performed. A multistage reaction system was also considered. Results are presented. 47 refs., 51 figs., 7 tabs.

Jiang, X.; Khang, S.J.; Keener, T.C.

1995-12-31T23:59:59.000Z

173

Effective hydrogen generation and resource circulation based on sulfur cycle system  

SciTech Connect (OSTI)

For the effective hydrogen generation from H{sub 2}S, it should be compatible that the increscent of the photocatalytic (or electrochemical) activities and the development of effective utilization method of by-products (poly sulfide ion). In this study, system integration to construct the sulfur cycle system, which is compatible with the increscent of the hydrogen and or electron energy generation ratio and resource circulation, is investigated. Photocatalytic hydrogen generation rate can be enhanced by using stratified photocatalysts. Photo excited electron can be transpired to electrode to convert the electron energy to hydrogen energy. Poly sulfide ion as the by-products can be transferred into elemental sulfur and/or industrial materials such as rubber. Moreover, elemental sulfur can be transferred into H{sub 2}S which is the original materials for hydrogen generation. By using this system integration, the sulfur cycle system for the new energy generation can be constructed.

Takahashi, Hideyuki; Mabuchi, Takashi; Hayashi, Tsugumi; Yokoyama, Shun; Tohji, Kazuyuki [Graduate School of Environmental Studies, Tohoku University 6-6-20, Aramaki, Aoba-ku, Sendai, 980-8579 (Japan)

2013-12-10T23:59:59.000Z

174

Sulfur capture in combination bark boilers  

SciTech Connect (OSTI)

A review of sulfur dioxide emission data for eight combination bark boilers in conjunction with the sulfur contents of the fuels reveals significant sulfur capture ranging from 10% to over 80% within the solid ash phase. Wood ash characteristics similar to activated carbon as well as the significant wood ash alkali oxide and carbonate fractions are believed responsible for the sulfur capture. Sulfur emissions from combination bark-fossil fuel firing are correlated to the sulfur input per ton of bark or wood residue fired.

Someshwar, A.V.; Jain, A.K. (National Council of the Paper Industry for Air and Stream Improvement, Gainesville, FL (United States))

1993-07-01T23:59:59.000Z

175

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

176

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

177

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

178

Halocarbon and Other Atmospheric Trace Species (HATS) | Data.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Halocarbon and Other Atmospheric Trace Species (HATS) Halocarbon and Other Atmospheric Trace Species (HATS) Agriculture Community Menu DATA APPS EVENTS DEVELOPER STATISTICS COLLABORATE ABOUT Agriculture You are here Data.gov » Communities » Agriculture » Data Halocarbon and Other Atmospheric Trace Species (HATS) Dataset Summary Description The general mission of the Halocarbons and other Atmospheric Trace Species group is to quantify the distributions and magnitudes of sources and sinks for atmospheric nitrous oxide (N2O) and halogen containing compounds. HATS utilizes numerous types of platforms, including ground-based stations, towers, ocean vessels, aircraft, and balloons, to accomplish its mission. For a detailed mission statement, consult our FAQ. Tags {"nitrous oxide","sulfur hexaflouride",CFC-11,CFC-12,CFC-113,CCl4,CH3CCl3,CH3Cl,halon-1211,HCFC-22,HCFC-142b,halocarbons,chromatograph,aircraft,balloons,vessels,ships,towers,"natural resources",environment,air,"GHG "}

179

Molecular Structures of Polymer/Sulfur Composites for Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life. Molecular Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long...

180

Nuclear elements in Banach Jordan pairs Ottmar Loos  

E-Print Network [OSTI]

Nuclear elements in Banach Jordan pairs Ottmar Loos Abstract We introduce nuclear elements in Banach Jordan pairs, generalizing the nuclear elements Jordan pairs and show that the trace form Trintroduced in [3] may be extended to the nuclear

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Amylopectin Wrapped Graphene Oxide/Sulfur for Improved Cyclability of LithiumSulfur Battery  

Science Journals Connector (OSTI)

Amylopectin Wrapped Graphene Oxide/Sulfur for Improved Cyclability of LithiumSulfur Battery ... An amylopectin wrapped graphene oxide-sulfur composite was prepared to construct a 3-dimensionally cross-linked structure through the interaction between amylopectin and graphene oxide, for stabilizing lithium sulfur batteries. ...

Weidong Zhou; Hao Chen; Yingchao Yu; Deli Wang; Zhiming Cui; Francis J. DiSalvo; Hctor D. Abrua

2013-09-05T23:59:59.000Z

182

Two stage sorption of sulfur compounds  

DOE Patents [OSTI]

A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

Moore, William E. (Manassas, VA)

1992-01-01T23:59:59.000Z

183

Rare Earth Elements:  

Science Journals Connector (OSTI)

...were also extracted as by-products of uranium mining from conglomerates at Elliot Lake...toxic waste lakes, acrid air, and high cancer rates in the Bayan Obo area. The environmental...Major and trace element composition of the depleted MORB mantle (DMM). Earth and Planetary...

Anton R. Chakhmouradian; Frances Wall

184

HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING  

SciTech Connect (OSTI)

This final report describes the objectives, technical approach, results and conclusions for a project funded by the U.S. Department of Energy to test a hybrid sulfur recovery process for natural gas upgrading. The process concept is a configuration of CrystaTech, Inc.'s CrystaSulf{reg_sign} process which utilizes a direct oxidation catalyst upstream of the absorber tower to oxidize a portion of the inlet hydrogen sulfide (H{sub 2}S) to sulfur dioxide (SO{sub 2}) and elemental sulfur. This hybrid configuration of CrystaSulf has been named CrystaSulf-DO and represents a low-cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day and more. This hybrid process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both onshore and offshore applications. CrystaSulf is a nonaqueous sulfur recovery process that removes H{sub 2}S from gas streams and converts it to elemental sulfur. In CrystaSulf, H{sub 2}S in the inlet gas is reacted with SO{sub 2} to make elemental sulfur according to the liquid phase Claus reaction: 2H{sub 2}S + SO{sub 2} {yields} 2H{sub 2}O + 3S. The SO{sub 2} for the reaction can be supplied from external sources by purchasing liquid SO{sub 2} and injecting it into the CrystaSulf solution, or produced internally by converting a portion of the inlet gas H{sub 2}S to SO{sub 2} or by burning a portion of the sulfur produced to make SO{sub 2}. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, the needed SO{sub 2} is produced by placing a bed of direct oxidation catalyst in the inlet gas stream to oxidize a portion of the inlet H{sub 2}S. Oxidation catalysts may also produce some elemental sulfur under these conditions, which can be removed and recovered prior to the CrystaSulf absorber. The CrystaSulf-DO process can utilize direct oxidation catalyst from many sources. Numerous direct oxidation catalysts are available from many suppliers worldwide. They have been used for H{sub 2}S oxidation to sulfur and/or SO{sub 2} for decades. It was believed at the outset of the project that TDA Research, Inc., a subcontractor, could develop a direct oxidation catalyst that would offer advantages over other commercially available catalysts for this CrystaSulf-DO process application. This project involved the development of several of TDA's candidate proprietary direct oxidation catalysts through laboratory bench-scale testing. These catalysts were shown to be effective for conversion of H{sub 2}S to SO{sub 2} and to elemental sulfur under certain operating conditions. One of these catalysts was subsequently tested on a commercial gas stream in a bench-scale reactor at CrystaTech's pilot plant site in west Texas with good results. However, commercial developments have precluded the use of TDA catalysts in the CrystaSulf-DO process. Nonetheless, this project has advanced direct oxidation catalyst technology for H{sub 2}S control in energy industries and led to several viable paths to commercialization. TDA is commercializing the use of its direct oxidation catalyst technology in conjunction with the SulfaTreat{reg_sign} solid scavenger for natural gas applications and in conjunction with ConocoPhillips and DOE for gasification applications using ConocoPhillips gasification technology. CrystaTech is commercializing its CrystaSulf-DO process in conjunction with Gas Technology Institute for natural gas applications (using direct oxidation catalysts from other commercial sources) and in conjunction with ChevronTexaco and DOE for gasification applications using ChevronTexaco's gasification technology.

Dennis Dalrymple

2004-06-01T23:59:59.000Z

185

EMSL - trace metals  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

trace-metals en Microbial Reductive Transformation of Phyllosilicate Fe(III) and U(VI) in Fluvial Subsurface Sediments. http:www.emsl.pnl.govemslwebpublications...

186

Elements & Compounds Atoms (Elements)  

E-Print Network [OSTI]

#12;Elements & Compounds #12;Atoms (Elements) Molecules (Compounds) Cells Elements & Compounds #12;Nucleus Electrons Cloud of negative charge (2 electrons) Fig. 2.5: Simplified model of a Helium (He) Atom He 4.002602 2 Helium Mass Number (~atomic mass) = number of Neutrons + Protons = 4 for Helium Atomic

Frey, Terry

187

Involvement of Intermediate Sulfur Species in Biological Reduction of Elemental Sulfur under Acidic, Hydrothermal Conditions  

E-Print Network [OSTI]

, Hydrothermal Conditions Eric S. Boyd,a Gregory K. Druschelb Department of Chemistry and Biochemistry, Montana in size, a rate which was influenced by the pH of the me- dium and the presence of organic carbon. Thus, S to serve as a growth-promoting TEA for A. sulfurireducens. Terrestrial and hydrothermal spring source

Ahmad, Sajjad

188

Measurement of gas/water uptake coefficients for trace gases active in the marine environment  

SciTech Connect (OSTI)

Ocean produced reduced sulfur compounds including dimethylsulfide (DMS), hydrogen sulfide (H{sub 2}S), carbon disulfide (CS{sub 2}), methyl mercaptan (CH{sub 3}CH) and carbonyl sulfide (OCS) deliver a sulfur burden to the atmosphere which is roughly equal to sulfur oxides produced by fossil fuel combustion. These species and their oxidation products dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO{sub 2}) and methane sulfonic acid (MSA) dominate aerosol and CCN production in clean marine air. Furthermore, oxidation of reduced sulfur species will be strongly influenced by NO{sub x}/O{sub 3} chemistry in marine atmospheres. The multiphase chemical processes for these species must be understood in order to study the evolving role of combustion produced sulfur oxides over the oceans. We have measured the chemical and physical parameters affecting the uptake of reduced sulfur compounds, their oxidation products, ozone, and nitrogen oxides by the ocean's surface, and marine clouds, fogs, and aerosols. These parameters include: gas/surface mass accommodation coefficients; physical and chemically modified (effective) Henry's law constants; and surface and liquid phase reaction constants. These parameters are critical to understanding both the interaction of gaseous trace species with cloud and fog droplets and the deposition of trace gaseous species to dew covered, fresh water and marine surfaces.

Davidovits, P. (Boston Coll., Chestnut Hill, MA (United States). Dept. of Chemistry); Worsnop, D.W.; Zahniser, M.S.; Kolb, C.E. (Aerodyne Research, Inc., Billerica, MA (United States). Center for Chemical and Environmental Physics)

1992-02-01T23:59:59.000Z

189

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Broader source: Energy.gov (indexed) [DOE]

CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries 2011 DOE...

190

Contribution of isotopologue self-shielding to sulfur mass-independent fractionation during sulfur dioxide photolysis  

E-Print Network [OSTI]

Signatures of sulfur mass-independent fractionation (S-MIF) are observed for sulfur minerals in Archean rocks, and for modern stratospheric sulfate aerosols (SSA) deposited in polar ice. Ultraviolet light photolysis of ...

Lyons, J. R.

191

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

SciTech Connect (OSTI)

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

192

Sulfur-Free Selective Pulping  

E-Print Network [OSTI]

Technoeconomic Appraisal," December 1991. 5. DOE Annual Report on Contract No. AC02-83CH10093, Bozell, J. J., Hames, B., Chum, H. L., Dimmel, D. R, Althen, E., Caldwell, P. L., Daube, Oxidation ;; Diels-Alder .. I I -Methanol .. ~ 5 I 3 (C~O) OCH... - Hydrogen 3 (Q-IP) # Q-I 3 o o ~ o 1 2 ~ (H) Lignin DMBQ =two OCH3 groups Anthraquinone MMBQ =one OCH3 group A. K, and Kuroda, K-I.,"Sulfur-free Selective Pulping," March 1992. 6. DOE Annual Report on Contrac No. DE-AC02-83CH10093, Bozell, J. J...

Dimmel, D. R.; Bozell, J. J.

193

Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake  

E-Print Network [OSTI]

promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

Borguet, Eric

194

Graphene-wrapped sulfur nanospheres with ultra-high sulfur loading for high energy density lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract Lithiumsulfur (LiS) battery with high theoretical energy density is one of the most promising energy storage systems for electric vehicles and intermittent renewable energy. However, due to the poor conductivity of the active material, considerable weight of the electrode is occupied by the conductive additives. Here we report a graphene-wrapped sulfur nanospheres composite (S-nanosphere@G) with sulfur content up to 91wt% as the high energy density cathode material for LiS battery. The sulfur nanospheres with diameter of 400500nm are synthesized through a solution-based approach with the existence of polyvinylpyrrolidone (PVP). Then the sulfur nanospheres are uniformly wrapped by conductive graphene sheets through the electrostatic interaction between graphene oxide and PVP, followed by reducing of graphene oxide with hydrazine. The design of graphene wrapped sulfur nanoarchitecture provides flexible conductive graphene coating with void space to accommodate the volume expansion of sulfur and to minimize polysulfide dissolution. As a result, the S-nanosphere@G nanocomposite with 91wt% sulfur shows a reversible initial capacity of 970mAhg?1 and an average columbic efficiency>96% over 100 cycles at a rate of 0.2C. Taking the total mass of electrode into account, the S-nanosphere@G composite is a promising cathode material for high energy density LiS batteries.

Ya Liu; Jinxin Guo; Jun Zhang; Qingmei Su; Gaohui Du

2015-01-01T23:59:59.000Z

195

Characterization of a thermophilic sulfur oxidizing enrichment culture dominated by a Sulfolobus sp. obtained from an underground hot spring for use in extreme bioleaching conditions  

Science Journals Connector (OSTI)

A thermoacidophilic elemental sulfur and chalcopyrite oxidizing enrichment culture VS2 was obtained from hot spring run-off sediments of an underground mine. It contained only archaeal species, namely a Sulfolobu...

Virpi L. A. Salo-Zieman; Tarja Sivonen

2006-12-01T23:59:59.000Z

196

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

High-Sulfur...FLUIDIZED-BED COMBUSTORS, COMBUSTION...MAY FLUE GAS DES S E...1971 ). High-sulfur...was brief. Natural gas became...overdependent on natural gas and oil to...elevated pressure with a downward...coals of high ash-fusion...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

197

Method of removal of sulfur from coal and petroleum products  

DOE Patents [OSTI]

A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

1995-01-01T23:59:59.000Z

198

Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...  

Broader source: Energy.gov (indexed) [DOE]

of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of...

199

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Broader source: Energy.gov (indexed) [DOE]

Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

200

Manipulating the Surface Reactions in Lithium Sulfur Batteries...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode Structures. Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode...

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Sulfur nanocrystals anchored graphene composite with highly improved electrochemical performance for lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract Two kinds of graphenesulfur composites with 50wt% of sulfur are prepared using hydrothermal method and thermal mixing, respectively. Transmission Electron Microscopy (TEM) and Energy Dispersive X-ray Spectra mapping show that sulfur nanocrystals with size of ?5nm dispersed on graphene sheets homogeneously for the sample prepared by hydrothermal method (NanoS@G). While for the thermal mixed graphenesulfur composite (SG mixture), sulfur shows larger and uneven size (50200nm). X-ray Photoelectron Spectra (XPS) reveals the strong chemical bonding between the sulfur nanocrystals and graphene. Comparing with the SG mixture, the NanoS@G composite shows highly improved electrochemical performance as cathode for lithiumsulfur (LiS) battery. The NanoS@G composite delivers an initial capacity of 1400mAhg?1 with the sulfur utilization of 83.7% at a current density of 335mAg?1. The capacity keeps above 720mAhg?1 over 100 cycles. The strong adherence of the sulfur nanocrystals on graphene immobilizes sulfur and polysulfides species and suppressed the shuttle effect, resulting higher coulombic efficiency and better capacity retention. Electrochemical impedance also suggests that the strong bonding enabled rapid electronic/ionic transport and improved electrochemical kinetics, therefore good rate capability is obtained. These results demonstrate that the NanoS@G composite is a very promising candidate for high-performance LiS batteries.

Jun Zhang; Zimin Dong; Xiuli Wang; Xuyang Zhao; Jiangping Tu; Qingmei Su; Gaohui Du

2014-01-01T23:59:59.000Z

202

Sulfur-graphene oxide material for lithium-sulfur battery cathodes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sulfur-graphene oxide material for lithium-sulfur battery cathodes Sulfur-graphene oxide material for lithium-sulfur battery cathodes Theoretical specific energy and theoretical energy density Scanning electron micrograph of the GO-S nanocomposite June 2013 Searching for a safer, less expensive alternative to today's lithium-ion batteries, scientists have turned to lithium-sulfur as a possible chemistry for next-generation batteries. Li/S batteries have several times the energy storage capacity of the best currently available rechargeable Li-ion battery, and sulfur is inexpensive and nontoxic. Current batteries using this chemistry, however, suffer from extremely short cycle life-they don't last through many charge-discharge cycles before they fail. A research team led by Elton Cairns and Yuegang Zhang has developed a new

203

Measurement of gas/water uptake coefficients for trace gases active in the marine environment. [Annual report  

SciTech Connect (OSTI)

Ocean produced reduced sulfur compounds including dimethylsulfide (DMS), hydrogen sulfide (H{sub 2}S), carbon disulfide (CS{sub 2}), methyl mercaptan (CH{sub 3}CH) and carbonyl sulfide (OCS) deliver a sulfur burden to the atmosphere which is roughly equal to sulfur oxides produced by fossil fuel combustion. These species and their oxidation products dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO{sub 2}) and methane sulfonic acid (MSA) dominate aerosol and CCN production in clean marine air. Furthermore, oxidation of reduced sulfur species will be strongly influenced by NO{sub x}/O{sub 3} chemistry in marine atmospheres. The multiphase chemical processes for these species must be understood in order to study the evolving role of combustion produced sulfur oxides over the oceans. We have measured the chemical and physical parameters affecting the uptake of reduced sulfur compounds, their oxidation products, ozone, and nitrogen oxides by the ocean`s surface, and marine clouds, fogs, and aerosols. These parameters include: gas/surface mass accommodation coefficients; physical and chemically modified (effective) Henry`s law constants; and surface and liquid phase reaction constants. These parameters are critical to understanding both the interaction of gaseous trace species with cloud and fog droplets and the deposition of trace gaseous species to dew covered, fresh water and marine surfaces.

Davidovits, P. [Boston Coll., Chestnut Hill, MA (United States). Dept. of Chemistry; Worsnop, D.W.; Zahniser, M.S.; Kolb, C.E. [Aerodyne Research, Inc., Billerica, MA (United States). Center for Chemical and Environmental Physics

1992-02-01T23:59:59.000Z

204

Phosphazene groups modified sulfur composites as active cathode materials for rechargeable lithium/sulfur batteries  

Science Journals Connector (OSTI)

A novel phosphazene groups modified sulfur composites cathode [triphosphazene sulfide composite (PS) or nitroanilinetriphosphazene disulfide composite (NPS)] which can give good affinity with electrolytes was...

J. D. Liu; S. Q. Zhang; S. B. Yang; Z. F. Shi; S. T. Zhang; L. K. Wu

2013-11-01T23:59:59.000Z

205

Energy Levels in Sulfur Nuclei  

Science Journals Connector (OSTI)

A study has been made of the proton groups from the reaction of 3.22-Mev deuterons with sulfur in the form, primarily, of H2S gas. The following Q values have been assigned to the reaction S32(dp)S33:6.48,5.69,4.58,4.31,3.63,3.33,2.60,2.33,2.06,1.78,1.37,0.85,and0.18 Mev, corresponding to the ground state and twelve excited states of S33. Four of these groups have been investigated for proton gamma-ray coincidences to confirm this assignment. The yield as a function of deuteron energy has been observed for the six highest energy groups and indication of the presence of some broad resonances found. A qualitative measurement of the variation with angle of relative yields of the groups has indicated a proton intensity distribution that is symmetric for some groups and asymmetric for others. The cross section for the reaction for 90 observation has been found to be 1.2 barns. The mass difference S33-S32 has been calculated to be 0.99963 mass unit.Two low intensity, high energy groups have been assigned to the reaction S33(dp)S34 with Q values of 8.67 and 7.85 Mev. This, together with the above observation, leads to a value of 1.99691 for the mass difference S34-S32.

Perry W. Davison

1949-03-01T23:59:59.000Z

206

Sulfur transformations in early diagenetic sediments from the Bay of Concepcion, off Chile  

SciTech Connect (OSTI)

Despite the recognition that both organic sulfur and pyrite form during the very early stages of diagenesis, and that the amount of H{sub 2}S generated in bacterial sulfate reduction primarily limits their formation, the mechanisms and the active species involved still are not clear. In this study, we quantified the major forms of sulfur distributed in sediments to assess the geochemical mechanisms involved in these transformations. XANES spectroscopy, together with elemental analysis, were used to measure sulfur speciation in the organic-rich sediments from the Bay of Concepcion, Chile. Organic polysulfides constituted the major fraction of the organic sulfur, and occurred maximally just below the sediment surface (1--3 cm), where intermediates from H{sub 2}S oxidation were likely to be generated most abundantly. Sulfonates, which could be formed through the reactions of sulfate and thiosulfate, also showed a sub-surface maximum in the vicinity of the ``oxic-anoxic interface``. These results strongly suggest a geochemical origin for organic polysulfides and sulfonates, and illustrate that intermediates from H{sub 2}S oxidation play a dominant role in incorporating sulfur into organic matter. Pyrite was absent in the surficial layer, and first appeared just below the H{sub 2}S maximum, where organic polysulfides began to decrease in abundance. From these results, we argue, that an iron monosulfide precursor formed first from reactions with H{sub 2}S, and then reacts with organic polysulfides, completing the synthesis of pyrite in the sediment column.

Vairavamurth, M.A.; Wang, Shengke; Khandelwal, B.; Manowitz, B. [Brookhaven National Lab., Upton, NY (United States); Ferdelman, T.; Fossing, H. [Max Plank Institute for Marine Microbiology, Bremen (Germany). Dept. of Biogeochemistry

1995-04-01T23:59:59.000Z

207

Steam reforming utilizing sulfur tolerant catalyst  

SciTech Connect (OSTI)

This patent describes a steam reforming process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of: adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalyst of platinum supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. It also describes a steam process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of steam to the hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalysts consisting essentially of iridium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. In addition a steam reforming process is described for converting hydrocarbon material to hydrogen gas in the presence of sulfur comprising adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity sulfur tolerant catalysts consisting essentially of palladium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina.

Setzer, H.J.; Karavolis, S.; Bett, J.A.S.

1987-09-15T23:59:59.000Z

208

CGC Trace Species Partitioning  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Species Partitioning as Affected Trace Species Partitioning as Affected by Cold Gas Cleanup Conditions: A Thermodynamic Analysis February 10, 2011 DOE/NETL-2011/1503 T r ace Species P ar titioning at C old G as C leanup C onditions Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name,

209

Parallel Seismic Ray Tracing  

E-Print Network [OSTI]

. . . . . . . . . . . . . . . . . . . . . 27 3.4.1 Rotated Take-Off Angle Mesh . . . . . . . . . . . . . . . . . . 28 3.4.2 Rotated Cubed Sphere Mesh . . . . . . . . . . . . . . . . . . . 29 3.4.3 Ray Tube Interpolation . . . . . . . . . . . . . . . . . . . . . . 30 3.5 Theoretical Model..., the ray parameters are defined as ?1 = ?(declination), ?2 = ?(azimuth), and ?3 = ?(travel-time). (b) Suppose we have a unit cube centered at the source point, then a ray can be traced from the source point through an evenly discretized point on the face...

Jain, Tarun K

2013-12-09T23:59:59.000Z

210

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries...

211

THE EFFECT OF ANOLYTE PRODUCT ACID CONCENTRATION ON HYBRID SULFUR CYCLE PERFORMANCE  

SciTech Connect (OSTI)

The Hybrid Sulfur (HyS) cycle (Fig. 1) is one of the simplest, all-fluids thermochemical cycles that has been devised for splitting water with a high-temperature nuclear or solar heat source. It was originally patented by Brecher and Wu in 1975 and extensively developed by Westinghouse in the late 1970s and early 1980s. As its name suggests, the only element used besides hydrogen and oxygen is sulfur, which is cycled between the +4 and +6 oxidation states. HyS comprises two steps. One is the thermochemical (>800 C) decomposition of sulfuric acid (H{sub 2}SO{sub 4}) to sulfur dioxide (SO{sub 2}), oxygen (O{sub 2}), and water. H{sub 2}SO{sub 4} = SO{sub 2} + 1/2 O{sub 2} + H{sub 2}O. The other is the SO{sub 2}-depolarized electrolysis of water to H{sub 2}SO{sub 4} and hydrogen (H{sub 2}), SO{sub 2} + 2 H{sub 2}O = H{sub 2}SO{sub 4} + H{sub 2}, E{sup o} = -0.156 V, explaining the 'hybrid' designation. These two steps taken together split water into H{sub 2} and O{sub 2} using heat and electricity. Researchers at the Savannah River National Laboratory (SRNL) and at the University of South Carolina (USC) have successfully demonstrated the use of proton exchange membrane (PEM) electrolyzers (Fig. 2) for the SO{sub 2}-depolarized electrolysis (sulfur oxidation) step, while Sandia National Laboratories (SNL) successfully demonstrated the high-temperature sulfuric acid decomposition (sulfur reduction) step using a bayonet-type reactor (Fig. 3). This latter work was performed as part of the Sulfur-Iodine (SI) cycle Integrated Laboratory Scale demonstration at General Atomics (GA). The combination of these two operations results in a simple process that will be more efficient and cost-effective for the massive production of hydrogen than alkaline electrolysis. Recent developments suggest that the use of PEMs other than Nafion will allow sulfuric acid to be produced at higher concentrations (>60 wt%), offering the possibility of net thermal efficiencies around 50% (HHV basis). The effect of operation at higher anolyte concentrations on the flowsheet, and on the net thermal efficiency for a nuclear-heated HyS process, is examined and quantified.

Gorensek, M.; Summers, W.

2010-03-24T23:59:59.000Z

212

An Aerosol Condensation Model for Sulfur Trioxide  

SciTech Connect (OSTI)

This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

Grant, K E

2008-02-07T23:59:59.000Z

213

MeTAGeM-Trace: Improving trace generation in model transformation by leveraging the role of transformation models  

Science Journals Connector (OSTI)

Abstract In the context of Model-Driven Engineering (MDE), generation of traces can be automated using the implicit traceability relationships contained in any model transformation. Besides, if transformations are developed adopting a Model-Driven Engineering (MDE) approach, i.e. promoting the role of models and the level of automation, model transformation will benefit from the promised advantages of MDE in terms of less costly software development while reducing the inherent complexity of coding model transformations. To put these ideas into practice, this work introduces MeTAGeM-Trace, the first prototype of an EMF-based toolkit for the MDD of model-to-model transformations which supports trace generation, i.e. it allows developing model transformations that produce not only the corresponding target models, but also a trace model between the elements of the source and target models involved in the transformation.

lvaro Jimnez; Juan M. Vara; Vernica A. Bollati; Esperanza Marcos

2015-01-01T23:59:59.000Z

214

Ray-tracing for coordinate knowledge in the JWST Integrated Science Instrument Module  

Science Journals Connector (OSTI)

We describe the matrix/vector ray tracing methods used to maintain pupil and image position knowledge in the James Webb Space Telescope Optical Telescope Element Simulator. These prove...

Sabatke, Derek S

215

SULFUR POLYMER STABILIZATION/SOLIDIFICATION (SPSS) TREATABILITY OF LOS ALAMOS NATIONAL LABORATORY MERCURY WASTE.  

SciTech Connect (OSTI)

Brookhaven National Laboratory's Sulfur Polymer Stabilization/Solidification (SPSS) process was used to treat approximately 90kg of elemental mercury mixed waste from Los Alamos National Laboratory. Treatment was carried out in a series of eight batches using a 1 ft{sup 3} pilot-scale mixer, where mercury loading in each batch was 33.3 weight percent. Although leach performance is currently not regulated for amalgamated elemental mercury (Hg) mixed waste, Toxicity Characteristic Leach Procedure (TCLP) testing of SPSS treated elemental mercury waste indicates that leachability is readily reduced to below the TCLP limit of 200 ppb (regulatory requirement following treatment by retort for wastes containing > 260 ppb Hg), and with process optimization, to levels less than the stringent Universal Treatment Standard (UTS) limit of 25 ppb that is applied to waste containing < 260 ppm Hg. In addition, mercury-contaminated debris, consisting of primary glass and plastic containers, as well as assorted mercury thermometers, switches, and labware, was first reacted with SPSS components to stabilize the mercury contamination, then macroencapsulated in the molten SPSS product. This treatment was done by vigorous agitation of the sulfur polymer powder and the comminuted debris. Larger plastic and metal containers were reacted to stabilize internal mercury contamination, and then filled with molten sulfur polymer to encapsulate the treated product.

ADAMS,J.W.; KALB,P.D.

2001-11-01T23:59:59.000Z

216

Safety considerations for the use of sulfur in sulfur-modified pavement materials  

E-Print Network [OSTI]

on the surround1ng environment. As sulfur-modified paving materials were being developed, there was a corresponding concern for studying the amounts of gaseous emiss1ons that were generated. The Texas Trans- portat1on Inst1tute (TTI) was one of the first... organizations in the United States to become 1nvolved in the research and development of sulfur-modified pavements, Throughout 1ts laboratory stud1es TTI cont1nually mon1tored hydrogen sulf1de (H25) and sulfur d1oxide (502) em1ssions produced during mix...

Jacobs, Carolyn Yuriko

2012-06-07T23:59:59.000Z

217

Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline  

Broader source: Energy.gov [DOE]

Sulfur naturally occurs in gasoline and diesel fuel, contributing to pollution when the fuel is burned. Beginning in 2004, standards were set on the amount of sulfur in gasoline (Tier 2 standards)....

218

Can Sulfur Spectroscopy the Vasa?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Title Title by Magnus Sandström*, Farideh Jalilehvand, Ingmar Persson, Ulrik Gelius and Patrick Frank The famous 17th-century Swedish warship Vasa has been on display in the Vasa Museum since 1990 (Figure 1). The Vasa sank on its maiden voyage in 1628, and was recovered in 1961 after 333 years in the cold brackish water of Stockholm harbor. After extensive conservation treatment, the oaken Vasa appeared in good condition (1). Figure 1. The Vasa on display in the Vasa Museum, Stockholm, Sweden. Dimensions: length 61 m (69 m including bowsprit), maximum width 11.7 m, stern castle 19.3 m high, displacement 1210 tons. (photo by Hans Hammarskiöld at the Vasa Museum). Reproduced by permission, (http://www.nature.com/). However, high acidity and a rapid spread of sulfate salts and elemental

219

BIOLOGICAL TRACE ELEMENT RESEARCH 6, 159-A Minireview  

E-Print Network [OSTI]

). 'Conver!iion from wet weight as!iuming 80% moisture. Biomagnification Biomagnification. the process wherl

Canberra, University of

220

A baseline characterization of trace elements in Texas soils  

E-Print Network [OSTI]

A baseline survey of concentrations of Mn, Fe, Zn, Cu, Se, As, Cd, Cr, Co, Pb, Ba, and Ni was performed for 100 soils from seven Land Resource Areas of Texas. Nearly 300 soil samples from the upper, middle, and lower depths of selected pedons were...

Frybarger, Mary Rita

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

The Leaching of Major and Trace Elements from Coal Ash  

Science Journals Connector (OSTI)

Most power stations currently operate wet ash disposal systems. However, this method of ash disposal is being subjected to increasing scrutiny as there is a potential for contamination of surface and groundwat...

D. R. Jones

1995-01-01T23:59:59.000Z

222

Nondestructive indices of trace element exposure in squamate reptiles  

E-Print Network [OSTI]

a , J.W. Snodgrass c , B.P. Jackson a , D.E Kling a , C.L. Rowe d , J.D. Congdon a a Savannah River Ecology Laboratory, University of Georgia, Aiken, SC 29802, USA b Department of Biological Sciences, snakes were either fed ®sh from a coal ash-contaminated site or uncontaminated food from a reference site

Hopkins, William A.

223

Trace elements in prehispanic hair samples of Gran Canaria  

Science Journals Connector (OSTI)

In the present study we have analysed hair Zn, Cu, Fe, Mn, Sr, Pb and Ca contents of 8 prehispanic hair specimens from Gran Canaria, comparing them with 10 acutal samples,...

E. Gonzlez-Reimers; M. Arnay-de-la-Rosa; V. Castro-Alemn

1991-04-01T23:59:59.000Z

224

ORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation  

E-Print Network [OSTI]

). Methylotrophs and iron oxidizers were also active in plume waters and expressed key proteins for methane by bacteria (especially, alpha-, gamma- and epsilon-proteobacteria) that likely participate in the oxidationORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation at a biogeochemical hot spot in the dark

Hansell, Dennis

225

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

...amounts of coal, because...Director-Mineral Re-sources...of Gas from Coal through a...on coals of high ash-fusion temperature...per ton of high-sulfur coal burned. Absorp-tion...particulate matter as well as...capable of remov-ing up to...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

226

Short communication Influence of molybdenum and sulfur on copper  

E-Print Network [OSTI]

Short communication Influence of molybdenum and sulfur on copper metabolism in sheep: comparison of molybdenum able to trigger the copper sulfur molybdenum interference in sheep was measured with either only) and 4 increasing molybdenum doses. The sulfur-molybdenum-copper interference was quantified

Paris-Sud XI, Université de

227

A novel lithium/sulfur battery based on sulfur/graphene nanosheet composite cathode and gel polymer electrolyte  

Science Journals Connector (OSTI)

A novel sulfur/graphene nanosheet (S/GNS) composite was prepared ... ball milling of sulfur with commercial multi-layer graphene nanosheet, followed by a heat treatment. ... of irregularly interlaced nanosheet-li...

Yongguang Zhang; Yan Zhao; Zhumabay Bakenov

2014-03-01T23:59:59.000Z

228

A simple approach to synthesize nanosized sulfur/graphene oxide materials for high-performance lithium/sulfur batteries  

Science Journals Connector (OSTI)

We report on a simple and facile synthesis route for the sulfur/graphene oxide composite via ultrasonic mixing of the nano-sulfur and graphene oxide aqueous suspensions followed by a low-temperature heat treat...

Yongguang Zhang; Yan Zhao; Zhumabay Bakenov

2014-07-01T23:59:59.000Z

229

Sulfur in the Timbers of Henry VIII's Warship Mary Rose: Synchrotrons  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sulfur in the Timbers of Henry Sulfur in the Timbers of Henry VIII's Warship Mary Rose: Synchrotrons Illuminate Conservation Concerns Magnus Sandström,1 Farideh Jalilehvand,2 Emiliana Damian,1 Yvonne Fors,1 Ulrik Gelius,3 Mark Jones,4 and Murielle Salomé5 1Structural Chemistry, Stockholm University, Sweden 2Department of Chemistry, University of Calgary, Alberta, Canada 3Department of Physics, Uppsala University, Sweden 4The Mary Rose Trust, HM Naval Base, Portsmouth, UK 5European Synchrotron Radiation Facility (ESRF), Grenoble, France Figure 1.The starboard side of the Mary Rose (about ½ of the hull, ~280 tons oak timbers) is since 1994 being sprayed with an aqueous solution of PEG 200. Figure 2. Sulfur K-edge XANES spectrum of Mary Rose oak core surface (0-3 mm). Standard spectra used for model fitting: 1 (solution), 1' (solid) disulfides R-SS-R (cystine with peaks at 2472.7 and 2474.4 eV); 45%; 2: Thiols R-SH (cysteine, 2473.6 eV) 23%; 3: Elemental sulfur (S8 in xylene 2473.0 eV) 10%; 4: Sulfoxide R(SO)R' (methionine sulfoxide, 2476.4 eV) 5%; 5: Sulfonate R-SO3- (methyl sulfonate, 2481.2 eV) 10%; 6: Sulfate SO42- (sodium sulfate, 2482.6 eV) 7%.

230

Graphene-Wrapped Sulfur Particles as a Rechargeable LithiumSulfur Battery Cathode Material with High Capacity and Cycling Stability  

Science Journals Connector (OSTI)

Graphene-Wrapped Sulfur Particles as a Rechargeable LithiumSulfur Battery Cathode Material with High Capacity and Cycling Stability ... The resulting graphenesulfur composite showed high and stable specific capacities up to ?600 mAh/g over more than 100 cycles, representing a promising cathode material for rechargeable lithium batteries with high energy density. ...

Hailiang Wang; Yuan Yang; Yongye Liang; Joshua Tucker Robinson; Yanguang Li; Ariel Jackson; Yi Cui; Hongjie Dai

2011-06-24T23:59:59.000Z

231

It's Elemental - The Element Europium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Samarium Samarium Previous Element (Samarium) The Periodic Table of Elements Next Element (Gadolinium) Gadolinium The Element Europium [Click for Isotope Data] 63 Eu Europium 151.964 Atomic Number: 63 Atomic Weight: 151.964 Melting Point: 1095 K (822°C or 1512°F) Boiling Point: 1802 K (1529°C or 2784°F) Density: 5.24 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: none Group Name: Lanthanide What's in a name? Named after the continent of Europe. Say what? Europium is pronounced as yoo-RO-pee-em. History and Uses: Europium was discovered by Eugène-Antole Demarçay, a French chemist, in 1896. Demarçay suspected that samples of a recently discovered element, samarium, were contaminated with an unknown element. He was able to produce

232

It's Elemental - The Element Potassium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Argon Argon Previous Element (Argon) The Periodic Table of Elements Next Element (Calcium) Calcium The Element Potassium [Click for Isotope Data] 19 K Potassium 39.0983 Atomic Number: 19 Atomic Weight: 39.0983 Melting Point: 336.53 K (63.38°C or 146.08°F) Boiling Point: 1032 K (759°C or 1398°F) Density: 0.89 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 1 Group Name: Alkali Metal What's in a name? From the English word potash. Potassium's chemical symbol comes from the Latin word for alkali, kalium. Say what? Potassium is pronounced as poh-TASS-ee-em. History and Uses: Although potassium is the eighth most abundant element on earth and comprises about 2.1% of the earth's crust, it is a very reactive element

233

It's Elemental - The Element Magnesium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sodium Sodium Previous Element (Sodium) The Periodic Table of Elements Next Element (Aluminum) Aluminum The Element Magnesium [Click for Isotope Data] 12 Mg Magnesium 24.3050 Atomic Number: 12 Atomic Weight: 24.3050 Melting Point: 923 K (650°C or 1202°F) Boiling Point: 1363 K (1090°C or 1994°F) Density: 1.74 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 3 Group Number: 2 Group Name: Alkaline Earth Metal What's in a name? For Magnesia, a district in the region of Thessaly, Greece. Say what? Magnesium is pronounced as mag-NEE-zhi-em. History and Uses: Although it is the eighth most abundant element in the universe and the seventh most abundant element in the earth's crust, magnesium is never found free in nature. Magnesium was first isolated by Sir Humphry Davy, an

234

CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER  

SciTech Connect (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

Hobbs, D; Hector Colon-Mercado, H

2007-01-31T23:59:59.000Z

235

Method to prevent sulfur accumulation in membrane electrode assembly  

DOE Patents [OSTI]

A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

Steimke, John L; Steeper, Timothy J; Herman, David T

2014-04-29T23:59:59.000Z

236

Compound and Elemental Analysis At Kilauea East Rift Geothermal...  

Open Energy Info (EERE)

(XRF). The samples were made into thin sections as well as ground in a tungsten carbide grinding mill. A table of trace elements and amounts found during the analysis is...

237

Heat-Traced Fluid Transfer Lines  

E-Print Network [OSTI]

This paper discusses basic considerations in designing a heat tracing system using either team or electrical tracing. Four basic reasons to heat trace are dealt with: water freeze protection, chemical freeze protection, viscosity maintenance...

Schilling, R. E.

1984-01-01T23:59:59.000Z

238

Tracing Geothermal Fluids  

SciTech Connect (OSTI)

Geothermal water must be injected back into the reservoir after it has been used for power production. Injection is critical in maximizing the power production and lifetime of the reservoir. To use injectate effectively the direction and velocity of the injected water must be known or inferred. This information can be obtained by using chemical tracers to track the subsurface flow paths of the injected fluid. Tracers are chemical compounds that are added to the water as it is injected back into the reservoir. The hot production water is monitored for the presence of this tracer using the most sensitive analytic methods that are economically feasible. The amount and concentration pattern of the tracer revealed by this monitoring can be used to evaluate how effective the injection strategy is. However, the tracers must have properties that suite the environment that they will be used in. This requires careful consideration and testing of the tracer properties. In previous and parallel investigations we have developed tracers that are suitable from tracing liquid water. In this investigation, we developed tracers that can be used for steam and mixed water/steam environments. This work will improve the efficiency of injection management in geothermal fields, lowering the cost of energy production and increasing the power output of these systems.

Michael C. Adams; Greg Nash

2004-03-01T23:59:59.000Z

239

It's Elemental - The Element Nitrogen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Carbon Previous Element (Carbon) The Periodic Table of Elements Next Element (Oxygen) Oxygen The Element Nitrogen [Click for Isotope Data] 7 N Nitrogen 14.0067 Atomic Number: 7 Atomic Weight: 14.0067 Melting Point: 63.15 K (-210.00°C or -346.00°F) Boiling Point: 77.36 K (-195.79°C or -320.44°F) Density: 0.0012506 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 15 Group Name: Pnictogen What's in a name? From the Greek words nitron and genes, which together mean "saltpetre forming." Say what? Nitrogen is pronounced as NYE-treh-gen. History and Uses: Nitrogen was discovered by the Scottish physician Daniel Rutherford in 1772. It is the fifth most abundant element in the universe and makes up

240

It's Elemental - The Element Sodium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Neon Neon Previous Element (Neon) The Periodic Table of Elements Next Element (Magnesium) Magnesium The Element Sodium [Click for Isotope Data] 11 Na Sodium 22.98976928 Atomic Number: 11 Atomic Weight: 22.98976928 Melting Point: 370.95 K (97.80°C or 208.04°F) Boiling Point: 1156 K (883°C or 1621°F) Density: 0.97 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 3 Group Number: 1 Group Name: Alkali Metal What's in a name? From the English word soda and from the Medieval Latin word sodanum, which means "headache remedy." Sodium's chemical symbol comes from the Latin word for sodium carbonate, natrium. Say what? Sodium is pronounced as SO-dee-em. History and Uses: Although sodium is the sixth most abundant element on earth and comprises

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

It's Elemental - The Element Francium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Radon Radon Previous Element (Radon) The Periodic Table of Elements Next Element (Radium) Radium The Element Francium [Click for Isotope Data] 87 Fr Francium 223 Atomic Number: 87 Atomic Weight: 223 Melting Point: 300 K (27°C or 81°F) Boiling Point: Unknown Density: Unknown Phase at Room Temperature: Solid Element Classification: Metal Period Number: 7 Group Number: 1 Group Name: Alkali Metal Radioactive What's in a name? Named for the country of France. Say what? Francium is pronounced as FRAN-see-em. History and Uses: Francium was discovered by Marguerite Catherine Perey, a French chemist, in 1939 while analyzing actinium's decay sequence. Although considered a natural element, scientists estimate that there is no more than one ounce of francium in the earth's crust at one time. Since there is so little

242

It's Elemental - The Element Cerium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lanthanum Lanthanum Previous Element (Lanthanum) The Periodic Table of Elements Next Element (Praseodymium) Praseodymium The Element Cerium [Click for Isotope Data] 58 Ce Cerium 140.116 Atomic Number: 58 Atomic Weight: 140.116 Melting Point: 1071 K (798°C or 1468°F) Boiling Point: 3697 K (3424°C or 6195°F) Density: 6.770 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: none Group Name: Lanthanide What's in a name? Named for the asteroid Ceres. Say what? Cerium is pronounced as SER-ee-em. History and Uses: Cerium was discovered by Jöns Jacob Berzelius and Wilhelm von Hisinger, Swedish chemists, and independently by Martin Heinrich Klaproth, a German chemist, in 1803. Cerium is the most abundant of the rare earth elements

243

It's Elemental - The Element Neon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fluorine Fluorine Previous Element (Fluorine) The Periodic Table of Elements Next Element (Sodium) Sodium The Element Neon [Click for Isotope Data] 10 Ne Neon 20.1797 Atomic Number: 10 Atomic Weight: 20.1797 Melting Point: 24.56 K (-248.59°C or -415.46°F) Boiling Point: 27.07 K (-246.08°C or -410.94°F) Density: 0.0008999 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 18 Group Name: Noble Gas What's in a name? From the Greek word for new, neos. Say what? Neon is pronounced as NEE-on. History and Uses: Neon was discovered by Sir William Ramsay, a Scottish chemist, and Morris M. Travers, an English chemist, shortly after their discovery of the element krypton in 1898. Like krypton, neon was discovered through the

244

It's Elemental - The Element Technetium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Molybdenum Molybdenum Previous Element (Molybdenum) The Periodic Table of Elements Next Element (Ruthenium) Ruthenium The Element Technetium [Click for Isotope Data] 43 Tc Technetium 98 Atomic Number: 43 Atomic Weight: 98 Melting Point: 2430 K (2157°C or 3915°F) Boiling Point: 4538 K (4265°C or 7709°F) Density: 11 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 5 Group Number: 7 Group Name: none Radioactive and Artificially Produced What's in a name? From the Greek word for artificial, technetos. Say what? Technetium is pronounced as tek-NEE-she-em. History and Uses: Technetium was the first artificially produced element. It was isolated by Carlo Perrier and Emilio Segrè in 1937. Technetium was created by bombarding molybdenum atoms with deuterons that had been accelerated by a

245

It's Elemental - The Element Cobalt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Iron Iron Previous Element (Iron) The Periodic Table of Elements Next Element (Nickel) Nickel The Element Cobalt [Click for Isotope Data] 27 Co Cobalt 58.933195 Atomic Number: 27 Atomic Weight: 58.933195 Melting Point: 1768 K (1495°C or 2723°F) Boiling Point: 3200 K (2927°C or 5301°F) Density: 8.86 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 9 Group Name: none What's in a name? From the German word for goblin or evil spirit, kobald and the Greek word for mine, cobalos. Say what? Cobalt is pronounced as KO-bolt. History and Uses: Cobalt was discovered by Georg Brandt, a Swedish chemist, in 1739. Brandt was attempting to prove that the ability of certain minerals to color glass blue was due to an unknown element and not to bismuth, as was commonly

246

It's Elemental - The Element Bromine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Selenium Selenium Previous Element (Selenium) The Periodic Table of Elements Next Element (Krypton) Krypton The Element Bromine [Click for Isotope Data] 35 Br Bromine 79.904 Atomic Number: 35 Atomic Weight: 79.904 Melting Point: 265.95 K (-7.2°C or 19.0°F) Boiling Point: 331.95 K (58.8°C or 137.8°F) Density: 3.11 grams per cubic centimeter Phase at Room Temperature: Liquid Element Classification: Non-metal Period Number: 4 Group Number: 17 Group Name: Halogen What's in a name? From the Greek word for stench, bromos. Say what? Bromine is pronounced as BRO-meen. History and Uses: The only nonmetallic element that is a liquid at normal room temperatures, bromine was produced by Carl Löwig, a young chemistry student, the summer before starting his freshman year at Heidelberg. When he showed his

247

It's Elemental - The Element Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen Nitrogen Previous Element (Nitrogen) The Periodic Table of Elements Next Element (Fluorine) Fluorine The Element Oxygen [Click for Isotope Data] 8 O Oxygen 15.9994 Atomic Number: 8 Atomic Weight: 15.9994 Melting Point: 54.36 K (-218.79°C or -361.82°F) Boiling Point: 90.20 K (-182.95°C or -297.31°F) Density: 0.001429 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 16 Group Name: Chalcogen What's in a name? From the greek words oxys and genes, which together mean "acid forming." Say what? Oxygen is pronounced as OK-si-jen. History and Uses: Oxygen had been produced by several chemists prior to its discovery in 1774, but they failed to recognize it as a distinct element. Joseph

248

It's Elemental - The Element Manganese  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chromium Chromium Previous Element (Chromium) The Periodic Table of Elements Next Element (Iron) Iron The Element Manganese [Click for Isotope Data] 25 Mn Manganese 54.938045 Atomic Number: 25 Atomic Weight: 54.938045 Melting Point: 1519 K (1246°C or 2275°F) Boiling Point: 2334 K (2061°C or 3742°F) Density: 7.3 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 7 Group Name: none What's in a name? From the Latin word for magnet, magnes. Say what? Manganese is pronounced as MAN-ge-nees. History and Uses: Proposed to be an element by Carl Wilhelm Scheele in 1774, manganese was discovered by Johan Gottlieb Gahn, a Swedish chemist, by heating the mineral pyrolusite (MnO2) in the presence of charcoal later that year.

249

It's Elemental - The Element Titanium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Scandium Scandium Previous Element (Scandium) The Periodic Table of Elements Next Element (Vanadium) Vanadium The Element Titanium [Click for Isotope Data] 22 Ti Titanium 47.867 Atomic Number: 22 Atomic Weight: 47.867 Melting Point: 1941 K (1668°C or 3034°F) Boiling Point: 3560 K (3287°C or 5949°F) Density: 4.5 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 4 Group Name: none What's in a name? From the Greek word Titans, the mythological "first sons of the Earth." Say what? Titanium is pronounced as tie-TAY-nee-em. History and Uses: Titanium was discovered in 1791 by the Reverend William Gregor, an English pastor. Pure titanium was first produced by Matthew A. Hunter, an American metallurgist, in 1910. Titanium is the ninth most abundant element in the

250

sulfur dioxide emissions | OpenEI  

Open Energy Info (EERE)

sulfur dioxide emissions sulfur dioxide emissions Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides

251

Sulfur-isotope separation by distillation  

SciTech Connect (OSTI)

Sulfur-isotope separation by low-temperature distillation of hydrogen sulfide was studied in an 8-m, 25-mm diameter distillation column. Column temperature was controlled by a propane-propylene heat pipe. Column packing HETP was measured using nitric oxide in the column. The column was operated at pressures from 45 to 125 kPa. The relative volatility of S-32 vs. S-34 varied from 1.0008 to 1.0014.

Mills, T.R.

1982-01-01T23:59:59.000Z

252

Development of the Hybrid Sulfur Thermochemical Cycle  

SciTech Connect (OSTI)

The production of hydrogen via the thermochemical splitting of water is being considered as a primary means for utilizing the heat from advanced nuclear reactors to provide fuel for a hydrogen economy. The Hybrid Sulfur (HyS) Process is one of the baseline candidates identified by the U.S. Department of Energy [1] for this purpose. The HyS Process is a two-step hybrid thermochemical cycle that only involves sulfur, oxygen and hydrogen compounds. Recent work has resulted in an improved process design with a calculated overall thermal efficiency (nuclear heat to hydrogen, higher heating value basis) approaching 50%. Economic analyses indicate that a nuclear hydrogen plant employing the HyS Process in conjunction with an advanced gas-cooled nuclear reactor system can produce hydrogen at competitive prices. Experimental work has begun on the sulfur dioxide depolarized electrolyzer, the major developmental component in the cycle. Proof-of-concept tests have established proton-exchange-membrane cells (a state-of-the-art technology) as a viable approach for conducting this reaction. This is expected to lead to more efficient and economical cell designs than were previously available. Considerable development and scale-up issues remain to be resolved, but the development of a viable commercial-scale HyS Process should be feasible in time to meet the commercialization schedule for Generation IV gas-cooled nuclear reactors.

Summers, William A.; Steimke, John L

2005-09-23T23:59:59.000Z

253

Trace 700 | Open Energy Information  

Open Energy Info (EERE)

Trace 700 Trace 700 Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Trace 700 Agency/Company /Organization: Trane Sector: Energy Focus Area: Buildings, Energy Efficiency Topics: Technology characterizations Resource Type: Software/modeling tools Website: www.trane.com/Commercial/Dna/View.aspx?i=1136 References: http://www.trane.com/Commercial/Dna/View.aspx?i=1136 Detailed HVAC design tool. Can provide heating and cooling load calculation, system sizing, and energy use. A fairly thorough understanding of HVAC is necessary to use this tool. Tool Summary LAUNCH TOOL Name: Trace 700 Agency/Company /Organization: Trane Phase: Create a Vision, Determine Baseline, "Evaluate Options and Determine Feasibility" is not in the list of possible values (Bring the Right People Together, Create a Vision, Determine Baseline, Evaluate Options, Develop Goals, Prepare a Plan, Get Feedback, Develop Finance and Implement Projects, Create Early Successes, Evaluate Effectiveness and Revise as Needed) for this property.

254

It's Elemental - The Element Astatine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Polonium Polonium Previous Element (Polonium) The Periodic Table of Elements Next Element (Radon) Radon The Element Astatine [Click for Isotope Data] 85 At Astatine 210 Atomic Number: 85 Atomic Weight: 210 Melting Point: 575 K (302°C or 576°F) Boiling Point: Unknown Density: about 7 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Semi-metal Period Number: 6 Group Number: 17 Group Name: Halogen Radioactive What's in a name? From the Greek word for unstable, astatos. Say what? Astatine is pronounced as AS-teh-teen or as AS-teh-ten. History and Uses: Astatine was produced by Dale R. Carson, K.R. MacKenzie and Emilio Segrè by bombarding an isotope of bismuth, bismuth-209, with alpha particles that had been accelerated in a device called a cyclotron. This created

255

It's Elemental - The Element Copper  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nickel Nickel Previous Element (Nickel) The Periodic Table of Elements Next Element (Zinc) Zinc The Element Copper [Click for Isotope Data] 29 Cu Copper 63.546 Atomic Number: 29 Atomic Weight: 63.546 Melting Point: 1357.77 K (1084.62°C or 1984.32°F) Boiling Point: 2835 K (2562°C or 4644°F) Density: 8.933 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 11 Group Name: none What's in a name? From the Latin word cuprum, which means "from the island of Cyprus." Say what? Copper is pronounced as KOP-er. History and Uses: Archaeological evidence suggests that people have been using copper for at least 11,000 years. Relatively easy to mine and refine, people discovered methods for extracting copper from its ores at least 7,000 years ago. The

256

It's Elemental - The Element Gadolinium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Europium Europium Previous Element (Europium) The Periodic Table of Elements Next Element (Terbium) Terbium The Element Gadolinium [Click for Isotope Data] 64 Gd Gadolinium 157.25 Atomic Number: 64 Atomic Weight: 157.25 Melting Point: 1586 K (1313°C or 2395°F) Boiling Point: 3546 K (3273°C or 5923°F) Density: 7.90 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: none Group Name: Lanthanide What's in a name? Named for the mineral gadolinite which was named after Johan Gadolin, a Finnish chemist. Say what? Gadolinium is pronounced as GAD-oh-LIN-ee-em. History and Uses: Spectroscopic evidence for the existence of gadolinium was first observed by the Swiss chemist Jean Charles Galissard de Marignac in the minerals

257

It's Elemental - The Element Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gold Gold Previous Element (Gold) The Periodic Table of Elements Next Element (Thallium) Thallium The Element Mercury [Click for Isotope Data] 80 Hg Mercury 200.59 Atomic Number: 80 Atomic Weight: 200.59 Melting Point: 234.32 K (-38.83°C or -37.89°F) Boiling Point: 629.88 K (356.73°C or 674.11°F) Density: 13.5336 grams per cubic centimeter Phase at Room Temperature: Liquid Element Classification: Metal Period Number: 6 Group Number: 12 Group Name: none What's in a name? Named after the planet Mercury. Mercury's chemical symbol comes from the Greek word hydrargyrum, which means "liquid silver." Say what? Mercury is pronounced as MER-kyoo-ree. History and Uses: Mercury was known to the ancient Chinese and Hindus and has been found in 3500 year old Egyptian tombs. Mercury is not usually found free in nature

258

It's Elemental - The Element Hafnium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lutetium Lutetium Previous Element (Lutetium) The Periodic Table of Elements Next Element (Tantalum) Tantalum The Element Hafnium [Click for Isotope Data] 72 Hf Hafnium 178.49 Atomic Number: 72 Atomic Weight: 178.49 Melting Point: 2506 K (2233°C or 4051°F) Boiling Point: 4876 K (4603°C or 8317°F) Density: 13.3 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 4 Group Name: none What's in a name? From the Latin word for the city of Copenhagen, Hafnia. Say what? Hafnium is pronounced as HAF-neeem. History and Uses: Hafnium was discovered by Dirk Coster, a Danish chemist, and Charles de Hevesy, a Hungarian chemist, in 1923. They used a method known as X-ray spectroscopy to study the arrangement of the outer electrons of atoms in

259

It's Elemental - The Element Boron  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Beryllium Beryllium Previous Element (Beryllium) The Periodic Table of Elements Next Element (Carbon) Carbon The Element Boron [Click for Isotope Data] 5 B Boron 10.811 Atomic Number: 5 Atomic Weight: 10.811 Melting Point: 2348 K (2075°C or 3767°F) Boiling Point: 4273 K (4000°C or 7232°F) Density: 2.37 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Semi-metal Period Number: 2 Group Number: 13 Group Name: none What's in a name? From the Arabic word Buraq and the Persian word Burah, which are both words for the material "borax." Say what? Boron is pronounced as BO-ron. History and Uses: Boron was discovered by Joseph-Louis Gay-Lussac and Louis-Jaques Thénard, French chemists, and independently by Sir Humphry Davy, an English chemist,

260

It's Elemental - The Element Thorium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Actinium Actinium Previous Element (Actinium) The Periodic Table of Elements Next Element (Protactinium) Protactinium The Element Thorium [Click for Isotope Data] 90 Th Thorium 232.03806 Atomic Number: 90 Atomic Weight: 232.03806 Melting Point: 2023 K (1750°C or 3182°F) Boiling Point: 5061 K (4788°C or 8650°F) Density: 11.72 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 7 Group Number: none Group Name: Actinide Radioactive What's in a name? Named for the Scandinavian god of war, Thor. Say what? Thorium is pronounced as THOR-ee-em or as THO-ree-em. History and Uses: Thorium was discovered by Jöns Jacob Berzelius, a Swedish chemist, in 1828. He discovered it in a sample of a mineral that was given to him by the Reverend Has Morten Thrane Esmark, who suspected that it contained an

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

It's Elemental - The Element Chromium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Vanadium Vanadium Previous Element (Vanadium) The Periodic Table of Elements Next Element (Manganese) Manganese The Element Chromium [Click for Isotope Data] 24 Cr Chromium 51.9961 Atomic Number: 24 Atomic Weight: 51.9961 Melting Point: 2180 K (1907°C or 3465°F) Boiling Point: 2944 K (2671°C or 4840°F) Density: 7.15 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 6 Group Name: none What's in a name? From the Greek word for color, chroma. Say what? Chromium is pronounced as KROH-mee-em. History and Uses: Chromium was discovered by Louis-Nicholas Vauquelin while experimenting with a material known as Siberian red lead, also known as the mineral crocoite (PbCrO4), in 1797. He produced chromium oxide (CrO3) by mixing

262

It's Elemental - The Element Iron  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Manganese Manganese Previous Element (Manganese) The Periodic Table of Elements Next Element (Cobalt) Cobalt The Element Iron [Click for Isotope Data] 26 Fe Iron 55.845 Atomic Number: 26 Atomic Weight: 55.845 Melting Point: 1811 K (1538°C or 2800°F) Boiling Point: 3134 K (2861°C or 5182°F) Density: 7.874 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 8 Group Name: none What's in a name? From the Anglo-Saxon word iron. Iron's chemical symbol comes from the Latin word for iron, ferrum. Say what? Iron is pronounced as EYE-ern. History and Uses: Archaeological evidence suggests that people have been using iron for at least 5000 years. Iron is the cheapest and one of the most abundant of all metals, comprising nearly 5.6% of the earth's crust and nearly all of the

263

It's Elemental - The Element Molybdenum  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Niobium Niobium Previous Element (Niobium) The Periodic Table of Elements Next Element (Technetium) Technetium The Element Molybdenum [Click for Isotope Data] 42 Mo Molybdenum 95.96 Atomic Number: 42 Atomic Weight: 95.96 Melting Point: 2896 K (2623°C or 4753°F) Boiling Point: 4912 K (4639°C or 8382°F) Density: 10.2 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 5 Group Number: 6 Group Name: none What's in a name? From the Greek word for lead, molybdos. Say what? Molybdenum is pronounced as meh-LIB-deh-nem. History and Uses: Molybdenum was discovered by Carl Welhelm Scheele, a Swedish chemist, in 1778 in a mineral known as molybdenite (MoS2) which had been confused as a lead compound. Molybdenum was isolated by Peter Jacob Hjelm in 1781. Today,

264

It's Elemental - The Element Cesium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Xenon Xenon Previous Element (Xenon) The Periodic Table of Elements Next Element (Barium) Barium The Element Cesium [Click for Isotope Data] 55 Cs Cesium 132.9054519 Atomic Number: 55 Atomic Weight: 132.9054519 Melting Point: 301.59 K (28.44°C or 83.19°F) Boiling Point: 944 K (671°C or 1240°F) Density: 1.93 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 1 Group Name: Alkali Metal What's in a name? From the Latin word for sky blue, caesius. Say what? Cesium is pronounced as SEE-zee-em. History and Uses: Cesium was discovered by Robert Wilhelm Bunsen and Gustav Robert Kirchhoff, German chemists, in 1860 through the spectroscopic analysis of Durkheim mineral water. They named cesium after the blue lines they observed in its

265

It's Elemental - The Element Iridium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Osmium Osmium Previous Element (Osmium) The Periodic Table of Elements Next Element (Platinum) Platinum The Element Iridium [Click for Isotope Data] 77 Ir Iridium 192.217 Atomic Number: 77 Atomic Weight: 192.217 Melting Point: 2719 K (2446°C or 4435°F) Boiling Point: 4701 K (4428°C or 8002°F) Density: 22.42 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 9 Group Name: none What's in a name? From the Latin word for rainbow, iris. Say what? Iridium is pronounced as i-RID-ee-em. History and Uses: Iridium and osmium were discovered at the same time by the British chemist Smithson Tennant in 1803. Iridium and osmium were identified in the black residue remaining after dissolving platinum ore with aqua regia, a mixture

266

It's Elemental - The Element Platinum  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Iridium Iridium Previous Element (Iridium) The Periodic Table of Elements Next Element (Gold) Gold The Element Platinum [Click for Isotope Data] 78 Pt Platinum 195.084 Atomic Number: 78 Atomic Weight: 195.084 Melting Point: 2041.55 K (1768.4°C or 3215.1°F) Boiling Point: 4098 K (3825°C or 6917°F) Density: 21.46 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 10 Group Name: none What's in a name? From the Spainsh word for silver, platina. Say what? Platinum is pronounced as PLAT-en-em. History and Uses: Used by the pre-Columbian Indians of South America, platinum wasn't noticed by western scientists until 1735. Platinum can occur free in nature and is sometimes found in deposits of gold-bearing sands, primarily those found in

267

It's Elemental - The Element Arsenic  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Germanium Germanium Previous Element (Germanium) The Periodic Table of Elements Next Element (Selenium) Selenium The Element Arsenic [Click for Isotope Data] 33 As Arsenic 74.92160 Atomic Number: 33 Atomic Weight: 74.92160 Melting Point: 1090 K (817°C or 1503°F) Boiling Point: 887 K (614°C or 1137°F) Density: 5.776 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Semi-metal Period Number: 4 Group Number: 15 Group Name: Pnictogen What's in a name? From the Latin word arsenicum, the Greek word arsenikon and the Arabic word Az-zernikh. Say what? Arsenic is pronounced as AR-s'n-ik. History and Uses: Although arsenic compounds were mined by the early Chinese, Greek and Egyptian civilizations, it is believed that arsenic itself was first identified by Albertus Magnus, a German alchemist, in 1250. Arsenic occurs

268

It's Elemental - The Element Barium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cesium Cesium Previous Element (Cesium) The Periodic Table of Elements Next Element (Lanthanum) Lanthanum The Element Barium [Click for Isotope Data] 56 Ba Barium 137.327 Atomic Number: 56 Atomic Weight: 137.327 Melting Point: 1000 K (727°C or 1341°F) Boiling Point: 2170 K (1897°C or 3447°F) Density: 3.62 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 2 Group Name: Alkaline Earth Metal What's in a name? From the Greek word for heavy, barys. Say what? Barium is pronounced as BAR-ee-em. History and Uses: Barium was first isolated by Sir Humphry Davy, an English chemist, in 1808 through the electrolysis of molten baryta (BaO). Barium is never found free in nature since it reacts with oxygen in the air, forming barium oxide

269

It's Elemental - The Element Gold  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Platinum Previous Element (Platinum) The Periodic Table of Elements Next Element (Mercury) Mercury The Element Gold [Click for Isotope Data] 79 Au Gold 196.966569 Atomic Number: 79 Atomic Weight: 196.966569 Melting Point: 1337.33 K (1064.18°C or 1947.52°F) Boiling Point: 3129 K (2856°C or 5173°F) Density: 19.282 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 11 Group Name: none What's in a name? From the Sanskrit word Jval and the Anglo-Saxon word gold. Gold's chemical symbol comes from the the latin word for gold, aurum. Say what? Gold is pronounced as GOLD. History and Uses: An attractive and highly valued metal, gold has been known for at least 5500 years. Gold is sometimes found free in nature but it is usually found

270

It's Elemental - The Element Rhenium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tungsten Tungsten Previous Element (Tungsten) The Periodic Table of Elements Next Element (Osmium) Osmium The Element Rhenium [Click for Isotope Data] 75 Re Rhenium 186.207 Atomic Number: 75 Atomic Weight: 186.207 Melting Point: 3459 K (3186°C or 5767°F) Boiling Point: 5869 K (5596°C or 10105°F) Density: 20.8 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 7 Group Name: none What's in a name? From the Latin word for the Rhine River, Rhenus. Say what? Rhenium is pronounced as REE-nee-em. History and Uses: Rhenium was discovered by the German chemists Ida Tacke-Noddack, Walter Noddack and Otto Carl Berg in 1925. They detected rhenium spectroscopically in platinum ores and in the minerals columbite ((Fe, Mn, Mg)(Nb, Ta)2O6),

271

It's Elemental - The Element Osmium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Rhenium Rhenium Previous Element (Rhenium) The Periodic Table of Elements Next Element (Iridium) Iridium The Element Osmium [Click for Isotope Data] 76 Os Osmium 190.23 Atomic Number: 76 Atomic Weight: 190.23 Melting Point: 3306 K (3033°C or 5491°F) Boiling Point: 5285 K (5012°C or 9054°F) Density: 22.57 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 8 Group Name: none What's in a name? From the Greek word for a smell, osme. Say what? Osmium is pronounced as OZ-mee-em. History and Uses: Osmium and iridium were discovered at the same time by the British chemist Smithson Tennant in 1803. Osmium and iridium were identified in the black residue remaining after dissolving platinum ore with aqua regia, a mixture

272

It's Elemental - The Element Antimony  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tin Tin Previous Element (Tin) The Periodic Table of Elements Next Element (Tellurium) Tellurium The Element Antimony [Click for Isotope Data] 51 Sb Antimony 121.760 Atomic Number: 51 Atomic Weight: 121.760 Melting Point: 903.78 K (630.63°C or 1167.13°F) Boiling Point: 1860 K (1587°C or 2889°F) Density: 6.685 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Semi-metal Period Number: 5 Group Number: 15 Group Name: Pnictogen What's in a name? From the Greek words anti and monos, which together mean "not alone." Antimony's chemical symbol comes from its historic name, Stibium. Say what? Antimony is pronounced as AN-the-MOH-nee. History and Uses: Antimony has been known since ancient times. It is sometimes found free in nature, but is usually obtained from the ores stibnite (Sb2S3) and

273

The role of trace gas flux networks in biogeosciences  

SciTech Connect (OSTI)

Vast networks of meteorological sensors ring the globe, providing continuous measurements of an array of atmospheric state variables such as temperature, humidity, rainfall, and the concentration of carbon dioxide [New etal., 1999; Tans etal., 1996]. These measurements provide input to weather and climate models and are key to detecting trends in climate, greenhouse gases, and air pollution. Yet to understand how and why these atmospheric state variables vary in time and space, biogeoscientists need to know where, when, and at what rates important gases are flowing between the land and the atmosphere. Tracking trace gas fluxes provides information on plant or microbial metabolism and climate-ecosystem interactions. The existence of trace gas flux networks is a relatively new phenomenon, dating back to research in 1984. The first gas flux measurement networks were regional in scope and were designed to track pollutant gases such as sulfur dioxide, ozone, nitric acid, and nitrogen dioxide. Atmospheric observations and model simulations were used to infer the depositional rates of these hazardous chemicals [Fowler etal., 2009; Meyers etal., 1991]. In the late 1990s, two additional trace gas flux measurement networks emerged. One, the United States Trace Gas Network (TRAGNET), was a short-lived effort that measured trace gas emissions from the soil and plants with chambers distributed throughout the country [Ojima etal., 2000]. The other, FLUXNET, was an international endeavor that brought many regional networks together to measure the fluxes of carbon dioxide, water vapor, and sensible heat exchange with the eddy covariance technique [Baldocchi etal., 2001]. FLUXNET, which remains active today, currently includes more than 400 tower sites, dispersed across most of the world's climatic zones and biomes, with sites in North and South America, Europe, Asia, Africa, and Australia. More recently, several specialized networks have emerged, including networks dedicated to urban areas (Urban Fluxnet), nitrogen compounds in Europe (NitroEurope), and methane (MethaneNet). Technical Aspects of Flux Networks Eddy covariance flux measurements are the preferred method by which biogeoscientists measure trace gas exchange between ecosystems and the atmosphere [Baldocchi, 2003].

Baldocch, Dennis [Department of Environmental Science, Policy and Management, University of California, Berkeley,; Reichstein, Markus [Max Planck Institute for Biogeochemistry; Papale, D. [University of Tuscia; KOTEEN, LAURIE [University of California, Berkeley; VARGAS, RODRIGO [Ensenada Center for Scientific Research and Higher Education (CICESE); Agarwal, D.A [Lawrence Berkeley National Laboratory (LBNL); Cook, Robert B [ORNL

2012-01-01T23:59:59.000Z

274

Process for production of synthesis gas with reduced sulfur content  

DOE Patents [OSTI]

A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

1989-01-01T23:59:59.000Z

275

Trace determination of lead by helium-4 activation analysis  

E-Print Network [OSTI]

glass samples doped with 61 different trace elements at nominal 500 to 1 ppm level concentrations. We evaluated the measurement sensitivities of two methods for alpha counting, i. e. , surface barrier detector and nuclear track detectors. Detection.... An automated system synchronized irradiation, solenoid operation, and data acquisition. Prior to irradiation, the solenoid was energized to position the aluminum sheet in front of the detector. The cyclotron's beam pulser system then began irradiation...

Vargas Bernal, Maria E.

2012-06-07T23:59:59.000Z

276

Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon - Energy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Advanced Materials Find More Like This Return to Search LithiumSulfur Batteries Based on Doped Mesoporous Carbon Oak Ridge National Laboratory Contact ORNL About...

277

Analyses of sulfur-asphalt field trials in Texas  

E-Print Network [OSTI]

128 LIST OF FIGURES FIGURE PAGF Layout of SNPA sulfur bitumen binder pavem nt test ? U. S. Highway 69, Lufkin, Texas 15 Col 1oi d mi 1 1 furnished by SNPA for preparation of sul fur-asphalt emulsions View of mixing station showing sulfur... designed to investigate the advantage of using a colloid mill to prepare sulfur-asphalt binders as compared to comingling the asphalt and molten sulfur in a pipeline leading directly to the pug mill. After only six months of testing, the results...

Newcomb, David Edward

1979-01-01T23:59:59.000Z

278

Development of sulfur cathode material for Li-S batteries.  

E-Print Network [OSTI]

??M.S. Efforts were taken to fabricate a cathode material having Sulfur as the active material. First step is composed of identifying potential ways of fabricating (more)

Dharmasena, Ruchira Ravinath, 1984-

2014-01-01T23:59:59.000Z

279

Project Profile: Baseload CSP Generation Integrated with Sulfur...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Related Links FAQs Contact Us Offices You are here Home Concentrating Solar Power Project Profile: Baseload CSP Generation Integrated with Sulfur-Based...

280

SULFUR-TOLERANT CATALYST FOR THE SOLID OXIDE FUEL CELL.  

E-Print Network [OSTI]

??JP-8 fuel is easily accessible, transportable, and has hydrogen content essential to solid oxide fuel cell (SOFC) operation. However, this syngas has sulfur content which (more)

Bozeman, Joe Frank, III

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Fundamental Studies of Lithium-Sulfur Cell Chemistry  

Broader source: Energy.gov (indexed) [DOE]

Studies of Lithium-Sulfur Cell Chemistry PI: Nitash Balsara LBNL June 17, 2014 Project ID ESS224 This presentation does not contain any proprietary, confidential, or otherwise...

282

Abatement of Air Pollution: Control of Sulfur Compound Emissions  

Broader source: Energy.gov (indexed) [DOE]

Abatement of Air Pollution: Control of Sulfur Compound Emissions Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) < Back Eligibility Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Residential Retail Supplier Rural Electric Cooperative Schools State/Provincial Govt Systems Integrator Transportation Tribal Government Utility Program Info State Connecticut Program Type Environmental Regulations Provider Department of Energy and Environmental Protection These regulations set limits on the sulfur content of allowable fuels (1.0%

283

It's Elemental - The Element Zinc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Copper Copper Previous Element (Copper) The Periodic Table of Elements Next Element (Gallium) Gallium The Element Zinc [Click for Isotope Data] 30 Zn Zinc 65.38 Atomic Number: 30 Atomic Weight: 65.38 Melting Point: 692.68 K (419.53°C or 787.15°F) Boiling Point: 1180 K (907°C or 1665°F) Density: 7.134 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 12 Group Name: none What's in a name? From the German word zink. Say what? Zinc is pronounced as ZINK. History and Uses: Although zinc compounds have been used for at least 2,500 years in the production of brass, zinc wasn't recognized as a distinct element until much later. Metallic zinc was first produced in India sometime in the 1400s by heating the mineral calamine (ZnCO3) with wool. Zinc was rediscovered by

284

It's Elemental - The Element Fluorine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen Oxygen Previous Element (Oxygen) The Periodic Table of Elements Next Element (Neon) Neon The Element Fluorine [Click for Isotope Data] 9 F Fluorine 18.9984032 Atomic Number: 9 Atomic Weight: 18.9984032 Melting Point: 53.53 K (-219.62°C or -363.32°F) Boiling Point: 85.03 K (-188.12°C or -306.62°F) Density: 0.001696 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 17 Group Name: Halogen What's in a name? From the Latin and French words for flow, fluere. Say what? Fluorine is pronounced as FLU-eh-reen or as FLU-eh-rin. History and Uses: Fluorine is the most reactive of all elements and no chemical substance is capable of freeing fluorine from any of its compounds. For this reason, fluorine does not occur free in nature and was extremely difficult for

285

Laboratory scale studies of Pd/{gamma}-Al{sub 2}O{sub 3} sorbents for the removal of trace contaminants from coal-derived fuel gas at elevated temperatures  

SciTech Connect (OSTI)

The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150540 C) to hot (>540 C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/?-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/?-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/?-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

Rupp, Erik C.; Granite, Evan J. [U.S. DOE; Stanko, Dennis C. [U.S. DOE

2013-01-01T23:59:59.000Z

286

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

Narain, N.K.; Ruether, J.A.; Smith, D.N.

1987-10-07T23:59:59.000Z

287

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

1988-01-01T23:59:59.000Z

288

Sulfur isotopes in coal constrain the evolution of the Phanerozoic sulfur cycle  

Science Journals Connector (OSTI)

...obviously influence the average isotope values. For the other data, samples...pp 87105 . 19 Price FT Casagrande DJ ( 1991 ) Sulfur...coals. Geology of Fossil Fuels, Proc 30th Int Geol Congress...Jersey Pinelands and its effect on stream water chemistry...223 248 . 29 Price FT Shieh YN ( 1979 ) Fractionation...

Donald E. Canfield

2013-01-01T23:59:59.000Z

289

SYNTHESIS OF SULFUR-BASED WATER TREATMENT AGENT FROM SULFUR DIOXIDE WASTE STREAMS  

SciTech Connect (OSTI)

We propose a process that uses sulfur dioxide from coal combustion as a raw material to synthesize polymeric ferric sulfate (PFS), a water treatment agent. The process uses sodium chlorate as an oxidant and ferrous sulfate as an absorbent. The major chemical mechanisms in this reaction system include oxidation, hydrolysis, and polymerization. Oxidation determines sulfur conversion efficiency while hydrolysis and polymerization control the quality of product. Many factors, including SO{sub 2} inlet concentration, flow rate of simulated flue gas, reaction temperature, addition rate of oxidant and stirring rate, may affect the efficiencies of SO{sub 2} removal. Currently, the effects of SO{sub 2} inlet concentration, the flow rate of simulated flue gas and addition rate of flue gas on removal efficiencies of SO{sub 2}, are being investigated. Experiments shown in this report have demonstrated that the conversion efficiencies of sulfur dioxide with ferrous sulfate as an absorbent are in the range of 60-80% under the adopted process conditions. However, the conversion efficiency of sulfur dioxide may be improved by optimizing reaction conditions to be investigated. Partial quality indices of the synthesized products, including Fe{sup 2+} concentration and total iron concentration, have been evaluated.

Robert C. Brown; Maohong Fan

2001-12-01T23:59:59.000Z

290

Lithiumsulfur batteries: Influence of C-rate, amount of electrolyte and sulfur loading on cycle performance  

Science Journals Connector (OSTI)

Abstract In the past four years major improvement of the lithium sulfur battery technology has been reported. Novel carbon cathode materials offer high sulfur loading, sulfur utilization and cycle stability. An often neglected aspect is that sulfur loading and amount of electrolyte strongly impact the performance. In this paper, we demonstrate how the amount of electrolyte, sulfur loading, lithium excess and cycling rate influences the cycle stability and sulfur utilization. We chose vertically aligned carbon nanotubes (VA-CNT) as model system with a constant areal loading of carbon. For a high reproducibility, decreased weight of current collector and good mechanical adhesion of the VA-CNTs we present a layer transfer technique that enables a light-weight sulfur cathode. The sulfur loading of the cathode was adjusted from 20 to 80wt.-%. Keeping the total amount of electrolyte constant and varying the C-rate, we are able to demonstrate that the capacity degradation is reduced for high rates, high amount of electrolyte and low sulfur loading. In addition idle periods in the cycling regiment and lower rates result in an increased degradation. We attribute this to the redox-reaction between reactive lithium and polysulfides that correlates with the cycling time, rather than cycle number.

Jan Brckner; Sren Thieme; Hannah Tamara Grossmann; Susanne Drfler; Holger Althues; Stefan Kaskel

2014-01-01T23:59:59.000Z

291

Development of viable solutions for the synthesis of sulfur bearing single crystals  

SciTech Connect (OSTI)

The discovery of high temperature superconductivity in FeAs and FeSe based compounds has once again focused the condensed matter community on the need to systematically explore compounds containing chalcogens and pnictogens. Whereas some solution growth techniques have been developed to handle P and As, and Sb and Bi are versatile solvents in their own right, S has remained a problematic element to incorporate into conventional solution growth. To a large extent its low boiling point, combined with its polymeric nature in a molten state have made S an uninviting solvent. In this paper we present our development of a range of binary sulfur bearing solutions (some even sulfur rich) and demonstrate how we have been able to use these as useful starting points for the growth of a wide range of transition metalsulfurX ternary compounds. We present growth details and basic characterization data for Ni{sub 3}Bi{sub 2}S{sub 2}, Co{sub 3}Sn{sub 2}S{sub 2}, Fe{sub 2}GeS{sub 4}, CoSSb, and CePd{sub 3}S{sub 4}. In addition we present a remarkably simple method for the growth of single crystalline Co with crystallization taking place below the Curie temperature.

Lin, Xiao; Budko, Sergey; Canfield, Paul

2012-04-18T23:59:59.000Z

292

It's Elemental - The Element Lead  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thallium Thallium Previous Element (Thallium) The Periodic Table of Elements Next Element (Bismuth) Bismuth The Element Lead [Click for Isotope Data] 82 Pb Lead 207.2 Atomic Number: 82 Atomic Weight: 207.2 Melting Point: 600.61 K (327.46°C or 621.43°F) Boiling Point: 2022 K (1749°C or 3180°F) Density: 11.342 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 14 Group Name: none What's in a name? From the Anglo-Saxon word lead. Lead's chemical symbol comes from the Latin word for waterworks, plumbum. Say what? Lead is pronounced as LED. History and Uses: Lead has been known since ancient times. It is sometimes found free in nature, but is usually obtained from the ores galena (PbS), anglesite (PbSO4), cerussite (PbCO3) and minum (Pb3O4). Although lead makes up only

293

Application of Digital SIMS Imaging to Light Element and Trace Element Mapping  

Science Journals Connector (OSTI)

The determination of the relationship of compositional microstructure to morphological microstructure is often critical for elucidating structure-property relationships in materials. Traditionally, the study of t...

D. Newbury; D. Bright; D. Williams; C. M. Sung

1986-01-01T23:59:59.000Z

294

Trace Element Determination by Combining Solid-Phase Microextraction Hyphenated to Elemental and Molecular Detection Techniques  

Science Journals Connector (OSTI)

......degradation according with the storage time. Moreover, NaBEt4 must...case of speciation studies in seawater. In the case of aqueous matrices...25123 14.8-14.9 Hg2+ Seawater NaBEt4, acetate 100 m PDMS...pH 5) 0.11 4.8 Hg2+ Seawater NaBPr4, acetate 100 m PDMS......

Sergi Dez; Josep M. Bayona

2006-08-01T23:59:59.000Z

295

Using ISC & GIS to predict sulfur deposition from coal-fired power plants  

E-Print Network [OSTI]

The goal of this research project was to determine if atmospheric sources have the potential of contributing significantly to the sulfur content of grazed forage. Sulfur deposition resulting from sulfur dioxide emissions from coal- fired power...

Lopez, Jose Ignacio

2012-06-07T23:59:59.000Z

296

Integrated boiler, superheater, and decomposer for sulfuric acid decomposition  

DOE Patents [OSTI]

A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

2010-01-12T23:59:59.000Z

297

HEALTH AND CLIMATE POLICY IMPACTS ON SULFUR EMISSION CONTROL  

E-Print Network [OSTI]

the climate and health effects of sulfate aerosol into an integrated-assessment model of fossil fuel emission warming and health simultaneously will support more stringent fossil fuel and sulfur controls control. Our simulations show that a policy that adjusts fossil fuel and sulfur emissions to address both

Russell, Lynn

298

Metal-sulfur type cell having improved positive electrode  

DOE Patents [OSTI]

An novel metal-sulfur type cell operable at a temperature of 200.degree. C. or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S).sub.y).sub.n wherein y=1 to 6; n=2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprisises one of more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associtated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

Dejonghe, Lutgard C. (Berkeley, CA); Visco, Steven J. (Berkeley, CA); Mailhe, Catherine C. (Berkeley, CA); Armand, Michel B. (St. Martin D'Uriage, FR)

1989-01-01T23:59:59.000Z

299

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Broader source: Energy.gov (indexed) [DOE]

May 2011 CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries "This presentation does not contain any proprietary, confidential, or otherwise...

300

E-Print Network 3.0 - amoco sulfur recovery process Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Medicine 80 Sulfur and oxygen isotope composition of the atmosphere in Saxony (Germany) Tichomirowa et al. Summary: ? a) Mixing processes 12;Sulfur and oxygen isotope...

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Specifying API Trace Birthmark by Abstract Interpretation  

Science Journals Connector (OSTI)

API trace birthmark is a major class of software birthmarks, where API sequences are defined as software birthmarks to ... , an abstract interpretation-based method for specifying API trace birthmark is proposed ...

Ying Zeng; Fenlin Liu; Jian Chen; Bin Yan

2013-01-01T23:59:59.000Z

302

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect (OSTI)

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

303

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect (OSTI)

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

2000-04-10T23:59:59.000Z

304

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect (OSTI)

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded research of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

1999-11-30T23:59:59.000Z

305

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides  

SciTech Connect (OSTI)

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Akyurtlu, A.; Akyurtlu, J.F.

1999-03-31T23:59:59.000Z

306

Distributed trace using central performance counter memory  

DOE Patents [OSTI]

A plurality of processing cores, are central storage unit having at least memory connected in a daisy chain manner, forming a daisy chain ring layout on an integrated chip. At least one of the plurality of processing cores places trace data on the daisy chain connection for transmitting the trace data to the central storage unit, and the central storage unit detects the trace data and stores the trace data in the memory co-located in with the central storage unit.

Satterfield, David L; Sexton, James C

2013-10-22T23:59:59.000Z

307

Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3  

SciTech Connect (OSTI)

The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

1995-09-01T23:59:59.000Z

308

Privacy vulnerability of published anonymous mobility traces  

Science Journals Connector (OSTI)

Mobility traces of people and vehicles have been collected and published to assist the design and evaluation of mobile networks, such as large-scale urban sensing networks. Although the published traces are often made anonymous in that the true identities ... Keywords: mobility traces, privacy, security and protection

Chris Y. T. Ma; David K. Y. Yau; Nung Kwan Yip; Nageswara S. V. Rao

2013-06-01T23:59:59.000Z

309

Ray Tracing JELLO Brand Paul S. Heckbert  

E-Print Network [OSTI]

Ray Tracing JELL­O ® Brand Gelatin Paul S. Heckbert Dessert Foods Division Pixar San Rafael, CA ABSTRACT Ray tracing has established itself in recent years as the most general image synthesis algorithm for ray tracing Jell­O ® brand gelatin. We believe the method may have application to other brands

Treuille, Adrien

310

Point-to-curve ray tracing  

Science Journals Connector (OSTI)

Point-to-curve ray tracing is an attempt at dealing with multiplicity of solutions to a generic boundary-value problem of ray tracing. In a point-to-curve tracing (P2C) the input parameters of the boundary-value....

Andrzej Hanyga

1996-01-01T23:59:59.000Z

311

Point-to-curve Ray Tracing  

Science Journals Connector (OSTI)

Point-to-curve ray tracing is an attempt at dealing with multiplicity of solutions to a generic boundary-value problem of ray tracing. In a point-to-curve tracing (P2C) the input parameters of the boundary-value....

Andrzej Hanyga

1996-01-01T23:59:59.000Z

312

The Origin of the Elements  

ScienceCinema (OSTI)

The world around us is made of atoms. Did you ever wonder where these atoms came from? How was the gold in our jewelry, the carbon in our bodies, and the iron in our cars made? In this lecture, we will trace the origin of a gold atom from the Big Bang to the present day, and beyond. You will learn how the elements were forged in the nuclear furnaces inside stars, and how, when they die, these massive stars spread the elements into space. You will learn about the origin of the building blocks of matter in the Big Bang, and we will speculate on the future of the atoms around us today.

Murphy, Edward

2014-08-06T23:59:59.000Z

313

Programmatic Elements  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The Guide provides acceptable methods of meeting the requirements of DOE O 151.1C for programmatic elements that sustain the emergency management program and maintain the readiness of the program to respond to an emergency. Cancels DOE G 151.1-1, Volume 5-1, DOE G 151.1-1, Volume 5-2, DOE G 151.1-1, Volume 5-3, DOE G 151.1-1, Volume 5-4, DOE G 151.1-1, Volume 7-1, and DOE G 151.1-1, Volume 7-3.

2007-07-11T23:59:59.000Z

314

Terpolymerization of ethylene, sulfur dioxide and carbon monoxide  

DOE Patents [OSTI]

This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

1981-01-01T23:59:59.000Z

315

Response Elements  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The Guide provides acceptable methods for meeting the requirement of DOE O 151.1C for response elements that respond or contribute to response as needed in an emergency. Cancels DOE G 151.1-1, Volume 3-1, DOE G 151.1-1, Volume 3-2, DOE G 151.1-1, Volume 3-3, DOE G 151.1-1, Volume 3-4, DOE G 151.1-1, Volume 4-1, DOE G 151.1-1, Volume 4-2, DOE G 151.1-1, Volume 4-3, DOE G 151.1-1, Volume 4-4, DOE G 151.1-1, Volume 4-5, and DOE G 151.1-1, Volume 4-6.

2007-07-11T23:59:59.000Z

316

Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams  

SciTech Connect (OSTI)

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjan

1999-09-30T23:59:59.000Z

317

Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams  

DOE Patents [OSTI]

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjani

2004-06-01T23:59:59.000Z

318

System for adding sulfur to a fuel cell stack system for improved fuel cell stability  

DOE Patents [OSTI]

A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

2013-08-13T23:59:59.000Z

319

Martinez Sulfuric Acid Regeneration Plt Biomass Facility | Open Energy  

Open Energy Info (EERE)

Martinez Sulfuric Acid Regeneration Plt Biomass Facility Martinez Sulfuric Acid Regeneration Plt Biomass Facility Jump to: navigation, search Name Martinez Sulfuric Acid Regeneration Plt Biomass Facility Facility Martinez Sulfuric Acid Regeneration Plt Sector Biomass Facility Type Non-Fossil Waste Location Contra Costa County, California Coordinates 37.8534093°, -121.9017954° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":37.8534093,"lon":-121.9017954,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

320

Diesel Emissions Control-Sulfur Effects (DECSE) Program Status  

SciTech Connect (OSTI)

Determine the impact of fuel sulfur levels on emission control systems that could be implemented to lower emissions of NO{sub x} and PM from on-highway trucks in the 2002-2004 time frame.

None

1999-06-29T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Hybrid Microfabricated Device for Field Measurement of Atmospheric Sulfur Dioxide  

Science Journals Connector (OSTI)

It is also now generally agreed that forthcoming major volcanic eruptions will sensitively monitored for increasing sulfur gas emissions as indicated by increasing seismic activity. ... (12)?Fish, B. R.; Durham, J. L. Environ. ...

Shin-Ichi Ohira; Kei Toda; Shin-Ichiro Ikebe; Purnendu K. Dasgupta

2002-10-10T23:59:59.000Z

322

Sulfur meter for blending coal at Plant Monroe: Final report  

SciTech Connect (OSTI)

An on-line sulfur analyzer, installed at the Detroit Edison, Monroe Power station, was placed into service and evaluated for coal blending optimization to minimize the cost of complying with changing stack gas sulfur dioxide regulations. The project involved debugging the system which consisted of an /open quotes/as-fired/close quotes/ sampler and nuclear source sulfur analyzer. The system was initially plagued with mechanical and electronic problems ranging from coal flow pluggages to calibration drifts in the analyzer. Considerable efforts were successfully made to make the system reliable and accurate. On-line testing showed a major improvement in control of sulfur dioxide emission rates and fuel blending optimization equivalent to as much as $6 million in fuel costs at the time of the evaluation. 7 refs., 14 figs., 12 tabs.

Trentacosta, S.D.; Yurko, J.O.

1988-04-01T23:59:59.000Z

323

Novel Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

One of the unique advantages of SOFCs over other types of fuel cells is the potential for direct utilization of hydrocarbon fuels (it may involve internal reforming). Unfortunately, most hydrocarbon fuels contain sulfur, which would dramatically degrade SOFC performance at parts-per-million (ppm) levels. Low concentration of sulfur (ppm or below) is difficult to remove efficiently and cost-effectively. Therefore, knowing the exact poisoning process for state-of-the-art anode-supported SOFCs with Ni-YSZ cermet anodes, understanding the detailed anode poisoning mechanism, and developing new sulfur-tolerant anodes are essential to the promotion of SOFCs that run on hydrocarbon fuels. The effect of cell operating conditions (including temperature, H{sub 2}S concentration, cell voltage/current density, etc.) on sulfur poisoning and recovery of nickel-based anode in SOFCs was investigated. It was found that sulfur poisoning is more severe at lower temperature, higher H{sub 2}S concentration or lower cell current density (higher cell voltage). In-situ Raman spectroscopy identified the nickel sulfide formation process on the surface of a Ni-YSZ electrode and the corresponding morphology change as the sample was cooled in H{sub 2}S-containing fuel. Quantum chemical calculations predicted a new S-Ni phase diagram with a region of sulfur adsorption on Ni surfaces, corresponding to sulfur poisoning of Ni-YSZ anodes under typical SOFC operating conditions. Further, quantum chemical calculations were used to predict the adsorption energy and bond length for sulfur and hydrogen atoms on various metal surfaces. Surface modification of Ni-YSZ anode by thin Nb{sub 2}O{sub 5} coating was utilized to enhance the sulfur tolerance. A multi-cell testing system was designed and constructed which is capable of simultaneously performing electrochemical tests of 12 button cells in fuels with four different concentrations of H{sub 2}S. Through systematical study of state-of-the-art anode-supported SOFC button cells, it is seen that the long-term sulfur poisoning behavior of those cells indicate that there might be a second-stage slower degradation due to sulfur poisoning, which would last for a thousand hour or even longer. However, when using G-18 sealant from PNNL, the 2nd stage poisoning was effectively prohibited.

Lei Yang; Meilin Liu

2008-12-31T23:59:59.000Z

324

METHOD TO PREVENT SULFUR ACCUMULATION INSIDE MEMBRANE ELECTRODE ASSEMBLY  

SciTech Connect (OSTI)

HyS is conceptually the simplest of the thermochemical cycles and involves only sulfur chemistry. In the HyS Cycle hydrogen gas (H{sub 2}) is produced at the cathode of the electrochemical cell (or electrolyzer). Sulfur dioxide (SO{sub 2}) is oxidized at the anode to form sulfuric acid (H{sub 2}SO{sub 4}) and protons (H{sup +}) as illustrated below. A separate high temperature reaction decomposes the sulfuric acid to water and sulfur dioxide which are recycled to the electrolyzers, and oxygen which is separated out as a secondary product. The electrolyzer includes a membrane that will allow hydrogen ions to pass through but block the flow of hydrogen gas. The membrane is also intended to prevent other chemical species from migrating between electrodes and undergoing undesired reactions that could poison the cathode or reduce overall process efficiency. In conventional water electrolysis, water is oxidized at the anode to produce protons and oxygen. The standard cell potential for conventional water electrolysis is 1.23 volts at 25 C. However, commercial electrolyzers typically require higher voltages ranging from 1.8 V to 2.6 V [Kirk-Othmer, 1991]. The oxidation of sulfur dioxide instead of water in the HyS electrolyzer occurs at a much lower potential. For example, the standard cell potential for sulfur dioxide oxidation at 25 C in 50 wt % sulfuric acid is 0.29 V [Westinghouse, 1980]. Since power consumption by the electrolyzers is equal to voltage times current, and current is proportional to hydrogen production, a large reduction in voltage results in a large reduction in electrical power cost per unit of hydrogen generated.

Steimke, J.; Steeper, T.; Herman, D.; Colon-Mercado, H.; Elvington, M.

2009-06-22T23:59:59.000Z

325

Low temperature fracture evaluation of plasticized sulfur paving mixtures  

E-Print Network [OSTI]

May 1985 Major Subject: Civil Engineering LOW TEMPERATURE FRACTURE EVALUATION OF PLASTICIZED SULFUR PAVING MIXTURES A Thesis by KAMYAR MAHBOUB Approved as to style and content by: Dallas N. Li tie (Chai rman of Committee) Ro e . Lytto Member... modifications to the standard ASTM procedure. These modifications were required due to the nature of plasticized sulfur mixtures and asphalt cement mixtures. The J-integral version of Paris ' law was successfully used to characterize the fatigue...

Mahboub, Kamyar

2012-06-07T23:59:59.000Z

326

Recent advances in lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract Lithiumsulfur (LiS) batteries have attracted much attention lately because they have very high theoretical specific energy (2500Whkg?1), five times higher than that of the commercial LiCoO2/graphite batteries. As a result, they are strong contenders for next-generation energy storage in the areas of portable electronics, electric vehicles, and storage systems for renewable energy such as wind power and solar energy. However, poor cycling life and low capacity retention are main factors limiting their commercialization. To date, a large number of electrode and electrolyte materials to address these challenges have been investigated. In this review, we present the latest fundamental studies and technological development of various nanostructured cathode materials for LiS batteries, including their preparation approaches, structure, morphology and battery performance. Furthermore, the development of other significant components of LiS batteries including anodes, electrolytes, additives, binders and separators are also highlighted. Not only does the intention of our review article comprise the summary of recent advances in LiS cells, but also we cover some of our proposals for engineering of LiS cell configurations. These systematic discussion and proposed directions can enlighten ideas and offer avenues in the rational design of durable and high performance LiS batteries in the near future.

Lin Chen; Leon L. Shaw

2014-01-01T23:59:59.000Z

327

Heat Transfer Characteristics of Sulfur and Sulfur Diluted with Hydrogen Sulfide Flowing Through Circular Tubes  

E-Print Network [OSTI]

is called the pumping-power advantage factor, and has the value 2. 5 x 10 for sodium. The only metals having a higher value of H are 13 lithium 7 and bismuth. Lithium 7 comprises 92. 5% of natural lithium, but the cost of separating it from lithium 6...-section for thermal neutrons being 0. 130 barns. For comparison, water has an absorption cross-section of 0. 58 barns for thermal neutrons (2) . Sulfur is not activated by exposure to neutron flux in such a way as to produce a radioactive isotope which...

Stone, Porter Walwyn

1960-01-01T23:59:59.000Z

328

Trace gas measurements in the Kuwait oil fire smoke plume  

SciTech Connect (OSTI)

The authors report trace gas measurements made both inside and outside the Kuwait oil-fire smoke plume during a flight of an instrumented research aircraft on May 30, 1991. Concentrations of SO{sub 2}, CO, and NO{sub x} averaged vertically and horizontally throughout the plume 80 km downwind of Kuwait City were 106, 127, and 9.1 parts per billion by volume (ppbv), respectively, above background concentrations. With the exception of SO{sub 2}, trace gas concentrations were far below typical US urban levels and primary national ambient air quality standards. Ambient ozone was titrated by NO in the dark, dense core of the smoke plume close to the fires, and photochemical ozone production was limited to the diffuse edge of the plume. Photochemical O{sub 3} production was noted throughout the plume at a distance of 160 km downwind of Kuwait City, and averaged 2.3 ppbv per hour during the first 3 hours of transport. Little additional photochemical production was noted at a downwind range of 340 km. The fluxes of sulfur dioxide, carbon monoxide, and reactive nitrogen from the roughly 520 fires still burning on May 30, 1991 are estimated at 1.4 x 10{sup 7} kg SO{sub 2}/d, 6.9 x 10{sup 6} kg CO/d, and 2.7 x 10{sup 5} kg N/d, respectively. Generally low concentrations of CO and NO{sub x} indicate that the combustion was efficient and occurred at low temperatures. Low total nonmethane hydrocarbon concentrations suggest that the volatile components of the petroleum were burned efficiently. 37 refs., 4 figs., 4 tabs.

Luke, W.T.; Kok, G.L.; Schillawski, R.D.; Zimmerman, P.R.; Greenberg, J.P.; Kadavanich, M. [National Center for Atmospheric Research, Boulder, CO (United States)

1992-09-20T23:59:59.000Z

329

Polyaniline-modified cetyltrimethylammonium bromide-graphene oxide-sulfur nanocomposites with enhanced performance for lithium-sulfur batteries  

Science Journals Connector (OSTI)

Conductive polymer coatings can boost the power storage capacity of lithium-sulfur batteries. We report here on the design and ... polyaniline (PANI)-modified cetyltrimethylammonium bromide (CTAB)-graphene oxide ...

Yongcai Qiu; Wanfei Li; Guizhu Li; Yuan Hou; Lisha Zhou; Hongfei Li

2014-09-01T23:59:59.000Z

330

COMPONENT DEVELOPMENT NEEDS FOR THE HYBRID SULFUR ELECTROLYZER  

SciTech Connect (OSTI)

Fiscal year 2008 studies in electrolyzer component development have focused on the characterization of membrane electrode assemblies (MEA) after performance tests in the single cell electrolyzer, evaluation of electrocatalysts and membranes using a small scale electrolyzer and evaluating the contribution of individual cell components to the overall electrochemical performance. Scanning electron microscopic (SEM) studies of samples taken from MEAs testing in the SRNL single cell electrolyzer test station indicates a sulfur-rich layer forms between the cathode catalyst layer and the membrane. Based on a review of operating conditions for each of the MEAs evaluated, we conclude that the formation of the layer results from the reduction of sulfur dioxide as it passes through the MEA and reaches the catalyst layer at the cathode-membrane interface. Formation of the sulfur rich layer results in partial delamination of the cathode catalyst layer leading to diminished performance. Furthermore we believe that operating the electrolyzer at elevated pressure significantly increases the rate of formation due to increased adsorption of hydrogen on the internal catalyst surface. Thus, identification of a membrane that exhibits much lower transport of sulfur dioxide is needed to reduce the quantity of sulfur dioxide that reaches the cathode catalyst and is reduced to produce the sulfur-rich layer. Three candidate membranes are currently being evaluated that have shown promise from preliminary studies, (1) modified Nafion{reg_sign}, (2) polybenzimidazole (PBI), and (3) sulfonated Diels Alder polyphenylene (SDAPP). Testing examined the activity for the sulfur dioxide oxidation of platinum (Pt) and platinum-alloy catalysts in 30 wt% sulfuric acid solution. Linear sweep voltammetry showed an increase in activity when catalysts in which Pt is alloyed with non-noble transition metals such as cobalt and chromium. However when Pt is alloyed with noble metals, such as iridium or ruthenium, the kinetic activity decreases. We recommend further testing to determine if these binary alloys will provide the increased reaction kinetic needed to meet the targets. We also plan to test the performance of these catalyst materials for both proton and sulfur dioxide reduction. The latter may provide another parameter by which we can control the reduction of sulfur dioxide upon transport to the cathode catalyst surface. A small scale electrolyzer (2 cm{sup 2}) has been fabricated and successfully installed as an additional tool to evaluate the effect of different operating conditions on electrolyzer and MEA performance. Currently this electrolyzer is limited to testing at temperatures up to 80 C and at atmospheric pressure. Selected electrochemical performance data from the single cell sulfur dioxide depolarized electrolyzer were analyzed with the aid of an empirical equation which takes into account the overpotential of each of the components. By using the empirical equation, the performance data was broken down into its components and a comparison of the potential losses was made. The results indicated that for the testing conditions of 80 C and 30 wt% sulfuric acid, the major overpotential contribution ({approx}70 % of all losses) arise from the slow reaction rate of oxidation of sulfur dioxide. The results indicate that in order to meet the target of hydrogen production at 0.5 A/cm{sup 2} at 0.6 V and 50 wt% sulfuric acid, identification of a better catalyst for sulfur dioxide oxidation will provide the largest gain in electrolyzer performance.

Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

2008-05-30T23:59:59.000Z

331

Trace metal concentration and fish size: Variation among fish species in a Mediterranean river  

E-Print Network [OSTI]

29 April 2014 Accepted 12 May 2014 Keywords: Bioaccumulation Heavy metals Llobregat River species in an Iberian river with moderate metal pollution. Al, Fe and Zn were the most abundant metals trace elements (Bervoets and Blust, 2003; Noël et al., 2013). Heavy metals in fish represent a potential

García-Berthou, Emili

332

Elemental composition in sealed plutoniumberyllium neutron sources  

Science Journals Connector (OSTI)

Abstract Five sealed plutoniumberyllium (PuBe) neutron sources from various manufacturers were disassembled. Destructive chemical analyses for recovered PuBe materials were conducted for disposition purposes. A dissolution method for PuBe alloys was developed for quantitative plutonium (Pu) and beryllium (Be) assay. Quantitation of Be and trace elements was performed using plasma based spectroscopic instruments, namely inductively coupled plasma mass spectrometry (ICP-MS) and atomic emission spectrometry (ICP-AES). Pu assay was accomplished by an electrochemical method. Variations in trace elemental contents among the five PuBe sources are discussed.

N. Xu; K. Kuhn; D. Gallimore; A. Martinez; M. Schappert; D. Montoya; E. Lujan; K. Garduno; L. Tandon

2015-01-01T23:59:59.000Z

333

INTRODUCTION Metals comprise about 75% of the known elements and can  

E-Print Network [OSTI]

quality. Metals have traditionally been classified into categories such as light, heavy, semimetal (i of less than 0.1%. In biochemical and bio- medical research, trace element concentrations in plant

Sparks, Donald L.

334

Coal Cleaning Using Resonance Disintegration for Mercury and Sulfur Reduction Prior to Combustion  

SciTech Connect (OSTI)

Coal-cleaning processes have been utilized to increase the heating value of coal by extracting ash-forming minerals in the coal. These processes involve the crushing or grinding of raw coal followed by physical separation processes, taking advantage of the density difference between carbonaceous particles and mineral particles. In addition to the desired increase in the heating value of coal, a significant reduction of the sulfur content of the coal fed to a combustion unit is effected by the removal of pyrite and other sulfides found in the mineral matter. WRI is assisting PulseWave to develop an alternate, more efficient method of liberating and separating the undesirable mineral matter from the carbonaceous matter in coal. The approach is based on PulseWave's patented resonance disintegration technology that reduces that particle size of materials by application of destructive resonance, shock waves, and vortex generating forces. Illinois No.5 coal, a Wyodak coal, and a Pittsburgh No.8 coal were processed using the resonance disintegration apparatus then subjected to conventional density separations. Initial microscopic results indicate that up to 90% of the pyrite could be liberated from the coal in the machine, but limitations in the density separations reduced overall effectiveness of contaminant removal. Approximately 30-80% of the pyritic sulfur and 30-50% of the mercury was removed from the coal. The three coals (both with and without the pyritic phase separated out) were tested in WRI's 250,000 Btu/hr Combustion Test Facility, designed to replicate a coal-fired utility boiler. The flue gases were characterized for elemental, particle bound, and total mercury in addition to sulfur. The results indicated that pre-combustion cleaning could reduce a large fraction of the mercury emissions.

Andrew Lucero

2005-04-01T23:59:59.000Z

335

Hybrid Sulfur Thermochemical Process Development Annual Report  

SciTech Connect (OSTI)

The Hybrid Sulfur (HyS) Thermochemical Process is a means of producing hydrogen via water-splitting through a combination of chemical reactions and electrochemistry. Energy is supplied to the system as high temperature heat (approximately 900 C) and electricity. Advanced nuclear reactors (Generation IV) or central solar receivers can be the source of the primary energy. Large-scale hydrogen production based on this process could be a major contributor to meeting the needs of a hydrogen economy. This project's objectives include optimization of the HyS process design, analysis of technical issues and concerns, creation of a development plan, and laboratory-scale proof-of-concept testing. The key component of the HyS Process is the SO2-depolarized electrolyzer (SDE). Studies were performed that showed that an electrolyzer operating in the range of 500-600 mV per cell can lead to an overall HyS cycle efficiency in excess of 50%, which is superior to all other currently proposed thermochemical cycles. Economic analysis indicated hydrogen production costs of approximately $1.60 per kilogram for a mature nuclear hydrogen production plant. However, in order to meet commercialization goals, the electrolyzer should be capable of operating at high current density, have a long operating lifetime , and have an acceptable capital cost. The use of proton-exchange-membrane (PEM) technology, which leverages work for the development of PEM fuel cells, was selected as the most promising route to meeting these goals. The major accomplishments of this project were the design and construction of a suitable electrolyzer test facility and the proof-of-concept testing of a PEM-based SDE.

Summers, William A.; Buckner, Melvin R.

2005-07-21T23:59:59.000Z

336

Adsorptive Stripping Voltammetric Measurements of Trace Uranium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Measurements of Trace Uranium at the Bismuth Film Electrode. Abstract: Bismuth-coated carbon-fiber electrodes have been successfully applied for adsorptive-stripping...

337

Accelerated Ray Traced Animations Exploiting Temporal Coherence.  

E-Print Network [OSTI]

??Ray tracing is a well-know technique for producing realistic graphics. However, the time necessary to generate images is unacceptably long. When producing the many frames (more)

Baines, Darwin Tarry

2005-01-01T23:59:59.000Z

338

Role of Polysulfides in Reduction of Elemental Sulfur by the Hyperthermophilic Archaebacterium Pyrococcus furiosus  

Science Journals Connector (OSTI)

...thiosul- likely due to the fate, cysteine, and tetrahydrothiophene. Two of these, cys- -ophiles in the yeast...cysteine, trithiane, so- dium thiosulfate, or tetrahydrothiophene, none of which produced polysulfides during...

I. I. Blumentals; M. Itoh; G. J. Olson; R. M. Kelly

1990-05-01T23:59:59.000Z

339

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

E-Print Network [OSTI]

III T; Murphy J T. DOE/NETLs Phase II Mercury ControlFired Power Plants, DOE/NETL Mercury R&D Program Review,

Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

2008-01-01T23:59:59.000Z

340

The production of 34S-depleted sulfide during bacterial disproportionation of elemental sulfur  

Science Journals Connector (OSTI)

...20), SBB (Santa Barbara Basin) from (21), and CLB (Cape Lookout Bight, North Carolina) from (13...of the glacial Lake Agassiz basin. The lake occupied parts of...meltwater impounded in the southern basin of Lake Agassiz. This value...

DE Canfield; B Thamdrup

1994-12-23T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

E-Print Network [OSTI]

removal from flue gas of coal-fired power plants. Environ.Speciation in a 100-MW Coal-Fired Boiler with Low-NOxControl Technologies for Coal-Fired Power Plants, DOE/NETL

Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

2008-01-01T23:59:59.000Z

342

Layered Video Coding Offset Distortion Traces for Trace-Based Evaluation of Video Quality after  

E-Print Network [OSTI]

Layered Video Coding Offset Distortion Traces for Trace-Based Evaluation of Video Quality after@kom.aau.dk Abstract-- Currently available video traces for scalable en- coded video with more than one layer are a convenient repre- sentation of the encoded video for the evaluation of networking mechanisms. The video

Reisslein, Martin

343

Layered Video Coding Offset Distortion Traces for Trace-Based Evaluation of Video Quality after  

E-Print Network [OSTI]

1 Layered Video Coding Offset Distortion Traces for Trace-Based Evaluation of Video Quality after video traces for scalable encoded video with more than one layer are a convenient representation of the encoded video for the evaluation of networking mechanisms. The video distortion (RMSE) or quality (PSNR

Reisslein, Martin

344

ADDITIVE TESTING FOR IMPROVED SULFUR RETENTION: PRELIMINARY REPORT  

SciTech Connect (OSTI)

The Savannah River National Laboratory is collaborating with Alfred University to evaluate the potential for additives in borosilicate glass to improve sulfur retention. This preliminary report provides further background on the incorporation of sulfur in glass and outlines the experiments that are being performed by the collaborators. A simulated waste glass composition has been selected for the experimental studies. The first phase of experimental work will evaluate the impacts of BaO, PbO, and V{sub 2}O{sub 5} at concentrations of 1.0, 2.0, and 5.0 wt % on sulfate retention in simulated high level waste borosilicate glass. The second phase of experimental work will evaluate the effects of time at the melt temperature on sulfur retention. The resulting samples will be characterized to determine the amount of sulfur remaining as well as to identify the formation of any crystalline phases. The results will be used to guide the future selection of frits and glass forming chemicals in vitrifying Department of Energy wastes containing high sulfur concentrations.

Amoroso, J.; Fox, K.

2011-09-07T23:59:59.000Z

345

Why sequence Sulfur cycling in the Frasassi aquifer?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sulfur cycling in the Frasassi aquifer? sulfur cycling in the Frasassi aquifer? The terrestrial subsurface remains one of the least explored microbial habitats on earth, and is critical for understanding pollutant migration and attenuation, subsurface processes such as limestone dissolution (affecting porosity), and the search for life elsewhere in the solar system and beyond. The deep and sulfidic Frasassi aquifer (of Ancona, Italy) has emerged as a model system for studying sulfur cycling in the terrestrial subsurface, and this sequencing project has relevance for developing applications for wastewater treatment and capabilities relevant for radionuclide, metal and organic pollutant remediation that can be applied at environments at DOE subsurface sites. Principal Investigators: Jennifer Macalady, Penn State University

346

Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

II. Phase Equilibria II. Phase Equilibria Title Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria Publication Type Journal Article Year of Publication 1996 Authors Ridgway, Paul L., Frank R. McLarnon, and John S. Newman Journal Journal of the Electrochemistry Society Volume 143 Issue 2 Pagination 412-417 Keywords 25 ENERGY STORAGE, 36 MATERIALS SCIENCE, ALUMINIUM OXIDES, equilibrium, performance, PHASE DIAGRAMS, PHOSPHIDES, PHOSPHORUS ADDITIONS, SODIUM COMPOUNDS, SODIUM SULFIDES, SODIUM-SULFUR BATTERIES Abstract Equilibrium open-circuit cell voltage data from a sodium/{beta}{double_prime}-alumina/phosphorus-sulfur cell utilizing P/S ratios of 0, 0.143, and 0.332 and a sodium atom fraction ranging from 0 to 0.4 were interpreted to construct ternary phase diagrams of the Na-P-S ternary system at 350 and 400 C.

347

Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results  

SciTech Connect (OSTI)

A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

2004-01-25T23:59:59.000Z

348

Indication of Meissner Effect in Sulfur-Substituted Strontium Ruthenates  

E-Print Network [OSTI]

Ceramic samples of Sr2RuO(4-y)Sy (y=0.03-1.2) with intended isovalent substitution of oxygen by sulfur have been synthesized and explored in the temperature range 4-300K. It is found that at a range of optimum sulfur substitution the magnetic response of ceramic samples reveals large diamagnetic signal with amplitudes approaching comparability with that of the YBCO-superconductors. Contrary to a pure ceramic Sr2RuO4, if properly optimized, the resistivity of sulfur-substituted samples has a metallic behavior except at lower temperatures where an upturn occurs. Both synthesis conditions and results of measurements are reported. The Meissner effect may point to high-temperature superconductivity.

Gulian, Armen

2011-01-01T23:59:59.000Z

349

HYBRID SULFUR ELECTROLYZER DEVELOPMENT FY09 SECOND QUARTER REPORT  

SciTech Connect (OSTI)

The primary objective of the DOE-NE Nuclear Hydrogen Initiative (NHI) is to develop the nuclear hydrogen production technologies necessary to produce hydrogen at a cost competitive with other alternative transportation fuels. The focus of the NHI is on thermochemical cycles and high temperature electrolysis that can be powered by heat from high temperature gas reactors. The Savannah River National Laboratory (SRNL) has been tasked with the primary responsibility to perform research and development in order to characterize, evaluate and develop the Hybrid Sulfur (HyS) thermochemical process. This report documents work during the first quarter of Fiscal Year 2009, for the period between January 1, 2009 and March 31, 2009. The HyS Process is a two-step hybrid thermochemical cycle that is part of the 'Sulfur Family' of cycles. As a sulfur cycle, it uses high temperature thermal decomposition of sulfuric acid to produce oxygen and to regenerate the sulfur dioxide reactant. The second step of the process uses a sulfur dioxide depolarized electrolyzer (SDE) to split water and produce hydrogen by electrochemically reacting sulfur dioxide with H{sub 2}O. The SDE produces sulfuric acid, which is then sent to the acid decomposer to complete the cycle. The DOE NHI program is developing the acid decomposer at Sandia National Laboratory for application to both the HyS Process and the Sulfur Iodine Cycle. The SDE is being developed at SRNL. During FY05 and FY06, SRNL designed and conducted proof-of-concept testing for a SDE using a low temperature, PEM fuel cell-type design concept. The advantages of this design concept include high electrochemical efficiency, small footprint and potential for low capital cost, characteristics that are crucial for successful implementation on a commercial scale. During FY07, SRNL extended the range of testing of the SDE to higher temperature and pressure, conducted a 100-hour longevity test with a 60-cm{sup 2} single cell electrolyzer, and designed and built a larger, multi-cell stack electrolyzer. During FY08, SRNL continued SDE development, including development and successful testing of a three-cell electrolyzer stack with a rated capacity of 100 liters per hour. The HyS program for FY09 program will address improving SDE performance by focusing on preventing or minimizing sulfur deposition inside the cell caused by SO{sub 2} crossover, reduction of cell voltage for improved efficiency, an extension of cell operating lifetime. During FY09 a baseline technology development program is being conducted to address each of these issues. Button-cell (2-cm{sup 2}) and single cell (60-cm{sup 2}) SDEs will be fabricated and tested. A pressurized button-cell test facility will be designed and constructed to facilitate addition testing. The single cell test facility will be upgraded for unattended operation, and later for operation at higher temperature and pressure. Work will continue on development of the Gas Diffusion Electrode (GDE), or Gap Cell, as an alternative electrolyzer design approach that is being developed under subcontract with industry partner Giner Electrochemical Systems. If successful, it could provide an alternative means of preventing sulfur crossover through the proton exchange membrane, as well as the possibility for higher current density operation based on more rapid mass transfer in a gas-phase anode. Promising cell components will be assembled into membrane electrode assemblies (MEAs) and tested in the single cell test facility. Upon modification for unattended operation, test will be conducted for 200 hours or more. Both the button-cell and modified single cell facility will be utilized to demonstrate electrolyzer operation without sulfur build-up limitations, which is a Level 1 Milestone.

Herman, D; David Hobbs, D; Hector Colon-Mercado, H; Timothy Steeper, T; John Steimke, J; Mark Elvington, M

2009-04-15T23:59:59.000Z

350

Extraction, separation, and analysis of high sulfur coal. Final report  

SciTech Connect (OSTI)

The work described in this report studies the removal of sulfur by oxidative interaction of various cupric salts with coal and also considers the possibility of removing organic sulfur by the selective interaction of supercritical ethanol with the organic coal matrix. Either one of these methods could potentially be used to pretreat coals before burning. The primary purpose of these studies is to ascertain the nature of the chemical reactions occurring, the chemical composition of the resultant products, and information on possible reaction mechanisms. This information should allow prediction of reasonable reaction conditions for the removal of organosulfur compound from coal.

Olesik, S.V.; Pekay, L.A.; Larkins, W. Jr. [comps.

1992-05-31T23:59:59.000Z

351

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect (OSTI)

The work described in this report studies the removal of sulfur by oxidative interaction of various cupric salts with coal and also considers the possibility of removing organic sulfur by the selective interaction of supercritical ethanol with the organic coal matrix. Either one of these methods could potentially be used to pretreat coals before burning. The primary purpose of these studies is to ascertain the nature of the chemical reactions occurring, the chemical composition of the resultant products, and information on possible reaction mechanisms. This information should allow prediction of reasonable reaction conditions for the removal of organosulfur compound from coal.

Olesik, S.V.; Pekay, L.A.; Larkins, W. Jr. (comps.)

1992-05-31T23:59:59.000Z

352

Sulfur dioxide oxidation and plume formation at cement kilns  

SciTech Connect (OSTI)

Results of source sampling at the Glens Falls cement kiln in Glens Falls, N.Y., are reported for sulfur oxides, ammonia, hydrochloric acid, oxygen, and moisture content. The origin of a detached, high-opacity, persistent plume originating from the cement kiln stack is investigated. It is proposed that this plume is due to ammonium salts of SOx and sulfuric acid that have been formed in condensed water droplets in the plume by the pseudocatalytic action of ammonia. (1 diagram, 1 graph, 22 references, 7 tables)

Dellinger, B.; Grotecloss, G.; Fortune, C.R.; Cheney, J.L.; Homolya, J.B.

1980-10-01T23:59:59.000Z

353

Microwave Plasma Monitoring System For Real-Time Elemental Analysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Microwave Plasma Monitoring System For Real-Time Elemental Analysis Microwave Plasma Monitoring System For Real-Time Elemental Analysis Microwave Plasma Monitoring System For Real-Time Elemental Analysis The invention apparatus can also be used to monitor for the presence of halogens, sulfur and silicon. Available for thumbnail of Feynman Center (505) 665-9090 Email Microwave Plasma Monitoring System For Real-Time Elemental Analysis There has been invented a process for analyzing ambient air in a microwave induced plasma without use of an additional carrier gas. There has also been invented an apparatus for analyzing ambient air, other sample gas, or nebulized and desolvated liquids wherein a novel arrangement of plasma gas and sample gas conduits is used to enhance dependability of the plasma. This apparatus embodiment of the invention has a concentric arrangement of

354

Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Tier 2 Vehicle and Tier 2 Vehicle and Gasoline Sulfur Program to someone by E-mail Share Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Facebook Tweet about Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Twitter Bookmark Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Google Bookmark Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Delicious Rank Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Digg Find More places to share Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Tier 2 Vehicle and Gasoline Sulfur Program

355

Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System effect and performance...

356

Revisit Carbon/Sulfur Composite for Li-S Batteries. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Revisit CarbonSulfur Composite for Li-S Batteries. Revisit CarbonSulfur Composite for Li-S Batteries. Abstract: To correlate the carbon properties e.g. surface area and porous...

357

A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts  

E-Print Network [OSTI]

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

358

System for adding sulfur to a fuel cell stack system for improved fuel cell stability  

DOE Patents [OSTI]

A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Mukerjee, Subhasish (Pittsford, NY); Haltiner, Jr., Karl J (Fairport, NY); Weissman, Jeffrey G. (West Henrietta, NY)

2012-03-06T23:59:59.000Z

359

Ultra-Low Sulfur diesel Update & Future Light Duty Diesel | Department...  

Broader source: Energy.gov (indexed) [DOE]

Ultra-Low Sulfur diesel Update & Future Light Duty Diesel Ultra-Low Sulfur diesel Update & Future Light Duty Diesel Presentation given at DEER 2006, August 20-24, 2006, Detroit,...

360

Trace and ultratrace metals in bottled waters: Survey of sources worldwide and comparison with refillable metal bottles  

Science Journals Connector (OSTI)

Bottled waters from diverse natural and industrial sources are becoming increasingly popular worldwide. Several potentially harmful trace metals (Ag, Be, Li, Ge, Sb, Sc, Te, Th, U) are not monitored regularly in such waters. As a consequence, there is extremely limited data on the abundance and potential health impacts of many potentially toxic trace elements. Containers used for the storage of bottled waters might also increase trace metal levels above threshold limits established for human consumption by the EPA or WHO. Applying strict clean room techniques and sector field ICPMS, 23 elements were determined in 132 brands of bottled water from 28 countries. In addition, leaching experiments with high purity water and various popular metal bottles investigated the release of trace metals from these containers. The threshold limits for elements such as Al, Be, Mn and U in drinking water were clearly exceeded in some waters. Several bottled waters had Li concentrations in the low mg/L range, a level which is comparable to blood plasma levels of patients treated against manic depression with Li-containing drugs. The rate of release of trace metals from metal bottles assessed after 13days was generally low, with one exception: Substantial amounts of both Sb and Tl were released from a commercially available pewter pocket flask, exceeding international guidelines 5- and 11-fold, respectively. Trace metal levels of most bottled waters are below guideline levels currently considered harmful for human health. The few exceptions that exist, however, clearly reveal that health concerns are likely to manifest through prolonged use of such waters. The investigated coated aluminium and stainless steel bottles are harmless with respect to leaching of trace metals into drinking water. Pocket flasks, in turn, should be selected with great care to avoid contamination of beverages with harmful amounts of potentially toxic trace metals such as Sb and Tl.

Michael Krachler; William Shotyk

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Sulfur Degassing From Volcanoes: Source Conditions, Surveillance, Plume Chemistry and Earth System Impacts  

E-Print Network [OSTI]

of sulfur in magmas owes much to its multiple valence states (-II, 0, IV, VI), speciation (e.g., S2, H2S, SO on the redox chemistry of sulfur: by reducing sulfur, thiosulfate, sulfite and sulfate to H2S, or oxidizing sulfur and H2S to sulfate (e.g., Takano et al. 1997; Amend and Shock 2001; Shock et al. 2010

Boyer, Edmond

362

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO[sub x]) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO[sub x]) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO[sub x] to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO[sub 2] and SO[sub 3]. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U. S. coal.

Not Available

1992-08-01T23:59:59.000Z

363

Ultrasensitive Voltammetric Detection of Trace Heavy Metal Ions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Voltammetric Detection of Trace Heavy Metal Ions Using Carbon Nanotube Nanoelectrode Array. Ultrasensitive Voltammetric Detection of Trace Heavy Metal Ions Using Carbon Nanotube...

364

Infrared near-field spectroscopy of trace explosives using an...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectroscopy of trace explosives using an external cavity quantum cascade laser. Infrared near-field spectroscopy of trace explosives using an external cavity quantum...

365

Sulfur-deactivated steam reforming of gasified biomass  

SciTech Connect (OSTI)

The effect of hydrogen sulfide on the stream reforming of methane has been studied. Methane is the most difficult component to convert by steam reforming in the mixture of hydrocarbons, which is produced in biomass gasification. Two catalysts were subjected to hydrogen sulfide levels up to 300 ppm so as to study the effect of sulfur on their deactivation. These catalysts were the C11-9-061, from United Catalyst Inc., and the HTSR1, from Haldor Topsoee. The activation energy of the sulfur-deactivated steam-reforming reaction was calculated to be 280 and 260 kJ/mol, for each catalyst, respectively. The high values most probably originate from the fact that the degree of sulfur coverage of the nickel surface is close to 1 for these experiments. Even under these severe conditions, steam reforming of methane is possible without any carbon formation. The HTSR1 catalyst exhibits a very high sulfur-free activity, resulting in a performance in the presence of hydrogen sulfide higher than that for the C11-9-061 catalyst. By using the HTSR1 catalyst, the reactor temperature can be lowered by 60 C in order to reach comparable levels of conversion.

Koningen, J.; Sjoestroem, K. [Kungl Tekniska Hoegskolan, Stockholm (Sweden)] [Kungl Tekniska Hoegskolan, Stockholm (Sweden)

1998-02-01T23:59:59.000Z

366

Effect of sulfur on heavy duty diesel engine lubricants  

SciTech Connect (OSTI)

Diesel engine exhaust legislation has become quite onerous for heavy duty engines. Yet, these high thermal efficiency engines continue to meet lower exhaust particulate and NOx emissions limits, due to new engine designs and the complementary engine oil performance requirements of the API service categories. In addition, the EPA has mandated changes in on-highway diesel fuel to help meet particulate emissions regulations. On October 1, 1993, when the EPA outlawed high sulfur fuels for on-highway use, the development of the API CG-4 engine oil performance specification was already in progress. All the new diesel engine tests in the category were therefore designed to run with low (< 0.05% wt.) sulfur fuel. In some engine tests, this new fuel improved some lubricant performance characteristics and degraded others. An engine oil specification for low sulfur fuel brings new challenges to developing future specifications for diesel engine oils. Both higher and lower lubricant additive treat rate products, high performance single grade oils, and formulations to meet world-wide specifications become viable. This paper discusses the results of a diesel engine oil technology that performs well with the new, low sulfur fuel in both engine tests and in the field.

Hayden, T.E. [Texaco Fuels and Lubricants Research Dept., Beacon, NY (United States)

1996-12-01T23:59:59.000Z

367

Revisit Carbon/Sulfur Composite for Li-S Batteries  

SciTech Connect (OSTI)

To correlate the carbon properties e.g. surface area and porous structure, with the electrochemical behaviors of carbon/sulfur (C/S) composite cathodes for lithium-sulfur (Li-S) batteries, four different carbon frameworks including Ketjen Black (KB, high surface area and porous), Graphene (high surface area and nonporous), Acetylene Black (AB, low surface area and nonporous) and Hollow Carbon Nano Sphere (HCNS, low surface area and porous) are employed to immobilize sulfur (80 wt.%). It has been revealed that high surface area of carbon improves the utilization rate of active sulfur and decreases the real current density during the electrochemical reactions. Accordingly, increased reversible capacities and reduced polarization are observed for high surface area carbon hosts such as KB/S and graphene/S composites. The porous structure of KB or HCNS matrix promotes the long-term cycling stability of C/S composites but only at relatively low rate (0.2 C). Once the current density increases, the pore effect completely disappears and all Li-S batteries show similar trend of capacity degradation regardless of the different carbon hosts used in the cathodes. The reason has been assigned to the formation of reduced amount of irreversible Li2S on the cathode as well as shortened time for polysulfides to transport towards lithium anode at elevated current densities. This work provides valuable information for predictive selection on carbon materials to construct C/S composite for practical applications from the electrochemical point of view.

Zheng, Jianming; Gu, Meng; Wagner, Michael J.; Hays, Kevin; Li, Xiaohong S.; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

2013-07-23T23:59:59.000Z

368

Workshop on sulfur chemistry in flue gas desulfurization  

SciTech Connect (OSTI)

The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

Wallace, W.E. Jr.

1980-05-01T23:59:59.000Z

369

Auction design and the market for sulfur dioxide emissions  

E-Print Network [OSTI]

Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

Joskow, Paul L.

1996-01-01T23:59:59.000Z

370

Sulfur tolerant molten carbonate fuel cell anode and process  

DOE Patents [OSTI]

Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

Remick, Robert J. (Naperville, IL)

1990-01-01T23:59:59.000Z

371

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase  

E-Print Network [OSTI]

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase Mercury: Sulfur was impregnated onto activated carbon fibers ACFs through H2S oxidation catalyzed by the sorbent CE Database subject headings: Activated carbon; Sulfur; Mercury; Hydrogen sulfides; Oxidation

Borguet, Eric

372

Sulfur-induced greenhouse warming on early Mars Sarah Stewart Johnson,1  

E-Print Network [OSTI]

and 500 mbar CO2 with varying abundances of H2O and sulfur volatiles (H2S and SO2 mixing ratios of 10?3Sulfur-induced greenhouse warming on early Mars Sarah Stewart Johnson,1 Michael A. Mischna,2 melting model, we obtain a high sulfur solubility, approximately 1400 ppm, in Martian mantle melts. We

Zuber, Maria

373

FY08 MEMBRANE CHARACTERIZATION REPORT FOR HYBRID SULFUR ELECTROLYZER  

SciTech Connect (OSTI)

This report summarizes results from all of the membrane testing completed to date at the Savannah River National Laboratory (SRNL) for the sulfur dioxide-depolarized electrolyzer (SDE). Several types of commercially-available membranes have been analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid (PFSA), sulfonated polyether-ketone-ketone (SPEKK), and polybenzimidazole membranes (PBI). Of these membrane types, the poly-benzimidazole membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Several experimental membranes have also been analyzed including hydrated sulfonated Diels-Alder polyphenylenes (SDAPP) membranes from Sandia National Laboratory, perfluorosulfonimide (PFSI) and sulfonated perfluorocyclobutyl aromatic ether (S-PFCB) prepared by Clemson University, hydrated platinum-treated PFSA prepared by Giner Electrochemical Systems (GES) and Pt-Nafion{reg_sign} 115 composites prepared at SRNL. The chemical stability, SO{sub 2} transport and ionic conductivity characteristics have been measured for several commercially available and experimental proton-conducting membranes. Commercially available PFSA membranes such as the Nafion{reg_sign} series exhibited excellent chemical stability and ionic conductivity in sulfur dioxide saturated sulfuric acid solutions. Sulfur dioxide transport in the Nafion{reg_sign} membranes varied proportionally with the thickness and equivalent weight of the membrane. Although the SO{sub 2} transport in the Nafion{reg_sign} membranes is higher than desired, the excellent chemical stability and conductivity makes this membrane the best commercially-available membrane at this time. Initial results indicated that a modified Nafion{reg_sign} membrane incorporating Pt nanoparticles exhibited significantly reduced SO{sub 2} transport. Reduced SO{sub 2} transport was also measured with commercially available PBI membrane and several experimental membranes produced at SNL and Clemson. These membranes also exhibit good chemical stability and conductivity in concentrated sulfuric acid solutions and, thus, serve as promising candidates for the SDE. Therefore, we recommend further testing of these membranes including electrolyzer testing to determine if the reduced SO{sub 2} transport eliminates the formation of sulfur-containing films at the membrane/cathode interface. SO{sub 2} transport measurements in the custom built characterization cell identified experimental limitations of the original design. During the last quarter of FY08 we redesigned and fabricated a new testing cell to overcome the previous limitations. This cell also offers the capability to test membranes under polarized conditions as well as test the performance of MEAs under selected electrolyzer conditions.

Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

2008-09-01T23:59:59.000Z

374

Studies on the sulfur poisoning of Ru-RuO{sub x}/TiO{sub 2} catalyst for the adsorption and methanation of carbon monoxide  

SciTech Connect (OSTI)

The effects of sulfur poisoning on the chemisorption and on the methanation of carbon monoxide over Ru/TiO{sub 2} catalyst were investigated by FTIR spectroscopy and volumetric gas adsorption measurements. The CS{sub 2} molecules are {eta}` bonded to Ru sites through one of the sulfur atoms and decompose to the constituent elements on thermal activation. Each S atom may deactivate 3 to 10 metal sites even at low coverages, the effect being more pronounced on the chemisorption of hydrogen. The deposited sulfur (and possibly carbon also) sterically hinders the formation of certain multicarbonyl and monocarbonyl species (vCO in 2055-2140 cm{sup -1} region), which otherwise transform to methane via surface methylene groups in the presence of chemisorbed hydrogen and are found to play an important role in the low-temperature methanation activity of the studied catalyst. The Ru-CO species giving rise to lower frequency vibrational bands are affected to a lesser extent. The presence of sulfur also results in the development of some new CO binding states which are weak and are identified with the CO and S coadsorbed at Ru sites of different oxidation states or of varying crystallographic nature. The CO adsorbed in these states is not reactive to hydrogen. 45 refs., 9 figs., 1 tab.

Kamble, V.S.; Londhe, V.P.; Gupta, N.M. [Bhambha Atomic Research centre, Bombay (India)] [and others] [Bhambha Atomic Research centre, Bombay (India); and others

1996-02-01T23:59:59.000Z

375

ACCEPTED MANUSCRIPT The behaviour of Rare-Earth Elements, Zr and Hf during biologically-mediated  

E-Print Network [OSTI]

ACCEPTED MANUSCRIPT ACCEPTED MANUSCRIPT 1 The behaviour of Rare-Earth Elements, Zr and Hf during.a,b* , Cangemi M.a , Brusca L.c , Madonia P.c , Saiano F.d , Zuddas P.e a) Department of Earth and Marine at the solid-liquid interface influencing the distribution of trace elements onto microbial surfaces. Since

376

Extraction of trace metals from fly ash  

DOE Patents [OSTI]

A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, M.; Wai, C.M.; Nagy, Z.

1983-08-15T23:59:59.000Z

377

Extraction of trace metals from fly ash  

DOE Patents [OSTI]

A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

1984-01-01T23:59:59.000Z

378

Effect of residual elements on high performance nickel base superalloys for gas turbines and strategies for manufacture  

Science Journals Connector (OSTI)

The need for better gas turbine operating efficiency and reliability has resulted in tightening of specification and acceptance standards. It has been realized that some elements even at trace level, can have ...

O. P. Sinha; M. Chatterjee; V. V. R. S. Sarma; S. N. Jha

2005-07-01T23:59:59.000Z

379

CP-violating CFT and trace anomaly  

E-Print Network [OSTI]

It is logically possible that the trace anomaly in four dimension includes the Hirzebruch-Pontryagin density in CP violating theories. Although the term vanishes at free conformal fixed points, we realize such a possibility in the holographic renormalization group and show that it is indeed possible. The Hirzebruch-Pontryagin term in the trace anomaly may serve as a barometer to understand how much CP is violated in conformal field theories.

Yu Nakayama

2012-01-17T23:59:59.000Z

380

Enhanced electrochemical performance by wrapping graphene on carbon nanotube/sulfur composites for rechargeable lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract A novel graphene-wrapped carbon nanotube/sulfur structure was designed to improve the electrochemical performance of the lithiumsulfur (LiS) batteries. Owing to the introduction of the reduced graphene oxide (rGO) with the aim to restrain the polysulfide anions diffusion phenomenon, increase the overall electronic conductivity of the electrode and accommodate volume expansion between the delithiated S and lithiated Li2S phases, the resulted graphene-wrapped carbon nanotube/sulfur (S/CNT@rGO) composite makes the cycling performance of the LiS batteries better than that without rGO. The S/CNT@rGO composite showed an initial discharge capacity of ~1299mAhg?1 at 0.2C rate. After 100 cycles of charge/discharge, the S/CNT@rGO composite retained a high specific capacity of ~670mAhg?1, much higher than that without rGO (graphene-wrapped carbon nanotube/sulfur composite could be a promising cathode material for high-rate performance LiS batteries.

Yishan Wu; Chunmei Xu; Jinxin Guo; Qingmei Su; Gaohui Du; Jun Zhang

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Compound and Elemental Analysis At Central Nevada Seismic Zone Region  

Open Energy Info (EERE)

Nevada Nevada Seismic Zone Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Central Nevada Seismic Zone Geothermal Region Exploration Technique Compound and Elemental Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for geothermal exploration, the analysis of lithium and other elements in tufa deposits could serve as exploration guides for hot spring lithium

382

Compound and Elemental Analysis At Northern Basin & Range Region  

Open Energy Info (EERE)

(Coolbaugh, Et Al., 2010) (Coolbaugh, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Northern Basin & Range Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Northern Basin and Range Geothermal Region Exploration Technique Compound and Elemental Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for

383

Strong Sulfur Binding with Conducting Magneli-Phase TinO2n-1 Nanomaterials for Improving Lithium-Sulfur Batteries  

E-Print Network [OSTI]

will go through a series of soluble intermediate higher-order polysulfides (Li2S8, Li2S6, and Li2S4 of Li2S2, Li2S, and sulfur.6-8 In order to solve these challenges, there have been recent developmentsStrong Sulfur Binding with Conducting Magneli-Phase TinO2n-1 Nanomaterials for Improving Lithium-Sulfur

Cui, Yi

384

Investigation into the effects of trace coal syn gas species on the performance of solid oxide fuel cell anodes, PhD. thesis, Russ College of Engineering and Technology of Ohio University  

SciTech Connect (OSTI)

Coal is the United States most widely used fossil fuel for the production of electric power. Coals availability and cost dictates that it will be used for many years to come in the United States for power production. As a result of the environmental impact of burning coal for power production more efficient and environmentally benign power production processes using coal are sought. Solid oxide fuel cells (SOFCs) combined with gasification technologies represent a potential methodology to produce electric power using coal in a much more efficient and cleaner manner. It has been shown in the past that trace species contained in coal, such as sulfur, severely degrade the performance of solid oxide fuel cells rendering them useless. Coal derived syngas cleanup technologies have been developed that efficiently remove sulfur to levels that do not cause any performance losses in solid oxide fuel cells. The ability of these systems to clean other trace species contained in syngas is not known nor is the effect of these trace species on the performance of solid oxide fuel cells. This works presents the thermodynamic and diffusion transport simulations that were combined with experimental testing to evaluate the effects of the trace species on the performance of solid oxide fuel cells. The results show that some trace species contained in coal will interact with the SOFC anode. In addition to the transport and thermodynamic simulations that were completed experimental tests were completed investigating the effect of HCl and AsH3 on the performance of SOFCs.

Trembly, J.P.

2007-06-01T23:59:59.000Z

385

Sulfur-tolerant anode materials for solid oxide fuel cell application  

SciTech Connect (OSTI)

This paper summarizes the degradation mechanisms for SOFC anodes in the presence of sulfur and recent developments in sulfur-tolerant anodes. There are two primary sulfur-degradation mechanisms for the anode materials: physical absorption of sulfur that blocks the hydrogen reaction sites, and chemical reaction that forms nickel sulfide. The sulfur-tolerant anodes are categorized into three kinds of materials: thiospinels and metal sulfides, metal cermets, and mixed ionic and electronic conductors. Each material has its own advantages and disadvantages, and the combined application of available materials to serve as different functional components in anodes through proper design may be effective to achieve a balance between stability and performance.

Gong, M. (West Virginia University, Morgantown, WV); Liu, X. (West Virginia University, Morgantown, WV); Trembly, J.; Johnson, C.

2007-06-01T23:59:59.000Z

386

Sulfur tolerant anode materials. Quarterly report, October 1--December 31, 1987  

SciTech Connect (OSTI)

The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

Not Available

1988-02-01T23:59:59.000Z

387

Sulfur tolerant anode materials. Quarterly report, January 1--March 31, 1988  

SciTech Connect (OSTI)

The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

Not Available

1988-05-01T23:59:59.000Z

388

Method of burning sulfur-containing fuels in a fluidized bed boiler  

DOE Patents [OSTI]

A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

Jones, Brian C. (Windsor, CT)

1982-01-01T23:59:59.000Z

389

Flue-gas sulfur-recovery plant for a multifuel boiler  

SciTech Connect (OSTI)

In October 1991, a Finnish fluting mill brought on stream a flue-gas desulfurization plant with an SO{sub 2} reduction capacity of 99%. The desulfurization plant enabled the mill to discontinue the use of its sulfur burner for SO{sub 2} production. The required makeup sulfur is now obtained in the form of sulfuric acid used by the acetic acid plant, which operates in conjunction with the evaporating plant. The mill`s sulfur consumption has decreased by about 6,000 tons/year (13.2 million lb/year) because of sulfur recycling.

Miettunen, J. [Tampella Power Inc., Tampere (Finland); Aitlahti, S. [Savon Sellu Oy, Kuopio (Finland)

1993-12-01T23:59:59.000Z

390

In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In situ Observation of Sulfur in Living In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine into MDCK Cells Sulfur is essential for life. It plays important roles in the amino acids methionine and cysteine, and has a structural function in disulfide bonds. As a component of iron-sulfur clusters it takes part in electron and sulfur transfer reactions.1 Glutathione, a sulfur-containing tripeptide, is an important part of biological antioxidant systems.2 Another example for the biological relevance of sulfur is the amino acid taurine, which is present in high concentrations in algae and the animal kingdom. Taurine has been implicated in a range of physiological phenomena, but its osmolytic role in cell volume regulation has been studied in greatest detail.3 In situ information on sulfur is rare despite its important biological role. This is due to the fact that sulfur is not easily accessible with most biophysical techniques. In recent years, sulfur x-ray absorption spectroscopy (XAS) has become increasingly important in the study of sulfur species in biological systems.4 The near-edge region of the XAS spectrum is a sensitive probe of electronic structure and hence chemical form.5

391

SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CSP Generation CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage to someone by E-mail Share SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Facebook Tweet about SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Twitter Bookmark SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Google Bookmark SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Delicious Rank SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Digg Find More places to share SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on

392

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

SciTech Connect (OSTI)

Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

2012-06-20T23:59:59.000Z

393

The fate of chlorine, sulfur, and potassium during co-combustion of bark, sludge, and solid recovered fuel in an industrial scale BFB boiler  

Science Journals Connector (OSTI)

The effect of fuel composition on the fate of chlorine, sulfur, and potassium was investigated during an extensive measurement campaign in a 107 \\{MWth\\} bubbling fluidized bed (BFB) combustor. Bark, sludge, and solid recovered fuel (SRF) were co-combusted in different proportions during the campaign. The elemental composition of the fuel and outgoing ashes was determined, supplemented with gas composition measurements, to obtain the distribution of chlorine, sulfur, and potassium. Additionally, chemical fractionation was carried out for the pure fuels to study the leachability of the ash-forming elements. When firing bark and bark+sludge, potassium, sulfur, and chlorine ended up mainly in the fly ash stream. When SRF was a part of the fuel mixture a considerable amount of SO2 was measured in the second pass. Most of the chlorine entering with the fuel was found as gaseous \\{HCl\\} in the second pass, which indicates that sulfation reactions took place in the furnace. Most of the \\{HCl\\} and a part of the SO2 were captured in the baghouse filter ash and the emissions of these gases were low. This work showed the positive effects of co-firing challenging fuels.

Emil Vainio; Patrik Yrjas; Maria Zevenhoven; Anders Brink; Tor Laurn; Mikko Hupa; Tuula Kajolinna; Hannu Vesala

2013-01-01T23:59:59.000Z

394

Short-Term Fates of High Sulfur Inputs in Northern California Vineyard Soils  

SciTech Connect (OSTI)

The widespread application of elemental sulfur (S{sup 0}) to vineyards may have ecosystem effects at multiple scales. We evaluated the short-term fates of applied S{sup 0} in a Napa Valley vineyard; we determined changes in soil sulfur (S) speciation (measured by X-ray absorption near-edge structure (XANES) spectroscopy), soil pH, extractable sulfate (SO{sub 4}{sup 2-}), and total S to evaluate changes in acidity and soil S within the vineyard over time. Surface soil samples were collected immediately prior to and following two applications of S{sup 0} (6.7 kg S{sup 0} ha{sup -1}), with weekly collections in the 2 weeks between applications and following the last application. XANES spectra indicated that the majority of soil S persists in the +6 oxidation state and that S{sup 0} oxidizes within 7 days following application. Soil pH and extractable SO{sub 4}{sup 2-} measurements taken at 30 min after S{sup 0} application revealed generation of acidity and an increase in extractable SO{sub 4}{sup 2-}, but by 12 days after application, soil pH increased to approximately pre-application levels. These data suggest that the major consequence of reactive S applications in vineyards may be the accumulation of soil SO{sub 4}{sup 2-} and organic S during the growing season, which can be mobilized during storm events during the dormant (wet) season. In spatially-extensive winegrowing regions where these applications are made by hundreds of individual farmers each year, it will be important to understand the long-term implications of this perturbation to the regional S cycle.

E Hinckley; S Fendorf; P Matson

2011-12-31T23:59:59.000Z

395

Recovery of phosphates from elemental phosphorus bearing wastes  

SciTech Connect (OSTI)

A process for oxidizing aqueous elemental phosphorus containing residues (sludges) to produce orthophosphate containing slurries suitable for subsequent reaction with ammonia to produce nitrogen and phosphate containing fertilizer products is presented. It comprises reacting aqueous elemental phosphorus containing residues with certain special mixtures of concentrated nitric acid and sulfuric acid to effect the conversion of the elemental phosphorus into mostly orthophosphoric acid and very little orthophosphorus acid with the relative ratios of the two acids being dependent upon the mole ratio of H{sub 2}SO{sub 4}:HNO{sub 3} employed in the processing. The resulting aqueous reaction intermediate is neutralized with ammonia during processing to a fluid or solid fertilizer product. Prior to the conversion to products, the aqueous reaction intermediate may be subjected to a solids separation step to remove insoluble salts of certain environmentally undesirable metals, such as Pb, Cd, Ba, and Cr.

Edwards, R.E.; Moore, O.E.; Sullivan, J.M.

1994-10-01T23:59:59.000Z

396

Sulfur Lamps-The Next Generation of Efficient Light?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 5 Sulfur Lamps-The Next Generation of Efficient Light? The figure above is a schematic of the system installed at the National Air and Space Museum and the DOE headquarters in Washington, D.C., Light from the sulfur lamp is focused by a parabolic reflector so that it enters the light pipe within a small angular cone. Light travels down the pipe, reflecting off the prismatic film (A) that lines the outer acrylic tube. The prismatic film reflects the light through total internal reflection (C), an intrinsically efficient process. Some of the light striking the film (at A) is not reflected and "leaks out" of the pipe walls (B), giving the pipe a glowing appearance. A light ray that travels all the way down the pipe will strike the mirror at the end (D) and return back up the pipe.

397

Cost-cutting for offshore sulfur recovery processes studied  

SciTech Connect (OSTI)

An increasing portion of future US gas supply is likely to come from offshore, primarily Gulf of Mexico. Because this gas can be sour, the industry has sought lower cost H{sub 2}S-removal/recovery processes for treating it. Usually the gas contains < 5 tons/day (tpd) of sulfur. A study to compare several emerging sulfur-removal/recovery processes against a baseline Amine/LO-CAT II process has indicated that some emerging processes, though not yet commercialized, show considerable potential for reducing costs. Specifically, the major findings were that Double Loop and CrystaSulf, developed by Radian International LLC, Austin, were the least expensive capital-cost processes by a significant margin and that Marathon Oil Co.`s Hysulf`s cost has the potential to compete with Double Loop and CrystaSulf.

Quinlan, M.P.; Echterhoff, L.W. [M.W. Kellogg Co., Houston, TX (United States); Leppin, D.; Meyer, H.S. [Gas Research Inst., Chicago, IL (United States)

1997-07-21T23:59:59.000Z

398

Method of making sulfur-resistant composite metal membranes  

DOE Patents [OSTI]

The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.

Way, J. Douglas (Boulder, CO) [Boulder, CO; Lusk, Mark (Golden, CO) [Golden, CO; Thoen, Paul (Littleton, CO) [Littleton, CO

2012-01-24T23:59:59.000Z

399

Availability of heavy fuel oils by sulfur level, September 1981  

SciTech Connect (OSTI)

A narrative analysis of the status of the United States' total new supply of heavy fuel oils, is given with emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held, refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and refinery Districts. Imports are given by PAD District, by country of origin, and by importing State. Waterborne movements from PAD District III to other districts are detailed for the most recent month only. This report was previously published by the Bureau of Mines in the Minerals Industries Surveys Series under the same title. Publication was discontinued with the December 1981 issue. 2 figures, 13 tables.

Wolfrey, J.

1981-01-01T23:59:59.000Z

400

More Economical Sulfur Removal for Fuel Processing Plants  

Broader source: Energy.gov (indexed) [DOE]

enabled TDA to develop and commercialize its direct oxidation process-a simple, catalyst-based system for removing sulfur from natural gas and petroleum-that was convenient and economical enough for smaller fuel processing plants to use. TDA Research, Inc. (TDA) of Wheat Ridge, CO, formed in 1987, is a privately-held R&D company that brings products to market either by forming internal business

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Structure of Chemisorbed Sulfur on a Pt(111) Electrode  

Science Journals Connector (OSTI)

Contribution from the Department of Chemistry, University of Illinois and Frederick Seitz Materials Research Laboratory, 600 S. Mathews Ave., Urbana, Illinois 61801, and Dpartement de Chimie, Universit de Sherbrooke, Sherbrooke, Qubec, J1K 2R1, Canada ... Sulfur was deposited from aqueous sulfide and bisulfide media on Pt(111), and the interrogations were conducted by low electron energy diffraction (LEED), Auger electron spectroscopy (AES), and core-level electron energy loss spectroscopy (CEELS). ...

Y.-E. Sung; W. Chrzanowski; A. Zolfaghari; G. Jerkiewicz; A. Wieckowski

1997-01-08T23:59:59.000Z

402

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network [OSTI]

HYDROGEN AND SULFUR PRODUCTION FROM HYDROGEN SULFIDE WASTES? John B.L. Harkness and Richard D. Doctor, Argonne National Laboratory, Argonne. IL ABSTRACT A new hydrogen sulfide waste-treatment process that uses microwave plasma... to be economically competitive. In addition, the experiments show-that. typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology. BACKGROUND In 1987, Argonne staff found the first...

Harkness, J.; Doctor, R. D.

403

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect (OSTI)

Coal Reaction Study: The results of the reaction of aqueous cupric chloride with Illinois {number sign}6 coal are listed on page 21. These results indicate that the oxidative desulfurization of coal with cupric chloride is more complex and less effective than previously reported. Although almost all the pyritic and sulfate sulfur are removed from the coal, the organic sulfur is actually reported to have increased. This may be due to an actual increase in the organic sulfur through a side reaction of the pyrite, or it may be caused by inaccuracy of the ASTM method when large proportions of chloro substituents are present. The amount of chlorine added to the coal (from 0 to 3.18%) is quite large and counterproductive. Most importantly, the amount of non-combustible ash has increased from 15.48 to 51.21%, most likely in the form of copper. This will dramatically decrease both the efficiency of combustion in terms of altering the heat capacity of the coal as well as decrease the amount of energy produced per ton of coal. As a result, it is quite evident that this method of desulfurization needs some modification prior to further exploitation.

Olesik, S. (comp.)

1990-01-01T23:59:59.000Z

404

Removal of nitrogen and sulfur from oil-shale  

SciTech Connect (OSTI)

This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

Olmstead, W.N.

1986-01-28T23:59:59.000Z

405

It's Elemental - Isotopes of the Element Magnesium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sodium Sodium Previous Element (Sodium) The Periodic Table of Elements Next Element (Aluminum) Aluminum Isotopes of the Element Magnesium [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 24 78.99% STABLE 25 10.00% STABLE 26 11.01% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 19 4.0 picoseconds Double Proton Emission 100.00% 20 90.8 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission ~ 27.00% 21 122 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 32.60% Electron Capture with delayed Alpha Decay < 0.50%

406

It's Elemental - Isotopes of the Element Potassium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Argon Argon Previous Element (Argon) The Periodic Table of Elements Next Element (Calcium) Calcium Isotopes of the Element Potassium [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 39 93.2581% STABLE 40 0.0117% 1.248×10+9 years 41 6.7302% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 32 No Data Available Proton Emission (suspected) No Data Available 33 < 25 nanoseconds Proton Emission No Data Available 34 < 25 nanoseconds Proton Emission No Data Available 35 178 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 0.37% 36 342 milliseconds Electron Capture 100.00%

407

It's Elemental - Isotopes of the Element Francium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Radon Radon Previous Element (Radon) The Periodic Table of Elements Next Element (Radium) Radium Isotopes of the Element Francium [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Francium has no naturally occurring isotopes. Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 199 12 milliseconds Alpha Decay > 0.00% Electron Capture No Data Available 200 49 milliseconds Alpha Decay 100.00% 201 62 milliseconds Alpha Decay 100.00% 201m 19 milliseconds Alpha Decay 100.00% 202 0.30 seconds Alpha Decay 100.00% 202m 0.29 seconds Alpha Decay 100.00% 203 0.55 seconds Alpha Decay <= 100.00% 204 1.8 seconds Alpha Decay 92.00%

408

It's Elemental - Isotopes of the Element Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen Nitrogen Previous Element (Nitrogen) The Periodic Table of Elements Next Element (Fluorine) Fluorine Isotopes of the Element Oxygen [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 16 99.757% STABLE 17 0.038% STABLE 18 0.205% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 12 1.139×10-21 seconds Proton Emission No Data Available 13 8.58 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 100.00% 14 70.620 seconds Electron Capture 100.00% 15 122.24 seconds Electron Capture 100.00% 16 STABLE - - 17 STABLE - - 18 STABLE - - 19 26.88 seconds Beta-minus Decay 100.00%

409

It's Elemental - Isotopes of the Element Gallium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Zinc Zinc Previous Element (Zinc) The Periodic Table of Elements Next Element (Germanium) Germanium Isotopes of the Element Gallium [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 69 60.108% STABLE 71 39.892% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 56 No Data Available Proton Emission (suspected) No Data Available 57 No Data Available Proton Emission (suspected) No Data Available 58 No Data Available Proton Emission (suspected) No Data Available 59 No Data Available Proton Emission (suspected) No Data Available 60 70 milliseconds Electron Capture 98.40%

410

It's Elemental - Isotopes of the Element Sodium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Neon Neon Previous Element (Neon) The Periodic Table of Elements Next Element (Magnesium) Magnesium Isotopes of the Element Sodium [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 23 100% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 18 1.3×10-21 seconds Proton Emission 100.00% 19 < 40 nanoseconds Proton Emission No Data Available 20 447.9 milliseconds Electron Capture with delayed Alpha Decay 20.05% Electron Capture 100.00% 21 22.49 seconds Electron Capture 100.00% 22 2.6027 years Electron Capture 100.00% 23 STABLE - - 24 14.997 hours Beta-minus Decay 100.00%

411

It's Elemental - Isotopes of the Element Neon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fluorine Fluorine Previous Element (Fluorine) The Periodic Table of Elements Next Element (Sodium) Sodium Isotopes of the Element Neon [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 20 90.48% STABLE 21 0.27% STABLE 22 9.25% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 16 9×10-21 seconds Double Proton Emission 100.00% 17 109.2 milliseconds Electron Capture with delayed Alpha Decay No Data Available Electron Capture 100.00% Electron Capture with delayed Proton Emission 100.00% 18 1.6670 seconds Electron Capture 100.00% 19 17.22 seconds Electron Capture 100.00% 20 STABLE - -

412

It's Elemental - Isotopes of the Element Copper  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nickel Nickel Previous Element (Nickel) The Periodic Table of Elements Next Element (Zinc) Zinc Isotopes of the Element Copper [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 63 69.15% STABLE 65 30.85% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 52 No Data Available Proton Emission No Data Available 53 < 300 nanoseconds Electron Capture No Data Available Proton Emission No Data Available 54 < 75 nanoseconds Proton Emission No Data Available 55 27 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 15.0% 56 93 milliseconds Electron Capture 100.00%

413

It's Elemental - Isotopes of the Element Boron  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Beryllium Beryllium Previous Element (Beryllium) The Periodic Table of Elements Next Element (Carbon) Carbon Isotopes of the Element Boron [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 10 19.9% STABLE 11 80.1% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 6 No Data Available Double Proton Emission (suspected) No Data Available 7 3.255×10-22 seconds Proton Emission No Data Available Alpha Decay No Data Available 8 770 milliseconds Electron Capture 100.00% Electron Capture with delayed Alpha Decay 100.00% 9 8.439×10-19 seconds Proton Emission 100.00% Double Alpha Decay 100.00%

414

It's Elemental - Isotopes of the Element Tungsten  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tantalum Tantalum Previous Element (Tantalum) The Periodic Table of Elements Next Element (Rhenium) Rhenium Isotopes of the Element Tungsten [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 180 0.12% >= 6.6×10+17 years 182 26.50% STABLE 183 14.31% > 1.3×10+19 years 184 30.64% STABLE 186 28.43% > 2.3×10+19 years Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 157 275 milliseconds Electron Capture No Data Available 158 1.25 milliseconds Alpha Decay 100.00% 158m 0.143 milliseconds Isomeric Transition No Data Available Alpha Decay No Data Available 159 7.3 milliseconds Alpha Decay ~ 99.90%

415

It's Elemental - Isotopes of the Element Radon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Astatine Astatine Previous Element (Astatine) The Periodic Table of Elements Next Element (Francium) Francium Isotopes of the Element Radon [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Radon has no naturally occurring isotopes. Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 193 1.15 milliseconds Alpha Decay 100.00% 194 0.78 milliseconds Alpha Decay 100.00% 195 6 milliseconds Alpha Decay 100.00% 195m 5 milliseconds Alpha Decay 100.00% 196 4.4 milliseconds Alpha Decay 99.90% Electron Capture ~ 0.10% 197 53 milliseconds Alpha Decay 100.00% 197m 25 milliseconds Alpha Decay 100.00% 198 65 milliseconds Alpha Decay No Data Available

416

It's Elemental - Isotopes of the Element Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Boron Boron Previous Element (Boron) The Periodic Table of Elements Next Element (Nitrogen) Nitrogen Isotopes of the Element Carbon [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 12 98.93% STABLE 13 1.07% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 8 1.981×10-21 seconds Proton Emission 100.00% Alpha Decay No Data Available 9 126.5 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 61.60% Electron Capture with delayed Alpha Decay 38.40% 10 19.308 seconds Electron Capture 100.00% 11 20.334 minutes Electron Capture 100.00% 12 STABLE - -

417

It's Elemental - Isotopes of the Element Rhenium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tungsten Tungsten Previous Element (Tungsten) The Periodic Table of Elements Next Element (Osmium) Osmium Isotopes of the Element Rhenium [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 185 37.40% STABLE 187 62.60% 4.33×10+10 years Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 159 No Data Available No Data Available No Data Available 160 0.82 milliseconds Proton Emission 91.00% Alpha Decay 9.00% 161 0.44 milliseconds Proton Emission 100.00% Alpha Decay <= 1.40% 161m 14.7 milliseconds Alpha Decay 93.00% Proton Emission 7.00% 162 107 milliseconds Alpha Decay 94.00% Electron Capture 6.00%

418

RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION  

SciTech Connect (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

Hobbs, D.

2010-07-22T23:59:59.000Z

419

Ray tracing of Jovian kilometric radiation  

SciTech Connect (OSTI)

Results of computer ray tracing of Jovian kilometric from 56.2 kHz to 1 MHz in a model Jovian magnetosphere with an Io torus are presented. Ray tracing calculations indicate that the Io torus presents a propagation barrier to the radiation and that the Jovian kilometric radiation must be generated in the L-O mode from a source near Jupiter on field lines passing through the Io torus. One effect of the Io torus is to refract the rays away from the magnetic equator forming a shadow zone at radial distances beyond the torus. In general, at radial distances greater than 10 Jovian radii, as the wave frequency increases (>200 kHz) so does the magnetic latitude of the shadow zone. These and other features of the ray tracing calculations are in good qualitative agreement with the observations from the plasma wave receiver and planetary radio astronomy experiment on board both Voyager 1 and 2.

Green, J.L.; Gurnett, D.A.

1980-01-01T23:59:59.000Z

420

Synthesis and development of processes for the recovery of sulfur from acid gases. Part 1, Development of a high-temperature process for removal of H{sub 2}S from coal gas using limestone -- thermodynamic and kinetic considerations; Part 2, Development of a zero-emissions process for recovery of sulfur from acid gas streams  

SciTech Connect (OSTI)

Limestone can be used more effectively as a sorbent for H{sub 2}S in high-temperature gas-cleaning applications if it is prevented from undergoing calcination. Sorption of H{sub 2}S by limestone is impeded by sintering of the product CaS layer. Sintering of CaS is catalyzed by CO{sub 2}, but is not affected by N{sub 2} or H{sub 2}. The kinetics of CaS sintering was determined for the temperature range 750--900{degrees}C. When hydrogen sulfide is heated above 600{degrees}C in the presence of carbon dioxide elemental sulfur is formed. The rate-limiting step of elemental sulfur formation is thermal decomposition of H{sub 2}S. Part of the hydrogen thereby produced reacts with CO{sub 2}, forming CO via the water-gas-shift reaction. The equilibrium of H{sub 2}S decomposition is therefore shifted to favor the formation of elemental sulfur. The main byproduct is COS, formed by a reaction between CO{sub 2} and H{sub 2}S that is analogous to the water-gas-shift reaction. Smaller amounts of SO{sub 2} and CS{sub 2} also form. Molybdenum disulfide is a strong catalyst for H{sub 2}S decomposition in the presence of CO{sub 2}. A process for recovery of sulfur from H{sub 2}S using this chemistry is as follows: Hydrogen sulfide is heated in a high-temperature reactor in the presence of CO{sub 2} and a suitable catalyst. The primary products of the overall reaction are S{sub 2}, CO, H{sub 2} and H{sub 2}O. Rapid quenching of the reaction mixture to roughly 600{degrees}C prevents loss Of S{sub 2} during cooling. Carbonyl sulfide is removed from the product gas by hydrolysis back to CO{sub 2} and H{sub 2}S. Unreacted CO{sub 2} and H{sub 2}S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H{sub 2} and CO, which recovers the hydrogen value from the H{sub 2}S. This process is economically favorable compared to the existing sulfur-recovery technology and allows emissions of sulfur-containing gases to be controlled to very low levels.

Towler, G.P.; Lynn, S.

1993-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL  

SciTech Connect (OSTI)

This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

Gary M. Blythe

2001-11-06T23:59:59.000Z

422

ENERGY EFFICIENCY LIMITS FOR A RECUPERATIVE BAYONET SULFURIC ACID DECOMPOSITION REACTOR FOR SULFUR CYCLE THERMOCHEMICAL HYDROGEN PRODUCTION  

SciTech Connect (OSTI)

A recuperative bayonet reactor design for the high-temperature sulfuric acid decomposition step in sulfur-based thermochemical hydrogen cycles was evaluated using pinch analysis in conjunction with statistical methods. The objective was to establish the minimum energy requirement. Taking hydrogen production via alkaline electrolysis with nuclear power as the benchmark, the acid decomposition step can consume no more than 450 kJ/mol SO{sub 2} for sulfur cycles to be competitive. The lowest value of the minimum heating target, 320.9 kJ/mol SO{sub 2}, was found at the highest pressure (90 bar) and peak process temperature (900 C) considered, and at a feed concentration of 42.5 mol% H{sub 2}SO{sub 4}. This should be low enough for a practical water-splitting process, even including the additional energy required to concentrate the acid feed. Lower temperatures consistently gave higher minimum heating targets. The lowest peak process temperature that could meet the 450-kJ/mol SO{sub 2} benchmark was 750 C. If the decomposition reactor were to be heated indirectly by an advanced gas-cooled reactor heat source (50 C temperature difference between primary and secondary coolants, 25 C minimum temperature difference between the secondary coolant and the process), then sulfur cycles using this concept could be competitive with alkaline electrolysis provided the primary heat source temperature is at least 825 C. The bayonet design will not be practical if the (primary heat source) reactor outlet temperature is below 825 C.

Gorensek, M.; Edwards, T.

2009-06-11T23:59:59.000Z

423

Building Energy Software Tools Directory: TRACE 700  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

700 700 TRACE 700 logo. Trane's TRACE 700 software - the latest version of Trane Air Conditioning Economics - brings the algorithms recommended by the American Society of Heating, Refrigerating, and Air-Conditioning Engineers (ASHRAE) to the familiar Windows operating environment. Use it to assess the energy and economic impacts of building-related selections such as architectural features, comfort-system design, HVAC equipment selections, operating schedules, and financial options. Flexible data entry, coupled with multiple views and "drag-and-drop" load assignments, simplify the modeling process and help you identify optimal zoning and plant configurations. Compare up to four alternatives for a single project by modeling various air distribution and mechanical

424

Trace fossil assemblages in selected shelf sandstones  

E-Print Network [OSTI]

with progradation of the delta. The presence of trace fossils throughout the section, as compared to the lack of burrows in the upper unit of the True Watt A-1 section, can be attributed to the marginal location of the deposits. Santa Fe 13 and Santa Fe 10... with progradation of the delta. The presence of trace fossils throughout the section, as compared to the lack of burrows in the upper unit of the True Watt A-1 section, can be attributed to the marginal location of the deposits. Santa Fe 13 and Santa Fe 10...

Locke, Kathleen Ann

2012-06-07T23:59:59.000Z

425

Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solvent Tuning of Properties of Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in nature and catalyze one-electron transfer processes. These proteins have evolved into two classes that have large differences in their electrochemical potentials: high potential iron-sulfur proteins (HiPIPs) and bacterial ferredoxins (Fds). The role of the surrounding protein environment in tuning the redox potential of these iron sulfur clusters has been a persistent puzzle in biological electron transfer [1]. Although HiPIPs and Fds have the same iron sulfur structural motif - a cubane-type structure - (Figure 1), there are large differences in their electrochemical

426

SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage General Atomics logo Graphic of a diagram of squares and circles connected by arrows. Sulfur-based TES can compensate for diurnal and seasonal insolation fluctuations. General Atomics, under the Baseload CSP FOA, is demonstrating the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power generation. Approach There are three main project objectives under this award: Study the sulfur generating disproportionation reaction and develop it into a practical engineering process step. Carry out preliminary process components design and experimental validation. The engineering data will be used for process integration between the CSP plant, the sulfur processing and storage plant, and the electricity generation unit.

427

Reversion and dehydration reactions of glucose during the dilute sulfuric acid hydrolysis of cellulose  

SciTech Connect (OSTI)

The inaccessibility of all glycosidic bonds necessitates industrial conversion schemes which employ a dilute acid catalyst at high temperatures. Process conditions also promote further reactions of glucose via the reversion and dehydration pathways. Quantitative determination of the yields of the major reversion and dehydration products is important for understanding and predicting the amounts of these materials expected under envisioned industrial operating conditions. Microcrystalline cellulose (Avicel) was hydrolyzed with sulfuric acid (0.0-1.25 wt.%), at high temperatures (160-250/sup 0/C), and at a 3:1 liquid-to-solid ratio. The hydrolysis was monitored by evaluating the amount of cellulose remaining and the yields of glucose, solid humin, levulinic acid, formic acid, hydroxymethylfurfural (HMF), and reversion products as a function of the aforementioned reaction conditions. Analysis of the reversion products required the development of a technique for the quantitation of trace carbohydrates in complex mixtures and led to the development of a reduction/permethylation gas chromatographic procedure. Cellulose hydrolysis followed pseudo-homogeneous first-order kinetics. Glucose yield was adequately described as consecutive first-order reactions. Anhydrosugars formed via reversion followed equilibrium reaction kinetics whereas the disaccharides did not. Total reversion product yields approached 10% at 250/sup 0/C. Quantitative determination of the major dehydration products provided important information concerning the destruction of glucose. HMF was produced in up to 12% yields based on the theoretical amount of glucose available, and furfural was detected in up to 5% yields. A carbon mass balance based on the determined product yields revealed that approximately 90% of all carbon was accounted for at maximum glucose yields.

Helm, R.F.

1987-01-01T23:59:59.000Z

428

Tracing compressed curves in triangulated surfaces  

Science Journals Connector (OSTI)

A simple path or cycle in a triangulated surface is normal if it intersects any triangle in a finite set of arcs, each crossing from one edge of the triangle to another. We describe an algorithm to "trace" a normal curve in O(min set{X, n2log ... Keywords: computational topology, geodesics, normal coordinates

Jeff Erickson; Amir Nayyeri

2012-06-01T23:59:59.000Z

429

doi:10.1016/j.gca.2005.02.002 Sulfur diffusion in basaltic melts  

E-Print Network [OSTI]

doi:10.1016/j.gca.2005.02.002 Sulfur diffusion in basaltic melts CARMELA FREDA,1, * DON R. BAKER,1,2 February 3, 2005) Abstract--We measured the diffusion coefficients of sulfur in two different basaltic for sulfur diffusion in anhydrous basalts: D 2.19 10 4 exp 226.3 58.3 RT where D is the diffusion coefficient

Long, Bernard

430

Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite...  

Broader source: Energy.gov (indexed) [DOE]

October 04, 2011 Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System DEER CONFERENCE 2011 Outline Introduction Zeolite-based SCR behavior -...

431

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

200 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

432

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

200 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

433

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

Energy Information Administration Petroleum Marketing Annual 1995 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

434

E-Print Network 3.0 - ashless low-sulfur fuel Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Blendstocks for Low Sulfur Diesel Fuel in PADD III . . . . . . . . . . . . . . . . 17... markets for low ... Source: Oak Ridge National Laboratory, Center for Transportation...

435

E-Print Network 3.0 - aromatic sulfur heterocycles Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale Summary: . Polycyclic aromatic sulfur heterocycles IV. Determination of polycyclic...

436

Portable instrument and method for detecting reduced sulfur compounds in a gas  

DOE Patents [OSTI]

A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

1983-06-01T23:59:59.000Z

437

Sulfur behavior in the Sasol-Lurgi fixed-bed dry-bottom gasification process  

SciTech Connect (OSTI)

This article reports on the findings of a study regarding the sulfur behavior across a Sasol-Lurgi gasifier. This was undertaken to understand the behavior of the various sulfur-bearing components in the coal, as they are exposed to the conditions in the gasifier. In this study, conventional characterization techniques were employed to monitor the behavior of sulfur-bearing mineral matter across the gasifier. It was observed from the study that the sulfur-bearing mineral (pyrite) in the coal structure undergoes various changes with pyrite being transformed to pyrrhotite and then to various oxides of iron with the subsequent loss of sulfur to form H{sub 2}S. A low proportion of the sulfur species including the organically associated sulfur was encapsulated by a melt that was formed by the interaction between kaolinite and fluxing minerals (pyrite, calcite, and dolomite/ankerite) present in the coal at elevated temperatures and pressure, thereby ending up in the ash. The remaining small proportions of sulfur-bearing mineral matter including pyrite and organically bound sulfur in the unburned carbon in the carbonaceous shales also report to the ash. 18 refs., 8 figs., 2 tabs.

M. Pat Skhonde; R. Henry Matjie; J. Reginald Bunt; A. Christien Strydom; H. Schobert [Sasol Technology R& amp; D, Sasolburg (South Africa)

2009-01-15T23:59:59.000Z

438

Status of Heavy Vehicle Diesel Emission Control Sulfur Effects (DECSE) Test Program  

SciTech Connect (OSTI)

DECSE test program is well under way to providing data on effects of sulfur levels in diesel fuel on performance of emission control technologies.

George Sverdrup

1999-06-07T23:59:59.000Z

439

Sulfur-tolerant natural gas reforming for fuel-cell applications.  

E-Print Network [OSTI]

??An attractive simplification of PEM-FC systems operated with natural gas would be the use of a sulfur tolerant reforming catalyst, but such a catalyst has (more)

Hennings, Ulrich

2010-01-01T23:59:59.000Z

440

E-Print Network 3.0 - absorbing sulfur dioxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

Note: This page contains sample records for the topic "trace elements sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

E-Print Network 3.0 - ambient sulfur dioxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

442

E-Print Network 3.0 - africa sulfur isotope Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: africa sulfur isotope Page: << < 1 2 3 4 5 > >> 1 Geobiology (2006), 4, 191201 2006 The...

443

Sulfur barrier for use with in situ processes for treating formations  

DOE Patents [OSTI]

Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. Sulfur may be introduced into one or more wellbores located inside a perimeter of a treatment area in the formation having a permeability of at least 0.1 darcy. At least some of the sulfur is allowed to move towards portions of the formation cooler than the melting point of sulfur to solidify the sulfur in the formation to form the barrier.

Vinegar, Harold J. (Bellaire, TX); Christensen, Del Scot (Friendswood, TX)

2009-12-15T23:59:59.000Z

444

SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NOX control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

Gary M. Blythe; Richard McMillan

2002-03-04T23:59:59.000Z

445

SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm the effectiveness of the sorbents tested over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP, Unit 3, and the second test was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant testing provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. This report presents the results from those long-term tests. The tests determined the effectiveness of injecting commercially available magnesium hydroxide slurry (Gavin Plant) and byproduct magnesium hydroxide slurry (both Gavin Plant and BMP) for sulfuric acid control. The results show that injecting either slurry could achieve up to 70 to 75% overall sulfuric acid removal. At BMP, this overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NOX control than at removing SO{sub 3} formed in the furnace. The long-term tests also determined balance-of-plant impacts from slurry injection during the two tests. These include impacts on boiler back-end temperatures and pressure drops, SCR catalyst properties, ESP performance, removal of other flue gas species, and flue gas opacity. For the most part the balance-of-plant impacts were neutral to positive, although adverse effects on ESP performance became an issue during the BMP test.

Gary M. Blythe; Richard McMillan

2002-07-03T23:59:59.000Z

446

SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NO{sub x} control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two First Energy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

Gary M. Blythe; Richard McMillan

2002-02-04T23:59:59.000Z

447

Central Appalachia: Production potential of low-sulfur coal  

SciTech Connect (OSTI)

The vast preponderance of eastern US low sulfur and 1.2-lbs SO{sub 2}/MMBtu compliance coal comes from a relatively small area composed of 14 counties located in eastern Kentucky, southern West Virginia and western Virginia. These 14 counties accounted for 68% of all Central Appalachian coal production in 1989 as well as 85% of all compliance coal shipped to electric utilities from this region. A property-by-property analysis of total production potential in 10 of the 14 counties (Floyd, Knott, Letcher, Harlan, Martin and Pike in Kentucky and Boone, Kanawha, Logan and Mingo in West Virginia) resulted in the following estimates of active and yet to be developed properties: (1) total salable reserves for all sulfur levels were 5.9 billion tons and (2) 1.2-lbs. SO{sub 2}/MMBtu compliance'' reserves totaled 2.38 billion tons. This potential supply of compliance coal is adequate to meet the expanded utility demand expected under acid rain for the next 20 years. Beyond 2010, compliance supplies will begin to reach depletion levels in some areas of the study region. A review of the cost structure for all active mines was used to categorize the cost structure for developing potential supplies. FOB cash costs for all active mines in the ten counties ranged from $15 per ton to $35 per ton and the median mine cost was about $22 per ton. A total of 47 companies with the ability to produce and ship coal from owned or leased reserves are active in the ten-county region. Identified development and expansion projects controlled by active companies are capable of expanding the region's current production level by over 30 million tons per year over the next twenty years. Beyond this period the issue of reserve depletion for coal of all sulfur levels in the ten county region will become a pressing issue. 11 figs., 12 tabs.

Watkins, J. (Hill and Associates, Inc., Annapolis, MD (United States))

1991-09-01T23:59:59.000Z

448

Sulfur polymer cement for macroencapsulation of mixed waste debris  

SciTech Connect (OSTI)

In FY 1997, the US DOE Mixed Waste Focus Area (MWFA) sponsored a demonstration of the macroencapsulation of mixed waste debris using sulfur polymer cement (SPC). Two mixed wastes were tested--a D006 waste comprised of sheets of cadmium and a D008/D009 waste comprised of lead pipes and joints contaminated with mercury. The demonstration was successful in rendering these wastes compliant with Land Disposal Restrictions (LDR), thereby eliminating one Mixed Waste Inventory Report (MWIR) waste stream from the national inventory.

Mattus, C.H.

1998-06-01T23:59:59.000Z

449

Removal of sulfur and nitrogen containing pollutants from discharge gases  

DOE Patents [OSTI]

Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

Joubert, James I. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

450

T-720: Blue Coat Director HTTP Trace Processing Flaw Permits...  

Broader source: Energy.gov (indexed) [DOE]

0: Blue Coat Director HTTP Trace Processing Flaw Permits Cross-Site Scripting Attacks T-720: Blue Coat Director HTTP Trace Processing Flaw Permits Cross-Site Scripting Attacks...

451

It's Elemental - Isotopes of the Element Nitrogen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Carbon Previous Element (Carbon) The Periodic Table of Elements Next Element (Oxygen) Oxygen Isotopes of the Element Nitrogen [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 14 99.636% STABLE 15 0.364% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 10 No Data Available Proton Emission 100.00% 11 5.49×10-22 seconds Proton Emission 100.00% 12 11.000 milliseconds Electron Capture 100.00% 13 9.965 minutes Electron Capture 100.00% 14 STABLE - - 15 STABLE - - 16 7.13 seconds Beta-minus Decay 100.00% Beta-minus Decay with delayed Alpha Decay 1.2×10-3 % 17 4.173 seconds Beta-minus Decay 100.00%

452

Corrosion rate and anodic dissolution behavior of a B2-iron aluminide alloy in sulfuric acid  

SciTech Connect (OSTI)

An electrochemical investigation was conducted to evaluate the corrosion behavior of an iron aluminide (B2-FeAl) alloy (with 24 wt% Al) in sulfuric acid (H{sub 2}SO{sub 3}) under potentiodynamic polarization conditions. Corrosion rates were determined using the polarization resistance (R{sub p}) technique, in which simultaneous computations of the Tafel slopes were obtained by a curve-fitting procedure. The corrosion rate of B2-FeAl was comparable to high-purity iron at the beginning of immersion but increased noticeably with time, showing significantly diminished corrosion resistance after several hours of immersion. At small anodic overpotentials, the polarization curve showed an active dissolution region, with the anodic current dependent upon potential and pH, which suggested an anodic process under iron dissolution control. Active corrosion of B2-FeAl was believed to follow an initial selective dissolution of the aluminum constituent. The rate-determining step of the process was the charge-transfer reaction of iron, similar to that for iron-chromium alloys. However, a significant difference between aluminum and chromium existed in the poorer performance of aluminum as an alloying element in inhibiting active dissolution of iron-based alloys.

Frangini, S. [ENEA Centro Ricerche Energie, Rome (Italy). Div. Nuovi Materiali

1999-01-01T23:59:59.000Z

453

Automation of organic elemental analysis  

Science Journals Connector (OSTI)

Automation of organic elemental analysis ... Describes the development and design of an apparatus for automated organic elemental analysis. ...

Velmer B. Fish

1969-01-01T23:59:59.000Z

454

Procedure for Cleaning Bottles for Trace Metal Analysis Initial cleaning  

E-Print Network [OSTI]

Procedure for Cleaning Bottles for Trace Metal Analysis Initial cleaning: Supplies LDPE 60ml bottles (nalgene) ACS grade Hydrochloric acid Trace metal grade nitric acid Day 1 1. Submerge 60ml bottles for up to three uses) 2. Rinse 3x in milli-q (DI) water 3. Fill bottles with 2% trace metal grade nitric

Paytan, Adina

455

ULTRA-LOW SULFUR REDUCTION EMISSION CONTROL DEVICE/DEVELOPMENT OF AN ON-BOARD FUEL SULFUR TRAP  

SciTech Connect (OSTI)

Honeywell is actively working on a 3-year program to develop and demonstrate proof-of-concept for an ''on-vehicle'' desulfurization fuel filter for heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NO{sub x} adsorbers. The NO{sub x} adsorber may be required to meet the proposed new EPA Tier II and ''2007-Rule'' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters will also be examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. It is anticipated that the technology developed for heavy-duty applications will be applicable to light-dut