National Library of Energy BETA

Sample records for toxic chemical release

  1. Toxic chemical considerations for tank farm releases

    SciTech Connect (OSTI)

    Van Keuren, J.C.; Davis, J.S., Westinghouse Hanford

    1996-08-01

    This topical report contains technical information used to determine the accident consequences of releases of toxic chemical and gases for the Tank Farm Final Safety Analysis report (FSAR).It does not provide results for specific accident scenarios but does provide information for use in those calculations including chemicals to be considered, chemical concentrations, chemical limits and a method of summing the fractional contributions of each chemical. Tank farm composites evaluated were liquids and solids for double shell tanks, single shell tanks, all solids,all liquids, headspace gases, and 241-C-106 solids. Emergency response planning guidelines (ERPGs) were used as the limits.Where ERPGs were not available for the chemicals of interest, surrogate ERPGs were developed. Revision 2 includes updated sample data, an executive summary, and some editorial revisions.

  2. Toxic Chemical Release Inventory reporting ``Qs & As``. Environmental Guidance

    SciTech Connect (OSTI)

    Not Available

    1994-03-01

    This document offers guidance on toxic chemical release inventory reporting, pursuant to Section 313 of the Emergency Planning and Community Right-to-Know Act (EPCRA) at DOE sites.

  3. 2008 Toxic Chemical Release Inventory 2008 Toxic Chemical Release Inventory Community Right-to-Know Act of 1986, Title III, Section 313

    SciTech Connect (OSTI)

    Ecology and Air Quality Group

    2009-10-01

    For reporting year 2008, Los Alamos National Laboratory (LANL) submitted a Form R report for lead as required under the Emergency Planning and Community Right-to- Know Act (EPCRA) Section 313. No other EPCRA Section 313 chemicals were used in 2008 above the reportable thresholds. This document was prepared to provide a description of the evaluation of EPCRA Section 313 chemical use and threshold determinations for LANL for calendar year 2008, as well as to provide background information about data included on the Form R reports. Section 313 of EPCRA specifically requires facilities to submit a Toxic Chemical Release Inventory Report (Form R) to the U.S. Environmental Protection Agency (EPA) and state agencies if the owners and operators manufacture, process, or otherwise use any of the listed toxic chemicals above listed threshold quantities. EPA compiles this data in the Toxic Release Inventory database. Form R reports for each chemical over threshold quantities must be submitted on or before July 1 each year and must cover activities that occurred at the facility during the previous year. In 1999, EPA promulgated a final rule on persistent bioaccumulative toxics (PBTs). This rule added several chemicals to the EPCRA Section 313 list of toxic chemicals and established lower reporting thresholds for these and other PBT chemicals that were already reportable. These lower thresholds became applicable in reporting year 2000. In 2001, EPA expanded the PBT rule to include a lower reporting threshold for lead and lead compounds. Facilities that manufacture, process, or otherwise use more than 100 lb of lead or lead compounds must submit a Form R.

  4. Green alternatives to toxic release inventory (TRI) chemicals in the process industry

    SciTech Connect (OSTI)

    Ahmed, I.; Baron, J.; Hamilton, C.

    1995-12-01

    Driven by TRI reporting requirements, the chemical process industry is searching for innovative ways to reduce pollution at the source. Distinct environmental advantages of biobased green chemicals (biochemicals) mean are attractive alternatives to petrochemicals. Biochemicals are made from renewable raw materials in biological processes, such as aerobic and anaerobic fermentation, that operate at ambient temperatures and pressures, and produce only nontoxic waste products. Key TRI chemicals and several classes of commodity and intermediate compounds, used on consumer end-products manufacturing, are examined and alternatives are suggested. Specific substitution options for chlorofluorocarbons, industrial solvents, and commodity organic and inorganic chemicals are reviewed. Currently encouraged pollution prevention alternatives in the manufacturing sector are briefly examined for their long-term feasibility such as bioalternatives to bleaching in the pulp & paper industry, solvent cleaning in the electronics and dry cleaning industries, and using petroleum-based feedstocks in the plastics industry. Total life cycle and cost/benefit analyses are employed to determine whether biochemicals are environmentally feasible and commercially viable as pollution prevention tools. Currently available green chemicals along with present and projected costs and premiums are also presented. Functional compatibility of biochemicals with petrochemicals and bioprocessing systems with conventional chemical processing methods are explored. This review demonstrates that biochemicals can be used cost effectively in certain industrial chemical operations due to their added environmental benefits.

  5. 1997 Toxic Chemical Release Inventory Report for the Emergency Planning and Community Right-to-Know Act of 1986, Title III, Section 313

    SciTech Connect (OSTI)

    Heather McBride

    1997-07-01

    The Emergency Planning and Community Right-to-Know Act of 1986 (EPCIL4), Title III, Section 313 [also known as the Superfund Amendment and Reauthorization Act (SARA)], as modified by Executive Order 12856, requires all federal facilities to submit an annual Toxic Chemical Release Inventory report every July for the preceding calendar year. Owners and operators of manufacturing, processing, or production facilities are required to report their toxic chemical releases to all environmental mediums (air, water, soil, etc.). At Los Alamos National Laboratory (LANL), nitric acid was the only toxic chemical used in 1997 that met the reportable threshold limit of 10,000 lb. Form R is the only documentation required by the Environmental Protection Agency, and it is included in the appendix of this report. This report, as requested by DOE, is provided for documentation purposes. In addition, a detailed description of the evaluation and reporting process for chemicals and processes at LANL has been included.

  6. 1998 Toxic Chemical Release Inventory Report for the Emergency Planning and Community Right-to-Know Act of 1986, Title III

    SciTech Connect (OSTI)

    Marjorie B. Stockton

    1999-11-01

    The Emergency Planning and Community Right-to-Know Act (EPCRA) of 1986 [also known as the Superfund Amendment and Reauthorization Act (SARA), Title III], as modified by Executive Order 12856, requires that all federal facilities evaluate the need to submit an annual Toxic Chemical Release Inventory report as prescribed in Title III, Section 313 of this Act. This annual report is due every July for the preceding calendar year. Owners and operators who manufacture, process, or otherwise use certain toxic chemicals above listed threshold quantities are required to report their toxic chemical releases to all environmental mediums (air, water, soil, etc.). At Los Alamos National Laboratory (LANL), no EPCRA Section 313 chemicals were used in 1998 above the reportable threshold limits of 10,000 lb or 25,000 lb. Therefore LANL was not required to submit any Toxic Chemical Release Inventory reports (Form Rs) for 1998. This document was prepared to provide a detailed description of the evaluation on chemical usage and EPCRA Section 313 threshold determinations for LANL for 1998.

  7. 2002 Toxic Chemical Release Inventory Report for the Emergency Planning and Community Right-to-Know Act of 1986, Title III, Section 313

    SciTech Connect (OSTI)

    M. Stockton

    2003-11-01

    For reporting year 2002, Los Alamos National Laboratory (LANL or the Laboratory) submitted Form R reports for lead compounds and mercury as required under the Emergency Planning and Community Right-to-Know Act (EPCRA), Section 313. No other EPCRA Section 313 chemicals were used in 2002 above the reportable thresholds. This document was prepared to provide a description of the evaluation of EPCRA Section 313 chemical usage and threshold determinations for LANL for calendar year 2002 as well as provide background information about the data included on the Form R reports. Section 313 of EPCRA specifically requires facilities to submit a Toxic Chemical Release Inventory report (Form R) to the U.S. Environmental Protection Agency (EPA) and state agencies if the owners and operators manufacture, process, or otherwise use any of the listed toxic chemicals above listed threshold quantities. EPA compiles this data in the Toxic Release Inventory database. Form R reports for each chemical over threshold quantities must be submitted on or before July 1 each year and must cover activities that occurred at the facility during the previous year. In 1999 EPA promulgated a final rule on Persistent Bioaccumulative Toxics (PBTs). This rule added several chemicals to the EPCRA Section 313 list of toxic chemicals and established lower reporting thresholds for these and other PBT chemicals that were already reportable under EPCRA Section 313. These lower thresholds became applicable in reporting year 2000. In 2001, EPA expanded the PBT rule to include a lower reporting threshold for lead and lead compounds. Facilities that manufacture, process, or otherwise use more than 100 lb of lead or lead compounds must submit a Form R.

  8. 2006 Toxic Chemical Release Inventory Report for the Emergency Planning and Community Right-to-Know Act of 1986, Title III, Section 313

    SciTech Connect (OSTI)

    Ecology and Air Quality Group

    2007-12-12

    For reporting year 2006, Los Alamos National Laboratory (LANL or the Laboratory) submitted Form R reports for lead as required under the Emergency Planning and Community Right-to-Know Act (EPCRA) Section 313. No other EPCRA Section 313 chemicals were used in 2006 above the reportable thresholds. This document was prepared to provide a description of the evaluation of EPCRA Section 313 chemical use and threshold determinations for LANL for calendar year 2006, as well as to provide background information about data included on the Form R reports. Section 313 of EPCRA specifically requires facilities to submit a Toxic Chemical Release Inventory Report (Form R) to the U.S. Environmental Protection Agency (EPA) and state agencies if the owners and operators manufacture, process, or otherwise use any of the listed toxic chemicals above listed threshold quantities. EPA compiles this data in the Toxic Release Inventory database. Form R reports for each chemical over threshold quantities must be submitted on or before July 1 each year and must cover activities that occurred at the facility during the previous year. In 1999, EPA promulgated a final rule on persistent bioaccumulative toxics (PBTs). This rule added several chemicals to the EPCRA Section 313 list of toxic chemicals and established lower reporting thresholds for these and other PBT chemicals that were already reportable. These lower thresholds became applicable in reporting year 2000. In 2001, EPA expanded the PBT rule to include a lower reporting threshold for lead and lead compounds. Facilities that manufacture, process, or otherwise use more than 100 lb of lead or lead compounds must submit a Form R.

  9. 2004 Toxic Chemical Release Inventory Report for the Emergency Planning and Community Right-to-Know Act of 1986, Title III, Section 313

    SciTech Connect (OSTI)

    M. Stockton

    2006-01-15

    Section 313 of Emergency Planning and Community Right-to-Know Act (EPCRA) specifically requires facilities to submit a Toxic Chemical Release Inventory Report (Form R) to the U.S. Environmental Protection Agency (EPA) and state agencies if the owners and operators manufacture, process, or otherwise use any of the listed toxic chemicals above listed threshold quantities. EPA compiles this data in the Toxic Release Inventory database. Form R reports for each chemical over threshold quantities must be submitted on or before July 1 each year and must cover activities that occurred at the facility during the previous year. For reporting year 2004, Los Alamos National Laboratory (LANL or the Laboratory) submitted Form R reports for lead compounds, nitric acid, and nitrate compounds as required under the EPCRA Section 313. No other EPCRA Section 313 chemicals were used in 2004 above the reportable thresholds. This document provides a description of the evaluation of EPCRA Section 313 chemical use and threshold determinations for LANL for calendar year 2004, as well as background information about data included on the Form R reports.

  10. Toxic release inventory, (TRI), 1991. Data file

    SciTech Connect (OSTI)

    1991-12-31

    Section 313 of the Emergency Planning and Community Right-to-Know Act (also known as Title III) of the Superfund Amendments and Reauthorization Act of 1986 (Public Law 99-499) requires EPA to establish a national inventory of toxic chemical emissions from certain facilities. The final Toxic Chemical Release Form R and regulations for the 1987 reporting year were published in the Federal Register on February 16, 1988 (53 FR 4500-4554). The reporting requirement applies to owners and operators of facilities that have 10 or more full-time employees, that are in Standard Industrial Classification (SIC) codes 20 through 39 (i.e., manufacturing facilities) and that manufacture (including importing), process or otherwise use a listed toxic chemical in excess of specified threshold quantities. The law mandates that the data be made publicly available through a computer database. The online TRI file should appeal to a broad-based user audience including industry, state and local environmental agencies, emergency planning committees, the Federal Government and other regulatory groups.

  11. U.S./Mexico Border environmental study toxics release inventory data, 1988--1992

    SciTech Connect (OSTI)

    O`Brien, R.F.; LoPresti, C.A.

    1996-02-01

    This is a report on industrial toxic chemical releases and transfers based on information reported to the Toxics Release Inventory (TRI), a database maintained by the USEPA. This document discusses patterns of toxic chemical releases to the atmosphere, to water, to the land, and to underground injection; and transfers of toxic chemicals to Publicly Owned Treatment Works (POTW), and for disposal, treatment and other off-site transfers during the TRI reporting years 1988--1992. Geographic coverage is limited to the US side of the ``Border Area``, the geographic area situated within 100 km of the US/Mexico international boundary. A primary purpose of this study is to provide background information that can be used in the future development of potential ``indicator variables`` for tracking environmental and public health status in the Border Area in conjunction with the implementation of the North American Free Trade Agreement (NAFTA).

  12. Revised Emergency Planning and Community Right-to-Know Act (EPCRA), Section 313, Toxic Chemical Release reporting for calendar year 1998

    SciTech Connect (OSTI)

    Evans, R.A.

    2000-01-01

    This report contains forms which contain information on the physical location of the Y-12 Plant and the amount of lead that was released to the East Fork Poplar Creek and amounts transferred to landfills on-site as well as landfills in Texas and South Carolina. Amounts are given in pounds per year.

  13. 2009 Toxic Chemical Release Inventory Report for the Emergency Planning and Community Right-to-Know Act of 1986, Title III, Section 313

    SciTech Connect (OSTI)

    Environmental Stewardship Group

    2010-11-01

    For reporting year 2009, Los Alamos National Laboratory (LANL) submitted a Form R report for lead as required under the Emergency Planning and Community Right-to- Know Act (EPCRA) Section 313. No other EPCRA Section 313 chemicals were used in 2009 above the reportable thresholds. This document was prepared to provide a description of the evaluation of EPCRA Section 313 chemical use and threshold determinations for LANL for calendar year 2009, as well as to provide background information about data included on the Form R reports.

  14. DOE contractor's meeting on chemical toxicity

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    The Office of Health and Environmental Research (OHER) is required to determine the potential health and environmental effects associated with energy production and use. To ensure appropriate communication among investigators and scientific disciplines that these research studies represent, OHER has sponsored workshops. This document provides a compilation of activities at the Third Annual DOE/OHER Workshop. This year's workshop was broadened to include all OHER activities identified as within the chemical effects area. The workshop consisted of eight sessions entitled Isolation and Detection of Toxic chemicals; Adduct Formation and Repair; Chemical Toxicity (Posters); Metabolism and Genotoxicity; Inhalation Toxicology; Gene Regulation; Metals Toxicity; and Biological Mechanisms. This document contains abstracts of the information presented by session.

  15. Probabilistic consequence model of accidenal or intentional chemical releases.

    SciTech Connect (OSTI)

    Chang, Y.-S.; Samsa, M. E.; Folga, S. M.; Hartmann, H. M.

    2008-06-02

    In this work, general methodologies for evaluating the impacts of large-scale toxic chemical releases are proposed. The potential numbers of injuries and fatalities, the numbers of hospital beds, and the geographical areas rendered unusable during and some time after the occurrence and passage of a toxic plume are estimated on a probabilistic basis. To arrive at these estimates, historical accidental release data, maximum stored volumes, and meteorological data were used as inputs into the SLAB accidental chemical release model. Toxic gas footprints from the model were overlaid onto detailed population and hospital distribution data for a given region to estimate potential impacts. Output results are in the form of a generic statistical distribution of injuries and fatalities associated with specific toxic chemicals and regions of the United States. In addition, indoor hazards were estimated, so the model can provide contingency plans for either shelter-in-place or evacuation when an accident occurs. The stochastic distributions of injuries and fatalities are being used in a U.S. Department of Homeland Security-sponsored decision support system as source terms for a Monte Carlo simulation that evaluates potential measures for mitigating terrorist threats. This information can also be used to support the formulation of evacuation plans and to estimate damage and cleanup costs.

  16. RCRA Subtitle C TSD facilities and solvent recovery facilities: Section 313 of the Emergency Planning and Community Right-to-Know Act. Toxic chemical release inventory; Industry guidance

    SciTech Connect (OSTI)

    1999-01-01

    The purpose of this guidance document is to assist facilities in SIC code 4953 that are regulated under the Resource Conservation and Recovery Act (RCRA), Subtitle C and facilities in SIC code 7389 that are primarily engaged in solvent recovery services on a contract or fee basis. This document explains the EPCRA Section 313 and PPA Section 6607 reporting requirements (collectively referred to as the EPCRA Section 313) reporting requirements, and discusses specific release and other waste management activities encountered at many facilities in these industries. The objectives of this manual are to: clarify EPCRA Section 313 requirements for industry; increase the accuracy and completeness of the data being reported by RCRA Subtitle C TSD and solvent recovery facilities; and reduce the level of effort expended by those facilities that prepare an EPCRA Section 313 report.

  17. Expansion of ARAC for chemical releases

    SciTech Connect (OSTI)

    Baskett, R.L.; Blair, M.D.; Foster, C.S.; Taylor, A.G.

    1997-07-01

    In 1996 the Atmospheric Release Advisory Capability (ARAC) at Lawrence Livermore National Laboratory (LLNL) completed an effort to expand its national emergency response modeling system for chemical releases. Key components of the new capability include the integration of (1) an extensive chemical property database, (2) source modeling for tanks and evaporating pools, (3) denser-than-air dispersion, (4) public exposure guidelines, and (5) an interactive graphical user interface (GUI). Recent use and the future of the new capability are also discussed.

  18. A New Understanding of Chemical Agent Release

    SciTech Connect (OSTI)

    Nakafuji, G; Greenman, R; Theofanous, T

    2002-07-24

    The evolution of thickened chemical agent released at supersonic velocities, due to a missile defense intercept or a properly functioning warhead, has been misunderstood. Current and historical experimental and modeling efforts have attributed agent breakup to a variety of droplet breakup mechanisms. According to this model, drops of agent fragment into subsequent generations of smaller drops until a stable drop size is reached. Recent experimental data conducted in a supersonic wind tunnel show that agent breakup is not driven by any droplet breakup mechanism. The breakup of agent is instead governed by viscoelastic behavior and aerodynamic history effects. This viscoelastic breakup mechanism results in the formation of threads and sheets of liquid, instead of drops. The evolution and final state of agent released has broad implications not only for aerobreakup models, but also for all atmospheric dispersion models.

  19. Analysis of 1994 Air Force toxic release inventory reporting. Master`s thesis

    SciTech Connect (OSTI)

    Pollock, B.A.

    1995-12-01

    The purpose of this research is to analyze the Air Force`s 1994 Toxic Release Inventory data. Statistical tests were used to meet the following research objectives: (1) review the CY 94 data to determine which chemicals were most often reported and which bases and major commands had the most releases in terms of the number of chemicals reported and the amount of chemicals reported and (2) investigate factors which could influence the reporting status of a facility. An analysis of a survey of Air Force facilities indicated that two factors had an influence on the reporting status of Air Force facilities: (1) whether the TRI point of contact had confidence in the completeness of the data used for threshold computations and (2) whether the primary database used for threshold computations was the Standard Base Supply System.

  20. Mobile Source Air Toxics Rule (released in AEO2008)

    Reports and Publications (EIA)

    2008-01-01

    On February 9, 2007, the Environmental Protection Agency (EPA) released its MSAT2 rule, which will establish controls on gasoline, passenger vehicles, and portable fuel containers. The controls are designed to reduce emissions of benzene and other hazardous air pollutants. Benzene is a known carcinogen, and the EPA estimates that mobile sources produced more than 70% of all benzene emissions in 1999. Other mobile source air toxics, including 1,3-butadiene, formaldehyde, acetaldehyde, acrolein, and naphthalene, also are thought to increase cancer rates or contribute to other serious health problems.

  1. Yellow phosphorus process to convert toxic chemicals to non-toxic products

    DOE Patents [OSTI]

    Chang, S.G.

    1994-07-26

    The present invention relates to a process for generating reactive species for destroying toxic chemicals. This process first contacts air or oxygen with aqueous emulsions of molten yellow phosphorus. This contact results in rapid production of abundant reactive species such as O, O[sub 3], PO, PO[sub 2], etc. A gaseous or liquid aqueous solution organic or inorganic chemicals is next contacted by these reactive species to reduce the concentration of toxic chemical and result in a non-toxic product. The final oxidation product of yellow phosphorus is phosphoric acid of a quality which can be recovered for commercial use. A process is developed such that the byproduct, phosphoric acid, is obtained without contamination of toxic species in liquids treated. A gas stream containing ozone without contamination of phosphorus containing species is also obtained in a simple and cost-effective manner. This process is demonstrated to be effective for destroying many types of toxic organic, or inorganic, compounds, including polychlorinated biphenyls (PCB), aromatic chlorides, amines, alcohols, acids, nitro aromatics, aliphatic chlorides, polynuclear aromatic compounds (PAH), dyes, pesticides, sulfides, hydroxyamines, ureas, dithionates and the like. 20 figs.

  2. Yellow phosphorus process to convert toxic chemicals to non-toxic products

    DOE Patents [OSTI]

    Chang, Shih-Ger

    1994-01-01

    The present invention relates to a process for generating reactive species for destroying toxic chemicals. This process first contacts air or oxygen with aqueous emulsions of molten yellow phosphorus. This contact results in rapid production of abundant reactive species such as O, O.sub.3, PO, PO.sub.2, etc. A gaseous or liquid aqueous solution organic or inorganic chemicals is next contacted by these reactive species to reduce the concentration of toxic chemical and result in a non-toxic product. The final oxidation product of yellow phosphorus is phosphoric acid of a quality which can be recovered for commercial use. A process is developed such that the byproduct, phosphoric acid, is obtained without contamination of toxic species in liquids treated. A gas stream containing ozone without contamination of phosphorus containing species is also obtained in a simple and cost-effective manner. This process is demonstrated to be effective for destroying many types of toxic organic, or inorganic, compounds, including polychlorinated biphenyls (PCB), aromatic chlorides, amines, alcohols, acids, nitro aromatics, aliphatic chlorides, polynuclear aromatic compounds (PAH), dyes, pesticides, sulfides, hydroxyamines, ureas, dithionates and the like.

  3. Reactive formulations for a neutralization of toxic industrial chemicals

    DOE Patents [OSTI]

    Tucker, Mark D.; Betty, Rita G.

    2006-10-24

    Decontamination formulations for neutralization of toxic industrial chemicals, and methods of making and using same. The formulations are effective for neutralizing malathion, hydrogen cyanide, sodium cyanide, butyl isocyanate, carbon disulfide, phosgene gas, capsaicin in commercial pepper spray, chlorine gas, anhydrous ammonia gas; and may be effective at neutralizing hydrogen sulfide, sulfur dioxide, formaldehyde, ethylene oxide, methyl bromide, boron trichloride, fluorine, tetraethyl pyrophosphate, phosphorous trichloride, arsine, and tungsten hexafluoride.

  4. Evaluation of Chemical Warfare Agent Percutaneous Vapor Toxicity: Derivation of Toxicity Guidelines for Assessing Chemical Protective Ensembles.

    SciTech Connect (OSTI)

    Watson, A.P.

    2003-07-24

    Percutaneous vapor toxicity guidelines are provided for assessment and selection of chemical protective ensembles (CPEs) to be used by civilian and military first responders operating in a chemical warfare agent vapor environment. The agents evaluated include the G-series and VX nerve agents, the vesicant sulfur mustard (agent HD) and, to a lesser extent, the vesicant Lewisite (agent L). The focus of this evaluation is percutaneous vapor permeation of CPEs and the resulting skin absorption, as inhalation and ocular exposures are assumed to be largely eliminated through use of SCBA and full-face protective masks. Selection of appropriately protective CPE designs and materials incorporates a variety of test parameters to ensure operability, practicality, and adequacy. One aspect of adequacy assessment should be based on systems tests, which focus on effective protection of the most vulnerable body regions (e.g., the groin area), as identified in this analysis. The toxicity range of agent-specific cumulative exposures (Cts) derived in this analysis can be used as decision guidelines for CPE acceptance, in conjunction with weighting consideration towards more susceptible body regions. This toxicity range is bounded by the percutaneous vapor estimated minimal effect (EME{sub pv}) Ct (as the lower end) and the 1% population threshold effect (ECt{sub 01}) estimate. Assumptions of exposure duration used in CPE certification should consider that each agent-specific percutaneous vapor cumulative exposure Ct for a given endpoint is a constant for exposure durations between 30 min and 2 hours.

  5. MODELING DISPERSION FROM CHEMICALS RELEASED AFTER A TRAIN COLLISION IN GRANITEVILLE, SOUTH CAROLINA

    SciTech Connect (OSTI)

    Buckley, R; Chuck Hunter, C; Robert Addis, R; Matt Parker, M

    2006-08-07

    The Savannah River National Laboratory's (SRNL) Weather INformation and Display (WIND) System was used to provide meteorological and atmospheric modeling/consequence assessment support to state and local agencies following the collision of two Norfolk Southern freight trains on the morning of January 6, 2005. This collision resulted in the release of several toxic chemicals to the environment, including chlorine. The dense and highly toxic cloud of chlorine gas that formed in the vicinity of the accident was responsible for nine fatalities, and caused injuries to more than five hundred others. Transport model results depicting the forecast path of the ongoing release were made available to emergency managers in the county's Unified Command Center shortly after SRNL received a request for assistance. Support continued over the ensuing two days of the active response. The SRNL also provided weather briefings and transport/consequence assessment model results to responders from South Carolina Department of Health and Environmental Control (SCDHEC), the Savannah River Site's (SRS) Emergency Operations Center (EOC), Department of Energy Headquarters, and hazmat teams dispatched from the SRS. Although model-generated forecast winds used in consequence assessments conducted during the incident were provided at 2-km horizontal grid spacing during the accident response, a high-resolution Regional Atmospheric Modeling System (RAMS, version 4.3.0) simulation was later performed to examine potential influences of local topography on plume migration. The detailed RAMS simulation was used to determine meteorology using multiple grids with an innermost grid spacing of 125 meters. Results from the two simulations are shown to generally agree with meteorological observations at the time; consequently, local topography did not significantly affect wind in the area. Use of a dense gas dispersion model to simulate localized plume behavior using the higher resolution winds indicated

  6. Scientist Named an American Chemical Society Fellow - News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scientist Named an American Chemical Society Fellow September 1, 2010 Helena Chum Dr. Helena Chum was named a 2010 Fellow by the American Chemical Society. Dr. Helena Chum, research fellow at the U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL), was recently named a 2010 Fellow by the American Chemical Society (ACS). Dr. Chum's work includes the development of technologies for the conversion of biomass and organic wastes into liquid and gaseous fuels, chemicals and

  7. The possibility of garbage, medical and other toxic waste treatment by plasma chemical method

    SciTech Connect (OSTI)

    Rutberg, P.G.; Safronov, A.A.; Bratsev, A.N.; Kuznetsov, V.E.

    1998-12-31

    This paper describes the creation of plasma facility for treatment of toxic waste. All industrialized countries are greatly interested in plasma chemical technology application for the destruction of different types of industrial, building, purification works toxic waste and waste of plants for garbage treatment. On the basis of three-phase plasma generators with power 0.1--1 MW intended for work in air a row of pilot facilities were created for carrying out of experiments on destruction of medical waste and fluorine-chlorine containing substances. The obtained results allow to design and create pilot-commercial plants with treatment productivity of 200 t/24 hours.

  8. The underlying toxicological mechanism of chemical mixtures: A case study on mixture toxicity of cyanogenic toxicants and aldehydes to Photobacterium phosphoreum

    SciTech Connect (OSTI)

    Tian, Dayong; Lin, Zhifen; Zhou, Xianghong; Yin, Daqiang

    2013-10-15

    Intracellular chemical reaction of chemical mixtures is one of the main reasons that cause synergistic or antagonistic effects. However, it still remains unclear what the influencing factors on the intracellular chemical reaction are, and how they influence on the toxicological mechanism of chemical mixtures. To reveal this underlying toxicological mechanism of chemical mixtures, a case study on mixture toxicity of cyanogenic toxicants and aldehydes to Photobacterium phosphoreum was employed, and both their joint effects and mixture toxicity were observed. Then series of two-step linear regressions were performed to describe the relationships between joint effects, the expected additive toxicities and descriptors of individual chemicals (including concentrations, binding affinity to receptors, octanol/water partition coefficients). Based on the quantitative relationships, the underlying joint toxicological mechanisms were revealed. The result shows that, for mixtures with their joint effects resulting from intracellular chemical reaction, their underlying toxicological mechanism depends on not only their interaction with target proteins, but also their transmembrane actions and their concentrations. In addition, two generic points of toxicological mechanism were proposed including the influencing factors on intracellular chemical reaction and the difference of the toxicological mechanism between single reactive chemicals and their mixtures. This study provided an insight into the understanding of the underlying toxicological mechanism for chemical mixtures with intracellular chemical reaction. - Highlights: • Joint effects of nitriles and aldehydes at non-equitoxic ratios were determined. • A novel descriptor, ligand–receptor interaction energy (E{sub binding}), was employed. • Quantitative relationships for mixtures were developed based on a novel descriptor. • The underlying toxic mechanism was revealed based on quantitative relationships. • Two generic points of

  9. Attempt to estimate measurement uncertainty in the Air Force Toxic Chemical Dispersion (AFTOX) model. Master's thesis

    SciTech Connect (OSTI)

    Zettlemoyer, M.D.

    1990-01-01

    The Air Force Toxic Chemical Dispersion (AFTOX) model is a Gaussian puff dispersion model that predicts plumes, concentrations, and hazard distances of toxic chemical spills. A measurement uncertainty propagation formula derived by Freeman et al. (1986) is used within AFTOX to estimate resulting concentration uncertainties due to the effects of data input uncertainties in wind speed, spill height, emission rate, and the horizontal and vertical Gaussian dispersion parameters, and the results are compared to true uncertainties as estimated by standard deviations computed by Monte Carlo simulations. The measurement uncertainty uncertainty propagation formula was found to overestimate measurement uncertainty in AFTOX-calculated concentrations by at least 350 percent, with overestimates worsening with increasing stability and/or increasing measurement uncertainty.

  10. In silico prediction of toxicity of non-congeneric industrial chemicals using ensemble learning based modeling approaches

    SciTech Connect (OSTI)

    Singh, Kunwar P. Gupta, Shikha

    2014-03-15

    Ensemble learning approach based decision treeboost (DTB) and decision tree forest (DTF) models are introduced in order to establish quantitative structure–toxicity relationship (QSTR) for the prediction of toxicity of 1450 diverse chemicals. Eight non-quantum mechanical molecular descriptors were derived. Structural diversity of the chemicals was evaluated using Tanimoto similarity index. Stochastic gradient boosting and bagging algorithms supplemented DTB and DTF models were constructed for classification and function optimization problems using the toxicity end-point in T. pyriformis. Special attention was drawn to prediction ability and robustness of the models, investigated both in external and 10-fold cross validation processes. In complete data, optimal DTB and DTF models rendered accuracies of 98.90%, 98.83% in two-category and 98.14%, 98.14% in four-category toxicity classifications. Both the models further yielded classification accuracies of 100% in external toxicity data of T. pyriformis. The constructed regression models (DTB and DTF) using five descriptors yielded correlation coefficients (R{sup 2}) of 0.945, 0.944 between the measured and predicted toxicities with mean squared errors (MSEs) of 0.059, and 0.064 in complete T. pyriformis data. The T. pyriformis regression models (DTB and DTF) applied to the external toxicity data sets yielded R{sup 2} and MSE values of 0.637, 0.655; 0.534, 0.507 (marine bacteria) and 0.741, 0.691; 0.155, 0.173 (algae). The results suggest for wide applicability of the inter-species models in predicting toxicity of new chemicals for regulatory purposes. These approaches provide useful strategy and robust tools in the screening of ecotoxicological risk or environmental hazard potential of chemicals. - Graphical abstract: Importance of input variables in DTB and DTF classification models for (a) two-category, and (b) four-category toxicity intervals in T. pyriformis data. Generalization and predictive abilities of the

  11. Migration and Retardation of Chemical Toxic Components from Radioactive Waste - Hydrochemical Aspects

    SciTech Connect (OSTI)

    Jedinakova-Krizova, V.; Hanslik, E.

    2003-02-24

    A systematic analysis of nuclear power plant (NPP) operation and radioactive wastes disposal (near-surface disposal and geologic disposal) in underground repositories has provided the basis for a comparison between the radiotoxicity and chemotoxicity as part of an EIA (environmental impact assessment) procedure. This contribution summarizes the hydrochemical mechanisms of transport and retardation processes, chemistry and migration behavior of radionuclides and chemical toxics in natural sorbents, especially bentonites. The effect of solubility and dissolution reactions, diffusion and sorption/desorption, complexation and variations in the aqueous phase composition, pH-value and oxidation-reduction properties and other phenomena affecting distribution coefficients (Kd values) is discussed.

  12. Knowledge system and method for simulating chemical controlled release device performance

    DOE Patents [OSTI]

    Cowan, Christina E.; Van Voris, Peter; Streile, Gary P.; Cataldo, Dominic A.; Burton, Frederick G.

    1991-01-01

    A knowledge system for simulating the performance of a controlled release device is provided. The system includes an input device through which the user selectively inputs one or more data parameters. The data parameters comprise first parameters including device parameters, media parameters, active chemical parameters and device release rate; and second parameters including the minimum effective inhibition zone of the device and the effective lifetime of the device. The system also includes a judgemental knowledge base which includes logic for 1) determining at least one of the second parameters from the release rate and the first parameters and 2) determining at least one of the first parameters from the other of the first parameters and the second parameters. The system further includes a device for displaying the results of the determinations to the user.

  13. Method for minimizing environmental release of toxic compounds in the incineration of wastes

    SciTech Connect (OSTI)

    Lerner, B.J.

    1993-08-24

    A method is described for reducing the discharge of contaminated liquid streams in the treatment of hot waste incinerator exhaust gases containing hydrochloric acid gas, particulate fly ash, toxic metal oxides and toxic organic compounds, comprising the steps of: contacting the exhaust gases with an alkaline material; reacting the major portion of the hydrochloric acid gas content of the exhaust gases with the alkaline material; removing substantially all of the reacted spent alkaline material, fly ash and other particulate matter from the gas in a solids separation stage; treating the particulate-free exhaust gases from the solids separation stage in at least two wet scrubber contact stages operating in series; operating each of the wet scrubber stages with separate dedicated salt-free aqueous scrubbing solutions; scrubbing the gas in the successive wet scrubber contact stages with acid solutions of diminishing acid concentration; absorbing in the scrubbing liquor of the wet scrubber stages substantially all of the residual hydrochloric acid and a portion of the toxic organic compounds from the particulate-free exhaust gases; operating at least the first wet scrubber stage with a recycle aqueous salt-free scrubbing solution loop; recycling a portion of the aqueous acid scrubbing solution from a downstream wet scrubber stage to the initial wet scrubber contactor stage; collecting and conveying the contaminated acid liquid blowdown stream from the initial wet scrubbing liquid recycle loop to the waste incinerator; reincinerating the acid liquor blowdown stream in the waste incinerator for destruction of the organic toxics; removing the major portion of the recycled acid gas in the first alkaline dry solids gas treatment stage and thereby eliminating discharge of a contaminated liquid stream to the environment; and thereafter recovering a purified gaseous stream from the wet scrubbing stages.

  14. Kinetics Study of Solid Ammonia Borane Hydrogen Release – Modeling and Experimental Validation for Chemical Hydrogen Storage

    SciTech Connect (OSTI)

    Choi, Yong-Joon; Ronnebro, Ewa; Rassat, Scot D.; Karkamkar, Abhijeet J.; Maupin, Gary D.; Holladay, Jamelyn D.; Simmons, Kevin L.; Brooks, Kriston P.

    2014-02-24

    Ammonia borane (AB), NH3BH3, is a promising material for chemical hydrogen storage with 19.6 wt% gravimetric hydrogen capacity of which 16.2 wt% hydrogen can be utilized below 200°C. We have investigated the kinetics of hydrogen release from AB and from an AB-methyl cellulose (AB/MC) composite at temperatures of 160-300°C using both experiments and modeling. The purpose of our study was to show safe hydrogen release without thermal runaway effects and to validate system model kinetics. AB/MC released hydrogen at ~20°C lower than neat AB and at a rate that is two times faster. Based on the experimental results, the kinetics equations were revised to better represent the growth and nucleation process during decomposition of AB. We explored two different reactor concepts; Auger and fixed bed. The current Auger reactor concept turned out to not be appropriate, however, we demonstrated safe self-propagation of the hydrogen release reaction of solid AB/MC in a fixed bed reactor.

  15. Decontamination and Management of Human Remains Following Incidents of Hazardous Chemical Release

    SciTech Connect (OSTI)

    Hauschild, Veronique; Watson, Annetta Paule; Bock, Robert Eldon

    2012-01-01

    Abstract Objective: To provide specific procedural guidance and resources for identification, assessment, control, and mitigation of compounds that may contaminate human remains resulting from chemical attack or release. Design: A detailed technical, policy, and regulatory review is summarized. Setting: Guidance is suitable for civilian or military settings where human remains potentially contaminated with hazardous chemicals may be present. Settings would include sites of transportation accidents, natural disasters, terrorist or military operations, mortuary affairs or medical examiner processing and decontamination points, and similar. Patients, Participants: While recommended procedures have not been validated with actual human remains, guidance has been developed from data characterizing controlled experiments with fabrics, materiel, and laboratory animals. Main Outcome Measure(s): Presentation of logic and specific procedures for remains management, protection and decontamination of mortuary affairs personnel, as well as decision criteria for determining when remains are sufficiently decontaminated so as to pose no chemical health hazard. Results: Established procedures and existing equipment/materiel available for decontamination and verification provide appropriate and reasonable means to mitigate chemical hazards from remains. Extensive characterization of issues related to remains decontamination indicates that supra-lethal concentrations of liquid chemical warfare agent VX may prove difficult to decontaminate and verify in a timely fashion. Specialized personnel can and should be called upon to assist with monitoring necessary to clear decontaminated remains for transport and processing. Conclusions: Once appropriate decontamination and verification have been accomplished, normal procedures for remains processing and transport to the decedent s family and the continental United States can be followed.

  16. Reducing Mortality from Terrorist Releases of Chemical and Biological Agents: I. Filtration for Ventilation Systems in Commercial Building

    SciTech Connect (OSTI)

    Thatcher, Tracy L.; Daisey, Joan M.

    1999-09-01

    There is growing concern about potential terrorist attacks involving releases of chemical and/or biological (CB) agents, such as sarin or anthrax, in and around buildings. For an external release, the CB agent can enter the building through the air intakes of a building's mechanical ventilation system and by infiltration through the building envelope. For an interior release in a single room, the mechanical ventilation system, which often recirculates some fraction of the air within a building, may distribute the released CB agent throughout the building. For both cases, installing building systems that remove chemical and biological agents may be the most effective way to protect building occupants. Filtration systems installed in the heating, ventilating and air-conditioning (HVAC) systems of buildings can significantly reduce exposures of building occupants in the event of a release, whether the release is outdoors or indoors. Reduced exposures can reduce the number of deaths from a terrorist attack. The purpose of this report is to provide information and examples of the design of filtration systems to help building engineers retrofit HVAC systems. The report also provides background information on the physical nature of CB agents and brief overviews of the basic principles of particle and vapor filtration.

  17. The development and application of the chemical mixture methodology in analysis of potential health impacts from airborne release in emergencies

    SciTech Connect (OSTI)

    Yu, Xiao-Ying; Petrocchi, Achille J.; Craig, Douglas K.; Glantz, Clifford S.; Trott, Donna M.; Ciolek, John T.; Lu, Po-Yung; Bond, Jayne-Anne; Tuccinardi, Thomas E.; Bouslaugh, Philip R.

    2010-07-15

    The Chemical Mixture Methodology (CMM) is used for emergency response and safety planning by the U.S. Department of Energy, its contractors, and other private and public sector organizations. The CMM estimates potential health impacts on individuals and their ability to take protective actions as a result of exposure to airborne chemical mixtures. They are based on the concentration of each chemical in the mixture at a designated receptor location, the protective action criteria (PAC) providing chemical-specific exposure limit values, and the health code numbers (HCNs) that identify the target organ groupings that may be impacted by exposure to each chemical in a mixture. The CMM has been significantly improved since its introduction more than 10 years ago. Major enhancements involve the expansion of the number of HCNs from 44 to 60 and inclusion of updated PAC values based on an improved development methodology and updates in the data used to derive the PAC values. Comparisons between the 1999 and 2009 versions of the CMM show potentially substantial changes in the assessment results for selected sets of chemical mixtures. In particular, the toxic mode hazard indices (HIs) and target organ HIs are based on more refined acute HCNs, thereby improving the quality of chemical consequence assessment, emergency planning, and emergency response decision making. Seven hypothetical chemical storage and processing scenarios are used to demonstrate how the CMM is applied in emergency planning and hazard assessment.

  18. VirtualToxLab — A platform for estimating the toxic potential of drugs, chemicals and natural products

    SciTech Connect (OSTI)

    Vedani, Angelo; Department of Pharmaceutical Sciences, University of Basel, Klingelbergstrasse 50, 4056 Basel ; Dobler, Max; Smieško, Martin

    2012-06-01

    The VirtualToxLab is an in silico technology for estimating the toxic potential (endocrine and metabolic disruption, some aspects of carcinogenicity and cardiotoxicity) of drugs, chemicals and natural products. The technology is based on an automated protocol that simulates and quantifies the binding of small molecules towards a series of proteins, known or suspected to trigger adverse effects. The toxic potential, a non-linear function ranging from 0.0 (none) to 1.0 (extreme), is derived from the individual binding affinities of a compound towards currently 16 target proteins: 10 nuclear receptors (androgen, estrogen ?, estrogen ?, glucocorticoid, liver X, mineralocorticoid, peroxisome proliferator-activated receptor ?, progesterone, thyroid ?, and thyroid ?), four members of the cytochrome P450 enzyme family (1A2, 2C9, 2D6, and 3A4), a cytosolic transcription factor (aryl hydrocarbon receptor) and a potassium ion channel (hERG). The interface to the technology allows building and uploading molecular structures, viewing and downloading results and, most importantly, rationalizing any prediction at the atomic level by interactively analyzing the binding mode of a compound with its target protein(s) in real-time 3D. The VirtualToxLab has been used to predict the toxic potential for over 2500 compounds: the results are posted on (http://www.virtualtoxlab.org). The free platform — the OpenVirtualToxLab — is accessible (in client–server mode) over the Internet. It is free of charge for universities, governmental agencies, regulatory bodies and non-profit organizations. -- Highlights: ? In silico technology for estimating the toxic potential of drugs and chemicals. ? Simulation of binding towards 16 proteins suspected to trigger adverse effects. ? Mechanistic interpretation and real-time 3D visualization. ? Accessible over the Internet. ? Free of charge for universities, governmental agencies, regulatory bodies and NPOs.

  19. Chemical behavior of fission products in the ORNL fission product release program. Supplement. [PWR; BWR

    SciTech Connect (OSTI)

    Collins, J.L.; Osborne, M.F.; Lorenz, R.A.

    1983-01-01

    Tests data are presented for BWR and PWR rods in test HI-4 and test HI-5. Operating conditions fission product release data are included.

  20. Acute environmental toxicity and persistence of methyl salicylate: A chemical agent simulant. Final report

    SciTech Connect (OSTI)

    Cataldo, D.A.; Ligotke, M.W.; Harvey, S.D.; Fellows, R.J.; Li, S.W.

    1994-06-01

    The interactions of methyl salicylate with plant foliage and soils were assessed using aerosol/vapor exposure methods. Measurements of deposition velocity and residence times for soils and foliar surfaces are reported. Severe plant contact toxicity was observed at foliar mass-loading levels above 4 {mu}g/cm{sup 2} leaf; however, recovery was noted after four to fourteen days. Methyl salicylate has a short-term effect on soil dehydrogenase activity, but not phosphatase activity. Results of the earthworm bioassay indicated only minimal effects on survival.

  1. Heme oxygenase-1 protects endothelial cells from the toxicity of air pollutant chemicals

    SciTech Connect (OSTI)

    Lawal, Akeem O.; Zhang, Min; Dittmar, Michael; Lulla, Aaron; Araujo, Jesus A.

    2015-05-01

    Diesel exhaust particles (DEPs) are a major component of diesel emissions, responsible for a large portion of their toxicity. In this study, we examined the toxic effects of DEPs on endothelial cells and the role of DEP-induced heme oxygenase-1 (HO-1) expression. Human microvascular endothelial cells (HMECs) were treated with an organic extract of DEPs from an automobile engine (A-DEP) or a forklift engine (F-DEP) for 1 and 4 h. ROS generation, cell viability, lactate dehydrogenase leakage, expression of HO-1, inflammatory genes, cell adhesion molecules and unfolded protein respone (UPR) gene were assessed. HO-1 expression and/or activity were inhibited by siRNA or tin protoporphyrin (Sn PPIX) and enhanced by an expression plasmid or cobalt protoporphyrin (CoPPIX). Exposure to 25 μg/ml of A-DEP and F-DEP significantly induced ROS production, cellular toxicity and greater levels of inflammatory and cellular adhesion molecules but to a different degree. Inhibition of HO-1 enzymatic activity with SnPPIX and silencing of the HO-1 gene by siRNA enhanced DEP-induced ROS production, further decreased cell viability and increased expression of inflammatory and cell adhesion molecules. On the other hand, overexpression of the HO-1 gene by a pcDNA 3.1D/V5-HO-1 plasmid significantly mitigated ROS production, increased cell survival and decreased the expression of inflammatory genes. HO-1 expression protected HMECs from DEP-induced prooxidative and proinflammatory effects. Modulation of HO-1 expression could potentially serve as a therapeutic target in an attempt to inhibit the cardiovascular effects of ambient PM. - Highlights: • We examined the role of HO-1 expression on diesel exhaust particle (DEP) in endothelial cells. • DEPs exert cytotoxic and inflammatory effects on human microvascular endothelial cells (HMECs). • DEPs induce HO-1 expression in HMECs. • HO-1 protects against the oxidative stress induced by DEps. • HO-1 attenuates the proinflammatory effects

  2. How Do I Know? A Guide to the Selection of Personal Protective Equipment for Use in Responding to A Release of Chemical Warfare Agents

    SciTech Connect (OSTI)

    Foust, C.B.

    1999-05-01

    An incident involving chemical warfare agents requires a unique hazardous materials (HAZMAT) response. As with an HAZMAT event, federal regulations prescribe that responders must be protected from exposure to the chemical agents. But unlike other HAZMAT events, special considerations govern selection of personal protective equipment (PPE). PPE includes all clothing, respirators and monitoring devices used to respond to a chemical release. PPE can differ depending on whether responders are military or civilian personnel.

  3. Reducing the impact of chemical releases: U.S. Steel Clairton Works` Early Warning Plan

    SciTech Connect (OSTI)

    York, R.G.; Hart, C.M.; Graeser, W.C.

    1995-12-01

    The Early Warning Plan (EWP) is a program designed to alert plant personnel to a release of contaminants to a receiving stream before it becomes significant enough to impinge on the environment or the public. It also provides a method of written documentation of any discharge of contaminants so that rapid corrective action can be taken. The EWP includes procedures for monitoring, rapid analytical turnaround, on-site analysis, statistical process control evaluation, and follow-up investigation. It is related to, but separate from other emergency response plans for the Clairton complex. The plant also uses a Spill Prevention, Control, and Countermeasure Plan (SPCC), an Environmental Emergency Response Plan (EERP), an Oil Pollution Act (OPA) Response Plan, and an EPA Facility Response Plan. Major spills and response activities are described in these other plans, but the EWP has served to concentrate on day-to-day plant operations. The paper discusses the driving forces behind the Plan, the EWP, and results of the program after nearly 10 years of operation.

  4. Changing Trends in the Bulk Chemicals and Pulp and Paper Industries (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01

    Compared with the experience of the 1990s, rising energy prices in recent years have led to questions about expectations of growth in industrial output, particularly in energy-intensive industries. Given the higher price trends, a review of expected growth trends in selected industries was undertaken as part of the production of Annual Energy Outlook 2005 (AEO). In addition, projections for the industrial value of shipments, which were based on the Standard Industrial Classification (SIC) system in AEO2004, are based on the North American Industry Classification System (NAICS) in AEO2005. The change in industrial classification leads to lower historical growth rates for many industrial sectors. The impacts of these two changes are highlighted in this section for two of the largest energy-consuming industries in the U.S. industrial sector-bulk chemicals and pulp and paper.

  5. Control of Toxic Chemicals in Puget Sound, Phase 3: Study of Atmospheric Deposition of Air Toxics to the Surface of Puget Sound

    SciTech Connect (OSTI)

    Brandenberger, Jill M.; Louchouarn, Patrick; Kuo, Li-Jung; Crecelius, Eric A.; Cullinan, Valerie I.; Gill, Gary A.; Garland, Charity R.; Williamson, J. B.; Dhammapala, R.

    2010-07-05

    The results of the Phase 1 Toxics Loading study suggested that runoff from the land surface and atmospheric deposition directly to marine waters have resulted in considerable loads of contaminants to Puget Sound (Hart Crowser et al. 2007). The limited data available for atmospheric deposition fluxes throughout Puget Sound was recognized as a significant data gap. Therefore, this study provided more recent or first reported atmospheric deposition fluxes of PAHs, PBDEs, and select trace elements for Puget Sound. Samples representing bulk atmospheric deposition were collected during 2008 and 2009 at seven stations around Puget Sound spanning from Padilla Bay south to Nisqually River including Hood Canal and the Straits of Juan de Fuca. Revised annual loading estimates for atmospheric deposition to the waters of Puget Sound were calculated for each of the toxics and demonstrated an overall decrease in the atmospheric loading estimates except for polybrominated diphenyl ethers (PBDEs) and total mercury (THg). The median atmospheric deposition flux of total PBDE (7.0 ng/m2/d) was higher than that of the Hart Crowser (2007) Phase 1 estimate (2.0 ng/m2/d). The THg was not significantly different from the original estimates. The median atmospheric deposition flux for pyrogenic PAHs (34.2 ng/m2/d; without TCB) shows a relatively narrow range across all stations (interquartile range: 21.2- 61.1 ng/m2/d) and shows no influence of season. The highest median fluxes for all parameters were measured at the industrial location in Tacoma and the lowest were recorded at the rural sites in Hood Canal and Sequim Bay. Finally, a semi-quantitative apportionment study permitted a first-order characterization of source inputs to the atmosphere of the Puget Sound. Both biomarker ratios and a principal component analysis confirmed regional data from the Puget Sound and Straits of Georgia region and pointed to the predominance of biomass and fossil fuel (mostly liquid petroleum products such

  6. Devices for collecting chemical compounds

    DOE Patents [OSTI]

    Scott, Jill R; Groenewold, Gary S

    2013-12-24

    A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from a fixed surface so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

  7. Toxic Substances Control Act (TSCA) chemical substances inventory: PMN number to EPA accession number link (for microcomputers). Data file

    SciTech Connect (OSTI)

    Not Available

    1994-05-01

    The PMN Number to EPA Accession Number Link Diskette provides a cross-reference of these numbers for commenced PMNs on the confidential portion of the Toxic Substances Control Act (TSCA) Master Inventory File. Neither this cross-reference nor the additional information included is TSCA Confidential Business Information. Provided on the diskette for each confidential commenced PMN are the PMN Case Number, EPA Accession Number, Generic Name, and EPA special flags. For more detailed information on the confidential portion of the TSCA Inventory, including generic names, users can consult the introductory material of the printed TSCA Inventory: 1985 Edition and its 1990 Supplement. New versions of this file may be issued in the future.

  8. Process safety management for highly hazardous chemicals

    SciTech Connect (OSTI)

    1996-02-01

    Purpose of this document is to assist US DOE contractors who work with threshold quantities of highly hazardous chemicals (HHCs), flammable liquids or gases, or explosives in successfully implementing the requirements of OSHA Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119). Purpose of this rule is to prevent releases of HHCs that have the potential to cause catastrophic fires, explosions, or toxic exposures.

  9. Exposure Levels for Chemical Threat Compounds; Information to Facilitate Chemical Incident Response

    SciTech Connect (OSTI)

    Hauschild, Veronique; Watson, Annetta Paule

    2013-01-01

    Exposure Standards, Limits and Guidelines for Chemical Threat Compunds ABSTRACT Exposure criteria for chemical warfare (CW) agents and certain toxic industrial chemicals (TICs) used as CW agents (such as chlorine fill in an improvised explosive device) have been developed for protection of the civilian general public, civilian employees in chemical agent processing facilities and deployed military populations. In addition, compound-specific concentrations have been developed to serve as how clean is clean enough clearance criteria guiding facility recovery following chemical terrorist or other hazardous release events. Such criteria are also useful to verify compound absence, identify containment boundaries and expedite facility recovery following chemical threat release. There is no single right value or concentration appropriate for all chemical hazard control applications. It is acknowledged that locating and comparing the many sources of CW agent and TIC exposure criteria has not been previously well-defined. This paper summarizes many of these estimates and assembles critical documentation regarding their derivation and use.

  10. Enhanced toxic cloud knockdown spray system for decontamination applications

    DOE Patents [OSTI]

    Betty, Rita G.; Tucker, Mark D.; Brockmann, John E.; Lucero, Daniel A.; Levin, Bruce L.; Leonard, Jonathan

    2011-09-06

    Methods and systems for knockdown and neutralization of toxic clouds of aerosolized chemical or biological warfare (CBW) agents and toxic industrial chemicals using a non-toxic, non-corrosive aqueous decontamination formulation.

  11. Improved Meteorological Input for Atmospheric Release Decision support Systems and an Integrated LES Modeling System for Atmospheric Dispersion of Toxic Agents: Homeland Security Applications

    SciTech Connect (OSTI)

    Arnold, E; Simpson, M; Larsen, S; Gash, J; Aluzzi, F; Lundquist, J; Sugiyama, G

    2010-04-26

    When hazardous material is accidently or intentionally released into the atmosphere, emergency response organizations look to decision support systems (DSSs) to translate contaminant information provided by atmospheric models into effective decisions to protect the public and emergency responders and to mitigate subsequent consequences. The Department of Homeland Security (DHS)-led Interagency Modeling and Atmospheric Assessment Center (IMAAC) is one of the primary DSSs utilized by emergency management organizations. IMAAC is responsible for providing 'a single piont for the coordination and dissemination of Federal dispersion modeling and hazard prediction products that represent the Federal position' during actual or potential incidents under the National Response Plan. The Department of Energy's (DOE) National Atmospheric Release Advisory Center (NARAC), locatec at the Lawrence Livermore National Laboratory (LLNL), serves as the primary operations center of the IMAAC. A key component of atmospheric release decision support systems is meteorological information - models and data of winds, turbulence, and other atmospheric boundary-layer parameters. The accuracy of contaminant predictions is strongly dependent on the quality of this information. Therefore, the effectiveness of DSSs can be enhanced by improving the meteorological options available to drive atmospheric transport and fate models. The overall goal of this project was to develop and evaluate new meteorological modeling capabilities for DSSs based on the use of NASA Earth-science data sets in order to enhance the atmospheric-hazard information provided to emergency managers and responders. The final report describes the LLNL contributions to this multi-institutional effort. LLNL developed an approach to utilize NCAR meteorological predictions using NASA MODIS data for the New York City (NYC) region and demonstrated the potential impact of the use of different data sources and data parameterizations on

  12. News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases News Releases We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. News Releases - 2016» News Releases - 2015» News Releases - 2014» News Releases - 2013» News Releases - 2012» News Releases - 2011» News Releases - 2010» News Releases - 2009» News Releases - 2008» The thermal traits of a leaf, critical for photosynthesis, may be under strong evolutionary selection

  13. Technical support for recovery phase decision-making in the event of a chemical warfare agent release

    SciTech Connect (OSTI)

    Watson, A.; Kistner, S.; Halbrook, R.

    1995-12-31

    In late 1985, Congress mandated that the U.S. stockpile of lethal unitary chemical agents and munitions be destroyed by the Department of the Army in a manner that provides maximum protection to the environment, the general public and personnel involved in the disposal program (Public Law 99-1, Section 1412, Title 14, Part b). These unitary munitions were last manufactured in the late 1960`s. The stockpiled inventory is estimated to approximate 25,000-30,000 tons, an includes organophosphate ({open_quotes}nerves{close_quotes}) agents such as VX [O-ethylester of S-(diisopropyl aminoethyl) methyl phosphonothiolate, C{sub 11}H{sub 26}NO{sub 2}PS] and vesicant ({open_quotes}blister{close_quotes}) agents such as Hd [sulfur mustard; bis (2-chloroethyl sulfide), C{sub 4}H{sub 8}Cl{sub 2}S]. The method of agent destruction selected by the Department of the Army is combined high-temperature and high-residence time incineration at secured military installations where munitions are currently stockpiled. This program supports the research program to address: the biomonitoring of nerve agent exposure; agent detection limits in foods and milk; and permeation of agents through porous construction materials.

  14. Evaluating temperature and fuel stratification for heat-release rate control in a reactivity-controlled compression-ignition engine using optical diagnostics and chemical kinetics modeling

    SciTech Connect (OSTI)

    Musculus, Mark P. B.; Kokjohn, Sage L.; Reitz, Rolf D.

    2015-04-23

    We investigated the combustion process in a dual-fuel, reactivity-controlled compression-ignition (RCCI) engine using a combination of optical diagnostics and chemical kinetics modeling to explain the role of equivalence ratio, temperature, and fuel reactivity stratification for heat-release rate control. An optically accessible engine is operated in the RCCI combustion mode using gasoline primary reference fuels (PRF). A well-mixed charge of iso-octane (PRF = 100) is created by injecting fuel into the engine cylinder during the intake stroke using a gasoline-type direct injector. Later in the cycle, n-heptane (PRF = 0) is delivered through a centrally mounted diesel-type common-rail injector. This injection strategy generates stratification in equivalence ratio, fuel blend, and temperature. The first part of this study uses a high-speed camera to image the injection events and record high-temperature combustion chemiluminescence. Moreover, the chemiluminescence imaging showed that, at the operating condition studied in the present work, mixtures in the squish region ignite first, and the reaction zone proceeds inward toward the center of the combustion chamber. The second part of this study investigates the charge preparation of the RCCI strategy using planar laser-induced fluorescence (PLIF) of a fuel tracer under non-reacting conditions to quantify fuel concentration distributions prior to ignition. The fuel-tracer PLIF data show that the combustion event proceeds down gradients in the n-heptane distribution. The third part of the study uses chemical kinetics modeling over a range of mixtures spanning the distributions observed from the fuel-tracer fluorescence imaging to isolate the roles of temperature, equivalence ratio, and PRF number stratification. The simulations predict that PRF number stratification is the dominant factor controlling the ignition location and growth rate of the reaction zone. Equivalence ratio has a smaller, but still significant

  15. Alginate based 3D hydrogels as an in vitro co-culture model platform for the toxicity screening of new chemical entities

    SciTech Connect (OSTI)

    Lan, Shih-Feng; Starly, Binil

    2011-10-01

    Prediction of human response to potential therapeutic drugs is through conventional methods of in vitro cell culture assays and expensive in vivo animal testing. Alternatives to animal testing require sophisticated in vitro model systems that must replicate in vivo like function for reliable testing applications. Advancements in biomaterials have enabled the development of three-dimensional (3D) cell encapsulated hydrogels as in vitro drug screening tissue model systems. In this study, we have developed an in vitro platform to enable high density 3D culture of liver cells combined with a monolayer growth of target breast cancer cell line (MCF-7) in a static environment as a representative example of screening drug compounds for hepatotoxicity and drug efficacy. Alginate hydrogels encapsulated with serial cell densities of HepG2 cells (10{sup 5}-10{sup 8} cells/ml) are supported by a porous poly-carbonate disc platform and co-cultured with MCF-7 cells within standard cell culture plates during a 3 day study period. The clearance rates of drug transformation by HepG2 cells are measured using a coumarin based pro-drug. The platform was used to test for HepG2 cytotoxicity 50% (CT{sub 50}) using commercially available drugs which further correlated well with published in vivo LD{sub 50} values. The developed test platform allowed us to evaluate drug dose concentrations to predict hepatotoxicity and its effect on the target cells. The in vitro 3D co-culture platform provides a scalable and flexible approach to test multiple-cell types in a hybrid setting within standard cell culture plates which may open up novel 3D in vitro culture techniques to screen new chemical entity compounds. - Graphical abstract: Display Omitted Highlights: > A porous support disc design to support the culture of desired cells in 3D hydrogels. > Demonstrated the co-culture of two cell types within standard cell-culture plates. > A scalable, low cost approach to toxicity screening involving

  16. Rad-Release

    ScienceCinema (OSTI)

    None

    2013-05-28

    The R&D 100 Award winning Rad-Release Chemical Decontamination Technology is a highly effective (up to 99% removal rate), affordable, patented chemical-foam-clay decontamination process tailored to specific radiological and metal contaminants, which is applicable to a wide variety of substrates. For more information about this project, visit http://www.inl.gov/rd100/2011/rad-release/

  17. Rad-Release

    SciTech Connect (OSTI)

    2011-01-01

    The R&D 100 Award winning Rad-Release Chemical Decontamination Technology is a highly effective (up to 99% removal rate), affordable, patented chemical-foam-clay decontamination process tailored to specific radiological and metal contaminants, which is applicable to a wide variety of substrates. For more information about this project, visit http://www.inl.gov/rd100/2011/rad-release/

  18. Evaluating temperature and fuel stratification for heat-release rate control in a reactivity-controlled compression-ignition engine using optical diagnostics and chemical kinetics modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Musculus, Mark P. B.; Kokjohn, Sage L.; Reitz, Rolf D.

    2015-04-23

    We investigated the combustion process in a dual-fuel, reactivity-controlled compression-ignition (RCCI) engine using a combination of optical diagnostics and chemical kinetics modeling to explain the role of equivalence ratio, temperature, and fuel reactivity stratification for heat-release rate control. An optically accessible engine is operated in the RCCI combustion mode using gasoline primary reference fuels (PRF). A well-mixed charge of iso-octane (PRF = 100) is created by injecting fuel into the engine cylinder during the intake stroke using a gasoline-type direct injector. Later in the cycle, n-heptane (PRF = 0) is delivered through a centrally mounted diesel-type common-rail injector. This injectionmore » strategy generates stratification in equivalence ratio, fuel blend, and temperature. The first part of this study uses a high-speed camera to image the injection events and record high-temperature combustion chemiluminescence. Moreover, the chemiluminescence imaging showed that, at the operating condition studied in the present work, mixtures in the squish region ignite first, and the reaction zone proceeds inward toward the center of the combustion chamber. The second part of this study investigates the charge preparation of the RCCI strategy using planar laser-induced fluorescence (PLIF) of a fuel tracer under non-reacting conditions to quantify fuel concentration distributions prior to ignition. The fuel-tracer PLIF data show that the combustion event proceeds down gradients in the n-heptane distribution. The third part of the study uses chemical kinetics modeling over a range of mixtures spanning the distributions observed from the fuel-tracer fluorescence imaging to isolate the roles of temperature, equivalence ratio, and PRF number stratification. The simulations predict that PRF number stratification is the dominant factor controlling the ignition location and growth rate of the reaction zone. Equivalence ratio has a smaller, but still

  19. Chemical process hazards analysis

    SciTech Connect (OSTI)

    1996-02-01

    The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

  20. Chemical Occurrences

    Broader source: Energy.gov [DOE]

    Classification of Chemical Occurrence Reports into the following four classes: Occurrences characterized by serious energy release, injury or exposure requiring medical treatment, or severe environmental damage, Occurrences characterized by minor injury or exposure, or reportable environmental release, Occurrences that were near misses including notable safety violations and Minor occurrences.

  1. Device for collecting chemical compounds and related methods

    DOE Patents [OSTI]

    Scott, Jill R.; Groenewold, Gary S.; Rae, Catherine

    2013-01-01

    A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from the fixed surfaces so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

  2. Experimental determination of the speciation, partitioning, and release of perrhenate as a chemical surrogate for pertechnetate from a sodalite-bearing multiphase ceramic waste form

    SciTech Connect (OSTI)

    Pierce, Eric M.; Lukens, Wayne W.; Fitts, Jeff. P.; Jantzen, Carol. M.; Tang, G.

    2013-12-01

    A key component to closing the nuclear fuel cycle is the storage and disposition of nuclear waste in geologic systems. Multiphase ceramic waste forms have been studied extensively as a potential host matrix for nuclear waste. Understanding the speciation, partitioning, and release behavior of radionuclides immobilized in multiphase ceramic waste forms is a critical aspect of developing the scientific and technical basis for nuclear waste management. In this study, we evaluated a sodalite-bearing multiphase ceramic waste form (i.e., fluidized-bed steam reform sodium aluminosilicate [FBSR NAS] product) as a potential host matrix for long-lived radionuclides, such as technetium (99Tc). The FBSR NAS material consists primarily of nepheline (ideally NaAlSiO4), anion-bearing sodalites (ideally M8[Al6Si6O24]X2, where M refers to alkali and alkaline earth cations and X refers to monovalent anions), and nosean (ideally Na8[AlSiO4]6SO4). Bulk X-ray absorption fine structure analysis of the multiphase ceramic waste form, suggest rhenium (Re) is in the Re(VII) oxidation state and has partitioned to a Re-bearing sodalite phase (most likely a perrhenate sodalite Na8[Al6Si6O24](ReO4)2). Rhenium was added as a chemical surrogate for 99Tc during the FBSR NAS synthesis process. The weathering behavior of the FBSR NAS material was evaluated under hydraulically unsaturated conditions with deionized water at 90 ?C. The steady-state Al, Na, and Si concentrations suggests the weathering mechanisms are consistent with what has been observed for other aluminosilicate minerals and include a combination of ion exchange, network hydrolysis, and the formation of an enriched-silica surface layer or phase. The steady-state S and Re concentrations are within an order of magnitude of the nosean and perrhenate sodalite solubility, respectively. The order of magnitude difference between the observed and predicted concentration for Re and S may be associated with the fact that the anion

  3. Toxicity evaluation and hazard review Cold Smoke

    SciTech Connect (OSTI)

    Archuleta, M.M.; Stocum, W.E.

    1993-12-01

    Cold Smoke is a dense white smoke produced by the reaction of titanium tetrachloride and aqueous ammonia aerosols. Early studies on the toxicity of this nonpyrotechnically generated smoke indicated that the smoke itself is essentially non-toxic (i.e. exhibits to systemic toxicity or organ damage due to exposure) under normal deployment conditions. The purpose of this evaluation was to review and summarize the recent literature data available on the toxicity of Cold Smoke, its chemical constituents, and its starting materials.

  4. Toxic Substances Control Act (TSCA) chemical substances inventory: Revised inventory synonym and preferred name file, February 1996 (for microcomputers). Data file

    SciTech Connect (OSTI)

    1996-02-01

    The TSCA Chemical Substance Inventory on diskette provides chemical identity information for the non-confidential substances on the TSCA Master Inventory File. For infomration on the scope and content of the TSCA Inventory, users can consult the introduction material of the printed TSCA Inventory: 1985 Edition and its 1990 Supplement (PB91-159665 and PB91-145458). The diskettes contain no TSCA Confidential Business Information. New versions of the TSCA Inventory on diskette may be issued at approximately six month intervals. Unlike the printed editions of the TSCA Inventory, the diskette version does not include the generic names for the confidential substances on the Master Inventory File, nor does it include synonyms derived from CAS files for the non-confidential substances. In addition, no search software is provided. The data provided for each chemical substance includes the CAS Registry Number, Preferred CA Index Name, molecular formula, and other appropriate information, such as valid chemical names reported by submitters. The entries are in ascending CAS Registry Number order.

  5. News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Releases News Releases Accessible by Topic, Keywords (See "Search Releases") or Chronologically (See "ALL") News Releases Science Briefs Photos Picture of the Week Publications Social Media Videos Fact Sheets The thermal traits of a leaf, critical for photosynthesis, may be under strong evolutionary selection that occurs in response to environmental temperatures. Here a thermal leaf image details temperature variation, which greatly affects plant functions since

  6. VARIATIONS IN REPRODUCTIVE TOXICANT IDENTIFICATION

    SciTech Connect (OSTI)

    Simmons, F

    2008-05-13

    Reproductive toxicants are a very important class of compounds. They present unique hazards to those of child bearing ages, perform their 'dirty work' using a wide variety of mechanisms on a number of different organs, and are regulatorily important. Because of all of this, properly identifying reproductive toxicants is important, but fraught with difficulty. In this paper we will describe types or reproductive toxicants, their importance, and both mistakes and good practices that people who are not experts in reproductive toxicology may use in their attempts to identify them. Additionally, this paper will focus on chemical reproductive toxicants and will not address biological agents that could affect reproductive toxicity although many principles outlined here could be applied to that endeavor.

  7. Toxic remediation

    DOE Patents [OSTI]

    Matthews, Stephen M.; Schonberg, Russell G.; Fadness, David R.

    1994-01-01

    What is disclosed is a novel toxic waste remediation system designed to provide on-site destruction of a wide variety of hazardous organic volatile hydrocarbons, including but not limited to halogenated and aromatic hydrocarbons in the vapor phase. This invention utilizes a detoxification plenum and radiation treatment which transforms hazardous organic compounds into non-hazardous substances.

  8. FINAL RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RELEASE AWARDEE: ____________________________________________________ The work under Award No. DE-__________________________, dated ______________, between the United States of America (represented by the Department of Energy, National Energy Technology Laboratory, and the undersigned awardee, having been completed and finally accepted , and in consideration of Final Payment thereunder, the United States of America, its officers, agents and employees are hereby released from all liabilities,

  9. University of Delaware | CCEI Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases DOE Funding Leads to New Technology that is Revolutionizing Chemical Analysis (November 2015) CCEI's carbon detection technology is commercialized by Activated ...

  10. Composition and method for storing and releasing hydrogen

    DOE Patents [OSTI]

    Thorn, David L.; Tumas, William; Ott, Kevin C.; Burrell, Anthony K.

    2010-06-15

    A chemical system for storing and releasing hydrogen utilizes an endothermic reaction that releases hydrogen coupled to an exothermic reaction to drive the process thermodynamically, or an exothermic reaction that releases hydrogen coupled to an endothermic reaction.

  11. Model for TCLP Releases from Waste Glasses

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Vienna, John D.

    2003-05-01

    A first-order property model for normalized Toxicity Characteristic Leaching Procedure (TCLP) release as a function of glass composition was developed using data collected from various studies. The normalized boron release is used to estimate the release of toxic elements based on the observation that the boron release represents the conservative release for those constituents of interest. The current TCLP model has two targeted application areas: (1) delisting of waste-glass product as radioactive (not mixed) waste and (2) designating the glass wastes generated from waste-glass research activities as hazardous or non-hazardous. This report describes the data collection and model development for TCLP releases and discusses the issues related to the application of the model.

  12. Health risk from earthquake caused releases of UF{sub 6} at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Brown, N.W; Lu, S.; Chen, J.C.; Roehnelt, R.; Lombardi, D.

    1998-05-01

    The health risk to the public and workers from potential exposure to the toxic materials from earthquake caused releases of uranium hexafluoride from the Paducah gaseous Diffusion Plant are evaluated. The results of the study show that the health risk from earthquake caused releases is small, and probably less than risks associated with the transportation of hydrogen fluoride and other similar chemicals used by industry. The probability of more than 30 people experiencing health consequences (injuries) from earthquake damage is less than 4xlO{sup 4}/yr.

  13. Chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P.; Frye-Mason, Gregory C.

    2001-01-01

    A chemical preconcentrator is disclosed with applications to chemical sensing and analysis. The preconcentrator can be formed by depositing a resistive heating element (e.g. platinum) over a membrane (e.g. silicon nitride) suspended above a substrate. A coating of a sorptive material (e.g. a microporous hydrophobic sol-gel coating or a polymer coating) is formed on the suspended membrane proximate to the heating element to selective sorb one or more chemical species of interest over a time period, thereby concentrating the chemical species in the sorptive material. Upon heating the sorptive material with the resistive heating element, the sorbed chemical species are released for detection and analysis in a relatively high concentration and over a relatively short time period. The sorptive material can be made to selectively sorb particular chemical species of interest while not substantially sorbing other chemical species not of interest. The present invention has applications for use in forming high-sensitivity, rapid-response miniaturized chemical analysis systems (e.g. a "chem lab on a chip").

  14. Assessing the toxic effects of ethylene glycol ethers using Quantitative Structure Toxicity Relationship models

    SciTech Connect (OSTI)

    Ruiz, Patricia; Mumtaz, Moiz; Gombar, Vijay

    2011-07-15

    Experimental determination of toxicity profiles consumes a great deal of time, money, and other resources. Consequently, businesses, societies, and regulators strive for reliable alternatives such as Quantitative Structure Toxicity Relationship (QSTR) models to fill gaps in toxicity profiles of compounds of concern to human health. The use of glycol ethers and their health effects have recently attracted the attention of international organizations such as the World Health Organization (WHO). The board members of Concise International Chemical Assessment Documents (CICAD) recently identified inadequate testing as well as gaps in toxicity profiles of ethylene glycol mono-n-alkyl ethers (EGEs). The CICAD board requested the ATSDR Computational Toxicology and Methods Development Laboratory to conduct QSTR assessments of certain specific toxicity endpoints for these chemicals. In order to evaluate the potential health effects of EGEs, CICAD proposed a critical QSTR analysis of the mutagenicity, carcinogenicity, and developmental effects of EGEs and other selected chemicals. We report here results of the application of QSTRs to assess rodent carcinogenicity, mutagenicity, and developmental toxicity of four EGEs: 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol, and 2-butoxyethanol and their metabolites. Neither mutagenicity nor carcinogenicity is indicated for the parent compounds, but these compounds are predicted to be developmental toxicants. The predicted toxicity effects were subjected to reverse QSTR (rQSTR) analysis to identify structural attributes that may be the main drivers of the developmental toxicity potential of these compounds.

  15. code release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    code release - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  16. Capacitive chemical sensor

    DOE Patents [OSTI]

    Manginell, Ronald P; Moorman, Matthew W; Wheeler, David R

    2014-05-27

    A microfabricated capacitive chemical sensor can be used as an autonomous chemical sensor or as an analyte-sensitive chemical preconcentrator in a larger microanalytical system. The capacitive chemical sensor detects changes in sensing film dielectric properties, such as the dielectric constant, conductivity, or dimensionality. These changes result from the interaction of a target analyte with the sensing film. This capability provides a low-power, self-heating chemical sensor suitable for remote and unattended sensing applications. The capacitive chemical sensor also enables a smart, analyte-sensitive chemical preconcentrator. After sorption of the sample by the sensing film, the film can be rapidly heated to release the sample for further analysis. Therefore, the capacitive chemical sensor can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  17. Apparatus and methods for detecting chemical permeation

    DOE Patents [OSTI]

    Vo-Dinh, Tuan

    1994-01-01

    Apparatus and methods for detecting the permeation of hazardous or toxic chemicals through protective clothing are disclosed. The hazardous or toxic chemicals of interest do not possess the spectral characteristic of luminescence. The apparatus and methods utilize a spectrochemical modification technique to detect the luminescence quenching of an indicator compound which upon permeation of the chemical through the protective clothing, the indicator is exposed to the chemical, thus indicating chemical permeation.

  18. Causes of toxicity in stormwater runoff from sawmills

    SciTech Connect (OSTI)

    Bailey, H.C.; Elphick, J.R.; Potter, A.; Chao, E.; Konasewich, D.; Zak, J.B.

    1999-07-01

    Samples of stormwater runoff from nine sawmills in British Columbia, Canada, were tested for acute toxicity with juvenile rainbow trout over a 23-month period. Forty-two of the 58 samples tested exhibited toxicity. Causes of toxicity were investigated using toxicity identification evaluation techniques. Toxicity was attributed to divalent cations, particularly zinc, in 32 of the samples. The low hardness associated with most of the samples increased the potential for metal toxicity. For example, the LC50 of zinc was 14 {micro}g/L at a hardness of 5 mg/L. Toxicity in the remaining samples was largely attributed to tannins and lignins and was associated with areas of bulk log handling. No evidence was found to indicate that antisapstain chemicals applied to freshly cut wood contributed to toxicity.

  19. Press Releases - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Newsroom Press Releases Newsroom Press Releases Media Contacts Photo Gallery The Hanford Story Hanford Blog Hanford YouTube Channel

  20. Nanoparticle toxicity testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    submit Nanoparticle toxicity testing Assessing the potential health hazards of nanotechnology March 25, 2013 Robot In the search for more accurate and efficient techniques to...

  1. Press Releases - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Richland Operations Office Newsroom Press Releases Richland Operations Office Richland Operations Office River Corridor Central Plateau Groundwater Mission Support Newsroom Press Releases News Calendar

  2. Press Releases - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of River Protection Newsroom Press Releases Office of River Protection About ORP ORP Projects & Facilities Newsroom Photos & Multimedia ORP Events Press Releases Contracts & ...

  3. Latest News Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Release Release Date: Contact: Shelley Martin, DOE National Energy Technology Laboratory, 304-285-0228, contact.publicaffairs@netl.doe.gov 2016 2015 2014 2013

  4. Structure activity relationships to assess new chemicals under TSCA

    SciTech Connect (OSTI)

    Auletta, A.E.

    1990-12-31

    Under Section 5 of the Toxic Substances Control Act (TSCA), manufacturers must notify the US Environmental Protection Agency (EPA) 90 days before manufacturing, processing, or importing a new chemical substance. This is referred to as a premanufacture notice (PMN). The PMN must contain certain information including chemical identity, production volume, proposed uses, estimates of exposure and release, and any health or environmental test data that are available to the submitter. Because there is no explicit statutory authority that requires testing of new chemicals prior to their entry into the market, most PMNs are submitted with little or no data. As a result, EPA has developed special techniques for hazard assessment of PMN chemicals. These include (1) evaluation of available data on the chemical itself, (2) evaluation of data on analogues of the PMN, or evaluation of data on metabolites or analogues of metabolites of the PMN, (3) use of quantitative structure activity relationships (QSARs), and (4) knowledge and judgement of scientific assessors in the interpretation and integration of the information developed in the course of the assessment. This approach to evaluating potential hazards of new chemicals is used to identify those that are most in need of addition review of further testing. It should not be viewed as a replacement for testing. 4 tabs.

  5. Tortuous path chemical preconcentrator (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    more chemical species of interest from a fluid stream that can be rapidly released as a concentrated plug into an analytical or microanalytical chain for separation and detection. ...

  6. Heat Release Rates

    Broader source: Energy.gov [DOE]

    Supporting Technical Document for the Radiological Release Accident Investigation Report (Phase II Report)

  7. Air toxics provisions of the Clean Air Act: Potential impacts on energy

    SciTech Connect (OSTI)

    Hootman, H.A.; Vernet, J.E.

    1991-11-01

    This report provides an overview of the provisions of the Clean Air Act and its Amendments of 1990 that identify hazardous air pollutant (HAP) emissions and addresses their regulation by the US Environmental Protection Agency (EPA). It defines the major energy sector sources of these HAPs that would be affected by the regulations. Attention is focused on regulations that would cover coke oven emissions; chromium emission from industrial cooling towers and the electroplating process; HAP emissions from tank vessels, asbestos-related activities, organic solvent use, and ethylene oxide sterilization; and emissions of air toxics from municipal waste combustors. The possible implications of Title III regulations for the coal, natural gas, petroleum, uranium, and electric utility industries are examined. The report discusses five major databases of HAP emissions: (1) TRI (EPA`s Toxic Release Inventory); (2) PISCES (Power Plant Integrated Systems: Chemical Emissions Studies developed by the Electric Power Research Institute); (3) 1985 Emissions Inventory on volatile organic compounds (used for the National Acid Precipitation Assessment Program); (4) Particulate Matter Species Manual (EPA); and (5) Toxics Emission Inventory (National Aeronautics and Space Administration). It also offers information on emission control technologies for municipal waste combustors.

  8. Air toxics provisions of the Clean Air Act: Potential impacts on energy

    SciTech Connect (OSTI)

    Hootman, H.A.; Vernet, J.E.

    1991-11-01

    This report provides an overview of the provisions of the Clean Air Act and its Amendments of 1990 that identify hazardous air pollutant (HAP) emissions and addresses their regulation by the US Environmental Protection Agency (EPA). It defines the major energy sector sources of these HAPs that would be affected by the regulations. Attention is focused on regulations that would cover coke oven emissions; chromium emission from industrial cooling towers and the electroplating process; HAP emissions from tank vessels, asbestos-related activities, organic solvent use, and ethylene oxide sterilization; and emissions of air toxics from municipal waste combustors. The possible implications of Title III regulations for the coal, natural gas, petroleum, uranium, and electric utility industries are examined. The report discusses five major databases of HAP emissions: (1) TRI (EPA's Toxic Release Inventory); (2) PISCES (Power Plant Integrated Systems: Chemical Emissions Studies developed by the Electric Power Research Institute); (3) 1985 Emissions Inventory on volatile organic compounds (used for the National Acid Precipitation Assessment Program); (4) Particulate Matter Species Manual (EPA); and (5) Toxics Emission Inventory (National Aeronautics and Space Administration). It also offers information on emission control technologies for municipal waste combustors.

  9. Potential Release Sites

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PRS Potential Release Sites Legacy sites where hazardous materials are found to be above acceptable levels are collectively called potential release sites. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Less than 10 percent of the total number of potential release sites need to go through the full corrective action process. What are potential release sites? Potential release sites are areas around the Laboratory and

  10. Apparatus and methods for detecting chemical permeation

    DOE Patents [OSTI]

    Vo-Dinh, T.

    1994-12-27

    Apparatus and methods for detecting the permeation of hazardous or toxic chemicals through protective clothing are disclosed. The hazardous or toxic chemicals of interest do not possess the spectral characteristic of luminescence. The apparatus and methods utilize a spectrochemical modification technique to detect the luminescence quenching of an indicator compound which upon permeation of the chemical through the protective clothing, the indicator is exposed to the chemical, thus indicating chemical permeation. The invention also relates to the fabrication of protective clothing materials. 13 figures.

  11. Results of Toxicity Studies Conducted on Outfall X-08 and Its Contributing Waste Streams, November 1999 - June 2000

    SciTech Connect (OSTI)

    Specht, W.L.

    2000-06-28

    This interim report summarizes the results of toxicity tests, Toxicity Identification Evaluations, and chemical analyses that have been conducted on SRS's NPDES Outfall X-08 and its contributing waste streams between November 1999 and June 2000.

  12. Chemical Engineering

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARPA-E Basic Energy Sciences Materials Sciences and Engineering Chemical Sciences ... SunShot Grand Challenge: Regional Test Centers Chemical Engineering HomeTag:Chemical ...

  13. Preliminary Release: March 28, 2011",,,,,,,,,,,,"Released: April 2013","Released

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,,,,,,,,,,,"Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April

  14. WIPP News Release Archives Index

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WIPP News Release Archives 2006 News Releases 2005 News Releases 2004 News Releases 2003 News Releases 2002 News Releases 2001 News Releases 2000 News Releases 1999 News Releases 1998 News Releases 1997 News Releases 1996 News Releases 1995 News Releases Back to 2007 News Releases If you have any questions regarding the above, contact: Dennis Hurtt, Team Leader Office of Public Affairs DOE, Carlsbad Field Office P.O. Box 3090 Carlsbad, NM 88221-3090 Phone: 505/234-7327 Fax: 505/234-7025 E-mail:

  15. Tortuous path chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P.; Lewis, Patrick R.; Adkins, Douglas R.; Wheeler, David R.; Simonson, Robert J.

    2010-09-21

    A non-planar, tortuous path chemical preconcentrator has a high internal surface area having a heatable sorptive coating that can be used to selectively collect and concentrate one or more chemical species of interest from a fluid stream that can be rapidly released as a concentrated plug into an analytical or microanalytical chain for separation and detection. The non-planar chemical preconcentrator comprises a sorptive support structure having a tortuous flow path. The tortuosity provides repeated twists, turns, and bends to the flow, thereby increasing the interfacial contact between sample fluid stream and the sorptive material. The tortuous path also provides more opportunities for desorption and readsorption of volatile species. Further, the thermal efficiency of the tortuous path chemical preconcentrator is comparable or superior to the prior non-planar chemical preconcentrator. Finally, the tortuosity can be varied in different directions to optimize flow rates during the adsorption and desorption phases of operation of the preconcentrator.

  16. ELECTROMAGNETIC RELEASE MECHANISM

    DOE Patents [OSTI]

    Michelson, C.

    1960-09-13

    An electromagnetic release mechanism is offered that may be used, for example, for supporting a safety rod for a nuclear reactor. The release mechanism is designed to have a large excess holding force and a rapid, uniform, and dependable release. The fast release is accomplished by providing the electromagnet with slotttd polts separated by an insulating potting resin, and by constructing the poles with a ferro-nickel alloy. The combination of these two features materially reduces the eddy current power density whenever the magnetic field changes during a release operation. In addition to these features, the design of the armature is such as to provide ready entrance of fluid into any void that might tend to form during release of the armature. This also improves the release time for the mechanism. The large holding force for the mechanism is accomplished by providing a small, selected, uniform air gap between the inner pole piece and the armature.

  17. Microbial stabilization and mass reduction of wastes containing radionuclides and toxic metals

    DOE Patents [OSTI]

    Francis, Arokiasamy J.; Dodge, Cleveland J.; Gillow, Jeffrey B.

    1991-01-01

    A process is provided to treat wastes containing radionuclides and toxic metals with Clostridium sp. BFGl to release a large fraction of the waste solids into solutin and convert the radionuclides and toxic metals to a more concentrated and stable form with concurrent volume and mass reduction. The radionuclides and toxic metals being in a more stable form are available for recovery, recycling and disposal.

  18. Microbial stabilization and mass reduction of wastes containing radionuclides and toxic metals

    DOE Patents [OSTI]

    Francis, A.J.; Dodge, C.J.; Gillow, J.B.

    1991-09-10

    A process is provided to treat wastes containing radionuclides and toxic metals with Clostridium sp. BFGl to release a large fraction of the waste solids into solution and convert the radionuclides and toxic metals to a more concentrated and stable form with concurrent volume and mass reduction. The radionuclides and toxic metals being in a more stable form are available for recovery, recycling and disposal. 18 figures.

  19. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current News Releases March 20, 2015 - Event News Release #2 WIPP Emergency Operations Center Deactivated March 20, 2015 - Event News Release #1 Emergency Operation Center Activated as Precautionary Measure for Offsite Event November 25, 2014 CBFO and WIPP Volunteerism Helps Little Ones This Winter Karing for Kids Koat Drive November 10, 2014 CBFO and WIPP Commemorations for Veterans Day 2014 Photo 1: Veterans Commeration at Skeen-Whitlock, Nov. 6, 2014 Photo 2: Veterans Commeration at

  20. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    email bland@fnal.gov For Immediate Release Fermilab Colloquium Series Offers Free Public Talks on World Energy Situation Beginning Wednesday, April 13 BATAVIA,...

  1. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sdahl@fnal.gov For Immediate Release Children's Science Adventures at Fermilab Offer Summer Fun - and Learning, Too BATAVIA, Illinois-Summertime is a bright season of...

  2. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    email mikep@fnal.gov For Immediate Release NRELs John Turner Explores The Sustainable Hydrogen Economy in Energy Colloquium Presentation at Fermilab on Wednesday, July 6;...

  3. Press Releases | JCESR

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases New Hybrid Electrolyte for Solid-State Lithium Batteries December 21, 2015 Scientists at the U.S. Department of Energy's Lawrence Berkeley National Laboratory have...

  4. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    26, 1999 For immediate release PRESS ADVISORY: SIGN UP FOR COVERAGE OF MAIN INJECTOR DEDICATION ON TUESDAY, JUNE 1; RICHARDSON, HASTERT TO SPEAK Batavia, Ill.Secretary of...

  5. Audit Manual (Release 8)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deputy Inspector General for Audits and Inspections AUDIT MANUAL Release 8 Revised 2014 Revised 2014 TOC-1 Release 8 OFFICE OF INSPECTOR GENERAL OFFICE OF AUDITS AUDIT MANUAL TABLE OF CONTENTS Page List of Acronyms ...................................................................................................................LOA-1 PART I -- INTRODUCTION CHAPTER 1 -- INTRODUCTION TO THE AUDIT MANUAL A. Purpose of the Audit Manual

  6. Toxic Substances Control Act

    SciTech Connect (OSTI)

    Not Available

    1992-05-15

    This Reference Book contains a current copy of the Toxic Substances Control Act and those regulations that implement the statute and appear to be most relevant to DOE activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. Questions concerning this Reference Book may be directed to Mark Petts, EH-231 (202/586-2609).

  7. News Releases - 2016

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases » News Releases - 2016 News Releases - 2016 We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. August» July» June» May» April» March» February» January» James TenCate James TenCate elected Acoustical Society of America fellow TenCate's research focuses on nonlinear acoustics and elasticity, seismology and nonlinear imaging. - 8/30/16 The thermal traits of a leaf,

  8. DOCUMENT RELEASE FORM C

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RELEASE FORM C (1) Document Number: RPP-RPT-431 74 (2) Revision Number: (3) Effective Date: 9/30/2009 (4) Document Type: El Digital Image El Hard copy (a) Number of pages (including the DRF) or 107 E PDF E] Video number of digital images (5) Release Type 0 New El Cancel El Page Change El complete Revision (6) Document Title: 2009 Auto-TOR for Tank 241 -T-204 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c)

  9. Data Release Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Release Page This page provides links to data (histograms, error matrices, ntuples, etc.) released in association with MINERvA publications. MINERvA Collaboration, L. Aliaga, M. Kordosky, T. Golan et al,"Neutrino Flux Predictions for the NuMI Beam" hep-ex/1607.00704.[Data Release Page] MINERvA Collaboration, Z. Wang, C.M. Marshall et al.,"First Evidence of Coherent Production of K + in Neutrino Interactions on Carbon Nuclei"hep-ex/1606.08890. MINERvA Collaboration, C.M.

  10. Metal toxicity evaluation of Savannah River Plant saltstone comparison of EP and TCLP test results

    SciTech Connect (OSTI)

    Langton, C A

    1988-01-01

    Saltstone is the waste treatment and disposal concept for low-level defense waste at the Savannah River Plant. The waste is a sodium salt solution which has about 230 ..mu..CiL in addition to the hazardous characteristics of corrosivity and metal toxicity (Cr/sup +6/ > 100 ppM). Two EPA test procedures are routinely used at SRP to evaluate metal toxicity of wastes and wasteforms. 1) the Extraction Procedure (EP); and 2) the Toxicity Characterization Leaching Procedure (TCLP). The EP test is required by SCDHEC and EPA. The TCLP is used to evaluate the effect of increased surface area on metal leaching from the various SRP wasteforms. EP and TCLP test results are presented for two types of wasteforms, a cement-based saltstone and for a slag-based saltstone. The slag saltstone chemically stabilizes and also physically entraps the chromium. For waste solutions with low to intermediate metal concentrations (up to 5000 ppM), the TCLP extracts typically have lower metal values than the EP extracts. This is attributed to the faster neutralization of the acetic acid by the crushed TCLP sample. Crushing increases surface area and consequently releases more alkalinity from the wasteform matrix and the wasteform pore solution. Metal concentrations in the EP and TCLP extracts are proportional to the concentrations of metals in the pore solution for both the cement or slag-based wasteforms. The pore solution concentrations for cement wasteforms are directly related to the soluble metal concentration in the waste. The metal concentration in the slag wasteform pore solutions are significantly lower than the waste because these metals are reduced lower valences and precipitated as insoluble solid phases. 3 refs., 3 figs., 5 tabs.

  11. News Releases Feed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 cool science and technology stories from Argonne in 2015 http:www.anl.govarticles10-cool-science-and-technology-stories-argonne-2015 December 23, 2015 News Releases Feed...

  12. FOR IMMEDIATE RELEASE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IMMEDIATE RELEASE Media Contacts: January 23, 2012 Cameron Hardy, DOE , (509) 376-5365, Cameron.Hardy@rl.doe.gov DOE Considers Natural Gas Utility Service Options Proposal Includes...

  13. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    release MiniBooNE opens the box Results from Fermilab experiment resolve long-standing neutrino question BATAVIA, Illinois-Scientists of the MiniBooNE1 experiment at the...

  14. WIPP News Releases - 2006

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Back to current year news releases 2006 News Releases December 12 Idaho National Laboratory Waste Stream Cleared for Shipment to WIPP November 15 WIPP Reaches 4-Million-Hour Safety Milestone October 16 State of New Mexico Issues Permit for Remote-Handled Waste at WIPP September 11 WIPP receives 5,000th shipment March 29 DOE Waste Isolation Pilot Plant Receives EPA Recertification

  15. Nanoscale copper in the soil–plant system – toxicity and underlying potential mechanisms

    SciTech Connect (OSTI)

    Anjum, Naser A.; Adam, Vojtech; Iqbal, Muhammad; Lukatkin, Alexander S.; Ahmad, Iqbal

    2015-04-15

    Nanoscale copper particles (nano-Cu) are used in many antimicrobial formulations and products for their antimicrobial activity. They may enter deliberately and/or accidentally into terrestrial environments including soils. Being the major ‘eco-receptors’ of nanoscale particles in the terrestrial ecosystem, soil–microbiota and plants (the soil–plant system) have been used as a model to dissect the potential impact of these particles on the environmental and human health. In the soil–plant system, the plant can be an indirect non-target organism of the soil-associated nano-Cu that may in turn affect plant-based products and their consumers. By all accounts, information pertaining to nano-Cu toxicity and the underlying potential mechanisms in the soil–plant system remains scanty, deficient and little discussed. Therefore, based on some recent reports from (bio)chemical, molecular and genetic studies of nano-Cu versus soil–plant system, this article: (i) overviews the status, chemistry and toxicity of nano-Cu in soil and plants, (ii) discusses critically the poorly understood potential mechanisms of nano-Cu toxicity and tolerance both in soil–microbiota and plants, and (iii) proposes future research directions. It appears from studies hitherto made that the uncontrolled generation and inefficient metabolism of reactive oxygen species through different reactions are the major factors underpinning the overall nano-Cu consequences in both the systems. However, it is not clear whether the nano-Cu or the ion released from it is the cause of the toxicity. We advocate to intensify the multi-approach studies focused at a complete characterization of the nano-Cu, its toxicity (during life cycles of the least-explored soil–microbiota and plants), and behavior in an environmentally relevant terrestrial exposure setting. Such studies may help to obtain a deeper insight into nano-Cu actions and address adequately the nano-Cu-associated safety concerns in the â

  16. Update On Aquatic Toxicity/Whole Effluent Toxicity (WET) Issues, 2005

    SciTech Connect (OSTI)

    Specht, Winona L

    2005-07-01

    This paper summarizes recent changes in the field of aquatic toxicity/Whole Effluent Toxicity (WET) testing. There are been numerous legal challenges to the validity of WET testing, both at the federal and state levels, but to date, the regulators have prevailed and WET testing is used as a regulatory tool to ensure that the biota of receiving streams are protected. The most recent ruling at the federal level was on December 10, 2004, when a federal appeals court in the District of Columbia upheld the validity of WET testing. At the state level, at the urging of the South Carolina Manufacturers Alliance, the state legislature passed a law (the South Carolina Aquatic Life Protection Act) in 2004 that requires the South Carolina Department of Health and Environmental Control (DHEC) to evaluate the accuracy and precision of the WET test. As a result, SCDHEC removed WET test limits from several NPDES permits. EPA took issue with the impact of the legislation and SCDHEC's actions, and as a result, EPA has taken over several NPDES permits from SCDHEC and threatened to revoke the state's delegated NPDES permit program. A new Act was signed into law in March 2005, which does not exclude the use of chronic toxicity testing for regulatory compliance. As a result, EPA has turned over the issuance of NPDES permits back to SCDHEC. In December 2004, the U.S. EPA issued the Draft National WET Implementation Guidance document for review and comment. The guidance contains recommendations on the determination of ''reasonable potential'' for toxicity. The EPA's ECOTOX database is a valuable resource of toxicity data for many chemicals. For those cases in which there are no toxicity data or very limited data available, the EPA has developed two models, the Interspecies Correlation Estimation (ICE) and the Acute to Chronic Estimation (ACE), for predicting toxicity. Active areas of research include assessing the uptake of heavy metals via multiple routes of exposure, the development of

  17. Chemical Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Science Chemical Science National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place on Earth pursues a broader array of world-class scientific endeavors. Actinide Chemistry» Modeling and Simulation in the Chemical Sciences» Synthetic and Mechanistic Chemistry» Chemistry for Measurement and Detection Science» Chemical Researcher Jeff Pietryga shows two vials of different-size nanocrystals, each

  18. Mass-sensitive chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P.; Adkins, Douglas R.; Lewis, Patrick R.

    2007-01-30

    A microfabricated mass-sensitive chemical preconcentrator actively measures the mass of a sample on an acoustic microbalance during the collection process. The microbalance comprises a chemically sensitive interface for collecting the sample thereon and an acoustic-based physical transducer that provides an electrical output that is proportional to the mass of the collected sample. The acoustic microbalance preferably comprises a pivot plate resonator. A resistive heating element can be disposed on the chemically sensitive interface to rapidly heat and release the collected sample for further analysis. Therefore, the mass-sensitive chemical preconcentrator can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  19. Articles of protective clothing adapted for deflecting chemical permeation and methods therefor

    DOE Patents [OSTI]

    Vo-Dinh, Tuan

    1996-01-01

    Apparatus and methods for detecting the permeation of hazardous or toxic chemicals through protective clothing are disclosed. The hazardous or toxic chemicals of interest do not possess the spectral characteristic of luminescence. The apparatus and methods utilize a spectrochemical modification technique to detect the luminescence quenching of an indicator compound which upon permeation of the chemical through the protective clothing, the indicator is exposed to the chemical, thus indicating chemical permeation.

  20. Articles of protective clothing adapted for deflecting chemical permeation and methods there for

    DOE Patents [OSTI]

    Vo-Dinh, T.

    1996-02-27

    Apparatus and methods for detecting the permeation of hazardous or toxic chemicals through protective clothing are disclosed. The hazardous or toxic chemicals of interest do not possess the spectral characteristic of luminescence. The apparatus and methods utilize a spectrochemical modification technique to detect the luminescence quenching of an indicator compound which upon permeation of the chemical through the protective clothing, the indicator is exposed to the chemical, thus indicating chemical permeation. 12 figs.

  1. Results of acute and chronic toxicity tests conducted at SRS NPDES outfalls, July--October 1991

    SciTech Connect (OSTI)

    Specht, W.L.

    1992-01-01

    Acute (48 hour LC50) and chronic (7-day reproductive impairment) toxicity tests were conducted on Ceriodaphnia dubia in water collected from 53 NPDES outfalls. All tests were conducted at the in-stream waste concentration. only 12 of the 53 outfalls showed no evidence of toxicity. Twenty-eight of the outfalls were acutely toxic, often producing 100% mortality during the first day of exposure. Fourteen outfalls had no discharge at the time of sampling and could not be tested. Three outfalls were not tested because their toxicity has been adequately characterized in other investigations. Elevated concentrations of total residual chlorine are suspected to be responsible for the observed toxicity of many NPDES outfalls, particularly the sanitary wastewater treatment plants. Chemical data from previous studies indicate that metals may also be present in toxic concentrations at many outfalls. Toxicity identification and reduction options are discussed.

  2. Release Resistant Electrical Interconnections For Mems Devices

    DOE Patents [OSTI]

    Peterson, Kenneth A.; Garrett, Stephen E.; Reber, Cathleen A.

    2005-02-22

    A release resistant electrical interconnection comprising a gold-based electrical conductor compression bonded directly to a highly-doped polysilicon bonding pad in a MEMS, IMEMS, or MOEMS device, without using any intermediate layers of aluminum, titanium, solder, or conductive adhesive disposed in-between the conductor and polysilicon pad. After the initial compression bond has been formed, subsequent heat treatment of the joint above 363 C creates a liquid eutectic phase at the bondline comprising gold plus approximately 3 wt % silicon, which, upon re-solidification, significantly improves the bond strength by reforming and enhancing the initial bond. This type of electrical interconnection is resistant to chemical attack from acids used for releasing MEMS elements (HF, HCL), thereby enabling the use of a "package-first, release-second" sequence for fabricating MEMS devices. Likewise, the bond strength of an Au--Ge compression bond may be increased by forming a transient liquid eutectic phase comprising Au-12 wt % Ge.

  3. Chemical Recycling | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Recycling Chemical Recycling

  4. Developing health-based pre-planning clearance goals for airport remediation following a chemical terrorist attack: Decision criteria for multipathway exposure routes

    SciTech Connect (OSTI)

    Watson, Annetta Paule; Dolislager, Frederick; Hall, Dr. Linda; Hauschild, Veronique; Raber, Ellen; Love, Dr. Adam

    2011-01-01

    In the event of a chemical terrorist attack on a transportation hub, post-event remediation and restoration activities necessary to attain unrestricted facility re-use and re-entry could require hours to multiple days. While timeframes are dependent on numerous variables, a primary controlling factor is the level of pre-planning and decision-making completed prior to chemical release. What follows is the second of a two-part analysis identifying key considerations, critical information and decision criteria to facilitate post-attack and post-decontamination consequence management activities. Decision criteria analysis presented here provides first-time, open-literature documentation of multi-pathway, health-based remediation exposure guidelines for selected toxic industrial compounds, chemical warfare agents, and agent degradation products for pre-planning application in anticipation of a chemical terrorist attack. Guideline values are provided for inhalation and direct ocular vapor exposure routes as well as percutaneous vapor, surface contact, and ingestion. Target populations include various employees as well as transit passengers. This work has been performed as a national case study conducted in partnership with the Los Angeles International Airport and The Bradley International Terminal. All recommended guidelines have been selected for consistency with airport scenario release parameters of a one-time, short-duration, finite airborne release from a single source followed by compound-specific decontamination.

  5. Developing health-based pre-planning clearance goals for airport remediation following chemical terrorist attack: Introduction and key assessment considerations

    SciTech Connect (OSTI)

    Watson, Annetta Paule; Raber, Ellen; Dolislager, Frederick; Hauschild, Veronique; Hall, Dr. Linda; Love, Dr. Adam

    2011-01-01

    In the event of a chemical terrorist attack on a transportation hub, post-event remediation and restoration activities necessary to attain unrestricted facility re-use and re-entry could require hours to multiple days. While restoration timeframes are dependent on numerous variables, a primary controlling factor is the level of pre-planning and decision-making completed prior to chemical terrorist release. What follows is the first of a two-part analysis identifying key considerations, critical information, and decision criteria to facilitate post-attack and post-decontamination consequence management activities. A conceptual site model and human health-based exposure guidelines are developed and reported as an aid to site-specific pre-planning in the current absence of U.S. state or Federal values designated as compound-specific remediation or re-entry concentrations, and to safely expedite facility recovery to full operational status. Chemicals of concern include chemical warfare nerve and vesicant agents and the toxic industrial compounds phosgene, hydrogen cyanide, and cyanogen chloride. This work has been performed as a national case study conducted in partnership with the Los Angeles International Airport and The Bradley International Terminal. All recommended guidelines have been selected for consistency with airport scenario release parameters of a one-time, short-duration, finite airborne release from a single source followed by compound-specific decontamination.

  6. National toxicology program chemical nomination and selection process

    SciTech Connect (OSTI)

    Selkirk, J.K.

    1990-12-31

    The National Toxicology Program (NTP) was organized to support national public health programs by initiating research designed to understand the physiological, metabolic, and genetic basis for chemical toxicity. The primary mandated responsibilities of NTP were in vivo and vitro toxicity testing of potentially hazardous chemicals; broadening the spectrum of toxicological information on known hazardous chemicals; validating current toxicological assay systems as well as developing new and innovative toxicity testing technology; and rapidly communicating test results to government agencies with regulatory responsibilities and to the medical and scientific communities. 2 figs.

  7. Altitude release mechanism

    DOE Patents [OSTI]

    Kulhanek, Frank C.

    1977-01-01

    An altitude release mechanism for releasing a radiosonde or other measuring instrument from a balloon carrying it up into the atmosphere includes a bottle partially filled with water, a tube sealed into the bottle having one end submerged in the water in the bottle and the free end extending above the top of the bottle and a strip of water-disintegrable paper held within the free end of the tube linking the balloon to the remainder of the package. As the balloon ascends, the lowered atmospheric air pressure causes the air in the bottle to expand, forcing the water in the bottle up the tubing to wet and disintegrate the paper, releasing the package from the balloon.

  8. Survey and discussion of models applicable to the transport and fate thrust area of the Department of Energy Chemical and Biological Nonproliferation Program

    SciTech Connect (OSTI)

    1997-09-01

    The availability and easy production of toxic chemical and biological agents by domestic and international terrorists pose a serious threat to US national security, especially to civilian populations in and around urban areas. To address this threat, the Department of Energy (DOE) has established the Chemical and Biological Nonproliferation Program (CBNP) with the goal of focusing the DOE`s technical resources and expertise on capabilities to deny, deter, mitigate and respond to clandestine releases of chemical and biological agents. With the intent to build on DOE core competencies, the DOE has established six technology thrust areas within the CBNP Program: Biological Information Resources; Point Sensor Systems; Stand-off Detection; Transport and Fate; Decontamination; and Systems Analysis and Integration. The purpose of the Transport and Fate Thrust is to accurately predict the dispersion, concentration and ultimate fate of chemical and biological agents released into the urban and suburban environments and has two major goals: (1) to develop an integrated and validated state-of-the-art atmospheric transport and fate modeling capability for chemical and biological agent releases within the complex urban environment from the regional scale down to building and subway interiors, and (2) to apply this modeling capability in a broad range of simulation case studies of chemical and biological agent release scenarios in suburban, urban and confined (buildings and subways) environments and provide analysis for the incident response user community. Sections of this report discuss subway transport and fate models; buildings interior transport and fate modeling; models for flow and transport around buildings; and local-regional meteorology and dispersion models.

  9. How toxic is coal ash? A laboratory toxicity case study

    SciTech Connect (OSTI)

    Sherrard, Rick M.; Carriker, Neil; Greeley, Jr., Mark Stephen

    2014-12-08

    Under a consent agreement among the Environmental Protection Agency (EPA) and proponents both for and against stricter regulation, EPA is to issue a new coal ash disposal rule by the end of 2014. Laboratory toxicity investigations often yield conservative estimates of toxicity because many standard test species are more sensitive than resident species, thus could provide information useful to the rule-making. However, few laboratory studies of coal ash toxicity are available; most studies reported in the literature are based solely on field investigations. In this paper, we describe a broad range of toxicity studies conducted for the Tennessee Valley Authority (TVA) Kingston ash spill, results of which help provide additional perspective on the toxicity of coal ash.

  10. How toxic is coal ash? A laboratory toxicity case study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sherrard, Rick M.; Carriker, Neil; Greeley, Jr., Mark Stephen

    2014-12-08

    Under a consent agreement among the Environmental Protection Agency (EPA) and proponents both for and against stricter regulation, EPA is to issue a new coal ash disposal rule by the end of 2014. Laboratory toxicity investigations often yield conservative estimates of toxicity because many standard test species are more sensitive than resident species, thus could provide information useful to the rule-making. However, few laboratory studies of coal ash toxicity are available; most studies reported in the literature are based solely on field investigations. In this paper, we describe a broad range of toxicity studies conducted for the Tennessee Valley Authoritymore » (TVA) Kingston ash spill, results of which help provide additional perspective on the toxicity of coal ash.« less

  11. Chemically-functionalized microcantilevers for detection of chemical, biological and explosive material

    SciTech Connect (OSTI)

    Pinnaduwage, Lal A; Thundat, Thomas G; Brown, Gilbert M; Hawk, John Eric; Boiadjiev, Vassil I

    2007-04-24

    A chemically functionalized cantilever system has a cantilever coated on one side thereof with a reagent or biological species which binds to an analyte. The system is of particular value when the analyte is a toxic chemical biological warfare agent or an explosive.

  12. DOCUMENT RELEASE FORM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 (2) Revision Number: 0 (3) Effective Date: 9/28/2009 (4) Document Type: [] Digital Image El Hard copy (a) Number of pages (including the DRF) or 74 0PDF E] Video number of digital images (5) Release Type E New El cancel l Page Change El complete Revision (6) Document Title: 2009 Auto-TCR for Tank 241-13-204 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c) Building Number: Structure, System, and Component N/A

  13. DOCUMENT RELEASE FORM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    31 97 (2) Revision Number: 0 -- (3) Effective Date: 9/30/2009 (4) Document Type: E] Digital Image l Hard copy (a) Number of pages (including the DRF) or 84 0 POE E Video number of digital images (5) Release Type Z New 1:1 Cancel liiPage Change Elcomplete Revision (6) Document Title: 2009 Auto-TOR for Tank 241 -TY-1 05 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure Location: (c) Building Number: Structure, System, and

  14. ARM - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases Related Links TWP-ICE Home Tropical Western Pacific Home ARM Data Discovery Browse Data Post-Experiment Data Sets Weather Summary (pdf, 6M) New York Workshop Presentations Experiment Planning TWP-ICE Proposal Abstract Detailed Experiment Description Science Plan (pdf, 1M) Operations Plan (pdf, 321K) Maps Contact Info Related Links Daily Report Report Archives Press Media Coverage TWP-ICE Fact Sheet (pdf, 211K) Press Releases TWP-ICE Images ARM flickr site <=""

  15. Chemical microsensors

    DOE Patents [OSTI]

    Li, DeQuan; Swanson, Basil I.

    1995-01-01

    An article of manufacture is provided including a substrate having an oxide surface layer and a selective thin film of a cyclodextrin derivative chemically bound upon said substrate, said film is adapted for the inclusion of a selected organic compound therewith. Such an article can be either a chemical sensor capable of detecting a resultant mass change from inclusion of the selected organic compound or a chemical separator capable of reversibly selectively separating a selected organic compound.

  16. Non-planar chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P.; Adkins, Douglas R.; Sokolowski, Sara S.; Lewis, Patrick R.

    2006-10-10

    A non-planar chemical preconcentrator comprises a high-surface area, low mass, three-dimensional, flow-through sorption support structure that can be coated or packed with a sorptive material. The sorptive material can collect and concentrate a chemical analyte from a fluid stream and rapidly release it as a very narrow temporal plug for improved separations in a microanalytical system. The non-planar chemical preconcentrator retains most of the thermal and fabrication benefits of a planar preconcentrator, but has improved ruggedness and uptake, while reducing sorptive coating concerns and extending the range of collectible analytes.

  17. Canadian Environmental Protection Act, strategic options for the management of toxic substances: Electric power generation (fossil fuel) sector, report of stakeholder consultations

    SciTech Connect (OSTI)

    1997-12-31

    The Electric Power Generation Sector Issue Table was formed to assess the management of toxic substances released from that sector, and more specifically, to develop (where warranted) goals, targets, and effective and efficient options for managing toxic releases in order to reduce potential risks to human health and the environment. This strategic options report sets out the recommendations of Issue Table members for the management of toxic substances. The introduction includes an industry profile and a review of the provincial management of electric power sector strategic options priority (SOP) substances. Chapter 2 discusses what substances are toxic, estimates releases of SOP substances from the sector, and reviews Issue Table approaches to risk assessment. Chapter 3 outlines Issue Table activities. Chapter 4 screens toxic substance management options, with evaluation of options against 13 groups of criteria. Chapter 5 presents toxic substances management proposals made to the Issue Table by the electric power generation industry, environmental groups, and Environment Canada.

  18. STEP Utility Data Release Form

    Broader source: Energy.gov [DOE]

    STEP Utility Data Release Form, from the Tool Kit Framework: Small Town University Energy Program (STEP).

  19. WIPP News Releases - 2002

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases September 30 Westinghouse Earns Mine Safety Award for 16th Consecutive Year July 9 Westinghouse TRU Solutions LLC Earns Corporate Award For Air Monitoring Initiative April 12 WIPP Receives Waste Characterized With Mobile System February 12 Ava Holland Joins DOE Carlsbad Field Office As Quality Assurance Manager January 7 WIPP Receives 500th Waste Shipment

  20. Acute toxicity of selected metals and phenols on RTG-2 and CHSE-214 fish cell lines

    SciTech Connect (OSTI)

    Castano, A. |; Vega, M.M.; Tarazona, J.V.

    1995-08-01

    In vitro toxicity tests with fish cell lines appear as an alternative to single species bioassays and have been used successfully in different applications, both for single chemicals and for environmental samples, including Toxicity Identification Evaluation procedures. Different fish cell lines, such as BF-2, RTG-2, FHM and R1 have been employed in these toxicological studies. The aim of the present study was to compare the sensitivity of two salmonid fish cell lines, RTG-2 and CHSE-214, in evaluating toxicity of seven compounds (three metals and four phenolic chemicals), by measuring three endpoints: cellular mass, cell viability and intracellular ATP content of the cells. 22 refs., 3 figs., 1 tab.

  1. Chemical sensors

    DOE Patents [OSTI]

    Lowell, J.R. Jr.; Edlund, D.J.; Friesen, D.T.; Rayfield, G.W.

    1991-07-02

    Sensors responsive to small changes in the concentration of chemical species are disclosed. The sensors comprise a mechanochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment. They are operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical response. 9 figures.

  2. Chemical sensors

    DOE Patents [OSTI]

    Lowell, Jr., James R.; Edlund, David J.; Friesen, Dwayne T.; Rayfield, George W.

    1991-01-01

    Sensors responsive to small changes in the concentration of chemical species are disclosed, comprising (a) a mechanochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment, operatively coupled to (b) a transducer capable of directly converting said expansion or contraction to a measurable electrical response.

  3. Chemical Processing Qualification Standard

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6-2010 February 2010 DOE STANDARD CHEMICAL PROCESSING QUALIFICATION STANDARD DOE Defense Nuclear Facilities Technical Personnel U.S. Department of Energy AREA TRNG Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. DOE-STD-1176-2010 ii This document is available on the Department of Energy Technical Standards Program Web Site at http://www.hss.energy.gov/nuclearsafety/ns/techstds DOE-STD-1176-2010 iv INTENTIONALLY BLANK DOE-STD-1176-2010 v

  4. Joint DOE-CH2M News Release Media Contact: For Immediate Release:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Joint DOE-CH2M News Release Media Contact: For Immediate Release: Destry Henderson, CH2M, (509) 376-8644, April 20, 2015 destry_j_henderson@rl.gov Mark Heeter, DOE, (509)373-1970, mark.heeter@rl.doe.gov WORKERS REMOVE LAST PENCIL TANK FROM KEY AREA OF HANFORD'S PLUTONIUM FINISHING PLANT Removal of contaminated pencil tanks brings facility one step closer toward demolition RICHLAND, Wash. - More than 50 pencil tank assemblies - some two stories tall - contaminated with chemical and radiological

  5. Chemical Safety Vulnerability Working Group report. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The Chemical Safety Vulnerability (CSV) Working Group was established to identify adverse conditions involving hazardous chemicals at DOE facilities that might result in fires or explosions, release of hazardous chemicals to the environment, or exposure of workers or the public to chemicals. A CSV Review was conducted in 148 facilities at 29 sites. Eight generic vulnerabilities were documented related to: abandoned chemicals and chemical residuals; past chemical spills and ground releases; characterization of legacy chemicals and wastes; disposition of legacy chemicals; storage facilities and conditions; condition of facilities and support systems; unanalyzed and unaddressed hazards; and inventory control and tracking. Weaknesses in five programmatic areas were also identified related to: management commitment and planning; chemical safety management programs; aging facilities that continue to operate; nonoperating facilities awaiting deactivation; and resource allocations. Volume 1 contains the Executive summary; Introduction; Summary of vulnerabilities; Management systems weaknesses; Commendable practices; Summary of management response plan; Conclusions; and a Glossary of chemical terms.

  6. Experiments and Modeling of High Altitude Chemical Agent Release

    SciTech Connect (OSTI)

    Nakafuji, G.; Greenman, R.; Theofanous, T.

    2002-07-08

    Using ASCA data, we find, contrary to other researchers using ROSAT data, that the X-ray spectra of the VY Scl stars TT Ari and KR Aur are poorly fit by an absorbed blackbody model but are well fit by an absorbed thermal plasma model. The different conclusions about the nature of the X-ray spectrum of KR Aur may be due to differences in the accretion rate, since this Star was in a high optical state during the ROSAT observation, but in an intermediate optical state during the ASCA observation. TT Ari, on the other hand, was in a high optical state during both observations, so directly contradicts the hypothesis that the X-ray spectra of VY Sol stars in their high optical states are blackbodies. Instead, based on theoretical expectations and the ASCA, Chandra, and XMM spectra of other nonmagnetic cataclysmic variables, we believe that the X-ray spectra of VY Sol stars in their low and high optical states are due to hot thermal plasma in the boundary layer between the accretion disk and the surface of the white dwarf, and appeal to the acquisition of Chandra and XMM grating spectra to test this prediction.

  7. On-Line Microbial Whole Effluent Toxicity Monitoring for Industrial Wastewater

    SciTech Connect (OSTI)

    Mathews, S; Hoppes, W; Mascetti, M; Campbell, C G

    2002-09-17

    In this study a respirometer is tested for its ability to act as an early upset warning device and whole effluent toxicity monitor for industrial discharge. Industrial discharge water quality is commonly evaluated by comparing measured chemical concentrations to target values or regulatory limits established by governmental agencies. Unless the regulatory values are based upon empirical data, the actual effect of the discharge on aquatic systems is unknown. At the same time assessing the environmental toxicology of wastewater discharges is complicated by synergistic relationships among chemical constituents producing greater total toxicity. For example, metals may be more toxic in waters with low total hardness or more soluble at lower pH. An alternative approach that we are investigating is whole effluent toxicity testing. This study investigates the measurement of whole effluent toxicity through an on-line respirometer that measures toxicity to microorganisms comprising activated sludge. In this approach the oxygen uptake rate is monitored and used as an indicator of microbial activity or health. This study investigates the use of an online whole effluent toxicity testing system to provide early upset warning and the consistency of measured response to low pH. Repeated exposure of the microorganisms to low pH results in reduced sensitivity of the microbial population. We investigate whether this reduction in sensitivity results from physiological acclimation or changes in species composition. We identify promising applications, where, with proper calibration, respirometry based toxicity monitoring appear to be well suited for relative comparisons of whole effluent toxicity.

  8. Toxicity of Uranium Adsorbent Materials using the Microtox Toxicity Test

    SciTech Connect (OSTI)

    Park, Jiyeon; Jeters, Robert T.; Gill, Gary A.; Kuo, Li-Jung; Bonheyo, George T.

    2015-10-01

    The Marine Sciences Laboratory at the Pacific Northwest National Laboratory evaluated the toxicity of a diverse range of natural and synthetic materials used to extract uranium from seawater. The uranium adsorbent materials are being developed as part of the U. S. Department of Energy, Office of Nuclear Energy, Fuel Resources Program. The goal of this effort was to identify whether deployment of a farm of these materials into the marine environment would have any toxic effects on marine organisms.

  9. Chemical and biological warfare: Biology, chemistry, and toxicology. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-10-01

    The bibliography contains citations concerning the physiological effects, physicochemical effects, and toxicology of chemical and biological warfare agents. Citations discuss toxic chemicals, chemical agent simulants, detoxification and decontamination, environmental toxicity, and land pollution. Detection techniques and warning systems are examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  10. Chemical and biological warfare: Biology, chemistry, and toxicology. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-10-01

    The bibliography contains citations concerning the physiological effects, physicochemical effects, and toxicology of chemical and biological warfare agents. Citations discuss toxic chemicals, chemical agent simulants, detoxification and decontamination, environmental toxicity, and land pollution. Detection techniques and warning systems are examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  11. Chemical and biological warfare: Biology, chemistry, and toxicology. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-03-01

    The bibliography contains citations concerning the physiological effects, physicochemical effects, and toxicology of chemical and biological warfare agents. Citations discuss toxic chemicals, chemical agent simulants, detoxification and decontamination, environmental toxicity, and land pollution. Detection techniques and warning systems are examined in a separate bibliography. (Contains a minimum of 229 citations and includes a subject term index and title list.)

  12. Chemical and biological warfare: Biology, chemistry, and toxicology. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1997-11-01

    The bibliography contains citations concerning the physiological effects, physicochemical effects, and toxicology of chemical and biological warfare agents. Citations discuss toxic chemicals, chemical agent simulants, detoxification and decontamination, environmental toxicity, and land pollution. Detection techniques and warning systems are examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  13. Press Pass - Press Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1-28 November 7, 2001 For immediate release Press contact: Judy Jackson (630-840-3351; jjackson@fnal.gov High resolution graphics at www.fnal.gov/pub/presspass/images/NuTev_images.html Neutrino Measurement Surprises Fermilab Physicists Batavia, Ill.-Scientists at the Department of Energy's Fermi National Accelerator Laboratory have found a surprising discrepancy between predictions for the behavior of neutrinos and the way the subatomic particles actually behave. Although the difference is tiny,

  14. Cryogenic hydrogen release research.

    SciTech Connect (OSTI)

    LaFleur, Angela Christine

    2015-12-01

    The objective of this project was to devolop a plan for modifying the Turbulent Combustion Laboratory (TCL) with the necessary infrastructure to produce a cold (near liquid temperature) hydrogen jet. The necessary infrastructure has been specified and laboratory modifications are currently underway. Once complete, experiments from this platform will be used to develop and validate models that inform codes and standards which specify protection criteria for unintended releases from liquid hydrogen storage, transport, and delivery infrastructure.

  15. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 News Releases December 1 State Renews WIPP Facility Permit November 18 National TRU Program Director Selected November 18 Waste Isolation Pilot Plant Receives Second EPA Recertification October 7 WIPP Receives 9,000th Shipment September 7 Carlsbad Field Office Manager Transition July 2 DOE Awards Technical Assistance Contract for Carlsbad Field Office June 14 WIPP Completes California Sites Cleanup May 3 DOE Extends Management and Operations Contract at Waste Isolation Pilot Plant May 3 DOE

  16. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 News Releases December 21 WIPP Receives First Remote-Handled Waste Shipment From Sandia Labs December 13 Carlsbad Field Office Recognized by New Mexico and DOE for Environmental Excellence at WIPP Click on photo below for larger image. November 10 Carlsbad Field Office Manager Selected November 9 WIPP Receives Top Safety Award November 9 Photos of New WIPP Transportation Exhibit's Debut at the National Museum of Nuclear Science and History Click on photos below for larger images. November 2

  17. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases October 29 WIPP Environmental Initiatives Earn DOE Recognition Click on photo below for larger image. October 24 WIPP Security Contractor Receives DOE Voluntary Protection Program Award Click on photo below for larger image. October 17 WIPP Employees Among Honorees for Nuclear Footprint Reduction October 3 DOE Exceeds 2012 TRU Waste Cleanup Goal at Los Alamos National Laboratory September 19 DOE Awards Grant to New Mexico Environment Department for Waste Isolation Pilot Plant

  18. WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases December 18 CBFO Selects Quality Assurance Director Click on photo below for larger image. December 2 Carlsbad Field Office Deputy Manager Selected Click on photo below for larger image. September 20 WIPP Management and Operating Contractor Recognized for Continuous Safety Performance Click on photo below for larger image. September 18 WIPP Receives Top Mine Safety Award September 18 WIPP Honored for Sustainability August 2 WIPP Employee Inducted Into Mine Rescue Hall of Fame -

  19. WIPP News Releases - 2003

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases December 18 50,000 Containers Safety Disposed at WIPP August 14 Drum Involved in Idaho Incident Not Shippable to WIPP July 31 Marchetti New CEO of Washington TRU Solutions March 25 HUBZone, Great Opportunity for Small Businesses February 18 TRU Solutions Announces $20,500 in Scholarships For Eddy and Lea County Students January 14 Washington TRU Solutions LLC Announces New Name and New General Manager

  20. WIPP News Releases - 2005

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases December 27 Empty WIPP truck overturns December 12 Dr. Dave Moody to Lead the Carlsbad Field Office December 7 WIPP Satellite Tracking System Relocates to Carlsbad November 23 Statement of Vernon Daub, Acting Manager of DOE's Carlsbad Field Office, Regarding New Mexico Environment Department's Issuance of a Draft Hazardous Waste Facility Permit for WIPP October 7 DOE Awards WIPP Independent Oversight Contract August 11 DOE Awards Technical Assistance Contract to Support Carlsbad

  1. 1995 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search NREL Funding Reductions to Further Impact Lab's Work Force (12/22/95) World Renewable Energy Congress To Be Held In Denver In 1996 (12/18/95) NREL Researchers Use Sunlight to Power Laser (12/14/95) National Renewable Energy Laboratory To Reduce Staff (11/3/95)

  2. 1998 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Popular Science Recognizes Innovative Solar Technologies - (12/16/98) Kazmerski Leads National Center for Solar Research - (12/1/98) MRI, Battelle and Bechtel to Manage National Renewable Energy Lab - (11/19/98) Prestigious Council to Advise National Renewable Energy Lab - (11/19/98) Tour Opens Doors, Minds to Solar Energy - (10/5/98) MRI, Battelle, Bechtel Team Wins National

  3. 2002 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Director of National Bioenergy Center Named - (12/12/02) Scientific American' Recognizes Solar Cell Research - (11/11/02) UPS Fleet Study Quantifies the Reliability, Low Emissions of CNG Trucks - (10/29/02) Energy Department Honors Solar Decathlon Winners - (10/05/02) Winner of Solar Decathlon to be Announced - (10/04/02) Solar Decathlon Engineering Design Results Announced -

  4. 2003 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 22, 2003 Renewable Energy a Smart Choice for Farmers and Ranchers December 10, 2003 Georgia Tech's Rohatgi Wins Second Annual Rappaport Award December 9, 2003 Acclaim for Three Leaders at Annual NREL Stakeholders Reception November 14, 2003 World Renewable Energy Congress Provides International Forum November 12, 2003 NREL and Company Researchers Team Up

  5. 2004 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 21, 2004 NREL Recognizes Solar Pioneer with National Honor November 23, 2004 NREL Recognizes Solar Pioneer with National Honor November 17, 2004 Basalt Middle School Teacher Recognized for Renewable Energy Efforts October 5, 2004 NREL Theorist Recognized for Highest Citation Impact September 24, 2004 NREL Selects Contractor for New Science & Technology

  6. 2005 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search November 17, 2005 Lakewood High School Teacher Recognized for Introduction of Renewable Energy Curriculum Students taking technology classes at Lakewood High School this semester are learning about more than construction, technical theater and computer aided drafting (CAD); they are learning about energy issues within their community. October 31, 2005 Agreement

  7. 2006 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 14, 2006 Experimental "Wind to Hydrogen" System Up and Running Xcel Energy and the National Renewable Energy Laboratory unveiled a unique facility that uses electricity from wind turbines to produce and store pure hydrogen. November 28, 2006 University of Denver High School Teacher Recognized for Commitment to Renewable Energy Don Cameron,

  8. 2007 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 4, 2007 Energy Lab Sets Aggressive Greenhouse Gas Reduction Goal The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) has pledged to reduce its greenhouse gas emissions by 75 percent from 2005 to 2009. The new goal is part of NREL's participation in the Environmental Protection Agency's (EPA) Climate Leaders program. November 8, 2007

  9. 2010 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 17, 2010 NREL Employees Significantly Increase Their Community Support For the second year in a row, employees of the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) pledged significantly more to community organizations during its annual charitable giving campaign this holiday season. December 2, 2010 Scientists Generate Two

  10. 2011 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 20, 2011 NREL Licenses Technology to Increase Solar Cell Efficiency The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) announced today that Natcore Technology Inc. has been granted a patent license agreement to develop a line of black silicon products. December 15, 2011 NREL Scientists Report First Solar Cell Producing More

  11. 2012 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 21, 2012 NREL Names New Executive The U.S. Department of Energy's National Renewable Energy Laboratory today named Barbara Goodman as Associate Laboratory Director for Renewable Fuels and Vehicle Systems to replace Dale Gardner who is retiring at the end of the year. December 20, 2012 Concentrated Solar Power with Thermal Energy Storage Can Help Utilities'

  12. 2013 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 12, 2013 NREL Seeks Leaders for National Executive Energy Academy The Energy Department's National Renewable Energy Laboratory (NREL) is accepting applications for its 2014 Executive Energy Leadership Academy. NREL's Executive Energy Leadership Academy, also known as Energy Execs, is a program for non-technical decision-makers throughout the country to

  13. SRNL EMERGENCY RESPONSE CAPABILITY FOR ATMOSPHERIC CONTAMINANT RELEASES

    SciTech Connect (OSTI)

    Koffman, L; Chuck Hunter, C; Robert Buckley, R; Robert Addis, R

    2006-07-12

    Emergency response to an atmospheric release of chemical or radiological contamination is enhanced when plume predictions, field measurements, and real-time weather information are integrated into a geospatial framework. The Weather Information and Display (WIND) System at Savannah River National Laboratory (SRNL) utilizes such an integrated framework. The rapid availability of predictions from a suite of atmospheric transport models within this geospatial framework has proven to be of great value to decision makers during an emergency involving an atmospheric contaminant release.

  14. California Environmental Protection Agency Department of Toxic...

    Open Energy Info (EERE)

    Department of Toxic Substances Control Jump to: navigation, search Name: California Environmental Protection Agency Department of Toxic Substances Control Place: Sacramento,...

  15. Media Release Media Contact FOR IMMEDIATE RELEASE Heather Rasmussen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Media Release Media Contact FOR IMMEDIATE RELEASE Heather Rasmussen September 22, 2011 Communication Specialist (801) 819-7623 hrasmussen@wecc.biz WECC releases its first-ever transmission plan for the Western Interconnection The Western Electricity Coordinating Council (WECC) announced the release of its first 10-Year Regional Transmission Plan (Plan) for the Western Interconnection. Looking ahead to 2020, the Plan focuses on how to meet the Western Interconnection's transmission requirements;

  16. Chemical sensors

    DOE Patents [OSTI]

    Lowell, J.R. Jr.; Edlund, D.J.; Friesen, D.T.; Rayfield, G.W.

    1992-06-09

    Sensors responsive to small changes in the concentration of chemical species are disclosed, comprising a mechanicochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment, either operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical or optical response, or adhered to a second inert polymeric strip, or doped with a conductive material. 12 figs.

  17. Chemical sensors

    DOE Patents [OSTI]

    Lowell, Jr., James R.; Edlund, David J.; Friesen, Dwayne T.; Rayfield, George W.

    1992-01-01

    Sensors responsive to small changes in the concentration of chemical species are disclosed, comprising a mechanicochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment, either operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical or optical response, or adhered to a second inert polymeric strip, or doped with a conductive material.

  18. Chemical Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Science Chemical Science Plant fatty acids are used in a vast range of products, from polymers to plastics and soaps to industrial feed stocks -- making up an estimated $150 billion market annually. A new discovery of inserting double bonds in the fatty acids could show the way to the designer production of plant fatty acids, and, in turn, to new industrial applications and new products. <a href

  19. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  20. WIPP News Releases - 1995

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 News Releases Westinghouse WID Earns DOE Quality Award - 11/08/95 DOE Accelerates WIPP Schedule - 10/20/95 WIPP Celebrates National Quality Month - 10/13/95 Assistant DOE Secretary Transfers WIPP Technology - 10/10/95 DOE Extends EIS Public Comment Period - 10/06/95 DOE Closes Underground Experimental Area - 09/28/95 SEIS Meetings Held For WIPP - 09/12/95 Lee Named Deputy GM For Westinghouse WID - 08/25/95 WIPP Transportation System At Trade Show - 07/11/95 Technology Transfer - 07/07/95

  1. WIPP News Releases - 1996

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 News Releases DOE to Hold Public Hearings Next Week in Albuquerque on WIPP SEIS - 12/31/96 DOE to Hold Public Hearings Next Week in Santa Fe on WIPP SEIS - 12/31/96 DOE Announces North Augusta Public Hearing for WIPP SEIS - 12/17/96 DOE Announces Denver Area Public Hearing for WIPP SEIS - 12/17/96 DOE Announces Richland Public Hearing for WIPP SEIS - 12/17/96 DOE Announces Santa Fe Public Hearings for WIPP SEIS - 12/17/96 DOE Announces Boise Public Hearing for WIPP SEIS - 12/17/96 DOE

  2. FOR IMMEDIATE RELEASE CIV

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    _ FOR IMMEDIATE RELEASE CIV FRIDAY, AUGUST 21, 2015 (202) 514-2007 WWW.JUSTICE.GOV TTY (866) 544-5309 SANDIA CORPORATION AGREES TO PAY $4.7 MILLION TO RESOLVE ALLEGATIONS RELATED TO LOBBYING ACTIVITIES WASHINGTON - The Justice Department announced today that Sandia Corporation has agreed to pay $4,790,042 to resolve allegations that Sandia violated the Byrd Amendment and the False Claims Act by using federal funds for activities related to lobbying Congress and federal agencies to obtain a

  3. WIPP News Releases - 2004

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 News Releases November 4 Detwiler Resumes Position at DOE Headquarters October 14 WIPP Mine Rescue Team First in Missouri October 12 DOE Announces WIPP Contract Negotiations October 6 Washington TRU Solutions is Mine Operator of the Year September 28 Washington Group International Named Tops in Safety July 24 No Damage to WIPP Cargo in Roswell Traffic Accident July 22 WIPP Mine Rescue Team Wins "Overall Contest" at Nationals July 2 DOE Prevails in WIPP Court Case July 1 $1M to Fund

  4. Manhattan Project app released

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    » Manhattan Project app released At the Bradbury Latest Issue:September 2016 all issues All Issues » submit Manhattan Project app available NOW! Downloadable through iTunes June 1, 2016 The opening graphic of the Los Alamos: Secret City of the Manhattan Project app Los Alamos: Secret City of the Manhattan Project is available through iTunes for free! We let you know about it. We provided a short video so you could get a feel for what the Los Alamos: Secret City of the Manhattan Project app is

  5. Pion Production Data Release

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pion Production Data Release This page gives the updated results for three different MINERvA Publications: Cross sections for neutrino and antineutrino induced pion production on hydrocarbon in the few-GeV region using MINERvA hep-ex/1606.07127 and Single neutral pion production by charged current antinu interactions on plastic scintillator at Enu ∼ 4 GeV hep-ex/1503.02107 and Charged Pion Production from CH in a Neutrino Beam hep-ex/1406.6415 Data Ancillary files for this result are available

  6. 1996 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Companies Selected for Small Wind Turbine Project - (11/27/96) DOE Forms National Center for Photovoltaics - (11/19/96) The Brightest in Solar Homes to Shine in Public Tour - (10/4/96) New NREL Research Facility Slashes Energy Use by 66 Percent - (10/3/96) Agreement Moves Nevada Solar Plant Step Closer to Reality - (10/3/96) Would-Be Solar Electric Homeowners Sought For

  7. 1997 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Local Middle School Receives School-to-Career Grant - (12/24/97) Free Consumer Workshops On Solar & Wind Power For Farm & Ranch At National Western Stock Show - (12/9/97) NREL Funds Research into Low-Cost Solar Electricity - (12/8/97) NREL Provides PV Holiday Lights for Christmas Tree - (12/2/97) Energy Saving Buildings Win National and Local Honors - (11/21/97)

  8. 1999 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search Sunlight Helps Laboratory Get Ready for Y2K - (12/27/99) NREL Hosts Free Workshops on Solar and Wind Energy - (12/15/99) Seminar Explores Benefits of Using Solar Power for Disaster Management - (11/17/99) Choices for a Brighter Future - (11/12/99) Better "Bugs" Lead to Cheaper Ethanol from Biomass - New Agreements Could Boost U.S. Biofuels Industry - (11/10/99)

  9. 2008 News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 News Releases Access news stories about the laboratory and renewable energy and energy efficiency technologies. Search News Search December 11, 2008 Alternative Fuels and Advanced Vehicle Data Center Creates New Tool to Calculate Ways to Cut Gas Use A business owner with a fleet of 10 heavy-duty diesel trucks wants to cut diesel use by 10 percent. Would using a biodiesel blend or investing in onboard power sources that reduce engine idling achieve the biggest drop in petroleum use? An average

  10. 2009 WIPP News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    09 News Releases December 21 Magnum Minerals to Buy WIPP Salt October 14 Agreement Reached Between WTS and Union Employees October 1 Truck Accident Did Not Involve WIPP Shipment September 18 WIPP Completes First RH-TRU Shipment from VNC July 24 DOE Issues Statement Concerning Debates Over Waste Disposal in Salt June 25 DOE Carlsbad Field Office Opens Local Recovery Act Office June 18 DOE Announces the Transfer of the WIPP Water Line to the City of Carlsbad June 3 Los Alamos National Laboratory

  11. Surviving the toxics in south Louisiana: A minority perspective

    SciTech Connect (OSTI)

    Wright, B.

    1995-12-01

    The Louisiana industrial corridor along the Mississippi River is lined with 136 petro-chemical plants and serves oil refineries. This approximates nearly one plant or refinery for every half mile of the river. The air, ground, and water along this corridor are so full or carcinogens that it has been described as a massive human experiment. Poor blacks live in river towns near the brunt of this discharge. Total mortality rates and cancer mortality rates in counties along the Mississippi River are significantly higher than in the rest of the nation`s counties. Moreover, the areas of greatest toxic discharge. Findings of disproportionately high mortality rates along the Mississippi, especially in communities on the lower river where toxic discharge minority and poor communities along the Mississippi River chemical corridor.

  12. Chemical Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical 'Sponges' Could Make Chemo Safer Chemical 'Sponges' Could Make Chemo Safer July 8, 2016 - 4:22pm Addthis A sample of a polymer-based membrane material created at Berkeley Lab. It’s designed to soak up cancer drugs and limit their side effects. | Photo by Roy Kaltschmidt, Berkeley Lab. A sample of a polymer-based membrane material created at Berkeley Lab. It's designed to soak up cancer drugs and limit their side effects. | Photo by Roy Kaltschmidt, Berkeley Lab. Glenn Roberts Jr.

  13. Method for producing chemical energy

    DOE Patents [OSTI]

    Jorgensen, Betty S.; Danen, Wayne C.

    2004-09-21

    Fluoroalkylsilane-coated metal particles having a central metal core, a buffer layer surrounding the core, and a fluoroalkylsilane layer attached to the buffer layer are prepared by combining a chemically reactive fluoroalkylsilane compound with an oxide coated metal particle having a hydroxylated surface. The resulting fluoroalkylsilane layer that coats the particles provides them with excellent resistance to aging. The particles can be blended with oxidant particles to form energetic powder that releases chemical energy when the buffer layer is physically disrupted so that the reductant metal core can react with the oxidant.

  14. Hybridization and Selective Release of DNA Microarrays

    SciTech Connect (OSTI)

    Beer, N R; Baker, B; Piggott, T; Maberry, S; Hara, C M; DeOtte, J; Benett, W; Mukerjee, E; Dzenitis, J; Wheeler, E K

    2011-11-29

    DNA microarrays contain sequence specific probes arrayed in distinct spots numbering from 10,000 to over 1,000,000, depending on the platform. This tremendous degree of multiplexing gives microarrays great potential for environmental background sampling, broad-spectrum clinical monitoring, and continuous biological threat detection. In practice, their use in these applications is not common due to limited information content, long processing times, and high cost. The work focused on characterizing the phenomena of microarray hybridization and selective release that will allow these limitations to be addressed. This will revolutionize the ways that microarrays can be used for LLNL's Global Security missions. The goals of this project were two-fold: automated faster hybridizations and selective release of hybridized features. The first study area involves hybridization kinetics and mass-transfer effects. the standard hybridization protocol uses an overnight incubation to achieve the best possible signal for any sample type, as well as for convenience in manual processing. There is potential to significantly shorten this time based on better understanding and control of the rate-limiting processes and knowledge of the progress of the hybridization. In the hybridization work, a custom microarray flow cell was used to manipulate the chemical and thermal environment of the array and autonomously image the changes over time during hybridization. The second study area is selective release. Microarrays easily generate hybridization patterns and signatures, but there is still an unmet need for methodologies enabling rapid and selective analysis of these patterns and signatures. Detailed analysis of individual spots by subsequent sequencing could potentially yield significant information for rapidly mutating and emerging (or deliberately engineered) pathogens. In the selective release work, optical energy deposition with coherent light quickly provides the thermal energy to

  15. Quick release engine cylinder

    DOE Patents [OSTI]

    Sunnarborg, Duane A.

    2000-01-01

    A quick release engine cylinder allows optical access to an essentially unaltered combustion chamber, is suitable for use with actual combustion processes, and is amenable to rapid and repeated disassembly and cleaning. A cylinder member, adapted to constrain a piston to a defined path through the cylinder member, sealingly engages a cylinder head to provide a production-like combustion chamber. A support member mounts with the cylinder member. The support-to-cylinder mounting allows two relationships therebetween. In the first mounting relationship, the support engages the cylinder member and restrains the cylinder against the head. In the second mounting relationship, the cylinder member can pass through the support member, moving away from the head and providing access to the piston-top and head.

  16. Metallothionein protection of cadmium toxicity

    SciTech Connect (OSTI)

    Klaassen, Curtis D. Liu, Jie; Diwan, Bhalchandra A.

    2009-08-01

    The discovery of the cadmium (Cd)-binding protein from horse kidney in 1957 marked the birth of research on this low-molecular weight, cysteine-rich protein called metallothionein (MT) in Cd toxicology. MT plays minimal roles in the gastrointestinal absorption of Cd, but MT plays important roles in Cd retention in tissues and dramatically decreases biliary excretion of Cd. Cd-bound to MT is responsible for Cd accumulation in tissues and the long biological half-life of Cd in the body. Induction of MT protects against acute Cd-induced lethality, as well as acute toxicity to the liver and lung. Intracellular MT also plays important roles in ameliorating Cd toxicity following prolonged exposures, particularly chronic Cd-induced nephrotoxicity, osteotoxicity, and toxicity to the lung, liver, and immune system. There is an association between human and rodent Cd exposure and prostate cancers, especially in the portions where MT is poorly expressed. MT expression in Cd-induced tumors varies depending on the type and the stage of tumor development. For instance, high levels of MT are detected in Cd-induced sarcomas at the injection site, whereas the sarcoma metastases are devoid of MT. The use of MT-transgenic and MT-null mice has greatly helped define the role of MT in Cd toxicology, with the MT-null mice being hypersensitive and MT-transgenic mice resistant to Cd toxicity. Thus, MT is critical for protecting human health from Cd toxicity. There are large individual variations in MT expression, which might in turn predispose some people to Cd toxicity.

  17. 2010 Report Released | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Report Released | National Nuclear Security Administration Facebook Twitter Youtube Flickr ... Home About Us Our History NNSA Timeline 2010 Report Released 2010 Report Released ...

  18. Preliminary Release: August 19, 2011",,,,,,,,,,,,,"Released: April 2013","Releas

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,,,,,,,,,,,,"Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April 2013","Released: April

  19. How Do I Work with Chemicals?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Do I Work with Chemicals? Print Planning In your experiment proposal, you must indicate whether you will be working with chemicals at the ALS. In the Experiment Safety Sheet (ESS), identify each chemical that you will be working with and let ALS This e-mail address is being protected from spambots. You need JavaScript enabled to view it know if any are flammable, toxic, engineered nanomaterials or reactive items. LBNL has an on-line MSDS database that can provide information for most

  20. How Do I Work with Chemicals?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Do I Work with Chemicals? Print Planning In your experiment proposal, you must indicate whether you will be working with chemicals at the ALS. In the Experiment Safety Sheet (ESS), identify each chemical that you will be working with and let ALS This e-mail address is being protected from spambots. You need JavaScript enabled to view it know if any are flammable, toxic, engineered nanomaterials or reactive items. LBNL has an on-line MSDS database that can provide information for most

  1. How Do I Work with Chemicals?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Do I Work with Chemicals? Print Planning In your experiment proposal, you must indicate whether you will be working with chemicals at the ALS. In the Experiment Safety Sheet (ESS), identify each chemical that you will be working with and let ALS This e-mail address is being protected from spambots. You need JavaScript enabled to view it know if any are flammable, toxic, engineered nanomaterials or reactive items. LBNL has an on-line MSDS database that can provide information for most

  2. How Do I Work with Chemicals?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Do I Work with Chemicals? Print Planning In your experiment proposal, you must indicate whether you will be working with chemicals at the ALS. In the Experiment Safety Sheet (ESS), identify each chemical that you will be working with and let ALS This e-mail address is being protected from spambots. You need JavaScript enabled to view it know if any are flammable, toxic, engineered nanomaterials or reactive items. LBNL has an on-line MSDS database that can provide information for most

  3. How Do I Work with Chemicals?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Do I Work with Chemicals? Print Planning In your experiment proposal, you must indicate whether you will be working with chemicals at the ALS. In the Experiment Safety Sheet (ESS), identify each chemical that you will be working with and let ALS This e-mail address is being protected from spambots. You need JavaScript enabled to view it know if any are flammable, toxic, engineered nanomaterials or reactive items. LBNL has an on-line MSDS database that can provide information for most

  4. Toxic Remediation System And Method

    DOE Patents [OSTI]

    Matthews, Stephen M.; Schonberg, Russell G.; Fadness, David R.

    1996-07-23

    What is disclosed is a novel toxic waste remediation system designed to provide on-site destruction of a wide variety of hazardous organic volatile hydrocarbons, including but not limited to halogenated and aromatic hydrocarbons in the vapor phase. This invention utilizes a detoxification plenum and radiation treatment which transforms hazardous organic compounds into non-hazardous substances.

  5. COMMERCIAL SNF ACCIDENT RELEASE FRACTIONS

    SciTech Connect (OSTI)

    S.O. Bader

    1999-10-18

    The purpose of this design analysis is to specify and document the total and respirable fractions for radioactive materials that are released from an accident event at the Monitored Geologic Repository (MGR) involving commercial spent nuclear fuel (CSNF) in a dry environment. The total and respirable release fractions will be used to support the preclosure licensing basis for the MGR. The total release fraction is defined as the fraction of total CSNF assembly inventory, typically expressed as an activity inventory (e.g., curies), of a given radionuclide that is released to the environment from a waste form. The radionuclides are released from the inside of breached fuel rods (or pins) and from the detachment of radioactive material (crud) from the outside surfaces of fuel rods and other components of fuel assemblies. The total release fraction accounts for several mechanisms that tend to retain, retard, or diminish the amount of radionuclides that are available for transport to dose receptors or otherwise can be shown to reduce exposure of receptors to radiological releases. The total release fraction includes a fraction of airborne material that is respirable and could result in inhalation doses. This subset of the total release fraction is referred to as the respirable release fraction. Potential accidents may involve waste forms that are characterized as either bare (unconfined) fuel assemblies or confined fuel assemblies. The confined CSNF assemblies at the MGR are contained in shipping casks, canisters, or disposal containers (waste packages). In contrast to the bare fuel assemblies, the container that confines the fuel assemblies has the potential of providing an additional barrier for diminishing the total release fraction should the fuel rod cladding breach during an accident. However, this analysis will not take credit for this additional bamer and will establish only the total release fractions for bare unconfined CSNF assemblies, which may however be

  6. Press Releases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Press Releases Press Releases RSS August 1, 2016 Press Releases NREL Technique Leads to Improved Solar Cells Scientists at the Energy Department's National Renewable Energy Laboratory (NREL), in collaboration with researchers at Shanghai Jiao Tong University (SJTU), devised a method to improve perovskite solar cells, making them more efficient and reliable with higher reproducibility. July 28, 2016 Battery500 Consortium to Spark EV Innovations: Pacific Northwest National Laboratory-led, 5-year

  7. Accident Investigation Report- Radiological Release

    Broader source: Energy.gov [DOE]

    On February 14, 2014, an airborne radiological release occurred at the Department of Energy Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico. Because access to the underground was restricted following the event, the investigation was broken into two phases. The Phase 1 report focused on how the radiological material was released into the atmosphere and Phase 2, performed once limited access to the underground was re‐established, focused on the source of the released radiological material.

  8. Rapid guide to hazardous chemicals in the workplace

    SciTech Connect (OSTI)

    Sax, I.N.; Lewis, R.J. Sr.

    1986-01-01

    This guide gives quick access to hazard data on almost 700 chemicals commonly found in the workplace. Alphabetically listed, each entry covers a specific chemical, standards and recommendations for exposure, its physical properties, and its toxic and hazard rating. A CAS, RTECS and DOT number identifies each substance; standards and recommendations cover its OSHA Permissible Exposure Limit, ACGIH Threshold Limit Value, MAKS, and DOT hazard classification. Physical properties include form, color, and odor. Here too is additional identifying information such as chemical formulas and well-known synonyms. The Toxic and Hazard Review summarizes hazards associated with the chemicals, revealing their: acute, immediate, chronic, and delayed effects; toxic or hazardous decomposition products; flammable and explosive properties; and incompatible materials and instabilities. This book is a reference source.

  9. Environmental Justice Interagency Working Group releases "Promising...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environmental Justice Interagency Working Group releases "Promising Practices for EJ Methodologies in NEPA Reviews" Environmental Justice Interagency Working Group releases ...

  10. DOE Releases Electricity Subsector Cybersecurity Risk Management...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Releases Electricity Subsector Cybersecurity Risk Management Process (RMP) Guideline DOE Releases Electricity Subsector Cybersecurity Risk Management Process (RMP) Guideline May ...

  11. Pharmacokinetic drivers of toxicity for basic molecules: Strategy to lower pKa results in decreased tissue exposure and toxicity for a small molecule Met inhibitor

    SciTech Connect (OSTI)

    Diaz, Dolores; Ford, Kevin A.; Hartley, Dylan P.; Harstad, Eric B.; Cain, Gary R.; Achilles-Poon, Kirsten; Nguyen, Trung; Peng, Jing; Zheng, Zhong; Merchant, Mark; Sutherlin, Daniel P.; Gaudino, John J.; Kaus, Robert; Lewin-Koh, Sock C.; Choo, Edna F.; Liederer, Bianca M.; Dambach, Donna M.

    2013-01-01

    Several toxicities are clearly driven by free drug concentrations in plasma, such as toxicities related to on-target exaggerated pharmacology or off-target pharmacological activity associated with receptors, enzymes or ion channels. However, there are examples in which organ toxicities appear to correlate better with total drug concentrations in the target tissues, rather than with free drug concentrations in plasma. Here we present a case study in which a small molecule Met inhibitor, GEN-203, with significant liver and bone marrow toxicity in preclinical species was modified with the intention of increasing the safety margin. GEN-203 is a lipophilic weak base as demonstrated by its physicochemical and structural properties: high LogD (distribution coefficient) (4.3) and high measured pKa (7.45) due to the basic amine (N-ethyl-3-fluoro-4-aminopiperidine). The physicochemical properties of GEN-203 were hypothesized to drive the high distribution of this compound to tissues as evidenced by a moderately-high volume of distribution (Vd > 3 l/kg) in mouse and subsequent toxicities of the compound. Specifically, the basicity of GEN-203 was decreased through addition of a second fluorine in the 3-position of the aminopiperidine to yield GEN-890 (N-ethyl-3,3-difluoro-4-aminopiperidine), which decreased the volume of distribution of the compound in mouse (Vd = 1.0 l/kg), decreased its tissue drug concentrations and led to decreased toxicity in mice. This strategy suggests that when toxicity is driven by tissue drug concentrations, optimization of the physicochemical parameters that drive tissue distribution can result in decreased drug concentrations in tissues, resulting in lower toxicity and improved safety margins. -- Highlights: ? Lower pKa for a small molecule: reduced tissue drug levels and toxicity. ? New analysis tools to assess electrostatic effects and ionization are presented. ? Chemical and PK drivers of toxicity can be leveraged to improve safety.

  12. Event reconstruction for line source releases

    SciTech Connect (OSTI)

    Zajic, Dragan; Brown, Michael J; Williams, Michael D

    2010-01-01

    The goal of source inversion, also called event reconstruction, is the calculation of source parameters from information obtained by network of concentration (or dosage) and meteorological sensors. Source parameters include source location and strength, but in certain cases there could be more than one source so the inversion procedure could deal with determination of number of sources, as well. In a case of limited time period pollutant emission events, as for example during accidents or intentional releases, it is of great use to estimate starting and ending times of the event. This kind of research is very useful for estimating the source parameters of industrial pollutants since it provides important information for regulation purposes. Also it provides information to fast responders in a case of accidental pollutant releases or for homeland security needs when chemical, biological or radiological agent is deliberately released. Development of faster and more accurate algorithms is very important since it could help reduce the populace's exposure to dangerous airborne contaminants, plan evacuation routes, and help assess the magnitude of clean up. During the last decade, the large number of research papers in area of source inversion was published where many different approaches were used. Most of the source inversion work publish to date apply to point source releases. The forward dispersion models used range from fast Gaussian plume and puff codes that enable almost instantaneous calculations of concentrations and dosages to Computational Fluid Dynamics (CFD) codes that provide more detailed and precise calculation but at the same time are expensive with respect to time and computer resources. The optimization methods were often used and examples are simulated annealing and genetic algorithms.

  13. NREL Releases Updated Typical Meteorological Year Data Set - News Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | NREL NREL Releases Updated Typical Meteorological Year Data Set May 1, 2008 The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) today released an updated typical meteorological year (TMY) data set derived from the 1991-2005 National Solar Radiation Data Base update. The TMY3 data and user's manual are available at http://rredc.nrel.gov/solar/old_data/nsrdb/1991-2005/tmy3. The new data sets update and expand the TMY2 data sets released by NREL in 1994. The TMY3 data

  14. Plant toxicity studies made publicly available by EPA and the TSCA Interagency Testing Committee

    SciTech Connect (OSTI)

    Walker, J.D.

    1994-12-31

    The purpose of this presentation is to briefly describe the ITC, describe the Toxic Substances Control Act (TSCA) Test Submissions (TSCATS) database and how the EPA makes unpublished health and safety studies publicly available through TSCATS as a result of ITC testing recommendations and other activities and to describe some of the unpublished plant toxicity studies that are available tin TSCATS. In 1976, under section 4(e) of the Toxic Substances Control Act (TSCA), the US Congress created the ITC to implement the initial phases of testing TSCA-regulable chemicals. Congress directed the ITC to: (1) make testing decisions on about 70,000 chemicals, (2) develop the TSCA Section 4(e) Priority Testing List, (3) coordinate chemical testing and (4) revise the List at least every six months. The creation, structure, functions and contributions of the ITC from 1977 to 1992 have been previously described. TSCATS is an EPA database. It is an online pointer file that identifies all the unpublished studies that have been submitted to EPA under TSCA sections 4 and 8 and as For Your Information studies. Most of the studies in TSCATS were submitted by manufacturers of chemicals that ITC has added to the Priority Testing List because EPA has published Federal Register notices requesting that manufacturers of ITC chemicals submit unpublished data under TSCA section 8 or conduct testing and submit the data that were developed under TSCA section 4. Data from plant toxicity studies indexed in TSCATS will be presented.

  15. NREL Releases New Version of Energy Evaluation Software - News Releases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL NREL Releases New Version of Energy Evaluation Software January 4, 2005 Golden, Colo. - Researchers at the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) recently released Version 2.1 of HOMER, a micropower optimization software model that simplifies the task of evaluating design options for both off-grid and grid-connected power systems. Users supply information about electrical loads, renewable resources and component costs and HOMER simulates multiple designs

  16. Commercial SNF Accident Release Fractions

    SciTech Connect (OSTI)

    J. Schulz

    2004-11-05

    The purpose of this analysis is to specify and document the total and respirable fractions for radioactive materials that could be potentially released from an accident at the repository involving commercial spent nuclear fuel (SNF) in a dry environment. The total and respirable release fractions are used to support the preclosure licensing basis for the repository. The total release fraction is defined as the fraction of total commercial SNF assembly inventory, typically expressed as an activity inventory (e.g., curies), of a given radionuclide that is released to the environment from a waste form. Radionuclides are released from the inside of breached fuel rods (or pins) and from the detachment of radioactive material (crud) from the outside surfaces of fuel rods and other components of fuel assemblies. The total release fraction accounts for several mechanisms that tend to retain, retard, or diminish the amount of radionuclides that are available for transport to dose receptors or otherwise can be shown to reduce exposure of receptors to radiological releases. The total release fraction includes a fraction of airborne material that is respirable and could result in inhalation doses; this subset of the total release fraction is referred to as the respirable release fraction. Accidents may involve waste forms characterized as: (1) bare unconfined intact fuel assemblies, (2) confined intact fuel assemblies, or (3) canistered failed commercial SNF. Confined intact commercial SNF assemblies at the repository are contained in shipping casks, canisters, or waste packages. Four categories of failed commercial SNF are identified: (1) mechanically and cladding-penetration damaged commercial SNF, (2) consolidated/reconstituted assemblies, (3) fuel rods, pieces, and debris, and (4) nonfuel components. It is assumed that failed commercial SNF is placed into waste packages with a mesh screen at each end (CRWMS M&O 1999). In contrast to bare unconfined fuel assemblies, the

  17. DOCUMENT RELEASE FORM G5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DOCUMENT RELEASE FORM G5 (1) Document Number: RPP-RPT-431 69 (2) Revision Number: 0 (3) Effective Date: 9/30/2009 (4) Document Type: E] Digital Image l Hard copy (a) Number of pages (including the IDRF) or 125 E PDF ElVideo number of digital images (5) Release Type Z New 0 Cancel El Page Change l complete Revision (6) Document Title: 2009 Auto-TCR for Tank 241 -T-1 11 (7) Change/Release Initial Issuance Description: (8) Change Initial Issuance Justification: (9) Associated (a) Structure

  18. Controlled release liquid dosage formulation

    DOE Patents [OSTI]

    Benton, Ben F.; Gardner, David L.

    1989-01-01

    A liquid dual coated dosage formulation sustained release pharmaceutic having substantial shelf life prior to ingestion is disclosed. A dual coating is applied over controlled release cores to form dosage forms and the coatings comprise fats melting at less than approximately 101.degree. F. overcoated with cellulose acetate phthalate or zein. The dual coated dosage forms are dispersed in a sugar based acidic liquid carrier such as high fructose corn syrup and display a shelf life of up to approximately at least 45 days while still retaining their release profiles following ingestion. Cellulose acetate phthalate coated dosage form cores can in addition be dispersed in aqueous liquids of pH <5.

  19. Identification of chemical hazards for security risk analysis activities.

    SciTech Connect (OSTI)

    Jaeger, Calvin Dell

    2005-01-01

    The presentation outline of this paper is: (1) How identification of chemical hazards fits into a security risk analysis approach; (2) Techniques for target identification; and (3) Identification of chemical hazards by different organizations. The summary is: (1) There are a number of different methodologies used within the chemical industry which identify chemical hazards: (a) Some develop a manual listing of potential targets based on published lists of hazardous chemicals or chemicals of concern, 'expert opinion' or known hazards. (b) Others develop a prioritized list based on chemicals found at a facility and consequence analysis (offsite release affecting population, theft of material, product tampering). (2) Identification of chemical hazards should include not only intrinsic properties of the chemicals but also potential reactive chemical hazards and potential use for activities off-site.

  20. Court decision dropping toxic substance rules stands

    SciTech Connect (OSTI)

    Bryant, C.R.

    1993-06-01

    In a somewhat surprising move, the U.S. Department of Labor has decided not to appeal a court decision essentially dropping regulations established by the Occupational Safety and Health Administration (OSHA) for about 400 hazardous substances. The decision leaves unregulated or subject to reduced standards substances that range from carbon monoxide to perchloroethylene. The Labor Department had until March 22, 1993, to appeal the court decision. On July 8, 1992, the U.S. Court of Appeals for the 11th Circuit overturned OSHA's final Air Contaminants Standard, which was promulgated in 1989. The standard established permissible exposure limits (PELs) for 428 toxic substances. In AFL-CIO vs. OSHA, the Court ruled that OSHA failed to make a separate scientific case for evaluating health risks of each chemical. Because of the decision not to appeal, PELs for more than half of the substances regulated by OSHA now are removed from the books or revert to the voluntary industry standards adopted by OSHA in 1970 and in force prior to the 1989 final rule.

  1. Fermilab | Newsroom | Press Releases | [TITLE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Press Release PDF Click to read answers to FAQ about the Higgs boson. Med Res | Hi Res | EPS After more than 10 years of gathering and analyzing data produced by the U.S....

  2. Media Releases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Media Releases Media Releases March 1, 2016 Lockheed Martin Agrees to Pay $5 Million to Settle False Claims Act Allegations February 26, 2016 Three Arrested and Charged in a Scheme to Defraud Federal Research Funding December 16, 2015 Two Men Charged With Wire Fraud December 15, 2015 Former Russian Nuclear Energy Official Sentenced to Four Years in Prison for Money Laundering Conspiracy October 21, 2015 OIG Receives Prestigious CIGIE Award September 24, 2015 Argonne National Laboratory Employee

  3. ARM - LASSO Pilot Project Releases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases Alpha 1 Links Primary Documentation File Contents Acknowledgements Evaluation Product Files Bundle Browser LASSO Information LASSO Home LASSO Backgrounder Pilot Phase Begins for Routine Large-Eddy Simulations Pilot Project Timeline Presentations News Science LASSO Implementation Strategy LASSO Pilot Project Releases Related Information ARM Decadal Vision Archive of LASSO Information e-mail list Contacts William Gustafson, Lead Principal Investigator Andrew Vogelmann, Co-Principal

  4. Pre-release plastic packaging of MEMS and IMEMS devices

    SciTech Connect (OSTI)

    Peterson, Kenneth A.; Conley, William R.

    2002-01-01

    A method is disclosed for pre-release plastic packaging of MEMS and IMEMS devices. The method can include encapsulating the MEMS device in a transfer molded plastic package. Next, a perforation can be made in the package to provide access to the MEMS elements. The non-ablative material removal process can include wet etching, dry etching, mechanical machining, water jet cutting, and ultrasonic machining, or any combination thereof. Finally, the MEMS elements can be released by using either a wet etching or dry plasma etching process. The MEMS elements can be protected with a parylene protective coating. After releasing the MEMS elements, an anti-stiction coating can be applied. The perforating step can be applied to both sides of the device or package. A cover lid can be attached to the face of the package after releasing any MEMS elements. The cover lid can include a window for providing optical access. The method can be applied to any plastic packaged microelectronic device that requires access to the environment, including chemical, pressure, or temperature-sensitive microsensors; CCD chips, photocells, laser diodes, VCSEL's, and UV-EPROMS. The present method places the high-risk packaging steps ahead of the release of the fragile portions of the device. It also provides protection for the die in shipment between the molding house and the house that will release the MEMS elements and subsequently treat the surfaces.

  5. Code System to Solve for Release and Transport of Contaminants through Saturated/Unsaturated Media.

    Energy Science and Technology Software Center (OSTI)

    1996-03-07

    The BLT code solves for release and transport of contaminants from containerized wastes. Each container may have unique properties (i.e., time to failure or localized failure, e.g. pitting) and each waste form may have unique release properties. Release from the waste form is limited by one of four physical or chemical constraints: solubility, diffusion, dissolution, and surface wash-off with partitioning. The release from the waste form acts as a source for transport in the advection/dispersionmore » equation. Transport is modeled in two-dimensions through the groundwater pathway from subsurface disposal.« less

  6. Press Releases | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    technology ---Fuel economy ---Fuel injection ---Heavy-duty vehicles ---Hybrid & ... The chemical reactions that make methanol from carbon dioxide rely on a catalyst to speed ...

  7. FY17 SBIR Phase I Release 1 FOA Released: Includes Fuel Cell...

    Energy Savers [EERE]

    FY17 SBIR Phase I Release 1 FOA Released: Includes Fuel Cell Catalysts and Hydrogen Delivery FY17 SBIR Phase I Release 1 FOA Released: Includes Fuel Cell Catalysts and Hydrogen ...

  8. Method for detecting toxic gases

    DOE Patents [OSTI]

    Stetter, Joseph R.; Zaromb, Solomon; Findlay, Jr., Melvin W.

    1991-01-01

    A method capable of detecting low concentrations of a pollutant or other component in air or other gas, utilizing a combination of a heating filament having a catalytic surface of a noble metal for exposure to the gas and producing a derivative chemical product from the component, and an electrochemical sensor responsive to the derivative chemical product for providing a signal indicative of the product. At concentrations in the order of about 1-100 ppm of tetrachloroethylene, neither the heating filament nor the electrochemical sensor is individually capable of sensing the pollutant. In the combination, the heating filament converts the benzyl chloride to one or more derivative chemical products which may be detected by the electrochemical sensor.

  9. Method for detecting toxic gases

    DOE Patents [OSTI]

    Stetter, J.R.; Zaromb, S.; Findlay, M.W. Jr.

    1991-10-08

    A method is disclosed which is capable of detecting low concentrations of a pollutant or other component in air or other gas. This method utilizes a combination of a heating filament having a catalytic surface of a noble metal for exposure to the gas and producing a derivative chemical product from the component. An electrochemical sensor responds to the derivative chemical product for providing a signal indicative of the product. At concentrations in the order of about 1-100 ppm of tetrachloroethylene, neither the heating filament nor the electrochemical sensor is individually capable of sensing the pollutant. In the combination, the heating filament converts the benzyl chloride to one or more derivative chemical products which may be detected by the electrochemical sensor. 6 figures.

  10. Chemical Safety Vulnerability Working Group report. Volume 3

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The Chemical Safety Vulnerability (CSV) Working Group was established to identify adverse conditions involving hazardous chemicals at DOE facilities that might result in fires or explosions, release of hazardous chemicals to the environment, or exposure of workers or the public to chemicals. A CSV Review was conducted in 148 facilities at 29 sites. Eight generic vulnerabilities were documented related to: abandoned chemicals and chemical residuals; past chemical spills and ground releases; characterization of legacy chemicals and wastes; disposition of legacy chemicals; storage facilities and conditions; condition of facilities and support systems; unanalyzed and unaddressed hazards; and inventory control and tracking. Weaknesses in five programmatic areas were also identified related to: management commitment and planning; chemical safety management programs; aging facilities that continue to operate; nonoperating facilities awaiting deactivation; and resource allocations. Volume 3 consists of eleven appendices containing the following: Field verification reports for Idaho National Engineering Lab., Rocky Flats Plant, Brookhaven National Lab., Los Alamos National Lab., and Sandia National Laboratories (NM); Mini-visits to small DOE sites; Working Group meeting, June 7--8, 1994; Commendable practices; Related chemical safety initiatives at DOE; Regulatory framework and industry initiatives related to chemical safety; and Chemical inventory data from field self-evaluation reports.

  11. THE RADIAL VELOCITY EXPERIMENT (RAVE): FOURTH DATA RELEASE

    SciTech Connect (OSTI)

    Kordopatis, G.; Gilmore, G.; Steinmetz, M.; Williams, M. E. K.; Piffl, T.; Enke, H.; Carrillo, I.; Boeche, C.; Roeser, S.; Seabroke, G. M.; Siebert, A.; Zwitter, T.; Binney, J.; De Laverny, P.; Recio-Blanco, A.; Bijaoui, A.; Wyse, R. F. G.; Freeman, K.; Munari, U.; Anguiano, B.; and others

    2013-11-01

    We present the stellar atmospheric parameters (effective temperature, surface gravity, overall metallicity), radial velocities, individual abundances, and distances determined for 425,561 stars, which constitute the fourth public data release of the RAdial Velocity Experiment (RAVE). The stellar atmospheric parameters are computed using a new pipeline, based on the algorithms of MATISSE and DEGAS. The spectral degeneracies and the Two Micron All Sky Survey photometric information are now better taken into consideration, improving the parameter determination compared to the previous RAVE data releases. The individual abundances for six elements (magnesium, aluminum, silicon, titanium, iron, and nickel) are also given, based on a special-purpose pipeline that is also improved compared to that available for the RAVE DR3 and Chemical DR1 data releases. Together with photometric information and proper motions, these data can be retrieved from the RAVE collaboration Web site and the Vizier database.

  12. Bioenergy Technologies Office Releases Symbiosis Biofeedstock...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Releases Symbiosis Biofeedstock Conference Summary Report Bioenergy Technologies Office Releases Symbiosis Biofeedstock Conference Summary Report January 2, 2014 - 12:00am Addthis...

  13. Webinar: Algal Biofuels Consortium Releases Groundbreaking Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Algal Biofuels Consortium Releases Groundbreaking Research Results Webinar: Algal Biofuels Consortium Releases Groundbreaking Research Results Dr. Jose Olivares of Los Alamos ...

  14. WIPP Radiological Release Report Phase 1

    Office of Environmental Management (EM)

    Phase 1 Radiological Release Event at the Waste Isolation Pilot Plant on February 14, 2014 April 2014 Radiological Release Event at the Waste Isolation Pilot Plant Radiological ...

  15. Theoretical energy release of thermites, intermetallics, and...

    Office of Scientific and Technical Information (OSTI)

    Theoretical energy release of thermites, intermetallics, and combustible metals Citation Details In-Document Search Title: Theoretical energy release of thermites, intermetallics, and ...

  16. Climate Change Press Release | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Climate Change Press Release Community Leaders Institutes (CLIs) to be conducted to promote awareness of climate change impacts. CLI Climate Change Press Release (118.51 KB) More ...

  17. Effects of water temperature and pH on toxicity of terbufos, trichlorfon, 4-nitrophenol and 2,4-dinitrophenol to the amphipod Gammarus pseudolimnaeus and rainbow trout (Oncorhynchus mykiss)

    SciTech Connect (OSTI)

    Howe, G.E.; Marking, L.L.; Bills, T.D.; Rach, J.J. . National Fisheries Research Center); Mayer, F.L. Jr. . Environmental Research Lab.)

    1994-01-01

    Acute toxicity tests were conducted to determine (a) the individual and interactive effects of water temperature (7, 12, 17 C), pH (6.5, 7.5, 8.5, 9.5), and time on the toxicity of terbufos, trichlorfon, 4-nitrophenol, and 2,4-dinitrophenol to rainbow trout (Oncorhynchus mykiss) and the amphipod Gammarus pseudolimnaeus, and (b) the individual and interactive effects of water temperature and pH on chemical bioconcentration during acute tests with rainbow trout and Gammarus exposed to terbufos, 4-nitrophenol, and 2,4-dinitrophenol. The toxicity of all four chemicals was significantly affected by pH in all tests, except for Gammarus exposed to terbufos. The toxicity of terbufos to rainbow trout and Gammarus was less at pH 7.5 than at higher or lower pH. The toxicity of both nitrophenols decreased as pH increased, whereas the toxicity of trichlorfon increased with pH. The effect of pH on trichlorfon toxicity decreased with temperature. Temperature significantly affected the toxicity of all four chemicals to both species. Toxicity increased with temperature in all tests, except for rainbow trout exposed to nitrophenols; toxicity decreased as temperature increased for rainbow trout. Chemical bioconcentration was also significantly affected by temperature and pH and was directly related to toxicity in most tests. Significant interactive effects between toxicity-modifying factors were also frequently observed. Temperature and pH effects on chemical toxicity need to be considered in chemical hazard assessment to ensure adequate protection of aquatic organisms.

  18. Next Release Date: August 2013

    Gasoline and Diesel Fuel Update (EIA)

    in Renewable Energy Consumption and Electricity 2010 Release Date: December 11, 2012 Next Release Date: August 2013 Table 10. Renewable electric power sector net generation by energy source and State, 2009 (thousand kilowatthours) Landfill Gas/MSW Biogenic 1 Other Biomass 2 Alabama 12,535,373 - 2,050 245,980 - - - 248,030 12,783,403 Alaska 1,323,744 - - - - - 7,027 7,027 1,330,771 Arizona 6,427,345 18,299 - 136,641 - 14,145 29545 198,630 6,625,975 Arkansas 4,192,706 34,371 17,645 - - - - 52,016

  19. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott J; Alvizo, Oscar

    2013-10-29

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  20. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott; Alvizo, Oscar

    2013-01-15

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  1. Enhanced formulations for neutralization of chemical, biological and industrial toxants

    DOE Patents [OSTI]

    Tucker, Mark D [Albuqueque, NM

    2008-06-24

    An enhanced formulation and method of making that neutralizes the adverse health effects of both chemical and biological compounds, especially chemical warfare (CW) and biological warfare (BW) agents, and toxic industrial chemicals. The enhanced formulation according to the present invention is non-toxic and non-corrosive and can be delivered by a variety of means and in different phases. The formulation provides solubilizing compounds that serve to effectively render the chemical and biological compounds, particularly CW and BW compounds, susceptible to attack, and at least one reactive compound that serves to attack (and detoxify or kill) the compound. The formulation includes at least one solubilizing agent, a reactive compound, a bleaching activator and water.

  2. Press Releases | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases Topic - Any - General Argonne Information -Awards -Honors Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive engineering ---Biofuels ---Diesel ---Electric drive technology ---Fuel economy ---Fuel injection ---Heavy-duty vehicles ---Hybrid & electric vehicles ---Hydrogen & fuel cells ---Internal combustion ---Maglev systems ---Powertrain research ---Vehicle testing --Building design ---Construction ---Industrial heating & cooling ---Industrial

  3. Press Releases | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases Topic - Any - General Argonne Information -Awards -Honors Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive engineering ---Biofuels ---Diesel ---Electric drive technology ---Fuel economy ---Fuel injection ---Heavy-duty vehicles ---Hybrid & electric vehicles ---Hydrogen & fuel cells ---Internal combustion ---Maglev systems ---Powertrain research ---Vehicle testing --Building design ---Construction ---Industrial heating & cooling ---Industrial

  4. Press Releases | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases Topic - Any - General Argonne Information -Awards -Honors Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive engineering ---Biofuels ---Diesel ---Electric drive technology ---Fuel economy ---Fuel injection ---Heavy-duty vehicles ---Hybrid & electric vehicles ---Hydrogen & fuel cells ---Internal combustion ---Maglev systems ---Powertrain research ---Vehicle testing --Building design ---Construction ---Industrial heating & cooling ---Industrial

  5. SRP RADIOACTIVE WASTE RELEASES S

    Office of Scientific and Technical Information (OSTI)

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  6. Press Releases | Stanford Synchrotron Radiation Lightsource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases 2012 Press Releases December 10, 2012 Experiment Finds Ulcer Bug's Achilles' Heel (see Press Release) June 6, 2012 New secrets from "Bay of the Pirates" warship that sunk 2,300 years ago (see Press Release) March 5, 2012 X-rays Reveal How Soil Bacteria Carry Out Surprising Chemistry (see Press Release) 2011 Press Releases July 3, 2011 Researchers Decipher Protein Structure of Key Molecule in DNA Transcription System (see Press Release) June 30, 2011 X-rays Reveal

  7. Microfluidic chemical reaction circuits

    DOE Patents [OSTI]

    Lee, Chung-cheng; Sui, Guodong; Elizarov, Arkadij; Kolb, Hartmuth C.; Huang, Jiang; Heath, James R.; Phelps, Michael E.; Quake, Stephen R.; Tseng, Hsian-rong; Wyatt, Paul; Daridon, Antoine

    2012-06-26

    New microfluidic devices, useful for carrying out chemical reactions, are provided. The devices are adapted for on-chip solvent exchange, chemical processes requiring multiple chemical reactions, and rapid concentration of reagents.

  8. Amineborane Based Chemical Hydrogen Storage - Final Report

    SciTech Connect (OSTI)

    Sneddon, Larry G.

    2011-04-21

    The development of efficient and safe methods for hydrogen storage is a major hurdle that must be overcome to enable the use of hydrogen as an alternative energy carrier. The objectives of this project in the DOE Center of Excellence in Chemical Hydride Storage were both to develop new methods for on-demand, low temperature hydrogen release from chemical hydrides and to design high-conversion off-board methods for chemical hydride regeneration. Because of their reactive protic (N-H) and hydridic (B-H) hydrogens and high hydrogen contents, amineboranes such as ammonia borane, NH3BH3 (AB), 19.6-wt% H2, and ammonia triborane NH3B3H7 (AT), 17.7-wt% H2, were initially identified by the Center as promising, high-capacity chemical hydrogen storage materials with the potential to store and deliver molecular hydrogen through dehydrogenation and hydrolysis reactions. In collaboration with other Center partners, the Penn project focused both on new methods to induce amineborane H2-release and on new strategies for the regeneration the amineborane spent-fuel materials. The Penn approach to improving amineborane H2-release focused on the use of ionic liquids, base additives and metal catalysts to activate AB dehydrogenation and these studies successfully demonstrated that in ionic liquids the AB induction period that had been observed in the solid-state was eliminated and both the rate and extent of AB H2-release were significantly increased. These results have clearly shown that, while improvements are still necessary, many of these systems have the potential to achieve DOE hydrogen-storage goals. The high extent of their H2­-release, the tunability of both their H2 materials weight-percents and release rates, and their product control that is attained by either trapping or suppressing unwanted volatile side products, such as borazine, continue to make AB/ionic­-liquid based systems attractive candidates for chemical hydrogen storage applications. These studies also

  9. Chemical Management System

    Energy Science and Technology Software Center (OSTI)

    1998-10-30

    CMS provides an inventory of all chemicals on order or being held in the laboratory, to provide a specific location for all chemical containers, to ensure that health and safety regulatory codes are being upheld, and to provide PNNL staff with hazardous chemical information to better manage their inventories. CMS is comprised of five major modules: 1) chemical purchasing, 2) chemical inventory, 3) chemical names, properties, and hazard groups, 4) reporting, and 5) system administration.

  10. NREL Releases Report Card on Environmental Efforts - News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Releases Report Card on Environmental Efforts October 23, 2015 The Energy Department's National Renewable Energy Laboratory (NREL) continued to improve its environmental protection efforts at its South Table Mountain and National Wind Technology Center sites during 2014 by reducing greenhouse gas emissions, adding bird-safety features to campus structures, and assessing environmental impacts of potential laboratory development. NREL annually reports on the environmental performance and