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Sample records for tot actl ipr

  1. Working with SRNL - Our Facilities - ACTL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    development in the fields of waste management, environmental sciences, and biotechnology. ... and Environmental Science & Biotechnology directorates work at ACTL, conducting ...

  2. IPR 2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Public Processes Integrated Program Review IPR 2012 IPR 2010 IPR 2009 IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic...

  3. IPR 2008

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Public Processes Integrated Program Review IPR 2012 IPR 2010 IPR 2009 IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic...

  4. IPR 2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Public Processes Integrated Program Review IPR 2012 IPR 2010 IPR 2009 IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic...

  5. IPR 2010

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Update Property Insurance Update Agency Services IBS P and T BPA Retirement Demographics July 8, 2010 Workshop Debt Management Presentation July 13, 2010 Workshop 2010 IPR...

  6. IPR 2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rate Cases Rate Information Residential Exchange Program Surplus Power Sales Reports 2014 Integrated Program Review The IPR process allows interested parties to see all relevant...

  7. IPR 2009

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic Capital Discussions Access to Capital Debt Optimization Asset Management Cost...

  8. Toys for Tots

    National Nuclear Security Administration (NNSA)

    relay race, which has raised 25,000 for the Savannah River Site's Toys for Tots campaign.

    Dozens of contractor employees at the Savannah River Site (SRS)...

  9. Toys for Tots | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    compete in the fifth annual "Dash for Bikes, Walk for Trikes" relay race, which has raised 25,000 for the Savannah River Site's Toys for Tots campaign.Dozens of contractor...

  10. Application to Export Electric Energy OE Docket No. EA-386 IPR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EA-386 IPR-GDF Suez Energy Marketing (Gsemna) Application from IPR-GDF SUEZ (GSEMNA) to export electric energy to Mexico. PDF icon EA-386 IPR-GDF SUEZ (GSEMNA) MX.pdf More ...

  11. Property:Tot rev (thousand $) | Open Energy Information

    Open Energy Info (EERE)

    "Tot rev (thousand )" Showing 25 pages using this property. (previous 25) (next 25) 4 4-County Electric Power Assn (Mississippi) EIA Revenue and Sales - April 2008 + 6,790 +...

  12. Property:Tot sales (mwh) | Open Energy Information

    Open Energy Info (EERE)

    property "Tot sales (mwh)" Showing 25 pages using this property. (previous 25) (next 25) 4 4-County Electric Power Assn (Mississippi) EIA Revenue and Sales - April 2008 + 69,154 +...

  13. Application to Export Electric Energy OE Docket No. EA-386 IPR-GDF Suez

    Energy Savers [EERE]

    Energy Marketing (Gsemna) | Department of Energy Suez Energy Marketing (Gsemna) Application to Export Electric Energy OE Docket No. EA-386 IPR-GDF Suez Energy Marketing (Gsemna) Application from IPR-GDF SUEZ (GSEMNA) to export electric energy to Mexico. PDF icon EA-386 IPR-GDF SUEZ (GSEMNA) MX.pdf More Documents & Publications EA-386 IPR-GDF Suez Energy Marketing North America, Inc. (GSEMNA) Application to Export Electric Energy OE Docket No. EA-386 IPR-GDF SUEZ Energy Marketing

  14. Cesium Delivery System for Negative Ion Source at IPR

    SciTech Connect (OSTI)

    Bansal, G.; Pandya, K.; Soni, J.; Gahlaut, A.; Parmar, K. G. [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat, 382 428 (India); Bandyopadhyay, M.; Chakraborty, A.; Singh, M. J. [ITER- India, Institute for Plasma Research, A-29, Sector 25, GIDC, Gandhinagar, Gujarat (India)


    The technique of surface production of negative ions using cesium, Cs, has been efficiently exploited over the years for producing negative ion beams with increased current densities from negative ion sources used on neutral beam lines. Deposition of Cs on the source walls and the plasma grid lowers the work function and therefore enables a higher yield of H{sup -}, when hydrogen particles (H and/or H{sub x}{sup +}) strike these surfaces.A single driver RF based (100 kW, 1 MHz) negative ion source test bed, ROBIN, is being set up at IPR under a technical collaboration between IPR and IPP, Germany. The optimization of the Cs oven design to be used on this facility as well as multidriver sources is underway. The characterization experiments of such a Cs delivery system with a 1 g Cs inventory have been carried out using surface ionization technique. The experiments have been carried by delivering Cs into a vacuum chamber without plasma. The linear motion of the surface ionization detector, SID, attached with a linear motion feedthrough allows measuring the angular distribution of the Cs coming out of the oven. Based on the experimental results, a Cs oven for ROBIN has been proposed. The Cs oven design and experimental results of the prototype Cs oven are reported and discussed in the paper.

  15. Application to Export Electric Energy OE Docket No. EA-386 IPR-GDF SUEZ

    Energy Savers [EERE]

    Energy Marketing (GSEMNA): Federal Register Notice, Volume 77, No. 129 - July 5, 2012 | Department of Energy SUEZ Energy Marketing (GSEMNA): Federal Register Notice, Volume 77, No. 129 - July 5, 2012 Application to Export Electric Energy OE Docket No. EA-386 IPR-GDF SUEZ Energy Marketing (GSEMNA): Federal Register Notice, Volume 77, No. 129 - July 5, 2012 Application from IPR-GDF SUEZ Energy (GSEMNA) to export electric to Mexico. Federal Register Notice. PDF icon EA-386 IPR-GDF SUEZ Energy

  16. Application to Export Electric Energy OE Docket No. EA-386 IPR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SUEZ Energy Marketing (GSEMNA): Federal Register Notice, Volume 77, No. 129 - July 5, 2012 Application to Export Electric Energy OE Docket No. EA-386 IPR-GDF SUEZ Energy Marketing ...

  17. EA-386 IPR-GDF Suez Energy Marketing North America, Inc. (GSEMNA...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EA-386 IPR-GDF Suez Energy Marketing North America, Inc. (GSEMNA) Order authorizing GSEMNA to export electric energy to Mexico. PDF icon EA-386 GSEMNA - MX.pdf More Documents & ...

  18. Simulation of integrated pollutant removal (IPR) water-treatment system using ASPEN Plus

    SciTech Connect (OSTI)

    Harendra, Sivaram; Oryshcyhn, Danylo [U.S. DOE Ochs, Thomas [U.S. DOE Gerdemann, Stephen; Clark, John


    Capturing CO2 from fossil fuel combustion provides an opportunity for tapping a significant water source which can be used as service water for a capture-ready power plant and its peripherals. Researchers at the National Energy Technology Laboratory (NETL) have patented a process—Integrated Pollutant Removal (IPR®)—that uses off-the-shelf technology to produce a sequestration ready CO2 stream from an oxy-combustion power plant. Water condensed from oxy-combustion flue gas via the IPR system has been analyzed for composition and an approach for its treatment—for in-process reuse and for release—has been outlined. A computer simulation model in ASPEN Plus has been developed to simulate water treatment of flue gas derived wastewater from IPR systems. At the field installation, water condensed in the IPR process contains fly ash particles, sodium (largely from spray-tower buffering) and sulfur species as well as heavy metals, cations, and anions. An IPR wastewater treatment system was modeled using unit operations such as equalization, coagulation and flocculation, reverse osmosis, lime softening, crystallization, and pH correction. According to the model results, 70% (by mass) of the inlet stream can be treated as pure water, the other 20% yields as saleable products such as gypsum (CaSO4) and salt (NaCl) and the remaining portion is the waste. More than 99% of fly ash particles are removed in the coagulation and flocculation unit and these solids can be used as filler materials in various applications with further treatment. Results discussed relate to a slipstream IPR installation and are verified experimentally in the coagulation/flocculation step.

  19. Studies of Intermittency-like Phenomena in Plasma turbulence at IPR

    SciTech Connect (OSTI)

    Jha, R.; Das, A.; Bisai, N.; Kaw, P. [Institute for Plasma Research, Bhat, Near Indira Bridge, Gandhinagar-382428 (India)


    The observation of intermittency in the turbulent scrape-off layer plasma of ADITYA tokamak was first reported about one and a half decade ago. In the last decade or so, several aspects of intermittency-like phenomena have been observed on tokamaks and other fusion devices throughout the world. A review of the research carried out at the Institute for Plasma Research (IPR) is presented, which closely follow the research trend on intermittency-like phenomena in plasmas worldwide. We also present our analysis of particle flux data in order to test the recently proposed fluctuation theorem, which states that the probability of 'entropy consuming' flux events falls off exponentially with the averaging time. This theorem, proposed in the context of small systems, is applied to macroscopic system like tokamak edge plasma by invoking an 'effective temperature' of the bath of drift waves from which, plasma objects take energy and carry out work of transporting matter

  20. Conceptual Design, Implementation and Commissioning of Data Acquisition and Control System for Negative Ion Source at IPR

    SciTech Connect (OSTI)

    Soni, Jignesh; Gahlaut, A.; Bansal, G.; Parmar, K. G.; Pandya, K.; Chakraborty, A.; Yadav, Ratnakar; Singh, M. J.; Bandyopadhyay, M.


    Negative ion Experimental facility has been setup at IPR. The facility consists of a RF based negative ion source (ROBIN)--procured under a license agreement with IPP Garching, as a replica of BATMAN, presently operating in IPP, 100 kW 1 MHz RF generators and a set of low and high voltage power supplies, vacuum system and diagnostics. 35 keV 10A H- beam is expected from this setup. Automated successful operation of the system requires an advanced, rugged, time proven and flexible control system. Further the data generated in the experimental phase needs to be acquired, monitored and analyzed to verify and judge the system performance. In the present test bed, this is done using a combination of PLC based control system and a PXI based data acquisition system. The control system consists of three different Siemens PLC systems viz. (1) S-7 400 PLC as a Master Control, (2) S-7 300 PLC for Vacuum system control and (3) C-7 PLC for RF generator control. Master control PLC directly controls all the subsystems except the Vacuum system and RF generator. The Vacuum system and RF generator have their own dedicated PLCs (S-7 300 and C-7 respectively). Further, these two PLC systems work as a slave for the Master control PLC system. Communication between PLC S-7 400, S-7 300 and central control room computer is done through Industrial Ethernet (IE). Control program and GUI are developed in Siemens Step-7 PLC programming software and Wincc SCADA software, respectively. There are approximately 150 analog and 200 digital control and monitoring signals required to perform complete closed loop control of the system. Since the source floats at high potential ({approx}35 kV); a combination of galvanic and fiber optic isolation has been implemented. PXI based Data Acquisition system (DAS) is a combination of PXI RT (Real time) system, front end signal conditioning electronics, host system and DAQ program. All the acquisition signals coming from various sub-systems are connected and acquired by the PXI RT system, through only fiber optics link for signal conditioning, electrical isolation and better noise immunity. Real time and Host application programs are developed in LabVIEW and the data shall be stored with a facility of online display of selected parameters. Mathematical calculations and report generation will take place at the end of each beam shot. The paper describes in detail about the design approach, implementation strategy, program development, commissioning and operational test result of ROBIN through a data acquisition and control system.

  1. ipr61c3.tmp

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    * Research and Energy Efficiency: Selected Success Stories P. W. Garland R. W. Garland* *U.S. Department of Energy 1000 Independence Ave., SW Washington, DC 20585 to be presented at the Society of Women Engineers Convention Albuquerque, New Mexico June 26, 1997 Prepared by the OAK RIDGE NATIONAL LABOIL4TORY managed by LOCKHEED MARTIN ENERGY RESEARCH CORPORATION Oak Ridge, Tennessee 37831-2008 for the U.S. DEPARTMENT OF ENERGY under Contract No. DE-AC05-960R22464 "The submitted manuscript

  2. RAMATION V=W Ot TOTS= t sAy VnoffZW COMM1 AV 10i90 2M3 AM=W V A CLSI~LL331M A1N2UW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  3. 2014 IPR Workshop Additional Follow Ups

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    accounted for 36% of injuries. One of which is a severe fall from a tower. The Safety Perception Survey has been completed. A presentation on the findings will be made to the...

  4. Property:Tot cons | Open Energy Information

    Open Energy Info (EERE)

    + 4-County Electric Power Assn (Mississippi) EIA Revenue and Sales - December 2008 + 44,709 + 4-County Electric Power Assn (Mississippi) EIA Revenue and Sales - February 2008 +...

  5. CIR-2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Processes Integrated Program Review IPR 2012 IPR 2010 IPR 2009 IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic Capital...

  6. CIR 2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Processes Integrated Program Review IPR 2012 IPR 2010 IPR 2009 IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic Capital...

  7. Home

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Public Processes Integrated Program Review IPR 2012 IPR 2010 IPR 2009 IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic...

  8. Table 17. Estimated natural gas plant liquids and dry natural gas content of tot

    U.S. Energy Information Administration (EIA) Indexed Site

    Estimated natural gas plant liquids and dry natural gas content of total natural gas proved reserves, 2014" "million barrels and billion cubic feet" ,"Total Wet Natural Gas Proved Reserves",,,,"Estimated content of proved reserves" " State and Subdivision",,2014,,,"Natural Gas Plant Liquids",,"Dry Natural Gas" ,,"billion cubic feet",,,"million barrels",,"billion cubic feet"

  9. Implications of final L3 measurement of {sigma}{sub tot}({gamma}{gamma}{yields}bb)

    SciTech Connect (OSTI)

    Chyla, Jiri


    The excess of data on the total cross section of bb production in {gamma}{gamma} collisions over QCD predictions, observed by L3, OPAL and DELPHI Collaborations at LEP2, has so far defied explanation. The recent final analysis of L3 data has brought important new information concerning the dependence of the observed excess on the {gamma}{gamma} collisions energy W{sub {gamma}}{sub {gamma}}. The implications of this dependence are discussed.

  10. SRNL Site Map

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spacer 11/22/2013 SEARCH SRNL GO SRNL Home SRNL Site Map About SRNL From the Director Operational Excellence Leadership Our History Visiting SRNL Science & Innovation National Security Enviromental Stewardship Clean Energy Innovations Fact Sheets PDRD / LDRD Working with SRNL Technology Transfer Technology Partnerships Our Facilities Main Campus ACTL - Aiken County Technology Laboratory HTRL - Hydrogen Technology Research Laboratory EMRL - Energy Materials Research Laboratory F / H Lab

  11. ACML Example

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    totPEs, ierr ) allocate(dpset(totPEs)) C all processors working from the same random sequence, same seed seed(1) 1234 call drandinitialize(naggen,1,seed,1,state1,statesize,info)...

  12. USAJobs Search | Department of Energy

    Broader source: (indexed) [DOE]

    (TO), Technical Operations (TOT) organization. Transmission Services provides reliable open access, non-discriminatory transmission service on the Bonneville Power...

  13. East Central Energy (Wisconsin) | Open Energy Information

    Open Energy Info (EERE)

    (MWH) OTH CONS TOT REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 497.322 5,074.657 4,666 49.223 506.276 262 546.545 5,580.933 4,928 2009-02 617.038 6,336.617 4,668 59.259...

  14. City Utilities of Springfield | Open Energy Information

    Open Energy Info (EERE)

    ) OTH SALES (MWH) OTH CONS TOT REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 5,574.607 75,387.438 94,458 7,723.39 113,122.676 13,958 2,145.435 34,204.077 318 15,443.432...

  15. City of Independence, Missouri (Utility Company) | Open Energy...

    Open Energy Info (EERE)

    OTH CONS TOT REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 3,560.56 35,314.852 51,607 3,689.899 38,562.777 5,126 271.211 3,999.786 10 7,521.67 77,877.415 56,743 2009-02...

  16. City of Seattle, Washington (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    ) OTH SALES (MWH) OTH CONS TOT REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 23,601 373,913 353,104 24,986 456,778 39,325 4,440 92,495 220 3 47 3 53,030 923,233 392,652...

  17. PacifiCorp (Idaho) | Open Energy Information

    Open Energy Info (EERE)

    OTH CONS TOT REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 4,863.802 67,315.248 56,342 2,259.042 33,641.948 8,317 6,035.093 136,727.669 5,524 13,157.937 237,684.865 70,183...

  18. City of Kansas City, Kansas (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    SALES (MWH) OTH CONS TOT REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 3,262 40,087 56,891 5,911 77,724 7,095 3,466 64,803 94 12,639 182,614 64,080 2009-02 5,311 48,126 57,266...

  19. Empire District Electric Co (Kansas) | Open Energy Information

    Open Energy Info (EERE)

    OTH SALES (MWH) OTH CONS TOT REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 766.958 8,132.05 8,688 437.806 4,470.832 1,413 386.225 5,336.492 51 1,590.989 17,939.374 10,152...

  20. Consolidated Edison Co-NY Inc | Open Energy Information

    Open Energy Info (EERE)

    CONS TOT REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 180,424 829,996 2,282,842 177,132 1,007,995 393,452 2,556 15,772 240 104 656 5 360,216 1,854,419 2,676,539 2009-02...

  1. CIR-2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    prior to the Integrated Program Review (IPR). The CIR will cover transmission, federal hydro, facilities, information technology, energy efficiency, fish and wildlife, security,...

  2. Access to Capital

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic Capital Discussions Access to Capital Debt Optimization Asset Management Cost...

  3. 2011 Strategic Capital Discussions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic Capital Discussions Access to Capital Debt Optimization Asset Management Cost...

  4. Debt Optimization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IPR 2008 Capital Investment Review CIR 2012 Quarterly Business Review Focus 2028 2011 Strategic Capital Discussions Access to Capital Debt Optimization Asset Management Cost...

  5. BPA Power Rates (pbl/main)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rates, please see the transmission rates web site. Inactive Rate Cases Integrated Business Review (IBR) Integrated Program Review (IPR) Quarterly Business Review (QBR) Content...


    Office of Legacy Management (LM)

    ----L---... Lype tot-i basis of reccrds reviewed) n -No Radioactive ci Health Physics Protection . cj Little or None respansibility Natural Radioactive from Feed Materials ...

  7. Bulk sensitive determination of the Fe[superscript 3+]/Fe[subscript...

    Office of Scientific and Technical Information (OSTI)

    Title: Bulk sensitive determination of the Fesuperscript 3+Fesubscript Tot-ratio in minerals by Fe Lsubscript 23-edge X-ray Raman scattering Authors: Nyrow, Alexander ; ...

  8. L3:VUQ.SAUQ.P2-2.01 Brian Williams LANL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    distributions for DBCoeff based on two calibrations to crud index from F71 and F22 (green) and F71, F22, and F88 (blue). Figure 4 . Calibrated V IPRE---W boiling index...

  9. Integrated Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Review (IPR) Quarterly Business Review (QBR) Access to Capital Debt Management July 2013 Aug. 2013 Sept. 2013 Oct. 2013 Nov. 2013 Dec. 2013 Jan. 2014 Feb. 2014 March...

  10. Wells Rural Electric Co (Utah) | Open Energy Information

    Open Energy Info (EERE)

    TOT SALES (MWH) TOT CONS 2009-03 46 519 490 71 957 210 55 979 5 172 2,455 705 2009-02 52 607 492 69 1,045 211 46 797 5 167 2,449 708 2009-01 57 672 490 77 1,053 211 51 899 5 185...

  11. Dayton Power & Light Co | Open Energy Information

    Open Energy Info (EERE)

    REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 42,929 405,917 457,328 32,828 369,986 56,335 12,936 163,248 1,748 38 375 1 88,731 939,526 515,412 2009-02 50,501 495,479 457,129...

  12. McKenzie Electric Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 4.139 55.309 113 0.083 0.047 2 4.222 55.356 115 2009-02 5.066 56.074 114 0.083 0.044 2 5.149 56.118 116 2009-01 4.899 69.559 114...

  13. Neutron Library (ENDL82) in the transmittal format

    SciTech Connect (OSTI)

    Howerton, R.J.; Dye, R.E.; Perkins, S.T.


    There are four main libraries of data included within the system described. They are ENDL (Evaluated Neutron Data Library), ECPL (Evaluated Charged-Particle Data Library), ACTL (Evaluated Neutron-Induced Activation Cross-Section Library), and EGDL (Evaluated Photon Interaction Data Library). The first three deal with nuclear processes induced by neutrons or light charged particles (Z less than or equal to 2, A less than or equal to 4). The fourth (EGDL) contains the data appropriate to photons with energies between 100 eV and 100 MeV that interact with atoms of the elements in their ground state, i.e., cold targets. EGDL does not contain data for photonuclear reactions.

  14. Bulk sensitive determination of the Fe[superscript 3+]/Fe[subscript

    Office of Scientific and Technical Information (OSTI)

    Tot]-ratio in minerals by Fe L[subscript 2/3]-edge X-ray Raman scattering (Journal Article) | SciTech Connect Bulk sensitive determination of the Fe[superscript 3+]/Fe[subscript Tot]-ratio in minerals by Fe L[subscript 2/3]-edge X-ray Raman scattering Citation Details In-Document Search Title: Bulk sensitive determination of the Fe[superscript 3+]/Fe[subscript Tot]-ratio in minerals by Fe L[subscript 2/3]-edge X-ray Raman scattering Authors: Nyrow, Alexander ; Sternemann, Christian ; Tse,

  15. Whimsical SRS Relay Race Brings Joy to those in Need this Holiday...

    National Nuclear Security Administration (NNSA)

    race, which has raised 25,000 for the Savannah River Site's Toys for Tots campaign. Dozens of contractor employees at the Savannah River Site (SRS) recently combined zany fun ...

  16. Dash for Bikes, Walk for Trikes | National Nuclear Security Administra...

    National Nuclear Security Administration (NNSA)

    thousands of dollars each year for the Savannah River Site's annual Toys for Tots campaign. The fun is profitable enough to raise a significant amount of money to surprise...

  17. Phone Log: Spoke to: C.V. Chung I Date/Time: 5/29/14

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    L (CONTR) - TOT-D1TT-2 Subject: FW: Request for WECC Maps - by non-profit org Hello Kim: One of my staff members received this third-party request from WECC for a "BPA...

  18. Verdigris Valley Elec Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    ) TOT SALES (MWH) TOT CONS 2009-03 3,334 39,732 29,287 620 6,280 4,308 487 5,668 607 4,441 51,680 34,202 2009-02 3,065 36,726 29,285 456 4,469 4,299 405 4,606 607 3,926...

  19. UNS Electric, Inc | Open Energy Information

    Open Energy Info (EERE)

    REV (THOUSAND ) TOT SALES (MWH) TOT CONS 2009-03 5,500 45,911 79,490 5,666 46,579 10,607 2,748 28,348 20 13,914 120,838 90,117 2009-02 6,301 52,859 79,557 5,084 42,064 10,613...

  20. Otter Tail Power Co (North Dakota) | Open Energy Information

    Open Energy Info (EERE)

    ) TOT SALES (MWH) TOT CONS 2009-03 4,536 69,096 44,206 6,635 104,771 12,634 326 5,568 2 11,497 179,435 56,842 2009-02 4,919 69,170 44,146 6,370 97,635 12,601 334 6,444 2...

  1. Montana-Dakota Utilities Co | Open Energy Information

    Open Energy Info (EERE)

    ) TOT SALES (MWH) TOT CONS 2009-03 1,134 15,419 18,636 1,164 19,883 5,080 1,252 25,660 132 3,550 60,962 23,848 2009-02 1,069 14,377 18,635 1,136 19,109 5,099 1,198 23,937 132...

  2. Unexpected formal insertion of CO2 into the C-Si bonds of a zinc compound

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kemp, Richard A.; McGrew, Genette I.; Khatri, Pathik A.; Geiger, William E.; Waterman, Rory


    Reaction of [κ2-PR2C(SiMe3)Py]2Zn (R = Ph, 2a; iPr, 2b) with CO2 affords the products of formal insertion at the C–Si bond, [κ2-PR2CC(O)O(SiMe3)Py]2Zn (R = Ph, 3a; iPr, 3b). Insertion product 3b was structurally characterized. As a result, the reaction appears to be a stepwise insertion and rearrangement of CO2 based on kinetic data.

  3. Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process

    SciTech Connect (OSTI)

    Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark


    Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.


    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    does it again! Thursday, December 18, 2014 - 2:23pm Employees donate bikes, toys, time, cash for Toys for Tots Employees at the Nevada National Security Site have outdone themselves again this year by collecting 123 bicycles and 17 barrels of toys for this year's Toys for Tots campaign. The items will be distributed to children in the Las Vegas, Nev., area. Last year the Marine Corps fulfilled the holiday hopes and dreams of 6.8 million less fortunate children in 762 communities nationwide.

  5. NNSS does it again! | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    does it again! Thursday, December 18, 2014 - 2:23pm Employees donate bikes, toys, time, cash for Toys for Tots Employees at the Nevada National Security Site have outdone themselves again this year by collecting 123 bicycles and 17 barrels of toys for this year's Toys for Tots campaign. The items will be distributed to children in the Las Vegas, Nev., area. Last year the Marine Corps fulfilled the holiday hopes and dreams of 6.8 million less fortunate children in 762 communities nationwide.

  6. Preoperational radiation surveillance of the WIPP Project by EEG for the years 1993 - 1995

    SciTech Connect (OSTI)

    Kenney, J.W.; Gray, D.H.; Ballard, S.C.


    Average {sup 241}Am, {sup 239+240}Pu and {sup 238}Pu concentrations measured in ambient air near the Waste Isolation Pilot Plant (WIPP) site during 1993, 1994 and 1995 are consistent with similar data reported by the U.S. Environmental Protection Agency (EPA) and Los Alamos National Laboratory (LANL) for Espanola, Pojoaque and Santa Fe, New Mexico. Through the use of replicate analyses of matrix blanks minimum detectable activity (MDA), minimum detectable concentration (MDC) and action levels (ACTL) were established for the Environmental Evaluation Group (EEG) measurement system. Using MDA data from fixed air sampler (FAS) filters and conservative assumptions applied in the National Council on Radiation Protection and Measurements (NCRP) Report 123 (NCRP 1996), it is shown that the EEG sampling and measurement methodology is capable of detecting effluent air emissions which would produce a dose that is approximately 1000 times below the 40 CFR 191 Subpart A limit of 2.5E{sup -4} Sv/y (25 mrem/y). A similar calculation using the NCRP worksheet with storm water effluent MDCs found the EEG measurement program capable of detecting actinide emissions which would result in a dose that is approximately 10 times below the dose limits in 40 CFR 191 Subpart A and 40 CFR 61 Subpart H.

  7. Rapid, Reversible, Solid–Gas and Solution-Phase Insertion of CO 2 into In–P Bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dickie, Diane A.; Barker, Madeline T.; Land, Michael A.; Hughes, Kira E.; Clyburne, Jason A. C.; Kemp, Richard A.


    The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with 2 equiv of (i-Pr2P)2NLi in Et2O/tetrahydrofuran solution. Samples of [(i-Pr2P)2N]2InCl in a pentane slurry, a CH2Cl2 solution, or in the solid state were exposed to CO2, resulting in the insertion of CO2 into two of the four M–P bonds to produce [O2CP(i-Pr2)NP(i-Pr2)]2InCl in each case. These compounds were characterized by multinuclear NMR and IR spectroscopy, as well as single-crystal X-ray diffraction. ReactIR solution studies show that the reaction is complete in less than 1 min at room temperature in solution and in less thanmore »2 h in the solid–gas reaction. The CO2 complex is stable up to at least 60 °C under vacuum, but the starting material is regenerated with concomitant loss of carbon dioxide upon heating above 75 °C. Furthermore, the compound [(i-Pr2P)2N]2InCl also reacts with CS2 to give a complicated mixture of products, one of which was identified as the CS2 cleavage product [S=P(i-Pr2)NP(i-Pr2)]2InCl]2(?-Cl)[?-(i-Pr2P)2N)].« less

  8. ORISE: Postdoc Research Experiences - Dr. Sivaram Harendra

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sivaram Harendra Researcher looks to help power plants clean up Dr. Sivaram Harendra reseraches improvements to IPR systems at NETL. As part of his postdoctoral research appointment, Dr. Sivaram Harendra is part of a National Energy Technology Laboratory team focused on removing carbon dioxide from fossil-fueled power plant emissions in a process called Integrated Pollutant Removal. Rising carbon dioxide levels in the earth's atmosphere are a well-known fact. The levels have been on an upward

  9. Rapid, reversible, solid–gas and solution-phase insertion of CO2 into In–P bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dickie, Diane A.; Barker, Madeline T.; Land, Michael A.; Hughes, Kira E.; Clyburne, Jason A. C.; Kemp, Richard A.


    The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with 2 equiv of (i-Pr2P)2NLi in Et2O/tetrahydrofuran solution. Samples of [(i-Pr2P)2N]2InCl in a pentane slurry, a CH2Cl2 solution, or in the solid state were exposed to CO2, resulting in the insertion of CO2 into two of the four M–P bonds to produce [O2CP(i-Pr2)NP(i-Pr2)]2InCl in each case. These compounds were characterized by multinuclear NMR and IR spectroscopy, as well as single-crystal X-ray diffraction. ReactIR solution studies show that the reaction is complete in less than 1 min at room temperature in solution and in less thanmore » 2 h in the solid–gas reaction. The CO2 complex is stable up to at least 60 °C under vacuum, but the starting material is regenerated with concomitant loss of carbon dioxide upon heating above 75 °C. Furthermore, the compound [(i-Pr2P)2N]2InCl also reacts with CS2 to give a complicated mixture of products, one of which was identified as the CS2 cleavage product [S=P(i-Pr2)NP(i-Pr2)]2InCl]2(μ-Cl)[μ-(i-Pr2P)2N)].« less

  10. Toy to the World: Savannah River Site Celebrates 21 Years of Bringing Joy to Kids

    Broader source: [DOE]

    AIKEN, S.C. – Santa Claus and his elves are getting a lot of help from DOE’s Savannah River Site (SRS) this year. Federal employees and contractors donated more than 14,200 toys to support the U.S. Marine Reserves Toys for Tots campaign.

  11. Microsoft Word - Over-generation letter.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    R - TO-DITT2 Ellison,Richard A - TOD-DITT1 Elizeh,Edison G - TOT-DITT2 Enyeart,Stephen H - TPC-TPP-4 Ehli,Cathy L - TS-DITT-2 King,Robert D - TSP-TPP-2 Jackson,Mark A -...

  12. Nucleus-nucleus total reaction cross sections, and the nuclear interaction radius

    SciTech Connect (OSTI)

    Abu-Ibrahim, Badawy


    We study the nucleus-nucleus total reaction cross sections for stable nuclei, in the energy region from 30A MeV to about 1A GeV, and find them to be in proportion to ({radical}({sigma}{sub pp}{sup tot}Z{sub 1}{sup 2/3}+{sigma}{sub pn}{sup tot}N{sub 1}{sup 2/3})+{radical}({sigma}{sub pp}{sup tot}Z{sub 2}{sup 2/3}+{sigma}{sub pn}{sup tot}N{sub 2}{sup 2/3})) {sup 2} in the mass range 8 to 100. Also, we find a parameter-free relation that enables us to predict a total reaction cross section for any nucleus-nucleus within 10% uncertainty at most, using the experimental value of the total reaction cross section of a given nucleus-nucleus. The power of the relation is demonstrated by several examples. The energy dependence of the nuclear interaction radius is deduced; it is found to be almost constant in the energy range from about 200A MeV to about 1A GeV; in this energy range and for nuclei with N=Z, R{sub I}(A)=(1.14{+-}0.02)A{sup 1/3} fm.

  13. Table of tables: A database design tool for SYBASE

    SciTech Connect (OSTI)

    Brown, B.C.; Coulter, K.; Glass, H.D.; Glosson, R.; Hanft, R.W.; Harding, D.J.; Trombly-Freytag, K.; Walbridge, D.G.C.; Wallis, D.B. ); Allen, M.E. )


    The Table of Tables' application system captures in a set of SYBASE tables the basic design specification for a database schema. Specification of tables, columns (including the related defaults and rules for the stored values) and keys is provided. The feature which makes this application specifically useful for SYBASE is the ability to automatically generate SYBASE triggers. A description field is provided for each database object. Based on the data stored, SQL scripts for creating complete schema including the tables, their defaults and rules, their indexes, and their SYBASE triggers, are written by TOT. Insert, update and delete triggers are generated from TOT to guarantee integrity of data relations when tables are connected by single column foreign keys. The application is written in SYBASE's APT-SQL and includes a forms based data entry system. Using the features of TOT we can create a complete database schema for which the data integrity specified by our design is guaranteed by the SYBASE triggers generated by TOT. 3 refs.

  14. A practical strategy for reducing the future security risk of United States spent nuclear fuel

    SciTech Connect (OSTI)

    Chodak, P. III; Buksa, J.J.


    Depletion calculations show that advanced oxide (AOX) fuels can be used in existing light water reactors (LWRs) to achieve and maintain virtually any desired level of US (US) reactor-grade plutonium (R-Pu) inventory. AOX fuels are composed of a neutronically inert matrix loaded with R-Pu and erbium. A 1/2 core load of 100% nonfertile, 7w% R-Pu AOX and 3.9 w% UO{sub 2} has a net total plutonium ({sup TOT}Pu) destruction rate of 310 kg/yr. The 20% residual {sup TOT}Pu in discharged AOX contains > 55% {sup 242}Pu making it unattractive for nuclear explosive use. A three-phase fuel-cycle development program sequentially loading 60 LWRs with 100% mixed oxide, 50% AOX with a nonfertile component displacing only some of the {sup 238}U, and 50% AOX, which is 100% nonfertile, could reduce the US plutonium inventory to near zero by 2050.

  15. Pyroelectric response mechanism of barium strontium titanate ceramics in dielectric bolometer mode: The underlying essence of the enhancing effect of direct current bias field

    SciTech Connect (OSTI)

    Mao, Chaoliang; Cao, Sheng; Yan, Shiguang; Yao, Chunhua; Cao, Fei; Wang, Genshui; Dong, Xianlin; Hu, Xu; Yang, Chunli


    Pyroelectric response mechanism of Ba{sub 0.70}Sr{sub 0.30}TiO{sub 3} ceramics under dielectric bolometer (DB) mode was investigated by dielectric and pyroelectric properties measurement. The variations of total, intrinsic, and induced pyroelectric coefficients (p{sub tot}, p{sub int}, p{sub ind}) with temperatures and bias fields were analyzed. p{sub int} plays the dominant role to p{sub tot} through most of the temperature range and p{sub ind} will be slightly higher than p{sub int} above T{sub 0}. The essence of the enhancing effect of DC bias field on pyroelectric coefficient can be attributed to the high value of p{sub int}. This mechanism is useful for the pyroelectric materials (DB mode) applications.

  16. Provo City Corp (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    (MWH) TOT CONS 2009-03 1,368 18,290 30,311 1,749 28,411 4,779 437 10,070 1 3,554 56,771 35,091 2009-02 1,552 20,914 30,371 1,847 31,146 4,792 451 10,886 1 3,850 62,946 35,164...

  17. Electron-Cloud Build-Up Simulations for the FNAL Main Injector

    SciTech Connect (OSTI)

    Furman, Miguel .A.


    We present a summary on ongoing simulation results for the electron-cloud (EC) buildup in the context of the proposed FNAL Main Injector (MI) intensity upgrade effort [1]. Most of the results presented here are for the field-free region at the location of the retarding field analyzer (RFA) electron detector [2-4]. The primary input variable we exercise is the peak secondary electron yield (SEY) {delta}{sub max}, which we let vary in the range 1.2 {le} {delta}{sub max} {le} 1.7. By combining our simulated results for the electron flux at the vacuum chamber wall with the corresponding RFA measurements we infer that 1.25 {approx}< {delta}{sub max} {approx}< 1.35 at this location. From this piece of information we estimate features of the EC distribution for various fill patterns, including the average electron number density n{sub e}. We then compare the behavior of the EC for a hypothetical RF frequency f{sub RF} = 212 MHz with the current 53 MHz for a given total beam population N{sub tot}. The density n{sub e} goes through a clear threshold as a function of N{sub tot} in a field-free region. As expected, the higher frequency leads to a weaker EC effect: the threshold in N{sub tot} is a factor {approx} 2 higher for f{sub RF} = 212 MHz than for 53 MHz, and ne is correspondingly lower by a factor {approx} 2 when N{sub tot} is above threshold. We briefly describe further work that needs to be carried out, sensitivities in the calculation, and puzzles in the results that remain to be addressed.

  18. PacifiCorp | Open Energy Information

    Open Energy Info (EERE)

    (MWH) TOT CONS 2009-03 4,513.328 40,300.371 35,420 2,957.385 28,242.692 7,794 295.18 3,403.742 1,964 7,765.893 71,946.805 45,178 2009-02 4,309.919 37,789.644 35,472 2,584.65...

  19. Montana-Dakota Utilities Co | Open Energy Information

    Open Energy Info (EERE)

    TOT CONS 2009-03 1,134 15,419 18,636 1,164 19,883 5,080 1,252 25,660 132 3,550 60,962 23,848 2009-02 1,069 14,377 18,635 1,136 19,109 5,099 1,198 23,937 132 3,403 57,423 23,866...

  20. Surprise Valley Electrification Corp. (Oregon) | Open Energy...

    Open Energy Info (EERE)

    TOT CONS 2009-03 108.007 1,617.292 1,134 21.619 300.164 336 14.159 214.616 248 143.785 2,132.072 1,718 2009-02 122.657 1,866.778 1,135 23.915 339.757 336 15.181 254.511 248 161.753...

  1. Inflow performance relationships for solution-gas-drive reservoirs

    SciTech Connect (OSTI)

    Camacho-V, R.G.; Raghavan, R.


    In this theoretical study, a numerical model was used to examine the influence of pressure level and skin factor on the inflow performance relationships (IPR's) of wells producing under solution-gas-drive systems. Examination of the synthetic deliverability curves suggests that the exponent of the deliverability curve is a function of time and that the exponent is usually greater than unity. The implication of this observation to field data is discussed. The accuracy of procedures given in the literature to predict oilwell deliverabilities is also examined. It is shown that these methods can be used to predict future performance provided that the exponent of the deliverability curve is known and that extrapolations over large time ranges are avoided. If single-point tests are used to predict future performance (such tests assume that the exponent of the deliverability curve is constant), then errors in predictions will be minimized. Although relative permeability and fluid property data are required, the Muskat material-balance equation and the assumption that GOR is independent of distance can be used to predict future production rates. This method avoids problems associated with other methods in the literature and always yields reliable results. New methods to modify the IPR curve to incorporate changes in skin factor are presented. A new flow-efficiency definition based on the structure of the deliverability equations for solution-gas-drive reservoirs is proposed. This definition avoids problems that result when the currently available methods are applied to heavily stimulated wells.

  2. White House Women's Leadership Summit on Climate and Energy recognizes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Nuclear Security Administration Whimsical SRS Relay Race Brings Joy to those in Need this Holiday Season Wednesday, December 23, 2015 - 12:00am NNSA Blog SRS contractor employees compete in the fifth annual "Dash for Bikes, Walk for Trikes" relay race, which has raised $25,000 for the Savannah River Site's Toys for Tots campaign. Dozens of contractor employees at the Savannah River Site (SRS) recently combined zany fun with athletic competition to create a race like no

  3. CG Q/v

    Office of Legacy Management (LM)

    ,_ . _ . . .*r, .- ., * ' . , ; ' . c 6 L - ) e.' ,c? . . E& .,, BP * CG Q/v - c: / I k@ 2 1 ' . , w? _ ._ _. I_ ._ _ ..- -.. ._ . - -. A1IcA coot .' I UT, /O-L ' -f 3c" TRACERLAB . ,* OIY,S,Ota OF LAmOaATOnT ron C~CctnON~es, IYC. . 1 I ISOl tRAPCl.0 ROAD l WALTHAH 84, MASSACnUSETTS I. I I lww,roo* 4-0000 CIICL T;;o".S. ' / LFL I . i I . .z -- , - . . January 16, 1964 . . . . Tot Maywood Chemical Company Maywood, New Jersey' : . From:, Tracerlab, Inc. - / Walkham, Mass. . . ' I . .

  4. Kinetic and Mechanistic Studies of Carbon-to-Metal Hydrogen Atom Transfer Involving Os-Centered Radicals: Evidence for Tunneling

    SciTech Connect (OSTI)

    Lewandowska-Androlojc, Anna; Grills, David C.; Zhang, Jie; Bullock, R. Morris; Miyazawa, Akira; Kawanishi, Yuji; Fujita, Etsuko


    We have investigated the kinetics of novel carbon-to-metal hydrogen atom transfer reactions, in which homolytic cleavage of a C-H bond is accomplished by a single metal-centered radical. Studies by means of time-resolved IR spectroscopic measurements revealed efficient hydrogen atom transfer from xanthene, 9,10-dihydroanthracene and 1,4-cyclohexadiene to Cp(CO)2Os• and (n5-iPr4C5H)(CO)2Os• radicals, formed by photoinduced homolysis of the corresponding osmium dimers. The rate constants for hydrogen abstraction from these hydrocarbons were found to be in the range 1.54 × 105 M 1 s 1 -1.73 × 107 M 1 s-1 at 25 °C. For the first time, kinetic isotope effects for carbon-to-metal hydrogen atom transfer were determined. Large primary kinetic isotope effects of 13.4 ± 1.0 and 16.6 ± 1.4 were observed for the hydrogen abstraction from xanthene to form Cp(CO)2OsH and (n5-iPr4C5H)(CO)2OsH, respectively, at 25 °C. Temperature-dependent measurements of the kinetic isotope effects over a 60 -C temperature range were carried out to obtain the difference in activation energies and the pre-exponential factor ratio. For hydrogen atom transfer from xanthene to (n5-iPr4C5H)(CO)2Os•, the (ED - EH) = 3.25 ± 0.20 kcal/mol and AH/AD = 0.056 ± 0.018 values are greater than the semi-classical limits and thus suggest a quantum mechanical tunneling mechanism. The work at BNL was carried out under contract DE-AC02-98CH10886 with the U.S. Department of Energy and supported by its Division of Chemical Sciences, Geosciences & Biosciences, Office of Basic Energy Sciences. RMB also thanks the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences for support. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  5. Relativistic electrons and magnetic fields of the M87 jet on the ?10 Schwarzschild radii scale

    SciTech Connect (OSTI)

    Kino, M.; Takahara, F.; Hada, K.; Doi, A.


    We explore energy densities of the magnetic fields and relativistic electrons in the M87 jet. Since the radio core at the jet base is identical to the optically thick surface against synchrotron self-absorption (SSA), the observing frequency is identical to the SSA turnover frequency. As a first step, we assume the radio core has a simple uniform sphere geometry. Using the observed angular size of the radio core measured by the Very Long Baseline Array at 43 GHz, we estimate the energy densities of magnetic fields (U{sub B} ) and relativistic electrons (U{sub e} ) on the basis of the standard SSA formula. Imposing the condition that the Poynting power and kinetic power of relativistic electrons should be smaller than the total power of the jet, we find that (1) the allowed range of the magnetic field strength (B {sub tot}) is 1 G ? B {sub tot} ? 15 G and that (2) 1 × 10{sup –5} ? U{sub e} /U{sub B} ? 6 × 10{sup 2} holds. The uncertainty of U{sub e} /U{sub B} comes from the strong dependence on the angular size of the radio core and the minimum Lorentz factor of non-thermal electrons (? {sub e,min}) in the core. It is still unsettled whether resultant energetics are consistent with either the magnetohydrodynamic jet or the kinetic power dominated jet even on the ?10 Schwarzschild radii scale.

  6. Accuracy of the centrifugal sudden approximation in the H + CHD{sub 3} → H{sub 2} + CD{sub 3} reaction

    SciTech Connect (OSTI)

    Zhang, Zhaojun; Chen, Jun; Liu, Shu; Zhang, Dong H.


    The initial state selected time-dependent wave packet method has been extended to calculate the coupled-channel reaction probabilities with total angular momentum J{sub tot} > 0 for the title reaction with seven degrees of freedom included. Fully converged integral cross sections were obtained for the ground and a number of vibrational excited initial states on a new potential energy surface recently constructed by this group using neural network fitting. As found from a previous study with the centrifugal sudden (CS) approximation, all these initial vibrational excitations investigated in this study enhance the reactivity considerably at a given collision energy, in particular the CH stretch excited state. The energy initially deposited in CH stretch motion is more effective than translational energy on promoting the reaction in the entire energy region, while for CH bending or CD{sub 3} umbrella excitations only at the high collision energy the vibrational energy becomes more effective. Our calculations also revealed that the accuracy of the CS approximation considerably deteriorates with the increase of J{sub tot}, in particular on the threshold energy. The CS approximation underestimates the integral cross sections for all these initial states, albeit not very severely. In general, it works better at high collision energies and for vibrationally excited initial states, with the increase of integral cross section.

  7. Buildings Energy Data Book: 6.1 Electric Utility Energy Consumption

    Buildings Energy Data Book [EERE]

    4 U.S. Electricity Net Generation, by Plant Type (Billion kWh) Renewables Growth Rate Hydr(1) Oth(2) Total CHP (3) Tot.(4) 2010-year 1980 276 6 282 N.A. 1981 261 6 267 N.A. 1982 309 5 314 N.A. 1983 332 6 339 N.A. 1984 321 9 330 N.A. 1985 281 11 292 N.A. 1986 291 12 302 N.A. 1987 250 12 262 N.A. 1988 223 12 235 N.A. 1989 269 28 297 42 1990 290 35 324 61 1991 286 38 324 72 1992 250 40 290 91 1993 278 42 320 108 1994 254 42 296 123 1995 305 39 345 141 1996 341 41 382 147 1997 351 41 392 148 1998

  8. A new measurement of the rare decay eta -> pi^0 gamma gamma with the Crystal Ball/TAPS detectors at the Mainz Microtron

    SciTech Connect (OSTI)

    Nefkens, B M; Prakhov, S; Aguar-Bartolom��, P; Annand, J R; Arends, H J; Bantawa, K; Beck, R; Bekrenev, V; Bergh��user, H; Braghieri, A; Briscoe, W J; Brudvik, J; Cherepnya, S; Codling, R F; Collicott, C; Costanza, S; Danilkin, I V; Denig, A; Demissie, B; Dieterle, M; Downie, E J; Drexler, P; Fil'kov, L V; Fix, A; Garni, S; Glazier, D I; Gregor, R; Hamilton, D; Heid, E; Hornidge, D; Howdle, D; Jahn, O; Jude, T C; Kashevarov, V L; K��ser, A; Keshelashvili, I; Kondratiev, R; Korolija, M; Kotulla, M; Koulbardis, A; Kruglov, S; Krusche, B; Lisin, V; Livingston, K; MacGregor, I J; Maghrbi, Y; Mancel, J; Manley, D M; McNicoll, E F; Mekterovic, D; Metag, V; Mushkarenkov, A; Nikolaev, A; Novotny, R; Oberle, M; Ortega, H; Ostrick, M; Ott, P; Otte, P B; Oussena, B; Pedroni, P; Polonski, A; Robinson, J; Rosner, G; Rostomyan, T; Schumann, S; Sikora, M H; Starostin, A; Strakovsky, I I; Strub, T; Suarez, I M; Supek, I; Tarbert, C M; Thiel, M; Thomas, A; Unverzagt, M; Watts, D P; Werthmueller, D; Witthauer, L


    A new measurement of the rare, doubly radiative decay eta->pi^0 gamma gamma was conducted with the Crystal Ball and TAPS multiphoton spectrometers together with the photon tagging facility at the Mainz Microtron MAMI. New data on the dependence of the partial decay width, Gamma(eta->pi^0 gamma gamma), on the two-photon invariant mass squared, m^2(gamma gamma), as well as a new, more precise value for the decay width, Gamma(eta->pi^0 gamma gamma) = (0.33+/-0.03_tot) eV, are based on analysis of 1.2 x 10^3 eta->pi^0 gamma gamma decays from a total of 6 x 10^7 eta mesons produced in the gamma p -> eta p reaction. The present results for dGamma(eta->pi^0 gamma gamma)/dm^2(gamma gamma) are in good agreement with previous measurements and recent theoretical calculations for this dependence.

  9. LANL: AOT & LANSCE The Pulse October 2011

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 3 From Alex's Desk 3 NeutroN scAtteriNg proviDes iNsight iNto eNzymAtic DegrADAtioN oF cellulose 4 NeutroN totAl scAtteriNg moNitors shiFts iN vAleNce stAtes 5 NeutroN reFlec- tometry exAmiNes the perFormANce oF rADiAtioN-resistANt mAteriAls 6 meAsuriNg the FissioN NeutroN spectrum At lANsce 7 heADs up! Daniel Shoemaker receives


    SciTech Connect (OSTI)

    Halfen, D. T.; Ziurys, L. M.; Ilyushin, V. E-mail:


    Extensive observations of acetamide (CH{sub 3}CONH{sub 2}) and formamide (NH{sub 2}CHO) have been conducted toward Sgr B2(N) at 1, 2, and 3 mm using the Submillimeter Telescope (SMT) and the 12 m antenna of the Arizona Radio Observatory. Over the frequency range 65-280 GHz, 132 transitions of acetamide have been observed as individual, distinguishable features, although in some cases they are partially blended. The unblended transitions in acetamide indicate V{sub LSR} = 63.2 {+-} 2.8 km s{sup -1} and {Delta}V{sub 1/2} = 12.5 {+-} 2.9 km s{sup -1}, line parameters that are very similar to that of formamide (NH{sub 2}CHO) and other organic species in Sgr B2(N). For formamide, 79 individual transitions were identified over the same frequency region. Rotational diagram analyses indicate the presence of two components for both species in Sgr B2(N). For acetamide, the colder component (E{sub u} < 40 K) exhibits a rotational temperature of T{sub rot} = 17 {+-} 4 K and a column density of N{sub tot} = 5.2 {+-} 3.5 Multiplication-Sign 10{sup 13} cm{sup -2}; the higher energy component has T{sub rot} = 171 {+-} 4 K and N{sub tot} = 6.4 {+-} 4.7 Multiplication-Sign 10{sup 14} cm{sup -2}. In the case of formamide, T{sub rot} = 26 {+-} 4 K and N{sub tot} = 1.6 {+-} 0.7 Multiplication-Sign 10{sup 14} cm{sup -2} for the colder component with T{sub rot} = 134 {+-} 17 K and N{sub tot} = 4.0 {+-} 1.2 Multiplication-Sign 10{sup 14} cm{sup -2} for the warmer region. The fractional abundances of acetamide are f (H{sub 2}) = 1.7 Multiplication-Sign 10{sup -11} and 2.1 Multiplication-Sign 10{sup -10} for the cold and warm components, and in formamide, f (H{sub 2}) = 5.3 Multiplication-Sign 10{sup -11} and 1.3 Multiplication-Sign 10{sup -10}. The similarity between the abundances and distributions of CH{sub 3}CONH{sub 2} and NH{sub 2}CHO suggests a synthetic connection. The abundance of acetamide, moreover, is only a factor of three lower than that of formaldehyde, and very similar to acetaldehyde and ketene. CH{sub 3}CONH{sub 2} is therefore one of the most abundant complex organic species in Sgr B2(N), and could be a possible source of larger peptide molecules, as opposed to amino acids.


    SciTech Connect (OSTI)

    Forero-Romero, J. E.; Hoffman, Y.; Bustamante, S.; Gottloeber, S.; Yepes, G.


    Recent observations constrained the tangential velocity of M31 with respect to the Milky Way to be v{sub M31,tan} < 34.4 km s{sup -1}and the radial velocity to be in the range v{sub M31,rad} = -109 {+-} 4.4 km s{sup -1}. In this study we use a large volume high-resolution N-body cosmological simulation (Bolshoi) together with three constrained simulations to statistically study this kinematics in the context of the {Lambda} cold dark matter ({Lambda}CDM). The comparison of the ensembles of simulated pairs with the observed Local Group (LG) at the 1{sigma} level in the uncertainties has been done with respect to the radial and tangential velocities, the reduced orbital energy (e{sub tot}), angular momentum (l{sub orb}), and the dimensionless spin parameter, {lambda}. Our main results are (1) the preferred radial and tangential velocities for pairs in {Lambda}CDM are v{sub r} = -80 {+-} 20 km s{sup -1} and v{sub t} = 50 {+-} 10 km s{sup -1}, (2) pairs around that region are 3-13 times more common than pairs within the observational values, (3) 15%-24% of LG-like pairs in {Lambda}CDM have energy and angular momentum consistent with observations, while (4) 9%-13% of pairs in the same sample show similar values in the inferred dimensionless spin parameter. It follows that within current observational uncertainties the quasi-conserved quantities that characterize the orbit of the LG, i.e., e{sub tot}, l{sub orb}, and {lambda}, do not challenge the standard {Lambda}CDM model, but the model is in tension with regard to the actual values of the radial and tangential velocities. This might hint to a problem of the {Lambda}CDM model to reproduce the observed LG.


    SciTech Connect (OSTI)

    Wong, Kenneth C.; Suyu, Sherry H.; Tran, Kim-Vy H.; Papovich, Casey J.; Momcheva, Ivelina G.; Brammer, Gabriel B.; Koekemoer, Anton M.; Brodwin, Mark; Gonzalez, Anthony H.; Kacprzak, Glenn G.; Rudnick, Gregory H.; Halkola, Aleksi


    We identify a strong lensing galaxy in the cluster IRC 0218 (also known as XMM-LSS J02182–05102) that is spectroscopically confirmed to be at z = 1.62, making it the highest-redshift strong lens galaxy known. The lens is one of the two brightest cluster galaxies and lenses a background source galaxy into an arc and a counterimage. With Hubble Space Telescope (HST) grism and Keck/LRIS spectroscopy, we measure the source redshift to be z {sub S} = 2.26. Using HST imaging in ACS/F475W, ACS/F814W, WFC3/F125W, and WFC3/F160W, we model the lens mass distribution with an elliptical power-law profile and account for the effects of the cluster halo and nearby galaxies. The Einstein radius is ?{sub E}=0.38{sub ?0.01}{sup +0.02} arcsec (3.2{sub ?0.1}{sup +0.2} kpc) and the total enclosed mass is M {sub tot}(tot}=2.1{sub ?0.3}{sup +0.4}. The source has at least one bright compact region offset from the source center. Emission from Ly? and [O III] are likely to probe different regions in the source.

  13. Optimizing artificial lift operations through the use of wireless conveyed real time bottom hole data

    SciTech Connect (OSTI)

    Campbell, B.; MacKinnon, J.; Bandy, T.R.; Hampton, T.


    The use of an innovative wireless bottom hole pressure/temperature telemetry acquisition system in artificial lift operations can dramatically improve efficiency and optimize fluid producing rates in those wells. The tool is installed into the producing well in the vicinity of the perforations, measuring and transmitting the producing bottom hole pressures and temperatures to the surface for instantaneous control of the surface pumping motor speed. This insures the lowest possible fluid level back pressures, thus allowing for the highest possible fluid entry into the wellbore from that reservoir`s capacity. Operating costs per barrel are lowered since the maximum oil production can now be realized from existing wells. The telemetry tool is deployed with standard slickline equipment and is installed inside a well in a manner similar to ordinary pressure recorder tools. Several unique advantages of the tool are: (1) no moving parts; (2) no wireline to the surface; (3) real time measurement of bottom hole data; and (4) slickline retrievable. Future versions of the acquisition system tool will improve operating efficiency in the following ways: (1) Temperature monitoring and control of perforation scaling, tubular waxing, and tubular hydrating plugs. (2) Provide data necessary to create diagnostically predictive IPR curves through monitoring of reservoir in-flow rates. (3) Enabling early warning of water encroachment or lensing through fluid resistivity monitoring.

  14. Characteristics of the positive ion source at reduced gas feed

    SciTech Connect (OSTI)

    Sharma, S. K. Bharathi, P.; Prahlad, V.; Patel, P. J.; Choksi, B.; Jana, M. R.; Bansal, L. K.; Qureshi, K.; Sumod, C. B.; Vadher, V.; Thakkar, D.; Gupta, L. N.; Rambabu, S.; Parmar, S.; Contractor, N.; Sahu, A. K.; Pandya, B.; Sridhar, B.; Pandya, S.; Baruah, U. K.


    The neutral beam injector of steady state superconducting tokamak (SST1-NBI) at IPR is designed for injecting upto 1.7 MW of neutral beam (Hº, 30–55 keV) power to the tokamak plasma for heating and current drive. Operations of the positive ion source (PINI or Plug-In-Neutral-Injector) of SST1-NBI were carried out on the NBI test stand. The PINI was operated at reduced gas feed rate of 2–3 Torr l/s, without using the high speed cryo pumps. Experiments were conducted to achieve a stable beam extraction by optimizing operational parameters namely, the arc current (120–300 A), acceleration voltage (16–40 kV), and a suitable control sequence. The beam divergence, power density profiles, and species fractions (H{sup +}:H{sub 2}{sup +}:H{sub 3}{sup +}) were measured by using the diagnostics such as thermal calorimetry, infrared thermography, and Doppler shift spectroscopy. The maximum extracted beam current was about 18 A. A further increase of beam current was found to be limited by the amount of gas feed rate to the ion source.

  15. Noise, sampling, and the number of projections in cone-beam CT with a flat-panel detector

    SciTech Connect (OSTI)

    Zhao, Z.; Gang, G. J.; Siewerdsen, J. H.


    Purpose: To investigate the effect of the number of projection views on image noise in cone-beam CT (CBCT) with a flat-panel detector. Methods: This fairly fundamental consideration in CBCT system design and operation was addressed experimentally (using a phantom presenting a uniform medium as well as statistically motivated “clutter”) and theoretically (using a cascaded systems model describing CBCT noise) to elucidate the contributing factors of quantum noise (?{sub Q}), electronic noise (?{sub E}), and view aliasing (?{sub view}). Analysis included investigation of the noise, noise-power spectrum, and modulation transfer function as a function of the number of projections (N{sub proj}), dose (D{sub tot}), and voxel size (b{sub vox}). Results: The results reveal a nonmonotonic relationship between image noise andN{sub proj} at fixed total dose: for the CBCT system considered, noise decreased with increasing N{sub proj} due to reduction of view sampling effects in the regime N{sub proj} tot}, and b{sub vox}. Conclusions: The work elucidates fairly basic elements of CBCT noise in a manner that demonstrates the role of distinct noise components (viz., quantum, electronic, and view sampling noise). For configurations fairly typical of CBCT with a flat-panel detector (FPD), the analysis reveals a “sweet spot” (i.e., minimum noise) in the rangeN{sub proj} ? 250–350, nearly an order of magnitude lower in N{sub proj} than typical of multidetector CT, owing to the relatively high electronic noise in FPDs. The analysis explicitly relates view aliasing and quantum noise in a manner that includes aspects of the object (“clutter”) and imaging chain (including nonidealities of detector blur and electronic noise) to provide a more rigorous basis for commonly held intuition and heurism in CBCT system design and operation.


    SciTech Connect (OSTI)

    Fan, X. L. [School of Physics and Electronics Information, Hubei University of Education, 430205 Wuhan (China); Pipino, A. [Institut fur Astronomie, ETH Zurich, CH-8093 Zurich (Switzerland); Matteucci, F., E-mail: [Dipartimento di Fisica, Sezione di Astronomia, Universit a di Trieste, via G.B. Tiepolo 11, I-34131 Trieste (Italy)


    The stacked spectral energy distribution (SED) 24 {mu}m Lyman break galaxies (MIPS-LBGs) detected by the Multiband Imaging Photometer for Spitzer (MIPS) is fitted by means of the spectrophotometric model GRASIL with an ''educated'' fitting approach which benefits from the results of chemical evolution models. The star formation rate-age-metallicity degeneracies of SED modeling are broken by using star formation history (SFH) and chemical enrichment history suggested by chemical models. The dust mass, dust abundance, and chemical pattern of elements locked in the dust component are also directly provided by chemical models. Using our new ''fitting'' approach, we derive the total mass M{sub tot}, stellar mass M{sub *}, gas mass M{sub g} , dust mass M{sub d} , age, and star formation rate (SFR) of the stacked MIPS-LBG in a self-consistent way. Our estimate of M{sub *} = 8 Multiplication-Sign 10{sup 10} of the stacked MIPS-LBG agrees with other works based on UV-optical SED fitting. We suggest that the MIPS-LBGs at z {approx} 3 are young (0.3-0.6 Gyr), massive (M{sub tot} {approx} 10{sup 11} M{sub Sun }), dusty (M{sub d} {approx} 10{sup 8} M{sub Sun }), and metal-rich (Z {approx} Z{sub Sun }) progenitors of elliptical galaxies undergoing a strong burst of star formation (SFR {approx} 200 M{sub Sun} yr{sup -1}). Our estimate of M{sub d} = 7 Multiplication-Sign 10{sup 7} M{sub Sun} of the stacked MIPS-LBG is about a factor of eight lower than the estimated value based on single temperature graybody fitting, suggesting that self-consistent SED models are needed to estimate dust mass. By comparing with Milky Way molecular cloud and dust properties, we suggest that denser and dustier environments and flatter dust size distribution are likely in high-redshift massive star-forming galaxies. These dust properties, as well as the different types of SFHs, can cause different SED shapes between high-redshift star-forming ellipticals and local starburst templates. This discrepancy of SED shapes could in turn explain the non-detection at submillimeter wavelengths of IR luminous (L{sub IR} Succeeds-Above-Single-Line-Equals-Sign 10{sup 12} L{sub Sun }) MIPS-LBGs.


    SciTech Connect (OSTI)

    Koopman, D.


    Lab-scale DWPF simulations of Sludge Batch 7b (SB7b) processing were performed. Testing was performed at the Savannah River National Laboratory - Aiken County Technology Laboratory (SRNL-ACTL). The primary goal of the simulations was to define a likely operating window for acid stoichiometry for the DWPF Sludge Receipt and Adjustment Tank (SRAT). In addition, the testing established conditions for the SRNL Shielded Cells qualification simulation of SB7b-Tank 40 blend, supported validation of the current glass redox model, and validated the coupled process flowsheet at the nominal acid stoichiometry. An acid window of 105-140% by the Koopman minimum acid (KMA) equation (107-142% DWPF Hsu equation) worked for the sludge-only flowsheet. Nitrite was present in the SRAT product for the 105% KMA run at 366 mg/kg, while SME cycle hydrogen reached 94% of the DWPF Slurry Mix Evaporator (SME) cycle limit in the 140% KMA run. The window was determined for sludge with added caustic (0.28M additional base, or roughly 12,000 gallons 50% NaOH to 820,000 gallons waste slurry). A suitable processing window appears to be 107-130% DWPF acid equation for sludge-only processing allowing some conservatism for the mapping of lab-scale simulant data to full-scale real waste processing including potentially non-conservative noble metal and mercury concentrations. This window should be usable with or without the addition of up to 7,000 gallons of caustic to the batch. The window could potentially be wider if caustic is not added to SB7b. It is recommended that DWPF begin processing SB7b at 115% stoichiometry using the current DWPF equation. The factor could be increased if necessary, but changes should be made with caution and in small increments. DWPF should not concentrate past 48 wt.% total solids in the SME cycle if moderate hydrogen generation is occurring simultaneously. The coupled flowsheet simulation made more hydrogen in the SRAT and SME cycles than the sludge-only run with the same acid stoichiometric factor. The slow acid addition in MCU seemed to alter the reactions that consumed the small excess acid present such that hydrogen generation was promoted relative to sludge-only processing. The coupled test reached higher wt.% total solids, and this likely contributed to the SME cycle hydrogen limit being exceeded at 110% KMA. It is clear from the trends in the SME processing GC data, however, that the frit slurry formic acid contributed to driving the hydrogen generation rate above the SME cycle limit. Hydrogen generation rates after the second frit addition generally exceeded those after the first frit addition. SRAT formate loss increased with increasing acid stoichiometry (15% to 35%). A substantial nitrate gain which was observed to have occurred after acid addition (and nitrite destruction) was reversed to a net nitrate loss in runs with higher acid stoichiometry (nitrate in SRAT product less than sum of sludge nitrate and added nitric acid). Increased ammonium ion formation was also indicated in the runs with nitrate loss. Oxalate loss on the order 20% was indicated in three of the four acid stoichiometry runs and in the coupled flowsheet run. The minimum acid stoichiometry run had no indicated loss. The losses were of the same order as the official analytical uncertainty of the oxalate concentration measurement, but were not randomly distributed about zero loss, so some actual loss was likely occurring. Based on the entire set of SB7b test data, it is recommended that DWPF avoid concentrating additional sludge solids in single SRAT batches to limit the concentrations of noble metals to SB7a processing levels (on a grams noble metal per SRAT batch basis). It is also recommended that DWPF drop the formic acid addition that accompanies the process frit 418 additions, since SME cycle data showed considerable catalytic activity for hydrogen generation from this additional acid (about 5% increase in stoichiometry occurred from the frit formic acid). Frit 418 also does not appear to need formic acid addition to prevent gel formation in

  18. Combined heat recovery and dry scrubbing for MWCs to meet the new EPA guidelines

    SciTech Connect (OSTI)

    Finnis, P.J.; Heap, B.M.


    Both the UK and US Municipal Waste Combuster (MWC) markets have undergone upgraded regulatory control. In the UK, the government`s Integrated Pollution Control (IPC) regime, enforced by the 1990 Environmental Protection Act (EPA) Standard IPR5/3 moved control of emissions of MWCs from local councils to the government Environmental Authority (EA). Existing MWCs had until December 1, 1996 to complete environmental upgrades. Simultaneously, the European Community (EC) was finalizing more stringent legislation to take place in the year 2001. In the US, the 1990 Clean Air Act amendments required the Environmental Protection Agency (EPA) to issue emission guidelines for new and existing facilities. Existing facilities are likely to have only until the end of 1999 to complete upgrades. In North America, Procedair Industries Corp had received contracts from Kvaerner EnviroPower AB, for APC systems of four new Refuse Derived Fuel (RDF) fluid bed boilers that incorporated low outlet temperature economizers as part of the original boiler equipment. The Fayetteville, North Carolina facility was designed for 200,000 tpy. What all these facilities have in common is low economizer outlet temperatures of 285{degrees}F coupled with a Total Dry Scrubbing System. MWC or RDF facilities using conventional spray dryer/fabric filter combinations have to have economizer gas outlet temperatures about 430{degrees}F to allow for evaporation of the lime slurry in the spray dryer without the likelihood of wall build up or moisture carry over. Since the Totally Dry Scrubbing System can operate with economizer gas outlet temperatures about 285{degrees}F, the added energy available for sale from adding low outlet temperature economizer heat recovery can be considerable. This paper focuses on Procedair`s new plant and retrofit experience using `Dry Venturi Reactor/Fabric Filter` combinations with the lower inlet temperature operating conditions.


    SciTech Connect (OSTI)

    Louie, Janis


    Our research program is broadly focused on activating CO{sub 2} through the use of organic and organometallic based catalysts. Some of our methods have centered on annulation reactions of unsaturated hydrocarbons (and carbonyl substrates) to provide a diverse array of carbocycles and heterocycles. We use a combination of catalyst discovery and optimization in conjunction with classical physical organic chemistry to elucidate the key mechanistic features of the cycloaddition reactions such that the next big advances in catalyst development can be made. Key to all of our cycloaddition reactions is the use of a sterically hindered, electron donating N heterocyclic carbene (NHC) ligand, namely IPr (or SIPr), in conjunction with a low valent nickel pre-catalyst. The efficacy of this ligand is two-fold: (1) the high {delta}-donating ability of the NHC increases the nucleophilicity of the metal center which thereby facilitates interaction with the electrophilic carbonyl and (2) the steric hindrance prevents an otherwise competitive side reaction involving only the alkyne substrate. Such a system has allowed for the facile cycloaddition to prepare highly functionalized pyrones, pyridones, pyrans, as well as novel carbocycles. Importantly, all reactions proceed under extremely mild conditions (room temperature, atmospheric pressures, and short reaction times), require only catalytic amounts of Ni/NHC and readily available starting materials, and afford annulated products in excellent yields. Our current focus revolves around understanding the fundamental processes that govern these cycloadditions such that the next big advance in the cyclization chemistry of CO{sub 2} can be made. Concurrent to our annulation chemistry is our investigation of the potential for imidazolylidenes to function as thermally-actuated CO{sub 2} sequestering and delivery agents.

  20. RF-Plasma Source Commissioning in Indian Negative Ion Facility

    SciTech Connect (OSTI)

    Singh, M. J.; Bandyopadhyay, M.; Yadava, Ratnakar; Chakraborty, A. K.; Bansal, G.; Gahlaut, A.; Soni, J.; Kumar, Sunil; Pandya, K.; Parmar, K. G.; Sonara, J.; Kraus, W.; Heinemann, B.; Riedl, R.; Obermayer, S.; Martens, C.; Franzen, P.; Fantz, U.


    The Indian program of the RF based negative ion source has started off with the commissioning of ROBIN, the inductively coupled RF based negative ion source facility under establishment at Institute for Plasma research (IPR), India. The facility is being developed under a technology transfer agreement with IPP Garching. It consists of a single RF driver based beam source (BATMAN replica) coupled to a 100 kW, 1 MHz RF generator with a self excited oscillator, through a matching network, for plasma production and ion extraction and acceleration. The delivery of the RF generator and the RF plasma source without the accelerator, has enabled initiation of plasma production experiments. The recent experimental campaign has established the matching circuit parameters that result in plasma production with density in the range of 0.5-1x10{sup 18}/m{sup 3}, at operational gas pressures ranging between 0.4-1 Pa. Various configurations of the matching network have been experimented upon to obtain a stable operation of the set up for RF powers ranging between 25-85 kW and pulse lengths ranging between 4-20 s. It has been observed that the range of the parameters of the matching circuit, over which the frequency of the power supply is stable, is narrow and further experiments with increased number of turns in the coil are in the pipeline to see if the range can be widened. In this paper, the description of the experimental system and the commissioning data related to the optimisation of the various parameters of the matching network, to obtain stable plasma of required density, are presented and discussed.

  1. Highly Luminescent Lanthanide Complexes of 1 Hydroxy-2-pyridinones

    SciTech Connect (OSTI)

    University of California, Berkeley; Lawrence National Laboratory; Raymond, Kenneth; Moore, Evan G.; Xu, Jide; Jocher, Christoph J.; Castro-Rodriguez, Ingrid; Raymond, Kenneth N.


    The synthesis, X-ray structure, stability, and photophysical properties of several trivalent lanthanide complexes formed from two differing bis-bidentate ligands incorporating either alkyl or alkyl ether linkages and featuring the 1-hydroxy-2-pyridinone (1,2-HOPO) chelate group in complex with Eu(III), Sm(III) and Gd(III) are reported. The Eu(III) complexes are among some of the best examples, pairing highly efficient emission ({Phi}{sub tot}{sup Eu} {approx} 21.5%) with high stability (pEu {approx} 18.6) in aqueous solution, and are excellent candidates for use in biological assays. A comparison of the observed behavior of the complexes with differing backbone linkages shows remarkable similarities, both in stability and photophysical properties. Low temperature photophysical measurements for a Gd(III) complex were also used to gain insight into the electronic structure, and were found to agree with corresponding TD-DFT calculations for a model complex. A comparison of the high resolution Eu(III) emission spectra in solution and from single crystals also revealed a more symmetric coordination geometry about the metal ion in solution due to dynamic rotation of the observed solid state structure.

  2. Me-3,2-HOPO Complexes of Near Infra-Red (NIR) Emitting Lanthanides: Efficient Sensitization of Yb(III) and Nd(III) in Aqueous Solution

    SciTech Connect (OSTI)

    Moore, Evan G.; Xu, Jide; Dodani, Sheel; Jocher, Christoph; D'Aleo, Anthony; Seitz, Michael; Raymond, Kenneth


    The synthesis, X-ray structure, solution stability, and photophysical properties of several trivalent lanthanide complexes of Yb(III) and Nd(III) using both tetradentate and octadentate ligand design strategies and incorporating the 1-methyl-3-hydroxy-pyridin-2-one (Me-3,2-HOPO) chelate group are reported. Both the Yb(III) and Nd(III) complexes have emission bands in the Near Infra-Red (NIR) region, and this luminescence is retained in aqueous solution ({Phi}{sub tot}{sup Yb} {approx} 0.09-0.22%). Furthermore, the complexes demonstrate very high stability (pYb {approx} 18.8-21.9) in aqueous solution, making them good candidates for further development as probes for NIR imaging. Analysis of the low temperature (77 K) photophysical measurements for a model Gd(III) complex were used to gain an insight into the electronic structure, and were found to agree well with corresponding TD-DFT calculations at the B3LYP/6-311G{sup ++}(d,p) level of theory for a simplified model monovalent sodium complex.

  3. Climax Granite, Nevada Test Site, as a host for a rock mechanics test facility related to the geologic disposal of high level nuclear wastes

    SciTech Connect (OSTI)

    Heuze, F.E.


    This document discusses the potential of the Climax pluton, at the Nevada Test Site, as the host for a granite mechanics test facility related to the geologic disposal of high-level nuclear waste. The Climax granitic pluton has been the site of three nuclear weapons effects tests: Hard Hat, Tiny Tot, and Piledriver. Geologic exploration and mapping of the granite body were performed at the occasion of these tests. Currently, it is the site Spent Fuel Test (SFT-C) conducted in the vicinity of and at the same depth as that of the Piledriver drifts. Significant exploration, mapping, and rock mechanics work have been performed and continue at this Piledriver level - the 1400 (ft) level - in the context of SFT-C. Based on our technical discussions, and on the review of the significant geological and rock mechanics work already achieved in the Climax pluton, based also on the ongoing work and the existing access and support, it is concluded that the Climax site offers great opportunities for a rock mechanics test facility. It is not claimed, however, that Climax is the only possible site or the best possible site, since no case has been made for another granite test facility in the United States. 12 figures, 3 tables.

  4. Preliminary Analysis and Case Study of Transmission Constraints and Wind Energy in the West: Preprint

    SciTech Connect (OSTI)

    Milligan, M.; Berger, D. P.


    Wind developers typically need long-term transmission service to finance their projects; however, most of the capacity on several key paths is reserved by existing firm contracts. Because non-firm contracts are only offered for periods up to 1 year, obtaining financing for the wind project is generally not possible when firm capacity is unavailable. However, sufficient capacity may exist on the constrained paths for new wind projects that can risk curtailment for a small number of hours of the year. This paper presents the results of a study sponsored by the National Renewable Energy Laboratory (NREL), a work group participant in the Rocky Mountain Area Transmission Study (RMATS). Using recent historical power flow data, case studies were conducted on the constrained paths between Wyoming-Colorado (TOT3) and Montana-Northwest, coinciding with areas of exceptional wind resources. The potential curtailment frequency for hypothetical 100-MW and 500-MW wind plants was calculated using hourly wind data. The results from the study indicate that sufficient potential exists for innovative transmission products that can help bring more wind to load centers and increase the efficiency of the existing transmission network.

  5. The Nature of the Emission Components in the Quasar / NLS1 PG 1211+143

    SciTech Connect (OSTI)

    Janiuk, Agnieszka; Czerny, Bozena; Madejski, Greg M.; /SLAC


    We present the study of the emission properties of the quasar PG1211+143, which belongs to the class of Narrow Line Seyfert 1 galaxies. On the basis of observational data analyzed by us and collected from the literature, we study the temporal and spectral variability of the source in the optical/UV/X-ray bands and we propose a model that explains the spectrum emitted in this broad energy range. In this model, the intrinsic emission originating in the warm skin of the accretion disk is responsible for the spectral component that is dominant in the softest X-ray range. The shape of reflected spectrum as well as Fe K line detected in hard X-rays require the reflecting medium to be mildly ionized ({zeta} {approx} 500). We identify this reflector with the warm skin of the disk and we show that the heating of the skin is consistent with the classical {alpha}P{sub tot} prescription, while {alpha}P{sub gas} option is at least two orders of magnitude too low to provide the required heating. We find that the mass of the central black hole is relatively small (M{sub BH} {approx} 10{sup 7} - 10{sup 8} M{sub {circle_dot}}), which is consistent with the Broad Line Region mapping results and characteristic for NLS1 class.


    SciTech Connect (OSTI)

    Toma, K.; Takahara, F.


    Plasmas of geometrically thick, black hole (BH) accretion flows in active galactic nuclei (AGNs) are generally collisionless for protons, and involve magnetic field turbulence. Under such conditions a fraction of protons can be accelerated stochastically and create relativistic neutrons via nuclear collisions. These neutrons can freely escape from the accretion flow and decay into protons in the dilute polar region above the rotating BH to form relativistic jets. We calculate geometric efficiencies of the neutron energy and mass injections into the polar region, and show that this process can deposit luminosity as high as L{sub j}{approx}2 Multiplication-Sign 10{sup -3} M-dot c{sup 2} and mass loading M-dot{sub j}{approx}6 Multiplication-Sign 10{sup -4} M-dot for the case of the BH mass M {approx} 10{sup 8} M{sub Sun }, where M-dot is the mass accretion rate. The terminal Lorentz factors of the jets are {Gamma} {approx} 3, and they may explain the AGN jets having low luminosities. For higher luminosity jets, which can be produced by additional energy inputs such as Poynting flux, the neutron decay still can be a dominant mass loading process, leading to, e.g., {Gamma} {approx} 50 for L{sub j,tot}{approx}3 Multiplication-Sign 10{sup -2} M-dot c{sup 2}.

  7. A Historical Evaluation of the U15 Complex, Nevada National Security Site, Nye County, Nevada

    SciTech Connect (OSTI)

    Drollinger, Harold; Holz, Barbara A; Bullard, Thomas F; Goldenberg, Nancy G; Ashbaugh, Laurence J; Griffin, Wayne R


    This report presents a historical evaluation of the U15 Complex on the Nevada National Security Site (NNSS) in southern Nevada. The work was conducted by the Desert Research Institute at the request of the U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office and the U.S. Department of Defense, Defense Threat Reduction Agency. Three underground nuclear tests and two underground nuclear fuel storage experiments were conducted at the complex. The nuclear tests were Hard Hat in 1962, Tiny Tot in 1965, and Pile Driver in 1966. The Hard Hat and Pile Driver nuclear tests involved different types of experiment sections in test drifts at various distances from the explosion in order to determine which sections could best survive in order to design underground command centers. The Tiny Tot nuclear test involved an underground cavity in which the nuclear test was executed. It also provided data in designing underground structures and facilities to withstand a nuclear attack. The underground nuclear fuel storage experiments were Heater Test 1 from 1977 to 1978 and Spent Fuel Test - Climax from 1978 to 1985. Heater Test 1 was used to design the later Spent Fuel Test - Climax experiment. The latter experiment was a model of a larger underground storage facility and primarily involved recording the conditions of the spent fuel and the surrounding granite medium. Fieldwork was performed intermittently in the summers of 2011 and 2013, totaling 17 days. Access to the underground tunnel complex is sealed and unavailable. Restricted to the surface, four buildings, four structures, and 92 features associated with nuclear testing and fuel storage experiment activities at the U15 Complex have been recorded. Most of these are along the west side of the complex and next to the primary access road and are characteristic of an industrial mining site, albeit one with scientific interests. The geomorphological fieldwork was conducted over three days in the summer of 2011. It was discovered that major modifications to the terrain have resulted from four principal activities. These are road construction and maintenance, mining activities related to development of the tunnel complex, site preparation for activities related to the tests and experiments, and construction of drill pads and retention ponds. Six large trenches for exploring across the Boundary geologic fault are also present. The U15 Complex, designated historic district 143 and site 26NY15177, is eligible to the National Register of Historic Places under Criteria A, C, and D of 36 CFR Part 60.4. As a historic district and archaeological site eligible to the National Register of Historic Places, the Desert Research Institute recommends that the area defined for the U15 Complex, historic district 143 and site 26NY15117, be left in place in its current condition. The U15 Complex should also be included in the NNSS cultural resources monitoring program and monitored for disturbances or alterations.

  8. In situ dehydration behavior of zeolite-like pentagonite: A single-crystal X-ray study

    SciTech Connect (OSTI)

    Danisi, Rosa Micaela; Armbruster, Thomas; Lazic, Biljana


    The structural modifications upon heating of pentagonite, Ca(VO)(Si{sub 4}O{sub 10}){center_dot}4H{sub 2}O (space group Ccm2{sub 1}, a=10.3708(2), b=14.0643(2), c=8.97810(10) A, V=1309.53(3) A{sup 3}) were investigated by in situ temperature dependent single-crystal X-ray structure refinements. Diffraction data of a sample from Poona district (India) have been measured in steps of 25 up to 250 Degree-Sign C and in steps of 50 Degree-Sign C between 250 and 400 Degree-Sign C. Pentagonite has a porous framework structure made up by layers of silicate tetrahedra connected by V{sup 4+}O{sub 5} square pyramids. Ca and H{sub 2}O molecules are extraframework occupants. Room temperature diffraction data allowed refinement of H positions. The hydrogen-bond system links the extraframework occupants to the silicate layers and also interconnects the H{sub 2}O molecules located inside the channels. Ca is seven-fold coordinated forming four bonds to O of the tetrahedral framework and three bonds to extraframework H{sub 2}O. The H{sub 2}O molecule at O9 showing a high displacement parameter is not bonded to Ca. The dehydration in pentagonite proceeds in three steps. At 100 Degree-Sign C the H{sub 2}O molecule at O8 was released while O9 moved towards Ca. As a consequence the displacement parameter of H{sub 2}O at O9 halved compared to that at room temperature. The unit-cell volume decreased to 1287.33(3) A{sup 3} leading to a formula with 3H{sub 2}O per formula unit (pfu). Ca remained seven-fold coordinated. At 175 Degree-Sign C Ca(VO)(Si{sub 4}O{sub 10}){center_dot}3H{sub 2}O transformed into a new phase with 1H{sub 2}O molecule pfu characterized by doubling of the c axis and the monoclinic space group Pn. Severe bending of specific T--O--T angles led to contraction of the porous three-dimensional framework. In addition, H{sub 2}O at O9 was expelled while H{sub 2}O at O7 approached a position in the center of the channel. The normalized volume decreased to 1069.44(9) A{sup 3}. The Ca coordination reduced from seven- to six-fold. At 225 Degree-Sign C a new anhydrous phase with space group Pna2{sub 1} but without doubling of c had formed. Release of H{sub 2}O at O7 caused additional contraction of T--O--T angles and volume reduction (V=1036.31(9) A{sup 3}). Ca adopted five-fold coordination. During heating excursion up to 400 Degree-Sign C this anhydrous phase remained preserved. Between room temperature and 225 Degree-Sign C the unit-cell volume decreased by 21% due to dehydration. The dehydration steps compare well with the thermo-gravimetric data reported in the literature. - Graphical abstract: Pentagonite structure at room temperature and at 225 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer We investigate the relationship between the removal of H{sub 2}O molecules and structural modifications of the framework of pentagonite. Black-Right-Pointing-Pointer Pentagonite undergoes phase transitions upon heating. Black-Right-Pointing-Pointer We analyze similarities and differences between pentagonite and related structures.


    SciTech Connect (OSTI)

    Halfen, D. T.; Ziurys, L. M.; Ilyushin, V. V. E-mail:


    Multiple observations of methanimine (CH{sub 2}NH) and methyl amine (CH{sub 3}NH{sub 2}) have been performed toward Sgr B2(N) at 1, 2, and 3 mm using the Submillimeter Telescope and the 12 m antenna of the Arizona Radio Observatory. In the frequency range 68-280 GHz, 23 transitions of CH{sub 2}NH and 170 lines of CH{sub 3}NH{sub 2} have been observed as individual, distinguishable features, although some are partially blended with other lines. For CH{sub 2}NH, the line profiles indicate V{sub LSR} = 64.2 {+-} 1.4 km s{sup -1} and {Delta}V{sub 1/2} = 13.8 {+-} 2.8 km s{sup -1}, while V{sub LSR} = 63.7 {+-} 1.6 km s{sup -1} and {Delta}V{sub 1/2} = 15.1 {+-} 3.0 km s{sup -1} for CH{sub 3}NH{sub 2}, parameters that are very similar to those of other organic species in Sgr B2(N). From these data, rotational diagrams were constructed for both species. In the case of CH{sub 2}NH, a rotational temperature of T{sub rot} = 44 {+-} 13 K and a column density of N{sub tot} = (9.1 {+-} 4.4) Multiplication-Sign 10{sup 14} cm{sup -2} were determined from the analysis. For CH{sub 3}NH{sub 2}, T{sub rot} = 159 {+-} 30 K and N{sub tot} = (5.0 {+-} 0.9) Multiplication-Sign 10{sup 15} cm{sup -2}, indicating that this species is present in much warmer gas than CH{sub 2}NH. The fractional abundances for CH{sub 2}NH and CH{sub 3}NH{sub 2} were established to be f (H{sub 2}) Almost-Equal-To 3.0 Multiplication-Sign 10{sup -10} and f (H{sub 2}) Almost-Equal-To 1.7 Multiplication-Sign 10{sup -9}, respectively. It has been proposed that CH{sub 2}NH is formed on grains via hydrogenation of HCN; further hydrogenation of CH{sub 2}NH on surfaces leads to CH{sub 3}NH{sub 2}. However, given the dissimilarity between the rotational temperatures and distributions of CH{sub 2}NH and CH{sub 3}NH{sub 2} in Sgr B2, it is improbable that these species are closely related synthetically, at least in this source. Both CH{sub 2}NH and CH{sub 3}NH{sub 2} are more likely created by neutral-neutral processes in the gas phase.

  10. Early science with the large millimeter telescope: exploring the effect of AGN activity on the relationships between molecular gas, dust, and star formation

    SciTech Connect (OSTI)

    Kirkpatrick, Allison; Pope, Alexandra; Calzetti, Daniela; Narayanan, Gopal; Schloerb, F. Peter; Yun, Min S.; Aretxaga, Itziar; Montaña, Alfredo; Vega, Olga; Armus, Lee; Helou, George; Shi, Yong


    The molecular gas, H{sub 2}, that fuels star formation in galaxies is difficult to observe directly. As such, the ratio of L {sub IR} to L{sub CO}{sup ?} is an observational estimate of the star formation rate compared with the amount of molecular gas available to form stars, which is related to the star formation efficiency and the inverse of the gas consumption timescale. We test what effect an IR luminous active galactic nucleus (AGN) has on the ratio L{sub IR}/L{sub CO}{sup ?} in a sample of 24 intermediate redshift galaxies from the 5 mJy Unbiased Spitzer Extragalactic Survey (5MUSES). We obtain new CO(1-0) observations with the Redshift Search Receiver on the Large Millimeter Telescope. We diagnose the presence and strength of an AGN using Spitzer IRS spectroscopy. We find that removing the AGN contribution to L{sub IR}{sup tot} results in a mean L{sub IR}{sup SF}/L{sub CO}{sup ?} for our entire sample consistent with the mean L{sub IR}/L{sub CO}{sup ?} derived for a large sample of star forming galaxies from z ? 0-3. We also include in our comparison the relative amount of polycyclic aromatic hydrocarbon emission for our sample and a literature sample of local and high-redshift ultra luminous infrared galaxies and find a consistent trend between L{sub 6.2}/L{sub IR}{sup SF} and L{sub IR}{sup SF}/L{sub CO}{sup ?}, such that small dust grain emission decreases with increasing L{sub IR}{sup SF}/L{sub CO}{sup ?} for both local and high-redshift dusty galaxies.

  11. The U.S. Army`s environmental compliance assessment in Germany, a case study

    SciTech Connect (OSTI)

    Schlessman, D.C.


    The U.S. Army, Europe (USAREUR) in 1995 is initiating the Army-wide program of assessing environmental compliance at each of its installations. The first assessment was done in Germany in January and is the basis of this study. These assessments are the conerstone of USAREUR`s compliance standards: air emissions, drinking and waste water standards, environmental noise, radon, asbestos, underground storage tanks, hazardous material and petroleum management, and pesticides. Also covered are areas of waste management to include solid, hazardous, and medical wastes and special requirements for handling and disposal of polychlorinated bi- & terphenyls. In addition policy and other science areas are checked. These include environmental program management, environmental effects analysis, endangered species and natural resource protection, and historical and cultural resource preservation. The ECAS`s breadth of medias assessed gives a comprehensive look at the environmental posture of an installation. One of the two manuals used in each assessment is based on the Department of Defense (DOD) environmental final governing standards (FGS). Each overseas country that has a substantial DOD long-term presence has a FGS. The FGS is developed by a DOD appointed executive agent. He compared the DOD baseline of environmental standards (based on U.S. law and DOD policy) and the HN`s environmental standards. From this comparison the standard that is most protective of human health and the environment is selected as the FGS. In Germany, the FGS, and thus the ECAS manual are substantially based on the German standards. This is due tot he well developed environmental standards found in Germany. This study provides the first look at the USAREUR ECAS process and the major changes required in a USAREUR community`s environmental compliance posture to meet the German FGS. The January Anbach ECAS is the first time a community in USAREUR was assessed using the fully operational ECAS.

  12. Licensing of spent fuel dry storage and consolidated rod storage: A Review of Issues and Experiences

    SciTech Connect (OSTI)

    Bailey, W.J.


    The results of this study, performed by Pacific Northwest Laboratory (PNL) and sponsored by the US Department of Energy (DOE), respond to the nuclear industry's recommendation that a report be prepared that collects and describes the licensing issues (and their resolutions) that confront a new applicant requesting approval from the US Nuclear Regulatory Commission (NRC) for dry storage of spent fuel or for large-scale storage of consolidated spent fuel rods in pools. The issues are identified in comments, questions, and requests from the NRC during its review of applicants' submittals. Included in the report are discussions of (1) the 18 topical reports on cask and module designs for dry storage fuel that have been submitted to the NRC, (2) the three license applications for dry storage of spent fuel at independent spent fuel storage installations (ISFSIs) that have been submitted to the NRC, and (3) the three applications (one of which was later withdrawn) for large-scale storage of consolidated fuel rods in existing spent fuel storage pools at reactors that were submitted tot he NRC. For each of the applications submitted, examples of some of the issues (and suggestions for their resolutions) are described. The issues and their resolutions are also covered in detail in an example in each of the three subject areas: (1) the application for the CASTOR V/21 dry spent fuel storage cask, (2) the application for the ISFSI for dry storage of spent fuel at Surry, and (3) the application for full-scale wet storage of consolidated spent fuel at Millstone-2. The conclusions in the report include examples of major issues that applicants have encountered. Recommendations for future applicants to follow are listed. 401 refs., 26 tabs.

  13. Intergalactic medium emission observations with the cosmic web imager. I. The circum-QSO medium of QSO 1549+19, and evidence for a filamentary gas inflow

    SciTech Connect (OSTI)

    Martin, D. Christopher; Chang, Daphne; Matuszewski, Matt; Morrissey, Patrick; Rahman, Shahin; Moore, Anna; Steidel, Charles C.


    The Palomar Cosmic Web Imager (PCWI), an integral field spectrograph designed to detect and map low surface brightness emission, has obtained imaging spectroscopic maps of Ly? from the circum-QSO medium (CQM) of QSO HS1549+19 at redshift z = 2.843. Extensive extended emission is detected from the CQM, consistent with fluorescent and pumped Ly? produced by the ionizing and Ly? continuum of the QSO. Many features present in PCWI spectral images match those detected in narrow-band images. Filamentary structures with narrow line profiles are detected in several cases as long as 250-400 kpc. One of these is centered at a velocity redshifted with respect to the systemic velocity, and displays a spatially collimated and kinematically cold line profile increasing in velocity width approaching the QSO. This suggests that the filament gas is infalling onto the QSO, perhaps in a cold accretion flow. Because of the strong ionizing flux, the neutral column density is low, typically N(H I)?10{sup 12}--10{sup 15} cm{sup ?2}, and the line center optical depth is also low (typically ?{sub 0} < 10), insufficient to display well separated double peak emission characteristic of higher line optical depths. With a simple ionization and cloud model we can very roughly estimate the total gas mass (log M {sub gas} = 12.5 ± 0.5) and the total (log M {sub tot} = 13.3 ± 0.5). We can also calculate a kinematic mass from the total line profile (2 × 10{sup 13} M {sub ?}), which agrees with the mass estimated from the gas emission. The intensity-binned spectrum of the CQM shows a progression in kinematic properties consistent with heirarchical structure formation.


    SciTech Connect (OSTI)

    Bonne, Nicolas J.; Brown, Michael J. I.; Jones, Heath; Pimbblet, Kevin A.


    We have determined K-band luminosity functions for 13,325 local universe galaxies as a function of morphology and color (for K {sub tot} ≤ 10.75). Our sample is drawn from the Two Micron All Sky Survey Extended Source Catalog, with all sample galaxies having measured morphologies and distances (including 4219 archival redshift-independent distances). The luminosity function for our total sample is in good agreement with previous works, but is relatively smooth at faint magnitudes (due to bulk flow distance corrections). We investigated the differences due to morphological and color selection using 5417 sample galaxies with NASA Sloan Atlas optical colors and find that red spirals comprise 20%-50% of all spirals with –25 ≤ M{sub K}  < –20. Fainter than M{sub K} = –24, red spirals are as common as early types, explaining the different faint end slopes (α = –0.87 and –1.00 for red and early-types, respectively). While we find red spirals comprise more than 50% of all M{sub K}  < –25 spiral galaxies, they do not dominate the bright end of the overall red galaxy luminosity function, which is dominated by early-type galaxies. The brightest red spirals have ongoing star formation and those without are frequently misclassified as early-types. The faintest ones have an appearance and Sérsic indices consistent with faded disks, rather than true bulge-dominated galaxies.


    SciTech Connect (OSTI)

    Appleton, P. N.; Lord, S.; Lu, N.; Guillard, P.; Boulanger, F.; Pineau des Forêts, G.; Cluver, M. E.; Konstantopoulos, I.; Ogle, P.; Falgarone, E.; Duc, P.-A.; Gallagher, S.; Gao, Y.; Jarrett, T.; Lisenfeld, U.; Peterson, B. W.; Struck, C.; Sturm, E.; Tuffs, R.; and others


    We present the first Herschel spectroscopic detections of the [O I] 63 ?m and [C II] 158 ?m fine-structure transitions, and a single para-H{sub 2}O line from the 35 × 15 kpc{sup 2} shocked intergalactic filament in Stephan's Quintet. The filament is believed to have been formed when a high-speed intruder to the group collided with a clumpy intergroup gas. Observations with the PACS spectrometer provide evidence for broad (>1000 km s{sup –1}) luminous [C II] line profiles, as well as fainter [O I] 63 ?m emission. SPIRE FTS observations reveal water emission from the p-H{sub 2}O (1{sub 11}-0{sub 00}) transition at several positions in the filament, but no other molecular lines. The H{sub 2}O line is narrow and may be associated with denser intermediate-velocity gas experiencing the strongest shock-heating. The [C II]/PAH{sub tot} and [C II]/FIR ratios are too large to be explained by normal photo-electric heating in photodissociation regions. H II region excitation or X-ray/cosmic-ray heating can also be ruled out. The observations lead to the conclusion that a large fraction the molecular gas is diffuse and warm. We propose that the [C II], [O I], and warm H{sub 2} line emission is powered by a turbulent cascade in which kinetic energy from the galaxy collision with the intergalactic medium is dissipated to small scales and low velocities, via shocks and turbulent eddies. Low-velocity magnetic shocks can help explain both the [C II]/[O I] ratio, and the relatively high [C II]/H{sub 2} ratios observed. The discovery that [C II] emission can be enhanced, in large-scale turbulent regions in collisional environments, has implications for the interpretation of [C II] emission in high-z galaxies.

  16. Temperature-dependent structural study of microporous CsAlSi{sub 5}O{sub 12}

    SciTech Connect (OSTI)

    Fisch, Martin; Armbruster, Thomas Kolesov, Boris


    CsAlSi{sub 5}O{sub 12} crystals were synthesized at high temperature by slow cooling of a vanadium oxide flux. Single-crystal X-ray diffraction structure analysis and electron microprobe analyses yielded the microporous CAS zeolite framework structure of Cs{sub 0.85}Al{sub 0.85}Si{sub 5.15}O{sub 12} composition. High-temperature single-crystal and powder X-ray diffraction studies were utilized to analyze anisotropic thermal expansion. Rietveld refined cell constants from powder diffraction data, measured in steps of 25 deg. C up to 700 deg. C, show a significant decrease in expansion above 500 deg. C. At 500 deg. C, a displacive, static disorder-dynamic disorder-type phase transition from the acentric low-temperature space group Ama2 to centrosymmetric Amam (Cmcm in standard setting) was found. Thermal expansion below the phase transition is governed by rigid-body TO{sub 4} rotations accompanied by stretching of T-O-T angles. Above the phase transition at 500 deg. C all atoms, except one oxygen (O6), are fixed on mirror planes. Temperature-dependent polarized Raman single-crystal spectra between -270 and 300 deg. C and unpolarized spectra between room temperature and 1000 deg. C become increasingly less resolved with rising temperature confirming the disordered static-disordered dynamic type of the phase transition. - Graphical abstract: Temperature-dependent structural evolution of microporous CsAlSi{sub 5}O{sub 12} has been investigated by single-crystal and powder X-ray diffraction, as well as Raman spectroscopy. Results yielded a phase transition of order-disorder type.


    SciTech Connect (OSTI)

    Pulliam, R. L.; Ziurys, L. M.; Savage, C.; Agundez, M.; Cernicharo, J.; Guelin, M.


    A new interstellar molecule, KCN, has been identified toward the circumstellar envelope of the carbon-rich asymptotic giant branch star, IRC+10216-the fifth metal cyanide species to be detected in space. Fourteen rotational transitions of this T-shaped, asymmetric top were searched for in the frequency range of 83-250 GHz using the Arizona Radio Observatory (ARO) 12 m Kitt Peak antenna, the IRAM 30 m telescope, and the ARO Submillimeter Telescope. Distinct lines were measured for 10 of these transitions, including the K{sub a} = 1 and 2 asymmetry components of the J = 11 {yields} 10 and J = 10 {yields} 9 transitions, i.e., the K-ladder structure distinct to an asymmetric top. These data are some of the most sensitive astronomical spectra at {lambda} {approx} 1 and 3 mm obtained to date, with 3{sigma} noise levels {approx}0.3 mK, made possible by new ALMA technology. The line profiles from the ARO and IRAM telescopes are consistent with a shell-like distribution for KCN with r{sub outer} {approx} 15'', but with an inner shell radius that extends into warmer gas. The column density for KCN in IRC+10216 was found to be N{sub tot} {approx} 1.0 x 10{sup 12} cm{sup -2} with a rotational temperature of T{sub rot} {approx} 53 K. The fractional abundance was calculated to be f(KCN/H{sub 2}) {approx} 6 x 10{sup -10}, comparable to that of KCl. The presence of KCN in IRC+10216, along with MgNC, MgCN, NaCN, and AlNC, suggests that cyanide/isocyanide species are the most common metal-containing molecules in carbon-rich circumstellar gas.

  18. DETECTION OF FeCN (X {sup 4}{Delta}{sub i} ) IN IRC+10216: A NEW INTERSTELLAR MOLECULE

    SciTech Connect (OSTI)

    Zack, L. N.; Halfen, D. T.; Ziurys, L. M.


    A new interstellar molecule, FeCN (X {sup 4}{Delta}{sub i} ), has been detected in the envelope of the carbon-rich asymptotic giant branch star, IRC+10216. This work is the first definitive detection of an iron-bearing molecule in the interstellar medium and is based on newly measured rest frequencies. Eight successive rotational transitions of this linear free radical in the lowest spin ladder, {Omega} = 7/2, were observed at 2 and 3 mm using the Arizona Radio Observatory (ARO) 12 m telescope. Three transitions appear as single, unblended features at the 1-2 mK level and exhibit characteristic IRC+10216 line profiles; one had previously been observed with the IRAM 30 m telescope. Two other transitions are partially blended, but exhibit distinct emission at the FeCN frequencies. The remaining transitions are either completely contaminated, or are too high in energy. Comparison of the ARO and IRAM data suggests a source size for FeCN of {approx}30'' in IRC+10216, indicating an outer shell distribution, as expected for a free radical. The column density derived for FeCN is N{sub tot} = 8.6 x 10{sup 11} cm{sup -2} with a rotational temperature of T{sub rot} = 21 K. The fractional abundance of this molecule is [FeCN]/[H{sub 2}] {approx} 2-7 x 10{sup -10}-comparable to that of MgCN and KCN in IRC+10216. FeCN is likely formed by gas-phase reactions of Fe{sup +} or neutral iron; the latter has a significant gas-phase abundance in the outer shell. The detection of FeCN is further evidence that metal cyanides/isocyanides dominate the chemistry of refractory elements in IRC+10216.

  19. Electron heating during magnetic reconnection: A simulation scaling study

    SciTech Connect (OSTI)

    Shay, M. A. Haggerty, C. C.; Phan, T. D.; Oieroset, M.; Drake, J. F.; Swisdak, M.; Cassak, P. A.; Wu, P.; Malakit, K.


    Electron bulk heating during magnetic reconnection with symmetric inflow conditions is examined using kinetic particle-in-cell simulations. Inflowing plasma parameters are varied over a wide range of conditions, and the increase in electron temperature is measured in the exhaust well downstream of the x-line. The degree of electron heating is well correlated with the inflowing Alfvén speed c{sub Ar} based on the reconnecting magnetic field through the relation ?T{sub e}=0.033?m{sub i}?c{sub Ar}{sup 2}, where ?T{sub e} is the increase in electron temperature. For the range of simulations performed, the heating shows almost no correlation with inflow total temperature T{sub tot}=T{sub i}+T{sub e} or plasma ?. An out-of-plane (guide) magnetic field of similar magnitude to the reconnecting field does not affect the total heating, but it does quench perpendicular heating, with almost all heating being in the parallel direction. These results are qualitatively consistent with a recent statistical survey of electron heating in the dayside magnetopause (Phan et al., Geophys. Res. Lett. 40, 4475, 2013), which also found that ?T{sub e} was proportional to the inflowing Alfvén speed. The net electron heating varies very little with distance downstream of the x-line. The simulations show at most a very weak dependence of electron heating on the ion to electron mass ratio. In the antiparallel reconnection case, the largely parallel heating is eventually isotropized downstream due a scattering mechanism, such as stochastic particle motion or instabilities. The simulation size is large enough to be directly relevant to reconnection in the Earth's magnetosphere, and the present findings may prove to be universal in nature with applications to the solar wind, the solar corona, and other astrophysical plasmas. The study highlights key properties that must be satisfied by an electron heating mechanism: (1) preferential heating in the parallel direction; (2) heating proportional to m{sub i}?c{sub Ar}{sup 2}; (3) at most a weak dependence on electron mass; and (4) an exhaust electron temperature that varies little with distance from the x-line.

  20. On the interaction of the PKS B1358–113 radio galaxy with the A1836 cluster

    SciTech Connect (OSTI)

    Stawarz, ?.; Simionescu, A.; Hagino, K.; Szostek, A.; Kozie?-Wierzbowska, D.; Ostrowski, M.; Cheung, C. C.; Siemiginowska, A.; Harris, D. E.; Werner, N.; Madejski, G.; Begelman, M. C.


    Here we present the analysis of multifrequency data gathered for the Fanaroff-Riley type-II (FR II) radio galaxy PKS B1358-113, hosted in the brightest cluster galaxy in the center of A1836. The galaxy harbors one of the most massive black holes known to date, and our analysis of the acquired optical data reveals that this black hole is only weakly active, with a mass accretion rate M-dot {sub acc}?2×10{sup ?4} M-dot {sub Edd}?0.02 M{sub ?} yr{sup –1}. Based on analysis of new Chandra and XMM-Newton X-ray observations and archival radio data, and assuming the well-established model for the evolution of FR II radio galaxies, we derive the preferred range for the jet kinetic luminosity L {sub j} ? (1-6) × 10{sup –3} L {sub Edd} ? (0.5-3) × 10{sup 45} erg s{sup –1}. This is above the values implied by various scaling relations proposed for radio sources in galaxy clusters, being instead very close to the maximum jet power allowed for the given accretion rate. We also constrain the radio source lifetime as ?{sub j} ? 40-70 Myr, meaning the total amount of deposited jet energy E {sub tot} ? (2-8) × 10{sup 60} erg. We argue that approximately half of this energy goes into shock heating of the surrounding thermal gas, and the remaining 50% is deposited into the internal energy of the jet cavity. The detailed analysis of the X-ray data provides indication for the presence of a bow shock driven by the expanding radio lobes into the A1836 cluster environment. We derive the corresponding shock Mach number in the range M{sub sh}?2--4, which is one of the highest claimed for clusters or groups of galaxies. This, together with the recently growing evidence that powerful FR II radio galaxies may not be uncommon in the centers of clusters at higher redshifts, supports the idea that jet-induced shock heating may indeed play an important role in shaping the properties of clusters, galaxy groups, and galaxies in formation. In this context, we speculate on a possible bias against detecting stronger jet-driven shocks in poorer environments, resulting from inefficient electron heating at the shock front, combined with a relatively long electron-ion temperature equilibration timescale.


    SciTech Connect (OSTI)

    Muccino, M.; Ruffini, R.; Bianco, C. L.; Izzo, L.; Penacchioni, A. V. [Dip. di Fisica and ICRA, Sapienza Universita di Roma, Piazzale Aldo Moro 5, I-00185 Rome (Italy)] [Dip. di Fisica and ICRA, Sapienza Universita di Roma, Piazzale Aldo Moro 5, I-00185 Rome (Italy)


    The time-resolved spectral analysis of GRB 090227B, made possible by the Fermi-GBM data, allows us to identify in this source the missing link between the genuine short and long gamma-ray bursts (GRBs). Within the Fireshell model of the GRBs we predict genuine short GRBs: bursts with the same inner engine of the long bursts but endowed with a severely low value of the baryon load, B {approx}< 5 Multiplication-Sign 10{sup -5}. A first energetically predominant emission occurs at the transparency of the e {sup +} e {sup -} plasma, the Proper-GRB (P-GRB), followed by a softer emission, the extended afterglow. The typical separation between the two emissions is expected to be of the order of 10{sup -3}-10{sup -2} s. We identify the P-GRB of GRB 090227B in the first 96 ms of emission, where a thermal component with the temperature kT = (517 {+-} 28) keV and a flux comparable with the non-thermal part of the spectrum is observed. This non-thermal component as well as the subsequent emission, where there is no evidence for a thermal spectrum, is identified with the extended afterglow. We deduce a theoretical cosmological redshift z = 1.61 {+-} 0.14. We then derive the total energy E{sup tot}{sub e{sup +}e{sup -}}= (2.83{+-}0.15) Multiplication-Sign 10{sup 53} erg, the baryon load B = (4.13 {+-} 0.05) Multiplication-Sign 10{sup -5}, the Lorentz {Gamma} factor at transparency {Gamma}{sub tr} = (1.44 {+-} 0.01) Multiplication-Sign 10{sup 4}, and the intrinsic duration {Delta}t' {approx} 0.35 s. We also determine the average density of the circumburst medium (CBM), (n {sub CBM}) = (1.90 {+-} 0.20) Multiplication-Sign 10{sup -5} particles cm{sup -3}. There is no evidence of beaming in the system. In view of the energetics and of the baryon load of the source, as well as of the low interstellar medium and of the intrinsic timescale of the signal, we identify the GRB progenitor as a binary neutron star. From the recent progress in the theory of neutron stars, we obtain masses of the stars m {sub 1} = m {sub 2} = 1.34 M {sub Sun} and their corresponding radii R {sub 1} = R {sub 2} = 12.24 km and thickness of their crusts {approx}0.47 km, consistent with the above values of the baryon load, of the energetics and of the time duration of the event.

  2. Studies of the physical aspects of intumescence using advance diagnostics methods

    SciTech Connect (OSTI)

    Saeed, Hussain Huang, Hua Wei Zhang, Yang


    The use of intumescent paints as an active fire protection method has gained immense interest in recent years. A significant aspect of research has focused on studying the chemical aspects of the system to improve performance. The dynamics and physical aspects of intumescence in real time fire conditions are still unclear. The present research uses an experimental approach where diagnostics techniques such as thermal imaging camera was used to study intumescent characteristics that have been not been reported in great detail. T-panels are a substitute to the most commonly used part in construction, the I-beam. Studies were conducted using a cone calorimeter that provided a uniform heat flux through radiation on steel T-panel samples. The complex nature of char movement was recorded and a novel algorithm was used to track the growing char laye07r. The samples are designed to cater to different fire conditions. Therefore, the degree of intumescence was observed to be very different in the samples. The samples designed for low temperature cellulosic fires focus on high degree of intumesce. Whereas, mechanical strength is the focus for samples used in high temperature turbulent hydrocarbon fire conditions. The variation in the internal structure of the sample is presented. Furthermore, the phenomenon is phase shift is discussed. The phase shift is an essential part of the process of intumescence when the majority of intumescence occurs. It was observed to be different in all the samples. The movement of the samples is a property of great interest. This is because if any part of the substrate is exposed then the formulation does not meet strict commercialisation criterion. The movement was diagonal in nature as compared to flat panels where it is perpendicular. This is due tot the heating pattern of the plate that results in the web part of the panel to influence the growth of char on the flange part of the panel. A special case of char cracking is also highlighted and using image processing algorithm on the thermal imaging data. A quantitative method of analsysis is presented to an otherwise commonly qualitative nature of experimental study in this field.


    SciTech Connect (OSTI)

    Gaspar, Andras; Rieke, George H.; Balog, Zoltan E-mail:


    We explore the collisional decay of disk mass and infrared emission in debris disks. With models, we show that the rate of the decay varies throughout the evolution of the disks, increasing its rate up to a certain point, which is followed by a leveling off to a slower value. The total disk mass falls off {proportional_to}t {sup -0.35} at its fastest point (where t is time) for our reference model, while the dust mass and its proxy-the infrared excess emission-fades significantly faster ({proportional_to}t {sup -0.8}). These later level off to a decay rate of M{sub tot}(t){proportional_to}t {sup -0.08} and M{sub dust}(t) or L{sub ir}(t){proportional_to}t {sup -0.6}. This is slower than the {proportional_to}t {sup -1} decay given for all three system parameters by traditional analytic models. We also compile an extensive catalog of Spitzer and Herschel 24, 70, and 100 {mu}m observations. Assuming a log-normal distribution of initial disk masses, we generate model population decay curves for the fraction of stars harboring debris disks detected at 24 {mu}m. We also model the distribution of measured excesses at the far-IR wavelengths (70-100 {mu}m) at certain age regimes. We show general agreement at 24 {mu}m between the decay of our numerical collisional population synthesis model and observations up to a Gyr. We associate offsets above a Gyr to stochastic events in a few select systems. We cannot fit the decay in the far-infrared convincingly with grain strength properties appropriate for silicates, but those of water ice give fits more consistent with the observations (other relatively weak grain materials would presumably also be successful). The oldest disks have a higher incidence of large excesses than predicted by the model; again, a plausible explanation is very late phases of high dynamical activity around a small number of stars. Finally, we constrain the variables of our numerical model by comparing the evolutionary trends generated from the exploration of the full parameter space to observations. Amongst other results, we show that erosive collisions are dominant in setting the timescale of the evolution and that planetesimals on the order of 100 km in diameter are necessary in the cascades for our population synthesis models to reproduce the observations.


    SciTech Connect (OSTI)

    Spitler, Lee R.; Rees, Glen; Straatman, Caroline M. S.; Labbé, Ivo; Glazebrook, Karl; Kacprzak, Glenn G.; Nanayakkara, Themiya; Tran, Kim-Vy H.; Papovich, Casey; Kawinwanichakij, Lalitwadee; Mehrtens, Nicola; Tilvi, Vithal; Tomczak, Adam R.; Quadri, Ryan F.; Persson, S. Eric; Kelson, Daniel D.; McCarthy, Patrick J.; Monson, Andrew J.; Van Dokkum, Pieter; Allen, Rebecca


    Our understanding of the redshift z > 3 galaxy population relies largely on samples selected using the popular ''dropout'' technique, typically consisting of UV-bright galaxies with blue colors and prominent Lyman breaks. As it is currently unknown if these galaxies are representative of the massive galaxy population, we here use the FOURSTAR Galaxy Evolution (ZFOURGE) survey to create a stellar mass-limited sample at z = 3-4. Uniquely, ZFOURGE uses deep near-infrared medium-bandwidth filters to derive accurate photometric redshifts and stellar population properties. The mass-complete sample consists of 57 galaxies with log M >10.6, reaching below M {sup *} at z = 3-4. On average, the massive z = 3-4 galaxies are extremely faint in the observed optical with median R{sub tot}{sup AB}=27.48±0.41 (rest-frame M {sub 1700} = –18.05 ± 0.37). They lie far below the UV luminosity-stellar mass relation for Lyman break galaxies and are about ?100 × fainter at the same mass. The massive galaxies are red (R – K {sub s} {sub AB} = 3.9 ± 0.2; rest-frame UV-slope ? = –0.2 ± 0.3) likely from dust or old stellar ages. We classify the galaxy spectral energy distributions by their rest-frame U–V and V–J colors and find a diverse population: 46{sub ?6?17}{sup +6+10}% of the massive galaxies are quiescent, 40{sub ?6?5}{sup +6+7}% are dusty star-forming galaxies, and only 14{sub ?3?4}{sup +3+10}% resemble luminous blue star-forming Lyman break galaxies. This study clearly demonstrates an inherent diversity among massive galaxies at higher redshift than previously known. Furthermore, we uncover a reservoir of dusty star-forming galaxies with 4 × lower specific star-formation rates compared to submillimeter-selected starbursts at z > 3. With 5 × higher numbers, the dusty galaxies may represent a more typical mode of star formation compared to submillimeter-bright starbursts.


    SciTech Connect (OSTI)

    Swinbank, A. M.; Smail, Ian; Papadopoulos, P. P.; Cox, P.; Krips, M.; Neri, R.; Ivison, R. J.; Thomson, A. P.; Richard, J.; Ebeling, H.


    We have used the Institut de Radioastronomie Millimetrique (IRAM) Plateau de Bure Interferometer and the Expanded Very Large Array to obtain a high-resolution map of the CO(6-5) and CO(1-0) emission in the lensed, star-forming galaxy SMM J2135-0102 at z = 2.32. The kinematics of the gas are well described by a model of a rotationally supported disk with an inclination-corrected rotation speed, v{sub rot} = 320 {+-} 25 km s{sup -1}, a ratio of rotational-to-dispersion support of v/{sigma} = 3.5 {+-} 0.2, and a dynamical mass of (6.0 {+-} 0.5) Multiplication-Sign 10{sup 10} M{sub Sun} within a radius of 2.5 kpc. The disk has a Toomre parameter, Q = 0.50 {+-} 0.15, suggesting that the gas will rapidly fragment into massive clumps on scales of L{sub J} {approx} 400 pc. We identify star-forming regions on these scales and show that they are {approx}10 Multiplication-Sign denser than those in quiescent environments in local galaxies, and significantly offset from the local molecular cloud scaling relations (Larson's relations). The large offset compared to local molecular cloud line-width-size scaling relations implies that supersonic turbulence should remain dominant on scales {approx}100 Multiplication-Sign smaller than in the kinematically quiescent interstellar medium (ISM) of the Milky Way, while the molecular gas in SMM J2135 is expected to be {approx}50 Multiplication-Sign denser than that in the Milky Way on all scales. This is most likely due to the high external hydrostatic pressure we measure for the ISM, P{sub tot}/k{sub B} {approx} (2 {+-} 1) Multiplication-Sign 10{sup 7} K cm{sup -3}. In such highly turbulent ISM, the subsonic regions of gravitational collapse (and star formation) will be characterized by much higher critical densities, n{sub crit} > = 10{sup 8} cm{sup -3}, a factor {approx}>1000 Multiplication-Sign more than the quiescent ISM of the Milky Way.

  6. Herschel observations of extra-ordinary sources: H{sub 2}S as a probe of dense gas and possibly hidden luminosity toward the Orion KL hot core

    SciTech Connect (OSTI)

    Crockett, N. R.; Bergin, E. A.; Neill, J. L.; Black, J. H.; Blake, G. A.; Kleshcheva, M.


    We present Herschel/HIFI observations of the light hydride H{sub 2}S obtained from the full spectral scan of the Orion Kleinmann-Low nebula (Orion KL) taken as part of the Herschel Observations of EXtra-Ordinary Sources GT (guaranteed time) key program. In total, we observe 52, 24, and 8 unblended or slightly blended features from H{sub 2} {sup 32}S, H{sub 2} {sup 34}S, and H{sub 2} {sup 33}S, respectively. We only analyze emission from the so-called hot core, but emission from the plateau, extended ridge, and/or compact ridge are also detected. Rotation diagrams for ortho and para H{sub 2}S follow straight lines given the uncertainties and yield T {sub rot} = 141 ± 12 K. This indicates H{sub 2}S is in local thermodynamic equilibrium and is well characterized by a single kinetic temperature or an intense far-IR radiation field is redistributing the population to produce the observed trend. We argue the latter scenario is more probable and find that the most highly excited states (E {sub up} ? 1000 K) are likely populated primarily by radiation pumping. We derive a column density, N {sub tot}(H{sub 2} {sup 32}S) = 9.5 ± 1.9 × 10{sup 17} cm{sup –2}, gas kinetic temperature, T {sub kin} = 120±{sub 10}{sup 13} K, and constrain the H{sub 2} volume density, n{sub H{sub 2}} ? 9 × 10 {sup 7} cm{sup –3}, for the H{sub 2}S emitting gas. These results point to an H{sub 2}S origin in markedly dense, heavily embedded gas, possibly in close proximity to a hidden self-luminous source (or sources), which are conceivably responsible for Orion KL's high luminosity. We also derive an H{sub 2}S ortho/para ratio of 1.7 ± 0.8 and set an upper limit for HDS/H{sub 2}S of <4.9 × 10 {sup –3}.


    SciTech Connect (OSTI)

    Croft, Stephen; Favalli, Andrea; Swinhoe, Martyn T.


    Verification of commercial low enriched uranium light water reactor fuel takes place at the fuel fabrication facility as part of the overall international nuclear safeguards solution to the civilian use of nuclear technology. The fissile mass per unit length is determined nondestructively by active neutron coincidence counting using a neutron collar. A collar comprises four slabs of high density polyethylene that surround the assembly. Three of the slabs contain {sup 3}He filled proportional counters to detect time correlated fission neutrons induced by an AmLi source placed in the fourth slab. Historically, the response of a particular collar design to a particular fuel assembly type has been established by careful cross-calibration to experimental absolute calibrations. Traceability exists to sources and materials held at Los Alamos National Laboratory for over 35 years. This simple yet powerful approach has ensured consistency of application. Since the 1980's there has been a steady improvement in fuel performance. The trend has been to higher burn up. This requires the use of both higher initial enrichment and greater concentrations of burnable poisons. The original analytical relationships to correct for varying fuel composition are consequently being challenged because the experimental basis for them made use of fuels of lower enrichment and lower poison content than is in use today and is envisioned for use in the near term. Thus a reassessment of the correction factors is needed. Experimental reassessment is expensive and time consuming given the great variation between fuel assemblies in circulation. Fortunately current modeling methods enable relative response functions to be calculated with high accuracy. Hence modeling provides a more convenient and cost effective means to derive correction factors which are fit for purpose with confidence. In this work we use the Monte Carlo code MCNPX with neutron coincidence tallies to calculate the influence of Gd{sub 2}O{sub 3} burnable poison on the measurement of fresh pressurized water reactor fuel. To empirically determine the response function over the range of historical and future use we have considered enrichments up to 5 wt% {sup 235}U/{sup tot}U and Gd weight fractions of up to 10 % Gd/UO{sub 2}. Parameterized correction factors are presented.

  8. Carbon-carbon bond cleavage of 1,2-hydroxy ethers b7 vanadium(V) dipicolinate complexes

    SciTech Connect (OSTI)

    Hanson, Susan K; Gordon, John C; Thorn, David L; Scott, Brian L; Baker, R Tom


    The development of alternatives to current petroleum-based fuels and chemicals is becoming increasingly important due to concerns over climate change, growing world energy demand, and energy security issues. Using non-food derived biomass to produce renewable feedstocks for chemicals and fuels is a particularly attractive possibility. However, the majority of biomass is in the form of lignocellulose, which is often not fully utilized due to difficulties associated with breaking down both lignin and cellulose. Recently, a number of methods have been reported to transform cellulose directly into more valuable materials such as glucose, sorbitol, 5-(chloromethyl)furfural, and ethylene glycol. Less progress has been made with selective transformations of lignin, which is typically treated in paper and forest industries by kraft pulping (sodium hydroxide/sodium sulfide) or incineration. Our group has begun investigating aerobic oxidative C-C bond cleavage catalyzed by dipicolinate vanadium complexes, with the idea that a selective C-C cleavage reaction of this type could be used to produce valuable chemicals or intermediates from cellulose or lignin. Lignin is a randomized polymer containing methoxylated phenoxy propanol units. A number of different linkages occur naturally; one of the most prevalent is the {beta}-O-4 linkage shown in Figure 1, containing a C-C bond with 1,2-hydroxy ether substituents. While the oxidative C-C bond cleavage of 1,2-diols has been reported for a number of metals, including vanadium, iron, manganese, ruthenium, and polyoxometalate complexes, C-C bond cleavage of 1,2-hydroxy ethers is much less common. We report herein vanadium-mediated cleavage of C-C bonds between alcohol and ether functionalities in several lignin model complexes. In order to explore the scope and potential of vanadium complexes to effect oxidative C-C bond cleavage in 1,2-hydroxy ethers, we examined the reactivity of the lignin model complexes pinacol monomethyl ether (A), 2-phenoxyethanol (B), and 1,2-diphenyl-2-methoxyethanol (C) (Figure 1). Reaction of (dipic)V{sup V}(O)O{sup i}Pr (1a) or (dipic)V{sup v}(O)OEt (lb) with A, B, or C in acetonitrile yielded new vanadium(V) complexes where the alcohol-ether ligand was bound in a chelating fashion. From the reaction of 1b with pinacol monomethyl ether (A) in acetonitrile solution, (dipic)V{sup v}(O)(pinOMe) (2) (PinOMe = 2,3-dimethyl-3-methoxy-2-butanoxide) was isolated in 61 % yield. Reaction of 1b with 2-phenoxyethanol (B) in acetonitrile gave the new complex (dipic)V{sup v}(O)(OPE) (3) (OPE = 2-phenoxyethoxide), which was isolated in 76% yield. In a similar fashion, 1a reacted with 1,2-diphenyl-2-methoxyethanol (C) to give (dipic)V(O)(DPME) (4) (DPME = 1,2-diphenyl-2-methoxyethoxide), which was isolated in 39% yield. Complexes 2, 3, and 4 were characterized by {sup 1}H NMR and IR spectroscopy, elemental analysis, and X-ray crystallography. Compared to the previously reported vanadium(V) pinacolate complex (dipic)V(O)(pinOH) the X-ray structure of complex 2 reveals a slightly shorter V = O bond, 1.573(2) {angstrom} vs 1.588(2) {angstrom} for the pinOH structure. Complexes 3 and 4 display similar vanadium oxo bond distances of 1.568(2) {angstrom} and 1.576(2) {angstrom}, respectively. All three complexes show longer bonds to the ether-oxygen trans to the oxo (2.388(2) {angstrom} for 2, 2.547(2) {angstrom} for 3, and 2.438(2) {angstrom} for 4) than to the hydroxy-oxygen in the pinOH structure (2.252(2) {angstrom}).

  9. Modeling of Groundwater Flow and Radionuclide Transport at the Climax Mine sub-CAU, Nevada Test Site

    SciTech Connect (OSTI)

    K. Pohlmann; M. Ye; D. Reeves; M. Zavarin; D. Decker; J. Chapman


    The Yucca Flat-Climax Mine Corrective Action Unit (CAU) on the Nevada Test Site comprises 747 underground nuclear detonations, all but three of which were conducted in alluvial, volcanic, and carbonate rocks in Yucca Flat. The remaining three tests were conducted in the very different hydrogeologic setting of the Climax Mine granite stock located in Area 15 at the northern end of Yucca Flat. As part of the Corrective Action Investigation (CAI) for the Yucca Flat-Climax Mine CAU, models of groundwater flow and radionuclide transport will be developed for Yucca Flat. However, two aspects of these CAU-scale models require focused modeling at the northern end of Yucca Flat beyond the capability of these large models. First, boundary conditions and boundary flows along the northern reaches of the Yucca Flat-Climax Mine CAU require evaluation to a higher level of detail than the CAU-scale Yucca Flat model can efficiently provide. Second, radionuclide fluxes from the Climax tests require analysis of flow and transport in fractured granite, a unique hydrologic environment as compared to Yucca Flat proper. This report describes the Climax Mine sub-CAU modeling studies conducted to address these issues, with the results providing a direct feed into the CAI for the Yucca Flat-Climax Mine CAU. Three underground nuclear detonations were conducted for weapons effects testing in the Climax stock between 1962 and 1966: Hard Hat, Pile Driver, and Tiny Tot. Though there is uncertainty regarding the position of the water table in the stock, it is likely that all three tests were conducted in the unsaturated zone. In the early 1980s, the Spent Fuel Test-Climax (SFT-C) was constructed to evaluate the feasibility of retrievable, deep geologic storage of commercial nuclear reactor wastes. Detailed mapping of fractures and faults carried out for the SFT-C studies greatly expanded earlier data sets collected in association with the nuclear tests and provided invaluable information for subsequent modeling studies at Climax. The objectives of the Climax Mine sub-CAU work are to (1) provide simulated heads and groundwater flows for the northern boundaries of the Yucca Flat-Climax Mine CAU model, while incorporating alternative conceptualizations of the hydrogeologic system with their associated uncertainty, and (2) provide radionuclide fluxes from the three tests in the Climax stock using modeling techniques that account for groundwater flow in fractured granite. Meeting these two objectives required two different model scales. The northern boundary groundwater fluxes were addressed using the Death Valley Regional Flow System (DVRFS) model (Belcher, 2004) developed by the U.S. Geological Survey as a modeling framework, with refined hydrostratigraphy in a zone north of Yucca Flat and including Climax stock. Radionuclide transport was simulated using a separate model confined to the granite stock itself, but linked to regional groundwater flow through boundary conditions and calibration targets.


    SciTech Connect (OSTI)

    Auger, M. W.; Treu, T.; Marshall, P. J.; Bolton, A. S.; Gavazzi, R.; Koopmans, L. V. E.; Moustakas, L. A.


    We use stellar masses, surface photometry, strong-lensing masses, and stellar velocity dispersions ({sigma}{sub e/2}) to investigate empirical correlations for the definitive sample of 73 early-type galaxies (ETGs) that are strong gravitational lenses from the SLACS survey. The traditional correlations (fundamental plane (FP) and its projections) are consistent with those found for non-lens galaxies, supporting the thesis that SLACS lens galaxies are representative of massive ETGs (dimensional mass M{sub dim} = 10{sup 11}-10{sup 12} M{sub sun}). The addition of high-precision strong-lensing estimates of the total mass allows us to gain further insights into their internal structure: (1) the average slope of the total mass-density profile ({rho}{sub tot}{proportional_to}r{sup -}{gamma}') is ({gamma}') = 2.078 {+-} 0.027 with an intrinsic scatter of 0.16 {+-} 0.02; (2) {gamma}' correlates with effective radius (r{sub e}) and central mass density, in the sense that denser galaxies have steeper profiles; (3) the dark matter (DM) fraction within r{sub e} /2 is a monotonically increasing function of galaxy mass and size (due to a mass-dependent central cold DM distribution or due to baryonic DM-stellar remnants or low-mass stars-if the initial mass function is non-universal and its normalization increases with mass); (4) the dimensional mass M{sub dim} {identical_to} 5r{sub e} {sigma}{sup 2}{sub e/2}/G is proportional to the total (lensing) mass M{sub r{sub e/2}}, and both increase more rapidly than stellar mass M{sub *} (M{sub *{proportional_to}}M{sub r{sub e/2}{sup 0.8}); (5) the mass plane (MP), obtained by replacing surface brightness with surface mass density in the FP, is found to be tighter and closer to the virial relation than the FP and the M{sub *}P, indicating that the scatter of those relations is dominated by stellar population effects; (6) we construct the fundamental hyper-plane by adding stellar masses to the MP and find the M{sub *} coefficient to be consistent with zero and no residual intrinsic scatter. Our results demonstrate that the dynamical structure of ETGs is not scale invariant and that it is fully specified by M{sub r{sub e/2}}, r{sub e} , and {sigma}{sub e/2}. Although the basic trends can be explained qualitatively in terms of varying star formation efficiency as a function of halo mass and as the result of dry and wet mergers, reproducing quantitatively the observed correlations and their tightness may be a significant challenge for galaxy formation models.

  11. Special Analysis of Transuranic Waste in Trench T04C at the Area 5 Radioactive Waste Management Site, Nevada Test Site, Nye County, Nevada, Revision 1

    SciTech Connect (OSTI)

    Greg Shott, Vefa Yucel, Lloyd Desotell


    This Special Analysis (SA) was prepared to assess the potential impact of inadvertent disposal of a limited quantity of transuranic (TRU) waste in classified Trench 4 (T04C) within the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada Test Site (NTS). The Area 5 RWMS is a low-level radioactive waste disposal site in northern Frenchman Flat on the Nevada Test Site (NTS). The Area 5 RWMS is regulated by the U.S. Department of Energy (DOE) under DOE Order 435.1 and DOE Manual (DOE M) 435.1-1. The primary objective of the SA is to evaluate if inadvertent disposal of limited quantities of TRU waste in a shallow land burial trench at the Area 5 RWMS is in compliance with the existing, approved Disposal Authorization Statement (DAS) issued under DOE M 435.1-1. In addition, supplemental analyses are performed to determine if there is reasonable assurance that the requirements of Title 40, Code of Federal Regulations (CFR), Part 191, Environmental Radiation Protection Standards for Management and Disposal of Spent Nuclear Fuel, High-Level, and Transuranic Radioactive Wastes, can be met. The 40 CFR 191 analyses provide supplemental information regarding the risk to human health and the environment of leaving the TRU waste in T04C. In 1989, waste management personnel reviewing classified materials records discovered that classified materials buried in trench T04C at the Area 5 RWMS contained TRU waste. Subsequent investigations determined that a total of 102 55-gallon drums of TRU waste from Rocky Flats were buried in trench T04C in 1986. The disposal was inadvertent because unclassified records accompanying the shipment indicated that the waste was low-level. The exact location of the TRU waste in T04C was not recorded and is currently unknown. Under DOE M 435.1-1, Chapter IV, Section P.5, low-level waste disposal facilities must obtain a DAS. The DAS specifies conditions that must be met to operate within the radioactive waste management basis, consisting of a performance assessment (PA), composite analysis (CA), closure plan, monitoring plan, waste acceptance criteria, and a PA/CA maintenance plan. The DOE issued a DAS for the Area 5 RWMS in 2000. The Area 5 RWMS DAS was, in part, based on review of a CA as required under DOE M 435.1-1, Chapter IV, Section P.(3). A CA is a radiological assessment required for DOE waste disposed before 26 September 1988 and includes the radiological dose from all sources of radioactive material interacting with all radioactive waste disposed at the Area 5 RWMS. The approved Area 5 RWMS CA, which includes the inventory of TRU waste in T04C, indicates that the Area 5 RWMS waste inventory and all interacting sources of radioactive material can meet the 0.3 mSv dose constraint. The composite analysis maximum annual dose for a future resident at the Area 5 RWMS was estimated to be 0.01 mSv at 1,000 years. Therefore, the inadvertent disposal of TRU in T04C is protective of the public and the environment, and compliant with all the applicable requirements in DOE M 435.1-1 and the DAS. The U.S. Environmental Protection Agency promulgated 40 CFR 191 to establish standards for the planned disposal of spent nuclear fuel, high level, and transuranic wastes in geologic repositories. Although not required, the National Nuclear Security Administration Nevada Site Office requested a supplemental analysis to evaluate the likelihood that the inadvertent disposal of TRU waste in T04C meets the requirements of 40 CFR 191. The SA evaluates the likelihood of meeting the 40 CFR 191 containment requirements (CRs), assurance requirements, individual protection requirements (IPRs), and groundwater protection standards. The results of the SA indicate that there is a reasonable expectation of meeting all the requirements of 40 CFR 191. The conclusion of the SA is that the Area 5 RWMS with the TRU waste buried in T04C is in compliance with all requirements in DOE M 435.1-1 and the DAS. Compliance with the DAS is demonstrated by the results of the Area 5 RWMS CA. Supplemental analyses in the SA indicate there is a reasonable expectation that the TRU in T04C can meet all the requirements of 40 CFR 191. Therefore, inadvertent disposal of a limited quantity of TRU in a shallow land burial trench at the Area 5 RWMS does not pose a significant risk to the public and the environment.