National Library of Energy BETA

Sample records for topics catalysis homogeneous

  1. Homogeneous and Interfacial Catalysis in 3D Controlled Environment | The

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ames Laboratory Homogeneous and Interfacial Catalysis in 3D Controlled Environment FWP/Project Description: Project Leader(s): Marek Pruski Principal Investigators: Marek Pruski, Aaron Sadow, Igor Slowing Key Scientific Personnel: Takeshi Kobayashi This collaborative research effort is geared toward bringing together the best features of homogeneous and heterogeneous catalysis for developing new catalytic principles. Novel silica-based, single-site mesoporous catalysts with controlled,

  2. Converting Homogeneous to Heterogeneous in Electrophilic Catalysis using Monodisperse Metal Nanoparticles

    SciTech Connect (OSTI)

    Witham, Cole A.; Huang, Wenyu; Tsung, Chia-Kuang; Kuhn, John N.; Somorjai, Gabor A.; Toste, F. Dean

    2009-10-15

    A continuing goal in catalysis is the transformation of processes from homogeneous to heterogeneous. To this end, nanoparticles represent a new frontier in heterogeneous catalysis, where this conversion is supplemented by the ability to obtain new or divergent reactivity and selectivity. We report a novel method for applying heterogeneous catalysts to known homogeneous catalytic reactions through the design and synthesis of electrophilic platinum nanoparticles. These nanoparticles are selectively oxidized by the hypervalent iodine species PhICl{sub 2}, and catalyze a range of {pi}-bond activation reactions previously only homogeneously catalyzed. Multiple experimental methods are utilized to unambiguously verify the heterogeneity of the catalytic process. The discovery of treatments for nanoparticles that induce the desired homogeneous catalytic activity should lead to the further development of reactions previously inaccessible in heterogeneous catalysis. Furthermore, our size and capping agent study revealed that Pt PAMAM dendrimer-capped nanoparticles demonstrate superior activity and recyclability compared to larger, polymer-capped analogues.

  3. ISHHC XIII International Symposium on the Relations betweenHomogeneous and Heterogeneous Catalysis

    SciTech Connect (OSTI)

    Somorjai , G.A.

    2007-06-11

    The International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC) has a long and distinguished history. Since 1974, in Brussels, this event has been held in Lyon, France (1977), Groeningen, The Netherlands (1981); Asilomar, California (1983); Novosibirsk, Russia (1986); Pisa, Italy (1989); Tokyo, Japan (1992); Balatonfuered, Hungary (1995); Southampton, United Kingdom (1999); Lyon, France (2001); Evanston, Illinois (2001) and Florence, Italy (2005). The aim of this international conference in Berkeley is to bring together practitioners in the three fields of catalysis, heterogeneous, homogeneous and enzyme, which utilize mostly nanosize particles. Recent advances in instrumentation, synthesis and reaction studies permit the nanoscale characterization of the catalyst systems, often for the same reaction, under similar experimental conditions. It is hoped that this circumstance will permit the development of correlations of these three different fields of catalysis on the molecular level. To further this goal we aim to uncover and focus on common concepts that emerge from nanoscale studies of structures and dynamics of the three types of catalysts. Another area of focus that will be addressed is the impact on and correlation of nanosciences with catalysis. There is information on the electronic and atomic structures of nanoparticles and their dynamics that should have importance in catalyst design and catalytic activity and selectivity.

  4. Surface functionalization of metal?organic polyhedron for homogeneous cyclopropanation catalysis

    SciTech Connect (OSTI)

    Lu, Weigang; Yuan, Daqiang; Yakovenko, Andrey; Zhou, Hong-Cai

    2012-03-13

    A super-paddlewheel (comprised of two paddlewheels) metal-organic polyhedron (MOP) containing surface hydroxyl groups was synthesized and characterized. Condensation reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst.

  5. Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2? In Operando-XAFS, Kinetic and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4 Cluster-Based Benzene Hydrogenation Catalysis

    SciTech Connect (OSTI)

    Bayram, Ercan; Linehan, John C.; Fulton, John L.; Roberts, John A.; Szymczak, Nathaniel; Smurthwaite, Tricia D.; Ozkar, Saim; Balasubramanian, Mahalingam; Finke, Richard G.

    2011-11-23

    Determining the true, kinetically dominant catalytically active species, in the classic benzene hydrogenation system pioneered by Maitlis and co-workers 34 years ago starting with [RhCp*Cl2]2 (Cp* = [{eta}5-C5(CH3)5]), has proven to be one of the most challenging case studies in the quest to distinguish single-metal-based 'homogeneous' from polymetallic, 'heterogeneous' catalysis. The reason, this study will show, is the previous failure to use the proper combination of (i) operando spectroscopy to determine the dominant form(s) of the precatalyst's mass under catalysis (i.e., operating) conditions, plus then and crucially also (ii) the previous lack of the necessary kinetic studies, catalysis being a 'wholly kinetic phenomenon' as J. Halpern long ago noted. An important contribution from this study will be to reveal the power of quantitiative kinetic poisoning experiments for distinguishing single-metal, or in this case subnanometer Rh4 cluster-based catalysis from larger, polymetallic Rh(0)n nanoparticle catalysis, at least under favorable conditions. The combined operando-XAFS (X-ray absorption fine structure) spectroscopy and kinetic evidences provide a compelling case for Rh4-based, with average stoichiometry 'Rh4Cp*2.4Cl4Hc', benzene hydrogenation catalysis in 2-propanol with added Et3N and at 100 C and 50 atm initial H2 pressure. The results also reveal, however, that if even ca. 1.4% of the total soluble Rh(0)n had formed nanoparticles, then those Rh(0)n nanoparticles would have been able to account for all the observed benzene hydrogenation catalytic rate (using commercial, ca. 2 nm, polyethyleneglycol-dodecylether hydrosol stabilized Rh(0)n nanoparticles as a model system). The results 'especially the poisoning methodology developed and employed' are of significant, broader interest since determining the nature of the true catalyst continues to be a central, often vexing issue in any and all catalytic reactions. The results are also of fundamental

  6. Virtual special issue on catalysis at the U.S. Department of Energy's National Laboratories

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pruski, Marek; Sadow, Aaron D.; Slowing, Igor I.; Marshall, Christopher L.; Stair, Peter; Rodriguez, Jose; Harris, Alex; Somorjai, Gabor A.; Biener, Juergen; Matranga, Christopher; et al

    2016-04-21

    Here the catalysis research at the U.S. Department of Energy's (DOE's) National Laboratories covers a wide range of research topics in heterogeneous catalysis, homogeneous/molecular catalysis, biocatalysis, electrocatalysis, and surface science. Since much of the work at National Laboratories is funded by DOE, the research is largely focused on addressing DOE's mission to ensure America's security and prosperity by addressing its energy, environmental, and nuclear challenges through transformative science and technology solutions.

  7. Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction. Task 1, Topical report No. 1

    SciTech Connect (OSTI)

    Laine, R.M.

    1986-01-20

    The purpose of this report is to update and reorganize our recent review on homogeneous catalysis of the water-gas shift reaction (WGSR) based on recent literature publications and patents. This updated version will serve as a means of selecting 10 candidate catalyst systems for use in developing effective, sulfur-tolerant, low temperature WGSR catalysts. This report discusses the variations possible in the basic chemistry associated with WGSR catalytic cycles, including basic, acidic, and neutral conditions. Then individual mechanism for specific WGSR catalyst systems are discussed. Finally, on the basis of the literature reports, a list is presented of candidate catalysts and basic systems we have chosen for study in Task 3.

  8. Catalysis | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Heterogeneous Catalysis - J. K. Norskov Homogeneous and Single-Site Heterogeneous Catalysis - Tobin Marks Thursday, May 16, 2002 - Breakout Summary Reports Catalysts Design Driven ...

  9. Fabrication of Carbon-Platinum Interdigitated Array Electrodes and Their Application for Investigating Homogeneous Hydrogen Evolution Catalysis

    SciTech Connect (OSTI)

    Liu, Fei; Divan, Ralu; Parkinson, Bruce A.

    2015-06-29

    Carbon interdigitated array (IDA) electrodes have been applied to study the homogeneous hydrogen evolution electrocatalyst [Ni(PPh2NBn2)2]2+ (where PPh2NBn2 is 1,5-dibenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane). The existence of reaction intermediates in the catalytic cycle is inferred from the electrochemical behavior of a glassy carbon disk electrodes and carbon IDA electrodes. The currents on IDA electrodes for an EC’ (electron transfer reaction followed by a catalytic reaction) mechanism are derived from the number of redox cycles and the contribution of non-catalytic currents. The catalytic reaction rate constant was then extracted from the IDA current equations. Applying the IDA current and kinetic equations to the electrochemical response of the [Ni(PPh2NBn2)2]2+ catalyst yielded a rate constant of 0.10 s-1 for the hydrogen evolution reaction that agrees with the literature value. The quantitative analysis of IDA cyclic voltammetry can be used as a simple and straightforward method for determining rate constants in other catalytic systems. This work was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for DOE. Use of the Center for Nanoscale Materials was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357.

  10. Catalysis Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Opportunities in Catalysis Research Using Synchrotron Radiation Stanford Synchrotron Radiation Laboratory October 8-9, 2002 Organizer: Anders Nilsson Chemical catalysis is one of the research areas of enormous importance for the industrial society. There are important challenges to be met in the near future where development of new processes and catalysts are a necessity. We need to find a way to make methanol from methane, split water into hydrogen using sunlight, find replacement of platinum

  11. DOE Laboratory Catalysis Research Symposium - Abstracts

    SciTech Connect (OSTI)

    Dunham, T.

    1999-02-01

    The conference consisted of two sessions with the following subtopics: (1) Heterogeneous Session: Novel Catalytic Materials; Photocatalysis; Novel Processing Conditions; Metals and Sulfides; Nuclear Magnetic Resonance; Metal Oxides and Partial Oxidation; Electrocatalysis; and Automotive Catalysis. (2) Homogeneous Catalysis: H-Transfer and Alkane Functionalization; Biocatalysis; Oxidation and Photocatalysis; and Novel Medical, Methods, and Catalyzed Reactions.

  12. EMSL and Institute for Integrated Catalysis (IIC) Catalysis Workshop

    SciTech Connect (OSTI)

    Campbell, Charles T.; Datye, Abhaya K.; Henkelman, Graeme A.; Lobo, Raul F.; Schneider, William F.; Spicer, Leonard D.; Tysoe, Wilfred T.; Vohs, John M.; Baer, Donald R.; Hoyt, David W.; Thevuthasan, Suntharampillai; Mueller, Karl T.; Wang, Chong M.; Washton, Nancy M.; Lyubinetsky, Igor; Teller, Raymond G.; Andersen, Amity; Govind, Niranjan; Kowalski, Karol; Kabius, Bernd C.; Wang, Hongfei; Campbell, Allison A.; Shelton, William A.; Bylaska, Eric J.; Peden, Charles HF; Wang, Yong; King, David L.; Henderson, Michael A.; Rousseau, Roger J.; Szanyi, Janos; Dohnalek, Zdenek; Mei, Donghai; Garrett, Bruce C.; Ray, Douglas; Futrell, Jean H.; Laskin, Julia; DuBois, Daniel L.; Kuprat, Laura R.; Plata, Charity

    2011-05-24

    Within the context of significantly accelerating scientific progress in research areas that address important societal problems, a workshop was held in November 2010 at EMSL to identify specific and topically important areas of research and capability needs in catalysis-related science.

  13. Workshop: Synchrotron Applications in Chemical Catalysis | Stanford

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synchrotron Radiation Lightsource Synchrotron Applications in Chemical Catalysis Tuesday, October 25, 2011 - 8:00am 2011 SSRL/LCLS Annual Users Conference This workshop, part of the 2011 SSRL/LCLS Annual Users Conference, will focus on understanding processes in homogeneous (both biological and small molecule) and heterogeneous catalysis, using synchrotron-based methods. The workshop will cover more traditional applications (using XANES and EXAFS), as well as applications of XES, RIXS and

  14. Seventh BES (Basic Energy Sciences) catalysis and surface chemistry research conference

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    Research programs on catalysis and surface chemistry are presented. A total of fifty-seven topics are included. Areas of research include heterogeneous catalysis; catalysis in hydrogenation, desulfurization, gasification, and redox reactions; studies of surface properties and surface active sites; catalyst supports; chemical activation, deactivation; selectivity, chemical preparation; molecular structure studies; sorption and dissociation. Individual projects are processed separately for the data bases. (CBS)

  15. A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst Covalently Attached to a Glassy Carbon Electrode: Preparation, Characterization, and Catalysis. Comparisons With the Homogeneous Analog

    SciTech Connect (OSTI)

    Das, Atanu K.; Engelhard, Mark H.; Bullock, R. Morris; Roberts, John A.

    2014-07-07

    A hydrogen-evolving homogeneous Ni(P2N2)2 electrocatalyst with peripheral ester groups has been covalently attached to a 1,2,3-triazolyllithium-terminated glassy carbon electrode. The surface-confined complex is an electroctalyst for hydrogen evolution, showing onset of catalytic current at the same potential as the soluble parent complex. X-ray photoemission spectra show excellent agreement between the coupled and homogeneous species. Coverage approaches a dense monolayer. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. The XPS measurements were performed at EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  16. 2012 Catalysis Lectures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Weckhuysen is since 2000 full professor Inorganic Chemistry and Catalysis at Utrecht University (The Netherlands). He is also scientific director of the Netherlands Institute of ...

  17. 2012 Catalysis Lectures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis Lectures May 21-24 2012 Bert Weckhuysen Bert Weckhuysen, who holds the chair of Inorganic Chemistry and Catalysis at Utrecht University, will give a series of catalysis lectures during his sabbatical period at Stanford University and SLAC. (1) "Characterization of Heterogeneous Catalysts: Possibilities and Limitations of In-situ Spectroscopy" (Part I) Monday, May 21, 2012, 4.30-6 p.m. Location: SLAC Redwood Conference Room C&D (2) "Characterization of Heterogeneous

  18. Catalysis by heteropoly compounds. XXII. Reactions of esters and esterification catalyzed by heteropolyacids in a homogeneous liquid phase - effects of the central atom of heteropolyanions having tungsten as the addenda atom

    SciTech Connect (OSTI)

    Hu, Changwen; Hashimoto, Masato; Okuhara, Toshio; Misono, Makoto )

    1993-10-01

    Decomposition of isobutyl propionate (IBP) (Reaction (1)), ester exchange of IBP with acetic acid (Reaction (2)), ester exchange of IBP with n-propyl alcohol (Reaction (3)), and esterification of propionic acid with isobutyl alcohol (Reaction (4)) have been studied in a homogeneous liquid phase using heteropolyacids H[sub m]XW[sub 12]O[sub 40] (X = P, Si, Ge, B, and Co) having the Keggin structure and H[sub 6]P[sub 2]W[sub 18]O[sub 62] having the Dawson structure. The results clearly indicated that the catalytic behavior of heteropolyacids remarkably depended on the kind of reaction system, namely, the basicity of reactants. For Reaction (1), the catalytic activities of the heteropolyacids were 60-100 times higher than those of H[sub 2]SO[sub 4] and p-toluenesulfonic acid. Among the heteropolyacids, the activity was in the order H[sub 3]PW[sub 12]O[sub 40] > H[sub 4]SiW[sub 12]O[sub 40] [approximately] H[sub 4]GeW[sub 12]O[sub 40] > H[sub 5]BW[sub 12]O[sub 40] > H[sub 6]CoW[sub 12]O[sub 40]. This order suggests that the activity follows the order of the acid strength of the solutions of heteropolyacids, which increases with the decrease in the negative charge of the polyanion. H[sub 6]P[sub 2]W[sub 18]O[sub 62] showed an activity between those of H[sub 5]BW[sub 12]O[sub 40] and H[sub 6]CoW[sub 12]O[sub 40]. Water molecules in the system retarded Reaction 1. For Reaction 2, the activity order was similar to that for Reaction 1 in the absence of water. However, contrary to Reaction 1, the addition of water greatly accelerated Reaction 2. It was presumed that, in the presence of water, Reaction 2 proceeds via the hydrolysis of IBP to propionic acid and isobutyl alcohol, followed by the esterification of isobutyl alcohol with acetic acid. 28 refs., 8 figs., 4 tabs.

  19. Neutrons for Catalysis: A Workshop on Neutron Scattering Techniques for Studies in Catalysis

    SciTech Connect (OSTI)

    Overbury, Steven {Steve} H; Coates, Leighton; Herwig, Kenneth W; Kidder, Michelle

    2011-10-01

    This report summarizes the Workshop on Neutron Scattering Techniques for Studies in Catalysis, held at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL) on September 16 and 17, 2010. The goal of the Workshop was to bring experts in heterogeneous catalysis and biocatalysis together with neutron scattering experimenters to identify ways to attack new problems, especially Grand Challenge problems in catalysis, using neutron scattering. The Workshop locale was motivated by the neutron capabilities at ORNL, including the High Flux Isotope Reactor (HFIR) and the new and developing instrumentation at the SNS. Approximately 90 researchers met for 1 1/2 days with oral presentations and breakout sessions. Oral presentations were divided into five topical sessions aimed at a discussion of Grand Challenge problems in catalysis, dynamics studies, structure characterization, biocatalysis, and computational methods. Eleven internationally known invited experts spoke in these sessions. The Workshop was intended both to educate catalyst experts about the methods and possibilities of neutron methods and to educate the neutron community about the methods and scientific challenges in catalysis. Above all, it was intended to inspire new research ideas among the attendees. All attendees were asked to participate in one or more of three breakout sessions to share ideas and propose new experiments that could be performed using the ORNL neutron facilities. The Workshop was expected to lead to proposals for beam time at either the HFIR or the SNS; therefore, it was expected that each breakout session would identify a few experiments or proof-of-principle experiments and a leader who would pursue a proposal after the Workshop. Also, a refereed review article will be submitted to a prominent journal to present research and ideas illustrating the benefits and possibilities of neutron methods for catalysis research.

  20. Zeolite catalysis: technology

    SciTech Connect (OSTI)

    Heinemann, H.

    1980-07-01

    Zeolites have been used as catalysts in industry since the early nineteen sixties. The great majority of commercial applications employ one of three zeolite types: zeolite Y; Mordenite; ZSM-5. By far the largest use of zeolites is in catalytic cracking, and to a lesser extent in hydrocracking. This paper reviews the rapid development of zeolite catalysis and its application in industries such as: the production of gasoline by catalytic cracking of petroleum; isomerization of C/sub 5/ and C/sub 6/ paraffin hydrocarbons; alkylation of aromatics with olefins; xylene isomerization; and conversion of methanol to gasoline.

  1. Electron Microscopy Catalysis Projects: Success Stories from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electron Microscopy Catalysis Projects: Success Stories from the High Temperature Materials Laboratory (HTML) User Program Electron Microscopy Catalysis Projects: Success Stories ...

  2. Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make ...

  3. Catalysis Capabilities | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis Research Areas Facilities and Equipment Intellectual Property Publications Staff Partnerships Licensing Sponsored Research Technical Services Technologist in Residence News Press Releases Feature Stories In the News Photos Videos Ombudsman Ombudsman Argonne National Laboratory Technology Development and Commercialization About Technologies Available for Licensing Capabilities Partnerships News Capabilities Catalysis Research Areas Facilities and Equipment Intellectual Property

  4. Enhanced Micellar Catalysis LDRD.

    SciTech Connect (OSTI)

    Betty, Rita G.; Tucker, Mark David; Taggart, Gretchen; Kinnan, Mark K.; Glen, Crystal Chanea; Rivera, Danielle; Sanchez, Andres; Alam, Todd Michael

    2012-12-01

    The primary goals of the Enhanced Micellar Catalysis project were to gain an understanding of the micellar environment of DF-200, or similar liquid CBW surfactant-based decontaminants, as well as characterize the aerosolized DF-200 droplet distribution and droplet chemistry under baseline ITW rotary atomization conditions. Micellar characterization of limited surfactant solutions was performed externally through the collection and measurement of Small Angle X-Ray Scattering (SAXS) images and Cryo-Transmission Electron Microscopy (cryo-TEM) images. Micellar characterization was performed externally at the University of Minnesota's Characterization Facility Center, and at the Argonne National Laboratory Advanced Photon Source facility. A micellar diffusion study was conducted internally at Sandia to measure diffusion constants of surfactants over a concentration range, to estimate the effective micelle diameter, to determine the impact of individual components to the micellar environment in solution, and the impact of combined components to surfactant phase behavior. Aerosolized DF-200 sprays were characterized for particle size and distribution and limited chemical composition. Evaporation rates of aerosolized DF-200 sprays were estimated under a set of baseline ITW nozzle test system parameters.

  5. Biomimetic Chalcogels for Solar Fuel Catalysis | ANSER Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomimetic Chalcogels for Solar Fuel Catalysis Home > Research > ANSER Research Highlights > Biomimetic Chalcogels for Solar Fuel Catalysis...

  6. Topic Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RAP Work Plan Topics Page 1 of 3 Topic Committee Potential FY 2016 Action/Product Context (from FY 2016 HAB Work Plan) 6-Month Status (IM, Committee, Advice, Deferred, No Action) 1. 100 Area retrieval process, K Basin RAP Project update (May not be ready until 2017 for an update; work ready in 2018 per milestone)  Attended tour in October 2015, including visit to MO-500/Sludge Annex facility 2. 100 D/H Proposed Plan RAP Project update Cleanup of soils and groundwater at D/H. Are the proposed

  7. Reaction Selectivity in Heterogeneous Catalysis

    SciTech Connect (OSTI)

    Somorjai, Gabor A.; Kliewer, Christopher J.

    2009-02-02

    The understanding of selectivity in heterogeneous catalysis is of paramount importance to our society today. In this review we outline the current state of the art in research on selectivity in heterogeneous catalysis. Current in-situ surface science techniques have revealed several important features of catalytic selectivity. Sum frequency generation vibrational spectroscopy has shown us the importance of understanding the reaction intermediates and mechanism of a heterogeneous reaction, and can readily yield information as to the effect of temperature, pressure, catalyst geometry, surface promoters, and catalyst composition on the reaction mechanism. DFT calculations are quickly approaching the ability to assist in the interpretation of observed surface spectra, thereby making surface spectroscopy an even more powerful tool. HP-STM has revealed three vitally important parameters in heterogeneous selectivity: adsorbate mobility, catalyst mobility, and selective site-blocking. The development of size controlled nanoparticles from 0.8 to 10 nm, of controlled shape, and of controlled bimetallic composition has revealed several important variables for catalytic selectivity. Lastly, DFT calculations may be paving the way to guiding the composition choice for multi-metallic heterogeneous catalysis for the intelligent design of catalysts incorporating the many factors of selectivity we have learned.

  8. 2013 DOE Catalysis Working Group Meeting Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    13 DOE Catalysis Working Group Meeting Agenda 2013 DOE Catalysis Working Group Meeting Agenda Agenda for the 2013 DOE Catalysis Working Group Meeting on May 15, 2013. cwg_may2013_agenda.pdf (89.11 KB) More Documents & Publications Catalysis Working Group Kick-Off Meeting Agenda DOE Durability Working Group June 2014 Meeting Agenda Catalysis Working Group Meeting: June 2015

  9. Catalysis Working Group | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis Working Group Catalysis Working Group The Catalysis Working Group (CWG) meets twice per year to exchange information, create synergies, and collaboratively develop both an understanding of and tools for studying electrocatalysis for polymer electrolyte fuel cells (PEFCs) and other low- and intermediate-temperature fuel cell systems, including direct methanol fuel cells (DMFCs), alkaline fuel cells (AFCs), alkaline membrane fuel cells (AMFCs), and phosphoric acid fuel cells (PAFCs). The

  10. Basic Research Needs: Catalysis for Energy

    SciTech Connect (OSTI)

    Bell, Alexis T.; Gates, Bruce C.; Ray, Douglas; Thompson, Michael R.

    2008-03-11

    The report presents results of a workshop held August 6-8, 2007, by DOE SC Basic Energy Sciences to determine the basic research needs for catalysis research.

  11. Workshop: Synchrotron Applications in Chemical Catalysis | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications in Chemical Catalysis Tuesday, October 25, 2011 - 8:00am 2011 SSRLLCLS Annual Users Conference This workshop, part of the 2011 SSRLLCLS Annual Users...

  12. Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... D2. Chemical Conversion: Alternatively, the sugars can be converted to fuels or an entire suite of other useful products using chemical catalysis. E. Product Recovery: Products are ...

  13. DOE Catalysis Working Group Meeting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    16, 2014 Marriott Wardman Park Hotel 2660 Woodley Road NM, Washington, D.C. 8:30 - 9:00 Continental breakfast: breads, coffee, tea Joint Durability and Catalysis Working Groups Meeting Delaware A 9:00 - 9:05 Welcome & introductory comments DWG co-chairs - Debbie Myers (ANL), Rod Borup (LANL), Donna Ho (DOE); CWG co-chairs - Piotr Zelenay (LANL), Nancy Garland (DOE) 9:05 - 9:25 Are We There Yet? Pt-Alloy Catalyst - Anu Kongkanand (GM) 9:25 - 9:45 Pt-Co/C Catalysts: PEMFC Performance and

  14. Pre-Competitive Catalysis Research: Fundamental Sulfation/Desulfation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of Lean NOx Traps Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of...

  15. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support ...

  16. The energy landscape of ;#8203;adenylate kinase during catalysis...

    Office of Scientific and Technical Information (OSTI)

    The energy landscape of ;8203;adenylate kinase during catalysis Citation Details In-Document Search Title: The energy landscape of ;8203;adenylate kinase during catalysis ...

  17. Materials Design and Discovery: Catalysis and Energy Storage...

    Office of Scientific and Technical Information (OSTI)

    Materials Design and Discovery: Catalysis and Energy Storage (Mira Early Science Program ... Citation Details In-Document Search Title: Materials Design and Discovery: Catalysis and ...

  18. Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts The Bioenergy ...

  19. Catalysis by Design - Theoretical and Experimental Studies of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis by Design - Theoretical and Experimental Studies of Model Catalysts for Lean NOx ... Lean NOx Traps - Microstructural Studies of Real World and Model Catalysts Catalysis by ...

  20. EERE Success Story-Fundamental Studies in Catalysis Enabled the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamental Studies in Catalysis Enabled the use of Efficient "Lean-Burn" Engines for Vehicle Transportation EERE Success Story-Fundamental Studies in Catalysis Enabled the use of ...

  1. Transmural Catalysis - High Efficiency Catalyst Systems for NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation ...

  2. Biomimetic Chalcogels for Solar Fuel Catalysis | ANSER Center |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne-Northwestern National Laboratory Biomimetic Chalcogels for Solar Fuel Catalysis Home > Research > ANSER Research Highlights > Biomimetic Chalcogels for Solar Fuel Catalysis

  3. "Nanocrystal bilayer for tandem catalysis"

    SciTech Connect (OSTI)

    Yamada, Yusuke; Tsung, Chia Kuang; Huang, Wenyu; Huo, Ziyang; E.Habas, Susan E; Soejima, Tetsuro; Aliaga, Cesar E; Samorjai, Gabor A; Yang, Peidong

    2011-01-24

    Supported catalysts are widely used in industry and can be optimized by tuning the composition and interface of the metal nanoparticles and oxide supports. Rational design of metal-metal oxide interfaces in nanostructured catalysts is critical to achieve better reaction activities and selectivities. We introduce here a new class of nanocrystal tandem catalysts that have multiple metal-metal oxide interfaces for the catalysis of sequential reactions. We utilized a nanocrystal bilayer structure formed by assembling platinum and cerium oxide nanocube monolayers of less than 10 nm on a silica substrate. The two distinct metal-metal oxide interfaces, CeO2-Pt and Pt-SiO2, can be used to catalyse two distinct sequential reactions. The CeO2-Pt interface catalysed methanol decomposition to produce CO and H2, which were subsequently used for ethylene hydroformylation catalysed by the nearby Pt-SiO2 interface. Consequently, propanal was produced selectively from methanol and ethylene on the nanocrystal bilayer tandem catalyst. This new concept of nanocrystal tandem catalysis represents a powerful approach towards designing high-performance, multifunctional nanostructured catalysts

  4. Center for Catalysis at Iowa State University

    SciTech Connect (OSTI)

    Kraus, George A.

    2006-10-17

    The overall objective of this proposal is to enable Iowa State University to establish a Center that enjoys world-class stature and eventually enhances the economy through the transfer of innovation from the laboratory to the marketplace. The funds have been used to support experimental proposals from interdisciplinary research teams in areas related to catalysis and green chemistry. Specific focus areas included: Catalytic conversion of renewable natural resources to industrial materials Development of new catalysts for the oxidation or reduction of commodity chemicals Use of enzymes and microorganisms in biocatalysis Development of new, environmentally friendly reactions of industrial importance These focus areas intersect with barriers from the MYTP draft document. Specifically, section 2.4.3.1 Processing and Conversion has a list of bulleted items under Improved Chemical Conversions that includes new hydrogenation catalysts, milder oxidation catalysts, new catalysts for dehydration and selective bond cleavage catalysts. Specifically, the four sections are: 1. Catalyst development (7.4.12.A) 2. Conversion of glycerol (7.4.12.B) 3. Conversion of biodiesel (7.4.12.C) 4. Glucose from starch (7.4.12.D) All funded projects are part of a soybean or corn biorefinery. Two funded projects that have made significant progress toward goals of the MYTP draft document are: Catalysts to convert feedstocks with high fatty acid content to biodiesel (Kraus, Lin, Verkade) and Conversion of Glycerol into 1,3-Propanediol (Lin, Kraus). Currently, biodiesel is prepared using homogeneous base catalysis. However, as producers look for feedstocks other than soybean oil, such as waste restaurant oils and rendered animal fats, they have observed a large amount of free fatty acids contained in the feedstocks. Free fatty acids cannot be converted into biodiesel using homogeneous base-mediated processes. The CCAT catalyst system offers an integrated and cooperative catalytic system

  5. Nanocrystal assembly for tandem catalysis

    DOE Patents [OSTI]

    Yang, Peidong; Somorjai, Gabor; Yamada, Yusuke; Tsung, Chia-Kuang; Huang, Wenyu

    2014-10-14

    The present invention provides a nanocrystal tandem catalyst comprising at least two metal-metal oxide interfaces for the catalysis of sequential reactions. One embodiment utilizes a nanocrystal bilayer structure formed by assembling sub-10 nm platinum and cerium oxide nanocube monolayers on a silica substrate. The two distinct metal-metal oxide interfaces, CeO.sub.2--Pt and Pt--SiO.sub.2, can be used to catalyze two distinct sequential reactions. The CeO.sub.2--Pt interface catalyzed methanol decomposition to produce CO and H.sub.2, which were then subsequently used for ethylene hydroformylation catalyzed by the nearby Pt--SiO.sub.2 interface. Consequently, propanal was selectively produced on this nanocrystal bilayer tandem catalyst.

  6. Heterogeneous Catalysis and Surface Science - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heterogeneous Catalysis and Surface Science / Part I: Surface Science in JCAP Laboratories Heterogeneous Catalysis and Surface Science research in JCAP focuses on the basic understanding of the relationships among the structure, composition, and reactivity of electrocatalysts. Knowledge gained from surface science experimentation can be implemented toward the discovery of better heterogeneous catalysts for solar-fuel production from carbon dioxide and water. REFERENCE Soriaga, M. P. et al.

  7. Catalysis and Synthesis | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis and Synthesis Catalysis and Synthesis Many different types of chemical reactions depend on catalysts in order to work, and the hunt for better catalysts has deep connections to our nation's economy. From biofuels to plastics, the majority of the products we depend on in our everyday lives rely on catalysts. An estimate from the American Chemical Society found that catalysts and catalytic processes are responsible for more than 20 percent of America's gross domestic product. The

  8. HOMOGENEOUS NUCLEAR POWER REACTOR

    DOE Patents [OSTI]

    King, L.D.P.

    1959-09-01

    A homogeneous nuclear power reactor utilizing forced circulation of the liquid fuel is described. The reactor does not require fuel handling outside of the reactor vessel during any normal operation including complete shutdown to room temperature, the reactor being selfregulating under extreme operating conditions and controlled by the thermal expansion of the liquid fuel. The liquid fuel utilized is a uranium, phosphoric acid, and water solution which requires no gus exhaust system or independent gas recombining system, thereby eliminating the handling of radioiytic gas.

  9. Advanced Resources for Catalysis Science; Recommendations for a National Catalysis Research Institute

    SciTech Connect (OSTI)

    Peden, Charles HF.; Ray, Douglas

    2005-10-05

    Catalysis is one of the most valuable contributors to our economy and historically an area where the United States has enjoyed, but is now losing, international leadership. While other countries are stepping up their work in this area, support for advanced catalysis research and development in the U.S. has diminished. Yet, more than ever, innovative and improved catalyst technologies are imperative for new energy production processes to ease our dependence on imported resources, for new energy-efficient and environmentally benign chemical production processes, and for new emission reduction technologies to minimize the environmental impact of an active and growing economy. Addressing growing concerns about the future direction of U.S. catalysis science, experts from the catalysis community met at a workshop to determine and recommend advanced resources needed to address the grand challenges for catalysis research and development. The workshop's primary conclusion: To recapture our position as the leader in catalysis innovation and practice, and promote crucial breakthroughs, the U.S. must establish one or more well-funded and well-equipped National Catalysis Research Institutes competitively selected, centered in the national laboratories and, by charter, networked to other national laboratories, universities, and industry. The Institute(s) will be the center of a national collaboratory that gives catalysis researchers access to the most advanced techniques available in the scientific enterprise. The importance of catalysis to our energy, economic, and environmental security cannot be overemphasized. Catalysis is a vital part of our core industrial infrastructure, as it is integral to chemical processing and petroleum refining, and is critical to proposed advances needed to secure a sustainable energy future. Advances in catalysis could reduce our need for foreign oil by making better use of domestic carbon resources, for example, allowing cost-effective and zero

  10. HOMOGENEOUS NUCLEAR REACTOR

    DOE Patents [OSTI]

    Hammond, R.P.; Busey, H.M.

    1959-02-17

    Nuclear reactors of the homogeneous liquid fuel type are discussed. The reactor is comprised of an elongated closed vessel, vertically oriented, having a critical region at the bottom, a lower chimney structure extending from the critical region vertically upwardly and surrounded by heat exchanger coils, to a baffle region above which is located an upper chimney structure containing a catalyst functioning to recombine radiolyticallydissociated moderator gages. In operation the liquid fuel circulates solely by convection from the critical region upwardly through the lower chimney and then downwardly through the heat exchanger to return to the critical region. The gases formed by radiolytic- dissociation of the moderator are carried upwardly with the circulating liquid fuel and past the baffle into the region of the upper chimney where they are recombined by the catalyst and condensed, thence returning through the heat exchanger to the critical region.

  11. Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenatio...

    Office of Scientific and Technical Information (OSTI)

    Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol Citation Details In-Document Search Title: Synergistic Catalysis between Pd and Fe in Gas Phase ...

  12. Shining Light on Catalysis | Stanford Synchrotron Radiation Lightsourc...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shining Light on Catalysis Tuesday, July 19, 2011 - 4:38pm SSRL Conference Room 137-322 Jeroen A. van Bokhoven, Professor for Heterogeneous Catalysis Institute for Chemical and...

  13. Study of catalysis of coal gasification at elevated pressures...

    Office of Scientific and Technical Information (OSTI)

    Study of catalysis of coal gasification at elevated pressures. Evaluation of 20 compounds at 850sup 0C Citation Details In-Document Search Title: Study of catalysis of coal ...

  14. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis ALS X-Rays Shine a New Light on Catalysis Print Thursday, 21 May 2015 11:16 Electrocatalysts are responsible for expediting reactions in...

  15. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Lean ...

  16. Opportunities in Catalysis Research Using Synchrotron Radiation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Catalysis Research Using Synchrotron Radiation Tuesday 10/8/02 Chair: Lars Pettersson 1:30-1:40 Anders Nilsson Welcome 1:40-2:30 Gabor Somorjai University of California, Berkeley and LBLN Need for New Directions of Research at the Frontiers of Catalysis Science 2:30-3:00 Geoff Thornton University of Manchester Influence of defects on the reactivity of ZnO 3:00-3:30 Anders Nilsson Stanford Synchrotron Radiation Laboratory Soft X-ray Spectroscopy of Surfaces and Reactions 3:30-3:45 Break Chair:

  17. Plasma Assisted Catalysis System for NOx Reduction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasma Assisted Catalysis System for NOx Reduction Plasma Assisted Catalysis System for NOx Reduction 2002 DEER Conference Presentation: Noxtech, Inc. 2002_deer_slone.pdf (595.6 KB) More Documents & Publications Noxtechs PAC System Development and Demonstration Lean NOx Catalysis Research and Development

  18. TEC Communications Topic Group

    Office of Environmental Management (EM)

    procurement - Routing criteriaemergency preparedness Tribal Issues Topic Group * TEPP Navajo Nation (Tom Clawson) - 1404 - Needs Assessment * Identified strengths and...

  19. TEC Communications Topic Group

    Office of Environmental Management (EM)

    Tribal Issues Topic Group Judith Holm, Chair April 21, 2004 Albuquerque, NM Tribal Issues Topic Group * February Tribal Summit with Secretary of Energy (Kristen Ellis, CI) - Held in conjunction with NCAI mid-year conference - First Summit held in response to DOE Indian Policy - Addressed barriers to communication and developing framework for interaction Tribal Issues Topic Group * Summit (continued) - Federal Register Notice published in March soliciting input on how to improve summit process

  20. UNIRIB: Physics Topics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics Research Capitalizing on the strengths of nine collaborating research ... Ion Beam (UNIRIB) consortium is conducting research at the forefront of nuclear physics. ...

  1. Nanoscale Advances in Catalysis and Energy Applications

    SciTech Connect (OSTI)

    Li, Yimin; Somorjai, Gabor A.

    2010-05-12

    In this perspective, we present an overview of nanoscience applications in catalysis, energy conversion, and energy conservation technologies. We discuss how novel physical and chemical properties of nanomaterials can be applied and engineered to meet the advanced material requirements in the new generation of chemical and energy conversion devices. We highlight some of the latest advances in these nanotechnologies and provide an outlook at the major challenges for further developments.

  2. USD Catalysis Group for Alternative Energy

    SciTech Connect (OSTI)

    Hoefelmeyer, James D.; Koodali, Ranjit; Sereda, Grigoriy; Engebretson, Dan; Fong, Hao; Puszynski, Jan; Shende, Rajesh; Ahrenkiel, Phil

    2012-03-13

    The South Dakota Catalysis Group (SDCG) is a collaborative project with mission to develop advanced catalysts for energy conversion with two primary goals: (1) develop photocatalytic systems in which polyfunctionalized TiO2 are the basis for hydrogen/oxygen synthesis from water and sunlight (solar fuels group), (2) develop new materials for hydrogen utilization in fuel cells (fuel cell group). In tandem, these technologies complete a closed chemical cycle with zero emissions.

  3. Heterogeneous Catalysis for Thermochemical Conversion | Bioenergy | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heterogeneous Catalysis for Thermochemical Conversion Our mission is to transform thermal biomass deconstruction products (syngas and pyrolysis oil) into the fuels and chemicals that keep society moving forward. Illustration of a stacked series of red and grey spheres in a square shape, where red spheres represent oxygen and grey spheres represent titanium) with a stack of orange and small white spheres, where orange spheres represent platinum and white spheres represent hydrogen, in a square

  4. CNEEC - TRG3: Nanoscale Control in Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRG3: Nanoscale control in catalysis TRG3 Leader: Thomas F. Jaramillo Participating CNEEC PI’s: Stacey Bent, Bruce Clemens, Arthur Grossman, Thomas F. Jaramillo, Jens Nørskov, Friedrich Prinz, Jennifer Wilcox The grand challenge in TRG3 is the manipulation of catalyst materials at the nanoscale to significantly improve activity and selectivity for energy conversion reactions. A number of promising renewable energy technologies such as fuel cells and solar fuel reactors depend upon the

  5. Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bioproducts | Department of Energy Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts The Bioenergy Technologies Office works with industry to develop pathways that use heat, pressure, and catalysis to convert domestic, non-food biomass into gasoline, jet fuel, and other products. thermochemical_four_pager.pdf (4.64 MB) More Documents & Publications 2013 Peer Review

  6. Shining Light on Catalysis | Stanford Synchrotron Radiation Lightsource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shining Light on Catalysis Tuesday, July 19, 2011 - 4:38pm SSRL Conference Room 137-322 Jeroen A. van Bokhoven, Professor for Heterogeneous Catalysis Institute for Chemical and Bioengineering ETH Zurich Head of Laboratory for Catalysis and Sustainable Chemistry (LSK) Swiss Light Source Paul Scherrer Institute Understanding a functioning catalyst requires understanding at the atomic scales in a time-resolved manner. X-rays can be readily used to accomplish that task, because of the large

  7. Catalysis Working Group Meeting: January 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    January 2015 Catalysis Working Group Meeting: January 2015 The Catalysis Working Group held a meeting on January 21, 2015, in Los Alamos, New Mexico. Meeting Agenda and Presentations Catalysis Working Group January 2015 Meeting Agenda (22.89 KB) Electrocatalysts with Ultra-Low PGM Loadings-Vojislav Stamenkovic, Argonne National Laboratory (15.95 MB) Improving Stability and Activity of Pt Monolayer in Non-Pt Core-Shell Electrocatalysts-Radoslav Adzic, Brookhaven National Laboratory (3.33 MB)

  8. Catalysis Working Group Meeting: June 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Catalysis Working Group Meeting: June 2015 The Catalysis Working Group held a meeting on June 8, 2015, in Arlington, Virginia, in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting. Meeting Agenda and Presentations Catalysis Working Group June 2015 Meeting Agenda (97.68 KB) Non-PGM Catalyst Targets: Summary-Piotr Zelenay, Los Alamos National Laboratory (657.07 KB) Alternative Metal Oxide Supports for Cathode Catalyst Powder in Automotive

  9. Catalysis Working Group Meeting: May 2013 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting: May 2013 Catalysis Working Group Meeting: May 2013 The Catalysis Working Group held a meeting on May 15, 2013, in Arlington, Virginia, in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting. Agenda Catalysis Working Group Meeting Agenda Presentations Electrocatalysts for Automotive Fuel Cells: Status and Challenges, Nilesh Dale, Nissan Technical Center North America Challenges for PEMFC Catalysts in Automotive Applications, Stephen

  10. Catalysis Science | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis Science Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs Reports and Activities Science Highlights Principal Investigators' Meetings BES Home Research Areas Catalysis Science Print Text Size: A A A FeedbackShare Page Notice: NOVEMBER 16, 2015 is the Catalysis Science target date for submission of proposals to be considered for funding within fiscal year 2016. Proposals

  11. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Broader source: Energy.gov (indexed) [DOE]

    Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Vehicle Technologies Office Merit Review 2016: Metal Oxide Nano-Array Catalysts for Low ...

  12. Control Heterogeneous Catalysis at Atomic and Electronic-level...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control Heterogeneous Catalysis at Atomic and Electronic-level Using Intermetallic Compounds Precious metals and metal alloys are important heterogeneous catalysts for renewable...

  13. Catalysis by Design: Bridging the Gap Between Theory and Experiments...

    Broader source: Energy.gov (indexed) [DOE]

    Catalysis by Design: Bridging the Gap between Theory and Experiments Catalyst by Design - Theoretical, Nanostructural, and Experimental Studies of Oxidation Catalyst for Diesel ...

  14. Visualizing Group II Intron Catalysis through the Stages of Splicing...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Visualizing Group II Intron Catalysis through the Stages of Splicing Citation Details In-Document Search Title: Visualizing Group II ...

  15. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme...

  16. Catalysis by Design: Bridging the Gap between Theory and Experiments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    between Theory and Experiments Catalysis by Design: Bridging the Gap between Theory and Experiments Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research ...

  17. Materials Design and Discovery: Catalysis and Energy Storage...

    Office of Scientific and Technical Information (OSTI)

    Materials Design and Discovery: Catalysis and Energy Storage (Mira Early Science Program Final Technical Report): ALCF-2 Early Science Program Technical Report Citation Details ...

  18. Computational catalyst screening: Scaling, bond-order and catalysis...

    Office of Scientific and Technical Information (OSTI)

    Computational catalyst screening: Scaling, bond-order and catalysis This content will become publicly available on December 29, 2017 Prev Next Title: Computational catalyst ...

  19. University of Delaware | Catalysis Center for Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modeling Activity map produced from the new high-throughput computational engine. Example for ethylene glycol catalysis. Reforming, hydrodeoxygenation, dehydrogenation, and ...

  20. Presentation: QER Energy Topics

    Office of Energy Efficiency and Renewable Energy (EERE)

    A briefing to the Secretary's Energy Advisory Board on QER Energy Topics (Energy Flows, Water Flows, and Program for Climate Model Diagnosis and Intercomparison) prepared by: A.J. Simon, Lawrence Livermore National Laboratory

  1. ARM - Topic List

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TeachersTopic List Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Topic List Atmosphere Atmospheric Heat Budget Atmospheric Pressure Composition of the Atmosphere Evolution of the Atmosphere Mesosphere Stratosphere Thermosphere Troposphere Oceans Oceans Sea Surface and Sea Level Weather and

  2. Lean NOx Catalysis Research and Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Catalysis Research and Development Lean NOx Catalysis Research and Development 2003 DEER Conference Presentation: Caterpillar, Inc. 2003_deer_park.pdf (588.44 KB) More Documents & Publications Lean-NOx Catalyst Development for Diesel Engine Applications Fuel Effects on Emissions Control Technologies

  3. Topical Committee | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topical Committee Topical Committee In the interest of optimum technology transfer, the DOE Technical Standards Program (TSP) has set up a network of topical committees. These committees provide a forum for communication across the DOE complex on technical standards related activities. If you would like information about a specific topical committee, or wish to join one of the groups, we've provided a roster of TSP Topical Committees and corresponding Topical Committee Chairpersons. Expectations

  4. Focus Group Meeting (Topical Meeting)

    Office of Energy Efficiency and Renewable Energy (EERE)

    Topical Meeting - Training Meeting agenda, summary and information package Meeting Date: April 30, 2008

  5. Catalysis Working Group Meeting: June 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Catalysis Working Group Meeting: June 2014 The Catalysis Working Group held a meeting on June 16, 2014, in Washington, D.C., in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting. Meeting Agenda and Presentations Catalysis Working Group June 2014 Meeting Agenda (100.38 KB) Are We There Yet? Pt-Alloy Catalysts-Anu Kongkanand, GM (1.05 MB) Pt-Co/C Catalysts: PEMFC Performance and Durability-Jim Waldecker, Ford (2.3 MB) Successes and

  6. Featured Topic Pages

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Featured Topic Pages * Renowned scientists, with information about the scientists' R&D results * Significant DOE research disciplines, with R&D results * Manhattan Project, including scientists and key events Laureates * Nobel Prize winners associated with DOE and predecessor agencies * Winners of the Enrico Fermi Award, a U.S. Presidential award Database * Selected documents about noteworthy R&D results * Documents and individual pages searchable by word or phrase * Tag cloud

  7. Manufacturing Innovation Topics Workshop

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Advanced Manufacturing Office (AMO) and the Office of the Secretary of Defense Manufacturing Technology Program (OSD ManTech) will host a workshop to discuss AMO's recent Request for Information (RFI) on Clean Energy Manufacturing Topic Areas as well as the recent areas of interest announced by OSD ManTech for a new Manufacturing Innovation Institute on October 8-9, 2014 in Fort Worth, TX.

  8. Coherence delay augmented laser beam homogenizer

    DOE Patents [OSTI]

    Rasmussen, Paul; Bernhardt, Anthony

    1993-01-01

    The geometrical restrictions on a laser beam homogenizer are relaxed by ug a coherence delay line to separate a coherent input beam into several components each having a path length difference equal to a multiple of the coherence length with respect to the other components. The components recombine incoherently at the output of the homogenizer, and the resultant beam has a more uniform spatial intensity suitable for microlithography and laser pantogography. Also disclosed is a variable aperture homogenizer, and a liquid filled homogenizer.

  9. Coherence delay augmented laser beam homogenizer

    DOE Patents [OSTI]

    Rasmussen, P.; Bernhardt, A.

    1993-06-29

    The geometrical restrictions on a laser beam homogenizer are relaxed by ug a coherence delay line to separate a coherent input beam into several components each having a path length difference equal to a multiple of the coherence length with respect to the other components. The components recombine incoherently at the output of the homogenizer, and the resultant beam has a more uniform spatial intensity suitable for microlithography and laser pantogography. Also disclosed is a variable aperture homogenizer, and a liquid filled homogenizer.

  10. Invariant distributions on compact homogeneous spaces

    SciTech Connect (OSTI)

    Gorbatsevich, V V

    2013-12-31

    In this paper, we study distributions on compact homogeneous spaces, including invariant distributions and also distributions admitting asub-Riemannian structure. We first consider distributions of dimension 1 and 2 on compact homogeneous spaces. After this, we study the cases of compact homogeneous spaces of dimension 2, 3, and 4 in detail. Invariant distributions on simply connected compact homogeneous spaces are also treated. Bibliography: 18 titles.

  11. Catalysis Working Group Kick-Off Meeting Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Arlington, VA - May 14, 2012 Catalysis Working Group Kick-off Meeting Co-Chairs: Piotr Zelenay Los Alamos National Laboratory Nancy L. Garland U.S. Department of Energy 2 2...

  12. Catalysis Center for Energy Innovation: University of Delaware

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MAT'LS TRANSFER FORM In The Spotlight Tweets by @CCEIUD Fueling the Quest for Green Energy August 24, 2016 -- Watch an introduction to the University of Delaware's Catalysis ...

  13. Theoretical Study on Catalysis by Protein Enzymes and Ribozyme

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theoretical Study on Catalysis by Protein Enzymes and Ribozyme Theoretical Study on Catalysis by Protein Enzymes and Ribozyme 2000 NERSC Annual Report 17shkarplus.jpg The energetics were determined for three mechanisms proposed for TIM catalyzed reactions. Results from reaction path calculations suggest that the two mechanisms that involve an enediol intermediate are likely to occur, while the direct intra-substrate proton transfer mechanism (in green) is energetically unfavorable due to the

  14. Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC) | U.S.

    Office of Science (SC) Website

    DOE Office of Science (SC) Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC) Print Text Size: A A A FeedbackShare Page IMASC Header Director Cynthia Friend Lead Institution Harvard University Year Established 2014 Mission To drive

  15. Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Make Fuels and Chemicals | Department of Energy Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals BETO works with the emerging U.S. bioindustry to sustainably convert non-food biomass resources into cost-competitive biofuels, biopower, and bioproducts. biochemical_four_pager.pdf (2.61 MB) More Documents & Publications Replacing the Whole

  16. Temperature Transient Effects in Plasma-Catalysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Temperature Transient Effects in Plasma-Catalysis Temperature Transient Effects in Plasma-Catalysis 2002 DEER Conference Presentation: Ford Motor Company 2002_deer_hoard.pdf (481.22 KB) More Documents & Publications Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction A Parametric Study of the Effect of Temperature and Hydrocarbon Species on the Product Distribution from a Non-Thermal Plasma Reactor Development of NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup Truck

  17. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis ALS X-Rays Shine a New Light on Catalysis Print Thursday, 21 May 2015 11:16 Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab

  18. Dedicated Beamline Facilities for Catalytic Research. Synchrotron Catalysis Consortium (SCC)

    SciTech Connect (OSTI)

    Chen, Jingguang; Frenkel, Anatoly; Rodriguez, Jose; Adzic, Radoslav; Bare, Simon R.; Hulbert, Steve L.; Karim, Ayman; Mullins, David R.; Overbury, Steve

    2015-03-04

    Synchrotron spectroscopies offer unique advantages over conventional techniques, including higher detection sensitivity and molecular specificity, faster detection rate, and more in-depth information regarding the structural, electronic and catalytic properties under in-situ reaction conditions. Despite these advantages, synchrotron techniques are often underutilized or unexplored by the catalysis community due to various perceived and real barriers, which will be addressed in the current proposal. Since its establishment in 2005, the Synchrotron Catalysis Consortium (SCC) has coordinated significant efforts to promote the utilization of cutting-edge catalytic research under in-situ conditions. The purpose of the current renewal proposal is aimed to provide assistance, and to develop new sciences/techniques, for the catalysis community through the following concerted efforts: Coordinating the implementation of a suite of beamlines for catalysis studies at the new NSLS-II synchrotron source; Providing assistance and coordination for catalysis users at an SSRL catalysis beamline during the initial period of NSLS to NSLS II transition; Designing in-situ reactors for a variety of catalytic and electrocatalytic studies; Assisting experimental set-up and data analysis by a dedicated research scientist; Offering training courses and help sessions by the PIs and co-PIs.

  19. TEC Working Group Topic Groups Archives Consolidated Grant Topic Group |

    Office of Environmental Management (EM)

    Department of Energy Consolidated Grant Topic Group TEC Working Group Topic Groups Archives Consolidated Grant Topic Group The Consolidated Grant Topic Group arose from recommendations provided by the TEC and other external parties to the DOE Senior Executive Transportation Forum in July 1998. It was proposed that the consolidation of multiple funding streams from numerous DOE sources into a single grant would provide a more equitable and efficient means of assistance to States and Tribes

  20. Some General Themes in Catalysis at LANL

    SciTech Connect (OSTI)

    Gordon, John C.

    2012-07-19

    Some general themes in catalysis at LANL are: (1) Storage and release of energy within chemical bonds (e.g. H{sub 2} storage in and release from covalent bonds, N{sub 2} functionalization, CO{sub 2} functionalization, H{sub 2} oxidation/evolution, O{sub 2} reduction/evolution); (2) Can we control the chemistry of reactive substrates to effect energy relevant transformations in non-traditional media (e.g. can we promote C-C couplings, dehydrations, or hydrogenations in water under relatively mild conditions)? (3) Can we supplant precious metal or rare earth catalysts to effect these transformations, by using earth abundant metals/elements instead? Can we use organocatalysis and circumvent the use of metals completely? (4) Can we improve upon existing rare earth catalyst systems (e.g. in rare earth oxides pertinent to fluid cracking or polymerization) and reduce amounts required for catalytic efficacy? Carbohydrates can be accessed from non-food based biomass sources such as woody residues and switchgrass. After extracted from the plant source, our goal is to upgrade these classes of molecules into useful fuels.

  1. TECHNICAL STANDARDS PROGRAM TOPICAL COMMITTEES

    Broader source: Energy.gov [DOE]

    PurposeThis procedure describes how topical committees are organized and recognized under the Technical Standards Program. 

  2. One- and two-dimensional infrared spectroscopic studies of solution-phase homogeneous catalysis and spin-forbidden reactions

    SciTech Connect (OSTI)

    Sawyer, Karma Rae

    2008-12-12

    Understanding chemical reactions requires the knowledge of the elementary steps of breaking and making bonds, and often a variety of experimental techniques are needed to achieve this goal. The initial steps occur on the femto- through picosecond time-scales, requiring the use of ultrafast spectroscopic methods, while the rate-limiting steps often occur more slowly, requiring alternative techniques. Ultrafast one and two-dimensional infrared and step-scan FTIR spectroscopies are used to investigate the photochemical reactions of four organometallic complexes. The analysis leads to a detailed understanding of mechanisms that are general in nature and may be applicable to a variety of reactions.

  3. AQUEOUS HOMOGENEOUS REACTORTECHNICAL PANEL REPORT

    SciTech Connect (OSTI)

    Diamond, D.J.; Bajorek, S.; Bakel, A.; Flanagan, G.; Mubayi, V.; Skarda, R.; Staudenmeier, J.; Taiwo, T.; Tonoike, K.; Tripp, C.; Wei, T.; Yarsky, P.

    2010-12-03

    Considerable interest has been expressed for developing a stable U.S. production capacity for medical isotopes and particularly for molybdenum- 99 (99Mo). This is motivated by recent re-ductions in production and supply worldwide. Consistent with U.S. nonproliferation objectives, any new production capability should not use highly enriched uranium fuel or targets. Conse-quently, Aqueous Homogeneous Reactors (AHRs) are under consideration for potential 99Mo production using low-enriched uranium. Although the Nuclear Regulatory Commission (NRC) has guidance to facilitate the licensing process for non-power reactors, that guidance is focused on reactors with fixed, solid fuel and hence, not applicable to an AHR. A panel was convened to study the technical issues associated with normal operation and potential transients and accidents of an AHR that might be designed for isotope production. The panel has produced the requisite AHR licensing guidance for three chapters that exist now for non-power reactor licensing: Reac-tor Description, Reactor Coolant Systems, and Accident Analysis. The guidance is in two parts for each chapter: 1) standard format and content a licensee would use and 2) the standard review plan the NRC staff would use. This guidance takes into account the unique features of an AHR such as the fuel being in solution; the fission product barriers being the vessel and attached systems; the production and release of radiolytic and fission product gases and their impact on operations and their control by a gas management system; and the movement of fuel into and out of the reactor vessel.

  4. Homogeneous catalysts in hypersonic combustion

    SciTech Connect (OSTI)

    Harradine, D.M.; Lyman, J.L.; Oldenborg, R.C.; Pack, R.T.; Schott, G.L.

    1989-01-01

    Density and residence time both become unfavorably small for efficient combustion of hydrogen fuel in ramjet propulsion in air at high altitude and hypersonic speed. Raising the density and increasing the transit time of the air through the engine necessitates stronger contraction of the air flow area. This enhances the kinetic and thermodynamic tendency of H/sub 2/O to form completely, accompanied only by N/sub 2/ and any excess H/sub 2/(or O/sub 2/). The by-products to be avoided are the energetically expensive fragment species H and/or O atoms and OH radicals, and residual (2H/sub 2/ plus O/sub 2/). However, excessive area contraction raises air temperature and consequent combustion-product temperature by adiabatic compression. This counteracts and ultimately overwhelms the thermodynamic benefit by which higher density favors the triatomic product, H/sub 2/O, over its monatomic and diatomic alternatives. For static pressures in the neighborhood of 1 atm, static temperature must be kept or brought below ca. 2400 K for acceptable stability of H/sub 2/O. Another measure, whose requisite chemistry we address here, is to extract propulsive work from the combustion products early in the expansion. The objective is to lower the static temperature of the combustion stream enough for H/sub 2/O to become adequately stable before the exhaust flow is massively expanded and its composition ''frozen.'' We proceed to address this mechanism and its kinetics, and then examine prospects for enhancing its rate by homogeneous catalysts. 9 refs.

  5. [Zeolite catalysis in conversion of cellulosics

    SciTech Connect (OSTI)

    Tsao, G.T.

    1992-12-31

    To transform biomass into fermentable substrate for yeast, we are using zeolites instead of enzymes to catalyze the two bottleneck reactions in biomass conversion, xylose isomerization and ceuobiose hydrolysis. The experimental results on these reactions carried out over various zeolites and other catalysts are presented herein. The advantages and disadvantages of using these catalysts over enzymes are also discussed. Heterogeneous solid catalysts other than zeolites has been employed for cellobiose-to-glucose hydrolysis. The size and shape selectivity that makes zeoutes unique for some reactions can add diffusional hindrance. We have spent some time screening various known solid acidic catalysts. We report that a class of cationic ion exchange resins in the acidified form (e.g. Amberlite) has worked well as an acidic catalyst in hydrolyzing cellobiose to glucose. Our experimental results, together with those obtained from a homogeneous acid catalyst (e.g. sulfuric acid) for comparison are provided. Having succeeded in finding an alternative solid acid catalyst for hydrolysis, we explored other solid resin or other homogeneous but non-enzyme catalyst to carry out the xylose-to-xylulose isomerization. A fairly extensive search has been made. We explored the use of sodium aluminates in the homogeneous phase isomerization of glucose to fructose and obtained a very high conversion of glucose to fructose with the final mixture containing 85% of fructose instead of the common 45%. Fructose apparently complexes with aluminates, and its equilibrium concentration is shifted to considerably higher values than permitted by simple glucose/fructose equilibrium. We have recently found a number of catalysts capable of promoting isomerization between aldoses and ketoses. One solid resin, known as polyvinyl pyridine (PVP), is able to convert xylose to xylulose at a pH below 7. Our usage of alternative isomerization catalysts, including PVP, are described.

  6. [Zeolite catalysis in conversion of cellulosics

    SciTech Connect (OSTI)

    Tsao, G.T.

    1992-01-01

    To transform biomass into fermentable substrate for yeast, we are using zeolites instead of enzymes to catalyze the two bottleneck reactions in biomass conversion, xylose isomerization and ceuobiose hydrolysis. The experimental results on these reactions carried out over various zeolites and other catalysts are presented herein. The advantages and disadvantages of using these catalysts over enzymes are also discussed. Heterogeneous solid catalysts other than zeolites has been employed for cellobiose-to-glucose hydrolysis. The size and shape selectivity that makes zeoutes unique for some reactions can add diffusional hindrance. We have spent some time screening various known solid acidic catalysts. We report that a class of cationic ion exchange resins in the acidified form (e.g. Amberlite) has worked well as an acidic catalyst in hydrolyzing cellobiose to glucose. Our experimental results, together with those obtained from a homogeneous acid catalyst (e.g. sulfuric acid) for comparison are provided. Having succeeded in finding an alternative solid acid catalyst for hydrolysis, we explored other solid resin or other homogeneous but non-enzyme catalyst to carry out the xylose-to-xylulose isomerization. A fairly extensive search has been made. We explored the use of sodium aluminates in the homogeneous phase isomerization of glucose to fructose and obtained a very high conversion of glucose to fructose with the final mixture containing 85% of fructose instead of the common 45%. Fructose apparently complexes with aluminates, and its equilibrium concentration is shifted to considerably higher values than permitted by simple glucose/fructose equilibrium. We have recently found a number of catalysts capable of promoting isomerization between aldoses and ketoses. One solid resin, known as polyvinyl pyridine (PVP), is able to convert xylose to xylulose at a pH below 7. Our usage of alternative isomerization catalysts, including PVP, are described.

  7. Homogeneously dispersed, multimetal oxygen-evolving catalysts...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Homogeneously dispersed, multimetal oxygen-evolving catalysts Citation ... Publication Date: 2016-03-24 OSTI Identifier: 1245398 Report ...

  8. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control 2002deeraardahl.pdf (7.98 ...

  9. Catalysis Working Group Kick-Off Meeting Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis Working Group Kick-Off Meeting Agenda Catalysis Working Group Kick-Off Meeting Agenda Agenda for the kick-off meeting of the U.S. Department of Energy Fuel Cell Technologies Program's Catalysis Working Group, held May 14, 2012, in Arlington, Virginia. 1_cwg_may2012_agenda.pdf (34.13 KB) More Documents & Publications Operando Raman and Theoretical Vibration Spectroscopy of Non-PGM Catalysts 2013 DOE Catalysis Working Group Meeting Agenda Advanced Cathode Catalysts

  10. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control 2002_deer_aardahl.pdf (7.98 MB) More Documents & Publications Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Selective reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies

  11. Homogeneous fluorescence linewidths for amorphous hosts

    SciTech Connect (OSTI)

    Lyo, S.K.; Orbach, R.

    1980-11-01

    A contribution to the homogeneous linewidth of optical transitions in amorphous hosts is calculated. The microscopic process is diagonal in the phonon interaction with two level systems (TLS) common to amorphous materials, and diagonal in the coupling between TLS and the optical center. The model predicts an optical homogeneous linewidth proportional to the square of the temperature at low temperature.

  12. Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and SCR | Department of Energy Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_atkinson.pdf (327.1 KB) More Documents & Publications Reductant Utilization in a LNT + SCR System Lean NOx Trap

  13. Special Topics and Data Reports

    U.S. Energy Information Administration (EIA) Indexed Site

    (HTML format) Yellow Arrow Energy Consumption and Expenditures (HTML format) adobe logo Download Acrobat Reader for viewing PDF files. Special Topics and Data Reports...

  14. Innovative Topics for Advanced Biofuels

    Broader source: Energy.gov (indexed) [DOE]

    Innovative Topics for Advanced Biofuels Jonathan Male, Ph.D. PNNL Report-Out Webinar ... into biomass sugars to feed advanced biofuels Separations - Compatibility with ...

  15. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E; Storey, John Morse; Theiss, Timothy J; Ponnusamy, Senthil; Ferguson, Harley Douglas; Williams, Aaron M; Tassitano, James B

    2007-09-01

    efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial

  16. Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction

    SciTech Connect (OSTI)

    Laine, R.M.

    1986-01-20

    The purpose of this report is to update and reorganize our recent review on homogeneous catalysis of the water-gas shift reaction (WGSR) based on recent literature publications and patents. This updated version will serve as a means of selecting 10 candidate catalyst systems for use in developing effective, sulfur-tolerant, low temperature WGSR catalysts. This report discusses the variations possible in the basic chemistry associated with WGSR catalytic cycles, including basic, acidic, and neutral conditions. Then individual mechanism for specific WGSR catalyst systems are discussed. Finally, on the basis of the literature reports, a list is presented of candidate catalysts and basic systems we have chosen for study in Task 3.

  17. Events & Topics | Metrolink Tour | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics | Metrolink Tour Events & Topics | Metrolink Tour

  18. Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2

    SciTech Connect (OSTI)

    Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.; Dobbek, Holger; DuBois, Daniel L.; Dupuis, Michel; Ferry, James G.; Fujita, Etsuko; Hille, Russ; Kenis, Paul; Kerfeld, Cheryl A.; Morris, Robert H.; Peden, Charles HF; Portis, Archie; Ragsdale, Steve; Rauchfuss, Thomas B.; Reek, Joost; Seefeldt, Lance C.; Thauer, Rudolf K.; Waldrop, Grover L.

    2013-08-14

    Our central premise is that catalytic scientists can learn by studying how these important metabolic processes occur in nature. Complementarily, biochemists can learn by studying how catalytic scientists view these same chemical transformations promoted by synthetic catalysts. From these studies, hypotheses can be developed and tested through manipulation of enzyme structure and by synthesizing simple molecular catalysts to incorporate different structural features of the enzymes. It is hoped that these studies will lead to new and useful concepts in catalyst design for fuel production and utilization. This paper describes the results of a workshop held to explore these concepts in regard to the development of new and more efficient catalytic processes for the conversion of CO2 to a variety of carbon-based fuels. The organization of this overview/review is as follows: 1) The first section briefly explores how interactions between the catalysis and biological communities have been fruitful in developing new catalysts for the reduction of protons to hydrogen, the simplest fuel generation reaction. 2) The second section assesses the state of the art in both biological and chemical reduction of CO2 by two electrons to form either carbon monoxide (CO) or formate (HCOO-). It also attempts to identify common principles between biological and synthetic catalysts and productive areas for future research. 3) The third section explores both biological and chemical processes that result in the reduction of CO2 beyond the level of CO and formate, again seeking to identify common principles and productive areas of future research. 4) The fourth section explores the formation of carbon-carbon bonds in biological and chemical systems in the same vein as the other sections. 5) A fifth section addresses the role of non-redox reactions of CO2 in biological systems and their role in carbon metabolism, with a parallel discussion of chemical systems. 6) In section 6, the topics of

  19. Methanol Synthesis over Cu/ZnO/Al2O3: The Active Site in Industrial Catalysis

    SciTech Connect (OSTI)

    Behrens, Malte

    2012-03-28

    Unlike homogeneous catalysts, heterogeneous catalysts that have been optimized through decades are typically so complex and hard to characterize that the nature of the catalytically active site is not known. This is one of the main stumbling blocks in developing rational catalyst design strategies in heterogeneous catalysis. We show here how to identify the crucial atomic structure motif for the industrial Cu/ZnO/Al{sub 2}O{sub 3} methanol synthesis catalyst. Using a combination of experimental evidence from bulk-, surface-sensitive and imaging methods collected on real high-performance catalytic systems in combination with DFT calculations. We show that the active site consists of Cu steps peppered with Zn atoms, all stabilized by a series of well defined bulk defects and surface species that need jointly to be present for the system to work.

  20. Molecular-Level Design of Heterogeneous Chiral Catalysis

    SciTech Connect (OSTI)

    Francisco Zaera

    2012-03-21

    The following is a proposal to continue our multi-institutional research on heterogeneous chiral catalysis. Our team combines the use of surface-sensitive analytical techniques for the characterization of model systems with quantum and statistical mechanical calculations to interpret experimental data and guide the design of future research. Our investigation focuses on the interrelation among the three main mechanisms by which enantioselectivity can be bestowed to heterogeneous catalysts, namely: (1) by templating chirality via the adsorption of chiral supramolecular assemblies, (2) by using chiral modifiers capable of forming chiral complexes with the reactant and force enantioselective surface reactions, and (3) by forming naturally chiral surfaces using imprinting chiral agents. Individually, the members of our team are leaders in these various aspects of chiral catalysis, but the present program provides the vehicle to generate and exploit the synergies necessary to address the problem in a comprehensive manner. Our initial work has advanced the methodology needed for these studies, including an enantioselective titration procedure to identify surface chiral sites, infrared spectroscopy in situ at the interface between gases or liquids and solids to mimic realistic catalytic conditions, and DFT and Monte Carlo algorithms to simulate and understand chirality on surfaces. The next step, to be funded by the monies requested in this proposal, is to apply those methods to specific problems in chiral catalysis, including the identification of the requirements for the formation of supramolecular surface structures with enantioselective behavior, the search for better molecules to probe the chiral nature of the modified surfaces, the exploration of the transition from supramolecular to one-to-one chiral modification, the correlation of the adsorption characteristics of one-to-one chiral modifiers with their physical properties, in particular with their configuration

  1. Recent advances of lanthanum-based perovskite oxides for catalysis

    SciTech Connect (OSTI)

    Zhu, Huiyuan; Zhang, Pengfei; Dai, Sheng

    2015-09-21

    There is a need to reduce the use of noble metal elements especially in the field of catalysis, where noble metals are ubiquitously applied. To this end, perovskite oxides, an important class of mixed oxide, have been attracting increasing attention for decades as potential replacements. Benefiting from the extraordinary tunability of their compositions and structures, perovskite oxides can be rationally tailored and equipped with targeted physical and chemical properties e.g. redox behavior, oxygen mobility, and ion conductivity for enhanced catalysis. Recently, the development of highly efficient perovskite oxide catalysts has been extensively studied. This review article summarizes the recent development of lanthanum-based perovskite oxides as advanced catalysts for both energy conversion applications and traditional heterogeneous reactions.

  2. Recent advances of lanthanum-based perovskite oxides for catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Huiyuan; Zhang, Pengfei; Dai, Sheng

    2015-09-21

    There is a need to reduce the use of noble metal elements especially in the field of catalysis, where noble metals are ubiquitously applied. To this end, perovskite oxides, an important class of mixed oxide, have been attracting increasing attention for decades as potential replacements. Benefiting from the extraordinary tunability of their compositions and structures, perovskite oxides can be rationally tailored and equipped with targeted physical and chemical properties e.g. redox behavior, oxygen mobility, and ion conductivity for enhanced catalysis. Recently, the development of highly efficient perovskite oxide catalysts has been extensively studied. This review article summarizes the recent developmentmore » of lanthanum-based perovskite oxides as advanced catalysts for both energy conversion applications and traditional heterogeneous reactions.« less

  3. Catalysis by Design: Bridging the Gap between Theory and Experiments |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy between Theory and Experiments Catalysis by Design: Bridging the Gap between Theory and Experiments Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). deer07_narula.pdf (372.33 KB) More Documents & Publications Catalysts via First Principles Catalysts via First

  4. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  5. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  6. Advanced Electronic Structure Methods for Heterogeneous Catalysis and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Separation of Heavy Metals | Argonne Leadership Computing Facility The research team is also using GAMESS in an INCITE project entitled State-of-the-Art Simulations of Liquid Phenomena. As part of the INCITE work, they predicted that the turning point between surface and interior solvation in a nitrate ion occurs at a cluster size of around 64 water molecules. Spencer Pruitt, Argonne National Laboratory Advanced Electronic Structure Methods for Heterogeneous Catalysis and Separation of Heavy

  7. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  8. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  9. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  10. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  11. Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Iron Catalysis in Oxidations by Ozone Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Ozone is used commercially for treatment of potable and non-potable water, and as an industrial oxidant. ISU and Ames Laboratory researchers have developed a method for using iron in ozone oxidation that significantly improves the speed of oxidation reactions. Description Ozone is recognized as potent and effective oxidizing agent, and has a

  12. Assessment of Homogeneous Thorium/Uranium Fuel for Pressurized...

    Office of Scientific and Technical Information (OSTI)

    Fuel for Pressurized Water Reactors Citation Details In-Document Search Title: Assessment of Homogeneous ThoriumUranium Fuel for Pressurized Water Reactors The homogeneous ...

  13. Distribution of Radiation Density in a Homogeneous Cloudy Laye

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Radiation Density in a Homogeneous Cloudy Layer S. V. Dvoryashin, K. A. Shukorov, A. H. ... method) allowing calculating radiation density in homogeneous and non-uniform ...

  14. Anomalous Behavior of the Homogeneous Ice Nucleation Rate in...

    Office of Scientific and Technical Information (OSTI)

    Published Article: Anomalous Behavior of the Homogeneous Ice Nucleation Rate in "No-Man's Land" Prev Next Title: Anomalous Behavior of the Homogeneous Ice Nucleation Rate in ...

  15. EERE Success Story-Fundamental Studies in Catalysis Enabled the use of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficient "Lean-Burn" Engines for Vehicle Transportation | Department of Energy Fundamental Studies in Catalysis Enabled the use of Efficient "Lean-Burn" Engines for Vehicle Transportation EERE Success Story-Fundamental Studies in Catalysis Enabled the use of Efficient "Lean-Burn" Engines for Vehicle Transportation May 7, 2015 - 1:29pm Addthis Building on a catalysis research program sponsored by EERE's Vehicles Technology Office (VTO) and DOE's Office of

  16. Missouri Botanical Gardens Tour | Events & Topics | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Events & Topics Missouri Botanical Gardens Tour | Events & Topics PARC welcomed community members for our guided tour of the Missouri Botanical Garden. http:...

  17. Events & Topics In Bioenergy | Photosynthetic Antenna Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics In Bioenergy Events & Topics In Bioenergy Dr. Chenyang Lu Smart Building with Wireless Sensor Networks Dr. Joseph Cullen "Measuring the Environmental Benefits of ...

  18. Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites...

    Office of Scientific and Technical Information (OSTI)

    low temperature oxygen electro catalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and Metal-air batteries. ...

  19. A numerical homogenization method for heterogeneous, anisotropic elastic media based on multiscale theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gao, Kai; Chung, Eric T.; Gibson, Richard L.; Fu, Shubin; Efendiev, Yalchin

    2015-06-05

    The development of reliable methods for upscaling fine scale models of elastic media has long been an important topic for rock physics and applied seismology. Several effective medium theories have been developed to provide elastic parameters for materials such as finely layered media or randomly oriented or aligned fractures. In such cases, the analytic solutions for upscaled properties can be used for accurate prediction of wave propagation. However, such theories cannot be applied directly to homogenize elastic media with more complex, arbitrary spatial heterogeneity. We therefore propose a numerical homogenization algorithm based on multiscale finite element methods for simulating elasticmore » wave propagation in heterogeneous, anisotropic elastic media. Specifically, our method used multiscale basis functions obtained from a local linear elasticity problem with appropriately defined boundary conditions. Homogenized, effective medium parameters were then computed using these basis functions, and the approach applied a numerical discretization that is similar to the rotated staggered-grid finite difference scheme. Comparisons of the results from our method and from conventional, analytical approaches for finely layered media showed that the homogenization reliably estimated elastic parameters for this simple geometry. Additional tests examined anisotropic models with arbitrary spatial heterogeneity where the average size of the heterogeneities ranged from several centimeters to several meters, and the ratio between the dominant wavelength and the average size of the arbitrary heterogeneities ranged from 10 to 100. Comparisons to finite-difference simulations proved that the numerical homogenization was equally accurate for these complex cases.« less

  20. A numerical homogenization method for heterogeneous, anisotropic elastic media based on multiscale theory

    SciTech Connect (OSTI)

    Gao, Kai; Chung, Eric T.; Gibson, Richard L.; Fu, Shubin; Efendiev, Yalchin

    2015-06-05

    The development of reliable methods for upscaling fine scale models of elastic media has long been an important topic for rock physics and applied seismology. Several effective medium theories have been developed to provide elastic parameters for materials such as finely layered media or randomly oriented or aligned fractures. In such cases, the analytic solutions for upscaled properties can be used for accurate prediction of wave propagation. However, such theories cannot be applied directly to homogenize elastic media with more complex, arbitrary spatial heterogeneity. We therefore propose a numerical homogenization algorithm based on multiscale finite element methods for simulating elastic wave propagation in heterogeneous, anisotropic elastic media. Specifically, our method used multiscale basis functions obtained from a local linear elasticity problem with appropriately defined boundary conditions. Homogenized, effective medium parameters were then computed using these basis functions, and the approach applied a numerical discretization that is similar to the rotated staggered-grid finite difference scheme. Comparisons of the results from our method and from conventional, analytical approaches for finely layered media showed that the homogenization reliably estimated elastic parameters for this simple geometry. Additional tests examined anisotropic models with arbitrary spatial heterogeneity where the average size of the heterogeneities ranged from several centimeters to several meters, and the ratio between the dominant wavelength and the average size of the arbitrary heterogeneities ranged from 10 to 100. Comparisons to finite-difference simulations proved that the numerical homogenization was equally accurate for these complex cases.

  1. Topic A Note: Includes STEPS Subtopic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic A Note: Includes STEPS Subtopic 33 Total Projects Developing and Enhancing Workforce Training Programs

  2. Hot topics from the Tevatron

    SciTech Connect (OSTI)

    Glenzinski, D.; /Fermilab

    2008-01-01

    The Tevatron Run-II began in March 2001. To date, both the CDF and D0 experiments have collected 1 fb{sup -1} of data each. The results obtained from this data set were summarized at this conference in 39 parallel session presentations covering a wide range of topics. The author summarizes the most important of those results here and comments on some of the prospects for the future.

  3. 2012 LANSCE Topical User Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 LANSCE Topical User Meeting January 9-10, 2012 The Office of Defense Programs is developing a long-term strategy for the construction of new experimental science facilities supporting NNSA missions. The new facilities will provide the critical science and technology capabilities necessary to execute the 21 st century responsibilities of NNSA in executing its mission and in supporting the broader national security agenda. The call focuses on large facilities with costs exceeding $100M. The NNSA

  4. Catalysis by Design - Theoretical and Experimental Studies of Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysts for Lean NOx Treatment | Department of Energy Design - Theoretical and Experimental Studies of Model Catalysts for Lean NOx Treatment Catalysis by Design - Theoretical and Experimental Studies of Model Catalysts for Lean NOx Treatment Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_narula.pdf (277.05 KB) More Documents & Publications Lean NOx Traps

  5. USD Catalysis Group for Alternative Energy - Final report

    SciTech Connect (OSTI)

    Hoefelmeyer, James

    2014-10-03

    I. Project Summary Catalytic processes are a major technological underpinning of modern society, and are essential to the energy sector in the processing of chemical fuels from natural resources, fine chemicals synthesis, and energy conversion. Advances in catalyst technology are enormously valuable since these lead to reduced chemical waste, reduced energy loss, and reduced costs. New energy technologies, which are critical to future economic growth, are also heavily reliant on catalysts, including fuel cells and photo-electrochemical cells. Currently, the state of South Dakota is underdeveloped in terms of research infrastructure related to catalysis. If South Dakota intends to participate in significant economic growth opportunities that result from advances in catalyst technology, then this area of research needs to be made a high priority for investment. To this end, a focused research effort is proposed in which investigators from The University of South Dakota (USD) and The South Dakota School of Mines and Technology (SDSMT) will contribute to form the South Dakota Catalysis Group (SDCG). The multidisciplinary team of the (SDCG) include: (USD) Dan Engebretson, James Hoefelmeyer, Ranjit Koodali, and Grigoriy Sereda; (SDSMT) Phil Scott Ahrenkiel, Hao Fong, Jan Puszynski, Rajesh Shende, and Jacek Swiatkiewicz. The group is well suited to engage in a collaborative project due to the resources available within the existing programs. Activities within the SDCG will be monitored through an external committee consisting of three distinguished professors in chemistry. The committee will provide expert advice and recommendations to the SDCG. Advisory meetings in which committee members interact with South Dakota investigators will be accompanied by individual oral and poster presentations in a materials and catalysis symposium. The symposium will attract prominent scientists, and will enhance the visibility of research in the state of South Dakota. The SDCG requests

  6. Hydrogen catalysis and scavenging action of Pd-POSS nanoparticles

    SciTech Connect (OSTI)

    Maiti, A; Gee, R H; Maxwell, R; Saab, A

    2007-02-01

    Prompted by the need for a self-supported, chemically stable, and functionally flexible catalytic nanoparticle system, we explore a system involving Pd clusters coated with a monolayer of polyhedral oligomeric silsesquioxane (POSS) cages. With an initial theoretical focus on hydrogen catalysis and sequestration in the Pd-POSS system, we report Density Functional Theory (DFT) results on POSS binding energies to the Pd(110) surface, hydrogen storing ability of POSS, and possible pathways of hydrogen radicals from the catalyst surface to unsaturated bonds away from the surface.

  7. Fuels and energy for the future: The role of catalysis

    SciTech Connect (OSTI)

    Rostrup-Nielsen, J.R.; Nielsen, R.

    2004-07-01

    There are many reasons to decrease the dependency on oil and to increase the use of other energy sources than fossil fuels. The wish for energy security is balanced by a wish for sustainable growth. Catalysis plays an important role in creating new routes and flexibility in the network of energy sources, energy carriers, and energy conversion. The process technologies resemble those applied in the large scale manufacture of commodities. This is illustrated by examples from refinery fuels, synfuels, and hydrogen and the future role of fossil fuels is discussed.

  8. Charge Transfer and Catalysis at the Metal Support Interface

    SciTech Connect (OSTI)

    Baker, Lawrence Robert

    2012-07-31

    Kinetic, electronic, and spectroscopic characterization of model Pt–support systems are used to demonstrate the relationship between charge transfer and catalytic activity and selectivity. The results show that charge flow controls the activity and selectivity of supported metal catalysts. This dissertation builds on extensive existing knowledge of metal–support interactions in heterogeneous catalysis. The results show the prominent role of charge transfer at catalytic interfaces to determine catalytic activity and selectivity. Further, this research demonstrates the possibility of selectively driving catalytic chemistry by controlling charge flow and presents solid-state devices and doped supports as novel methods for obtaining electronic control over catalytic reaction kinetics.

  9. Final technical report, Symposium on New Theoretical Concepts and Directions in Catalysis

    SciTech Connect (OSTI)

    Metiu, Horia

    2014-08-22

    We organized in August 2013 a “Symposium on New Theoretical Concepts and Directions in Catalysis” with the participation of 20 invited distinguished quantum chemists and other researchers who use computations to study catalysis. Symposium website; http://catalysis.cnsi.ucsb.edu/

  10. Surface Catalysis of Water Oxidation by the Blue Ruthenium Dimer

    SciTech Connect (OSTI)

    Jurss, Jonah W.; Concepcion, Javier C.; Norris, Michael R.; Templeton, Joseph L.; Meyer, Thomas J.

    2010-04-08

    Single-electron activation of multielectron catalysis has been shown to be viable in catalytic water oxidation with stepwise proton-coupled electron transfer, leading to high-energy catalytic precursors. For the blue dimer, cis,cis-[(bpy)2(H2O)RuIIIORuIII(H2O)(bpy)2]4+, the first well-defined molecular catalyst for water oxidation, stepwise 4e-/4H+ oxidation occurs to give the reactive precursor [(O)RuVORuV(O)]4+. This key intermediate is kinetically inaccessible at an unmodified metal oxide surface, where the only available redox pathway is electron transfer. We report here a remarkable surface activation of indium-tin oxide (In2O3:Sn) electrodes toward catalytic water oxidation by the blue dimer at electrodes derivatized by surface phosphonate binding of [Ru(4,4'-((HO)2P(O)CH2)2bpy)2(bpy)]2+. Surface binding dramatically improves the rate of surface oxidation of the blue dimer and induces water oxidation catalysis.

  11. WTP Communications Strategy Discussion Topics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Discussion Topics For discussion at the April 7, 2015 PIC meeting Issue Managers: Bob Suyama, Dave Bernhard, Melanie Myers-Magnuson, Dirk Dunning, Liz Mattson, Pam Larsen, Ken Niles Some potential questions and areas that the TWC/PIC need to discuss in order to develop a Communica- tions Strategy for the Waste Treatment Plant. These questions represent the data that the TWC/PIC might need in order to provide a plan that will be of value to the Tri-Party Agencies and the Public and Stakeholders.

  12. Framework Topic Briefing: Direct Feed LAW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    February 13, 2014 Framework Topic Briefing: Direct Feed LAW Next steps: Put Dick's handouts on SharePoint * Continue Framework topic briefing series Page 1 System Plan 7 Next ...

  13. TEC Working Group Topic Groups Routing

    Broader source: Energy.gov [DOE]

    The Routing Topic Group has been established to examine topics of interest and relevance concerning routing of shipments of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) to a...

  14. Energy & Manufacturing Workforce Training Topics List - Version...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Manufacturing Workforce Training Topics List - Version 1.7 (02.11.14) Energy & Manufacturing Workforce Training Topics List - Version 1.7 (02.11.14) View this searchable list of ...

  15. Technical Assistance Topics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Assistance Topics Technical Assistance Topics Topics addressed are those of greatest interest to states, regions, and Tribes, including: Reliability, resiliency, and cyber security of electric power systems Electric resource planning, integrated resource planning, regional transmission planning, and resource acquisition strategies Ratepayer-funded energy efficiency, demand response, and smart grid programs Renewable energy development, including state renewable portfolio standards,

  16. Technical Assistance Topics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Policy Coordination and Implementation » Electricity Policy Technical Assistance Program » Technical Assistance Topics Technical Assistance Topics Topics addressed are those of greatest interest to states, regions, and Tribes, including: Reliability, resiliency, and cyber security of electric power systems Electric resource planning, integrated resource planning, regional transmission planning, and resource acquisition strategies Ratepayer-funded energy efficiency, demand response,

  17. Theoretical approach to heterogeneous catalysis using large finite crystals

    SciTech Connect (OSTI)

    Salem, L.

    1985-12-19

    A theoretical-approach is described for heterogeneous catalysis using large finite crystals and an exactly soluble model. First, reviews of some themes which are well-known to physicists but need a translation into chemical language: wave vectors, the tight-binding model, and energy bands. Next a description of the finite simple cubic crystal and its analytical wave functions and energies in the Hueckel scheme is given. Also the analytical Hueckel wave functions for a finite face-centered cubic (FCC) crystal cut along square, (100)-type faces is described. Then the calculation of the perturbation interaction energy between H/sub 2/ and large finite (simple cubic or FCC) crystals of Ni atoms, having up to 13,824 atoms is described. The interaction energy is shown to be independent of crystal size, whatever the position of attack of the H/sub 2/ molecule. 28 references, 9 figures, 8 tables.

  18. Catalysis Working Group Kick-Off Meeting: May 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kick-Off Meeting: May 2012 Catalysis Working Group Kick-Off Meeting: May 2012 The Catalysis Working Group held a kick-off meeting May 14, 2012, in Arlington, Virginia, in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting. Agenda Catalysis Working Group Kick-off Meeting Agenda Presentations DOE's Fuel Cell Catalyst R&D Activities, Nancy Garland, U.S. Department of Energy Fuel Cells: Just a Dream - or Future Reality, Nenad Markovic,

  19. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder; Sapienza, Richard S.; Slegeir, William A.; O'Hare, Thomas E.

    1990-01-01

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.13 ), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  20. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder; Sapienza, Richard S.; Slegeir, William A.; O'Hare, Thomas E.

    1991-02-12

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.-), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  1. Soliton production with nonlinear homogeneous lines

    SciTech Connect (OSTI)

    Elizondo-Decanini, Juan M.; Coleman, Phillip D.; Moorman, Matthew W.; Petney, Sharon Joy Victor; Dudley, Evan C.; Youngman, Kevin; Penner, Tim Dwight; Fang, Lu; Myers, Katherine M.

    2015-11-24

    Low- and high-voltage Soliton waves were produced and used to demonstrate collision and compression using diode-based nonlinear transmission lines. Experiments demonstrate soliton addition and compression using homogeneous nonlinear lines. We built the nonlinear lines using commercially available diodes. These diodes are chosen after their capacitance versus voltage dependence is used in a model and the line design characteristics are calculated and simulated. Nonlinear ceramic capacitors are then used to demonstrate high-voltage pulse amplification and compression. The line is designed such that a simple capacitor discharge, input signal, develops soliton trains in as few as 12 stages. We also demonstrated output voltages in excess of 40 kV using Y5V-based commercial capacitors. The results show some key features that determine efficient production of trains of solitons in the kilovolt range.

  2. Soliton production with nonlinear homogeneous lines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elizondo-Decanini, Juan M.; Coleman, Phillip D.; Moorman, Matthew W.; Petney, Sharon Joy Victor; Dudley, Evan C.; Youngman, Kevin; Penner, Tim Dwight; Fang, Lu; Myers, Katherine M.

    2015-11-24

    Low- and high-voltage Soliton waves were produced and used to demonstrate collision and compression using diode-based nonlinear transmission lines. Experiments demonstrate soliton addition and compression using homogeneous nonlinear lines. We built the nonlinear lines using commercially available diodes. These diodes are chosen after their capacitance versus voltage dependence is used in a model and the line design characteristics are calculated and simulated. Nonlinear ceramic capacitors are then used to demonstrate high-voltage pulse amplification and compression. The line is designed such that a simple capacitor discharge, input signal, develops soliton trains in as few as 12 stages. We also demonstrated outputmore » voltages in excess of 40 kV using Y5V-based commercial capacitors. The results show some key features that determine efficient production of trains of solitons in the kilovolt range.« less

  3. Decision Point 1 Topical Report

    SciTech Connect (OSTI)

    Yablonsky, Al; Barsoumian, Shant; Legere, David

    2013-05-01

    This Topical Report addresses accomplishments achieved during Phase 2a of the SkyMine® Carbon Mineralization Pilot Project. The primary objectives of this project are to design, construct, and operate a system to capture CO2 from a slipstream of flue gas from a commercial coal-fired cement kiln, convert that CO2 to products having commercial value (i.e., beneficial use), show the economic viability of the CO2 capture and conversion process, and thereby advance the technology to the point of readiness for commercial scale demonstration and proliferation. The overall process is carbon negative, resulting in mineralization of CO2 that would otherwise be released into the atmosphere. The project will also substantiate market opportunities for the technology by sales of chemicals into existing markets, and identify opportunities to improve technology performance and reduce costs at the commercial scale. The project is being conducted in two phases. The primary objectives of Phase 1 were to elaborate proven SkyMine® process chemistry to commercial pilot-scale operation and complete the preliminary design for the pilot plant to be built and operated in Phase 2, complete a NEPA evaluation, and develop a comprehensive carbon life cycle analysis. The objective of the current Phase (2a) is to complete the detailed design of the pilot plant to be built in Phase 2b.

  4. Fundamental Studies in Catalysis Enabled the use of Efficient Lean-Burn Engines for Vehicle Transportation

    Broader source: Energy.gov [DOE]

    Building on a catalysis research program sponsored by EEREs Vehicles Technology Office (VTO) and DOEs Office of Science, researchers at Cummins, Inc. and Pacific Northwest National Laboratory ...

  5. Catalysis by Design: Bridging the Gap Between Theory and Experiments at

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanoscale Level | Department of Energy Between Theory and Experiments at Nanoscale Level Catalysis by Design: Bridging the Gap Between Theory and Experiments at Nanoscale Level Studies on a simple platinum-alumina system constitute a first step toward a "catalyst by design" approach. deer08_narula.pdf (273.18 KB) More Documents & Publications Catalysis by Design: Bridging the Gap between Theory and Experiments Catalyst by Design - Theoretical, Nanostructural, and Experimental

  6. Catalysis Center for Energy Innovation (CCEI) | U.S. DOE Office of Science

    Office of Science (SC) Website

    (SC) Catalysis Center for Energy Innovation (CCEI) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Catalysis Center for Energy Innovation (CCEI) Print Text Size: A A A FeedbackShare Page CCEI Header Director Dionisios Vlachos Lead Institution University of Delaware Year Established 2009 Mission To focus on developing innovative, transformational heterogeneous

  7. Center for Biological Electron Transfer and Catalysis (BETCy) | U.S. DOE

    Office of Science (SC) Website

    Office of Science (SC) Center for Biological Electron Transfer and Catalysis (BETCy) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Center for Biological Electron Transfer and Catalysis (BETCy) Print Text Size: A A A FeedbackShare Page BETCy Header Director John Peters Lead Institution Montana State University Year Established 2014 Mission To investigate the

  8. The Catalysis Center for Energy Innovation is an Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Friday, September 2, 2016 11:00 AM  322 ISE Yong Wang The Gene & Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University Institute for Integrated Catalysis, Pacific Northwest National Laboratory College of Chemistry and Chemical Engineering, Xiamen University Biography: Dr. Wang joined PNNL in 1994 and was promoted to Laboratory Fellow (highest scientific rank in national labs) in 2005. He led the Catalysis and Reaction Engineering Team from 2000 to

  9. Improving Catalysis by Putting the Best Face Forward | U.S. DOE Office of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science (SC) Improving Catalysis by Putting the Best Face Forward Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 04.01.12 Improving Catalysis by

  10. Foam Generation in Homogeneous Porous Media

    SciTech Connect (OSTI)

    Gauglitz, Phillip A.; Friedman, F.; Kam, S. I.; Rossen, W. R.

    2002-10-01

    In steady gas-liquid flow in homogeneous porous media with surfactant present, there is often observed a critical injection velocity or pressure gradient ?grad p min? at which ?weak? or ?coarse? foam is abruptly converted into ?strong foam,? with reduction of one to two orders of magnitude in total mobility: i.e., ?foam generation.? Earlier research on foam generation is extended here with extensive data for a variety of porous media, permeabilities, gases (N2 and C02), surfactants, and temperatures. For bead and sandpacks, ?grad p min? scales like (1/k), where k is permeability, over 2 1/2 orders of magnitude in k; for consolidated media the relation is more complex. For dense C02 foam, ?grad p min? exists but can be less than 1 psi/ft. If pressure drop, rather than flow rates, is fixed, one observes and unstable regime between stable ?strong? and ?coarse? foam regimes; in the unstable regime ?grad p? is nonuniform in space or variable in time.

  11. Homogeneously dispersed, multimetal oxygen-evolving catalysts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Bo; Zheng, Xueli; Voznyy, Oleksandr; Comin, Riccardo; Bajdich, Michal; Garcia-Melchor, Max; Han, Lili; Xu, Jixian; Liu, Min; Zheng, Lirong; et al

    2016-03-24

    Earth-abundant first-row (3d) transition-metal-based catalysts have been developed for the oxygen-evolution reaction (OER); however, they operate at overpotentials significantly above thermodynamic requirements. Density functional theory suggested that non-3d high-valency metals such as tungsten can modulate 3d metal oxides, providing near-optimal adsorption energies for OER intermediates. We developed a room-temperature synthesis to produce gelled oxy-hydroxide materials with an atomically homogeneous metal distribution. These gelled FeCoW oxy-hydroxide exhibits the lowest overpotential (191 mV) reported at 10 mA per square centimeter in alkaline electrolyte. Here, the catalyst shows no evidence of degradation following more than 500 hours of operation. X-ray absorption and computationalmore » studies reveal a synergistic interplay between W, Fe and Co in producing a favorable local coordination environment and electronic structure that enhance the energetics for OER.« less

  12. Tracking topic birth and death in LDA.

    SciTech Connect (OSTI)

    Wilson, Andrew T.; Robinson, David Gerald

    2011-09-01

    Most topic modeling algorithms that address the evolution of documents over time use the same number of topics at all times. This obscures the common occurrence in the data where new subjects arise and old ones diminish or disappear entirely. We propose an algorithm to model the birth and death of topics within an LDA-like framework. The user selects an initial number of topics, after which new topics are created and retired without further supervision. Our approach also accommodates many of the acceleration and parallelization schemes developed in recent years for standard LDA. In recent years, topic modeling algorithms such as latent semantic analysis (LSA)[17], latent Dirichlet allocation (LDA)[10] and their descendants have offered a powerful way to explore and interrogate corpora far too large for any human to grasp without assistance. Using such algorithms we are able to search for similar documents, model and track the volume of topics over time, search for correlated topics or model them with a hierarchy. Most of these algorithms are intended for use with static corpora where the number of documents and the size of the vocabulary are known in advance. Moreover, almost all current topic modeling algorithms fix the number of topics as one of the input parameters and keep it fixed across the entire corpus. While this is appropriate for static corpora, it becomes a serious handicap when analyzing time-varying data sets where topics come and go as a matter of course. This is doubly true for online algorithms that may not have the option of revising earlier results in light of new data. To be sure, these algorithms will account for changing data one way or another, but without the ability to adapt to structural changes such as entirely new topics they may do so in counterintuitive ways.

  13. Physics Topics - MST - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics UW Madison Madison Symmetric Torus Physics Topics MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST People mst logo CPLA Home Directory Publications Links Internal University of Wisconsin Physics Department Research funding includes support from: Department of Energy National Science Foundation The MST physics challenges are large and many, but much of our work is captured in the following four major RFP physics goals

  14. LANSCE | Users | LUG | Topical User Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 LANSCE Topical User Meeting | January 9-10 2012 LANSCE Topical User Workshop LANSCE will host the 2012 Topical User Workshop, January 9-10, 2012. We hope to see you there! Registration | Accommodations | Agenda (some presentations are included on the agenda) LANL foreign nationals may register at anytime. | Poster Dimensions: 32 in x 40 in This workshop will solicit user input for the scientific opportunities offered by the pulse stacker and superconducting accelerator that LANSCE has proposed

  15. NOX REDUCTION FOR LEAN EXHAUST USING PLASMA ASSISTED CATALYSIS

    SciTech Connect (OSTI)

    Bhatt, B.

    2000-08-20

    Currently CARB estimates on road diesel vehicles contribute 50% of the NOX and 78% of the particulates being discharged from mobile sources. Diesel emissions obviously must be reduced if future air quality targets are to be met. A critical technological barrier exists because there are no commercial technologies available, which can reduce NOX from diesel (lean), exhaust containing 5-15% O2 concentration. One promising approach to reducing NOX and particulates from diesel exhaust is to use a combination of plasma with catalyst. Plasma can be generated thermally or non-thermally. Thermal plasma is formed by heating the system to an exceedingly high temperature (>2000 C). High temperature requirements for plasma makes thermal plasma inefficient and requires skillful thermal management and hence is considered impractical for mobile applications. Non-thermal plasma directs electrical energy into the creation of free electrons, which in turn react with gaseous species thus creating plasma. A combination of non-thermal plasma with catalysts can be referred to Plasma Assisted Catalysts or PAC. PAC technology has been demonstrated in stationary sources where non-thermal plasma catalysis is carried out in presence of NH3 as a reductant. In stationary applications NO is oxidized to HNO3 and then into ammonium nitrate where it is condensed and removed. This approach is impractical for mobile application because of the ammonia requirement and the ultimate mechanism by which NOX is removed. However, if a suitable catalyst can be found which can use onboard fuel as reductant then the technology holds a considerable promise. NOX REDUCTION FOR LEAN EXHAUST USING PLASMA ASSISTED CATALYSIS Ralph Slone, B. Bhatt and Victor Puchkarev NOXTECH INC. In addition to the development of an effective catalyst, a non-thermal plasma reactor needs be scaled and demonstrated along with a reliable and cost effective plasma power source and onboard HC source needs to be proven. Under the work

  16. Preface: Special Topic on Interfacial and Confined Water (Journal...

    Office of Scientific and Technical Information (OSTI)

    Preface: Special Topic on Interfacial and Confined Water Citation Details In-Document Search Title: Preface: Special Topic on Interfacial and Confined Water This Special Topic on...

  17. Topic Index to the DOE Administrative Records Disposition Schedules...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative...

  18. Highly Dispersed Pseudo-Homogeneous and Heterogeneous Catalysts Synthesized via Inverse Micelle Solutions for the Liquefaction of Coal

    SciTech Connect (OSTI)

    Hampden-Smith, M.; Kawola, J.S.; Martino, A.; Sault, A.G.; Yamanaka, S.A.

    1999-01-05

    The mission of this project was to use inverse micelle solutions to synthesize nanometer sized metal particles and test the particles as catalysts in the liquefaction of coal and other related reactions. The initial focus of the project was the synthesis of iron based materials in pseudo-homogeneous form. The frost three chapters discuss the synthesis, characterization, and catalyst testing in coal liquefaction and model coal liquefaction reactions of iron based pseudo-homogeneous materials. Later, we became interested in highly dispersed catalysts for coprocessing of coal and plastic waste. Bifunctional catalysts . to hydrogenate the coal and depolymerize the plastic waste are ideal. We began studying, based on our previously devised synthesis strategies, the synthesis of heterogeneous catalysts with a bifunctional nature. In chapter 4, we discuss the fundamental principles in heterogeneous catalysis synthesis with inverse micelle solutions. In chapter 5, we extend the synthesis of chapter 4 to practical systems and use the materials in catalyst testing. Finally in chapter 6, we return to iron and coal liquefaction now studied with the heterogeneous catalysts.

  19. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Western Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Western ...

  20. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Eastern Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Eastern ...

  1. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A, Interconnection-Level Analysis and Planning Interconnection-Wide Transmission Planning Initiative: Topic A, Interconnection-Level Analysis and Planning A description of the ...

  2. Interconnection-Wide Transmission Planning Initiative: Topic...

    Energy Savers [EERE]

    the Texas Interconnection Interconnection-Wide Transmission Planning Initiative: Topic B, State Agency Input Regarding Electric Resource and Transmission Planning in the Texas ...

  3. Application of solid ash based catalysts in heterogeneous catalysis

    SciTech Connect (OSTI)

    Shaobin Wang

    2008-10-01

    Solid wastes, fly ash, and bottom ash are generated from coal and biomass combustion. Fly ash is mainly composed of various metal oxides and possesses higher thermal stability. Utilization of fly ash for other industrial applications provides a cost-effective and environmentally friendly way of recycling this solid waste, significantly reducing its environmental effects. On the one hand, due to the higher stability of its major component, aluminosilicates, fly ash could be employed as catalyst support by impregnation of other active components for various reactions. On the other hand, other chemical compounds in fly ash such as Fe{sub 2}O{sub 3} could also provide an active component making fly ash a catalyst for some reactions. In this paper, physicochemical properties of fly ash and its applications for heterogeneous catalysis as a catalyst support or catalyst in a variety of catalytic reactions were reviewed. Fly-ash-supported catalysts have shown good catalytic activities for H{sub 2} production, deSOx, deNOx, hydrocarbon oxidation, and hydrocracking, which are comparable to commercially used catalysts. As a catalyst itself, fly ash can also be effective for gas-phase oxidation of volatile organic compounds, aqueous-phase oxidation of organics, solid plastic pyrolysis, and solvent-free organic synthesis. 107 refs., 4 figs., 2 tabs.

  4. TEC Working Group Topic Groups Rail Conference Call Summaries...

    Office of Environmental Management (EM)

    Summaries Rail Topic Group TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group Rail Topic Group PDF icon May 17, 2007 PDF icon January 16, 2007 PDF icon...

  5. Webtrends Archives by Fiscal Year - Topic Landing Pages | Department...

    Broader source: Energy.gov (indexed) [DOE]

    topic landing pages by fiscal year. Topic Landing Pages FY10 (2.04 MB) Topic Landing Pages FY11 (2.02 MB) Topic Landing Pages FY12-FY13 (366.66 KB) More Documents & Publications ...

  6. Computationally Optimized Homogenization Heat Treatment of Metal Alloys -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Industrial Technologies Industrial Technologies Advanced Materials Advanced Materials Find More Like This Return to Search Computationally Optimized Homogenization Heat Treatment of Metal Alloys National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication Computationally Optimized Homogenization Heat Treatment of Metal Alloys (291 KB) Technology Marketing Summary ? A computational approach has been developed to

  7. State of Supported Nickel Nanoparticles during Catalysis in Aqueous Media

    SciTech Connect (OSTI)

    Chase, Zizwe; Kasakov, Stanislav; Shi, Hui; Vjunov, Aleksei; Fulton, John L.; Camaioni, Donald M.; Balasubramanian, Mahalingam; Zhao, Chen; Wang, Yong; Lercher, Johannes A.

    2015-11-09

    The state of Ni supported on HZSM-5 zeolite, silica, and sulfonated carbon was determined during aqueous phase catalysis of phenol hydrodeoxygenation using in situ extended X-ray absorption fine structure spectroscopy (EXAFS). On sulfonated carbon and HZSM-5 supports, the NiO and Ni(OH)2 were readily reduced to Ni(0) under reaction conditions (~35 bar H2 in aqueous phenol solutions containing up to 0.5 wt. % phosphoric acid at 473 K). On the silica support, less than 70% of the Ni was converted to Ni(0) under reaction conditions, which is attributed to the formation of Ni phyllosilicates. Over a broad range of reaction conditions there was no leaching of Ni from the supports. In contrast, rapid leaching of the Ni(II) from HZSM-5 was observed, when 15 wt. % aqueous acetic acid was substituted for the aqueous phenol solution. Once the metallic state of Ni was established there was no leaching in 15 wt. % acetic acid at 473 K and 35 bar H2. This work was supported by the U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences & Biosciences. The STEM was supported under the Laboratory Directed Research and Development Program: Chemical Imaging Initiative at Pacific Northwest National Laboratory (PNNL), a multi-program national laboratory operated for DOE by Battelle under Contract DE-AC05-76RL01830. STEM was performed at EMSL, a DOE Office of Science user facility sponsored by the Office of Biological and Environmental Research and located at PNNL.

  8. Shape-selective catalysis in dimethyl ether conversion

    SciTech Connect (OSTI)

    Sardesai, A.; Lee, S.

    1999-07-01

    Coal-derived syngas can be effectively converted to dimethyl ether (DME) in a single-stage, liquid-phase process. This Liquid Phase Dimethyl Ether (LPDME) process utilizes a dual catalytic system, which comprises of a physical blend between the methanol synthesis and the methanol dehydration catalyst slurried in an inert mineral oil. Such produced DME has vast potential as a building block chemical in the petrochemical industry to produce value-added specialty chemicals. The current research efforts are made to exploit the utilization of shape-selective catalysis using zeolites to produce targeted petrochemicals, including lower olefinic hydrocarbons. The catalysts probed in this investigation include zeolites of different physical, morphological, and chemical configurations. The effect of acidity of ZSM-5 type zeolites as well as the effect of the different channel size and orientation of the zeolites on product selectivity and catalyst deactivation are examined. Results obtained from experimentation of this study show that ZSM-5 type zeolite with low acidity (high SiO{sub 2}/Al{sub 2}O{sub 3} ratio, in this case 150) exhibits the highest selectivity towards lower (C{sub 2}-C{sub 4}) olefins in general. Controlled selectivity toward targeted olefinic species can be accomplished via devising catalytic reaction systems in such a way that the structural property of the catalyst and reactive interaction between molecules in the pores are geared toward formation of targeted molecular species which also at the same time prevent the formation of less desirable products. The internal morphology of the catalyst also has a pronounced effect on the deactivation phenomenon, where it is observed that zeolites possessing high acidity and a unidimensional channel structure are prone towards catalyst deactivation by coking and pore blockage.

  9. Structural Insights into the Mechanism of PEPCK Catalysis

    SciTech Connect (OSTI)

    Holyoak,T.; Sullivan, S.; Nowak, T.

    2006-01-01

    Phosphoenolpyruvate carboxykinase catalyzes the reversible decarboxylation of oxaloacetic acid with the concomitant transfer of the {gamma}-phosphate of GTP to form PEP and GDP as the first committed step of gluconeogenesis and glyceroneogenesis. The three structures of the mitochondrial isoform of PEPCK reported are complexed with Mn{sup 2+}, Mn{sup 2+}-PEP, or Mn{sup 2+}-malonate-Mn{sup 2+}GDP and provide the first observations of the structure of the mitochondrial isoform and insight into the mechanism of catalysis mediated by this enzyme. The structures show the involvement of the hyper-reactive cysteine (C307) in the coordination of the active site Mn{sup 2+}. Upon formation of the PEPCK-Mn{sup 2+}-PEP or PEPCK-Mn{sup 2+}-malonate-Mn{sup 2+}GDP complexes, C307 coordination is lost as the P-loop in which it resides adopts a different conformation. The structures suggest that stabilization of the cysteine-coordinated metal geometry holds the enzyme as a catalytically incompetent metal complex and may represent a previously unappreciated mechanism of regulation. A third conformation of the mobile P-loop in the PEPCK-Mn{sup 2+}-malonate-Mn{sup 2+}GDP complex demonstrates the participation of a previously unrecognized, conserved serine residue (S305) in mediating phosphoryl transfer. The ordering of the mobile active site lid in the PEPCK-Mn{sup 2+}-malonate-Mn{sup 2+}GDP complex yields the first observation of this structural feature and provides additional insight into the mechanism of phosphoryl transfer.

  10. Jonathan Link, Columbia KEK Topical Conference

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -22, 2001 Jonathan Link, Columbia KEK Topical Conference Short Baseline Neutrino Oscillations and MiniBooNE Jonathan Link Columbia University The 5 th KEK Topical Conference - Frontiers in Flavor Physics November 20-22, 2001 November 20-22, 2001 Jonathan Link, Columbia KEK Topical Conference Outline 1. Background on Short Baseline Neutrino Oscillations * A little neutrino physics * The LSND oscillation result 2. About MiniBooNE 3. Status of MiniBooNE. Some of you may have noticed that I'll be

  11. At tank Low Activity Feed Homogeneity Analysis Verification

    SciTech Connect (OSTI)

    DOUGLAS, J.G.

    2000-09-28

    This report evaluates the merit of selecting sodium, aluminum, and cesium-137 as analytes to indicate homogeneity of soluble species in low-activity waste (LAW) feed and recommends possible analytes and physical properties that could serve as rapid screening indicators for LAW feed homogeneity. The three analytes are adequate as screening indicators of soluble species homogeneity for tank waste when a mixing pump is used to thoroughly mix the waste in the waste feed staging tank and when all dissolved species are present at concentrations well below their solubility limits. If either of these conditions is violated, then the three indicators may not be sufficiently chemically representative of other waste constituents to reliably indicate homogeneity in the feed supernatant. Additional homogeneity indicators that should be considered are anions such as fluoride, sulfate, and phosphate, total organic carbon/total inorganic carbon, and total alpha to estimate the transuranic species. Physical property measurements such as gamma profiling, conductivity, specific gravity, and total suspended solids are recommended as possible at-tank methods for indicating homogeneity. Indicators of LAW feed homogeneity are needed to reduce the U.S. Department of Energy, Office of River Protection (ORP) Program's contractual risk by assuring that the waste feed is within the contractual composition and can be supplied to the waste treatment plant within the schedule requirements.

  12. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    TEC Tribal Topic Group Conference Call January 18, 2006 Group Chair: Jay Jones (DOE/OCRWM) Participating TEC Tribal Topic Group Members: Rob Burnside (CTUIR), Earl Easton (U.S. NRC), Kristen Ellis (DOE/CI), Ed Gonzales (ELG), Angela Hill (DOE/OCRWM), Marsha Keister (INL), Dan King (Oneida Nation), Corinne Macaluso (DOE/OCRWM), Titto Moses (CTUIR), Stanley Paytiamo (Pueblo of Acoma), Willie Preacher (Shoshone-Bannock Tribes), Cathy Reynolds (DOE/GC), Larry Stern (CVSA), Kevin Tafoya (Santa Clara

  13. 2010 CATALYSIS GORDON RESEARCH CONFERENCE, JUNE 27 - JULY 2, 2010, NEW LONDON, NEW HAMPSHIRE

    SciTech Connect (OSTI)

    Abhaya Datye

    2010-07-02

    Catalysis is a key technology for improving the quality of life while simultaneously reducing the adverse impact of human activities on the environment. The discovery of new catalytic processes and the improvement of existing ones are also critically important for securing the nation's energy supply. The GRC on Catalysis is considered one the most prestigious conference for catalysis research, bringing together leading researchers from both academia, industry and national labs to discuss the latest, most exciting research in catalysis and the future directions for the field. The 2010 GRC on Catalysis will follow time-honored traditions and feature invited talks from the world's leading experts in the fundamentals and applications of catalytic science and technology. We plan to have increased participation from industry. The extended discussions in the company of outstanding thinkers will stimulate and foster new science. The conference will include talks in the following areas: Alternative feedstocks for chemicals and fuels, Imaging and spectroscopy, Design of novel catalysts, Catalyst preparation fundamentals, Molecular insights through theory, Surface Science, Catalyst stability and dynamics. In 2010, the Catalysis conference will move to a larger conference room with a new poster session area that will allow 40 posters per session. The dorm rooms provide single and double accommodations, free WiFi and the registration fee includes all meals and the famous lobster dinner on Thursday night. Afternoons are open to enjoy the New England ambiance with opportunities for hiking, sailing, golf and tennis to create an outstanding conference that will help you network with colleagues, and make long lasting connections.

  14. Hydrogen storage materials and method of making by dry homogenation

    DOE Patents [OSTI]

    Jensen, Craig M.; Zidan, Ragaiy A.

    2002-01-01

    Dry homogenized metal hydrides, in particular aluminum hydride compounds, as a material for reversible hydrogen storage is provided. The reversible hydrogen storage material comprises a dry homogenized material having transition metal catalytic sites on a metal aluminum hydride compound, or mixtures of metal aluminum hydride compounds. A method of making such reversible hydrogen storage materials by dry doping is also provided and comprises the steps of dry homogenizing metal hydrides by mechanical mixing, such as be crushing or ball milling a powder, of a metal aluminum hydride with a transition metal catalyst. In another aspect of the invention, a method of powering a vehicle apparatus with the reversible hydrogen storage material is provided.

  15. Geek-Up[3.11.2011]: Energy Efficiency, Catalysis and Open Source Tools |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 11.2011]: Energy Efficiency, Catalysis and Open Source Tools Geek-Up[3.11.2011]: Energy Efficiency, Catalysis and Open Source Tools March 11, 2011 - 4:37pm Addthis L. Keith Woo | Photo courtesy of Ames National Laboratory L. Keith Woo | Photo courtesy of Ames National Laboratory Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs Ames Laboratory researcher and Iowa State University professor L. Keith Woo is on the search for catalysts that lead

  16. Growth mechanism of graphene on platinum: Surface catalysis and carbon segregation

    SciTech Connect (OSTI)

    Sun, Jie Lindvall, Niclas; Yurgens, August; Nam, Youngwoo; Cole, Matthew T.; Teo, Kenneth B. K.; Woo Park, Yung

    2014-04-14

    A model of the graphene growth mechanism of chemical vapor deposition on platinum is proposed and verified by experiments. Surface catalysis and carbon segregation occur, respectively, at high and low temperatures in the process, representing the so-called balance and segregation regimes. Catalysis leads to self-limiting formation of large area monolayer graphene, whereas segregation results in multilayers, which evidently grow from below. By controlling kinetic factors, dominantly monolayer graphene whose high quality has been confirmed by quantum Hall measurement can be deposited on platinum with hydrogen-rich environment, quench cooling, tiny but continuous methane flow and about 1000?C growth temperature.

  17. Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype confirms Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype

  18. Tritium Technology Program TTP-1-3089 TPBAR Homogenized Composition

    SciTech Connect (OSTI)

    Love, Edward F.

    2014-10-12

    Homogenized TPBAR number densities contained herein have been derived for unclassified core physics calculations. The use of this information may not provide accurate, conservative or representative results and must be evaluated for applicability to the specific problem.

  19. Surface functionalization of metal-organic polyhedron for homogeneous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst...

  20. TEC Working Group Topic Groups Rail Key Documents Intermodal Subgroup |

    Office of Environmental Management (EM)

    Department of Energy Intermodal Subgroup TEC Working Group Topic Groups Rail Key Documents Intermodal Subgroup Intermodal Subgroup Draft Work Plan (206.83 KB) More Documents & Publications TEC Working Group Topic Groups Rail Key Documents Radiation Monitoring Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Intermodal Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group

  1. TEC Working Group Topic Groups Routing Meeting Summaries | Department of

    Office of Environmental Management (EM)

    Energy Meeting Summaries TEC Working Group Topic Groups Routing Meeting Summaries MEETING SUMMARIES Atlanta TEC Meeting, Routing Topic Group Summary (101.72 KB) More Documents & Publications TEC Meeting Summaries - January - February 2007 TEC Working Group Topic Groups Rail Meeting Summaries TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group

  2. Enzyme-Like Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation

    SciTech Connect (OSTI)

    Hastings, Courtney; Pluth, Michael; Bergman, Robert; Raymond, Kenneth

    2010-03-29

    A primary goal in the design and synthesis of molecular hosts has been the selective recognition and binding of a variety of guests using non-covalent interactions. Supramolecular catalysis, which is the application of such hosts towards catalysis, has much in common with many enzymatic reactions, chiefly the use of both spatially appropriate binding pockets and precisely oriented functional groups to recognize and activate specific substrate molecules. Although there are now many examples which demonstrate how selective encapsulation in a host cavity can enhance the reactivity of a bound guest, all have failed to reach the degree of increased reactivity typical of enzymes. We now report the catalysis of the Nazarov cyclization by a self-assembled coordination cage, a carbon-carbon bond-forming reaction which proceeds under mild, aqueous conditions. The acceleration in this system is over a million-fold, and represents the first example of supramolecular catalysis that achieves the level of rate enhancement comparable to that observed in several enzymes. We explain the unprecedented degree of rate increase as due to the combination of (a) preorganization of the encapsulated substrate molecule, (b) stabilization of the transition state of the cyclization by constrictive binding, and (c) increase in the basicity of the complexed alcohol functionality.

  3. Chemistry - Oxygen Vacancies and Catalysis on Ceria Surfaces

    SciTech Connect (OSTI)

    Campbell, Charles T.; Peden, Charles HF.

    2005-07-29

    Chemistry occurring at the surface of metal oxides is critical in a variety of industrial applications including catalysis and photocatalysis, optical display technology, solar energy devices and corrosion prevention. Defects have long been recognized to be the most reactive sites on the surfaces of many oxide materials. The most common types of defects present on the surfaces of metal oxides are oxygen vacancies and step edges. The nature of surface oxygen vacancies, and their number, distribution and diffusion across the surface of oxides, are thus issues of major scientific importance. One of the most interesting oxides in this respect is CeO2, since oxygen vacancies play the key role in giving this material it's industrially important ''oxygen-storage capacity''. This capacity makes modern automotive exhaust treatment catalysts containing CeO2 much more effective than their predecessors without CeO2. Ceria is also well known as a support which enhances the performance of transition metal catalysts, relative to other oxide supports, in a variety of other reactions including water-gas shift, steam reforming of oxygenates and PROX 1-7, all of which hold promise for enabling a hydrogen economy 1. Related to ceria's facile redox capacity (ability to rapidly form and eliminate oxygen vacancy defects) is the poorly understood observation that some less reducible oxides, such as zirconia (ZrO2), are used as additives that actually enhance this ''oxygen storage'' property of CeO2. In this issue, Esch and coworkers in Trieste, Italy report an exciting study that for the first time clearly elucidates the structure, distribution and formation of oxygen vacancies on a cerium oxide surface 8. They have elegantly combined beautiful, atomic-resolution imaging using scanning-tunneling microscopy (STM) on a ceria surface with state-of-the-art quantum mechanical calculations using Density Functional Theory (DFT) to raise our understanding of CeO2 surfaces to a much higher level

  4. Solvation and Acid Strength Effects on Catalysis by Faujasite Zeolites

    SciTech Connect (OSTI)

    Gounder, Rajamani P.; Jones, Andrew J.; Carr, Robert T.; Iglesia, Enrique

    2012-02-01

    Kinetic, spectroscopic, and chemical titration data indicate that differences in monomolecular isobutane cracking and dehydrogenation and methanol dehydration turnover rates (per H+) among FAU zeolites treated thermally with steam (H-USY) and then chemically with ammonium hexafluorosilicate (CDHUSY) predominantly reflect differences in the size and solvating properties of their supercage voids rather than differences in acid strength. The number of protons on a given sample was measured consistently by titrations with Na+, with CH3 groups via reactions of dimethyl ether, and with 2,6-di-tert-butylpyridine during methanol dehydration catalysis; these titration values were also supported by commensurate changes in acidic OH infrared band areas upon exposure to titrant molecules. The number of protons, taken as the average of the three titration methods, was significantly smaller than the number of framework Al atoms (Alf) obtained from X-ray diffraction and 27Al magic angle spinning nuclear magnetic resonance spectroscopy on H-USY (0.35 H+/Alf) and CD-HUSY (0.69 H+/Alf). These data demonstrate that the ubiquitous use of Alf sites as structural proxies for active H+ sites in zeolites can be imprecise, apparently because distorted Al structures that are not associated with acidic protons are sometimes detected as Alf sites. Monomolecular isobutane cracking and dehydrogenation rate constants, normalized non-rigorously by the number of Alf species, decreased with increasing Na+ content on both H-USY and CD-HUSY samples and became undetectable at sub-stoichiometric exchange levels (0.32 and 0.72 Na+/Alf ratios, respectively), an unexpected finding attributed incorrectly in previous studies to the presence of minority ‘‘super-acidic’’ sites. These rate constants, when normalized rigorously by the number of residual H+ sites were independent of Na+ content on both H-USY and CD-HUSY samples, reflecting the stoichiometric replacement of protons that are uniform in

  5. OSTIblog Articles in the history of science Topic | OSTI, US...

    Office of Scientific and Technical Information (OSTI)

    history of science Topic World Wide Information: The Other Side of the Coin by Kristin ... Of course, the world's information covers numerous topics other than science and ...

  6. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment MIssouri Botanical Garden | Earthways Center - October 6th, 3:15 -...

  7. Public Perception of 13 Different Energy Topics analyzed in new...

    Open Energy Info (EERE)

    and unfavorability energy topics such as transportation, renewable technology, nuclear, clean coal, and smart grid topics. Some of the highlights of the study are as...

  8. TEC Working Group Topic Groups Security | Department of Energy

    Office of Environmental Management (EM)

    TEC Working Group Topic Groups Security The Security Topic group is comprised of regulators, law enforcement officials, labor and industry representatives and other subject matter ...

  9. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Tyson Living Learning Center tour November 18, 2014 - 4:00pm Tyson...

  10. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Donald Danforth Plant Science Center April 9, 2015 - 3:15pm Donald...

  11. Hot Topics Workshops | June 2016 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Workshops | June 2016 Hot Topics Workshops | June 2016 A look at our workshops this past June on various topics including nuclear energy, biofuels, and renewable

  12. TEC Working Group Topic Groups Rail Meeting Summaries | Department...

    Office of Environmental Management (EM)

    TEC Working Group Topic Groups Rail Meeting Summaries MEETING SUMMARIES PDF icon Kansas City TEC Meeting, Rail Topic Group Summary - July 25, 2007 PDF icon Atlanta TEC...

  13. OSTIblog Articles in the greenhouse gases Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    greenhouse gases Topic Carbon Sequestration - Helping to Save Our Beautiful World by Kathy ... Related Topics: carbon dioxide, carbon sequestration, climate change, greenhouse gases

  14. Hot topics in flavor physics at CDF

    SciTech Connect (OSTI)

    Jun, Soon Yung; /Carnegie Mellon U.

    2005-01-01

    Hot topics in flavor physics at CDF are reviewed. Selected results of top, beauty, charm physics and exotic states in about 200 pb{sup -1} data collected by the CDF II detector in p{bar p} collisions at {radical}s = 1.96 TeV at the Fermilab Tevatron are presented.

  15. Quark-gluon plasma (Selected Topics)

    SciTech Connect (OSTI)

    Zakharov, V. I.

    2012-09-15

    Introductory lectures to the theory of (strongly interacting) quark-gluon plasma given at the Winter School of Physics of ITEP (Moscow, February 2010). We emphasize theoretical issues highlighted by the discovery of the low viscosity of the plasma. The topics include relativistic hydrodynamics, manifestations of chiral anomaly in hydrodynamics, superfluidity, relativistic superfluid hydrodynamics, effective stringy scalars, holographic models of Yang-Mills theories.

  16. More About "Topic A" and "Topic B" Awards | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More About "Topic A" and "Topic B" Awards More About "Topic A" and "Topic B" Awards The awards pursuant to the Department of Energy's Interconnection-wide Transmission Planning Initiative cover two broad topics. "Topic A" covers Interconnection-Level Analysis and Planning. "Topic B" covers Cooperation Among States on Electric Resource Planning and Priorities, where the states will develop input to the Topic A analyses and perform other

  17. A Computationally Based Approach to Homogenizing Advanced Alloys

    SciTech Connect (OSTI)

    Jablonski, P D; Cowen, C J

    2011-02-27

    We have developed a computationally based approach to optimizing the homogenization heat treatment of complex alloys. The Scheil module within the Thermo-Calc software is used to predict the as-cast segregation present within alloys, and DICTRA (Diffusion Controlled TRAnsformations) is used to model the homogenization kinetics as a function of time, temperature and microstructural scale. We will discuss this approach as it is applied to both Ni based superalloys as well as the more complex (computationally) case of alloys that solidify with more than one matrix phase as a result of segregation. Such is the case typically observed in martensitic steels. With these alloys it is doubly important to homogenize them correctly, especially at the laboratory scale, since they are austenitic at high temperature and thus constituent elements will diffuse slowly. The computationally designed heat treatment and the subsequent verification real castings are presented.

  18. Cryogenic homogenization and sampling of heterogeneous multi-phase feedstock

    DOE Patents [OSTI]

    Doyle, Glenn Michael (Lakewood, CO); Ideker, Virgene Linda (Arvada, CO); Siegwarth, James David (Boulder, CO)

    2002-01-01

    An apparatus and process for producing a homogeneous analytical sample from a heterogenous feedstock by: providing the mixed feedstock, reducing the temperature of the feedstock to a temperature below a critical temperature, reducing the size of the feedstock components, blending the reduced size feedstock to form a homogeneous mixture; and obtaining a representative sample of the homogeneous mixture. The size reduction and blending steps are performed at temperatures below the critical temperature in order to retain organic compounds in the form of solvents, oils, or liquids that may be adsorbed onto or absorbed into the solid components of the mixture, while also improving the efficiency of the size reduction. Preferably, the critical temperature is less than 77 K (-196.degree. C.). Further, with the process of this invention the representative sample may be maintained below the critical temperature until being analyzed.

  19. Variable valve timing in a homogenous charge compression ignition engine

    DOE Patents [OSTI]

    Lawrence, Keith E.; Faletti, James J.; Funke, Steven J.; Maloney, Ronald P.

    2004-08-03

    The present invention relates generally to the field of homogenous charge compression ignition engines, in which fuel is injected when the cylinder piston is relatively close to the bottom dead center position for its compression stroke. The fuel mixes with air in the cylinder during the compression stroke to create a relatively lean homogeneous mixture that preferably ignites when the piston is relatively close to the top dead center position. However, if the ignition event occurs either earlier or later than desired, lowered performance, engine misfire, or even engine damage, can result. The present invention utilizes internal exhaust gas recirculation and/or compression ratio control to control the timing of ignition events and combustion duration in homogeneous charge compression ignition engines. Thus, at least one electro-hydraulic assist actuator is provided that is capable of mechanically engaging at least one cam actuated intake and/or exhaust valve.

  20. TEC Working Group Topic Groups Archives | Department of Energy

    Office of Environmental Management (EM)

    Archives TEC Working Group Topic Groups Archives The following Topic Groups are no longer active; however, related documents and notes for these archived Topic Groups are available through the following links: Communications Consolidated Grant Topic Group Training - Medical Training Protocols Route Identification Process Mechanics of Funding and Technical Assistance

  1. Innovative Topics for Advanced Biofuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovative Topics for Advanced Biofuels Innovative Topics for Advanced Biofuels PNNL report-out presentation at the CTAB webinar on innovative topics for advanced biofuels. ctab_webinar_innovative_topics.pdf (1.55 MB) More Documents & Publications Cross-cutting Technologies for Advanced Biofuels Conversion Technologies for Advanced Biofuels - Carbohydrates Production Conversion Technologies for Advanced Biofuels - Bio-Oil Upgrading

  2. Topic A Awardee: Eastern Interconnection Planning Collaborative |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Eastern Interconnection Planning Collaborative Topic A Awardee: Eastern Interconnection Planning Collaborative Eastern Interconnection Planning Collaborative The Eastern Interconnection Planning Collaborative (EIPC) was initiated by a coalition of regional Planning Authorities. These Planning Authorities are entities listed on the NERC compliance registry as Planning Authorities and represent the entire Eastern Interconnection. The EIPC was founded to be a broad-based,

  3. Renewable Energy Project Development: Advanced Concept Topics

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concept Topics An Introduction to Risk, Tribal Roles, and Support Policies in the Renewable Energy Project Development Process Course Outline What we will cover...  About the DOE Office of Indian Energy Education Initiative  Concepts and Policies for Understanding Renewable Energy Projects on Tribal Lands - Risk and Uncertainty - Tribal Project Roles - Policies and Incentives  Additional Information and Resources 2 Introduction The U.S. Department of Energy (DOE) Office of Indian Energy

  4. Renewable Energy Project Development: Advanced Process Topics

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process Topics Understanding Energy Markets, Project Scale Decision Factors, Procurement Options, and the Role of the Project Team Course Outline What we will cover...  About the DOE Office of Indian Energy Education Initiative  Processes for Developing Renewable Energy Projects on Tribal Lands - Understanding the Energy Market and Project Scale - Project Scale and Ownership Options - Procurement Process - Project Team  Additional Information and Resources 2 Introduction The U.S.

  5. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    Meeting September 22, 2005 - Pueblo, CO Group Chair: Jay Jones (DOE/OCRWM) Tribal Topic Group Members Present: Richard Arnold (Southern Paiute/CGTO), Vicki Best (Bechtel SAIC-YMP), Kevin Blackwell (DOT/FRA), Sandra Covi (UPRR), Barbara Durham (Timbisha Shoshone Tribe), Greg Fasano (Bechtel SAIC-YMP), Elizabeth Helvey (BSC), Angela Hill (DOE/OCRWM), Judith Holm (DOE/OCRWM), Marsha Keister (INL), Dan King (Oneida Nation), Gary Lanthrum (DOE/OCRWM), Corinne Macaluso (DOE/OCRWM), Calvin Meyers

  6. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    Conference Call December 6, 2005 Group Chair: Jay Jones (DOE/OCRWM) Participating TEC Tribal Topic Group Members: Kevin Clarke (DOE/RL), Kristen Ellis (DOE/CI), Lisa Gover (NTEC), Dan King (Oneida Nation), Corinne Macaluso (DOE/OCRWM), Ellen Ott (DOE/GC), Ted Repasky (CTUIR), Cathy Reynolds (DOE/GC), Lisa Sattler (CSG-MW) Herman Shorty (Navajo Nation), Linda Sikkema (NCSL), Christopher Wells (SSEB) DOE support contractors also participated in this call. Action Items: Responsible Party Action to

  7. TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic

    Office of Environmental Management (EM)

    Group | Department of Energy Summaries Rail Topic Group TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group Rail Topic Group May 17, 2007 (10.98 KB) January 16, 2007 (14.41 KB) August 31, 2006 (16.39 KB) July 27, 2006 (19.28 KB) June 8, 2006 (15.79 KB) April 20, 2006 (19.91 KB) March 9, 2006 (19.65 KB) January 26, 2006 (20.86 KB) November 9, 2005 (24.38 KB) September 15, 2005 (32.13 KB) April 28, 2005 (19.16 KB) March 24, 2005 (28.33 KB) February 24, 2005 (32.77

  8. TEC Working Group Topic Groups | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic Groups TEC Working Group Topic Groups TEC Topic Groups were formed in 1991 following an evaluation of the TEC program. Interested members, DOE and other federal agency staff meet to examine specific issues related to radioactive materials transportation. TEC Topic Groups enable a small number of participants to focus intensively on key issues at a level of detail that is unattainable during the TEC semiannual meetings due to time and group size constraints. Topic Groups meet individually

  9. Kokes Awards for the 22nd North American Catalysis Society Meeting, June 5-10, 2011

    SciTech Connect (OSTI)

    Fabio H. Ribeiro

    2011-06-05

    The biennial North American Catalysis Society (NACS) Meetings are the premiere conferences in the area of catalysis, surface science, and reaction engineering. The 22nd meeting will be held the week of June 5-10, 2011 in Detroit, Michigan. The objective of the Meetings is to bring together leading researchers for intensive scientific exchange and interactions. Financial support that offsets some of the associated costs (specifically, registration fee, airline tickets, and hotel accommodations) would encourage graduate students, and for the first time undergraduate students, to attend and participate meaningfully in this conference. The funds sought in this proposal will help support the Richard J. Kokes Travel Award program. Graduate students eligible for these merit-based Awards are those who study at a North American university and who will present at the Meeting. We have currently 209 applications and we expect to be able to fund about half of them. The NACS has traditionally sought to encourage graduate student, and this year for the first time undergraduate studies, participation at the National Meetings and providing financial support is the most effective means to do so. Their attendance would contribute significantly to their scientific training and communication and presentation skills. They would be exposed to the leading researchers from the US and abroad; they would meet their peers from other universities; they would learn about cutting-edge results that could benefit their research projects; and they may become interested in becoming active participants in the catalysis community. These young investigators represent the next generation of scientists and engineers, and their proper training will lead to future scientific breakthroughs and technological innovations that benefit the US economy. Advances in catalysis can come in the form of more energy-efficient and environmentally-friendly chemical processes, improved fuel cell performance, efficient

  10. Kokes Awards for the 23rd North American Catalysis Society Meeting

    SciTech Connect (OSTI)

    Jacobs, Gary

    2014-01-31

    The Tri-State Catalysis Society awarded 107 Kokes Travel Awards. The program was very successful and to date this was the most Kokes Travel Awards ever awarded at a North American Catalysis Society Meeting. It provided students who merited an award the opportunity to attend the meeting, present a paper in the form of either an oral presentation or a poster presentation, and to serve the North American Catalysis Society by participating in the organization of the meeting. Students worked very hard during the week of the meeting to make it a success. Financial support for the Kokes awards was provided by DOE, NSF, NACS, as well as the Tri-State Catalysis Society, the latter through fund raising activities, and other donations. AT the meeting, each student received over $1050 in kind to offset the costs of registration fees ($260), hotel accommodations ($295.7), transportation ($400 travel allowance), as well as T-shirts ($20), and banquet tickets ($95 provided by donations from society members). In addition, for the first time, students received certificates that were signed by the President of NACS, Professor Enrique Iglesia, and by the Kokes Awards Chair, Gary Jacobs (see last page). A list of meeting co-chairs (i.e., Uschi M. Graham, Umit S. Ozkan, and Madan Bhassin) and the honorary chair (Burtron H. Davis) was also included on the certificate, along with the name of the recipient. The awardees were chosen on a merit-based guideline which also included the requirements of having a presentation accepted at the meeting and being a student at a North American University. The Richard J. Kokes Student Travel Award Committee (Gary Jacobs, Rodney Andrews, and Peter Smirniotis) with help from the Organizing Committee were able to secure money from four sources as detailed in Table 1. As detailed by our Treasurer, Dr. Helge Toufar of Clariant, the total amount spent was $105,000.

  11. NMR Computational Studies of Solid Acidity/Fundamental Studies of Catalysis by Solid Acids

    SciTech Connect (OSTI)

    James F. Haw

    2008-06-28

    This project focused on catalysis by zeolites and the synergy of spectroscopic characterization and theoretical modeling. In collaboration with the Waroquier group in Belgium we used state-of-the-art quantum chemical simulations on a supramolecular model of both the HZSM-5 zeolite and the co-catalytic hydrocarbon pool species and calculated a full catalytic cycle (including all rate constants) for methanol-to-olefin (MTO) catalysis involving a hydrocarbon pool species. This work not only represents the most robust computational analysis of a successful MTO route to date, but it also succeeds in tying together the many experimental clues. That work was featured on the cover of Angewandte Chemie. More recently we elucidated several unsuspected roles for formaldehyde in methanol to olefin catalysis. Formaldehyde proves to be a key species responsible for both the growth of the catalytically active hydrocarbon pool and its inevitable aging into deactivated polycyclic aromatic species. The apparent inevitability of formaldehyde formation at high temperatures, in particular in contact with active metal or metal oxide surfaces, may put some fundamental limitations on the economic potential of conversion of methanol to olefins.

  12. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support of HCCI Emission Control

    Broader source: Energy.gov [DOE]

    Development of catalyst materials to facilitate the low-temperature oxidation of hydrocarbons and CO in homogeneous charge compression ignition (HCCI) emissions.

  13. Preface to Special Topic: Marine Renewable Energy

    SciTech Connect (OSTI)

    Pinto, F. T.; Iglesias, G.; Santos, P. R.; Deng, Zhiqun

    2015-12-30

    Marine renewable energy (MRE) is generates from waves, currents, tides, and thermal resources in the ocean. MRE has been identified as a potential commercial-scale source of renewable energy. This special topic presents a compilation of works selected from the 3rd IAHR Europe Congress, held in Porto, Portugal, in 2014. It covers different subjects relevant to MRE, including resource assessment, marine energy sector policies, energy source comparisons based on levelized cost, proof-of-concept and new-technology development for wave and tidal energy exploitation, and assessment of possible inference between wave energy converters (WEC).

  14. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    April 4, 2005 - Phoenix, AZ Group Chair: Jay Jones (DOE/OCRWM) Tribal Topic Group Members Present: Nancy Bennett (UNM/ATRI), Kevin Blackwell (DOT/FRA), Kristen Ellis (DOE/CI), Ed Gonzales (ELG), Elizabeth Helvey (BSC), Jeff Hepting (Pueblo of Acoma), Robert Holden (NCAI), Judith Holm (DOE/OCRWM), Dan King (Oneida Nation), Gary Lanthrum (DOE/OCRWM), Bob Lupton (DOE/ORD/IR), Corinne Macaluso (DOE/OCRWM), Ellen Ott (DOE/GC), Jennifer Patric (BAH), Stanley Paytiamo (Pueblo of Acoma), Wilda Portner

  15. Homogeneous charge engines -- Basis of cyclic variations. Final report

    SciTech Connect (OSTI)

    Whitelaw, J.H.

    1997-06-30

    The objectives of the Grant required investigations of cyclic variations in a homogeneous-charge engine initially with gas combustion and the air from ranging from near quiescent to the incorporation of swirl and tumble by valve inserts. Later experiments were performed with unleaded gasoline. The measurements included local velocity and cylinder pressure through the four strokes of a single-cylinder engine, under motored and firing conditions and with examination of the flame kernel growth by combinations of photography and flame-ionization gauges. In all cases, the measurements of in-cylinder characteristics were linked to performance as measured in terms of speed and its variability, load and emissions. The experiments progressed to consider deviations from homogeneous charge and included consideration of stratified charge with local injection of a rich mixture in the vicinity of the spark gap so as to establish a flame kernel which would propagate securely into an overall weak mixture.

  16. Apparatus for unilateral generation of a homogeneous magnetic field

    DOE Patents [OSTI]

    Fukushima, Eiichi; Rath, Alan R.; Roeder, Stephen B. W.

    1988-01-01

    An apparatus for unilaterally producing a substantially homogeneous magnetic field. The apparatus includes two circular electromagnet coils, a small coil and a large coil, which are coaxial with one another and which are separated by a distance equal to one-half the difference in the radius of the two coils. By appropriate selection of electrical currents, which are passed through the coil in opposite directions, a region of homogeneous magnetic field is formed. This region is centered on the common axis of the two coils, at a point on the axis which is at a distance from the small coil equal to one-half the radius of the small coil, and which is on the opposite side of the small coil from the large coil. The apparatus has particular application in the field of diagnostic medical NMR and other NMR applications.

  17. Apparatus for unilateral generation of a homogeneous magnetic field

    DOE Patents [OSTI]

    Fukushima, E.; Rath, A.R.; Roeder, S.B.W.

    1984-05-01

    An apparatus for unilaterally producing a substantially homogeneous magnetic field. The apparatus includes two circular electromagnet coils, a small coil and a large coil, which are coaxial with one another and which are separated by a distance equal to one-half the difference in the radius of the two coils. By appropriate selection of electrical currents, which are passed through the coils in opposite directions, a region of homogeneous magnetic field is formed. This region is centered on the common axis of the two coils, at a point on the axis which is at a distance from the small coil equal to one-half the radius of the small coil, and which is on the opposite side of the small coil from the large coil. The apparatus has particular application in the field of diagnostic medical NMR and other NMR applications.

  18. Simulator for SUPO, a Benchmark Aqueous Homogeneous Reactor (AHR)

    SciTech Connect (OSTI)

    Klein, Steven Karl; Determan, John C.

    2015-10-14

    A simulator has been developed for SUPO (Super Power) an aqueous homogeneous reactor (AHR) that operated at Los Alamos National Laboratory (LANL) from 1951 to 1974. During that period SUPO accumulated approximately 600,000 kWh of operation. It is considered the benchmark for steady-state operation of an AHR. The SUPO simulator was developed using the process that resulted in a simulator for an accelerator-driven subcritical system, which has been previously reported.

  19. High load operation in a homogeneous charge compression ignition engine

    SciTech Connect (OSTI)

    Duffy, Kevin P.; Kieser, Andrew J.; Liechty, Michael P.; Hardy, William L.; Rodman, Anthony; Hergart, Carl-Anders

    2008-12-23

    A homogeneous charge compression ignition engine is set up by first identifying combinations of compression ratio and exhaust gas percentages for each speed and load across the engines operating range. These identified ratios and exhaust gas percentages can then be converted into geometric compression ratio controller settings and exhaust gas recirculation rate controller settings that are mapped against speed and load, and made available to the electronic

  20. Multicomponent homogeneous alloys and method for making same

    DOE Patents [OSTI]

    Dutta, Partha S.; Miller, Thomas R.

    2003-09-02

    The present application discloses a method for preparing a homogeneous ternary or quaternary alloy from a quaternary melt. The method includes providing a family of phase diagrams for the quaternary melt which shows (i) composition/temperature data, (ii) tie lines connecting equilibrium liquid and solid compositions, and (iii) isotherms representing boundaries of a miscibility gap. Based on the family of phase diagrams, a quaternary melt composition and an alloy growth temperature is selected. A quaternary melt having the selected quaternary melt composition is provided and a ternary or quaternary alloy is grown from the quaternary melt at the selected alloy growth temperature. A method for making homogeneous ternary or quaternary alloy from a ternary or quaternary melt is also disclosed, as are homogeneous quaternary single-crystal alloys which are substantially free from crystal defects and which have the formula A.sub.x B.sub.1-x C.sub.y D.sub.1-y, x and y being the same or different and in the range of 0.001 to 0.999.

  1. OSTIblog Articles in the science information Topic | OSTI, US...

    Office of Scientific and Technical Information (OSTI)

    The search engine that helps you find science information from U.S. Department of Energy ... Science News and Wikipedia information on your topic(s) of interest and clusters results ...

  2. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Missouri Botanical Garden- EarthWays Center October 6, 2015 - 4:00pm How...

  3. Hot Topics Workshop - February 2015 | Photosynthetic Antenna Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center - February 2015 Hot Topics Workshop - February 2015 Shots from our Hot Topics Workshop: Energy and the Environment for Secondary Science Teachers. Original Event Info found here

  4. TEC Working Group Topic Groups Rail Conference Call Summaries | Department

    Office of Environmental Management (EM)

    of Energy Rail Conference Call Summaries TEC Working Group Topic Groups Rail Conference Call Summaries CONFERENCE CALL SUMMARIES Rail Topic Group Inspections Subgroup Planning Subgroup Tracking Subgroup TRAGIS Subgroup Radiation Monitoring Subgroup Intermodel Subgroup

  5. Smart Grid Investment Grant Topic Areas | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic Areas Smart Grid Investment Grant Topic Areas A description of the topic areas for projects selected for award under the Smart Grid Investment Grant project of the American Recovery and Reinvestment Act. Smart Grid Investment Grant Topic Areas (25.19 KB) More Documents & Publications Smart Grid Investment Grant Program - Progress Report (July 2012) SGIG and SGDP Highlights: Jumpstarting a Modern Grid (October 2014) Smart Grid R&D Multi-Year Program Plan (2010-2014) - September 2011

  6. OSTIblog Articles in the Strategic Plan Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    and nuclear challenges through transformative science and technology solutions. The... Related Topics: clean energy, nuclear security, Science Accelerator, Strategic Plan

  7. TEC Working Group Topic Groups Archives Communications Meeting Summaries |

    Office of Environmental Management (EM)

    Department of Energy Archives Communications Meeting Summaries TEC Working Group Topic Groups Archives Communications Meeting Summaries Meeting Summaries Milwaukee TEC Meeting, Communications Topic Group Summary - July 1998 (58.3 KB) Inaugural Group Meeting - April 1998 (83.34 KB) More Documents & Publications TEC Working Group Topic Groups Archives Communications Conference Call Summaries TEC Meeting Summaries - January 1997 TEC Working Group Topic Groups Tribal Conference Call

  8. Webtrends Archives by Fiscal Year — Topic Landing Pages

    Broader source: Energy.gov [DOE]

    From the EERE Web Statistics Archive: Corporate sites, Webtrends archives for the topic landing pages by fiscal year.

  9. TEC Working Group Topic Groups Archives Protocols Meeting Summaries |

    Office of Environmental Management (EM)

    Department of Energy Protocols Meeting Summaries TEC Working Group Topic Groups Archives Protocols Meeting Summaries Meeting Summaries Philadelphia TEC Meeting, Protocols Topic Group Summary - July 1999 (110.63 KB) Jacksonville TEC Meeting, Protocols Topic Group Summary - January 1999 (102.04 KB) More Documents & Publications TEC Working Group Topic Groups Archives Protocols Conference Call Summaries TEC Meeting Summaries - July 1997 TEC Meeting Summaries - January 1997

  10. TEC Working Group Topic Groups Rail Conference Call Summaries Inspections

    Office of Environmental Management (EM)

    Subgroup | Department of Energy Summaries Inspections Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Inspections Subgroup Inspections Subgroup April 6, 2006 (14.05 KB) February 23, 2006 Draft (20.29 KB) January 24, 2006 (27.44 KB) More Documents & Publications TEC Working Group Topic Groups Rail Conference Call Summaries Planning Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Tracking Subgroup TEC Working Group Topic Groups Rail Conference