National Library of Energy BETA

Sample records for topics catalysis homogeneous

  1. Homogeneous and Interfacial Catalysis in 3D Controlled Environment | The

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ames Laboratory Homogeneous and Interfacial Catalysis in 3D Controlled Environment FWP/Project Description: Project Leader(s): Marek Pruski Principal Investigators: Marek Pruski, Aaron Sadow, Igor Slowing Key Scientific Personnel: Takeshi Kobayashi This collaborative research effort is geared toward bringing together the best features of homogeneous and heterogeneous catalysis for developing new catalytic principles. Novel silica-based, single-site mesoporous catalysts with controlled,

  2. Converting Homogeneous to Heterogeneous in Electrophilic Catalysis using Monodisperse Metal Nanoparticles

    SciTech Connect (OSTI)

    Witham, Cole A.; Huang, Wenyu; Tsung, Chia-Kuang; Kuhn, John N.; Somorjai, Gabor A.; Toste, F. Dean

    2009-10-15

    A continuing goal in catalysis is the transformation of processes from homogeneous to heterogeneous. To this end, nanoparticles represent a new frontier in heterogeneous catalysis, where this conversion is supplemented by the ability to obtain new or divergent reactivity and selectivity. We report a novel method for applying heterogeneous catalysts to known homogeneous catalytic reactions through the design and synthesis of electrophilic platinum nanoparticles. These nanoparticles are selectively oxidized by the hypervalent iodine species PhICl{sub 2}, and catalyze a range of {pi}-bond activation reactions previously only homogeneously catalyzed. Multiple experimental methods are utilized to unambiguously verify the heterogeneity of the catalytic process. The discovery of treatments for nanoparticles that induce the desired homogeneous catalytic activity should lead to the further development of reactions previously inaccessible in heterogeneous catalysis. Furthermore, our size and capping agent study revealed that Pt PAMAM dendrimer-capped nanoparticles demonstrate superior activity and recyclability compared to larger, polymer-capped analogues.

  3. ISHHC XIII International Symposium on the Relations betweenHomogeneous and Heterogeneous Catalysis

    SciTech Connect (OSTI)

    Somorjai , G.A.

    2007-06-11

    The International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC) has a long and distinguished history. Since 1974, in Brussels, this event has been held in Lyon, France (1977), Groeningen, The Netherlands (1981); Asilomar, California (1983); Novosibirsk, Russia (1986); Pisa, Italy (1989); Tokyo, Japan (1992); Balatonfuered, Hungary (1995); Southampton, United Kingdom (1999); Lyon, France (2001); Evanston, Illinois (2001) and Florence, Italy (2005). The aim of this international conference in Berkeley is to bring together practitioners in the three fields of catalysis, heterogeneous, homogeneous and enzyme, which utilize mostly nanosize particles. Recent advances in instrumentation, synthesis and reaction studies permit the nanoscale characterization of the catalyst systems, often for the same reaction, under similar experimental conditions. It is hoped that this circumstance will permit the development of correlations of these three different fields of catalysis on the molecular level. To further this goal we aim to uncover and focus on common concepts that emerge from nanoscale studies of structures and dynamics of the three types of catalysts. Another area of focus that will be addressed is the impact on and correlation of nanosciences with catalysis. There is information on the electronic and atomic structures of nanoparticles and their dynamics that should have importance in catalyst design and catalytic activity and selectivity.

  4. Surface functionalization of metal?organic polyhedron for homogeneous cyclopropanation catalysis

    SciTech Connect (OSTI)

    Lu, Weigang; Yuan, Daqiang; Yakovenko, Andrey; Zhou, Hong-Cai

    2012-03-13

    A super-paddlewheel (comprised of two paddlewheels) metal-organic polyhedron (MOP) containing surface hydroxyl groups was synthesized and characterized. Condensation reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst.

  5. Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2? In Operando-XAFS, Kinetic and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4 Cluster-Based Benzene Hydrogenation Catalysis

    SciTech Connect (OSTI)

    Bayram, Ercan; Linehan, John C.; Fulton, John L.; Roberts, John A.; Szymczak, Nathaniel; Smurthwaite, Tricia D.; Ozkar, Saim; Balasubramanian, Mahalingam; Finke, Richard G.

    2011-11-23

    Determining the true, kinetically dominant catalytically active species, in the classic benzene hydrogenation system pioneered by Maitlis and co-workers 34 years ago starting with [RhCp*Cl2]2 (Cp* = [{eta}5-C5(CH3)5]), has proven to be one of the most challenging case studies in the quest to distinguish single-metal-based 'homogeneous' from polymetallic, 'heterogeneous' catalysis. The reason, this study will show, is the previous failure to use the proper combination of (i) operando spectroscopy to determine the dominant form(s) of the precatalyst's mass under catalysis (i.e., operating) conditions, plus then and crucially also (ii) the previous lack of the necessary kinetic studies, catalysis being a 'wholly kinetic phenomenon' as J. Halpern long ago noted. An important contribution from this study will be to reveal the power of quantitiative kinetic poisoning experiments for distinguishing single-metal, or in this case subnanometer Rh4 cluster-based catalysis from larger, polymetallic Rh(0)n nanoparticle catalysis, at least under favorable conditions. The combined operando-XAFS (X-ray absorption fine structure) spectroscopy and kinetic evidences provide a compelling case for Rh4-based, with average stoichiometry 'Rh4Cp*2.4Cl4Hc', benzene hydrogenation catalysis in 2-propanol with added Et3N and at 100 C and 50 atm initial H2 pressure. The results also reveal, however, that if even ca. 1.4% of the total soluble Rh(0)n had formed nanoparticles, then those Rh(0)n nanoparticles would have been able to account for all the observed benzene hydrogenation catalytic rate (using commercial, ca. 2 nm, polyethyleneglycol-dodecylether hydrosol stabilized Rh(0)n nanoparticles as a model system). The results 'especially the poisoning methodology developed and employed' are of significant, broader interest since determining the nature of the true catalyst continues to be a central, often vexing issue in any and all catalytic reactions. The results are also of fundamental

  6. Virtual special issue on catalysis at the U.S. Department of Energy's National Laboratories

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pruski, Marek; Sadow, Aaron D.; Slowing, Igor I.; Marshall, Christopher L.; Stair, Peter; Rodriguez, Jose; Harris, Alex; Somorjai, Gabor A.; Biener, Juergen; Matranga, Christopher; et al

    2016-04-21

    Here the catalysis research at the U.S. Department of Energy's (DOE's) National Laboratories covers a wide range of research topics in heterogeneous catalysis, homogeneous/molecular catalysis, biocatalysis, electrocatalysis, and surface science. Since much of the work at National Laboratories is funded by DOE, the research is largely focused on addressing DOE's mission to ensure America's security and prosperity by addressing its energy, environmental, and nuclear challenges through transformative science and technology solutions.

  7. Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction. Task 1, Topical report No. 1

    SciTech Connect (OSTI)

    Laine, R.M.

    1986-01-20

    The purpose of this report is to update and reorganize our recent review on homogeneous catalysis of the water-gas shift reaction (WGSR) based on recent literature publications and patents. This updated version will serve as a means of selecting 10 candidate catalyst systems for use in developing effective, sulfur-tolerant, low temperature WGSR catalysts. This report discusses the variations possible in the basic chemistry associated with WGSR catalytic cycles, including basic, acidic, and neutral conditions. Then individual mechanism for specific WGSR catalyst systems are discussed. Finally, on the basis of the literature reports, a list is presented of candidate catalysts and basic systems we have chosen for study in Task 3.

  8. Catalysis | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Heterogeneous Catalysis - J. K. Norskov Homogeneous and Single-Site Heterogeneous Catalysis - Tobin Marks Thursday, May 16, 2002 - Breakout Summary Reports Catalysts Design Driven ...

  9. Fabrication of Carbon-Platinum Interdigitated Array Electrodes and Their Application for Investigating Homogeneous Hydrogen Evolution Catalysis

    SciTech Connect (OSTI)

    Liu, Fei; Divan, Ralu; Parkinson, Bruce A.

    2015-06-29

    Carbon interdigitated array (IDA) electrodes have been applied to study the homogeneous hydrogen evolution electrocatalyst [Ni(PPh2NBn2)2]2+ (where PPh2NBn2 is 1,5-dibenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane). The existence of reaction intermediates in the catalytic cycle is inferred from the electrochemical behavior of a glassy carbon disk electrodes and carbon IDA electrodes. The currents on IDA electrodes for an EC’ (electron transfer reaction followed by a catalytic reaction) mechanism are derived from the number of redox cycles and the contribution of non-catalytic currents. The catalytic reaction rate constant was then extracted from the IDA current equations. Applying the IDA current and kinetic equations to the electrochemical response of the [Ni(PPh2NBn2)2]2+ catalyst yielded a rate constant of 0.10 s-1 for the hydrogen evolution reaction that agrees with the literature value. The quantitative analysis of IDA cyclic voltammetry can be used as a simple and straightforward method for determining rate constants in other catalytic systems. This work was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for DOE. Use of the Center for Nanoscale Materials was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357.

  10. Catalysis Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Opportunities in Catalysis Research Using Synchrotron Radiation Stanford Synchrotron Radiation Laboratory October 8-9, 2002 Organizer: Anders Nilsson Chemical catalysis is one of the research areas of enormous importance for the industrial society. There are important challenges to be met in the near future where development of new processes and catalysts are a necessity. We need to find a way to make methanol from methane, split water into hydrogen using sunlight, find replacement of platinum

  11. DOE Laboratory Catalysis Research Symposium - Abstracts

    SciTech Connect (OSTI)

    Dunham, T.

    1999-02-01

    The conference consisted of two sessions with the following subtopics: (1) Heterogeneous Session: Novel Catalytic Materials; Photocatalysis; Novel Processing Conditions; Metals and Sulfides; Nuclear Magnetic Resonance; Metal Oxides and Partial Oxidation; Electrocatalysis; and Automotive Catalysis. (2) Homogeneous Catalysis: H-Transfer and Alkane Functionalization; Biocatalysis; Oxidation and Photocatalysis; and Novel Medical, Methods, and Catalyzed Reactions.

  12. EMSL and Institute for Integrated Catalysis (IIC) Catalysis Workshop

    SciTech Connect (OSTI)

    Campbell, Charles T.; Datye, Abhaya K.; Henkelman, Graeme A.; Lobo, Raul F.; Schneider, William F.; Spicer, Leonard D.; Tysoe, Wilfred T.; Vohs, John M.; Baer, Donald R.; Hoyt, David W.; Thevuthasan, Suntharampillai; Mueller, Karl T.; Wang, Chong M.; Washton, Nancy M.; Lyubinetsky, Igor; Teller, Raymond G.; Andersen, Amity; Govind, Niranjan; Kowalski, Karol; Kabius, Bernd C.; Wang, Hongfei; Campbell, Allison A.; Shelton, William A.; Bylaska, Eric J.; Peden, Charles HF; Wang, Yong; King, David L.; Henderson, Michael A.; Rousseau, Roger J.; Szanyi, Janos; Dohnalek, Zdenek; Mei, Donghai; Garrett, Bruce C.; Ray, Douglas; Futrell, Jean H.; Laskin, Julia; DuBois, Daniel L.; Kuprat, Laura R.; Plata, Charity

    2011-05-24

    Within the context of significantly accelerating scientific progress in research areas that address important societal problems, a workshop was held in November 2010 at EMSL to identify specific and topically important areas of research and capability needs in catalysis-related science.

  13. Workshop: Synchrotron Applications in Chemical Catalysis | Stanford

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synchrotron Radiation Lightsource Synchrotron Applications in Chemical Catalysis Tuesday, October 25, 2011 - 8:00am 2011 SSRL/LCLS Annual Users Conference This workshop, part of the 2011 SSRL/LCLS Annual Users Conference, will focus on understanding processes in homogeneous (both biological and small molecule) and heterogeneous catalysis, using synchrotron-based methods. The workshop will cover more traditional applications (using XANES and EXAFS), as well as applications of XES, RIXS and

  14. Seventh BES (Basic Energy Sciences) catalysis and surface chemistry research conference

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    Research programs on catalysis and surface chemistry are presented. A total of fifty-seven topics are included. Areas of research include heterogeneous catalysis; catalysis in hydrogenation, desulfurization, gasification, and redox reactions; studies of surface properties and surface active sites; catalyst supports; chemical activation, deactivation; selectivity, chemical preparation; molecular structure studies; sorption and dissociation. Individual projects are processed separately for the data bases. (CBS)

  15. A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst Covalently Attached to a Glassy Carbon Electrode: Preparation, Characterization, and Catalysis. Comparisons With the Homogeneous Analog

    SciTech Connect (OSTI)

    Das, Atanu K.; Engelhard, Mark H.; Bullock, R. Morris; Roberts, John A.

    2014-07-07

    A hydrogen-evolving homogeneous Ni(P2N2)2 electrocatalyst with peripheral ester groups has been covalently attached to a 1,2,3-triazolyllithium-terminated glassy carbon electrode. The surface-confined complex is an electroctalyst for hydrogen evolution, showing onset of catalytic current at the same potential as the soluble parent complex. X-ray photoemission spectra show excellent agreement between the coupled and homogeneous species. Coverage approaches a dense monolayer. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. The XPS measurements were performed at EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  16. 2012 Catalysis Lectures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Weckhuysen is since 2000 full professor Inorganic Chemistry and Catalysis at Utrecht University (The Netherlands). He is also scientific director of the Netherlands Institute of ...

  17. 2012 Catalysis Lectures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis Lectures May 21-24 2012 Bert Weckhuysen Bert Weckhuysen, who holds the chair of Inorganic Chemistry and Catalysis at Utrecht University, will give a series of catalysis lectures during his sabbatical period at Stanford University and SLAC. (1) "Characterization of Heterogeneous Catalysts: Possibilities and Limitations of In-situ Spectroscopy" (Part I) Monday, May 21, 2012, 4.30-6 p.m. Location: SLAC Redwood Conference Room C&D (2) "Characterization of Heterogeneous

  18. Catalysis by heteropoly compounds. XXII. Reactions of esters and esterification catalyzed by heteropolyacids in a homogeneous liquid phase - effects of the central atom of heteropolyanions having tungsten as the addenda atom

    SciTech Connect (OSTI)

    Hu, Changwen; Hashimoto, Masato; Okuhara, Toshio; Misono, Makoto )

    1993-10-01

    Decomposition of isobutyl propionate (IBP) (Reaction (1)), ester exchange of IBP with acetic acid (Reaction (2)), ester exchange of IBP with n-propyl alcohol (Reaction (3)), and esterification of propionic acid with isobutyl alcohol (Reaction (4)) have been studied in a homogeneous liquid phase using heteropolyacids H[sub m]XW[sub 12]O[sub 40] (X = P, Si, Ge, B, and Co) having the Keggin structure and H[sub 6]P[sub 2]W[sub 18]O[sub 62] having the Dawson structure. The results clearly indicated that the catalytic behavior of heteropolyacids remarkably depended on the kind of reaction system, namely, the basicity of reactants. For Reaction (1), the catalytic activities of the heteropolyacids were 60-100 times higher than those of H[sub 2]SO[sub 4] and p-toluenesulfonic acid. Among the heteropolyacids, the activity was in the order H[sub 3]PW[sub 12]O[sub 40] > H[sub 4]SiW[sub 12]O[sub 40] [approximately] H[sub 4]GeW[sub 12]O[sub 40] > H[sub 5]BW[sub 12]O[sub 40] > H[sub 6]CoW[sub 12]O[sub 40]. This order suggests that the activity follows the order of the acid strength of the solutions of heteropolyacids, which increases with the decrease in the negative charge of the polyanion. H[sub 6]P[sub 2]W[sub 18]O[sub 62] showed an activity between those of H[sub 5]BW[sub 12]O[sub 40] and H[sub 6]CoW[sub 12]O[sub 40]. Water molecules in the system retarded Reaction 1. For Reaction 2, the activity order was similar to that for Reaction 1 in the absence of water. However, contrary to Reaction 1, the addition of water greatly accelerated Reaction 2. It was presumed that, in the presence of water, Reaction 2 proceeds via the hydrolysis of IBP to propionic acid and isobutyl alcohol, followed by the esterification of isobutyl alcohol with acetic acid. 28 refs., 8 figs., 4 tabs.

  19. Neutrons for Catalysis: A Workshop on Neutron Scattering Techniques for Studies in Catalysis

    SciTech Connect (OSTI)

    Overbury, Steven {Steve} H; Coates, Leighton; Herwig, Kenneth W; Kidder, Michelle

    2011-10-01

    This report summarizes the Workshop on Neutron Scattering Techniques for Studies in Catalysis, held at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL) on September 16 and 17, 2010. The goal of the Workshop was to bring experts in heterogeneous catalysis and biocatalysis together with neutron scattering experimenters to identify ways to attack new problems, especially Grand Challenge problems in catalysis, using neutron scattering. The Workshop locale was motivated by the neutron capabilities at ORNL, including the High Flux Isotope Reactor (HFIR) and the new and developing instrumentation at the SNS. Approximately 90 researchers met for 1 1/2 days with oral presentations and breakout sessions. Oral presentations were divided into five topical sessions aimed at a discussion of Grand Challenge problems in catalysis, dynamics studies, structure characterization, biocatalysis, and computational methods. Eleven internationally known invited experts spoke in these sessions. The Workshop was intended both to educate catalyst experts about the methods and possibilities of neutron methods and to educate the neutron community about the methods and scientific challenges in catalysis. Above all, it was intended to inspire new research ideas among the attendees. All attendees were asked to participate in one or more of three breakout sessions to share ideas and propose new experiments that could be performed using the ORNL neutron facilities. The Workshop was expected to lead to proposals for beam time at either the HFIR or the SNS; therefore, it was expected that each breakout session would identify a few experiments or proof-of-principle experiments and a leader who would pursue a proposal after the Workshop. Also, a refereed review article will be submitted to a prominent journal to present research and ideas illustrating the benefits and possibilities of neutron methods for catalysis research.

  20. Zeolite catalysis: technology

    SciTech Connect (OSTI)

    Heinemann, H.

    1980-07-01

    Zeolites have been used as catalysts in industry since the early nineteen sixties. The great majority of commercial applications employ one of three zeolite types: zeolite Y; Mordenite; ZSM-5. By far the largest use of zeolites is in catalytic cracking, and to a lesser extent in hydrocracking. This paper reviews the rapid development of zeolite catalysis and its application in industries such as: the production of gasoline by catalytic cracking of petroleum; isomerization of C/sub 5/ and C/sub 6/ paraffin hydrocarbons; alkylation of aromatics with olefins; xylene isomerization; and conversion of methanol to gasoline.

  1. Electron Microscopy Catalysis Projects: Success Stories from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electron Microscopy Catalysis Projects: Success Stories from the High Temperature Materials Laboratory (HTML) User Program Electron Microscopy Catalysis Projects: Success Stories ...

  2. Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make ...

  3. Catalysis Capabilities | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis Research Areas Facilities and Equipment Intellectual Property Publications Staff Partnerships Licensing Sponsored Research Technical Services Technologist in Residence News Press Releases Feature Stories In the News Photos Videos Ombudsman Ombudsman Argonne National Laboratory Technology Development and Commercialization About Technologies Available for Licensing Capabilities Partnerships News Capabilities Catalysis Research Areas Facilities and Equipment Intellectual Property

  4. Enhanced Micellar Catalysis LDRD.

    SciTech Connect (OSTI)

    Betty, Rita G.; Tucker, Mark David; Taggart, Gretchen; Kinnan, Mark K.; Glen, Crystal Chanea; Rivera, Danielle; Sanchez, Andres; Alam, Todd Michael

    2012-12-01

    The primary goals of the Enhanced Micellar Catalysis project were to gain an understanding of the micellar environment of DF-200, or similar liquid CBW surfactant-based decontaminants, as well as characterize the aerosolized DF-200 droplet distribution and droplet chemistry under baseline ITW rotary atomization conditions. Micellar characterization of limited surfactant solutions was performed externally through the collection and measurement of Small Angle X-Ray Scattering (SAXS) images and Cryo-Transmission Electron Microscopy (cryo-TEM) images. Micellar characterization was performed externally at the University of Minnesota's Characterization Facility Center, and at the Argonne National Laboratory Advanced Photon Source facility. A micellar diffusion study was conducted internally at Sandia to measure diffusion constants of surfactants over a concentration range, to estimate the effective micelle diameter, to determine the impact of individual components to the micellar environment in solution, and the impact of combined components to surfactant phase behavior. Aerosolized DF-200 sprays were characterized for particle size and distribution and limited chemical composition. Evaporation rates of aerosolized DF-200 sprays were estimated under a set of baseline ITW nozzle test system parameters.

  5. Topic Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RAP Work Plan Topics Page 1 of 3 Topic Committee Potential FY 2016 Action/Product Context (from FY 2016 HAB Work Plan) 6-Month Status (IM, Committee, Advice, Deferred, No Action) 1. 100 Area retrieval process, K Basin RAP Project update (May not be ready until 2017 for an update; work ready in 2018 per milestone)  Attended tour in October 2015, including visit to MO-500/Sludge Annex facility 2. 100 D/H Proposed Plan RAP Project update Cleanup of soils and groundwater at D/H. Are the proposed

  6. Biomimetic Chalcogels for Solar Fuel Catalysis | ANSER Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomimetic Chalcogels for Solar Fuel Catalysis Home > Research > ANSER Research Highlights > Biomimetic Chalcogels for Solar Fuel Catalysis...

  7. Reaction Selectivity in Heterogeneous Catalysis

    SciTech Connect (OSTI)

    Somorjai, Gabor A.; Kliewer, Christopher J.

    2009-02-02

    The understanding of selectivity in heterogeneous catalysis is of paramount importance to our society today. In this review we outline the current state of the art in research on selectivity in heterogeneous catalysis. Current in-situ surface science techniques have revealed several important features of catalytic selectivity. Sum frequency generation vibrational spectroscopy has shown us the importance of understanding the reaction intermediates and mechanism of a heterogeneous reaction, and can readily yield information as to the effect of temperature, pressure, catalyst geometry, surface promoters, and catalyst composition on the reaction mechanism. DFT calculations are quickly approaching the ability to assist in the interpretation of observed surface spectra, thereby making surface spectroscopy an even more powerful tool. HP-STM has revealed three vitally important parameters in heterogeneous selectivity: adsorbate mobility, catalyst mobility, and selective site-blocking. The development of size controlled nanoparticles from 0.8 to 10 nm, of controlled shape, and of controlled bimetallic composition has revealed several important variables for catalytic selectivity. Lastly, DFT calculations may be paving the way to guiding the composition choice for multi-metallic heterogeneous catalysis for the intelligent design of catalysts incorporating the many factors of selectivity we have learned.

  8. 2013 DOE Catalysis Working Group Meeting Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    13 DOE Catalysis Working Group Meeting Agenda 2013 DOE Catalysis Working Group Meeting Agenda Agenda for the 2013 DOE Catalysis Working Group Meeting on May 15, 2013. cwg_may2013_agenda.pdf (89.11 KB) More Documents & Publications Catalysis Working Group Kick-Off Meeting Agenda DOE Durability Working Group June 2014 Meeting Agenda Catalysis Working Group Meeting: June 2015

  9. Catalysis Working Group | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis Working Group Catalysis Working Group The Catalysis Working Group (CWG) meets twice per year to exchange information, create synergies, and collaboratively develop both an understanding of and tools for studying electrocatalysis for polymer electrolyte fuel cells (PEFCs) and other low- and intermediate-temperature fuel cell systems, including direct methanol fuel cells (DMFCs), alkaline fuel cells (AFCs), alkaline membrane fuel cells (AMFCs), and phosphoric acid fuel cells (PAFCs). The

  10. Workshop: Synchrotron Applications in Chemical Catalysis | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications in Chemical Catalysis Tuesday, October 25, 2011 - 8:00am 2011 SSRLLCLS Annual Users Conference This workshop, part of the 2011 SSRLLCLS Annual Users...

  11. Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... D2. Chemical Conversion: Alternatively, the sugars can be converted to fuels or an entire suite of other useful products using chemical catalysis. E. Product Recovery: Products are ...

  12. Basic Research Needs: Catalysis for Energy

    SciTech Connect (OSTI)

    Bell, Alexis T.; Gates, Bruce C.; Ray, Douglas; Thompson, Michael R.

    2008-03-11

    The report presents results of a workshop held August 6-8, 2007, by DOE SC Basic Energy Sciences to determine the basic research needs for catalysis research.

  13. DOE Catalysis Working Group Meeting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    16, 2014 Marriott Wardman Park Hotel 2660 Woodley Road NM, Washington, D.C. 8:30 - 9:00 Continental breakfast: breads, coffee, tea Joint Durability and Catalysis Working Groups Meeting Delaware A 9:00 - 9:05 Welcome & introductory comments DWG co-chairs - Debbie Myers (ANL), Rod Borup (LANL), Donna Ho (DOE); CWG co-chairs - Piotr Zelenay (LANL), Nancy Garland (DOE) 9:05 - 9:25 Are We There Yet? Pt-Alloy Catalyst - Anu Kongkanand (GM) 9:25 - 9:45 Pt-Co/C Catalysts: PEMFC Performance and

  14. The energy landscape of ;#8203;adenylate kinase during catalysis...

    Office of Scientific and Technical Information (OSTI)

    The energy landscape of ;8203;adenylate kinase during catalysis Citation Details In-Document Search Title: The energy landscape of ;8203;adenylate kinase during catalysis ...

  15. Materials Design and Discovery: Catalysis and Energy Storage...

    Office of Scientific and Technical Information (OSTI)

    Materials Design and Discovery: Catalysis and Energy Storage (Mira Early Science Program ... Citation Details In-Document Search Title: Materials Design and Discovery: Catalysis and ...

  16. Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts The Bioenergy ...

  17. Catalysis by Design - Theoretical and Experimental Studies of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis by Design - Theoretical and Experimental Studies of Model Catalysts for Lean NOx ... Lean NOx Traps - Microstructural Studies of Real World and Model Catalysts Catalysis by ...

  18. EERE Success Story-Fundamental Studies in Catalysis Enabled the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamental Studies in Catalysis Enabled the use of Efficient "Lean-Burn" Engines for Vehicle Transportation EERE Success Story-Fundamental Studies in Catalysis Enabled the use of ...

  19. Transmural Catalysis - High Efficiency Catalyst Systems for NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation ...

  20. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support ...

  1. Pre-Competitive Catalysis Research: Fundamental Sulfation/Desulfation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of Lean NOx Traps Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of...

  2. Biomimetic Chalcogels for Solar Fuel Catalysis | ANSER Center |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne-Northwestern National Laboratory Biomimetic Chalcogels for Solar Fuel Catalysis Home > Research > ANSER Research Highlights > Biomimetic Chalcogels for Solar Fuel Catalysis

  3. "Nanocrystal bilayer for tandem catalysis"

    SciTech Connect (OSTI)

    Yamada, Yusuke; Tsung, Chia Kuang; Huang, Wenyu; Huo, Ziyang; E.Habas, Susan E; Soejima, Tetsuro; Aliaga, Cesar E; Samorjai, Gabor A; Yang, Peidong

    2011-01-24

    Supported catalysts are widely used in industry and can be optimized by tuning the composition and interface of the metal nanoparticles and oxide supports. Rational design of metal-metal oxide interfaces in nanostructured catalysts is critical to achieve better reaction activities and selectivities. We introduce here a new class of nanocrystal tandem catalysts that have multiple metal-metal oxide interfaces for the catalysis of sequential reactions. We utilized a nanocrystal bilayer structure formed by assembling platinum and cerium oxide nanocube monolayers of less than 10 nm on a silica substrate. The two distinct metal-metal oxide interfaces, CeO2-Pt and Pt-SiO2, can be used to catalyse two distinct sequential reactions. The CeO2-Pt interface catalysed methanol decomposition to produce CO and H2, which were subsequently used for ethylene hydroformylation catalysed by the nearby Pt-SiO2 interface. Consequently, propanal was produced selectively from methanol and ethylene on the nanocrystal bilayer tandem catalyst. This new concept of nanocrystal tandem catalysis represents a powerful approach towards designing high-performance, multifunctional nanostructured catalysts

  4. Center for Catalysis at Iowa State University

    SciTech Connect (OSTI)

    Kraus, George A.

    2006-10-17

    The overall objective of this proposal is to enable Iowa State University to establish a Center that enjoys world-class stature and eventually enhances the economy through the transfer of innovation from the laboratory to the marketplace. The funds have been used to support experimental proposals from interdisciplinary research teams in areas related to catalysis and green chemistry. Specific focus areas included: Catalytic conversion of renewable natural resources to industrial materials Development of new catalysts for the oxidation or reduction of commodity chemicals Use of enzymes and microorganisms in biocatalysis Development of new, environmentally friendly reactions of industrial importance These focus areas intersect with barriers from the MYTP draft document. Specifically, section 2.4.3.1 Processing and Conversion has a list of bulleted items under Improved Chemical Conversions that includes new hydrogenation catalysts, milder oxidation catalysts, new catalysts for dehydration and selective bond cleavage catalysts. Specifically, the four sections are: 1. Catalyst development (7.4.12.A) 2. Conversion of glycerol (7.4.12.B) 3. Conversion of biodiesel (7.4.12.C) 4. Glucose from starch (7.4.12.D) All funded projects are part of a soybean or corn biorefinery. Two funded projects that have made significant progress toward goals of the MYTP draft document are: Catalysts to convert feedstocks with high fatty acid content to biodiesel (Kraus, Lin, Verkade) and Conversion of Glycerol into 1,3-Propanediol (Lin, Kraus). Currently, biodiesel is prepared using homogeneous base catalysis. However, as producers look for feedstocks other than soybean oil, such as waste restaurant oils and rendered animal fats, they have observed a large amount of free fatty acids contained in the feedstocks. Free fatty acids cannot be converted into biodiesel using homogeneous base-mediated processes. The CCAT catalyst system offers an integrated and cooperative catalytic system

  5. Nanocrystal assembly for tandem catalysis

    DOE Patents [OSTI]

    Yang, Peidong; Somorjai, Gabor; Yamada, Yusuke; Tsung, Chia-Kuang; Huang, Wenyu

    2014-10-14

    The present invention provides a nanocrystal tandem catalyst comprising at least two metal-metal oxide interfaces for the catalysis of sequential reactions. One embodiment utilizes a nanocrystal bilayer structure formed by assembling sub-10 nm platinum and cerium oxide nanocube monolayers on a silica substrate. The two distinct metal-metal oxide interfaces, CeO.sub.2--Pt and Pt--SiO.sub.2, can be used to catalyze two distinct sequential reactions. The CeO.sub.2--Pt interface catalyzed methanol decomposition to produce CO and H.sub.2, which were then subsequently used for ethylene hydroformylation catalyzed by the nearby Pt--SiO.sub.2 interface. Consequently, propanal was selectively produced on this nanocrystal bilayer tandem catalyst.

  6. Catalysis and Synthesis | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis and Synthesis Catalysis and Synthesis Many different types of chemical reactions depend on catalysts in order to work, and the hunt for better catalysts has deep connections to our nation's economy. From biofuels to plastics, the majority of the products we depend on in our everyday lives rely on catalysts. An estimate from the American Chemical Society found that catalysts and catalytic processes are responsible for more than 20 percent of America's gross domestic product. The

  7. Heterogeneous Catalysis and Surface Science - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heterogeneous Catalysis and Surface Science / Part I: Surface Science in JCAP Laboratories Heterogeneous Catalysis and Surface Science research in JCAP focuses on the basic understanding of the relationships among the structure, composition, and reactivity of electrocatalysts. Knowledge gained from surface science experimentation can be implemented toward the discovery of better heterogeneous catalysts for solar-fuel production from carbon dioxide and water. REFERENCE Soriaga, M. P. et al.

  8. HOMOGENEOUS NUCLEAR POWER REACTOR

    DOE Patents [OSTI]

    King, L.D.P.

    1959-09-01

    A homogeneous nuclear power reactor utilizing forced circulation of the liquid fuel is described. The reactor does not require fuel handling outside of the reactor vessel during any normal operation including complete shutdown to room temperature, the reactor being selfregulating under extreme operating conditions and controlled by the thermal expansion of the liquid fuel. The liquid fuel utilized is a uranium, phosphoric acid, and water solution which requires no gus exhaust system or independent gas recombining system, thereby eliminating the handling of radioiytic gas.

  9. Advanced Resources for Catalysis Science; Recommendations for a National Catalysis Research Institute

    SciTech Connect (OSTI)

    Peden, Charles HF.; Ray, Douglas

    2005-10-05

    Catalysis is one of the most valuable contributors to our economy and historically an area where the United States has enjoyed, but is now losing, international leadership. While other countries are stepping up their work in this area, support for advanced catalysis research and development in the U.S. has diminished. Yet, more than ever, innovative and improved catalyst technologies are imperative for new energy production processes to ease our dependence on imported resources, for new energy-efficient and environmentally benign chemical production processes, and for new emission reduction technologies to minimize the environmental impact of an active and growing economy. Addressing growing concerns about the future direction of U.S. catalysis science, experts from the catalysis community met at a workshop to determine and recommend advanced resources needed to address the grand challenges for catalysis research and development. The workshop's primary conclusion: To recapture our position as the leader in catalysis innovation and practice, and promote crucial breakthroughs, the U.S. must establish one or more well-funded and well-equipped National Catalysis Research Institutes competitively selected, centered in the national laboratories and, by charter, networked to other national laboratories, universities, and industry. The Institute(s) will be the center of a national collaboratory that gives catalysis researchers access to the most advanced techniques available in the scientific enterprise. The importance of catalysis to our energy, economic, and environmental security cannot be overemphasized. Catalysis is a vital part of our core industrial infrastructure, as it is integral to chemical processing and petroleum refining, and is critical to proposed advances needed to secure a sustainable energy future. Advances in catalysis could reduce our need for foreign oil by making better use of domestic carbon resources, for example, allowing cost-effective and zero

  10. HOMOGENEOUS NUCLEAR REACTOR

    DOE Patents [OSTI]

    Hammond, R.P.; Busey, H.M.

    1959-02-17

    Nuclear reactors of the homogeneous liquid fuel type are discussed. The reactor is comprised of an elongated closed vessel, vertically oriented, having a critical region at the bottom, a lower chimney structure extending from the critical region vertically upwardly and surrounded by heat exchanger coils, to a baffle region above which is located an upper chimney structure containing a catalyst functioning to recombine radiolyticallydissociated moderator gages. In operation the liquid fuel circulates solely by convection from the critical region upwardly through the lower chimney and then downwardly through the heat exchanger to return to the critical region. The gases formed by radiolytic- dissociation of the moderator are carried upwardly with the circulating liquid fuel and past the baffle into the region of the upper chimney where they are recombined by the catalyst and condensed, thence returning through the heat exchanger to the critical region.

  11. Shining Light on Catalysis | Stanford Synchrotron Radiation Lightsourc...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shining Light on Catalysis Tuesday, July 19, 2011 - 4:38pm SSRL Conference Room 137-322 Jeroen A. van Bokhoven, Professor for Heterogeneous Catalysis Institute for Chemical and...

  12. Study of catalysis of coal gasification at elevated pressures...

    Office of Scientific and Technical Information (OSTI)

    Study of catalysis of coal gasification at elevated pressures. Evaluation of 20 compounds at 850sup 0C Citation Details In-Document Search Title: Study of catalysis of coal ...

  13. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis ALS X-Rays Shine a New Light on Catalysis Print Thursday, 21 May 2015 11:16 Electrocatalysts are responsible for expediting reactions in...

  14. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Lean ...

  15. Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenatio...

    Office of Scientific and Technical Information (OSTI)

    Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol Citation Details In-Document Search Title: Synergistic Catalysis between Pd and Fe in Gas Phase ...

  16. Opportunities in Catalysis Research Using Synchrotron Radiation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Catalysis Research Using Synchrotron Radiation Tuesday 10/8/02 Chair: Lars Pettersson 1:30-1:40 Anders Nilsson Welcome 1:40-2:30 Gabor Somorjai University of California, Berkeley and LBLN Need for New Directions of Research at the Frontiers of Catalysis Science 2:30-3:00 Geoff Thornton University of Manchester Influence of defects on the reactivity of ZnO 3:00-3:30 Anders Nilsson Stanford Synchrotron Radiation Laboratory Soft X-ray Spectroscopy of Surfaces and Reactions 3:30-3:45 Break Chair:

  17. TEC Communications Topic Group

    Office of Environmental Management (EM)

    procurement - Routing criteriaemergency preparedness Tribal Issues Topic Group * TEPP Navajo Nation (Tom Clawson) - 1404 - Needs Assessment * Identified strengths and...

  18. Plasma Assisted Catalysis System for NOx Reduction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasma Assisted Catalysis System for NOx Reduction Plasma Assisted Catalysis System for NOx Reduction 2002 DEER Conference Presentation: Noxtech, Inc. 2002_deer_slone.pdf (595.6 KB) More Documents & Publications Noxtechs PAC System Development and Demonstration Lean NOx Catalysis Research and Development

  19. TEC Communications Topic Group

    Office of Environmental Management (EM)

    Tribal Issues Topic Group Judith Holm, Chair April 21, 2004 Albuquerque, NM Tribal Issues Topic Group * February Tribal Summit with Secretary of Energy (Kristen Ellis, CI) - Held in conjunction with NCAI mid-year conference - First Summit held in response to DOE Indian Policy - Addressed barriers to communication and developing framework for interaction Tribal Issues Topic Group * Summit (continued) - Federal Register Notice published in March soliciting input on how to improve summit process

  20. UNIRIB: Physics Topics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics Research Capitalizing on the strengths of nine collaborating research ... Ion Beam (UNIRIB) consortium is conducting research at the forefront of nuclear physics. ...

  1. Nanoscale Advances in Catalysis and Energy Applications

    SciTech Connect (OSTI)

    Li, Yimin; Somorjai, Gabor A.

    2010-05-12

    In this perspective, we present an overview of nanoscience applications in catalysis, energy conversion, and energy conservation technologies. We discuss how novel physical and chemical properties of nanomaterials can be applied and engineered to meet the advanced material requirements in the new generation of chemical and energy conversion devices. We highlight some of the latest advances in these nanotechnologies and provide an outlook at the major challenges for further developments.

  2. USD Catalysis Group for Alternative Energy

    SciTech Connect (OSTI)

    Hoefelmeyer, James D.; Koodali, Ranjit; Sereda, Grigoriy; Engebretson, Dan; Fong, Hao; Puszynski, Jan; Shende, Rajesh; Ahrenkiel, Phil

    2012-03-13

    The South Dakota Catalysis Group (SDCG) is a collaborative project with mission to develop advanced catalysts for energy conversion with two primary goals: (1) develop photocatalytic systems in which polyfunctionalized TiO2 are the basis for hydrogen/oxygen synthesis from water and sunlight (solar fuels group), (2) develop new materials for hydrogen utilization in fuel cells (fuel cell group). In tandem, these technologies complete a closed chemical cycle with zero emissions.

  3. CNEEC - TRG3: Nanoscale Control in Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRG3: Nanoscale control in catalysis TRG3 Leader: Thomas F. Jaramillo Participating CNEEC PI’s: Stacey Bent, Bruce Clemens, Arthur Grossman, Thomas F. Jaramillo, Jens Nørskov, Friedrich Prinz, Jennifer Wilcox The grand challenge in TRG3 is the manipulation of catalyst materials at the nanoscale to significantly improve activity and selectivity for energy conversion reactions. A number of promising renewable energy technologies such as fuel cells and solar fuel reactors depend upon the

  4. Heterogeneous Catalysis for Thermochemical Conversion | Bioenergy | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heterogeneous Catalysis for Thermochemical Conversion Our mission is to transform thermal biomass deconstruction products (syngas and pyrolysis oil) into the fuels and chemicals that keep society moving forward. Illustration of a stacked series of red and grey spheres in a square shape, where red spheres represent oxygen and grey spheres represent titanium) with a stack of orange and small white spheres, where orange spheres represent platinum and white spheres represent hydrogen, in a square

  5. Catalysis Science | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis Science Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs Reports and Activities Science Highlights Principal Investigators' Meetings BES Home Research Areas Catalysis Science Print Text Size: A A A FeedbackShare Page Notice: NOVEMBER 16, 2015 is the Catalysis Science target date for submission of proposals to be considered for funding within fiscal year 2016. Proposals

  6. Shining Light on Catalysis | Stanford Synchrotron Radiation Lightsource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shining Light on Catalysis Tuesday, July 19, 2011 - 4:38pm SSRL Conference Room 137-322 Jeroen A. van Bokhoven, Professor for Heterogeneous Catalysis Institute for Chemical and Bioengineering ETH Zurich Head of Laboratory for Catalysis and Sustainable Chemistry (LSK) Swiss Light Source Paul Scherrer Institute Understanding a functioning catalyst requires understanding at the atomic scales in a time-resolved manner. X-rays can be readily used to accomplish that task, because of the large

  7. Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bioproducts | Department of Energy Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts The Bioenergy Technologies Office works with industry to develop pathways that use heat, pressure, and catalysis to convert domestic, non-food biomass into gasoline, jet fuel, and other products. thermochemical_four_pager.pdf (4.64 MB) More Documents & Publications 2013 Peer Review

  8. Catalysis Working Group Meeting: January 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    January 2015 Catalysis Working Group Meeting: January 2015 The Catalysis Working Group held a meeting on January 21, 2015, in Los Alamos, New Mexico. Meeting Agenda and Presentations Catalysis Working Group January 2015 Meeting Agenda (22.89 KB) Electrocatalysts with Ultra-Low PGM Loadings-Vojislav Stamenkovic, Argonne National Laboratory (15.95 MB) Improving Stability and Activity of Pt Monolayer in Non-Pt Core-Shell Electrocatalysts-Radoslav Adzic, Brookhaven National Laboratory (3.33 MB)

  9. Catalysis Working Group Meeting: June 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Catalysis Working Group Meeting: June 2015 The Catalysis Working Group held a meeting on June 8, 2015, in Arlington, Virginia, in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting. Meeting Agenda and Presentations Catalysis Working Group June 2015 Meeting Agenda (97.68 KB) Non-PGM Catalyst Targets: Summary-Piotr Zelenay, Los Alamos National Laboratory (657.07 KB) Alternative Metal Oxide Supports for Cathode Catalyst Powder in Automotive

  10. Catalysis Working Group Meeting: May 2013 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting: May 2013 Catalysis Working Group Meeting: May 2013 The Catalysis Working Group held a meeting on May 15, 2013, in Arlington, Virginia, in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting. Agenda Catalysis Working Group Meeting Agenda Presentations Electrocatalysts for Automotive Fuel Cells: Status and Challenges, Nilesh Dale, Nissan Technical Center North America Challenges for PEMFC Catalysts in Automotive Applications, Stephen

  11. Presentation: QER Energy Topics

    Office of Energy Efficiency and Renewable Energy (EERE)

    A briefing to the Secretary's Energy Advisory Board on QER Energy Topics (Energy Flows, Water Flows, and Program for Climate Model Diagnosis and Intercomparison) prepared by: A.J. Simon, Lawrence Livermore National Laboratory

  12. Visualizing Group II Intron Catalysis through the Stages of Splicing...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Visualizing Group II Intron Catalysis through the Stages of Splicing Citation Details In-Document Search Title: Visualizing Group II ...

  13. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme...

  14. Catalysis by Design: Bridging the Gap between Theory and Experiments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    between Theory and Experiments Catalysis by Design: Bridging the Gap between Theory and Experiments Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research ...

  15. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Broader source: Energy.gov (indexed) [DOE]

    Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Vehicle Technologies Office Merit Review 2016: Metal Oxide Nano-Array Catalysts for Low ...

  16. Control Heterogeneous Catalysis at Atomic and Electronic-level...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control Heterogeneous Catalysis at Atomic and Electronic-level Using Intermetallic Compounds Precious metals and metal alloys are important heterogeneous catalysts for renewable...

  17. Catalysis by Design: Bridging the Gap Between Theory and Experiments...

    Broader source: Energy.gov (indexed) [DOE]

    Catalysis by Design: Bridging the Gap between Theory and Experiments Catalyst by Design - Theoretical, Nanostructural, and Experimental Studies of Oxidation Catalyst for Diesel ...

  18. Computational catalyst screening: Scaling, bond-order and catalysis...

    Office of Scientific and Technical Information (OSTI)

    Computational catalyst screening: Scaling, bond-order and catalysis This content will become publicly available on December 29, 2017 Prev Next Title: Computational catalyst ...

  19. Materials Design and Discovery: Catalysis and Energy Storage...

    Office of Scientific and Technical Information (OSTI)

    Materials Design and Discovery: Catalysis and Energy Storage (Mira Early Science Program Final Technical Report): ALCF-2 Early Science Program Technical Report Citation Details ...

  20. University of Delaware | Catalysis Center for Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modeling Activity map produced from the new high-throughput computational engine. Example for ethylene glycol catalysis. Reforming, hydrodeoxygenation, dehydrogenation, and ...

  1. ARM - Topic List

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TeachersTopic List Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Topic List Atmosphere Atmospheric Heat Budget Atmospheric Pressure Composition of the Atmosphere Evolution of the Atmosphere Mesosphere Stratosphere Thermosphere Troposphere Oceans Oceans Sea Surface and Sea Level Weather and

  2. Lean NOx Catalysis Research and Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Catalysis Research and Development Lean NOx Catalysis Research and Development 2003 DEER Conference Presentation: Caterpillar, Inc. 2003_deer_park.pdf (588.44 KB) More Documents & Publications Lean-NOx Catalyst Development for Diesel Engine Applications Fuel Effects on Emissions Control Technologies

  3. Topical Committee | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topical Committee Topical Committee In the interest of optimum technology transfer, the DOE Technical Standards Program (TSP) has set up a network of topical committees. These committees provide a forum for communication across the DOE complex on technical standards related activities. If you would like information about a specific topical committee, or wish to join one of the groups, we've provided a roster of TSP Topical Committees and corresponding Topical Committee Chairpersons. Expectations

  4. Focus Group Meeting (Topical Meeting)

    Office of Energy Efficiency and Renewable Energy (EERE)

    Topical Meeting - Training Meeting agenda, summary and information package Meeting Date: April 30, 2008

  5. Featured Topic Pages

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Featured Topic Pages * Renowned scientists, with information about the scientists' R&D results * Significant DOE research disciplines, with R&D results * Manhattan Project, including scientists and key events Laureates * Nobel Prize winners associated with DOE and predecessor agencies * Winners of the Enrico Fermi Award, a U.S. Presidential award Database * Selected documents about noteworthy R&D results * Documents and individual pages searchable by word or phrase * Tag cloud

  6. Manufacturing Innovation Topics Workshop

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Advanced Manufacturing Office (AMO) and the Office of the Secretary of Defense Manufacturing Technology Program (OSD ManTech) will host a workshop to discuss AMO's recent Request for Information (RFI) on Clean Energy Manufacturing Topic Areas as well as the recent areas of interest announced by OSD ManTech for a new Manufacturing Innovation Institute on October 8-9, 2014 in Fort Worth, TX.

  7. Catalysis Working Group Meeting: June 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Catalysis Working Group Meeting: June 2014 The Catalysis Working Group held a meeting on June 16, 2014, in Washington, D.C., in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting. Meeting Agenda and Presentations Catalysis Working Group June 2014 Meeting Agenda (100.38 KB) Are We There Yet? Pt-Alloy Catalysts-Anu Kongkanand, GM (1.05 MB) Pt-Co/C Catalysts: PEMFC Performance and Durability-Jim Waldecker, Ford (2.3 MB) Successes and

  8. Catalysis Working Group Kick-Off Meeting Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Arlington, VA - May 14, 2012 Catalysis Working Group Kick-off Meeting Co-Chairs: Piotr Zelenay Los Alamos National Laboratory Nancy L. Garland U.S. Department of Energy 2 2...

  9. Catalysis Center for Energy Innovation: University of Delaware

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MAT'LS TRANSFER FORM In The Spotlight Tweets by @CCEIUD Fueling the Quest for Green Energy August 24, 2016 -- Watch an introduction to the University of Delaware's Catalysis ...

  10. TEC Working Group Topic Groups Archives Consolidated Grant Topic Group |

    Office of Environmental Management (EM)

    Department of Energy Consolidated Grant Topic Group TEC Working Group Topic Groups Archives Consolidated Grant Topic Group The Consolidated Grant Topic Group arose from recommendations provided by the TEC and other external parties to the DOE Senior Executive Transportation Forum in July 1998. It was proposed that the consolidation of multiple funding streams from numerous DOE sources into a single grant would provide a more equitable and efficient means of assistance to States and Tribes

  11. Invariant distributions on compact homogeneous spaces

    SciTech Connect (OSTI)

    Gorbatsevich, V V

    2013-12-31

    In this paper, we study distributions on compact homogeneous spaces, including invariant distributions and also distributions admitting asub-Riemannian structure. We first consider distributions of dimension 1 and 2 on compact homogeneous spaces. After this, we study the cases of compact homogeneous spaces of dimension 2, 3, and 4 in detail. Invariant distributions on simply connected compact homogeneous spaces are also treated. Bibliography: 18 titles.

  12. Coherence delay augmented laser beam homogenizer

    DOE Patents [OSTI]

    Rasmussen, Paul; Bernhardt, Anthony

    1993-01-01

    The geometrical restrictions on a laser beam homogenizer are relaxed by ug a coherence delay line to separate a coherent input beam into several components each having a path length difference equal to a multiple of the coherence length with respect to the other components. The components recombine incoherently at the output of the homogenizer, and the resultant beam has a more uniform spatial intensity suitable for microlithography and laser pantogography. Also disclosed is a variable aperture homogenizer, and a liquid filled homogenizer.

  13. Coherence delay augmented laser beam homogenizer

    DOE Patents [OSTI]

    Rasmussen, P.; Bernhardt, A.

    1993-06-29

    The geometrical restrictions on a laser beam homogenizer are relaxed by ug a coherence delay line to separate a coherent input beam into several components each having a path length difference equal to a multiple of the coherence length with respect to the other components. The components recombine incoherently at the output of the homogenizer, and the resultant beam has a more uniform spatial intensity suitable for microlithography and laser pantogography. Also disclosed is a variable aperture homogenizer, and a liquid filled homogenizer.

  14. Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC) | U.S.

    Office of Science (SC) Website

    DOE Office of Science (SC) Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC) Print Text Size: A A A FeedbackShare Page IMASC Header Director Cynthia Friend Lead Institution Harvard University Year Established 2014 Mission To drive

  15. Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Make Fuels and Chemicals | Department of Energy Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals BETO works with the emerging U.S. bioindustry to sustainably convert non-food biomass resources into cost-competitive biofuels, biopower, and bioproducts. biochemical_four_pager.pdf (2.61 MB) More Documents & Publications Replacing the Whole

  16. Theoretical Study on Catalysis by Protein Enzymes and Ribozyme

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theoretical Study on Catalysis by Protein Enzymes and Ribozyme Theoretical Study on Catalysis by Protein Enzymes and Ribozyme 2000 NERSC Annual Report 17shkarplus.jpg The energetics were determined for three mechanisms proposed for TIM catalyzed reactions. Results from reaction path calculations suggest that the two mechanisms that involve an enediol intermediate are likely to occur, while the direct intra-substrate proton transfer mechanism (in green) is energetically unfavorable due to the

  17. Temperature Transient Effects in Plasma-Catalysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Temperature Transient Effects in Plasma-Catalysis Temperature Transient Effects in Plasma-Catalysis 2002 DEER Conference Presentation: Ford Motor Company 2002_deer_hoard.pdf (481.22 KB) More Documents & Publications Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction A Parametric Study of the Effect of Temperature and Hydrocarbon Species on the Product Distribution from a Non-Thermal Plasma Reactor Development of NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup Truck

  18. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis ALS X-Rays Shine a New Light on Catalysis Print Thursday, 21 May 2015 11:16 Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab

  19. Dedicated Beamline Facilities for Catalytic Research. Synchrotron Catalysis Consortium (SCC)

    SciTech Connect (OSTI)

    Chen, Jingguang; Frenkel, Anatoly; Rodriguez, Jose; Adzic, Radoslav; Bare, Simon R.; Hulbert, Steve L.; Karim, Ayman; Mullins, David R.; Overbury, Steve

    2015-03-04

    Synchrotron spectroscopies offer unique advantages over conventional techniques, including higher detection sensitivity and molecular specificity, faster detection rate, and more in-depth information regarding the structural, electronic and catalytic properties under in-situ reaction conditions. Despite these advantages, synchrotron techniques are often underutilized or unexplored by the catalysis community due to various perceived and real barriers, which will be addressed in the current proposal. Since its establishment in 2005, the Synchrotron Catalysis Consortium (SCC) has coordinated significant efforts to promote the utilization of cutting-edge catalytic research under in-situ conditions. The purpose of the current renewal proposal is aimed to provide assistance, and to develop new sciences/techniques, for the catalysis community through the following concerted efforts: Coordinating the implementation of a suite of beamlines for catalysis studies at the new NSLS-II synchrotron source; Providing assistance and coordination for catalysis users at an SSRL catalysis beamline during the initial period of NSLS to NSLS II transition; Designing in-situ reactors for a variety of catalytic and electrocatalytic studies; Assisting experimental set-up and data analysis by a dedicated research scientist; Offering training courses and help sessions by the PIs and co-PIs.

  20. TECHNICAL STANDARDS PROGRAM TOPICAL COMMITTEES

    Broader source: Energy.gov [DOE]

    PurposeThis procedure describes how topical committees are organized and recognized under the Technical Standards Program. 

  1. Some General Themes in Catalysis at LANL

    SciTech Connect (OSTI)

    Gordon, John C.

    2012-07-19

    Some general themes in catalysis at LANL are: (1) Storage and release of energy within chemical bonds (e.g. H{sub 2} storage in and release from covalent bonds, N{sub 2} functionalization, CO{sub 2} functionalization, H{sub 2} oxidation/evolution, O{sub 2} reduction/evolution); (2) Can we control the chemistry of reactive substrates to effect energy relevant transformations in non-traditional media (e.g. can we promote C-C couplings, dehydrations, or hydrogenations in water under relatively mild conditions)? (3) Can we supplant precious metal or rare earth catalysts to effect these transformations, by using earth abundant metals/elements instead? Can we use organocatalysis and circumvent the use of metals completely? (4) Can we improve upon existing rare earth catalyst systems (e.g. in rare earth oxides pertinent to fluid cracking or polymerization) and reduce amounts required for catalytic efficacy? Carbohydrates can be accessed from non-food based biomass sources such as woody residues and switchgrass. After extracted from the plant source, our goal is to upgrade these classes of molecules into useful fuels.

  2. One- and two-dimensional infrared spectroscopic studies of solution-phase homogeneous catalysis and spin-forbidden reactions

    SciTech Connect (OSTI)

    Sawyer, Karma Rae

    2008-12-12

    Understanding chemical reactions requires the knowledge of the elementary steps of breaking and making bonds, and often a variety of experimental techniques are needed to achieve this goal. The initial steps occur on the femto- through picosecond time-scales, requiring the use of ultrafast spectroscopic methods, while the rate-limiting steps often occur more slowly, requiring alternative techniques. Ultrafast one and two-dimensional infrared and step-scan FTIR spectroscopies are used to investigate the photochemical reactions of four organometallic complexes. The analysis leads to a detailed understanding of mechanisms that are general in nature and may be applicable to a variety of reactions.

  3. [Zeolite catalysis in conversion of cellulosics

    SciTech Connect (OSTI)

    Tsao, G.T.

    1992-12-31

    To transform biomass into fermentable substrate for yeast, we are using zeolites instead of enzymes to catalyze the two bottleneck reactions in biomass conversion, xylose isomerization and ceuobiose hydrolysis. The experimental results on these reactions carried out over various zeolites and other catalysts are presented herein. The advantages and disadvantages of using these catalysts over enzymes are also discussed. Heterogeneous solid catalysts other than zeolites has been employed for cellobiose-to-glucose hydrolysis. The size and shape selectivity that makes zeoutes unique for some reactions can add diffusional hindrance. We have spent some time screening various known solid acidic catalysts. We report that a class of cationic ion exchange resins in the acidified form (e.g. Amberlite) has worked well as an acidic catalyst in hydrolyzing cellobiose to glucose. Our experimental results, together with those obtained from a homogeneous acid catalyst (e.g. sulfuric acid) for comparison are provided. Having succeeded in finding an alternative solid acid catalyst for hydrolysis, we explored other solid resin or other homogeneous but non-enzyme catalyst to carry out the xylose-to-xylulose isomerization. A fairly extensive search has been made. We explored the use of sodium aluminates in the homogeneous phase isomerization of glucose to fructose and obtained a very high conversion of glucose to fructose with the final mixture containing 85% of fructose instead of the common 45%. Fructose apparently complexes with aluminates, and its equilibrium concentration is shifted to considerably higher values than permitted by simple glucose/fructose equilibrium. We have recently found a number of catalysts capable of promoting isomerization between aldoses and ketoses. One solid resin, known as polyvinyl pyridine (PVP), is able to convert xylose to xylulose at a pH below 7. Our usage of alternative isomerization catalysts, including PVP, are described.

  4. [Zeolite catalysis in conversion of cellulosics

    SciTech Connect (OSTI)

    Tsao, G.T.

    1992-01-01

    To transform biomass into fermentable substrate for yeast, we are using zeolites instead of enzymes to catalyze the two bottleneck reactions in biomass conversion, xylose isomerization and ceuobiose hydrolysis. The experimental results on these reactions carried out over various zeolites and other catalysts are presented herein. The advantages and disadvantages of using these catalysts over enzymes are also discussed. Heterogeneous solid catalysts other than zeolites has been employed for cellobiose-to-glucose hydrolysis. The size and shape selectivity that makes zeoutes unique for some reactions can add diffusional hindrance. We have spent some time screening various known solid acidic catalysts. We report that a class of cationic ion exchange resins in the acidified form (e.g. Amberlite) has worked well as an acidic catalyst in hydrolyzing cellobiose to glucose. Our experimental results, together with those obtained from a homogeneous acid catalyst (e.g. sulfuric acid) for comparison are provided. Having succeeded in finding an alternative solid acid catalyst for hydrolysis, we explored other solid resin or other homogeneous but non-enzyme catalyst to carry out the xylose-to-xylulose isomerization. A fairly extensive search has been made. We explored the use of sodium aluminates in the homogeneous phase isomerization of glucose to fructose and obtained a very high conversion of glucose to fructose with the final mixture containing 85% of fructose instead of the common 45%. Fructose apparently complexes with aluminates, and its equilibrium concentration is shifted to considerably higher values than permitted by simple glucose/fructose equilibrium. We have recently found a number of catalysts capable of promoting isomerization between aldoses and ketoses. One solid resin, known as polyvinyl pyridine (PVP), is able to convert xylose to xylulose at a pH below 7. Our usage of alternative isomerization catalysts, including PVP, are described.

  5. AQUEOUS HOMOGENEOUS REACTORTECHNICAL PANEL REPORT

    SciTech Connect (OSTI)

    Diamond, D.J.; Bajorek, S.; Bakel, A.; Flanagan, G.; Mubayi, V.; Skarda, R.; Staudenmeier, J.; Taiwo, T.; Tonoike, K.; Tripp, C.; Wei, T.; Yarsky, P.

    2010-12-03

    Considerable interest has been expressed for developing a stable U.S. production capacity for medical isotopes and particularly for molybdenum- 99 (99Mo). This is motivated by recent re-ductions in production and supply worldwide. Consistent with U.S. nonproliferation objectives, any new production capability should not use highly enriched uranium fuel or targets. Conse-quently, Aqueous Homogeneous Reactors (AHRs) are under consideration for potential 99Mo production using low-enriched uranium. Although the Nuclear Regulatory Commission (NRC) has guidance to facilitate the licensing process for non-power reactors, that guidance is focused on reactors with fixed, solid fuel and hence, not applicable to an AHR. A panel was convened to study the technical issues associated with normal operation and potential transients and accidents of an AHR that might be designed for isotope production. The panel has produced the requisite AHR licensing guidance for three chapters that exist now for non-power reactor licensing: Reac-tor Description, Reactor Coolant Systems, and Accident Analysis. The guidance is in two parts for each chapter: 1) standard format and content a licensee would use and 2) the standard review plan the NRC staff would use. This guidance takes into account the unique features of an AHR such as the fuel being in solution; the fission product barriers being the vessel and attached systems; the production and release of radiolytic and fission product gases and their impact on operations and their control by a gas management system; and the movement of fuel into and out of the reactor vessel.

  6. Homogeneous catalysts in hypersonic combustion

    SciTech Connect (OSTI)

    Harradine, D.M.; Lyman, J.L.; Oldenborg, R.C.; Pack, R.T.; Schott, G.L.

    1989-01-01

    Density and residence time both become unfavorably small for efficient combustion of hydrogen fuel in ramjet propulsion in air at high altitude and hypersonic speed. Raising the density and increasing the transit time of the air through the engine necessitates stronger contraction of the air flow area. This enhances the kinetic and thermodynamic tendency of H/sub 2/O to form completely, accompanied only by N/sub 2/ and any excess H/sub 2/(or O/sub 2/). The by-products to be avoided are the energetically expensive fragment species H and/or O atoms and OH radicals, and residual (2H/sub 2/ plus O/sub 2/). However, excessive area contraction raises air temperature and consequent combustion-product temperature by adiabatic compression. This counteracts and ultimately overwhelms the thermodynamic benefit by which higher density favors the triatomic product, H/sub 2/O, over its monatomic and diatomic alternatives. For static pressures in the neighborhood of 1 atm, static temperature must be kept or brought below ca. 2400 K for acceptable stability of H/sub 2/O. Another measure, whose requisite chemistry we address here, is to extract propulsive work from the combustion products early in the expansion. The objective is to lower the static temperature of the combustion stream enough for H/sub 2/O to become adequately stable before the exhaust flow is massively expanded and its composition ''frozen.'' We proceed to address this mechanism and its kinetics, and then examine prospects for enhancing its rate by homogeneous catalysts. 9 refs.

  7. Homogeneously dispersed, multimetal oxygen-evolving catalysts...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Homogeneously dispersed, multimetal oxygen-evolving catalysts Citation ... Publication Date: 2016-03-24 OSTI Identifier: 1245398 Report ...

  8. Innovative Topics for Advanced Biofuels

    Broader source: Energy.gov (indexed) [DOE]

    Innovative Topics for Advanced Biofuels Jonathan Male, Ph.D. PNNL Report-Out Webinar ... into biomass sugars to feed advanced biofuels Separations - Compatibility with ...

  9. Special Topics and Data Reports

    U.S. Energy Information Administration (EIA) Indexed Site

    (HTML format) Yellow Arrow Energy Consumption and Expenditures (HTML format) adobe logo Download Acrobat Reader for viewing PDF files. Special Topics and Data Reports...

  10. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control 2002deeraardahl.pdf (7.98 ...

  11. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control 2002_deer_aardahl.pdf (7.98 MB) More Documents & Publications Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Selective reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies

  12. Catalysis Working Group Kick-Off Meeting Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis Working Group Kick-Off Meeting Agenda Catalysis Working Group Kick-Off Meeting Agenda Agenda for the kick-off meeting of the U.S. Department of Energy Fuel Cell Technologies Program's Catalysis Working Group, held May 14, 2012, in Arlington, Virginia. 1_cwg_may2012_agenda.pdf (34.13 KB) More Documents & Publications Operando Raman and Theoretical Vibration Spectroscopy of Non-PGM Catalysts 2013 DOE Catalysis Working Group Meeting Agenda Advanced Cathode Catalysts

  13. Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and SCR | Department of Energy Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_atkinson.pdf (327.1 KB) More Documents & Publications Reductant Utilization in a LNT + SCR System Lean NOx Trap

  14. Homogeneous fluorescence linewidths for amorphous hosts

    SciTech Connect (OSTI)

    Lyo, S.K.; Orbach, R.

    1980-11-01

    A contribution to the homogeneous linewidth of optical transitions in amorphous hosts is calculated. The microscopic process is diagonal in the phonon interaction with two level systems (TLS) common to amorphous materials, and diagonal in the coupling between TLS and the optical center. The model predicts an optical homogeneous linewidth proportional to the square of the temperature at low temperature.

  15. Events & Topics | Metrolink Tour | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics | Metrolink Tour Events & Topics | Metrolink Tour

  16. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E; Storey, John Morse; Theiss, Timothy J; Ponnusamy, Senthil; Ferguson, Harley Douglas; Williams, Aaron M; Tassitano, James B

    2007-09-01

    efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial

  17. Low temperature, sulfur tolerant homogeneous catalysts for the water-gas shift reaction

    SciTech Connect (OSTI)

    Laine, R.M.

    1986-01-20

    The purpose of this report is to update and reorganize our recent review on homogeneous catalysis of the water-gas shift reaction (WGSR) based on recent literature publications and patents. This updated version will serve as a means of selecting 10 candidate catalyst systems for use in developing effective, sulfur-tolerant, low temperature WGSR catalysts. This report discusses the variations possible in the basic chemistry associated with WGSR catalytic cycles, including basic, acidic, and neutral conditions. Then individual mechanism for specific WGSR catalyst systems are discussed. Finally, on the basis of the literature reports, a list is presented of candidate catalysts and basic systems we have chosen for study in Task 3.

  18. Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2

    SciTech Connect (OSTI)

    Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.; Dobbek, Holger; DuBois, Daniel L.; Dupuis, Michel; Ferry, James G.; Fujita, Etsuko; Hille, Russ; Kenis, Paul; Kerfeld, Cheryl A.; Morris, Robert H.; Peden, Charles HF; Portis, Archie; Ragsdale, Steve; Rauchfuss, Thomas B.; Reek, Joost; Seefeldt, Lance C.; Thauer, Rudolf K.; Waldrop, Grover L.

    2013-08-14

    Our central premise is that catalytic scientists can learn by studying how these important metabolic processes occur in nature. Complementarily, biochemists can learn by studying how catalytic scientists view these same chemical transformations promoted by synthetic catalysts. From these studies, hypotheses can be developed and tested through manipulation of enzyme structure and by synthesizing simple molecular catalysts to incorporate different structural features of the enzymes. It is hoped that these studies will lead to new and useful concepts in catalyst design for fuel production and utilization. This paper describes the results of a workshop held to explore these concepts in regard to the development of new and more efficient catalytic processes for the conversion of CO2 to a variety of carbon-based fuels. The organization of this overview/review is as follows: 1) The first section briefly explores how interactions between the catalysis and biological communities have been fruitful in developing new catalysts for the reduction of protons to hydrogen, the simplest fuel generation reaction. 2) The second section assesses the state of the art in both biological and chemical reduction of CO2 by two electrons to form either carbon monoxide (CO) or formate (HCOO-). It also attempts to identify common principles between biological and synthetic catalysts and productive areas for future research. 3) The third section explores both biological and chemical processes that result in the reduction of CO2 beyond the level of CO and formate, again seeking to identify common principles and productive areas of future research. 4) The fourth section explores the formation of carbon-carbon bonds in biological and chemical systems in the same vein as the other sections. 5) A fifth section addresses the role of non-redox reactions of CO2 in biological systems and their role in carbon metabolism, with a parallel discussion of chemical systems. 6) In section 6, the topics of

  19. Methanol Synthesis over Cu/ZnO/Al2O3: The Active Site in Industrial Catalysis

    SciTech Connect (OSTI)

    Behrens, Malte

    2012-03-28

    Unlike homogeneous catalysts, heterogeneous catalysts that have been optimized through decades are typically so complex and hard to characterize that the nature of the catalytically active site is not known. This is one of the main stumbling blocks in developing rational catalyst design strategies in heterogeneous catalysis. We show here how to identify the crucial atomic structure motif for the industrial Cu/ZnO/Al{sub 2}O{sub 3} methanol synthesis catalyst. Using a combination of experimental evidence from bulk-, surface-sensitive and imaging methods collected on real high-performance catalytic systems in combination with DFT calculations. We show that the active site consists of Cu steps peppered with Zn atoms, all stabilized by a series of well defined bulk defects and surface species that need jointly to be present for the system to work.

  20. Molecular-Level Design of Heterogeneous Chiral Catalysis

    SciTech Connect (OSTI)

    Francisco Zaera

    2012-03-21

    The following is a proposal to continue our multi-institutional research on heterogeneous chiral catalysis. Our team combines the use of surface-sensitive analytical techniques for the characterization of model systems with quantum and statistical mechanical calculations to interpret experimental data and guide the design of future research. Our investigation focuses on the interrelation among the three main mechanisms by which enantioselectivity can be bestowed to heterogeneous catalysts, namely: (1) by templating chirality via the adsorption of chiral supramolecular assemblies, (2) by using chiral modifiers capable of forming chiral complexes with the reactant and force enantioselective surface reactions, and (3) by forming naturally chiral surfaces using imprinting chiral agents. Individually, the members of our team are leaders in these various aspects of chiral catalysis, but the present program provides the vehicle to generate and exploit the synergies necessary to address the problem in a comprehensive manner. Our initial work has advanced the methodology needed for these studies, including an enantioselective titration procedure to identify surface chiral sites, infrared spectroscopy in situ at the interface between gases or liquids and solids to mimic realistic catalytic conditions, and DFT and Monte Carlo algorithms to simulate and understand chirality on surfaces. The next step, to be funded by the monies requested in this proposal, is to apply those methods to specific problems in chiral catalysis, including the identification of the requirements for the formation of supramolecular surface structures with enantioselective behavior, the search for better molecules to probe the chiral nature of the modified surfaces, the exploration of the transition from supramolecular to one-to-one chiral modification, the correlation of the adsorption characteristics of one-to-one chiral modifiers with their physical properties, in particular with their configuration

  1. Recent advances of lanthanum-based perovskite oxides for catalysis

    SciTech Connect (OSTI)

    Zhu, Huiyuan; Zhang, Pengfei; Dai, Sheng

    2015-09-21

    There is a need to reduce the use of noble metal elements especially in the field of catalysis, where noble metals are ubiquitously applied. To this end, perovskite oxides, an important class of mixed oxide, have been attracting increasing attention for decades as potential replacements. Benefiting from the extraordinary tunability of their compositions and structures, perovskite oxides can be rationally tailored and equipped with targeted physical and chemical properties e.g. redox behavior, oxygen mobility, and ion conductivity for enhanced catalysis. Recently, the development of highly efficient perovskite oxide catalysts has been extensively studied. This review article summarizes the recent development of lanthanum-based perovskite oxides as advanced catalysts for both energy conversion applications and traditional heterogeneous reactions.

  2. Recent advances of lanthanum-based perovskite oxides for catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Huiyuan; Zhang, Pengfei; Dai, Sheng

    2015-09-21

    There is a need to reduce the use of noble metal elements especially in the field of catalysis, where noble metals are ubiquitously applied. To this end, perovskite oxides, an important class of mixed oxide, have been attracting increasing attention for decades as potential replacements. Benefiting from the extraordinary tunability of their compositions and structures, perovskite oxides can be rationally tailored and equipped with targeted physical and chemical properties e.g. redox behavior, oxygen mobility, and ion conductivity for enhanced catalysis. Recently, the development of highly efficient perovskite oxide catalysts has been extensively studied. This review article summarizes the recent developmentmore » of lanthanum-based perovskite oxides as advanced catalysts for both energy conversion applications and traditional heterogeneous reactions.« less

  3. Advanced Electronic Structure Methods for Heterogeneous Catalysis and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Separation of Heavy Metals | Argonne Leadership Computing Facility The research team is also using GAMESS in an INCITE project entitled State-of-the-Art Simulations of Liquid Phenomena. As part of the INCITE work, they predicted that the turning point between surface and interior solvation in a nitrate ion occurs at a cluster size of around 64 water molecules. Spencer Pruitt, Argonne National Laboratory Advanced Electronic Structure Methods for Heterogeneous Catalysis and Separation of Heavy

  4. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  5. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  6. Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Iron Catalysis in Oxidations by Ozone Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Ozone is used commercially for treatment of potable and non-potable water, and as an industrial oxidant. ISU and Ames Laboratory researchers have developed a method for using iron in ozone oxidation that significantly improves the speed of oxidation reactions. Description Ozone is recognized as potent and effective oxidizing agent, and has a

  7. Catalysis by Design: Bridging the Gap between Theory and Experiments |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy between Theory and Experiments Catalysis by Design: Bridging the Gap between Theory and Experiments Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). deer07_narula.pdf (372.33 KB) More Documents & Publications Catalysts via First Principles Catalysts via First

  8. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  9. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  10. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  11. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  12. Missouri Botanical Gardens Tour | Events & Topics | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Events & Topics Missouri Botanical Gardens Tour | Events & Topics PARC welcomed community members for our guided tour of the Missouri Botanical Garden. http:...

  13. Events & Topics In Bioenergy | Photosynthetic Antenna Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics In Bioenergy Events & Topics In Bioenergy Dr. Chenyang Lu Smart Building with Wireless Sensor Networks Dr. Joseph Cullen "Measuring the Environmental Benefits of ...

  14. Distribution of Radiation Density in a Homogeneous Cloudy Laye

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Radiation Density in a Homogeneous Cloudy Layer S. V. Dvoryashin, K. A. Shukorov, A. H. ... method) allowing calculating radiation density in homogeneous and non-uniform ...

  15. Assessment of Homogeneous Thorium/Uranium Fuel for Pressurized...

    Office of Scientific and Technical Information (OSTI)

    Fuel for Pressurized Water Reactors Citation Details In-Document Search Title: Assessment of Homogeneous ThoriumUranium Fuel for Pressurized Water Reactors The homogeneous ...

  16. Anomalous Behavior of the Homogeneous Ice Nucleation Rate in...

    Office of Scientific and Technical Information (OSTI)

    Published Article: Anomalous Behavior of the Homogeneous Ice Nucleation Rate in "No-Man's Land" Prev Next Title: Anomalous Behavior of the Homogeneous Ice Nucleation Rate in ...

  17. EERE Success Story-Fundamental Studies in Catalysis Enabled the use of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficient "Lean-Burn" Engines for Vehicle Transportation | Department of Energy Fundamental Studies in Catalysis Enabled the use of Efficient "Lean-Burn" Engines for Vehicle Transportation EERE Success Story-Fundamental Studies in Catalysis Enabled the use of Efficient "Lean-Burn" Engines for Vehicle Transportation May 7, 2015 - 1:29pm Addthis Building on a catalysis research program sponsored by EERE's Vehicles Technology Office (VTO) and DOE's Office of

  18. Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites...

    Office of Scientific and Technical Information (OSTI)

    low temperature oxygen electro catalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and Metal-air batteries. ...

  19. Topic A Note: Includes STEPS Subtopic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic A Note: Includes STEPS Subtopic 33 Total Projects Developing and Enhancing Workforce Training Programs

  20. A numerical homogenization method for heterogeneous, anisotropic elastic media based on multiscale theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gao, Kai; Chung, Eric T.; Gibson, Richard L.; Fu, Shubin; Efendiev, Yalchin

    2015-06-05

    The development of reliable methods for upscaling fine scale models of elastic media has long been an important topic for rock physics and applied seismology. Several effective medium theories have been developed to provide elastic parameters for materials such as finely layered media or randomly oriented or aligned fractures. In such cases, the analytic solutions for upscaled properties can be used for accurate prediction of wave propagation. However, such theories cannot be applied directly to homogenize elastic media with more complex, arbitrary spatial heterogeneity. We therefore propose a numerical homogenization algorithm based on multiscale finite element methods for simulating elasticmore » wave propagation in heterogeneous, anisotropic elastic media. Specifically, our method used multiscale basis functions obtained from a local linear elasticity problem with appropriately defined boundary conditions. Homogenized, effective medium parameters were then computed using these basis functions, and the approach applied a numerical discretization that is similar to the rotated staggered-grid finite difference scheme. Comparisons of the results from our method and from conventional, analytical approaches for finely layered media showed that the homogenization reliably estimated elastic parameters for this simple geometry. Additional tests examined anisotropic models with arbitrary spatial heterogeneity where the average size of the heterogeneities ranged from several centimeters to several meters, and the ratio between the dominant wavelength and the average size of the arbitrary heterogeneities ranged from 10 to 100. Comparisons to finite-difference simulations proved that the numerical homogenization was equally accurate for these complex cases.« less

  1. A numerical homogenization method for heterogeneous, anisotropic elastic media based on multiscale theory

    SciTech Connect (OSTI)

    Gao, Kai; Chung, Eric T.; Gibson, Richard L.; Fu, Shubin; Efendiev, Yalchin

    2015-06-05

    The development of reliable methods for upscaling fine scale models of elastic media has long been an important topic for rock physics and applied seismology. Several effective medium theories have been developed to provide elastic parameters for materials such as finely layered media or randomly oriented or aligned fractures. In such cases, the analytic solutions for upscaled properties can be used for accurate prediction of wave propagation. However, such theories cannot be applied directly to homogenize elastic media with more complex, arbitrary spatial heterogeneity. We therefore propose a numerical homogenization algorithm based on multiscale finite element methods for simulating elastic wave propagation in heterogeneous, anisotropic elastic media. Specifically, our method used multiscale basis functions obtained from a local linear elasticity problem with appropriately defined boundary conditions. Homogenized, effective medium parameters were then computed using these basis functions, and the approach applied a numerical discretization that is similar to the rotated staggered-grid finite difference scheme. Comparisons of the results from our method and from conventional, analytical approaches for finely layered media showed that the homogenization reliably estimated elastic parameters for this simple geometry. Additional tests examined anisotropic models with arbitrary spatial heterogeneity where the average size of the heterogeneities ranged from several centimeters to several meters, and the ratio between the dominant wavelength and the average size of the arbitrary heterogeneities ranged from 10 to 100. Comparisons to finite-difference simulations proved that the numerical homogenization was equally accurate for these complex cases.

  2. Hot topics from the Tevatron

    SciTech Connect (OSTI)

    Glenzinski, D.; /Fermilab

    2008-01-01

    The Tevatron Run-II began in March 2001. To date, both the CDF and D0 experiments have collected 1 fb{sup -1} of data each. The results obtained from this data set were summarized at this conference in 39 parallel session presentations covering a wide range of topics. The author summarizes the most important of those results here and comments on some of the prospects for the future.

  3. 2012 LANSCE Topical User Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 LANSCE Topical User Meeting January 9-10, 2012 The Office of Defense Programs is developing a long-term strategy for the construction of new experimental science facilities supporting NNSA missions. The new facilities will provide the critical science and technology capabilities necessary to execute the 21 st century responsibilities of NNSA in executing its mission and in supporting the broader national security agenda. The call focuses on large facilities with costs exceeding $100M. The NNSA

  4. Hydrogen catalysis and scavenging action of Pd-POSS nanoparticles

    SciTech Connect (OSTI)

    Maiti, A; Gee, R H; Maxwell, R; Saab, A

    2007-02-01

    Prompted by the need for a self-supported, chemically stable, and functionally flexible catalytic nanoparticle system, we explore a system involving Pd clusters coated with a monolayer of polyhedral oligomeric silsesquioxane (POSS) cages. With an initial theoretical focus on hydrogen catalysis and sequestration in the Pd-POSS system, we report Density Functional Theory (DFT) results on POSS binding energies to the Pd(110) surface, hydrogen storing ability of POSS, and possible pathways of hydrogen radicals from the catalyst surface to unsaturated bonds away from the surface.

  5. Fuels and energy for the future: The role of catalysis

    SciTech Connect (OSTI)

    Rostrup-Nielsen, J.R.; Nielsen, R.

    2004-07-01

    There are many reasons to decrease the dependency on oil and to increase the use of other energy sources than fossil fuels. The wish for energy security is balanced by a wish for sustainable growth. Catalysis plays an important role in creating new routes and flexibility in the network of energy sources, energy carriers, and energy conversion. The process technologies resemble those applied in the large scale manufacture of commodities. This is illustrated by examples from refinery fuels, synfuels, and hydrogen and the future role of fossil fuels is discussed.

  6. USD Catalysis Group for Alternative Energy - Final report

    SciTech Connect (OSTI)

    Hoefelmeyer, James

    2014-10-03

    I. Project Summary Catalytic processes are a major technological underpinning of modern society, and are essential to the energy sector in the processing of chemical fuels from natural resources, fine chemicals synthesis, and energy conversion. Advances in catalyst technology are enormously valuable since these lead to reduced chemical waste, reduced energy loss, and reduced costs. New energy technologies, which are critical to future economic growth, are also heavily reliant on catalysts, including fuel cells and photo-electrochemical cells. Currently, the state of South Dakota is underdeveloped in terms of research infrastructure related to catalysis. If South Dakota intends to participate in significant economic growth opportunities that result from advances in catalyst technology, then this area of research needs to be made a high priority for investment. To this end, a focused research effort is proposed in which investigators from The University of South Dakota (USD) and The South Dakota School of Mines and Technology (SDSMT) will contribute to form the South Dakota Catalysis Group (SDCG). The multidisciplinary team of the (SDCG) include: (USD) Dan Engebretson, James Hoefelmeyer, Ranjit Koodali, and Grigoriy Sereda; (SDSMT) Phil Scott Ahrenkiel, Hao Fong, Jan Puszynski, Rajesh Shende, and Jacek Swiatkiewicz. The group is well suited to engage in a collaborative project due to the resources available within the existing programs. Activities within the SDCG will be monitored through an external committee consisting of three distinguished professors in chemistry. The committee will provide expert advice and recommendations to the SDCG. Advisory meetings in which committee members interact with South Dakota investigators will be accompanied by individual oral and poster presentations in a materials and catalysis symposium. The symposium will attract prominent scientists, and will enhance the visibility of research in the state of South Dakota. The SDCG requests

  7. Catalysis by Design - Theoretical and Experimental Studies of Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysts for Lean NOx Treatment | Department of Energy Design - Theoretical and Experimental Studies of Model Catalysts for Lean NOx Treatment Catalysis by Design - Theoretical and Experimental Studies of Model Catalysts for Lean NOx Treatment Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_narula.pdf (277.05 KB) More Documents & Publications Lean NOx Traps

  8. Charge Transfer and Catalysis at the Metal Support Interface

    SciTech Connect (OSTI)

    Baker, Lawrence Robert

    2012-07-31

    Kinetic, electronic, and spectroscopic characterization of model Pt–support systems are used to demonstrate the relationship between charge transfer and catalytic activity and selectivity. The results show that charge flow controls the activity and selectivity of supported metal catalysts. This dissertation builds on extensive existing knowledge of metal–support interactions in heterogeneous catalysis. The results show the prominent role of charge transfer at catalytic interfaces to determine catalytic activity and selectivity. Further, this research demonstrates the possibility of selectively driving catalytic chemistry by controlling charge flow and presents solid-state devices and doped supports as novel methods for obtaining electronic control over catalytic reaction kinetics.

  9. Final technical report, Symposium on New Theoretical Concepts and Directions in Catalysis

    SciTech Connect (OSTI)

    Metiu, Horia

    2014-08-22

    We organized in August 2013 a “Symposium on New Theoretical Concepts and Directions in Catalysis” with the participation of 20 invited distinguished quantum chemists and other researchers who use computations to study catalysis. Symposium website; http://catalysis.cnsi.ucsb.edu/

  10. WTP Communications Strategy Discussion Topics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Discussion Topics For discussion at the April 7, 2015 PIC meeting Issue Managers: Bob Suyama, Dave Bernhard, Melanie Myers-Magnuson, Dirk Dunning, Liz Mattson, Pam Larsen, Ken Niles Some potential questions and areas that the TWC/PIC need to discuss in order to develop a Communica- tions Strategy for the Waste Treatment Plant. These questions represent the data that the TWC/PIC might need in order to provide a plan that will be of value to the Tri-Party Agencies and the Public and Stakeholders.

  11. Surface Catalysis of Water Oxidation by the Blue Ruthenium Dimer

    SciTech Connect (OSTI)

    Jurss, Jonah W.; Concepcion, Javier C.; Norris, Michael R.; Templeton, Joseph L.; Meyer, Thomas J.

    2010-04-08

    Single-electron activation of multielectron catalysis has been shown to be viable in catalytic water oxidation with stepwise proton-coupled electron transfer, leading to high-energy catalytic precursors. For the blue dimer, cis,cis-[(bpy)2(H2O)RuIIIORuIII(H2O)(bpy)2]4+, the first well-defined molecular catalyst for water oxidation, stepwise 4e-/4H+ oxidation occurs to give the reactive precursor [(O)RuVORuV(O)]4+. This key intermediate is kinetically inaccessible at an unmodified metal oxide surface, where the only available redox pathway is electron transfer. We report here a remarkable surface activation of indium-tin oxide (In2O3:Sn) electrodes toward catalytic water oxidation by the blue dimer at electrodes derivatized by surface phosphonate binding of [Ru(4,4'-((HO)2P(O)CH2)2bpy)2(bpy)]2+. Surface binding dramatically improves the rate of surface oxidation of the blue dimer and induces water oxidation catalysis.

  12. TEC Working Group Topic Groups Routing

    Broader source: Energy.gov [DOE]

    The Routing Topic Group has been established to examine topics of interest and relevance concerning routing of shipments of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) to a...

  13. Energy & Manufacturing Workforce Training Topics List - Version...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Manufacturing Workforce Training Topics List - Version 1.7 (02.11.14) Energy & Manufacturing Workforce Training Topics List - Version 1.7 (02.11.14) View this searchable list of ...

  14. Framework Topic Briefing: Direct Feed LAW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    February 13, 2014 Framework Topic Briefing: Direct Feed LAW Next steps: Put Dick's handouts on SharePoint * Continue Framework topic briefing series Page 1 System Plan 7 Next ...

  15. Technical Assistance Topics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Assistance Topics Technical Assistance Topics Topics addressed are those of greatest interest to states, regions, and Tribes, including: Reliability, resiliency, and cyber security of electric power systems Electric resource planning, integrated resource planning, regional transmission planning, and resource acquisition strategies Ratepayer-funded energy efficiency, demand response, and smart grid programs Renewable energy development, including state renewable portfolio standards,

  16. Technical Assistance Topics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Policy Coordination and Implementation » Electricity Policy Technical Assistance Program » Technical Assistance Topics Technical Assistance Topics Topics addressed are those of greatest interest to states, regions, and Tribes, including: Reliability, resiliency, and cyber security of electric power systems Electric resource planning, integrated resource planning, regional transmission planning, and resource acquisition strategies Ratepayer-funded energy efficiency, demand response,

  17. Theoretical approach to heterogeneous catalysis using large finite crystals

    SciTech Connect (OSTI)

    Salem, L.

    1985-12-19

    A theoretical-approach is described for heterogeneous catalysis using large finite crystals and an exactly soluble model. First, reviews of some themes which are well-known to physicists but need a translation into chemical language: wave vectors, the tight-binding model, and energy bands. Next a description of the finite simple cubic crystal and its analytical wave functions and energies in the Hueckel scheme is given. Also the analytical Hueckel wave functions for a finite face-centered cubic (FCC) crystal cut along square, (100)-type faces is described. Then the calculation of the perturbation interaction energy between H/sub 2/ and large finite (simple cubic or FCC) crystals of Ni atoms, having up to 13,824 atoms is described. The interaction energy is shown to be independent of crystal size, whatever the position of attack of the H/sub 2/ molecule. 28 references, 9 figures, 8 tables.

  18. Catalysis Working Group Kick-Off Meeting: May 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kick-Off Meeting: May 2012 Catalysis Working Group Kick-Off Meeting: May 2012 The Catalysis Working Group held a kick-off meeting May 14, 2012, in Arlington, Virginia, in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting. Agenda Catalysis Working Group Kick-off Meeting Agenda Presentations DOE's Fuel Cell Catalyst R&D Activities, Nancy Garland, U.S. Department of Energy Fuel Cells: Just a Dream - or Future Reality, Nenad Markovic,

  19. Soliton production with nonlinear homogeneous lines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elizondo-Decanini, Juan M.; Coleman, Phillip D.; Moorman, Matthew W.; Petney, Sharon Joy Victor; Dudley, Evan C.; Youngman, Kevin; Penner, Tim Dwight; Fang, Lu; Myers, Katherine M.

    2015-11-24

    Low- and high-voltage Soliton waves were produced and used to demonstrate collision and compression using diode-based nonlinear transmission lines. Experiments demonstrate soliton addition and compression using homogeneous nonlinear lines. We built the nonlinear lines using commercially available diodes. These diodes are chosen after their capacitance versus voltage dependence is used in a model and the line design characteristics are calculated and simulated. Nonlinear ceramic capacitors are then used to demonstrate high-voltage pulse amplification and compression. The line is designed such that a simple capacitor discharge, input signal, develops soliton trains in as few as 12 stages. We also demonstrated outputmore » voltages in excess of 40 kV using Y5V-based commercial capacitors. The results show some key features that determine efficient production of trains of solitons in the kilovolt range.« less

  20. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder; Sapienza, Richard S.; Slegeir, William A.; O'Hare, Thomas E.

    1990-01-01

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.13 ), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  1. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder; Sapienza, Richard S.; Slegeir, William A.; O'Hare, Thomas E.

    1991-02-12

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.-), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  2. Soliton production with nonlinear homogeneous lines

    SciTech Connect (OSTI)

    Elizondo-Decanini, Juan M.; Coleman, Phillip D.; Moorman, Matthew W.; Petney, Sharon Joy Victor; Dudley, Evan C.; Youngman, Kevin; Penner, Tim Dwight; Fang, Lu; Myers, Katherine M.

    2015-11-24

    Low- and high-voltage Soliton waves were produced and used to demonstrate collision and compression using diode-based nonlinear transmission lines. Experiments demonstrate soliton addition and compression using homogeneous nonlinear lines. We built the nonlinear lines using commercially available diodes. These diodes are chosen after their capacitance versus voltage dependence is used in a model and the line design characteristics are calculated and simulated. Nonlinear ceramic capacitors are then used to demonstrate high-voltage pulse amplification and compression. The line is designed such that a simple capacitor discharge, input signal, develops soliton trains in as few as 12 stages. We also demonstrated output voltages in excess of 40 kV using Y5V-based commercial capacitors. The results show some key features that determine efficient production of trains of solitons in the kilovolt range.

  3. Decision Point 1 Topical Report

    SciTech Connect (OSTI)

    Yablonsky, Al; Barsoumian, Shant; Legere, David

    2013-05-01

    This Topical Report addresses accomplishments achieved during Phase 2a of the SkyMine® Carbon Mineralization Pilot Project. The primary objectives of this project are to design, construct, and operate a system to capture CO2 from a slipstream of flue gas from a commercial coal-fired cement kiln, convert that CO2 to products having commercial value (i.e., beneficial use), show the economic viability of the CO2 capture and conversion process, and thereby advance the technology to the point of readiness for commercial scale demonstration and proliferation. The overall process is carbon negative, resulting in mineralization of CO2 that would otherwise be released into the atmosphere. The project will also substantiate market opportunities for the technology by sales of chemicals into existing markets, and identify opportunities to improve technology performance and reduce costs at the commercial scale. The project is being conducted in two phases. The primary objectives of Phase 1 were to elaborate proven SkyMine® process chemistry to commercial pilot-scale operation and complete the preliminary design for the pilot plant to be built and operated in Phase 2, complete a NEPA evaluation, and develop a comprehensive carbon life cycle analysis. The objective of the current Phase (2a) is to complete the detailed design of the pilot plant to be built in Phase 2b.

  4. Fundamental Studies in Catalysis Enabled the use of Efficient Lean-Burn Engines for Vehicle Transportation

    Broader source: Energy.gov [DOE]

    Building on a catalysis research program sponsored by EEREs Vehicles Technology Office (VTO) and DOEs Office of Science, researchers at Cummins, Inc. and Pacific Northwest National Laboratory ...

  5. Catalysis Center for Energy Innovation (CCEI) | U.S. DOE Office of Science

    Office of Science (SC) Website

    (SC) Catalysis Center for Energy Innovation (CCEI) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Catalysis Center for Energy Innovation (CCEI) Print Text Size: A A A FeedbackShare Page CCEI Header Director Dionisios Vlachos Lead Institution University of Delaware Year Established 2009 Mission To focus on developing innovative, transformational heterogeneous

  6. Center for Biological Electron Transfer and Catalysis (BETCy) | U.S. DOE

    Office of Science (SC) Website

    Office of Science (SC) Center for Biological Electron Transfer and Catalysis (BETCy) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Center for Biological Electron Transfer and Catalysis (BETCy) Print Text Size: A A A FeedbackShare Page BETCy Header Director John Peters Lead Institution Montana State University Year Established 2014 Mission To investigate the

  7. Improving Catalysis by Putting the Best Face Forward | U.S. DOE Office of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science (SC) Improving Catalysis by Putting the Best Face Forward Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 04.01.12 Improving Catalysis by

  8. The Catalysis Center for Energy Innovation is an Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Friday, September 2, 2016 11:00 AM  322 ISE Yong Wang The Gene & Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University Institute for Integrated Catalysis, Pacific Northwest National Laboratory College of Chemistry and Chemical Engineering, Xiamen University Biography: Dr. Wang joined PNNL in 1994 and was promoted to Laboratory Fellow (highest scientific rank in national labs) in 2005. He led the Catalysis and Reaction Engineering Team from 2000 to

  9. Catalysis by Design: Bridging the Gap Between Theory and Experiments at

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanoscale Level | Department of Energy Between Theory and Experiments at Nanoscale Level Catalysis by Design: Bridging the Gap Between Theory and Experiments at Nanoscale Level Studies on a simple platinum-alumina system constitute a first step toward a "catalyst by design" approach. deer08_narula.pdf (273.18 KB) More Documents & Publications Catalysis by Design: Bridging the Gap between Theory and Experiments Catalyst by Design - Theoretical, Nanostructural, and Experimental

  10. Tracking topic birth and death in LDA.

    SciTech Connect (OSTI)

    Wilson, Andrew T.; Robinson, David Gerald

    2011-09-01

    Most topic modeling algorithms that address the evolution of documents over time use the same number of topics at all times. This obscures the common occurrence in the data where new subjects arise and old ones diminish or disappear entirely. We propose an algorithm to model the birth and death of topics within an LDA-like framework. The user selects an initial number of topics, after which new topics are created and retired without further supervision. Our approach also accommodates many of the acceleration and parallelization schemes developed in recent years for standard LDA. In recent years, topic modeling algorithms such as latent semantic analysis (LSA)[17], latent Dirichlet allocation (LDA)[10] and their descendants have offered a powerful way to explore and interrogate corpora far too large for any human to grasp without assistance. Using such algorithms we are able to search for similar documents, model and track the volume of topics over time, search for correlated topics or model them with a hierarchy. Most of these algorithms are intended for use with static corpora where the number of documents and the size of the vocabulary are known in advance. Moreover, almost all current topic modeling algorithms fix the number of topics as one of the input parameters and keep it fixed across the entire corpus. While this is appropriate for static corpora, it becomes a serious handicap when analyzing time-varying data sets where topics come and go as a matter of course. This is doubly true for online algorithms that may not have the option of revising earlier results in light of new data. To be sure, these algorithms will account for changing data one way or another, but without the ability to adapt to structural changes such as entirely new topics they may do so in counterintuitive ways.

  11. Physics Topics - MST - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics UW Madison Madison Symmetric Torus Physics Topics MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST People mst logo CPLA Home Directory Publications Links Internal University of Wisconsin Physics Department Research funding includes support from: Department of Energy National Science Foundation The MST physics challenges are large and many, but much of our work is captured in the following four major RFP physics goals

  12. LANSCE | Users | LUG | Topical User Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 LANSCE Topical User Meeting | January 9-10 2012 LANSCE Topical User Workshop LANSCE will host the 2012 Topical User Workshop, January 9-10, 2012. We hope to see you there! Registration | Accommodations | Agenda (some presentations are included on the agenda) LANL foreign nationals may register at anytime. | Poster Dimensions: 32 in x 40 in This workshop will solicit user input for the scientific opportunities offered by the pulse stacker and superconducting accelerator that LANSCE has proposed

  13. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Western Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Western ...

  14. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Eastern Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Eastern ...

  15. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A, Interconnection-Level Analysis and Planning Interconnection-Wide Transmission Planning Initiative: Topic A, Interconnection-Level Analysis and Planning A description of the ...

  16. Interconnection-Wide Transmission Planning Initiative: Topic...

    Energy Savers [EERE]

    the Texas Interconnection Interconnection-Wide Transmission Planning Initiative: Topic B, State Agency Input Regarding Electric Resource and Transmission Planning in the Texas ...

  17. Preface: Special Topic on Interfacial and Confined Water (Journal...

    Office of Scientific and Technical Information (OSTI)

    Preface: Special Topic on Interfacial and Confined Water Citation Details In-Document Search Title: Preface: Special Topic on Interfacial and Confined Water This Special Topic on...

  18. Topic Index to the DOE Administrative Records Disposition Schedules...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative...

  19. Foam Generation in Homogeneous Porous Media

    SciTech Connect (OSTI)

    Gauglitz, Phillip A.; Friedman, F.; Kam, S. I.; Rossen, W. R.

    2002-10-01

    In steady gas-liquid flow in homogeneous porous media with surfactant present, there is often observed a critical injection velocity or pressure gradient ?grad p min? at which ?weak? or ?coarse? foam is abruptly converted into ?strong foam,? with reduction of one to two orders of magnitude in total mobility: i.e., ?foam generation.? Earlier research on foam generation is extended here with extensive data for a variety of porous media, permeabilities, gases (N2 and C02), surfactants, and temperatures. For bead and sandpacks, ?grad p min? scales like (1/k), where k is permeability, over 2 1/2 orders of magnitude in k; for consolidated media the relation is more complex. For dense C02 foam, ?grad p min? exists but can be less than 1 psi/ft. If pressure drop, rather than flow rates, is fixed, one observes and unstable regime between stable ?strong? and ?coarse? foam regimes; in the unstable regime ?grad p? is nonuniform in space or variable in time.

  20. Homogeneously dispersed, multimetal oxygen-evolving catalysts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Bo; Zheng, Xueli; Voznyy, Oleksandr; Comin, Riccardo; Bajdich, Michal; Garcia-Melchor, Max; Han, Lili; Xu, Jixian; Liu, Min; Zheng, Lirong; et al

    2016-03-24

    Earth-abundant first-row (3d) transition-metal-based catalysts have been developed for the oxygen-evolution reaction (OER); however, they operate at overpotentials significantly above thermodynamic requirements. Density functional theory suggested that non-3d high-valency metals such as tungsten can modulate 3d metal oxides, providing near-optimal adsorption energies for OER intermediates. We developed a room-temperature synthesis to produce gelled oxy-hydroxide materials with an atomically homogeneous metal distribution. These gelled FeCoW oxy-hydroxide exhibits the lowest overpotential (191 mV) reported at 10 mA per square centimeter in alkaline electrolyte. Here, the catalyst shows no evidence of degradation following more than 500 hours of operation. X-ray absorption and computationalmore » studies reveal a synergistic interplay between W, Fe and Co in producing a favorable local coordination environment and electronic structure that enhance the energetics for OER.« less

  1. NOX REDUCTION FOR LEAN EXHAUST USING PLASMA ASSISTED CATALYSIS

    SciTech Connect (OSTI)

    Bhatt, B.

    2000-08-20

    Currently CARB estimates on road diesel vehicles contribute 50% of the NOX and 78% of the particulates being discharged from mobile sources. Diesel emissions obviously must be reduced if future air quality targets are to be met. A critical technological barrier exists because there are no commercial technologies available, which can reduce NOX from diesel (lean), exhaust containing 5-15% O2 concentration. One promising approach to reducing NOX and particulates from diesel exhaust is to use a combination of plasma with catalyst. Plasma can be generated thermally or non-thermally. Thermal plasma is formed by heating the system to an exceedingly high temperature (>2000 C). High temperature requirements for plasma makes thermal plasma inefficient and requires skillful thermal management and hence is considered impractical for mobile applications. Non-thermal plasma directs electrical energy into the creation of free electrons, which in turn react with gaseous species thus creating plasma. A combination of non-thermal plasma with catalysts can be referred to Plasma Assisted Catalysts or PAC. PAC technology has been demonstrated in stationary sources where non-thermal plasma catalysis is carried out in presence of NH3 as a reductant. In stationary applications NO is oxidized to HNO3 and then into ammonium nitrate where it is condensed and removed. This approach is impractical for mobile application because of the ammonia requirement and the ultimate mechanism by which NOX is removed. However, if a suitable catalyst can be found which can use onboard fuel as reductant then the technology holds a considerable promise. NOX REDUCTION FOR LEAN EXHAUST USING PLASMA ASSISTED CATALYSIS Ralph Slone, B. Bhatt and Victor Puchkarev NOXTECH INC. In addition to the development of an effective catalyst, a non-thermal plasma reactor needs be scaled and demonstrated along with a reliable and cost effective plasma power source and onboard HC source needs to be proven. Under the work

  2. Highly Dispersed Pseudo-Homogeneous and Heterogeneous Catalysts Synthesized via Inverse Micelle Solutions for the Liquefaction of Coal

    SciTech Connect (OSTI)

    Hampden-Smith, M.; Kawola, J.S.; Martino, A.; Sault, A.G.; Yamanaka, S.A.

    1999-01-05

    The mission of this project was to use inverse micelle solutions to synthesize nanometer sized metal particles and test the particles as catalysts in the liquefaction of coal and other related reactions. The initial focus of the project was the synthesis of iron based materials in pseudo-homogeneous form. The frost three chapters discuss the synthesis, characterization, and catalyst testing in coal liquefaction and model coal liquefaction reactions of iron based pseudo-homogeneous materials. Later, we became interested in highly dispersed catalysts for coprocessing of coal and plastic waste. Bifunctional catalysts . to hydrogenate the coal and depolymerize the plastic waste are ideal. We began studying, based on our previously devised synthesis strategies, the synthesis of heterogeneous catalysts with a bifunctional nature. In chapter 4, we discuss the fundamental principles in heterogeneous catalysis synthesis with inverse micelle solutions. In chapter 5, we extend the synthesis of chapter 4 to practical systems and use the materials in catalyst testing. Finally in chapter 6, we return to iron and coal liquefaction now studied with the heterogeneous catalysts.

  3. Application of solid ash based catalysts in heterogeneous catalysis

    SciTech Connect (OSTI)

    Shaobin Wang

    2008-10-01

    Solid wastes, fly ash, and bottom ash are generated from coal and biomass combustion. Fly ash is mainly composed of various metal oxides and possesses higher thermal stability. Utilization of fly ash for other industrial applications provides a cost-effective and environmentally friendly way of recycling this solid waste, significantly reducing its environmental effects. On the one hand, due to the higher stability of its major component, aluminosilicates, fly ash could be employed as catalyst support by impregnation of other active components for various reactions. On the other hand, other chemical compounds in fly ash such as Fe{sub 2}O{sub 3} could also provide an active component making fly ash a catalyst for some reactions. In this paper, physicochemical properties of fly ash and its applications for heterogeneous catalysis as a catalyst support or catalyst in a variety of catalytic reactions were reviewed. Fly-ash-supported catalysts have shown good catalytic activities for H{sub 2} production, deSOx, deNOx, hydrocarbon oxidation, and hydrocracking, which are comparable to commercially used catalysts. As a catalyst itself, fly ash can also be effective for gas-phase oxidation of volatile organic compounds, aqueous-phase oxidation of organics, solid plastic pyrolysis, and solvent-free organic synthesis. 107 refs., 4 figs., 2 tabs.

  4. TEC Working Group Topic Groups Rail Conference Call Summaries...

    Office of Environmental Management (EM)

    Summaries Rail Topic Group TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group Rail Topic Group PDF icon May 17, 2007 PDF icon January 16, 2007 PDF icon...

  5. Webtrends Archives by Fiscal Year - Topic Landing Pages | Department...

    Broader source: Energy.gov (indexed) [DOE]

    topic landing pages by fiscal year. Topic Landing Pages FY10 (2.04 MB) Topic Landing Pages FY11 (2.02 MB) Topic Landing Pages FY12-FY13 (366.66 KB) More Documents & Publications ...

  6. Jonathan Link, Columbia KEK Topical Conference

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -22, 2001 Jonathan Link, Columbia KEK Topical Conference Short Baseline Neutrino Oscillations and MiniBooNE Jonathan Link Columbia University The 5 th KEK Topical Conference - Frontiers in Flavor Physics November 20-22, 2001 November 20-22, 2001 Jonathan Link, Columbia KEK Topical Conference Outline 1. Background on Short Baseline Neutrino Oscillations * A little neutrino physics * The LSND oscillation result 2. About MiniBooNE 3. Status of MiniBooNE. Some of you may have noticed that I'll be

  7. Computationally Optimized Homogenization Heat Treatment of Metal Alloys -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Industrial Technologies Industrial Technologies Advanced Materials Advanced Materials Find More Like This Return to Search Computationally Optimized Homogenization Heat Treatment of Metal Alloys National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication Computationally Optimized Homogenization Heat Treatment of Metal Alloys (291 KB) Technology Marketing Summary ? A computational approach has been developed to

  8. Shape-selective catalysis in dimethyl ether conversion

    SciTech Connect (OSTI)

    Sardesai, A.; Lee, S.

    1999-07-01

    Coal-derived syngas can be effectively converted to dimethyl ether (DME) in a single-stage, liquid-phase process. This Liquid Phase Dimethyl Ether (LPDME) process utilizes a dual catalytic system, which comprises of a physical blend between the methanol synthesis and the methanol dehydration catalyst slurried in an inert mineral oil. Such produced DME has vast potential as a building block chemical in the petrochemical industry to produce value-added specialty chemicals. The current research efforts are made to exploit the utilization of shape-selective catalysis using zeolites to produce targeted petrochemicals, including lower olefinic hydrocarbons. The catalysts probed in this investigation include zeolites of different physical, morphological, and chemical configurations. The effect of acidity of ZSM-5 type zeolites as well as the effect of the different channel size and orientation of the zeolites on product selectivity and catalyst deactivation are examined. Results obtained from experimentation of this study show that ZSM-5 type zeolite with low acidity (high SiO{sub 2}/Al{sub 2}O{sub 3} ratio, in this case 150) exhibits the highest selectivity towards lower (C{sub 2}-C{sub 4}) olefins in general. Controlled selectivity toward targeted olefinic species can be accomplished via devising catalytic reaction systems in such a way that the structural property of the catalyst and reactive interaction between molecules in the pores are geared toward formation of targeted molecular species which also at the same time prevent the formation of less desirable products. The internal morphology of the catalyst also has a pronounced effect on the deactivation phenomenon, where it is observed that zeolites possessing high acidity and a unidimensional channel structure are prone towards catalyst deactivation by coking and pore blockage.

  9. Structural Insights into the Mechanism of PEPCK Catalysis

    SciTech Connect (OSTI)

    Holyoak,T.; Sullivan, S.; Nowak, T.

    2006-01-01

    Phosphoenolpyruvate carboxykinase catalyzes the reversible decarboxylation of oxaloacetic acid with the concomitant transfer of the {gamma}-phosphate of GTP to form PEP and GDP as the first committed step of gluconeogenesis and glyceroneogenesis. The three structures of the mitochondrial isoform of PEPCK reported are complexed with Mn{sup 2+}, Mn{sup 2+}-PEP, or Mn{sup 2+}-malonate-Mn{sup 2+}GDP and provide the first observations of the structure of the mitochondrial isoform and insight into the mechanism of catalysis mediated by this enzyme. The structures show the involvement of the hyper-reactive cysteine (C307) in the coordination of the active site Mn{sup 2+}. Upon formation of the PEPCK-Mn{sup 2+}-PEP or PEPCK-Mn{sup 2+}-malonate-Mn{sup 2+}GDP complexes, C307 coordination is lost as the P-loop in which it resides adopts a different conformation. The structures suggest that stabilization of the cysteine-coordinated metal geometry holds the enzyme as a catalytically incompetent metal complex and may represent a previously unappreciated mechanism of regulation. A third conformation of the mobile P-loop in the PEPCK-Mn{sup 2+}-malonate-Mn{sup 2+}GDP complex demonstrates the participation of a previously unrecognized, conserved serine residue (S305) in mediating phosphoryl transfer. The ordering of the mobile active site lid in the PEPCK-Mn{sup 2+}-malonate-Mn{sup 2+}GDP complex yields the first observation of this structural feature and provides additional insight into the mechanism of phosphoryl transfer.

  10. State of Supported Nickel Nanoparticles during Catalysis in Aqueous Media

    SciTech Connect (OSTI)

    Chase, Zizwe; Kasakov, Stanislav; Shi, Hui; Vjunov, Aleksei; Fulton, John L.; Camaioni, Donald M.; Balasubramanian, Mahalingam; Zhao, Chen; Wang, Yong; Lercher, Johannes A.

    2015-11-09

    The state of Ni supported on HZSM-5 zeolite, silica, and sulfonated carbon was determined during aqueous phase catalysis of phenol hydrodeoxygenation using in situ extended X-ray absorption fine structure spectroscopy (EXAFS). On sulfonated carbon and HZSM-5 supports, the NiO and Ni(OH)2 were readily reduced to Ni(0) under reaction conditions (~35 bar H2 in aqueous phenol solutions containing up to 0.5 wt. % phosphoric acid at 473 K). On the silica support, less than 70% of the Ni was converted to Ni(0) under reaction conditions, which is attributed to the formation of Ni phyllosilicates. Over a broad range of reaction conditions there was no leaching of Ni from the supports. In contrast, rapid leaching of the Ni(II) from HZSM-5 was observed, when 15 wt. % aqueous acetic acid was substituted for the aqueous phenol solution. Once the metallic state of Ni was established there was no leaching in 15 wt. % acetic acid at 473 K and 35 bar H2. This work was supported by the U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences & Biosciences. The STEM was supported under the Laboratory Directed Research and Development Program: Chemical Imaging Initiative at Pacific Northwest National Laboratory (PNNL), a multi-program national laboratory operated for DOE by Battelle under Contract DE-AC05-76RL01830. STEM was performed at EMSL, a DOE Office of Science user facility sponsored by the Office of Biological and Environmental Research and located at PNNL.

  11. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    TEC Tribal Topic Group Conference Call January 18, 2006 Group Chair: Jay Jones (DOE/OCRWM) Participating TEC Tribal Topic Group Members: Rob Burnside (CTUIR), Earl Easton (U.S. NRC), Kristen Ellis (DOE/CI), Ed Gonzales (ELG), Angela Hill (DOE/OCRWM), Marsha Keister (INL), Dan King (Oneida Nation), Corinne Macaluso (DOE/OCRWM), Titto Moses (CTUIR), Stanley Paytiamo (Pueblo of Acoma), Willie Preacher (Shoshone-Bannock Tribes), Cathy Reynolds (DOE/GC), Larry Stern (CVSA), Kevin Tafoya (Santa Clara

  12. At tank Low Activity Feed Homogeneity Analysis Verification

    SciTech Connect (OSTI)

    DOUGLAS, J.G.

    2000-09-28

    This report evaluates the merit of selecting sodium, aluminum, and cesium-137 as analytes to indicate homogeneity of soluble species in low-activity waste (LAW) feed and recommends possible analytes and physical properties that could serve as rapid screening indicators for LAW feed homogeneity. The three analytes are adequate as screening indicators of soluble species homogeneity for tank waste when a mixing pump is used to thoroughly mix the waste in the waste feed staging tank and when all dissolved species are present at concentrations well below their solubility limits. If either of these conditions is violated, then the three indicators may not be sufficiently chemically representative of other waste constituents to reliably indicate homogeneity in the feed supernatant. Additional homogeneity indicators that should be considered are anions such as fluoride, sulfate, and phosphate, total organic carbon/total inorganic carbon, and total alpha to estimate the transuranic species. Physical property measurements such as gamma profiling, conductivity, specific gravity, and total suspended solids are recommended as possible at-tank methods for indicating homogeneity. Indicators of LAW feed homogeneity are needed to reduce the U.S. Department of Energy, Office of River Protection (ORP) Program's contractual risk by assuring that the waste feed is within the contractual composition and can be supplied to the waste treatment plant within the schedule requirements.

  13. 2010 CATALYSIS GORDON RESEARCH CONFERENCE, JUNE 27 - JULY 2, 2010, NEW LONDON, NEW HAMPSHIRE

    SciTech Connect (OSTI)

    Abhaya Datye

    2010-07-02

    Catalysis is a key technology for improving the quality of life while simultaneously reducing the adverse impact of human activities on the environment. The discovery of new catalytic processes and the improvement of existing ones are also critically important for securing the nation's energy supply. The GRC on Catalysis is considered one the most prestigious conference for catalysis research, bringing together leading researchers from both academia, industry and national labs to discuss the latest, most exciting research in catalysis and the future directions for the field. The 2010 GRC on Catalysis will follow time-honored traditions and feature invited talks from the world's leading experts in the fundamentals and applications of catalytic science and technology. We plan to have increased participation from industry. The extended discussions in the company of outstanding thinkers will stimulate and foster new science. The conference will include talks in the following areas: Alternative feedstocks for chemicals and fuels, Imaging and spectroscopy, Design of novel catalysts, Catalyst preparation fundamentals, Molecular insights through theory, Surface Science, Catalyst stability and dynamics. In 2010, the Catalysis conference will move to a larger conference room with a new poster session area that will allow 40 posters per session. The dorm rooms provide single and double accommodations, free WiFi and the registration fee includes all meals and the famous lobster dinner on Thursday night. Afternoons are open to enjoy the New England ambiance with opportunities for hiking, sailing, golf and tennis to create an outstanding conference that will help you network with colleagues, and make long lasting connections.

  14. Growth mechanism of graphene on platinum: Surface catalysis and carbon segregation

    SciTech Connect (OSTI)

    Sun, Jie Lindvall, Niclas; Yurgens, August; Nam, Youngwoo; Cole, Matthew T.; Teo, Kenneth B. K.; Woo Park, Yung

    2014-04-14

    A model of the graphene growth mechanism of chemical vapor deposition on platinum is proposed and verified by experiments. Surface catalysis and carbon segregation occur, respectively, at high and low temperatures in the process, representing the so-called balance and segregation regimes. Catalysis leads to self-limiting formation of large area monolayer graphene, whereas segregation results in multilayers, which evidently grow from below. By controlling kinetic factors, dominantly monolayer graphene whose high quality has been confirmed by quantum Hall measurement can be deposited on platinum with hydrogen-rich environment, quench cooling, tiny but continuous methane flow and about 1000?C growth temperature.

  15. Geek-Up[3.11.2011]: Energy Efficiency, Catalysis and Open Source Tools |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 11.2011]: Energy Efficiency, Catalysis and Open Source Tools Geek-Up[3.11.2011]: Energy Efficiency, Catalysis and Open Source Tools March 11, 2011 - 4:37pm Addthis L. Keith Woo | Photo courtesy of Ames National Laboratory L. Keith Woo | Photo courtesy of Ames National Laboratory Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs Ames Laboratory researcher and Iowa State University professor L. Keith Woo is on the search for catalysts that lead

  16. Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype confirms Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype

  17. Hydrogen storage materials and method of making by dry homogenation

    DOE Patents [OSTI]

    Jensen, Craig M.; Zidan, Ragaiy A.

    2002-01-01

    Dry homogenized metal hydrides, in particular aluminum hydride compounds, as a material for reversible hydrogen storage is provided. The reversible hydrogen storage material comprises a dry homogenized material having transition metal catalytic sites on a metal aluminum hydride compound, or mixtures of metal aluminum hydride compounds. A method of making such reversible hydrogen storage materials by dry doping is also provided and comprises the steps of dry homogenizing metal hydrides by mechanical mixing, such as be crushing or ball milling a powder, of a metal aluminum hydride with a transition metal catalyst. In another aspect of the invention, a method of powering a vehicle apparatus with the reversible hydrogen storage material is provided.

  18. TEC Working Group Topic Groups Rail Key Documents Intermodal Subgroup |

    Office of Environmental Management (EM)

    Department of Energy Intermodal Subgroup TEC Working Group Topic Groups Rail Key Documents Intermodal Subgroup Intermodal Subgroup Draft Work Plan (206.83 KB) More Documents & Publications TEC Working Group Topic Groups Rail Key Documents Radiation Monitoring Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Intermodal Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group

  19. TEC Working Group Topic Groups Routing Meeting Summaries | Department of

    Office of Environmental Management (EM)

    Energy Meeting Summaries TEC Working Group Topic Groups Routing Meeting Summaries MEETING SUMMARIES Atlanta TEC Meeting, Routing Topic Group Summary (101.72 KB) More Documents & Publications TEC Meeting Summaries - January - February 2007 TEC Working Group Topic Groups Rail Meeting Summaries TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group

  20. Tritium Technology Program TTP-1-3089 TPBAR Homogenized Composition

    SciTech Connect (OSTI)

    Love, Edward F.

    2014-10-12

    Homogenized TPBAR number densities contained herein have been derived for unclassified core physics calculations. The use of this information may not provide accurate, conservative or representative results and must be evaluated for applicability to the specific problem.

  1. Surface functionalization of metal-organic polyhedron for homogeneous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst...

  2. Enzyme-Like Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation

    SciTech Connect (OSTI)

    Hastings, Courtney; Pluth, Michael; Bergman, Robert; Raymond, Kenneth

    2010-03-29

    A primary goal in the design and synthesis of molecular hosts has been the selective recognition and binding of a variety of guests using non-covalent interactions. Supramolecular catalysis, which is the application of such hosts towards catalysis, has much in common with many enzymatic reactions, chiefly the use of both spatially appropriate binding pockets and precisely oriented functional groups to recognize and activate specific substrate molecules. Although there are now many examples which demonstrate how selective encapsulation in a host cavity can enhance the reactivity of a bound guest, all have failed to reach the degree of increased reactivity typical of enzymes. We now report the catalysis of the Nazarov cyclization by a self-assembled coordination cage, a carbon-carbon bond-forming reaction which proceeds under mild, aqueous conditions. The acceleration in this system is over a million-fold, and represents the first example of supramolecular catalysis that achieves the level of rate enhancement comparable to that observed in several enzymes. We explain the unprecedented degree of rate increase as due to the combination of (a) preorganization of the encapsulated substrate molecule, (b) stabilization of the transition state of the cyclization by constrictive binding, and (c) increase in the basicity of the complexed alcohol functionality.

  3. Solvation and Acid Strength Effects on Catalysis by Faujasite Zeolites

    SciTech Connect (OSTI)

    Gounder, Rajamani P.; Jones, Andrew J.; Carr, Robert T.; Iglesia, Enrique

    2012-02-01

    Kinetic, spectroscopic, and chemical titration data indicate that differences in monomolecular isobutane cracking and dehydrogenation and methanol dehydration turnover rates (per H+) among FAU zeolites treated thermally with steam (H-USY) and then chemically with ammonium hexafluorosilicate (CDHUSY) predominantly reflect differences in the size and solvating properties of their supercage voids rather than differences in acid strength. The number of protons on a given sample was measured consistently by titrations with Na+, with CH3 groups via reactions of dimethyl ether, and with 2,6-di-tert-butylpyridine during methanol dehydration catalysis; these titration values were also supported by commensurate changes in acidic OH infrared band areas upon exposure to titrant molecules. The number of protons, taken as the average of the three titration methods, was significantly smaller than the number of framework Al atoms (Alf) obtained from X-ray diffraction and 27Al magic angle spinning nuclear magnetic resonance spectroscopy on H-USY (0.35 H+/Alf) and CD-HUSY (0.69 H+/Alf). These data demonstrate that the ubiquitous use of Alf sites as structural proxies for active H+ sites in zeolites can be imprecise, apparently because distorted Al structures that are not associated with acidic protons are sometimes detected as Alf sites. Monomolecular isobutane cracking and dehydrogenation rate constants, normalized non-rigorously by the number of Alf species, decreased with increasing Na+ content on both H-USY and CD-HUSY samples and became undetectable at sub-stoichiometric exchange levels (0.32 and 0.72 Na+/Alf ratios, respectively), an unexpected finding attributed incorrectly in previous studies to the presence of minority ‘‘super-acidic’’ sites. These rate constants, when normalized rigorously by the number of residual H+ sites were independent of Na+ content on both H-USY and CD-HUSY samples, reflecting the stoichiometric replacement of protons that are uniform in

  4. Chemistry - Oxygen Vacancies and Catalysis on Ceria Surfaces

    SciTech Connect (OSTI)

    Campbell, Charles T.; Peden, Charles HF.

    2005-07-29

    Chemistry occurring at the surface of metal oxides is critical in a variety of industrial applications including catalysis and photocatalysis, optical display technology, solar energy devices and corrosion prevention. Defects have long been recognized to be the most reactive sites on the surfaces of many oxide materials. The most common types of defects present on the surfaces of metal oxides are oxygen vacancies and step edges. The nature of surface oxygen vacancies, and their number, distribution and diffusion across the surface of oxides, are thus issues of major scientific importance. One of the most interesting oxides in this respect is CeO2, since oxygen vacancies play the key role in giving this material it's industrially important ''oxygen-storage capacity''. This capacity makes modern automotive exhaust treatment catalysts containing CeO2 much more effective than their predecessors without CeO2. Ceria is also well known as a support which enhances the performance of transition metal catalysts, relative to other oxide supports, in a variety of other reactions including water-gas shift, steam reforming of oxygenates and PROX 1-7, all of which hold promise for enabling a hydrogen economy 1. Related to ceria's facile redox capacity (ability to rapidly form and eliminate oxygen vacancy defects) is the poorly understood observation that some less reducible oxides, such as zirconia (ZrO2), are used as additives that actually enhance this ''oxygen storage'' property of CeO2. In this issue, Esch and coworkers in Trieste, Italy report an exciting study that for the first time clearly elucidates the structure, distribution and formation of oxygen vacancies on a cerium oxide surface 8. They have elegantly combined beautiful, atomic-resolution imaging using scanning-tunneling microscopy (STM) on a ceria surface with state-of-the-art quantum mechanical calculations using Density Functional Theory (DFT) to raise our understanding of CeO2 surfaces to a much higher level

  5. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Donald Danforth Plant Science Center April 9, 2015 - 3:15pm Donald...

  6. OSTIblog Articles in the history of science Topic | OSTI, US...

    Office of Scientific and Technical Information (OSTI)

    history of science Topic World Wide Information: The Other Side of the Coin by Kristin ... Of course, the world's information covers numerous topics other than science and ...

  7. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment MIssouri Botanical Garden | Earthways Center - October 6th, 3:15 -...

  8. Public Perception of 13 Different Energy Topics analyzed in new...

    Open Energy Info (EERE)

    and unfavorability energy topics such as transportation, renewable technology, nuclear, clean coal, and smart grid topics. Some of the highlights of the study are as...

  9. Hot Topics Workshops | June 2016 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Workshops | June 2016 Hot Topics Workshops | June 2016 A look at our workshops this past June on various topics including nuclear energy, biofuels, and renewable

  10. OSTIblog Articles in the greenhouse gases Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    greenhouse gases Topic Carbon Sequestration - Helping to Save Our Beautiful World by Kathy ... Related Topics: carbon dioxide, carbon sequestration, climate change, greenhouse gases

  11. TEC Working Group Topic Groups Rail Meeting Summaries | Department...

    Office of Environmental Management (EM)

    TEC Working Group Topic Groups Rail Meeting Summaries MEETING SUMMARIES PDF icon Kansas City TEC Meeting, Rail Topic Group Summary - July 25, 2007 PDF icon Atlanta TEC...

  12. TEC Working Group Topic Groups Security | Department of Energy

    Office of Environmental Management (EM)

    TEC Working Group Topic Groups Security The Security Topic group is comprised of regulators, law enforcement officials, labor and industry representatives and other subject matter ...

  13. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Tyson Living Learning Center tour November 18, 2014 - 4:00pm Tyson...

  14. Quark-gluon plasma (Selected Topics)

    SciTech Connect (OSTI)

    Zakharov, V. I.

    2012-09-15

    Introductory lectures to the theory of (strongly interacting) quark-gluon plasma given at the Winter School of Physics of ITEP (Moscow, February 2010). We emphasize theoretical issues highlighted by the discovery of the low viscosity of the plasma. The topics include relativistic hydrodynamics, manifestations of chiral anomaly in hydrodynamics, superfluidity, relativistic superfluid hydrodynamics, effective stringy scalars, holographic models of Yang-Mills theories.

  15. Hot topics in flavor physics at CDF

    SciTech Connect (OSTI)

    Jun, Soon Yung; /Carnegie Mellon U.

    2005-01-01

    Hot topics in flavor physics at CDF are reviewed. Selected results of top, beauty, charm physics and exotic states in about 200 pb{sup -1} data collected by the CDF II detector in p{bar p} collisions at {radical}s = 1.96 TeV at the Fermilab Tevatron are presented.

  16. More About "Topic A" and "Topic B" Awards | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More About "Topic A" and "Topic B" Awards More About "Topic A" and "Topic B" Awards The awards pursuant to the Department of Energy's Interconnection-wide Transmission Planning Initiative cover two broad topics. "Topic A" covers Interconnection-Level Analysis and Planning. "Topic B" covers Cooperation Among States on Electric Resource Planning and Priorities, where the states will develop input to the Topic A analyses and perform other

  17. A Computationally Based Approach to Homogenizing Advanced Alloys

    SciTech Connect (OSTI)

    Jablonski, P D; Cowen, C J

    2011-02-27

    We have developed a computationally based approach to optimizing the homogenization heat treatment of complex alloys. The Scheil module within the Thermo-Calc software is used to predict the as-cast segregation present within alloys, and DICTRA (Diffusion Controlled TRAnsformations) is used to model the homogenization kinetics as a function of time, temperature and microstructural scale. We will discuss this approach as it is applied to both Ni based superalloys as well as the more complex (computationally) case of alloys that solidify with more than one matrix phase as a result of segregation. Such is the case typically observed in martensitic steels. With these alloys it is doubly important to homogenize them correctly, especially at the laboratory scale, since they are austenitic at high temperature and thus constituent elements will diffuse slowly. The computationally designed heat treatment and the subsequent verification real castings are presented.

  18. Cryogenic homogenization and sampling of heterogeneous multi-phase feedstock

    DOE Patents [OSTI]

    Doyle, Glenn Michael (Lakewood, CO); Ideker, Virgene Linda (Arvada, CO); Siegwarth, James David (Boulder, CO)

    2002-01-01

    An apparatus and process for producing a homogeneous analytical sample from a heterogenous feedstock by: providing the mixed feedstock, reducing the temperature of the feedstock to a temperature below a critical temperature, reducing the size of the feedstock components, blending the reduced size feedstock to form a homogeneous mixture; and obtaining a representative sample of the homogeneous mixture. The size reduction and blending steps are performed at temperatures below the critical temperature in order to retain organic compounds in the form of solvents, oils, or liquids that may be adsorbed onto or absorbed into the solid components of the mixture, while also improving the efficiency of the size reduction. Preferably, the critical temperature is less than 77 K (-196.degree. C.). Further, with the process of this invention the representative sample may be maintained below the critical temperature until being analyzed.

  19. Variable valve timing in a homogenous charge compression ignition engine

    DOE Patents [OSTI]

    Lawrence, Keith E.; Faletti, James J.; Funke, Steven J.; Maloney, Ronald P.

    2004-08-03

    The present invention relates generally to the field of homogenous charge compression ignition engines, in which fuel is injected when the cylinder piston is relatively close to the bottom dead center position for its compression stroke. The fuel mixes with air in the cylinder during the compression stroke to create a relatively lean homogeneous mixture that preferably ignites when the piston is relatively close to the top dead center position. However, if the ignition event occurs either earlier or later than desired, lowered performance, engine misfire, or even engine damage, can result. The present invention utilizes internal exhaust gas recirculation and/or compression ratio control to control the timing of ignition events and combustion duration in homogeneous charge compression ignition engines. Thus, at least one electro-hydraulic assist actuator is provided that is capable of mechanically engaging at least one cam actuated intake and/or exhaust valve.

  20. TEC Working Group Topic Groups Archives | Department of Energy

    Office of Environmental Management (EM)

    Archives TEC Working Group Topic Groups Archives The following Topic Groups are no longer active; however, related documents and notes for these archived Topic Groups are available through the following links: Communications Consolidated Grant Topic Group Training - Medical Training Protocols Route Identification Process Mechanics of Funding and Technical Assistance

  1. Innovative Topics for Advanced Biofuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovative Topics for Advanced Biofuels Innovative Topics for Advanced Biofuels PNNL report-out presentation at the CTAB webinar on innovative topics for advanced biofuels. ctab_webinar_innovative_topics.pdf (1.55 MB) More Documents & Publications Cross-cutting Technologies for Advanced Biofuels Conversion Technologies for Advanced Biofuels - Carbohydrates Production Conversion Technologies for Advanced Biofuels - Bio-Oil Upgrading

  2. Renewable Energy Project Development: Advanced Concept Topics

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concept Topics An Introduction to Risk, Tribal Roles, and Support Policies in the Renewable Energy Project Development Process Course Outline What we will cover...  About the DOE Office of Indian Energy Education Initiative  Concepts and Policies for Understanding Renewable Energy Projects on Tribal Lands - Risk and Uncertainty - Tribal Project Roles - Policies and Incentives  Additional Information and Resources 2 Introduction The U.S. Department of Energy (DOE) Office of Indian Energy

  3. Renewable Energy Project Development: Advanced Process Topics

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process Topics Understanding Energy Markets, Project Scale Decision Factors, Procurement Options, and the Role of the Project Team Course Outline What we will cover...  About the DOE Office of Indian Energy Education Initiative  Processes for Developing Renewable Energy Projects on Tribal Lands - Understanding the Energy Market and Project Scale - Project Scale and Ownership Options - Procurement Process - Project Team  Additional Information and Resources 2 Introduction The U.S.

  4. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    Meeting September 22, 2005 - Pueblo, CO Group Chair: Jay Jones (DOE/OCRWM) Tribal Topic Group Members Present: Richard Arnold (Southern Paiute/CGTO), Vicki Best (Bechtel SAIC-YMP), Kevin Blackwell (DOT/FRA), Sandra Covi (UPRR), Barbara Durham (Timbisha Shoshone Tribe), Greg Fasano (Bechtel SAIC-YMP), Elizabeth Helvey (BSC), Angela Hill (DOE/OCRWM), Judith Holm (DOE/OCRWM), Marsha Keister (INL), Dan King (Oneida Nation), Gary Lanthrum (DOE/OCRWM), Corinne Macaluso (DOE/OCRWM), Calvin Meyers

  5. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    Conference Call December 6, 2005 Group Chair: Jay Jones (DOE/OCRWM) Participating TEC Tribal Topic Group Members: Kevin Clarke (DOE/RL), Kristen Ellis (DOE/CI), Lisa Gover (NTEC), Dan King (Oneida Nation), Corinne Macaluso (DOE/OCRWM), Ellen Ott (DOE/GC), Ted Repasky (CTUIR), Cathy Reynolds (DOE/GC), Lisa Sattler (CSG-MW) Herman Shorty (Navajo Nation), Linda Sikkema (NCSL), Christopher Wells (SSEB) DOE support contractors also participated in this call. Action Items: Responsible Party Action to

  6. Topic A Awardee: Eastern Interconnection Planning Collaborative |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Eastern Interconnection Planning Collaborative Topic A Awardee: Eastern Interconnection Planning Collaborative Eastern Interconnection Planning Collaborative The Eastern Interconnection Planning Collaborative (EIPC) was initiated by a coalition of regional Planning Authorities. These Planning Authorities are entities listed on the NERC compliance registry as Planning Authorities and represent the entire Eastern Interconnection. The EIPC was founded to be a broad-based,

  7. TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic

    Office of Environmental Management (EM)

    Group | Department of Energy Summaries Rail Topic Group TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group Rail Topic Group May 17, 2007 (10.98 KB) January 16, 2007 (14.41 KB) August 31, 2006 (16.39 KB) July 27, 2006 (19.28 KB) June 8, 2006 (15.79 KB) April 20, 2006 (19.91 KB) March 9, 2006 (19.65 KB) January 26, 2006 (20.86 KB) November 9, 2005 (24.38 KB) September 15, 2005 (32.13 KB) April 28, 2005 (19.16 KB) March 24, 2005 (28.33 KB) February 24, 2005 (32.77

  8. TEC Working Group Topic Groups | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic Groups TEC Working Group Topic Groups TEC Topic Groups were formed in 1991 following an evaluation of the TEC program. Interested members, DOE and other federal agency staff meet to examine specific issues related to radioactive materials transportation. TEC Topic Groups enable a small number of participants to focus intensively on key issues at a level of detail that is unattainable during the TEC semiannual meetings due to time and group size constraints. Topic Groups meet individually

  9. Kokes Awards for the 22nd North American Catalysis Society Meeting, June 5-10, 2011

    SciTech Connect (OSTI)

    Fabio H. Ribeiro

    2011-06-05

    The biennial North American Catalysis Society (NACS) Meetings are the premiere conferences in the area of catalysis, surface science, and reaction engineering. The 22nd meeting will be held the week of June 5-10, 2011 in Detroit, Michigan. The objective of the Meetings is to bring together leading researchers for intensive scientific exchange and interactions. Financial support that offsets some of the associated costs (specifically, registration fee, airline tickets, and hotel accommodations) would encourage graduate students, and for the first time undergraduate students, to attend and participate meaningfully in this conference. The funds sought in this proposal will help support the Richard J. Kokes Travel Award program. Graduate students eligible for these merit-based Awards are those who study at a North American university and who will present at the Meeting. We have currently 209 applications and we expect to be able to fund about half of them. The NACS has traditionally sought to encourage graduate student, and this year for the first time undergraduate studies, participation at the National Meetings and providing financial support is the most effective means to do so. Their attendance would contribute significantly to their scientific training and communication and presentation skills. They would be exposed to the leading researchers from the US and abroad; they would meet their peers from other universities; they would learn about cutting-edge results that could benefit their research projects; and they may become interested in becoming active participants in the catalysis community. These young investigators represent the next generation of scientists and engineers, and their proper training will lead to future scientific breakthroughs and technological innovations that benefit the US economy. Advances in catalysis can come in the form of more energy-efficient and environmentally-friendly chemical processes, improved fuel cell performance, efficient

  10. Kokes Awards for the 23rd North American Catalysis Society Meeting

    SciTech Connect (OSTI)

    Jacobs, Gary

    2014-01-31

    The Tri-State Catalysis Society awarded 107 Kokes Travel Awards. The program was very successful and to date this was the most Kokes Travel Awards ever awarded at a North American Catalysis Society Meeting. It provided students who merited an award the opportunity to attend the meeting, present a paper in the form of either an oral presentation or a poster presentation, and to serve the North American Catalysis Society by participating in the organization of the meeting. Students worked very hard during the week of the meeting to make it a success. Financial support for the Kokes awards was provided by DOE, NSF, NACS, as well as the Tri-State Catalysis Society, the latter through fund raising activities, and other donations. AT the meeting, each student received over $1050 in kind to offset the costs of registration fees ($260), hotel accommodations ($295.7), transportation ($400 travel allowance), as well as T-shirts ($20), and banquet tickets ($95 provided by donations from society members). In addition, for the first time, students received certificates that were signed by the President of NACS, Professor Enrique Iglesia, and by the Kokes Awards Chair, Gary Jacobs (see last page). A list of meeting co-chairs (i.e., Uschi M. Graham, Umit S. Ozkan, and Madan Bhassin) and the honorary chair (Burtron H. Davis) was also included on the certificate, along with the name of the recipient. The awardees were chosen on a merit-based guideline which also included the requirements of having a presentation accepted at the meeting and being a student at a North American University. The Richard J. Kokes Student Travel Award Committee (Gary Jacobs, Rodney Andrews, and Peter Smirniotis) with help from the Organizing Committee were able to secure money from four sources as detailed in Table 1. As detailed by our Treasurer, Dr. Helge Toufar of Clariant, the total amount spent was $105,000.

  11. NMR Computational Studies of Solid Acidity/Fundamental Studies of Catalysis by Solid Acids

    SciTech Connect (OSTI)

    James F. Haw

    2008-06-28

    This project focused on catalysis by zeolites and the synergy of spectroscopic characterization and theoretical modeling. In collaboration with the Waroquier group in Belgium we used state-of-the-art quantum chemical simulations on a supramolecular model of both the HZSM-5 zeolite and the co-catalytic hydrocarbon pool species and calculated a full catalytic cycle (including all rate constants) for methanol-to-olefin (MTO) catalysis involving a hydrocarbon pool species. This work not only represents the most robust computational analysis of a successful MTO route to date, but it also succeeds in tying together the many experimental clues. That work was featured on the cover of Angewandte Chemie. More recently we elucidated several unsuspected roles for formaldehyde in methanol to olefin catalysis. Formaldehyde proves to be a key species responsible for both the growth of the catalytically active hydrocarbon pool and its inevitable aging into deactivated polycyclic aromatic species. The apparent inevitability of formaldehyde formation at high temperatures, in particular in contact with active metal or metal oxide surfaces, may put some fundamental limitations on the economic potential of conversion of methanol to olefins.

  12. Preface to Special Topic: Marine Renewable Energy

    SciTech Connect (OSTI)

    Pinto, F. T.; Iglesias, G.; Santos, P. R.; Deng, Zhiqun

    2015-12-30

    Marine renewable energy (MRE) is generates from waves, currents, tides, and thermal resources in the ocean. MRE has been identified as a potential commercial-scale source of renewable energy. This special topic presents a compilation of works selected from the 3rd IAHR Europe Congress, held in Porto, Portugal, in 2014. It covers different subjects relevant to MRE, including resource assessment, marine energy sector policies, energy source comparisons based on levelized cost, proof-of-concept and new-technology development for wave and tidal energy exploitation, and assessment of possible inference between wave energy converters (WEC).

  13. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    April 4, 2005 - Phoenix, AZ Group Chair: Jay Jones (DOE/OCRWM) Tribal Topic Group Members Present: Nancy Bennett (UNM/ATRI), Kevin Blackwell (DOT/FRA), Kristen Ellis (DOE/CI), Ed Gonzales (ELG), Elizabeth Helvey (BSC), Jeff Hepting (Pueblo of Acoma), Robert Holden (NCAI), Judith Holm (DOE/OCRWM), Dan King (Oneida Nation), Gary Lanthrum (DOE/OCRWM), Bob Lupton (DOE/ORD/IR), Corinne Macaluso (DOE/OCRWM), Ellen Ott (DOE/GC), Jennifer Patric (BAH), Stanley Paytiamo (Pueblo of Acoma), Wilda Portner

  14. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support of HCCI Emission Control

    Broader source: Energy.gov [DOE]

    Development of catalyst materials to facilitate the low-temperature oxidation of hydrocarbons and CO in homogeneous charge compression ignition (HCCI) emissions.

  15. Homogeneous charge engines -- Basis of cyclic variations. Final report

    SciTech Connect (OSTI)

    Whitelaw, J.H.

    1997-06-30

    The objectives of the Grant required investigations of cyclic variations in a homogeneous-charge engine initially with gas combustion and the air from ranging from near quiescent to the incorporation of swirl and tumble by valve inserts. Later experiments were performed with unleaded gasoline. The measurements included local velocity and cylinder pressure through the four strokes of a single-cylinder engine, under motored and firing conditions and with examination of the flame kernel growth by combinations of photography and flame-ionization gauges. In all cases, the measurements of in-cylinder characteristics were linked to performance as measured in terms of speed and its variability, load and emissions. The experiments progressed to consider deviations from homogeneous charge and included consideration of stratified charge with local injection of a rich mixture in the vicinity of the spark gap so as to establish a flame kernel which would propagate securely into an overall weak mixture.

  16. Apparatus for unilateral generation of a homogeneous magnetic field

    DOE Patents [OSTI]

    Fukushima, Eiichi; Rath, Alan R.; Roeder, Stephen B. W.

    1988-01-01

    An apparatus for unilaterally producing a substantially homogeneous magnetic field. The apparatus includes two circular electromagnet coils, a small coil and a large coil, which are coaxial with one another and which are separated by a distance equal to one-half the difference in the radius of the two coils. By appropriate selection of electrical currents, which are passed through the coil in opposite directions, a region of homogeneous magnetic field is formed. This region is centered on the common axis of the two coils, at a point on the axis which is at a distance from the small coil equal to one-half the radius of the small coil, and which is on the opposite side of the small coil from the large coil. The apparatus has particular application in the field of diagnostic medical NMR and other NMR applications.

  17. Apparatus for unilateral generation of a homogeneous magnetic field

    DOE Patents [OSTI]

    Fukushima, E.; Rath, A.R.; Roeder, S.B.W.

    1984-05-01

    An apparatus for unilaterally producing a substantially homogeneous magnetic field. The apparatus includes two circular electromagnet coils, a small coil and a large coil, which are coaxial with one another and which are separated by a distance equal to one-half the difference in the radius of the two coils. By appropriate selection of electrical currents, which are passed through the coils in opposite directions, a region of homogeneous magnetic field is formed. This region is centered on the common axis of the two coils, at a point on the axis which is at a distance from the small coil equal to one-half the radius of the small coil, and which is on the opposite side of the small coil from the large coil. The apparatus has particular application in the field of diagnostic medical NMR and other NMR applications.

  18. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Missouri Botanical Garden- EarthWays Center October 6, 2015 - 4:00pm How...

  19. OSTIblog Articles in the science information Topic | OSTI, US...

    Office of Scientific and Technical Information (OSTI)

    The search engine that helps you find science information from U.S. Department of Energy ... Science News and Wikipedia information on your topic(s) of interest and clusters results ...

  20. Hot Topics Workshop - February 2015 | Photosynthetic Antenna Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center - February 2015 Hot Topics Workshop - February 2015 Shots from our Hot Topics Workshop: Energy and the Environment for Secondary Science Teachers. Original Event Info found here

  1. TEC Working Group Topic Groups Rail Conference Call Summaries | Department

    Office of Environmental Management (EM)

    of Energy Rail Conference Call Summaries TEC Working Group Topic Groups Rail Conference Call Summaries CONFERENCE CALL SUMMARIES Rail Topic Group Inspections Subgroup Planning Subgroup Tracking Subgroup TRAGIS Subgroup Radiation Monitoring Subgroup Intermodel Subgroup

  2. Simulator for SUPO, a Benchmark Aqueous Homogeneous Reactor (AHR)

    SciTech Connect (OSTI)

    Klein, Steven Karl; Determan, John C.

    2015-10-14

    A simulator has been developed for SUPO (Super Power) an aqueous homogeneous reactor (AHR) that operated at Los Alamos National Laboratory (LANL) from 1951 to 1974. During that period SUPO accumulated approximately 600,000 kWh of operation. It is considered the benchmark for steady-state operation of an AHR. The SUPO simulator was developed using the process that resulted in a simulator for an accelerator-driven subcritical system, which has been previously reported.

  3. High load operation in a homogeneous charge compression ignition engine

    SciTech Connect (OSTI)

    Duffy, Kevin P.; Kieser, Andrew J.; Liechty, Michael P.; Hardy, William L.; Rodman, Anthony; Hergart, Carl-Anders

    2008-12-23

    A homogeneous charge compression ignition engine is set up by first identifying combinations of compression ratio and exhaust gas percentages for each speed and load across the engines operating range. These identified ratios and exhaust gas percentages can then be converted into geometric compression ratio controller settings and exhaust gas recirculation rate controller settings that are mapped against speed and load, and made available to the electronic

  4. Multicomponent homogeneous alloys and method for making same

    DOE Patents [OSTI]

    Dutta, Partha S.; Miller, Thomas R.

    2003-09-02

    The present application discloses a method for preparing a homogeneous ternary or quaternary alloy from a quaternary melt. The method includes providing a family of phase diagrams for the quaternary melt which shows (i) composition/temperature data, (ii) tie lines connecting equilibrium liquid and solid compositions, and (iii) isotherms representing boundaries of a miscibility gap. Based on the family of phase diagrams, a quaternary melt composition and an alloy growth temperature is selected. A quaternary melt having the selected quaternary melt composition is provided and a ternary or quaternary alloy is grown from the quaternary melt at the selected alloy growth temperature. A method for making homogeneous ternary or quaternary alloy from a ternary or quaternary melt is also disclosed, as are homogeneous quaternary single-crystal alloys which are substantially free from crystal defects and which have the formula A.sub.x B.sub.1-x C.sub.y D.sub.1-y, x and y being the same or different and in the range of 0.001 to 0.999.

  5. OSTIblog Articles in the Strategic Plan Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    and nuclear challenges through transformative science and technology solutions. The... Related Topics: clean energy, nuclear security, Science Accelerator, Strategic Plan

  6. TEC Working Group Topic Groups Archives Communications Meeting Summaries |

    Office of Environmental Management (EM)

    Department of Energy Archives Communications Meeting Summaries TEC Working Group Topic Groups Archives Communications Meeting Summaries Meeting Summaries Milwaukee TEC Meeting, Communications Topic Group Summary - July 1998 (58.3 KB) Inaugural Group Meeting - April 1998 (83.34 KB) More Documents & Publications TEC Working Group Topic Groups Archives Communications Conference Call Summaries TEC Meeting Summaries - January 1997 TEC Working Group Topic Groups Tribal Conference Call

  7. Webtrends Archives by Fiscal Year — Topic Landing Pages

    Broader source: Energy.gov [DOE]

    From the EERE Web Statistics Archive: Corporate sites, Webtrends archives for the topic landing pages by fiscal year.

  8. Smart Grid Investment Grant Topic Areas | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic Areas Smart Grid Investment Grant Topic Areas A description of the topic areas for projects selected for award under the Smart Grid Investment Grant project of the American Recovery and Reinvestment Act. Smart Grid Investment Grant Topic Areas (25.19 KB) More Documents & Publications Smart Grid Investment Grant Program - Progress Report (July 2012) SGIG and SGDP Highlights: Jumpstarting a Modern Grid (October 2014) Smart Grid R&D Multi-Year Program Plan (2010-2014) - September 2011

  9. TEC Working Group Topic Groups Archives Protocols Meeting Summaries |

    Office of Environmental Management (EM)

    Department of Energy Protocols Meeting Summaries TEC Working Group Topic Groups Archives Protocols Meeting Summaries Meeting Summaries Philadelphia TEC Meeting, Protocols Topic Group Summary - July 1999 (110.63 KB) Jacksonville TEC Meeting, Protocols Topic Group Summary - January 1999 (102.04 KB) More Documents & Publications TEC Working Group Topic Groups Archives Protocols Conference Call Summaries TEC Meeting Summaries - July 1997 TEC Meeting Summaries - January 1997

  10. TEC Working Group Topic Groups Rail Conference Call Summaries Inspections

    Office of Environmental Management (EM)

    Subgroup | Department of Energy Summaries Inspections Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Inspections Subgroup Inspections Subgroup April 6, 2006 (14.05 KB) February 23, 2006 Draft (20.29 KB) January 24, 2006 (27.44 KB) More Documents & Publications TEC Working Group Topic Groups Rail Conference Call Summaries Planning Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Tracking Subgroup TEC Working Group Topic Groups Rail Conference

  11. TEC Working Group Topic Groups Rail Key Documents Radiation Monitoring

    Office of Environmental Management (EM)

    Subgroup | Department of Energy Radiation Monitoring Subgroup TEC Working Group Topic Groups Rail Key Documents Radiation Monitoring Subgroup Radiation Monitoring Subgroup Draft Work Plan - February 4, 2008 (114.02 KB) More Documents & Publications TEC Working Group Topic Groups Rail Meeting Summaries TEC Working Group Topic Groups Rail Conference Call Summaries Radiation Monitoring Subgroup TEC Working Group Topic Groups Rail Key Documents Intermodal Subgroup

  12. TEC Working Group Topic Groups Archives Protocols | Department of Energy

    Office of Environmental Management (EM)

    Protocols TEC Working Group Topic Groups Archives Protocols The Transportation Protocols Topic Group serves as an important vehicle for DOE senior managers to assess and incorporate stakeholder input into the protocols process. The Topic Group was formed to review a series of transportation protocols developed in response to a request for DOE to be more consistent in its approach to transportation.

  13. TEC Working Group Topic Groups Section 180(c) Meeting Summaries |

    Office of Environmental Management (EM)

    Department of Energy Section 180(c) Meeting Summaries TEC Working Group Topic Groups Section 180(c) Meeting Summaries Meeting Summaries Washington, DC TEC Meeting - 180(c) Group Summary - March 15, 2006 (29.33 KB) More Documents & Publications TEC Working Group Topic Groups Tribal Meeting Summaries TEC Meeting Summaries - July 2007 TEC Working Group Topic Groups Tribal Conference Call Summaries

  14. OSTIblog Articles in the 9 Topic | OSTI, US Dept of Energy Office of

    Office of Scientific and Technical Information (OSTI)

    Scientific and Technical Information 9 Topic No topics or articles found

  15. Search tool plug-in: imploements latent topic feedback

    Energy Science and Technology Software Center (OSTI)

    2011-09-23

    IRIS is a search tool plug-in that is used to implement latent topic feedback for enhancing text navigation. It accepts a list of returned documents from an information retrieval wywtem that is generated from keyword search queries. Data is pulled directly from a topic information database and processed by IRIS to determine the most prominent and relevant topics, along with topic-ngrams, associated with the list of returned documents. User selected topics are then used tomore » expand the query and presumabley refine the search results.« less

  16. Electric-field enhanced performance in catalysis and solid-state devices involving gases

    DOE Patents [OSTI]

    Blackburn, Bryan M.; Wachsman, Eric D.; Van Assche, IV, Frederick Martin

    2015-05-19

    Electrode configurations for electric-field enhanced performance in catalysis and solid-state devices involving gases are provided. According to an embodiment, electric-field electrodes can be incorporated in devices such as gas sensors and fuel cells to shape an electric field provided with respect to sensing electrodes for the gas sensors and surfaces of the fuel cells. The shaped electric fields can alter surface dynamics, system thermodynamics, reaction kinetics, and adsorption/desorption processes. In one embodiment, ring-shaped electric-field electrodes can be provided around sensing electrodes of a planar gas sensor.

  17. Controlling And Operating Homogeneous Charge Compression Ignition (Hcci) Engines

    SciTech Connect (OSTI)

    Flowers, Daniel L.

    2005-08-02

    A Homogeneous Charge Compression Ignition (HCCI) engine system includes an engine that produces exhaust gas. A vaporization means vaporizes fuel for the engine an air induction means provides air for the engine. An exhaust gas recirculation means recirculates the exhaust gas. A blending means blends the vaporized fuel, the exhaust gas, and the air. An induction means inducts the blended vaporized fuel, exhaust gas, and air into the engine. A control means controls the blending of the vaporized fuel, the exhaust gas, and the air and for controls the inducting the blended vaporized fuel, exhaust gas, and air into the engine.

  18. Exhaust gas recirculation in a homogeneous charge compression ignition engine

    SciTech Connect (OSTI)

    Duffy, Kevin P.; Kieser, Andrew J.; Rodman, Anthony; Liechty, Michael P.; Hergart, Carl-Anders; Hardy, William L.

    2008-05-27

    A homogeneous charge compression ignition engine operates by injecting liquid fuel directly in a combustion chamber, and mixing the fuel with recirculated exhaust and fresh air through an auto ignition condition of the fuel. The engine includes at least one turbocharger for extracting energy from the engine exhaust and using that energy to boost intake pressure of recirculated exhaust gas and fresh air. Elevated proportions of exhaust gas recirculated to the engine are attained by throttling the fresh air inlet supply. These elevated exhaust gas recirculation rates allow the HCCI engine to be operated at higher speeds and loads rendering the HCCI engine a more viable alternative to a conventional diesel engine.

  19. Application of lidar to current atmospheric topics

    SciTech Connect (OSTI)

    Sedlacek, A.J. III

    1996-12-31

    The goal of the conference was to address the various applications of lidar to topics of interest in the atmospheric community. Specifically, with the development of frequency-agile, all solid state laser systems, high-quantum-efficiency detectors, increased computational power along with new and more powerful algorithms, and novel detection schemes, the application of lidar to both old and new problems has expanded. This expansion is evidenced by the contributions to the proceedings, which demonstrate the progress made on a variety of atmospheric remote sensing problems, both theoretically and experimentally. The first session focused on aerosol, ozone, and temperature profile measurements from ground-based units. The second session, Chemical Detection, provided applications of lidar to the detection of atmospheric pollutants. Papers in the third session, Wind and Turbulence Measurements, described the Multi-center Airborne Coherent Atmospheric Wind Sensor (MACAWS) experiments, Doppler techniques for ground-based wind profiling and mesopause radial wind and temperature measurements utilizing a frequency-agile lidar system. The papers in the last two sessions, Recent Advanced in Lidar Technology and Techniques and Advanced Operational Lidars, provided insights into novel approaches, materials, and techniques that would be of value to the lidar community. Papers have been processed separately for inclusion on the data base.

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... (5) hydrogenation (5) catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, materials and chemistry by design, ...

  1. In Situ Electron Energy-Loss Spectroscopy in Liquids (Journal...

    Office of Scientific and Technical Information (OSTI)

    Subject: catalysis (homogeneous), catalysis (heterogeneous), energy storage (including batteries and capacitors), hydrogen and fuel cells, defects, charge transport, membrane, ...

  2. Multiferroicity of Carbon-Based Charge-Transfer Magnets (Journal...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Energy Frontier Research Centers (EFRC); Argonne-Northwestern Solar Energy ... Subject: catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar ...

  3. Charge-Transfer Induced Magnetic Field Effects of Nano-Carbon...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Energy Frontier Research Centers (EFRC); Argonne-Northwestern Solar Energy ... Subject: catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar ...

  4. Understanding catalysis in a multiphasic two-dimensional transition metal dichalcogenide.

    SciTech Connect (OSTI)

    Chou, Stanley Shihyao; Sai, Na; Lu, Ping; Coker, Eric Nicholas; Liu, Sheng; Artyushkova, Kateryna; Luk, Ting S.; Kaehr, Bryan James; Brinker, C. Jeffrey

    2015-10-07

    Establishing processing–structure–property relationships for monolayer materials is crucial for a range of applications spanning optics, catalysis, electronics and energy. Presently, for molybdenum disulfide, a promising catalyst for artificial photosynthesis, considerable debate surrounds the structure/property relationships of its various allotropes. Here we unambiguously solve the structure of molybdenum disulfide monolayers using high-resolution transmission electron microscopy supported by density functional theory and show lithium intercalation to direct a preferential transformation of the basal plane from 2H (trigonal prismatic) to 1T' (clustered Mo). These changes alter the energetics of molybdenum disulfide interactions with hydrogen (ΔGH), and, with respect to catalysis, the 1T' transformation renders the normally inert basal plane amenable towards hydrogen adsorption and hydrogen evolution. Furthermore, we show basal plane activation of 1T' molybdenum disulfide and a lowering of ΔGH from +1.6 eV for 2H to +0.18 eV for 1T', comparable to 2H molybdenum disulfide edges on Au(111), one of the most active hydrogen evolution catalysts known.

  5. Understanding catalysis in a multiphasic two-dimensional transition metal dichalcogenide.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chou, Stanley Shihyao; Sai, Na; Lu, Ping; Coker, Eric Nicholas; Liu, Sheng; Artyushkova, Kateryna; Luk, Ting S.; Kaehr, Bryan James; Brinker, C. Jeffrey

    2015-10-07

    Establishing processing–structure–property relationships for monolayer materials is crucial for a range of applications spanning optics, catalysis, electronics and energy. Presently, for molybdenum disulfide, a promising catalyst for artificial photosynthesis, considerable debate surrounds the structure/property relationships of its various allotropes. Here we unambiguously solve the structure of molybdenum disulfide monolayers using high-resolution transmission electron microscopy supported by density functional theory and show lithium intercalation to direct a preferential transformation of the basal plane from 2H (trigonal prismatic) to 1T' (clustered Mo). These changes alter the energetics of molybdenum disulfide interactions with hydrogen (ΔGH), and, with respect to catalysis, the 1T' transformationmore » renders the normally inert basal plane amenable towards hydrogen adsorption and hydrogen evolution. Furthermore, we show basal plane activation of 1T' molybdenum disulfide and a lowering of ΔGH from +1.6 eV for 2H to +0.18 eV for 1T', comparable to 2H molybdenum disulfide edges on Au(111), one of the most active hydrogen evolution catalysts known.« less

  6. Proton Mediated Chemistry and Catalysis in a Self-Assembled Supramolecular Host

    SciTech Connect (OSTI)

    Pluth, Michael; Bergman, Robert; Raymond, Kenneth

    2009-04-10

    Synthetic supramolecular host assemblies can impart unique reactivity to encapsulated guest molecules. Synthetic host molecules have been developed to carry out complex reactions within their cavities, despite the fact that they lack the type of specifically tailored functional groups normally located in the analogous active sites of enzymes. Over the past decade, the Raymond group has developed a series of self-assembled supramolecules and the Bergman group has developed and studied a number of catalytic transformations. In this Account, we detail recent collaborative work between these two groups, focusing on chemical catalysis stemming from the encapsulation of protonated guests and expanding to acid catalysis in basic solution. We initially investigated the ability of a water-soluble, self-assembled supramolecular host molecule to encapsulate protonated guests in its hydrophobic core. Our study of encapsulated protonated amines revealed rich host-guest chemistry. We established that self-exchange (that is, in-out guest movement) rates of protonated amines were dependent on the steric bulk of the amine rather than its basicity. The host molecule has purely rotational tetrahedral (T) symmetry, so guests with geminal N-methyl groups (and their attendant mirror plane) were effectively desymmetrized; this allowed for the observation and quantification of the barriers for nitrogen inversion followed by bond rotation. Furthermore, small nitrogen heterocycles, such as N-alkylaziridines, N-alkylazetidines, and N-alkylpyrrolidines, were found to be encapsulated as proton-bound homodimers or homotrimers. We further investigated the thermodynamic stabilization of protonated amines, showing that encapsulation makes the amines more basic in the cavity. Encapsulation raises the effective basicity of protonated amines by up to 4.5 pK{sub a} units, a difference almost as large as that between the moderate and strong bases carbonate and hydroxide. The thermodynamic stabilization

  7. Manufacturing Innovation Multi-Topic Workshop Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing Innovation Multi-Topic Workshop Report Manufacturing Innovation Multi-Topic Workshop Report The U.S. Department of Energy (DOE) and Department of Defense (DoD) held a Manufacturing Innovation Topics Workshop on October 8 and 9, 2014. Representatives from industry, academia, DOE national laboratories, and DoD centers gathered in Fort Worth TX to hear keynote addresses and participate in workshop breakout sessions. The Workshop Report is listed below. U.S DOE and DoD Manufacturing

  8. Fossil Energy Technical Assistance Topic Areas | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Energy Technical Assistance Topic Areas Fossil Energy Technical Assistance Topic Areas Potential Technical Assistance Topic Areas in the Office of Fossil Energy EPA Regulations - Analysis to Support Planning Contact: Jordan Kislear Storage Infrastructure Contact: Mark Ackiewicz Major Demonstrations Contact: Joe Giove Department of Energy and National Association of Regulatory Utility Commissioners (NARUC) Contact: Doug Middleton Fossil Capacity and Resources in Your State or Region

  9. Energy Department Announces New Grant Topics to Help Small Businesses

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Develop Clean Energy Technologies | Department of Energy Grant Topics to Help Small Businesses Develop Clean Energy Technologies Energy Department Announces New Grant Topics to Help Small Businesses Develop Clean Energy Technologies October 27, 2014 - 2:41pm Addthis The Energy Department's Office of Energy Efficiency and Renewable Energy (EERE) today announced nine topics and 26 new subtopics under its Small Business Innovation Research (SBIR) and Technology Transfer (STTR) programs that

  10. Integrated Operation Scenarios ITPA Topical Group Meeting | Princeton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plasma Physics Lab 20, 2010, 9:00am to April 23, 2010, 5:00pm Conference Princeton, NJ Integrated Operation Scenarios ITPA Topical Group Meeting Integrated Operation Scenarios ITPA Topical Group Meeting Contact Information Website: Integrated Operation Scenarios ITPA Topical Group Meeting Coordinator(s): Kathleen Lukazik KLukazik@pppl.gov Host(s): Chuck Kessel ckessel@pppl.gov PPPL Entrance Procedures Visitor Information, Directions, Security at PPPL As a federal facility, the Princeton

  11. TEC Working Group Topic Groups Archives Communications Conference Call

    Office of Environmental Management (EM)

    Summaries | Department of Energy Communications Conference Call Summaries TEC Working Group Topic Groups Archives Communications Conference Call Summaries Conference Call Summaries Conference Call Summary April 2000 (91.86 KB) Conference Call Summary February 1999 (11.81 KB) Conference Call Summary November 1998 (54.77 KB) More Documents & Publications TEC Working Group Topic Groups Archives Communications Meeting Summaries TEC Working Group Topic Groups Tribal Conference Call Summaries

  12. TEC Working Group Topic Groups Archives Communications | Department of

    Office of Environmental Management (EM)

    Energy Communications TEC Working Group Topic Groups Archives Communications The Communications Topic Group was convened in April 1998 to improve internal and external strategic level communications regarding DOE shipments of radioactive and other hazardous materials. Major issues under consideration by this Topic Group include: - Examination of DOE external and internal communications processes; - Roles and responsibilities when communicating with a diverse range of stakeholders; and -

  13. TEC Working Group Topic Groups Archives Training - Medical Training |

    Office of Environmental Management (EM)

    Department of Energy Training - Medical Training TEC Working Group Topic Groups Archives Training - Medical Training The TEC Training and Medical Training Issues Topic Group was formed to address the training issues for emergency responders in the event of a radioactive material transportation incident. The Topic Group first met in 1996 to assist DOE in developing an approach to address radiological emergency response training needs and to avoid redundancy of existing training materials. The

  14. TEC Working Group Topic Groups Rail Archived Documents | Department of

    Office of Environmental Management (EM)

    Energy Archived Documents TEC Working Group Topic Groups Rail Archived Documents ARCHIVED DOCUMENTS Inspections Summary Matrix (49.36 KB) TEC Transportation Safety WIPP-PIG Rail Comparison (130.46 KB) Regulatory Summary Matrix (62.08 KB) More Documents & Publications TEC Working Group Topic Groups Rail Key Documents TEC Working Group Topic Groups Rail Meeting Summaries TEC Meeting Summaries - September 2005 Presentations

  15. TEC Working Group Topic Groups Security Key Documents | Department of

    Office of Environmental Management (EM)

    Energy Key Documents TEC Working Group Topic Groups Security Key Documents Key Documents Security TG Work Plan August 7, 2006 (24.31 KB) Security Lessons Learned Document August 2, 2006 (40.77 KB) Security Module (635.1 KB) STG Terms and Definitions from DOE 470.4 (18.54 KB) More Documents & Publications TEC Working Group Topic Groups Security Meeting Summaries TEC Meeting Summaries - April 2005 Presentations TEC Working Group Topic Groups Security Conference Call Summaries

  16. TEC Working Group Topic Groups Security Meeting Summaries | Department of

    Office of Environmental Management (EM)

    Energy Meeting Summaries TEC Working Group Topic Groups Security Meeting Summaries Meeting Summaries Green Bay STG Meeting Summary- September 14, 2006 (28.22 KB) Washington STG Meeting Summary - March 14, 2006 (25.61 KB) Pueblo STG Meeting Summary - September 22, 2005 (18.7 KB) More Documents & Publications TEC Working Group Topic Groups Security Conference Call Summaries TEC Meeting Summaries - September 2006 TEC Working Group Topic Groups Security Key Documents

  17. TRIBAL ISSUES TOPIC GROUP MEETING SUMMARY Milwaukee, WI July 1998

    Office of Environmental Management (EM)

    Milwaukee, WI July 1998 The Topic Group is developing a process to identify appropriate Topic Group membership, and will be working on a protocol for identifying and inviting individual tribes to participate he group identified five actions: (1) catalogue tribal transportation issues; (2) identify a level of tribal awareness of DOE transportation issues; (3) examine funding and tribal support; (4) develop a process for Tribal Topic Group membership; and (5) review the best channels to

  18. Physics Topics - Plasma Couette Experiment - Cary Forest Group - UW Plasma

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Physics Topics UW Madison Plasma Couette Experiment Physics Topics PCX HomeResearch MissionPhysics TopicsDeviceDiagnosticsContacts LinksPCX People CPLA Home Directory Publications Links University of Wisconsin Physics Department Department of Energy National Science Foundation Accretion Accretion is a fundamental process in astrophysics by which virtually all astrophysical bodies are formed. Due to gravity, the interstellar gas and plasma collapses into rotating disks around the

  19. Physics Topics - Rotating Wall Machine - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics UW Madison Line Tied Reconnection Experiment Physics Topics LTRX HomeResearch MissionLTRX DevicePhysics TopicsDiagnosticsLTRX GalleryLTRX People CPLA Home Directory Publications Links University of Wisconsin Physics Department Department of Energy National Science Foundation Reconnection in a line-tied plasma Stability of zero-net-current equilibria Stability of hollow current equilibria Magnetic Launching of Astrophysical Jets

  20. Interconnection-Wide Transmission Planning Initiative: Topic A,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Interconnection-Level Analysis and Planning | Department of Energy A, Interconnection-Level Analysis and Planning Interconnection-Wide Transmission Planning Initiative: Topic A, Interconnection-Level Analysis and Planning A description of the requirements for Topic A for all Interconnections under the Interconnection-Wide Transmission Planning Initiative, part of the American Recovery and Reinvestment Act. Interconnection-Wide Transmission Planning Initiative: Topic A, Interconnection-Level

  1. 2013 February POTENTIAL COMMITTEE MEETING TOPICS HAB Committee: RAP

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    Page 1 of 3 2013 February POTENTIAL COMMITTEE MEETING TOPICS HAB Committee: RAP Committee meeting: Tuesday, February 12 from 9 a.m. - 4 p.m. Agenda Topic When is HAB input needed? Issue Managers (* = lead) Agency Lead(s) Time to Allocate (minutes) Title: Framing Discussion: Central Plateau Groundwater and Vadose Zone Modeling (JOINT TOPIC W/ TWC) 2013 Priority: Groundwater Modeling Purpose: To hear a report-out from issue managers on their work regarding Central Plateau groundwater and vadose

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  6. Focus Group Meeting (Topical Wrap-Up) | Department of Energy

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    Wrap-Up) Focus Group Meeting (Topical Wrap-Up) Meeting Date: December 4, 2008 Meeting Agenda, Summary and Informational Materials Documents Available for Download Meeting Agenda (22 KB) Meeting Summary (83.05 KB) 2008 Topical Meeting Executive Summaries and Actions Lists (90.46 KB) Union Topical Priorities - 2008 (32.86 KB) Draft Topical Action Matrix - 2008 (81.56 KB) HSS Office of Worker Health and Safety Former Worker/EEOIPCA Activities and Initiatives (41.3 KB) HSS/Union Training Work

  7. Small Business Innovation Research Program Topics- October 28, 2013

    Office of Energy Efficiency and Renewable Energy (EERE)

    This document outlines the topics covered by the 2013-14 SBIR funding opportunity announcement and show the details of how to apply for the program.

  8. OSTIblog Articles in the Supercomputers Topic | OSTI, US Dept...

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  12. HEC-DPSSL 2012 Workshop, Topics: National Ignition Facility ...

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    Potential Session Topics High Power Diode Arrays Laser Gain Media Laser Damage Resistance Thermal ModelingResults GainParasitics ModelingResults Laser Propagation Modeling ...

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    a certain critical temperature, and the sharp difference between the densities of water and water vapor disappears above a critical pressure. ... Related Topics: bettencourt, ...

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    a certain critical temperature, and the sharp difference between the densities of water and water vapor disappears above a critical pressure. ... Related Topics: bettencourt, ...

  17. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

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    Technologies campus, followed by a brief presentation. Topics will include home automation, the internet of things, wireless sensor networks and other smart technologies. The...

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  1. Crystallization in supercooled liquid Cu: Homogeneous nucleation and growth

    SciTech Connect (OSTI)

    E, J. C.; Wang, L.; Luo, S. N.; Cai, Y.; Wu, H. A.

    2015-02-14

    Homogeneous nucleation and growth during crystallization of supercooled liquid Cu are investigated with molecular dynamics simulations, and the microstructure is characterized with one- and two-dimensional x-ray diffraction. The resulting solids are single-crystal or nanocrystalline, containing various defects such as stacking faults, twins, fivefold twins, and grain boundaries; the microstructure is subject to thermal fluctuations and extent of supercooling. Fivefold twins form via sequential twinning from the solid-liquid interfaces. Critical nucleus size and nucleation rate at 31% supercooling are obtained from statistical runs with the mean first-passage time and survival probability methods, and are about 14 atoms and 10{sup 32} m{sup −3}s{sup −1}, respectively. The bulk growth dynamics are analyzed with the Johnson-Mehl-Avrami law and manifest three stages; the Avrami exponent varies in the range of 1–19, which also depends on thermal fluctuations and supercooling.

  2. The manufacture and performance of homogeneous microstructure SBR MOX fuel

    SciTech Connect (OSTI)

    Barker, Matthew A.; Stephenson, Keith; Weston, Rebecca

    2007-07-01

    In the early 1980's, British experience in the manufacture of mixed-oxide fast reactor fuel was used to develop a new thermal MOX manufacturing route called the Short Binder-less Route (SBR). Laboratory- scale development led to the manufacture of commercial PWR fuel in a small pilot plant, and the construction of the full-scale dual-line Sellafield MOX Plant (SMP). SMP's first MOX assemblies are now under irradiation. SBR MOX is manufactured with 100% co-milled feedstock, leading to a microstructure dominated by a solid solution of (U,Pu)O{sub 2} at the nominal enrichment. A comprehensive fuel performance research programme has demonstrated the benign performance of SBR MOX up to 54 MWd/kgHM. In particular, the homogeneous microstructure is believed to be instrumental in the favourable fission gas retention and PCI resistance properties. (authors)

  3. Homogenization limit for a multiband effective mass model in heterostructures

    SciTech Connect (OSTI)

    Morandi, O.

    2014-06-15

    We study the homogenization limit of a multiband model that describes the quantum mechanical motion of an electron in a quasi-periodic crystal. In this approach, the distance among the atoms that constitute the material (lattice parameter) is considered a small quantity. Our model include the description of materials with variable chemical composition, intergrowth compounds, and heterostructures. We derive the effective multiband evolution system in the framework of the kp approach. We study the well posedness of the mathematical problem. We compare the effective mass model with the standard kp models for uniform and non-uniforms crystals. We show that in the limit of vanishing lattice parameter, the particle density obtained by the effective mass model, converges to the exact probability density of the particle.

  4. Application of cryogenic grinding to achieve homogenization of transuranic wastes

    SciTech Connect (OSTI)

    Atkins, W.H.; Hill, D.D.; Lucero, M.E.; Jaramillo, L.; Martinez, H.E.

    1996-08-01

    This paper describes work done at Los Alamos National Laboratory (LANL) in collaboration with the Department of Energy Rocky Flats Field Office (DOE/RFFO) and with the National Institute of Standards and Technology (NIST), Boulder, Colorado. Researchers on this project have developed a method for cryogenic grinding of mixed wastes to homogenize and, thereby, to acquire a representative sample of the materials. There are approximately 220,000 waste drums owned by the Rocky Flats Environmental Technology Site (RFETS)-50,000 at RFETS and 170,000 at the Idaho National Engineering Laboratory. The cost of sampling the heterogeneous distribution of waste in each drum is prohibitive. In an attempt to produce a homogeneous mixture of waste that would reduce greatly the cost of sampling, researchers at NIST and RFETS are developing a cryogenic grinder. The Los Alamos work herein described addresses the implementation issues of the task. The first issue was to ascertain whether samples of the {open_quotes}small particle{close_quotes} mixtures of materials present in the waste drums at RFETS were representative of actual drum contents. Second, it was necessary to determine at what temperature the grinding operation must be performed in order to minimize or to eliminate the release of volatile organic compounds present in the waste. Last, it was essential to evaluate any effect the liquid cryogen might have on the structural integrity and ventilation capacity of the glovebox system. Results of this study showed that representative samples could be and had been obtained, that some release of organics occurred below freezing because of sublimation, and that operation of the cryogenic grinding equipment inside the glovebox was feasible.

  5. Acid Catalysis in Basic Solution: A Supramolecular Host PromotesOrthoformate Hydrolysis

    SciTech Connect (OSTI)

    Pluth, Michael D.; Bergman, Robert G.; Raymond, Kenneth N.

    2007-12-12

    Though many enzymes can promote chemical reactions by tuning substrate properties purely through the electrostatic environment of a docking cavity, this strategy has proven challenging to mimic in synthetic host-guest systems. Here we report a highly-charged, water soluble, metal-ligand assembly with a hydrophobic interior cavity that thermodynamically stabilizes protonated substrates and consequently catalyzes the normally acidic hydrolysis of orthoformates in basic solution, with rate accelerations of up to 890-fold. The catalysis reaction obeys Michaelis-Menten kinetics, exhibits competitive inhibition, and the substrate scope displays size selectivity consistent with the constrained binding environment of the molecular host. Synthetic chemists have long endeavored to design host molecules capable of selectively binding slow-reacting substrates and catalyzing their chemical reactions. While synthetic catalysts are often site-specific and require certain properties of the substrate to insure catalysis, enzymes are often able to modify basic properties of the bound substrate such as pK{sub a} in order to enhance reactivity. Two common motifs used by nature to activate otherwise unreactive compounds are the precise arrangement of hydrogen-bonding networks and electrostatic interactions between the substrate and adjacent residues of the protein. Precise arrangement of hydrogen bonding networks near the active sites of proteins can lead to well-tuned pK{sub a}-matching, and can result in pK{sub a} shifts of up to eight units, as shown in bacteriorhodopsin. Similarly, purely electrostatic interactions can greatly favor charged states and have been responsible for pK{sub a} shifts of up to five units for acetoacetate decarboxylase. Attempts have been made to isolate the contributions of electrostatic versus covalent interactions to such pK{sub a} shifts; however this remains a difficult challenge experimentally. This challenge emphasizes the importance of synthesizing

  6. OSTIblog Articles in the proceedings Topic | OSTI, US Dept of Energy Office

    Office of Scientific and Technical Information (OSTI)

    of Scientific and Technical Information proceedings Topic

  7. OSTIblog Articles in the visualizations Topic | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information visualizations Topic

  8. Design, Synthesis and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals

    SciTech Connect (OSTI)

    Akio Ishikawa; Manuel Ojeda; Nan Yao; Enrique Iglesia

    2007-03-31

    seventh reporting period, we have explored several methods to modify the silanol groups on SiO{sub 2} by using either a homogeneous deposition-precipitation method or surface titration of Si-OH on SiO{sub 2} with zirconium (IV) ethoxide to prevent the formation of unreducible and unreactive CoO{sub x} species during synthesis and FTS catalysis. We have synthesized monometallic Co/ZrO{sub 2}/SiO{sub 2} catalysts with different Co loadings (11-20 wt%) by incipient wetness impregnation methods and characterized the prepared Co supported catalysts by H{sub 2} temperature-programmed reduction (H{sub 2}-TPR) and H{sub 2}-chemisorption. We have measured the catalytic performance in FTS reactions and shown that although the hydroxyl groups on the SiO{sub 2} surface are difficult to be fully titrated by ZrO{sub 2}, modification of ZrO{sub 2} on SiO{sub 2} surface can improve the Co clusters dispersion and lead to a larger number of exposed Co surface atoms after reduction and during FTS reactions. During this seventh reporting period, we have also advanced our development of the reaction mechanism proposed in the previous reporting period. Specifically, we have shown that our novel proposal for the pathways involved in CO activation on Fe and Co catalysts is consistent with state-of-the-art theoretical calculations carried out in collaboration with Prof. Manos Mavrikakis (University of Wisconsin-Madison). Finally, we have also worked on the preparation of several manuscripts describing our findings about the preparation, activation and mechanism of the FTS with Fe-based catalysts and we have started redacting the final report for this project.

  9. Wavelet-based surrogate time series for multiscale simulation of heterogeneous catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Savara, Aditya Ashi; Daw, C. Stuart; Xiong, Qingang; Gur, Sourav; Danielson, Thomas L.; Hin, Celine N.; Pannala, Sreekanth; Frantziskonis, George N.

    2016-01-28

    We propose a wavelet-based scheme that encodes the essential dynamics of discrete microscale surface reactions in a form that can be coupled with continuum macroscale flow simulations with high computational efficiency. This makes it possible to simulate the dynamic behavior of reactor-scale heterogeneous catalysis without requiring detailed concurrent simulations at both the surface and continuum scales using different models. Our scheme is based on the application of wavelet-based surrogate time series that encodes the essential temporal and/or spatial fine-scale dynamics at the catalyst surface. The encoded dynamics are then used to generate statistically equivalent, randomized surrogate time series, which canmore » be linked to the continuum scale simulation. As a result, we illustrate an application of this approach using two different kinetic Monte Carlo simulations with different characteristic behaviors typical for heterogeneous chemical reactions.« less

  10. Multifunctional cellulase catalysis targeted by fusion to different carbohydrate-binding modules

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Walker, Johnnie A.; Takasuka, Taichi E.; Deng, Kai; Bianchetti, Christopher M.; Udell, Hannah S.; Prom, Ben M.; Kim, Hyunkee; Adams, Paul D.; Northen, Trent R.; Fox, Brian G.

    2015-12-21

    Carbohydrate binding modules (CBMs) bind polysaccharides and help target glycoside hydrolases catalytic domains to their appropriate carbohydrate substrates. To better understand how CBMs can improve cellulolytic enzyme reactivity, representatives from each of the 18 families of CBM found in Ruminoclostridium thermocellum were fused to the multifunctional GH5 catalytic domain of CelE (Cthe_0797, CelEcc), which can hydrolyze numerous types of polysaccharides including cellulose, mannan, and xylan. Since CelE is a cellulosomal enzyme, none of these fusions to a CBM previously existed. CelEcc_CBM fusions were assayed for their ability to hydrolyze cellulose, lichenan, xylan, and mannan. Several CelEcc_CBM fusions showed enhanced hydrolyticmore » activity with different substrates relative to the fusion to CBM3a from the cellulosome scaffoldin, which has high affinity for binding to crystalline cellulose. Additional binding studies and quantitative catalysis studies using nanostructure-initiator mass spectrometry (NIMS) were carried out with the CBM3a, CBM6, CBM30, and CBM44 fusion enzymes. In general, and consistent with observations of others, enhanced enzyme reactivity was correlated with moderate binding affinity of the CBM. Numerical analysis of reaction time courses showed that CelEcc_CBM44, a combination of a multifunctional enzyme domain with a CBM having broad binding specificity, gave the fastest rates for hydrolysis of both the hexose and pentose fractions of ionic-liquid pretreated switchgrass. In conclusion, we have shown that fusions of different CBMs to a single multifunctional GH5 catalytic domain can increase its rate of reaction with different pure polysaccharides and with pretreated biomass. This fusion approach, incorporating domains with broad specificity for binding and catalysis, provides a new avenue to improve reactivity of simple combinations of enzymes within the complexity of plant biomass.« less

  11. Multifunctional cellulase catalysis targeted by fusion to different carbohydrate-binding modules

    SciTech Connect (OSTI)

    Walker, Johnnie A.; Takasuka, Taichi E.; Deng, Kai; Bianchetti, Christopher M.; Udell, Hannah S.; Prom, Ben M.; Kim, Hyunkee; Adams, Paul D.; Northen, Trent R.; Fox, Brian G.

    2015-12-21

    Carbohydrate binding modules (CBMs) bind polysaccharides and help target glycoside hydrolases catalytic domains to their appropriate carbohydrate substrates. To better understand how CBMs can improve cellulolytic enzyme reactivity, representatives from each of the 18 families of CBM found in Ruminoclostridium thermocellum were fused to the multifunctional GH5 catalytic domain of CelE (Cthe_0797, CelEcc), which can hydrolyze numerous types of polysaccharides including cellulose, mannan, and xylan. Since CelE is a cellulosomal enzyme, none of these fusions to a CBM previously existed. CelEcc_CBM fusions were assayed for their ability to hydrolyze cellulose, lichenan, xylan, and mannan. Several CelEcc_CBM fusions showed enhanced hydrolytic activity with different substrates relative to the fusion to CBM3a from the cellulosome scaffoldin, which has high affinity for binding to crystalline cellulose. Additional binding studies and quantitative catalysis studies using nanostructure-initiator mass spectrometry (NIMS) were carried out with the CBM3a, CBM6, CBM30, and CBM44 fusion enzymes. In general, and consistent with observations of others, enhanced enzyme reactivity was correlated with moderate binding affinity of the CBM. Numerical analysis of reaction time courses showed that CelEcc_CBM44, a combination of a multifunctional enzyme domain with a CBM having broad binding specificity, gave the fastest rates for hydrolysis of both the hexose and pentose fractions of ionic-liquid pretreated switchgrass. In conclusion, we have shown that fusions of different CBMs to a single multifunctional GH5 catalytic domain can increase its rate of reaction with different pure polysaccharides and with pretreated biomass. This fusion approach, incorporating domains with broad specificity for binding and catalysis, provides a new avenue to improve reactivity of simple combinations of enzymes within the complexity of plant biomass.

  12. Dynamic control of a homogeneous charge compression ignition engine

    DOE Patents [OSTI]

    Duffy, Kevin P.; Mehresh, Parag; Schuh, David; Kieser, Andrew J.; Hergart, Carl-Anders; Hardy, William L.; Rodman, Anthony; Liechty, Michael P.

    2008-06-03

    A homogenous charge compression ignition engine is operated by compressing a charge mixture of air, exhaust and fuel in a combustion chamber to an autoignition condition of the fuel. The engine may facilitate a transition from a first combination of speed and load to a second combination of speed and load by changing the charge mixture and compression ratio. This may be accomplished in a consecutive engine cycle by adjusting both a fuel injector control signal and a variable valve control signal away from a nominal variable valve control signal. Thereafter in one or more subsequent engine cycles, more sluggish adjustments are made to at least one of a geometric compression ratio control signal and an exhaust gas recirculation control signal to allow the variable valve control signal to be readjusted back toward its nominal variable valve control signal setting. By readjusting the variable valve control signal back toward its nominal setting, the engine will be ready for another transition to a new combination of engine speed and load.

  13. TEC Working Group Topic Groups Tribal | Department of Energy

    Office of Environmental Management (EM)

    Energy Meeting Summaries TEC Working Group Topic Groups Tribal Meeting Summaries Meeting Summaries Kansas City TEC Meeting - Tribal Group Summary - July 25, 2007 (29.33 KB) Atlanta TEC Meeting - Tribal Group Summary - March 6, 2007 (27.82 KB) Green Bay TEC Meeting -- Tribal Group Summary - October 26, 2006 (31.56 KB) Washington TEC Meeting - Tribal Topic Group Summary - March 14, 2006 (39.76 KB) Pueblo TEC Meeting - Tribal Topic Group Summary, September 22, 2005 (40.34 KB) Phoenix TEC

  14. TEC Working Group Topic Groups Tribal Meeting Summaries | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Tribal Meeting Summaries TEC Working Group Topic Groups Tribal Meeting Summaries Meeting Summaries Kansas City TEC Meeting - Tribal Group Summary - July 25, 2007 (29.33 KB) Atlanta TEC Meeting - Tribal Group Summary - March 6, 2007 (27.82 KB) Green Bay TEC Meeting -- Tribal Group Summary - October 26, 2006 (31.56 KB) Washington TEC Meeting - Tribal Topic Group Summary - March 14, 2006 (39.76 KB) Pueblo TEC Meeting - Tribal Topic Group Summary, September 22, 2005 (40.34 KB) Phoenix TEC

  15. TEC Working Group Topic Groups Routing Conference Call Summaries |

    Office of Environmental Management (EM)

    Department of Energy Routing Conference Call Summaries TEC Working Group Topic Groups Routing Conference Call Summaries CONFERENCE CALL SUMMARIES January 31, 2008 (11.6 KB) December 6, 2007 (11.96 KB) October 4, 2007 (16.46 KB) August 23, 2007 (26.38 KB) June 21, 2007 (41.02 KB) May 31, 2007 (31.04 KB) January 18, 2007 (93.16 KB) December 19, 2006 (28.83 KB) November 9, 2006 (19.84 KB) More Documents & Publications TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic

  16. Studies of Immobilized Homogeneous Metal Catalysts on Silica Supports

    SciTech Connect (OSTI)

    Keith James Stanger

    2003-05-31

    The tethered, chiral, chelating diphosphine rhodium complex, which catalyzes the enantioselective hydrogenation of methyl-{alpha}-acetamidocinnamate (MAC), has the illustrated structure as established by {sup 31}P NMR and IR studies. Spectral and catalytic investigations also suggest that the mechanism of action of the tethered complex is the same as that of the untethered complex in solution. The rhodium complexes, [Rh(COD)H]{sub 4}, [Rh(COD){sub 2}]{sup +}BF{sub 4}{sup -}, [Rh(COD)Cl]{sub 2}, and RhCl{sub 3} {center_dot} 3H{sub 2}O, adsorbed on SiO{sub 2} are optimally activated for toluene hydrogenation by pretreatment with H{sub 2} at 200 C. The same complexes on Pd-SiO{sub 2} are equally active without pretreatments. The active species in all cases is rhodium metal. The catalysts were characterized by XPS, TEM, DRIFTS, and mercury poisoning experiments. Rhodium on silica catalyzes the hydrogenation of fluorobenzene to produce predominantly fluorocyclohexane in heptane and 1,2-dichloroethane solvents. In heptane/methanol and heptane/water solvents, hydrodefluorination to benzene and subsequent hydrogenation to cyclohexane occurs exclusively. Benzene inhibits the hydrodefluorination of fluorobenzene. In DCE or heptane solvents, fluorocyclohexane reacts with hydrogen fluoride to form cyclohexene. Reaction conditions can be chosen to selectively yield fluorocyclohexane, cyclohexene, benzene, or cyclohexane. The oxorhenium(V) dithiolate catalyst [-S(CH{sub 2}){sub 3}s-]Re(O)(Me)(PPh{sub 3}) was modified by linking it to a tether that could be attached to a silica support. Spectroscopic investigation and catalytic oxidation reactivity showed the heterogenized catalyst's structure and reactivity to be similar to its homogeneous analog. However, the immobilized catalyst offered additional advantages of recyclability, extended stability, and increased resistance to deactivation.

  17. Method of Producing Ultra-heavy Homogeneous Aerosol of Sub-micron Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ernest J. Valeo and Nathaniel J. Fisch | Princeton Plasma Physics Lab Method of Producing Ultra-heavy Homogeneous Aerosol of Sub-micron Particles Ernest J. Valeo and Nathaniel J. Fisch This invention forms a heavy homogeneous aerosol by agitating sub-micron particles throughacoustic forces and then releasing the aerosol into a low-pressure reservoir. Through this method, the aerosol particulates comprise the dominant mass of the aerosol to produce plasma of the requisite homogeneity,

  18. OSTIblog Articles in the researchers Topic | OSTI, US Dept of...

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    Documents such as these then are of the sort that becomes the central body of scientific information... Related Topics: colleagues, documents, E-Print Network (EPN), e-prints, full ...

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    Documents such as these then are of the sort that becomes the central body of scientific information... Related Topics: colleagues, documents, E-Print Network (EPN), e-prints, full ...

  20. OSTIblog Articles in the colleagues Topic | OSTI, US Dept of...

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    Documents such as these then are of the sort that becomes the central body of scientific information... Related Topics: colleagues, documents, E-Print Network (EPN), e-prints, full ...

  1. OSTIblog Articles in the Green River Formation Topic | OSTI,...

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    Green River Formation Topic Out of the past and into the future by Kathy Chambers 17 May, ... The Green River Formation in the United States records 6 million years of Eocene ...

  2. OSTIblog Articles in the digitization Topic | OSTI, US Dept of...

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    ... OSTI's most recent contributions to... Related Topics: digitization, DOE Green Energy, preservation, Science.gov, ScienceCinema, ScienceEducation.gov Read more... You Can Be a Part ...

  3. OSTIblog Articles in the technology Topic | OSTI, US Dept of...

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    ... Bing, etc.) sometimes cannot mine the deep web for you, thus missing R&D results residing ... Topics: archives, dark, Star Wars Read more... How to Integrate Anything on the Web by Dr. ...

  4. EAC Presentation (March 10, 2011): Potential Study Topics | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    or whether it should limit itself to providing recommendations to DOE about how the topic should be framed and analyzed by the national laboratories or other parties. PDF icon...

  5. CANCELED - Events & Topics in Renewable Energy & the Environment...

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    Environment CANCELED - Events & Topics in Renewable Energy & the Environment Midwest Biodiesel Products LLC November 3, 2015 - 4:00pm Please join us for a tour of the Midwest...

  6. OSTIblog Articles in the earth systems modeling Topic | OSTI...

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    earth systems modeling Topic ACME - Perfecting Earth System Models by Kathy Chambers 29 Oct, 2014 in Earth system modeling as we know it and how it benefits climate change research ...

  7. OSTIblog Articles in the Digital Object Identifier Topic | OSTI...

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    focus mainly on natural gas resources or solar power...stuff like that?" you think. "I ... Search on the word "solar," for example, and you will... Related Topics: data, data sets, ...

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    OSTI cannot be immune to these disruptive forces, nor would we wish it to be. Here,... Related Topics: .EDUconnections, Adopt-A-Doc, DOE Green Energy, DOE STI, journal literature, ...

  9. Proposed Work Scope for the Rail Topic Group

    Office of Environmental Management (EM)

    (TEC) Working Group's Rail Topic Group (RTG) is to provide stakeholder perspectives and ... or as necessary, reporting back to the full RTG on the bimonthly calls and at meetings. ...

  10. OSTIblog Articles in the Lawrence Berkeley Topic | OSTI, US Dept...

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    Lawrence Berkeley Topic Nano research in DOE collections by Kathy Chambers 24 Jul, 2012 in Science Communications 4311 Javey-baseball-300x266.jpg Nano research in DOE collections ...

  11. OSTIblog Articles in the MAJORANA Demonstrator Topic | OSTI,...

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    MAJORANA Demonstrator Topic Mining for Gold, Neutrinos and the Neutrinoless Double Beta ... The site of the former Homestake Mine was once one of the largest and deepest gold mines ...

  12. OSTIblog Articles in the Long Baseline Neutrino Experiment Topic...

    Office of Scientific and Technical Information (OSTI)

    Long Baseline Neutrino Experiment Topic Mining for Gold, Neutrinos and the Neutrinoless ... The site of the former Homestake Mine was once one of the largest and deepest gold mines ...

  13. OSTIblog Articles in the Saul Perlmutter Topic | OSTI, US Dept...

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    Saul Perlmutter Topic 100th DOE R&D Accomplishments Feature Page Celebration by Linda McBrearty 07 Jul, 2013 in Products and Content 7566 Accomp100slide.preview.jpg 100th DOE R&D ...

  14. OSTIblog Articles in the nobel laureates Topic | OSTI, US Dept...

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    nobel laureates Topic 100th DOE R&D Accomplishments Feature Page Celebration by Linda McBrearty 07 Jul, 2013 in Products and Content 7566 Accomp100slide.preview.jpg 100th DOE R&D ...

  15. OSTIblog Articles in the Glenn Seaborg Topic | OSTI, US Dept...

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    Glenn Seaborg Topic 100th DOE R&D Accomplishments Feature Page Celebration by Linda McBrearty 07 Jul, 2013 in Products and Content 7566 Accomp100slide.preview.jpg 100th DOE R&D ...

  16. OSTIblog Articles in the Melvin Calvin Topic | OSTI, US Dept...

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    Melvin Calvin Topic 100th DOE R&D Accomplishments Feature Page Celebration by Linda McBrearty 07 Jul, 2013 in Products and Content 7566 Accomp100slide.preview.jpg 100th DOE R&D ...

  17. OSTIblog Articles in the archimedes Topic | OSTI, US Dept of...

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    if they had been available, but he did not live long enough to invent those things, which he probably could have if given... Related Topics: archimedes, multimedia, new media, slac

  18. OSTIblog Articles in the OSTI Facebook Topic | OSTI, US Dept...

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    OSTI Experiences Facebook--Part One The Office of Scientific and Technical Information (OSTI) for the U.S. Department of Energy... Related Topics: OSTI Facebook, social media, sti, ...

  19. OSTIblog Articles in the customized alerts Topic | OSTI, US Dept...

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    customized alerts Topic The Web and Science: the First Twenty Years by Kate Bannan 18 Aug, 2011 in Science Communications 4366 tim-berners-lee.jpg The Web and Science: the First ...

  20. OSTIblog Articles in the information Topic | OSTI, US Dept of...

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    Related Topics: anniversary, CENDI, information, partnership, science, Science.gov, USA.gov Read more... How to Integrate Anything on the Web by Dr. Walt Warnick 03 Aug, 2011 in ...

  1. OSTIblog Articles in the osti corollary Topic | OSTI, US Dept...

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    Related Topics: information sharing, osti corollary, r&d programs Read more... Dynamically OSTI--Web 2.0 -- Enabling Information-Enabling Users-Enabling Acceleration by Erin ...

  2. OSTIblog Articles in the data warehouse Topic | OSTI, US Dept...

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    warehouse Topic How to Integrate Anything on the Web by Dr. Walt Warnick 03 Aug, 2011 in Technology 4295 ComputerIntegration.jpg How to Integrate Anything on the Web Read more ...

  3. OSTIblog Articles in the integration Topic | OSTI, US Dept of...

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    integration Topic How to Integrate Anything on the Web by Dr. Walt Warnick 03 Aug, 2011 in Technology 4295 ComputerIntegration.jpg How to Integrate Anything on the Web Read more ...

  4. OSTIblog Articles in the antibodies Topic | OSTI, US Dept of...

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    antibodies Topic Where Do New Scientists Come From? by Philip Ellis 07 Feb, 2013 in ... Thus the reality is that "new" scientists come from the general public fortuitously, and ...

  5. OSTIblog Articles in the open access journals Topic | OSTI, US...

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    access journals Topic Where Do New Scientists Come From? by Philip Ellis 07 Feb, 2013 in ... Thus the reality is that "new" scientists come from the general public fortuitously, and ...

  6. OSTIblog Articles in the Albert Einstein Topic | OSTI, US Dept...

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    Albert Einstein Topic "The New Einsteins Will Be Scientists Who Share." by Kate Bannan 01 Nov, 2011 in Science Communications 4355 225px-Einstein1921portrait2.jpg "The New ...

  7. OSTIblog Articles in the pancreatic cancer Topic | OSTI, US Dept...

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    pancreatic cancer Topic Where Do New Scientists Come From? by Philip Ellis 07 Feb, 2013 in ... Thus the reality is that "new" scientists come from the general public fortuitously, and ...

  8. Hot Topics Workshop-Summer 2014 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Workshop-Summer 2014 Hot Topics Workshop-Summer 2014 Teachers from St. Louis area schools were welcomed to Washington University in St. Louis to learn about new, exciting classroom activities centered around Solar, Wind, and Biomass

  9. OSTIblog Articles in the basic research Topic | OSTI, US Dept...

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    basic research Topic Basic Research and Innovation by Dr. Jeffrey Salmon 24 Mar, 2014 in 17010 IdeaSharing.jpg Basic Research and Innovation Read more about 17010 Recently, I ...

  10. OSTIblog Articles in the High Flux Isotope Reactor Topic | OSTI...

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    High Flux Isotope Reactor Topic The NXS Class of 2014 by Kathy Chambers 19 Nov, 2014 in ... National Laboratory, High Flux Isotope Reactor, National School on Neutron and X-ray ...

  11. OSTIblog Articles in the research results Topic | OSTI, US Dept...

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    research results Topic Keep current - sign up now by Valerie Allen 27 Jun, 2012 in Products and Content 4298 SAalerts.jpg Keep current - sign up now Read more about 4298 We've ...

  12. OSTIblog Articles in the relevance ranked Topic | OSTI, US Dept...

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    ranked Topic WorldWideScience and data by Lorrie Johnson 05 Nov, 2012 in Products and Content 4258 wwsNov2012.jpg WorldWideScience and data Read more about 4258 WorldWideScience.org ...

  13. List of Topics for Interagency Performance & Risk Assessment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Risk Assessment Community of Practice (P&RA CoP) Discussion List of Topics for Interagency Performance & Risk Assessment Community of Practice (P&RA CoP) Discussion List of ...

  14. Manufacturing Innovation Multi-Topic Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovation Multi-Topic Workshop Manufacturing Innovation Multi-Topic Workshop DOE's Advanced Manufacturing Office (AMO) and the Office of Secretary of Defense Manufacturing Technology Program (OSD ManTech) held a joint workshop October 8 and 9, 2014 in Fort Worth, TX. This workshop identified mid-Technology Readiness Level (TRL) research and development (R&D) needs, market and supply chain challenges, and shared facility needs for advanced manufacturing. The workshop complemented a recently

  15. Request for Information (RFI): Clean Energy Manufacturing Topics Suitable

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for a Manufacturing Innovation Institute | Department of Energy Clean Energy Manufacturing Topics Suitable for a Manufacturing Innovation Institute Request for Information (RFI): Clean Energy Manufacturing Topics Suitable for a Manufacturing Innovation Institute April 17, 2014 - 11:04am Addthis Funding: This RFI is not a Funding Opportunity Announcement (FOA); therefore, EERE is not accepting applications at this time. Open Date: 04/17/2014 Close Date: 05/20/2014 Funding Organization: The

  16. Topics: Determining the Beta Limit - MST - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determining the Beta Limit UW Madison Madison Symmetric Torus Topics: Determining the Beta Limit MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST People mst logo CPLA Home Directory Publications Links Internal University of Wisconsin Physics Department Research funding includes support from: Department of Energy National Science Foundation One of the reasons improved confinement in MST can be described as "tokamak-like"

  17. Microsoft Word - 20111012_RAP Dec_Mtg_Topics.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October12, 2011 1/2 Potential December RAP Committee Meeting Agenda Topics Topic/Purpose (incl. any framing questions) 2012 Priority? Issue Managers (* denotes lead) Agency Lead (s) Time Allocation 618-10&11 * Characterization (bottles) * Etc. TBD TBD TBD 60 min (30 min) 100 - K * What RAP will do based on review of Proposed Plan * River Corridor decisions - schedule * In situ technology development - status * Discuss potential concerns (advice points?) TBD TBD TBD 120 min Site-wide Permit *

  18. Funding Topics for Small Business Innovation Research and Small Business

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Transfer Programs | Department of Energy Topics for Small Business Innovation Research and Small Business Technology Transfer Programs Funding Topics for Small Business Innovation Research and Small Business Technology Transfer Programs Each year, the Office of Energy Efficiency and Renewable Energy's (EERE's) Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) programs issue Funding Opportunity Announcements (FOAs), which invite established or

  19. Topical Collaboration "Neutrinos and Nucleosynthesis in Hot and Dense Matter"

    SciTech Connect (OSTI)

    Allahverdi, Rouzbeh

    2015-09-18

    This is the final technical report describing contributions from the University of New Mexico to Topical Collaboration on "Neutrinos and Nucleosynthesis in Hot and Dense Matter" in the period June 2010 through May 2015. During the funding period, the University of New Mexico successfully hired Huaiyu Duan as a new faculty member with the support from DOE, who has contributed to the Topical Collaboration through his research and collaborations.

  20. Hot Topics Workshops - Summer 2016 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Status message Submissions for this form are closed. You are here Home / Outreach / Outreach for Educators / Hot Topics Workshops - Summer 2016 Hot Topics Workshops - Summer 2016 Registration has closed for the Summer Workshops. If you have any questions, please reach out to Chris Mohr at mohr@wustl.edu. Nuclear Energy Friday, June 24, 9am-5pm, Instructor: Kathleen Dwyer & Tracie Cain Participants will use model kits to review the atomic structure of isotopes and nuclear reactions. We will

  1. 18th Topical Conference High-Temperature Plasma Diagnostics (HTPD) |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab May 16, 2010, 9:00am to May 20, 2010, 5:00pm Conference Wildwood, New Jersey 18th Topical Conference High-Temperature Plasma Diagnostics (HTPD) The 18th Topical Conference on High-Temperature Plasma Diagnostics will be held May 16-20, 2010 in Wildwood, New Jersey. This biennial conference brings together plasma physicists from a variety of fields including magnetic confinement fusion, inertial confinement fusion, space plasmas, astrophysics, and industrial

  2. Topic B Awardee: Western Governors' Association | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Western Governors' Association Topic B Awardee: Western Governors' Association For the Topic A input requirements of the award, the states and provinces in the Western Interconnection have formed a new committee -- the State and Provincial Steering Committee -- to provide input in regional transmission planning and analysis in the interconnection. The Committee will consist of representatives from each state and province in the Western Interconnection. Pending formal announcement, the Committee

  3. Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Among States in the Eastern Interconnection on Electric Resource Planning and Priorities | Department of Energy Eastern Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Eastern Interconnection on Electric Resource Planning and Priorities A description of the requirements for Topic B for the Eastern Interconnection under the Interconnection-Wide Transmission Planning Initiative, part of

  4. Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Among States in the Western Interconnection on Electric Resource Planning and Priorities | Department of Energy Western Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Western Interconnection on Electric Resource Planning and Priorities A description of the requirements for Topic B for the Western Interconnection under the Interconnection-Wide Transmission Planning Initiative, part of

  5. Interconnection-Wide Transmission Planning Initiative: Topic B, State

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Agency Input Regarding Electric Resource and Transmission Planning in the Texas Interconnection | Department of Energy State Agency Input Regarding Electric Resource and Transmission Planning in the Texas Interconnection Interconnection-Wide Transmission Planning Initiative: Topic B, State Agency Input Regarding Electric Resource and Transmission Planning in the Texas Interconnection A description of the requirements for Topic B for the Texas Interconnect under the Interconnection-Wide

  6. Method of fabricating a homogeneous wire of inter-metallic alloy

    DOE Patents [OSTI]

    Ohriner, Evan Keith (Knoxville, TN); Blue, Craig Alan (Knoxville, TN)

    2001-01-01

    A method for fabricating a homogeneous wire of inter-metallic alloy comprising the steps of providing a base-metal wire bundle comprising a metal, an alloy or a combination thereof; working the wire bundle through at least one die to obtain a desired dimension and to form a precursor wire; and, controllably heating the precursor wire such that a portion of the wire will become liquid while simultaneously maintaining its desired shape, whereby substantial homogenization of the wire occurs in the liquid state and additional homogenization occurs in the solid state resulting in a homogenous alloy product.

  7. QUANTIFYING COMPOSITIONAL HOMOGENEITY IN Pb(ZrTi)O3 USING ATOM...

    Office of Scientific and Technical Information (OSTI)

    Title: QUANTIFYING COMPOSITIONAL HOMOGENEITY IN Pb(ZrTi)O3 USING ATOM PROBE TOMOGRAPHY. Abstract not provided. Authors: Ihlefeld, Jon F. ; Kotula, Paul Gabriel ; Brennecka, ...

  8. SBIR/STTR Phase I Release 2 Technical Topics Announced for FY14 Fuel Cell Topics Included

    Broader source: Energy.gov [DOE]

    Phase I Release 2 technical topics include prototype fuel cell-battery electric hybrid trucks for waste transportation and novel membranes and non-platinum group metal catalysts for direct methanol as well as hydrogen fuel cells.

  9. High Efficiency, Low Emissions Homogeneous Charge Compression Ignition (HCCI) Engines

    SciTech Connect (OSTI)

    2011-01-31

    This is the final report of the High Efficiency Clean Combustion (HECC) Research Program for the U.S. Department of Energy. Work under this co-funded program began in August 2005 and finished in July 2010. The objective of this program was to develop and demonstrate a low emission, high thermal efficiency engine system that met 2010 EPA heavy-duty on-highway truck emissions requirements (0.2g/bhp-hr NOx, 0.14g/bhp-hr HC and 0.01g/bhp-hr PM) with a thermal efficiency of 46%. To achieve this goal, development of diesel homogenous charge compression ignition (HCCI) combustion was the chosen approach. This report summarizes the development of diesel HCCI combustion and associated enabling technologies that occurred during the HECC program between August 2005 and July 2010. This program showed that although diesel HCCI with conventional US diesel fuel was not a feasible means to achieve the program objectives, the HCCI load range could be increased with a higher volatility, lower cetane number fuel, such as gasoline, if the combustion rate could be moderated to avoid excessive cylinder pressure rise rates. Given the potential efficiency and emissions benefits, continued research of combustion with low cetane number fuels and the effects of fuel distillation are recommended. The operation of diesel HCCI was only feasible at part-load due to a limited fuel injection window. A 4% fuel consumption benefit versus conventional, low-temperature combustion was realized over the achievable operating range. Several enabling technologies were developed under this program that also benefited non-HCCI combustion. The development of a 300MPa fuel injector enabled the development of extended lifted flame combustion. A design methodology for minimizing the heat transfer to jacket water, known as precision cooling, will benefit conventional combustion engines, as well as HCCI engines. An advanced combustion control system based on cylinder pressure measurements was developed. A Well

  10. Molecular-scale, Three-dimensional Non-Platinum Group Metal Electrodes for Catalysis of Fuel Cell Reactions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Molecular-scale, Three-dimensional Non-Platinum Group Metal Electrodes for Catalysis of Fuel Cell Reactions John B. Kerr Lawrence Berkeley National Laboratory (LBNL) September 30, 2009 Team Members: Adam Weber, Rachel Segalman, Robert Kostecki, Jeff Reimer, John Arnold, Martin Head-Gordon (LBNL). Piotr Zelenay, James Boncella, Yu Seung Kim, Neil Henson, Jerzy Chlistunoff (LANL). Steve Hamrock, Radoslav Atanasoski (3M) Budget: DOE share - $9.58MM over four years; 3M share - in-kind over four

  11. Mechanistic Details and Reactivity Descriptors in Oxidation and Acid Catalysis of Methanol

    SciTech Connect (OSTI)

    Deshlahra, Prashant; Carr, Robert T.; Chai, Song-Hai; Iglesia, Enrique

    2015-02-06

    Acid and redox reaction rates of CH₃OH-O₂ mixtures on polyoxometalate (POM) clusters, together with isotopic, spectroscopic, and theoretical assessments of catalyst properties and reaction pathways, were used to define rigorous descriptors of reactivity and to probe the compositional effects for oxidative dehydrogenation (ODH) and dehydration reactions. ³¹P-MAS NMR, transmission electron microscopy and titrations of protons with di-tert-butylpyridine during catalysis showed that POM clusters retained their Keggin structure upon dispersion on SiO₂ and after use in CH₃OH reactions. The effects of CH₃OH and O₂ pressures and of D-substitution on ODH rates show that C-H activation in molecularly adsorbed CH₃OH is the sole kinetically relevant step and leads to reduced centers as intermediates present at low coverages; their concentrations, measured from UV-vis spectra obtained during catalysis, are consistent with the effects of CH₃OH/O₂ ratios predicted from the elementary steps proposed. First-order ODH rate constants depend strongly on the addenda atoms (Mo vs W) but weakly on the central atom (P vs Si) in POM clusters, because C-H activation steps inject electrons into the lowest unoccupied molecular orbitals (LUMO) of the clusters, which are the d-orbitals at Mo⁶⁺ and W⁶⁺ centers. H-atom addition energies (HAE) at O-atoms in POM clusters represent the relevant theoretical probe of the LUMO energies and of ODH reactivity. The calculated energies of ODH transition states at each O-atom depend linearly on their HAE values with slopes near unity, as predicted for late transition states in which electron transfer and C-H cleavage are essentially complete. HAE values averaged over all accessible O-atoms in POM clusters provide the appropriate reactivity descriptor for oxides whose known structures allow accurate HAE calculations. CH₃OH dehydration proceeds via parallel pathways mediated by late carbenium-ion transition states; effects of

  12. Damping of linear waves via ionization and recombination in homogeneous plasmas

    SciTech Connect (OSTI)

    Dodin, I. Y.; Fisch, N. J.

    2010-11-15

    An oscillation-center model is proposed that analytically describes transformation of an arbitrary homogeneous linear wave at gradual ionization and recombination in homogeneous plasma. For the case when either of the processes dominates, general adiabatic invariants are found, from which the wave energy is derived as a function of the frequency.

  13. Homogeneous, dual layer, solid state, thin film deposition for structural and/or electrochemical characteristics

    DOE Patents [OSTI]

    Pitts, J. Roland; Lee, Se-Hee; Tracy, C. Edwin; Li, Wenming

    2014-04-08

    Solid state, thin film, electrochemical devices (10) and methods of making the same are disclosed. An exemplary device 10 includes at least one electrode (14) and an electrolyte (16) deposited on the electrode (14). The electrolyte (16) includes at least two homogenous layers of discrete physical properties. The two homogenous layers comprise a first dense layer (15) and a second porous layer (16).

  14. Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal–Organic Framework

    SciTech Connect (OSTI)

    Fei, Honghan; Shin, JaeWook; Meng, Ying Shirley; Adelhardt, Mario; Sutter, Jörg; Meyer, Karsten; Cohen, Seth M.

    2014-04-02

    An isolated metal-monocatecholato moiety has been achieved in a highly robust metal–organic framework (MOF) by two fundamentally different postsynthetic strategies: postsynthetic deprotection (PSD) and postsynthetic exchange (PSE). Compared with PSD, PSE proved to be a more facile and efficient functionalization approach to access MOFs that could not be directly synthesized under solvothermal conditions. Metalation of the catechol functionality residing in the MOFs resulted in unprecedented Fe-monocatecholato and Cr-monocatecholato species, which were characterized by X-ray absorption spectroscopy, X-band electron paramagnetic resonance spectroscopy, and ⁵⁷Fe Mössbauer spectroscopy. The resulting materials are among the first examples of Zr(IV)-based UiO MOFs (UiO = University of Oslo) with coordinatively unsaturated active metal centers. Importantly, the Cr-metalated MOFs are active and efficient catalysts for the oxidation of alcohols to ketones using a wide range of substrates. Catalysis could be achieved with very low metal loadings (0.5–1 mol %). Unlike zeolite-supported, Cr-exchange oxidation catalysts, the MOF-based catalysts reported here are completely recyclable and reusable, which may make them attractive catalysts for ‘green’ chemistry processes.

  15. Plasma-assisted heterogeneous catalysis for NOx reduction in lean-burn engine exhaust

    SciTech Connect (OSTI)

    Penetrante, B.M.; Hsaio, M.C.; Merritt, B.T.; Vogtlin, G.E.; Wan, C.Z.; Rice, G.W.; Voss, K.E.

    1997-12-31

    This paper discusses the combination of a plasma with a catalyst to improve the reduction of NO{sub x} under lean-burn conditions. The authors have been investigating the effects of a plasma on the NO{sub x} reduction activity and temperature operating window of various catalytic materials. One of the goals is to develop a fundamental understanding of the interaction between the gas-phase plasma chemistry and the heterogeneous chemistry on the catalyst surface. The authors have observed that plasma assisted heterogeneous catalysis can facilitate NO{sub x} reduction under conditions that normally make it difficult for either the plasma or the catalyst to function by itself. By systematically varying the plasma electrode and catalyst configuration, they have been able to elucidate the process by which the plasma chemistry affects the chemical reduction of NO{sub x} on the catalyst surface. They have discovered that the main effect of the plasma is to induce the gas-phase oxidation of NO to NO{sub 21}. The reduction of NO{sub x} to N{sub 2} is then accomplished by heterogeneous reaction of O with activated hydrocarbons on the catalyst surface. The use of a plasma opens the opportunity for a new class of catalysts that are potentially more durable, more active, more selective and more sulfur-tolerant compared to conventional lean-NO{sub x} catalysts.

  16. Sulfation of metal-organic framework: Opportunities for acid catalysis and proton conductivity

    SciTech Connect (OSTI)

    Goesten, M.G.; Stavitski, E.; Juan-Alcaniz, J.; Ramos-Fernandez, E.V.; Sai Sankar Gupta, K.B.; van Bekkum, H.; Gascon, J. and Kapteijn, F.

    2011-05-24

    A new post-functionalization method for metal-organic frameworks (MOFs) has been developed to introduce acidity for catalysis. Upon treatment with a mixture of triflic anhydride and sulfuric acid, chemically stable MOF structures MIL-101(Cr) and MIL-53(Al) can be sulfated, resulting in a Broensted sulfoxy acid group attached to up to 50% of the aromatic terephthalate linkers of the structure. The sulfated samples have been extensively characterized by solid-state NMR, XANES, and FTIR spectroscopy. The functionalized acidic frameworks show catalytic activity similar to that of acidic polymers like Nafion{reg_sign} display in the esterification of n-butanol with acetic acid (TOF {approx} 1 min{sup -1} {at} 343 K). Water adsorbs strongly up to 4 molecules per sulfoxy acid group, and an additional 2 molecules are taken up at lower temperatures in the 1-D pore channels of S-MIL-53(Al). The high water content and Broensted acidity provide the structure S-MIL-53(Al) a high proton conductivity up to moderate temperatures.

  17. Topic Index to the DOE Administrative Records Disposition Schedules

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    /21/07 TOPICINDEXTODOEADMINSCHEDULES Topic Index to the DOE Administrative Records Disposition Schedules (excluding the GRS Schedules) Topic Schedule Item [A] [B] [C] [D] [E] [F] [G] [H] [I] [J] [K] [L] [M] [N] [O] [P] [Q] [R] [S] [T] [U] [V] [W] [X] [Y] [Z] A Academic/Outreach Program 1 44 Access Request Files 18 6 Accountable Officers' Files 6 1 Accounting Administrative Files 6 5 Administrative Claims Files 6 10 Administrative Training Records 1 29.2 Administrative Issuances 16 1

  18. Acoustics topic of upcoming Frontiers in Science series

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acoustics topic of upcoming Frontiers in Science Acoustics topic of upcoming Frontiers in Science series Dipen Sinha will discuss acoustics and its applications, including how it is possible to use sound to solve problems in health, national security and for industry. July 24, 2014 Whenever an object vibrates, it creates sound, vibrations can 0:19 be detected. Besides just listening to it, we can detect it with various sensors. We 0:25 can tell what's inside a single container from the sound or

  19. Events & Topics in Renewable Energy & the Environment | Photosynthetic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Antenna Research Center Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Missouri MetroLink Facility April 12, 2016 - 4:00pm 700 S. Ewing, St. Louis, MO 63103 Event flyer RSVP here Free bus will depart from the front of Brookings Hall at 3:30 pm sharp and will return to the same location following the tour. If you plan to drive yourself, please contact Erin Plut (eplut@wustl.edu) for parking information and meet up

  20. TEC Working Group Topic Groups Security Conference Call Summaries |

    Office of Environmental Management (EM)

    Department of Energy Conference Call Summaries TEC Working Group Topic Groups Security Conference Call Summaries Conference Call Summaries August 17, 2006 (Draft) (17.12 KB) July 18, 2006 (Draft) (14.08 KB) June 20, 2006 (Draft) (16.18 KB) April 18, 2006 (27.83 KB) February 21, 2006 (32.98 KB) January 24, 2006 (19.36 KB) December 20, 2005 (13.79 KB) November 17, 2005 (17.52 KB) October 18, 2005 (18.51 KB) May 8, 2005 (29.42 KB) More Documents & Publications TEC Working Group Topic Groups

  1. SBIR and STTR: Topics, FY 2015 Phase I Release 2 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SBIR and STTR: Topics, FY 2015 Phase I Release 2 Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) Programs: Topics, FY 2015, Phase I, Release ...

  2. Chemistry {ampersand} Materials Science progress report summary of selected research and development topics, FY97

    SciTech Connect (OSTI)

    Newkirk, L.

    1997-12-01

    This report contains summaries of research performed in the Chemistry and Materials Science division. Topics include Metals and Ceramics, High Explosives, Organic Synthesis, Instrument Development, and other topics.

  3. 2015 DOE SSL R&D Workshop LED Topic Table Questions to Consider

    Broader source: Energy.gov [DOE]

    This document was distributed during the LED Topic Table portion of the DOE SSL R&D Workshop and aimed to prompt discussion on the following topics:

  4. OSTIblog Articles in the slac Topic | OSTI, US Dept of Energy...

    Office of Scientific and Technical Information (OSTI)

    Related Topics: archimedes, multimedia, new media, slac Read more... Recording Science: ... he probably could have if given... Related Topics: archimedes, multimedia, new media, slac

  5. OSTIblog Articles in the research-results Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    research-results Topic DOE R&D Accomplishments Brings You More by Mary Schorn 19 Jan, ... and predecessors,... Related Topics: DOE Research & Development (R&D) Accomplishments, ...

  6. Accelerators, Beams And Physical Review Special Topics - Accelerators And Beams

    SciTech Connect (OSTI)

    Siemann, R.H.; /SLAC

    2011-10-24

    Accelerator science and technology have evolved as accelerators became larger and important to a broad range of science. Physical Review Special Topics - Accelerators and Beams was established to serve the accelerator community as a timely, widely circulated, international journal covering the full breadth of accelerators and beams. The history of the journal and the innovations associated with it are reviewed.

  7. Hot Topics Workshop 2016 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2016 Hot Topics Workshop 2016 Participants explored how to use Makey Makey to teach electric circuits. Using Makey Makey is a great way to combine science, technology, engineering and math. Participants analyzed and solved problems all while learning the basics of circuits and using the engineering design process. This is a fun way to incorporate creativity into the science or technology classroom.

  8. TEC Working Group Topic Groups Archives Route Identification Process |

    Office of Environmental Management (EM)

    Department of Energy Route Identification Process TEC Working Group Topic Groups Archives Route Identification Process Route Identification Process Items Available for Download Routing Discussion Paper (April 1998) (71.87 KB) More Documents & Publications TEC Meeting Summaries - January 1997 TEC Meeting Summaries - July 1997 TEC Meeting Summaries - January 1998

  9. Tritium R&D at AECL Selected Topics

    Office of Environmental Management (EM)

    Tritium R&D at AECL Selected Topics Tritium Focus Group Meeting, Savannah River Site 2014 April 22-24 Hugh Boniface Chalk River Laboratories, Ontario, CANADA Outline of Presentation * Introduction & Background * Tritium Facilities: Laboratories, old and new * Tritium Separations: CECE process * Tritium Properties: Materials * Tritium Exploitation: Batteries, Helium-3 * Other work: Education, environment, biology, fusion, hydrogen UNRESTRICTED / ILLIMITÉ 2 Background UNRESTRICTED /

  10. Preface: Special Topic on Interfacial and Confined Water

    SciTech Connect (OSTI)

    Molinero, Valeria; Kay, Bruce D.

    2014-11-14

    This Special Topic on the Chemical Physics of Interfacial and Confined Water contains a collection of original research papers that showcase recent theoretical and experimental advances in the field. These papers provide a timely discussion of fundamental aspects of interfacial and confined water that are important in both natural environments and engineered applications.

  11. Structures of trihydroxynaphthalene reductase-fungicide complexes: implications for structure-based design and catalysis

    SciTech Connect (OSTI)

    Liao, D.-I.; Basarab, G.S.; Gatenby, A.A.; Valent, B.; Jordan, D.B.

    2010-03-08

    Trihydroxynaphthalene reductase catalyzes two intermediate steps in the fungal melanin biosynthetic pathway. The enzyme, a typical short-chain dehydrogenase, is the biochemical target of three commercial fungicides. The fungicides bind preferentially to the NADPH form of the enzyme. Three X-ray structures of the Magnaporthe grisea enzyme complexed with NADPH and two commercial and one experimental fungicide were determined at 1.7 {angstrom} (pyroquilon), 2.0 {angstrom} (2,3-dihydro-4-nitro-1H-inden-1-one, 1), and 2.1 {angstrom} (phthalide) resolutions. The chemically distinct inhibitors occupy similar space within the enzyme's active site. The three inhibitors share hydrogen bonds with the side chain hydroxyls of Ser-164 and Tyr-178 via a carbonyl oxygen (pyroquilon and 1) or via a carbonyl oxygen and a ring oxygen (phthalide). Active site residues occupy similar positions among the three structures. A buried water molecule that is hydrogen bonded to the NZ nitrogen of Lys-182 in each of the three structures likely serves to stabilize the cationic form of the residue for participation in catalysis. The pro S hydrogen of NADPH (which is transferred as a hydride to the enzyme's naphthol substrates) is directed toward the carbonyl carbon of the inhibitors that mimic an intermediate along the reaction coordinate. Modeling tetrahydroxynaphthalene and trihydroxynaphthalene in the active site shows steric and electrostatic repulsion between the extra hydroxyl oxygen of the former substrate and the sulfur atom of Met-283 (the C-terminal residue), which accounts, in part, for the 4-fold greater substrate specificity for trihydroxynaphthalene over tetrahydroxynaphthalene.

  12. Direct current dielectric barrier assistant discharge to get homogeneous plasma in capacitive coupled discharge

    SciTech Connect (OSTI)

    Du, Yinchang; Li, Yangfang; Cao, Jinxiang; Liu, Yu; Wang, Jian; Zheng, Zhe

    2014-06-15

    In this paper, we propose a method to get more homogeneous plasma in the geometrically asymmetric capacitive coupled plasma (CCP) discharge. The dielectric barrier discharge (DBD) is used for the auxiliary discharge system to improve the homogeneity of the geometrically asymmetric CCP discharge. The single Langmuir probe measurement shows that the DBD can increase the electron density in the low density volume, where the DBD electrodes are mounted, when the pressure is higher than 5?Pa. By this manner, we are able to improve the homogeneity of the plasma production and increase the overall density in the target volume. At last, the finite element simulation results show that the DC bias, applied to the DBD electrodes, can increase the homogeneity of the electron density in the CCP discharge. The simulation results show a good agreement with the experiment results.

  13. Organo-Lewis acid as cocatalyst for cationic homogenous metallocene Ziegler-Natta olefin polymerizations

    DOE Patents [OSTI]

    Marks, Tobin J.; Chen, You-Xian

    2000-01-01

    The synthesis of the organo-Lewis acid perfluorobiphenylborane (PBB) and the activation of metallocenes for the formation of a variety of highly active homogeneous Ziegler-Natta metallocene olefin polymerization, copolymerization and ring-opening polymerization catalysts is described.

  14. A novel approach to make homogeneous protease-stable monovalent streptavidin

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, M.; Shao, J; Xiao, J.; Deng, W.; Yu, H.

    2015-06-11

    The interaction between the tetramer streptavidin and biotin is recognized as one of the strongest non-covalent associations. Owing to the tight and specific binding, the streptavidin-biotin system has been used widely for bimolecular labeling, purification, immobilization, and even for targeted delivery of therapeutics drugs. Here, we report a novel approach to make homogeneous monovalent tetramer streptavidin. The purified monovalent protein showed both thermal stability and protease stability. Unexpectedly, we found that two proteases, Proteinase K (PK) and Subtilisin (SU), can efficiently remove the His8-tag from the wild-type subunit without affecting the tetramer architecture of monovalent streptavidin, thus making it moremore » homogeneous. In addition, crystallization was performed to assure the homogeneity of the monovalent protein prepared. Overall, monovalent streptavidin shows increased homogeneity and will likely be valuable for many future applications in a wide range of research areas.« less

  15. Opportunities for Catalysis in The 21st Century. A report from the Basic Energy Sciences Advisory Committee

    SciTech Connect (OSTI)

    White, J. M.; Bercaw, J.

    2002-05-16

    Chemical catalysis affects our lives in myriad ways. Catalysis provides a means of changing the rates at which chemical bonds are formed and broken and of controlling the yields of chemical reactions to increase the amounts of desirable products from these reactions and reduce the amounts of undesirable ones. Thus, it lies at the heart of our quality of life: The reduced emissions of modern cars, the abundance of fresh food at our stores, and the new pharmaceuticals that improve our health are made possible by chemical reactions controlled by catalysts. Catalysis is also essential to a healthy economy: The petroleum, chemical, and pharmaceutical industries, contributors of $500 billion to the gross national product of the United States, rely on catalysts to produce everything from fuels to ''wonder drugs'' to paints to cosmetics. Today, our Nation faces a variety of challenges in creating alternative fuels, reducing harmful by-products in manufacturing, cleaning up the environment and preventing future pollution, dealing with the causes of global warming, protecting citizens from the release of toxic substances and infectious agents, and creating safe pharmaceuticals. Catalysts are needed to meet these challenges, but their complexity and diversity demand a revolution in the way catalysts are designed and used. This revolution can become reality through the application of new methods for synthesizing and characterizing molecular and material systems. Opportunities to understand and predict how catalysts work at the atomic scale and the nanoscale are now appearing, made possible by breakthroughs in the last decade in computation, measurement techniques, and imaging and by new developments in catalyst design, synthesis, and evaluation.

  16. Simultaneous dual mode combustion engine operating on spark ignition and homogenous charge compression ignition

    DOE Patents [OSTI]

    Fiveland, Scott B.; Wiggers, Timothy E.

    2004-06-22

    An engine particularly suited to single speed operation environments, such as stationary power generators. The engine includes a plurality of combustion cylinders operable under homogenous charge compression ignition, and at least one combustion cylinder operable on spark ignition concepts. The cylinder operable on spark ignition concepts can be convertible to operate under homogenous charge compression ignition. The engine is started using the cylinders operable under spark ignition concepts.

  17. Homogeneous Charge Compression Ignition (HCCI) R&D | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Homogeneous Charge Compression Ignition (HCCI) R&D Homogeneous Charge Compression Ignition (HCCI) R&D 2002 DEER Conference Presentation: Lawrence Livermore National Laboratory 2002_deer_aceves.pdf (753.26 KB) More Documents & Publications Detailed Modeling of HCCI and PCCI combustion and Multi-cylinder HCCI Engine Control Bridging the Gap between Fundamental Physics and Chemistry and Applied Models for HCCI Engines Modeling of HCCI and PCCI Combustion Processes

  18. Effects of H{sub 2}O, SO{sub 2}, and NO on homogeneous Hg oxidation...

    Office of Scientific and Technical Information (OSTI)

    Effects of Hsub 2O, SOsub 2, and NO on homogeneous Hg oxidation by Clsub 2 Citation Details In-Document Search Title: Effects of Hsub 2O, SOsub 2, and NO on homogeneous Hg ...

  19. Support for Speakers and Attendees at 2008 GRC Conference Catalysis (to be held at Colby Sawyer College, New London, New Hampshire on June 22-27, 2008)

    SciTech Connect (OSTI)

    Stuart L. Soled and Nancy Ryan Gray

    2009-01-01

    The GRC on Catalysis is one of the most prestigious catalysis conferences as it brings together leading researchers from around the world to discuss their latest, most exciting work in catalysis. The 2008 conference will continue this tradition. The conference will cover a variety of themes including new catalytic materials, theoretical and experimental approaches to improve understanding of kinetics and transport phenomena, and state of the art nanoscale characterization probes to monitor active sites. The conference promotes interactions among established researchers and young scientists. It provides a venue for students to meet, talk to and learn from some of the world leading researchers in the area. It also gives them a platform for displaying their own work during the poster sessions. The informal nature of the meeting, excellent quality of the presentations and posters, and ability to meet many outstanding colleagues makes this an excellent conference.

  20. 11th Topical conference high-temperature plasma diagnostics. Book of abstracts

    SciTech Connect (OSTI)

    1996-06-01

    This report contains abstracts from the 11th topical conference on high-temperature plasma diagnostics.

  1. OSTIblog Articles in the DOE program offices Topic | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy Office of Scientific and Technical Information program offices Topic

  2. DOE-TSPP-11, Technical Standards Program Topical Committees- July 1, 2009

    Broader source: Energy.gov [DOE]

    This procedure describes how topical committees are organized and recognized under the Technical Standards Program.

  3. DOE-TSPP-11, Technical Standards Program Topical Committees- August 1, 2000

    Broader source: Energy.gov [DOE]

    This procedure describes how topical committees are organized and recognized under the Technical Standards Program.

  4. TEC Working Group Topic Groups Routing Key Documents | Department of Energy

    Office of Environmental Management (EM)

    Key Documents TEC Working Group Topic Groups Routing Key Documents KEY DOCUMENTS Proposed Task Plan - Routing Topic Group (53.69 KB) More Documents & Publications TEC Working Group Topic Groups Routing Conference Call Summaries TEC Working Group Topic Groups Rail Key Documents TEC Meeting Summaries - September 2006

  5. DOE-TSPP-9-2013, DOE Technical Standards Program Topical Committees

    Office of Energy Efficiency and Renewable Energy (EERE)

    This procedure describes how topical committees are organized and recognized under the Technical Standards Program (TSP).

  6. SBIR and STTR Topics FY 2015 Phase Release 2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) Programs Topics FY 2015 Phase I Release 2 Participating DOE Research Programs  Office of Defense Nuclear  Office of Fossil Energy Nonproliferation  Office of Electricity Delivery and  Office of Fusion Energy Sciences Energy Reliability  Office of Energy Efficiency and  Office of High Energy Physics Renewable Energy  Office of Nuclear Energy 1 PROGRAM AREA

  7. OSTIblog Articles in the Energy Information Administration Topic | OSTI, US

    Office of Scientific and Technical Information (OSTI)

    Dept of Energy Office of Scientific and Technical Information Information Administration Topic Refreshed National Library of Energy(Beta) Takes on Expanded Role in Disseminating Department of Energy Scientific and Technical Information by Lynn Davis 29 May, 2014 in The National Library of EnergyBeta (NLEBeta), a gateway to information across the U.S. Department of Energy (DOE), is taking on an expanded role in providing access to DOE scientific and technical information (STI) with the

  8. OSTIblog Articles in the National Nuclear Security Administration Topic |

    Office of Scientific and Technical Information (OSTI)

    OSTI, US Dept of Energy Office of Scientific and Technical Information Nuclear Security Administration Topic Refreshed National Library of Energy(Beta) Takes on Expanded Role in Disseminating Department of Energy Scientific and Technical Information by Lynn Davis 29 May, 2014 in The National Library of EnergyBeta (NLEBeta), a gateway to information across the U.S. Department of Energy (DOE), is taking on an expanded role in providing access to DOE scientific and technical information (STI)

  9. OSTIblog Articles in the Special Libraries Association Topic | OSTI, US

    Office of Scientific and Technical Information (OSTI)

    Dept of Energy Office of Scientific and Technical Information Special Libraries Association Topic Special Libraries Association President Visits Tennessee by Erin Anderson 13 Nov, 2013 in Personal Perspectives 10223 SLA%20Visit.jpg Special Libraries Association President Visits Tennessee Read more about 10223 In honor of the 60th Anniversary of the local Tennessee Valley Chapter (TVC) of the Special Libraries Association (SLA), International SLA President Deborah Hunt recently visited

  10. Mat. Sci. Training More Advanced Topics Jack Deslippe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mat. Sci. Training More Advanced Topics Jack Deslippe Part 1: Building Applications at NERSC Jack Deslippe Applications Already Available Did you know that NERSC offers precompiled executables for more than 100 applications? Applications Already Available Did you know that NERSC offers precompiled executables for more than 100 applications? Example, Materials Science: VASP, NAMD, LAMMPS, NWCHEM, Quantum ESPRESSO, BerkeleyGW, SIESTA, Abinit, Gamess, GROMACS, GPAW MEEP, cpmd, libxc, etsf_io,

  11. SBIR and STTR: Topics, FY 2015, Phase I, Release 2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) Programs Participating DOE Research Programs  Office of Defense Nuclear Nonproliferation  Office of Fossil Energy  Office of Electricity Delivery and Energy Reliability  Office of Fusion Energy Sciences Office of  Energy Efficiency and Renewable Energy  Office of High Energy Physics  Office of Nuclear Energy Topics FY 2015 Phase I Release 2 2 PROGRAM AREA OVERVIEW: OFFICE OF ENERGY

  12. Focus Group Meeting (Topical Meeting) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting Date: June 11, 2009 Documents Available for Download Meeting Agenda (17.51 KB) Meeting Summary/Participants (43.82 KB) Task Schedule (26.2 KB) EFCOG Overview (894.09 KB) Assessing Training Gaps in ORPS (301.26 KB) Oversight and Enforcement Inspection Schedule (34.62 KB) More Documents & Publications Focus Group Meeting (Activities Status) Focus Group Meeting (Activities Status) Focus Group Meeting (Topical Wrap-Up)

  13. TEC Working Group Topic Groups Rail Key Documents Planning Subgroup |

    Office of Environmental Management (EM)

    Department of Energy Planning Subgroup TEC Working Group Topic Groups Rail Key Documents Planning Subgroup Planning Subgroup Rail Planning Timeline (135.57 KB) Benchmarking Project: AREVA Trip Report (651.92 KB) More Documents & Publications TEC Meeting Summaries - July 2007 Evaluation of Shortline Railroads & SNF/HLW Rail Shipment Inspections Tasked for the Transportation of Spent Nuclear Fuel Federal Railroad Administration

  14. Topic Group Reports  DOE Program Summaries

    Broader source: Energy.gov (indexed) [DOE]

    Philadelphia 1999 Meeting  Topic Group Reports  DOE Program Summaries  Discussion of SNF Storage Initiatives & Transportations Issues  Discussion of WIPP Opening  Summary of Breakout Sessions The Transportation External Coordination (TEC) Working Group held its 15th semi-annual meeting July 14-15, 1999 in Philadelphia, Pennsylvania. Over 150 members, participants, and observers representing state, tribal, and local governments, regional groups, industry and professional

  15. Preface: Special Topic on Advances in Density Functional Theory

    SciTech Connect (OSTI)

    Yang, Weitao

    2014-05-14

    This Special Topic Issue on the Advances in Density Functional Theory, published as a celebration of the fifty years of density functional theory, contains a retrospective article, a perspective article, and a collection of original research articles that showcase recent theoretical advances in the field. It provides a timely discussion reflecting a cross section of our understanding, and the theoretical and computational developments, which have significant implications in broad areas of sciences and engineering.

  16. Discussion series on PURPA related topics: load management

    SciTech Connect (OSTI)

    Sturgeon, J I

    1980-08-01

    The Discussion Series on PURPA Related Topics is composed of five volumes: Metering, Billing, Information to Customers, Load Management Techniques and Master Metering. These reports are based on twenty-five Demonstration and Implementation projects sponsored and directed during the past five years by the US Department of Energy, Office of Utility Systems. Each of the topics bears directly on one or more of the federal standards contained in the Public Utilities Regulatory Policies Act of 1978 (PURPA). This volume, Load Management Techniques, relates primarily to the Time-of-Day rates standard, PURPA IB(d)3. The experiences related in this report deal, in part, with the procedures and equipment which are affected when time-of-day rates are implemented. One goal of this report is to describe how people in a variety of settings have dealt with the many practical issues in load management. Another is to highlight the lessons and summarize the experiences of the Project participants. This report does not stand as a manual nor provide prescriptive guidelines on how to deal with the topic. Rather it offers an account for those charged with the responsibility of implementing PURPA requirements to learn from the insights and problems which occurred during the Rate Demonstration projects.

  17. Regulatory cross-cutting topics for fuel cycle facilities.

    SciTech Connect (OSTI)

    Denman, Matthew R.; Brown, Jason; Goldmann, Andrew Scott; Louie, David

    2013-10-01

    This report overviews crosscutting regulatory topics for nuclear fuel cycle facilities for use in the Fuel Cycle Research&Development Nuclear Fuel Cycle Evaluation and Screening study. In particular, the regulatory infrastructure and analysis capability is assessed for the following topical areas:Fire Regulations (i.e., how applicable are current Nuclear Regulatory Commission (NRC) and/or International Atomic Energy Agency (IAEA) fire regulations to advance fuel cycle facilities)Consequence Assessment (i.e., how applicable are current radionuclide transportation tools to support risk-informed regulations and Level 2 and/or 3 PRA) While not addressed in detail, the following regulatory topic is also discussed:Integrated Security, Safeguard and Safety Requirement (i.e., how applicable are current Nuclear Regulatory Commission (NRC) regulations to future fuel cycle facilities which will likely be required to balance the sometimes conflicting Material Accountability, Security, and Safety requirements.)

  18. Recent advances in automotive catalysis for NOx emission control by small-pore microporous materials

    SciTech Connect (OSTI)

    Beale, Andrew M.; Gao, Feng; Lezcano-Gonzalez, Ines; Peden, Charles HF; Szanyi, Janos

    2015-10-05

    The ever increasing demand to develop highly fuel efficient engines coincides with the need to minimize air pollution originating from the exhaust gases of internal combustion engines. Dramatically improved fuel efficiency can be achieved at air-to-fuel ratios much higher than stoichiometric. In the presence of oxygen in large excess, however, traditional three-way catalysts are unable to reduce NOx. Among the number of lean-NOx reduction technologies, selective catalytic reduction (SCR) of NOx by NH3 over Cu- and Fe-ion exchanged zeolite catalysts has been extensively studied over the past 30+ years. Despite the significant advances in developing a viable practical zeolite-based catalyst for lean NOx reduction, the insufficient hydrothermal stabilities of the zeolite structures considered cast doubts about their real-world applicability. During the past decade a renewed interest in zeolite-based lean NOx reduction was spurred by the discovery of the very high activity of Cu-SSZ-13 (and the isostructural Cu-SAPO-34) in the NH3 SCR of NOx. These new, small-pore zeolite-based catalysts not only exhibited very high NOx conversion and N2 selectivity, but also exhibited exceptional high hydrothermal stability at high temperatures. In this review we summarize the key discoveries of the past ~5 years that lead to the introduction of these catalysts into practical application. The review first briefly discusses the structure and preparation of the CHA structure-based zeolite catalysts, and then summarizes the key learnings of the rather extensive (but not complete) characterisation work. Then we summarize the key findings of reaction kinetics studies, and provide some mechanistic details emerging from these investigations. At the end of the review we highlight some of the issues that are still need to be addressed in automotive exhaust control catalysis. Funding A.M.B. and I.L.G. would like to thank EPSRC for funding. F.G., C.H.F.P. and J.Sz. gratefully acknowledge

  19. Point matching: A new electronic method for homogenizing the phase characteristics of giant magnetoimpedance sensors

    SciTech Connect (OSTI)

    Silva, E. Costa Gusmo, L. A. P.; Barbosa, C. R. Hall; Leipner, Y.; Fortaleza, L. G. S.; Monteiro, E. Costa

    2014-08-15

    Recently, our research group at PUC-Rio discovered that magnetic transducers based on the impedance phase characteristics of GMI sensors have the potential to multiply by one hundred the sensitivity values when compared to magnitude-based GMI transducers. Those GMI sensors can be employed in the measurement of ultra-weak magnetic fields, which intensities are even lower than the environmental magnetic noise. A traditional solution for cancelling the electromagnetic noise and interference makes use of gradiometric configurations, but the performance is strongly tied to the homogeneity of the sensing elements. This paper presents a new method that uses electronic circuits to modify the equivalent impedance of the GMI samples, aiming at homogenizing their phase characteristics and, consequently, improving the performance of gradiometric configurations based on GMI samples. It is also shown a performance comparison between this new method and another homogenization method previously developed.

  20. Error Assessment of Homogenized Cross Sections Generation for Whole Core Neutronic Calculation

    SciTech Connect (OSTI)

    Hursin, Mathieu; Kochunas, Brendan; Downar, Thomas J.

    2007-10-26

    The objective of the work here was to assess the errors introduced by using 2D, few group homogenized cross sections to perform neutronic analysis of BWR problems with significant axial heterogeneities. The 3D method of characteristics code DeCART is used to generate 2-group assembly homogenized cross sections first using a conventional 2D lattice model and then using a full 3D solution of the assembly. A single BWR fuel assembly model based on an advanced BWR lattice design is used with a typical void distribution applied to the fuel channel coolant. This model is validated against an MCNP model. A comparison of the cross sections is performed for the assembly homogenized planar cross sections from the DeCART 3D and DeCART 2D solutions.

  1. Homogenous charge compression ignition engine having a cylinder including a high compression space

    DOE Patents [OSTI]

    Agama, Jorge R.; Fiveland, Scott B.; Maloney, Ronald P.; Faletti, James J.; Clarke, John M.

    2003-12-30

    The present invention relates generally to the field of homogeneous charge compression engines. In these engines, fuel is injected upstream or directly into the cylinder when the power piston is relatively close to its bottom dead center position. The fuel mixes with air in the cylinder as the power piston advances to create a relatively lean homogeneous mixture that preferably ignites when the power piston is relatively close to the top dead center position. However, if the ignition event occurs either earlier or later than desired, lowered performance, engine misfire, or even engine damage, can result. Thus, the present invention divides the homogeneous charge between a controlled volume higher compression space and a lower compression space to better control the start of ignition.

  2. WTP Safety Culture Advice Joint Topic (HSEP/TWC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 2012 v1 Page 1 of 2 Note: The views expressed in committee meetings should not be considered a substitute for full HAB consensus on any particular issue. WTP Safety Culture Advice Joint Topic (HSEP/TWC) Framing questions for discussion regarding DOE's recently released Implementation Plan: Re: Secretary Chu's response to the DNFSB with the Implementation Plan for Recommendation 2011-1 (December 27, 2011) Note: The ORP coordinator for the DOE Response to DNFSB 2011-1 is Steve Pfaff. o

  3. OSTIblog Articles in the Building Technologies Program Topic | OSTI, US

    Office of Scientific and Technical Information (OSTI)

    Dept of Energy Office of Scientific and Technical Information Building Technologies Program Topic A Roadmap to Geothermal Heat Pump Feasibility by Kathy Chambers 28 Feb, 2013 in Technology 4810 roadmap.png A Roadmap to Geothermal Heat Pump Feasibility Read more about 4810 Planning a trip is exciting. I can't tell you how long my family planned our trip out west. For so many years we wanted to do this. When we finally hit the road our adventure was more than we could have possibly imagined.

  4. OSTIblog Articles in the Princeton Plasma Physics Laboratory Topic | OSTI,

    Office of Scientific and Technical Information (OSTI)

    US Dept of Energy Office of Scientific and Technical Information Princeton Plasma Physics Laboratory Topic Snowflake Science by Kate Bannan 13 Dec, 2011 in Science Communications 4351 snowflake.jpg Snowflake Science Read more about 4351 With winter just around the corner, can snow be far behind? We've all heard that no two snowflakes are alike, but what do we really know about them? Snowflakes always have six sides. Their form and shape depends on temperature and moisture. Snowflake shapes

  5. OSTIblog Articles in the brookhaven national laboratory Topic | OSTI, US

    Office of Scientific and Technical Information (OSTI)

    Dept of Energy Office of Scientific and Technical Information brookhaven national laboratory Topic OSTI Link in New York Times Blog by Nena Moss 23 Mar, 2009 in Products and Content A document made available by the Office of Scientific and Technical Information (OSTI) was recently linked in the New York Times City Room? blog article "Answers about New York's Weather, Part 3". It was included with the answer to "How strong can an Atlantic sea breeze get? Is there Long Island

  6. Preface: Special Topic on Supramolecular Self-Assembly at Surfaces

    SciTech Connect (OSTI)

    Bartels, Ludwig; Ernst, Karl-Heinz; Gao, Hong-Jun; Thiel, Patricia A.

    2015-03-14

    Supramolecular self-assembly at surfaces is one of the most exciting and active fields in Surface Science today. Applications can take advantage of two key properties: (i) versatile pattern formation over a broad length scale and (ii) tunability of electronic structure and transport properties, as well as frontier orbital alignment. It provides a new frontier for Chemical Physics as it uniquely combines the versatility of Organic Synthesis and the Physics of Interfaces. The Journal of Chemical Physics is pleased to publish this Special Topic Issue, showcasing recent advances and new directions.

  7. TRIBAL ISSUES TOPIC GROUP MEETING SUMMARY JACKSONVILLE, FL

    Office of Environmental Management (EM)

    JACKSONVILLE, FL JANUARY 20, 1999 Mr. Kevin Blackwell (USDOT/FRA) updated the group on the status of the DOT response to DOE's inquiry about the tribal right to inspect rail shipments. The response was in the final stages of review in the General Counsel's office and is expected by July 1999. The Group has added a representative from the NRC General Counsel's office, as a topic group member, to help keep abreast of developments in the NRC's upcoming draft rulemaking regarding tribes and advanced

  8. TRIBAL ISSUES TOPIC GROUP MEETING SUMMARY JULY 13, 1999 Crowne

    Office of Environmental Management (EM)

    JULY 13, 1999 Crowne Plaza Center City Hotel, Philadelphia, PA Kevin Blackwell (U.S. Department of Transportation/Federal Rail Administration) (DOT/FRA) presented an overview of the topic group's discussion. The status of the DOT/FRA's response to DOE's inquiry about the tribal right to inspect rail shipments is still an open issue. At the time of the July meeting, the response was in the final stages of review in the Secretary of Transportation's Legal Division. The response will be forwarded

  9. SBIR/STTR FY16 Phase 1 Release 1 Topics Announced-Includes Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production and Fuel Cell Membrane Topics | Department of Energy 1 Release 1 Topics Announced-Includes Hydrogen Production and Fuel Cell Membrane Topics SBIR/STTR FY16 Phase 1 Release 1 Topics Announced-Includes Hydrogen Production and Fuel Cell Membrane Topics August 18, 2015 - 4:55pm Addthis The U.S. Department of Energy has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 1 Topics, including hydrogen production from

  10. Enhancement of crystal homogeneity of protein crystals under application of an external alternating current electric field

    SciTech Connect (OSTI)

    Koizumi, H.; Uda, S.; Fujiwara, K.; Nozawa, J.; Tachibana, M.; Kojima, K.

    2014-10-06

    X-ray diffraction rocking-curve measurements were performed on tetragonal hen egg white (HEW) lysozyme crystals grown with and without the application of an external alternating current (AC) electric field. The crystal quality was assessed by the full width at half maximum (FWHM) value for each rocking curve. For two-dimensional maps of the FWHMs measured on the 440 and the 12 12 0 reflection, the crystal homogeneity was improved under application of an external electric field at 1 MHz, compared with that without. In particular, the significant improvement of the crystal homogeneity was observed for the 12 12 0 reflection.

  11. Determining whether metals nucleate homogeneously on graphite: A case study with copper

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Appy, David; Lei, Huaping; Han, Yong; Wang, Cai -Zhuang; Tringides, Michael C.; Shao, Dahai; Kwolek, Emma J.; Evans, J. W.; Thiel, P. A.

    2014-11-05

    In this study, we observe that Cu clusters grow on surface terraces of graphite as a result of physical vapor deposition in ultrahigh vacuum. We show that the observation is incompatible with a variety of models incorporating homogeneous nucleation and calculations of atomic-scale energetics. An alternative explanation, ion-mediated heterogeneous nucleation, is proposed and validated, both with theory and experiment. This serves as a case study in identifying when and whether the simple, common observation of metal clusters on carbon-rich surfaces can be interpreted in terms of homogeneous nucleation. We describe a general approach for making system-specific and laboratory-specific predictions.

  12. Two stroke homogenous charge compression ignition engine with pulsed air supplier

    DOE Patents [OSTI]

    Clarke, John M.

    2003-08-05

    A two stroke homogenous charge compression ignition engine includes a volume pulsed air supplier, such as a piston driven pump, for efficient scavenging. The usage of a homogenous charge tends to decrease emissions. The use of a volume pulsed air supplier in conjunction with conventional poppet type intake and exhaust valves results in a relatively efficient scavenging mode for the engine. The engine preferably includes features that permit valving event timing, air pulse event timing and injection event timing to be varied relative to engine crankshaft angle. The principle use of the invention lies in improving diesel engines.

  13. Organusulfur Catalysis With Reduced Molybdenum Sulfides Containing the Mo6S8 Cluster

    SciTech Connect (OSTI)

    Thomas Jay Paskach

    2002-08-27

    Industrial synthesis of sulfur-containing organic chemicals basically focuses on the broad categories of mercaptans (thiols), alkylsulfides (thioethers), polysulfides, and thiophenes. Of the organo-sulfur compounds produced, by far the most important in terms of quantities produced is methyl mercaptan (methanethiol or MeSH), which is produced mainly for the downstream production of methionine and methanesulfonyl chloride. Higher thiols are also used in the manufacture of rubber and plastics as polymerization regulators, chain transfer agents, or initiators. Other important organosulfur chemicals are dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), both of which are used extensively for presulfiding of industrial hydroprocessing catalysts, and substituted thiophenes which are used as intermediates for production of agrochemicals, dyes, and pharmaceuticals. Thiols are produced commercially at the rate of about 10{sup 4} ton/yr from hydrogen sulfide (H{sub 2}S) and alcohols or olefins, using homogeneous free-radical synthesis, or heterogeneous catalysts based on solid acids or supported metal oxides and/or sulfides. Despite this large production rate, and the industrial importance of the organosulfur compounds, only limited research has been devoted to the development of new catalytic materials for their synthesis. Additionally, for most organosulfur catalytic reactions, only limited information exists about reaction mechanisms, active sites, adsorbed surface species, and especially the nature of the catalysts under reaction conditions.

  14. Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis

    SciTech Connect (OSTI)

    Lu, Qingquan; Zhang, Jian; Peng, Pan; Zhang, Guanghui; Huang, Zhiliang; Yi, Hong; Miller, Jeffrey T.; Lei, Aiwen

    2015-05-26

    An unprecedented single electron redox process in copper catalysis is confirmed using operando X-ray absorption and EPR spectroscopies. The oxidation state of the copper species in the interaction between Cu(II) and a sulfinic acid at room temperature, and the accurate characterization of the formed Cu(I) are clearly shown using operando X-ray absorption and EPR evidence. Further investigation of anion effects on Cu(II) discloses that bromine ions can dramatically increase the rate of the redox process. Moreover, it is proven that the sulfinic acids are converted into sulfonyl radicals, which can be trapped by 2-arylacrylic acids and various valuable β-keto sulfones are synthesized with good to excellent yields under mild conditions.

  15. Crystal Structure of 12-Lipoxygenase Catalytic-Domain-Inhibitor Complex Identifies a Substrate-Binding Channel for Catalysis

    SciTech Connect (OSTI)

    Xu, Shu; Mueser, Timothy C.; Marnett, Lawrence J.; Funk, Jr., Max O.

    2014-10-02

    Lipoxygenases are critical enzymes in the biosynthesis of families of bioactive lipids including compounds with important roles in the initiation and resolution of inflammation and in associated diseases such as diabetes, cardiovascular disease, and cancer. Crystals diffracting to high resolution (1.9 {angstrom}) were obtained for a complex between the catalytic domain of leukocyte 12-lipoxygenase and the isoform-specific inhibitor, 4-(2-oxapentadeca-4-yne)phenylpropanoic acid (OPP). In the three-dimensional structure of the complex, the inhibitor occupied a new U-shaped channel open at one end to the surface of the protein and extending past the redox-active iron site that is essential for catalysis. In models, the channel accommodated arachidonic acid, defining the binding site for the substrate of the catalyzed reaction. There was a void adjacent to the OPP binding site connecting to the surface of the enzyme and providing a plausible access channel for the other substrate, oxygen.

  16. Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Qingquan; Zhang, Jian; Peng, Pan; Zhang, Guanghui; Huang, Zhiliang; Yi, Hong; Miller, Jeffrey T.; Lei, Aiwen

    2015-05-26

    An unprecedented single electron redox process in copper catalysis is confirmed using operando X-ray absorption and EPR spectroscopies. The oxidation state of the copper species in the interaction between Cu(II) and a sulfinic acid at room temperature, and the accurate characterization of the formed Cu(I) are clearly shown using operando X-ray absorption and EPR evidence. Further investigation of anion effects on Cu(II) discloses that bromine ions can dramatically increase the rate of the redox process. Moreover, it is proven that the sulfinic acids are converted into sulfonyl radicals, which can be trapped by 2-arylacrylic acids and various valuable β-keto sulfonesmore » are synthesized with good to excellent yields under mild conditions.« less

  17. OSTIblog Articles in the world wide web Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    world wide web Topic The Knowledge Investment Curve by Dr. Walt Warnick 19 Aug, 2009 in ... to colleague... Related Topics: knowledge, Web, world wide web, WorldWideScience.org (WWS)

  18. Fundamental Understanding of the Interaction of Acid Gases with CeO2 : From Surface Science to Practical Catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tumuluri, Uma; Rother, Gernot; Wu, Zili

    2016-03-21

    Acid gases including CO2, SO2, and NOx are ubiquitous in large-scale energy applications including heterogeneous catalysis. The adverse environmental and health effects of these acid gases have resulted in high interest in the research and development of technologies to remove or convert these acid gases. The main challenge for the development of these technologies is to develop catalysts that are highly efficient, stable, and cost-effective, and many catalysts have been reported in this regard. CeO2 and CeO2-based catalysts have gained prominence in the removal and conversion of CO2, SO2, and NOx because of their structural robustness and redox and acid–basemore » properties. In this article, we provide a brief overview of the application of CeO2 and CeO2-based catalysts for the removal of CO2, SO2, and NOx gases with an emphasis on the fundamental understanding of the interactions of these acid gases with CeO2. The studies summarized in this review range from surface science using single crystals and thin films with precise crystallographic planes to practical catalysis applications of nanocrystalline and polycrystalline CeO2 materials with defects and dopants. After an introduction to the properties of CeO2 surfaces, their catalytic properties for conversions of different acid gases are reviewed and discussed. Lastly, we find that the surface atomic structure, oxygen vacancies, and surface acid–base properties of CeO2 play vital roles in the surface chemistry and structure evolution during the interactions of acid gases with CeO2 and CeO2-based catalysts.« less

  19. Preliminary Fuel Cell Manufacturing R&D Topics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Preliminary Fuel Cell Manufacturing R&D Topics Preliminary Fuel Cell Manufacturing R&D Topics Preliminary draft research topics subject to revision prior to a soliciatation being issued. preliminary_solicitation_topics.pdf (164.55 KB) More Documents & Publications DOE Hydrogen Program Manufacturing R&D Pre-Solicitation Meeting PEM Stack Manufacturing: Industry Status 2011 NREL/DOE Hydrogen and Fuel Cell Manufacturing R&D Workshop Report

  20. Topic: Cesium Management and Disposition Alternatives for the Low Activity Waste Pre-Treatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative Records Disposition Schedules (235.82 KB) More Documents & Publications ADMINISTRATIVE RECORDS SCHEDULE 20: ELECTRONIC RECORDS ADMINISTRATIVE RECORDS SCHEDULE 20: ELECTRONIC RECORDS ADMINISTRATIVE RECORDS SCHEDULE 12:

  1. TEC Working Group Topic Groups Manual Review Key Documents | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Manual Review Key Documents TEC Working Group Topic Groups Manual Review Key Documents Key Documents Transportation Practices Manual (DOE M 460) - March 8, 2006 (438.51 KB) More Documents & Publications DOE Shipment Activities: What We Accomplished and a Look Forward TEC Working Group Topic Groups Section 180(c) Key Documents TEC Working Group Topic Groups Rail Key Documents

  2. Additional EIPC Study Analysis: Interim Report on High Priority Topics

    SciTech Connect (OSTI)

    Hadley, Stanton W

    2013-11-01

    Between 2010 and 2012 the Eastern Interconnection Planning Collaborative (EIPC) conducted a major long-term resource and transmission study of the Eastern Interconnection (EI). With guidance from a Stakeholder Steering Committee (SSC) that included representatives from the Eastern Interconnection States Planning Council (EISPC) among others, the project was conducted in two phases. Phase 1 involved a long-term capacity expansion analysis that involved creation of eight major futures plus 72 sensitivities. Three scenarios were selected for more extensive transmission- focused evaluation in Phase 2. Five power flow analyses, nine production cost model runs (including six sensitivities), and three capital cost estimations were developed during this second phase. The results from Phase 1 and 2 provided a wealth of data that could be examined further to address energy-related questions. A list of 13 topics was developed for further analysis; this paper discusses the first five.

  3. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... sciences zeolites (1) biofuels (1) biomass vapor-phase upgrading (1) carbocations (1) catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and ...

  4. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Everything19 Electronic Full Text6 Citations13 Multimedia0 Datasets0 Software0 Filter Results Filter by Subject solar energy (4) catalysis (homogeneous), catalysis (heterogeneous), ...

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Filter Results Filter by Subject catalysis (homogeneous), catalysis (heterogeneous), energy storage (including batteries and capacitors), hydrogen and fuel cells, defects, charge ...

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Filter Results Filter by Subject basic biological sciences (4) catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, materials ...

  7. Some mismatches occurred when simulating fractured reservoirs as homogeneous porous media

    SciTech Connect (OSTI)

    Mario Cesar Suarez Arriaga; Fernando Samaniego V.; Fernando Rodriguez

    1996-01-24

    The understanding of transport processes that occur in naturally fractured geothermal systems is far from being complete. Often, evaluation and numerical simulations of fractured geothermal reservoirs, are carried out by assuming equivalent porous media and homogeneous petrophysical properties within big matrix blocks. The purpose of this paper, is to present a comparison between results obtained from numerical studies of a naturally fractured reservoir treated as a simple porous medium and the simulation of some real aspects of the fractured reservoir. A general conclusion outlines the great practical importance of considering even approximately, the true nature of such systems. Our results show that the homogeneous simplified evaluation of the energy resource in a fractured system, could result in unrealistic estimates of the reservoir capacity to generate electricity.

  8. Characterization of the homogeneous tissue mixture approximation in breast imaging dosimetry

    SciTech Connect (OSTI)

    Sechopoulos, Ioannis; Bliznakova, Kristina; Qin Xulei; Fei Baowei; Feng, Steve Si Jia

    2012-08-15

    Purpose: To compare the estimate of normalized glandular dose in mammography and breast CT imaging obtained using the actual glandular tissue distribution in the breast to that obtained using the homogeneous tissue mixture approximation. Methods: Twenty volumetric images of patient breasts were acquired with a dedicated breast CT prototype system and the voxels in the breast CT images were automatically classified into skin, adipose, and glandular tissue. The breasts in the classified images underwent simulated mechanical compression to mimic the conditions present during mammographic acquisition. The compressed thickness for each breast was set to that achieved during each patient's last screening cranio-caudal (CC) acquisition. The volumetric glandular density of each breast was computed using both the compressed and uncompressed classified images, and additional images were created in which all voxels representing adipose and glandular tissue were replaced by a homogeneous mixture of these two tissues in a proportion corresponding to each breast's volumetric glandular density. All four breast images (compressed and uncompressed; heterogeneous and homogeneous tissue) were input into Monte Carlo simulations to estimate the normalized glandular dose during mammography (compressed breasts) and dedicated breast CT (uncompressed breasts). For the mammography simulations the x-ray spectra used was that used during each patient's last screening CC acquisition. For the breast CT simulations, two x-ray spectra were used, corresponding to the x-ray spectra with the lowest and highest energies currently being used in dedicated breast CT prototype systems under clinical investigation. The resulting normalized glandular dose for the heterogeneous and homogeneous versions of each breast for each modality was compared. Results: For mammography, the normalized glandular dose based on the homogeneous tissue approximation was, on average, 27% higher than that estimated using the

  9. MFT homogeneity study at TNX: Final report on the low weight percent solids concentration

    SciTech Connect (OSTI)

    Jenkins, W.J.

    1993-09-21

    A statistical design and analysis of both elemental analyses and weight percent solids analyses data was utilized to evaluate the MFT homogeneity at low heel levels and low agitator speed at both high and low solids feed concentrations. The homogeneity was also evaluated at both low and high agitator speed at the 6000+ gallons static level. The dynamic level portion of the test simulated feeding the Melter from the MFT to evaluate the uniformity of the solids slurry composition (Frit-PHA-Sludge) entering the melter from the MFT. This final report provides the results and conclusions from the second half of the study, the low weight percent solids concentration portion, as well as a comparison with the results from the first half of the study, the high weight percent solids portion.

  10. Method for preparing homogeneous single crystal ternary III-V alloys

    DOE Patents [OSTI]

    Ciszek, Theodore F.

    1991-01-01

    A method for producing homogeneous, single-crystal III-V ternary alloys of high crystal perfection using a floating crucible system in which the outer crucible holds a ternary alloy of the composition desired to be produced in the crystal and an inner floating crucible having a narrow, melt-passing channel in its bottom wall holds a small quantity of melt of a pseudo-binary liquidus composition that would freeze into the desired crystal composition. The alloy of the floating crucilbe is maintained at a predetermined lower temperature than the alloy of the outer crucible, and a single crystal of the desired homogeneous alloy is pulled out of the floating crucible melt, as melt from the outer crucible flows into a bottom channel of the floating crucible at a rate that corresponds to the rate of growth of the crystal.

  11. Impact of heterogeneous ice nuclei on homogeneous freezing events in cirrus clouds

    SciTech Connect (OSTI)

    Spichtinger, Peter; Cziczo, Daniel J.

    2010-07-29

    The influence of initial heterogeneous nucleation on subsequent homogeneous nucleation events in cirrus clouds is investigated using a box model which includes the explicit impact of aerosols on the nucleation of ice crystals and sedimentation. Different effects are discussed, namely the impact of external mixtures of heterogeneous ice nuclei and the influence of size-dependent freezing thresholds. Several idealized experiments are carried out, which show that the treatment of external mixtures of ice nuclei can strongly change later homogeneous nucleation events (i.e., the ice crystal number densities) in different matters. The use of size-dependent freezing thresholds can also change the cloud prop erties when compared to more simple parameterizations. This size effect is most important for large IN concentrations. Based upon these findings, recommendations for future modeling and measurement efforts are presented.

  12. Closely spaced mirror pair for reshaping and homogenizing pump beams in laser amplifiers

    SciTech Connect (OSTI)

    Bass, I.L.

    1992-12-01

    Channeling a laser beam by multiple reflections between two closely-spaced, parallel or nearly parallel mirrors, serves to reshape and homogenize the beam at the output gap between the mirrors. Application of this device to improve the spatial overlap of a copper laser pump beam with the signal beam in a dye laser amplifier is described. This technique has been applied to the AVLIS program at the Lawrence Livermore National Laboratory.

  13. The performance of 3500 MWth homogeneous and heterogeneous metal fueled core designs

    SciTech Connect (OSTI)

    Turski, R.; Yang, Shi-tien

    1987-11-01

    Performance parameters are calculated for a representative 3500 MWth homogeneous and a heterogeneous metal fueled reactor design. The equilibrium cycle neutronic characteristics, safety coefficients, control system requirements, and control rod worths are evaluated. The thermal-hydraulic characteristics for both configurations are also compared. The heavy metal fuel loading requirements and neutronic performance characteristics are also evaluated for the uranium startup option. 14 refs., 14 figs., 20 tabs.

  14. Homogeneous piecewise polynomial Lyapunov function for robust stability of uncertain piecewise linear system

    SciTech Connect (OSTI)

    BenAbdallah, Abdallah; Hammami, Mohamed Ali; Kallel, Jalel

    2009-03-05

    In this paper we present some sufficient conditions for the robust stability and stabilization of time invariant uncertain piecewise linear system using homogenous piecewise polynomial Lyapunov function. The proposed conditions are given in terms of linear matrix inequalities which can be numerically solved. An application of the obtained result is given. It consists in resolving the stabilization of piecewise uncertain linear control systems by using a state piecewise linear feedback.

  15. Scalar and tensor spherical harmonics expansion of the velocity correlation in homogeneous anisotropic turbulence

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rubinstein, Robert; Kurien, Susan; Cambon, Claude

    2015-06-22

    The representation theory of the rotation group is applied to construct a series expansion of the correlation tensor in homogeneous anisotropic turbulence. The resolution of angular dependence is the main analytical difficulty posed by anisotropic turbulence; representation theory parametrises this dependence by a tensor analogue of the standard spherical harmonics expansion of a scalar. As a result, the series expansion is formulated in terms of explicitly constructed tensor bases with scalar coefficients determined by angular moments of the correlation tensor.

  16. Beam Homogeneity Dependence on the Magnetic Filter Field at the IPP Test Facility MANITU

    SciTech Connect (OSTI)

    Franzen, P.; Fantz, U.

    2011-09-26

    The homogeneity of the extracted current density from the large RF driven negative hydrogen ion sources of the ITER neutral beam system is a critical issue for the transmission of the negative ion beam through the accelerator and the beamline components. As a first test, the beam homogeneity at the IPP long pulse test facility MANITU is measured by means of the divergence and the stripping profiles obtained with a spatially resolved Doppler-shift spectroscopy system. Since MANITU is typically operating below the optimum perveance, an increase in the divergence corresponds to a lower local extracted negative ion current density if the extraction voltage is constant. The beam H{sub {alpha}} Doppler-shift spectroscopy is a rather simple tool, as no absolute calibration - both for the wavelength and the emission - is necessary. Even no relative calibration of the different used lines of sight is necessary for divergence and stripping profiles as these quantities can be obtained by the line broadening of the Doppler-shifted peak and the ratio of the integral of the stripping peak to the integral of the Doppler-shifted peak, respectively. The paper describes the H{sub {alpha}} MANITU Doppler-shift spectroscopy system which is now operating routinely and the evaluation methods of the divergence and the stripping profiles. Beam homogeneity measurements are presented for different extraction areas and magnetic filter field configurations both for Hydrogen and Deuterium operation; the results are compared with homogeneity measurements of the source plasma. The stripping loss measurements are compared with model calculations.

  17. Non-homogeneous solutions of a Coulomb Schrdinger equation as basis set for scattering problems

    SciTech Connect (OSTI)

    Del Punta, J. A.; Ambrosio, M. J.; Gasaneo, G.; Zaytsev, S. A.; Ancarani, L. U.

    2014-05-15

    We introduce and study two-body Quasi Sturmian functions which are proposed as basis functions for applications in three-body scattering problems. They are solutions of a two-body non-homogeneous Schrdinger equation. We present different analytic expressions, including asymptotic behaviors, for the pure Coulomb potential with a driven term involving either Slater-type or Laguerre-type orbitals. The efficiency of Quasi Sturmian functions as basis set is numerically illustrated through a two-body scattering problem.

  18. Effect of high pressure homogenization on aqueous phase solvent extraction of lipids from Nannochloris Oculata microalgae

    SciTech Connect (OSTI)

    Samarasinghe, Nalin; Fernando, Sandun; Faulkner, William B.

    2012-12-01

    The ability to extract lipids from high-moisture Nannochloris Oculata algal biomass disrupted with high pressure homogenization was investigated. During the first phase, the effect of high pressure homogenization (system pressure and number of passes) on disrupting aqueous algae (of different concentrations and degree of stress) was investigated. Secondly, the effect of degree of cell wall disruption on the amount of lipids extracted with three solvents, namely: hexane, dichloromethane and chloroform, were compared. Studies reveled that high pressure homogenization is effective on cell disruption while the amount of system pressure being the most significant factor affecting the degree of cell breakage. Although the number of passes had some impact, the level of disruption seemed to level-off after a certain number of passes. The study revealed that slightly polar solvents (such as chloroform and dichloromethane) performed better in aqueous-phase lipid extractions as compared to hexane. Also, it was revealed that it was not necessary to disrupt the algal cells completely to achieve appreciable levels of lipid yields. In fact, conditions that exerted only 20% of the cells to completely disrupt, allowed sufficient damage to liberate most of the lipids contained in the remainder of the cells.

  19. Effect of high pressure homogenization on aqueous phase solvent extraction of lipids from Nannochloris Oculata microalgae

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samarasinghe, Nalin; Fernando, Sandun; Faulkner, William B.

    2012-12-01

    The ability to extract lipids from high-moisture Nannochloris Oculata algal biomass disrupted with high pressure homogenization was investigated. During the first phase, the effect of high pressure homogenization (system pressure and number of passes) on disrupting aqueous algae (of different concentrations and degree of stress) was investigated. Secondly, the effect of degree of cell wall disruption on the amount of lipids extracted with three solvents, namely: hexane, dichloromethane and chloroform, were compared. Studies reveled that high pressure homogenization is effective on cell disruption while the amount of system pressure being the most significant factor affecting the degree of cell breakage.more » Although the number of passes had some impact, the level of disruption seemed to level-off after a certain number of passes. The study revealed that slightly polar solvents (such as chloroform and dichloromethane) performed better in aqueous-phase lipid extractions as compared to hexane. Also, it was revealed that it was not necessary to disrupt the algal cells completely to achieve appreciable levels of lipid yields. In fact, conditions that exerted only 20% of the cells to completely disrupt, allowed sufficient damage to liberate most of the lipids contained in the remainder of the cells.« less

  20. Selected topics in special nuclear materials safeguard system design

    SciTech Connect (OSTI)

    King, L.L.; Thatcher, C.D.; Clarke, J.D. ); Rodriguez, M.P. )

    1991-01-01

    During the past two decades the improvements in circuit integration have given rise to many new applications in digital processing technology by continuously reducing the unit cost of processing power. Along with this increase in processing power a corresponding decrease in circuit volume has been achieved. Progress has been so swift that new classes of applications become feasible every 2 or 3 years. This is especially true in the application of proven new technology to special nuclear materials (SNM) safeguard systems. Several areas of application were investigated in establishing the performance requirements for the SNM safeguard system. These included the improvements in material control and accountability and surveillance by using multiple sensors to continuously monitor SNM inventory within the selected value(s); establishing a system architecture to provide capabilities needed for present and future performance requirements; and limiting operating manpower exposure to radiation. This paper describes two selected topics in the application of state-of-the-art, well-proven technology to SNM safeguard system design.