National Library of Energy BETA

Sample records for tons average sulfur

  1. Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities

    U.S. Energy Information Administration (EIA) Indexed Site

    (Percent) Type: Sulfur Content API Gravity Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Type Area Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History U.S. 1.43 1.38 1.43 1.39 1.43 1.47 1985-2016 PADD 1 0.75 0.63 0.83 0.88 0.90 0.86 1985-2016 East Coast 0.68 0.55 0.76 0.81 0.84 0.79 1985-2016 Appalachian No. 1 1.53 1.57 1.51 1.74 1.58 1.59 1985-2016 PADD 2 1.56 1.58 1.56 1.58 1.45 1.55

  2. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","6/2016","1/15/1985" ,"Release Date:","8/31/2016" ,"Next Release

  3. Table 1. Real Average Transportation and Delivered Costs of Coal...

    U.S. Energy Information Administration (EIA) Indexed Site

    Real Average Transportation and Delivered Costs of Coal, By Year and Primary Transport Mode" "Year","Average Transportation Cost of Coal (Dollars per Ton)","Average Delivered Cost...

  4. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    DOE Patents [OSTI]

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuiliang; Li, Xiaolin

    2014-06-17

    Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm..

  5. Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    SciTech Connect (OSTI)

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuliang; Li, Xiaolin

    2015-04-07

    A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing the graphene layers with a first solution comprising sulfur and carbon disulfide, evaporating the carbon disulfide to yield a solid nanocomposite, and grinding the solid nanocomposite to yield the graphene-sulfur nanocomposite. Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter of less than 50 nm.

  6. Two (2) 175 Ton (350 Tons total) Chiller Geothermal Heat Pumps for recently

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    commissioned LEED Platinum Building | Department of Energy Two (2) 175 Ton (350 Tons total) Chiller Geothermal Heat Pumps for recently commissioned LEED Platinum Building Two (2) 175 Ton (350 Tons total) Chiller Geothermal Heat Pumps for recently commissioned LEED Platinum Building This project will operate; collect data; and market the energy savings and capital costs of a recently commissioned chiller geothermal heat pump project to promote the wide-spread adoption of this mature

  7. "Table 2. Real Average Annual Coal Transportation Costs, By Primary...

    U.S. Energy Information Administration (EIA) Indexed Site

    Real Average Annual Coal Transportation Costs, By Primary Transport Mode and Supply Region" "(2013 dollars per ton)" "Coal Supply Region",2008,2009,2010,2011,2012,2013 "Railroad"...

  8. E TON Solar Tech | Open Energy Information

    Open Energy Info (EERE)

    Solar Tech Jump to: navigation, search Name: E-TON Solar Tech Place: Tainan, Taiwan Zip: 709 Product: Taiwan-based manufacturer of PV cells. Coordinates: 22.99721, 120.180862...

  9. Biogenic sulfur source strengths

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.; Bamesberger, W.L.

    1981-12-01

    Conclusions are presented from a 4-yr field measurement study of biogenic sulfur gas emissions from soils, and some water and vegetated surfaces, at 35 locales in the eastern and southeastern United States. More than one soil order was examined whenever possible to increase the data base obtained from the 11 major soil orders comprising the study area. Data analysis and emission model development were based upon an (80 x 80)-km/sup 2/ grid system. The measured sulfur fluxes, adjusted for the annual mean temperature for each sampling locale, weigted by the percentage of each soil order within each grid, and averaged for each of the east-west grid tiers from 47/sup 0/N to 25/sup 0/N latitude, showed an exponential north-to-south increase in total sulfur gas flux. Our model predits an additional increase of nearly 25-fold in sulfur flux between 25/sup 0/N and the equator.

  10. THERMAL MODELING ANALYSIS OF SRS 70 TON CASK

    SciTech Connect (OSTI)

    Lee, S.; Jordan, J.; Hensel, S.

    2011-03-08

    The primary objective of this work was to perform the thermal calculations to evaluate the Material Test Reactor (MTR) fuel assembly temperatures inside the SRS 70-Ton Cask loaded with various bundle powers. MTR fuel consists of HFBR, MURR, MIT, and NIST. The MURR fuel was used to develop a bounding case since it is the fuel with the highest heat load. The results will be provided for technical input for the SRS 70 Ton Cask Onsite Safety Assessment. The calculation results show that for the SRS 70 ton dry cask with 2750 watts total heat source with a maximum bundle heat of 670 watts and 9 bundles of MURR bounding fuel, the highest fuel assembly temperatures are below about 263 C. Maximum top surface temperature of the plastic cover is about 112 C, much lower than its melting temperature 260 C. For 12 bundles of MURR bounding fuel with 2750 watts total heat and a maximum fuel bundle of 482 watts, the highest fuel assembly temperatures are bounded by the 9 bundle case. The component temperatures of the cask were calculated by a three-dimensional computational fluid dynamics approach. The modeling calculations were performed by considering daily-averaged solar heat flux.

  11. Bioenergy Impacts … Billion Dry Tons

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Oak Ridge National Laboratory published research that shows that U.S. resources could sustainably produce by 2030 at least one billion dry tons of non-food biomass resources, yielding up to 60 billion gallons of biofuels, as well as bio- based chemicals, products, and electricity. This could potentially reduce greenhouse gas emissions by up to 500 million tons per year, create 1.5 million new jobs, and keep about $200 billion extra in the U.S. economy each year. Research is showing that U.S.

  12. Biogenic sulfur emissions in the SURE region

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.

    1980-09-01

    The objective of this study was to estimate the magnitude of biogenic sulfur emissions from the northeastern United States - defined as the EPRI Sulfate Regional Experiment (SURE) study area. Initial laboratory efforts developed and validated a portable sulfur sampling system and a sensitive, gas chromatographic analytical detection system. Twenty-one separate sites were visited in 1977 to obtain a representative sulfur emission sampling of soil orders, suborders, and wetlands. The procedure determined the quantity of sulfur added to sulfur-free sweep air by the soil flux as the clean air was blown through the dynamic enclosure set over the selected sampling area. This study represents the first systematic sampling for biogenic sulfur over such a wide range of soils and such a large land area. The major impacts upon the measured sulfur flux were found to include soil orders, temperature, sunlight intensity, tidal effects along coastal areas. A mathematical model was developed for biogenic sulfur emissions which related these field variables to the mean seasonal and annual ambient temperatures regimes for each SURE grid and the percentage of each soil order within each grid. This model showed that at least 53,500 metric tons (MT) of biogenic sulfur are emitted from the SURE land surfaces and approximately 10,000 MT are emitted from the oceanic fraction of the SURE grids. This equates to a land sulfur flux of nearly 0.02 gram of sulfur per square meter per yr, or about 0.6% of the reported anthropogenic emissions withn the SURE study area. Based upon these data and the summertime Bermuda high clockwise circulation of maritime air across Florida and the Gulf Coast states northward through the SURE area, the total land biogenic sulfur emission contribution to the SURE area atmospheric sulfur burden might approach 1 to 2.5% of the anthropogenic.

  13. Billion Ton Study-A Historical Perspective | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Billion Ton Study-A Historical Perspective Billion Ton Study-A Historical Perspective Breakout Session 1A: Biomass Feedstocks for the Bioeconomy Billion Ton Study-A Historical Perspective Bryce Stokes, Senior Advisor, CNJV stokes_bioenergy_2015.pdf (1.37 MB) More Documents & Publications Biomass Econ 101: Measuring the Technological Improvements on Feedstocks Costs WEBINAR: A CHANGING MARKET FOR BIOFUELS AND BIOPRODUCTS 2016 Billion-Ton Report Factsheets

  14. 2016 Billion-Ton Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Billion-Ton Report 2016 Billion-Ton Report Alison Goss Eng, of the U.S. Department of Energy Bioenergy Technologies Office, Tim Theiss, Laboratory Relationship Manager of the Bioenergy Technologies Program at Oak Ridge National Laboratory, and Tim Rials, Director of the Tennessee Forest Products Center, provide background and their insights into the production and contents of the soon-to-be-released 2016 Billion-Ton Report. The 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving

  15. Development of a new FGD process that converts sulfur dioxide to salable ammonium phosphate fertilizer

    SciTech Connect (OSTI)

    Ji-lu Chen

    1993-12-31

    Rich mineral resources have enabled Chinese coal output and energy consumption to rank second and third in the world, respectively. In 1992, up to 70 percent of the country`s electric power was generated by the combustion of some 300 million tons of coal. Although the average sulfur content level in Chinese coals is only about 0.8 percent, the share of high- sulfur coals with 2 percent or more sulfur content is as high as 18 percent. As a result, air pollution accompanied by acid rain now occurs over most of the country, especially in southwestern China. Currently, the area comprising Guangdong, Guangxi, the Sichuan Basin, and the greater part of Gueizhou, where the sulfur content in coal is between 2 and 7 percent and the average pH values of rain water are between 4 and 5 per annum, has become one of the three biggest acid rain-affected areas in the world. In 1992, the national installed coal-fired electricity generation capacity exceeded 100,000 MWe. By the year 2000, it is expected to reach as much as 200,000 MWe, according to a new scheduled program. Environmental pollution caused by large-scale coal combustion is a very important issue that needs to be considered in the implementation of the program. To ensure that the effects of coal-fired power generation on the environment can be properly controlled in the near future, TPRI (Thermal Power Research Institute), the sole thermal power engineering research institution within the Ministry of Electric Power Industry (MOEPI), has conducted a long-term research program to develop sulfur emission control technologies suitable to the special conditions prevalent in China since the early 1970s. The details are summarized. The objective of this chapter is to describe the fundamental concept and major pilot test results and present an economic evaluation of a new process combining flue gas desulfurization (FGD) and ammonium phosphate fertilizer production.

  16. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur...

    Office of Scientific and Technical Information (OSTI)

    Title: Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur ...

  17. Department of Energy Releases New 'Billion-Ton' Study Highlighting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunities for Growth in Bioenergy Resources | Department of Energy New 'Billion-Ton' Study Highlighting Opportunities for Growth in Bioenergy Resources Department of Energy Releases New 'Billion-Ton' Study Highlighting Opportunities for Growth in Bioenergy Resources August 10, 2011 - 3:41pm Addthis Washington, D.C. - The U.S. Department of Energy today released a report - 2011 U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry - detailing U.S. biomass

  18. Moab Project Disposes 2 Million Tons of Uranium Mill Tailings...

    Office of Environmental Management (EM)

    The Moab Uranium Mill Tailings Remedial Action Project reached its primary American ... of schedule on Wednesday with the disposal of 2 million tons of uranium mill tailings. ...

  19. Department of Energy Releases New 'Billion-Ton' Study Highlighting...

    Office of Environmental Management (EM)

    Opportunities for Growth in Bioenergy Resources Department of Energy Releases New 'Billion-Ton' Study Highlighting Opportunities for Growth in Bioenergy Resources August 10, 2011 - ...

  20. DOE Announces Webinars on Building a Billion Ton Bioeconomy and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building a Billion Ton Bioeconomy and an Opportunity in ... from adopting the latest energy efficiency and renewable energy ... Tribal Energy Financing Models, and More DOE Announces ...

  1. Uses of lunar sulfur

    SciTech Connect (OSTI)

    Vaniman, D.T.; Pettit, D.R.; Heiken, G.

    1988-01-01

    Sulfur and sulfur compounds have a wide range of applications for their fluid, electrical, chemical and biochemical properties. Although low in abundance on the Moon (/approximately/0.1% in mare soils), sulfur is surface-correlated and relatively extractable. Co-production of sulfur during oxygen extraction from ilmenite-rich soils could yield sulfur in masses up to 10% of the mass of oxygen produced. Sulfur deserves serious consideration as a lunar resource. 29 refs., 3 figs.

  2. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H.

    1983-12-20

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  3. 2016 Billion-Ton Report Factsheets | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Report Factsheets 2016 Billion-Ton Report Factsheets 2016 Billion-Ton Report Factsheets 2016_billion_ton_report_preview_factsheet.pdf (1.13 MB) summary_and_comparison_factsheet_bt16.pdf (299.96 KB) forest_resources_factsheet_bt16.pdf (217.66 KB) agricultural_residues_facsheet_bt16.pdf (745.74 KB) municipal_solid_waste_factsheet_bt16.pdf (341.29 KB) algae_research_factsheet_bt16.pdf (364.99 KB) to_the_biorefinery_factsheet_bt16.pdf (325.45 KB) More Documents & Publications A Summary of the

  4. Picture of the Week: The 100-Ton Test

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 The 100-Ton Test Before the historic Trinity test on July 16th, 1945, Los Alamos scientists conducted a host of other experiments designed to ensure that they would be ready to...

  5. Operational and maintenance manual, 100 ton hydraulic trailer

    SciTech Connect (OSTI)

    Koons, B.M.

    1995-03-03

    The 100 ton hydraulic trailer is used to remove the mitigation pump from Tank 241SY101. This manual explains how to inspect, operate, and maintain the trailer in a state of readiness.

  6. 305 Building 2 ton bridge crane and monorail assembly analysis

    SciTech Connect (OSTI)

    Axup, M.D.

    1995-12-01

    The analyses in the appendix of this document evaluate the integrity of the existing bridge crane structure, as depicted on drawing H-3-34292, for a bridge crane and monorail assembly with a load rating of 2 tons. This bridge crane and monorail assembly is a modification of a 1 1/2 ton rated manipulator bridge crane which originally existed in the 305 building.

  7. Sneak Peek to the 2016 Billion-Ton Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resource Analysis * Potential economic availability of biomass feedstocks under speci- fed market scenarios, including currently used resources * Cost of production, harvesting, and transportation; potential yield range, and economic supply for 30 candidate feedstocks (>1 billion dry tons/year) Resource Commercialization * Advanced feedstock supply system simulation, expansion of feedstock production over time in response to simulated markets. Volume 2 Environmental Sustainability Analysis

  8. Sulfur recovery process

    SciTech Connect (OSTI)

    Hise, R.E.; Cook, W.J.

    1991-06-04

    This paper describes a method for recovering sulfur from a process feed stream mixture of gases comprising sulfur-containing compounds including hydrogen sulfide using the Claus reaction to convert sulfur-containing compounds to elemental sulfur and crystallization to separate sulfur-containing compounds from a tail gas of the Claus reaction for further processing as a recycle stream. It comprises: providing a Claus feed stream containing a stoichiometric excess of hydrogen sulfide, the Claus feed stream including the process feed stream and the recycles stream; introducing the Claus feed stream and an oxidizing agent into a sulfur recovery unit for converting sulfur-containing compounds in the Claus feed stream to elemental sulfur; withdrawing the tail gas from the sulfur recovery unit; separating water from the tail gas to producing a dehydrated tail gas; separating sulfur-containing compounds including carbonyl sulfide from the dehydrated tail gas as an excluded material by crystallization and withdrawing an excluded material-enriched output from the crystallization to produce the recycle stream; and combining the recycle stream with the process feed stream to produce the Claus feed stream.

  9. Neutron resonance averaging

    SciTech Connect (OSTI)

    Chrien, R.E.

    1986-10-01

    The principles of resonance averaging as applied to neutron capture reactions are described. Several illustrations of resonance averaging to problems of nuclear structure and the distribution of radiative strength in nuclei are provided. 30 refs., 12 figs.

  10. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  11. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect (OSTI)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  12. Average Residential Price

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Average Residential Price Residential Price - Local Distribution Companies Residential Price - Marketers Residential % Sold by Local Distribution Companies Average Commercial Price Commercial Price - Local Distribution Companies Commerical Price - Marketers Commercial % Sold by Local Distribution Companies Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 2010 2011

  13. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  14. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Hu, Zhicheng

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  15. DOE to Remove 200 Metric Tons of Highly Enriched Uranium from...

    Energy Savers [EERE]

    200 Metric Tons of Highly Enriched Uranium from U.S. Nuclear Weapons Stockpile DOE to Remove 200 Metric Tons of Highly Enriched Uranium from U.S. Nuclear Weapons Stockpile ...

  16. U.S. Manufacturers Save $1 Billion, 11 Million Tons of CO2 through...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy Efficiency Investments U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy...

  17. In Milestone, Energy Department Projects Safely and Permanently Store 10 Million Metric Tons of Carbon Dioxide

    Broader source: Energy.gov [DOE]

    Carbon Capture and Storage projects supported by the Department reached a milestone of 10 million tons of carbon dioxide.

  18. Moab Project Disposes 2 Million Tons of Uranium Mill Tailings with Recovery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Act Funds | Department of Energy Moab Project Disposes 2 Million Tons of Uranium Mill Tailings with Recovery Act Funds Moab Project Disposes 2 Million Tons of Uranium Mill Tailings with Recovery Act Funds The Moab Uranium Mill Tailings Remedial Action Project reached its primary American Recovery and Reinvestment Act milestone ahead of schedule on Wednesday with the disposal of 2 million tons of uranium mill tailings. The project had originally planned to ship 2 million tons of tailings with

  19. Bacterial Sulfur Storage Globules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for...

  20. U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industry | Department of Energy Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry An update to the 2005 report, "Biomass as a Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply" For the most recent report, view the 2016 Billion-Ton Report. billion_ton_update.pdf (6.41 MB) More Documents & Publications 2016

  1. Acceptance test report for the Westinghouse 100 ton hydraulic trailer

    SciTech Connect (OSTI)

    Barrett, R.A.

    1995-03-06

    The SY-101 Equipment Removal System 100 Ton Hydraulic Trailer was designed and built by KAMP Systems, Inc. Performance of the Acceptance Test Procedure at KAMP`s facility in Ontario, California (termed Phase 1 in this report) was interrupted by discrepancies noted with the main hydraulic cylinder. The main cylinder was removed and sent to REMCO for repair while the trailer was sent to Lampson`s facility in Pasco, Washington. The Acceptance Test Procedure was modified and performance resumed at Lampson (termed Phase 2 in this report) after receipt of the repaired cylinder. At the successful conclusion of Phase 2 testing the trailer was accepted as meeting all the performance criteria specified.

  2. Separation of sulfur isotopes

    DOE Patents [OSTI]

    DeWitt, Robert; Jepson, Bernhart E.; Schwind, Roger A.

    1976-06-22

    Sulfur isotopes are continuously separated and enriched using a closed loop reflux system wherein sulfur dioxide (SO.sub.2) is reacted with sodium hydroxide (NaOH) or the like to form sodium hydrogen sulfite (NaHSO.sub.3). Heavier sulfur isotopes are preferentially attracted to the NaHSO.sub.3, and subsequently reacted with sulfuric acid (H.sub.2 SO.sub.4) forming sodium hydrogen sulfate (NaHSO.sub.4) and SO.sub.2 gas which contains increased concentrations of the heavier sulfur isotopes. This heavy isotope enriched SO.sub.2 gas is subsequently separated and the NaHSO.sub.4 is reacted with NaOH to form sodium sulfate (Na.sub.2 SO.sub.4) which is subsequently decomposed in an electrodialysis unit to form the NaOH and H.sub.2 SO.sub.4 components which are used in the aforesaid reactions thereby effecting sulfur isotope separation and enrichment without objectionable loss of feed materials.

  3. Neutrino physics with multi-ton scale liquid xenon detectors

    SciTech Connect (OSTI)

    Baudis, L.; Ferella, A.; Kish, A.; Manalaysay, A.; Undagoitia, T. Marrodn; Schumann, M., E-mail: laura.baudis@physik.uzh.ch, E-mail: alfredo.ferella@lngs.infn.it, E-mail: alexkish@physik.uzh.ch, E-mail: aaronm@ucdavis.edu, E-mail: marrodan@mpi-hd.mpg.de, E-mail: marc.schumann@lhep.unibe.ch [Physik Institut, University of Zrich, Winterthurerstrasse 190, Zrich, CH-8057 (Switzerland)

    2014-01-01

    We study the sensitivity of large-scale xenon detectors to low-energy solar neutrinos, to coherent neutrino-nucleus scattering and to neutrinoless double beta decay. As a concrete example, we consider the xenon part of the proposed DARWIN (Dark Matter WIMP Search with Noble Liquids) experiment. We perform detailed Monte Carlo simulations of the expected backgrounds, considering realistic energy resolutions and thresholds in the detector. In a low-energy window of 230 keV, where the sensitivity to solar pp and {sup 7}Be-neutrinos is highest, an integrated pp-neutrino rate of 5900 events can be reached in a fiducial mass of 14 tons of natural xenon, after 5 years of data. The pp-neutrino flux could thus be measured with a statistical uncertainty around 1%, reaching the precision of solar model predictions. These low-energy solar neutrinos will be the limiting background to the dark matter search channel for WIMP-nucleon cross sections below ? 2 10{sup ?48} cm{sup 2} and WIMP masses around 50 GeV?c{sup ?2}, for an assumed 99.5% rejection of electronic recoils due to elastic neutrino-electron scatters. Nuclear recoils from coherent scattering of solar neutrinos will limit the sensitivity to WIMP masses below ? 6 GeV?c{sup ?2} to cross sections above ? 4 10{sup ?45}cm{sup 2}. DARWIN could reach a competitive half-life sensitivity of 5.6 10{sup 26} y to the neutrinoless double beta decay of {sup 136}Xe after 5 years of data, using 6 tons of natural xenon in the central detector region.

  4. Transportation system benefits of early deployment of a 75-ton multipurpose canister system

    SciTech Connect (OSTI)

    Wankerl, M.W.; Schmid, S.P.

    1995-12-31

    In 1993 the US Civilian Radioactive Waste Management System (CRWMS) began developing two multipurpose canister (MPC) systems to provide a standardized method for interim storage and transportation of spent nuclear fuel (SNF) at commercial nuclear power plants. One is a 75-ton concept with an estimated payload of about 6 metric tons (t) of SNF, and the other is a 125-ton concept with an estimated payload of nearly 11 t of SNF. These payloads are two to three times the payloads of the largest currently certified US rail transport casks, the IF-300. Although is it recognized that a fully developed 125-ton MPC system is likely to provide a greater cost benefit, and radiation exposure benefit than the lower-capacity 75-ton MPC, the authors of this paper suggest that development and deployment of the 75-ton MPC prior to developing and deploying a 125-ton MPC is a desirable strategy. Reasons that support this are discussed in this paper.

  5. LOW SULFUR HOME HEATING OIL DEMONSTRATION PROJECT SUMMARY REPORT.

    SciTech Connect (OSTI)

    BATEY, J.E.; MCDONALD, R.J.

    2005-06-01

    almost the same as predicted by past laboratory studies. Fouling deposition rates are reduced by a factor of two to three by using lower sulfur oil. This translates to a potential for substantial service cost savings by extending the interval between labor-intensive cleanings of the internal surfaces of the heating systems in these homes. In addition, the time required for annual service calls can be lowered, reducing service costs and customer inconvenience. The analyses conducted as part of this field demonstration project indicates that service costs can be reduced by up to $200 million a year nationwide by using lower sulfur oil and extending vacuum cleaning intervals depending on the labor costs and existing cleaning intervals. The ratio of cost savings to added fuel costs is economically attractive based on past fuel price differentials for the lower sulfur product. The ratio of cost savings to added costs vary widely as a function of hourly service rates and the additional cost for lower sulfur oil. For typical values, the expected benefit is a factor of two to four higher than the added fuel cost. This means that for every dollar spent on higher fuel cost, two to four dollars can be saved by lowered vacuum cleaning costs when the cleaning intervals are extended. Information contained in this report can be used by individual oil marketers to estimate the benefit to cost ratio for their specific applications. Sulfur oxide and nitrogen oxide air emissions are reduced substantially by using lower sulfur fuel oil in homes. Sulfur oxides emissions are lowered by 75 percent by switching from fuel 0.20 percent to 0.05 percent sulfur oil. This is a reduction of 63,000 tons a year nationwide. In New York State, sulfur oxide emissions are reduced by 13,000 tons a year. This translates to a total value of $12 million a year in Sulfur Oxide Emission Reduction Credits for an emission credit cost of $195 a ton. While this ''environmental cost'' dollar savings is smaller than

  6. Concentration Averaging | Department of Energy

    Office of Environmental Management (EM)

    Concentration Averaging Concentration Averaging Summary Notes from 3 October 2007 Generic Technical Issue Discussion on Concentration Averaging PDF icon Summary Notes from 3...

  7. Sodium-sulfur thermal battery

    SciTech Connect (OSTI)

    Ludwig, F.A.

    1990-12-11

    This paper discusses a sodium-sulfur thermal battery for generating electrical energy at temperatures above the melting point of sodium metal and sulfur. It comprises a sodium electrode comprising sodium metal; a sulfur electrode comprising sulfur; and a separator located between the sodium and sulfur electrodes. The separator having sufficient porosity to allow preliminary migration of fluid sodium metal and fluid sulfur and fluid sodium polysulfides therethrough during operation of the thermal battery to form a mixed polysulfides electrolyte gradient within the separator.

  8. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C.

    1982-01-01

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  9. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Mikkor, Mati

    1981-01-01

    This disclosure is directed to an improvement in a sodium sulfur battery construction in which a seal between various battery compartments is made by a structure in which a soft metal seal member is held in a sealing position by holding structure. A pressure applying structure is used to apply pressure on the soft metal seal member when it is being held in sealing relationship to a surface of a container member of the sodium sulfur battery by the holding structure. The improvement comprises including a thin, well-adhered, soft metal layer on the surface of the container member of the sodium sulfur battery to which the soft metal seal member is to be bonded.

  10. AmeriFlux US-Ton Tonzi Ranch

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Baldocchi, Dennis [University of California, Berkeley

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-Ton Tonzi Ranch. Site Description - Located in the lower foothills of the Sierra Nevada Mountains, the Tonzi Ranch site is classified as an oak savanna woodland on privately owned land. Managed by local rancher, Russell Tonzi, brush has been periodically removed for cattle grazing. The overstory is dominated by blue oak trees (40% of total vegetation) with intermittent grey pine trees (3 trees/ha). Understory species include a variety of grasses and herbs, including purple false brome, smooth cat's ear, and rose clover. These two distinctive layers operate in and out from one another. Growing season of the understory is confined to the wet season only, typically from October to early May. In contrast, the deciduous blue oak trees are dormant during the rainy winter months and reach maximum LAI in April. The blue oak ecosystem rings the Great Central Valley of California, inhabiting the lower reaches of the Sierra Nevada foothills.

  11. Carbonyl sulfide: potential agent of atmospheric sulfur corrosion

    SciTech Connect (OSTI)

    Graedel, T.E.; Kammlott, G.W.; Franey, J.P.

    1981-05-08

    Laboratory exposure experiments demonstrate that carbonyl sulfide in wet air corrodes copper at 22/sup 0/C at a rate that is approximately linear with total exposure (the product of exposure time and carbonyl sulfide concentration). The corrosion rate is similar to that of hydrogen sulfide, a widely recognized corrodant. The much greater average atmospheric abundance of carbonyl sulfide compared with that of hydrogen sulfide or sulfur dioxide suggests that carbonyl sulfide may be a major agent of atmospheric sulfur corrosion.

  12. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun; Yu, Qiquan; Chang, Shih-Ger

    1996-01-01

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.

  13. DOE Will Dispose of 34 Metric Tons of Plutonium by Turning it into Fuel for

    National Nuclear Security Administration (NNSA)

    Civilian Reactors | National Nuclear Security Administration | (NNSA) Will Dispose of 34 Metric Tons of Plutonium by Turning it into Fuel for Civilian Reactors DOE Will Dispose of 34 Metric Tons of Plutonium by Turning it into Fuel for Civi Washington, DC Secretary Abraham announced that DOE will dispose of 34 metric tons of surplus weapons grade plutonium by turning the material into mixed oxide fuel (MOX) for use in nuclear reactors. The decision follows an exhaustive Administration review

  14. 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bioeconomy | Department of Energy Report: Advancing Domestic Resources for a Thriving Bioeconomy 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Volume I Download the full interactive report to view visualizations of potential energy crop production, agricultural residues, forestry production and other scenarios on the BioenergyKDF. 2016_billion_ton_report.pdf (29.08 MB) More

  15. A Summary of the Results of the 2016 Billion-Ton Report: Advancing Domestic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resources for a Thriving Bioeconomy, Vol. 1 | Department of Energy A Summary of the Results of the 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Vol. 1 A Summary of the Results of the 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Vol. 1 bt16_webinar_20160721.pdf (3.32 MB) More Documents & Publications Biomass Econ 101: Measuring the Technological Improvements on Feedstocks Costs 2016 Billion-Ton Report Factsheets

  16. Removal of 1,082-Ton Reactor Among Richland Operations Office...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from groundwater across the site ahead of schedule and pumped a record volume of water through treatment facilities to remove contamination, with more than 130 tons of...

  17. U.S. Billion-Ton Update. Biomass Supply for a Bioenergy and Bioproducts Industry

    SciTech Connect (OSTI)

    none,

    2011-08-01

    This report is an update to the 2005 Billion-Ton Study that addresses shotcomings and questions that arose from the original report..

  18. DOE-Sponsored Mississippi Project Hits 1-Million-Ton Milestone for Injected CO2

    Broader source: Energy.gov [DOE]

    A large-scale carbon dioxide storage project in Mississippi has become the fifth worldwide to reach the important milestone of more than 1 million tons injected.

  19. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Topouzian, Armenag

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which a flexible diaphragm sealing elements respectively engage opposite sides of a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  20. Process for forming sulfuric acid

    DOE Patents [OSTI]

    Lu, Wen-Tong P.

    1981-01-01

    An improved electrode is disclosed for the anode in a sulfur cycle hydrogen generation process where sulfur dioxie is oxidized to form sulfuric acid at the anode. The active compound in the electrode is palladium, palladium oxide, an alloy of palladium, or a mixture thereof. The active compound may be deposited on a porous, stable, conductive substrate.

  1. SULFUR POLYMER ENCAPSULATION.

    SciTech Connect (OSTI)

    KALB, P.

    2001-08-22

    Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not

  2. DOE Partner Begins Injecting 50,000 Tons of CO2 in Michigan Basin

    Broader source: Energy.gov [DOE]

    Building on an initial injection project of 10,000 metric tons of carbon dioxide into a Michigan geologic formation, a U.S. Department of Energy team of regional partners has begun injecting 50,000 additional tons into the formation, which is believed capable of storing hundreds of years worth of CO2, a greenhouse gas that contributes to climate change.

  3. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Y.; Yu, Q.; Chang, S.G.

    1996-02-27

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

  4. Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

  5. Criticality safety review of 2 1/2 -, 10-, and 14-ton UF sub 6 cylinders

    SciTech Connect (OSTI)

    Broadhead, B.L.

    1991-01-01

    The US regulations governing the packaging and transportation of UF{sub 6} cylinders are contained in the publication 10CFR71. Under the current 10CFR71 regulations, packages are classified according to Fissile Class I, II, or III and a corresponding transport index (TI). UF{sub 6} cylinders designed to contain 2{1/2}-tons of UF{sub 6} are classified as Fissile Class II packages with a TI of 5 for the purpose of transportation. The 10-ton UF{sub 6} cylinders are classified as Fissile Class I with no TI assigned for transportation. The 14-ton cylinders are not certified for transport with enrichments greater than 1 wt % since they have no approved overpack. This work reviews the suitability of 2{1/2}-ton UF{sub 6} packages for reclassification as Fissile Class I with a maximum {sup 235}U enrichment of 5 wt %. Additionally, the 10- and 14-ton cylinders are reviewed to address a change in maximum {sup 235}U enrichment from 4.5 to 5 wt %. Based on this evaluation, the 2{1/2}-ton UF{sub 6} cylinders meet the 10CFR71 criteria for Fissile Class I packages, and no TI is needed for criticality safety purposes. Similarly, the 10- and 14-ton UF{sub 6} packages appear suitable for a maximum enrichment rating change to 5 wt % {sup 235}U. 6 refs., 4 figs., 1 tab.

  6. Billion-Ton Update: Home-Grown Energy Resources Across the Nation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Billion-Ton Update: Home-Grown Energy Resources Across the Nation Billion-Ton Update: Home-Grown Energy Resources Across the Nation August 11, 2011 - 3:59pm Addthis Total potential biomass resources by county in the contiguous U.S. from the baseline scenario of the Update (Figure 6.4, page 159) | Map from Billion-Ton Update Total potential biomass resources by county in the contiguous U.S. from the baseline scenario of the Update (Figure 6.4, page 159) | Map from

  7. Evaluation of Sulfur in Syngas

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project will define the options and costs at different scales of technology that can be used to remove sulfur from syngas.

  8. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  9. Low-sulfur coal usage alters transportation strategies

    SciTech Connect (OSTI)

    Stein, H.

    1995-07-01

    As electricity production has grown, so has the amount of coal burned by US utilities. In order to comply with the 1990 Clean Air Act Amendments (CAAA), many utilities have changed from high-sulfur coal to lower-sulfur coal to reduce sulfur dioxide emissions. The primary mode of transporting coal to utilities remains the railroad, and coal represents the largest freight tonnage shipped - two out of every five tons. Since coal is so important to the railroads, it is logical that as utilities have changed their coal-buying strategies, the railroads` strategies have also changed. The increased demand for Western coal has caused rail lines some capacity problems which they are attempting to meet head-on by buying new railcars and locomotives and expanding track capacities. The new railcars typically have aluminum bodies to reduce empty weight, enabling them to carry larger loads of coal. Train locomotives are also undergoing upgrade changes. Most new locomotives have as motors to drive the wheels which deliver more motive power (traction) to the wheel trucks. In fact the motors are up to 30% more efficient at getting the traction to the trucks. Trackage is also being expanded to alleviate serious congestion on the tracks when moving Western coal.

  10. Process for removing sulfur from sulfur-containing gases

    DOE Patents [OSTI]

    Rochelle, Gary T.; Jozewicz, Wojciech

    1989-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

  11. 11,202,720 Metric Tons of CO2 Injected as of October 14, 2015...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This carbon dioxide (CO2) has been injected in the United States as part of DOE's Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is ...

  12. DOE Moab Project Safely Removes 7 Million Tons of Mill Tailings

    Broader source: Energy.gov [DOE]

    (Grand Junction, CO) ― The U.S. Department of Energy (DOE) has safely moved another million tons of uranium mill tailings from the Moab site in Utah under the Uranium Mill Tailings Remedial Action Project.

  13. 11,202,720 Metric Tons of CO2 Injected as of October 14, 2015

    Office of Energy Efficiency and Renewable Energy (EERE)

    This carbon dioxide (CO2) has been injected in the United States as part of DOEs Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is equivalent to the...

  14. Long-term Decline of Aggregate Fuel Use per Cargo-ton-mile of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Long-term Decline of Aggregate Fuel Use per Cargo-ton-mile of Commercial Trucking; A Key Enabler of Expanded U.S. Trade and Economic Growth Poster presentation at the 2007 Diesel ...

  15. Hanford Landfill Reaches 15 Million Tons Disposed- Waste Disposal Mark Shows Success Cleaning Up River Corridor

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – The U.S. Department of Energy (DOE) and its contractors have disposed of 15 million tons of contaminated material at the Environmental Restoration Disposal Facility (ERDF) since the facility began operations in 1996.

  16. U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproduct...

    Energy Savers [EERE]

    and Bioproducts Industry An update to the 2005 report, "Biomass as a Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply" ...

  17. 12,877,644 Metric Tons of CO2 Injected as of July 1, 2016

    Broader source: Energy.gov [DOE]

    This carbon dioxide (CO2) has been injected in the United States as part of DOE’s Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is equivalent to the...

  18. NNSA Eliminates 100 Metric Tons Of Weapons-Grade Nuclear Material |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Nuclear Security Administration | (NNSA) Eliminates 100 Metric Tons Of Weapons-Grade Nuclear Material August 25, 2008 WASHINGTON, D.C. -Today the Department of Energy's National Nuclear Security Administration (NNSA) announced that it successfully eliminated 100 metric tons of U.S. highly enriched uranium (HEU), enough for thousands of nuclear weapons. For the last decade, the U.S. HEU disposition program has eliminated surplus HEU from the nuclear weapons program by downblending

  19. Two 175 ton geothermal chiller heat pumps for leed platinum building

    Office of Scientific and Technical Information (OSTI)

    technology demonstration project. Operation data, data collection and marketing (Technical Report) | SciTech Connect Two 175 ton geothermal chiller heat pumps for leed platinum building technology demonstration project. Operation data, data collection and marketing Citation Details In-Document Search Title: Two 175 ton geothermal chiller heat pumps for leed platinum building technology demonstration project. Operation data, data collection and marketing The activities funded by this grant

  20. DOE Announces Webinars on Building a Billion Ton Bioeconomy and an

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunity in Innovative Sensors | Department of Energy Building a Billion Ton Bioeconomy and an Opportunity in Innovative Sensors DOE Announces Webinars on Building a Billion Ton Bioeconomy and an Opportunity in Innovative Sensors May 5, 2016 - 9:06am Addthis EERE offers webinars to the public on a range of subjects, from adopting the latest energy efficiency and renewable energy technologies, to training for the clean energy workforce. Webinars are free; however, advanced registration is

  1. Future Bioeconomy Supported by More Than One Billion Tons of Biomass

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Potential | Department of Energy Future Bioeconomy Supported by More Than One Billion Tons of Biomass Potential Future Bioeconomy Supported by More Than One Billion Tons of Biomass Potential July 12, 2016 - 2:15pm Addthis Within 25 years, the United States could produce enough biomass to support a bioeconomy, including renewable aquatic and terrestrial biomass resources that could be used for energy and to develop products for economic, environmental, social, and national security benefits.

  2. Volume efficient sodium sulfur battery

    DOE Patents [OSTI]

    Mikkor, Mati

    1980-01-01

    In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

  3. An Evolutionary Arms Race for Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    globally distributed sulfur-oxidizing bacteria in the deep sea carry bacterial genes for the oxidation of elemental sulfur. Although such observations are common in...

  4. Spacetime averaged null energy condition

    SciTech Connect (OSTI)

    Urban, Douglas; Olum, Ken D.

    2010-06-15

    The averaged null energy condition has known violations for quantum fields in curved space, even when one considers only achronal geodesics. Many such examples involve rapid variation in the stress-energy tensor in the vicinity of the geodesic under consideration, giving rise to the possibility that averaging in additional dimensions would yield a principle universally obeyed by quantum fields. However, after discussing various procedures for additional averaging, including integrating over all dimensions of the manifold, we give here a class of examples that violate any such averaged condition.

  5. Natural sulfur flux from the Gulf of Mexico: dimethyl sulfide, carbonyl sulfide, and sulfur dioxide. Technical report

    SciTech Connect (OSTI)

    Van Valin, C.C.; Luria, M.; Wellman, D.L.; Gunter, R.L.; Pueschel, R.F.

    1987-06-01

    Atmospheric measurements of natural sulfur compounds were performed over the northern Gulf of Mexico during the late summer months of 1984. Air samples were collected with an instrumented aircraft at elevations of 30-3500 m, during both day and night. Most air samples were representative of the clean maritime atmosphere, although some were from continental contaminated air during periods of offshore flow at the coastline. In all samples, carbonyl sulfide concentrations were within the range of 400-500 pptv. Conversely, the dimethyl sulfide concentrations showed significant variability: during clean atmospheric conditions the average of all measurements was 27 pptv, whereas under polluted conditions the average was 7 pptv. Measureable quantities of dimethyl sulfide (>5 pptv) were not observed above the boundary layer. The average sulfur dioxide concentration measured in the marine (clean) atmosphere was 215 pptv, which is consistent with the oxidation of dimethyl sulfide being its major source.

  6. Alkali metal/sulfur battery

    DOE Patents [OSTI]

    Anand, Joginder N.

    1978-01-01

    Alkali metal/sulfur batteries in which the electrolyte-separator is a relatively fragile membrane are improved by providing means for separating the molten sulfur/sulfide catholyte from contact with the membrane prior to cooling the cell to temperatures at which the catholyte will solidify. If the catholyte is permitted to solidify while in contact with the membrane, the latter may be damaged. The improvement permits such batteries to be prefilled with catholyte and shipped, at ordinary temperatures.

  7. High average power pockels cell

    DOE Patents [OSTI]

    Daly, Thomas P.

    1991-01-01

    A high average power pockels cell is disclosed which reduces the effect of thermally induced strains in high average power laser technology. The pockels cell includes an elongated, substantially rectangular crystalline structure formed from a KDP-type material to eliminate shear strains. The X- and Y-axes are oriented substantially perpendicular to the edges of the crystal cross-section and to the C-axis direction of propagation to eliminate shear strains.

  8. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  9. Support EM LA Airport Landfill Cover Project by providing 40000 tons of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    soil | Department of Energy Support EM LA Airport Landfill Cover Project by providing 40000 tons of soil Support EM LA Airport Landfill Cover Project by providing 40000 tons of soil DE-DT0010454-Task-Order-4 Airport Landfill Construction Activities The purpose of this task order (TO) is to support the EM-LA Field Office in replacing the cover at the Los Alamos County Airport Landfill. The new cover design is an evapotranspiration (ET) cover. Contractor: TSAY Corporation DOE Contracting

  10. U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Supply for a Bioenergy and Bioproducts Industry U.S. BILLI N-TON UPDATE U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry A Study Sponsored by U.S. Department of Energy Energy Effciency and Renewable Energy Offce of the Biomass Program August 2011 Prepared by OAK RIDGE NATIONAL LABORATORY Oak Ridge, Tennessee 37831-6335 managed by UT-Battelle, LLC for the U.S. DEPARTMENT OF ENERGY under contract DE-AC05-00OR22725 This report was prepared as an account of

  11. Y-12's rough roads smoothed over with 23,000 tons of recycled asphalt |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration | (NNSA) 's rough roads smoothed over with 23,000 tons of recycled asphalt Tuesday, December 29, 2015 - 12:00am NNSA Blog Some 23,000 tons of asphalt removed during this summer's UPF site work have been put to use throughout the site. Potholes and gravel roads are now "paved" with the recycled asphalt that has been ground into a material called base course. Unlike gravel, the material tends to rebind into a solid form as it is packed down,

  12. REGIONAL FEEDSTOCK PARTNERSHIP SUMMARY REPORT Enabling the Billion-Ton Vision

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FEEDSTOCK PARTNERSHIP SUMMARY REPORT Enabling the Billion-Ton Vision July 2016 Regional Feedstock Partnership Report | i Regional Feedstock Partnership Summary Report: Enabling the Billion-Ton Vision A Study Sponsored by U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Bioenergy Technologies Office July 2016 Prepared by Managed by Battelle Energy Alliance, LLC for the U.S. Department of Energy Under Contract DE-AC07-015D14517 This report was prepared as an account of

  13. DOE to Remove 200 Metric Tons of Highly Enriched Uranium from U.S. Nuclear

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Weapons Stockpile | Department of Energy to Remove 200 Metric Tons of Highly Enriched Uranium from U.S. Nuclear Weapons Stockpile DOE to Remove 200 Metric Tons of Highly Enriched Uranium from U.S. Nuclear Weapons Stockpile November 7, 2005 - 12:38pm Addthis Will Be Redirected to Naval Reactors, Down-blended or Used for Space Programs WASHINGTON, DC - Secretary of Energy Samuel W. Bodman today announced that the Department of Energy's (DOE) National Nuclear Security Administration (NNSA) will

  14. Energy Department Project Captures and Stores One Million Metric Tons of Carbon

    Broader source: Energy.gov [DOE]

    As part of President Obama’s all-of-the-above energy strategy, the Department of Energy announced today that its Illinois Basin-Decatur Project successfully captured and stored one million metric tons of carbon dioxide (CO2) and injected it into a deep saline formation.

  15. 6 Million Tons of Mill Tailings Removed From DOE Moab Project Site

    Broader source: Energy.gov [DOE]

    (Grand Junction, CO) ― Today, the Department of Energy (DOE) announced that 6 million tons of uranium mill tailings have been shipped from Moab, Utah, under the Uranium Mill Tailings Remedial Action Project to an engineered disposal cell near Crescent Junction, Utah.

  16. Planning for the 400,000 tons/year AISI ironmaking demonstration plant

    SciTech Connect (OSTI)

    Aukrust, E. . AISI Direct Steelmaking Program)

    1993-01-01

    The American Iron and Steel Institute (AISI) has formulated a four-year program to design, construct, and operate a 400,000 net ton per year ironmaking demonstration plant. The plant will employ the coal-based ironmaking process developed under a 1989 cooperative agreement with DOE. AISI will manage the design and construction to be completed in the first two years and operate the plant for the second two years with a variety or ores, coals, and fluxes. Campaigns of increasing length are planned to optimize operations. After successful operation, the plant will be taken over by the host company. Results of studies to date indicate that, on a commercial scale, the AISI process will use 27% less energy and have variable operating costs $10 per ton lower and capital costs of $160 per annual ton, compared to the $250 per annual ton rebuild cost for the coke oven-blast furnace process it will replace. The process will enable the domestic steel industry to become more competitive by reducing its capital and operating cost. Furthermore, by eliminating the pollution problems associated with coke production and by completely enclosing the smelting reactions, this process represents a major step towards an environmentally friendly steel industry.

  17. Variable Average Absolute Percent Differences

    U.S. Energy Information Administration (EIA) Indexed Site

    Variable Average Absolute Percent Differences Percent of Projections Over- Estimated Gross Domestic Product Real Gross Domestic Product (Average Cumulative Growth)* (Table 2) 0.9 45.8 Petroleum Imported Refiner Acquisition Cost of Crude Oil (Constant $) (Table 3a) 37.7 17.3 Imported Refiner Acquisition Cost of Crude Oil (Nominal $) (Table 3b) 36.6 18.7 Total Petroleum Consumption (Table 4) 7.9 70.7 Crude Oil Production (Table 5) 8.1 51.1 Petroleum Net Imports (Table 6) 24.7 73.8 Natural Gas

  18. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur ...

  19. Martinez Sulfuric Acid Regeneration Plt Biomass Facility | Open...

    Open Energy Info (EERE)

    Martinez Sulfuric Acid Regeneration Plt Biomass Facility Jump to: navigation, search Name Martinez Sulfuric Acid Regeneration Plt Biomass Facility Facility Martinez Sulfuric Acid...

  20. Identification of Martian Regolith Sulfur Components In Shergottites...

    Office of Scientific and Technical Information (OSTI)

    Sulfur Components In Shergottites Using Sulfur K XANES and FeS Ratios. Citation Details In-Document Search Title: Identification of Martian Regolith Sulfur Components In ...

  1. Table 19. Average Price of U.S. Coal Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    9. Average Price of U.S. Coal Imports (dollars per short ton) Year to Date Continent and Country of Origin January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 71.92 104.33 107.02 71.92 107.02 -32.8 Canada 71.93 104.32 107.01 71.93 107.01 -32.8 Mexico 66.79 360.25 113.43 66.79 113.43 -41.1 South America Total 64.73 64.18 70.82 64.73 70.82 -8.6 Colombia 64.73 63.86 70.58 64.73 70.58 -8.3 Peru 63.31 86.76 86.19 63.31 86.19 -26.5 Venezuela -

  2. Table 22. Average Price of U.S. Coke Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Average Price of U.S. Coke Imports (dollars per short ton) Year to Date Continent and Country of Origin January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 181.85 113.11 213.82 181.85 213.82 -15.0 Canada 181.85 113.11 213.82 181.85 213.82 -15.0 Europe Total 270.94 416.80 770.50 270.94 770.50 -64.8 Austria - 1,788.00 - - - - France - 1,110.35 - - - - Germany, Federal Republic of - - 206.27 - 206.27 - Italy 265.37 300.11 - 265.37 - -

  3. Table 8. Average Price of U.S. Coal Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    8. Average Price of U.S. Coal Exports (dollars per short ton) Year to Date Continent and Country of Destination January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 62.62 81.09 76.28 62.62 76.28 -17.9 Canada* 87.37 97.37 80.39 87.37 80.39 8.7 Dominican Republic 213.68 - 461.75 213.68 461.75 -53.7 Guatemala - 66.22 359.27 - 359.27 - Honduras 78.02 78.02 54.43 78.02 54.43 43.3 Jamaica 38.10 39.48 45.51 38.10 45.51 -16.3 Mexico 41.25 37.52

  4. Seal for sodium sulfur battery

    DOE Patents [OSTI]

    Topouzian, Armenag; Minck, Robert W.; Williams, William J.

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which the sealing is accomplished by a radial compression seal made on a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  5. Texas CO2 Capture Demonstration Project Hits Three Million Metric Ton Milestone

    Broader source: Energy.gov [DOE]

    On June 30, Allentown, PA-based Air Products and Chemicals, Inc. successfully captured and transported, via pipeline, its 3 millionth metric ton of carbon dioxide (CO2) to be used for enhanced oil recovery. This achievement highlights the ongoing success of a carbon capture and storage (CCS) project sponsored by the U.S. Department of Energy (DOE) and managed by the National Energy Technology Laboratory (NETL).

  6. Recovery of sulfur from native ores

    SciTech Connect (OSTI)

    Womack, J.T.; Wiewiorowski, T.K.; Astley, V.C.; Perez, J.W.; Headington, T.A.

    1992-03-17

    This patent describes a process for removing elemental sulfur from ores containing elemental sulfur. It comprises crushing a sulfur-containing ore to a coarse particle size wherein ore particles produced during crushing enable substantially all of the sulfur to be liberated during a heating step and to produce an ore gangue that is substantially not susceptible to flotation: forming an aqueous ore slurry containing about 50-80% by weight of solids from the crushed ore and adjusting the pH to at least a pH of about 8.0; heating the aqueous ore slurry formed in step (b) under elevated pressure to a temperature of about 240{degrees} - 315{degrees} F. for sufficient time to melt and liberate elemental sulfur contained in the ore to produce liberated molten sulfur and ore gangue, wherein the slurry is heated while agitating the slurry at sufficient velocity to substantially maintain the ore, ore gangue and liberated molten sulfur in suspension; cooling the heated slurry sufficiently to resolidify the liberated molten sulfur; conditioning the aqueous slurry of step (d) with a flotation aid; separating the condition aqueous slurry of ore gangue and resolidified sulfur in a flotation unit to produce a sulfur-rich flotation concentrate overstream; and recovering the sulfur-rich flotation concentrate and separating the sulfur therefrom.

  7. Two stage sorption of sulfur compounds

    DOE Patents [OSTI]

    Moore, William E.

    1992-01-01

    A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

  8. How well will ton-scale dark matter direct detection experiments constrain minimal supersymmetry?

    SciTech Connect (OSTI)

    Akrami, Yashar; Savage, Christopher; Scott, Pat; Conrad, Jan; Edsj, Joakim E-mail: savage@fysik.su.se E-mail: conrad@fysik.su.se

    2011-04-01

    Weakly interacting massive particles (WIMPs) are amongst the most interesting dark matter (DM) candidates. Many DM candidates naturally arise in theories beyond the standard model (SM) of particle physics, like weak-scale supersymmetry (SUSY). Experiments aim to detect WIMPs by scattering, annihilation or direct production, and thereby determine the underlying theory to which they belong, along with its parameters. Here we examine the prospects for further constraining the Constrained Minimal Supersymmetric Standard Model (CMSSM) with future ton-scale direct detection experiments. We consider ton-scale extrapolations of three current experiments: CDMS, XENON and COUPP, with 1000 kg-years of raw exposure each. We assume energy resolutions, energy ranges and efficiencies similar to the current versions of the experiments, and include backgrounds at target levels. Our analysis is based on full likelihood constructions for the experiments. We also take into account present uncertainties on hadronic matrix elements for neutralino-quark couplings, and on halo model parameters. We generate synthetic data based on four benchmark points and scan over the CMSSM parameter space using nested sampling. We construct both Bayesian posterior PDFs and frequentist profile likelihoods for the model parameters, as well as the mass and various cross-sections of the lightest neutralino. Future ton-scale experiments will help substantially in constraining supersymmetry, especially when results of experiments primarily targeting spin-dependent nuclear scattering are combined with those directed more toward spin-independent interactions.

  9. Catalytic conversion of sulfur dioxide and trioxide

    SciTech Connect (OSTI)

    Solov'eva, E.L.; Shenfel'd, B.E.; Kuznetsova, S.M.; Khludenev, A.G.

    1987-11-10

    The reclamation and utilization of sulfur-containing wastes from the flue gas of fossil-fuel power plants and the subsequent reduction in sulfur emission is addressed in this paper. The authors approach this problem from the standpoint of the catalytic oxidation of sulfur dioxide on solid poison-resistant catalysts with subsequent sorption of the sulfur trioxide and its incorporation into the manufacture of sulfuric acid. The catalyst they propose is a polymetallic dust-like waste from the copper-smelting industry comprised mainly of iron and copper oxides. Experiments with this catalyst were carried out using multifactorial experiment planning.

  10. Process for reducing sulfur in coal char

    DOE Patents [OSTI]

    Gasior, Stanley J.; Forney, Albert J.; Haynes, William P.; Kenny, Richard F.

    1976-07-20

    Coal is gasified in the presence of a small but effective amount of alkaline earth oxide, hydroxide or carbonate to yield a char fraction depleted in sulfur. Gases produced during the reaction are enriched in sulfur compounds and the alkaline earth compound remains in the char fraction as an alkaline earth oxide. The char is suitable for fuel use, as in a power plant, and during combustion of the char the alkaline earth oxide reacts with at least a portion of the sulfur oxides produced from the residual sulfur contained in the char to further lower the sulfur content of the combustion gases.

  11. Criticality Safety Review of 2 1/2-, 10-, and 14-Ton UF(Sub 6) Cylinders

    SciTech Connect (OSTI)

    Broadhead, B.L.

    1991-01-01

    Currently, UF{sub 6} cylinders designed to contain 2 1/2 tons of UF{sub 6} are classified as Fissile Class II packages with a transport index (TI) of 5 for the purpose of transportation. The 10-ton UF{sub 6} cylinders are classified as Fissile Class I with no TI assigned for transportation. The 14-ton cylinders, although not certified for transport with enrichments greater than 1 wt % because they have no approved overpack, can be used in on-site operations for enrichments greater than 1 wt %. The maximum 235U enrichments for these cylinders are 5.0 wt % for the 2 1/2-ton cylinder and 4.5 wt % for the 10- and 14-ton cylinders. This work reviews the suitability for reclassification of the 2 1/2-ton UF{sub 6} packages as Fissile Class I with a maximum {sup 235}U enrichment of 5 wt %. Additionally, the 10- and 14-ton cylinders are reviewed to address a change in maximum {sup 235}U enrichment from 4.5 to 5 wt %. Based on this evaluation, the 2 1/2-ton UF{sub 6} cylinders meet the 10 CFR.71 criteria for Fissile Class I packages, and no TI is needed for criticality safety purposes; however, a TI may be required based on radiation from the packages. Similarly, the 10- and 14-ton UF{sub 6} packages appear acceptable for a maximum enrichment rating change to 5 wt % {sup 235}U.

  12. Facile synthesis, spectral properties and formation mechanism of sulfur nanorods in PEG-200

    SciTech Connect (OSTI)

    Xie, Xin-yuan; Li, Li-yun; Zheng, Pu-sheng; Zheng, Wen-jie; Bai, Yan; Cheng, Tian-feng; Liu, Jie

    2012-11-15

    Graphical abstract: Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of about 68 was obtained. The sulfur nanoparticles could self-assemble from spherical particles to nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift which was due to the production of nanorods. Highlights: ? A novel, facile and greener method to synthesize sulfur nanorods by the solubilizing and templating effect of PEG-200 was reported. ? S{sup 0} nanoparticles could self assemble in PEG-200 and finally form monodisperse and homogeneous rod-like structure with an average diameter of about 80 nm, the length ca. 600 nm. ? The absorption band showed a red shift and the RRS intensity enhanced continuously during the self-assembling process. ? PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal hydroxyl groups. -- Abstract: The synthesis of nano-sulfur sol by dissolving sublimed sulfur in a green solvent-PEG-200 was studied. Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of 68 was obtained. The structure, morphology, size, and stability of the products were investigated by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and dynamic light scattering (DLS) measurements. The spectral properties of the products were investigated by ultraviolet-visible (UVvis) absorption and resonance Rayleigh scattering spectroscopy (RRS). The results showed that the spherical sulfur nanoparticles could self-assemble into nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift and the RRS intensity enhanced continuously. There was physical cross-linking between PEG and sulfur nanoparticles. PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal

  13. 12,893,780 Metric Tons of CO2 Injected as of July 19, 2016 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 12,893,780 Metric Tons of CO2 Injected as of July 19, 2016 12,893,780 Metric Tons of CO2 Injected as of July 19, 2016 This carbon dioxide (CO2) has been injected in the United States as part of DOE's Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is equivalent to the annual greenhouse gas emissions from 210,526 passenger vehicles. The projects currently injecting CO2 within DOE's Regional Carbon Sequestration Partnership Program and the

  14. Occidental Chemical's Energy From Waste facility: 3,000,000 tons later

    SciTech Connect (OSTI)

    Blasins, G.F. )

    1988-01-01

    Occidental Chemical's Energy From Waste's cogeneration facility continues to be one of the most successful RDF plants in the U.S. The facility began operation in 1980 and was an operational success after a lengthy 2-1/2 year start-up and redesign, utilizing the air classification technology to produce RDF. In 1984, the plant was converted to a simplified shred and burn concept, significantly improving overall economics and viability of the operation. After processing 3.0 million tons the facility is a mature operation with a well developed experience base in long range operation and maintenance of the equipment utilized for processing and incinerating municipal solid waste.

  15. Table 11.4 Nitrous Oxide Emissions, 1980-2009 (Thousand Metric Tons of Nitrous Oxide)

    U.S. Energy Information Administration (EIA) Indexed Site

    Nitrous Oxide Emissions, 1980-2009 (Thousand Metric Tons of Nitrous Oxide) Year Energy Sources Waste Management Agricultural Sources Industrial Processes 3 Total Mobile Combustion 1 Stationary Combustion 2 Total Waste Combustion Human Sewage in Wastewater Total Nitrogen Fertilization of Soils Crop Residue Burning Solid Waste of Domesticated Animals Total 1980 60 44 104 1 10 11 364 1 75 440 88 642 1981 63 44 106 1 10 11 364 2 74 440 84 641 1982 67 42 108 1 10 11 339 2 74 414 80 614 1983 71 43 114

  16. An ounce of prevention, a ton of cure | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An ounce of prevention, a ... An ounce of prevention, a ton of cure Posted: June 24, 2015 - 3:11pm Aaron Spoon of Power Operations performs maintenance on 13.8 kV transformers 145 and 145A. Photo by Scott Fraker Y-12 recently saved time, taxpayer dollars, effort and potential injuries by taking a 72-hour planned simultaneous outage of power, steam and air systems. The weekend outage allowed a small army of Y-12 infrastructure, facilities and utilities workers to make repairs and perform

  17. U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry

    SciTech Connect (OSTI)

    Downing, Mark; Eaton, Laurence M; Graham, Robin Lambert; Langholtz, Matthew H; Perlack, Robert D; Turhollow Jr, Anthony F; Stokes, Bryce; Brandt, Craig C

    2011-08-01

    The report, Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply (generally referred to as the Billion-Ton Study or 2005 BTS), was an estimate of 'potential' biomass based on numerous assumptions about current and future inventory, production capacity, availability, and technology. The analysis was made to determine if conterminous U.S. agriculture and forestry resources had the capability to produce at least one billion dry tons of sustainable biomass annually to displace 30% or more of the nation's present petroleum consumption. An effort was made to use conservative estimates to assure confidence in having sufficient supply to reach the goal. The potential biomass was projected to be reasonably available around mid-century when large-scale biorefineries are likely to exist. The study emphasized primary sources of forest- and agriculture-derived biomass, such as logging residues, fuel treatment thinnings, crop residues, and perennially grown grasses and trees. These primary sources have the greatest potential to supply large, reliable, and sustainable quantities of biomass. While the primary sources were emphasized, estimates of secondary residue and tertiary waste resources of biomass were also provided. The original Billion-Ton Resource Assessment, published in 2005, was divided into two parts-forest-derived resources and agriculture-derived resources. The forest resources included residues produced during the harvesting of merchantable timber, forest residues, and small-diameter trees that could become available through initiatives to reduce fire hazards and improve forest health; forest residues from land conversion; fuelwood extracted from forests; residues generated at primary forest product processing mills; and urban wood wastes, municipal solid wastes (MSW), and construction and demolition (C&D) debris. For these forest resources, only residues, wastes, and small-diameter trees were

  18. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in Li–S battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfurmore » were the S42– and S52– species, while the widely accepted reduction products of S82– and S62– for the first reduction wave were in low abundance.« less

  19. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in Li–S battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfur were the S42– and S52– species, while the widely accepted reduction products of S82– and S62– for the first reduction wave were in low abundance.

  20. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  1. Table 11.3 Methane Emissions, 1980-2009 (Million Metric Tons of Methane)

    U.S. Energy Information Administration (EIA) Indexed Site

    Methane Emissions, 1980-2009 (Million Metric Tons of Methane) Year Energy Sources Waste Management Agricultural Sources Industrial Processes 9 Total 5 Coal Mining Natural Gas Systems 1 Petroleum Systems 2 Mobile Com- bustion 3 Stationary Com- bustion 4 Total 5 Landfills Waste- water Treatment 6 Total 5 Enteric Fermen- tation 7 Animal Waste 8 Rice Cultivation Crop Residue Burning Total 5 1980 3.06 4.42 NA 0.28 0.45 8.20 10.52 0.52 11.04 5.47 2.87 0.48 0.04 8.86 0.17 28.27 1981 2.81 5.02 NA .27

  2. Table 4.8 Coal Demonstrated Reserve Base, January 1, 2011 (Billion Short Tons)

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Coal Demonstrated Reserve Base, January 1, 2011 (Billion Short Tons) Region and State Anthracite Bituminous Coal Subbituminous Coal Lignite Total Underground Surface Underground Surface Underground Surface Surface 1 Underground Surface Total Appalachian 4.0 3.3 68.2 21.9 0.0 0.0 1.1 72.1 26.3 98.4 Alabama .0 .0 .9 2.1 .0 .0 1.1 .9 3.1 4.0 Kentucky, Eastern .0 .0 .8 9.1 .0 .0 .0 .8 9.1 9.8 Ohio .0 .0 17.4 5.7 .0 .0 .0 17.4 5.7 23.1 Pennsylvania 3.8 3.3 18.9 .8 .0 .0 .0 22.7 4.2 26.9 Virginia .1

  3. Table 7.2 Coal Production, 1949-2011 (Short Tons)

    U.S. Energy Information Administration (EIA) Indexed Site

    Coal Production, 1949-2011 (Short Tons) Year Rank Mining Method Location Total 1 Bituminous Coal 1 Subbituminous Coal Lignite Anthracite 1 Underground Surface 1 East of the Mississippi 1 West of the Mississippi 1 1949 437,868,000 [2] [2] 42,702,000 358,854,000 121,716,000 444,199,000 36,371,000 480,570,000 1950 516,311,000 [2] [2] 44,077,000 421,000,000 139,388,000 524,374,000 36,014,000 560,388,000 1951 533,665,000 [2] [2] 42,670,000 442,184,000 134,151,000 541,703,000 34,632,000 576,335,000

  4. Table 7.4 Coal Imports by Country of Origin, 2000-2011 (Short Tons)

    U.S. Energy Information Administration (EIA) Indexed Site

    Coal Imports by Country of Origin, 2000-2011 (Short Tons) Year Australia New Zealand Canada Mexico Colombia Venezuela China India Indonesia Europe South Africa Other Total Norway Poland Russia Ukraine United Kingdom Other Total 2000 167,595 0 1,923,434 6,671 7,636,614 2,038,774 19,646 205 718,149 0 0 1,212 0 238 0 1,450 0 85 12,512,623 2001 315,870 24,178 2,571,415 8,325 11,176,191 3,335,258 109,877 1,169 882,455 15,933 514,166 219,077 0 75,704 12 824,892 440,408 97,261 19,787,299 2002 821,280 0

  5. Table 7.5 Coal Exports by Country of Destination, 1960-2011 (Thousand Short Tons)

    U.S. Energy Information Administration (EIA) Indexed Site

    Coal Exports by Country of Destination, 1960-2011 (Thousand Short Tons) Year Canada Brazil Europe Japan Other 3 Total Belgium 1 Denmark France Germany 2 Italy Nether- lands Spain Turkey United Kingdom Other 3 Total 1960 12,843 1,067 1,116 130 794 4,566 4,899 2,837 331 NA – 2,440 17,113 5,617 1,341 37,981 1961 12,135 994 971 80 708 4,326 4,797 2,552 228 NA – 2,026 15,688 6,614 974 36,405 1962 12,302 1,327 1,289 38 851 5,056 5,978 3,320 766 NA 2 1,848 19,148 6,465 973 40,215 1963 14,557 1,161

  6. Table 7.7 Coal Mining Productivity, 1949-2011 (Short Tons per Employee Hour )

    U.S. Energy Information Administration (EIA) Indexed Site

    Coal Mining Productivity, 1949-2011 (Short Tons per Employee Hour 1) Year Mining Method Location Total 2 Underground Surface 2 East of the Mississippi West of the Mississippi Underground Surface 2 Total 2 Underground Surface 2 Total 2 1949 0.68 [3] 1.92 [3] NA NA NA NA NA NA 0.72 1950 .72 [3] 1.96 [3] NA NA NA NA NA NA .76 1951 .76 [3] 2.00 [3] NA NA NA NA NA NA .80 1952 .80 [3] 2.10 [3] NA NA NA NA NA NA .84 1953 .88 [3] 2.22 [3] NA NA NA NA NA NA .93 1954 1.00 [3] 2.48 [3] NA NA NA NA NA NA

  7. Table 7.9 Coal Prices, 1949-2011 (Dollars per Short Ton)

    U.S. Energy Information Administration (EIA) Indexed Site

    Coal Prices, 1949-2011 (Dollars per Short Ton) Year Bituminous Coal Subbituminous Coal Lignite 1 Anthracite Total Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 1949 4.90 [4] 33.80 [4,R] [4] [4] 2.37 16.35 [R] 8.90 61.38 [R] 5.24 36.14 [R] 1950 4.86 [4] 33.16 [4,R] [4] [4] 2.41 16.44 [R] 9.34 63.73 [R] 5.19 35.41 [R] 1951 4.94 [4] 31.44 [4,R] [4] [4] 2.44 15.53 [R] 9.94 63.26 [R] 5.29 33.67 [R] 1952 4.92 [4] 30.78 [4,R] [4] [4] 2.39 14.95 [R] 9.58 59.94 [R]

  8. Dynamic performance testing of prototype 3 ton air-cooled carrier absorption chiller

    SciTech Connect (OSTI)

    Borst, R.R.; Wood, B.D.

    1985-05-01

    The performance of a prototype 3 ton cooling capacity air-cooled lithium bromide/water absorption chiller was tested using an absorption chiller test facility which was modified to expand its testing capabilities to include air-cooled chillers in addition to water-cooled chillers. Temperatures of the three externally supplied fluid loops: hot water, chilled water, and cooling air, were varied in order to determine the effects this would have on the two principal measures of chiller performance: cooling capacity and thermal coefficient of performance (COP). A number of interrelated factors were identified as contributing to less than expected performance. For comparison, experimental correlations of other investigators for this and other similar absorption chillers are presented. These have been plotted as both contour and three-dimensional performance maps in order to more clearly show the functional dependence of the chiller performance on the fluid loop temperatures.

  9. Cracked lifting lug welds on ten-ton UF{sub 6} cylinders

    SciTech Connect (OSTI)

    Dorning, R.E.

    1991-12-31

    Ten-ton, Type 48X, UF{sub 6} cylinders are used at the Portsmouth Gaseous Diffusion Plant to withdraw enriched uranium hexafluoride from the cascade, transfer enriched uranium hexafluoride to customer cylinders, and feed enriched product to the cascade. To accomplish these activities, the cylinders are lifted by cranes and straddle carriers which engage the cylinder lifting lugs. In August of 1988, weld cracks on two lifting lugs were discovered during preparation to lift a cylinder. The cylinder was rejected and tagged out, and an investigating committee formed to determine the cause of cracking and recommend remedial actions. Further investigation revealed the problem may be general to this class of cylinder in this use cycle. This paper discusses the actions taken at the Portsmouth site to deal with the cracked lifting lug weld problem. The actions include inspection activities, interim corrective actions, metallurgical evaluation of cracked welds, weld repairs, and current monitoring/inspection program.

  10. Sulfur-carbon nanocomposites and their application as cathode materials in lithium-sulfur batteries

    SciTech Connect (OSTI)

    Liang, Chengdu; Dudney, Nancy J; Howe, Jane Y

    2015-05-05

    The invention is directed in a first aspect to a sulfur-carbon composite material comprising: (i) a bimodal porous carbon component containing therein a first mode of pores which are mesopores, and a second mode of pores which are micropores; and (ii) elemental sulfur contained in at least a portion of said micropores. The invention is also directed to the aforesaid sulfur-carbon composite as a layer on a current collector material; a lithium ion battery containing the sulfur-carbon composite in a cathode therein; as well as a method for preparing the sulfur-composite material.

  11. Stabilized sulfur binding using activated fillers

    DOE Patents [OSTI]

    Kalb, Paul D.; Vagin, Vyacheslav P.; Vagin, Sergey P.

    2015-07-21

    A method of making a stable, sulfur binding composite comprising impregnating a solid aggregate with an organic modifier comprising unsaturated hydrocarbons with at least one double or triple covalent bond between adjacent carbon atoms to create a modifier-impregnated aggregate; heating and drying the modifier-impregnated aggregate to activate the surface of the modifier-impregnated aggregate for reaction with sulfur.

  12. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu; King, David L.

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  13. Effect of coal quality on maintenance costs at utility plants. Final report. [Effect of ash and sulfur content of coal

    SciTech Connect (OSTI)

    Holt, E.C. Jr.

    1980-06-01

    In an attempt to determine if correlation exists between coal quality, as measured by its ash and sulfur contents, and the maintenance cost at utility plants, an examination was made of the actual maintenance cost experience of selected portions of five TVA coal-fired power plants as a function of the fuel quality consumed during an extended period of time. The results indicate that, according to our decision rules developed in compliance with accepted statistical practices, correlation does exist in many portions of the coal-fired plants for which sufficient maintenance cost records were available. The degree of correlation varies significantly among the individual portions of a particular plant as well as among the various plants. However, the indicators are sufficient to confirm that a change (within the design constraints of the unit) in the ash and/or sulfur content of the coal being consumed by a utility boiler will have a proportionate effect on the maintenance cost at the plant. In the cases examined, each percent variation in ash content could have a monetary effect of from $0.05 to $0.10 per ton of coal consumed. Similarly, each percent variation in sulfur content could influence maintenance costs from $0.30 to $0.50 per ton of coal. Since these values are based on preliminary analysis of limited data, they must be approached with caution and not removed from the context in which they are presented. However, if borne out by further study, the potential magnitude of such savings may be sufficient to justify the acquisition of superior coal supplies, either by changing the source and/or using preparation to obtain a lower ash and sulfur fuel.

  14. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 ...

  15. Scientists Probe Lithium-Sulfur Batteries in Real Time - Joint...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7, 2012, Videos Scientists Probe Lithium-Sulfur Batteries in Real Time Lithium-sulfur batteries are a promising technology that could some day power electric vehicles. Scientists ...

  16. Understanding Lithium-Sulfur Batteries at the Molecular Level...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 17, 2015, Accomplishments Understanding Lithium-Sulfur Batteries at the Molecular Level Conceived some 40 years ago, the lithium-sulfur battery can store, in theory, ...

  17. Sulfur Poisoning of Metal Membranes for Hydrogen Separation ...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Sulfur Poisoning of Metal Membranes for Hydrogen Separation Citation Details In-Document Search Title: Sulfur Poisoning of Metal Membranes for Hydrogen Separation ...

  18. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G.; Mohan, Thyagarajan; Angelici, Robert J.

    1995-01-01

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  19. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  20. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  1. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    . Receipts, Average Cost, and Quality of Fossil Fuels for the Electric Power Industry, 2004 through 2014 Coal Petroleum Natural Gas All Fossil Fuels Average Cost Average Cost Average Cost Average Cost Period Receipts (Thousand Tons) Average Sulfur Percent by Weight (Dollars per MMBtu) (Dollars per Ton) Receipts (Thousand Barrels) Average Sulfur Percent by Weight (Dollars per MMBtu) (Dollars per Barrel) Receipts (Thousand Mcf) (Dollars per MMBtu) (Dollars per MMBtu) 2004 1,002,032 0.97 1.36 27.42

  2. Average and effective Q-values for fission product average (n...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Average and effective Q-values for fission product average (n,2n) and (n,3n) reaction cross sections Citation Details In-Document Search Title: Average and ...

  3. Average and effective Q-values for fission product average (n...

    Office of Scientific and Technical Information (OSTI)

    Average and effective Q-values for fission product average (n,2n) and (n,3n) reaction cross sections Citation Details In-Document Search Title: Average and effective Q-values for ...

  4. 1000–ton testing machine for cyclic fatigue tests of materials at liquid nitrogen temperatures

    SciTech Connect (OSTI)

    Khitruk, A. A.; Klimchenko, Yu. A.; Kovalchuk, O. A.; Marushin, E. L.; Mednikov, A. A.; Nasluzov, S. N.; Privalova, E. K.; Rodin, I. Yu.; Stepanov, D. B.; Sukhanova, M. V.

    2014-01-29

    One of the main tasks of superconductive magnets R and D is to determine the mechanical and fatigue properties of structural materials and the critical design elements in the cryogenic temperature range. This paper describes a new facility built based on the industrial 1000-ton (10 MN) testing machine Schenk PC10.0S. Special equipment was developed to provide the mechanical and cyclic tensile fatigue tests of large-scale samples at the liquid nitrogen temperature and in a given load range. The main feature of the developed testing machine is the cryostat, in which the device converting a standard compression force of the testing machine to the tensile force affected at the test object is placed. The control system provides the remote control of the test and obtaining, processing and presentation of test data. As an example of the testing machine operation the test program and test results of the cyclic tensile fatigue tests of fullscale helium inlet sample of the PF1 coil ITER are presented.

  5. Performance and results of the LBNE 35 ton membrane cryostat prototype

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Montanari, David; Adamowski, Mark; Hahn, Alan; Norris, Barry; Reichenbacher, Juergen; Rucinski, Russell; Stewart, Jim; Tope, Terry

    2015-07-15

    We report on the performance and commissioning of the first membrane cryostat to be used for scientific application. The Long Baseline Neutrino Experiment (LBNE) has designed and fabricated a membrane cryostat prototype in collaboration with Ishikawajima-Harima Heavy Industries Co., Ltd. (IHI). LBNE has designed and fabricated the supporting cryogenic system infrastructure and successfully commissioned and operated the first membrane cryostat. Original goals of the prototype are: to demonstrate the membrane cryostat technology in terms of thermal performance, feasibility for liquid argon and leak tightness; to demonstrate that we can remove all the impurities from the vessel and achieve the puritymore » requirements in a membrane cryostat without evacuation; to demonstrate that we can achieve and maintain the purity requirements of the liquid argon using mol sieve and copper filters. The purity requirements of a large liquid argon detector such as LBNE are contaminants below 200 parts per trillion (ppt) oxygen equivalent. LBNE is planning the design and construction of a large liquid argon detector. This presentation will present requirements, design and construction of the LBNE 35 ton membrane cryostat prototype, and detail the commissioning and performance. The experience and results of this prototype are extremely important for the development of the LBNE detector.« less

  6. Performance and results of the LBNE 35 ton membrane cryostat prototype

    SciTech Connect (OSTI)

    Montanari, David; Adamowski, Mark; Hahn, Alan; Norris, Barry; Reichenbacher, Juergen; Rucinski, Russell; Stewart, Jim; Tope, Terry

    2015-07-15

    We report on the performance and commissioning of the first membrane cryostat to be used for scientific application. The Long Baseline Neutrino Experiment (LBNE) has designed and fabricated a membrane cryostat prototype in collaboration with Ishikawajima-Harima Heavy Industries Co., Ltd. (IHI). LBNE has designed and fabricated the supporting cryogenic system infrastructure and successfully commissioned and operated the first membrane cryostat. Original goals of the prototype are: to demonstrate the membrane cryostat technology in terms of thermal performance, feasibility for liquid argon and leak tightness; to demonstrate that we can remove all the impurities from the vessel and achieve the purity requirements in a membrane cryostat without evacuation; to demonstrate that we can achieve and maintain the purity requirements of the liquid argon using mol sieve and copper filters. The purity requirements of a large liquid argon detector such as LBNE are contaminants below 200 parts per trillion (ppt) oxygen equivalent. LBNE is planning the design and construction of a large liquid argon detector. This presentation will present requirements, design and construction of the LBNE 35 ton membrane cryostat prototype, and detail the commissioning and performance. The experience and results of this prototype are extremely important for the development of the LBNE detector.

  7. High temperature experiments on a 4 tons UF6 container TENERIFE program

    SciTech Connect (OSTI)

    Casselman, C.; Duret, B.; Seiler, J.M.; Ringot, C.; Warniez, P.

    1991-12-31

    The paper presents an experimental program (called TENERIFE) whose aim is to investigate the behaviour of a cylinder containing UF{sub 6} when exposed to a high temperature fire for model validation. Taking into account the experiments performed in the past, the modelization needs further information in order to be able to predict the behaviour of a real size cylinder when engulfed in a 800{degrees}C fire, as specified in the regulation. The main unknowns are related to (1) the UF{sub 6} behaviour beyond the critical point, (2) the relationship between temperature field and internal pressure and (3) the equivalent conductivity of the solid UF{sub 6}. In order to investigate these phenomena in a representative way it is foreseen to perform experiments with a cylinder of real diameter, but reduced length, containing 4 tons of UF{sub 6}. This cylinder will be placed in an electrically heated furnace. A confinement vessel prevents any dispersion of UF{sub 6}. The heat flux delivered by the furnace will be calibrated by specific tests. The cylinder will be changed for each test.

  8. ,"Selected National Average Natural Gas Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    Selected National Average Natural Gas Prices" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data ...

  9. A new, safer method of sulfur degassing

    SciTech Connect (OSTI)

    Schico, C.M.; Clem, K.R.; Hartley, D.; Watson, E.A.

    1985-10-01

    The Exxon system for degassing liquid sulfur is presented, and it can reduce total H2S in liquid sulfur to levels as low as 10-15 wppm under the commercial conditions tested. Because Exxon found commercially available mechanical degassing systems to be inadequate, the Claus plant initiated an RandD program to develop the new degassing process. Hydrogen sulfide and hydrogen polysulfide are inherent to the Claus process. The major concerns associated with this H2S in the Claus liquid sulfur include: toxic levels of H2S are possible while loading/unloading liquid sulfur; the H2S lower explosive limit in air can be exceeded in unvented pit/tank vapor space; nuisance odors/environmental concerns; and potential government regulations/ customer restrictions. Results are presented in this article of successful commercial tests using the process at five sites.

  10. "Table A29. Average Prices of Selected Purchased Energy Sources...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...,"(gallon)","(gallon)","(1000 cu ft)","(gallon)","(short ton)","Factors" ,"Total United States" "RSE Column Factors:",0.7,1.2,1.1,0.8,1.2,1 "Value of Shipments and Receipts " ...

  11. "Table A41. Average Prices of Selected Purchased Energy Sources...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...allons)","(gallons)","(1000 cu ft)","(gallons)","(short tons)","Factors" ,"Total United States" "RSE Column Factors:",0.6,0.8,1.2,0.7,2.5,0.9 "Value of Shipments and Receipts" ...

  12. Definition of Non-Conventional Sulfur Utilization in Western Kazakhstan for Sulfur Concrete (Phase 1)

    SciTech Connect (OSTI)

    Kalb, Paul

    2007-05-31

    Battelle received a contract from Agip-KCO, on behalf a consortium of international oil and gas companies with exploration rights in the North Caspian Sea, Kazakhstan. The objective of the work was to identify and help develop new techniques for sulfur concrete products from waste, by-product sulfur that will be generated in large quantitites as drilling operations begin in the near future. BNL has significant expertise in the development and use of sulfur concrete products and has direct experience collaborating with the Russian and Kazakh partners that participated. Feasibility testing was successfully conducted for a new process to produce cost-effective sulfur polymer cement that has broad commerical applications.

  13. Method for reducing the sulfur content of a sulfur-containing hydrocarbon stream

    DOE Patents [OSTI]

    Mahajan, Devinder

    2004-12-28

    The sulfur content of a liquid hydrocarbon stream is reduced under mild conditions by contracting a sulfur-containing liquid hydrocarbon stream with transition metal particles containing the transition metal in a zero oxidation state under conditions sufficient to provide a hydrocarbon product having a reduced sulfur content and metal sulfide particles. The transition metal particles can be produced in situ by adding a transition metal precursor, e.g., a transition metal carbonyl compound, to the sulfur-containing liquid feed stream and sonicating the feed steam/transition metal precursor combination under conditions sufficient to produce the transition metal particles.

  14. Copper mercaptides as sulfur dioxide indicators

    DOE Patents [OSTI]

    Eller, Phillip G.; Kubas, Gregory J.

    1979-01-01

    Organophosphine copper(I) mercaptide complexes are useful as convenient and semiquantitative visual sulfur dioxide gas indicators. The air-stable complexes form 1:1 adducts in the presence of low concentrations of sulfur dioxide gas, with an associated color change from nearly colorless to yellow-orange. The mercaptides are made by mixing stoichiometric amounts of the appropriate copper(I) mercaptide and phosphine in an inert organic solvent.

  15. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  16. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, Tetsuo; Squires, Thomas G.; Venier, Clifford G.

    1985-02-05

    A process for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  17. Spray drying for high-sulfur coal

    SciTech Connect (OSTI)

    Rhudy, R.

    1988-09-01

    Recent pilot plant tests indicate that spray drying, now used to control SO/sub 2/ emissions from low-sulfur coal, can also be effective for high-sulfur coal. Spray drying coupled with baghouse particulate removal is the most effective configuration tested to date, removing over 90% of SO/sub 2/ while easily meeting New Source Performance Standards for particulate emissions. 2 figures, 1 table.

  18. Dynamic Multiscale Averaging (DMA) of Turbulent Flow

    SciTech Connect (OSTI)

    Richard W. Johnson

    2012-09-01

    A new approach called dynamic multiscale averaging (DMA) for computing the effects of turbulent flow is described. The new method encompasses multiple applications of temporal and spatial averaging, that is, multiscale operations. Initially, a direct numerical simulation (DNS) is performed for a relatively short time; it is envisioned that this short time should be long enough to capture several fluctuating time periods of the smallest scales. The flow field variables are subject to running time averaging during the DNS. After the relatively short time, the time-averaged variables are volume averaged onto a coarser grid. Both time and volume averaging of the describing equations generate correlations in the averaged equations. These correlations are computed from the flow field and added as source terms to the computation on the next coarser mesh. They represent coupling between the two adjacent scales. Since they are computed directly from first principles, there is no modeling involved. However, there is approximation involved in the coupling correlations as the flow field has been computed for only a relatively short time. After the time and spatial averaging operations are applied at a given stage, new computations are performed on the next coarser mesh using a larger time step. The process continues until the coarsest scale needed is reached. New correlations are created for each averaging procedure. The number of averaging operations needed is expected to be problem dependent. The new DMA approach is applied to a relatively low Reynolds number flow in a square duct segment. Time-averaged stream-wise velocity and vorticity contours from the DMA approach appear to be very similar to a full DNS for a similar flow reported in the literature. Expected symmetry for the final results is produced for the DMA method. The results obtained indicate that DMA holds significant potential in being able to accurately compute turbulent flow without modeling for practical

  19. World copper smelter sulfur balance-1988

    SciTech Connect (OSTI)

    Towle, S.W. )

    1993-01-01

    In 1989, the US Bureau of Mines initiated a contract to gather engineering, operating, and environmental cost data for 1988 for 30 major foreign primary copper smelters in market economy countries. Data were collected for 29 of the designated smelters together with information on applicable environmental regulations. Materials balance data obtained were used with available data for the eight US smelters to determine the approximate extent of copper smelter sulfur emission control in 1988. A broad characterization of the status of sulfur emission control regulation was made. The 37 US and foreign smelters represented roughly 73.2% of world and 89.3% of market economy primary copper production in 1988. The 29 non-US smelters attained 55.3% control of their input sulfur in 1988. Combined with the 90.4% control of US smelters, an aggregate 63.4% sulfur control existed. Roughly 1,951,100 mt of sulfur was emitted from the 37 market economy smelters in 1988. Identifiable SO[sub 2] control regulations covered 72.4% of the 29 foreign smelters, representing 65.5% of smelting capacity. Including US smelters, 78.4% of the major market economy smelters were regulated, representing 73.1% of smelting capacity. Significant changes since 1988 that may increase sulfur emission control are noted.

  20. A Proposal for a Ton Scale Bubble Chamber for Dark Matter Detection

    SciTech Connect (OSTI)

    Collar, Juan; Dahl, C.Eric; Fustin, Drew; Robinson, Alan; Behnke, Ed; Behnke, Joshua; Breznau, William; Connor, Austin; Kuehnemund, Emily Grace; Levine, Ilan; Moan, Timothy; /Indiana U., South Bend /Fermilab

    2010-10-07

    The nature of non-baryonic dark matter is one of the most intriguing questions for particle physics at the start of the 21st century. There is ample evidence for its existence, but almost nothing is known of its properties. WIMPs are a very appealing candidate particle and several experimental campaigns are underway around the world to search for these particles via the nuclear recoils that they should induce. The COUPP series of bubble chambers has played a significant role in the WIMP search. Through a sequence of detectors of increasing size, a number of R&D issues have arisen and been solved, and the technology has now been advanced to the point where the construction of large chambers requires a modest research effort, some development, but mostly just engineering. It is within this context that we propose to build the next COUPP detector - COUPP-500, a ton scale device to be built over the next three years at Fermilab and then deployed deep underground at SNOLAB. The primary advantages of the COUPP approach over other technologies are: (1) The ability to reject electron and gamma backgrounds by arranging the chamber thermodynamics such that these particles do not even trigger the detector. (2) The ability to suppress neutron backgrounds by having the radioactively impure detection elements far from the active volume and by using the self-shielding of a large device and the high granularity to identify multiple bubbles. (3) The ability to build large chambers cheaply and with a choice of target fluids. (4) The ability to increase the size of the chambers without changing the size or complexity of the data acquisition. (5) Sensitivity to spin-dependent and spin-independent WIMP couplings. These key advantages should enable the goal of one background event in a ton-year of exposure to be achieved. The conceptual design of COUPP-500 is scaled from the preceding devices. In many cases all that is needed is a simple scaling up of components previously used

  1. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    . Receipts and Quality of Coal Delivered for the Electric Power Industry, 2004 through 2014 Bituminous Subbituminous Lignite Period Receipts (Thousand Tons) Average Sulfur Percent by Weight Average Ash Percent by Weight Receipts (Thousand Tons) Average Sulfur Percent by Weight Average Ash Percent by Weight Receipts (Thousand Tons) Average Sulfur Percent by Weight Average Ash Percent by Weight 2004 470,619 1.52 10.4 445,603 0.36 6.0 78,268 1.05 14.2 2005 480,179 1.56 10.5 456,856 0.36 6.2 77,677

  2. Electrostatic self-assembly of graphene oxide wrapped sulfur particles for lithium–sulfur batteries

    SciTech Connect (OSTI)

    Wu, Haiwei; Huang, Ying Zong, Meng; Ding, Xiao; Ding, Juan; Sun, Xu

    2015-04-15

    Highlights: • Researched graphene oxide wrapped sulfur particles for lithium–sulfur batteries. • New approach for core–shell GO/S composites by electrostatic self-assembly method. • Both core–shell structure and the GO support help to retard the diffusion of polysulfides during the electrochemical cycling process of GO/S cathode. - Abstract: A novel graphene oxide (GO)/sulfur (S) composite is developed by electrostatic self-assembly method. Remarkably, the core–shell structure of the composite and the GO support helps to retard the diffusion of polysulfides during the electrochemical cycling process. The GO/sulfur cathode presents enhanced cycling ability. Specific discharge capacities up to 494.7 mAh g{sup −1} over 200 cycles at 0.1 C is achieved with enhanced columbic efficiency around 95%, representing a good cathode material for lithium–sulfur batteries.

  3. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; et al

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-Smore » cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.« less

  4. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; Yang, Xiao-Qing; Zhang, Ji-Guang; Liu, Jun; Xiao, Jie

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-S cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  5. Direct Observation of Sulfur Radicals as Reaction Media in lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric D.; Pan, Huilin; Lu, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Zhiqun; Liaw, Bor Yann; Yu, Xiqian; Yang, Xiaoning; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge process follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials, it is revealed that the chemical and electrochemical reactions in Li-S cell are driven each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new insights to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  6. Spacetime Average Density (SAD) cosmological measures

    SciTech Connect (OSTI)

    Page, Don N.

    2014-11-01

    The measure problem of cosmology is how to obtain normalized probabilities of observations from the quantum state of the universe. This is particularly a problem when eternal inflation leads to a universe of unbounded size so that there are apparently infinitely many realizations or occurrences of observations of each of many different kinds or types, making the ratios ambiguous. There is also the danger of domination by Boltzmann Brains. Here two new Spacetime Average Density (SAD) measures are proposed, Maximal Average Density (MAD) and Biased Average Density (BAD), for getting a finite number of observation occurrences by using properties of the Spacetime Average Density (SAD) of observation occurrences to restrict to finite regions of spacetimes that have a preferred beginning or bounce hypersurface. These measures avoid Boltzmann brain domination and appear to give results consistent with other observations that are problematic for other widely used measures, such as the observation of a positive cosmological constant.

  7. Effect of sulfur content in a sulfur-activated carbon composite on the electrochemical properties of a lithium/sulfur battery

    SciTech Connect (OSTI)

    Park, Jin-Woo; Kim, Changhyeon; Ryu, Ho-Suk; Cho, Gyu-Bong; Cho, Kwon-Koo; Kim, Ki-Won; Ahn, Jou-Hyeon; Wang, Guoxiu; Ahn, Jae-Pyeung; Ahn, Hyo-Jun

    2015-09-15

    Highlights: • The content of sulfur in activated carbon was controlled by solution process. • The sulfur electrode with low sulfur content shows the best performance. • The Li/S battery has capacity of 1360 mAh/g at 1 C and 702 mAh/g at 10 C. - Abstract: The content of sulfur in sulfur/activated carbon composite is controlled from 32.37 wt.% to 55.33 wt.% by a one-step solution-based process. When the sulfur content is limited to 41.21 wt.%, it can be loaded into the pores of an activated carbon matrix in a highly dispersed state. On the contrary, when the sulfur content is 55.33 wt.%, crystalline sulfur can be detected on the surface of the activated carbon matrix. The best electrochemical performance can be obtained for a sulfur electrode with the lowest sulfur content. The sulfur/activated carbon composite with 32.37 wt.% sulfur afforded the highest first discharge capacity of 1360 mAh g{sup −1} at 1 C rate and a large reversible capacity of 702 mAh g{sup −1} at 10 C (16.75 A/g)

  8. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Broader source: Energy.gov (indexed) [DOE]

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Vehicle Technologies ...

  9. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Broader source: Energy.gov (indexed) [DOE]

    CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Protection of Li Anodes ...

  10. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  11. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, Perry E.

    1981-01-01

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another.

  12. Reynolds-Averaged Navier-Stokes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reynolds-Averaged Navier-Stokes simulation of the heave performance of a two-body floating-point absorber wave energy system Yi-Hsiang Yu, Ye Li ⇑ National Wind Technology Center, National Renewable Energy Laboratory (NREL), Golden, CO 80401, USA a r t i c l e i n f o Article history: Received 7 September 2011 Received in revised form 5 August 2012 Accepted 9 October 2012 Available online 17 October 2012 Keywords: Wave energy conversion Heave Computational Fluid Dynamics Reynolds-averaged

  13. STEO January 2013 - average gasoline prices

    U.S. Energy Information Administration (EIA) Indexed Site

    drivers to see lower average gasoline prices in 2013 and 2014 U.S. retail gasoline prices are expected to decline over the next two years. The average pump price for regular unleaded gasoline was $3.63 a gallon during 2012. That is expected to fall to $3.44 this year and then drop to $3.34 in 2014, according to the new forecast from the U.S. Energy Information Administration. Expected lower crude oil prices.....which accounted for about two-thirds of the price of gasoline in 2012....will

  14. Polarized electron beams at milliampere average current

    SciTech Connect (OSTI)

    Poelker, Matthew

    2013-11-01

    This contribution describes some of the challenges associated with developing a polarized electron source capable of uninterrupted days-long operation at milliAmpere average beam current with polarization greater than 80%. Challenges will be presented in the context of assessing the required level of extrapolation beyond the performance of today's CEBAF polarized source operating at ~ 200 uA average current. Estimates of performance at higher current will be based on hours-long demonstrations at 1 and 4 mA. Particular attention will be paid to beam-related lifetime-limiting mechanisms, and strategies to construct a photogun that operate reliably at bias voltage > 350kV.

  15. Effect of Sulfur on Solid Oxide Fuel Cell (SOFC) Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effect of Sulfur on SOFC Performance Using Diesel Reformate R. Kerr March 6-7, 2014 Workshop on Gas Cleanup for Fuel Cell Applications, ANL, March 6-7, 2014 Sulfur Poisoning Effect ...

  16. EPA Diesel Rule and the Sulfur Effects (DECSE) Project

    SciTech Connect (OSTI)

    2009-05-08

    The VT program collaborated with industry stakeholders and the EPA (in an effort initiated in 1998 called Diesel Emission Control – Sulfur Effects study, otherwise known as DECSE) to quantify the effects of fuel sulfur on emission control technologies.

  17. HIGH AVERAGE POWER OPTICAL FEL AMPLIFIERS.

    SciTech Connect (OSTI)

    BEN-ZVI, ILAN, DAYRAN, D.; LITVINENKO, V.

    2005-08-21

    Historically, the first demonstration of the optical FEL was in an amplifier configuration at Stanford University [l]. There were other notable instances of amplifying a seed laser, such as the LLNL PALADIN amplifier [2] and the BNL ATF High-Gain Harmonic Generation FEL [3]. However, for the most part FELs are operated as oscillators or self amplified spontaneous emission devices. Yet, in wavelength regimes where a conventional laser seed can be used, the FEL can be used as an amplifier. One promising application is for very high average power generation, for instance FEL's with average power of 100 kW or more. The high electron beam power, high brightness and high efficiency that can be achieved with photoinjectors and superconducting Energy Recovery Linacs (ERL) combine well with the high-gain FEL amplifier to produce unprecedented average power FELs. This combination has a number of advantages. In particular, we show that for a given FEL power, an FEL amplifier can introduce lower energy spread in the beam as compared to a traditional oscillator. This properly gives the ERL based FEL amplifier a great wall-plug to optical power efficiency advantage. The optics for an amplifier is simple and compact. In addition to the general features of the high average power FEL amplifier, we will look at a 100 kW class FEL amplifier is being designed to operate on the 0.5 ampere Energy Recovery Linac which is under construction at Brookhaven National Laboratory's Collider-Accelerator Department.

  18. 1984 Virginia coal mine directory: producers of 100,000 tons or more

    SciTech Connect (OSTI)

    Hibbard, W.R. Jr.

    1985-01-01

    The purpose of this directory is to identify major Virginia coal sources for the use of prospective buyers and other interested parties. It is divided into lists: (1) 1984 Virginia coal production, (2) eighty-five largest companies identified by MSHA, (3) alphabetical listing of Virginia coal mines, (4) alphabetical listing of coal mines by county, and (5) coal mines rated by production figures. The rating order for the last list includes factors affecting productivity such as type of mine, number of injuries, seam thickness, total production, and average employment.

  19. Hybrid 320 Ton Off Highway Haul Truck: Quarterly Technical Status Report 1

    SciTech Connect (OSTI)

    Salasoo, Lembit

    2003-02-11

    The mine proving ground to be used for the hybrid off highway vehicle (OHV) demonstration was visited, to obtain haul route profile data and OHV vehicle data. A 6500-ft haul mission with 7% average grade was selected. Enhancements made to a dynamic model of hybrid missions provided capability to analyze hybrid OHV performance. A benefits study defined relationships between fuel and productivity benefits and hybrid system parameters. OHV hybrid system requirements were established, and a survey of candidate energy storage technology characteristics was carried out. Testing of the performance of an existing power battery bank verified its suitability for use in the hybrid OHV demonstration.

  20. Sulfuric acid thermoelectrochemical system and method

    DOE Patents [OSTI]

    Ludwig, Frank A.

    1989-01-01

    A thermoelectrochemical system in which an electrical current is generated between a cathode immersed in a concentrated sulfuric acid solution and an anode immersed in an aqueous buffer solution of sodium bisulfate and sodium sulfate. Reactants consumed at the electrodes during the electrochemical reaction are thermochemically regenerated and recycled to the electrodes to provide continuous operation of the system.

  1. Anodes for Rechargeable Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Xu, Wu; Lu, Dongping; Xiao, Jie; Zhang, Jiguang

    2015-04-10

    In this work, we will review the recent developments on the protection of Li metal anode in Li-S batteries. Various strategies used to minimize the corrosion of Li anode and reducing its impedance increase will be analyzed. Other potential anodes used in sulfur based rechargeable batteries will also be discussed.

  2. Table 10. Average Price of U.S. Steam Coal Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Average Price of U.S. Steam Coal Exports (dollars per short ton) Year to Date Continent and Country of Destination January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 40.85 44.62 71.22 40.85 71.22 -42.6 Canada* 85.43 69.79 74.16 85.43 74.16 15.2 Dominican Republic 213.68 - 461.75 213.68 461.75 -53.7 Guatemala - - 359.27 - 359.27 - Honduras - - 54.43 - 54.43 - Jamaica 38.10 39.48 45.51 38.10 45.51 -16.3 Mexico 28.06 28.52 70.79 28.06

  3. Table 12. Average Price of U.S. Metallurgical Coal Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Average Price of U.S. Metallurgical Coal Exports (dollars per short ton) Year to Date Continent and Country of Destination January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 91.86 102.82 92.36 91.86 92.36 -0.5 Canada* 88.10 104.16 87.30 88.10 87.30 0.9 Guatemala - 66.22 - - - - Honduras 78.02 78.02 - 78.02 - - Mexico 111.56 110.99 108.37 111.56 108.37 2.9 South America Total 64.83 75.44 96.14 64.83 96.14 -32.6 Argentina - - 100.77 -

  4. Process for removing sulfur from sulfur-containing gases: high calcium fly-ash

    DOE Patents [OSTI]

    Rochelle, Gary T.; Chang, John C. S.

    1991-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

  5. Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof

    SciTech Connect (OSTI)

    Oswald, A.A.; Bhatia, R.N.; Mozeleski, E.J.; Glivicky, A.P.; Brueggeman, B.G.; Hooten, J.R.; Smith, C.M.; Hsu, C.S.

    1991-07-09

    This patent describes a hydroformylation-hydrogenation process comprising reacting an olefinic cracked petroleum distillate feed, produced from petroleum residue by high temperature thermal cracking, and containing C{sub 5} to C{sub 35}-1-n-alkyl olefins as the major type of olefin components, and organic sulfur compounds in concentrations exceeding 0.1% sulfur. It comprises at first with carbon monoxide and hydrogen at temperatures between about 50 and 250{degrees} C and pressures in the range of 50 to 6000 psi; in the presence of a Group VIII transition metal carbonyl complex catalyst in effective amounts to produce aldehydes of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule.

  6. New applications for high average power beams

    SciTech Connect (OSTI)

    Neau, E.L.; Turman, B.N.; Patterson, E.L.

    1993-08-01

    The technology base formed by the development of high peak power simulators, laser drivers, FEL`s, and ICF drivers from the early 60`s through the late 80`s is being extended to high average power short-pulse machines with the capabilities of supporting new types of manufacturing processes and performing new roles in environmental cleanup applications. This paper discusses a process for identifying and developing possible commercial applications, specifically those requiring very high average power levels of hundreds of kilowatts to perhaps megawatts. The authors discuss specific technology requirements and give examples of application development efforts. The application development work is directed at areas that can possibly benefit from the high specific energies attainable with short pulse machines.

  7. Tailoring Pore Size of Nitrogen-Doped Hollow Carbon Nanospheres for Confi ning Sulfur in LithiumSulfur Batteries

    SciTech Connect (OSTI)

    Zhou, Weidong; Wang, Chong M.; Zhang, Quiglin; Abruna, Hector D.; He, Yang; Wang, Jiangwei; Mao, Scott X.; Xiao, Xingcheng

    2015-08-19

    Three types of nitrogen-doped hollow carbon spheres with different pore sized porous shells are prepared to investigate the performance of sulfur confinement. The reason that why no sulfur is observed in previous research is determined and it is successfully demonstrated that the sulfur/polysulfide will overflow the porous carbon during the lithiation process.

  8. CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H

    2007-01-31

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

  9. Method to prevent sulfur accumulation in membrane electrode assembly

    DOE Patents [OSTI]

    Steimke, John L; Steeper, Timothy J; Herman, David T

    2014-04-29

    A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

  10. Influence of wind speed averaging on estimates of dimethylsulfide emission fluxes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chapman, E. G.; Shaw, W. J.; Easter, R. C.; Bian, X.; Ghan, S. J.

    2002-12-03

    The effect of various wind-speed-averaging periods on calculated DMS emission fluxes is quantitatively assessed. Here, a global climate model and an emission flux module were run in stand-alone mode for a full year. Twenty-minute instantaneous surface wind speeds and related variables generated by the climate model were archived, and corresponding 1-hour-, 6-hour-, daily-, and monthly-averaged quantities calculated. These various time-averaged, model-derived quantities were used as inputs in the emission flux module, and DMS emissions were calculated using two expressions for the mass transfer velocity commonly used in atmospheric models. Results indicate that the time period selected for averaging wind speedsmore » can affect the magnitude of calculated DMS emission fluxes. A number of individual marine cells within the global grid show DMS emissions fluxes that are 10-60% higher when emissions are calculated using 20-minute instantaneous model time step winds rather than monthly-averaged wind speeds, and at some locations the differences exceed 200%. Many of these cells are located in the southern hemisphere where anthropogenic sulfur emissions are low and changes in oceanic DMS emissions may significantly affect calculated aerosol concentrations and aerosol radiative forcing.« less

  11. Longitudinal study of children exposed to sulfur oxides

    SciTech Connect (OSTI)

    Dodge, R.; Solomon, P.; Moyers, J.; Hayes, C.

    1985-05-01

    This study is a longitudinal comparison of the health of children exposed to markedly different concentrations of sulfur dioxide and moderately different concentrations of particulate sulfate. The four groups of subjects lived in two areas of one smelter town and in two other towns, one of which was also a smelter town. In the area of highest pollution, children were intermittently exposed to high SO/sub 2/ levels (peak three-hour average concentration exceeded 2,500 micrograms/m3) and moderate particulate SO/sub 4/= levels (average concentration was 10.1 micrograms/m3). When the children were grouped by the four gradients of pollution observed, the prevalence of cough (measured by questionnaire) correlated significantly with pollution levels (trend chi-square = 5.6, p = 0.02). No significant differences in the incidence of cough or other symptoms occurred among the groups of subjects over three years, and pulmonary function and lung function growth over the study were roughly equal among all the groups. These results suggest that intermittent elevations in SO/sub 2/ concentration, in the presence of moderate particulate SO/sub 4/= concentration, produced evidence of bronchial irritation in the subjects, but no chronic effect on lung function or lung function growth was detected.

  12. Fuel-rich sulfur capture in a combustion environment

    SciTech Connect (OSTI)

    Lindgren, E.R.; Pershing, D.W.; Kirchgessner, D.A.; Drehmel, D.C.

    1992-01-01

    The paper discusses the use of a refactory-lined, natural gas furnace to study the fuel-rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel-rich sulfur species hydrogen sulfide and carbonyl sulfide were monitored in a nearly continuous fashion using a gas chromatograph equiped with a flame photometric detector and an automatic system that sampled every 30 seconds. Below the fuel-rich zone, 25% excess air was added, and the ultimate fuel-lean capture was simultaneously measured using a continuous sulfur dioxide monitor. Under fuel-rich conditions, high levels of sulfur capture were obtained, and calcium utilization increased with sulfur concentration. The ultimate lean capture was found to be weakly dependent on sulfur concentration and independent of the sulfur capture level obtained in the fuel-rich zone.

  13. A Green's function quantum average atom model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Starrett, Charles Edward

    2015-05-21

    A quantum average atom model is reformulated using Green's functions. This allows integrals along the real energy axis to be deformed into the complex plane. The advantage being that sharp features such as resonances and bound states are broadened by a Lorentzian with a half-width chosen for numerical convenience. An implementation of this method therefore avoids numerically challenging resonance tracking and the search for weakly bound states, without changing the physical content or results of the model. A straightforward implementation results in up to a factor of 5 speed-up relative to an optimized orbital based code.

  14. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Liu, Wei

    1995-01-01

    A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k, [(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or [Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.k wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

  15. SUSTAINABLE DEVELOPMENT IN KAZAKHASTAN: USING OIL AND GAS PRODUCTION BY-PRODUCT SULFUR FOR COST-EFFECTIVE SECONDARY END-USE PRODUCTS.

    SciTech Connect (OSTI)

    KALB, P.D.; VAGIN, S.; BEALL, P.W.; LEVINTOV, B.L.

    2004-09-25

    The Republic of Kazakhstan is continuing to develop its extensive petroleum reserves in the Tengiz region of the northeastern part of the Caspian Sea. Large quantities of by-product sulfur are being produced as a result of the removal of hydrogen sulfide from the oil and gas produced in the region. Lack of local markets and economic considerations limit the traditional outlets for by-product sulfur and the buildup of excess sulfur is a becoming a potential economic and environmental liability. Thus, new applications for re-use of by-product sulfur that will benefit regional economies including construction, paving and waste treatment are being developed. One promising application involves the cleanup and treatment of mercury at a Kazakhstan chemical plant. During 19 years of operation at the Pavlodar Khimprom chlor-alkali production facility, over 900 tons of mercury was lost to the soil surrounding and beneath the buildings. The Institute of Metallurgy and Ore Benefication (Almaty) is leading a team to develop and demonstrate a vacuum-assisted thermal process to extract the mercury from the soil and concentrate it as pure, elemental mercury, which will then be treated using the Sulfur Polymer Stabilization/Solidification (SPSS) process. The use of locally produced sulfur will recycle a low-value industrial by-product to treat hazardous waste and render it safe for return to the environment, thereby helping to solve two problems at once. SPSS chemically stabilizes mercury to mercuric sulfide, which has a low vapor pressure and low solubility, and then physically encapsulates the material in a durable, monolithic solid sulfur polymer matrix. Thus, mercury is placed in a solid form very much like stable cinnabar, the form in which it is found in nature. Previous research and development has shown that the process can successfully encapsulate up to 33 wt% mercury in the solid form, while still meeting very strict regulatory standards for leachable mercury (0.025 mg

  16. Process for production of synthesis gas with reduced sulfur content

    DOE Patents [OSTI]

    Najjar, Mitri S.; Corbeels, Roger J.; Kokturk, Uygur

    1989-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

  17. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  18. Taking out 1 billion tons of CO2: The magic of China's 11th Five-Year Plan?

    SciTech Connect (OSTI)

    Zhou, Nan; Lin, Jiang; Zhou, Nan; Levine, Mark; Fridley, David

    2007-07-01

    China's 11th Five-Year Plan (FYP) sets an ambitious target for energy-efficiency improvement: energy intensity of the country's gross domestic product (GDP) should be reduced by 20% from 2005 to 2010 (NDRC, 2006). This is the first time that a quantitative and binding target has been set for energy efficiency, and signals a major shift in China's strategic thinking about its long-term economic and energy development. The 20% energy intensity target also translates into an annual reduction of over 1.5 billion tons of CO2 by 2010, making the Chinese effort one of most significant carbon mitigation effort in the world today. While it is still too early to tell whether China will achieve this target, this paper attempts to understand the trend in energy intensity in China and to explore a variety of options toward meeting the 20% target using a detailed end-use energy model.

  19. Methods and results for stress analyses on 14-ton, thin-wall depleted UF{sub 6} cylinders

    SciTech Connect (OSTI)

    Kirkpatrick, J.R.; Chung, C.K.; Frazier, J.L.; Kelley, D.K.

    1996-10-01

    Uranium enrichment operations at the three US gaseous diffusion plants produce depleted uranium hexafluoride (DUF{sub 6}) as a residential product. At the present time, the inventory of DUF{sub 6} in this country is more than half a million tons. The inventory of DUF{sub 6} is contained in metal storage cylinders, most of which are located at the gaseous diffusion plants. The principal objective of the project is to ensure the integrity of the cylinders to prevent causing an environmental hazard by releasing the contents of the cylinders into the atmosphere. Another objective is to maintain the cylinders in such a manner that the DUF{sub 6} may eventually be converted to a less hazardous material for final disposition. An important task in the DUF{sub 6} cylinders management project is determining how much corrosion of the walls can be tolerated before the cylinders are in danger of being damaged during routine handling and shipping operations. Another task is determining how to handle cylinders that have already been damaged in a manner that will minimize the chance that a breach will occur or that the size of an existing breach will be significantly increased. A number of finite element stress analysis (FESA) calculations have been done to analyze the stresses for three conditions: (1) while the cylinder is being lifted, (2) when a cylinder is resting on two cylinders under it in the customary two-tier stacking array, and (3) when a cylinder is resting on tis chocks on the ground. Various documents describe some of the results and discuss some of the methods whereby they have been obtained. The objective of the present report is to document as many of the FESA cases done at Oak Ridge for 14-ton thin-wall cylinders as possible, giving results and a description of the calculations in some detail.

  20. Removal of sulfur compounds from combustion product exhaust

    DOE Patents [OSTI]

    Cheng, Dah Y.

    1982-01-01

    A method and device are disclosed for removing sulfur containing contaminents from a combustion product exhaust. The removal process is carried out in two stages wherein the combustion product exhaust is dissolved in water, the water being then heated to drive off the sulfur containing contaminents. The sulfur containing gases are then resolublized in a cold water trap to form a concentrated solution which can then be used as a commercial product.

  1. Project Profile: Baseload CSP Generation Integrated with Sulfur-Based

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Heat Storage | Department of Energy Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage Project Profile: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage General Atomics logo General Atomics, under the Baseload CSP FOA, demonstrated the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power generation. Approach Graphic of a diagram of squares and

  2. Sulfur-impurity Induced Amorphization of Nickel | Argonne Leadership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Facility Sulfur-impurity Induced Amorphization of Nickel Authors: Yuan, Z., Chen, H.P, Wang, W., Nomura, K., Kalia, R.K., Nakano, A., Vashishta, P. Recent experimental and theoretical studies have shown an essential role of sulfur segregation-induced amorphization of crystalline nickel leading to its embrittlement at a critical sulfur concentration of ∼14%, but the atomistic mechanism of the amorphization remains unexplained. Here, molecular dynamics simulations reveal that the

  3. Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries - Joint Center for Energy Storage Research August 24, 2016, Videos Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur Batteries As JCESR scientists work to develop lighter and less expensive chemistries than those used in current lithium-ion batteries, lithium-sulfur shows tremendous promise. However, current lithium-sulfur batteries require an excessive amount of electrolyte to achieve moderate cycle life. This perspective presents an alternate approach of

  4. Sulfide catalysts for reducing SO2 to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun; Yu, Qiquan; Chang, Shih-Ger

    2001-01-01

    A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

  5. Extraction of Sulfur Mustard Metabolites from Urine Samples and...

    Office of Scientific and Technical Information (OSTI)

    Title: Extraction of Sulfur Mustard Metabolites from Urine Samples and Analysis by Liquid Chromatography-High-Resolution Mass Spectrometry (LC-HRMS) Authors: Mayer, B P ; Williams, ...

  6. Microsoft Word - Updated Air Dispersion Modeling Table _sulfur...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DIVINE STRAKE AIR DISPERSION MODELING RESULTS for SULFUR DIOXIDE The attached table is ... within the Nevada Ambient Air Quality Standards at the boundary of the Nevada Test Site. ...

  7. Following the Transient Reactions in Lithium-Sulfur Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Following the Transient Reactions in Lithium-Sulfur Batteries Using an In Situ Nuclear ... cell electrochemical reactions in Li-S batteries using a microbattery design Interphase ...

  8. Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of doped mesoporous carbon and elemental sulfur at a temperature inside a stainless steel vessel, which was used in lithiumsulfur batteries that were tested in ...

  9. Project Profile: Baseload CSP Generation Integrated with Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concentrating Solar Power Project Profile: Baseload CSP Generation Integrated with Sulfur-Based ... General Atomics is seeking a better thermal energy storage approach using ...

  10. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, Nand K.; Ruether, John A.; Smith, Dennis N.

    1988-01-01

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

  11. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, N.K.; Ruether, J.A.; Smith, D.N.

    1987-10-07

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

  12. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  13. Nonflame, source-induced sulfur fluorescence detector for sulfur-containing compounds

    SciTech Connect (OSTI)

    Gage, D.R.; Farwell, S.O.

    1980-12-01

    Results of some preliminary investigations of the fluorescence spectra of S/sub 2/ and the non-flame production of S/sub 2/ from sulfur-containing molecules are reported. Passage of the gas to be analyzed through a catalyst-oven containing a plug of NiO/sub 2//Al/sub 2/O/sub 3/ catalyst containing 10 wt% NiO/sub 2/ and heated to 400/sup 0/C resulted in conversion of H/sub 2/S to S/sub 2/ and elemental sulfur. The S/sub 2/ was detected by measurement of its fluorescence bands at 260 and 310nm, and elemental sulfur condensed on the cool parts of the apparatus. However, determination of sulfur-content of gas mixtures with the apparatus described herein were not as repeatable as desired, and the work is being continued on various facets of the non-flame system with work being directed toward the evaluation of different catalysts, catalyst temperature, design of a smaller detector geometry utilizing a pulsed-light excitation source, a windowless cell, and optical filters instead of monochromators to select the S/sub 2/ excitation and emission wavelengths. (BLM)

  14. ARM: AOS Wet Nephelometer 1 Minute Averages (Dataset) | Data...

    Office of Scientific and Technical Information (OSTI)

    Title: ARM: AOS Wet Nephelometer 1 Minute Averages AOS Wet Nephelometer 1 Minute Averages Authors: Scott Smith ; Cynthia Salwen ; Janek Uin ; Gunnar Senum ; Stephen Springston ; ...

  15. ARM: AOS Dry Nephelometer 1 Minute Averages (Dataset) | Data...

    Office of Scientific and Technical Information (OSTI)

    Title: ARM: AOS Dry Nephelometer 1 Minute Averages AOS Dry Nephelometer 1 Minute Averages Authors: Scott Smith ; Cynthia Salwen ; Janek Uin ; Gunnar Senum ; Stephen Springston ; ...

  16. High Average Brightness Photocathode Development for FEL Applications...

    Office of Scientific and Technical Information (OSTI)

    Conference: High Average Brightness Photocathode Development for FEL Applications Citation Details In-Document Search Title: High Average Brightness Photocathode Development for...

  17. ARM: Temperature Profiles from Raman Lidar at 60-min averaging...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: ARM: Temperature Profiles from Raman Lidar at 60-min averaging interval Temperature Profiles from Raman Lidar at 60-min averaging ...

  18. ARM: Temperature Profiles from Raman Lidar at 10-min averaging...

    Office of Scientific and Technical Information (OSTI)

    Temperature Profiles from Raman Lidar at 10-min averaging interval Title: ARM: Temperature Profiles from Raman Lidar at 10-min averaging interval Temperature Profiles from Raman ...

  19. Annual average efficiency of a solar thermochemical reactor....

    Office of Scientific and Technical Information (OSTI)

    Annual average efficiency of a solar thermochemical reactor. Citation Details In-Document Search Title: Annual average efficiency of a solar thermochemical reactor. Abstract not ...

  20. Sodium sulfur container with chromium/chromium oxide coating

    DOE Patents [OSTI]

    Ludwig, Frank A.; Higley, Lin R.

    1981-01-01

    A coating of chromium/chromium oxide is disclosed for coating the surfaces of electrically conducting components of a sodium sulfur battery. This chromium/chromium oxide coating is placed on the surfaces of the electrically conducting components of the battery which are in contact with molten polysulfide and sulfur reactants during battery operation.

  1. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda; Janiak, Jerzy S.; Turak, Ali A.; Ignasiak, Boleslaw L.

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  2. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert; Pickard, Paul S.; Parma, Jr., Edward J.; Vernon, Milton E.; Gelbard, Fred; Lenard, Roger X.

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  3. Metal-sulfur type cell having improved positive electrode

    DOE Patents [OSTI]

    Dejonghe, Lutgard C.; Visco, Steven J.; Mailhe, Catherine C.; Armand, Michel B.

    1989-01-01

    An novel metal-sulfur type cell operable at a temperature of 200.degree. C. or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S).sub.y).sub.n wherein y=1 to 6; n=2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprisises one of more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associtated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

  4. Metal-sulfur type cell having improved positive electrode

    DOE Patents [OSTI]

    DeJonghe, L.C.; Visco, S.J.; Mailhe, C.C.; Armand, M.B.

    1988-03-31

    A novel metal-sulfur type cell operable at a temperature of 200/degree/C or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S)/sub y/)n wherein y = 1 to 6; n = 2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprises one or more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon. 4 figs.

  5. Sulfur Speciation of Different Kerogens using XANES Spectroscopy

    SciTech Connect (OSTI)

    Wiltfong,R.; Mitra-Kirtley, S.; Mullins, O.; Andrews, B.; Fujisawa, G.; Larsen, J.

    2005-01-01

    X-ray absorption near-edge structure (XANES) methodology has been employed to quantify the different sulfur structures present in three Type I and three Type II kerogens. Kerogens from the Green River (3), Bakken (1), Woodford (1), and Indiana limestone (1) formations were studied. Both aliphatic (sulfide) and aromatic (thiophene) forms of sulfur exist in all these kerogen samples. Except for Woodford, all of the kerogens contain oxidized functional groups. Sulfur in Types I and II kerogens mimics the carbon chemistry in that the sulfur structures are more aromatic in Type II than in Type I. It was impossible to differentiate elemental sulfur from pyrite in these samples by using K-edge XANES.

  6. Removal of sulfur contaminants in methanol for fuel cell applications

    SciTech Connect (OSTI)

    Lee, S.H.D.; Kumar, R.; Sederquist, R.

    1996-12-31

    Fuel cell power plants are being developed for transit bus and passenger car applications that use methanol as the on-board fuel. Commodity methanol by itself contains very little sulfur; however, it may occasionally be contaminated with up to about 1% diesel fuel or gasoline in current liquid-fuel distribution systems, leading to the presence of sulfur in the methanol fuel. This sulfur must be removed because of its deleterious effect on the reforming catalysts. International Fuel Cells has set the allowable sulfur limit in the methanol fuel at less than 1 ppm. The equilibrium adsorption isotherm and breakthrough data were used to assess the feasibility of developing a granular activated carbon adsorber for the removal of sulfur from transportation fuel cell systems.

  7. Multi-model mean nitrogen and sulfur deposition from the Atmospheric...

    Office of Scientific and Technical Information (OSTI)

    Multi-model mean nitrogen and sulfur deposition from the Atmospheric Chemistry and Climate ... Title: Multi-model mean nitrogen and sulfur deposition from the Atmospheric Chemistry and ...

  8. Chemical reactions of UF{sub 6} with water on ingress to damaged model 48X 10 ton cylinder

    SciTech Connect (OSTI)

    Rothman, A.B.

    1996-02-01

    Chemistry studies of the effects of water flooding in Model 48X 10-ton UF{sub 6} storage cylinders, as a result of impact fractures, were conducted to support the Safety Analysis Report for Packaging (SARP) review of the Paducah Tiger Overpack for transportation of those cylinders. The objectives of the study were to determine the maximum amount of water that could be admitted to the interior of such a damaged cylinder, the resulting geometries and chemical compositions from reactions of water with the UF{sub 6} contents of the cylinder, and the end-state water moderated and reflected configurations for input to nuclear criticality safety analyses. The case identified for analysis was the flooding of the inside of a cylinder, submerged horizontally in 3 ft of water. The flooding was driven by an initial pressure drop of 13 psig, through an assumed fracture (1/32 in. wide {times} 1/2 in. deep {times} 18 in. long) in the barrel of the cylinder. During the initial addition of water, transient back pressures occur from the effects of the heats of reaction and solution at the water/UF{sub 6} interface, with some chugging as more water is added to alternately coot the reaction surface and then heat it again as the added water reacts with more UF{sub 6}.

  9. Membranes for the Sulfur-Iodine Integrated Laboratory Scale Demonstration

    SciTech Connect (OSTI)

    Frederick F. Stewart

    2007-08-01

    INL has developed polymeric membrane-based chemical separations to enable the thermochemical production of hydrogen. Major activities included studies of sulfuric acid concentration membranes, hydriodic acid concentration membranes, SO2/O2 separation membranes, potential applications of a catalyst reactor system for the decomposition of HI, and evaluation of the chemical separation needs for alternate thermochemical cycles. Membranes for the concentration of sulfuric acid were studied using pervaporation. The goal of this task was to offer the sulfur-iodine (S-I) and the hybrid sulfur (HyS) cycles a method to concentrate the sulfuric acid containing effluent from the decomposer without boiling. In this work, sulfuric acid decomposer effluent needs to be concentrated from ~50 % acid to 80 %. This task continued FY 2006 efforts to characterize water selective membranes for use in sulfuric acid concentration. In FY 2007, experiments were conducted to provide specific information, including transmembrane fluxes, separation factors, and membrane durability, necessary for proper decision making on the potential inclusion of this process into the S-I or HyS Integrated Laboratory Scale demonstration.

  10. Review of corrosion in 10- and 14-ton mild steel depleted UF{sub 6} storage cylinders

    SciTech Connect (OSTI)

    Lykins, M.L.

    1995-08-01

    A literature review was conducted to determine the type, extent and severity of corrosion found in the 10- and 14-ton mild steel depleted UF{sub 6} storage cylinders. Also discussed in this review is corrosion found in the valves and plugs used in the cylinders. Corrosion of the cylinders is a gradual process which occurs slowly over time. Understanding corrosion of the cylinders is an important concern for long term storage of the UF{sub 6} in the cylinder yards, as well as the final disposition of the depleted UF{sub 6} tails inventory in the future. The following conclusions are made from the literature review: (1) The general external corrosion rate of the cylinders is about 1 to 2 mils per year (1 mil = 0.001{double_prime}). The highest general external corrosion rate was over 5 mpy on the 48G type cylinders. (2) General internal corrosion from the depleted UF{sub 6} is negligible under normal storage conditions. Crevice corrosion can occur at the cylinder/saddle interface from the retention of water in this area. Crevice corrosion can occur at the cylinder/skirt interface on the older skirted cylinders due to the lack of water drainage in this area. Crevice corrosion can occur on cylinders that have been in ground contact. Crevice corrosion and galvanic corrosion can occur where the stainless steel I.D. nameplates are attached to the cylinder. The packing nuts on the bronze one-inch valves used in the cylinders are susceptible to stress corrosion cracking (SCC). Mechanical damage from routine handling can lead to a breach in a cylinder with subsequent accelerated corrosion of the mild steel due to attack from HF and other UF{sub 6} hydrolysis by-products.

  11. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, R.; Steinberg, M.

    This invention relates to high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280/sup 0/C and containing as little as 36 mo1% ethylene and about 41 to 51 mo1% sulfur dioxide, and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10 to 50/sup 0/C, and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  12. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, Richard; Steinberg, Meyer

    1981-01-01

    This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  13. Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    via Surface Modification of SiO2 with TiO2 and ZrO2 | Department of Energy Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts via Surface Modification of SiO2 with TiO2 and ZrO2 Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts via Surface Modification of SiO2 with TiO2 and ZrO2 This study demonstrates the feasibility of developing highly stable, sulfur-tolerant oxidation catalysts that use less Pt via surface modification of silica supports

  14. Fact #849: December 1, 2014 Midsize Hybrid Cars Averaged 51%...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel Economy than Midsize Non-Hybrid Cars in 2014 Fact 849: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better ...

  15. Fact #835: August 25, 2014 Average Annual Gasoline Pump Price...

    Broader source: Energy.gov (indexed) [DOE]

    35: Average Annual Gasoline Pump Price, 1929-2013 fotw835web.xlsx (21.31 KB) More Documents & Publications Fact 915: March 7, 2016 Average Historical Annual Gasoline Pump Price, ...

  16. Fact #889: September 7, 2015 Average Diesel Price Lower than...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years Fact 889: September 7, 2015 Average Diesel Price Lower than Gasoline for the First ...

  17. Fact #870: April 27, 2015 Corporate Average Fuel Economy Progress...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0: April 27, 2015 Corporate Average Fuel Economy Progress, 1978-2014 - Dataset Fact 870: April 27, 2015 Corporate Average Fuel Economy Progress, 1978-2014 - Dataset Excel file and ...

  18. Fact #693: September 19, 2011 Average Vehicle Footprint for Cars...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    It is calculated as the product of the wheelbase and the average track width of the vehicle. The upcoming Corporate Average Fuel Economy (CAFE) Standards have fuel economy targets ...

  19. Effects of sulfur loading on the corrosion behaviors of metal lithium anode in lithium–sulfur batteries

    SciTech Connect (OSTI)

    Han, Yamiao; Duan, Xiaobo; Li, Yanbing; Huang, Liwu; Zhu, Ding; Chen, Yungui

    2015-08-15

    Highlights: • The effects of sulfur loading on the corrosion behaviors were investigated systematically. • The corrosion became severer with increasing sulfur loading or cycle times. • The corrosion films are porous and loose and cannot prevent further reaction between lithium and polysulfides. - Abstract: The corrosion behaviors in rechargeable lithium–sulfur batteries come from the reactions between polysulfides and metal lithium anode, and they are significantly influenced by the sulfur loading. While there are limited papers reported on the effects of sulfur loading on the corrosion behaviors. In this paper, the effects have been investigated systematically. The corrosion films consisted of insulating lithium ion conductors are loose and porous, so that the corrosive reactions cannot be hindered. The thickness of the corrosion layers, consequently, increased along with increasing sulfur loading or cycle times. For instance, the thickness of corrosion layers after 50 cycles was 98 μm in the cell with 5 mg sulfur while it reached up to 518 μm when the loading increased to 15 mg. The continuous deposition of corrosion products gave rise to low active materials utilization and poor cycling performance.

  20. Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2004-06-01

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  1. Sulfur vacancies in photorefractive Sn{sub 2}P{sub 2}S{sub 6} crystals

    SciTech Connect (OSTI)

    Golden, E. M.; Giles, N. C.; Basun, S. A.; Grabar, A. A.; Stoika, I. M.; Evans, D. R.; Halliburton, L. E.

    2014-12-28

    A photoinduced electron paramagnetic resonance (EPR) spectrum in single crystals of Sn{sub 2}P{sub 2}S{sub 6} (SPS) is assigned to an electron trapped at a sulfur vacancy. These vacancies are unintentionally present in undoped SPS crystals and are expected to play an important role in the photorefractive behavior of the material. Nonparamagnetic sulfur vacancies are formed during the initial growth of the crystal. Subsequent illumination below 100 K with 442 nm laser light easily converts these vacancies to EPR-active defects. The resulting S = 1/2 spectrum shows well-resolved and nearly isotropic hyperfine interactions with two P ions and two Sn ions. Partially resolved interactions with four additional neighboring Sn ions are also observed. Principal values of the g matrix are 1.9700, 1.8946, and 1.9006, with the corresponding principal axes along the a, b, and c directions in the crystal. The isotropic parts of the two primary {sup 31}P hyperfine interactions are 19.5 and 32.6 MHz and the isotropic parts of the two primary Sn hyperfine interactions are 860 and 1320 MHz (the latter values are each an average for {sup 117}Sn and {sup 119}Sn). These hyperfine results suggest that singly ionized sulfur vacancies have a diffuse wave function in SPS crystals, and thus are shallow donors. Before illumination, sulfur vacancies are in the doubly ionized charge state because of compensation by unidentified acceptors. They then trap an electron during illumination. The EPR spectrum from the sulfur vacancy is destroyed when a crystal is heated above 120 K in the dark and reappears when the crystal is illuminated again at low temperature.

  2. Lithium / Sulfur Cells with Long Cycle Life and High Specific...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Sulfur Cells with Long Cycle Life and High Specific Energy Lawrence Berkeley ... Song, M-K., Zhang, Y., Cairns, E.J., "A long-life, high-rate lithiumsulfur cell: a ...

  3. Sulfur Resistant Electrodes for Zirconia Oxygen Sensors - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxide (Tb-YSZ) electrode have tested in a high-sulfur-coal fired power plant side by side against Zirconia-based O2 sensors with a standard platinum electrode. ...

  4. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

    2013-08-13

    A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  5. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    6. Receipts, Average Cost, and Quality of Fossil Fuels: Electric Utilities, 2004 - 2014 (continued) Petroleum Coke Natural Gas All Fossil Fuels Receipts Average Cost Receipts Average Cost Average Cost Period (Billion Btu) (Thousand Tons) (Dollars per MMbtu) (Dollars per Ton) Average Sulfur Percent by Weight Percentage of Consumption (Billion Btu) (Thousand Mcf) (Dollars per MMBtu) (Dollars per Mcf) Percentage of Consumption (Dollars per MMBtu) Annual Totals 2004 107,985 3,817 0.89 25.15 5.10

  6. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    8. Receipts, Average Cost, and Quality of Fossil Fuels: Independent Power Producers, 2004 - 2014 (continued) Petroleum Coke Natural Gas All Fossil Fuels Receipts Average Cost Receipts Average Cost Average Cost Period (Billion Btu) (Thousand Tons) (Dollars per MMbtu) (Dollars per Ton) Average Sulfur Percent by Weight Percentage of Consumption (Billion Btu) (Thousand Mcf) (Dollars per MMBtu) (Dollars per Mcf) Percentage of Consumption (Dollars per MMBtu) Annual Totals 2004 73,745 2,609 0.72 20.30

  7. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Receipts, Average Cost, and Quality of Fossil Fuels: Commerical Sector, 2004 - 2014 (continued) Petroleum Coke Natural Gas All Fossil Fuels Receipts Average Cost Receipts Average Cost Average Cost Period (Billion Btu) (Thousand Tons) (Dollars per MMbtu) (Dollars per Ton) Average Sulfur Percent by Weight Percentage of Consumption (Billion Btu) (Thousand Mcf) (Dollars per MMBtu) (Dollars per Mcf) Percentage of Consumption (Dollars per MMBtu) Annual Totals 2004 0 0 -- -- -- 0.0 16,176 15,804

  8. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Receipts, Average Cost, and Quality of Fossil Fuels: Industrial Sector, 2004 - 2014 (continued) Petroleum Coke Natural Gas All Fossil Fuels Receipts Average Cost Receipts Average Cost Average Cost Period (Billion Btu) (Thousand Tons) (Dollars per MMbtu) (Dollars per Ton) Average Sulfur Percent by Weight Percentage of Consumption (Billion Btu) (Thousand Mcf) (Dollars per MMBtu) (Dollars per Mcf) Percentage of Consumption (Dollars per MMBtu) Annual Totals 2004 14,876 540 0.98 27.01 5.59 40.4

  9. Gasoline from natural gas by sulfur processing

    SciTech Connect (OSTI)

    Erekson, E.J.; Miao, F.Q.

    1995-12-31

    The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process, called the HSM (Hydrogen Sulfide-Methane) Process, consists of two steps that each utilize a catalyst and sulfur-containing intermediates: (1) converting natural gas to CS{sub 2} and (2) converting CS{sub 2} to gasoline range liquids. Catalysts have been found that convert methane to carbon disulfide in yields up to 98%. This exceeds the target of 40% yields for the first step. The best rate for CS{sub 2} formation was 132 g CS{sub 2}/kg-cat-h. The best rate for hydrogen production is 220 L H{sub 2} /kg-cat-h. A preliminary economic study shows that in a refinery application hydrogen made by the HSM technology would cost $0.25-R1.00/1000 SCF. Experimental data will be generated to facilitate evaluation of the overall commercial viability of the process.

  10. Evaluation of Sulfur Spinel Compounds for Multivalent Battery Cathode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications - Joint Center for Energy Storage Research August 17, 2016, Research Highlights Evaluation of Sulfur Spinel Compounds for Multivalent Battery Cathode Applications A group of 3d transition-metal sulfur-spinel compounds were systematically assessed for MV cathode applications, based on their electrochemical and thermodynamic properties . Cr2S4, Ti2S4 and Mn2S4 spinel compounds exhibit superior Mg2+ mobility, and hence, emerge as the top three candidates. Scientific Achievement

  11. METHOD TO PREVENT SULFUR ACCUMULATION INSIDE MEMBRANE ELECTRODE ASSEMBLY

    SciTech Connect (OSTI)

    Steimke, J.; Steeper, T.; Herman, D.; Colon-Mercado, H.; Elvington, M.

    2009-06-22

    HyS is conceptually the simplest of the thermochemical cycles and involves only sulfur chemistry. In the HyS Cycle hydrogen gas (H{sub 2}) is produced at the cathode of the electrochemical cell (or electrolyzer). Sulfur dioxide (SO{sub 2}) is oxidized at the anode to form sulfuric acid (H{sub 2}SO{sub 4}) and protons (H{sup +}) as illustrated below. A separate high temperature reaction decomposes the sulfuric acid to water and sulfur dioxide which are recycled to the electrolyzers, and oxygen which is separated out as a secondary product. The electrolyzer includes a membrane that will allow hydrogen ions to pass through but block the flow of hydrogen gas. The membrane is also intended to prevent other chemical species from migrating between electrodes and undergoing undesired reactions that could poison the cathode or reduce overall process efficiency. In conventional water electrolysis, water is oxidized at the anode to produce protons and oxygen. The standard cell potential for conventional water electrolysis is 1.23 volts at 25 C. However, commercial electrolyzers typically require higher voltages ranging from 1.8 V to 2.6 V [Kirk-Othmer, 1991]. The oxidation of sulfur dioxide instead of water in the HyS electrolyzer occurs at a much lower potential. For example, the standard cell potential for sulfur dioxide oxidation at 25 C in 50 wt % sulfuric acid is 0.29 V [Westinghouse, 1980]. Since power consumption by the electrolyzers is equal to voltage times current, and current is proportional to hydrogen production, a large reduction in voltage results in a large reduction in electrical power cost per unit of hydrogen generated.

  12. Ultra Low Sulfur Home Heating Oil Demonstration Project

    SciTech Connect (OSTI)

    Batey, John E.; McDonald, Roger

    2015-09-30

    This Ultra Low Sulfur (ULS) Home Heating Oil Demonstration Project was funded by the New York State Energy Research and Development Authority (NYSERDA) and has successfully quantified the environmental and economic benefits of switching to ULS (15 PPM sulfur) heating oil. It advances a prior field study of Low Sulfur (500 ppm sulfur) heating oil funded by NYSERDA and laboratory research conducted by Brookhaven National Laboratory (BNL) and Canadian researchers. The sulfur oxide and particulate matter (PM) emissions are greatly reduced as are boiler cleaning costs through extending cleaning intervals. Both the sulfur oxide and PM emission rates are directly related to the fuel oil sulfur content. The sulfur oxide and PM emission rates approach near-zero levels by switching heating equipment to ULS fuel oil, and these emissions become comparable to heating equipment fired by natural gas. This demonstration project included an in-depth review and analysis of service records for both the ULS and control groups to determine any difference in the service needs for the two groups. The detailed service records for both groups were collected and analyzed and the results were entered into two spreadsheets that enabled a quantitative side-by-side comparison of equipment service for the entire duration of the ULS test project. The service frequency for the ULS and control group were very similar and did indicate increased service frequency for the ULS group. In fact, the service frequency with the ULS group was slightly less (7.5 percent) than the control group. The only exception was that three burner fuel pump required replacement for the ULS group and none were required for the control group.

  13. Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasability of a Billion-Ton Annual Supply

    SciTech Connect (OSTI)

    Perlack, R.D.

    2005-12-15

    land resources of the United States are capable of producing a sustainable supply of biomass sufficient to displace 30 percent or more of the country's present petroleum consumption--the goal set by the Advisory Committee in their vision for biomass technologies. Accomplishing this goal would require approximately 1 billion dry tons of biomass feedstock per year.

  14. In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    into MDCK Cells In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine into MDCK Cells Sulfur is essential for life. It plays important roles in the amino acids methionine and cysteine, and has a structural function in disulfide bonds. As a component of iron-sulfur clusters it takes part in electron and sulfur transfer reactions.1 Glutathione, a sulfur-containing tripeptide, is an important part of biological antioxidant systems.2 Another example for the biological

  15. A Summary of the Results of the 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Vol. 1

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Summary of the Results of the 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Vol. 1 July 21, 2016 Dr. Mark Elless U.S. Department of Energy Dr. Matthew Langholtz Mr. Laurence Eaton Mr. Aaron Myers Oak Ridge National Laboratory Dr. Bryce Stokes Allegheny Science and Technology - Contractor to the U.S. Department of Energy 2 | Bioenergy Technologies Office Agenda I. Introduction: Bioenergy Technologies Office Mission and Organization - Mark Elless, Bioenergy

  16. Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply, April 2005

    SciTech Connect (OSTI)

    2005-04-01

    The purpose of this report is to determine whether the land resources of the United States are capable of producing a sustainable supply of biomass sufficient to displace 30 percent or more of the country’s present petroleum consumption – the goal set by the Biomass R&D Technical Advisory Committee in their vision for biomass technologies. Accomplishing this goal would require approximately 1 billion dry tons of biomass feedstock per year.

  17. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key partsa positive and negative electrode and an electrolytethat exchange ions to store and release electricity. Using different materials for these components changes a batterys chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  18. "Variable","Average Absolute Percent Differences","Percent of...

    U.S. Energy Information Administration (EIA) Indexed Site

    Annual Energy Outlook Retrospective Review, 2014" "Variable","Average Absolute Percent Differences","Percent of Projections Over- Estimated" "Gross Domestic Product" "Real Gross ...

  19. High Average Brightness Photocathode Development for FEL Applications...

    Office of Scientific and Technical Information (OSTI)

    Title: High Average Brightness Photocathode Development for FEL Applications Authors: Rao T. ; Ben-Zvi I. ; Skarita, J. ; Wang, E. Publication Date: 2013-08-26 OSTI Identifier: ...

  20. Turning Bayesian model averaging into Bayesian model combination...

    Office of Scientific and Technical Information (OSTI)

    Title: Turning Bayesian model averaging into Bayesian model combination Authors: Carroll, James 1 ; Monteith, Kristine 2 ; Seppi, Kevin 2 ; Martinez, Tony 2 + Show Author ...

  1. Table 14a. Average Electricity Prices, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Average Electricity Prices, Projected vs. Actual" "Projected Price in Constant Dollars" " (constant dollars, cents per kilowatt-hour in ""dollar year"" specific to each AEO)" ...

  2. Fact #803: November 11, 2013 Average Number of Transmission Gears...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Average Number of Gears for New Light Vehicles, Model Years 1979-2012 Model Year Average Number of Gears 1979 3.3 1980 3.5 1981 3.5 1982 3.6 1983 3.7 1984 3.7 1985 3.8 1986 3.8 ...

  3. Insight into Sulfur Reactions in Li–S Batteries

    SciTech Connect (OSTI)

    Xu, Rui; Belharouak, Ilias; Zhang, Xiaofeng; chamoun, rita; Yu, Cun; Ren, Yang; Nie, Anmin; Reza, Shahbazian-Yassar; Lu, Jun; Li, James C.M.; Amine, Khalil

    2014-12-09

    Understanding and controlling the sulfur reduction species (Li2Sx, 1 ≤ x ≤ 8) under realistic battery conditions are essential for the development of advanced practical Li–S cells that can reach their full theoretical capacity. However, it has been a great challenge to probe the sulfur reduction intermediates and products because of the lack of methods. This work employed various ex situ and in situ methods to study the mechanism of the Li–S redox reactions and the properties of Li2Sx and Li2S. Synchrotron high-energy X-ray diffraction analysis used to characterize dry powder deposits from lithium polysulfide solution suggests that the new crystallite phase may be lithium polysulfides. The formation of Li2S crystallites with a polyhedral structure was observed in cells with both the conventional (LiTFSI) electrolyte and polysulfide-based electrolyte. In addition, an in situ transmission electron microscopy experiment observed that the lithium diffusion to sulfur during discharge preferentially occurred at the sulfur surface and formed a solid Li2S crust. This may be the reason for the capacity fade in Li–S cells (as also suggested by EIS experiment in Supporting Information). The results can be a guide for future studies and control of the sulfur species and meanwhile a baseline for approaching the theoretical capacity of the Li–S battery.

  4. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H.; Stegen, Gary E.

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  5. ADDITIVE TESTING FOR IMPROVED SULFUR RETENTION: PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Amoroso, J.; Fox, K.

    2011-09-07

    The Savannah River National Laboratory is collaborating with Alfred University to evaluate the potential for additives in borosilicate glass to improve sulfur retention. This preliminary report provides further background on the incorporation of sulfur in glass and outlines the experiments that are being performed by the collaborators. A simulated waste glass composition has been selected for the experimental studies. The first phase of experimental work will evaluate the impacts of BaO, PbO, and V{sub 2}O{sub 5} at concentrations of 1.0, 2.0, and 5.0 wt % on sulfate retention in simulated high level waste borosilicate glass. The second phase of experimental work will evaluate the effects of time at the melt temperature on sulfur retention. The resulting samples will be characterized to determine the amount of sulfur remaining as well as to identify the formation of any crystalline phases. The results will be used to guide the future selection of frits and glass forming chemicals in vitrifying Department of Energy wastes containing high sulfur concentrations.

  6. Process and system for removing sulfur from sulfur-containing gaseous streams

    DOE Patents [OSTI]

    Basu, Arunabha; Meyer, Howard S.; Lynn, Scott; Leppin, Dennis; Wangerow, James R.

    2012-08-14

    A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

  7. Analytical method for the evaluation of sulfur functionalities in American coals. Final report

    SciTech Connect (OSTI)

    Attar, A.

    1983-05-01

    This investigation consisted of the following 6 tasks: (1) improve the instrumentation for the sulfur functional groups analysis and make it more reliable. (2) create a set of reference standards of sulfur-containing compounds. (3) examine the sulfur groups distribution in untreated and desulfurized coals. (4) examine the sulfur functionalities in raw and processed coals, i.e., liquefied coals. (5) determine the distribution of sulfur functionalities in modified coals. (6) prepare computer programs for calculations related to the distribution of sulfur functional groups in coal. Each task is discussed and results are presented. Appendix A contains the computer program used to interpret the data. 31 references, 56 figures, 17 tables.

  8. Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results

    SciTech Connect (OSTI)

    Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

    2004-01-25

    A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

  9. HYBRID SULFUR ELECTROLYZER DEVELOPMENT FY09 SECOND QUARTER REPORT

    SciTech Connect (OSTI)

    Herman, D; David Hobbs, D; Hector Colon-Mercado, H; Timothy Steeper, T; John Steimke, J; Mark Elvington, M

    2009-04-15

    The primary objective of the DOE-NE Nuclear Hydrogen Initiative (NHI) is to develop the nuclear hydrogen production technologies necessary to produce hydrogen at a cost competitive with other alternative transportation fuels. The focus of the NHI is on thermochemical cycles and high temperature electrolysis that can be powered by heat from high temperature gas reactors. The Savannah River National Laboratory (SRNL) has been tasked with the primary responsibility to perform research and development in order to characterize, evaluate and develop the Hybrid Sulfur (HyS) thermochemical process. This report documents work during the first quarter of Fiscal Year 2009, for the period between January 1, 2009 and March 31, 2009. The HyS Process is a two-step hybrid thermochemical cycle that is part of the 'Sulfur Family' of cycles. As a sulfur cycle, it uses high temperature thermal decomposition of sulfuric acid to produce oxygen and to regenerate the sulfur dioxide reactant. The second step of the process uses a sulfur dioxide depolarized electrolyzer (SDE) to split water and produce hydrogen by electrochemically reacting sulfur dioxide with H{sub 2}O. The SDE produces sulfuric acid, which is then sent to the acid decomposer to complete the cycle. The DOE NHI program is developing the acid decomposer at Sandia National Laboratory for application to both the HyS Process and the Sulfur Iodine Cycle. The SDE is being developed at SRNL. During FY05 and FY06, SRNL designed and conducted proof-of-concept testing for a SDE using a low temperature, PEM fuel cell-type design concept. The advantages of this design concept include high electrochemical efficiency, small footprint and potential for low capital cost, characteristics that are crucial for successful implementation on a commercial scale. During FY07, SRNL extended the range of testing of the SDE to higher temperature and pressure, conducted a 100-hour longevity test with a 60-cm{sup 2} single cell electrolyzer, and

  10. Graphene-wrapped sulfur/metal organic framework-derived microporous carbon composite for lithium sulfur batteries

    SciTech Connect (OSTI)

    Chen, Renjie E-mail: chenrj@bit.edu.cn; Zhao, Teng; Tian, Tian; Fairen-Jimenez, David; Cao, Shuai; Coxon, Paul R.; Xi, Kai E-mail: chenrj@bit.edu.cn; Vasant Kumar, R.; Cheetham, Anthony K.

    2014-12-01

    A three-dimensional hierarchical sandwich-type graphene sheet-sulfur/carbon (GS-S/C{sub ZIF8-D}) composite for use in a cathode for a lithium sulfur (Li-S) battery has been prepared by an ultrasonic method. The microporous carbon host was prepared by a one-step pyrolysis of Zeolitic Imidazolate Framework-8 (ZIF-8), a typical zinc-containing metal organic framework (MOF), which offers a tunable porous structure into which electro-active sulfur can be diffused. The thin graphene sheet, wrapped around the sulfur/zeolitic imidazolate framework-8 derived carbon (S/C{sub ZIF8-D}) composite, has excellent electrical conductivity and mechanical flexibility, thus facilitating rapid electron transport and accommodating the changes in volume of the sulfur electrode. Compared with the S/C{sub ZIF8-D} sample, Li-S batteries with the GS-S/C{sub ZIF8-D} composite cathode showed enhanced capacity, improved electrochemical stability, and relatively high columbic efficiency by taking advantage of the synergistic effects of the microporous carbon from ZIF-8 and a highly interconnected graphene network. Our results demonstrate that a porous MOF-derived scaffold with a wrapped graphene conductive network structure is a potentially efficient design for a battery electrode that can meet the challenge arising from low conductivity and volume change.

  11. Assessment of Reusing 14-ton, Thin-Wall, Depleted UF{sub 6} Cylinders as LLW Disposal Containers

    SciTech Connect (OSTI)

    O'Connor, D.G.

    2000-11-30

    - 14TTW cylinders, which have a nominal diameter of 48 inches and nominally contain 14 tons (12.7 MT) of DUF{sub 6}, were originally designed and fabricated for temporary storage of DUF{sub 6}. They were fabricated from pressure-vessel-grade steels according to the provisions of the ASME Boiler and Pressure Vessel Code (Ref. 4). Cylinders are stored in open yards at the three sites and, due to historical storage techniques, were subject to corrosion. Roughly 10,000 of the 14TTW cylinders are considered substandard (Ref. 5) due to corrosion and other structural anomalies caused by mishandling. This means that approximately 40,000 14TTW cylinders could be made available as containers for LLW disposal In order to demonstrate the use of 14TTW cylinders as LLW disposal containers, several qualifying tasks need to be performed. Two demonstrations are being considered using 14TTW cylinders--one demonstration using contaminated soil and one demonstration using U{sub 3}O{sub 8}. The objective of this report are to determine how much information is known that could be used to support the demonstrations, and how much additional work will need to be done in order to conduct the demonstrations. Information associated with the following four qualifying tasks are evaluated in this report. (1) Perform a review of structural assessments that have been conducted for 14TTW. (2) Develop a procedure for filling 14TTW cylinders with LLW that have been previously washed. (3) Evaluate the transportation requirements for shipping 14TTW cylinders containing LLW. (4) Evaluate the WAC that will be imposed by the NTS. Two assumptions are made to facilitate this evaluation of using DUF{sub 6} cylinders as LLW disposal containers. (1) Only 14TTW cylinders will be considered for use as LLW containers, and (2) The NTS will be the LLW disposal site.

  12. U.S. Refiner Sales to End Users (Average) Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales Type: Sales to End Users, Average Through Retail Outlets Sales for Resale, Average DTW Rack Bulk Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Formulation/ Grade Sales Type Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Conventional, Average 1.346 1.209 1.450 1.617 1.790 1.894 1994-2016 Conventional Regular 1.305 1.167 1.412 1.576 1.749 1.854 1994-2016 Conventional Midgrade 1.524 1.376 1.601 1.781

  13. Fact #870: April 27, 2015 Corporate Average Fuel Economy Progress,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1978-2014 - Dataset | Department of Energy 0: April 27, 2015 Corporate Average Fuel Economy Progress, 1978-2014 - Dataset Fact #870: April 27, 2015 Corporate Average Fuel Economy Progress, 1978-2014 - Dataset Excel file and dataset for Corporate Average Fuel Economy Progress, 1978-2014 fotw#870_web.xlsx (17.92 KB) More Documents & Publications Reactor Pressure Vessel Task of Light Water Reactor Sustainability Program: Milestone Report on Materials and Machining of Specimens for the ATR-2

  14. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L.; Gorski, Anthony J.; Daniels, Edward J.

    1993-01-01

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  15. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  16. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage - FY13 Q1 | Department of Energy Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 This document summarizes the progress of this General Atomics project, funded by SunShot, for the first quarter of fiscal year 2013. progress_report_baseload_generalatomics_fy13_q1.pdf (196.13 KB) More Documents & Publications Baseload CSP Generation Integrated with

  17. Method for removing sulfur oxides from a hot gas

    SciTech Connect (OSTI)

    Morris, W.P.; Hurst, T.B.

    1984-06-05

    An improved method for removing sulfur oxides from a hot gas by introducing the gas into a first compartment of a spray drying reactor chamber for settleable particulate removal, by then directing the gas to a second compartment of the reactor chamber wherein the gas is contacted with an atomized alkali slurry for sulfur oxide removal by formation of a dry mixture of sulfite and sulfate compounds, by removing a portion of the dry mixture from the gas in the second compartment and by passing the gas from the second compartment to a dry particle collection zone for removal of substantially all of the remaining gas entrained dry mixture.

  18. A nuclear criticality safety assessment of the loss of moderation control in 2 1/2 and 10-ton cylinders containing enriched UF{sub 6}

    SciTech Connect (OSTI)

    Newvahner, R.L.; Pryor, W.A.

    1991-12-31

    Moderation control for maintaining nuclear criticality safety in 2 {1/2}-ton, 10-ton, and 14-ton cylinders containing enriched uranium hexafluoride (UF{sub 6}) has been used safely within the nuclear industry for over thirty years, and is dependent on cylinder integrity and containment. This assessment evaluates the loss of moderation control by the breaching of containment and entry of water into the cylinders. The first objective of this study was to estimate the required amounts of water entering these large UF{sub 6} cylinders to react with, and to moderate the uranium compounds sufficiently to cause criticality. Hypothetical accident situations were modeled as a uranyl fluoride (UO{sub 2}F{sub 2}) slab above a UF{sub 6} hemicylinder, and a UO{sub 2}F{sub 2} sphere centered within a UF{sub 6} hemicylinder. These situations were investigated by computational analyses utilizing the KENO V.a Monte Carlo Computer Code. The results were used to estimate both the masses of water required for criticality, and the limiting masses of water that could be considered safe. The second objective of the assessment was to calculate the time available for emergency control actions before a criticality would occur, i.e., a {open_quotes}safetime{close_quotes}, for various sources of water and different size openings in a breached cylinder. In the situations considered, except the case for a fire hose, the safetime appears adequate for emergency control actions. The assessment shows that current practices for handling moderation controlled cylinders of low enriched UF{sub 6}, along with the continuation of established personnel training programs, ensure nuclear criticality safety for routine and emergency operations.

  19. Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump...

    Broader source: Energy.gov (indexed) [DOE]

    Average Historical Annual Gasoline Pump Price, 1929-2015 fotw915web.xlsx (24.76 KB) More Documents & Publications Fact 888: August 31, 2015 Historical Gas Prices - Dataset Fact ...

  20. Does anyone have access to 2012 average residential rates by...

    Open Energy Info (EERE)

    Does anyone have access to 2012 average residential rates by utility company? I'm seeing an inconsistency between the OpenEI website and EIA 861 data set. Home > Groups > Utility...

  1. Fact #624: May 24, 2010 Corporate Average Fuel Economy Standards...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The final rule for the Corporate Average Fuel Economy (CAFE) Standards was published in ... The CAFE levels that must be met by the fleet of each manufacturer will be determined by ...

  2. Table 14b. Average Electricity Prices, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    b. Average Electricity Prices, Projected vs. Actual" "Projected Price in Nominal Dollars" " (nominal dollars, cents per kilowatt-hour)" ,1993,1994,1995,1996,1997,1998,1999,2000,200...

  3. Table 14b. Average Electricity Prices, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    b. Average Electricity Prices, Projected vs. Actual Projected Price in Nominal Dollars (nominal dollars, cents per kilowatt-hour) 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 ...

  4. Table 11.1 Carbon Dioxide Emissions From Energy Consumption by Source, 1949-2011 (Million Metric Tons of Carbon Dioxide )

    U.S. Energy Information Administration (EIA) Indexed Site

    Carbon Dioxide Emissions From Energy Consumption by Source, 1949-2011 (Million Metric Tons of Carbon Dioxide 1) Year Coal 3 Natural Gas 4 Petroleum Total 2,9 Biomass 2 Aviation Gasoline Distillate Fuel Oil 5 Jet Fuel Kero- sene LPG 6 Lubri- cants Motor Gasoline 7 Petroleum Coke Residual Fuel Oil Other 8 Total Wood 10 Waste 11 Fuel Ethanol 12 Bio- diesel Total 1949 1,118 270 12 140 NA 42 13 7 329 8 244 25 820 2,207 145 NA NA NA 145 1950 1,152 313 14 168 NA 48 16 9 357 8 273 26 918 2,382 147 NA NA

  5. Table 11.2c Carbon Dioxide Emissions From Energy Consumption: Industrial Sector, 1949-2011 (Million Metric Tons of Carbon Dioxide )

    U.S. Energy Information Administration (EIA) Indexed Site

    c Carbon Dioxide Emissions From Energy Consumption: Industrial Sector, 1949-2011 (Million Metric Tons of Carbon Dioxide 1) Year Coal Coal Coke Net Imports Natural Gas 3 Petroleum Retail Elec- tricity 8 Total 2 Biomass 2 Distillate Fuel Oil 4 Kero- sene LPG 5 Lubri- cants Motor Gasoline 6 Petroleum Coke Residual Fuel Oil Other 7 Total Wood 9 Waste 10 Fuel Ethanol 11 Total 1949 500 -1 166 41 18 3 3 16 8 95 25 209 120 995 44 NA NA 44 1950 531 (s) 184 51 20 4 3 18 8 110 26 239 140 1,095 50 NA NA 50

  6. Table 11.2d Carbon Dioxide Emissions From Energy Consumption: Transportation Sector, 1949-2011 (Million Metric Tons of Carbon Dioxide )

    U.S. Energy Information Administration (EIA) Indexed Site

    d Carbon Dioxide Emissions From Energy Consumption: Transportation Sector, 1949-2011 (Million Metric Tons of Carbon Dioxide 1) Year Coal Natural Gas 3 Petroleum Retail Elec- tricity 7 Total 2 Biomass 2 Aviation Gasoline Distillate Fuel Oil 4 Jet Fuel LPG 5 Lubricants Motor Gasoline 6 Residual Fuel Oil Total Fuel Ethanol 8 Biodiesel Total 1949 161 NA 12 30 NA (s) 4 306 91 443 6 611 NA NA NA 1950 146 7 14 35 NA (s) 5 332 95 481 6 640 NA NA NA 1951 129 11 18 42 NA (s) 6 360 102 529 7 675 NA NA NA

  7. Flavor Physics Data from the Heavy Flavor Averaging Group (HFAG)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Heavy Flavor Averaging Group (HFAG) was established at the May 2002 Flavor Physics and CP Violation Conference in Philadelphia, and continues the LEP Heavy Flavor Steering Group's tradition of providing regular updates to the world averages of heavy flavor quantities. Data are provided by six subgroups that each focus on a different set of heavy flavor measurements: B lifetimes and oscillation parameters, Semi-leptonic B decays, Rare B decays, Unitarity triangle parameters, B decays to charm final states, and Charm Physics.

  8. Averaged null energy condition violation in a conformally flat spacetime

    SciTech Connect (OSTI)

    Urban, Douglas; Olum, Ken D.

    2010-01-15

    We show that the averaged null energy condition can be violated by a conformally coupled scalar field in a conformally flat spacetime in 3+1 dimensions. The violation is dependent on the quantum state and can be made as large as desired. It does not arise from the presence of anomalies, although anomalous violations are also possible. Since all geodesics in conformally flat spacetimes are achronal, the achronal averaged null energy condition is likewise violated.

  9. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G.

    2012-03-06

    A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  10. Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in...

  11. Low Quality Natural Gas Sulfur Removal and Recovery CNG Claus Sulfur Recovery Process

    SciTech Connect (OSTI)

    Klint, V.W.; Dale, P.R.; Stephenson, C.

    1997-10-01

    Increased use of natural gas (methane) in the domestic energy market will force the development of large non-producing gas reserves now considered to be low quality. Large reserves of low quality natural gas (LQNG) contaminated with hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}) and nitrogen (N) are available but not suitable for treatment using current conventional gas treating methods due to economic and environmental constraints. A group of three technologies have been integrated to allow for processing of these LQNG reserves; the Controlled Freeze Zone (CFZ) process for hydrocarbon / acid gas separation; the Triple Point Crystallizer (TPC) process for H{sub 2}S / C0{sub 2} separation and the CNG Claus process for recovery of elemental sulfur from H{sub 2}S. The combined CFZ/TPC/CNG Claus group of processes is one program aimed at developing an alternative gas treating technology which is both economically and environmentally suitable for developing these low quality natural gas reserves. The CFZ/TPC/CNG Claus process is capable of treating low quality natural gas containing >10% C0{sub 2} and measurable levels of H{sub 2}S and N{sub 2} to pipeline specifications. The integrated CFZ / CNG Claus Process or the stand-alone CNG Claus Process has a number of attractive features for treating LQNG. The processes are capable of treating raw gas with a variety of trace contaminant components. The processes can also accommodate large changes in raw gas composition and flow rates. The combined processes are capable of achieving virtually undetectable levels of H{sub 2}S and significantly less than 2% CO in the product methane. The separation processes operate at pressure and deliver a high pressure (ca. 100 psia) acid gas (H{sub 2}S) stream for processing in the CNG Claus unit. This allows for substantial reductions in plant vessel size as compared to conventional Claus / Tail gas treating technologies. A close integration of the components of the CNG Claus

  12. Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 4: June 9, 2014 EPA Sulfur Standards for Gasoline Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline Sulfur naturally occurs in gasoline and diesel fuel, contributing to pollution when the fuel is burned. Beginning in 2004, standards were set on the amount of sulfur in gasoline (Tier 2 standards). Separate standards were set for different entities, such as large refiners, small refiners, importers, downstream wholesalers, etc. In March 2014, Tier 3 standards were finalized by

  13. Chromium modified nickel-iron aluminide useful in sulfur bearing environments

    DOE Patents [OSTI]

    Cathcart, John V.; Liu, Chain T.

    1989-06-13

    An improved nickel-iron aluminide containing chromium and molybdenum additions to improve resistance to sulfur attack.

  14. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application deer09_cheng.pdf (564.79 KB) More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials Sulfur Effect and Performance Recovery of a DOC + CSF +

  15. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    5. Receipts, Average Cost, and Quality of Fossil Fuels: Electric Utilities, 2004 - 2014 Coal Petroleum Liquids Receipts Average Cost Receipts Average Cost Period (Billion Btu) (Thousand Tons) (Dollars per MMBtu) (Dollars per Ton) Average Sulfur Percent by Weight Percentage of Consumption (Billion Btu) (Thousand Barrels) (Dollars per MMBtu) (Dollars per Barrel) Average Sulfur Percent by Weight Percentage of Consumption Annual Totals 2004 15,440,681 758,557 1.34 27.30 0.91 98.2 592,478 93,034 4.80

  16. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    7 Receipts, Average Cost, and Quality of Fossil Fuels: Independent Power Producers, 2004 - 2014 Coal Petroleum Liquids Receipts Average Cost Receipts Average Cost Period (Billion Btu) (Thousand Tons) (Dollars per MMBtu) (Dollars per Ton) Average Sulfur Percent by Weight Percentage of Consumption (Billion Btu) (Thousand Barrels) (Dollars per MMBtu) (Dollars per Barrel) Average Sulfur Percent by Weight Percentage of Consumption Annual Totals 2004 4,410,775 227,700 1.41 27.27 1.13 93.3 337,011

  17. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    9. Receipts, Average Cost, and Quality of Fossil Fuels: Commercial Sector, 2004 - 2014 Coal Petroleum Liquids Receipts Average Cost Receipts Average Cost Period (Billion Btu) (Thousand Tons) (Dollars per MMBtu) (Dollars per Ton) Average Sulfur Percent by Weight Percentage of Consumption (Billion Btu) (Thousand Barrels) (Dollars per MMBtu) (Dollars per Barrel) Average Sulfur Percent by Weight Percentage of Consumption Annual Totals 2004 10,682 451 2.08 49.32 2.48 23.5 3,066 527 6.19 35.96 0.20

  18. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Receipts, Average Cost, and Quality of Fossil Fuels: Industrial Sector, 2004 - 2014 Coal Petroleum Liquids Receipts Average Cost Receipts Average Cost Period (Billion Btu) (Thousand Tons) (Dollars per MMBtu) (Dollars per Ton) Average Sulfur Percent by Weight Percentage of Consumption (Billion Btu) (Thousand Barrels) (Dollars per MMBtu) (Dollars per Barrel) Average Sulfur Percent by Weight Percentage of Consumption Annual Totals 2004 326,495 15,324 1.63 34.79 1.43 57.6 25,491 4,107 4.98 30.93

  19. Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of SiO2 with TiO2 and ZrO2 Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts via Surface Modification of SiO2 with TiO2 and ZrO2 This study ...

  20. Sulfur isotope ratios in petroleum research and exploration: Williston basin

    SciTech Connect (OSTI)

    Thode, H.G.

    1981-09-01

    The three major types of crude oil in the Williston basin - the type I oils of the Winnipeg-Red River system, the type II oils of the Bakken-Madison system, and the type III oils of the Tyler-Pennsylvanian system - can be distinguished by their sulfur isotope compositions. They have characteristic delta/sup 34/S values of 5.8 +- 1.2 parts per thousand (ppt), 2.8 +- 0.8 ppt, and -4.0 +- 0.7 ppt respectively. Highly mature oils have less typical values. Type II oils which have migrated over a distance of some 150 km beyond the region of generation have maintained their characteristic delta/sup 34/S values even though sulfur may have been lost. This indicates little or no interaction with reservoir sulfates under normal circumstances. On the periphery of the basin, type II oils altered by water washing and biodegradation have altered delta/sup 34/S values which increase from +2.9 to +9.4 ppt with the increasing degree of crude oil degradation. The Bakken shales, source of the type II oils, have delta/sup 34/S distribution patterns in the reduced sulfur typical of marine sediments. The delta/sup 34/S values for the type II oils match most closely the delta/sup 34/S value of organic sulfur in the black bituminous shales of the lower Bakken.

  1. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  2. Catalyst added to Claus furnace reduces sulfur losses

    SciTech Connect (OSTI)

    Luinstra, E.A.; d'Haene, P.E. (Shell Canada Ltd., Toronto, ON (Canada). Oakville Research Centre)

    1989-07-01

    Several substances effectively catalyze the reduction of carbon disulfide in Claus gas streams at Claus reaction furnace conditions (about 1,000{sup 0}C). Some conversion of carbonyl sulfide also occurs. Carbon disulfide and carbonyl sulfide as well-known problem compounds that reduce sulfur recovery efficiency in many sulfur recovery plants. Installation of a suitable catalytic material in the reaction furnace promises significant improvement of Claus plant efficiency, and prolonged life of the catalytic converters. Almost every Claus sulfur recovery plant makes some carbon disulfide (CS/sub 2/) and carbonyl sulfide (COS) in the reaction furnace, and in many of these plants, these compounds constitute a significant problem. CS/sub 2/ and COS often comprise more than 50% of sulfur losses in the tail gas. This article reexamines the issue of CS/sub 2/ and COS in the Claus plant. The relative importance of these two troublesome components is explored with data accumulated from Shell Canada Claus plants. The authors discuss which factors tend to produce these components. Then a method for reducing CS/sub 2/ and COS virtually at the source will be introduced.

  3. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect (OSTI)

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  4. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2004-11-02

    The disclosure is directed to sorbent compositions for removing reduced sulfur species (e.g., H.sub.2 S, COS and CS.sub.2) a feed stream. The sorbent is formed from a multi-phase composition including a zinc titanate phase and a zinc oxide-aluminate phase. The sorbent composition is substantially free of unreacted alumina.

  5. Hydroprocessing key issue in low-sulfur' era

    SciTech Connect (OSTI)

    Not Available

    1993-07-26

    Refiners gave heavy attention to hydroprocessing operations at the most recent National Petroleum Refiners Association annual question and answer session on refining and petrochemical technology. Among the topics covered were diesel color, blending to meet diesel sulfur specs, and ammonia injection in hydrocracking units. The panelists also related their experiences with increasing vacuum gas oil conversion in hydrocracking operations. These discussions are reproduced here.

  6. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J.

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  7. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    SciTech Connect (OSTI)

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  8. Doped carbon-sulfur species nanocomposite cathode for Li--S batteries

    SciTech Connect (OSTI)

    Wang, Donghai; Xu, Tianren; Song, Jiangxuan

    2015-12-29

    We report a heteroatom-doped carbon framework that acts both as conductive network and polysulfide immobilizer for lithium-sulfur cathodes. The doped carbon forms chemical bonding with elemental sulfur and/or sulfur compound. This can significantly inhibit the diffusion of lithium polysulfides in the electrolyte, leading to high capacity retention and high coulombic efficiency.

  9. FY08 MEMBRANE CHARACTERIZATION REPORT FOR HYBRID SULFUR ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

    2008-09-01

    This report summarizes results from all of the membrane testing completed to date at the Savannah River National Laboratory (SRNL) for the sulfur dioxide-depolarized electrolyzer (SDE). Several types of commercially-available membranes have been analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid (PFSA), sulfonated polyether-ketone-ketone (SPEKK), and polybenzimidazole membranes (PBI). Of these membrane types, the poly-benzimidazole membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Several experimental membranes have also been analyzed including hydrated sulfonated Diels-Alder polyphenylenes (SDAPP) membranes from Sandia National Laboratory, perfluorosulfonimide (PFSI) and sulfonated perfluorocyclobutyl aromatic ether (S-PFCB) prepared by Clemson University, hydrated platinum-treated PFSA prepared by Giner Electrochemical Systems (GES) and Pt-Nafion{reg_sign} 115 composites prepared at SRNL. The chemical stability, SO{sub 2} transport and ionic conductivity characteristics have been measured for several commercially available and experimental proton-conducting membranes. Commercially available PFSA membranes such as the Nafion{reg_sign} series exhibited excellent chemical stability and ionic conductivity in sulfur dioxide saturated sulfuric acid solutions. Sulfur dioxide transport in the Nafion{reg_sign} membranes varied proportionally with the thickness and equivalent weight of the membrane. Although the SO{sub 2} transport in the Nafion{reg_sign} membranes is higher than desired, the excellent chemical stability and conductivity makes this membrane the best commercially-available membrane at this time. Initial results indicated that a modified Nafion{reg_sign} membrane incorporating Pt nanoparticles exhibited significantly reduced SO{sub 2} transport. Reduced SO{sub 2} transport was also measured with commercially available PBI membrane and several experimental membranes produced

  10. High average power scaleable thin-disk laser

    DOE Patents [OSTI]

    Beach, Raymond J.; Honea, Eric C.; Bibeau, Camille; Payne, Stephen A.; Powell, Howard; Krupke, William F.; Sutton, Steven B.

    2002-01-01

    Using a thin disk laser gain element with an undoped cap layer enables the scaling of lasers to extremely high average output power values. Ordinarily, the power scaling of such thin disk lasers is limited by the deleterious effects of amplified spontaneous emission. By using an undoped cap layer diffusion bonded to the thin disk, the onset of amplified spontaneous emission does not occur as readily as if no cap layer is used, and much larger transverse thin disks can be effectively used as laser gain elements. This invention can be used as a high average power laser for material processing applications as well as for weapon and air defense applications.

  11. U.S. average gasoline price up slightly

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. average gasoline price up slightly The U.S. average retail price for regular gasoline rose slightly to $3.65 a gallon on Monday. That's up a tenth of a penny from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Pump prices were highest in the West Coast region at 3.89 a gallon, down 4.4 cents from a week ago. Prices were lowest in the Gulf Coast States at 3.34 a gallon, down 2.6 cents. Jonathan Cogan for EIA,

  12. Turning Bayesian model averaging into Bayesian model combination

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Turning Bayesian model averaging into Bayesian model combination Citation Details In-Document Search Title: Turning Bayesian model averaging into Bayesian model combination Authors: Carroll, James [1] ; Monteith, Kristine [2] ; Seppi, Kevin [2] ; Martinez, Tony [2] + Show Author Affiliations Los Alamos National Laboratory BYU Publication Date: 2011-07-28 OSTI Identifier: 1084524 Report Number(s): LA-UR-11-04419; LA-UR-11-4419 DOE Contract Number: AC52-06NA25396

  13. Sulfur Based Thermochemical Heat Storage for Baseload Concentrated Solar Power Generation

    SciTech Connect (OSTI)

    wong, bunsen

    2014-11-20

    This project investigates the engineering and economic feasibility of supplying baseload power using a concentrating solar power (CSP) plant integrated with sulfur based thermochemical heat storage. The technology stores high temperature solar heat in the chemical bonds of elemental sulfur. Energy is recovered as high temperature heat upon sulfur combustion. Extensive developmental and design work associated with sulfur dioxide (SO2) disproportionation and sulfuric acid (H2SO4) decomposition chemical reactions used in this technology had been carried out in the two completed phases of this project. The feasibility and economics of the proposed concept was demonstrated and determined.

  14. CLOSEOUT REPORT FOR HYBRID SULFUR PRESSURIZED BUTTON CELL TEST FACILITY

    SciTech Connect (OSTI)

    Steeper, T.

    2010-09-15

    This document is the Close-Out Report for design and partial fabrication of the Pressurized Button Cell Test Facility at Savannah River National Laboratory (SRNL). This facility was planned to help develop the sulfur dioxide depolarized electrolyzer (SDE) that is a key component of the Hybrid Sulfur Cycle for generating hydrogen. The purpose of this report is to provide as much information as possible in case the decision is made to resume research. This report satisfies DOE Milestone M3GSR10VH030107.0. The HyS Cycle is a hybrid thermochemical cycle that may be used in conjunction with advanced nuclear reactors or centralized solar receivers to produce hydrogen by watersplitting. The HyS Cycle utilizes the high temperature (>800 C) thermal decomposition of sulfuric acid to produce oxygen and regenerate sulfur dioxide. The unique aspect of HyS is the generation of hydrogen in a water electrolyzer that is operated under conditions where dissolved sulfur dioxide depolarizes the anodic reaction, resulting in substantial voltage reduction. Low cell voltage is essential for both high thermodynamic efficiency and low hydrogen cost. Sulfur dioxide is oxidized at the anode, producing sulfuric acid that is sent to the high temperature acid decomposition portion of the cycle. Sulfur dioxide from the decomposer is cycled back to electrolyzers. The electrolyzer cell uses the membrane electrode assembly (MEA) concept. Anode and cathode are formed by spraying a catalyst, typically platinized carbon, on both sides of a Proton Exchange Membrane (PEM). SRNL has been testing SDEs for several years including an atmospheric pressure Button Cell electrolyzer (2 cm{sup 2} active area) and an elevated temperature/pressure Single Cell electrolyzer (54.8 cm{sup 2} active area). SRNL tested 37 MEAs in the Single Cell electrolyzer facility from June 2005 until June 2009, when funding was discontinued. An important result of the final months of testing was the development of a method that

  15. Pennsylvania Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Ma 8.75 8.64 9.51 9.91 11.30 15.62 1989-2016 Commercial Average Price 7.19 7.44 8.21 8.12 8.74 10.69

  16. Speckle averaging system for laser raster-scan image projection

    DOE Patents [OSTI]

    Tiszauer, D.H.; Hackel, L.A.

    1998-03-17

    The viewers` perception of laser speckle in a laser-scanned image projection system is modified or eliminated by the addition of an optical deflection system that effectively presents a new speckle realization at each point on the viewing screen to each viewer for every scan across the field. The speckle averaging is accomplished without introduction of spurious imaging artifacts. 5 figs.

  17. Virginia Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Market 9.45 8.76 10.20 10.63 12.69 15.51 1989-2016 Commercial Average Price 6.88 6.67 7.18 6.65 7.24 7.22

  18. Speckle averaging system for laser raster-scan image projection

    DOE Patents [OSTI]

    Tiszauer, Detlev H.; Hackel, Lloyd A.

    1998-03-17

    The viewers' perception of laser speckle in a laser-scanned image projection system is modified or eliminated by the addition of an optical deflection system that effectively presents a new speckle realization at each point on the viewing screen to each viewer for every scan across the field. The speckle averaging is accomplished without introduction of spurious imaging artifacts.

  19. Maryland Average Price of Natural Gas Delivered to Residential...

    Gasoline and Diesel Fuel Update (EIA)

    8.35 18.44 19.08 19.39 13.51 12.72 1989-2015 Commercial Average Price 11.74 10.98 11.61 11.11 9.98 9.56...

  20. Michigan Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    2.50 13.65 13.52 13.21 8.93 7.84 1989-2015 Commercial Average Price 8.91 9.31 9.17 9.05 7.46 6.75...

  1. Parity-violating anomalies and the stationarity of stochastic averages

    SciTech Connect (OSTI)

    Reuter, M.

    1988-01-15

    Within the framework of stochastic quantization the parity-violating anomalies in odd space-time dimensions are derived from the asymptotic stationarity of the stochastic average of a certain fermion bilinear. Contrary to earlier attempts, this method yields the correct anomalies for both massive and massless fermions.

  2. Florida Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Markete 6.78 16.00 17.06 17.83 20.52 22.40 1989-2016 Commercial Average Price 10.70 10.62 10.50 10.29 10.16 10.38

  3. Georgia Average Price of Natural Gas Delivered to Residential and

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers by Local Distribution and Markete 0.79 10.94 13.01 16.48 20.53 24.74 1989-2016 Commercial Average Price 6.57 7.05 7.42 7.98 8.22 8.53

  4. Maryland Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 12.20 2006-2010 Marketers 13.51 2006-2010 Percent Sold by Local Distribution Companies 81.7 2006-2010 Commercial Average Price 9.87 10.29 10.00 10.06 ...

  5. Florida Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 17.85 2006-2010 Marketers 19.44 2006-2010 Percent Sold by Local Distribution Companies 97.9 2006-2010 Commercial Average Price 10.60 11.14 10.41 10.87 ...

  6. New Jersey Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 12.77 2006-2010 Marketers 14.87 2006-2010 Percent Sold by Local Distribution Companies 96.6 2006-2010 Commercial Average Price 10.11 9.51 8.50 9.55 ...

  7. Michigan Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Average Price 8.95 9.14 8.35 7.82 8.28 7.49 1967-2015 Local Distribution Companies 10.00 2006-2010 Marketers 7.61 2006-2010 Percent Sold by Local Distribution Companies ...

  8. Virginia Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 12.64 2006-2010 Marketers 13.64 2006-2010 Percent Sold by Local Distribution Companies 90.9 2006-2010 Commercial Average Price 9.55 9.69 8.77 8.83 9.17 ...

  9. Pennsylvania Average Price of Natural Gas Delivered to Residential...

    U.S. Energy Information Administration (EIA) Indexed Site

    Local Distribution Companies 12.82 2006-2010 Marketers 13.78 2006-2010 Percent Sold by Local Distribution Companies 91.2 2006-2010 Commercial Average Price 10.47 10.42 10.24 10.11 ...

  10. District of Columbia Average Price of Natural Gas Delivered to...

    U.S. Energy Information Administration (EIA) Indexed Site

    Average Price 12.26 12.24 11.19 11.64 12.18 11.55 1980-2015 Local Distribution Companies 12.99 2006-2010 Marketers 12.12 2006-2010 Percent Sold by Local Distribution Companies 16.4 ...

  11. Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification

    SciTech Connect (OSTI)

    Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

    2012-06-20

    Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

  12. Table 11.2b Carbon Dioxide Emissions From Energy Consumption: Commercial Sector, 1949-2011 (Million Metric Tons of Carbon Dioxide )

    U.S. Energy Information Administration (EIA) Indexed Site

    b Carbon Dioxide Emissions From Energy Consumption: Commercial Sector, 1949-2011 (Million Metric Tons of Carbon Dioxide 1) Year Coal Natural Gas 3 Petroleum Retail Electricity 7 Total 2 Biomass 2 Distillate Fuel Oil 4 Kerosene LPG 5 Motor Gasoline 6 Petroleum Coke Residual Fuel Oil Total Wood 8 Waste 9 Fuel Ethanol 10 Total 1949 148 19 16 3 2 7 NA 28 55 58 280 2 NA NA 2 1950 147 21 19 3 2 7 NA 33 66 63 297 2 NA NA 2 1951 125 25 21 4 3 8 NA 34 70 69 289 2 NA NA 2 1952 112 28 22 4 3 8 NA 35 71 73

  13. Table 11.2e Carbon Dioxide Emissions From Energy Consumption: Electric Power Sector, 1949-2011 (Million Metric Tons of Carbon Dioxide )

    U.S. Energy Information Administration (EIA) Indexed Site

    e Carbon Dioxide Emissions From Energy Consumption: Electric Power Sector, 1949-2011 (Million Metric Tons of Carbon Dioxide 1) Year Coal Natural Gas 3 Petroleum Geo- thermal Non- Biomass Waste 5 Total 2 Biomass 2 Distillate Fuel Oil 4 Petroleum Coke Residual Fuel Oil Total Wood 6 Waste 7 Total 1949 187 30 2 NA 30 33 NA NA 250 1 NA 1 1950 206 35 2 NA 35 37 NA NA 278 1 NA 1 1951 235 42 2 NA 29 31 NA NA 308 1 NA 1 1952 240 50 2 NA 31 33 NA NA 323 1 NA 1 1953 260 57 3 NA 38 40 NA NA 358 (s) NA (s)

  14. Scale-up of mild gasification to be a process development unit mildgas 24 ton/day PDU design report. Final report, November 1991--July 1996

    SciTech Connect (OSTI)

    1996-03-01

    From November 1991 to April 1996, Kerr McGee Coal Corporation (K-M Coal) led a project to develop the Institute of Gas Technology (IGT) Mild Gasification (MILDGAS) process for near-term commercialization. The specific objectives of the program were to: design, construct, and operate a 24-tons/day adiabatic process development unit (PDU) to obtain process performance data suitable for further design scale-up; obtain large batches of coal-derived co-products for industrial evaluation; prepare a detailed design of a demonstration unit; and develop technical and economic plans for commercialization of the MILDGAS process. The project team for the PDU development program consisted of: K-M Coal, IGT, Bechtel Corporation, Southern Illinois University at Carbondale (SIUC), General Motors (GM), Pellet Technology Corporation (PTC), LTV Steel, Armco Steel, Reilly Industries, and Auto Research.

  15. Investigations on catalyzed steam gasification of biomass. Appendix A. Feasibility study of methane production via catalytic gasification of 2000 tons of wood per day

    SciTech Connect (OSTI)

    Mudge, L.K.; Weber, S.L.; Mitchell, D.H.; Sealock, L.J. Jr.; Robertus, R.J.

    1981-01-01

    A study has been made of the economic feasibility of producing substitute natural gas (SNG) from wood via catalytic gasification with steam. The plant design in this study was developed from information on gasifier operation supplied by the Pacific Northwest Laboratory (PNL). The plant is designed to process 2000 tons per day of dry wood to SNG. Plant production is 21.6 MM scfd of SNG with a HHV of 956 Btu per scf. All process and support facilities necessary to convert wood to SNG are included. The plant location is Newport, Oregon. The capital cost for the plant is $95,115,000 - September, 1980 basis. Gas production costs which allow for return on capital have been calculated for various wood prices for both utility and private investor financing. For utility financing, the gas production costs are respectively $5.09, $5.56, $6.50, and $8.34 per MM Btu for wood costs of $5, $10, $20, and $40 per dry ton delivered to the plant at a moisture content of 49.50 wt %. For private investor financing, the corresponding product costs are $6.62, $7.11, $8.10, and $10.06 per MM Btu. The cost calculated by the utility financing method includes a return on equity of 15% and an interest rate of 10% on the debt. The private investor financing method, which is 100% equity financing, incorporates a discounted cash flow (DCF) return on equity of 12%. The thermal efficiency without taking an energy credit for by-product char is 58.3%.

  16. Method of making sulfur-resistant composite metal membranes

    DOE Patents [OSTI]

    Way, J. Douglas (Boulder, CO) [Boulder, CO; Lusk, Mark (Golden, CO) [Golden, CO; Thoen, Paul (Littleton, CO) [Littleton, CO

    2012-01-24

    The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.

  17. Modeling an Application's Theoretical Minimum and Average Transactional Response Times

    SciTech Connect (OSTI)

    Paiz, Mary Rose

    2015-04-01

    The theoretical minimum transactional response time of an application serves as a ba- sis for the expected response time. The lower threshold for the minimum response time represents the minimum amount of time that the application should take to complete a transaction. Knowing the lower threshold is beneficial in detecting anomalies that are re- sults of unsuccessful transactions. On the converse, when an application's response time falls above an upper threshold, there is likely an anomaly in the application that is causing unusual performance issues in the transaction. This report explains how the non-stationary Generalized Extreme Value distribution is used to estimate the lower threshold of an ap- plication's daily minimum transactional response time. It also explains how the seasonal Autoregressive Integrated Moving Average time series model is used to estimate the upper threshold for an application's average transactional response time.

  18. Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries - Joint Center for Energy Storage Research July 11, 2016, Research Highlights Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur Batteries Precipitation-dissolution Li-S chemistry achieved by sparingly solvating electrolyte and various electrolyte design concepts Scientific Achievement This work presents the promising new concepts of using sparingly solvating electrolyte to enable Li-S battery operation at lean electrolyte condition, as well as the design rules

  19. Development of High Energy Lithium-Sulfur Batteries

    Broader source: Energy.gov (indexed) [DOE]

    High Energy Lithium-Sulfur Batteries Jun Liu and Dongping Lu Pacific Northwest National Laboratory 2016 DOE Vehicle Technologies Program Review June 6-10, 2016 This presentation does not contain any proprietary, confidential, or otherwise restricted information Project ID #ES282 1 1 2 Overview Timeline * Start date: Oct. 2012 * End date: Sept. 2017 * Percent complete: 80% Budget * Total project funding - DOE share 100% * Funding received in FY15: $400k * Funding for FY16: $400k Barriers *

  20. Molten iron oxysulfide as a superior sulfur sorbent

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1990-01-01

    Slagging combustors with injected lime or limestone are being considered as replacements for conventional coal burners. They have advantages in that they can be staged to reduce NO{sub x} and SO{sub x} emissions. Iron oxide, as an alternative to lime or limestone may be effective not only as a desulfurizing agent, but under the right conditions of oxygen potential and after combination with sulfur, the reaction products of coal gases with iron oxide can act as a flux to produce a fluid phase. The thermodynamic conditions for determining the most effective operating conditions of the first stage of a combustor are calculated for several Illinois coals. These conditions include contact of the gas with the phase combinations: CaO/CaSO{sub 4}, CaO/CaS, and Fe/FeO/liquid for the temperature range 950{degree} to 1300{degree}C. In the latter system, the minimum dosage of iron required at equilibrium and the calculated maximum percent sulfur removal are reported. Also given are the expected pounds of SO{sub 2} per million Btu of heat evolution calculated for complete combustion. The calculations indicate that for the Fe-O-S system, higher temperatures give better results approaching 96 percent sulfur removal from a coal containing 4.2% sulfur. For this example, the stack gas emerging from the second stage of combustion under stoichiometric conditions would contain 0.36 pounds of SO{sub 2} per million BTU's of heat generated. The temperature limits of the sulfate and sulfide forming reactions are defined.

  1. Modified dry limestone process for control of sulfur dioxide emissions

    DOE Patents [OSTI]

    Shale, Correll C.; Cross, William G.

    1976-08-24

    A method and apparatus for removing sulfur oxides from flue gas comprise cooling and conditioning the hot flue gas to increase the degree of water vapor saturation prior to passage through a bed of substantially dry carbonate chips or lumps, e.g., crushed limestone. The reaction products form as a thick layer of sulfites and sulfates on the surface of the chips which is easily removed by agitation to restore the reactive surface of the chips.

  2. Averaging cross section data so we can fit it

    SciTech Connect (OSTI)

    Brown, D.

    2014-10-23

    The 56Fe cross section we are interested in have a lot of fluctuations. We would like to fit the average of the cross section with cross sections calculated within EMPIRE. EMPIRE is a Hauser-Feshbach theory based nuclear reaction code, requires cross sections to be smoothed using a Lorentzian profile. The plan is to fit EMPIRE to these cross sections in the fast region (say above 500 keV).

  3. Electric Sales, Revenue, and Average Price 2011 - Energy Information

    U.S. Energy Information Administration (EIA) Indexed Site

    Administration Electricity Glossary › FAQS › Overview Data Electricity Data Browser (interactive query tool with charting & mapping) Summary Sales (consumption), revenue, prices & customers Generation and thermal output Capacity of electric power plants Consumption of fuels used to generate electricity Receipts of fossil-fuels for electricity generation Average cost of fossil-fuels for electricity generation Fossil-fuel stocks for electricity generation Cost, revenue and expense

  4. Average dynamics of a finite set of coupled phase oscillators

    SciTech Connect (OSTI)

    Dima, Germn C. Mindlin, Gabriel B.

    2014-06-15

    We study the solutions of a dynamical system describing the average activity of an infinitely large set of driven coupled excitable units. We compared their topological organization with that reconstructed from the numerical integration of finite sets. In this way, we present a strategy to establish the pertinence of approximating the dynamics of finite sets of coupled nonlinear units by the dynamics of its infinitely large surrogate.

  5. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    SciTech Connect (OSTI)

    Lin, Zhan; Liang, Chengdu

    2015-01-01

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and the electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.

  6. Method for preparing a sodium/sulfur cell

    DOE Patents [OSTI]

    Weiner, Steven A.

    1978-01-01

    A method for preparing a sodium/sulfur cell comprising (A) inserting a solid sodium slug, adapted to be connected to an external circuit, into the anodic reaction zone of a cell subassembly maintained within an inert atmosphere, said cell subassembly comprising a cell container and a tubular cation-permeable barrier disposed within said container such that a first reaction zone is located within cation-permeable barrier and a second reaction zone is located between the outer surface of said cation-permeable barrier and the inner surface of said container, one of said reaction zones being said anodic reaction zone and the other of said reaction zone being a cathodic reaction zone containing a precast composite cathodic reactant comprising a sulfur impregnated porous conductive material connected to said cation permeable barrier and adapted to be connected to said external circuit; and (B) providing closure means for said subassembly and sealing the same to said subassembly at a temperature less than about 100.degree. C. The method of the invention overcomes deficiencies of the prior art methods by allowing preparation of a sodium/sulfur cell without the use of molten reactants and the fill spouts which are required when the cell is filled with molten reactants.

  7. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Zhan; Liang, Chengdu

    2014-11-11

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and themore » electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.« less

  8. Removal of nitrogen and sulfur from oil-shale

    SciTech Connect (OSTI)

    Olmstead, W.N.

    1986-01-28

    This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

  9. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    SciTech Connect (OSTI)

    Lin, Zhan; Liang, Chengdu

    2014-11-11

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and the electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.

  10. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P.; Lynn, Scott

    1995-01-01

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  11. Glass surface deactivants for sulfur-containing gases

    SciTech Connect (OSTI)

    Farwell, S.O.; Gluck, S.J.

    1980-10-01

    In gas chromatographic technique for measuring reduced sulfur-containing gases in biogenic air fluxes, the major problem seemed to be the irreversible adsorption of the polar sulfur compounds on the glass surfaces of the cryogenic sampling traps. This article discusses the comparative degrees of Pyrex glass surface passivation for over 25 chemical deactivants and their related pretreatment procedures. Since H/sub 2/S was discovered to be the sulfur compound with a consistently lower recovery efficiency than COS, CH/sub 3/SH, CH/sub 3/SCH, CS/sub 2/ or CH/sub 3/SSCH/sub 3/, the percent recovery for H/sub 2/S was employed as the indicator of effectiveness for the various deactivation treatments. Tables are presented summarizing the mean H/sub 2/S recoveries for chlorosilane deactivants and for the mean H/sub 2/S recoveries for different pyrex surface pretreatments with an octadecyltrialkoxysilane deactivation. The general conclusion of this investigation is that the relative degree of passivation for glass surfaces by present deactivation techniques is dependent on the types of analyzed compounds and the nature of the glass surface.

  12. Utilizing the market to control sulfur dioxide emissions

    SciTech Connect (OSTI)

    Loeher, C.F. III

    1995-12-01

    Environmental policy in the United States is evolving; command and control approaches are being slowly replaced with market-based incentives. Market-based regulation is favorable because it provides the regulated community with flexibility in choosing between pollution control options. A recent application of a market-based approach is Title IV of the 1990 Clean Air Act Amendments. This paper evaluates the advantages of utilizing market-based incentives to control sulfur dioxide emissions. The evaluation embodies an extensive methodology, which provides an overview of the policy governing air quality, discusses pollution control philosophies and analyzes their associated advantages and limitations. Further, it describes the development and operation of a market for emissions trading, impediments to the market, and recommends strategies to improve the market. The evaluation concludes by analyzing the results of five empirical simulations demonstrating the cost-effectiveness of employing market-based incentives versus command-and-control regulation for controlling sulfur dioxide emissions. The results of the evaluation indicate that regulatory barriers and market impediments have inhibited allowance trading. However, many of these obstacles have been or are being eliminated through Federal and state regulations, and through enhancement of the market. Results also demonstrate that sulfur dioxide allowance trading can obtain identical levels of environmental protection as command-and-control approaches while realizing cost savings to government and industry.

  13. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility ofmore » the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.« less

  14. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  15. RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Hobbs, D.

    2010-07-22

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

  16. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2001-11-06

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x

  17. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2002-04-29

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2001 through March 31, 2002. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub X} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the fifth reporting period for the subject Cooperative Agreement. During the previous (fourth) period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant) and a byproduct magnesium hydroxide slurry (at both Gavin and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub X} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the

  18. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Date Report No. 3: Diesel Fuel Sulfur Effects on Particulate Matter Emissions

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    1999-11-15

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report covers the effects of diesel fuel sulfur level on particulate matter emissions for four technologies.

  19. ENERGY EFFICIENCY LIMITS FOR A RECUPERATIVE BAYONET SULFURIC ACID DECOMPOSITION REACTOR FOR SULFUR CYCLE THERMOCHEMICAL HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Gorensek, M.; Edwards, T.

    2009-06-11

    A recuperative bayonet reactor design for the high-temperature sulfuric acid decomposition step in sulfur-based thermochemical hydrogen cycles was evaluated using pinch analysis in conjunction with statistical methods. The objective was to establish the minimum energy requirement. Taking hydrogen production via alkaline electrolysis with nuclear power as the benchmark, the acid decomposition step can consume no more than 450 kJ/mol SO{sub 2} for sulfur cycles to be competitive. The lowest value of the minimum heating target, 320.9 kJ/mol SO{sub 2}, was found at the highest pressure (90 bar) and peak process temperature (900 C) considered, and at a feed concentration of 42.5 mol% H{sub 2}SO{sub 4}. This should be low enough for a practical water-splitting process, even including the additional energy required to concentrate the acid feed. Lower temperatures consistently gave higher minimum heating targets. The lowest peak process temperature that could meet the 450-kJ/mol SO{sub 2} benchmark was 750 C. If the decomposition reactor were to be heated indirectly by an advanced gas-cooled reactor heat source (50 C temperature difference between primary and secondary coolants, 25 C minimum temperature difference between the secondary coolant and the process), then sulfur cycles using this concept could be competitive with alkaline electrolysis provided the primary heat source temperature is at least 825 C. The bayonet design will not be practical if the (primary heat source) reactor outlet temperature is below 825 C.

  20. Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Lin, Zhan; Liu, Zengcai; Fu, Wujun; Dudney, Nancy J; Liang, Chengdu

    2013-01-01

    Given the great potential for improving the energy density of state-of-the-art lithium-ion batteries by a factor of 5, a breakthrough in lithium-sulfur (Li-S) batteries will have a dramatic impact in a broad scope of energy related fields. Conventional Li-S batteries that use liquid electrolytes are intrinsically short-lived with low energy efficiency. The challenges stem from the poor electronic and ionic conductivities of elemental sulfur and its discharge products. We report herein lithium polysulfidophosphates (LPSP), a family of sulfur-rich compounds, as the enabler of long-lasting and energy-efficient Li-S batteries. LPSP have ionic conductivities of 3.0 10-5 S cm-1 at 25 oC, which is 8 orders of magnitude higher than that of Li2S (~10-13 S cm-1). The high Li-ion conductivity of LPSP is the salient characteristic of these compounds that impart the excellent cycling performance to Li-S batteries. In addition, the batteries are configured in an all-solid state that promises the safe cycling of high-energy batteries with metallic lithium anodes.

  1. Table 4. Average value of photovoltaic modules, 2004-2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Average value of photovoltaic modules, 2004-2014" "(dollars per peak watt)" "Year","Modules" 2004,2.99 2005,3.19 2006,3.5 2007,3.37 2008,3.49 2009,2.79 2010,1.96 2011,1.59 2012,1.15 2013,0.75 2014,0.87 "Source: U.S. Energy Information Administration, Form EIA-63B, 'Annual Photovoltaic Cell/Module Shipments Report.' Note: Dollars are not adjusted for inflation.

  2. The South Karelia Air Pollution Study. The effects of malodorous sulfur compounds from pulp mills on respiratory and other symptoms

    SciTech Connect (OSTI)

    Jaakkola, J.J.; Vilkka, V.; Marttila, O.; Jaeppinen, P.H.; Haahtela, T. )

    1990-12-01

    The paper mills in South Karelia, the southeast part of Finland, are responsible for releasing a substantial amount of malodorous sulfur compounds such as hydrogen sulfide (H2S), methyl mercaptan (CH3SH), and methyl sulfides ((CH3)2S and (CH3)2S2), into ambient air. In the most polluted residential area the annual mean concentrations of hydrogen sulfide and methyl mercaptan are estimated to be 8 and 2 to 5 micrograms/m3 and the highest daily average concentration 100 and 50 micrograms/m3. The annual mean and highest daily concentrations of sulfur dioxide (SO2) are very low. We studied the effects of malodorous sulfur compounds on eye, nasal and respiratory symptoms, and headache in adults. A cross-sectional self-administered questionnaire was distributed in February 1987 and responded to by 488 adults living in a severely (n = 198), a moderately (n = 204), and a nonpolluted community (n = 86). This included questions about occurrence of the symptoms of interest during the previous 4 wk and 12 months and individual, behavioral, and other environmental determinants of the symptoms. The response rate was 83%. The odds ratios (OR) for symptoms experienced often or constantly in severely versus nonpolluted and moderately versus nonpolluted communities were estimated in logistic regression analysis controlling potential confounders. The odds ratios for eye (moderate exposure OR 11.70, Cl95% 2.33 to 58.65; severe exposure OR 11.78, Cl95% 2.35 to 59.09) and nasal symptoms (OR 2.01, Cl95% 0.97 to 4.15; OR 2.19, Cl95% 1.06 to 4.55) and cough (OR 1.89, Cl95% 0.61 to 5.86; OR 3.06, Cl95% 1.02 to 9.29) during the previous 12 months were increased, with a dose-response pattern.

  3. Predictive RANS simulations via Bayesian Model-Scenario Averaging

    SciTech Connect (OSTI)

    Edeling, W.N.; Cinnella, P.; Dwight, R.P.

    2014-10-15

    The turbulence closure model is the dominant source of error in most Reynolds-Averaged Navier–Stokes simulations, yet no reliable estimators for this error component currently exist. Here we develop a stochastic, a posteriori error estimate, calibrated to specific classes of flow. It is based on variability in model closure coefficients across multiple flow scenarios, for multiple closure models. The variability is estimated using Bayesian calibration against experimental data for each scenario, and Bayesian Model-Scenario Averaging (BMSA) is used to collate the resulting posteriors, to obtain a stochastic estimate of a Quantity of Interest (QoI) in an unmeasured (prediction) scenario. The scenario probabilities in BMSA are chosen using a sensor which automatically weights those scenarios in the calibration set which are similar to the prediction scenario. The methodology is applied to the class of turbulent boundary-layers subject to various pressure gradients. For all considered prediction scenarios the standard-deviation of the stochastic estimate is consistent with the measurement ground truth. Furthermore, the mean of the estimate is more consistently accurate than the individual model predictions.

  4. Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System | Department of Energy Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System effect and performance recovery studies at system level with typical diesel emission control consisting of diesel oxidation catalyst, catalyzed soot filter, and selective catalytic reduction deer11_tang.pdf (504.68 KB) More Documents & Publications Investigation of Sulfur Deactivation on Cu/Zeolite SCR

  5. DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Distillate | Department of Energy Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate February 1, 2011 - 12:00pm Addthis Washington, DC - The current inventory of the Northeast Home Heating Oil Reserve will be converted to cleaner burning ultra low sulfur distillate to comply with new, more stringent fuel standards by some Northeastern states, the U.S. Department of Energy (DOE) said

  6. Prevalence of persistent cough and phlegm in young adults in relation to long-term ambient sulfur oxide exposure

    SciTech Connect (OSTI)

    Chapman, R.S.; Calafiore, D.C.; Hasselblad, V.

    1985-01-01

    In early 1976, a survey of persistent co gh and plegma (PCP) prevalence was conducted in 5623 young adults in four Utah communities. Over the previous five years, community specific mean sulfur dioxide levels had been 11, 18, 36, and 115 ug/mT. Corresponding mean suspended sulfate levels had been 5, 7, 8, and 14 g/mT No intercommunity exposure gradient of total suspended particulates or suspended nitrates was observed. In mothers, PCP prevalence among non-smokers was 4.2% in the high-exposure community and about 2.0% in all other communities. In smoking mothers, PCP prevalence was 21.8% in the high-exposure community and about 15.0% elsewhere. In fathers, PCP prevalence among non-smokers was about 8.0% in the high-exposure community and averaged about 3.0% elsewhere. In smoking fathers, PCP prevalence was less strongly associated with sulfur oxide exposure. PCP prevalence rates estimated in a categorical logistic regression model were qualitatively consistent with the prevalences presented above.

  7. "(Million Metric Tons Carbon Dioxide)"

    U.S. Energy Information Administration (EIA) Indexed Site

    ....0280756469,0.02562455361,0.02345646124 " China",2293,5558,5862,6284,7716,9057,10514,11945...,0.4312535075,0.4478837352,0.7550810962 " China",0.1064692737,0.1961919973,0.2032923089,0....

  8. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-10-01

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2003 through September, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the eighth reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the semi

  9. SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-07-03

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for

  10. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    SciTech Connect (OSTI)

    Maddalena, Randy

    2011-08-20

    Problem drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. The U.S. Consumer Product Safety Commission's (CPSC) investigation of problem drywall incorporates three parallel tracks: (1) evaluating the relationship between the drywall and reported health symptoms; (2) evaluating the relationship between the drywall and electrical and fire safety issues in affected homes; and (3) tracing the origin and the distribution of the drywall. To assess the potential impact on human health and to support testing for electrical and fire safety, the CPSC has initiated a series of laboratory tests that provide elemental characterization of drywall, characterization of chemical emissions, and in-home air sampling. The chemical emission testing was conducted at Lawrence Berkeley National Laboratory (LBNL). The LBNL study consisted of two phases. In Phase 1 of this study, LBNL tested thirty drywall samples provided by CPSC and reported standard emission factors for volatile organic compounds (VOCs), aldehydes, reactive sulfur gases (RSGs) and volatile sulfur compounds (VSCs). The standard emission factors were determined using small (10.75 liter) dynamic test chambers housed in a constant temperature environmental chamber. The tests were all run at 25 C, 50% relative humidity (RH) and with an area-specific ventilation rate of {approx}1.5 cubic meters per square meter of emitting surface per hour [m{sup 3}/m{sup 2}/h]. The thirty samples that were tested in Phase 1 included seventeen that were manufactured in China in 2005, 2006 and 2009, and thirteen that were manufactured in North America in 2009. The measured emission factors for VOCs and aldehydes were generally low and did not differ significantly between the Chinese and North American drywall. Eight of the samples tested had elevated emissions of volatile sulfur-containing compounds with total RSG emission factors between 32 and 258 micrograms per square meter

  11. Sulfur barrier for use with in situ processes for treating formations

    DOE Patents [OSTI]

    Vinegar, Harold J.; Christensen, Del Scot

    2009-12-15

    Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. Sulfur may be introduced into one or more wellbores located inside a perimeter of a treatment area in the formation having a permeability of at least 0.1 darcy. At least some of the sulfur is allowed to move towards portions of the formation cooler than the melting point of sulfur to solidify the sulfur in the formation to form the barrier.

  12. SULFUR REMOVAL FROM PIPE LINE NATURAL GAS FUEL: APPLICATION TO FUEL CELL POWER GENERATION SYSTEMS

    SciTech Connect (OSTI)

    King, David L.; Birnbaum, Jerome C.; Singh, Prabhakar

    2003-11-21

    Pipeline natural gas is being considered as the fuel of choice for utilization in fuel cell-based distributed generation systems because of its abundant supply and the existing supply infrastructure (1). For effective utilization in fuel cells, pipeline gas requires efficient removal of sulfur impurities (naturally occurring sulfur compounds or sulfur bearing odorants) to prevent the electrical performance degradation of the fuel cell system. Sulfur odorants such as thiols and sulfides are added to pipeline natural gas and to LPG to ensure safe handling during transportation and utilization. The odorants allow the detection of minute gas line leaks, thereby minimizing the potential for explosions or fires.

  13. Portable instrument and method for detecting reduced sulfur compounds in a gas

    DOE Patents [OSTI]

    Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

    1983-06-01

    A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

  14. Status of Heavy Vehicle Diesel Emission Control Sulfur Effects (DECSE) Test Program

    SciTech Connect (OSTI)

    George Sverdrup

    1999-06-07

    DECSE test program is well under way to providing data on effects of sulfur levels in diesel fuel on performance of emission control technologies.

  15. CE IGCC Repowering plant sulfuric acid plant. Topical report, June 1993

    SciTech Connect (OSTI)

    Chester, A.M.

    1993-12-01

    A goal of the CE IGCC Repowering project is to demonstrate a hot gas clean-up system (HGCU), for the removal of sulfur from the product gas stream exiting the gasifier island. Combustion Engineering, Inc. (ABB CE) intends to use a HGCU developed by General Electric Environmental Services (GEESI). The original design of this system called for the installation of the HGCU, with a conventional cold gas clean-up system included as a full-load operational back-up. Each of these systems removes sulfur compounds and converts them into an acid off-gas. This report deals with the investigation of equipment to treat this off-gas, recovering these sulfur compounds as elemental sulfur, sulfuric acid or some other form. ABB CE contracted ABB Lummus Crest Inc. (ABB LCI) to perform an engineering evaluation to compare several such process options. This study concluded that the installation of a sulfuric acid plant represented the best option from both a technical and economic point of view. Based on this evaluation, ABB CE specified that a sulfuric acid plant be installed to remove sulfur from off-gas exiling the gas clean-up system. ABB LCI prepared a request for quotation (RFQ) for the construction of a sulfuric acid production plant. Monsanto Enviro-Chem Inc. presented the only proposal, and was eventually selected as the EPC contractor for this system.

  16. A Long-Life, High-Rate Lithium/Sulfur Cell: A Multifaceted Approach...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Life, High-Rate LithiumSulfur Cell: A Multifaceted Approach to Enhancing Cell Performance Min-Kyu Song, , Yuegang Zhang,* ,, and Elton J. Cairns* ,, The...

  17. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Content, Sales Type, and PAD District 242 Energy Information Administration Petroleum Marketing Annual 1997 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  18. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Content, Sales Type, and PAD District 242 Energy Information Administration Petroleum Marketing Annual 1996 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  19. U.S. Conventional, Average Refiner Gasoline Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    346 1.209 1.450 1.617 1.790 1.894 1994-2016 Through Retail Outlets 1.345 1.209 1.451 1.617 1.791 1.895 1994-2016 Sales for Resale, Average 1.117 0.998 1.276 1.416 1.573 1.597 1994-2016 DTW 1.337 1.143 1.369 1.498 1.641 1.696 1994-2016 Rack 1.109 0.995 1.283 1.421 1.583 1.602 1994-2016 Bulk 1.137 0.991 1.194 1.339 1.451 1.522

  20. U.S. Reformulated, Average Refiner Gasoline Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    790 1.553 1.736 1.921 2.011 2.078 1994-2016 Through Retail Outlets 1.792 1.554 1.737 1.921 2.012 2.079 1994-2016 Sales for Resale, Average 1.331 1.143 1.463 1.601 1.694 1.740 1994-2016 DTW 1.796 1.471 1.783 1.895 1.917 1.983 1994-2016 Rack 1.221 1.066 1.388 1.533 1.645 1.690 1994-2016 Bulk 1.307 1.074 1.377 1.514 1.602 1.619

  1. Average System Cost Methodology : Administrator's Record of Decision.

    SciTech Connect (OSTI)

    United States. Bonneville Power Administration.

    1984-06-01

    Significant features of average system cost (ASC) methodology adopted are: retention of the jurisdictional approach where retail rate orders of regulartory agencies provide primary data for computing the ASC for utilities participating in the residential exchange; inclusion of transmission costs; exclusion of construction work in progress; use of a utility's weighted cost of debt securities; exclusion of income taxes; simplification of separation procedures for subsidized generation and transmission accounts from other accounts; clarification of ASC methodology rules; more generous review timetable for individual filings; phase-in of reformed methodology; and each exchanging utility must file under the new methodology within 20 days of implementation by the Federal Energy Regulatory Commission of the ten major participating utilities, the revised ASC will substantially only affect three. (PSB)

  2. Gauge and averaging in gravitational self-force

    SciTech Connect (OSTI)

    Gralla, Samuel E.

    2011-10-15

    A difficulty with previous treatments of the gravitational self-force is that an explicit formula for the force is available only in a particular gauge (Lorenz gauge), where the force in other gauges must be found through a transformation law once the Lorenz-gauge force is known. For a class of gauges satisfying a 'parity condition' ensuring that the Hamiltonian center of mass of the particle is well-defined, I show that the gravitational self-force is always given by the angle average of the bare gravitational force. To derive this result I replace the computational strategy of previous work with a new approach, wherein the form of the force is first fixed up to a gauge-invariant piece by simple manipulations, and then that piece is determined by working in a gauge designed specifically to simplify the computation. This offers significant computational savings over the Lorenz gauge, since the Hadamard expansion is avoided entirely and the metric perturbation takes a very simple form. I also show that the rest mass of the particle does not evolve due to first-order self-force effects. Finally, I consider the 'mode sum regularization' scheme for computing the self-force in black hole background spacetimes, and use the angle-average form of the force to show that the same mode-by-mode subtraction may be performed in all parity-regular gauges. It appears plausible that suitably modified versions of the Regge-Wheeler and radiation gauges (convenient to Schwarzschild and Kerr, respectively) are in this class.

  3. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I.

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  4. A solvent system to provide selective removal of sulfur compounds

    SciTech Connect (OSTI)

    Pearce, R.L.; Bacon, T.R.

    1986-01-01

    Energy costs and SRU inefficiencies resulting from utilization of low strength MEA technology induced a large refinery to convert to MDEA. One of the seven product streams being treated required extremely low carbonyl sulfide in the treated product. This required careful consideration in making the decision to convert. However, the conclusions were that the advantages outweighed the disadvantages. When the initial converted operations verified a need to improve the carbonyl sulfide removal, GAS/SPEC Tech Service produced an innovative solution which allowed for efficient operation at acceptable COS specification, lower energy utilization, reduced solvent losses, and improved sulfur recovery unit operation.

  5. Corrosion of aluminum clad spent nuclear fuel in the 70 ton cask during transfer from L area to H-canyon

    SciTech Connect (OSTI)

    Mickalonis, J. I.

    2015-08-01

    Aluminum-clad spent nuclear fuel will be transported for processing in the 70-ton nuclear fuel element cask from L Basin to H-canyon. During transport these fuels would be expected to experience high temperature aqueous corrosion from the residual L Basin water that will be present in the cask. Cladding corrosion losses during transport were calculated for material test reactor (MTR) and high flux isotope reactors (HFIR) fuels using literature and site information on aqueous corrosion at a range of time/temperature conditions. Calculations of the cladding corrosion loss were based on Arrhenius relationships developed for aluminum alloys typical of cladding material with the primary assumption that an adherent passive film does not form to retard the initial corrosion rate. For MTR fuels a cladding thickness loss of 33% was found after 1 year in the cask with a maximum temperature of 263 °C. HFIR fuels showed a thickness loss of only 6% after 1 year at a maximum temperature of 180 °C. These losses are not expected to impact the overall confinement function of the aluminum cladding.

  6. Corrosion of aluminum clad spent nuclear fuel in the 70 ton cask during transfer from L area to H-canyon

    SciTech Connect (OSTI)

    Mickalonis, J. I.

    2015-08-31

    Aluminum-clad spent nuclear fuel will be transported for processing in the 70-ton nuclear fuel element cask from L Basin to H-canyon. During transport these fuels would be expected to experience high temperature aqueous corrosion from the residual L Basin water that will be present in the cask. Cladding corrosion losses during transport were calculated for material test reactor (MTR) and high flux isotope reactors (HFIR) fuels using literature and site information on aqueous corrosion at a range of time/temperature conditions. Calculations of the cladding corrosion loss were based on Arrhenius relationships developed for aluminum alloys typical of cladding material with the primary assumption that an adherent passive film does not form to retard the initial corrosion rate. For MTR fuels a cladding thickness loss of 33 % was found after 1 year in the cask with a maximum temperature of 263 °C. HFIR fuels showed a thickness loss of only 6% after 1 year at a maximum temperature of 180 °C. These losses are not expected to impact the overall confinement function of the aluminum cladding.

  7. CORROSION OF ALUMINUM CLAD SPENT NUCLEAR FUEL IN THE 70 TON CASK DURING TRANSFER FROM L AREA TO H-CANYON

    SciTech Connect (OSTI)

    Mickalonis, J.

    2014-06-01

    Aluminum-clad spent nuclear fuel will be transported for processing in the 70-ton nuclear fuel element cask from L Basin to H-canyon. During transport these fuels would be expected to experience high temperature aqueous corrosion from the residual L Basin water that will be present in the cask. Cladding corrosion losses during transport were calculated for material test reactor (MTR) and high flux isotope reactors (HFIR) fuels using literature and site information on aqueous corrosion at a range of time/temperature conditions. Calculations of the cladding corrosion loss were based on Arrhenius relationships developed for aluminum alloys typical of cladding material with the primary assumption that an adherent passive film does not form to retard the initial corrosion rate. For MTR fuels a cladding thickness loss of 33 % was found after 1 year in the cask with a maximum temperature of 260 {degrees}C. HFIR fuels showed a thickness loss of only 6% after 1 year at a maximum temperature of 180 {degrees}C. These losses are not expected to impact the overall confinement function of the aluminum cladding.

  8. Permanent draft genome sequence of Desulfurococcus mobilis type strain DSM 2161, a thermoacidophilic sulfur-reducing crenarchaeon isolated from acidic hot springs of Hveravellir, Iceland

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Susanti, Dwi; Johnson, Eric F.; Lapidus, Alla; Han, James; Reddy, T. B. K.; Pilay, Manoj; Ivanova, Natalia N.; Markowitz, Victor M.; Woyke, Tanja; Kyrpides, Nikos C.; et al

    2016-01-13

    Our report presents the permanent draft genome sequence of Desulfurococcus mobilis type strain DSM 2161, an obligate anaerobic hyperthermophilic crenarchaeon that was isolated from acidic hot springs in Hveravellir, Iceland. D. mobilis utilizes peptides as carbon and energy sources and reduces elemental sulfur to H2S. A metabolic construction derived from the draft genome identified putative pathways for peptide degradation and sulfur respiration in this archaeon. Existence of several hydrogenase genes in the genome supported previous findings that H2 is produced during the growth of D. mobilis in the absence of sulfur. Interestingly, genes encoding glucose transport and utilization systems alsomore » exist in the D. mobilis genome though this archaeon does not utilize carbohydrate for growth. The draft genome of D. mobilis provides an additional mean for comparative genomic analysis of desulfurococci. In addition, our analysis on the Average Nucleotide Identity between D. mobilis and Desulfurococcus mucosus suggested that these two desulfurococci are two different strains of the same species.« less

  9. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  10. Effects of ambient sulfur oxides and suspended particles on respiratory health of preadolescent children

    SciTech Connect (OSTI)

    Ware, J.H.; Ferris, B.G. Jr.; Dockery, D.W.; Spengler, J.D.; Stram, D.O.; Speizer, F.E.

    1986-05-01

    Reported here are the results from an ongoing study of outdoor air pollution and respiratory health of children living in six cities in the eastern and midwestern United States. The study enrolled 10,106 white preadolescent children between 1974 and 1977 in 3 successive annual visits to each city. Each child received a spirometric examination, and a parent completed a standard questionnaire. Of this cohort, 8,380 children were seen for a second examination 1 yr later. An air pollution monitoring program was begun in each community at about the time of the first examination. For this report, measurements of total suspended particulates (TSP), the sulfate fraction of TSP (TSO/sub 4/), and sulfur dioxide (SO2) concentrations at study-affiliated outdoor stations were combined with measurements at other public and private monitoring sites to create a record of TSP, TSO/sub 4/, and SO/sub 2/ concentrations in each of 9 air pollution regions during the 1-yr period preceding each examination and, for TSP, during each child's lifetime up to the time of testing. Across the 6 cities, frequency of cough was significantly associated with the average of 24-h mean concentrations of all 3 air pollutants during the year preceding the health examination (p less than 0.01). Rates of bronchitis and a composite measure of lower respiratory illness were significantly associated with average particulate concentrations (p less than 0.05). In analyses restricted to lifetime residents, these outcomes were significantly associated with measures of lifetime mean TSP concentration. Within the cities, however, temporal and spatial variation in air pollutant concentrations and illness and symptom rates were not positively associated.

  11. Catalysts for the selective oxidation of hydrogen sulfide to sulfur

    DOE Patents [OSTI]

    Srinivas, Girish; Bai, Chuansheng

    2000-08-08

    This invention provides catalysts for the oxidation of hydrogen sulfide. In particular, the invention provides catalysts for the partial oxidation of hydrogen sulfide to elemental sulfur and water. The catalytically active component of the catalyst comprises a mixture of metal oxides containing titanium oxide and one or more metal oxides which can be selected from the group of metal oxides or mixtures of metal oxides of transition metals or lanthanide metals. Preferred metal oxides for combination with TiO.sub.2 in the catalysts of this invention include oxides of V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Hf, Ta, W, Au, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Catalysts which comprise a homogeneous mixture of titanium oxide and niobium (Nb) oxide are also provided. A preferred method for preparing the precursor homogenous mixture of metal hydroxides is by coprecipitation of titanium hydroxide with one or more other selected metal hydroxides. Catalysts of this invention have improved activity and/or selectivity for elemental sulfur production. Further improvements of activity and/or selectivity can be obtained by introducing relatively low amounts (up to about 5 mol %)of a promoter metal oxide (preferably of metals other than titanium and that of the selected second metal oxide) into the homogeneous metal/titanium oxide catalysts of this invention.

  12. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-06-01

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2002 through March 31, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the seventh reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO3 removal results were presented in the semi

  13. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID REMOVAL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2004-01-01

    The objective of this project has been to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project was co-funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corporation, the Tennessee Valley Authority, and Carmeuse North America. Sulfuric acid controls are becoming of increased interest for coal-fired power generating units for a number of reasons. In particular, sulfuric acid can cause plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NOX control, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project tested the effectiveness of furnace injection of four different magnesium-based or dolomitic alkaline sorbents on full-scale utility boilers. These reagents were tested during one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide slurry byproduct from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercially available magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners. The other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm sorbent effectiveness over extended operation on two

  14. Table 14a. Average Electricity Prices, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Average Electricity Prices, Projected vs. Actual Projected Price in Constant Dollars (constant dollars, cents per kilowatt-hour in "dollar year" specific to each AEO) AEO $ Year 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 AEO 1994 1992 6.80 6.80 6.90 6.90 6.90 6.90 7.00 7.00 7.10 7.10 7.20 7.20 7.20 7.30 7.30 7.40 7.50 7.60 AEO 1995 1993 6.80 6.80 6.70 6.70 6.70 6.70 6.70 6.80 6.80 6.90 6.90 6.90 7.00 7.00 7.10 7.10 7.20

  15. High average power magnetic modulator for copper lasers

    SciTech Connect (OSTI)

    Cook, E.G.; Ball, D.G.; Birx, D.L.; Branum, J.D.; Peluso, S.E.; Langford, M.D.; Speer, R.D.; Sullivan, J.R.; Woods, P.G.

    1991-06-14

    Magnetic compression circuits show the promise of long life for operation at high average powers and high repetition rates. When the Atomic Vapor Laser Isotope Separation (AVLIS) Program at Lawrence Livermore National Laboratory needed new modulators to drive their higher power copper lasers in the Laser Demonstration Facility (LDF), existing technology using thyratron switched capacitor inversion circuits did not meet the goal for long lifetimes at the required power levels. We have demonstrated that magnetic compression circuits can achieve this goal. Improving thyratron lifetime is achieved by increasing the thyratron conduction time, thereby reducing the effect of cathode depletion. This paper describes a three stage magnetic modulator designed to provide a 60 kV pulse to a copper laser at a 4. 5 kHz repetition rate. This modulator operates at 34 kW input power and has exhibited MTBF of {approx}1000 hours when using thyratrons and even longer MTBFs with a series of stack of SCRs for the main switch. Within this paper, the electrical and mechanical designs for the magnetic compression circuits are discussed as are the important performance parameters of lifetime and jitter. Ancillary circuits such as the charge circuit and reset circuit are shown. 8 refs., 5 figs., 1 tab.

  16. Long-term average performance benefits of parabolic trough improvements

    SciTech Connect (OSTI)

    Gee, R.; Gaul, H.W.; Kearney, D.; Rabl, A.

    1980-03-01

    Improved parabolic trough concentrating collectors will result from better design, improved fabrication techniques, and the development and utilization of improved materials. The difficulty of achieving these improvements varies as does their potential for increasing parabolic trough performance. The purpose of this analysis is to quantify the relative merit of various technology advancements in improving the long-term average performance of parabolic trough concentrating collectors. The performance benefits of improvements are determined as a function of operating temperature for north-south, east-west, and polar mounted parabolic troughs. The results are presented graphically to allow a quick determination of the performance merits of particular improvements. Substantial annual energy gains are shown to be attainable. Of the improvements evaluated, the development of stable back-silvered glass reflective surfaces offers the largest performance gain for operating temperatures below 150/sup 0/C. Above 150/sup 0/C, the development of trough receivers that can maintain a vacuum is the most significant potential improvement. The reduction of concentrator slope errors also has a substantial performance benefit at high operating temperatures.

  17. Ensemble bayesian model averaging using markov chain Monte Carlo sampling

    SciTech Connect (OSTI)

    Vrugt, Jasper A; Diks, Cees G H; Clark, Martyn P

    2008-01-01

    Bayesian model averaging (BMA) has recently been proposed as a statistical method to calibrate forecast ensembles from numerical weather models. Successful implementation of BMA however, requires accurate estimates of the weights and variances of the individual competing models in the ensemble. In their seminal paper (Raftery etal. Mon Weather Rev 133: 1155-1174, 2(05)) has recommended the Expectation-Maximization (EM) algorithm for BMA model training, even though global convergence of this algorithm cannot be guaranteed. In this paper, we compare the performance of the EM algorithm and the recently developed Differential Evolution Adaptive Metropolis (DREAM) Markov Chain Monte Carlo (MCMC) algorithm for estimating the BMA weights and variances. Simulation experiments using 48-hour ensemble data of surface temperature and multi-model stream-flow forecasts show that both methods produce similar results, and that their performance is unaffected by the length of the training data set. However, MCMC simulation with DREAM is capable of efficiently handling a wide variety of BMA predictive distributions, and provides useful information about the uncertainty associated with the estimated BMA weights and variances.

  18. Fact #615: March 22, 2010 Average Vehicle Trip Length | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 5: March 22, 2010 Average Vehicle Trip Length Fact #615: March 22, 2010 Average Vehicle Trip Length According to the latest National Household Travel Survey, the average trip length grew to over 10 miles in 2009, just slightly over the 9.9 mile average in 2001. Trips to work in 2009 increased to an average of 12.6 miles. The average trip length has been growing each survey year since the lowest average in 1983. Average Vehicle Trip Length, 1969-2009 Graph showing the average vehicle

  19. Production of low sulfur binder pitich from high-sulfur Illinois coals. Quarterly report, 1 March 1995--31 May 1995

    SciTech Connect (OSTI)

    Knight, R.A.

    1995-12-31

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. Previously, flash thermocracking (FTC) was used to successfully upgrade the properties of mild gasification pitch, yielding a suitable blending stock for use as a binder in the production of carbon electrodes for the aluminum industry. However, in pitches from high-sulfur (4%) Illinois coal, the pitch sulfur content (2%) was still higher than preferred. In this project two approaches to sulfur reduction are being explored in conjunction with FTC: (1) the use of a moderate-sulfur (1.2%) Illinois coal as mild gasification feedstock, and (2) direct biodesulfurization of the liquids from high-sulfur coal prior to FTC. In Case 1, the liquids are being produced by mild gasification of IBC-109 coal in a bench-scale fluidized-bed reactor, followed by distillation to isolate the crude pitch. In Case 2, biodesulfurization with Rhodococcus Rhodochrous IGTS8 biocatalyst is being performed on crude pitch obtained from Illinois No. 6 coal tests conducted in the IGT MILDGAS PRU in 1990. Following preparation of the crude pitches, pitch upgrading experiments are being conducted in a continuous FTC reactor constructed in previous ICCI-sponsored studies. This quarter, mild gasification of IBC-109 coal was completed, producing 450 g of coal liquids, which were then distilled to recover 329 g of Case 1 crude pitch. Next month, the pitch will be subjected to FTC treatment and evaluated. Biodesulfurization experiments were performed on Case 2 pitch dispersed in l-undecanol, resulting in sulfur reductions of 15.1 to 21.4%. This was marginally lower than the 24.8% desulfurization obtained in l-dodecanol, but separation of pitch from the dispersant was facilitated by the greater volatility of l-undecanol.

  20. Assessing historical global sulfur emission patterns for the period 1850--1990

    SciTech Connect (OSTI)

    Lefohn, A.S.; Husar, J.D.; Husar, R.B.; Brimblecombe, P.

    1996-07-19

    Anthropogenic sulfur dioxide emissions from energy-producing and metal production activities have become an important factor in better understanding the relationship between humans and the environment. Concerns about (1) acid rain effects on the environment and (2) anthropogenic aerosols affecting possible global change have prompted interest in the transformation and fate of sulfur in the environment. One step in assessing the importance of sulfur emissions is the development of a reliable regional emission inventory of sulfur as a function of time. The objective of this research effort was to create a homogeneous database for historical sulfur emission estimates for the world. The time from 1850--1990 was selected to include the period of industrialization form the time the main production of fuels and minerals began until the most recent year for which complete production data exist. This research effort attempts to correct some of the deficiencies associated with previous global sulfur emission estimates by (1) identifying those production activities that resulted in sulfur emissions by country and (2) calculating historical emission trends by country across years. An important component of this study was the comparison of the sulfur emission results with those of previous studies.

  1. Use of selective oxidation of petroleum residue for production of low-sulfur coke

    SciTech Connect (OSTI)

    Hairudinov, I.R.; Kul`chitskaya, O.V.; Imashev, U.B.

    1995-12-10

    The chemical nature of liquid-phase oxidation of sulfurous petroleum residues by cumene hydroperoxide was studied by a tracer technique. Sulfur compounds are selectively oxidized in the presence of catalytic additives of molybdenum salts. Desulfurization of distillate products and coke during coking of preoxidized raw materials was revealed.

  2. Adsorbed sulfur-gas methods for both near-surface exploration and downhole logging

    SciTech Connect (OSTI)

    Farwell, S.O.; Barinaga, C.J.; Dolenc, M.R.; Farwell, G.H.

    1986-08-01

    The use of sulfur-containing gases in petroleum exploration is supported by (1) the idea that sulfur may play a role in petroleum genesis, (2) the corresponding existence of sulfur-containing compounds in petroleum and the potential for vertical migration of the low-molecular-weight sulfur species from these reservoirs, (3) the production of H/sub 2/S by anaerobic microorganism populations that develop in the subsurface areas overlying petroleum reservoirs due to the concomitant supply of hydrocarbon nutrients, (4) the recent discovery of near-surface accumulations of pyrite and marcasite as the source of induction potential anomalies over certain fields, and (5) the strong adsorptive affinities of sulfur gases to solid surfaces, which enhance both the concentration and localization of such sulfur-expressed anomalies. During the past 3 years, numerous near-surface soil samples and well cuttings from the Utah-Wyoming Overthrust belt have been analyzed for adsorbed sulfur-gas content by two novel analytical techniques: thermal desorption/metal foil collection/flash desorption/sulfur-selective detection (TD/MFC/FD/SSD) and thermal desorption/cryogenic preconcentration/high-resolution-gas chromatography/optimized-flame photometry (TD/CP/HRGC/OFP).

  3. Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sulfur Dioxide on Lean NOx Trap Catalysts Impact of Sulfur Dioxide on Lean NOx Trap Catalysts 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of New Mexico 2004_deer_hammache.pdf (249.2 KB) More Documents & Publications CLEERS Aftertreatment Modeling and Analysis CLEERS Aftertreatment Modeling and Analysis An Improvement of Diesel PM and NOx Reduction System

  4. Determination of total biogenic sulfur gases by filter/flash vaporization/flame photometry

    SciTech Connect (OSTI)

    Farwell, S.O.; Liebowitz, D.P.; Kagel, R.A.; Adams, D.F.

    1980-12-01

    Complete conversion of H/sub 2/S, COS, CH/sub 3/SH, CH/sub 3/SCH/sub 3/, CS/sub 2/, and CH/sub 3/SSCH/sub 3/ to SO/sub 2/ has been shown to occur in a quartz tube held at a furnace temperature of 1050/sup 0/C for sample air flows from 30 mL/min to 2.8 L/min. The resultant SO/sub 2/-containing air flow is passed through an inline, precleaned Gelman Spectrograde filter which collects an average of 1.5 +- 0.3 ..mu..g of S/47 mm filter prior to SO/sub 2/ breakthrough. The sulfur collected on the filters is extracted with a recovery of 100 +- 3%. Final quantitative determinations of the sulfur in the filter extracts are performed via the flash vaporization/flame photometric (FV/FPD) technique using platinum boats. Equivalent FV/FPD linear responses were observed for H/sub 2/SO/sub 4/, Na/sub 2/SO/sub 4/, K/sub 2/SO/sub 4/, and (NH/sub 4/)/sub 2/SO/sub 4/ standards in the range of 0.4 to 12 ng of S. Repeated analyses of sulfate standards showed a relative standard deviation (RSD) = +-7.0%. Experimental results obtained for NaHCO/sub 3/, Na/sub 2/CO/sub 3/, NaOH, NaCl, KHCO/sub 3/, K/sub 2/CO/sub 3/, KOH, NH/sub 4/HCO/sub 3/, (NH/sub 4/)/sub 2/CO/sub 3/, NH/sub 3/(aq), FeCl/sub 3/, MnCl/sub 2/, and Na/sub 2/HgCl/sub 4/ as chemical impregnants in glass fiber filters for SO/sub 2/ collection and their compatibility with the FV/FPD system are also described.

  5. Toxicology Studies on Lewisite and Sulfur Mustard Agents: Subchronic Toxicity of Sulfur Mustard (HD) In Rats Final Report

    SciTech Connect (OSTI)

    Sasser, L. B.; Miller, R. A.; Kalkwarf, D, R.; Buschbom, R. L.; Cushing, J. A.

    1989-06-30

    Occupational health standards have not been established for sulfur mustard [bis(2- chlorethyl)-sulfide], a strong alkylating agent with known mutagenic properties. Seventytwo Sprague-Dawley rats of each sex, 6-7 weeks old, were divided into six groups (12/group/ sex) and gavaged with either 0, 0.003 , 0.01 , 0.03 , 0.1 or 0.3 mg/kg of sulfur mustard in sesame oil 5 days/week for 13 weeks. No dose-related mortality was observed. A significant decrease (P ( 0.05) in body weight was observed in both sexes of rats only in the 0.3 mg/kg group. Hematological evaluations and clinical chemistry measurements found no consistent treatment-related effects at the doses studied. The only treatment-related lesion associated with gavage exposure upon histopathologic evaluation was epithelial hyperplasia of the forestomach of both sexes at 0.3 mg/kg and males at 0.1 mg/kg. The hyperplastic change was minimal and characterized by cellular disorganization of the basilar layer, an apparent increase in mitotic activity of the basilar epithelial cells, and thickening of the epithelial layer due to the apparent increase in cellularity. The estimated NOEL for HD in this 90-day study is 0.1 mg/kg/day when administered orally.

  6. Investigation of the sulfur and lithium to sulfur ratio threshold in stress corrosion cracking of sensitized alloy 600 in borated thiosulfate solution

    SciTech Connect (OSTI)

    Bandy, R.; Kelly, K.

    1984-07-01

    The stress corrosion cracking of sensitized Alloy 600 was investigated in aerated solutions of sodium thiosulfate generally containing 1.3% boric acid. The aim of the investigation, among others, was to determine the existence, if any, of a threshold level of sulfur, and lithium to sulfur ratio governing the SCC. Specimens were first solution annealed at 1135/sup 0/C for 45 minutes, water quenched, and then sensitized at 621/sup 0/C for 18 hours. Reverse U-bends were tested at room temperature, whereas slow strain rate and constant load tests were performed at 80/sup 0/C. All tests were performed in solutions open to the atmosphere. The results indicate that in the borated thiosulfate solution containing 7 ppM sulfur, 5 ppM lithium as lithium hydroxide is sufficient to inhibit SCC in U-bends. The occurrence of inhibition seems to correlate to the rapid increase of pH and conductivity of the solution as a result of the lithium hydroxide addition. In the slow strain rate tests in the borated solution containing 0.7 ppM lithium as lithium hydroxide, significant stress corrosion cracking is observed at a sulfur level of 30 ppb, i.e., a lithium to sulfur ratio of 23. In a parallel test in 30 ppb sulfur level but without any lithium hydroxide, the stress corrosion cracking is more severe than that in the lithiated environment, thus implying that lithium hydroxide plays some role in the stress corrosion cracking inhibition.

  7. Production of low-sulfur binder pitch from high-sulfur Illinois coals. Technical report, December 1, 1994--February 28, 1995

    SciTech Connect (OSTI)

    Knight, R.A.

    1996-03-01

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. In previous ICCI projects at IGT, flash thermocracking (FTC) was used to successfully upgrade the properties of mild gasification pitch, yielding a suitable blending stock for use as a binder in the production of carbon electrodes for the aluminum industry. However, in pitches from high-sulfur (4%) Illinois coal, the pitch sulfur content is still unacceptably high at 2%. In this project, two approaches to sulfur reduction are being explored in conjunction with FTC: (1) the use of conventionally cleaned coal with low ({approximately}1%) sulfur as a mild gasification feedstock, and (2) direct biodesulfurization of the liquids prior to FTC. In Case 1, the crude pitch is being produced by mild gasification of IBC-109 coal in an existing IGT bench-scale reactor, followed by distillation to isolate the crude pitch. In Case 2, the crude pitch for biodesulfurization was obtained from Illinois No. 6 coal tests conducted in the IGT mild gasification PRU in 1990. Biodesulfurization is to be performed by contacting the pitch with Rhodococcus Rhodochrous IGTS8 biocatalyst. Following preparation of the crude pitches, pitch upgrading experiments are to be conducted in a continuous FTC reactor constructed in previous ICCI-sponsored studies. The finished pitch is then characterized for physical and chemical properties (density, softening point, QI, TI, coking value, and elemental composition), and compared to typical specifications for binder pitches.

  8. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  9. Simultaneous removal of nitrogen oxides and sulfur oxides from combustion gases

    DOE Patents [OSTI]

    Clay, David T.; Lynn, Scott

    1976-10-19

    A process for the simultaneous removal of sulfur oxides and nitrogen oxides from power plant stack gases comprising contacting the stack gases with a supported iron oxide catalyst/absorbent in the presence of sufficient reducing agent selected from the group consisting of carbon monoxide, hydrogen, and mixtures thereof, to provide a net reducing atmosphere in the SO.sub.x /NO.sub.x removal zone. The sulfur oxides are removed by absorption substantially as iron sulfide, and nitrogen oxides are removed by catalytic reduction to nitrogen and ammonia. The spent iron oxide catalyst/absorbent is regenerated by oxidation and is recycled to the contacting zone. Sulfur dioxide is also produced during regeneration and can be utilized in the production of sulfuric acid and/or sulfur.

  10. Method of forming and starting a sodium sulfur battery

    DOE Patents [OSTI]

    Paquette, David G.

    1981-01-01

    A method of forming a sodium sulfur battery and of starting the reactive capability of that battery when heated to a temperature suitable for battery operation is disclosed. An anodic reaction zone is constructed in a manner that sodium is hermetically sealed therein, part of the hermetic seal including fusible material which closes up openings through the container of the anodic reaction zone. The hermetically sealed anodic reaction zone is assembled under normal atmospheric conditions with a suitable cathodic reaction zone and a cation-permeable barrier. When the entire battery is heated to an operational temperature, the fusible material of the hermetically sealed anodic reaction zone is fused, thereby allowing molten sodium to flow from the anodic reaction zone into reactive engagement with the cation-permeable barrier.

  11. Sulfur-Iodine Integrated Lab Scale Experiment Development

    SciTech Connect (OSTI)

    Russ, Ben

    2011-05-27

    The sulfur-iodine (SI) cycle was deermined to be the best cycle for coupling to a high temperature reactor (HTR) because of its high efficiency and potential for further improvement. The Japanese Atomic Energy Agency (JAEA) has also selected the SI process for further development and has successfully completed bench-scale demonstrations of the SI process at atmospheric pressure. JEA also plans to proceed with pilot-scale demonstrations of the SI process and eventually plans to couple an SI demonstration plant to its High Temperature Test Reactor (HHTR). As part of an international NERI project, GA, SNL, and the Frech Commissariat L'Energie Atomique performed laboratory-scale demonstrations of the SI process at prototypical temperatures and pressures. This demonstration was performed at GA in San Diego, CA and concluded in April 2009.

  12. Process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal sulfide sorbents

    DOE Patents [OSTI]

    Ayala, Raul E.; Gal, Eli

    1995-01-01

    A process and apparatus for generating elemental sulfur and re-usable metal oxide from spent metal-sulfur compound. Spent metal-sulfur compound is regenerated to re-usable metal oxide by moving a bed of spent metal-sulfur compound progressively through a single regeneration vessel having a first and second regeneration stage and a third cooling and purging stage. The regeneration is carried out and elemental sulfur is generated in the first stage by introducing a first gas of sulfur dioxide which contains oxygen at a concentration less than the stoichiometric amount required for complete oxidation of the spent metal-sulfur compound. A second gas containing sulfur dioxide and excess oxygen at a concentration sufficient for complete oxidation of the partially spent metal-sulfur compound, is introduced into the second regeneration stage. Gaseous sulfur formed in the first regeneration stage is removed prior to introducing the second gas into the second regeneration stage. An oxygen-containing gas is introduced into the third cooling and purging stage. Except for the gaseous sulfur removed from the first stage, the combined gases derived from the regeneration stages which are generally rich in sulfur dioxide and lean in oxygen, are removed from the regenerator as an off-gas and recycled as the first and second gas into the regenerator. Oxygen concentration is controlled by adding air, oxygen-enriched air or pure oxygen to the recycled off-gas.

  13. Fact #744: September 10, 2012 Average New Light Vehicle Price Grows Faster

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    than Average Used Light Vehicle Price | Department of Energy 4: September 10, 2012 Average New Light Vehicle Price Grows Faster than Average Used Light Vehicle Price Fact #744: September 10, 2012 Average New Light Vehicle Price Grows Faster than Average Used Light Vehicle Price In 2011 the average used light vehicle price was 36% higher than in 1990, while the average new light vehicle price was 67% higher than it was in 1990. The average price of a used vehicle had been between $6,000 and

  14. Ultra-low Sulfur Reduction Emission Control Device/Development of an On-board Fuel Sulfur Trap

    SciTech Connect (OSTI)

    Rohrbach, Ron; Barron, Ann

    2008-07-31

    Honeywell has completed working on a multiyear program to develop and demonstrate proof-of-concept for an 'on-vehicle' desulfurization fuel filter for both light duty and heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NOx adsorbers. The NOx adsorber may be required to meet the proposed new EPA Tier II and '2007-Rule' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters was also examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. In the second phase of the program a light duty diesel engine test was also demonstrated. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consisted of four phases. Phase I focused on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II concentrated on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III studied life cycle and regeneration options for the spent filter. Phase IV focused on efficacy and benefits in the desulfation steps of a NOx adsorber on both a heavy and light duty engine. The project team included a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer

  15. NONEQUILIBRIUM SULFUR CAPTURE & RETENTION IN AN AIR COOLED SLAGGING COAL COMBUSTOR

    SciTech Connect (OSTI)

    Bert Zauderer

    2003-04-21

    Calcium oxide injected in a slagging combustor reacts with the sulfur from coal combustion to form sulfur-bearing particles. The reacted particles impact and melt in the liquid slag layer on the combustor wall by the centrifugal force of the swirling combustion gases. Due to the low solubility of sulfur in slag, it must be rapidly drained from the combustor to limit sulfur gas re-evolution. Prior analyses and laboratory scale data indicated that for Coal Tech's 20 MMBtu/hour, air-cooled, slagging coal combustor slag mass flow rates in excess of 400 lb/hr should limit sulfur re-evolution. The objective of this 42-month project was to validate this sulfur-in-slag model in a group of combustor tests. A total of 36 days of testing on the combustor were completed during the period of performance of this project. This was more that double the 16 test days that were required in the original work statement. The extra tests were made possible by cost saving innovations that were made in the operation of the combustor test facility and in additional investment of Coal Tech resources in the test effort. The original project plan called for two groups of tests. The first group of tests involved the injection of calcium sulfate particles in the form of gypsum or plaster of Paris with the coal into the 20 MMBtu/hour-combustor. The second group of tests consisted of the entire two-step process, in which lime or limestone is co-injected with coal and reacts with the sulfur gas released during combustion to form calcium sulfate particles that impact and dissolve in the slag layer. Since this sulfur capture process has been validated in numerous prior tests in this combustor, the primary effort in the present project was on achieving the high slag flow rates needed to retain the sulfur in the slag.

  16. Toward Understanding the Effect of Low-Activity Waste Glass Composition on Sulfur Solubility

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Muller, Isabelle S.; Piepel, Gregory F.; Kruger, Albert A.

    2014-10-01

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis). If the amount of sulfur exceeds its tolerance level a molten salt will accumulate and upset melter operations and potentially shorten melter useful life. Therefore relatively conservative limits have been placed on sulfur loading in melter feed which in-turn significantly impacts the amount of glass that will be produced, in particular at the Hanford site. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 312 individual glass compositions. This model was shown to well represent the data, accounting for over 80% of the variation in data and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed based on 19 scaled melter tests. The model is appropriate for control of waste glass processing which includes uncertainty quantification. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5 ? TiO2 < CaO < P2O5 ? ZnO. The components that most decrease sulfur solubility are Cl > Cr2O3 > SiO2 ? ZrO2 > Al2O3.

  17. Emission of biogenic sulfur gases from Chinese paddy soil and rice plant

    SciTech Connect (OSTI)

    Zhen Yang [Nanjing Univ. of Science and Technology (China); Li Kong [Nanjing Agricultural Univ. (China)

    1996-12-31

    Biogenic sulfur gases emitted from terrestrial ecosystem may play in important role in global sulfur cycle and have a profound influence on global climate change. But very little is known concerning emissions from paddy soil and rice plant, which are abundant in many parts of the world. As a big agricultural country, this is about 33 million hectare rice planted in China. With laboratory incubation and closed chamber method in the field, the biogenic sulfur gases emitted from Chinese paddy soil and rice plant were detected in both conditions: hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), methyl mercaptan (MSH), carbon disulfide (CS{sub 2}), dimethyl sulfide (DMS) and dimethyl disulfide (DMDS). Among which, DMS was predominant part of sulfur emission. Emission of sulfur gases from different paddy field exhibit high spatial and temporal variability. The application of fertilizer and organic manure, total sulfur content in wetland, air temperature were positively correlated to the emission of volatile sulfur gases from paddy soil. Diurnal and seasonal variation of total volatile sulfur gases and DMS indicate that their emissions were greatly influenced by the activity of the rice plant. The annual emission of total volatile sulfur gases, from Nanjing paddy field is ranged from 4.0 to 9.5 mg S m{sup -2}yr{sup -1}, that of DMS is ranged from 3.1 to 6.5 mg S m{sup -2}yr{sup -1}. Rice plant could absorb COS gas, that may be one of the sinks of COS.

  18. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  19. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, R.P.; Winterbottom, W.L.; Wroblowa, H.S.

    1987-03-10

    This specification is directed to a method of making a current collector for a sodium/sulfur battery. The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500--1,000 angstroms. 2 figs.

  20. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, Ragnar P.; Winterbottom, Walter L.; Wroblowa, Halina S.

    1987-01-01

    This specification is directed to a method of making a current collector (14) for a sodium/sulfur battery (10). The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material (16) formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500-1000 angstroms.

  1. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  2. Update on Transition to Ultra-Low-Sulfur Diesel Fuel (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    On November 8, 2005, the Environmental Protection Agency (EPA) Administrator signed a direct final rule that will shift the retail compliance date for offering ultra-low sulfur diesel (ULSD) for highway use from September 1, 2006, to October 15, 2006. The change will allow more time for retail outlets and terminals to comply with the new 15 parts per million (ppm) sulfur standard, providing time for entities in the diesel fuel distribution system to flush higher sulfur fuel out of the system during the transition. Terminals will have until September 1, 2006, to complete their transitions to ULSD. The previous deadline was July 15, 2006.

  3. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E.; Jalan, Vinod M.

    1984-01-01

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  4. Fact #614: March 15, 2010 Average Age of Household Vehicles | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 4: March 15, 2010 Average Age of Household Vehicles Fact #614: March 15, 2010 Average Age of Household Vehicles The average age of household vehicles has increased from 6.6 years in 1977 to 9.2 years in 2009. Pickup trucks have the oldest average age in every year listed. Sport utility vehicles (SUVs), first reported in the 1995 survey, have the youngest average age. Average Vehicle Age by Vehicle Type Graph showing the average vehicle age by type (car, van, pickup, SUV, all household

  5. Strontium and sulfur isotope study of well-preserved Permian anhydrite, Palo Duro basin, Texas

    SciTech Connect (OSTI)

    Leary, D.A. )

    1990-05-01

    The {delta}{sup 34}S, {sup 87}Sr/{sup 86}Sr ratio, and strontium concentrations for 50 well-preserved samples of Permian marine anhydrite have been determined. The samples were collected from two continuous cores drilled through cyclic Permian evaporites, The Department of Energy drilled the samples in its search for a permanent storage facility for high-level nuclear waste. Primary depositional fabrics (selenite pseudomorphs) and high strontium concentrations (average 1,850 ppm), in association with published bromide and fluid inclusion data from associated halite, suggest primary seawater {sup 87}Sr/{sup 86}Sr ratios may be recorded in many of the samples. The general shape of the {sup 87}Sr/{sup 86}Sr ratio curve through the Permian is in accord with previously published observations. However, the increased stratigraphic detail from this unique set of cores constrains the abrupt charge in {sup 87}Sr/{sup 86}Sr during the Permian at a precision previously available only in Deep Sea Drilling Project material. Interpretation of the more complex portions of the curve is limited by poor biostratigraphic control, the specter of provincial early diagenetic effects, and interpretation of the time significance of hiatal surfaces in cyclic strata. Age relationships are constrained by a K-Ar date on an interbedded volcanic ash in the Ochoan strata, and fusulinid age determinations of a well-documented regional transgression during the earliest Guadalupe. Sulfur isotopes yield typical Permian values of 12{per thousand} during the marine portion of the basin fill phase, and abruptly shift to 10{per thousand} in those cycles with a significant component of siliciclastic sediment.

  6. Fact #671: April 18, 2011 Average Truck Speeds | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1: April 18, 2011 Average Truck Speeds Fact #671: April 18, 2011 Average Truck Speeds The Federal Highway Administration studies traffic volume and flow on major truck routes by tracking more than 500,000 trucks. The average speed of trucks on selected interstate highways is between 50 and 60 miles per hour (mph). The average operating speed of trucks is typically below 55 mph in major urban areas, border crossings, and in mountainous terrain. The difference in average speed between peak traffic

  7. Complexation of Mercury(II) in Soil Organic Matter: EXAFS Evidence for Linear Two-Coordination with Reduced Sulfur Groups

    SciTech Connect (OSTI)

    Skyllberg,U.; Bloom, P.; Qian, J.; Lin, C.; Bleam, W.

    2006-01-01

    The chemical speciation of inorganic mercury (Hg) is to a great extent controlling biologically mediated processes, such as mercury methylation, in soils, sediments, and surface waters. Of utmost importance are complexation reactions with functional groups of natural organic matter (NOM), indirectly determining concentrations of bioavailable, inorganic Hg species. Two previous extended X-ray absorption fine structure (EXAFS) spectroscopic studies have revealed that reduced organic sulfur (S) and oxygen/nitrogen (O/N) groups are involved in the complexation of Hg(II) to humic substances extracted from organic soils. In this work, covering intact organic soils and extending to much lower concentrations of Hg than before, we show that Hg is complexed by two reduced organic S groups (likely thiols) at a distance of 2.33 Angstroms in a linear configuration. Furthermore, a third reduced S (likely an organic sulfide) was indicated to contribute with a weaker second shell attraction at a distance of 2.92-3.08 Angstroms. When all high-affinity S sites, corresponding to 20-30% of total reduced organic S, were saturated, a structure involving one carbonyl-O or amino-N at 2.07 Angstroms and one carboxyl-O at 2.84 Angstroms in the first shell, and two second shell C atoms at an average distance of 3.14 Angstroms, gave the best fit to data. Similar results were obtained for humic acid extracted from an organic wetland soil. We conclude that models that are in current use to describe the biogeochemistry of mercury and to calculate thermodynamic processes need to include a two-coordinated complexation of Hg(II) to reduced organic sulfur groups in NOM in soils and waters.

  8. Sulfur dioxide emissions from primary copper smelters in the western US

    SciTech Connect (OSTI)

    Mangeng, C.A.; Mead, R.W.

    1980-01-01

    The body of information presented is directed to environmental scientists and policy makers without chemical or metallurgical engineering backgrounds. This paper addresses the problems of reducing sulfur dioxide emissions from primary copper smelters in the western United States and projects the future impact of emissions within a framework of legal, technological, and economic considerations. Methodology used to calculate historical sulfur dioxide emissions is described. Sulfur dioxide emission regulations are outlined as they apply to primary copper smelters. A discussion of available sulfur dioxide control technology and copper smelting processes summarizes the technological and economic problems of reducing copper smelter emissions. Based upon these technological and economic considerations, projections of smelter emissions indicate that compliance with existing legislative requirements will be achieved by 1990. Three smelters are projected to close by 1985.

  9. Diesel Fuel Sulfur Effects on the Performance of Diesel Oxidation Catalysts

    SciTech Connect (OSTI)

    Whitacre, Shawn D.

    2000-08-20

    Research focus: - Impact of sulfur on: Catalyst performance; Short term catalyst durability. This presentation summarizes results from fresh catalyst performance evaluations - WVU contracted to conduct DOC and Lean NOx catalyst testing for DECSE DECSE program. (experimental details discussed previously)

  10. First-Principles Study of Redox End-Members in Li-Sulfur Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First-Principles Study of Redox End-Members in Li-Sulfur Batteries Images for Redox ... and surface characteristics of solid-phase redox end-members in Li-S batteries. ...

  11. Demand, Supply, and Price Outlook for Low-Sulfur Diesel Fuel

    Reports and Publications (EIA)

    1993-01-01

    The Clean Air Act Amendments of 1990 established a new, sharply lower standard for the maximum sulfur content of on-highway diesel fuel, to take effect October 1, 1993.

  12. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    57.8 42.0 See footnotes at end of table. 200 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  13. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    62.6 47.4 See footnotes at end of table. 200 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  14. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    51.8 See footnotes at end of table. 242 Energy Information Administration Petroleum Marketing Annual 1995 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  15. Sulfur tolerant highly durable CO.sub.2 sorbents (Patent) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Sulfur tolerant highly durable CO.sub.2 sorbents A sorbent for the capture of carbon dioxide from a gas stream is provided, the sorbent ...

  16. Combining automatic titration of total iron and sulfur in thermal battery materials

    SciTech Connect (OSTI)

    Marley, N.A.

    1986-05-28

    Optimal thermal battery performance requires careful control of the iron disulfide content in the catholyte mixture. Previously, the iron and sulfur content of battery materials was determined separately, each requiring a lengthy sample preparation and clean up procedure. A new method has been developed which allows both determinations to be made on the same sample following a simple dissolution procedure. Sample preparation requires oxidation and dissolution with nitric acid followed by dissolution in hydrochloric acid. Iron and sulfur are then determined on sample aliquots by automatic titration. The implementation of this combined procedure for the determination of iron and sulfur by automatic titration has resulted in a substantial reduction in the analysis time. Since sample aliquots are used for each determination, the need to repeat a sample for analysis is rare, improving both the analytical efficiency and sample throughput. Results obtained for sulfur show an improved precision.

  17. Low-quality natural gas sulfur removal/recovery

    SciTech Connect (OSTI)

    Damon, D.A.; Siwajek, L.A.; Klint, B.W.

    1993-12-31

    Low quality natural gas processing with the integrated CFZ/CNG Claus process is feasible for low quality natural gas containing 10% or more of CO{sub 2}, and any amount of H{sub 2}S. The CNG Claus process requires a minimum CO{sub 2} partial pressure in the feed gas of about 100 psia (15% CO{sub 2} for a 700 psia feed gas) and also can handle any amount of H{sub 2}S. The process is well suited for handling a variety of trace contaminants usually associated with low quality natural gas and Claus sulfur recovery. The integrated process can produce high pressure carbon dioxide at purities required by end use markets, including food grade CO{sub 2}. The ability to economically co-produce high pressure CO{sub 2} as a commodity with significant revenue potential frees process economic viability from total reliance on pipeline gas, and extends the range of process applicability to low quality gases with relatively low methane content. Gases with high acid gas content and high CO{sub 2} to H{sub 2}S ratios can be economically processed by the CFZ/CNG Claus and CNG Claus processes. The large energy requirements for regeneration make chemical solvent processing prohibitive. The cost of Selexol physical solvent processing of the LaBarge gas is significantly greater than the CNG/CNG Claus and CNG Claus processes.

  18. Sulfur gas sensor using a calcium fluoride solid electrolyte

    SciTech Connect (OSTI)

    Toniguchi, M.; Wakihara, M.; Uchida, T.; Hirakawa, K.; Nii, J.

    1988-01-01

    The sulfur gas potentials in the H/sub 2/S + H/sub 2/ buffer gases were measured by a galvanic cell Ps/sub 2/(g),Au(Pt)/(MoS/sub 2/ + CaS)/CaF/sub 2//(Cu + Cu/sub 2/S + CaS)/Au(Pt) in the temperature range from 650/sup 0/ to 950/sup 0/C and Ps/sub 2/ region from 10/sup -2/ to 10/sup -10/ atm. A quick response time (within 5 to 10 min) in emf with the change of Ps/sub 2/ at a given temperature was observed by placing a MoS/sub 2/ and CaS mixed pellet auxiliary electrode at the bottom of the cylindrical single-crystal CaF/sub 2/ electrolyte. The observed emf's agreed well with with those calculated from the Nernst equation. Using this sensor, Ps/sub 2/ values in the SO/sub 2/ + H/sub 2/ + H/sub 2/S gas system were also evaluated from the measured emf at 827/sup 0/C and were found to be in close agreement with those calculated from the thermochemical tables.

  19. Sulfur dioxide-induced chronic bronchitis in beagle dogs

    SciTech Connect (OSTI)

    Greene, S.A.; Wolff, R.K.; Hahn, F.F.; Henderson, R.F.; Mauderly, J.L.; Lundgren, D.L.

    1984-01-01

    This study was done to produce a model of chronic bronchitis. Twelve beagle dogs were exposed to 500 ppm sulfur dioxide (SO/sub 2/) for 2 h/d, 5d/wk for 21 wk and 4 dogs were sham-exposed to filtered ambient air for the same period. Exposure effects were evaluated by periodically examining the dogs using chest radiographs, pulmonary function, tracheal mucous clearance, and the cellular and soluble components of bronchopulmonary lavage fluids. Dogs were serially sacrificed after 13 and 21 wk of exposure and after 6 and 14 wk of recovery. Clinical signs produced in the SO/sub 2/-exposed dogs included mucoid nasal discharge, productive cough, moist rales on auscultation, tonsilitis, and conjunctivitis. Chest radiographs revealed mild peribronchiolar thickening. Histopathology, tracheal mucous clearance measurements, and lavage cytology were consistent with a diagnosis of chronic bronchitis. It is concluded that repeated exposure to 500 ppm SO/sub 2/ for 21 wk produced chronic bronchitis in the beagle dog. Complete recovery occurred within 5 wk following cessation of SO/sub 2/ exposure. 43 references, 2 figures, 2 tables.

  20. Low Temperature Sodium-Sulfur Grid Storage and EV Battery - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Low Temperature Sodium-Sulfur Grid Storage and EV Battery Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing Summary Berkeley Lab researcher Gao Liu has developed an innovative design for a battery, made primarily of sodium and sulfur, that

  1. Direct Observation of the Redistribution of Sulfur and Polysufides in Li-S

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries by In Situ X-Ray Fluorescence Microscopy - Joint Center for Energy Storage Research March 30, 2015, Research Highlights Direct Observation of the Redistribution of Sulfur and Polysufides in Li-S Batteries by In Situ X-Ray Fluorescence Microscopy (Top) The morphology and chemical state changes of a sulfur electrode were observed in real time throughout an entire first electro-chemical cycle. The contamination of polysulfides on the Li anode was also investigated. (Bottom) A

  2. Development of Efficient Flowsheet and Transient Modeling for Nuclear Heat Coupled Sulfur Iodine Cyclefor Hydrogen Production

    SciTech Connect (OSTI)

    Shripad T. Revankar; Nicholas R. Brown; Cheikhou Kane; Seungmin Oh

    2010-05-01

    The realization of the hydrogen as an energy carrier for future power sources relies on a practical method of producing hydrogen in large scale with no emission of green house gases. Hydrogen is an energy carrier which can be produced by a thermochemical water splitting process. The Sulfur-Iodine (SI) process is an example of a water splitting method using iodine and sulfur as recycling agents.

  3. Fitting the Lithium-Sulfur Battery with a New Membrane - Joint Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Research October 22, 2015, Accomplishments Fitting the Lithium-Sulfur Battery with a New Membrane The lithium-sulfur battery has higher energy storage capacity and lower cost than lithium ion. But there is a serious stumbling block. Polysulfides form in the cathode during battery cycling and pass through the membrane to contaminate the lithium metal anode. This results in a rapid decline in performance. JCESR researchers appear to have found a solution to the problem - the

  4. Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control

    DOE Patents [OSTI]

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2011-03-15

    Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.

  5. Interaction of CuS and sulfur in Li-S battery system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, undermore » a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.« less

  6. Interaction of CuS and sulfur in Li-S battery system

    SciTech Connect (OSTI)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, under a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.

  7. Sulfur oxidation to sulfate coupled with electron transfer to electrodes by Desulfuromonas strain TZ1

    SciTech Connect (OSTI)

    Zhang, T; Bain, TS; Barlett, MA; Dar, SA; Snoeyenbos-West, OL; Nevin, KP; Lovley, DR

    2014-01-02

    Microbial oxidation of elemental sulfur with an electrode serving as the electron acceptor is of interest because this may play an important role in the recovery of electrons from sulfidic wastes and for current production in marine benthic microbial fuel cells. Enrichments initiated with a marine sediment inoculum, with elemental sulfur as the electron donor and a positively poised (+300 mV versus Ag/AgCl) anode as the electron acceptor, yielded an anode biofilm with a diversity of micro-organisms, including Thiobacillus, Sulfurimonas, Pseudomonas, Clostridium and Desulfuromonas species. Further enrichment of the anode biofilm inoculum in medium with elemental sulfur as the electron donor and Fe(III) oxide as the electron acceptor, followed by isolation in solidified sulfur/Fe(III) medium yielded a strain of Desulfuromonas, designated strain TZ1. Strain TZ1 effectively oxidized elemental sulfur to sulfate with an anode serving as the sole electron acceptor, at rates faster than Desulfobulbus propionicus, the only other organism in pure culture previously shown to oxidize S with current production. The abundance of Desulfuromonas species enriched on the anodes of marine benthic fuel cells has previously been interpreted as acetate oxidation driving current production, but the results presented here suggest that sulfur-driven current production is a likely alternative.

  8. Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks

    SciTech Connect (OSTI)

    Lopez-Lopez, D.; Wong-Moreno, A.

    1998-12-31

    Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

  9. Fact #715: February 20, 2012 The Average Age of Light Vehicles Continues to Rise

    Broader source: Energy.gov [DOE]

    The average age for cars and light trucks continues to rise as consumers hold onto their vehicles longer. Between 1995 and 2011, the average age for cars increased by 32% from 8.4 years to 11.1...

  10. Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report

    SciTech Connect (OSTI)

    Elmore, B.B.

    1993-08-01

    As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

  11. Fact #849: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Economy than Midsize Non-Hybrid Cars in 2014 | Department of Energy 9: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel Economy than Midsize Non-Hybrid Cars in 2014 Fact #849: December 1, 2014 Midsize Hybrid Cars Averaged 51% Better Fuel Economy than Midsize Non-Hybrid Cars in 2014 For the 2014 model year, midsize hybrid cars averaged 43.4 miles per gallon (mpg) while midsize non-hybrid cars averaged 28.7 mpg; the difference between the two has narrowed due to the rising average

  12. Epidemiological-environemental study of lead acid battery workers. III. Chronic effects of sulfuric acid on the respiratory system and teeth

    SciTech Connect (OSTI)

    Gamble, J.; Jones, W.; Hancock, J.; Meckstroth, R.L.

    1984-10-01

    The effects of long-term exposure to sulfuric acid mist on the teeth and respiratory system were studied in 248 workers in five plants manufacturing lead acid batteries. The prevalence of cough, phlegm, dyspnea, and wheezing as determined by questionnaire were not associated with estimates of cumulative acid exposure. There was only one case of irregular opacities seen on the chest radiographs. There was no statistically significant association of reduced FEV/sub 1/ peak flow, FEF/sub 50/, and FEF/sub 75/ with acid exposure although the higher exposed group had lower mean values. FVC in the high exposure group showed a statistically significant reductioon compared to the low exposure group but there was no significant association when exposure was analyzed as a continuous variable. The ratio of observed to expected prevalence of teeth etching and erosion was about four times greater in the high acid-exposure group. The earliest case of etching occured after 4 months exposure to an estimated average exposure of 0.23 mg/m/sup 3/ sulfuric acid.

  13. Nuclear Hydrogen Initiative, Results of the Phase II Testing of Sulfur-Iodine Integrated Lab Scale Experiments

    SciTech Connect (OSTI)

    Benjamin Russ; G. Naranjo; R. Moore; W. Sweet; M. Hele; N. Pons

    2009-10-30

    International collaborative effort to construct a laboratory-scale Sulfur-Iodine process capable of producing 100-200 L/hr of hydrogen.

  14. Letter from Commonwealth to Mirant Potomac River Concerning Serious Violations of the National Ambient Air Quality Standards for Sulfur Dioxide

    Office of Energy Efficiency and Renewable Energy (EERE)

    Docket No. EO-05-01: Letter from Commonwealth of Virginia to Mirant Potomac River concerning Serious Violations of the National Ambient Air Quality Standards for Sulfur Dioxide.

  15. Toward Understanding the Effect of Low-Activity Waste Glass Composition on Sulfur Solubility

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Muller, Isabelle S.; Piepel, Greg F.; Kruger, Albert A.

    2014-07-24

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

  16. Toward understanding the effect of low-activity waste glass composition on sulfur solubility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vienna, John D.; Kim, Dong -Sang; Muller, Isabelle S.; Piepel, Greg F.; Kruger, Albert A.; Jantzen, C.

    2014-07-24

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which inmore » turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ≈ P2O5 > Na2O ≈ B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ≈ SnO2 > Others ≈ SiO2. As a result, the order of component effects is similar to previous literature data, in most cases.« less

  17. Effect of morphology of sulfurized materials in the retention of mercury from gas streams

    SciTech Connect (OSTI)

    Guijarro, M.I.; Mendioroz, S.; Munoz, V.

    1998-03-01

    Mercury pollution sources are chloralkali industries, metal sulfide ore smelting, gold refining, cement production, industrial applications of metals, and, especially, fossil fuel combustion and incineration of sewage sludge or municipal garbage. The retention of mercury vapor by sulfur supported on sepiolite has been studied, and the utility of sepiolite as a dispersant for the active phase, sulfur, has been thoroughly ascertained. Samples with 10% S supported on sepiolite of varying size and shape have been prepared from powders sulfurized by reaction/deposit, and their efficiency in depurating air streams with 95 ppm mercury has been tested in a dynamic system using a fixed-bed glass reactor and fluid velocities ranging from 3.1 to 18.9 cm/s. From breakthrough curves under various sets of conditions, the importance of mass transfer under the process conditions has been proven. The progress of the reaction is limited by the resistance to reactant diffusion inside the solid through the layer of product formed. Sulfur reaction to HgS is reduced to an external zone of the solid, giving rise to an egg-shell deposit whose extension is related to sulfur dispersion and porosity of the adsorbent. Then, conversion and capacity of the samples are related to their porosity and S/V ratio. The use of SEM helps to confirm those statements. The 10% S samples compare well with the more conventional S/activated carbon, with their use being advantageous for the low price and abundance of the substrate.

  18. Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin

    SciTech Connect (OSTI)

    Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

    2011-02-28

    Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

  19. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. ); Gidaspow, D.; Gupta, R.; Wasan, D.T. ); Pfister, R.M.: Krieger, E.J. )

    1992-05-01

    This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  20. Evaluation of sulfur-reducing microorganisms for organic desulfurization. [Pyrococcus furiosus

    SciTech Connect (OSTI)

    Miller, K.W.

    1991-01-01

    Because of substantial portion of the sulfur in Illinois coal is organic, microbial desulfurization of sulfidic and thiophenic functionalities could hold great potential for completing pyritic sulfur removal. We are testing the hypothesis that organic sulfur can be reductively removed as H{sub 2}S through the activities of anaerobic microorganisms. Our objectives for this year include the following: (1) To obtain cultures that will reductively desulfurize thiophenic model compounds. In addition to crude oil enrichments begun last year, we sampled municipal sewage sludge. (2) To continue to work toward optimizing the activity of the DBDS-reducing cultures obtained during the previous year. (3) To expand coal desulfurization work to include other coals including Illinois Basin Coal 101 and a North Dakota lignite, which might be more susceptible to the dibenzyldisulfide reducing cultures due to its lower rank. (4) To address the problem of sulfide sorption, by investigating the sorption capacity of coals in addition to Illinois Basin Coal 108.

  1. Electrochemical separation and concentration of sulfur containing gases from gas mixtures

    DOE Patents [OSTI]

    Winnick, Jack (3805 Woodrail-on-the-Green, Columbia, MO 65201)

    1981-01-01

    A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4.sup.= or, in the case of H.sub.2 S, to S.sup.=. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

  2. Development of Ni-based Sulfur Resistant Catalyst for Diesel Reforming

    SciTech Connect (OSTI)

    Gunther Dieckmann

    2006-06-30

    In order for diesel fuel to be used in a solid oxide fuel cell auxiliary power unit, the diesel fuel must be reformed into hydrogen, carbon monoxide and carbon dioxide. One of the major problems facing catalytic reforming is that the level of sulfur found in low sulfur diesel can poison most catalysts. This report shows that a proprietary low cost Ni-based reforming catalyst can be used to reform a 7 and 50 ppm sulfur containing diesel fuel for over 500 hours of operation. Coking, which appears to be route of catalyst deactivation due to metal stripping, can be controlled by catalyst modifications, introduction of turbulence, and/or by application of an electromagnetic field with a frequency from {approx}50 kHz to 13.56 MHz with field strength greater than about 100 V/cm and more preferably greater about 500 V/cm.

  3. Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

    DOE Patents [OSTI]

    Walker, Richard J.

    1986-01-01

    A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

  4. Fact #910: February 1, 2016 Study Shows Average Cost of Electric Vehicle

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Charger Installations - Dataset | Department of Energy 0: February 1, 2016 Study Shows Average Cost of Electric Vehicle Charger Installations - Dataset Fact #910: February 1, 2016 Study Shows Average Cost of Electric Vehicle Charger Installations - Dataset Excel file and dataset for Study Shows Average Cost of Electric Vehicle Charger Installations fotw#910_web.xlsx (16.26 KB) More Documents & Publications Fact #909: January 25, 2016 Workplace Charging Accounts for About a Third of All

  5. Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions

    SciTech Connect (OSTI)

    Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

    1995-12-31

    When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

  6. Gasoline price to average below $2 in 2016 for first time in 12 years

    U.S. Energy Information Administration (EIA) Indexed Site

    Gasoline price to average below $2 in 2016 for first time in 12 years The annual average price for U.S. regular-grade gasoline is expected to fall below $2 per gallon this year for the first time since 2004. In its new monthly forecast, the U.S. Energy Information Administration said drivers will pay on average $1.98 per gallon to fill up at the pump with regular-grade gasoline. EIA expects the monthly average price of gasoline to reach a seven-year low of $1.82 per gallon in February, before

  7. Table 7.4 Average Prices of Selected Purchased Energy Sources...

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Average Prices of Selected Purchased Energy Sources, 2002;" " Level: National and Regional Data; " " Row: Values of Shipments and Employment Sizes;" " Column: Energy Sources;" " ...

  8. Plan averaging for multicriteria navigation of sliding window IMRT and VMAT

    SciTech Connect (OSTI)

    Craft, David Papp, Dávid; Unkelbach, Jan

    2014-02-15

    Purpose: To describe a method for combining sliding window plans [intensity modulated radiation therapy (IMRT) or volumetric modulated arc therapy (VMAT)] for use in treatment plan averaging, which is needed for Pareto surface navigation based multicriteria treatment planning. Methods: The authors show that by taking an appropriately defined average of leaf trajectories of sliding window plans, the authors obtain a sliding window plan whose fluence map is the exact average of the fluence maps corresponding to the initial plans. In the case of static-beam IMRT, this also implies that the dose distribution of the averaged plan is the exact dosimetric average of the initial plans. In VMAT delivery, the dose distribution of the averaged plan is a close approximation of the dosimetric average of the initial plans. Results: The authors demonstrate the method on three Pareto optimal VMAT plans created for a demanding paraspinal case, where the tumor surrounds the spinal cord. The results show that the leaf averaged plans yield dose distributions that approximate the dosimetric averages of the precomputed Pareto optimal plans well. Conclusions: The proposed method enables the navigation of deliverable Pareto optimal plans directly, i.e., interactive multicriteria exploration of deliverable sliding window IMRT and VMAT plans, eliminating the need for a sequencing step after navigation and hence the dose degradation that is caused by such a sequencing step.

  9. Fact #889: September 7, 2015 Average Diesel Price Lower than Gasoline for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the First Time in Six Years | Department of Energy 9: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years Fact #889: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years SUBSCRIBE to the Fact of the Week In July of 2015, the nationwide average price of diesel was lower than the average price of a regular gallon of gasoline for the first time since June 2009. Both gasoline and diesel prices fluctuate throughout the

  10. Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1929-2015 - Dataset | Department of Energy 5: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 - Dataset Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 - Dataset Excel file and dataset for Average Historical Annual Gasoline Pump Price, 1929-2015 fotw#915_web.xlsx (24.76 KB) More Documents & Publications Fact #835: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013 - Dataset Fact #888: August 31, 2015 Historical Gas

  11. Fact #835: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Dataset | Department of Energy 5: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013 - Dataset Fact #835: August 25, 2014 Average Annual Gasoline Pump Price, 1929-2013 - Dataset Excel file with dataset for Fact #835: Average Annual Gasoline Pump Price, 1929-2013 fotw#835_web.xlsx (21.31 KB) More Documents & Publications Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 - Dataset Fact #888: August 31, 2015 Historical Gas Prices - Dataset

  12. Sulfur determination in blood from inhabitants of Brazil using neutron activation analysis

    SciTech Connect (OSTI)

    Oliveira, Laura C.; Zamboni, Cibele B.

    2013-05-06

    In this study the NAA technique was applied to analyze sulfur in blood from inhabitants of Brazil for the proposition of an indicative interval. The measurements were performed considering lifestyle factors (non-smokers, non-drinkers and no history of toxicological exposure) of Brazilian inhabitants. The influence of gender was also investigated considering several age ranges (18-29, 30-39, 40-49, >50 years). These data are useful in clinical investigations, to identify or prevent diseases caused by inadequate sulfur ingestion and for nutritional evaluation of Brazilian population.

  13. NO[sub x] reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

    1992-09-15

    This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter. 7 figs.

  14. NOx reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

    1993-08-31

    This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  15. NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, Virendra K.; Breault, Ronald W.; McLarnon, Christopher R.; Medros, Frank G.

    1993-01-01

    This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  16. NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, Virendra K.; Breault, Ronald W.; McLarnon, Christopher R.; Medros, Frank G.

    1992-01-01

    This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  17. Preliminary analysis of patent trends for sodium/sulfur battery technology

    SciTech Connect (OSTI)

    Triplett, M.B.; Winter, C.; Ashton, W.B.

    1985-07-01

    This document summarizes development trends in sodium/sulfur battery technology based on data from US patents. Purpose of the study was to use the activity, timing and ownership of 285 US patents to identify and describe broad patterns of change in sodium/sulfur battery technology. The analysis was conducted using newly developed statistical and computer graphic techniques for describing technology development trends from patent data. This analysis suggests that for some technologies trends in patent data provide useful information for public and private R and D planning.

  18. A reanalysis of carbonyl sulfide as a source of stratospheric background sulfur aerosol

    SciTech Connect (OSTI)

    Chin, M.; Davis, D.D. [Georgia Institute of Technology, Atlanta, GA (United States)] [Georgia Institute of Technology, Atlanta, GA (United States)

    1995-05-20

    The authors present an analysis of carbonyl sulfide (OCS) in the earth`s atmosphere, with the objective being to assess its role in the formation of sulfate aerosols in the stratosphere. They review the amount of OCS in the atmosphere, its distribution between the troposphere and stratosphere, the estimated source term for emission to the atmosphere, and from one-dimensional model calculations infer a stratospheric lifetime to photochemical reactions of ten years. Calculations infer a sulfur production rate from OCS oxidation which is a factor of 2 to 5 less than recent sulfur aerosol estimates would infer. They discuss a number of possible explanations for the discrepancy.

  19. Advection of sulfur dioxide over the western Atlantic Ocean during CITE 3

    SciTech Connect (OSTI)

    Thornton, D.C.; Bandy, A.R.; Beltz, N.; Driedger, A.R. III; Ferek, R. ||

    1993-12-01

    During the NASA Chemical Instrumentation Test and Evaluation 3 sulfur intercomparison over the western Atlantic Ocean, five techniques for the determination of sulfur dioxide were evaluated. The response times of the techniques varied from 3 to 30 min. Based on the ensemble of measurements reported, it was clear that advection of SO2 from the North American continent occurred in the boundary layer (altitude less than 1 km) with only one exception. The vertical distribution of SO2 above the boundary layer for the northern and southern Atlantic Ocean was remarkably similar duing this experiment.

  20. Performance and economics of a spray-dryer FGD system used with high-sulfur coal

    SciTech Connect (OSTI)

    Livengood, C.D.; Farber, P.S.

    1986-04-01

    Flue-gas desulfurization (FGD) systems based on spray drying to offer advantages over wet lime/limestone systems in a number of areas: low energy consumption, low capital cost, high reliability, and production of a dry waste that is easily handled and disposed of. Uncertainties regarding the performance and economics of such systems for control of high-sulfur-coal emissions have slowed adoption of the technology in the Midwest and East. This paper summarizes 4 years, operating and research experience with that system and describes the current research program, which includes an indepth characterization of an industrial scale dry scrubber with 3.5% sulfur coal.

  1. Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects | Department of Energy Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_parks.pdf (655.5 KB) More Documents & Publications The Next Regulatory Chapter for Commercial Vehicles Review of Diesel

  2. HYBRID SULFUR PROCESS REFERENCE DESIGN AND COST ANALYSIS

    SciTech Connect (OSTI)

    Gorensek, M.; Summers, W.; Boltrunis, C.; Lahoda, E.; Allen, D.; Greyvenstein, R.

    2009-05-12

    PBMR (Pty.) Ltd. in the RSA, with the Hybrid Sulfur (HyS) Process, under development by the Savannah River National Laboratory (SRNL) in the US as part of the NHI. This work was performed by SRNL, Westinghouse Electric Company, Shaw, PBMR (Pty) Ltd., and Technology Insights under a Technical Consulting Agreement (TCA). Westinghouse Electric, serving as the lead for the PBMR process heat application team, established a cost-shared TCA with SRNL to prepare an updated HyS thermochemical water-splitting process flowsheet, a nuclear hydrogen plant preconceptual design and a cost estimate, including the cost of hydrogen production. SRNL was funded by DOE under the NHI program, and the Westinghouse team was self-funded. The results of this work are presented in this Final Report. Appendices have been attached to provide a detailed source of information in order to document the work under the TCA contract.

  3. Structure of the Archaeoglobus fulgidus orphan ORF AF1382 determined by sulfur SAD from a moderately diffracting crystal

    SciTech Connect (OSTI)

    Zhu, Jin-Yi; Fu, Zheng-Qing; Chen, Lirong; Xu, Hao; Chrzas, John; Rose, John Wang, Bi-Cheng

    2012-09-01

    The crystal structure of the 11.14 kDa orphan ORF 1382 from Archaeoglobus fulgidus (AF1382) has been determined by sulfur SAD phasing using data collected from a moderately diffracting crystal and 1.9 synchrotron X-rays. The crystal structure of the 11.14 kDa orphan ORF 1382 from Archaeoglobus fulgidus (AF1382) has been determined by sulfur SAD phasing using a moderately diffracting crystal and 1.9 wavelength synchrotron X-rays. AF1382 was selected as a structural genomics target by the Southeast Collaboratory for Structural Genomics (SECSG) since sequence analyses showed that it did not belong to the Pfam-A database and thus could represent a novel fold. The structure was determined by exploiting longer wavelength X-rays and data redundancy to increase the anomalous signal in the data. AF1382 is a 95-residue protein containing five S atoms associated with four methionine residues and a single cysteine residue that yields a calculated Bijvoet ratio (?F{sub anom}/F) of 1.39% for 1.9 wavelength X-rays. Coupled with an average Bijvoet redundancy of 25 (two 360 data sets), this produced an excellent electron-density map that allowed 69 of the 95 residues to be automatically fitted. The S-SAD model was then manually completed and refined (R = 23.2%, R{sub free} = 26.8%) to 2.3 resolution. High-resolution data were subsequently collected from a better diffracting crystal using 0.97 wavelength synchrotron X-rays and the S-SAD model was refined (R = 17.9%, R{sub free} = 21.4%) to 1.85 resolution. AF1382 has a winged-helixturnhelix structure common to many DNA-binding proteins and most closely resembles the N-terminal domain (residues 182) of the Rio2 kinase from A. fulgidus, which has been shown to bind DNA, and a number of MarR-family transcriptional regulators, suggesting a similar DNA-binding function for AF1382. The analysis also points out the advantage gained from carrying out data reduction and structure determination on-site while the crystal is

  4. A comparison of spatial averaging and Cadzow's method for array wavenumber estimation

    SciTech Connect (OSTI)

    Harris, D.B.; Clark, G.A.

    1989-10-31

    We are concerned with resolving superimposed, correlated seismic waves with small-aperture arrays. The limited time-bandwidth product of transient seismic signals complicates the task. We examine the use of MUSIC and Cadzow's ML estimator with and without subarray averaging for resolution potential. A case study with real data favors the MUSIC algorithm and a multiple event covariance averaging scheme.

  5. Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte

    SciTech Connect (OSTI)

    Unemoto, Atsushi, E-mail: unemoto@imr.tohoku.ac.jp; Ikeshoji, Tamio [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yasaku, Syun; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu [Mitsubishi Gas Chemicals Co., Ltd., 182 Tayuhama Shinwari, Kita-ku, Niigata 950-3112 (Japan); Orimo, Shin-ichi [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2014-08-25

    Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

  6. Study on removal of organic sulfur compound by modified activated carbon

    SciTech Connect (OSTI)

    Fan Huiling; Li Chunhu; Guo Hanxian [Taiyuan Univ. of Technology (China). Research Inst. for Chemical Engineering of Coal

    1997-12-31

    With the price of coal increasing in China, more and more small and medium scale chemical plants are turning to high sulfur coal as the raw material in order to cut cost. However, the major drawback is that the lifetime of the ammonia synthesis catalyst is then reduced greatly because of the high concentration of the sulfur compounds in the synthesis gas, especially organic sulfur, usually CS{sub 2} and COS. The effects of water vapor and experimental temperature on removal of organic sulfur compounds by using a modified activated carbon were studied in this paper. It was found that water vapor had a negative effect on removal of carbon disulfide by activated carbon impregnated with organic amine. The use of activated carbon impregnated with K{sub 2}CO{sub 3} for removal of carbonyl sulfide was also investigated over the temperature range 30--60, the results show a favorable temperature (40) existing for carbonyl sulfide removal. Fixed-bed breakthrough curves for the adsorbent bed were also offered in this paper.

  7. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents and methods of use thereof

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2006-06-27

    Reduced sulfur gas species (e.g., H.sub.2S, COS and CS.sub.2) are removed from a gas stream by compositions wherein a zinc titanate ingredient is associated with a metal oxide-aluminate phase material in the same particle species. Nonlimiting examples of metal oxides comprising the compositions include magnesium oxide, zinc oxide, calcium oxide, nickel oxide, etc.

  8. Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

    DOE Patents [OSTI]

    Way, J. Douglas; Hatlevik, Oyvind

    2014-07-15

    The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.

  9. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 0.059-0.87 seconds at 125-155 C to evaluate effects of reaction temperature, H{sub 2}S concentration, reaction pressure, and catalyst loading on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 62-78 v% hydrogen, 3,000-7,000-ppmv hydrogen sulfide, 1,500-3,500 ppmv sulfur dioxide, and 10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 50 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an

  10. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2004-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 1-6 milliseconds at 125-155 C to evaluate effects of reaction temperature, moisture concentration, reaction pressure on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 70 v% hydrogen, 2,500-7,500-ppmv hydrogen sulfide, 1,250-3,750 ppmv sulfur dioxide, and 0-15 vol% moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 100 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The

  11. Average U.S. household to spend $710 less on gasoline during 2015

    U.S. Energy Information Administration (EIA) Indexed Site

    drivers to see big savings at the gasoline pump this summer U.S. consumers are expected to pay the lowest average price for gasoline in six years during this summer's driving season, mostly because of lower crude oil costs. In its new forecast, the U.S. Energy Information Administration said the price for regular gasoline should average $2.45 per gallon this summer. That's down more than a dollar from the $3.59 per gallon seen last summer, and the cheapest average summer pump price since 2009.

  12. Average household expected to save $675 at the pump in 2015

    U.S. Energy Information Administration (EIA) Indexed Site

    Average household expected to save $675 at the pump in 2015 Although retail gasoline prices have risen in recent weeks U.S. consumers are still expected to save about $675 per household in motor fuel costs this year. In its new monthly forecast, the U.S. Energy Information Administration says the average pump price for regular grade gasoline in 2015 will be $2.43 per gallon. That's about 93 cents lower than last year's average. The savings for consumers will be even bigger during the

  13. Diesel prices continue to increase … U.S. average over $4

    U.S. Energy Information Administration (EIA) Indexed Site

    Diesel prices continue to increase - U.S. average over $4 The U.S. average retail price for on-highway diesel fuel broke the 4-dollar mark for the first time since last March. The U.S. retail average rose to $4.02 a gallon. That's up 2.8 cents from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the New England region at 4.39 a gallon, up 1.3 cents from a week ago. Prices were lowest in the Gulf Coast states at 3.81 a

  14. Fact #622: May 10, 2010 Average Length of Light Vehicle Ownership |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 2: May 10, 2010 Average Length of Light Vehicle Ownership Fact #622: May 10, 2010 Average Length of Light Vehicle Ownership Vehicle owners are holding onto their vehicles for a longer period, according to data from R.L. Polk and Company. The vehicle retention trends show that owners held onto a new vehicle for 56.3 months in 2008, up from 48.4 months six years earlier. New vehicle owners hold onto vehicles about 15 or 16 months longer than used vehicle owners. Average

  15. Fact #624: May 24, 2010 Corporate Average Fuel Economy Standards, Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Years 2012-2016 | Department of Energy 4: May 24, 2010 Corporate Average Fuel Economy Standards, Model Years 2012-2016 Fact #624: May 24, 2010 Corporate Average Fuel Economy Standards, Model Years 2012-2016 The final rule for the Corporate Average Fuel Economy (CAFE) Standards was published in March 2010. Under this rule, each light vehicle model produced for sale in the United States will have a fuel economy target based on its footprint. A vehicle's footprint is defined as the wheelbase

  16. Fact #638: August 30, 2010 Average Expenditure for a New Car Declines in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Relation to Family Earnings | Department of Energy 8: August 30, 2010 Average Expenditure for a New Car Declines in Relation to Family Earnings Fact #638: August 30, 2010 Average Expenditure for a New Car Declines in Relation to Family Earnings Although the average expenditure for a new car has increased from 1967 to 2009, family earnings have also been on the rise. For this period, new car expenditures went from $3,216 to $23,186, while median family earnings went from $7,933 to $77,149.

  17. Fact #889: September 7, 2015 Average Diesel Price Lower than Gasoline for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the First Time in Six Years - Dataset | Department of Energy 9: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years - Dataset Fact #889: September 7, 2015 Average Diesel Price Lower than Gasoline for the First Time in Six Years - Dataset Excel file and dataset for Average Diesel Price Lower than Gasoline for the First Time in Six Years fotw#889_web.xlsx (19.04 KB) More Documents & Publications Fact #859 February 9, 2015 Excess Supply is the Most

  18. Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1929-2015 | Department of Energy 915: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price, 1929-2015 SUBSCRIBE to the Fact of the Week When adjusted for inflation, the average annual price of gasoline has fluctuated greatly, and has recently experienced sharp increases and decreases. The effect of the U.S. embargo of oil from Iran can be seen in the early 1980's with the price of gasoline peaking in

  19. Interfacial reaction dependent performance of hollow carbon nanosphere - sulfur composite as a cathode for Li-S battery

    SciTech Connect (OSTI)

    Zheng, Jianming; Yan, Pengfei; Gu, Meng; Wagner, Michael J.; Hays, Kevin A.; Chen, Junzheng; Li, Xiaohong S.; Wang, Chong M.; Zhang, Ji -Guang; Liu, Jun; Xiao, Jie

    2015-05-26

    Lithium-sulfur (Li-S) battery is a promising energy storage system due to its high energy density, cost effectiveness and environmental friendliness of sulfur. However, there are still a number of challenges, such as low Coulombic efficiency and poor long-term cycling stability, impeding the commercialization of Li-S battery. The electrochemical performance of Li-S battery is closely related with the interfacial reactions occurring between hosting substrate and active sulfur species which are poorly conducting at fully oxidized and reduced states. Here, we correlate the relationship between the performance and interfacial reactions in the Li-S battery system, using a hollow carbon nanosphere (HCNS) with highly graphitic character as hosting substrate for sulfur. With an appropriate amount of sulfur loading, HCNS/S composite exhibits excellent electrochemical performance because of the fast interfacial reactions between HCNS and the polysulfides. However, further increase of sulfur loading leads to increased formation of highly resistive insoluble reaction products (Li2S2/Li2S) which limits the reversibility of the interfacial reactions and results in poor electrochemical performance. In conclusion, these findings demonstrate the importance of the interfacial reaction reversibility in the whole electrode system on achieving high capacity and long cycle life of sulfur cathode for Li-S batteries.

  20. Interfacial reaction dependent performance of hollow carbon nanosphere - sulfur composite as a cathode for Li-S battery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Jianming; Yan, Pengfei; Gu, Meng; Wagner, Michael J.; Hays, Kevin A.; Chen, Junzheng; Li, Xiaohong S.; Wang, Chong M.; Zhang, Ji -Guang; Liu, Jun; et al

    2015-05-26

    Lithium-sulfur (Li-S) battery is a promising energy storage system due to its high energy density, cost effectiveness and environmental friendliness of sulfur. However, there are still a number of challenges, such as low Coulombic efficiency and poor long-term cycling stability, impeding the commercialization of Li-S battery. The electrochemical performance of Li-S battery is closely related with the interfacial reactions occurring between hosting substrate and active sulfur species which are poorly conducting at fully oxidized and reduced states. Here, we correlate the relationship between the performance and interfacial reactions in the Li-S battery system, using a hollow carbon nanosphere (HCNS) withmore » highly graphitic character as hosting substrate for sulfur. With an appropriate amount of sulfur loading, HCNS/S composite exhibits excellent electrochemical performance because of the fast interfacial reactions between HCNS and the polysulfides. However, further increase of sulfur loading leads to increased formation of highly resistive insoluble reaction products (Li2S2/Li2S) which limits the reversibility of the interfacial reactions and results in poor electrochemical performance. In conclusion, these findings demonstrate the importance of the interfacial reaction reversibility in the whole electrode system on achieving high capacity and long cycle life of sulfur cathode for Li-S batteries.« less