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Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

High-Quality Epitaxy of Ruthenium Dioxide, RuO2, on Rutile Titanium Dioxide, TiO2, by Pulsed Chemical Vapor Deposition  

E-Print Network [OSTI]

of rutile TiO2, a material with a high dielectric constant. Therefore, capacitors with high capacitance per these capacitors have low leakage current. Due to its good redox properties, RuO2 has been made into electrodes films have been made by CVD, such as wide-gap semiconductors ZnO23,25 and SnO2,26,27 super- conducting

2

Monitoring Molecular Adsorption on High-Area Titanium Dioxide via Modulated Diffraction of Visible Light  

E-Print Network [OSTI]

Letters Monitoring Molecular Adsorption on High-Area Titanium Dioxide via Modulated Diffraction and evaluation of organic chemical adsorption on various titanium dioxide surfaces. The strategy is illustrated thin films of titanium dioxide (TiO2), with micrometer-sized features, were prepared on transparent

3

Multiscale Modeling of TiO2 Nanoparticle Production in Flame Reactors: Effect of Chemical Mechanism  

E-Print Network [OSTI]

Multiscale Modeling of TiO2 Nanoparticle Production in Flame Reactors: Effect of Chemical Mechanism and Engineering Mechanics, The UniVersity of Texas, Austin, Texas 78712 For titanium dioxide (TiO2) nanoparticles, catalysis, energy, and semiconductors. Titanium dioxide (TiO2) nanoparticles are traditionally used

Raman, Venkat

4

Properties of Disorder-Engineered Black Titanium Dioxide Nanoparticles through  

E-Print Network [OSTI]

hydrogen atom could easily bond to a terminal oxygen site13 . The observed hydrogen diffusion into the TiO2Properties of Disorder-Engineered Black Titanium Dioxide Nanoparticles through Hydrogenation Xiaobo, on the other hand, can undergo fast diffusion and exchange. The enhanced hydrogen mobility may be explained

5

Direct Compressive Measurements of Individual Titanium Dioxide Nanotubes  

E-Print Network [OSTI]

Direct Compressive Measurements of Individual Titanium Dioxide Nanotubes Tolou Shokuhfar the syn- thesis of TiO2 nanotube arrays using an aqueous HF based electrolyte.5 The pH of F ion containing electrolytes was con- trolled to form nanotubes up to a few mi- crometers in length. They reported

Endres. William J.

6

Inorganic-modified semiconductor TiO2 nanotube arrays for photocatalysis  

E-Print Network [OSTI]

titanium dioxide (TiO2) has become a promising route to degrade organic pollutants.5­8 TiO2 is one and efficient technologies to control and reduce pollution growth. Traditional techniques, such as adsorption

Lin, Zhiqun

7

Studying the Mechanisms of Titanium Dioxide as Ultraviolet-Blocking Additive for Films and Fabrics by an  

E-Print Network [OSTI]

Studying the Mechanisms of Titanium Dioxide as Ultraviolet-Blocking Additive for Films and Fabrics November 2003 ABSTRACT: Titanium dioxide (TiO2) has good ultraviolet (UV)-blocking power and is very: inorganic UV-blocking agents; additives; films; adsorption; light scattering INTRODUCTION More frequent

Pan, Ning

8

TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)  

E-Print Network [OSTI]

and pigment industries. Global production of titanium mineral concentrates was expected to increase during half of 2015. In Western Australia, the heavy-mineral resource, data for at the Keysbrook project were172 TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise

9

Adsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a  

E-Print Network [OSTI]

to the surface properties and the adsorption reactions of titanium dioxide-anatase surface. Lin and Bai [3 reserved. Keywords: TiO2; Anatase; Adsorption; Water; Ammonia; DFT 1. Introduction Titanium oxides are usedAdsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a , Selim

Senkan, Selim M.

10

Scanning tunneling microscopy investigation of the TiO2 anatase ,,101... surface Wilhelm Hebenstreit,1  

E-Print Network [OSTI]

of tunneling sites in STM. Titanium dioxide (TiO2) is a versatile material that finds uses as a promoter. Fourfold-coordinated Ti atoms at step edges are preferred adsorption sites and allow the identification

Diebold, Ulrike

11

Small Au and Pt Clusters at the Anatase TiO2(101) Surface: Behavior at Terraces, Steps, and Surface Oxygen Vacancies  

E-Print Network [OSTI]

polymorph of titanium dioxide (TiO2). TiO2 is a versatile oxide material with important applications in many@ecust.edu.cn; diebold@tulane.edu Abstract: The adsorption properties of Au and Pt metal nanoclusters on TiO2 anatase edges. A preference for adsorption at type D-(112) steps is observed, which is probably a result

Diebold, Ulrike

12

TITANIUM--2001 79.1 By Joseph Gambogi  

E-Print Network [OSTI]

metal form but as titanium dioxide (TiO2) pigment, a white pigment in paints, paper, and plastics. TiO2-scattering ability, which impart excellent hiding power and brightness. Owing to a slowing global economy, demand for TiO2 pigment was slightly lower in 2001 than in 2000. Demand for titanium metal was relatively high

13

Surface studies of nitrogen implanted TiO2 Matthias Batzill a,*, Erie H. Morales b  

E-Print Network [OSTI]

.V. All rights reserved. Keywords: Titanium dioxide; Doping; Nitrogen; Surface science 1. IntroductionSurface studies of nitrogen implanted TiO2 Matthias Batzill a,*, Erie H. Morales b , Ulrike Diebold Available online 3 August 2007 Abstract Rutile TiO2(110) single crystals have been doped by nitrogen

Diebold, Ulrike

14

Steps on anatase TiO2(101) XUE-QING GONG1  

E-Print Network [OSTI]

of anatase titanium dioxide (TiO2). This surface is of great interest in its own right. TiO2 is one with the theoretical predictions. Step-edge formation energies as well as the adsorption energies of water scale to be related to defects3,4 . Steps are special adsorption sites for molecules5­7 , and most metals

Diebold, Ulrike

15

The influence of surface conductivity on the apparent zeta potential of TiO2 nanoparticles  

E-Print Network [OSTI]

Titanium dioxide is widely used as TiO2 nanoparticles and has a large variety of potential applications in of these properties, the surface ionization of titanium dioxide nanoparticles in contact with an electrolytic solution is a physico-chemical parameter of particular importance to describe ion adsorption and electrostatic

Paris-Sud XI, Université de

16

TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)  

E-Print Network [OSTI]

as a percentage of apparent consumption E E E E E Recycling: New scrap metal recycled by the titanium industry. Consumption and production of TiO2 pigment was led by China, and several TiO2 pigment producers in China

17

Combined Investigation of Water Sorption on TiO2 Rutile (110) Single Crystal Face: XPS vs. Periodic DFT  

E-Print Network [OSTI]

Introduction During the last decade, the titanium dioxide TiO2 has been widely studied, as well and catalysis [1-5]. At the natural state, the titanium dioxide can be found under three crystallographic phases calculations were performed to investigate the water adsorption process to determine if molecular and

Paris-Sud XI, Université de

18

Reaction of titanium polonides with carbon dioxide  

SciTech Connect (OSTI)

It has been ascertained that heating titanium and tantalum in carbon dioxide to temperatures of 500 or 800/sup 0/C alters the composition of the gas phase, causing the advent of carbon monoxide and lowering the oxygen content. Investigation of the thermal stability of titanium polonides in a carbon dioxide medium has shown that titanium mono- and hemipolonides are decomposed at temperatures below 350/sup 0/C. The temperature dependence of the vapor pressure of polonium produced in the decomposition of these polonides in a carbon dioxide medium have been determined by a radiotensimetric method. The enthalpy of the process, calculated from this relationship, is close to the enthalpy of vaporization of elementary polonium in vacuo.

Abakumov, A.S.; Malyshev, M.L.; Reznikova, N.F.

1987-05-01T23:59:59.000Z

19

Array of titanium dioxide nanostructures for solar energy utilization  

DOE Patents [OSTI]

An array of titanium dioxide nanostructures for solar energy utilization includes a plurality of nanotubes, each nanotube including an outer layer coaxial with an inner layer, where the inner layer comprises p-type titanium dioxide and the outer layer comprises n-type titanium dioxide. An interface between the inner layer and the outer layer defines a p-n junction.

Qiu, Xiaofeng; Parans Paranthaman, Mariappan; Chi, Miaofang; Ivanov, Ilia N; Zhang, Zhenyu

2014-12-30T23:59:59.000Z

20

Glutamate Surface Speciation on Amorphous Titanium Dioxide and  

E-Print Network [OSTI]

Glutamate Surface Speciation on Amorphous Titanium Dioxide and Hydrous Ferric Oxide D I M I T R I (HFO) and titanium dioxide exhibit similar strong attachment of many adsorbates including biomolecules on amorphous titanium dioxide. The results indicate that glutamate adsorbs on HFO as a deprotonated divalent

Sverjensky, Dimitri A.

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Study of Interfacial Charge-Transfer Complex on TiO2 Particles in Aqueous Suspension by Second-Harmonic Generation  

E-Print Network [OSTI]

/mol. 1. Introduction Titanium dioxide (TiO2) is a wide band-gap semiconductor having two common crystal, the adsorption isotherm of catechol on the colloidal TiO2 suspension was obtained and gave an excellent fit to the Langmuir adsorption model. From this, we infer the free energy of the adsorption to be G° ) -6.8 kcal

Eisenthal, Kenneth B.

22

Method for synthesis of titanium dioxide nanotubes using ionic liquids  

SciTech Connect (OSTI)

The invention is directed to a method for producing titanium dioxide nanotubes, the method comprising anodizing titanium metal in contact with an electrolytic medium containing an ionic liquid. The invention is also directed to the resulting titanium dioxide nanotubes, as well as devices incorporating the nanotubes, such as photovoltaic devices, hydrogen generation devices, and hydrogen detection devices.

Qu, Jun; Luo, Huimin; Dai, Sheng

2013-11-19T23:59:59.000Z

23

Optimisation of Accurate Rutile TiO2 (110), (100), (101) and (001) Surface Models from Periodic DFT Calculations  

E-Print Network [OSTI]

For years, the titanium dioxide, TiO2, has been widely used as a white pigment and opacifier. Its recent of pseudopotentials was studied and it appears that four valence electrons for titanium atoms are sufficient. The aim and inorganic molecules adsorption [14-21], have been also studied and the surface chemistry on this phase has

Paris-Sud XI, Université de

24

TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)  

E-Print Network [OSTI]

consumption E E E E E Recycling: New scrap metal recycled by the titanium industry totaled about 29,000 tons and automotive industries led to an increase in global production of TiO2 pigment compared with that in 2009

25

The surface science of titanium dioxide Ulrike Diebold*  

E-Print Network [OSTI]

The surface science of titanium dioxide Ulrike Diebold* Department of Physics, Tulane University, New Orleans, LA 70118, USA Manuscript received in final form 7 October 2002 Abstract Titanium dioxide is reviewed on the adsorption and reaction of a wide variety of inorganic molecules (H2, O2, H2O, CO, CO2, N2

Diebold, Ulrike

26

TITANIUM--1999 79.1 By Joseph Gambogi  

E-Print Network [OSTI]

is consumed as titanium dioxide (TiO2), a white pigment in paints, paper, and plastics. The superiority of Ti in a major producer. Because of decreased demand from the commercial aerospace industry, production

27

TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)  

E-Print Network [OSTI]

mine tailings at Green Cove Springs, FL, ceased. At the Stony Creek mining operation, development to have decreased significantly. While mining continued at Starke, FL, and Stony Creek, VA, reprocessing operations in Sorel, Quebec, Canada. In response to uncertain market conditions, mining and TiO2 slag

28

Charge transfer in photovoltaics consisting of interpenetrating networks of conjugated polymer and TiO2 nanoparticles  

E-Print Network [OSTI]

Charge transfer in photovoltaics consisting of interpenetrating networks of conjugated polymer and interpenetrating polymer networks6 can substantially im- prove the photoconductivity, and thus quantum efficiency and layered titanium dioxide (TiO2) nanoparticles on charge transfer processes in conjugated polymer

Carter, Sue

29

Visible-light active TiO2 for microwave assisted photocatalytic reactions using mercury electrodeless discharge lamps  

E-Print Network [OSTI]

activity was evaluated by the degradation of mono-chloroacetic acid in a microwave field using mercury with pure titania, the UV-Vis spectra of Ag+, Zr4+ and VO2+ doped titanium dioxide show significant absorption in visible region. The degradation efficiency of MCAA in a microwave field on these TiO2 layers

Cirkva, Vladimir

30

TITANIUM MINERAL CONCENTRATES1 (Data in thousand metric tons of contained TiO2 unless otherwise noted)  

E-Print Network [OSTI]

as a percentage of estimated consumption 76 78 68 65 68 Recycling: None. Import Sources (200710): South Africa of titanium minerals was led by China. Although world mine production increased in 2011, a shortage

31

Titanium dioxide based high temperature carbon monoxide selective sensor  

E-Print Network [OSTI]

Titanium dioxide based high temperature carbon monoxide selective sensor Nancy O. Savagea , Sheikh as a trap for the oxidation products of CO and CH4. Upon oxidation of CO on ALC, carbonate species were detected, whereas the reaction of CH4 produced negligible carbonate species. The insensitivity of the ALC

Dutta, Prabir K.

32

Hollow hemispherical titanium dioxide aggregates fabricated by coaxial  

E-Print Network [OSTI]

hemispherical titanium dioxide aggregates fabricated by coaxial electrospray for dye-sensitized solar cell nanocrystallites were prepared by a coaxial electrospray method and applied to dye- sensitized solar cells (DSCs-Optical Instrumentation Engineers (SPIE). [DOI: 10.1117/1.JNP.6.063519] Keywords dye-sensitized solar cells; hollow

Cao, Guozhong

33

Distributed feedback laser biosensor incorporating a titanium dioxide nanorod surface  

E-Print Network [OSTI]

Distributed feedback laser biosensor incorporating a titanium dioxide nanorod surface Chun Ge,1 emission wavelength is modulated by the adsorption of biomolecules, whose greater dielectric permittivity- dimensional volume overlap between the DFBLB resonant mode and the region where biomolecule adsorption can oc

Cunningham, Brian

34

Structure and dynamics of liquid water on rutile TiO2(110) Li-Min Liu, Changjun Zhang, Geoff Thornton, and Angelos Michaelides  

E-Print Network [OSTI]

those between water and titanium dioxide TiO2 . Water-TiO2 interfaces are relevant to photocatalysis on which adsorption state the water molecules are in at the interface: dissociated or molecular? Many, density-functional theory DFT studies predict either molecular or dissociative adsorption on the perfect

Alavi, Ali

35

Dye Sensitization of Nanocrystalline Titanium Dioxide with Osmium and Ruthenium Polypyridyl Complexes  

E-Print Network [OSTI]

dioxide electrodes.2-4 The highest efficiency reported to date for such systems has been obtained using conversion efficiencies of up to 10% have been reported.4 The approximate energetics for this system while maintaining the excited-state redox potential at the same energy level relative to the TiO2 can

Sauvé, Geneviève

36

E-Print Network 3.0 - amorphous titanium dioxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

, increasing carbon dioxide emissions." It is hoped that custom- ers will buy into the smart meter... Titanium is often considered a valuable metal. In fact, this light- weight...

37

EQCM Investigations of Dye-Functionalized Nanocrystalline Titanium Dioxide Electrode/ Solution Interfaces: Does Luminescence Report Directly on Interfacial Electron Transfer  

E-Print Network [OSTI]

LETTERS EQCM Investigations of Dye-Functionalized Nanocrystalline Titanium Dioxide Electrode microbalance (EQCM) experiments have been performed on dye-functionalized nanocrystalline titanium dioxide electrode/solution interfaces. The experiments show that reversible, potential- induced dye desorption

38

Role of ethylene on surface oxidation of TiO2(110) Y. Murata, V. Petrova, I. Petrov, C. V. Ciobanu, and S. Kodambaka  

E-Print Network [OSTI]

Institute of Physics. [http://dx.doi.org/10.1063/1.4767954] Transition-metal (TM) oxides,1 notably titanium dioxide (TiO2),2­4 have a wide variety of applications in photocataly- sis, for splitting of water5­13 and are essential to promote adsorption and reaction of gas molecules.14 As O atoms desorb from the sur- face of Ti

Ciobanu, Cristian

39

VOLUME 81, NUMBER 14 P H Y S I C A L R E V I E W L E T T E R S 5 OCTOBER 1998 Structure and Energetics of Water Adsorbed at TiO2 Anatase 101 and 001 Surfaces  

E-Print Network [OSTI]

of TiO2 rutile, that is, in turn, the most stable polymorph of titanium dioxide. However, it is anatase, nondissociative molecular adsorption at fivefold coordinated Ti sites is favored at both low and monolayer coverage. On the (001) surface, for u # 0.5, H2O is adsorbed dissociatively, with an adsorption energy DHH

Selloni, Annabella

40

TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless noted)  

E-Print Network [OSTI]

, and lacquers, 47%; paper, 24%; plastics, 18%; and other, 11%. Other uses of TiO2 included catalysts, ceramics level in 1995 and demand decreased slightly. A shift in the global supply demand scenario pushed demand

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons unless otherwise noted)  

E-Print Network [OSTI]

import reliance 2 as a percentage of apparent consumption E E E E E Recycling: New scrap metal recycled in 2011. Increased consumption and production of TiO2 pigment was led by China. To meet rising domestic

42

TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless otherwise noted)  

E-Print Network [OSTI]

Stockpile Center continued to solicit offers for the sale of titanium sponge held in the Government-grade sponge. For fiscal year 2001, 4,540 tons of titanium sponge is being offered for sale. Stockpile Status for disposal FY 2000 FY 2000 Titanium sponge 19,100 3,390 19,100 4,540 4,240 Ev

43

TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless otherwise noted)  

E-Print Network [OSTI]

metal recycled by the titanium industry totaled about 18,000 tons in 2001. Estimated use of titanium as scrap and in the form of ferrotitanium made from scrap by the steel industry was about 6,000 tons; by the superalloy industry, 900 tons; and, in other industries, 700 tons. Old scrap reclaimed totaled about 500 tons

44

Antimicrobial polymers - The antibacterial effect of photoactivated nano titanium dioxide polymer composites  

SciTech Connect (OSTI)

To obtain a polymer with antimicrobial properties for medical and sanitary applications nanoscale titanium dioxide (TiO{sub 2}) particles have been incorporated into a medical grade polypropylene (PP) matrix with various filler contents (0 wt %, 2 wt %, 10 wt % and 15 wt %). The standard application of TiO{sub 2} for antimicrobial efficacy is to deposit a thin TiO{sub 2} coating on the surface. In contrast to the common way of applying a coating, TiO{sub 2} particles were applied into the bulk polymer. With this design we want to ensure antimicrobial properties even after application of impact effects that could lead to surface defects. The filler material (Aeroxide TiO{sub 2} P25, Evonik) was applied via melt compounding and the compounding parameters were optimized with respect to nanoscale titanium dioxide. In a next step the effect of UV-irradiation on the compounds concerning their photocatalytic activity, which is related to the titanium dioxide amount, was investigated. The photocatalytic effect of TiO{sub 2}-PP-composites was analyzed by contact angle measurement, by methylene blue testing and by evaluation of inactivation potential for Escherichia coli (E.coli) bacteria. The dependence of antimicrobial activity on the filler content was evaluated, and on the basis of different titanium dioxide fractions adequate amounts of additives within the compounds were discussed. Specimens displayed a higher photocatalytic and also antimicrobial activity and lower contact angles with increasing titania content. The results suggest that the presence of titania embedded in the PP matrix leads to a surface change and a photocatalytic effect with bacteria killing result.

Huppmann, T., E-mail: teresa.huppmann@tum.de; Leonhardt, S., E-mail: stefan.leonhardt@mytum.de, E-mail: erhard.krampe@tum.de; Krampe, E., E-mail: stefan.leonhardt@mytum.de, E-mail: erhard.krampe@tum.de; Wintermantel, E., E-mail: wintermantel@tum.de [Institute of Medical and Polymer Engineering, Technische Universitt Mnchen (Germany); Yatsenko, S., E-mail: s.yatsenko@skz.de; Radovanovic, I., E-mail: i.radovanovic@skz.de, E-mail: m.bastian@skz.de; Bastian, M., E-mail: i.radovanovic@skz.de, E-mail: m.bastian@skz.de [SKZ- German Plastics Center, Wrzburg (Germany)

2014-05-15T23:59:59.000Z

45

TITANIUM AND TITANIUM DIOXIDE1 (Data in metric tons, unless otherwise noted)  

E-Print Network [OSTI]

E E E E E Recycling: New scrap metal recycled by the titanium industry was about 25,000 tons in 1996 industry was 4,700 tons; by the superalloy industry, 730 tons; and in other industries, 510 tons. Old scrap nation (MFN) Non-MFN3 12/31/96 12/31/96 Waste and scrap metal 8108.10.1000 Free Free. Unwrought metal

46

Titanium dioxide nanofiber-cotton targets for efficient multi-keV x-ray generation  

SciTech Connect (OSTI)

Multi-keV x-ray generation from low-density (27{+-}7 mg/cm{sup 3}) nanofiber-cotton targets composed of titanium dioxide has been investigated. The cotton targets were heated volumetrically and supersonically to a peak electron temperature of 2.3 keV, which is optimal to yield Ti K-shell x rays. Considerable enhancement of conversion efficiency [(3.7{+-}0.5)%] from incident laser energy into Ti K-shell x rays (4-6 keV band) was attained in comparison with that [(1.4{+-}0.9)%] for a planar Ti-foil target.

Tanabe, Minoru; Nishimura, Hiroaki; Fujioka, Shinsuke; Nagai, Keiji; Yamamoto, Norimasa; Mima, Kunioki [Institute of Laser Engineering, Osaka University, 2-6 Yamada-Oka, Suita, Osaka 565-0871 (Japan); Gu, Zhong-Ze; Pan, Chao [State Key Laboratory of Bioelectronics, Southeast University, Nanjing, Jiangsu 210096 (China); Girard, Frederic; Primout, Michel; Villette, Bruno; Brebion, Didier [Commissariat a l'Energie Atomique, DAM-Ile-de-France, Bruyeres-le-Chatel, 91297 Arpajon, Cedex (France); Fournier, Kevin B. [Lawrence Livermore National Laboratory, P.O. Box 808, L-473, Livermore, California 94550 (United States); Fujishima, Akira [Kanagawa Academy of Science and Technology, 3-2-1 Sakato, Takatsu-ku, Kawasaki 213-0012 (Japan)

2008-08-04T23:59:59.000Z

47

Energetics of the Nanocrystalline Titanium Dioxide/Aqueous Solution Interface: Approximate Conduction Band Edge Variations between H0 ) -10 and H-) +26  

E-Print Network [OSTI]

Energetics of the Nanocrystalline Titanium Dioxide/Aqueous Solution Interface: Approximate). Here we report on the dependence of the conduction band edge energy of nanocrystalline titanium dioxide the reversible uptake of protons at near band edge trap sites,6 even under conditions where surface adsorption

48

Modeling Excited States in TiO2 Nanoparticles: On the Accuracy of a TD-DFT Based Description  

SciTech Connect (OSTI)

We have investigated the suitability of Time-Dependent Density Functional Theory (TD-DFT) to describe vertical low-energy excitations in naked and hydrated titanium dioxide nanoparticles through a comparison with results from Equation-of-Motion Coupled Cluster (EOM-CC) quantum chemistry methods. We demonstrate that for most TiO2 nanoparticles TD-DFT calculations with commonly used exchange-correlation (XC-)potentials (e.g. B3LYP) and EOM-CC methods give qualitatively similar results. Importantly, however, we also show that for an important subset of structures, TD-DFT gives qualitatively different results depending upon the XC-potential used and that in this case only TD-CAM-B3LYP and TD-BHLYP calculations yield results that are consistent with those obtained using EOM-CC theory. Moreover, we demonstrate that the discrepancies for such structures arise from a particular combination of defects, excitations involving which are charge-transfer excitations and hence are poorly described by XC-potentials that contain no or low fractions of Hartree-Fock like exchange. Finally, we discuss that such defects are readily healed in the presence of ubiquitously present water and that as a result the description of vertical low-energy excitations for hydrated TiO2 nanoparticles is hence non-problematic.

Berardo, Enrico; Hu, Hanshi; Shevlin, S. A.; Woodley, Scott M.; Kowalski, Karol; Zwijnenburg, Martijn A.

2014-03-11T23:59:59.000Z

49

Enhanced light-conversion efficiency of titanium-dioxide dye-sensitized solar cells with the addition of  

E-Print Network [OSTI]

Enhanced light-conversion efficiency of titanium- dioxide dye-sensitized solar cells-doped tin oxide (FTO) nanoparticles and the application of such electrodes on dye-sensitized solar cell to the presence of ITO or FTO nanoparticles. Keywords: dye-sensitized solar cell, nanoparticle, electrode film

Cao, Guozhong

50

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications  

E-Print Network [OSTI]

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications by anodic oxidation of titanium foil followed with O2 and CO annealing were employed as matrices consisted of Ti3+ defects with carbon-doping and exhibited well defined quasi-reversible cyclic voltammetric

Cao, Guozhong

51

E-Print Network 3.0 - anatase tio2 thin Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

at Madison Collection: Materials Science 36 Titanium dioxide based high temperature carbon monoxide selective sensor Summary: October 2000; accepted 16 October 2000 Abstract The...

52

Titanium-Dioxide Nano-Fiber-Cotton Targets for Efficient Multi-keV X-Ray Generation  

SciTech Connect (OSTI)

Multi-keV x-ray generation from low-density (27 {+-} 7 mg/cc) nano-fiber-cotton targets composed of titanium-dioxide has been investigated. The cotton targets were heated volumetrically and supersonically to a peak electron temperature of 2.3 keV, which is optimal to yield Ti K-shell x rays. Considerable enhancement of conversion efficiency (3.7 {+-} 0.5%) from incident laser energy into Ti K-shell x rays (4-6 keV band) was attained in comparison with that (1.4 {+-} 0.9%) for a planar Ti-foil target.

Tanabe, M; Nishimura, H; Fujioka, S; Nagai, K; Yamamoto, N; Gu, Z; Pan, C; Girard, F; Primout, M; Villette, B; Brebion, D; Fournier, K B; Fujishima, A; Mima, K

2008-06-12T23:59:59.000Z

53

Process for synthesizing titanium carbide, titanium nitride and titanium carbonitride  

DOE Patents [OSTI]

A process is disclosed for synthesizing titanium carbide, titanium nitride or titanium carbonitride. The process comprises placing particles of titanium, a titanium salt or titanium dioxide within a vessel and providing a carbon-containing atmosphere within the vessel. The vessel is heated to a pyrolysis temperature sufficient to pyrolyze the carbon to thereby coat the particles with a carbon coating. Thereafter, the carbon-coated particles are heated in an inert atmosphere to produce titanium carbide, or in a nitrogen atmosphere to produce titanium nitride or titanium carbonitride, with the heating being of a temperature and time sufficient to produce a substantially complete solid solution.

Koc, R.; Glatzmaier, G.C.

1995-05-23T23:59:59.000Z

54

Process for synthesizing titanium carbide, titanium nitride and titanium carbonitride  

DOE Patents [OSTI]

A process for synthesizing titanium carbide, titanium nitride or titanium carbonitride. The process comprises placing particles of titanium, a titanium salt or titanium dioxide within a vessel and providing a carbon-containing atmosphere within the vessel. The vessel is heated to a pyrolysis temperature sufficient to pyrolyze the carbon to thereby coat the particles with a carbon coating. Thereafter, the carbon-coated particles are heated in an inert atmosphere to produce titanium carbide, or in a nitrogen atmosphere to produce titanium nitride or titanium carbonitride, with the heating being of a temperature and time sufficient to produce a substantially complete solid solution.

Koc, Rasit (Lakewood, CO); Glatzmaier, Gregory C. (Boulder, CO)

1995-01-01T23:59:59.000Z

55

approach multifunctional tio2: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reactions arises from TiO2 band gap. When TiO2 is irradiated with light of energy equal or higher to its band gap energy, an electron is promoted from the valence band...

56

Semiconductor-Based Interfacial Electron-Transfer Reactivity: Decoupling Kinetics from pH-Dependent Band Energetics in a Dye-Sensitized Titanium Dioxide/Aqueous Solution  

E-Print Network [OSTI]

H-Dependent Band Energetics in a Dye-Sensitized Titanium Dioxide/Aqueous Solution System Susan G. Yan and Joseph T-bandgap semiconductors via attachment of redox-active dyes offers a means of sensitizing these materials for visible,3 As with other semiconductor/molecular dye assemblies, these work by electron injection from a photoexcited state

57

A New Method for Production of Titanium Dioxide Pigment - Eliminating CO2 Emission  

SciTech Connect (OSTI)

The objective of this project was to demonstrate the potential of a new process technology to reduce the energy consumption and CO{sub 2} emission from the production of titanium dioxide (TiO{sub 2}) pigment. TiO{sub 2} is one of the most commonly used minerals in the chemical manufacturing industry. It has been commercially processed as a pigment since the early 1900's, and has a wide variety of domestic and industrial applications. TiO{sub 2} pigment is currently produced primarily by the use of the so called ?chloride process?. A key step of the chloride process relies on high temperature carbo-chlorination of TiO{sub 2} bearing raw materials, hence producing large quantities of CO{sub 2}. The new method uses a chemical/metallurgical sequential extraction methodology to produce pigment grade TiO{sub 2} from high-TiO{sub 2} slag. The specific project objectives were to 1) study and prove the scientific validity of the concept, 2) understand the primary chemical reactions and the efficiency of sequential extraction schemes, 3) determine the properties of TiO{sub 2} produced using the technology, and 4) model the energy consumptions and environmental benefits of the technology. These objectives were successfully met and a new process for producing commercial quality TiO{sub 2} pigment was developed and experimentally validated. The process features a unique combination of established metallurgical processes, including alkaline roasting of titania slag followed by leaching, solvent extraction, hydrolysis, and calcination. The caustic, acidic, and organic streams in the process will also be regenerated and reused in the process, greatly reducing environmental waste. The purpose and effect of each of these steps in producing purified TiO{sub 2} is detailed in the report. The levels of impurities in our pigment meet the requirements for commercial pigment, and are nearly equivalent to those of two commercial pigments. Solvent extraction with an amine extractant proved to be extremely effective in achieving these targets. A model plant producing 100,000 tons TiO{sub 2} per year was designed that would employ the new method of pigment manufacture. A flow sheet was developed and a mass and energy balance was performed. A comparison of the new process and the chloride process indicate that implementation of the new process in the US would result in a 21% decrease in energy consumption, an annual energy savings of 42.7 million GJ. The new process would reduce CO{sub 2} emissions by 21% in comparison to the chloride process, an annual reduction of 2.70 million tons of CO{sub 2}. Since the process equipment employed in the new process is well established in other industrial processes and the raw materials for the two processes are identical we believe the capital, labor and materials cost of production of pigment grade TiO{sub 2} using the new method would be at least equivalent to that of the chloride process. Additionally, it is likely that the operating costs will be lower by using the new process because of the reduced energy consumption. Although the new process technology is logical and feasible based on its chemistry, thermodynamic principles, and experimental results, its development and refinement through more rigorous and comprehensive research at the kilogram scale is needed to establish it as a competitive industrial process. The effect of the recycling of process streams on the final product quality should also be investigated. Further development would also help determine if the energy efficiency and the environmental benefits of the new process are indeed significantly better than current commercial methods of pigment manufacture.

Fang, Zhigang Zak [University of Utah] [University of Utah

2013-11-05T23:59:59.000Z

58

Experiment on TiO2/AC Photocatalysis Technique to Eliminate Toluene in Air Conditioning Systems  

E-Print Network [OSTI]

at present, the article proposes that new-type purification technique and hopes to promote the upgrading of the product about purification. 2. INTRODUTION ON THE STRURE AND STUFF OF ACTIVE CARBON AND NANO- TITANIUM DIOXIDE PHOTOCATALYSIS PURIFICATION... WEB What is called active carbon and nano-titanium dioxide photocatalysis technique is to utilize the method of compounding active carbon and nanometer photocatalyst to firstly form absorption layer on supporting body surface by gluing, which...

Hu, Y.; Feng, G.; Yuan, Q.

2006-01-01T23:59:59.000Z

59

A novel "gelsol" strategy to synthesize TiO2 nanorod combining reduced graphene oxide composites  

E-Print Network [OSTI]

Graphene oxide Titanium dioxide Nanostructure Semiconductors Nanorods a b s t r a c t In this studyH value benefits the deprotonation of TEOA for adsorption to the stationary nuclei. Therefore triethanolamine (TEOA) with titanium (IV) isopropoxide (TIPO) at a molar ratio of [TEOA]:[TIPO]¼2:1, was added

Guo, John Zhanhu

60

applying nanostructured tio2: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sputtering. Highly oriented, crack-free, stoichiometric polycrystalline rutile TiO2 thin film; RF magnetron sputtering; Phase transition; Deposition parameter effects 1....

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

TITANIUM--2000 80.1 By Joseph Gambogi  

E-Print Network [OSTI]

, rising demand in certain sectors allowed producers to use some of the excess capacity. Approximately 95% of titanium is consumed as TiO2 pigment, a pigment used in paints, paper, and plastics. The superiority of Ti

62

Surface Science Letters Nature of the excited states of the rutile TiO2(110) surface  

E-Print Network [OSTI]

The nature of the electronically excited states on titanium dioxide surface is important for under- standing to the band gap in titanium dioxide that slows down recombina- tion of the electron­hole pair produced upon with adsorbed water molecule. The calculated adsorption energies and geometries are compared with available

Truong, Thanh N.

63

Effect of Chemical Lithium Intercalation into Rutile TiO2 Nanorods...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemical Lithium Intercalation into Rutile TiO2 Nanorods. Effect of Chemical Lithium Intercalation into Rutile TiO2 Nanorods. Abstract: Rutile TiO2 nanorods were synthesized by...

64

Nonthermal Water Splitting on Rutile TiO2: Electron-Stimulated...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nonthermal Water Splitting on Rutile TiO2: Electron-Stimulated Production of H-2 and O-2 in Amorphous Solid Water Films on TiO2 Nonthermal Water Splitting on Rutile TiO2:...

65

Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Abstract: Understanding hydrogen formation on TiO2...

66

Atmospheric Pressure Chemical Vapor Deposition of High Silica SiO2-TiO2 Antireflective Thin Films for Glass Based Solar Panels  

SciTech Connect (OSTI)

The atmospheric pressure chemical vapor deposition (APCVD) of SiO2-TiO2 thin films employing [[(tBuO)3Si]2O-Ti(OiPr)2], which can be prepared from commercially available materials, results in antireflective thin films on float glass under industrially relevant manufacturing conditions. It was found that while the deposition temperature had an effect on the SiO2:TiO2 ratio, the thickness was dependent on the time of deposition. This study shows that it is possible to use APCVD employing a single source precursor containing titanium and silicon to produce thin films on float glass with high SiO2:TiO2 ratios.

Klobukowski, Erik R [ORNL; Tenhaeff, Wyatt E [ORNL; McCamy, James [PPG; Harris, Caroline [PPG; Narula, Chaitanya Kumar [ORNL

2013-01-01T23:59:59.000Z

67

TITANIUM--2002 79.1 References that include a section mark () are found in the Internet  

E-Print Network [OSTI]

in paints, paper, and plastics. TiO2 is used as a pigment because of its whiteness, brightness, and opacity. In 2002, numerous titanium mineral exploration and development projects were in progress. World demand. Europe and Asia led the slight increase in the global demand for TiO2 pigment. Depressed demand from

68

Preparation of porous nitrogen-doped titanium dioxide microspheres and a study of their photocatalytic, antibacterial and electrochemical activities  

SciTech Connect (OSTI)

Graphical abstract: Porous N-doped TiO{sub 2} microspheres were prepared for the first time via plasma technique. The sample exhibited better photocatalytic activity, photoinduced inactivation activity and better electrochemical activity than those of TiO{sub 2} microspheres and P25. Display Omitted Highlights: ? Porous N-doped TiO{sub 2} microspheres were prepared via nitrogen plasma technique. ? Plasma treatment did not affect the porous structure of the TiO{sub 2} microspheres. ? With the plasma treatment, the N contents in the samples increased. ? Their photocatalytic, antibacterial and electrochemical activities were studied. -- Abstract: Nitrogen-doped titanium dioxide (N-doped TiO{sub 2}) microspheres with porous structure were prepared via the nitrogen-assisted glow discharge plasma technique at room temperature for the first time. The samples were characterized by X-ray diffraction, scanning electron microscopy, nitrogen adsorptiondesorption measurement, UVVis diffuse reflectance spectra, photoluminescence spectroscopy and X-ray photoelectron spectroscopy. The results indicated that the plasma treatment did not affect the porous structure of the TiO{sub 2} microspheres. With the plasma treatment, the N contents in the samples increased. During the photocatalytic degradation of methylene blue under simulative sunlight irradiation, the sample after plasma treatment for 60 min (N-TiO{sub 2}-60) exhibited higher photocatalytic activity than those of the TiO{sub 2} microspheres, P25 and other N-doped TiO{sub 2} microspheres. Furthermore, the N-TiO{sub 2}-60 showed excellent antibacterial activities towards Escherichia coli under visible irradiation. These should be attributed to the enhancement of the visible light region absorption for TiO{sub 2} after N-doping. Electrochemical data demonstrated that the N-doping not only enhanced the electrochemical activity of TiO{sub 2}, but also improved the reversibility of Li insertion/extraction reactions and the rate behavior of TiO{sub 2} during chargedischarge cycles.

Chen, S. [College of Chemical Engineering, Sichuan University, Chengdu 610065 (China)] [College of Chemical Engineering, Sichuan University, Chengdu 610065 (China); Chu, W., E-mail: chuwei65@yahoo.com.cn [College of Chemical Engineering, Sichuan University, Chengdu 610065 (China); Huang, Y.Y. [College of Materials and Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu 610059 (China)] [College of Materials and Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu 610059 (China); Liu, X. [College of Chemical Engineering, Sichuan University, Chengdu 610065 (China)] [College of Chemical Engineering, Sichuan University, Chengdu 610065 (China); Tong, D.G., E-mail: tongdongge@163.com [College of Chemical Engineering, Sichuan University, Chengdu 610065 (China); College of Materials and Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu 610059 (China)

2012-12-15T23:59:59.000Z

69

Decoding Titanium Dioxide | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesData Files Data Files 1B&W Y-12 Tymes &Decisions

70

Structure, defects, and impurities at the rutile TiO2(011)-(2 1) surface: A scanning tunneling microscopy study  

E-Print Network [OSTI]

Available online 21 July 2006 Abstract The titanium dioxide rutile (011) (equivalent to (101)) surface boundaries 1. Introduction Titanium dioxide is a versatile material that finds appli- cations in a wide range) structure are active adsorption sites. Segregation of calcium impurities from the bulk results in an ordered

Diebold, Ulrike

71

Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TiO2(110) Surfaces Prepared via Carboxylic Acid Adsorption and Photolysis. Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces Prepared via Carboxylic Acid...

72

2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking....

73

Chemical Reactivity of Reduced TiO2(110): The dominant role of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

74

Methylene Bromide Chemistry and Photochemistry on Rutile TiO2...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Abstract: The chemistry and photochemistry...

75

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

76

Surface Chemistry of 2-Propanol on TiO2(110): Low and High Temperature...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry of 2-Propanol on TiO2(110): Low and High Temperature Dehydration, Isotope Effects, and Influence of Local Surface Chemistry of 2-Propanol on TiO2(110): Low and High...

77

Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Abstract: We used anionic...

78

Hierarchically structured TIO2 nanorod spheres for clean water and energy production.  

E-Print Network [OSTI]

??This study focuses on the synthesis of hierarchical TiO2 nanorod spheres for photocatalytic clean water and energy production. TiO2 nanorod spheres were firstly synthesized by (more)

Bai, Hongwei

2014-01-01T23:59:59.000Z

79

A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature  

E-Print Network [OSTI]

A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature Jia Zhang,ab Chao temperature oxygen sensor based on TiO2/graphene device was developed with an enhanced sensing performance­hole pairs in the TiO2 film and the photogenerated electrons were scavenged by graphene and percolated

Cao, Wenwu

80

Enhanced visible-light absorption of mesoporous TiO2 by co-doping with transition-metal/nitrogen ions  

SciTech Connect (OSTI)

Titanium (IV) oxide, TiO2, has been the object of intense scrutiny for energy applications. TiO2 is inexpensive, non-toxic, and has excellent corrosion resistance when exposed to electrolytes. A major drawback preventing the widespread use TiO2 for photolysis is its relatively large band gap of ~3eV. Only light with wavelengths shorter than 400 nm, which is in the ultraviolet portion of the spectrum, has sufficient energy to be absorbed. Less than 14 percent of the solar irradiation reaching the earth s surface has energy exceeding this band gap. Adding dopants such as transition metals has long been used to reduce the gap and increase photocatalytic activity by accessing the visible part of the solar spectrum. The degree to which the band gap is reduced using transition metals depends in part on the overlap of the d-orbitals of the transition metals with the oxygen p-orbitals. Therefore, doping with anions such as nitrogen to modify the cation-anion orbital overlap is another approach to reduce the gap. Recent studies suggest that using a combination of transition metals and nitrogen as dopants is more effective at introducing intermediate states within the band gap, effectively narrowing it. Here we report the synthesis of mesoporous TiO2 spheres, co-doped with transition metals and nitrogen that exhibit a nearly flat absorbance response across the visible spectrum extending into the near infrared.

Mathis, John [Embry-Riddle Aeronautical University; Bi, Zhonghe [ORNL; Bridges, Craig A [ORNL; Kidder, Michelle [ORNL; Paranthaman, Mariappan Parans [ORNL

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

In Search of the Inverted Region: Chromophore-Based Driving Force Dependence of Interfacial Electron Transfer Reactivity at the Nanocrystalline Titanium Dioxide  

E-Print Network [OSTI]

. Introduction Dye sensitization of wide band gap semiconductor electrodes in photoelectrochemical cells can lead chromophores to function effectively as sensitizers in TiO2- based photoelectrochemical cells. The findings to significant portions of the visible spectrum.1-3 Dye sensitization also provides a scheme for inititiating

82

High-rate and low-temperature synthesis of TiO2, TiN, and TiO2/TiN/TiO2 thin films and study of their optical and interfacial characteristics  

E-Print Network [OSTI]

High-rate and low-temperature synthesis of TiO2, TiN, and TiO2/TiN/TiO2 thin films and study with unbalanced magnetrons, we deposited advanced inorganic functional thin films such as TiO2, TiN, and TiO2/Ti sputtering. The TiO2 101 and TiN 100 thin films were stoichiometric and polycrystalline but highly oriented

Boo, Jin-Hyo

83

The 2 1 reconstruction of the rutile TiO2(011) surface: A combined density functional theory, X-ray diffraction, and scanning  

E-Print Network [OSTI]

for publication 28 October 2008 Available online 5 November 2008 Keywords: Titanium dioxide Surface reconstruction exhibits two different types of undercoordinated oxygen and titanium atoms, and is, in its stoichiometric form, predicted to be rather inert towards the adsorption of probe molecules. ? 2008 Elsevier B.V. All

Diebold, Ulrike

84

Adsorption States and Mobility of TMAA Molecules on Reduced TiO2...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectroscopy (XPS) and density functional theory (DFT) studies have probed the bonding configurations and mobility of trimethylacetic acid (TMAA) molecules on TiO2(100)...

85

Three Human Cell Types Respond to Multi-Walled Carbon Nanotubes and Titanium Dioxide Nanobelts with Cell-Specific Transcriptomic and Proteomic Expression Patterns.  

SciTech Connect (OSTI)

The growing use of engineered nanoparticles (NPs) in commercial and medical applications raises the urgent need for tools that can predict NP toxicity. Global transcriptome and proteome analyses were conducted on three human cell types, exposed to two high aspect ratio NP types, to identify patterns of expression that might indicate high versus low NP toxicity. Three cell types representing the most common routes of human exposure to NPs, including macrophage-like (THP-1), small airway epithelial and intestinal (Caco-2/HT29-MTX) cells, were exposed to TiO2 nanobelts (TiO2-NB; high toxicity) and multi-walled carbon nanotubes (MWCNT; low toxicity) at low (10 g/mL) and high (100 g/mL) concentrations for 1 and 24 h. Unique patterns of gene and protein expressions were identified for each cell type, with no differentially expressed (p < 0.05, 1.5-fold change) genes or proteins overlapping across all three cell types. While unique to each cell type, the early response was primarily independent of NP type, showing similar expression patterns in response to both TiO2-NB and MWCNT. The early response might, therefore, indicate a general response to insult. In contrast, the 24 h response was unique to each NP type. The most significantly (p < 0.05) enriched biological processes in THP-1 cells indicated TiO2-NB regulation of pathways associated with inflammation, apoptosis, cell cycle arrest, DNA replication stress and genomic instability, while MWCNT-regulated pathways indicated increased cell proliferation, DNA repair and anti-apoptosis. These two distinct sets of biological pathways might, therefore, underlie cellular responses to high and low NP toxicity, respectively.

Tilton, Susan C.; Karin, Norman J.; Tolic, Ana; Xie, Yumei; Lai, Xianyin; Hamilton, Raymond F.; Waters, Katrina M.; Holian, Andrij; Witzmann, Frank A.; Orr, Galya

2014-08-01T23:59:59.000Z

86

Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries. Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For...

87

Enhanced Energy Conversion Efficiency of the Sr2+-Modified Nanoporous TiO2 Electrode Sensitized  

E-Print Network [OSTI]

efficiency achieved with dye-sensitized solar cells may be attributed to the nanoporous TiO2 electrode.3 photon to current efficiency of a solar cell based on the dye Ru[LL(NCS)2] (L ) 2,2-bipyridine-4 cell based on dye-sensitized nanoporous TiO2 thin film electrode, and power conversion efficiency

Huang, Yanyi

88

Solar Energy Materials & Solar Cells 71 (2002) 261271 Photoelectric behavior of nanocrystalline TiO2  

E-Print Network [OSTI]

. A sandwich-type solar cell fabricated by this dye-sensitized nanocrystalline TiO2 film generated 6:1 mA cm?2; Nanocrystalline TiO2; Dye sensitized solar cell; Terpyridyl ruthenium dyes; Photoelectrochemical solar cells unmatched performance in dye staff studied as solar cell sensitizer before 1997. Only recently, a black dye

Huang, Yanyi

89

Laser processing of nanocrystalline TiO2 films for dye-sensitized solar cells  

E-Print Network [OSTI]

Laser processing of nanocrystalline TiO2 films for dye-sensitized solar cells H. Kim,a) G. P­20 m thick) layers incorporated in dye-sensitized solar cells. Laser direct-write is a laser techniques to produce porous nc- TiO2 films required for dye-sensitized solar cells. The dye solar cells

Arnold, Craig B.

90

Morphological Dependence of Lithium Insertion in Nanocrystalline TiO2(B) Nanoparticles and Nanosheets  

E-Print Network [OSTI]

Morphological Dependence of Lithium Insertion in Nanocrystalline TiO2(B) Nanoparticles ABSTRACT: The lithium insertion behavior of nanoparticle (3-D) and nanosheet (2- D) architectures of TiO2(B-axis that reduces Li+ -Li+ interactions between C and A2 sites. The calculated lithiation potentials and degree

Henkelman, Graeme

91

Photocatalytic Degradation of VOC's by TOTO's Hydrotect (TiO2 Impregnated) Surfaces  

E-Print Network [OSTI]

1 Photocatalytic Degradation of VOC's by TOTO's Hydrotect (TiO2 Impregnated) Surfaces Eva Land. This report describes the photocatalytic degradation of formaldehyde and methanol, two common VOC's, by TiO2 to produce measurable gas phase concentrations. The extended UV illumination of the tiles resulted in a 50

Bergin, Mike

92

Europium-Doped TiO2 Hollow Nanoshells: Two-Photon Imaging of Cell Binding  

E-Print Network [OSTI]

Europium-Doped TiO2 Hollow Nanoshells: Two-Photon Imaging of Cell Binding Sergio Sandoval,,,§ Jian Laboratory, § Moores Cancer Center, Department of Chemistry & Biochemistry, Department of Nano method to fabricate luminescent monodisperse 200 nm europium-doped hollow TiO2 nanoshell (NS) particles

Kummel, Andrew C.

93

Sealing glasses for titanium and titanium alloys  

DOE Patents [OSTI]

Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B.sub.2 O.sub.3), barium oxide (BaO), lanthanum oxide (La.sub.2 O.sub.3), and at least one other oxide selected from the group consisting of aluminum oxide (Al.sub.2 O.sub.3), calcium oxide (CaO), lithium oxide (Li.sub.2 O), sodium oxide (Na.sub.2 O), silicon dioxide (SiO.sub.2), or titanium dioxide (TiO.sub.2). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900.degree. C., and generally about 700.degree.-800.degree. C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

1997-01-01T23:59:59.000Z

94

Sealing glasses for titanium and titanium alloys  

DOE Patents [OSTI]

Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B{sub 2}O{sub 3}), barium oxide (BaO), lanthanum oxide (La{sub 2}O{sub 3}), and at least one other oxide selected from the group consisting of aluminum oxide (Al{sub 2}O{sub 3}), calcium oxide (CaO), lithium oxide (Li{sub 2}O), sodium oxide (Na{sub 2}O), silicon dioxide (SiO{sub 2}), or titanium dioxide (TiO{sub 2}). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900 C, and generally about 700--800 C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 1 fig.

Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

1997-07-15T23:59:59.000Z

95

Breakdown Anodization (BDA) for hierarchical structures of titanium oxide  

E-Print Network [OSTI]

Breakdown Anodization (BDA) of titanium dioxide is a very promising, fast fabrication method to construct micro-scale and nano-scale structures on titanium surfaces. This method uses environmentally friendly electrolytes, ...

Choi, Soon Ju, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

96

Titanium metal: extraction to application  

SciTech Connect (OSTI)

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

Gambogi, Joseph (USGS, Reston, VA); Gerdemann, Stephen J.

2002-09-01T23:59:59.000Z

97

Increasing the Conversion Efficiency of Dye-Sensitized TiO2 Photoelectrochemical Cells by Coupling to Photonic Crystals  

E-Print Network [OSTI]

The mechanism of enhancing the light harvesting efficiency of dye-sensitized TiO2 solar cells by coupling TiO2Increasing the Conversion Efficiency of Dye-Sensitized TiO2 Photoelectrochemical Cells by Coupling to conventional single-crystal solar cells. In this cell, an optically excited dye injects electrons

98

DOI: 10.1002/asia.201200349 Dye-Sensitized TiO2 Nanotube Solar Cells: Rational Structural and Surface  

E-Print Network [OSTI]

DOI: 10.1002/asia.201200349 Dye-Sensitized TiO2 Nanotube Solar Cells: Rational Structural employed to substitute TiO2 nanoparticles for use in dye-sensitized solar cells. To fur- ther improve the performance of dye-sensitized TiO2 nanotube solar cells, efforts have been directed toward the optimization

Lin, Zhiqun

99

Synthesis and structure of Al clusters supported on TiO2,,110...: A scanning tunneling microscopy study  

E-Print Network [OSTI]

Synthesis and structure of Al clusters supported on TiO2,,110...: A scanning tunneling microscopy, Texas 77843-3255 Received 14 October 1997; accepted 6 April 1998 Al clusters supported on TiO2(110) have been investigated using scanning tunneling microscopy. Al interacts strongly with the TiO2(110) surface

Goodman, Wayne

100

A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed on MCM-48  

E-Print Network [OSTI]

A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed.932), suggesting the formation of oxygen vacancies. The fraction of Ti that could be reduced increased with TiO2 the TiO2 overlayer as the size of the titania patches increases. The amount of oxygen removed during

Bell, Alexis

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Tuning the Optical Properties of Mesoporous TiO2 Films by Nanoscale Engineering  

SciTech Connect (OSTI)

Introducing mesoscale pores into spincoated titanium dioxide films, prepared by spincoating different sol-gel precursor solutions on silicon substrates and subsequent annealing at 350 C, 400 C or 450 C, respectively, affects several optical properties of the material. The change in refractive index observed for different mesoporous anatase films directly correlates with changes in pore size, but is also in a more complex manner influenced by the film thickness and the density of pores within the films. Additionally, the band gap of the films is blueshifted by the stress the introduction of pores exerts on the inorganic matrix. The differently sized pores were templated by Pluronic{reg_sign} block copolymers in the solgel solutions and tuned by employing different annealing temperatures for the film preparation. This study focused on elucidating the effect different templating materials (F127 and P123) have on the pore size of the final mesoporous titania film, and on understanding the relation of varying polymer concentration (taking P123 as an example) in the sol-gel solution to the pore concentration and size in the resultant titania film. Titania thin film samples or corresponding titanium dioxide powders were characterized by X-ray diffraction, nitrogen adsorption, ellipsometery, UV/Vis spectrometry and other techniques to understand the interplay between mesoporosity and optical properties.

Schwenzer, Birgit; Wang, Liang; Swensen, James S.; Padmaperuma, Asanga B.; Silverman, Gary; Korotkov, Roman; Gaspar, Daniel J.

2012-07-03T23:59:59.000Z

102

Low cost titanium--myth or reality  

SciTech Connect (OSTI)

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium, and titanium cost has prevented its use in non-aerospace applications including the automotive and heavy vehicle industries.

Turner, Paul C.; Hartman, Alan D.; Hansen, Jeffrey S.; Gerdemann, Stephen J.

2001-01-01T23:59:59.000Z

103

E-Print Network 3.0 - anatase tio2 nanotubes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

nanotubes Search Powered by Explorit Topic List Advanced Search Sample search results for: anatase tio2 nanotubes Page: << < 1 2 3 4 5 > >> 1 Solid State Communications 141 (2007)...

104

Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110)  

SciTech Connect (OSTI)

Understanding hydrogen formation on TiO2 surfaces is of great importance as it could provide fundamental insight into water splitting for hydrogen production using solar energy. In this work, hydrogen formation from glycols having different numbers of methyl end-groups have been studied using temperature pro-grammed desorption on reduced, hydroxylated, and oxidized TiO2(110) surfaces. The results from OD-labeled glycols demon-strate that gas-phase molecular hydrogen originates exclusively from glycol hydroxyl groups. The yield is controlled by a combi-nation of glycol coverage, steric hindrance, TiO2(110) order and the amount of subsurface charge. Combined, these results show that proximal pairs of hydroxyl aligned glycol molecules and subsurface charge are required to maximize the yield of this redox reaction. These findings highlight the importance of geometric and electronic effects in hydrogen formation from adsorbates on TiO2(110).

Chen, Long; Li, Zhenjun; Smith, R. Scott; Kay, Bruce D.; Dohnalek, Zdenek

2014-04-16T23:59:59.000Z

105

EPR Study of the Surface Characteristics of Nanostructured TiO2 under UV Irradiation  

E-Print Network [OSTI]

EPR Study of the Surface Characteristics of Nanostructured TiO2 under UV Irradiation Juan M of EPR spectroscopy. The samples of the H series present the smallest crystallite size and after

106

Vacancy Assisted Diffusion of Alkoxy Species on Rutile TiO2(110...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

vacancy sites. For reduced rutile TiO2(110)-11, the bridge-bonded oxygen (BBO) vacancies (BBOVs) are the most prevalent surface defects and, as has been shown, they...

107

Porous TiO2 microspheres with tunable properties for photocatalytic air purification Alberto Naldoni a,  

E-Print Network [OSTI]

, continuous operation, facile scale-up process from small to large production, and thorough control overPorous TiO2 microspheres with tunable properties for photocatalytic air purification Alberto

Suslick, Kenneth S.

108

Ultrafast Photooxidation of Mn(II)-Terpyridine Complexes Covalently Attached to TiO2 Nanoparticles  

E-Print Network [OSTI]

-energy conversion by dye-sensitized solar cells,1,2 photocatalysis,3-6 and molecular electronics.7,8 Most previous-cost, high-efficiency solar cell based on Ru-dye sensitization of colloidal TiO2 films.1 Presently, the most studies have been focused on TiO2 nanoparticles sensitized with Ru dyes,9,10 although IET in other

109

ELSEVIER Journal of ElectronSpectroscopyand Related Phenomena 73 (1995) 1-11 ELECTRON SPECTROSCOPY  

E-Print Network [OSTI]

1994;in finalform 9 August 1994 Abstract The adsorption of titanium on titanium dioxide TiO2(110) has SPECTROSCOPY andRelatedPhenomena Titanium and reduced titania overlayers on titanium dioxide(110) J.T. Mayer a spectroscopy I. Introduction Titanium dioxide has received extensive attention in the surface science community

Diebold, Ulrike

110

Cr, N-Codoped TiO2 Mesoporous Microspheres for Li-ion Rechargeable Batteries with Enhanced Electrochemical Performance  

SciTech Connect (OSTI)

Cr,N-codoped TiO2 mesoporous microspheres synthesized using hydrothermal and subsequent nitridation treatment, exhibited higher solubility of nitrogen, and improved electrical conductivity than N-doped TiO2, as anode for Lithium-ion rechargeable batteries, which led to improving charge-discharge capacity at 0.1 C and twice higher rate capability compared to that of nitrogen-doped TiO2 mesoporous microsphere at 10 C

Bi, Zhonghe [ORNL] [ORNL; Paranthaman, Mariappan Parans [ORNL] [ORNL; Guo, Bingkun [ORNL] [ORNL; Unocic, Raymond R [ORNL] [ORNL; Meyer III, Harry M [ORNL] [ORNL; Bridges, Craig A [ORNL] [ORNL; Sun, Xiao-Guang [ORNL] [ORNL; Dai, Sheng [ORNL] [ORNL

2014-01-01T23:59:59.000Z

111

Improved Lithium Ion Behavior Properties of TiO2@Graphitic-like Carbon Core@Shell Nanostructure  

E-Print Network [OSTI]

Improved Lithium Ion Behavior Properties of TiO2@Graphitic-like Carbon Core@Shell Nanostructure Min Intercalation Electrochemistry Capacitance Lithium Ion batteries A B S T R A C T We demonstrate TiO2@graphitic on the electrode surface and enhanced lithium ion intercalation, leading to lower charge transfer resistance

Cao, Guozhong

112

Oriented Hierarchical Porous TiO2 Nanowires on Ti Substrate: Evolution of Nanostructures for Dye-Sensitized Solar Cells  

E-Print Network [OSTI]

of highly-oriented anatase TiO2 nanocrystals, are adopted as photoelectrodes in dye-sensitized solar cells. [1­4]. In particular, lightweight and flexible dye-sensitized solar cells (DSSCs) have received muchOriented Hierarchical Porous TiO2 Nanowires on Ti Substrate: Evolution of Nanostructures for Dye-Sensitized

Park, Byungwoo

113

Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation of  

E-Print Network [OSTI]

Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation that an alizarin red S ~ARS! dye coating on TiO2 nanoparticles enables visible light activation of reactive oxygen species. Successful coating of nanoparti- cles with dye is demonstrated through

Brown, Eric

114

Predicting New TiO2 Phases with Low Band Gaps by a Multiobjective Global Optimization Approach  

E-Print Network [OSTI]

stable. This is equivalent to a global optimization problem of a biobjective function, i.e., total energyPredicting New TiO2 Phases with Low Band Gaps by a Multiobjective Global Optimization Approach Hou as a novel global optimization algorithm to predict new polymorphs of bulk TiO2 with better optical

Gong, Xingao

115

Enhanced Photovoltaic Performance of Nanostructured Hybrid Solar Cell Using Highly Oriented TiO2 Nanotubes  

E-Print Network [OSTI]

-called third generation of solar cells including dye-sensitized solar cells, DSCs2,3 and organic phoEnhanced Photovoltaic Performance of Nanostructured Hybrid Solar Cell Using Highly Oriented TiO2 nanotubes can be effectively controlled for the suitable use for a hybrid solar cell by varying the diameter

Cao, Guozhong

116

Hierarchical TiO2Si nanowire architecture with photoelectrochemical activity under visible light illumination  

E-Print Network [OSTI]

systems are currently less competitive than common solar panels, which to a great extent limits decoration approach opens a new window to tailoring electrical properties of TiO2 for wider spectrum solar energy harvesting and conversion. Owing to the abundance, cleanness, potentially low-cost

Wang, Xudong

117

Dopant location identification in Nd3+ -doped TiO2 nanoparticles  

E-Print Network [OSTI]

Dopant location identification in Nd3+ -doped TiO2 nanoparticles W. Li Department of Materials. The identification of dopant position and its local environ- ment are essential to explore the effect of doping. X and Technology, Gaithersburg, Maryland 20899, USA C. Ni Department of Materials Science and Engineering

Frenkel, Anatoly

118

Absorption Spectra Related to Heterogeneous Electron Transfer Reactions: The Perylene TiO2 System  

E-Print Network [OSTI]

Absorption Spectra Related to Heterogeneous Electron Transfer Reactions: The Perylene TiO2 System Form: March 16, 2005 Linear absorption spectra of dye-semiconductor systems (perylene attached displaying line broadenings follow the qualitative trend obtained from transient absorption spectra. I

Röder, Beate

119

Optical excitations of metallic nanoclusters buried in TiO2 for solar photochemistry  

E-Print Network [OSTI]

to the solar spectrum.3 A natural dielectric to consider is to encapsulate these metal clusters supported on TiOptical excitations of metallic nanoclusters buried in TiO2 for solar photochemistry Fei WangV range, a much better match to the solar spectrum than the 3.8 eV Ag plasmon. AFM measurements indicate

120

Available online at www.sciencedirect.com Talanta 74 (2008) 14141419  

E-Print Network [OSTI]

synthesized, such as TiO2, ZnO, ZrO2, Al2O3 and so on [11­14]. Titanium dioxide is a widely used, inorganic 2007 Available online 29 September 2007 Abstract Titanium oxide nanotubes (TiO2-NTs) synthesized B.V. All rights reserved. Keywords: Titanium oxide nanotubes; Hemoglobin; Electrochemistry; Hydrogen

Zheng, Yufeng

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Understanding of catalytic behaviors of TiO2/CuOx catalysts  

SciTech Connect (OSTI)

Aiming to reveal the catalysis at the metal-oxide and oxide-oxide interfaces,1,2 the water-gas shift reaction (WGS, CO + H2O and #61664; CO2 + H2) and CO oxidation (2CO + O2 and #61664; 2CO2) at the interface of the Cu(111) and Cu2O(111) supported TiO2 clusters were studied based on DFT calculations

Kim H. Y.; Liu, P.

2013-09-08T23:59:59.000Z

122

Band Offsets at the Epitaxial Anatase TiO2/n-SrTiO3(001) Interface...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to measure valence band offsets at the epitaxial anatase TiO2(002)n-SrTiO3(001) heterojunction prepared by molecular beam epitaxy, Within experimental error, the valance band...

123

Patterned Growth of TiO2 Nanowires on Titanium Substrates Jong-Yoon Ha1;2  

E-Print Network [OSTI]

and short processing time utilizes the Ti foil both as a substrate and as a metal supply, thus eliminating transport methods. Adachi et al. have reported the synthesis of titania NWs using hydrothermal reactions, these methods typically require complex setups and processes, harsh environmental conditions, and extended

Lin, Liwei

124

Photooxidation of Acetone on TiO2(110): Conversion to Acetate via Methyl  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 TheStevenAdministrationPhotometric Variations4TiO2(110).

125

Seoul National UniversitySeoul National University http://bp.snu.ac.kr1 The Effect of TiCl4-Treated TiO2  

E-Print Network [OSTI]

TiO2 Compact Layer on the Performance of Dye-Sensitized Solar Cell #12;Seoul National UniversitySeoul National University http://bp.snu.ac.kr Dye-Sensitized Solar Cell 2 Schematic Diagram of the Electron Flow by the TiO2 compact layer. Electrolyte Hydrolysis of TiCl4 Solution Dye-Coated TiO2 Back Electron Transfere

Park, Byungwoo

126

On the consistency of QCBED structure factor measurements for TiO2 (Rutile)  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The same Bragg reflection in TiO2 from twelve different CBED patterns (from different crystals, orientations and thicknesses) are analysed quantitatively in order to evaluate the consistency of the QCBED method for bond-charge mapping. The standard deviation in the resulting distribution of derived X-ray structure factors is found to be an order of magnitude smaller than that in conventional X-ray work , and the standard error (0.026% for FX(110)) is slightly better than obtained by the X-ray Pendellosung method applied to silicon. This is sufficiently accuracy to distinguish between atomic, covalent and ionic models of bonding. We describe the importance of extracting experimental parameters from CCD camera characterization, and of surface oxidation and crystal shape. The current experiments show that the QCBED method is now a robust and powerful tool for low order structure factor measurement, which does not suffer from the large extinction (multiple scattering) errors which occur in inorganic X-ray crystallography, and may be applied to nanocrystals. Our results will be used to understand the role of d electrons in the chemical bonding of TiO2.

Spence, J.C.H [Arizona State University; Friis, J. [Norwegian University of Science and Technology; Zuo, J.M [University of Illinois, Urbana, IL; Jiang, B.

2003-10-01T23:59:59.000Z

127

Surface Science Perspectives Dispersed Au atoms, supported on TiO2(110)  

E-Print Network [OSTI]

activation energy for the oxidation of carbon monoxide? Many factors could con- tribute. For example); Catalysis; Gold; Titanium oxide; Surface defects At the end of the 1980s Haruta and coworkers made

Diebold, Ulrike

128

The Materials Science of Titanium Dioxide Memristors  

E-Print Network [OSTI]

Park, D. -j. Seong, W. Lee, M. Hasan, G. - Y. Jung, and H.vol. 93, no. 22, [38] M. Hasan, R. Dong, H. J. Choi, D. S.for switching in SrTiO 3 . Hasan et al. also used pulsed

Pickett, Matthew

2010-01-01T23:59:59.000Z

129

The Materials Science of Titanium Dioxide Memristors  

E-Print Network [OSTI]

which causes current-voltage oscillations. The confusion isoscillations were dependent on both the applied DC voltage andsustained oscillations when biased with a DC voltage based

Pickett, Matthew

2010-01-01T23:59:59.000Z

130

A Highly Efficient Solar Cell Made from a Dye-Modified ZnO-Covered TiO2 Nanoporous Electrode  

E-Print Network [OSTI]

-circuit photovoltage. Introduction Overall power conversion efficiency1,2 reaching 10% for dye sensitized solar cellA Highly Efficient Solar Cell Made from a Dye-Modified ZnO-Covered TiO2 Nanoporous Electrode Zhong A photoelectrochemical solar cell based on porous ZnO-covered TiO2 film has been fabricated with ruthenium bipyridyl

Huang, Yanyi

131

Effect of the Presence of Iodide on the Electron Injection Dynamics of Dye-Sensitized TiO2-Based Solar Cells  

E-Print Network [OSTI]

dynamics of dye-sensitized TiO2-based solar cells have been investigated to determine the effectsEffect of the Presence of Iodide on the Electron Injection Dynamics of Dye-Sensitized TiO2-Based Solar Cells Amanda L. Smeigh, Jordan E. Katz, Bruce S. Brunschwig,*,,§ Nathan S. Lewis,*, and James K

McCusker, James K.

132

Describing excited state relaxation and localization in TiO2 nanoparticles using TD-DFT  

SciTech Connect (OSTI)

We have investigated the description of excited state relaxation in naked and hydrated TiO2 nanoparticles using Time-Dependent Density Functional Theory (TD-DFT) with three common hybrid exchange-correlation (XC) potentials; B3LYP, CAM-B3LYP and BHLYP. Use of TD-CAM-B3LYP and TD-BHLYP yields qualitatively similar results for all structures, which are also consistent with predictions of coupled cluster theory for small particles. TD-B3LYP, in contrast, is found to make rather different predictions; including apparent conical intersections for certain particles that are not observed with TD-CAM-B3LYP nor with TD-BHLYP. In line with our previous observations for vertical excitations, the issue with TD-B3LYP appears to be the inherent tendency of TD-B3LYP, and other XC potentials with no or a low percentage of Hartree-Fock Like Exchange, to spuriously stabilize the energy of charge-transfer (CT) states. Even in the case of hydrated particles, for which vertical excitations are generally well described with all XC potentials, the use of TD-B3LYP appears to result in CT-problems for certain particles. We hypothesize that the spurious stabilization of CT-states by TD-B3LYP even may drive the excited state optimizations to different excited state geometries than those obtained using TD-CAM-B3LYP or TD-BHLYP. Finally, focusing on the TD-CAM-B3LYP and TD-BHLYP results, excited state relaxation in naked and hydrated TiO2 nanoparticles is predicted to be associated with a large Stokes shift.

Berardo, Enrico; Hu, Hanshi; van Dam, Hubertus JJ; Shevlin, S. A.; Woodley, Scott M.; Kowalski, Karol; Zwijnenburg, Martijn A.

2014-10-30T23:59:59.000Z

133

Performance enhancement of TiO2-based dye-sensitized solar cells by carbon nanospheres in photoanode  

E-Print Network [OSTI]

The conversion efficiency of dye-sensitized solar cells (DSSCs) is optimized by modifying the optical design and improving absorbance within the cell. These objectives are obtained by creating different sized cavities in TiO2 photoanode. For this purpose, carbon nanospheres with diameters 100-600 nm are synthesized by hydrothermal method. A paste of TiO2 is mixed with various amounts of carbon nanospheres. During TiO2 photoanode sintering processes at 500C temperature, the carbon nanospheres are removed. This leads to random creation of cavities in the DSSCs photoanode. These cavities enhance light scattering and porosity which improve light absorbance by dye N719 and provide a larger surface area for dye loading. These consequences enhance performance of DSSCs. By mixing 3% Wt. carbon nanospheres in the TiO2 pastes, we were able to increase the short circuit current density and efficiency by 40% (from 12.59 to 17.73 mA/cm2) and 33% (from 5.72% to 7.59%), respectively.

Bayatloo, Elham; Polkoo, Sajad Saghaye

2013-01-01T23:59:59.000Z

134

Time-Domain ab Initio Study of Charge Relaxation and Recombination in Dye-Sensitized TiO2  

E-Print Network [OSTI]

with surface hopping in the Kohn-Sham basis. Representing the dye-sensitized semiconductor Gra¨tzel cellTime-Domain ab Initio Study of Charge Relaxation and Recombination in Dye-Sensitized TiO2 Walter R understanding of these processes is crucial for improving solar cell design and optimizing photovoltaic current

135

Ambipolar Diffusion of Photocarriers in Electrolyte-Filled, Nanoporous TiO2 N. Kopidakis and E. A. Schiff*  

E-Print Network [OSTI]

, 1999 We report transient photocurrent measurements on solar cell structures based on dye-sensitized and by O'Regan and Gra¨tzel's demonstration of a remarkably efficient photoelectrochemical solar cell based on dye-sensitized, nanoporous TiO2.5 In this paper, we present transient photocurrent measurements

Schiff, Eric A.

136

Charge Transport Limitations in Self-Assembled TiO2 Photoanodes for Dye-Sensitized Solar Cells  

E-Print Network [OSTI]

Charge Transport Limitations in Self-Assembled TiO2 Photoanodes for Dye-Sensitized Solar Cells and Storage; Energy and Charge Transport The dye-sensitized solar cell (DSC) has attracted wide- spread. Thomson Avenue, Cambridge, CB3 0HE, United Kingdom *S Supporting Information ABSTRACT: Solid-state dye-sensitized

Steiner, Ullrich

137

Charge Transport Properties in TiO2 Network with Different Particle Sizes for Dye Sensitized Solar Cells  

E-Print Network [OSTI]

the large improvement in performance of dye sensitized solar cells (DSCs) achieved in 1991, mesoporousCharge Transport Properties in TiO2 Network with Different Particle Sizes for Dye Sensitized Solar sensitized solar cells, nanoparticle size, impedance, charge transport properties INTRODUCTION Since

Cao, Guozhong

138

Rate Characteristics of Anatase TiO2 Nanotubes and Nanorods for Lithium Battery Anode Materials at Room  

E-Print Network [OSTI]

ratio.11 Repulsive Coulombic interactions be- tween lithium ions are expected to be responsibleRate Characteristics of Anatase TiO2 Nanotubes and Nanorods for Lithium Battery Anode Materials for lithium content to x = 0.7. Li surface storage on nanometer-sized particles can be energetically more

Cho, Jaephil

139

182 IEEE TRANSACTIONS ON NANOTECHNOLOGY, VOL. 12, NO. 2, MARCH 2013 Monitoring the Environmental Impact of TiO2  

E-Print Network [OSTI]

the potential environmental impact of these nanoparticles. The goal of this research was to de- velop a plant-based sensor network for characterizing, monitoring, and understanding the environmental impact of TiO2 impact of nanomaterials. Index Terms--Biosystems, environmental monitoring, nanobio- science

Parker, Lynne E.

140

Temperature Independence of the Photoinduced Electron Injection in Dye-Sensitized TiO2 Rationalized by Ab Initio  

E-Print Network [OSTI]

electron transfer (ET) in dye-sensitized semiconductor solar cells [J. Am. Chem. Soc. 2005, 127, 18234; IsrTemperature Independence of the Photoinduced Electron Injection in Dye-Sensitized TiO2 Rationalized) between a chro- mophore and an inorganic semiconductor creates the initial charge separation in the dye-sensitized

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Figure 1: Functionalization of TiO2 by anhydrous chemical vapor deposition of trifunctional siloxane adsorbates.  

E-Print Network [OSTI]

siloxanes form only 2 covalent bonds, in a `bridge' mode with adjacent Ti4+ ions on the TiO2 surface of binding enthalpies at the DFT B3LYP/(LACVP/6-31G**) level of theory indicating that the `bridge' binding optical, electrical, magnetic and mechanical properties of semiconductor materials. For example, dye

142

19.2% Efficient InP Heterojunction Solar Cell with Electron-Selective TiO2 Contact  

E-Print Network [OSTI]

19.2% Efficient InP Heterojunction Solar Cell with Electron-Selective TiO2 Contact Xingtian Yin of California, Berkeley, California 94720, United States Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States § Electronic Materials Research Laboratory

Javey, Ali

143

Chemically grown TiO2 on glass with superior photocatalytic properties G. Kenanakis a,b,  

E-Print Network [OSTI]

suspensions or in small-scale purification systems, thus limiting their practical use due to difficulties of photocatalysis for various applications such as water treatment, air purification and fuel cells [1­5]. TiO2 techniques [8­10]. Since then, many large scale deposition techniques, such as doctor blade and spray coating

144

Bisphosphine dioxides  

DOE Patents [OSTI]

A process for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

Moloy, Kenneth G. (Charleston, WV)

1990-01-01T23:59:59.000Z

145

Bisphosphine dioxides  

DOE Patents [OSTI]

A process is described for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

Moloy, K.G.

1990-02-20T23:59:59.000Z

146

Composite materials and bodies including silicon carbide and titanium diboride and methods of forming same  

DOE Patents [OSTI]

Methods of forming composite materials include coating particles of titanium dioxide with a substance including boron (e.g., boron carbide) and a substance including carbon, and reacting the titanium dioxide with the substance including boron and the substance including carbon to form titanium diboride. The methods may be used to form ceramic composite bodies and materials, such as, for example, a ceramic composite body or material including silicon carbide and titanium diboride. Such bodies and materials may be used as armor bodies and armor materials. Such methods may include forming a green body and sintering the green body to a desirable final density. Green bodies formed in accordance with such methods may include particles comprising titanium dioxide and a coating at least partially covering exterior surfaces thereof, the coating comprising a substance including boron (e.g., boron carbide) and a substance including carbon.

Lillo, Thomas M.; Chu, Henry S.; Harrison, William M.; Bailey, Derek

2013-01-22T23:59:59.000Z

147

Non-solvolytic synthesis of aqueous soluble TiO2 nanoparticles and real-time dynamic measurements of the nanoparticle formation  

E-Print Network [OSTI]

-Cryst Solids 1997, 220:202209. 15. Qiao QQ, Mcleskey JT: Water-soluble polythiophene/nanocrystalline TiO2 solar cells. Appl Phys 2005, 86:153501153505. 16. Bach U, Lupo D, Comte P, Moser JE, Weissortel F, Salbeck J, Spreitzer H, Gratzel M: Solid-state dye-sensitized... mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies. Nature 1998, 395:583585. 17. Oregan B, Gratzel M: A low-cost, high-efficiency solar-cell based on dye- sensitized colloidal TiO2 films. Nature 1991, 353:737740. 18. Morris GE...

Chen, Lan; Rahme, Kamil; Holmes, Justin D; Morris, Michael A; Slater, Nigel KH

2012-06-07T23:59:59.000Z

148

Solid State Solar Cells Based On Tio2 Sensitized With Natural Pigment Extracted From the Anthurium  

E-Print Network [OSTI]

Abstract: The purpose of this experiment was to create functional dye-sensitized solid state solar cells using natural pigments extracted from the blood red Anthurium as the electron donating species. Natural dye was extracted and adsorbed onto a nano-porous titania substrate. Platinum coated glass was used as the counter electrode. The cells were prepared using drop coating method to get a thickness around 10?m using 25 nm size TiO2 particles. Using the extracted natural dye we have been able to obtain high efficiencies with CuSCN over CuI hole conductor. The prepared cells show open circuit voltage (Voc) of 0.46 V and 0.43 of fill factor (FF) with an overall efficiency (?) of 0.34 % for CuSCN over the CuI hole conductor. Nevertheless short circuit current density (Jsc) was 2.37 mA cm-2 for CuI, it was 1.73 mA cm-2 for CuSCN. Key words: Dye Sensitized Solid State Solar Cells, Cyanidin, Anthurium, hole conductor. 1.

G. R. A. Kumara

149

The role of vacancies, impurities and crystal structure in the magnetic properties of TiO2  

E-Print Network [OSTI]

We present an ab initio study of pure and doped TiO2 in the rutile and anatase phases. The main purpose of this work is to determine the role played by different defects and different crystal structures in the appearance of magnetic order. The calculations were performed for varying impurity and vacancy concentrations in both TiO2 structures. For Co impurities the local magnetic moment remained almost independent of the concentration and distribution while for Cu this is not the case, there is magnetism for low concentrations that disappears for the higher ones. Impurity-impurity interactions in both structures favor linear ordering of them. Magnetism in un-doped samples appears for certain vacancy concentrations and structural strain.

Mariana Weissmann; Leonardo A. Errico

2007-04-20T23:59:59.000Z

150

Determination of titanium and iron in ilmenite ores by cerate titrimetry  

E-Print Network [OSTI]

which provided for: (1) flushing of the solution with carbon dioxide to remove air snd, (2) quick, easy removal of the sine amalgam before titration. After reduction, a quantitative determination of titanium and iron in the solution was made... complete contact with the melt. Cool, add 100 milliliters of water, and boil for 15 minutes. Add 500 milliliters of water snd place in an ice bath. Decant the supernatant liquid off the voluminous, white~ crystalline titanium dioxide precipitate...

Gainer, Alvis Beryl

1959-01-01T23:59:59.000Z

151

Efficient band alignment for ZnxCd1xSe QD-sensitized TiO2 solar cells  

E-Print Network [OSTI]

the signicant breakthrough in dye-sensitized solar cells (DSSCs) was rst reported by O'Regan and GrEfficient band alignment for ZnxCd1?xSe QD-sensitized TiO2 solar cells Lin Yang,ab Ru Zhou,a Jolin photoelectrodes for solar cells. In the fabricated QDs sensitized solar cells, QDs with the composition of x ¼ 0

Cao, Guozhong

152

Equivalent Circuit Description of Non-compensated n-p Codoped TiO2 as Intermediate Band Solar Cells  

E-Print Network [OSTI]

The novel concept of non-compensated n-p codoping has made it possible to create tunable intermediate bands in the intrinsic band gap of TiO2, making the codoped TiO2 a promising material for developing intermediate band solar cells (IBSCs). Here we investigate the quantum efficiency of such IBSCs within two scenarios - with and without current extracted from the extended intermediate band. Using the ideal equivalent circuit model, we find that the maximum efficiency of 57% in the first scenario and 53% in the second are both much higher than the Shockley-Queisser limit from single gap solar cells. We also obtain various key quantities of the circuits, a useful step in realistic development of TiO2 based solar cells invoking device integration. These equivalent circuit results are also compared with the efficiencies obtained directly from consideration of electron transition between the energy bands, and both approaches reveal the intriguing existence of double peaks in the maximum quantum efficiency as a function of the relative location of IBs.

Tian-Li Feng; Guang-Wei Deng; Yi Xia; Feng-Cheng Wu; Ping Cui; Hai-Ping Lan; Zhen-Yu Zhang

2010-12-09T23:59:59.000Z

153

Equivalent Circuit Description of Non-compensated n-p Codoped TiO2 as Intermediate Band Solar Cells  

E-Print Network [OSTI]

The novel concept of non-compensated n-p codoping has made it possible to create tunable intermediate bands in the intrinsic band gap of TiO2, making the codoped TiO2 a promising material for developing intermediate band solar cells (IBSCs). Here we investigate the quantum efficiency of such IBSCs within two scenarios - with and without current extracted from the extended intermediate band. Using the ideal equivalent circuit model, we find that the maximum efficiency of 57% in the first scenario and 53% in the second are both much higher than the Shockley-Queisser limit from single gap solar cells. We also obtain various key quantities of the circuits, a useful step in realistic development of TiO2 based solar cells invoking device integration. These equivalent circuit results are also compared with the efficiencies obtained directly from consideration of electron transition between the energy bands, and both approaches reveal the intriguing existence of double peaks in the maximum quantum efficiency as a fun...

Feng, Tian-Li; Xia, Yi; Wu, Feng-Cheng; Cui, Ping; Lan, Hai-Ping; Zhang, Zhen-Yu

2010-01-01T23:59:59.000Z

154

ARTICLE IN PRESS Aerosol and Air Quality Research, x: 1-10, xxxx  

E-Print Network [OSTI]

sorbent, titanium dioxide (TiO2) used with UV irradiation, was evaluated in a laboratory-scale coal distance before being deposited on the land and water, where it may eventually enter the food chain

Li, Ying

155

U.S. GEOLOGICAL SURVEY--MINERALS INFORMATION--1997 1 By Joseph Gambogi  

E-Print Network [OSTI]

, and plastics. Titanium dioxide pigment is characterized by its purity, refractive index, particle size and brightness. Following a flat year of demand growth, global demand for TiO2 pigment increased about 5% in 1997

156

Abatement of 3-methylbutanal and trimethylamine with combined plasma1 and photocatalysisin a continuous planar reactor2  

E-Print Network [OSTI]

titanium dioxide (TiO2) and the gas phase [9, 40, 42, 43]. The catalyst47 is activated by photons provided[5], combustion [6], adsorption [7], absorption and44 photocatalysis [3, 8,14, 39, 40, 42

Paris-Sud XI, Université de

157

Electronic and transport properties of reduced and oxidized nanocrystalline A. Rothschilda)  

E-Print Network [OSTI]

. © 2003 American Institute of Physics. DOI: 10.1063/1.1539556 Nanocrystalline titanium dioxide (TiO2) has- tive to gas adsorption. A correlation between the surface and GB potential bar- riers

Shapira, Yoram

158

Journal of Catalysis 202, 413420 (2001) doi:10.1006/jcat.2001.3301, available online at http://www.idealibrary.com on  

E-Print Network [OSTI]

Academic Press Key Words: photocatalysis; nanoparticles; titanium dioxide; toluene; volatile organic. The nanostructured TiO2 provides a larger surface area for adsorption and decomposition of VOC. Quantum size effects

159

Surface characterization studies of TiO2 supported manganese oxide catalysts for low temperature SCR of NO with NH3  

E-Print Network [OSTI]

through the scrubber and the electrostatic precipitator or bag-house [5]. The advantages of tail 6 May 2007 Abstract A series of TiO2 supported manganese oxide catalysts were prepared by wet

Boolchand, Punit

160

Solar Energy Materials & Solar Cells 87 (2005) 181196 Optical filters from SiO2 and TiO2 multi-layers  

E-Print Network [OSTI]

Solar Energy Materials & Solar Cells 87 (2005) 181­196 Optical filters from SiO2 and TiO2 multi Abstract Sol­gel spin coating process is used to produce optical filters from SiO2 and TiO2 multi- layers­19] properties. They vary according to the chosen substrate, sol, central wavelength, number of layers, optical

Thirumalai, Devarajan

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Mesoporous TiO2 beads for high efficiency CdS/ CdSe quantum dot co-sensitized solar cells  

E-Print Network [OSTI]

) as a derivative of dye-sensitized solar cells (DSCs) have attracted considerable attention and been regardedMesoporous TiO2 beads for high efficiency CdS/ CdSe quantum dot co-sensitized solar cells Ru Zhou for a CdS/CdSe quantum dot (QD) co-sensitized solar cell, which was constructed with the mesoporous TiO2

Cao, Guozhong

162

Conversion of 1,3-Propylene Glycol on Rutile TiO2(110)  

SciTech Connect (OSTI)

The adsorption of 1,3-propylene glycol (1,3-PG) on partially reduced TiO2(110) and its conversion to products have been studied by a combination of molecular beam dosing and temperature programmed desorption (TPD). When the Ti surface sites are saturated by 1,3-PG, ~80% of the molecules undergo further reactions to yield products that are liberated during the TPD ramp. In contrast to ethylene glycol (EG) and 1,2- propylene glycol (1,2-PG) that yield only alkenes and water at very low coverages (< 0.05 ML), two additional products, HCHO and C2H4, along with propylene (CH3CHCH2) and water are observed for 1,3-PG. Identical TPD line shapes and desorption yields for HCHO and C2H4 suggest that these products result from C-C bond cleavage and are coupled. At higher 1,3-PG coverages (> 0.1 ML), propanal (CH3CH2CHO) and two additional products, 1-propanol (CH3CH2CH2OH) and acrolein (CH2CHCHO), are observed. The desorption of 1-propanol is found to be coupled with the desorption of acrolein, suggesting that these products are formed by the disproportionation of two 1,3-PG molecules. The coverage dependent TPD results further show that propylene formation dominates at low coverages (< 0.3 ML), while the decomposition and disproportionation channels increase rapidly at higher coverages and reach yields comparable to that of propylene at the 1,3-PG saturation coverage of 0.5 ML. The observed surface chemistry clearly shows how the molecular structure of glycols influences their reaction pathways on oxide surfaces.

Chen, Long; Li, Zhenjun; Smith, R. Scott; Kay, Bruce D.; Dohnalek, Zdenek

2014-10-09T23:59:59.000Z

163

Titanium hermetic seals  

DOE Patents [OSTI]

Titanium is prenitrided by being heated in a nitrogen environment under conditions which give rise to the formation of a titanium-nitride surface layer on the titanium. Titanium thus prenitrided may be used in electrical components which are hermetically sealed using silicate glasses and standard glass sealing techniques. According to the method of the invention, alkali volatilization and formation of deleterious interfacial silicide are inhibited.

Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Tijeras, NM)

1995-01-01T23:59:59.000Z

164

Sealing glasses for titanium and titanium alloys  

DOE Patents [OSTI]

Glass compositions containing CaO, Al/sub 2/O/sub 3/, B/sub 2/O/sub 3/, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

Brow, R.K.; Watkins, R.D.

1988-01-21T23:59:59.000Z

165

Sealing glasses for titanium and titanium alloys  

DOE Patents [OSTI]

Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Albuquerque, NM)

1992-01-01T23:59:59.000Z

166

Off-normal CO2 desorption from the photooxidation of CO on reduced TiO2(110)  

SciTech Connect (OSTI)

Photo-induced reactions between O2 and CO on reduced rutile TiO2(110) are studied at low temperature (~30K). Photon stimulated desorption (PSD) of O2, CO2 and CO are observed with comparable yields. Isotope labeling experiments indicate that O2 chemisorbed in a vacancy is more active for photooxidation than O2 chemisorbed on a Ti5c site. The angular distribution for the desorbing CO2 is peaked at ~40 with respect to the surface normal in the azimuth (i.e. perpendicular to the bridging oxygen rows) suggesting that CO2 is produced from O2 occupying an oxygen vacancy and CO adsorbed on a Ti5c site next to it. The experimental results are consistent with CO2 being produced from a transition state complex that has been predicted theoretically. The CO PSD from TiO2(110) is enhanced dramatically by the presence of chemisorbed O2 suggesting that it is a by-product of the CO photooxidation process.

Petrik, Nikolay G.; Kimmel, Gregory A.

2010-09-02T23:59:59.000Z

167

PHYSICAL REVIEW B 84, 245115 (2011) Electronic structure of dye-sensitized TiO2 clusters from many-body perturbation theory  

E-Print Network [OSTI]

by the need for clean and sustainable energy. In this respect dye-sensitized solar cells (DSC) are considered the traditional solid-state cells is a dye-sensitized solar cell (DSC).1,2 In this type of cell, the lightPHYSICAL REVIEW B 84, 245115 (2011) Electronic structure of dye-sensitized TiO2 clusters from many

168

The effect of TiCl4-treated TiO2 compact layer on the performance of dye-sensitized solar cell  

E-Print Network [OSTI]

The effect of TiCl4-treated TiO2 compact layer on the performance of dye-sensitized solar cell by a factor of five compared with the bare cell. ? 2011 Elsevier B.V. All rights reserved. 1. Introduction Dye-sensitized: Received 11 October 2011 Accepted 25 October 2011 Available online 4 November 2011 Keywords: Dye-sensitized

Park, Byungwoo

169

Growth of Aligned Single-Crystalline Rutile TiO2 Nanowires on Arbitrary Substrates and Their Application in Dye-Sensitized Solar Cells  

E-Print Network [OSTI]

and Their Application in Dye-Sensitized Solar Cells Akshay Kumar, Anuj R. Madaria, and Chongwu Zhou* Department array of TiO2 nanowires on FTO as the photoanode is demonstrated in dye-sensitized solar cell for applications related to solar energy such as dye-sensitized solar cell (to convert light into electricity),18

Zhou, Chongwu

170

An Integrated Power Pack of Dye-Sensitized Solar Cell and Li Battery Based on Double-Sided TiO2 Nanotube Arrays  

E-Print Network [OSTI]

An Integrated Power Pack of Dye-Sensitized Solar Cell and Li Battery Based on Double-Sided TiO2 harvest and storage processes. This power pack incorporates a series-wound dye- sensitized solar cell, nanostructures have been widely used in energy harvesting devices, such as dye-sensitized solar cells (DSSCs

Wang, Zhong L.

171

An Unconventional Route to High-Efficiency Dye-Sensitized Solar Cells via Embedding Graphitic Thin Films into TiO2 Nanoparticle  

E-Print Network [OSTI]

An Unconventional Route to High-Efficiency Dye-Sensitized Solar Cells via Embedding Graphitic Thin into the conventional dye- sensitized solar cells (DSSCs), resulting in a remarkably improved cell efficiency due to its followed by direct carbonization. For dye-sensitized TiO2 based solar cells containing carbon/TiO2 thin

Lin, Zhiqun

172

Magnetic Fe3O4@TiO2 Nanoparticles-based Test Strip Immunosensing Device for Rapid Detection of Phosphorylated Butyrylcholinesterase  

SciTech Connect (OSTI)

An integrated magnetic nanoparticles-based test-strip immunosensing device was developed for rapid and sensitive quantification of phosphorylated butyrylcholinesterase (BChE), the biomarker of exposure to organophosphous pesticides (OP), in human plasma. In order to overcome the difficulty in scarce availability of OP-specific antibody, here magnetic Fe3O4@TiO2 nanoparticles were used and adsorbed on the test strip through a small magnet inserted in the device to capture target OP-BChE through selective binding between TiO2 and OP moiety. Further recognition was completed by horseradish peroxidase (HRP) and anti-BChE antibody (Ab) co-immobilized gold nanoparticles (GNPs). Their strong affinities among Fe3O4@TiO2, OP-BChE and HRP/Ab-GNPs were characterized by quartz crystal microbalance (QCM), surface plasmon resonance (SPR) and square wave voltammetry (SWV) measurements. After cutting off from test strip, the resulted immunocomplex (HRP/Ab-GNPs/OP-BChE/Fe3O4@TiO2) was measured by SWV using a screen printed electrode under the test zone. Greatly enhanced sensitivity was achieved by introduction of GNPs to link enzyme and antibody at high ratio, which amplifies electrocatalytic signal significantly. Moreover, the use of test strip for fast immunoreactions reduces analytical time remarkably. Coupling with a portable electrochemical detector, the integrated device with advanced nanotechnology displays great promise for sensitive, rapid and in-filed on-site evaluation of OP poisoning.

Ge, Xiaoxiao; Zhang, Weiying; Lin, Yuehe; Du, Dan

2013-12-15T23:59:59.000Z

173

Nb-doped TiO2 Nanofibers for Lithium Ion Batteries M. Fehse,, S. Cavaliere, P. E. Lippens, I. Savych, A. Iodacela, L.  

E-Print Network [OSTI]

Nb-doped TiO2 Nanofibers for Lithium Ion Batteries M. Fehse,, S. Cavaliere, P. E. Lippens, I, lithium ion batteries (LIB) have come a long way.1 Originally intended to serve only for small portable properties due to necessary solid elec- trolyte interphase (SEI) formation and the risk of lithium plating

Paris-Sud XI, Université de

174

Impact of three different TiO2 morphologies on hydrogen evolution by methonal assisted water-splitting: nanoparticles, nanotubes and  

E-Print Network [OSTI]

-splitting: nanoparticles, nanotubes and aerogels. (published in International Journal of Hydrogen Energy 36, 22 (2011, nanotubes and aerogels. These materials have shown different behaviours depending on both their composition of the samples (nanotubes or aerogels). Among all the tested samples, the TiO2 aerogel supported Pt one exhibited

Boyer, Edmond

175

Dependence of Band Offset and Open-Circuit Voltage on the Interfacial Interaction between TiO2 and Carboxylated Polythiophenes  

E-Print Network [OSTI]

the open-circuit voltage. An attractive approach for making low-cost photovoltaic (PV) cells is to use bulk, 2005 The interface of planar TiO2/polymer photovoltaic cells was modified with two carboxylated to titania surfaces in photovoltaic cells. If the density of attachment groups is just enough to attach

McGehee, Michael

176

Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries  

SciTech Connect (OSTI)

Lithium titanate (Li4Ti5O12) is well known as a zero strain material inherently, which provides excellent long cycle stability as a negative electrode for lithium ion batteries. However, the low specific capacity (175 mA h g?1) limits it to power batteries although the low electrical conductivity is another intrinsic issue need to be solved. In this work, we developed a facile hydrothermal and ion-exchange route to synthesize the self-supported dual-phase Li4Ti5O12TiO2 nanowire arrays to further improve its capacity as well as rate capability. The ratio of Li4Ti5O12 to TiO2 in the dual phase Li4Ti5O12TiO2 nanowire is around 2:1. The introduction of TiO2 into Li4Ti5O12 increases the specific capacity. More importantly, by interface design, it creates a dual-phase nanostructure with high grain boundary density that facilitates both electron and Li ion transport. Compared with phase-pure nanowire Li4Ti5O12 and TiO2 nanaowire arrays, the dual-phase nanowire electrode yielded superior rate capability (135.5 at 5 C, 129.4 at 10 C, 120.2 at 20 C and 115.5 mA h g?1 at 30 C). In-situ transmission electron microscope clearly shows the near zero deformation of the dual phase structure, which explains its excellent cycle stability.

Liao, Jin; Chabot, Victor; Gu, Meng; Wang, Chong M.; Xiao, Xingcheng; Chen, Zhongwei

2014-08-19T23:59:59.000Z

177

Site-Specific Imaging of Elemental Steps in Dehydration of Diols on TiO2(110)  

SciTech Connect (OSTI)

The conversion of diols on partially reduced TiO2(110) at low coverage was studied using variable-temperature scanning tunneling microscopy, temperature programmed desorption and density functional theory calculations. We find, that below ~230 K, ethane-1,2-diol and propane-1,3-diol molecules adsorb predominantly on five-fold coordinated Ti5c atoms. The dynamic equilibrium between molecularly bound and dissociated species resulting from O-H bond scission and reformation is observed. As the diols start to diffuse on the Ti5c rows above ~230 K, they dissociate irreversibly upon encountering bridging oxygen (Ob) vacancy (VOs) defects. Two dissociation pathways, one via O-H and the other via C-O bond scission leading to identical surface intermediates, hydroxyalkoxy, Ob-(CH2)n-OH (n = 2, 3) and bridging hydroxyl, HOb, are seen. For O-H bond scission, the Ob-(CH2)n-OH is found on the position of the original VO, while for C-O scission it is found on the adjacent Ob site. Theoretical calculations suggest that the observed mixture of C-O/O-H bond breaking processes are a result of the steric factors enforced upon the diols by the second OH group that is bound to a Ti5c site. At room temperature, rich dissociation/reformation dynamics of the second, Ti5c-bound O-H leads to the formation of dioxo, Ob-(CH2)n-OTi, species. Above ~400 K, both Ob-(CH2)n-OH and Ob-(CH2)n-OTi species convert into a new intermediate, that is centered on Ob row. Combined experimental and theoretical evidence shows that this intermediate is most likely a new dioxo, Ob-(CH2)2-Ob, species. Further annealing leads to sequential C-Ob bond cleavage and alkene desorption above ~ 500 K. Simulations find that the sequential C-O bond breaking process follows a homolytic diradical pathway with the first C-O bond breaking event accompanied by a non-adiabatic electron transfer within the TiO2(110) substrate.

Acharya, Danda P.; Yoon, Yeohoon; Li, Zhenjun; Zhang, Zhenrong; Lin, Xiao; Mu, Rentao; Chen, Long; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek

2013-11-26T23:59:59.000Z

178

Electrochimica Acta 46 (2001) 33513358 Transference number measurements of TiO2 BaO melts by  

E-Print Network [OSTI]

variations in ion density and variations in net free-charge density. 2. Background By direct comparison joule heating of the electrolyte is central to establishing the thermal balance of the reactor. Molten processes [1]. In particular, Sadoway has spec- ulated on the utility of producing titanium metal by direct

Sadoway, Donald Robert

179

Magnetic properties of epitaxial Co-doped anatase TiO2 thin films with excellent structural quality  

SciTech Connect (OSTI)

The heteroepitaxy of Co-doped anatase TiO2 on LaAlO3(001) has been refined with the goal of determining the relationship between structural quality and magnetic ordering. By significantly reducing the deposition rate and substrate temperature, well-ordered Co:TiO2 films with unprecedented crystalline quality were obtained by oxygen-plasma-assisted molecular beam epitaxy, as characterized by x-ray diffraction. These films exhibit uniform Co doping, with no evidence of Co segregation or secondary phases throughout the film depth or on the surface. Despite the improvement in crystalline quality and Co distribution, the films exhibit negligible ferromagnetism, with saturation moments of only ~0.1 ?B/Co. This loss of ferromagnetism is in stark contrast to faster-grown Co:TiO2 films, where a higher growth rate and substrate temperature typically result in lower crystalline quality, a highly non-uniform Co distribution, and average saturation moments of ~1.2 ?B/Co. The presence of ferromagnetism in faster-grown Co:TiO2 does not appear to arise from intrinsic point defects present in the bulk material, such as charge-compensating oxygen vacancies, but is instead attributed to the presence of extended structural defects.

Kaspar, Tiffany C.; Droubay, Timothy C.; McCready, David E.; Nachimuthu, Ponnusamy; Heald, Steve M.; Wang, Chong M.; Lea, Alan S.; Shutthanandan, V.; Chambers, Scott A.; Toney, Michael F.

2006-07-26T23:59:59.000Z

180

Surface Passivation of Nanoporous TiO2 via Atomic Layer Deposition of ZrO2 for Solid-State Dye-Sensitized Solar Cell Applications  

E-Print Network [OSTI]

to the spiro-OMeTAD. Introduction Dye-sensitized solar cells (DSCs) based on mesoporous titania and liquidSurface Passivation of Nanoporous TiO2 via Atomic Layer Deposition of ZrO2 for Solid-State Dye-Sensitized Solar Cell Applications Tina C. Li, Ma´rcio S. Go´es,,§ Francisco Fabregat-Santiago,*, Juan Bisquert

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Model relation between the energy-band edge and the Fermi level of the nondegenerate semiconductor TiO2: Application to electrochemistry  

E-Print Network [OSTI]

, i.e., anatase and rutile, are widely used in photocatalysis and dye-sensitized solar cell DSSC, is demonstrated in the comparative studies of anatase and rutile TiO2 that are used in photocatalysis and dye-sensitized solar cells. DOI: 10.1103/PhysRevB.82.235109 PACS number s : 82.45.Vp, 71.38.Ht, 73.40. c, 82.47.Jk I

Li, Weixue

182

Dust in brown dwarfs and extra-solar planets IV. Assessing TiO2 and SiO nucleation for cloud formation modeling  

E-Print Network [OSTI]

Clouds form in atmospheres of brown dwarfs and planets. The cloud particle formation processes are similar to the dust formation process studied in circumstellar shells of AGB stars and in Supernovae. Cloud formation modelling in substellar objects requires gravitational settling and element replenishment in addition to element depletion. All processes depend on the local conditions, and a simultaneous treatment is required. We apply new material data in order to assess our cloud formation model results regarding the treatment of the formation of condensation seeds. We re-address the question of the primary nucleation species in view of new (TiO2)_N-cluster data and new SiO vapour pressure data. We apply the density functional theory using the computational chemistry package Gaussian 09 to derive updated thermodynamical data for (TiO2)_N-clusters as input for our TiO2 seed formation model. We test different nucleation treatments and their effect on the overall cloud structure by solving a system of dust momen...

Lee, G; Giles, H; Bromley, S T

2014-01-01T23:59:59.000Z

183

Self-Organized Amorphous TiO2 Nanotube Arrays on Porous Ti Foam for Rechargeable Lithium and Sodium Ion Batteries  

SciTech Connect (OSTI)

Self-organized amorphous TiO2 nanotube arrays (NTAs) were successfully fabricated on both Ti foil and porous Ti foam through electrochemical anodization techniques. The starting Ti foams were fabricated using ARCAM s Electron Beam Melting (EBM) technology. The TiO2 NTAs on Ti foam were used as anodes in lithium ion batteries; they exhibited high capacities of 103 Ahcm-2 at 10 Acm-2 and 83 Ahcm-2 at 500 Acm-2, which are two to three times higher than those achieved on the standard Ti foil, which is around 40 Ahcm-2 at 10 Acm-2 and 24 Ahcm-2 at 500 Acm-2, respectively. This improvement is mainly attributed to higher surface area of the Ti foam and higher porosity of the nanotube arrays layer grown on the Ti foam. In addition, a Na-ion half-cell composed of these NTAs anodes and Na metal showed a self-improving specific capacity upon cycling at 10 Acm-2. These results indicate that TiO2 NTAs grown on Ti porous foam are promising electrodes for Li-ion or Na-ion rechargeable batteries.

Bi, Zhonghe [ORNL; Paranthaman, Mariappan Parans [ORNL; Menchhofer, Paul A [ORNL; Dehoff, Ryan R [ORNL; Bridges, Craig A [ORNL; Chi, Miaofang [ORNL; Guo, Bingkun [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

2013-01-01T23:59:59.000Z

184

Comparison of Three Digestibility Markers in Beef Cattle Fed Finishing Rations Containing Different Sources of Supplemental Fat  

E-Print Network [OSTI]

bioavailability throughout the digestive system. This study compares two external dietary markers, chromium oxide (Cr2O3) and titanium dioxide (TiO2), and one internal marker, acid detergent insoluble ash (ADIA) with the objective of validating titanium oxide as a...

Christian, Amelia

2014-01-22T23:59:59.000Z

185

DOI: 10.1007/s00339-002-2004-5 Appl. Phys. A 76, 17 (2002)  

E-Print Network [OSTI]

- pects of TiO2 surfaces or interfaces would potentially have a positive impact. Titanium dioxide is used online: 2001 · © Springer-Verlag 2002 ABSTRACT Titanium oxides are used in a wide variety of tech initio approaches and to calculate properties of adsorption systems. Scanning tunneling microscopy (STM

Diebold, Ulrike

186

Surface Structure of TiO2011-2 1 T. J. Beck,1  

E-Print Network [OSTI]

.43.Bc, 68.47.Gh Titanium dioxide is a promising photocatalyst for the remediation of pollutants of metal oxides [9,10]. In bulk TiO2 the titanium atoms are surrounded by octahedra of six oxygen atoms of the model in Fig. 1.) Such undercoordinated Ti(5) atoms are preferred adsorption sites for a variety

Diebold, Ulrike

187

An Insoluble Titanium-Lead Anode for Sulfate Electrolytes  

SciTech Connect (OSTI)

The project is devoted to the development of novel insoluble anodes for copper electrowinning and electrolytic manganese dioxide (EMD) production. The anodes are made of titanium-lead composite material produced by techniques of powder metallurgy, compaction of titanium powder, sintering and subsequent lead infiltration. The titanium-lead anode combines beneficial electrochemical behavior of a lead anode with high mechanical properties and corrosion resistance of a titanium anode. In the titanium-lead anode, the titanium stabilizes the lead, preventing it from spalling, and the lead sheathes the titanium, protecting it from passivation. Interconnections between manufacturing process, structure, composition and properties of the titanium-lead composite material were investigated. The material containing 20-30 vol.% of lead had optimal combination of mechanical and electrochemical properties. Optimal process parameters to manufacture the anodes were identified. Prototypes having optimized composition and structure were produced for testing in operating conditions of copper electrowinning and EMD production. Bench-scale, mini-pilot scale and pilot scale tests were performed. The test anodes were of both a plate design and a flow-through cylindrical design. The cylindrical anodes were composed of cylinders containing titanium inner rods and fitting over titanium-lead bushings. The cylindrical design allows the electrolyte to flow through the anode, which enhances diffusion of the electrolyte reactants. The cylindrical anodes demonstrate higher mass transport capabilities and increased electrical efficiency compared to the plate anodes. Copper electrowinning represents the primary target market for the titanium-lead anode. A full-size cylindrical anode performance in copper electrowinning conditions was monitored over a year. The test anode to cathode voltage was stable in the 1.8 to 2.0 volt range. Copper cathode morphology was very smooth and uniform. There was no measurable anode weight loss during this time period. Quantitative chemical analysis of the anode surface showed that the lead content after testing remained at its initial level. No lead dissolution or transfer from the anode to the product occurred.A key benefit of the titanium-lead anode design is that cobalt additions to copper electrolyte should be eliminated. Cobalt is added to the electrolyte to help stabilize the lead oxide surface of conventional lead anodes. The presence of the titanium intimately mixed with the lead should eliminate the need for cobalt stabilization of the lead surface. The anode should last twice as long as the conventional lead anode. Energy savings should be achieved due to minimizing and stabilizing the anode-cathode distance in the electrowinning cells. The anode is easily substitutable into existing tankhouses without a rectifier change.The copper electrowinning test data indicate that the titanium-lead anode is a good candidate for further testing as a possible replacement for a conventional lead anode. A key consideration is the cost. Titanium costs have increased. One of the ways to get the anode cost down is manufacturing the anodes with fewer cylinders. Additional prototypes having different number of cylinders were constructed for a long-term commercial testing in a circuit without cobalt. The objective of the testing is to evaluate the need for cobalt, investigate the effect of decreasing the number of cylinders on the anode performance, and to optimize further the anode design in order to meet the operating requirements, minimize the voltage, maximize the life of the anode, and to balance this against a reasonable cost for the anode. It is anticipated that after testing of the additional prototypes, a whole cell commercial test will be conducted to complete evaluation of the titanium-lead anode costs/benefits.

Ferdman, Alla

2005-05-11T23:59:59.000Z

188

Physisorption of N2, O2, and CO on Fully Oxidized TiO2(110)  

SciTech Connect (OSTI)

Physisorption of N2, O2 and CO was studied on fully oxidized TiO2(110) using beam reflection and temperature programmed desorption (TPD) techniques. Sticking coefficients for all three molecules are nearly equal (0.75 0.05) and approximately independent of coverage suggesting that adsorption occurs via a precursor mediated mechanism. Excluding multilayer coverages, the TPD spectra for all three adsorbates exhibit three distinct coverage regimes that can be interpreted in accord with previous theoretical studies of N2 adsorption. At low coverages (0 to 0.5 N2/Ti4+), N2 molecules bind head-on to five-coordinated Ti4+ ions. The adsorption occurs preferentially on the Ti4+ sites that do not have neighboring adsorbates. This arrangement minimizes the repulsive interactions between the adsorbed molecules along the Ti4+ rows resulting in a relatively small shift of the TPD peak (105 ? 90 K) with increasing coverage. At higher N2 coverages (0 to 1.0 N2/Ti4+) the nearest-neighbor Ti4+ sites become occupied. The close proximity of the adsorbates results in strong repulsion thus giving rise to a significant shift of the TPD leading edges (90 ? 45 K) with increasing coverage. For N2/Ti4+ > 1, an additional low temperature peak (~ 43 K) is present and is ascribed to N2 adsorption on bridge-bonded oxygen rows. The results for O2 and CO are qualitatively similar. The repulsive adsorbate-adsorbate interactions largest for CO, most likely due to aligned CO dipole moments. The coverage dependent binding energies of O2, N2, and CO are determined by inverting TPD profiles.

Dohnalek, Zdenek; Kim, Jooho; Bondarchuk, Oleksander A.; White, J. M.; Kay, Bruce D.

2006-03-30T23:59:59.000Z

189

Formation of nanostructured TiO{sub 2} by femtosecond laser irradiation of titanium in O{sub 2}  

SciTech Connect (OSTI)

We used femtosecond laser irradiation of titanium metal in an oxidizing environment to form a highly stable surface layer of nanostructured amorphous titanium dioxide (TiO{sub 2}). We studied the influence of atmospheric composition on these surface structures and found that gas composition and pressure affect the chemical composition of the surface layer but not the surface morphology. Incorporation of nitrogen is only possible when no oxygen is present in the surrounding atmosphere.

Landis, Elizabeth C. [Department of Chemistry, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Phillips, Katherine C.; Mazur, Eric [School of Engineering and Applied Sciences, Harvard University, 9 Oxford Street, Cambridge, Massachusetts 02138 (United States); Friend, Cynthia M. [Department of Chemistry, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); School of Engineering and Applied Sciences, Harvard University, 9 Oxford Street, Cambridge, Massachusetts 02138 (United States)

2012-09-15T23:59:59.000Z

190

anatase titanium dioxide: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

mixed anatase and rutile phases. Under simulated AM 1.5 G illumination, the peak solar energy conversion Heller, Eric 6 Room-temperature ferromagnetism in manganese doped reduced...

191

Using Ionic Liquids to Make Titanium Dioxide Nanotubes - Energy Innovation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II Field Emission SEMUsedUser

192

Nitrogen dioxide detection  

DOE Patents [OSTI]

Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

Sinha, Dipen N. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM); Christensen, William H. (Buena Park, CA)

1993-01-01T23:59:59.000Z

193

Excellent Passivation and Low Reflectivity Al2O3/TiO2 Bilayer Coatings for n-Wafer Silicon Solar Cells: Preprint  

SciTech Connect (OSTI)

A bilayer coating of Al2O3 and TiO2 is used to simultaneously achieve excellent passivation and low reflectivity on p-type silicon. This coating is targeted for achieving high efficiency n-wafer Si solar cells, where both passivation and anti-reflection (AR) are needed at the front-side p-type emitter. It could also be valuable for front-side passivation and AR of rear-emitter and interdigitated back contact p-wafer cells. We achieve high minority carrier lifetimes {approx}1 ms, as well as a nearly 2% decrease in absolute reflectivity, as compared to a standard silicon nitride AR coating.

Lee, B. G.; Skarp, J.; Malinen, V.; Li, S.; Choi, S.; Branz, H. M.

2012-06-01T23:59:59.000Z

194

Induction slag reduction process for making titanium  

DOE Patents [OSTI]

Continuous process for preparing titanium comprising fluorinating titanium ore, and reducing the formed alkaline earth fluotitanate with an alkaline earth metal in an induction slag reactor.

Traut, Davis E. (Corvallis, OR)

1991-01-01T23:59:59.000Z

195

Selective reduction of nitric oxide with ammonia over vanadia on pillared titanium phosphate  

E-Print Network [OSTI]

in the catalyst. Shikada et al. (1981) compared AlzOz, SiOz, and SiO, ? TiOz (equimolar) supports for VzOs using a simulated flue gas containing 100 ppni SOz. The silica- titanium dioxide supported catalyst showed the highest NO conversions followed by those...SELECTIVE REDUCTION OF NITRIC OXIDE YVITH AMMONIA OVER VANADIA ON PILLARED TITANIUM PHOSPHATE A Thesis LAWRENCE JOSEPH CZARNECKI Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirement for the degree...

Czarnecki, Lawrence Joseph

1988-01-01T23:59:59.000Z

196

Process for stabilization of titanium silicide particulates within titanium aluminide containing metal matrix composites  

SciTech Connect (OSTI)

This paper describes a method for forming a final composite material comprising titanium silicide particles within a titanium aluminide containing matrix. It comprises: contacting titanium, silicon and aluminum at a temperature sufficient to initiate a reaction between the titanium and silicon to thereby form a first composite comprising titanium silicide particles dispersed within an aluminum matrix; admixing the first composite with titanium and zirconium to form a mixture; heating the mixture to a temperature sufficient to convert at least a portion of the aluminum matrix to titanium aluminide; and recovering a final composite material comprising titanium silicide particles dispersed within a titanium aluminide containing matrix.

Christodoulou, L.; Williams, J.C.; Riley, M.A.

1990-04-10T23:59:59.000Z

197

What's Next for Vanadium Dioxide?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

How Atomic Vibrations Transform Vanadium Dioxide How Atomic Vibrations Transform Vanadium Dioxide Calculations Confirm Material's Potential for Next-Generation Electronics, Energy...

198

Au/PO43-/TiO2 and PO43-/Au/TiO2 catalysts for CO oxidation: effect of synthesis details on catalytic performance  

SciTech Connect (OSTI)

Supported gold catalysts are active for CO oxidation, but the high-temperature deactivation is a shortcoming that may constrain their applications. Herein, we attempted to address this problem by using phosphate-doped Au/TiO{sub 2} synthesized via two routes. In route I, Au/PO{sub 4}{sup 3-}/TiO{sub 2} catalysts were prepared by treating TiO{sub 2} (Degussa P25) with diluted H{sub 3}PO{sub 4}, followed by loading gold via deposition-precipitation. In route II, PO{sub 4}{sup 3-}/Au/TiO{sub 2} catalysts were prepared by treating H{sub 2}-reduced Au/TiO{sub 2} with diluted H{sub 3}PO{sub 4}. These catalysts were systematically pretreated at 200 or 500 C before reaction testing. The overall CO conversion on 200 C-pretreated Au/PO43-/TiO2 or PO43-/Au/TiO2 was always lower than that on 200 C-pretreated Au/TiO2. However, the advantage of the phosphate addition became apparent after thermal treatment at a higher temperature. Both Au/PO43-/TiO2 and PO43-/Au/TiO2 pretreated at 500 C retained significant activities at room temperature, whereas 500 C-pretreated Au/TiO2 lost its activity. Control experiments and catalyst characterization were performed to investigate the impact of synthesis details on catalytic performance.

Ma, Zhen [ORNL; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

2007-01-01T23:59:59.000Z

199

6090 Chem. Commun., 2010, 46, 60906092 This journal is c The Royal Society of Chemistry 2010 Porphyrin sensitized solar cells: TiO2 sensitization with a p-extended  

E-Print Network [OSTI]

been synthesized and successfully applied to dye-sensitized solar cells with a power conversion the conditions employed here. Dye-sensitized solar cells (DSSCs) have attracted much attention as promising Porphyrin sensitized solar cells: TiO2 sensitization with a p-extended porphyrin possessing two anchoring

200

Gas-Solid Displacement Reactions for Converting Silica Diatom Frustules into MgO and TiO2  

SciTech Connect (OSTI)

Technology for the microfabrication of freely moving parts began with a Bell Labs microgear spun by an air jet, and electrostatic silicon micro motors in the mid-1980s. It continued with development work on micropositioning of optics, miniature heat exchangers, small fluidic devices, and chemical reaction chambers. Recently, there has been a great deal of interest centered on the design and manufacture of devices of nanometer proportions and this speculation has spawned a new industry named, nanotechnology. Despite the technological and economic promise of this technology, current commercial micro/mesofabrication methods have largely been based upon two-dimensional processing principles which is not well suited to the low-cost mass production of three-dimensional micro devices with complex geometries and meso/nanoscale features. Diatoms are three dimensional (3D) microstructures from nature that provide a practical alternative for nanotechnology and microfabrication. Diatoms (Figure 1) are single-celled micro algae that form rigid cell walls (frustules) composed of amorphous silica. Their dimensions can range from less than 1 micron to several hundreds of microns. They are distributed throughout the world in aquatic, semi-aquatic and moist habitats, and extremely abundant in freshwater and marine ecosystems. Diatoms are thought to be responsible for up to 25% of the world's net primary production of organic carbon (by transforming of carbon dioxide and water into sugars by photosynthesis). Approximately 10{sup 5} unique diatom frustule shapes have been claimed to exist in nature. The frustules are composed of two valves that fit together like a petri-dish, connected to each other by one or more girdle bands. The frustule wall consists of a nanoporous assembly of silica nanoparticles. They absorb soluble silica from water even at extremely low concentrations and metabolize and deposit it as an external skeleton. Continued reproduction of a single parent diatom can yield large numbers of descendant diatoms, each of which possesses a frustule with the same microshape and meso/nano features. Each mitotic division results in the formation of two differently sized daughter cells, one that is the same size as the parent and one that is slightly smaller. Therefore, over successive generations the mean cell size of a population decreases and standard deviation about this mean increases. It is believed that when a cell decreases in size to a diameter of less than about 30 to 40% of the maximum diameter for a given species, sexual reproduction initiates. This enables an entirely new frustule to be generated that is many times larger than either parent. Importantly, these newly formed large cells rapidly resume asexual reproduction and are essentially ''immune'' to sexual reproduction until an appropriate small cell size is obtained.

Tugba Kalem

2004-12-19T23:59:59.000Z

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Sulfur Dioxide Regulations (Ohio)  

Broader source: Energy.gov [DOE]

This chapter of the law establishes that the Ohio Environmental Protection Agency provides sulfur dioxide emission limits for every county, as well as regulations for the emission, monitoring and...

202

Carbon dioxide removal process  

DOE Patents [OSTI]

A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

2003-11-18T23:59:59.000Z

203

Calcification capacity of porous pHEMATiO2 composite Chao Li Yu-Feng Zheng Xia Lou  

E-Print Network [OSTI]

polymers for applica- tions as orthopaedic and dental implants. In this study, novel titanium dioxide (TiO2. Infiltration of calcium phosphate, up to 1000 lm, was observed. The diffusion capacity of calcium ions bonding to hard tissue which in turn provides a favourable procedure to mimic the bone environment through

Zheng, Yufeng

204

Mesostructures DOI: 10.1002/anie.201310748  

E-Print Network [OSTI]

functionalized with organic groups that can form tight bonding to inorganic species. Such polymers were able analogues (AlPO4 and other related metal phos- phates with open frameworks), titanium dioxide (TiO2. The incorporation of mesoporosity into these materials has been an important issue for resolving the diffusion

Ihee, Hyotcherl

205

Studies on Waterborne Pathogen Reactivation after Disinfection  

E-Print Network [OSTI]

ultraviolet (LP UV) irradiation at five titanium dioxide (TiO_(2)) concentrations (1 g/L, 0.5 g/L, 0.75 g/L, and 0.1 g/L) to achieve 5 log_(10) reduction of a laboratory E. coli K-12 strain (ATCC 10798). Regrowth and reactivation of E. coli in dark and light...

Kaur, Jasjeet

2013-12-09T23:59:59.000Z

206

Synthesis and Electric Field-Manipulation of High Aspect Ratio Barium Titanate  

E-Print Network [OSTI]

and shapes of titanium dioxide (TiO2) and barium titanate (BaTiO3) nanoparticles were purchased and measured. However, after a number of experiments detailed in the thesis, it was found that none of the commercially available nanoparticles could satisfy our...

Li, Junjia

2012-07-16T23:59:59.000Z

207

IOP PUBLISHING NANOTECHNOLOGY Nanotechnology 20 (2009) 065606 (5pp) doi:10.1088/0957-4484/20/6/065606  

E-Print Network [OSTI]

, 15] as well as insulating [16­19] surfaces. The (110) surface of rutile titanium dioxide [20 are in colour only in the electronic version) 1. Introduction The adsorption of molecules onto surfaces has been­27]. In this work, we study the principles of adsorption of C60 on rutile TiO2(110) by non-contact atomic force

Kühnle, Angelika

208

Sensors and Actuators B 155 (2011) 159164 Contents lists available at ScienceDirect  

E-Print Network [OSTI]

Titanium dioxide (TiO2) is frequently used as matrix to immobilize proteins and enzymes for biomaterial concentration, the electron transfer rate and enzyme adsorption amount of TNT arrays were improved largely, which could be ascribed to the creation of hydroxyl groups on TNT surface due to dissociative adsorption

Cao, Guozhong

209

Role of Moisture in Adsorption, Photocatalytic Oxidation, and  

E-Print Network [OSTI]

various Hg emission sources. A novel low-cost methodology using titanium dioxide (TiO2) nanoparticlesRole of Moisture in Adsorption, Photocatalytic Oxidation, and Reemission of Elemental Mercury gas. Without UV irradiation, Hg0 adsorption was found to be insignificant, but it could be enhanced

Li, Ying

210

A theoretical approach for modeling reactivity at solidliquid interfaces Eugene V. Stefanovicha)  

E-Print Network [OSTI]

- dustry and environmental protection.1 For example, the in- terface between titanium dioxide (TiO2­water interface. Geometries and adsorption binding energies of H2O, NaCl, Na , and Cl at the NaCl 001 ­water and interactions of adsorption complexes and surface defects with the crystal lattice and solvent wa- ter

Truong, Thanh N.

211

The Role of Interstitial Sites in the Ti3d Defect State  

E-Print Network [OSTI]

Matthiesen,1 Asger Blekinge-Rasmussen,1 Erik Lægsgaard,1 Bjørk Hammer,1 * Flemming Besenbacher1 * Titanium dioxide (TiO2) has a number of uses in catalysis, photochemistry, and sensing that are linked adsorption and dissociation. Specifically, we identified a second O2 dissociation channel that occurs within

212

Evidence for the Predominance of Subsurface Defects on Reduced Anatase TiO2101 Yunbin He,1  

E-Print Network [OSTI]

numbers: 68.47.Gh, 68.35.Dv, 68.37.Ef Titanium dioxide, TiO2, finds applications in a wide range on well-characterized anatase sur- faces are available. STM [13] and adsorption [14] experiments indicated

Diebold, Ulrike

213

Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications  

DOE Patents [OSTI]

A method for the separation of carbon dioxide from ambient air and flue gases is provided wherein a phase separating moiety with a second moiety are simultaneously coupled and bonded onto an inert substrate to create a mixture which is subsequently contacted with flue gases or ambient air. The phase-separating moiety is an amine whereas the second moiety is an aminosilane, or a Group 4 propoxide such as titanium (IV) propoxide (tetrapropyl orthotitanate, C.sub.12H.sub.28O.sub.4Ti). The second moiety makes the phase-separating moiety insoluble in the pores of the inert substrate. The new sorbents have a high carbon dioxide loading capacity and considerable stability over hundreds of cycles. The synthesis method is readily scalable for commercial and industrial production.

Gay, McMahan; Choi, Sunho; Jones, Christopher W

2014-09-16T23:59:59.000Z

214

Method of making multilayered titanium ceramic composites  

DOE Patents [OSTI]

A method making a titanium ceramic composite involves forming a hot pressed powder body having a microstructure comprising at least one titanium metal or alloy layer and at least one ceramic particulate reinforced titanium metal or alloy layer and hot forging the hot pressed body follwed by hot rolling to substantially reduce a thickness dimension and substantially increase a lateral dimension thereof to form a composite plate or sheet that retains in the microstructure at least one titanium based layer and at least one ceramic reinforced titanium based layer in the thickness direction of the composite plate or sheet.

Fisher, George T., II; Hansen; Jeffrey S.; Oden; Laurance L.; Turner; Paul C.; Ochs; Thomas L.

1998-08-25T23:59:59.000Z

215

Project Profile: Direct Supercritical Carbon Dioxide Receiver...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Carbon Dioxide Receiver Development Project Profile: Direct Supercritical Carbon Dioxide Receiver Development National Renewable Energy Laboratory logo The National...

216

Carbon dioxide sensor  

DOE Patents [OSTI]

The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

2011-11-15T23:59:59.000Z

217

CARBON DIOXIDE EMISSION REDUCTION  

E-Print Network [OSTI]

.5 Primary Energy Use and Carbon Dioxide Emissions for Selected US Chemical Subsectors in 1994 ...............................................................................................................16 Table 2.7 1999 Energy Consumption and Specific Energy Consumption (SEC) in the U.S. Cement Efficiency Technologies and Measures in Cement Industry.................22 Table 2.9 Energy Consumption

Delaware, University of

218

E-Print Network 3.0 - annealed titanium alloys Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

... Source: Ecole Polytechnique, Centre de mathmatiques Collection: Mathematics 47 Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications...

219

Hydrothermal processing of chlorinated hydrocarbons in a titanium reactor  

SciTech Connect (OSTI)

Experiments are reported on the oxidative hydrothermal destruction of chlorinated organics in a corrosion-resistant titanium reactor. Oxidation reaction conditions were 250-500 {degree}C near 650 bar and reaction times of 30-100 s in a continuous-flow reactor. Trichloroacetic acid, trichloroethylene, and 1,1,1-trichloroethane behaved similarly. The organic concentration was approximately 1.5 wt%; hydrogen peroxide was the oxidizer; sodium bicarbonate was added to achieve neutral pH. Hydrolysis occurs at low temperature, producing chloride ion and secondary organics. Carbon dioxide is the sole carbon product at 500 {degree}C. Sodium nitrate and sodium nitrite were also found to be effective oxidizers. Corrosion of the titanium was found to be slight (<0.038 mm/yr). The reaction mixture is likely not a single phase at these conditions. The destruction efficiency for trichloroethylene was estimated as 99.96% at 450 {degree}C and 60 s, with <0.02% conversion to volatile chlorinated organic byproducts. 33 refs., 9 figs., 6 tabs.

Foy, B.R.; Waldthausen, K.; Sedillo, M.A.; Buelow, S.J. [Los Alamos National Lab., NM (United States)] [Los Alamos National Lab., NM (United States)

1996-09-01T23:59:59.000Z

220

TITANIUM--2003 78.1 References that include a section mark () are found in the Internet  

E-Print Network [OSTI]

status to imports of unwrought titanium from Russia and Kazakhstan. Kazakhstan's Ust-Kamenogorsk Titanium

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

CARBON DIOXIDE FIXATION.  

SciTech Connect (OSTI)

Solar carbon dioxide fixation offers the possibility of a renewable source of chemicals and fuels in the future. Its realization rests on future advances in the efficiency of solar energy collection and development of suitable catalysts for CO{sub 2} conversion. Recent achievements in the efficiency of solar energy conversion and in catalysis suggest that this approach holds a great deal of promise for contributing to future needs for fuels and chemicals.

FUJITA,E.

2000-01-12T23:59:59.000Z

222

Recovery of titanium values from titanium grinding swarf by electric furnace smelting  

DOE Patents [OSTI]

A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag.

Gerdemann, Stephen J. (Albany, OR); White, Jack C. (Albany, OR)

1999-01-01T23:59:59.000Z

223

Recovery of titanium values from titanium grinding swarf by electric furnace smelting  

DOE Patents [OSTI]

A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag.

Gerdemann, Stephen J. (Albany, OR); White, Jack C. (Albany, OR)

1998-01-01T23:59:59.000Z

224

Recovery of titanium values from titanium grinding swarf by electric furnace smelting  

DOE Patents [OSTI]

A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag. 1 fig.

Gerdemann, S.J.; White, J.C.

1998-08-04T23:59:59.000Z

225

Igniter containing titanium hydride and potassium perchlorate  

DOE Patents [OSTI]

An explosive device is described which employs a particular titanium hydride-potassium perchlorate composition directly ignitible by an electrical bridgewire.

Dietzel, Russel W. (Albuquerque, NM); Leslie, William B. (Albuquerque, NM)

1976-01-01T23:59:59.000Z

226

Synthesis of Nanodispersed Oxides of Vanadium, Titanium, Molybdenum...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nanodispersed Oxides of Vanadium, Titanium, Molybdenum, and Tungsten on Mesoporous Silica using Atomic Layer Synthesis of Nanodispersed Oxides of Vanadium, Titanium, Molybdenum,...

227

Low Cost PM Technology for Particle Reinforced Titanium Automotive...  

Broader source: Energy.gov (indexed) [DOE]

10 - Low Cost PM Technology for Particle Reinforced Titanium Automotive Components edm2@chrysler.com February 28, 2008 Low Cost PM Technology for Particle Reinforced Titanium...

228

Process for sequestering carbon dioxide and sulfur dioxide  

DOE Patents [OSTI]

A process for sequestering carbon dioxide, which includes reacting a silicate based material with an acid to form a suspension, and combining the suspension with carbon dioxide to create active carbonation of the silicate-based material, and thereafter producing a metal salt, silica and regenerating the acid in the liquid phase of the suspension.

Maroto-Valer, M. Mercedes (State College, PA); Zhang, Yinzhi (State College, PA); Kuchta, Matthew E. (State College, PA); Andresen, John M. (State College, PA); Fauth, Dan J. (Pittsburgh, PA)

2009-10-20T23:59:59.000Z

229

Carbon Dioxide Reduction Through Urban Forestry  

E-Print Network [OSTI]

. Retrieval Terms: urban forestry, carbon dioxide, sequestration, avoided energy The Authors E. Gregory McCarbon Dioxide Reduction Through Urban Forestry: Guidelines for Professional and Volunteer Tree; Simpson, James R. 1999. Carbon dioxide reduction through urban forestry

Standiford, Richard B.

230

Titanium carbide bipolar plate for electrochemical devices  

DOE Patents [OSTI]

A corrosion resistant, electrically conductive, non-porous bipolar plate is made from titanium carbide for use in an eletrochemical device. The process involves blending titanium carbide powder with a suitable binder material, and molding the mixture, at an elevated temperature and pressure.

LaConti, Anthony B. (Lynnfield, MA); Griffith, Arthur E. (Lynn, MA); Cropley, Cecelia C. (Acton, MA); Kosek, John A. (Danvers, MA)

2000-07-04T23:59:59.000Z

231

Titanium Carbide Bipolar Plate for Electrochemical Devices  

SciTech Connect (OSTI)

Titanium carbide comprises a corrosion resistant, electrically conductive, non-porous bipolar plate for use in an electrochemical device. The process involves blending titanium carbide powder with a suitable binder material, and molding the mixture, at an elevated temperature and pressure.

LaConti, Anthony B.; Griffith, Arthur E.; Cropley, Cecelia C.; Kosek, John A.

1998-05-08T23:59:59.000Z

232

Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one...

233

Optimize carbon dioxide sequestration, enhance oil recovery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

234

Optimize carbon dioxide sequestration, enhance oil recovery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields...

235

Carbon dioxide and climate  

SciTech Connect (OSTI)

Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

Not Available

1990-10-01T23:59:59.000Z

236

Characterisation of titanium-titanium boride composites processed by powder metallurgy techniques  

SciTech Connect (OSTI)

In this work, a detailed characterisation of titanium-titanium boride composites processed by three powder metallurgy techniques, namely, hot isostatic pressing, spark plasma sintering and vacuum sintering, was conducted. Two composites with different volume percents of titanium boride reinforcement were used for the investigation. One was titanium with 20% titanium boride, and the other was titanium with 40% titanium boride (by volume). Characterisation was performed using X-ray diffraction, electron probe micro analysis - energy dispersive spectroscopy and wavelength dispersive spectroscopy, image analysis and scanning electron microscopy. The characterisation results confirm the completion of the titanium boride reaction. The results reveal the presence of titanium boride reinforcement in different morphologies such as needle-shaped whiskers, short agglomerated whiskers and fine plates. The paper also discusses how mechanical properties such as microhardness, elastic modulus and Poisson's ratio are influenced by the processing techniques as well as the volume fraction of the titanium boride reinforcement. - Highlights: Black-Right-Pointing-Pointer Ti-TiB composites were processed by HIP, SPS and vacuum sintering. Black-Right-Pointing-Pointer The completion of Ti-TiB{sub 2} reaction was confirmed by XRD, SEM and EPMA studies. Black-Right-Pointing-Pointer Hardness and elastic properties of Ti-TiB composites were discussed. Black-Right-Pointing-Pointer Processing techniques were compared with respect to their microstructure.

Selva Kumar, M., E-mail: sel_mcet@yahoo.co.in [Department of Mechanical Engineering, Dr. Mahalingam College of Engineering and Technology, Pollachi-642003 (India); Chandrasekar, P.; Chandramohan, P. [School of Engineering, Professional Group of Institutions, Coimbatore-641662 (India)] [School of Engineering, Professional Group of Institutions, Coimbatore-641662 (India); Mohanraj, M. [Department of Mechanical Engineering, Info Institute of Engineering, Coimbatore-641107 (India)] [Department of Mechanical Engineering, Info Institute of Engineering, Coimbatore-641107 (India)

2012-11-15T23:59:59.000Z

237

Uranium dioxide electrolysis  

DOE Patents [OSTI]

This is a single stage process for treating spent nuclear fuel from light water reactors. The spent nuclear fuel, uranium oxide, UO.sub.2, is added to a solution of UCl.sub.4 dissolved in molten LiCl. A carbon anode and a metallic cathode is positioned in the molten salt bath. A power source is connected to the electrodes and a voltage greater than or equal to 1.3 volts is applied to the bath. At the anode, the carbon is oxidized to form carbon dioxide and uranium chloride. At the cathode, uranium is electroplated. The uranium chloride at the cathode reacts with more uranium oxide to continue the reaction. The process may also be used with other transuranic oxides and rare earth metal oxides.

Willit, James L. (Batavia, IL); Ackerman, John P. (Prescott, AZ); Williamson, Mark A. (Naperville, IL)

2009-12-29T23:59:59.000Z

238

CARBON DIOXIDE AND OUR OCEAN LEGACY  

E-Print Network [OSTI]

is a biologist at the California State Univer- sity San Marcos, with expertise in the effects of carbon dioxideCARBON DIOXIDE AND OUR OCEAN LEGACY G Carbon Dioxide: Our Role The United States is the single. Every day the average American adds about 118 pounds of carbon dioxide to the atmos- phere, due largely

239

Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide from the post-  

E-Print Network [OSTI]

Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide dioxide separation and sequestration because the lower cost of carbon dioxide separation from for injection of carbon dioxide into oil or gas-bearing formations. An advantage of sequestration involving

240

Corrosion of Titanium Matrix Composites  

SciTech Connect (OSTI)

The corrosion behavior of unalloyed Ti and titanium matrix composites containing up to 20 vol% of TiC or TiB{sub 2} was determined in deaerated 2 wt% HCl at 50, 70, and 90 degrees C. Corrosion rates were calculated from corrosion currents determined by extrapolation of the tafel slopes. All curves exhibited active-passive behavior but no transpassive region. Corrosion rates for Ti + TiC composites were similar to those for unalloyed Ti except at 90 degrees C where the composites were slightly higher. Corrosion rates for Ti + TiB{sub 2} composites were generally higher than those for unalloyed Ti and increased with higher concentrations of TiB{sub 2}. XRD and SEM-EDS analyses showed that the TiC reinforcement did not react with the Ti matrix during fabrication while the TiB{sub 2} reacted to form a TiB phase.

Covino, B.S., Jr.; Alman, D.E.

2002-09-22T23:59:59.000Z

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Neutron scattering and models: Titanium  

SciTech Connect (OSTI)

Differential neutron elastic-scattering cross sections of elemental titanium were measured from 4.5 {r_arrow} 10.0 MeV in incident energy increments of {approx} 0.5 MeV. At each energy the measurements were made at forty or more scattering angles distributed between {approx} 17 and 160{degree}. Concurrently, differential neutron inelastic-scattering cross sections were measured for observed excitations of 0.975 {+-} 0.034, 1.497 {+-} 0.033, 2.322 {+-} 0.058, 3.252 {+-} 0.043, 3.700 {+-} 0.093, 4.317 {+-} 0.075 and 4.795 {+-} 0.100 MeV. All of the observed inelastically-scattered neutron groups were composites of contributions from several isotopes and/or levels. The experimental results were used to develop energy-average optical, statistical and coupled-channels models.

Smith, A.B.

1997-07-01T23:59:59.000Z

242

Membranes for separation of carbon dioxide  

DOE Patents [OSTI]

Methods for separating carbon dioxide from a fluid stream at a temperature higher than about 200.degree. C. with selectivity higher than Knudsen diffusion selectivity include contacting a porous membrane with the fluid stream to preferentially transport carbon dioxide. The porous membrane includes a porous support and a continuous porous separation layer disposed on a surface of the porous support and extending between the fluid stream and the porous support layer. The porous support comprises alumina, silica, zirconia, stabilized zirconia, stainless steel, titanium, nickel-based alloys, aluminum-based alloys, zirconium-based alloys or a combination thereof. Median pore size of the porous separation layer is less than about 10 nm, and the porous separation layer comprises titania, MgO, CaO, SrO, BaO, La.sub.2O.sub.3, CeO.sub.2, HfO.sub.2, Y.sub.2O.sub.3, VO.sub.z, NbO.sub.z, TaO.sub.z, ATiO.sub.3, AZrO.sub.3, AAl.sub.2O.sub.4, A.sup.1FeO.sub.3, A.sup.1MnO.sub.3, A.sup.1CoO.sub.3, A.sup.1NiO.sub.3, A.sup.2HfO.sub.3, A.sup.3 CeO.sub.3, Li.sub.2ZrO.sub.3, Li.sub.2SiO.sub.3, Li.sub.2TiO.sub.3, Li.sub.2HfO.sub.3, A.sup.4N.sup.1.sub.yO.sub.z, Y.sub.xN.sup.1.sub.yO.sub.z, La.sub.xN.sup.1.sub.yO.sub.z, HfN.sup.2.sub.yO.sub.z, or a combination thereof; wherein A is La, Mg, Ca, Sr or Ba; A.sup.1 is La, Ca, Sr or Ba; A.sup.2 is Ca, Sr or Ba; A.sup.3 is Sr or Ba; A.sup.4 is Mg, Ca, Sr, Ba, Ti or Zr; N.sup.1 is V, Nb, Ta, Cr, Mo, W, Mn, Si or Ge; N.sup.2 is V, Mo, W or Si; x is 1 or 2; y ranges from 1 to 3; and z ranges from 2 to 7.

Ku, Anthony Yu-Chung (Rexford, NY); Ruud, James Anthony (Delmar, NY); Ramaswamy, Vidya (Niskayuna, NY); Willson, Patrick Daniel (Latham, NY); Gao, Yan (Niskayuna, NY)

2011-03-01T23:59:59.000Z

243

TiO2-modified Ag-CuO Reactive Air Brazes for Improved Wettability on Mixed Ionic/Electronic Conductors  

SciTech Connect (OSTI)

Mixed ionic/electronic conducting perovskite oxides such as lanthanum strontium cobalt ferrite (LSCF) are strong candidates for potential use in a number of electrochemical devices, including gas separation membranes and solid oxide fuel cells (SOFC). Underlying the excitement over the these novel ceramics is the engineering challenge of effectively incorporating them into practical devices. Taking full advantage of the unique properties of advanced ceramics such as mixed conducting oxides depends in large part on being able to develop reliable joining techniques. Earlier studies have indicated that Ag-CuO reactive air braze (RAB) compositions are effective in joining to LSCF. Meanwhile, it has been found that small additions of as little as 0.5 mol% titanium oxide to Ag-CuO RAB compositions cause a dramatic increase in the wettability of RAB on many oxide ceramic surfaces. Therefore the wettabilty of Ag-CuO-TiO2 brazes on LSCF substrates will be examined and the flexural strength, microstructure, and conductivity of joints in LSCF made using Ag-CuO-TiO2 brazes will be discussed. Long-term aging effects on conductivity and microstructure will also be presented.

Hardy, John S.; Weil, K. Scott; Kim, Jin Yong Y.; Thomsen, Ed C.; Darsell, Jens T.

2005-03-01T23:59:59.000Z

244

Low-Cost Titanium Alloy Production  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Systems Titanium (Ti) is highly valued for its strength-to-weight ratio and corrosion re- sistance. However, after it is processed to a wrought, or shaped form, it is...

245

High modulus carbon fiber/titanium laminates  

E-Print Network [OSTI]

Titanium has been used to meet ever-stricter standards for high-temperature performance, creep resistance, low weight and high strength. Having low density, a high melting point, and high tensile strength, it seems like ...

Tsang, Lina

2006-01-01T23:59:59.000Z

246

Carbon Dioxide: Threat or Opportunity?  

E-Print Network [OSTI]

catastrophic long term effects on world climate. An alternative to discharging carbon dioxide into the atmosphere is to find new uses. One possible use is in 'Biofactories'. Biofactories may be achieved by exploiting two new developing technologies: Solar...

McKinney, A. R.

1982-01-01T23:59:59.000Z

247

Reducing carbon dioxide to products  

DOE Patents [OSTI]

A method reducing carbon dioxide to one or more products may include steps (A) to (C). Step (A) may bubble said carbon dioxide into a solution of an electrolyte and a catalyst in a divided electrochemical cell. The divided electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode may reduce said carbon dioxide into said products. Step (B) may adjust one or more of (a) a cathode material, (b) a surface morphology of said cathode, (c) said electrolyte, (d) a manner in which said carbon dioxide is bubbled, (e), a pH level of said solution, and (f) an electrical potential of said divided electrochemical cell, to vary at least one of (i) which of said products is produced and (ii) a faradaic yield of said products. Step (C) may separate said products from said solution.

Cole, Emily Barton; Sivasankar, Narayanappa; Parajuli, Rishi; Keets, Kate A

2014-09-30T23:59:59.000Z

248

Recuperative supercritical carbon dioxide cycle  

DOE Patents [OSTI]

A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

2014-11-18T23:59:59.000Z

249

Black Conductive Titanium Oxide High-Capacity Materials for Battery Electrodes  

SciTech Connect (OSTI)

Stoichiometric titanium dioxide (TiO{sub 2}) is one of the most widely studied transitionmetal oxides because of its many potential applications in photoelectrochemical systems, such as dye-sensitized TiO{sub 2} electrodes for photovoltaic solar cells, and water-splitting catalysts for hydrogen generation, and in environmental purification for creating or degrading specific compounds. However, TiO{sub 2} has a wide bandgap and high electrical resistivity, which limits its use as an electrode. A set of non-stoichiometric titanium oxides called the Magneli phases, having a general formula of Ti{sub n}O{sub 2n-1} with n between 4 and 10, exhibits lower bandgaps and resistivities, with the highest electrical conductivities reported for Ti{sub 4}O{sub 7}. These phases have been formulated under different conditions, but in all reported cases the resulting oxides have minimum grain sizes on the order of micrometers, regardless of the size of the starting titanium compounds. In this method, nanoparticles of TiO{sub 2} or hydrogen titanates are first coated with carbon using either wet or dry chemistry methods. During this process the size and shape of the nanoparticles are 'locked in.' Subsequently the carbon-coated nanoparticles are heated. This results in the transformation of the original TiO{sub 2} or hydrogen titanates to Magneli phases without coarsening, so that the original size and shape of the nanoparticles are maintained to a precise degree. People who work on batteries, fuel cells, ultracapacitors, electrosynthesis cells, electro-chemical devices, and soil remediation have applications that could benefit from using nanoscale Magneli phases of titanium oxide. Application of these electrode materials may not be limited to substitution for TiO{sub 2} electrodes. Combining the robustness and photosensitivity of TiO{sub 2} with higher electrical conductivity may result in a general electrode material.

Han, W.

2011-05-18T23:59:59.000Z

250

Thermochemical cyclic system for decomposing H/sub 2/O and/or CO/sub 2/ by means of cerium-titanium-sodium-oxygen compounds  

DOE Patents [OSTI]

A thermochemical closed cyclic process for the decomposition of water and/or carbon dioxide to hydrogen and/or carbon monoxide begins with the reaction of ceric oxide (CeO/sub 2/), titanium dioxide (TiO/sub 2/) and sodium titanate (Na/sub 2/TiO/sub 3/) to form sodium cerous titanate (NaCeTi/sub 2/O/sub 6/) and oxygen. Sodium cerous titanate (NaCeTi/sub 2/O/sub 6/) reacted with sodium carbonate (Na/sub 2/CO/sub 3/) in the presence of steam, produces hydrogen. The same reaction, in the absence of steam, produces carbon monoxide. The products, ceric oxide and sodium titanate, obtained in either case, are treated with carbon dioxide and water to produce ceric oxide, titanium dioxide, sodium titanate, and sodium bicarbonate. After dissolving sodium bicarbonate from the mixture in water, the remaining insoluble compounds are used as starting materials for a subsequent cycle. The sodium bicarbonate can be converted to sodium carbonate by heating and returned to the cycle.

Bamberger, C.E.

1980-04-24T23:59:59.000Z

251

Thermochemical cyclic system for decomposing H.sub.2 O and/or CO.sub.2 by means of cerium-titanium-sodium-oxygen compounds  

SciTech Connect (OSTI)

A thermochemical closed cyclic process for the decomposition of water and/or carbon dioxide to hydrogen and/or carbon monoxide begins with the reaction of ceric oxide (CeO.sub.2), titanium dioxide (TiO.sub.2) and sodium titanate (Na.sub.2 TiO.sub.3) to form sodium cerous titanate (NaCeTi.sub.2 O.sub.6) and oxygen. Sodium cerous titanate (NaCeTi.sub.2 O.sub.6) reacted with sodium carbonate (Na.sub.2 CO.sub.3) in the presence of steam, produces hydrogen. The same reaction, in the absence of steam, produces carbon monoxide. The products, ceric oxide and sodium titanate, obtained in either case, are treated with carbon dioxide and water to produce ceric oxide, titanium dioxide, sodium titanate, and sodium bicarbonate. After dissolving sodium bicarbonate from the mixture in water, the remaining insoluble compounds are used as starting materials for a subsequent cycle. The sodium bicarbonate can be converted to sodium carbonate by heating and returned to the cycle.

Bamberger, Carlos E. (Oak Ridge, TN)

1982-01-01T23:59:59.000Z

252

Process for preparing titanium nitride powder  

DOE Patents [OSTI]

A process for making titanium nitride powder by reaction of titanium phosphates with sodium cyanide. The process of this invention may comprise mixing one or more phosphates of Ti with a cyanide salt in the absence of oxygen and heating to a temperature sufficient to cause reaction to occur. In the preferred embodiment the ratio of cyanide salt to Ti should be at least 2 which results in the major Ti-containing product being TiN rather than sodium titanium phosphate byproducts. The process is an improvement over prior processes since the byproducts are water soluble salts of sodium which can easily be removed from the preferred TiN product by washing. 2 tabs.

Bamberger, C.E.

1988-06-17T23:59:59.000Z

253

Titanium sealing glasses and seals formed therefrom  

DOE Patents [OSTI]

Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La{sub 2}O{sub 3}, B{sub 2}O{sub 3}, TiO{sub 2} and Al{sub 2}O{sub 3} in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 2 figs.

Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

1997-12-02T23:59:59.000Z

254

Titanium sealing glasses and seals formed therefrom  

DOE Patents [OSTI]

Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La.sub.2 O.sub.3, B.sub.2 O.sub.3, TiO.sub.2 and Al.sub.2 O.sub.3 in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

1997-01-01T23:59:59.000Z

255

Surface Science Letters Bulk-defect dependent adsorption on a metal oxide surface  

E-Print Network [OSTI]

-6028(01)01067-6 #12;Titanium dioxide is a wide-band gap semicon- ductor (Egap 3 eV) that can easily be reducedSurface Science Letters Bulk-defect dependent adsorption on a metal oxide surface: S/TiO2(1 1 0) E Abstract The adsorption of molecular sulfur on TiO2(1 1 0)(1 ? 1) has been studied with scanning tunneling

Diebold, Ulrike

256

Hydrogen storage with titanium-functionalized graphene  

E-Print Network [OSTI]

We report on hydrogen adsorption and desorption on titanium-covered graphene in order to test theoretical proposals to use of graphene functionalized with metal atoms for hydrogen storage. At room temperature titanium islands grow with an average diameter of about 10 nm. Samples were then loaded with hydrogen, and its desorption kinetics was studied by thermal desorption spectroscopy. We observe the desorption of hydrogen in the temperature range between 400K and 700 K. Our results demonstrate the stability of hydrogen binding at room temperature and show that hydrogen desorbs at moderate temperatures in line with what required for practical hydrogen-storage applications.

Mashoff, Torge; Tanabe, Shinichi; Hibino, Hiroki; Beltram, Fabio; Heun, Stefan

2013-01-01T23:59:59.000Z

257

SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW  

E-Print Network [OSTI]

SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW J. E. Santos1, G. B. Savioli2, J. M. Carcione3, D´e, Argentina SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. I Storage of CO2). SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. II CO2 is separated from natural

Santos, Juan

258

Spectroscopy of Photovoltaic Materials: Charge-Transfer Complexes and Titanium Dioxide  

E-Print Network [OSTI]

RIVERSIDE Spectroscopy of Photovoltaic Materials: Charge-DISSERTATION Spectroscopy of Photovoltaic Materials: Charge-function of photovoltaic (PV) and photocatalytic (PC)

Dillon, Robert

2013-01-01T23:59:59.000Z

259

The Fabrication of Titanium Dioxide Based Anode Material Using Aerosol Method  

E-Print Network [OSTI]

interaction between lithium ion interactions. The doping ofwould benefit the interaction with lithium ions. (a) (b) (al. , Interaction and concerted diffusion of lithium in a (

Zhao, Lin

2013-01-01T23:59:59.000Z

260

Electrochemical investigation of the energetics of particulate titanium dioxide photocatalysts. The methyl viologen-acetate system  

SciTech Connect (OSTI)

Addition of methyl viologen (MV/sup 2 +/) enhances the anodic currents observed for TiO/sub 2/ suspensions under illumination by trapping of photogenerated electrons with formation of MV/sup +/. The magnitude of the photocurrent depends upon the relative location of the semiconductor Fermi level and E/sub redox/ of the MV/sup 2 +//MV/sup +/.couple. The location of the Fermi level in the anatase powders was estimated as -0.05 V vs. NHE (pH 0) based on the observed variation of photocurrent with pH. The shift in the quasi-Fermi level with light intensity is also discussed.

Ward, M.D.; White, J.R.; Bard, A.J.

1983-01-12T23:59:59.000Z

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Synthesis of Titanium Dioxide Hetero-Structures for Photovoltaic Energy Conversion  

E-Print Network [OSTI]

The photovoltaic energy conversion system (PV cells or solar cells) has been researched over the last few decades, and new technologies have been proposed. At the same time, the synthesis of nano-scale materials has been investigated intensively...

Park, Jongbok

2010-10-12T23:59:59.000Z

262

The Fabrication of Titanium Dioxide Based Anode Material Using Aerosol Method  

E-Print Network [OSTI]

Whittingham, M.S. , Lithium batteries and cathode materials.Whittingham, M.S. , Lithium batteries and cathode materials.applications of lithium secondary batteries. 2012: Wiley-VCH

Zhao, Lin

2013-01-01T23:59:59.000Z

263

The Fabrication of Titanium Dioxide Based Anode Material Using Aerosol Method  

E-Print Network [OSTI]

energy, rechargeable Li-ion battery based on carbon nanotubewith Sb and SnSb0.5 as Li-ion battery anodes. Carbon, 2003.Li, A review of application of carbon nanotubes for lithium ion battery

Zhao, Lin

2013-01-01T23:59:59.000Z

264

Standing Wave Enhancement of Red Absorbance and Photocurrent in Dye-Sensitized Titanium Dioxide  

E-Print Network [OSTI]

the Department of Chemistry, The PennsylVania State UniVersity, UniVersity Park, PennsylVania 16802, Central, American UniVersity of Beirut, Beirut 110236, Lebanon, and National Renewable Energy Laboratory, Golden have attracted much attention as inexpensive and relatively efficient solar photovol- taic devices

265

Effects of Nano-Titanium Dioxide on Freshwater Algal Population Dynamics  

E-Print Network [OSTI]

and Environment, University of Michigan, Ann Arbor, Michigan, United States of America Abstract To make used in paints, sunscreens, cosmetics, and solar technologies [1,4]. Like most nanomaterials

Cardinale, Bradley J.

266

An investigation of the reaction kinetics of photocatalytic wastewater treatment using suspended titanium dioxide catalyst  

E-Print Network [OSTI]

The goal of wastewater treatment is to remove compounds that may be harmful to the natural ecosystem or to humans. Although traditional treatment is fairly effective in meeting water quality standards, current technologies ...

Hotz, William Joseph, Jr

2014-01-01T23:59:59.000Z

267

Titanium Metal Powder Production by the Plasma Quench Process  

SciTech Connect (OSTI)

The goals of this project included the scale-up of the titanium hydride production process to a production rate of 50 kg/hr at a purity level of 99+%. This goal was to be achieved by incrementally increasing the production capability of a series of reactor systems. This methodic approach was designed to allow Idaho Titanium Technologies to systematically address the engineering issues associated with plasma system performance, and powder collection system design and performance. With quality powder available, actual fabrication with the titanium hydride was to be pursued. Finally, with a successful titanium production system in place, the production of titanium aluminide was to be pursued by the simultaneously injection of titanium and aluminum precursors into the reactor system. Some significant accomplishments of the project are: A unique and revolutionary torch/reactor capable of withstanding temperatures up to 5000 C with high thermal efficiency has been operated. The dissociation of titanium tetrachloride into titanium powder and HC1 has been demonstrated, and a one-megawatt reactor potentially capable of producing 100 pounds per hour has been built, but not yet operated at the powder level. The removal of residual subchlorides and adsorbed HC1 and the sintering of powder to form solid bodies have been demonstrated. The production system has been operated at production rates up to 40 pounds per hour. Subsequent to the end of the project, Idaho Titanium Technologies demonstrated that titanium hydride powder can indeed be sintered into solid titanium metal at 1500 C without sintering aids.

R. A. Cordes; A. Donaldson

2000-09-01T23:59:59.000Z

268

Titanium nitride electrodes for thermoelectric generators  

DOE Patents [OSTI]

The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film of titanium nitride as an electrode deposited onto solid electrolyte. The invention is also directed to the method of making same.

Novak, Robert F. (Farmington Hills, MI); Schmatz, Duane J. (Dearborn Heights, MI); Hunt, Thomas K. (Ann Arbor, MI)

1987-12-22T23:59:59.000Z

269

Process for making a titanium diboride-chromium diboride-yttrium titanium oxide ceramic composition  

DOE Patents [OSTI]

A ceramic composition composition is described. The ceramic composition consists essentially of from about 84 to 96 w/o titanium diboride, from about 1 to 9 w/o chromium diboride, and from about 3 to aobut 15 w/o yttrium-titanium-oxide. A method of making the ceramic composition is also described. The method of making the ceramic composition comprises the following steps: Step 1--A consolidated body containing stoichiometric quantities of titanium diboride and chromium diboride is provided. Step 2--The consolidated body is enclosed in and in contact with a thermally insulated package of yttria granules having a thickness of at least 0.5 inches. Step 3--The consolidated body enclosed in the thermally insulated package of yttria granules is heated in a microwave oven with microwave energy to a temperature equal to or greater than 1,900 degrees centigrade to sinter and uniformly disperse yttria particles having a size range from about 1 to about 12 microns throughout the consolidated body forming a densified body consisting essentially of titanium diboride, chromium diboride, and yttrium-titanium-oxide. The resulting densified body has enhanced fracture toughness and hardness.

Holcombe, Cressie E. (Knoxville, TN); Dykes, Norman L. (Oak Ridge, TN)

1992-01-01T23:59:59.000Z

270

Process for making a titanium diboride-chromium diboride-yttrium titanium oxide ceramic composition  

DOE Patents [OSTI]

A ceramic composition is described. The ceramic composition consists essentially of from about 84 to 96 w/o titanium diboride, from about 1 to 9 w/o chromium diboride, and from about 3 to about 15 w/o yttrium-titanium-oxide. A method of making the ceramic composition is also described. The method of making the ceramic composition comprises the following steps: Step 1--A consolidated body containing stoichiometric quantities of titanium diboride and chromium diboride is provided. Step 2--The consolidated body is enclosed in and in contact with a thermally insulated package of yttria granules having a thickness of at least 0.5 inches. Step 3--The consolidated body enclosed in the thermally insulated package of yttria granules is heated in a microwave oven with microwave energy to a temperature equal to or greater than 1,900 degrees centigrade to sinter and uniformly disperse yttria particles having a size range from about 1 to about 12 microns throughout the consolidated body forming a densified body consisting essentially of titanium diboride, chromium diboride, and yttrium-titanium-oxide. The resulting densified body has enhanced fracture toughness and hardness. No Drawings

Holcombe, C.E.; Dykes, N.L.

1992-04-28T23:59:59.000Z

271

An analysis of the impact of having uranium dioxide mixed in with plutonium dioxide  

SciTech Connect (OSTI)

An assessment was performed to show the impact on airborne release fraction, respirable fraction, dose conversion factor and dose consequences of postulated accidents at the Plutonium Finishing Plant involving uranium dioxide rather than plutonium dioxide.

MARUSICH, R.M.

1998-10-21T23:59:59.000Z

272

Thermal coatings for titanium-aluminum alloys  

SciTech Connect (OSTI)

Titanium aluminides and titanium alloys are candidate materials for use in hot structure and heat-shield components of hypersonic vehicles because of their good strength-to-weight characteristics at elevated temperature. However, in order to utilize their maximum temperature capability, they must be coated to resist oxidation and to have a high total remittance. Also, surface catalysis for recombination of dissociated species in the aerodynamic boundary layer must be minimized. Very thin chemical vapor deposition (CVD) coatings are attractive candidates for this application because of durability and very light weight. To demonstrate this concept, coatings of boron-silicon and aluminum-boron-silicon compositions were applied to the titanium-aluminides alpha2 (Ti-14Al-21Nb), super-alpha2 (Ti-14Al-23-Nb-2V), and gamma (Ti-33Al-6Nb-1Ta) and to the titanium alloy beta-21S (Ti-15Mo-3Al-3Nb-0.2Si). Coated specimens of each alloy were subjected to a set of simulated hypersonic vehicle environmental tests to determine their properties of oxidation resistance, surface catalysis, radiative emittance, and thermal shock resistance. Surface catalysis results should be viewed as relative performance only of the several coating-alloy combinations tested under the specific environmental conditions of the LaRC Hypersonic Materials Environmental Test System (HYMETS) arc-plasma-heated hypersonic wind tunnel. Tests were also conducted to evaluate the hydrogen transport properties of the coatings and any effects of the coating processing itself on fatigue life of the base alloys. Results are presented for three types of coatings, which are as follows: (1) a single layer boron silicon coating, (2) a single layer aluminum-boron-silicon coating, and (3) a multilayer coating consisting of an aluminum-boron-silicon sublayer with a boron-silicon outer layer.

Cunnington, G.R.; Clark, R.K.; Robinson, J.C.

1993-04-01T23:59:59.000Z

273

Time-resolved surface infrared spectroscopy during atomic layer deposition of TiO{sub 2} using tetrakis(dimethylamido)titanium and water  

SciTech Connect (OSTI)

Atomic layer deposition of titanium dioxide using tetrakis(dimethylamido)titanium (TDMAT) and water vapor is studied by reflection-absorption infrared spectroscopy (RAIRS) with a time resolution of 120?ms. At 190?C and 240?C, a decrease in the absorption from adsorbed TDMAT is observed without any evidence of an adsorbed product. Ex situ measurements indicate that this behavior is not associated with an increase in the impurity concentration or a dramatic change in the growth rate. A desorbing decomposition product is consistent with these observations. RAIRS also indicates that dehydroxylation of the growth surface occurs only among one type of surface hydroxyl groups. Molecular water is observed to remain on the surface and participates in reactions even at a relatively high temperature (110?C) and with long purge times (30?s)

Sperling, Brent A., E-mail: brent.sperling@nist.gov; Hoang, John; Kimes, William A.; Maslar, James E. [Chemical Sciences Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8320, Gaithersburg, Maryland 20899-8320 (United States); Steffens, Kristen L. [Biomolecular Measurement Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8362, Gaithersburg, Maryland 20899-8362 (United States); Nguyen, Nhan V. [Semiconductor and Dimensional Metrology Division, National Institute of Standards and Technology, 100 Bureau Dr., Stop 8120, Gaithersburg, Maryland 20899-8120 (United States)

2014-05-15T23:59:59.000Z

274

SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW  

E-Print Network [OSTI]

SEISMIC MONITORING OF. CARBON DIOXIDE FLUID FLOW. J. E. Santos. 1. , G. B. Savioli. 2. , J. M. Carcione. 3. , D. Gei. 3. 1. CONICET, IGPUBA, Fac.

santos

275

VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE FROM  

E-Print Network [OSTI]

(for water: the SPC-, SPC/E-, and TIP4P-potential models; for carbon dioxide: the EPM2 potential model dioxide are calculated. For water, the SPC- and TIP4P-models give superior results for the vapor pressure when compared to the SPC/E-model. The vapor liquid equilibrium of the binary mixture carbon dioxide

276

anodized titanium discs: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

mixed anatase and rutile phases. Under simulated AM 1.5 G illumination, the peak solar energy conversion Heller, Eric 6 Biocompatibility of osteoblast cells on titanium implants....

277

Process for preparing fine grain titanium carbide powder  

DOE Patents [OSTI]

A method for preparing finely divided titanium carbide powder in which an organotitanate is reacted with a carbon precursor polymer to provide an admixture of the titanium and the polymer at a molecular-level due to a crosslinking reaction between the organotitanate and the polymer. The resulting gel is dried, pyrolyzed to drive off volatile components and provide carbon. The resulting solids are then heated at an elevated temperature to convert the titanium and carbon to high-purity titanium carbide powder in a submicron size range.

Janey, Mark A. (Concord, TN)

1986-01-01T23:59:59.000Z

278

DOE - Office of Legacy Management -- Titanium Alloys Manufacturing...  

Office of Legacy Management (LM)

Morgan to Roth; Shipment of Zr Tetrachloride; August 22, 1949 NY.41-8 - Letter; Johnson to Titanium Alloy Manufacturing Division (Attn.: Urban); Source Material License No....

279

An experimental investigation of the urea-water decomposition and selective catalytic reduction (SCR) of nitric oxides with urea using V2O5-WO3-TiO2 catalyst.  

E-Print Network [OSTI]

) stream. The decomposition experiments were conducted with a number of oxygen (O2) compositions (0, 1, 10, and 15%) over the temperature range of 227oC to 477oC. The study showed ammonia (NH3), carbon-dioxide (CO2) and nitric oxide (NO) as the major...

Johar, Jasmeet Singh

2005-11-01T23:59:59.000Z

280

A laser-ablation ICP-MS study of Apollo 15 low-titanium olivine-normative and quartz-normative mare basalts  

E-Print Network [OSTI]

differences in the mantle source to explain the $25% difference in whole-rock TiO2, and corresponding-normative basalt types, based on their different SiO2, FeO, and TiO2 whole-rock compositions. Previous studies have as originating from different lunar mantle source regions. To provide new information on the compositions

Perfect, Ed

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

atmospheric sulphur dioxide: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carbon dioxide CERN Preprints Summary: The primary ingredient of Anthropogenic Global Warming hypothesis is the assumption that atmospheric carbon dioxide variations are the cause...

282

Carbon dioxide-assisted fabrication of highly uniform submicron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dioxide-assisted fabrication of highly uniform submicron-sized colloidal carbon spheres via hydrothermal carbonization Carbon dioxide-assisted fabrication of highly uniform...

283

Optimize carbon dioxide sequestration, enhance oil recovery  

E-Print Network [OSTI]

- 1 - Optimize carbon dioxide sequestration, enhance oil recovery January 8, 2014 Los Alamos simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known production. Due to carbon capture and storage technology advances, prolonged high oil prices

284

Electron beam melting and casting of zirconium and titanium alloys  

SciTech Connect (OSTI)

The results of electron beam melting (EBM) and casting Zirconium and Titanium alloys are discussed. The data on different schedules used for EBM of this metals as well as equipment for crucible melting and special equipment for casting are described. The results of production of Zirconium and Titanium alloy mold castings for various purposes are presented.

Arzhakova, V.M.; Popov, E.I. [A.A. Bochvar All Union Scientific and Research Institute of Inorganic Materials, Moscow (Russian Federation); Dubrovski, V.A.; Frolov, V.I. [PO ChMZ, Glazov (Russian Federation); Ladohin, S.V.; Levitsky, N.I.; Chernyavsky, V.B. [Scientific and Research Institute of Casting, Kiev (Ukraine)

1994-12-31T23:59:59.000Z

285

Vanadium-pumped titanium x-ray laser  

DOE Patents [OSTI]

A resonantly photo-pumped x-ray laser is formed of a vanadium and titanium foil combination that is driven by two beams of intense line focused optical laser radiation. Ground state neon-like titanium ions are resonantly photo-pumped by line emission from fluorine-like vanadium ions. 4 figs.

Nilsen, J.

1992-05-26T23:59:59.000Z

286

Vanadium-pumped titanium x-ray laser  

DOE Patents [OSTI]

A resonantly photo-pumped x-ray laser (10) is formed of a vanadium (12) and titanium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state neon-like titanium ions (34) are resonantly photo-pumped by line emission from fluorine-like vanadium ions (32).

Nilsen, Joseph (Livermore, CA)

1992-01-01T23:59:59.000Z

287

Stress enhanced diffusion of krypton ions in polycrystalline titanium  

SciTech Connect (OSTI)

An experimental investigation on the mutual influence of pre-existing residual stress and point defect following ion implantation is presented. The study has been carried out using polycrystalline titanium samples energetically implanted with krypton ions at different fluences. Ion beam analysis was used to determine the concentration profile of the injected krypton ions, while synchrotron X-ray diffraction has been used for stress determination. Ion beam analysis and synchrotron X-ray diffraction stress profile measurements of the implanted titanium samples show a clear evidence of stress-enhanced diffusion of krypton ions in titanium. It is further observed that for the titanium samples implanted at low fluence, ion implantation modifies the pre-existing residual stress through the introduction of point and open volume defects. The stress fields resulting from the ion implantation act to drift the krypton inclusions towards the surface of titanium.

Nsengiyumva, S., E-mail: s.nsengiyumva@ru.ac.za [Department of Physics and Electronics, Rhodes University, Grahamstown 6140 (South Africa); Raji, A. T. [School of Interdisciplinary Research and Graduate Studies, University of South Africa, Mucklenuek Campus, P O Box 392, UNISA 0003, Pretoria (South Africa); Rivire, J. P. [Laboratoire de Mtallurgie Physique, UMR 6630 CNRS- Universit de Poitiers, Bd M. et P. Curie, BP30179, 86962 Chasseneuil Futuroscope, Cedex (France); Britton, D. T.; Hrting, M. [NanoSciences Innovation Center, Department of Physics, University of Cape Town, Rondebosch 7701 (South Africa)

2014-07-14T23:59:59.000Z

288

Sandia National Laboratories: TiO2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmitted for USMaterials ProgramProtected: Tech ReferenceEnhancementTiO2

289

A MOLECULAR SIMULATION STUDY OF ADSORPTION OF NITROGEN AND METHANE IN TITANIUM SILICATE (ETS-4)  

E-Print Network [OSTI]

A MOLECULAR SIMULATION STUDY OF ADSORPTION OF NITROGEN AND METHANE IN TITANIUM SILICATE (ETS-4 titanium silicate ETS-4 (Engelhard titanium silicate) are calculated using grand canonical Monte Carlo. Commun. 2010, Vol. 75, No. 2, pp. 145­164 Adsorption of Nitrogen and Methane in Titanium Silicate 145

Lisal, Martin

290

Displacement of crude oil by carbon dioxide  

E-Print Network [OSTI]

by Carbon Dioxide (December 1980) Olusegun Omole, B. S. , University of Ibadan, Nigeria Chairman of Advisory Committee: Dr. J. S. Osoba It has long been recognized that carbon dioxide could be used as an oil recovery agent. Both laboratory and field...- tion. Crude oil from the Foster Field in West Texas, of 7 cp and 34 API, 0 was used as the oil in place. Oil displacements were conducted at pres- sures between 750 psig and 1800 ps1g, and at a temperature of 110 F. 0 Carbon dioxide was injected...

Omole, Olusegun

1980-01-01T23:59:59.000Z

291

Identifying and Developing New, Carbon Dioxide Consuming Processes , Sudheer Indalaa  

E-Print Network [OSTI]

of propane, styrene from ethyl benzene and carbon dioxide, and methanol from hydrogenation of carbon dioxide408b Identifying and Developing New, Carbon Dioxide Consuming Processes Aimin Xua , Sudheer Indalaa@hal.lamar.edu, yawscl@hal.lamar.edu Key words; Carbon Dioxide Processes, Greenhouse Gases, Chemical Complex, Sustainable

Pike, Ralph W.

292

TEMPORARILY ALLOYING TITANIUM TO FACILITATE FRICTION STIR WELDING  

SciTech Connect (OSTI)

While historically hydrogen has been considered an impurity in titanium, when used as a temporary alloying agent it promotes beneficial changes to material properties that increase the hot-workability of the metal. This technique known as thermohydrogen processing was used to temporarily alloy hydrogen with commercially pure titanium sheet as a means of facilitating the friction stir welding process. Specific alloying parameters were developed to increase the overall hydrogen content of the titanium sheet ranging from commercially pure to 30 atomic percent. Each sheet was evaluated to determine the effect of the hydrogen content on process loads and tool deformation during the plunge phase of the friction stir welding process. Two materials, H-13 tool steel and pure tungsten, were used to fabricate friction stir welding tools that were plunged into each of the thermohydrogen processed titanium sheets. Tool wear was characterized and variations in machine loads were quantified for each tool material and weld metal combination. Thermohydrogen processing was shown to beneficially lower plunge forces and stabilize machine torques at specific hydrogen concentrations. The resulting effects of hydrogen addition to titanium metal undergoing the friction stir welding process are compared with modifications in titanium properties documented in modern literature. Such comparative analysis is used to explain the variance in resulting process loads as a function of the initial hydrogen concentration of the titanium.

Hovanski, Yuri

2009-05-06T23:59:59.000Z

293

Regulating carbon dioxide capture and storage  

E-Print Network [OSTI]

This essay examines several legal, regulatory and organizational issues that need to be addressed to create an effective regulatory regime for carbon dioxide capture and storage ("CCS"). Legal, regulatory, and organizational ...

De Figueiredo, Mark A.

2007-01-01T23:59:59.000Z

294

Carbon Dioxide Emission Factors for Coal  

Reports and Publications (EIA)

The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

1994-01-01T23:59:59.000Z

295

Titanium aluminide intermetallic alloys with improved wear resistance  

SciTech Connect (OSTI)

The invention is directed to a method for producing a titanium aluminide intermetallic alloy composition having an improved wear resistance, the method comprising heating a titanium aluminide intermetallic alloy material in an oxygen-containing environment at a temperature and for a time sufficient to produce a top oxide layer and underlying oxygen-diffused layer, followed by removal of the top oxide layer such that the oxygen-diffused layer is exposed. The invention is also directed to the resulting oxygen-diffused titanium aluminide intermetallic alloy, as well as mechanical components or devices containing the improved alloy composition.

Qu, Jun; Lin, Hua-Tay; Blau, Peter J.; Sikka, Vinod K.

2014-07-08T23:59:59.000Z

296

Thorium dioxide: properties and nuclear applications  

SciTech Connect (OSTI)

This is the sixth book on reactor materials published under sponsorship of the Naval Reactors Office of the United States Department of Energy, formerly the United States Atomic Energy Commission. This book presents a comprehensive compilation of the most significant properties of thorium dioxide, much like the book Uranium Dioxide: Properties and Nuclear Applications presented information on the fuel material used in the Shippingport Pressurized Water Reactor core.

Belle, J.; Berman, R.M. (eds.)

1984-01-01T23:59:59.000Z

297

Surface roughness of anodized titanium coatings.  

SciTech Connect (OSTI)

Samples of grade five 6Al4V titanium alloy were coated with two commercial fluoropolymer anodizations (Tiodize and Canadize) and compared. Neither coating demonstrates significant outgassing. The coatings show very similar elemental analysis, except for the presence of lead in the Canadize coating, which may account for its lower surface friction in humid environments. Surface roughness has been compared by SEM, contact profilometry, optical profilometry, power spectral density and bidirectional scattering distribution function (BSDF). The Tiodize film is slightly smoother by all measurement methods, but the Canadize film shows slightly less scatter at all angles of incidence. Both films exhibited initial friction coefficients of 0.2 to 0.4, increasing to 0.4 to 0.8 after 1000 cycles of sliding due to wear of the coating and ball. The coatings are very similar and should behave identically in most applications.

Dugger, Michael Thomas; Chinn, Douglas Alan

2010-10-01T23:59:59.000Z

298

Cleaning graphene with a titanium sacrificial layer  

SciTech Connect (OSTI)

Graphene is a promising material for future electronic applications and chemical vapor deposition of graphene on copper is a promising method for synthesizing graphene on the wafer scale. The processing of such graphene films into electronic devices introduces a variety of contaminants which can be difficult to remove. An approach to cleaning residues from the graphene channel is presented in which a thin layer of titanium is deposited via thermal e-beam evaporation and immediately removed. This procedure does not damage the graphene as evidenced by Raman spectroscopy, greatly enhances the electrical performance of the fabricated graphene field effect transistors, and completely removes the chemical residues from the surface of the graphene channel as evidenced by x-ray photoelectron spectroscopy.

Joiner, C. A., E-mail: cjoiner3@gatech.edu; Roy, T.; Hesabi, Z. R.; Vogel, E. M. [School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Chakrabarti, B. [School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Department of Materials Science and Engineering, The University of Texas at Dallas, Richardson, Texas 75080 (United States)

2014-06-02T23:59:59.000Z

299

Cesium titanium silicate and method of making  

DOE Patents [OSTI]

The invention is the new material, a ternary compound of cesium, silica, and titania, together with a method of making the ternary compound, cesium titanium silicate pollucite. More specifically, the invention is Cs.sub.2 Ti.sub.2 Si.sub.4 O.sub.13 pollucite which is a new crystalline phase representing a novel class of Ti-containing zeolites. Compositions contain relatively high Cs.sub.2 O and TiO.sub.2 loadings and are durable glass and ceramic materials. The amount of TiO.sub.2 and Cs.sub.2 that can be incorporated into these glasses and crystalline ceramics far exceeds the limits set for the borosilicate high level waste glass.

Balmer, Mari L. (West Richland, WA)

1997-01-01T23:59:59.000Z

300

Cesium titanium silicate and method of making  

DOE Patents [OSTI]

The invention is the new material, a ternary compound of cesium, silica, and titania, together with a method of making the ternary compound, cesium titanium silicate pollucite. More specifically, the invention is Cs{sub 2}Ti{sub 2}Si{sub 4}O{sub 13} pollucite which is a new crystalline phase representing a novel class of Ti-containing zeolites. Compositions contain relatively high Cs{sub 2}O and TiO{sub 2} loadings and are durable glass and ceramic materials. The amount of TiO{sub 2} and Cs{sub 2} that can be incorporated into these glasses and crystalline ceramics far exceeds the limits set for the borosilicate high level waste glass. 10 figs.

Balmer, M.L.

1997-01-07T23:59:59.000Z

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Waterless TiO{sub 2} atomic layer deposition using titanium tetrachloride and titanium tetraisopropoxide  

SciTech Connect (OSTI)

The surface chemistry for TiO{sub 2} atomic layer deposition (ALD) typically utilizes water or other oxidants that can oxidize underlying substrates such as magnetic disks or semiconductors. To avoid this oxidation, waterless or oxidant-free surface chemistry can be used that involves titanium halides and titanium alkoxides. In this study, waterless TiO{sub 2} ALD was accomplished using titanium tetrachloride (TiCl{sub 4}) and titanium tetraisopropoxide (TTIP). In situ transmission Fourier transform infrared (FTIR) studies were employed to study the surface species and the reactions during waterless TiO{sub 2} ALD. At low temperatures between 125 and 225??C, the FTIR absorbance spectra revealed that the isopropoxide species remained on the surface after TTIP exposures. The TiCl{sub 4} exposures then removed the isopropoxide species and deposited additional titanium species. At high temperatures between 250 and 300??C, the isopropoxide species were converted to hydroxyl species by ?-hydride elimination. The observation of propene gaseous reaction product by quadrupole mass spectrometry (QMS) confirmed the ?-hydride elimination reaction pathway. The TiCl{sub 4} exposures then easily reacted with the hydroxyl species. QMS studies also observed the 2-chloropropane and HCl gaseous reaction products and monitored the self-limiting nature of the TTIP reaction. Additional studies examined the waterless TiO{sub 2} ALD growth at low and high temperature. Quartz crystal microbalance measurements observed growth rates of ?3?ng/cm{sup 2} at a low temperature of 150??C. Much higher growth rates of ?15?ng/cm{sup 2} were measured at a higher temperature of 250??C under similar reaction conditions. X-ray reflectivity analysis measured a growth rate of 0.55 0.05?/cycle at 250??C. X-ray photoelectron depth-profile studies showed that the TiO{sub 2} films contained low Cl concentrations <1 at. %. This waterless TiO{sub 2} ALD process using TiCl{sub 4} and TTIP should be valuable to prevent substrate oxidation during TiO{sub 2} ALD on oxygen-sensitive substrates.

Anderson, Virginia R.; Cavanagh, Andrew S.; Abdulagatov, Aziz I. [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215 (United States); Gibbs, Zachary M. [Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309-0424 (United States); George, Steven M., E-mail: Steven.George@Colorado.Edu [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215 and Department of Mechanical Engineering, University of Colorado, Boulder, Colorado 80309-0427. (United States)

2014-01-15T23:59:59.000Z

302

Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance Technology available for licensing: Li4Ti5O12 spinel is a promising alternative to graphite electrodes with...

303

Interdiffusivity in titanium-tantalum alloys processed at 1473 K  

E-Print Network [OSTI]

Titanium-tantalum (Ti-Ta) alloys are likely to have a high biocompatibility and corrosion resistance that renders them novel materials of interest for biomedical applications[7, 14, 2]. With high strength and a low elastic ...

Dibbern, Jennifer C

2007-01-01T23:59:59.000Z

304

Increasing carbon dioxideIncreasing carbon dioxide & its effect on forest& its effect on forest  

E-Print Network [OSTI]

ecosystem's natural capacity toA forest ecosystem's natural capacity to capture energy, capture energy's natural capacity toA forest ecosystem's natural capacity to capture energy, capture energy, sustain life10/13/2010 1 Increasing carbon dioxideIncreasing carbon dioxide & its effect on forest& its effect

Gray, Matthew

305

Electrical discharge machining of titanium diboride and its composites  

E-Print Network [OSTI]

ELECTRICAL DISCHARGE MACHINING OF TITANIUM DIBORIDE AND ITS COMPOSITES A Thesis by HARMOHINDER SINGH BEDI Submitted to the office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE December 1990 Major Subject: Chemical Engineering ELECTRICAL DISCHARGE MACHINING OF TITANIUM DIBORIDE AND ITS COMPOSITES A THESIS by HARMOHINDER SINGH BEDI Approved as to style and content by: Ahmed M. Gadalla (Chair of Committee) Ralph...

Bedi, Harmohinder Singh

1990-01-01T23:59:59.000Z

306

Carbon dioxide capture process with regenerable sorbents  

DOE Patents [OSTI]

A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

2002-05-14T23:59:59.000Z

307

1. Lithographically Patterned Gold/Manganese Dioxide Core/Shell...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LiPF6 salt, lithium was clearly and controllably electroplated on nanoscale titanium electrodes under galvanostatic control, and a formation of natural andor...

308

Percutaneous Vertebroplasty in a Broken Vertebral Titanium Implant (Titanium Mesh Cage)  

SciTech Connect (OSTI)

We report the case of a percutaneous consolidation of a broken vertebral implant (Surgical Titanium Mesh Implants; DePuy Spine, Raynham, MA, USA) by vertebroplasty. Four years after anterior spondylectomy with cage implantation and stabilization with posterior instrumentation, the patient was admitted for excruciating back pain. Radiographs showed fracture of the cage, screw, and rod. An anterior surgical approach was deemed difficult and a percutaneous injection of polymethyl methacrylate into the cage was performed following posterior instrumentation replacement. This seems to be an interesting alternative to the classical anterior surgical approach, which is often difficult in postoperative conditions.

Bierry, G.; Buy, X.; Mohan, P. Chandra; Cupelli, J. [University Hospital of Strasbourg, Department of Radiology B (France); Steib, J.P. [University Hospital of Strasbourg, Department of Orthopedic and Spinal Surgery (France); Gangi, A. [University Hospital of Strasbourg, Department of Radiology B (France)], E-mail: gangi@rad6.u-strasbg.fr

2006-08-15T23:59:59.000Z

309

SEQUESTERING CARBON DIOXIDE IN COALBEDS  

SciTech Connect (OSTI)

The authors' long-term goal is to develop accurate prediction methods for describing the adsorption behavior of gas mixtures on solid adsorbents over complete ranges of temperature, pressure, and adsorbent types. The originally-stated, major objectives of the current project are to: (1) measure the adsorption behavior of pure CO{sub 2}, methane, nitrogen, and their binary and ternary mixtures on several selected coals having different properties at temperatures and pressures applicable to the particular coals being studied, (2) generalize the adsorption results in terms of appropriate properties of the coals to facilitate estimation of adsorption behavior for coals other than those studied experimentally, (3) delineate the sensitivity of the competitive adsorption of CO{sub 2}, methane, and nitrogen to the specific characteristics of the coal on which they are adsorbed; establish the major differences (if any) in the nature of this competitive adsorption on different coals, and (4) test and/or develop theoretically-based mathematical models to represent accurately the adsorption behavior of mixtures of the type for which measurements are made. As this project developed, an important additional objective was added to the above original list. Namely, we were encouraged to interact with industry and/or governmental agencies to utilize our expertise to advance the state of the art in coalbed adsorption science and technology. As a result of this additional objective, we participated with the Department of Energy and industry in the measurement and analysis of adsorption behavior as part of two distinct investigations. These include (a) Advanced Resources International (ARI) DOE Project DE-FC26-00NT40924, ''Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on Wet Tiffany Coal'', and (b) the DOE-NETL Project, ''Round Robin: CO{sub 2} Adsorption on Selected Coals''. These activities, contributing directly to the DOE projects listed above, also provided direct synergism with the original goals of our work. Specific accomplishments of this project are summarized below in three broad categories: experimentation, model development, and coal characterization.

K.A.M. Gasem; R.L. Robinson, Jr.; J.E. Fitzgerald; Z. Pan; M. Sudibandriyo

2003-04-30T23:59:59.000Z

310

A new route for the synthesis of titanium silicalite-1  

SciTech Connect (OSTI)

Graphical abstract: Well-prepared TS-1 was synthesized by an innovative procedure using inexpensive reagents such as fumed silica and TPABr as structure-directing agent. This is the first time when highly crystalline TS-1 is obtained in basic medium, using sodium hydroxide as HO{sup -} ion source required for the crystallization process. Hydrolysis of titanium source has been prevented by titanium complexation with acetylacetone before structuring gel. Highlights: Black-Right-Pointing-Pointer TS-1 was obtained using cheap reagents as fumed silica and tetrapropylammonium bromide. Black-Right-Pointing-Pointer First time NaOH was used as source of OH{sup -} ions required for crystallization process. Black-Right-Pointing-Pointer The hydrolysis Ti alkoxides was controlled by Ti complexation with 2,4-pentanedione. -- Abstract: A new and efficient route using inexpensive reagents such as fumed silica and tetrapropylammonium bromide is proposed for the synthesis of titanium silicalite-1. High crystalline titanium silicalite-1 was obtained in alkaline medium, using sodium hydroxide as HO{sup -} ion source required for the crystallization process. Hydrolysis of titanium source with formation of insoluble oxide species was prevented by titanium complexation with before structuring gel. The final solids were fully characterized by powder X-ray diffraction, scanning electron microscopy, Fourier transform infrared, ultraviolet-visible diffuse reflectance, Raman and atomic absorption spectroscopies, as well as nitrogen sorption analysis. It was found that a molar ratio Ti:Si of about 0.04 in the initial reaction mixture is the upper limit to which well formed titanium silicalite-1 with channels free of crystalline or amorphous material can be obtained. Above this value, solids with MFI type structure containing both Ti isomorphously substituted in the network and extralattice anatase nanoparticles inside of channels is formed.

Vasile, Aurelia, E-mail: aurelia_vasile@yahoo.com [Laboratory of Materials Chemistry, Faculty of Chemistry, 'Al.I. Cuza' University of Iasi, B-dul Carol I, No. 11, 700506 Iasi (Romania)] [Laboratory of Materials Chemistry, Faculty of Chemistry, 'Al.I. Cuza' University of Iasi, B-dul Carol I, No. 11, 700506 Iasi (Romania); Busuioc-Tomoiaga, Alina Maria [Laboratory of Materials Chemistry, Faculty of Chemistry, 'Al.I. Cuza' University of Iasi, B-dul Carol I, No. 11, 700506 Iasi (Romania) [Laboratory of Materials Chemistry, Faculty of Chemistry, 'Al.I. Cuza' University of Iasi, B-dul Carol I, No. 11, 700506 Iasi (Romania); Catalysis Research Department, ChemPerformance SRL, Iasi 700337 (Romania)

2012-01-15T23:59:59.000Z

311

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network [OSTI]

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

312

A methodology for forecasting carbon dioxide flooding performance  

E-Print Network [OSTI]

A methodology was developed for forecasting carbon dioxide (CO2) flooding performance quickly and reliably. The feasibility of carbon dioxide flooding in the Dollarhide Clearfork "AB" Unit was evaluated using the methodology. This technique is very...

Marroquin Cabrera, Juan Carlos

1998-01-01T23:59:59.000Z

313

Dry process fluorination of uranium dioxide using ammonium bifluoride  

E-Print Network [OSTI]

An experimental study was conducted to determine the practicality of various unit operations for fluorination of uranium dioxide. The objective was to prepare ammonium uranium fluoride double salts from uranium dioxide and ...

Yeamans, Charles Burnett, 1978-

2003-01-01T23:59:59.000Z

314

Carbon Dioxide Capture/Sequestration Tax Deduction (Kansas)  

Broader source: Energy.gov [DOE]

Carbon Dioxide Capture/Sequestration Tax Deduction allows a taxpayer a deduction to adjusted gross income with respect to the amortization of the amortizable costs of carbon dioxide capture,...

315

Louisiana Geologic Sequestration of Carbon Dioxide Act (Louisiana)  

Broader source: Energy.gov [DOE]

This law establishes that carbon dioxide and sequestration is a valuable commodity to the citizens of the state. Geologic storage of carbon dioxide may allow for the orderly withdrawal as...

316

The Greenness of Cities: Carbon Dioxide Emissions and Urban Development  

E-Print Network [OSTI]

carbon dioxide emissions per 1,000 cubic feet of natural gas. In this case, there is much less energy

Glaeser, Edward L.; Kahn, Matthew E.

2008-01-01T23:59:59.000Z

317

E-Print Network 3.0 - aluminum silicon titanium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

titanium, 6% aluminum, 4% vanadium, and 2% of other elements, such as iron, carbon... Titanium-alloy MEMS wing technology for a micro aerial vehicle application T. Nick Pornsin......

318

Adhesion improvement of electroless copper depositions on titanium nitride by low temperature annealing  

E-Print Network [OSTI]

copper depositions onto titanium nitride, a diffusion barrier material. In particular, an effort is made to characterize the adhesion of the electronics copper deposit on titanium nitride and the improvement of the adhesion produced by low temperature...

Eiserer, Rex Anthony

1999-01-01T23:59:59.000Z

319

Air Pollution XVI 247 Emissions of Nitrogen Dioxide from Modern  

E-Print Network [OSTI]

Air Pollution XVI 247 Emissions of Nitrogen Dioxide from Modern Diesel Vehicles G.A. Bishop and D negative implications for local photochemical ozone production. Keywords: Nitrogen dioxide, automobile strategies, Lemaire [1] suggests that nitrogen dioxide (NO2) was forgotten as a separate component of the NOx

Denver, University of

320

Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere  

E-Print Network [OSTI]

dioxide Water vapor #12;Atmospheric composition (parts per million by volume) · Nitrogen (N2) 780Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere Bill Satzer 3M Company #12;Outline,840 · Oxygen (O2) 209,460 · Argon (Ar) 9340 · Carbon dioxide (CO2) 394 · Methane (CH4) 1.79 · Ozone (O3) 0

Olver, Peter

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Nanostructured Tin Dioxide Materials for Gas Sensor Applications  

E-Print Network [OSTI]

CHAPTER 30 Nanostructured Tin Dioxide Materials for Gas Sensor Applications T. A. Miller, S. D) levels for some species. Tin dioxide (also called stannic oxide or tin oxide) semi- conductor gas sensors undergone extensive research and development. Tin dioxide (SnO2) is the most important material for use

Wooldridge, Margaret S.

322

Designed amyloid fibers as materials for selective carbon dioxide capture  

E-Print Network [OSTI]

Designed amyloid fibers as materials for selective carbon dioxide capture Dan Lia,b,c,1 , Hiroyasu demonstrate that amyloids, self-assembling protein fibers, are effective for selective carbon dioxide capture. Solid-state NMR proves that amyloid fibers containing alkylamine groups reversibly bind carbon dioxide

323

Chukwuemeka I. Okoye Carbon Dioxide Solubility and Absorption Rate in  

E-Print Network [OSTI]

Copyright by Chukwuemeka I. Okoye 2005 #12;Carbon Dioxide Solubility and Absorption Rate _______________________ Nicholas A. Peppas #12;Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O for. #12;iii Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O

Rochelle, Gary T.

324

Hydrothermal synthesis of nanocubes of sillenite type compounds for photovoltaic applications and solar energy conversion of carbon dioxide to fuels  

DOE Patents [OSTI]

The present invention relates to formation of nanocubes of sillenite type compounds, such as bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, via a hydrothermal synthesis process, with the resulting compound(s) having multifunctional properties such as being useful in solar energy conversion, environmental remediation, and/or energy storage, for example. In one embodiment, a hydrothermal method is disclosed that transforms nanoparticles of TiO.sub.2 to bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, optionally loaded with palladium nanoparticles. The method includes reacting titanium dioxide nanotubes with a bismuth salt in an acidic bath at a temperature sufficient and for a time sufficient to form bismuth titanate crystals, which are subsequently annealed to form bismuth titanate nanocubes. After annealing, the bismuth titanate nanocubes may be optionally loaded with nano-sized metal particles, e.g., nanosized palladium particles.

Subramanian, Vaidyanathan; Murugesan, Sankaran

2014-04-29T23:59:59.000Z

325

Introduction Air Quality and Nitrogen Dioxide  

E-Print Network [OSTI]

- Global update 2005. Primary sources of air pollutants include combustion products from power generationIntroduction Air Quality and Nitrogen Dioxide Air pollution can be defined as "the presence effects to man and/or the environment". (DEFRA) "Clean air is considered to be a basic requirement

326

Carbon Dioxide Corrosion: Modelling and Experimental Work  

E-Print Network [OSTI]

Carbon Dioxide Corrosion: Modelling and Experimental Work Applied to Natural Gas Pipelines Philip in the corrosion related research institutions at IFE and the Ohio University or any other scientific research;#12;Introduction - v - Summary CO2 corrosion is a general problem in the industry and it is expensive. The focus

327

Atmospheric Lifetime of Fossil Fuel Carbon Dioxide  

E-Print Network [OSTI]

Atmospheric Lifetime of Fossil Fuel Carbon Dioxide David Archer,1 Michael Eby,2 Victor Brovkin,3 released from combustion of fossil fuels equilibrates among the various carbon reservoirs of the atmosphere literature on the atmospheric lifetime of fossil fuel CO2 and its impact on climate, and we present initial

Scherer, Norbert F.

328

Hydroelectric Reservoirs -the Carbon Dioxide and Methane  

E-Print Network [OSTI]

Hydroelectric Reservoirs - the Carbon Dioxide and Methane Emissions of a "Carbon Free" Energy an overview on the greenhouse gas production of hydroelectric reservoirs. The goals are to point out the main how big the greenhouse gas emissions from hydroelectric reservoirs are compared to thermo-power plants

Fischlin, Andreas

329

Acid sorption regeneration process using carbon dioxide  

DOE Patents [OSTI]

Carboxylic acids are sorbed from aqueous feedstocks onto a solid adsorbent in the presence of carbon dioxide under pressure. The acids are freed from the sorbent phase by a suitable regeneration method, one of which is treating them with an organic alkylamine solution thus forming an alkylamine-carboxylic acid complex which thermally decomposes to the desired carboxylic acid and the alkylamine.

King, C. Judson (Kensington, CA); Husson, Scott M. (Anderson, SC)

2001-01-01T23:59:59.000Z

330

Carbon dioxide storage professor Martin Blunt  

E-Print Network [OSTI]

of CCS storage there are over a hundred sites worldwide where Co2 is injected under- ground as partCarbon dioxide storage professor Martin Blunt executive summary Carbon Capture and Storage (CCS and those for injection and storage in deep geological formations. all the individual elements operate today

331

Carbon Dioxide Capture from Coal-Fired  

E-Print Network [OSTI]

. LFEE 2005-002 Report #12;#12;i ABSTRACT Investments in three coal-fired power generation technologiesCarbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005 environment. The technologies evaluated are pulverized coal (PC), integrated coal gasification combined cycle

332

Carbon Dioxide Corrosion and Inhibition Studies  

E-Print Network [OSTI]

· Corrosion inhibition very important in the oil industry · Film forming inhibitors containing nitrogenCarbon Dioxide Corrosion and Inhibition Studies Kristin Gilida #12;Outline · Background = Zreal + Zim Rp 1/Corr Rate #12;Tafel · Measures corrosion rate directly · Measures iCORR from A and C

Petta, Jason

333

Organometallics 1987, 6, 2551-2556 2551 Seven-Coordinate Titanium and Vanadium Carbonyls. Synthesis  

E-Print Network [OSTI]

, with sodium naphthalenide in thf under carbon monoxide gives the titanium(0) carbonyl [~-BUSOrganometallics 1987, 6, 2551-2556 2551 Seven-Coordinate Titanium and Vanadium Carbonyls. Synthesis of the fourfold and threefold faces; the titanium and vanadium structures may also be described in terms of a face

Girolami, Gregory S.

334

Titanium diboride-chromium diboride-yttrium titanium oxide ceramic composition and a process for making the same  

DOE Patents [OSTI]

A ceramic composition is described. The ceramic composition consists essentially of from about 84 to 96 w/o titanium diboride, from about 1 to 9 w/o chromium diboride, and from about 3 to about 15 w/o yttrium-titanium-oxide. A method of making the ceramic composition is also described. The method of making the ceramic composition comprises the following steps: Step 1--A consolidated body containing stoichiometric quantities of titanium diboride and chromium diboride is provided. Step 2--The consolidated body is enclosed in and in contact with a thermally insulated package of yttria granules having a thickness of at least 0.5 inches. Step 3--The consolidated body enclosed in the thermally insulated package of yttria granules is heated in a microwave oven with microwave energy to a temperature equal to or greater than 1,900 degrees centigrade to sinter and uniformly disperse yttria particles having a size range from about 1 to about 12 microns throughout the consolidated body forming a densified body consisting essentially of titanium diboride, chromium diboride, and yttrium-titanium-oxide. The resulting densified body has enhanced fracture toughness and hardness.

Holcombe, Cressie E. (Knoxville, TN); Dykes, Norman L. (Oak Ridge, TN)

1991-01-01T23:59:59.000Z

335

Impact of silver and titanium dioxide nanoparticles on the in-vessel composting of biodegradable municipal solid waste  

E-Print Network [OSTI]

The extensive use of nanoparticles (NPs) has started receiving increased attention because of the knowledge gaps regarding their fate in the environment and the possible impact on the environment and human health. The ...

Stamou, Ioannis

2015-06-29T23:59:59.000Z

336

A kinetic and adsorption study of CO oxidation over unsupported fine gold powder and over gold supported on titanium dioxide  

SciTech Connect (OSTI)

The catalytic oxidation of CO with O{sub 2} and adsorption of CO{sub 2} and O{sub 2} on Au deposited on TiO{sub 2} (AuTiO{sub 2}, mean diameter of gold particles 3.5 nm), TiO{sub 2}, and unsupported Au powder (mean diameter 76 nm) have been investigated by using a closed recirculation reaction system. The catalytic oxidation of CO with O{sub 2} on Au/TiO{sub 2} measured at 253--293 K proceeded very rapidly. In the same temperature range, fine gold powder was catalytically active, while TiO{sub 2} alone was entirely inactive for the oxidation. The rate constant of CO oxidation per unit of surface area of gold was larger by two orders of magnitude for Au/TiO{sub 2} than for Au powder. Adsorption of CO and CO{sub 2} occurred almost instantaneously and reversibly on preoxidized Au/TiO{sub 2}, whereas a slow increase in the O{sub 2} pressure was observed at 273 K in the absence of evacuation. A similar increase of O{sub 2} pressure was observed from oxidized TiO{sub 2}, but Au powder did not show any increase. The increase was ascribed to the desorption of weakly adsorbed O{sub 2} on the support surface of Au/TiO{sub 2}. The rate of reduction of preoxidized Au/TiO{sub 2} with CO almost corresponded to the increase in the O{sub 2} pressure and was far smaller than the rate of the catalytic oxidation of CO with O{sub 2} on the catalyst, indicating that molecular oxygen weakly adsorbed on the support surface of Au/TiO{sub 2} contributes only partly to the catalytic oxidation of CO. During the oxidation, O{sub 2} in the gas phase may be directly activated on the surface of deposited gold particles and/or on the very narrow perimeter interface between the gold and the support.

Iizuka, Yasuo; Tode, Toshihisa; Takao, Toshiaki; Yatsu, Kenichiro; Takeuchi, Toshiaki; Tsubota, Susumu; Haruta, Masatake

1999-10-01T23:59:59.000Z

337

Channeling of electron transport to improve collection efficiency in mesoporous titanium dioxide dye sensitized solar cell stacks  

SciTech Connect (OSTI)

Dye-sensitized solar cell (DSC) modules are generally made by interconnecting large photoelectrode strips with optimized thickness (?14??m) and show lower current density (J{sub SC}) compared with their single cells. We found out that the key to achieving higher J{sub SC} in large area devices is optimized photoelectrode volume (V{sub D}), viz., thickness and area which facilitate the electron channeling towards working electrode. By imposing constraints on electronic path in a DSC stack, we achieved >50% increased J{sub SC} and ?60% increment in photoelectric conversion efficiency in photoelectrodes of similar V{sub D} (?3.36??10{sup ?4} cm{sup 3}) without using any metallic grid or a special interconnections.

Fakharuddin, Azhar; Ahmed, Irfan; Yusoff, Mashitah M.; Jose, Rajan, E-mail: rjose@ump.edu.my, E-mail: joserajan@gmail.com [Nanostructured Renewable Energy Materials Laboratory, Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang, 26300 Pahang (Malaysia); Khalidin, Zulkeflee [Faculty of Electrical and Electronics Engineering, Universiti Malaysia Pahang, 26300 Pahang (Malaysia)

2014-02-03T23:59:59.000Z

338

Effect of polymer-nanoparticle interactions on the glass transition dynamics and the conductivity mechanism in polyurethane titanium dioxide nanocomposites  

SciTech Connect (OSTI)

We report on the glass transition dynamics and the conductivity properties of a nanodielectric system composed of pre-synthesized TiO{sub 2} nanoparticles embedded in thermoplastic polyurethane. Increase of TiO{sub 2} loading results in enhanced segmental mobility of the composites and less steep temperature dependence, i.e., lower fragility index. The decrease in the fragility index and glass transition temperature is discussed based on the FTIR results. We observe different behavior of conductivity for temperatures above and below the glass transition temperature. At high temperatures the composites exhibit conductivity values more than 2 orders of magnitude higher than those in the pristine matrix. At the same time, at sub-Tg temperatures composites are characterized by superior electrical insulation properties compared to pristine matrix material. Such drastic temperature dependence of the conductivity/insulating ability of the flexible and light-weight, low-Tg composite material can be utilized in various applications including sensing and temperature switching materials.

Polyzos, Georgios [ORNL; Tuncer, Enis [ORNL; Agapov, Alexander L [ORNL; Stevens, Derrick [ORNL; Sokolov, Alexei P [ORNL; Kidder, Michelle [ORNL; Jacobs, [Air Force Research Laboratory, Wright-Patterson AFB, OH; Koerner, Hilmar [Air Force Research Laboratory, Wright-Patterson AFB, OH; Vaia, Richard [Air Force Research Laboratory, Wright-Patterson AFB, OH; More, Karren Leslie [ORNL; Sauers, Isidor [ORNL

2012-01-01T23:59:59.000Z

339

Dissimilar friction welding of titanium alloys to alloy 718  

SciTech Connect (OSTI)

The design of advanced, high-performance gas-turbine engines will require the utilization of elevated-temperature titanium-based materials, including conventional alloys, titanium aluminides, and titanium metal-matrix composites. The most efficient utilization of these materials in the engine compressor section would be achieved by directly joining these materials to existing nickel-base superalloys, such as Alloy 718. To date, the dissimilar welding of titanium alloys to nickel-based alloys has not been common practice because intermetallic compounds form in the weld and cause embrittlement. Special welding techniques must be developed to inhibit this compound formation and to provide high strength welds. In this investigation, a friction welding process was developed for joining titanium alloys (Ti-6Al-2Sn-4Zr-2Mo and Ti-6Al-4V) to nickel-based superalloy Alloy 718. An interlayer system comprised of copper and niobium sheet layers was employed as a diffusion barrier and weld deformation enhancer. A postweld heat treatment (PWHT, 700{degrees}C for 20 min in vacuum) under axial pressure (Ksi) was used to improve the joint strength consistency. The following conclusions can be drawn from this investigation: (1) A friction welding technique has been developed for joining titanium alloys (Ti-6Al-2Sn-4Zr-2Mo and Ti-6Al-4V) to Alloy 718 using an interlayer system of niobium and copper. Joint strengths averaging approximately 50 Ksi were achieved. (2) Deformation was concentrated in the interlayers, especially the copper interlayer, during friction welding. Increased reduction in length (RIL) during friction welding resulted in a decrease in the interlayer thicknesses. (3) The EDS results showed that the niobium and copper interlayers prevent interdiffusion between the two parent metals, producing formation of detrimental phases.

Kuo, M.; Albright, C.E.; Baeslack, W.A. III

1994-12-31T23:59:59.000Z

340

Electron beam evaporation for titanium metal matrix composites  

SciTech Connect (OSTI)

3M, in partnership with ARPA, is developing electron beam evaporation as a method for producing titanium metal matrix composites (TMC`s). This paper discusses some of the opportunities presented by these strong and lightweight structural materials but also points out the many challenges which must be met. The excellent mechanical properties of titanium matrix composites have been recognized for quite some time; however use of these materials has been limited by the lack of a commercially viable process to produce them. 3M is removing this logjam in processing technology by using high rate electron beam evaporation technology to manufacture these materials on a significantly large scale.

Storer, J. [3M, Mendota Heights, MN (United States)

1994-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Titanium tritide radioisotope heat source development : palladium-coated titanium hydriding kinetics and tritium loading tests.  

SciTech Connect (OSTI)

We have found that a 180 nm palladium coating enables titanium to be loaded with hydrogen isotopes without the typical 400-500 C vacuum activation step. The hydriding kinetics of Pd coated Ti can be described by the Mintz-Bloch adherent film model, where the rate of hydrogen absorption is controlled by diffusion through an adherent metal-hydride layer. Hydriding rate constants of Pd coated and vacuum activated Ti were found to be very similar. In addition, deuterium/tritium loading experiments were done on stacks of Pd coated Ti foil in a representative-size radioisotope heat source vessel. The experiments demonstrated that such a vessel could be loaded completely, at temperatures below 300 C, in less than 10 hours, using existing department-of-energy tritium handling infrastructure.

Van Blarigan, Peter; Shugard, Andrew D.; Walters, R. Tom (Savannah River National Labs, Aiken, SC)

2012-01-01T23:59:59.000Z

342

Increasing the active surface of titanium islands on graphene by nitrogen sputtering  

E-Print Network [OSTI]

Titanium-island formation on graphene as a function of defect density is investigated. When depositing titanium on pristine graphene, titanium atoms cluster and form islands with an average diameter of about 10nm and an average height of a few atomic layers. We show that if defects are introduced in the graphene by ion bombardment, the mobility of the deposited titanium atoms is reduced and the average diameter of the islands decreases to 5nm with monoatomic height. This results in an optimized coverage for hydrogen storage applications since the actual titanium surface available per unit graphene area is significantly increased.

Mashoff, T; Miseikis, V; Coletti, C; Piazza, V; Beltram, F; Heun, S

2014-01-01T23:59:59.000Z

343

Causal Factors of Weld Porosity in Gas Tungsten Arc Welding of Powder Metallurgy Produced Titanium Alloys  

SciTech Connect (OSTI)

ORNL undertook an investigation using gas tungsten arc (GTA) welding on consolidated powder metallurgy (PM) titanium (Ti) plate, to identify the causal factors behind observed porosity in fusion welding. Tramp element compounds of sodium and magnesium, residual from the metallothermic reduction of titanium chloride used to produce the titanium, were remnant in the starting powder and were identified as gas forming species. PM-titanium made from revert scrap where sodium and magnesium were absent, showed fusion weld porosity, although to a lesser degree. We show that porosity was attributable to hydrogen from adsorbed water on the surface of the powders prior to consolidation. The removal / minimization of both adsorbed water on the surface of titanium powder and the residues from the reduction process prior to consolidation of titanium powders, are critical to achieve equivalent fusion welding success similar to that seen in wrought titanium produced via the Kroll process.

Muth, Thomas R [ORNL; Yamamoto, Yukinori [ORNL; Frederick, David Alan [ORNL; Contescu, Cristian I [ORNL; Chen, Wei [ORNL; Lim, Yong Chae [ORNL; Peter, William H [ORNL; Feng, Zhili [ORNL

2013-01-01T23:59:59.000Z

344

Instrument Development and Measurements of the Atmospheric Pollutants Sulfur Dioxide, Nitrate Radical, and Nitrous Acid by Cavity Ring-down Spectroscopy and Cavity Enhanced Absorption Spectroscopy  

E-Print Network [OSTI]

A. , A method of nitrogen dioxide and sulphur dioxidedetermination of nitrogen dioxide and sulfur dioxide in theDOAS) have measured nitrogen dioxide (NO 2 ), nitrate

Medina, David Salvador

2011-01-01T23:59:59.000Z

345

Integration of Arsenic Trisulfide and Titanium Diffused Lithium Niobate Waveguides  

E-Print Network [OSTI]

A chalcogenide glass (arsenic-trisulfide, As2S3) optical waveguide is vertically integrated onto titanium-diffused lithium-niobate (Ti:LiNbO3) waveguides to add optical feedback paths and to create more compact optical circuits. Lithium...

Solmaz, Mehmet E.

2011-08-08T23:59:59.000Z

346

Frequency stabilization of a Titanium-Sapphire laser for  

E-Print Network [OSTI]

Frequency stabilization of a Titanium-Sapphire laser for precision spectroscopy on Calcium ions . . . . . . . . . . . . . . . . . . . . . . . 53 5.3.2 In-loop error signal . . . . . . . . . . . . . . . . . . . . . . 56 6 Laser linewidth 59 6.1 Performance estimation with the in-loop error signal . . . . . . . 59 6.1.1 Theoretical description

Blatt, Rainer

347

Fractal Studies on Titanium-Silica Aerogels using SMARTer  

SciTech Connect (OSTI)

Power-law scattering approximation has been employed to reveal the fractal structures of solid-state titanium-silica aerogel samples. All small-angle neutron scattering (SANS) measurements were performed using 36 meters SANS BATAN spectrometer (SMARTer) at the neutron scattering laboratory (NSL) in Serpong, Indonesia. The mass fractal dimension of titanium-silica aerogels at low scattering vector q range increases from -1.4 to -1.92 with the decrease of acid concentrations during sol-gel process. These results are attributed to the titanium-silica aerogels that are growing to more polymeric and branched structures. At high scattering vector q range the Porod slope of -3.9 significantly down to -2.24 as the roughness of particle surfaces becomes higher. The cross over between these two regimes decreases from 0.4 to 0.16 nm{sup -1} with the increase of acid concentrations indicating also that the titanium-silica aerogels are growing.

Putra, E. Giri Rachman; Ikram, A.; Bharoto; Santoso, E. [Neutron Scattering Laboratory, BATAN, Kawasan Puspiptek Serpong, Tangerang 15314 (Indonesia); Fang, T. Chiar; Ibrahim, N. [Department of Physics, Faculty of Science Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor (Malaysia); Mohamed, A. Aziz [Materials Technology Group, Industrial Technology Division Agensi Nuklear Malaysia, 43000 Kajang (Malaysia)

2008-03-17T23:59:59.000Z

348

Degradation mode survey of titanium-base alloys  

SciTech Connect (OSTI)

Of the materials reviewed, commercially pure titanium, Ti Gr 2, is the most susceptible to crevice corrosion. Ti Gr 7, 12, and 16 are likely to be resistant to crevice corrosion under the current expected Yucca Mountain repository conditions. Although Grade 7 has the greatest resistance to crevice corrosion it is also the most expensive. Although the possibility of sustained loads cracking exists, it has not yet been observed in a Ti alloys. For hydride precipitation to occur 100{degrees}C, the hydrogen concentration would need to be relatively high, much higher than the maximum amount of hydrogen allowed during the manufacture of ({alpha} Ti alloys (0.0 15 wt%). A large amount of (SCC) stress corrosion cracking data accumulated at SNL and BNL for the WIPP program and by the Canadian Waste Management Program on titanium grades 2 and 12 indicates that there is no SCC at naturally occurring potentials in various brines. Hydride-induced cracking of titanium is a possibility and therefore, further investigation of this phenomenon under credible repository conditions is warranted. One disadvantage of titanium and its alloys is that their strengths decrease rather rapidly with temperature. This is due to the strong temperature dependence of interstitial solute strengthening mechanisms. Ti Gr 12 and 16 are recommended for further consideration as candidate materials for high level nuclear waste containers.

Gdowski, G.E. [Lawrence Livermore National Lab., CA (United States); Ahluwalia, H.S. [Science and Engineering Associates, Inc., Livermore, CA (United States)

1995-01-30T23:59:59.000Z

349

Titanium Enolates of Thiazolidinethione Chiral Auxiliaries: Versatile Tools for  

E-Print Network [OSTI]

extensively and are now an important and general method for asymmetric carbon-carbon bond forma- tion.1 of titanium tetrachloride and nature of the amine employed.3 However, more easily cleavable auxiliaries than by conversion of the amino alcohol to the thiazolidinethione by exposure to carbon disulfide and 1 M KOH6

350

Anisotropic reactive ion etching of vanadium dioxide  

E-Print Network [OSTI]

. Weichold Vanadium dioxide (V02) was anisotropically reactive ion etched using carbon tetrafluoride (CF4) . CF4, as an etch gas, provided the chemistry along with the control needed to achieve an anisotropic etch. This chemistry was practically inert... with vanadium quite easily. This leads to interest in using a fluorine- based chemistry. The goal of this research is to produce a selective anisotropic reactive ion etch for VO2 /photoresist using only carbon tetrafluoride (CFq) . Reactive ion etching...

Radle, Byron K

1990-01-01T23:59:59.000Z

351

Gel and process for preventing carbon dioxide break through  

SciTech Connect (OSTI)

A process is described for retarding the flow of carbon dioxide in carbon dioxide break-through fingers in a subterranean formation, the process comprising: (a) introducing a gas selected from the group consisting of carbon dioxide and gases containing carbon dioxide into a subterranean deposit containing carbon dioxide break-through fingers; (b) after the carbon dioxide break-through fingers have sorbed a predetermined amount of the gas, stopping the flow of the gas into the subterranean formation, (c) after stopping the flow of the gas into the subterranean formation, introducing an effective amount of a gel-forming composition into the subterranean formation and into the carbon dioxide break-through fingers, the gel-forming composition being operable, when contacting carbon dioxide break-through fingers containing the brine which has absorbed substantial amounts of carbon dioxide to form a gel in the fingers which is operable for retarding the flow of the gas in the finger. The gel-forming composition comprises: i. an aqueous solution comprising a first substance selected from the group consisting of polyvinyl alcohols, polyvinyl alcohol copolymers, and mixtures thereof, and ii. an amount of a second substance selected from the group consisting of aldehydes, aldehyde generating substances, acetals, acetal generating substances, and mixtures thereof.

Sandiford, B.B.; Zillmer, R.C.

1987-06-16T23:59:59.000Z

352

The Greenness of Cities: Carbon Dioxide Emissions and Urban Development  

E-Print Network [OSTI]

dioxide impact of electricity consumption in different majorand residential electricity consumption. Car usage and homefor fuel oil and electricity consumption. We then use

Glaeser, Edward L.; Kahn, Matthew E.

2008-01-01T23:59:59.000Z

353

Carbon dioxide absorbent and method of using the same  

SciTech Connect (OSTI)

In accordance with one aspect, the present invention provides a composition which contains the amino-siloxane structures I, or III, as described herein. The composition is useful for the capture of carbon dioxide from process streams. In addition, the present invention provides methods of preparing the amino-siloxane composition. Another aspect of the present invention provides methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention, as species which react with carbon dioxide to form an adduct with carbon dioxide.

Perry, Robert James; O'Brien, Michael Joseph

2014-06-10T23:59:59.000Z

354

Carbon Dioxide Capture and Storage Demonstration in Developing...  

Open Energy Info (EERE)

Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Capture and Storage Demonstration in Developing Countries: Analysis of Key Policy Issues and Barriers...

355

assisted silicon dioxide: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dioxide substrates is described. The approach consists of solid such as displays and thin-film polycrystalline solar cells. Particularly important for low- cost thin-film solar...

356

Sulfur dioxide removal by enhanced electrostatics  

SciTech Connect (OSTI)

The economic removal of sulfur dioxide (SO{sub 2}) still represents a significant technical challenge which could determine the use of certain types of fossil fuels for energy production. This paper will present the preliminary results of an innovative research project utilizing a low-cost wet electrostatic precipitator to remove sulfur dioxide. There are many aspects for gas removal in an electrostatic precipitator which are not currently being used. This project utilizes electron attachment of free electrons onto gas molecules and ozone generation to remove sulfur dioxide which is a typical flue gas pollutant. This research was conducted on a bench-scale, wet electrostatic precipitator. A direct-current negative discharge corona is used to generate the ozone in-situ. This ozone will be used to oxidize SO{sub 2} to form sulfuric acid, which is very soluble in water. However, it is believed that the primary removal mechanism is electron attachment of the free electrons from the corona which force the SO{sub 2} to go to equilibrium with the water and be removed from the gas stream. Forcing the equilibrium has been shown to achieve removal efficiencies of up to 70%. The bench scale unit has been designed to operate wet or dry, positive and negative for comparison purposes. The applied dc voltage is variable from 0 to 100 kV, the flow rate is a nominal 7 m{sup 3}/hr and the collecting electrode area is 0.20 m{sup 2}. Tests are conducted on a simulated flue gas stream with SO{sub 2} ranging from 0 to 4,000 ppmv. This paper presents the results of tests conducted to determine the effect of operating conditions on removal efficiency. The removal efficiency was found to vary with gas residence time, water flow rate, inlet concentration, applied power, and the use of corona pulsing.

Larkin, K.; Tseng, C.; Keener, T.C.; Khang, S.J. [Univ. of Cincinnati, OH (United States)

1997-12-31T23:59:59.000Z

357

Nitrogen dioxide, sulfur dioxide, and ammonia detector for remote sensing of vehicle emissions  

E-Print Network [OSTI]

with sulfuric and nitric acids formed from at- mospheric oxidations of sulfur dioxide SO2 and nitrogen oxides mobile sources comes from the combustion of sulfur compounds in fuel. The U.S. is in the process of reducing sulfur in fuel for all mobile sources. This process begins with ultralow sulfur on-road diesel

Denver, University of

358

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III (SAGE III)  

E-Print Network [OSTI]

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas extinction. We retrieve ozone and nitrogen dioxide number densities and aerosol extinction from transmission), Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III

359

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures  

E-Print Network [OSTI]

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures Nitrogen Dioxide and Nitric Oxide Print a copy and insert into your laboratory the precautions and safe handling procedures for the use of Nitrogen Dioxide

Cohen, Ronald C.

360

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates  

E-Print Network [OSTI]

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates #12 Satellite observations of ozone and nitrogen dioxide: from retrievals to emission es- timates / by Bas Subject headings: satellite retrieval / nitrogen dioxide / ozone / air pollution / emis- sion estimates

Haak, Hein

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Apparatus for extracting and sequestering carbon dioxide  

DOE Patents [OSTI]

An apparatus and method associated therewith to extract and sequester carbon dioxide (CO.sub.2) from a stream or volume of gas wherein said apparatus hydrates CO.sub.2 and reacts the resulting carbonic acid with carbonate. Suitable carbonates include, but are not limited to, carbonates of alkali metals and alkaline earth metals, preferably carbonates of calcium and magnesium. Waste products are metal cations and bicarbonate in solution or dehydrated metal salts, which when disposed of in a large body of water provide an effective way of sequestering CO.sub.2 from a gaseous environment.

Rau, Gregory H. (Castro Valley, CA); Caldeira, Kenneth G. (Livermore, CA)

2010-02-02T23:59:59.000Z

362

Method for extracting and sequestering carbon dioxide  

DOE Patents [OSTI]

A method and apparatus to extract and sequester carbon dioxide (CO.sub.2) from a stream or volume of gas wherein said method and apparatus hydrates CO.sub.2, and reacts the resulting carbonic acid with carbonate. Suitable carbonates include, but are not limited to, carbonates of alkali metals and alkaline earth metals, preferably carbonates of calcium and magnesium. Waste products are metal cations and bicarbonate in solution or dehydrated metal salts, which when disposed of in a large body of water provide an effective way of sequestering CO.sub.2 from a gaseous environment.

Rau, Gregory H. (Castro Valley, CA); Caldeira, Kenneth G. (Livermore, CA)

2005-05-10T23:59:59.000Z

363

Capture of carbon dioxide by hybrid sorption  

DOE Patents [OSTI]

A composition, process and system for capturing carbon dioxide from a combustion gas stream. The composition has a particulate porous support medium that has a high volume of pores, an alkaline component distributed within the pores and on the surface of the support medium, and water adsorbed on the alkaline component, wherein the proportion of water in the composition is between about 5% and about 35% by weight of the composition. The process and system contemplates contacting the sorbent and the flowing gas stream together at a temperature and for a time such that some water remains adsorbed in the alkaline component when the contact of the sorbent with the flowing gas ceases.

Srinivasachar, Srivats

2014-09-23T23:59:59.000Z

364

A Vortex Contactor for Carbon Dioxide Separations  

SciTech Connect (OSTI)

Many analysts identify carbon dioxide (CO2) capture and separation as a major roadblock in efforts to cost effectively mitigate greenhouse gas emissions via sequestration. An assessment 4 conducted by the International Energy Agency (IEA) Greenhouse Gas Research and Development Programme cited separation costs from $35 to $264 per tonne of CO2 avoided for a conventional coal fired power plant utilizing existing capture technologies. Because these costs equate to a greater than 40% increase in current power generation rates, it appears obvious that a significant improvement in CO2 separation technology is required if a negative impact on the world economy is to be avoided.

Raterman, Kevin Thomas; Mc Kellar, Michael George; Turner, Terry Donald; Podgorney, Anna Kristine; Stacey, Douglas Edwin; Stokes, B.; Vranicar, J.

2001-05-01T23:59:59.000Z

365

Capture of Carbon Dioxide Archived Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites Proposed Route BTRICGEGR-N-Capture of Carbon Dioxide Archived

366

Electron beam melting of charge based on titanium sponge  

SciTech Connect (OSTI)

An experience of 0.8 MW consumable box melting furnace operation and theoretical simulation have led to the further development of the FIKO plant under construction on the base of melting of two consumable box-like bullets which move opposite each other and form narrow heated space between melted butt ends. It allows to reduce vaporization, spatter and radiation losses by several times and to reach two times increase in melting rate and 99%(97%) yield for c.p. titanium (alloys) without furnace power add. Future furnace design will provide the optimum protection of vacuum pumps against chlorides, the safety when melting titanium sponge and will permit hot ingots to move to the special furnace for EB surface conditioning. The maximum productivity is to be 18,000 t/year. The furnace can be used for the manufacture of aluminum-, copper-, iron-, nickel-, tungsten-based alloys and others of any charge including salvage.

Tikhonovsky, A.L.; Tikhonovsky, K.A. [JS Co FIKO, Kiev (Ukraine)

1995-12-31T23:59:59.000Z

367

High-Resolution Soft X-Ray Spectral Analysis in the CK Region of Titanium Carbide (TiC) using the DV-X alpha Molecular Orbital Method  

E-Print Network [OSTI]

in the CK Region of Titanium Carbide (TiC) using the DV-X?USA Keyword titanium carbide, soft X-ray spectroscopy,C K region of titanium carbide (TiC). The spectral profiles

Shimomura, Kenta

2010-01-01T23:59:59.000Z

368

Intermetallic and titanium matrix composite materials for hypersonic applications  

SciTech Connect (OSTI)

As part of the French Program of Research and Technology for Advanced Hypersonic Propulsion (PREPHA) which was launched in 1992 between Aerospatiale, Dassault Aviation, ONERA, SNECMA and SEP, an important work is specially devoted to the development of titanium and intermetallic composite materials for large airframe structures. At Dassault Aviation, starting from a long experience in Superplastic Forming - Diffusion Bonding (SPF-DB) of titanium parts, the effort is brought on the manufacturing and characterization of composites made from Timet beta 21S or IMI 834 foils and Textron SCS6 fiber fabrics. At `Aersopatiale Espace & Defence`, associated since a long time about intermetallic composite materials with university research laboratories, the principal effort is brought on plasma technology to develop the gamma titanium aluminide TiAl matrix composite reinforced by protected silicon carbide fibers (BP SM 1240 or TEXTRON SCS6). The objective, is to achieve, after 3 years of time, to elaborate a medium size integrally stiffened panel (300 x 600 sq mm).

Berton, B.; Surdon, G.; Colin, C. [Dassault Aviation, Saint-Cloud (France)]|[Aersopatiale Space & Defence, St Medard en Jalles (France)

1995-09-01T23:59:59.000Z

369

Oxygen-Diffused Titanium as a Candidate Brake Rotor Material  

SciTech Connect (OSTI)

Titanium alloys are one of several candidate materials for the next generation of truck disk brake rotors. Despite their advantages of lightweight relative to cast iron and good strength and corrosion resistance, titanium alloys are unlikely to be satisfactory brake rotor materials unless their friction and wear behavior can be significantly improved. In this study, a surface engineering process oxygen diffusion was applied to titanium rotors and has shown very encouraging results. The oxygen diffused Ti-6Al-4V (OD-Ti) was tested on a sub-scale brake tester against a flat block of commercial brake lining material and benchmarked against several other Ti-based materials, including untreated Ti-6Al-4V, ceramic particle-reinforced Ti composites (MMCs), and a thermal-spray-coated Ti alloy. With respect to friction, the OD-Ti outperformed all other candidate materials under the imposed test conditions with the friction coefficient remaining within a desirable range of 0.35-0.50, even under the harshest conditions when the disk surface temperature reached nearly 600 ?C. In addition, the OD-Ti showed significantly improved wear-resistance over the non-treated one and was even better than the Ti-based composite materials.

Qu, Jun [ORNL; Blau, Peter Julian [ORNL; Jolly, Brian C [ORNL

2009-01-01T23:59:59.000Z

370

Thickness measurement of aluminum, titanium, titanium silicide, and tungsten silicide films by x-ray fluorescence  

SciTech Connect (OSTI)

X-ray fluorescence (XRF) has received a great deal of attention in the last few years as a quantitative means of determining both the stoichiometry and thickness of many different kinds of films. Examples include Ag and Cu films on mica substrates, Sn-Pb alloys on steel substrates, Al-Ti multilayers on Cu substrates and oxide films on silicon substrates. In XRF the sample is irradiated with x-rays which in turn cause x-rays to be given off by the sample. These x-rays that are given off by the sample can then be analyzed both for energy and intensity. The energy of the x-rays is characteristic of the elemental makeup of the sample and the intensity of the x-rays is dependent on how much of the particular element is present. The intensity then can be related to the thickness of a film if the stoichiometry of the film can be assumed constant. With the increased interest in silicides and more recently, the self-aligned silicide (salicide) process (8-10) for VLSI applications, in-line process monitoring of silicide film thickness has become important to integrated circuit manufacturing. In this study, the number of x-ray photons given of by Al, Ti, titanium silicide, and tungsten silicide films on silicon-based substrates was quantified so that a film thickness for an unknown sample could then be determined easily. In addition, XRF is a more accurate technique, limited principally by the accuracy technique, limited principally by the accuracy of the reference used and the amount of time the x-ray photons are counted.

Ernst, S.; Lee, C.O.; Lee, J.J. (Motorola, Inc., Advanced Products Research and Development Lab., Austin, TX (US))

1988-08-01T23:59:59.000Z

371

Faraday rotation spectroscopy of nitrogen dioxide based on a widely tunable external cavity quantum cascade laser  

E-Print Network [OSTI]

Faraday rotation spectroscopy of nitrogen dioxide based on a widely tunable external cavity quantum: Faraday Rotation Spectroscopy, external-cavity quantum cascade laser, nitrogen dioxide, trace

372

ORNL/CDIAC-143 CARBON DIOXIDE, HYDROGRAPHIC, AND CHEMICAL DATA OBTAINED DURING THE  

E-Print Network [OSTI]

Kozyr Carbon Dioxide Information Analysis Center Oak Ridge National Laboratory Oak Ridge, Tennessee, U Prepared by the Carbon Dioxide Information Analysis Center OAK RIDGE NATIONAL LABORATORY Oak Ridge

373

E-Print Network 3.0 - applied carbon dioxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7 By-Products Utilization Summary: Center for By-Products Utilization DRAFT REPORT CARBON DIOXIDE SEQUESTRATION IN CEMENTITIOUS... -MILWAUKEE 12;CARBON DIOXIDE...

374

E-Print Network 3.0 - american carbon dioxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7 By-Products Utilization Summary: Center for By-Products Utilization DRAFT REPORT CARBON DIOXIDE SEQUESTRATION IN CEMENTITIOUS... -MILWAUKEE 12;CARBON DIOXIDE...

375

E-Print Network 3.0 - ammonia-water-carbon dioxide mixtures Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: . The possibility of using carbonation process as a direct means for carbon dioxide sequestration is yet... . Carbon dioxide gas is the principal greenhouse...

376

E-Print Network 3.0 - air carbon dioxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: . The possibility of using carbonation process as a direct means for carbon dioxide sequestration is yet... . Carbon dioxide gas is the principal greenhouse...

377

ORNL/CDIAC-34 Carbon Dioxide Information Analysis Center and  

E-Print Network [OSTI]

Research U.S. Department of Energy Budget Activity Number KP 12 04 01 0 Prepared by the Carbon Dioxide. Burtis Carbon Dioxide Information Analysis Center Environmental Sciences Division Publication No. 4777's (DOE) Environmental Sciences Division, Office of Biological and Environmental Research (OBER

378

World Energy Consumption and Carbon Dioxide Emissions: 1950 2050  

E-Print Network [OSTI]

-U" relation with a within- sample peak between carbon dioxide emissions (and energy use) per capita and perWorld Energy Consumption and Carbon Dioxide Emissions: 1950 2050 Richard Schmalensee, Thomas M capita income. Using the income and population growth assumptions of the Intergovernmental Panel

379

Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine  

E-Print Network [OSTI]

i Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine Topical Report Prepared Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine Ross Edward Dugas, M capture using monoethanolamine (MEA). MEA is an appropriate choice for a baseline study since

Rochelle, Gary T.

380

Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study  

E-Print Network [OSTI]

1 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha Kothandaraman Students #12;2 #12;3 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha with electricity generation accounting for 40% of the total1 . Carbon capture and sequestration (CCS) is one

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Carbon Dioxide Capture DOI: 10.1002/anie.200902836  

E-Print Network [OSTI]

Carbon Dioxide Capture DOI: 10.1002/anie.200902836 Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks** Hye-Sun Choi and Myunghyun Paik Suh* Carbon dioxide capture has been warming, and the development of efficient methods for capturing CO2 from industrial flue gas has become

Paik Suh, Myunghyun

382

Carbon Dioxide, Global Warming, and Michael Crichton's "State of Fear"  

E-Print Network [OSTI]

Carbon Dioxide, Global Warming, and Michael Crichton's "State of Fear" Bert W. Rust Mathematical- tioned the connection between global warming and increasing atmospheric carbon dioxide by pointing out of these plots to global warming have spilled over to the real world, inviting both praise [4, 17] and scorn [15

Rust, Bert W.

383

Exhaust Gas Sensor Based On Tin Dioxide For Automotive Application  

E-Print Network [OSTI]

Exhaust Gas Sensor Based On Tin Dioxide For Automotive Application Arthur VALLERON a,b , Christophe, Engineering Materials Department The aim of this paper is to investigate the potentialities of gas sensor based on semi-conductor for exhaust gas automotive application. The sensing element is a tin dioxide

Paris-Sud XI, Université de

384

Carbon dioxide sequestration in concrete in different curing environments  

E-Print Network [OSTI]

Carbon dioxide sequestration in concrete in different curing environments Y.-m. Chun, T.R. Naik, USA ABSTRACT: This paper summarizes the results of an investigation on carbon dioxide (CO2) sequestration in concrete. Concrete mixtures were not air entrained. Concrete mixtures were made containing

Wisconsin-Milwaukee, University of

385

Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine  

E-Print Network [OSTI]

Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine Sanjay Bishnoi and Gary T dioxide absorption in 0.6 M piperazine PZ r4 M methyldiethanolamine ( )MDEA was measured in a wetted wall loading. The absorption rate did not follow pseudo first-order beha®ior except at ®ery low loading. All

Rochelle, Gary T.

386

Development of a Carbon Dioxide Monitoring Rotorcraft Unmanned Aerial Vehicle  

E-Print Network [OSTI]

stage to prevent potential danger to workforce and material, and carbon capture and sequestration (CCSDevelopment of a Carbon Dioxide Monitoring Rotorcraft Unmanned Aerial Vehicle Florian Poppa and Uwe the development of a carbon dioxide (CO2) sensing rotorcraft unmanned aerial vehicle (RUAV) and the experiences

Zimmer, Uwe

387

Carbon dioxide emission during forest fires ignited by lightning  

E-Print Network [OSTI]

In this paper we developed the model for the carbon dioxide emission from forest fire. The master equation for the spreading of the carbon dioxide to atmosphere is the hyperbolic diffusion equation. In the paper we study forest fire ignited by lightning. In that case the fores fire has the well defined front which propagates with finite velocity.

Magdalena Pelc; Radoslaw Osuch

2009-03-31T23:59:59.000Z

388

Carbon dioxide adsorption and methanation on ruthenium  

SciTech Connect (OSTI)

The adsorption and methanation of carbon dioxide on a ruthenium-silica catalyst were studied using temperature-programmed desorption (TPD) and temperature-programmed reaction (TPR). Carbon dioxide adsorption was found to be activated; CO/sub 2/ adsorption increased significantly as the temperature increased from 298 to 435 K. During adsorption, some of the CO/sub 2/ dissociated to carbon monoxide and oxygen; upon hydrogen exposure at room temperature, the oxygen reacted to water. Methanation of adsorbed CO and of adsorbed CO/sub 2/, using TPR in flowing hydrogen, yielded a CH/sub 4/ peak with a peak temperature of 459 K for both adsorbates, indicating that both reactions follow the same mechanism after adsorption. This peak temperature did not change with initial surface coverage of CO, indicating that methanation is first order in CO coverage. The desorption and reaction spectra for Ru/SiO/sub 2/ were similar to those previously obtained for Ni/SiO/sub 2/, but both CO/sub 2/ formation and CH/sub 4/ formation proceeded faster on Ru. Also, the details of CO desorption and the changes in CO/sub 2/ and CO desorptions with initial coverage were different on the two metals. 5 figures, 3 tables.

Zagli, E.; Falconer, J.L.

1981-05-01T23:59:59.000Z

389

Production of Diesel Engine Turbocharger Turbine from Low Cost Titanium Powder  

SciTech Connect (OSTI)

Turbochargers in commercial turbo-diesel engines are multi-material systems where usually the compressor rotor is made of aluminum or titanium based material and the turbine rotor is made of either a nickel based superalloy or titanium, designed to operate under the harsh exhaust gas conditions. The use of cast titanium in the turbine section has been used by Cummins Turbo Technologies since 1997. Having the benefit of a lower mass than the superalloy based turbines; higher turbine speeds in a more compact design can be achieved with titanium. In an effort to improve the cost model, and develop an industrial supply of titanium componentry that is more stable than the traditional aerospace based supply chain, the Contractor has developed component manufacturing schemes that use economical Armstrong titanium and titanium alloy powders and MgR-HDH powders. Those manufacturing schemes can be applied to compressor and turbine rotor components for diesel engine applications with the potential of providing a reliable supply of titanium componentry with a cost and performance advantage over cast titanium.

Muth, T. R.; Mayer, R. (Queen City Forging)

2012-05-04T23:59:59.000Z

390

Method of producing titanium-modified austenitic steel having improved swelling resistance  

DOE Patents [OSTI]

A process for improving the swelling resistance of a titanium-modified austenitic stainless steel that involves a combination of rapid solidification and dynamic compaction techniques.

Megusar, Janez (Belmont, MA); Grant, Nicholas J. (Winchester, MA)

1989-01-01T23:59:59.000Z

391

E-Print Network 3.0 - anodized nanotubular titanium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxide Electrolysis Naomi A. Fried and Donald R. Sadoway Department... in presence of O dioxins? furans? 12;Sadoway, MIT TMS Meeting, Charlotte, NC March 15, 2004 Titanium......

392

E-Print Network 3.0 - anodically oxidized titanium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxide Electrolysis Naomi A. Fried and Donald R. Sadoway Department... in presence of O dioxins? furans? 12;Sadoway, MIT TMS Meeting, Charlotte, NC March 15, 2004 Titanium......

393

E-Print Network 3.0 - anodic oxidized titanium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxide Electrolysis Naomi A. Fried and Donald R. Sadoway Department... in presence of O dioxins? furans? 12;Sadoway, MIT TMS Meeting, Charlotte, NC March 15, 2004 Titanium......

394

E-Print Network 3.0 - advanced titanium processing Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

< 1 2 3 4 5 > >> 1 Titanium Performance and Potential: an NPB Experimental Study Summary: exploration of advanced algorithms, and restricts the set of available programmers. The...

395

Excess Titanium from NNSA's Y-12 Plant to be Used by the Army...  

National Nuclear Security Administration (NNSA)

Excess Titanium from NNSA's Y-12 Plant to be Used by the Army for New Generation of Protective Body Armor for Combat Troops | National Nuclear Security Administration Facebook...

396

Carbon dioxide absorbent and method of using the same  

DOE Patents [OSTI]

In accordance with one aspect, the present invention provides an amino-siloxane composition comprising at least one of structures I, II, III, IV or V said compositions being useful for the capture of carbon dioxide from gas streams such as power plant flue gases. In addition, the present invention provides methods of preparing the amino-siloxane compositions are provided. Also provided are methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention as species which react with carbon dioxide to form an adduct with carbon dioxide. The reaction of the amino-siloxane compositions provided by the present invention with carbon dioxide is reversible and thus, the method provides for multicycle use of said compositions.

Perry, Robert James (Niskayuna, NY); Lewis, Larry Neil (Scotia, NY); O'Brien, Michael Joseph (Clifton Park, NY); Soloveichik, Grigorii Lev (Latham, NY); Kniajanski, Sergei (Clifton Park, NY); Lam, Tunchiao Hubert (Clifton Park, NY); Lee, Julia Lam (Niskayuna, NY); Rubinsztajn, Malgorzata Iwona (Ballston Spa, NY)

2011-10-04T23:59:59.000Z

397

Geothermal carbon dioxide for use in greenhouses  

SciTech Connect (OSTI)

Geothermal fluids often contain carbon dioxide, which is a very effective growth stimulant for plants in greenhouses. Studies have shown that as CO{sub 2} concentration is increased from a normal level of 300 ppm (mmol/kmol) to levels of approximately 1000 ppm crop yields may increase by up to 15% (Ullmann`s Encyclopedia of Industrial Chemistry, 1989). It is suggested that geothermal greenhouse heating offers a further opportunity for utilization of the carbon dioxide present in the fluid. The main difficulty is that plants react adversely to hydrogen sulphide which is invariably mixed, at some concentration, with the CO{sub 2} from geothermal fluids. Even very low H{sub 2}S concentrations of 0.03 mg/kg can have negative effects on the growth of plants (National Research Council, 1979). Therefore, an appropriate purification process for the CO{sub 2} must be used to avoid elevated H{sub 2}S levels in the greenhouses. The use of adsorption and absorption processes is proposed. Two purification processes have been modelled using the ASOEN PLUS software package, using the Geothermal Greenhouses Ltd. Operation Kawerau New Zealand and an example. A greenhouse area of 8,000 m{sup 2}, which would create a demand for approximately 20 kg CO{sub 2} per hour, was chosen based on a proposed expansion at Kawerau. The Kawerau operation currently takes geothermal steam (and gas) from a high temperature 2-phase well to heat an area of 1650 m{sup 2}. Bottled carbon dioxide is utilized at a rate of about 50 kg per day, to provide CO{sub 2} levels of 800 mg/kg when the greenhouse is closed and 300 to 350 mg/kg whilst venting. In England and the Netherlands, CO{sub 2} levels of 1000 mg/kg are often used (Ullmann`s Encyclopedia of Industrial Chemistry, 1989) and similar concentrations are desired at Kawerau, but current costs of 0.60 NZ$/kg for bottled CO{sub 2} are too high (Foster, 1995).

Dunstall, M.G. [Univ. of Auckland (New Zealand); Graeber, G. [Univ. of Stuttgart (Germany)

1997-01-01T23:59:59.000Z

398

The effects of laser trimming on the tensile strength and fatigue resistance properties of titanium - 6Al-4V  

E-Print Network [OSTI]

The effect of laser trimming on the tensile strength and fatigue resistance of titanium-6% aluminum-4% vanadium specimens was investigated. Due to the nature of laser processing, the microstructure of the titanium alloy was altered in an area local...

Whitesel, Dean Adam

1994-01-01T23:59:59.000Z

399

Titanium oxidation state and coordination in the lunar high-titanium glass source mantle  

SciTech Connect (OSTI)

XANES and EXAFS spectra from synthetic HiTi lunar glasses determine coordination of Ti in the HiTi source region. The amount of Ti{sup 3+} present affects the olivine-opx equilibrium, and the total amount of Ti{sup 3+} present requires a pyx bearing source. Lunar high-titanium (HiTi) ultramafic glasses provide us with evidence of the mantle processes that led to the melting of the lunar magma ocean cumulates nearly one billion years after the magma ocean solidified. Constraints on the depth, temperature and melting processes that formed the HiTi glasses are crucial for understanding the melting history of LMO products. The Apollo 17 orange glass (A17O) and Apollo 15 red glass (A15R) represent two of the HiTi compositions in the spectrum of pristine ultramafic glasses returned from the moon. The difference between these two compositions is that the A15R contains {approx}40% more TiO{sub 2} than the A17O. The low f{sub O2} of the ultramafic glass source regions allows for a certain amount of Ti{sup 3+} in the source mineralogy; however the amount of Ti{sup 3+} in the source and the host mineral for this element remain relatively unconstrained. In addition to the unknown mineralogy of the source region, the high amount of TiO*{sub 2} and FeO* in the HiTi magmas makes the phase relations extremely sensitive to changes in the oxidation state of the source region. We have previously investigated the oxidation state effect on the olivine-orthopyroxene multiple saturations points of the A15R and A17O and shown that the magnitude of the effect is proportional to the amount of Ti in the system. X-ray absorption near-edge spectroscopy (XANES) and extended X-ray absorption fine-structure (EXAFS) measurements have been made on minerals and glasses in experiments on synthetic analogues to the A17O and A15R. Our results show that Ti{sup 3+} concentration does indeed affect the multiple saturation points, and is an important constituent in the lunar interior.

Krawczynski, M.J.; Sutton, S.R.; Grove, T.L.; Newville, M. (MIT); (UofC)

2009-03-20T23:59:59.000Z

400

Nitrogen dioxide and respiratory illness in children. Part II: Assessment of exposure to nitrogen dioxide  

SciTech Connect (OSTI)

Repeated measurements of nitrogen dioxide were obtained from 1988 to 1991 in the homes of 1,205 infants living in Albuquerque, NM. Passive diffusion samplers were used to obtain a series of two-week integrated measurements from the home of each infant for use in a cohort study of the relation of residential exposure to nitrogen dioxide and respiratory illnesses. Information on stove use and time spent inside the residence was collected at two-week and two-month intervals, respectively. During the winter, in the bedrooms of homes with gas cooking stoves, mean nitrogen dioxide concentrations were 21 parts per billion (ppb); mean concentrations in the living room and kitchen were 29 ppb and 34 ppb, respectively. In homes with electric cooking stoves, the mean bedroom concentration was 7 ppb during the winter. Lower indoor concentrations were observed during the summer in homes with both gas and electric stoves. On average, infants spent approximately 12.3 hours per day in their bedrooms, 7.3 hours in the living rooms, 35 minutes in the kitchens, and 3.8 hours out of their homes. (As a condition of participation, none of the infants spent more than 20 hours per week in day care outside of their homes). The mean time infants spent in the kitchen during cooking was approximately nine minutes per day. We tested whether exposures of infants living in homes with gas stoves could be reasonably estimated by measurements in the bedroom in comparison with time-weighted average concentrations based on time-activity data and simultaneous nitrogen dioxide measurements in the kitchen, living room, and bedroom. In 1,937 two-week intervals from 587 infants, 90% of time-weighted exposure (on the three-level classification used in this study) estimates were in agreement with estimates based on bedroom concentrations alone.

Lambert, W.E.; Samet, J.M.; Hunt, W.C.; Skipper, B.J.; Schwab, M.; Spengler, J.D. (Univ. of New Mexico Medical Center, Albuquerque (United States))

1993-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Molten uranium dioxide structure and dynamics  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Uranium dioxide (UO2) is the major nuclear fuel component of fission power reactors. A key concern during severe accidents is the melting and leakage of radioactive UO2 as it corrodes through its zirconium cladding and steel containment. Yet, the very high temperatures (>3140 kelvin) and chemical reactivity of molten UO2 have prevented structural studies. In this work, we combine laser heating, sample levitation, and synchrotron x-rays to obtain pair distribution function measurements of hot solid and molten UO2. The hot solid shows a substantial increase in oxygen disorder around the lambda transition (2670 K) but negligible U-O coordination change. On melting, the average U-O coordination drops from 8 to 6.7 0.5. Molecular dynamics models refined to this structure predict higher U-U mobility than 8-coordinated melts.

Skinner, L. B. [Argonne National Laboratory (ANL), Argonne, IL (United States); Stony Brook Univ., Stony Brook, NY (United States); Materials Development Inc., Arlington Heights, IL (United States); Parise, J. B. [Stony Brook Univ., Stony Brook, NY (United States); Benmore, C. J. [Argonne National Laboratory (ANL), Argonne, IL (United States); Weber, J. K.R. [Materials Development Inc., Arlington Heights, IL (United States); Williamson, M. A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Tamalonis, A. [Materials Development Inc., Arlington Heights, IL (United States); Hebden, A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Wiencek, T. [Argonne National Laboratory (ANL), Argonne, IL (United States); Alderman, O. L.G. [Materials Development Inc., Arlington Heights, IL (United States); Guthrie, M. [Carnegie Inst., Washington, DC (United States); Leibowitz, L. [Argonne National Laboratory (ANL), Argonne, IL (United States)

2014-11-20T23:59:59.000Z

402

Carbon Dioxide Sequestration in Geologic Coal Formations  

SciTech Connect (OSTI)

BP Corporation North America, Inc. (BP) currently operates a nitrogen enhanced recovery project for coal bed methane at the Tiffany Field in the San Juan Basin, Colorado. The project is the largest and most significant of its kind wherein gas is injected into a coal seam to recover methane by competitive adsorption and stripping. The Idaho National Engineering and Environmental Laboratory (INEEL) and BP both recognize that this process also holds significant promise for the sequestration of carbon dioxide, a greenhouse gas, while economically enhancing the recovery of methane from coal. BP proposes to conduct a CO2 injection pilot at the tiffany Field to assess CO2 sequestration potential in coal. For its part the INEEL will analyze information from this pilot with the intent to define the Co2 sequestration capacity of coal and its ultimate role in ameliorating the adverse effects of global warming on the nation and the world.

None

2001-09-30T23:59:59.000Z

403

Layered solid sorbents for carbon dioxide capture  

SciTech Connect (OSTI)

A solid sorbent for the capture and the transport of carbon dioxide gas is provided having at least one first layer of a positively charged material that is polyethylenimine or poly(allylamine hydrochloride), that captures at least a portion of the gas, and at least one second layer of a negatively charged material that is polystyrenesulfonate or poly(acryclic acid), that transports the gas, wherein the second layer of material is in juxtaposition to, attached to, or crosslinked with the first layer for forming at least one bilayer, and a solid substrate support having a porous surface, wherein one or more of the bilayers is/are deposited on the surface of and/or within the solid substrate. A method of preparing and using the solid sorbent is provided.

Li, Bingyun; Jiang, Bingbing; Gray, McMahan L; Fauth, Daniel J; Pennline, Henry W; Richards, George A

2014-11-18T23:59:59.000Z

404

The lifetime of excess atmospheric carbon dioxide  

SciTech Connect (OSTI)

Since the beginning of the industrial revolution human activity has significantly altered biogeochemical cycling on a global scale. The uncertainties of future climate change rests partly on issues of physical-climate system dynamics and their representation in general circulation models. However understanding the carbon cycle is a key to comprehending the changing terrestrial biosphere and to developing a reasonable range of future concentrations of greenhouse gases. The authors look at correction of model uncertainties in the examination of the lifetime of carbon dioxide. The two difficulties analysed are as follows: (1) most model-derived estimates of the relaxation of the concentration of CO2 reveal a function which is not always well approximated by weighted sums of exponentials; (2) the function c(t) is quite sensitive to assumptions about the terrestrial biosphere and the relaxation experiment. 51 refs., 15 figs., 7 tabs.

Moore, B. III; Braswell, B.H. (Univ. of New Hampshire, Durham, NH (United States))

1994-03-01T23:59:59.000Z

405

Measurements of Modulus of Elasticity and Thermal Contraction of Epoxy Impregnated Niobium-Tin and Niobium-Titanium Composites  

E-Print Network [OSTI]

of Epoxy Impregnated Niobium-Tin and Niobium-Titaniumwith epoxy impregnated niobium tin and niobium titanium

Chow, K.P.

2011-01-01T23:59:59.000Z

406

Coiled tubing drilling with supercritical carbon dioxide  

DOE Patents [OSTI]

A method for increasing the efficiency of drilling operations by using a drilling fluid material that exists as supercritical fluid or a dense gas at temperature and pressure conditions existing at a drill site. The material can be used to reduce mechanical drilling forces, to remove cuttings, or to jet erode a substrate. In one embodiment, carbon dioxide (CO.sub.2) is used as the material for drilling within wells in the earth, where the normal temperature and pressure conditions cause CO.sub.2 to exist as a supercritical fluid. Supercritical carbon dioxide (SC--CO.sub.2) is preferably used with coiled tube (CT) drilling equipment. The very low viscosity SC--CO.sub.2 provides efficient cooling of the drill head, and efficient cuttings removal. Further, the diffusivity of SC--CO.sub.2 within the pores of petroleum formations is significantly higher than that of water, making jet erosion using SC--CO.sub.2 much more effective than water jet erosion. SC--CO.sub.2 jets can be used to assist mechanical drilling, for erosion drilling, or for scale removal. A choke manifold at the well head or mud cap drilling equipment can be used to control the pressure within the borehole, to ensure that the temperature and pressure conditions necessary for CO.sub.2 to exist as either a supercritical fluid or a dense gas occur at the drill site. Spent CO.sub.2 can be vented to the atmosphere, collected for reuse, or directed into the formation to aid in the recovery of petroleum.

Kolle , Jack J. (Seattle, WA)

2002-01-01T23:59:59.000Z

407

TITANIUM AND VANADIUM CHEMISTRY IN LOW-MASS DWARF STARS Katharina Lodders  

E-Print Network [OSTI]

. The most profound effect of a decrease in temperature is that carbon monoxide (CO) con- verts to methaneTITANIUM AND VANADIUM CHEMISTRY IN LOW-MASS DWARF STARS Katharina Lodders Planetary Chemistry The equilibrium gas and condensation chemistry of titanium and vanadium in M, L, and T dwarf atmos- pheres

Fegley Jr., Bruce

408

WICKING OPTIMIZATION FOR THERMAL COOLING -WITH A TITANIUM BASED HEAT PIPE SYSTEM  

E-Print Network [OSTI]

WICKING OPTIMIZATION FOR THERMAL COOLING -WITH A TITANIUM BASED HEAT PIPE SYSTEM C. Ding1* , P for a proposed flat heat pipe system. This unique bitextured titania structure (BTS) provides a suprerhydrophilic based flat heat pipe is proposed to integrate the BTS wicks and study the concept of this titanium based

MacDonald, Noel C.

409

Structural changes induced by heavy ion irradiation in titanium silicon carbide J.C. Nappa,  

E-Print Network [OSTI]

Structural changes induced by heavy ion irradiation in titanium silicon carbide Authors J.C. Nappéa, UMR 8609, Bât. 108, 91405 Orsay, France ABSTRACT Carbide-type ceramics, which have remarkable at high temperature. The MAX phases, and more particularly titanium silicon carbide, are distinguished

Paris-Sud XI, Université de

410

Magnesium and titanium: "The odd couple" Local order and the influence of stress on the  

E-Print Network [OSTI]

Magnesium and titanium: "The odd couple" Local order and the influence of stress on the hydrogen (Sweden) Cover: The graph on the cover is a collection of loading isotherms measured on magnesium thin UNIVERSITEIT Magnesium and titanium: "The odd couple" Local order and the influence of stress on the hydrogen

Dam, Bernard

411

Product: Tetrakis(dimethylamino)titanium(IV) P-6331 Date: February 2005 Copyright 2005, Praxair Technology, Inc. Page 1 of 8  

E-Print Network [OSTI]

Product: Tetrakis(dimethylamino)titanium(IV) P-6331 Date: February 2005 Copyright © 2005, Praxair Technology, Inc. Page 1 of 8 All rights reserved. Praxair Material Safety Data Sheet 1. Chemical Product-(dimethylamino)titanium(IV)] (MSDS No. P-6331) Trade Name: Praxair® TDMAT Chemical Name: Tetrakis(dimethylamino)titanium(IV) Synonyms

Rubloff, Gary W.

412

Estimated Carbon Dioxide Emissions in 2008: United States  

SciTech Connect (OSTI)

Flow charts depicting carbon dioxide emissions in the United States have been constructed from publicly available data and estimates of state-level energy use patterns. Approximately 5,800 million metric tons of carbon dioxide were emitted throughout the United States for use in power production, residential, commercial, industrial, and transportation applications in 2008. Carbon dioxide is emitted from the use of three major energy resources: natural gas, coal, and petroleum. The flow patterns are represented in a compact 'visual atlas' of 52 state-level (all 50 states, the District of Columbia, and one national) carbon dioxide flow charts representing a comprehensive systems view of national CO{sub 2} emissions. Lawrence Livermore National Lab (LLNL) has published flow charts (also referred to as 'Sankey Diagrams') of important national commodities since the early 1970s. The most widely recognized of these charts is the U.S. energy flow chart (http://flowcharts.llnl.gov). LLNL has also published charts depicting carbon (or carbon dioxide potential) flow and water flow at the national level as well as energy, carbon, and water flows at the international, state, municipal, and organizational (i.e. United States Air Force) level. Flow charts are valuable as single-page references that contain quantitative data about resource, commodity, and byproduct flows in a graphical form that also convey structural information about the system that manages those flows. Data on carbon dioxide emissions from the energy sector are reported on a national level. Because carbon dioxide emissions are not reported for individual states, the carbon dioxide emissions are estimated using published energy use information. Data on energy use is compiled by the U.S. Department of Energy's Energy Information Administration (U.S. EIA) in the State Energy Data System (SEDS). SEDS is updated annually and reports data from 2 years prior to the year of the update. SEDS contains data on primary resource consumption, electricity generation, and energy consumption within each economic sector. Flow charts of state-level energy usage and explanations of the calculations and assumptions utilized can be found at: http://flowcharts.llnl.gov. This information is translated into carbon dioxide emissions using ratios of carbon dioxide emissions to energy use calculated from national carbon dioxide emissions and national energy use quantities for each particular sector. These statistics are reported annually in the U.S. EIA's Annual Energy Review. Data for 2008 (US. EIA, 2010) was updated in August of 2010. This is the first presentation of a comprehensive state-level package of flow charts depicting carbon dioxide emissions for the United States.

Smith, C A; Simon, A J; Belles, R D

2011-04-01T23:59:59.000Z

413

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue  

E-Print Network [OSTI]

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

Dennis, J A

1971-01-01T23:59:59.000Z

414

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy  

E-Print Network [OSTI]

, and carbon dioxide. Introduction Carbon dioxide emissions resulting from the burning of fossil fuels 20 metric tons of carbon dioxide per capita are released annually into the atmosphere.1a,b CarbonStorage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks

Yaghi, Omar M.

415

Method of producing tungsten-titanium sputter targets and targets produced thereby  

SciTech Connect (OSTI)

A method is described for preparing a tungsten-titanium sputter target having substantially no [beta](Ti,W) phase present and exhibiting improvement in reduction of particulate emission upon sputtering, comprising: (a) providing powders of said tungsten and titanium wherein said titanium powder is present in an amount of about 1-20 wt. % based on the total weight of said tungsten and titanium powders provided; (b) compacting said powders at a pressure of from about 200 to 1,000 MPa; and (c) heating said powders at a temperature from about 600-882 C. A method for preparing a tungsten-titanium sputtering target having substantially no [beta](Ti,W) phase present and exhibiting improvement in reduction of particulate emission upon sputtering.

Wickersham, C.E. Jr.; Mueller, J.J.

1993-08-10T23:59:59.000Z

416

Titanium diboride ceramic fiber composites for Hall-Heroult cells  

DOE Patents [OSTI]

An improved cathode structure for Hall-Heroult cells for the electrolytic production of aluminum metal. This cathode structure is a preform fiber base material that is infiltrated with electrically conductive titanium diboride using chemical vapor infiltration techniques. The structure exhibits good fracture toughness, and is sufficiently resistant to attack by molten aluminum. Typically, the base can be made from a mat of high purity silicon carbide fibers. Other ceramic or carbon fibers that do not degrade at temperatures below about 1000 deg. C can be used.

Besmann, Theodore M. (Knoxville, TN); Lowden, Richard A. (Knoxville, TN)

1990-01-01T23:59:59.000Z

417

Titanium diboride ceramic fiber composites for Hall-Heroult cells  

DOE Patents [OSTI]

An improved cathode structure is described for Hall-Heroult cells for the electrolytic production of aluminum metal. This cathode structure is a preform fiber base material that is infiltrated with electrically conductive titanium diboride using chemical vapor infiltration techniques. The structure exhibits good fracture toughness, and is sufficiently resistant to attack by molten aluminum. Typically, the base can be made from a mat of high purity silicon carbide fibers. Other ceramic or carbon fibers that do not degrade at temperatures below about 1000 C can be used.

Besmann, T.M.; Lowden, R.A.

1990-05-29T23:59:59.000Z

418

Producing titanium aluminide foil from plasma-sprayed preforms  

SciTech Connect (OSTI)

A new method was used to fabricate foils of Ti-6Al-4V (Ti-6-4) alloy and Ti-14Al-21Nb(Ti-14-21) titanium aluminide, starting from a plasma-sprayed (PS) preform. The foils were 100 percent dense, with microstructures similar to those of wrought (IM) foil material. The foil made from PS preforms were characterized by the mechanical properties equivalent to their IM-processed counterparts. It is concluded that the method of roll consolidation of a PS preform is well suited for alloys and intermetallics that do not possess extensive hot and cold workability. 6 refs.

Jha, S.C.; Forster, J.A. (Texas Instruments, Inc., Attleboro, MA (United States))

1993-07-01T23:59:59.000Z

419

Sandia National Laboratories: Titanium-di-oxide nanoparticles  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmitted for USMaterials ProgramProtected: TechTitanium-di-oxide

420

Slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures  

DOE Patents [OSTI]

A slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures includes the steps of dissolving the gas mixture and carbon dioxide in water providing a gas, carbon dioxide, water mixture; adding a porous solid media to the gas, carbon dioxide, water mixture forming a slurry of gas, carbon dioxide, water, and porous solid media; heating the slurry of gas, carbon dioxide, water, and porous solid media producing steam; and cooling the steam to produce purified water and carbon dioxide.

Aines, Roger D.; Bourcier, William L.; Viani, Brian

2013-01-29T23:59:59.000Z

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Formation of rare earth carbonates using supercritical carbon dioxide  

DOE Patents [OSTI]

The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

Fernando, Quintus (Tucson, AZ); Yanagihara, Naohisa (Zacopan, MX); Dyke, James T. (Santa Fe, NM); Vemulapalli, Krishna (Tuscon, AZ)

1991-09-03T23:59:59.000Z

422

Haverford Researchers Create Carbon Dioxide-Separating Polymer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PG-ES1, that uses a combination of surface adsorption and narrow pores to separate carbon dioxide from nitrogen, oxygen, and methane gases. Image by Joshua Schrier, Haverford...

423

Electrochemically-mediated amine regeneration for carbon dioxide separations  

E-Print Network [OSTI]

This thesis describes a new strategy for carbon dioxide (CO?) separations based on amine sorbents, which are electrochemically-mediated to facilitate the desorption and regeneration steps of the separation cycle. The ...

Stern, Michael C. (Michael Craig)

2014-01-01T23:59:59.000Z

424

www.sciam.com SCIENTIFIC AMERICAN 49 Pumping carbon dioxide  

E-Print Network [OSTI]

www.sciam.com SCIENTIFIC AMERICAN 49 CREDIT CanWe Bury GLOBAL WARMING? Pumping carbon dioxide is then pumped two kilometers below ground. COPYRIGHT 2005 SCIENTIFIC AMERICAN, INC. #12;adapt

O'Donnell, Tom

425

Separation of carbon dioxide from flue emissions using Endex principles  

E-Print Network [OSTI]

In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

Ball, R

2009-01-01T23:59:59.000Z

426

World energy consumption and carbon dioxide emissions : 1950-2050  

E-Print Network [OSTI]

Emissions of carbon dioxide form combustion of fossil fuels, which may contribute to long-term climate change, are projected through 2050 using reduced form models estimated with national-level panel data for the period ...

Schmalensee, Richard

1995-01-01T23:59:59.000Z

427

World energy consumption and carbon dioxide emissions : 1950-2050  

E-Print Network [OSTI]

Emissions of carbon dioxide from combustion of fossil fuels, which may contribute to long-term climate change, are projected through 2050 using reduced form models estimated with national-level panel data for the period ...

Schmalensee, Richard.; Stoker, Thomas M.; Judson, Ruth A.

428

Optical properties of nanostructured silicon-rich silicon dioxide  

E-Print Network [OSTI]

We have conducted a study of the optical properties of sputtered silicon-rich silicon dioxide (SRO) thin films with specific application for the fabrication of erbium-doped waveguide amplifiers and lasers, polarization ...

Stolfi, Michael Anthony

2006-01-01T23:59:59.000Z

429

Control strategies for supercritical carbon dioxide power conversion systems  

E-Print Network [OSTI]

The supercritical carbon dioxide (S-C02) recompression cycle is a promising advanced power conversion cycle which couples well to numerous advanced nuclear reactor designs. This thesis investigates the dynamic simulation ...

Carstens, Nathan, 1978-

2007-01-01T23:59:59.000Z

430

Mechanisms for mechanical trapping of geologically sequestered carbon dioxide  

E-Print Network [OSTI]

Carbon dioxide (CO[subscript 2]) sequestration in subsurface reservoirs is important for limiting atmospheric CO[subscript 2] concentrations. However, a complete physical picture able to predict the structure developing ...

Cohen, Yossi

431

Ownership of Carbon Dioxide Captured by Clean Coal Project (Texas)  

Broader source: Energy.gov [DOE]

This legislation stipulates that the Railroad Commission of Texas automatically acquires the title to any carbon dioxide captured by a clean coal project in the state. The Bureau of Economic...

432

Carbon dioxide dissolution in structural and stratigraphic traps  

E-Print Network [OSTI]

The geologic sequestration of carbon dioxide (CO[subscript 2]) in structural and stratigraphic traps is a viable option to reduce anthropogenic emissions. While dissolution of the CO[subscript 2] stored in these traps ...

Hesse, M. A.

433

Figure 3. Energy-Related Carbon Dioxide Emissions  

U.S. Energy Information Administration (EIA) Indexed Site

3. Energy-Related Carbon Dioxide Emissions" " (million metric tons)" ,2007,2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024,2025,2026,2027,2028,...

434

Tethered catalysts for the hydration of carbon dioxide  

DOE Patents [OSTI]

A system is provided that substantially increases the efficiency of CO.sub.2 capture and removal by positioning a catalyst within an optimal distance from the air-liquid interface. The catalyst is positioned within the layer determined to be the highest concentration of carbon dioxide. A hydrophobic tether is attached to the catalyst and the hydrophobic tether modulates the position of the catalyst within the liquid layer containing the highest concentration of carbon dioxide.

Valdez, Carlos A; Satcher, Jr., Joe H; Aines, Roger D; Wong, Sergio E; Baker, Sarah E; Lightstone, Felice C; Stolaroff, Joshuah K

2014-11-04T23:59:59.000Z

435

CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS  

SciTech Connect (OSTI)

This report describes research conducted between April 1, 2005 and June 30, 2005 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas from coal combustion and synthesis gas from coal gasification. Supported sodium carbonate sorbents removed up to 76% of the carbon dioxide from simulated flue gas in a downflow cocurrent flow reactor system, with an approximate 15 second gas-solid contact time. This reaction proceeds at temperatures as low as 25 C. Lithium silicate sorbents remove carbon dioxide from high temperature simulated flue gas and simulated synthesis gas. Both sorbent types can be thermally regenerated and reused. The lithium silicate sorbent was tested in a thermogravimetric analyzer and in a 1-in quartz reactor at atmospheric pressure; tests were also conducted at elevated pressure in a 2-in diameter high temperature high pressure reactor system. The lithium sorbent reacts rapidly with carbon dioxide in flue gas at 350-500 C to absorb about 10% of the sorbent weight, then continues to react at a lower rate. The sorbent can be essentially completely regenerated at temperatures above 600 C and reused. In atmospheric pressure tests with synthesis gas of 10% initial carbon dioxide content, the sorbent removed over 90% of the carbon dioxide. An economic analysis of a downflow absorption process for removal of carbon dioxide from flue gas with a supported sodium carbonate sorbent suggests that a 90% efficient carbon dioxide capture system installed at a 500 MW{sub e} generating plant would have an incremental capital cost of $35 million ($91/kWe, assuming 20 percent for contingencies) and an operating cost of $0.0046/kWh. Assuming capital costs of $1,000/kW for a 500 MWe plant the capital cost of the down flow absorption process represents a less than 10% increase, thus meeting DOE goals as set forth in its Carbon Sequestration Technology Roadmap and Program Plan.

David A. Green; Thomas Nelson; Brian S. Turk; Paul Box; Weijiong Li; Raghubir P. Gupta

2005-07-01T23:59:59.000Z

436

Neutral beam dump with cathodic arc titanium gettering  

SciTech Connect (OSTI)

An incomplete neutral beam capture can degrade the plasma performance in neutral beam driven plasma machines. The beam dumps mitigating the shine-through beam recycling must entrap and retain large particle loads while maintaining the beam-exposed surfaces clean of the residual impurities. The cathodic arc gettering, which provides high evaporation rate coupled with a fast time response, is a powerful and versatile technique for depositing clean getter films in vacuum. A compact neutral beam dump utilizing the titanium arc gettering was developed for a field-reversed configuration plasma sustained by 1 MW, 20-40 keV neutral hydrogen beams. The titanium evaporator features a new improved design. The beam dump is capable of handling large pulsed gas loads, has a high sorption capacity, and is robust and reliable. With the beam particle flux density of 5 x 10{sup 17} H/(cm{sup 2}s) sustained for 3-10 ms, the beam recycling coefficient, defined as twice the ratio of the hydrogen molecular flux leaving the beam dump to the incident flux of high-energy neutral atoms, is {approx}0.7. The use of the beam dump allows us to significantly reduce the recycling of the shine-through neutral beam as well as to improve the vacuum conditions in the machine.

Smirnov, A.; Korepanov, S. A.; Putvinski, S. [Tri Alpha Energy Inc., Rancho Santa Margarita, California 92688 (United States); Krivenko, A. S.; Murakhtin, S. V.; Savkin, V. Ya. [Budker Institute of Nuclear Physics, Novosibirsk 630090 (Russian Federation)

2011-03-15T23:59:59.000Z

437

Plasma arc melting of titanium-tantalum alloys  

SciTech Connect (OSTI)

Los Alamos has several applications for high temperature, oxidation and liquid-metal corrosion resistant materials. Further, materials property constraints are dictated by a requirement to maintain low density; e.g., less than the density of stainless steel. Liquid metal compatibility and density requirements have driven the research toward the Ti-Ta system with an upper bound of 60 wt% Ta-40 wt% Ti. Initial melting of these materials was performed in a small button arc melter with several hundred grams of material; however, ingot quantities were soon needed. But, refractory metal alloys whose constituents possess very dissimilar densities, melting temperatures and vapor pressures pose significant difficulty and require specialized melting practices. The Ti-Ta alloys fall into this category with the density of tantalum 16.5 g/cc and that of titanium 4.5 g/cc. Melting is further complicated by the high melting point of Ta(3020 C) and the relatively low boiling point of Ti(3287 C). Previous electron beam melting experience with these materials resulted, in extensive vaporization of the titanium and poor chemical homogeneity. Vacuum arc remelting(VAR) was considered as a melting candidate and discarded due to density and vapor pressure issues associated with electron beam. Plasma arc melting offered the ability to supply a cover gas to deal with vapor pressure issues as well as solidification control to help with macrosegregation in the melt and has successfully produced high quality ingots of the Ti-Ta alloys.

Dunn, P.; Patterson, R.A. [Los Alamos National Lab., NM (United States); Haun, R. [Retech, Inc., Ukiah, CA (United States)

1994-08-01T23:59:59.000Z

438

Nitrogen dioxide and respiratory illnesses in infants  

SciTech Connect (OSTI)

Nitrogen dioxide is an oxidant gas that contaminates outdoor air and indoor air in homes with unvented gas appliances. A prospective cohort study was carried out to test the hypothesis that residential exposure to NO2 increases incidence and severity of respiratory illnesses during the first 18 months of life. A cohort of 1,205 healthy infants from homes without smokers was enrolled. The daily occurrence of respiratory symptoms and illnesses was reported by the mothers every 2 wk. Illnesses with wheezing or wet cough were classified as lower respiratory tract. Indoor NO2 concentrations were serially measured with passive samplers place in the subjects' bedrooms. In stratified analyses, illness incidence rates did not consistently increase with exposure to NO2 or stove type. In multivariate analyses that adjusted for potential confounding factors, odds ratios were not significantly elevated for current or lagged NO2 exposures, or stove type. Illness duration, a measure of illness severity, was not associated with NO2 exposure. The findings can be extended to homes with gas stoves in regions of the United States where the outdoor air is not heavily polluted by NO2.

Samet, J.M.; Lambert, W.E.; Skipper, B.J.; Cushing, A.H.; Hunt, W.C.; Young, S.A.; McLaren, L.C.; Schwab, M.; Spengler, J.D. (Univ. of New Mexico Medical Center, Albuquerque (United States))

1993-11-01T23:59:59.000Z

439

Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model  

E-Print Network [OSTI]

do fossil fuel carbon dioxide emissions from California go?do fossil fuel carbon dioxide emissions from California go?1 distribution of carbon dioxide emissions from fossil fuel

2008-01-01T23:59:59.000Z

440

Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide  

SciTech Connect (OSTI)

This project involves the use of an innovative new invention ? Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude oilcontaining formations or saline aquifers. The term ?globule? refers to the water or liquid carbon dioxide droplets sheathed with ultrafine particles dispersed in the continuous external medium, liquid CO{sub 2} or H{sub 2}O, respectively. The key to obtaining very small globules is the shear force acting on the two intermixing fluids, and the use of ultrafine stabilizing particles or nanoparticles. We found that using Kenics-type static mixers with a shear rate in the range of 2700 to 9800 s{sup -1} and nanoparticles between 100-300 nm produced globule sizes in the 10 to 20 ?m range. Particle stabilized emulsions with that kind of globule size should easily penetrate oil-bearing formations or saline aquifers where the pore and throat size can be on the order of 50 ?m or larger. Subsequent research focused on creating particle stabilized emulsions that are deemed particularly suitable for Permanent Sequestration of Carbon Dioxide. Based on a survey of the literature an emulsion consisting of 70% by volume of water, 30% by volume of liquid or supercritical carbon dioxide, and 2% by weight of finely pulverized limestone (CaCO{sub 3}) was selected as the most promising agent for permanent sequestration of CO{sub 2}. In order to assure penetration of the emulsion into tight formations of sandstone or other silicate rocks and carbonate or dolomite rock, it is necessary to use an emulsion consisting of the smallest possible globule size. In previous reports we described a high shear static mixer that can create such small globules. In addition to the high shear mixer, it is also necessary that the emulsion stabilizing particles be in the submicron size, preferably in the range of 0.1 to 0.2 ?m (100 to 200 nm) size. We found a commercial source of such pulverized limestone particles, in addition we purchased under this DOE Project a particle grinding apparatus that can provide particles in the desired size range. Additional work focused on attempts to generate particle stabilized emulsions with a flow through, static mixer based apparatus under a variety

Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

2011-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Carbon-dioxide-controlled ventilation study  

SciTech Connect (OSTI)

The In-House Energy Management (IHEM) Program has been established by the U.S. Department of Energy to provide funds to federal laboratories to conduct research on energy-efficient technology. The Energy Sciences Department of Pacific Northwest Laboratory (PNL) was tasked by IHEM to research the energy savings potential associated with reducing outdoor-air ventilation of buildings. By monitoring carbon dioxide (CO{sub 2}) levels in a building, outdoor air provided by the heating, ventilating, and air-conditioning (HVAC) system can be reduced to the percentage required to maintain satisfactory CO{sub 2} levels rather than ventilating with a higher outdoor-air percentage based on an arbitrary minimum outdoor-air setting. During summer months, warm outdoor air brought into a building for ventilation must be cooled to meet the appropriate cooling supply-air temperature, and during winter months, cold outdoor air must be heated. By minimizing the amount of hot or cold outdoor air brought into the HVAC system, the supply air requires less cooling or heating, saving energy and money. Additionally, the CO{sub 2} levels in a building can be monitored to ensure that adequate outdoor air is supplied to a building to maintain air quality levels. The two main considerations prior to implementing CO{sub 2}-based ventilation control are its impact on energy consumption and the adequacy of indoor air quality (IAQ) and occupant comfort. To address these considerations, six portable CO{sub 2} monitors were placed in several Hanford Site buildings to estimate the adequacy of office/workspace ventilation. The monitors assessed the potential for reducing the flow of outdoor-air to the buildings. A candidate building was also identified to monitor various ventilation control strategies for use in developing a plan for implementing and assessing energy savings.

McMordie, K.L.; Carroll, D.M.

1994-05-01T23:59:59.000Z

442

Acetaldehyde Photochemistry on TiO2(110). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAre the Effects ofAboutTestAccounting -Research

443

Acetaldehyde photochemistry on TiO2(110). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAre the Effects ofAboutTestAccounting -Researchphotochemistry

444

Low Cost TiO2 Nanoparticles - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and InterfacesAdministration - Rocky MountainPrepared: 10/28/09 Low

445

Study of nitrogen-rich titanium and zirconium nitride films  

SciTech Connect (OSTI)

Thin titanium nitride (TiN) and zirconium nitride (ZrN) films containing excess nitrogen up to 59 and 63 at. % N, respectively, were deposited on austenitic stainless-steel substrates by reactive triode ion plating at about 823 K. The film structure and surface chemistry were studied using x-ray diffraction, scanning Auger spectroscopy, and electron energy-loss spectroscopy (EELS). In TiN films only the face-centered-cubic mononitride phase was detected. The lattice parameter of the stoichiometric TiN film was larger than the corresponding bulk value and it increased with increasing nitrogen content. The lattice parameter of overstoichiometric ZrN films showed abnormal behavior when calculated from different diffracting planes. This behavior together with the EELS and other measurements indicate that a dielectric Zr/sub 3/N/sub 4/ phase was formed at overstoichiometric compositions.

Ristolainen, E.O.; Molarius, J.M.; Korhonen, A.S.; Lindroos, V.K.

1987-07-01T23:59:59.000Z

446

FreedomCAR and Fuel Partnership 2005 Highlights of Technical...  

Broader source: Energy.gov (indexed) [DOE]

type used for titanium dioxide paint pigment production) as the precursor in ITP's Armstrong titanium synthesis process. The resulting titanium powders, while containing...

447

Application of chlorine dioxide as an oilfield facilities treatment fluid  

SciTech Connect (OSTI)

Both mechanical and chemical treatments are used to clean water flood injection distribution systems whose efficiency has been reduced as a result of plugging material such as iron sulfide sludge. Most mechanical treatments rely on uniform line diameter to be effective, while chemical treatments require good contact with the plugging material for efficient removal. This paper describes the design and operation of a new innovative application using chlorine dioxide for the removal of iron sulfide sludge from water flood injection distribution systems. This technology has evolved from the use of chlorine dioxide in well stimulation applications. The use of chlorine dioxide for continuous treatment of injection brines will also be discussed. Exxon USA`s Hartzog Draw facility in Gillette, Wyoming was the site for the application described. 4,500 barrels of chlorine dioxide was pumped in three phases to clean sixty-six miles of the water flood distribution system. Results indicate that chlorine dioxide was effective in cleaning the well guard screens, the injection lines, frac tanks used to collect the treatment fluids and the injection wells.

Romaine, J.; Strawser, T.G.; Knippers, M.L.

1995-11-01T23:59:59.000Z

448

Numerical simulation of oxidation and its effect on the crack growth resistance of titanium alloys  

E-Print Network [OSTI]

The use of titanium alloys Metal Matrix Composites (MMC) has become more extensive in the aerospace field, especially for elevated temperature applications such as leading edges on hypersonic aircraft and the jet engine turbine blades...

Triharjanto, Robertus Heru

1997-01-01T23:59:59.000Z

449

E-Print Network 3.0 - aged titanium tritides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

N... -WellP-Well P P NP Poly-Silicon N -N - P -P - TEOS Photo resist N+ N+ P+ P+ Titanium Silicide Attila ... Source: Lee, Seung-Wuk - Department of Bioengineering, University of...

450

Perchlorate reduction using electrochemically induced pitting corrosion of zero-valent titanium  

E-Print Network [OSTI]

effective technologies, especially chemical treatments, to completely destroy trace levels of perchlorate present in drinking and groundwater. The research on perchlorate reduction by zero-valent titanium (Ti(0)) showed that perchlorate was effectively...

Lee, Chun Woo

2009-05-15T23:59:59.000Z

451

Analysis of multicomponent evaporation in electron beam melting and refining of titanium alloys  

SciTech Connect (OSTI)

Experimental evidence and a mathematical model are presented to evaluate the effect of beam-scan frequency on composition change in electron-beam melting of titanium alloys. Experiments characterized the evaporation rate of commercially pure (CP) titanium and vapor composition over titanium alloy with up to 6 wt pct aluminum and 4.5 wt pct vanadium, as a function of beam power, scan frequency, and background pressure. These data and thermal mapping of the hearth melt surface are used to estimate activity coefficients of aluminum and vanadium in the hearth. The model describes transient heat transfer in the surface of the melt and provides a means of estimating enhancement of pure titanium evaporation and change in final aluminum composition due to local heating at moderate beam-scan frequencies.

Powell, A.; Szekely, J.; Pal, U. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Materials Science and Engineering; Avyle, J. van den; Damkroger, B. [Sandia National Labs., Albuquerque, NM (United States). Materials Processing Dept.

1997-12-01T23:59:59.000Z

452

Thermal infrared emission spectroscopy of titanium-enriched V. E. Hamilton  

E-Print Network [OSTI]

Thermal infrared emission spectroscopy of titanium-enriched pyroxenes V. E. Hamilton Hawai, Angra dos Reis, remote sensing Citation: Hamilton, V. E., Thermal infrared emission spectroscopy [Lyon, 1962], and emission [Hamilton, 1998, 2000] spectroscopic studies. These studies have documented

Hamilton, Victoria E.

453

Formation of a memristor matrix based on titanium oxide and investigation by probe-nanotechnology methods  

SciTech Connect (OSTI)

The results of investigation of a memristor-matrix model on the basis of titanium-oxide nanoscale structures (ONSs) fabricated by methods of focused ion beams and atomic-force microscopy (AFM) are presented. The effect of the intensity of interaction between the AFM probe and the sample surface on the memristor effect in the titanium ONS is shown. The memristor effect in the titanium ONS is investigated by an AFM in the mode of spreading-resistance map. The possibility of the recording and erasure of information in the submicron cells is shown on the basis of using the memristor effect in the titanium ONS, which is most promising for developing the technological processes of the formation of resistive operation memory cells.

Avilov, V. I.; Ageev, O. A.; Kolomiitsev, A. S.; Konoplev, B. G., E-mail: kbg@sfedu.ru; Smirnov, V. A.; Tsukanova, O. G. [Southern Federal University, Institute of Nanotechnologies, Electronics, and Electronic Equipment Engineering (Russian Federation)

2014-12-15T23:59:59.000Z

454

Near-Net Shape Fabrication Using Low-Cost Titanium Alloy Powders  

SciTech Connect (OSTI)

The use of titanium in commercial aircraft production has risen steadily over the last half century. The aerospace industry currently accounts for 58% of the domestic titanium market. The Kroll process, which has been used for over 50 years to produce titanium metal from its mineral form, consumes large quantities of energy. And, methods used to convert the titanium sponge output of the Kroll process into useful mill products also require significant energy resources. These traditional approaches result in product forms that are very expensive, have long lead times of up to a year or more, and require costly operations to fabricate finished parts. Given the increasing role of titanium in commercial aircraft, new titanium technologies are needed to create a more sustainable manufacturing strategy that consumes less energy, requires less material, and significantly reduces material and fabrication costs. A number of emerging processes are under development which could lead to a breakthrough in extraction technology. Several of these processes produce titanium alloy powder as a product. The availability of low-cost titanium powders may in turn enable a more efficient approach to the manufacture of titanium components using powder metallurgical processing. The objective of this project was to define energy-efficient strategies for manufacturing large-scale titanium structures using these low-cost powders as the starting material. Strategies include approaches to powder consolidation to achieve fully dense mill products, and joining technologies such as friction and laser welding to combine those mill products into near net shape (NNS) preforms for machining. The near net shape approach reduces material and machining requirements providing for improved affordability of titanium structures. Energy and cost modeling was used to define those approaches that offer the largest energy savings together with the economic benefits needed to drive implementation. Technical feasibility studies were performed to identify the most viable approaches to NNS preform fabrication using basic powder metallurgy mill product forms as the building blocks and advanced joining techniques including fusion and solid state joining to assemble these building blocks into efficient machining performs.

Dr. David M. Bowden; Dr. William H. Peter

2012-03-31T23:59:59.000Z

455

Spectral slicing filters in titanium diffused lithium niobate (ti:linbo3)  

E-Print Network [OSTI]

SPECTRAL SLICING FILTERS IN TITANIUM DIFFUSED LITHIUM NIOBATE (Ti:LiNbO 3 ) A Dissertation by RENATO CUNHA RABELO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of DOCTOR OF PHILOSOPHY December 2008 Major Subject: Electrical Engineering SPECTRAL SLICING FILTERS IN TITANIUM DIFFUSED LITHIUM NIOBATE (Ti:LiNbO 3 ) A Dissertation by RENATO CUNHA RABELO Submitted...

Rabelo, Renato Cunha

2009-05-15T23:59:59.000Z

456

Experimental: Sample Preparation TiO2 compact (TiO2comp) anatase films (0.1  

E-Print Network [OSTI]

) solar cells by an embossing technique to increase light harvesting and electron percolation.biancardo@risoe.dk Working principle of ETA solar cells: light irradiation (1) produce excitation (2) of the absorber (Abs 20 kgcm-2). Experimental: Device Testing Sun simulation was provided by a solar simulator KHS Solar

457

Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents  

SciTech Connect (OSTI)

This report describes research conducted between July 1, 2006 and September 30, 2006 on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. Modifications to the integrated absorber/ sorbent regenerator/ sorbent cooler system were made to improve sorbent flow consistency and measurement reliability. Operation of the screw conveyor regenerator to achieve a sorbent temperature of at least 120 C at the regenerator outlet is necessary for satisfactory carbon dioxide capture efficiencies in succeeding absorption cycles. Carbon dioxide capture economics in new power plants can be improved by incorporating increased capacity boilers, efficient flue gas desulfurization systems and provisions for withdrawal of sorbent regeneration steam in the design.

David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box Raghubir P. Gupta

2006-09-30T23:59:59.000Z

458

Alloy Design and Thermomechanical Processing of a Beta Titanium Alloy for a Heavy Vehicle Application  

SciTech Connect (OSTI)

With the strength of steel, but at half the weight, titanium has the potential to offer significant benefits in the weight reduction of heavy vehicle components while possibly improving performance. However, the cost of conventional titanium fabrication is a major barrier in implementation. New reduction technologies are now available that have the potential to create a paradigm shift in the way the United States uses titanium, and the economics associated with fabrication of titanium components. This CRADA project evaluated the potential to develop a heavy vehicle component from titanium powders. The project included alloy design, development of manufacturing practices, and modeling the economics associated with the new component. New Beta alloys were designed for this project to provide the required mechanical specifications while utilizing the benefits of the new fabrication approach. Manufacturing procedures were developed specific to the heavy vehicle component. Ageing and thermal treatment optimization was performed to provide the desired microstructures. The CRADA partner established fabrication practices and targeted capital investment required for fabricating the component out of titanium. Though initial results were promising, the full project was not executed due to termination of the effort by the CRADA partner and economic trends observed in the heavy vehicle market.

Blue, C.A.; Peter, W.H.

2010-07-02T23:59:59.000Z

459

Water and Carbon Dioxide Adsorption at Olivine Surfaces  

SciTech Connect (OSTI)

Plane-wave density functional theory (DFT) calculations were performed to simulate water and carbon dioxide adsorption at the (010) surface of five olivine minerals, namely, forsterite (Mg2SiO4), calcio-olivine (Ca2SiO4), tephroite (Mn2SiO4), fayalite (Fe2SiO4), and Co-olivine (Co2SiO4). Adsorption energies per water molecule obtained from energy minimizations varied from -78 kJ mol-1 for fayalite to -128 kJ mol-1 for calcio-olivine at sub-monolayer coverage and became less exothermic as coverage increased. In contrast, carbon dioxide adsorption energies at sub-monolayer coverage ranged from -20 kJ mol-1 for fayalite to -59 kJ mol-1 for calcio-olivine. Therefore, the DFT calculations show a strong driving force for carbon dioxide displacement by water at the surface of all olivine minerals in a competitive adsorption scenario. Additionally, adsorption energies for both water and carbon dioxide were found to be more exothermic for the alkaline-earth (AE) olivines than for the transition-metal (TM) olivines and to not correlate with the solvation enthalpies of the corresponding divalent cations. However, a correlation was obtained with the charge of the surface divalent cation indicating that the more ionic character of the AE cations in the olivine structure relative to the TM cations leads to greater interactions with adsorbed water and carbon dioxide molecules at the surface and thus more exothermic adsorption energies for the AE olivines. For calcio-olivine, which exhibits the highest divalent cation charge of the five olivines, ab initio molecular dynamics simulations showed that this effect leads both water and carbon dioxide to react with the surface and form hydroxyl groups and a carbonate-like species, respectively.

Kerisit, Sebastien N.; Bylaska, Eric J.; Felmy, Andrew R.

2013-11-14T23:59:59.000Z

460

Seven years of carbon dioxide enrichment, nitrogen fertilization and plant diversity influence arbuscular  

E-Print Network [OSTI]

Seven years of carbon dioxide enrichment, nitrogen fertilization and plant diversity influence by examining the joint effects of carbon dioxide (CO2) enrichment, nitrogen (N) fertilization and plant, community composition, grassland, niche partitioning hypothesis, nitrogen fertilization, plant richness

Minnesota, University of

Note: This page contains sample records for the topic "titanium dioxide tio2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Technical Data Sheet: TDS 15 DIFRAM100: RAPID AIR MONITOR -NITROGEN DIOXIDE (NO2).  

E-Print Network [OSTI]

Technical Data Sheet: TDS 15 DIFRAM100: RAPID AIR MONITOR - NITROGEN DIOXIDE (NO2). Description: A plastic (H.D.P.E.) circular diffusive sampler containing a sorbent for measuring gaseous nitrogen dioxide

Short, Daniel

462

Seven years of carbon dioxide enrichment, nitrogen fertilization and plant diversity influence arbuscular  

E-Print Network [OSTI]

Seven years of carbon dioxide enrichment, nitrogen fertilization and plant diversity influence by examining the joint effects of carbon dioxide (CO2) enrichment, nitrogen (N) fertilization and plant enrichment, community composition, grassland, niche partitioning hypothesis, nitrogen fertilization, plant

Minnesota, University of

463

Effet of Combined Nitrogen Dioxide and Carbon Nanoparticle Exposure on Lung Function During  

E-Print Network [OSTI]

Effet of Combined Nitrogen Dioxide and Carbon Nanoparticle Exposure on Lung Function During: Layachi S, Rogerieux F, Robidel F, Lacroix G, Bayat S (2012) Effet of Combined Nitrogen Dioxide and Carbon

Boyer, Edmond

464

Capture of green-house carbon dioxide in Portland cement  

SciTech Connect (OSTI)

A novel process has been developed to sequester green-house carbon dioxide produced by the cement industry in precast cement products. Typically, 10--24 wt % of CO{sub 2} produced by calcination of calcium carbonate during clinkering of the cement may be captured. The carbonation process also cures the cement paste within minutes into hard bodies. The process maintains high pH conditions during curing, to allow conventional steel reinforcement of concrete. The process will save time and money to the cement industry, and at the same time, help them to comply with the Clean Air Act by sequestering the green-house carbon dioxide.

Wagh, A.S.; Singh, D.; Pullockaran, J.; Knox, L.

1993-12-31T23:59:59.000Z

465

Solubility of anthracene and anthraquinone in cyclohexanone + carbon dioxide  

SciTech Connect (OSTI)

In the processing of an anthracene oil fraction from coal tar, a mixture of anthracene and anthraquinone is required to be separated to obtain products of high purity. The solubilities of anthracene and anthraquinone were measured in cyclohexanone + carbon dioxide as a function of the temperature and pressure of carbon dioxide at 291, 300, and 313 K and from 1.8--12.4 MPa. Average equilibrium solubilities and recoveries of both solids increased with increasing normalized concentration and pressure. The average separation factor of anthracene to anthraquinone, due to the effect of the mixed solvent, was 2.88 [+-] 1.91.

Chang, C.J. (National Chung-Hsing Univ., Taichung (Taiwan, Province of China). Dept. of Chemical Engineering)

1994-10-01T23:59:59.000Z

466

E-Print Network 3.0 - atmospheric sulfur dioxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: (O3), nitrogen oxides (NOx), carbon monoxide (CO), and sulfur dioxide (SO2) will be measured... Ren...

467

E-Print Network 3.0 - acute sulphur dioxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acetone Concentrated nitric and sulphuric acid mixtures Alkali and alkaline Water, carbon tetrachloride... & other chlorinated earth metals hydrocarbons, carbon dioxide,...

468

Enery Efficient Press and Sinter of Titanium Powder for Low-Cost Components in Vehicle Applications  

SciTech Connect (OSTI)

This is the final technical report for the Department of Energy NETL project NT01931 Energy Efficient Press and Sinter of Titanium Powder for Low-Cost Components in Vehicle Applications. Titanium has been identified as one of the key materials with the required strength that can reduce the weight of automotive components and thereby reduce fuel consumption. Working with newly developed sources of titanium powder, Webster-Hoff will develop the processing technology to manufacture low cost vehicle components using the single press/single sinter techniques developed for iron based powder metallurgy today. Working with an automotive or truck manufacturer, Webster-Hoff will demonstrate the feasibility of manufacturing a press and sinter titanium component for a vehicle application. The project objective is two-fold, to develop the technology for manufacturing press and sinter titanium components, and to demonstrate the feasibility of producing a titanium component for a vehicle application. The lowest cost method for converting metal powder into a net shape part is the Powder Metallurgy Press and Sinter Process. The method involves compaction of the metal powder in a tool (usually a die and punches, upper and lower) at a high pressure (up to 60 TSI or 827 MPa) to form a green compact with the net shape of the final component. The powder in the green compact is held together by the compression bonds between the powder particles. The sinter process then converts the green compact to a metallurgically bonded net shape part through the process of solid state diffusion. The goal of this project is to expand the understanding and application of press and sinter technology to Titanium Powder applications, developing techniques to manufacture net shape Titanium components via the press and sinter process. In addition, working with a vehicle manufacturer, demonstrate the feasibility of producing a titanium component for a vehicle. This is not a research program, but rather a project to develop a process for press and sinter of net shape Titanium components. All of these project objectives have been successfully completed.

Thomas Zwitter; Phillip Nash; Xiaoyan Xu; Chadwick Johnson

2011-03-31T23:59:59.000Z

469

The Implied Cost of Carbon Dioxide under the Cash for Clunkers Christopher R. Knittel  

E-Print Network [OSTI]

The Implied Cost of Carbon Dioxide under the Cash for Clunkers Program Christopher R. Knittel of the implied cost of carbon dioxide reductions under the Cash for Clunker program. The estimates suggest pollutants. Conservative estimates of the implied carbon dioxide cost exceed $365 per ton; best case scenario

Rothman, Daniel

470

Interference of a short-term exposure to nitrogen dioxide with allergic airways responses to allergenic  

E-Print Network [OSTI]

Interference of a short-term exposure to nitrogen dioxide with allergic airways responses, 4 (2002) 251-260" DOI : 10.1080/096293502900000113 #12;Abstract Nitrogen dioxide (NO2) is a common and may depend to concentration of pollutant. Keywords: Mouse model of asthma; nitrogen dioxide; air

Paris-Sud XI, Université de

471

Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen in the  

E-Print Network [OSTI]

1 Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen the mole fraction of CO2 in the carbon dioxide + nitrogen + cyclopentane mixed hydrate phase, both defined;2 {water +carbon dioxide + nitrogen}, the equilibrium pressure of the mixed hydrate is reduced by 0.95 up

Paris-Sud XI, Université de

472

Enhanced carbon dioxide capture upon incorporation of -dimethylethylenediamine in the metalorganic framework CuBTTri  

E-Print Network [OSTI]

. Introduction The separation of carbon dioxide from nitrogen at low pressures, applicable to postEnhanced carbon dioxide capture upon incorporation of N,N0 -dimethylethylenediamine in the metal-combustion carbon dioxide capture will be judged. The incorporation of N,N0 -dimethylethylenediamine (mmen) into H3

473

Validation of Ozone Monitoring Instrument nitrogen dioxide columns E. A. Celarier,1  

E-Print Network [OSTI]

Validation of Ozone Monitoring Instrument nitrogen dioxide columns E. A. Celarier,1 E. J. Brinksma the standard nitrogen dioxide (NO2) data product (Version 1.0.), which is based on measurements made), Validation of Ozone Monitoring Instrument nitrogen dioxide columns, J. Geophys. Res., 113, D15S15, doi:10

474

Ground-level nitrogen dioxide concentrations inferred from the satellite-borne Ozone Monitoring Instrument  

E-Print Network [OSTI]

Ground-level nitrogen dioxide concentrations inferred from the satellite-borne Ozone Monitoring; published 28 August 2008. [1] We present an approach to infer ground-level nitrogen dioxide (NO2), Ground-level nitrogen dioxide concentrations inferred from the satellite-borne Ozone Monitoring

Martin, Randall

475

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates  

E-Print Network [OSTI]

Summary Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates be inferred for important trace gases such as ozone (O3) and nitrogen dioxide (NO2). Chemical transport models.11 to 3.79. Total nitrogen dioxide columns can be retrieved from space in the 405­465 nm window

Haak, Hein

476

A global single-sensor analysis of 20022011 tropospheric nitrogen dioxide trends observed from space  

E-Print Network [OSTI]

A global single-sensor analysis of 2002­2011 tropospheric nitrogen dioxide trends observed from nitrogen dioxide trends observed from space, J. Geophys. Res., 117, D16309, doi:10.1029/2012JD017571. 1. Introduction [2] Nitrogen dioxide (NO2) is one of most prominent air pollutants and is emitted primarily

Haak, Hein

477

Indirect validation of tropospheric nitrogen dioxide retrieved from the OMI satellite instrument: Insight into the seasonal  

E-Print Network [OSTI]

Click Here for Full Article Indirect validation of tropospheric nitrogen dioxide retrieved from nitrogen dioxide retrieved from the OMI satellite instrument: Insight into the seasonal variation of the hydroxyl radical (OH). Nitrogen dioxide (NO2) is an indicator of surface air quality that is associated

Dirksen, Ruud

478

An idealized assessment of the economics of air capture of carbon dioxide in mitigation policy  

E-Print Network [OSTI]

the assumption that technol- ogies available today are used to fully offset net human emissions of carbon dioxideAn idealized assessment of the economics of air capture of carbon dioxide in mitigation policy, primarily carbon dioxide (CO2). During 2007, countries have been actively engaged in negotiating future

Colorado at Boulder, University of

479

Carbon Dioxide-Induced Anesthesia Results in a Rapid Increase in Plasma Levels of Vasopressin  

E-Print Network [OSTI]

Carbon Dioxide-Induced Anesthesia Results in a Rapid Increase in Plasma Levels of Vasopressin Brian of carbon dioxide, prior to decapitation is considered a more humane alternative for the euthanasia with carbon dioxide until recumbent (20­25 sec), immediately killed via decapitation, and trunk blood

Chait, Brian T.

480

Surface blistering and flaking of sintered uranium dioxide samples under high dose gas implantation and annealing  

E-Print Network [OSTI]

Surface blistering and flaking of sintered uranium dioxide samples under high dose gas implantation-sur-Yvette, France. a guillaume.martin@cea.fr Keywords: uranium dioxide, helium, hydrogen, implantation, blistering, flaking Abstract. High helium contents will be generated within minor actinide doped uranium dioxide

Boyer, Edmond

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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis Ram Chandra Sekar  

E-Print Network [OSTI]

Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis by Ram Chandra Sekar;2 #12;3 Carbon Dioxide Capture in Coal-Fired Power Plants: A Real Options Analysis by Ram Chandra Sekar technologies are valued using the "real options" valuation methodology in an uncertain carbon dioxide (CO2

482

Regulating Carbon Dioxide Capture and Storage 07-003 April 2007  

E-Print Network [OSTI]

Regulating Carbon Dioxide Capture and Storage by 07-003 April 2007 M.A. de Figueiredo, H.J. Herzog, P.L. Joskow, K.A. Oye, and D.M. Reiner #12;#12;Regulating Carbon Dioxide Capture and Storage M.A. de to be addressed to create an effective regulatory regime for carbon dioxide capture and storage ("CCS"). Legal

483

A correlation of optimal heat rejection pressures in transcritical carbon dioxide cycles  

E-Print Network [OSTI]

®cance for the design and control of the transcritical carbon dioxide air- conditioning and heat pump systems 7 2000A correlation of optimal heat rejection pressures in transcritical carbon dioxide cycles S.M. Liaoa) of transcritical carbon dioxide air-conditioning cycles. The analysis shows that the COP of the transcritical

Zhao, Tianshou

484

Estimation of Methane and Carbon Dioxide Surface Fluxes using a 3-D Global Atmospheric  

E-Print Network [OSTI]

Estimation of Methane and Carbon Dioxide Surface Fluxes using a 3-D Global Atmospheric Chemical@mit.edu Website: http://mit.edu/cgcs/ Printed on recycled paper #12;Estimation of Methane and Carbon Dioxide of Methane and Carbon Dioxide Surface Fluxes using a 3-D Global Atmospheric Chemical Transport Model by Yu

485

Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California  

E-Print Network [OSTI]

Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California Lawrence Berkeley National Laboratory October, 2008 Contract #05-310 "Improving the Carbon Dioxide Emission Continuous Emissions Monitoring CHP Combined Heat and Power CO2 Carbon Dioxide DMV Department of Motor

486

Silicon dioxide and hafnium dioxide evaporation characteristics from a high-frequency sweep e-beam system  

SciTech Connect (OSTI)

Reactive oxygen evaporation characteristics were determined as a function of the front-panel control parameters provided by a programmable, high-frequency sweep e-beam system. An experimental design strategy used deposition rate, beam speed, pattern, azimuthal rotation speed, and dwell time as the variables. The optimal settings for obtaining a broad thickness distribution, efficient silicon dioxide boule consumption, and minimal hafnium dioxide defect density were generated. The experimental design analysis showed the compromises involved with evaporating these oxides. {copyright} {ital 1996 Optical Society of America.}

Chow, R. [Lawrence Livermore National Laboratory, Livermore, California 94551-0808 (United States); Tsujimoto, N. [MDC Vacuum Products Corporation, Hayward, California 94545 (United States)

1996-09-01T23:59:59.000Z

487

Carbon dioxide flash-freezing applied to ice cream production  

E-Print Network [OSTI]

(cont.) Carbon dioxide is recompressed from 1.97 x 106 Pa (285 psi) to 3.96 x 106 Pa (575 psi). The process is scaled by increasing the number of nozzles to accommodate the desired flow rate. Only 165 nozzles are required ...

Peters, Teresa Baker, 1981-

2006-01-01T23:59:59.000Z

488

Corrosion of various engineering alloys in supercritical carbon dioxide  

E-Print Network [OSTI]

The corrosion resistance of ten engineering alloys were tested in a supercritical carbon dioxide (S-CO 2) environment for up to 3000 hours at 610C and 20MPa. The purpose of this work was to evaluate each alloy as a potential ...

Gibbs, Jonathan Paul

2010-01-01T23:59:59.000Z

489

II. Greenhouse gas markets, carbon dioxide credits and biofuels17  

E-Print Network [OSTI]

15 II. Greenhouse gas markets, carbon dioxide credits and biofuels17 The previous chapter analysed biofuels production. GHG policies18 that create a carbon price either through an emissions trading system or directly by taxing GHG emissions also generate increased demand for biofuels. They do so by raising

490

Zinc-catalyzed copolymerization of carbon dioxide and propylene oxide  

E-Print Network [OSTI]

dioxide has recently been paid attention in the field of extraction, separation, and reaction medium, its aptitude for both a reaction solvent and a reactant was examined in zinc glutarate-catalyzed reactions. As a result, it was proved that supercritical...

Katsurao, Takumi

1994-01-01T23:59:59.000Z

491

Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide  

Broader source: Energy.gov [DOE]

Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250C, and to develop chemical modeling of CO2-reservior rock interactions.

492

Auction design and the market for sulfur dioxide emissions  

E-Print Network [OSTI]

Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

Joskow, Paul L.

1996-01-01T23:59:59.000Z

493

Degassing of metamorphic carbon dioxide from the Nepal Himalaya  

E-Print Network [OSTI]

Degassing of metamorphic carbon dioxide from the Nepal Himalaya Matthew J. Evans Chemistry at the foot of the Higher Himalaya near the Main Central Thrust (MCT), Nepal Himalaya. We have sampled hot the Nepal Himalaya, Geochem. Geophys. Geosyst., 9, Q04021, doi:10.1029/2007GC001796. 1. Introduction [2

Derry, Louis A.

494

Remote estimation of carbon dioxide uptake by a Mediterranean forest  

E-Print Network [OSTI]

to assessing the global carbon budget in a context of climate change (Ciais et al., 2005; Boisvenue & RunningRemote estimation of carbon dioxide uptake by a Mediterranean forest M A R T I´ N F. G A R B U L of the ecology of global change. Current remote sensing methodologies for estimating gross primary productivity

Garbulsky, Martín

495

Phase relation between global temperature and atmospheric carbon dioxide  

E-Print Network [OSTI]

The primary ingredient of Anthropogenic Global Warming hypothesis is the assumption that atmospheric carbon dioxide variations are the cause for temperature variations. In this paper we discuss this assumption and analyze it on basis of bi-centenary measurements and using a relaxation model which causes phase shifts and delays.

Stallinga, Peter

2013-01-01T23:59:59.000Z

496

Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide  

DOE Patents [OSTI]

A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

Rathke, J.W.; Klingler, R.J.

1993-03-30T23:59:59.000Z

497

Methane-assisted combustion synthesis of nanocomposite tin dioxide materials  

E-Print Network [OSTI]

Methane-assisted combustion synthesis of nanocomposite tin dioxide materials S.D. Bakrania *, C and flow conditions using methane as a supplemental fuel. The experiments were carried out at atmospheric-phase precursor for metal additives. In the methane-assisted (MA) system, the inert carrier gas was replaced

Wooldridge, Margaret S.

498

High Temperature Electrolysis of Steam and Carbon Dioxide  

E-Print Network [OSTI]

High Temperature Electrolysis of Steam and Carbon Dioxide Søren Højgaard Jensen+,#, Jens V. T. Høgh + O2 #12;Electrolysis of steam at high temperature Interesting because · Improved thermodynamic of electrolysis of steam Picture taken from E. Erdle, J. Gross, V. Meyringer, "Solar thermal central receiver

499

Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite  

E-Print Network [OSTI]

Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite C H E N H . S H E N A N D G by absorption in sulfite solution in existing scrubbers for desulfurization. Rates of NO2 absorption and sulfite absorption initiates sulfite oxidation in the presence of oxygen, and this study quantified the effect

Rochelle, Gary T.

500

The Net Environmental Effects of Carbon Dioxide Reduction Policies  

E-Print Network [OSTI]

of policy measures have been proposed to reduce the emissions of carbon dioxide (CO2). However, policies which reduce CO2 emissions will also decrease the emissions of greenhouse-relevant gases methane are overlooked the net effect of CO2 reduction policies on global warming is understated. Thus, emissions of all